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Sample records for fenton hill hdr

  1. Scientific progress on the Fenton Hill HDR project since 1983

    SciTech Connect

    Brown, D.W.; Duchane, D.V.

    1998-02-01

    The modern HDR concept originated at the Los Alamos National Laboratory and was first demonstrated at Fenton Hill, NM. Experience gained during the development of the deeper HDR reservoir at Fenton Hill clearly showed that HDR reservoirs are formed by opening pre-existing, but sealed, multiply connected joint sets. Subsequent flow testing indicated that sustained operation of HDR systems under steady state conditions is feasible. The most significant remaining HDR issues are related to economics and locational flexibility. Additional field test sites are needed to advance the understanding of HDR technology so that the vast potential of this resource can be economically realized around the world.

  2. Heat extracted from the long term flow test in the Fenton Hill HDR reservoir

    SciTech Connect

    Kruger, Paul; Robinson, Bruce

    1994-01-20

    A long-term flow test was carried out in the Fenton Hill HDR Phase-2 reservoir for 14 months during 1992-1993 to examine the potential for supplying thermal energy at a sustained rate as a commercial demonstration of HDR technology. The test was accomplished in several segments with changes in mean flowrate due to pumping conditions. Re-test estimates of the extractable heat content above a minimum useful temperature were based on physical evidence of the size of the Fenton Hill reservoir. A numerical model was used to estimate the extent of heat extracted during the individual flow segments from the database of measured production data during the test. For a reservoir volume of 6.5x10{sup 6}m{sup 3}, the total heat content above a minimum temperature of 150{degree} C was 1.5x10{sup 15}J. For the total test period at the three sustained mean flowrates, the integrated heat extracted was 0.088x10{sup 15}J, with no discernable temperature decline of the produced fluid. The fraction of energy extracted above the abandonment temperature was 5.9%. On the basis of a constant thermal energy extraction rate, the lifetime of the reservoir (without reservoir growth) to the abandonment temperature would be 13.3 years, in good agreement with the pre-test estimate of 15.0 years for the given reservoir volume.

  3. Start-Up Operations at the Fenton Hill HDR Pilot Plant

    SciTech Connect

    Ponden, Raymond F.

    1992-03-24

    With the completion of the surface test facilities at Fenton Hill, the Hot Dry Rock (HDR) Geothermal Energy Program at Los Alamos is moving steadily into the next stage of development. Start-up operations of the surface facilities have begun in preparation for testing the Phase II reservoir and the initial steady-state phase of operations. A test program has been developed that will entail a number of operational strategies to characterize the thermal performance of the reservoir. The surface facilities have been designed to assure high reliability while providing the flexibility and control to support the different operating modes. This paper presents a review of the system design and provides a discussion of the preliminary results of plant operations and equipment performance.

  4. ICFT: An initial closed-loop flow test of the Fenton Hill Phase II HDR reservoir

    SciTech Connect

    Dash, Z.V.; Aguilar, R.G.; Dennis, B.R.; Dreesen, D.S.; Fehler, M.C.; Hendron, R.H.; House, L.S.; Ito, H.; Kelkar, S.M.; Malzahn, M.V.

    1989-02-01

    A 30-day closed-loop circulation test of the Phase II Hot Dry Rock reservoir at Fenton Hill, New Mexico, was conducted to determine the thermal, hydraulic, chemical, and seismic characteristics of the reservoir in preparation for a long-term energy-extraction test. The Phase II heat-extraction loop was successfully tested with the injection of 37,000 m/sup 3/ of cold water and production of 23,300 m/sup 3/ of hot water. Up to 10 MW/sub t/ was extracted when the production flow rate reached 0.0139 m/sup 3//s at 192/degree/C. By the end of the test, the water-loss rate had decreased to 26% and a significant portion of the injected water was recovered; 66% during the test and an additional 20% during subsequent venting. Analysis of thermal, hydraulic, geochemical, tracer, and seismic data suggests the fractured volume of the reservoir was growing throughout the test. 19 refs., 64 figs., 19 tabs.

  5. Geology and geochemistry of samples from Los Alamos National Laboratory HDR Well EE-2, Fenton Hill, New Mexico

    SciTech Connect

    Laney, R.; Laughlin, A.W.; Aldrich, M.J. Jr.

    1981-07-01

    Petrologic, geochemical, and structural analyses of cores and cuttings obtained from 3000 to 4389-m true vertical depth in drill hole EE-2 indicate that this deeper part of the Precambrian section at Fenton Hill, New Mexico is composed primarily of a very heterogeneous and structurally anisotropic metamorphic complex, locally intruded by dikes and sills of granodioritic and monzogranitic composition. In this borehole none of these igneous bodies approach in size the 335-m-thick biotite-granodiorite body encountered at 2591-m depth beneath Fenton Hill in the other two drill holes. Contacts between the igneous and metamorphic rocks range from sharp and discordant to gradational. Analysis of cuttings indicates that clay-rich alteration zones are relatively common in the openhole portion of EE-2. These zones average about 20 m in thickness. Fracture sets in the Precambrian basement rock intersected by the EE-2 well bore mostly trend northeast and are steeply dipping to vertical; however, one of the sets dips gently to the northwest. Slickensided fault planes are present in a core (No.5) taken from a true vertical depth of 4195 m. Available core orientation data and geologic inference suggest that the faults dip steeply and trend between N.42/sup 0/ and 59/sup 0/E.

  6. Orientation of minimum principal stress in the hot dry rock geothermal reservoir at Fenton Hill, New Mexico

    SciTech Connect

    Burns, K.L.

    1991-01-01

    The stress field at the source of microearthquakes in the interior of the hot dry rock geothermal reservoir at Fenton Hill appears to be different to the far field stress outside the reservoir. The stress field seems to be re-oriented prior to failure, during the course of processes that inflate the reservoir. The state of stress, both inside and outside, the hot dry rock (HDR) geothermal reservoir at Fenton Hill, is important in predicting the course of stress-dependent processes, and in transferring HDR technology developed at Fenton Hill, to sites, such as at Clearlake in California, where the stress field is expected to be substantially different. The state of stress at Fenton Hill is not well known because of limitations in stress measuring technology. It is necessary to use a variety of indirect methods and seek an estimate of the stress. 5 refs.

  7. Proposed Schedule for Fenton Hill Experiments

    SciTech Connect

    Albright, James N.; Brown, Donald W.

    1990-10-22

    To help in planning Fenton Hill experimental operations in concert with preparations for the Long-Term Flow Test (LTFT) next summer, the following schedule is proposed. This schedule fits some of the realities of the next few months, including the Laboratory closure during the Holidays, the seismic monitoring tests in Roswell, and the difficulties of operating during the winter months. Whenever possible, cyclic pumping operations during the colder months will be scheduled so that the pump will be on during the late evening and early morning hours to prevent freezeup.

  8. Meteorological analysis for Fenton Hill, 1979

    SciTech Connect

    Barr, S.; Wilson, S.K.

    1981-01-01

    Three years of meteorological data have been collected at the Fenton Hill site to establish a local climatic baseline, transport and diffusion climatology, and an initial site for an eventual Valles Caldera meteorological network. Tower-based wind and temperature data at 15 m above ground were supplemented during 1979 with precipitation, humidity and pressure measurements, and a limited program of upper winds. Preliminary analysis of the data has been made to identify major topographic and meteorological driving forces affecting the local climatic variations on diurnal and seasonal time scales. The site is quite high and exposed enough tht external influences such as gradient wind flow and thunderstorms tend to dominate over purely local driving forces in determining climate. Locally generated wind circulations are identifiable at night but tend to be weak and sporadic. The presence of topographic obstacles on the 10- to 100-km scale is observed in the winds.

  9. Environmental studies conducted at the Fenton Hill Hot Dry Rock geothermal development site

    SciTech Connect

    Miera, F.R. Jr.; Langhorst, G.; McEllin, S.; Montoya, C.

    1984-05-01

    An environmental investigation of Hot Dry Rock (HDR) geothermal development was conducted at Fenton Hill, New Mexico, during 1976-1979. Activities at the Fenton Hill Site included an evaluation of baseline data for biotic and abiotic ecosystem components. Identification of contaminants produced by HDR processes that had the potential for reaching the surrounding environment is also discussed. Three dominant vegetative communities were identified in the vicinity of the site. These included grass-forb, aspen, and mixed conifer communities. The grass-forb area was identified as having the highest number of species encountered, with Phleum pratense and Dactylis glomerata being the dominant grass species. Frequency of occurrence and mean coverage values are also given for other species in the three main vegetative complexes. Live trapping of small mammals was conducted to determine species composition, densities, population, and diversity estimates for this component of the ecosystem. The data indicate that Peromyscus maniculatus was the dominant species across all trapping sites during the study. Comparisons of relative density of small mammals among the various trapping sites show the grass-forb vegetative community to have had the highest overall density. Comparisons of small mammal diversity for the three main vegetative complexes indicate that the aspen habitat had the highest diversity and the grass-forb habitat had the lowest. Analyses of waste waters from the closed circulation loop indicate that several trace contaminants (e.g., arsenic, cadmium, fluoride, boron, and lithium) were present at concentrations greater than those reported for surface waters of the region.

  10. A Brief History With Lessons Learned From The Hot Dry Rock Geothermal Energy Program At Fenton Hill, New Mexico, USA

    NASA Astrophysics Data System (ADS)

    Kelkar, S.; Woldegabriel, G. W.; Rehfeldt, K. R.

    2009-12-01

    Important lessons were learned that continue to be relevant today from the world’s first successful demonstration of a Hot Dry Rock (HDR) system for extracting underground geothermal energy conducted at Fenton Hill, New Mexico. This experiment, conducted in hot, low-permeability, low-water context, crystalline basement rock was fundamentally different from the Enhanced Geothermal Systems (EGS) development currently underway at several sites in the U.S. and world. The HDR concept was developed in 1970’s at Los Alamos National Laboratory (LANL). Two HDR reservoirs with two wells each were created and tested at the Fenton Hill site. In spite of its proximity to the Valles caldera and the Rio Grande rift, geological information and heat-flow data were used successfully to select the Fenton Hill experimental site within a block of intact crystalline basement rocks. Deep crystalline basement rocks marginal to active fault/recent volcanic centers were good candidates for HDR systems: these rocks had high heat content, and low matrix permeability leading to low water losses. Reconnaissance surveys indicated significant potential HDR geothermal resources through out the USA. Drilling and completion operations in hot crystalline rocks were challenging requiring further R&D. Hydraulic stimulation activities were carried out successfully in deep, hot crystalline rocks. Logging tools and instruments were developed that could operate successfully in the ~250oC environment. Development of techniques and tools for microseismic data monitoring, analysis, and interpretation was found to be enormously valuable. It was found that the systematic process that should be followed in developing HDR reservoirs is to drill and stimulate the first well, use the microseismic data to locate the target zone, and then complete the additional wells. The largest fraction of the flow impedance was found to be near the production well. Combined interpretation of the pressure testing, microseismic

  11. Pre-test estimates of temperature decline for the LANL Fenton Hill Long-Term Flow Test

    SciTech Connect

    Robinson, B.A.; Kruger, P.

    1992-06-01

    Pre-test predications for the Long-Term Flow Test (LTFT) of the experimental Hot Dry Rock (HDR) reservoir at Fenton Hill were made using two models. Both models are dependent on estimates of the ``effective`` reservoir volume accessed by the fluid and the mean fracture spacing (MFS) of major joints for fluid flow. The effective reservoir volume was estimated using a variety of techniques, and the range of values for the MFS was set through experience in modeling the thermal cooldown of other experimental HDR reservoirs. The two pre-test predictions for cooldown to 210{degrees}C (a value taken to compare the models) from initial temperature of 240{degrees}C are 6.1 and 10.7 years. Assuming that a minimum of 10{degrees}C is required to provide an unequivocal indication of thermal cooldown, both models predict that the reservoir will not exhibit observable cooldown for at least two years.

  12. Gas Analysis of Core Samples from Fenton Hill

    SciTech Connect

    Laughlin, A. William

    1983-07-15

    Among the suggested sources of the CO2 produced by the deep wells at Fenton Hill are secondary fluid inclusions produced during formation of the magma chamber related to the Valles event. If this hypothesis were correct, the number of fluid inclusions and the amount of CO2 in them should increase with depth in the well bore, particularly since EE-2 was deviated toward the caldera. Twenty core samples and two surface gneiss samples from Guadalupe Box were decrepitated to open these inclusions and the gases analyzed by mass spectrometry by MIDECO of Salt Lake City.

  13. Peer Review of the Hot Dry Rock Project at Fenton Hill, New Mexico

    SciTech Connect

    1998-12-01

    This report briefly describes the history of the hot dry rock experiment project conducted by the U.S. Department of Energy and Los Alamos National Laboratory at Fenton Hill, New Mexico, from about 1971 through 1995. The authors identify the primary lessons learned and techniques developed during the course of the Fenton Hill project, and summarize the extent to which these technologies have been transferred to the U.S. geothermal industry.

  14. Investigation of a shallow aquifer near the Fenton Hill hot dry rock site using DC resistivity

    SciTech Connect

    Pearson, C.F.

    1981-10-01

    A shallow aquifer in the base of the Tertiary volcanic sequence was investigated using a series of 9 DC Schlumberger soundings taken within 10 km of the Fenton Hill hot dry rock geothermal site. The aquifer dips to the southwest following the top of the Abo formation, which acts as an aquiclude. Depth increases from 130 m in the eastern part of the study area to 260 m at 1.5 km west of the Fenton Hill site. Aquifer resistivities varied from 13..cap omega..-m to 126..cap omega..-m, which could be caused by variable permeability in the aquifer. Using results from empirical studies permeabilities ranging from 40 darcies to less than 0.3 darcies were estimated with the highest values occurring nearest to the Fenton Hill site.

  15. Structural analysis of Precambrian rocks at the Hot Dry Rock Site at Fenton Hill, New Mexico

    SciTech Connect

    Burns, K.L.; Potter, R.M.

    1995-01-01

    The subcrop of basement rock at Fenton HIll comprises Precambrian gneiss, schist, amphibolite, pegmatite, and granitoids with affinities in metamorphic and structural history to surface outcrops in the Tusas and Picuris Ranges. Televiewer measurements of structures were analyzed by taking advantage of the spatial continuity of foliations. Folds in the foliation are predominantly conical forms due to interference between structures formed in F2 and F3 tectonic events. Field observations of outcrops in the Picuris Range show that the fractures are predominantly an X-T network controlled by the lithological layering, and statistical evidence indicates that this layer-controlled network persists to depth at Fenton Hill.

  16. The history of HDR research and development

    SciTech Connect

    Duchane, D.

    1998-12-31

    An energy source rivaling the sun exists in the form of the heat emanating from the interior of the earth. Although limited quantities of this geothermal energy are produced today by bringing natural hot fluids to the surface, most of the earth`s heat is trapped in hot dry rock (HDR). The application of hydraulic fracturing technology to tap this vast HDR resource was pioneered by Los Alamos National Laboratory beginning in 1970. Since that time, engineered geothermal reservoirs have been constructed and operated at numerous locations around the world. Major work at the US HDR facility at Fenton Hill, NM, and at the British HDR site in Cornwall, UK, has been completed, but advanced HDR field work continues at two sites on the island of Honshu in Japan and at Soultz in northeastern France. In addition, plans are currently being completed for the construction of an HDR system on the continent of Australia. Over the past three decades the worldwide research and development effort has taken HDR from its early conceptual stage to its present state as a demonstrated technology that is on the verge of becoming commercially feasible. Extended flow tests in the United States, Japan, and Europe have proven that sustained operation of HDR reservoirs is possible. In support of these field tests, an international body of scientists and engineers have pursued a variety of innovative approaches for assessing HDR resources, constructing and characterizing engineered geothermal reservoirs, and operating HDR systems. Taken together, these developments form a strong base upon which to build the practical HDR systems that will provide clean energy for the world in the 21st century.

  17. Drilling fluids and lost circulation in hot-dry-rock geothermal wells at Fenton Hill

    SciTech Connect

    Nuckols, E.B.; Miles, D.; Laney, R.; Polk, G.; Friddle, H.; Simpson, G.

    1981-01-01

    Geothermal hot dry rock drilling at Fenton Hill in northern New Mexico encountered problems of catastrophic lost circulation in cavernous areas of limestones in the Sandia Formation, severe corrosion due to temperatures of up to 320/sup 0/C, and torque problems caused by 35/sup 0/ hole angle and the abrasiveness of Precambrian crystalline rock. The use of polymeric flocculated bentonite fluid, clear water, fibrous material, dry drilling, oxygen scavengers, a biodegradable lubricant mixture of modified triglicerides and alcohol, and maintenance of a high pH, were some of the approaches taken toward solving these problems.

  18. Next stages in HDR technology development

    SciTech Connect

    Duchane, D.V.

    1993-03-01

    Twenty years of research and development have brought HDR heat mining technology from the purely conceptual stage to the establishment of an engineering-scale heat mine at Fenton Hill, NM. In April 1992, a long-term flow test (LTFT) of the HDR reservoir at Fenton Hill was begun. The test was carried out under steady-state conditions on a continuous basis for four months, but a major equipment failure in late July forced a temporary suspension of operations. Even this short test provided valuable information and extremely encouraging results as summarized below: There was no indication of thermal drawdown of the reservoir. There was evidence of increasing access to hot rock with time. Water consumption was in the rangki of 10--12%. Measured pumping costs were $0.003 per kilowatt of energy produced. Temperature logs conducted in the reservoir production zone during and after the flow test confirmed the fact that there was no decline in the average temperature of the fluid being produced from the reservoir. In fact, tracer testing showed that the fluid was taking more indirect pathways and thus contacting a greater amount of hot rock as the test progressed. Water usage quickly dropped to a level of 10--15 gallons per minute, an amount equivalent to about 10--12% of the injected fluid volume. At a conversion rate of 10--15%, these would translate to effective ``fuel costs`` of 2--3{cents} per kilowatt hour of electricity production potential. The completion of the LTFT will set the stage for commercialization of HDR but will not bring HDR technology to maturity. Relatively samples extensions of the current technology may bring significant improvements in efficiency, and these should be rapidly investigated. In the longer run, advanced operational concepts could further improve the efficiency of HDR energy extraction and may even offer the possibility of cogeneration schemes which solve both energy and water problems throughout the world.

  19. Reservoir water loss modeling and measurements at Fenton Hill, New Mexico

    SciTech Connect

    Brown, D.W.

    1989-01-01

    An extensive series of pressurized reservoir water loss experiments are presently being conducted in the deeper Phase II reservoir, at the Laboratory's Fenton Hill site in north-central New Mexico. The objectives of these experiments are: to measure the reservoir water leak-off rate at a number of equilibrium reservoir pressure levels, and as a function of time; and with this pressure- and time-dependent water-loss data, to determine the joint dilation (i.e., mean joint porosity) of the reservoir as a function of pressure up to about 24 MPa (as measured at the surface). The permeability model of Gangi has been used to explain the Phase II reservoir water loss as measured during two reservoir flow tests of 7 and 30 days duration. During the 30-day flow test, the model strongly suggests that the reservoir was actively growing by fracture extension, even at injection pressures as low as 27 MPa, which is confirmed by our seismic observations. 3 refs., 6 figs., 1 tab.

  20. Drilling Fluids and Lost Circulation in Hot Dry Rock Geothermal Wells at Fenton Hill

    SciTech Connect

    Nuckols, E.B.; Miles, D.; Laney, R.; Polk, G. Friddle, H.; Simpson, G.

    1981-01-01

    Geothermal hot dry rock drilling activities at Fenton Hill in the Jemez Mountains of northern New Mexico encountered problems in designing drilling fluids that will reduce catastrophic lost circulation. Four wells (GT-2, EE-1, EE-2, and EE-3) penetrated 733 m (2405 ft) of Cenozoic and Paleozoic sediments and Precambrian crystalline rock units to +4572 m (+15,000 ft). The Cenozoic rocks consist of volcanics (rhyolite, tuff, and pumice) and volcaniclastic sediments. Paleozoic strata include Permian red beds (Abo formation) and the Pennsylvanian Madera and Sandia Formations, which consist of massive limestones and shales. Beneath the Sandia Formation are igneous and metamorphic rocks of Precambrian age. The drilling fluid used for the upper sedimentary formations was a polymeric flocculated bentonite drilling fluid. Severe loss of circulation occurred in the cavernous portions of the Sandia limestones. The resultant loss of hydrostatic head caused sloughing of the Abo and of some beds within the Madera Formation. Stuck pipe, repetitive reaming, poor casing cement jobs and costly damage to the intermediate casing resulted. The Precambrian crystalline portion of the EE-2 and EE-3 wells were directionally drilled at a high angle, and drilled with water as the primary circulating fluid. Due to high temperatures (approximately 320 C (608 F) BHT) and extreme abrasiveness of the deeper part of the Precambrian crystalline rocks, special problems of corrosion inhibition and of torque friction were incurred. Several techniques were attempted to solve these problems but have met with varying degrees of success.

  1. Drilling fluids and lost circulation in hot dry rock geothermal wells at Fenton Hill

    SciTech Connect

    Nuckols, E.B.; Miles, D.; Laney, R.; Polk, G.; Friddle, H.; Simpson, G.; Baroid, N.L.

    1981-01-01

    Geothermal hot dry rock drilling activities at Fenton Hill in the Jemez Mountains of northern New Mexico encountered problems in designing drilling fluids that will reduce catastrophic lost circulation. Four wells (GT-2, EE-1, EE-2, and EE-3) penetrated 733 m (2405 ft) of Cenozoic and Paleozoic sediments and Precambrian crystalline rock units to +4572 m (+15,000 ft). The Cenozoic rocks consist of volcanics (rhyolite, tuff, and pumice) and volcaniclastic sediments. Paleozoic strata include Permian red beds (Abo Formation) and the Pennsylvanian Madera and Sandia Formations, which consist of massive limestones and shales. Beneath the Sandia Formation are igneous and metamorphic rocks of Precambrian age. The drilling fluid used for the upper sedimentary formations was a polymeric flocculated bentonite drilling fluid. Severe loss of circulation occurred in the cavernous portions of the Sandia limestones. The resultant loss of hydrostatic head caused sloughing of the Abo and of some beds within the Madera Formation. Stuck pipe, repetitive reaming, poor casing cement jobs and costly damage to the intermediate casing resulted. The Precambrian crystalline portion of the EE-2 and EE-3 wells were directionally drilled at a high angle, and drilled with water as the primary circulating fluid. Due to high temperatures (approximately 320/sup 0/C (608/sup 0/F) BHT) and extreme abrasiveness of the deeper part of the Precambrian crystalline rocks, special problems of corrosion inhibition and of torque friction were incurred.

  2. HDR opportunities and challenges beyond the long-term flow test

    SciTech Connect

    Duchane, D.V.

    1992-01-01

    The long term flow test (LTFT) of the world's largest, deepest, and hottest hot dry rock (HDR) reservoir currently underway at Fenton Hill, NM, is expected to demonstrate that thermal energy can be mined from hot rock within the earth on a sustainable basis with minimal water consumption. This test will simulate the operations of a commercial facility in some ways, but it will not show that energy from HDR can be produced at a variety of locations with different geological settings. Since the Fenton Hill system was designed as a research facility rather than strictly for production purposes, it will also not demonstrate economic viability, although it may well give indications of system modifications needed for economic HDR operations. A second production site must be constructed, ideally under the direction of the private geothermal community, to begin the process of proving that the vast HDR resources can be accessed on a worldwide scale. Finally, research and development work in areas such as reservoir interrogation, and system modeling must be accelerated to increase the competitiveness and geographical applications of HDR and the geothermal industry in general. This paper addresses the above issues in detail and outlines possible paths to future prosperity for the commercial geothermal industry.

  3. HDR Opportunities and Challenges Beyond the Long-Term Flow Test

    SciTech Connect

    Duchane, David

    1992-03-24

    The long term flow test (LTFT) of the worlds largest, deepest, and hottest hot dry rock (HDR) reservoir currently underway at Fenton Hill, NM, is expected to demonstrate that thermal energy can be mined from hot rock within the earth on a sustainable basis with minimal water consumption. This test will simulate the operations of a commercial facility in some ways, but it will not show that energy from HDR can be produced at a variety of locations with different geological settings. Since the Fenton Hill system was designed as a research facility rather than strictly for production purposes, it will also not demonstrate economic viability, although it may well give indications of system modifications needed for economic HDR operations. A second production site must be constructed, ideally under the direction of the private geothermal community, to begin the process of proving that the vast HDR resources can be accessed on a worldwide scale. This facility should be designed and engineered to produce and market energy at competitive prices. At the same time, a wide variety of techniques to advance the state-of-the-art of HDR technology must be pursued to develop this infant technology rapidly to its maximum potential. A number of design and operational techniques have been conceived which may lead to improved economics in HDR systems. After careful technical and economic scrutiny, those showing merit should be vigorously pursued. Finally, research and development work in areas such as reservoir interrogation, and system modeling must be accelerated to increase the competitiveness and geographical applications of HDR and the geothermal industry in general. This paper addresses the above issues in detail and outlines possible paths to future prosperity for the commercial geothermal industry.

  4. HDR opportunities and challenges beyond the long-term flow test isco, CA, 24-26 Mar. 1992

    NASA Astrophysics Data System (ADS)

    Duchane, D. V.

    1992-06-01

    The long term flow test (LTFT) of the world's largest, deepest, and hottest hot dry rock (HDR) reservoir currently underway at Fenton Hill, NM is expected to demonstrate that thermal energy can be mined from hot rock within the earth on a sustainable basis with minimal water consumption. This test will simulate the operations of a commercial facility in some ways, but it will not show that energy from HDR can be produced at a variety of locations with different geological settings. Since the Fenton Hill system was designed as a research facility rather than strictly for production purposes, it will also not demonstrate economic viability, although it may well give indications of system modifications needed for economic HDR operations. A second production site must be constructed, ideally under the direction of the private geothermal community, to begin the process of proving that the vast HDR resources can be accessed on a worldwide scale. Finally, research and development work in areas such as reservoir interrogation and system modeling must be accelerated to increase the competitiveness and geographical applications of HDR and the geothermal industry in general. This paper addresses the above issues in detail and outlines possible paths to future prosperity for the commercial geothermal industry.

  5. The dependence of permeability on effective stress from flow tests at hot dry rock reservoirs at Rosemanowes (Cornwall) and Fenton Hill (New Mexico)

    USGS Publications Warehouse

    Nathenson, M.

    1999-01-01

    Effective stress is the primary control on permeability and thus on flow and water loss for two-well hot dry rock systems involving injection and production that have been tested to date. Theoretical relations are derived for the flow between an injector and producer, including the dependence of permeability on effective stress. Four relations for permeability as a function of effective stress are used to match field data for the hot dry rock systems at Rosemanowes, Cornwall, and Fenton Hill, New Mexico. The flow and water loss behavior of these systems are well explained by the influence of effective stress on permeability. All four relations for permeability as a function of effective stress are successful in matching the field data, but some have difficulty in determining unique values for elastic and hydrologic parameters.Effective stress is the primary control on permeability and thus on flow and water loss for two-well hot dry rock systems involving injection and production that have been tested to date. Theoretical relations are derived for the flow between an injector and producer, including the dependence of permeability on effective stress. Four relations for permeability as a function of effective stress are used to match field data for the hot dry rock systems at Rosemanowes, Cornwall, and Fenton Hill, New Mexico. The flow and water loss behavior of these systems are well explained by the influence of effective stress on permeability. All four relations for permeability as a function of effective stress are successful in matching the field data, but some have difficulty in determining unique values for elastic and hydrologic parameters.

  6. A thermo-hydro-mechanical coupled model in local thermal non-equilibrium for fractured HDR reservoir with double porosity

    NASA Astrophysics Data System (ADS)

    Gelet, R.; Loret, B.; Khalili, N.

    2012-07-01

    The constitutive thermo-hydro-mechanical equations of fractured media are embodied in the theory of mixtures applied to three-phase poroelastic media. The solid skeleton contains two distinct cavities filled with the same fluid. Each of the three phases is endowed with its own temperature. The constitutive relations governing the thermomechanical behavior, generalized diffusion and transfer are structured by, and satisfy, the dissipation inequality. The cavities exchange both mass and energy. Mass exchanges are driven by the jump in scaled chemical potential, and energy exchanges by the jump in coldness. The finite element approximation uses the displacement vector, the two fluid pressures and the three temperatures as primary variables. It is used to analyze a generic hot dry rock geothermal reservoir. Three parameters of the model are calibrated from the thermal outputs of Fenton Hill and Rosemanowes HDR reservoirs. The calibrated model is next applied to simulate circulation tests at the Fenton Hill HDR reservoir. The finer thermo-hydro-mechanical response provided by the dual porosity model with respect to a single porosity model is highlighted in a parameter analysis. Emphasis is put on the influence of the fracture spacing, on the effective stress response and on the permeation of the fluid into the porous blocks. The dual porosity model yields a thermally induced effective stress that is less tensile compared with the single porosity response. This effect becomes significant for large fracture spacings. In agreement with field data, fluid loss is observed to be high initially and to decrease with time.

  7. High-temperature logging for basic development of HDR reservoirs

    SciTech Connect

    Mathews, M.; Pettitt, R.A.; Miles, D.J.

    1981-01-01

    The second phase of the Hot Dry Rock (HDR) Geothermal Development Program at Fenton Hill, New Mexico, consists of two boreholes, directionally-drilled in a northeast direction, inclined at an angle of 35/sup 0/, with a vertical separation of 365 m (1200 ft). The two boreholes will be connected by 12 to 15 vertical parallel fractures to make a geothermal reservoir calculated to produce 20 MW(e) for 20 years. Accurate temperature measurements, borehole caliper logs, and directional surveys are required for the successful development and operation of this man-made system. Obtaining these data is extremely difficult because of the bottom hole static temperature of 335/sup 0/C (635/sup 0/F) at a depth of 4660 m (15,289 ft), the 35/sup 0/ deviation, the abrasive formation, and the presence of sticky drilling residue products. The efforts during July, August, and September 1980, to obtain these data are presented as a case history. The temperature logs and borehole directional survey produced realistic results; but the borehole caliper measurements were inconsistent and unreliable, due to the developmental stage of the caliper tools.

  8. HDR geothermal energy - a progress report

    SciTech Connect

    Nunz, G.J.; Franke, P.R.

    1983-01-01

    A description of the Hot Dry Rock Geothermal Energy Program and a summary of the work completed to date are presented. The Fenton Hill Project is reviewed starting with the research system (Phase I) established in its initial configuration in 1977 with the research work completed in mid-1981. The engineering system (Phase II) initiated in parallel with the completion of the Phase I is now being developed in its interim configuration. The final system is planned for completion in FY 1985 with about one year of testing extending through FY 1986. Technical evaluations and test data to date are encouraging. The foreign involvement (FRG and Japan) is expected to continue along with positive support in the US.

  9. Demonstration of the Fenton Reaction

    ERIC Educational Resources Information Center

    Luehrs, Dean C.; Roher, Alex E.

    2007-01-01

    The study demonstrates the Fenton reaction, which is carried out using the Fenton reagent that is used for groundwater and soil remediation. The Fenton reaction can be implicated in DNA damage, Alzheimer's disease, cardiovascular disease and ageing in general.

  10. User's manual for HDR3 computer code

    SciTech Connect

    Arundale, C.J.

    1982-10-01

    A description of the HDR3 computer code and instructions for its use are provided. HDR3 calculates space heating costs for a hot dry rock (HDR) geothermal space heating system. The code also compares these costs to those of a specific oil heating system in use at the National Aeronautics and Space Administration Flight Center at Wallops Island, Virginia. HDR3 allows many HDR system parameters to be varied so that the user may examine various reservoir management schemes and may optimize reservoir design to suit a particular set of geophysical and economic parameters.

  11. Live HDR video streaming on commodity hardware

    NASA Astrophysics Data System (ADS)

    McNamee, Joshua; Hatchett, Jonathan; Debattista, Kurt; Chalmers, Alan

    2015-09-01

    High Dynamic Range (HDR) video provides a step change in viewing experience, for example the ability to clearly see the soccer ball when it is kicked from the shadow of the stadium into sunshine. To achieve the full potential of HDR video, so-called true HDR, it is crucial that all the dynamic range that was captured is delivered to the display device and tone mapping is confined only to the display. Furthermore, to ensure widespread uptake of HDR imaging, it should be low cost and available on commodity hardware. This paper describes an end-to-end HDR pipeline for capturing, encoding and streaming high-definition HDR video in real-time using off-the-shelf components. All the lighting that is captured by HDR-enabled consumer cameras is delivered via the pipeline to any display, including HDR displays and even mobile devices with minimum latency. The system thus provides an integrated HDR video pipeline that includes everything from capture to post-production, archival and storage, compression, transmission, and display.

  12. Image and video compression for HDR content

    NASA Astrophysics Data System (ADS)

    Zhang, Yang; Reinhard, Erik; Agrafiotis, Dimitris; Bull, David R.

    2012-10-01

    High Dynamic Range (HDR) technology can offer high levels of immersion with a dynamic range meeting and exceeding that of the Human Visual System (HVS). A primary drawback with HDR images and video is that memory and bandwidth requirements are significantly higher than for conventional images and video. Many bits can be wasted coding redundant imperceptible information. The challenge is therefore to develop means for efficiently compressing HDR imagery to a manageable bit rate without compromising perceptual quality. In this paper, we build on previous work of ours and propose a compression method for both HDR images and video, based on an HVS optimised wavelet subband weighting method. The method has been fully integrated into a JPEG 2000 codec for HDR image compression and implemented as a pre-processing step for HDR video coding (an H.264 codec is used as the host codec for video compression). Experimental results indicate that the proposed method outperforms previous approaches and operates in accordance with characteristics of the HVS, tested objectively using a HDR Visible Difference Predictor (VDP). Aiming to further improve the compression performance of our method, we additionally present the results of a psychophysical experiment, carried out with the aid of a high dynamic range display, to determine the difference in the noise visibility threshold between HDR and Standard Dynamic Range (SDR) luminance edge masking. Our findings show that noise has increased visibility on the bright side of a luminance edge. Masking is more consistent on the darker side of the edge.

  13. Black Hills

    Atmospheric Science Data Center

    2014-05-15

    article title:  Drought in the Black Hills     View ... and western South Dakota remain in the midst of a severe drought. This set of images and maps from NASA's Multi-angle Imaging ... the 2000 and 2004 dates. As the vegetation faded with the drought, the  albedo  at the surface increased. Albedo measures the ...

  14. Municipal solid waste landfill leachate treatment by fenton, photo-fenton and fenton-like processes: Effect of some variables

    PubMed Central

    2012-01-01

    Advanced oxidation processes like Fenton and photo-Fenton have been effectively applied to oxidize the persistent organic compounds in solid waste leachate and convert them to unharmful materials and products. However, there are limited data about application of Fenton-like process in leachate treatment. Therefore, this study was designed with the objective of treating municipal landfill leachate by Fenton, Fenton-like and photo–Fenton processes to determine the effect of different variables, by setting up a pilot system. The used leachate was collected from a municipal unsanitary landfill in Qaem-Shahr in the north of Iran. Fenton and Fenton-like processes were conducted by Jar-test method. Photo-Fenton process was performed in a glass photo-reactor. In all processes, H2O2 was used as the oxidant. FeSO4.7H2O and FeCl3.6H2O were used as reagents. All parameters were measured based on standard methods. The results showed that the optimum concentration of H2O2 was equal to 5 g/L for the Fenton-like process and 3 g/L for the Fenton and photo-Fenton processes. The optimum ratio of H2O2: Fe+2/Fe+3 were equal to 8:1 in all processes. At optimum conditions, the amount of COD removal was 69.6%, 65.9% and 83.2% in Fenton, Fenton-like and photo–Fenton processes, respectively. In addition, optimum pH were 3, 5 and 3 and the optimum contact time were 150, 90 and 120 minutes, for Fenton, Fenton-like and photo–Fenton processes, respectively. After all processes, the biodegradability (BOD5/COD ratio) of the treated leachate was increased compared to that of the raw leachate and the highest increase in BOD5/COD ratio was observed in the photo-Fenton process. The efficiency of the Fenton-like process was overally less than Fenton and photo-Fenton processes, meanwhile the Fenton-like process was at higher pH and did not show problems. PMID:23369204

  15. A JPEG backward-compatible HDR image compression

    NASA Astrophysics Data System (ADS)

    Korshunov, Pavel; Ebrahimi, Touradj

    2012-10-01

    High Dynamic Range (HDR) imaging is expected to become one of the technologies that could shape next generation of consumer digital photography. Manufacturers are rolling out cameras and displays capable of capturing and rendering HDR images. The popularity and full public adoption of HDR content is however hindered by the lack of standards in evaluation of quality, file formats, and compression, as well as large legacy base of Low Dynamic Range (LDR) displays that are unable to render HDR. To facilitate wide spread of HDR usage, the backward compatibility of HDR technology with commonly used legacy image storage, rendering, and compression is necessary. Although many tone-mapping algorithms were developed for generating viewable LDR images from HDR content, there is no consensus on which algorithm to use and under which conditions. This paper, via a series of subjective evaluations, demonstrates the dependency of perceived quality of the tone-mapped LDR images on environmental parameters and image content. Based on the results of subjective tests, it proposes to extend JPEG file format, as the most popular image format, in a backward compatible manner to also deal with HDR pictures. To this end, the paper provides an architecture to achieve such backward compatibility with JPEG and demonstrates efficiency of a simple implementation of this framework when compared to the state of the art HDR image compression.

  16. Summary of HDR Technology Commercialization Board Meeting

    SciTech Connect

    Duchane, David V.

    1993-04-23

    The Hot Dry Rock Technology Commercialization Board met on April 15, 1993, to review the current status of the Los Alamos Program and suggest future courses of action. During the first part of the meeting, the position of the U.S. DOE was presented, the most recent results of the long-term testing program were reviewed, and an economic study prepared recently for the DOE was described. This was followed by several hours of wide-ranging discussions on the future of HDR.

  17. Creating cinematic wide gamut HDR-video for the evaluation of tone mapping operators and HDR-displays

    NASA Astrophysics Data System (ADS)

    Froehlich, Jan; Grandinetti, Stefan; Eberhardt, Bernd; Walter, Simon; Schilling, Andreas; Brendel, Harald

    2014-03-01

    High quality video sequences are required for the evaluation of tone mapping operators and high dynamic range (HDR) displays. We provide scenic and documentary scenes with a dynamic range of up to 18 stops. The scenes are staged using professional film lighting, make-up and set design to enable the evaluation of image and material appearance. To address challenges for HDR-displays and temporal tone mapping operators, the sequences include highlights entering and leaving the image, brightness changing over time, high contrast skin tones, specular highlights and bright, saturated colors. HDR-capture is carried out using two cameras mounted on a mirror-rig. To achieve a cinematic depth of field, digital motion picture cameras with Super-35mm size sensors are used. We provide HDR-video sequences to serve as a common ground for the evaluation of temporal tone mapping operators and HDR-displays. They are available to the scientific community for further research.

  18. Effect of pH on Fenton and Fenton-like oxidation.

    PubMed

    Jung, Yong Sik; Lim, Woo Taik; Park, Joo-Yang; Kim, Young-Hun

    2009-02-01

    The lifetime of H2O2 is an important factor in the feasibility of Fenton's reaction for soil and groundwater remediation. The lifetime of H2O2 was evaluated in Fenton's reaction and Fenton-like reactions with haematite and magnetite. H2O2 was more stable in the Fenton-like reaction than in the Fenton's reaction. The lifetime of H2O2 was also highly affected by the solution pH, and a pH buffered acidic condition was preferred. Fenton's reaction and Fenton-like reaction were tested for phenanthrene adsorbed on sand. Fenton-like reaction and acidic condition showed better degradation rates in comparing with those of Fenton's reaction and unbuffered systems. The dissolved iron species were measured in the Fenton's reaction, and Fenton-like reaction with haematite as a function of pH. In the presence of H2O2, ferric iron was the major dissolved iron species and the pH buffered to acidic condition maintained relatively high levels of dissolved iron in the aqueous solution. The higher iron concentration in the solution contributed to effective production of hydroxyl radical and degradation of organic contaminants.

  19. Ghost removing for HDR real-time video stream generation

    NASA Astrophysics Data System (ADS)

    Bouderbane, Mustapha; Dubois, Julien; Heyrman, Barthélémy; Lapray, Pierre-Jean; Ginhac, Dominique

    2016-04-01

    High dynamic range (HDR) imaging generation from a set of low dynamic range images taken in different exposure times is a low cost and an easy technique. This technique provides a good result for static scenes. Temporal exposure bracketing cannot be applied directly for dynamic scenes, since camera or object motion in bracketed exposures creates ghosts in the resulting HDR image. In this paper we describe a real-time ghost removing hardware implementation on high dynamic range video ow added for our HDR FPGA based smart camera which is able to provide full resolution (1280 x 1024) HDR video stream at 60 fps. We present experimental results to show the efficiency of our implemented method in ghost removing.

  20. Cloning and analysis of 1-hydroxy-2-methyl-2-(E)-butenyl-4-diphosphate reductase genes HsHDR1 and HsHDR2 in Huperzia serrate

    PubMed Central

    Lv, Haizhou; Zhang, Xin; Liao, Baosheng; Liu, Wanjing; He, Liu; Song, Jingyuan; Sun, Chao; Luo, Hongmei; Chen, Shilin

    2015-01-01

    We cloned and analyzed the two genes of the 1-hydroxy-2-methyl-2-(E)-butenyl-4-diphosphate reductase (HDR) gene family from Huperzia serrate. The two transcripts coding HDR, named HsHDR1 and HsHDR2, were discovered in the transcriptome dataset of H. serrate and were cloned by reverse transcription-polymerase chain reaction (RT-PCR). The physicochemical properties, protein domains, protein secondary structure, and 3D structure of the putative HsHDR1 and HsHDR2 proteins were analyzed. The full-length cDNA of the HsHDR1 gene contained 1431 bp encoding a putative protein with 476 amino acids, whereas the HsHDR2 gene contained 1428 bp encoding a putative protein of 475 amino acids. These two proteins contained the conserved domain of 1-hydroxy-2-methyl-2-(E)-butenyl-4-diphosphate reductase (PF02401), but without the transmembrane region and signal peptide. The most abundant expression of HsHDR1 and HsHDR2 was detected in H. serrate roots, followed by the stems and leaves. Our results provide a foundation for exploring the function of HsHDR1 and HsHDR2 in terpenoid and sterol biosynthesis in Huperziaceae plants. PMID:26713274

  1. Pretreatment of lignocellulosic biomass using Fenton chemistry

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Pretreatment is a necessary step in “biomass to biofuel conversion” due to the recalcitrant nature of lignocellulosic biomass. White-rot fungi utilize peroxidases and hydrogen peroxide (in vivo Fenton chemistry) to degrade lignin. In an attempt to mimic this process, solution phase Fenton chemistry ...

  2. TREATMENT OF MTBE USING FENTON'S REAGENT

    EPA Science Inventory

    This paper addresses the removal of MTBE from water, using Fenton's Reagent. Although complete mineralization of MTBE by Fenton's Reagent was not achieved, greater than 99% destruction of MTBE was realized. This was accomplished at a Fe+2:H2O2 ratio of 1:1 and one hour of contact...

  3. Exploitation of Fenton and Fenton-like reagents as alternative conditioners for alum sludge conditioning.

    PubMed

    Tony, Maha A; Zhao, Y Q; Tayeb, Aghareed M

    2009-01-01

    The use of Fenton's reagent (Fe2+/H2O2) and Fenton-like reagents containing transition metals of Cu(II), Zn(II), Co(II), and Mn(II) for an alum sludge conditioning to improve its dewaterability was investigated. The results obtained were compared with those obtained from conditioning the same alum sludge using cationic and anionic polymers. Experimental results show that Fenton's reagent was the best among the Fenton and Fenton-like reagents for the alum sludge conditioning. A considerable effectiveness of capillary suction time (CST) reduction efficiency of 47% can be achieved under test conditions of Fe2+/H2O2 = 20/125 mg/g DS (dry solid) and pH 6.0. The observation of floc-like particles after Fenton's reagent conditioning of alum sludge suggested that the mechanism of Fenton's reagent conditioning was different from that of polymer conditioning. In spite of the lower efficiency in the CST reduction of Fenton's reagent in alum sludge conditioning compared to that of polymer conditioning, Fenton's reagent offers a more environmentally safe option. This study provided an example of proactive treatment engineering, which is aimed at seeking a safe alternative to the use of polymers in sludge conditioning towards achieving a more sustainable sludge management strategy.

  4. Evaluating HDR photos using Web 2.0 technology

    NASA Astrophysics Data System (ADS)

    Qiu, Guoping; Mei, Yujie; Duan, Jiang

    2011-01-01

    High dynamic range (HDR) photography is an emerging technology that has the potential to dramatically enhance the visual quality and realism of digital photos. One of the key technical challenges of HDR photography is displaying HDR photos on conventional devices through tone mapping or dynamic range compression. Although many different tone mapping techniques have been developed in recent years, evaluating tone mapping operators prove to be extremely difficult. Web2.0, social media and crowd-sourcing are emerging Internet technologies which can be harnessed to harvest the brain power of the mass to solve difficult problems in science, engineering and businesses. Paired comparison is used in the scientific study of preferences and attitudes and has been shown to be capable of obtaining an interval-scale ordering of items along a psychometric dimension such as preference or importance. In this paper, we exploit these technologies for evaluating HDR tone mapping algorithms. We have developed a Web2.0 style system that enables Internet users from anywhere to evaluate tone mapped HDR photos at any time. We adopt a simple paired comparison protocol, Internet users are presented a pair of tone mapped images and are simply asked to select the one that they think is better or click a "no difference" button. These user inputs are collected in the web server and analyzed by a rank aggregation algorithm which ranks the tone mapped photos according to the votes they received. We present experimental results which demonstrate that the emerging Internet technologies can be exploited as a new paradigm for evaluating HDR tone mapping algorithms. The advantages of this approach include the potential of collecting large user inputs under a variety of viewing environments rather than limited user participation under controlled laboratory environments thus enabling more robust and reliable quality assessment. We also present data analysis to correlate user generated qualitative

  5. Photo-Fenton and Fenton Oxidation of Recalcitrant Wastewater from the Wooden Floor Industry.

    PubMed

    Hansson, Henrik; Kaczala, Fabio; Marques, Marcia; Hogland, William

    2015-06-01

    There is a need for development of on-site wastewater treatment technologies suitable to "dry-process" industries, such as the wooden floor sector. Due to the nature of their activities, these industries generate low volumes of highly polluted and recalcitrant wastewaters due to washing and cleaning surfaces and machinery. Advanced oxidation processes such as Fenton and photo-Fenton are potentially feasible options for the treatment of wastewaters with not easily biodegradable pollutants. The wastewater from a wooden floor industry with initial COD value of 4956 mg/L and TOC value of 2730 mg/L was treated with Fenton (Fe/H2O2) and photo-Fenton (Fe/H2O2/UV) applying a 2-level full-factorial experimental design. The highest removals of COD and TOC (79% and 62% respectively) were achieved when photo-Fenton was applied. In conclusion, Fenton and photo-Fenton are promising treatment options for these highly recalcitrant wastewaters, photo-Fenton being a more promising option according to the results.

  6. David Keynes Hill.

    PubMed

    Huxley, Andrew

    2003-01-01

    David Hill followed his father, A.V. Hill FRS, into the study of muscular contraction. Using a wide range of experimental techniques, he made several important advances of which the most important was the discovery of the 'short-range elastic component', a phenomenon which implied that even in the resting state there was an interaction between the thick (myosin) and thin (actin) filaments. He also studied physical changes in nerve when stimulated.

  7. Virtual HDR{sup SM} CyberKnife Treatment for Localized Prostatic Carcinoma: Dosimetry Comparison With HDR Brachytherapy and Preliminary Clinical Observations

    SciTech Connect

    Fuller, Donald B. Naitoh, John; Lee, Charles; Hardy, Steven C.; Jin, Haoran

    2008-04-01

    Background: We tested our ability to approximate the dose (38 Gy), fractionation (four fractions), and distribution of high-dose-rate (HDR) brachytherapy for prostate cancer with CyberKnife (CK) stereotactic body radiotherapy (SBRT) plans. We also report early clinical observations of CK SBRT treatment. Methods and Materials: Ten patients were treated with CK. For each CK SBRT plan, an HDR plan was designed using common contour sets and simulated HDR catheters. Planning target volume coverage, intraprostatic dose escalation, and urethra, rectum, and bladder exposure were compared. Results: Planning target volume coverage by the prescription dose was similar for CK SBRT and HDR plans, whereas percent of volume of interest receiving 125% of prescribed radiation dose (V125) and V150 values were higher for HDR, reflecting higher doses near HDR source dwell positions. Urethra dose comparisons were lower for CK SBRT in 9 of 10 cases, suggesting that CK SBRT may more effectively limit urethra dose. Bladder maximum point doses were higher with HDR, but bladder dose falloff beyond the maximum dose region was more rapid with HDR. Maximum rectal wall doses were similar, but CK SBRT created sharper rectal dose falloff beyond the maximum dose region. Second CK SBRT plans, constructed by equating urethra radiation dose received by point of maximum exposure of volume of interest to the HDR plan, significantly increased V125 and V150. Clinically, 4-month post-CK SBRT median prostate-specific antigen levels decreased 86% from baseline. Acute toxicity was primarily urologic and returned to baseline by 2 months. Acute rectal morbidity was minimal and transient. Conclusions: It is possible to construct CK SBRT plans that closely recapitulate HDR dosimetry and deliver the plans noninvasively.

  8. Designs of an HDR reservoir at Clearlake, California

    SciTech Connect

    Brown, D.W.; Burns, K.L.

    1994-08-01

    The Clearlake area of California lies within the Geysers/Clearlake geothermal anomaly, a region of some 270 square miles in Sonoma and Lake Counties exhibiting elevated heat flow. The bulk of the electric power generated from geothermal resources in the United States is produced from this geothermal anomaly. However, the quantity of the Hot Dry Rock (HDR) resource within the Geysers/Clearlake geothermal anomaly is vastly larger than that of the hydrothermal resource, and could provide the basis for significant further electric power production. Of most interest from the standpoint of demonstrating the Hot Dry Rock (HDR) resource in this region is the extremely high heat flow that surrounds the City of Clearlake, as attested to by the very high temperatures measured in numerous dry (i.e., hydrothermally nonproductive) holes drilled there over the past 20 years.

  9. Vitamin D deficiency in a patient with HDR syndrome.

    PubMed

    Kostoglou-Athanassiou, Ifigenia; Stefanopoulos, Dimitrios; Karfi, Areti; Athanassiou, Panagiotis

    2015-01-01

    The case of a patient with clinical symptoms, laboratory and imaging findings of hypoparathyroidism, sensorineural deafness, renal dysplasia HDR, or Barakat syndrome (hypoparathyroidism, deafness, renal dysplasia), and vitamin D deficiency, is presented. A Caucasian man aged 51 years with a history of chronic hypocalcaemia since childhood, was admitted with hypertonia of the body and extremities, and loss of consciousness. On admission, he was found to have severe hypocalcaemia, hyperphosphataemia, severe hypoparathyroidism, low serum magnesium and mild renal insufficiency. Calcium gluconate was administered intravenously supplemented with magnesium, and the patient recovered consciousness while clinical and laboratory findings improved. Evaluation revealed left renal aplasia and sensorineural deafness affecting both ears. Vitamin D deficiency was also present. He was given calcium and vitamin D supplements orally, and the hypocalcaemia was corrected. This case is described as it is an extremely rare case of HDR syndrome with concurrent vitamin D deficiency.

  10. Cosmetic wastewater treatment using the Fenton, Photo-Fenton and H2O2/UV processes.

    PubMed

    Marcinowski, Piotr P; Bogacki, Jan P; Naumczyk, Jeremi H

    2014-01-01

    Advanced Oxidation Processes (AOPs), such as the Fenton, photo-Fenton and H2O2/UV processes, have been investigated for the treatment of cosmetic wastewaters that were previously coagulated by FeCl3. The Photo-Fenton process at pH 3.0 with 1000/100 mg L(-1) H2O2/Fe(2+) was the most effective (74.0% Chemical Oxygen Demand (COD) removal). The Fenton process with 1200/500 mg L(-1) H2O2/Fe(2+) achieved a COD removal of 72.0%, and the H2O2/UV process achieved a COD removal of 47.0%. Spreading the H2O2 doses over time to obtain optimal conditions did not improve COD removal. The kinetics of the Fenton and photo-Fenton processes may be described by the following equation: d[COD]/dt = -a[COD] t(m) (t represents time and a and m are constants). The rate of COD removal by the H2O2/UV process may be described by a second-order reaction equation. Head Space, Solid-Phase MicroExtraction, Gas Chromatography and Mass Spectrometry (HS-SPME-GC-MS) were used to identify 48 substances in precoagulated wastewater. Among these substances, 26 were fragrances. Under optimal AOP conditions, over 99% of the identified substances were removed in 120 min.

  11. WE-F-BRD-01: HDR Brachytherapy II: Integrating Imaging with HDR

    SciTech Connect

    Craciunescu, O; Todor, D; Leeuw, A de

    2014-06-15

    In recent years, with the advent of high/pulsed dose rate afterloading technology, advanced treatment planning systems, CT/MRI compatible applicators, and advanced imaging platforms, image-guided adaptive brachytherapy treatments (IGABT) have started to play an ever increasing role in modern radiation therapy. The most accurate way to approach IGABT treatment is to provide the infrastructure that combines in a single setting an appropriate imaging device, a treatment planning system, and a treatment unit. The Brachytherapy Suite is not a new concept, yet the modern suites are incorporating state-of-the-art imaging (MRI, CBCT equipped simulators, CT, and /or US) that require correct integration with each other and with the treatment planning and delivery systems. Arguably, an MRI-equipped Brachytherapy Suite is the ideal setup for real-time adaptive brachytherapy treatments. The main impediment to MRI-IGABT adoption is access to MRI scanners. Very few radiation oncology departments currently house MRI scanners, and even fewer in a dedicated Brachytherapy Suite. CBCT equipped simulators are increasingly offered by manufacturers as part of a Brachytherapy Suite installation. If optimized, images acquired can be used for treatment planning, or can be registered with other imaging modalities. This infrastructure is relevant for all forms of brachytherapy, especially those utilizing multi-fractionated courses of treatment such as prostate and cervix. Moreover, for prostate brachytherapy, US imaging systems can be part of the suite to allow for real-time HDR/LDR treatments. Learning Objectives: Understand the adaptive workflow of MR-based IGBT for cervical cancer. Familiarize with commissioning aspects of a CBCT equipped simulator with emphasis on brachytherapy applications Learn about the current status and future developments in US-based prostate brachytherapy.

  12. USE OF FENTON'S REAGENT AS A DISINFECTANT

    EPA Science Inventory

    Combined sewage samples obtained from a wastewater treatment facility were disinfected by the Fenton's Reagent of several different compositions. The pre-settled samples contained both suspended solids (SS) and dissolved organic carbon (DOC) at concentrations of 28 and 290 mg/L,...

  13. DEGRADATION OF MTBE INTERMEDIATES USING FENTON'S REAGENT

    EPA Science Inventory

    In a previous study, the chemical oxidation of MTBE at low concentrations in water using the Fenton's reagent (FR) was investigated. At certain reaction conditions the process achieved 99.99% degradation of MTBE but it did not result in complete MTBE mineralization. In the pres...

  14. INFLUENCE OF PEAT ON FENTON OXIDATION

    EPA Science Inventory

    A diagnostic probe was used to estimate the activity of Fenton-derived hydroxyl radicals (@OH), reaction kinetics, and oxidation efficiency in batch suspensions comprised of silica sand, crushed goethite ("-FeOOH) ore, peat, and H2O2 (0.13 mM). A simple method of kinetic analysi...

  15. Vital role of volume and number of needles in HDR brachytherapy (HDR-BT) of prostate cancer

    PubMed Central

    Kanikowski, Marek; Skowronek, Janusz

    2009-01-01

    Purpose The quality of HDR-BT of prostate cancer depends on operator skills, anatomy, prostate volume and relation to surrounding tissues as well as previous diseases and treatments of a patient. There is a rare data available concerning the minimum number of needles and its influence on dose distribution, side effects and long-term outcome. The study is to determine the minimal prostate volume and minimum number of needles suitable for HDR-BT in order to obtain an implant of good quality. Material and methods 181 patients with localized prostate cancer were treated with interstitial HDR-BT boost. 15 Gy from HDR-BT was administered after 50 Gy from EBRT. Clinical, volumetric and dosimetric data were collected. Treatment plans were divided into Group A, consisted of optimal treatment plans (P-D90 > 90%, P-V200 < 15%, U-D10 < 125%, U-Dmax < 160%, R-D10 < 85%) and Group B, with suboptimal plans. Results The difference between two groups was statistically significant (p = 0.013) with regard to number of needles. There was no statistically significant difference concerning prostatic volume. Median number of inserted needles in the first and the second group resulted in 15 (range 9-18) and 13 (range 8-18), respectively. Differences were the most eminent in patients with prostate glands of small volume (< 20 cc). In the study, either the minimum number of needles nor minimal prostate gland volume were not clearly defined in terms of high probability of achieving a good quality implant. Conclusions Larger volume and higher number of needles are related to an advanced probability of treatment plan with all DVC fulfilled. The minimum number of needles suggested is > 9, optimally ≥ 13. Furthermore, the minimal prostate volume recommended is > 12 cc, optimally ≥ 18 cc. The volume of insufficient size and/or small number of needles results in suboptimal treatment plans.

  16. SU-E-T-124: Dosimetric Comparison of HDR Brachytherapy and Intensity Modulated Proton Therapy

    SciTech Connect

    Wu, J; Wu, H; Das, I

    2014-06-01

    Purpose: Brachytherapy is known to be able to deliver more radiation dose to tumor while minimizing radiation dose to surrounding normal tissues. Proton therapy also provides superior dose distribution due to Bragg peak. Since both HDR and Intensity Modulated Proton Therapy (IMPT) are beneficial for their quick dose drop off, our goal in this study is to compare the pace of dose gradient drop-off between HDR and IMPT plans based on the same CT image data-set. In addition, normal tissues sparing were also compared among HDR, IMPT and SBRT. Methods: Five cervical cancer cases treated with EBRT + HDR boost combination with Tandem and Ovoid applicator were used for comparison purpose. Original HDR plans with prescribed dose of 5.5 Gy x 5 fractions were generated and optimized. The 100% isodose line of HDR plans was converted to a dose volume, and treated as CTV for IMPT and SBRT planning. The same HDR CT scans were also used for IMPT plan and SBRT plan for direct comparison. The philosophy of the IMPT and SBRT planning was to create the same CTV coverage as HDR plans. All three modalities treatment plans were compared to each other with a set of predetermined criteria. Results: With similar target volume coverage in cervix cancer boost treatment, HDR provides a slightly sharper dose drop-off from 100% to 50% isodose line, averagely in all directions compared to IMPT. However, IMPT demonstrated more dose gradient drop-off at the junction of the target and normal tissues by providing more normal tissue sparing and superior capability to reduce integral dose. Conclusion: IMPT is capable of providing comparable dose drop-off as HDR. IMPT can be explored as replacement for HDR brachytherapy in various applications.

  17. Degradation of alachlor using an enhanced sono-Fenton process with efficient Fenton's reagent dosages.

    PubMed

    Wang, Chikang; Liu, Zonghan

    2015-01-01

    In this study, an enhanced sono-Fenton process for the degradation of alachlor is presented. At high ultrasonic power, low pH, and in the presence of adequate Fenton's reagent dosages, alachlor degradation can reach nearly 100%. The toxicity of treated alachlor wastewater, which was measured by changes in cell viability, slightly decreased after the Fenton or ultrasound/H2O2 process and significantly decreased after the enhanced sono-Fenton process. A satisfactory relationship was observed between the total organic carbon removal and cell viability increment, indicating that alachlor mineralization is a key step in reducing the toxicity of the solution. The formation of alachlor degradation byproducts was observed during the oxidation process, in which the first step was the substitution of a chloride by a hydroxyl group. In conclusion, the enhanced sono-Fenton process was effective in the degradation and detoxification of alachlor within a short reaction time. Thus, the treated wastewater can then be passed through a biological treatment unit for further treatment.

  18. Realistic camera noise modeling with application to improved HDR synthesis

    NASA Astrophysics Data System (ADS)

    Goossens, Bart; Luong, Hiêp; Aelterman, Jan; Pižurica, Aleksandra; Philips, Wilfried

    2012-12-01

    Due to the ongoing miniaturization of digital camera sensors and the steady increase of the "number of megapixels", individual sensor elements of the camera become more sensitive to noise, even deteriorating the final image quality. To go around this problem, sophisticated processing algorithms in the devices, can help to maximally exploit the knowledge on the sensor characteristics (e.g., in terms of noise), and offer a better image reconstruction. Although a lot of research focuses on rather simplistic noise models, such as stationary additive white Gaussian noise, only limited attention has gone to more realistic digital camera noise models. In this article, we first present a digital camera noise model that takes several processing steps in the camera into account, such as sensor signal amplification, clipping, post-processing,.. We then apply this noise model to the reconstruction problem of high dynamic range (HDR) images from a small set of low dynamic range (LDR) exposures of a static scene. In literature, HDR reconstruction is mostly performed by computing a weighted average, in which the weights are directly related to the observer pixel intensities of the LDR image. In this work, we derive a Bayesian probabilistic formulation of a weighting function that is near-optimal in the MSE sense (or SNR sense) of the reconstructed HDR image, by assuming exponentially distributed irradiance values. We define the weighting function as the probability that the observed pixel intensity is approximately unbiased. The weighting function can be directly computed based on the noise model parameters, which gives rise to different symmetric and asymmetric shapes when electronic noise or photon noise is dominant. We also explain how to deal with the case that some of the noise model parameters are unknown and explain how the camera response function can be estimated using the presented noise model. Finally, experimental results are provided to support our findings.

  19. Use of radiochromic dosimetry film for HDR brachytherapy quality assurance.

    PubMed

    Steidley, K D

    1998-01-01

    An important quality assurance (QA) procedure in high dose rate (HDR) remote afterloading brachytherapy is the verification of the system's control of the source by a direct test with dosimetry medium prior to the patient's first treatment. In this test radiochromic film is placed in direct contact with the applicator and the patient's proposed treatment is then run with their EPROM card. Examination of the film allows a quick appraisal of step size, number of steps, and offset. Advantages of this film include self-development so the image may be viewed immediately, insensitivity to normal room light, and archivability. The cost is about U.S. $2 per clinical case.

  20. High dynamic range optical projection tomography (HDR-OPT).

    PubMed

    Fei, Peng; Yu, Zhilong; Wang, Xu; Lu, Peter J; Fu, Yusi; He, Zi; Xiong, Jingwei; Huang, Yanyi

    2012-04-01

    Traditional optical projection tomography (OPT) acquires a single image at each rotation angle, thereby suffering from limitations in CCD dynamic range; this conventional usage cannot resolve features in samples with highly heterogeneous absorption, such as in small animals with organs of varying size. We present a novel technique, applying multiple-exposure high dynamic range (HDR) imaging to OPT, and demonstrate its ability to resolve fine details in zebrafish embryos, without complicated chemical clearing. We implement the tomographic reconstruction algorithm on the GPU, yielding a performance increase of two orders of magnitude. These features give our method potential application in high-throughput, high-resolution in vivo 3D imaging.

  1. 'Scarecrow' Descends Hill

    NASA Technical Reports Server (NTRS)

    2007-01-01

    An engineering model for NASA's Mars Science Laboratory makes its way up a hill in the Mars Yard testing area at NASA's Jet Propulsion Laboratory. The model, called 'Scarecrow' because it does not include a computer brain, is used for tests of mobility and landing.

    The Mars Science Laboratory rover is in development for launch in 2009. JPL, a division of the California Institute of Technology, Pasadena, manages the mission for the NASA Science Mission Directorate, Washington.

  2. Nose Hill Artifacts

    ERIC Educational Resources Information Center

    Hansen, Vivian

    2008-01-01

    A Blackfoot woman, caught in the act of adultery, was condemned at this site to have her nose cut off as a penalty for her actions. People do not know her story. The tribe cast it on the ground. And so She, Nose Hill, was named. John Laurie Boulevard holds her mound in a circlet of asphalt, defining the map of her "terra incognita." She is a park…

  3. Hdr Imaging for Feature Detection on Detailed Architectural Scenes

    NASA Astrophysics Data System (ADS)

    Kontogianni, G.; Stathopoulou, E. K.; Georgopoulos, A.; Doulamis, A.

    2015-02-01

    3D reconstruction relies on accurate detection, extraction, description and matching of image features. This is even truer for complex architectural scenes that pose needs for 3D models of high quality, without any loss of detail in geometry or color. Illumination conditions influence the radiometric quality of images, as standard sensors cannot depict properly a wide range of intensities in the same scene. Indeed, overexposed or underexposed pixels cause irreplaceable information loss and degrade digital representation. Images taken under extreme lighting environments may be thus prohibitive for feature detection/extraction and consequently for matching and 3D reconstruction. High Dynamic Range (HDR) images could be helpful for these operators because they broaden the limits of illumination range that Standard or Low Dynamic Range (SDR/LDR) images can capture and increase in this way the amount of details contained in the image. Experimental results of this study prove this assumption as they examine state of the art feature detectors applied both on standard dynamic range and HDR images.

  4. Seismic investigations of the HDR Safety Program. Summary report

    SciTech Connect

    Malcher, L.; Schrammel, D.; Steinhilber, H.; Kot, C.A.

    1994-08-01

    The primary objective of the seismic investigations, performed at the HDR facility in Kahl/Main, FRG was to validate calculational methods for the seismic evaluation of nuclear-reactor systems, using experimental data from an actual nuclear plant. Using eccentric mass shaker excitation the HDR soil/structure system was tested to incipient failure, exhibiting highly nonlinear response and demonstrating that structures not seismically designed can sustain loads equivalent to a design basin earthquake (DBE). Load transmission from the structure to piping/equipment indicated significant response amplifications and shifts to higher frequencies, while the response of tanks/vessels depended mainly on their support conditions. The evaluation of various piping support configurations demonstrated that proper system design (for a given spectrum) rather than number of supports or system stiffness is important to limiting pipe greens. Piping at loads exceeding the DBE eightfold still had significant margins and failure is improbable inspite of multiple support failures. The mean value for pipe damping, even under extreme loads, was found to be about 4%. Comparison of linear and nonlinear computational results with piping response measurements showed that predictions have a wide scatter and do not necessarily yield conservative responses underpredicting, in particular, peak support forces. For the soil/structure system the quality of the predictions did not depend so much on the complexity of the modeling, but rather on whether the model captured the salient features and nonlinearities of the system.

  5. Fenton-like initiation of a toluene transformation mechanism

    EPA Science Inventory

    In Fenton-driven oxidation treatment systems, reaction intermediates derived from parent compounds can play a significant role in the overall treatment process. Fenton-like reactions in the presence of toluene or benzene, involved a transformation mechanism that was highly effici...

  6. WE-E-BRD-01: HDR Brachytherapy I: Overview of Clinical Application and QA

    SciTech Connect

    Libby, B; Showalter, T

    2014-06-15

    With the increased usage of high dose rate (HDR) brachytherapy and the introduction of dedicated image guided brachytherapy suites, it is necessary to review the processes and procedures associated with safely delivering these treatments in the expedited time scales that dedicated treatment suites afford. The speakers will present the clinical aspects of switching from LDR to HDR treatments, including guidelines for patient selection, and the clinical outcomes comparing LDR to HDR. The speakers will also discuss the HDR treatment process itself, because the shortened clinical timeline involved with a streamlined scan/plan/treat workflow can introduce other issues. Safety and QA aspects involved with the streamlined process, including increased personnel required for parallel tasks, and possible interfering tasks causing delays in patient treatments will also be discussed. Learning Objectives: To understand the clinical aspects of HDR Brachytherapy, including common clinical indications, patient selection, and the evolving evidence in support of this therapeutic modality To review the current prominent clinical trials for HDR brachytherapy To interpret the established guidelines for HDR brachytherapy quality assurance for implementation into practical clinical settings. To introduce the basic requirements for image guided brachytherapy.

  7. A Capitol Hill Perspective

    NASA Astrophysics Data System (ADS)

    Sheppard, Christal

    2006-04-01

    Relatively few women receive advanced degrees in the sciences, and relatively few scientists find their way into staff positions on Capitol Hill. Yet in this staffer's experience, I count more female science Ph.D.s in my circle of colleagues than I counted female classmates in physics graduate school. Why, at least anecdotally, does it seem that women with advanced degrees in science are more likely than their male peers to leave the laboratory and join the policy lobby? My observations are based on my own work in energy and environmental policy as a staffer in both the U.S. Senate and the U.S. House of Representatives.

  8. KISATCHIE HILLS WILDERNESS, LOUISIANA.

    USGS Publications Warehouse

    Haley, Boyd R.; Ryan, George S.

    1984-01-01

    A mineral-resource survey of the Kisatchie Hills Wilderness, Louisiana indicated little promise for the occurrence of mineral resources. There is insufficient data on oil and gas producing formations that underlie the area to evaluate the oil and gas resource potential. All the oil fields of Wilcox age are less than 40 acres in extent; therefore, closer spaced deeper wells might find additional fields in sediments of Wilcox age. Oil and natural gas have been produced from older reservoirs (Cretaceous age) to the northwest of the wilderness, and deeper wells might find oil and natural gas in sediments of Cretaceous and older age in the vicinity of the wilderness.

  9. Dosimetric analysis and comparison of IMRT and HDR brachytherapy in treatment of localized prostate cancer.

    PubMed

    Murali, V; Kurup, P G G; Mahadev, P; Mahalakshmi, S

    2010-04-01

    Radical radiotherapy is one of the options for the management of prostate cancer. In external beam therapy, 3D conformal radiotherapy (3DCRT) and intensity modulated radiotherapy (IMRT) are the options for delivery of increased radiation dose, as vital organs are very close to the prostate and a higher dose to these structures leads to an increased toxicity. In brachytherapy, low dose rate brachytherapy with permanent implant of radioactive seeds and high dose rate brachytherapy (HDR) with remote after loaders are available. A dosimetric analysis has been made on IMRT and HDR brachytherapy plans. Ten cases from each IMRT and HDR brachytherapy have been taken for the study. The analysis includes comparison of conformity and homogeneity indices, D100, D95, D90, D80, D50, D10 and D5 of the target. For the organs at risk (OAR), namely rectum and bladder, V100, V90 and V50 are compared. In HDR brachytherapy, the doses to 1 cc and 0.1 cc of urethra have also been studied. Since a very high dose surrounds the source, the 300% dose volumes in the target and within the catheters are also studied in two plans, to estimate the actual volume of target receiving dose over 300%. This study shows that the prescribed dose covers 93 and 92% of the target volume in IMRT and HDR brachytherapy respectively. HDR brachytherapy delivers a much lesser dose to OAR, compared to the IMRT. For rectum, the V50 in IMRT is 34.0cc whilst it is 7.5cc in HDR brachytherapy. With the graphic optimization tool in HDR brachytherapy planning, the dose to urethra could be kept within 120% of the target dose. Hence it is concluded that HDR brachytherapy may be the choice of treatment for cancer of prostate in the early stage.

  10. Spatial adaptive upsampling filter for HDR image based on multiple luminance range

    NASA Astrophysics Data System (ADS)

    Chen, Qian; Su, Guan-ming; Peng, Yin

    2014-03-01

    In this paper, we propose an adaptive upsampling filter to spatially upscale HDR image based on luminance range of the HDR picture in each color channel. It first searches for the optimal luminance range values to partition an HDR image to three different parts: dark, mid-tone and highlight. Then we derive the optimal set of filter coefficients both vertically and horizontally for each part. When the HDR pixel is within the dark area, we apply one set of filter coefficients to vertically upsample the pixel. If the HDR pixel falls in mid-tone area, we apply another set of filter for vertical upsampling. Otherwise the HDR pixel is in highlight area, another set of filter will be applied for vertical upsampling. Horizontal upsampling will be carried out likewise based on its luminance. The inherent idea to partition HDR image to different luminance areas is based on the fact that most HDR images are created from multiple exposures. Different exposures usually demonstrate slight variation in captured signal statistics, such as noise level, subtle misalignment etc. Hence, to group different regions to three luminance partitions actually helps to eliminate the variation between signals, and to derive optimal filter for each group with signals of lesser variation is certainly more efficient than for the entire HDR image. Experimental results show that the proposed adaptive upsampling filter based on luminance ranges outperforms the optimal upsampling filter around 0.57dB for R channel, 0.44dB for G channel and 0.31dB for B channel.

  11. Dosimetric analysis and comparison of IMRT and HDR brachytherapy in treatment of localized prostate cancer

    PubMed Central

    Murali, V.; Kurup, P. G. G.; Mahadev, P.; Mahalakshmi, S.

    2010-01-01

    Radical radiotherapy is one of the options for the management of prostate cancer. In external beam therapy, 3D conformal radiotherapy (3DCRT) and intensity modulated radiotherapy (IMRT) are the options for delivery of increased radiation dose, as vital organs are very close to the prostate and a higher dose to these structures leads to an increased toxicity. In brachytherapy, low dose rate brachytherapy with permanent implant of radioactive seeds and high dose rate brachytherapy (HDR) with remote after loaders are available. A dosimetric analysis has been made on IMRT and HDR brachytherapy plans. Ten cases from each IMRT and HDR brachytherapy have been taken for the study. The analysis includes comparison of conformity and homogeneity indices, D100, D95, D90, D80, D50, D10 and D5 of the target. For the organs at risk (OAR), namely rectum and bladder, V100, V90 and V50 are compared. In HDR brachytherapy, the doses to 1 cc and 0.1 cc of urethra have also been studied. Since a very high dose surrounds the source, the 300% dose volumes in the target and within the catheters are also studied in two plans, to estimate the actual volume of target receiving dose over 300%. This study shows that the prescribed dose covers 93 and 92% of the target volume in IMRT and HDR brachytherapy respectively. HDR brachytherapy delivers a much lesser dose to OAR, compared to the IMRT. For rectum, the V50 in IMRT is 34.0cc whilst it is 7.5cc in HDR brachytherapy. With the graphic optimization tool in HDR brachytherapy planning, the dose to urethra could be kept within 120% of the target dose. Hence it is concluded that HDR brachytherapy may be the choice of treatment for cancer of prostate in the early stage. PMID:20589121

  12. Mineralization of sulfamethizole in photo-Fenton and photo-Fenton-like systems.

    PubMed

    Wu, C H; Wu, J T; Lin, Y H

    2016-01-01

    In this investigation, UV/H2O2, UV/H2O2/Fe(2+) (photo-Fenton) and UV/H2O2/Fe(3+) (photo-Fenton-like) systems were used to mineralize sulfamethizole (SFZ). The optimal doses of H2O2 (1-20 mM) in UV/H2O2 and iron (0.1-1 mM) in photo-Fenton and photo-Fenton-like systems were determined. Direct photolysis by UV irradiation and direct oxidation by added H2O2, Fe(2+) and Fe(3+) did not mineralize SFZ. The optimal dose of H2O2 was 10 mM in UV/H2O2 and that of iron (Fe(2+) or Fe(3+)) was 0.2 mM in both UV/H2O2/Fe(2+) and UV/H2O2/Fe(3+) systems. Under the best experimental conditions and after 60 min of reaction, the SFZ mineralization percentages in UV/H2O2, UV/H2O2/Fe(2+) and UV/H2O2/Fe(3+) systems were 16, 90 and 88%, respectively. The UV/H2O2/Fe(2+) and UV/H2O2/Fe(3+) systems effectively mineralized SFZ. PMID:26901716

  13. Mineralization of sulfamethizole in photo-Fenton and photo-Fenton-like systems.

    PubMed

    Wu, C H; Wu, J T; Lin, Y H

    2016-01-01

    In this investigation, UV/H2O2, UV/H2O2/Fe(2+) (photo-Fenton) and UV/H2O2/Fe(3+) (photo-Fenton-like) systems were used to mineralize sulfamethizole (SFZ). The optimal doses of H2O2 (1-20 mM) in UV/H2O2 and iron (0.1-1 mM) in photo-Fenton and photo-Fenton-like systems were determined. Direct photolysis by UV irradiation and direct oxidation by added H2O2, Fe(2+) and Fe(3+) did not mineralize SFZ. The optimal dose of H2O2 was 10 mM in UV/H2O2 and that of iron (Fe(2+) or Fe(3+)) was 0.2 mM in both UV/H2O2/Fe(2+) and UV/H2O2/Fe(3+) systems. Under the best experimental conditions and after 60 min of reaction, the SFZ mineralization percentages in UV/H2O2, UV/H2O2/Fe(2+) and UV/H2O2/Fe(3+) systems were 16, 90 and 88%, respectively. The UV/H2O2/Fe(2+) and UV/H2O2/Fe(3+) systems effectively mineralized SFZ.

  14. Chemical analysis and sampling techniques for geothermal fluids and gases at the Fenton Hill Laboratory

    SciTech Connect

    Trujillo, P.E.; Counce, D.; Grigsby, C.O.; Goff, F.; Shevenell, L.

    1987-06-01

    A general description of methods, techniques, and apparatus used for the sampling, chemical analysis, and data reporting of geothermal gases and fluids is given. Step-by-step descriptions of the procedures are included in the appendixes.

  15. Subsurface Geology of the Fenton Hill Hot Dry Rock Geothermal Energy Site

    SciTech Connect

    Levey, Schon S.

    2010-12-01

    The Precambrian rock penetrated by wells EE-2A and -3A belongs to one or more granitic to granodioritic plutons. The plutonic rock contains two major xenolith zones of amphibolite, locally surrounded by fine-grained mafic rock of hybrid igneous origin. The granodiorite is cut by numerous leucogranite dikes that diminish in abundance with depth. The most prominent structural feature is the main breccia zone, in which the rock is highly fractured and moderately altered. This zone is at least 75 m thick and is of uncertain but near-horizontal orientation. Fracture abundance decreases with increasing depth below the main breccia zone, and fractures tend to be associated with leucogranite dikes. This association suggests that at least some of the fractures making up the geothermal reservoir are of Precambrian age or have long-range orientations controlled by the presence of Precambrian-age granitic dikes.

  16. One month circulation test at the Hijiori HDR test site in 1996

    SciTech Connect

    Sato, Yoshiteru; Matsunaga, Isao; Nagai, Masahiro

    1996-12-31

    As shown in Table 1, four wells have been used for circulation tests at Hijiori. The diameters of all the open-hole sections of the wells are 8-{1/2} inches. SKG-2 is an injection well. An 1800 m deep reservoir was stimulated hydraulically by water injection into the open-hole section of SKG-2 in 1986. HDR-1 is also an injection well. A 2200 m deep reservoir was stimulated by water injection into the open-hole section of HDR-1 in 1992. HDR-2a and HDR-3 are used to produce steam and hot water from both reservoirs. The subsurface system was created In granodiorite basement rock with temperatures of 250 {degrees}C at a depth of 2,500 m and 270{degrees} C at depth of 2,700 m.

  17. Lost Hills, California Interferogram

    NASA Technical Reports Server (NTRS)

    2001-01-01

    This figure shows a comparison of interferograms from four different years mapping the rapid ground subsidence over the Lost Hills oil field in California. Lost Hills is located about 60 km (40 miles) northwest of Bakersfield in the San Joaquin Valley. The oil field is about 1.5 km (1mile) wide and 6 km (3.5 miles) long.

    Each interferogram was created using pairs of images taken by synthetic aperture radar that have been combined to measure surface deformation or changes that may have occurred in the time between when data for the two images were taken. The images were collected by the European Space Agency's Remote Sensing satellites (ERS-1 and ERS-2) in two months of each year shown (1995, 1996, 1998 and 1999) and were combined to produce these image maps of the apparent surface deformation, or changes.

    The interferometric measurements that show the changes, primarily vertical subsidence of the surface, are rendered in color with purple indicating no motion and the brightest red showing rapid subsidence. The white areas are where the radar measurements could not be obtained, mostly in the agricultural fields around the oil fields where plant growth or plowing altered the radar properties of the surface.

    These radar data show that parts of the oil field were subsiding unusually rapidly, more than 3 centimeters (1.2 inches) a month, in 1995 and 1996. They also reveal that while the ground subsidence rate decreased in the center part of the oil field, it increased in the northern part between 1995 and 1996 and 1998 and 1999.

    Subsidence maps like these combined with records of oil and water extraction and injection will help scientist understand how the rocks within an oil field are behaving, leading to improvements in oil field operations.

  18. Lost Hills, California Interferogram

    NASA Technical Reports Server (NTRS)

    2002-01-01

    This figure shows a comparison of interferograms from four different years mapping the rapid ground subsidence over the Lost Hills oil field in California. Lost Hills is located about 60 km (40 miles) northwest of Bakersfield in the San Joaquin Valley. The oilfield is about 1.5 km (1 mile) wide and 6 km (3.5 miles) long. Each interferogram was created using pairs of images taken by synthetic aperture radar that have been combined to measure surface deformation or changes that may have occurred in the time between when data for the two images were taken. The images were collected by the European Space Agency's Remote Sensing satellites (ERS-1 and ERS-2) in two months of each year shown (1995, 1996, 1998 and 1999) and were combined to produce these image maps of the apparent surface deformation, or changes. The interferometric measurements that show the changes, primarily vertical subsidence of the surface, are rendered in color with purple indicating no motion and the brightest red showing rapid subsidence. The white areas are where the radar measurements could not be obtained, mostly in the agricultural fields around the oilfields where plant growth or plowing altered the radar properties of the surface. These radar data show that parts of the oilfield were subsiding unusually rapidly, more than 3 centimenters (1.2 inches) a month, in 1995 and 1996. They also reveal that while the ground subsidence rate decreased in the center part of the oilfield, it increased in the northern part between 1995 and 1996 and 1998 and 1999. Subsidence maps like these combined with records of oil and water extraction and injection will help scientist understand how the rocks within an oilfield are behaving, leading to improvements in oilfield operations. For more information, read Radar Helps Monitor Oil Fields. Images courtesy Eric Fielding, NASA Jet Propulsion Laboratory

  19. Clinical application of radiophotoluminescent glass dosimeter for dose verification of prostate HDR procedure

    SciTech Connect

    Hsu, Shih-Ming; Yeh, Chien-Yi; Yeh, Tien-Chi; Hong, Ji-Hong; Tipton, Annie Y. H.; Chen, Wei-Li; Sun, Shung-Shung; Huang, David Y. C.

    2008-12-15

    High dose rate brachytherapy (HDR-BT) is one of the many modalities for prostate cancer treatment. Due to the nature of HDR-BT, in vivo dosimetry is feasible and can be used to verify consistent dose delivery. In order to validate a dose verification system for HDR-BT prostate cancer treatment, a radiophotoluminescent glass dosimeter (RPLGD) was used and the measurements were compared with those from a thermoluminescent dosimeter. The RPLGD shows many advantages in HDR-BT dose measurement, such as repeatability, stability, and small effective size. These advantages make the RPLGD a superior option for use as a dosimeter in HDR-BT. The results described here show that the difference between the measured dose and the treatment planned dose is less than 5%. A Monte Carlo simulation for the dose was performed using Monte Carlo N -particle to investigate position error. This study concludes that the RPLGD is a promising and reliable dosimeter for HDR-BT in vivo dosimetry with clinically acceptable accuracy.

  20. 16. Interior view of Cherry Hill lettuce shed looking up ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    16. Interior view of Cherry Hill lettuce shed looking up at the trusses of the second floor - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  1. 6. Oblique view of Cherry Hill lettuce shed looking northeast, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Oblique view of Cherry Hill lettuce shed looking northeast, with chute building to the right - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  2. 22. View of second floor of the Cherry Hill lettuce ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    22. View of second floor of the Cherry Hill lettuce shed looking at double doors - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  3. 21. View of second floor of the Cherry Hill lettuce ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    21. View of second floor of the Cherry Hill lettuce shed looking towards window - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  4. 18. View of the second floor of the Cherry Hill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    18. View of the second floor of the Cherry Hill lettuce shed looking at door - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  5. 9. View of Cherry Hill lettuce shed looking north, with ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. View of Cherry Hill lettuce shed looking north, with chute building on the left - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  6. 3. View of Cherry Hill lettuce shed looking southeast; parking ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. View of Cherry Hill lettuce shed looking southeast; parking lot in foreground - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  7. 12. Partial view of Cherry Hill lettuce shed looking northwest ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    12. Partial view of Cherry Hill lettuce shed looking northwest showing office - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  8. 20. View of second floor to the Cherry Hill lettuce ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    20. View of second floor to the Cherry Hill lettuce shed looking at floor area - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  9. 15. Interior view of Cherry Hill lettuce shed showing posts ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    15. Interior view of Cherry Hill lettuce shed showing posts looking towards the chute building - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  10. 14. Interior view of Cherry Hill lettuce shed looking towards ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. Interior view of Cherry Hill lettuce shed looking towards chute building - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  11. 19. View of second floor of the Cherry Hill lettuce ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    19. View of second floor of the Cherry Hill lettuce shed looking at door to stairwell - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  12. 2. Oblique view of Cherry Hill lettuce shed looking south; ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Oblique view of Cherry Hill lettuce shed looking south; chute building is in background - Richmond Hill Plantation, Cherry Hill Lettuce Shed, East of Richmond Hill on Ford Neck Road, Richmond Hill, Bryan County, GA

  13. Removal of NOM from drinking water: Fenton's and photo-Fenton's processes.

    PubMed

    Murray, Christine A; Parsons, Simon A

    2004-02-01

    The control of disinfection by-products during water treatment is primarily undertaken by reducing the levels of precursor species prior to chlorination. As many waters contain natural organic matter at levels of up to 15 mgl(-1) there is a need for a range of control methods to support conventional coagulation. Two such processes are the Fenton and photo-Fenton's processes and in this paper they are assessed for their potential to remove NOM from organic rich waters. The performance of both processes is shown to be depentent on pH, Fe: H2O2 ratio as well as Fe2+ dose. Under optimum conditions both processes achieved greater than 90% removal of DOC and UV254 absorbance. This removal lead to the trihalomethane formation potential of the water being reduced from 140 to below 10 microgl(-1), well below UK and US standards.

  14. Progress in making hot dry rock geothermal energy a viable renewable energy resource for America in the 21. century

    SciTech Connect

    Duchane, D.V.

    1996-01-01

    An enormous geothermal energy resource exists in the form of rock at depth that is hot but essentially dry. For more than two decades, work has been underway at the Los Alamos National Laboratory to develop and demonstrate the technology to transport the energy in hot dry rock (HDR) to the surface for practical use. During the 1980`s, the world`s largest, deepest and hottest HDR reservoir was created at the Fenton Hill HDR test facility in northern New Mexico. The reservoir is centered in rock at a temperature of about 460 F at a depth of about 11,400 ft. After mating the reservoir to a fully automated surface plant, heat was mined at Fenton Hill for a total period of almost a year in a series of flow tests conducted between 1992 and 1995. These tests addressed the major questions regarding the viability of long-term energy extraction from HDR. The steady-state flow tests at Fenton Hill showed that energy can be produced from an HDR reservoir on a routine basis and that there are no major technical obstacles to implementation of this heat mining technology. Additional brief special flow tests also demonstrated that the energy output from HDR systems can be rapidly increased in a controlled manner to meet sudden changes in power demand.

  15. FENTON-DRIVEN CHEMICAL REGENERATION OF MTBE-SPENT GAC

    EPA Science Inventory

    Methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC) was chemically regenerated utilizing the Fenton mechanism. Two successive GAC regeneration cycles were performed involving iterative adsorption and oxidation processes: MTBE was adsorbed to the GAC, oxidized, r...

  16. Drinking water and biofilm disinfection by Fenton-like reaction.

    PubMed

    Gosselin, F; Madeira, L M; Juhna, T; Block, J C

    2013-10-01

    A Fenton-like disinfection process was conducted with Fenton's reagent (H2O2) at pH 3 or 5 on autochthonous drinking water biofilms grown on corroded or non-corroded pipe material. The biofilm disinfection by Fenton-like oxidation was limited by the low content of iron and copper in the biomass grown on non-corroded plumbing. It was slightly improved by spiking the distribution system with some additional iron source (soluble iron II or ferrihydrite particles appeared as interesting candidates). However successful in situ disinfection of biofilms was only achieved in fully corroded cast iron pipes using H2O2 and adjusting the pH to 5. These new results provide additional support for the use of Fenton's processes for cleaning drinking water distribution systems contaminated with biological agents or organics.

  17. Antigravity hills are visual illusions.

    PubMed

    Bressan, Paola; Garlaschelli, Luigi; Barracano, Monica

    2003-09-01

    Antigravity hills, also known as spook hills or magnetic hills, are natural places where cars put into neutral are seen to move uphill on a slightly sloping road, apparently defying the law of gravity. We show that these effects, popularly attributed to gravitational anomalies, are in fact visual illusions. We re-created all the known types of antigravity spots in our laboratory using tabletop models; the number of visible stretches of road, their slant, and the height of the visible horizon were systematically varied in four experiments. We conclude that antigravity-hill effects follow from a misperception of the eye level relative to gravity, caused by the presence of either contextual inclines or a false horizon line.

  18. Combined photo-Fenton-SBR process for antibiotic wastewater treatment.

    PubMed

    Elmolla, Emad S; Chaudhuri, Malay

    2011-09-15

    The study examined combined photo-Fenton-SBR treatment of an antibiotic wastewater containing amoxicillin and cloxacillin. Optimum H(2)O(2)/COD and H(2)O(2)/Fe(2+) molar ratio of the photo-Fenton pretreatment were observed to be 2.5 and 20, respectively. Complete degradation of the antibiotics occurred in one min. The sequencing batch reactor (SBR) was operated at different hydraulic retention times (HRTs) with the wastewater treated under different photo-Fenton operating conditions (H(2)O(2)/COD and H(2)O(2)/Fe(2+) molar ratio). The SBR performance was found to be very sensitive to BOD(5)/COD ratio of the photo-Fenton treated wastewater. Statistical analysis of the results indicated that it was possible to reduce the Fe(2+) dose and increase the irradiation time of the photo-Fenton pretreatment. The best operating conditions of the combined photo-Fenton-SBR treatment were observed to be H(2)O(2)/COD molar ratio 2, H(2)O(2)/Fe(2+) molar ratio 150, irradiation time 90 min and HRT of 12h. Under the best operating conditions, 89% removal of sCOD with complete nitrification was achieved and the SBR effluent met the discharge standards. PMID:21767911

  19. Source geometry factors for HDR 192Ir brachytherapy secondary standard well-type ionization chamber calibrations

    NASA Astrophysics Data System (ADS)

    Shipley, D. R.; Sander, T.; Nutbrown, R. F.

    2015-03-01

    Well-type ionization chambers are used for measuring the source strength of radioactive brachytherapy sources before clinical use. Initially, the well chambers are calibrated against a suitable national standard. For high dose rate (HDR) 192Ir, this calibration is usually a two-step process. Firstly, the calibration source is traceably calibrated against an air kerma primary standard in terms of either reference air kerma rate or air kerma strength. The calibrated 192Ir source is then used to calibrate the secondary standard well-type ionization chamber. Calibration laboratories are usually only equipped with one type of HDR 192Ir source. If the clinical source type is different from that used for the calibration of the well chamber at the standards laboratory, a source geometry factor, ksg, is required to correct the calibration coefficient for any change of the well chamber response due to geometric differences between the sources. In this work we present source geometry factors for six different HDR 192Ir brachytherapy sources which have been determined using Monte Carlo techniques for a specific ionization chamber, the Standard Imaging HDR 1000 Plus well chamber with a type 70010 HDR iridium source holder. The calculated correction factors were normalized to the old and new type of calibration source used at the National Physical Laboratory. With the old Nucletron microSelectron-v1 (classic) HDR 192Ir calibration source, ksg was found to be in the range 0.983 to 0.999 and with the new Isodose Control HDR 192Ir Flexisource ksg was found to be in the range 0.987 to 1.004 with a relative uncertainty of 0.4% (k = 2). Source geometry factors for different combinations of calibration sources, clinical sources, well chambers and associated source holders, can be calculated with the formalism discussed in this paper.

  20. Pretreatment of furfural industrial wastewater by Fenton, electro-Fenton and Fe(II)-activated peroxydisulfate processes: a comparative study.

    PubMed

    Yang, C W; Wang, D; Tang, Q

    2014-01-01

    The Fenton, electro-Fenton and Fe(II)-activated peroxydisulfate (PDS) processes have been applied for the treatment of actual furfural industrial wastewater in this paper. Through the comparative study of the three processes, a suitable pretreatment technology for actual furfural wastewater treatment was obtained, and the mechanism and dynamics process of this technology is discussed. The experimental results show that Fenton technology has a good and stable effect without adjusting pH of furfural wastewater. At optimal conditions, which were 40 mmol/L H₂O₂ initial concentration and 10 mmol/L Fe²⁺ initial concentration, the chemical oxygen demand (COD) removal rate can reach 81.2% after 90 min reaction at 80 °C temperature. The PDS process also has a good performance. The COD removal rate could attain 80.3% when Na₂S₂O₈ initial concentration was 4.2 mmol/L, Fe²⁺ initial concentration was 0.1 mol/L, the temperature remained at 70 °C, and pH value remained at 2.0. The electro-Fenton process was not competent to deal with the high-temperature furfural industrial wastewater and only 10.2% COD was degraded at 80 °C temperature in the optimal conditions (2.25 mA/cm² current density, 4 mg/L Na₂SO₄, 0.3 m³/h aeration rate). For the Fenton, electro-Fenton and PDS processes in pretreatment of furfural wastewater, their kinetic processes follow the pseudo first order kinetics law. The pretreatment pathways of furfural wastewater degradation are also investigated in this study. The results show that furfural and furan formic acid in furfural wastewater were preferentially degraded by Fenton technology. Furfural can be degraded into low-toxicity or nontoxic compounds by Fenton pretreatment technology, which could make furfural wastewater harmless and even reusable.

  1. Mature landfill leachate treatment by coagulation/flocculation combined with Fenton and solar photo-Fenton processes.

    PubMed

    Amor, Carlos; De Torres-Socías, Estefanía; Peres, José A; Maldonado, Manuel I; Oller, Isabel; Malato, Sixto; Lucas, Marco S

    2015-04-01

    This work reports the treatment of a mature landfill leachate through the application of chemical-based treatment processes in order to achieve the discharge legal limits into natural water courses. Firstly, the effect of coagulation/flocculation with different chemicals was studied, evaluating the role of different initial pH and chemicals concentration. Afterwards, the efficiency of two different advanced oxidation processes for leachate remediation was assessed. Fenton and solar photo-Fenton processes were applied alone and in combination with a coagulation/flocculation pre-treatment. This physicochemical conditioning step, with 2 g L(-1) of FeCl3 · 6H2O at pH 5, allowed removing 63% of COD, 80% of turbidity and 74% of total polyphenols. Combining the coagulation/flocculation pre-treatment with Fenton reagent, it was possible to reach 89% of COD removal in 96 h. Moreover, coagulation/flocculation combined with solar photo-Fenton revealed higher DOC (75%) reductions than single solar photo-Fenton (54%). In the combined treatment (coagulation/flocculation and solar photo-Fenton), it was reached a DOC reduction of 50% after the chemical oxidation, with 110 kJ L(-1) of accumulated UV energy and a H2O2 consumption of 116 mM. Toxicity and biodegradability assays were performed to evaluate possible variations along the oxidation processes. After the combined treatment, the leachate under study presented non-toxicity but biodegradability increased.

  2. Crowdsourcing-based evaluation of privacy in HDR images

    NASA Astrophysics Data System (ADS)

    Korshunov, Pavel; Nemoto, Hiromi; Skodras, Athanassios; Ebrahimi, Touradj

    2014-05-01

    The ability of High Dynamic Range imaging (HDRi) to capture details in high-contrast environments, making both dark and bright regions clearly visible, has a strong implication on privacy. However, the extent to which HDRi affects privacy when it is used instead of typical Standard Dynamic Range imaging (SDRi) is not yet clear. In this paper, we investigate the effect of HDRi on privacy via crowdsourcing evaluation using the Microworkers platform. Due to the lack of HDRi standard privacy evaluation dataset, we have created such dataset containing people of varying gender, race, and age, shot indoor and outdoor and under large range of lighting conditions. We evaluate the tone-mapped versions of these images, obtained by several representative tone-mapping algorithms, using subjective privacy evaluation methodology. Evaluation was performed using crowdsourcing-based framework, because it is a popular and effective alternative to traditional lab-based assessment. The results of the experiments demonstrate a significant loss of privacy when even tone-mapped versions of HDR images are used compared to typical SDR images shot with a standard exposure.

  3. FENTON-DRIVEN REGENERATION OF GRANULAR ACTIVATED CARBON: A TECHNOLOGY OVERVIEW

    EPA Science Inventory

    A Fenton-driven mechanism for regenerating spent granular activated carbon (GAC) involves the combined, synergistic use of two reliable and well established treatment technologies - adsorption onto activated carbon and Fenton oxidation. During carbon adsorption treatment, enviro...

  4. BrachyView, a novel in-body imaging system for HDR prostate brachytherapy: Experimental evaluation

    SciTech Connect

    Safavi-Naeini, M.; Han, Z.; Alnaghy, S.; Cutajar, D.; Petasecca, M.; Lerch, M. L. F.; Rosenfeld, A. B.; Franklin, D. R.; Bucci, J.; Carrara, M.; Zaider, M.

    2015-12-15

    Purpose: This paper presents initial experimental results from a prototype of high dose rate (HDR) BrachyView, a novel in-body source tracking system for HDR brachytherapy based on a multipinhole tungsten collimator and a high resolution pixellated silicon detector array. The probe and its associated position estimation algorithms are validated and a comprehensive evaluation of the accuracy of its position estimation capabilities is presented. Methods: The HDR brachytherapy source is moved through a sequence of positions in a prostate phantom, for various displacements in x, y, and z. For each position, multiple image acquisitions are performed, and source positions are reconstructed. Error estimates in each dimension are calculated at each source position and combined to calculate overall positioning errors. Gafchromic film is used to validate the accuracy of source placement within the phantom. Results: More than 90% of evaluated source positions were estimated with an error of less than one millimeter, with the worst-case error being 1.3 mm. Experimental results were in close agreement with previously published Monte Carlo simulation results. Conclusions: The prototype of HDR BrachyView demonstrates a satisfactory level of accuracy in its source position estimation, and additional improvements are achievable with further refinement of HDR BrachyView’s image processing algorithms.

  5. Soufriere Hills Volcano

    NASA Technical Reports Server (NTRS)

    2002-01-01

    In this ASTER image of Soufriere Hills Volcano on Montserrat in the Caribbean, continued eruptive activity is evident by the extensive smoke and ash plume streaming towards the west-southwest. Significant eruptive activity began in 1995, forcing the authorities to evacuate more than 7,000 of the island's original population of 11,000. The primary risk now is to the northern part of the island and to the airport. Small rockfalls and pyroclastic flows (ash, rock and hot gases) are common at this time due to continued growth of the dome at the volcano's summit.

    This image was acquired on October 29, 2002 by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) on NASA's Terra satellite. With its 14 spectral bands from the visible to the thermal infrared wavelength region, and its high spatial resolution of 15 to 90 meters (about 50 to 300 feet), ASTER images Earth to map and monitor the changing surface of our planet.

    ASTER is one of five Earth-observing instruments launched December 18, 1999, on NASA's Terra satellite. The instrument was built by Japan's Ministry of Economy, Trade and Industry. A joint U.S./Japan science team is responsible for validation and calibration of the instrument and the data products.

    The broad spectral coverage and high spectral resolution of ASTER will provide scientists in numerous disciplines with critical information for surface mapping, and monitoring of dynamic conditions and temporal change. Example applications are: monitoring glacial advances and retreats; monitoring potentially active volcanoes; identifying crop stress; determining cloud morphology and physical properties; wetlands evaluation; thermal pollution monitoring; coral reef degradation; surface temperature mapping of soils and geology; and measuring surface heat balance.

    Dr. Anne Kahle at NASA's Jet Propulsion Laboratory, Pasadena, California, is the U.S. Science team leader; Bjorn Eng of JPL is the project manager. The Terra mission is

  6. Mineralization of flumequine in acidic medium by electro-Fenton and photoelectro-Fenton processes.

    PubMed

    Garcia-Segura, Sergi; Garrido, José A; Rodríguez, Rosa M; Cabot, Pere L; Centellas, Francesc; Arias, Conchita; Brillas, Enric

    2012-05-01

    The mineralization of flumequine, an antimicrobial agent belonging to the first generation of synthetic fluoroquinolones which is detected in natural waters, has been studied by electrochemical advanced oxidation processes (EAOPs) like electro-Fenton (EF) and photoelectro-Fenton (PEF) with UVA light. The experiments were performed in a cell containing a boron-doped diamond (BDD) anode and an air-diffusion cathode to generate H(2)O(2) at constant current. The Fe(2+) ion added to the medium increased the solubility of the drug by the formation of a complex of intense orange colour and also reacted with electrogenerated H(2)O(2) to form hydroxyl radical from Fenton reaction. Oxidant hydroxyl radicals at the BDD surface were produced from water oxidation. A partial mineralization of flumequine in a solution near to saturation with optimum 2.0mM Fe(2+) at pH 3.0 was achieved by EF. The PEF process was more powerful, giving an almost total mineralization with 94-96% total organic carbon removal. Increasing current accelerated both treatments, but with decreasing mineralization current efficiency. Comparative treatments using a real wastewater matrix led to similar degradation degrees. The kinetics for flumequine decay always followed a pseudo-first-order reaction and its rate constant, similar for both EAOPs, raised with increasing current. Generated carboxylic acids like malonic, formic, oxalic and oxamic acids were quantified by ion-exclusion HPLC. Fe(III)-oxalate and Fe(III)-oxamate complexes were the most persistent by-products under EF conditions and their quicker photolysis by UVA light explains the higher oxidation power of PEF. The release of inorganic ions such as F(-), NO(3)(-) and in lesser extent NH(4)(+) was followed by ionic chromatography. PMID:22348999

  7. Error Analysis of non-TLD HDR Brachytherapy Dosimetric Techniques

    NASA Astrophysics Data System (ADS)

    Amoush, Ahmad

    The American Association of Physicists in Medicine Task Group Report43 (AAPM-TG43) and its updated version TG-43U1 rely on the LiF TLD detector to determine the experimental absolute dose rate for brachytherapy. The recommended uncertainty estimates associated with TLD experimental dosimetry include 5% for statistical errors (Type A) and 7% for systematic errors (Type B). TG-43U1 protocol does not include recommendation for other experimental dosimetric techniques to calculate the absolute dose for brachytherapy. This research used two independent experimental methods and Monte Carlo simulations to investigate and analyze uncertainties and errors associated with absolute dosimetry of HDR brachytherapy for a Tandem applicator. An A16 MicroChamber* and one dose MOSFET detectors† were selected to meet the TG-43U1 recommendations for experimental dosimetry. Statistical and systematic uncertainty analyses associated with each experimental technique were analyzed quantitatively using MCNPX 2.6‡ to evaluate source positional error, Tandem positional error, the source spectrum, phantom size effect, reproducibility, temperature and pressure effects, volume averaging, stem and wall effects, and Tandem effect. Absolute dose calculations for clinical use are based on Treatment Planning System (TPS) with no corrections for the above uncertainties. Absolute dose and uncertainties along the transverse plane were predicted for the A16 microchamber. The generated overall uncertainties are 22%, 17%, 15%, 15%, 16%, 17%, and 19% at 1cm, 2cm, 3cm, 4cm, and 5cm, respectively. Predicting the dose beyond 5cm is complicated due to low signal-to-noise ratio, cable effect, and stem effect for the A16 microchamber. Since dose beyond 5cm adds no clinical information, it has been ignored in this study. The absolute dose was predicted for the MOSFET detector from 1cm to 7cm along the transverse plane. The generated overall uncertainties are 23%, 11%, 8%, 7%, 7%, 9%, and 8% at 1cm, 2cm, 3cm

  8. SU-D-19A-07: Dosimetric Comparison of HDR Plesiotherapy and Electron Beam Therapy for Superficial Lesions

    SciTech Connect

    Mitchell, A; Jacob, D; Andreou, K; Raben, A; Chen, H; Koprowski, C; Mourtada, F

    2014-06-01

    Purpose: Large superficial (skin, soft tissue sarcoma) lesions located on curved areas are hard to treat with electrons. The Freiburg Flap (Nucletron, Netherlands) is a flexible mesh style surface which can be easily shaped to fit curved surfaces for reproducible HDR fraction delivery. To understand the fundamental dosimetric differences, a dosimetric comparison was made between HDR plesiotherapy (Freiburg applicator for lesions over 4cm) and external electron beam radiotherapy over cases with varying target curvature (both stylized and clinical cases). Methods: Four stylized cases with variable complexity were created using artificial DICOM axial CT slices and RT structures (a square and three curved structures on a 4.5cm radius cylinder). They were planned using Oncentra v4.3 and exported to Pinnacle v9.6 for electrons planning. The HDR source dwell positions were optimized for the best coverage of the targets using graphical optimization. Electron treatment plans were created in Pinnacle using the same CT and RT structures of three HDR cases with surface lesions previously treated with the Freiburg flap. The En face electron plans used 6-12 MeV electrons and 0.5–1 cm bolus was added to increase surface dose. The electron plans were prescribed to an isodose line to conform to the target. Results: For all lesions, the average target dose coverage was similar (D90ave of 100% for HDR vs 101% for electrons). For lesions with high curvature, the HDR coverage was better (D90 102% vs D90 97% for electron). For all cases, adjacent structures high dose region was lower for HDR than electrons (D1cc 100% for HDR vs D1cc 111% for electrons). Conclusion: HDR plesiotherapy offers excellent target conformity for superficial targets similar to electrons. However, for lesions with complex curved surfaces, HDR has the advantage to achieve better dose distributions using graphical optimization to spare adjacent normal tissue while maximizing target coverage.

  9. Trans-Pacific HDR Satellite Communications Experiment Phase-2 Project Plan and Experimental Network

    NASA Technical Reports Server (NTRS)

    Hsu, Eddie; Kadowaki, Naoto; Yoshimura, Naoko; Takahashi, Takashi; Yoshikawa, Makoto; Bergman, Larry; Bhasin, Kul

    2000-01-01

    The trans-Pacific high data rate (TP-HDR) satellite communications experiment was proposed at the Japan-U.S. Cooperation in Space (JUCS) Program Workshop held in Hawaii in 1993 and remote high definition video post-production was demonstrated as the first phase trial. ATM-based 45 Mbps trans-Pacific link was established in the first phase, and the following experiments with 155 Mbps was planned as the phase 2. This paper describes the experimental network configuration and project plan of TP-HDR experiment phase 2. Additional information is provided in the original.

  10. The First Turkish Case of Hypoparathyroidism, Deafness and Renal Dysplasia (HDR) Syndrome.

    PubMed

    Döneray, Hakan; Usui, Takeshi; Kaya, Avni; Dönmez, Ayşe Sena

    2015-06-01

    Hypoparathyroidism, deafness and renal dysplasia (HDR) syndrome is an autosomal dominant genetic disorder characterized by hypoparathyroidism, sensorineural deafness and renal dysplasia. We herein present the first Turkish patient with HDR syndrome, who has a p.R367X mutation. This report indicates that p.R367X is not a mutation specific for the Far Eastern populations and also that urological findings in infants with hypoparathyroidism should be carefully examined because clinical findings relating to the p.R367X mutation may show a variable age of onset.

  11. A Prospective Cohort Study to Compare Treatment Results Between 2 Fractionation Schedules of High-Dose-Rate Intracavitary Brachytherapy (HDR-ICBT) in Patients With Cervical Cancer

    SciTech Connect

    Huang, Eng-Yen; Sun, Li-Min; Lin, Hao; Lan, Jen-Hong; Chanchien, Chan-Chao; Huang, Yu-Jie; Wang, Chang-Yu; Wang, Chong-Jong

    2013-01-01

    Purpose: To compare the treatment results of 2 fractionation schedules for high-dose-rate intracavitary brachytherapy (HDR-ICBT) in patients with cervical cancer. Methods and Materials: From June 2001 through January 2008, 267 patients with stage IB-IVA cervical cancer were enrolled in the study. All patients underwent 4-field pelvic irradiation and HDR-ICBT. The median central and parametrial doses were 39.6 Gy and 45 Gy, respectively. Patient underwent either 6 Gy Multiplication-Sign 4 (HDR-4) (n=144) or 4.5 Gy Multiplication-Sign 6 (HDR-6) (n=123) to point A of ICBT using {sup 192}Ir isotope twice weekly. The rates of overall survival, locoregional failure, distant metastasis, proctitis, cystitis, and enterocolitis were compared between HDR-4 and HDR-6. Results: There were no significant differences in the demographic data between HDR-4 and HDR-6 except for total treatment time. The 5-year proctitis rates were 23.0% and 21.5% in HDR-4 and HDR-6 (P=.399), respectively. The corresponding rates of grade 2-4 proctitis were 18.7% and 9.6% (P=.060). The corresponding rates of grades 3-4 proctitis were 5.2% and 1.3% (P=.231). Subgroup analysis revealed that HDR-4 significantly increased grade 2-4 proctitis in patients aged {>=}62 years old (P=.012) but not in patients aged <62 years (P=.976). The rates of overall survival, locoregional failure, distant metastasis, cystitis, and enterocolitis were not significantly different between HDR-4 and HDR-6 schedules. Conclusion: The small fraction size of HDR-ICBT is associated with grade 2 proctitis without compromise of prognosis in elderly patients. This schedule is suggested for patients who tolerate an additional 2 applications of HDR-ICBT.

  12. Stratigraphic Relationships on Husband Hill, Mars

    NASA Astrophysics Data System (ADS)

    Cole, S. B.; Watters, W. A.; Squyres, S. W.

    2011-03-01

    We measure bedding plane orientations of outcrops on Cumberland Ridge in the Columbia Hills. Our measurements are consistent with the hypotheses that the outcrops (1) form a stratigraphic section, and (2) drape the Husband Hill edifice.

  13. Fenton oxidation and combined Fenton-microbial treatment for remediation of crude oil contaminated soil in Assam - India.

    PubMed

    Buragohain, Surabhi; Deka, Dibakar Chandra; Devi, Arundhuti

    2013-10-01

    The study is aimed at the remediation of soil spiked with crude oil (5%) by employing Fenton oxidation, biological treatment and combined Fenton-biological treatment. A spiked concentration of 5% crude oil was selected on the basis of contamination levels of 0-5% as found in the soil of upper Assam oil fields (India). The degradation of the aliphatic fraction (C14-C28) of the crude oil was investigated by gas chromatography. Fenton oxidation was carried out at different pH (3 to 8) in a laboratory batch reactor and maximum oxidative degradation was observed at pH 3-5. At pH 3, single Fenton oxidation resulted in 36 and 57% degradation in 5 and 10 days respectively. Biological treatment (with Fusarium solani) and combined Fenton-biological treatment were carried out with a one month incubation period. Biological treatment alone brought about 61% degradation of the crude oil while the combined process could achieve as much as 75% degradation of the aliphatic fractions of the crude oil.

  14. Fenton oxidation and combined Fenton-microbial treatment for remediation of crude oil contaminated soil in Assam - India.

    PubMed

    Buragohain, Surabhi; Deka, Dibakar Chandra; Devi, Arundhuti

    2013-10-01

    The study is aimed at the remediation of soil spiked with crude oil (5%) by employing Fenton oxidation, biological treatment and combined Fenton-biological treatment. A spiked concentration of 5% crude oil was selected on the basis of contamination levels of 0-5% as found in the soil of upper Assam oil fields (India). The degradation of the aliphatic fraction (C14-C28) of the crude oil was investigated by gas chromatography. Fenton oxidation was carried out at different pH (3 to 8) in a laboratory batch reactor and maximum oxidative degradation was observed at pH 3-5. At pH 3, single Fenton oxidation resulted in 36 and 57% degradation in 5 and 10 days respectively. Biological treatment (with Fusarium solani) and combined Fenton-biological treatment were carried out with a one month incubation period. Biological treatment alone brought about 61% degradation of the crude oil while the combined process could achieve as much as 75% degradation of the aliphatic fractions of the crude oil. PMID:24056615

  15. 'Columbia Hills' Color Elevation Map

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Figure 1: Spirit's Long Journey, Sol 450

    This elevation map shows the region of the 'Columbia Hills' where NASA's Mars Exploration Rover Spirit has been working since mid-2004. Areas colored blue are lower in elevation and areas colored yellow are higher in elevation. The map imagery is from the Mars Orbiter Camera on NASA's Mars Global Surveyor orbiter.

    Spirit's Long Journey, Sol 450 More than 15 months after landing on Mars, NASA's Spirit rover is still going strong, having traveled a total of 4,276 meters (2.66 miles) as of martian day, or sol, 450 (April 8, 2005). This elevation map shows the traverse followed by Spirit since arriving at the 'Columbia Hills' in June, 2004. The areas colored blue are low in elevation and areas colored yellow are high in elevation. The blue area at the foot of the 'Columbia Hills' is approximately 20 meters (66 feet) higher in elevation than the site where Spirit landed in Gusev Crater. The highest peak is on the order of 80 meters (262 feet) higher still. In other words, the hills Spirit is exploring are more than 250 feet high. The map imagery is from the Mars Orbiter Camera on NASA's Mars Global Surveyor.

  16. Coming Down from the Hill

    ERIC Educational Resources Information Center

    Frank, Fiona

    2009-01-01

    Lancaster University's Department of Continuing Education has a long tradition of engagement with older learners. Its latest innovation aims to reach out to older people sometimes suspicious of the "university on the hill". This article discusses how Lancaster University develops a "Senior Learner' Programme", which is continuing as one of the…

  17. [Treatment of Petrochemical Treatment Plant Secondary Effluent by Fenton Oxidation].

    PubMed

    Wang, Yi; Wu, Chang-yong; Zhou, Yue-xi; Zhang, Xue; Dong, Bo; Chen, Xue-min

    2015-07-01

    Fenton oxidation was applied to treat the petrochemical treatment plant secondary effluent by the continuous flow configuration. The effect of Fenton agent dosage on the COD and phosphorus removal and the variation of the dissolved organic matter characteristics during the treatment process were investigated. The results showed the average COD and PO(4)3- -P concentrations were 64.8 mg.L-1 and 0. 79 mg.L-1, respectively. When the dosage of H2O (30%), FeSO4.7H2O and PAM were 0. 4 mL.L-1, 0. 8 mg.L-1 and 0. 9 mg.L-1 and the residence time was 30 min, the average removal rate of COD and PO(4)3- -P were 24. 3% and 95. 5% respectively. The effluent COD was lower than 50 mg.L-1. The percentage of dissolved organic matters with molecular weight less than 1 x 10(3) was 80. 4% in the raw wastewater, however, the percentage increased to 95. 6% when treated by Fenton oxidation. Three-dimensional fluorescence analysis showed that the Fenton oxidation can effectively remove protein and phenols. GC-MS results showed that there were about 117 kinds of organic matters detected in the secondary effluent, while the number reduced to 27 after oxidation by Fenton. The organics containing unsaturated bond had a better removal than those of other types of organics. Fenton oxidation can be used in the advanced treatment of petrochemical secondary effluent.

  18. 27 CFR 9.52 - Chalk Hill.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Chalk Hill. 9.52 Section 9... TREASURY LIQUORS AMERICAN VITICULTURAL AREAS Approved American Viticultural Areas § 9.52 Chalk Hill. (a) Name. The name of the viticultural area described in this section is “Chalk Hill.” (b) Approved...

  19. 27 CFR 9.52 - Chalk Hill.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Chalk Hill. 9.52 Section 9... TREASURY LIQUORS AMERICAN VITICULTURAL AREAS Approved American Viticultural Areas § 9.52 Chalk Hill. (a) Name. The name of the viticultural area described in this section is “Chalk Hill.” (b) Approved...

  20. 27 CFR 9.52 - Chalk Hill.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Chalk Hill. 9.52 Section 9... TREASURY LIQUORS AMERICAN VITICULTURAL AREAS Approved American Viticultural Areas § 9.52 Chalk Hill. (a) Name. The name of the viticultural area described in this section is “Chalk Hill.” (b) Approved...

  1. 27 CFR 9.52 - Chalk Hill.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Chalk Hill. 9.52 Section 9... TREASURY ALCOHOL AMERICAN VITICULTURAL AREAS Approved American Viticultural Areas § 9.52 Chalk Hill. (a) Name. The name of the viticultural area described in this section is “Chalk Hill.” (b) Approved...

  2. 27 CFR 9.52 - Chalk Hill.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Chalk Hill. 9.52 Section 9... TREASURY ALCOHOL AMERICAN VITICULTURAL AREAS Approved American Viticultural Areas § 9.52 Chalk Hill. (a) Name. The name of the viticultural area described in this section is “Chalk Hill.” (b) Approved...

  3. Evolution of a Hybrid Roller Cone/PDC core bit

    SciTech Connect

    Pettitt, R.; Laney, R.; George, D.; Clemens, G.

    1980-01-01

    The development of the hot dry rock (HDR) geothermal resource, as presently being accomplished by the Los Alamos Scientific Laboratory (LASL), requires that sufficient quantities of good quality core be obtained at a reasonable cost. The use of roller cone core bits, with tungsten carbide inserts, was initiated by the Deep Sea Drilling Program. These bits were modified for continental drilling in deep, hot, granitic rock for the LASL HDR Geothermal Site at Fenton Hill, New Mexico in 1974. After the advent of monocrystalline diamond Stratapax pads, a prototype hybrid roller cone/Stratapax core bit was fabricated by Smith Tool, and tested at Fenton Hill in 1978. During the drilling for a deeper HDR reservoir system in 1979 and 1980, six of the latest generation of these bits, now called Hybrid Roller Cone/Polycrystalline Diamond Cutter (PDC) core bits, were successfully used in granitic rock at depths below 11,000 ft.

  4. Systematic quantification of HDR and NHEJ reveals effects of locus, nuclease, and cell type on genome-editing.

    PubMed

    Miyaoka, Yuichiro; Berman, Jennifer R; Cooper, Samantha B; Mayerl, Steven J; Chan, Amanda H; Zhang, Bin; Karlin-Neumann, George A; Conklin, Bruce R

    2016-01-01

    Precise genome-editing relies on the repair of sequence-specific nuclease-induced DNA nicking or double-strand breaks (DSBs) by homology-directed repair (HDR). However, nonhomologous end-joining (NHEJ), an error-prone repair, acts concurrently, reducing the rate of high-fidelity edits. The identification of genome-editing conditions that favor HDR over NHEJ has been hindered by the lack of a simple method to measure HDR and NHEJ directly and simultaneously at endogenous loci. To overcome this challenge, we developed a novel, rapid, digital PCR-based assay that can simultaneously detect one HDR or NHEJ event out of 1,000 copies of the genome. Using this assay, we systematically monitored genome-editing outcomes of CRISPR-associated protein 9 (Cas9), Cas9 nickases, catalytically dead Cas9 fused to FokI, and transcription activator-like effector nuclease at three disease-associated endogenous gene loci in HEK293T cells, HeLa cells, and human induced pluripotent stem cells. Although it is widely thought that NHEJ generally occurs more often than HDR, we found that more HDR than NHEJ was induced under multiple conditions. Surprisingly, the HDR/NHEJ ratios were highly dependent on gene locus, nuclease platform, and cell type. The new assay system, and our findings based on it, will enable mechanistic studies of genome-editing and help improve genome-editing technology. PMID:27030102

  5. Systematic quantification of HDR and NHEJ reveals effects of locus, nuclease, and cell type on genome-editing

    PubMed Central

    Miyaoka, Yuichiro; Berman, Jennifer R.; Cooper, Samantha B.; Mayerl, Steven J.; Chan, Amanda H.; Zhang, Bin; Karlin-Neumann, George A.; Conklin, Bruce R.

    2016-01-01

    Precise genome-editing relies on the repair of sequence-specific nuclease-induced DNA nicking or double-strand breaks (DSBs) by homology-directed repair (HDR). However, nonhomologous end-joining (NHEJ), an error-prone repair, acts concurrently, reducing the rate of high-fidelity edits. The identification of genome-editing conditions that favor HDR over NHEJ has been hindered by the lack of a simple method to measure HDR and NHEJ directly and simultaneously at endogenous loci. To overcome this challenge, we developed a novel, rapid, digital PCR–based assay that can simultaneously detect one HDR or NHEJ event out of 1,000 copies of the genome. Using this assay, we systematically monitored genome-editing outcomes of CRISPR-associated protein 9 (Cas9), Cas9 nickases, catalytically dead Cas9 fused to FokI, and transcription activator–like effector nuclease at three disease-associated endogenous gene loci in HEK293T cells, HeLa cells, and human induced pluripotent stem cells. Although it is widely thought that NHEJ generally occurs more often than HDR, we found that more HDR than NHEJ was induced under multiple conditions. Surprisingly, the HDR/NHEJ ratios were highly dependent on gene locus, nuclease platform, and cell type. The new assay system, and our findings based on it, will enable mechanistic studies of genome-editing and help improve genome-editing technology. PMID:27030102

  6. The conception and implementation of a local HDR fusion algorithm depending on contrast and luminosity parameters

    NASA Astrophysics Data System (ADS)

    Besrour, Amine; Abdelkefi, Fatma; Siala, Mohamed; Snoussi, Hichem

    2015-09-01

    Nowadays, the high dynamic range (HDR) imaging represents the subject of the most researches. The major problem lies in the implementation of the best algorithm to acquire the best video quality. In fact, the major constraint is to conceive an optimal fusion which must meet the rapid movement of video frames. The implemented merging algorithms were not quick enough to reconstitute the HDR video. In this paper, we detail each of the previous existing works before detailing our algorithm and presenting results from the acquired HDR images, tone mapped with various techniques. Our proposed algorithm guarantees a more enhanced and faster solution compared to the existing ones. In fact, it has the ability to calculate the saturation matrix related to the saturation rate of the neighboring pixels. The computed coefficients are affected respectively to each picture from the tested ones. This analysis provides faster and efficient results in terms of quality and brightness. The originality of our work remains on its processing method including the pixels saturation in the totality of the captured pictures and their combination in order to obtain the best pictures illustrating all the possible details. These parameters are computed for each zone depending on the contrast and the luminosity of the current pixel and its neighboring. The final HDR image's coefficients are calculated dynamically ensuring the best image quality equilibrating the brightness and contrast values and making the perfect final image.

  7. Mineralization of metoprolol by electro-Fenton and photoelectro-Fenton processes.

    PubMed

    Isarain-Chávez, Eloy; Garrido, José Antonio; Rodríguez, Rosa María; Centellas, Francesc; Arias, Conchita; Cabot, Pere Lluís; Brillas, Enric

    2011-02-24

    Solutions of about 0.25 mM of the β-blocker metoprolol tartrate (100 mg L(-1) total organic carbon) with 0.5 mM Fe(2+) in the presence and absence of 0.1 mM Cu(2+) of pH 3.0 have been comparatively degraded under electro-Fenton (EF) and photoelectro-Fenton (PEF) conditions. The electrolyses were carried out with two systems: (i) a single cell with a boron-doped diamond (BDD) anode and an air-diffusion cathode (ADE) for H(2)O(2) electrogeneration and (ii) a combined cell with a BDD/ADE pair coupled with a Pt/carbon felt (CF) cell. Overall mineralization was reached in all PEF treatments using both systems due to the efficient production of hydroxyl radical ((•)OH) from Fenton's reaction induced by UVA light and the quick photolysis of Fe(III) carboxylate complexes formed. In EF, the combined cell was much more potent than the single one by the larger (•)OH generation from the continuous Fe(2+) regeneration at the CF cathode, accelerating the oxidation of organics. However, almost total mineralization in EF was feasible using the combined cell in the presence of 0.1 mM Cu(2+), because of the parallel quick oxidation of Cu(II) carboxylate complexes by (•)OH. Metoprolol decay always followed a pseudo-first-order reaction. Aromatic products related to consecutive hydroxylation/oxidation reactions of metoprolol were detected by gas chromatography-mass spectrometry. The evolution of the aromatic 4-(2-methoxyethyl)phenol and generated carboxylic acids was followed by HPLC. The degradation rate and mineralization degree of metoprolol tartrate were limited by the removal of Fe(III) and Cu(II) complexes of ultimate carboxylic acids such as formic, oxalic, and oxamic. NH(4)(+) ion and to a lesser extent NO(3)(-) ion were released in all treatments, being quantified by ionic chromatography. PMID:21288029

  8. On the origin of Hill's causal criteria.

    PubMed

    Morabia, A

    1991-09-01

    The rules to assess causation formulated by the eighteenth century Scottish philosopher David Hume are compared to Sir Austin Bradford Hill's causal criteria. The strength of the analogy between Hume's rules and Hill's causal criteria suggests that, irrespective of whether Hume's work was known to Hill or Hill's predecessors, Hume's thinking expresses a point of view still widely shared by contemporary epidemiologists. The lack of systematic experimental proof to causal inferences in epidemiology may explain the analogy of Hume's and Hill's, as opposed to Popper's, logic.

  9. SU-E-T-574: Fessiblity of Using the Calypso System for HDR Interstitial Catheter Reconstruction

    SciTech Connect

    Li, J S; Ma, C

    2014-06-01

    Purpose: It is always a challenge to reconstruct the interstitial catheter for high dose rate (HDR) brachytherapy on patient CT or MR images. This work aims to investigate the feasibility of using the Calypso system (Varian Medical, CA) for HDR catheter reconstruction utilizing its accuracy on tracking the electromagnetic transponder location. Methods: Experiment was done with a phantom that has a HDR interstitial catheter embedded inside. CT scan with a slice thickness of 1.25 mm was taken for this phantom with two Calypso beacon transponders in the catheter. The two transponders were connected with a wire. The Calypso system was used to record the beacon transponders’ location in real time when they were gently pulled out with the wire. The initial locations of the beacon transponders were used for registration with the CT image and the detected transponder locations were used for the catheter path reconstruction. The reconstructed catheter path was validated on the CT image. Results: The HDR interstitial catheter was successfully reconstructed based on the transponders’ coordinates recorded by the Calypso system in real time when the transponders were pulled in the catheter. After registration with the CT image, the shape and location of the reconstructed catheter are evaluated against the CT image and the result shows an accuracy of 2 mm anywhere in the Calypso detectable region which is within a 10 cm X 10 cm X 10 cm cubic box for the current system. Conclusion: It is feasible to use the Calypso system for HDR interstitial catheter reconstruction. The obstacle for its clinical usage is the size of the beacon transponder whose diameter is bigger than most of the interstitial catheters used in clinic. Developing smaller transponders and supporting software and hardware for this application is necessary before it can be adopted for clinical use.

  10. HDR brachytherapy (HDR–BT) combined with stent placement in palliative treatment of esophageal cancer

    PubMed Central

    Skowronek, Janusz; Kubaszewska, Magda; Chichel, Adam; Piotrowski, Tomasz

    2009-01-01

    Purpose In the study we present the initial results of palliative treatment using combined methods of HDR-BT and stent insertion in patients with advanced esophagus cancer. Material and methods Fifty patients were treated in the Great Poland Cancer Center using HDR-BT between June 2001 and December 2005 and they were enrolled into the study. All patients underwent endoscopic insertion of self-expanding, metal, endoesophageal stents owing to blockages in the lumen of the esophagus which excluded brachytherapy. The group included 41 men and 9 women, aged between 44 and 79 years (average 59.3 years). 36 of patients received 3 fractions of HDR once a week of 7.5 Gy, up to total dose of 22.5 Gy, 14 patients received 2 fractions of 7.5 Gy (15 Gy). Results The average patient observation period was 5.4 months. Complete remission (CR) was observed after 4 weeks in 2 cases (4%), partial remission (PR) in 31 (62%), no remission (NR) was seen in 6 patients (12%) and progression was noted in 11 cases (22%). Complications of brachytherapy for esophageal cancer were observed in 11 patients (22%), ulceration in 1 patient (2%), haemorrhage in 1 patient (2%) and bronchotracheal fistulas in 9 (18%) patients. The average observation period for patients with bronchotracheal fistulas was notably shorter than in remaining patients and amounted 3.5 months. Conclusions 1. Endoscopic implantation of stents to the lumen of the esophagus provides access to esophagus and, in many cases, allows application of HDR-BT. 2. HDR-BT for advanced esophageal cancer brought relief from dysphagia in most of patients. 3. The combination of the two methods of treatment represents an effective choice for palliative care of this group of patients, with a complication rate similar to observed one in the instance of brachytherapy alone.

  11. IN-SITU FENTON OXIDATION: A CRITICAL ANALYSIS

    EPA Science Inventory

    In-situ Fenton oxidation (ISFO) is a rapidly emerging technology which involves the injection of hydrogen peroxide (H2O2) and other chemical reagents into the subsurface for the purpose of oxidizing and transforming contaminants. ISFO is being applied at an increasing number of ...

  12. PREDICTING FENTON-DRIVEN DEGRADATION USING CONTAMINANT ANALOG

    EPA Science Inventory

    The reaction of hydrogen peroxide (H2O2) and Fe(II) (Fenton's reaction) generates hydroxyl radicals (OH) that can be used to oxidize contaminants in soils and aquifers. In such environments, insufficient iron, reactions involving H2O2 that do not yield OH, and OH reactions with ...

  13. Degradation of ethylparaben under simulated sunlight using photo-Fenton.

    PubMed

    Zúñiga-Benítez, Henry; Peñuela, Gustavo A

    2016-01-01

    Ethylparaben (EPB) has been classified by different research groups as a potential endocrine-disrupting chemical, implying that it can potentially interfere with the normal balance of the endocrine system of living beings, which with its presence in different effluents, including drinking water, generates the need to seek methods that allow its removal from different water bodies. Advanced oxidation processes have been employed widely to remove organic compounds from different matrices. In this way, Fenton technology (process based on the reaction between ferrous ions and hydrogen peroxide) has been able to degrade different substrates, but due to the Fe(2+) requirements to carry out the reaction optimally, combination of the conventional Fenton process with visible light radiation (photo-Fenton) is an alternative used in the treatment of pollution due to the presence of chemicals. In this way, the effectiveness of photo-Fenton on EPB degradation was assessed using a face-centered central composite experimental design that allowed assessment of the effects of Fe(2+) and H2O2 initial concentrations on process. In general, results indicated that after 180 min of reaction almost all EPB was eliminated, the dissolved organic carbon in solution was reduced and the sample biodegradability index was increased. PMID:26901724

  14. Improvement in carbofuran degradation by different Fenton's reagent dosing processes.

    PubMed

    Ma, Ying-Shih

    2011-11-01

    Attempts were made in this study to examine the efficiency of Fenton's reagent with different dosing processes and H(2)O(2) and Fe(2+) concentrations for the treatment of carbofuran wastewater. Carbofuran degradation, total organic carbon (TOC) removal and H(2)O(2) consumption were determined during the experiments. Increases in H(2)O(2) and Fe(2+) concentrations led to an increase in the degradation of carbofuran. Almost 100% of carbofuran could be degraded at pH 3, 120 mg L(-1) H(2)O(2), 24 mg L(-1) Fe(2+) and 30 minutes reaction time; removals of TOC were among 48.8%-53.3% under different dosing processes. A continuous dosing process was beneficial to improve the removal of TOC by Fenton's reagent. Rate constants of carbofuran degradation could be calculated by the first-order kinetics; increase in the Fenton's reagent generally increased the rate constants. Gas chromatography-mass spectrometry analysis found five degradation products by hydroxyl radicals attack. Thus, this study might offer an effective dosing way for carbofuran wastewater treatment by Fenton's reagent.

  15. EFFECT OF FENTON'S REAGENT ON SUBSURFACE MICROBIOLOGY AND BIODEGRADATION CAPACITY

    EPA Science Inventory

    Microcosm studies were conducted to determine the effect of Fenton's reagent on subsurface microbiology and biodegradation capacity in a DNAPL (PCE/TCE) contaminated aquifer previously treated with the reagent. Groundwater pH declined from 5 to 2.4 immediately after the treatmen...

  16. GEOCHEMISTRY OF MAJUBA HILL, NEVADA.

    USGS Publications Warehouse

    Wenrich, Karen J.; Mascarenas, Joseph F.; Silberman, Miles L.

    1984-01-01

    Majuba Hill is the erosional remnant of a mineralized volcanic complex of rhyolite porphyry stocks, dikes, sills and irregular masses of breccia intruded into Triassic(? ) argillites. Majuba Hill is best known for its Cu and Sn ore; in addition, it was mineralized with other metals of possible economic significance, most notably, Mo, Ag, and U. Although this is an intrusive complex with no evidence of any extrusive phases, it was intruded sufficiently near the surface to develop a porphyritic texture. Intense sericitic and argillic alteration affected all stages of intrusion. Fresh rocks were not available for K-Ar analyses. Several samples of feldspars and sericite from altered zones yielded K-Ar ages for the alteration of 24. 7 to 25. 5 m. y. The tight clustering of ages suggests that all stages of the complex were altered within less than 1 m. y.

  17. Rocks of the Columbia Hills

    USGS Publications Warehouse

    Squyres, S. W.; Arvidson, R. E.; Blaney, D.L.; Clark, B. C.; Crumpler, L.; Farrand, W. H.; Gorevan, S.; Herkenhoff, K. E.; Hurowitz, J.; Kusack, A.; McSween, H.Y.; Ming, D. W.; Morris, R.V.; Ruff, S.W.; Wang, A.; Yen, A.

    2006-01-01

    The Mars Exploration Rover Spirit has identified five distinct rock types in the Columbia Hills of Gusev crater. Clovis Class rock is a poorly sorted clastic rock that has undergone substantial aqueous alteration. We interpret it to be aqueously altered ejecta deposits formed by impacts into basaltic materials. Wishstone Class rock is also a poorly sorted clastic rock that has a distinctive chemical composition that is high in Ti and P and low in Cr. Wishstone Class rock may be pyroclastic or impact in origin. Peace Class rock is a sedimentary material composed of ultramafic sand grains cemented by significant quantities of Mg- and Ca-sulfates. Peace Class rock may have formed when water briefly saturated the ultramafic sands and evaporated to allow precipitation of the sulfates. Watchtower Class rocks are similar chemically to Wishstone Class rocks and have undergone widely varying degrees of near-isochemical aqueous alteration. They may also be ejecta deposits, formed by impacts into Wishstone-rich materials and altered by small amounts of water. Backstay Class rocks are basalt/trachybasalt lavas that were emplaced in the Columbia Hills after the other rock classes were, either as impact ejecta or by localized volcanic activity. The geologic record preserved in the rocks of the Columbia Hills reveals a period very early in Martian history in which volcanic materials were widespread, impact was a dominant process, and water was commonly present. Copyright 2006 by the American Geophysical Union.

  18. Destruction of 2,4,6-trinitrotoluene by Fenton oxidation

    SciTech Connect

    Li, Z.M.; Comfort, S.D.; Shea, P.J.

    1997-03-01

    Past disposal practices at munitions production facilities have generated numerous acres of 2,4,6-trinitrotoluene (TNT)-contaminated soil. We determined the potential of the Fenton reagent (Fe{sup 2+} and H{sub 2}O{sub 2}) to remediate TNT contamination in water, aqueous extracts of contaminated soil, and soil-water slurries. The effects of H{sub 2}O{sub 2} and Fe{sup 2+} concentrations, solution pH, temperature, and initial TNT concentration on transformation and mineralization rates were evaluated. Treating an aqueous TNT solution (70 mg TNT L{sup -1}) with Fenton reagent (1% H{sub 2}O{sub 2}, 80 mg Fe{sup 2+} L{sup -1}) in the dark resulted in 100% destruction of TNT within 24 h. This coincided with 40% mineralization. Subsequent exposure to light resulted in >90% mineralization. We observed generation of 2,4,6-trinitrobenzoic acid and 1,3,5-trinitrobenzene within 15 min following Fenton oxidation of TNT. This indicates that initial TNT destruction likely occurs by methyl group oxidation and decarboxylation. Subsequent transformations involve nitro moiety removal with ring hydroxylation and cleavage, as evidenced by the stoichiometric recovery of TNT-nitrogen as NO{sub 3}{sup -} and production of oxalic acid as the primary C-containing end product. Upon exposure to light, Fe(II) was regenerated and the oxalate produced from 14C-TNT oxidation disappeared; this coincided with a decrease in solution {sup 14}C activity. Similar observations were made when {sup 14}C-oxalic acid was the starting substrate. Fenton oxidation was also effective in destroying TNT in aqueous extracts of contaminated soil and soil-water slurries. Experimental data provide evidence that the Fenton reagent can effectively remediate TNT-contaminated water and soil. 39 refs., 8 figs., 1 tab.

  19. Chemical decomposition of 2,4,6-trichlorophenol by ozone, Fenton`s reagent, and UV radiation

    SciTech Connect

    Benitez, F.J.; Beltran-Heredia, J.; Acero, J.L.; Rubio, F.J.

    1999-04-01

    The kinetics of the decomposition of 2,4,6-trichlorophenol by ozonation, by Fenton`s reagent reaction, and by a polychromatic UV radiation is investigated from experiments performed in a batch reactor. In each oxidation system, the degree of removal of the organic compound from water is evaluated and the influence of the operating variables is established. The ozonation process is conducted at pH = 2 and in the presence of radical scavengers: In these conditions the kinetic constants and reaction orders for the direct reaction between ozone and that organic compound are deduced by using a model based in the film theory. The oxidation by Fenton`s reagent (Fe{sup 2+} ion and H{sub 2}O{sub 2}), a generating system of hydroxyl radicals, leads to the evaluation of pseudo-first-order rate constants for the global reaction and to the determination of the kinetic constant for the direct radical reaction. Finally, the quantum yields in the photodecomposition process are determined from the rate equation, with the radiation flow rates absorbed previously calculated by means of a radiation source emission model.

  20. Handheld directional reflectometer: an angular imaging device to measure BRDF and HDR in real time

    NASA Astrophysics Data System (ADS)

    Mattison, Phillip R.; Dombrowski, Mark S.; Lorenz, James M.; Davis, Keith J.; Mann, Harley C.; Johnson, Philip; Foos, Bryan

    1998-10-01

    Many applications require quantitative measurements of surface light scattering, including quality control on production lines, inspection of painted surfaces, inspection of field repairs, etc. Instruments for measuring surface scattering typically fall into two main categories, namely bidirectional reflectometers, which measure the angular distribution of scattering, and hemispherical directional reflectometers, which measure the total scattering into the hemisphere above the surface. Measurement of the bi-directional reflectance distribution function (BRDF) gives the greatest insight into how light is scattered from a surface. Measurements of BRDF, however, are typically very lengthy measurements taken by moving a source and detector to map the scattering. Since BRDF has four angular degrees of freedom, such measurements can require hours to days to complete. Instruments for measuring BRDF are also typically laboratory devices, although a field- portable bi-directional reflectometer does exist. Hemispherical directional reflectance (HDR) is a much easier measurement to make, although care must be taken to use the proper methodology when measuring at wavelengths beyond 10 micrometer, since integrating spheres (typically used to make such measurements) are very energy inefficient and lose their integrating properties at very long wavelengths. A few field- portable hemispherical directional reflectometers do exist, but typically measure HDR only at near-normal angles. Boeing Defense and Space Group and Surface Optics Corporation, under a contract from the Air Force Research Laboratory, have developed a new hand-held instrument capable of measuring both BRDF and HDR using a unique, patented angular imaging technique. A combination of an hemi-ellipsoidal mirror and an additional lens translate the angular scatter from a surface into a two-dimensional spatial distribution, which is recorded by an imaging array. This configuration fully maps the scattering from a half

  1. The Oryza sativa Regulator HDR1 Associates with the Kinase OsK4 to Control Photoperiodic Flowering

    PubMed Central

    Cui, Xuean; Feng, Dan; Wang, Kai; Xu, Ming; Zhou, Li; Han, Xiao; Gu, Xiaofeng; Lu, Tiegang

    2016-01-01

    Rice is a facultative short-day plant (SDP), and the regulatory pathways for flowering time are conserved, but functionally modified, in Arabidopsis and rice. Heading date 1 (Hd1), an ortholog of Arabidopsis CONSTANS (CO), is a key regulator that suppresses flowering under long-day conditions (LDs), but promotes flowering under short-day conditions (SDs) by influencing the expression of the florigen gene Heading date 3a (Hd3a). Another key regulator, Early heading date 1 (Ehd1), is an evolutionarily unique gene with no orthologs in Arabidopsis, which acts as a flowering activator under both SD and LD by promoting the rice florigen genes Hd3a and RICE FLOWERING LOCUST 1 (RFT1). Here, we report the isolation and characterization of the flowering regulator Heading Date Repressor1 (HDR1) in rice. The hdr1 mutant exhibits an early flowering phenotype under natural LD in a paddy field in Beijing, China (39°54'N, 116°23'E), as well as under LD but not SD in a growth chamber, indicating that HDR1 may functionally regulate flowering time via the photoperiod-dependent pathway. HDR1 encodes a nuclear protein that is most active in leaves and floral organs and exhibits a typical diurnal expression pattern. We determined that HDR1 is a novel suppressor of flowering that upregulates Hd1 and downregulates Ehd1, leading to the downregulation of Hd3a and RFT1 under LDs. We have further identified an HDR1-interacting kinase, OsK4, another suppressor of rice flowering under LDs. OsK4 acts similarly to HDR1, suppressing flowering by upregulating Hd1 and downregulating Ehd1 under LDs, and OsK4 can phosphorylate HD1 with HDR1 presents. These results collectively reveal the transcriptional regulators of Hd1 for the day-length-dependent control of flowering time in rice. PMID:26954091

  2. A segmentation and point-matching enhanced efficient deformable image registration method for dose accumulation between HDR CT images.

    PubMed

    Zhen, Xin; Chen, Haibin; Yan, Hao; Zhou, Linghong; Mell, Loren K; Yashar, Catheryn M; Jiang, Steve; Jia, Xun; Gu, Xuejun; Cervino, Laura

    2015-04-01

    Deformable image registration (DIR) of fractional high-dose-rate (HDR) CT images is challenging due to the presence of applicators in the brachytherapy image. Point-to-point correspondence fails because of the undesired deformation vector fields (DVF) propagated from the applicator region (AR) to the surrounding tissues, which can potentially introduce significant DIR errors in dose mapping. This paper proposes a novel segmentation and point-matching enhanced efficient DIR (named SPEED) scheme to facilitate dose accumulation among HDR treatment fractions. In SPEED, a semi-automatic seed point generation approach is developed to obtain the incremented fore/background point sets to feed the random walks algorithm, which is used to segment and remove the AR, leaving empty AR cavities in the HDR CT images. A feature-based 'thin-plate-spline robust point matching' algorithm is then employed for AR cavity surface points matching. With the resulting mapping, a DVF defining on each voxel is estimated by B-spline approximation, which serves as the initial DVF for the subsequent Demons-based DIR between the AR-free HDR CT images. The calculated DVF via Demons combined with the initial one serve as the final DVF to map doses between HDR fractions. The segmentation and registration accuracy are quantitatively assessed by nine clinical HDR cases from three gynecological cancer patients. The quantitative analysis and visual inspection of the DIR results indicate that SPEED can suppress the impact of applicator on DIR, and accurately register HDR CT images as well as deform and add interfractional HDR doses. PMID:25790059

  3. A segmentation and point-matching enhanced efficient deformable image registration method for dose accumulation between HDR CT images

    NASA Astrophysics Data System (ADS)

    Zhen, Xin; Chen, Haibin; Yan, Hao; Zhou, Linghong; Mell, Loren K.; Yashar, Catheryn M.; Jiang, Steve; Jia, Xun; Gu, Xuejun; Cervino, Laura

    2015-04-01

    Deformable image registration (DIR) of fractional high-dose-rate (HDR) CT images is challenging due to the presence of applicators in the brachytherapy image. Point-to-point correspondence fails because of the undesired deformation vector fields (DVF) propagated from the applicator region (AR) to the surrounding tissues, which can potentially introduce significant DIR errors in dose mapping. This paper proposes a novel segmentation and point-matching enhanced efficient DIR (named SPEED) scheme to facilitate dose accumulation among HDR treatment fractions. In SPEED, a semi-automatic seed point generation approach is developed to obtain the incremented fore/background point sets to feed the random walks algorithm, which is used to segment and remove the AR, leaving empty AR cavities in the HDR CT images. A feature-based ‘thin-plate-spline robust point matching’ algorithm is then employed for AR cavity surface points matching. With the resulting mapping, a DVF defining on each voxel is estimated by B-spline approximation, which serves as the initial DVF for the subsequent Demons-based DIR between the AR-free HDR CT images. The calculated DVF via Demons combined with the initial one serve as the final DVF to map doses between HDR fractions. The segmentation and registration accuracy are quantitatively assessed by nine clinical HDR cases from three gynecological cancer patients. The quantitative analysis and visual inspection of the DIR results indicate that SPEED can suppress the impact of applicator on DIR, and accurately register HDR CT images as well as deform and add interfractional HDR doses.

  4. Anodic Fenton process assisted by a microbial fuel cell for enhanced degradation of organic pollutants.

    PubMed

    Liu, Xian-Wei; Sun, Xue-Fei; Li, Dao-Bo; Li, Wen-Wei; Huang, Yu-Xi; Sheng, Guo-Ping; Yu, Han-Qing

    2012-09-15

    The electro-Fenton process is efficient for degradation of organic pollutants, but it suffers from the high operating costs due to the need of power investment. Here, a new anodic Fenton system is developed for energy-saving and efficient treatment of organic pollutants by incorporating microbial fuel cell (MFC) into an anodic Fenton process. This system is composed of an anodic Fenton reactor and a two-chamber air-cathode MFC. The power generated from a two-chamber MFC is used to drive the anodic Fenton process for Acid Orange 7 (AO7) degradation through accelerating in situ generation of Fe(2+) from sacrificial iron. The kinetic results show that the MFC-assisted anodic Fenton process system had a significantly higher pseudo-first-order rate constant than those for the chemical Fenton methods. The electrochemical analysis reveals that AO7 did not hinder the corrosion of iron. The anodic Fenton process was influenced by the MFC performance. It was also found that increasing dissolved oxygen in the cathode improved the MFC power density, which in turn enhanced the AO7 degradation rate. These clearly demonstrate that the anodic Fenton process could be integrated with MFC to develop a self-sustained system for cost-effective and energy-saving electrochemical wastewater treatment.

  5. Interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials: A review.

    PubMed

    He, Jie; Yang, Xiaofang; Men, Bin; Wang, Dongsheng

    2016-01-01

    The heterogeneous Fenton reaction can generate highly reactive hydroxyl radicals (OH) from reactions between recyclable solid catalysts and H2O2 at acidic or even circumneutral pH. Hence, it can effectively oxidize refractory organics in water or soils and has become a promising environmentally friendly treatment technology. Due to the complex reaction system, the mechanism behind heterogeneous Fenton reactions remains unresolved but fascinating, and is crucial for understanding Fenton chemistry and the development and application of efficient heterogeneous Fenton technologies. Iron-based materials usually possess high catalytic activity, low cost, negligible toxicity and easy recovery, and are a superior type of heterogeneous Fenton catalysts. Therefore, this article reviews the fundamental but important interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials. OH, hydroperoxyl radicals/superoxide anions (HO2/O2(-)) and high-valent iron are the three main types of reactive oxygen species (ROS), with different oxidation reactivity and selectivity. Based on the mechanisms of ROS generation, the interfacial mechanisms of heterogeneous Fenton systems can be classified as the homogeneous Fenton mechanism induced by surface-leached iron, the heterogeneous catalysis mechanism, and the heterogeneous reaction-induced homogeneous mechanism. Different heterogeneous Fenton systems catalyzed by characteristic iron-based materials are comprehensively reviewed. Finally, related future research directions are also suggested. PMID:26899649

  6. Microbially driven Fenton reaction for degradation of the widespread environmental contaminant 1,4-dioxane.

    PubMed

    Sekar, Ramanan; DiChristina, Thomas J

    2014-11-01

    The carcinogenic cyclic ether compound 1,4-dioxane is employed as a stabilizer of chlorinated industrial solvents and is a widespread environmental contaminant in surface water and groundwater. In the present study, a microbially driven Fenton reaction was designed to autocatalytically generate hydroxyl (HO•) radicals that degrade 1,4-dioxane. In comparison to conventional (purely abiotic) Fenton reactions, the microbially driven Fenton reaction operated at circumneutral pH and did not the require addition of exogenous H2O2 or UV irradiation to regenerate Fe(II) as Fenton reagents. The 1,4-dioxane degradation process was driven by pure cultures of the Fe(III)-reducing facultative anaerobe Shewanella oneidensis manipulated under controlled laboratory conditions. S. oneidensis batch cultures were provided with lactate, Fe(III), and 1,4-dioxane and were exposed to alternating aerobic and anaerobic conditions. The microbially driven Fenton reaction completely degraded 1,4-dioxane (10 mM initial concentration) in 53 h with an optimal aerobic-anaerobic cycling period of 3 h. Acetate and oxalate were detected as transient intermediates during the microbially driven Fenton degradation of 1,4-dioxane, an indication that conventional and microbially driven Fenton degradation processes follow similar reaction pathways. The microbially driven Fenton reaction provides the foundation for development of alternative in situ remediation technologies to degrade environmental contaminants susceptible to attack by HO• radicals generated by the Fenton reaction.

  7. Keeping pace with Capitol Hill

    USGS Publications Warehouse

    Cooper, C.

    2007-01-01

    At the Capitol Hill, the legislative branch of the United States government, the work is always at pace. Working with Congress is a tough job yet, rewarding. The Congress worked hard together to serve the public interest but many big issues are one small part of what Congress does. However, many US news media do not report what the government does instead, the media report what the government argues about. The media reports the conflicts but story is always incomplete. In order for the people know what is happening to the government, contact the congressional representative to know the complete story.

  8. Dosimetric study of surface applicators of HDR brachytherapy GammaMed Plus equipment

    SciTech Connect

    Reyes-Rivera, E. E-mail: modesto@fisica.ugto.mx Sosa, M. E-mail: modesto@fisica.ugto.mx Reyes, U. E-mail: modesto@fisica.ugto.mx Jesús Bernal-Alvarado, José de E-mail: theo@fisica.ugto.mx Córdova, T. E-mail: theo@fisica.ugto.mx Gil-Villegas, A. E-mail: theo@fisica.ugto.mx; Monzón, E.

    2014-11-07

    The cone type surface applicators used in HDR brachytherapy for treatment of small skin lesions are an alternative to be used with both electron beams and orthovoltage X-ray equipment. For a good treatment planning is necessary to know the dose distribution of these applicators, which can be obtained by experimental measurement and Monte Carlo simulation as well. In this study the dose distribution of surface applicators of 3 and 3.5 cm diameter, respectively of HDR brachytherapy GammaMed Plus equipment has been estimated using the Monte Carlo method, MCNP code. The applicators simulated were placed on the surface of a water phantom of 20 × 20 × 20 cm and the dose was calculated at depths from 0 to 3 cm with increments of 0.25 mm. The dose profiles obtained at depth show the expected gradients for surface therapy.

  9. A Novel Tone Mapping Based on Double-Anchoring Theory for Displaying HDR Images

    NASA Astrophysics Data System (ADS)

    Wang, Jinhua; Xu, De; Li, Bing

    In this paper, we present a Double-Anchoring Based Tone Mapping (DABTM) algorithm for displaying high dynamic range (HDR) images. First, two anchoring values are obtained using the double-anchoring theory. Second, we use the two values to formulate the compressing operator, which can achieve the aim of tone mapping directly. A new method based on accelerated K-means for the decomposition of HDR images into groups (frameworks) is proposed. Most importantly, a group of piecewise-overlap linear functions is put forward to define the belongingness of pixels to their locating frameworks. Experiments show that our algorithm is capable of achieving dynamic range compression, while preserving fine details and avoiding common artifacts such as gradient reversals, halos, or loss of local contrast.

  10. Dosimetric study of surface applicators of HDR brachytherapy GammaMed Plus equipment

    NASA Astrophysics Data System (ADS)

    Reyes-Rivera, E.; Sosa, M.; Reyes, U.; Monzón, E.; de Jesús Bernal-Alvarado, José; Córdova, T.; Gil-Villegas, A.

    2014-11-01

    The cone type surface applicators used in HDR brachytherapy for treatment of small skin lesions are an alternative to be used with both electron beams and orthovoltage X-ray equipment. For a good treatment planning is necessary to know the dose distribution of these applicators, which can be obtained by experimental measurement and Monte Carlo simulation as well. In this study the dose distribution of surface applicators of 3 and 3.5 cm diameter, respectively of HDR brachytherapy GammaMed Plus equipment has been estimated using the Monte Carlo method, MCNP code. The applicators simulated were placed on the surface of a water phantom of 20 × 20 × 20 cm and the dose was calculated at depths from 0 to 3 cm with increments of 0.25 mm. The dose profiles obtained at depth show the expected gradients for surface therapy.

  11. Impact Analysis of Baseband Quantizer on Coding Efficiency for HDR Video

    NASA Astrophysics Data System (ADS)

    Wong, Chau-Wai; Su, Guan-Ming; Wu, Min

    2016-10-01

    Digitally acquired high dynamic range (HDR) video baseband signal can take 10 to 12 bits per color channel. It is economically important to be able to reuse the legacy 8 or 10-bit video codecs to efficiently compress the HDR video. Linear or nonlinear mapping on the intensity can be applied to the baseband signal to reduce the dynamic range before the signal is sent to the codec, and we refer to this range reduction step as a baseband quantization. We show analytically and verify using test sequences that the use of the baseband quantizer lowers the coding efficiency. Experiments show that as the baseband quantizer is strengthened by 1.6 bits, the drop of PSNR at a high bitrate is up to 1.60dB. Our result suggests that in order to achieve high coding efficiency, information reduction of videos in terms of quantization error should be introduced in the video codec instead of on the baseband signal.

  12. Trans-Pacific HDR Satellite Communications Experiment Phase-2: Experimental Network and Demonstration Plan

    NASA Technical Reports Server (NTRS)

    Kadowaki, Naoto; Yoshimura, Naoko; Takahashi, Takashi; Yoshikawa, Makoto; Hsu, Eddie; Bergman, Larry; Bhasin, Kul; Gary, Pat

    1998-01-01

    The trans-Pacific high data rate (TP-HDR) satellite communications experiment was proposed at the Japan-U.S. Cooperation in Space (JUCS) Program Workshop held in Hawaii in 1993 and remote high definition video post-production was demonstrated as the first phase trial. Following the first phase, the second phase experiment is currently prepared. This paper describes the experimental network configuration, application demonstration, and performance evaluation plan of the second phase experiment.

  13. HDR (Hot Dry Rock) technology transfer activities in the Clear Lake Area, California

    SciTech Connect

    Burns, K.; Potter, R.

    1990-01-01

    A large Hot Dry Rock resource has been recognized in northern California. It underlies the region extending NE of The Geysers to N of the City of Clearlake. The long-range productive potential is thousands of megawatts. The geothermal resource is heterogeneous. There are two mechanisms of heat flow occurring together. One is fluid transport, up natural zones of permeability, to outflows as surface springs. The other is conductive heat flow through impermeable rock. The temperature isotherms are thought to be nearly level surfaces, for example, the 300{degree}C isotherm is at about 8000 ft depth, with spikes'' or ridges'' occurring around narrow zones of fluid flow. While there is accessible heat at shallow depth in the naturally permeable rocks, the really substantial resource is in the impermeable rock. This is the HDR resource. The potential reservoir rocks are Franciscan greywackes and greenstones. Recorded drilling problems appear to be mainly due to intersection with serpentinites or to the effects of stimulation, so are potentially avoidable. Greywacke is favoured as a reservoir rock, and is expected to fail by brittle fracture. The water shortages in Northern California appear to be surmountable. Leakoff rates are expected to be low. Sewerage water may be available for fill and makeup. There is a possibility of combining HDR heat power production with sewerage disposal. To establish the first HDR producer in Northern California offers challenges in technology transfer. Two significant challenges will be creation of dispersed permeability in a greywacke reservoir, and pressure management in the vicinity of naturally permeable zones. A successful demonstration of HDR production technology will improve the long-term prospects for the geothermal power industry in California. 29 refs., 20 figs., 4 tabs.

  14. A Study of Experimental Measurements of Dosimetric Parameters in HDR IR-192 Source

    SciTech Connect

    Zhang Menglong; Zhang Liangan; Yuan Shuyu; Dai Guangfu

    2010-01-01

    Thermoluminescent dosimeters have been used to perform dosimetry measurements for the widely used Ir-192 microSelectron-HDR source with an improved polystyrene phantom. Radial dose functions and anisotropy functions, main parameters of 2D dose-rate formalism from the TG-43U1 protocol, have been obtained experimentally. Measurement results are compared with that of the Monte Carlo calculations reported, and no difference has been found between them.

  15. IPIP: A new approach to inverse planning for HDR brachytherapy by directly optimizing dosimetric indices

    SciTech Connect

    Siauw, Timmy; Cunha, Adam; Atamtuerk, Alper; Hsu, I-Chow; Pouliot, Jean; Goldberg, Ken

    2011-07-15

    Purpose: Many planning methods for high dose rate (HDR) brachytherapy require an iterative approach. A set of computational parameters are hypothesized that will give a dose plan that meets dosimetric criteria. A dose plan is computed using these parameters, and if any dosimetric criteria are not met, the process is iterated until a suitable dose plan is found. In this way, the dose distribution is controlled by abstract parameters. The purpose of this study is to develop a new approach for HDR brachytherapy by directly optimizing the dose distribution based on dosimetric criteria. Methods: The authors developed inverse planning by integer program (IPIP), an optimization model for computing HDR brachytherapy dose plans and a fast heuristic for it. They used their heuristic to compute dose plans for 20 anonymized prostate cancer image data sets from patients previously treated at their clinic database. Dosimetry was evaluated and compared to dosimetric criteria. Results: Dose plans computed from IPIP satisfied all given dosimetric criteria for the target and healthy tissue after a single iteration. The average target coverage was 95%. The average computation time for IPIP was 30.1 s on an Intel(R) Core{sup TM}2 Duo CPU 1.67 GHz processor with 3 Gib RAM. Conclusions: IPIP is an HDR brachytherapy planning system that directly incorporates dosimetric criteria. The authors have demonstrated that IPIP has clinically acceptable performance for the prostate cases and dosimetric criteria used in this study, in both dosimetry and runtime. Further study is required to determine if IPIP performs well for a more general group of patients and dosimetric criteria, including other cancer sites such as GYN.

  16. Radiation dose enhancement at tissue-tungsten interfaces in HDR brachytherapy

    NASA Astrophysics Data System (ADS)

    Han, Z.; Safavi-Naeini, M.; Alnaghy, S.; Cutajar, DL; Guatelli, S.; Petasecca, M.; Franklin, DR; Malaroda, A.; Carrara, M.; Bucci, J.; Zaider, M.; Lerch, MLF; Rosenfeld, AB

    2014-11-01

    HDR BrachyView is a novel in-body dosimetric imaging system for real-time monitoring and verification of the source position in high dose rate (HDR) prostate brachytherapy treatment. It is based on a high-resolution pixelated detector array with a semi-cylindrical multi-pinhole tungsten collimator and is designed to fit inside a compact rectal probe, and is able to resolve the 3D position of the source with a maximum error of 1.5 mm. This paper presents an evaluation of the additional dose that will be delivered to the patient as a result of backscatter radiation from the collimator. Monte Carlo simulations of planar and cylindrical collimators embedded in a tissue-equivalent phantom were performed using Geant4, with an 192Ir source placed at two different source-collimator distances. The planar configuration was replicated experimentally to validate the simulations, with a MOSkin dosimetry probe used to measure dose at three distances from the collimator. For the cylindrical collimator simulation, backscatter dose enhancement was calculated as a function of axial and azimuthal displacement, and dose distribution maps were generated at three distances from the collimator surface. Although significant backscatter dose enhancement was observed for both geometries immediately adjacent to the collimator, simulations and experiments indicate that backscatter dose is negligible at distances beyond 1 mm from the collimator. Since HDR BrachyView is enclosed within a 1 mm thick tissue-equivalent plastic shell, all backscatter radiation resulting from its use will therefore be absorbed before reaching the rectal wall or other tissues. dosimetry, brachytherapy, HDR

  17. SU-E-J-270: Study of PET Response to HDR Brachytherapy of Rectal Cancer

    SciTech Connect

    Hobbs, R; Le, Y; Armour, E; Efron, J; Azad, N; Wahl, R; Gearhart, S; Herman, J

    2014-06-01

    Purpose: Dose-response studies in radiation therapy are typically using single response values for tumors across ensembles of tumors. Using the high dose rate (HDR) treatment plan dose grid and pre- and post-therapy FDG-PET images, we look for correlations between voxelized dose and FDG uptake response in individual tumors. Methods: Fifteen patients were treated for localized rectal cancer using 192Ir HDR brachytherapy in conjunction with surgery. FDG-PET images were acquired before HDR therapy and 6–8 weeks after treatment (prior to surgery). Treatment planning was done on a commercial workstation and the dose grid was calculated. The two PETs and the treatment dose grid were registered to each other using non-rigid registration. The difference in PET SUV values before and after HDR was plotted versus absorbed radiation dose for each voxel. The voxels were then separated into bins for every 400 cGy of absorbed dose and the bin average values plotted similarly. Results: Individual voxel doses did not correlate with PET response; however, when group into tumor subregions corresponding to dose bins, eighty percent of the patients showed a significant positive correlation (R2 > 0) between PET uptake difference in the targeted region and the absorbed dose. Conclusion: By considering larger ensembles of voxels, such as organ average absorbed dose or the dose bins considered here, valuable information may be obtained. The dose-response correlations as measured by FDG-PET difference potentially underlines the importance of FDG-PET as a measure of response, as well as the value of voxelized information.

  18. High-dose-rate (HDR) brachytherapy for the treatment of benign obstructive endobronchial granulation tissue

    SciTech Connect

    Madu, Chika N. . E-mail: chikam@xrt.upenn.edu; Machuzak, Michael S.; Sterman, Daniel H.; Musani, Ali; Ahya, Vivek; McDonough, James; Metz, James M.

    2006-12-01

    Background: Severe airway obstruction can occur in the setting of benign granulation tissue forming at bronchial anastomotic sites after lung transplantation in up to 20% of patients. Many of these benign lesions respond to stent placement, laser ablation, or balloon bronchoplasty. However, in certain cases, proliferation of granulation tissue may persist despite all therapeutic attempts. This study describes a series of refractory patients treated with high-dose-rate (HDR) brachytherapy for benign proliferation of granulation tissue, causing airway compromise. Methods and Materials: Between April 2002 and June 2005, 5 patients with significant airway compromise from recurrent granulation tissue were treated with HDR brachytherapy. All patients had previously failed to maintain a patent airway despite multiple bronchoscopic interventions. Treatment was delivered using an HDR brachytherapy afterloader with {sup 192}Ir. Dose prescription was to a depth of 1 cm. All patients were treated weekly, with total doses ranging from 10 Gy to 21 Gy in two to three fractions. Results: The median follow-up was 12 months. All patients experienced a reduction in therapeutic bronchoscopic procedures after HDR brachytherapy compared with the pretreatment period. With the exception of possible radiation-induced bronchitis in 1 patient, there were no other treatment related complications. At the time of this report, 2 patients have died and the other 3 are alive with marked symptomatic improvement and reduced bronchoscopic procedures. Conclusion: High-dose-rate brachytherapy is an effective treatment for benign proliferation of granulation tissue causing airway obstruction. The early response to therapy is encouraging and further follow-up is necessary to determine long-term durability and late effects.

  19. Radiation dose enhancement at tissue-tungsten interfaces in HDR brachytherapy.

    PubMed

    Han, Z; Safavi-Naeini, M; Alnaghy, S; Cutajar, D L; Guatelli, S; Petasecca, M; Franklin, D R; Malaroda, A; Carrara, M; Bucci, J; Zaider, M; Lerch, M L F; Rosenfeld, A B

    2014-11-01

    HDR BrachyView is a novel in-body dosimetric imaging system for real-time monitoring and verification of the source position in high dose rate (HDR) prostate brachytherapy treatment. It is based on a high-resolution pixelated detector array with a semi-cylindrical multi-pinhole tungsten collimator and is designed to fit inside a compact rectal probe, and is able to resolve the 3D position of the source with a maximum error of 1.5 mm. This paper presents an evaluation of the additional dose that will be delivered to the patient as a result of backscatter radiation from the collimator. Monte Carlo simulations of planar and cylindrical collimators embedded in a tissue-equivalent phantom were performed using Geant4, with an (192)Ir source placed at two different source-collimator distances. The planar configuration was replicated experimentally to validate the simulations, with a MOSkin dosimetry probe used to measure dose at three distances from the collimator. For the cylindrical collimator simulation, backscatter dose enhancement was calculated as a function of axial and azimuthal displacement, and dose distribution maps were generated at three distances from the collimator surface. Although significant backscatter dose enhancement was observed for both geometries immediately adjacent to the collimator, simulations and experiments indicate that backscatter dose is negligible at distances beyond 1 mm from the collimator. Since HDR BrachyView is enclosed within a 1 mm thick tissue-equivalent plastic shell, all backscatter radiation resulting from its use will therefore be absorbed before reaching the rectal wall or other tissues. dosimetry, brachytherapy, HDR.

  20. Prostate CT segmentation method based on nonrigid registration in ultrasound-guided CT-based HDR prostate brachytherapy

    PubMed Central

    Yang, Xiaofeng; Rossi, Peter; Ogunleye, Tomi; Marcus, David M.; Jani, Ashesh B.; Mao, Hui; Curran, Walter J.; Liu, Tian

    2014-01-01

    Purpose: The technological advances in real-time ultrasound image guidance for high-dose-rate (HDR) prostate brachytherapy have placed this treatment modality at the forefront of innovation in cancer radiotherapy. Prostate HDR treatment often involves placing the HDR catheters (needles) into the prostate gland under the transrectal ultrasound (TRUS) guidance, then generating a radiation treatment plan based on CT prostate images, and subsequently delivering high dose of radiation through these catheters. The main challenge for this HDR procedure is to accurately segment the prostate volume in the CT images for the radiation treatment planning. In this study, the authors propose a novel approach that integrates the prostate volume from 3D TRUS images into the treatment planning CT images to provide an accurate prostate delineation for prostate HDR treatment. Methods: The authors’ approach requires acquisition of 3D TRUS prostate images in the operating room right after the HDR catheters are inserted, which takes 1–3 min. These TRUS images are used to create prostate contours. The HDR catheters are reconstructed from the intraoperative TRUS and postoperative CT images, and subsequently used as landmarks for the TRUS–CT image fusion. After TRUS–CT fusion, the TRUS-based prostate volume is deformed to the CT images for treatment planning. This method was first validated with a prostate-phantom study. In addition, a pilot study of ten patients undergoing HDR prostate brachytherapy was conducted to test its clinical feasibility. The accuracy of their approach was assessed through the locations of three implanted fiducial (gold) markers, as well as T2-weighted MR prostate images of patients. Results: For the phantom study, the target registration error (TRE) of gold-markers was 0.41 ± 0.11 mm. For the ten patients, the TRE of gold markers was 1.18 ± 0.26 mm; the prostate volume difference between the authors’ approach and the MRI-based volume was 7.28% ± 0

  1. Prostate CT segmentation method based on nonrigid registration in ultrasound-guided CT-based HDR prostate brachytherapy

    SciTech Connect

    Yang, Xiaofeng Rossi, Peter; Ogunleye, Tomi; Marcus, David M.; Jani, Ashesh B.; Curran, Walter J.; Liu, Tian; Mao, Hui

    2014-11-01

    Purpose: The technological advances in real-time ultrasound image guidance for high-dose-rate (HDR) prostate brachytherapy have placed this treatment modality at the forefront of innovation in cancer radiotherapy. Prostate HDR treatment often involves placing the HDR catheters (needles) into the prostate gland under the transrectal ultrasound (TRUS) guidance, then generating a radiation treatment plan based on CT prostate images, and subsequently delivering high dose of radiation through these catheters. The main challenge for this HDR procedure is to accurately segment the prostate volume in the CT images for the radiation treatment planning. In this study, the authors propose a novel approach that integrates the prostate volume from 3D TRUS images into the treatment planning CT images to provide an accurate prostate delineation for prostate HDR treatment. Methods: The authors’ approach requires acquisition of 3D TRUS prostate images in the operating room right after the HDR catheters are inserted, which takes 1–3 min. These TRUS images are used to create prostate contours. The HDR catheters are reconstructed from the intraoperative TRUS and postoperative CT images, and subsequently used as landmarks for the TRUS–CT image fusion. After TRUS–CT fusion, the TRUS-based prostate volume is deformed to the CT images for treatment planning. This method was first validated with a prostate-phantom study. In addition, a pilot study of ten patients undergoing HDR prostate brachytherapy was conducted to test its clinical feasibility. The accuracy of their approach was assessed through the locations of three implanted fiducial (gold) markers, as well as T2-weighted MR prostate images of patients. Results: For the phantom study, the target registration error (TRE) of gold-markers was 0.41 ± 0.11 mm. For the ten patients, the TRE of gold markers was 1.18 ± 0.26 mm; the prostate volume difference between the authors’ approach and the MRI-based volume was 7.28% ± 0

  2. The effect of split pixel HDR image sensor technology on MTF measurements

    NASA Astrophysics Data System (ADS)

    Deegan, Brian M.

    2014-03-01

    Split-pixel HDR sensor technology is particularly advantageous in automotive applications, because the images are captured simultaneously rather than sequentially, thereby reducing motion blur. However, split pixel technology introduces artifacts in MTF measurement. To achieve a HDR image, raw images are captured from both large and small sub-pixels, and combined to make the HDR output. In some cases, a large sub-pixel is used for long exposure captures, and a small sub-pixel for short exposures, to extend the dynamic range. The relative size of the photosensitive area of the pixel (fill factor) plays a very significant role in the output MTF measurement. Given an identical scene, the MTF will be significantly different, depending on whether you use the large or small sub-pixels i.e. a smaller fill factor (e.g. in the short exposure sub-pixel) will result in higher MTF scores, but significantly greater aliasing. Simulations of split-pixel sensors revealed that, when raw images from both sub-pixels are combined, there is a significant difference in rising edge (i.e. black-to-white transition) and falling edge (white-to-black) reproduction. Experimental results showed a difference of ~50% in measured MTF50 between the falling and rising edges of a slanted edge test chart.

  3. The Ansel Adams zone system: HDR capture and range compression by chemical processing

    NASA Astrophysics Data System (ADS)

    McCann, John J.

    2010-02-01

    We tend to think of digital imaging and the tools of PhotoshopTM as a new phenomenon in imaging. We are also familiar with multiple-exposure HDR techniques intended to capture a wider range of scene information, than conventional film photography. We know about tone-scale adjustments to make better pictures. We tend to think of everyday, consumer, silver-halide photography as a fixed window of scene capture with a limited, standard range of response. This description of photography is certainly true, between 1950 and 2000, for instant films and negatives processed at the drugstore. These systems had fixed dynamic range and fixed tone-scale response to light. All pixels in the film have the same response to light, so the same light exposure from different pixels was rendered as the same film density. Ansel Adams, along with Fred Archer, formulated the Zone System, staring in 1940. It was earlier than the trillions of consumer photos in the second half of the 20th century, yet it was much more sophisticated than today's digital techniques. This talk will describe the chemical mechanisms of the zone system in the parlance of digital image processing. It will describe the Zone System's chemical techniques for image synthesis. It also discusses dodging and burning techniques to fit the HDR scene into the LDR print. Although current HDR imaging shares some of the Zone System's achievements, it usually does not achieve all of them.

  4. Impact of using linear optimization models in dose planning for HDR brachytherapy

    SciTech Connect

    Holm, Aasa; Larsson, Torbjoern; Carlsson Tedgren, Aasa

    2012-02-15

    Purpose: Dose plans generated with optimization models hitherto used in high-dose-rate (HDR) brachytherapy have shown a tendency to yield longer dwell times than manually optimized plans. Concern has been raised for the corresponding undesired hot spots, and various methods to mitigate these have been developed. The hypotheses upon this work is based are (a) that one cause for the long dwell times is the use of objective functions comprising simple linear penalties and (b) that alternative penalties, as these are piecewise linear, would lead to reduced length of individual dwell times. Methods: The characteristics of the linear penalties and the piecewise linear penalties are analyzed mathematically. Experimental comparisons between the two types of penalties are carried out retrospectively for a set of prostate cancer patients. Results: When the two types of penalties are compared, significant changes can be seen in the dwell times, while most dose-volume parameters do not differ significantly. On average, total dwell times were reduced by 4.2%, with a reduction of maximum dwell times by 25%, when the alternative penalties were used. Conclusions: The use of linear penalties in optimization models for HDR brachytherapy is one cause for the undesired long dwell times that arise in mathematically optimized plans. By introducing alternative penalties, a significant reduction in dwell times can be achieved for HDR brachytherapy dose plans. Although various measures for mitigating the long dwell times are already available, the observation that linear penalties contribute to their appearance is of fundamental interest.

  5. Combined ultrasound and Fenton (US-Fenton) process for the treatment of ammunition wastewater.

    PubMed

    Li, Yangang; Hsieh, Wen-Pin; Mahmudov, Rovshan; Wei, Xiaomei; Huang, C P

    2013-01-15

    A wastewater collected from a regional ammunition process site was treated with combined US-Fenton process. Factors such as pH, temperature, reaction time, US energy intensity, initial TOC concentration, and the molar ratio of iron to hydrogen peroxide that might affect the treatment efficiency were investigated. The removal of TOC, COD, and color increased with decreasing pH and increasing temperature and US intensity. Color was removed rapidly reaching 85% in 10 min; whereas TOC and COD were removed slowly, only about 20% for both in 10 min and approaching 65 and 92% removal in 120 min, respectively. The optimal molar ratio of Fe(II) to H(2)O(2) for TOC and COD removal was 500. The results showed that the change in the average carbon oxidation number (ACON) was parallel to that of the removal efficiency of TOC, COD, and color. The toxicity of treated wastewater was reduced as assessed by the respiration rate of Escherichia coli. PMID:23274940

  6. Fenton-treated functionalized diamond nanoparticles as gene delivery system.

    PubMed

    Martín, Roberto; Alvaro, Mercedes; Herance, José Raúl; García, Hermenegildo

    2010-01-26

    When raw diamond nanoparticles (Dnp, 7 nm average particle size) obtained from detonation are submitted to harsh Fenton-treatment, the resulting material becomes free of amorphous soot matter and the process maintains the crystallinity, reduces the particle size (4 nm average particle size), increases the surface OH population, and increases water solubility. All these changes are beneficial for subsequent Dnp covalent functionalization and for the ability of Dnp to cross cell membranes. Fenton-treated Dnps have been functionalized with thionine and the resulting sample has been observed in HeLa cell nuclei. A triethylammonium-functionalized Dnp pairs electrostatically with a plasmid having the green fluorescent protein gene and acts as gene delivery system permitting the plasmid to cross HeLa cell membrane, something that does not occur for the plasmid alone without assistance of polycationic Dnp. PMID:20047335

  7. Enhancement of activated sludge disintegration and dewaterability by Fenton process

    NASA Astrophysics Data System (ADS)

    Heng, G. C.; Isa, M. H.

    2016-06-01

    Municipal and industrial wastewater treatment plants produce large amounts of sludge. This excess sludge is an inevitable drawback inherent to the activated sludge process. In this study, the waste activated sludge was obtained from the campus wastewater treatment plant at Universiti Teknologi PETRONAS (UTP), Malaysia. Fenton pretreatment was optimized by using the response surface methodology (RSM) to study the effects of three operating conditions including the dosage of H2O2 (g H2O2/kg TS), the molar ratio of H2O2/Fe2+ and reaction time. The optimum operating variables to achieve MLVSS removal 65%, CST reduction 28%, sCOD 11000 mg/L and EPS 500 mg/L were: 1000 g H2O2/kg TS, H2O2/Fe2+ molar ratio 70 and reaction time 45 min. Fenton process was proved to be able to enhance the sludge disintegration and dewaterability.

  8. The Turn for Ultimate Harm: A Reply to Fenton

    PubMed Central

    Persson, Ingmar; Savulescu, Julian

    2011-01-01

    Elizabeth Fenton has criticized an earlier article of ours in which we claim that, by providing humankind with means of causing its destruction, the advance of science and technology has put it in a perilous condition which it might take the development of genetic or biomedical techniques of moral enhancement to get out of. The development of these techniques would however require further scientific advances, thus forcing humanity deeper into the danger zone created by modern science. Fenton argues that we undervalue the benefits of scientific advances. We believe that our argument rather relies upon attaching a special weight to even very slight risks of major catastrophes, and attempt to vindicate this weighting. PMID:21343630

  9. Cytotoxicity of Doxycycline Effluent Generated by the Fenton Process

    PubMed Central

    Borghi, Alexandre Augusto; Stephano, Marco Antônio; Monteiro de Souza, Paula; Alves Palma, Mauri Sérgio

    2014-01-01

    This study aims at determining the Minimum Inhibitory Concentration with Escherichia coli ATCC 25922 and cytotoxicity to L929 cells (ATCC CCL-1) of the waste generated by doxycycline degradation by the Fenton process. This process has shown promise in this treatment thanks mainly to the fact that the waste did not show any relevant inhibitory effect on the test organism and no cytotoxicity to L-929 cells, thus demonstrating that the antibiotic properties were inactivated. PMID:25379532

  10. 7. Detail of balcony rail. August 1936. Joseph Hill, photographer, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    7. Detail of balcony rail. August 1936. Joseph Hill, photographer, copied from small photo taken by survey member. - Jansonist Colony, Steeple Building, Main & Bishop Hill Streets, Bishop Hill, Henry County, IL

  11. 6. Detail of pilaster cap. Aug. 10, 1936. Joseph Hill, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Detail of pilaster cap. Aug. 10, 1936. Joseph Hill, photographer, copied from small photo taken by survey member. - Jansonist Colony, Steeple Building, Main & Bishop Hill Streets, Bishop Hill, Henry County, IL

  12. 3. West and south elevations. Joseph Hill, photographer, copied from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. West and south elevations. Joseph Hill, photographer, copied from photo lent by Evelyn S. Craig. August 1936. - Jansonist Colony, Steeple Building, Main & Bishop Hill Streets, Bishop Hill, Henry County, IL

  13. 1. Historic American Buildings Survey Joseph Hill, Photographer August 1936 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Historic American Buildings Survey Joseph Hill, Photographer August 1936 FIRST ORIGINAL STORE AND POSTOFFICE, COPY OF AN EARLY PHOTOGRAPH. LENT BY EVELYN S. CRAIG - Jansonist Colony, Colony Store & Post Office, Main & Bishop Hill Streets, Bishop Hill, Henry County, IL

  14. Identification and application of Phyto-Fenton reactions.

    PubMed

    Inagaki, Yoshihiko; Cong, Vo Huu; Sakakibara, Yutaka

    2016-02-01

    The formation of hydroxyl radicals (•OHs) by aquatic plants was investigated using electron-spin-resonance (ESR) spectroscopy and fluorescence microscopy. ESR observations, using 5- (diethoxyphosphoryl)-5-methyl-pyrroline N-oxide as a trapping agent, indicated that the signals produced by aquatic plants ground with ferrous iron ions are almost identical to those produced by Fenton's reagent. In addition, fluorescence was observed in the oxidized form of aminophenyl fluorescein in the presence of ferrous ions as well as any particles of colloidal ferrihydrite, magnetite, and ferric-ion-exchanged zeolite, while no fluorescence appeared in the absence of these iron compounds. Moreover, fluorescence-microscopy observations demonstrated that fluorescence mainly occurs on the surface of aquatic plants at neutral pH in the presence of the latter three solid iron compounds, implying the occurrence of heterogeneous phyto-Fenton reactions utilizing endogenous hydrogen peroxide (H2O2) in the aquatic plants. Furthermore, batch treatments of the pollutant 17α-ethinylestradiol (EE2), using colloidal ferrihydrite iron, indicated the feasible removal of EE2 with enhanced performance, lower-or apparently no-consumption of endogenous H2O2, and no significant stress to the aquatic plants. We concluded that the treatment of environmental pollutants through •OH formations via heterogeneous phyto-Fenton reactions should be a feasible alternative to conventional wastewater and water-treatment processes. PMID:26495829

  15. Efficiency and toxicity: comparison between the Fenton and electrochemical processes.

    PubMed

    Tavares, Marcela Gomes; Santos, Danilo Henrique da Silva; Torres, Sheyla Jaqueline Albuquerque; Pimentel, Wagner Roberto Oliveira; Tonholo, Josealdo; Zanta, Carmem Lucia de Paiva E Silva

    2016-01-01

    This study aimed to determine the best method to treat a textile effluent containing the dye basic blue 99 (BB). Treatments by the electrochemical and the Fenton processes were compared by means of a 2(3) experimental design, and the interaction of experimental conditions for BB oxidation were determined. The electrochemical treatment gave better results in the presence of NaCl as electrolyte and high current density (30 mA cm(-2)); the Fenton reaction provided better results at H2O2 and Fe(2+) concentrations of 10 mg L(-1) and 0.5 mmol L(-1), respectively. Electrochemical treatment was 23 times faster than the Fenton reaction because formation of chlorinated species during electrooxidation significantly contributed to dye oxidation. Although the electrochemical process was more efficient, the resulting treated effluent was more toxic to Lactuca sativa germination and growth, which indicated some biotoxicity. Results demonstrated that both processes efficiently remediated effluents containing the dye BB, but they need to be combined with other processes to ensure complete adequacy of the effluent for disposal. PMID:27642834

  16. The "House" in Half Hollow Hills

    ERIC Educational Resources Information Center

    Karnilow, Sheldon

    2006-01-01

    In this article, the author relates how he initiated a systemic improvement to Half Hollow Hills school district when he became its superintendent. He relates that although he came to Half Hollow Hills with a deep understanding of the models of systemic change, he did not bring with him a specific prescriptive plan for improvement. His plan for…

  17. Counseling Uses of the Hill Interaction Matrix.

    ERIC Educational Resources Information Center

    Boyd, Robert E.

    While the Hill Interaction Matrix was developed as a research instrument to assess interview process, it is also generally useful in any undertaking requiring the evaluation of verbal interaction and, hence, can be used as an aid in modifying communication in order to increase its therapeutic effect. The Hill Interaction Matrix with accompanying…

  18. Glaciated appalachian plateau: till shadows on hills.

    PubMed

    Coates, D R

    1966-06-17

    North slopes are twice as steep as south slopes on the hills of central New York. This asymmetry is caused by unequal till thickness-3.6 meters on north slopes and 27.6 meters on south slopes. Previous workers interpreted the hills as being of bedrock sculptured by glacial erosion, with till 0.9 to 3 meters thick.

  19. Leslie Pickney Hill's "Toussaint L'Ouverture."

    ERIC Educational Resources Information Center

    Ako, Edward O.

    1987-01-01

    In his 1928 play, the Harlem Renaissance writer Leslie Pickney Hill portrays Toussaint L'Ouverture, the leader of the Haitian slave rebellion, with historical accuracy. Hill's presentation was aimed at rehabilitating black pride, "A worthy literature reared upon authentic records of achievement is the present spiritual need of the race." (BJV)

  20. Colleges as Shining Cities on a Hill

    ERIC Educational Resources Information Center

    Townsend, Kathleen Kennedy

    2012-01-01

    In this article, the author proposes that the notion of America be reintroduced as the "shining city on a hill," that abiding image from American history. The image of the shining city on a hill captures the imagination because it reflects the abiding truth that people become fully human in society, not outside of it. People need one another to…

  1. Report on the Black Hills Alliance.

    ERIC Educational Resources Information Center

    Ryan, Joe

    1979-01-01

    A rally to save the Black Hills from coal- and uranium-greedy energy companies was held on July 6 and over 2,000 joined in a 15-mile walk on July 7 in Rapid City, South Dakota. The Black Hills Alliance, an Indian coalition concerned about energy development proposals in the Great Plains, sponsored the gathering. (NQ)

  2. Tolerance and efficacy of preoperative intracavitary HDR brachytherapy in IB and IIA cervical cancer

    PubMed Central

    Bialas, Brygida; Fijalkowski, Marek; Raczek-Zwierzycka, Katarzyna

    2009-01-01

    Purpose The aim of this work is to analyze the efficacy and tolerance of preoperative intracavitary HDR brachytherapy (HDR-BT) in patients with IB and IIA cervical cancer. Material and methods 139 patients with cervical cancer IB-IIA with preoperative HDR-BT, out of which 60 patients with cervical cancer IB (43.2%) and 79 with IIA (56.8%) were treated since 1996 to 2002. In preoperative BT total dose to point A ranged from 30-45 Gy in 6-9 fractions twice a week. The fraction dose was 4-5 Gy at point A. Six weeks after BT all patients underwent radical Wertheim-Meigs hysterectomy. Patients with disadvantageous risk factors or with positive specimen histology had a complementary therapy: external-beam radiotherapy (EBRT) given to the whole pelvic volume in daily fractions of 2 Gy up to total dose of 36-52 Gy (20 patients) or EBRT with cisplatin-based chemotherapy with the dose of 30-40 mg/m2 in 5-7 fractions given weekly (7 patients) or chemotherapy (6 patients). Acute and late radiation toxicity was evaluated according to EORTC/RTOG. Results In postoperative specimen histopathology the number of 114 women (82%) had tumor-free specimen within brachytherapy target (in cervix and cavity), 96 women (60.1%) had tumor-free specimen both in and outside brachytherapy target (lymph nodes, parametra, adnexis). The 5-year and 10-year DFS were 93.8% and 88% for IB and 89.7% and 64.7% for IIA respectively. 7.9% of patients developed acute toxicity both in rectum and bladder (only in I and II grade of EORTC/RTOG). Late severe complication occurred in rectum in 2.2% of patients and in bladder 1.4%. Conclusions 1. Preoperative HDR-BT in patients with IB and IIA cervical cancer is an effective and well tolerated therapy with acceptable rate of side effects. 2. Preoperative HDR-BT followed by surgery in a group without risk factors is a sufficient treatment option with no additional adjuvant therapy requirement.

  3. Source geometry factors for HDR ¹⁹²Ir brachytherapy secondary standard well-type ionization chamber calibrations.

    PubMed

    Shipley, D R; Sander, T; Nutbrown, R F

    2015-03-21

    Well-type ionization chambers are used for measuring the source strength of radioactive brachytherapy sources before clinical use. Initially, the well chambers are calibrated against a suitable national standard. For high dose rate (HDR) (192)Ir, this calibration is usually a two-step process. Firstly, the calibration source is traceably calibrated against an air kerma primary standard in terms of either reference air kerma rate or air kerma strength. The calibrated (192)Ir source is then used to calibrate the secondary standard well-type ionization chamber. Calibration laboratories are usually only equipped with one type of HDR (192)Ir source. If the clinical source type is different from that used for the calibration of the well chamber at the standards laboratory, a source geometry factor, k(sg), is required to correct the calibration coefficient for any change of the well chamber response due to geometric differences between the sources. In this work we present source geometry factors for six different HDR (192)Ir brachytherapy sources which have been determined using Monte Carlo techniques for a specific ionization chamber, the Standard Imaging HDR 1000 Plus well chamber with a type 70010 HDR iridium source holder. The calculated correction factors were normalized to the old and new type of calibration source used at the National Physical Laboratory. With the old Nucletron microSelectron-v1 (classic) HDR (192)Ir calibration source, ksg was found to be in the range 0.983 to 0.999 and with the new Isodose Control HDR (192)Ir Flexisource k(sg) was found to be in the range 0.987 to 1.004 with a relative uncertainty of 0.4% (k = 2). Source geometry factors for different combinations of calibration sources, clinical sources, well chambers and associated source holders, can be calculated with the formalism discussed in this paper.

  4. High dynamic range adaptive real-time smart camera: an overview of the HDR-ARTiST project

    NASA Astrophysics Data System (ADS)

    Lapray, Pierre-Jean; Heyrman, Barthélémy; Ginhac, Dominique

    2015-04-01

    Standard cameras capture only a fraction of the information that is visible to the human visual system. This is specifically true for natural scenes including areas of low and high illumination due to transitions between sunlit and shaded areas. When capturing such a scene, many cameras are unable to store the full Dynamic Range (DR) resulting in low quality video where details are concealed in shadows or washed out by sunlight. The imaging technique that can overcome this problem is called HDR (High Dynamic Range) imaging. This paper describes a complete smart camera built around a standard off-the-shelf LDR (Low Dynamic Range) sensor and a Virtex-6 FPGA board. This smart camera called HDR-ARtiSt (High Dynamic Range Adaptive Real-time Smart camera) is able to produce a real-time HDR live video color stream by recording and combining multiple acquisitions of the same scene while varying the exposure time. This technique appears as one of the most appropriate and cheapest solution to enhance the dynamic range of real-life environments. HDR-ARtiSt embeds real-time multiple captures, HDR processing, data display and transfer of a HDR color video for a full sensor resolution (1280 1024 pixels) at 60 frames per second. The main contributions of this work are: (1) Multiple Exposure Control (MEC) dedicated to the smart image capture with alternating three exposure times that are dynamically evaluated from frame to frame, (2) Multi-streaming Memory Management Unit (MMMU) dedicated to the memory read/write operations of the three parallel video streams, corresponding to the different exposure times, (3) HRD creating by combining the video streams using a specific hardware version of the Devebecs technique, and (4) Global Tone Mapping (GTM) of the HDR scene for display on a standard LCD monitor.

  5. Solar Rossby Wave 'Hills' Identified As Supergranules

    NASA Technical Reports Server (NTRS)

    Williams, P. E.; Hathaway, David H.; Cuntz, M.

    2007-01-01

    We explore the nature of 'hills' observed on the solar surface which had previously been attributed to Rossby waves. We investigate the sol ar hills phenomenon by analyzing the output from a synthetic model ba sed solely on the observed solar photospheric convection spectrum. We show that the characteristics of these hills can be explained by the corrugation of the surface produced by the radial flows of the conve ction. The hills in our simulations are dominated by supergranules, a well-known component of solar convection. Rossby waves have been predicted to exist within the Sun and may play an important role in the d ynamics of the solar interior, including the Sun's differential rotat ion and magnetic dynamo. Our study suggests, however, that the hills observed at the solar limb do not confirm the existence of solar Ross by waves.

  6. Layered Rocks in 'Columbia Hills'

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This black-and-white image shows the first layered rocks scientists have seen close up in Gusev Crater, where NASA's Mars Exploration Rover Spirit landed Jan. 4, 2004. While Spirit's twin rover, Opportunity, reached the stadium-size Endurance Crater on the other side of Mars and began exploring its many layered outcrops in early May, Spirit traveled more than 3.5 kilometers (2.2 miles) to get to this layered bedrock in the 'Columbia Hills.' Scientists are planning to conduct a study of these rocks to determine if they are volcanic or sedimentary in origin, and if they have been chemically altered. Spirit's panoramic camera took this image on sol 217 (Aug. 13, 2004).

  7. Particle Size Effects on Fenton Regeneration of MTBE-spent Activated Carbon

    EPA Science Inventory

    Fenton-driven regeneration of spent granular activated carbon (GAC) is a developing technology that may reduce water treatment costs. In this study, the effect of GAC particle size on Fenton-driven oxidation of methyl tert-butyl ether (MTBE)-spent GAC was evaluated. The GAC was...

  8. POLYNUCLEAR AROMATIC HYDROCARBON (PAH) RELEASE FROM SOIL DURING TREATMENT WITH FENTON'S REAGENT

    EPA Science Inventory

    Fenton's Reagent was used to treat soil from a wood-treating site in southeastern Ohio which had been contaminated with creosote. Slurries, consisting of 10 µg of contaminated soil and 30 mL water were treated with 40 mL of Fenton's Reagent (1:1 of 30% H2O2 ...

  9. COMPARISON OF MINERAL AND SOLUBLE IRON FENTON'S CATALYSTS FOR THE TREATMENT OF TRICHLOROETHYLENE. (R826163)

    EPA Science Inventory

    Abstract

    Contaminant degradation, stoichiometry, and role of hydroxyl radicals (OH·) in four Fenton's systems were investigated using trichloroethylene (TCE) as a model contaminant. A standard Fenton's system, a modified soluble iron system with a...

  10. Stable carbon isotope fractionation during trichloroethene degradation in magnetite-catalyzed Fenton-like reaction.

    PubMed

    Liu, Yunde; Zhou, Aiguo; Gan, Yiqun; Liu, Cunfu; Yu, Tingting; Li, Xiaoqian

    2013-02-01

    Mineral-catalyzed Fenton-like oxidation of chlorinated ethylenes is an attractive technique for in situ soil and groundwater remediation. Stable carbon isotope enrichment factors associated with magnetite-catalyzed Fenton-like oxidation of trichloroethylene (TCE) have been determined, to study the possibility of applying stable carbon isotope analysis as a technique to assess the efficacy of remediation implemented by Fenton-like oxidation. The carbon enrichment factors (ε values) ranged from -2.7‰ to -3.6‰ with a mean value of -3.3±0.3‰, and only small differences were observed for different initial reactive conditions. The ε values were robust and reproducible, and were relatively insensitive to a number of environmental factors such as ratios of reactants and PCE co-contamination, which can reduce the uncertainty associated with application of isotope enrichment factors for quantification of in situ remediation by Fenton-like reaction. ε values for Fenton-like oxidation of TCE were intermediate in those previously reported for aerobic biological processes (ε=-1.1 to -20.7‰). Thus, field-derived ε values that are more negative than those for Fenton-like oxidation, may indicate the occurrence of aerobic biodegradation at contaminated sites undergoing in situ remediation with Fenton-like reaction. However, stable carbon isotope analysis is unable to determine whether there is the occurrence of biodegradation processes if field-derived ε values are less negative than those for Fenton-like oxidation.

  11. Application of Fenton's reagent as a pretreatment step in biological degradation of polyaromatic hydrocarbons

    SciTech Connect

    Kelley, R.L.; Gauger, W.K.; Srivastava, V.J.

    1990-01-01

    Fenton's reagent (H{sub 2}O{sub 2} and Fe{sup ++}) has been used for chemical oxidation of numerous organic compounds in water treatment schemes. In this study, the Institute of Gas Technology (IGT) applied Fenton's treatment to polynuclear aromatic hydrocarbons (PAHs) and PAH-contaminated soils. Fenton's treatment was very reactive with PAHs, causing rapid modification of the parental compounds to oxidized products and complete degradation to CO{sub 2}. This treatment was more effective on chemically reactive PAHs, such as benzo(a)pyrene and phenanthrene. Important parameters and conditions for Fenton's treatment of PAHs in solution and soil matrices have been identified. As much as 99% of the PAHs on soil matrices can be removed by treatment with Fenton's reagent. 28 refs., 13 figs., 1 tab.

  12. Descent from the Summit of 'Husband Hill'

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Click on the image for Descent from the Summit of 'Husband Hill' (QTVR)

    In late November 2005 while descending 'Husband Hill,' NASA's Mars Exploration Rover Spirit took the most detailed panorama so far of the 'Inner Basin,' the rover's next target destination. Spirit acquired the 405 individual images that make up this 360-degree view of the surrounding terrain using five different filters on the panoramic camera. The rover took the images on Martian days, or sols, 672 to 677 (Nov. 23 to 28, 2005 -- the Thanksgiving holiday weekend).

    This image is an approximately true-color rendering using camera's 750-, 530-, and 430-nanometer filters. Seams between individual frames have been eliminated from the sky portion of the mosaic to better simulate the vista a person standing on Mars would see.

    'Home Plate,' a bright, semi-circular feature scientists hope to investigate, is harder to discern in this image than in earlier views taken from higher up the hill. Spirit acquired this more oblique view, known as the 'Seminole panorama,' from about halfway down the south flank of Husband Hill, 50 meters (164 feet) or so below the summit. Near the center of the panorama, on the horizon, are 'McCool Hill' and 'Ramon Hill,' named, like Husband Hill, in honor of the fallen astronauts of the space shuttle Columbia. Husband Hill is visible behind the rover, on the right and left sides of the panorama. An arc of rover tracks made while avoiding obstacles and getting into position to examine rock outcrops can be traced over a long distance by zooming in to explore the panorama in greater detail.

    Spirit is now significantly farther downhill toward the center of this panorama, en route to Home Plate and other enigmatic soils and outcrop rocks in the quest to uncover the history of Gusev Crater and the 'Columbia Hills.'

  13. Enhancement of Fenton and photo-Fenton processes at initial circumneutral pH for the degradation of the β-blocker metoprolol.

    PubMed

    Romero, V; Acevedo, S; Marco, P; Giménez, J; Esplugas, S

    2016-01-01

    The need for acidification in the Fenton and photo-Fenton process is often outlined as one of its major drawbacks, thus in this work the acidification of the Metoprolol (MET) is avoided by the addition of resorcinol (RES), which is used to simulate model organic matter. The experiments were carried out at natural pH (6.2) with different Fe(2+) (1, 2.5, 5, and 10 mg/L) and H2O2 (25, 50, 125 and 150 mg/L) concentrations. The performance of MET and RES degradation was assessed along the reaction time. Working with the highest concentrations (5 and 10 mg/L of ferrous iron and 125 and 150 mg/L of H2O2) more than 90% of MET and RES removals were reached within 50 and 20 min of treatment, respectively, by Fenton process. However a low mineralization was achieved in both cases, likely, due to by-products accumulation. Regarding to photo-Fenton process, within 3 min with the highest iron and hydrogen peroxide concentrations, a complete MET degradation was obtained and 95% of RES conversion was achieved. Parameters such Total Organic Carbon, Chemical Oxygen Demand, and AOS were measured. Intermediates were identified and MET degradation path was proposed in the presence of resorcinol. Finally, a comparison between Fenton and photo-Fenton processes at acid pH and at initial circumneutral pH was discussed. The positive effect of RES on Fenton and photo-Fenton systems has been confirmed, allowing the work at circumneutral pH.

  14. Removal of refractory organics in nanofiltration concentrates of municipal solid waste leachate treatment plants by combined Fenton oxidative-coagulation with photo--Fenton processes.

    PubMed

    Li, Jiuyi; Zhao, Lei; Qin, Lele; Tian, Xiujun; Wang, Aimin; Zhou, Yanmei; Meng, Liao; Chen, Yong

    2016-03-01

    Removal of the refractory organic matters in leachate brines generated from nanofiltration unit in two full-scale municipal solid waste landfill leachate treatment plants was investigated by Fenton oxidative-coagulation and ultraviolet photo - Fenton processes in this study. Fenton oxidative-coagulation was performed under the condition of an initial pH of 5.0 and low H2O2/Fe(2+) ratios. After precipitate separation, the remaining organic constituents were further oxidized by photo - Fenton process. For both leachate brines with varying pollution strength, more than 90% COD and TOC reductions were achieved at H2O2/Fe(2+) dosages of 35 mM/8 mM and 90 mM/10 mM, respectively. The effluent COD ranged 120-160 mg/L under the optimal operating conditions, and the biodegradability was increased significantly. Fenton oxidative-coagulation was demonstrated to contribute nearly 70% overall removal of organic matters. In the combined processes, the efficiency of hydrogen peroxide varied from 216 to 228%, which may significantly reduce the operating cost of conventional Fenton method. Six phthalic acid esters and thirteen polycyclic aromatic hydrocarbons were found in leachate brines, and, on the average, around 80% phthalic acid esters and 90% polycyclic aromatic hydrocarbons were removed by the combined treatments.

  15. Removal of refractory organics in nanofiltration concentrates of municipal solid waste leachate treatment plants by combined Fenton oxidative-coagulation with photo--Fenton processes.

    PubMed

    Li, Jiuyi; Zhao, Lei; Qin, Lele; Tian, Xiujun; Wang, Aimin; Zhou, Yanmei; Meng, Liao; Chen, Yong

    2016-03-01

    Removal of the refractory organic matters in leachate brines generated from nanofiltration unit in two full-scale municipal solid waste landfill leachate treatment plants was investigated by Fenton oxidative-coagulation and ultraviolet photo - Fenton processes in this study. Fenton oxidative-coagulation was performed under the condition of an initial pH of 5.0 and low H2O2/Fe(2+) ratios. After precipitate separation, the remaining organic constituents were further oxidized by photo - Fenton process. For both leachate brines with varying pollution strength, more than 90% COD and TOC reductions were achieved at H2O2/Fe(2+) dosages of 35 mM/8 mM and 90 mM/10 mM, respectively. The effluent COD ranged 120-160 mg/L under the optimal operating conditions, and the biodegradability was increased significantly. Fenton oxidative-coagulation was demonstrated to contribute nearly 70% overall removal of organic matters. In the combined processes, the efficiency of hydrogen peroxide varied from 216 to 228%, which may significantly reduce the operating cost of conventional Fenton method. Six phthalic acid esters and thirteen polycyclic aromatic hydrocarbons were found in leachate brines, and, on the average, around 80% phthalic acid esters and 90% polycyclic aromatic hydrocarbons were removed by the combined treatments. PMID:26741550

  16. Hill-Climbing Attacks and Robust Online Signature Verification Algorithm against Hill-Climbing Attacks

    NASA Astrophysics Data System (ADS)

    Muramatsu, Daigo

    Attacks using hill-climbing methods have been reported as a vulnerability of biometric authentication systems. In this paper, we propose a robust online signature verification algorithm against such attacks. Specifically, the attack considered in this paper is a hill-climbing forged data attack. Artificial forgeries are generated offline by using the hill-climbing method, and the forgeries are input to a target system to be attacked. In this paper, we analyze the menace of hill-climbing forged data attacks using six types of hill-climbing forged data and propose a robust algorithm by incorporating the hill-climbing method into an online signature verification algorithm. Experiments to evaluate the proposed system were performed using a public online signature database. The proposed algorithm showed improved performance against this kind of attack.

  17. Radiochromic film dosimetry of HDR {sup 192}Ir source radiation fields

    SciTech Connect

    Aldelaijan, Saad; Mohammed, Huriyyah; Tomic, Nada; Liang Liheng; DeBlois, Francois; Sarfehnia, Arman; Abdel-Rahman, Wamied; Seuntjens, Jan; Devic, Slobodan

    2011-11-15

    Purpose: A radiochromic film based dosimetry system for high dose rate (HDR) Iridium-192 brachytherapy source was described. A comparison between calibration curves established in water and Solid Water was provided. Methods: Pieces of EBT-2 model GAFCHROMIC film were irradiated in both water and Solid Water with HDR {sup 192}Ir brachytherapy source in a dose range from 0 to 50 Gy. Responses of EBT-2 GAFCHROMIC film were compared for irradiations in water and Solid Water by scaling the dose between media through Monte Carlo calculated conversion factor for both setups. To decrease uncertainty in dose delivery due to positioning of the film piece with respect to the radiation source, traceable calibration irradiations were performed in a parallel-opposed beam setup. Results: The EBT-2 GAFCHROMIC film based dosimetry system described in this work can provide an overall one-sigma dose uncertainty of 4.12% for doses above 1 Gy. The ratio of dose delivered to the sensitive layer of the film in water to the dose delivered to the sensitive layer of the film in Solid Water was calculated using Monte Carlo simulations to be 0.9941 {+-} 0.0007. Conclusions: A radiochromic film based dosimetry system using only the green color channel of a flatbed document scanner showed superior precision if used alone in a dose range that extends up to 50 Gy, which greatly decreases the complexity of work. In addition, Solid Water material was shown to be a viable alternative to water in performing radiochromic film based dosimetry with HDR {sup 192}Ir brachytherapy sources.

  18. Characterization of GATA3 mutations in the hypoparathyroidism, deafness, and renal dysplasia (HDR) syndrome.

    PubMed

    Nesbit, M Andrew; Bowl, Michael R; Harding, Brian; Ali, Asif; Ayala, Alejandro; Crowe, Carol; Dobbie, Angus; Hampson, Geeta; Holdaway, Ian; Levine, Michael A; McWilliams, Robert; Rigden, Susan; Sampson, Julian; Williams, Andrew J; Thakker, Rajesh V

    2004-05-21

    The hypoparathyroidism, deafness, and renal dysplasia (HDR) syndrome is an autosomal dominant disorder caused by mutations of the dual zinc finger transcription factor, GATA3. The C-terminal zinc finger (ZnF2) binds DNA, whereas the N-terminal finger (ZnF1) stabilizes this DNA binding and interacts with other zinc finger proteins, such as the Friends of GATA (FOG). We have investigated seven HDR probands and their families for GATA3 abnormalities and have identified two nonsense mutations (Glu-228 --> Stop and Arg-367 --> Stop); two intragenic deletions that result in frameshifts from codons 201 and 355 with premature terminations at codons 205 and 370, respectively; one acceptor splice site mutation that leads to a frameshift from codon 351 and a premature termination at codon 367; and two missense mutations (Cys-318 --> Arg and Asn-320 --> Lys). The functional effects of these mutations, together with a previously reported GATA3 ZnF1 mutation and seven other engineered ZnF1 mutations, were assessed by electrophoretic mobility shift, dissociation, yeast two-hybrid and glutathione S-transferase pull-down assays. Mutations involving GATA3 ZnF2 or adjacent basic amino acids resulted in a loss of DNA binding, but those of ZnF1 either lead to a loss of interaction with specific FOG2 ZnFs or altered DNA-binding affinity. These findings are consistent with the proposed three-dimensional model of ZnF1, which has separate DNA and protein binding surfaces. Thus, our results, which expand the spectrum of HDR-associated GATA3 mutations and report the first acceptor splice site mutation, help to elucidate the molecular mechanisms that alter the function of this zinc finger transcription factor and its role in causing this developmental anomaly. PMID:14985365

  19. Is there any place for LDR brachytherapy for head and neck carcinomas in HDR era?

    PubMed Central

    2009-01-01

    In Poland, the classical LDR brachytherapy for head and neck carcinomas with Ir-192 wires or hairpins has completely disappeared some time ago after 30 years of successful clinical use. Can this technique be fully and safely replaced by HDR or PDR application? This option seems attractive because of new possibilities of 3D reconstruction and computer real-time treatment planning and optimization. However, in my opinion, long time is needed to get a clinical and scientific experience that has been accumulated for decades with the use of LDR technique.

  20. Verification of computerized treatment planning for HDR 192Ir brachytherapy for gynaecological cancer.

    PubMed

    Buzdar, Saeed Ahmad; Gadhi, Muhammad Asghar; Rao, Muhammad Afzal; Laghari, Naeem Ahmad; Anees, Mohammad

    2009-02-01

    Treatment planning in both teletherapy and brachytherapy is time consuming practice but accurate determination of planning parameters is more important. This paper aims to verify the dose delivery time for the treatment of vaginal cancer, which is a vital parameter of High Dose Rate (HDR) brachytherapy treatment planning. Treatment time has been calculated by the computerized treatment planning system (ABACUS 3.1), and then it has been compared with the manually calculated time. The results obtained are in good agreement. Independent verification of nominal time by two different protocols assures the quality of treatment. This should always be practiced to increase the accuracy of treatment.

  1. Salvage high-dose-rate (HDR) brachytherapy for recurrent head-and-neck cancer

    SciTech Connect

    Hepel, Jaroslaw T.; Syed, A.M. Nisar . E-mail: bvigil@memnet.org; Puthawala, Ajmel; Sharma, Anil; Frankel, Paul

    2005-08-01

    Background: A significant portion of head-and-neck cancer patients will develop persistent or recurrent disease after definitive treatment. Radiation therapy is often used as definitive therapy or as an adjunct to surgery. Recurrent cancer of the head and neck in the previously irradiated field is, thus, a common occurrence and poses a therapeutic challenge. Some studies have evaluated low-dose-rate (LDR) brachytherapy as a therapeutic option, including a large case series with long-term follow-up by our own institution. High-dose-rate (HDR) brachytherapy offers therapeutic advantages over LDR brachytherapy. This study evaluates the local control and outcomes of patients with previously irradiated recurrent head-and-neck cancer treated with HDR interstitial brachytherapy. Methods and Materials: Between 1997 and 2002, 30 patients who received prior radiation therapy for primary tumors of the head and neck were treated for biopsy-proven recurrent disease. All patients received previous radiation as definitive therapy alone or as adjunct to surgery. All patients were inoperable, refused surgery, or had gross residual disease after salvage surgery for their recurrent disease. Thirty-six sites on the 30 patients were implanted by application of high-dose-rate interstitial brachytherapy techniques with mean tumor dose of 34 Gy (18-48 Gy) in twice daily fractions of 300 to 400cGy per fraction. Results: At a minimum follow-up of 12 months, local tumor control was achieved in 69% of implanted sites. Disease-specific survival at 1 and 2 years was 54% and 45%, respectively. Overall survival at 1 and 2 years was 56% and 37%, respectively. Grade 3/4 late complications occurred in 16% of the patients. No fatal complications occurred. Conclusion: HDR brachytherapy can play an important role in the salvage treatment of previously irradiated recurrent head-and-neck cancer. This study shows that comparable results are obtained by HDR brachytherapy with fewer late complications than

  2. Inside Beacon Hill: Bertrand Russell as Schoolmaster.

    ERIC Educational Resources Information Center

    Jespersen, Shirley

    1987-01-01

    The author describes the life and theories of Bertrand Russell, founder of Beacon Hill School. Russell's educational theories centered on the personal autonomy of the student and democratization of the learning process. (CH)

  3. MO-C-17A-11: A Segmentation and Point Matching Enhanced Deformable Image Registration Method for Dose Accumulation Between HDR CT Images

    SciTech Connect

    Zhen, X; Chen, H; Zhou, L; Yan, H; Jiang, S; Jia, X; Gu, X; Mell, L; Yashar, C; Cervino, L

    2014-06-15

    Purpose: To propose and validate a novel and accurate deformable image registration (DIR) scheme to facilitate dose accumulation among treatment fractions of high-dose-rate (HDR) gynecological brachytherapy. Method: We have developed a method to adapt DIR algorithms to gynecologic anatomies with HDR applicators by incorporating a segmentation step and a point-matching step into an existing DIR framework. In the segmentation step, random walks algorithm is used to accurately segment and remove the applicator region (AR) in the HDR CT image. A semi-automatic seed point generation approach is developed to obtain the incremented foreground and background point sets to feed the random walks algorithm. In the subsequent point-matching step, a feature-based thin-plate spline-robust point matching (TPS-RPM) algorithm is employed for AR surface point matching. With the resulting mapping, a DVF characteristic of the deformation between the two AR surfaces is generated by B-spline approximation, which serves as the initial DVF for the following Demons DIR between the two AR-free HDR CT images. Finally, the calculated DVF via Demons combined with the initial one serve as the final DVF to map doses between HDR fractions. Results: The segmentation and registration accuracy are quantitatively assessed by nine clinical HDR cases from three gynecological cancer patients. The quantitative results as well as the visual inspection of the DIR indicate that our proposed method can suppress the interference of the applicator with the DIR algorithm, and accurately register HDR CT images as well as deform and add interfractional HDR doses. Conclusions: We have developed a novel and robust DIR scheme that can perform registration between HDR gynecological CT images and yield accurate registration results. This new DIR scheme has potential for accurate interfractional HDR dose accumulation. This work is supported in part by the National Natural ScienceFoundation of China (no 30970866 and no

  4. A perspective on Capitol Hill

    NASA Astrophysics Data System (ADS)

    Hodges, Carroll Ann

    As the AGU Congressional Science Fellow for 1980-1981, I had a unique opportunity to witness the federal engine in action—a remarkable piece of machinery. The American Association for the Advancement of Science organized an excellent orientation program, introducing our class of science fellows (about 30) to the kinds of options available for a year's tenure on Capitol Hill. These include affiliation with a congressman's or senator's staff or with one of the hundred or so standing, select, or joint committees and subcommittees. I arranged to join the personal staff of Congressman Jim Santini (D, Nev.), largely because of his demonstrated interest in Department of Interior affairs in general and the minerals industry in particular. The position of fellow provides no guarantee of work in one's areas of expertise or inclination, however, and I found that my staff assignments included topics ranging from wild horses to peanut subsidies. My principal task involved evaluation of the Air Force proposal to deploy the MX missile in Nevada and the consequent impact of that incredible scheme on the physical and economic environments of the state and the nation, including effects on minerals exploration. I had not expected to become conversant with missile technology, but the exercise provided quite an education.

  5. The Igwisi Hills extrusive 'kimberlites'

    NASA Technical Reports Server (NTRS)

    Reid, A. M.; Donaldson, C. H.; Dawson, J. B.; Brown, R. W.; Ridley, W. I.

    1975-01-01

    The petrography and mineral chemistry of volcanic rocks from the Igwisi Hills in Tanzania are discussed. There is considerable evidence to suggest that the Igwisi rocks are extrusive kimberlites: a two-component nature with high P-T minerals in a low P-T matrix; the presence of chrome pyrope, Al enstatite, chrome diopside, chromite and olivine; a highly oxidized, volatile-rich matrix with serpentine, calcite, magnetite, perovskite; high Sr, Zr, and Nb contents; occurrence in a narrow isolated vent within a stable shield area. The Igwisi rocks differ from kimberlite in the lack of magnesian ilmenite, the scarcity of matrix phlogopite, and the overall low alkali content. They apparently contain material from phlogopite-bearing garnet peridotites with a primary mineral assemblage indicative of equilibrium at upper mantle temperatures and pressures. This primary assemblage was brought rapidly to the surface in a gas-charged, carbonate-rich fluid. Rapid upward transport, extrusion, and rapid cooling have tended to prevent reaction between inclusions and the carbonate-rich matrix that might otherwise have yielded a more typical kimberlite.

  6. Oblique View of Columbia Hills

    NASA Technical Reports Server (NTRS)

    2006-01-01

    [figure removed for brevity, see original site] Annotated Version

    This perspective view looking toward the northeast shows part of the Columbia Hills range inside Gusev Crater. At the center is the winter campaign site of NASA's Mars Exploration Rover Spirit.

    On its 805th Martian day, or sol, (April 8, 2006), Spirit was parked on a slope tilting 11 degrees to the north to maximize sunlight on the solar panels during the southern winter season. Science observations were formulated to take advantage of the long time during which the rover was parked. The plan focused on two tasks: tracking atmospheric and surface dynamics by periodically surveying the surface and atmosphere; and extensively examining surrounding terrains, rocks and soils using the panoramic camera and the miniature thermal emission spectrometer, coupled with long duration measurements using the alpha particle X-ray and Moessbauer spectrometers of rock and soil targets. For reference, the feature known as 'Home Plate' is approximately 90 meters (295 feet) wide.

    An image from Mars Global Surveyor's Mars Orbital Camera, catalogued as E03_00012 and courtesy Malin Space Science Systems, was used as the base image for this figure. The perspective was generated using elevation data generated from analyses of the camera's stereo images by the U.S. Geological Survey, Flagstaff, Ariz.

  7. Tertiary treatment of pulp mill wastewater by solar photo-Fenton.

    PubMed

    Lucas, Marco S; Peres, José A; Amor, Carlos; Prieto-Rodríguez, Lucía; Maldonado, Manuel I; Malato, Sixto

    2012-07-30

    This work reports on pulp mill wastewater (PMW) tertiary treatment by Fenton (Fe(2+)/H(2)O(2)) and solar photo-Fenton (Fe(2+)/H(2)O(2)/UV) processes in a pilot plant based on compound parabolic collectors (CPCs). Solar photo-Fenton reaction is much more efficient than the respective dark reaction under identical experimental conditions. It leads to DOC mineralisation, COD and total polyphenols (TP) removal higher than 90%. The solar photo-Fenton experiment with 5mg Fe L(-1) reaches 90% of DOC mineralisation with 31kJ L(-1) of UV energy and 50mM of H(2)O(2). The initial non-biodegradability of PMW, as shown by respirometry assays and BOD(5)/COD ratio, can be changed after a solar photo-Fenton treatment. Experiments with 20 and 50mg Fe L(-1) revealed that solar photo-Fenton can reach the same DOC degradation (90%), however, consuming less H(2)O(2) and time. Diluting the initial organic load to 50% also diminishes the dosage of H(2)O(2) and the necessary reaction time to achieve high DOC removals. Accordingly, solar photo-Fenton can be considered an alternative or complementary process to improve the performance of a biologic treatment and, subsequently, achieve legal limits on discharge into natural waters.

  8. Advanced Treatment of Pesticide-Containing Wastewater Using Fenton Reagent Enhanced by Microwave Electrodeless Ultraviolet.

    PubMed

    Cheng, Gong; Lin, Jing; Lu, Jian; Zhao, Xi; Cai, Zhengqing; Fu, Jie

    2015-01-01

    The photo-Fenton reaction is a promising method to treat organic contaminants in water. In this paper, a Fenton reagent enhanced by microwave electrodeless ultraviolet (MWEUV/Fenton) method was proposed for advanced treatment of nonbiodegradable organic substance in pesticide-containing biotreated wastewater. MWEUV lamp was found to be more effective for chemical oxygen demand (COD) removal than commercial mercury lamps in the Fenton process. The pseudo-first order kinetic model can well describe COD removal from pesticide-containing wastewater by MWEUV/Fenton, and the apparent rate constant (k) was 0.0125 min(-1). The optimal conditions for MWEUV/Fenton process were determined as initial pH of 5, Fe(2+) dosage of 0.8 mmol/L, and H2O2 dosage of 100 mmol/L. Under the optimal conditions, the reaction exhibited high mineralization degrees of organics, where COD and dissolved organic carbon (DOC) concentration decreased from 183.2 mg/L to 36.9 mg/L and 43.5 mg/L to 27.8 mg/L, respectively. Three main pesticides in the wastewater, as Dimethoate, Triazophos, and Malathion, were completely removed by the MWEUV/Fenton process within 120 min. The high degree of pesticides decomposition and mineralization was proved by the detected inorganic anions. PMID:26347877

  9. Advanced Treatment of Pesticide-Containing Wastewater Using Fenton Reagent Enhanced by Microwave Electrodeless Ultraviolet

    PubMed Central

    Cheng, Gong; Lin, Jing; Lu, Jian; Zhao, Xi; Cai, Zhengqing; Fu, Jie

    2015-01-01

    The photo-Fenton reaction is a promising method to treat organic contaminants in water. In this paper, a Fenton reagent enhanced by microwave electrodeless ultraviolet (MWEUV/Fenton) method was proposed for advanced treatment of nonbiodegradable organic substance in pesticide-containing biotreated wastewater. MWEUV lamp was found to be more effective for chemical oxygen demand (COD) removal than commercial mercury lamps in the Fenton process. The pseudo-first order kinetic model can well describe COD removal from pesticide-containing wastewater by MWEUV/Fenton, and the apparent rate constant (k) was 0.0125 min−1. The optimal conditions for MWEUV/Fenton process were determined as initial pH of 5, Fe2+ dosage of 0.8 mmol/L, and H2O2 dosage of 100 mmol/L. Under the optimal conditions, the reaction exhibited high mineralization degrees of organics, where COD and dissolved organic carbon (DOC) concentration decreased from 183.2 mg/L to 36.9 mg/L and 43.5 mg/L to 27.8 mg/L, respectively. Three main pesticides in the wastewater, as Dimethoate, Triazophos, and Malathion, were completely removed by the MWEUV/Fenton process within 120 min. The high degree of pesticides decomposition and mineralization was proved by the detected inorganic anions. PMID:26347877

  10. Degradation of Anthraquinone Dye Reactive Blue 4 in Pyrite Ash Catalyzed Fenton Reaction

    PubMed Central

    Becelic-Tomin, Milena; Dalmacija, Bozo; Rajic, Ljiljana; Tomasevic, Dragana; Kerkez, Djurdja; Watson, Malcolm; Prica, Miljana

    2014-01-01

    Pyrite ash (PA) is created by burning pyrite in the chemical production of sulphuric acid. The high concentration of iron oxide, mostly hematite, present in pyrite ash, gives the basis for its application as a source of catalytic iron in a modified Fenton process for anthraquinone dye reactive blue 4 (RB4) degradation. The effect of various operating variables such as catalyst and oxidant concentration, initial pH and RB4 concentration on the abatement of total organic carbon, and dye has been assessed in this study. Here we show that degradation of RB4 in the modified Fenton reaction was efficient under the following conditions: pH = 2.5; [PA]0 = 0.2 g L−1; [H2O2]0 = 5 mM and initial RB4 concentration up to 100 mg L−1. The pyrite ash Fenton reaction can overcome limitations observed from the classic Fenton reaction, such as the early termination of the Fenton reaction. Metal (Pb, Zn, and Cu) content of the solution after the process suggests that an additional treatment step is necessary to remove the remaining metals from the water. These results provide basic knowledge to better understand the modified, heterogeneous Fenton process and apply the PA Fenton reaction for the treatment of wastewaters which contains anthraquinone dyes. PMID:24526885

  11. Repair, sidetrack, drilling, and completion of EE-2A for Phase 2 reservoir production service

    SciTech Connect

    Dreesen, D.S.; Cocks, G.G.; Nicholson, R.W.; Thomson, J.C.

    1989-08-01

    Hot Dry Rock (HDR) geothermal energy well EE-2 at Fenton Hill, New Mexico, was sidetracked and redrilled into the HDR Phase II reservoir after two unsuccessful attempts to repair damage in the lower wellbore. Before sidetracking was begun, six cement slurries were pumped to plug the abandoned lower wellbore and to support the production casing where drilling wear was predicted and where sidetracking was to occur. This work and the redrill of EE-2A were completed in November 1987. Specifications were prepared for a state-of-the-art tie-back casing, which was procured, manufactured, and delivered to Fenton Hill in May 1988. The well was then completed in June 1988 for hot-water production service by cementing in a liner and the upper section of production casing and installing and cementing a tie-back casing string. 24 refs., 17 figs., 5 tabs.

  12. Inactivation of MS2 coliphage in Fenton and Fenton-like systems: role of transition metals, hydrogen peroxide and sunlight.

    PubMed

    Nieto-Juarez, Jessica I; Pierzchła, Katarzyna; Sienkiewicz, Andrzej; Kohn, Tamar

    2010-05-01

    The inactivation of coliphage MS2 by iron- and copper-catalyzed Fenton systems was studied to assess the importance of this process for virus inactivation in natural systems and during water treatment by advanced oxidation processes. The influence of H(2)O(2) (3-50 microM) and metal (1-10 microM) concentrations, HO(*) production, and sunlight on inactivation was investigated. Inactivation was first order with respect to H(2)O(2), but the dependence on the metal concentration was more complex. In the Cu/H(2)O(2) system, the inactivation rate constant k(obs) increased with added Cu up to 2.5 microM, and then leveled off. This was consistent with Cu saturation of the solution, indicating that only soluble Cu contributed to inactivation. In contrast, inactivation in the Fe/H(2)O(2) system was governed by colloidal iron. Irradiation by sunlight only affected the Fe/H(2)O(2) system, leading to a 5.5-fold increase in k(obs) (up to 3.1 min(-1)). HO(*) production, measured by electron spin resonance, could not account for the observed inactivation in the Fe/H(2)O(2) system. Other oxidants, such as ferryl species, must therefore play a role. Experiments using bulk oxidant scavengers revealed that inactivation occurred by a caged mechanism involving oxidant production by metals located in close proximity to the virus. Overall, our results show that the Fenton/photo-Fenton process may serve as an efficient technology for virus disinfection.

  13. Degradation of trans-ferulic acid in acidic aqueous medium by anodic oxidation, electro-Fenton and photoelectro-Fenton.

    PubMed

    Flores, Nelly; Sirés, Ignasi; Garrido, José Antonio; Centellas, Francesc; Rodríguez, Rosa María; Cabot, Pere Lluís; Brillas, Enric

    2016-12-01

    Solutions of pH 3.0 containing trans-ferulic acid, a phenolic compound in olive oil mill wastewater, have been comparatively degraded by anodic oxidation with electrogenerated H2O2 (AO-H2O2), electro-Fenton (EF) and photoelectro-Fenton (PEF). Trials were performed with a BDD/air-diffusion cell, where oxidizing OH was produced from water discharge at the BDD anode and/or in the solution bulk from Fenton's reaction between cathodically generated H2O2 and added catalytic Fe(2+). The substrate was very slowly removed by AO-H2O2, whereas it was very rapidly abated by EF and PEF, at similar rate in both cases, due to its fast reaction with OH in the bulk. The AO-H2O2 process yielded a slightly lower mineralization than EF, which promoted the accumulation of barely oxidizable products like Fe(III) complexes. In contrast, the fast photolysis of these latter species under irradiation with UVA light in PEF led to an almost total mineralization with 98% total organic carbon decay. The effect of current density and substrate concentration on the performance of all treatments was examined. Several solar PEF (SPEF) trials showed its viability for the treatment of wastewater containing trans-ferulic acid at larger scale. Four primary aromatic products were identified by GC-MS analysis of electrolyzed solutions, and final carboxylic acids like fumaric, acetic and oxalic were detected by ion-exclusion HPLC. A reaction sequence for trans-ferulic acid mineralization involving all the detected products is finally proposed. PMID:26691522

  14. Degradation of trans-ferulic acid in acidic aqueous medium by anodic oxidation, electro-Fenton and photoelectro-Fenton.

    PubMed

    Flores, Nelly; Sirés, Ignasi; Garrido, José Antonio; Centellas, Francesc; Rodríguez, Rosa María; Cabot, Pere Lluís; Brillas, Enric

    2016-12-01

    Solutions of pH 3.0 containing trans-ferulic acid, a phenolic compound in olive oil mill wastewater, have been comparatively degraded by anodic oxidation with electrogenerated H2O2 (AO-H2O2), electro-Fenton (EF) and photoelectro-Fenton (PEF). Trials were performed with a BDD/air-diffusion cell, where oxidizing OH was produced from water discharge at the BDD anode and/or in the solution bulk from Fenton's reaction between cathodically generated H2O2 and added catalytic Fe(2+). The substrate was very slowly removed by AO-H2O2, whereas it was very rapidly abated by EF and PEF, at similar rate in both cases, due to its fast reaction with OH in the bulk. The AO-H2O2 process yielded a slightly lower mineralization than EF, which promoted the accumulation of barely oxidizable products like Fe(III) complexes. In contrast, the fast photolysis of these latter species under irradiation with UVA light in PEF led to an almost total mineralization with 98% total organic carbon decay. The effect of current density and substrate concentration on the performance of all treatments was examined. Several solar PEF (SPEF) trials showed its viability for the treatment of wastewater containing trans-ferulic acid at larger scale. Four primary aromatic products were identified by GC-MS analysis of electrolyzed solutions, and final carboxylic acids like fumaric, acetic and oxalic were detected by ion-exclusion HPLC. A reaction sequence for trans-ferulic acid mineralization involving all the detected products is finally proposed.

  15. Variability of Marker-Based Rectal Dose Evaluation in HDR Cervical Brachytherapy

    SciTech Connect

    Wang Zhou; Jaggernauth, Wainwright; Malhotra, Harish K.; Podgorsak, Matthew B.

    2010-01-01

    In film-based intracavitary brachytherapy for cervical cancer, position of the rectal markers may not accurately represent the anterior rectal wall. This study was aimed at analyzing the variability of rectal dose estimation as a result of interfractional variation of marker placement. A cohort of five patients treated with multiple-fraction tandem and ovoid high-dose-rate (HDR) brachytherapy was studied. The cervical os point and the orientation of the applicators were matched among all fractional plans for each patient. Rectal points obtained from all fractions were then input into each clinical treated plan. New fractional rectal doses were obtained and a new cumulative rectal dose for each patient was calculated. The maximum interfractional variation of distances between rectal dose points and the closest source positions was 1.1 cm. The corresponding maximum variability of fractional rectal dose was 65.5%. The percentage difference in cumulative rectal dose estimation for each patient was 5.4%, 19.6%, 34.6%, 23.4%, and 13.9%, respectively. In conclusion, care should be taken when using rectal markers as reference points for estimating rectal dose in HDR cervical brachytherapy. The best estimate of true rectal dose for each fraction should be determined by the most anterior point among all fractions.

  16. Ir-192 HDR transit dose and radial dose function determination using alanine/EPR dosimetry

    NASA Astrophysics Data System (ADS)

    Guzmán Calcina, Carmen S.; de Almeida, Adelaide; Oliveira Rocha, José R.; Abrego, Felipe Chen; Baffa, Oswaldo

    2005-03-01

    Source positioning close to the tumour in high dose rate (HDR) brachytherapy is not instantaneous. An increment of dose will be delivered during the movement of the source in the trajectory to its static position. This increment is the transit dose, often not taken into account in brachytherapeutic treatment planning. The transit dose depends on the prescribed dose, number of treatment fractions, velocity and activity of the source. Combining all these factors, the transit dose can be 5% higher than the prescribed absorbed dose value (Sang-Hyun and Muller-Runkel, 1994 Phys. Med. Biol. 39 1181 8, Nath et al 1995 Med. Phys. 22 209 34). However, it cannot exceed this percentage (Nath et al 1995). In this work, we use the alanine-EPR (electron paramagnetic resonance) dosimetric system using analysis of the first derivative of the signal. The transit dose was evaluated for an HDR system and is consistent with that already presented for TLD dosimeters (Bastin et al 1993 Int. J. Radiat. Oncol. Biol. Phys. 26 695 702). Also using the same dosimetric system, the radial dose function, used to evaluate the geometric dose degradation around the source, was determined and its behaviour agrees better with those obtained by Monte Carlo simulations (Nath et al 1995, Williamson and Nath 1991 Med. Phys. 18 434 48, Ballester et al 1997 Med. Phys. 24 1221 8, Ballester et al 2001 Phys. Med. Biol. 46 N79 90) than with TLD measurements (Nath et al 1990 Med. Phys. 17 1032 40).

  17. Preliminary geological and geophysical evaluation of the Castle Dome HDR geothermal prospect, Southwestern Arizona

    SciTech Connect

    Gutmann, J.T.; Aiken, C.L.V.; Ander, M.E.; Laney, R.T.

    1980-01-01

    The Castle Dome HDR geothermal prospect is located in Yuma County, Arizona, in a region centered about 80 km north of Yuma along US Rte. 95. The area of interest is broadly defined by a negative residual Bouguer gravity anomaly which is about 45 km across, steep-sided in many places, and as much as 30 mgals in magnitude. The geology of this Basin and Range area is poorly known, but the few published reports and current Los Alamos Scientific Laboratory (LASL) field studies indicate that the Castle Dome Mountains and adjacent ranges are chiefly a thick pile of welded ash-flow tuffs of probable mid-Tertiary age. The tuffs rest unconformably on Mesozoic metasedimentary rocks exposed only outside steep edges of the gravity low. This gravity anomaly may reflect the presence of a large caldera. A regional magnetotelluric study now in progress will define the depths to electrical conductors within the crust and upper mantle and contribute to understanding of crustal structure, the gravity anomaly, and the Hot Dry Rock (HDR) geothermal potential of the Castle Dome area.

  18. Image guided Brachytherapy: The paradigm of Gynecologic and Partial Breast HDR Brachytherapy

    NASA Astrophysics Data System (ADS)

    Diamantopoulos, S.; Kantemiris, I.; Konidari, A.; Zaverdinos, P.

    2015-09-01

    High dose rate (HDR) brachytherapy uses high strength radioactive sources and temporary interstitial implants to conform the dose to target and minimize the treatment time. The advances of imaging technology enable accurate reconstruction of the implant and exact delineation of high-risk CTV and the surrounding critical structures. Furthermore, with sophisticated treatment planning systems, applicator devices and stepping source afterloaders, brachytherapy evolved to a more precise, safe and individualized treatment. At the Radiation Oncology Department of Metropolitan Hospital Athens, MRI guided HDR gynecologic (GYN) brachytherapy and accelerated partial breast irradiation (APBI) with brachytherapy are performed routinely. Contouring and treatment planning are based on the recommendations of the GEC - ESTRO Working group. The task of this presentation is to reveal the advantages of 3D image guided brachytherapy over 2D brachytherapy. Thus, two patients treated at our department (one GYN and one APBI) will be presented. The advantage of having adequate dose coverage of the high risk CTV and simultaneous low doses to the OARs when using 3D image- based brachytherapy will be presented. The treatment techniques, equipment issues, as well as implantation, imaging and treatment planning procedures will be described. Quality assurance checks will be treated separately.

  19. Drought in the Black Hills

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Annotated Color-Coded Map

    Despite good rainfall and record-setting snowstorms in the spring of 2005, most of northeastern Wyoming, the Black Hills, and western South Dakota remain in the midst of a severe drought. This set of images and maps from NASA's Multi-angle Imaging SpectroRadiometer (MISR) contrast the appearance of the Black Hills region of northwestern South Dakota on July 12, 2000 (left column), with views acquired four years later, on July 14, 2004 (right column). The natural-color images along the top are from MISR's nadir (downward-looking) camera. The browning that appears in 2004 compared with 2000 indicates that the vigor of green vegetation was significantly diminished in 2004.

    The color-coded maps (along the bottom) provide a quantitative measurement of the sunlight reflected from these surfaces, and the loss of sunlight-absorbing vegetation between the 2000 and 2004 dates. As the vegetation faded with the drought, the albedo at the surface increased. Albedo measures the fraction of incident sunlight that is reflected by a surface, and can vary between zero (if all the incident sunlight is absorbed and none is reflected) and one (if all sunlight is reflected and none is absorbed). Dense forest has a low albedo; bright desert, snow and clouds, have a high albedo. Here, albedo is provided for the wavelengths of sunlight that plants use for photosynthesis (400 - 700 nanometers). This measurement is known as the albedo for Photosynthetically Active Radiation (PAR). Surfaces with greater absorption of PAR appear here in blue hues, whereas surfaces with lower absorption appear as green, yellow, orange or red. Black pixels indicate areas where albedo could not be derived, usually due to the presence of clouds. In July 2004, low albedo areas (blue pixels) are notably reduced in extent, and higher albedo areas (yellow, orange and red pixels) have increased.

    Because incoming sunlight is

  20. Bunker Hill Sediment Characterization Study

    SciTech Connect

    Neal A. Yancey; Debby F. Bruhn

    2009-12-01

    The long history of mineral extraction in the Coeur d’Alene Basin has left a legacy of heavy metal laden mine tailings that have accumulated along the Coeur d’Alene River and its tributaries (U.S. Environmental Protection Agency, 2001; Barton, 2002). Silver, lead and zinc were the primary metals of economic interest in the area, but the ores contained other elements that have become environmental hazards including zinc, cadmium, lead, arsenic, nickel, and copper. The metals have contaminated the water and sediments of Lake Coeur d’Alene, and continue to be transported downstream to Spokane Washington via the Spokane River. In 1983, the EPA listed the Bunker Hill Mining and Metallurgical Complex on the National Priorities List. Since that time, many of the most contaminated areas have been stabilized or isolated, however metal contaminants continue to migrate through the basin. Designation as a Superfund site causes significant problems for the economically depressed communities in the area. Identification of primary sources of contamination can help set priorities for cleanup and cleanup options, which can include source removal, water treatment or no action depending on knowledge about the mobility of contaminants relative to water flow. The mobility of contaminant mobility under natural or engineered conditions depends on multiple factors including the physical and chemical state (or speciation) of metals and the range of processes, some of which can be seasonal, that cause mobilization of metals. As a result, it is particularly important to understand metal speciation (National Research Council, 2005) and the link between speciation and the rates of metal migration and the impact of natural or engineered variations in flow, biological activity or water chemistry.

  1. Fenton-like application to pretreated cheese whey wastewater.

    PubMed

    Prazeres, Ana R; Carvalho, Fátima; Rivas, Javier

    2013-11-15

    Cheese whey wastewater has been treated by the Fenton-like oxidation system after being pre-processed through a coagulation - flocculation stage with FeCl3 or alternatively, through a sedimentation step with Ca(OH)2 plus aerobic digestion. In the first case, Fenton-like oxidation is capable of reducing the initial COD (chemical oxygen demand) to 80% of the initial value, 20% of COD shows recalcitrance to chemical oxidation regardless of the operating conditions used. In the second case, the oxidation system is capable of removing almost the total COD present in the pretreated effluent. Given the lower values of initial COD, complete COD conversion is achieved at short reaction times within minutes depending on the initial reagent concentration. Removal of Fe(III) from the oxidation treatment can be achieved by Ca(OH)2 addition. Sedimentation pH significantly affects the observed settling rate. Hence, neutral conditions lead to better results than slightly acidic pHs. PMID:23948438

  2. Degradation of ethylene glycol using Fenton's reagent and UV.

    PubMed

    McGinnis, B D; Adams, V D; Middlebrooks, E J

    2001-10-01

    Oxidation of ethylene glycol in aqueous solutions was found to occur with the addition of Fenton's reagent with further conversion observed upon UV irradiation. The pH range studied was 2.5-9.0 with initial H2O2 concentrations ranging from 100 to 1000 mg/l. Application of this method to airport storm-water could potentially result in reduction of chemical oxygen demand by conversion of ethylene glycol to oxalic and formic acids. Although the amount of H2O2 added follows the amount of ethylene glycol degraded, smaller H2O2 doses were associated with increases in the ratio of ethylene glycol removed per unit H2O2 added indicating the potential of pulsed doses or constant H2O2 feed systems. Ethylene glycol removal was enhanced by exposure to UV light after treatment with Fenton's reagent, with rates dependent on initial H2O2 concentration. In addition to ethylene glycol, the principle products of this reaction, oxalic and formic acids, have been shown to be mineralized in other HO generating systems presenting the potential for ethylene glycol mineralization in this system with increased HO* production.

  3. Degradation of carbofuran-contaminated water by the Fenton process.

    PubMed

    Ma, Ying-Shih; Kumar, Mathava; Lin, Jih-Gaw

    2009-07-15

    In this study, the Fenton process was applied for the degradation of carbofuran from aqueous system. Batch experiments were conducted at two different carbofuran concentrations i.e., 10 and 50 mg/L, and at pH 3. Batch experiments at each carbofuran concentration were designed by central composite design (CCD) with two independent variables i.e. Fe2+ and H2O2. Experimental results indicate that more than 90% of carbofuran removal was observed within 5 mins of Fenton reaction at 5 mg/L of Fe2+ concentration and 100 mg/L of H202 concentration. Increases in Fe2+ and/or H2O2 concentrations beyond 5 and 100 mg/L, respectively produced 100% carbofuran removal. Based on the experimental observations, the optimal Fe2+ and H2O2 dosages required for 10 mg/L of aqueous carbofuran removal were estimated as 7.4 and 143 mg/L, respectively. During this study, three carbofuran intermediates such as 7-benzofuranol,2,3,-dihydro-2,2-dimethyl, 7-hydroxy-2,2-dimethyl-benzofuran-3-one and 1,4-Benzene-di-carboxaldehyde were identified using GC/MS analyses.

  4. Novel electro-fenton approach for regeneration of activated carbon.

    PubMed

    Bañuelos, Jennifer A; Rodríguez, Francisco J; Manríquez Rocha, Juan; Bustos, Erika; Rodríguez, Adrián; Cruz, Julio C; Arriaga, L G; Godínez, Luis A

    2013-07-16

    An electro-Fenton-based method was used to promote the regeneration of granular activated carbon (GAC) previously adsorbed with toluene. Electrochemical regeneration experiments were carried out using a standard laboratory electrochemical cell with carbon paste electrodes and a batch electrochemical reactor. For each system, a comparison was made using FeSO4 as a precursor salt in solution (homogeneous system) and an Fe-loaded ion-exchange resin (Purolite C-100, heterogeneous system), both in combination with electrogenerated H2O2 at the GAC cathode. In the two cases, high regeneration efficiencies were obtained in the presence of iron using appropriate conditions of applied potential and adsorption-polarization time. Consecutive loading and regeneration cycles of GAC were performed in the reactor without great loss of the adsorption properties, only reducing the regeneration efficiency by 1% per cycle during 10 cycles of treatment. Considering that, in the proposed resin-containing process, the use of Fe salts is avoided and that GAC cathodic polarization results in efficient cleaning and regeneration of the adsorbent material, this novel electro-Fenton approach could constitute an excellent alternative for regenerating activated carbon when compared to conventional methods. PMID:23782426

  5. Phenanthrene and pyrene oxidation in contaminated soils using Fenton's reagent.

    PubMed

    Silva, Paula Tereza de Souza E; Silva, Valdinete Lins da; Neto, Benício de Barros; Simonnot, Marie-Odile

    2009-01-30

    Fenton's reagent has shown its applicability to oxidizing these biorefractory organic contaminants. The purpose of this contribution was to investigate the influence of operating parameters on the process efficiency for soil highly contaminated by PAHs. Five variables were selected: pH, reaction time, UV irradiation, hydrogen peroxide concentration and Fe (II) amendment. Their effects on the oxidation of (i) phenanthrene and on (ii) phenanthrene and pyrene present in freshly contaminated soil samples were studied through batch reactor experiments following factorial designs. For phenanthrene oxidation run with a soil contaminated at 700 mg kg(-1), one set of variables enabled us to reach a residual concentration lower than 40 mg kg(-1) (Dutch legislation threshold). The most important factor was the reaction time, followed at a certain distance by UV irradiation, Fe (II), H(2)O(2) concentration and pH, this last variable being the least significant. The possibility of operating without pH adjustment is of importance in the treatment at the field scale. This shows the feasibility of photo-Fenton-like oxidation for the treatment of soil highly contaminated with PAH and the relative importance of the process variables. PMID:18524479

  6. Potentially toxic element release by fenton oxidation of sewage sludge.

    PubMed

    Andrews, J P; Asaadi, M; Clarke, B; Ouki, S

    2006-01-01

    The presence, in sewage sludge, of excess levels of the potentially toxic elements (PTE) copper, zinc, chromium, cadmium, nickel, lead and mercury, could impact on our ability to recycle these residues in the future. Far stricter limits on the levels of PTEs are likely in proposed legislation. A method involving the dosing of Fenton's reagent, a mixture of ferrous iron and hydrogen peroxide, under acidic conditions was evaluated for its potential to reduce metal levels. The [Fe]:[H2O2] (w/w) ratio was found to give a good indication of the percentage copper and zinc elution obtainable. Sites with no iron dosing as part of wastewater treatment required extra iron to be added in order to initiate the Fenton's reaction. A significant reduction, in excess of 70%, of the copper and zinc was eluted from both raw primary and activated sludge solid fractions. Cadmium and nickel could be reduced to below detection limits but elution of mercury, lead and chromium was less than 40%. The iron catalyst concentration was found to be a crucial parameter. This process has the potential to reduce the heavy metal content of the sludge and allow the recycling of sludge to continue in a sustainable manner. PMID:17087386

  7. Fenton Oxidation Kinetics and Intermediates of Nonylphenol Ethoxylates

    PubMed Central

    Cui, Kai; Yi, Hao; Zhou, Zi-jian; Zhuo, Qiong-fang; Bing, Yong-xin; Guo, Qing-wei; Xu, Zhen-cheng

    2014-01-01

    Abstract Removal of nonylphenol ethoxylates (NPEOs) in aqueous solution by Fenton oxidation process was studied in a laboratory-scale batch reactor. Operating parameters, including initial pH temperature, hydrogen peroxide, and ferrous ion dosage, were thoroughly investigated. Maximum NPEOs reduction of 84% was achieved within 6 min, under an initial pH of 3.0, 25°C, an H2O2 dosage of 9.74×10−3 M, and a molar ratio of [H2O2]/[Fe2+] of 3. A modified pseudo-first-order kinetic model was found to well represent experimental results. Correlations of reaction rate constants and operational parameters were established based on experimental data. Results indicated that the Fenton oxidation rate and removal efficiency were more dependent on the dosage of H2O2 than Fe2+, and the apparent activation energy (ΔE) was 17.5 kJ/mol. High-performance liquid chromatography and gas chromatograph mass spectrometer analytical results indicated degradation of NPEOs obtained within the first 2 min stepwise occurred by ethoxyl (EO) unit shortening. Long-chain NPEOs mixture demonstrated a higher degradation rate than shorter-chain ones. Nonylphenol (NP), short-chain NPEOs, and NP carboxyethoxylates were identified as the primary intermediates, which were mostly further degraded. PMID:24868141

  8. Candidate sites for future hot-dry-rock development in the United States

    SciTech Connect

    Goff, F.; Decker, E.R.

    1982-12-01

    Generalized geologic and other data are tabulated for 24 potential hot dry rock (HDR) sites in the contiguous United States. The data show that HDR resources occur in many geologic and tectonic settings. Potential reservoir rocks at each prospect are described and each system is cateogrized accoridng to inferred heat sources. The Fenton Hill area in New Mexico is discussed in detail because this region may be considered ideal for HDR development. Three other prospectively valuable localities are described: The Geysers-Clear lake region in California, the Roosevelt Hot Springs area in Utah, and the White Mountains region in New Hampshire. These areas are singled out to illustrate the roles of significantly different geology and geophysics, reservoir rocks, and reservoir heat contents in possible HDR developments.

  9. Hot dry rock reservoir engineering

    SciTech Connect

    Murphy, H.

    1987-01-01

    The Hot Dry Rock (HDR) concept is a simple one. Two nearly parallel wells are drilled, and hydraulic fractures are then formed to hydraulically connect the wells. Water pumped down the injection well and through the fracture system is heated by contact with the hot rock and rises to the production well. This hot fluid is passed through a heat exchanger at the surface and the extracted heat is used for direct heating or electricity generation. The cooled production fluid is then reinjected, thereby setting up a circulation loop. This paper describes the development and execution of the HDR project at Fenton Hill, New Mexico.

  10. Hot Dry Rock Geothermal Energy Development Program. Annual report, fiscal year 1979

    SciTech Connect

    Cremer, G.M.; Duffield, R.B.; Smith, M.C.; Wilson, M.G.

    1980-08-01

    The Fenton Hill Project is still the principal center for developing methods, equipment, and instrumentation for creating and utilizing HDR geothermal reservoirs. The search for a second site for a similar experimental system in a different geological environment has been intensified, as have the identification and characterization of other HDR areas that may prove suitable for either experimental or commercial development. The Phase I fracture system was enlarged during FY79. Drilling of the injection well of the Phase II system began at Fenton Hill in April 1979. Environmental monitoring of the Fenton Hill area continued through FY79. The environmental studies indicate that the hot dry rock operations have caused no significant environmental impact. Other supporting activities included rock physics, rock mechanics, fracture mapping, and instrumentation development. Two closely related activities - evaluation of the potential HDR energy resource of the US and the selection of a site for development of a second experimental heat-extraction system generally similar to that at Fenton Hill - have resulted in the collection of geology, hydrology, and heat-flow data on some level of field activity in 30 states. The resource-evaluation activity included reconnaissance field studies and a listing and preliminary characterization of US geothermal areas in which HDR energy extraction methods may be applicable. The selection of Site 2 has taken into account such legal, institutional, and economic factors as land ownership and use, proximity to possible users, permitting and licensing requirements and procedures, environmental issues, areal extent of the geothermal area, and visibility to and apparent interest by potential industrial developers.

  11. HDR-VDP-2.2: a calibrated method for objective quality prediction of high-dynamic range and standard images

    NASA Astrophysics Data System (ADS)

    Narwaria, Manish; Mantiuk, Rafal K.; Da Silva, Mattheiu Perreira; Le Callet, Patrick

    2015-01-01

    With the emergence of high-dynamic range (HDR) imaging, the existing visual signal processing systems will need to deal with both HDR and standard dynamic range (SDR) signals. In such systems, computing the objective quality is an important aspect in various optimization processes (e.g., video encoding). To that end, we present a newly calibrated objective method that can tackle both HDR and SDR signals. As it is based on the previously proposed HDR-VDP-2 method, we refer to the newly calibrated metric as HDR-VDP-2.2. Our main contribution is toward improving the frequency-based pooling in HDR-VDP-2 to enhance its objective quality prediction accuracy. We achieve this by formulating and solving a constrained optimization problem and thereby finding the optimal pooling weights. We also carried out extensive cross-validation as well as verified the performance of the new method on independent databases. These indicate clear improvement in prediction accuracy as compared with the default pooling weights. The source codes for HDR-VDP-2.2 are publicly available online for free download and use.

  12. Comparison of the calculation of HDR RPV-1 blowdown loads for test V32 with the experimental data

    SciTech Connect

    Mortensen, G.A.; Santee, G.E. Jr.; Chang, F.H.; Brockett, G.F.; Gross, M.; Belytschko, T.

    1984-08-01

    Using the three-dimensional STEALTH/WHAMSE computer program, researchers calculated blowdown loads for HDR test V32 on a large-scale reactor vessel. The calculation, which compared well with test results, provides a good example of the predictive capability of the computer program. The program can be applied to nuclear and nonnuclear fluid-structure interaction problems.

  13. Photo-Fenton and modified photo-Fenton at neutral pH for the treatment of emerging contaminants in wastewater treatment plant effluents: a comparison.

    PubMed

    Klamerth, N; Malato, S; Agüera, A; Fernández-Alba, A

    2013-02-01

    This study compares two different solar photo-Fenton processes, conventional photo-Fenton at pH3 and modified photo-Fenton at neutral pH with minimal Fe (5 mg L⁻¹) and minimal initial H₂O₂ (50 mg L⁻¹) concentrations for the degradation of emerging contaminants in Municipal Wastewater Treatment Plants effluents in solar pilot plant. As Fe precipitates at neutral pH, complexing agents which are able to form photoactive species, do not pollute the environment or increase toxicity have to be used to keep the iron in solution. This study was done using real effluents containing over 60 different contaminants, which were monitored during treatment by liquid chromatography coupled to a hybrid quadrupole/linear ion trap mass analyzer (LC-QTRAP-MS/MS) operating in selected reaction monitoring (SRM) mode. Concentrations of the selected contaminants ranged from a few ng L⁻¹ to tens of μg L⁻¹. It was demonstrated in all cases the removal of over 95% of the contaminants. Photo-Fenton at pH3 provided the best treatment time, but has the disadvantage that the water must be previously acidified. The most promising process was photo-Fenton modified with Ethylenediamine-N,N'-disuccinic acid (EDDS), as the pH remained in the neutral range. PMID:23206497

  14. BrachyView, A novel inbody imaging system for HDR prostate brachytherapy: Design and Monte Carlo feasibility study

    SciTech Connect

    Safavi-Naeini, M.; Han, Z.; Cutajar, D.; Guatelli, S.; Petasecca, M.; Lerch, M. L. F.; Franklin, D. R.; Jakubek, J.; Pospisil, S.; Bucci, J.; Zaider, M.; Rosenfeld, A. B.

    2013-07-15

    Purpose: High dose rate (HDR) brachytherapy is a form of radiation therapy for treating prostate cancer whereby a high activity radiation source is moved between predefined positions inside applicators inserted within the treatment volume. Accurate positioning of the source is essential in delivering the desired dose to the target area while avoiding radiation injury to the surrounding tissue. In this paper, HDR BrachyView, a novel inbody dosimetric imaging system for real time monitoring and verification of the radioactive seed position in HDR prostate brachytherapy treatment is introduced. The current prototype consists of a 15 Multiplication-Sign 60 mm{sup 2} silicon pixel detector with a multipinhole tungsten collimator placed 6.5 mm above the detector. Seven identical pinholes allow full imaging coverage of the entire treatment volume. The combined pinhole and pixel sensor arrangement is geometrically designed to be able to resolve the three-dimensional location of the source. The probe may be rotated to keep the whole prostate within the transverse plane. The purpose of this paper is to demonstrate the efficacy of the design through computer simulation, and to estimate the accuracy in resolving the source position (in detector plane and in 3D space) as part of the feasibility study for the BrachyView project.Methods: Monte Carlo simulations were performed using the GEANT4 radiation transport model, with a {sup 192}Ir source placed in different locations within a prostate phantom. A geometrically accurate model of the detector and collimator were constructed. Simulations were conducted with a single pinhole to evaluate the pinhole design and the signal to background ratio obtained. Second, a pair of adjacent pinholes were simulated to evaluate the error in calculated source location.Results: Simulation results show that accurate determination of the true source position is easily obtainable within the typical one second source dwell time. The maximum error in

  15. Mimicking the Fenton reaction-induced wood decay by fungi for pretreatment of lignocellulose.

    PubMed

    Jung, Young Hoon; Kim, Hyun Kyung; Park, Hyun Min; Park, Yong-Cheol; Park, Kyungmoon; Seo, Jin-Ho; Kim, Kyoung Heon

    2015-03-01

    In this study, the Fenton reaction, which is naturally used by fungi for wood decay, was employed to pretreat rice straw and increase the enzymatic digestibility for the saccharification of lignocellulosic biomass. Using an optimized Fenton's reagent (FeCl3 and H2O2) for pretreatment, an enzymatic digestibility that was 93.2% of the theoretical glucose yield was obtained. This is the first report of the application of the Fenton reaction to lignocellulose pretreatment at a moderate temperature (i.e., 25°C) and with a relatively high loading of biomass (i.e., 10% (w/v)). Substantial improvement in the process economics of cellulosic fuel and chemical production can be achieved by replacing the conventional pretreatment with this Fenton-mimicking process.

  16. Chemical oxidation of sulfadiazine by the Fenton process: kinetics, pathways, toxicity evaluation.

    PubMed

    Yang, Ji-Feng; Zhou, Shi-Biao; Xiao, An-Guo; Li, Wen-Jun; Ying, Guang-Guo

    2014-01-01

    This paper investigated sulfadiazine oxidation by the Fenton process under various reaction conditions. The reaction conditions tested in the experiments included the initial pH value of reaction solutions, and the dosages of ferrous ions and hydrogen peroxide. Under the reaction conditions with pH 3, 0.25 mM of ferrous ion and 2 mM of hydrogen peroxide, a removal efficiency of nearly 100% was achieved for sulfadiazine. A series of intermediate products including 4-OH-sulfadiazine/or 5-OH-sulfadiazine, 2-aminopyrimidine, sulfanilamide, formic acid, and oxalic acid were identified. Based on these products, the possible oxidation pathway of sulfadiazine by Fenton's reagent was proposed. The toxicity evaluation of reaction solutions showed increased antimicrobial effects following the Fenton oxidation process. The results from this study suggest that the Fenton oxidation process could remove sulfadiazine, but also increase solution toxicity due to the presence of more toxic products. PMID:25310806

  17. Fenton- and Persulfate-driven Regeneration of Contaminant-spent Granular Activated Carbon

    EPA Science Inventory

    Fenton- or persulfate-driven chemical oxidation regeneration of spent granular activated carbon (GAC) involves the combined, synergistic use of two treatment technologies: adsorption of organic chemicals onto GAC and chemical oxidation regeneration of the spent-GAC. Environmental...

  18. IN-SITU REGENERATION OF GRANULAR ACTIVATED CARBON (GAC) USING FENTON'S REAGENTS

    EPA Science Inventory

    Fenton-dependent regeneration of granular activated carbon (GAC) initially saturated with one of several chlorinated aliphatic contaminants was studied in batch and continuous-flow reactors. Homogeneous and heterogeneous experiments were designed to investigate the effects of va...

  19. Balloon-based adjuvant radiotherapy in breast cancer: comparison between 99mTc and HDR 192Ir*

    PubMed Central

    de Campos, Tarcísio Passos Ribeiro; de Lima, Carla Flavia; Cuperschmid, Ethel Mizrahy

    2016-01-01

    Objective To perform a comparative dosimetric analysis, based on computer simulations, of temporary balloon implants with 99mTc and balloon brachytherapy with high-dose-rate (HDR) 192Ir, as boosts to radiotherapy. We hypothesized that the two techniques would produce equivalent doses under pre-established conditions of activity and exposure time. Materials and Methods Simulations of implants with 99mTc-filled and HDR 192Ir-filled balloons were performed with the Siscodes/MCNP5, modeling in voxels a magnetic resonance imaging set related to a young female. Spatial dose rate distributions were determined. In the dosimetric analysis of the protocols, the exposure time and the level of activity required were specified. Results The 99mTc balloon presented a weighted dose rate in the tumor bed of 0.428 cGy.h-1.mCi-1 and 0.190 cGyh-1.mCi-1 at the balloon surface and at 8-10 mm from the surface, respectively, compared with 0.499 and 0.150 cGyh-1.mCi-1, respectively, for the HDR 192Ir balloon. An exposure time of 24 hours was required for the 99mTc balloon to produce a boost of 10.14 Gy with 1.0 Ci, whereas only 24 minutes with 10.0 Ci segments were required for the HDR 192Ir balloon to produce a boost of 5.14 Gy at the same reference point, or 10.28 Gy in two 24-minutes fractions. Conclusion Temporary 99mTc balloon implantation is an attractive option for adjuvant radiotherapy in breast cancer, because of its availability, economic viability, and similar dosimetry in comparison with the use of HDR 192Ir balloon implantation, which is the current standard in clinical practice. PMID:27141131

  20. Treatment of SRS Tank 48H Simulants Using Fenton's Reagent

    SciTech Connect

    Taylor, PA

    2003-11-18

    High-level-waste Tank 48H at the Savannah River Site (SRS) contains about 50,000 lb of tetraphenylborate (TPB), which must be destroyed to return the tank to active service. Laboratory-scale tests were conducted to evaluate the use of Fenton's Reagent (hydrogen peroxide and a metal catalyst) to treat simulants of the Tank 48H waste. Samples of the treated slurry and the off-gas were analyzed to determine the reaction products. Process parameters developed earlier by AEA Technology were used for these tests; namely (for 500 mL of waste simulant), reduce pH to 7.5 with nitric acid, heat to boiling, add hydrogen peroxide at 1 mL/min for 1 h, reduce pH to 3.5, and add the remaining peroxide at 2 mL/min. These parameters were developed to minimize the formation of tarry materials during the early part of the reaction and to minimize the concentration of total organic carbon in the final treated slurry. The treated samples contained low concentrations of total organic carbon (TOC) and no detectable TPB. Tests using a mixture of iron and copper salts as the Fenton's catalyst had a lower TOC concentration in the final treated slurry than did tests that used a copper-only catalyst. TPB is known to hydrolyze to benzene, particularly at high temperature and low pH, and copper is known to increase the rate of hydrolysis. Significant amounts of benzene were present in the off-gas from the tests, especially during the early portion of the treatment, indicating that the hydrolysis reaction was occurring in parallel with the oxidation of the TPB by Fenton's reagent. For the reaction conditions used in these tests, approximately equal fractions of the TPB were converted to benzene and carbon dioxide. Minimizing the formation of benzene is important to SRS personnel; however, this consideration was not addressed in the AEA-recommended parameters, since they did not analyze for benzene in the off-gas. Smaller amounts of carbon monoxide and other organics were also produced. One test

  1. Carbon nanotube membrane stack for flow-through sequential regenerative electro-Fenton.

    PubMed

    Gao, Guandao; Zhang, Qiaoying; Hao, Zhenwei; Vecitis, Chad D

    2015-02-17

    Electro-Fenton is a promising advanced oxidation process for water treatment consisting a series redox reactions. Here, we design and examine an electrochemical filter for sequential electro-Fenton reactions to optimize the treatment process. The carbon nanotube (CNT) membrane stack (thickness ∼ 200 μm) used here consisted of 1) a CNT network cathode for O2 reduction to H2O2, 2) a CNT-COOFe(2+) cathode to chemical reduction H2O2 to (•)OH and HO(-) and to regenerate Fe(2+) in situ, 3) a porous PVDF or PTFE insulating separator, and 4) a CNT filter anode for remaining intermediate oxidation intermediates. The sequential electro-Fenton was compared to individual electrochemical and Fenton process using oxalate, a persistent organic, as a target molecule. Synergism is observed during the sequential electro-Fenton process. For example, when [DO]in = 38 ± 1 mg L(-1), J = 1.6 mL min(-1), neutral pH, and Ecell = 2.89 V, the sequential electro-Fenton oxidation rate was 206.8 ± 6.3 mgC m(-2) h(-1), which is 4-fold greater than the sum of the individual electrochemistry (16.4 ± 3.2 mgC m(-2) h(-1)) and Fenton (33.3 ± 1.3 mgC m(-2) h(-1)) reaction fluxes, and the energy consumption was 45.8 kWh kgTOC(-1). The sequential electro-Fenton was also challenged with the refractory trifluoroacetic acid (TFA) and trichloroacetic acid (TCA), and they can be transferred at a removal rate of 11.3 ± 1.2 and 21.8 ± 1.9 mmol m(-2) h(-1), respectively, with different transformation mechanisms. PMID:25602741

  2. Development of a system for treatment of coconut industry wastewater using electrochemical processes followed by Fenton reaction.

    PubMed

    Gomes, Lúcio de Moura; Duarte, José Leandro da Silva; Pereira, Nathalia Marcelino; Martínez-Huitle, Carlos A; Tonholo, Josealdo; Zanta, Carmen Lúcia de Paiva E Silva

    2014-01-01

    The coconut processing industry generates a significant amount of liquid waste. New technologies targeting the treatment of industrial effluents have emerged, including advanced oxidation processes, the Fenton reaction, and electrochemical processes, which produce strong oxidizing species to remove organic matter. In this study we combined the Fenton reaction and electrochemical process to treat wastewater generated by the coconut industry. We prepared a synthetic wastewater consisting of a mixture of coconut milk and water and assessed how the Fenton reagents' concentration, the cathode material, the current density, and the implementation of associated technologies affect its treatment. Electrochemical treatment followed by the Fenton reaction diminished turbidity and chemical oxygen demand (COD) by 85 and 95%, respectively. The Fenton reaction followed by the electrochemical process reduced turbidity and COD by 93 and 85%, respectively. Therefore, a combination of the Fenton and electrochemical technologies can effectively treat the effluent from the coconut processing industry. PMID:24901620

  3. Development of a system for treatment of coconut industry wastewater using electrochemical processes followed by Fenton reaction.

    PubMed

    Gomes, Lúcio de Moura; Duarte, José Leandro da Silva; Pereira, Nathalia Marcelino; Martínez-Huitle, Carlos A; Tonholo, Josealdo; Zanta, Carmen Lúcia de Paiva E Silva

    2014-01-01

    The coconut processing industry generates a significant amount of liquid waste. New technologies targeting the treatment of industrial effluents have emerged, including advanced oxidation processes, the Fenton reaction, and electrochemical processes, which produce strong oxidizing species to remove organic matter. In this study we combined the Fenton reaction and electrochemical process to treat wastewater generated by the coconut industry. We prepared a synthetic wastewater consisting of a mixture of coconut milk and water and assessed how the Fenton reagents' concentration, the cathode material, the current density, and the implementation of associated technologies affect its treatment. Electrochemical treatment followed by the Fenton reaction diminished turbidity and chemical oxygen demand (COD) by 85 and 95%, respectively. The Fenton reaction followed by the electrochemical process reduced turbidity and COD by 93 and 85%, respectively. Therefore, a combination of the Fenton and electrochemical technologies can effectively treat the effluent from the coconut processing industry.

  4. Source position verification and dosimetry in HDR brachytherapy using an EPID

    SciTech Connect

    Smith, R. L.; Taylor, M. L.; McDermott, L. N.; Franich, R. D.; Haworth, A.; Millar, J. L.

    2013-11-15

    Purpose: Accurate treatment delivery in high dose rate (HDR) brachytherapy requires correct source dwell positions and dwell times to be administered relative to each other and to the surrounding anatomy. Treatment delivery inaccuracies predominantly occur for two reasons: (i) anatomical movement or (ii) as a result of human errors that are usually related to incorrect implementation of the planned treatment. Electronic portal imaging devices (EPIDs) were originally developed for patient position verification in external beam radiotherapy and their application has been extended to provide dosimetric information. The authors have characterized the response of an EPID for use with an {sup 192}Ir brachytherapy source to demonstrate its use as a verification device, providing both source position and dosimetric information.Methods: Characterization of the EPID response using an {sup 192}Ir brachytherapy source included investigations of reproducibility, linearity with dose rate, photon energy dependence, and charge build-up effects associated with exposure time and image acquisition time. Source position resolution in three dimensions was determined. To illustrate treatment verification, a simple treatment plan was delivered to a phantom and the measured EPID dose distribution compared with the planned dose.Results: The mean absolute source position error in the plane parallel to the EPID, for dwells measured at 50, 100, and 150 mm source to detector distances (SDD), was determined to be 0.26 mm. The resolution of the z coordinate (perpendicular distance from detector plane) is SDD dependent with 95% confidence intervals of ±0.1, ±0.5, and ±2.0 mm at SDDs of 50, 100, and 150 mm, respectively. The response of the EPID is highly linear to dose rate. The EPID exhibits an over-response to low energy incident photons and this nonlinearity is incorporated into the dose calibration procedure. A distance (spectral) dependent dose rate calibration procedure has been

  5. Determination of transit dose profile for a {sup 192}Ir HDR source

    SciTech Connect

    Fonseca, G. P.; Antunes, P. C. G.; Yoriyaz, H.

    2013-05-15

    Purpose: Several studies have reported methodologies to calculate and correct the transit dose component of the moving radiation source for high dose rate (HDR) brachytherapy planning systems. However, most of these works employ the average source speed, which varies significantly with the measurement technique used, and does not represent a realistic speed profile, therefore, providing an inaccurate dose determination. In this work, the authors quantified the transit dose component of a HDR unit based on the measurement of the instantaneous source speed to produce more accurate dose values. Methods: The Nucletron microSelectron-HDR Ir-192 source was characterized considering the Task Group 43 (TG-43U1) specifications. The transit dose component was considered through the calculation of the dose distribution using a Monte Carlo particle transport code, MCNP5, for each source position and correcting it by the source speed. The instantaneous source speed measurements were performed in a previous work using two optical fibers connected to a photomultiplier and an oscilloscope. Calculated doses were validated by comparing relative dose profiles with those obtained experimentally using radiochromic films. Results: TG-43U1 source parameters were calculated to validate the Monte Carlo simulations. These agreed with the literature, with differences below 1% for the majority of the points. Calculated dose profiles without transit dose were also validated by comparison with ONCENTRA{sup Registered-Sign} Brachy v. 3.3 dose values, yielding differences within 1.5%. Dose profiles obtained with MCNP5 corrected using the instantaneous source speed profile showed differences near dwell positions of up to 800% in comparison to values corrected using the average source speed, but they are in good agreement with the experimental data, showing a maximum discrepancy of approximately 3% of the maximum dose. Near a dwell position the transit dose is about 22% of the dwell dose delivered

  6. Design of an electro-Fenton system with a novel sandwich film cathode for wastewater treatment.

    PubMed

    Fan, Yan; Ai, Zhihui; Zhang, Lizhi

    2010-04-15

    In this study, we demonstrate an electro-Fenton (E-Fenton) system constructed with a novel sandwich film cathode (SFC). For the fabrication of SFC, Fe(2+)-chitosan (Fe-CHI) was first deposited on foam nickel (Fe-CHI/Ni). Then two pieces of Fe-CHI/Ni was used to fasten one piece of activated carbon fiber (ACF) to obtain a Fe-CHI/Ni|ACF|Fe-CHI/Ni sandwich film cathode. We interestingly found that this SFC based E-Fenton system could effectively degrade rodamine B with in situ generating both hydrogen peroxide and iron ions. Its degradation efficiency was significantly higher than those of the E-Fenton systems constructed with composite cathodes of carbon nanotubes with Fe@Fe(2)O(3) core-shell nanowires or Cu(2)O nanocubes reported in our previous studies. Hydrogen peroxide electrogenerated through the reduction of O(2) adsorbed on the sandwich film cathode and the iron ions produced by the leakage from Fe(2+)-chitosan film during the E-Fenton reaction were, respectively, monitored, providing clues to understand the high efficiency of this novel SFC based E-Fenton system. More importantly, this low-cost sandwich film cathode was very stable and could be reused without catalytic activity decrease, suggesting its potential application in the wastewater treatment.

  7. Factorial design analysis for COD removal from landfill leachate by photoassisted Fered-Fenton process.

    PubMed

    Wu, Xiaogang; Zhang, Hui; Li, Yanli; Zhang, Daobin; Li, Xianwang

    2014-01-01

    The Fered-Fenton process has been shown to be an effective method for leachate treatment, but it still faces problems of inadequate regeneration of ferrous ion. However, the use of the photoassisted Fered-Fenton process could overcome this difficulty and improve the efficiency of chemical oxygen demand (COD) removal since photoassisted Fered-Fenton process induces the production of hydroxyl radicals from the regeneration of ferrous ions and the reaction of hydrogen peroxide with UV light. As there are so many operating parameters in photoassisted Fered-Fenton process, it is necessary to develop a mathematical model in order to produce the most economical process. In the present study, a factorial design was carried out to evaluate leachate treatment by photoassisted Fered-Fenton process. The influence of the following variables: H₂O₂ concentration, Fe(2+) concentration, current density, and initial pH in the photoassisted Fered-Fenton process was investigated by measuring COD removal efficiencies after 60-min reaction. The relationship between COD removal and the most significant independent variables was established by means of an experimental design. The H₂O₂ concentration, Fe(2+) concentration, initial pH, and the interaction effect between current density and initial pH were all significant factors. The factorial design models were derived based on the COD removal efficiency results and the models fit the data well.

  8. Toxicity assessment of tannery effluent treated by an optimized photo-Fenton process.

    PubMed

    Borba, Fernando Henrique; Módenes, Aparecido Nivaldo; Espinoza-Quiñones, Fernando Rodolfo; Manenti, Diego Ricieri; Bergamasco, Rosangela; Mora, Nora Diaz

    2013-01-01

    In this work, an optimized photo-Fenton process was applied to remove pollutants from tannery industrial effluent (TIE) with its final toxicity level being assessed by a lettuce-seed-based bioassay test. A full 33 factorial design was applied for the optimization of long-term photo-Fenton experiments. The oPtimum conditions of the photo-Fenton process were attained at concentration values of 0.3 g Fe(2+) L(-1) and 20 g H2O2 L(-1) and pH3, for 120 min UV irradiation time. Reactor operating parameter (ROP) effects on the removal of chemical oxygen demand, colour, turbidity, total suspended solids and total volatile solids were evaluated, suggesting that a broad range of ROP values are also suitable to give results very near to those of the photo-Fenton experiments under optimal conditions. Based on the low calculated median lethal dose (LD50) values from a lettuce-seed-based bioassay test, we suggest that recalcitrant substances are present in treated TIE samples. A possible cause of the high toxicity level could partly be attributed to the nitrate concentration, which was not completely abated by the photo-Fenton process. Apart from this, the photo-Fenton process can be used as a part of an industrial effluent treatment system in order to abate high organic pollutant loads. PMID:23837315

  9. Matching, maximizing, and hill-climbing

    PubMed Central

    Hinson, John M.; Staddon, J. E. R.

    1983-01-01

    In simple situations, animals consistently choose the better of two alternatives. On concurrent variable-interval variable-interval and variable-interval variable-ratio schedules, they approximately match aggregate choice and reinforcement ratios. The matching law attempts to explain the latter result but does not address the former. Hill-climbing rules such as momentary maximizing can account for both. We show that momentary maximizing constrains molar choice to approximate matching; that molar choice covaries with pigeons' momentary-maximizing estimate; and that the “generalized matching law” follows from almost any hill-climbing rule. PMID:16812350

  10. Photovoltaics - 10 years after Cherry Hill

    NASA Astrophysics Data System (ADS)

    Ralph, E. L.

    The status of R&D programs connected with photovoltaic (PV) systems 10 years after the Cherry Hill workshop on 'Photovoltaic Conversion of Solar Energy for Terrestrial Applications' is assessed. The five categories of research recommended by the Cherry Hill Workshop are listed in a table together with their recommended research budget allocations. The workshop categories include: single-crystal Si cells; poly-Si cells; systems and diagnostics. Categories for thin film CdS/Cu2S and CuInSe2 cells are also included. The roles of government and private utility companies in providing adequate financial support for PV research programs is emphasized.

  11. Elk Hills: still out in front

    SciTech Connect

    Rintoul, B.

    1982-07-01

    The producing history and capacity of the Elk Hills Oil and Gas Fields in California are described. Developments in the field are discussed, including waterflooding. The field presently produces ca. 160,000 bpd of oil and 350 mmcfd of natural gas. Gas liquids production totals ca. 683,000 gal/day. Waterflooding is expected to pay an increasingly important role in the production of crude oil. Steaming techniques also are viewed with favor after analysis of results of pilot projects. Exploratory develoment in Elk Hills also continues.

  12. Fenton peroxidation improves the drying performance of waste activated sludge.

    PubMed

    Dewil, Raf; Baeyens, Jan; Neyens, Elisabeth

    2005-01-31

    Advanced sludge treatment processes (AST) reduce the amount of sludge produced and improve the dewaterability, thus probably also affecting the heat transfer properties and the drying characteristics of the sludge. This paper studies the influence of the Fenton peroxidation on the thermal conductivity of the sludge. Results demonstrate that the Fenton's peroxidation positively influences the sludge cake consistency and hence enhances the mechanical dewaterability and the drying characteristics of the dewatered sludge. For the two sludges used in this study, i.e. obtained from the wastewater treatment plants (WWTP) of Tienen and Sint-Niklaas--the dry solids content of the mechanically dewatered sludge increased from 22.5% to 40.3% and from 18.7% to 35.2%, respectively. The effective thermal conductivity k(e) of the untreated and the peroxidized sludges is measured and used to determine the heat transfer coefficient h(s). An average improvement for k(e) of 16.7% (Tienen) and 5.8% (Sint-Niklaas) was observed. Consequently the value of h(s) increased with 15.6% (Tienen) and 5.0% (Sint-Niklaas). This increased heat transfer coefficient in combination with the increased dewaterability has direct implications on the design of sludge dryers. A plate-to-plate calculation of a multiple hearth dryer illustrates that the number of plates required to dry the peroxidized sludge to 90% DS is less than half the number of plates needed to dry untreated sludge. This results in reduced dryer dimensions or a higher capacity for an existing dryer of given dimensions.

  13. A BrachyPhantom for verification of dose calculation of HDR brachytherapy planning system

    SciTech Connect

    Austerlitz, C.; Campos, C. A. T.

    2013-11-15

    Purpose: To develop a calibration phantom for {sup 192}Ir high dose rate (HDR) brachytherapy units that renders possible the direct measurement of absorbed dose to water and verification of treatment planning system.Methods: A phantom, herein designated BrachyPhantom, consists of a Solid Water™ 8-cm high cylinder with a diameter of 14 cm cavity in its axis that allows the positioning of an A1SL ionization chamber with its reference measuring point at the midheight of the cylinder's axis. Inside the BrachyPhantom, at a 3-cm radial distance from the chamber's reference measuring point, there is a circular channel connected to a cylindrical-guide cavity that allows the insertion of a 6-French flexible plastic catheter from the BrachyPhantom surface. The PENELOPE Monte Carlo code was used to calculate a factor, P{sub sw}{sup lw}, to correct the reading of the ionization chamber to a full scatter condition in liquid water. The verification of dose calculation of a HDR brachytherapy treatment planning system was performed by inserting a catheter with a dummy source in the phantom channel and scanning it with a CT. The CT scan was then transferred to the HDR computer program in which a multiple treatment plan was programmed to deliver a total dose of 150 cGy to the ionization chamber. The instrument reading was then converted to absorbed dose to water using the N{sub gas} formalism and the P{sub sw}{sup lw} factor. Likewise, the absorbed dose to water was calculated using the source strength, S{sub k}, values provided by 15 institutions visited in this work.Results: A value of 1.020 (0.09%, k= 2) was found for P{sub sw}{sup lw}. The expanded uncertainty in the absorbed dose assessed with the BrachyPhantom was found to be 2.12% (k= 1). To an associated S{sub k} of 27.8 cGy m{sup 2} h{sup −1}, the total irradiation time to deliver 150 cGy to the ionization chamber point of reference was 161.0 s. The deviation between the absorbed doses to water assessed with the Brachy

  14. Custom-designed mouthpiece for HDR brachytherapy of embryonal rhabdomyosarcoma of the soft palate.

    PubMed

    Ekwelundu, Emmanuel; Krasin, Matthew J; Farr, Jonathan B

    2014-10-01

    This paper describes the design and fabrication of the mouthpiece used for high-dose-rate (HDR) brachytherapy of a cancerous lesion in the soft palate of a pediatric patient. A custom mouth guard made with Thermo-forming material (Clear - Mouthguard) similar to those used by athletes, with a bite section, alveolar sulcus, hard and soft palate sections was made. Markers were placed around the lesion using a color transfer applicator and the impression transferred to the mouthpiece. Ten catheters arranged in a plane were placed on the inferior side (concave part) of the mouthpiece, and held in place by stitching each to the mouthpiece. Two pieces of lead (Pb) sheets with total thickness of 5.7 mm were placed beneath the catheters. Wax was used to create additional distance between the tongue and the catheters, and the entire assembly was covered with wax. PMID:25337134

  15. Custom-designed mouthpiece for HDR brachytherapy of embryonal rhabdomyosarcoma of the soft palate.

    PubMed

    Ekwelundu, Emmanuel; Krasin, Matthew J; Farr, Jonathan B

    2014-10-01

    This paper describes the design and fabrication of the mouthpiece used for high-dose-rate (HDR) brachytherapy of a cancerous lesion in the soft palate of a pediatric patient. A custom mouth guard made with Thermo-forming material (Clear - Mouthguard) similar to those used by athletes, with a bite section, alveolar sulcus, hard and soft palate sections was made. Markers were placed around the lesion using a color transfer applicator and the impression transferred to the mouthpiece. Ten catheters arranged in a plane were placed on the inferior side (concave part) of the mouthpiece, and held in place by stitching each to the mouthpiece. Two pieces of lead (Pb) sheets with total thickness of 5.7 mm were placed beneath the catheters. Wax was used to create additional distance between the tongue and the catheters, and the entire assembly was covered with wax.

  16. Custom-designed mouthpiece for HDR brachytherapy of embryonal rhabdomyosarcoma of the soft palate

    PubMed Central

    Krasin, Matthew J.; Farr, Jonathan B.

    2014-01-01

    This paper describes the design and fabrication of the mouthpiece used for high-dose-rate (HDR) brachytherapy of a cancerous lesion in the soft palate of a pediatric patient. A custom mouth guard made with Thermo-forming material (Clear – Mouthguard) similar to those used by athletes, with a bite section, alveolar sulcus, hard and soft palate sections was made. Markers were placed around the lesion using a color transfer applicator and the impression transferred to the mouthpiece. Ten catheters arranged in a plane were placed on the inferior side (concave part) of the mouthpiece, and held in place by stitching each to the mouthpiece. Two pieces of lead (Pb) sheets with total thickness of 5.7 mm were placed beneath the catheters. Wax was used to create additional distance between the tongue and the catheters, and the entire assembly was covered with wax. PMID:25337134

  17. Cloning, molecular characterization and functional analysis of 1-hydroxy-2-methyl-2-(E)-butenyl-4-diphosphate reductase (HDR) gene for diterpenoid tanshinone biosynthesis in Salvia miltiorrhiza Bge. f. alba.

    PubMed

    Hao, Gangping; Shi, Renjiu; Tao, Ru; Fang, Qian; Jiang, Xingyu; Ji, Haiwei; Feng, Lei; Huang, Luqi

    2013-09-01

    The enzyme 1-hydroxy-2-methyl-2-(E)-butenyl-4-diphosphate reductase (HDR) is a terminal-acting enzyme in the plastid MEP pathway, which produce isoprenoid precursors. The full-length cDNA of HDR, designated SmHDR1 (Genbank Accession No. JX516088), was isolated for the first time from Salvia miltiorrhiza Bge. f. alba. SmHDR1 contains a 1389-bp open reading frame encoding 463 amino acids. The deduced SmHDR1 protein, which shows high identity to HDRs of other plant species, is predicted to possess a chloroplast transit peptide at the N-terminus and four conserved cysteine residues. Transcription pattern analysis revealed that SmHDR1 has high levels of transcription in leaves and low levels of transcription in roots and stems. The expression of SmHDR1 was induced by 0.1 mM methyl-jasmonate (MeJA) and salicylic acid (SA), but not by 0.1 mM abscisic acid (ABA), in the hairy roots of S. miltiorrhiza Bge. f. alba. Complementation of SmHDR1 in the Escherichia coli HDR mutant MG1655 ara < > ispH demonstrated the function of this enzyme. A functional color assay in E. coli showed that SmHDR1 accelerates the biosynthesis of β-carotene, indicating that SmHDR1 encodes a functional protein. Overexpression of SmHDR1 enhanced the production of tanshinones in cultured hairy roots of S. miltiorrhiza Bge. f. alba. These results indicate that SmHDR1 is a novel and important enzyme involved in the biosynthesis of diterpenoid tanshinones in S. miltiorrhiza Bge. f. alba.

  18. High level seismic/vibrational tests at the HDR: An overview

    SciTech Connect

    Kot, C.A.; Srinivasan, M.G.; Hsieh, B.J.; Schrammel, D.; Malcher, L.; Steinhilber, H.; Costello, J.F.

    1991-12-31

    As part of the Phase II testing at the HDR Test Facility in Kahl/Main, FRG, two series of high-level seismic/vibrational experiments were performed. In the first of these (SHAG) a coast-down shaker, mounted on the reactor operating floor and capable of generating 1000 tonnes of force, was used to investigate full-scale structural response, soil-structure interaction (SSI), and piping/equipment response at load levels equivalent to those of a design basis earthquake. The HDR soil/structure system was tested to incipient failure exhibiting highly nonlinear response. In the load transmission from structure to piping/equipment significant response amplifications and shifts to higher frequencies occurred. The performance of various pipe support configurations was evaluated. This latter effort was continued in the second series of tests (SHAM), in which an in-plant piping system was investigated at simulated seismic loads (generated by two servo-hydraulic actuators each capable of generating 40 tonnes of force), that exceeded design levels manifold and resulted in considerable pipe plastification and failure of some supports (snubbers). The evaluation of six different support configurations demonstrated that proper system design (for a given spectrum) rather than number of supports or system stiffness is essential to limiting pipe stresses. Pipe strains at loads exceeding the design level eightfold were still tolerable, indicating that pipe failure even under extreme seismic loads is unlikely inspite of multiple support failures. Conservatively, an excess capacity (margin) of at least four was estimated for the piping system, and the pipe damping was found to be 4%. Comparisons of linear and nonlinear computational results with measurements showed that analytical predictions have wide scatter and do not necessarily yield conservative responses, underpredicting, in particular, peak support forces.

  19. High level seismic/vibrational tests at the HDR: An overview

    SciTech Connect

    Kot, C.A.; Srinivasan, M.G.; Hsieh, B.J. ); Schrammel, D.; Malcher, L. ); Steinhilber, H. ); Costello, J.F. . Office of Nuclear Regulatory Research)

    1991-01-01

    As part of the Phase II testing at the HDR Test Facility in Kahl/Main, FRG, two series of high-level seismic/vibrational experiments were performed. In the first of these (SHAG) a coast-down shaker, mounted on the reactor operating floor and capable of generating 1000 tonnes of force, was used to investigate full-scale structural response, soil-structure interaction (SSI), and piping/equipment response at load levels equivalent to those of a design basis earthquake. The HDR soil/structure system was tested to incipient failure exhibiting highly nonlinear response. In the load transmission from structure to piping/equipment significant response amplifications and shifts to higher frequencies occurred. The performance of various pipe support configurations was evaluated. This latter effort was continued in the second series of tests (SHAM), in which an in-plant piping system was investigated at simulated seismic loads (generated by two servo-hydraulic actuators each capable of generating 40 tonnes of force), that exceeded design levels manifold and resulted in considerable pipe plastification and failure of some supports (snubbers). The evaluation of six different support configurations demonstrated that proper system design (for a given spectrum) rather than number of supports or system stiffness is essential to limiting pipe stresses. Pipe strains at loads exceeding the design level eightfold were still tolerable, indicating that pipe failure even under extreme seismic loads is unlikely inspite of multiple support failures. Conservatively, an excess capacity (margin) of at least four was estimated for the piping system, and the pipe damping was found to be 4%. Comparisons of linear and nonlinear computational results with measurements showed that analytical predictions have wide scatter and do not necessarily yield conservative responses, underpredicting, in particular, peak support forces.

  20. An automated optimization tool for high-dose-rate (HDR) prostate brachytherapy with divergent needle pattern.

    PubMed

    Borot de Battisti, M; Maenhout, M; Denis de Senneville, B; Hautvast, G; Binnekamp, D; Lagendijk, J J W; van Vulpen, M; Moerland, M A

    2015-10-01

    Focal high-dose-rate (HDR) for prostate cancer has gained increasing interest as an alternative to whole gland therapy as it may contribute to the reduction of treatment related toxicity. For focal treatment, optimal needle guidance and placement is warranted. This can be achieved under MR guidance. However, MR-guided needle placement is currently not possible due to space restrictions in the closed MR bore. To overcome this problem, a MR-compatible, single-divergent needle-implant robotic device is under development at the University Medical Centre, Utrecht: placed between the legs of the patient inside the MR bore, this robot will tap the needle in a divergent pattern from a single rotation point into the tissue. This rotation point is just beneath the perineal skin to have access to the focal prostate tumor lesion. Currently, there is no treatment planning system commercially available which allows optimization of the dose distribution with such needle arrangement. The aim of this work is to develop an automatic inverse dose planning optimization tool for focal HDR prostate brachytherapy with needle insertions in a divergent configuration. A complete optimizer workflow is proposed which includes the determination of (1) the position of the center of rotation, (2) the needle angulations and (3) the dwell times. Unlike most currently used optimizers, no prior selection or adjustment of input parameters such as minimum or maximum dose or weight coefficients for treatment region and organs at risk is required. To test this optimizer, a planning study was performed on ten patients (treatment volumes ranged from 8.5 cm(3)to 23.3 cm(3)) by using 2-14 needle insertions. The total computation time of the optimizer workflow was below 20 min and a clinically acceptable plan was reached on average using only four needle insertions. PMID:26378657

  1. Dwell time modulation restrictions do not necessarily improve treatment plan quality for prostate HDR brachytherapy

    NASA Astrophysics Data System (ADS)

    Balvert, Marleen; Gorissen, Bram L.; den Hertog, Dick; Hoffmann, Aswin L.

    2015-01-01

    Inverse planning algorithms for dwell time optimisation in interstitial high-dose-rate (HDR) brachytherapy may produce solutions with large dwell time variations within catheters, which may result in undesirable selective high-dose subvolumes. Extending the dwell time optimisation model with a dwell time modulation restriction (DTMR) that limits dwell time differences between neighboring dwell positions has been suggested to eliminate this problem. DTMRs may additionally reduce the sensitivity for uncertainties in dwell positions that inevitably result from catheter reconstruction errors and afterloader source positioning inaccuracies. This study quantifies the reduction of high-dose subvolumes and the robustness against these uncertainties by applying a DTMR to template-based prostate HDR brachytherapy implants. Three different DTMRs were consecutively applied to a linear dose-based penalty model (LD) and a dose-volume based model (LDV), both obtained from literature. The models were solved with DTMR levels ranging from no restriction to uniform dwell times within catheters in discrete steps. Uncertainties were simulated on clinical cases using in-house developed software, and dose-volume metrics were calculated in each simulation. For the assessment of high-dose subvolumes, the dose homogeneity index (DHI) and the contiguous dose volume histogram were analysed. Robustness was measured by the improvement of the lowest D90% of the planning target volume (PTV) observed in the simulations. For (LD), a DTMR yields an increase in DHI of approximately 30% and reduces the size of the largest high-dose volume by 2-5 cc. However, this comes at a cost of a reduction in D90% of the PTV of 10%, which often implies that it drops below the desired minimum of 100%. For (LDV), none of the DTMRs were able to improve high-dose volume measures. DTMRs were not capable of improving robustness of PTV D90% against uncertainty in dwell positions for both models.

  2. An automated optimization tool for high-dose-rate (HDR) prostate brachytherapy with divergent needle pattern

    NASA Astrophysics Data System (ADS)

    Borot de Battisti, M.; Maenhout, M.; de Senneville, B. Denis; Hautvast, G.; Binnekamp, D.; Lagendijk, J. J. W.; van Vulpen, M.; Moerland, M. A.

    2015-10-01

    Focal high-dose-rate (HDR) for prostate cancer has gained increasing interest as an alternative to whole gland therapy as it may contribute to the reduction of treatment related toxicity. For focal treatment, optimal needle guidance and placement is warranted. This can be achieved under MR guidance. However, MR-guided needle placement is currently not possible due to space restrictions in the closed MR bore. To overcome this problem, a MR-compatible, single-divergent needle-implant robotic device is under development at the University Medical Centre, Utrecht: placed between the legs of the patient inside the MR bore, this robot will tap the needle in a divergent pattern from a single rotation point into the tissue. This rotation point is just beneath the perineal skin to have access to the focal prostate tumor lesion. Currently, there is no treatment planning system commercially available which allows optimization of the dose distribution with such needle arrangement. The aim of this work is to develop an automatic inverse dose planning optimization tool for focal HDR prostate brachytherapy with needle insertions in a divergent configuration. A complete optimizer workflow is proposed which includes the determination of (1) the position of the center of rotation, (2) the needle angulations and (3) the dwell times. Unlike most currently used optimizers, no prior selection or adjustment of input parameters such as minimum or maximum dose or weight coefficients for treatment region and organs at risk is required. To test this optimizer, a planning study was performed on ten patients (treatment volumes ranged from 8.5 cm3to 23.3 cm3) by using 2-14 needle insertions. The total computation time of the optimizer workflow was below 20 min and a clinically acceptable plan was reached on average using only four needle insertions.

  3. Dosimetric analysis at ICRU reference points in HDR-brachytherapy of cervical carcinoma.

    PubMed

    Eich, H T; Haverkamp, U; Micke, O; Prott, F J; Müller, R P

    2000-01-01

    In vivo dosimetry in bladder and rectum as well as determining doses on suggested reference points following the ICRU report 38 contribute to quality assurance in HDR-brachytherapy of cervical carcinoma, especially to minimize side effects. In order to gain information regarding the radiation exposure at ICRU reference points in rectum, bladder, ureter and regional lymph nodes those were calculated (digitalisation) by means of orthogonal radiographs of 11 applications in patients with cervical carcinoma, who received primary radiotherapy. In addition, the doses at the ICRU rectum reference point was compared to the results of in vivo measurements in the rectum. The in vivo measurements were by factor 1.5 below the doses determined for the ICRU rectum reference point (4.05 +/- 0.68 Gy versus 6.11 +/- 1.63 Gy). Reasons for this were: calibration errors, non-orthogonal radiographs, movement of applicator and probe in the time span between X-ray and application, missing connection of probe and anterior rectal wall. The standard deviation of calculations at ICRU reference points was on average +/- 30%. Possible reasons for the relatively large standard deviation were difficulties in defining the points, identifying them on radiographs and the different locations of the applicators. Although 3 D CT, US or MR based treatment planning using dose volume histogram analysis is more and more established, this simple procedure of marking and digitising the ICRU reference points lengthened treatment planning only by 5 to 10 minutes. The advantages of in vivo dosimetry are easy practicability and the possibility to determine rectum doses during radiation. The advantages of computer-aided planning at ICRU reference points are that calculations are available before radiation and that they can still be taken into account for treatment planning. Both methods should be applied in HDR-brachytherapy of cervical carcinoma. PMID:10994367

  4. 3. GENERAL VIEW DOWN EAST HILLS DRIVE, BUILDING 20 (ONE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. GENERAL VIEW DOWN EAST HILLS DRIVE, BUILDING 20 (ONE BEDROOM) AND BUILDING 21 (TWO/THREE BEDROOM); ACTIVITY CENTER IN REAR, FACING NORTHEAST. - Aluminum City Terrace, East Hill Drive, New Kensington, Westmoreland County, PA

  5. OVERVIEW OF GOLD HILL MILL, ROAD, AND WARM SPRINGS CAMP ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    OVERVIEW OF GOLD HILL MILL, ROAD, AND WARM SPRINGS CAMP BUILDINGS, LOOKING SOUTH SOUTHEAST. THE FUNCTION OF THE FLAT AREA AT CENTER RIGHT IS UNKNOWN. - Gold Hill Mill, Warm Spring Canyon Road, Death Valley Junction, Inyo County, CA

  6. Hill-Burton Free and Reduced Cost Health Care

    MedlinePlus

    ... Hill-Burton Spanish Brochure (PDF - 83 KB) HHS Poverty Guidelines HHS Spanish Poverty Guidelines (PDF - 32 KB) Spanish Inquiry Letter (PDF - ... income is at or below the current HHS Poverty Guidelines . You may be eligible for Hill-Burton ...

  7. General Education at UNC-Chapel Hill

    ERIC Educational Resources Information Center

    Schalin, Jay; Robinson, Jenna Ashley

    2013-01-01

    The general education program at UNC-Chapel Hill has abandoned the concept of a core curriculum. Instead, students choose their "required" classes from lists of thousands of courses that may be as narrow and idiosyncratic as Love, Sex and Marriage in Soviet Culture (RUSS 277) or The Gardens, Shrines and Temples of Japan (ASIA 586).…

  8. 27 CFR 9.193 - Rattlesnake Hills.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... Valley viticultural area (27 CFR 9.69). From the beginning point, the Rattlesnake Hills viticultural area boundary line— (2) Proceeds straight eastward, crossing onto the Elephant Mountain map, to the 2,192-foot...) Yakima East Quadrangle, Washington—Yakima Co., 1953, photorevised 1985; (2) Elephant Mountain...

  9. 27 CFR 9.193 - Rattlesnake Hills.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Valley viticultural area (27 CFR 9.69). From the beginning point, the Rattlesnake Hills viticultural area boundary line— (2) Proceeds straight eastward, crossing onto the Elephant Mountain map, to the 2,192-foot...) Yakima East Quadrangle, Washington—Yakima Co., 1953, photorevised 1985; (2) Elephant Mountain...

  10. 27 CFR 9.193 - Rattlesnake Hills.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... Valley viticultural area (27 CFR 9.69). From the beginning point, the Rattlesnake Hills viticultural area boundary line— (2) Proceeds straight eastward, crossing onto the Elephant Mountain map, to the 2,192-foot...) Yakima East Quadrangle, Washington—Yakima Co., 1953, photorevised 1985; (2) Elephant Mountain...

  11. 27 CFR 9.193 - Rattlesnake Hills.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... Valley viticultural area (27 CFR 9.69). From the beginning point, the Rattlesnake Hills viticultural area boundary line— (2) Proceeds straight eastward, crossing onto the Elephant Mountain map, to the 2,192-foot...) Yakima East Quadrangle, Washington—Yakima Co., 1953, photorevised 1985; (2) Elephant Mountain...

  12. 27 CFR 9.193 - Rattlesnake Hills.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Valley viticultural area (27 CFR 9.69). From the beginning point, the Rattlesnake Hills viticultural area boundary line— (2) Proceeds straight eastward, crossing onto the Elephant Mountain map, to the 2,192-foot...) Yakima East Quadrangle, Washington—Yakima Co., 1953, photorevised 1985; (2) Elephant Mountain...

  13. 27 CFR 9.197 - Clements Hills.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... area (27 CFR 9.107). The Clements Hills viticultural areas boundary is as follows— (1) The beginning...., 1968, minor revision 1993; (4) Wallace, Calif., 1962; (5) Valley Springs SW., Calif., 1962... along the San Joaquin-Amador and San Joaquin-Calaveras County lines, crossing over the Wallace map,...

  14. 27 CFR 9.197 - Clements Hills.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... area (27 CFR 9.107). The Clements Hills viticultural areas boundary is as follows— (1) The beginning...., 1968, minor revision 1993; (4) Wallace, Calif., 1962; (5) Valley Springs SW., Calif., 1962... along the San Joaquin-Amador and San Joaquin-Calaveras County lines, crossing over the Wallace map,...

  15. 27 CFR 9.197 - Clements Hills.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... area (27 CFR 9.107). The Clements Hills viticultural areas boundary is as follows— (1) The beginning...., 1968, minor revision 1993; (4) Wallace, Calif., 1962; (5) Valley Springs SW., Calif., 1962... along the San Joaquin-Amador and San Joaquin-Calaveras County lines, crossing over the Wallace map,...

  16. 27 CFR 9.197 - Clements Hills.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... area (27 CFR 9.107). The Clements Hills viticultural areas boundary is as follows— (1) The beginning...., 1968, minor revision 1993; (4) Wallace, Calif., 1962; (5) Valley Springs SW., Calif., 1962... along the San Joaquin-Amador and San Joaquin-Calaveras County lines, crossing over the Wallace map,...

  17. 27 CFR 9.197 - Clements Hills.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... area (27 CFR 9.107). The Clements Hills viticultural areas boundary is as follows— (1) The beginning...., 1968, minor revision 1993; (4) Wallace, Calif., 1962; (5) Valley Springs SW., Calif., 1962... along the San Joaquin-Amador and San Joaquin-Calaveras County lines, crossing over the Wallace map,...

  18. An Unlikely Student Hits Capitol Hill

    ERIC Educational Resources Information Center

    Hoover, Eric

    2009-01-01

    Todd Sollar, a laid-off autoworker from Ohio who is studying for an associate degree in engineering at Sinclair Community College, in Dayton, OH, went to Capitol Hill to help educate lawmakers about the importance of including support for community colleges in the economic-stimulus bill. Mr. Sollar came to Washington with Sinclair's president, and…

  19. Numerical construction of the Hill functions.

    NASA Technical Reports Server (NTRS)

    Segethova, J.

    1972-01-01

    As an aid in the numerical construction of Hill functions and their derivatives, an algorithm using local coordinates and an expansion in Legendre polynomials is proposed. The algorithm is shown to possess sufficient stability, and the orthogonality of the Legendre polynomials simplifies the computation when the Ritz-Galerkin technique is used.

  20. The House on the Hill Challenge

    ERIC Educational Resources Information Center

    Roman, Harry T.

    2011-01-01

    In this article, the author suggests a classroom challenge that will engage students in designing a house on the hill. He suggests teachers ask a local builder to come to the school to discuss the kinds of concerns that must be dealt with when building homes in cold environments. The use of dioramas and cardboard scale models would be very useful…

  1. Ocean Hill-Brownsville, 40 Years Later

    ERIC Educational Resources Information Center

    Kahlenberg, Richard D.

    2008-01-01

    Forty years ago--on May 9, 1968--the local school board in Brooklyn's black ghetto of Ocean Hill-Brownsville sent telegrams to 19 unionized educators, informing them that their employment in the district was terminated. Eighteen were white. One black teacher was mistakenly included on the list, but reinstated almost immediately after the error was…

  2. ENHANCED REMEDIATION DEMONSTRATIONS AT HILL AFB: INTRODUCTION

    EPA Science Inventory

    Nine enhanced aquifer remediation technologies were demonstrated side-by-side at a Hill Air Force Base Chemical Disposal Pit/Fire Training Area site. The demonstrations were performed inside 3 x 5 m cells isolated from the surrounding shallow aquifer by steel piling. The site w...

  3. Plains and Hills Explored by Spirit

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Figure 1: Spirit's Long Journey, Sol 450

    This view from orbit shows the region within Gusev Crater where NASA's Mars Exploration Rover Spirit has been working for the past 15 months. The view is a mosaic of images from the Mars Orbiter Camera on NASA's Mars Global Surveyor orbiter. In the left and central portion, previously released as PIA07192, tracks made by Spirit's wheels are visible from the landing site to the edge of the 'Columbia Hills.'

    Spirit's Long Journey, Sol 450 (Full Traverse) More than 15 months after landing on Mars, NASA's Spirit rover is still going strong, having traveled a total of 4,276 meters (2.66 miles) as of martian day, or sol, 450 (April 8, 2005). This elevation map shows the traverse followed by Spirit since arriving at the 'Columbia Hills' in June, 2004. The areas colored blue are low in elevation and areas colored yellow are high in elevation. The blue area at the foot of the 'Columbia Hills' is approximately 20 meters (66 feet) higher in elevation than the site where Spirit landed in Gusev Crater. The highest peak is on the order of 80 meters (262 feet) higher still. In other words, the hills Spirit is exploring are more than 250 feet high. The map imagery is from the Mars Orbiter Camera on NASA's Mars Global Surveyor.

  4. 27 CFR 9.145 - Dunnigan Hills.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    .... The Dunnigan Hills viticultural area is located in Yolo County, California. The boundary is as follows... and U.S. Route 99W just south of the Colusa-Yolo county line; (2) From the beginning point, the... just north of the town of Yolo, California, on the Woodland, Calif., U.S.G.S. map; (3) The...

  5. 27 CFR 9.145 - Dunnigan Hills.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    .... The Dunnigan Hills viticultural area is located in Yolo County, California. The boundary is as follows... and U.S. Route 99W just south of the Colusa-Yolo county line; (2) From the beginning point, the... just north of the town of Yolo, California, on the Woodland, Calif., U.S.G.S. map; (3) The...

  6. 27 CFR 9.145 - Dunnigan Hills.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    .... The Dunnigan Hills viticultural area is located in Yolo County, California. The boundary is as follows... and U.S. Route 99W just south of the Colusa-Yolo county line; (2) From the beginning point, the... just north of the town of Yolo, California, on the Woodland, Calif., U.S.G.S. map; (3) The...

  7. 27 CFR 9.145 - Dunnigan Hills.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    .... The Dunnigan Hills viticultural area is located in Yolo County, California. The boundary is as follows... and U.S. Route 99W just south of the Colusa-Yolo county line; (2) From the beginning point, the... just north of the town of Yolo, California, on the Woodland, Calif., U.S.G.S. map; (3) The...

  8. Jesse Stuart: Lessons from the Kentucky Hills.

    ERIC Educational Resources Information Center

    Sands, Lu

    1986-01-01

    Highlights events in the life of Jesse Stuart, who began his teaching career at the age of 17 in a remote one-room school in the Kentucky hills and went on to become widely recognized as teacher, lecturer, and significant regional writer. Emphasizes Stuart's love of teaching and his personal values. (JHZ)

  9. 75. Southeast elevation of Forest Hills station looking Northwest ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    75. Southeast elevation of Forest Hills station - looking Northwest from junction of Washington and Walk Hill Streets. At left is the beginning of Section F-7 the exposed steel portion of elevated structure leading to the Forest Hills storage yard (demolished in 1985). - Boston Elevated Railway, Elevated Mainline, Washington Street, Boston, Suffolk County, MA

  10. AERIAL VIEW, LAUREL HILL CEMETERY (LEFT) AND MOUNT PEACE CEMETERY ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    AERIAL VIEW, LAUREL HILL CEMETERY (LEFT) AND MOUNT PEACE CEMETERY (RIGHT). LOCATED ACROSS RIDGE AVENUE FROM LAUREL HILL CEMETERY, MOUNT PEACE CEMETERY WAS FOUNDED BY THE ODD FELLOWS CEMETERY COMPANY IN 1865. - Laurel Hill Cemetery, 3822 Ridge Avenue, Philadelphia, Philadelphia County, PA

  11. 27 CFR 9.136 - Texas Hill Country.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Texas Hill Country. 9.136... Texas Hill Country. (a) Name. The name of the viticultural area described in this section is “Texas Hill Country.” (b) Approved maps. The appropriate maps for determining the boundaries of the “Texas...

  12. 27 CFR 9.136 - Texas Hill Country.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Texas Hill Country. 9.136... Texas Hill Country. (a) Name. The name of the viticultural area described in this section is “Texas Hill Country.” (b) Approved maps. The appropriate maps for determining the boundaries of the “Texas...

  13. 27 CFR 9.136 - Texas Hill Country.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Texas Hill Country. 9.136... Texas Hill Country. (a) Name. The name of the viticultural area described in this section is “Texas Hill Country.” (b) Approved maps. The appropriate maps for determining the boundaries of the “Texas...

  14. 27 CFR 9.136 - Texas Hill Country.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Texas Hill Country. 9.136... Texas Hill Country. (a) Name. The name of the viticultural area described in this section is “Texas Hill Country.” (b) Approved maps. The appropriate maps for determining the boundaries of the “Texas...

  15. View of south boundary of Easter Hill project site, former ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of south boundary of Easter Hill project site, former right of way for Hoffman Boulevard. Note reconstructed Easter Hill Building No. 6 at rear. Looking east - Easter Hill Village, Bordered by South Twenty-sixth Street, South Twenty-eighth Street, Hinkley Avenue, Foothill Avenue & Corto Square, Richmond, Contra Costa County, CA

  16. 27 CFR 9.190 - Red Hill Douglas County, Oregon.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Red Hill Douglas County... Areas § 9.190 Red Hill Douglas County, Oregon. (a) Name. The name of the viticultural area described in this section is “Red Hill Douglas County, Oregon”. For purposes of part 4 of this chapter, “Red...

  17. Structure, stratigraphy, and origin of Husband Hill, Columbia Hills, Gusev Crater, Mars

    NASA Astrophysics Data System (ADS)

    McCoy, T. J.; Sims, M.; Schmidt, M. E.; Edwards, L.; Tornabene, L. L.; Crumpler, L. S.; Cohen, B. A.; Soderblom, L. A.; Blaney, D. L.; Squyres, S. W.; Arvidson, R. E.; Rice, J. W.; Tréguier, E.; d'Uston, C.; Grant, J. A.; McSween, H. Y.; Golombek, M. P.; Haldemann, A. F. C.; de Souza, P. A.

    2008-06-01

    The strike and dip of lithologic units imaged in stereo by the Spirit rover in the Columbia Hills using three-dimensional imaging software shows that measured dips (15-32°) for bedding on the main edifice of the Columbia Hill are steeper than local topography (~8-10°). Outcrops measured on West Spur are conformable in strike with shallower dips (7-15°) than observed on Husband Hill. Dips are consistent with observed strata draping the Columbia Hills. Initial uplift was likely related either to the formation of the Gusev Crater central peak or ring or through mutual interference of overlapping crater rims. Uplift was followed by subsequent draping by a series of impact and volcaniclastic materials that experienced temporally and spatially variable aqueous infiltration, cementation, and alteration episodically during or after deposition. West Spur likely represents a spatially isolated depositional event. Erosion by a variety of processes, including mass wasting, removed tens of meters of materials and formed the Tennessee Valley primarily after deposition. This was followed by eruption of the Adirondack-class plains basalt lava flows which embayed the Columbia Hills. Minor erosion, impact, and aeolian processes have subsequently modified the Columbia Hills.

  18. Structure, stratigraphy, and origin of Husband Hill, Columbia Hills, Gusev Crater, Mars

    USGS Publications Warehouse

    McCoy, T.J.; Sims, M.; Schmidt, M.E.; Edwards, L.; Tornabene, L.L.; Crumpler, L.S.; Cohen, B. A.; Soderblom, L.A.; Blaney, D.L.; Squyres, S. W.; Arvidson, R. E.; Rica, J.W.; Treguier, E.; d'Uston, C.; Grant, J. A.; McSween, H.Y.; Golombek, M.P.; Haldemann, A.F.C.; de Souza, P.A.

    2008-01-01

    The strike and dip of lithologic units imaged in stereo by the Spirit rover in the Columbia Hills using three-dimensional imaging software shows that measured dips (15-32??) for bedding on the main edifice of the Columbia Hill are steeper than local topography (???8-10??). Outcrops measured on West Spur are conformable in strike with shallower dips (7-15??) than observed on Husband Hill. Dips are consistent with observed strata draping the Columbia Hills. Initial uplift was likely related either to the formation of the Gusev Crater central peak or ring or through mutual interference of overlapping crater rims. Uplift was followed by subsequent draping by a series of impact and volcaniclastic materials that experienced temporally and spatially variable aqueous infiltration, cementation, and alteration episodically during or after deposition. West Spur likely represents a spatially isolated depositional event. Erosion by a variety of processes, including mass wasting, removed tens of meters of materials and formed the Tennessee Valley primarily after deposition. This was followed by eruption of the Adirondack-class plains basalt lava flows which embayed the Columbia Hills. Minor erosion, impact, and aeolian processes have subsequently modified the Columbia Hills. Copyright 2008 by the American Geophysical Union.

  19. Decolorization kinetics of Procion H-exl dyes from textile dyeing using Fenton-like reactions.

    PubMed

    Ntampegliotis, K; Riga, A; Karayannis, V; Bontozoglou, V; Papapolymerou, G

    2006-08-10

    The decolorization kinetics of three commercially used Procion H-exl dyes was studied using a Fenton-like reagent. The effect of the major system parameters (pH, concentration of H(2)O(2) and Fe(3+) and initial dye concentration) on the kinetics was determined. For comparison, the effect of the use of UV irradiated Fenton-like reagent and of Fenton reagent on the kinetics was also examined. In addition, mineralization rates and the biodegradability improvement as well as the effect of the addition of Cl(-), CO(3)(2-) or HCO(3)(-) on the decolorization rates was studied. The reactions were carried out in a 300 ml stirred cylindrical reactor with the capability of UV irradiation. The dye half-life time goes through a minimum with respect to the solution pH between 3 and 4. It also exhibits a broad minimum with respect to Fe(3+) and H(2)O(2) at molar ratios of H(2)O(2)/Fe(3+) from about 100 to 10. The addition of CO(3)(2-) and HCO(3)(-) substantially reduces the decolorization rates, while this effect is significantly less pronounced with Cl(-). At an optimum range of parameters, the mineralization rate (TOC reduction) is very slow for the Fenton-like process (TOC decrease from an initial 49.5 to 41.1 mg/l after 30 min and to only 35.2 mg/l after 600 min), but it increases significantly for the photo-Fenton-like process (to TOC values of 39.7 and 11.4 mg/l, respectively). The biodegradability, as expressed by the BOD/COD ratio, increases significantly from an initial value of 0.11-0.55 for the Fenton-like and to 0.72 for the photo-Fenton-like processes.

  20. UV light photo-Fenton degradation of polyphenols in oolong tea manufacturing wastewater.

    PubMed

    Sabaikai, Waraluk; Sekine, Makoto; Tokumura, Masahiro; Kawase, Yoshinori

    2014-01-01

    The UV light photo-Fenton degradation of oolong tea polyphenols in tea manufacturing effluent that color the wastewater to a dark brown has been examined. In order to elucidate the photo-Fenton degradation mechanism of oolong tea polyphenols and find the optimal dosages of the Fenton reagents, systematic study has been conducted. For the UV light photo-Fenton degradation of oolong tea effluent being 70 mg-(polyphenol) L(-1), the optimum dosages of Fenton reagents were found to be 20 mgL(-1) of total Fe and 500 mgL(-1) of H2O2. The polyphenol degradation could be divided into two stages. The polyphenols concentration rapidly decreased to around 30% of the initial concentration within 2 min and the degradation rate significantly slowed down in the subsequent stage. After 60 min of UV light irradiation, 97% polyphenol removal was obtained. The initial quick degradation of oolong tea polyphenols suggests that hydroxyl radical generated by the photo-Fenton process might preferentially attack polyphenols having high antioxidant activity by scavenging hydroxyl radicals. Almost complete decolorization of the oolong tea effluent was achieved after 80 min. About 96% mineralization of 63 mgL(-1) TOC loading was achieved within 60 min and then further mineralization was rather slow. The complete COD removal of 239 mgL(-1) COD loading was obtained after 100 min. The present results indicate that the UV light photo-Fenton degradation process can treat tea manufacturing wastewaters very effectively.

  1. Surface structure and properties of biomedical NiTi shape memory alloy after Fenton's oxidation.

    PubMed

    Chu, C L; Hu, T; Wu, S L; Dong, Y S; Yin, L H; Pu, Y P; Lin, P H; Chung, C Y; Yeung, K W K; Chu, Paul K

    2007-09-01

    Fenton's oxidation is traditionally used to remove inorganic and organic pollutants from water in waster water treatment. It is an advanced oxidation process in which H2O2 is catalytically decomposed by ferrous irons into hydroxyl radicals (*OH) which have a higher oxidation potential (2.8V) than H2O2. In the work reported here, we for the first time use Fenton's oxidation to modify the surface of biomedical NiTi shape memory alloy (SMA). The influences of Fenton's oxidation on the surface microstructure, blood compatibility, leaching of harmful Ni ions and corrosion resistance in simulated body fluids is assessed using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, inductively coupled plasma mass spectrometry, electrochemical tests, hemolysis analysis and the blood platelet adhesion test. The mechanical stability of the surface titania film produced by Fenton's oxidation as well as their effects on the shape memory behavior of the SMA are studied by bending tests. Our results show that Fenton's oxidation produces a novel nanostructured titania gel film with a graded structure on the NiTi substrate without an intermediate Ni-rich layer that is typical of high-temperature oxidation. Moreover, there is a clear Ni-free zone near the top surface of the titania film. The surface structural changes introduced by Fenton's oxidation improve the electrochemical corrosion resistance and mitigate Ni release. The latter effects are comparable to those observed after oxygen plasma immersion ion implantation reported previously and better than those of high-temperature oxidation. Aging in boiling water improves the crystallinity of the titania film and further reduces Ni leaching. Blood platelet adhesion is remarkably reduced after Fenton's oxidation, suggesting that the treated SMA has improved thrombo resistance. Enhancement of blood compatibility is believed to stem from the improved hemolysis resistance, the surface wettability and the

  2. Elimination of radiocontrast agent diatrizoic acid by photo-Fenton process and enhanced treatment by coupling with electro-Fenton process.

    PubMed

    Bocos, Elvira; Oturan, Nihal; Pazos, Marta; Sanromán, M Ángeles; Oturan, Mehmet A

    2016-10-01

    The removal of radiocontrast agent diatrizoic acid (DIA) from water was performed using photo-Fenton (PF) process. First, the effect of H2O2 dosage on mineralization efficiency was determined using ultraviolet (UV) irradiation. The system reached a maximum mineralization degree of 60 % total organic carbon (TOC) removal at 4 h with 20 mM initial H2O2 concentration while further concentration values led to a decrease in TOC abatement efficiency. Then, the effect of different concentrations of Fenton's reagents was studied for homogeneous Fenton process. Obtained results revealed that 0.25 mM Fe(3+) and 20 mM H2O2 were the best conditions, achieving 80 % TOC removal efficiency at 4 h treatment. Furthermore, heterogeneous PF treatment was developed using iron-activated carbon as catalyst. It was demonstrated that this catalyst is a promising option, reaching 67 % of TOC removal within 4 h treatment without formation of iron leachate in the medium. In addition, two strategies of enhancement for process efficiency are proposed: coupling of PF with electro-Fenton (EF) process in two ways: photoelectro-Fenton (PEF) or PF followed by EF (PF-EF) treatments, achieving in both cases the complete mineralization of DIA solution within only 2 h. Finally, the Microtox tests revealed the formation of more toxic compounds than the initial DIA during PF process, while, it was possible to reach total mineralization by both proposed alternatives (PEF or PF-EF) and thus to remove the toxicity of DIA solution. PMID:27349786

  3. Elimination of radiocontrast agent diatrizoic acid by photo-Fenton process and enhanced treatment by coupling with electro-Fenton process.

    PubMed

    Bocos, Elvira; Oturan, Nihal; Pazos, Marta; Sanromán, M Ángeles; Oturan, Mehmet A

    2016-10-01

    The removal of radiocontrast agent diatrizoic acid (DIA) from water was performed using photo-Fenton (PF) process. First, the effect of H2O2 dosage on mineralization efficiency was determined using ultraviolet (UV) irradiation. The system reached a maximum mineralization degree of 60 % total organic carbon (TOC) removal at 4 h with 20 mM initial H2O2 concentration while further concentration values led to a decrease in TOC abatement efficiency. Then, the effect of different concentrations of Fenton's reagents was studied for homogeneous Fenton process. Obtained results revealed that 0.25 mM Fe(3+) and 20 mM H2O2 were the best conditions, achieving 80 % TOC removal efficiency at 4 h treatment. Furthermore, heterogeneous PF treatment was developed using iron-activated carbon as catalyst. It was demonstrated that this catalyst is a promising option, reaching 67 % of TOC removal within 4 h treatment without formation of iron leachate in the medium. In addition, two strategies of enhancement for process efficiency are proposed: coupling of PF with electro-Fenton (EF) process in two ways: photoelectro-Fenton (PEF) or PF followed by EF (PF-EF) treatments, achieving in both cases the complete mineralization of DIA solution within only 2 h. Finally, the Microtox tests revealed the formation of more toxic compounds than the initial DIA during PF process, while, it was possible to reach total mineralization by both proposed alternatives (PEF or PF-EF) and thus to remove the toxicity of DIA solution.

  4. Fenton-driven regeneration of MTBE-spent granular activated carbon - Effects of particle size and Iron Amendment Procedures

    EPA Science Inventory

    Fenton-driven regeneration of spent granular activated carbon (GAC) is a technology being developed to regenerate organic contaminant-spent GAC. Here, the effect of GAC particle size (>2 mm to <0.35 mm) on Fenton-driven oxidation of methyl tert-butyl ether (MTBE)-spent GAC was ev...

  5. Modified Fenton reaction for trichlorophenol dechlorination by enzymatically generated H2O2 and gluconic acid chelate.

    PubMed

    Ahuja, Deepak K; Bachas, Leonidas G; Bhattacharyya, D

    2007-02-01

    Glucose oxidase is a well-known enzyme that catalyzes the oxidation of beta-D-glucose to produce gluconic acid and hydrogen peroxide. Fenton reaction is a powerful oxidation technology used for the oxidation of groundwater pollutants. For the application of Fenton reaction in groundwater remediation, successful operation of Fenton reaction near neutral pH, and on-site generation of both H2O2 and chelate will be beneficial. The focus of this experimental study was to couple the glucose oxidation reaction with chelate-based Fenton reaction. The idea was to use the hydrogen peroxide and chelate gluconic acid generated during glucose oxidation for the dechlorination of 2,4,6-trichlorophenol (TCP) by Fenton reaction. The oxidation of glucose was achieved using the enzyme in free and immobilized forms. The rate of production of hydrogen peroxide was determined for each system, and was used to estimate the time required for complete consumption of glucose during the process, thus avoiding any traces of glucose in the Fenton reaction. In the case of free enzyme reaction, separation of the enzyme was achieved using an ultrafiltration membrane before initiating the Fenton reaction. The oxidation of TCP by Fenton reaction was performed at varying ratios of gluconic acid/Fe, and its effect on the decomposition of TCP and H2O2 was studied. TCP degradation was studied both in terms of parent compound degradation and free chloride generation.

  6. In vivo dosimeters for HDR brachytherapy: A comparison of a diamond detector, MOSFET, TLD, and scintillation detector

    SciTech Connect

    Lambert, Jamil; Nakano, Tatsuya; Law, Sue; Elsey, Justin; McKenzie, David R.; Suchowerska, Natalka

    2007-05-15

    The large dose gradients in brachytherapy necessitate a detector with a small active volume for accurate dosimetry. The dosimetric performance of a novel scintillation detector (BrachyFOD{sup TM}) is evaluated and compared to three commercially available detectors, a diamond detector, a MOSFET, and LiF TLDs. An {sup 192}Ir HDR brachytherapy source is used to measure the depth dependence, angular dependence, and temperature dependence of the detectors. Of the commercially available detectors, the diamond detector was found to be the most accurate, but has a large physical size. The TLDs cannot provide real time readings and have depth dependent sensitivity. The MOSFET used in this study was accurate to within 5% for distances of 20 to 50 mm from the {sup 192}Ir source in water but gave errors of 30%-40% for distances greater than 50 mm from the source. The BrachyFOD{sup TM} was found to be accurate to within 3% for distances of 10 to 100 mm from an HDR {sup 192}Ir brachytherapy source in water. It has an angular dependence of less than 2% and the background signal created by Cerenkov radiation and fluorescence of the plastic optical fiber is insignificant compared to the signal generated in the scintillator. Of the four detectors compared in this study the BrachyFOD{sup TM} has the most favorable combination of characteristics for dosimetry in HDR brachytherapy.

  7. In vivo dosimeters for HDR brachytherapy: a comparison of a diamond detector, MOSFET, TLD, and scintillation detector.

    PubMed

    Lambert, Jamil; Nakano, Tatsuya; Law, Sue; Elsey, Justin; McKenzie, David R; Suchowerska, Natalka

    2007-05-01

    The large dose gradients in brachytherapy necessitate a detector with a small active volume for accurate dosimetry. The dosimetric performance of a novel scintillation detector (BrachyFOD) is evaluated and compared to three commercially available detectors, a diamond detector, a MOSFET, and LiF TLDs. An 192Ir HDR brachytherapy source is used to measure the depth dependence, angular dependence, and temperature dependence of the detectors. Of the commercially available detectors, the diamond detector was found to be the most accurate, but has a large physical size. The TLDs cannot provide real time readings and have depth dependent sensitivity. The MOSFET used in this study was accurate to within 5% for distances of 20 to 50 mm from the 192Ir source in water but gave errors of 30%-40% for distances greater than 50 mm from the source. The BrachyFOD was found to be accurate to within 3% for distances of 10 to 100 mm from an HDR 192Ir brachytherapy source in water. It has an angular dependence of less than 2% and the background signal created by Cerenkov radiation and fluorescence of the plastic optical fiber is insignificant compared to the signal generated in the scintillator. Of the four detectors compared in this study the BrachyFOD has the most favorable combination of characteristics for dosimetry in HDR brachytherapy.

  8. A Feasibility Study of Fricke Dosimetry as an Absorbed Dose to Water Standard for 192Ir HDR Sources

    PubMed Central

    deAlmeida, Carlos Eduardo; Ochoa, Ricardo; de Lima, Marilene Coelho; David, Mariano Gazineu; Pires, Evandro Jesus; Peixoto, José Guilherme; Salata, Camila; Bernal, Mario Antônio

    2014-01-01

    High dose rate brachytherapy (HDR) using 192Ir sources is well accepted as an important treatment option and thus requires an accurate dosimetry standard. However, a dosimetry standard for the direct measurement of the absolute dose to water for this particular source type is currently not available. An improved standard for the absorbed dose to water based on Fricke dosimetry of HDR 192Ir brachytherapy sources is presented in this study. The main goal of this paper is to demonstrate the potential usefulness of the Fricke dosimetry technique for the standardization of the quantity absorbed dose to water for 192Ir sources. A molded, double-walled, spherical vessel for water containing the Fricke solution was constructed based on the Fricke system. The authors measured the absorbed dose to water and compared it with the doses calculated using the AAPM TG-43 report. The overall combined uncertainty associated with the measurements using Fricke dosimetry was 1.4% for k = 1, which is better than the uncertainties reported in previous studies. These results are promising; hence, the use of Fricke dosimetry to measure the absorbed dose to water as a standard for HDR 192Ir may be possible in the future. PMID:25521914

  9. A feasibility study of Fricke dosimetry as an absorbed dose to water standard for 192Ir HDR sources.

    PubMed

    deAlmeida, Carlos Eduardo; Ochoa, Ricardo; Lima, Marilene Coelho de; David, Mariano Gazineu; Pires, Evandro Jesus; Peixoto, José Guilherme; Salata, Camila; Bernal, Mario Antônio

    2014-01-01

    High dose rate brachytherapy (HDR) using 192Ir sources is well accepted as an important treatment option and thus requires an accurate dosimetry standard. However, a dosimetry standard for the direct measurement of the absolute dose to water for this particular source type is currently not available. An improved standard for the absorbed dose to water based on Fricke dosimetry of HDR 192Ir brachytherapy sources is presented in this study. The main goal of this paper is to demonstrate the potential usefulness of the Fricke dosimetry technique for the standardization of the quantity absorbed dose to water for 192Ir sources. A molded, double-walled, spherical vessel for water containing the Fricke solution was constructed based on the Fricke system. The authors measured the absorbed dose to water and compared it with the doses calculated using the AAPM TG-43 report. The overall combined uncertainty associated with the measurements using Fricke dosimetry was 1.4% for k = 1, which is better than the uncertainties reported in previous studies. These results are promising; hence, the use of Fricke dosimetry to measure the absorbed dose to water as a standard for HDR 192Ir may be possible in the future. PMID:25521914

  10. Effects of Fenton Reaction on Human Serum Albumin: An In Vitro Study

    PubMed Central

    Khosravifarsani, Meysam; Monfared, Ali Shabestani; Pouramir, Mahdi; Zabihi, Ebrahim

    2016-01-01

    Introduction Human serum albumin (HSA) is a critical protein in human blood plasma, which can be highly damaged by oxidative stress. The aim of this study was to analyze modifications of this protein after oxidation using a Fenton system. Methods In this 2015 experiment, different ratios of Fenton reagent (Fe2+/H2O2) was incubated with one concentration of human serum albumin (1mg/ml). Hence, HSA was incubated 30 min with various combinations of a Fenton system and quantified oxidation products such as carbonyl groups, fragmentations, degradations, and oxidized free thiol group using reliable techniques. Image and data analysis were carried out using ImageJ software and Excel (version 2007), respectively. Results An SDS-PAGE profile showed no cross link and aggregation. However, protein band intensity has decreased to 50% in the highest ratio of H2O2/Fe. Carbonylation assay indicated carbonyl/protein (molc/molp) ratio increased linearly in lower ratios and the values plateau at higher levels of H2O2/Fe 2+. The only free sulfhydryl group on HSA was oxidized in all ratios of the Fenton system. Conclusion To sum, the structure of HSA has been changed following treatment with Hydroxyl Radical as the main product of Fenton reaction. These data confirm the antioxidant activity of HSA. PMID:27790352

  11. Bio-electro-Fenton process driven by microbial fuel cell for wastewater treatment.

    PubMed

    Feng, Chun-Hua; Li, Fang-Bai; Mai, Hong-Jian; Li, Xiang-Zhong

    2010-03-01

    In this study, we proposed a new concept of utilizing the biological electrons produced from a microbial fuel cell (MFC) to power an E-Fenton process to treat wastewater at neutral pH as a bioelectro-Fenton (Bio-E-Fenton) process. This process can be achieved in a dual-chamber MFC from which electrons were generated via the catalyzation of Shewanella decolorationis S12 in its anaerobic anode chamber and transferred to its aerated cathode chamber equipped with a carbon nanotube (CNT)/gamma-FeOOH composite cathode. In the cathode chamber, the Fenton's reagents including hydrogen peroxide (H(2)O(2)) and ferrous irons (Fe(2+)) were in situ generated. This Bio-E-Fenton process led to the complete decolorization and mineralization of Orange II at pH 7.0 with the apparent first-order rate constants, k(app) = 0.212 h(-1) and k(TOC) = 0.0827 h(-1), respectively, and simultaneously produced a maximum power output of 230 mW m(-2) (normalized to the cathode surface area). The apparent mineralization current efficiency was calculated to be as high as 89%. The cathode composition was an important factor in governing system performance. When the ratio of CNT to gamma-FeOOH in the composite cathode was 1:1, the system demonstrated the fastest rate of Orange II degradation, corresponding to the highest amount of H(2)O(2) formed.

  12. Degradation of thiamethoxam by the synergetic effect between anodic oxidation and Fenton reactions.

    PubMed

    Meijide, J; Gómez, J; Pazos, M; Sanromán, M A

    2016-12-01

    In this work, a comparative study using anodic oxidation, Fenton and electro-Fenton treatments was performed in order to determine the synergic effect for the removal of thiamethoxan. The results determined that electro-Fenton process showed high efficiency in comparison with Fenton or anodic oxidation. After that, this hybrid process was optimized and the influence of iron catalyst concentration and applied current intensity on the degradation and mineralization were evaluated. Degradation profiles were monitored by high performance liquid chromatography (HPLC) being satisfactorily described by pseudo-first order kinetic model. At the optimal experimental conditions (300mA and 0.2mM Fe(+2)), the complete degradation of thiamethoxam was achieved after 10min. On the other hand, mineralization of thiamethoxam was monitored by total organic carbon (TOC) decay reaching more than 92% of TOC removal after 8h. Furthermore, a plausible mineralization pathway for the thiamethoxam degradation was proposed based on the identification of by-products such as aromatic intermediates, carboxylic acids and inorganic ions released throughout electro-Fenton process.

  13. Degradation of thiamethoxam by the synergetic effect between anodic oxidation and Fenton reactions.

    PubMed

    Meijide, J; Gómez, J; Pazos, M; Sanromán, M A

    2016-12-01

    In this work, a comparative study using anodic oxidation, Fenton and electro-Fenton treatments was performed in order to determine the synergic effect for the removal of thiamethoxan. The results determined that electro-Fenton process showed high efficiency in comparison with Fenton or anodic oxidation. After that, this hybrid process was optimized and the influence of iron catalyst concentration and applied current intensity on the degradation and mineralization were evaluated. Degradation profiles were monitored by high performance liquid chromatography (HPLC) being satisfactorily described by pseudo-first order kinetic model. At the optimal experimental conditions (300mA and 0.2mM Fe(+2)), the complete degradation of thiamethoxam was achieved after 10min. On the other hand, mineralization of thiamethoxam was monitored by total organic carbon (TOC) decay reaching more than 92% of TOC removal after 8h. Furthermore, a plausible mineralization pathway for the thiamethoxam degradation was proposed based on the identification of by-products such as aromatic intermediates, carboxylic acids and inorganic ions released throughout electro-Fenton process. PMID:26968996

  14. Combined effects of Fenton peroxidation and CaO conditioning on sewage sludge thermal drying.

    PubMed

    Liu, Huan; Liu, Peng; Hu, Hongyun; Zhang, Qiang; Wu, Zhenyu; Yang, Jiakuan; Yao, Hong

    2014-12-01

    Joint application of Fenton's reagent and CaO can dramatically enhance sludge dewaterability, thus are also likely to affect subsequent thermal drying process. This study investigated the synergistic effects of the two conditioners on the thermal drying behavior of sewage sludge and the emission characteristics of main sulfur-/nitrogen-containing gases. According to the results, Fenton peroxidation combined with CaO conditioning efficiently promoted sludge heat transfer, reduced the amounts of both free and bound water, and created porous structure in solids to provide evaporation channels, thus producing significant positive effects on sludge drying performance. In this case, the required time for drying was shortened to one-third. Additionally, joint usage of Fenton's reagent and CaO did not increase the losses of organic matter during sludge drying process. Meanwhile, they facilitated the formation of sulfate and sulfonic acid/sulfone, leading to sulfur retention in dried sludge. Both of Fenton peroxidation and CaO conditioning promoted the oxidation, decomposition, and/or dissolution of protein and inorganic nitrogen in sludge pre-treatment. As a consequence, the emissions of sulfurous and nitrogenous gases from dewatered sludge drying were greatly suppressed. These indicate that combining Fenton peroxidation with CaO conditioning is a promising strategy to improve drying efficiency of sewage sludge and to control sulfur and nitrogen contaminants during sludge thermal drying process.

  15. Influence of Fenton's reagent doses on the degradation and mineralization of H-acid.

    PubMed

    Liu, Huanhuan; Chen, Quanyuan; Yu, Yang; Liu, Zhenhong; Xue, Gang

    2013-12-15

    The recalcitrant H-acid (1-amino-8-naphthol-3,6-disulfonic acid) in aqueous solution was oxidized by Fenton process, focusing on the relation of Fenton's reagent doses and degradation products. The experimental results showed that COD and TOC removals and biodegradability (BOD/COD ratio) of the solution increased with increasing Fenton's reagent doses. Over 80% COD can be removed and the biodegradability was improved significantly. It was found that major SO3H and NH2 groups in H-acid molecules were mineralized to SO4(2-) and NH4(+) ions during Fenton oxidation processes. H-acid degradation intermediates with benzene structures substituted by hydroxyl and/or carboxyl groups were identified by GC-MS. It was also found that short-chain fatty acids primarily oxalic acid were degradation products of H-acid by Fenton oxidation. Oxalic acid accumulated could account for approximately 60% of the residual TOC. The degradation pathway of H-acid was proposed based on above analyses in this work. PMID:24231329

  16. Treatment of oilfield fracturing wastewater by a sequential combination of flocculation, Fenton oxidation and SBR process.

    PubMed

    Yang, Jian; Hong, Liang; Liu, Yan-Hong; Guo, Jian-Wei; Lin, Li-Fei

    2014-01-01

    In this study, a combined process was developed that included flocculation, Fenton oxidation and sequencing batch reactor (SBR) to treat oilfield fracturing wastewater (FW). Flocculation and Fenton oxidation were applied to reduce chemical oxygen demand (COD) organic load and to enhance biodegradability, respectively. For flocculation, the optimum conditions were: polymeric aluminium chloride dosage, 40 mg/L; polyacrylamide dosage, 4 mg/L; dilution ratio, 1:2 and stirring time, 30 min. For Fenton oxidation, a total reaction time of 60 min, a H₂O₂dosage of 2 m mol/L, with a [H₂O₂]/[FeSO₄] ratio of 2 were selected to achieve optimum oxidation. Under these optimum flocculation and Fenton oxidation conditions, the COD removal efficiency was found to be 76.6%. Following pretreatment with flocculation and Fenton oxidation, the FW was further remediated using a SBR. Results show that COD was reduced to 92 mg/L, and the overall water quality of the final effluent could meet the class I national wastewater discharge standard of petrochemical industry of China.

  17. Oil shale semicoke leachate treatment using ozonation and the Fenton oxidation.

    PubMed

    Trapido, M; Munter, R; Veressinina, Y; Kulik, N

    2006-03-01

    The storage of semicoke in Estonian oil shale industry causes a variety of impacts on the environment, including formation of a very toxic leachate, and requires additional efforts to bring the environmental situation into accord with environmental standards. The present study focused on the chemical treatment of the semicoke leachate and the usage of chemical oxidation (ozonation and the Fenton oxidation) for the improvement of conditions for subsequent biodegradation. Moderate ozone doses removed from 40 to 63 % of organics and enhanced the biodegradability. However, 40-45 % of the residual organics remained not biodegradable and ozonation did not lead to detoxification of the leachate. The Fenton oxidation was found to be effective for the treatment of leachate and led to substantial increase in biodegradability. It was ascertained that the Fenton oxidation of the leachate may be applied without pH adjustment. The toxicity reduction in the Fenton oxidation was of great significance. More than 70 % removal of COD values, increase in biodegradability and the reduction in the toxicity suggest that under some circumstances the Fenton treatment may be even applied as the main treatment process for this leachate.

  18. Fosetyl-Al photo-Fenton degradation and its endogenous catalyst inhibition.

    PubMed

    Micó, María M; Zapata, Ana; Maldonado, Manuel I; Bacardit, Jordi; Malfeito, Jorge; Sans, Carme

    2014-01-30

    Interferences from many sources can affect photo-Fenton reaction performance. Among them, catalyst inhibition can be caused by the complexation and/or precipitation of iron species by the organic matter and salts present in the reaction media. This is the case of the oxidation of effluents containing organophosphorous fosetyl-Al. The degradation of this fungicide generates phosphate anions that scavenge iron and hinder Fe(II) availability. Experimental design was applied to artificially enlighten photo-Fenton reaction, in order to evaluate fosetyl-Al degradation. The performed experiments suggested how iron inhibition takes place. The monitoring of photo-Fenton reaction over a mixture of fosetyl-Al with other two pesticides also showed the interferences caused by the presence of the fungicide on other species degradation. Solar empowered photo-Fenton was also essayed for comparison purposes. Artificial and solar light photo-Fenton reactions were revealed as effective treatments for the elimination of tested fungicide. However, the phosphate ions generated during fosetyl oxidation decreased iron availability, what hampered organic matter degradation.

  19. Degradation of p-nitrophenol in a BES-Fenton system based on limonite.

    PubMed

    Tao, Hu-Chun; Wei, Xue-Yan; Zhang, Li-Juan; Lei, Tao; Xu, Nan

    2013-06-15

    This study confirmed the feasibility of natural limonite working as the iron catalyst for the PNP wastewater treatment in the BES-Fenton system. After the start-up period of the BES-Fenton systems, air and limonite powder were injected into the cathode chamber as the original materials for manufacturing Fenton reagents of H₂O₂ and Fe(II) respectively. The experiment parameters like pH, external resistance, limonite dosage and initial PNP concentration were investigated in this research. The removal efficiency of PNP (0.25 mM) could achieve 96% in 6h under the optimal experimental conditions. A limonite dosage of 112 mg per 50 ml of PNP solution at 0.25 mM concentration each time could sustain 7 cycles of the BES-Fenton system operation with PNP removal efficiency >94%. This study suggests an efficiency and cost-effective approach for the PNP removal by using the natural limonite as the iron catalyst of the BES-Fenton system.

  20. Decolorizing textile wastewater with Fenton's reagent electrogenerated with a solar photovoltaic cell.

    PubMed

    Figueroa, Sandra; Vázquez, Leticia; Alvarez-Gallegos, A

    2009-02-01

    In this work it is demonstrated that Fenton's reagent can be electroproduced with abundant and cheap feedstock: oxygen saturated wastewater and solar energy. Experiments were carried out in a divided electrochemical flow cell using two electrodes: a three dimensional reticulated vitreous carbon cathode and stainless steel anode. Fenton's reagent is produced by oxygen reduction on the cathode in the presence of 1mM Fe(2+). The influence of electrolyte nature and its concentration and potential difference on the current efficiency, as well as the rate of Fenton's reagent electroproduction is discussed and it is concluded that over this extended range of conditions the current efficiency, for Fenton's reagent production, fell within the range 50-70%. It is possible to electroproduce a stoichiometric amount of Fenton reagent for the oxidation of 0.061mM Reactive Black 5 (in tap water+0.05M Na(2)SO(4), approximately pH 2.8). Similar results were obtained for solutions containing 0.1mM Acid Green 25. Some practical applications in the field of water treatment are included. The energy required for drive electrochemical reaction is supplied to the flow cell by means of a commercial solar panel. PMID:18977506

  1. Decolorizing textile wastewater with Fenton's reagent electrogenerated with a solar photovoltaic cell.

    PubMed

    Figueroa, Sandra; Vázquez, Leticia; Alvarez-Gallegos, A

    2009-02-01

    In this work it is demonstrated that Fenton's reagent can be electroproduced with abundant and cheap feedstock: oxygen saturated wastewater and solar energy. Experiments were carried out in a divided electrochemical flow cell using two electrodes: a three dimensional reticulated vitreous carbon cathode and stainless steel anode. Fenton's reagent is produced by oxygen reduction on the cathode in the presence of 1mM Fe(2+). The influence of electrolyte nature and its concentration and potential difference on the current efficiency, as well as the rate of Fenton's reagent electroproduction is discussed and it is concluded that over this extended range of conditions the current efficiency, for Fenton's reagent production, fell within the range 50-70%. It is possible to electroproduce a stoichiometric amount of Fenton reagent for the oxidation of 0.061mM Reactive Black 5 (in tap water+0.05M Na(2)SO(4), approximately pH 2.8). Similar results were obtained for solutions containing 0.1mM Acid Green 25. Some practical applications in the field of water treatment are included. The energy required for drive electrochemical reaction is supplied to the flow cell by means of a commercial solar panel.

  2. Hot dry rock geothermal energy development program. Annual report, fiscal year 1980

    SciTech Connect

    Cremer, G.M.

    1981-07-01

    Investigation and flow testing of the enlarged Phase I heat-extraction system at Fenton Hill continued throughout FY80. Temperature drawdown observed at that time indicated an effective fracture of approximately 40,000 to 60,000 m/sup 2/. In May 1980, hot dry rock (HDR) technology was used to produce electricity in an interface demonstration experiment at Fenton Hill. A 60-kVA binary-cycle electrical generator was installed in the Phase I surface system and heat from about 3 kg/s of geothermal fluid at 132/sup 0/C was used to boil Freon R-114, whose vapor drove a turboalternator. A Phase II system was designed and is now being constructed at Fenton Hill that should approach commercial requirements. Borehole EE-2, the injection well, was completed on May 12, 1980. It was drilled to a vertical depth of about 4500 m, where the rock temperature is approximately 320/sup 0/C. The production well, EE-3 had been drilled to a depth of 3044 m and drilling was continuing. Environmental monitoring of Fenton Hill site continued. Development of equipment, instruments, and materials for technical support at Fenton Hill continued during FY80. Several kinds of models were also developed to understand the behavior of the Phase I system and to develop a predictive capability for future systems. Data from extensive resource investigations were collected, analyzed, and assembled into a geothermal gradient map of the US, and studies were completed on five specific areas as possible locations for HDR Experimental Site 2.

  3. Prospects for the commercial development of hot dry rock geothermal energy in New Mexico

    NASA Astrophysics Data System (ADS)

    Duchane, D. V.; Goff, F.

    A vast store of energy is available to the world in the form of hot dry rock (HDR) which exists almost everywhere beneath the surface of the earth. The Los Alamos National Laboratory has developed technology to mine the heat from HDR by using techniques developed in the petroleum industry. In practice, an artificial reservoir is created in the hot rock and water is circulated through the reservoir to extract the thermal energy and bring it to the surface. There are virtually no adverse environmental effects from an HDR plant when the system is operated in a closed-loop mode with the process water continually recirculated. An experimental plant at Fenton Hill, NM is now undergoing long-term testing to demonstrate that energy can be obtained from HDR on a sustained basis with operational procedures which are readily adaptable to industry. Significant HDR resources exist in the state of New Mexico. Resources in the Valles Caldera, Zuni Uplift, and Rio Grande Rift have been evaluated in detail. Studies indicate that it should be possible to economically develop high grade HDR resources with technology available today. As advanced concepts for developing and operating HDR systems are investigated, even more widespread utilization of the technology will be commercially feasible.

  4. Uranium series dating of Allan Hills ice

    NASA Astrophysics Data System (ADS)

    Fireman, E. L.

    1986-03-01

    Uranium-238 decay series nuclides dissolved in Antarctic ice samples were measured in areas of both high and low concentrations of volcanic glass shards. Ice from the Allan Hills site (high shard content) had high Ra-226, Th-230 and U-234 activities but similarly low U-238 activities in comparison with Antarctic ice samples without shards. The Ra-226, Th-230 and U-234 excesses were found to be proportional to the shard content, while the U-238 decay series results were consistent with the assumption that alpha decay products recoiled into the ice from the shards. Through this method of uranium series dating, it was learned that the Allen Hills Cul de Sac ice is approximately 325,000 years old.

  5. The planar Hill problem with oblate primary

    NASA Astrophysics Data System (ADS)

    Papadakis, K. E.

    2004-09-01

    The regularized equations of motion of the planar Hill problem which includes the effect of the oblateness of the larger primary body, is presented. Using the Levi-Civita coordinate transformation as well as the corresponding time transformation, we obtain a simple regularized polynomial Hamiltonian of the dynamical system that corresponds to that of two uncoupled harmonic oscillators perturbed by polynomial terms. The relations between the synodic and regularized variables are also given. The convenient numerical computations of the regularized equations of motion, allow derivation of a map of the group of families of simple-periodic orbits, free of collision cases, of both the classical and the Hill problem with oblateness. The horizontal stability of the families is calculated and we determine series of horizontally critical symmetric periodic orbits of the basic families g and g'.

  6. Uranium series dating of Allan Hills ice

    NASA Technical Reports Server (NTRS)

    Fireman, E. L.

    1986-01-01

    Uranium-238 decay series nuclides dissolved in Antarctic ice samples were measured in areas of both high and low concentrations of volcanic glass shards. Ice from the Allan Hills site (high shard content) had high Ra-226, Th-230 and U-234 activities but similarly low U-238 activities in comparison with Antarctic ice samples without shards. The Ra-226, Th-230 and U-234 excesses were found to be proportional to the shard content, while the U-238 decay series results were consistent with the assumption that alpha decay products recoiled into the ice from the shards. Through this method of uranium series dating, it was learned that the Allen Hills Cul de Sac ice is approximately 325,000 years old.

  7. HDR brachytherapy of prostate cancer – two years experience in Greater Poland Cancer Centre

    PubMed Central

    Skowronek, Janusz; Chicheł, Adam

    2009-01-01

    Purpose The aim of this work was to analyze the results and complications of three treatment schemes of patients with initially localized prostate cancer after two years of observation time. Material and methods Sixty-three patients were enrolled into the study and divided into groups according to radiation schemes (I group – EBRT 50 Gy/BRT 15 Gy, II – EBRT 46 Gy/BRT 2 × 10 Gy, III group – BRT 3 × 15 Gy). Group I, II and III consisted of 46 (73%), 14 (22.2%), 3 (4.8%) patients, respectively. The low-, intermediate- and high risk groups consisted of 23 (36.5%), 18 (28.5%) and 22 (35%) men, respectively. Results and tolerance of the treatment and acute complications in analyzed groups were discussed. Results Median observation time was 24 months. Complete remission was observed in 43 patients (68.3%) out of the whole group. Locoregional and distal metastases progression were noted in 4 patients (6.4%). Partial remission was observed in low-, intermediate- and high risk group: 7.9%, 9.5% and 9.5% of all men. Nadir of PSA results were estimated as mean value of 0.094 ng/ml, average 0.0-0.63. The mean value for the complete group decreased from 0.98 ng/ml (range 0.0-9.7) in the third months to 0.32 ng/ml after one year (0.0-3.34) of the end of treatment time. Urologic and gastrointenstinal side effects were noted in different rates according to 1 month observation (dysuria – 22.2%, urinary incontinence – 7.9%, frequency – 58.7%, weak stream – 68.3%, rectal bleeding – 15.9%). Conclusions 1. HDR brachytherapy of prostate cancer can be used as a boost after or before the external beam radiation therapy in different treatment schemes. 2. In selected groups under investigation trials, sole HDR-BRT is a suitable method of treatment. 3. To confirm superiority of analyzed modality treatment a prospective investigation with larger groups of patients would be required.

  8. Fast, automatic, and accurate catheter reconstruction in HDR brachytherapy using an electromagnetic 3D tracking system

    SciTech Connect

    Poulin, Eric; Racine, Emmanuel; Beaulieu, Luc; Binnekamp, Dirk

    2015-03-15

    Purpose: In high dose rate brachytherapy (HDR-B), current catheter reconstruction protocols are relatively slow and error prone. The purpose of this technical note is to evaluate the accuracy and the robustness of an electromagnetic (EM) tracking system for automated and real-time catheter reconstruction. Methods: For this preclinical study, a total of ten catheters were inserted in gelatin phantoms with different trajectories. Catheters were reconstructed using a 18G biopsy needle, used as an EM stylet and equipped with a miniaturized sensor, and the second generation Aurora{sup ®} Planar Field Generator from Northern Digital Inc. The Aurora EM system provides position and orientation value with precisions of 0.7 mm and 0.2°, respectively. Phantoms were also scanned using a μCT (GE Healthcare) and Philips Big Bore clinical computed tomography (CT) system with a spatial resolution of 89 μm and 2 mm, respectively. Reconstructions using the EM stylet were compared to μCT and CT. To assess the robustness of the EM reconstruction, five catheters were reconstructed twice and compared. Results: Reconstruction time for one catheter was 10 s, leading to a total reconstruction time inferior to 3 min for a typical 17-catheter implant. When compared to the μCT, the mean EM tip identification error was 0.69 ± 0.29 mm while the CT error was 1.08 ± 0.67 mm. The mean 3D distance error was found to be 0.66 ± 0.33 mm and 1.08 ± 0.72 mm for the EM and CT, respectively. EM 3D catheter trajectories were found to be more accurate. A maximum difference of less than 0.6 mm was found between successive EM reconstructions. Conclusions: The EM reconstruction was found to be more accurate and precise than the conventional methods used for catheter reconstruction in HDR-B. This approach can be applied to any type of catheters and applicators.

  9. NPIP: A skew line needle configuration optimization system for HDR brachytherapy

    SciTech Connect

    Siauw, Timmy; Cunha, Adam; Berenson, Dmitry; Atamtuerk, Alper; Hsu, I-Chow; Goldberg, Ken; Pouliot, Jean

    2012-07-15

    Purpose: In this study, the authors introduce skew line needle configurations for high dose rate (HDR) brachytherapy and needle planning by integer program (NPIP), a computational method for generating these configurations. NPIP generates needle configurations that are specific to the anatomy of the patient, avoid critical structures near the penile bulb and other healthy structures, and avoid needle collisions inside the body. Methods: NPIP consisted of three major components: a method for generating a set of candidate needles, a needle selection component that chose a candidate needle subset to be inserted, and a dose planner for verifying that the final needle configuration could meet dose objectives. NPIP was used to compute needle configurations for prostate cancer data sets from patients previously treated at our clinic. NPIP took two user-parameters: a number of candidate needles, and needle coverage radius, {delta}. The candidate needle set consisted of 5000 needles, and a range of {delta} values was used to compute different needle configurations for each patient. Dose plans were computed for each needle configuration. The number of needles generated and dosimetry were analyzed and compared to the physician implant. Results: NPIP computed at least one needle configuration for every patient that met dose objectives, avoided healthy structures and needle collisions, and used as many or fewer needles than standard practice. These needle configurations corresponded to a narrow range of {delta} values, which could be used as default values if this system is used in practice. The average end-to-end runtime for this implementation of NPIP was 286 s, but there was a wide variation from case to case. Conclusions: The authors have shown that NPIP can automatically generate skew line needle configurations with the aforementioned properties, and that given the correct input parameters, NPIP can generate needle configurations which meet dose objectives and use as many

  10. Segment lengths influence hill walking strategies.

    PubMed

    Sheehan, Riley C; Gottschall, Jinger S

    2014-08-22

    Segment lengths are known to influence walking kinematics and muscle activity patterns. During level walking at the same speed, taller individuals take longer, slower strides than shorter individuals. Based on this, we sought to determine if segment lengths also influenced hill walking strategies. We hypothesized that individuals with longer segments would display more joint flexion going uphill and more extension going downhill as well as greater lateral gastrocnemius and vastus lateralis activity in both directions. Twenty young adults of varying heights (below 155 cm to above 188 cm) walked at 1.25 m/s on a level treadmill as well as 6° and 12° up and downhill slopes while we collected kinematic and muscle activity data. Subsequently, we ran linear regressions for each of the variables with height, leg, thigh, and shank length. Despite our population having twice the anthropometric variability, the level and hill walking patterns matched closely with previous studies. While there were significant differences between level and hill walking, there were few hill walking variables that were correlated with segment length. In support of our hypothesis, taller individuals had greater knee and ankle flexion during uphill walking. However, the majority of the correlations were between tibialis anterior and lateral gastrocnemius activities and shank length. Contrary to our hypothesis, relative step length and muscle activity decreased with segment length, specifically shank length. In summary, it appears that individuals with shorter segments require greater propulsion and toe clearance during uphill walking as well as greater braking and stability during downhill walking. PMID:24968942

  11. Photovoltaics - 10 years after Cherry Hill

    SciTech Connect

    Ralph, E.L.

    1984-05-01

    The question is, could a workshop today be effective in planning the next 10 years of development in the PV industry. Given is some insight into the Cherry Hill workshop, who was there and what was accomplished. Plans were made at workshop sessions, open panels discussed the needs, and invited papers were presented by experts in the field showing what concepts and ideas existed. The need for U.S. Government support of a 10 year PV development program was confirmed.

  12. Possible Meteorites in the Martian Hills

    NASA Technical Reports Server (NTRS)

    2006-01-01

    From its winter outpost at 'Low Ridge' inside Gusev Crater, NASA's Mars Exploration Rover Spirit took this spectacular, color mosaic of hilly, sandy terrain and two potential iron meteorites. The two light-colored, smooth rocks about two-thirds of the way up from the bottom of the frame have been labeled 'Zhong Shan' and 'Allan Hills.'

    The two rocks' informal names are in keeping with the rover science team's campaign to nickname rocks and soils in the area after locations in Antarctica. Zhong Shang is an Antarctic base that the People's Republic of China opened on Feb. 26, 1989, at the Larsemann Hills in Prydz Bay in East Antarctica. Allan Hills is a location where researchers have found many Martian meteorites, including the controversial ALH84001, which achieved fame in 1996 when NASA scientists suggested that it might contain evidence for fossilized extraterrestrial life. Zhong Shan was the given name of Dr. Sun Yat-sen (1866-1925), known as the 'Father of Modern China.' Born to a peasant family in Guangdong, Sun moved to live with his brother in Honolulu at age 13 and later became a medical doctor. He led a series of uprisings against the Qing dynasty that began in 1894 and eventually succeeded in 1911. Sun served as the first provisional president when the Republic of China was founded in 1912.

    The Zhong Shan and Allan Hills rocks, at the left and right, respectively, have unusual morphologies and miniature thermal emission spectrometer signatures that resemble those of a rock known as 'Heat Shield' at the Meridiani site explored by Spirit's twin, Opportunity. Opportunity's analyses revealed Heat Shield to be an iron meteorite.

    Spirit acquired this approximately true-color image on the rover's 872nd Martian day, or sol (June 16, 2006), using exposures taken through three of the panoramic camera's filters, centered on wavelengths of 600 nanometers, 530 nanometers, and 480 nanometers.

  13. Flow over periodic hills: an experimental study

    NASA Astrophysics Data System (ADS)

    Rapp, Ch.; Manhart, M.

    2011-07-01

    Two-dimensional flow over periodically arranged hills was investigated experimentally in a water channel. Two-dimensional particle image velocimetry (PIV) and one-dimensional laser Doppler anemometry (LDA) measurements were undertaken at four Reynolds numbers ({5,600} le Re le {37,000}). Two-dimensional PIV field measurements were thoroughly validated by means of point-by-point 1D LDA measurements at certain positions of the flow. A detailed study of the periodicity and the homogeneity was undertaken, which demonstrates that the flow can be regarded as two-dimensional and periodic for Re ge {10,000}. We found a decreasing reattachment length with increasing Reynolds number. This is connected to a higher momentum in the near-wall zone close to flow separation which comes from the velocity speed up above the obstacle. This leads to a velocity overshoot directly above the hill crest which increases with Reynolds number as the inner layer depth decreases. The flow speed up above that layer is independent of the Reynolds number which supports the assumption of inviscid flow disturbance in the outer layer usually made in asymptotic theory for flow over small hills.

  14. The Rocks of the Columbia Hills

    NASA Technical Reports Server (NTRS)

    Squyres, Steven W.; Arvidson, Raymond E.; Blaney, Diana L.; Clark, Benton C.; Crumpler, Larry; Farrand, William H.; Gorevan, Stephen; Herkenhoff, Kenneth; Hurowitz, Joel; Kusack, Alastair; McSween, Harry Y.; Ming, Douglas W.; Morris, Richard V.; Ruff, Steven W.; Wang, Alian; Yen, Albert

    2006-01-01

    The Mars Exploration Rover Spirit has identified five distinct rock types in the Columbia Hills of Gusev crater. Clovis Class rock is a poorly-sorted clastic rock that has undergone substantial aqueous alteration. We interpret it to be aqueously-altered ejecta deposits formed by impacts into basaltic materials. Wishstone Class rock is also a poorly-sorted clastic rock that has a distinctive chemical composition that is high in Ti and P and low in Cr. Wishstone Class rock may be pyroclastic in origin. Peace Class rock is a sedimentary material composed of ultramafic sand grains cemented by significant quantities of Mg- and Ca-sulfates. Peace Class rock may have formed when water briefly saturated the ultramafic sands, and evaporated to allow precipitation of the sulfates. Watchtower Class rocks are similar chemically to Wishstone Class rocks, and have undergone widely varying degrees of near-isochemical aqueous alteration. They may also be ejecta deposits, formed by impacts into Wishstone-rich materials and altered by small amounts of water. Backstay Class rocks are basalt/trachybasalt lavas that were emplaced in the Columbia Hills after the other rock classes were, either as impact ejecta or by localized volcanic activity. The geologic record preserved in the rocks of the Columbia Hills reveals a period very early in martian history in which volcanic materials were widespread, impact was a dominant process, and water was commonly present.

  15. Fenton-driven chemical regeneration of MTBE-spent GAC.

    PubMed

    Huling, Scott G; Jones, Patrick K; Ela, Wendell P; Arnold, Robert G

    2005-05-01

    Methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC) was chemically regenerated utilizing the Fenton mechanism. Two successive GAC regeneration cycles were performed involving iterative adsorption and oxidation processes: MTBE was adsorbed to the GAC, oxidized, re-adsorbed, oxidized, and finally re-adsorbed. Oxidant solutions comprised of hydrogen peroxide (H2O2) (1.7-2.0%) and FeSO4 x 7H2O (3 g/L) (pH 2.5), were recirculated through the GAC column (30% bed expansion). The regeneration efficiency after two full cycles of treatment was calculated to be 91%. The cost of H2O2 was 0.59 dollars/kg GAC (0.27 dollars/lb) per regeneration cycle. There was no loss of sorptive capacity. Small reductions in carbon surface area and pore volume were measured. The lack of carbon deterioration under aggressive oxidative conditions was attributed to the oxidation of the target contaminants relative to the oxidation of carbon surfaces. The reaction byproducts from MTBE oxidation, tertiary butanol and acetone, were also degraded and did not accumulate significantly on the GAC. Excessive accumulation of Fe on the GAC and consequent interference with MTBE sorption and carbon regeneration was controlled by monitoring and adjusting Fe in the oxidative solution.

  16. Biomimetic Fenton-catalyzed lignin depolymerization to high-value aromatics and dicarboxylic acids.

    PubMed

    Zeng, Jijiao; Yoo, Chang Geun; Wang, Fei; Pan, Xuejun; Vermerris, Wilfred; Tong, Zhaohui

    2015-03-01

    By mimicking natural lignin degradation systems, the Fenton catalyst (Fe(3+), H2O2) can effectively facilitate lignin depolymerization in supercritical ethanol (7 MPa, 250 °C) to give organic oils that consist of mono- and oligomeric aromatics, phenols, dicarboxylic acids, and their derivatives in yields up to (66.0±8.5) %. The thermal properties, functional groups, and surface chemistry of lignin before and after Fenton treatment were examined by thermogravimetric analysis, pyrolysis-gas chromatography-mass spectrometry, (31)P NMR spectroscopy, and X-ray photoelectron spectroscopy. The results suggest that the Fenton catalyst facilitates lignin depolymerization through cleavage of β-ether bonds between lignin residues. The formation of a lignin-iron chelating complex effectively depresses lignin recondensation; thus minimizing charcoal formation and enhancing the yield of liquid products.

  17. Oil removal from produced water by conjugation of flotation and photo-Fenton processes.

    PubMed

    da Silva, Syllos Santos; Chiavone-Filho, Osvaldo; de Barros Neto, Eduardo Lins; Foletto, Edson Luiz

    2015-01-01

    The present work investigates the conjugation of flotation and photo-Fenton techniques on oil removal performance from oilfield produced water. The experiments were conducted in a column flotation and annular lamp reactor for induced air flotation and photodegradation steps, respectively. A nonionic surfactant was used as a flotation agent. The flotation experimental data were analyzed in terms of a first-order kinetic rate model. Two experimental designs were employed to evaluate the oil removal efficiency: fractional experimental design and central composite rotational design (CCRD). Overall oil removal of 99% was reached in the optimum experimental condition after 10 min of flotation followed by 45 min of photo-Fenton. The results of the conjugation of induced air flotation and photo-Fenton processes allowed meeting the wastewater limits established by the legislations for disposal. PMID:25239685

  18. Sequential treatment of olive oil mill wastewater with adsorption and biological and photo-Fenton oxidation.

    PubMed

    Aytar, Pınar; Gedikli, Serap; Sam, Mesut; Farizoğlu, Burhanettin; Çabuk, Ahmet

    2013-05-01

    Olive oil mill wastewater (OMWW), a recalcitrant pollutant, has features including high phenolic content and dark color; thereby, several chemical or physical treatments or biological processes were not able to remediate it. In this study, the treatment efficiencies of three treatments, including adsorption, biological application, and photo-Fenton oxidation were sequentially evaluated for OMWW. Adsorption, biological treatment, and photo-Fenton caused decreasing phenolic contents of 48.69 %, 59.40 %, and 95 %, respectively. However, after three sequential treatments were performed, higher reduction percentages in phenolic (total 99 %) and organic contents (90 %) were observed. Although the studied fungus has not induced significant color reduction, photo-Fenton oxidation was considered to be an attractive solution, especially for color reduction. Besides, toxicity of OMWW treatment was significantly reduced. PMID:23054778

  19. Reduction of acute toxicity and genotoxicity of dye effluent using Fenton-coagulation process.

    PubMed

    Zhang, Jing; Chen, Shuo; Zhang, Ying; Quan, Xie; Zhao, Huimin; Zhang, Yaobin

    2014-06-15

    Dye wastewater exhibits significant ecotoxicity even though its physico-chemical parameters meet the discharge standards. In this work, the acute toxicity and genotoxicity of dye effluent were tested, and the Fenton-coagulation process was carried out to detoxify this dye effluent. The acute toxicity was evaluated according to the mortality rate of zebrafish, and genotoxicity was evaluated by micronucleus (MN) and comet assays. Removal of color and chemical oxygen demand (COD) was also investigated. The results indicated that the dye effluent showed strong acute toxicity and genotoxicity to zebrafish. After 4h of treatment by Fenton-coagulation process, the dye effluent exhibited no significant acute toxicity and genotoxicity to zebrafish. In addition, its COD was less than 50mg/L, which met the discharge standard. It demonstrates that Fenton-coagulation process can comprehensively reduce the acute toxicity and genotoxicity as well as the COD of the dye effluent.

  20. Sequential treatment of olive oil mill wastewater with adsorption and biological and photo-Fenton oxidation.

    PubMed

    Aytar, Pınar; Gedikli, Serap; Sam, Mesut; Farizoğlu, Burhanettin; Çabuk, Ahmet

    2013-05-01

    Olive oil mill wastewater (OMWW), a recalcitrant pollutant, has features including high phenolic content and dark color; thereby, several chemical or physical treatments or biological processes were not able to remediate it. In this study, the treatment efficiencies of three treatments, including adsorption, biological application, and photo-Fenton oxidation were sequentially evaluated for OMWW. Adsorption, biological treatment, and photo-Fenton caused decreasing phenolic contents of 48.69 %, 59.40 %, and 95 %, respectively. However, after three sequential treatments were performed, higher reduction percentages in phenolic (total 99 %) and organic contents (90 %) were observed. Although the studied fungus has not induced significant color reduction, photo-Fenton oxidation was considered to be an attractive solution, especially for color reduction. Besides, toxicity of OMWW treatment was significantly reduced.

  1. Depolymerization of microcrystalline cellulose by the combination of ultrasound and Fenton reagent.

    PubMed

    Zhang, Mei-Fang; Qin, Yuan-Hang; Ma, Jia-Yu; Yang, Li; Wu, Zai-Kun; Wang, Tie-Lin; Wang, Wei-Guo; Wang, Cun-Wen

    2016-07-01

    In this study, the combined use of Fenton reagent and ultrasound to the pretreatment of microcrystalline cellulose (MCC) for subsequent enzyme hydrolysis was investigated. The morphological analysis showed that the aspect ratio of MCC was greatly reduced after pretreatment. The X-ray diffraction (XRD) and degree of polymerization (DP) analyses showed that Fenton reagent was more efficient in decreasing the crystallinity of MCC while ultrasound was more efficient in decreasing the DP of MCC. The combination of Fenton reaction and ultrasound, which produced the lowest crystallinity (84.8 ± 0.2%) and DP (124.7 ± 0.6) of MCC and the highest yield of reducing sugar (22.9 ± 0.3 g/100 g), provides a promising pretreatment process for MCC depolymerization. PMID:26964965

  2. Hot dry rock energy: Hot dry rock geothermal development program. Progress report. Fiscal year 1993

    SciTech Connect

    Salazar, J.; Brown, M.

    1995-03-01

    Extended flow testing at the Fenton Hill Hot Dry Rock (HDR) test facility concluded in Fiscal Year 1993 with the completion of Phase 2 of the long-term flow test (LTFT) program. As is reported in detail in this report, the second phase of the LTFT, although only 55 days in duration, confirmed in every way the encouraging test results of the 112-day Phase I LTFT carried out in Fiscal Year 1992. Interim flow testing was conducted early in FY 1993 during the period between the two LTFT segments. In addition, two brief tests involving operation of the reservoir on a cyclic schedule were run at the end of the Phase 2 LTFT. These interim and cyclic tests provided an opportunity to conduct evaluations and field demonstrations of several reservoir engineering concepts that can now be applied to significantly increase the productivity of HDR systems. The Fenton Hill HDR test facility was shut down and brought into standby status during the last part of FY 1993. Unfortunately, the world`s largest, deepest, and most productive HDR reservoir has gone essentially unused since that time.

  3. [Degradation of organic contaminant in landfill leachate by photo-Fenton process].

    PubMed

    Zheng, Huai-Li; Pan, Yun-Xia; Li, Dan-Dan; Wu, You-Quan

    2009-06-01

    In the present work, the treatment of landfill leachate was studied by photo-Fenton process. All photocatalytic experiments were carried out under similar conditions on July or August sunny days between 12 a. m. and 14 p. m. in Chongqing based on the change in solar light intensity with time. The effect of operating conditions such as Fe/H2O2, pH value and Fenton's reagent dosage on color removal and UV254 was investigated. The UV-Vis absorption spectra of 1.00 X 10(3) mg x L(-1) landfill leachate were considered before and after photo-Fenton experiment. The experiment result indicated that photo-Fenton process can effectively remove color. The oxidation of organic materials in the leachate was pH dependent and the optimal pH was 2.5. The favorable Fe2+ to H2O2 molar ratio was 1/95. The optimal conditions in this research were Fe2+ concentration of 5.00 mmol x L(-1) and H2O2 concentration of 5.70 x 10(2) mmol x L(-1). Meanwhile, the analysis of reaction kinesics was carried out in the research. Second-order kinetic was observed for the degradation of landfill leachate, and the rate equation of photo-Fenton process was -dc/dt = -4.34[c]1.92. The result of UV-Vis spectra of landfill leachate showed that photo-Fenton process is an effective method for removal of organic compounds.

  4. Confidence Hills Mineralogy and Chemin Results from Base of Mt. Sharp, Pahrump Hills, Gale Crater, Mars

    NASA Technical Reports Server (NTRS)

    Cavanagh, P. D.; Bish, D. L.; Blake, D. F.; Vaniman, D. T.; Morris, R. V.; Ming, D. W.; Rampe, E. B.; Achilles, C. N.; Chipera, S. J.; Treiman, A. H.; Downs, R. T.; Morrison, S. M.; Fendrich, K. V.; Yen, A. S.; Grotzinger, J.; Crisp, J. A.; Bristow, T. F.; Sarrazin, P. C.; Farmer, J. D.; Des Marais, D. J.; Stolper, E. M.; Morookian, J. M.; Wilson, M. A.; Spanovich, N.; Anderson, R. C.

    2015-01-01

    The Mars Science Laboratory (MSL) rover Curiosity recently completed its fourth drill sampling of sediments on Mars. The Confidence Hills (CH) sample was drilled from a rock located in the Pahrump Hills region at the base of Mt. Sharp in Gale Crater. The CheMin X-ray diffractometer completed five nights of analysis on the sample, more than previously executed for a drill sample, and the data have been analyzed using Rietveld refinement and full-pattern fitting to determine quantitative mineralogy. Confidence Hills mineralogy has several important characteristics: 1) abundant hematite and lesser magnetite; 2) a 10 angstrom phyllosilicate; 3) multiple feldspars including plagioclase and alkali feldspar; 4) mafic silicates including forsterite, orthopyroxene, and two types of clinopyroxene (Ca-rich and Ca-poor), consistent with a basaltic source; and 5) minor contributions from sulfur-bearing species including jarosite.

  5. Tracer measurements during long-term circulation of the Rosemanowes HDR geothermal system

    SciTech Connect

    Kwakwa, K.A.

    1988-01-01

    Circulation experiments have been in operation for over two years in the artificially stimulated hot dry rock (HDR) doublet of the Camborne School of Mines (CSM) research facility in Cornwall, England. During that period tracer tests have been run at intervals using inert and reactive compounds. Initially, the results of the inert tracer investigations showed that the active volume (indicated by modal and median volumes) of the circulating system was dormant. Then, after a period of sustained oscillation, notable increases in active volume were observed which depended on both the subsequent flow rate changes and circulation time. these dynamic changes had almost reached optimum values when a downhole pump was introduced in the production well. The drawdown in the production well caused a reduction of the modal volume, whilst the median volume remained almost the same. Since then, the active volume has remained unchanged and irresponsive to circulation time and flow rate. The results of the reactive tracer tests confirm increasing chemical reaction with increasing circulation time and correlate qualitatively with the opening of newer and hotter pathways within the reservoir. However, repeated production logs throughout the circulation have identified flow paths that have depleted thermally; a discrepancy that can be explained by the geometry of the system and the preferential downward reservoir growth.

  6. A summary of the Fire Testing Program at the German HDR Test Facility

    SciTech Connect

    Nowlen, S.P.

    1995-11-01

    This report provides an overview of the fire safety experiments performed under the sponsorship of the German government in the containment building of the decommissioned pilot nuclear power plant known as HDR. This structure is a highly complex, multi-compartment, multi-level building which has been used as the test bed for a wide range of nuclear power plant operation safety experiments. These experiments have included numerous fire tests. Test fire fuel sources have included gas burners, wood cribs, oil pools, nozzle release oil fires, and cable in cable trays. A wide range of ventilation conditions including full natural ventilation, full forced ventilation, and combined natural and forced ventilation have been evaluated. During most of the tests, the fire products mixed freely with the full containment volume. Macro-scale building circulation patterns which were very sensitive to such factors as ventilation configuration were observed and characterized. Testing also included the evaluation of selective area pressurization schemes as a means of smoke control for emergency access and evacuation stairwells.

  7. A novel optical calorimetry dosimetry approach applied to an HDR Brachytherapy source

    NASA Astrophysics Data System (ADS)

    Cavan, A.; Meyer, J.

    2013-06-01

    The technique of Digital Holographic Interferometry (DHI) is applied to the measurement of radiation absorbed dose distribution in water. An optical interferometer has been developed that captures the small variations in the refractive index of water due to the radiation induced temperature increase ΔT. The absorbed dose D is then determined with high temporal and spatial resolution using the calorimetric relation D=cΔT (where c is the specific heat capacity of water). The method is capable of time resolving 3D spatial calorimetry. As a proof-of-principle of the approach, a prototype DHI dosimeter was applied to the measurement of absorbed dose from a High Dose Rate (HDR) Brachytherapy source. Initial results are in agreement with modelled doses from the Brachyvision treatment planning system, demonstrating the viability of the system for high dose rate applications. Future work will focus on applying corrections for heat diffusion and geometric effects. The method has potential to contribute to the dosimetry of diverse high dose rate applications which require high spatial resolution such as microbeam radiotherapy (MRT) or small field proton beam dosimetry but may potentially also be useful for interface dosimetry.

  8. The Application of Elliptic Cylindrical Phantom in Brachytherapy Dosimetric Study of HDR 192Ir Source

    NASA Astrophysics Data System (ADS)

    Ahn, Woo Sang; Park, Sung Ho; Jung, Sang Hoon; Choi, Wonsik; Do Ahn, Seung; Shin, Seong Soo

    2014-06-01

    The purpose of this study is to determine the radial dose function of HDR 192Ir source based on Monte Carlo simulation using elliptic cylindrical phantom, similar to realistic shape of pelvis, in brachytherapy dosimetric study. The elliptic phantom size and shape was determined by analysis of dimensions of pelvis on CT images of 20 patients treated with brachytherapy for cervical cancer. The radial dose function obtained using the elliptic cylindrical water phantom was compared with radial dose functions for different spherical phantom sizes, including the Williamsion's data loaded into conventional planning system. The differences in the radial dose function for the different spherical water phantoms increase with radial distance, r, and the largest differences in the radial dose function appear for the smallest phantom size. The radial dose function of the elliptic cylindrical phantom significantly decreased with radial distance in the vertical direction due to different scatter condition in comparison with the Williamson's data. Considering doses to ICRU rectum and bladder points, doses to reference points can be underestimated up to 1-2% at the distance from 3 to 6 cm. The radial dose function in this study could be used as realistic data for calculating the brachytherapy dosimetry for cervical cancer.

  9. Enhancement and validation of Geant4 Brachytherapy application on clinical HDR 192Ir source

    NASA Astrophysics Data System (ADS)

    Ababneh, Eshraq; Dababneh, Saed; Qatarneh, Sharif; Wadi-Ramahi, Shada

    2014-10-01

    The Geant4 Monte Carlo MC associated Brachytherapy example was adapted, enhanced and several analysis techniques have been developed. The simulation studies the isodose distribution of the total, primary and scattered doses around a Nucletron microSelectron 192Ir source. Different phantom materials were used (water, tissue and bone) and the calculation was conducted at various depths and planes. The work provides an early estimate of the required number of primary events to ultimately achieve a given uncertainty at a given distance, in the otherwise CPU and time consuming clinical MC calculation. The adaptation of the Geant4 toolkit and the enhancements introduced to the code are all validated including the comprehensive decay of the 192Ir source, the materials used to build the geometry, the geometry itself and the calculated scatter to primary dose ratio. The simulation quantitatively illustrates that the scattered dose in the bone medium is larger than its value in water and tissue. As the distance away from the source increases, scatter contribution to dose becomes more significant as the primary dose decreases. The developed code could be viewed as a platform that contains detailed dose calculation model for clinical application of HDR 192Ir in Brachytherapy.

  10. Feasibility of MatriXX 2D detector array for HDR brachytherapy planning system assessment

    NASA Astrophysics Data System (ADS)

    Zeman, Jozef; Valenta, Jiri; Gabris, Frantisek; Grezdo, Jozef; Stastna, Simona

    2012-10-01

    IBA Dosimetry GmbH participated in the Joint Research Project ‘Increasing cancer treatment efficacy using 3D brachytherapy’ as a non-funded partner in the work package which was mostly dedicated to the determination of dose-to-water distribution from a high-dose-rate (HDR) brachytherapy source. The dose distribution was measured with a MatriXX (MXX) 2D detector array and compared with Dose Cube Data, calculated by treatment planning systems (TPS). All measurements and calculations were performed in cooperation with OUSA, Bratislava and FNB, Prague. The comparison has been carried out for three irradiation geometries: single source position, single line and four line motions of the source, and with the effective point of measurement in a plane at 6 mm, 10 mm and 20 mm distance from the source position. The comparison of the MXX measurements and the TPS calculations was evaluated by the commercial IBA Dosimetry software OmniPro I'mRT (1) as the difference between maximum of measured and calculated values and (2) as the maximum difference between the two-dimensional distributions of measured and calculated values. The dose distribution was evaluated by the gamma method with parameters 3 mm and 3%. All differences of comparison of the MXX measurements and TPS calculations were within the range ±10% and the γ-index was less than 1 for 96% (or 97%, respectively) of the dose distribution in the plane at 10 mm distance from the source position.

  11. Chloride accelerated Fenton chemistry for the ultrasensitive and selective colorimetric detection of copper.

    PubMed

    Shan, Zhi; Lu, Mingsheng; Wang, Li; MacDonald, Bruce; MacInnis, Judy; Mkandawire, Martin; Zhang, Xu; Oakes, Ken D

    2016-02-01

    A highly selective, ultrasensitive (visual and instrumental detection limits of 40 nM and 0.1 nM, respectively), environmentally-friendly, simple and rapid colorimetric sensor was developed for the detection of copper(II) in water. This sensor is based on a novel signal-amplification mechanism involving reactive halide species (RHSs) including chlorides or bromides, which accelerate copper Fenton reactions oxidizing the chromogenic substrate to develop colour. The results of this study expand our understanding of copper-based Fenton chemistry. PMID:26685747

  12. Three-dimensional potential flow over hills and oval mounds

    NASA Technical Reports Server (NTRS)

    Siegel, R.

    1976-01-01

    An analysis was made of the potential flow behavior for an initially uniform flow passing over a single axisymmetric hill, an oval mound, and a combination of two hills. Small perturbation theory was used, and the resulting Laplace equation for the perturbation velocity potential was solved by using either a product solution or a Green's function. The three dimensional solution is of interest in calculating the pressure distribution around obstacles, the flow of pollutants carried by the wind, and the augmentation of wind velocity for windmill siting. The augmentation in velocity at the top of a hill was found to be proportional to the hill height relative to a characteristic width dimension of the hill. An axisymmetric hill produced about 20 percent less velocity increase than a two dimensional ridge having the same cross-sectional profile.

  13. PLANS AND SECTIONS. WEIR SPILLWAY. TEXAS HILL CANAL STA. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    PLANS AND SECTIONS. WEIR SPILLWAY. TEXAS HILL CANAL - STA. 132+82.15. TEXAS HILL CANAL AND DISTRIBUTION SYSTEM. United States Department of Interior, Bureau of Reclamation; Gila Project, Arizona, Wellton-Mohawk Division. Drawing No. 50-D-3200, dated February 7, 1955, Denver, Colorado - Wellton-Mohawk Irrigation System, Relift Station, Texas Hill Canal 2.5, Northern Terminus of Avenue 51 East, approximately .5 mile south of Union Pacific Railroad, Wellton, Yuma County, AZ

  14. Degradation of carbofuran in aqueous solution by ultrasound and Fenton processes: Effect of system parameters and kinetic study.

    PubMed

    Ma, Ying-Shih; Sung, Chi-Fanga; Lin, Jih-Gaw

    2010-06-15

    To establish an efficient oxidation process for carbofuran degradation, the effects of some operating parameters such as dosages of H(2)O(2), Fe(2+) and initial carbofuran concentrations were observed during carbofuran degradation by the ultrasound process, Fenton process and a combined ultrasound/Fenton process. The degradation kinetics of carbofuran was also examined based on the experimental data. The results show that more than 99% of the carbofuran was degraded by the ultrasound/Fenton process within short reaction time periods. Increased dosages of H(2)O(2) and Fe(2+) enhanced the degradation of carbofuran in the ultrasound and Fenton oxidation processes, but initial carbofuran concentrations decreased carbofuran degradation in both the Fenton and ultrasound/Fenton processes. The degradation kinetics of carbofuran by the three oxidation processes was found to be in accordance with first-order reaction kinetics. The results provide fundamental information about the treatment of carbofuran wastewater and/or other pesticides by the ultrasound/Fenton oxidation process.

  15. 10. Historic American Buildings Survey Joseph Hill, Photographer May, 1936 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    10. Historic American Buildings Survey Joseph Hill, Photographer May, 1936 EAST ELEVATION - Rock Island Arsenal, Building No. 346, Davenport Drive, Arsenal Grounds, Rock Island, Rock Island County, IL

  16. 78 FR 73187 - Black Hills National Forest Advisory Board

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-05

    ... entry into the building. FOR FURTHER INFORMATION CONTACT: Scott Jacobson, Committee Coordinator, by... requests for oral comments must be sent to Scott Jacobson, Black Hills National Forest Supervisor's...

  17. RYAN HILL ROADLESS AREA, NEW MEXICO.

    USGS Publications Warehouse

    Maxwell, C.H.; Ellis, C.E.

    1984-01-01

    On the basis of a geochemical survey, the Ryan Hill Roadless Area, now the Langmuir Research Site in New Mexico has both probable and substantiated resource potential for manganese deposits. The nature of the geologic terrane holds little likelihood for the occurrence of organic fuels. Additional geochemical studies of the manganese vein systems are desirable to better delineate the resource potential; mineralogical and metallurgical studies are needed to determine recoverability of potentially important byproducts, including tungsten and cobalt. Drilling into the vein system at depth would be required to test the continuity of the manganese deposits and evaluate the resource potential of the area for deeply buried base- and precious-metal resources.

  18. Spirit's View of 'Columbia Hills' (3-D)

    NASA Technical Reports Server (NTRS)

    2004-01-01

    [figure removed for brevity, see original site] Figure 1

    [figure removed for brevity, see original site] Figure 2

    NASA's Mars Exploration Rover Spirit looked up at the 'Columbia Hills' from its location on the 265th martian day, or sol, of its mission (Sept. 30, 2004) and captured this 3-D view. This cropped mosaic image, presented here in a cylindrical-perspective projection with geometric seam correction, was taken by the rover's navigation camera.

    Figure 1 is the left-eye view of a stereo pair and Figure 2 is the right-eye view of a stereo pair.

  19. Mineralization of sulfanilamide by electro-Fenton and solar photoelectro-Fenton in a pre-pilot plant with a Pt/air-diffusion cell.

    PubMed

    El-Ghenymy, Abdellatif; Cabot, Pere Lluís; Centellas, Francesc; Garrido, José Antonio; Rodríguez, Rosa María; Arias, Conchita; Brillas, Enric

    2013-05-01

    The mineralization of sulfanilamide solutions at pH 3.0 was comparatively studied by electro-Fenton (EF) and solar photoelectro-Fenton (SPEF) using a 2.5 L pre-pilot plant containing a Pt/air-diffusion cell coupled with a solar photoreactor. Organics were primordially oxidized by hydroxyl radical (OH) formed from Fenton's reaction between H₂O₂ generated at the cathode and added Fe(2+) and/or under the action of sunlight. A mineralization up to 94% was achieved using SPEF, whereas EF yielded much poorer degradation. The effect of current density and Fe(2+) and drug concentrations on the degradation rate, mineralization current efficiency and energy cost per unit DOC mass of EF and/or SPEF was examined. The sulfanilamide decay always followed a pseudo first-order kinetics, being more rapid in SPEF due to the additional generation of OH induced by sunlight on Fe(III) species. Catechol, resorcinol, hydroquinone and p-benzoquinone were identified as aromatic intermediates. The final solutions treated by EF contained Fe(III) complexes of maleic, fumaric, oxamic and mainly oxalic acids, which are hardly destroyed by OH. The quick photolysis of Fe(III)-oxalate complexes by sunlight explains the higher oxidation ability of SPEF. The N content of sulfanilamide was mainly mineralized as NH₄⁺ ion and in much lesser extent as NO₃⁻ ion, whereas most of its initial S was converted into SO₄²⁻ ion. PMID:23561569

  20. Electro-fenton and photoelectro-fenton degradation of sulfanilic acid using a boron-doped diamond anode and an air diffusion cathode.

    PubMed

    El-Ghenymy, Abdellatif; Garrido, José Antonio; Centellas, Francesc; Arias, Conchita; Cabot, Pere Lluís; Rodríguez, Rosa María; Brillas, Enric

    2012-04-01

    The mineralization of sulfanilic acid has been studied by electro-Fenton (EF) and photoelectro-Fenton (PEF) reaction with UVA light using an undivided electrochemical cell with a boron-doped diamond (BDD) anode and an air diffusion cathode able to generate H(2)O(2). Organics were then oxidized by hydroxyl radicals formed at the anode surface from water oxidation and in the bulk from Fenton's reaction between generated H(2)O(2) and added Fe(2+). The UVA irradiation in PEF enhanced the production of hydroxyl radicals in the bulk, accelerating the removal of organics and photodecomposed intermediates like Fe(III)-carboxylate complexes. Partial decontamination of 1.39 mM sulfanilic acid solutions was achieved by EF until 100 mA cm(-2) at optimum conditions of 0.4 mM Fe(2+) and pH 3.0. The increase in current density and substrate content led to an almost total mineralization. In contrast, the PEF process was more powerful, yielding almost complete mineralization in less electrolysis time under comparable conditions. The kinetics for sulfanilic acid decay always followed a pseudo-first-order reaction. Hydroquinone and p-benzoquinone were detected as aromatic intermediates, whereas acetic, maleic, formic, oxalic, and oxamic acids were identified as generated carboxylic acids. NH(4)(+) ion was preferentially released in both treatments, along with NO(3)(-) ion in smaller proportion.

  1. Wastewater treatment from biodiesel production via a coupled photo-Fenton-aerobic sequential batch reactor (SBR) system.

    PubMed

    Ramírez, Ximena María Vargas; Mejía, Gina Maria Hincapié; López, Kelly Viviana Patiño; Vásquez, Gloria Restrepo; Sepúlveda, Juan Miguel Marín

    2012-01-01

    A coupled system of the photo-Fenton advanced oxidation technique and an aerobic sequential batch reactor (SBR) was used to treat wastewater from biodiesel production using either palm or castor oil. The photo-Fenton reaction and biological process were evaluated individually and were effective at treating the wastewater; nevertheless, each process required longer degradation times for the wastewater pollutants compared with the coupled system. The proposed coupled photo-Fenton/aerobic SBR system obtained a 90% reduction of the chemical oxygen demand (COD) in half of the time required for the biological system individually. PMID:22766873

  2. Enhancing biodegradability of priority substances (pesticides) by solar photo-Fenton.

    PubMed

    Lapertot, Milena; Pulgarín, César; Fernández-Ibáñez, Pilar; Maldonado, Manuel I; Pérez-Estrada, Leonidas; Oller, Isabel; Gernjak, Wolfgang; Malato, Sixto

    2006-03-01

    In this paper, we present the photo-Fenton treatment in a solar pilot-plant scale of several EU priority hazardous substances (Alachlor, Atrazine, Chlorfenvinphos, Diuron and Isoproturon) dissolved in water. The results have been evaluated not only from the point of view of contaminant disappearance and mineralisation, but also of toxicity reduction and enhancement of biodegradability. Degradation was monitored by total organic carbon, pesticide concentration by HPLC-UV, inorganics released by ion chromatography, and biodegradability by the Zahn-Wellens (Z-W) test. The total volume of the solar photoreactor, composed of compound parabolic collectors with a total area of 4.16m2, was between 70 and 82 L. The treatment was shown to be effective, mineralising all of the pesticides tested, both alone and in mixtures. In order to find out the conditions for biocompatibility using the photo-Fenton reaction as a pre-treatment step, wastewater inoculated with unacclimated municipal sludge containing pesticides after certain degradation time was evaluated by the Z-W test. Biodegradability was enhanced (70% considered biodegradable) by the photo-Fenton treatment after 12-25min. It may be concluded that the photo-Fenton treatment consistently enhances biodegradability of wastewater containing pesticides.

  3. Effects of inorganic anions on carbon isotope fractionation during Fenton-like degradation of trichloroethene.

    PubMed

    Liu, Yunde; Zhou, Aiguo; Gan, Yiqun; Li, Xiaoqian

    2016-05-01

    Understanding the magnitude and variability in isotope fractionation with respect to specific processes is crucial to the application of stable isotopic analysis as a tool to infer and quantify transformation processes. The variability of carbon isotope fractionation during Fenton-like degradation of trichloroethene (TCE) in the presence of different inorganic ions (nitrate, sulfate, and chloride), was investigated to evaluate the potential effects of inorganic anions on carbon isotope enrichment factor (ε value). A comparison of ε values obtained in deionized water, nitrate solution, and sulfate solution demonstrated that the ε values were identical and not affected by the presence of nitrate and sulfate. In the presence of chloride, however, the ε values (ranging from -6.3±0.8 to 10±1.3‰) were variable and depended on the chloride concentration, indicating that chloride could significantly affect carbon isotope fractionation during Fenton-like degradation of TCE. Thus, caution should be exercised in selecting appropriate ε values for the field application of stable isotope analysis, as various chloride concentrations may be present due to naturally present or introduced with pH adjustment and iron salts during Fenton-like remediation. Furthermore, the effects of chloride on carbon isotope fractionation may be able to provide new insights about reaction mechanisms of Fenton-like processes.

  4. Oxidation of AOX and organic compounds in pharmaceutical wastewater in RSM-optimized-Fenton system.

    PubMed

    Xie, Yawei; Chen, Lujun; Liu, Rui

    2016-07-01

    Adsorbable organic halogens (AOX) and total organic carbon (TOC) removal efficiencies in pharmaceutical wastewater treated by Fenton process under response surface methodology (RSM) optimized conditions were studied. High regression coefficient value R(2) (R(2) = 0.9680, 0.9040 for AOX and TOC removal efficiency, respectively) and low value coefficient of variation (2.21%, 2.04% for AOX and TOC, respectively) of the quadratic model indicated that the model was accurate in predicting the experimental results. The desirability function was used to optimize AOX and TOC removal efficiencies simultaneously. The optimal pH, Fe(2+) concentration, molar ratio of H2O2/Fe(2+) and reaction time were found to be 3.3, 19.05 mM, 20.16 and 2.2 h, respectively, and 91.78% AOX and 75.01% TOC were removed under these conditions, which was validated. Furthermore, gas chromatography-mass spectrometer (GC-MS) results revealed that 28 out of 33 kinds of organic compounds, including 11 kinds of AOX were completely removed by the Fenton process while one new AOX compound, 4,5,6,7-tetrachlorophthalide, was produced which was the result of the carbonyl of 4,5,6,7-tetrachloro-1,3-isobenzofurandione being attacked in the Fenton reaction. These results indicated that analysis of organics was important since new AOX compounds could be produced in Fenton process despite the value of AOX decreasing. PMID:27115846

  5. Using Fenton Oxidation to Simultaneously Remove Different Estrogens from Cow Manure.

    PubMed

    Sun, Minxia; Xu, Defu; Ji, Yuefei; Liu, Juan; Ling, Wanting; Li, Shunyao; Chen, Mindong

    2016-01-01

    The presence of estrogens in livestock excrement has raised concerns about their potential negative influence on animals and the overall food cycle. This is the first investigation to simultaneously remove estrogens, including estriol (E3), bisphenol A (BPA), diethylstilbestrol (DES), estradiol (E2), and ethinyl estradiol (EE2), from cow manure using a Fenton oxidation technique. Based on the residual concentrations and removal efficiency of estrogens, the Fenton oxidation reaction conditions were optimized as follows: a H₂O₂ dosage of 2.56 mmol/g, a Fe(II) to H₂O₂ molar ratio of 0.125 M/M, a solid to water mass ratio of 2 g/mL, an initial pH of 3, and a reaction time of 24 h. Under these conditions, the simultaneous removal efficiencies of E3, BPA, DES, E2, and EE2, with initial concentrations in cow manure of 97.40, 96.54, 100.22, 95.01, and 72.49 mg/kg, were 84.9%, 99.5%, 99.1%, 97.8%, and 84.5%, respectively. We clarified the possible Fenton oxidation reaction mechanisms that governed the degradation of estrogens. We concluded that Fenton oxidation technique could be effective for efficient removal of estrogens in livestock excrement. Results are of great importance for cow manure reuse in agricultural management, and can be used to reduce the threat of environmental estrogens to human health and ecological safety. PMID:27649223

  6. Spent caustic oxidation using electro-generated Fenton's reagent in a batch reactor.

    PubMed

    Rodriguez, Nicolas; Hansen, Henrik K; Nunez, Patricio; Guzman, Jaime

    2008-07-01

    This work shows the results of four Electro-Fenton laboratory tests to reduce the chemical oxygen demand (COD) in spent caustic solutions. The treatment consisted of (i) a pH reduction followed by (ii) an Electro-Fenton process, which was analyzed in this work. The Fenton's reagent was produced in a specially designed reactor, where the waste stream flowed through a labyrinth made by ferrous plates. These plates acted as sacrificial anodes-releasing Fe(2 +) cations to the solution, where H(2)O(2) was also added. The Electro-Fenton process was analyzed varying the ferrous ion concentration ([Fe(+ 2)]), the spent caustic's initial temperature and the initial pH. Close to 95% removal of COD (from 8800 mg L(- 1)) was achieved at a pH of 4, a temperature of 40 degrees C and 100 mg L(- 1) of Fe(+ 2) (applying 1 A). Two models were considered to simulate the behavior of the reactor considering (i) axial dispersion and (ii) kinetic rate, respectively. The model that was based on kinetics, proved to be the slightly closest fit to the experimental values. PMID:18569308

  7. Studies on modulation of DNA integrity in Fenton's system by phytochemicals.

    PubMed

    Benherlal, Palayyan Saraswathy; Arumughan, Chami

    2008-12-15

    Chronic exposure to oxidative stress especially to highly reactive hydroxyl radicals (HO*) could damage biomolecules, particularly DNA, that in turn would accelerate onset of degenerative diseases. In the present study a few standard phytochemicals (vitamin C, gallic acid, catechin, apigenin, naringenin and naringin) and plant extracts (Hippophae rhamnoides kernel (HRK), Syzygium cumini kernel (SCK) and Punica granatum pericarp (PGP)) were evaluated for their potential to protect/damage DNA in Fenton's system using in vitro models. The results indicated a significant DNA protective effect for naringin and PGP whereas other phytochemicals/extracts showed DNA damaging effect similar to or more than that of control value. The phytochemicals/extracts were also evaluated for their antioxidant and iron chelation properties. In general, the phytochemicals/extracts with high antioxidant activity but without iron chelation capacity failed to protect DNA in Fenton's system, suggesting that iron chelation was an essential requirement for the phytochemicals studied here to retard HO* generation by Fenton's reaction. This was demonstrated by the high iron chelation capacity of naringin and PGP (83.67% and 68.67% respectively) and their DNA protective effect. Commonly consumed phytochemicals such as vitamin C and gallic acid with their high reducing power and at higher physiological concentration, could regenerate free iron for Fenton's reaction leading to DNA damage as shown here. PMID:18824181

  8. Development of a trickle bed reactor of electro-Fenton process for wastewater treatment.

    PubMed

    Lei, Yangming; Liu, Hong; Shen, Zhemin; Wang, Wenhua

    2013-10-15

    To avoid electrolyte leakage and gas bubbles in the electro-Fenton (E-Fenton) reactors using a gas diffusion cathode, we developed a trickle bed cathode by coating a layer composed of carbon black and polytetrafluoroethylene (C-PTFE) onto graphite chips instead of carbon cloth. The trickle bed cathode was optimized by single-factor and orthogonal experiments, in which carbon black, PTFE, and a surfactant were considered as the determinant of the performance of graphite chips. In the reactor assembled by the trickle bed cathode, H2O2 was generated with a current of 0.3A and a current efficiency of 60%. This performance was attributed to the fine distribution of electrolyte and air, as well as the effective oxygen transfer from the gas phase to the electrolyte-cathode interface. In terms of H2O2 generation and current efficiency, the developed trickle bed reactor had a performance comparable to that of the conventional E-Fenton reactor using a gas diffusion cathode. Further, 123 mg L(-1) of reactive brilliant red X-3B in aqueous solution was decomposed in the optimized trickle bed reactor as E-Fenton reactor. The decolorization ratio reached 97% within 20 min, and the mineralization reached 87% within 3h.

  9. IRON OPTIMIZATION FOR FENTON-DRIVEN OXIDATION OF MTBE-SPENT GRANULAR ACTIVATED CARBON

    EPA Science Inventory

    Fenton-driven chemical regeneration of granular activated carbon (GAC) is accomplished through the addition of H2O2 and iron (Fe) to spent GAC. The overall objective of this treatment process is to transform target contaminants into less toxic byproducts, re-establish the sorpti...

  10. Application of electro-Fenton technology to remediation of polluted effluents by self-sustaining process.

    PubMed

    Fernández de Dios, Maria Ángeles; Iglesias, Olaia; Pazos, Marta; Sanromán, Maria Ángeles

    2014-01-01

    The applicability of electro-Fenton technology to remediation of wastewater contaminated by several organic pollutants such as dyes and polycyclic aromatic hydrocarbons has been evaluated using iron-enriched zeolite as heterogeneous catalyst. The electro-Fenton technology is an advanced oxidation process that is efficient for the degradation of organic pollutants, but it suffers from the high operating costs due to the need for power investment. For this reason, in this study microbial fuel cells (MFCs) were designed in order to supply electricity to electro-Fenton processes and to achieve high treatment efficiency at low cost. Initially, the effect of key parameters on the MFC power generation was evaluated. Afterwards, the degradation of Reactive Black 5 dye and phenanthrene was evaluated in an electro-Fenton reactor, containing iron-enriched zeolite as catalyst, using the electricity supplied by the MFC. Near complete dye decolourization and 78% of phenanthrene degradation were reached after 90 min and 30 h, respectively. Furthermore, preliminary reusability tests of the developed catalyst showed high degradation levels for successive cycles. The results permit concluding that the integrated system is adequate to achieve high treatment efficiency with low electrical consumption. PMID:24723828

  11. Electro-Fenton decolourisation of dyes in an airlift continuous reactor using iron alginate beads.

    PubMed

    Iglesias, O; Rosales, E; Pazos, M; Sanromán, M A

    2013-04-01

    In this study, electro-Fenton dye degradation was performed in an airlift continuous reactor configuration by harnessing the catalytic activity of Fe alginate gel beads. Electro-Fenton experiments were carried out in an airlift reactor with a working volume of 1.5 L, air flow of 1.5 L/min and 115 g of Fe alginate gel beads. An electric field was applied by two graphite bars connected to a direct current power supply with a constant potential drop. In this study, Lissamine Green B and Reactive Black 5 were selected as model dyes. Fe alginate gel beads can be used as an effective heterogeneous catalyst for the degradation of organic dyes in the electro-Fenton process, as they are more efficient than the conventional electrochemical techniques. At optimal working conditions (3 V and pH 2), the continuous process was performed. For both dyes, the degree of decolourisation increases when the residence time augments. Taking into account hydrodynamic and kinetic behaviour, a model to describe the reactor profile was obtained, and the standard deviation between experimental and theoretical data was lower than 6%. The results indicate the suitability of the electro-Fenton technique to oxidise polluted effluents in the presence of Fe alginate gel beads. Moreover, the operation is possible in a continuous airlift reactor, due to the entrapment of iron in the alginate matrix. PMID:22851224

  12. Iron Amendment and Fenton Oxidation of MTBE-Spent Granular Activated Carbon

    EPA Science Inventory

    Fenton-driven regeneration of Methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC) involves Fe amendment to the GAC to catalyze H2O2 reactions and to enhance the rate of MTBE oxidation and GAC regeneration. Four forms of iron (ferric sulfate, ferric chloride, fer...

  13. Application of Electro-Fenton Technology to Remediation of Polluted Effluents by Self-Sustaining Process

    PubMed Central

    Fernández de Dios, Maria Ángeles; Iglesias, Olaia; Pazos, Marta; Sanromán, Maria Ángeles

    2014-01-01

    The applicability of electro-Fenton technology to remediation of wastewater contaminated by several organic pollutants such as dyes and polycyclic aromatic hydrocarbons has been evaluated using iron-enriched zeolite as heterogeneous catalyst. The electro-Fenton technology is an advanced oxidation process that is efficient for the degradation of organic pollutants, but it suffers from the high operating costs due to the need for power investment. For this reason, in this study microbial fuel cells (MFCs) were designed in order to supply electricity to electro-Fenton processes and to achieve high treatment efficiency at low cost. Initially, the effect of key parameters on the MFC power generation was evaluated. Afterwards, the degradation of Reactive Black 5 dye and phenanthrene was evaluated in an electro-Fenton reactor, containing iron-enriched zeolite as catalyst, using the electricity supplied by the MFC. Near complete dye decolourization and 78% of phenanthrene degradation were reached after 90 min and 30 h, respectively. Furthermore, preliminary reusability tests of the developed catalyst showed high degradation levels for successive cycles. The results permit concluding that the integrated system is adequate to achieve high treatment efficiency with low electrical consumption. PMID:24723828

  14. Effects of inorganic anions on carbon isotope fractionation during Fenton-like degradation of trichloroethene.

    PubMed

    Liu, Yunde; Zhou, Aiguo; Gan, Yiqun; Li, Xiaoqian

    2016-05-01

    Understanding the magnitude and variability in isotope fractionation with respect to specific processes is crucial to the application of stable isotopic analysis as a tool to infer and quantify transformation processes. The variability of carbon isotope fractionation during Fenton-like degradation of trichloroethene (TCE) in the presence of different inorganic ions (nitrate, sulfate, and chloride), was investigated to evaluate the potential effects of inorganic anions on carbon isotope enrichment factor (ε value). A comparison of ε values obtained in deionized water, nitrate solution, and sulfate solution demonstrated that the ε values were identical and not affected by the presence of nitrate and sulfate. In the presence of chloride, however, the ε values (ranging from -6.3±0.8 to 10±1.3‰) were variable and depended on the chloride concentration, indicating that chloride could significantly affect carbon isotope fractionation during Fenton-like degradation of TCE. Thus, caution should be exercised in selecting appropriate ε values for the field application of stable isotope analysis, as various chloride concentrations may be present due to naturally present or introduced with pH adjustment and iron salts during Fenton-like remediation. Furthermore, the effects of chloride on carbon isotope fractionation may be able to provide new insights about reaction mechanisms of Fenton-like processes. PMID:26835895

  15. Treatment of Actual Chemical Wastewater by a Heterogeneous Fenton Process Using Natural Pyrite

    PubMed Central

    Sun, Liang; Li, Yan; Li, Aimin

    2015-01-01

    Wastewater from chemical plants has remarkable antibiotic effects on the microorganisms in traditional biological treatment processes. An enhanced Fenton system catalyzed by natural pyrite was developed to degrade this kind of wastewater. Approximately 30% chemical oxygen demand (COD) was removed within 120 min when 50 mmol/L H2O2 and 10 g/L natural pyrite were used at initial pH from 1.8 to 7. A BOD5/COD enhancement efficiency of 210% and an acute biotoxicity removal efficiency of 84% were achieved. The COD removal efficiency was less sensitive to initial pH than was the classic Fenton process. Excessive amounts of pyrite and H2O2 did not negatively affect the pyrite Fenton system. The amount of aniline generated indicated that nitrobenzene reduction by pyrite was promoted using a low initial concentration of H2O2 (<5 mmol/L). Fluorescence excitation emission matrix analyses illustrated that H2O2 facilitated the reduction by natural pyrite of organic molecules containing an electron-withdrawing group to electron-donating group. Thus, the Fenton-like process catalyzed by pyrite can remediate wastewater containing organic pollutants under mild reaction conditions and provide an alternative environmentally friendly method by which to reuse natural pyrite. PMID:26516893

  16. Technical and economic feasibility of polyester dyeing wastewater treatment by coagulation/flocculation and Fenton's oxidation.

    PubMed

    Rodrigues, Carmen S D; Boaventura, Rui A R; Madeira, Luis M

    2014-01-01

    This study aims to investigate the efficiency of individual and integrated processes applied to organic matter abatement and biodegradability improvement of a polyester dyeing wastewater, namely coagulation/flocculation combined with Fenton's reagent (Approach 1), Fenton oxidation alone (Approach 2) and its integration with coagulation/flocculation (Approach 3). The effects of Fe2+ dose, initial concentration of the oxidant (H202) and temperature during Fenton's oxidation were evaluated in Approaches 1 and 2, whereas in Approach 3 the influence ofpH and flocculant dose was also assessed, during the coagulation/flocculation stage. Toxicity and biodegradability of the final effluent were also evaluated. After oxidation, a slight increase in the specific oxygen uptake rate of the effluent was observed (from 27.0 up to 28.5-30.0mg O2/(gVSSh)) and the inhibition to Vibrio fischeri was eliminated. An effluent that complies with discharge standards was obtained in all cases; however, Approach 3 revealed to be a promising solution for treating this effluent as it leads to smaller operating costs. Therefore, the use of dissolved iron resulting from Fenton's oxidation as coagulant in the second stage was shown to be an innovative, efficient and economically attractive strategy for treating these effluents.

  17. Using Fenton Oxidation to Simultaneously Remove Different Estrogens from Cow Manure

    PubMed Central

    Sun, Minxia; Xu, Defu; Ji, Yuefei; Liu, Juan; Ling, Wanting; Li, Shunyao; Chen, Mindong

    2016-01-01

    The presence of estrogens in livestock excrement has raised concerns about their potential negative influence on animals and the overall food cycle. This is the first investigation to simultaneously remove estrogens, including estriol (E3), bisphenol A (BPA), diethylstilbestrol (DES), estradiol (E2), and ethinyl estradiol (EE2), from cow manure using a Fenton oxidation technique. Based on the residual concentrations and removal efficiency of estrogens, the Fenton oxidation reaction conditions were optimized as follows: a H2O2 dosage of 2.56 mmol/g, a Fe(II) to H2O2 molar ratio of 0.125 M/M, a solid to water mass ratio of 2 g/mL, an initial pH of 3, and a reaction time of 24 h. Under these conditions, the simultaneous removal efficiencies of E3, BPA, DES, E2, and EE2, with initial concentrations in cow manure of 97.40, 96.54, 100.22, 95.01, and 72.49 mg/kg, were 84.9%, 99.5%, 99.1%, 97.8%, and 84.5%, respectively. We clarified the possible Fenton oxidation reaction mechanisms that governed the degradation of estrogens. We concluded that Fenton oxidation technique could be effective for efficient removal of estrogens in livestock excrement. Results are of great importance for cow manure reuse in agricultural management, and can be used to reduce the threat of environmental estrogens to human health and ecological safety. PMID:27649223

  18. CHEMICAL DESTRUCTION OF MTBE USING FENTON'S REAGENT: EFFECT OF FERROUS IRON/HYDROGEN PEROXIDE RATIO

    EPA Science Inventory

    In previous laboratory experiments Fenton's Reagent (FR) was successfully used as the source of hydroxyl radicals (OH*) for chemical treatment of low concentrations of methyl tert-butyl ether (MTBE) in water. Although under certain conditions MTBE degradation levels as high as 99...

  19. Ultrasound enhancement of near-neutral photo-Fenton for effective E. coli inactivation in wastewater.

    PubMed

    Giannakis, Stefanos; Papoutsakis, Stefanos; Darakas, Efthymios; Escalas-Cañellas, Antoni; Pétrier, Christian; Pulgarin, César

    2015-01-01

    In this study, we attempt for the first time to couple sonication and photo-Fenton for bacterial inactivation of secondary treated effluent. Synthetic wastewater was subjected to sequential high-frequency/low power sonication, followed by mild photo-Fenton treatment, under a solar simulator. It was followed by the assessment of the contribution of each component of the process (Fenton, US, hv) towards the removal rate and the long-term survival; sunlight greatly improved the treatment efficiency, with the coupled process being the only one to yield total inactivation within the 4-h period of treatment. The short-term beneficial disinfecting action of US and its detrimental effect on bacterial survival in long term, as well as the impact of light addition were also revealed. Finally, an investigation on the operational parameters of the process was performed, to investigate possible improvement and/or limitations of the coupled treatment; 3 levels of each parameter involved (hydraulic, environmental, US and Fenton) were tested. Only H2O2 increased improved the process significantly, but the action mode of the joint process indicated potential cost-effective solutions towards the implementation of this method.

  20. Iron-loaded mangosteen as a heterogeneous Fenton catalyst for the treatment of landfill leachate.

    PubMed

    Laiju, A R; Sivasankar, T; Nidheesh, P V

    2014-09-01

    Iron-loaded mangosteen shell powder (Fe-MSP) was found as an effective heterogeneous Fenton catalyst for the treatment of stabilized landfill leachate. Sonolytically produced catalyst has higher efficiency than other catalysts. At the optimal conditions (pH 3, catalyst concentration of 1,750 mg/L and hydrogen peroxide concentration of 0.26 M), 81 % of the chemical oxygen demand (COD) was removed effectively from the landfill leachate. But, the efficiency of Fe-MSP was reduced in the first recycling due to the poisoning of active sites. A metal leaching study indicated that the degradation of the pollutant is mainly due to solid Fe ions present in Fe-MSP rather than the leached ferrous and ferric ions. Hydroxyl radical production in the system was confirmed by the Fenton oxidation of benzoic acid. Compared to the homogeneous Fenton process, the heterogeneous Fenton process using Fe-MSP had higher COD removal efficiency, indicating the practical applicability of the prepared catalyst. PMID:24798918

  1. Fenton-like Degradation of MTBE: Effects of Iron Counter Anion and Radical Scavengers

    EPA Science Inventory

    Fenton-driven oxidation of Methyl tert-butyl ether (MTBE) (0.11-0.16 mM) in batch reactors containing ferric iron (5 mM), hydrogen peroxide (H2O2) (6 mM) (pH=3) was performed to investigate MTBE transformation mechanisms. Independent variables included the form of iron (Fe) (Fe2(...

  2. Study of solar photo-Fenton system applied to removal of phenol from water.

    PubMed

    Freire, Layla F A; da Fonseca, Fabiana Valéria; Yokoyama, Lidia; Teixeira, Luiz Alberto Cesar

    2014-01-01

    This study evaluated the use of a Fenton's reaction in a falling film solar reactor (FFR), as a possible advanced oxidation process for the mineralization of the organic compound phenol in water. Preliminary tests were carried out to evaluate phenol degradation by photolysis and to select the optimal residence time in which to carry out the process using a solar photo-Fenton system. The variables studied were the initial phenol concentration (100 to 300 mg L(-1)), the [Phenol]:[H2O2] mass ratio (1.0 to 2.0) and the [H2O2]/[Fe2+] molar ratio (5 to 10). Phenol degradation of 99% and chemical oxygen demand (COD) reduction of 97% were obtained under the following reaction conditions: phenol concentration=200 mg L(-1), mass ratio [Phenol]:[H2O2]=1.5 and molar ratio [H2O2]/[Fe2+]=7.5. Overall mineralization was achieved using the solar photo-Fenton process to destroy phenol and COD. The solar photo-Fenton process using a FFR appears to be a viable method for removing phenols in wastewaters on an industrial scale.

  3. Application of electro-Fenton technology to remediation of polluted effluents by self-sustaining process.

    PubMed

    Fernández de Dios, Maria Ángeles; Iglesias, Olaia; Pazos, Marta; Sanromán, Maria Ángeles

    2014-01-01

    The applicability of electro-Fenton technology to remediation of wastewater contaminated by several organic pollutants such as dyes and polycyclic aromatic hydrocarbons has been evaluated using iron-enriched zeolite as heterogeneous catalyst. The electro-Fenton technology is an advanced oxidation process that is efficient for the degradation of organic pollutants, but it suffers from the high operating costs due to the need for power investment. For this reason, in this study microbial fuel cells (MFCs) were designed in order to supply electricity to electro-Fenton processes and to achieve high treatment efficiency at low cost. Initially, the effect of key parameters on the MFC power generation was evaluated. Afterwards, the degradation of Reactive Black 5 dye and phenanthrene was evaluated in an electro-Fenton reactor, containing iron-enriched zeolite as catalyst, using the electricity supplied by the MFC. Near complete dye decolourization and 78% of phenanthrene degradation were reached after 90 min and 30 h, respectively. Furthermore, preliminary reusability tests of the developed catalyst showed high degradation levels for successive cycles. The results permit concluding that the integrated system is adequate to achieve high treatment efficiency with low electrical consumption.

  4. Decolourisation of dyes under electro-Fenton process using Fe alginate gel beads.

    PubMed

    Rosales, E; Iglesias, O; Pazos, M; Sanromán, M A

    2012-04-30

    This study focuses on the application of electro-Fenton technique by use of catalytic activity of Fe alginate gel beads for the remediation of wastewater contaminated with synthetic dyes. The Fe alginate gel beads were evaluated for decolourisation of two typical dyes, Lissamine Green B and Azure B under electro-Fenton process. After characterization of Fe alginate gel beads, the pH effect on the process with Fe alginate beads and a comparative study of the electro-Fenton process with free Fe and Fe alginate bead was done. The results showed that the use of Fe alginate beads increases the efficiency of the process; moreover the developed particles show a physical integrity in a wide range of pH (2-8). Around 98-100% of dye decolourisation was obtained for both dyes by electro-Fenton process in successive batches. Therefore, the process was performed with Fe alginate beads in a bubble continuous reactor. High color removal (87-98%) was attained for both dyes operating at a residence time of 30 min, without operational problems and maintaining particle shapes throughout the oxidation process. Consequently, the stable performance of Fe alginate beads opens promising perspectives for fast and economical treatment of wastewater polluted by dyes or similar organic contaminants.

  5. Electro-Fenton decolourisation of dyes in an airlift continuous reactor using iron alginate beads.

    PubMed

    Iglesias, O; Rosales, E; Pazos, M; Sanromán, M A

    2013-04-01

    In this study, electro-Fenton dye degradation was performed in an airlift continuous reactor configuration by harnessing the catalytic activity of Fe alginate gel beads. Electro-Fenton experiments were carried out in an airlift reactor with a working volume of 1.5 L, air flow of 1.5 L/min and 115 g of Fe alginate gel beads. An electric field was applied by two graphite bars connected to a direct current power supply with a constant potential drop. In this study, Lissamine Green B and Reactive Black 5 were selected as model dyes. Fe alginate gel beads can be used as an effective heterogeneous catalyst for the degradation of organic dyes in the electro-Fenton process, as they are more efficient than the conventional electrochemical techniques. At optimal working conditions (3 V and pH 2), the continuous process was performed. For both dyes, the degree of decolourisation increases when the residence time augments. Taking into account hydrodynamic and kinetic behaviour, a model to describe the reactor profile was obtained, and the standard deviation between experimental and theoretical data was lower than 6%. The results indicate the suitability of the electro-Fenton technique to oxidise polluted effluents in the presence of Fe alginate gel beads. Moreover, the operation is possible in a continuous airlift reactor, due to the entrapment of iron in the alginate matrix.

  6. Treatment of Actual Chemical Wastewater by a Heterogeneous Fenton Process Using Natural Pyrite.

    PubMed

    Sun, Liang; Li, Yan; Li, Aimin

    2015-11-01

    Wastewater from chemical plants has remarkable antibiotic effects on the microorganisms in traditional biological treatment processes. An enhanced Fenton system catalyzed by natural pyrite was developed to degrade this kind of wastewater. Approximately 30% chemical oxygen demand (COD) was removed within 120 min when 50 mmol/L H₂O₂ and 10 g/L natural pyrite were used at initial pH from 1.8 to 7. A BOD₅/COD enhancement efficiency of 210% and an acute biotoxicity removal efficiency of 84% were achieved. The COD removal efficiency was less sensitive to initial pH than was the classic Fenton process. Excessive amounts of pyrite and H₂O₂ did not negatively affect the pyrite Fenton system. The amount of aniline generated indicated that nitrobenzene reduction by pyrite was promoted using a low initial concentration of H₂O₂ (<5 mmol/L). Fluorescence excitation emission matrix analyses illustrated that H₂O₂ facilitated the reduction by natural pyrite of organic molecules containing an electron-withdrawing group to electron-donating group. Thus, the Fenton-like process catalyzed by pyrite can remediate wastewater containing organic pollutants under mild reaction conditions and provide an alternative environmentally friendly method by which to reuse natural pyrite. PMID:26516893

  7. Enhanced Fenton degradation of hydrophobic organics by simultaneous iron and pollutant complexation with cyclodextrins.

    PubMed

    Lindsey, Michele E; Xu, Guoxiang; Lu, Jia; Tarr, Matthew A

    2003-05-20

    The effectiveness and selectivity of Fenton degradation of hydrophobic organic compounds (HOCs) can be improved by simultaneous complexation of Fe(2+) and the organic compound with a cyclodextrin or derivatized cyclodextrin. Such selective complexation of a target substrate and a catalytic metal is a crude mimic of enzyme systems. Both beta-cyclodextrin and carboxymethyl-beta-cyclodextrin (CMCD) were able to simultaneously complex Fe(2+) and an aromatic hydrocarbon, such as phenol, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls (PCBs). Degradation of compounds included in cyclodextrins was unaffected by hydroxyl radical scavengers, indicating that the radical was formed at the ternary complex (HOC-cyclodextrin-iron) and in close proximity to the included molecule. Without cyclodextrins, humic acid (HA) decreased degradation efficiency. However, in the presence of CMCD, HA did not inhibit degradation of the target compound. CMCD is capable of removing HOCs from HA binding sites while at the same time complexing Fe(2+). PCBs sorbed to glass were resistant to Fenton degradation, but were significantly degraded using a cyclodextrin modified Fenton system. In all of these systems, the ternary HOC-cyclodextrin-iron complexes effectively direct hydroxyl radical reaction toward the HOC, increasing the efficiency of Fenton degradation. One potential application of such targeted degradation systems is the in situ remediation of hydrophobic organic pollutants in contaminated soil and groundwater or in industrial waste streams.

  8. Combined fenton oxidation and biological activated carbon process for recycling of coking plant effluent.

    PubMed

    Jiang, Wen-xin; Zhang, Wei; Li, Bing-jing; Duan, Jun; Lv, Yan; Liu, Wan-dong; Ying, Wei-chi

    2011-05-15

    Fenton oxidation and coagulation-flocculation-sedimentation (CFS) were both effective in removing many organic constituents of the biotreated coking plant effluent before the final treatment in an activated carbon adsorber. Fenton oxidation broke down most persistent organic pollutants and complex cyanides present in the feed stream and caused the eventual biodegradation of the organic residues in the adsorber. The results of Fenton oxidation followed by adsorption and biodegradation in two biological activated carbon (BAC) adsorbers show that the combined treatment consistently produced a high quality final effluent of <50mg/L in COD(Cr) and <0.5mg/L in total cyanide during the 70-d study without replacing any activated carbon. The BAC function of the adsorber substantially reduced the need for replacing activated carbon making the combined Fenton oxidation-BAC treatment process a cost effective treatment process to recycle the final effluent for many beneficial reuses while meeting the much more stringent discharge limits of the future.

  9. A dosimetry method in the transverse plane of HDR Ir-192 brachytherapy source using gafchromic EBT2 film.

    PubMed

    Uniyal, S C; Sharma, S D; Naithani, U C

    2012-04-01

    Radiochromic film dosimetry is increasingly used in brachytherapy applications for its higher resolution ability as compared to other experimental methods. The present study was aimed to assess the accuracy and suitability of use of the improved radiochromic film model, Gafchromic EBT2, to evaluate the dose distribution in the transverse plane of microselectron HDR (192)Ir source. A specially designed and locally fabricated Polymethyl methacrylate (PMMA) phantom was used in this work for the experimental measurement of dose distribution around the source in its transverse plane. The AAPM TG-43U1 recommended radial dose function, g (r), and dose rate constant, Λ, for the source were measured using Gafchromic EBT2 film and thermoluminescent dosimeters (TLD). The EBT2 film measured dosimetric quantities were validated against their values obtained from the TLD measurements and previously published values for the same source available in literature. The dose rate constant and radial dose function for microselectron HDR (192)Ir source obtained from Gafchromic EBT2 film measurements are in agreement with their TLD measured results within 3.9% and 2.8% respectively. They also agree within the accepted range of uncertainty with their experimental and Monte Carlo calculated results reported in literature. This work demonstrates the suitability of using Gafchromic EBT2 film dosimetry in characterization of dose distribution in the transverse plane of HDR Ir-192 source. This is a more efficient method than TLD dosimetry at discrete and distant positions. Relative to TLD dosimetry, it is found to be better reproducible, easy to use and a less expensive method of dosimetry.

  10. SU-E-T-517: Analytic Formalism to Compute in Real Time Dose Distributions Delivered by HDR Units

    SciTech Connect

    Pokhrel, S; Loyalka, S; Palaniswaamy, G; Rangaraj, D; Izaguirre, E

    2014-06-01

    Purpose: Develop an analytical algorithm to compute the dose delivered by Ir-192 dwell positions with high accuracy using the 3-dimensional (3D) dose distribution of an HDR source. Using our analytical function, the dose delivered by an HDR unit as treatment progresses can be determined using the actual delivered temporal and positional data of each individual dwell. Consequently, true delivered dose can be computed when each catheter becomes active. We hypothesize that the knowledge of such analytical formulation will allow developing HDR systems with a real time treatment evaluation tool to avoid mistreatments. Methods: In our analytic formulation, the dose is computed by using the full anisotropic function data of the TG 43 formalism with 3D ellipsoidal function. The discrepancy between the planned dose and the delivered dose is computed using an analytic perturbation method over the initial dose distribution. This methodology speeds up the computation because only changes in dose discrepancies originated by spatial and temporal deviations are computed. A dose difference map at the point of interest is obtained from these functions and this difference can be shown during treatment in real time to examine the treatment accuracy. Results: We determine the analytical solution and a perturbation function for the 3 translational 3 rotational, and 1D temporal errors in source distributions. The analytic formulation is a sequence of simple equations that can be processed in any modern computer in few seconds. Because computations are based in an analytical solution, small deviations of the dose when sub-millimeter positional changes occur can be detected. Conclusions: We formulated an analytical method to compute 4D dose distributions and dose differences based on an analytical solution and perturbations to the original dose. This method is highly accurate and can be.

  11. SU-C-16A-05: OAR Dose Tolerance Recommendations for Prostate and Cervical HDR Brachytherapy: Dose Versus Volume Metrics

    SciTech Connect

    Geneser, S; Cunha, J; Pouliot, J; Hsu, I

    2014-06-15

    Purpose: HDR brachytherapy consensus dose tolerance recommendations for organs at risk (OARs) remain widely debated. Prospective trials reporting metrics must be sufficiently data-dense to assess adverse affects and identify optimally predictive tolerances. We explore the tradeoffs between reporting dose-metrics versus volume-metrics and the potential impact on trial outcome analysis and tolerance recommendations. Methods: We analyzed 26 prostate patients receiving 15 Gy HDR single-fraction brachytherapy boost to 45 Gy external beam radiation therapy and 28 cervical patients receiving 28 Gy HDR brachytherapy monotherapy in 4 fractions using 2 implants. For each OAR structure, a robust linear regression fit was performed for the dose-metrics as a function of the volume-metrics. The plan quality information provided by recommended dose-metric and volume-metric values were compared. Results: For prostate rectal dose, D2cc and V75 lie close to the regression line, indicating they are similarly informative. Two outliers for prostate urethral dose are substantially different from the remaining cohort in terms of D0.1cc and V75, but not D1cc, suggesting the choice of reporting dose metric is essential. For prostate bladder and cervical bladder, rectum, and bowel, dose outliers are more apparent via V75 than recommended dose-metrics. This suggests that for prostate bladder dose and all cervical OAR doses, the recommended volume-metrics may be better predictors of clinical outcome than dose-metrics. Conclusion: For plan acceptance criteria, dose and volume-metrics are reciprocally equivalent. However, reporting dosemetrics or volume-metrics alone provides substantially different information. Our results suggest that volume-metrics may be more sensitive to differences in planned dose, and if one metric must be chosen, volumemetrics are preferable. However, reporting discrete DVH points severely limits the ability to identify planning tolerances most predictive of adverse

  12. Determination of contributions of scatter and distance error to the source strength of 192Ir HDR brachytherapy source

    NASA Astrophysics Data System (ADS)

    Bondel, Shwetha; Ravikumar, Manickam

    2016-09-01

    High dose rate (HDR) brachytherapy commonly employs a 192Ir encapsulated source to deliver high dose to the malignant tissues. Calibrations of brachytherapy sources are performed by the manufacturer using a well-type chamber or by in-air measurement using a cylindrical ionization chamber. Calibration using the latter involves measurements to be carried out at several distances and room scatter can also be determined. The aim of the present study is to estimate the scatter contribution from the walls, floor and various materials in the room in order to determine the reference air kerma rate of an 192Ir HDR brachytherapy source by in-air measurements and also to evaluate the error in the setup distance between the source centre and chamber centre. Air kerma measurements were performed at multiple distances from 10 cm to 40 cm between the source and chamber. The room scatter correction factor was determined using the iterative technique. The distance error of -0.094 cm and -0.112 cm was observed for chamber with and without buildup cap respectively. The scatter component ranges from 0.3% to 5.4% for the chamber with buildup cap and 0.3% to 4.6% without buildup cap for distances between 10 to 40 cm respectively. Since the average of the results at multiple distances is considered to obtain the actual air kerma rate of the HDR source, the seven distance method and iterative technique are very effective in determining the scatter contribution and the error in the distance measurements.

  13. Evaluation of Scatter Contribution and Distance Error by Iterative Methods for Strength Determination of HDR {sup 192}Ir Brachytherapy Source

    SciTech Connect

    Kumar, Sudhir; Srinivasan, Panchapakesan; Sharma, Sunil D.; Subbaiah, Kamatam V.; Mayya, Yelia S.

    2010-10-01

    High-dose rate (HDR) {sup 192}Ir brachytherapy sources are commonly used for management of malignancies by brachytherapy applications. Measurement of source strength at the hospital is an important dosimetry requirement. The use of 0.6-cm{sup 3} cylindrical ionization chamber is one of the methods of measuring the source strength at the hospitals because this chamber is readily available for beam calibration and dosimetry. While using the cylindrical chamber for this purpose, it is also required to determine the positioning error of the ionization chamber, with respect to the source, commonly called a distance error (c). The contribution of scatter radiation (M{sub s}) from floor, walls, ceiling, and other materials available in the treatment room also need to be determined accurately so that appropriate correction can be applied while calculating the source strength from the meter reading. Iterative methods of Newton-Raphson and least-squares were used in this work to determine scatter contribution in the experimentally observed meter reading (pC/s) of a cylindrical ionization chamber. Monte Carlo simulation was also used to cross verify the results of the least-squares method. The experimentally observed, least-squares calculated and Monte Carlo estimated values of meter readings from HDR {sup 192}Ir brachytherapy source were in good agreement. Considering procedural simplicity, the method of least-squares is recommended for use at the hospitals to estimate values of f (constant of proportionality), c, and M{sub s} required to determine the strength of HDR {sup 192}Ir brachytherapy sources.

  14. Estimation of distance error by fuzzy set theory required for strength determination of HDR (192)Ir brachytherapy sources.

    PubMed

    Kumar, Sudhir; Datta, D; Sharma, S D; Chourasiya, G; Babu, D A R; Sharma, D N

    2014-04-01

    Verification of the strength of high dose rate (HDR) (192)Ir brachytherapy sources on receipt from the vendor is an important component of institutional quality assurance program. Either reference air-kerma rate (RAKR) or air-kerma strength (AKS) is the recommended quantity to specify the strength of gamma-emitting brachytherapy sources. The use of Farmer-type cylindrical ionization chamber of sensitive volume 0.6 cm(3) is one of the recommended methods for measuring RAKR of HDR (192)Ir brachytherapy sources. While using the cylindrical chamber method, it is required to determine the positioning error of the ionization chamber with respect to the source which is called the distance error. An attempt has been made to apply the fuzzy set theory to estimate the subjective uncertainty associated with the distance error. A simplified approach of applying this fuzzy set theory has been proposed in the quantification of uncertainty associated with the distance error. In order to express the uncertainty in the framework of fuzzy sets, the uncertainty index was estimated and was found to be within 2.5%, which further indicates that the possibility of error in measuring such distance may be of this order. It is observed that the relative distance li estimated by analytical method and fuzzy set theoretic approach are consistent with each other. The crisp values of li estimated using analytical method lie within the bounds computed using fuzzy set theory. This indicates that li values estimated using analytical methods are within 2.5% uncertainty. This value of uncertainty in distance measurement should be incorporated in the uncertainty budget, while estimating the expanded uncertainty in HDR (192)Ir source strength measurement.

  15. HDR {sup 192}Ir source speed measurements using a high speed video camera

    SciTech Connect

    Fonseca, Gabriel P.; Rubo, Rodrigo A.; Sales, Camila P. de; Verhaegen, Frank

    2015-01-15

    Purpose: The dose delivered with a HDR {sup 192}Ir afterloader can be separated into a dwell component, and a transit component resulting from the source movement. The transit component is directly dependent on the source speed profile and it is the goal of this study to measure accurate source speed profiles. Methods: A high speed video camera was used to record the movement of a {sup 192}Ir source (Nucletron, an Elekta company, Stockholm, Sweden) for interdwell distances of 0.25–5 cm with dwell times of 0.1, 1, and 2 s. Transit dose distributions were calculated using a Monte Carlo code simulating the source movement. Results: The source stops at each dwell position oscillating around the desired position for a duration up to (0.026 ± 0.005) s. The source speed profile shows variations between 0 and 81 cm/s with average speed of ∼33 cm/s for most of the interdwell distances. The source stops for up to (0.005 ± 0.001) s at nonprogrammed positions in between two programmed dwell positions. The dwell time correction applied by the manufacturer compensates the transit dose between the dwell positions leading to a maximum overdose of 41 mGy for the considered cases and assuming an air-kerma strength of 48 000 U. The transit dose component is not uniformly distributed leading to over and underdoses, which is within 1.4% for commonly prescribed doses (3–10 Gy). Conclusions: The source maintains its speed even for the short interdwell distances. Dose variations due to the transit dose component are much lower than the prescribed treatment doses for brachytherapy, although transit dose component should be evaluated individually for clinical cases.

  16. Mixed integer programming improves comprehensibility and plan quality in inverse optimization of prostate HDR brachytherapy.

    PubMed

    Gorissen, Bram L; den Hertog, Dick; Hoffmann, Aswin L

    2013-02-21

    Current inverse treatment planning methods that optimize both catheter positions and dwell times in prostate HDR brachytherapy use surrogate linear or quadratic objective functions that have no direct interpretation in terms of dose-volume histogram (DVH) criteria, do not result in an optimum or have long solution times. We decrease the solution time of the existing linear and quadratic dose-based programming models (LP and QP, respectively) to allow optimizing over potential catheter positions using mixed integer programming. An additional average speed-up of 75% can be obtained by stopping the solver at an early stage, without deterioration of the plan quality. For a fixed catheter configuration, the dwell time optimization model LP solves to optimality in less than 15 s, which confirms earlier results. We propose an iterative procedure for QP that allows us to prescribe the target dose as an interval, while retaining independence between the solution time and the number of dose calculation points. This iterative procedure is comparable in speed to the LP model and produces better plans than the non-iterative QP. We formulate a new dose-volume-based model that maximizes V(100%) while satisfying pre-set DVH criteria. This model optimizes both catheter positions and dwell times within a few minutes depending on prostate volume and number of catheters, optimizes dwell times within 35 s and gives better DVH statistics than dose-based models. The solutions suggest that the correlation between the objective value and the clinical plan quality is weak in the existing dose-based models. PMID:23363622

  17. SU-E-T-560: Commissioning An HDR Freiburg Flap Applicator for Skin Lesion Treatment

    SciTech Connect

    Dou, K; Li, B; Lerma, F; Aroumougame, V; Sarfaraz, M; Laser, B; Jacobs, M

    2014-06-01

    Purpose: Flexible Freiburg flap used with high dose rate afterloaders is easy to cut into any size for any body site and to dwell with a precise source position, conforms to curved skin surface and then to the planned target. However, unlike intracavity or interstitial situations, incomplete scatter environment due to flap applicators exposed to air might lead to dose difference between the delivered and planned. This research is focused on the dose deviation of incomplete scatter versus full scatter. Methods: A 12x12 cm of Freiburg flap applicator was used for the validation. A Nucletron Oncentra Brachy Ver. 4.3 treatment planning system (TPS) was used for treatment planning. However, no heterogeneity correction incorporated into the brachytherap TPS needs to be considered. A Philips Brilliance CT Big Bore was employed for CT scan. Radiation was delivered using a Nucletron HDR remote afterloader system. A 10cm bolus was used to cover the flap for obtaining a full scatter. An OSL, ion chamber, and Gafchromic EBT2 film were used for commissioning the flap applicator. Results: The applicator calibration at 5mm depth was performed using an OSL dosimeter. Applicator source dwelling positions with 1D and 2D array exposed to and recorded by Gafchromic EBT2 film showed an agreement within 1mm. 1D array of Freiburg flap exhibited 4.2% cooler in dose with incomplete scatter than full scatter. 2D array showed 7.1% lower in dose for incomplete scatter than full scatter. The deviation was found more than 10% beyond 8cm in depth. Conclusion: Significant dose deviation caused by the incomplete scatter environment was found to be 7.1% at 1cm depth. This deviation was increased with increasing depth. The inaccuracy resulted from the incomplete scatter can be fixed by either placing a bolus on the top of the flap or making the plan at least 7% hotter.

  18. Non-melanoma skin cancer treated with HDR Valencia applicator: clinical outcomes

    PubMed Central

    Tormo, Alejandro; Celada, Francisco; Rodriguez, Silvia; Botella, Rafael; Ballesta, Antonio; Kasper, Michael; Ouhib, Zoubir; Santos, Manuel

    2014-01-01

    Purpose Radiotherapy (RT) has played a significant role in treating non melanoma skin cancer (NMSC). High-dose-rate brachytherapy (HDR-BT) approaches have a paramount relevance due to their adaptability, patient protection, and variable dose fractionation schedules. Several innovative applicators have been introduced to the brachytherapy community. The Valencia applicator is a new superficial device that improves the dose distribution compared with the Leipzig applicator. The purpose of this work is to assess the tumor control, cosmesis, and toxicity in patients with NMSC treated with the Valencia applicator and a new regimen of hypofractionation. Material and methods From January 2008 to March 2010, 32 patients with 45 NMSC lesions were treated with the Valencia applicator in the Hospital La Fe. The gross tumor volume was visually assessed, but the tumor depth was evaluated using ultrasound imaging. All lesions for the selected cases were limited to 4 mm depth. The prescription dose was 42 Gy in 6 or 7 fractions (biologically effective dose [BED] ≈ 70 Gy), delivered twice a week. Results Ninety-eight percent of the lesions were locally controlled at 47 months from treatment. Ninety-three percent of patients were out at least 36 months from treatment. The treatment was well tolerated in all cases. The highest skin toxicity was grade 1 RTOG/EORTC, having resolved with topical treatment at 4 weeks in all but one case which required 2 months. There were no grade 2 or higher late adverse events. Conclusions In patients with superficial basal cell carcinoma lesions less than 25 mm in maximum diameter, HDRBT treatment with the Valencia applicator using a hypofractionated regimen provides excellent results, for both cosmetic and local control at a minimum of 3 years follow-up. Moreover, the shorter hypofractionated regimen facilitates compliance, which is very relevant for the elderly patients in our series. Valencia applicators offer a simple, safe, quick, and

  19. Kinetics and reaction pathways of formaldehyde degradation using the UV-fenton method.

    PubMed

    Liu, Xiangxuan; Liang, Jiantao; Wang, Xuanjun

    2011-05-01

    This study was based on the purpose of investigating the reaction rules of formaldehyde (HCHO) as an intermediate product in the degradation of many other organic wastewaters. The process conditions of UV-Fenton method for the degradation of the low concentrations of HCHO were studied in a batch photochemical reactor. The results showed that, when the original HCHO concentration was 30 mg/L, at an operating temperature of 23 degrees C, pH = 3, an H202 dosage of 68 mg/L, and an H2O2-to-Fe2+ mole ratio (H2O2:Fe2+) of 5, 91.89% of the HCHO was removed after 30 minutes. The degradation of HCHO in the UV-Fenton system was basically in accordance with the exponential decay. The kinetic study results showed that the reaction orders of HCHO, Fe2+, and H2O2 in the system were 1.054, 0.510, and 0.728, respectively, and the activation energy (Ea) was 9.85 kJ/mol. The comparison of UV/H2O2, Fenton, and UV-Fenton systems for the degradation of HCHO, and the results of iron catalyst tests showed that the mechanism of UV-Fenton on the degradation of HCHO was through a synergistic effect of Fe2+ and UV light to catalyze the decomposition of H2O2. The introduction of UV irradiation to the Fenton system largely increased the degradation rate of HCHO, mainly as a result of the accelerating effect on the formation of the Fe2+/Fe3+ cycle. The reaction products were analyzed by gas chromatography-mass spectrometry and a chemical oxygen demand (COD) analyzer. The effluent gases also were analyzed by gas chromatography. Based on those results, the reaction pathways of HCHO in the UV-Fenton system were proposed. The qualitative and quantitative analysis of the reaction products and the COD showed that the main intermediate product of the reaction was formic acid, and the further oxidation of it was the rate-limiting step for the degradation of HCHO.

  20. New type of hill-top inflation

    NASA Astrophysics Data System (ADS)

    Barvinsky, A. O.; Kamenshchik, A. Yu.; Nesterov, D. V.

    2016-01-01

    We suggest a new type of hill-top inflation originating from the initial conditions in the form of the microcanonical density matrix for the cosmological model with a large number of quantum fields conformally coupled to gravity. Initial conditions for inflation are set up by cosmological instantons describing underbarrier oscillations in the vicinity of the inflaton potential maximum. These periodic oscillations of the inflaton field and cosmological scale factor are obtained within the approximation of two coupled oscillators subject to the slow roll regime in the Euclidean time. This regime is characterized by rapid oscillations of the scale factor on the background of a slowly varying inflaton, which guarantees smallness of slow roll parameters epsilon and η of the following inflation stage. A hill-like shape of the inflaton potential is shown to be generated by logarithmic loop corrections to the tree-level asymptotically shift-invariant potential in the non-minimal Higgs inflation model and R2-gravity. The solution to the problem of hierarchy between the Planckian scale and the inflation scale is discussed within the concept of conformal higher spin fields, which also suggests the mechanism bringing the model below the gravitational cutoff and, thus, protecting it from large graviton loop corrections.

  1. Spirit's Express Route to 'Columbia Hills'

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This map illustrates the Mars Exploration Rover Spirit's position as of sol 112 (April 26, 2004), near the crater called 'Missoula.' Like a train on a tight schedule, Spirit will make regular stops along the way to its ultimate destination, the 'Columbia Hills.' At each stop, or 'station,' the rover will briefly analyze the area's rocks and soils. Each tick mark on the rover's route represents one sol's worth of travel, or about 60 to 70 meters (200 to 230 feet). Rover planners estimate that Spirit will reach the hills around mid-June. Presently, the rover is stopped at a site called 'Plains Station.'

    The color thermal data show how well different surface features hold onto heat. Red indicates warmth; blue indicates coolness. Areas with higher temperatures are more likely to be rocky, as rocks absorb heat. Lower temperatures denote small particles and fewer rocks. During its traverse, Spirit will document the causes of these temperature variations.

    The map comprises data from the camera on NASA's Mars Global Surveyor orbiter and the thermal emission imaging system on NASA's Mars Odyssey orbiter.

  2. Spirit's Express Route to 'Columbia Hills'

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This map illustrates the Mars Exploration Rover Spirit's position as of sol 112 (April 26, 2004), near the crater called 'Missoula.' Like a train on a tight schedule, Spirit will make regular stops along the way to its ultimate destination, the 'Columbia Hills.' At each stop, or 'station,' the rover will briefly analyze the area's rocks and soils. Each tick mark on the rover's route represents one sol's worth of travel, or about 60 to 70 meters (200 to 230 feet). Rover planners estimate that Spirit will reach the hills around mid-June. Presently, the rover is stopped at a site called 'Plains Station.'

    The color thermal data show how well different surface features hold onto heat. Red indicates a higher thermal inertia associated with rocky terrain (cooler in the day, warmer at night); blue indicates a lower thermal inertia associated with smaller particles and fewer rocks (warmer at night, cooler in the day). During its traverse, Spirit will document the causes of these thermal variations.

    The map comprises data from the camera on NASA's Mars Global Surveyor orbiter and the thermal emission imaging system on NASA's Mars Odyssey orbiter.

  3. Hill crossing during preheating after hilltop inflation

    NASA Astrophysics Data System (ADS)

    Antusch, Stefan; Nolde, David; Orani, Stefano

    2015-06-01

    In ``hilltop inflation'', inflation takes place when the inflaton field slowly rolls from close to a maximum of its potential (i.e. the ``hilltop'') towards its minimum. When the inflaton potential is associated with a phase transition, possible topological defects produced during this phase transition, such as domain walls, are efficiently diluted during inflation. It is typically assumed that they also do not reform after inflation, i.e. that the inflaton field stays on its side of the ``hill'', finally performing damped oscillations around the minimum of the potential. In this paper we study the linear and the non-linear phases of preheating after hilltop inflation. We find that the fluctuations of the inflaton field during the tachyonic oscillation phase grow strong enough to allow the inflaton field to form regions in position space where it crosses ``over the top of the hill'' towards the ``wrong vacuum''. We investigate the formation and behaviour of these overshooting regions using lattice simulations: rather than durable domain walls, these regions form oscillon-like structures (i.e. localized bubbles that oscillate between the two vacua) which should be included in a careful study of preheating in hilltop inflation.

  4. New type of hill-top inflation

    SciTech Connect

    Barvinsky, A.O.; Nesterov, D.V.; Kamenshchik, A.Yu. E-mail: Alexander.Kamenshchik@bo.infn.it

    2016-01-01

    We suggest a new type of hill-top inflation originating from the initial conditions in the form of the microcanonical density matrix for the cosmological model with a large number of quantum fields conformally coupled to gravity. Initial conditions for inflation are set up by cosmological instantons describing underbarrier oscillations in the vicinity of the inflaton potential maximum. These periodic oscillations of the inflaton field and cosmological scale factor are obtained within the approximation of two coupled oscillators subject to the slow roll regime in the Euclidean time. This regime is characterized by rapid oscillations of the scale factor on the background of a slowly varying inflaton, which guarantees smallness of slow roll parameters ε and η of the following inflation stage. A hill-like shape of the inflaton potential is shown to be generated by logarithmic loop corrections to the tree-level asymptotically shift-invariant potential in the non-minimal Higgs inflation model and R{sup 2}-gravity. The solution to the problem of hierarchy between the Planckian scale and the inflation scale is discussed within the concept of conformal higher spin fields, which also suggests the mechanism bringing the model below the gravitational cutoff and, thus, protecting it from large graviton loop corrections.

  5. Neonatal diagnosis of a patient with hypoparathyroidism, sensorineural deafness and renal dysplasia (HDR) syndrome associated with cerebral infarction.

    PubMed

    Mejia, Juan Diego; Cervantes, Luisa; Puerta, Herminia; Bauer, Mislen; Diaz, Alejandro

    2014-09-01

    Hypoparathyroidism, sensorineural deafness and renal dysplasia syndrome (HDRS) is comprised of a triad of conditions. It is an autosomal dominant condition caused by mutations in the GATA3 gene, located at 10p15, a critical region in the development of the embryonic parathyroid glands, inner ear, and kidneys. Here we describe the case of a patient with all three components of HDR syndrome diagnosed in the neonatal period who presented with cerebral infarction, hypocalcemia, and renal anomalies. Upon chromosomal microarray he was found to have an interstitial deletion at 10p, which produced a partial deletion in the GATA3 gene.

  6. Direct measurement of instantaneous source speed for a HDR brachytherapy unit using an optical fiber based detector

    SciTech Connect

    Minamisawa, R. A.; Rubo, R. A.; Seraide, R. M.; Rocha, J. R. O.; Almeida, A.

    2010-10-15

    Purpose: Several attempts to determine the transit time of a high dose rate (HDR) brachytherapy unit have been reported in the literature with controversial results. The determination of the source speed is necessary to accurately calculate the transient dose in brachytherapy treatments. In these studies, only the average speed of the source was measured as a parameter for transit dose calculation, which does not account for the realistic movement of the source, and is therefore inaccurate for numerical simulations. The purpose of this work is to report the implementation and technical design of an optical fiber based detector to directly measure the instantaneous speed profile of a {sup 192}Ir source in a Nucletron HDR brachytherapy unit. Methods: To accomplish this task, we have developed a setup that uses the Cerenkov light induced in optical fibers as a detection signal for the radiation source moving inside the HDR catheter. As the {sup 192}Ir source travels between two optical fibers with known distance, the threshold of the induced signals are used to extract the transit time and thus the velocity. The high resolution of the detector enables the measurement of the transit time at short separation distance of the fibers, providing the instantaneous speed. Results: Accurate and high resolution speed profiles of the {sup 192}Ir radiation source traveling from the safe to the end of the catheter and between dwell positions are presented. The maximum and minimum velocities of the source were found to be 52.0{+-}1.0 and 17.3{+-}1.2 cm/s. The authors demonstrate that the radiation source follows a uniformly accelerated linear motion with acceleration of |a|=113 cm/s{sup 2}. In addition, the authors compare the average speed measured using the optical fiber detector to those obtained in the literature, showing deviation up to 265%. Conclusions: To the best of the authors' knowledge, the authors directly measured for the first time the instantaneous speed profile of

  7. [Study on apparent kinetics of photocatalytic oxidation degradation Rhodamine B by photo-Fenton reaction].

    PubMed

    Li, Hong; Zheng, Huai-Li; Li, Xiao-Hong; Xie, Li-Guo; Tang, Xue

    2008-11-01

    The Fenton process, mixed by hydrogen peroxide and iron salts with highly oxidative effect, is recognized as one of powerful advanced oxidation technologies available and can be used to destroy a variety of persistent organic pollutants. The oxidation power of Fenton reagent is due to the generation of hydroxyl radical (* OH) during the iron catalysed decomposition of hydrogen peroxide in acid medium. The hydroxyl radical with a high oxidation potential (2.8 eV) attacks and completely destroys the pollutants in Fenton process. The degradation of pollutants can be considerably improved by using sunlight radiation, which is due to the generation of additional hydroxyl radicals. This photo-Fenton process had been effectively used to degrade the pollutants. In this paper, the definite quantity of Fenton reagent was added in the definite concentration of Rhodamine B solution. The degradation reaction was carried out at pH 3.5 under natural sunlight. The factors influencing on photocatalytic oxidation degradation rate of Rhodamine B were studied following: the initial concentration of Rhodamine B, initial concentrateions of Fe2+ and H2O2. The orders of degradation reaction were obtained by solving exponential kinetics equations of curve fitting, thereby gaining the kinetic parameters and reaction dynamics equation of the reaction system. The research contents included mainly: the UV-Vis spectra of Rhodamine B solution, the concentration-absorbency work curve of Rhodamine B solution, the analysis of the reaction system at various initial Rhodamine B concentrations, the analysis of the reaction system at various initial Fe2+ concentrateions, the analysis of the reaction system at various initial H2O2 concentrations, and the calculation of the apparent kinetics parameters in reaction dynamics equation. The reaction dynamics equation from experiments was constructed: V = 5 x 10(-9) P1.28 F0.366 E0.920, and overall reaction order was 2.57.

  8. Mechanism of red mud combined with Fenton's reagent in sewage sludge conditioning.

    PubMed

    Zhang, Hao; Yang, Jiakuan; Yu, Wenbo; Luo, Sen; Peng, Li; Shen, Xingxing; Shi, Yafei; Zhang, Shinan; Song, Jian; Ye, Nan; Li, Ye; Yang, Changzhu; Liang, Sha

    2014-08-01

    Red mud was evaluated as an alternative skeleton builder combined with Fenton's reagent in sewage sludge conditioning. The results show that red mud combined with Fenton's reagent showed good conditioning capability with the pH of the filtrate close to neutrality, indicating that red mud acted as a neutralizer as well as a skeleton builder when jointly used with Fenton's reagent. Through response surface methodology (RSM), the optimal dosages of Fe(2+), H2O2 and red mud were proposed as 31.9, 33.7 and 275.1 mg/g DS (dry solids), respectively. The mechanism of the composite conditioner could be illuminated as follows: (1) extracellular polymeric substances (EPS), including loosely bound EPS and tightly bound EPS, were degraded into dissolved organics, e.g., proteins and polysaccharides; (2) bound water was released and converted into free water due to the degradation of EPS; and (3) morphology of the conditioned sludge exhibited a porous structure in contrast with the compact structure of raw sludge, and the addition of red mud formed new mineral phases and a rigid lattice structure in sludge, allowing the outflow of free water. Thus, sludge dewatering performance was effectively improved. The economic assessment for a wastewater treatment plant of 370,000 equivalent inhabitants confirms that using red mud conditioning, combined with Fenton's reagent, leads to a saving of approximately 411,000 USD/y or 50.8 USD/t DS comparing with using lime and ordinary Portland cement combined with Fenton's reagent, and approximately 612,000 USD/y or 75.5 USD/t DS comparing with the traditional treatment. PMID:24810740

  9. Treatment of sugarcane vinasse by combination of coagulation/flocculation and Fenton's oxidation.

    PubMed

    Guerreiro, Lígia F; Rodrigues, Carmen S D; Duda, Rose M; de Oliveira, Roberto A; Boaventura, Rui A R; Madeira, Luis M

    2016-10-01

    The efficiency of individual and integrated processes applied to organic matter reduction and biodegradability improvement of a biodigested sugarcane vinasse wastewater was assessed. Strategies considered were Fenton's oxidation (Strategy 1), coagulation/flocculation (Strategy 2) and the combination of both processes (coagulation/flocculation followed by Fenton's reaction) - Strategy 3. It was found that Fenton's oxidation per se allowed reducing the organic matter, increasing the wastewater biodegradability and a non-toxic effluent was generated; however the cost of treatment was very high (86.6 R$/m(3) - 21.2 €/m(3)). Under optimized conditions, coagulation/flocculation provided a slight increase in effluent's biodegradability, toxicity towards Vibrio fischeri was also eliminated and moderate removals of total organic carbon - TOC - (30.5%), biological oxygen demand - BOD5 - (27.9%) and chemical oxygen demand - COD - (43.6%) were achieved; however, the operating costs are much smaller. The use of dissolved iron resulting from coagulation/flocculation (270 mg/L) as catalyst in the second stage - Fenton's oxidation - was shown to be an innovative and economically attractive strategy. Under optimal conditions overall removals of 51.6% for TOC, 45.7% for BOD5 and 69.2% for COD were achieved, and a biodegradable (BOD5:COD ratio = 0.54) and non-toxic effluent was obtained. In order to increase the efficiency of the process but using less hydrogen peroxide, the Fenton's oxidation was performed by gradually adding the oxidant. This procedure allowed to obtain the highest organic matter removal efficiency (as compared with the addition of all hydrogen peroxide at the beginning of the reaction). This way it was possible to minimize the reagent consumption and, consequently, reduce the treatment cost.

  10. Treatment of sugarcane vinasse by combination of coagulation/flocculation and Fenton's oxidation.

    PubMed

    Guerreiro, Lígia F; Rodrigues, Carmen S D; Duda, Rose M; de Oliveira, Roberto A; Boaventura, Rui A R; Madeira, Luis M

    2016-10-01

    The efficiency of individual and integrated processes applied to organic matter reduction and biodegradability improvement of a biodigested sugarcane vinasse wastewater was assessed. Strategies considered were Fenton's oxidation (Strategy 1), coagulation/flocculation (Strategy 2) and the combination of both processes (coagulation/flocculation followed by Fenton's reaction) - Strategy 3. It was found that Fenton's oxidation per se allowed reducing the organic matter, increasing the wastewater biodegradability and a non-toxic effluent was generated; however the cost of treatment was very high (86.6 R$/m(3) - 21.2 €/m(3)). Under optimized conditions, coagulation/flocculation provided a slight increase in effluent's biodegradability, toxicity towards Vibrio fischeri was also eliminated and moderate removals of total organic carbon - TOC - (30.5%), biological oxygen demand - BOD5 - (27.9%) and chemical oxygen demand - COD - (43.6%) were achieved; however, the operating costs are much smaller. The use of dissolved iron resulting from coagulation/flocculation (270 mg/L) as catalyst in the second stage - Fenton's oxidation - was shown to be an innovative and economically attractive strategy. Under optimal conditions overall removals of 51.6% for TOC, 45.7% for BOD5 and 69.2% for COD were achieved, and a biodegradable (BOD5:COD ratio = 0.54) and non-toxic effluent was obtained. In order to increase the efficiency of the process but using less hydrogen peroxide, the Fenton's oxidation was performed by gradually adding the oxidant. This procedure allowed to obtain the highest organic matter removal efficiency (as compared with the addition of all hydrogen peroxide at the beginning of the reaction). This way it was possible to minimize the reagent consumption and, consequently, reduce the treatment cost. PMID:27353374

  11. Disinfection of wastewater effluents with the Fenton-like process induced by electromagnetic fields.

    PubMed

    Rodríguez-Chueca, J; Mediano, A; Ormad, M P; Mosteo, R; Ovelleiro, J L

    2014-09-01

    This research work is focused on the application and assessment of effectiveness of the Fenton-like processes induced by radiofrequency for the inactivation of faecal bacteria (Escherichia coli and Enterococcus sp.) present in treated urban wastewater effluents. Fenton processes were carried out at near neutral pH (pH 5) with different iron sources, such as iron salts (ferric chloride, 5, 50 and 100 mg/L Fe(3+)), magnetite (1 g/L) and clay (80 g/L), hydrogen peroxide (25 mg/L) and in absence and presence of radiofrequency. Two different electromagnetic field intensities (1.57 and 3.68 kA/m) were used in Fenton processes induced by radiofrequency. Different agents used in the Fenton processes induced by electromagnetic fields (iron source, hydrogen peroxide and RF) were analyzed individually and in combination under the same experimental conditions. First assays of ferromagnetic material/H2O2/radiofrequency processes achieved promising results in terms of bacterial inactivation. For instance, Fe(3+)/H2O2/Radiofrequency achieved a maximum level of E. coli inactivation of 3.55 log after 10 min of treatment. These results are higher than those obtained in absence of radiofrequency. The thermal activation of iron atoms allows the Fenton reaction to intensify, increasing the final yield of the treatment. On the other hand, different behavior was observed in the inactivation of E. coli and Enterococcus sp. due to the structural differences between Gram-negative and Gram-positive bacteria.

  12. Combined humic acid adsorption and enhanced Fenton processes for the treatment of naphthalene dye intermediate wastewater.

    PubMed

    Gu, Lin; Zhu, Nanwen; Wang, Liang; Bing, Xiaoxiao; Chen, Xiaoliang

    2011-12-30

    In this work, an humic acid adsorption with an enhanced Fenton oxidation was employed to treat the real effluent originating from the 1-diazo-2-naphthol-4-sulfonic acid (1,2,4-Acid) production plant. In a first step, humic acid with MgSO(4) was selected as adsorbent and precipitant for physicochemical pretreatment, the synergetic effect had led to 39% of COD removal and 89% of colour removal. A multi-staged Fenton oxidation process with inner circulation was introduced subsequently. The TOC, COD, 1,2,4-Acid, NH(4)(+)-N, SS and colour were reduced from 3024 mg/L, 12,780 mg/L, 9103 mg/L, 110 mg/L, 240 mg/L and 25,600 (multiple) to 46 mg/L, 210 mg/L, 21 mg/L, 16 mg/L, 3 mg/L and 25 through the combined process, respectively. Hydrogen peroxide consumed per kg COD had saved up to 36% when two-staged Fenton process with inner circulation (flow-back to influent ratio: 3) was applied. Influence of H(2)O(2) concentration, flow-back to influent ratio and staged Fenton mode were investigated in detail in order to find out the optimal operating parameters. The kinetics of 1,2,4-Acid degradation by two-staged Fenton process was investigated. The evolution of the main intermediates during the degradation process was conducted using the LC-(ESI)-TOF-MS technique, and the results showed a staged degradation pathway from the ring opening of naphthalene compounds to the formation of benzene compounds and carboxyl acids. The combined process had been proved effective in both technical and economic aspects.

  13. Service with Style: Corinne Hill--Denton Public Library, TX

    ERIC Educational Resources Information Center

    Library Journal, 2004

    2004-01-01

    Although a librarian for only eight years, Corinne Hill is already known in Dallas and Denton, TX, for turning dull, little-used branches into vibrant community centers. A stylish woman with a zest for shopping, Hill loves developing new collections and showing them off. She sees no reason why a library should not be as attractive as any good…

  14. Accounting for imperfect detection in Hill numbers for biodiversity studies

    USGS Publications Warehouse

    Broms, Kristin M.; Hooten, Mevin B.; Fitzpatrick, Ryan M.

    2015-01-01

    The occupancy-based Hill number estimators are always at their asymptotic values (i.e. as if an infinite number of samples have been taken for the study region), therefore making it easy to compare biodiversity between different assemblages. In addition, the Hill numbers are computed as derived quantities within a Bayesian hierarchical model, allowing for straightforward inference.

  15. View of sports field and Easter Hill at west side ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of sports field and Easter Hill at west side of project site. Looking west - Easter Hill Village, Bordered by South Twenty-sixth Street, South Twenty-eighth Street, Hinkley Avenue, Foothill Avenue & Corto Square, Richmond, Contra Costa County, CA

  16. View of sports field from Easter Hill looking at intersection ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of sports field from Easter Hill looking at intersection of South Twenty-Sixth Street and Foothill Avenue at left center rear. Buildings No. 36, 35, 25, 27, and 29, from left to right. Looking northeast - Easter Hill Village, Bordered by South Twenty-sixth Street, South Twenty-eighth Street, Hinkley Avenue, Foothill Avenue & Corto Square, Richmond, Contra Costa County, CA

  17. View of sports field and Easter Hill at west side ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of sports field and Easter Hill at west side of project site. Looking southwest - Easter Hill Village, Bordered by South Twenty-sixth Street, South Twenty-eighth Street, Hinkley Avenue, Foothill Avenue & Corto Square, Richmond, Contra Costa County, CA

  18. 78 FR 76100 - Black Hills National Forest Advisory Board

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-16

    ...; ] DEPARTMENT OF AGRICULTURE Forest Service Black Hills National Forest Advisory Board AGENCY: Forest Service, USDA. ACTION: Notice of meeting. SUMMARY: The Black Hills National Forest Advisory Board (Board) will... Committee Act of 1972 (5 U.S.C. App. II), the Forest and Rangeland Renewable Resources Planning Act of...

  19. AmeriFlux US-Blk Black Hills

    SciTech Connect

    Meyers, Tilden

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-Blk Black Hills. Site Description - The Black Hills tower was established by the Institute for Atmospheric Studies of the South Dakota School of Mines and Technology.

  20. Is "Home" Still in the Hills? Staff Paper 153.

    ERIC Educational Resources Information Center

    Smith, Eldon D.

    Although there was expectation that the current recession would bring a new wave of Appalachian Kentuckians back to their homeland hills, as had previous recessions, no great "return to the hills" (or even to other areas of the state) has materialized. Unemployment insurance claims by people formerly employed in other states have not increased in…

  1. OVERVIEW OF GOLD HILL MILL, ROAD, AND WHITE PINE TALC ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    OVERVIEW OF GOLD HILL MILL, ROAD, AND WHITE PINE TALC MINE LOOKING EAST. THE OPENING TO THE TALC MINE IS IN THE DARK AREA AT CENTER LEFT EDGE. WARM SPRINGS CAMP IS OUT OF FRAME TO THE RIGHT. - Gold Hill Mill, Warm Spring Canyon Road, Death Valley Junction, Inyo County, CA

  2. VIEW TO SOUTHEAST TOWARD QUARTERMASTER BUILDINGS GROUP AND RESERVOIR HILL, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW TO SOUTHEAST TOWARD QUARTERMASTER BUILDINGS GROUP AND RESERVOIR HILL, FROM AMMUNITION (IGLOO) HILL. (Part 2 of a 3 view panorama; see also CA-2398-J-1 and CA-2398-16.) - Hamilton Field, East of Nave Drive, Novato, Marin County, CA

  3. "This Delightfull Garden": "Rabbit Hill" and the Pastoral Tradition.

    ERIC Educational Resources Information Center

    Jordan, Anne Devereaux

    1997-01-01

    Contends that Robert Lawson's children's book "Rabbit Hill" (1944) falls within the genre of pastoral literature, in the tradition of Edmund Spenser's "Faerie Queen." Examines the history of the genre and finds reasons for classifying Lawson's book as pastoral. Cites classic elements in "Rabbit Hill." Gives five questions for stimulating student…

  4. 83. GENERAL VIEW FROM NORTH END OF GUN HILL PLATFORM ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    83. GENERAL VIEW FROM NORTH END OF GUN HILL PLATFORM OF 3RD AVENUE EL SHOWING THE SOUTHBOUND TRACK APPROACH INTO GUN HILL STATION. 7TH AVENUE EXPRESS EL ABOVE. - Interborough Rapid Transit Company, Third Avenue Elevated Line, Borough of the Bronx, New York County, NY

  5. 78 FR 64471 - Black Hills National Forest Advisory Board

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-29

    ... Fifth Street, Custer, SD. Please call ahead to Scott Jacobson, ] Committee Management Officer, at 605...: Scott Jacobson, Committee Management Officer, Black Hills National Forest Supervisor's Office, 605-673... comments must be sent to Scott Jacobson, Supervisor's Office, Black Hills National Forest, 1019 North...

  6. 78 FR 59337 - Black Hills National Forest Advisory Board; Meeting

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-26

    ... Fifth Street, Custer, SD. Please call ahead to Scott Jacobson, ] Committee Management Officer, at 605...: Scott Jacobson, Committee Management Officer, Black Hills National Forest Supervisor's Office, 605-673... comments must be sent to Scott Jacobson, Supervisor's Office, Black Hills National Forest, 1019 North...

  7. 2. BUNKER HILL LEAD SMELTER. VIEW IS FROM CIA TO ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. BUNKER HILL LEAD SMELTER. VIEW IS FROM CIA TO THE SOUTH. IN FOREGROUND, PLANT DRY, SLAG FUMING PLANT, BLAST FURNACE, SMELTER OFFICE, LEAD AND SILVER REFINERIES ARE VISIBLE, L. TO R. HIGH VELOCITY FLUE LEADS FROM LOWER PLANT TO BAG HOUSE AND STACKS AT TOP OF SMELTING FACILITY. - Bunker Hill Lead Smelter, Bradley Rail Siding, Kellogg, Shoshone County, ID

  8. 3. BUNKER HILL LEAD SMELTER. VIEW IS FROM CIA TO ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. BUNKER HILL LEAD SMELTER. VIEW IS FROM CIA TO THE SOUTHWEST. BUILDINGS NOTED IN ID-29-2 APPEAR, IN ADDITION TO DRY ORE PLANT AND BONNOT COAL PULVERIZING EQUIPMENT BUILDING ON THE RIGHT. - Bunker Hill Lead Smelter, Bradley Rail Siding, Kellogg, Shoshone County, ID

  9. 1. BUNKER HILL LEAD SMELTER. VIEW IS FROM CENTRAL IMPOUNDMENT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. BUNKER HILL LEAD SMELTER. VIEW IS FROM CENTRAL IMPOUNDMENT AREA LOOKING SOUTH. PLANT DRY IS IN CENTER FOREGROUND, SLAG FUMING PLANT IS IN RIGHT FOREGROUND, AND BAG HOUSE IS IN RIGHT BACKGROUND. VARIOUS PLANT STACKS ARE ALSO VISIBLE. - Bunker Hill Lead Smelter, Bradley Rail Siding, Kellogg, Shoshone County, ID

  10. View of south boundary of Easter Hill project site for ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of south boundary of Easter Hill project site for right of way for Hoffman Boulevard. Buildings No. 11 and 14 at right in trees. Looking west - Easter Hill Village, Bordered by South Twenty-sixth Street, South Twenty-eighth Street, Hinkley Avenue, Foothill Avenue & Corto Square, Richmond, Contra Costa County, CA

  11. 77 FR 22755 - Black Hills National Forest Advisory Board

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-17

    ... approval of the Board's re-charter package submitted to the Secretary, U.S. Department of Agriculture...; ] DEPARTMENT OF AGRICULTURE Forest Service Black Hills National Forest Advisory Board AGENCY: USDA Forest Service. ACTION: Notice of cancellation of meetings of the Black Hills National Forest Advisory...

  12. VIEW LOOKING WEST TOWARD RESERVOIR HILL. THE SPRR HOTEL WAS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW LOOKING WEST TOWARD RESERVOIR HILL. THE SPRR HOTEL WAS LOCATED IN THE STRIPED AREA AT THE BOTTOM OF THE IMAGE, AND THE TRACK RAN BETWEEN THE HILL AND THE HOTEL. - Southern Pacific Railroad Water Settling Reservoir, Yuma Crossing, south bank of Colorado River at foot of Madison Avenue, Yuma, Yuma County, AZ

  13. 27 CFR 9.188 - Horse Heaven Hills.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Horse Heaven Hills. 9.188... Horse Heaven Hills. (a) Name. The name of the viticultural area described in this section is “Horse Heaven Hills”. For purposes of part 4 of this chapter, “Horse Heaven Hills” and “Horse Heaven” are...

  14. 27 CFR 9.162 - Sta. Rita Hills.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Sta. Rita Hills. 9.162.... Rita Hills. (a) Name. The name of the viticultural area described in this section is “Sta. Rita Hills”. For purposes of part 4 of this chapter, “Sta. Rita Hills” is a term of viticultural significance....

  15. 27 CFR 9.162 - Sta. Rita Hills.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Sta. Rita Hills. 9.162.... Rita Hills. (a) Name. The name of the viticultural area described in this section is “Sta. Rita Hills”. For purposes of part 4 of this chapter, “Sta. Rita Hills” is a term of viticultural significance....

  16. 27 CFR 9.162 - Sta. Rita Hills.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Sta. Rita Hills. 9.162.... Rita Hills. (a) Name. The name of the viticultural area described in this section is “Sta. Rita Hills”. For purposes of part 4 of this chapter, “Sta. Rita Hills” is a term of viticultural significance....

  17. Comparisons of calculated and measured helicopter noise near instrument hill

    NASA Technical Reports Server (NTRS)

    Bass, Henry E.; You, Chulsoo

    1993-01-01

    The polar parabolic equation (POPE) method solves for the diffraction of sound by a curved surface including a realistic sound speed profile. POPE is outlined briefly to describe diffraction which propagates the field over a hill. Experimental data are compared with POPE predictions using the measured sound speed profile and ground impedance. Two trial cases are considered for the comparisons: the helicopter located at the base of the hill and far away from the base of the hill, respectively. The physical mechanisms for sound propagation over a hill are examined with and of POPE calculations and experimental data. The shedding of rays from the hillside gives an interference effect with a wave along the flat surface beyond the base of a hill.

  18. Decay of isolated hills and saddles on Si(001)

    NASA Astrophysics Data System (ADS)

    Kirschbaum, Pierre; Brendel, Lothar; Roos, Kelly R.; Horn-von Hoegen, Michael; Heringdorf, Frank-J. Meyer zu

    2016-08-01

    We discuss the high temperature decay of isolated hills and saddle points on Si(001). Using in situ dark-field imaging in low energy electron microscopy, we track the movement of individual steps during high temperature annealing. We find different temperature dependent decay rates for the top of the hill compared to a saddle point with low step density that is present in the vicinity of the hill. The decay rate of the hill is always higher than the decay rate at the saddle. The two rates converge with increasing temperature and become equal at temperatures above 1060 °C. We also report an alternating fast and low decay rate for the layer-by-layer decay of the hills. This surprising finding is independent of temperature and is explained by macroscopic strain in the sample.

  19. Seeing mountains in mole hills: geographical-slant perception

    NASA Technical Reports Server (NTRS)

    Proffitt, D. R.; Creem, S. H.; Zosh, W. D.; Kaiser, M. K. (Principal Investigator)

    2001-01-01

    When observers face directly toward the incline of a hill, their awareness of the slant of the hill is greatly overestimated, but motoric estimates are much more accurate. The present study examined whether similar results would be found when observers were allowed to view the side of a hill. Observers viewed the cross-sections of hills in real (Experiment 1) and virtual (Experiment 2) environments and estimated the inclines with verbal estimates, by adjusting the cross-section of a disk, and by adjusting a board with their unseen hand to match the inclines. We found that the results for cross-section viewing replicated those found when observers directly face the incline. Even though the angles of hills are directly evident when viewed from the side, slant perceptions are still grossly overestimated.

  20. A linear programming model for optimizing HDR brachytherapy dose distributions with respect to mean dose in the DVH-tail

    SciTech Connect

    Holm, Åsa; Larsson, Torbjörn; Tedgren, Åsa Carlsson

    2013-08-15

    Purpose: Recent research has shown that the optimization model hitherto used in high-dose-rate (HDR) brachytherapy corresponds weakly to the dosimetric indices used to evaluate the quality of a dose distribution. Although alternative models that explicitly include such dosimetric indices have been presented, the inclusion of the dosimetric indices explicitly yields intractable models. The purpose of this paper is to develop a model for optimizing dosimetric indices that is easier to solve than those proposed earlier.Methods: In this paper, the authors present an alternative approach for optimizing dose distributions for HDR brachytherapy where dosimetric indices are taken into account through surrogates based on the conditional value-at-risk concept. This yields a linear optimization model that is easy to solve, and has the advantage that the constraints are easy to interpret and modify to obtain satisfactory dose distributions.Results: The authors show by experimental comparisons, carried out retrospectively for a set of prostate cancer patients, that their proposed model corresponds well with constraining dosimetric indices. All modifications of the parameters in the authors' model yield the expected result. The dose distributions generated are also comparable to those generated by the standard model with respect to the dosimetric indices that are used for evaluating quality.Conclusions: The authors' new model is a viable surrogate to optimizing dosimetric indices and quickly and easily yields high quality dose distributions.

  1. Dosimetric impact of applicator displacement during high dose rate (HDR) Cobalt-60 brachytherapy for cervical cancer: A planning study

    NASA Astrophysics Data System (ADS)

    Yong, J. S.; Ung, N. M.; Jamalludin, Z.; Malik, R. A.; Wong, J. H. D.; Liew, Y. M.; Ng, K. H.

    2016-02-01

    We investigated the dosimetric impact of applicator displacement on dose specification during high dose rate (HDR) Cobalt-60 (Co-60) brachytherapy for cervical cancer through a planning study. Eighteen randomly selected HDR full insertion plans were restrospectively studied. The tandem and ovoids were virtually shifted translationally and rotationally in the x-, y- and z-axis directions on the treatment planning system. Doses to reference points and volumes of interest in the plans with shifted applicators were compared with the original plans. The impact of dose displacement on 2D (point-based) and 3D (volume-based) treatment planning techniques was also assessed. A ±2 mm translational y-axis applicator shift and ±4° rotational x-axis applicator shift resulted in dosimetric changes of more than 5% to organs at risk (OAR) reference points. Changes to the maximum doses to 2 cc of the organ (D2cc) in 3D planning were statistically significant and higher than the reference points in 2D planning for both the rectum and bladder (p<0.05). Rectal D2cc was observed to be the most sensitive to applicator displacement among all dose metrics. Applicator displacement that is greater than ±2 mm translational y-axis and ±4° rotational x-axis resulted in significant dose changes to the OAR. Thus, steps must be taken to minimize the possibility of applicator displacement during brachytherapy.

  2. AGU climate scientists visit Capitol Hill

    NASA Astrophysics Data System (ADS)

    Hankin, Erik

    2012-02-01

    On 1 February 2012, AGU teamed with 11 other scientific societies to bring 29 scientists researching various aspects of climate change to Washington, D. C., for the second annual Climate Science Day on Capitol Hill. The participants represented a wide range of expertise, from meteorology to agriculture, paleoclimatology to statistics, but all spoke to the reality of climate change as demonstrated in their scientific research. With Congress debating environmental regulations and energy policy amid tight fiscal pressures, it is critical that lawmakers have access to the best climate science to help guide policy decisions. The scientists met with legislators and their staff to discuss the importance of climate science for their districts and the nation and offered their expertise as an ongoing resource to the legislators.

  3. Motivations of female Black Hills deer hunters

    USGS Publications Warehouse

    Gigliotti, Larry M.; Covelli Metcalf, Elizabeth

    2016-01-01

    State fish and wildlife agencies are particularly interested in attracting female participation because of the potential to offset declining participation in hunting. Understanding female hunters’ motivations will be critical for designing effective recruitment and retention programs for women hunters. Although female participation in hunting is increasing, males still outnumber females by about tenfold. Gender differences in deer hunters were explored by comparing ratings of eight motivations (social, nature, excitement, meat, challenge, trophy, extra hunting opportunity, and solitude). Hunter types were defined by hunters’ selection of the most important motivation for why they like Black Hills deer hunting. Overall, females and males were relatively similar in their ratings of the eight motivations, and we found 85% gender similarity in the selection of the most important motivation. Women were slightly more motivated by the food aspect of the hunt while men placed slightly more value on the hunt as a sporting activity.

  4. Ash and Steam, Soufriere Hills Volcano, Monserrat

    NASA Technical Reports Server (NTRS)

    2002-01-01

    International Space Station crew members are regularly alerted to dynamic events on the Earth's surface. On request from scientists on the ground, the ISS crew observed and recorded activity from the summit of Soufriere Hills on March 20, 2002. These two images provide a context view of the island (bottom) and a detailed view of the summit plume (top). When the images were taken, the eastern side of the summit region experienced continued lava growth, and reports posted on the Smithsonian Institution's Weekly Volcanic Activity Report indicate that 'large (50-70 m high), fast-growing, spines developed on the dome's summit. These spines periodically collapsed, producing pyroclastic flows down the volcano's east flank that sometimes reached the Tar River fan. Small ash clouds produced from these events reached roughly 1 km above the volcano and drifted westward over Plymouth and Richmond Hill. Ash predominately fell into the sea. Sulfur dioxide emission rates remained high. Theodolite measurements of the dome taken on March 20 yielded a dome height of 1,039 m.' Other photographs by astronauts of Montserrat have been posted on the Earth Observatory: digital photograph number ISS002-E-9309, taken on July 9, 2001; and a recolored and reprojected version of the same image. Digital photograph numbers ISS004-E-8972 and 8973 were taken 20 March, 2002 from Space Station Alpha and were provided by the Earth Sciences and Image Analysis Laboratory at Johnson Space Center. Additional images taken by astronauts and cosmonauts can be viewed at the NASA-JSC Gateway to Astronaut Photography of Earth.

  5. Reuse of recalcitrant-rich anaerobic effluent as dilution water after enhancement of biodegradability by Fenton processes.

    PubMed

    Arimi, Milton M; Zhang, Yongjun; Namango, Saul S; Geißen, Sven-Uwe

    2016-03-01

    Anaerobic digestion is used to treat effluents with a lot of organics, such as molasses distillery wastewater (MDW) which is the effluent of bioethanol production from molasses. The raw MDW requires a lot of dilution water before biodigestion, while the digested MDW has high level of recalcitrants which are problematic for its discharge. This study investigated ferric coagulation, Fenton, Fenton-like (with ferric ions as catalyst) processes and their combinations on the biodegradability of digested MDW. The Fenton and Fenton-like processes after coagulation increased the MDW biodegradability defined by (BOD5/COD) from 0.07 to (0.4-0.6) and saved 50% of H2O2 consumed in the classic Fenton process. The effluent from coagulation coupled to a Fenton-like process was used as dilution water for the raw MDW before the anaerobic digestion. The process was stable with volumetric loading of approx. 2.7 g COD/L/d. It resulted in increased overall biogas recovery and significantly decreased the demand for the dilution water. PMID:26692412

  6. Real-time detection of hydrogen peroxide using microelectrodes in an ultrasonic enhanced heterogeneous Fenton process catalyzed by ferrocene.

    PubMed

    Lin, Jun; Xin, Qing; Gao, Xiumin

    2015-07-01

    Microelectrodes were used for real-time detection of hydrogen peroxide (H2O2) in a heterogeneous sono-Fenton system with ferrocene as the catalyst. The working mechanism of reactive blue 13 decolorization in a heterogeneous sono-Fenton system was investigated. Ultrasonic irradiation showed no effect on decolorization when used alone and did not enhance decolorization in the H2O2 system (43.0 % for H2O2 vs. 48.1 % for US+H2O2). However, a system with the presence of Fenton-like reagents achieved complete decolorization. Decolorization was greatly accelerated by the addition of ultrasonic irradiation. Thorough decolorization was achieved in 20 min in the heterogeneous sono-Fenton system, which was 30 min faster than in the heterogeneous Fenton system. Based on the data collected by microelectrodes, accelerated decomposition of H2O2 was also observed. Ultrasonic irradiation aided the ferrocene catalyst in liberating more •OH from Fenton reactions, leading to the faster decolorization.

  7. Impact of radical versus non-radical pathway in the Fenton chemistry on the iron redox cycle in clouds.

    PubMed

    Deguillaume, Laurent; Leriche, Maud; Chaumerliac, Nadine

    2005-07-01

    Modeling studies have shown that the Fenton reaction of iron(II) with H2O2 can contribute, in a significant amount, to OH radicals production in cloud droplets. However, the destruction mechanism of hydrogen peroxide by iron(II) is still uncertain. Two reaction pathways for the first step of Fenton chemistry have been advanced: a radical pathway which considers an OH radical production and a non-radical pathway considering ferryl ion production. The aim of this work is to evaluate the impact of these two possible reaction pathways for Fenton chemistry on the iron redox cycle in cloud droplets. For this purpose, the numerical model of multiphase chemistry M2C2 has been applied to a rural chemical scenario representative of continental conditions. This study highlights that the iron redox cycling is driven by Fenton reaction whatever Fenton mechanism is considered. The ferryl ion chemistry becomes significant in the iron redox cycling when this species is considered as an active intermediate in Fenton chemistry and under night time conditions the iron redox chemistry is controlled by the ferryl ion reactivity. The partitioning of iron between its two main oxidation states (+II and +III) in cloud droplets, which is the indicator of the iron oxido-reduction potential, does not change significantly between the two cases. However, for the non-radical case, the ferryl ion concentration is up to four orders of magnitude higher than the OH concentration highlighting its potential role in oxidative capacity of cloud droplets.

  8. Design of a neutral three-dimensional electro-Fenton system with foam nickel as particle electrodes for wastewater treatment.

    PubMed

    Liu, Wei; Ai, Zhihui; Zhang, Lizhi

    2012-12-01

    In this work, we demonstrate a novel three-dimensional electro-Fenton system (3D-E-Fenton) for wastewater treatment with foam nickel, activated carbon fiber and Ti/RuO(2)-IrO(2) as the particle electrodes, the cathode, and the anode respectively. This 3D-E-Fenton system could exhibit much higher rhodamine B removal efficiency (99%) than the counterpart three-dimensional electrochemical system (33%) and E-Fenton system (19%) at neutral pH in 30 min. The degradation efficiency enhancement was attributed to much more hydroxyl radicals generated in the 3D-E-Fenton system because foam nickel particle electrodes could activate molecular oxygen to produce O(2)(-) via a single-electron transfer pathway to subsequently generate more H(2)O(2) and hydroxyl radicals. This is the first observation of molecular oxygen activation over the particle electrodes in the three-dimensional electrochemical system. These interesting findings could provide some new insight on the development of high efficient E-Fenton system for wastewater treatment at neutral pH. PMID:23141376

  9. Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes.

    PubMed

    Bokare, Alok D; Choi, Wonyong

    2014-06-30

    Iron-catalyzed hydrogen peroxide decomposition for in situ generation of hydroxyl radicals (HO(•)) has been extensively developed as advanced oxidation processes (AOPs) for environmental applications. A variety of catalytic iron species constituting metal salts (in Fe(2+) or Fe(3+) form), metal oxides (e.g., Fe2O3, Fe3O4), and zero-valent metal (Fe(0)) have been exploited for chemical (classical Fenton), photochemical (photo-Fenton) and electrochemical (electro-Fenton) degradation pathways. However, the requirement of strict acidic conditions to prevent iron precipitation still remains the bottleneck for iron-based AOPs. In this article, we present a thorough review of alternative non-iron Fenton catalysts and their reactivity towards hydrogen peroxide activation. Elements with multiple redox states (like chromium, cerium, copper, cobalt, manganese and ruthenium) all directly decompose H2O2 into HO(•) through conventional Fenton-like pathways. The in situ formation of H2O2 and decomposition into HO(•) can be also achieved using electron transfer mechanism in zero-valent aluminum/O2 system. Although these Fenton systems (except aluminum) work efficiently even at neutral pH, the H2O2 activation mechanism is very specific to the nature of the catalyst and critically depends on its composition. This review describes in detail the complex mechanisms and emphasizes on practical limitations influencing their environmental applications.

  10. Quantifying the role of mitigation hills in reducing tsunami runup

    NASA Astrophysics Data System (ADS)

    Marras, S.; Suckale, J.; Lunghino, B.; Giraldo, F.; Hood, K. M.

    2015-12-01

    Coastal communities around the world are being encouraged to plant or restore vegetation along their shores for the purpose of mitigating tsunami damage. A common setup for these projects is to develop 'mitigation hills' - an ensemble of vegetated hills along the coast - instead of one continuous stretch of vegetation. The rationale behind a staggered-hill setup is to give tree roots more space to grow and deepen. From a fluid-dynamical point of view, however, staggered mitigation hills may have significant drawbacks such as diverting the flow into the low-lying areas of the park, which could entail strong currents in the narrow channels between the hills and lead to erosion of the hills from the sides. The goal of this study is to quantify how mitigation hills affect tsunami runup and to provide constraints on the design of mitigation hills that mitigate tsunami damage using numerical simulations. Our computations of tsunami runup are based on the non-linear shallow water equation solved through a fully implicit, high-order, discontinuous Galerkin method. The adaptive computational grid is fitted to the hill topography to capture geometric effects accurately. A new dynamic subgrid-scale eddy viscosity originally designed for large eddy simulation of compressible flows is used for stabilization and to capture the obstacle-generated turbulence. We have carefully benchmarked our model in 1D and 2D against classical test cases. The included figure shows an example run of tsunami runup through coastal mitigation hills. In the interest of providing generalizable results, we perform a detailed scaling analysis of our model runs. We find that the protective value of mitigation hills depends sensitively on the non-linearity of the incoming wave and the relative height of the wave to the hills. Our simulations also suggest that the assumed initial condition is consequential and we hence consider a range of incoming waves ranging from a simple soliton to a more realistic N

  11. Wheel Tracks from Landing Site to Hills

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] [figure removed for brevity, see original site] Figure 1Figure 2

    Wheel tracks left by the NASA rover Spirit's 3-kilometer (2-mile) trek from its landing site to the 'Columbia Hills' are visible in this orbital view from the Mars Orbiter Camera on NASA's Mars Global Surveyor. Spirit's rover track shows up nicely from orbit because the surfaces disrupted and churned by the wheels are darker than the surrounding, dust-coated plain. North is up.

    The largest crater in the view, dubbed 'Bonneville Crater,' is about 210 meters (230 yards) in diameter. The picture is a composite of Mars Orbiter Camera image R15-02643, taken on March 30, 2004, when Spirit was near the south rim of Bonneville Crater, and image R20-01024, taken Aug. 18, 2004, when Spirit was climbing the hills' western spur, seen in the picture's bottom right corner.

    New Dark Streak Near Spirit In figure 1, frames taken from orbit 20 weeks apart (top pair) and by the NASA rover Spirit at ground level (bottom) show the formation of a new dark streak on the ground in the area where Spirit was driving inside Mars' Gusev Crater in April 2004. The new dark streak and other dark streaks in the area are believed to result from dust devils removing brighter dust from the surface.

    The upper frames were taken by the Mars Orbiter Camera aboard NASA's Mars Global Surveyor. They are from the same pair of images combined to create the orbital view of the NASA rover Spirit's trail from the rover's landing site to the 'Columbia Hills.' The orbiter took the upper-left picture on March 30, 2004 (Spirit's 85th martian day, or sol). It took the upper-right picture on Aug. 18, 2004 (Spirit's sol 223). A dark streak occurs in the larger crater in the lower right quarter of the August image. This streak was not present when the March image was obtained. Inspection of the lower image, which was taken by Spirit's navigation camera when the rover was at

  12. SU-E-T-362: Automatic Catheter Reconstruction of Flap Applicators in HDR Surface Brachytherapy

    SciTech Connect

    Buzurovic, I; Devlin, P; Hansen, J; O'Farrell, D; Bhagwat, M; Friesen, S; Damato, A; Lewis, J; Cormack, R

    2014-06-01

    Purpose: Catheter reconstruction is crucial for the accurate delivery of radiation dose in HDR brachytherapy. The process becomes complicated and time-consuming for large superficial clinical targets with a complex topology. A novel method for the automatic catheter reconstruction of flap applicators is proposed in this study. Methods: We have developed a program package capable of image manipulation, using C++class libraries of The-Visualization-Toolkit(VTK) software system. The workflow for automatic catheter reconstruction is: a)an anchor point is placed in 3D or in the axial view of the first slice at the tip of the first, last and middle points for the curved surface; b)similar points are placed on the last slice of the image set; c)the surface detection algorithm automatically registers the points to the images and applies the surface reconstruction filter; d)then a structured grid surface is generated through the center of the treatment catheters placed at a distance of 5mm from the patient's skin. As a result, a mesh-style plane is generated with the reconstructed catheters placed 10mm apart. To demonstrate automatic catheter reconstruction, we used CT images of patients diagnosed with cutaneous T-cell-lymphoma and imaged with Freiburg-Flap-Applicators (Nucletron™-Elekta, Netherlands). The coordinates for each catheter were generated and compared to the control points selected during the manual reconstruction for 16catheters and 368control point Results: The variation of the catheter tip positions between the automatically and manually reconstructed catheters was 0.17mm(SD=0.23mm). The position difference between the manually selected catheter control points and the corresponding points obtained automatically was 0.17mm in the x-direction (SD=0.23mm), 0.13mm in the y-direction (SD=0.22mm), and 0.14mm in the z-direction (SD=0.24mm). Conclusion: This study shows the feasibility of the automatic catheter reconstruction of flap applicators with a high level

  13. SU-C-16A-03: Direction Modulated Brachytherapy for HDR Treatment of Cervical Cancer

    SciTech Connect

    Han, D; Webster, M; Scanderbeg, D; Yashar, C; Choi, D; Song, B; Song, W; Devic, S; Ravi, A

    2014-06-15

    Purpose: To investigate a new Directional Modulated Brachytherapy (DMBT) intra-uterine tandem using various 192-Ir after-loaders. Methods: Dose distributions from the 192-Ir sources were modulated using a 6.3mm diameter tungsten shield (18.0g/cm3). The source moved along 6 longitudinal grooves, each 1.3mm in diameter, evenly spaced along periphery of the shield, The tungsten rod was enclosqed by 0.5mm thick Delrin (1.41g/cc). Monte Carlo N particle (MCNPX) was used to calculate dose distributions. 51million particles were calculated on 504 cores of a supercomputer. Fifteen different patients originally treated with a traditional tandem-and-ovoid applicator, with 5 fractions each, (15 patients X 5 fxs = 75 plans) were re-planned with the DMBT applicator combined with traditional ovoids, on an in-house developed HDR brachytherapy planning platform, which used intensity modulated planning capabilities using a constrained gradient optimization algorithm. For all plans the prescription dose was 6 Gy and they were normalized to match the clinical treated V100. Results: Generally, the DMBT plan quality was a remarkable improvement from conventional T and O plans because of the anisotropic dose distribution of DMBT. The largest difference was to the bladder which had a 0.59±0.87 Gy (8.5±28.7%) reduction in dose. This was because of the the horseshoe shape (U-shape) of the bladder. The dose reduction to rectum and sigmoid were 0.48±0.55 Gy (21.1±27.2%) and 0.10±0.38 Gy (40.6±214.9%), respectively. The D90 to the HRCTV was 6.55±0.96 Gy (conventional T and O) and 6.59±1.06 Gy (DMBT). Conclusion: For image guided adaptive brachytherapy, greater flexibility of radiation intensity is essential and DMBT can be the solution.

  14. Physics-aspects of dose accuracy in high dose rate (HDR) brachytherapy: source dosimetry, treatment planning, equipment performance and in vivo verification techniques

    PubMed Central

    Bradley, David; Nisbet, Andrew

    2012-01-01

    This study provides a review of recent publications on the physics-aspects of dosimetric accuracy in high dose rate (HDR) brachytherapy. The discussion of accuracy is primarily concerned with uncertainties, but methods to improve dose conformation to the prescribed intended dose distribution are also noted. The main aim of the paper is to review current practical techniques and methods employed for HDR brachytherapy dosimetry. This includes work on the determination of dose rate fields around brachytherapy sources, the capability of treatment planning systems, the performance of treatment units and methods to verify dose delivery. This work highlights the determinants of accuracy in HDR dosimetry and treatment delivery and presents a selection of papers, focusing on articles from the last five years, to reflect active areas of research and development. Apart from Monte Carlo modelling of source dosimetry, there is no clear consensus on the optimum techniques to be used to assure dosimetric accuracy through all the processes involved in HDR brachytherapy treatment. With the exception of the ESTRO mailed dosimetry service, there is little dosimetric audit activity reported in the literature, when compared with external beam radiotherapy verification. PMID:23349649

  15. HDR and PDR 192Ir source activity control procedures, as the part of the quality assurance system at Brachytherapy Department of Greater Poland Cancer Centre

    PubMed Central

    Błasiak, Barbara; Stefaniak, Patrycja; Bielęda, Grzegorz

    2009-01-01

    Purpose One of the main causes of treatment failures in brachytherapy is incorrect source strength specification in planning system or treatment delivery console. Source strength control is the only scheme to avoid such mistakes. The main aim of this work was to present results of three years of HDR and PDR sources activity control. Material and methods Study was based on data from 14 192Ir HDR and PDR sources exchanges. Sources were checked three times: at the exchange day and after one and two months. Measurements were performed twice with thimble chamber (PMMA phantom), and well chamber. The source strength were measured as air – kerma and recalculated to activity. Results Source activities measured using well chamber and thimble chamber, as well as activities provided by planning system, were presented for PDR and HDR, respectively. Differences between results obtained using each chamber and activities from planning system were presented graphically. The calculated and measured activities differed less than 5%. Wilcoxon test was performed as well, no statistically significant differences were observed among HDR or PDR activities. Conclusions Checking of source parameters is one of the most important parts of quality control system in brachytherapy facilities. Well chamber and thimble chamber based dosimetry systems are fast and reliable tools for 192Ir source parameters checking in working brachytherapy department conditions.

  16. Scientific contributions of A. V. Hill: exercise physiology pioneer.

    PubMed

    Bassett, David R

    2002-11-01

    Beginning in 1910, A. V. Hill performed careful experiments on the time course of heat production in isolated frog muscle. His research paralleled that of the German biochemist Otto Meyerhof, who measured the changes in muscle glycogen and lactate during contractions and recovery. For their work in discovering the distinction between aerobic and anaerobic metabolism, Hill and Meyerhof were jointly awarded the 1922 Nobel Prize for Physiology or Medicine. Because of Hill's interest in athletics, he sought to apply the concepts discovered in isolated frog muscle to the exercising human. Hill and his colleagues made measurements of O(2) consumption on themselves and other subjects running around an 85-m grass track. In the process of this work, they defined the terms "maximum O(2) intake," "O(2) requirement," and "steady state of exercise." Other contributions of Hill include his discoveries of heat production in nerve, the series elastic component, and the force-velocity equation in muscle. Around the time of World War II, Hill was a leading figure in the Academic Assistance Council, which helped Jewish scientists fleeing Nazi Germany to relocate in the West. He served as a member of the British Parliament from 1940 to 1945 and as a scientific advisor to India. Hill's vision and enthusiasm attracted many scientists to the field of exercise physiology, and he pointed the way toward many of the physiological adaptations that occur with physical training.

  17. Descent from the Summit of 'Husband Hill' (False Color)

    NASA Technical Reports Server (NTRS)

    2005-01-01

    In late November 2005 while descending 'Husband Hill,' NASA's Mars Exploration Rover Spirit took the most detailed panorama so far of the 'Inner Basin,' the rover's next target destination. Spirit acquired the 405 individual images that make up this 360-degree view of the surrounding terrain using five different filters on the panoramic camera. The rover took the images on Martian days, or sols, 672 to 677 (Nov. 23 to 28, 2005 -- the Thanksgiving holiday weekend).

    This image is a false-color rendering using camera's 750-, 530-, and 430-nanometer filters, emphasizing some colors more than others to enhance striking but subtle color differences among rocks, soils, hills, and plains.

    'Home Plate,' a bright, semi-circular feature scientists hope to investigate, is harder to discern in this image than in earlier views taken from higher up the hill. Spirit acquired this more oblique view, known as the 'Seminole panorama,' from about halfway down the south flank of Husband Hill, 50 meters (164 feet) or so below the summit. Near the center of the panorama, on the horizon, are 'McCool Hill' and 'Ramon Hill,' named, like Husband Hill, in honor of the fallen astronauts of the space shuttle Columbia. Husband Hill is visible behind the rover, on the right and left sides of the panorama. An arc of rover tracks made while avoiding obstacles and getting into position to examine rock outcrops can be traced over a long distance by zooming in to explore the panorama in greater detail.

    Spirit is now significantly farther downhill toward the center of this panorama, en route to Home Plate and other enigmatic soils and outcrop rocks in the quest to uncover the history of Gusev Crater and the 'Columbia Hills.'

  18. Methyl-orange and cadmium simultaneous removal using fly ash and photo-Fenton systems.

    PubMed

    Visa, Maria; Duta, Anca

    2013-01-15

    Wastewaters resulting from the textile and dye finishing industries need complex treatment for efficient removal of colour and other compounds existent in the dyeing and rising baths (heavy metals, surfactants, equalizers, etc.). Modified fly ash (FA) mixed with TiO(2) photocatalyst represent a viable option for simultaneous removal of dyes and heavy metals, and the optimized conditions are discussed in this paper for synthetic wastewaters containing methyl-orange (MO) and cadmium. For a cost-effective dye removal process, further tests were done, replacing the photocatalyst with a (photo)Fenton system. The optimized technological parameters (contact time, amount of fly ash and amount of Fe(2+)/H(2)O(2)) allow to reach removal efficiencies up to 88% for the heavy metal and up to 70% for the dye. The adsorption mechanisms and the process kinetic are discussed, also considering the possibility of in situ generation of the Fenton system, due to the fly ash composition.

  19. Degradation of organics in reverse osmosis concentrate by electro-Fenton process.

    PubMed

    Zhou, Minghua; Tan, Qingqing; Wang, Qian; Jiao, Yongli; Oturan, Nihal; Oturan, Mehmet A

    2012-05-15

    The present work studied, for the first time, the removal of organic pollutants from a high-salinity reverse osmosis (RO) concentrate by electro-Fenton approach using a graphite-felt as cathode. To gain insights into the process, the in situ generation of hydrogen peroxide was also investigated. The COD removal efficiency and energy consumption were optimized by investigating the effects of some important operating parameters such as ferric ion concentration, initial pH and cathodic potential. Under the conditions of cathodic potential at -0.72V and Fe(3+) concentration 0.2mM, more than 62% COD could be removed in 3h treatment, meeting the local wastewater discharge requirement (COD <50mg/L). It confirmed the feasibility of electro-Fenton process for the treatment of RO concentrate accounting for its cost-effectiveness in wide pH ranges.

  20. Optimization of Brazilian TNT industry wastewater treatment using combined zero-valent iron and fenton processes.

    PubMed

    Barreto-Rodrigues, Marcio; Silva, Flávio T; Paiva, Teresa C B

    2009-09-15

    This work explores the optimization of combined zero-valent iron and fenton processes for the treatment of TNT industry wastewater, a residue with recognized polluting potential due to its high concentration of 2,4,6-trinitrotoluene and extremely acidic pH due of the nature of the product purification process. The results of the optimization study indicate that the most efficient condition for reducing the concentration of TNT also generates sufficient amounts of iron(II)for the subsequent oxidative treatment through the Fenton reaction. In general, it was observed that the treatment was highly efficient in terms of meeting the main associated environmental parameters, since it reduced acute toxicity, removed 100% of TNT, 100% of the organic nitrogen and 95.4% of the COD.

  1. Use of Enzymatic Bio-Fenton as a New Approach in Decolorization of Malachite Green

    PubMed Central

    Karimi, Afzal; Aghbolaghy, Mostafa; Khataee, Alireza; Shoa Bargh, Shabnam

    2012-01-01

    An enzymatic reaction using glucose oxidase was applied for in situ production of hydrogen peroxide for use in simultaneously Fenton's reaction in decolorization of malachite green. It was found that decolorization rate increased by increasing of glucose concentration from 0.2 g/L to 1.5 g/L. Decolorization rate showed different behaviors versus temperature changes. Initial rate of decolorization process was increased by increasing of temperature; after 30 minutes, especially at temperatures above 30°C, the decolorization rate was gradually reduced. The pH value in the reaction media was decreased from natural to about pH = 3 which had synergic effect on the Fenton process by stabilizing of Fe2+ ions. PMID:22649310

  2. Preparation of FeCeOx by ultrasonic impregnation method for heterogeneous Fenton degradation of diclofenac.

    PubMed

    Chong, Shan; Zhang, Guangming; Zhang, Nan; Liu, Yucan; Zhu, Jia; Huang, Ting; Fang, Shunyan

    2016-09-01

    FeCeOx has been successfully synthesized by ultrasonic impregnation method and applied in diclofenac removal in heterogeneous Fenton process. The effects of ultrasonic density, impregnation time, mole ratio of Fe and Ce and calcination temperature were investigated. Nitrogen adsorption/desorption, SEM, XRD, HRTEM, Raman and XPS analyses were characterized. Stability and reusability of FeCeOx were evaluated. The results indicated that 83% degradation efficiency of diclofenac was achieved by FeCeOx under the optimum preparation conditions. Fe ions were distributed uniformly in crystal structure and the solid solution structure of FeCeOx with a lattice constriction was formed. Exposed crystalline plane (200) with a relatively high surface energy may be the main reason to provide high catalytic activity of FeCeOx. Oxygen vacancies took part in catalytic process and a portion of them were oxidized after reaction. FeCeOx showed an excellent chemical stability and reusability in heterogeneous Fenton process.

  3. Optimization of photo-Fenton process of RO concentrated coking wastewater using response surface methodology.

    PubMed

    Huiqing, Zhang; Chunsong, Ye; Xian, Zhang; Fan, Yang; Jun, Yang; Wei, Zhou

    2012-01-01

    The objective of this study was aimed at investigating the removal of chemical oxygen demand (COD) from reverse osmosis (RO) concentrated coking wastewater by the photo-Fenton process. The optimum extraction conditions for the photo-Fenton process by Box-Behnken design (BBD) and response surface methodology (RSM) to establish a predictive polynomial quadratic model were discussed based on a single factor test. Optimized parameters validated by the analysis of variances (ANOVA) were found to be H(2)O(2) concentration of 345.2 mg/L, pH value of 4.1 and reaction time of 103.5 minutes under ultraviolet irradiation. The experimental results of the COD removal under the optimized conditions presented better agreement with the predicted values with deviation error of 3.2%. The results confirmed that RSM based on BBD was a suitable method to optimize the operating conditions of RO concentrated coking wastewater.

  4. Applicability of nano zero valent iron (nZVI) in sono - Fenton process

    NASA Astrophysics Data System (ADS)

    Taha, M. R.; Ibrahim, A. H.; Amat, R. C.; Azhari, A. W.

    2014-04-01

    Fenton process is one of the advanced oxidation processes (AOPs) used to remove complex organic pollutants in wastewater. In this study, instead of iron sulfate (FeSO4), nano zero valent iron (nZVI) was used as a major source of ferrous iron (Fe2+). In order to enhance the process, ultrasound was utilized in this study. Results show that, with the aid of ultrasound, nZVI produced more Fe2+ compared to FeSO4 at pH 2. Furthermore, combination of higher intensity and longer sonication time in Fenton process acceleratde the chemical oxygen demand (COD) removal from palm oil mill effluent (POME). Through the process, 80% of COD content was removed within 2 hours instead of 24 hours of silent degradation.

  5. Application of Fenton's reaction to steam explosion prehydrolysates from poplar biomass.

    PubMed

    Oliva, J M; Manzanares, P; Ballesteros, I; Negro, M J; González, A; Ballesteros, M

    2005-01-01

    The application of Fenton's reaction to enhance the fermentability of prehydrolysates obtained from steam explosion pretreatment of poplar biomass was studied. Reaction conditions of temperature and H2O2 and Fe(II) concentrations were studied. The fermentability of prehydrolysate treated by Fenton's reaction was tested by using different inoculum sizes of thermotolerant strain Kluyveromyces marxianus CECT 10875. The highest percentages of toxic compound degradation (ranging from 71 to 93% removal) were obtained at the highest H2O2 concentration tested (50 mM). However, a negative effect on fermentability was observed at this H2O2 concentration at the lower inoculum loading. An increase in inoculum size to 0.6 g/L resulted in an enhanced ethanol fermentation yield of 95% relative to control.

  6. Application of click chemistry conditions for 5-bromo-2'-deoxyuridine determination through Fenton and related reactions.

    PubMed

    Cappella, Paolo; Pulici, Maurizio; Gasparri, Fabio

    2015-01-05

    Mixtures of ascorbate and copper used in certain click chemistry experimental conditions act as oxidizing agents, catalyzing the formation of reactive oxygen species through Fenton and related reactions. Hydroxyl radicals act as chemical nucleases, introducing DNA strand breaks that can be exploited for BrdU immunostaining in place of acid denaturation. This procedure is readily applicable to high content analysis and flow cytometry assays, and provides results comparable to click chemistry EdU cycloaddition and classical BrdU immunodetection. Importantly, this approach allows preservation of labile epitopes such as phosphoproteins. This unit describes an optimized method that successfully employs Fenton chemistry for simultaneous detection of phosphoproteins and BrdU in intact cells.

  7. [Research on Fenton treatment of the biochemical processes effluent of bamboo industry wastewater].

    PubMed

    Guo, Qing-Wen; Zhang, Min; Wang, Wei; Yang, Zhi-Zhong; Wu, Dong-Lei

    2013-06-01

    The decolorization and organic matter reduction of bamboo wastewater using Fenton oxidation was studied. Considering the cost and the removal efficiency, the optimal conditions were t = 30 degrees C, pH = 3.5, p(H2O2) = 1 665 mg x L(-1), c(Fe2+)/c(H2O2) = 0.072 and reaction time 3 h, with an initial COD and color concentration of wastewater of 430 mg x L(-1) and 1 500 times, under these conditions, the removal efficiency of COD and color could achieve 87.5% and 94.4%, respectively. It was found that the color reduction was higher than that of organics, and less affected by operation factors. The GC-MS analysis revealed that the chromophoric groups and auxochromic groups were greatly removed after Fenton treatment. The intermediates were mainly ester derivatives, and the by-products included 1-iodo-tridecane and 1,1'-oxybisoctane.

  8. Evolution of the Puente Hills Thrust Fault

    NASA Astrophysics Data System (ADS)

    Bergen, K. J.; Shaw, J. H.; Dolan, J. F.

    2013-12-01

    This study aims to assess the evolution of the blind Puente Hills thrust fault system (PHT) by determining its age of initiation, lateral propagation history, and changes in slip rate over time. The PHT presents one of the largest seismic hazards in the United States, given its location beneath downtown Los Angeles. The PHT is comprised of three fault segments: the Los Angeles (LA), Santa Fe Springs (SFS), and Coyote Hills (CH). The LA and SFS segments are characterized by growth stratigraphy where folds formed by uplift on the fault segments have been continually buried by sediment from the Los Angeles and San Gabriel rivers. The CH segment has developed topography and is characterized by onlapping growth stratigraphy. This depositional setting gives us the unique opportunity to measure uplift on the LA and SFS fault segments, and minimum uplift on the CH fault segment, as the difference in sediment thicknesses across the buried folds. We utilize depth converted oil industry seismic reflection data to image the fold geometries. Identifying time-correlative stratigraphic markers for slip rate determination in the basin has been a problem for researchers in the past, however, as the faunal assemblages observed in wells are time-transgressive by nature. To overcome this, we utilize the sequence stratigraphic model and well picks of Ponti et al. (2007) as a basis for mapping time-correlative sequence boundaries throughout our industry seismic reflection data from the present to the Pleistocene. From the Pleistocene to Miocene we identify additional sequence boundaries in our seismic reflection data from imaged sequence geometries and by correlating industry well formation tops. The sequence and formation top picks are then used to build 3-dimensional surfaces in the modeling program Gocad. From these surfaces we measure the change in thicknesses across the folds to obtain uplift rates between each sequence boundary. Our results show three distinct phases of

  9. Fenton reaction-based colorimetric immunoassay for sensitive detection of brevetoxin B.

    PubMed

    Lai, Wenqiang; Wei, Qiaohua; Zhuang, Junyang; Lu, Minghua; Tang, Dianping

    2016-06-15

    We designed a new colorimetric immunoassay for sensitive monitoring of brevetoxin B (BTB) using enzyme-controlled Fenton reaction with a high-resolution 3,3',5,5'-tetramethylbenzidine (TMB)-based visual colored system. Upon addition of hydrogen peroxide (H2O2), the equivalent iron(II) could be first converted into iron(III) and free hydroxyl radical (•OH) via the classical Fenton reaction. Then the as-produced iron(III) and •OH could cause a perceptible change from colorless to blue with the increasing H2O2 concentration in the presence of TMB. Based on Fenton reaction-triggered visual colored system, a novel competitive-type colorimetric enzyme immunoassay was developed for the quantitative screening of target BTB on the bovine serum albumin-BTB-modified magnetic bead using glucose oxidase/anti-BTB antibody-labeled gold nanoparticle as the signal-transduction tag. Upon target BTB introduction, the analyte competed with the conjugated BTB on the magnetic bead for anti-BTB antibody on gold nanoparticle. The carried glucose oxidase with the gold nanoparticle could implement the oxidation of glucose to produce H2O2, and the generated H2O2 promoted the above-mentioned Fenton reaction for color development. Under the optimal conditions, the absorbance decreased with the increasing target BTB in the range from 0.1 to 150 ng kg(-1) with a low detection limit (LOD) of 0.076 ng kg(-1). The LOD was 500-fold lower than that of commercialized Abraxis BTB ELISA kit. Non-specific adsorption was not observed. The precision, reproducibility and specificity were acceptable. Finally, the method accuracy was also validated for monitoring spiked seafood samples, giving results well matched with the referenced brevetoxin ELISA kit. PMID:26851583

  10. Advanced treatment of biologically pretreated coal gasification wastewater by a novel heterogeneous Fenton oxidation process.

    PubMed

    Zhuang, Haifeng; Han, Hongjun; Ma, Wencheng; Hou, Baolin; Jia, Shengyong; Zhao, Qian

    2015-07-01

    Sewage sludge from a biological wastewater treatment plant was converted into sewage sludge based activated carbon (SBAC) with ZnCl2 as activation agent, which was used as a support for ferric oxides to form a catalyst (FeOx/SBAC) by a simple impregnation method. The new material was then used to improve the performance of Fenton oxidation of real biologically pretreated coal gasification wastewater (CGW). The results indicated that the prepared FeOx/SBAC significantly enhanced the pollutant removal performance in the Fenton process, so that the treated wastewater was more biodegradable and less toxic. The best performance was obtained over a wide pH range from 2 to 7, temperature 30°C, 15 mg/L of H2O2 and 1g/L of catalyst, and the treated effluent concentrations of COD, total phenols, BOD5 and TOC all met the discharge limits in China. Meanwhile, on the basis of significant inhibition by a radical scavenger in the heterogeneous Fenton process as well as the evolution of FT-IR spectra of pollutant-saturated FeOx/BAC with and without H2O2, it was deduced that the catalytic activity was responsible for generating hydroxyl radicals, and a possible reaction pathway and interface mechanism were proposed. Moreover, FeOx/SBAC showed superior stability over five successive oxidation runs. Thus, heterogeneous Fenton oxidation of biologically pretreated CGW by FeOx/SBAC, with the advantages of being economical, efficient and sustainable, holds promise for engineering application.

  11. Physical and oxidative removal of organics during Fenton treatment of mature municipal landfill leachate.

    PubMed

    Deng, Yang

    2007-07-19

    Municipal landfill leachate, especially mature leachate, may disrupt the performance of moderately-sized municipal activated sludge wastewater treatment plants, and likewise tend to be recalcitrant to biological pretreatment. Recently, Fenton methods have been investigated for chemical treatment or pre-treatment of mature leachate. In this paper, the results of laboratory tests to determine the roles of oxidation and coagulation in reducing the organic content of mature leachate during Fenton treatment are presented. The efficiencies of chemical oxygen demand (COD) oxidation and coagulation were tested, and the ratio of COD removal by oxidation to that by coagulation was assessed, under various operating conditions. Low initial pH, appropriate relative and absolute Fenton reagent dosages, aeration, and stepwise addition of reagents increased COD removal by oxidation and the importance of oxidation relative to coagulation. Simultaneous aeration and stepwise reagent addition allowed comparable treatment without initial acidification pH, due to the generation of acidic organic intermediates and the continuous input of CO2. On the other hand, high COD oxidation efficiency and low ferrous dosage inhibited COD removal by coagulation. At significantly high oxidation efficiency, overall COD reduction decrease slightly due to low coagulation efficiency. Under the most favorable conditions (initial pH 3, molar ratio [H(2)O(2)]/[Fe2+]=3, [H2O2]=240 mM, and six dosing steps), 61% of the initial COD was removed, and the ratio of COD removal oxidation to coagulation was 0.75. Results highlighted the synergistic roles of oxidation and coagulation in Fenton treatment of mature leachate, and the role of oxidation in controlling the efficiency of removal of COD by coagulation. PMID:17208367

  12. Fe-pillared clay as a Fenton-type heterogeneous catalyst for cinnamic acid degradation.

    PubMed

    Tabet, Djamel; Saidi, Mohamed; Houari, Mohamed; Pichat, Pierre; Khalaf, Hussein

    2006-09-01

    Fe-pillared montmorillonite has been used as a Fenton-type heterogeneous catalyst for the removal of cinnamic acid in water. The influences of the cinnamic acid, catalyst and H2O2 concentrations and pH on the removal rate of cinnamic acid have been studied. The results show that the efficiency of Fe-pillared montmorillonite is higher than that of the Fe ions in the homogeneous phase, and less sensitive to pH. PMID:16546315

  13. Comparison of mineral and soluble iron Fenton's catalysts for the treatment of trichloroethylene.

    PubMed

    Teel, A L; Warberg, C R; Atkinson, D A; Watts, R J

    2001-03-01

    Contaminant degradation, stoichiometry, and role of hydroxyl radicals (OH*) in four Fenton's systems were investigated using trichloroethylene (TCE) as a model contaminant. A standard Fenton's system, a modified soluble iron system with a pulse input of hydrogen peroxide, and two modified mineral-catalyzed systems (pH 3 and 7) were studied. In the standard Fenton's system, which had the most efficient reaction stoichiometry, 78% of the TCE was degraded; however, chloride analysis indicated that no more than two of the three chlorines were displaced per TCE molecule degraded. Although the modified soluble iron system was characterized by 91% TCE degradation, chloride analysis also indicated that no more than two of the chlorines were lost from the TCE. In the goethite system of pH 3, > 99% of the TCE was degraded. Near-complete release of chloride suggested that the TCE may have been mineralized. Only 22% degradation of TCE was achieved in the pH 7 goethite system. and there was minimal release of chloride. The mineral-catalyzed reactions exhibited the least efficient reaction stoichiometry of the four systems. Experiments using hydroxyl radical scavengers showed that the standard Fenton's system degraded TCE entirely by hydroxyl radical mechanisms, while approximately 10-15% of the degradation achieved in the modified soluble iron and goethite-catalyzed systems at pH 3 was mediated by non-hydroxyl radical mechanisms. In the goethite system at pH 7, only non-hydroxyl radical mechanisms were found. The goethite-catalyzed system at pH 3 effectively degraded the parent compound and may have the potential to mineralize contaminants when used for in situ soil and groundwater remediation and ex situ waste stream treatment in packed-bed reactors.

  14. New approach to solar photo-Fenton operation. Raceway ponds as tertiary treatment technology.

    PubMed

    Carra, Irene; Santos-Juanes, Lucas; Acién Fernández, Francisco Gabriel; Malato, Sixto; Sánchez Pérez, José Antonio

    2014-08-30

    The photo-Fenton process has proven its efficiency in the removal of micropollutants. However, the high costs usually associated with it prevent a spread of this technology. An important factor affecting costs is the kind of photoreactor used, usually tubular with a reflecting surface. Tubular reactors like compound parabolic collectors, CPCs, involve high capital costs. In comparison, the application of less costly reactors such as the extensive raceway ponds (RPRs) would help to spread the use of the photo-Fenton process as tertiary treatment at commercial scale. As far as the authors know, RPRs have never been used in advanced oxidation processes (AOPs) applications. This work is aimed at studying the applicability of RPRs to remove micropollutants with solar photo-Fenton. For this purpose, a pesticide mixture of commercial acetamiprid (ACTM) and thiabendazole (TBZ) (100μg/L each) was used in simulated secondary effluent. Iron concentration (1, 5.5 and 10mg/L) and liquid depth (5, 10 and 15cm) were studied as process variables. TBZ was removed at the beginning of the treatment (less than 5min), although ACTM removal times were longer (20-40min for the highest iron concentrations). High treatment capacity per surface area was obtained (48mg/hm(2) with 5.5mg Fe/L and 15cm liquid depth), proving the feasibility of using RPRs for micropollutant removal.

  15. Degradation of caffeine by photo-Fenton process: optimization of treatment conditions using experimental design.

    PubMed

    Trovó, Alam G; Silva, Tatiane F S; Gomes, Oswaldo; Machado, Antonio E H; Neto, Waldomiro Borges; Muller, Paulo S; Daniel, Daniela

    2013-01-01

    The degradation of caffeine in different kind of effluents, via photo-Fenton process, was investigated in lab-scale and in a solar pilot plant. The treatment conditions (caffeine, Fe(2+) and H(2)O(2) concentrations) were defined by experimental design. The optimized conditions for each variable, obtained using the response factor (% mineralization), were: 52.0 mg L(-1)caffeine, 10.0 mg L(-1)Fe(2+) and 42.0 mg L(-1)H(2)O(2) (replaced in kinetic experiments). Under these conditions, in ultrapure water (UW), the caffeine concentration reached the quantitation limit (0.76 mg L(-1)) after 20 min, and 78% of mineralization was obtained respectively after 120 min of reaction. Using the same conditions, the matrix influence (surface water - SW and sewage treatment plant effluent - STP) on caffeine degradation was also evaluated. The total removal of caffeine in SW was reached at the same time in UW (after 20 min), while 40 min were necessary in STP. Although lower mineralization rates were verified for high organic load, under the same operational conditions, less H(2)O(2) was necessary to mineralize the dissolved organic carbon as the initial organic load increases. A high efficiency of the photo-Fenton process was also observed in caffeine degradation by solar photocatalysis using a CPC reactor, as well as intermediates of low toxicity, demonstrating that photo-Fenton process can be a viable alternative for caffeine removal in wastewater.

  16. Solar photo-Fenton treatment of carbofuran: analysis of mineralization, toxicity, and organic by-products.

    PubMed

    Lopez-Alvarez, Blady; Torres-Palma, Ricardo A; Ferraro, Franklin; Peñuela, Gustavo

    2012-01-01

    The degradation of the pesticide carbofuran (CBF) using solar photo-Fenton treatment, at both the laboratory and the pilot scale, was evaluated. At the laboratory scale, in a suntest reactor, the Fe(2+) concentration and H(2)O(2) concentration were evaluated and optimized using the surface response methodology and the Pareto diagram. Under optimal conditions experiments were performed to evaluate the evolution of the substrate removal, oxidation, subsequent mineralization, toxicity and the formation of chloride ions during the treatment. The analysis and evolution of five CBF by-products as well as several control and reactivity tests at the density functional theory level were used to depict a general scheme of the main degradation pathway of CBF via the photo-Fenton system. Finally, at the pilot scale, a sample of the commercial CBF product Furadan was eliminated after 420 min by the photo-Fenton system using direct sunlight. Under these conditions, after 900 min 89% of toxicity (1/E(50) on Vibrio fischeri bacteria), 97% of chemical oxygen demand, and 90% of dissolved organic carbon were removed. PMID:22871012

  17. Sequencing treatment of landfill leachate using ammonia stripping, Fenton oxidation and biological treatment.

    PubMed

    Nurisepehr, Mohammad; Jorfi, Sahand; Rezaei Kalantary, Roshanak; Akbari, Hamideh; Soltani, Reza Darvishi Cheshmeh; Samaei, Mohamad

    2012-09-01

    Landfill leachates contain a wide variety of pollutants such as organic matter, refractory compounds, ammonia, particulate and dissolved solids and hazardous metals requiring application of advanced and well designed treatment processes before release to the environment. The main purpose of this research was to evaluate the efficiency of combined air stripping, Fenton oxidation and biological treatment in treating landfill leachate, especially the elimination of ammonia and refractory organics. The laboratory scale set-up consisted of three sequential but separate steps. The optimum conditions for air stripping and the Fenton oxidation were determined for landfill leachate from Karaj city, Iran. The final step was a moving bed bioreactor with HRTs of 18, 12 and 6 h. The highest NH(3)-N removal was 79% in the air stripping process at pH 10.5. At the optimum conditions for the Fenton reaction at a reaction time of 90 min, pH 3 and a H(2)O(2)/Fe(2+) mass ratio of 20, the COD removal was 61% and improved the BOD/COD ratio from 0.42 to 0.78. The overall COD removal including the final biological reactor with a HRT of 6 h resulted in an effluent COD concentration of less than 100 mg L(-1).

  18. Treatment of landfill leachate using a combined stripping, Fenton, SBR, and coagulation process.

    PubMed

    Guo, Jin-Song; Abbas, Abdulhussain A; Chen, You-Peng; Liu, Zhi-Ping; Fang, Fang; Chen, Peng

    2010-06-15

    The leachate from Changshengqiao landfill (Chongqing, China) was characterized and submitted to a combined process of air stripping, Fenton, sequencing batch reactor (SBR), and coagulation. Optimum operating conditions for each process were identified. The performance of the treatment was assessed by monitoring the removal of organic matter (COD and BOD(5)) and ammonia nitrogen (NH(3)-N). It has been confirmed that air stripping (at pH 11.0 and aeration time 18h) effectively removed 96.6% of the ammonia. The Fenton process was investigated under optimum conditions (pH 3.0, FeSO(4).7H(2)O of 20 g l(-1) and H(2)O(2) of 20 ml l(-1)), COD removal of up to 60.8% was achieved. Biodegradability (BOD(5)/COD ratio) increased from 0.18 to 0.38. Thereafter the Fenton effluent was mixed with sewage at dilutions to a ratio of 1:3 before it was subjected to the SBR reactor; under the optimum aeration time of 20 h, up to 82.8% BOD(5) removal and 83.1% COD removal were achieved. The optimum coagulant (Fe(2)(SO(4))(3)) was a dosage of 800 mg l(-1) at pH of 5.0, which reduced COD to an amount of 280 mg l(-1). These combined processes were successfully employed and very effectively decreased pollutant loading.

  19. Degradation of alachlor and pyrimethanil by combined photo-Fenton and biological oxidation.

    PubMed

    Ballesteros Martín, M M; Sánchez Pérez, J A; García Sánchez, J L; Montes de Oca, L; Casas López, J L; Oller, I; Malato Rodríguez, S

    2008-06-30

    Biodegradability of aqueous solutions of the herbicide alachlor and the fungicide pyrimethanil, partly treated by photo-Fenton, and the effect of photoreaction intermediates on growth and DOC removal kinetics of the bacteria Pseudomonas putida CECT 324 are demonstrated. Toxicity of 30-120 mg L(-1) alachlor and pyrimethanil has been assayed in P. putida. The biodegradability of photocatalytic intermediates found at different photo-treatment times was evaluated for each pesticide. At a selected time during batch-mode phototreatment, larger-scale biodegradation kinetics were analysed in a 12 L bubble column bioreactor. Both alachlor and pyrimethanil are non-toxic for P. putida CECT 324 at the test concentrations, but they are not biodegradable. A approximately 100 min photo-Fenton pre-treatment was enough to enhance biodegradability, the biological oxidation response being dependent on the pesticide tested. The different alachlor and pyrimethanil respiration and carbon uptake rates in pre-treated solutions are related to change in the growth kinetics of P. putida. Reproducible results have shown that P. putida could be a suitable microorganism for determining photo-Fenton pre-treatment time. PMID:18162295

  20. Pyrite nanoparticles as a Fenton-like reagent for in situ remediation of organic pollutants

    PubMed Central

    Losa-Adams, Elisabeth; F.-Dávila, Alfonso; Gago-Duport, Luis

    2014-01-01

    Summary The Fenton reaction is the most widely used advanced oxidation process (AOP) for wastewater treatment. This study reports on the use of pyrite nanoparticles and microparticles as Fenton reagents for the oxidative degradation of copper phthalocyanine (CuPc) as a representative contaminant. Upon oxidative dissolution in water, pyrite (FeS2) particles can generate H2O2 at their surface while simultaneously promoting recycling of Fe3+ into Fe2+ and vice versa. Pyrite nanoparticles were synthesized by the hot injection method. The use of a high concentration of precursors gave individual nanoparticles (diameter: 20 nm) with broader crystallinity at the outer interfaces, providing a greater number of surface defects, which is advantageous for generating H2O2. Batch reactions were run to monitor the kinetics of CuPc degradation in real time and the amount of H2O2. A markedly greater degradation of CuPc was achieved with nanoparticles as compared to microparticles: at low loadings (0.08 mg/L) and 20 h reaction time, the former enabled 60% CuPc removal, whereas the latter enabled only 7% removal. These results confirm that the use of low concentrations of synthetic nanoparticles can be a cost effective alternative to conventional Fenton procedures for use in wastewater treatment, avoiding the potential risks caused by the release of heavy metals upon dissolution of natural pyrites. PMID:24991522

  1. Citric Acid-Modified Fenton's Reaction for the Oxidation of Chlorinated Ethylenes in Soil Solution Systems

    SciTech Connect

    Seol, Yongkoo; Javandel, Iraj

    2008-03-15

    Fenton's reagent, a solution of hydrogen peroxide and ferrous iron catalyst, is used for an in-situ chemical oxidation of organic contaminants. Sulfuric acid is commonly used to create an acidic condition needed for catalytic oxidation. Fenton's reaction often involves pressure buildup and precipitation of reaction products, which can cause safety hazards and diminish efficiency. We selected citric acid, a food-grade substance, as an acidifying agent to evaluate its efficiencies for organic contaminant removal in Fenton's reaction, and examined the impacts of using citric acid on the unwanted reaction products. A series of batch and column experiments were performed with varying H{sub 2}O{sub 2} concentrations to decompose selected chlorinated ethylenes. Either dissolved iron from soil or iron sulfate salt was added to provide the iron catalyst in the batch tests. Batch experiments revealed that both citric and sulfuric acid systems achieved over 90% contaminant removal rates, and the presence of iron catalyst was essential for effective decontamination. Batch tests with citric acid showed no signs of pressure accumulation and solid precipitations, however the results suggested that an excessive usage of H{sub 2}O{sub 2} relative to iron catalysts (Fe{sup 2+}/H{sub 2}O{sub 2} < 1/330) would result in lowering the efficiency of contaminant removal by iron chelations in the citric acid system. Column tests confirmed that citric acid could provide suitable acidic conditions to achieve higher than 55% contaminant removal rates.

  2. New approach to solar photo-Fenton operation. Raceway ponds as tertiary treatment technology.

    PubMed

    Carra, Irene; Santos-Juanes, Lucas; Acién Fernández, Francisco Gabriel; Malato, Sixto; Sánchez Pérez, José Antonio

    2014-08-30

    The photo-Fenton process has proven its efficiency in the removal of micropollutants. However, the high costs usually associated with it prevent a spread of this technology. An important factor affecting costs is the kind of photoreactor used, usually tubular with a reflecting surface. Tubular reactors like compound parabolic collectors, CPCs, involve high capital costs. In comparison, the application of less costly reactors such as the extensive raceway ponds (RPRs) would help to spread the use of the photo-Fenton process as tertiary treatment at commercial scale. As far as the authors know, RPRs have never been used in advanced oxidation processes (AOPs) applications. This work is aimed at studying the applicability of RPRs to remove micropollutants with solar photo-Fenton. For this purpose, a pesticide mixture of commercial acetamiprid (ACTM) and thiabendazole (TBZ) (100μg/L each) was used in simulated secondary effluent. Iron concentration (1, 5.5 and 10mg/L) and liquid depth (5, 10 and 15cm) were studied as process variables. TBZ was removed at the beginning of the treatment (less than 5min), although ACTM removal times were longer (20-40min for the highest iron concentrations). High treatment capacity per surface area was obtained (48mg/hm(2) with 5.5mg Fe/L and 15cm liquid depth), proving the feasibility of using RPRs for micropollutant removal. PMID:25072137

  3. Removal of PAHs and pesticides from polluted soils by enhanced electrokinetic-Fenton treatment.

    PubMed

    Bocos, Elvira; Fernández-Costas, Carmen; Pazos, Marta; Sanromán, M Ángeles

    2015-04-01

    In this study, electrokinetic-Fenton treatment was used to remediate a soil polluted with PAHs and the pesticide pyrimethanil. Recently, this treatment has emerged as an interesting alternative to conventional soil treatments due to its peculiar advantages, namely the capability of treating fine and low-permeability materials, as well as that of achieving a high yield in the removals of salt content and inorganic and organic pollutants. In a standard electrokinetic-Fenton treatment, the maximum degradation of the pollutant load achieved was 67%, due to the precipitation of the metals near the cathode chamber that reduces the electro-osmotic flow of the system and thus the efficiency of the treatment. To overcome this problem, different complexing agents and pH control in the cathode chamber were evaluated to increase the electro-osmotic flux as well as to render easier the solubilization of the metal species present in the soil. Four complexing agents (ascorbic acid, citric acid, oxalic acid and ethylenediaminetetraacetic acid) in the Fenton-like treatment were evaluated. Results revealed the citric acid as the most suitable complexing agent. Thereby its efficiency was tested as pH controller by flushing it in the cathode chamber (pH 2 and 5). For the latter treatments, near total degradation was achieved after 27 d. Finally, phytotoxicity tests for polluted and treated samples were carried out. The high germination levels of the soil treated under enhanced conditions concluded that nearly complete restoration was achieved. PMID:25577698

  4. Ultrasonic application to boost hydroxyl radical formation during Fenton oxidation and release organic matter from sludge.

    PubMed

    Gong, Changxiu; Jiang, Jianguo; Li, De'an; Tian, Sicong

    2015-06-12

    We examined the effects of ultrasound and Fenton reagent on ultrasonic coupling Fenton oxidation (U+F) pre-treatment processes for the disintegration of wastewater treatment plant sludge. The results demonstrated that U+F treatment could significantly increase soluble chemical oxygen demand (SCOD), total organic carbon (TOC), and extracellular polymeric substances (EPS) concentrations in sludge supernatant. This method was more effective than ultrasonic (U) or Fenton oxidation (F) treatment alone. U+F treatment increased the release of SCOD by 2.1- and 1.4-fold compared with U and F alone, respectively. U+F treatment increased the release of EPS by 1.2-fold compared with U alone. After U+F treatment, sludge showed a considerably finer particle size and looser microstructure based on fluorescence microscopy, and the concentration of hydroxyl radicals (OH•) increased from 0.26 mM by F treatment to 0.43 mM by U+F treatment based on fluorescence spectrophotometer. This demonstrated that U+F treatment improves the release of organic matter from sludge.

  5. Removal of PAHs and pesticides from polluted soils by enhanced electrokinetic-Fenton treatment.

    PubMed

    Bocos, Elvira; Fernández-Costas, Carmen; Pazos, Marta; Sanromán, M Ángeles

    2015-04-01

    In this study, electrokinetic-Fenton treatment was used to remediate a soil polluted with PAHs and the pesticide pyrimethanil. Recently, this treatment has emerged as an interesting alternative to conventional soil treatments due to its peculiar advantages, namely the capability of treating fine and low-permeability materials, as well as that of achieving a high yield in the removals of salt content and inorganic and organic pollutants. In a standard electrokinetic-Fenton treatment, the maximum degradation of the pollutant load achieved was 67%, due to the precipitation of the metals near the cathode chamber that reduces the electro-osmotic flow of the system and thus the efficiency of the treatment. To overcome this problem, different complexing agents and pH control in the cathode chamber were evaluated to increase the electro-osmotic flux as well as to render easier the solubilization of the metal species present in the soil. Four complexing agents (ascorbic acid, citric acid, oxalic acid and ethylenediaminetetraacetic acid) in the Fenton-like treatment were evaluated. Results revealed the citric acid as the most suitable complexing agent. Thereby its efficiency was tested as pH controller by flushing it in the cathode chamber (pH 2 and 5). For the latter treatments, near total degradation was achieved after 27 d. Finally, phytotoxicity tests for polluted and treated samples were carried out. The high germination levels of the soil treated under enhanced conditions concluded that nearly complete restoration was achieved.

  6. Pyrite nanoparticles as a Fenton-like reagent for in situ remediation of organic pollutants.

    PubMed

    Gil-Lozano, Carolina; Losa-Adams, Elisabeth; F-Dávila, Alfonso; Gago-Duport, Luis

    2014-01-01

    The Fenton reaction is the most widely used advanced oxidation process (AOP) for wastewater treatment. This study reports on the use of pyrite nanoparticles and microparticles as Fenton reagents for the oxidative degradation of copper phthalocyanine (CuPc) as a representative contaminant. Upon oxidative dissolution in water, pyrite (FeS2) particles can generate H2O2 at their surface while simultaneously promoting recycling of Fe(3+) into Fe(2+) and vice versa. Pyrite nanoparticles were synthesized by the hot injection method. The use of a high concentration of precursors gave individual nanoparticles (diameter: 20 nm) with broader crystallinity at the outer interfaces, providing a greater number of surface defects, which is advantageous for generating H2O2. Batch reactions were run to monitor the kinetics of CuPc degradation in real time and the amount of H2O2. A markedly greater degradation of CuPc was achieved with nanoparticles as compared to microparticles: at low loadings (0.08 mg/L) and 20 h reaction time, the former enabled 60% CuPc removal, whereas the latter enabled only 7% removal. These results confirm that the use of low concentrations of synthetic nanoparticles can be a cost effective alternative to conventional Fenton procedures for use in wastewater treatment, avoiding the potential risks caused by the release of heavy metals upon dissolution of natural pyrites. PMID:24991522

  7. Transformation of PAHs during ethanol-Fenton treatment of an aged gasworks' soil.

    PubMed

    Lundstedt, Staffan; Persson, Ylva; Oberg, Lars

    2006-11-01

    PAH-contaminated soil from a former gasworks site was treated with Fenton's reagent in a number of lab-scale slurry reactors. The degradation result obtained by traditional Fenton oxidation and Fenton oxidation preceded by ethanol treatment were compared. The ethanol pre-treatment enhanced the depletion of all PAHs in the soil by facilitating their desorption from the soil matrix. However, some PAHs, especially anthracene, benzo[a]pyrene and perylene, were more extensively depleted than other PAHs with fewer or equal numbers of fused rings, indicating that the hydroxyl radicals react faster with these PAHs than with other kinds. The ethanol present in the slurry also appeared to influence the relative reactivity of the PAHs. Furthermore, the enhanced oxidation that occurred in the ethanol pre-treated soil resulted in the accumulation of oxidation products. For example, 1-indanone, anthracene-9,10-dione, 1-methylanthracenedione, 2-methylanthracenedione, 1,8-naphthalic anhydride, benz[a]anthracene-7,12-dione and two compounds tentatively identified as hydroxy-9-fluorenones were found at higher concentrations after the treatment than before it. The accumulation was most evident for the quinones, and in many cases it could be attributed to extensive oxidation of their parent PAHs, although the total oxidation efficiency in this study was relatively poor. PMID:16735053

  8. Pyrite nanoparticles as a Fenton-like reagent for in situ remediation of organic pollutants.

    PubMed

    Gil-Lozano, Carolina; Losa-Adams, Elisabeth; F-Dávila, Alfonso; Gago-Duport, Luis

    2014-01-01

    The Fenton reaction is the most widely used advanced oxidation process (AOP) for wastewater treatment. This study reports on the use of pyrite nanoparticles and microparticles as Fenton reagents for the oxidative degradation of copper phthalocyanine (CuPc) as a representative contaminant. Upon oxidative dissolution in water, pyrite (FeS2) particles can generate H2O2 at their surface while simultaneously promoting recycling of Fe(3+) into Fe(2+) and vice versa. Pyrite nanoparticles were synthesized by the hot injection method. The use of a high concentration of precursors gave individual nanoparticles (diameter: 20 nm) with broader crystallinity at the outer interfaces, providing a greater number of surface defects, which is advantageous for generating H2O2. Batch reactions were run to monitor the kinetics of CuPc degradation in real time and the amount of H2O2. A markedly greater degradation of CuPc was achieved with nanoparticles as compared to microparticles: at low loadings (0.08 mg/L) and 20 h reaction time, the former enabled 60% CuPc removal, whereas the latter enabled only 7% removal. These results confirm that the use of low concentrations of synthetic nanoparticles can be a cost effective alternative to conventional Fenton procedures for use in wastewater treatment, avoiding the potential risks caused by the release of heavy metals upon dissolution of natural pyrites.

  9. Improving degradation of paracetamol by integrating gamma radiation and Fenton processes.

    PubMed

    Cruz-González, Germán; Rivas-Ortiz, Iram B; González-Labrada, Katia; Rapado-Paneque, Manuel; Chávez-Ardanza, Armando; Nuevas-Paz, Lauro; Jáuregui-Haza, Ulises J

    2016-10-14

    Degradation of paracetamol (N-(4-hydroxiphenyl)acetamide) in aqueous solution by gamma radiation, gamma radiation/H2O2 and gamma radiation/Fenton processes was studied. Parameters affecting the radiolysis of paracetamol such as radiation dose, initial concentration of pollutant, pH and initial oxidant concentration were investigated. Gamma radiation was performed using a (60)Co source irradiator. Paracetamol degradation and mineralization increased with increasing absorbed radiation dose, but decreased with increasing initial concentration of the drug in aqueous solution. The addition of H2O2 resulted in an increased effect on irradiation-driven paracetamol degradation in comparison with the performance of the irradiation-driven process alone: paracetamol removal increased from 48.9% in the absence of H2O2 to 95.2% for H2O2 concentration of 41.7 mmol/L. However, the best results were obtained with gamma radiation/Fenton process with 100% of the drug removal at 5 kGy, for optimal H2O2 and Fe(2+) concentrations at 13.9 and 2.3 mmol/L, respectively, with a high mineralization of 63.7%. These results suggest gamma radiation/H2O2 and gamma radiation/Fenton processes as promising methods for paracetamol degradation in polluted wastewaters.

  10. Combined photo-fenton-SBR processes for the treatment of wastewater from the citrus processing industry.

    PubMed

    Guzmán, José; Mosteo, Rosa; Ormad, María P; Ovelleiro, José L

    2015-01-21

    In this study, the photo-Fenton process was combined with a sequencing batch reactor (SBR) for the treatment of synthetic samples of citrus wastewater (CWW). An experimental design based on the surface response methodology was applied to assess the individual and combined effects of several operating parameters (CODinitial, Fe3(+) concentration and H2O2 concentration) on the photo-Fenton treatment efficiency (DOC removal) with the aim of optimizing the process. The experimental results obtained under optimal conditions for CWW with high CODinitial (10000 mgO2/L) showed a partial degradation of organic matter of around of 61% (measured as DOC). Thereafter, the photo-Fenton effluent was neutralized and clarified before being subjected to the SBR reactor. The results show degradation yields up to 93% of the initial DOC removal without producing undesired side effects, using a hydraulic retention time (HRT) of 1.59 d. The final effluent contained a concentration of organic matter (measured as COD) of 120 mg O2/L.

  11. Combined treatment of olive mill wastewater by Fenton's reagent and anaerobic biological process.

    PubMed

    Amor, Carlos; Lucas, Marco S; García, Juan; Dominguez, Joaquín R; De Heredia, J Beltrán; Peres, José A

    2015-01-01

    This work presents the application of Fenton's reagent process combined with anaerobic digestion to treat an olive mill wastewater (OMW). Firstly, OMW was pre-treated by chemical oxidation in a batch reactor with Fenton's reagent, using a fixed H2O2/COD ratio of 0.20, pH = 3.5 and a H2O2/Fe(2+) molar ratio of 15:1. This advanced oxidation treatment allowed reaching reductions of 17.6 and 82.5% of chemical oxygen demand (COD) and total polyphenols (TP), respectively. Secondly, OMW treatment by anaerobic digestion was performed using previously adapted microorganisms immobilized in Sepiolite. These biological tests were carried out varying the substrate concentration supplied to the reactor and COD conversions from 52 to 74% were obtained. Afterwards, Fenton's reagent followed by anaerobic digestion was applied to OMW treatment. This combined process presented a significant improvement on organic load removal, reaching COD degradations from 64 to 88%. Beyond the pollutant load removal, it was also monitored the yield of methane generated throughout anaerobic experiments. The methane produced ranged from 281 cm(3) to 322 cm(3) of CH4/g COD removed. Additionally, a methane generation kinetic study was performed using the Monod Model. The application of this model allowed observing a kinetic constant increase of the combined process (kFN = 0.036 h(-1)) when compared to the single anaerobic process (kF = 0.017 h(-1)).

  12. Ultrasonic application to boost hydroxyl radical formation during Fenton oxidation and release organic matter from sludge

    PubMed Central

    Gong, Changxiu; Jiang, Jianguo; Li, De’an; Tian, Sicong

    2015-01-01

    We examined the effects of ultrasound and Fenton reagent on ultrasonic coupling Fenton oxidation (U+F) pre-treatment processes for the disintegration of wastewater treatment plant sludge. The results demonstrated that U+F treatment could significantly increase soluble chemical oxygen demand (SCOD), total organic carbon (TOC), and extracellular polymeric substances (EPS) concentrations in sludge supernatant. This method was more effective than ultrasonic (U) or Fenton oxidation (F) treatment alone. U+F treatment increased the release of SCOD by 2.1- and 1.4-fold compared with U and F alone, respectively. U+F treatment increased the release of EPS by 1.2-fold compared with U alone. After U+F treatment, sludge showed a considerably finer particle size and looser microstructure based on fluorescence microscopy, and the concentration of hydroxyl radicals (OH•) increased from 0.26 mM by F treatment to 0.43 mM by U+F treatment based on fluorescence spectrophotometer. This demonstrated that U+F treatment improves the release of organic matter from sludge. PMID:26066562

  13. Combined photo-fenton-SBR processes for the treatment of wastewater from the citrus processing industry.

    PubMed

    Guzmán, José; Mosteo, Rosa; Ormad, María P; Ovelleiro, José L

    2015-01-21

    In this study, the photo-Fenton process was combined with a sequencing batch reactor (SBR) for the treatment of synthetic samples of citrus wastewater (CWW). An experimental design based on the surface response methodology was applied to assess the individual and combined effects of several operating parameters (CODinitial, Fe3(+) concentration and H2O2 concentration) on the photo-Fenton treatment efficiency (DOC removal) with the aim of optimizing the process. The experimental results obtained under optimal conditions for CWW with high CODinitial (10000 mgO2/L) showed a partial degradation of organic matter of around of 61% (measured as DOC). Thereafter, the photo-Fenton effluent was neutralized and clarified before being subjected to the SBR reactor. The results show degradation yields up to 93% of the initial DOC removal without producing undesired side effects, using a hydraulic retention time (HRT) of 1.59 d. The final effluent contained a concentration of organic matter (measured as COD) of 120 mg O2/L. PMID:25531123

  14. Ultrasonic application to boost hydroxyl radical formation during Fenton oxidation and release organic matter from sludge

    NASA Astrophysics Data System (ADS)

    Gong, Changxiu; Jiang, Jianguo; Li, De'An; Tian, Sicong

    2015-06-01

    We examined the effects of ultrasound and Fenton reagent on ultrasonic coupling Fenton oxidation (U+F) pre-treatment processes for the disintegration of wastewater treatment plant sludge. The results demonstrated that U+F treatment could significantly increase soluble chemical oxygen demand (SCOD), total organic carbon (TOC), and extracellular polymeric substances (EPS) concentrations in sludge supernatant. This method was more effective than ultrasonic (U) or Fenton oxidation (F) treatment alone. U+F treatment increased the release of SCOD by 2.1- and 1.4-fold compared with U and F alone, respectively. U+F treatment increased the release of EPS by 1.2-fold compared with U alone. After U+F treatment, sludge showed a considerably finer particle size and looser microstructure based on fluorescence microscopy, and the concentration of hydroxyl radicals (OH•) increased from 0.26 mM by F treatment to 0.43 mM by U+F treatment based on fluorescence spectrophotometer. This demonstrated that U+F treatment improves the release of organic matter from sludge.

  15. Sulfonamide antibiotic reduction in aquatic environment by application of fenton oxidation process

    PubMed Central

    2013-01-01

    Presence of antibiotics in the environment may cause potential risk for aquatic environment and organisms. In this research, Fenton oxidation process was offered as an effective method for removal of antibiotic sulfamethoxazole from aqueous solutions. The experiments were performed on laboratory-scale study under complete mixing at 25±2°C. The effects of initial antibiotic concentration, molar ratio of H2O2/Fe+2, solution pH, concentration of H2O2, Fe+2 and reaction time was studied on the oxidation of sulfamethoxazole in three level. The results indicated that the optimal parameters for Fenton process were as follows: molar ratio of [H2O2]/[Fe+2] = 1.5, pH= 4.5, and contact time= 15 min. In this situation, the antibiotic removal and COD reduction were achieved 99.99% and 64.7-70.67%, respectively. Although, Fenton reaction could effectively degrade antibiotic sulfamethoxazole under optimum experimental conditions, however, the rate of mineralization was not completed. This process can be considered to eliminate other refractory antibiotics with similar structure or to increase their biodegradability. PMID:23570238

  16. Arsenite oxidation and removal driven by a bio-electro-Fenton process under neutral pH conditions.

    PubMed

    Wang, Xiang-Qin; Liu, Chuan-Ping; Yuan, Yong; Li, Fang-bai

    2014-06-30

    The iron-catalyzed oxidation of arsenite (As(III)) associated with Fenton or Fenton-like reactions is one of the most efficient arsenic removal methods. However, the conventional chemical or electro-Fenton systems for the oxidation of As(III) are only efficient under acid conditions. In the present study, a cost-effective and efficient bio-electro-Fenton process was performed for As(III) oxidation in a dual-chamber microbial fuel cell (MFC) under neutral pH conditions. In such a system, the Fenton reagents, including H2O2 and Fe(II), were generated in situ by microbial-driven electro-reduction of O2 and γ-FeOOH, respectively, without an electricity supply. The results indicated that the process was capable of inducing As(III) oxidation with an apparent As(III) depletion first-order rate constant of 0.208 h(-1). The apparent oxidation current efficiency was calculated to be as high as 73.1%. The γ-FeOOH dosage in the cathode was an important factor in determining the system performance. Fourier-transform infrared spectroscopy (FT-IR) analysis indicated that As(V) was bound to the solid surface as a surface complex but not as a precipitated solid phase. The mechanism of bio-E-Fenton reaction for As(III) oxidation was also proposed. The bio-electro-Fenton system makes it potentially attractive method for the detoxification of As(III) from aqueous solution. PMID:24857903

  17. 123. Dennis Hill, Photographer January 1998 VIEW OF UPPER DECK ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    123. Dennis Hill, Photographer January 1998 VIEW OF UPPER DECK OFF-RAMP DESCENDING TO FREMONT STREET, WITH TRANSBAY TERMINAL BUS LOOP BEHIND, FACING NORTH. - San Francisco Oakland Bay Bridge, Spanning San Francisco Bay, San Francisco, San Francisco County, CA

  18. EXTERIOR, A view looking northwest from far hill toward the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    EXTERIOR, A view looking northwest from far hill toward the Mounds complex and the HH Building - Department of Energy, Mound Facility, Hydrolysis House Building (HH Building), One Mound Road, Miamisburg, Montgomery County, OH

  19. Directional Site Amplification Effect on Tarzana Hill, California

    NASA Astrophysics Data System (ADS)

    Graizer, V.; Shakal, A.

    2003-12-01

    Significantly amplified ground accelerations at the Tarzana Hill station were recorded during the 1987 Mw 5.9 Whittier Narrows and the 1994 Mw 6.7 Northridge earthquakes. Peak horizontal ground acceleration at the Tarzana station during the 1999 Mw 7.1 Hector Mine earthquake was almost twice as large as the accelerations recorded at nearby stations. The Tarzana site was drilled to a depth of 100 m. A low shear-wave velocity near the surface of 100 m/sec increasing to near 750 m/sec at 100 m depth was measured. The 20 m high hill was found to be well drained with a water table near 17 m. Modelo formation (extremely weathered at the surface to fresh at depth) underlies the hill. The subsurface geology and velocities obtained allow classification of this location as a soft-rock site. After the Northridge earthquake the California Strong Motion Instrumentation Program significantly increased instrumentation at Tarzana to study the unusual site amplification effect. Current instrumentation at Tarzana consists of an accelerograph at the top of Tarzana hill (Tarzana - Cedar Hill B), a downhole instrument at 60 m depth, and an accelerograph at the foot of the hill (Tarzana - Clubhouse), 180 m from the Cedar Hill B station. The original station, Tarzana - Cedar Hill Nursery A, was lost in 1999 due to construction. More than twenty events, including the Hector Mine earthquake, were recorded by all these instruments at Tarzana. Comparison of recordings and response spectra demonstrates strong directional resonance on the top of the hill in a direction perpendicular to the strike of the hill in the period range from 0.04 to 0.8 sec (1.2 to 25 Hz). There is practically no amplification from the bottom to the top of the hill for the component parallel to the strike of the hill. In contrast to accelerations recorded during the Hector Mine earthquake (high frequency part of seismic signal), displacements (relatively low frequency part of seismic signal) demonstrate almost no site

  20. 12. Historic American Buildings Survey Joseph Hill, Photographer July 10, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    12. Historic American Buildings Survey Joseph Hill, Photographer July 10, 1936 SOUTH ELEVATION (Copied from student's drawing, Dept. of Architecture, Armour Institute of Technology. Chicago) - Keating House, U.S. Highway 430, Fayville, Alexander County, IL