Science.gov

Sample records for flammable gas upgrades

  1. Fixed target flammable gas upgrades

    SciTech Connect

    Schmitt, R.; Squires, B.; Gasteyer, T.; Richardson, R.

    1996-12-01

    In the past, fixed target flammable gas systems were not supported in an organized fashion. The Research Division, Mechanical Support Department began to support these gas systems for the 1995 run. This technical memo describes the new approach being used to supply chamber gasses to fixed target experiments at Fermilab. It describes the engineering design features, system safety, system documentation and performance results. Gas mixtures provide the medium for electron detection in proportional and drift chambers. Usually a mixture of a noble gas and a polyatomic quenching gas is used. Sometimes a small amount of electronegative gas is added as well. The mixture required is a function of the specific chamber design, including working voltage, gain requirements, high rate capability, aging and others. For the 1995 fixed target run all the experiments requested once through gas systems. We obtained a summary of problems from the 1990 fixed target run and made a summary of the operations logbook entries from the 1991 run. These summaries primarily include problems involving flammable gas alarms, but also include incidents where Operations was involved or informed. Usually contamination issues were dealt with by the experimenters. The summaries are attached. We discussed past operational issues with the experimenters involved. There were numerous incidents of drift chamber failure where contaminated gas was suspect. However analyses of the gas at the time usually did not show any particular problems. This could have been because the analysis did not look for the troublesome component, the contaminant was concentrated in the gas over the liquid and vented before the sample was taken, or that contaminants were drawn into the chambers directly through leaks or sub-atmospheric pressures. After some study we were unable to determine specific causes of past contamination problems, although in argon-ethane systems the problems were due to the ethane only.

  2. Methodology for flammable gas evaluations

    SciTech Connect

    Hopkins, J.D., Westinghouse Hanford

    1996-06-12

    There are 177 radioactive waste storage tanks at the Hanford Site. The waste generates flammable gases. The waste releases gas continuously, but in some tanks the waste has shown a tendency to trap these flammable gases. When enough gas is trapped in a tank`s waste matrix, it may be released in a way that renders part or all of the tank atmosphere flammable for a period of time. Tanks must be evaluated against previously defined criteria to determine whether they can present a flammable gas hazard. This document presents the methodology for evaluating tanks in two areas of concern in the tank headspace:steady-state flammable-gas concentration resulting from continuous release, and concentration resulting from an episodic gas release.

  3. Flammable gas project topical report

    SciTech Connect

    Johnson, G.D.

    1997-01-29

    The flammable gas safety issue was recognized in 1990 with the declaration of an unreviewed safety question (USQ) by the U. S. Department of Energy as a result of the behavior of the Hanford Site high-level waste tank 241-SY-101. This tank exhibited episodic releases of flammable gas that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years there has been a considerable amount of knowledge gained about the chemical and physical processes that govern the behavior of tank 241-SY-1 01 and other tanks associated with the flammable gas safety issue. This report was prepared to provide an overview of that knowledge and to provide a description of the key information still needed to resolve the issue. Items covered by this report include summaries of the understanding of gas generation, retention and release mechanisms, the composition and flammability behavior of the gas mixture, the amounts of stored gas, and estimated gas release fractions for spontaneous releases. `Me report also discusses methods being developed for evaluating the 177 tanks at the Hanford Site and the problems associated with these methods. Means for measuring the gases emitted from the waste are described along with laboratory experiments designed to gain more information regarding rates of generation, species of gases emitted and modes of gas storage and release. Finally, the process for closing the USQ is outlined as are the information requirements to understand and resolve the flammable gas issue.

  4. Flammable gas program topical report

    SciTech Connect

    Johnson, G.D.

    1996-10-30

    The major emphasis of this report is to describe what has been learned about the generation, retention, and release of flammable gas mixtures in high-level waste tanks. A brief overview of efforts to characterize the gas composition will be provided. The report also discusses what needs to be learned about the phenomena, how the Unreviewed Safety Question will be closed, and the approach for removing tanks from the Watch List.

  5. Flammable Gas Safety Self-Study 52827

    SciTech Connect

    Glass, George

    2016-03-17

    This course, Flammable Gas Safety Self-Study (COURSE 52827), presents an overview of the hazards and controls associated with commonly used, compressed flammable gases at Los Alamos National Laboratory (LANL).

  6. 49 CFR 172.417 - FLAMMABLE GAS label.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false FLAMMABLE GAS label. 172.417 Section 172.417... SECURITY PLANS Labeling § 172.417 FLAMMABLE GAS label. (a) Except for size and color, the FLAMMABLE GAS... on the FLAMMABLE GAS label must be red. ...

  7. 49 CFR 172.532 - FLAMMABLE GAS placard.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false FLAMMABLE GAS placard. 172.532 Section 172.532... SECURITY PLANS Placarding § 172.532 FLAMMABLE GAS placard. (a) Except for size and color, the FLAMMABLE GAS... on the FLAMMABLE GAS placard must be red. The symbol, text, class number and inner border must be...

  8. 49 CFR 172.532 - FLAMMABLE GAS placard.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false FLAMMABLE GAS placard. 172.532 Section 172.532... SECURITY PLANS Placarding § 172.532 FLAMMABLE GAS placard. (a) Except for size and color, the FLAMMABLE GAS... on the FLAMMABLE GAS placard must be red. The symbol, text, class number and inner border must be...

  9. 49 CFR 172.532 - FLAMMABLE GAS placard.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false FLAMMABLE GAS placard. 172.532 Section 172.532... SECURITY PLANS Placarding § 172.532 FLAMMABLE GAS placard. (a) Except for size and color, the FLAMMABLE GAS... on the FLAMMABLE GAS placard must be red. The symbol, text, class number and inner border must be...

  10. 49 CFR 172.417 - FLAMMABLE GAS label.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false FLAMMABLE GAS label. 172.417 Section 172.417... SECURITY PLANS Labeling § 172.417 FLAMMABLE GAS label. (a) Except for size and color, the FLAMMABLE GAS... on the FLAMMABLE GAS label must be red. ...

  11. 49 CFR 172.417 - FLAMMABLE GAS label.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false FLAMMABLE GAS label. 172.417 Section 172.417... SECURITY PLANS Labeling § 172.417 FLAMMABLE GAS label. (a) Except for size and color, the FLAMMABLE GAS... on the FLAMMABLE GAS label must be red. ...

  12. 49 CFR 172.532 - FLAMMABLE GAS placard.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false FLAMMABLE GAS placard. 172.532 Section 172.532... SECURITY PLANS Placarding § 172.532 FLAMMABLE GAS placard. (a) Except for size and color, the FLAMMABLE GAS... on the FLAMMABLE GAS placard must be red. The symbol, text, class number and inner border must...

  13. 49 CFR 172.417 - FLAMMABLE GAS label.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false FLAMMABLE GAS label. 172.417 Section 172.417... SECURITY PLANS Labeling § 172.417 FLAMMABLE GAS label. (a) Except for size and color, the FLAMMABLE GAS... on the FLAMMABLE GAS label must be red....

  14. 46 CFR 188.10-43 - Liquefied flammable gas.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 7 2012-10-01 2012-10-01 false Liquefied flammable gas. 188.10-43 Section 188.10-43... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-43 Liquefied flammable gas. This term means any flammable gas having a Reid vapor pressure exceeding 40 p.s.i. which has been liquefied. ...

  15. 46 CFR 188.10-43 - Liquefied flammable gas.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 7 2011-10-01 2011-10-01 false Liquefied flammable gas. 188.10-43 Section 188.10-43... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-43 Liquefied flammable gas. This term means any flammable gas having a Reid vapor pressure exceeding 40 p.s.i. which has been liquefied. ...

  16. 46 CFR 188.10-43 - Liquefied flammable gas.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 7 2014-10-01 2014-10-01 false Liquefied flammable gas. 188.10-43 Section 188.10-43... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-43 Liquefied flammable gas. This term means any flammable gas having a Reid vapor pressure exceeding 40 p.s.i. which has been liquefied. ...

  17. 46 CFR 154.1350 - Flammable gas detection system.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Flammable gas detection system. 154.1350 Section 154... Equipment Instrumentation § 154.1350 Flammable gas detection system. (a) The vessel must have a fixed flammable gas detection system that has sampling points in: (1) Each cargo pump room; (2) Each cargo...

  18. The Chemistry of Flammable Gas Generation

    SciTech Connect

    ZACH, J.J.

    2000-10-30

    The document collects information from field instrumentation, laboratory tests, and analytical models to provide a single source of information on the chemistry of flammable gas generation at the Hanford Site. It considers the 3 mechanisms of formation: radiolysis, chemical reactions, and thermal generation. An assessment of the current models for gas generation is then performed. The results are that the various phenomena are reasonably understood and modeled compared to field data.

  19. 49 CFR 172.415 - NON-FLAMMABLE GAS label.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.415 NON-FLAMMABLE GAS label. (a) Except for size and color, the NON-FLAMMABLE... color on the NON-FLAMMABLE GAS label must be green....

  20. Flammable gas interlock spoolpiece flow response test plan and procedure

    SciTech Connect

    Schneider, T.C., Fluor Daniel Hanford

    1997-02-13

    The purpose of this test plan and procedure is to test the Whittaker electrochemical cell and the Sierra Monitor Corp. flammable gas monitors in a simulated field flow configuration. The sensors are used on the Rotary Mode Core Sampling (RMCS) Flammable Gas Interlock (FGI), to detect flammable gases, including hydrogen and teminate the core sampling activity at a predetermined concentration level.

  1. Flammable gas data evaluation. Progress report

    SciTech Connect

    Whitney, P.D.; Meyer, P.A.; Miller, N.E.

    1996-10-01

    The Hanford Site is home to 177 large, underground nuclear waste storage tanks. Numerous safety and environmental concerns surround these tanks and their contents. One such concern is the propensity for the waste in these tanks to generate, retain, and periodically release flammable gases. This report documents some of the activities of the Flammable Gas Project Data Evaluation Task conducted for Westinghouse Hanford Company during fiscal year 1996. Described in this report are: (1) the results of examining the in-tank temperature measurements for insights into gas release behavior; (2) the preliminary results of examining the tank waste level measurements for insights into gas release behavior; and (3) an explanation for the observed hysteresis in the level/pressure measurements, a phenomenon observed earlier this year when high-frequency tank waste level measurements came on-line.

  2. Flammable Gas Detection for the D-Zero Gas System

    SciTech Connect

    Spires, L.D.; Foglesong, J.; /Fermilab

    1991-02-11

    The use of flammable gas and high voltage in detector systems is common in many experiments at Fermilab. To mitigate the hazards associated with these systems, Fermilab Engineering Standard SD-45B (Ref. 1) was adopted. Since this note is meant to be a guide and not a mandatory standard, each experiment is reviewed for compliance with SD-45B by the flammable gas safety subcommittee. Currently, there are only two types of flammable gas in use, ethane (Appendix A) and methane (Appendix B). The worst flammable-gas case is C2H6 (ethane), which has an estimated flow rate that is 73% of the CH4 (methane) flow but a heat of combustion (in kcal/g-mole) that is 173% of that of methane. In the worst case, if ethane were to spew through its restricting orifice into its gas line at 0 psig and then through a catastrophic leak into Room 215 (TRD) or Room 511 (CDC/FDCNTX), the time that would be required to build up a greater than Class 1 inventory (0.4kg H2 equivalent) would be 5.2 hours (Ref. 2). Therefore a worst-case flammable gas leak would have to go undetected for over 5 hours in order to transform a either mixing room to an environment with a Risk Class greater than Class 1. The mixing systems, gas lines, and detectors themselves will be thoroughly leak checked prior to active service. All vessels that are part of the mixing systems will be protected from overpressure by safety valves vented outside the building. Both the input and output of all detector volumes are protected from overpressure in the same way. The volume immediately outside the central tracking detectors is continuously purged by nitrogen from boiloff from the main nitrogen dewar at the site. However, if flammable gas were to build up in the mixing rooms or particular detector areas, no matter how unlikely, flammable gas detectors that are part of the interlock chain of each gas mixing system will shut down the appropriate system. This includes shutting off the output of flammable gas manifolds within the

  3. 49 CFR 172.528 - NON-FLAMMABLE GAS placard.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false NON-FLAMMABLE GAS placard. 172.528 Section 172.528... SECURITY PLANS Placarding § 172.528 NON-FLAMMABLE GAS placard. (a) Except for size and color, the NON-FLAMMABLE GAS placard must be as follows: EC02MR91.045 (b) In addition to complying with § 172.519, the...

  4. 49 CFR 172.415 - NON-FLAMMABLE GAS label.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false NON-FLAMMABLE GAS label. 172.415 Section 172.415... SECURITY PLANS Labeling § 172.415 NON-FLAMMABLE GAS label. (a) Except for size and color, the NON-FLAMMABLE GAS label must be as follows: EC02MR91.020 (b) In addition to complying with § 172.407, the background...

  5. 49 CFR 172.528 - NON-FLAMMABLE GAS placard.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false NON-FLAMMABLE GAS placard. 172.528 Section 172.528... SECURITY PLANS Placarding § 172.528 NON-FLAMMABLE GAS placard. (a) Except for size and color, the NON-FLAMMABLE GAS placard must be as follows: EC02MR91.045 (b) In addition to complying with § 172.519, the...

  6. 49 CFR 172.415 - NON-FLAMMABLE GAS label.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false NON-FLAMMABLE GAS label. 172.415 Section 172.415... SECURITY PLANS Labeling § 172.415 NON-FLAMMABLE GAS label. (a) Except for size and color, the NON-FLAMMABLE GAS label must be as follows: EC02MR91.020 (b) In addition to complying with § 172.407, the background...

  7. 49 CFR 172.415 - NON-FLAMMABLE GAS label.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false NON-FLAMMABLE GAS label. 172.415 Section 172.415... SECURITY PLANS Labeling § 172.415 NON-FLAMMABLE GAS label. (a) Except for size and color, the NON-FLAMMABLE GAS label must be as follows: EC02MR91.020 (b) In addition to complying with § 172.407, the background...

  8. 49 CFR 172.528 - NON-FLAMMABLE GAS placard.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false NON-FLAMMABLE GAS placard. 172.528 Section 172.528... SECURITY PLANS Placarding § 172.528 NON-FLAMMABLE GAS placard. (a) Except for size and color, the NON-FLAMMABLE GAS placard must be as follows: EC02MR91.045 (b) In addition to complying with § 172.519, the...

  9. 49 CFR 172.528 - NON-FLAMMABLE GAS placard.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false NON-FLAMMABLE GAS placard. 172.528 Section 172.528... SECURITY PLANS Placarding § 172.528 NON-FLAMMABLE GAS placard. (a) Except for size and color, the NON-FLAMMABLE GAS placard must be as follows: EC02MR91.045 (b) In addition to complying with § 172.519,...

  10. 49 CFR 172.415 - NON-FLAMMABLE GAS label.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false NON-FLAMMABLE GAS label. 172.415 Section 172.415... SECURITY PLANS Labeling § 172.415 NON-FLAMMABLE GAS label. (a) Except for size and color, the NON-FLAMMABLE GAS label must be as follows: EC02MR91.020 (b) In addition to complying with § 172.407, the...

  11. 46 CFR 148.420 - Flammable gas analyzers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Flammable gas analyzers. 148.420 Section 148.420... MATERIALS THAT REQUIRE SPECIAL HANDLING Additional Special Requirements § 148.420 Flammable gas analyzers..., each vessel transporting the material, other than an unmanned barge, must have on board a gas analyzer...

  12. 46 CFR 148.420 - Flammable gas analyzers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Flammable gas analyzers. 148.420 Section 148.420... MATERIALS THAT REQUIRE SPECIAL HANDLING Additional Special Requirements § 148.420 Flammable gas analyzers..., each vessel transporting the material, other than an unmanned barge, must have on board a gas analyzer...

  13. 46 CFR 148.420 - Flammable gas analyzers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Flammable gas analyzers. 148.420 Section 148.420... MATERIALS THAT REQUIRE SPECIAL HANDLING Additional Special Requirements § 148.420 Flammable gas analyzers..., each vessel transporting the material, other than an unmanned barge, must have on board a gas analyzer...

  14. 46 CFR 154.1350 - Flammable gas detection system.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Equipment Instrumentation § 154.1350 Flammable gas detection system. (a) The vessel must have a fixed... gas-safe; (5) Each hold space, interbarrier space, and other enclosed spaces, except fuel oil or... 46 Shipping 5 2011-10-01 2011-10-01 false Flammable gas detection system. 154.1350 Section...

  15. 46 CFR 154.1350 - Flammable gas detection system.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Equipment Instrumentation § 154.1350 Flammable gas detection system. (a) The vessel must have a fixed... gas-safe; (5) Each hold space, interbarrier space, and other enclosed spaces, except fuel oil or... 46 Shipping 5 2014-10-01 2014-10-01 false Flammable gas detection system. 154.1350 Section...

  16. 46 CFR 154.1350 - Flammable gas detection system.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Equipment Instrumentation § 154.1350 Flammable gas detection system. (a) The vessel must have a fixed... gas-safe; (5) Each hold space, interbarrier space, and other enclosed spaces, except fuel oil or... 46 Shipping 5 2013-10-01 2013-10-01 false Flammable gas detection system. 154.1350 Section...

  17. Retained Gas Sampling Results for the Flammable Gas Program

    SciTech Connect

    J.M. Bates; L.A. Mahoney; M.E. Dahl; Z.I. Antoniak

    1999-11-18

    The key phenomena of the Flammable Gas Safety Issue are generation of the gas mixture, the modes of gas retention, and the mechanisms causing release of the gas. An understanding of the mechanisms of these processes is required for final resolution of the safety issue. Central to understanding is gathering information from such sources as historical records, tank sampling data, tank process data (temperatures, ventilation rates, etc.), and laboratory evaluations conducted on tank waste samples.

  18. 49 CFR 172.528 - NON-FLAMMABLE GAS placard.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.528 NON-FLAMMABLE GAS placard. (a) Except for size and color, the NON... background color on the NON-FLAMMABLE GAS placard must be green. The letters in both words must be at...

  19. 49 CFR 172.417 - FLAMMABLE GAS label.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.417 FLAMMABLE GAS label. (a) Except for size and color, the FLAMMABLE GAS label must be as follows: EC02MR91.022 (b) In addition to complying with § 172.407, the background...

  20. 49 CFR 172.532 - FLAMMABLE GAS placard.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.532 FLAMMABLE GAS placard. (a) Except for size and color, the FLAMMABLE GAS placard must be as follows: EC02MR91.047 (b) In addition to complying with § 172.519, the background...

  1. Strategy for resolution of the flammable gas safety issue

    SciTech Connect

    Johnson, G.D.

    1997-05-23

    This document provides a strategy for resolution of the Flammable Gas Safety Issue. It defines the key elements required for the following: Closing the Flammable Gas Unreviewed Safety Question (USQ); Providing the administrative basis for resolving the safety issue; Defining the data needed to support these activities; and Providing the technical and administrative path for removing tanks from the Watch List.

  2. STEADY-STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    HU TA

    2007-10-26

    Assess the steady-state flammability level at normal and off-normal ventilation conditions. The methodology of flammability analysis for Hanford tank waste is developed. The hydrogen generation rate model was applied to calculate the gas generation rate for 177 tanks. Flammability concentrations and the time to reach 25% and 100% of the lower flammability limit, and the minimum ventilation rate to keep from 100 of the LFL are calculated for 177 tanks at various scenarios.

  3. Assessment of gas flammability in transuranic waste container

    SciTech Connect

    Connolly, M.J.; Loehr, C.A.; Djordjevic, S.M.; Spangler, L.R.

    1995-12-01

    The Safety Analysis Report for the TRUPACT-II Shipping Package [Transuranic Package Transporter-II (TRUPACT-II) SARP] set limits for gas generation rates, wattage limits, and flammable volatile organic compound (VOC) concentrations in transuranic (TRU) waste containers that would be shipped to the Waste Isolation Pilot Plant (WIPP). Based on existing headspace gas data for drums stored at the Idaho National Engineering Laboratory (INEL) and the Rocky Flats Environmental Technology Site (RFETS), over 30 percent of the contact-handled TRU waste drums contain flammable VOC concentrations greater than the limit. Additional requirements may be imposed for emplacement of waste in the WIPP facility. The conditional no-migration determination (NMD) for the test phase of the facility required that flame tests be performed if significant levels of flammable VOCs were present in TRU waste containers. This paper describes an approach for investigating the potential flammability of TRU waste drums, which would increase the allowable concentrations of flammable VOCS. A flammability assessment methodology is presented that will allow more drums to be shipped to WIPP without treatment or repackaging and reduce the need for flame testing on drums. The approach includes experimental work to determine mixture lower explosive limits (MLEL) for the types of gas mixtures observed in TRU waste, a model for predicting the MLEL for mixtures of VOCS, hydrogen, and methane, and revised screening limits for total flammable VOCs concentrations and concentrations of hydrogen and methane using existing drum headspace gas data and the model predictions.

  4. 77 FR 62224 - Hanford Tank Farms Flammable Gas Safety Strategy

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-12

    ... identified that the safety analyses for accident scenarios used non-bounding values for (1) the radiological... flammable gas releases in DSTs and the challenges they pose to any ventilation system are...

  5. FLAMMABLE GAS DIFFUSION THROUGH SINGLE SHELL TANK (SST) DOMES

    SciTech Connect

    MEACHAM, J.E.

    2003-11-10

    This report quantified potential hydrogen diffusion through Hanford Site Single-Shell tank (SST) domes if the SSTs were hypothetically sealed airtight. Results showed that diffusion would keep headspace flammable gas concentrations below the lower flammability limit in the 241-AX and 241-SX SST. The purpose of this document is to quantify the amount of hydrogen that could diffuse through the domes of the SSTs if they were hypothetically sealed airtight. Diffusion is assumed to be the only mechanism available to reduce flammable gas concentrations. The scope of this report is limited to the 149 SSTs.

  6. Offsite Radiological Consequence Analysis for the Bounding Flammable Gas Accident

    SciTech Connect

    CARRO, C.A.

    2003-07-30

    This document quantifies the offsite radiological consequences of the bounding flammable gas accident for comparison with the 25 rem Evaluation Guideline established in DOE-STD-3009, Appendix A. The bounding flammable gas accident is a detonation in a single-shell tank The calculation applies reasonably conservation input parameters in accordance with DOE-STD-3009, Appendix A, guidance. Revision 1 incorporates comments received from Office of River Protection.

  7. 46 CFR 30.10-39 - Liquefied flammable gas-TB/ALL.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Liquefied flammable gas-TB/ALL. 30.10-39 Section 30.10-39 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY TANK VESSELS GENERAL PROVISIONS Definitions § 30.10-39 Liquefied flammable gas—TB/ALL. The term liquefied flammable gas means any flammable...

  8. 46 CFR 30.10-39 - Liquefied flammable gas-TB/ALL.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 1 2011-10-01 2011-10-01 false Liquefied flammable gas-TB/ALL. 30.10-39 Section 30.10-39 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY TANK VESSELS GENERAL PROVISIONS Definitions § 30.10-39 Liquefied flammable gas—TB/ALL. The term liquefied flammable gas means any flammable...

  9. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    MEACHAM JE

    2008-11-17

    This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for al1 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 13 days for DSTs (i.e., tank 241-AZ-102) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 12 days for DSTs (i.e., tank 241-AZ-102) and 34 days for SSTs (i.e., tank 241-B-203).

  10. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    MEACHAM JE

    2009-10-26

    This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for all 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 11 days for DSTs (i.e., tank 241-AZ-10l) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 10 days for DSTs (i.e., tank 241-AZ-101) and 34 days for SSTs (i.e., tank 241-B-203).

  11. Flammable gas cloud build up in a ventilated enclosure.

    PubMed

    Ivings, M J; Gant, S E; Saunders, C J; Pocock, D J

    2010-12-15

    Ventilation is frequently used as a means for preventing the build up of flammable or toxic gases in enclosed spaces. The effectiveness of the ventilation often has to be considered as part of a safety case or risk assessment. In this paper methods for assessing ventilation effectiveness for hazardous area classification are examined. The analysis uses data produced from Computational Fluid Dynamics (CFD) simulations of low-pressure jet releases of flammable gas in a ventilated enclosure. The CFD model is validated against experimental measurements of gas releases in a ventilation-controlled test chamber. Good agreement is found between the model predictions and the experimental data. Analysis of the CFD results shows that the flammable gas cloud volume resulting from a leak is largely dependent on the mass release rate of flammable gas and the ventilation rate of the enclosure. The effectiveness of the ventilation for preventing the build up of flammable gas can therefore be assessed by considering the average gas concentration at the enclosure outlet(s). It is found that the ventilation rate of the enclosure provides a more useful measure of ventilation effectiveness than considering the enclosure air change rate.

  12. A summary description of the flammable gas tank safety program

    SciTech Connect

    Johnson, G.D.; Sherwood, D.J.

    1994-10-01

    Radioactive liquid waste may produce hydrogen as result of the interaction of gamma radiation and water. If the waste contains organic chelating agents, additional hydrogen as well as nitrous oxide and ammonia may be produced by thermal and radiolytic decomposition of these organics. Several high-level radioactive liquid waste storage tanks, located underground at the Hanford Site in Washington State, are on a Flammable Gas Watch List. Some contain waste that produces and retains gases until large quantities of gas are released rapidly to the tank vapor space. Tanks nearly-filled to capacity have relatively little vapor space; therefore if the waste suddenly releases a large amount of hydrogen and nitrous oxide, a flammable gas mixture could result. The most notable example of a Hanford waste tank with a flammable gas problem is tank 241-SY-101. Upon occasion waste stored in this tank has released enough flammable gas to burn if an ignition source had been present inside of the tank. Several, other Hanford waste tanks exhibit similar behavior although to a lesser magnitude. Because this behavior was hot adequately-addressed in safety analysis reports for the Hanford Tank Farms, an unreviewed safety question was declared, and in 1990 the Flammable Gas Tank Safety Program was established to address this problem. The purposes of the program are a follows: (1) Provide safety documents to fill gaps in the safety analysis reports, and (2) Resolve the safety issue by acquiring knowledge about gas retention and release from radioactive liquid waste and developing mitigation technology. This document provides the general logic and work activities required to resolve the unreviewed safety question and the safety issue of flammable gas mixtures in radioactive liquid waste storage tanks.

  13. 49 CFR 176.230 - Stowage of Division 2.1 (flammable gas) materials.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false Stowage of Division 2.1 (flammable gas) materials... CARRIAGE BY VESSEL Detailed Requirements for Class 2 (Compressed Gas) Materials § 176.230 Stowage of Division 2.1 (flammable gas) materials. Division 2.1 (flammable gas) materials transported in...

  14. 49 CFR 176.230 - Stowage of Division 2.1 (flammable gas) materials.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Stowage of Division 2.1 (flammable gas) materials... CARRIAGE BY VESSEL Detailed Requirements for Class 2 (Compressed Gas) Materials § 176.230 Stowage of Division 2.1 (flammable gas) materials. Division 2.1 (flammable gas) materials transported in...

  15. 49 CFR 176.230 - Stowage of Division 2.1 (flammable gas) materials.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 2 2014-10-01 2014-10-01 false Stowage of Division 2.1 (flammable gas) materials... CARRIAGE BY VESSEL Detailed Requirements for Class 2 (Compressed Gas) Materials § 176.230 Stowage of Division 2.1 (flammable gas) materials. Division 2.1 (flammable gas) materials transported in...

  16. 49 CFR 176.230 - Stowage of Division 2.1 (flammable gas) materials.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false Stowage of Division 2.1 (flammable gas) materials... CARRIAGE BY VESSEL Detailed Requirements for Class 2 (Compressed Gas) Materials § 176.230 Stowage of Division 2.1 (flammable gas) materials. Division 2.1 (flammable gas) materials transported in...

  17. 49 CFR 176.230 - Stowage of Division 2.1 (flammable gas) materials.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false Stowage of Division 2.1 (flammable gas) materials... CARRIAGE BY VESSEL Detailed Requirements for Class 2 (Compressed Gas) Materials § 176.230 Stowage of Division 2.1 (flammable gas) materials. Division 2.1 (flammable gas) materials transported in...

  18. Hazard assessments of double-shell flammable gas tanks

    SciTech Connect

    Fox, G.L.; Stepnewski, D.D.

    1994-09-28

    This report is the fourth in a series of hazard assessments performed on the double-shell flammable gas watch list tanks. This report focuses on hazards associated with the double-shell watch list tanks (101-AW, 103-AN, 104-AN, and 105-AN). While a similar assessment has already been performed for tank 103-SY, it is also included here to incorporate a more representative slurry gas mixture and provide a consistent basis for comparing results for all the flammable gas tanks. This report is intended to provide an in-depth assessment by considering the details of the gas release event and slurry gas mixing as the gas is released from the waste. The consequences of postulated gas ignition are evaluated using a plume burn model and updated ignition frequency predictions. Tank pressurization which results from a gas burn, along with the structural response, is also considered. The report is intended to support the safety basis for work activities in flammable gas tanks by showing margins to safety limits that are available in the design and procedures.

  19. Project W-030 flammable gas verification monitoring test

    SciTech Connect

    BARKER, S.A.

    1999-02-24

    This document describes the verification monitoring campaign used to document the ability of the new ventilation system to mitigate flammable gas accumulation under steady state tank conditions. This document reports the results of the monitoring campaign. The ventilation system configuration, process data, and data analysis are presented.

  20. Control Decisions for Flammable Gas Hazards in Waste Transfer Systems

    SciTech Connect

    KRIPPS, L.J.

    2000-06-28

    This report describes the control decisions for flammable gas hazards in waste transfer systems (i.e., waste transfer piping and waste transfer-associated structures) made at control decision meetings on November 30, 1999a and April 19, 2000, and their basis. These control decisions, and the analyses that support them, will be documented in an amendment to the Final Safety Analysis Report (FSAR) (CHG 2000a) and Technical Safety Requirements (TSR) (CHG 2000b) to close the Flammable Gas Unreviewed Safety Question (USQ) (Bacon 1996 and Wagoner 1996). Following the Contractor Tier I review of the FSAR and TSR amendment, it will be submitted to the US. Department of Energy (DOE), Office of River Protection (ORP) for review and approval. The control decision meeting on November 30, 1999 to address flammable gas hazards in waste transfer systems followed the control decision process and the criteria for control decisions described in Section 3.3.1.5 of the FSAR. The control decision meeting agenda, attendance list, and introductory and background presentations are included in Attachments 1 through 4. The control decision discussions on existing and other possible controls for flammable gas hazards in waste transfer systems and the basis for selecting or not selecting specific controls are summarized in this report.

  1. OFFSITE RADIOLOGICAL CONSEQUENCE ANALYSIS FOR THE BOUNDING FLAMMABLE GAS ACCIDENT

    SciTech Connect

    KRIPPS, L.J.

    2005-02-18

    This document quantifies the offsite radiological consequences of the bounding flammable gas accident for comparison with the 25 rem Evaluation Guideline established in DOE-STD-3009, Appendix A. The bounding flammable gas accident is a detonation in a SST. The calculation applies reasonably conservative input parameters in accordance with guidance in DOE-STD-3009, Appendix A. The purpose of this analysis is to calculate the offsite radiological consequence of the bounding flammable gas accident. DOE-STD-3009-94, ''Preparation Guide for US. Department of Energy Nonreactor Nuclear Facility Documented Safety Analyses'', requires the formal quantification of a limited subset of accidents representing a complete set of bounding conditions. The results of these analyses are then evaluated to determine if they challenge the DOE-STD-3009-94, Appendix A, ''Evaluation Guideline,'' of 25 rem total effective dose equivalent in order to identify and evaluate safety-class structures, systems, and components. The bounding flammable gas accident is a detonation in a single-shell tank (SST). A detonation versus a deflagration was selected for analysis because the faster flame speed of a detonation can potentially result in a larger release of respirable material. A detonation in an SST versus a double-shell tank (DST) was selected as the bounding accident because the estimated respirable release masses are the same and because the doses per unit quantity of waste inhaled are greater for SSTs than for DSTs. Appendix A contains a DST analysis for comparison purposes.

  2. Flammable gas interlock spoolpiece flow response test report

    SciTech Connect

    Schneider, T.C., Fluor Daniel Hanford

    1997-03-24

    The purpose of this test report is to document the testing performed under the guidance of HNF-SD-WM-TC-073, {ital Flammable Gas Interlock Spoolpiece Flow Response Test Plan and Procedure}. This testing was performed for Lockheed Martin Hanford Characterization Projects Operations (CPO) in support of Rotary Mode Core Sampling jointly by SGN Eurisys Services Corporation and Numatec Hanford Company. The testing was conducted in the 305 building Engineering Testing Laboratory (ETL). NHC provides the engineering and technical support for the 305 ETL. The key personnel identified for the performance of this task are as follows: Test responsible engineering manager, C. E. Hanson; Flammable Gas Interlock Design Authority, G. P. Janicek; 305 ETL responsible manager, N. J. Schliebe; Cognizant RMCS exhauster engineer, E. J. Waldo/J. D. Robinson; Cognizant 305 ETL engineer, K. S. Witwer; Test director, T. C. Schneider. Other support personnel were supplied, as necessary, from 305/306 ETL. The testing, on the flammable Gas Interlock (FGI) system spoolpiece required to support Rotary Mode Core Sampling (RMCS) of single shell flammable gas watch list tanks, took place between 2-13-97 and 2-25-97.

  3. 46 CFR 154.1350 - Flammable gas detection system.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Flammable gas detection system. 154.1350 Section 154.1350 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction...

  4. Progress toward mitigation of flammable gas Tank 241-SY-101

    SciTech Connect

    Lentsch, J.W.; Babad, H.; Hanson, C.E.; Kirch, N.W.

    1994-01-01

    The mixing pump installed in Hanford Site tank 241-SY-101 has been shown to be effective in releasing flammable gases in a controlled manner. This controlled release of gas prevents the accumulation and episodic release above flammable limits. More work needs to be done to optimize the pumping operation, and to evaluate the long-term effects of mixing so as to assure that no undesirable changes have occurred to the waste. Other alternative mitigation concepts are still being evaluated as a backup to mixing.

  5. Thermal Flammable Gas Production from Bulk Vitrification Feed

    SciTech Connect

    Scheele, Randall D.; McNamara, Bruce K.; Bagaasen, Larry M.

    2008-05-21

    The baseline bulk-vitrification (BV) process (also known as in-container vitrification ICV™) includes a mixer/dryer to convert liquid low-activity waste (LAW) into a dried, blended feed for vitrification. Feed preparation includes blending LAW with glass-forming minerals (GFMs) and cellulose and drying the mixture to a suitable dryness, consistency, and particle size for transport to the ICVTM container. The cellulose is to be added to the BV feed at a rate sufficient to destroy 75% of the nitrogen present as nitrate or nitrite. Concern exists that flammable gases may be produced during drying operations at levels that could pose a risk. The drying process is conducted under vacuum in the temperature range of 60 to 80°C. These flammable gases could be produced either through thermal decomposition of cellulose or waste organics or as a by-product of the reaction of cellulose and/or waste organics with nitrate or the postulated small amount of nitrite present in the waste. To help address the concern about flammable gas production during drying, the Pacific Northwest National Laboratory (PNNL) performed studies to identify the gases produced at dryer temperatures and at possible process upset conditions. Studies used a thermogravimetric analyzer (TGA) up to 525°C and isothermal testing up to 120°C to determine flammable gas production resulting from the cellulose and organic constituents in bulk vitrification feed. This report provides the results of those studies to determine the effects of cellulose and waste organics on flammable gas evolution

  6. Flammable gas tank safety program: Technical basis for gas analysis and monitoring

    SciTech Connect

    Sherwood, D.J.

    1995-09-08

    Flammable gases generated in radioactive liquids. Twenty-five high level radioactive liquid waste storage tanks located underground at the Hanford Site are on a Flammable Gas Watch List because they contain waste which tends to retain the gases generated in it until rather large quantities are available for sudden release to the tank head space; if a tank is full it has little dome space, and a flammable concentration of gases could be produced--even if the tank is ventilated. If the waste has no tendency to retain gas generated in it then a continual flammable gas concentration in the tank dome space is established by the gas production rate and the tank ventilation rate (or breathing rate for unventilated tanks); this is also a potential problem for Flammable Gas Watch List tanks, and perhaps other Hanford tanks too. All Flammable Gas Watch List tanks will be fitted with Standard Hydorgen Monitoring Systems so that their behavior can be observed. In some cases, such as tank 241-SY-101, the data gathered from such observations will indicate that tank conditions need to be mitigated so that gas release events are either eliminated or rendered harmless. For example, a mixer pump was installed in tank 241-SY-101; operating the pump stirs the waste, replacing the large gas release events with small releases of gas that are kept below twenty-five percent of the lower flammability limit by the ventilation system. The concentration of hydrogen measured in Hanford waste tanks is greater than that of any other flammable gas. Hydrogen levels measured with a Standard Hydrogen Monitoring System in excess of 0.6 volume percent will cause Westinghouse Hanford Company to consider actions which will decrease the amount of flammable gas in the tank

  7. Evaluation of 241 AN tank farm flammable gas behavior

    SciTech Connect

    Reynolds, D.A.

    1994-01-01

    The 241 AN Tank Farm tanks 241-AN-103, -104, and 105 are Flammable Gas Watch List tanks. Characteristics exhibited by these tanks (i.e., surface level drops, pressure increases, and temperature profiles) are similar to those exhibited by tank 241-SY-101, which is also a Watch List tank. Although the characteristics exhibited by tank 241-SY-101 are also present in tanks 241-AN-103, -104, and 105, they are exhibited to a lesser degree in the AN Tank Farm tanks. The 241 AN Tank Farm tanks have only small surface level drops, and the pressure changes that occur are not sufficient to release an amount of gas that would cause the dome space to exceed the lower flammability limit (LFL) for hydrogen. Therefore, additional restrictions are probably unnecessary for working within the 241 AN Tank Farm, either within the dome space of the tanks or in the waste.

  8. A risk-based approach to flammable gas detector spacing.

    PubMed

    Defriend, Stephen; Dejmek, Mark; Porter, Leisa; Deshotels, Bob; Natvig, Bernt

    2008-11-15

    Flammable gas detectors allow an operating company to address leaks before they become serious, by automatically alarming and by initiating isolation and safe venting. Without effective gas detection, there is very limited defense against a flammable gas leak developing into a fire or explosion that could cause loss of life or escalate to cascading failures of nearby vessels, piping, and equipment. While it is commonly recognized that some gas detectors are needed in a process plant containing flammable gas or volatile liquids, there is usually a question of how many are needed. The areas that need protection can be determined by dispersion modeling from potential leak sites. Within the areas that must be protected, the spacing of detectors (or alternatively, number of detectors) should be based on risk. Detector design can be characterized by spacing criteria, which is convenient for design - or alternatively by number of detectors, which is convenient for cost reporting. The factors that influence the risk are site-specific, including process conditions, chemical composition, number of potential leak sites, piping design standards, arrangement of plant equipment and structures, design of isolation and depressurization systems, and frequency of detector testing. Site-specific factors such as those just mentioned affect the size of flammable gas cloud that must be detected (within a specified probability) by the gas detection system. A probability of detection must be specified that gives a design with a tolerable risk of fires and explosions. To determine the optimum spacing of detectors, it is important to consider the probability that a detector will fail at some time and be inoperative until replaced or repaired. A cost-effective approach is based on the combined risk from a representative selection of leakage scenarios, rather than a worst-case evaluation. This means that probability and severity of leak consequences must be evaluated together. In marine and

  9. 46 CFR 111.105-32 - Bulk liquefied flammable gas and ammonia carriers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Bulk liquefied flammable gas and ammonia carriers. 111... gas and ammonia carriers. (a) Each vessel that carries bulk liquefied flammable gases or ammonia as a.... (2) The term “gas-dangerous” does not include the weather deck of an ammonia carrier. (c) Each...

  10. 46 CFR 111.105-32 - Bulk liquefied flammable gas and ammonia carriers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Bulk liquefied flammable gas and ammonia carriers. 111... gas and ammonia carriers. (a) Each vessel that carries bulk liquefied flammable gases or ammonia as a.... (2) The term “gas-dangerous” does not include the weather deck of an ammonia carrier. (c) Each...

  11. 46 CFR 111.105-32 - Bulk liquefied flammable gas and ammonia carriers.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Bulk liquefied flammable gas and ammonia carriers. 111... gas and ammonia carriers. (a) Each vessel that carries bulk liquefied flammable gases or ammonia as a.... (2) The term “gas-dangerous” does not include the weather deck of an ammonia carrier. (c) Each...

  12. 46 CFR 111.105-32 - Bulk liquefied flammable gas and ammonia carriers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Bulk liquefied flammable gas and ammonia carriers. 111... gas and ammonia carriers. (a) Each vessel that carries bulk liquefied flammable gases or ammonia as a.... (2) The term “gas-dangerous” does not include the weather deck of an ammonia carrier. (c) Each...

  13. 46 CFR 111.105-32 - Bulk liquefied flammable gas and ammonia carriers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Bulk liquefied flammable gas and ammonia carriers. 111... gas and ammonia carriers. (a) Each vessel that carries bulk liquefied flammable gases or ammonia as a.... (2) The term “gas-dangerous” does not include the weather deck of an ammonia carrier. (c) Each...

  14. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    HU, T.A.

    2005-10-27

    Assess the steady-state flammability level at normal and off-normal ventilation conditions. The hydrogen generation rate was calculated for 177 tanks using the rate equation model. Flammability calculations based on hydrogen, ammonia, and methane were performed for 177 tanks for various scenarios.

  15. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    HU TA

    2009-10-26

    Assess the steady-state flammability level at normal and off-normal ventilation conditions. The hydrogen generation rate was calculated for 177 tanks using the rate equation model. Flammability calculations based on hydrogen, ammonia, and methane were performed for 177 tanks for various scenarios.

  16. Flammable gas tank waste level reconciliation for 241-SX-105

    SciTech Connect

    Brevick, C.H.; Gaddie, L.A.

    1997-06-23

    Fluor Daniel Northwest was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 241-SX-105 (SX-105, typical). The trapped gas evaluation document states that Tank SX-105 exceeds the 25% of the lower flammable limit criterion, based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the Welty Report is the basis for this letter report. The Welty Report is also a part of the trapped gas evaluation document criteria. The Welty Report contains various tank information, including: physical information, status, levels, and dry wells. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unaccounted for surface level rise. From 1973 through 1980, the Welty Report tracked Tank SX-105 transfers and reported a net cumulative change of 20.75 in. This surface level increase is from an unknown source or is unaccounted for. Duke Engineering and Services Hanford and Lockheed Martin Hanford Corporation are interested in determining the validity of unexplained surface level changes reported in the Welty Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unaccounted for surface level changes as shown in the Welty Report from 1973 through 1980. Tank SX-105 initially received waste from REDOX starting the second quarter of 1955. After June 1975, the tank primarily received processed waste (slurry) from the 242-S Evaporator/Crystallizer and transferred supernate waste to Tanks S-102 and SX-102. The Welty Report shows a cumulative change of 20.75 in. from June 1973 through December 1980.

  17. Flammable gas tank waste level reconcilliation for 241-SX-102

    SciTech Connect

    Brevick, C.H.; Gaddie, L.A.

    1997-06-23

    Fluoro Dynel Northwest (FDNW) was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 24 1-S-1 1 1 (S-I 1 1, typical). The trapped gas evaluation document (ref 1) states that Tank SX-102 exceeds the 25% of the lower flammable limit (FL) criterion (ref 2), based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the ``Wallet Report`` is the basis for this letter report (ref 3). The Wallet Report is also a part of the trapped gas evaluation document criteria. The Wallet Report contains various tank information, including: physical information, status, levels, and dry wells, see Appendix A. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unacquainted for surface level rise. From 1973 through 1980, the Wallet Report tracked Tank S- 102 transfers and reported a net cumulative change of 19.95 in. This surface level increase is from an unknown source or is unacquainted for. Duke Engineering and Services Hanford (DASH) and Leached Martin Hanford Corporation (LMHC) are interested in determining the validity of the unexplained surface level changes reported in the 0611e Wallet Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unacquainted for surface level changes as shown in the Wallet Report from 1973 through 1980.

  18. Flammable gas tank waste level reconciliation for 241-S-111

    SciTech Connect

    Brevick, C.H.; Gaddis, L.A.

    1997-06-23

    Fluor Daniel Northwest (FDNW) was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 241-S-111. The trapped gas evaluation document states that Tank S-111 exceeds the 25% of the lower flammable-limit criterion, based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the Welty Report is the basis for this letter report. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unaccounted for surface level rise. From 1973 through 1980, the Welty Report tracked Tank S-111 transfers. This surface level increase is from an unknown source or is unaccounted for. Duke Engineering and Services Hanford and Lockheed Martin Hanford Corporation are interested in determining the validity of the unexplained surface level changes reported in the Welty Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unaccounted for surface level changes as shown in the Welty Report from 1973 through 1980. Tank S-111 initially received waste from REDOX in 1952, and after April 1974, primarily received processed waste slurry from the 242-S Evaporator/Crystallizer and transferred supernatant waste to Tank S-102. From the FDNW review and comparisons of the Welty Report versus other daily records for Tank S-111, FDNW determined that the majority of the time, the Welty Report is consistent with daily records. Surface level decreases that occurred following saltwell pumping were identified as unaccounted for decreases in the Welty Report, however they were probably a continued settlement caused by saltwell pumping of the interstitial liquids. Because the flammable/trapped gas

  19. THE FLAMMABILITY ANALYSIS AND TIME TO REACH LOWER FLAMMABILITY LIMIT CALCULATIONS ON THE WASTE EVAPORATION AT 242-A EVAPORATOR

    SciTech Connect

    HU TA

    2007-10-31

    This document describes the analysis of the waste evaporation process on the flammability behavior. The evaluation calculates the gas generation rate, time to reach 25% and 100% of the lower flammability limit (LFL), and minimum ventilation rates for the 242-A Evaporator facility during the normal evaporation process and when vacuum is lost. This analysis performs flammability calculations on the waste currently within all 28 double-shell tanks (DST) under various evaporation process conditions to provide a wide spectrum of possible flammable gas behavior. The results of this analysis are used to support flammable gas control decisions and support and upgrade to Documented Safety Analysis for the 242-A Evaporator.

  20. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE [SEC 1 & 2

    SciTech Connect

    HU, T.A.

    2003-09-30

    Flammable gases such as hydrogen, ammonia, and methane are observed in the tank dome space of the Hanford Site high-level waste tanks. This report assesses the steady-state flammability level under normal and off-normal ventilation conditions in the tank dome space for 177 double-shell tanks and single-shell tanks at the Hanford Site. The steady-state flammability level was estimated from the gas concentration of the mixture in the dome space using estimated gas release rates, Le Chatelier's rule and lower flammability limits of fuels in an air mixture. A time-dependent equation of gas concentration, which is a function of the gas release and ventilation rates in the dome space, has been developed for both soluble and insoluble gases. With this dynamic model, the time required to reach the specified flammability level at a given ventilation condition can be calculated. In the evaluation, hydrogen generation rates can be calculated for a given tank waste composition and its physical condition (e.g., waste density, waste volume, temperature, etc.) using the empirical rate equation model provided in Empirical Rate Equation Model and Rate Calculations of Hydrogen Generation for Hanford Tank Waste, HNF-3851. The release rate of other insoluble gases and the mass transport properties of the soluble gas can be derived from the observed steady-state gas concentration under normal ventilation conditions. The off-normal ventilation rate is assumed to be natural barometric breathing only. A large body of data is required to do both the hydrogen generation rate calculation and the flammability level evaluation. For tank waste that does not have sample-based data, a statistical-based value from probability distribution regression was used based on data from tanks belonging to a similar waste group. This report (Revision 3) updates the input data of hydrogen generation rates calculation for 177 tanks using the waste composition information in the Best-Basis Inventory Detail

  1. 46 CFR 35.30-40 - Flammable liquid and gas fuels as ship's stores-TB/ALL.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Flammable liquid and gas fuels as ship's stores-TB/ALL... OPERATIONS General Safety Rules § 35.30-40 Flammable liquid and gas fuels as ship's stores—TB/ALL. Flammable liquids and gases other than diesel fuel, to be used as fuel for approved equipment must satisfy...

  2. 46 CFR 35.30-40 - Flammable liquid and gas fuels as ship's stores-TB/ALL.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 1 2013-10-01 2013-10-01 false Flammable liquid and gas fuels as ship's stores-TB/ALL... OPERATIONS General Safety Rules § 35.30-40 Flammable liquid and gas fuels as ship's stores—TB/ALL. Flammable liquids and gases other than diesel fuel, to be used as fuel for approved equipment must satisfy...

  3. 46 CFR 35.30-40 - Flammable liquid and gas fuels as ship's stores-TB/ALL.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 1 2014-10-01 2014-10-01 false Flammable liquid and gas fuels as ship's stores-TB/ALL... OPERATIONS General Safety Rules § 35.30-40 Flammable liquid and gas fuels as ship's stores—TB/ALL. Flammable liquids and gases other than diesel fuel, to be used as fuel for approved equipment must satisfy...

  4. 46 CFR 35.30-40 - Flammable liquid and gas fuels as ship's stores-TB/ALL.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 1 2012-10-01 2012-10-01 false Flammable liquid and gas fuels as ship's stores-TB/ALL... OPERATIONS General Safety Rules § 35.30-40 Flammable liquid and gas fuels as ship's stores—TB/ALL. Flammable liquids and gases other than diesel fuel, to be used as fuel for approved equipment must satisfy...

  5. Steady State Flammable Gas Release Rate Calculation and Lower Flammability Level Evaluation for Hanford Tank Waste

    SciTech Connect

    HU, T.A.

    2000-04-27

    This work is to assess the steady-state flammability level at normal and off-normal ventilation conditions in the tank dome space for 177 double-shell and single-shell tanks at Hanford. Hydrogen generation rate was calculated for 177 tanks using rate equation model developed recently.

  6. Flammability tests on D0 Run II muon PDT Gas and P-10 Gas

    SciTech Connect

    Herman F. Haggerty; James L. Priest and Tom Marshall

    2001-07-12

    The authors have done a series of measurements with mixtures of Argon, CF4 and CH4 to demonstrate that the mixture chosen for RunII (84% Argon, 8% CH4, 8% CF4) is not flammable. The tests were conducted in the Meson Detector Building in a test cell similar in construction to a cell of a Muon PDT. In order to establish the viability of the test set-up, they first repeated the demonstration that P-10 gas (90% Argon, 10% CH4) is in fact flammable, contrary to the classification by the US DOT. US DOT regulation 173.115 defines flammable gas as: (1) is ignitable (at 14.7 psi) when in a mixture of 13% or less with air; or (2) has a flammability range (at 14.7 psi) with air of at least 12% regardless of the lower explosive limit (LEL). P-10 has a LEL of about 40% and a flammability range of about 10%, so P-10 is not flammable according to the US DOT definition. The point here is that the DOT classifications are to serve the DOT's function to ensure transportation safety, and are not necessarily appropriate for other situations. The first configuration of their test cell, however, apparently failed to ignite P-10. With the guidance of Bill Nuttall of CERN, they modified their test cell to make it more like the standard flammability testing setups, with a large viewing window and a spark gap in the middle of the cell. In this second configuration P-10 was easily and reliably ignitable. After becoming more familiar with the visible indicators of combustion of P-10 (water vapor cloud formation, pressure changes and gas venting) they retested with the initial configuration, and found that the mixture actually had been burning, and that they had just missed all the indications. The data from CERN showed that P-10 burns rather slowly, with about a one second rise time for the pressure to reach the maximum of four atmospheres overpressure. In the tests they saw no signs of any flame, but only a water vapor cloud. Some preliminary tests with the same cell using Argon-Ethane and

  7. Flammable gas issues in double-contained receiver tanks. Revision 2

    SciTech Connect

    Peurrung, L.M.; Mahoney, L.A.; Stewart, C.W.; Gauglitz, P.A.; Pederson, L.R.; Bryan, S.A.; Shepard, C.L.

    1998-08-01

    Four double-contained receiver tanks (DCRTs) at Hanford will be used to store salt-well pumped liquids from tanks on the Flammable Gas Watch List. This document was created to serve as a reference document describing the current knowledge of flammable gas issues in DCRTs. The document identifies, describes, evaluates, and attempts to quantify potential gas carryover and release mechanisms. It estimates several key parameters needed for these calculations, such as initial aqueous concentrations and ventilation rate, and evaluates the uncertainty in those estimates. It justifies the use of the Schumpe model for estimating vapor-liquid equilibrium constants. It identifies several potential waste compatibility issues (such as mixing and pH or temperature changes) that could lead to gas release and provides a basis for calculating their effects. It evaluates the potential for gas retention in precipitated solids within a DCRT and whether retention could lead to a buoyant displacement instability (rollover) event. It discusses rates of radiolytic, thermal, and corrosive hydrogen generation within the DCRT. It also describes in detail the accepted method of calculating the lower flammability limit (LFL) for mixtures of flammable gases. The report incorporates these analyses into two models for calculating headspace flammability, one based on instantaneous equilibrium between dissolved gases and the headspace and one incorporating limited release rates based on mass-transfer considerations. Finally, it demonstrates the use of both models to estimate headspace flammable gas concentrations and minimum ventilation rates required to maintain concentrations below 25% of the LFL.

  8. TRU waste transportation -- The flammable gas generation problem

    SciTech Connect

    Connolly, M.J.; Kosiewicz, S.T.

    1997-11-01

    The Nuclear Regulatory Commission (NRC) has imposed a flammable gas (i.e., hydrogen) concentration limit of 5% by volume on transuranic (TRU) waste containers to be shipped using the TRUPACT-II transporter. This concentration is the lower explosive limit (LEL) in air. This was done to minimize the potential for loss of containment during a hypothetical 60 day period. The amount of transuranic radionuclide that is permissible for shipment in TRU waste containers has been tabulated in the TRUPACT-II Safety Analysis Report for Packaging (SARP, 1) to conservatively prevent accumulation of hydrogen above this 5% limit. Based on the SARP limitations, approximately 35% of the TRU waste stored at the Idaho National Engineering and Environmental Lab (INEEL), Los Alamos National Lab (LANL), and Rocky Flats Environmental Technology Site (RFETS) cannot be shipped in the TRUPACT-II. An even larger percentage of the TRU waste drums at the Savannah River Site (SRS) cannot be shipped because of the much higher wattage loadings of TRU waste drums in that site`s inventory. This paper presents an overview of an integrated, experimental program that has been initiated to increase the shippable portion of the Department of Energy (DOE) TRU waste inventory. In addition, the authors will estimate the anticipated expansion of the shippable portion of the inventory and associated cost savings. Such projection should provide the TRU waste generating sites a basis for developing their TRU waste workoff strategies within their Ten Year Plan budget horizons.

  9. Summary of information on flammable gas watch list tanks

    SciTech Connect

    Brager, H.R.

    1994-01-01

    This document compiles and summarizes available, relevant information pertaining to Hanford Site waste tanks designated as Flammable Gas Watch List (FGWL) tanks. There are four primary objectives of this document. First, it provides summary data, including surface level readings, chemical composition, and temperature readings for each FGWL tank. This document also is intended to be used as a source of information on FGWL tanks references. More than 400 documents were used to compile the information presented in this report, and the Endnotes at the conclusion of each section; Section 5.0, {open_quotes}References;{close_quotes} and Section 6.0, {open_quotes}Sources of Information{close_quotes} are all included to direct the reader to further, more detailed sources of information that pertain to specific FGWL tanks or information. The third objective of this document is to present the specific fill history of each FGWL double-shell tank (DST), including data obtained from detailed Evaporator 242-A documents. Finally, this document includes an assessment of the total organic carbon (TOC) content of each DST.

  10. Novel industrial application: flammable and toxic gas monitoring in the printing industry

    NASA Astrophysics Data System (ADS)

    Jacobson, Esther; Spector, Yechiel

    1999-12-01

    The present paper describes an Open Path Electro-Optical Gas Monitoring System specifically designed for in-situ on-line monitoring of flammable and toxic atmospheres in the Printing Industry in general, and for air-duct applications in particular. The printing industry posies unique fire hazards due to the variety of toxic and flammable chemical employed in the various printing process. Flammable material such as paper, ink, solvents, thinners, metal powders, cornstarch powders, cloth, synthetic materials are frequently used in the printing industry in several processes such as letter-pressing, lithography, screen printing etc.

  11. [Calculation of flammability limits of gas phases with ethylene oxide in sterilisers].

    PubMed

    Askar, Enis; Schröder, Volkmar; Acikalin, Aydan; Steinbach, Jörg

    2008-12-01

    A calculation method for flammability limits of gas phases with ethylene oxide in sterilisers was developed. Using the Software GasEq and the newly developed Makro "SterEx" for MS-Excel, flammability limits of mixtures with ethylene oxide, air and inert gases at temperatures between 20 degrees C and 100 degrees C and pressures between 0.4 bar and 1.0 bar can be calculated. This method can be used to easily determine safe operating conditions. The used semi-empirical model is based upon the assumption of constant flame temperature profiles at the flammability limits subject to the EO-concentration for different mixtures. To collect model parameters and to validate the model, several experiments with mixtures of ethylene oxide, nitrogen, carbon dioxide, water vapour and air were carried out to determine flammability limits. To simulate the structural conditions of sterilisers, the experiments were conducted in accordance to DIN EN 1839-B in a closed autoclave with temperatures and pressures relevant for sterilisation processes. The calculation of flammability limits of process gas mixtures with "SterEx" provides good agreement with flammability limits that were determined in experiments.

  12. Evaluation of high-level nuclear waste tanks having a potential flammable gas hazard

    SciTech Connect

    Johnson, G.D.; Barton, W.B.; Hill, R.C.; et al, Fluor Daniel Hanford

    1997-02-14

    In 1990 the U.S. Department of Energy declared an unreviewed safety question as a result of the behavior of tank 241-SY-101. This tank exhibited episodic releases of flammable gases that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years a considerable amount of knowledge has been gained about the chemical and physical processes that govern the behavior of tank 241-SY-101 and the other tanks associated with a potential flammable gas hazard. This paper presents an overview of the current understanding of gas generation, retention, and release and covers the results of direct sampling of the tanks to determine the gas composition and the amount of stored gas.

  13. Summary of flammable gas hazard and potential consequences in tank waste remediation system facility at the Hanford site

    SciTech Connect

    Van Vleet, R.J., Westinghouse Hanford

    1996-12-11

    This document provides a summary of the flammable gas program since 1992. It provides the best understanding of generation, retention, release of flammable gases. It gives a composition for each of the flammable gas tanks, calculates postulated concentrations in the event of a release, calculates the pressure obtained during a burn, and provides radiological and toxicological consequences. Controls from the analysis are found in WHC-SD-WM-SAR-067.

  14. Final design review report for RMCST modifications for flammable gas tanks

    SciTech Connect

    Corbett, J.E., Westinghouse Hanford

    1996-05-31

    This report documents the completion of the formal design review for the Rotary Mode Core Sample Truck (RMCST) modification for flammable gas tanks. The RMCST modifications are intended to support core sampling operations in waste tanks requiring flammable gas controls. The objective of this review was to approve Engineering controls. The objective of this review was to approve Engineering Change orders and new drawings, at the 100% design completion state. The conclusion reached by the review committee was that the design was acceptable and efforts should continue toward fabrication and delivery.

  15. Methods of Off-Gas Flammability Control for DWPF Melter Off-Gas System at Savannah River Site

    SciTech Connect

    Choi, A.S.; Iverson, D.C.

    1996-05-02

    Several key operating variables affecting off-gas flammability in a slurry-fed radioactive waste glass melter are discussed, and the methods used to prevent potential off-gas flammability are presented. Two models have played a central role in developing such methods. The first model attempts to describe the chemical events occurring during the calcining and melting steps using a multistage thermodynamic equilibrium approach, and it calculates the compositions of glass and calcine gases. Volatile feed components and calcine gases are fed to the second model which then predicts the process dynamics of the entire melter off-gas system including off-gas flammability under both steady state and various transient operating conditions. Results of recent simulation runs are also compared with available data

  16. Flammable gas issues in double-contained receiver tanks. Revision 1

    SciTech Connect

    Peurrung, L.M.; Mahoney, L.A.; Stewart, C.W.; Gauglitz, P.A.; Pederson, L.R.; Bryan, S.A.; Shepard, C.L.

    1998-06-01

    Four double-contained receiver tanks (DCRTs) at Hanford will be used to store salt-well pumped liquids from tanks on the Flammable Gas Watch List. This document was created to serve as a technical basis or reference document for flammable gas issues in DCRTs. The document identifies, describes, evaluates, and attempts to quantify potential gas carryover and release mechanisms. It estimates several key parameters needed for these calculations, such as initial aqueous concentrations and ventilation rate, and evaluates the uncertainty in those estimates. It justifies the use of the Schumpe model for estimating vapor-liquid equilibrium constants. It identifies several potential waste compatibility issues (such as mixing and pH or temperature changes) that could lead to gas release and provides a basis for calculating their effects. It evaluates the potential for gas retention in precipitated solids within a DCRT and whether retention could lead to a buoyant displacement instability (rollover) event. It discusses rates of radiolytic, thermal, and corrosive hydrogen generation within the DCRT. It also describes in detail the accepted method of calculating the lower flammability limit (LFL) for mixtures of flammable gases.

  17. Slurry growth, gas retention, and flammable gas generation by Hanford radioactive waste tanks: Synthetic waste studies, FY 1991

    SciTech Connect

    Bryan, S.A.; Pederson, L.R.; Ryan, J.L.; Scheele, R.D.; Tingey, J.M.

    1992-08-01

    Of 177 high-level waste storage tanks on the Hanford Site, 23 have been placed on a safety watch list because they are suspected of producing flammable gases in flammable or explosive concentrate. One tankin particular, Tank 241-SY-101 (Tank 101-SY), has exhibited slow increases in waste volume followed by a rapid decrease accompanied by venting of large quantities of gases. The purpose of this study is to help determine the processes by which flammable gases are produced, retained, and eventually released from Tank 101-SY. Waste composition data for single- and double-shell waste tanks on the flammable gas watch listare critically reviewed. The results of laboratory studies using synthetic double-shell wastes are summarized, including physical and chemical properties of crusts that are formed, the stoichiometry and rate ofgas generation, and mechanisms responsible for formation of a floating crust.

  18. Data and Observations of Single Shell Flammable Gas Watch List Tank Behavior

    SciTech Connect

    HEDENGREN, D.C.

    2001-02-14

    This report summarizes the available data, observations, and analyses performed relating to flammable gas generation, retention, and release in the nineteen single-shell nuclear waste storage tanks at the Hanford Site that are on the Flammable Gas Watch List (Public Law 101-510 1990). The tanks and the waste they contain are described in terms of their fill history, chemistry, and waste physical properties and configuration. In-situ measurement and monitoring systems are described and their data are summarized. The gas generation rates, retained gas volumes, and the spontaneous and induced gas release history of each tank are discussed. Saltwell pumping activities are also summarized, and the effects of pumping on gas generation, retention, and release are described.

  19. UPGRADING NATURAL GAS VIA MEMBRANE SEPARATION PROCESSES

    SciTech Connect

    S.A.Stern; P.A. Rice; J. Hao

    2000-03-01

    The objective of the present study is to assess the potential usefulness of membrane separation processes for removing CO{sub 2} and H{sub 2}S from low-quality natural gas containing substantial amounts of both these ''acid'' gases, e.g., up to 40 mole-% CO{sub 2} and 10 mole-% H{sub 2}S. The membrane processes must be capable of upgrading the crude natural gas to pipeline specifications ({le} 2 mole-% CO{sub 2}, {le} 4 ppm H{sub 2}S). Moreover, these processes must also be economically competitive with the conventional separation techniques, such as gas absorption, utilized for this purpose by the gas industry.

  20. Flammable gas safety program. Analytical methods development: FY 1994 progress report

    SciTech Connect

    Campbell, J.A.; Clauss, S.; Grant, K.; Hoopes, V.; Lerner, B.; Lucke, R.; Mong, G.; Rau, J.; Wahl, K.; Steele, R.

    1994-09-01

    This report describes the status of developing analytical methods to account for the organic components in Hanford waste tanks, with particular focus on tanks assigned to the Flammable Gas Watch List. The methods that have been developed are illustrated by their application to samples obtained from Tank 241-SY-101 (Tank 101-SY).

  1. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Flammable vapor-gas dispersion protection. 193.2059 Section 193.2059 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE...

  2. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Flammable vapor-gas dispersion protection. 193.2059 Section 193.2059 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE...

  3. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Flammable vapor-gas dispersion protection. 193.2059 Section 193.2059 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE...

  4. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Flammable vapor-gas dispersion protection. 193.2059 Section 193.2059 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE...

  5. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Flammable vapor-gas dispersion protection. 193.2059 Section 193.2059 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE...

  6. A study of non-flammable gas mixture for resistive plate counter

    SciTech Connect

    Takamatsu, H.; Hoshi, Y.; Abe, K.

    1996-06-01

    The RPC (resistive plate counter) has good time and position resolution. These factors make it an attractive candidate for trigger system at collider experiment. The standard gas mixtures (Ar+iso-C{sub 4}H{sub 10}+Freon) used in RPC are very flammable when leaked into air. In view of safety issue, the authors have studied non-flammable gas of Ar+CO{sub 2}+iso-C{sub 4}H{sub 10}+Freon as a function of ratio Ar:CO{sub 2} allowed in non-flammable gas mixtures for the RPC with ABS electrodes. The basic performance of the various mixtures have been measured; singles (untriggered) count rate, detection efficiency and charge spectra versus operating voltage. They have found a set of non-flammable mixtures of the kind of AR+CO{sub 2}+Freon contained less than {approximately}8.4% of iso-C{sub 4}H{sub 10} for K{sub L}/muon counter of KEK B-factory at KEK.

  7. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2002-06-01

    A new project was initiated this quarter to develop gas/liquid membranes for natural gas upgrading. Efforts have concentrated on legal agreements, including alternative field sites. Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project.

  8. 46 CFR 35.30-40 - Flammable liquid and gas fuels as ship's stores-TB/ALL.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... OPERATIONS General Safety Rules § 35.30-40 Flammable liquid and gas fuels as ship's stores—TB/ALL. Flammable... portable safety container approved by a recognized testing laboratory for the contents carried. (b) The... exceed a capacity of five gallons may be stowed below the weather deck in a paint or lamp locker. ...

  9. Summary of tank information relating salt well pumping to flammable gas safety issues

    SciTech Connect

    Caley, S.M.; Mahoney, L.A.; Gauglitz, P.A.

    1996-09-01

    The Hanford Site has 149 single-shell tanks (SSTs) containing radioactive wastes that are complex mixes of radioactive and chemical products. Active use of these SSTs was phased out completely by November 1980, and the first step toward final disposal of the waste in the SSTs is interim stabilization, which involves removing essentially all of the drainable liquid from the tank. Stabilization can be achieved administratively, by jet pumping to remove drainable interstitial liquid, or by supernatant pumping. To date, 116 tanks have been declared interim stabilized; 44 SSTs have had drainable liquid removed by salt well jet pumping. Of the 149 SSTs, 19 are on the Flammable Gas Watch List (FGWL) because the waste in these tanks is known or suspected, in all but one case, to generate and retain mixtures of flammable gases, including; hydrogen, nitrous oxide, and ammonia. Salt well pumping to remove the drainable interstitial liquid from these SSTs is expected to cause the release of much of the retained gas, posing a number of safety concerns. The scope of this work is to collect and summarize information, primarily tank data and observations, that relate salt well pumping to flammable gas safety issues. While the waste within FGWL SSTs is suspected offering flammable gases, the effect of salt well pumping on the waste behavior is not well understood. This study is being conducted for the Westinghouse Hanford Company as part of the Flammable Gas Project at the Pacific Northwest National Laboratory (PNNL). Understanding the historical tank behavior during and following salt well pumping will help to resolve the associated safety issues.

  10. An approximate-reasoning-based method for screening flammable gas tanks

    SciTech Connect

    Eisenhawer, S.W.; Bott, T.F.; Smith, R.E.

    1998-03-01

    High-level waste (HLW) produces flammable gases as a result of radiolysis and thermal decomposition of organics. Under certain conditions, these gases can accumulate within the waste for extended periods and then be released quickly into the dome space of the storage tank. As part of the effort to reduce the safety concerns associated with flammable gas in HLW tanks at Hanford, a flammable gas watch list (FGWL) has been established. Inclusion on the FGWL is based on criteria intended to measure the risk associated with the presence of flammable gas. It is important that all high-risk tanks be identified with high confidence so that they may be controlled. Conversely, to minimize operational complexity, the number of tanks on the watchlist should be reduced as near to the true number of flammable risk tanks as the current state of knowledge will support. This report presents an alternative to existing approaches for FGWL screening based on the theory of approximate reasoning (AR) (Zadeh 1976). The AR-based model emulates the inference process used by an expert when asked to make an evaluation. The FGWL model described here was exercised by performing two evaluations. (1) A complete tank evaluation where the entire algorithm is used. This was done for two tanks, U-106 and AW-104. U-106 is a single shell tank with large sludge and saltcake layers. AW-104 is a double shell tank with over one million gallons of supernate. Both of these tanks had failed the screening performed by Hodgson et al. (2) Partial evaluations using a submodule for the predictor likelihood for all of the tanks on the FGWL that had been flagged previously by Whitney (1995).

  11. DWPF Melter Off-Gas Flammability Assessment for Sludge Batch 9

    SciTech Connect

    Choi, A. S.

    2016-07-11

    The slurry feed to the Defense Waste Processing Facility (DWPF) melter contains several organic carbon species that decompose in the cold cap and produce flammable gases that could accumulate in the off-gas system and create potential flammability hazard. To mitigate such a hazard, DWPF has implemented a strategy to impose the Technical Safety Requirement (TSR) limits on all key operating variables affecting off-gas flammability and operate the melter within those limits using both hardwired/software interlocks and administrative controls. The operating variables that are currently being controlled include; (1) total organic carbon (TOC), (2) air purges for combustion and dilution, (3) melter vapor space temperature, and (4) feed rate. The safety basis limits for these operating variables are determined using two computer models, 4-stage cold cap and Melter Off-Gas (MOG) dynamics models, under the baseline upset scenario - a surge in off-gas flow due to the inherent cold cap instabilities in the slurry-fed melter.

  12. Flammable Gas Refined Safety Analysis Tool Software Verification and Validation Report for Resolve Version 2.5

    SciTech Connect

    BRATZEL, D.R.

    2000-09-28

    The purpose of this report is to document all software verification and validation activities, results, and findings related to the development of Resolve Version 2.5 for the analysis of flammable gas accidents in Hanford Site waste tanks.

  13. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2003-04-01

    Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. KPS and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on field site selection. ChevronTexaco has nominated their Headlee Gas Plant in Odessa, TX for a commercial-scale dehydration test. Potting and module materials testing were initiated. Preliminary design

  14. Control Decisions for Flammable Gas Hazards in Double Contained Receiver Tanks (DCRTs)

    SciTech Connect

    KRIPPS, L.J.

    2000-06-28

    This report describes the control decisions for flammable gas hazards in double-contained receiver tanks (DCRTs) made at control decision meetings on November 16, 17, and 18, 1999, on April 19,2000, and on May 10,2000, and their basis. These control decisions, and the analyses that support them, will be documented in an amendment to the Final Safety Analysis Report (FSAR) (CHG 2000a) and Technical Safety Requirements (TSR) (CHG 2000b) to close the Flammable Gas Unreviewed Safety Question (USQ) (Bacon 1996 and Wagoner 1996) for DCRTs. Following the contractor Tier I review of the FSAR and TSR amendment, it will be submitted to the U.S. Department of Energy (DOE), Office of River Protection (ORP) for review and approval.

  15. Flammable gas double shell tank expert elicitation presentations (Part A and Part B)

    SciTech Connect

    Bratzel, D.R.

    1998-04-17

    This document is a compilation of presentation packages and white papers for the Flammable Gas Double Shell Tank Expert Elicitation Workshop {number_sign}2. For each presentation given by the different authors, a separate section was developed. The purpose for issuing these workshop presentation packages and white papers as a supporting document is to provide traceability and a Quality Assurance record for future reference to these packages.

  16. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2003-01-01

    Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on legal agreements, including alternative field sites. Preliminary design of the bench-scale equipment continues.

  17. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2002-10-01

    Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. KPS and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on legal agreements, including alternative field sites. Preliminary design of the bench-scale equipment continues.

  18. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2002-06-30

    Efforts this quarter have concentrated on legal agreements, including alternative field sites. Preliminary design of the bench-scale equipment continues. Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50--70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project.

  19. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2002-06-01

    Efforts this quarter have concentrated on legal agreements, including alternative field sites. Preliminary design of the bench-scale equipment has been initiated. Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50--70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project.

  20. Results of vapor space monitoring of flammable gas Watch List tanks

    SciTech Connect

    Wilkins, N.E.

    1997-09-18

    This report documents the measurement of headspace gas concentrations and monitoring results from the Hanford tanks that have continuous flammable gas monitoring. The systems used to monitor the tanks are Standard Hydrogen Monitoring Systems. Further characterization of the tank off-gases was done with Gas Characterization Systems and vapor grab samples. The background concentrations of all tanks are below the action level of 6250 ppm. Other information which can be derived from the measurements (such as generation rate, release rate, and ventilation rate) is also discussed.

  1. Results of Vapor Space Monitoring of Flammable Gas Watch List Tanks

    SciTech Connect

    MCCAIN, D.J.

    2000-09-27

    This report documents the measurement of headspace gas concentrations and monitoring results from the Hanford tanks that have continuous flammable gas monitoring. The systems used to monitor the tanks are Standard Hydrogen Monitoring Systems. Further characterization of the tank off-gases was done with Gas Characterization systems and vapor grab samples. The background concentrations of all tanks are below the action level of 6250 ppm. Other information which can be derived from the measurements (such as generation rate, released rate, and ventilation rate) is also discussed.

  2. Equipment design guidance document for flammable gas waste storage tank new equipment

    SciTech Connect

    Smet, D.B.

    1996-04-11

    This document is intended to be used as guidance for design engineers who are involved in design of new equipment slated for use in Flammable Gas Waste Storage Tanks. The purpose of this document is to provide design guidance for all new equipment intended for application into those Hanford storage tanks in which flammable gas controls are required to be addressed as part of the equipment design. These design criteria are to be used as guidance. The design of each specific piece of new equipment shall be required, as a minimum to be reviewed by qualified Unreviewed Safety Question evaluators as an integral part of the final design approval. Further Safety Assessment may be also needed. This guidance is intended to be used in conjunction with the Operating Specifications Documents (OSDs) established for defining work controls in the waste storage tanks. The criteria set forth should be reviewed for applicability if the equipment will be required to operate in locations containing unacceptable concentrations of flammable gas.

  3. Flammable Gas Safety Program: actual waste organic analysis FY 1996 progress report; Flammable Gas Safety Program: actual waste organic analysis FY 1996 progress report

    SciTech Connect

    Clauss, S.A.; Grant, K.E.; Hoopes, V.; Mong, G.M.; Rau, J.; Steele, R.; Wahl, K.H.

    1996-09-01

    This report describes the status of optimizing analytical methods to account for the organic components in Hanford waste tanks, with emphasis on tanks assigned to the Flammable Gas Watch List. The methods developed are illustrated by their application to samples from Tanks 241-SY-103 and 241-S-102. Capability to account for organic carbon in Tank SY-101 was improved significantly by improving techniques for isolating organic constituents relatively free from radioactive contamination and by improving derivatization methodology. The methodology was extended to samples from Tank SY-103 and results documented in this report. Results from analyzing heated and irradiated SY-103 samples (Gas Generation Task) and evaluating methods for analyzing tank waste directly for chelators and chelator fragments are also discussed.

  4. Potential Flammable Gas Explosion in the TRU Vent and Purge Machine

    SciTech Connect

    Vincent, A

    2006-04-05

    The objective of the analysis was to determine the failure of the Vent and Purge (V&P) Machine due to potential explosion in the Transuranic (TRU) drum during its venting and/or subsequent explosion in the V&P machine from the flammable gases (e.g., hydrogen and Volatile Organic Compounds [VOCs]) vented into the V&P machine from the TRU drum. The analysis considers: (a) increase in the pressure in the V&P cabinet from the original deflagration in the TRU drum including lid ejection, (b) pressure wave impact from TRU drum failure, and (c) secondary burns or deflagrations resulting from excess, unburned gases in the cabinet area. A variety of cases were considered that maximized the pressure produced in the V&P cabinet. Also, cases were analyzed that maximized the shock wave pressure in the cabinet from TRU drum failure. The calculations were performed for various initial drum pressures (e.g., 1.5 and 6 psig) for 55 gallon TRU drum. The calculated peak cabinet pressures ranged from 16 psig to 50 psig for various flammable gas compositions. The blast on top of cabinet and in outlet duct ranged from 50 psig to 63 psig and 12 psig to 16 psig, respectively, for various flammable gas compositions. The failure pressures of the cabinet and the ducts calculated by structural analysis were higher than the pressure calculated from potential flammable gas deflagrations, thus, assuring that V&P cabinet would not fail during this event. National Fire Protection Association (NFPA) 68 calculations showed that for a failure pressure of 20 psig, the available vent area in the V&P cabinet is 1.7 to 2.6 times the required vent area depending on whether hydrogen or VOCs burn in the V&P cabinet. This analysis methodology could be used to design the process equipment needed for venting TRU waste containers at other sites across the Department of Energy (DOE) Complex.

  5. Methodology for Predicting Flammable Gas Mixtures in Double Contained Receiver Tanks [SEC 1 THRU SEC 3

    SciTech Connect

    HEDENGREN, D.C.

    2000-01-31

    This methodology document provides an estimate of the maximum concentrations of flammable gases (ammonia, hydrogen, and methane) which could exist in the vapor space of a double-contained receiver tank (DCRT) from the simultaneous saltwell pumping of one or more single-shell tanks (SSTs). This document expands Calculation Note 118 (Hedengren et a1 1997) and removes some of the conservatism from it, especially in vapor phase ammonia predictions. The methodologies of Calculation Note 118 (Hedengren et a1 1997) are essentially identical for predicting flammable gas mixtures in DCRTs from saltwell pumping for low DCRT ventilation rates, 1e, < 1 cfm. The hydrogen generation model has also been updated in the methodology of this document.

  6. An Improved Analytical Approach to Determine the Explosive Effects of Flammable Gas-Air Mixtures

    SciTech Connect

    Yang, J M

    2005-11-10

    The U.S. Department of Energy (DOE) Complex includes many sites and laboratories that store quantities of low-level, solid nuclear waste in drums and other types of shipping containers. The drums may be stored for long periods of time prior to being transported and final dispositioning. Based on the radioactivity (e.g., Pu{sup 239} equivalent), chemical nature (e.g. volatile organic compounds) and other characteristics of the stored waste, flammable gases may evolve. Documented safety analyses (DSAs) for storage of these drums must address storage and safety management issues to protect workers, the general public, and the environment. This paper discusses an improved analytical method for determining the explosion effects flammable gas-air mixtures as well as the subsequent accident phenomenology.

  7. Data Observations on Double Shell Tank (DST) Flammable Gas Watch List Tank Behavior

    SciTech Connect

    HEDENGREN, D.C.

    2000-09-28

    This report provides the data from the retained gas sampler, void fraction instrument, ball rheometer, standard hydrogen monitoring system, and other tank data pertinent to gas retention and release behavior in the waste stored in double-shelled Flammable Gas Watch List tanks at Hanford. These include tanks 241-AN-103,241-AN-104, 241-AN-105, 241-AW-101, 241-SY-101, and 241-SY-103. The tanks and the waste they contain are described in terms of fill history and chemistry. The results of mixer pump operation and recent waste transfers and back-dilution in SY-101 are also described. In-situ measurement and monitoring systems are described and the data are summarized under the categories of thermal behavior, waste configuration and properties, gas generation and composition, gas retention and historical gas release behavior.

  8. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2003-07-01

    Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on field site selection. ChevronTexaco has nominated their Headlee Gas Plant in Odessa, TX for a commercial-scale dehydration test. Design and cost estimation for this new site are underway. Potting

  9. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2003-10-01

    Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on field site selection. ChevronTexaco has nominated their Headlee Gas Plant in Odessa, TX for a commercial-scale dehydration test. Design and cost estimation for this new site are underway. A Haz

  10. Assessment of alternative mitigation concepts for Hanford flammable gas tanks

    SciTech Connect

    Stewart, C.W.; Schienbein, L.A.; Hudson, J.D.; Eschbach, E.J.; Lessor, D.L.

    1994-09-01

    This report provides a review and assessment of four selected mitigation concepts: pump jet mixing, sonic vibration, dilution, and heating. Though the relative levels of development of these concepts are quite different, some definite conclusions are made on their comparative feasibility. Key findings of this report are as follows. A mixer pump has proven to be a safe and effective active mitigation method in Tank 241-SY-101, and the authors are confident that mixer pumps will effectively mitigate other tanks with comparable waste configurations and properties. Low-frequency sonic vibration is also predicted to be effective for mitigation. Existing data cannot prove that dilution can mitigate gas release event (GRE) behavior. However, dilution is the only concept of the four that potentially offers passive mitigation. Like dilution, heating the waste cannot be proven with available information to mitigate GRE behavior. The designs, analyses, and data from which these conclusions are derived are presented along with recommendations.

  11. Electrical classification for the single shell flammable gas watch list tanks

    SciTech Connect

    Huckfeldt, R.A.; Anderson, R.A.

    1995-04-01

    This document is to establish the hazard classification of single shell watch list tanks according to National Fire Protection Association (NFPA) criteria and sound engineering judgment. Establishing the hazard classification is necessary to determine the appropriate wiring methods and installation of electrical and mechanical equipment assure safety in an atmosphere that may be hazardous. The tanks have been placed on the flammable gas watch list because their waste types are similar to those in tanks that exhibit episodic behavior and/or unexplained growth of the waste-level height occuring over time. They contain mostly solid wastes.

  12. Resolve! Version 2.5: Flammable Gas Accident Analysis Tool Acceptance Test Plan and Test Results

    SciTech Connect

    LAVENDER, J.C.

    2000-10-17

    RESOLVE! Version 2 .5 is designed to quantify the risk and uncertainty of combustion accidents in double-shell tanks (DSTs) and single-shell tanks (SSTs). The purpose of the acceptance testing is to ensure that all of the options and features of the computer code run; to verify that the calculated results are consistent with each other; and to evaluate the effects of the changes to the parameter values on the frequency and consequence trends associated with flammable gas deflagrations or detonations.

  13. Operability test report for core sample truck {number_sign}1 flammable gas modifications

    SciTech Connect

    Akers, J.C.

    1997-09-15

    This report primarily consists of the original test procedure used for the Operability Testing of the flammable gas modifications to Core Sample Truck No. One. Included are exceptions, resolutions, comments, and test results. This report consists of the original, completed, test procedure used for the Operability Testing of the flammable gas modifications to the Push Mode Core Sample Truck No. 1. Prior to the Acceptance/Operability test the truck No. 1 operations procedure (TO-080-503) was revised to be more consistent with the other core sample truck procedures and to include operational steps/instructions for the SR weather cover pressurization system. A draft copy of the operations procedure was used to perform the Operability Test Procedure (OTP). A Document Acceptance Review Form is included with this report (last page) indicating the draft status of the operations procedure during the OTP. During the OTP 11 test exceptions were encountered. Of these exceptions four were determined to affect Acceptance Criteria as listed in the OTP, Section 4.7 ACCEPTANCE CRITERIA.

  14. An approximate-reasoning-based method for screening high-level waste tanks for flammable gas

    SciTech Connect

    Eisenhawer, S.W.; Bott, T.F.; Smith, R.E.

    1998-07-01

    The in situ retention of flammable gas produced by radiolysis and thermal decomposition in high-level waste can pose a safety problem if the gases are released episodically into the dome space of a storage tank. Screening efforts at Hanford have been directed at identifying tanks in which this situation could exist. Problems encountered in screening motivated an effort to develop an improved screening methodology. Approximate reasoning (AR) is a formalism designed to emulate the kinds of complex judgments made by subject matter experts. It uses inductive logic structures to build a sequence of forward-chaining inferences about a subject. AR models incorporate natural language expressions known as linguistic variables to represent evidence. The use of fuzzy sets to represent these variables mathematically makes it practical to evaluate quantitative and qualitative information consistently. The authors performed a pilot study to investigate the utility of AR for flammable gas screening. They found that the effort to implement such a model was acceptable and that computational requirements were reasonable. The preliminary results showed that important judgments about the validity of observational data and the predictive power of models could be made. These results give new insights into the problems observed in previous screening efforts.

  15. An approximate reasoning-based method for screening high-level-waste tanks for flammable gas

    SciTech Connect

    Eisenhawer, S.W.; Bott, T.F.; Smith, R.E.

    2000-06-01

    The in situ retention of flammable gas produced by radiolysis and thermal decomposition in high-level waste can pose a safety problem if the gases are released episodically into the dome space of a storage tank. Screening efforts at the Hanford site have been directed at identifying tanks in which this situation could exist. Problems encountered in screening motivated an effort to develop and improved screening methodology. Approximate reasoning (AR) is a formalism designed to emulate the kinds of complex judgments made by subject matter experts. It uses inductive logic structures to build a sequence of forward-chaining inferences about a subject. Approximate-reasoning models incorporate natural language expressions known as linguistic variables to represent evidence. The use of fuzzy sets to represent these variables mathematically makes it practical to evaluate quantitative and qualitative information consistently. In a pilot study to investigate the utility of AR for flammable gas screening, the effort to implement such a model was found to be acceptable, and computational requirements were found to be reasonable. The preliminary results showed that important judgments about the validity of observational data and the predictive power of models could be made. These results give new insights into the problems observed in previous screening efforts.

  16. Waste tank 241-SY-101 dome airspace and ventilation system response to a flammable gas plume burn

    SciTech Connect

    Heard, F.J.

    1995-11-01

    A series of flammable gas plume burn and transient pressure analyses have been completed for a nuclear waste tank (241-SY-101) and associated tank farm ventilation system at the U.S. Department of Energy`s Hanford facility. The subject analyses were performed to address issues concerning the effects of transient pressures resulting from igniting a small volume of concentrated flammable gas just released from the surface of the waste as a plume and before the flammable gas concentration could be reduced by mixing with the dome airspace by local convection and turbulent diffusion. Such a condition may exist as part of an in progress episode gas release (EGR) or gas plume event. The analysis goal was to determine the volume of flammable gas that if burned within the dome airspace would result in a differential pressure, after propagating through the ventilation system, greater than the current High Efficiency Particulate Filter (HEPA) limit of 2.49 KPa (10 inches of water or 0. 36 psi). Such a pressure wave could rupture the tank ventilation system inlet and outlet HEPA filters leading to a potential release of contaminants to the environment

  17. Assessment of the impact of the next generation solvent on DWPF melter off-gas flammability

    SciTech Connect

    Daniel, W. E.

    2013-02-13

    An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of replacing the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process with the Next Generation Solvent (NGS-MCU) and blended solvent. The results of this study showed that the concentrations of nonvolatile carbon and hydrogen of the current solvent in the Slurry Mix Evaporator (SME) product would both be about 29% higher than their counterparts of the NGS-MCU and blended solvent in the absence of guanidine partitioning. When 6 ppm of guanidine (TiDG) was added to the effluent transfer to DWPF to simulate partitioning for the NGS-MCU and blended solvent cases and the concentration of Isopar{reg_sign} L in the effluent transfer was controlled below 87 ppm, the concentrations of nonvolatile carbon and hydrogen of the NGS-MCU and blended solvent were still about 12% and 4% lower, respectively, than those of the current solvent. It is, therefore, concluded that as long as the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle and the concentration of Isopar{reg_sign} L in the effluent transfer is controlled below 87 ppm, using the current solvent assumption of 105 ppm Isopar{reg_sign} L or 150 ppm solvent in lieu of NGS-MCU or blended solvent in the DWPF melter off-gas flammability assessment is conservative for up to an additional 6 ppm of TiDG in the effluent due to guanidine partitioning. This report documents the calculations performed to reach this conclusion.

  18. Mitigation/remediation concepts for Hanford Site flammable gas generating waste tanks

    SciTech Connect

    Babad, H.; Deichman, J.L. ); Johnson, B.M.; Lemon, D.K.; Strachan, D.M. )

    1992-04-01

    This report presents a preliminary assessment of concepts for the mitigation and/or remediation of the hydrogen gas generation, storage, and periodic release in Tank 241-SY-101 (101-SY) and 22 other tanks. The 22 other tanks exhibit much less hydrogen generation (volume and concentration of released flammable gases) than Tank 101-SY and have not had the focus nor attention that has been given to Tank 101-SY. These tanks have been listed as potential hydrogen gas-generating tanks from analysis of tank performance and data from flowsheets and Track Radioactive Constituents Reports (TRAC). These lesser hydrogen-generating tanks will also need to be revisited and revalidated. Of the 23 hydrogen class tanks, 5 are double-shell tanks (DST) and 18 are single-shell tanks (SST). Options for mitigation or remediation are different for the two types of tanks because of age, configuration, and waste form. While this document principally focuses on Tank 101-SY, the information presented has been useful to address other tanks containing hydrogen-generating waste.

  19. Flammable gas safety program. Analytical methods development: FY 1993 progress report

    SciTech Connect

    Campbell, J.A.; Clauss, S.; Grant, K.; Hoopes, V.; Lerner, B.; Lucke, R.; Mong, G.; Rau, J.; Steele, R.

    1994-01-01

    This report describes the status of developing analytical methods to account for the organic constituents in Hanford waste tanks, with particular emphasis on those tanks that have been assigned to the Flammable Gas Watch List. Six samples of core segments from Tank 101-SY, obtained during the window E core sampling, have been analyzed for organic constituents. Four of the samples were from the upper region, or convective layer, of the tank and two were from the lower, nonconvective layer. The samples were analyzed for chelators, chelator fragments, and several carboxylic acids by derivatization gas chromatography/mass spectrometry (GC/MS). The major components detected were ethylenediaminetetraacetic acid (EDTA), nitroso-iminodiacetic acid (NIDA), nitrilotriacetic acid (NTA), citric acid (CA), succinic acid (SA), and ethylenediaminetriacetic acid (ED3A). The chelator of highest concentration was EDTA in all six samples analyzed. Liquid chromatography (LC) was used to quantitate low molecular weight acids (LMWA) including oxalic, formic, glycolic, and acetic acids, which are present in the waste as acid salts. From 23 to 61% of the total organic carbon (TOC) in the samples analyzed was accounted for by these acids. Oxalate constituted approximately 40% of the TOC in the nonconvective layer samples. Oxalate was found to be approximately 3 to 4 times higher in concentration in the nonconvective layer than in the convective layer. During FY 1993, LC methods for analyzing LWMA, and two chelators N-(2-hydroxyethyl) ethylenediaminetriacetic acid and EDTA, were transferred to personnel in the Analytical Chemistry Laboratory and the 222-S laboratory.

  20. Spent N fuel project preliminary saftey evaluation of the cold vacuum drying system -- calculations for the flammable gas ignition scenario

    SciTech Connect

    Scott, D.L.

    1996-06-12

    For a preliminary safety evaluation of the Cold Vacuum Drying System, calculations for the flammable gas ignition scenario are provided. Hydrogen buildup from uranium corrosion in the MCO followed by inadvertent injection of oxygen and the presence of an ignition source leads to hydrogen deflagration that over pressurizes and releases radioactive particulate matter to the environment. The adiabatic flame temperature, MCO pressure and source term are calculated.

  1. Independent design review report for truck {number_sign}1 modifications for flammable gas tanks

    SciTech Connect

    Wilson, G.W.

    1997-05-09

    The East and West Tank Farm Standing Order 97-01 requires that the PMST be modified to include purging of the enclosed space underneath the shielded receiver weather cover per National Fire Protection Association (NFPA) 496, Purged and Pressurized Enclosures for Electrical Equipment. The Standing Order also requires that the PMST be modified by replacing the existing electrical remote latch (RLU) unit with a mechanical remote latch unit. As the mechanical remote latch unit was exactly like the RLU installed on the Rotary Mode Core Sampler Trucks (RMCST) and the design for the RMCST went through formal design review, replacing the RLU was done utilizing informal design verification and was completed per work package ES-97-0028. As the weather cover purge was similar to the design for the RMCSTS, this design was reviewed using the independent review method with multiple independent reviewers. A function design criteria (WHC-SD-WM-FDC-048, Functional Design Criteria for Core Sampling in Flammable Gas Watch List Tanks) provided the criteria for the modifications. The review consisted of distributing the design review package to the reviewers and collecting and dispositioning the RCR comments. The review package included the ECNs for review, the Design Compliance Matrix, copies of all drawings affected, and copies of outstanding ECNs against these drawings. A final meeting was held to ensure that all reviewers were aware of the changes to ECNs from incorporation of RCR comments.

  2. Flammability Indices for Refrigerants

    NASA Astrophysics Data System (ADS)

    Kataoka, Osami

    This paper introduces a new index to classify flammable refrigerants. A question on flammability indices that ASHRAE employs arose from combustion test results of R152a and ammonia. Conventional methods of not only ASHRAE but also ISO and Japanese High-pressure gas safety law to classify the flammability of refrigerants are evaluated to show why these methods conflict with the test results. The key finding of this paper is that the ratio of stoichiometric concentration to LFL concentration (R factor) represents the test results most precisely. In addition, it has excellent correlation with other flammability parameters such as flame speed and pressure rise coefficient. Classification according to this index gives reasonable flammability order of substances including ammonia, R152a and carbon monoxide. Theoretical background why this index gives good correlation is also discussed as well as the insufficient part of this method.

  3. Predicting flammable gas mixtures in Hanford double-contained receiver tanks

    SciTech Connect

    Hedengren, D.C.

    1998-05-13

    This study presents a methodology to estimate the maximum concentrations of flammable gases (ammonia, hydrogen, and methane) which could exist in the vapor space of a double-contained receiver tank (DCRT). DCRTs are temporary storage tanks which receive highly radioactive liquid wastes from salt well pumping of Hanford single-shell tanks (SST). The methodology of this study could be used in other applications involving the storage and transfer of radioactive liquid wastes which generate or contain various dissolved flammable gases.

  4. MELTER OFF-GAS FLAMMABILITY ASSESSMENT FOR DWPF ALTERNATE REDUCTANT FLOWSHEET OPTIONS

    SciTech Connect

    Choi, A.

    2011-07-08

    Glycolic acid and sugar are being considered as potential candidates to substitute for much of the formic acid currently being added to the Defense Waste Processing Facility (DWPF) melter feed as a reductant. A series of small-scale melter tests were conducted at the Vitreous State Laboratory (VSL) in January 2011 to collect necessary data for the assessment of the impact of these alternate reductants on the melter off-gas flammability. The DM10 melter with a 0.021 m{sup 2} melt surface area was run with three different feeds which were prepared at SRNL based on; (1) the baseline formic/nitric acid flowsheet, (2) glycolic/formic/nitric acid flowsheet, and (3) sugar/formic/nitric acid flowsheet - these feeds will be called the baseline, glycolic, and sugar flowsheet feeds, respectively, hereafter. The actual addition of sugar to the sugar flowsheet feed was made at VSL before it was fed to the melter. For each feed, the DM10 was run under both bubbled (with argon) and non-bubbled conditions at varying melter vapor space temperatures. The goal was to lower its vapor space temperature from nominal 500 C to less than 300 C at 50 C increments and maintain steady state at each temperature at least for one hour, preferentially for two hours, while collecting off-gas data including CO, CO{sub 2}, and H{sub 2} concentrations. Just a few hours into the first test with the baseline feed, it was discovered that the DM10 vapor space temperature would not readily fall below 350 C simply by ramping up the feed rate as the test plan called for. To overcome this, ambient air was introduced directly into the vapor space through a dilution air damper in addition to the natural air inleakage occurring at the operating melter pressure of -1 inch H{sub 2}O. A detailed description of the DM10 run along with all the data taken is given in the report issued by VSL. The SRNL personnel have analyzed the DM10 data and identified 25 steady state periods lasting from 32 to 92 minutes for all

  5. Gas box control system for Tandem Mirror Experiment-Upgrade

    SciTech Connect

    Bell, H.H. Jr.; Hunt, A.L.; Clower, C.A. Jr.

    1983-11-14

    The Tandem Mirror Experiment-Upgrade (TMX-U) uses several methods to feed gas (usually deuterium) at different energies into the plasma region of the machine. One is an arrangement of eight high-speed piezo-electric valves mounted on special manifolds (gas box) that feed cold gas directly to the plasma. This paper describes the electronic valve control and data acquisition portions of the gas box, which are controlled by a desk-top computer. Various flow profiles have been developed and stored in the control computer for ready access by the operator. The system uses two modes of operation, one that exercises and characterizes the valves and one that operates the valves with the rest of the experiment. Both the valve control signals and the pressure transducers data are recorded on the diagnostics computer so that they are available for experiment analysis.

  6. The BaBar Gas Bubbler Upgrade and Evaluation

    SciTech Connect

    Gan, Yu; Young, C.; /SLAC

    2005-12-15

    The Instrumented Flux Return region (muon and K{sub L} detection barrel) of the BaBar detector at SLAC requires careful monitoring of the gas flow through the detector array. This is currently done by a system of digital gas bubblers which monitor the flow rate by using photogate technology to detect the presence of bubbles formed by gas flowing through an internal oil chamber. Recently, however, a design flaw was discovered in these bubblers. Because the bubblers are connected directly to the detector array with no filter, during rises in atmospheric pressure or a drop in the gas flow rate (e.g. when the gas system is shut off for maintenance), the oil in this chamber could be forced backwards into the detector tubes. To compensate for this problem, we upgraded the existing gas bubbler systems by installing metal traps into the old gas lines to capture the oil. This installation was followed by an evaluation of the retro-fitted bubblers during which we determined a relationship between the bubble counting rate and the actual gas flow rate, but encountered recurring problems with baseline fluctuations and unstable bubble counting rates. Future work will involve the study of how these instabilities develop, and whether or not they can be mitigated.

  7. Upgrading natural gas by means of highly performing polyimide membranes

    SciTech Connect

    Stern, S.A.

    1993-12-31

    The objective of the present research project is to assess the potential usefulness of membrane separation processes for the removal of acid gases (CO{sub 2} and H{sub 2}S) and H{sub 2}O vapor from low-quality natural gas. The following tasks were performed during the last two years of the project: (1) A laboratory-scale apparatus for measuring the permeability and selectivity of polymer membranes to gas mixtures was built and tested. (2) The permeability and selectivity of seven new polyamide membranes to binary CH{sub 4}/CO{sub 2} and ternary CH{sub 4}/CO{sub 2}/H{sub 2}S mixtures were measured at 95{degrees}F (35{degrees}C) and at ``upstream`` pressures in the range from 58.8 psia to 200 psia (4 atm to 13.6 atm). (3) Gas separation measurements were made using binary CH{sub 4}/CO{sub 2} and ternary CH{sub 4}/CO{sub 2}/H{sub 2}S feed gas mixtures. (4) Process design studies and economic evaluations of membrane processes for upgrading low-quality natural gas were made using the experimentally obtained permeability and selectivity values for the three most promising polyamide membranes. For the sake of comparison, similar studies were made also for cellulose acetate membranes, which are at present being widely used on an industrial scale for the separation of CO{sub 2} from natural gas.

  8. Fuel Flexible Gas Turbine Combustor Flametube Facility Upgraded

    NASA Technical Reports Server (NTRS)

    Little, James E.; Nemets, Steve A.; Tornabene, Robert T.; Smith, Timothy D.; Frankenfeld, Bruce J.

    2004-01-01

    In fiscal year 2003, test cell 23 of the Research Combustion Laboratory (RCL 23) at the NASA Glenn Research Center was upgraded with the addition of gaseous hydrogen as a working propellant and the addition of a 450-psig air-supply system. Test flexibility was further enhanced by upgrades to the facility control systems. RCL 23 can now test with gaseous hydrogen flow rates up to 0.05 lbm/sec and jet fuel flow rates up to 0.62 lbm/sec. Research airflow rates up to 3 lbm/sec are possible with the 450-psig supply system over a range of inlet temperatures. Nonvitiated, heated air is supplied from a shell and tube heat exchanger. The maximum nonvitiated facility air temperature is 1100 F at 1.5 lbm/sec. Research-section exhaust temperatures are limited to 3200 F because of material and cooling capacity limits. A variety of support systems are available depending on the research hardware configuration. Test section ignition can be provided via either a hydrogen air torch system or an electronic spark system. Emissions measurements are obtained with either pneumatically or electromechanically actuated gas sample probes, and the electromechanical system allows for radial measurements at a user-specified axial location for measurement of emissions profiles. Gas analysis data can be obtained for a variety of species, including carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NO and NOx), oxygen (O2), unburnt hydrocarbons, and unburnt hydrogen. Facility control is accomplished with a programmable logic control system. Facility operations have been upgraded to a system based on graphical user interface control screens. A data system is available for real-time acquisition and monitoring of both measurements in engineering units and performance calculations. The upgrades have made RCL 23 a highly flexible facility for research into low emissions gas turbine combustor concepts, and the flame tube configuration inherently allows for a variety of fuel nozzle

  9. Upgrade to the Cryogenic Hydrogen Gas Target Monitoring System

    NASA Astrophysics Data System (ADS)

    Slater, Michael; Tribble, Robert

    2013-10-01

    The cryogenic hydrogen gas target at Texas A&M is a vital component for creating a secondary radioactive beam that is then used in experiments in the Momentum Achromat Recoil Spectrometer (MARS). A stable beam from the K500 superconducting cyclotron enters the gas cell and some incident particles are transmuted by a nuclear reaction into a radioactive beam, which are separated from the primary beam and used in MARS experiments. The pressure in the target chamber is monitored so that a predictable isotope production rate can be assured. A ``black box'' received the analog pressure data and sent RS232 serial data through an outdated serial connection to an outdated Visual Basic 6 (VB6) program, which plotted the chamber pressure continuously. The black box has been upgraded to an Arduino UNO microcontroller [Atmel Inc.], which can receive the pressure data and output via USB to a computer. It has been programmed to also accept temperature data for future upgrade. A new computer program, with updated capabilities, has been written in Python. The software can send email alerts, create audible alarms through the Arduino, and plot pressure and temperature. The program has been designed to better fit the needs of the users. Funded by DOE and NSF-REU Program.

  10. Flammability limits of lithium-ion battery thermal runaway vent gas in air and the inerting effects of halon 1301

    NASA Astrophysics Data System (ADS)

    Karp, Matthew Eugene

    Lithium-ion (rechargeable) and lithium-metal (non-rechargeable) battery cells put aircraft at risk of igniting and fueling fires. Lithium batteries can be packed in bulk and shipped in the cargo holds of freighter aircraft; currently lithium batteries are banned from bulk shipment on passenger aircraft [1]. The federally regulated Class C cargo compartment extinguishing system's utilization of a 5 %vol Halon 1301 knockdown concentration and a sustained 3 %vol Halon 1301 may not be sufficient at inerting lithium-ion battery vent gas and air mixtures [2]. At 5 %vol Halon 1301 the flammability limits of lithium-ion premixed battery vent gas (Li-Ion pBVG) in air range from 13.80 %vol to 26.07 %vol Li-Ion pBVG. Testing suggests that 8.59 %vol Halon 1301 is required to render all ratios of the Li-Ion pBVG in air inert. The lower flammability limit (LFL) and upper flammability limit (UFL) of hydrogen and air mixtures are 4.95 %vol and 76.52 %vol hydrogen, respectively. With the addition of 10 %vol and 20 %vol Halon 1301 the LFL is 9.02 %vol and 11.55 %vol hydrogen, respectively, and the UFL is 45.70 %vol and 28.39 %vol hydrogen, respectively. The minimum inerting concentration (MIC) of Halon 1301 in hydrogen and air mixtures is 26.72 %vol Halon 1301 at 16.2 %vol hydrogen. The LFL and UFL of Li-Ion pBVG and air mixtures are 7.88 %vol and 37.14 %vol Li-Ion pBVG, respectively. With the addition of 5 %vol, 7 %vol, and 8 %vol Halon 1301 the LFL is 13.80 %vol, 16.15 %vol, and 17.62 % vol Li-Ion pBVG, respectively, and the UFL is 26.07 %vol, 23.31 %vol, and 21.84 %vol Li- Ion pBVG, respectively. The MIC of Halon 1301 in Li-Ion pBVG and air mixtures is 8.59 %vol Halon 1301 at 19.52 %vol Li-Ion pBVG. Le Chatelier's mixing rule has been shown to be an effective measure for estimating the flammability limits of Li-Ion pBVGes. The LFL has a 1.79 % difference while the UFL has a 4.53 % difference. The state of charge (SOC) affects the flammability limits in an apparent parabolic

  11. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2004-01-01

    Efforts this quarter have concentrated on field site selection. ChevronTexaco has signed a contract with Kvaerner process Systems for the 50 MM scf/d dehydration skid at their Headlee Gas Plant in Odessa, TX for a commercial-scale test. This will allow the test to go forth. A new test schedule was established with testing beyond the existing contract completion date. Potting and module materials testing continued. Construction of the bench-scale equipment was started. Additional funding to support the test was obtained through a contract with Research Partnership for Secure Energy for America.

  12. GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

    SciTech Connect

    Howard S. Meyer

    2004-04-01

    Efforts this quarter have concentrated on field site selection. ChevronTexaco has signed a contract with Kvaerner process Systems for the 50 MM scf/d dehydration skid at their Headlee Gas Plant in Odessa, TX for a commercial-scale test. This will allow the test to go forth. A new test schedule was established with testing beyond the existing contract completion date. Potting and module materials testing continued. Construction of the bench-scale equipment was started. Additional funding to support the test was obtained through a contract with Research Partnership for Secure Energy for America.

  13. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Girish Srinivas; Steven C. Gebhard; David W. DeBerry

    2001-05-01

    This first quarter report of 2001 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf{trademark} (service mark of Gas Research Institute) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. During this reporting periods new catalyst formulations were tested. The experiments showed that the newest catalyst has slightly better performance, but catalyst TDA No.2 is still superior overall for use with the hybrid CrystaSulf process due to lower costs. Plans for catalyst pelletization and continued testing are described.

  14. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Dennis Dalrymple

    2003-10-01

    This third quarter report of 2003 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and off-shore applications. CrystaSulf{reg_sign} (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant site in west Texas.

  15. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Dennis Dalrymple

    2004-04-01

    This first quarter report of 2004 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and off-shore applications. CrystaSulf{reg_sign} (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane while avoiding methane oxidation and fouling due to coking from other hydrocarbon contaminants. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant site in west Texas.

  16. Evaluation of mitigation strategies in Facility Group 1 double-shell flammable-gas tanks at the Hanford Site

    SciTech Connect

    Unal, C.; Sadasivan, P.; Kubic, W.L.; White, J.R.

    1997-11-01

    Radioactive nuclear waste at the Hanford Site is stored in underground waste storage tanks at the site. The tanks fall into two main categories: single-shell tanks (SSTs) and double-shell tanks (DSTs). There are a total of 149 SSTs and 28 DSTs. The wastes stored in the tanks are chemically complex. They basically involve various sodium salts (mainly nitrite, nitrate, carbonates, aluminates, and hydroxides), organic compounds, heavy metals, and various radionuclides, including cesium, strontium, plutonium, and uranium. The waste is known to generate flammable gas (FG) [hydrogen, ammonia, nitrous oxide, hydrocarbons] by complex chemical reactions. The process of gas generation, retention, and release is transient. Some tanks reach a quasi-steady stage where gas generation is balanced by the release rate. Other tanks show continuous cycles of retention followed by episodic release. There currently are 25 tanks on the Flammable Gas Watch List (FGWL). The objective of this report is to evaluate possible mitigation strategies to eliminate the FG hazard. The evaluation is an engineering study of mitigation concepts for FG generation, retention, and release behavior in Tanks SY-101, AN-103, AN 104, An-105, and Aw-101. Where possible, limited quantification of the effects of mitigation strategies on the FG hazard also is considered. The results obtained from quantification efforts discussed in this report should be considered as best-estimate values. Results and conclusions of this work are intended to help in establishing methodologies in the contractor`s controls selection analysis to develop necessary safety controls for closing the FG unreviewed safety question. The general performance requirements of any mitigation scheme are discussed first.

  17. Flammable gas/slurry growth unreviewed safety question:justification for continued operation for the tank farms at the Hanford site

    SciTech Connect

    Leach, C.E., Westinghouse Hanford

    1996-07-31

    This Justification for Continued Operation (JCO) provides a basis for continued operation in 176 high level waste tanks, double contained receiver tanks (DCRTs), catch tanks, 244-AR Vault, 242-S and 242-T Evaporators and inactive miscellaneous underground storage tanks (IMUSTs) relative to flammable gas hazards. Required controls are specified.

  18. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Girish Srinivas; Steven C. Gebhard; David W. DeBerry

    2001-08-01

    This first quarter report of 2001 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf (service mark of Gas Research Institute) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. During this reporting period tests were done to determine the effect of hydrocarbons such as n-hexane on catalyst performance with and without H{sub 2}S present. The experiments showed that hexane oxidation is suppressed when H{sub 2}S is present. Hexane represents the most reactive of the C1 to C6 series of alkanes. Since hexane exhibits low reactivity under H{sub 2}S oxidation conditions, and more importantly, does not change the

  19. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Girish Srinivas; Steven C. Gebhard; David W. DeBerry

    2002-07-01

    This second quarter report of 2002 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. Previous reports described development of a catalyst with the required selectivity and efficiency for producing sulfur dioxide from H{sub 2}S. In the laboratory, the catalyst was shown to be robust and stable in the presence of several intentionally added contaminants, including condensate from the pilot plant site. This report describes testing using the laboratory apparatus but operated at the pilot plant using the actual pilot plant

  20. A safety assessment of rotary mode core sampling in flammable gas single shell tanks: Hanford Site, Richland, Washington

    SciTech Connect

    Raymond, R.E.

    1996-04-15

    This safety assessment (SA) addresses each of the required elements associated with the installation, operation, and removal of a rotary-mode core sampling (RMCS) device in flammable-gas single-shell tanks (SSTs). The RMCS operations are needed in order to retrieve waste samples from SSTs with hard layers of waste for which push-mode sampling is not adequate for sampling. In this SA, potential hazards associated with the proposed action were identified and evaluated systematically. Several potential accident cases that could result in radiological or toxicological gas releases were identified and analyzed and their consequences assessed. Administrative controls, procedures and design changes required to eliminate or reduce the potential of hazards were identified. The accidents were analyzed under nine categories, four of which were burn scenarios. In SSTS, burn accidents result in unacceptable consequences because of a potential dome collapse. The accidents in which an aboveground burn propagates into the dome space were shown to be in the ``beyond extremely unlikely`` frequency category. Given the unknown nature of the gas-release behavior in the SSTS, a number of design changes and administrative controls were implemented to achieve these low frequencies. Likewise, drill string fires and dome space fires were shown to be very low frequency accidents by taking credit for the design changes, controls, and available experimental and analytical data. However, a number of Bureau of Mines (BOM) tests must be completed before some of the burn accidents can be dismissed with high confidence. Under the category of waste fires, the possibility of igniting the entrapped gases and the waste itself were analyzed. Experiments are being conducted at the BOM to demonstrate that the drill bit is not capable of igniting the trapped gas in the waste. Laboratory testing and thermal analysis demonstrated that, under normal operating conditions, the drill bit will not create high

  1. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Girish Srinivas; Steven C. Gebhard; David W. DeBerry

    2002-04-01

    This first quarter report of 2002 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf{sup SM} (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. In a previous reporting period tests were done to determine the effect of hydrocarbons such as n-hexane on catalyst performance with and without H{sub 2}S present. The experiments showed that hexane oxidation is suppressed when H{sub 2}S is present. Hexane represents the most reactive of the C1 to C6 series of alkanes. Since hexane exhibits low reactivity under H{sub 2}S oxidation conditions, and more importantly, does not change

  2. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Dennis Dalrymple

    2004-06-01

    This final report describes the objectives, technical approach, results and conclusions for a project funded by the U.S. Department of Energy to test a hybrid sulfur recovery process for natural gas upgrading. The process concept is a configuration of CrystaTech, Inc.'s CrystaSulf{reg_sign} process which utilizes a direct oxidation catalyst upstream of the absorber tower to oxidize a portion of the inlet hydrogen sulfide (H{sub 2}S) to sulfur dioxide (SO{sub 2}) and elemental sulfur. This hybrid configuration of CrystaSulf has been named CrystaSulf-DO and represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day and more. This hybrid process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both onshore and offshore applications. CrystaSulf is a nonaqueous sulfur recovery process that removes H{sub 2}S from gas streams and converts it to elemental sulfur. In CrystaSulf, H{sub 2}S in the inlet gas is reacted with SO{sub 2} to make elemental sulfur according to the liquid phase Claus reaction: 2H{sub 2}S + SO{sub 2} {yields} 2H{sub 2}O + 3S. The SO{sub 2} for the reaction can be supplied from external sources by purchasing liquid SO{sub 2} and injecting it into the CrystaSulf solution, or produced internally by converting a portion of the inlet gas H{sub 2}S to SO{sub 2} or by burning a portion of the sulfur produced to make SO{sub 2}. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, the needed SO{sub 2} is produced by placing a bed of direct oxidation catalyst in the inlet gas stream to oxidize a

  3. Flammable Gas Safety Program: Mechanisms of gas generation from simulated SY Tank Farm wastes. Progress report, FY 1994

    SciTech Connect

    Barefield, E.K.; Boadtright, D.; Deshpande, A.; Doctorovich, F.; Liotta, C.L.; Neumann, H.M.; Seymore, S.

    1995-09-01

    This is the final report for work done at Georgia Tech during Fiscal Year 1994. The objectives of this work were to develop a better understanding of the mechanism of formation of flammable gases in the thermal decomposition of metal complexants, such as HEDTA and sodium glycolate, in simulated SY waste mixtures. This project is a continuation of work begun under earlier contracts with Westinghouse Hanford Co. Three major areas are discussed: development of a reliable analysis for dissolved ammonia, the initiation of long term studies of HEDTA decomposition in stainless steel vessels and product analyses through 3800 h, and further consideration of product analyses and kinetic data reported in FY 1993 for decomposition of HEDTA and sodium glycolate in Teflon-lined glass vessels. A brief exploration was also made of the speciation of aluminum(l1l) in the presence of HEDTA as a function of pH using {sup 27}Al NMR.

  4. Interstage Flammability Analysis Approach

    NASA Technical Reports Server (NTRS)

    Little, Jeffrey K.; Eppard, William M.

    2011-01-01

    The Interstage of the Ares I launch platform houses several key components which are on standby during First Stage operation: the Reaction Control System (ReCS), the Upper Stage (US) Thrust Vector Control (TVC) and the J-2X with the Main Propulsion System (MPS) propellant feed system. Therefore potentially dangerous leaks of propellants could develop. The Interstage leaks analysis addresses the concerns of localized mixing of hydrogen and oxygen gases to produce deflagration zones in the Interstage of the Ares I launch vehicle during First Stage operation. This report details the approach taken to accomplish the analysis. Specified leakage profiles and actual flammability results are not presented due to proprietary and security restrictions. The interior volume formed by the Interstage walls, bounding interfaces with the Upper and First Stages, and surrounding the J2-X engine was modeled using Loci-CHEM to assess the potential for flammable gas mixtures to develop during First Stage operations. The transient analysis included a derived flammability indicator based on mixture ratios to maintain achievable simulation times. Validation of results was based on a comparison to Interstage pressure profiles outlined in prior NASA studies. The approach proved useful in the bounding of flammability risk in supporting program hazard reviews.

  5. Gas system Upgrade for the BaBar IFR Detector at SLAC

    SciTech Connect

    Foulkes, S

    2004-07-29

    A new gas distribution and monitoring system was installed as part of an upgrade of the forward endcap muon detection system (IFR) of the BaBar detector at SLAC. Over 300 gas circuits are controlled and monitored. The return gas flow is monitored by digital bubblers which use photo-gate electronics to count the bubbling rate. The rates are monitored in real time and recorded in a history database allowing studies of flow rate versus chamber performance.

  6. Elimination of methane in exhaust gas from biogas upgrading process by immobilized methane-oxidizing bacteria.

    PubMed

    Wu, Ya-Min; Yang, Jing; Fan, Xiao-Lei; Fu, Shan-Fei; Sun, Meng-Ting; Guo, Rong-Bo

    2017-01-13

    Biogas upgrading is essential for the comprehensive utilization of biogas as substitute of natural gas. However, the methane in the biogas can be fully recovered during the upgrading process of biogas, and the exhaust gas produced during biogas upgrading may contain a very low concentration of methane. If the exhaust gas with low concentration methane releases to atmosphere, it will be harmful to environment. In addition, the utilization of large amounts of digestate produced from biogas plant is another important issue for the development of biogas industry. In this study, solid digestate was used to produce active carbon, which was subsequently used as immobilized material for methane-oxidizing bacteria (MOB) in biofilter. Biofilter with MOB immobilized on active carbon was used to eliminate the methane in exhaust gas from biogas upgrading process. Results showed porous active carbon was successfully made from solid digestate. The final methane elimination capacity of immobilized MOB reached about 13molh(-1)m(-3), which was more 4 times higher than that of MOB without immobilization.

  7. NOVEL COMPOSITE MEMBRANES AND PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Ben Bikson; Sal Giglia; Jibin Hao

    2003-03-01

    In the second phase of this project, the newly developed membrane module for natural gas dehydration was tested and evaluated in a pilot plant located at a commercial natural gas treatment site. This phase was undertaken jointly with UOP LLC, our commercialization partner. The field test demonstrated that a commercial-size membrane module for natural gas dehydration was successfully manufactured. The membrane module operated reliably over 1000 psi differential pressure across the membrane in the field test. The effects of feed gas pressure, permeate gas pressure, feed flow rate, purge ratio (flow rate ratio of permeate outlet to feed), and feed gas dew point on the membrane module performance were determined and found to meet the design expectations. Although water vapor permeance was lower than expected, substantial natural gas dehydration was demonstrated with low purge ratio. For example, dew point was suppressed by as much as 30 F with only about 2 {approx} 3% purge ratio. However the bore side pressure drops were significantly higher than the projected value from the fluid dynamic calculation. It is likely that not all the fibers were open in either the sweep or the permeate tube sheet end. This could help to explain the relatively low water vapor permeances that were measured in the field. An economic evaluation of the membrane process and the traditional Triethylene Glycol (TEG) process to dehydrate natural gas was performed and the economics of the two processes were compared. Two sets of membrane module performance properties were used in the economic analysis of the membrane process. One was from the results of this field test and the other from the results of the previous small-scale test with a medium pressure membrane variant conducted at 750 psig. The membrane process was competitive with the TEG process for the natural gas feed flow rate below 10 MMSCFD for the membrane with previously measured water vapor permeance. The membrane process was

  8. Development and Application of a Life Cycle-Based Model to Evaluate Greenhouse Gas Emissions of Oil Sands Upgrading Technologies.

    PubMed

    Pacheco, Diana M; Bergerson, Joule A; Alvarez-Majmutov, Anton; Chen, Jinwen; MacLean, Heather L

    2016-12-20

    A life cycle-based model, OSTUM (Oil Sands Technologies for Upgrading Model), which evaluates the energy intensity and greenhouse gas (GHG) emissions of current oil sands upgrading technologies, is developed. Upgrading converts oil sands bitumen into high quality synthetic crude oil (SCO), a refinery feedstock. OSTUM's novel attributes include the following: the breadth of technologies and upgrading operations options that can be analyzed, energy intensity and GHG emissions being estimated at the process unit level, it not being dependent on a proprietary process simulator, and use of publicly available data. OSTUM is applied to a hypothetical, but realistic, upgrading operation based on delayed coking, the most common upgrading technology, resulting in emissions of 328 kg CO2e/m(3) SCO. The primary contributor to upgrading emissions (45%) is the use of natural gas for hydrogen production through steam methane reforming, followed by the use of natural gas as fuel in the rest of the process units' heaters (39%). OSTUM's results are in agreement with those of a process simulation model developed by CanmetENERGY, other literature, and confidential data of a commercial upgrading operation. For the application of the model, emissions are found to be most sensitive to the amount of natural gas utilized as feedstock by the steam methane reformer. OSTUM is capable of evaluating the impact of different technologies, feedstock qualities, operating conditions, and fuel mixes on upgrading emissions, and its life cycle perspective allows easy incorporation of results into well-to-wheel analyses.

  9. DEVELOPMENT OF AN ANTIFOAM TRACKING SYSTEM AS AN OPTION TO SUPPORT THE MELTER OFF-GAS FLAMMABILITY CONTROL STRATEGY AT THE DWPF

    SciTech Connect

    Edwards, T.; Lambert, D.

    2014-08-27

    The Savannah River National Laboratory (SRNL) has been working with the Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) in the development and implementation of an additional strategy for confidently satisfying the flammability controls for DWPF’s melter operation. An initial strategy for implementing the operational constraints associated with flammability control in DWPF was based upon an analytically determined carbon concentration from antifoam. Due to the conservative error structure associated with the analytical approach, its implementation has significantly reduced the operating window for processing and has led to recurrent Slurry Mix Evaporator (SME) and Melter Feed Tank (MFT) remediation. To address the adverse operating impact of the current implementation strategy, SRR issued a Technical Task Request (TTR) to SRNL requesting the development and documentation of an alternate strategy for evaluating the carbon contribution from antifoam. The proposed strategy presented in this report was developed under the guidance of a Task Technical and Quality Assurance Plan (TTQAP) and involves calculating the carbon concentration from antifoam based upon the actual mass of antifoam added to the process assuming 100% retention. The mass of antifoam in the Additive Mix Feed Tank (AMFT), in the Sludge Receipt and Adjustment Tank (SRAT), and in the SME is tracked by mass balance as part of this strategy. As these quantities are monitored, the random and bias uncertainties affecting their values are also maintained and accounted for. This report documents: 1) the development of an alternate implementation strategy and associated equations describing the carbon concentration from antifoam in each SME batch derived from the actual amount of antifoam introduced into the AMFT, SRAT, and SME during the processing of the batch. 2) the equations and error structure for incorporating the proposed strategy into melter off-gas flammability assessments

  10. Elimination of Flammable Gas Effects in Cerium Oxide Semiconductor-Type Resistive Oxygen Sensors for Monitoring Low Oxygen Concentrations

    PubMed Central

    Itoh, Toshio; Izu, Noriya; Akamatsu, Takafumi; Shin, Woosuck; Miki, Yusuke; Hirose, Yasuo

    2015-01-01

    We have investigated the catalytic layer in zirconium-doped cerium oxide, Ce0.9Zr0.1O2 (CeZr10) resistive oxygen sensors for reducing the effects of flammable gases, namely hydrogen and carbon monoxide. When the concentration of flammable gases is comparable to that of oxygen, the resistance of CeZr10 is affected by the presence of these gases. We have developed layered thick films, which consist of an oxygen sensor layer (CeZr10), an insulation layer (Al2O3), and a catalytic layer consisting of CeZr10 with 3 wt% added platinum, which was prepared via the screen printing method. The Pt-CeZr10 catalytic layer was found to prevent the detrimental effects of the flammable gases on the resistance of the sensor layer. This effect is due to the catalytic layer promoting the oxidation of hydrogen and carbon monoxide through the consumption of ambient O2 and/or the lattice oxygen atoms of the Pt-CeZr10 catalytic layer. PMID:25905705

  11. NOVEL COMPOSITE MEMBRANES AND PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Johann LeRoux

    2002-02-01

    The first phase of this project involved the development of a high performance composite membranes for the treatment of natural gas. The objective of the second phase is to demonstrate the commercial potential of a full-size membrane module in a pilot scale field test. This phase is undertaken jointly with our commercial partner, UOP LLC. At the conclusion of Phase I, two composite membrane products had been developed for the enrichment (sweetening) of natural gas. The one was a low pressure membrane with a high CO{sub 2}/CH{sub 4} separation factor that falls within the target range of 25-30 (at 50 C) set for the program. This is a significant improvement over current commercial membranes that have separation factors of around 18-19. The second membrane had excellent high pressure capability and good contamination resistance, with a separation factor of 20-22. Based on the performance and the economic evaluation of the newly developed membranes, and with the input of UOP and DOE, it was decided to devote the demonstration phase of the program to the field testing and commercial evaluation of natural gas dehydration membranes. Due to the events of September 11, the program was also extended by 6 months until June 30, 2002. In Phase II, UOP has essentially completed preparation of the field test site. Site preparation included the re-design of the test system, purchase and installation of analytical equipment, and making the necessary piping and other hardware changes. IMS has produced two commercial sized dehydration membrane modules for the field tests. These have been successfully tested up to pressures expected in the field tests, and the modules have been shipped to the test site. The remainder of the program will comprise performance testing of the membrane modules, evaluation of the results and submission of the final report with recommendations.

  12. Biological upgrading of coal-derived synthesis gas: Final report

    SciTech Connect

    Barik, S.; Johnson, E.R.; Ko, C.W.; Clausen, E.C.; Gaddy, J.L.

    1986-10-01

    The technical feasibility of the biological conversion of coal synthesis gas to methane has been demonstrated in the University of Arkansas laboratories. Cultures of microorganisms have been developed which achieve total conversion in the water gas shift and methanation reactions in either mixed or pure cultures. These cultures carry out these conversions at ordinary temperatures and pressures, without sulfur toxicity. Several microorganisms have been identified as having commercial potential for producing methane. These include a mixed culture of unidentified bacteria; P. productus which produces acetate, a methane precursor; and Methanothrix sp., which produces methane from acetate. These cultures have been used in mixed reactors and immobilized cell reactors to achieve total CO and H/sub 2/ conversion in a retention time of less than two hours, quite good for a biological reactor. Preliminary economic projections indicate that a biological methanation plant with a size of 5 x 10/sup 10/ Btu/day can be economically attractive. 42 refs., 26 figs., 86 tabs.

  13. Catalyst design for natural-gas upgrading through oxybromination chemistry

    NASA Astrophysics Data System (ADS)

    Paunović, Vladimir; Zichittella, Guido; Moser, Maximilian; Amrute, Amol P.; Pérez-Ramírez, Javier

    2016-08-01

    Natural gas contains large volumes of light alkanes, and its abundant reserves make it an appealing feedstock for value-added chemicals and fuels. However, selectively activating the C-H bonds in these useful hydrocarbons is one of the greatest challenges in catalysis. Here we report an attractive oxybromination method for the one-step functionalization of methane under mild conditions that integrates gas-phase alkane bromination with heterogeneously catalysed HBr oxidation, a step that is usually executed separately. Catalyst-design strategies to provide optimal synergy between these two processes are discussed. Among many investigated material families, vanadium phosphate (VPO) is identified as the best oxybromination catalyst, as it provides selectivity for CH3Br up to 95% and stable operation for over 100 hours on stream. The outstanding performance of VPO is rationalized by its high activity in HBr oxidation and low propensity for methane and bromomethane oxidation. Data on the oxybromination of ethane and propane over VPO suggest that the reaction network for higher alkanes is more complex.

  14. Experimental digester facility modifications and digester gas upgrading research

    SciTech Connect

    Srivastava, V.J.; Biljetina, R.; Akin, C.

    1989-01-01

    The Institute of Gas Technology (IGT) has been participating in an experimental program at the Community Waste Research Facility (CWRF) located at the Walt Disney World Resort Complex, Orlando, Florida. Four institutions have formed a team to provide solutions to community waste treatment and disposal programs. Of primary importance to this research effort is the implementation of low-cost, energy-efficient waste treatment and recovery technologies and the net production of energy (methane) from biomass and waste resources. The production of methane is being studied in a novel, high-rate digester. During 1988, we were responsible for modifying the Experimental Test Unit (ETU) to permit dry solids feeding of refuse-derived fuel (RDF) and for conducting bench-scale experiments to evaluate techniques for efficient removal of carbon dioxide produced during anaerobic digestion.

  15. Effects of outer top gas injection on ICRF coupling in ASDEX Upgrade: towards modelling of ITER gas injection

    NASA Astrophysics Data System (ADS)

    Zhang, W.; Bobkov, V.; Noterdaeme, J.-M.; Tierens, W.; Bilato, R.; Carralero, D.; Coster, D.; Jacquot, J.; Jacquet, P.; Lunt, T.; Pitts, R. A.; Rohde, V.; Siegl, G.; Fuenfgelder, H.; Aguiam, D.; Silva, A.; Colas, L.; Ceccuzzi, S.; the ASDEX Upgrade Team

    2017-07-01

    The influence of outer top gas injection on the scrape-off layer (SOL) density and ion cyclotron range of frequency (ICRF) coupling has been studied in ASDEX Upgrade (AUG) L-mode plasmas for the first time. The three-dimensional (3D) edge plasma fluid and neutral transport code EMC3-EIRENE is used to simulate the SOL plasma density, and the 3D wave code RAPLICASOL is used to compute the ICRF coupling resistance with the calculated density. Improvements have been made in the EMC3-EIRENE simulations by fitting transport parameters separately for each gas puffing case. It is found that the calculated local density profiles and coupling resistances are in good agreement with the experimental ones. The results indicate that the SOL density increase depends sensitively on the spreading of the injected outer top gas. If more gas enters into the main chamber through the paths near the top of vessel, the SOL density increase will be more toroidally uniform; if more gas chooses the paths closer to the mid-plane, then the SOL density increase will be more local and more significant. Among the various local gas puffing methods, the mid-plane gas valve close to the antenna is still the best option in terms of improving ICRF coupling. Differences between the outer top gas puffing in AUG and the outer top gas puffing in ITER are briefly summarized. Instructive suggestions for ITER and future plans for ITER gas injection simulations are discussed.

  16. Field tests prove microscale NRU to upgrade low-btu gas

    USGS Publications Warehouse

    Bhattacharya, S.; David, Newell K.; Lynn, Watney W.; Sigel, M.

    2009-01-01

    The Kansas Geological Survey (University of Kansas) and the American Energies Corp., Wichita, have conducted field tests of a scalable, microscale, N2-rejection unit (NRU) to demonstrate its effectiveness to upgrade low-pressure ((<100 psig) and low-volume (=100 Mcfd) low-btu gas to pipeline quality. The tests aim to develop inexpensive NRU technology, which is designed for low- volume, low-pressure gas wells, to significantly increase the contribution of marginal low-btu gas to the gas supply of the US. The NRU uses two towers and uses three stages, namely, adsorption under pressure, venting to 2 psig, and desorption under vacuum. The modular design allows additional sets of towers to be added or removed to handle increases or decreases in feed volumes. The field tests also reveal that a strong compressor, which is capable of evacuating the tower (volume) as quickly as possible, should be employed to reduce process cycle time and increase plant throughput.

  17. Flammability: A Review and Analysis

    NASA Technical Reports Server (NTRS)

    Wilson, D. Bruce; Steinberg, Theodore A.; Stoltzfus, Joel M.; Fries, Joseph (Technical Monitor)

    2000-01-01

    With its founding in 1975, Committee G-4 of the American Society for Testing and Materials (ASTM) embarked on the process of defining the flammability of metallic materials in oxygen-enriched atmospheres. In this process, they are joined by the National Aeronautics and Space Administration (NASA), the National Fire Protection Association (NFPA), and the Compressed Gas Association (CGA). Although none of these organizations has explicitly defined flammability, the following definitions and statements provide a composite understanding of the concept: 1. "This Standard Guide (ASTM G94-92) is concerned primarily with the properties of a material associated with its relative susceptibility to ignition and propagation of combustion." 2. "A material is considered flammable at the maximum use pressure if at least one sample burns more than 6 in. (15.2 cm). At least, five samples must be tested." NASA 3. "Flammable: Capable, when ignited of maintaining combustion under the specified environmental conditions." NFPA 53. 4. "Combustion: A complex sequence of chemical reactions between a fuel and an oxidant accompanied by the evolution of heat, and usually, the emission of light." NFPA 53. and 5. "A safe oxygen-piping transmission or distribution system is one that is designed and installed in accordance with all applicable codes and regulations for the service conditions and locations involved and further meets the special requirements for oxygen services." CGA-G4 Flammability thus equates, after ignition, to propagation of combustion, synonymous with steady state burning, under specified environmental conditions. Properties for which quantitative values are given in ASTM G94-92 and which are used to describe metals flammability consistent with the concept of steady state burning are either system independent properties, such as, enthalpies of reaction, burn ratios, flame temperatures, thermal conductivity, and heat release; or system dependent properties, such as, oxygen

  18. Disruption mitigation by injection of small quantities of noble gas in ASDEX Upgrade

    NASA Astrophysics Data System (ADS)

    Pautasso, G.; Bernert, M.; Dibon, M.; Duval, B.; Dux, R.; Fable, E.; Fuchs, J. C.; Conway, G. D.; Giannone, L.; Gude, A.; Herrmann, A.; Hoelzl, M.; McCarthy, P. J.; Mlynek, A.; Maraschek, M.; Nardon, E.; Papp, G.; Potzel, S.; Rapson, C.; Sieglin, B.; Suttrop, W.; Treutterer, W.; The ASDEX Upgrade Team; The EUROfusion MST1 Team

    2017-01-01

    The most recent experiments of disruption mitigation by massive gas injection in ASDEX Upgrade have concentrated on small—relatively to the past—quantities of noble gas injected, and on the search for the minimum amount of gas necessary for the mitigation of the thermal loads on the divertor and for a significant reduction of the vertical force during the current quench. A scenario for the generation of a long-lived runaway electron beam has been established; this allows the study of runaway current dissipation by moderate quantities of argon injected. This paper presents these recent results and discusses them in the more general context of physical models and extrapolation, and of the open questions, relevant for the realization of the ITER disruption mitigation system.

  19. Upgrading producer gas quality from rubber wood gasification in a radio frequency tar thermocatalytic treatment reactor.

    PubMed

    Anis, Samsudin; Zainal, Z A

    2013-12-01

    This study focused on improving the producer gas quality using radio frequency (RF) tar thermocatalytic treatment reactor. The producer gas containing tar, particles and water was directly passed at a particular flow rate into the RF reactor at various temperatures for catalytic and thermal treatments. Thermal treatment generates higher heating value of 5.76 MJ Nm(-3) at 1200°C. Catalytic treatments using both dolomite and Y-zeolite provide high tar and particles conversion efficiencies of about 97% on average. The result also showed that light poly-aromatic hydrocarbons especially naphthalene and aromatic compounds particularly benzene and toluene were still found even at higher reaction temperatures. Low energy intensive RF tar thermocatalytic treatment was found to be effective for upgrading the producer gas quality to meet the end user requirements and increasing its energy content.

  20. Upgrade to the Gas Puff Imaging Diagnostic that Views Alcator C-Mod's Inboard Edge

    NASA Astrophysics Data System (ADS)

    Sierchio, J. M.; Terry, J. L.

    2012-10-01

    We describe an upgrade of Alcator C-Mod's Gas Puff Imaging system which views the inboard plasma edge and SOL along lines-of-sight that are approximately parallel to the local magnetic field. The views are arranged in a 2D (R,Z) array with ˜2.8 cm radial coverage and ˜2.4 cm poloidal coverage. 23 of 54 available views were coupled via fibers to individual interference filters and PIN photodiode detectors. We are in the process of upgrading the system in order to increase the sensitivity of the system by replacing the PIN photodiodes with a 4x8 array of Avalanche Photo-Diodes (APD). Light from 30 views is coupled to the single-chip APD array through a single interference filter. We expect an improvement in signal-to-noise ratio of more than 10x. The frequency response of the system will increase from ˜400 kHz to 1MHz. The dynamic range of the new system is manipulated by changing the high-voltages on the APDs. Test results of the detectors' channel-to-channel cross-talk, frequency response, and gain curves will be presented, along with schematics of the experimental setup. The upgraded system allows for more study of inboard edge fluctuations, including whether the quasi-coherent fluctuations observed in the outboard edge also exist inboard.

  1. Assembly and Quality Assurance Tests of Gas Gaps for the PHENIX Muon Trigger Upgrade

    NASA Astrophysics Data System (ADS)

    Broxmeyer, David

    2008-10-01

    The RHIC ``spin'' program investigates the spin of a proton by looking at collisions between polarized protons. W bosons are sometimes created in these collisions. The parity violating decay of W bosons can be used to identify the underlying quark-quark and quark-antiquark interaction. The PHENIX muon trigger upgrade will utilize resistive plate chambers (RPCs) to distinguish the muons that decay from W bosons from other muons. The RPCs use 95% Freon 134A, 4.5% isobutene, and 0.5% sulfur hexafluoride (SF6). In order for these gas gaps to be used, checks are performed on the gaps. The gas gaps must contain no leaks. Approximately 10kV are placed across the 2mm gaps and therefore the gaps require spacers to insure that there is uniform separation between the surfaces. Popped spacer tests are performed to insure that the spacers are properly attached.

  2. Transport simulations of the pre-thermal-quench phase in ASDEX Upgrade massive gas injection experiments

    NASA Astrophysics Data System (ADS)

    Fable, E.; Pautasso, G.; Lehnen, M.; Dux, R.; Bernert, M.; Mlynek, A.; the ASDEX Upgrade Team

    2016-02-01

    The pre-thermal-quench (PTQ) phase of the massive gas injection (MGI) scenario to terminate the tokamak plasma discharge is studied by means of one-dimensional (1D) transport simulations. This phase is characterized by the cold-front penetration in the hot plasma after the gas has been released from the valves, and before the actual thermal quench takes place, with consequent plasma disruption at lower stored energy. The comparison between the simulations and the ASDEX Upgrade (AUG) experiments allows to gain insight in the observed dependencies and time scales. Despite the genuine three-dimensional structure of the problem, it is shown that the 1D simulations are already giving experimentally relevant answers, the reason for which will be discussed in detail. Influence of unknown parameters and simplifying assumptions are also discussed.

  3. Upgrading low-quality natural gas by means of highly performing polymer membranes

    SciTech Connect

    Stern, S.A.

    1995-04-01

    The objective of the present study is to assess the potential usefulness of membrane separation processes for removing acid gases (CO{sub 2} and H{sub 2}S) from low-quality natural gas. Nonporous {open_quotes}dense{close_quotes} (homogeneous) membranes made from new, highly gas-selective polymers are being evaluated for this purpose. The project comprises gas permeability and separation measurements with CH{sub 4}/CO{sub 2} and CH{sub 4}/CO{sub 2}/H{sub 2}S mixtures having compositions in ranges found in low-quality natural gas. Process design studies and economic evaluations are also being made to determine the cost of upgrading low-quality natural gas with the most promising membranes. Until recently, the membranes used in this study were made from new types of polyimides synthesized in our laboratory. The polyimide membranes were found to exhibit a very high CO{sub 2}/CH{sub 4} selectivity but a relatively low H{sub 2}S/CH{sub 4} selectivity. Therefore, different types of polymers that exhibit a high H{sub 2}S/CH{sub 4} selectivity are also being evaluated.

  4. Is Your Furniture Flammable?

    ERIC Educational Resources Information Center

    Crump, Eva

    1982-01-01

    A flammability standard for upholstered furniture is intended to prevent furniture from becoming a major contributing factor to a fire or from generating toxic fumes. Advice is offered on how to set a flammability standard and how to apply it. (Author/MLF)

  5. Catalytically upgraded landfill gas as a cost-effective alternative for fuel cells

    NASA Astrophysics Data System (ADS)

    Urban, W.; Lohmann, H.; Gómez, J. I. Salazar

    The potential use of landfill gas as feeding fuel for the so-called molten carbonate fuel cells (MCFC) imposes the need for new upgrading technologies in order to meet the much tougher feed gas specifications of this type of fuel cells in comparison to gas engines. Nevertheless, MCFC has slightly lower purity demands than low temperature fuel cells. This paper outlines the idea of a new catalytic purification process for landfill gas conditioning, which may be supposed to be more competitive than state-of-the-art technologies and summarises some lab-scale results. This catalytic process transforms harmful landfill gas minor compounds into products that can be easily removed from the gas stream by a subsequent adsorption step. The optimal process temperature was found to be in the range 250-400 °C. After a catalyst screening, two materials were identified, which have the ability to remove all harmful minor compounds from landfill gas. The first material was a commercial alumina that showed a high activity towards the removal of organic silicon compounds. The alumina protects both a subsequent catalyst for the removal of other organic minor compounds and the fuel cell. Due to gradual deactivation caused by silica deposition, the activated alumina needs to be periodically replaced. The second material was a commercial V 2O 5/TiO 2-based catalyst that exhibited a high activity for the total oxidation of a broad spectrum of other harmful organic minor compounds into a simpler compound class "acid gases (HCl, HF and SO 2)", which can be easily removed by absorption with, e.g. alkalised alumina. The encouraging results obtained allow the scale-up of this LFG conditioning process to test it under real LFG conditions.

  6. Oxygen speciation in upgraded fast pyrolysis bio-oils by comprehensive two-dimensional gas chromatography.

    PubMed

    Omais, Badaoui; Crepier, Julien; Charon, Nadège; Courtiade, Marion; Quignard, Alain; Thiébaut, Didier

    2013-04-21

    Biomass fast pyrolysis is considered as a promising route to produce liquid for the transportation field from a renewable resource. However, the derived bio-oils are mainly oxygenated (45-50%w/w O on a wet basis) and contain almost no hydrocarbons. Therefore, upgrading is necessary to obtain a liquid with lower oxygen content and characterization of oxygenated compounds in these products is essential to assist conversion reactions. For this purpose, comprehensive two-dimensional gas chromatography (GC × GC) can be investigated. Oxygen speciation in such matrices is hampered by the large diversity of oxygenated families and the complexity of the hydrocarbon matrix. Moreover, response factors must be taken into account for oxygenate quantification as the Flame Ionisation Detector (FID) response varies when a molecule contains heteroatoms. To conclude, no distillation cuts were accessible and the analysis had to cover a large range of boiling points (30-630 °C). To take up this analytical challenge, a thorough optimization approach was developed. In fact, four GC × GC column sets were investigated to separate oxygenated compounds from the hydrocarbon matrix. Both model mixtures and the upgraded biomass flash pyrolysis oil were injected using GC × GC-FID to reach a suitable chromatographic separation. The advantages and drawbacks of each column combination for oxygen speciation in upgraded bio-oils are highlighted in this study. Among the four sets, an original polar × semi-polar column combination was selected and enabled the identification by GC × GC-ToF/MS of more than 40 compounds belonging to eight chemical families: ketones, furans, alcohols, phenols, carboxylic acids, guaiacols, anisols, and esters. For quantification purpose, the GC × GC-FID chromatogram was divided into more than 60 blobs corresponding to the previously identified analyte and hydrocarbon zones. A database associating each blob to a molecule and its specific response factor (determined

  7. Aqueous extractive upgrading of bio-oils created by tail-gas reactive pyrolysis to produce pure hydrocarbons and phenols

    USDA-ARS?s Scientific Manuscript database

    Tail-gas reactive pyrolysis (TGRP) of biomass produces bio-oil that is lower in oxygen (~15 wt% total) and significantly more hydrocarbon-rich than traditional bio-oils or even catalytic fast pyrolysis. TGRP bio-oils lend themselves toward mild and inexpensive upgrading procedures. We isolated oxyge...

  8. Impact of a pulsed supersonic deuterium gas jet on the ELM behaviour in ASDEX Upgrade

    NASA Astrophysics Data System (ADS)

    Lang, P. T.; Neuhauser, J.; Bucalossi, J.; Chankin, A.; Coster, D. P.; Drube, R.; Dux, R.; Haas, G.; Horton, L. D.; Kalvin, S.; Kocsis, G.; Maraschek, M.; Mertens, V.; Rohde, V.; Rozhansky, V.; Schneider, R.; Senichenkov, I.; Veselova, I.; Wolfrum, E.; ASDEX Upgrade Team

    2005-09-01

    The possibility for pacing of type-I edge localized modes (ELMs) in H-mode plasmas by intermittent gas injection was investigated in ASDEX Upgrade as a possible alternative to, and in comparison with, ELM control by pellets. A Laval nozzle type molecular deuterium injector was used, delivering 1.7 ms long jets with up to about 1020D per pulse at a supersonic flow velocity of 2.2 km s-1. With a repetition rate of 2 Hz and a fast rise time of ap25 µs, comparable to typical ELM rise times, the injector seemed to be well-suited for single ELM trigger tests. When applied to H-mode discharges with a moderate type-I ELM frequency of 40-60 Hz, no prompt (<0.5 ms) ELM triggering could be achieved, in contrast to the experience with pellets. There was, however, clear evidence for a delayed effect in the form of an inverse correlation of the gas pulse amplitude with the time interval between the gas pulse and the next ELM. The apparent lack of prompt ELM triggering seems to be due to a self-blocking of the gas jet by an extremely fast formation of a high density plasma layer in the separatrix vicinity, while the delayed effect may be simply caused by the jet-induced axisymmetric edge profile modification, similar to the delayed ELM cascade observed after a prompt ELM in case of large pellet injection. The delayed trigger effect observed might still be useful for ELM control in future machines, but the related high gas fuelling at elevated pulse frequency could make it unattractive in view of overall plasma performance.

  9. Influence of gas injection location and magnetic perturbations on ICRF antenna performance in ASDEX Upgrade

    SciTech Connect

    Bobkov, V.; Bilato, R.; Dux, R.; Faugel, H.; Kallenbach, A.; Müller, H. W.; Potzel, S.; Pütterich, Th.; Suttrop, W.; Stepanov, I.; Noterdaeme, J.-M.; Jacquet, P.; Monakhov, I.; Czarnecka, A.; Collaboration: ASDEX Upgrade Team

    2014-02-12

    In ASDEX Upgrade H-modes with H{sub 98}≈0.95, similar effect of the ICRF antenna loading improvement by local gas injection was observed as previously in L-modes. The antenna loading resistance R{sub a} between and during ELMs can increase by more than 25% after a switch-over from a deuterium rate of 7.5⋅10{sup 21} D/s injected from a toroidally remote location to the same amount of deuterium injected close to an antenna. However, in contrast to L-mode, this effect is small in H-mode when the valve downstream w.r.t. parallel plasma flows is used. In L-mode, a non-linearity of R{sub a} at P{sub ICRP}<30 kW is observed when using the gas valve integrated in antenna. Application of magnetic perturbations (MPs) in H-mode discharges leads to an increase of R{sub a}>30% with no effect of spectrum and phase of MPs on R{sub a} found so far. In the case ELMs are fully mitigated, the antenna loading is higher and steadier. In the case ELMs are not fully mitigated, the value of R{sub a} between ELMs is increased. Looking at the W source modification for the improved loading, the local gas injection is accompanied by decreased values of tungsten (W) influx Γ{sub W} from the limiters and its effective sputtering yield Y{sub w}, with the exception of the locations directly at the antenna gas valve. Application of MPs leads to increase of Γ{sub W} and Y{sub w} for some of the MP phases. With nitrogen seeding in the divertor, ICRF is routinely used to avoid impurity accumulation and that despite enhanced Γ{sub W} and Y{sub W} at the antenna limiters.

  10. An acid-gas removal system for upgrading subquality natural gas

    SciTech Connect

    Palla, N.; Lee, A.L.; Leppin, D.; Shoemaker, H.D.; Hooper, H.M.; Emmrich, G.; Moore, T.F.

    1996-09-01

    The objective of this project is to develop systems to reduce the cost of treating subquality natural gas. Based on over 1,000 laboratory experiments on vapor-liquid equilibria and mass transfer and simulation studies, the use of N-Formyl Morpholine as a solvent together with structured packings has the following advantages: high capacity for H{sub 2}S and CO{sub 2} removal; little or no refrigeration required; less loss of hydrocarbons (CH{sub 4}, C{sub 2}-C{sub 6}); and dehydration potential. To verify these findings and to obtain additional data base for scale-up, a field test unit capable of processing 1MMSCF/d of natural gas has been installed at the Shell Western E and P Inc. (SWEPI) Fandango processing plant site. The results of the testing at the Fandango site will be presented when available.

  11. Simulations of gas puff effects on edge density and ICRF coupling in ASDEX upgrade using EMC3-Eirene

    SciTech Connect

    Zhang, W.; Lunt, T.; Bobkov, V.; Coster, D.; Brida, D.; Noterdaeme, J.-M.; Jacquet, P.; Feng, Y.

    2015-12-10

    Simulations were carried out with the 3D plasma transport code EMC3-EIRENE, to study the deuterium gas (D{sub 2}) puff effects on edge density and the coupling of Ion Cyclotron Range of Frequency (ICRF) power in ASDEX Upgrade. Firstly we simulated an inter-ELM phase of an H-mode discharge with a moderate (1.2 × 10{sup 22} electrons/s) lower divertor gas puff. Then we changed the gas source positions to the mid-plane or top of machine while keeping other conditions the same. Cases with different mid-plane or top gas valves are investigated. Our simulations indicate that compared to lower divertor gas puffing, the mid-plane gas puff can enhance the local density in front of the antennas most effectively, while a rather global (toroidally uniform) but significantly smaller enhancement is found for top gas puffing. Our results show quantitative agreement with the experiments.

  12. Flammability Assessment Methodology Program Phase I: Final Report

    SciTech Connect

    C. A. Loehr; S. M. Djordjevic; K. J. Liekhus; M. J. Connolly

    1997-09-01

    The Flammability Assessment Methodology Program (FAMP) was established to investigate the flammability of gas mixtures found in transuranic (TRU) waste containers. The FAMP results provide a basis for increasing the permissible concentrations of flammable volatile organic compounds (VOCs) in TRU waste containers. The FAMP results will be used to modify the ''Safety Analysis Report for the TRUPACT-II Shipping Package'' (TRUPACT-II SARP) upon acceptance of the methodology by the Nuclear Regulatory Commission. Implementation of the methodology would substantially increase the number of drums that can be shipped to the Waste Isolation Pilot Plant (WIPP) without repackaging or treatment. Central to the program was experimental testing and modeling to predict the gas mixture lower explosive limit (MLEL) of gases observed in TRU waste containers. The experimental data supported selection of an MLEL model that was used in constructing screening limits for flammable VOC and flammable gas concentrations. The MLEL values predicted by the model for individual drums will be utilized to assess flammability for drums that do not meet the screening criteria. Finally, the predicted MLEL values will be used to derive acceptable gas generation rates, decay heat limits, and aspiration time requirements for drums that do not pass the screening limits. The results of the program demonstrate that an increased number of waste containers can be shipped to WIPP within the flammability safety envelope established in the TRUPACT-II SARP.

  13. Overview of the Flammability of Gases Generated in Hanford Waste Tanks

    SciTech Connect

    LA Mahoney; JL Huckaby; SA Bryan; GD Johnson

    2000-07-21

    This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, the flammability and detonability limits of the gas constituents, and the availability of ignition sources. The intrinsic flammability (or nonflammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, volume of the release, and the tank ventilation rate, which are not covered in this report.

  14. Flammability limits of fuel/fluorocarbon azeotropes

    SciTech Connect

    Alvares, N.J.; Hammond, P.R.; Foote, K.; Ford, H.W. Jr.

    1981-02-10

    Both Dehn and Thorne have intimated that flash point (FP) measurements could be used to define the gas-phase flammability limits of fire and retardant vapor mixtures above the surface of heated retardant containing flammable liquids. However, it was found that ignitable mixtures exist above the liquid surface, where the concentration of the agent in the fluid is well beyond the limiting concentrating for inerting of alcohol fires. Clearly this anomaly results from diffusion competition of air and liquid vapor mixture at the position of the ignitor, as influenced by the design of the experimental apparatus. The authors are skeptical about the need or worth of attempting to define flammability limits using FP data, especially since unknown variables control the response. More important is to define the concentration of liquid phase retardant that will affect gas phase inerting. Thus, it is necessary to continue practical testing of retardant-containing liquids for their effectiveness in mitigating possible accidents, e.g., the next phase of this work will assess the effectiveness of halocarbons to inert high-pressure alcohol/agent leaks impinging on both electrical and flame ignition sources.

  15. Test results of the Chrysler upgraded automotive gas turbine engine: Initial design

    NASA Technical Reports Server (NTRS)

    Horvath, D.; Ribble, G. H., Jr.; Warren, E. L.; Wood, J. C.

    1981-01-01

    The upgraded engine as built to the original design was deficient in power and had excessive specific fuel consumption. A high instrumented version of the engine was tested to identify the sources of the engine problems. Analysis of the data shows the major problems to be low compressor and power turbine efficiency and excessive interstage duct losses. In addition, high HC and CO emission were measured at idle, and high NOx emissions at high energy speeds.

  16. Test results of the Chrysler upgraded automotive gas turbine engine: Initial design

    NASA Astrophysics Data System (ADS)

    Horvath, D.; Ribble, G. H., Jr.; Warren, E. L.; Wood, J. C.

    1981-07-01

    The upgraded engine as built to the original design was deficient in power and had excessive specific fuel consumption. A high instrumented version of the engine was tested to identify the sources of the engine problems. Analysis of the data shows the major problems to be low compressor and power turbine efficiency and excessive interstage duct losses. In addition, high HC and CO emission were measured at idle, and high NOx emissions at high energy speeds.

  17. Control of Materials Flammability Hazards

    NASA Technical Reports Server (NTRS)

    Griffin, Dennis E.

    2003-01-01

    This viewgraph presentation provides information on selecting, using, and configuring spacecraft materials in such a way as to minimize the ability of fire to spread onboard a spacecraft. The presentation gives an overview of the flammability requirements of NASA-STD-6001, listing specific tests and evaluation criteria it requires. The presentation then gives flammability reduction methods for specific spacecraft items and materials.

  18. 46 CFR 153.465 - Flammable vapor detector.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Flammable vapor detector. 153.465 Section 153.465 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Design and Equipment Special...

  19. Thermodynamic modelling of an onsite methanation reactor for upgrading producer gas from commercial small scale biomass gasifiers.

    PubMed

    Vakalis, S; Malamis, D; Moustakas, K

    2017-06-26

    Small scale biomass gasifiers have the advantage of having higher electrical efficiency in comparison to other conventional small scale energy systems. Nonetheless, a major drawback of small scale biomass gasifiers is the relatively poor quality of the producer gas. In addition, several EU Member States are seeking ways to store the excess energy that is produced from renewables like wind power and hydropower. A recent development is the storage of energy by electrolysis of water and the production of hydrogen in a process that is commonly known as "power-to-gas". The present manuscript proposes an onsite secondary reactor for upgrading producer gas by mixing it with hydrogen in order to initiate methanation reactions. A thermodynamic model has been developed for assessing the potential of the proposed methanation process. The model utilized input parameters from a representative small scale biomass gasifier and molar ratios of hydrogen from 1:0 to 1:4.1. The Villar-Cruise-Smith algorithm was used for minimizing the Gibbs free energy. The model returned the molar fractions of the permanent gases, the heating values and the Wobbe Index. For mixtures of hydrogen and producer gas on a 1:0.9 ratio the increase of the heating value is maximized with an increase of 78%. For ratios higher than 1:3, the Wobbe index increases significantly and surpasses the value of 30 MJ/Nm(3). Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. 46 CFR 153.515 - Special requirements for extremely flammable cargoes.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Special requirements for extremely flammable cargoes... and Equipment Special Requirements § 153.515 Special requirements for extremely flammable cargoes... inerting system that meets the requirements in § 153.500 applying to the inert gas system of a...

  1. Upgraded automotive gas turbine engine design and development program, volume 2

    NASA Technical Reports Server (NTRS)

    Wagner, C. E. (Editor); Pampreen, R. C. (Editor)

    1979-01-01

    Results are presented for the design and development of an upgraded engine. The design incorporated technology advancements which resulted from development testing on the Baseline Engine. The final engine performance with all retro-fitted components from the development program showed a value of 91 HP at design speed in contrast to the design value of 104 HP. The design speed SFC was 0.53 versus the goal value of 0.44. The miss in power was primarily due to missing the efficiency targets of small size turbomachinery. Most of the SFC deficit was attributed to missed goals in the heat recovery system relative to regenerator effectiveness and expected values of heat loss. Vehicular fuel consumption, as measured on a chassis dynamometer, for a vehicle inertia weight of 3500 lbs., was 15 MPG for combined urban and highway driving cycles. The baseline engine achieved 8 MPG with a 4500 lb. vehicle. Even though the goal of 18.3 MPG was not achieved with the upgraded engine, there was an improvement in fuel economy of 46% over the baseline engine, for comparable vehicle inertia weight.

  2. Flammability of photovoltaic modules

    NASA Technical Reports Server (NTRS)

    Sugimura, R. S.; Otth, D. H.; Ross, R. G., Jr.; Lewis, K. J.; Arnett, J. C.

    1984-01-01

    A series of Class B burning-brand tests were performed on experimental modules using high-temperature, back-surface materials to develop the technology base required to construct fire-ratable modules. Results indicate the existence of synergistic relationships between hydrocarbon encapsulation materials and the experimental module configurations that provide increased fire resistance. These configurations use Kapton, fiberglass, neoprene rubber, stainless-steel foil or aluminum foil as the back surface. Successful test results occur when the structural integrity of the module back surface is maintained. Test failures of these modules always occur for one of three reasons: the outermost back cover melts, rips, or is too porous. In each case flammable molten encapsulant, its gaseous byproducts, or both, penetrates the back surface of the module and bursts into flame. Future efforts to complete the technology base will concentrate on the spread-of-flame test, focusing on the more promising configurations identified in the initial series of tests.

  3. Flammability of photovoltaic modules

    NASA Astrophysics Data System (ADS)

    Sugimura, R. S.; Otth, D. H.; Ross, R. G., Jr.; Lewis, K. J.; Arnett, J. C.

    A series of Class B burning-brand tests were performed on experimental modules using high-temperature, back-surface materials to develop the technology base required to construct fire-ratable modules. Results indicate the existence of synergistic relationships between hydrocarbon encapsulation materials and the experimental module configurations that provide increased fire resistance. These configurations use Kapton, fiberglass, neoprene rubber, stainless-steel foil or aluminum foil as the back surface. Successful test results occur when the structural integrity of the module back surface is maintained. Test failures of these modules always occur for one of three reasons: the outermost back cover melts, rips, or is too porous. In each case flammable molten encapsulant, its gaseous byproducts, or both, penetrates the back surface of the module and bursts into flame. Future efforts to complete the technology base will concentrate on the spread-of-flame test, focusing on the more promising configurations identified in the initial series of tests.

  4. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING LAST TECHNICAL REPORT BEFORE NOVATION FROM URS CORP. TO CRYSTATECH, INC.

    SciTech Connect

    Girish Srinivas; Steven C. Gebhard; David W. DeBerry

    2001-02-01

    This project was funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf (service mark of Gas Research Institute) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane while avoiding methane oxidation. The project involved the development of a detailed plan for laboratory and bench scale-up application, laboratory/bench-scale catalyst testing, and demonstration of scale-up economic advantages. The bench-scale tests examined two different catalysts that are promoted modifications of TDA's patented partial oxidation catalyst used to make elemental sulfur. The experiments showed that catalyst TDA No.2 is superior for use with the hybrid CrystaSulf process in that much higher yields of SO{sub 2} can be obtained. Continued testing is planned.

  5. Simultaneous valorization and biocatalytic upgrading of heavy vacuum gas oil by the biosurfactant-producing Pseudomonas aeruginosa AK6U.

    PubMed

    Ismail, Wael Ahmed; Mohamed, Magdy El-Said; Awadh, Maysoon N; Obuekwe, Christian; El Nayal, Ashraf M

    2017-07-11

    Heavy vacuum gas oil (HVGO) is a complex and viscous hydrocarbon stream that is produced as the bottom side product from the vacuum distillation units in petroleum refineries. HVGO is conventionally treated with thermochemical process, which is costly and environmentally polluting. Here, we investigate two petroleum biotechnology applications, namely valorization and bioupgrading, as green approaches for valorization and upgrading of HVGO. The Pseudomonas aeruginosa AK6U strain grew on 20% v/v of HVGO as a sole carbon and sulfur source. It produced rhamnolipid biosurfactants in a growth-associated mode with a maximum crude biosurfactants yield of 10.1 g l(-1) , which reduced the surface tension of the cell-free culture supernatant to 30.6 mN m(-1) within 1 week of incubation. The rarely occurring dirhamnolipid Rha-Rha-C12 -C12 dominated the congeners' profile of the biosurfactants produced from HVGO. Heavy vacuum gas oil was recovered from the cultures and abiotic controls and the maltene fraction was extracted for further analysis. Fractional distillation (SimDist) of the biotreated maltene fraction showed a relative decrease in the high-boiling heavy fuel fraction (BP 426-565 °C) concomitant with increase in the lighter distillate diesel fraction (BP 315-426 °C). Analysis of the maltene fraction revealed compositional changes. The number-average (Mn) and weight-average (Mw) molecular weights, as well as the absolute number of hydrocarbons and sulfur heterocycles were higher in the biotreated maltene fraction of HVGO. These findings suggest that HVGO can be potentially exploited as a carbon-rich substrate for production of the high-value biosurfactants by P. aeruginosa AK6U and to concomitantly improve/upgrade its chemical composition. © 2017 The Authors. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

  6. Hydroquinone and Quinone-Grafted Porous Carbons for Highly Selective CO2 Capture from Flue Gases and Natural Gas Upgrading.

    PubMed

    Wang, Jun; Krishna, Rajamani; Yang, Jiangfeng; Deng, Shuguang

    2015-08-04

    Hydroquinone and quinone functional groups were grafted onto a hierarchical porous carbon framework via the Friedel-Crafts reaction to develop more efficient adsorbents for the selective capture and removal of carbon dioxide from flue gases and natural gas. The oxygen-doped porous carbons were characterized with scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, Fourier transform infrared spectroscopy, and Raman spectroscopy. CO2, CH4, and N2 adsorption isotherms were measured and correlated with the Langmuir model. An ideal adsorbed solution theory (IAST) selectivity for the CO2/N2 separation of 26.5 (298 K, 1 atm) was obtained on the hydroquinone-grafted carbon, which is 58.7% higher than that of the pristine porous carbon, and a CO2/CH4 selectivity value of 4.6 (298 K, 1 atm) was obtained on the quinone-grafted carbon (OAC-2), which represents a 28.4% improvement over the pristine porous carbon. The highest CO2 adsorption capacity on the oxygen-doped carbon adsorbents is 3.46 mmol g(-1) at 298 K and 1 atm. In addition, transient breakthrough simulations for CO2/CH4/N2 mixture separation were conducted to demonstrate the good separation performance of the oxygen-doped carbons in fixed bed adsorbers. Combining excellent adsorption separation properties and low heats of adsorption, the oxygen-doped carbons developed in this work appear to be very promising for flue gas treatment and natural gas upgrading.

  7. Program plan for evaluation and remediation of the generation and release of flammable gases in Hanford Site waste tanks

    SciTech Connect

    Johnson, G.D.

    1991-08-01

    This program plan describes the activities being conducted for the resolution of the flammable gas problem that is associated with 23 high-level waste tanks at the Hanford Site. The classification of the wastes in all of these tanks is not final and some wastes may not be high-level wastes. However, until the characterization and classification is complete, all the tanks are treated as if they contain high-level waste. Of the 23 tanks, Tank 241-SY-101 (referred to as Tank 101-SY) has exhibited significant episodic releases of flammable gases (hydrogen and nitrous oxide) for the past 10 years. The major near-term focus of this program is for the understanding and stabilization of this tank. An understanding of the mechanism for gas generation and the processes for the episodic release will be obtained through sampling of the tank contents, laboratory studies, and modeling of the tank behavior. Additional information will be obtained through new and upgraded instrumentation for the tank. A number of remediation, or stabilization, concepts will be evaluated for near-term (2 to 3 years) applications to Tank 101-SY. Detailed safety assessments are required for all activities that will occur in the tank (sampling, removal of equipment, and addition of new instruments). This program plan presents a discussion of each task, provides schedules for near-term activities, and gives a summary of the expected work for fiscal years 1991, 1992, and 1993. 16 refs., 7 figs., 8 tabs.

  8. Efficient gas-separation process to upgrade dilute methane stream for use as fuel

    DOEpatents

    Wijmans, Johannes G [Menlo Park, CA; Merkel, Timothy C [Menlo Park, CA; Lin, Haiqing [Mountain View, CA; Thompson, Scott [Brecksville, OH; Daniels, Ramin [San Jose, CA

    2012-03-06

    A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

  9. Upgrading the sensitivity of spectroscopy gas analysis with application of supersonic molecular beams

    SciTech Connect

    Vaks, V.; Domracheva, E.; Sobakinskaya, E.; Chernyaeva, M.

    2012-04-01

    We propose an approach to increase a sensitivity of microwave and THz spectroscopy, that involves application of supersonic molecular beams. The key advantage offered by such an approach is that a gas temperature can be decreased along with an increase in the gas density, which results in a much greater number of molecules interacting with radiation and, hence, in a higher absorption coefficient. This effect has been demonstrated experimentally on supersonic CO and NO beams, using a phase manipulation microwave spectrometer. The absorption coefficient was found to be three orders of magnitude higher than the value of gas absorption coefficient in a standard 1-m long cell at room temperature.

  10. Upgraded biogas from municipal solid waste for natural gas substitution and CO{sub 2} reduction – A case study of Austria, Italy, and Spain

    SciTech Connect

    Starr, Katherine; Villalba, Gara; Gabarrell, Xavier

    2015-04-15

    Highlights: • Biogas can be upgraded to create biomethane, a substitute to natural gas. • Biogas upgrading was applied to landfills and anaerobic digestors in 3 countries. • Up to 0.6% of a country’s consumption of natural gas could be replaced by biomethane. • Italy could save 46% of the national CO{sub 2} emissions attributed to the waste sector. • Scenarios were created to increase biomethane production. - Abstract: Biogas is rich in methane and can be further purified through biogas upgrading technologies, presenting a viable alternative to natural gas. Landfills and anaerobic digestors treating municipal solid waste are a large source of such biogas. They therefore offer an attractive opportunity to tap into this potential source of natural gas while at the same time minimizing the global warming impact resulting from methane emissions in waste management schemes (WMS) and fossil fuel consumption reduction. This study looks at the current municipal solid waste flows of Spain, Italy, and Austria over one year (2009), in order to determine how much biogas is generated. Then it examines how much natural gas could be substituted by using four different biogas upgrading technologies. Based on current waste generation rates, exploratory but realistic WMS were created for each country in order to maximize biogas production and potential for natural gas substitution. It was found that the potential substitution of natural gas by biogas resulting from the current WMS seems rather insignificant: 0.2% for Austria, 0.6% for Italy and 0.3% for Spain. However, if the WMS is redesigned to maximize biogas production, these figures can increase to 0.7% for Austria, 1% for Italy and 2% for Spain. Furthermore, the potential CO{sub 2} reduction as a consequence of capturing the biogas and replacing fossil fuel can result in up to a 93% reduction of the annual national waste greenhouse gas emissions of Spain and Italy.

  11. Biomass gasification: Produced gas upgrading by in-bed use of dolomite

    SciTech Connect

    Olivares, A.; Aznar, M.P.; Caballero, M.A.; Gil, J.; Frances, E.; Corella, J.

    1997-12-01

    When some calcined dolomite (OCa{center_dot}OMg) is used in the bed of a biomass gasifier of fluidized bed type the raw gas produced is cleaner than when only silica sand is used in it as fluidizing medium. In-bed dolomite changes the product distribution at the gasifier exit because of in-situ catalytic reactions promoted by the calcined dolomite. Gasifying with steam-O{sub 2} mixtures causes the tar content in the exit gas to decrease from 12 to 2--3 g tar/m{sup 3}{sub n}, the H{sub 2} content to increase from 25--28 to 43 vol%, and the CO content to decrease from 45 to 27 vol% when the gas and char yields, heating value of the gas, and other main variables also undergo important changes because of the in-bed dolomite. The experimental work here reported is carried out at small pilot plant scale in a 15 cm i.d. atmospheric and bubbling fluidized bed gasifier fed by 10 kg biomass/h. Dolomite is continuously fed to the gasifier, mixed with the biomass in percentages of 2--3 wt% of the total mass flow fed. A 10 wt% of calcined dolomite in the gasifier bed is enough to significantly improve the product distribution and gas quality.

  12. Performance and microbial community analysis of the anaerobic reactor with coke oven gas biomethanation and in situ biogas upgrading.

    PubMed

    Wang, Wen; Xie, Li; Luo, Gang; Zhou, Qi; Angelidaki, Irini

    2013-10-01

    A new method for simultaneous coke oven gas (COG) biomethanation and in situ biogas upgrading in anaerobic reactor was developed in this study. The simulated coke oven gas (SCOG) (92% H2 and 8% CO) was injected directly into the anaerobic reactor treating sewage sludge through hollow fiber membrane (HFM). With pH control at 8.0, the added H2 and CO were fully consumed and no negative effects on the anaerobic degradation of sewage sludge were observed. The maximum CH4 content in the biogas was 99%. The addition of SCOG resulted in enrichment and dominance of homoacetogenetic genus Treponema and hydrogenotrophic genus Methanoculleus in the liquid, which indicated that H2 were converted to methane by both direct (hydrogenotrophic methanogenesis) and indirect (homoacetogenesis+aceticlastic methanogenesis) pathways in the liquid. However, the aceticlasitic genus Methanosaeta was dominant for archaea in the biofilm on the HFM, which indicated indirect (homoacetogenesis+aceticlastic methanogenesis) H2 conversion pathway on the biofilm.

  13. Upgrades to the Radiochemistry Analysis of Gas Samples (RAGS) diagnostic at the National Ignition Facility

    NASA Astrophysics Data System (ADS)

    Jedlovec, Donald; Christensen, Kim; Velsko, Carol; Cassata, Bill; Stoeffl, Wolfgang; Shaughnessy, Dawn; Lugten, John; Golod, Tony; Massey, Warren

    2015-08-01

    The Radiochemical Analysis of Gaseous Samples (RAGS) diagnostic apparatus operates at the National Ignition Facility (NIF). At the NIF, xenon is injected into the target chamber as a tracer, used as an analyte in the NIF targets, and generated as a fission product from 14 MeV neutron fission of depleted uranium contained in the NIF hohlraum. Following a NIF shot, the RAGS apparatus used to collect the gas from the NIF target chamber and then to cryogenically fractionate xenon gas. Radio-xenon and other activation products are collected and counted via gamma spectrometry, with the results used to determine critical physics parameters including: capsule areal density, fuel-ablator mix, and nuclear cross sections.

  14. Experimental performance of the regenerator for the Chrysler upgraded automotive gas turbine engine

    NASA Technical Reports Server (NTRS)

    Winter, J. M.; Nussle, R. C.

    1982-01-01

    Automobile gas turbine engine regenerator performance was studied in a regenerator test facility that provided a satisfactory simulation of the actual engine operating environment but with independent control of airflow and gas flow. Velocity and temperature distributions were measured immediately downstream of both the core high-pressure-side outlet and the core low-pressure-side outlet. For the original engine housing, the regenerator temperature effectiveness was 1 to 2 percent higher than the design value, and the heat transfer effectiveness was 2 to 4 percent lower than the design value over the range of test conditions simulating 50 to 100 percent of gas generator speed. Recalculating the design values to account for seal leakage decreased the design heat transfer effectiveness to values consistent with those measured herein. A baffle installed in the engine housing high-pressure-side inlet provided more uniform velocities out of the regenerator but did not improve the effectiveness. A housing designed to provide more uniform axial flow to the regenerator was also tested. Although temperature uniformity was improved, the effectiveness values were not improved. Neither did 50-percent flow blockage (90 degree segment) applied to the high-pressure-side inlet change the effectiveness significantly.

  15. The effects of gravity on flammability

    NASA Technical Reports Server (NTRS)

    Pearce, J. P.; Kimzey, J. H.; Pippen, D. L.

    1971-01-01

    The effects of weightlessness and increased gravity on flammability and flame propagation are discussed. The test equipment and procedures for determining gravity effects are described. Comparisons are made between flammability under normal gravity conditions and occurrences under altered gravity conditions

  16. The effects of gravity on flammability

    NASA Technical Reports Server (NTRS)

    Pearce, J. P.; Kimzey, J. H.; Pippen, D. L.

    1971-01-01

    The effects of weightlessness and increased gravity on flammability and flame propagation are discussed. The test equipment and procedures for determining gravity effects are described. Comparisons are made between flammability under normal gravity conditions and occurrences under altered gravity conditions

  17. Antimisting kerosene atomization and flammability

    NASA Technical Reports Server (NTRS)

    Fleeter, R.; Petersen, R. A.; Toaz, R. D.; Jakub, A.; Sarohia, V.

    1982-01-01

    Various parameters found to affect the flammability of antimisting kerosene (Jet A + polymer additive) are investigated. Digital image processing was integrated into a technique for measurement of fuel spray characteristics. This technique was developed to avoid many of the error sources inherent to other spray assessment techniques and was applied to the study of engine fuel nozzle atomization performance with Jet A and antimisting fuel. Aircraft accident fuel spill and ignition dynamics were modeled in a steady state simulator allowing flammability to be measured as a function of airspeed, fuel flow rate, fuel jet Reynolds number and polymer concentration. The digital imaging technique was employed to measure spray characteristics in this simulation and these results were related to flammability test results. Scaling relationships were investigated through correlation of experimental results with characteristic dimensions spanning more than two orders of magnitude.

  18. Self-Flammability of Gases Generated by Hanford Tank Waste and the Potential of Nitrogen Inerting to Eliminate Flammability Safety Concerns

    SciTech Connect

    Mahoney, Lenna A.

    2015-10-12

    Through radiolytic and thermolytic reactions, Hanford tank wastes generate and retain a variety of gases, including hydrogen, nitrous oxide, methane (and other hydrocarbons), ammonia, and nitrogen. This gas generation can be expected to continue during processing in the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The generation rates in the WTP will change from those for the in-situ tank waste because of different process temperatures, different dose rates produced by in-process changes in the proportions of solid and liquid, and dilution of the waste liquid. The flammability of the generated gas that is continuously released, and of any retained gas that might be released into a vessel headspace in quantity due to a spontaneous release, depends on the concentrations not only of the fuel gases—primarily hydrogen (H2), methane, other hydrocarbons, and ammonia—but of the oxidizer nitrous oxide (N2O). As a result of high concentrations of N2O, some gas mixtures are “self-flammable” (i.e., ignition can occur when no air is present because N2O provides the only oxidizer needed). Self-flammability could potentially reduce the effectiveness of using a nitrogen (N2) purge in the headspace as a flammability control, if its effects are not accounted for. A given amount of inertant gas (N2) can accommodate only a certain amount of a generated self-flammable gas before the mixture with inertant gas becomes flammable.

  19. Nitrogen dilution effect on the flammability limits for hydrocarbons.

    PubMed

    Chen, Chan-Cheng; Wang, Tzu-Chi; Liaw, Horng-Jang; Chen, Hui-Chu

    2009-07-30

    Theoretical models to predict the upper/lower flammability limits of hydrocarbons diluted with inert nitrogen gas are proposed in this study. It is found that there are linear relations between the reciprocal of the upper/lower flammability limits and the reciprocal of the molar fraction of hydrocarbon in the hydrocarbon/inert nitrogen mixture. Such linearity is examined by experimental data reported in the literature, which include the cases of methane, propane, ethylene and propylene. The R-squared values (R(2)) of the regression lines of the cases explored are all greater than 0.989 for upper flammability limit (UFL). The theoretical slope of the predictive line for lower flammability limit (LFL) is found to be very close to zero for all explored cases; and this result successfully explains the experimental fact that adding inert nitrogen to a flammable material has very limited effect on LFL. Because limit oxygen concentration (LOC) could be taken as the intersectional point of the UFL curve and LFL curve, a LOC-based method is proposed to predict the slope of the UFL curve when experimental data of UFL are not available. This LOC-based method predicts the UFL with average error ranging from 2.17% to 5.84% and maximum error ranging from 8.58% to 12.18% for the cases explored. The predictive models for inert gas of nitrogen are also extended to the case of inert gas other than nitrogen. Through the extended models, it was found that the inert ability of an inert gas depends on its mean molar heat capacity at the adiabatic flame temperature. Theoretical calculation shows that the inert abilities of carbon dioxide, steam, nitrogen and helium are in the following order: carbon dioxide>steam>nitrogen>helium; and this sequence conforms to the existing experimental data reported in the literature.

  20. Flammability screening tests of resins

    NASA Technical Reports Server (NTRS)

    Arhart, R. W.; Farrar, D. G.; Hughes, B. M.

    1979-01-01

    Selected flammability characteristics of glass cloth laminates of thermosetting resins are evaluated. A protocol for the evaluation of the flammability hazards presented by glass cloth laminates of thermosetting resins and the usefulness of that protocol with two laminates are presented. The glass laminates of an epoxy resin, M-751 are evaluated for: (1) determination of smoke generation from the laminates; (2) analysis of products of oxidative degradation of the laminates; (3) determination of minimum oxygen necessary to maintain flaming oxidation; (4) evaluation of toxicological hazards.

  1. 16 CFR 1611.4 - Flammability test.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 16 Commercial Practices 2 2012-01-01 2012-01-01 false Flammability test. 1611.4 Section 1611.4... FLAMMABILITY OF VINYL PLASTIC FILM The Standard § 1611.4 Flammability test. (a) Apparatus and materials. The... protect the igniter flame and specimen from air currents during tests, yet contain a suitable door...

  2. 14 CFR 25.1185 - Flammable fluids.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 1 2014-01-01 2014-01-01 false Flammable fluids. 25.1185 Section 25.1185... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Powerplant Fire Protection § 25.1185 Flammable fluids. (a... system containing flammable fluids or gases may be in a designated fire zone unless the fluid contained...

  3. 14 CFR 29.1185 - Flammable fluids.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 1 2013-01-01 2013-01-01 false Flammable fluids. 29.1185 Section 29.1185... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Powerplant Fire Protection § 29.1185 Flammable fluids. (a) No tank or reservoir that is part of a system containing flammable fluids or gases may be in a...

  4. 14 CFR 125.153 - Flammable fluids.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 3 2013-01-01 2013-01-01 false Flammable fluids. 125.153 Section 125.153....153 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in designated fire zones, except where the fluid contained, the design of...

  5. 14 CFR 125.153 - Flammable fluids.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 3 2014-01-01 2014-01-01 false Flammable fluids. 125.153 Section 125.153....153 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in designated fire zones, except where the fluid contained, the design of...

  6. 14 CFR 125.153 - Flammable fluids.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Flammable fluids. 125.153 Section 125.153....153 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in designated fire zones, except where the fluid contained, the design of...

  7. 14 CFR 121.255 - Flammable fluids.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 3 2012-01-01 2012-01-01 false Flammable fluids. 121.255 Section 121.255..., FLAG, AND SUPPLEMENTAL OPERATIONS Special Airworthiness Requirements § 121.255 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in...

  8. 14 CFR 125.153 - Flammable fluids.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 3 2012-01-01 2012-01-01 false Flammable fluids. 125.153 Section 125.153....153 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in designated fire zones, except where the fluid contained, the design of...

  9. 14 CFR 121.255 - Flammable fluids.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 3 2011-01-01 2011-01-01 false Flammable fluids. 121.255 Section 121.255..., FLAG, AND SUPPLEMENTAL OPERATIONS Special Airworthiness Requirements § 121.255 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in...

  10. 14 CFR 121.255 - Flammable fluids.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Flammable fluids. 121.255 Section 121.255..., FLAG, AND SUPPLEMENTAL OPERATIONS Special Airworthiness Requirements § 121.255 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in...

  11. 14 CFR 125.153 - Flammable fluids.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 3 2011-01-01 2011-01-01 false Flammable fluids. 125.153 Section 125.153....153 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in designated fire zones, except where the fluid contained, the design of...

  12. 14 CFR 121.255 - Flammable fluids.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 3 2013-01-01 2013-01-01 false Flammable fluids. 121.255 Section 121.255..., FLAG, AND SUPPLEMENTAL OPERATIONS Special Airworthiness Requirements § 121.255 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in...

  13. 14 CFR 29.1185 - Flammable fluids.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 1 2014-01-01 2014-01-01 false Flammable fluids. 29.1185 Section 29.1185... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Powerplant Fire Protection § 29.1185 Flammable fluids. (a) No tank or reservoir that is part of a system containing flammable fluids or gases may be in a...

  14. 14 CFR 25.1185 - Flammable fluids.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Flammable fluids. 25.1185 Section 25.1185... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Powerplant Fire Protection § 25.1185 Flammable fluids. (a... system containing flammable fluids or gases may be in a designated fire zone unless the fluid contained...

  15. 14 CFR 121.255 - Flammable fluids.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 3 2014-01-01 2014-01-01 false Flammable fluids. 121.255 Section 121.255..., FLAG, AND SUPPLEMENTAL OPERATIONS Special Airworthiness Requirements § 121.255 Flammable fluids. (a) No tanks or reservoirs that are a part of a system containing flammable fluids or gases may be located in...

  16. Upgraded biogas from municipal solid waste for natural gas substitution and CO2 reduction--a case study of Austria, Italy, and Spain.

    PubMed

    Starr, Katherine; Villalba, Gara; Gabarrell, Xavier

    2015-04-01

    Biogas is rich in methane and can be further purified through biogas upgrading technologies, presenting a viable alternative to natural gas. Landfills and anaerobic digestors treating municipal solid waste are a large source of such biogas. They therefore offer an attractive opportunity to tap into this potential source of natural gas while at the same time minimizing the global warming impact resulting from methane emissions in waste management schemes (WMS) and fossil fuel consumption reduction. This study looks at the current municipal solid waste flows of Spain, Italy, and Austria over one year (2009), in order to determine how much biogas is generated. Then it examines how much natural gas could be substituted by using four different biogas upgrading technologies. Based on current waste generation rates, exploratory but realistic WMS were created for each country in order to maximize biogas production and potential for natural gas substitution. It was found that the potential substitution of natural gas by biogas resulting from the current WMS seems rather insignificant: 0.2% for Austria, 0.6% for Italy and 0.3% for Spain. However, if the WMS is redesigned to maximize biogas production, these figures can increase to 0.7% for Austria, 1% for Italy and 2% for Spain. Furthermore, the potential CO2 reduction as a consequence of capturing the biogas and replacing fossil fuel can result in up to a 93% reduction of the annual national waste greenhouse gas emissions of Spain and Italy. Copyright © 2015 Elsevier Ltd. All rights reserved.

  17. Compression testing of flammable liquids

    NASA Technical Reports Server (NTRS)

    Briles, O. M.; Hollenbaugh, R. P.

    1979-01-01

    Small cylindrical test chamber determines catalytic effect of given container material on fuel that might contribute to accidental deflagration or detonation below expected temperature under adiabatic compression. Device is useful to producers and users of flammable liquids and to safety specialists.

  18. Initial parametric study of the flammability of plume releases in Hanford waste tanks

    SciTech Connect

    Antoniak, Z.I.; Recknagle, K.P.

    1997-08-01

    This study comprised systematic analyses of waste tank headspace flammability following a plume-type of gas release from the waste. First, critical parameters affecting plume flammability were selected, evaluated, and refined. As part of the evaluation the effect of ventilation (breathing) air inflow on the convective flow field inside the tank headspace was assessed, and the magnitude of the so-called {open_quotes}numerical diffusion{close_quotes} on numerical simulation accuracy was investigated. Both issues were concluded to be negligible influences on predicted flammable gas concentrations in the tank headspace. Previous validation of the TEMPEST code against experimental data is also discussed, with calculated results in good agreements with experimental data. Twelve plume release simulations were then run, using release volumes and flow rates that were thought to cover the range of actual release volumes and rates. The results indicate that most plume-type releases remain flammable only during the actual release ends. Only for very large releases representing a significant fraction of the volume necessary to make the entire mixed headspace flammable (many thousands of cubic feet) can flammable concentrations persist for several hours after the release ends. However, as in the smaller plumes, only a fraction of the total release volume is flammable at any one time. The transient evolution of several plume sizes is illustrated in a number of color contour plots that provide insight into plume mixing behavior.

  19. Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks for Fast Pyrolysis and Upgrading: Techno-economic Analysis and Greenhouse Gas Life Cycle Analysis

    SciTech Connect

    Meyer, Pimphan A.; Snowden-Swan, Lesley J.; Rappé, Kenneth G.; Jones, Susanne B.; Westover, Tyler L.; Cafferty, Kara G.

    2016-11-17

    This work shows preliminary results from techno-economic analysis and life cycle greenhouse gas analysis of the conversion of seven (7) biomass feedstocks to produce liquid transportation fuels via fast pyrolysis and upgrading via hydrodeoxygenation. The biomass consists of five (5) pure feeds (pine, tulip poplar, hybrid poplar, switchgrass, corn stover) and two blends. Blend 1 consists of equal weights of pine, tulip poplar and switchgrass, and blend 2 is 67% pine and 33% hybrid poplar. Upgraded oil product yield is one of the most significant parameters affecting the process economics, and is a function of both fast pyrolysis oil yield and hydrotreating oil yield. Pure pine produced the highest overall yield, while switchgrass produced the lowest. Interestingly, herbaceous materials blended with woody biomass performed nearly as well as pure woody feedstock, suggesting a non-trivial relationship between feedstock attributes and production yield. Production costs are also highly dependent upon hydrotreating catalyst-related costs. The catalysts contribute an average of ~15% to the total fuel cost, which can be reduced through research and development focused on achieving performance at increased space velocity (e.g., reduced catalyst loading) and prolonging catalyst lifetime. Green-house-gas reduction does not necessarily align with favorable economics. From the greenhouse gas analysis, processing tulip poplar achieves the largest GHG emission reduction relative to petroleum (~70%) because of its lower hydrogen consumption in the upgrading stage that results in a lower natural gas requirement for hydrogen production. Conversely, processing blend 1 results in the smallest GHG emission reduction from petroleum (~58%) because of high natural gas demand for hydrogen production.

  20. Flow Effects on the Flammability Diagrams of Solid Fuels

    NASA Technical Reports Server (NTRS)

    Cordova, J. L.; Ceamanos, J.; Fernandez-Pello, A. C.; Long, R. T.; Torero, J. L.; Quintiere, J. G.

    1997-01-01

    A research program is currently underway with the final objective of developing a fundamental understanding of the controlling mechanisms underlying the flammability diagrams of solid combustible materials and their derived fire properties. Given that there is a high possibility of an accidental fire occurring in a space-based facility, understanding the fire properties of materials that will be used in such facilities is of critical importance. With this purpose, the flammability diagrams of the materials, as those produced by the Lateral Ignition and Flame Spread Test (LIFT) apparatus and by a new forced flow device, the Forced Flow Ignition and Flame Spread Test (FIST) apparatus, will be obtained. The specific objective of the program is to apply the new flammability apparatus, which will more accurately reflect the potential ambient conditions of space-based environments, to the characterization of the materials for space applications. This paper presents a parametric study of oxidizer flow effects on the ignition curve of the flammability diagrams of PMMA. The dependence of the ignition delay time on the external radiant flux and either the sample width (LIFT) or the flow velocity (FIST) has been studied. Although preliminary, the results indicate that natural and forced convection flow changes, affect the characteristics of the ignition curves of the flammability diagrams. The major effect on the ignition time appears to be due to convective transfer variations at the fuel surface. At high radiant fluxes or high flow velocities, however, it appears that gas phase processes become increasingly important, affecting the overall ignition delay time. A numerical analysis of the solid fuel heating and pyrolysis has also been developed. The theoretical predictions approximate the experiments well for conditions in which the gas phase induction time is negligible.

  1. Flow Effects on the Flammability Diagrams of Solid Fuels

    NASA Technical Reports Server (NTRS)

    Cordova, J. L.; Ceamanos, J.; Fernandez-Pello, A. C.; Long, R. T.; Torero, J. L.; Quintiere, J. G.

    1997-01-01

    A research program is currently underway with the final objective of developing a fundamental understanding of the controlling mechanisms underlying the flammability diagrams of solid combustible materials and their derived fire properties. Given that there is a high possibility of an accidental fire occurring in a space-based facility, understanding the fire properties of materials that will be used in such facilities is of critical importance. With this purpose, the flammability diagrams of the materials, as those produced by the Lateral Ignition and Flame Spread Test (LIFT) apparatus and by a new forced flow device, the Forced Flow Ignition and Flame Spread Test (FIST) apparatus, will be obtained. The specific objective of the program is to apply the new flammability apparatus, which will more accurately reflect the potential ambient conditions of space-based environments, to the characterization of the materials for space applications. This paper presents a parametric study of oxidizer flow effects on the ignition curve of the flammability diagrams of PMMA. The dependence of the ignition delay time on the external radiant flux and either the sample width (LIFT) or the flow velocity (FIST) has been studied. Although preliminary, the results indicate that natural and forced convection flow changes, affect the characteristics of the ignition curves of the flammability diagrams. The major effect on the ignition time appears to be due to convective transfer variations at the fuel surface. At high radiant fluxes or high flow velocities, however, it appears that gas phase processes become increasingly important, affecting the overall ignition delay time. A numerical analysis of the solid fuel heating and pyrolysis has also been developed. The theoretical predictions approximate the experiments well for conditions in which the gas phase induction time is negligible.

  2. Development of Micro-Pattern Gas Detectors for the Upgrade of the Muon System of the CMS Experiment at the Large Hadron Collider

    NASA Astrophysics Data System (ADS)

    Bouhali, Othmane

    2017-06-01

    After the discovery of the long awaited Higgs boson in 2012, the Large Hadron Collider (LHC) at the European Organization for Nuclear Research (CERN) and its two general purpose experiments (ATLAS and CMS) are preparing to break new grounds in High Energy Physics (HEP). The international HEP collaboration has established a rigorous research program of exploring new physics at the high energy frontiers. The program includes substantial increase in the luminosity of the LHC putting detectors into a completely new and unprecedented harsh environment. In order to maintain their excellent performance, an upgrade of the existing detectors is mandatory. In this work we will describe ongoing efforts for the upgrade of the CMS muon detection system, in particular the addition of detection layers based on the Gas Electron Multiplier (GEM) technology. We will summarize the past 5-year R&D program and the future installation and operation plans.

  3. Flammability as an ecological and evolutionary driver

    USGS Publications Warehouse

    Pausas, Juli G.; Keeley, Jon E.; Schwilk, Dylan W.

    2017-01-01

    We live on a flammable planet yet there is little consensus on the origin and evolution of flammability in our flora.We argue that part of the problem lies in the concept of flammability, which should not be viewed as a single quantitative trait or metric. Rather, we propose that flammability has three major dimensions that are not necessarily correlated: ignitability, heat release and fire spread rate. These major axes of variation are controlled by different plant traits and have differing ecological impacts during fire.At the individual plant scale, these traits define three flammability strategies observed in fire-prone ecosystems: the non-flammable, the fast-flammable and the hot-flammable strategy (with low ignitability, high flame spread rate and high heat release, respectively). These strategies increase the survival or reproduction under recurrent fires, and thus, plants in fire-prone ecosystems benefit from acquiring one of them; they represent different (alternative) ways to live under recurrent fires.Synthesis. This novel framework based on different flammability strategies helps us to understand variability in flammability across scales, and provides a basis for further research.

  4. CDF calorimeter and its upgrade

    SciTech Connect

    Seiya, Y.

    1995-01-01

    The CDF calorimeter systems are briefly reviewed with an emphasis on the calibration and the performance of the central electromagnetic calorimeter. Several physics analyses where the calorimetry plays an important role are discussed. The present gas calorimeter will be upgraded in accord with the collider upgrade. The new system is a scintillator-based calorimeter with optical fiber readout. A status of the CDF calorimeter upgrade project is also described.

  5. 46 CFR 105.10-15 - Flammable liquid.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Flammable liquid. 105.10-15 Section 105.10-15 Shipping... liquid. (a) The term flammable liquid means any liquid which gives off flammable vapors (as determined by.... Flammable liquids are referred to by grades as follows: (1) Grade A. Any flammable liquid having a Reid...

  6. 46 CFR 105.10-15 - Flammable liquid.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Flammable liquid. 105.10-15 Section 105.10-15 Shipping... liquid. (a) The term flammable liquid means any liquid which gives off flammable vapors (as determined by.... Flammable liquids are referred to by grades as follows: (1) Grade A. Any flammable liquid having a Reid...

  7. 46 CFR 105.10-15 - Flammable liquid.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Flammable liquid. 105.10-15 Section 105.10-15 Shipping... liquid. (a) The term flammable liquid means any liquid which gives off flammable vapors (as determined by.... Flammable liquids are referred to by grades as follows: (1) Grade A. Any flammable liquid having a Reid...

  8. 46 CFR 105.10-15 - Flammable liquid.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Flammable liquid. 105.10-15 Section 105.10-15 Shipping... liquid. (a) The term flammable liquid means any liquid which gives off flammable vapors (as determined by.... Flammable liquids are referred to by grades as follows: (1) Grade A. Any flammable liquid having a Reid...

  9. 46 CFR 105.10-15 - Flammable liquid.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Flammable liquid. 105.10-15 Section 105.10-15 Shipping... liquid. (a) The term flammable liquid means any liquid which gives off flammable vapors (as determined by.... Flammable liquids are referred to by grades as follows: (1) Grade A. Any flammable liquid having a Reid...

  10. Antimisting fuel breakup and flammability

    NASA Technical Reports Server (NTRS)

    Parikh, P.; Fleeter, R.; Sarohia, V.

    1983-01-01

    The breakup behavior and flammability of antimisting turbine fuels subjected to aerodynamic shear are investigated. Fuels tested were Jet A containing 0.3% FM-9 polymer at various levels of degradation ranging from virgin AMK to neat Jet A. The misting behavior of the fuels was quantified by droplet size distribution measurements. A technique based on high resolution laser photography and digital image processing of photographic records for rapid determination of droplet size distribution was developed. The flammability of flowing droplet-air mixtures was quantified by direct measurements of temperature rise in a flame established in the wake of a continuous ignition source. The temperature rise measurements were correlated with droplet size measurements. The flame anchoring phenomenon associated with the breakup of a liquid fuel in the wake of bluff body was shown to be important in the context of a survivable crash scenario. A pass/fail criterion for flammability testing of antimisting fuels, based on this flame-anchoring phenomenon, was proposed. The role of various ignition sources and their intensity in ignition and post-ignition behavior of antimisting fuels was also investigated.

  11. Impact of wastewater infrastructure upgrades on the urban water cycle: Reduction in halogenated reaction byproducts following conversion from chlorine gas to ultraviolet light disinfection.

    PubMed

    Barber, Larry B; Hladik, Michelle L; Vajda, Alan M; Fitzgerald, Kevin C; Douville, Chris

    2015-10-01

    The municipal wastewater treatment facility (WWTF) infrastructure of the United States is being upgraded to expand capacity and improve treatment, which provides opportunities to assess the impact of full-scale operational changes on water quality. Many WWTFs disinfect their effluent prior to discharge using chlorine gas, which reacts with natural and synthetic organic matter to form halogenated disinfection byproducts (HDBPs). Because HDBPs are ubiquitous in chlorine-disinfected drinking water and have adverse human health implications, their concentrations are regulated in potable water supplies. Less is known about the formation and occurrence of HDBPs in disinfected WWTF effluents that are discharged to surface waters and become part of the de facto wastewater reuse cycle. This study investigated HDBPs in the urban water cycle from the stream source of the chlorinated municipal tap water that comprises the WWTF inflow, to the final WWTF effluent disinfection process before discharge back to the stream. The impact of conversion from chlorine-gas to low-pressure ultraviolet light (UV) disinfection at a full-scale (68,000 m(3) d(-1) design flow) WWTF on HDBP concentrations in the final effluent was assessed, as was transport and attenuation in the receiving stream. Nutrients and trace elements (boron, copper, and uranium) were used to characterize the different urban source waters, and indicated that the pre-upgrade and post-upgrade water chemistry was similar and insensitive to the disinfection process. Chlorinated tap water during the pre-upgrade and post-upgrade samplings contained 11 (mean total concentration=2.7 μg L(-1); n=5) and 10 HDBPs (mean total concentration=4.5 μg L(-1)), respectively. Under chlorine-gas disinfection conditions 13 HDBPs (mean total concentration=1.4 μg L(-1)) were detected in the WWTF effluent, whereas under UV disinfection conditions, only one HDBP was detected. The chlorinated WWTF effluent had greater relative proportions of

  12. Impact of wastewater infrastructure upgrades on the urban water cycle: Reduction in halogenated reaction byproducts following conversion from chlorine gas to ultraviolet light disinfection

    USGS Publications Warehouse

    Barber, Larry B.; Hladik, Michelle; Vajda, Alan M.; Fitzgerald, Kevin C.; Douville, Chris

    2015-01-01

    The municipal wastewater treatment facility (WWTF) infrastructure of the United States is being upgraded to expand capacity and improve treatment, which provides opportunities to assess the impact of full-scale operational changes on water quality. Many WWTFs disinfect their effluent prior to discharge using chlorine gas, which reacts with natural and synthetic organic matter to form halogenated disinfection byproducts (HDBPs). Because HDBPs are ubiquitous in chlorine-disinfected drinking water and have adverse human health implications, their concentrations are regulated in potable water supplies. Less is known about the formation and occurrence of HDBPs in disinfected WWTF effluents that are discharged to surface waters and become part of the de facto wastewater reuse cycle. This study investigated HDBPs in the urban water cycle from the stream source of the chlorinated municipal tap water that comprises the WWTF inflow, to the final WWTF effluent disinfection process before discharge back to the stream. The impact of conversion from chlorine-gas to low-pressure ultraviolet light (UV) disinfection at a full-scale (68,000 m3 d−1 design flow) WWTF on HDBP concentrations in the final effluent was assessed, as was transport and attenuation in the receiving stream. Nutrients and trace elements (boron, copper, and uranium) were used to characterize the different urban source waters, and indicated that the pre-upgrade and post-upgrade water chemistry was similar and insensitive to the disinfection process. Chlorinated tap water during the pre-upgrade and post-upgrade samplings contained 11 (mean total concentration = 2.7 μg L−1; n=5) and 10 HDBPs (mean total concentration = 4.5 μg L−1), respectively. Under chlorine-gas disinfection conditions 13 HDBPs (mean total concentration = 1.4 μg L−1) were detected in the WWTF effluent, whereas under UV disinfection conditions, only one HDBP was detected. The chlorinated WWTF effluent had greater relative

  13. Material flammability in space exploration atmospheres

    NASA Astrophysics Data System (ADS)

    McAllister, Sara Suzanne

    In order to reduce the risk of decompression sickness associated with extravehicular activity, NASA is designing the next generation of exploration vehicles with a different cabin pressure and oxygen concentration than used previously. This work explores how the flammability of solid materials changes in this new environment. One method to evaluate material flammability is by its ease of ignition. To this end, piloted ignition delay tests were conducted in a small-scale wind tunnel subject to this new space exploration atmosphere (SEA -- 58.6 kPa and 32% oxygen) and compared to similar tests in standard atmospheric conditions. In these tests, polymethylmethacylate (PMMA) was exposed to a range of oxidizer flow velocities and externally applied heat fluxes. It was found that the ignition time was reduced by 27% in the intended space exploration atmosphere. It was also noted that the critical heat flux for ignition decreases in exploration atmospheres. These results show that materials are more susceptible to ignition than in current spacecraft atmospheres. To further explore the effect of pressure and oxygen concentration, tests were performed for a wide range of pressures and oxygen concentrations. In all oxygen concentrations tested, the ignition delay time was seen to decrease with pressure, reach a minimum, and then increase with further reduction in pressure creating a classic u-shaped curve. No ignition was seen at sufficiently low pressures. The no ignition pressure depended on the oxygen concentration. Increasing the oxygen concentration uniformly decreases the ignition time; however, no significant differences were seen in oxygen concentrations above 24%. These results indicate there are several competing mechanisms controlling the ignition time. By reducing the pressure, the heat transfer coefficient and the mass flow rate of fuel to reach the lean flammability limit are reduced. Conversely, a reduction in pressure increases the gas-phase chemical

  14. Influence of the gas-liquid flow configuration in the absorption column on photosynthetic biogas upgrading in algal-bacterial photobioreactors.

    PubMed

    Toledo-Cervantes, Alma; Madrid-Chirinos, Cindy; Cantera, Sara; Lebrero, Raquel; Muñoz, Raúl

    2017-02-01

    The potential of an algal-bacterial system consisting of a high rate algal pond (HRAP) interconnected to an absorption column (AC) via recirculation of the cultivation broth for the upgrading of biogas and digestate was investigated. The influence of the gas-liquid flow configuration in the AC on the photosynthetic biogas upgrading process was assessed. AC operation in a co-current configuration enabled to maintain a biomass productivity of 15gm(-2)d(-1), while during counter-current operation biomass productivity decreased to 8.7±0.5gm(-2)d(-1) as a result of trace metal limitation. A bio-methane composition complying with most international regulatory limits for injection into natural gas grids was obtained regardless of the gas-liquid flow configuration. Furthermore, the influence of the recycling liquid to biogas flowrate (L/G) ratio on bio-methane quality was assessed under both operational configurations obtaining the best composition at an L/G ratio of 0.5 and co-current flow operation. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Quantifying the loss of methane through secondary gas mass transport (or 'slip') from a micro-porous membrane contactor applied to biogas upgrading.

    PubMed

    McLeod, Andrew; Jefferson, Bruce; McAdam, Ewan J

    2013-07-01

    Secondary gas transport during the separation of a binary gas with a micro-porous hollow fibre membrane contactor (HMFC) has been studied for biogas upgrading. In this application, the loss or 'slip' of the secondary gas (methane) during separation is a known concern, specifically since methane possesses the intrinsic calorific value. Deionised (DI) water was initially used as the physical solvent. Under these conditions, carbon dioxide (CO2) and methane (CH4) absorption were dependent upon liquid velocity (V(L)). Whilst the highest CO2 flux was recorded at high V(L), selectivity towards CO2 declined due to low residence times and a diminished gas-side partial pressure, and resulted in slip of approximately 5.2% of the inlet methane. Sodium hydroxide was subsequently used as a comparative chemical absorption solvent. Under these conditions, CO2 mass transfer increased by increasing gas velocity (VG) which is attributed to the excess of reactive hydroxide ions present in the solvent, and the fast conversion of dissolved CO2 to carbonate species reinitiating the concentration gradient at the gas-liquid interface. At high gas velocities, CH4 slip was reduced to 0.1% under chemical conditions. Methane slip is therefore dependent upon whether the process is gas phase or liquid phase controlled, since methane mass transport can be adequately described by Henry's law within both physical and chemical solvents. The addition of an electrolyte was found to further retard CH4 absorption via the salting out effect. However, their applicability to physical solvents is limited since electrolytic concentration similarly impinges upon the solvents' capacity for CO2. This study illustrates the significance of secondary gas mass transport, and furthermore demonstrates that gas-phase controlled systems are recommended where greater selectivity is required.

  16. Off-site ignition probability of flammable gases.

    PubMed

    Rew, P J; Spencer, H; Daycock, J

    2000-01-07

    A key step in the assessment of risk for installations where flammable liquids or gases are stored is the estimation of ignition probability. A review of current modelling and data confirmed that ignition probability values used in risk analyses tend to be based on extrapolation of limited incident data or, in many cases, on the judgement of those conducting the safety assessment. Existing models tend to assume that ignition probability is a function of release rate (or flammable gas cloud size) alone and they do not consider location, density or type of ignition source. An alternative mathematical framework for calculating ignition probability is outlined in which the approach used is to model the distribution of likely ignition sources and to calculate ignition probability by considering whether the flammable gas cloud will reach these sources. Data are collated on the properties of ignition sources within three generic land-use types: industrial, urban and rural. These data are then incorporated into a working model for ignition probability in a form capable of being implemented within risk analysis models. The sensitivity of the model results to assumptions made in deriving the ignition source properties is discussed and the model is compared with other available ignition probability methods.

  17. 29 CFR 1915.36 - Flammable liquids.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 29 Labor 7 2014-07-01 2014-07-01 false Flammable liquids. 1915.36 Section 1915.36 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR... Preservation § 1915.36 Flammable liquids. (a) In all cases when liquid solvents, paint and...

  18. 29 CFR 1915.36 - Flammable liquids.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 29 Labor 7 2012-07-01 2012-07-01 false Flammable liquids. 1915.36 Section 1915.36 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR... Preservation § 1915.36 Flammable liquids. (a) In all cases when liquid solvents, paint and...

  19. 29 CFR 1915.36 - Flammable liquids.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 29 Labor 7 2011-07-01 2011-07-01 false Flammable liquids. 1915.36 Section 1915.36 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR... Preservation § 1915.36 Flammable liquids. (a) In all cases when liquid solvents, paint and...

  20. 49 CFR 172.542 - FLAMMABLE placard.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.542 FLAMMABLE placard. (a) Except for size and color, the FLAMMABLE placard must be as follows: EC02MR91.049 (b) In addition to complying with § 172.519, the background color...

  1. 49 CFR 172.542 - FLAMMABLE placard.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.542 FLAMMABLE placard. (a) Except for size and color, the FLAMMABLE placard must be as follows: EC02MR91.049 (b) In addition to complying with § 172.519, the background color...

  2. 49 CFR 172.542 - FLAMMABLE placard.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.542 FLAMMABLE placard. (a) Except for size and color, the FLAMMABLE placard must be as follows: EC02MR91.049 (b) In addition to complying with § 172.519, the background color...

  3. 49 CFR 172.542 - FLAMMABLE placard.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.542 FLAMMABLE placard. (a) Except for size and color, the FLAMMABLE placard must be as follows: EC02MR91.049 (b) In addition to complying with § 172.519, the background color...

  4. Cold-air performance of compressor-drive turbine of Department of Energy upgraded automobile gas turbine engine. 2: Stage performance

    NASA Technical Reports Server (NTRS)

    Roelke, R. J.; Haas, J. E.

    1982-01-01

    The aerodynamic performance of the compressor-drive turbine of the DOE upgraded gas turbine engine was determined in low temperature air. The as-received cast rotor blading had a significantly thicker profile than design and a fairly rough surface finish. Because of these blading imperfections a series of stage tests with modified rotors were made. These included the as-cast rotor, a reduced-roughness rotor, and a rotor with blades thinned to near design. Significant performance changes were measured. Tests were also made to determine the effect of Reynolds number on the turbine performance. Comparisons are made between this turbine and the compressor-drive turbine of the DOE baseline gas turbine engine.

  5. Bending fatigue of electron-beam-welded foils. Application to a hydrodynamic air bearing in the Chrysler/DOE upgraded automotive gas tubine engine

    NASA Technical Reports Server (NTRS)

    Saltsman, J. F.; Halford, G. R.

    1984-01-01

    A hydrodynamic air bearing with a compliment surface is used in the gas generator of an upgraded automotive gas turbine engine. In the prototype design, the compliant surface is a thin foil spot welded at one end to the bearing cartridge. During operation, the foil failed along the line of spot welds which acted as a series of stress concentrators. Because of its higher degree of geometric uniformity, electron beam welding of the foil was selected as an alternative to spot welding. Room temperature bending fatigue tests were conducted to determine the fatigue resistance of the electron beam welded foils. Equations were determined relating cycles to crack initiation and cycles to failure to nominal total strain range. A scaling procedure is presented for estimating the reduction in cyclic life when the foil is at its normal operating temperature of 260 C (500 F).

  6. Implications of Cost Effectiveness Screening Practices in a Low Natural Gas Price Environment: Case Study of a Midwestern Residential Energy Upgrade Program

    SciTech Connect

    Hoffman, Ian M.; Borgeson, Merrian Goggio; Zimring, Mark

    2013-04-12

    With the proliferation of statewide energy savings targets and other policies favorable to energy efficiency, savings from utility customer-funded energy efficiency programs could rise to offset much of annual load growth by 2025 (Barbose et al 2013). For these increased savings to occur, however, nearly all of these programs must pass screening for cost effectiveness. Some program administrators and state regulators are finding that conventional analyses, which only consider a narrow set of energy-savings related efficiency program benefits, are now resulting in some natural gas efficiency programs failing their cost-effectiveness criteria in the new low natural gas price environment. Regulators are considering whether to scale back or terminate gas portfolios in at least four states (WA, OR, ID, NM) because of cost-effectiveness concerns. Stakeholders in several regions of the country have asked LBNL to help assess alternatives to reducing the pursuit of energy savings in their regions. We address these requests by producing two working papers: one exploring cost-effectiveness screening policy implications of low to moderate natural gas prices, and a second assessing some of the values that policymakers may take into account in weighing the pros and cons of ending natural gas efficiency programs. In this policy brief, we lay out the challenges that low gas prices pose for cost effectiveness of an electric-gas efficiency program and portfolio. We then quantify options available to regulators and administrators who want to evaluate the tradeoffs among multiple policy objectives. A multi-measure, residential energy upgrade program in the Midwest is used as a lens to explore the implications of common and emerging cost-effectiveness policies in the context of low prices for natural gas. We illustrate the results across a range of cost-effectiveness screening options, including different discount rates, levels of test application, various benefit-cost tests, and the

  7. FLAMMABILITY AND CONSEQUENCE ANALYSIS FOR MCU WASTE TANKS

    SciTech Connect

    Knight, J; Mukesh Gupta, M

    2007-02-13

    The Savannah River Site of Department of Energy will use the new Modular Caustic Side Solvent Extraction Unit (MCU) to process the waste stream by removing/reducing Cs-137 using Caustic Side Solvent Extraction (CSSX) technology. The CSSX technology utilizes multicomponent organic solvent and annular centrifugal contactors to extract Cs-137 from waste salt solution. Due to the radiolysis of the aqueous nuclear wastes, hydrogen generation is expected in the MCU holding tanks. The hydrogen from radiolysis and the vapor from the organic component of the solvent, Isopar-L, may form a composite flammable gas mixture, resulting in a shorter time to flammability than that of a pure hydrogen environment. It has been found that the time-to-Lower Flammability Limit (LFL) and stoichiometric concentration (SC) vary greatly from tank to tank, and could be decreased significantly by the presence of the Isopar-L. However, neither the deflagration nor the detonation event would challenge the Evaluation Guideline for any of the tanks at any liquid level.

  8. Selected Parametric Effects on Materials Flammability Limits

    NASA Technical Reports Server (NTRS)

    Hirsch, David B.; Juarez, Alfredo; Peyton, Gary J.; Harper, Susana A.; Olson, Sandra L.

    2011-01-01

    NASA-STD-(I)-6001B Test 1 is currently used to evaluate the flammability of materials intended for use in habitable environments of U.S. spacecraft. The method is a pass/fail upward flame propagation test conducted in the worst case configuration, which is defined as a combination of a material s thickness, test pressure, oxygen concentration, and temperature that make the material most flammable. Although simple parametric effects may be intuitive (such as increasing oxygen concentrations resulting in increased flammability), combinations of multi-parameter effects could be more complex. In addition, there are a variety of material configurations used in spacecraft. Such configurations could include, for example, exposed free edges where fire propagation may be different when compared to configurations commonly employed in standard testing. Studies involving combined oxygen concentration, pressure, and temperature on flammability limits have been conducted and are summarized in this paper. Additional effects on flammability limits of a material s thickness, mode of ignition, burn-length criteria, and exposed edges are presented. The information obtained will allow proper selection of ground flammability test conditions, support further studies comparing flammability in 1-g with microgravity and reduced gravity environments, and contribute to persuasive scientific cases for rigorous space system fire risk assessments.

  9. 30 CFR 57.4460 - Storage of flammable liquids underground.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Storage of flammable liquids underground. 57... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4460 Storage of flammable liquids underground. (a) Flammable liquids shall not be stored underground, except— (1) Small...

  10. 30 CFR 77.1103 - Flammable liquids; storage.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Flammable liquids; storage. 77.1103 Section 77... Fire Protection § 77.1103 Flammable liquids; storage. (a) Flammable liquids shall be stored in accordance with standards of the National Fire Protection Association. Small quantities of flammable...

  11. 30 CFR 57.4460 - Storage of flammable liquids underground.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Storage of flammable liquids underground. 57... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4460 Storage of flammable liquids underground. (a) Flammable liquids shall not be stored underground, except— (1) Small...

  12. 30 CFR 77.1103 - Flammable liquids; storage.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Flammable liquids; storage. 77.1103 Section 77... Fire Protection § 77.1103 Flammable liquids; storage. (a) Flammable liquids shall be stored in accordance with standards of the National Fire Protection Association. Small quantities of flammable...

  13. 30 CFR 77.1103 - Flammable liquids; storage.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Flammable liquids; storage. 77.1103 Section 77... Fire Protection § 77.1103 Flammable liquids; storage. (a) Flammable liquids shall be stored in accordance with standards of the National Fire Protection Association. Small quantities of flammable...

  14. 30 CFR 57.4460 - Storage of flammable liquids underground.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Storage of flammable liquids underground. 57... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4460 Storage of flammable liquids underground. (a) Flammable liquids shall not be stored underground, except— (1) Small...

  15. 30 CFR 77.1103 - Flammable liquids; storage.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Flammable liquids; storage. 77.1103 Section 77... Fire Protection § 77.1103 Flammable liquids; storage. (a) Flammable liquids shall be stored in accordance with standards of the National Fire Protection Association. Small quantities of flammable...

  16. 30 CFR 57.4460 - Storage of flammable liquids underground.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Storage of flammable liquids underground. 57... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4460 Storage of flammable liquids underground. (a) Flammable liquids shall not be stored underground, except— (1) Small...

  17. 30 CFR 57.4460 - Storage of flammable liquids underground.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Storage of flammable liquids underground. 57... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4460 Storage of flammable liquids underground. (a) Flammable liquids shall not be stored underground, except— (1) Small...

  18. 30 CFR 77.1103 - Flammable liquids; storage.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Flammable liquids; storage. 77.1103 Section 77... Fire Protection § 77.1103 Flammable liquids; storage. (a) Flammable liquids shall be stored in accordance with standards of the National Fire Protection Association. Small quantities of flammable...

  19. 14 CFR 25.1727 - Flammable fluid shutoff means: EWIS.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Flammable fluid shutoff means: EWIS. 25... Systems (EWIS) § 25.1727 Flammable fluid shutoff means: EWIS. EWIS associated with each flammable fluid... zone will not affect operation of the flammable fluid shutoff means, in accordance with the...

  20. 14 CFR 25.1727 - Flammable fluid shutoff means: EWIS.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 1 2013-01-01 2013-01-01 false Flammable fluid shutoff means: EWIS. 25... Systems (EWIS) § 25.1727 Flammable fluid shutoff means: EWIS. EWIS associated with each flammable fluid... zone will not affect operation of the flammable fluid shutoff means, in accordance with the...

  1. 14 CFR 25.1727 - Flammable fluid shutoff means: EWIS.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 1 2014-01-01 2014-01-01 false Flammable fluid shutoff means: EWIS. 25... Systems (EWIS) § 25.1727 Flammable fluid shutoff means: EWIS. EWIS associated with each flammable fluid... zone will not affect operation of the flammable fluid shutoff means, in accordance with the...

  2. 14 CFR 25.1727 - Flammable fluid shutoff means: EWIS.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Flammable fluid shutoff means: EWIS. 25... Systems (EWIS) § 25.1727 Flammable fluid shutoff means: EWIS. EWIS associated with each flammable fluid... zone will not affect operation of the flammable fluid shutoff means, in accordance with the...

  3. 14 CFR 25.1727 - Flammable fluid shutoff means: EWIS.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 1 2012-01-01 2012-01-01 false Flammable fluid shutoff means: EWIS. 25... Systems (EWIS) § 25.1727 Flammable fluid shutoff means: EWIS. EWIS associated with each flammable fluid... zone will not affect operation of the flammable fluid shutoff means, in accordance with the...

  4. Plant traits determine forest flammability

    NASA Astrophysics Data System (ADS)

    Zylstra, Philip; Bradstock, Ross

    2016-04-01

    Carbon and nutrient cycles in forest ecosystems are influenced by their inherent flammability - a property determined by the traits of the component plant species that form the fuel and influence the micro climate of a fire. In the absence of a model capable of explaining the complexity of such a system however, flammability is frequently represented by simple metrics such as surface fuel load. The implications of modelling fire - flammability feedbacks using surface fuel load were examined and compared to a biophysical, mechanistic model (Forest Flammability Model) that incorporates the influence of structural plant traits (e.g. crown shape and spacing) and leaf traits (e.g. thickness, dimensions and moisture). Fuels burn with values of combustibility modelled from leaf traits, transferring convective heat along vectors defined by flame angle and with plume temperatures that decrease with distance from the flame. Flames are re-calculated in one-second time-steps, with new leaves within the plant, neighbouring plants or higher strata ignited when the modelled time to ignition is reached, and other leaves extinguishing when their modelled flame duration is exceeded. The relative influence of surface fuels, vegetation structure and plant leaf traits were examined by comparing flame heights modelled using three treatments that successively added these components within the FFM. Validation was performed across a diverse range of eucalypt forests burnt under widely varying conditions during a forest fire in the Brindabella Ranges west of Canberra (ACT) in 2003. Flame heights ranged from 10 cm to more than 20 m, with an average of 4 m. When modelled from surface fuels alone, flame heights were on average 1.5m smaller than observed values, and were predicted within the error range 28% of the time. The addition of plant structure produced predicted flame heights that were on average 1.5m larger than observed, but were correct 53% of the time. The over-prediction in this

  5. Unmanned Vehicle Material Flammability Test

    NASA Technical Reports Server (NTRS)

    Urban, David L.; Ruff, Gary A.; Minster, Olivier; Toth, Balazs; Fernandez-Pello, A. Carlos; Tien, James S.; Torero, Jose L.; Cowlard, Adam J.; Legros, Guillaume; Eigenbrod, Christian; Smirnov, Nickolay; Fujita, Osamu; Rouvreau, Sebastien; Jomaas, Grunde

    2012-01-01

    Microgravity fire behaviour remains poorly understood and a significant risk for spaceflight An experiment is under development that will provide the first real opportunity to examine this issue focussing on two objectives: a) Flame Spread. b) Material Flammability. This experiment has been shown to be feasible on both ESA's ATV and Orbital Science's Cygnus vehicles with the Cygnus as the current base-line carrier. An international topical team has been formed to develop concepts for that experiment and support its implementation: a) Pressure Rise prediction. b) Sample Material Selection. This experiment would be a landmark for spacecraft fire safety with the data and subsequent analysis providing much needed verification of spacecraft fire safety protocols for the crews of future exploration vehicles and habitats.

  6. Tank 241-C-103 headspace flammability

    SciTech Connect

    Huckaby, J.L.

    1994-01-01

    Information regarding flammable vapors, gases, and aerosols is presented for the purpose of resolving the tank 241-C-103 headspace flammability issue. Analyses of recent vapor and liquid samples, as well as visual inspections of the tank headspace, are discussed in the context of tank dynamics. This document is restricted to issues regarding the flammability of gases, vapors, and an aerosol that may exist in the headspace of tank 241-C-103. While discussing certain information about the organic liquid present in tank 241-C-103, this document addresses neither the potential for, nor consequences of, a pool fire involving this organic liquid; they will be discussed in a separate report.

  7. Determinants of flammability in savanna grass species.

    PubMed

    Simpson, Kimberley J; Ripley, Brad S; Christin, Pascal-Antoine; Belcher, Claire M; Lehmann, Caroline E R; Thomas, Gavin H; Osborne, Colin P

    2016-01-01

    Tropical grasses fuel the majority of fires on Earth. In fire-prone landscapes, enhanced flammability may be adaptive for grasses via the maintenance of an open canopy and an increase in spatiotemporal opportunities for recruitment and regeneration. In addition, by burning intensely but briefly, high flammability may protect resprouting buds from lethal temperatures. Despite these potential benefits of high flammability to fire-prone grasses, variation in flammability among grass species, and how trait differences underpin this variation, remains unknown.By burning leaves and plant parts, we experimentally determined how five plant traits (biomass quantity, biomass density, biomass moisture content, leaf surface-area-to-volume ratio and leaf effective heat of combustion) combined to determine the three components of flammability (ignitability, sustainability and combustibility) at the leaf and plant scales in 25 grass species of fire-prone South African grasslands at a time of peak fire occurrence. The influence of evolutionary history on flammability was assessed based on a phylogeny built here for the study species.Grass species differed significantly in all components of flammability. Accounting for evolutionary history helped to explain patterns in leaf-scale combustibility and sustainability. The five measured plant traits predicted components of flammability, particularly leaf ignitability and plant combustibility in which 70% and 58% of variation, respectively, could be explained by a combination of the traits. Total above-ground biomass was a key driver of combustibility and sustainability with high biomass species burning more intensely and for longer, and producing the highest predicted fire spread rates. Moisture content was the main influence on ignitability, where species with higher moisture contents took longer to ignite and once alight burnt at a slower rate. Biomass density, leaf surface-area-to-volume ratio and leaf effective heat of combustion

  8. 29 CFR 1915.36 - Flammable liquids.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... flammable atmosphere under the conditions of use, the following precautions shall be taken: (1) Smoking... atmospheres, or approved as permissible by the Mine Safety and Health Administration or the U.S. Coast Guard...

  9. Organizing Questions for Reduced-Gravity Flammability

    NASA Technical Reports Server (NTRS)

    Miller, Fletcher

    2004-01-01

    A team consisting of of the Microgravity Flight Project Scientists for solid flammability experiments has been reviewing and prioritizing a set of organizing questions for fire prevention (material flammability).In particular the team has been charged with determining:What experiments must be conducted to best answer these questions, and can some of the quest ions be answered using existing/planned hardware or experimental concepts?Is the NASA STD 6001, Test 1 configuration conservative or non-conservative in assessing material flammability in reduced gravity?NASA ST D 6001, Test 1 is an upward flammability test, considered the most stringent test in normal gravity. A material that passes this test would most likely not burn in a quiescent microgravity environment.A forced ignition and spread test is described.

  10. 29 CFR 1915.36 - Flammable liquids.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... flammable atmosphere under the conditions of use, the following precautions shall be taken: (1) Smoking... sufficient slack to prevent undue stress or chafing. (6) Suitable fire extinguishing equipment shall...

  11. Performance sensitivity analysis of Department of Energy-Chrysler upgraded automotive gas turbine engine, S/N 5-4

    NASA Technical Reports Server (NTRS)

    Johnsen, R. L.

    1979-01-01

    The performance sensitivity of a two-shaft automotive gas turbine engine to changes in component performance and cycle operating parameters was examined. Sensitivities were determined for changes in turbomachinery efficiency, compressor inlet temperature, power turbine discharge temperature, regenerator effectiveness, regenerator pressure drop, and several gas flow and heat leaks. Compressor efficiency was found to have the greatest effect on system performance.

  12. Benzene/nitrous oxide flammability in the precipitate hydrolysis process

    SciTech Connect

    Jacobs, R A

    1989-09-18

    The HAN (hydroxylamine nitrate) process for destruction of nitrite in precipitate hydrolysis produces nitrous oxide (N2O) gas as one of the products. N2O can form flammable mixtures with benzene which is also present due to radiolysis and hydrolysis of tetraphenylborate. Extensive flame modeling and explosion testing was undertaken to define the minimum oxidant for combustion of N2O/benzene using both nitrogen and carbon dioxide as diluents. The attached memorandum interprets and documents the results of the studies.

  13. Spectrometers for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) Upgrade to Full Sun-Sky-Cloud-Trace Gas Spectrometry Capability for Airborne Science

    NASA Astrophysics Data System (ADS)

    Dunagan, S. E.; Flynn, C. J.; Johnson, R. R.; Kacenelenbogen, M. S.; Knobelspiesse, K. D.; LeBlanc, S. E.; Livingston, J. M.; Redemann, J.; Russell, P. B.; Schmid, B.; Segal-Rosenhaimer, M.; Shinozuka, Y.

    2014-12-01

    The Spectrometers for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) instrument has been developed at NASA Ames in collaboration with Pacific Northwest National Laboratory (PNNL) and NASA Goddard, supported substantially since 2009 by NASA's Radiation Science Program and Earth Science Technology Office. It combines grating spectrometers with fiber optic links to a tracking, scanning head to enable sun tracking, sky scanning, and zenith viewing. 4STAR builds on the long and productive heritage of the NASA Ames Airborne Tracking Sunphotometers (AATS-6 and -14), which have yielded more than 100 peer-reviewed publications and extensive archived data sets in many NASA Airborne Science campaigns from 1986 to the present. The baseline 4STAR instrument has provided extensive data supporting the TCAP (Two Column Aerosol Project, July 2012 & Feb. 2013), SEAC4RS (Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys, 2013), and ARISE (Arctic Radiation - IceBridge Sea and Ice Experiment, 2014), field campaigns.This poster presents plans and progress for an upgrade to the 4STAR instrument to achieve full science capability, including (1) direct-beam sun tracking measurements to derive aerosol optical depth spectra, (2) sky radiance measurements to retrieve aerosol absorption and type (via complex refractive index and mode-resolved size distribution), (3) cloud properties via zenith radiance, and (4) trace gas spectrometry. Technical progress in context with the governing physics is reported on several upgrades directed at improved light collection and usage, particularly as related to spectrally and radiometrically stable propagation through the collection light path. In addition, improvements to field calibration and verification, and flight operability and reliability are addressed.

  14. Generation of basic centers in high-silica zeolites and their application in gas-phase upgrading of bio-oil.

    PubMed

    Keller, Tobias C; Rodrigues, Elodie G; Pérez-Ramírez, Javier

    2014-06-01

    High-silica zeolites have been reported recently as efficient catalysts for liquid- and gas-phase condensation reactions because of the presence of a complementary source of basicity compared to Al-rich basic zeolites. Herein, we describe the controlled generation of these active sites on silica-rich FAU, BEA, and MFI zeolites. Through the application of a mild base treatment in aqueous Na2CO3, alkali-metal-coordinating defects are generated within the zeolite whereas the porous properties are fully preserved. The resulting catalysts were applied in the gas-phase condensation of propanal at 673 K as a model reaction for the catalytic upgrading of pyrolysis oil, for which an up to 20-fold increased activity compared to the unmodified zeolites was attained. The moderate basicity of these new sites leads to a coke resistance superior to traditional base catalysts such as CsX and MgO, and comparable activity and excellent selectivity is achieved for the condensation pathways. Through strategic acid and base treatments and the use of magic-angle spinning NMR spectroscopy, the nature of the active sites was investigated, which supports the theory of siloxy sites as basic centers. This contribution represents a key step in the understanding and design of high-silica base catalysts for the intermediate deoxygenation of crude bio-oil prior to the hydrotreating step for the production of second-generation biofuels. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2003-01-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a liquid flue gas conditioning system was completed at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Two cohesivity-specific additive formulations, ADA-44C and ADA-51, will be evaluated. In addition, ammonia conditioning will also be compared.

  16. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2000-09-01

    The U.S. Department of Energy and ADA Environmental Solutions have begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During the second reporting quarter for this project, design and development is continuing on an electrostatic tensiometer to measure cohesion of flyash layers. A dedicated test fixture to automate flyash electrical resistivity testing is also underway. Ancillary instrumentation to control gas humidification within these test fixtures is also under construction.

  17. Upgrade of PARC2D to include real gas effects. [computer program for flowfield surrounding aeroassist flight experiment

    NASA Technical Reports Server (NTRS)

    Saladino, Anthony; Praharaj, Sarat C.; Collins, Frank G.; Seaford, C. Mark

    1990-01-01

    This paper presents a description of the changes and additions to the perfect gas PARC2D code to include chemical equilibrium effects, resulting in a code called PARCEQ2D. The work developed out of a need to have the capability of more accurately representing the flowfield surrounding the aeroassist flight experiment (AFE) vehicle. Use is made of the partition function of statistical mechanics in the evaluation of the thermochemical properties. This approach will allow the PARC code to be extended to thermal nonequilibrium when this task is undertaken in the future. The transport properties follow from formulae from the kinetic theory of gases. Results are presented for a two-dimensional AFE that compare perfect gas and real gas solutions at flight conditions, showing vast differences between the two cases.

  18. Sampling and Analysis Plan for Flammable Gases in Inactive Miscellaneous Underground Storage Tanks

    SciTech Connect

    NGUYEN, D.M.

    2000-02-01

    This sampling and analysis plan (SAP) identifies the field measurements for a screening of flammable gases in the vapor space of the inactive miscellaneous underground storage tanks (IMUSTs) currently assigned to the River Protection Project (RPP). If a measurement exceeds 25% of the lower flammability limit (LFL), vapor grab samples will be collected for laboratory analysis. This SAP also specifies the sample collection, laboratory analysis, quality assurance/quality control (QA/QC), and reporting objectives for grab sampling. Technical bases for the sampling objectives are provided in the Tank Safety Screening Data Quality Objectives (Dukelow et al 1995). The screening data will be used to determine if additional data are needed to support closure of a flammable gas unreviewed safety question for these facilities.

  19. Unmanned Vehicle Material Flammability Test

    NASA Technical Reports Server (NTRS)

    Urban, David; Ruff, Gary A.; Fernandez-Pello, A. Carlos; T’ien, James S.; Torero, Jose L.; Cowlard, Adam; Rouvreau, Sebastian; Minster, Olivier; Toth, Balazs; Legros, Guillaume; Eigenbrod, Christian; Smirnov, Nickolay; Fujita, Osamu; Jomaas, Grande

    2013-01-01

    Microgravity combustion phenomena have been an active area of research for the past 3 decades however, there have been very few experiments directly studying spacecraft fire safety under low-gravity conditions. Furthermore, none of these experiments have studied sample and environment sizes typical of those expected in a spacecraft fire. All previous experiments have been limited to samples of the order of 10 cm in length and width or smaller. Terrestrial fire safety standards for all other habitable volumes on earth, e.g. mines, buildings, airplanes, ships, etc., are based upon testing conducted with full-scale fires. Given the large differences between fire behavior in normal and reduced gravity, this lack of an experimental data base at relevant length scales forces spacecraft designers to base their designs using 1-g understanding. To address this question a large scale spacecraft fire experiment has been proposed by an international team of investigators. This poster presents the objectives, status and concept of this collaborative international project to examine spacecraft material flammability at realistic scales. The concept behind this project is to utilize an unmanned spacecraft such as Orbital Cygnus vehicle after it has completed its delivery of cargo to the ISS and it has begun its return journey to earth. This experiment will consist of a flame spread test involving a meter scale sample ignited in the pressurized volume of the spacecraft and allowed to burn to completion while measurements are made. A computer modeling effort will complement the experimental effort. Although the experiment will need to meet rigorous safety requirements to ensure the carrier vehicle does not sustain damage, the absence of a crew removes the need for strict containment of combustion products. This will facilitate the examination of fire behavior on a scale that is relevant to spacecraft fire safety and will provide unique data for fire model validation. This will be

  20. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2002-07-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was completed at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. The product was effective as a flue gas conditioner. However, ongoing problems with in-duct deposition resulting from the flue gas conditioning were not entirely resolved. Primarily these problems were the result of difficulties encountered with retrofit of an existing spray humidification system. Eventually it proved necessary to replace all of the original injection lances and to manually bypass the PLC-based air/liquid feed control. This yielded substantial improvement in spray atomization and system reliability. However, the plant opted not to install a permanent system. Also in this quarter, preparations continued for a test of the cohesivity additives at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

  1. Pressure Drop Versus Flow Rate Analysis of the Limited Streamer Tube Gas System of the BaBar Muon Detector Upgrade

    SciTech Connect

    Yi, M.

    2004-09-03

    It has been proposed that Limited Streamer Tubes (LST) be used in the current upgrade of the muon detector in the BaBar detector. An LST consists of a thin silver plated wire centered in a graphite-coated cell. One standard LST tube consists of eight such cells, and two or three such tubes form an LST module. Under operation, the cells are filled with a gas mixture of CO{sub 2}, argon and isobutane. During normal operation of the detector, the gas will be flushed out of the system at a constant low rate of one volume change per day. During times such as installation, however, it is often desired to flush and change the LST gas volumes very rapidly, leading to higher than normal pressure which may damage the modules. This project studied this pressure as a function of flow rate and the number of modules that are put in series in search of the maximal safe flow rate at which to flush the modules. Measurements of pressure drop versus flow rate were taken using a flow meter and a pressure transducer on configurations of one to five modules put in series. Minimal Poly-Flo tubing was used for all connections between test equipment and modules. They contributed less than 25% to all measurements. A ratio of 0.00022 {+-} 0.00001 mmHg per Standard Cubic Centimeter per Minute (SCCM) per module was found, which was a slight overestimate since it included the contributions from the tubing connections. However, for the purpose of finding a flow rate at which the modules can be safely flushed, this overestimate acts as a safety cushion. For a standard module with a volume of 16 liters and a known safe overpressure of 2 inches of water, the ratio translates into a flow rate of 17000 {+-} 1000SCCM and a time requirement of 56 {+-} 5 seconds to flush an entire module.

  2. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  3. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-10-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, progress was made in obtaining an industry partner for a long-term demonstration and in technology transfer activities. Engineering and equipment procurement activities related to the long-term demonstration were also completed.

  4. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-05-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of flyash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory flyash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  5. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-01-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During the third reporting quarter, the electrostatic tensiometer for laboratory determination of flyash cohesivity was completed. Modifications were made to this method to improve repeatability. In addition, a new multi-cell laboratory flyash resistivity furnace was completed. Also during this quarter an agreement was reached for the initial field trial of the new additives at the City of Ames, Iowa Municipal Power Plant.

  6. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2003-07-30

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. This quarterly report summarizes project activity for the period April-June, 2003. In this period there was limited activity and no active field trials. Results of ash analysis from the AEP Conesville demonstration were received. In addition, a site visit was made to We Energies Presque Isle Power Plant and a proposal extended for a flue gas conditioning trial with the ADA-51 cohesivity additive. It is expected that this will be the final full-scale evaluation on the project.

  7. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2002-01-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a flue gas conditioning system was completed at PacifiCorp Jim Bridger Power Plant. Performance testing was underway. Results will be detailed in the next quarterly and subsequent technical summary reports. Also in this quarter, discussions were initiated with a prospective long-term candidate plant. This plant fires a bituminous coal and has opacity performance issues related to fly ash re-entrainment. Ammonia conditioning has been proposed here, but there is interest in liquid additives as a safer alternative.

  8. Secondary compounds enhance flammability in a Mediterranean plant.

    PubMed

    Pausas, J G; Alessio, G A; Moreira, B; Segarra-Moragues, J G

    2016-01-01

    Some plant secondary compounds, such as terpenes, are very flammable; however, their role in enhancing plant flammability is poorly understood and often neglected in reviews on plant chemical ecology. This is relevant as there is growing evidence that flammability-enhancing traits are adaptive in fire-prone ecosystems. We analyzed the content of monoterpenes and sesquiterpenes, performed flammability tests and genotyped microsatellite markers, all in the same individuals of Rosmarinus officinalis, to evaluate the link between the content of terpenes, flammability and the genetic similarity among individuals. The results suggest that terpenes enhance flammability in R. officinalis, and that variability in flammability among individuals is likely to have a genetic basis. Overall our results suggest that the capacity to produce and store terpenes can be considered a flammability-enhancing trait and could have an adaptive value in fire-prone ecosystems.

  9. 16 CFR Figure 2 to Part 1610 - Flammability Apparatus Views

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Flammability Apparatus Views 2 Figure 2 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS... Apparatus Views ER25MR08.001...

  10. 16 CFR Figure 2 to Part 1610 - Flammability Apparatus Views

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 16 Commercial Practices 2 2011-01-01 2011-01-01 false Flammability Apparatus Views 2 Figure 2 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS... Apparatus Views ER25MR08.001...

  11. 49 CFR 172.420 - FLAMMABLE SOLID label.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.420 FLAMMABLE SOLID label. (a) Except for size and color, the FLAMMABLE...

  12. 49 CFR 172.420 - FLAMMABLE SOLID label.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.420 FLAMMABLE SOLID label. (a) Except for size and color, the FLAMMABLE...

  13. 49 CFR 172.420 - FLAMMABLE SOLID label.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.420 FLAMMABLE SOLID label. (a) Except for size and color, the FLAMMABLE...

  14. 49 CFR 172.420 - FLAMMABLE SOLID label.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Labeling § 172.420 FLAMMABLE SOLID label. (a) Except for size and color, the FLAMMABLE...

  15. Correlating Flammability of Materials with FTIR Analysis Test Results

    NASA Technical Reports Server (NTRS)

    Moore, Robin; Whitfield, Steve

    2003-01-01

    The purpose of this experiment was to correlate flammability data with FTIR test results. Kydex 100 is a blend of chlorinated polyvinyl chloride and polymethylmethacrylate, with some filler materials. Samples supplied were 0.125 in. thick. 10 samples were taken from a sheet of Kydex and analyzed for flammability and by FTIR spectroscopy. This material was utilized as a round robin sample for flammability testing. The flammability test results were found to vary across the same sheet.

  16. Flammability of Heterogeneously Combusting Metals

    NASA Technical Reports Server (NTRS)

    Jones, Peter D.

    1998-01-01

    Most engineering materials, including some metals, most notably aluminum, burn in homogeneous combustion. 'Homogeneous' refers to both the fuel and the oxidizer being in the same phase, which is usually gaseous. The fuel and oxidizer are well mixed in the combustion reaction zone, and heat is released according to some relation like q(sub c) = delta H(sub c)c[((rho/rho(sub 0))]exp a)(exp -E(sub c)/RT), Eq. (1) where the pressure exponent a is usually close to unity. As long as there is enough heat released, combustion is sustained. It is useful to conceive of a threshold pressure beyond which there is sufficient heat to keep the temperature high enough to sustain combustion, and beneath which the heat is so low that temperature drains away and the combustion is extinguished. Some materials burn in heterogeneous combustion, in which the fuel and oxidizer are in different phases. These include iron and nickel based alloys, which burn in the liquid phase with gaseous oxygen. Heterogeneous combustion takes place on the surface of the material (fuel). Products of combustion may appear as a solid slag (oxide) which progressively covers the fuel. Propagation of the combustion melts and exposes fresh fuel. Heterogeneous combustion heat release also follows the general form of Eq.(1), except that the pressure exponent a tends to be much less than 1. Therefore, the increase in heat release with increasing pressure is not as dramatic as it is in homogeneous combustion. Although the concept of a threshold pressure still holds in heterogeneous combustion, the threshold is more difficult to identify experimentally, and pressure itself becomes less important relative to the heat transfer paths extant in any specific application. However, the constants C, a, and E(sub c) may still be identified by suitable data reduction from heterogeneous combustion experiments, and may be applied in a heat transfer model to judge the flammability of a material in any particular actual

  17. 16 CFR Figure 2 to Part 1610 - Flammability Apparatus Views

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 16 Commercial Practices 2 2013-01-01 2013-01-01 false Flammability Apparatus Views 2 Figure 2 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF CLOTHING TEXTILES Pt. 1610, Fig. 2 Figure 2 to Part...

  18. 16 CFR Figure 2 to Part 1610 - Flammability Apparatus Views

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 16 Commercial Practices 2 2012-01-01 2012-01-01 false Flammability Apparatus Views 2 Figure 2 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF CLOTHING TEXTILES Pt.1610, Fig. 2 Figure 2 to Part...

  19. 16 CFR Figure 2 to Part 1610 - Flammability Apparatus Views

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 16 Commercial Practices 2 2014-01-01 2014-01-01 false Flammability Apparatus Views 2 Figure 2 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF CLOTHING TEXTILES Pt. 1610, Fig. 2 Figure 2 to Part...

  20. 49 CFR 172.419 - FLAMMABLE LIQUID label.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false FLAMMABLE LIQUID label. 172.419 Section 172.419... SECURITY PLANS Labeling § 172.419 FLAMMABLE LIQUID label. (a) Except for size and color the FLAMMABLE LIQUID label must be as follows: EC02MR91.023 (b) In addition to complying with § 172.407, the...

  1. 49 CFR 172.419 - FLAMMABLE LIQUID label.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false FLAMMABLE LIQUID label. 172.419 Section 172.419... SECURITY PLANS Labeling § 172.419 FLAMMABLE LIQUID label. (a) Except for size and color the FLAMMABLE LIQUID label must be as follows: EC02MR91.023 (b) In addition to complying with § 172.407, the...

  2. 49 CFR 172.419 - FLAMMABLE LIQUID label.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false FLAMMABLE LIQUID label. 172.419 Section 172.419... SECURITY PLANS Labeling § 172.419 FLAMMABLE LIQUID label. (a) Except for size and color the FLAMMABLE LIQUID label must be as follows: EC02MR91.023 (b) In addition to complying with § 172.407, the...

  3. 49 CFR 172.419 - FLAMMABLE LIQUID label.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false FLAMMABLE LIQUID label. 172.419 Section 172.419... SECURITY PLANS Labeling § 172.419 FLAMMABLE LIQUID label. (a) Except for size and color the FLAMMABLE LIQUID label must be as follows: EC02MR91.023 (b) In addition to complying with § 172.407, the...

  4. 49 CFR 172.419 - FLAMMABLE LIQUID label.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 2 2014-10-01 2014-10-01 false FLAMMABLE LIQUID label. 172.419 Section 172.419... SECURITY PLANS Labeling § 172.419 FLAMMABLE LIQUID label. (a) Except for size and color the FLAMMABLE LIQUID label must be as follows: EC02MR91.023 (b) In addition to complying with § 172.407, the...

  5. 46 CFR 147.45 - Flammable and combustible liquids.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Flammable and combustible liquids. 147.45 Section 147.45... Stowage and Other Special Requirements for Particular Materials § 147.45 Flammable and combustible liquids. (a) This section applies to the stowage and transfer of flammable and combustible liquids...

  6. 46 CFR 147.45 - Flammable and combustible liquids.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Flammable and combustible liquids. 147.45 Section 147.45... Stowage and Other Special Requirements for Particular Materials § 147.45 Flammable and combustible liquids. (a) This section applies to the stowage and transfer of flammable and combustible liquids...

  7. 46 CFR 147.45 - Flammable and combustible liquids.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Flammable and combustible liquids. 147.45 Section 147.45... Stowage and Other Special Requirements for Particular Materials § 147.45 Flammable and combustible liquids. (a) This section applies to the stowage and transfer of flammable and combustible liquids...

  8. 46 CFR 147.45 - Flammable and combustible liquids.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Flammable and combustible liquids. 147.45 Section 147.45... Stowage and Other Special Requirements for Particular Materials § 147.45 Flammable and combustible liquids. (a) This section applies to the stowage and transfer of flammable and combustible liquids...

  9. 16 CFR 1500.133 - Extremely flammable contact adhesives; labeling.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 16 Commercial Practices 2 2011-01-01 2011-01-01 false Extremely flammable contact adhesives... REGULATIONS § 1500.133 Extremely flammable contact adhesives; labeling. (a) Extremely flammable contact adhesives, also known as contact bonding cements, when distributed in containers intended or suitable...

  10. 16 CFR 1500.133 - Extremely flammable contact adhesives; labeling.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 16 Commercial Practices 2 2014-01-01 2014-01-01 false Extremely flammable contact adhesives... REGULATIONS § 1500.133 Extremely flammable contact adhesives; labeling. (a) Extremely flammable contact adhesives, also known as contact bonding cements, when distributed in containers intended or suitable...

  11. 16 CFR 1500.133 - Extremely flammable contact adhesives; labeling.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 16 Commercial Practices 2 2013-01-01 2013-01-01 false Extremely flammable contact adhesives... REGULATIONS § 1500.133 Extremely flammable contact adhesives; labeling. (a) Extremely flammable contact adhesives, also known as contact bonding cements, when distributed in containers intended or suitable...

  12. 16 CFR 1500.133 - Extremely flammable contact adhesives; labeling.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Extremely flammable contact adhesives... REGULATIONS § 1500.133 Extremely flammable contact adhesives; labeling. (a) Extremely flammable contact adhesives, also known as contact bonding cements, when distributed in containers intended or suitable...

  13. 16 CFR 1500.133 - Extremely flammable contact adhesives; labeling.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 16 Commercial Practices 2 2012-01-01 2012-01-01 false Extremely flammable contact adhesives... REGULATIONS § 1500.133 Extremely flammable contact adhesives; labeling. (a) Extremely flammable contact adhesives, also known as contact bonding cements, when distributed in containers intended or suitable...

  14. 16 CFR 1611.3 - Flammability-general requirement.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 16 Commercial Practices 2 2011-01-01 2011-01-01 false Flammability-general requirement. 1611.3 Section 1611.3 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF VINYL PLASTIC FILM The Standard § 1611.3 Flammability—general...

  15. 16 CFR 1611.3 - Flammability-general requirement.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 16 Commercial Practices 2 2013-01-01 2013-01-01 false Flammability-general requirement. 1611.3 Section 1611.3 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF VINYL PLASTIC FILM The Standard § 1611.3 Flammability—general...

  16. 16 CFR 1611.3 - Flammability-general requirement.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 16 Commercial Practices 2 2014-01-01 2014-01-01 false Flammability-general requirement. 1611.3 Section 1611.3 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF VINYL PLASTIC FILM The Standard § 1611.3 Flammability—general...

  17. 16 CFR 1611.3 - Flammability-general requirement.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 16 Commercial Practices 2 2012-01-01 2012-01-01 false Flammability-general requirement. 1611.3 Section 1611.3 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF VINYL PLASTIC FILM The Standard § 1611.3 Flammability—general...

  18. 16 CFR 1611.3 - Flammability-general requirement.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Flammability-general requirement. 1611.3 Section 1611.3 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF VINYL PLASTIC FILM The Standard § 1611.3 Flammability—general...

  19. 16 CFR 423.9 - Conflict with flammability standards.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 16 Commercial Practices 1 2012-01-01 2012-01-01 false Conflict with flammability standards. 423.9... TEXTILE WEARING APPAREL AND CERTAIN PIECE GOODS AS AMENDED § 423.9 Conflict with flammability standards. If there is a conflict between this regulation and any regulations issued under the Flammable Fabrics...

  20. 16 CFR 423.9 - Conflict with flammability standards.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 16 Commercial Practices 1 2013-01-01 2013-01-01 false Conflict with flammability standards. 423.9... TEXTILE WEARING APPAREL AND CERTAIN PIECE GOODS AS AMENDED § 423.9 Conflict with flammability standards. If there is a conflict between this regulation and any regulations issued under the Flammable Fabrics...

  1. 16 CFR 423.9 - Conflict with flammability standards.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 16 Commercial Practices 1 2014-01-01 2014-01-01 false Conflict with flammability standards. 423.9... TEXTILE WEARING APPAREL AND CERTAIN PIECE GOODS AS AMENDED § 423.9 Conflict with flammability standards. If there is a conflict between this regulation and any regulations issued under the Flammable Fabrics...

  2. 46 CFR 182.480 - Flammable vapor detection systems.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Flammable vapor detection systems. 182.480 Section 182... detection systems. (a) A flammable vapor detection system required by § 182.410(c) must meet UL 1110... checking the proper operation of a flammable vapor detection system must be posted at the primary operating...

  3. 46 CFR 182.480 - Flammable vapor detection systems.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 7 2011-10-01 2011-10-01 false Flammable vapor detection systems. 182.480 Section 182... detection systems. (a) A flammable vapor detection system required by § 182.410(c) must meet UL 1110... checking the proper operation of a flammable vapor detection system must be posted at the primary operating...

  4. 46 CFR 182.480 - Flammable vapor detection systems.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 7 2013-10-01 2013-10-01 false Flammable vapor detection systems. 182.480 Section 182... detection systems. (a) A flammable vapor detection system required by § 182.410(c) must meet UL 1110... checking the proper operation of a flammable vapor detection system must be posted at the primary operating...

  5. 46 CFR 182.480 - Flammable vapor detection systems.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 7 2012-10-01 2012-10-01 false Flammable vapor detection systems. 182.480 Section 182... detection systems. (a) A flammable vapor detection system required by § 182.410(c) must meet UL 1110... checking the proper operation of a flammable vapor detection system must be posted at the primary operating...

  6. 14 CFR 25.1723 - Flammable fluid fire protection: EWIS.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 1 2012-01-01 2012-01-01 false Flammable fluid fire protection: EWIS. 25... Systems (EWIS) § 25.1723 Flammable fluid fire protection: EWIS. EWIS components located in each area where flammable fluid or vapors might escape by leakage of a fluid system must be considered a potential ignition...

  7. 14 CFR 27.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 1 2012-01-01 2012-01-01 false Flammable fluid fire protection. 27.863....863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the fluids and...

  8. 14 CFR 25.1183 - Flammable fluid-carrying components.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Flammable fluid-carrying components. 25... Protection § 25.1183 Flammable fluid-carrying components. (a) Except as provided in paragraph (b) of this section, each line, fitting, and other component carrying flammable fluid in any area subject to engine...

  9. 14 CFR 27.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 1 2014-01-01 2014-01-01 false Flammable fluid fire protection. 27.863....863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the fluids and...

  10. 14 CFR 25.1723 - Flammable fluid fire protection: EWIS.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Flammable fluid fire protection: EWIS. 25... Systems (EWIS) § 25.1723 Flammable fluid fire protection: EWIS. EWIS components located in each area where flammable fluid or vapors might escape by leakage of a fluid system must be considered a potential ignition...

  11. 14 CFR 25.1723 - Flammable fluid fire protection: EWIS.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Flammable fluid fire protection: EWIS. 25... Systems (EWIS) § 25.1723 Flammable fluid fire protection: EWIS. EWIS components located in each area where flammable fluid or vapors might escape by leakage of a fluid system must be considered a potential ignition...

  12. 14 CFR 27.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 1 2013-01-01 2013-01-01 false Flammable fluid fire protection. 27.863....863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the fluids and...

  13. 14 CFR 29.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 1 2012-01-01 2012-01-01 false Flammable fluid fire protection. 29.863... § 29.863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the...

  14. 14 CFR 29.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 1 2014-01-01 2014-01-01 false Flammable fluid fire protection. 29.863... § 29.863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the...

  15. 14 CFR 23.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Flammable fluid fire protection. 23.863... Construction Fire Protection § 23.863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability...

  16. 14 CFR 25.1723 - Flammable fluid fire protection: EWIS.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 1 2013-01-01 2013-01-01 false Flammable fluid fire protection: EWIS. 25... Systems (EWIS) § 25.1723 Flammable fluid fire protection: EWIS. EWIS components located in each area where flammable fluid or vapors might escape by leakage of a fluid system must be considered a potential ignition...

  17. 14 CFR 25.1723 - Flammable fluid fire protection: EWIS.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 1 2014-01-01 2014-01-01 false Flammable fluid fire protection: EWIS. 25... Systems (EWIS) § 25.1723 Flammable fluid fire protection: EWIS. EWIS components located in each area where flammable fluid or vapors might escape by leakage of a fluid system must be considered a potential ignition...

  18. 14 CFR 29.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 1 2013-01-01 2013-01-01 false Flammable fluid fire protection. 29.863... § 29.863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the...

  19. 14 CFR 27.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Flammable fluid fire protection. 27.863....863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the fluids and...

  20. 14 CFR 29.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Flammable fluid fire protection. 29.863... § 29.863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the...

  1. 14 CFR 25.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Flammable fluid fire protection. 25.863....863 Flammable fluid fire protection. (a) In each area where flammable fluids or vapors might escape by leakage of a fluid system, there must be means to minimize the probability of ignition of the fluids and...

  2. 46 CFR 109.557 - Flammable and combustible liquids: Carriage.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Flammable and combustible liquids: Carriage. 109.557... DRILLING UNITS OPERATIONS Miscellaneous § 109.557 Flammable and combustible liquids: Carriage. The master or person in charge shall ensure that— (a) Flammable and combustible liquids in bulk are not carried...

  3. 46 CFR 147.45 - Flammable and combustible liquids.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Flammable and combustible liquids. 147.45 Section 147.45... Stowage and Other Special Requirements for Particular Materials § 147.45 Flammable and combustible liquids. (a) This section applies to the stowage and transfer of flammable and combustible liquids (including...

  4. 46 CFR 109.557 - Flammable and combustible liquids: Carriage.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Flammable and combustible liquids: Carriage. 109.557... DRILLING UNITS OPERATIONS Miscellaneous § 109.557 Flammable and combustible liquids: Carriage. The master or person in charge shall ensure that— (a) Flammable and combustible liquids in bulk are not carried...

  5. 46 CFR 109.557 - Flammable and combustible liquids: Carriage.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Flammable and combustible liquids: Carriage. 109.557... DRILLING UNITS OPERATIONS Miscellaneous § 109.557 Flammable and combustible liquids: Carriage. The master or person in charge shall ensure that— (a) Flammable and combustible liquids in bulk are not carried...

  6. 46 CFR 109.557 - Flammable and combustible liquids: Carriage.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Flammable and combustible liquids: Carriage. 109.557... DRILLING UNITS OPERATIONS Miscellaneous § 109.557 Flammable and combustible liquids: Carriage. The master or person in charge shall ensure that— (a) Flammable and combustible liquids in bulk are not carried...

  7. 46 CFR 111.105-37 - Flammable anesthetics.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Flammable anesthetics. 111.105-37 Section 111.105-37...-GENERAL REQUIREMENTS Hazardous Locations § 111.105-37 Flammable anesthetics. Each electric installation where a flammable anesthetic is used or stored must meet NFPA 99 (incorporated by reference, see 46 CFR...

  8. 46 CFR 111.105-37 - Flammable anesthetics.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Flammable anesthetics. 111.105-37 Section 111.105-37...-GENERAL REQUIREMENTS Hazardous Locations § 111.105-37 Flammable anesthetics. Each electric installation where a flammable anesthetic is used or stored must meet NFPA 99 (incorporated by reference, see 46 CFR...

  9. 46 CFR 111.105-37 - Flammable anesthetics.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Flammable anesthetics. 111.105-37 Section 111.105-37...-GENERAL REQUIREMENTS Hazardous Locations § 111.105-37 Flammable anesthetics. Each electric installation where a flammable anesthetic is used or stored must meet NFPA 99 (incorporated by reference, see 46 CFR...

  10. 46 CFR 111.105-37 - Flammable anesthetics.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Flammable anesthetics. 111.105-37 Section 111.105-37...-GENERAL REQUIREMENTS Hazardous Locations § 111.105-37 Flammable anesthetics. Each electric installation where a flammable anesthetic is used or stored must meet NFPA 99 (incorporated by reference, see 46 CFR...

  11. 46 CFR 111.105-37 - Flammable anesthetics.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Flammable anesthetics. 111.105-37 Section 111.105-37...-GENERAL REQUIREMENTS Hazardous Locations § 111.105-37 Flammable anesthetics. Each electric installation where a flammable anesthetic is used or stored must meet NFPA 99 (incorporated by reference, see 46 CFR...

  12. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-05-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During the fourth reporting quarter, laboratory-screening tests of more than 20 potential additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of flyash cohesivity. Resistivity was measured for each screening test with a new multi-cell laboratory flyash resistivity furnace constructed for this project. An initial field trial of three additive formulations was also conducted at the City of Ames, Iowa Municipal Power Plant.

  13. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2003-02-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, two cohesivity-specific additive formulations, ADA-44C and ADA-51, were evaluated in a full-scale trial at the American Electric Power Conesville plant. Ammonia conditioning was also evaluated for comparison. ADA-51 and ammonia conditioning significantly reduced rapping and non-rapped particulate re-entrainment based on stack opacity monitor data. Based on the successful tests to date, ADA-51 will be evaluated in a long-term test.

  14. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-09-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  15. Effect of vessel size and shape on experimental flammability limits of gases.

    PubMed

    Takahashi, Akifumi; Urano, Youkichi; Tokuhashi, Kazuaki; Kondo, Shigeo

    2003-12-12

    The flammability limits of methane and propane have been measured using cylindrical vessels of various sizes and one spherical vessel. An ac discharge ignition method has been employed. For a cylindrical vessel of small diameter with a large height, the flammability limits are primarily determined by the quenching effect of the wall. For cylindrical vessels of smaller heights, the experimental flammability limits are affected by hot gas accumulation at the vessel ceiling, unburned gas heating, self heating of the incipient flame by the reflection both from walls and ceiling, and the quenching effect of the walls. If the vessel size is large enough so that all these effects become negligible, the experimental values of flammability limits may approach to the values that would be obtained in free space. In order to approach this condition for a cylindrical vessel, it is desirable to use a container at least 30 cm in diameter and 60 cm in height. For comparison purpose, the measurement has also been done using ASHRAE type 12l spherical flask.

  16. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    C. Jean Bustard

    2003-12-01

    ADA Environmental Solutions (ADA-ES) has successfully completed a research and development program granted by the Department of Energy National Energy Technology Laboratory (NETL) to develop a family of non-toxic flue gas conditioning agents to provide utilities and industries with a cost-effective means of complying with environmental regulations on particulate emissions and opacity. An extensive laboratory screening of potential additives was completed followed by full-scale trials at four utility power plants. The developed cohesivity additives have been demonstrated on a 175 MW utility boiler that exhibited poor collection of unburned carbon in the electrostatic precipitator. With cohesivity conditioning, opacity spiking caused by rapping reentrainment was reduced and total particulate emissions were reduced by more than 30%. Ammonia conditioning was also successful in reducing reentrainment on the same unit. Conditioned fly ash from the process is expected to be suitable for dry or wet disposal and for concrete admixture.

  17. Evaluation of flammability for cable-like polymers

    NASA Technical Reports Server (NTRS)

    Mikado, Tuneo; Akita, Kazuo

    1988-01-01

    A new test method is developed for the flammability of insulated electric cables as well as polymers formed in the cables. The rate of downward flame spread along the polymer surface is measured by a technique in which the flame is stopped at a particular position by winding up the cable at the same speed as the flame spreading rate, with external preheating by an electric furnace having oxidative gas flow. The polymer burns continuously without change of flame condition and the rate is obtained from the winding speed of the cable. A flame spread equation relates the flame spreading rate (V) of the cable-like polymer to O concentration (Yo) and the atmosphere, the preheating temperature, and the pyrolysis temperature for polymer burning. Plotting log V vs. log Yo for experimental results allows evaluation of the flammability of polymers, with discrimination between the effects of O concentration, heating temperature, and specimen shape. Results with various types of PVC electrical cable indicated the validity of the method. Application of the method to the cables in groups showed a flame retardation behavior different from the case of a single cable, in a atmosphere of high O concentration.

  18. Evaluation of flammability for cable-like polymers

    NASA Technical Reports Server (NTRS)

    Mikado, Tuneo; Akita, Kazuo

    1988-01-01

    A new test method is developed for the flammability of insulated electric cables as well as polymers formed in the cables. The rate of downward flame spread along the polymer surface is measured by a technique in which the flame is stopped at a particular position by winding up the cable at the same speed as the flame spreading rate, with external preheating by an electric furnace having oxidative gas flow. The polymer burns continuously without change of flame condition and the rate is obtained from the winding speed of the cable. A flame spread equation relates the flame spreading rate (V) of the cable-like polymer to O concentration (Yo) and the atmosphere, the preheating temperature, and the pyrolysis temperature for polymer burning. Plotting log V vs. log Yo for experimental results allows evaluation of the flammability of polymers, with discrimination between the effects of O concentration, heating temperature, and specimen shape. Results with various types of PVC electrical cable indicated the validity of the method. Application of the method to the cables in groups showed a flame retardation behavior different from the case of a single cable, in a atmosphere of high O concentration.

  19. Logging slash flammability after five years

    Treesearch

    George R. Fahnestock; John H. Dieterich

    1962-01-01

    This paper reports the final phase of research that has determined the flammability of slash for nine species of northern Rocky Mountain conifers at three ages. Visual characteristics, rate of fire spread, and fire intensity for 5-year-old slash were studied by essentially the same methods as had been used previously on freshly cut and 1-year-old material. Final...

  20. 14 CFR 29.1185 - Flammable fluids.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT AIRWORTHINESS STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Powerplant Fire Protection § 29.1185 Flammable fluids... equal to that which would exist if the tank or reservoir were outside such a zone. (b) Each fuel...

  1. 14 CFR 25.1185 - Flammable fluids.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Powerplant Fire Protection § 25.1185 Flammable fluids. (a..., the design of the system, the materials used in the tank, the shut-off means, and all connections... or reservoir and each firewall or shroud isolating a designated fire zone. (c) Absorbent...

  2. 14 CFR 25.1185 - Flammable fluids.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Powerplant Fire Protection § 25.1185 Flammable fluids. (a..., the design of the system, the materials used in the tank, the shut-off means, and all connections... or reservoir and each firewall or shroud isolating a designated fire zone. (c) Absorbent...

  3. 14 CFR 25.1185 - Flammable fluids.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Powerplant Fire Protection § 25.1185 Flammable fluids. (a..., the design of the system, the materials used in the tank, the shut-off means, and all connections... or reservoir and each firewall or shroud isolating a designated fire zone. (c) Absorbent...

  4. Flammability testing of 22 conventional European pediculicides.

    PubMed

    Dörge, Dorian D; Kuhn, Thomas; Klimpel, Sven

    2017-04-01

    Lice have been parasitizing humans for at least 10,000 years. Since then, humans have tried to rid themselves of these unpleasant and potentially disease-carrying insects. Despite various plant extracts and chemical compounds being used to combat recurring infestations to this date, several lice populations have developed resistance to some of the abundantly used compounds. This resulted in the development of anti-louse products that physically kill the different lice stages. Today, a widely used group of delousing agents are dimethicones (polydimethylsiloxane PDMS) which function by suffocating the lice. However, many dimethicones and related products are highly flammable which makes them potentially dangerous for treatment. In the present study, we tested the flammability of 22 delousing agents in order to shed some light onto this currently unresolved problem in the product design of pediculicides. Thirteen products were easily ignitable, some even by distant contact with a sparkler.

  5. Flammability Configuration Analysis for Spacecraft Applications

    NASA Technical Reports Server (NTRS)

    Pedley, Michael D.

    2014-01-01

    Fire is one of the many potentially catastrophic hazards associated with the operation of crewed spacecraft. A major lesson learned by NASA from the Apollo 204 fire in 1966 was that ignition sources in an electrically powered vehicle should and can be minimized, but can never be eliminated completely. For this reason, spacecraft fire control is based on minimizing potential ignition sources and eliminating materials that can propagate fire. Fire extinguishers are always provided on crewed spacecraft, but are not considered as part of the fire control process. "Eliminating materials that can propagate fire" does not mean eliminating all flammable materials - the cost of designing and building spacecraft using only nonflammable materials is extraordinary and unnecessary. It means controlling the quantity and configuration of such materials to eliminate potential fire propagation paths and thus ensure that any fire would be small, localized, and isolated, and would self-extinguish without harm to the crew. Over the years, NASA has developed many solutions for controlling the configuration of flammable materials (and potentially flammable materials in commercial "off-the-shelf" hardware) so that they can be used safely in air and oxygen-enriched environments in crewed spacecraft. This document describes and explains these design solutions so payload customers and other organizations can use them in designing safe and cost-effective flight hardware. Proper application of these guidelines will produce acceptable flammability configurations for hardware located in any compartment of the International Space Station or other program crewed vehicles and habitats. However, use of these guidelines does not exempt hardware organizations of the responsibility for safety of the hardware under their control.

  6. Flammabilities Of Graphite-Reinforced Composites

    NASA Technical Reports Server (NTRS)

    Kourtides, Demetrius A.

    1990-01-01

    Report describes tests and comparisons of flammabilities, thermal properties, and selected mechanical properties of composite materials made of epoxy and other matrices reinforced by graphite fibers. Composites also compared with baseline epoxy/fiberglass composite. Considers such properties as limiting oxygen index, smoke evolution, products of thermal degradation, total heat release, heat-release rate, loss of mass, spread of flames, resistance to ignition, and thermal stability.

  7. 46 CFR 30.10-22 - Flammable liquid-TB/ALL.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Flammable liquid-TB/ALL. 30.10-22 Section 30.10-22...-22 Flammable liquid—TB/ALL. The term flammable liquid means any liquid which gives off flammable... below a temperature of 80 °F. Flammable liquids are referred to by grades as follows: (a) Grade A....

  8. 46 CFR 30.10-22 - Flammable liquid-TB/ALL.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 1 2014-10-01 2014-10-01 false Flammable liquid-TB/ALL. 30.10-22 Section 30.10-22...-22 Flammable liquid—TB/ALL. The term flammable liquid means any liquid which gives off flammable... below a temperature of 80 °F. Flammable liquids are referred to by grades as follows: (a) Grade A....

  9. 46 CFR 30.10-22 - Flammable liquid-TB/ALL.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 1 2013-10-01 2013-10-01 false Flammable liquid-TB/ALL. 30.10-22 Section 30.10-22...-22 Flammable liquid—TB/ALL. The term flammable liquid means any liquid which gives off flammable... below a temperature of 80 °F. Flammable liquids are referred to by grades as follows: (a) Grade A....

  10. 46 CFR 30.10-22 - Flammable liquid-TB/ALL.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 1 2012-10-01 2012-10-01 false Flammable liquid-TB/ALL. 30.10-22 Section 30.10-22...-22 Flammable liquid—TB/ALL. The term flammable liquid means any liquid which gives off flammable... below a temperature of 80 °F. Flammable liquids are referred to by grades as follows: (a) Grade A....

  11. 46 CFR 30.10-22 - Flammable liquid-TB/ALL.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 1 2011-10-01 2011-10-01 false Flammable liquid-TB/ALL. 30.10-22 Section 30.10-22...-22 Flammable liquid—TB/ALL. The term flammable liquid means any liquid which gives off flammable... below a temperature of 80 °F. Flammable liquids are referred to by grades as follows: (a) Grade A....

  12. Flammability test for sunglasses: developing a system

    NASA Astrophysics Data System (ADS)

    Magri, Renan; Ventura, Liliane

    2014-02-01

    Recent investigations show the need for certificating sunglasses to ensure the safety and health to population. The Brazilian Standard ABNT NBR 15111 regulates features to sunglasses, however, there is not a sunglasses certification office in Brazil, therefore, our lab has been developing several equipment for sunglasses testing. This work refers to one of them: the flammability test system for sunglasses in compliance with the NBR 15111. The standard provides requirements for the flammability test procedure which requires that the equipment must operate at a temperature of 650 °C +/- 20 °C the end of a steel rod of 300 mm length and 6 mm diameter should be heated and pressed over the surface of the lenses for five seconds; the flammability is checked by visual inspection. The furnace is made of ceramic. We used a power electronic circuit to control the power in the furnace using ON/OFF mode and for measuring the temperature, we used a K-type thermocouple. A stepper motor with pulley lifts the steel rod. The system reaches the working temperature in 15 minutes for a step input of 61 V in open loop system. The electronics control are under development in order to shorten the time necessary to reach the working temperature and maintain the temperature variation in the furnace within the limits imposed by the standard as next steps.

  13. Support of gas flowmeter upgrade

    NASA Technical Reports Server (NTRS)

    Waugaman, Dennis

    1996-01-01

    A project history review, literature review, and vendor search were conducted to identify a flowmeter that would improve the accuracy of gaseous flow measurements in the White Sands Test Facility (WSTF) Calibration Laboratory and the Hydrogen High Flow Facility. Both facilities currently use sonic flow nozzles to measure flowrates. The flow nozzle pressure drops combined with corresponding pressure and temperature measurements have been estimated to produce uncertainties in flowrate measurements of 2 to 5 percent. This study investigated the state of flowmeter technology to make recommendations that would reduce those uncertainties. Most flowmeters measure velocity and volume, therefore mass flow measurement must be calculated based on additional pressures and temperature measurement which contribute to the error. The two exceptions are thermal dispersion meters and Coriolis mass flowmeters. The thermal dispersion meters are accurate to 1 to 5 percent. The Coriolis meters are significantly more accurate, at least for liquids. For gases, there is evidence they may be accurate to within 0.5 percent or better of the flowrate, but there may be limitations due to inappropriate velocity, pressure, Mach number and vibration disturbances. In this report, a comparison of flowmeters is presented. Candidate Coriolis meters and a methodology to qualify the meter with tests both at WSTF and Southwest Research Institute are recommended and outlined.

  14. Flammability limits of olefinic and saturated fluoro-compounds.

    PubMed

    Kondo, Shigeo; Takizawa, Kenji; Takahashi, Akifumi; Tokuhashi, Kazuaki; Mizukado, Junji; Sekiya, Akira

    2009-11-15

    Flammability limits were measured for a number of olefinic and saturated fluoro-compounds in a 12l spherical glass vessel. The obtained data together with the ones of previous studies have been analyzed based on the F-number scheme of flammability limits. The flammability limits of these compounds have been found to be explained very well by the present scheme of interpretation. The flammability limits are dependent upon distribution of F atoms in a molecule as well as upon F-substitution rate itself. It has been found that -O-CF(3) group in a molecule conspicuously decreases the flammability of the compound, while -C-CF(3) group does not much. For olefinic compounds, distribution of F atoms around double bonds markedly diminishes the flammability of the molecule.

  15. Report on the handling of safety information concerning flammable gases and ferrocyanide at the Hanford waste tanks

    SciTech Connect

    Not Available

    1990-07-01

    This report discusses concerns safety issues, and management at Hanford Tank Farm. Concerns center on the issue of flammable gas generation which could ignite, and on possible exothermic reactions of ferrocyanide compounds which were added to single shell tanks in the 1950's. It is believed that information concerning these issues has been mis-handled and the problems poorly managed. (CBS)

  16. Estimation of Flammability Limits of Selected Fluorocarbons with F(sub 2) and CIF(sub3)

    SciTech Connect

    Trowbridge, L.D.

    1999-09-01

    During gaseous diffusion plant operations, conditions leading to the formation of flammable gas mixtures may occasionally arise. Currently, these could consist of the evaporative coolant CFC-114 and fluorinating agents such as F(sub 2) and CIF(sub 3). Replacement of CFC-114 with non-ozone-depleting substitutes such as c-C(sub 4)F(sub 8) and C(sub 4)F(sub 10) is planned. Consequently, in the future, these too must be considered potential ''fuels'' in flammable gas mixtures. Two questions of practical interest arise: (1) can a particular mixture sustain and propagate a flame if ignited, and (2) what is the maximum pressure that can be generated by the burning (and possibly exploding) gas mixture, should ignite? Experimental data on these systems are limited. To assist in answering these questions, a literature search for relevant data was conducted, and mathematical models were developed to serve as tools for predicting potential detonation pressures and estimating (based on empirical correlations between gas mixture thermodynamics and flammability for known systems) the composition limits of flammability for these systems. The models described and documented in this report are enhanced versions of similar models developed in 1992.

  17. TECHNICAL JUSTIFICATION FOR CHOOSING PROPANE AS A CALIBRATION AGENT FOR TOTAL FLAMMABLE VOLATILE ORGANIC COMPOUND (VOC) DETERMINATIONS

    SciTech Connect

    DOUGLAS, J.G.

    2006-07-06

    This document presents the technical justification for choosing and using propane as a calibration standard for estimating total flammable volatile organic compounds (VOCs) in an air matrix. A propane-in-nitrogen standard was selected based on a number of criteria: (1) has an analytical response similar to the VOCs of interest, (2) can be made with known accuracy and traceability, (3) is available with good purity, (4) has a matrix similar to the sample matrix, (5) is stable during storage and use, (6) is relatively non-hazardous, and (7) is a recognized standard for similar analytical applications. The Waste Retrieval Project (WRP) desires a fast, reliable, and inexpensive method for screening the flammable VOC content in the vapor-phase headspace of waste containers. Table 1 lists the flammable VOCs of interest to the WRP. The current method used to determine the VOC content of a container is to sample the container's headspace and submit the sample for gas chromatography--mass spectrometry (GC-MS) analysis. The driver for the VOC measurement requirement is safety: potentially flammable atmospheres in the waste containers must be allowed to diffuse prior to processing the container. The proposed flammable VOC screening method is to inject an aliquot of the headspace sample into an argon-doped pulsed-discharge helium ionization detector (Ar-PDHID) contained within a gas chromatograph. No actual chromatography is performed; the sample is transferred directly from a sample loop to the detector through a short, inert transfer line. The peak area resulting from the injected sample is proportional to the flammable VOC content of the sample. However, because the Ar-PDHID has different response factors for different flammable VOCs, a fundamental assumption must be made that the agent used to calibrate the detector is representative of the flammable VOCs of interest that may be in the headspace samples. At worst, we desire that calibration with the selected calibrating

  18. Energy Efficiency Upgrades

    SciTech Connect

    Roby Williams

    2012-03-29

    The energy efficiency upgrades project at Hardin County General Hospital did not include research nor was it a demonstration project. The project enabled the hospital to replace outdated systems with modern efficient models. Hardin County General Hospital is a 501c3, nonprofit hospital and the sole community provider for Hardin and Pope Counties of Illinois. This project provided much needed equipment and facility upgrades that would not have been possible through locally generated funding. Task 1 was a reroofing of the hospital. The hospital architect designed the replacement to increase the energy efficiency of the hospital roof/ceiling structure. Task 2 was replacement and installation of a new more efficient CT scanner for the hospital. Included in the project was replacement of HVAC equipment for the entire radiological suite. Task 5 was a replacement and installation of a new higher capacity diesel-fueled emergency generator for the hospital replacing a 50+ year old gas-fired generator. Task 7 was the replacement of 50+ year-old walk-in cooler/freezer with a newer, energy efficient model. Task 8 was the replacement of 10+ year-old washing machines in the hospital laundry with higher capacity, energy efficient models. Task 9 was replacement of 50-year old single pane curtain window system with double-pane insulated windows. Additionally, insulation was added around ventilation systems and the curtain wall system.

  19. 49 CFR 172.546 - FLAMMABLE SOLID placard.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.546 FLAMMABLE SOLID placard. (a) Except for size and color, the...

  20. 49 CFR 172.546 - FLAMMABLE SOLID placard.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.546 FLAMMABLE SOLID placard. (a) Except for size and color, the...

  1. 49 CFR 172.546 - FLAMMABLE SOLID placard.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.546 FLAMMABLE SOLID placard. (a) Except for size and color, the...

  2. 49 CFR 172.546 - FLAMMABLE SOLID placard.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS HAZARDOUS MATERIALS TABLE, SPECIAL... SECURITY PLANS Placarding § 172.546 FLAMMABLE SOLID placard. (a) Except for size and color, the...

  3. Laminar lean premixed methane/air combustion near the lean flammability limit using nanosecond repetitive pulsed discharge plasmas

    NASA Astrophysics Data System (ADS)

    Bak, Moon Soo; Do, Hyungrok; Mungal, Mark G.; Cappelli, Mark A.

    2011-10-01

    Gas chromatographic and temperature measurements have been carried out to investigate the extent of premixed methane/air combustion with the application of nanosecond repetitive pulsed discharges around the lean flammability limit for laminar flows. The results show that the discharges lead to the complete combustion when the equivalence ratio is above 0.54, but when the ratio is below the limit, the combustion is quenched at the downstream flow. To investigate the kinetics in detail, 2-D simulations of plasma-induced combustion have been conducted for methane/air mixtures at below and above the lean flammability limit. The simulations reveal that methane is mostly combusted in the discharge region since the discharge repetition timescale is much shorter than the species diffusion and advection timescales, and so the discharge serves more as a heat and radical source rather than a small combustor, to flame hold near the lean flammability limit.

  4. 16 CFR Figure 1 to Part 1610 - Sketch of Flammability Apparatus

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Sketch of Flammability Apparatus 1 Figure 1 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT... Flammability Apparatus ER25MR08.000...

  5. 16 CFR Figure 1 to Part 1610 - Sketch of Flammability Apparatus

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 16 Commercial Practices 2 2011-01-01 2011-01-01 false Sketch of Flammability Apparatus 1 Figure 1 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT... Flammability Apparatus ER25MR08.000...

  6. Gas characterization system software acceptance test report

    SciTech Connect

    Vo, C.V.

    1996-03-28

    This document details the results of software acceptance testing of gas characterization systems. The gas characterization systems will be used to monitor the vapor spaces of waste tanks known to contain measurable concentrations of flammable gases.

  7. TWRS hydrogen mitigation gas characterization system design and fabrication engineering task plan

    SciTech Connect

    Straalsund, E.K.

    1995-01-01

    The flammable gas watch-list (FGWL) tanks, which have demonstrated a gas release event (GRE) exceeding 0.625% hydrogen by volume will require additional characterization. The purpose of this additional characterization is to accurately measure the flammable and hazardous gas compositions and resulting lower flammability limit (LFL) of the tank vapor space during baseline and GRE emissions. Data from this characterization will help determine methods to resolve the unreviewed safety questions for the FGWL tanks. This document details organization responsibilities and engineering requirements for the design and fabrication of two gas characterization systems used to monitor flammable gas watch-list tanks.

  8. Flammability characteristics of aircraft interior composites

    NASA Technical Reports Server (NTRS)

    Kourtides, D. A.; Parker, J. A.; Gilwee, W. J., Jr.; Lerner, N. R.; Hilado, C. J.; Labossiere, L. A.; Hsu, M.-T. S.

    1976-01-01

    The thermochemical and flammability characteristics of two polymeric composites currently in use and seven others being considered for use as aircraft interior panels are described. The properties studied included: (1) oxygen index of the composite constituents; (2) fire containment capability of the composite; (3) smoke evolution from the composite; (4) thermogravimetric analysis; (5) composition of the volatile products of pyrolysis. The performance of foam filled honeycomb laminated panels consisting of high-temperature laminating bismaleimide resins is compared with the performance of empty honeycomb laminated panels consisting of laminating epoxy or phenolic resins at similar densities. Processing parameters of one of the bismaleimide composites is detailed.

  9. Aircraft seat cushion materials tests. [flammability

    NASA Technical Reports Server (NTRS)

    Bricker, R. W.

    1975-01-01

    Five component level flammability tests were conducted in a 400 cubic foot chamber to determine the products of combustion and relative destruction of coated (with fire-retardants) and uncoated polyurethane foams during exposure of the foams to a large flaming ignition source for five minutes. The test results indicate that the improved state-of-the-art polyurethane foams without the added fire retardant and coating treatments were not significantly better than untreated older less fire-resistant polyurethane foams. however, by treating and coating the state-of-the-art foams, the production of toxic gases was delayed and the destruction of the foam limited.

  10. Laboratory flammability studies of mixtures of hydrogen, nitrous oxide, and air

    SciTech Connect

    Cashdollar, K L; Hertzberg, M; Zlochower, I A; Lucci, C E; Green, G M; Thomas, R A

    1992-06-26

    At the request of the Department of Energy and the Westinghouse Hanford Company, the Bureau of Mines has investigated the flammability of mixtures of hydrogen, nitrous oxide, and air. This work is relevant to the possible hazards of flammable gas generation from nuclear waste tanks at Hanford, WA. The tests were performed in a 120-L spherical chamber under both quiescent and turbulent conditions using both electric spark and pyrotechnic ignition sources. The data reported here for binary mixtures of hydrogen in air generally confirm the data of previous investigators, but they are more comprehensive than those reported previously. The results clarify to a greater extent the complications associated with buoyancy, turbulence, and selective diffusion. The data reported here for ternary mixtures of hydrogen and nitrous oxide in air indicate that small additions of nitrous oxide (relative to the amount of air) have little effect, but that higher concentrations of nitrous oxide (relative to air) significantly increase the explosion hazard.

  11. 46 CFR 109.557 - Flammable and combustible liquids: Carriage.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Flammable and combustible liquids: Carriage. 109.557 Section 109.557 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.557 Flammable and combustible liquids: Carriage. The master...

  12. 16 CFR 423.9 - Conflict with flammability standards.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 16 Commercial Practices 1 2011-01-01 2011-01-01 false Conflict with flammability standards. 423.9 Section 423.9 Commercial Practices FEDERAL TRADE COMMISSION TRADE REGULATION RULES CARE LABELING OF TEXTILE WEARING APPAREL AND CERTAIN PIECE GOODS AS AMENDED § 423.9 Conflict with flammability...

  13. 16 CFR 423.9 - Conflict with flammability standards.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 16 Commercial Practices 1 2010-01-01 2010-01-01 false Conflict with flammability standards. 423.9 Section 423.9 Commercial Practices FEDERAL TRADE COMMISSION TRADE REGULATION RULES CARE LABELING OF TEXTILE WEARING APPAREL AND CERTAIN PIECE GOODS AS AMENDED § 423.9 Conflict with flammability...

  14. 46 CFR 188.10-27 - Flammable liquid.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 7 2014-10-01 2014-10-01 false Flammable liquid. 188.10-27 Section 188.10-27 Shipping... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-27 Flammable liquid. This term includes any liquid whose flashpoint, as determined by an open cup tester, is 80 °F. or below....

  15. 46 CFR 188.10-27 - Flammable liquid.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Flammable liquid. 188.10-27 Section 188.10-27 Shipping... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-27 Flammable liquid. This term includes any liquid whose flashpoint, as determined by an open cup tester, is 80 °F. or below....

  16. 46 CFR 188.10-27 - Flammable liquid.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 7 2012-10-01 2012-10-01 false Flammable liquid. 188.10-27 Section 188.10-27 Shipping... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-27 Flammable liquid. This term includes any liquid whose flashpoint, as determined by an open cup tester, is 80 °F. or below....

  17. 46 CFR 188.10-27 - Flammable liquid.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 7 2013-10-01 2013-10-01 false Flammable liquid. 188.10-27 Section 188.10-27 Shipping... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-27 Flammable liquid. This term includes any liquid whose flashpoint, as determined by an open cup tester, is 80 °F. or below....

  18. 46 CFR 188.10-27 - Flammable liquid.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 7 2011-10-01 2011-10-01 false Flammable liquid. 188.10-27 Section 188.10-27 Shipping... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-27 Flammable liquid. This term includes any liquid whose flashpoint, as determined by an open cup tester, is 80 °F. or below....

  19. 43 CFR 423.31 - Fires and flammable material.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 1 2011-10-01 2011-10-01 false Fires and flammable material. 423.31... of Conduct § 423.31 Fires and flammable material. (a) You must not leave a fire unattended, and it... designed for that purpose. (e) You must comply with all applicable Federal, State, and local fire...

  20. 14 CFR 25.1183 - Flammable fluid-carrying components.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... section, each line, fitting, and other component carrying flammable fluid in any area subject to engine... safeguard against the ignition of leaking flammable fluid. An integral oil sump of less than 25-quart...) Paragraph (a) of this section does not apply to— (1) Lines, fittings, and components which are...

  1. 14 CFR 25.1183 - Flammable fluid-carrying components.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... section, each line, fitting, and other component carrying flammable fluid in any area subject to engine... safeguard against the ignition of leaking flammable fluid. An integral oil sump of less than 25-quart...) Paragraph (a) of this section does not apply to— (1) Lines, fittings, and components which are...

  2. 14 CFR 25.1183 - Flammable fluid-carrying components.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... section, each line, fitting, and other component carrying flammable fluid in any area subject to engine... safeguard against the ignition of leaking flammable fluid. An integral oil sump of less than 25-quart...) Paragraph (a) of this section does not apply to— (1) Lines, fittings, and components which are...

  3. 14 CFR 25.1183 - Flammable fluid-carrying components.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... section, each line, fitting, and other component carrying flammable fluid in any area subject to engine... safeguard against the ignition of leaking flammable fluid. An integral oil sump of less than 25-quart...) Paragraph (a) of this section does not apply to— (1) Lines, fittings, and components which are...

  4. Flammability tests for regulation of building and construction materials

    Treesearch

    K. Sumathipala

    2006-01-01

    The regulation of building materials and products for flammability is critical to ensure the safety of occupants in buildings and other structures. The involvement of exposed building materials and products in fires resulting in the loss of human life often spurs an increase in regulation and new test methods to address the problem. Flammability tests range from those...

  5. Flammability of litter from southeastern trees: a preliminary assessment

    Treesearch

    J. Morgan Varner; Jeffrey M. Kane; Erin M. Banwell; Jesse K. Kreye

    2015-01-01

    The southeastern United States possesses a great diversity of woody species and an equally impressive history of wildland fires. Species are known to vary in their flammability, but little is known about southeastern species. We used published data and our own collections to perform standard litter flammability tests on a diverse suite of 25 native overstory trees from...

  6. Measurement and numerical analysis of flammability limits of halogenated hydrocarbons.

    PubMed

    Kondo, Shigeo; Takizawa, Kenji; Takahashi, Akifumi; Tokuhashi, Kazuaki

    2004-06-18

    Flammability limits measurement was made for a number of halogenated compounds by the ASHRAE method. Most of compounds measured are the ones for which discrepancy was noted between the literature values and predicted values of flammability limits. As a result, it has been found that most of the newly obtained values of flammability limits are not in accordance with the literature values. Numerical analysis was carried out for a set of flammability limits data including the newly obtained ones using a modified analytical method based on F-number scheme. In this method, fitting procedure was done directly to flammability limits themselves instead of fitting to F-number. After the fitting process, the average relative deviation between the observed and calculated values is 9.3% for the lower limits and 14.6% for the upper limits.

  7. Flammability limits of dusts: Minimum inerting concentrations

    SciTech Connect

    Dastidar, A.G.; Amyotte, P.R.; Going, J.; Chatrathi, K.

    1999-05-01

    A new flammability limit parameter has been defined as the Minimum Inerting Concentration (MIC). This is the concentration of inertant required to prevent a dust explosion regardless of fuel concentration. Previous experimental work at Fike in a 1-m{sup 3} spherical chamber has shown this flammability limit to exist for pulverized coal dust and cornstarch. In the current work, inerting experiments with aluminum, anthraquinone and polyethylene dusts as fuels were performed, using monoammonium phosphate and sodium bicarbonate as inertants. The results show that an MIC exists only for anthraquinone inerted with sodium bicarbonate. The other combustible dust and inertant mixtures did not show a definitive MIC, although they did show a strong dependence between inerting level and suspended fuel concentration. As the fuel concentration increased, the amount of inertant required to prevent an explosion decreased. Even though a definitive MIC was not found for most of the dusts an effective MIC can be estimated from the data. The use of MIC data can aid in the design of explosion suppression schemes.

  8. TLRS-3 system upgrades

    NASA Technical Reports Server (NTRS)

    Eichinger, Richard; Cheng, Grace; Crawford, William; Cresswell, Don; Crooks, Henry A.; Donovan, Howard; Edge, David R.; Emenheiser, Kenneth S.; Hanrahan, William P., III; Heinick, J. Michael

    1993-01-01

    This presentation describes the upgrades to the Transportable Laser Ranging Systems serial number three (TLRS-3), and the impact that these upgrades will have on the TLRS-3 performance in the field. The four major areas of system upgrades are the HP-380 computer, the Optical Attenuation Mechanism (OAM), the upgraded spatial, spectral and temporal filtering for improved daylight ranging capability, and the software upgrade to enable the system to track the Etalon satellites. The TLRS-3 was returned to the Goddard Geophysical and Astronomical Observatory (GGAO) in December 1991 for system upgrades in preparation of the TOPEX/POSEIDON campaign scheduled to begin in the summer of 1992. Many system upgrades were incorporated into the system while interleaving planned facility maintenance making TLRS-3 a more versatile and more dependable laser ranging system. The TLRS-3 was initially baselined with the MOBLAS-7 via simultaneous satellite ranging on the LAGEOS, Ajisai, Starlette, and ERS-I satellites. During the upgrades and following completion of the system upgrades intercomparisons with the MOBLAS-7 were made to verify the integrity and accuracy of the system changes. Several other groups of personnel participated in the TLRS-3 upgrade and they are: the Survey Section, the Precision Measurement Equipment Laboratory, the Architectural and Engineering Services Department, the Precision Timing Section, and the station personnel at TLRS-3 and MOBLAS-7.

  9. One-pot, bioinspired coatings to reduce the flammability of flexible polyurethane foams.

    PubMed

    Davis, Rick; Li, Yu-Chin; Gervasio, Michelle; Luu, Jason; Kim, Yeon Seok

    2015-03-25

    In this manuscript, natural materials were combined into a single "pot" to produce flexible, highly fire resistant, and bioinspired coatings on flexible polyurethane foam (PUF). In one step, PUF was coated with a fire protective layer constructed of a polysaccharide binder (starch or agar), a boron fire retardant (boric acid or derivative), and a dirt char former (montmorillonite clay). Nearly all coatings produced a 63% reduction in a critical flammability value, the peak heat release rate (PHRR). One formulation produced a 75% reduction in PHRR. This technology was validated in full-scale furniture fire tests, where a 75% reduction in PHRR was measured. At these PHRR values, this technology could reduce the fire threat of furniture from significant fire damage in and beyond the room of fire origin to being contained to the burning furniture. This flammability reduction was caused by three mechanisms-the gas-phase and condensed-phase processes of the boron fire retardant and the condensed-phase process of the clay. We describe the one-pot coating process and the impact of the coating composition on flammability.

  10. 14 CFR Appendix M to Part 25 - Fuel Tank System Flammability Reduction Means

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... inoperative and the tank is flammable. (b) The Fleet Average Flammability Exposure, as defined in Appendix N.... (a) The Fleet Average Flammability Exposure of each fuel tank, as determined in accordance with... defined in Appendix N of this part. As a portion of this 3 percent, if flammability reduction means (FRM...

  11. Spacecraft and Navy Materials Flammability: Review of Some Concepts and Test Methods

    NASA Technical Reports Server (NTRS)

    Hirsch, David

    2004-01-01

    The agenda covered by this viewgraph presentation includes: 1) Concepts of Spacecraft Fire Safety; 2) Spacecraft materials flammability test methods; 3) Evaluation of flight hardware flammability; 4) Review of flammability data in conditions of interest to the Navy; 5) Overview of some flammability test methods recommended for the Navy.

  12. 46 CFR 194.05-9 - Flammable liquid chemical stores-Detail requirements.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 7 2011-10-01 2011-10-01 false Flammable liquid chemical stores-Detail requirements... and Marking § 194.05-9 Flammable liquid chemical stores—Detail requirements. (a) Flammable liquids as chemical stores and reagents are governed by subparts 194.15 and 194.20. (b) Other flammable liquids...

  13. 46 CFR 194.05-9 - Flammable liquid chemical stores-Detail requirements.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 7 2013-10-01 2013-10-01 false Flammable liquid chemical stores-Detail requirements... and Marking § 194.05-9 Flammable liquid chemical stores—Detail requirements. (a) Flammable liquids as chemical stores and reagents are governed by subparts 194.15 and 194.20. (b) Other flammable liquids...

  14. 46 CFR 194.05-9 - Flammable liquid chemical stores-Detail requirements.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Flammable liquid chemical stores-Detail requirements... and Marking § 194.05-9 Flammable liquid chemical stores—Detail requirements. (a) Flammable liquids as chemical stores and reagents are governed by subparts 194.15 and 194.20. (b) Other flammable liquids...

  15. 46 CFR 194.05-9 - Flammable liquid chemical stores-Detail requirements.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 7 2012-10-01 2012-10-01 false Flammable liquid chemical stores-Detail requirements... and Marking § 194.05-9 Flammable liquid chemical stores—Detail requirements. (a) Flammable liquids as chemical stores and reagents are governed by subparts 194.15 and 194.20. (b) Other flammable liquids...

  16. 46 CFR 194.05-9 - Flammable liquid chemical stores-Detail requirements.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 7 2014-10-01 2014-10-01 false Flammable liquid chemical stores-Detail requirements... and Marking § 194.05-9 Flammable liquid chemical stores—Detail requirements. (a) Flammable liquids as chemical stores and reagents are governed by subparts 194.15 and 194.20. (b) Other flammable liquids...

  17. Flammability measurements of difluoromethane in air at 100 C

    SciTech Connect

    Grosshandler, W.L.; Donnelly, M.K.; Womeldorf, C.

    1999-07-01

    Difluoromethane (CH{sub 2}F{sub 2}, or R-32) is a candidate to replace currently used ozone-depleting chlorofluorocarbon refrigerants. Because CH{sub 2}F{sub 2} is flammable, it is necessary to assess the hazard posed by a leak in a refrigeration machine. The currently accepted method for determining flammability, ASTM E 681, has difficulty discerning the flammability boundary for weak fuels such as CH{sub 2}F{sub 2}. This paper describes an alternative approach to identify the limits of flammability, using a twin, premixed counter-flow flame. By using the extinction of an already established flame, the point dividing flammable from non-flammable becomes unambiguous. The limiting extinction mixture changes with stretch rate, so it is convenient to report the flammability limit as the value extrapolated to a zero stretch condition. In the burner, contoured nozzles with outlet diameters of 12 mm are aligned counter to each other and spaced 12 mm apart. The lean flammability limit of CH{sub 2}F{sub 2} in dry air at room temperature was previously reported by the authors to be a mole fraction of 0.14, using the twin counter-flow flame method. In the current study, relative humidity was not found to affect the lean limit. Increasing the temperature of the premixed fuel and air to 100 C is shown to extend the flammability limit in the lean direction to 0.13. The rich limit of CH{sub 2}F{sub 2} found using the counter-flow method is around 0.27. The uncertainties of the measurements are presented and the results compared to data in the literature.

  18. Pressure Flammability Thresholds of Selected Aerospace Materials

    NASA Technical Reports Server (NTRS)

    Hirsch, David B.; Williams, James H.; Harper, Susana A.; Beeson, Harold D.; Ruff, Gary A.; Pedley, Michael D.

    2010-01-01

    A test program was performed to determine the highest pressure in oxygen where materials used in the planned NASA Constellation Program Orion Crew Exploration Vehicle (CEV) Crew Module (CM) would not propagate a flame if an ignition source was present. The test methodology used was similar to that previously used to determine the maximum oxygen concentration (MOC) at which self-extinguishment occurs under constant total pressure conditions. An upward limiting pressure index (ULPI) was determined, where approximately 50 percent of the materials self-extinguish in a given environment. Following this, the maximum total pressure (MTP) was identified; where all samples tested (at least five) self-extinguished following the NASA-STD-6001.A Test 1 burn length criteria. The results obtained on seven materials indicate that the non-metallic materials become flammable in oxygen between 0.4 and 0.9 psia.

  19. Upward Flammability Testing: A Probabilistic Measurement

    NASA Technical Reports Server (NTRS)

    Davis, Samuel E.; Engel, Carl D.; Richardson, Erin R.

    2003-01-01

    Examination of NASA-STD-6001 Test 1 data suggests burn length outcome for a given environment has a large statistical variation from run to run. Large data sets show that burn length data form cumulative probability distribution curves, which describe a material's characteristic to burn in a specific environment, suggesting that the current practice of testing three samples at specific conditions is inadequate. Sufficient testing can establish material characteristics probability curves to provide the probability that a material will sustain a burn length of at least 15.24 cm (6.0 in.) or will sustain burning until all material is consumed. A simple pasdfail criterion may not be possible or practical. Future application of flammability data for some material classes may require the engineer to assess risk based on the probability of an occurrence and the probable outcome with different materials as characterized with cumulative burn length distributions for specific use conditions.

  20. Upward Flammability Testing: A Probabilistic Measurement

    NASA Technical Reports Server (NTRS)

    Davis, Samuel E.; Engel, Carl D.; Richardson, Erin R.

    2003-01-01

    Examination of NASA-STD-6001 Test 1 data suggests burn length outcome for a given environment has a large statistical variation from run to run. Large data sets show that burn length data form cumulative probability distribution curves, which describe a material's characteristic to burn in a specific environment, suggesting that the current practice of testing three samples at specific conditions is inadequate. Sufficient testing can establish material characteristics probability curves to provide the probability that a material will sustain a burn length of at least 15.24 cm (6.0 in.) or will sustain burning until all material is consumed. A simple pasdfail criterion may not be possible or practical. Future application of flammability data for some material classes may require the engineer to assess risk based on the probability of an occurrence and the probable outcome with different materials as characterized with cumulative burn length distributions for specific use conditions.

  1. The D0 Upgrade

    SciTech Connect

    Abachi, S.; D0 Collaboration

    1995-07-01

    In this paper we describe the approved DO Upgrade detector, and its physics capabilities. The DO Upgrade is under construction and will run during the next Fermilab collider running period in early 1999 (Run II). The upgrade is designed to work at the higher luminosities and shorter bunch spacings expected during this run. The major elements of t he upgrade are: a new tracking system with a silicon tracker, scintillating fiber tracker, a 2T solenoid, and a central preshower detector; new calorimeter electronics; new muon trigger and tracking detectors with new muon system electronics; a forward preshower detector; new trigger electronics and DAQ improvements to handle the higher rates.

  2. EPIC Computer Upgrade

    NASA Image and Video Library

    Expedition 30 Commander Dan Burbank and Flight Engineer Don Pettit work on installing hardware for the Enhanced Processor and Integrated Communications (EPIC) upgrade of the International Space Sta...

  3. Low flammability cap-sensitive flexible explosive composition

    DOEpatents

    Wagner, Martin G.

    1992-01-14

    A cap-sensitive flexible explosive composition of reduced flammability is provided by incorporating a finely divided, cap-sensitive explosive in a flame resistant polymeric binder system which contains a compatible flame retardant material.

  4. DOE/DOE Tight Oil Flammability & Transportation Spill Safety

    SciTech Connect

    Lord, David L.

    2014-12-01

    This presentation describes crude oils, their phase behavior, the SPR vapor pressure program, and presents data comparisons from various analytical techniques. The overall objective is to describe physical properties of crude oil relevant to flammability and transport safety

  5. Pressure Flammability Thresholds in Oxygen of Selected Aerospace Materials

    NASA Technical Reports Server (NTRS)

    Hirsch, David; Williams, Jim; Harper, Susana; Beeson, Harold; Ruff, Gary; Pedley, Mike

    2010-01-01

    The experimental approach consisted of concentrating the testing in the flammability transition zone following the Bruceton Up-and-Down Method. For attribute data, the method has been shown to be very repeatable and most efficient. Other methods for characterization of critical levels (Karberand Probit) were also considered. The data yielded the upward limiting pressure index (ULPI), the pressure level where approx.50% of materials self-extinguish in a given environment.Parametric flammability thresholds other than oxygen concentration can be determined with the methodology proposed for evaluating the MOC when extinguishment occurs. In this case, a pressure threshold in 99.8% oxygen was determined with the methodology and found to be 0.4 to 0.9 psia for typical spacecraft materials. Correlation of flammability thresholds obtained with chemical, hot wire, and other ignition sources will be conducted to provide recommendations for using alternate ignition sources to evaluate flammability of aerospace materials.

  6. Flammability limits of isobutane and its mixtures with various gases.

    PubMed

    Kondo, Shigeo; Takizawa, Kenji; Takahashi, Akifumi; Tokuhashi, Kazuaki; Sekiya, Akira

    2007-09-30

    Flammability limits of isobutane and five kinds of binary mixtures of isobutane were measured by the ASHRAE method. Propane, nitrogen, carbon dioxide, chloroform, and HFC-125 (1,1,1,2,2-pentafluoroethane) were used as the counter part gases in the mixtures. The observed data were analyzed using the equations based on Le Chatelier's formula. The flammability limits of mixtures with propane were well explained by the original Le Chatelier's formula. The flammability limits of mixtures with nitrogen and the ones with carbon dioxide were adequately analyzed by the extended Le Chatelier's formula. It was found that the extended Le Chatelier's formula is also applicable to the flammability limits of mixtures with chloroform and HFC-125.

  7. Chemical Safety Alert: Lightning Hazard to Facilities Handling Flammable Substances

    EPA Pesticide Factsheets

    Raises awareness about lightning strikes, which cause more death/injury and damage than all other environmental elements combined, so industry can take proper precautions to protect equipment and storage or process vessels containing flammable materials.

  8. 28. VIEW OF FLAMMABLE TEST ROOM, LOCATED IN THE NORTHEAST ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    28. VIEW OF FLAMMABLE TEST ROOM, LOCATED IN THE NORTHEAST CORNER OF SHIPPING AND STORAGE ROOM, 1923 ADDITION, FIRST FLOOR - Underwriters' Laboratories, 207-231 East Ohio Street, Chicago, Cook County, IL

  9. Magnetic switching, final chapter, Book I: the ATA upgrade prototype

    SciTech Connect

    Birx, D.; Cook, E.; Hawkins, S.; Poor, S.; Reginato, L.; Schmidt, J.; Smith, M.W.

    1983-03-22

    Efforts directed at finding a 10 kHz switch to replace the current 1 kHz gas blown spark gap have culminated in a prototype for an upgrade of ATA. The design and performance of this prototype as well as possible options and recommendations concerning an eventual upgrade are described. 4 references, 9 figures.

  10. Hydrocarbonaceous material upgrading method

    DOEpatents

    Brecher, Lee E.; Mones, Charles G.; Guffey, Frank D.

    2015-06-02

    A hydrocarbonaceous material upgrading method may involve a novel combination of heating, vaporizing and chemically reacting hydrocarbonaceous feedstock that is substantially unpumpable at pipeline conditions, and condensation of vapors yielded thereby, in order to upgrade that feedstock to a hydrocarbonaceous material condensate that meets crude oil pipeline specification.

  11. Effect of a zero g environment on flammability limits as determined using a standard flammability tube apparatus

    NASA Technical Reports Server (NTRS)

    Strehlow, R. A.; Reuss, D. L.

    1980-01-01

    Flammability limits in a zero gravity environment were defined. Key aspects of a possible spacelab experiment were investigated analytically, experimentally on the bench, and in drop tower facilities. A conceptual design for a spacelab experiment was developed.

  12. Climate balance of biogas upgrading systems.

    PubMed

    Pertl, A; Mostbauer, P; Obersteiner, G

    2010-01-01

    One of the numerous applications of renewable energy is represented by the use of upgraded biogas where needed by feeding into the gas grid. The aim of the present study was to identify an upgrading scenario featuring minimum overall GHG emissions. The study was based on a life-cycle approach taking into account also GHG emissions resulting from plant cultivation to the process of energy conversion. For anaerobic digestion two substrates have been taken into account: (1) agricultural resources and (2) municipal organic waste. The study provides results for four different upgrading technologies including the BABIU (Bottom Ash for Biogas Upgrading) method. As the transport of bottom ash is a critical factor implicated in the BABIU-method, different transport distances and means of conveyance (lorry, train) have been considered. Furthermore, aspects including biogas compression and energy conversion in a combined heat and power plant were assessed. GHG emissions from a conventional energy supply system (natural gas) have been estimated as reference scenario. The main findings obtained underlined how the overall reduction of GHG emissions may be rather limited, for example for an agricultural context in which PSA-scenarios emit only 10% less greenhouse gases than the reference scenario. The BABIU-method constitutes an efficient upgrading method capable of attaining a high reduction of GHG emission by sequestration of CO(2).

  13. Climate balance of biogas upgrading systems

    SciTech Connect

    Pertl, A.; Mostbauer, P.; Obersteiner, G.

    2010-01-15

    One of the numerous applications of renewable energy is represented by the use of upgraded biogas where needed by feeding into the gas grid. The aim of the present study was to identify an upgrading scenario featuring minimum overall GHG emissions. The study was based on a life-cycle approach taking into account also GHG emissions resulting from plant cultivation to the process of energy conversion. For anaerobic digestion two substrates have been taken into account: (1) agricultural resources and (2) municipal organic waste. The study provides results for four different upgrading technologies including the BABIU (Bottom Ash for Biogas Upgrading) method. As the transport of bottom ash is a critical factor implicated in the BABIU-method, different transport distances and means of conveyance (lorry, train) have been considered. Furthermore, aspects including biogas compression and energy conversion in a combined heat and power plant were assessed. GHG emissions from a conventional energy supply system (natural gas) have been estimated as reference scenario. The main findings obtained underlined how the overall reduction of GHG emissions may be rather limited, for example for an agricultural context in which PSA-scenarios emit only 10% less greenhouse gases than the reference scenario. The BABIU-method constitutes an efficient upgrading method capable of attaining a high reduction of GHG emission by sequestration of CO{sub 2}.

  14. Experimental Verification of Material Flammability in Space

    NASA Technical Reports Server (NTRS)

    Ivanov, A. V.; Balashov, Y. V.; Andreeva, T. V.; Melikhov, A. S.

    1999-01-01

    The flammability in microgravity of three US-furnished materials, Delrin, polymethylmethacrylate (PMMA), and high-density polyethylene, was determined using a Russian-developed combustion tunnel on Mir. Four 4.5-mm-diameter cylindrical samples of each plastic were ignited under concurrent airflow (in the direction of flame spread) with velocities from no flow to 8.5 cm/s. The test results identify a limiting air-flow velocity V(sub lim) for each material, below which combustion ceases. Nominal values are V(sub lim) < 0.3 cm/s for Delrin, 0.5 cm/s for PMMA, and 0.3 to 0.5 cm/s for polyethylene. These values are lower than those obtained in prior ground testing. Nevertheless, they demonstrate that flow shutoff is effective for extinguishment in the microgravity environment of spacecraft. Microgravity test results also show that the plastic materials maintain a stable melt ball within the spreading flame zone. In general, as the concurrent flow velocity V decreases, the flame-spread rate V(sub F) decreases, from an average (for all three materials) of V(sub F)= 0.5-0.75 mm/s at V = 8.5 cm/s to V(sub F)= 0.05-0.01 mm/s at V = 0.3-0.5 cm/s. Also, as V decreases, the flames become less visible but expand, increasing the probability of igniting an adjacent surface.

  15. Flammable gas tank exhauster interlock (FGTEI) computer software design description

    SciTech Connect

    Smith, S.O., Westinghouse Hanford

    1996-09-20

    Modicon Compact Programmable Logic Controller (PLC). The device configuration integrates the isolation and current- carrying capacities of mechanical relays with the logic and programming sophistication of the PLC. This revised document provides descriptions of components and tasks involved in the PLC system for controlling and monitoring the FGTEI. All control functions required by the PLC, and how they are implemented, are described in detail.

  16. Flammable gas tank exhauster interlock (LFGTEI) computer software design description

    SciTech Connect

    Smith, S.O.; Irvitt, R.W., Fluor Daniel Hanford

    1997-02-21

    Modicon Compact Programmable Logic Controller (PLC). The device configuration integrates the isolation and current- carrying capacities of mechanical relays with the logic and programming sophistication of the PLC. This revised document provides descriptions of components and tasks involved in the PLC system for controlling and monitoring the FGTEI. All control functions required by the PLC, and how they are implemented, are described in detail.

  17. Flammable gas tank exhauster interlock (FGTEI) computer software design description

    SciTech Connect

    Smith, S.0.

    1996-09-10

    Modicon Compact Programmable Logic Controller (PLC). The device configuration integrates the isolation and current-carrying capacities of mechanical relays with the logic and programming sophistication of the PLC. This document provides descriptions of components and tasks involved in the PLC system for controlling and monitoring the FGTEI. All control functions required by the PLC, and how they are implemented, are described in detail.

  18. Impact Of Melter Internal Design On Off-Gas Flammability

    SciTech Connect

    Choi, A. S.; Lee, S. Y.

    2012-05-30

    The purpose of this study was to: (1) identify the more dominant design parameters that can serve as the quantitative measure of how prototypic a given melter is, (2) run the existing DWPF models to simulate the data collected using both DWPF and non-DWPF melter configurations, (3) confirm the validity of the selected design parameters by determining if the agreement between the model predictions and data is reasonably good in light of the design and operating conditions employed in each data set, and (4) run Computational Fluid Dynamics (CFD) simulations to gain new insights into how fluid mixing is affected by the configuration of melter internals and to further apply the new insights to explaining, for example, why the agreement is not good.

  19. Simplifying SCADA RTU upgrades

    SciTech Connect

    Barr, J.; Curnutt, B. )

    1989-07-01

    When a pipe line company decides to upgrade SCADA remote terminal units (RTUs) in a system, the new RTUs are usually made to work with existing communications and host equipment. The authors tell how to avoid most conversion problems.

  20. Tapping upgrade potential

    SciTech Connect

    Gill, H.S. )

    1993-01-01

    Modernizing aging hydropower stations presents plant owners with a unique opportunity for improving efficiency and plant output. But several factors should be considered before undertaking a turbine upgrade project.

  1. Training for Technology Upgrade.

    ERIC Educational Resources Information Center

    Strandberg, John

    1997-01-01

    A computer system conversion in a business was relatively painless for users and invisible to customers. The plan relied on basic training strategies that apply to a variety of technology upgrades. (Author/JOW)

  2. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  3. Optics upgrade for switchyard

    SciTech Connect

    Kobilarcik, Thomas R.; /Fermilab

    2005-08-01

    An upgrade of the Switchyard optics is proposed. This upgrade extends the P3 (old Main Ring) lattice through enclosure C. The septa for the 3-way Meson Area split is moved from enclosure F1 to enclosure M01. The functionality of the Meson Target Train is preserved. Finally, for the purpose of demonstrating that the resulting split can be transported, a straw-man lattice is proposed for enclosure M02 and beyond.

  4. On the temperature dependence of flammability limits of gases.

    PubMed

    Kondo, Shigeo; Takizawa, Kenji; Takahashi, Akifumi; Tokuhashi, Kazuaki

    2011-03-15

    Flammability limits of several combustible gases were measured at temperatures from 5 to 100 °C in a 12-l spherical flask basically following ASHRAE method. The measurements were done for methane, propane, isobutane, ethylene, propylene, dimethyl ether, methyl formate, 1,1-difluoroethane, ammonia, and carbon monoxide. As the temperature rises, the lower flammability limits are gradually shifted down and the upper limits are shifted up. Both the limits shift almost linearly to temperature within the range examined. The linear temperature dependence of the lower flammability limits is explained well using a limiting flame temperature concept at the lower concentration limit (LFL)--'White's rule'. The geometric mean of the flammability limits has been found to be relatively constant for many compounds over the temperature range studied (5-100 °C). Based on this fact, the temperature dependence of the upper flammability limit (UFL) can be predicted reasonably using the temperature coefficient calculated for the LFL. However, some compounds such as ethylene and dimethyl ether, in particular, have a more complex temperature dependence.

  5. Credit PSR. The flammable waste materials shed appears as seen ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Credit PSR. The flammable waste materials shed appears as seen when looking south (186°) from South Liquid Loop Road. Note the catch basin for retaining accidentally spilled substances. Wastes are stored in drums and other safety containers until disposal by burning at the Incinerator (4249/E-50) or by other means. Note the nearby sign warning of corrosive, flammable materials, and calling attention to a fire extinguisher; a telephone is provided to call for assistance in the event of an emergency. This structure is isolated to prevent the spread of fire, and it is lightly built so damage from a fire will be inexpensive to repair - Jet Propulsion Laboratory Edwards Facility, Waste Flammable Storage Building, Edwards Air Force Base, Boron, Kern County, CA

  6. Some electrostatic considerations in the transportation of flammable liquids

    SciTech Connect

    Pratt, T.H.; Atharton, J.G.

    1996-12-31

    The transportation of flammable liquids in bulk quantities is a common operation in the chemical industry. Therefore a rather comprehensive set of regulations, standards, and recommended practices exists which govern how these operations should be performed in strict accordance with the directions given, occurrence of inadvertent ignitions have been rare, if nonexistent. On the other hand, there have been occasions when seemingly slight and innocuous deviations from the guidelines have been incorporated into an operation, resulting in catastrophic incidents. This paper discusses some of the guidelines concerning electrostatic ignitions of flammable liquids and illustrates specific case histories where such deviations have led to accidents. Two marine incidents, one rail car incident, and two tank truck incidents are presented in detail to amplify why strict adherence to the regulations, standards and recommended practices is vital in operations where flammable liquids are transported. 5 refs., 4 figs., 1 tab.

  7. Flammability Control In A Nuclear Waste Vitrification System

    SciTech Connect

    Zamecnik, John R.; Choi, Alexander S.; Johnson, Fabienne C.; Miller, Donald H.; Lambert, Daniel P.; Stone, Michael E.; Daniel, William E. Jr.

    2013-07-25

    The Defense Waste Processing Facility at the Savannah River Site processes high-level radioactive waste from the processing of nuclear materials that contains dissolved and precipitated metals and radionuclides. Vitrification of this waste into borosilicate glass for ultimate disposal at a geologic repository involves chemically modifying the waste to make it compatible with the glass melter system. Pretreatment steps include removal of excess aluminum by dissolution and washing, and processing with formic and nitric acids to: 1) adjust the reduction-oxidation (redox) potential in the glass melter to reduce radionuclide volatility and improve melt rate; 2) adjust feed rheology; and 3) reduce by steam stripping the amount of mercury that must be processed in the melter. Elimination of formic acid in pretreatment has been studied to eliminate the production of hydrogen in the pretreatment systems, which requires nuclear grade monitoring equipment. An alternative reductant, glycolic acid, has been studied as a substitute for formic acid. However, in the melter, the potential for greater formation of flammable gases exists with glycolic acid. Melter flammability is difficult to control because flammable mixtures can be formed during surges in offgases that both increase the amount of flammable species and decrease the temperature in the vapor space of the melter. A flammable surge can exceed the 60% of the LFL with no way to mitigate it. Therefore, careful control of the melter feed composition based on scaled melter surge testing is required. The results of engineering scale melter tests with the formic-nitric flowsheet and the use of these data in the melter flammability model are presented.

  8. Applicability of Aerospace Materials Ground Flammability Test Data to Spacecraft Environments Theory and Applied Technologies

    NASA Technical Reports Server (NTRS)

    Hirsch, David; Williams, Jim; Beeson, Harold

    2009-01-01

    This slide presentation reviews the use of ground test data in reference to flammability to spacecraft environments. It reviews the current approach to spacecraft fire safety, the challenges to fire safety that the Constellation program poses, the current trends in the evaluation of the Constellation materials flammability, and the correlation of test data from ground flammability tests with the spacecraft environment. Included is a proposal for testing and the design of experiments to test the flammability of materials under similar spacecraft conditions.

  9. Development of flammable liquid storage wooden cabinets for chemical laboratories

    SciTech Connect

    Staggs, K.J.; Hasegawa, H.K.; Doughty, S.M.; Barr, J.G.

    1993-11-01

    A fire hardened wooden cabinet was developed for the storage of flammable liquids for LLNL Bldg. 151 nuclear chemistry laboratories. The new cabinet requirements were to fit into existing cabinet spaces, match existing cabinets in appearance, and meet the National Fire Protection Association Flammable and Combustible Liquids Code. A standard test apparatus was developed to produce the required fire exposure necessary to evaluate existing cabinets and new designs. The final design was a cabinet insert that could be prefabricated and installed into the appropriate storage area of the existing cabinets.

  10. 16 CFR Figure 1 to Part 1610 - Sketch of Flammability Apparatus

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 16 Commercial Practices 2 2014-01-01 2014-01-01 false Sketch of Flammability Apparatus 1 Figure 1 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF CLOTHING TEXTILES Pt. 1610, Fig. 1 Figure 1 to Part...

  11. 16 CFR Figure 1 to Part 1610 - Sketch of Flammability Apparatus

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 16 Commercial Practices 2 2012-01-01 2012-01-01 false Sketch of Flammability Apparatus 1 Figure 1 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF CLOTHING TEXTILES Pt.1610, Fig. 1 Figure 1 to Part 1610—Sketch...

  12. 16 CFR Figure 1 to Part 1610 - Sketch of Flammability Apparatus

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 16 Commercial Practices 2 2013-01-01 2013-01-01 false Sketch of Flammability Apparatus 1 Figure 1 to Part 1610 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FLAMMABLE FABRICS ACT REGULATIONS STANDARD FOR THE FLAMMABILITY OF CLOTHING TEXTILES Pt. 1610, Fig. 1 Figure 1 to Part...

  13. 14 CFR 26.37 - Pending type certification projects: Fuel tank flammability.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Pending type certification projects: Fuel tank flammability. 26.37 Section 26.37 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION... AIRPLANES Fuel Tank Flammability § 26.37 Pending type certification projects: Fuel tank flammability....

  14. 14 CFR 26.37 - Pending type certification projects: Fuel tank flammability.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Pending type certification projects: Fuel tank flammability. 26.37 Section 26.37 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION... AIRPLANES Fuel Tank Flammability § 26.37 Pending type certification projects: Fuel tank flammability....

  15. 46 CFR 30.10-21 - Flammable or inflammable-TB/ALL.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 1 2011-10-01 2011-10-01 false Flammable or inflammable-TB/ALL. 30.10-21 Section 30.10-21 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY TANK VESSELS GENERAL PROVISIONS Definitions § 30.10-21 Flammable or inflammable—TB/ALL. The words flammable and inflammable are interchangeable...

  16. 46 CFR 30.10-21 - Flammable or inflammable-TB/ALL.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Flammable or inflammable-TB/ALL. 30.10-21 Section 30.10-21 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY TANK VESSELS GENERAL PROVISIONS Definitions § 30.10-21 Flammable or inflammable—TB/ALL. The words flammable and inflammable are interchangeable...

  17. 46 CFR 90.05-35 - Flammable and combustible liquid cargo in bulk.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Flammable and combustible liquid cargo in bulk. 90.05-35... VESSELS GENERAL PROVISIONS Application § 90.05-35 Flammable and combustible liquid cargo in bulk. Note... limited quantities of flammable and combustible liquid cargo in bulk in the grades indicated, provided...

  18. 46 CFR 90.05-35 - Flammable and combustible liquid cargo in bulk.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Flammable and combustible liquid cargo in bulk. 90.05-35... VESSELS GENERAL PROVISIONS Application § 90.05-35 Flammable and combustible liquid cargo in bulk. Note... limited quantities of flammable and combustible liquid cargo in bulk in the grades indicated, provided...

  19. 46 CFR 90.05-35 - Flammable and combustible liquid cargo in bulk.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Flammable and combustible liquid cargo in bulk. 90.05-35... VESSELS GENERAL PROVISIONS Application § 90.05-35 Flammable and combustible liquid cargo in bulk. Note... limited quantities of flammable and combustible liquid cargo in bulk in the grades indicated, provided...

  20. 46 CFR 90.05-35 - Flammable and combustible liquid cargo in bulk.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Flammable and combustible liquid cargo in bulk. 90.05-35... VESSELS GENERAL PROVISIONS Application § 90.05-35 Flammable and combustible liquid cargo in bulk. Note... limited quantities of flammable and combustible liquid cargo in bulk in the grades indicated, provided...

  1. 46 CFR 90.05-35 - Flammable and combustible liquid cargo in bulk.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Flammable and combustible liquid cargo in bulk. 90.05-35... VESSELS GENERAL PROVISIONS Application § 90.05-35 Flammable and combustible liquid cargo in bulk. Note... limited quantities of flammable and combustible liquid cargo in bulk in the grades indicated, provided...

  2. 46 CFR 194.05-11 - Flammable solids and oxidizing materials-Detail requirements.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 7 2011-10-01 2011-10-01 false Flammable solids and oxidizing materials-Detail... and Marking § 194.05-11 Flammable solids and oxidizing materials—Detail requirements. (a) Flammable solids and oxidizing materials used as chemical stores and reagents are governed by subparts 194.15...

  3. ISO 14624 Series - Space Systems - Safety and Compatibility of Materials Flammability Assessment of Spacecraft Materials

    NASA Technical Reports Server (NTRS)

    Hirsch, David B.

    2007-01-01

    A viewgraph presentation on the flammability of spacecraft materials is shown. The topics include: 1) Spacecraft Fire Safety; 2) Materials Flammability Test; 3) Impetus for enhanced materials flammability characterization; 4) Exploration Atmosphere Working Group Recommendations; 5) Approach; and 6) Status of implementation

  4. 49 CFR 174.304 - Class 3 (flammable liquid) materials in tank cars.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false Class 3 (flammable liquid) materials in tank cars... (flammable liquid) materials in tank cars. A tank car containing a Class 3 (flammable liquid) material, other... the liquid from the tank car to permanent storage tanks of sufficient capacity to receive the...

  5. 49 CFR 174.304 - Class 3 (flammable liquid) materials in tank cars.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 2 2014-10-01 2014-10-01 false Class 3 (flammable liquid) materials in tank cars... (flammable liquid) materials in tank cars. A tank car containing a Class 3 (flammable liquid) material, other... the liquid from the tank car to permanent storage tanks of sufficient capacity to receive the...

  6. The LHCb Upgrade

    NASA Astrophysics Data System (ADS)

    Piucci, Alessio

    2017-07-01

    During the LHC Run 1 the LHCb experiment has successfully performed a large number of high precision measurements in heavy flavour physics using 3 fb-1 of data collected at centre-of-mass energies of 7 TeV and 8 TeV. In LHC Run 2 the LHCb is expected to integrate an additional 5 fb-1 data, however many of the measurements will remain limited by statistics. For this reason LHCb will undergo in 2020 a major upgrade during the Long Shutdown 2 of LHC, with the aim to collect 50 fb-1 of data by 2028. To achieve this goal the LHCb detector readout rate will be upgraded from the current 1 MHz to the LHC bunch crossing rate of 40 MHz. The luminosity delivered to the experiment will increase by a factor five, up to 2 ṡ 1033 cm-2 s-1. The online selection of events will be uniquely performed by a pure software trigger, improving the trigger efficiencies. In order to sustain the increased luminosity and readout rate, all the sub-detectors will be upgraded. The architecture of the upgraded DAQ system and trigger strategy will be presented, as well an overview of the sub-detector upgrades.

  7. Cyclotron Institute Upgrade Project

    SciTech Connect

    Clark, Henry; Yennello, Sherry; Tribble, Robert

    2014-08-26

    The Cyclotron Institute at Texas A&M University has upgraded its accelerator facilities to extend research capabilities with both stable and radioactive beams. The upgrade is divided into three major tasks: (1) re-commission the K-150 (88”) cyclotron, couple it to existing beam lines to provide intense stable beams into the K-500 experimental areas and use it as a driver to produce radioactive beams; (2) develop light ion and heavy ion guides for stopping radioactive ions created with the K-150 beams; and (3) transport 1+ ions from the ion guides into a charge-breeding electron-cyclotron-resonance ion source (CB-ECR) to produce highly-charged radioactive ions for acceleration in the K-500 cyclotron. When completed, the upgraded facility will provide high-quality re-accelerated secondary beams in a unique energy range in the world.

  8. ATLAS IBL Pixel Upgrade

    NASA Astrophysics Data System (ADS)

    La Rosa, A.; Atlas Ibl Collaboration

    2011-06-01

    The upgrade for ATLAS detector will undergo different phases towards super-LHC. The first upgrade for the Pixel detector will consist of the construction of a new pixel layer which will be installed during the first shutdown of the LHC machine (LHC phase-I upgrade). The new detector, called Insertable B-Layer (IBL), will be inserted between the existing pixel detector and a new (smaller radius) beam-pipe at a radius of 3.3 cm. The IBL will require the development of several new technologies to cope with increase of radiation or pixel occupancy and also to improve the physics performance which will be achieved by reducing the pixel size and of the material budget. Three different promising sensor technologies (planar-Si, 3D-Si and diamond) are currently under investigation for the pixel detector. An overview of the project with particular emphasis on the pixel module is presented in this paper.

  9. ADCOM Secure Voice Upgrade.

    DTIC Science & Technology

    1981-08-27

    EE G/EETS-TR-81-17-KN ENMIhE~h 1842 EEG/EETS TR 81-17-EK’"" ’""LEVEL AELECT E D -cH q is ITECHNICAL REPORT ADCOM SECURE VOICE UPGRADE A Past of Pride...REPO NUMBER 2. GOVT ACCESSION NO. 3. RECIPIENT’S CATALOG NUMBER 1842 EEG/EETS-TR-81-17-EK 1/ 5. TYPE OF REPORT & PERIOD COVERED ADCOM Secure Voice...neceseary and Identify by block number) This technical report is a re-evaluation of alternatives to satisfy the ADCOM secure voice upgrade requirements. The

  10. The UKIRT Upgrades Programme

    NASA Astrophysics Data System (ADS)

    Adamson, Andy; Davies, John; Robson, Ian

    Tim Hawarden presented this paper to the 30th anniversary workshop, just a month before his untimely death. The editors have done their best to convert his talk into this paper, and gratefully acknowledge the assistance of Nick Rees (a member of the Upgrades team, now at Diamond Light Source). Tim's discussion concerned the UKIRT Upgrades Project, which ran through the 1990s and transformed the telescope and made it truly competitive on the world stage for operation into the twenty-first century. The reference list at the end of the paper is comprehensive; some of these are referred to in the paper itself and some are included for completeness only.

  11. Gas release during salt well pumping: model predictions and comparisons to laboratory experiments

    SciTech Connect

    Peurrung, L.M.; Caley, S.M.; Bian, E.Y.; Gauglitz, P.A.

    1996-09-01

    The Hanford Site has 149 single-shell tanks (SSTs) containing radioactive wastes that are complex mixes of radioactive and chemical products. Some of these wastes are known to generate mixtures of flammable gases, including hydrogen, nitrous oxide, and ammonia. Nineteen of these SSTs have been placed on the Flammable Gas Watch List (FGWL) because they are known or suspected, in all but one case, to retain these flammable gases. Salt well pumping to remove the interstitial liquid from SSTs is expected to cause the release of much of the retained gas, posing a number of safety concerns. Research at the Pacific Northwest National Laboratory (PNNL) has sought to quantify the release of flammable gases during salt well pumping operations. This study is being conducted for Westinghouse Hanford Company as part of the PNNL Flammable Gas Project. Understanding and quantifying the physical mechanisms and waste properties that govern gas release during salt well pumping will help to resolve the associated safety issues.

  12. The flammability limits of lean fuel-air mixtures: thermochemical and kinetic criteria for explosion hazards.

    PubMed

    Burgess, D; Hertzberg, M

    1975-01-01

    The present state of knowledge is reviewed concisely in terms of the experimental methods used, the effect of apparatus size, accuracy of data, methods of data presentation, and the sensitivity of the limits to initial temperature and pressure. The heat of combustion per mole of gas mixture at the lean limit is a reliable thermochemical criterion for the flammability of organic fuels with comparable reactivities. The limit calorific value for the heavy paraffins is 11.5 +/- 0.1 kcal mole -1. However, kinetic effects strongly influence this value. Highly reactive fuels (hydrogen, acetylene) require lower energy contents, whereas less reactive fuels (ammonia) require higher values. Hydrogen-starved fuels (carbon monoxide, cyanogen) show marked anomalies and are sensitive to impurities that can provide H-atom chain carriers. These kinetic effects are reflected in the experimentally measurable burning velocity of the fuel. This parameter is a key ingredient in the theory of flammable limits, which is briefly sketched. Five competing processes dissipate power from the combustion wave and quench it at some characteristic limit velocity. The prevalent consensus that the limits are controlled by natural convection is clearly demonstrated, and the complex interplay of kinetics and thermochemistry follows logically therefrom.

  13. Estimation of the lower flammability limit of organic compounds as a function of temperature.

    PubMed

    Rowley, J R; Rowley, R L; Wilding, W V

    2011-02-15

    A new method of estimating the lower flammability limit (LFL) of general organic compounds is presented. The LFL is predicted at 298 K for gases and the lower temperature limit for solids and liquids from structural contributions and the ideal gas heat of formation of the fuel. The average absolute deviation from more than 500 experimental data points is 10.7%. In a previous study, the widely used modified Burgess-Wheeler law was shown to underestimate the effect of temperature on the lower flammability limit when determined in a large-diameter vessel. An improved version of the modified Burgess-Wheeler law is presented that represents the temperature dependence of LFL data determined in large-diameter vessels more accurately. When the LFL is estimated at increased temperatures using a combination of this model and the proposed structural-contribution method, an average absolute deviation of 3.3% is returned when compared with 65 data points for 17 organic compounds determined in an ASHRAE-style apparatus.

  14. Spruce beetle-induced changes to Engelmann spruce foliage flammability

    Treesearch

    Wesley G. Page; Michael J. Jenkins; Justin B. Runyon

    2014-01-01

    Intermountain Engelmann spruce (Picea engelmannii Parry ex Engelm) stands affected by the spruce beetle (Dendroctonus rufipennis Kirby) represent a unique and growing fuel complex. In this study, we quantified and compared the changes in moisture content, chemistry, and flammability of foliage from trees in three crown condition classes: unattacked (green [G]),...

  15. Flammability and Thermophysical Characterization of Thermoplastic Elastomer Nanocomposites

    DTIC Science & Technology

    2004-08-01

    montmorillonite organoclays, POSS®, carbon nanofibers to develop a flame resistant material Thermophysical and flammability properties of these...elastomer manufactured by Dow Chemical. Its typical applications include seals, gaskets, belting, and others. Montmorillonite Nanoclays – Cloisite...30B is a surface treated montmorillonite [Tallow bishydroxyethyl methyl, T(EOH)2M] manufactured by Southern Clay Products Carbon Nanofibers (CNFs

  16. 43 CFR 423.31 - Fires and flammable material.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 1 2012-10-01 2011-10-01 true Fires and flammable material. 423.31 Section 423.31 Public Lands: Interior Regulations Relating to Public Lands BUREAU OF RECLAMATION... smoking materials, including cigarettes, cigars, pipes, matches, or other burning material. (c) You...

  17. The Safety of Small Containers for Flammable Fluids.

    ERIC Educational Resources Information Center

    Shanley, Edward S.

    1988-01-01

    Highlights aspects of safety that are unfamiliar to most laypersons and to many chemists as well. Presents findings that may lend themselves to presentation in chemistry classes. Details flammability tests, vapor space hazards, and the special case of gasoline containers. Provides experimental data relating vent area and internal pressure. (CW)

  18. Wire insulation degradation and flammability in low gravity

    NASA Technical Reports Server (NTRS)

    Friedman, Robert

    1994-01-01

    This view-graph presentation covers the following topics: an introduction to spacecraft fire safety, concerns in fire prevention in low gravity, shuttle wire insulation flammability experiment, drop tower risk-based fire safety experiment, and experimental results, conclusions, and proposed studies.

  19. 43 CFR 423.31 - Fires and flammable material.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 1 2014-10-01 2014-10-01 false Fires and flammable material. 423.31 Section 423.31 Public Lands: Interior Regulations Relating to Public Lands BUREAU OF RECLAMATION, DEPARTMENT OF THE INTERIOR PUBLIC CONDUCT ON BUREAU OF RECLAMATION FACILITIES, LANDS, AND WATERBODIES...

  20. 14 CFR 23.863 - Flammable fluid fire protection.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... AIRCRAFT AIRWORTHINESS STANDARDS: NORMAL, UTILITY, ACROBATIC, AND COMMUTER CATEGORY AIRPLANES Design and...) Flammability characteristics of fluids, including effects of any combustible or absorbing materials. (3... airplane components that are critical to safety of flight to withstand fire and heat. (c) If action by...