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Sample records for fluid-saturated anisotropic porous

  1. Investigation of ultrasonic wave interactions with fluid-saturated porous rocks

    SciTech Connect

    Adler, L.

    1990-01-01

    Investigation of ultrasonic waves, especially the slow compressional wave, with fluid-saturated porous solids, especially rocks. This research effort should fine applications in the geophysical evaluation of fluid-bearing porous rocks where parameters such as tortuosity, permeability, saturation level, and internal impurities are difficult to measure by conventional techniques. The proposed investigation may be divided into three major subtasks: Experimental study of surface wave propagation on fluid-saturated porous materials. A new, so-called direct excitation technique will be used on both air- and water-saturated samples; further development of the Lamb wave technique recently introduced to study guided wave propagation in thin fluid-saturated porous plates. The analytical treatment will be extended to account for viscous losses and scattering inhomogeneities; and theoretical and experimental study of slow wave propagation in fluid-saturated natural rocks. A new technique based on the transmission of airborne ultrasound through air-saturated porous plates will be used to determine properties such as tortuosity, permeability, etc. 22 refs., 37 figs., 3 tabs.

  2. A coupled deformation-diffusion theory for fluid-saturated porous solids

    NASA Astrophysics Data System (ADS)

    Henann, David; Kamrin, Ken; Anand, Lallit

    2012-02-01

    Fluid-saturated porous materials are important in several familiar applications, such as the response of soils in geomechanics, food processing, pharmaceuticals, and the biomechanics of living bone tissue. An appropriate constitutive theory describing the coupling of the mechanical behavior of the porous solid with the transport of the fluid is a crucial ingredient towards understanding the material behavior in these varied applications. In this work, we formulate and numerically implement in a finite-element framework a large-deformation theory for coupled deformation-diffusion in isotropic, fluid-saturated porous solids. The theory synthesizes the classical Biot theory of linear poroelasticity and the more-recent Coussy theory of poroplasticity in a large deformation framework. In this talk, we highlight several salient features of our theory and discuss representative examples of the application of our numerical simulation capability to problems of consolidation as well as deformation localization in granular materials.

  3. Effect of thermal stratification on free convection in a fluid-saturated porous enclosure

    SciTech Connect

    Kumar, B.V.R.; Singh, P.

    1998-08-28

    Natural convection heat transfer from an isothermal vertical surface in a fluid-saturated porous medium under the influence of thermal stratification has been numerically analyzed using the finite element method. The combined effect of Rayleigh number and thermal stratification on the global heat flux in porous cavities of varying aspect ratios has been analyzed. It is observed that the global heat flux (1) decreases with increasing values of the thermal stratification b and (2) increases with increasing values of Rayleigh number Ra. However, the cumulative heat flux along the midsegment of the vertical wall increases with increasing b and decreases with Ra. With increasing b, a reduction in the convection zone with a downward drift is noticed. Global heat flux can be boosted by reducing the width L of the cavity by a factor of {approximately}8 or more. The flow field and the heat transfer results are presented through the streamlines, isotherms, and global heat flux plots.

  4. On wave propagation characteristics in fluid saturated porous materials by a nonlocal Biot theory

    NASA Astrophysics Data System (ADS)

    Tong, Lihong; Yu, Yang; Hu, Wentao; Shi, Yufeng; Xu, Changjie

    2016-09-01

    A nonlocal Biot theory is developed by combing Biot theory and nonlocal elasticity theory for fluid saturated porous material. The nonlocal parameter is introduced as an independent variable for describing wave propagation characteristics in poroelastic material. A physical insight on nonlocal term demonstrates that the nonlocal term is a superposition of two effects, one is inertia force effect generated by fluctuation of porosity and the other is pore size effect inherited from nonlocal constitutive relation. Models for situations of excluding fluid nonlocal effect and including fluid nonlocal effect are proposed. Comparison with experiment confirms that model without fluid nonlocal effect is more reasonable for predicting wave characteristics in saturated porous materials. The negative dispersion is observed theoretically which agrees well with the published experimental data. Both wave velocities and quality factors as functions of frequency and nonlocal parameter are examined in practical cases. A few new physical phenomena such as backward propagation and disappearance of slow wave when exceeding critical frequency and disappearing shear wave in high frequency range, which were not predicted by Biot theory, are demonstrated.

  5. Liquid accumulation in vibrating vocal fold tissue: A simplified model based on a fluid-saturated porous solid theory

    PubMed Central

    Tao, Chao; Jiang, Jack J.; Czerwonka, Lukasz

    2011-01-01

    The human vocal fold is treated as a continuous, transversally isotropic, porous solid saturated with liquid. A set of mathematical equations, based on the theory of fluid-saturated porous solids, is developed to formulate the vibration of the vocal fold tissue. As the fluid-saturated porous tissue model degenerates to the continuous elastic tissue model when the relative movement of liquid in the porous tissue is ignored, it can be considered a more general description of vocal fold tissue than the continuous, elastic model. Using the fluid-saturated porous tissue model, the vibration of a bunch of one-dimensional fibers in the vocal fold is analytically solved based on the small amplitude assumption. It is found that the vibration of the tissue will lead to the accumulation of excess liquid in the midmembranous vocal fold. The degree of liquid accumulation is positively proportional to the vibratory amplitude and frequency. The correspondence between the liquid distribution predicted by the porous tissue theory and the location of vocal nodules observed in clinical practice, provides theoretical evidence for the liquid accumulation hypothesis of vocal nodule formation (Jiang, Ph. D., dissertation, 1991, University of Iowa). PMID:19660905

  6. Non-Darcy double-diffusive natural convection in axisymmetric fluid saturated porous cavities

    NASA Astrophysics Data System (ADS)

    Nithiarasu, P.; Seetharamu, K. N.; Sundararajan, T.

    Double-diffusive natural convection in a fluid saturated porous medium has been investigated using the finite element method. A generalised porous medium model is used to study both Darcy and non-Darcy flow regimes in an axisymmetric cavity. Results indicate that the Darcy number should be a separate parameter to understand flow characteristics in non-Darcy regime. The influence of porosity on heat and mass transfer is significant and the transport rates may differ by 25% or more, at higher Darcy and Rayleigh numbers. When compared with the Darcy and other specialised models of Brinkman and Forchheimer, the present generalised model predicts the least heat and mass transfer rates. It is also observed that an increase in radius ratio leads to higher Nusselt and Sherwood numbers along the inner wall. Zusammenfassung Mit Hilfe der Finitelement-Methode wurde die Doppeldiffusion bei natürlicher Konvektion in einem fluidgetränktem porösen Medium untersucht, wobei ein verallgemeinertes Modell für poröse Medien Verwendung fand, das sich sowohl für Darcysches, wie für nicht-Darcysches Fluidverhalten in einem achsialsymmetrischen Ringraum eignet. Aus den Ergebnissen geht hervor, daß die Darcy-Zahl als zusätzlicher Parameter eingeführt werden muß, um das Strömungsverhalten im nicht-Darcyschen Regime verstehen zu können. Die Porosität hat großen Einfluß auf den Wärme- und Stoffaustausch, so daß bei höheren Darcy- und Rayleigh-Zahlen diesbezüglich Unterschiede bis über 25% auftreten können. Im Vergleich mit den speziellen Modellen nach Darcy, Brinkman und Forchheimer liefert das hier untersuchte verallgemeinerte Modell die geringsten Wärme- und Stoffflüsse. Es zeigt sich ferner, daß die Vergrößerung des Radienverhältnisses höhere Nusselt- und Sherwood- Zahlen entlang der Innenwand zur Folge hat.

  7. The onset of double diffusive convection in a viscoelastic fluid-saturated porous layer with non-equilibrium model.

    PubMed

    Yang, Zhixin; Wang, Shaowei; Zhao, Moli; Li, Shucai; Zhang, Qiangyong

    2013-01-01

    The onset of double diffusive convection in a viscoelastic fluid-saturated porous layer is studied when the fluid and solid phase are not in local thermal equilibrium. The modified Darcy model is used for the momentum equation and a two-field model is used for energy equation each representing the fluid and solid phases separately. The effect of thermal non-equilibrium on the onset of double diffusive convection is discussed. The critical Rayleigh number and the corresponding wave number for the exchange of stability and over-stability are obtained, and the onset criterion for stationary and oscillatory convection is derived analytically and discussed numerically.

  8. Phenomenological model of propagation of the elastic waves in a fluid-saturated porous solid with nonzero boundary slip velocity.

    PubMed

    Tsiklauri, David

    2002-09-01

    It is known that a boundary slip velocity starts to play an important role when the length scale over which the fluid velocity changes approaches the slip length, i.e., when the fluid is highly confined, for example, fluid flow through porous rock or blood vessel capillaries. Zhu and Granick [Phys. Rev. Lett. 87, 096105 (2001)] have recently experimentally established the existence of a boundary slip in a Newtonian liquid. They reported typical values of the slip length of the order of few micrometers. In this light, the effect of introduction of the boundary slip into the theory of propagation of elastic waves in a fluid-saturated porous medium formulated by Biot [J. Acoust. Soc. Am. 28, 179-191 (1956)] is investigated. Namely, the effect of introduction of boundary slip upon the function F(kappa) that measures the deviation from Poiseuille flow friction as a function of frequency parameter kappa is studied. By postulating phenomenological dependence of the slip velocity upon frequency, notable deviations in the domain of intermediate frequencies in the behavior of F(kappa) are introduced with the incorporation of the boundary slip into the model. It is known that F(kappa) crucially enters Biot's equations, which describe dynamics of fluid-saturated porous solid. Thus, consequences of the nonzero boundary slip by calculating the phase velocities and attenuation coefficients of both rotational and dilatational waves with the variation of frequency are investigated. The new model should allow one to fit the experimental seismic data in circumstances when Biot's theory fails, as the introduction of phenomenological dependence of the slip velocity upon frequency, which is based on robust physical arguments, adds an additional degree of freedom to the model. In fact, it predicts higher than the Biot's theory values of attenuation coefficients of the both rotational and dilatational waves in the intermediate frequency domain, which is in qualitative agreement with the

  9. Thermal instability of a fluid-saturated porous medium bounded by thin fluid layers

    SciTech Connect

    Pillatsis, G.; Taslim, M.E.; Narusawa, U. )

    1987-08-01

    A linear stability analysis is performed for a horizontal Darcy porous layer of depth 2d{sub m} sandwiched between two fluid layers of depth d (each) with the top and bottom boundaries being dynamically free and kept at fixed temperatures. The Beavers-Joseph condition is employed as one of the interfacial boundary conditions between the fluid and the porous layer. The critical Rayleigh number and the horizontal wave number for the onset of convective motion depend on the following four dimensional parameters: {cflx d} (= d{sub m}/d, the depth ratio), {delta} (= {radical}K/d{sub m} with K being the permeability of the porous medium) {alpha} (the proportionality constant in the Beavers-Joseph condition), and k/k{sub m} (the thermal conductivity ratio). In order to analyze the effect of these parameters on the stability condition, a set of numerical solutions is obtained in terms of a convergent series for the respective layers, for the case in which the thickness of the porous layer is much greater than that of the fluid layer. A comparison of this study with the previously obtained exact solution for the case of constant heat flux boundaries is made to illustrate quantitative effects of the interfacial and the top/bottom boundaries on the thermal instability of a combined system of porous and fluid layers.

  10. Acoustic emission in a fluid saturated heterogeneous porous layer with application to hydraulic fracture

    SciTech Connect

    Nelson, J.T. . Dept. of Mechanical Engineering Lawrence Berkeley Lab., CA )

    1988-11-01

    A theoretical model for acoustic emission in a vertically heterogeneous porous layer bounded by semi-infinite solid regions is developed using linearized equations of motion for a fluid/solid mixture and a reflectivity method. Green's functions are derived for both point loads and moments. Numerically integrated propagators represent solutions for intermediate heterogeneous layers in the porous region. These are substituted into a global matrix for solution by Gaussian elimination and back-substitution. Fluid partial stress and seismic responses to dislocations associated with fracturing of a layer of rock with a hydraulically conductive fracture network are computed with the model. A constitutive model is developed for representing the fractured rock layer as a porous material, using commonly accepted relationships for moduli. Derivations of density, tortuosity, and sinuosity are provided. The main results of the model application are the prediction of a substantial fluid partial stress response related to a second mode wave for the porous material. The response is observable for relatively large distances, on the order of several tens of meters. The visco-dynamic transition frequency associated with parabolic versus planar fluid velocity distributions across micro-crack apertures is in the low audio or seismic range, in contrast to materials with small pore size, such as porous rocks, for which the transition frequency is ultrasonic. Seismic responses are predicted for receiver locations both in the layer and in the outlying solid regions. In the porous region, the seismic response includes both shear and dilatational wave arrivals and a second-mode arrival. The second-mode arrival is not observable outside of the layer because of its low velocity relative to the dilatational and shear wave propagation velocities of the solid region.

  11. [Investigation of ultrasonic wave interactions with fluid-saturated porous rocks]. [Annual report

    SciTech Connect

    Adler, L.

    1992-07-01

    During the last two years we have continued our investigation of ultrasonic wave propagation in fluid-filled porous materials. First, we studied the feasibility of using different surface modes to characterize both synthetic and natural rocks. We introduced a novel experimental technique based on the direct generation of surface waves by edge excitation. We used two low-frequency (100--500 kHz) shear transducers in pitch-catch mode to launch and receive the ultrasonic surface wave. The contact transducers were coupled to the opposite edges of the porous specimens with normal polarization relative to the surface. The same technique was successfully used to generate Rayleigh-type surface modes on the free surface of both dry and water-saturated specimens, as well as Stoneley-type interface modes on the fluid-loaded surfaces of immersed samples. Our main achievement in this area is the realization that, due to surface tension, practically closed-pore boundary conditions can prevail on the free surface of a water-saturated rock for completely open pores. As a result, the velocity of the true surface mode might be much lower than the Rayleigh velocity of the dry skeleton.

  12. (Investigation of ultrasonic wave interactions with fluid-saturated porous rocks)

    SciTech Connect

    Adler, L.

    1992-01-01

    During the last two years we have continued our investigation of ultrasonic wave propagation in fluid-filled porous materials. First, we studied the feasibility of using different surface modes to characterize both synthetic and natural rocks. We introduced a novel experimental technique based on the direct generation of surface waves by edge excitation. We used two low-frequency (100--500 kHz) shear transducers in pitch-catch mode to launch and receive the ultrasonic surface wave. The contact transducers were coupled to the opposite edges of the porous specimens with normal polarization relative to the surface. The same technique was successfully used to generate Rayleigh-type surface modes on the free surface of both dry and water-saturated specimens, as well as Stoneley-type interface modes on the fluid-loaded surfaces of immersed samples. Our main achievement in this area is the realization that, due to surface tension, practically closed-pore boundary conditions can prevail on the free surface of a water-saturated rock for completely open pores. As a result, the velocity of the true surface mode might be much lower than the Rayleigh velocity of the dry skeleton.

  13. Analytical and numerical analysis of bifurcations in thermal convection of viscoelastic fluids saturating a porous square box

    NASA Astrophysics Data System (ADS)

    Taleb, A.; BenHamed, H.; Ouarzazi, M. N.; Beji, H.

    2016-05-01

    We report theoretical and numerical results on bifurcations in thermal instability for a viscoelastic fluid saturating a porous square cavity heated from below. The modified Darcy law based on the Oldroyd-B model was used for modeling the momentum equation. In addition to Rayleigh number ℜ, two more dimensionless parameters are introduced, namely, the relaxation time λ1 and the retardation time λ2. Temporal stability analysis showed that the first bifurcation from the conductive state may be either oscillatory for sufficiently elastic fluids or stationary for weakly elastic fluids. The dynamics associated with the nonlinear interaction between the two kinds of instabilities is first analyzed in the framework of a weakly nonlinear theory. For sufficiently elastic fluids, analytical expressions of the nonlinear threshold above which a second hysteretic bifurcation from oscillatory to stationary convective pattern are derived and found to agree with two-dimensional numerical simulations of the full equations. Computations performed with high Rayleigh number indicated that the system exhibits a third transition from steady single-cell convection to oscillatory multi-cellular flows. Moreover, we found that an intermittent oscillation regime may exist with steady state before the emergence of the secondary Hopf bifurcation. For weakly elastic fluids, we determined a second critical value ℜ2 Osc ( λ 1 , λ 2 ) above which a Hopf bifurcation from steady convective pattern to oscillatory convection occurs. The well known limit of ℜ2 Osc ( λ 1 = 0 , λ 2 = 0 ) = 390 for Newtonian fluids is recovered, while the fluid elasticity is found to delay the onset of the Hopf bifurcation. The major new findings were presented in the form of bifurcation diagrams as functions of viscoelastic parameters for ℜ up to 420.

  14. Spectral Quasi-linearization Method for Homogeneous-Heterogeneous Reactions on Nonlinear Convection Flow of Micropolar Fluid Saturated Porous Medium with Convective Boundary Condition

    NASA Astrophysics Data System (ADS)

    RamReddy, Chetteti; Pradeepa, Teegala

    2016-05-01

    Based on the nonlinear variation of density with temperature (NDT) in the buoyancy term, the mixed convection flow along a vertical plate of a micropolar fluid saturated porous medium is considered. In addition, the effect of homogeneous-heterogeneous reaction and convective boundary condition has been taken into account. Using lie scaling group transformations, the similarity representation is attained for the system of partial differential equations, prior to being solved by a spectral quasilinearization method. The results show that in the presence of aiding and opposing flow situations, both the species concentration and mass transfer rate decreases when the strength of homogeneous and heterogeneous reaction parameters are enhanced.

  15. Similarity solution for free convection from a point heat source embedded in a non-Newtonian fluid-saturated porous medium

    SciTech Connect

    Nakayama, A. )

    1993-05-01

    Convection problems associated with concentrated heat sources within fluid-saturated porous media are of great practical significance, for there are a number of practical applications in geophysics and energy-related problems, such as recovery of petroleum resources, geophysical flows, cooling of underground electric cables, and environmental impact of buried heat generating waste. In this note, a boundary layer analysis is presented for free convection from a point heat source embedded in a porous medium saturated with a non-Newtonian power-law fluid. The governing equations are found to possess a similarity solution for an arbitrary value of the power-law index. Closed-form solutions are presented for both flow and temperature fields, and the effects of pseudoplasticity on the plumes are examined. 17 refs., 5 figs.

  16. Analysis of matching conditions at the boundary surface of a fluid-saturated porous solid and a bulk fluid: the use of Lagrange multipliers

    NASA Astrophysics Data System (ADS)

    Kubik, J.; Cieszko, M.

    2005-12-01

    The compatibility conditions matching macroscopic mechanical fields at the contact surface between a fluid-saturated porous solid and an adjacent bulk fluid are considered. The general form of balance equations at that discontinuity surface are analyzed to obtain the compatibility conditions for the tangent and normal components of the velocity and the stress vector fields. Considerations are based on the procedure similar to that used in the phenomenological thermodynamics for derivation of constitutive relations, where the entropy inequality and the concept of Lagrange multipliers are applied. This procedure made possible to derive the compatibility conditions for the viscous fluid flowing tangentially and perpendicularly to the boundary surface of the porous solid and to formulate the generalized form of the so called slip condition for the fluid velocity field, postulated earlier by Beavers and Joseph, J. Fluid. Mech. 30, 197-207 (1967).

  17. Influence of phase connectivity on the relationship among capillary pressure, fluid saturation, and interfacial area in two-fluid-phase porous medium systems

    DOE PAGES

    McClure, James E.; Berrill, Mark A.; Gray, William G.; Miller, Cass T.

    2016-09-02

    Here, multiphase flow in porous medium systems is typically modeled using continuum mechanical representations at the macroscale in terms of averaged quantities. These models require closure relations to produce solvable forms. One of these required closure relations is an expression relating fluid pressures, fluid saturations, and, in some cases, the interfacial area between the fluid phases, and the Euler characteristic. An unresolved question is whether the inclusion of these additional morphological and topological measures can lead to a non-hysteretic closure relation compared to the hysteretic forms that are used in traditional models, which typically do not include interfacial areas, ormore » the Euler characteristic. We develop a lattice-Boltzmann (LB) simulation approach to investigate the equilibrium states of a two-fluid-phase porous medium system, which include disconnected now- wetting phase features. The proposed approach is applied to a synthetic medium consisting of 1,964 spheres arranged in a random, non-overlapping, close-packed manner, yielding a total of 42,908 different equilibrium points. This information is evaluated using a generalized additive modeling approach to determine if a unique function from this family exists, which can explain the data. The variance of various model estimates is computed, and we conclude that, except for the limiting behavior close to a single fluid regime, capillary pressure can be expressed as a deterministic and non-hysteretic function of fluid saturation, interfacial area between the fluid phases, and the Euler characteristic. This work is unique in the methods employed, the size of the data set, the resolution in space and time, the true equilibrium nature of the data, the parameterizations investigated, and the broad set of functions examined. The conclusion of essentially non-hysteretic behavior provides support for an evolving class of two-fluid-phase flow in porous medium systems models.« less

  18. Influence of phase connectivity on the relationship among capillary pressure, fluid saturation, and interfacial area in two-fluid-phase porous medium systems

    NASA Astrophysics Data System (ADS)

    McClure, James E.; Berrill, Mark A.; Gray, William G.; Miller, Cass T.

    2016-09-01

    Multiphase flows in porous medium systems are typically modeled at the macroscale by applying the principles of continuum mechanics to develop models that describe the behavior of averaged quantities, such as fluid pressure and saturation. These models require closure relations to produce solvable forms. One of these required closure relations is an expression relating the capillary pressure to fluid saturation and, in some cases, other topological invariants such as interfacial area and the Euler characteristic (or average Gaussian curvature). The forms that are used in traditional models, which typically consider only the relationship between capillary pressure and saturation, are hysteretic. An unresolved question is whether the inclusion of additional morphological and topological measures can lead to a nonhysteretic closure relation. Relying on the lattice Boltzmann (LB) method, we develop an approach to investigate equilibrium states for a two-fluid-phase porous medium system, which includes disconnected nonwetting phase features. A set of simulations are performed within a random close pack of 1964 spheres to produce a total of 42 908 distinct equilibrium configurations. This information is evaluated using generalized additive models to quantitatively assess the degree to which functional relationships can explain the behavior of the equilibrium data. The variance of various model estimates is computed, and we conclude that, except for the limiting behavior close to a single fluid regime, capillary pressure can be expressed as a deterministic and nonhysteretic function of fluid saturation, interfacial area between the fluid phases, and the Euler characteristic. To our knowledge, this work is unique in the methods employed, the size of the data set, the resolution in space and time, the true equilibrium nature of the data, the parametrizations investigated, and the broad set of functions examined. The conclusion of essentially nonhysteretic behavior provides

  19. Thermal convection of magneto compressible couple-stress fluid saturated in a porous medium with Hall current

    NASA Astrophysics Data System (ADS)

    Mehta, C. B.; Singh, M.; Kumar, S.

    2016-02-01

    An investigation is made on the effect of Hall currents on thermal instability of a compressible couple-stress fluid in the presence of a horizontal magnetic field saturated in a porous medium. The analysis is carried out within the framework of the linear stability theory and normal mode technique. A dispersion relation governing the effects of viscoelasticity, Hall currents, compressibility, magnetic field and porous medium is derived. For the stationary convection a couple-stress fluid behaves like an ordinary Newtonian fluid due to the vanishing of the viscoelastic parameter. Compressibility, the magnetic filed and couple-stress parameter have stabilizing effects on the system whereas Hall currents and medium permeability have a destabilizing effect on the system, but in the absence of Hall current couple-stress has a destabilizing effect on the system. It has been observed that oscillatory modes are introduced due to the presence of viscoelasticity, magnetic field porous medium and Hall currents which were non-existent in their absence.

  20. Influence of anisotropic permeability on convection in porous media: Implications for geological CO2 sequestration

    NASA Astrophysics Data System (ADS)

    De Paoli, Marco; Zonta, Francesco; Soldati, Alfredo

    2016-05-01

    Solute convection in porous media at high Rayleigh-Darcy numbers has important fundamental features and may also bear implications for geological CO2 sequestration processes. With the aid of direct numerical simulations, we examine the role of anisotropic permeability on the distribution of solutal concentration in fluid saturated porous medium. Our computational analyses span over few decades of Rayleigh-Darcy number and confirm the linear scaling of Nusselt number that was previously found in the literature. In addition, we find that anisotropic permeability γ < 1, i.e., with vertical permeability smaller than horizontal permeability, effectively increases the Nusselt number compared with isotropic conditions. We link this seemingly counterintuitive effect with the occurring modifications to the flow topology in the anisotropic conditions. Finally, we use our data computed for the two-sided configuration (i.e., Dirichlet conditions on upper and lower boundaries) to examine the time evolution of solutal dynamics in the one-sided configuration, and we demonstrate that the finite-time (short-term) amount of CO2 that can be dissolved in anisotropic sedimentary rocks is much larger than in isotropic rocks.

  1. Poroelastic measurement schemes resulting in complete data sets for granular and other anisotropic porous media

    SciTech Connect

    Berryman, J.G.

    2009-11-20

    Poroelastic analysis usually progresses from assumed knowledge of dry or drained porous media to the predicted behavior of fluid-saturated and undrained porous media. Unfortunately, the experimental situation is often incompatible with these assumptions, especially when field data (from hydrological or oil/gas reservoirs) are involved. The present work considers several different experimental scenarios typified by one in which a set of undrained poroelastic (stiffness) constants has been measured using either ultrasound or seismic wave analysis, while some or all of the dry or drained constants are normally unknown. Drained constants for such a poroelastic system can be deduced for isotropic systems from available data if a complete set of undrained compliance data for the principal stresses are available - together with a few other commonly measured quantities such as porosity, fluid bulk modulus, and grain bulk modulus. Similar results are also developed here for anisotropic systems having up to orthotropic symmetry if the system is granular (i.e., composed of solid grains assembled into a solid matrix, either by a cementation process or by applied stress) and the grains are known to be elastically homogeneous. Finally, the analysis is also fully developed for anisotropic systems with nonhomogeneous (more than one mineral type), but still isotropic, grains - as well as for uniform collections of anisotropic grains as long as their axes of symmetry are either perfectly aligned or perfectly random.

  2. Dilatant hardening of fluid-saturated sandstone

    NASA Astrophysics Data System (ADS)

    Makhnenko, Roman Y.; Labuz, Joseph F.

    2015-02-01

    The presence of pore fluid in rock affects both the elastic and inelastic deformation processes, yet laboratory testing is typically performed on dry material even though in situ the rock is often saturated. Techniques were developed for testing fluid-saturated porous rock under the limiting conditions of drained, undrained, and unjacketed response. Confined compression experiments, both conventional triaxial and plane strain, were performed on water-saturated Berea sandstone to investigate poroelastic and inelastic behavior. Measured drained response was used to calibrate an elasto-plastic constitutive model that predicts undrained inelastic deformation. The experimental data show good agreement with the model: dilatant hardening in undrained triaxial and plane strain compression tests under constant mean stress was predicted and observed.

  3. Pore-Scale Study of the Effect of the Saturation History on Fluid Saturation and Relative Permeability of Three-Fluid Flow in Porous Media

    NASA Astrophysics Data System (ADS)

    Hsu, S. Y.; Tsai, J. P.; Chang, L. C.

    2014-12-01

    The flow of three immiscible fluids - water, NAPL, air - in porous media is important in many subsurface processes. To model the three-fluid flow, the relation of relative permeability-saturation-capillary pressure (k-S-P) of three fluids is of central importance. In this experimental study, we directly measure the k-S-P of the water (wetting phase) when three fluids are coexist in a micromodel during the water drainage and imbibition. The results show that the sequence of the non-wetting fluids (air and NAPL) entering into the micromodel affects the fluid distributions as well as the relative permeability of water. During the drainage process, the relative permeability of water dropped drastically when the pathway of water from inlet to outlet of the micromodel was visually blocked by the non-wetting fluids. At this stage, the relative permeability of water was low but not down to zero. The water was still able to move via corner flows or thin-film flows. During the imbibition process, the water displaced two non-wetting liquids via both "snap-off" and "piston-type" motions. The relative permeability of water jumped when the water pathway was formed again. In addition, we found that the well-known scaling format proposed by Parker et al. [1] might fail when the interfaces between the most non-wetting (air) and the most wetting (water) fluids occurs in the three-fluids system. References[1] J. C. Parker, R. J. Lenhard, and T. Kuppusamy, Water Resources Research, 23, 4, 618-624 (1987)

  4. Lifting a large object from an anisotropic porous bed

    NASA Astrophysics Data System (ADS)

    Karmakar, Timir; Raja Sekhar, G. P.

    2016-09-01

    An analytical study of two dimensional problem of lifting an object from the top of a fully saturated rigid porous bed is discussed. It is assumed that the porous bed is anisotropic in nature. The flow within the gap region between the object and the porous bed is assumed to be governed by Stokes equation while the flow within the porous bed is governed by Brinkman equation. The breakout phenomenon for different kinds of soil is reported. The effect of mechanical properties like anisotropic permeability, grain diameter size, and porosity on streamlines, velocity, and force is analyzed. Relevant comparison with C. C. Mei, R. W. Yeung, and K. F. Liu ["Lifting a large object from a porous bed," J. Fluid. Mech. 152, 203-215 (1985)] and Y. Chang, L. H. Huang and F. P. Y. Yang ["Two-dimensional lift-up problem for a rigid porous bed," Phys. Fluids, 27, 053101 (2015)] is done.

  5. Anisotropic porous metals production by melt processing

    SciTech Connect

    Shapovalov, V.; Boiko, L.; Baldwin, M.D.; Maguire, M.C.; Zanner, F.J.

    1997-02-01

    The collapse of the Soviet Union has left many of its scientific institutes and technical universities without their traditional backbone of financial support. In an effort to stem the export of science to nations advocating nuclear proliferation, and to acquire potentially useful technology, several US government-sponsored programs have arise to mine the best of former USSR scientific advances. In the field of metallurgy, the earliest institutes to be investigated by Sandia National Laboratories are located in Ukraine. In particular, scientists at the State Metallurgical Academy have developed unique porous metals, resembling what could be described as gas-solid ``eutectic``. While porous metals are available in the US and other western countries, none have the remarkable structure and properties of these materials. Sandia began a collaborative program with the Ukrainian scientists to bring this technology to the US, verify the claims regarding these materials, and begin production of the so-called Gasars. This paper will describe the casting process technology and metallurgy associated with the production of Gasars, and will review the progress of the collaborative project.

  6. Numerical investigation of nanoparticles transport in anisotropic porous media.

    PubMed

    Salama, Amgad; Negara, Ardiansyah; El Amin, Mohamed; Sun, Shuyu

    2015-10-01

    In this work the problem related to the transport of nanoparticles in anisotropic porous media is investigated numerically using the multipoint flux approximation. Anisotropy of porous media properties is an essential feature that exists almost everywhere in subsurface formations. In anisotropic media, the flux and the pressure gradient vectors are no longer collinear and therefore interesting patterns emerge. The transport of nanoparticles in subsurface formations is affected by several complex processes including surface charges, heterogeneity of nanoparticles and soil grain collectors, interfacial dynamics of double-layer and many others. We use the framework of the theory of filtration in this investigation. Processes like particles deposition, entrapment, as well as detachment are accounted for. From the numerical methods point of view, traditional two-point flux finite difference approximation cannot handle anisotropy of media properties. Therefore, in this work we use the multipoint flux approximation (MPFA). In this technique, the flux components are affected by more neighboring points as opposed to the mere two points that are usually used in traditional finite volume methods. We also use the experimenting pressure field approach which automatically constructs the global system of equations by solving multitude of local problems. This approach facilitates to a large extent the construction of the global system. A set of numerical examples is considered involving two-dimensional rectangular domain. A source of nanoparticles is inserted in the middle of the anisotropic layer. We investigate the effects of both anisotropy angle and anisotropy ratio on the transport of nanoparticles in saturated porous media. It is found that the concentration plume and porosity contours follow closely the principal direction of anisotropy of permeability of the central domain.

  7. Numerical investigation of nanoparticles transport in anisotropic porous media.

    PubMed

    Salama, Amgad; Negara, Ardiansyah; El Amin, Mohamed; Sun, Shuyu

    2015-10-01

    In this work the problem related to the transport of nanoparticles in anisotropic porous media is investigated numerically using the multipoint flux approximation. Anisotropy of porous media properties is an essential feature that exists almost everywhere in subsurface formations. In anisotropic media, the flux and the pressure gradient vectors are no longer collinear and therefore interesting patterns emerge. The transport of nanoparticles in subsurface formations is affected by several complex processes including surface charges, heterogeneity of nanoparticles and soil grain collectors, interfacial dynamics of double-layer and many others. We use the framework of the theory of filtration in this investigation. Processes like particles deposition, entrapment, as well as detachment are accounted for. From the numerical methods point of view, traditional two-point flux finite difference approximation cannot handle anisotropy of media properties. Therefore, in this work we use the multipoint flux approximation (MPFA). In this technique, the flux components are affected by more neighboring points as opposed to the mere two points that are usually used in traditional finite volume methods. We also use the experimenting pressure field approach which automatically constructs the global system of equations by solving multitude of local problems. This approach facilitates to a large extent the construction of the global system. A set of numerical examples is considered involving two-dimensional rectangular domain. A source of nanoparticles is inserted in the middle of the anisotropic layer. We investigate the effects of both anisotropy angle and anisotropy ratio on the transport of nanoparticles in saturated porous media. It is found that the concentration plume and porosity contours follow closely the principal direction of anisotropy of permeability of the central domain. PMID:26212784

  8. Fabric dependence of quasi-waves in anisotropic porous media

    PubMed Central

    Cardoso, Luis; Cowin, Stephen C.

    2011-01-01

    Assessment of bone loss and osteoporosis by ultrasound systems is based on the speed of sound and broadband ultrasound attenuation of a single wave. However, the existence of a second wave in cancellous bone has been reported and its existence is an unequivocal signature of poroelastic media. To account for the fact that ultrasound is sensitive to microarchitecture as well as bone mineral density (BMD), a fabric-dependent anisotropic poroelastic wave propagation theory was recently developed for pure wave modes propagating along a plane of symmetry in an anisotropic medium. Key to this development was the inclusion of the fabric tensor—a quantitative stereological measure of the degree of structural anisotropy of bone—into the linear poroelasticity theory. In the present study, this framework is extended to the propagation of mixed wave modes along an arbitrary direction in anisotropic porous media called quasi-waves. It was found that differences between phase and group velocities are due to the anisotropy of the bone microarchitecture, and that the experimental wave velocities are more accurately predicted by the poroelastic model when the fabric tensor variable is taken into account. This poroelastic wave propagation theory represents an alternative for bone quality assessment beyond BMD. PMID:21568431

  9. Fabric dependence of quasi-waves in anisotropic porous media.

    PubMed

    Cardoso, Luis; Cowin, Stephen C

    2011-05-01

    Assessment of bone loss and osteoporosis by ultrasound systems is based on the speed of sound and broadband ultrasound attenuation of a single wave. However, the existence of a second wave in cancellous bone has been reported and its existence is an unequivocal signature of poroelastic media. To account for the fact that ultrasound is sensitive to microarchitecture as well as bone mineral density (BMD), a fabric-dependent anisotropic poroelastic wave propagation theory was recently developed for pure wave modes propagating along a plane of symmetry in an anisotropic medium. Key to this development was the inclusion of the fabric tensor--a quantitative stereological measure of the degree of structural anisotropy of bone--into the linear poroelasticity theory. In the present study, this framework is extended to the propagation of mixed wave modes along an arbitrary direction in anisotropic porous media called quasi-waves. It was found that differences between phase and group velocities are due to the anisotropy of the bone microarchitecture, and that the experimental wave velocities are more accurately predicted by the poroelastic model when the fabric tensor variable is taken into account. This poroelastic wave propagation theory represents an alternative for bone quality assessment beyond BMD.

  10. Frequency-dependent processing and interpretation (FDPI) of seismic data for identifying, imaging and monitoring fluid-saturated underground reservoirs

    DOEpatents

    Goloshubin, Gennady M.; Korneev, Valeri A.

    2005-09-06

    A method for identifying, imaging and monitoring dry or fluid-saturated underground reservoirs using seismic waves reflected from target porous or fractured layers is set forth. Seismic imaging the porous or fractured layer occurs by low pass filtering of the windowed reflections from the target porous or fractured layers leaving frequencies below low-most corner (or full width at half maximum) of a recorded frequency spectra. Additionally, the ratio of image amplitudes is shown to be approximately proportional to reservoir permeability, viscosity of fluid, and the fluid saturation of the porous or fractured layers.

  11. Frequency-dependent processing and interpretation (FDPI) of seismic data for identifying, imaging and monitoring fluid-saturated underground reservoirs

    DOEpatents

    Goloshubin, Gennady M.; Korneev, Valeri A.

    2006-11-14

    A method for identifying, imaging and monitoring dry or fluid-saturated underground reservoirs using seismic waves reflected from target porous or fractured layers is set forth. Seismic imaging the porous or fractured layer occurs by low pass filtering of the windowed reflections from the target porous or fractured layers leaving frequencies below low-most corner (or full width at half maximum) of a recorded frequency spectra. Additionally, the ratio of image amplitudes is shown to be approximately proportional to reservoir permeability, viscosity of fluid, and the fluid saturation of the porous or fractured layers.

  12. Birefringence and anisotropic optical absorption in porous silicon

    SciTech Connect

    Efimova, A. I. Krutkova, E. Yu.; Golovan', L. A.; Fomenko, M. A.; Kashkarov, P. K.; Timoshenko, V. Yu.

    2007-10-15

    The refractive indices and the coefficients of optical absorption by free charge carriers and local vibrations in porous silicon (por-Si) films, comprising nanometer-sized silicon residues (nanocrystals) separated by nanometer-sized pores (nanopores) formed in the course of electrochemical etching of the initial single crystal silicon, have been studied by polarization-resolved IR absorption spectroscopy techniques. It is shown that the birefringence observed in por-Si is related to the anisotropic shapes of nanocrystals and nanopores, while the anisotropy (dichroism) of absorption by the local vibrational modes is determined predominantly by the microrelief of the surface of nanocrystals. It is demonstrated that silicon-hydrogen surface bonds in nanocrystals can be restored by means of selective hydrogen thermodesorption with the formation of a considerable number of H-terminated surface Si-Si dimers.

  13. Stability of Poiseuille flow in a fluid overlying an anisotropic and inhomogeneous porous layer

    NASA Astrophysics Data System (ADS)

    Deepu, P.; Anand, Prateek; Basu, Saptarshi

    2015-08-01

    We present the linear stability analysis of horizontal Poiseuille flow in a fluid overlying a porous medium with anisotropic and inhomogeneous permeability. The generalized Darcy model is used to describe the flow in the porous medium with the Beavers-Joseph condition at the interface of the two layers and the eigenvalue problem is solved numerically. The effect of major system parameters on the stability characteristics is addressed in detail. It is shown that the anisotropic and inhomogeneous modulation of the permeability of the underlying porous layer provides an effective means for passive control of the flow stability.

  14. Elastic and inelastic deformation of fluid-saturated rock.

    PubMed

    Makhnenko, Roman Y; Labuz, Joseph F

    2016-10-13

    In situ rock is often saturated with fluid, the presence of which affects both elastic parameters and inelastic deformation processes. Techniques were developed for testing fluid-saturated porous rock under the limiting conditions of drained (long-term), undrained (short-term) and unjacketed (solid matrix) response in hydrostatic, axisymmetric and plane-strain compression. Drained and undrained poroelastic parameters, including bulk modulus, Biot and Skempton coefficients, of Berea sandstone were found to be stress dependent up to 35 MPa mean stress, and approximately constant at higher levels of loading. The unjacketed bulk modulus was measured to be constant for pressure up to 60 MPa, and it appears to be larger than the unjacketed pore bulk modulus. An elasto-plastic constitutive model calibrated with parameters from drained tests provided a first-order approximation of undrained inelastic deformation: dilatant hardening was observed due to pore pressure decrease during inelastic deformation of rock specimens with constant fluid content.This article is part of the themed issue 'Energy and the subsurface'.

  15. Elastic and inelastic deformation of fluid-saturated rock.

    PubMed

    Makhnenko, Roman Y; Labuz, Joseph F

    2016-10-13

    In situ rock is often saturated with fluid, the presence of which affects both elastic parameters and inelastic deformation processes. Techniques were developed for testing fluid-saturated porous rock under the limiting conditions of drained (long-term), undrained (short-term) and unjacketed (solid matrix) response in hydrostatic, axisymmetric and plane-strain compression. Drained and undrained poroelastic parameters, including bulk modulus, Biot and Skempton coefficients, of Berea sandstone were found to be stress dependent up to 35 MPa mean stress, and approximately constant at higher levels of loading. The unjacketed bulk modulus was measured to be constant for pressure up to 60 MPa, and it appears to be larger than the unjacketed pore bulk modulus. An elasto-plastic constitutive model calibrated with parameters from drained tests provided a first-order approximation of undrained inelastic deformation: dilatant hardening was observed due to pore pressure decrease during inelastic deformation of rock specimens with constant fluid content.This article is part of the themed issue 'Energy and the subsurface'. PMID:27597783

  16. Liquid film condensation along a vertical surface in a thin porous medium with large anisotropic permeability.

    PubMed

    Sanya, Arthur S O; Akowanou, Christian; Sanya, Emile A; Degan, Gerard

    2014-01-01

    The problems of steady film condensation on a vertical surface embedded in a thin porous medium with anisotropic permeability filled with pure saturated vapour are studied analytically by using the Brinkman-Darcy flow model. The principal axes of anisotropic permeability are oriented in a direction that non-coincident with the gravity force. On the basis of the flow permeability tensor due to the anisotropic properties and the Brinkman-Darcy flow model adopted by considering negligible macroscopic and microscopic inertial terms, boundary-layer approximations in the porous liquid film momentum equation is solved analytically. Scale analysis is applied to predict the order-of-magnitudes involved in the boundary layer regime. The first novel contribution in the mathematics consists in the use of the anisotropic permeability tensor inside the expression of the mathematical formulation of the film condensation problem along a vertical surface embedded in a porous medium. The present analytical study reveals that the anisotropic permeability properties have a strong influence on the liquid film thickness, condensate mass flow rate and surface heat transfer rate. The comparison between thin and thick porous media is also presented. PMID:26034679

  17. In-situ ellipsometric characterization of the growth of porous anisotropic nanocrystalline ZnO layers

    SciTech Connect

    Laha, P. Terryn, H.; Ustarroz, J.; Nazarkin, M. Y. Gavrilov, S. A.; Volkova, A. V.; Simunin, M. M.

    2015-03-09

    ZnO films have increasingly been in the spotlight due to their largely varied electro-physical and optical properties. For several applications, porous anisotropic nanocrystalline layers are especially interesting. To study the growth kinetics of such films during different fabrication processes, a powerful non-destructive in-situ technique is required. In this work, both ex-situ and in-situ spectroscopic ellipsometry are used along with advanced modelling techniques that are able to take both the anisotropy and the porosity of the films into account. Scanning electron microscopy, along with nitrogen absorption methods for measuring porosity, validated the ellipsometric data and proposed model. The film, grown by chemical bath deposition, was monitored from around 700 to 1800 nm in thickness. This same principle can now be used to monitor any other porous and/or anisotropic structure in an effective in-situ manner, e.g., growth of porous anodic aluminium oxides, nano-porous silica films, etc.

  18. Fabrication, pore structure and compressive behavior of anisotropic porous titanium for human trabecular bone implant applications.

    PubMed

    Li, Fuping; Li, Jinshan; Xu, Guangsheng; Liu, Gejun; Kou, Hongchao; Zhou, Lian

    2015-06-01

    Porous titanium with average pore size of 100-650 μm and porosity of 30-70% was fabricated by diffusion bonding of titanium meshes. Pore structure was characterized by Micro-CT scan and SEM. Compressive behavior of porous titanium in the out-of-plane direction was studied. The effect of porosity and pore size on the compressive properties was also discussed based on the deformation mode. The results reveal that the fabrication process can control the porosity precisely. The average pore size of porous titanium can be tailored by adjusting the pore size of titanium meshes. The fabricated porous titanium possesses an anisotropic structure with square pores in the in-plane direction and elongated pores in the out-of-plane direction. The compressive Young's modulus and yield stress are in the range of 1-7.5 GPa and 10-110 MPa, respectively. The dominant compressive deformation mode is buckling of mesh wires, but some uncoordinated buckling is present in porous titanium with lower porosity. Relationship between compressive properties and porosity conforms well to the Gibson-Ashby model. The effect of pore size on compressive properties is fundamentally ascribed to the aspect ratio of titanium meshes. Porous titanium with 60-70% porosity has potential for trabecular bone implant applications.

  19. Imaging fluid saturation development in long-core flood displacements

    SciTech Connect

    Grave, A.; Kolitvelt, K.; Lien, J.R.; Skauge, A. )

    1990-12-01

    Fluid saturation development in long-core flood experiments is investigated. Information on 1D fluid saturation distributions is obtained by labeling the fluid phases with nuclear tracers and detecting radiation with a movable detector. Various flood experiments were done on 2.5-ft (76-cm)-long sandstone cores. In miscible displacements where radioactive brine is displacing inactive brine, dispersion and ion adsorption are evaluated. Imaging saturation profiles during drainages and waterfloods gives information on saturation front velocity and time development of local saturation variations. Experimental results are compared with numerical results from a 1D front-tracking black-oil simulator that incorporated inhomogeneities and capillary effects. Surfactant floods were investigated to test the applicability for EOR studies.

  20. Method of determining interwell oil field fluid saturation distribution

    DOEpatents

    Donaldson, Erle C.; Sutterfield, F. Dexter

    1981-01-01

    A method of determining the oil and brine saturation distribution in an oil field by taking electrical current and potential measurements among a plurality of open-hole wells geometrically distributed throughout the oil field. Poisson's equation is utilized to develop fluid saturation distributions from the electrical current and potential measurement. Both signal generating equipment and chemical means are used to develop current flow among the several open-hole wells.

  1. Initiation of acoustic emission in fluid-saturated sandstone samples

    NASA Astrophysics Data System (ADS)

    Lapshin, V. B.; Patonin, A. V.; Ponomarev, A. V.; Potanina, M. G.; Smirnov, V. B.; Stroganova, S. M.

    2016-07-01

    A rock behavior experiment with uniaxial compression revealed the effect of acoustic activity in loaded fluid-saturated Berea sandstone samples in response to an electric current. It is established that it is substantially intensified in periods of the current impact and decreases after its cut-off. The current impact also results in a growth of radial deformation indicating an increase in the sample volume. The effect of acoustic activation increases in response to increased heat emitted by the electric current during its flow through the sample, which allows the discovered effect to be explained by initiation of its destruction due to thermal expansion of the fluid in rock interstices and fissures.

  2. Laminar film condensation along a vertical plate embedded in an anisotropic porous medium with oblique principal axes

    NASA Astrophysics Data System (ADS)

    Degan, Gérard; Sanya, Arthur; Akowanou, Christian

    2016-10-01

    This work analytically investigates the problem of steady film condensation along a vertical surface embedded in an anisotropic porous medium filled with a dry saturated vapor. The porous medium is anisotropic in permeability whose principal axes are oriented in a direction which is oblique to the gravity vector. On the basis of the generalized Darcy's law and within the boundary layer approximations, similar solutions have been obtained for the temperature and flow patterns in the condensate. Moreover, closed form solutions for the boundary layer thickness and heat transfer rate have been obtained in terms of the governing parameters of the problem.

  3. Investigation of low field dielectric properties of anisotropic porous Pb(Zr,Ti)O3 ceramics: Experiment and modeling

    NASA Astrophysics Data System (ADS)

    Olariu, C. S.; Padurariu, L.; Stanculescu, R.; Baldisserri, C.; Galassi, C.; Mitoseriu, L.

    2013-12-01

    Anisotropic porous Pb(Zr,Ti)O3 ceramics with various porosity degrees have been studied in order to determine the role of the pore shape and orientation on the low-field dielectric properties. Ceramic samples with formula Pb(Zr0.52Ti0.48)0.976Nb0.024O3 with different porosity degrees (dense, 10%, 20%, 40% vol.) have been prepared by solid state reaction. Taking into consideration the shape and orientation of the pore inclusions, the dielectric properties of porous ceramics have been described by using adapted mixing rules models. Rigorous bounds, derived on the basis on Variational Principle, were used to frame dielectric properties of porous composites. The finite element method (FEM) was additionally used to simulate the dielectric response of the porous composites under various applied fields. Among the few effective medium approximation models adapted for anisotropic oriented inclusions, the best results were obtained in case of needle-like shape inclusions (which do not correspond to the real shape of microstructure inclusions). The general case of Wiener bounds limited well the dielectric properties of anisotropic porous composites in case of parallel orientation. Among the theoretical approaches, FEM technique allowed to simulate the distribution of potential and electric field inside composites and provided a very good agreement between the computed permittivity values and experimental ones.

  4. Calibration of Gurson-type models for porous sheet metals with anisotropic non-quadratic plasticity

    NASA Astrophysics Data System (ADS)

    Gologanu, M.; Kami, A.; Comsa, D. S.; Banabic, D.

    2016-08-01

    The growth and coalescence of voids in sheet metals are not only the main active mechanisms in the final stages of fracture in a necking band, but they also contribute to the forming limits via changes in the normal directions to the yield surface. A widely accepted method to include void effects is the development of a Gurson-type model for the appropriate yield criterion, based on an approximate limit analysis of a unit cell containing a single spherical, spheroidal or ellipsoidal void. We have recently [2] obtained dissipation functions and Gurson-type models for porous sheet metals with ellipsoidal voids and anisotropic non-quadratic plasticity, including yield criteria based on linear transformations (Yld91 and Yld2004-18p) and a pure plane stress yield criteria (BBC2005). These Gurson-type models contain several parameters that depend on the void and cell geometries and on the selected yield criterion. Best results are obtained when these key parameters are calibrated via numerical simulations using the same unit cell and a few representative loading conditions. The single most important such loading condition corresponds to a pure hydrostatic macroscopic stress (pure pressure) and the corresponding velocity field found during the solution of the limit analysis problem describes the expansion of the cavity. However, for the case of sheet metals, the condition of plane stress precludes macroscopic stresses with large triaxiality or ratio of mean stress to equivalent stress, including the pure hydrostatic case. Also, pure plane stress yield criteria like BBC2005 must first be extended to 3D stresses before attempting to develop a Gurson-type model and such extensions are purely phenomenological with no due account for the out- of-plane anisotropic properties of the sheet. Therefore, we propose a new calibration method for Gurson- type models that uses only boundary conditions compatible with the plane stress requirement. For each such boundary condition we use

  5. Description of a Furnace for the Creation of Anisotropic Porous Metals

    SciTech Connect

    Gutsch, Thomas; Miszkiel, Mark; Schmale, David T.

    1999-05-01

    A furnace has been built for the purpose of producing anisotropic porous metals through solid-gas eutectic solidification. This process allows control of continuously formed anisotropic pores in metals and was discovered at the State Metallurgical Academic' University in Dnepropetrovsk Ukraine. The process incorporates hydrogen gas within the metal as it solidifies from the molten state. Metals which do not form hydrides, including iron, nickel, aluminum, copper and others can be formed in this manner. The furnace is housed within a ~.64 meter³ (30 ft³) ASME code stamped cylindrical stainless steel vacuum/pressure vessel. The vessel is a water chilled vertical cylinder with removable covers at the top and bottom. It can be evacuated to 20 mTorr or pressurized to 5.5 MPa (800 psi). A charge of 2700 cc (167 in³) of molten metal can be melted in a crucible in the upper portion within a watercooled 30 cm (12 in.) ID induction coil. A 175 kW Inductotherm power source energizes the coil. Vertical actuation of a ceramic stopper rod allows the molten metal to be tapped into a solidification mold beneath the melting crucible. The cylindrical mold rests on a water cooled copper base inducing directional solidification from the bottom. Mixtures of hydrogen and argon gases are introduced during the process. The system is remotely controlled and located in a structure with frangible walls specially designed for possible ambient pressure excursions as a result of equipment failure. This paper includes a general description of the furnace and operating procedure and a detailed description of the control, monitoring and interlock systems.

  6. Growth Assisted by Glancing Angle Deposition: A New Technique to Fabricate Highly Porous Anisotropic Thin Films.

    PubMed

    Sanchez-Valencia, Juan Ramon; Longtin, Remi; Rossell, Marta D; Gröning, Pierangelo

    2016-04-01

    We report a new methodology based on glancing angle deposition (GLAD) of an organic molecule in combination with perpendicular growth of a second inorganic material. The resulting thin films retain a very well-defined tilted columnar microstructure characteristic of GLAD with the inorganic material embedded inside the columns. We refer to this new methodology as growth assisted by glancing angle deposition or GAGLAD, since the material of interest (here, the inorganic) grows in the form of tilted columns, though it is deposited under a nonglancing configuration. As a "proof of concept", we have used silver and zinc oxide as the perpendicularly deposited material since they usually form ill-defined columnar microstructures at room temperature by GLAD. By means of our GAGLAD methodology, the typical tilted columnar microstructure can be developed for materials that otherwise do not form ordered structures under conventional GLAD. This simple methodology broadens significantly the range of materials where control of the microstructure can be achieved by tuning the geometrical deposition parameters. The two examples presented here, Ag/Alq3 and ZnO/Alq3, have been deposited by physical vapor deposition (PVD) and plasma enhanced chemical vapor deposition (PECVD), respectively: two different vacuum techniques that illustrate the generality of the proposed technique. The two type of hybrid samples present very interesting properties that demonstrate the potentiality of GAGLAD. On one hand, the Ag/Alq3 samples present highly optical anisotropic properties when they are analyzed with linearly polarized light. To our knowledge, these Ag/Alq3 samples present the highest angular selectivity reported in the visible range. On the other hand, ZnO/Alq3 samples are used to develop highly porous ZnO thin films by using Alq3 as sacrificial material. In this way, antireflective ZnO samples with very low refractive index and extinction coefficient have been obtained. PMID:26954074

  7. Growth Assisted by Glancing Angle Deposition: A New Technique to Fabricate Highly Porous Anisotropic Thin Films.

    PubMed

    Sanchez-Valencia, Juan Ramon; Longtin, Remi; Rossell, Marta D; Gröning, Pierangelo

    2016-04-01

    We report a new methodology based on glancing angle deposition (GLAD) of an organic molecule in combination with perpendicular growth of a second inorganic material. The resulting thin films retain a very well-defined tilted columnar microstructure characteristic of GLAD with the inorganic material embedded inside the columns. We refer to this new methodology as growth assisted by glancing angle deposition or GAGLAD, since the material of interest (here, the inorganic) grows in the form of tilted columns, though it is deposited under a nonglancing configuration. As a "proof of concept", we have used silver and zinc oxide as the perpendicularly deposited material since they usually form ill-defined columnar microstructures at room temperature by GLAD. By means of our GAGLAD methodology, the typical tilted columnar microstructure can be developed for materials that otherwise do not form ordered structures under conventional GLAD. This simple methodology broadens significantly the range of materials where control of the microstructure can be achieved by tuning the geometrical deposition parameters. The two examples presented here, Ag/Alq3 and ZnO/Alq3, have been deposited by physical vapor deposition (PVD) and plasma enhanced chemical vapor deposition (PECVD), respectively: two different vacuum techniques that illustrate the generality of the proposed technique. The two type of hybrid samples present very interesting properties that demonstrate the potentiality of GAGLAD. On one hand, the Ag/Alq3 samples present highly optical anisotropic properties when they are analyzed with linearly polarized light. To our knowledge, these Ag/Alq3 samples present the highest angular selectivity reported in the visible range. On the other hand, ZnO/Alq3 samples are used to develop highly porous ZnO thin films by using Alq3 as sacrificial material. In this way, antireflective ZnO samples with very low refractive index and extinction coefficient have been obtained.

  8. Streamline Simulation of a Two-Phase Flow in Heterogeneous and Anisotropic Porous Media

    NASA Astrophysics Data System (ADS)

    Cervantes, D.; Salazar, A.; de la Cruz, L.

    2013-05-01

    numerical errors on the solution. The domain of study is a heterogeneous and anisotropic porous media, with several distributions of injector and producer wells. [1] Muskat, M. and Wyckoff, R.: "Theoretical Analysis of Waterfooding Networks," Trans. AIME (1934) 107, 62-77.

  9. Measurements of ultrasound velocity and attenuation in numerical anisotropic porous media compared to Biot's and multiple scattering models.

    PubMed

    Mézière, Fabien; Muller, Marie; Bossy, Emmanuel; Derode, Arnaud

    2014-07-01

    This article quantitatively investigates ultrasound propagation in numerical anisotropic porous media with finite-difference simulations in 3D. The propagation media consist of clusters of ellipsoidal scatterers randomly distributed in water, mimicking the anisotropic structure of cancellous bone. Velocities and attenuation coefficients of the ensemble-averaged transmitted wave (also known as the coherent wave) are measured in various configurations. As in real cancellous bone, one or two longitudinal modes emerge, depending on the micro-structure. The results are confronted with two standard theoretical approaches: Biot's theory, usually invoked in porous media, and the Independent Scattering Approximation (ISA), a classical first-order approach of multiple scattering theory. On the one hand, when only one longitudinal wave is observed, it is found that at porosities higher than 90% the ISA successfully predicts the attenuation coefficient (unlike Biot's theory), as well as the existence of negative dispersion. On the other hand, the ISA is not well suited to study two-wave propagation, unlike Biot's model, at least as far as wave speeds are concerned. No free fitting parameters were used for the application of Biot's theory. Finally we investigate the phase-shift between waves in the fluid and the solid structure, and compare them to Biot's predictions of in-phase and out-of-phase motions.

  10. Inverse estimation of the elastic and anelastic properties of the porous frame of anisotropic open-cell foams.

    PubMed

    Cuenca, Jacques; Göransson, Peter

    2012-08-01

    This paper presents a method for simultaneously identifying both the elastic and anelastic properties of the porous frame of anisotropic open-cell foams. The approach is based on an inverse estimation procedure of the complex stiffness matrix of the frame by performing a model fit of a set of transfer functions of a sample of material subjected to compression excitation in vacuo. The material elastic properties are assumed to have orthotropic symmetry and the anelastic properties are described using a fractional-derivative model within the framework of an augmented Hooke's law. The inverse estimation problem is formulated as a numerical optimization procedure and solved using the globally convergent method of moving asymptotes. To show the feasibility of the approach a numerically generated target material is used here as a benchmark. It is shown that the method provides the full frequency-dependent orthotropic complex stiffness matrix within a reasonable degree of accuracy.

  11. Imaging of multiphase fluid saturation within a porous material via sodium NMR.

    PubMed

    Washburn, Kathryn E; Madelin, Guillaume

    2010-01-01

    We present in this paper a method to monitor multiphase fluid core saturation through measurement of the sodium NMR signal. In a rock core saturated with water and oil, sodium will be present only in the water phase, and therefore can be used to separate the two fluids. Two dimensional sodium images were taken to monitor the movement of brine into oil saturated rock cores. The measured fluid exchange agrees well with expected behavior from traditional core analysis methods. Indications of damage to the rock structure can be seen from the patterns of fluid imbibition. PMID:19864169

  12. Evidence of anisotropic quenched disorder effects on a smectic liquid crystal confined in porous silicon

    SciTech Connect

    Guegan, Regis; Morineau, Denis; Loverdo, Claude; Beziel, Wilfried; Guendouz, Mohammed

    2006-01-15

    We present a neutron scattering analysis of the structure of the smectic liquid crystal octylcyanobiphenyl (8CB) confined in one-dimensional nanopores of porous silicon films (PS). The smectic transition is completely suppressed, leading to the extension of a short-range ordered smectic phase aligned along the pore axis. It evolves reversibly over an extended temperature range, down to 50 K below the N-SmA transition in pure 8CB. This behavior strongly differs from previous observations of smectics in different one-dimensional porous materials. A coherent picture of this striking behavior requires that quenched disorder effects are invoked. The strongly disordered nature of the inner surface of PS acts as random fields coupling to the smectic order. The one-dimensionality of PS nanochannels offers perspectives on quenched disorder effects, of which observation has been restricted to homogeneous random porous materials so far.

  13. Flow and dispersion in anisotropic porous media: A lattice-Boltzmann study

    NASA Astrophysics Data System (ADS)

    Maggiolo, D.; Picano, F.; Guarnieri, M.

    2016-10-01

    Given their capability of spreading active chemical species and collecting electricity, porous media made of carbon fibers are extensively used as diffusion layers in energy storage systems, such as redox flow batteries. In spite of this, the dispersion dynamics of species inside porous media is still not well understood and often lends itself to different interpretations. Actually, the microscopic design of efficient porous media, which can potentially and effectively improve the performances of flow batteries, is still an open challenge. The present study aims to investigate the effect of fibrous media micro-structure on dispersion, in particular the effect of fiber orientation on drag and dispersion dynamics. Several lattice-Boltzmann simulations of flows through differently oriented fibrous media coupled with Lagrangian simulations of particle tracers have been performed. Results show that orienting fibers preferentially along the streamwise direction minimizes the drag and maximizes the dispersion, which is the most desirable condition for diffusion layers in flow batteries' applications.

  14. Superior mechanical performance of highly porous, anisotropic nanocellulose-montmorillonite aerogels prepared by freeze casting.

    PubMed

    Donius, Amalie E; Liu, Andong; Berglund, Lars A; Wegst, Ulrike G K

    2014-09-01

    Directionally solidified nanofibrillated cellulose (NFC)-sodium-montmorillonite (MMT) composite aerogels with a honeycomb-like pore structure were compared with non-directionally frozen aerogels with equiaxed pore structure and identical composition and found to have superior functionalities. To explore structure-property correlations, three different aerogel compositions of 3wt% MMT, and 0.4wt%, 0.8wt%, and 1.2wt% NFC, respectively, were tested. Young׳s modulus, compressive strength and toughness were found to increase with increasing NFC content for both architectures. The modulus increased from 25.8kPa to 386kPa for the isotropic and from 2.13MPa to 3.86MPa for the anisotropic aerogels, the compressive yield strength increased from 3.3kPa to 18.0kPa for the isotropic and from 32.3kPa to 52.5kPa for the anisotropic aerogels, and the toughness increased from 6.3kJ/m(3) to 24.1kJ/m(3) for the isotropic and from 22.9kJ/m(3) to 46.2kJ/m(3) for the anisotropic aerogels. The great range of properties, which can be achieved through compositional as well as architectural variations, makes these aerogels highly attractive for a large range of applications, for which either a specific composition, or a particular pore morphology, or both are required. Finally, because NFC is flammable, gasification experiments were performed, which revealed that the inclusion of MMT increased the heat endurance and shape retention functions of the aerogels dramatically up to 800°C while the mechanical properties were retained up to 300°C. PMID:24905177

  15. Anisotropic magnetic porous assemblies of oxide nanoparticles interconnected via silica bridges for catalytic application.

    PubMed

    Wacker, Josias B; Parashar, Virendra K; Gijs, Martin A M

    2011-04-19

    We report the microfluidic chip-based assembly of colloidal silanol-functionalized silica nanoparticles using monodisperse water-in-oil droplets as templates. The nanoparticles are linked via silica bridges, thereby forming superstructures that range from doublets to porous spherical or rod-like micro-objects. Adding magnetite nanoparticles to the colloid generates micro-objects that can be magnetically manipulated. We functionalized such magnetic porous assemblies with horseradish peroxidase and demonstrate the catalytic binding of fluorescent dye-labeled tyramide over the complete effective surface of the superstructure. Such nanoparticle assemblies permit easy manipulation and recovery after a heterogeneous catalytic process while providing a large surface similar to that of the individual nanoparticles. PMID:21417232

  16. Anisotropic elastic properties of flexible metal-organic frameworks: how soft are soft porous crystals?

    PubMed

    Ortiz, Aurélie U; Boutin, Anne; Fuchs, Alain H; Coudert, François-Xavier

    2012-11-01

    We performed ab initio calculations of the elastic constants of five flexible metal-organic frameworks (MOFs): MIL-53(Al), MIL-53(Ga), MIL-47, and the square and lozenge structures of DMOF-1. Tensorial analysis of the elastic constants reveals a highly anisotropic elastic behavior, some deformation directions exhibiting very low Young's modulus and shear modulus. This anisotropy can reach a 400:1 ratio between the most rigid and weakest directions, in stark contrast to the case of nonflexible MOFs such as MOF-5 and ZIF-8. In addition, we show that flexible MOFs can display extremely large negative linear compressibility. These results uncover the microscopic roots of stimuli-induced structural transitions in flexible MOFs, by linking the local elastic behavior of the material and its multistability. PMID:23215398

  17. Anisotropic Elastic Properties of Flexible Metal-Organic Frameworks: How Soft are Soft Porous Crystals?

    NASA Astrophysics Data System (ADS)

    Ortiz, Aurélie U.; Boutin, Anne; Fuchs, Alain H.; Coudert, François-Xavier

    2012-11-01

    We performed ab initio calculations of the elastic constants of five flexible metal-organic frameworks (MOFs): MIL-53(Al), MIL-53(Ga), MIL-47, and the square and lozenge structures of DMOF-1. Tensorial analysis of the elastic constants reveals a highly anisotropic elastic behavior, some deformation directions exhibiting very low Young’s modulus and shear modulus. This anisotropy can reach a 400∶1 ratio between the most rigid and weakest directions, in stark contrast to the case of nonflexible MOFs such as MOF-5 and ZIF-8. In addition, we show that flexible MOFs can display extremely large negative linear compressibility. These results uncover the microscopic roots of stimuli-induced structural transitions in flexible MOFs, by linking the local elastic behavior of the material and its multistability.

  18. Numerical research on the anisotropic transport of thermal neutron in heterogeneous porous media with micron X-ray computed tomography

    NASA Astrophysics Data System (ADS)

    Wang, Yong; Yue, Wenzheng; Zhang, Mo

    2016-06-01

    The anisotropic transport of thermal neutron in heterogeneous porous media is of great research interests in many fields. In this paper, it is the first time that a new model based on micron X-ray computed tomography (CT) has been proposed to simultaneously consider both the separation of matrix and pore and the distribution of mineral components. We apply the Monte Carlo method to simulate thermal neutrons transporting through the model along different directions, and meanwhile detect those unreacted thermal neutrons by an array detector on the other side of the model. Therefore, the anisotropy of pore structure can be imaged by the amount of received thermal neutrons, due to the difference of rock matrix and pore-filling fluids in the macroscopic reaction cross section (MRCS). The new model has been verified by the consistent between the simulated data and the pore distribution from X-ray CT. The results show that the evaluation of porosity can be affected by the anisotropy of media. Based on the research, a new formula is developed to describe the correlation between the resolution of array detectors and the quality of imaging. The formula can be further used to analyze the critical resolution and the suitable number of thermal neutrons emitted in each simulation. Unconventionally, we find that a higher resolution cannot always lead to a better image.

  19. Numerical research on the anisotropic transport of thermal neutron in heterogeneous porous media with micron X-ray computed tomography.

    PubMed

    Wang, Yong; Yue, Wenzheng; Zhang, Mo

    2016-01-01

    The anisotropic transport of thermal neutron in heterogeneous porous media is of great research interests in many fields. In this paper, it is the first time that a new model based on micron X-ray computed tomography (CT) has been proposed to simultaneously consider both the separation of matrix and pore and the distribution of mineral components. We apply the Monte Carlo method to simulate thermal neutrons transporting through the model along different directions, and meanwhile detect those unreacted thermal neutrons by an array detector on the other side of the model. Therefore, the anisotropy of pore structure can be imaged by the amount of received thermal neutrons, due to the difference of rock matrix and pore-filling fluids in the macroscopic reaction cross section (MRCS). The new model has been verified by the consistent between the simulated data and the pore distribution from X-ray CT. The results show that the evaluation of porosity can be affected by the anisotropy of media. Based on the research, a new formula is developed to describe the correlation between the resolution of array detectors and the quality of imaging. The formula can be further used to analyze the critical resolution and the suitable number of thermal neutrons emitted in each simulation. Unconventionally, we find that a higher resolution cannot always lead to a better image. PMID:27271330

  20. Numerical research on the anisotropic transport of thermal neutron in heterogeneous porous media with micron X-ray computed tomography

    PubMed Central

    Wang, Yong; Yue, Wenzheng; Zhang, Mo

    2016-01-01

    The anisotropic transport of thermal neutron in heterogeneous porous media is of great research interests in many fields. In this paper, it is the first time that a new model based on micron X-ray computed tomography (CT) has been proposed to simultaneously consider both the separation of matrix and pore and the distribution of mineral components. We apply the Monte Carlo method to simulate thermal neutrons transporting through the model along different directions, and meanwhile detect those unreacted thermal neutrons by an array detector on the other side of the model. Therefore, the anisotropy of pore structure can be imaged by the amount of received thermal neutrons, due to the difference of rock matrix and pore-filling fluids in the macroscopic reaction cross section (MRCS). The new model has been verified by the consistent between the simulated data and the pore distribution from X-ray CT. The results show that the evaluation of porosity can be affected by the anisotropy of media. Based on the research, a new formula is developed to describe the correlation between the resolution of array detectors and the quality of imaging. The formula can be further used to analyze the critical resolution and the suitable number of thermal neutrons emitted in each simulation. Unconventionally, we find that a higher resolution cannot always lead to a better image. PMID:27271330

  1. Diffusion ellipsoids of anisotropic porous rocks calculated by X-ray computed tomography-based random walk simulations

    NASA Astrophysics Data System (ADS)

    Nakashima, Yoshito; Kamiya, Susumu; Nakano, Tsukasa

    2008-12-01

    Water molecules and contaminants migrate in water-saturated porous strata by diffusion in systems with small Péclet numbers. Natural porous rocks possess the anisotropy for diffusive transport along the percolated pore space. An X-ray computed tomography (CT) based approach is presented to quickly characterize anisotropic diffusion in porous rocks. High-resolution three-dimensional (3-D) pore images were obtained for a pumice and three sandstones by microfocus X-ray CT and synchrotron microtomography systems. The cluster-labeling process was applied to each image set to extract the 3-D image of a single percolated pore cluster through which diffusing species can migrate a long distance. The nonsorbing lattice random walk simulation was performed on the percolated pore cluster to obtain the mean square displacement. The self-diffusion coefficient along each direction in the 3-D space was calculated by taking the time derivative of the mean square displacement projected on the corresponding direction. A diffusion ellipsoid (i.e., polar representation of the direction-dependent normalized self-diffusivity) with three orthogonal principal axes was obtained for each rock sample. The 3-D two-point autocorrelation was also calculated for the percolated pore cluster of each rock sample to estimate the pore diameter anisotropy. The autocorrelation ellipsoids obtained by the ellipsoid fitting to the high correlation zone were prolate or oblate in shape, presumably depending on the eruption-induced deformation of magma and regional stress during sandstone diagenesis. The pore network anisotropy was estimated by calculating the diffusion ellipsoid for uniaxially elongated or compressed rock images. The degree and direction of the geological deformation of the samples estimated by the pore diameter anisotropy analysis agreed well with those estimated by the pore network anisotropy analysis. We found that the direction of the geological deformation coincided with the direction

  2. An H2O-CO2 mixed fluid saturation model compatible with rhyolite-MELTS

    NASA Astrophysics Data System (ADS)

    Ghiorso, Mark S.; Gualda, Guilherme A. R.

    2015-06-01

    A thermodynamic model for estimating the saturation conditions of H2O-CO2 mixed fluids in multicomponent silicate liquids is described. The model extends the capabilities of rhyolite-MELTS (Gualda et al. in J Petrol 53:875-890, 2012a) and augments the water saturation model in MELTS (Ghiorso and Sack in Contrib Mineral Petrol 119:197-212, 1995). The model is internally consistent with the fluid-phase thermodynamic model of Duan and Zhang (Geochim Cosmochim Acta 70:2311-2324, 2006). It may be used independently of rhyolite-MELTS to estimate intensive variables and fluid saturation conditions from glass inclusions trapped in phenocrysts. The model is calibrated from published experimental data on water and carbon dioxide solubility, and mixed fluid saturation in silicate liquids. The model is constructed on the assumption that water dissolves to form a hydroxyl melt species, and that carbon dioxide both a molecular species and a carbonate ion, the latter complexed with calcium. Excess enthalpy interaction terms in part compensate for these simplistic assumptions regarding speciation. The model is restricted to natural composition liquids over the pressure range 0-3 GPa. One characteristic of the model is that fluid saturation isobars at pressures greater than ~100 MPa always display a maximum in melt CO2 at nonzero H2O melt concentrations, regardless of bulk composition. This feature is universal and can be attributed to the dominance of hydroxyl speciation at low water concentrations. The model is applied to four examples. The first involves estimation of pressures from H2O-CO2-bearing glass inclusions found in quartz phenocrysts of the Bishop Tuff. The second illustrates H2O and CO2 partitioning between melt and fluid during fluid-saturated equilibrium and fractional crystallization of MORB. The third example demonstrates that the position of the quartz-feldspar cotectic surface is insensitive to melt CO2 contents, which facilitates geobarometry using phase

  3. Dynamic bulk and shear moduli due to grain-scale local fluid flow in fluid-saturated cracked poroelastic rocks: Theoretical model

    NASA Astrophysics Data System (ADS)

    Song, Yongjia; Hu, Hengshan; Rudnicki, John W.

    2016-07-01

    Grain-scale local fluid flow is an important loss mechanism for attenuating waves in cracked fluid-saturated poroelastic rocks. In this study, a dynamic elastic modulus model is developed to quantify local flow effect on wave attenuation and velocity dispersion in porous isotropic rocks. The Eshelby transform technique, inclusion-based effective medium model (the Mori-Tanaka scheme), fluid dynamics and mass conservation principle are combined to analyze pore-fluid pressure relaxation and its influences on overall elastic properties. The derivation gives fully analytic, frequency-dependent effective bulk and shear moduli of a fluid-saturated porous rock. It is shown that the derived bulk and shear moduli rigorously satisfy the Biot-Gassmann relationship of poroelasticity in the low-frequency limit, while they are consistent with isolated-pore effective medium theory in the high-frequency limit. In particular, a simplified model is proposed to quantify the squirt-flow dispersion for frequencies lower than stiff-pore relaxation frequency. The main advantage of the proposed model over previous models is its ability to predict the dispersion due to squirt flow between pores and cracks with distributed aspect ratio instead of flow in a simply conceptual double-porosity structure. Independent input parameters include pore aspect ratio distribution, fluid bulk modulus and viscosity, and bulk and shear moduli of the solid grain. Physical assumptions made in this model include (1) pores are inter-connected and (2) crack thickness is smaller than the viscous skin depth. This study is restricted to linear elastic, well-consolidated granular rocks.

  4. Compressive mechanical compatibility of anisotropic porous Ti6Al4V alloys in the range of physiological strain rate for cortical bone implant applications.

    PubMed

    Li, Fuping; Li, Jinshan; Kou, Hongchao; Huang, Tingting; Zhou, Lian

    2015-09-01

    Porous titanium and its alloys are believed to be promising materials for bone implant applications, since they can reduce the "stress shielding" effect by tailoring porosity and improve fixation of implant through bone ingrowth. In the present work, porous Ti6Al4V alloys for biomedical application were fabricated by diffusion bonding of alloy meshes. Compressive mechanical behavior and compatibility in the range of physiological strain rate were studied under quasi-static and dynamic conditions. The results show that porous Ti6Al4V alloys possess anisotropic structure with elongated pores in the out-of-plane direction. For porous Ti6Al4V alloys with 60-70 % porosity, more than 40 % pores are in the range of 200-500 μm which is the optimum pore size suited for bone ingrowth. Quasi-static Young's modulus and yield stress of porous Ti6Al4V alloys with 30-70 % relative density are in the range of 6-40 GPa and 100-500 MPa, respectively. Quasi-static compressive properties can be quantitatively tailored by porosity to match those of cortical bone. Strain rate sensitivity of porous Ti6Al4V alloys is related to porosity. Porous Ti6Al4V alloys with porosity higher than 50 % show enhanced strain rate sensitivity, which is originated from that of base materials and micro-inertia effect. Porous Ti6Al4V alloys with 60-70 % porosity show superior compressive mechanical compatibility in the range of physiological strain rate for cortical bone implant applications.

  5. Effect of irregularity on torsional surface waves in an initially stressed anisotropic porous layer sandwiched between homogeneous and non-homogeneous half-space

    NASA Astrophysics Data System (ADS)

    Saha, Anup; Kundu, Santimoy; Gupta, Shishir; Vaishnav, Pramod Kumar

    2016-06-01

    The present paper is concerned with the propagation of torsional surface waves in an initially stressed anisotropic porous layer sandwiched between homogeneous and non-homogeneous half-space. We assume the quadratic inhomogeneity in rigidity and density in the lower half-space and irregularity is taken in the form of rectangle at the interface separating the layer from the lower half-space. The dispersion equation for torsional waves has been obtained in a closed form. Velocity equation is also obtained in the absence of irregularity. The study reveals that the presence of irregularity, initial stress, porosity, inhomogeneity and anisotropy factor in the dispersion equation approves the significant effect of these parameters in the propagation of torsional waves in porous medium. It has also been observed that for a uniform media, the velocity equation reduces to the classical result of Love wave.

  6. In vivo vascularization of anisotropic channeled porous polylactide-based capsules for islet transplantation: the effects of scaffold architecture and implantation site.

    PubMed

    Kasoju, N; Kubies, D; Fábryová, E; Kříž, J; Kumorek, M M; Sticová, E; Rypáček, F

    2015-01-01

    The replacement of pancreatic islets for the possible treatment of type 1 diabetes is limited by the extremely high oxygen demand of the islets. To this end, here we hypothesize to create a novel extra-hepatic highly-vascularized bioartificial cavity using a porous scaffold as a template and using the host body as a living bioreactor for subsequent islet transplantation. Polylactide-based capsular-shaped anisotropic channeled porous scaffolds were prepared by following the unidirectional thermally-induced phase separation technique, and were implanted under the skin and in the greater omentum of Brown Norway rats. Polyamide mesh-based isotropic regular porous capsules were used as the controls. After 4weeks, the implants were excised and analyzed by histology. The hematoxylin and eosin, as well as Masson's trichrome staining, revealed a) low or no infiltration of giant inflammatory cells in the implant, b) minor but insignificant fibrosis around the implant, c) guided infiltration of host cells in the test capsule in contrast to random cell infiltration in the control capsule, and d) relatively superior cell infiltration in the capsules implanted in the greater omentum than in the capsules implanted under the skin. Furthermore, the anti-CD31 immunohistochemistry staining revealed numerous vessels at the implant site, but mostly on the external surface of the capsules. Taken together, the current study, the first of its kind, is a significant step-forward towards engineering a bioartificial microenvironment for the transplantation of islets. PMID:26447597

  7. Laboratory Measurement of Guided Wave (Krauklis Wave) Propagation Within a Fluid-Saturated Fracture

    NASA Astrophysics Data System (ADS)

    Nakagawa, S.; Korneev, V. A.

    2013-12-01

    A fluid-saturated flat channel between two solid half-spaces (i.e. a fracture) is known to support a guided wave called the Krauklis wave. In the field, this wave can potentially be used to examine the size and connectivity of natural and hydraulically induced fractures from a borehole. Krauklis waves propagate primarily within the fluid part of a fracture, can have very low velocity and large attenuation, and are very dispersive at low frequencies. We conducted laboratory measurements of the velocity of Krauklis waves using analogue fracture models at frequencies below 1 kHz. The models consisted of (1) two concentric aluminum cylinders with a water-filled gap and (2) a pair of rectangular aluminum plates containing a thin water-filled gap (tri-layer mode). In the latter, the water was contained by an o-ring along the edge of the plates. The velocity of the waves propagating within the models was determined both from waveforms in the time domain measured along the wave path and from acoustic resonances in the system. The results indicated that the waves measured from the cylindrical model were not dispersive at frequencies below 400 Hz, with a phase velocity of ~250 m/s. In contrast, the tri-layer model exhibited strongly dispersive velocity at measured frequencies of 7.5 Hz-500 Hz, with the lowest phase velocity being ~14 m/s at 7.5 Hz. These measurements agree well with our theoretical model predictions.

  8. Preparation of asymmetric porous materials

    DOEpatents

    Coker, Eric N.

    2012-08-07

    A method for preparing an asymmetric porous material by depositing a porous material film on a flexible substrate, and applying an anisotropic stress to the porous media on the flexible substrate, where the anisotropic stress results from a stress such as an applied mechanical force, a thermal gradient, and an applied voltage, to form an asymmetric porous material.

  9. Seismic attenuation in fractured porous media: insights from a hybrid numerical and analytical model

    NASA Astrophysics Data System (ADS)

    Ekanem, A. M.; Li, X. Y.; Chapman, M.; Main, I. G.

    2015-04-01

    Seismic attenuation in fluid-saturated porous rocks can occur by geometric spreading, wave scattering or the internal dissipation of energy, most likely due to the squirt-flow mechanism. In principle, the pattern of seismic attenuation recorded on an array of sensors contains information about the medium, in terms of material heterogeneity and anisotropy, as well as material properties such as porosity, crack density, and pore-fluid composition and mobility. In practice, this inverse problem is challenging. Here we provide some insights into the effects of internal dissipation by analysing synthetic data produced by a hybrid numerical and analytical model for seismic wave propagation in a fractured medium embedded within a layered geological structure. The model is made up of one anisotropic and three isotropic horizontal layers. The anisotropic layer consists of a porous, fluid-saturated material containing vertically aligned inclusions representing a set of fractures. This combination allows squirt-flow to occur between the pores in the matrix and the model fractures. Our results show that the fluid mobility and the associated relaxation time of the fluid-pressure gradient control the frequency range over which attenuation occurs. This induced attenuation increases with incidence angle and azimuth away from the fracture strike-direction. Azimuthal variations in the induced attenuation are elliptical allowing the fracture orientations to be obtained from the axes of the ellipse. These observations hold out the potential of using seismic attenuation as an additional diagnostic in the characterisation of rock formations for a variety of applications including hydrocarbon exploration and production, subsurface storage of CO2, and geothermal energy extraction.

  10. Pressure and fluid saturation prediction in a multicomponent reservoir, using combined seismic and electromagnetic imaging

    SciTech Connect

    Hoversten, G.M.; Gritto, Roland; Washbourne, John; Daley, Tom

    2002-06-10

    This paper presents a method for combining seismic and electromagnetic measurements to predict changes in water saturation, pressure, and CO{sub 2} gas/oil ratio in a reservoir undergoing CO{sub 2} flood. Crosswell seismic and electromagnetic data sets taken before and during CO{sub 2} flooding of an oil reservoir are inverted to produce crosswell images of the change in compressional velocity, shear velocity, and electrical conductivity during a CO{sub 2} injection pilot study. A rock properties model is developed using measured log porosity, fluid saturations, pressure, temperature, bulk density, sonic velocity, and electrical conductivity. The parameters of the rock properties model are found by an L1-norm simplex minimization of predicted and observed differences in compressional velocity and density. A separate minimization, using Archie's law, provides parameters for modeling the relations between water saturation, porosity, and the electrical conductivity. The rock-properties model is used to generate relationships between changes in geophysical parameters and changes in reservoir parameters. Electrical conductivity changes are directly mapped to changes in water saturation; estimated changes in water saturation are used along with the observed changes in shear wave velocity to predict changes in reservoir pressure. The estimation of the spatial extent and amount of CO{sub 2} relies on first removing the effects of the water saturation and pressure changes from the observed compressional velocity changes, producing a residual compressional velocity change. This velocity change is then interpreted in terms of increases in the CO{sub 2}/oil ratio. Resulting images of the CO{sub 2}/oil ratio show CO{sub 2}-rich zones that are well correlated to the location of injection perforations, with the size of these zones also correlating to the amount of injected CO{sub 2}. The images produced by this process are better correlated to the location and amount of injected

  11. Pressure diffusion waves in porous media

    SciTech Connect

    Silin, Dmitry; Korneev, Valeri; Goloshubin, Gennady

    2003-04-08

    Pressure diffusion wave in porous rocks are under consideration. The pressure diffusion mechanism can provide an explanation of the high attenuation of low-frequency signals in fluid-saturated rocks. Both single and dual porosity models are considered. In either case, the attenuation coefficient is a function of the frequency.

  12. A note on conservative transport in anisotropic, heterogeneous porous media in the presence of small-amplitude transients

    USGS Publications Warehouse

    Naff, R.L.

    1998-01-01

    The late-time macrodispersion coefficients are obtained for the case of flow in the presence of a small-scale deterministic transient in a three-dimensional anisotropic, heterogeneous medium. The transient is assumed to affect only the velocity component transverse to the mean flow direction and to take the form of a periodic function. For the case of a highly stratified medium, these late-time macrodispersion coefficients behave largely as the standard coefficients used in the transport equation. Only in the event that the medium is isotropic is it probable that significant deviations from the standard coefficients would occur.

  13. Smooth Particle Hydrodynamics with nonlinear Moving-Least-Squares WENO reconstruction to model anisotropic dispersion in porous media

    NASA Astrophysics Data System (ADS)

    Avesani, Diego; Herrera, Paulo; Chiogna, Gabriele; Bellin, Alberto; Dumbser, Michael

    2015-06-01

    Most numerical schemes applied to solve the advection-diffusion equation are affected by numerical diffusion. Moreover, unphysical results, such as oscillations and negative concentrations, may emerge when an anisotropic dispersion tensor is used, which induces even more severe errors in the solution of multispecies reactive transport. To cope with this long standing problem we propose a modified version of the standard Smoothed Particle Hydrodynamics (SPH) method based on a Moving-Least-Squares-Weighted-Essentially-Non-Oscillatory (MLS-WENO) reconstruction of concentrations. This scheme formulation (called MWSPH) approximates the diffusive fluxes with a Rusanov-type Riemann solver based on high order WENO scheme. We compare the standard SPH with the MWSPH for different a few test cases, considering both homogeneous and heterogeneous flow fields and different anisotropic ratios of the dispersion tensor. We show that, MWSPH is stable and accurate and that it reduces the occurrence of negative concentrations compared to standard SPH. When negative concentrations are observed, their absolute values are several orders of magnitude smaller compared to standard SPH. In addition, MWSPH limits spurious oscillations in the numerical solution more effectively than classical SPH. Convergence analysis shows that MWSPH is computationally more demanding than SPH, but with the payoff a more accurate solution, which in addition is less sensitive to particles position. The latter property simplifies the time consuming and often user dependent procedure to define the initial dislocation of the particles.

  14. Effective Hydro-Mechanical Properties of Fluid-Saturated Fracture Networks

    NASA Astrophysics Data System (ADS)

    Pollmann, N.; Vinci, C.; Renner, J.; Steeb, H.

    2015-12-01

    Consideration of hydro-mechanical processes is essential for the characterization of liquid-resources as well as for many engineering applications. Furthermore, the modeling of seismic waves in fractured porous media finds application not only in geophysical exploration but also reservoir management. Fractures exhibit high-aspect-ratio geometries, i.e. they constitute thin and long hydraulic conduits. Motivated by this peculiar geometry, the investigation of the hydro-mechanically coupled processes is performed by means of a hybrid-dimensional modeling approach. The effective material behavior of domains including complex fracture patterns in a porous rock is assessed by investigating the fluid pressure and the solid displacement of the skeleton saturated by compressible fluids. Classical balance equations are combined with a Poiseuille-type flow in the dimensionally reduced fracture. In the porous surrounding rock, the classical Biot-theory is applied. For simple geometries, our findings show that two main fluid-flow processes occur, leak-off from fractures to the surrounding rock and fracture flow within and between the connected fractures. The separation of critical frequencies of the two flow processes is not straightforward, in particular for systems containing a large number of fractures. Our aim is to model three dimensional hydro-mechanically coupled processes within complex fracture patterns and in particular determine the frequency-dependent attenuation characteristics. Furthermore, the effect of asperities of the fracture surfaces on the fracture stiffness and on the hydraulic conductivity will be added to the approach.

  15. Hydrothermal alteration of silicate minerals: effects of crystallographic orientation and fluid saturation state

    NASA Astrophysics Data System (ADS)

    Pollet-Villard, M.; Daval, D.; Saldi, G.; Knauss, K.; Wild, B.; Guyot, F. J.; Cabié, M.; Fritz, B.

    2014-12-01

    Prediction of reaction kinetics of fluid/rock interactions represents a critical issue for several geological and engineering concerns. In the specific context of geothermal energy, the relative intensities of primary mineral leaching and secondary phase formation significantly affect porosity and permeability of the reservoir, thereby influencing its hydraulic performance and the efficiency of a geothermal site. Moreover, it is noteworthy that in general, the circulation of aqueous fluids induces only modest modifications of their chemical composition, which slightly deviate from an equilibrium state. Therefore, fluid rock interactions take place at close-to-equilibrium conditions, where the rate-affinity relations are poorly known and intensively debated [1]. To unravel these points, in the context of the geothermal power station of Soultz-sous-Forêts (Alsace, France), our strategy consists in (1) investigating the dissolution of the main cleavages of K-spar, one of the prevalent primary minerals in the reservoir, in order to decipher the impact of crystallographic orientation and microstructural surface modifications on the dissolution kinetics and (2) proposing a relation between K-spar dissolution rate and the Gibbs free energy of reaction (∆G) over a wide range of ∆G conditions. Our experimental work relies on a coupled approach which combines classical experiments of K-spar dissolution monitored by aqueous chemical analyses (ICPAES) and innovative techniques of nm to μm-scale characterization of solid surface (FIB-TEM, AFM, VSI) [2]. Our ongoing experiments evidence that K-spar dissolution is an anisotropic process, with faces (-1-1 1) dissolving up to ten times faster than the slowest (001) faces. The complex evolution of surface topography with the occurrence of etch pits is at odds with the shrinking core model implemented in most of reactive-transport codes, representing a possible cause of an apparent modification of silicate dissolution rate over

  16. The Materials Chemistry of Atomic Oxygen with Applications to Anisotropic Etching of Submicron Structures in Microelectronics and the Surface Chemistry Engineering of Porous Solids

    NASA Technical Reports Server (NTRS)

    Koontz, Steve L.; Leger, Lubert J.; Wu, Corina; Cross, Jon B.; Jurgensen, Charles W.

    1994-01-01

    Neutral atomic oxygen is the most abundant component of the ionospheric plasma in the low Earth orbit environment (LEO; 200 to 700 kilometers altitude) and can produce significant degradation of some spacecraft materials. In order to produce a more complete understanding of the materials chemistry of atomic oxygen, the chemistry and physics of O-atom interactions with materials were determined in three radically different environments: (1) The Space Shuttle cargo bay in low Earth orbit (the EOIM-3 space flight experiment), (2) a high-velocity neutral atom beam system (HVAB) at Los Alamos National Laboratory (LANL), and (3) a microwave-plasma flowing-discharge system at JSC. The Space Shuttle and the high velocity atom beam systems produce atom-surface collision energies ranging from 0.1 to 7 eV (hyperthermal atoms) under high-vacuum conditions, while the flowing discharge system produces a 0.065 eV surface collision energy at a total pressure of 2 Torr. Data obtained in the three different O-atom environments referred to above show that the rate of O-atom reaction with polymeric materials is strongly dependent on atom kinetic energy, obeying a reactive scattering law which suggests that atom kinetic energy is directly available for overcoming activation barriers in the reaction. General relationships between polymer reactivity with O atoms and polymer composition and molecular structure have been determined. In addition, vacuum ultraviolet photochemical effects have been shown to dominate the reaction of O atoms with fluorocarbon polymers. Finally, studies of the materials chemistry of O atoms have produced results which may be of interest to technologists outside the aerospace industry. Atomic oxygen 'spin-off' or 'dual use' technologies in the areas of anisotropic etching in microelectronic materials and device processing, as well as surface chemistry engineering of porous solid materials are described.

  17. 2D steady-state general solution and fundamental solution for fluid-saturated, orthotropic, poroelastic materials

    NASA Astrophysics Data System (ADS)

    Pan, Li-Hua; Hou, Peng-Fei; Chen, Jia-Yun

    2016-08-01

    The 2D steady-state solutions regarding the expressions of stress and strain for fluid-saturated, orthotropic, poroelastic plane are derived in this paper. For this object, the general solutions of the corresponding governing equation are first obtained and expressed in harmonic functions. Based on these compact general solutions, the suitable harmonic functions with undetermined constants for line fluid source in the interior of infinite poroelastic body and a line fluid source on the surface of semi-infinite poroelastic body are presented, respectively. The fundamental solutions can be obtained by substituting these functions into the general solution, and the undetermined constants can be obtained by the continuous conditions, equilibrium conditions and boundary conditions.

  18. Mixed convection opposing flow in porous annulus

    NASA Astrophysics Data System (ADS)

    Salman, Ahmed N. J.; Kamangar, Sarfaraz; Al-Rashed, Abdullah A. A. A.; Khan, T. M. Yunus; Khaleed, H. M. T.

    2016-06-01

    The current work investigates the mixed convection flow in a vertical porous annulus embedded with fluid saturated porous medium. The annulus is isothermally heated discretely at 20%, 35% and 50% of the height of cylinder at the center of annulus. Darcy law with thermal non-equilibrium approach is considered. The governing partial differential equations are solved using Finite Element Method (FEM). The effects of Peclet number Pe and conductivity ratio Kr on heat transfer and fluid flow is discussed It is found that the applied velocity in the downward direction, in case of an opposing flow, does not allow the thermal energy to reach from a hot to a cold surface.

  19. H2O-fluid-saturated melting of subducted continental crust facilitates exhumation of ultrahigh-pressure rocks in continental subduction zones

    NASA Astrophysics Data System (ADS)

    Labrousse, L.; Duretz, T.; Gerya, T.

    2015-10-01

    We present two-dimensional numerical models of plate subduction and collision inspired by the Scandinavian Caledonian orogeny to investigate the possible impact of continental crust partial melting on the exhumation of ultra-high pressure metamorphic rocks. Three possible reactions were tested: low temperature solidus representing H2O-fluid-saturated partial melting, and two end-member reaction curves for dehydration melting. Thermo-mechanical effects of partial melting were implemented as (1) a viscosity decrease as a determined rheologically critical melt percentage was reached (here 0.1), (2) a change in effective heat capacity and adiabatic heating/cooling accounting for a latent heat term in the heat equation. Among the 3 tested reactions, only H2O-fluid-saturated partial melting drastically modifies the collision dynamics from the non-melting reference model holding all other parameters constant. A substantially low general viscosity truncation (here 1017 Pa s) is needed to properly resolve the effect of partial melting on deep collision processes. Low temperature melting indeed induces the development of a low viscosity buoyant plume prior to slab detachment, where migmatites exhume from UHP conditions at rates and with pressure-temperature paths similar to the natural values acknowledged for the Norwegian Caledonides. High temperature melting has no drastic influence on early collision dynamics. While positive buoyancy remains the first order driver for the exhumation of buried continental rocks, exhumation initiates in these cases with eduction subsequent to slab detachment. Melting and formation of a migmatite plume can later occur along decompression path while continental crust undergoes thermal reequilibration at temperatures above 900 °C. Some of the partially molten material can also relaminate in the overriding plate rather than exhume within the collision zone. Even if minor in terms of amount of magma produced, H2O-fluid-saturated partial melting

  20. A general methodology for inverse estimation of the elastic and anelastic properties of anisotropic open-cell porous materials—with application to a melamine foam

    NASA Astrophysics Data System (ADS)

    Cuenca, Jacques; Van der Kelen, Christophe; Göransson, Peter

    2014-02-01

    This paper proposes an inverse estimation method for the characterisation of the elastic and anelastic properties of the frame of anisotropic open-cell foams used for sound absorption. A model of viscoelasticity based on a fractional differential constitutive equation is used, leading to an augmented Hooke's law in the frequency domain, where the elastic and anelastic phenomena appear as distinctive terms in the stiffness matrix. The parameters of the model are nine orthotropic elastic moduli, three angles of orientation of the material principal directions and three parameters governing the anelastic frequency dependence. The inverse estimation consists in numerically fitting the model on a set of transfer functions extracted from a sample of material. The setup uses a seismic-mass measurement repeated in the three directions of space and is placed in a vacuum chamber in order to remove the air from the pores of the sample. The method allows to reconstruct the full frequency-dependent complex stiffness matrix of the frame of an anisotropic open-cell foam and in particular it provides the frequency of maximum energy dissipation by viscoelastic effects. The characterisation of a melamine foam sample is performed and the relation between the fractional-derivative model and other types of parameterisations of the augmented Hooke's law is discussed.

  1. A general methodology for inverse estimation of the elastic and anelastic properties of anisotropic open-cell porous materials—with application to a melamine foam

    SciTech Connect

    Cuenca, Jacques Van der Kelen, Christophe; Göransson, Peter

    2014-02-28

    This paper proposes an inverse estimation method for the characterisation of the elastic and anelastic properties of the frame of anisotropic open-cell foams used for sound absorption. A model of viscoelasticity based on a fractional differential constitutive equation is used, leading to an augmented Hooke's law in the frequency domain, where the elastic and anelastic phenomena appear as distinctive terms in the stiffness matrix. The parameters of the model are nine orthotropic elastic moduli, three angles of orientation of the material principal directions and three parameters governing the anelastic frequency dependence. The inverse estimation consists in numerically fitting the model on a set of transfer functions extracted from a sample of material. The setup uses a seismic-mass measurement repeated in the three directions of space and is placed in a vacuum chamber in order to remove the air from the pores of the sample. The method allows to reconstruct the full frequency-dependent complex stiffness matrix of the frame of an anisotropic open-cell foam and in particular it provides the frequency of maximum energy dissipation by viscoelastic effects. The characterisation of a melamine foam sample is performed and the relation between the fractional-derivative model and other types of parameterisations of the augmented Hooke's law is discussed.

  2. [Models for quantification of fluid saturation in two-phase flow system by light transmission method and its application].

    PubMed

    Zhang, Yan-Hong; Ye, Shu-Jun; Wu, Ji-Chun

    2014-06-01

    Based on light transmission method in quantification of liquid saturation and its application in two-phase flow system, two groups of sandbox experiments were set up to study the migration of gas or Dense Non-Aqueous Phase Liquids (DNAPLs) in water saturated porous media. The migration of gas or DNAPL was monitored in the study. Two modified Light Intensity-Saturation (LIS) models for water/gas two-phase system were applied and verified by the experiment data. Moreover two new LIS models for NAPL/water system were developed and applied to simulate the DNAPL infiltration experiment data. The gas injection experiment showed that gas moved upward to the top of the sandbox in the form of 'fingering' and finally formed continuous distribution. The results of DNAPL infiltration experiment showed that TCE mainly moved downward as the result of its gravity, eventually formed irregular plume and accumulated at the bottom of the sandbox. The outcomes of two LIS models for water/gas system (WG-A and WG-B) were consistent to the measured data. The results of two LIS models for NAPL/water system (NW-A and NW-B) fit well with the observations, and Model NW-A based on assumption of individual drainage gave better results. It could be a useful reference for quantification of NAPL/water saturation in porous media system.

  3. The diffraction of Rayleigh waves by a fluid-saturated alluvial valley in a poroelastic half-space modeled by MFS

    NASA Astrophysics Data System (ADS)

    Liu, Zhongxian; Liang, Jianwen; Wu, Chengqing

    2016-06-01

    Two dimensional diffraction of Rayleigh waves by a fluid-saturated poroelastic alluvial valley of arbitrary shape in a poroelastic half-space is investigated using the method of fundamental solutions (MFS). To satisfy the free surface boundary conditions exactly, Green's functions of compressional (PI and PII) and shear (SV) wave sources buried in a fluid-saturated poroelastic half-space are adopted. Next, the procedure for solving the scattering wave field is presented. It is verified that the MFS is of excellent accuracy and numerical stability. Numerical results illustrate that the dynamic response strongly depends on such factors as the incident frequency, the porosity of alluvium, the boundary drainage condition, and the valley shape. There is a significant difference between the diffraction of Rayleigh waves for the saturated soil case and for the corresponding dry soil case. The wave focusing effect both on the displacement and pore pressure can be observed inside the alluvial valley and the amplification effect seems most obvious in the case of higher porosity and lower frequency. Additionally, special attention should also be paid to the concentration of pore pressure, which is closely related to the site liquefaction in earthquakes.

  4. Pore Structure Reconstruction and Moisture Migration in Porous Media

    NASA Astrophysics Data System (ADS)

    Zheng, Jiayi; Shi, Xing; Shi, Juan; Chen, Zhenqian

    2014-09-01

    Three kinds of porous media (isotropic, perpendicular anisotropic and parallel anisotropic porous media) with the same porosity, different pore size distributions and fractal spectral dimensions were reconstructed by random growth method. It was aimed to theoretically study the impact of microscopic pore structure on water vapor diffusion process in porous media. The results show that pore size distribution can only denote the static characteristics of porous media but cannot effectively reflect the dynamic transport characteristics of porous media. Fractal spectral dimension can effectively analyze and reflect pores connectivity and moisture dynamic transport properties of porous media from the microscopic perspective. The pores connectivity and water vapor diffusion performance in pores of porous media get better with the increase of fractal spectral dimension of porous media. Fractal spectral dimension of parallel anisotropic porous media is more than that of perpendicular anisotropic porous media. Fractal spectral dimension of isotropic porous media is between parallel anisotropic porous media and perpendicular anisotropic porous media. Other macroscopic parameters such as equilibrium diffusion coefficient of water vapor, water vapor concentration variation at right boundary in equilibrium, the time when water vapor diffusion process reaches a stable state also can characterize the pores connectivity and water vapor diffusion properties of porous media.

  5. Amplitude of Biot's slow wave scattered by a spherical inclusion in a fluid-saturated poroelastic medium

    NASA Astrophysics Data System (ADS)

    Ciz, Radim; Gurevich, Boris

    2005-03-01

    Spatial heterogeneity of hydrocarbon reservoirs causes significant attenuation and dispersion of seismic waves due to wave-induced flow of the pore fluid between more compliant and less compliant areas. This paper investigates the interaction between a plane elastic wave in a poroelastic medium with a spherical inhomogeneity of another porous material. The behaviour of both the inclusion and the background medium is described by the low-frequency variant of Biot's equations of poroelasticity with the standard boundary conditions at the inclusion surface, and for the inclusion size much smaller than the wavelength of the fast compressional wave. The scattering problem is formulated as a series expansion of displacements expressed in the spherical harmonics. The resulting scattered wavefield consists of the scattered normal compressional and shear waves and Biot's slow wave, which attenuates rapidly with distance from the inclusion and represents the main difference from the elastic case. This study concentrates on the attenuation effects caused by the mode conversion into Biot's slow wave. The solution obtained for Biot's slow wave is well described by the two terms of order n= 0 and n= 2 of the scattering series. The scattering amplitude for the term of order n= 0 is given by a simple expression. The full expression for the term of order n= 2 is very complicated, but can be simplified assuming that the amplitude of the scattered fast (normal) compressional and shear waves are well approximated by the solution of the equivalent elastic problem. This assumption yields a simple approximation for the amplitude of the scattered slow wave, which is accurate for a wide range of material properties and is sufficient for the analysis of the scattering amplitude as a function of frequency. In the low-frequency limit the scattering amplitude of the slow wave scales with ω3/2, and reduces to the asymptotic long-wavelength solution of Berryman (1985), which is valid for

  6. Anisotropic universe with anisotropic sources

    SciTech Connect

    Aluri, Pavan K.; Panda, Sukanta; Sharma, Manabendra; Thakur, Snigdha E-mail: sukanta@iiserb.ac.in E-mail: snigdha@iiserb.ac.in

    2013-12-01

    We analyze the state space of a Bianchi-I universe with anisotropic sources. Here we consider an extended state space which includes null geodesics in this background. The evolution equations for all the state observables are derived. Dynamical systems approach is used to study the evolution of these equations. The asymptotic stable fixed points for all the evolution equations are found. We also check our analytic results with numerical analysis of these dynamical equations. The evolution of the state observables are studied both in cosmic time and using a dimensionless time variable. Then we repeat the same analysis with a more realistic scenario, adding the isotropic (dust like dark) matter and a cosmological constant (dark energy) to our anisotropic sources, to study their co-evolution. The universe now approaches a de Sitter space asymptotically dominated by the cosmological constant. The cosmic microwave background anisotropy maps due to shear are also generated in this scenario, assuming that the universe contains anisotropic matter along with the usual (dark) matter and vacuum (dark) energy since decoupling. We find that they contribute dominantly to the CMB quadrupole. We also constrain the current level of anisotropy and also search for any cosmic preferred axis present in the data. We use the Union 2 Supernovae data to this extent. An anisotropy axis close to the mirror symmetry axis seen in the cosmic microwave background data from Planck probe is found.

  7. Mixed convection aiding flow in a vertical porous annulus-two temperature model

    NASA Astrophysics Data System (ADS)

    Salman Ahmed, N. J.; AAAl-Rashed, Abdullah A.; Kamangar, Sarfaraz; Khaleed, H. M. T.; YunusKhan, T. M.; Athani, Abdulgaphur

    2016-09-01

    The effect of convective heat transfer on mixed convection flow in a vertical porous annulus embedded with fluid saturated porous medium for aiding flow is studied. The inner surface of the annular cylinder is heated with constant temperature whereas the outer surface remains at ambient temperature. The governing partial differential equations are solved using Finite Element Method (FEM). It is assumed that the Darcy law is applicable and thermal nonequilibrium TNE exists between solid and fluid phases of porous medium. The aiding flow behavior of heat transfer with respect to Radius ratioRr, Aspect ratio ArandRadiation parameter Rd for different values of Peclet number Peare investigated.

  8. PoreFlow: A complex pore-network model for simulation of reactive transport in variably saturated porous media

    NASA Astrophysics Data System (ADS)

    Raoof, A.; Nick, H. M.; Hassanizadeh, S. M.; Spiers, C. J.

    2013-12-01

    This study introduces PoreFlow, a pore-network modeling tool capable of simulating fluid flow and multi-component reactive and adsorptive transport under saturated and variably saturated conditions. PoreFlow includes a variety of modules, such as: pore network generator, drainage simulator, calculation of pressure and velocity distributions, and modeling of reactive solute transport accounting for advection and diffusion. The pore space is represented using a multi-directional pore-network capable of capturing the random structure of a given porous media with user-defined directional connectivities for anisotropic pore structures. The chemical reactions can occur within the liquid phase, as well as between the liquid and solid phases which may result in an evolution of porosity and permeability. Under variably saturated conditions the area of interfaces changes with degree of the fluid saturation. PoreFlow uses complex formulations for more accurate modeling of transport problems in presence of the nonwetting phase. This is done by refining the discretization within drained pores. An implicit numerical scheme is used to solve the governing equations, and an efficient substitution method is applied to considerably minimize computational times. Several examples are provided, under saturated and variably saturated conditions, to demonstrate the model applicability in hydrogeology problems and petroleum fields. We show that PoreFlow is a powerful tool for upscaling of flow and transport in porous media, utilizing different pore scale information such as various interfaces, phase distributions and local fluxes and concentrations to determine macro scale properties such as average saturation, relative permeability, solute dispersivity, adsorption coefficients, effective diffusion and tortuosity. Such information can be used as constitutive relations within continuum scale governing equations to model physical and chemical processes more accurately at the larger scales.

  9. The response of fluid-saturated reservoirs to lunisolar tides: Part 1. Background parameters of tidal components in ground displacements and groundwater level

    NASA Astrophysics Data System (ADS)

    Besedina, A. N.; Vinogradov, E. A.; Gorbunova, E. M.; Kabychenko, N. V.; Svintsov, I. S.; Pigulevskiy, P. I.; Svistun, V. K.; Shcherbina, S. V.

    2015-01-01

    The first part of this work is dedicated to the response of different-age structures to lunisolar tides, which can be considered as a sounding signal for monitoring the state of fluid-saturated reservoirs. The complex approach to processing the data obtained at the testing sites of the Institute of Geosphere Dynamics of the Russian Academy of Sciences, Institute of Geophysics of the National Academy of Sciences of Ukraine, and KIEV station of the IRIS seismic network is applied for recognizing the tides against the hydrogeological, barometric, and seismic series. The comparative analysis of the experimental and theoretical values of the diurnal and semidiurnal tidal components in the time series of ground displacements is carried out. The tidal variations in the groundwater level are compared with the tidal components revealed in the ground displacement of the different-age structure of the Moscow Basin and Ukrainian Shield, which are parts of the East European artesian region. The differences in the tidal responses of the groundwater level and ground displacement probably suggest that the state of the massif is affected by certain additional factors associated, e.g., with the passage of earthquake-induced seismic waves and the changes in the hydrogeodynamic environment.

  10. Homogenization of two fluid flow in porous media

    PubMed Central

    Daly, K. R.; Roose, T.

    2015-01-01

    The macroscopic behaviour of air and water in porous media is often approximated using Richards' equation for the fluid saturation and pressure. This equation is parametrized by the hydraulic conductivity and water release curve. In this paper, we use homogenization to derive a general model for saturation and pressure in porous media based on an underlying periodic porous structure. Under an appropriate set of assumptions, i.e. constant gas pressure, this model is shown to reduce to the simpler form of Richards' equation. The starting point for this derivation is the Cahn–Hilliard phase field equation coupled with Stokes equations for fluid flow. This approach allows us, for the first time, to rigorously derive the water release curve and hydraulic conductivities through a series of cell problems. The method captures the hysteresis in the water release curve and ties the macroscopic properties of the porous media with the underlying geometrical and material properties. PMID:27547073

  11. Directional wetting in anisotropic inverse opals.

    PubMed

    Phillips, Katherine R; Vogel, Nicolas; Burgess, Ian B; Perry, Carole C; Aizenberg, Joanna

    2014-07-01

    Porous materials display interesting transport phenomena due to restricted motion of fluids within the nano- to microscale voids. Here, we investigate how liquid wetting in highly ordered inverse opals is affected by anisotropy in pore geometry. We compare samples with different degrees of pore asphericity and find different wetting patterns depending on the pore shape. Highly anisotropic structures are infiltrated more easily than their isotropic counterparts. Further, the wetting of anisotropic inverse opals is directional, with liquids filling from the side more easily. This effect is supported by percolation simulations as well as direct observations of wetting using time-resolved optical microscopy. PMID:24941308

  12. Directional wetting in anisotropic inverse opals.

    PubMed

    Phillips, Katherine R; Vogel, Nicolas; Burgess, Ian B; Perry, Carole C; Aizenberg, Joanna

    2014-07-01

    Porous materials display interesting transport phenomena due to restricted motion of fluids within the nano- to microscale voids. Here, we investigate how liquid wetting in highly ordered inverse opals is affected by anisotropy in pore geometry. We compare samples with different degrees of pore asphericity and find different wetting patterns depending on the pore shape. Highly anisotropic structures are infiltrated more easily than their isotropic counterparts. Further, the wetting of anisotropic inverse opals is directional, with liquids filling from the side more easily. This effect is supported by percolation simulations as well as direct observations of wetting using time-resolved optical microscopy.

  13. Form birefringence in porous semiconductors and dielectrics: A review

    SciTech Connect

    Golovan', L. A. Kashkarov, P. K.; Timoshenko, V. Yu.

    2007-07-15

    The phenomenon of optical anisotropy in porous semiconductors and dielectrics (porous silicon, gallium phosphide, and alumina) and photonic crystal structures formed on their basis is reviewed. It is shown that anisotropic nanostructuring of initially isotropic media leads to the occurrence of strong birefringence. Applicability of the effective-medium model to description of the form birefringence in porous semiconductors and dielectrics is discussed.

  14. Effects of Fluid Saturation on Gas Recovery from Class-3 Hydrate Accumulations Using Depressurization: Case Study of Yuan-An Ridge Site in Southwestern Offshore Taiwan

    NASA Astrophysics Data System (ADS)

    Huang, Yi-Jyun; Wu, Cheng-Yueh; Hsieh, Bieng-Zih

    2016-04-01

    Gas hydrates are crystalline compounds in which guest gas molecules are trapped in host lattices of ice crystals. In Taiwan, the significant efforts have recently begun to evaluate the reserves of hydrate because the vast accumulations of gas hydrates had been recognized in southwestern offshore Taiwan. Class-3 type hydrate accumulations are referred to an isolated hydrate layer without an underlying zone of mobile fluids, and the entire hydrate layer may be well within the hydrate stability zone. The depressurization method is a useful dissociation method for gas production from Class-3 hydrate accumulations. The dissociation efficiency is controlled by the responses of hydrate to the propagating pressure disturbance, and the pressure propagation is relating to the amount (or saturation) of the mobile fluid in pore space of the hydrate layer. The purpose of this study is to study the effects of fluid saturation on the gas recovery from a class-3 hydrate accumulation using depressurization method. The case of a class-3 hydrate deposit of Yuan-An Ridge in southwestern offshore Taiwan is studied. The numerical method was used in this study. The reservoir simulator we used to study the dissociation of hydrate and the production of gas was the STARS simulator developed by CMG, which coupled heat transfer, geo-chemical, geo-mechanical, and multiphase fluid flow mechanisms. The study case of Yuan-An Ridge is located in southwestern offshore Taiwan. The hydrate deposit was found by the bottom simulating reflectors (BSRs). The geological structure of the studied hydrate deposit was digitized to build the geological model (grids) of the case. The formation parameters, phase behavior data, rock and fluid properties, and formation's initial conditions were assigned sequentially to grid blocks, and the completion and operation conditions were designed to wellbore blocks to finish the numerical model. The changes of reservoir pressure, temperature, saturation due to the hydrate

  15. Soret and Dufour Effects on MHD Peristaltic Flow of Jeffrey Fluid in a Rotating System with Porous Medium.

    PubMed

    Hayat, Tasawar; Rafiq, Maimona; Ahmad, Bashir

    2016-01-01

    The objective of present paper is to examine the peristaltic flow of magnetohydrodynamic (MHD) Jeffrey fluid saturating porous space in a channel through rotating frame. Unlike the previous attempts, the flow formulation is based upon modified Darcy's law porous medium effect in Jeffrey fluid situation. In addition the impacts due to Soret and Dufour effects in the radiative peristaltic flow are accounted. Rosseland's approximation has been utilized for the thermal radiative heat flux. Lubrication approach is implemented for the simplification. Resulting problems are solved for the stream function, temperature and concentration. Graphical results are prepared and analyzed for different parameters of interest entering into the problems. PMID:26808387

  16. Soret and Dufour Effects on MHD Peristaltic Flow of Jeffrey Fluid in a Rotating System with Porous Medium

    PubMed Central

    Hayat, Tasawar; Rafiq, Maimona; Ahmad, Bashir

    2016-01-01

    The objective of present paper is to examine the peristaltic flow of magnetohydrodynamic (MHD) Jeffrey fluid saturating porous space in a channel through rotating frame. Unlike the previous attempts, the flow formulation is based upon modified Darcy's law porous medium effect in Jeffrey fluid situation. In addition the impacts due to Soret and Dufour effects in the radiative peristaltic flow are accounted. Rosseland’s approximation has been utilized for the thermal radiative heat flux. Lubrication approach is implemented for the simplification. Resulting problems are solved for the stream function, temperature and concentration. Graphical results are prepared and analyzed for different parameters of interest entering into the problems. PMID:26808387

  17. Study on Two-Phase Flow in Heterogeneous Porous Media by Light Transmission Method

    NASA Astrophysics Data System (ADS)

    Qiao, W.

    2015-12-01

    The non-aqueous phase liquid (NAPL) released to the subsurface can form residual ganglia and globules occupying pores and also accumulate and form pools, in which multiphase system forms. Determining transient fluid saturations in a multiphase system is essential to understand the flow characteristics of systems and to perform effective remediation strategies. As a non-destructive and non-invasive laboratory technique utilized for the measurement of liquid saturation in porous media, light transmission is of the lowest cost and safe. Utilization of Coupled Charge Device camera in light transmission systems provides a nearly instantaneous high-density array of spatial measurements over a very large dynamic range. The migration of NAPL and air spariging technique applied to remove NAPL in aquifer systems are typically two-phase flow problem. Because of the natural aquifer normally being heterogeneous, two 2-D sandboxes (Length55cm×width1.3cm×hight45cm) are set up to study the migration of gas and DNAPL in heterogeneous porous media based on light transmission method and its application in two-phase flow. Model D for water/gas system developed by Niemet and Selker (2001) and Model NW-A for water/NAPL system developed by Zhang et al. (2014) are applied for the calculation of fluid saturation in the two experiments, respectively. The gas injection experiments show that the gas moves upward in the irregular channels, piling up beneath the low permeability lenses and starting lateral movement. Bypassing the lenses, the gas moves upward and forms continuous distribution in the top of the sandbox. The faster of gas injects, the wider of gas migration will be. The DNAPL infiltration experiment shows that TCE mainly moves downward as the influence of gravity, stopping vertical infiltration when reaching the low permeability lenses because of its failure to overcome the capillary pressure. Then, TCE accumulates on the surface and starts transverse movement. Bypassing the

  18. Numerical solutions for steady thermal convection from a concentrated source in a porous medium

    SciTech Connect

    Hickox, C.E.; Watts, H.A.

    1980-06-01

    Solutions for the steady, axisymmetric velocity and temperature fields associated with a point source of thermal energy in a fluid-saturated porous medium are obtained numerically through use of similarity transformations. The two cases considered are those of a point source located on the lower, insulated boundary of a semi-infinite region and a point source embedded in an infinite region. Numerical results are presented from which complete descriptions of the velocity and temperature fields can be constructed for Rayleigh numbers ranging from 10/sup -3/ to 10/sup 2/.

  19. Empirical time dependence of liquid self-diffusion coefficient in porous media.

    PubMed

    Loskutov, V V

    2012-03-01

    A new method of finding experimental time dependence of the self-diffusion coefficient D(t) for fluid in the porous media is proposed. We investigate the time-dependent self-diffusion coefficient D(t) of random walkers in permeable porous media. D(t) is measured in pulse field gradient (PFG) experiments with fluid-saturated porous media of randomly packed spherical glass beads. In absence of the specific interactions between pore walls and a fluid we show that D(t) = (D(0) - D(∞))exp(-F√(D(0)t)/d) + D(∞), where D(0) is the diffusion constant in a bulk fluid, D(∞) is the asymptotical value of the diffusion coefficient for long diffusion times (t→∞), d is the bead diameter and F is the constant characterizing the geometry (the size and shape) pores.

  20. A fully coupled porous flow and geomechanics model for fluid driven cracks: a peridynamics approach

    NASA Astrophysics Data System (ADS)

    Ouchi, Hisanao; Katiyar, Amit; York, Jason; Foster, John T.; Sharma, Mukul M.

    2015-03-01

    A state-based non-local peridynamic formulation is presented for simulating fluid driven fractures in an arbitrary heterogeneous poroelastic medium. A recently developed peridynamic formulation of porous flow has been coupled with the existing peridynamic formulation of solid and fracture mechanics resulting in a peridynamic model that for the first time simulates poroelasticity and fluid-driven fracture propagation. This coupling is achieved by modeling the role of pore pressure on the deformation of porous media and vice versa through porosity variation with medium deformation, pore pressure and total mean stress. The poroelastic model is verified by simulating the one-dimensional consolidation of fluid saturated rock. An additional porous flow equation with material permeability dependent on fracture width is solved to simulate fluid flow in the fractured region. Finally, single fluid-driven fracture propagation with a two-dimensional plane strain assumption is simulated and verified against the corresponding classical analytical solution.

  1. Mixed Convection Opposing Flow in a Vertical Porous Annulus-Two Temperature Model

    NASA Astrophysics Data System (ADS)

    Al-Rashed, Abdullah A. AA; J, Salman Ahmed N.; Khaleed, H. M. T.; Yunus Khan, T. M.; NazimAhamed, K. S.

    2016-09-01

    The opposing flow in a porous medium refers to a condition when the forcing velocity flows in opposite direction to thermal buoyancy obstructing the buoyant force. The present research refers to the effect of opposing flow in a vertical porous annulus embedded with fluid saturated porous medium. The thermal non-equilibrium approach with Darcy modal is considered. The boundary conditions are such that the inner radius is heated with constant temperature Tw the outer radius is maintained at constant temperature Tc. The coupled nonlinear partial differential equations such as momentum equation, energy equation for fluid and energy equation for solid are solved using the finite element method. The opposing flow variation of average Nusselt number with respect to radius ratio Rr, Aspect ratioAr and Radiation parameter Rd for different values of Peclet number Pe are investigated. It is found that the flow behavior is quite different from that of aiding flow.

  2. Anisotropic ray trace

    NASA Astrophysics Data System (ADS)

    Lam, Wai Sze Tiffany

    Optical components made of anisotropic materials, such as crystal polarizers and crystal waveplates, are widely used in many complex optical system, such as display systems, microlithography, biomedical imaging and many other optical systems, and induce more complex aberrations than optical components made of isotropic materials. The goal of this dissertation is to accurately simulate the performance of optical systems with anisotropic materials using polarization ray trace. This work extends the polarization ray tracing calculus to incorporate ray tracing through anisotropic materials, including uniaxial, biaxial and optically active materials. The 3D polarization ray tracing calculus is an invaluable tool for analyzing polarization properties of an optical system. The 3x3 polarization ray tracing P matrix developed for anisotropic ray trace assists tracking the 3D polarization transformations along a ray path with series of surfaces in an optical system. To better represent the anisotropic light-matter interactions, the definition of the P matrix is generalized to incorporate not only the polarization change at a refraction/reflection interface, but also the induced optical phase accumulation as light propagates through the anisotropic medium. This enables realistic modeling of crystalline polarization elements, such as crystal waveplates and crystal polarizers. The wavefront and polarization aberrations of these anisotropic components are more complex than those of isotropic optical components and can be evaluated from the resultant P matrix for each eigen-wavefront as well as for the overall image. One incident ray refracting or reflecting into an anisotropic medium produces two eigenpolarizations or eigenmodes propagating in different directions. The associated ray parameters of these modes necessary for the anisotropic ray trace are described in Chapter 2. The algorithms to calculate the P matrix from these ray parameters are described in Chapter 3 for

  3. Speckle reducing anisotropic diffusion.

    PubMed

    Yu, Yongjian; Acton, Scott T

    2002-01-01

    This paper provides the derivation of speckle reducing anisotropic diffusion (SRAD), a diffusion method tailored to ultrasonic and radar imaging applications. SRAD is the edge-sensitive diffusion for speckled images, in the same way that conventional anisotropic diffusion is the edge-sensitive diffusion for images corrupted with additive noise. We first show that the Lee and Frost filters can be cast as partial differential equations, and then we derive SRAD by allowing edge-sensitive anisotropic diffusion within this context. Just as the Lee and Frost filters utilize the coefficient of variation in adaptive filtering, SRAD exploits the instantaneous coefficient of variation, which is shown to be a function of the local gradient magnitude and Laplacian operators. We validate the new algorithm using both synthetic and real linear scan ultrasonic imagery of the carotid artery. We also demonstrate the algorithm performance with real SAR data. The performance measures obtained by means of computer simulation of carotid artery images are compared with three existing speckle reduction schemes. In the presence of speckle noise, speckle reducing anisotropic diffusion excels over the traditional speckle removal filters and over the conventional anisotropic diffusion method in terms of mean preservation, variance reduction, and edge localization.

  4. Anisotropic Hydraulic Permeability Under Finite Deformation

    PubMed Central

    Ateshian, Gerard A.; Weiss, Jeffrey A.

    2011-01-01

    The structural organization of biological tissues and cells often produces anisotropic transport properties. These tissues may also undergo large deformations under normal function, potentially inducing further anisotropy. A general framework for formulating constitutive relations for anisotropic transport properties under finite deformation is lacking in the literature. This study presents an approach based on representation theorems for symmetric tensor-valued functions and provides conditions to enforce positive semi-definiteness of the permeability or diffusivity tensor. Formulations are presented which describe materials that are orthotropic, transversely isotropic, or isotropic in the reference state, and where large strains induce greater anisotropy. Strain-induced anisotropy of the permeability of a solid-fluid mixture is illustrated for finite torsion of a cylinder subjected to axial permeation. It is shown that, in general, torsion can produce a helical flow pattern, rather than the rectilinear pattern observed when adopting a more specialized, unconditionally isotropic spatial permeability tensor commonly used in biomechanics. The general formulation presented in this study can produce both affine and non-affine reorientation of the preferred directions of material symmetry with strain, depending on the choice of material functions. This study addresses a need in the biomechanics literature by providing guidelines and formulations for anisotropic strain-dependent transport properties in porous-deformable media undergoing large deformations. PMID:21034145

  5. Mixture of Anisotropic Fluids

    NASA Astrophysics Data System (ADS)

    Florkowski, W.; Maj, R.

    The recently introduced approach describing coupled quark and gluon anisotropic fluids is generalized to include explicitly the transitions between quarks and gluons. We study the effects of such processes on the thermalization rate of anisotropic systems. We find that the quark-gluon transitions may enhance the overall thermalization rate in the cases where the initial momentum anisotropies correspond to mixed oblate-prolate or prolate configurations. On the other hand, no effect on the thermalization rate is found in the case of oblate configurations. The observed regularities are connected with the late-time behavior of the analyzed systems which is described either by the exponential decay or the power law.

  6. Molecular anisotropic magnetoresistance

    NASA Astrophysics Data System (ADS)

    Otte, Fabian; Heinze, Stefan; Mokrousov, Yuriy

    2015-12-01

    Using density functional theory calculations, we demonstrate that the effect of anisotropic magnetoresistance (AMR) can be enhanced by orders of magnitude with respect to conventional bulk ferromagnets in junctions containing molecules sandwiched between ferromagnetic leads. We study ballistic transport in metal-benzene complexes contacted by 3 d transition-metal wires. We show that a gigantic AMR can arise from spin-orbit coupling effects in the leads, drastically enhanced by orbital-symmetry filtering properties of the molecules. We further discuss how this molecular anisotropic magnetoresistance (MAMR) can be tuned by the proper choice of materials and their electronic properties.

  7. Hydromagnetic Flow and Heat Transfer over a Porous Oscillating Stretching Surface in a Viscoelastic Fluid with Porous Medium.

    PubMed

    Khan, Sami Ullah; Ali, Nasir; Abbas, Zaheer

    2015-01-01

    An analysis is carried out to study the heat transfer in unsteady two-dimensional boundary layer flow of a magnetohydrodynamics (MHD) second grade fluid over a porous oscillating stretching surface embedded in porous medium. The flow is induced due to infinite elastic sheet which is stretched periodically. With the help of dimensionless variables, the governing flow equations are reduced to a system of non-linear partial differential equations. This system has been solved numerically using the finite difference scheme, in which a coordinate transformation is used to transform the semi-infinite physical space to a bounded computational domain. The influence of the involved parameters on the flow, the temperature distribution, the skin-friction coefficient and the local Nusselt number is shown and discussed in detail. The study reveals that an oscillatory sheet embedded in a fluid-saturated porous medium generates oscillatory motion in the fluid. The amplitude and phase of oscillations depends on the rheology of the fluid as well as on the other parameters coming through imposed boundary conditions, inclusion of body force term and permeability of the porous medium. It is found that amplitude of flow velocity increases with increasing viscoelastic and mass suction/injection parameters. However, it decreases with increasing the strength of the applied magnetic field. Moreover, the temperature of fluid is a decreasing function of viscoelastic parameter, mass suction/injection parameter and Prandtl number. PMID:26657931

  8. Hydromagnetic Flow and Heat Transfer over a Porous Oscillating Stretching Surface in a Viscoelastic Fluid with Porous Medium.

    PubMed

    Khan, Sami Ullah; Ali, Nasir; Abbas, Zaheer

    2015-01-01

    An analysis is carried out to study the heat transfer in unsteady two-dimensional boundary layer flow of a magnetohydrodynamics (MHD) second grade fluid over a porous oscillating stretching surface embedded in porous medium. The flow is induced due to infinite elastic sheet which is stretched periodically. With the help of dimensionless variables, the governing flow equations are reduced to a system of non-linear partial differential equations. This system has been solved numerically using the finite difference scheme, in which a coordinate transformation is used to transform the semi-infinite physical space to a bounded computational domain. The influence of the involved parameters on the flow, the temperature distribution, the skin-friction coefficient and the local Nusselt number is shown and discussed in detail. The study reveals that an oscillatory sheet embedded in a fluid-saturated porous medium generates oscillatory motion in the fluid. The amplitude and phase of oscillations depends on the rheology of the fluid as well as on the other parameters coming through imposed boundary conditions, inclusion of body force term and permeability of the porous medium. It is found that amplitude of flow velocity increases with increasing viscoelastic and mass suction/injection parameters. However, it decreases with increasing the strength of the applied magnetic field. Moreover, the temperature of fluid is a decreasing function of viscoelastic parameter, mass suction/injection parameter and Prandtl number.

  9. Hydromagnetic Flow and Heat Transfer over a Porous Oscillating Stretching Surface in a Viscoelastic Fluid with Porous Medium

    PubMed Central

    Khan, Sami Ullah; Ali, Nasir; Abbas, Zaheer

    2015-01-01

    An analysis is carried out to study the heat transfer in unsteady two-dimensional boundary layer flow of a magnetohydrodynamics (MHD) second grade fluid over a porous oscillating stretching surface embedded in porous medium. The flow is induced due to infinite elastic sheet which is stretched periodically. With the help of dimensionless variables, the governing flow equations are reduced to a system of non-linear partial differential equations. This system has been solved numerically using the finite difference scheme, in which a coordinate transformation is used to transform the semi-infinite physical space to a bounded computational domain. The influence of the involved parameters on the flow, the temperature distribution, the skin-friction coefficient and the local Nusselt number is shown and discussed in detail. The study reveals that an oscillatory sheet embedded in a fluid-saturated porous medium generates oscillatory motion in the fluid. The amplitude and phase of oscillations depends on the rheology of the fluid as well as on the other parameters coming through imposed boundary conditions, inclusion of body force term and permeability of the porous medium. It is found that amplitude of flow velocity increases with increasing viscoelastic and mass suction/injection parameters. However, it decreases with increasing the strength of the applied magnetic field. Moreover, the temperature of fluid is a decreasing function of viscoelastic parameter, mass suction/injection parameter and Prandtl number. PMID:26657931

  10. Wave Attenuation in Partially Saturated Porous Solids.

    NASA Astrophysics Data System (ADS)

    Yin, Chuan-Sheng

    1992-01-01

    This thesis consists of three independent papers. Paper 1 studies effects of pulsating gas pockets on wave propagation in partially saturated porous solids containing both liquid and gas phases. On the basis of Biot theory, an analytic solution for the White model for study of the effects of saturation history on wave attenuation is derived. One of the most significant findings of this work is that when the average spacing among the neighboring gas pockets is of the order of the boundary-layer thickness associated with the slow compressional (or P2) wave, the attenuation of the compressional (or P) wave due to local fluid flow reaches its maximum. Results of Paper 1 bear direct applications to seismic and logging responses of partially saturated rocks in prospecting for petroleum, and monitoring of oil and natural gas reservoirs. Paper 2 presents the results of the experimental studies of the effects of partial liquid/gas saturation on extensional wave attenuation in Berea sandstones. Two experimental methods are used; one is the resonant-bar method and the other the forced-deformation method. It is found that the wave attenuation depends on sample-saturation history (drainage or imbibition), as well as boundary-flow conditions, and the degree of saturation. The attenuation caused by "flowable" liquid is sensitive only in the region of low degree of gas saturation. An open-pore boundary tends to induce higher attenuation. The results obtained by the forced-deformation method show that the magnitude of the attenuation decreases substantially with decreasing frequency to the extent that no attenuation peak was apparent at frequencies below 100 Hz. Paper 3 analyzes extensional wave propagation in a porous fluid-saturated hollow-cylinder of infinite extent. Analytic solutions of complex Young's modulus for the long wavelength limit was obtained for a hollow -cylinder with open-pore inner surface. A simplified formula for estimating the frequency at which the

  11. Anisotropic eddy viscosity models

    NASA Technical Reports Server (NTRS)

    Carati, D.; Cabot, W.

    1996-01-01

    A general discussion on the structure of the eddy viscosity tensor in anisotropic flows is presented. The systematic use of tensor symmetries and flow symmetries is shown to reduce drastically the number of independent parameters needed to describe the rank 4 eddy viscosity tensor. The possibility of using Onsager symmetries for simplifying further the eddy viscosity is discussed explicitly for the axisymmetric geometry.

  12. Dynamics of Anisotropic Universes

    NASA Astrophysics Data System (ADS)

    Perez, Jérôme

    2006-11-01

    We present a general study of the dynamical properties of Anisotropic Bianchi Universes in the context of Einstein General Relativity. Integrability results using Kovalevskaya exponents are reported and connected to general knowledge about Bianchi dynamics. Finally, dynamics toward singularity in Bianchi type VIII and IX universes are showed to be equivalent in some precise sence.

  13. Modeling anisotropic flow and heat transport by using mimetic finite differences

    NASA Astrophysics Data System (ADS)

    Chen, Tao; Clauser, Christoph; Marquart, Gabriele; Willbrand, Karen; Büsing, Henrik

    2016-08-01

    Modeling anisotropic flow in porous or fractured rock often assumes that the permeability tensor is diagonal, which means that its principle directions are always aligned with the coordinate axes. However, the permeability of a heterogeneous anisotropic medium usually is a full tensor. For overcoming this shortcoming, we use the mimetic finite difference method (mFD) for discretizing the flow equation in a hydrothermal reservoir simulation code, SHEMAT-Suite, which couples this equation with the heat transport equation. We verify SHEMAT-Suite-mFD against analytical solutions of pumping tests, using both diagonal and full permeability tensors. We compare results from three benchmarks for testing the capability of SHEMAT-Suite-mFD to handle anisotropic flow in porous and fractured media. The benchmarks include coupled flow and heat transport problems, three-dimensional problems and flow through a fractured porous medium with full equivalent permeability tensor. It shows firstly that the mimetic finite difference method can model anisotropic flow both in porous and in fractured media accurately and its results are better than those obtained by the multi-point flux approximation method in highly anisotropic models, secondly that the asymmetric permeability tensor can be included and leads to improved results compared the symmetric permeability tensor in the equivalent fracture models, and thirdly that the method can be easily implemented in existing finite volume or finite difference codes, which has been demonstrated successfully for SHEMAT-Suite.

  14. Seismoelectric Phenomena in Fluid-Saturated Sediments

    SciTech Connect

    Block, G I; Harris, J G

    2005-04-22

    Seismoelectric phenomena in sediments arise from acoustic wave-induced fluid motion in the pore space, which perturbs the electrostatic equilibrium of the electric double layer on the grain surfaces. Experimental techniques and the apparatus built to study this electrokinetic (EK) effect are described and outcomes for studies of seismoelectric phenomena in loose glass microspheres and medium-grain sand are presented. By varying the NaCl concentration in the pore fluid, we measured the conductivity dependence of two kinds of EK behavior: (1) the electric fields generated within the samples by the passage of transmitted acoustic waves, and (2) the electromagnetic wave produced at the fluid-sediment interface by the incident acoustic wave. Both phenomena are caused by relative fluid motion in the sediment pores--this feature is characteristic of poroelastic (Biot) media, but not predicted by either viscoelastic fluid or solid models. A model of plane-wave reflection from a fluid-sediment interface using EK-Biot theory leads to theoretical predictions that compare well to the experimental data for both sand and glass microspheres.

  15. Anisotropic resistivity tomography

    NASA Astrophysics Data System (ADS)

    Herwanger, J. V.; Pain, C. C.; Binley, A.; de Oliveira, C. R. E.; Worthington, M. H.

    2004-08-01

    Geophysical tomographic techniques have the potential to remotely detect and characterize geological features, such as fractures and spatially varying lithologies, by their response to signals passed through these features. Anisotropic behaviour in many geological materials necessitates the generalization of tomographic methods to include anisotropic material properties in order to attain high-quality images of the subsurface. In this paper, we present a finite element (FE) based direct-current electrical inversion method to reconstruct the conductivity tensor at each node point of a FE mesh from electrical resistance measurements. The inverse problem is formulated as a functional optimization and the non-uniqueness of the electrical inverse problem is overcome by adding penalty terms for structure and anisotropy. We use a modified Levenberg-Marquardt method for the functional optimization and the resulting set of linear equation is solved using pre-conditioned conjugate gradients. The method is tested using both synthetic and field experiments in cross-well geometry. The acquisition geometry for both experiments uses a cross-well experiment at a hard-rock test site in Cornwall, southwest England. Two wells, spaced at 25.7 m, were equipped with electrodes at a 1 m spacing at depths from 21-108 m and data were gathered in pole-pole geometry. The test synthetic model consists of a strongly anisotropic and conductive body underlain by an isotropic resistive formation. Beneath the resistive formation, the model comprises a moderately anisotropic and moderately conductive half-space, intersected by an isotropic conductive layer. This model geometry was derived from the interpretation of a seismic tomogram and available geological logs and the conductivity values are based on observed conductivities. We use the test model to confirm the ability of the inversion scheme to recover the (known) true model. We find that all key features of the model are recovered. However

  16. Thermal effects in orthotropic porous elastic beams

    NASA Astrophysics Data System (ADS)

    Iaşan, D.

    2009-01-01

    This paper is concerned with the linear theory of anisotropic porous elastic bodies. The extension and bending of orthotropic porous elastic cylinders subjected to a plane temperature field is investigated. The work is motivated by the recent interest in the using of the orthotropic porous elastic solid as model for bones and various engineering materials. First, the thermoelastic deformation of inhomogeneous beams whose constitutive coefficients are independent of the axial coordinate is studied. Then, the extension and bending effects in orthotropic cylinders reinforced by longitudinal rods are investigated. The three-dimensional problem is reduced to the study of two-dimensional problems. The method is used to solve the problem of an orthotropic porous circular cylinder with a special kind of inhomogeneity.

  17. Natural convection flow in porous enclosure with localized heating from below with heat flux

    NASA Astrophysics Data System (ADS)

    Siddiki, Md. Noor-A.-Alam; Molla, Md. Mamun; Saha, Suvash C.

    2016-07-01

    Unsteady natural convection flow in a two dimensional fluid saturated porous enclosure with localized heating from below with heat flux, symmetrical cooling from the sides and the insulated top wall has been investigated numerically. The governing equations are the Darcy's law for the porous media and the energy equation for the temperature field has been considered. The non-dimensional Darcy's law in terms of the stream function is solved by finite difference method using the successive over-relaxation (SOR) scheme and the energy equation is solved by Alternative Direction Alternative (ADI) scheme. The uniform heat flux source is located centrally at the bottom wall. The numerical results are presented in terms of the streamlines and isotherms, as well as the local and average rate of heat transfer for the wide range of the Darcy's Rayleigh number and the length of the heat flux source at the bottom wall.

  18. Effect of segmental heating on mixed convection aiding flow in a vertical porous annulus

    NASA Astrophysics Data System (ADS)

    Salman, Ahmed N. J.; Al-Rashed, Abdullah A. A. A.; Kamangar, Sarfaraz; Khan, T. M. Yunus; Khaleed, H. M. T.

    2016-06-01

    Mixed convection flow in a vertical porous annulus embedded with fluid saturated porous medium for aiding is investigated. The annulus is imposed by 20%, 35% and 50% heater length at the bottom, mid and top sections of the annulus respectively. Darcy law with thermal non-equilibrium approach is considered. The governing partial differential equations are converted to simple algebraic equations using Finite Element Method (FEM). The effects of Peclet number Pe and conductivity ratio Kr on heat transfer and fluid flow behaviour are examined and it is found that for lower conductivity ratio, the heat transfer rate was higher with the increase in the Peclet number Pe, whereas this trend reversed when thermal conductivity ratio Kr is increased.

  19. Parallel Anisotropic Tetrahedral Adaptation

    NASA Technical Reports Server (NTRS)

    Park, Michael A.; Darmofal, David L.

    2008-01-01

    An adaptive method that robustly produces high aspect ratio tetrahedra to a general 3D metric specification without introducing hybrid semi-structured regions is presented. The elemental operators and higher-level logic is described with their respective domain-decomposed parallelizations. An anisotropic tetrahedral grid adaptation scheme is demonstrated for 1000-1 stretching for a simple cube geometry. This form of adaptation is applicable to more complex domain boundaries via a cut-cell approach as demonstrated by a parallel 3D supersonic simulation of a complex fighter aircraft. To avoid the assumptions and approximations required to form a metric to specify adaptation, an approach is introduced that directly evaluates interpolation error. The grid is adapted to reduce and equidistribute this interpolation error calculation without the use of an intervening anisotropic metric. Direct interpolation error adaptation is illustrated for 1D and 3D domains.

  20. Fractures in anisotropic media

    NASA Astrophysics Data System (ADS)

    Shao, Siyi

    Rocks may be composed of layers and contain fracture sets that cause the hydraulic, mechanical and seismic properties of a rock to be anisotropic. Coexisting fractures and layers in rock give rise to competing mechanisms of anisotropy. For example: (1) at low fracture stiffness, apparent shear-wave anisotropy induced by matrix layering can be masked or enhanced by the presence of a fracture, depending on the fracture orientation with respect to layering, and (2) compressional-wave guided modes generated by parallel fractures can also mask the presence of matrix layerings for particular fracture orientations and fracture specific stiffness. This report focuses on two anisotropic sources that are widely encountered in rock engineering: fractures (mechanical discontinuity) and matrix layering (impedance discontinuity), by investigating: (1) matrix property characterization, i.e., to determine elastic constants in anisotropic solids, (2) interface wave behavior in single-fractured anisotropic media, (3) compressional wave guided modes in parallel-fractured anisotropic media (single fracture orientation) and (4) the elastic response of orthogonal fracture networks. Elastic constants of a medium are required to understand and quantify wave propagation in anisotropic media but are affected by fractures and matrix properties. Experimental observations and analytical analysis demonstrate that behaviors of both fracture interface waves and compressional-wave guided modes for fractures in anisotropic media, are affected by fracture specific stiffness (controlled by external stresses), signal frequency and relative orientation between layerings in the matrix and fractures. A fractured layered medium exhibits: (1) fracture-dominated anisotropy when the fractures are weakly coupled; (2) isotropic behavior when fractures delay waves that are usually fast in a layered medium; and (3) matrix-dominated anisotropy when the fractures are closed and no longer delay the signal. The

  1. Characterization of porous hydroxyapatite.

    PubMed

    Hing, K A; Best, S M; Bonfield, W

    1999-03-01

    Hydroxyapatite has been considered for use in the repair of osseous defects for the last 20 years. Recent developments have led to interest in the potential of porous hydroxyapatite as a synthetic bone graft. However, despite considerable activity in this field, regarding assessment of the biological response to such materials, the basic materials characterization is often inadequate. This paper documents the characterization of the chemical composition, mechanical integrity, macro- and microstructure of a porous hydroxyapatite, Endobon (E. Merck GmbH), intended for the bone-graft market. Specimens possesed a range of apparent densities from 0.35 to 1.44 g cm(-3). Chemical analysis demonstrated that the natural apatite precursor of Endobon was not converted to pure hydroxyapatite, but retained many of the ionic substituents found in bone mineral, notably carbonate, sodium and magnesium ions. Investigation of the microstructure illustrated that the struts of the material were not fully dense, but had retained some traces of the network of osteocyte lacunae. Macrostructural analysis demonstrated the complex inter-relationship between the structural features of an open pore structure. Both pore size and connectivity were found to be inversely dependent on apparent density. Furthermore, measurement of pore aspect ratio and orientation demonstrated a relationship between apparent density and the degree of macrostructural anisotropy within the specimens, while, it was also noted that pore connectivity was sensitive to anisotropy. Compression testing demonstrated the effect of apparent density and macrostructural anisotropy on the mechanical properties. An increase in apparent density from 0.38 to 1.25 g cm(-3) resulted in increases in ultimate compressive stress and compressive modulus of 1 to 11 MPa and 0.2 to 3.1 GPa, respectively. Furthermore, anisotropic high density (> 0.9 g cm(-3)) specimens were found to possess lower compressive moduli than isotropic specimens

  2. Anisotropic Total Variation Filtering

    SciTech Connect

    Grasmair, Markus; Lenzen, Frank

    2010-12-15

    Total variation regularization and anisotropic filtering have been established as standard methods for image denoising because of their ability to detect and keep prominent edges in the data. Both methods, however, introduce artifacts: In the case of anisotropic filtering, the preservation of edges comes at the cost of the creation of additional structures out of noise; total variation regularization, on the other hand, suffers from the stair-casing effect, which leads to gradual contrast changes in homogeneous objects, especially near curved edges and corners. In order to circumvent these drawbacks, we propose to combine the two regularization techniques. To that end we replace the isotropic TV semi-norm by an anisotropic term that mirrors the directional structure of either the noisy original data or the smoothed image. We provide a detailed existence theory for our regularization method by using the concept of relaxation. The numerical examples concluding the paper show that the proposed introduction of an anisotropy to TV regularization indeed leads to improved denoising: the stair-casing effect is reduced while at the same time the creation of artifacts is suppressed.

  3. Anisotropic spinfoam cosmology

    NASA Astrophysics Data System (ADS)

    Rennert, Julian; Sloan, David

    2014-01-01

    The dynamics of a homogeneous, anisotropic universe are investigated within the context of spinfoam cosmology. Transition amplitudes are calculated for a graph consisting of a single node and three links—the ‘Daisy graph’—probing the behaviour a classical Bianchi I spacetime. It is shown further how the use of such single node graphs gives rise to a simplification of states such that all orders in the spin expansion can be calculated, indicating that it is the vertex expansion that contains information about quantum dynamics.

  4. Anisotropic Thermal Diffusion

    NASA Astrophysics Data System (ADS)

    Gardiner, Thomas

    2013-10-01

    Anisotropic thermal diffusion in magnetized plasmas is an important physical phenomena for a diverse set of physical conditions ranging from astrophysical plasmas to MFE and ICF. Yet numerically simulating this phenomenon accurately poses significant challenges when the computational mesh is misaligned with respect to the magnetic field. Particularly when the temperature gradients are unresolved, one frequently finds entropy violating solutions with heat flowing from cold to hot zones for χ∥ /χ⊥ >=102 which is substantially smaller than the range of interest which can reach 1010 or higher. In this talk we present a new implicit algorithm for solving the anisotropic thermal diffusion equations and demonstrate its characteristics on what has become a fairly standard set of test problems in the literature. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2013-5687A.

  5. Constraining anisotropic baryon oscillations

    NASA Astrophysics Data System (ADS)

    Padmanabhan, Nikhil; White, Martin

    2008-06-01

    We present an analysis of anisotropic baryon acoustic oscillations and elucidate how a mis-estimation of the cosmology, which leads to incorrect values of the angular diameter distance, dA, and Hubble parameter, H, manifest themselves in changes to the monopole and quadrupole power spectrum of biased tracers of the density field. Previous work has focused on the monopole power spectrum, and shown that the isotropic dilation combination dA2H-1 is robustly constrained by an overall shift in the scale of the baryon feature. We extend this by demonstrating that the quadrupole power spectrum is sensitive to an anisotropic warping mode dAH, allowing one to break the degeneracy between dA and H. We describe a method for measuring this warping, explicitly marginalizing over the form of redshift-space distortions. We verify this method on N-body simulations and estimate that dAH can be measured with a fractional accuracy of ˜(3/V)% where the survey volume is estimated in h-3Gpc3.

  6. Inhomogeneous anisotropic cosmology

    NASA Astrophysics Data System (ADS)

    Kleban, Matthew; Senatore, Leonardo

    2016-10-01

    In homogeneous and isotropic Friedmann-Robertson-Walker cosmology, the topology of the universe determines its ultimate fate. If the Weak Energy Condition is satisfied, open and flat universes must expand forever, while closed cosmologies can recollapse to a Big Crunch. A similar statement holds for homogeneous but anisotropic (Bianchi) universes. Here, we prove that arbitrarily inhomogeneous and anisotropic cosmologies with ``flat'' (including toroidal) and ``open'' (including compact hyperbolic) spatial topology that are initially expanding must continue to expand forever at least in some region at a rate bounded from below by a positive number, despite the presence of arbitrarily large density fluctuations and/or the formation of black holes. Because the set of 3-manifold topologies is countable, a single integer determines the ultimate fate of the universe, and, in a specific sense, most 3-manifolds are ``flat'' or ``open''. Our result has important implications for inflation: if there is a positive cosmological constant (or suitable inflationary potential) and initial conditions for the inflaton, cosmologies with ``flat'' or ``open'' topology must expand forever in some region at least as fast as de Sitter space, and are therefore very likely to begin inflationary expansion eventually, regardless of the scale of the inflationary energy or the spectrum and amplitude of initial inhomogeneities and gravitational waves. Our result is also significant for numerical general relativity, which often makes use of periodic (toroidal) boundary conditions.

  7. Influence of Soret, Hall and Joule heating effects on mixed convection flow saturated porous medium in a vertical channel by Adomian Decomposition Method

    NASA Astrophysics Data System (ADS)

    Reddy, Ch. Ram; Kaladhar, K.; Srinivasacharya, D.; Pradeepa, T.

    2016-02-01

    This paper analyzes the laminar, incompressible mixed convective transport inside vertical channel in an electrically conducting fluid saturated porous medium. In addition, this model incorporates the combined effects of Soret, Hall current and Joule heating. The nonlinear governing equations and their related boundary conditions are initially cast into a dimensionless form using suitable similarity transformations and hence solved using Adomian Decomposition Method (ADM). In order to explore the influence of various parameters on fluid flow properties, quantitative analysis is exhibited graphically and shown in tabular form.

  8. Measurement and Estimation of Organic-Liquid/Water Interfacial Areas for Several Natural Porous Media

    SciTech Connect

    Brusseau, M.L.; Narter, M.; Schnaar, G.; Marble, J.

    2009-06-01

    The objective of this study was to quantitatively characterize the impact of porous-medium texture on interfacial area between immiscible organic liquid and water residing within natural porous media. Synchrotron X-ray microtomography was used to obtain high-resolution, three-dimensional images of solid and liquid phases in packed columns. The image data were processed to generate quantitative measurements of organic-liquid/water interfacial area and of organic-liquid blob sizes. Ten porous media, comprising a range of median grain sizes, grain-size distributions, and geochemical properties, were used to evaluate the impact of porous-medium texture on interfacial area. The results show that fluid-normalized specific interfacial area (A{sub f}) and maximum specific interfacial area (A{sub m}) correlate very well to inverse median grain diameter. These functionalities were shown to result from a linear relationship between effective organic-liquid blob diameter and median grain diameter. These results provide the basis for a simple method for estimating specific organic-liquid/water interfacial area as a function of fluid saturation for a given porous medium. The availability of a method for which the only parameter needed is the simple-to-measure median grain diameter should be of great utility for a variety of applications.

  9. Anisotropic power-law inflation

    SciTech Connect

    Kanno, Sugumi; Soda, Jiro; Watanabe, Masa-aki E-mail: jiro@tap.scphys.kyoto-u.ac.jp

    2010-12-01

    We study an inflationary scenario in supergravity model with a gauge kinetic function. We find exact anisotropic power-law inflationary solutions when both the potential function for an inflaton and the gauge kinetic function are exponential type. The dynamical system analysis tells us that the anisotropic power-law inflation is an attractor for a large parameter region.

  10. Chaotic advection in 2D anisotropic porous media

    NASA Astrophysics Data System (ADS)

    Varghese, Stephen; Speetjens, Michel; Trieling, Ruben; Toschi, Federico

    2015-11-01

    Traditional methods for heat recovery from underground geothermal reservoirs employ a static system of injector-producer wells. Recent studies in literature have shown that using a well-devised pumping scheme, through actuation of multiple injector-producer wells, can dramatically enhance production rates due to the increased scalar / heat transport by means of chaotic advection. However the effect of reservoir anisotropy on kinematic mixing and heat transport is unknown and has to be incorporated and studied for practical deployment in the field. As a first step, we numerically investigate the effect of anisotropy (both magnitude and direction) on (chaotic) advection of passive tracers in a time-periodic Darcy flow within a 2D circular domain driven by periodically reoriented diametrically opposite source-sink pairs. Preliminary results indicate that anisotropy has a significant impact on the location, shape and size of coherent structures in the Poincare sections. This implies that the optimal operating parameters (well spacing, time period of well actuation) may vary strongly and must be carefully chosen so as to enhance subsurface transport. This work is part of the research program of the Foundation for Fundamental Research on Matter (FOM), which is part of Netherlands Organisation for Scientific Research (NWO). This research program is co-financed by Shell Global Solutions International B.V.

  11. Anisotropic Model Colloids

    NASA Astrophysics Data System (ADS)

    van Kats, C. M.

    2008-10-01

    The driving forces for fundamental research in colloid science are the ability to manage the material properties of colloids and to unravel the forces that play a role between colloids to be able to control and understand the processes where colloids play an important role. Therefore we are searching for colloidal materials with specific physical properties to better understand our surrounding world.Until recently research in colloid science was mainly focused on spherical (isotropic) particles. Monodisperse spherical colloids serve as a model system as they exhibit similar phase behaviour as molecular and atomic systems. Nevertheless, in many cases the spherical shape is not sufficient to reach the desired research goals. Recently the more complex synthesis methods of anisotropic model colloids has strongly developed. This thesis should be regarded as a contribution to this research area. Anisotropic colloids can be used as a building block for complex structures and are expected not only to lead to the construction of full photonic band gap materials. They will also serve as new, more realistic, models systems for their molecular analogues. Therefore the term ‘molecular colloids” is sometimes used to qualify these anisotropic colloidal particles. In the introduction of this thesis, we give an overview of the main synthesis techniques for anisotropic colloids. Chapter 2 describes the method of etching silicon wafers to construct monodisperse silicon rods. They subsequently were oxidized and labeled (coated) with a fluorescent silica layer. The first explorative phase behaviour of these silica rods was studied. The particles showed a nematic ordering in charge stabilized suspensions. Chapter 3 describes the synthesis of colloidal gold rods and the (mesoporous) silica coating of gold rods. Chapter 4 describes the physical and optical properties of these particles when thermal energy is added. This is compared to the case where the particles are irradiated with

  12. Anisotropic Kepler and anisotropic two fixed centres problems

    NASA Astrophysics Data System (ADS)

    Maciejewski, Andrzej J.; Przybylska, Maria; Szumiński, Wojciech

    2016-09-01

    In this paper we show that the anisotropic Kepler problem is dynamically equivalent to a system of two point masses which move in perpendicular lines (or planes) and interact according to Newton's law of universal gravitation. Moreover, we prove that generalised version of anisotropic Kepler problem as well as anisotropic two centres problem are non-integrable. This was achieved thanks to investigation of differential Galois groups of variational equations along certain particular solutions. Properties of these groups yield very strong necessary integrability conditions.

  13. Stability Of Superposed Fluids Through Magnetic Field With Suspended Particles Of Different Permeability Saturated Through Porous Layer

    NASA Astrophysics Data System (ADS)

    Singh, M.

    2015-12-01

    The instability of plane interface between two superposed Rivlin-Ericksen elastico-viscous fluids saturated through a porous medium has been studied to include the suspended (dust) particles effect. Following the linearized stability theory and normal mode analysis the dispersion relation is obtained. For stationary convection, the Rivlin-Ericksen elastico-viscous fluid behaves like Newtonian fluids. It found that for a potentially stable arrangement the Rivlin-Ericksen elastico-viscous fluid of different permeabilities in the presence of suspended particles in a porous medium is stable, whereas in a potentially unstable case instability of the system occurs. In the presence of a magnetic field for a potentially stable arrangement the system is always stable and for the potentially unstable arrangement, the magnetic field succeeds in stabilizing certain wave-number band which was unstable in the absence of the magnetic field.

  14. [Investigation of ultrasonic surface wave interaction with porous saturated rocks]. Progress report, [July 1, 1993--June 30, 1994

    SciTech Connect

    Not Available

    1994-06-01

    Calculations showed that capillary forces can easily produce closed- pore boundary conditions at interface between nonwetting fluid (air) and a porous solid saturated by a wetting fluid (water). The direct excitation technique was used to measure surface wave velocity and attenuation on both wet and dry rocks. The strong correlation between the observed surface wave velocity change caused by water saturation and the formation permeability can be used for ultrasonic assessment of the dynamic permeability. The experimental system was improved further by introducing laser interferometric detection, which was adapted to surface wave inspection of fluid-saturated permeable materials. In a separate effort, the surface stiffness of different water-saturated porous solids was studied by a novel acoustical method. Areas for further study are described.

  15. Optical trapping of anisotropic nanocylinder

    NASA Astrophysics Data System (ADS)

    Bareil, Paul B.; Sheng, Yunlong

    2013-09-01

    The T-matrix method with the Vector Spherical Wave Function (VSWF) expansions represents some difficulties for computing optical scattering of anisotropic particles. As the divergence of the electric field is nonzero in the anisotropic medium and the VSWFs do not satisfy the anisotropic wave equations one questioned whether the VSWFs are still a suitable basis in the anisotropic medium. We made a systematic and careful review on the vector basis functions and the VSWFs. We found that a field vector in Euclidean space can be decomposed to triplet vectors {L, M, N}, which as non-coplanar. Especially, the vector L is designed to represent non-zero divergence component of the vector solution, so that the VSWF basis is sufficiently general to represent the solutions of the anisotropic wave equation. The mathematical proof can be that when the anisotropic wave equations is solved in the Fourier space, the solution is expanded in the basis of the plan waves with angular spectrum amplitude distributions. The plane waves constitute an orthogonal and complete set for the anisotropic solutions. Furthermore, the plane waves are expanded into the VSWF basis. These two-step expansions are equivalent to the one-step direct expansion of the anisotropic solution to the VSWF basis. We used direct VSWF expansion, along with the point-matching method in the T-matrix, and applied the boundary condition to the normal components displacement field in order to compute the stress and the related forces and torques and to show the mechanism of the optical trap of the anisotropic nano-cylinders.

  16. Anisotropic inflation with general potentials

    NASA Astrophysics Data System (ADS)

    Shi, JiaMing; Huang, XiaoTian; Qiu, TaoTao

    2016-04-01

    Anomalies in recent observational data indicate that there might be some "anisotropic hair" generated in an inflation period. To obtain general information about the effects of this anisotropic hair to inflation models, we studied anisotropic inflation models that involve one vector and one scalar using several types of potentials. We determined the general relationship between the degree of anisotropy and the fraction of the vector and scalar fields, and concluded that the anisotropies behave independently of the potentials. We also generalized our study to the case of multi-directional anisotropies.

  17. Variably porous structures

    SciTech Connect

    Braun, Paul V.; Yu, Xindi

    2011-01-18

    A method of making a monolithic porous structure, comprises electrodepositing a material on a template; removing the template from the material to form a monolithic porous structure comprising the material; and electropolishing the monolithic porous structure.

  18. Vortex dynamics in anisotropic traps

    SciTech Connect

    McEndoo, S.; Busch, Th.

    2010-07-15

    We investigate the dynamics of linear vortex lattices in anisotropic traps in two dimensions and show that the interplay between the rotation and the anisotropy leads to a rich but highly regular dynamics.

  19. Mechanics of layered anisotropic poroelastic media with applications to effective stress for fluid permeability

    SciTech Connect

    Berryman, J.G.

    2010-06-01

    The mechanics of vertically layered porous media has some similarities to and some differences from the more typical layered analysis for purely elastic media. Assuming welded solid contact at the solid-solid interfaces implies the usual continuity conditions, which are continuity of the vertical (layering direction) stress components and the horizontal strain components. These conditions are valid for both elastic and poroelastic media. Differences arise through the conditions for the pore pressure and the increment of fluid content in the context of fluid-saturated porous media. The two distinct conditions most often considered between any pair of contiguous layers are: (1) an undrained fluid condition at the interface, meaning that the increment of fluid content is zero (i.e., {delta}{zeta} = 0), or (2) fluid pressure continuity at the interface, implying that the change in fluid pressure is zero across the interface (i.e., {delta}p{sub f} = 0). Depending on the types of measurements being made on the system and the pertinent boundary conditions for these measurements, either (or neither) of these two conditions might be directly pertinent. But these conditions are sufficient nevertheless to be used as thought experiments to determine the expected values of all the poroelastic coefficients. For quasi-static mechanical changes over long time periods, we expect drained conditions to hold, so the pressure must then be continuous. For high frequency wave propagation, the pore-fluid typically acts as if it were undrained (or very nearly so), with vanishing of the fluid increment at the boundaries being appropriate. Poroelastic analysis of both these end-member cases is discussed, and the general equations for a variety of applications to heterogeneous porous media are developed. In particular, effective stress for the fluid permeability of such poroelastic systems is considered; fluid permeabilities characteristic of granular media or tubular pore shapes are treated

  20. Characterizing Fluid/Fluid Interfacial Areas for Non-Wetting/Wetting Fluid Pairs in Natural Porous Media

    NASA Astrophysics Data System (ADS)

    Narter, M.; Brusseau, M. L.; Araujo, J. B.; Marble, J. C.; Schnaar, G. A.

    2011-12-01

    The interface between fluids in the subsurface mediates a number of pore-scale processes affecting contaminant transport and fate. These processes include multiphase flow, mass transfer, sorption, and bioavailability. The objective of this study was to characterize the interfacial area between pairs of non-wetting and wetting fluids in a variety of natural porous media. Synchrotron X-ray microtomography was used to obtain high-resolution, three-dimensional images of multi-phase porous media systems. Four porous media, comprising a range of physical properties, were used in the study. The three pairs of non-wetting/wetting fluids used were organic-liquid/water, air/organic-liquid, and air/water. Tetrachloroethene and hexadecane were used as the model organic liquids. The results show that for each fluid pair, total (capillary + film) interfacial areas increased linearly with decreasing non-wetting fluid saturation. The maximum specific interfacial area (Am) was determined to quantify the magnitude of interfacial area associated with a given porous medium. The value of Am did not vary significantly between fluid-pairs for a given porous medium.

  1. Coefficient adaptive triangulation for strongly anisotropic problems

    SciTech Connect

    D`Azevedo, E.F.; Romine, C.H.; Donato, J.M.

    1996-01-01

    Second order elliptic partial differential equations arise in many important applications, including flow through porous media, heat conduction, the distribution of electrical or magnetic potential. The prototype is the Laplace problem, which in discrete form produces a coefficient matrix that is relatively easy to solve in a regular domain. However, the presence of anisotropy produces a matrix whose condition number is increased, making the resulting linear system more difficult to solve. In this work, we take the anisotropy into account in the discretization by mapping each anisotropic region into a ``stretched`` coordinate space in which the anisotropy is removed. The region is then uniformly triangulated, and the resulting triangulation mapped back to the original space. The effect is to generate long slender triangles that are oriented in the direction of ``preferred flow.`` Slender triangles are generally regarded as numerically undesirable since they tend to cause poor conditioning; however, our triangulation has the effect of producing effective isotropy, thus improving the condition number of the resulting coefficient matrix.

  2. Anisotropically structured magnetic aerogel monoliths

    NASA Astrophysics Data System (ADS)

    Heiligtag, Florian J.; Airaghi Leccardi, Marta J. I.; Erdem, Derya; Süess, Martin J.; Niederberger, Markus

    2014-10-01

    Texturing of magnetic ceramics and composites by aligning and fixing of colloidal particles in a magnetic field is a powerful strategy to induce anisotropic chemical, physical and especially mechanical properties into bulk materials. If porosity could be introduced, anisotropically structured magnetic materials would be the perfect supports for magnetic separations in biotechnology or for magnetic field-assisted chemical reactions. Aerogels, combining high porosity with nanoscale structural features, offer an exceptionally large surface area, but they are difficult to magnetically texture. Here we present the preparation of anatase-magnetite aerogel monoliths via the assembly of preformed nanocrystallites. Different approaches are proposed to produce macroscopic bodies with gradient-like magnetic segmentation or with strongly anisotropic magnetic texture.Texturing of magnetic ceramics and composites by aligning and fixing of colloidal particles in a magnetic field is a powerful strategy to induce anisotropic chemical, physical and especially mechanical properties into bulk materials. If porosity could be introduced, anisotropically structured magnetic materials would be the perfect supports for magnetic separations in biotechnology or for magnetic field-assisted chemical reactions. Aerogels, combining high porosity with nanoscale structural features, offer an exceptionally large surface area, but they are difficult to magnetically texture. Here we present the preparation of anatase-magnetite aerogel monoliths via the assembly of preformed nanocrystallites. Different approaches are proposed to produce macroscopic bodies with gradient-like magnetic segmentation or with strongly anisotropic magnetic texture. Electronic supplementary information (ESI) available: Digital photographs of dispersions and gels with different water-to-ethanol ratios; magnetic measurements of an anatase aerogel containing 0.25 mol% Fe3O4 nanoparticles; XRD patterns of the iron oxide and

  3. Dynamical analysis of anisotropic inflation

    NASA Astrophysics Data System (ADS)

    Karčiauskas, Mindaugas

    2016-06-01

    The inflaton coupling to a vector field via the f(φ)2F μνFμν term is used in several contexts in the literature, such as to generate primordial magnetic fields, to produce statistically anisotropic curvature perturbation, to support anisotropic inflation, and to circumvent the η-problem. In this work, I perform dynamical analysis of this system allowing for the most general Bianchi I initial conditions. I also confirm the stability of attractor fixed points along phase-space directions that had not been investigated before.

  4. Instability of fluid flow over saturated porous medium

    NASA Astrophysics Data System (ADS)

    Lyubimova, Tatyana; Kolchanova, Ekaterina; Lyubimov, Dmitry

    2013-04-01

    We investigate the stability of a fluid flow over a saturated porous medium. The problem is of importance due to the applications to washing out of contaminants from the bottom layer of vegetation, whose properties are similar to the properties of porous medium. In the case of porous medium with the relatively high permeability and porosity the flow involves a part of the fluid saturating the porous medium, with the tangential fluid velocity drop occurring because of the resistance of the solid matrix. The drop leads to the instability analogous to Kelvin-Helmholtz one accompanied by the formation of travelling waves. In the present paper we consider a two-layer system consisting of a pure fluid layer and a porous layer saturated by the fluid located underneath. The system is bounded by a rigid surface at the bottom and a non-deformable free surface at the top. It is under the gravity and inclined at a slight angle to the horizontal axis. The boundary conditions at the interface between the fluid and porous layers are the continuity of fluid velocities and the balance of normal and tangential stresses taking into account the resistance of the solid matrix with respect to the fluid flow near the interface [1-2]. The problem is solved in the framework of the Brinkman model applying the classical shooting algorithm with orthogonalization. The stability boundaries of the stationary fluid flow over the saturated porous medium with respect to the small oscillatory perturbations are obtained for the various values of the Darcy number and the ratio of the porous layer thickness to the full thickness of the system d. It was shown that at the d > 0.5 with increasing the porous layer thickness (or with decreasing of the fluid layer thickness) the stability threshold rises. This is because of the fact that the instability is primarily caused by perturbations located in the fluid layer. At the d < 0.5 the reduction of the porous layer thickness leads to the stability threshold

  5. Freeze Tape Casting of Functionally Graded Porous Ceramics

    NASA Technical Reports Server (NTRS)

    Sofie, Stephen W.

    2007-01-01

    Freeze tape casting is a means of making preforms of ceramic sheets that, upon subsequent completion of fabrication processing, can have anisotropic and/or functionally graded properties that notably include aligned and graded porosity. Freeze tape casting was developed to enable optimization of the microstructures of porous ceramic components for use as solid oxide electrodes in fuel cells: Through alignment and grading of pores, one can tailor surface areas and diffusion channels for flows of gas and liquid species involved in fuel-cell reactions. Freeze tape casting offers similar benefits for fabrication of optimally porous ceramics for use as catalysts, gas sensors, and filters.

  6. Fracture toughness of anisotropic graphites

    SciTech Connect

    Kennedy, C.R.; Kehne, M.T.

    1985-01-01

    Fracture toughness measurements have been made at 0, 30, 45, 60, and 90/sup 0/ from the extrusion axis on a reasonably anisotropic graphite, grade AGOT. It was found that the fracture toughness did not vary appreciably with orientation. An observed variation in strength was found to be the result of defect orientation.

  7. Fabrication, properties, and applications of porous metals with directional pores.

    PubMed

    Nakajima, Hideo

    2010-01-01

    Lotus-type porous metals with aligned long cylindrical pores are fabricated by unidirectional solidification from the melt with a dissolved gas such as hydrogen, nitrogen, or oxygen. The gas atoms can be dissolved into the melt via a pressurized gas atmosphere or thermal decomposition of gaseous compounds. Three types of solidification techniques have been developed: mold casting, continuous zone melting, and continuous casting techniques. The last method is superior from the viewpoint of mass production of lotus metals. The observed anisotropic behaviors of the mechanical properties, sound absorption, and thermal conductivity are inherent to the anisotropic porous structure. In particular, the remarkable anisotropy in the mechanical strength is attributed to the stress concentration around the pores aligned perpendicular to the loading direction. Heat sinks are a promising application of lotus metals due to the high cooling performance with a large heat transfer.

  8. Fabrication, properties, and applications of porous metals with directional pores

    PubMed Central

    NAKAJIMA, Hideo

    2010-01-01

    Lotus-type porous metals with aligned long cylindrical pores are fabricated by unidirectional solidification from the melt with a dissolved gas such as hydrogen, nitrogen, or oxygen. The gas atoms can be dissolved into the melt via a pressurized gas atmosphere or thermal decomposition of gaseous compounds. Three types of solidification techniques have been developed: mold casting, continuous zone melting, and continuous casting techniques. The last method is superior from the viewpoint of mass production of lotus metals. The observed anisotropic behaviors of the mechanical properties, sound absorption, and thermal conductivity are inherent to the anisotropic porous structure. In particular, the remarkable anisotropy in the mechanical strength is attributed to the stress concentration around the pores aligned perpendicular to the loading direction. Heat sinks are a promising application of lotus metals due to the high cooling performance with a large heat transfer. PMID:21084772

  9. Fabrication, properties, and applications of porous metals with directional pores.

    PubMed

    Nakajima, Hideo

    2010-01-01

    Lotus-type porous metals with aligned long cylindrical pores are fabricated by unidirectional solidification from the melt with a dissolved gas such as hydrogen, nitrogen, or oxygen. The gas atoms can be dissolved into the melt via a pressurized gas atmosphere or thermal decomposition of gaseous compounds. Three types of solidification techniques have been developed: mold casting, continuous zone melting, and continuous casting techniques. The last method is superior from the viewpoint of mass production of lotus metals. The observed anisotropic behaviors of the mechanical properties, sound absorption, and thermal conductivity are inherent to the anisotropic porous structure. In particular, the remarkable anisotropy in the mechanical strength is attributed to the stress concentration around the pores aligned perpendicular to the loading direction. Heat sinks are a promising application of lotus metals due to the high cooling performance with a large heat transfer. PMID:21084772

  10. Investigation of physical properties of porous rocks and fluid flow phenomena in porous media using computer assisted tomography

    SciTech Connect

    Kantzas, A. )

    1990-01-01

    Computer assisted tomography is becoming a very attractive tool for petroleum engineers. The method can give an image of a core in two or three dimensions with a very fine resolution and high accuracy. The image data can be processed to give information about the physical properties of the core (density, porosity, mineralogy, heterogeneities) and the fluids within the core (saturation and saturation profiles). This paper presents a software package that uses the CAT scanner output data as input for petrographic and dynamic modelling of a porous rock. Core samples up to 10 cm in diameter are scanned at different x-ray energy levels using an EMI CT5005 full body scanner. The scanner computer is producing an array of normalized linear attenuation coefficients per scanned slice. The resolution is 0.75 mm {times} 0.75 mm while the slice thickness can vary from 15 mm down to 1 mm depending on the bulk density and size of the sample. The developed package analyzes the CAT scanner data for bulk and grain density, effective atomic number, static and dynamic porosity and fluid saturations for up to three fluids present. The capabilities and limitations of the presented algorithm are discussed and characteristic examples are presented.

  11. On the validity of the effective stress concept for assessing the strength of saturated porous materials: A homogenization approach

    NASA Astrophysics Data System (ADS)

    De Buhan, P.; Dormieux, L.

    1996-10-01

    The much debated question of whether the strength criterion of a fluid saturated porous medium, such as most geomaterials, can be expressed in terms of "effective stress," is critically examined in this paper using the yield design homogenization theory as an investigating tool. Adopting a periodic description of the saturated porous material at the microscopic level, where the fluid phase exerts a pressure on the solid matrix making up the skeleton, a general definition of the strength properties of the porous material at the macroscopic scale is given. While some situations are identified where the "effective stress principle," as classically formulated, remains appropriate, it is proved that for a frictional solid matrix, such a principle, even in its generalized form, is not relevant. Nevertheless, the dependence on the pore pressure can still be specified in a simple way, so that the complete knowledge of the criterion for any prescribed value of the pore pressure only requires determining the strength properties of the dry porous material. Moreover, the possibility of adopting sufficiently accurate approximations of the actual criterion by resorting to an effective stress formulation is discussed.

  12. Use of a high magnetic field to visualize fluids and to study wettability in porous media by MRI

    SciTech Connect

    Chardaire-Riviere, C.; Roussel, J.C.

    1993-12-31

    Magnetic Resonance Imaging (MRI) is very useful for core analysis because it gives information related to petrophysical parameters: porosity and fluid saturations. The authors have used a high magnetic field of 9.4 Tesla to study fluid distributions in porous media. The use of high magnetic field coupled with strong gradients (up to 20 G/cm) enable the authors to produce images with a good resolution and to obtain very thin slices. The different applications studied are visualization of oil and water distributions during a flooding experiment, and study of wettability by NMR and MRI. For this last application, the authors have investigated to decouple the influence of pore size distribution and wettability in relaxation parameters.

  13. Anisotropic Ripple Deformation in Phosphorene.

    PubMed

    Kou, Liangzhi; Ma, Yandong; Smith, Sean C; Chen, Changfeng

    2015-05-01

    Two-dimensional materials tend to become crumpled according to the Mermin-Wagner theorem, and the resulting ripple deformation may significantly influence electronic properties as observed in graphene and MoS2. Here, we unveil by first-principles calculations a new, highly anisotropic ripple pattern in phosphorene, a monolayer black phosphorus, where compression-induced ripple deformation occurs only along the zigzag direction in the strain range up to 10%, but not the armchair direction. This direction-selective ripple deformation mode in phosphorene stems from its puckered structure with coupled hinge-like bonding configurations and the resulting anisotropic Poisson ratio. We also construct an analytical model using classical elasticity theory for ripple deformation in phosphorene under arbitrary strain. The present results offer new insights into the mechanisms governing the structural and electronic properties of phosphorene crucial to its device applications.

  14. Mechanistic models of biofilm growth in porous media

    NASA Astrophysics Data System (ADS)

    Jaiswal, Priyank; Al-Hadrami, Fathiya; Atekwana, Estella A.; Atekwana, Eliot A.

    2014-07-01

    Nondestructive acoustics methods can be used to monitor in situ biofilm growth in porous media. In practice, however, acoustic methods remain underutilized due to the lack of models that can translate acoustic data into rock properties in the context of biofilm. In this paper we present mechanistic models of biofilm growth in porous media. The models are used to quantitatively interpret arrival times and amplitudes recorded in the 29 day long Davis et al. (2010) physical scale biostimulation experiment in terms of biofilm morphologies and saturation. The model pivots on addressing the sediment elastic behavior using the lower Hashin-Shtrikman bounds for grain mixing and Gassmann substitution for fluid saturation. The time-lapse P wave velocity (VP; a function of arrival times) is explained by a combination of two rock models (morphologies); "load bearing" which assumes the biofilm as an additional mineral in the rock matrix and "pore filling" which assumes the biofilm as an additional fluid phase in the pores. The time-lapse attenuation (QP-1; a function of amplitudes), on the other hand, can be explained adequately in two ways; first, through squirt flow where energy is lost from relative motion between rock matrix and pore fluid, and second, through an empirical function of porosity (φ), permeability (κ), and grain size. The squirt flow model-fitting results in higher internal φ (7% versus 5%) and more oblate pores (0.33 versus 0.67 aspect ratio) for the load-bearing morphology versus the pore-filling morphology. The empirical model-fitting results in up to 10% increase in κ at the initial stages of the load-bearing morphology. The two morphologies which exhibit distinct mechanical and hydraulic behavior could be a function of pore throat size. The biofilm mechanistic models developed in this study can be used for the interpretation of seismic data critical for the evaluation of biobarriers in bioremediation, microbial enhanced oil recovery, and CO2

  15. Anisotropic microturbulence near the Sun

    NASA Technical Reports Server (NTRS)

    Coles, William A.; Grall, R. R.; Spangler, S. R.; Sakurai, T.; Harmon, J. K.

    1995-01-01

    Interplanetary scintillation observations which sample the spatial spectrum of electron density at scales between 10 and 100 km show power-law spectra which are flatter than the Kolmogorov spectra observed at larger scales by spacecraft and also, indirectly, by phase scintillation of coherent radio signals. Furthermore, angular broadening observations of compact radio sources have shown that the microscale density fluctuations are field-aligned and become more anisotropic as R decreases inside 10 solar radius. We present angular broadening observations taken in October of 1992 which were recorded nearly simultaneously on the VLA and VLBA arrays. The VLA samples structure at scales between 3 and 30 km, whereas the VLBA samples scales between 200 and 4000 km. The small scale VLA measurements of the south polar source 1246-075 showed lower turbulence than those of the equatorial source 1256-057, consistent with previous work showing that the density delta N(exp 2)(sub e) is a factor of 10-15 lower in coronal holes. The VLA observations inside of 10 solar radius were anisotropic, as expected. We were not able to measure the equatorial source with the VLBA inside of 10 solar radius because the scattering was too strong, however we did observe the polar source just inside this distance with both the VLA and the VLBA. Significant anisotropy was seen on the smaller scales, but the larger scales were essentially isotropic. This suggests that the process responsible for the anisotropic microturbulence is distinct from the larger scale isotropic turbulence.

  16. Porous Shape Memory Polymers

    PubMed Central

    Hearon, Keith; Singhal, Pooja; Horn, John; Small, Ward; Olsovsky, Cory; Maitland, Kristen C.; Wilson, Thomas S.; Maitland, Duncan J.

    2013-01-01

    Porous shape memory polymers (SMPs) include foams, scaffolds, meshes, and other polymeric substrates that possess porous three-dimensional macrostructures. Porous SMPs exhibit active structural and volumetric transformations and have driven investigations in fields ranging from biomedical engineering to aerospace engineering to the clothing industry. The present review article examines recent developments in porous SMPs, with focus given to structural and chemical classification, methods of characterization, and applications. We conclude that the current body of literature presents porous SMPs as highly interesting smart materials with potential for industrial use. PMID:23646038

  17. Tailored Porous Materials

    SciTech Connect

    BARTON,THOMAS J.; BULL,LUCY M.; KLEMPERER,WALTER G.; LOY,DOUGLAS A.; MCENANEY,BRIAN; MISONO,MAKOTO; MONSON,PETER A.; PEZ,GUIDO; SCHERER,GEORGE W.; VARTULI,JAMES C.; YAGHI,OMAR M.

    1999-11-09

    Tailoring of porous materials involves not only chemical synthetic techniques for tailoring microscopic properties such as pore size, pore shape, pore connectivity, and pore surface reactivity, but also materials processing techniques for tailoring the meso- and the macroscopic properties of bulk materials in the form of fibers, thin films and monoliths. These issues are addressed in the context of five specific classes of porous materials: oxide molecular sieves, porous coordination solids, porous carbons, sol-gel derived oxides, and porous heteropolyanion salts. Reviews of these specific areas are preceded by a presentation of background material and review of current theoretical approaches to adsorption phenomena. A concluding section outlines current research needs and opportunities.

  18. Field determination of the three-dimensional hydraulic conductivity tensor of anisotropic media 2. Methodology and application to fractured rocks.

    USGS Publications Warehouse

    Hsieh, P.A.; Neuman, S.P.; Stiles, G.K.; Simpson, E.S.

    1985-01-01

    The analytical solutions developed in the first paper can be used to interpret the results of cross-hole tests conducted in anisotropic porous or fractured media. Test results from a granitic rock near Oracle in southern Arizona are presented to illustrate how the method works for fractured rocks. At the site, the Oracle granite is shown to respond as a near-uniform, anisotropic medium, the hydraulic conductivity of which is strongly controlled by the orientations of major fracture sets. The cross-hole test results are shown to be consistent with the results of more than 100 single- hole packer tests conducted at the site. -from Authors

  19. Molecular dynamic simulation methods for anisotropic liquids.

    PubMed

    Aoki, Keiko M; Yoneya, Makoto; Yokoyama, Hiroshi

    2004-03-22

    Methods of molecular dynamics simulations for anisotropic molecules are presented. The new methods, with an anisotropic factor in the cell dynamics, dramatically reduce the artifacts related to cell shapes and overcome the difficulties of simulating anisotropic molecules under constant hydrostatic pressure or constant volume. The methods are especially effective for anisotropic liquids, such as smectic liquid crystals and membranes, of which the stacks of layers are compressible (elastic in direction perpendicular to the layers) while the layer itself is liquid and only elastic under uniform compressive force. The methods can also be used for crystals and isotropic liquids as well.

  20. Remarks on inhomogeneous anisotropic cosmology

    NASA Astrophysics Data System (ADS)

    Kaya, Ali

    2016-08-01

    Recently a new no-global-recollapse argument was given for some inhomogeneous and anisotropic cosmologies that utilizes surface deformation by the mean curvature flow. In this paper we discuss important properties of the mean curvature flow of spacelike surfaces in Lorentzian manifolds. We show that singularities may form during cosmic evolution, and the theorems forbidding the global recollapse lose their validity. The time evolution of the spatial scalar curvature that may kinematically prevent the recollapse is determined in normal coordinates, which shows the impact of inhomogeneities explicitly. Our analysis indicates a caveat in numerical solutions that give rise to inflation.

  1. Spin precession in anisotropic cosmologies

    NASA Astrophysics Data System (ADS)

    Kamenshchik, A. Yu.; Teryaev, O. V.

    2016-05-01

    We consider the precession of a Dirac particle spin in some anisotropic Bianchi universes. This effect is present already in the Bianchi-I universe. We discuss in some detail the geodesics and the spin precession for both the Kasner and the Heckmann-Schucking solutions. In the Bianchi-IX universe the spin precession acquires the chaotic character due to the stochasticity of the oscillatory approach to the cosmological singularity. The related helicity flip of fermions in the very early universe may produce the sterile particles contributing to dark matter.

  2. New charged anisotropic compact models

    NASA Astrophysics Data System (ADS)

    Kileba Matondo, D.; Maharaj, S. D.

    2016-07-01

    We find new exact solutions to the Einstein-Maxwell field equations which are relevant in the description of highly compact stellar objects. The relativistic star is charged and anisotropic with a quark equation of state. Exact solutions of the field equations are found in terms of elementary functions. It is interesting to note that we regain earlier quark models with uncharged and charged matter distributions. A physical analysis indicates that the matter distributions are well behaved and regular throughout the stellar structure. A range of stellar masses are generated for particular parameter values in the electric field. In particular the observed mass for a binary pulsar is regained.

  3. Anisotropic inflation from vector impurity

    SciTech Connect

    Kanno, Sugumi; Kimura, Masashi; Soda, Jiro; Yokoyama, Shuichiro E-mail: mkimura@sci.osaka-cu.ac.jp E-mail: shu@a.phys.nagoya-u.ac.jp

    2008-08-15

    We study an inflationary scenario with a vector impurity. We show that the universe undergoes anisotropic inflationary expansion due to a preferred direction determined by the vector. Using the slow roll approximation, we find a formula for determining the anisotropy of the inflationary universe. We discuss possible observable predictions of this scenario. In particular, it is stressed that primordial gravitational waves can be induced from curvature perturbations. Hence, even in low scale inflation, a sizable amount of primordial gravitational waves may be produced during inflation.

  4. Granular Segregation with Anisotropic Particles

    NASA Astrophysics Data System (ADS)

    Sykes, Tim

    2005-11-01

    The results from experimental investigations of horizontally vibrated mixtures of anisotropic poppy seeds and long chains of linked spheres will be presented. A critical packing fraction was observed to be required to initiate a transition to segregation. The average size of the resulting patterns was measured and the concentration ratio of the mixtures was varied by changing the number of chains present in the mixtures. A change in the order of the transition, from second to first order with associated hysteresis, was observed as the chain number was reduced. This gave rise to three distinct regions of behaviour: segregated, mixed and a bi-stable state.

  5. Free convection heat transfer from an isothermal wavy surface in a porous enclosure

    NASA Astrophysics Data System (ADS)

    Rathish Kumar, B. V.; Murthy, P. V. S. N.; Singh, P.

    1998-09-01

    The coupled streamfuction-temperature equations governing the Darcian flow and convection process in a fluid-saturated porous enclosure with an isothermal sinusoidal bottom sun face, has been numerically analyzed using a finite element method (FEM). No restrictions have been imposed on the geometrical non-linearity arising from the parameters like wave amplitude (a), number of waves per unit length (N), wave phase (), aspect ratio (A) and also on the flow driving parameter Rayleigh number (Ra). The numerical simulations for varying values of Ra bring about interesting flow features, like the transformation of a unicellular flow to a multicellular flow. Both with increasing amplitude and increasing number of waves per unit length, owing to the shift in the separation and reattachment points, a row-column pattern of multicellular flow transforms to a simple row of multicellular flow. A cycle of n celluar and n+1 cellular flows, with the flow in adjacent cells in the opposite direction, periodically manifest with phase varying between 0 and 360°. The global heat transfer into the system has been found to decrease with increasing amplitude and increasing number of waves per unit length. Only marginal changes in the global heat flux are observed, either with increasing Ra or varying . Effectively, sinusoidal bottom surface undulations of the isothermal wall of a porous enclosure reduces the heat transfer into the system.

  6. Natural convection heat transfer from a horizontal wavy surface in a porous enclosure

    SciTech Connect

    Murthy, P.V.S.N.; Kumar, B.V.R.; Singh, P.

    1997-02-07

    The effect of surface undulations on the natural convection heat transfer from an isothermal surface in a Darcian fluid-saturated porous enclosure has been numerically analyzed using the finite element method on a graded nonuniform mesh system. The flow-driving Rayleigh number Ra together with the geometrical parameters of wave amplitude a, wave phase {phi}, and the number of waves N considered in the horizontal dimension of the cavity are found to influence the flow and heat transfer process in the enclosure. For Ra around 50 and above, the phenomenon of flow separation and reattachment is noticed on the walls of the enclosure. A periodic shift in the reattachment point from the bottom wall to the adjacent walls in the clockwise direction, leading to the manifestation of cycles of unicellular and bicellular clockwise and counterclockwise flows, is observed, with the phase varying between 0{degree} and 350{degree}. The counterflow in the secondary circulation zone is intensified with the increase in the value of Ra. The counterflow on the wavy wall hinders the heat transfer into the system. An increase in either wave amplitude or the number of waves considered per unit length decreases the global heat flux into the system. Only marginal changes in global heat flux are noticed with increasing Ra. On the whole, the comparison of global heat flux results in the wavy wall case with those of the horizontal flat wall case shows that, in a porous enclosure, the wavy wall reduces the heat transfer into the system.

  7. BISQ model based on a Kelvin-Voigt viscoelastic frame in a partially saturated porous medium

    NASA Astrophysics Data System (ADS)

    Nie, Jian-Xin; Ba, Jing; Yang, Ding-Hui; Yan, Xin-Fei; Yuan, Zhen-Yu; Qiao, Hai-Peng

    2012-06-01

    Taking into account three important porous media mechanisms during wave propagation (the Biot-flow, squirt-flow, and solid-skeleton viscoelastic mechanisms), we introduce water saturation into the dynamic governing equations of wave propagation by analyzing the effective medium theory and then providing a viscoelastic Biot/squirt (BISQ) model which can analyze the wave propagation problems in a partially viscous pore fluid saturated porous media. In this model, the effects of pore fluid distribution patterns on the effective bulk modulus at different frequencies are considered. Then we derive the wave dynamic equations in the time-space domain. The phase velocity and the attenuation coefficient equations of the viscoelatic BISQ model in the frequency-wavenumber domain are deduced through a set of plane harmonic solution assumptions. Finally, by means of numerical simulations, we investigate the effects of water saturation, permeability, and frequency on compressional wave velocity and attenuation. Based on tight sandstone and carbonate experimental observed data, the compressional wave velocities of partially saturated reservoir rocks are calculated. The compressional wave velocity in carbonate reservoirs is more sensitive to gas saturation than in sandstone reservoirs.

  8. Dynamics of shear layers at the interface of a highly porous medium and a pure fluid

    NASA Astrophysics Data System (ADS)

    Antoniadis, P. D.; Papalexandris, M. V.

    2015-01-01

    In this paper, we report on shear flows in domains that contain a macroscopic interface between a highly porous medium and a pure fluid. Our study is based on the single-domain approach, according to which, the same set of governing equations is employed for both inside the porous medium and in the pure-fluid domain. In particular, we introduce a mathematical model for the flows of interest that is derived directly from a continuum theory for fluid-saturated granular materials. The resulting set of equations is a variation of the well-known unsteady Darcy-Brinkman model. First, we employ this model to perform a linear stability analysis of inviscid shear layers over a highly porous medium. Our analysis shows that such layers are unconditionally unstable. Next, we present results from numerical simulations of temporally evolving shear layers in both two and three dimensions. The simulations are performed via a recently designed algorithm that employs a predictor-corrector time-marching scheme and a projection method for the computation of the pressure field on a collocated grid. According to our numerical predictions, the onset of the Kelvin-Helmholtz instability leads to the formation of vortices that extend to both sides of the material interface, thus producing substantial recirculation inside the porous medium. These vortices eventually merge, leading to significant growth of the shear layer and, in three dimensional flows, transition to turbulence. The dynamics of the shear layers, including growth rate and self-similarity, is presented and analysed. Finally, the structure of these layers is described in detail and compared to the one of plain mixing layers.

  9. Identification of the full anisotropic flow resistivity tensor for multiple glass wool and melamine foam samples.

    PubMed

    Van der Kelen, Christophe; Göransson, Peter

    2013-12-01

    The flow resistivity tensor, which is the inverse of the viscous permeability tensor, is one of the most important material properties for the acoustic performance of porous materials used in acoustic treatments. Due to the manufacturing processes involved, these porous materials are most often geometrically anisotropic on a microscopic scale, and for demanding applications, there is a need for improved characterization methods. This paper discusses recent refinements of a method for the identification of the anisotropic flow resistivity tensor. The inverse estimation is verified for three fictitious materials with different degrees of anisotropy. Measurements are performed on nine glass wool samples and seven melamine foam samples, and the anisotropic flow resistivity tensors obtained are validated by comparison to measurements performed on uni-directional cylindrical samples, extracted from the same, previously measured cubic samples. The variability of flow resistivity in the batch of material from which the glass wool is extracted is discussed. The results for the melamine foam suggest that there is a relation between the direction of highest flow resistivity, and the rise direction of the material.

  10. Anisotropic Non-Fermi Liquids

    NASA Astrophysics Data System (ADS)

    Sur, Shouvik; Lee, Sung-Sik

    We study non-Fermi liquids that arise at quantum critical points associated with spin (SDW) and charge density wave (CDW) transitions in metals with twofold rotational symmetry. We use the `codimensional' regularization scheme, where a one-dimensional Fermi surface is embedded in 3 - ɛ dimensional momentum space. In three dimensions, quasilocal marginal Fermi liquids arise at the SDW and CDW critical points. Below three dimensions, a perturbative anisotropic non-Fermi liquid state is realized at the SDW critical point, where not only time but also different spatial coordinates develop distinct anomalous dimensions. The stable non-Fermi liquid exhibits an emergent algebraic nesting as the patches of the Fermi surface are deformed into a universal power-law shape near the hot spots. Due to the anisotropic scaling, the energy of spin fluctuations disperse with different power laws in different momentum directions. In contrast, at the CDW critical point, the perturbative expansion breaks down immediately below three dimensions as the interaction renormalizes the speed of charge fluctuations to zero within a finite renormalization group scale.

  11. Postbuckling of laminated anisotropic panels

    NASA Technical Reports Server (NTRS)

    Jeffrey, Glenda L.

    1987-01-01

    A two-part study of the buckling and postbuckling of laminated anisotropic plates with bending-extensional coupling is presented. The first part involves the development and application of a modified Rayleigh-Ritz analysis technique. Modifications made to the classical technique can be grouped into three areas. First, known symmetries of anisotropic panels are exploited in the selection of approximation functions. Second, a reduced basis technique based on these same symmetries is applied in the linear range. Finally, geometric boundary conditions are enforced via an exterior penalty function approach, rather than relying on choice of approximation functions to satisfy these boundary conditions. Numerical results are presented for both the linear and nonlinear range, with additional studies made to determine the effect of variation in penalty parameter and number of basis vectors. In the second part, six panels possessing anisotropy and bending-extensional coupling are tested. Detailed comparisons are made between experiment and finite element results in order to gain insight into the postbuckling and failure characteristics of such panels. The panels are constructed using two different lamination sequences, and panels with three different aspect ratios were constructed for each lamination sequence.

  12. Cryogenic microwave anisotropic artificial materials

    NASA Astrophysics Data System (ADS)

    Trang, Frank

    This thesis addresses analysis and design of a cryogenic microwave anisotropic wave guiding structure that isolates an antenna from external incident fields from specific directions. The focus of this research is to design and optimize the radome's constituent material parameters for maximizing the isolation between an interior receiver antenna and an exterior transmitter without significantly disturbing the transmitter antenna far field characteristics. The design, characterization, and optimization of high-temperature superconducting metamaterials constitutive parameters are developed in this work at X-band frequencies. A calibrated characterization method for testing arrays of split-ring resonators at cryogenic temperature inside a TE10 waveguide was developed and used to back-out anisotropic equivalent material parameters. The artificial material elements (YBCO split-ring resonators on MgO substrate) are optimized to improve the narrowband performance of the metamaterial radome with respect to maximizing isolation and minimizing shadowing, defined as a reduction of the transmitted power external to the radome. The optimized radome is fabricated and characterized in a parallel plate waveguide in a cryogenic environment to demonstrate the degree of isolation and shadowing resulting from its presence. At 11.12 GHz, measurements show that the HTS metamaterial radome achieved an isolation of 10.5 dB and the external power at 100 mm behind the radome is reduced by 1.9 dB. This work demonstrates the feasibility of fabricating a structure that provides good isolation between two antennas and low disturbance of the transmitter's fields.

  13. Effects of anisotropic dynamics on cosmic strings

    SciTech Connect

    Kunze, Kerstin E.

    2011-08-01

    The dynamics of cosmic strings is considered in anisotropic backgrounds. In particular, the behaviour of infinitely long straight cosmic strings and of cosmic string loops is determined. Small perturbations of a straight cosmic string are calculated. The relevance of these results is discussed with respect to the possible observational imprints of an anisotropic phase on the behaviour of a cosmic string network.

  14. 2-D solution for drying with internal vaporization of anisotropic media

    SciTech Connect

    Perre, P.; Passard, J.

    1999-01-01

    A set of physical assumptions for a straightforward and efficient simulation of the drying of a porous medium submitted to a convective and/or radiative heating is proposed. All of the parameters used are physical (liquid migration coefficient, permeability values along the thickness and the length, thermal conductivity, and external changes), but the relevant geometrical properties (length and thickness of the slab) were also included in the analysis. The 2-D pressure field generated within the medium during the drying process is obtained by using an analytical expression. The treatment of the pressure field, especially for a strongly anisotropic medium, is an important feature of the model, which allows an analytical model for such a complicated porous medium as wood to be used across a wide range of drying conditions. The computer code developed from the proposed formulation permits a complete simulation of the drying process within a few seconds on a personal computer. Different configurations have been tested for both anisotropic (wood) and isotropic (light concrete) porous media. Agreement with the experimental results is reasonable in terms of the observed physical phenomena. For instance, the model highlights dependence of the duration of the first drying rate on both material properties and drying conditions. This new model can be used for a global physical characterization of products by curve fitting and the collated information for the design of dryers.

  15. Ventilation of porous media

    DOEpatents

    Neeper, D.A.

    1994-02-22

    Methods are presented for distributing gases throughout the interstices of porous materials and removing volatile substances from the interstices of porous materials. Continuous oscillation of pressures and flows results in increased penetration of the interstices by flowing gases and increased transport of gaseous components out of the interstices. The invention is particularly useful in soil vapor extraction. 10 figures.

  16. Ventilation of porous media

    DOEpatents

    Neeper, Donald A.

    1994-01-01

    Methods for distributing gases throughout the interstices of porous materials and removing volatile substances from the interstices of porous materials. Continuous oscillation of pressures and flows results in increased penetration of the interstices by flowing gases and increased transport of gaseous components out of the interstices. The invention is particularly useful in soil vapor extraction.

  17. Porous silicon gettering

    SciTech Connect

    Tsuo, Y.S.; Menna, P.; Al-Jassim, M.

    1995-08-01

    We have studied a novel extrinsic gettering method that utilizes the very large surface areas, produced by porous silicon etch on both front and back surfaces of the silicon wafer, as gettering sites. In this method, a simple and low-cost chemical etching is used to generate the porous silicon layers. Then, a high-flux solar furnace (HFSF) is used to provide high-temperature annealing and the required injection of silicon interstitials. The gettering sites, along with the gettered impurities, can be easily removed at the end the process. The porous silicon removal process consists of oxidizing the porous silicon near the end the gettering process followed by sample immersion in HF acid. Each porous silicon gettering process removes up to about 10 {mu}m of wafer thickness. This gettering process can be repeated so that the desired purity level is obtained.

  18. Gravitational baryogenesis after anisotropic inflation

    NASA Astrophysics Data System (ADS)

    Fukushima, Mitsuhiro; Mizuno, Shuntaro; Maeda, Kei-ichi

    2016-05-01

    The gravitational baryogensis may not generate a sufficient baryon asymmetry in the standard thermal history of the Universe when we take into account the gravitino problem. Hence, it has been suggested that anisotropy of the Universe can enhance the generation of the baryon asymmetry through the increase of the time change of the Ricci scalar curvature. We study the gravitational baryogenesis in the presence of anisotropy, which is produced at the end of an anisotropic inflation. Although we confirm that the generated baryon asymmetry is enhanced compared with the original isotropic cosmological model, taking into account the constraint on the anisotropy by the recent CMB observations, we find that it is still difficult to obtain the observed baryon asymmetry only through the gravitational baryogenesis without suffering from the gravitino problem.

  19. Anisotropic scaling of magnetohydrodynamic turbulence.

    PubMed

    Horbury, Timothy S; Forman, Miriam; Oughton, Sean

    2008-10-24

    We present a quantitative estimate of the anisotropic power and scaling of magnetic field fluctuations in inertial range magnetohydrodynamic turbulence, using a novel wavelet technique applied to spacecraft measurements in the solar wind. We show for the first time that, when the local magnetic field direction is parallel to the flow, the spacecraft-frame spectrum has a spectral index near 2. This can be interpreted as the signature of a population of fluctuations in field-parallel wave numbers with a k(-2)_(||) spectrum but is also consistent with the presence of a "critical balance" style turbulent cascade. We also find, in common with previous studies, that most of the power is contained in wave vectors at large angles to the local magnetic field and that this component of the turbulence has a spectral index of 5/3.

  20. Anisotropic invariance in minisuperspace models

    NASA Astrophysics Data System (ADS)

    Chagoya, Javier; Sabido, Miguel

    2016-06-01

    In this paper we introduce invariance under anisotropic transformations to cosmology. This invariance is one of the key ingredients of the theory of quantum gravity at a Lifshitz point put forward by Hořava. We find that this new symmetry in the minisuperspace introduces characteristics to the model that can be relevant in the ultraviolet regime. For example, by canonical quantization we find a Schrödinger-type equation which avoids the problem of frozen time in quantum cosmology. For simple cases we obtain solutions to this quantum equation in a Kantowski–Sachs (KS) minisuperspace. At the classical level, we study KS and Friedmann–Robertson–Walker cosmologies, obtaining modifications to the solutions of general relativity that can be relevant in the early Universe.

  1. Anisotropic charged core envelope star

    NASA Astrophysics Data System (ADS)

    Mafa Takisa, P.; Maharaj, S. D.

    2016-08-01

    We study a charged compact object with anisotropic pressures in a core envelope setting. The equation of state is quadratic in the core and linear in the envelope. There is smooth matching between the three regions: the core, envelope and the Reissner-Nordström exterior. We show that the presence of the electric field affects the masses, radii and compactification factors of stellar objects with values which are in agreement with previous studies. We investigate in particular the effect of electric field on the physical features of the pulsar PSR J1614-2230 in the core envelope model. The gravitational potentials and the matter variables are well behaved within the stellar object. We demonstrate that the radius of the core and the envelope can vary by changing the parameters in the speed of sound.

  2. Anisotropic invariance in minisuperspace models

    NASA Astrophysics Data System (ADS)

    Chagoya, Javier; Sabido, Miguel

    2016-06-01

    In this paper we introduce invariance under anisotropic transformations to cosmology. This invariance is one of the key ingredients of the theory of quantum gravity at a Lifshitz point put forward by Hořava. We find that this new symmetry in the minisuperspace introduces characteristics to the model that can be relevant in the ultraviolet regime. For example, by canonical quantization we find a Schrödinger-type equation which avoids the problem of frozen time in quantum cosmology. For simple cases we obtain solutions to this quantum equation in a Kantowski-Sachs (KS) minisuperspace. At the classical level, we study KS and Friedmann-Robertson-Walker cosmologies, obtaining modifications to the solutions of general relativity that can be relevant in the early Universe.

  3. Modeling of Anisotropic Inelastic Behavior

    SciTech Connect

    Nikkel, D.J.; Nath, D.S.; Brown, A.A.; Casey, J.

    2000-02-25

    An experimental capability, developed at Lawrence Livermore National Laboratory (LLNL), is being used to study the yield behavior of elastic-plastic materials. The objective of our research is to develop better constitutive equations for polycrystalline metals. We are experimentally determining the multidimensional yield surface of the material, both in its initial state and as it evolves during large inelastic deformations. These experiments provide a more complete picture of material behavior than can be obtained from traditional uniaxial tests. Experimental results show that actual material response can differ significantly from that predicted by simple idealized models. These results are being used to develop improved constitutive models of anisotropic plasticity for use in continuum computer codes.

  4. Anisotropic Superfluidity in a Dipolar Bose Gas

    SciTech Connect

    Ticknor, Christopher; Wilson, Ryan M.; Bohn, John L.

    2011-02-11

    We study the superfluid character of a dipolar Bose-Einstein condensate (DBEC) in a quasi-two dimensional geometry. We consider the dipole polarization to have some nonzero projection into the plane of the condensate so that the effective interaction is anisotropic in this plane, yielding an anisotropic dispersion relation. By performing direct numerical simulations of a probe moving through the DBEC, we observe the sudden onset of drag or creation of vortex-antivortex pairs at critical velocities that depend strongly on the direction of the probe's motion. This anisotropy emerges because of the anisotropic manifestation of a rotonlike mode in the system.

  5. Anisotropic optical film embedded with cellulose nanowhisker.

    PubMed

    Kim, Dah Hee; Song, Young Seok

    2015-10-01

    We investigated anisotropic optical behaviors of composite films embedded with CNWs. To control the orientation of CNWs, elongation was applied to the composite film. Morphological and mechanical analyses of the specimens were carried out to examine the influence of the applied extension. The CNWs were found to be aligned in the elongated direction, yielding remarkable anisotropic microstructure and optical properties. As the applied elongation and CNW loading increased, the resulting degree of polarization and birefringence increased due to increased interactions between the embedded particles. This study suggests a way to prepare an anisotropic optical component with nanoparticles of which the microstructures, such as orientation and filler content, can be controlled. PMID:26076646

  6. Anisotropic inflation in Gauss-Bonnet gravity

    NASA Astrophysics Data System (ADS)

    Lahiri, Sayantani

    2016-09-01

    We study anisotropic inflation with Gauss-Bonnet correction in presence of a massless vector field. In this scenario, exact anisotropic power-law inflation is realized when the inflaton potential, gauge coupling function and the Gauss-Bonnet coupling are exponential functions. We show that anisotropy becomes proportional to two slow-roll parameters of the theory and hence gets enhanced in presence of quadratic curvature corrections. The stability analysis reveals that anisotropic power-law solutions remain stable over a substantially large parameter region.

  7. Determination of integral turbulence model parameters as applied to calculation of rod-bundle flows in porous-body approximation

    NASA Astrophysics Data System (ADS)

    Vlasov, M. N.; Korsun, A. S.; Maslov, Yu. A.; Merinov, I. G.; Rachkov, V. I.; Kharitonov, V. S.

    2016-03-01

    In the present paper, results of numerical simulation of single-phase flows of heat carrier through square and triangular rod bundles are reported. The simulations were aimed at the determination of parameters involved in an integral model of turbulence being developed for modeling nuclear-reactor cores and heat exchangers in anisotropic porous-body approximation.

  8. Fabricating porous silicon carbide

    NASA Technical Reports Server (NTRS)

    Shor, Joseph S. (Inventor); Kurtz, Anthony D. (Inventor)

    1994-01-01

    The formation of porous SiC occurs under electrochemical anodization. A sample of SiC is contacted electrically with nickel and placed into an electrochemical cell which cell includes a counter electrode and a reference electrode. The sample is encapsulated so that only a bare semiconductor surface is exposed. The electrochemical cell is filled with an HF electrolyte which dissolves the SiC electrochemically. A potential is applied to the semiconductor and UV light illuminates the surface of the semiconductor. By controlling the light intensity, the potential and the doping level, a porous layer is formed in the semiconductor and thus one produces porous SiC.

  9. Seismic attenuation: Laboratory measurements in fluid saturated rocks

    NASA Astrophysics Data System (ADS)

    Subramaniyan, Shankar; Madonna, Claudio; Tisato, Nicola; Saenger, Erik; Quintal, Beatriz

    2014-05-01

    Seismic wave attenuation could be used as an indicator of reservoir fluids due to its dependence on rock and fluid properties. Over the past 30 years, many laboratory methodologies to study attenuation in rocks have been employed, such as ultrasonic (MHz), resonant bar (kHz) and forced oscillation methods in the low frequency range (0.01-100Hz) (Tisato & Madonna 2012; Madonna & Tisato 2013). Forced oscillation methods have gained prominence over time as the frequency range of measurements correspond to that of field seismic data acquired for oil/gas exploration. These experiments measure attenuation as the phase shift between the applied stress (sinusoidal) and measured strain. Since the magnitudes of measured phase shifts are quite low (Q-1 ~0.01-0.1) and the amplitudes of strain applied to the rock samples are of the order ~10-6 (i.e., similar orders of magnitude to seismic waves), it is challenging. A comparison of such forced oscillation setups will be presented to provide an overview of the various possibilities of design and implementation for future setups. In general, there is a lack of laboratory data and most of the published data are for sandstones. Currently, attenuation measurements are being carried out on carbonate and sandstone samples. We employ the Seismic Wave Attenuation Module (SWAM, Madonna & Tisato 2013) to measure seismic attenuation in these samples for different saturation degrees (90% and 100% water) and under three different confining pressures (5, 10 and 15MPa). Preliminary results from these investigations will be discussed. REFERENCES Madonna, C. & Tisato, N. 2013: A new seismic wave attenuation module to experimentally measure low-frequency attenuation in extensional mode. Geophysical Prospecting, doi: 10.1111/1365-2478.12015. Tisato, N. & Madonna, C. 2012: Attenuation at low seismic frequencies in partially saturated rocks: Measurements and description of a new apparatus. Journal of Applied Geophysics, 86, 44-53.

  10. Discrimination of porosity and fluid saturation using seismic velocity analysis

    DOEpatents

    Berryman, James G.

    2001-01-01

    The method of the invention is employed for determining the state of saturation in a subterranean formation using only seismic velocity measurements (e.g., shear and compressional wave velocity data). Seismic velocity data collected from a region of the formation of like solid material properties can provide relatively accurate partial saturation data derived from a well-defined triangle plotted in a (.rho./.mu., .lambda./.mu.)-plane. When the seismic velocity data are collected over a large region of a formation having both like and unlike materials, the method first distinguishes the like materials by initially plotting the seismic velocity data in a (.rho./.lambda., .mu./.lambda.)-plane to determine regions of the formation having like solid material properties and porosity.

  11. Solidus of carbonated fertile peridotite under fluid-saturated conditions

    SciTech Connect

    Falloon, T.J.; Green, D.H. )

    1990-03-01

    The solidus for a fertile peridotite composition (Hawaiian pyrolite) in the presence of a CO{sub 2}-H{sub 2}O fluid phase has been determined from 10 to 35 kbar. The intersection of the decarbonation reaction (olivine + diopside + CO{sub 2} {l reversible} orthopyroxene + dolomite) with the pyrolite solidus defines the point Q{prime}, located at 22 kbar and 940 C. At pressures less than Q{prime}, the solidus passes through a temperature maximum at kbar, 1060 C. The solidus is coincident with amphibole breakdown at pressures less than 16 kbar. At pressures above Q{prime}, the solidus is defined by the dissolution of crystalline carbonate into a sodic, dolomitic carbonatite melt. The solidus is at a temperature of 925 C at {approximately} 28 kbar. The solidus temperature above the point Q{prime} is similar to the solidus determined for Hawaiian pyrolite-H{sub 2}O-CO{sub 2} for small contents of H{sub 2}O (<0.3 wt%) and CO{sub 2} (<5 wt%), thus indicating that the primary sodic dolomitic carbonatite melt at both solidi has a very low and limited H{sub 2}O solubility. The new data clarify the roles of carbonatite melt, carbonated silicate melt, and H{sub 2}O-rich fluid in mantle conditions that are relatively oxidized (f{sub O{sub 2}} {approximately} MW to FMQ). In particular, a carbonatite melt + garnet lherzolite region is intersected by continental shield geothermal gradients, but such geotherms only intersect regions with carbonated silicate melt if perturbed to higher temperatures (kinked geotherm).

  12. Wettability and fluid saturations determined from NMR T1 distributions.

    PubMed

    Howard, J J

    1994-01-01

    The abundance and distribution of brine and decane are determined from T1 distributions at different stages of a water-flood test in water-wet and oil-wet chalks. The T1 distributions generated from multi-exponential decomposition of inversion-recovery data provide more information than obtained from stretched and bi-exponential fits. Chalk samples because of their uniform pore size and ideal sedimentary rocks for NMR investigations of wettability since water and decane interactions with pore walls of differing wettability are easily distinguished.

  13. Optical trapping of the anisotropic crystal nanorod.

    PubMed

    Bareil, Paul B; Sheng, Yunlong

    2015-05-18

    We observed in the optical tweezers experiment that some anisotropic nanorod was stably trapped in an orientation tiled to the beam axis. We explain this trapping with the T-matrix calculation. As the vector spherical wave functions do not individually satisfy the anisotropic vector wave equation, we expand the incident and scattered fields in the isotropic buffer in terms of E→, and the internal field in the anisotropic nanoparticle in terms of D→, and use the boundary condition for the normal components of D→ to compute the T-matrix. We found that when the optical axes of an anisotropic nanorod are not aligned to the nanorod axis, the nanorod may be trapped stably at a tilted angle, under which the lateral torque equals to zero and the derivative of the torque is negative. PMID:26074566

  14. Strongly Anisotropic Bianchi i Quantum Cosmology

    NASA Astrophysics Data System (ADS)

    Schmidt, Hans-Jürgen

    2002-12-01

    We report on the period-doubling bifurcation recently detected for strongly anisotropic Bianchi I quantum cosmology by M. Bachmann and H.-J. Schmidt and present further arguments related to the quantum boundary.

  15. Inflation in anisotropic scalar-tensor theories

    NASA Technical Reports Server (NTRS)

    Pimentel, Luis O.; Stein-Schabes, Jaime

    1988-01-01

    The existence of an inflationary phase in anisotropic Scalar-Tensor Theories is investigated by means of a conformal transformation that allows us to rewrite these theories as gravity minimally coupled to a scalar field with a nontrivial potential. The explicit form of the potential is then used and the No Hair Theorem concludes that there is an inflationary phase in all open or flat anisotropic spacetimes in these theories. Several examples are constructed where the effect becomes manifest.

  16. Phase space analysis in anisotropic optical systems

    NASA Technical Reports Server (NTRS)

    Rivera, Ana Leonor; Chumakov, Sergey M.; Wolf, Kurt Bernardo

    1995-01-01

    From the minimal action principle follows the Hamilton equations of evolution for geometric optical rays in anisotropic media. As in classical mechanics of velocity-dependent potentials, the velocity and the canonical momentum are not parallel, but differ by an anisotropy vector potential, similar to that of linear electromagnetism. Descartes' well known diagram for refraction is generalized and a factorization theorem holds for interfaces between two anisotropic media.

  17. Overview of anisotropic flow measurements from ALICE

    NASA Astrophysics Data System (ADS)

    Zhou, You

    2016-05-01

    Anisotropic flow is an important observable to study the properties of the hot and dense matter, the Quark Gluon Plasma (QGP), created in heavy-ion collisions. Measurements of anisotropic flow for inclusive and identified charged hadrons are reported in Pb-Pb, p-Pb and pp collisions with the ALICE detector. The comparison of experimental measurements to various theoretical calculations are also presented in these proceedings.

  18. Polarisation reflectometry of anisotropic optical fibres

    SciTech Connect

    Konstantinov, Yurii A; Kryukov, Igor' I; Pervadchuk, Vladimir P; Toroshin, Andrei Yu

    2009-11-30

    Anisotropic, polarisation-maintaining fibres have been studied using a reflectometer and integrated optic polariser. Linearly polarised pulses were launched into the fibre under test at different angles between their plane of polarisation and the main optical axis of the fibre. A special procedure for the correlation analysis of these reflectograms is developed to enhance the reliability of the information about the longitudinal optical uniformity of anisotropic fibres. (optical fibres and fibreoptic sensors)

  19. Modelling Coulomb Collisions in Anisotropic Plasmas

    NASA Astrophysics Data System (ADS)

    Hellinger, P.; Travnicek, P. M.

    2009-12-01

    Collisional transport in anisotropic plasmas is investigated comparing the theoretical transport coefficients (Hellinger and Travnicek, 2009) for anisotropic particles with the results of the corresponding Langevin equation, obtained as a generalization of Manheimer et al. (1997). References: Hellinger, P., and P. M. Travnicek (2009), On Coulomb collisions in bi-Maxwellian plasmas, Phys. Plasmas, 16, 054501. Manheimer, W. M., M. Lampe and G. Joyce (1997), Langevin representation of Coulomb collisions in PIC simulations, J. Comput. Phys., 138, 563-584.

  20. Soft particles with anisotropic interactions

    NASA Astrophysics Data System (ADS)

    Schurtenberger, Peter

    Responsive colloids such as thermo- or pH-sensitive microgels are ideal model systems to investigate the relationship between the nature of interparticle interactions and the plethora of self-assembled structures that can form in colloidal suspensions. They allow for a variation of the form, strength and range of the interaction potential almost at will. While microgels have extensively been used as model systems to investigate various condensed matter problems such as glass formation, jamming or crystallization, they can also be used to study systems with anisotropic interactions. Here we show results from a systematic investigation of the influence of softness and anisotropy on the structural and dynamic properties of strongly interacting suspensions. We focus first on ionic microgels. Due to their large number of internal counterions they possess very large polarisabilities, and we can thus use external electrical ac fields to generate large dipolar contributions to the interparticle interaction potential. This leads to a number of new crystal phases, and we can trigger crystal-crystal phase transitions through the appropriate choice of the field strength. We then show that this approach can be extended to more complex particle shapes in an attempt to copy nature's well documented success in fabricating complex nanostructures such as virus shells via self assembly. European Research Council (ERC-339678-COMPASS).

  1. Anisotropic diffusion-limited aggregation.

    PubMed

    Popescu, M N; Hentschel, H G E; Family, F

    2004-06-01

    Using stochastic conformal mappings, we study the effects of anisotropic perturbations on diffusion-limited aggregation (DLA) in two dimensions. The harmonic measure of the growth probability for DLA can be conformally mapped onto a constant measure on a unit circle. Here we map m preferred directions for growth to a distribution on the unit circle, which is a periodic function with m peaks in [-pi,pi) such that the angular width sigma of the peak defines the "strength" of anisotropy kappa= sigma(-1) along any of the m chosen directions. The two parameters (m,kappa) map out a parameter space of perturbations that allows a continuous transition from DLA (for small enough kappa ) to m needlelike fingers as kappa--> infinity. We show that at fixed m the effective fractal dimension of the clusters D(m,kappa) obtained from mass-radius scaling decreases with increasing kappa from D(DLA) approximately 1.71 to a value bounded from below by D(min) = 3 / 2. Scaling arguments suggest a specific form for the dependence of the fractal dimension D(m,kappa) on kappa for large kappa which compares favorably with numerical results. PMID:15244564

  2. Magnetospheric equilibrium with anisotropic pressure

    SciTech Connect

    Cheng, C.Z.

    1991-07-01

    Self-consistent magnetospheric equilibrium with anisotropic pressure is obtained by employing an iterative metric method for solving the inverse equilibrium equation in an optimal flux coordinate system. A method of determining plasma parallel and perpendicular pressures from either analytic particle distribution or particle distribution measured along the satellite's path is presented. The numerical results of axisymmetric magnetospheric equilibrium including the effects of finite beta, pressure anisotropy, and boundary conditions are presented for a bi-Maxwellian particle distribution. For the isotropic pressure cases, the finite beta effect produces an outward expansion of the constant magnetic flux surfaces in relation to the dipole field lines, and along the magnetic field the toroidal ring current is maximum at the magnetic equator. The effect of pressure anisotropy is found to further expand the flux surfaces outward. Along the magnetic field lines the westward ring current can be peak away from the equator due to an eastward current contribution resulting from pressure anisotropy. As pressure anisotropy increases, the peak westward current can become more singular. The outer boundary flux surface has significant effect on the magnetospheric equilibrium. For the outer flux boundary resembling dayside compressed flux surface due to solar wind pressure, the deformation of the magnetic field can be quite different from that for the outer flux boundary resembling the tail-like surface. 23 refs., 17 figs.

  3. Modeling of anisotropic wound healing

    NASA Astrophysics Data System (ADS)

    Valero, C.; Javierre, E.; García-Aznar, J. M.; Gómez-Benito, M. J.; Menzel, A.

    2015-06-01

    Biological soft tissues exhibit non-linear complex properties, the quantification of which presents a challenge. Nevertheless, these properties, such as skin anisotropy, highly influence different processes that occur in soft tissues, for instance wound healing, and thus its correct identification and quantification is crucial to understand them. Experimental and computational works are required in order to find the most precise model to replicate the tissues' properties. In this work, we present a wound healing model focused on the proliferative stage that includes angiogenesis and wound contraction in three dimensions and which relies on the accurate representation of the mechanical behavior of the skin. Thus, an anisotropic hyperelastic model has been considered to analyze the effect of collagen fibers on the healing evolution of an ellipsoidal wound. The implemented model accounts for the contribution of the ground matrix and two mechanically equivalent families of fibers. Simulation results show the evolution of the cellular and chemical species in the wound and the wound volume evolution. Moreover, the local strain directions depend on the relative wound orientation with respect to the fibers.

  4. Metal filled porous carbon

    DOEpatents

    Gross, Adam F.; Vajo, John J.; Cumberland, Robert W.; Liu, Ping; Salguero, Tina T.

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  5. Dilution and reactive mixing in three-dimensional helical flows in porous media

    NASA Astrophysics Data System (ADS)

    Chiogna, Gabriele; Ye, Yu; Grathwohl, Peter; Cirpka, Olaf A.; Rolle, Massimo

    2016-04-01

    Dilution under steady-state flow and transport conditions in porous media occurs primarily by lateral mass exchange at the fringe of solute plumes. This process controls the fate and transport of scalars in groundwater and in chemical reactors and it is fundamental for the understanding of many reactive processes. Three-dimensional flow fields can be characterized by a complex topological structure, which may greatly influence dilution and dilution enhancement of dissolved plumes, which is quantified by the exponential of the Shannon entropy [1]. In previous works, we identified the necessary conditions to obtain helical flow fields in non-stationary anisotropic heterogeneous porous media [2, 3]. To prove our theoretical findings, we perform steady-state bench-scale experiments with a conservative tracer and we provide a model-based investigation of the results [4]. The relevance of transverse mixing enhancement for the case of reactive solute transport is computed numerically using, as metrics of mixing, the length of a reactive plume undergoing an instantaneous complete bimolecular reaction and its critical dilution index. [1] Cirpka O.A., Chiogna G., Rolle M. and A. Bellin (2015). Transverse mixing in three-dimensional non-stationary anisotropic heterogeneous porous media. Water Resources Research, 51, DOI: 10.1002/2014WR015331. [2] Chiogna G., Cirpka O.A., Rolle M. and A. Bellin (2015). Helical flow streamlines in three-dimensional nonstationary anisotropic heterogeneous porous media. Water Resources Research, 51, DOI:10.1002/2014WR015330. [3] Chiogna G., Rolle M., Bellin A. and O.A. Cirpka (2014). Helicity and flow topology in three dimensional porous media. Advances in Water Resources, 73, 134-143, DOI: 10.1016/j.advwatres.2014.06.017. [4] Ye Y., Chiogna G., Cirpka O.A., Grathwohl P., and M. Rolle (2015). Experimental evidence of helical flow in porous media. Phys. Rev. Lett., 115, 194502, DOI: 10.1103/PhysRevLett.115.194502

  6. Gaseous NH3 Confers Porous Pt Nanodendrites Assisted by Halides

    PubMed Central

    Lu, Shuanglong; Eid, Kamel; Li, Weifeng; Cao, Xueqin; Pan, Yue; Guo, Jun; Wang, Liang; Wang, Hongjing; Gu, Hongwei

    2016-01-01

    Tailoring the morphology of Pt nanocrystals (NCs) is of great concern for their enhancement in catalytic activity and durability. In this article, a novel synthetic strategy is developed to selectively prepare porous dendritic Pt NCs with different structures for oxygen reduction reaction (ORR) assisted by NH3 gas and halides (F−, Cl−, Br−). The NH3 gas plays critical roles on tuning the morphology. Previously, H2 and CO gas are reported to assist the shape control of metallic nanocrystals. This is the first demonstration that NH3 gas assists the Pt anisotropic growth. The halides also play important role in the synthetic strategy to regulate the formation of Pt NCs. As-made porous dendritic Pt NCs, especially when NH4F is used as a regulating reagent, show superior catalytic activity for ORR compared with commercial Pt/C catalyst and other previously reported Pt-based NCs. PMID:27184228

  7. Gaseous NH3 Confers Porous Pt Nanodendrites Assisted by Halides

    NASA Astrophysics Data System (ADS)

    Lu, Shuanglong; Eid, Kamel; Li, Weifeng; Cao, Xueqin; Pan, Yue; Guo, Jun; Wang, Liang; Wang, Hongjing; Gu, Hongwei

    2016-05-01

    Tailoring the morphology of Pt nanocrystals (NCs) is of great concern for their enhancement in catalytic activity and durability. In this article, a novel synthetic strategy is developed to selectively prepare porous dendritic Pt NCs with different structures for oxygen reduction reaction (ORR) assisted by NH3 gas and halides (F‑, Cl‑, Br‑). The NH3 gas plays critical roles on tuning the morphology. Previously, H2 and CO gas are reported to assist the shape control of metallic nanocrystals. This is the first demonstration that NH3 gas assists the Pt anisotropic growth. The halides also play important role in the synthetic strategy to regulate the formation of Pt NCs. As-made porous dendritic Pt NCs, especially when NH4F is used as a regulating reagent, show superior catalytic activity for ORR compared with commercial Pt/C catalyst and other previously reported Pt-based NCs.

  8. Scalar field in the anisotropic universe

    SciTech Connect

    Kim, Hyeong-Chan; Minamitsuji, Masato

    2010-04-15

    We discuss the primordial spectrum of a massless and minimally coupled scalar field, produced during the initial anisotropic epoch before the onset of inflation. We consider two models of the anisotropic cosmology, the (planar) Kasner-de Sitter solution (Bianchi I) and the Taub-NUT-de Sitter solution (Bianchi IX), where the 3-space geometry is initially anisotropic, followed by the de Sitter phase due to the presence of a positive cosmological constant. We discuss the behavior of a quantized, massless and minimally coupled scalar field in the anisotropic stage. This scalar field is not the inflaton and hence does not contribute to the background dynamics. We focus on the quantization procedure and evolution in the preinflationary anisotropic background. Also, in this paper for simplicity the metric perturbations are not taken into account. The initial condition is set by the requirement that the scalar field is initially in an adiabatic state. Usually, in a quantum harmonic oscillator system, an adiabatic process implies the one where the potential changes slowly enough compared to its size, and the time evolution can be obtained from the zeroth order WKB approximation. In our case, such a vacuum state exists only for limited solutions of the anisotropic universe, whose spacetime structure is regular in the initial times. In this paper, we call our adiabatic vacuum state the anisotropic vacuum. In the Kasner-de Sitter model, for one branch of planar solutions there is an anisotropic vacuum unless k{sub 3{ne}}0, where k{sub 3} is the comoving momentum along the third direction, while in the other branch there is no anisotropic vacuum state. In the first branch, for the moderate modes, k{sub 3{approx}}k, where k is the total comoving momentum, the scalar power spectrum has an oscillatory behavior and its direction dependence is suppressed. For the planar modes, k{sub 3}<

  9. A dynamic pressure view cell for acoustic stimulation of fluids—Micro-bubble generation and fluid movement in porous media

    NASA Astrophysics Data System (ADS)

    Stewart, Robert A.; Shaw, J. M.

    2015-09-01

    The development and baseline operation of an acoustic view cell for observing fluids, and fluid-fluid and fluid-solid interfaces in porous media over the frequency range of 10-5000 Hz is described. This range includes the industrially relevant frequency range 500-5000 Hz that is not covered by existing devices. Pressure waveforms of arbitrary shape are generated in a 17.46 mm ID by 200 mm and 690.5 mm long glass tubes at flow rates up to 200 ml/min using a syringe pump. Peak-to-peak amplitudes exceeding 80 kPa are readily realized at frequencies from 10 to 5000 Hz in bubble free fluids when actuated with 20 Vpp as exemplified using castor oil. At resonant frequencies, peak-to-peak pressure amplitudes exceeding 500 kPa were obtained (castor oil at 2100 Hz when actuated with 20 Vpp). Impacts of vibration on macroscopic liquid-liquid and liquid-vapour interfaces and interface movement are illustrated. Pressure wave transmission and attenuation in a fluid saturated porous medium, randomly packed 250-330 μm spherical silica beads, is also demonstrated. Attenuation differences and frequency shifts in resonant peaks are used to detect the presence and generation of dispersed micro-bubbles (<180 μm diameter), and bubbles within porous media that are not readily visualized. Envisioned applications include assessment of the impacts of vibration on reaction, mass transfer, and flow/flow pattern outcomes. This knowledge will inform laboratory and pilot scale process studies, where nuisance vibrations may affect the interpretation of process outcomes, and large scale or in situ processes in aquifers or hydrocarbon reservoirs where imposed vibration may be deployed to improve aspects of process performance. Future work will include miscible interface observation and quantitative measurements in the bulk and in porous media where the roles of micro-bubbles comprise subjects of special interest.

  10. A dynamic pressure view cell for acoustic stimulation of fluids--Micro-bubble generation and fluid movement in porous media.

    PubMed

    Stewart, Robert A; Shaw, J M

    2015-09-01

    The development and baseline operation of an acoustic view cell for observing fluids, and fluid-fluid and fluid-solid interfaces in porous media over the frequency range of 10-5000 Hz is described. This range includes the industrially relevant frequency range 500-5000 Hz that is not covered by existing devices. Pressure waveforms of arbitrary shape are generated in a 17.46 mm ID by 200 mm and 690.5 mm long glass tubes at flow rates up to 200 ml/min using a syringe pump. Peak-to-peak amplitudes exceeding 80 kPa are readily realized at frequencies from 10 to 5000 Hz in bubble free fluids when actuated with 20 Vpp as exemplified using castor oil. At resonant frequencies, peak-to-peak pressure amplitudes exceeding 500 kPa were obtained (castor oil at 2100 Hz when actuated with 20 Vpp). Impacts of vibration on macroscopic liquid-liquid and liquid-vapour interfaces and interface movement are illustrated. Pressure wave transmission and attenuation in a fluid saturated porous medium, randomly packed 250-330 μm spherical silica beads, is also demonstrated. Attenuation differences and frequency shifts in resonant peaks are used to detect the presence and generation of dispersed micro-bubbles (<180 μm diameter), and bubbles within porous media that are not readily visualized. Envisioned applications include assessment of the impacts of vibration on reaction, mass transfer, and flow/flow pattern outcomes. This knowledge will inform laboratory and pilot scale process studies, where nuisance vibrations may affect the interpretation of process outcomes, and large scale or in situ processes in aquifers or hydrocarbon reservoirs where imposed vibration may be deployed to improve aspects of process performance. Future work will include miscible interface observation and quantitative measurements in the bulk and in porous media where the roles of micro-bubbles comprise subjects of special interest.

  11. Anisotropic membranes for gas separation

    DOEpatents

    Gollan, A.Z.

    1987-07-21

    A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7--25 C and then air dried at ambient temperature, typically 10--30 C. 2 figs.

  12. Anisotropic membranes for gas separation

    DOEpatents

    Gollan, Arye Z.

    1987-01-01

    A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7.degree.-25.degree. C. and then air dried at ambient temperature, typically 10.degree.-30.degree. C.

  13. Low-frequency Stoneley wave propagation at the interface of two porous half-spaces

    NASA Astrophysics Data System (ADS)

    Markov, M. G.

    2009-05-01

    The Frenkel-Biot theory is used to study a propagation of Stoneley elastic wave at the boundary of two fluid-saturated porous media. The velocity and attenuation of the Stoneley surface wave are determined. I show that the dispersion equation coincides with the equation for the Stoneley wave at the interface of two elastic half-spaces in the low-frequency range. Numerical examples of calculations are presented for two important cases: two different fluids lying in the same viscoelastic skeleton (gas-water interface) and two poroelastic half-spaces with different porosity and permeability containing the same fluid. To take into account the absorption in the solid matrix, I use well-known Stoll's model. Our calculation results have shown that the Stoneley wave absorption is determined by the energy dissipation in the solid matrix for consolidated rocks. As the frequency is increased, hydrodynamic effects connected with the presence of a movable fluid in the pores begin to play a significant role.

  14. Tracking interface and common curve dynamics for two-fluid flow in porous media

    DOE PAGES

    Mcclure, James E.; Miller, Cass T.; Gray, W. G.; Berrill, Mark A.

    2016-04-29

    Pore-scale studies of multiphase flow in porous medium systems can be used to understand transport mechanisms and quantitatively determine closure relations that better incorporate microscale physics into macroscale models. Multiphase flow simulators constructed using the lattice Boltzmann method provide a means to conduct such studies, including both the equilibrium and dynamic aspects. Moving, storing, and analyzing the large state space presents a computational challenge when highly-resolved models are applied. We present an approach to simulate multiphase flow processes in which in-situ analysis is applied to track multiphase flow dynamics at high temporal resolution. We compute a comprehensive set of measuresmore » of the phase distributions and the system dynamics, which can be used to aid fundamental understanding and inform closure relations for macroscale models. The measures computed include microscale point representations and macroscale averages of fluid saturations, the pressure and velocity of the fluid phases, interfacial areas, interfacial curvatures, interface and common curve velocities, interfacial orientation tensors, phase velocities and the contact angle between the fluid-fluid interface and the solid surface. Test cases are studied to validate the approach and illustrate how measures of system state can be obtained and used to inform macroscopic theory.« less

  15. Time dependence of the probability to return to the origin for diffusive motion in porous media

    NASA Astrophysics Data System (ADS)

    Schwartz, L.; Hurlimann, M.; Dunn, K.; Mitra, P..; Bregmann, D.

    1996-03-01

    Pulsed field gradient spin echo (PGSE) magnetic resonance measurements on fluid saturated porous media, provide a natural framework for the examination of a classic problem of mathematical physics. We examine the overall time dependence of the return to the origin probability with particular emphasis on the intermediate and long time behavior.^1 In the long time limit this probability is related to the electrical conductivity. In periodic geometries we compare the results of eigenvalue expansions and numerical simulations. Here we find that, when the diffusion length is roughly equal to a pore diameter, the normalized probability to return to the origin, P_s(t), shows a maximum. Thus, the approach to the long time limit is not monotonic. For disordered systems, simulations and experiments are found to be in agreement and again suggest that the behavoir of P_s(t) is not monotonic. ^1 P. P. Mitra, L. L. Latour, R. L. Kleinberg and C. H. Sotak, J. Mag. Resonance A114, 47 (1995); M. D. Hürlimann, L. M. Schwartz, and Pabitra N. Sen, Phys. Rev. B 51, 14936 (1995).

  16. Anisotropic nanomaterials: structure, growth, assembly, and functions

    PubMed Central

    Sajanlal, Panikkanvalappil R.; Sreeprasad, Theruvakkattil S.; Samal, Akshaya K.; Pradeep, Thalappil

    2011-01-01

    Comprehensive knowledge over the shape of nanomaterials is a critical factor in designing devices with desired functions. Due to this reason, systematic efforts have been made to synthesize materials of diverse shape in the nanoscale regime. Anisotropic nanomaterials are a class of materials in which their properties are direction-dependent and more than one structural parameter is needed to describe them. Their unique and fine-tuned physical and chemical properties make them ideal candidates for devising new applications. In addition, the assembly of ordered one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) arrays of anisotropic nanoparticles brings novel properties into the resulting system, which would be entirely different from the properties of individual nanoparticles. This review presents an overview of current research in the area of anisotropic nanomaterials in general and noble metal nanoparticles in particular. We begin with an introduction to the advancements in this area followed by general aspects of the growth of anisotropic nanoparticles. Then we describe several important synthetic protocols for making anisotropic nanomaterials, followed by a summary of their assemblies, and conclude with major applications. PMID:22110867

  17. Anisotropic matching principle for the hydrodynamic expansion

    NASA Astrophysics Data System (ADS)

    Tinti, Leonardo

    2016-10-01

    Following the recent success of anisotropic hydrodynamics, I propose here a new, general prescription for the hydrodynamic expansion around an anisotropic background. The anisotropic distribution fixes exactly the complete energy-momentum tensor, just like the effective temperature fixes the proper energy density in the ordinary expansion around local equilibrium. This means that momentum anisotropies are already included at the leading order, allowing for large pressure anisotropies without the need of a next-to-leading-order treatment. The first moment of the Boltzmann equation (local four-momentum conservation) provides the time evolution of the proper energy density and the four-velocity. Differently from previous prescriptions, the dynamic equations for the pressure corrections are not derived from the zeroth or second moment of the Boltzmann equation, but they are taken directly from the exact evolution given by the Boltzmann equation. As known in the literature, the exact evolution of the pressure corrections involves higher moments of the Boltzmann distribution, which cannot be fixed by the anisotropic distribution alone. Neglecting the next-to-leading-order contributions corresponds to an approximation, which depends on the chosen form of the anisotropic distribution. I check the the effectiveness of the leading-order expansion around the generalized Romatschke-Stricklad distribution, comparing with the exact solution of the Boltzmann equation in the Bjorken limit with the collisional kernel treated in the relaxation-time approximation, finding an unprecedented agreement.

  18. Mie scattering by a uniaxial anisotropic sphere

    SciTech Connect

    Geng Youlin; Wu Xinbao; Li Lewei; Guan Boran

    2004-11-01

    The field solution to the electromagnetic scattering of a plane wave by a uniaxial anisotropic sphere is obtained in terms of a spherical vector wave function expansion form. Using the source-free Maxwell's equations for uniaxial anisotropic media and making the Fourier transform of the field quantities, the electromagnetic fields in the spectral domain in uniaxial anisotropic media are assumed to have a form similar to the plane wave expanded also in terms of the spherical vector wave functions. Applying the continuous boundary conditions of electromagnetic fields on the surface between the air region and uniaxial anisotropic sphere, the coefficients of transmitted fields and the scattered fields in uniaxial anisotropic media can be obtained analytically in the expansion form of vector wave eigenfunctions. Numerical results for some special cases are obtained and compared with those of the classical Lorenz-Mie theory and the method of moments accelerated with the conjugate-gradient fast-Fourier-transform approach. We also present some new numerical results for the more general uniaxial dielectric material media.

  19. Mie scattering by a uniaxial anisotropic sphere.

    PubMed

    Geng, You-Lin; Wu, Xin-Bao; Li, Le-Wei; Guan, Bo-Ran

    2004-11-01

    The field solution to the electromagnetic scattering of a plane wave by a uniaxial anisotropic sphere is obtained in terms of a spherical vector wave function expansion form. Using the source-free Maxwell's equations for uniaxial anisotropic media and making the Fourier transform of the field quantities, the electromagnetic fields in the spectral domain in uniaxial anisotropic media are assumed to have a form similar to the plane wave expanded also in terms of the spherical vector wave functions. Applying the continuous boundary conditions of electromagnetic fields on the surface between the air region and uniaxial anisotropic sphere, the coefficients of transmitted fields and the scattered fields in uniaxial anisotropic media can be obtained analytically in the expansion form of vector wave eigenfunctions. Numerical results for some special cases are obtained and compared with those of the classical Lorenz-Mie theory and the method of moments accelerated with the conjugate-gradient fast-Fourier-transform approach. We also present some new numerical results for the more general uniaxial dielectric material media.

  20. Minimization principles for the coupled problem of Darcy-Biot-type fluid transport in porous media linked to phase field modeling of fracture

    NASA Astrophysics Data System (ADS)

    Miehe, Christian; Mauthe, Steffen; Teichtmeister, Stephan

    2015-09-01

    This work develops new minimization and saddle point principles for the coupled problem of Darcy-Biot-type fluid transport in porous media at fracture. It shows that the quasi-static problem of elastically deforming, fluid-saturated porous media is related to a minimization principle for the evolution problem. This two-field principle determines the rate of deformation and the fluid mass flux vector. It provides a canonically compact model structure, where the stress equilibrium and the inverse Darcy's law appear as the Euler equations of a variational statement. A Legendre transformation of the dissipation potential relates the minimization principle to a characteristic three field saddle point principle, whose Euler equations determine the evolutions of deformation and fluid content as well as Darcy's law. A further geometric assumption results in modified variational principles for a simplified theory, where the fluid content is linked to the volumetric deformation. The existence of these variational principles underlines inherent symmetries of Darcy-Biot theories of porous media. This can be exploited in the numerical implementation by the construction of time- and space-discrete variational principles, which fully determine the update problems of typical time stepping schemes. Here, the proposed minimization principle for the coupled problem is advantageous with regard to a new unconstrained stable finite element design, while space discretizations of the saddle point principles are constrained by the LBB condition. The variational principles developed provide the most fundamental approach to the discretization of nonlinear fluid-structure interactions, showing symmetric systems in algebraic update procedures. They also provide an excellent starting point for extensions towards more complex problems. This is demonstrated by developing a minimization principle for a phase field description of fracture in fluid-saturated porous media. It is designed for an

  1. Direct Template Approach for the Formation of (Anisotropic shape) Hollow Silicate Microparticles

    NASA Astrophysics Data System (ADS)

    Rivera Virtudazo, R. V.; Watanabe, H.; Shirai, T.; Fuji, M.; Takahashi, M.

    2011-10-01

    Non-uniform bulk or surface morphology of hollow particles has been an emerging interest because of the potential applications involving chemical storage, delivery and self-assembly for novel functional materials. There had been reports that experimental anisotropic (non-uniform) particles are much more difficult than synthesizing particles with uniform bulk and surface. Hence, this study reported a simple direct approach for the formation of unique hollow anisotropic amorphous silicate microparticles (10 to 20 μm). This was successfully prepared at room temperature via hydrolysis and condensation of tetraethylorthosilicate (TEOS), with ammonia water (NH4OH) as catalyst, ethanol (EtOH) and inorganic micro-size calcium carbonate (CaCO3) as template. The molar ratio used was 1.88:28.85:1:2.85 (CaCO3: EtOH: TEOS: NH4OH), mixed/stirred (at room temperature for 2 h), then filtered/washed by ethanol/water, after then dried and acid treated (3.0 mole/L) to obtained a micro-sized hollow SiO2 particles. This simple approach for the formation of unique anisotropic shape hollow silicate micro-sized particles can be a good alternative for a possible application as large porous carrier for nanoparticles (large drug delivery (LPP's)).

  2. Porous silicon nanowires.

    PubMed

    Qu, Yongquan; Zhou, Hailong; Duan, Xiangfeng

    2011-10-01

    In this mini-review, we summarize recent progress in the synthesis, properties and applications of a new type of one-dimensional nanostructures-single crystalline porous silicon nanowires. The growth of porous silicon nanowires starting from both p- and n-type Si wafers with a variety of dopant concentrations can be achieved through either one-step or two-step reactions. The mechanistic studies indicate the dopant concentration of Si wafers, oxidizer concentration, etching time and temperature can affect the morphology of the as-etched silicon nanowires. The porous silicon nanowires are both optically and electronically active and have been explored for potential applications in diverse areas including photocatalysis, lithium ion batteries, gas sensors and drug delivery.

  3. Foams in porous media

    SciTech Connect

    Marsden, S.S.

    1986-07-01

    In 1978 a literature search on selective blocking of fluid flow in porous media was done by Professor S.S. Marsden and two of his graduate students, Tom Elson and Kern Huppy. This was presented as SUPRI Report No. TR-3 entitled ''Literature Preview of the Selected Blockage of Fluids in Thermal Recovery Projects.'' Since then a lot of research on foam in porous media has been done on the SUPRI project and a great deal of new information has appeared in the literature. Therefore we believed that a new, up-to-date search should be done on foam alone, one which would be helpful to our students and perhaps of interest to others. This is a chronological survey showing the development of foam flow, blockage and use in porous media, starting with laboratory studies and eventually getting into field tests and demonstrations. It is arbitrarily divided into five-year time periods. 81 refs.

  4. Porous material neutron detector

    DOEpatents

    Diawara, Yacouba; Kocsis, Menyhert

    2012-04-10

    A neutron detector employs a porous material layer including pores between nanoparticles. The composition of the nanoparticles is selected to cause emission of electrons upon detection of a neutron. The nanoparticles have a maximum dimension that is in the range from 0.1 micron to 1 millimeter, and can be sintered with pores thereamongst. A passing radiation generates electrons at one or more nanoparticles, some of which are scattered into a pore and directed toward a direction opposite to the applied electrical field. These electrons travel through the pore and collide with additional nanoparticles, which generate more electrons. The electrons are amplified in a cascade reaction that occurs along the pores behind the initial detection point. An electron amplification device may be placed behind the porous material layer to further amplify the electrons exiting the porous material layer.

  5. FLUID TRANSPORT THROUGH POROUS MEDIA

    EPA Science Inventory

    Fluid transport through porous media is a relevant topic to many scientific and engineering fields. Soil scientists, civil engineers, hydrologists and hydrogeologists are concerned with the transport of water, gases and nonaqueous phase liquid contaminants through porous earth m...

  6. Modeling isothermal and non-isothermal flows in porous media

    NASA Astrophysics Data System (ADS)

    Mohseni Languri, Ehsan

    2011-12-01

    solutions obtained after applying the stress-continuity and stress-jump boundary conditions are found to work well at low porosities, which is in contradiction with the results achieved earlier by other researchers. The traditional approach of using averaged equations in the regions of sharp gradients in porous media to describe flow and transport is theoretically untenable and perhaps inaccurate. A novel ensemble averaging method is being proposed to test the accuracy of the volume averaged or smoothed description of flows in porous media in the regions of sharp gradients. In the new method, the flow in a certain arrangement of particles (called a realization) is averaged using a small unit cell, much smaller than the REV. Then such an averaged flow variable is further averaged over a whole gamut of randomly-generated particle realizations. First the accuracy of the ensemble averaging method was tested by comparing the permeability of an artificially generated porous medium obtained by the proposed method against the permeability predicted by some established theoretical models of permeability. The proposed method was found to be quite accurate. Later the ensemble average method was applied to the open-channel porous-medium interface region characterized by a sharp gradient in the flow velocities. It was discovered that the volume averaged description of such flows, characterized by the use of the Brinkman equation along with the stress-continuity and stress-jump conditions, is quite accurate for a range of Reynolds numbers. The non-isothermal transport during flow in porous media is examined next. The main focus in this area of research is the thermal dispersion term found in the heat transfer equation for single- and dual-scale porous media. Most of the previous efforts on modeling the heat transfer phenomena in porous media were devoted to isotropic porous media. However, for the anisotropic porous media widely in many industrial applications, not much research on the

  7. Anisotropic magnetoresistance in an antiferromagnetic semiconductor.

    PubMed

    Fina, I; Marti, X; Yi, D; Liu, J; Chu, J H; Rayan-Serrao, C; Suresha, S; Shick, A B; Zelezný, J; Jungwirth, T; Fontcuberta, J; Ramesh, R

    2014-01-01

    Recent studies in devices comprising metal antiferromagnets have demonstrated the feasibility of a novel spintronic concept in which spin-dependent phenomena are governed by an antiferromagnet instead of a ferromagnet. Here we report experimental observation of the anisotropic magnetoresistance in an antiferromagnetic semiconductor Sr2IrO4. Based on ab initio calculations, we associate the origin of the phenomenon with large anisotropies in the relativistic electronic structure. The antiferromagnet film is exchange coupled to a ferromagnet, which allows us to reorient the antiferromagnet spin-axis in applied magnetic fields via the exchange spring effect. We demonstrate that the semiconducting nature of our AFM electrode allows us to perform anisotropic magnetoresistance measurements in the current-perpendicular-to-plane geometry without introducing a tunnel barrier into the stack. Temperature-dependent measurements of the resistance and anisotropic magnetoresistance highlight the large, entangled tunabilities of the ordinary charge and spin-dependent transport in a spintronic device utilizing the antiferromagnet semiconductor.

  8. Magnetization of anisotropic Type II superconductors

    SciTech Connect

    Mints, R.G.

    1989-04-10

    Peculiarities of magnetization of anisotropic type II superconductors are of considerable interest in view of the discovery of high-T/sub c/ superconductors characterized by strongly asymmetric layered structure. Specifics of the penetration of magnetic flux into an anisotropic type II superconductor were discussed in the literature. This analysis gave the distribution of induction in an isolated vortex, its energy, and critical magnetic field H/sub c1/. However, the magnetization curve of anisotropic superconductors was not considered. This paper deals with the magnetic moment of uniaxial London superconductor in the interval H/sub c1/ /le/ H/sub 0/ << H/sub c2/, where H/sub 0/ is the external magnetic field strength.

  9. Elastic properties of spherically anisotropic piezoelectric composites

    NASA Astrophysics Data System (ADS)

    Wei, En-Bo; Gu, Guo-Qing; Poon, Ying-Ming

    2010-09-01

    Effective elastic properties of spherically anisotropic piezoelectric composites, whose spherically anisotropic piezoelectric inclusions are embedded in an infinite non-piezoelectric matrix, are theoretically investigated. Analytical solutions for the elastic displacements and the electric potentials under a uniform external strain are derived exactly. Taking into account of the coupling effects of elasticity, permittivity and piezoelectricity, the formula is derived for estimating the effective elastic properties based on the average field theory in the dilute limit. An elastic response mechanism is revealed, in which the effective elastic properties increase as inclusion piezoelectric properties increase and inclusion dielectric properties decrease. Moreover, a piezoelectric response mechanism, of which the effective piezoelectric response vanishes due to the symmetry of spherically anisotropic composite, is also disclosed.

  10. Gravitational stresses in anisotropic rock masses

    USGS Publications Warehouse

    Amadei, B.; Savage, W.Z.; Swolfs, H.S.

    1987-01-01

    This paper presents closed-form solutions for the stress field induced by gravity in anisotropic rock masses. These rocks are assumed to be laterally restrained and are modelled as a homogeneous, orthotropic or transversely isotropic, linearly elastic material. The analysis, constrained by the thermodynamic requirement that strain energy be positive definite, gives the following important result: inclusion of anisotropy broadens the range of permissible values of gravity-induced horizontal stresses. In fact, for some ranges of anisotropic rock properties, it is thermodynamically admissible for gravity-induced horizontal stresses to exceed the vertical stress component; this is not possible for the classical isotropic solution. Specific examples are presented to explore the nature of the gravity-induced stress field in anisotropic rocks and its dependence on the type, degree and orientation of anisotropy with respect to the horizontal ground surface. ?? 1987.

  11. Azimuthally Anisotropic 3D Velocity Continuation

    DOE PAGES

    Burnett, William; Fomel, Sergey

    2011-01-01

    We extend time-domain velocity continuation to the zero-offset 3D azimuthally anisotropic case. Velocity continuation describes how a seismic image changes given a change in migration velocity. This description turns out to be of a wave propagation process, in which images change along a velocity axis. In the anisotropic case, the velocity model is multiparameter. Therefore, anisotropic image propagation is multidimensional. We use a three-parameter slowness model, which is related to azimuthal variations in velocity, as well as their principal directions. This information is useful for fracture and reservoir characterization from seismic data. We provide synthetic diffraction imaging examples to illustratemore » the concept and potential applications of azimuthal velocity continuation and to analyze the impulse response of the 3D velocity continuation operator.« less

  12. Saturation-Dependent Hydraulic Conductivity Anisotropy for Multifluid Systems in Porous Media

    SciTech Connect

    Zhang, Z. F.; Oostrom, Mart; Ward, Andy L.

    2007-11-01

    The hydraulic conductivity of unsaturated anisotropic soils has recently been described with a tensorial connectivity-tortuosity (TCT) concept. We extend this concept to unsaturated porous media with two or three immiscible fluids. Mathematical expressions to describe the conductivity of each fluid in anisotropic porous media under unsaturated condition are derived in the form of symmetric second order tensors. The theory is applicable to the combination of any type of saturation-pressure formulation and a generalized hydraulic conductivity model. The extended model shows that the anisotropic coefficient of a fluid is independent of the saturation of other fluids. Synthetic Miller-similar soils having hypothetical anisotropy were defined by allowing the saturated hydraulic conductivity to have different correlation ranges for different directions of flow. The extended TCT concept was tested using synthetic soils with four levels of heterogeneity and four levels of anisotropy. Numerical experiments of infiltration of two liquid phases, i.e., water and the nonaqueous phase liquid (NAPL) carbon tetrachloride, were carried out to test the extended model. The results show that, similar to water in a two-fluid (air-water) system, NAPL retention curves in a three-fluid (air-NAPL-water) system were independent of flow direction but dependent on soil heterogeneity, while the connectivity-tortuosity coefficients are functions of both soil heterogeneity and anisotropy. The extended TCT model accurately describes unsaturated hydraulic functions of anisotropic soils and can be combined into commonly used relative permeability functions for use in multifluid flow and transport numerical simulations.

  13. Porous silicon gettering

    SciTech Connect

    Tsuo, Y.S.; Menna, P.; Pitts, J.R.

    1996-05-01

    The authors have studied a novel extrinsic gettering method that uses the large surface areas produced by a porous-silicon etch as gettering sites. The annealing step of the gettering used a high-flux solar furnace. They found that a high density of photons during annealing enhanced the impurity diffusion to the gettering sites. The authors used metallurgical-grade Si (MG-Si) prepared by directional solidification casing as the starting material. They propose to use porous-silicon-gettered MG-Si as a low-cost epitaxial substrate for polycrystalline silicon thin-film growth.

  14. Chemically Layered Porous Solids

    NASA Technical Reports Server (NTRS)

    Koontz, Steve

    1991-01-01

    Aerogels and other porous solids in which surfaces of pores have chemical properties varying with depth below macroscopic surfaces prepared by sequences of chemical treatments. Porous glass or silica bead treated to make two depth zones having different chemical properties. Beads dropped along tube filled with flowing gas containing atomic oxygen, generated in microwave discharge. General class of materials treatable include oxides of aluminum, silicon, zirconium, tin, titanium, and nickel, and mixtures of these oxides. Potential uses of treated materials include chromatographic separations, membrane separations, controlled releases of chemicals, and catalysis.

  15. Porous block nanofiber composite filters

    DOEpatents

    Ginley, David S.; Curtis, Calvin J.; Miedaner, Alexander; Weiss, Alan J.; Paddock, Arnold

    2016-08-09

    Porous block nano-fiber composite (110), a filtration system (10) and methods of using the same are disclosed. An exemplary porous block nano-fiber composite (110) includes a porous block (100) having one or more pores (200). The porous block nano-fiber composite (110) also includes a plurality of inorganic nano-fibers (211) formed within at least one of the pores (200).

  16. Foam front propagation in anisotropic oil reservoirs.

    PubMed

    Grassia, P; Torres-Ulloa, C; Berres, S; Mas-Hernández, E; Shokri, N

    2016-04-01

    The pressure-driven growth model is considered, describing the motion of a foam front through an oil reservoir during foam improved oil recovery, foam being formed as gas advances into an initially liquid-filled reservoir. In the model, the foam front is represented by a set of so-called "material points" that track the advance of gas into the liquid-filled region. According to the model, the shape of the foam front is prone to develop concave sharply curved concavities, where the orientation of the front changes rapidly over a small spatial distance: these are referred to as "concave corners". These concave corners need to be propagated differently from the material points on the foam front itself. Typically the corner must move faster than those material points, otherwise spurious numerical artifacts develop in the computed shape of the front. A propagation rule or "speed up" rule is derived for the concave corners, which is shown to be sensitive to the level of anisotropy in the permeability of the reservoir and also sensitive to the orientation of the corners themselves. In particular if a corner in an anisotropic reservoir were to be propagated according to an isotropic speed up rule, this might not be sufficient to suppress spurious numerical artifacts, at least for certain orientations of the corner. On the other hand, systems that are both heterogeneous and anisotropic tend to be well behaved numerically, regardless of whether one uses the isotropic or anisotropic speed up rule for corners. This comes about because, in the heterogeneous and anisotropic case, the orientation of the corner is such that the "correct" anisotropic speed is just very slightly less than the "incorrect" isotropic one. The anisotropic rule does however manage to keep the corner very slightly sharper than the isotropic rule does.

  17. Foam front propagation in anisotropic oil reservoirs.

    PubMed

    Grassia, P; Torres-Ulloa, C; Berres, S; Mas-Hernández, E; Shokri, N

    2016-04-01

    The pressure-driven growth model is considered, describing the motion of a foam front through an oil reservoir during foam improved oil recovery, foam being formed as gas advances into an initially liquid-filled reservoir. In the model, the foam front is represented by a set of so-called "material points" that track the advance of gas into the liquid-filled region. According to the model, the shape of the foam front is prone to develop concave sharply curved concavities, where the orientation of the front changes rapidly over a small spatial distance: these are referred to as "concave corners". These concave corners need to be propagated differently from the material points on the foam front itself. Typically the corner must move faster than those material points, otherwise spurious numerical artifacts develop in the computed shape of the front. A propagation rule or "speed up" rule is derived for the concave corners, which is shown to be sensitive to the level of anisotropy in the permeability of the reservoir and also sensitive to the orientation of the corners themselves. In particular if a corner in an anisotropic reservoir were to be propagated according to an isotropic speed up rule, this might not be sufficient to suppress spurious numerical artifacts, at least for certain orientations of the corner. On the other hand, systems that are both heterogeneous and anisotropic tend to be well behaved numerically, regardless of whether one uses the isotropic or anisotropic speed up rule for corners. This comes about because, in the heterogeneous and anisotropic case, the orientation of the corner is such that the "correct" anisotropic speed is just very slightly less than the "incorrect" isotropic one. The anisotropic rule does however manage to keep the corner very slightly sharper than the isotropic rule does. PMID:27090239

  18. Porous metal for orthopedics implants

    PubMed Central

    Matassi, Fabrizio; Botti, Alessandra; Sirleo, Luigi; Carulli, Christian; Innocenti, Massimo

    2013-01-01

    Summary Porous metal has been introduced to obtain biological fixation and improve longevity of orthopedic implants. The new generation of porous metal has intriguing characteristics that allows bone healing and high osteointegration of the metallic implants. This article gives an overview about biomaterials properties of the contemporary class of highly porous metals and about the clinical use in orthopaedic surgery. PMID:24133527

  19. Anisotropic Gold Nanocrystals:. Synthesis and Characterization

    NASA Astrophysics Data System (ADS)

    Stiufiuc, R.; Toderas, F.; Iosin, M.; Stiufiuc, G.

    In this letter we report on successful preparation and characterization of anisotropic gold nanocrystals bio-synthesized by reduction of aqueous chloroaurate ions in pelargonium plant extract. The nanocrystals have been characterized by means of Transmission Electron Microscopy (TEM), UV-VIS absorption spectroscopy and tapping mode atomic force microscopy (TM-AFM). Using these investigation techniques, the successful formation of anisotropic single nanocrystals with the preferential growth direction along the gold (111) plane has been confirmed. The high detail phase images could give us an explanation concerning the growth mechanism of the nanocrystals.

  20. Optical Activity of Anisotropic Achiral Surfaces

    SciTech Connect

    Verbiest, T.; Kauranen, M.; Van Rompaey, Y.; Persoons, A. |

    1996-08-01

    Anisotropic achiral surfaces respond differently to left- and right-hand circularly polarized light. This occurs when the orientation of the surface with respect to an otherwise achiral experimental setup makes the total geometry chiral. Such optical activity is demonstrated in second-harmonic generation from an anisotropic thin molecular film. The circular-difference response reverses sign as the handedness of the geometry is reversed and vanishes when the setup possesses a mirror plane. The results are explained within the electric-dipole-allowed second-order surface nonlinearity. {copyright} {ital 1996 The American Physical Society.}

  1. Controllable underwater anisotropic oil-wetting

    SciTech Connect

    Yong, Jiale; Chen, Feng Yang, Qing; Farooq, Umar; Bian, Hao; Du, Guangqing; Hou, Xun

    2014-08-18

    This Letter demonstrates a simple method to achieve underwater anisotropic oil-wetting using silicon surfaces with a microgroove array produced by femtosecond laser ablation. The oil contact angles along the direction perpendicular to the grooves are consistently larger than those parallel to the microgroove arrays in water because the oil droplet is restricted by the energy barrier that exists between the non-irradiated domain and the trapped water in the laser-ablated microgrooves. This underwater anisotropic oil-wetting is able to be controlled, and the anisotropy can be tuned from 0° to ∼20° by adjusting the period of the microgroove arrays.

  2. Inverse moments equilibria for helical anisotropic systems

    NASA Astrophysics Data System (ADS)

    Cooper, W. A.; Hirshman, S. P.; Depassier, M. C.

    1987-11-01

    An energy functional is devised for magnetic confinement schemes that have anisotropic plasma pressure. The minimization of this energy functional is demonstrated to reproduce components of the magnetohydrodynamic (MHD) force balance relation in systems with helical symmetry. An iterative steepest descent procedure is applied to the Fourier moments of the inverse magnetic flux coordinates to minimize the total energy and thus generate anisotropic pressure MHD equilibria. Applications to straight ELMO Snaky Torus (NTIS Document No. DE-84002406) configurations that have a magnetic well on the outermost flux surfaces have been obtained.

  3. Evolution of multidimensional flat anisotropic cosmological models

    SciTech Connect

    Beloborodov, A. ); Demianski, M. Nicolaus Copernicus Astronomical Center, Bartycka 18, 00-716 Warsaw International Center for Relativistic Astrophysics , Universita di Roma I, La Sapienza, Rome ); Ivanov, P.; Polnarev, A.G. )

    1993-07-15

    We study the dynamics of a flat multidimensional anisotropic cosmological model filled with an anisotropic fluidlike medium. By an appropriate choice of variables, the dynamical equations reduce to a two-dimensional dynamical system. We present a detailed analysis of the time evolution of this system and the conditions of the existence of spacetime singularities. We investigate the conditions under which violent, exponential, and power-law inflation is possible. We show that dimensional reduction cannot proceed by anti-inflation (rapid contraction of internal space). Our model indicates that it is very difficult to achieve dimensional reduction by classical means.

  4. δN formalism in anisotropic inflation and large anisotropic bispectrum and trispectrum

    SciTech Connect

    Abolhasani, Ali Akbar; Emami, Razieh; Firouzjaee, Javad T.; Firouzjahi, Hassan E-mail: emami@ipm.ir E-mail: firouz@mail.ipm.ir

    2013-08-01

    We present the consistent δN formalism for curvature perturbations in anisotropic cosmological backgrounds. We employ our δN formalism to calculate the power spectrum, the bispectrum and the trispectrum in models of anisotropic inflation with the background gauge fields in Bianchi I universe. Our results coincide exactly with the recent results obtained from in-in formalism. To satisfy the observational constraints the anisotropies generated on power spectrum are kept small but large orientation-dependent non-Gaussianities can be generated. We study the Suyama-Yamaguchi inequality for the amplitudes of the bispectrum and the trispectrum in the presence of anisotropic shapes.

  5. Hydrophobic, Porous Battery Boxes

    NASA Technical Reports Server (NTRS)

    Bragg, Bobby J.; Casey, John E., Jr.

    1995-01-01

    Boxes made of porous, hydrophobic polymers developed to contain aqueous potassium hydroxide electrolyte solutions of zinc/air batteries while allowing air to diffuse in as needed for operation. Used on other types of batteries for in-cabin use in which electrolytes aqueous and from which gases generated during operation must be vented without allowing electrolytes to leak out.

  6. Porous metallic bodies

    DOEpatents

    Landingham, R.L.

    1984-03-13

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

  7. Highly Anisotropic, Highly Transparent Wood Composites.

    PubMed

    Zhu, Mingwei; Song, Jianwei; Li, Tian; Gong, Amy; Wang, Yanbin; Dai, Jiaqi; Yao, Yonggang; Luo, Wei; Henderson, Doug; Hu, Liangbing

    2016-07-01

    For the first time, two types of highly anisotropic, highly transparent wood composites are demonstrated by taking advantage of the macro-structures in original wood. These wood composites are highly transparent with a total transmittance up to 90% but exhibit dramatically different optical and mechanical properties.

  8. Conformally flat polytropes for anisotropic matter

    NASA Astrophysics Data System (ADS)

    Herrera, L.; Di Prisco, A.; Barreto, W.; Ospino, J.

    2014-12-01

    We analyze in detail conformally flat spherically symmetric fluid distributions, satisfying a polytropic equation of state. Among the two possible families of relativistic polytropes, only one contains models which satisfy all the required physical conditions. The ensuing configurations are necessarily anisotropic and show interesting physical properties. Prospective applications of the presented models to the study of super-Chandrasekhar white dwarfs, are discussed.

  9. Polarization of Cerenkov radiation in anisotropic media

    SciTech Connect

    Orisa, B.D.

    1995-10-01

    Using the method of Stokes parameters, we examine the polarization of Cerenkov radiation in anisotropic media. The study reveals that the radiation is totally polarized and that circular polarization is purely a quantum effect. We examine two cases; when the particle initially moves along the optical axis and when the particle initially moves perpendicular to the optical axis.

  10. Casimir interactions for anisotropic magnetodielectric metamaterials

    SciTech Connect

    Da Rosa, Felipe S; Dalvit, Diego A; Milonni, Peter W

    2008-01-01

    We extend our previous work on the generalization of the Casimir-Lifshitz theory to treat anisotropic magnetodielectric media, focusing on the forces between metals and magnetodielectric metamaterials and on the possibility of inferring magnetic effects by measurements of these forces.

  11. Anisotropic MHD model and some solutions

    SciTech Connect

    Kuznetsov, V. D.; Dzhalilov, N. S.

    2010-09-15

    MHD waves and instabilities in a collisionless anisotropic-pressure plasma are analyzed in an anisotropic MHD model based on the 16-moment approximation, and the results are found to agree well with those obtained in the low-frequency limit of the kinetic model. It is shown that accounting for heat fluxes leads to an asymmetry in the phase velocities of the wave modes with respect to the heat flux direction and also to a strong interaction between the modes, especially between the backward ones (those that propagate in a direction opposite to that of the heat flux). A correct description of the mirror instability is given. The resonant interaction of three backward modes-fast acoustic, fast magnetosonic, and slow acoustic-under the conditions for the onset of the classical firehose instability triggers a new type of instability the growth rate of which is faster than the maximum growth rate of the conventional firehose instability. The results prove that, in contrast to the familiar Chew-Goldberger-Low approximate model, the anisotropic MHD approach provides a correct description of the large-scale dynamics of collisionless anisotropic plasmas (such as solar corona, solar wind, and ionospheric and magnetospheric plasmas).

  12. A generalized anisotropic deformation formulation for geomaterials

    NASA Astrophysics Data System (ADS)

    Lei, Z.; Rougier, Esteban; Knight, E. E.; Munjiza, A.; Viswanathan, H.

    2016-04-01

    In this paper, the combined finite-discrete element method (FDEM) has been applied to analyze the deformation of anisotropic geomaterials. In the most general case geomaterials are both non-homogeneous and non-isotropic. With the aim of addressing anisotropic material problems, improved 2D FDEM formulations have been developed. These formulations feature the unified hypo-hyper elastic approach combined with a multiplicative decomposition-based selective integration for volumetric and shear deformation modes. This approach is significantly different from the co-rotational formulations typically encountered in finite element codes. Unlike the co-rotational formulation, the multiplicative decomposition-based formulation naturally decomposes deformation into translation, rotation, plastic stretches, elastic stretches, volumetric stretches, shear stretches, etc. This approach can be implemented for a whole family of finite elements from solids to shells and membranes. This novel 2D FDEM based material formulation was designed in such a way that the anisotropic properties of the solid can be specified in a cell by cell basis, therefore enabling the user to seed these anisotropic properties following any type of spatial variation, for example, following a curvilinear path. In addition, due to the selective integration, there are no problems with volumetric or shear locking with any type of finite element employed.

  13. Vibrations and stresses in layered anisotropic cylinders

    NASA Technical Reports Server (NTRS)

    Mulholland, G. P.; Gupta, B. P.

    1976-01-01

    An equation describing the radial displacement in a k layered anisotropic cylinder was obtained. The cylinders are initially unstressed but are subjected to either a time dependent normal stress or a displacement at the external boundaries of the laminate. The solution is obtained by utilizing the Vodicka orthogonalization technique. Numerical examples are given to illustrate the procedure.

  14. Anisotropic solutions in f(R) gravity

    NASA Astrophysics Data System (ADS)

    Tripathy, S. K.; Mishra, B.

    2016-08-01

    Anisotropic cosmological models are investigated in f( R) gravity in the metric formalism. Plane symmetric models with anisotropy in the expansion rates are considered. The anisotropy in expansion rates are assumed to be maintained throughout the cosmic evolution. Two accelerating models are constructed by assuming different functional forms for f( R). The viability of these models is tested through a stability analysis.

  15. Methodology for determining material constants of anisotropic materials belonging to the transversely isotropic system by ultrasound method.

    PubMed

    Piekarczyk, Wojciech; Kata, Dariusz

    2016-09-01

    The paper presents the methodology and results of the ultrasound determination of material constants of anisotropic materials belonging to the transversely isotropic system. Ultrasound through-transmission method was used for determining material constants. Based on the measurements of velocities of longitudinal and transverse ultrasounds waves propagation, respectively polarized in required directions all the elastic and the material constant of the test materials were determined. Measurements of all the velocities necessary to determine the elastic constants were performed on a specially prepared individual samples. The tests were carried out on porous polycrystalline anisotropic graphites of anisotropy in Young's modulus of up to 26% and Al2O3 composites with up to 30% of hBN causing anisotropy of Young's modulus of up to 50%. It was found that for all tested samples the value of Young's modules and modules stiffness decreasing with increasing porosity in the graphites and increasing content of hBN in Al2O3.

  16. Methodology for determining material constants of anisotropic materials belonging to the transversely isotropic system by ultrasound method.

    PubMed

    Piekarczyk, Wojciech; Kata, Dariusz

    2016-09-01

    The paper presents the methodology and results of the ultrasound determination of material constants of anisotropic materials belonging to the transversely isotropic system. Ultrasound through-transmission method was used for determining material constants. Based on the measurements of velocities of longitudinal and transverse ultrasounds waves propagation, respectively polarized in required directions all the elastic and the material constant of the test materials were determined. Measurements of all the velocities necessary to determine the elastic constants were performed on a specially prepared individual samples. The tests were carried out on porous polycrystalline anisotropic graphites of anisotropy in Young's modulus of up to 26% and Al2O3 composites with up to 30% of hBN causing anisotropy of Young's modulus of up to 50%. It was found that for all tested samples the value of Young's modules and modules stiffness decreasing with increasing porosity in the graphites and increasing content of hBN in Al2O3. PMID:27395009

  17. A facile method for the preparation of chitosan-based scaffolds with anisotropic pores for tissue engineering applications.

    PubMed

    Ran, Jiabing; Xie, Lingjun; Sun, Guanglin; Hu, Jingxiao; Chen, Si; Jiang, Pei; Shen, Xinyu; Tong, Hua

    2016-11-01

    To date, great efforts have been made to prepare different kinds of isotropic tissue engineering (TE) scaffolds. However, little attention has been paid to anisotropic porous scaffolds in spite of many examples of their excellent performances. In this work, a facile method termed "ammonia-induced method" (AIM) was proposed and applied to generate anisotropic pores in chitosan (CS)-based scaffolds. The pore structures of these scaffolds were studied in detail. In order to clarify the rationale behind this process, a speculative explanation was provided on basis of the experimental results and the theory of Uras (Uras & Devlin, 2000). Compression tests indicated that the mechanical strengths of these scaffolds were sufficient for TE applications. In vitro cell culture showed that MC3T3-E1 cells cultivated in the pores of these scaffolds had positive proliferation potential. We anticipated that this novel AIM could inspire research not only in TE but also in other fields. PMID:27516311

  18. Porous silicon and porous polymer substrates for optical chemical sensors

    NASA Astrophysics Data System (ADS)

    Hajj-Hassan, Mohamad; Kim, Sung-Jin; Cheung, Maurice C.; Yao, Lei; Chodavarapu, Vamsy; Cartwright, Alexander

    2010-07-01

    Mesoporous materials, such as porous silicon and porous polymer gratings (Bragg structures), offer an attractive platform for the encapsulation of chemical and biological recognition elements. These materials include the advantages of high surface to volume ratio, biocompatibility, functionality with various recognition elements, and the ability to modify the material surface/volume properties and porosity. Two porous structures were used for chemical and biological sensing: porous silicon and porous polymer photonic bandgap structures. Specifically, a new dry etching manufacturing technique employing xenon difluoride (XeF2) based etching was used to produce porous silicon Porous silicon continues to be extensively researched for various optical and electronic devices and applications in chemical and biological sensing are abundant. The dry etching technique to manufacture porous silicon offers a simple and efficient alternative to the traditional wet electrochemical etching using hydrofluoric acid. This new porous silicon material was characterized for its pore size and morphology using top and cross-sectional views from scanning electron microscopy. Its optical properties were determined by angular dependence of reflectance measurements. A new class of holographically ordered porous polymer gratings that are an extension of holographic polymer dispersed liquid crystal (H-PDLC) structures. As an alternative structure and fabrication process, porous polymer gratings that include a volatile solvent as the phase separation fluid was fabricated. Porous silicon and porous polymer materials were used as substrates to encapsulate gaseous oxygen (O2) responsive luminophores in their nanostructured pores. These substrate materials behave as optical interference filters that allow efficient and selective detection of the wavelengths of interest in optical sensors.

  19. Wave propagation in anisotropic poroelastic beam with axial-flexural coupling

    NASA Astrophysics Data System (ADS)

    Chakraborty, A.

    2009-05-01

    The exact solution of the governing partial differential equations describing the motion of an anisotropic porous beam with axial-flexural coupling is presented. The motion of the beam is described by the classical Euler-Bernoulli theory. The pore-fluid pressure is governed by the generalized Darcy’s law with relaxation and retardation time parameters to account for the inertia and viscosity of the fluid. Solutions are sought in the frequency domain where the governing equations are converted into a polynomial eigenvalue structure and solved exactly. The wavenumbers and group speeds of propagating waves in the beam are studied in detail. It is found that the presence of fluid-filled porous micro-structure introduces three additional propagating modes, other than the axial and bending modes predicted by the classical beam theory. The effect of diffusion boundary conditions on the transverse motion of a porous beam is investigated in detail. It is also found that the material parameters have considerable influence on the magnitude of the transverse velocity, the group speed of propagation and the behavior of the pressure resultants.

  20. Porous bioactive materials

    NASA Astrophysics Data System (ADS)

    Zhang, Kai

    Bioactive materials chemically bond to tissues through the development of biologically active apatite. Porous structures in biomaterials are designed to enhance bioactivity, grow artificial tissues and achieve better integration with host tissues in the body. The goal of this research is to design, fabricate and characterize novel porous bioactive materials. 3D ordered macroporous bioactive glasses (3DOM-BGs, pore size: 200--1000 nm) were prepared using a sol-gel process and colloidal crystal templates. 3DOM-BGs are more bioactive and degradable than mesoporous (pore size <50 nm) sol-gel BGs in simulated body fluid (SBF). Apatite formation and 3DOM-BG degradation rates increased with the decrease of soaking ratio. Apatite induction time in SBF increased with 3DOM-BG calcination temperature (600--800°C). Apatite formation and 3DOMBG degradation were slightly enhanced for a phosphate containing composition. Large 3DOM-BG particles formed less apatite and degraded less completely as compared with small particles. An increase in macropore size slowed down 3DOM-BG degradation and apatite formation processes. After heating the converted apatite at a temperature higher than 700°C, highly crystalline hydroxyapatite and a minor tri-calcium phosphate phase formed. 3DOM-BGs have potential applications as bone/periodontal fillers, and drugs and biological factors delivery agents. Anchoring artificial soft tissues (e.g., cartilage) to native bone presents a challenge. Porous polymer/bioactive glass composites are candidate materials for engineering artificial soft tissue/bone interfaces. Porous composites consisting of polymer matrices (e.g., polysulfone, polylactide, and polyurethane) and bioactive glass particles were prepared by polymer phase separation techniques adapted to include ceramic particles. Composites (thickness: 200--500 mum) have asymmetric structures with dense top layers and porous structures beneath. Porous structures consist of large pores (>100 mum) in a

  1. Strong, Lightweight, Porous Materials

    NASA Technical Reports Server (NTRS)

    Leventis, Nicholas; Meador, Mary Ann B.; Johnston, James C.; Fabrizio, Eve F.; Ilhan, Ulvi

    2007-01-01

    A new class of strong, lightweight, porous materials has been invented as an outgrowth of an effort to develop reinforced silica aerogels. The new material, called X-Aerogel is less hygroscopic, but no less porous and of similar density to the corresponding unmodified aerogels. However, the property that sets X-Aerogels apart is their mechanical strength, which can be as much as two and a half orders of magnitude stronger that the unmodified aerogels. X-Aerogels are envisioned to be useful for making extremely lightweight, thermally insulating, structural components, but they may also have applications as electrical insulators, components of laminates, catalyst supports, templates for electrode materials, fuel-cell components, and filter membranes.

  2. Porous polymer media

    DOEpatents

    Shepodd, Timothy J.

    2002-01-01

    Highly crosslinked monolithic porous polymer materials for chromatographic applications. By using solvent compositions that provide not only for polymerization of acrylate monomers in such a fashion that a porous polymer network is formed prior to phase separation but also for exchanging the polymerization solvent for a running buffer using electroosmotic flow, the need for high pressure purging is eliminated. The polymer materials have been shown to be an effective capillary electrochromatographic separations medium at lower field strengths than conventional polymer media. Further, because of their highly crosslinked nature these polymer materials are structurally stable in a wide range of organic and aqueous solvents and over a pH range of 2-12.

  3. Porous electrode preparation method

    DOEpatents

    Arons, Richard M.; Dusek, Joseph T.

    1983-01-01

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder of such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity.

  4. Porous electrode preparation method

    DOEpatents

    Arons, R.M.; Dusek, J.T.

    1983-10-18

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder of such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity. 2 figs.

  5. Oligonucleotide-Functionalized Anisotropic Gold Nanoparticles

    NASA Astrophysics Data System (ADS)

    Jones, Matthew Robert

    In this thesis, we describe the properties of oligonucleotide-functionalized gold colloids under the unique set of conditions where the particles are geometrically anisotropic and have nanometer-scale dimensions. While nearly two decades of previous work elucidated numerous unexpected and emergent phenomena arising from the combination of inorganic nanoparticles with surface-bound DNA strands, virtually nothing was known about how these properties are altered when the shape of the nanoparticle core is chosen to be non-spherical. In particular, we are interested in understanding, and ultimately controlling, the ways in which these DNA-conjugated anisotropic nanostructures interact when their attraction is governed by programmable DNA hybridization events. Chapter 1 introduces the field of DNA-based materials assembly by discussing how nanoscale building blocks which present rigid, directional interactions can be thought of as possessing artificial versions of the familiar chemical principles of "bonds" and "valency". In chapter 2 we explore the fundamental interparticle binding thermodynamics of DNA-functionalized spherical and anisotropic nanoparticles, which reveals enormous preferences for collective ligand interactions occurring between flat surfaces over those that occur between curved surfaces. Using these insights, chapter 3 demonstrates that when syntheses produce mixtures of different nanoparticle shapes, the tailorable nature of DNA-mediated interparticle association can be used to selectively crystallize and purify the desired anisotropic nanostructure products, leaving spherical impurity particles behind. Chapter 4 leverages the principle that the flat facets of anisotropic particles generate directional DNA-based hybridization interactions to assemble a variety of tailorable nanoparticle superlattices whose symmetry and dimensionality are a direct consequence of the shape of the nanoparticle building block used in their construction. Chapter 5 explores

  6. Porous materials. Function-led design of new porous materials.

    PubMed

    Slater, Anna G; Cooper, Andrew I

    2015-05-29

    Porous solids are important as membranes, adsorbents, catalysts, and in other chemical applications. But for these materials to find greater use at an industrial scale, it is necessary to optimize multiple functions in addition to pore structure and surface area, such as stability, sorption kinetics, processability, mechanical properties, and thermal properties. Several different classes of porous solids exist, and there is no one-size-fits-all solution; it can therefore be challenging to choose the right type of porous material for a given job. Computational prediction of structure and properties has growing potential to complement experiment to identify the best porous materials for specific applications.

  7. Observation of an Anisotropic Wigner Crystal

    NASA Astrophysics Data System (ADS)

    Liu, Yang; Hasdemir, S.; Pfeiffer, L. N.; West, K. W.; Baldwin, K. W.; Shayegan, M.

    2016-09-01

    We report a new correlated phase of two-dimensional charged carriers in high magnetic fields, manifested by an anisotropic insulating behavior at low temperatures. It appears in a large range of low Landau level fillings 1 /3 ≲ν ≲2 /3 in hole systems confined to wide GaAs quantum wells when the sample is tilted in magnetic field to an intermediate angle. The parallel field component (B∥) leads to a crossing of the lowest two Landau levels, and an elongated hole wave function in the direction of B∥. Under these conditions, the in-plane resistance exhibits an insulating behavior, with the resistance along B∥ about 10 times smaller than the resistance perpendicular to B∥. We interpret this anisotropic insulating phase as a two-component, striped Wigner crystal.

  8. Wireless energy transfer between anisotropic metamaterials shells

    SciTech Connect

    Díaz-Rubio, Ana; Carbonell, Jorge; Sánchez-Dehesa, José

    2014-06-15

    The behavior of strongly coupled Radial Photonic Crystals shells is investigated as a potential alternative to transfer electromagnetic energy wirelessly. These sub-wavelength resonant microstructures, which are based on anisotropic metamaterials, can produce efficient coupling phenomena due to their high quality factor. A configuration of selected constitutive parameters (permittivity and permeability) is analyzed in terms of its resonant characteristics. The coupling to loss ratio between two coupled resonators is calculated as a function of distance, the maximum (in excess of 300) is obtained when the shells are separated by three times their radius. Under practical conditions an 83% of maximum power transfer has been also estimated. -- Highlights: •Anisotropic metamaterial shells exhibit high quality factors and sub-wavelength size. •Exchange of electromagnetic energy between shells with high efficiency is analyzed. •Strong coupling is supported with high wireless transfer efficiency. •End-to-end energy transfer efficiencies higher than 83% can be predicted.

  9. Comparing anisotropic displacement parameters in protein structures.

    PubMed

    Merritt, E A

    1999-12-01

    The increasingly widespread use of synchrotron-radiation sources and cryo-preparation of samples in macromolecular crystallography has led to a dramatic increase in the number of macromolecular structures determined at atomic or near-atomic resolution. This permits expansion of the structural model to include anisotropic displacement parameters U(ij) for individual atoms. In order to explore the physical significance of these parameters in protein structures, it is useful to be able to compare quantitatively the electron-density distribution described by the refined U(ij) values associated with corresponding crystallographically independent atoms. This paper presents the derivation of an easily calculated correlation coefficient in real space between two atoms modeled with anisotropic displacement parameters. This measure is used to investigate the degree of similarity between chemically equivalent but crystallographically independent atoms in the set of protein structural models currently available from the Protein Data Bank.

  10. Rotating Anisotropic Crystalline Silicon Nanoclusters in Graphene.

    PubMed

    Chen, Qu; Koh, Ai Leen; Robertson, Alex W; He, Kuang; Lee, Sungwoo; Yoon, Euijoon; Lee, Gun-Do; Sinclair, Robert; Warner, Jamie H

    2015-10-27

    The atomic structure and dynamics of silicon nanoclusters covalently bonded to graphene are studied using aberration-corrected transmission electron microscopy. We show that as the cluster size increases to 4-10 atoms, ordered crystalline cubic phases start to emerge. Anisotropic crystals are formed due to higher stability of the Si-C bond under electron beam irradiation compared to the Si-Si bond. Dynamics of the anisotropic crystalline Si nanoclusters reveal that they can rotate perpendicular to the graphene plane, with oscillations between the two geometric configurations driven by local volume constraints. These results provide important insights into the crystalline phases of clusters of inorganic dopants in graphene at the intermediate size range between isolated single atoms and larger bulk 2D forms.

  11. Disentangling scaling properties in anisotropic fracture.

    PubMed

    Bouchbinder, Eran; Procaccia, Itamar; Sela, Shani

    2005-12-16

    Structure functions of rough fracture surfaces in isotropic materials exhibit complicated scaling properties due to the broken isotropy in the fracture plane generated by a preferred propagation direction. Decomposing the structure functions into the even order irreducible representations of the SO(2) symmetry group indexed by (m = 0, 2, 4, . . .) results in a lucid and quickly convergent description. The scaling exponent of the isotropic sector (m = 0) dominates at small length scales. One can reconstruct the anisotropic structure functions using only the isotropic and the first nonvanishing anisotropic sector (m = 2) [or at most the next one (m = 4)]. The scaling exponent of the isotropic sector should be observed in a proposed, yet unperformed, experiment.

  12. Cosmological signatures of anisotropic spatial curvature

    NASA Astrophysics Data System (ADS)

    Pereira, Thiago S.; Mena Marugán, Guillermo A.; Carneiro, Saulo

    2015-07-01

    If one is willing to give up the cherished hypothesis of spatial isotropy, many interesting cosmological models can be developed beyond the simple anisotropically expanding scenarios. One interesting possibility is presented by shear-free models in which the anisotropy emerges at the level of the curvature of the homogeneous spatial sections, whereas the expansion is dictated by a single scale factor. We show that such models represent viable alternatives to describe the large-scale structure of the inflationary universe, leading to a kinematically equivalent Sachs-Wolfe effect. Through the definition of a complete set of spatial eigenfunctions we compute the two-point correlation function of scalar perturbations in these models. In addition, we show how such scenarios would modify the spectrum of the CMB assuming that the observations take place in a small patch of a universe with anisotropic curvature.

  13. Acoustic analysis of anisotropic poroelastic multilayered systems

    NASA Astrophysics Data System (ADS)

    Parra Martinez, Juan Pablo; Dazel, Olivier; Göransson, Peter; Cuenca, Jacques

    2016-02-01

    The proposed method allows for an extended analysis of the wave analysis, internal powers, and acoustic performance of anisotropic poroelastic media within semi-infinite multilayered systems under arbitrary excitation. Based on a plane wave expansion, the solution is derived from a first order partial derivative as proposed by Stroh. This allows for an in-depth analysis of the mechanisms controlling the acoustic behaviour in terms of internal powers and wave properties in the media. In particular, the proposed approach is used to highlight the influence of the phenomena intrinsic to anisotropic poroelastic media, such as compression-shear coupling related to the material alignment, the frequency shift of the fundamental resonance, or the appearance of particular geometrical coincidences in multilayered systems with such materials.

  14. Performance analysis of anisotropic scattering center detection

    NASA Astrophysics Data System (ADS)

    Moses, Randolph L.; Erten, Eniz; Potter, Lee C.

    1997-07-01

    We consider the problem of detecting anisotropic scattering of targets from wideband SAR measurements. We first develop a scattering model for the response of an ideal dihedral when interrogated by a wideband radar. We formulate a stochastic detection problem based on this model and Gaussian clutter models. We investigate the performance of three detectors, the conventional imaging detector, a generalized likelihood ratio test (GLRT) detector based on the dihedral anisotropic scattering model, and a sum-of- squares detector motivated as a computationally attractive alternative to the GLRT test. We also investigate the performance degradation of the GLRT detector when using truncated angle response filters, and analyze detector sensitivity to changes in target length. Finally, we present initial results of angular matched filter detection applied to UWB radar measurements collected by the Army Research Laboratory at Aberdeen Proving Grounds.

  15. Formation of Anisotropic Block Copolymer Gels

    NASA Astrophysics Data System (ADS)

    Liaw, Chya Yan; Shull, Kenneth; Henderson, Kevin; Joester, Derk

    2011-03-01

    Anisotropic, fibrillar gels are important in a variety of processes. Biomineralization is one example, where the mineralization process often occurs within a matrix of collagen or chitin fibers that trap the mineral precursors and direct the mineralization process. We wish to replicate this type of behavior within block copolymer gels. Particularly, we are interested in employing gels composed of cylindrical micelles, which are anisotropic and closely mimic biological fibers. Micelle geometry is controlled in our system by manipulating the ratio of molecular weights of the two blocks and by controlling the detailed thermal processing history of the copolymer solutions. Small-Angle X-ray Scattering and Dynamic Light Scattering are used to determine the temperature dependence of the gel formation process. Initial experiments are based on a thermally-reversible alcohol-soluble system, that can be subsequently converted to a water soluble system by hydrolysis of a poly(t-butyl methacrylate) block to a poly (methacrylic acid) block. MRSEC.

  16. Observation of an Anisotropic Wigner Crystal.

    PubMed

    Liu, Yang; Hasdemir, S; Pfeiffer, L N; West, K W; Baldwin, K W; Shayegan, M

    2016-09-01

    We report a new correlated phase of two-dimensional charged carriers in high magnetic fields, manifested by an anisotropic insulating behavior at low temperatures. It appears in a large range of low Landau level fillings 1/3≲ν≲2/3 in hole systems confined to wide GaAs quantum wells when the sample is tilted in magnetic field to an intermediate angle. The parallel field component (B_{∥}) leads to a crossing of the lowest two Landau levels, and an elongated hole wave function in the direction of B_{∥}. Under these conditions, the in-plane resistance exhibits an insulating behavior, with the resistance along B_{∥} about 10 times smaller than the resistance perpendicular to B_{∥}. We interpret this anisotropic insulating phase as a two-component, striped Wigner crystal. PMID:27636486

  17. Differential dynamic microscopy for anisotropic colloidal dynamics.

    PubMed

    Reufer, Mathias; Martinez, Vincent A; Schurtenberger, Peter; Poon, Wilson C K

    2012-03-13

    Differential dynamic microscopy (DDM) is a low-cost, high-throughput technique recently developed for characterizing the isotropic diffusion of spherical colloids using white-light optical microscopy. (1) We develop the theory for applying DDM to probe the dynamics of anisotropic colloidal samples such as various ordered phases, or particles interacting with an external field. The q-dependent dynamics can be measured in any direction in the image plane. We demonstrate the method on a dilute aqueous dispersion of anisotropic magnetic particles (hematite) aligned in a magnetic field. The measured diffusion coefficients parallel and perpendicular to the field direction are in good agreement with theoretical values. We show how these measurements allow us to extract the orientational order parameter S(2) of the system.

  18. Porous microsphere and its applications

    PubMed Central

    Cai, Yunpeng; Chen, Yinghui; Hong, Xiaoyun; Liu, Zhenguo; Yuan, Weien

    2013-01-01

    Porous microspheres have drawn great attention in the last two decades for their potential applications in many fields, such as carriers for drugs, absorption and desorption of substances, pulmonary drug delivery, and tissue regeneration. The application of porous microspheres has become a feasible way to address existing problems. In this essay, we give a brief introduction of the porous microsphere, its characteristics, preparation methods, applications, and a brief summary of existing problems and research tendencies. PMID:23515359

  19. Natural convection in porous media

    SciTech Connect

    Prasad, V.; Hussain, N.A.

    1986-01-01

    This book presents the papers given at a conference on free convection in porous materials. Topics considered at the conference included heat transfer, nonlinear temperature profiles and magnetic fields, boundary conditions, concentrated heat sources in stratified porous media, free convective flow in a cavity, heat flux, laminar mixed convection flow, and the onset of convection in a porous medium with internal heat generation and downward flow.

  20. Anisotropic magnetocapacitance in ferromagnetic-plate capacitors

    NASA Astrophysics Data System (ADS)

    Haigh, J. A.; Ciccarelli, C.; Betz, A. C.; Irvine, A.; Novák, V.; Jungwirth, T.; Wunderlich, J.

    2015-04-01

    The capacitance of a parallel-plate capacitor can depend on the applied magnetic field. Previous studies have identified capacitance changes induced via classical Lorentz force or spin-dependent Zeeman effects. Here we measure a magnetization direction-dependent capacitance in parallel-plate capacitors where one plate is a ferromagnetic semiconductor, gallium manganese arsenide. This anisotropic magnetocapacitance is due to the anisotropy in the density of states dependent on the magnetization through the strong spin-orbit interaction.

  1. Anisotropic resonant scattering from polymer photonic crystals.

    PubMed

    Haines, Andrew I; Finlayson, Chris E; Snoswell, David R E; Spahn, Peter; Hellmann, G Peter; Baumberg, Jeremy J

    2012-11-20

    Hyperspectral goniometry reveals anisotropic scattering which dominates the visual appearance of self-assembled polymer opals. The technique allows reconstruction of the reciprocal-space of nanostructures, and indicates that chain defects formed during shear-ordering are responsible for the anisotropy in these samples. Enhanced scattering with improving order is shown to arise from increased effective refractive index contrast, while broadband background scatter is suppressed by absorptive dopants. PMID:22915079

  2. Perspectives of anisotropic flow measurements at NICA

    NASA Astrophysics Data System (ADS)

    Korotkikh, V. L.; Lokhtin, I. P.; Malinina, L. V.; Petrushanko, S. V.; Snigirev, A. M.

    2016-08-01

    High-accuracy and high-luminosity measurements of anisotropic flow for various hadron types over full NICA energy range will provide important constraints on the early dynamics of heavy-ion reactions under the conditions where a first-order quark-hadron phase transition may occur. The statistical reach for elliptic flow measurements at NICA is estimated with HYDJET++ heavy-ion event generator.

  3. Anisotropic conducting films for electromagnetic radiation applications

    DOEpatents

    Cavallo, Francesca; Lagally, Max G.; Rojas-Delgado, Richard

    2015-06-16

    Electronic devices for the generation of electromagnetic radiation are provided. Also provided are methods for using the devices to generate electromagnetic radiation. The radiation sources include an anisotropic electrically conducting thin film that is characterized by a periodically varying charge carrier mobility in the plane of the film. The periodic variation in carrier mobility gives rise to a spatially varying electric field, which produces electromagnetic radiation as charged particles pass through the film.

  4. Multidimensional Contact Moduli of Elastically Anisotropic Solids

    SciTech Connect

    Gao, Yanfei; Pharr, George Mathews

    2007-01-01

    Effective moduli of elastically anisotropic solids under normal and tangential contacts are derived using the Stroh formalism and the two dimensional Fourier transform. Each Fourier component corresponds to a plane field in the plane spanned by the surface normal and a wavevector, the solution of which only involves an algebraic eigenvalue problem. Exact solutions are obtained for indenters described by parabolae of revolution, which are found to be a good approximation for arbitrary axisymmetric indenters.

  5. Restoring unitarity in anisotropic quantum cosmological models

    NASA Astrophysics Data System (ADS)

    Pal, Sridip; Banerjee, Narayan

    2015-02-01

    The present work shows that a properly chosen ordering of operators can restore unitarity in anisotropic quantum cosmological models. Bianchi V and Bianchi IX models with a perfect fluid are worked out. A transformation of coordinates takes the Hamiltonian to that of an inverse square potential which has equal deficiency indices; thus, a self-adjoint extension is possible. Although not clearly detected before, we show here that isotropic models are also apt to violate the conservation of probability for careless operator ordering.

  6. Anisotropic Thermal Conductivity of Exfoliated Black Phosphorus.

    PubMed

    Jang, Hyejin; Wood, Joshua D; Ryder, Christopher R; Hersam, Mark C; Cahill, David G

    2015-12-22

    The anisotropic thermal conductivity of passivated black phosphorus (BP), a reactive two-dimensional material with strong in-plane anisotropy, is ascertained. The room-temperature thermal conductivity for three crystalline axes of exfoliated BP is measured by time-domain thermo-reflectance. The thermal conductivity along the zigzag direction is ≈2.5 times higher than that of the armchair direction.

  7. Observational signatures of anisotropic inflationary models

    SciTech Connect

    Ohashi, Junko; Tsujikawa, Shinji; Soda, Jiro E-mail: jiro@phys.sci.kobe-u.ac.jp

    2013-12-01

    We study observational signatures of two classes of anisotropic inflationary models in which an inflaton field couples to (i) a vector kinetic term F{sub μν}F{sup μν} and (ii) a two-form kinetic term H{sub μνλ}H{sup μνλ}. We compute the corrections from the anisotropic sources to the power spectrum of gravitational waves as well as the two-point cross correlation between scalar and tensor perturbations. The signs of the anisotropic parameter g{sub *} are different depending on the vector and the two-form models, but the statistical anisotropies generally lead to a suppressed tensor-to-scalar ratio r and a smaller scalar spectral index n{sub s} in both models. In the light of the recent Planck bounds of n{sub s} and r, we place observational constraints on several different inflaton potentials such as those in chaotic and natural inflation in the presence of anisotropic interactions. In the two-form model we also find that there is no cross correlation between scalar and tensor perturbations, while in the vector model the cross correlation does not vanish. The non-linear estimator f{sub NL} of scalar non-Gaussianities in the two-form model is generally smaller than that in the vector model for the same orders of |g{sub *}|, so that the former is easier to be compatible with observational bounds of non-Gaussianities than the latter.

  8. Symmetry analysis for anisotropic field theories

    SciTech Connect

    Parra, Lorena; Vergara, J. David

    2012-08-24

    The purpose of this paper is to study with the help of Noether's theorem the symmetries of anisotropic actions for arbitrary fields which generally depend on higher order spatial derivatives, and to find the corresponding current densities and the Noether charges. We study in particular scale invariance and consider the cases of higher derivative extensions of the scalar field, electrodynamics and Chern-Simons theory.

  9. Nonparaxial solitary waves in anisotropic dielectrics

    SciTech Connect

    Alberucci, Alessandro; Assanto, Gaetano

    2011-03-15

    We account for the vectorial character of electromagnetic waves in the study of nonlinear self-action and transverse localization in dielectric anisotropic media. With reference to uniaxials, we address spatial solitons propagating in the nonparaxial regime in the presence of an arbitrary degree of nonlocality, going from the standard Kerr response to the highly nonlocal case, unveiling various effects, including transverse profile asymmetry and bending of the trajectory, as well as a weak effective nonlocality even in local media.

  10. Multidimensional reaction rate theory with anisotropic diffusion.

    PubMed

    Berezhkovskii, Alexander M; Szabo, Attila; Greives, Nicholas; Zhou, Huan-Xiang

    2014-11-28

    An analytical expression is derived for the rate constant that describes diffusive transitions between two deep wells of a multidimensional potential. The expression, in contrast to the Kramers-Langer formula for the rate constant, is valid even when the diffusion is highly anisotropic. Our approach is based on a variational principle for the reactive flux and uses a trial function for the splitting probability or commitor. The theoretical result is validated by Brownian dynamics simulations.

  11. Anisotropic Thermal Conductivity of Exfoliated Black Phosphorus.

    PubMed

    Jang, Hyejin; Wood, Joshua D; Ryder, Christopher R; Hersam, Mark C; Cahill, David G

    2015-12-22

    The anisotropic thermal conductivity of passivated black phosphorus (BP), a reactive two-dimensional material with strong in-plane anisotropy, is ascertained. The room-temperature thermal conductivity for three crystalline axes of exfoliated BP is measured by time-domain thermo-reflectance. The thermal conductivity along the zigzag direction is ≈2.5 times higher than that of the armchair direction. PMID:26516073

  12. Selective formation of porous silicon

    NASA Technical Reports Server (NTRS)

    Fathauer, Robert W. (Inventor); Jones, Eric W. (Inventor)

    1993-01-01

    A pattern of porous silicon is produced in the surface of a silicon substrate by forming a pattern of crystal defects in said surface, preferably by applying an ion milling beam through openings in a photoresist layer to the surface, and then exposing said surface to a stain etchant, such as HF:HNO3:H2O. The defected crystal will preferentially etch to form a pattern of porous silicon. When the amorphous content of the porous silicon exceeds 70 percent, the porous silicon pattern emits visible light at room temperature.

  13. Selective formation of porous silicon

    NASA Technical Reports Server (NTRS)

    Fathauer, Jones (Inventor)

    1993-01-01

    A pattern of porous silicon is produced in the surface of a silicon substrate by forming a pattern of crystal defects in said surface, preferably by applying an ion milling beam through openings in a photoresist layer to the surface, and then exposing said surface to a stain etchant, such as HF:HNO3:H20. The defected crystal will preferentially etch to form a pattern of porous silicon. When the amorphous content of the porous silicon exceeds 70 percent, the porous silicon pattern emits visible light at room temperature.

  14. Active Damping Using Distributed Anisotropic Actuators

    NASA Technical Reports Server (NTRS)

    Schiller, Noah H.; Cabell, Randolph H.; Quinones, Juan D.; Wier, Nathan C.

    2010-01-01

    A helicopter structure experiences substantial high-frequency mechanical excitation from powertrain components such as gearboxes and drive shafts. The resulting structure-borne vibration excites the windows which then radiate sound into the passenger cabin. In many cases the radiated sound power can be reduced by adding damping. This can be accomplished using passive or active approaches. Passive treatments such as constrained layer damping tend to reduce window transparency. Therefore this paper focuses on an active approach utilizing compact decentralized control units distributed around the perimeter of the window. Each control unit consists of a triangularly shaped piezoelectric actuator, a miniature accelerometer, and analog electronics. Earlier work has shown that this type of system can increase damping up to approximately 1 kHz. However at higher frequencies the mismatch between the distributed actuator and the point sensor caused control spillover. This paper describes new anisotropic actuators that can be used to improve the bandwidth of the control system. The anisotropic actuators are composed of piezoelectric material sandwiched between interdigitated electrodes, which enables the application of the electric field in a preferred in-plane direction. When shaped correctly the anisotropic actuators outperform traditional isotropic actuators by reducing the mismatch between the distributed actuator and point sensor at high frequencies. Testing performed on a Plexiglas panel, representative of a helicopter window, shows that the control units can increase damping at low frequencies. However high frequency performance was still limited due to the flexible boundary conditions present on the test structure.

  15. ARTc: Anisotropic reflectivity and transmissivity calculator

    NASA Astrophysics Data System (ADS)

    Malehmir, Reza; Schmitt, Douglas R.

    2016-08-01

    While seismic anisotropy is known to exist within the Earth's crust and even deeper, isotropic or even highly symmetric elastic anisotropic assumptions for seismic imaging is an over-simplification which may create artifacts in the image, target mis-positioning and hence flawed interpretation. In this paper, we have developed the ARTc algorithm to solve reflectivity, transmissivity as well as velocity and particle polarization in the most general case of elastic anisotropy. This algorithm is able to provide reflectivity solution from the boundary between two anisotropic slabs with arbitrary symmetry and orientation up to triclinic. To achieve this, the algorithm solves full elastic wave equation to find polarization, slowness and amplitude of all six wave-modes generated from the incident plane-wave and welded interface. In the first step to calculate the reflectivity, the algorithm solves properties of the incident wave such as particle polarization and slowness. After calculation of the direction of generated waves, the algorithm solves their respective slowness and particle polarization. With this information, the algorithm then solves a system of equations incorporating the imposed boundary conditions to arrive at the scattered wave amplitudes, and thus reflectivity and transmissivity. Reflectivity results as well as slowness and polarization are then tested in complex computational anisotropic models to ensure their accuracy and reliability. ARTc is coded in MATLAB ® and bundled with an interactive GUI and bash script to run on single or multi-processor computers.

  16. Anisotropic representations for superresolution of hyperspectral data

    NASA Astrophysics Data System (ADS)

    Bosch, Edward H.; Czaja, Wojciech; Murphy, James M.; Weinberg, Daniel

    2015-05-01

    We develop a method for superresolution based on anisotropic harmonic analysis. Our ambition is to efficiently increase the resolution of an image without blurring or introducing artifacts, and without integrating additional information, such as sub-pixel shifts of the same image at lower resolutions or multimodal images of the same scene. The approach developed in this article is based on analysis of the directional features present in the image that is to be superesolved. The harmonic analytic technique of shearlets is implemented in order to efficiently capture the directional information present in the image, which is then used to provide smooth, accurate images at higher resolutions. Our algorithm is compared to both a recent anisotropic technique based on frame theory and circulant matrices,1 as well as to the standard superresolution method of bicubic interpolation. We evaluate our algorithm on synthetic test images, as well as a hyperspectral image. Our results indicate the superior performance of anisotropic methods, when compared to standard bicubic interpolation.

  17. Anisotropic materials appearance analysis using ellipsoidal mirror

    NASA Astrophysics Data System (ADS)

    Filip, Jiří; Vávra, Radomír.

    2015-03-01

    Many real-world materials exhibit significant changes in appearance when rotated along a surface normal. The presence of this behavior is often referred to as visual anisotropy. Anisotropic appearance of spatially homogeneous materials is commonly characterized by a four-dimensional BRDF. Unfortunately, due to simplicity most past research has been devoted to three dimensional isotropic BRDFs. In this paper, we introduce an innovative, fast, and inexpensive image-based approach to detect the extent of anisotropy, its main axes and width of corresponding anisotropic highlights. The method does not rely on any moving parts and uses only an off-the-shelf ellipsoidal reflector with a compact camera. We analyze our findings with a material microgeometry scan, and present how results correspond to the microstructure of individual threads in a particular fabric. We show that knowledge of a material's anisotropic behavior can be effectively used in order to design a material-dependent sampling pattern so as the material's BRDF could be measured much more precisely in the same amount of time using a common gonioreflectometer.

  18. Electrospinning-thermal treatment synthesis: a general strategy to decorate highly porous nanotubes on both internal and external side-walls with metal oxide/noble metal nanoparticles

    NASA Astrophysics Data System (ADS)

    Zhao, Haitao; Lu, Bingan; Xu, Jing; Xie, Erqing; Wang, Taihong; Xu, Zhi

    2013-03-01

    The hybrid structure of nanoparticle-decorated highly porous nanotubes combines the advantages of large specific surface areas of nanoparticles and anisotropic properties of highly porous nanotubes, which is desirable for many applications, including batteries, photoelectrochemical water splitting, and catalysis. Here, we report a novel emulsion electrospinning-thermal treatment method to synthesize the nanoparticles deposited on both side walls of nanotubes with two unique characteristics: (1) large loading amount of nanoparticles per highly porous nanotubes (with the morphology of nanoparticles); (2) intimate contact between nanoparticles and highly porous nanotubes. Both features are advantageous for the above applications that involve both surface reactions and charge transportation processes. Moreover, the emulsion electrospinning-thermal treatment method is simple and straightforward, with which we have successfully decorated various highly porous metal oxide nanotubes with metal oxide or noble metal nanoparticles. The new method will have an impact on diverse technologies such as lithium ion batteries, catalysts, and photoelectrochemical devices.The hybrid structure of nanoparticle-decorated highly porous nanotubes combines the advantages of large specific surface areas of nanoparticles and anisotropic properties of highly porous nanotubes, which is desirable for many applications, including batteries, photoelectrochemical water splitting, and catalysis. Here, we report a novel emulsion electrospinning-thermal treatment method to synthesize the nanoparticles deposited on both side walls of nanotubes with two unique characteristics: (1) large loading amount of nanoparticles per highly porous nanotubes (with the morphology of nanoparticles); (2) intimate contact between nanoparticles and highly porous nanotubes. Both features are advantageous for the above applications that involve both surface reactions and charge transportation processes. Moreover, the

  19. Limitation of parallel flow in double diffusive convection: Two- and three-dimensional transitions in a horizontal porous domain

    SciTech Connect

    Mimouni, N.; Chikh, S.; Rahli, O.; Bennacer, R.

    2014-07-15

    Two-dimensional (2D) and three-dimensional (3D) numerical simulations of double diffusion natural convection in an elongated enclosure filled with a binary fluid saturating a porous medium are carried out in the present work. The Boussinesq approximation is made in the formulation of the problem, and Neumann boundary conditions for temperature and concentration are adopted, respectively, on vertical and horizontal walls of the cavity. The used numerical method is based on the control volume approach, with the third order quadratic upstream interpolation scheme in approximating the advection terms. A semi implicit method algorithm is used to handle the velocity-pressure coupling. To avoid the excessively high computer time inherent to the solution of 3D natural convection problems, full approximation storage with full multigrid method is used to solve the problem. A wide range of the controlling parameters (Rayleigh-Darcy number Ra, lateral aspect ratio Ay, Lewis number Le, and the buoyancy ration N) is investigated. We clearly show that increasing the depth of the cavity (i.e., the lateral aspect ratio) has an important effect on the flow patterns. The 2D perfect parallel flows obtained for small lateral aspect ratio are drastically destabilized by increasing the cavity lateral dimension. This yields a 3D fluid motion with a much more complex flow pattern and the usually considered 2D parallel flow model cannot be applied.

  20. Understanding conoscopic interference patterns in anisotropic crystals

    NASA Astrophysics Data System (ADS)

    Olorunsola, Oluwatobi Gabriel

    The interference patterns observed in conoscopy are important in studying the optical and geometrical properties of anisotropic materials. They have also been used to identify minerals and to explore the structure of biological tissues. In a conoscopic interferometer, an optically anisotropic specimen is placed between two crossed linear polarizers and illuminated by a convergent light beam. The interference patterns are produced because in an anisotropic material an incident light is split into two eigenwaves, namely the ordinary and the extraordinary waves. We report our work on the theoretical simulation and experimental observation of the conoscopic interference patterns in anisotropic crystals. In our simulation, the interference patterns are decomposed into fringes of isogyres and isochromates. For each light propagation direction inside the crystal there exist two eigenwaves that have their own characteristic velocities and vibration directions. The isogyres are obtained by computing the angle between the polarization of the incident light and the vibration directions of the two eigenwaves. The isochromates are obtained by computing the phase retardance between the two eigenwaves inside the crystal. The interference patterns are experimentally observed in several crystals, with their optic axes either parallel or perpendicular to their surfaces. An external electric field is applied to deform the crystals from uniaxial to biaxial. The results of our experimental observation agree well with our computer simulation. In conventional interferometers the isochromatic interference fringes are observed by using a circular polarizer and a circular analyzer, both constructed by a linear polarizer and a quarter wave plate. However, due to the dispersion of the quarter wave plates, the phase-retardance between the two light waves inside the quarter wave plates is wavelength-dependent, which results in different conoscopic interference patterns for different colors of

  1. A patterned anisotropic nanofluidic sieving structure for continuous-flow separation of DNA and proteins.

    PubMed

    Fu, Jianping; Schoch, Reto B; Stevens, Anna L; Tannenbaum, Steven R; Han, Jongyoon

    2007-02-01

    Microfabricated regular sieving structures hold great promise as an alternative to gels to improve the speed and resolution of biomolecule separation. In contrast to disordered porous gel networks, these regular structures also provide well defined environments ideal for the study of molecular dynamics in confining spaces. However, the use of regular sieving structures has, to date, been limited to the separation of long DNA molecules, however separation of smaller, physiologically relevant macromolecules, such as proteins, still remains a challenge. Here we report a microfabricated anisotropic sieving structure consisting of a two-dimensional periodic nanofluidic filter array. The designed structural anisotropy causes different-sized or -charged biomolecules to follow distinct trajectories, leading to efficient separation. Continuous-flow size-based separation of DNA and proteins, as well as electrostatic separation of proteins, was achieved, demonstrating the potential use of this device as a generic molecular sieving structure for an integrated biomolecule sample preparation and analysis system. PMID:18654231

  2. A patterned anisotropic nanofluidic sieving structure for continuous-flow separation of DNA and proteins

    NASA Astrophysics Data System (ADS)

    Fu, Jianping; Schoch, Reto B.; Stevens, Anna L.; Tannenbaum, Steven R.; Han, Jongyoon

    2007-02-01

    Microfabricated regular sieving structures hold great promise as an alternative to gels to improve the speed and resolution of biomolecule separation. In contrast to disordered porous gel networks, these regular structures also provide well defined environments ideal for the study of molecular dynamics in confining spaces. However, the use of regular sieving structures has, to date, been limited to the separation of long DNA molecules, however separation of smaller, physiologically relevant macromolecules, such as proteins, still remains a challenge. Here we report a microfabricated anisotropic sieving structure consisting of a two-dimensional periodic nanofluidic filter array. The designed structural anisotropy causes different-sized or -charged biomolecules to follow distinct trajectories, leading to efficient separation. Continuous-flow size-based separation of DNA and proteins, as well as electrostatic separation of proteins, was achieved, demonstrating the potential use of this device as a generic molecular sieving structure for an integrated biomolecule sample preparation and analysis system.

  3. Thermal conductivities of sub-micron Bi2Te3 films sputtered on anisotropic substrates

    NASA Astrophysics Data System (ADS)

    Yan, Dan; Wu, Ping; Zhang, Shiping; Pei, Yili; Yang, Fan; Wang, Li

    2016-07-01

    Approximately 450 nm thick Bi2Te3 films were deposited on flat Al2O3 substrate and nanochannel alumina (NCA) templates with different pore diameters through radio-frequency magnetron sputtering. The structure and morphology of Bi2Te3 films were investigated by x-ray diffraction and field-emission scanning electron microscopy. Moreover, the thermal conductivities of the films deposited on anisotropic substrates were evaluated by micro-Raman method combined with numerical simulation and optimization conducted by COMSOL Multiphysics. The thermal conductivities of Bi2Te3 films deposited on NCA templates with discontinuous Φ20 and Φ100 nm pores and flat Al2O3 substrate were 0.80, 0.99 and 1.54 Wm‑1 K‑1, respectively. The lower thermal conductivities of Bi2Te3 films deposited on NCA templates are attributed to much smaller grain size, bottom porous layers, and rougher surfaces through analysis.

  4. Post-Synthetic Anisotropic Wet-Chemical Etching of Colloidal Sodalite ZIF Crystals.

    PubMed

    Avci, Civan; Ariñez-Soriano, Javier; Carné-Sánchez, Arnau; Guillerm, Vincent; Carbonell, Carlos; Imaz, Inhar; Maspoch, Daniel

    2015-11-23

    Controlling the shape of metal-organic framework (MOF) crystals is important for understanding their crystallization and useful for myriad applications. However, despite the many advances in shaping of inorganic nanoparticles, post-synthetic shape control of MOFs and, in general, molecular crystals remains embryonic. Herein, we report using a simple wet-chemistry process at room temperature to control the anisotropic etching of colloidal ZIF-8 and ZIF-67 crystals. Our work enables uniform reshaping of these porous materials into unprecedented morphologies, including cubic and tetrahedral crystals, and even hollow boxes, by an acid-base reaction and subsequent sequestration of leached metal ions. Etching tests on these ZIFs reveal that etching occurs preferentially in the crystallographic directions richer in metal-ligand bonds; that, along these directions, the etching rate tends to be faster on the crystal surfaces of higher dimensionality; and that the etching can be modulated by adjusting the pH of the etchant solution.

  5. Rigid porous filter

    DOEpatents

    Chiang, Ta-Kuan; Straub, Douglas L.; Dennis, Richard A.

    2000-01-01

    The present invention involves a porous rigid filter including a plurality of concentric filtration elements having internal flow passages and forming external flow passages there between. The present invention also involves a pressure vessel containing the filter for the removal of particulates from high pressure particulate containing gases, and further involves a method for using the filter to remove such particulates. The present filter has the advantage of requiring fewer filter elements due to the high surface area-to-volume ratio provided by the filter, requires a reduced pressure vessel size, and exhibits enhanced mechanical design properties, improved cleaning properties, configuration options, modularity and ease of fabrication.

  6. Crosslinked, porous, polyacrylate beads

    NASA Technical Reports Server (NTRS)

    Rembaum, Alan (Inventor); Yen, Shiao-Ping S. (Inventor); Dreyer, William J. (Inventor)

    1977-01-01

    Uniformly-shaped, porous, round beads are prepared by the co-polymerization of an acrylic monomer and a cross-linking agent in the presence of 0.05 to 5% by weight of an aqueous soluble polymer such as polyethylene oxide. Cross-linking proceeds at high temperature above about 50.degree. C or at a lower temperature with irradiation. Beads of even shape and even size distribution of less than 2 micron diameter are formed. The beads will find use as adsorbents in chromatography and as markers for studies of cell surface receptors.

  7. Crosslinked, porous, polyacrylate beads

    NASA Technical Reports Server (NTRS)

    Rembaum, Alan (Inventor); Yen, Shiao-Ping Siao (Inventor); Dreyer, William J. (Inventor)

    1976-01-01

    Uniformly-shaped, porous, round beads are prepared by the co-polymerization of an acrylic monomer and a cross-linking agent in the presence of 0.05 to 5% by weight of an aqueous soluble polymer such as polyethylene oxide. Cross-linking proceeds at high temperature above about 50.degree.C or at a lower temperature with irradiation. Beads of even shape and even size distribution of less than 2 micron diameter are formed. The beads will find use as adsorbents in chromatography and as markers for studies of cell surface receptors.

  8. Small, porous polyacrylate beads

    NASA Technical Reports Server (NTRS)

    Rembaum, Alan (Inventor); Yen, Shiao-Ping Siao (Inventor); Dreyer, William J. (Inventor)

    1976-01-01

    Uniformly-shaped, porous, round beads are prepared by the co-polymerization of an acrylic monomer and a cross-linking agent in the presence of 0.05 to 5% by weight of an aqueous soluble polymer such as polyethylene oxide. Cross-linking proceeds at high temperature above about 50.degree.C or at a lower temperature with irradiation. Beads of even shape and even size distribution of less than 2 micron diameter are formed. The beads will find use as adsorbents in chromatography and as markers for studies of cell surface receptors.

  9. Testing different formulations of leading-order anisotropic hydrodynamics

    NASA Astrophysics Data System (ADS)

    Tinti, Leonardo; Ryblewski, Radoslaw; Florkowski, Wojciech; Strickland, Michael

    2016-02-01

    A recently obtained set of the equations for leading-order (3+1)D anisotropic hydrodynamics is tested against exact solutions of the Boltzmann equation with the collisional kernel treated in the relaxation time approximation. In order to perform detailed comparisons, the new anisotropic hydrodynamics equations are reduced to the boost-invariant and transversally homogeneous case. The agreement with the exact solutions found using the new anisotropic hydrodynamics equations is similar to that found using previous, less general formulations of anisotropic hydrodynamics. In addition, we find that, when compared to a state-of-the-art second-order viscous hydrodynamics framework, leading-order anisotropic hydrodynamics better reproduces the exact solution for the pressure anisotropy and gives comparable results for the bulk pressure evolution. Finally, we compare the transport coefficients obtained using linearized anisotropic hydrodynamics with results obtained using second-order viscous hydrodynamics.

  10. Analysis of electromagnetic scattering by uniaxial anisotropic bispheres.

    PubMed

    Li, Zheng-Jun; Wu, Zhen-Sen; Li, Hai-Ying

    2011-02-01

    Based on the generalized multiparticle Mie theory and the Fourier transformation approach, electromagnetic (EM) scattering of two interacting homogeneous uniaxial anisotropic spheres with parallel primary optical axes is investigated. By introducing the Fourier transformation, the EM fields in the uniaxial anisotropic spheres are expanded in terms of the spherical vector wave functions. The interactive scattering coefficients and the expansion coefficients of the internal fields are derived through the continuous boundary conditions on which the interaction of the bispheres is considered. Some selected calculations on the effects of the size parameter, the uniaxial anisotropic absorbing dielectric, and the sphere separation distance are described. The backward radar cross section of two uniaxial anisotropic spheres with a complex permittivity tensor changing with the sphere separation distance is numerically studied. The authors are hopeful that the work in this paper will help provide an effective calibration for further research on the scattering characteristic of an aggregate of anisotropic spheres or other shaped anisotropic particles.

  11. Fullerene-doped porous glasses

    NASA Astrophysics Data System (ADS)

    Joshi, M. P.; Kukreja, L. M.; Rustagi, K. C.

    We report the doping of C60 in porous glass by diffusion in solution phase at room temperature. The presence of C60 in the doped porous glass was confirmed spectroscopically. We also report the changes in optical absorption spectrum and intensity-dependent transmission of 30 ns laser pulses at 527 nm in these materials.

  12. Porous metallic bodies

    DOEpatents

    Landingham, Richard L.

    1985-01-01

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides are heated in a confining container at a controlled rate to a temperature of about greater than the temperature at which the hydride decomposes. Hydrogen is removed from the container and the remaining metal is heated during a second stage to a temperature greater than the temperature at which it was previously heated but not greater than the temperature of 1/2 to 2/3 the temperature at which the metal melts at a controlled rate. The resulting porous metallic body produced has a density less than about 25 percent theoretical and a pore size of less than about 200 microns. The metallic particles of the present invention have high inner surface area and possess minimum resistance to gas flow.

  13. Wetting of Porous Solids.

    PubMed

    Patkar, Saket; Chaudhuri, Parag

    2013-01-10

    This paper presents a simple, three stage method to simulate the mechanics of wetting of porous solid objects, like sponges and cloth, when they interact with a fluid. In the first stage, we model the absorption of fluid by the object when it comes in contact with the fluid. In the second stage, we model the transport of absorbed fluid inside the object, due to diffusion, as a flow in a deforming, unstructured mesh. The fluid diffuses within the object depending on saturation of its various parts and other body forces. Finally, in the third stage, over-saturated parts of the object shed extra fluid by dripping. The simulation model is motivated by the physics of imbibition of fluids into porous solids in the presence of gravity. It is phenomenologically capable of simulating wicking and imbibition, dripping, surface flows over wet media, material weakening and volume expansion due to wetting. The model is inherently mass conserving and works for both thin 2D objects like cloth and for 3D volumetric objects like sponges. It is also designed to be computationally efficient and can be easily added to existing cloth, soft body and fluid simulation pipelines. PMID:23319518

  14. Wetting of porous solids.

    PubMed

    Patkar, Saket; Chaudhuri, Parag

    2013-09-01

    This paper presents a simple, three stage method to simulate the mechanics of wetting of porous solid objects, like sponges and cloth, when they interact with a fluid. In the first stage, we model the absorption of fluid by the object when it comes in contact with the fluid. In the second stage, we model the transport of absorbed fluid inside the object, due to diffusion, as a flow in a deforming, unstructured mesh. The fluid diffuses within the object depending on saturation of its various parts and other body forces. Finally, in the third stage, oversaturated parts of the object shed extra fluid by dripping. The simulation model is motivated by the physics of imbibition of fluids into porous solids in the presence of gravity. It is phenomenologically capable of simulating wicking and imbibition, dripping, surface flows over wet media, material weakening, and volume expansion due to wetting. The model is inherently mass conserving and works for both thin 2D objects like cloth and for 3D volumetric objects like sponges. It is also designed to be computationally efficient and can be easily added to existing cloth, soft body, and fluid simulation pipelines. PMID:23846102

  15. Templated open flocs of anisotropic particles for pulmonary delivery with pressurized metered dose inhalers.

    PubMed

    Tam, Jasmine M; Engstrom, Josh D; Ferrer, Domingo; Williams, Robert O; Johnston, Keith P

    2010-07-01

    The challenges in forming stable drug suspensions in hydrofluoroalkane (HFA) propellants have limited drug dosages and efficiency of drug delivery with pressurized metered dose inhalers (pMDI). Herein, stable suspensions of weakly flocculated particles, in the shape of thin plates or needles, of a poorly water-soluble drug, itraconazole (Itz), are efficiently delivered by pMDI at high doses, up to 2.4 mg/actuation. These anisotropic particles pack inefficiently and form low-density flocs that stack upon each other to prevent settling. In contrast, spherical particles formed dense aggregates that settled within minutes. Upon actuation of the pMDI, atomized propellant droplets shear apart and thus template the highly friable flocs. Evaporation of the HFA compacts the flocs to yield porous particles with optimal aerodynamic properties. High fine particle fractions (49-64%) were achieved with the stable suspensions for drug loadings up to 50 mg/mL. Furthermore, the micron-sized particles, ideal for pulmonary delivery, are composed of nanoparticles that dissociate and facilitate rapid dissolution of poorly water-soluble drugs. Pulmonary delivery of stable suspensions of templated, open flocs is broadly applicable to a range of anisotropic particle morphologies for poorly water-soluble drugs and proteins for efficient delivery of high doses, up to several milligrams, using minimal amounts of excipients. PMID:20187139

  16. Tuning anisotropic electronic transport properties of phosphorene via substitutional doping.

    PubMed

    Guo, Caixia; Xia, Congxin; Fang, Lizhen; Wang, Tianxing; Liu, Yufang

    2016-10-01

    Using first-principles calculations, we studied the anisotropic electronic transport properties of pristine and X-doped phosphorene (X = B, Al, Ga, C, Si, Ge, N, As, O, S, and Se atoms). The results show that doping different elements can induce obviously different electronic transport characteristics. Moreover, isovalent doping maintains semiconducting characteristics and anisotropic transport properties, while group IV and VI atoms doping can induce metal properties. Meanwhile, Al and Ga substituting P decrease the anisotropic behaviors of transport, and other atom doping still preserves anisotropic characteristics. Interestingly, obvious negative differential resistance behaviors can be observed in C, Si, Ge, O, S, and Se-doped phosphorene.

  17. Polarisation of Thermal Emission under an Anisotropic Radiation

    NASA Astrophysics Data System (ADS)

    Onaka, T.

    1999-12-01

    Aspherical dust grains in an anisotropic radiation field have different temperatures depending on the cross-sections projected to the radiation. The temperature difference produces polarized thermal emission even without alignment, if the observer looks at the grains from a direction different from the anisotropic radiation. When the dust grains are aligned, the anisotropic radiation makes various affects on the polarization of the thermal emission, depending on the relative angle between the anisotropy and alignment directions. This paper presents examples of the effects and demonstrates the importance of anisotropic radiation field on the polarized thermal emission.

  18. Anisotropic hydrodynamics for a mixture of quark and gluon fluids

    NASA Astrophysics Data System (ADS)

    Florkowski, Wojciech; Maksymiuk, Ewa; Ryblewski, Radoslaw; Tinti, Leonardo

    2015-11-01

    A system of equations for anisotropic hydrodynamics is derived that describes a mixture of anisotropic quark and gluon fluids. The consistent treatment of the zeroth, first, and second moments of the kinetic equations allows us to construct a new framework with more general forms of the anisotropic phase-space distribution functions than used before. In this way, the main deficiencies of the previous formulations of anisotropic hydrodynamics for mixtures are overcome and a good agreement with the exact kinetic-theory results is obtained.

  19. Stability conditions for the Bianchi type II anisotropically inflating universes

    SciTech Connect

    Kao, W.F.; Lin, Ing-Chen E-mail: g9522528@oz.nthu.edu.tw

    2009-01-15

    Stability conditions for a class of anisotropically inflating solutions in the Bianchi type II background space are shown explicitly in this paper. These inflating solutions were known to break the cosmic no-hair theorem such that they do not approach the de Sitter universe at large times. It can be shown that unstable modes of the anisotropic perturbations always exist for this class of expanding solutions. As a result, we show that these set of anisotropically expanding solutions are unstable against anisotropic perturbations in the Bianchi type II space.

  20. On uniqueness and non-degeneracy of anisotropic polarons

    NASA Astrophysics Data System (ADS)

    Ricaud, Julien

    2016-05-01

    We study the anisotropic Choquard-Pekar equation which describes a polaron in an anisotropic medium. We prove the uniqueness and non-degeneracy of minimizers in a weakly anisotropic medium. In addition, for a wide range of anisotropic media, we derive the symmetry properties of minimizers and prove that the kernel of the associated linearized operator is reduced, apart from three functions coming from the translation invariance, to the kernel on the subspace of functions that are even in each of the three principal directions of the medium.

  1. Fluid flow in porous media with rough pore-solid interface

    NASA Astrophysics Data System (ADS)

    Ghanbarian, Behzad; Hunt, Allen G.; Daigle, Hugh

    2016-03-01

    Quantifying fluid flow through porous media hinges on the description of permeability, a property of considerable importance in many fields ranging from oil and gas exploration to hydrology. A common building block for modeling porous media permeability is consideration of fluid flow through tubes with circular cross section described by Poiseuille's law in which flow discharge is proportional to the fourth power of the tube's radius. In most natural porous media, pores are neither cylindrical nor smooth; they often have an irregular cross section and rough surfaces. This study presents a theoretical scaling of Poiseuille's approximation for flow in pores with irregular rough cross section quantified by a surface fractal dimension Ds2. The flow rate is a function of the average pore radius to the power 2(3-Ds2) instead of 4 in the original Poiseuille's law. Values of Ds2 range from 1 to 2, hence, the power in the modified Poiseuille's approximation varies between 4 and 2, indicating that flow rate decreases as pore surface roughness (and surface fractal dimension Ds2) increases. We also proposed pore length-radius relations for isotropic and anisotropic fractal porous media. The new theoretical derivations are compared with standard approximations and with experimental values of relative permeability. The new approach results in substantially improved prediction of relative permeability of natural porous media relative to the original Poiseuille equation.

  2. Experimental investigation of transverse mixing in porous media under helical flow conditions.

    PubMed

    Ye, Yu; Chiogna, Gabriele; Cirpka, Olaf A; Grathwohl, Peter; Rolle, Massimo

    2016-07-01

    Plume dilution and transverse mixing can be considerably enhanced by helical flow occurring in three-dimensional heterogeneous anisotropic porous media. In this study, we perform tracer experiments in a fully three-dimensional flow-through chamber to investigate the effects of helical flow on plume spiraling and deformation, as well as on its dilution. Porous media were packed in angled stripes of materials with different grain sizes to create blocks with macroscopically anisotropic hydraulic conductivity, which caused helical flows. Steady-state transport experiments were carried out by continuously injecting dye tracers at different inlet ports. High-resolution measurements of concentration and flow rates were performed at 49 outlet ports. These measurements allowed quantifying the spreading and dilution of the solute plumes at the outlet cross section. Direct evidence of plume spiraling and visual proof of helical flow was obtained by freezing and slicing the porous media at different cross sections and observing the dye-tracer distribution. We simulated flow and transport to interpret our experimental observations and investigate the effects of helical flow on mixing-controlled reactive transport. The simulation results were evaluated using metrics of reactive mixing such as the critical dilution index and the length of continuously injected steady-state plumes. The results show considerable reaction enhancement, quantified by the remarkable decrease of reactive plume lengths (up to four times) in helical flows compared to analogous scenarios in uniform flows. PMID:27575223

  3. Experimental investigation of transverse mixing in porous media under helical flow conditions.

    PubMed

    Ye, Yu; Chiogna, Gabriele; Cirpka, Olaf A; Grathwohl, Peter; Rolle, Massimo

    2016-07-01

    Plume dilution and transverse mixing can be considerably enhanced by helical flow occurring in three-dimensional heterogeneous anisotropic porous media. In this study, we perform tracer experiments in a fully three-dimensional flow-through chamber to investigate the effects of helical flow on plume spiraling and deformation, as well as on its dilution. Porous media were packed in angled stripes of materials with different grain sizes to create blocks with macroscopically anisotropic hydraulic conductivity, which caused helical flows. Steady-state transport experiments were carried out by continuously injecting dye tracers at different inlet ports. High-resolution measurements of concentration and flow rates were performed at 49 outlet ports. These measurements allowed quantifying the spreading and dilution of the solute plumes at the outlet cross section. Direct evidence of plume spiraling and visual proof of helical flow was obtained by freezing and slicing the porous media at different cross sections and observing the dye-tracer distribution. We simulated flow and transport to interpret our experimental observations and investigate the effects of helical flow on mixing-controlled reactive transport. The simulation results were evaluated using metrics of reactive mixing such as the critical dilution index and the length of continuously injected steady-state plumes. The results show considerable reaction enhancement, quantified by the remarkable decrease of reactive plume lengths (up to four times) in helical flows compared to analogous scenarios in uniform flows.

  4. Experimental investigation of transverse mixing in porous media under helical flow conditions

    NASA Astrophysics Data System (ADS)

    Ye, Yu; Chiogna, Gabriele; Cirpka, Olaf A.; Grathwohl, Peter; Rolle, Massimo

    2016-07-01

    Plume dilution and transverse mixing can be considerably enhanced by helical flow occurring in three-dimensional heterogeneous anisotropic porous media. In this study, we perform tracer experiments in a fully three-dimensional flow-through chamber to investigate the effects of helical flow on plume spiraling and deformation, as well as on its dilution. Porous media were packed in angled stripes of materials with different grain sizes to create blocks with macroscopically anisotropic hydraulic conductivity, which caused helical flows. Steady-state transport experiments were carried out by continuously injecting dye tracers at different inlet ports. High-resolution measurements of concentration and flow rates were performed at 49 outlet ports. These measurements allowed quantifying the spreading and dilution of the solute plumes at the outlet cross section. Direct evidence of plume spiraling and visual proof of helical flow was obtained by freezing and slicing the porous media at different cross sections and observing the dye-tracer distribution. We simulated flow and transport to interpret our experimental observations and investigate the effects of helical flow on mixing-controlled reactive transport. The simulation results were evaluated using metrics of reactive mixing such as the critical dilution index and the length of continuously injected steady-state plumes. The results show considerable reaction enhancement, quantified by the remarkable decrease of reactive plume lengths (up to four times) in helical flows compared to analogous scenarios in uniform flows.

  5. Chromo-natural model in anisotropic background

    SciTech Connect

    Maleknejad, Azadeh; Erfani, Encieh E-mail: eerfani@ipm.ir

    2014-03-01

    In this work we study the chromo-natural inflation model in the anisotropic setup. Initiating inflation from Bianchi type-I cosmology, we analyze the system thoroughly during the slow-roll inflation, from both analytical and numerical points of view. We show that the isotropic FRW inflation is an attractor of the system. In other words, anisotropies are damped within few e-folds and the chromo-natural model respects the cosmic no-hair conjecture. Furthermore, we demonstrate that in the slow-roll limit, the anisotropies in both chromo-natural and gauge-flation models share the same dynamics.

  6. A transitioning universe with anisotropic dark energy

    NASA Astrophysics Data System (ADS)

    Yadav, Anil Kumar

    2016-08-01

    In this paper, we present a model of transitioning universe with minimal interaction between perfect fluid and anisotropic dark energy in Bianchi I space-time. The two sources are assumed to minimally interacted and therefore their energy momentum tensors are conserved separately. The explicit expression for average scale factor are considered in hybrid form that gives time varying deceleration parameter which describes both the early and late time physical features of universe. We also discuss the physical and geometrical properties of the model derived in this paper. The solution is interesting physically as it explain accelerating universe as well as singularity free universe.

  7. Laminated anisotropic reinforced plastic plates and shells

    NASA Technical Reports Server (NTRS)

    Korolev, V. I.

    1981-01-01

    Basic technical theories and engineering calculation equations for anisotropic plates and shells made of rigid reinforced plastics, mainly laminated fiberglass, are presented and discussed. Solutions are given for many problems of design of structural plates and shells, including curved sections and tanks, as well as two chapters on selection of the optimum materials, are given. Accounting for interlayer shearing and transverse separation, which are new engineering properties, are discussed. Application of the results obtained to thin three ply plates and shells wth a light elastic filler is presented and discussed.

  8. Stresses in edge stiffened anisotropic sandwich plate

    NASA Astrophysics Data System (ADS)

    Rao, Koganti M.; Rao, Y. U. M.

    Hybrid-stress finite elements are used to study the static behavior of an edge stiffened anisotropic sandwich plate subjected to cylindrical bending. The stress concentration factors at the interface of core and stiffener are evaluated. The analysis of the simply-supported sandwich indicates that the state of stress at the interface of core and stiffener is increased and that the edge stiffener induces clamping conditions. The faces and stiffener at the edge are, respectively, subjected to negative and positive transverse shear, causing considerable bending action in faces about their own centroidal axis.

  9. Anisotropic perturbations due to dark energy

    NASA Astrophysics Data System (ADS)

    Battye, Richard A.; Moss, Adam

    2006-08-01

    A variety of observational tests seem to suggest that the Universe is anisotropic. This is incompatible with the standard dogma based on adiabatic, rotationally invariant perturbations. We point out that this is a consequence of the standard decomposition of the stress-energy tensor for the cosmological fluids, and that rotational invariance need not be assumed, if there is elastic rigidity in the dark energy. The dark energy required to achieve this might be provided by point symmetric domain wall network with P/ρ=-2/3, although the concept is more general. We illustrate this with reference to a model with cubic symmetry and discuss various aspects of the model.

  10. Hydrodynamics of anisotropic quark and gluon fluids

    NASA Astrophysics Data System (ADS)

    Florkowski, Wojciech; Maj, Radoslaw; Ryblewski, Radoslaw; Strickland, Michael

    2013-03-01

    The recently developed framework of anisotropic hydrodynamics is generalized to describe the dynamics of coupled quark and gluon fluids. The quark and gluon components of the fluids are characterized by different dynamical anisotropy parameters. The dynamical equations describing such mixtures are derived from kinetic theory, with the collisional kernel treated in the relaxation-time approximation, allowing for different relaxation times for quarks and gluons. Baryon number conservation is enforced in the quark and antiquark components of the fluid, but overall parton number nonconservation is allowed in the system. The resulting equations are solved numerically in the (0+1)-dimensional boost-invariant case at zero and finite baryon density.

  11. Coarsening dynamics in elastically anisotropic alloys

    SciTech Connect

    Pfau, B.; Stadler, L.-M.; Sepiol, B.; Vogl, G.; Weinkamer, R.; Kantelhardt, J. W.; Zontone, F.

    2006-05-01

    We study in situ the coarsening dynamics in elastically anisotropic phase-separating alloys, taking advantage of coherent x rays. Temporally fluctuating speckle intensities are analyzed for two different Ni-Al-Mo samples with different lattice misfits between precipitates and matrix. The detected long-term correlations depend not only on the norm but strongly on the direction of the scattering vector--an unambiguous proof of direction-dependent coarsening dynamics. For strong lattice misfits, our results indicate coalescence of precipitates in the {l_brace}100{r_brace} planes.

  12. Scattering by anisotropic grains in beryllium mirrors

    SciTech Connect

    Church, E.L. ); Takacs, P.Z. ); Stover, J.C. )

    1990-08-01

    Scattering from mirror surfaces arises from topographic and non-topographic sources. This paper considers the nontopographic scattering of beryllium mirrors modelled as a collection of randomly oriented bireflective grains. Simple scattering theory shows that this type of scatting scales as {lambda}{sup {minus}2}, rather than as {lambda}{sup {minus}4} for topographic scattering, which means that it is relatively more important at long radiation wavelengths. Estimates of the intensity based an available short-wavelength values of the anisotropic optical constants of beryllium indicate that this type of scattering could dominate the topographic scattering from smooth surfaces at CO{sub 2} wavelengths. 10 refs., 2 figs.

  13. Watertight Anisotropic Surface Meshing Using Quadrilateral Patches

    NASA Technical Reports Server (NTRS)

    Haimes, Robert; Aftosmis, Michael J.

    2004-01-01

    This paper presents a simple technique for generating anisotropic surface triangulations using unstructured quadrilaterals when the CAD entity can be mapped to a logical rectangle. Watertightness and geometric quality measures are maintained and are consistent with the CAPRI default tessellator. These triangulations can match user specified criteria for chord-height tolerance, neighbor triangle dihedral angle, and maximum triangle side length. This discrete representation has hooks back to the owning geometry and therefore can be used in conjunction with these entities to allow for easy enhancement or modification of the tessellation suitable for grid generation or other downstream applications.

  14. Anisotropic fiber alignment in composite structures

    DOEpatents

    Graham, A.L.; Mondy, L.A.; Guell, D.C.

    1993-11-16

    High strength material composite structures are formed with oriented fibers to provide controlled anisotropic fibers. Fibers suspended in non-dilute concentrations (e.g., up to 20 volume percent for fibers having an aspect ratio of 20) in a selected medium are oriented by moving an axially spaced array of elements in the direction of desired fiber alignment. The array elements are generally perpendicular to the desired orientation. The suspension medium may also include sphere-like particles where the resulting material is a ceramic. 5 figures.

  15. Anisotropic fiber alignment in composite structures

    DOEpatents

    Graham, Alan L.; Mondy, Lisa A.; Guell, David C.

    1993-01-01

    High strength material composite structures are formed with oriented fibers to provide controlled anisotropic fibers. Fibers suspended in non-dilute concentrations (e.g., up to 20 volume percent for fibers having an aspect ratio of 20) in a selected medium are oriented by moving an axially spaced array of elements in the direction of desired fiber alignment. The array elements are generally perpendicular to the desired orientation. The suspension medium may also include sphere-like particles where the resulting material is a ceramic.

  16. Some analytical models of anisotropic strange stars

    NASA Astrophysics Data System (ADS)

    Murad, Mohammad Hassan

    2016-01-01

    Over the years of the concept of local isotropy has become a too stringent condition in modeling relativistic self-gravitating objects. Taking local anisotropy into consideration, in this work, some analytical models of relativistic anisotropic charged strange stars have been developed. The Einstein-Maxwell gravitational field equations have been solved with a particular form of one of the metric potentials. The radial pressure and the energy density have been assumed to follow the usual linear equation of state of strange quark matter, the MIT bag model.

  17. Inhomogeneous viscous fluid in anisotropic inflationary universe

    NASA Astrophysics Data System (ADS)

    Sharif, M.; Mohsaneen, Sidra

    2015-06-01

    In this paper, we study inhomogeneous viscous fluid for inflation in the framework of locally rotationally symmetric Bianchi type I universe model. We consider an inhomogeneous equation of state with viscosity term to ensure a graceful exit from inflationary period. In order to study inflationary perturbations, we evaluate slow-roll parameters, scalar and tensor power spectra, scalar spectral index, tensor to scalar ratio for scalar field and inhomogeneous viscous fluid. It is concluded that our anisotropic inflationary universe model with inhomogeneous viscous fluid is consistent with recent data in a specific range of the model parameters.

  18. Generalized Jones matrices for anisotropic media.

    PubMed

    Ortega-Quijano, Noé; Arce-Diego, José Luis

    2013-03-25

    The interaction of arbitrary three-dimensional light beams with optical elements is described by the generalized Jones calculus, which has been formally proposed recently [Azzam, J. Opt. Soc. Am. A 28, 2279 (2011)]. In this work we obtain the parametric expression of the 3×3 differential generalized Jones matrix (dGJM) for arbitrary optical media assuming transverse light waves. The dGJM is intimately connected to the Gell-Mann matrices, and we show that it provides a versatile method for obtaining the macroscopic GJM of media with either sequential or simultaneous anisotropic effects. Explicit parametric expressions of the GJM for some relevant optical elements are provided.

  19. Anisotropic Tribological Properties of Silicon Carbide

    NASA Technical Reports Server (NTRS)

    Miyoshi, K.; Buckley, D. H.

    1980-01-01

    The anisotropic friction, deformation and fracture behavior of single crystal silicon carbide surfaces were investigated in two categories. The categories were called adhesive and abrasive wear processes, respectively. In the adhesive wear process, the adhesion, friction and wear of silicon carbide were markedly dependent on crystallographic orientation. The force to reestablish the shearing fracture of adhesive bond at the interface between silicon carbide and metal was the lowest in the preferred orientation of silicon carbide slip system. The fracturing of silicon carbide occurred near the adhesive bond to metal and it was due to primary cleavages of both prismatic (10(-1)0) and basal (0001) planes.

  20. Symmetries in the Anisotropic Kepler Problem

    NASA Astrophysics Data System (ADS)

    Mioc, Vasile

    The two-body problem associated to an anisotropic Newtonian-type potential function is being considered. We point out the complex symmetries that feature this problem. Such symmetries, expressed in standard polar coordinates, are recovered for McGee-type coordinates of both collision-blow-up kind and infinity-blow-up kind. They form isomorphic commutative groups endowed with an idempotent structure. Expressed in Levi-Civita's coordinates, the problem exhibits a larger group of symmetries, also commutative and endowed with an idempotent structure.

  1. Multichannel image regularization using anisotropic geodesic filtering

    SciTech Connect

    Grazzini, Jacopo A

    2010-01-01

    This paper extends a recent image-dependent regularization approach introduced in aiming at edge-preserving smoothing. For that purpose, geodesic distances equipped with a Riemannian metric need to be estimated in local neighbourhoods. By deriving an appropriate metric from the gradient structure tensor, the associated geodesic paths are constrained to follow salient features in images. Following, we design a generalized anisotropic geodesic filter; incorporating not only a measure of the edge strength, like in the original method, but also further directional information about the image structures. The proposed filter is particularly efficient at smoothing heterogeneous areas while preserving relevant structures in multichannel images.

  2. Generalized anisotropic turbulence spectra and applications in the optical waves' propagation through anisotropic turbulence.

    PubMed

    Cui, Linyan; Xue, Bindang; Zhou, Fugen

    2015-11-16

    Theoretical and experimental investigations have shown that the atmospheric turbulence exhibits both anisotropic and non-Kolmogorov properties. In this work, two theoretical atmosphere refractive-index fluctuations spectral models are derived for optical waves propagating through anisotropic non-Kolmogorov atmospheric turbulence. They consider simultaneously the finite turbulence inner and outer scales and the asymmetric property of turbulence eddies in the orthogonal xy-plane throughout the path. Two anisotropy factors which parameterize the asymmetry of turbulence eddies in both horizontal and vertical directions are introduced in the orthogonal xy-plane, so that the circular symmetry assumption of turbulence eddies in the xy-plane is no longer required. Deviations from the classic 11/3 power law behavior in the spectrum model are also allowed by assuming power law value variations between 3 and 4. Based on the derived anisotropic spectral model and the Rytov approximation theory, expressions for the variance of angle of arrival (AOA) fluctuations are derived for optical plane and spherical waves propagating through weak anisotropic non-Kolmogorov turbulence. Calculations are performed to analyze the derived spectral models and the variance of AOA fluctuations.

  3. Binary porous convection

    NASA Astrophysics Data System (ADS)

    Carey, Michael Richard

    Binary porous convection falls into the larger category of pattern formation---a symmetry breaking instability which creates a spatially periodic structure within a homogeneous system. The experiments and model presented in this dissertation indicate that an essential piece of physics is missing from the standard Darcian picture used to describe pattern formation in a porous medium convection system. Present theory predicts a bifurcation to an oscillatory state at onset for a binary mixture in a porous media over a wide range of experimental parameters (Brand and Steinberg, Physics Letters 93A 333 (1983)). This theory is inadequate in explaining the predominant large amplitude, backward, stationary overturning convection state observed in our experiments after transients have decayed. Convection experiments were visualized with magnetic resonance imaging and performed with a foam medium in slot and cylindrical geometries as well as a rectangular, packed bead system with water-ethanol mixtures. We explore the possibility that the difference between theory and experiment is due to enhanced solutal mixing not included in previous theories. The enhanced mixing of the fluid produces an effective diffusion coefficient that largely suppresses gradients in the concentration field, resulting in single-fluid like behavior. We model the experimental system with a Lorenz truncation of the binary Darcy equations with enhanced mixing. This model predicts results qualitatively similar to experiments: a forward bifurcation to small amplitude oscillations with a secondary backward bifurcation to large amplitude stationary convection. We have also developed an experimental nuclear magnetic resonance technique that measures the effective diffusion coefficient, D = D(v), as a function of velocity, v, for the individual species of the binary mixture simultaneously. However, the mixing effect measured in plug flow experiments is roughly two to three orders of magnitude too small to have

  4. A comparison of magnetic resonance methods for spatially resolved T2 distribution measurements in porous media

    NASA Astrophysics Data System (ADS)

    Vashaee, S.; Marica, F.; Newling, B.; Balcom, B. J.

    2015-05-01

    Naturally occurring porous media are usually characterized by a distribution of pore sizes. If the material is fluid saturated, the 1H magnetic resonance (MR) signal depends on the pore size, the surface relaxivity and the fluid itself. Measurement of the transverse relaxation time T2 is a well-established technique to characterize material samples by means of MR. T2 distribution measurements, including T2 distribution mapping, are widely employed in clinical applications and in petroleum engineering. T2 distribution measurements are the most basic measurement employed to determine the fluid-matrix properties in MR core analysis. Three methods for T2 distribution mapping, namely spin-echo single point imaging (SE-SPI), DANTE-Z Carr-Purcell-Meiboom-Gill (CPMG) and adiabatic inversion CPMG are compared in terms of spatial resolution, minimum observable T2 and sensitivity. Bulk CPMG measurement is considered to be the gold standard for T2 determination. Bulk measurement of uniform samples is compared to the three spatially resolved measurements. SE-SPI is an imaging method, which measures spatially resolved T2s in samples of interest. A variant is introduced in this work that employs pre-equalized magnetic field gradient waveforms and is therefore able to measure shorter T2s than previously reported. DANTE-Z CPMG and adiabatic inversion CPMG are faster, non-imaging, local T2 distribution measurements. The DANTE-Z pulse train and adiabatic inversion pulse are compared in terms of T1 or T2 relaxation time effects during the RF pulse application, minimum pulse duration, requisite RF pulse power, and inversion profile quality. In addition to experimental comparisons, simulation results are presented.

  5. Capillary-Driven Solute Transport and Precipitation in Porous Media during Dry-Out

    NASA Astrophysics Data System (ADS)

    Ott, Holger; Andrew, Matthew; Blunt, Martin; Snippe, Jeroen

    2014-05-01

    The injection of dry or under-saturated gases or supercritical (SC) fluids into water bearing formations might lead to a formation dry-out in the vicinity of the injection well. The dry-out is caused by the evaporation/dissolution of formation water into the injected fluid and the subsequent transport of dissolved water in the injected fluid away from the injection well. Dry-out results in precipitation from solutes of the formation brine and consequently leads to a reduction of the rock's pore space (porosity) and eventually to a reduction of permeability near the injection well, or even to the loss of injectivity. Recently evidence has been found that the complexity of the pore space and the respective capillary driven solute transport plays a key role. While no effective-permeability (Keff) reduction was observed in a single-porosity sandstone, multi porosity carbonate rocks responded to precipitation with a strong reduction of Keff. The reason for the different response of Keff to salt precipitation is suspected to be in the exact location of the precipitate (solid salt) in the pore space. In this study, we investigate dry-out and salt precipitation due to supercritical CO2 injection in single and multi-porosity systems under near well-bore conditions. We image fluid saturation changes by means of μCT scanning during desaturation. We are able to observe capillary driven transport of the brine phase and the respective transport of solutes on the rock's pore scale. Finally we have access to the precipitated solid-salt phase and their distribution. The results can proof the thought models behind permeability porosity relationships K(φ) for injectivity modeling. The topic and the mechanisms we show are of general interest for drying processes in porous material such as soils and paper.

  6. Infiltration through porous media

    NASA Astrophysics Data System (ADS)

    Hwang, W.; Redner, S.

    2001-02-01

    We study the kinetics of infiltration in which contaminant particles, which are suspended in a flowing carrier fluid, penetrate a porous medium. The progress of the ``invader'' particles is impeded by their trapping on active ``defender'' sites which are on the surfaces of the medium. As the defenders are used up, the invader penetrates further and ultimately breaks through. We study this process in the regime where the particles are much smaller than the pores so that the permeability change due to trapping is negligible. We develop a family of microscopic models of increasing realism to determine the propagation velocity of the invasion front, as well as the shapes of the invader and defender profiles. The predictions of our model agree qualitatively with experimental results on breakthrough times and the time dependence of the invader concentration at the output. Our results also provide practical guidelines for improving the design of deep bed filters in which infiltration is the primary separation mechanism.

  7. Combustion in porous media

    SciTech Connect

    Dillon, J.

    1999-09-01

    A 2.8-liter tube-shaped combustion vessel was constructed to study flame propagation and quenching in porous media. For this experiment, hydrogen-air flames propagating horizontally into abed of 6 mm diameter glass beads were studied. Measurements of pressure and temperature along the length of the tube were used to observe flame propagation of quenching. The critical hydrogen concentration for Hz-air mixtures was found to be 11.5%, corresponding to a critical Peclet number of Pe* = 37. This value is substantially less than the value of Pe* = 65 quoted in the literature, for example Babkin et al. (1991). It is hypothesized that buoyancy and a dependence of Pe on the Lewis number account for the discrepancy between these two results.

  8. Biogenic Cracks in Porous Rock

    NASA Astrophysics Data System (ADS)

    Hemmerle, A.; Hartung, J.; Hallatschek, O.; Goehring, L.; Herminghaus, S.

    2014-12-01

    Microorganisms growing on and inside porous rock may fracture it by various processes. Some of the mechanisms of biofouling and bioweathering are today identified and partially understood but most emphasis is on chemical weathering, while mechanical contributions have been neglected. However, as demonstrated by the perseverance of a seed germinating and cracking up a concrete block, the turgor pressure of living organisms can be very significant. Here, we present results of a systematic study of the effects of the mechanical forces of growing microbial populations on the weathering of porous media. We designed a model porous medium made of glass beads held together by polydimethylsiloxane (PDMS), a curable polymer. The rheological properties of the porous medium, whose shape and size are tunable, can be controlled by the ratio of crosslinker to base used in the PDMS (see Fig. 1). Glass and PDMS being inert to most chemicals, we are able to focus on the mechanical processes of biodeterioration, excluding any chemical weathering. Inspired by recent measurements of the high pressure (~0.5 Mpa) exerted by a growing population of yeasts trapped in a microfluidic device, we show that yeast cells can be cultured homogeneously within porous medium until saturation of the porous space. We investigate then the effects of such an inner pressure on the mechanical properties of the sample. Using the same model system, we study also the complex interplay between biofilms and porous media. We focus in particular on the effects of pore size on the penetration of the biofilm within the porous sample, and on the resulting deformations of the matrix, opening new perspectives into the understanding of life in complex geometry. Figure 1. Left : cell culture growing in a model porous medium. The white spheres represent the grains, bonds are displayed in grey, and microbes in green. Right: microscopy picture of glass beads linked by PDMS bridges, scale bar: 100 μm.

  9. Finite-difference schemes for anisotropic diffusion

    SciTech Connect

    Es, Bram van; Koren, Barry; Blank, Hugo J. de

    2014-09-01

    In fusion plasmas diffusion tensors are extremely anisotropic due to the high temperature and large magnetic field strength. This causes diffusion, heat conduction, and viscous momentum loss, to effectively be aligned with the magnetic field lines. This alignment leads to different values for the respective diffusive coefficients in the magnetic field direction and in the perpendicular direction, to the extent that heat diffusion coefficients can be up to 10{sup 12} times larger in the parallel direction than in the perpendicular direction. This anisotropy puts stringent requirements on the numerical methods used to approximate the MHD-equations since any misalignment of the grid may cause the perpendicular diffusion to be polluted by the numerical error in approximating the parallel diffusion. Currently the common approach is to apply magnetic field-aligned coordinates, an approach that automatically takes care of the directionality of the diffusive coefficients. This approach runs into problems at x-points and at points where there is magnetic re-connection, since this causes local non-alignment. It is therefore useful to consider numerical schemes that are tolerant to the misalignment of the grid with the magnetic field lines, both to improve existing methods and to help open the possibility of applying regular non-aligned grids. To investigate this, in this paper several discretization schemes are developed and applied to the anisotropic heat diffusion equation on a non-aligned grid.

  10. Measuring anisotropic muscle stiffness properties using elastography.

    PubMed

    Green, M A; Geng, G; Qin, E; Sinkus, R; Gandevia, S C; Bilston, L E

    2013-11-01

    Physiological and pathological changes to the anisotropic mechanical properties of skeletal muscle are still largely unknown, with only a few studies quantifying changes in vivo. This study used the noninvasive MR elastography (MRE) technique, in combination with diffusion tensor imaging (DTI), to measure shear modulus anisotropy in the human skeletal muscle in the lower leg. Shear modulus measurements parallel and perpendicular to the fibre direction were made in 10 healthy subjects in the medial gastrocnemius, soleus and tibialis anterior muscles. The results showed significant differences in the medial gastrocnemius (μ‖ = 0.86 ± 0.15 kPa; μ⊥ = 0.66 ± 0.19 kPa, P < 0.001), soleus (μ‖ = 0.83 ± 0.22 kPa; μ⊥ = 0.65 ± 0.13 kPa, P < 0.001) and the tibialis anterior (μ‖ = 0.78 ± 0.24 kPa; μ⊥ = 0.66 ± 0.16 kPa, P = 0.03) muscles, where the shear modulus measured in the direction parallel is greater than that measured in the direction perpendicular to the muscle fibres. No significant differences were measured across muscle groups. This study provides the first direct estimates of the anisotropic shear modulus in the triceps surae muscle group, and shows that the technique may be useful for the probing of mechanical anisotropy changes caused by disease, aging and injury.

  11. New formulation of leading order anisotropic hydrodynamics

    NASA Astrophysics Data System (ADS)

    Tinti, Leonardo

    2015-05-01

    Anisotropic hydrodynamics is a reorganization of the relativistic hydrodynamics expansion, with the leading order already containing substantial momentum-space anisotropies. The latter are a cause of concern in the traditional viscous hydrodynamics, since large momentum anisotropies generated in ultrarelativistic heavy-ion collisions are not consistent with the hypothesis of small deviations from an isotropic background, i.e., from the local equilibrium distribution. We discuss the leading order of the expansion, presenting a new formulation for the (1+1)- dimensional case, namely, for the longitudinally boost invariant and cylindrically symmetric flow. This new approach is consistent with the well established framework of Israel and Stewart in the close to equilibrium limit (where we expect viscous hydrodynamics to work well). If we consider the (0+1)-dimensional case, that is, transversally homogeneous and longitudinally boost invariant flow, the new form of anisotropic hydrodynamics leads to better agreement with known solutions of the Boltzmann equation than the previous formulations, especially when we consider massive particles.

  12. EuNiGe₃, an anisotropic antiferromagnet.

    PubMed

    Maurya, A; Bonville, P; Thamizhavel, A; Dhar, S K

    2014-05-28

    Single crystals of EuNiGe3, crystallizing in the non-centrosymmetric BaNiSn3-type structure, were grown using In flux, enabling us to explore the anisotropic magnetic properties, which was not possible with previously reported polycrystalline samples. The EuNiGe3 single crystalline sample is found to order antiferromagnetically at 13.2 K, as revealed from the magnetic susceptibility, heat capacity and electrical resistivity data. The low temperature magnetization M (H) is distinctly different for the field parallel to the ab-plane and c-axis; the ab-plane magnetization varies almost linearly with the field before the occurrence of an induced ferromagnetic (FM) phase (spin-flip) at 6.2 Tesla. On the other hand M (H) along the c-axis is accompanied by two metamagnetic transitions followed by a spin-flip at 4.1 T. A model including anisotropic exchange and dipole-dipole interactions reproduces the main features of magnetization plots but falls short of full representation. (H,T) phase diagrams have been constructed for the field applied along the principal directions. From the (151)Eu Mössbauer spectra, we determine that the 13.2 K transition leads to an incommensurate antiferromagnetic (AFM) intermediate phase followed by a transition near 10.5 K to a commensurate AFM configuration. PMID:24787717

  13. Anisotropic elliptic PDEs for feature classification.

    PubMed

    Wang, Shengfa; Hou, Tingbo; Li, Shuai; Su, Zhixun; Qin, Hong

    2013-10-01

    The extraction and classification of multitype (point, curve, patch) features on manifolds are extremely challenging, due to the lack of rigorous definition for diverse feature forms. This paper seeks a novel solution of multitype features in a mathematically rigorous way and proposes an efficient method for feature classification on manifolds. We tackle this challenge by exploring a quasi-harmonic field (QHF) generated by elliptic PDEs, which is the stable state of heat diffusion governed by anisotropic diffusion tensor. Diffusion tensor locally encodes shape geometry and controls velocity and direction of the diffusion process. The global QHF weaves points into smooth regions separated by ridges and has superior performance in combating noise/holes. Our method's originality is highlighted by the integration of locally defined diffusion tensor and globally defined elliptic PDEs in an anisotropic manner. At the computational front, the heat diffusion PDE becomes a linear system with Dirichlet condition at heat sources (called seeds). Our new algorithms afford automatic seed selection, enhanced by a fast update procedure in a high-dimensional space. By employing diffusion probability, our method can handle both manufactured parts and organic objects. Various experiments demonstrate the flexibility and high performance of our method. PMID:23929843

  14. Building an Anisotropic Meniscus with Zonal Variations

    PubMed Central

    Higashioka, Michael M.; Chen, Justin A.; Hu, Jerry C.

    2014-01-01

    Toward addressing the difficult problems of knee meniscus regeneration, a self-assembling process has been used to re-create the native morphology and matrix properties. A significant problem in such attempts is the recapitulation of the distinct zones of the meniscus, the inner, more cartilaginous and the outer, more fibrocartilaginous zones. In this study, an anisotropic and zonally variant meniscus was produced by self-assembly of the inner meniscus (100% chondrocytes) followed by cell seeding the outer meniscus (coculture of chondrocytes and meniscus cells). After 4 weeks in culture, the engineered, inner meniscus exhibited a 42% increase in both instantaneous and relaxation moduli and a 62% increase in GAG/DW, as compared to the outer meniscus. In contrast, the circumferential tensile modulus and collagen/DW of the outer zone was 101% and 129% higher, respectively, than the values measured for the inner zone. Furthermore, there was no difference in the radial tensile modulus between the control and zonal engineered menisci, suggesting that the inner and outer zones of the engineered zonal menisci successfully integrated. These data demonstrate that not only can biomechanical and biochemical properties be engineered to differ by the zone, but they can also recapitulate the anisotropic behavior of the knee meniscus. PMID:23931258

  15. Regeneratively Cooled Porous Media Jacket

    NASA Technical Reports Server (NTRS)

    Mungas, Greg (Inventor); Fisher, David J. (Inventor); London, Adam Pollok (Inventor); Fryer, Jack Merrill (Inventor)

    2013-01-01

    The fluid and heat transfer theory for regenerative cooling of a rocket combustion chamber with a porous media coolant jacket is presented. This model is used to design a regeneratively cooled rocket or other high temperature engine cooling jacket. Cooling jackets comprising impermeable inner and outer walls, and porous media channels are disclosed. Also disclosed are porous media coolant jackets with additional structures designed to transfer heat directly from the inner wall to the outer wall, and structures designed to direct movement of the coolant fluid from the inner wall to the outer wall. Methods of making such jackets are also disclosed.

  16. Light emission from porous silicon

    NASA Astrophysics Data System (ADS)

    Penczek, John

    The continuous evolution of silicon microelectronics has produced significant gains in electronic information processing. However, greater improvements in performance are expected by utilizing optoelectronic techniques. But these techniques have been severely limited in silicon- based optoelectronics due to the lack of an efficient silicon light emitter. The recent observation of efficient light emission from porous silicon offer a promising opportunity to develop a suitable silicon light source that is compatible with silicon microelectronics. This dissertation examined the porous silicon emission mechanism via photoluminescence, and by a novel device structure for porous silicon emitters. The investigation first examined the correlation between porous silicon formation conditions (and subsequent morphology) with the resulting photoluminescence properties. The quantum confinement theory for porous silicon light emission contends that the morphology changes induced by the different formation conditions determine the optical properties of porous silicon. The photoluminescence spectral shifts measured in this study, in conjunction with TEM analysis and published morphological data, lend support to this theory. However, the photoluminescence spectral broadening was attributed to electronic wavefunction coupling between adjacent silicon nanocrystals. An novel device structure was also investigated in an effort to improve current injection into the porous silicon layer. The selective etching properties of porous silicon were used to create a p-i-n structure with crystalline silicon contacts to the porous silicon layer. The resulting device was found to have unique characteristics, with a negative differential resistance region and current-induced emission that spanned from 400 nm to 5500 nm. The negative differential resistance was correlated to resistive heating effects in the device. A numerical analysis of thermal emission spectra from silicon films, in addition to

  17. A Direct Comparison between the Negative and Positive Effects of Throughflow on the Thermal Convection in an Anisotropy and Symmetry Porous Medium

    NASA Astrophysics Data System (ADS)

    Harfash, Akil J.; Alshara, Ahmed K.

    2015-05-01

    The linear and nonlinear stability analysis of the motionless state (conduction solution) and of a vertical throughflow in an anisotropic porous medium are tested. In particular, the effect of a nonhomogeneous porosity and a constant anisotropic thermal diffusivity have been taken into account. Then, the accuracy of the linear instability thresholds are tested using a three dimensional simulation. It is shown that the strong stabilising effect of gravity field. Moreover, the results support the assertion that the linear theory, in general, is accurate in predicting the onset of convective motion, and thus, regions of stability.

  18. Anisotropic superfluidity in a dipolar Bose gas

    SciTech Connect

    Ticknor, Christopher; Wilson, Ryan M; Bohn, John L

    2010-11-04

    so that the in-plane interaction is anisotropic. By induding repulsive contact interactions to ensure a stable system, we perform direct numeric simulations of an obstacle moving through the system in directions parallel and perpendicular to the tilt of the dipoles. We observe a distinct anisotropic superfluid response in these cases, both for dissipation into quasipartides and topological excitations (vortices), in the form of an anisotropic critical velocity that is larger in the direction of the dipole tilt than in the perpendicular direction. Interestingly, we find that, while the roton displays an anisotropic character, the speed of sound in the systrm is isotropic. Thus, we characterize the DBEC as an fmisotropic superfluid while illuminating the crucial role that the roton plays in this anisotropic behavior.

  19. Anisotropic artificial substrates for microwave applications

    NASA Astrophysics Data System (ADS)

    Shahvarpour, Attieh

    The perfect electromagnetic conductor (PEMC) boundary is a novel fundamental electromagnetic concept. It is a generalized description of the electromagnetic boundary conditions including the perfect electric conductor (PEC) and the perfect magnetic conductor (PMC) and due to its fundamental properties, it has the potential of enabling several electromagnetic applications. However, the PEMC boundaries concept had remained at the theoretical level and has not been practically realized. Therefore, motivated by the importance of this electromagnetic fundamental concept and its potential applications, the first contribution of this thesis is focused on the practical implementation of the PEMC boundaries by exploiting Faraday rotation principle and ground reflection in the ferrite materials which are intrinsically anisotropic. As a result, this thesis reports the first practical approach for the realization of PEMC boundaries. A generalized scattering matrix (GSM) is used for the analysis of the grounded-ferrite PEMC boundaries structure. As an application of the PEMC boundaries, a transverse electromagnetic (TEM) waveguide is experimentally demonstrated using grounded ferrite PMC (as particular case of the PEMC boundaries) side walls. Perfect electromagnetic conductor boundaries may find applications in various types of sensors, reflectors, polarization convertors and polarization-based radio frequency identifiers. Leaky-wave antennas perform as high directivity and frequency beam scanning antennas and as a result they enable applications in radar, point-to-point communications and MIMO systems. The second contribution of this thesis is introducing and analysing a novel broadband and highly directive two-dimensional leaky-wave antenna. This antenna operates differently in the lower and higher frequency ranges. Toward its lower frequencies, it allows full-space conical-beam scanning while at higher frequencies, it provides fixed-beam radiation (at a designable angle

  20. Fabrication and characterization of porous silicon nanowires

    NASA Astrophysics Data System (ADS)

    Jung, Daeyoon; Cho, Soo Gyeong; Moon, Taeho; Sohn, Honglae

    2016-01-01

    We report the synthesis of porous silicon nanowires through the metalassisted chemical etching of porous silicon in a solution of hydrofluoric acid and hydrogen peroxide. The morphology of porous silicon nanowires was characterized by scanning electron microscopy and transmission electron microscopy. The etch rate of the porous silicon nanowires was faster than that of silicon nanowires, but slower than that of porous silicon. The porous silicon nanowires distributed uniformly on the entire porous silicon layer and the tips of the porous silicon nanowires congregated together. The single crystalline and sponge-like porous structure with the pore diameters of less than 5 nm was confirmed for the porous silicon nanowires. [Figure not available: see fulltext.

  1. Seismic Absorption and Modulus Measurements in Porous Rocks Under Fluid and Gas Flow-Physical and Chemical Effects: a Laboratory Study

    SciTech Connect

    Harmut Spetzler

    2005-11-28

    This paper describes the culmination of a research project in which we investigated the complex modulus change in partially fluid saturated porous rocks. The investigation started with simple flow experiments over ''clean'' and ''contaminated'' surfaces, progressed to moduli measurements on partially filled single cracks, to measurements in ''clean'' and ''contaminated'' porous rocks and finally to a feasibility study in the field. For the experiments with the simple geometries we were able to measure fundamental physical properties such as contact angles of the meniscus and time dependent forces required to get the meniscus moving and to keep it moving at various velocities. From the data thus gathered we were able to interpret the complex elastic moduli data we measured in the partially saturated single cracks. While the geometry in real rocks is too complex to make precise calculations we determined that we had indeed identified the mechanisms responsible for the changes in the moduli we had measured. Thus encouraged by the laboratory studies we embarked on a field experiment in the desert of Arizona. The field site allowed for controlled irrigation. Instrumentation for fluid sampling and water penetration were already in place. The porous loosely consolidated rocks at the site were not ideal for finding the effects of the attenuation mechanism we had identified in the lab, but for logistic and cost constraint reasons we chose to field test the idea at that site. Tiltmeters and seismometers were installed and operated nearly continuously for almost 3 years. The field was irrigated with water in the fall of 2003 and with water containing a biosurfactant in the fall of 2004. We have indications that the biosurfactant irrigation has had a notable effect on the tilt data.

  2. Method for anisotropic etching in the manufacture of semiconductor devices

    NASA Technical Reports Server (NTRS)

    Koontz, Steven L. (Inventor); Cross, Jon B. (Inventor)

    1993-01-01

    Hydrocarbon polymer coatings used in microelectronic manufacturing processes are anisotropically etched by hyperthermal atomic oxygen beams (translational energies of 0.2 to 20 eV, preferably 1 to 10 eV). Etching with hyperthermal oxygen atom species obtains highly anisotropic etching with sharp boundaries between etched and mask protected areas.

  3. Long-Range Surface Plasmons on Highly Anisotropic Dielectric Substrates

    NASA Astrophysics Data System (ADS)

    Gumen, L.; Nagaraj; Neogi, A.; Krokhin, A.

    We calculate the propagation length of surface plasmons in metal-dielectric structures with anisotropic substrates. We show that the Joule losses can be minimized by appropriate orientation of the optical axis of a birefringent substrate and that the favorable orientation of the axis depends on ω. A simple Kronig-Penney model for anisotropic plasmonic crystal is also proposed.

  4. Anisotropic microporous supports impregnated with polymeric ion-exchange materials

    DOEpatents

    Friesen, Dwayne; Babcock, Walter C.; Tuttle, Mark

    1985-05-07

    Novel ion-exchange media are disclosed, the media comprising polymeric anisotropic microporous supports containing polymeric ion-exchange or ion-complexing materials. The supports are anisotropic, having small exterior pores and larger interior pores, and are preferably in the form of beads, fibers and sheets.

  5. Anisotropic microporous supports impregnated with polymeric ion-exchange materials

    DOEpatents

    Friesen, D.; Babcock, W.C.; Tuttle, M.

    1985-05-07

    Novel ion-exchange media are disclosed, the media comprising polymeric anisotropic microporous supports containing polymeric ion-exchange or ion-complexing materials. The supports are anisotropic, having small exterior pores and larger interior pores, and are preferably in the form of beads, fibers and sheets. 5 figs.

  6. Method for anisotropic etching in the manufacture of semiconductor devices

    DOEpatents

    Koontz, Steven L.; Cross, Jon B.

    1993-01-01

    Hydrocarbon polymer coatings used in microelectronic manufacturing processes are anisotropically etched by atomic oxygen beams (translational energies of 0.2-20 eV, preferably 1-10 eV). Etching with hyperthermal (kinetic energy>1 eV) oxygen atom species obtains highly anisotropic etching with sharp boundaries between etched and mask-protected areas.

  7. Optical isotropy at terahertz frequencies using anisotropic metamaterials

    NASA Astrophysics Data System (ADS)

    Lee, In-Sung; Sohn, Ik-Bu; Kang, Chul; Kee, Chul-Sik; Yang, Jin-Kyu; Lee, Joong Wook

    2016-07-01

    We demonstrate optically isotropic filters in the terahertz (THz) frequency range using structurally anisotropic metamaterials. The proposed metamaterials with two-dimensional arrangements of anisotropic H-shaped apertures show polarization-independent transmission due to the combined effects of the dipole resonances of resonators and antennas. Our results may offer the potential for the design and realization of versatile THz devices and systems.

  8. Forced convective heat transfer from anisotropic aluminum foam in a channel flow

    SciTech Connect

    Paek, J.W.; Kim, S.Y.; Kang, B.H.; Hyun, J.M.

    1999-07-01

    Porous media is employed widely in industrial applications which demand compact and highly efficient thermal systems, such as a substrate for catalyst and regenerative heat exchangers. The main advantage of porous media is high surface area-to-volume ratio, which leads to enhanced heat transport a condition necessary for the miniaturization of thermal systems. A recently introduced foam material is a highly permeable porous medium with porosity, typically {epsilon} {ge} 0.9, which can provide a considerably reduced pressure drop for the throughflow, compared with packed beds. Also, inherently inter-connected solid ligaments in the foam material increase the effective thermal conductivity of the entire system. By these favorable features for the heat transport, the foam material made of aluminum has emerged to be a promising candidate for enhanced heat transport. Convective heat transfer and pressure drop in anisotropic aluminum foam metal are investigated by experimental measurements. Anisotropic aluminum foam metal could be obtained by drilling holes in an isotropic foam metal. The porosity of aluminum foam metals used in the present study is fixed at around 0.92, and the Reynolds number varies from 250 to 2,100. The axial holes fabricated in the foam metal aim to reduce pressure loss through the foam metal while maintaining similar heat transfer rates to the isotropic foam. The experiments are implemented for wide ranges of governing parameters: the hole arrangement such as straight and interrupted holes, the staggered position of holes, the hole spacing 2.8 mm {lt} S {le} 35 mm, and the diameter of holes 1.0 mm {le} d {le} 6.0 mm. The results obtained in the present experiment indicate that the straight holes fabricated along the center line of the foam yield higher heat transfer rates against the pressure loss, compared with the other hole arrangement. It is also observed that there exists an optimal hole spacing and hole diameter, which can provide similar

  9. Anisotropic Properties of Stainless Steel—Clad Aluminum Sheet

    NASA Astrophysics Data System (ADS)

    Kim, Daeyong; Hwang, Bum Kyu; Lee, Young Seon; Kim, Ji Hoon; Kim, Min-Joong

    2010-06-01

    The production of a stainless steel—clad aluminum sheet by the cold rolling process is a more efficient and economical approach compared with the other types of processes utilized for the production of such sheets. Because both the stainless steel and aluminum sheets show the highly anisotropic behavior, it is necessary to investigate anisotropic properties of clad sheets for the design of process. In this paper, to investigate the anisotropic properties of stainless steel—clad aluminum sheet, two kinds of clad sheets were considered: STS439/AA3003 and STS439/AA1050/STS304 clad sheets. The uni-axial tension tests at 0, 45 and 90 degrees for the rolling direction were performed to obtained yield stresses and R values. The strain ratio at balanced biaxial tension state was measured from compression disk test. In order to describe the anisotropic behavior of the clad sheet, nonquadratic anisotropic yield function Yld2000-2d was utilized.

  10. Interfacing porous silicon with biomolecules

    NASA Astrophysics Data System (ADS)

    Sweetman, Martin J.; Graney, Sean D.; Voelcker, Nicolas H.

    2007-12-01

    The control of protein binding into nanostructured porous surfaces is highly relevant to the development of advanced biosensors and other biodevices. Here, an investigation of the covalent immobilisation of a model protein (albumin) onto porous silicon (pSi) films was conducted using a new alkene linker, the synthesis of which was developed. This alkene linker contained both hydrophobic and hydrophilic (oligoethylene glycol) sections and terminated in a protected thiol. The alkene was attached to freshly etched porous silicon via thermal hydrosilylation, where further surface reactions resulted in the attachment of a maleimido N-hydroxysuccinimidyl (NHS) heterobifunctional crosslinker. Albumin was then covalently immobilised on the porous silicon layer through reaction of the protein's amine groups and the NHS functional group of the crosslinker. Surface modification reactions were monitored by infrared spectroscopy and interferometric reflectance spectroscopy. Protein binding was monitored by infrared spectroscopy, fluorescence imaging and atomic force microscopy.

  11. Porous substrates filled with nanomaterials

    SciTech Connect

    Worsley, Marcus A.; Baumann, Theodore F.; Satcher, Jr., Joe H.; Stadermann, Michael

    2014-08-19

    A composition comprising: at least one porous carbon monolith, such as a carbon aerogel, comprising internal pores, and at least one nanomaterial, such as carbon nanotubes, disposed uniformly throughout the internal pores. The nanomaterial can be disposed in the middle of the monolith. In addition, a method for making a monolithic solid with both high surface area and good bulk electrical conductivity is provided. A porous substrate having a thickness of 100 microns or more and comprising macropores throughout its thickness is prepared. At least one catalyst is deposited inside the porous substrate. Subsequently, chemical vapor deposition is used to uniformly deposit a nanomaterial in the macropores throughout the thickness of the porous substrate. Applications include electrical energy storage, such as batteries and capacitors, and hydrogen storage.

  12. Capturing poromechanical coupling effects of the reactive fracturing process in porous rock via a DEM-network model

    NASA Astrophysics Data System (ADS)

    Ulven, Ole Ivar; Sun, WaiChing

    2016-04-01

    Fluid transport in a porous medium has important implications for understanding natural geological processes. At a sufficiently large scale, a fluid-saturated porous medium can be regarded as a two-phase continuum, with the fluid constituent flowing in the Darcian regime. Nevertheless, a fluid mediated chemical reaction can in some cases change the permeability of the rock locally: Mineral dissolution can cause increased permeability, whereas mineral precipitation can reduce the permeability. This might trigger a complicated hydro-chemo-mechanical coupling effect that causes channeling of fluids or clogging of the system. If the fluid is injected or produced at a sufficiently high rate, the pressure might increase enough to cause the onset and propagation of fractures. Fractures in return create preferential flow paths that enhance permeability, localize fluid flow and chemical reaction, prevent build-up of pore pressure and cause anisotropy of the hydro-mechanical responses of the effective medium. This leads to a complex coupled process of solid deformation, chemical reaction and fluid transport enhanced by the fracture formation. In this work, we develop a new coupled numerical model to study the complexities of feedback among fluid pressure evolution, fracture formation and permeability changes due to a chemical process in a 2D system. We combine a discrete element model (DEM) previously used to study a volume expanding process[1, 2] with a new fluid transport model based on poroelasticity[3] and a fluid-mediated chemical reaction that changes the permeability of the medium. This provides new insights into the hydro-chemo-mechanical process of a transforming porous medium. References [1] Ulven, O. I., Storheim, H., Austrheim, H., and Malthe-Sørenssen, A. "Fracture Initiation During Volume Increasing Reactions in Rocks and Applications for CO2 Sequestration", Earth Planet. Sc. Lett. 389C, 2014a, pp. 132 - 142, doi:10.1016/j.epsl.2013.12.039. [2] Ulven, O. I

  13. Transport of Graphene Oxide through Porous Media

    NASA Astrophysics Data System (ADS)

    Duster, T. A.; Na, C.; Bolster, D.; Fein, J. B.

    2012-12-01

    Graphene oxide (GO) is comprised of anisotropic nanosheets decorated with covalently-bonded epoxide, ketone, and hydroxyl functional groups on the basal planes, and carboxylic and phenolic functional groups at the edges. Individual GO nanosheets are generally two to three micrometers in width, with thicknesses depending on the degree of exfoliation and typically ranging from one to approximately 100 nanometers. As a result of this extraordinarily large surface area-to-mass ratio and the presence of numerous proton-active functional groups, GO nanosheets exhibit a tremendous capacity to adsorb metals and other contaminants from aqueous solutions and are thus often suggested for use in in situ remediation efforts. The potential importance of GO nanosheets as an adsorbent in soil and groundwater necessitates a detailed understanding of their mobility in environmental systems, but this topic remains largely unexplored. Hence, the objective of this study was to investigate the transport behavior of GO nanosheets through well-characterized saturated porous media. In this study, we used replicate glass columns packed with two different sand grain sizes, and within each treatment we varied pH (5.5 to 8.5), ionic strength (<0.01 M to 0.1 M), electrolyte composition (Na+ and Ca2+ salts), and GO nanosheet exfoliation extent (few-layered and many-layered) to determine the relative influence of both physical and electrochemical properties on GO nanosheet transport in these systems. The break-through of GO nanosheets from each treatment was continuously monitored using a flow-through quartz cuvette and UV-Vis absorbance at 230 nm. GO nanosheet transport through these systems was then modeled using distinct advection-dispersion equations to establish the relative influence of attachment, deposition, and detachment in the overall transport behavior, and a corresponding retardation coefficient was calculated for each treatment. Break-through curves displayed anomalous transport

  14. Steady Counterflow he II Heat Transfer Through Porous Media

    NASA Astrophysics Data System (ADS)

    Dalban-Canassy, M.; Van Sciver, S. W.

    2010-04-01

    We present steady state counterflow measurements performed on porous samples saturated in He II. The experiment is composed of a vacuum insulated open channel whose top extremity is closed to a Minco® heater. The temperature and pressure differences across the plug are measured by two germanium TTR-G Microsensors® thermometers and a Validyne DP10-20 differential pressure sensor. Applied heat fluxes range up to 0.5 kW/m2 of sample cross section. Measurements were performed at temperatures ranging from 1.7 to 2.1 K on highly anisotropic samples provided by Composite Technology Development Inc.: circular pellets (3.08 mm thick and 28.58 mm in diameter) of 20 compressed layers of pre-impregnated woven magnet insulation. In the laminar regime, the permeability is estimated from the pressure drop measurements for comparison with room temperature data. In the turbulent regime, the model based on tortuosity developed previously fails to describe the heat transfer behavior of He II in this type of porous medium.

  15. Two-Dimensional Phosphorus Porous Polymorphs with Tunable Band Gaps.

    PubMed

    Zhuo, Zhiwen; Wu, Xiaojun; Yang, Jinlong

    2016-06-01

    Exploring stable two-dimensional (2D) crystalline structures of phosphorus with tunable properties is of considerable importance partly due to the novel anisotropic behavior in phosphorene and potential applications in high-performance devices. Here, 21 new 2D phosphorus allotropes with porous structure are reported based on topological modeling method and first-principles calculations. We establish that stable 2D phosphorus crystals can be obtained by topologically assembling selected phosphorus monomer, dimer, trimer, tetramer, and hexamer. Nine of reported structures are predicted to be more stable than white phosphorus. Their dynamic and thermal stabilities are confirmed by the calculated vibration spectra and Born-Oppenheimer molecular dynamic simulation at temperatures up to 1500 K. These phosphorus porous polymorphs have isotropic mechanic properties that are significantly softer than phosphorene. The electronic band structures calculated with the HSE06 method indicate that new structures are semiconductors with band gaps ranging widely from 0.15 to 3.42 eV, which are tuned by the basic units assembled in the network. Of particular importance is that the position of both conduction and valence band edges of some allotropes matches well with the chemical reaction potential of H2/H(+) and O2/H2O, which can be used as element photocatalysts for visible-light-driven water splitting. PMID:27171121

  16. STEADY COUNTERFLOW HE II HEAT TRANSFER THROUGH POROUS MEDIA

    SciTech Connect

    Dalban-Canassy, M.; Van Sciver, S. W.

    2010-04-09

    We present steady state counterflow measurements performed on porous samples saturated in He II. The experiment is composed of a vacuum insulated open channel whose top extremity is closed to a Minco registered heater. The temperature and pressure differences across the plug are measured by two germanium TTR-G Microsensors registered thermometers and a Validyne DP10-20 differential pressure sensor. Applied heat fluxes range up to 0.5 kW/m{sup 2} of sample cross section. Measurements were performed at temperatures ranging from 1.7 to 2.1 K on highly anisotropic samples provided by Composite Technology Development Inc.: circular pellets (3.08 mm thick and 28.58 mm in diameter) of 20 compressed layers of pre-impregnated woven magnet insulation. In the laminar regime, the permeability is estimated from the pressure drop measurements for comparison with room temperature data. In the turbulent regime, the model based on tortuosity developed previously fails to describe the heat transfer behavior of He II in this type of porous medium.

  17. Porous light-emitting compositions

    DOEpatents

    Burrell, Anthony K.; McCleskey, Thomas Mark; Jia, Quanxi; Bauer, Eve; Mueller, Alexander H.

    2012-04-17

    Light-emitting devices are prepared by coating a porous substrate using a polymer-assisted deposition process. Solutions of metal precursor and soluble polymers having binding properties for metal precursor were coated onto porous substrates. The coated substrates were heated at high temperatures under a suitable atmosphere. The result was a substrate with a conformal coating that did not substantially block the pores of the substrate.

  18. Additively manufactured porous tantalum implants.

    PubMed

    Wauthle, Ruben; van der Stok, Johan; Amin Yavari, Saber; Van Humbeeck, Jan; Kruth, Jean-Pierre; Zadpoor, Amir Abbas; Weinans, Harrie; Mulier, Michiel; Schrooten, Jan

    2015-03-01

    The medical device industry's interest in open porous, metallic biomaterials has increased in response to additive manufacturing techniques enabling the production of complex shapes that cannot be produced with conventional techniques. Tantalum is an important metal for medical devices because of its good biocompatibility. In this study selective laser melting technology was used for the first time to manufacture highly porous pure tantalum implants with fully interconnected open pores. The architecture of the porous structure in combination with the material properties of tantalum result in mechanical properties close to those of human bone and allow for bone ingrowth. The bone regeneration performance of the porous tantalum was evaluated in vivo using an orthotopic load-bearing bone defect model in the rat femur. After 12 weeks, substantial bone ingrowth, good quality of the regenerated bone and a strong, functional implant-bone interface connection were observed. Compared to identical porous Ti-6Al-4V structures, laser-melted tantalum shows excellent osteoconductive properties, has a higher normalized fatigue strength and allows for more plastic deformation due to its high ductility. It is therefore concluded that this is a first step towards a new generation of open porous tantalum implants manufactured using selective laser melting.

  19. Additively manufactured porous tantalum implants.

    PubMed

    Wauthle, Ruben; van der Stok, Johan; Amin Yavari, Saber; Van Humbeeck, Jan; Kruth, Jean-Pierre; Zadpoor, Amir Abbas; Weinans, Harrie; Mulier, Michiel; Schrooten, Jan

    2015-03-01

    The medical device industry's interest in open porous, metallic biomaterials has increased in response to additive manufacturing techniques enabling the production of complex shapes that cannot be produced with conventional techniques. Tantalum is an important metal for medical devices because of its good biocompatibility. In this study selective laser melting technology was used for the first time to manufacture highly porous pure tantalum implants with fully interconnected open pores. The architecture of the porous structure in combination with the material properties of tantalum result in mechanical properties close to those of human bone and allow for bone ingrowth. The bone regeneration performance of the porous tantalum was evaluated in vivo using an orthotopic load-bearing bone defect model in the rat femur. After 12 weeks, substantial bone ingrowth, good quality of the regenerated bone and a strong, functional implant-bone interface connection were observed. Compared to identical porous Ti-6Al-4V structures, laser-melted tantalum shows excellent osteoconductive properties, has a higher normalized fatigue strength and allows for more plastic deformation due to its high ductility. It is therefore concluded that this is a first step towards a new generation of open porous tantalum implants manufactured using selective laser melting. PMID:25500631

  20. Influence of mechanochemical activation in various media on structure of porous and non-porous silicas

    NASA Astrophysics Data System (ADS)

    Sydorchuk, V.; Khalameida, S.; Zazhigalov, V.; Skubiszewska-Zięba, J.; Leboda, R.; Wieczorek-Ciurowa, K.

    2010-11-01

    Influence of mechanochemical activation on porous structure and surface properties of porous and non-porous silicas in air, water and ethanol has been studied. Milled samples have been investigated with help of nitrogen adsorption-desorption, mercury porometry, thermogravimetric analysis, FTIR and ESR spectroscopy. It has been revealed that destruction of porous structure of silicagel at dry milling and, on the contrary, formation of porous silica from non-porous powders (aerosils) during treatment in liquid media occurs.

  1. Primordial power spectra from anisotropic inflation

    SciTech Connect

    Dulaney, Timothy R.; Gresham, Moira I.

    2010-05-15

    We examine cosmological perturbations in a dynamical theory of inflation in which an Abelian gauge field couples directly to the inflaton, breaking conformal invariance. When the coupling between the gauge field and the inflaton takes a specific form, inflation becomes anisotropic and anisotropy can persist throughout inflation, avoiding Wald's no-hair theorem. After discussing scenarios in which anisotropy can persist during inflation, we calculate the dominant effects of a small persistent anisotropy on the primordial gravitational wave and curvature perturbation power spectra using the ''in-in'' formalism of perturbation theory. We find that the primordial power spectra of cosmological perturbations gain significant direction dependence and that the fractional direction dependence of the tensor power spectrum is suppressed in comparison to that of the scalar power spectrum.

  2. Effects of anisotropic heat conduction on solidification

    NASA Technical Reports Server (NTRS)

    Weaver, J. A.; Viskanta, R.

    1989-01-01

    Two-dimensional solidification influenced by anisotropic heat conduction has been considered. The interfacial energy balance was derived to account for the heat transfer in one direction (x or y) depending on the temperature gradient in both the x and y directions. A parametric study was made to determine the effects of the Stefan number, aspect ratio, initial superheat, and thermal conductivity ratios on the solidification rate. Because of the imposed boundary conditions, the interface became skewed and sometimes was not a straight line between the interface position at the upper and lower adiabatic walls (spatially nonlinear along the height). This skewness depends on the thermal conductivity ratio k(yy)/k(yx). The nonlinearity of the interface is influenced by the solidification rate, aspect ratio, and k(yy/k(yx).

  3. Isotropic and anisotropic surface wave cloaking techniques

    NASA Astrophysics Data System (ADS)

    McManus, T. M.; La Spada, L.; Hao, Y.

    2016-04-01

    In this paper we compare two different approaches for surface waves cloaking. The first technique is a unique application of Fermat’s principle and requires isotropic material properties, but owing to its derivation is limited in its applicability. The second technique utilises a geometrical optics approximation for dealing with rays bound to a two dimensional surface and requires anisotropic material properties, though it can be used to cloak any smooth surface. We analytically derive the surface wave scattering behaviour for both cloak techniques when applied to a rotationally symmetric surface deformation. Furthermore, we simulate both using a commercially available full-wave electromagnetic solver and demonstrate a good level of agreement with their analytically derived solutions. Our analytical solutions and simulations provide a complete and concise overview of two different surface wave cloaking techniques.

  4. Anisotropic criteria for the type of superconductivity

    SciTech Connect

    Kogan, Vladimir G; Prozorov, Ruslan

    2014-08-01

    The classical criterion for classification of superconductors as type I or type II based on the isotropic Ginzburg-Landau theory is generalized to arbitrary temperatures for materials with anisotropic Fermi surfaces and order parameters. We argue that the relevant quantity for this classification is the ratio of the upper and thermodynamic critical fields Hc2/Hc, rather than the traditional ratio of the penetration depth and the coherence length λ/ξ. Even in the isotropic case, Hc2/Hc coincides with 2√λ/ξ only at the critical temperature Tc and they differ as T decreases, the long-known fact. Anisotropies of Fermi surfaces and order parameters may amplify this difference and render false the criterion based on the value of κ=λ/ξ.

  5. Anisotropic Absorption of Pure Spin Currents

    NASA Astrophysics Data System (ADS)

    Baker, A. A.; Figueroa, A. I.; Love, C. J.; Cavill, S. A.; Hesjedal, T.; van der Laan, G.

    2016-01-01

    Spin transfer in magnetic multilayers offers the possibility of ultrafast, low-power device operation. We report a study of spin pumping in spin valves, demonstrating that a strong anisotropy of spin pumping from the source layer can be induced by an angular dependence of the total Gilbert damping parameter, α , in the spin sink layer. Using lab- and synchrotron-based ferromagnetic resonance, we show that an in-plane variation of damping in a crystalline Co50 Fe50 layer leads to an anisotropic α in a polycrystalline Ni81 Fe19 layer. This anisotropy is suppressed above the spin diffusion length in Cr, which is found to be 8 nm, and is independent of static exchange coupling in the spin valve. These results offer a valuable insight into the transmission and absorption of spin currents, and a mechanism by which enhanced spin torques and angular control may be realized for next-generation spintronic devices.

  6. Far field expansion for anisotropic wave equations

    NASA Technical Reports Server (NTRS)

    Hariharan, S. I.; Hagstrom, Thomas

    1989-01-01

    A necessary ingredient for the numerical simulation of many time dependent phenomena in acoustics and aerodynamics is the imposition of accurate radiation conditions at artificial boundaries. The asymptotic analysis of propagating waves provides a rational approach to the development of such conditions. A far field asymptotic expansion of solutions of anisotropic wave equations is derived. This generalizes the well known Friedlander expansion for the standard wave operator. The expansion is used to derive a hierarchy of radiation conditions of increasing accuracy. Two numerical experiments are given to illustrate the utility of this approach. The first application is the study of unsteady vortical disturbances impinging on a flat plate; the second is the simulation of inviscid flow past an impulsively started cylinder.

  7. Quarkonium states in an anisotropic QCD plasma

    SciTech Connect

    Dumitru, Adrian; Guo Yun; Mocsy, Agnes; Strickland, Michael

    2009-03-01

    We consider quarkonium in a hot quantum chromodynamics (QCD) plasma which, due to expansion and nonzero viscosity, exhibits a local anisotropy in momentum space. At short distances the heavy-quark potential is known at tree level from the hard-thermal loop resummed gluon propagator in anisotropic perturbative QCD. The potential at long distances is modeled as a QCD string which is screened at the same scale as the Coulomb field. At asymptotic separation the potential energy is nonzero and inversely proportional to the temperature. We obtain numerical solutions of the three-dimensional Schroedinger equation for this potential. We find that quarkonium binding is stronger at nonvanishing viscosity and expansion rate, and that the anisotropy leads to polarization of the P-wave states.

  8. Anisotropic Absorption of Pure Spin Currents.

    PubMed

    Baker, A A; Figueroa, A I; Love, C J; Cavill, S A; Hesjedal, T; van der Laan, G

    2016-01-29

    Spin transfer in magnetic multilayers offers the possibility of ultrafast, low-power device operation. We report a study of spin pumping in spin valves, demonstrating that a strong anisotropy of spin pumping from the source layer can be induced by an angular dependence of the total Gilbert damping parameter, α, in the spin sink layer. Using lab- and synchrotron-based ferromagnetic resonance, we show that an in-plane variation of damping in a crystalline Co_{50}Fe_{50} layer leads to an anisotropic α in a polycrystalline Ni_{81}Fe_{19} layer. This anisotropy is suppressed above the spin diffusion length in Cr, which is found to be 8 nm, and is independent of static exchange coupling in the spin valve. These results offer a valuable insight into the transmission and absorption of spin currents, and a mechanism by which enhanced spin torques and angular control may be realized for next-generation spintronic devices. PMID:26871353

  9. Effects of anisotropic heat conduction on solidification

    SciTech Connect

    Weaver, J.A.; Viskanta, R.

    1989-01-01

    Two-dimensional solidfication influenced by anisotropic heat conductions has been considered. The interfacial energy balance was derived to account for the heat transfer in one direction (x or y) depending on the temperature gradient in both the x and y directions. A parametric study was made to determine the effect of Stefan number, aspect ratio, initial superheat, and thermal conductivity ratios on the solidification rate. Because of the imposed boundary conditions, the interface became skewed and sometimes was not a straight line between the interface position at the upper and lower adiabatic walls (spatially nonlinear along the height). This skewness depends on the thermal conductivity ratio k/sub yy//k/sub yx/. The nonlinearity of the interface is influenced by the solidificaton rate, aspect ratio, and k/sub yy//k/sub yx/.

  10. 3D macrosegregation simulation with anisotropic remeshing

    NASA Astrophysics Data System (ADS)

    Gouttebroze, Sylvain; Bellet, Michel; Combeau, Hervé

    2007-05-01

    The article presents a three-dimensional coupled numerical solution of momentum, mass, energy and solute conservation equations, for binary alloy solidification. The interdendritic flow in the mushy zone is assumed to obey the Darcy's law. Microsegregation is governed by the lever rule, assuming local equilibrium at phase interfaces. The resulting energy and solute advection-diffusion equations are solved using the Streamline-Upwind/Petrov-Galerkin (SUPG) finite element method. A SUPG-PSPG velocity-pressure formulation is applied for the momentum equation. The full algorithm was implemented in the 3D code THERCAST, together with an anisotropic remeshing method. Two applications have been considered: a small ingot of Pb-48wt%Sn alloy and a large steel ingot. The numerical results of these two cases are presented with the evolution of temperature, liquid velocity, and solute concentration fields during solidification. To cite this article: S. Gouttebroze et al., C. R. Mecanique 335 (2007).

  11. Turbulent Output-Based Anisotropic Adaptation

    NASA Technical Reports Server (NTRS)

    Park, Michael A.; Carlson, Jan-Renee

    2010-01-01

    Controlling discretization error is a remaining challenge for computational fluid dynamics simulation. Grid adaptation is applied to reduce estimated discretization error in drag or pressure integral output functions. To enable application to high O(10(exp 7)) Reynolds number turbulent flows, a hybrid approach is utilized that freezes the near-wall boundary layer grids and adapts the grid away from the no slip boundaries. The hybrid approach is not applicable to problems with under resolved initial boundary layer grids, but is a powerful technique for problems with important off-body anisotropic features. Supersonic nozzle plume, turbulent flat plate, and shock-boundary layer interaction examples are presented with comparisons to experimental measurements of pressure and velocity. Adapted grids are produced that resolve off-body features in locations that are not known a priori.

  12. An Anisotropic Hardening Model for Springback Prediction

    NASA Astrophysics Data System (ADS)

    Zeng, Danielle; Xia, Z. Cedric

    2005-08-01

    As more Advanced High-Strength Steels (AHSS) are heavily used for automotive body structures and closures panels, accurate springback prediction for these components becomes more challenging because of their rapid hardening characteristics and ability to sustain even higher stresses. In this paper, a modified Mroz hardening model is proposed to capture realistic Bauschinger effect at reverse loading, such as when material passes through die radii or drawbead during sheet metal forming process. This model accounts for material anisotropic yield surface and nonlinear isotropic/kinematic hardening behavior. Material tension/compression test data are used to accurately represent Bauschinger effect. The effectiveness of the model is demonstrated by comparison of numerical and experimental springback results for a DP600 straight U-channel test.

  13. Anisotropic acoustic metafluid for underwater operation.

    PubMed

    Popa, Bogdan-Ioan; Wang, Wenqi; Konneker, Adam; Cummer, Steven A; Rohde, Charles A; Martin, Theodore P; Orris, Gregory J; Guild, Matthew D

    2016-06-01

    The paper presents a method to design and characterize mechanically robust solid acoustic metamaterials suitable for operation in dense fluids such as water. These structures, also called metafluids, behave acoustically as inertial fluids characterized by anisotropic mass densities and isotropic bulk modulus. The method is illustrated through the design and experimental characterization of a metafluid consisting of perforated steel plates held together by rubber coated magnetic spacers. The spacers are very effective at reducing the effective shear modulus of the structure, and therefore effective at minimizing the ensuing coupling between the shear and pressure waves inside the solid effective medium. Inertial anisotropy together with fluid-like acoustic behavior are key properties that bring transformation acoustics in dense fluids closer to reality. PMID:27369158

  14. Impact location estimation in anisotropic structures

    NASA Astrophysics Data System (ADS)

    Zhou, Jingru; Mathews, V. John; Adams, Daniel O.

    2015-03-01

    Impacts are major causes of in-service damage in aerospace structures. Therefore, impact location estimation techniques are necessary components of Structural Health Monitoring (SHM). In this paper, we consider impact location estimation in anisotropic composite structures using acoustic emission signals arriving at a passive sensor array attached to the structure. Unlike many published location estimation algorithms, the algorithm presented in this paper does not require the waveform velocity profile for the structure. Rather, the method employs time-of-arrival information to jointly estimate the impact location and the average signal transmission velocities from the impact to each sensor on the structure. The impact location and velocities are estimated as the solution of a nonlinear optimization problem with multiple quadratic constraints. The optimization problem is solved by using first-order optimality conditions. Numerical simulations as well as experimental results demonstrate the ability of the algorithm to accurately estimate the impact location using acoustic emission signals.

  15. Anisotropic magnetoresistance in manganites: experiment and theory.

    PubMed

    Fuhr, J D; Granada, M; Steren, L B; Alascio, B

    2010-04-14

    We present measurements of the anisotropic magnetoresistance (AMR) of La(0.75)Sr(0.25)MnO(3) films deposited on (001) SrTiO(3) substrates, and a model that describes the experimental results. The model, based on the electronic structure of manganites plus the spin-orbit coupling, correctly accounts for the dependence of the AMR on the direction of the current to the crystalline axes. We measure an AMR of the order of 10(-3) for the current I parallel to the [100] axis of the crystal and vanishing AMR for I , in agreement with the model predictions. Further, we calculate the planar Hall effect and show its connection to AMR.

  16. Cloaking with optimized homogeneous anisotropic layers

    NASA Astrophysics Data System (ADS)

    Popa, Bogdan-Ioan; Cummer, Steven A.

    2009-02-01

    We present a method to reduce the scattering from arbitrary objects by surrounding them with shells composed of several layers of homogeneous anisotropic materials. An optimization procedure is used to find the material parameters for each layer, the starting point of which is a discretized approximation of a coordinate transformation cloaking shell. We show that an optimized, three-layer shell can reduce the maximum scattering of an object by as much as 15dB more than a 100-layer realization of a coordinate transformation cloaking shell. Moreover, using an optimization procedure can yield high-performance cloaking shell solutions that also meet external constraints, such as the maximum value of permittivity or permeability. This design approach can substantially simplify the fabrication of moderate-size cloaking shells.

  17. Multistability of spontaneously curved anisotropic strips

    NASA Astrophysics Data System (ADS)

    Giomi, Luca; Mahadevan, L.

    2010-03-01

    Multistable structures are elastic objects, typically composite plates or shells, with more than one stable conformation. The common tape measure or the steel band enclosed inside the bright fabric cover of a ``slap bracelet'', are classic examples of plates that exhibit two stable configurations: folded and unfolded. Multistable structures have many potential applications, from the simple construction of objects of adjustable size to the design of mechanical devices that switch between a discrete number of states. In this talk I will discuss multistability in a quasi-one-dimensional anisotropic strip. The reduced dimensionality allows an exact analytical treatment in terms of the classic F"oppl - von K'arm'an theory of plates. In the conclusions I will comment on the possible occurrence of multistability in biological materials.

  18. Particle Behavior at Anisotropically Curved Liquid Interfaces

    NASA Astrophysics Data System (ADS)

    McEnnis, Kathleen; Zeng, Chuan; Davidovitch, Benny; Dinsmore, Anthony; Russell, Thomas

    2011-03-01

    A particle bound to an anisotropically curved liquid interface, such as a cylinder or catenoid, cannot maintain a constant contact angle without deforming the interface. Theory suggests that the particles will experience a force that depends on the interfacial shape and migrate to minimize the total interfacial energy. To test these predictions, particles were deposited on top of liquid semi-cylinders of ionic liquid or melted polystyrene confined on chemically patterned surfaces. Particles were also deposited on liquid catenoid structures created by placing a melted polymer film under an electric field. The location of the particles on these structures was observed by optical, confocal, and scanning electron microscopy. The implications for the directed assembly of particles and stability of Pickering emulsions are also discussed.

  19. Anisotropic Cloth Modeling for Material Fabric

    NASA Astrophysics Data System (ADS)

    Zhang, Mingmin; Pan, Zhigengx; Mi, Qingfeng

    Physically based cloth simulation has been challenging the graphics community for more than three decades. With the developing of virtual reality and clothing CAD, it has become the key technique of virtual garment and try-on system. Although it has received considerable attention in computer graphics, due to its flexible property and realistic feeling that the textile engineers pay much attention to, there is not a successful methodology to simulate cloth both in visual realism and physical accuracy. We present a new anisotropic textile modeling method based on physical mass-spring system, which models the warps and wefts separately according to the different material fabrics. The simulation process includes two main steps: firstly the rigid object simulation and secondly the flexible mass simulation near to be equilibrium. A multiresolution modeling is applied to enhance the tradeoff fruit of the realistic presentation and computation cost. Finally, some examples and the analysis results show the efficiency of the proposed method.

  20. Sur le remodelage des tissus osseux anisotropes

    NASA Astrophysics Data System (ADS)

    DiCarlo, Antonio; Naili, Salah; Quiligotti, Sara

    2006-11-01

    Growth (change of relaxed lengths) and remodelling (change of mechanical properties) are both involved in the morphogenesis of biological tissues. To model them is of paramount import for progressing both in scientific understanding and health technologies. We model bone tissue as a microstructured continuum, whose mechanical properties at the macroscopic scale are described by a linear, anisotropic elastic response that evolves in time. Our kinematics is rich enough to allow for the microstructural evolution, as well as for the interplay between stress, growth and remodelling. This is a unified approach to the mechanics of growth and remodelling, in which all balance laws derive from one virtual-power principle. As a first application, we study the problem of stiffness remodelling due to planar rotation of the microstructure, excluding bulk growth and all physiological response to mechanical stimuli (passive remodelling). To cite this article: A. DiCarlo et al., C. R. Mecanique 334 (2006).

  1. Adiabatic theory for anisotropic cold molecule collisions

    SciTech Connect

    Pawlak, Mariusz; Shagam, Yuval; Narevicius, Edvardas; Moiseyev, Nimrod

    2015-08-21

    We developed an adiabatic theory for cold anisotropic collisions between slow atoms and cold molecules. It enables us to investigate the importance of the couplings between the projection states of the rotational motion of the atom about the molecular axis of the diatom. We tested our theory using the recent results from the Penning ionization reaction experiment {sup 4}He(1s2s {sup 3}S) + HD(1s{sup 2}) → {sup 4}He(1s{sup 2}) + HD{sup +}(1s) + e{sup −} [Lavert-Ofir et al., Nat. Chem. 6, 332 (2014)] and demonstrated that the couplings have strong effect on positions of shape resonances. The theory we derived provides cross sections which are in a very good agreement with the experimental findings.

  2. Physical modification of the interior surfaces of PLGA porous scaffolds using sugar fibers as template.

    PubMed

    Qu, Zehua; Ding, Jiandong

    2013-01-01

    A three-dimensional (3D) poly(D,L-lactic-co-glycolic acid) porous scaffold with microgrooves and microholes on the pore walls was fabricated by using salt particulates as main porogens and sugar fibers as modifiers. Besides macropores templated from salt particulates, microgrooves and microholes were generated after leaching sugar fibers. The resultant porous scaffolds were of high porosity over 90% and still kept good mechanical properties. The microgrooves were globally randomly distributed, but locally anisotropic, resulting in contact guidance of cells, and an appropriate fraction of fibers in fabrication of 3D scaffolds led to a significantly enhanced cell viability; the microholes increased the loading amount of a model protein bovine serum albumin. Two key ideal parameters of this technical strategy, the full coverage amount of sugar fibers on the salt particulates, m(c), and the ratio of the surface areas of modified and unmodified scaffolds S(in)=S(in,o) were defined and derived.

  3. Standing shear waves in anisotropic viscoelastic media

    NASA Astrophysics Data System (ADS)

    Krit, T.; Golubkova, I.; Andreev, V.

    2015-10-01

    We studied standing shear waves in anisotropic resonator represented by a rectangular parallelepiped (layer) fixed without slipping between two wooden plates of finite mass. The viscoelastic layer with edges of 70 mm × 40 mm × 15 mm was made of a rubber-like polymer plastisol with rubber bands inside. The bands were placed vertical between the top and the bottom plate. Mechanical properties of the plastisol itself were carefully measured previously. It was found that plastisol shows a cubic nonlinear behavior, i.e. the stress-strain curve could be represented as: σ = μɛ + βμɛ3, where ɛ stands for shear strain and σ is an applied shear stress. The value of shear modulus μ depends on frequency and was found to be several kilopascals which is common for such soft solids. Nonlinear parameter β is frequency dependent too and varies in range from tenths to unity at 1-100 Hz frequency range, decreasing with frequency growth. Stretching the rubber bands inside the layer leads to change of elastic properties in resonator. Such effect could be noticed due to frequency response of the resonator. The numerical model of the resonator was based on finite elements method (FEM) and performed in MatLab. The resonator was cut in hundreds of right triangular prisms. Each prism was provided with viscoelastic properties of the layer except for the top prisms provided with the wooden plate properties and the prisms at the site of the rubber bands provided with the rubber properties. The boundary conditions on each prism satisfied the requirements that resonator is inseparable and all its boundaries but bottom are free. The bottom boundary was set to move horizontally with constant acceleration amplitude. It was shown numerically that the resonator shows anisotropic behavior expressed in different frequency response to oscillations applied to a bottom boundary in different directions.

  4. A POROUS, LAYERED HELIOPAUSE

    SciTech Connect

    Swisdak, M.; Drake, J. F.; Opher, M. E-mail: drake@umd.edu

    2013-09-01

    The picture of the heliopause (HP)-the boundary between the domains of the Sun and the local interstellar medium (LISM)-as a pristine interface with a large rotation in the magnetic field fails to describe recent Voyager 1 (V1) data. Magnetohydrodynamic (MHD) simulations of the global heliosphere reveal that the rotation angle of the magnetic field across the HP at V1 is small. Particle-in-cell simulations, based on cuts through the MHD model at V1's location, suggest that the sectored region of the heliosheath (HS) produces large-scale magnetic islands that reconnect with the interstellar magnetic field while mixing LISM and HS plasma. Cuts across the simulation reveal multiple, anti-correlated jumps in the number densities of LISM and HS particles, similar to those observed, at the magnetic separatrices. A model is presented, based on both the observations and simulations, of the HP as a porous, multi-layered structure threaded by magnetic fields. This model further suggests that contrary to the conclusions of recent papers, V1 has already crossed the HP.

  5. Enhancement of non-resonant dielectric cloaks using anisotropic composites

    NASA Astrophysics Data System (ADS)

    Takezawa, Akihiro; Kitamura, Mitsuru

    2014-01-01

    Cloaking techniques conceal objects by controlling the flow of electromagnetic waves to minimize scattering. Herein, the effectiveness of homogenized anisotropic materials in non-resonant dielectric multilayer cloaking is studied. Because existing multilayer cloaking by isotropic materials can be regarded as homogenous anisotropic cloaking from a macroscopic view, anisotropic materials can be efficiently designed through optimization of their physical properties. Anisotropic properties can be realized in two-phase composites if the physical properties of the material are within appropriate bounds. The optimized anisotropic physical properties are identified by a numerical optimization technique based on a full-wave simulation using the finite element method. The cloaking performance measured by the total scattering width is improved by about 2.8% and 25% in eight- and three-layer cylindrical cloaking materials, respectively, compared with multilayer cloaking by isotropic materials. In all cloaking examples, the optimized microstructures of the two-phase composites are identified as the simple lamination of two materials, which maximizes the anisotropy. The same performance as published for eight-layer cloaking by isotropic materials is achieved by three-layer cloaking using the anisotropic material. Cloaking with an approximately 50% reduction of total scattering width is achieved even in an octagonal object. Since the cloaking effect can be realized using just a few layers of the laminated anisotropic dielectric composite, this may have an advantage in the mass production of cloaking devices.

  6. Lattice Boltzmann simulation of solute transport in heterogeneous porous media with conduits to estimate macroscopic continuous time random walk model parameters

    SciTech Connect

    Anwar, S.; Cortis, A.; Sukop, M.

    2008-10-20

    Lattice Boltzmann models simulate solute transport in porous media traversed by conduits. Resulting solute breakthrough curves are fitted with Continuous Time Random Walk models. Porous media are simulated by damping flow inertia and, when the damping is large enough, a Darcy's Law solution instead of the Navier-Stokes solution normally provided by the lattice Boltzmann model is obtained. Anisotropic dispersion is incorporated using a direction-dependent relaxation time. Our particular interest is to simulate transport processes outside the applicability of the standard Advection-Dispersion Equation (ADE) including eddy mixing in conduits. The ADE fails to adequately fit any of these breakthrough curves.

  7. Intensity fluctuations of asymmetrical optical beams in anisotropic turbulence.

    PubMed

    Baykal, Yahya

    2016-09-20

    Intensity fluctuations of asymmetrical optical beams are examined when such beams propagate through anisotropic turbulence. Anisotropic turbulence is modeled by non-Kolmogorov von Kármán spectrum. The variations of the scintillation index are observed against the changes in the asymmetry factor of the Gaussian beam, power law exponent of non-Kolmogorov spectrum, anisotropic factors in the transverse direction, and the link length. It is found that for all the conditions, asymmetry in the optical beam is a disadvantage but the anisotropy in the atmosphere is an advantage for reducing the intensity fluctuations in an optical wireless communications link operating in the atmosphere. PMID:27661570

  8. Renormalized anisotropic exchange for representing heat assisted magnetic recording media

    SciTech Connect

    Jiao, Yipeng; Liu, Zengyuan; Victora, R. H.

    2015-05-07

    Anisotropic exchange has been incorporated in a description of magnetic recording media near the Curie temperature, as would be found during heat assisted magnetic recording. The new parameters were found using a cost function that minimized the difference between atomistic properties and those of renormalized spin blocks. Interestingly, the anisotropic exchange description at 1.5 nm discretization yields very similar switching and magnetization behavior to that found at 1.2 nm (and below) discretization for the previous isotropic exchange. This suggests that the increased accuracy of anisotropic exchange may also reduce the computational cost during simulation.

  9. Anisotropic Nanomechanics of Boron Nitride Nanotubes: Nanostructured "Skin" Effect

    NASA Technical Reports Server (NTRS)

    Srivastava, Deepak; Menon, Madhu; Cho, KyeongJae

    2000-01-01

    The stiffness and plasticity of boron nitride nanotubes are investigated using generalized tight-binding molecular dynamics and ab-initio total energy methods. Due to boron-nitride BN bond buckling effects, compressed zigzag BN nanotubes are found to undergo novel anisotropic strain release followed by anisotropic plastic buckling. The strain is preferentially released towards N atoms in the rotated BN bonds. The tubes buckle anisotropically towards only one end when uniaxially compressed from both. A "skin-effect" model of smart nanocomposite materials is proposed which will localize the structural damage towards the 'skin' or surface side of the material.

  10. Fabrication of a porous membrane for the gas pre-combustion

    NASA Astrophysics Data System (ADS)

    Stuermann, Joerg; Boedecker, Andre; Splinter, Alexandra; Benecke, Wolfgang

    2003-01-01

    This paper presents a micro reactor, which consists of a permeable membrane fabricated by silicon micro machining technology. The fabrication process is a combination of anisotropic silicon etching (wet etching and dry etching) and porous silicon technology. To avoid a reaction chamber with a high dead volume, we have realised a permeable membrane in conjunction with porous silicon to achieve a high surface to volume ratio, impregnated with palladium or platinum. For the activation of the heterogeneous reaction on the surface of the catalytic material a heating element around the permeable membrane, which is thermally decoupled with a porous silicon well of the surrounding bulk material is realised. The gas flows through the membrane and reacts during the passing time. The reaction time for gases depends on the membrane thickness and the active surface of the porous silicon. The application is the integration into a gas analysing system combined with a gas sensor array, a gas chromatographic system, microvalves, and calibration units mounted all on a pneumatic motherboard.

  11. Anisotropic nature of radially strained metal tubes

    NASA Astrophysics Data System (ADS)

    Strickland, Julie N.

    Metal pipes are sometimes swaged by a metal cone to enlarge them, which increases the strain in the material. The amount of strain is important because it affects the burst and collapse strength. Burst strength is the amount of internal pressure that a pipe can withstand before failure, while collapse strength is the amount of external pressure that a pipe can withstand before failure. If the burst or collapse strengths are exceeded, the pipe may fracture, causing critical failure. Such an event could cost the owners and their customers millions of dollars in clean up, repair, and lost time, in addition to the potential environmental damage. Therefore, a reliable way of estimating the burst and collapse strength of strained pipe is desired and valuable. The sponsor currently rates strained pipes using the properties of raw steel, because those properties are easily measured (for example, yield strength). In the past, the engineers assumed that the metal would be work-hardened when swaged, so that yield strength would increase. However, swaging introduces anisotropic strain, which may decrease the yield strength. This study measured the yield strength of strained material in the transverse and axial direction and compared them to raw material, to determine the amount of anisotropy. This information will be used to more accurately determine burst and collapse ratings for strained pipes. More accurate ratings mean safer products, which will minimize risk for the sponsor's customers. Since the strained metal has a higher yield strength than the raw material, using the raw yield strength to calculate burst and collapse ratings is a conservative method. The metal has even higher yield strength after strain aging, which indicates that the stresses are relieved. Even with the 12% anisotropy in the strained and 9% anisotropy in the strain aged specimens, the raw yield strengths are lower and therefore more conservative. I recommend that the sponsor continue using the raw

  12. Fabrication of anisotropic multifunctional colloidal carriers

    NASA Astrophysics Data System (ADS)

    Jerri, Huda A.

    The field of colloidal assembly has grown tremendously in recent years, although the direct or template-assisted methods used to fabricate complex colloidal constructions from monodisperse micro- and nanoparticles have been generally demonstrated on model materials. In this work, novel core particle syntheses, particle functionalizations and bottom-up assembly techniques are presented to create functional colloidal devices. Using particle lithography, high-information colloidal vectors have been developed and modified with imaging and targeting agents. Localized nanoscale patches have been reliably positioned on microparticles to serve as foundations for further chemical or physical modifications. Site-specific placement of RGD targeting ligands has been achieved in these lithographed patches. Preferential uptake of these targeted vectors by RGD-specific 3T3 fibroblasts was verified using confocal laser scanning microscopy. A transition was made from the functionalization of model imaging core particles to the lithography of colloidal cartridges, in an effort to construct colloidal syringes with specialized, programmable release profiles. A variety of functional, pH-sensitive fluorescent cores were engineered to respond to solution conditions. When triggered, the diverse composite core microparticles and reservoir microcapsules released embedded fluorescent moieties such as dye molecules, and fluorophore-conjugated nanoparticles. The microcapsules, created using layer-by-layer polyelectrolyte deposition on sacrificial templates, were selectively modified with a robust coating. The pH-responsive anisotropic reservoir microcapsules were extremely stable in solution, and exhibited a "Lazarus" functionality of rehydrating to their original state following desiccation. A snapshot of focused-release of core constituents through the lone opening in colloidal monotremes has been obtained by anisotropically-functionalizing degradable cores with barrier shells. Additionally

  13. Acoustic Absorption in Porous Materials

    NASA Technical Reports Server (NTRS)

    Kuczmarski, Maria A.; Johnston, James C.

    2011-01-01

    An understanding of both the areas of materials science and acoustics is necessary to successfully develop materials for acoustic absorption applications. This paper presents the basic knowledge and approaches for determining the acoustic performance of porous materials in a manner that will help materials researchers new to this area gain the understanding and skills necessary to make meaningful contributions to this field of study. Beginning with the basics and making as few assumptions as possible, this paper reviews relevant topics in the acoustic performance of porous materials, which are often used to make acoustic bulk absorbers, moving from the physics of sound wave interactions with porous materials to measurement techniques for flow resistivity, characteristic impedance, and wavenumber.

  14. Novel anisotropic engineered cardiac tissues: studies of electrical propagation

    PubMed Central

    Bursac, Nenad; Loo, Yihua; Leong, Kam; Tung, Leslie

    2007-01-01

    The goal of this study was to engineer cardiac tissue constructs with uniformly anisotropic architecture, and to evaluate their electrical function using multi-site optical mapping of cell membrane potentials. Anisotropic polymer scaffolds made by leaching of aligned sucrose templates were seeded with neonatal rat cardiac cells and cultured in rotating bioreactors for 6-14 days. Cells aligned and interconnected inside the scaffolds and when stimulated by a point electrode, supported macroscopically continuous, anisotropic impulse propagation. By culture day 14, the ratio of conduction velocities along vs. across cardiac fibers reached a value of 2, similar to that in native neonatal ventricles, while action potential duration and maximum capture rate respectively decreased to 120 ms and increased to ~5 Hz. The shorter culture time and larger scaffold thickness were associated with increased incidence of sustained reentrant arrhythmias. In summary, this study is the first successful attempt to engineer a cm2-size, functional anisotropic cardiac tissue patch. PMID:17689494

  15. Autofocus imaging: Experimental results in an anisotropic austenitic weld

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Drinkwater, B. W.; Wilcox, P. D.; Hunter, A.

    2012-05-01

    The quality of an ultrasonic array image, especially for anisotropic material, depends on accurate information about acoustic properties. Inaccuracy of acoustic properties causes image degradation, e.g., blurring, errors in locating of reflectors and introduction of artifacts. In this paper, for an anisotropic austenitic steel weld, an autofocus imaging technique is presented. The array data from a series of beacons is captured and then used to statistically extract anisotropic weld properties by using a Monte-Carlo inversion approach. The beacon and imaging systems are realized using two separated arrays; one acts as a series of beacons and the other images these beacons. Key to the Monte-Carlo inversion scheme is a fast forward model of wave propagation in the anisotropic weld and this is based on the Dijkstra algorithm. Using this autofocus approach a measured weld map was extracted from an austenitic weld and used to reduce location errors, initially greater than 6mm, to less than 1mm.

  16. Variational bounds on the effective moduli of anisotropic composites

    NASA Astrophysics Data System (ADS)

    Milton, Graeme W.; Kohn, Robert V.

    THE VRITIONAL inequalities of Hashin and Shtrikman are transformed to a simple and concise form. They are used to bound the effective conductivity tensor σ∗ of an anisotropic composite made from an arbitrary number of possibly anisotropic phases, and to bound the effective elasticity tensor C∗ of an anisotropic mixture of two well-ordered isotropic materials. The bounds depend on the conductivities and elastic moduli of the components and their respective volume fractions. When the components are isotropic the conductivity bounds, which constrain the eigenvalues of σ∗, include those previously obtained by Hashin and Shtrikman, Murat and Tartar, and Lurie and Cherkaev. Our approach can also be used in the context of linear elasticity to derive bounds on C∗ for composites comprised of an arbitrary number of anisotropic phases. For two-component composites our bounds are tighter than those obtained by Kantor and Bergman and by Francfort and Murat, and are attained by sequentially layered laminate materials.

  17. Joining porous components to solid metal structures

    NASA Technical Reports Server (NTRS)

    Fortini, A.; Tulisiak, G.

    1972-01-01

    Process for joining porous metal material to solid metal structure without cracking or blockage of porous component is described. Procedures of electron beam welding and electroforming are discussed. Illustration of microstructure resulting from process is included.

  18. Anisotropic Bianchi types VIII and IX locally rotationally symmetric cosmologies

    SciTech Connect

    Assad, M.J.D.; Soares, I.D.

    1983-10-15

    We present a class of exact cosmological solutions of Einstein-Maxwell equations, which are anisotropic and spatially homogeneous of Bianchi types VIII and IX, and class IIIb in the Stewart-Ellis classification of locally rotationally symmetric models. If we take the electromagnetic field equal to zero, a class of Bianchi types VIII/IX spatially homogeneous anisotropic cosmological solutions with perfect fluid is obtained.

  19. On the electrodynamics of Josephson effect in anisotropic superconductors

    SciTech Connect

    Mints, R.G.

    1989-01-01

    Specificities of Josephson effect electrodynamics in anisotropic superconductors are of considerable interest for the study of high temperature superconductors with strongly anisotropic layered structure. In this paper the authors give the calculation for the tunnel Josephson contact of an isolated vortex, the law of dispersion of its low-amplitude oscillations, the critical field H/sub cl/ for the penetration of magnetic flux, and the maximum current across a rectangular contact.

  20. Schwarz alternating methods for anisotropic problems with prolate spheroid boundaries.

    PubMed

    Dai, Zhenlong; Du, Qikui; Liu, Baoqing

    2016-01-01

    The Schwarz alternating algorithm, which is based on natural boundary element method, is constructed for solving the exterior anisotropic problem in the three-dimension domain. The anisotropic problem is transformed into harmonic problem by using the coordinate transformation. Correspondingly, the algorithm is also changed. Continually, we analysis the convergence and the error estimate of the algorithm. Meanwhile, we give the contraction factor for the convergence. Finally, some numerical examples are computed to show the efficiency of this algorithm. PMID:27625977

  1. Metal recovery from porous materials

    DOEpatents

    Sturcken, Edward F.

    1992-01-01

    A method for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF.sub.4 and HNO.sub.3 and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200.degree. C. The porous material can be pulverized before immersion to further increase the leach rate.

  2. Anisotropic universe with magnetized dark energy

    NASA Astrophysics Data System (ADS)

    Goswami, G. K.; Dewangan, R. N.; Yadav, Anil Kumar

    2016-04-01

    In the present work we have searched the existence of the late time acceleration of the Universe filled with cosmic fluid and uniform magnetic field as source of matter in anisotropic Heckmann-Schucking space-time. The observed acceleration of universe has been explained by introducing a positive cosmological constant Λ in the Einstein's field equation which is mathematically equivalent to vacuum energy with equation of state (EOS) parameter set equal to -1. The present values of the matter and the dark energy parameters (Ωm)0 & (Ω_{Λ})0 are estimated in view of the latest 287 high red shift (0.3 ≤ z ≤1.4) SN Ia supernova data's of observed apparent magnitude along with their possible error taken from Union 2.1 compilation. It is found that the best fit value for (Ωm)0 & (Ω_{Λ})0 are 0.2820 & 0.7177 respectively which are in good agreement with recent astrophysical observations in the latest surveys like WMAP [2001-2013], Planck [latest 2015] & BOSS. Various physical parameters such as the matter and dark energy densities, the present age of the universe and deceleration parameter have been obtained on the basis of the values of (Ωm)0 & (Ω_{Λ})0. Also we have estimated that the acceleration would have begun in the past at z = 0.71131 ˜6.2334 Gyrs before from present.

  3. Details of tetrahedral anisotropic mesh adaptation

    NASA Astrophysics Data System (ADS)

    Jensen, Kristian Ejlebjerg; Gorman, Gerard

    2016-04-01

    We have implemented tetrahedral anisotropic mesh adaptation using the local operations of coarsening, swapping, refinement and smoothing in MATLAB without the use of any for- N loops, i.e. the script is fully vectorised. In the process of doing so, we have made three observations related to details of the implementation: 1. restricting refinement to a single edge split per element not only simplifies the code, it also improves mesh quality, 2. face to edge swapping is unnecessary, and 3. optimising for the Vassilevski functional tends to give a little higher value for the mean condition number functional than optimising for the condition number functional directly. These observations have been made for a uniform and a radial shock metric field, both starting from a structured mesh in a cube. Finally, we compare two coarsening techniques and demonstrate the importance of applying smoothing in the mesh adaptation loop. The results pertain to a unit cube geometry, but we also show the effect of corners and edges by applying the implementation in a spherical geometry.

  4. Anisotropic photoinduced current injection in graphene

    NASA Astrophysics Data System (ADS)

    Rioux, Julien; Sipe, John E.; Burkard, Guido

    2014-03-01

    Quantum-mechanical interference effects are considered in carrier and charge current excitation in gapless semiconductors using coherent optical field components at frequencies ω and 2 ω . Due to the absence of a bandgap, excitation scenarios outside of the typical operation regime are considered; we calculate the polarization and spectral dependence of these all-optical effects for single- and bilayer graphene. For linearly-polarized light and with one-photon absorption at ω interfering with 2 ω absorption and ω emission, the resulting current injection is five times stronger for perpendicular polarization axes compared to parallel polarization axes. This additional process results in an anisotropic current as a function of the angle between polarization axes, in stark contrast with the isotropic current resulting from the typical interference term in graphene [Rioux et al., PRB 83, 195406 (2011)]. Varying the Fermi level allows to tune the disparity parameter d closer to typical values in GaAs [ | d | ~ 0 . 2 , Rioux and Sipe, Physica E 45, 1 (2012)]: from -1, when the additional process is fully Pauli-blocked, to -3/7, when it is fully accessible, thus facilitating polarization sensitive applications.

  5. Anisotropic reflectance characteristics of natural Earth surfaces.

    PubMed

    Brennan, B; Bandeen, W R

    1970-02-01

    The patterns of reflection of solar radiation from cloud, water, and land surfaces were measured with an aircraft-borne medium resolution radiometer. Reflectances in the 0.2-4.0-micro and 0.55-0.85-micro portions of the electromagnetic spectrum were investigated. Results indicate that the reflectance characteristics of most of the surface types measured are anisotropic. The anisotropy is dependent on the type of surface and the angles of incidence and reflection. In general, the anisotropy increases with increasing solar zenith angle. Clouds and forests show similar reflectance patterns, with forward and backward scattering peaks. Ocean surfaces yield a pattern similar to those of the clouds and forests but with an additional peak which is associated with sun glitter. Reflectances measured in the 0.2-4.0-micro band are generally lower than those in the 0.55-0.85-micro band under cloudy conditions. Anisotropy and spectral bandwidth should be accounted for when computing the albedo of the earth from narrow field-of-view measurements from satellites; otherwise, large errors may be expected to occur.

  6. Colloidal aggregation and dynamics in anisotropic fluids

    PubMed Central

    Mondiot, Frédéric; Botet, Robert; Snabre, Patrick; Mondain-Monval, Olivier; Loudet, Jean-Christophe

    2014-01-01

    We present experiments and numerical simulations to investigate the collective behavior of submicrometer-sized particles immersed in a nematic micellar solution. We use latex spheres with diameters ranging from 190 to 780 nm and study their aggregation properties due to the interplay of the various colloidal forces at work in the system. We found that the morphology of aggregates strongly depends on the particle size, with evidence for two distinct regimes: the biggest inclusions clump together within minutes into either compact clusters or V-like structures that are completely consistent with attractive elastic interactions. On the contrary, the smallest particles form chains elongated along the nematic axis, within comparable timescales. In this regime, Monte Carlo simulations, based on a modified diffusion-limited cluster aggregation model, strongly suggest that the anisotropic rotational Brownian motion of the clusters combined with short-range depletion interactions dominate the system coarsening; elastic interactions no longer prevail. The simulations reproduce the sharp transition between the two regimes on increasing the particle size. We provide reasonable estimates to interpret our data and propose a likely scenario for colloidal aggregation. These results emphasize the growing importance of the diffusion of species at suboptical-wavelength scales and raise a number of fundamental issues. PMID:24715727

  7. Dynamic wetting on anisotropic patterned surfaces

    NASA Astrophysics Data System (ADS)

    Do-Quang, Minh; Wang, Jiayu; Nita, Satoshi; Shiomi, Junichiro; Amberg, Gustav; Physiochemical fluid mechanics Team; Maruyama-Chiashi Laboratory Team

    2014-11-01

    Dynamic wetting, as occurs when a droplet of a wetting liquid is brought in contact with a dry solid, is important in various engineering processes, such as printing, coating, and lubrication. Our overall aim is to investigate if and how the detailed properties of the solid surface influence the dynamics of wetting. We have recently quantified the hindering effect of fairly isotropic micron-sized patterns on the substrate. Here we will study highly anisotropic surfaces, such as parallel grooves, either perpendicular or parallel to an advancing contact line. This is done by detailed phase field simulations and experiments on structured silicon surfaces. The dynamic wetting behavior of drops on the grooved surfaces is governed by the combined interplay of the wetting line friction and the internal viscous dissipation. Influence of roughness is quantified in terms of the energy dissipation rate at the contact line using the experiment-simulation combined analysis. The energy dissipation of the contact line at the different part of the groove will be discussed. The performance of the model is assessed by comparing its predictions with the experimental data. This work was financially supported in part by, the Japan Society for the Promotion of Science (J.W., S.N., and J.S) and Swedish Governmental Agency for Innovation Systems (M.D.-Q. and G.A).

  8. Self assembly of anisotropic colloidal particles

    NASA Astrophysics Data System (ADS)

    Florea, Daniel; Wyss, Hans

    2012-02-01

    Colloidal particles have been successfully used as ''model atoms'', as their behavior can be more directly studied than that of atoms or molecules by direct imaging in a confocal microscope. Most studies have focussed on spherical particles with isotropic interactions. However, a range of interesting materials such as many supramolecular polymers or biopolymers exhibit highly directional interactions. To capture their behavior in colloidal model systems, particles with anisotropic interactions are clearly required. Here we use a colloidal system of nonspherical colloids, where highly directional interactions can be induced via depletion. By biaxially stretching spherical PMMA particles we create oblate spheroidal particles. We induce attractive interactions between these particles by adding a non-adsorbing polymer to the background liquid. The resulting depletion interaction is stronger along the minor axis of the oblate spheroids. We study the phase behavior of these materials as a function of the ellipsoid aspect ratio, the strength of the depletion interactions, and the particle concentration. The resulting morphologies are qualitatively different from those observed with spherical particles. This can be exploited for creating new materials with tailored structures.

  9. Zonal flows in tokamaks with anisotropic pressure

    NASA Astrophysics Data System (ADS)

    Ren, Haijun

    2014-04-01

    Zonal flows (ZFs) in a tokamak plasma with anisotropic pressure are investigated. The dynamics of perpendicular and parallel pressures are determined by the Chew-Goldberger-Low double equations and low-β condition is adopted, where β is the ratio of plasma pressure to the magnetic field pressure. The dispersion relation is analytically derived and illustrates two branches of ZFs. The low frequency zonal flow (LFZF) branch becomes unstable when χ, the ratio of the perpendicular pressure to the parallel one, is greater than a threshold value χc, which is about 3.8. In the stable region, its frequency increases first and then decreases with increasing χ. For χ = 1, the frequency of LFZF agrees well with the experimental observation. For the instability, the growth rate of LFZF increases with χ. The geodesic acoustic mode branch is shown to be always stable with a frequency increasing with χ. The safety factor is shown to diminish the frequencies of both branches or the growth rate of LFZF.

  10. Polarization dynamics in nonlinear anisotropic fibers

    SciTech Connect

    Komarov, Andrey; Komarov, Konstantin; Meshcheriakov, Dmitry; Amrani, Foued; Sanchez, Francois

    2010-07-15

    We give an extensive study of polarization dynamics in anisotropic fibers exhibiting a third-order index nonlinearity. The study is performed in the framework of the Stokes parameters with the help of the Poincare sphere. Stationary states are determined, and their stability is investigated. The number of fixed points and their stability depend on the respective magnitude of the linear and nonlinear birefringence. A conservation relation analogous to the energy conservation in mechanics allows evidencing a close analogy between the movement of the polarization in the Poincare sphere and the motion of a particle in a potential well. Two distinct potentials are found, leading to the existence of two families of solutions, according to the sign of the total energy of the equivalent mechanical system. The mechanical analogy allows us to fully characterize the solutions and also to determine analytically the associated beat lengths. General analytical solutions are given for the two families in terms of Jacobi's functions. The intensity-dependent transmission of a fiber placed between two crossed polarizers is calculated. Optimal conditions for efficient nonlinear switching compatible with mode-locking applications are determined. The general case of a nonlinear fiber ring with an intracavity polarizer placed between two polarization controllers is also considered.

  11. Anisotropic distributions in a multiphase transport model

    NASA Astrophysics Data System (ADS)

    Zhou, You; Xiao, Kai; Feng, Zhao; Liu, Feng; Snellings, Raimond

    2016-03-01

    With a multiphase transport (AMPT) model we investigate the relation between the magnitude, fluctuations, and correlations of the initial state spatial anisotropy ɛn and the final state anisotropic flow coefficients vn in Au+Au collisions at √{s NN}=200 GeV. It is found that the relative eccentricity fluctuations in AMPT account for the observed elliptic flow fluctuations, both are in agreement with the elliptic flow fluctuation measurements from the STAR collaboration. In addition, the studies based on two- and multiparticle correlations and event-by-event distributions of the anisotropies suggest that the elliptic-power function is a promising candidate of the underlying probability density function of the event-by-event distributions of ɛn as well as vn. Furthermore, the correlations between different order symmetry planes and harmonics in the initial coordinate space and final state momentum space are presented. Nonzero values of these correlations have been observed. The comparison between our calculations and data will, in the future, shed new insight into the nature of the fluctuations of the quark-gluon plasma produced in heavy ion collisions.

  12. Anisotropic model-based SAR processing

    NASA Astrophysics Data System (ADS)

    Knight, Chad; Gunther, Jake; Moon, Todd

    2013-05-01

    Synthetic aperture radar (SAR) collections that integrate over a wide range of aspect angles hold the potentional for improved resolution and fosters improved scene interpretability and target detection. However, in practice it is difficult to realize the potential due to the anisotropic scattering of objects in the scene. The radar cross section (RCS) of most objects changes as a function of aspect angle. The isotropic assumption is tacitly made for most common image formation algorithms (IFA). For wide aspect scenarios one way to account for anistropy would be to employ a piecewise linear model. This paper focuses on such a model but it incorporates aspect and spatial magnitude filters in the image formation process. This is advantageous when prior knowledge is available regarding the desired targets' RCS signature spatially and in aspect. The appropriate filters can be incorporated into the image formation processing so that specific targets are emphasized while other targets are suppressed. This is demonstrated on the Air Force Research Laboratory (AFRL) GOTCHA1 data set to demonstrate the utility of the proposed approach.

  13. Biochemical and anisotropical properties of tendons.

    PubMed

    Aparecida de Aro, Andrea; Vidal, Benedicto de Campos; Pimentel, Edson Rosa

    2012-02-01

    Tendons are formed by dense connective tissue composed of an abundant extracellular matrix (ECM) that is constituted mainly of collagen molecules, which are organized into fibrils, fibers, fiber bundles and fascicles helicoidally arranged along the largest axis of the tendon. The biomechanical properties of tendons are directly related to the organization of the collagen molecules that aggregate to become a super-twisted cord. In addition to collagen, the ECM of tendons is composed of non-fibrillar components, such as proteoglycans and non-collagenous glycoproteins. The capacity of tendons to resist mechanical stress is directly related to the structural organization of the ECM. Collagen is a biopolymer and presents optical anisotropies, such as birefringence and linear dichroism, that are important optical properties in the characterization of the supramolecular organization of the fibers. The objective of this study was to present a review of the composition and organization of the ECM of tendons and to highlight the importance of the anisotropic optical properties in the study of alterations in the ECM.

  14. THE ANISOTROPIC TRANSPORT EFFECTS ON DILUTE PLASMAS

    SciTech Connect

    Devlen, Ebru

    2011-04-20

    We examine the linear stability analysis of a hot, dilute, and differentially rotating plasma by considering anisotropic transport effects. In dilute plasmas, the ion Larmor radius is small compared with its collisional mean free path. In this case, the transport of heat and momentum along the magnetic field lines becomes important. This paper presents a novel linear instability that may be more powerful and greater than ideal magnetothermal instability and ideal magnetorotational instability in the dilute astrophysical plasmas. This type of plasma is believed to be found in the intracluster medium (ICM) of galaxy clusters and radiatively ineffective accretion flows around black holes. We derive the dispersion relation of this instability and obtain the instability condition. There is at least one unstable mode that is independent of the temperature gradient direction for a helical magnetic field geometry. This novel instability is driven by the gyroviscosity coupled with differential rotation. Therefore, we call it gyroviscous-modified magnetorotational instability (GvMRI). We examine how the instability depends on signs of the temperature gradient and the gyroviscosity and also on the magnitude of the thermal frequency and on the values of the pitch angle. We provide a detailed physical interpretation of the obtained results. The GvMRI is applicable not only to the accretion flows and ICM but also to the transition region between cool dense gas and the hot low-density plasma in stellar coronae, accretion disks, and the multiphase interstellar medium because it is independent of the temperature gradient direction.

  15. Production and characterization of anisotropic particles from biodegradable materials.

    PubMed

    Romanski, Francis S; Winkler, Jennifer S; Riccobene, Ryan C; Tomassone, M Silvina

    2012-02-28

    In recent years, production and characterization of anisotropic particles has become of interest in a wide range of scientific fields including polymer chemistry, drug delivery, electronics, energy, and nanotechnology. In this work, we demonstrate a novel formulation for production of anisotropic particles via an internal phase separation of biodegradable components. Specifically, binary mixtures of biodegradable polymers poly(lactic-co-glycolic acid), polycaprolactone, and biodegradable lipid Precirol (glyceryl palmitostearate) were dissolved in dichloromethane, emulsified, and prepared into anisotropic particles using a modified solvent evaporation technique. During the slow evaporation process the components self-assembled into anisotropic particles with distinct morphologies. Polymer/polymer formulations resulted in compartmentalized anisotropic heterodimer particles, while polymer/lipid combinations yielded "ice cream cone" shaped particles. It was found that addition of certain active pharmaceuticals resulted in an altered, pox-like segregation at the particle surface of polymer/polymer formulations. The anisotropic nature of the particles was subsequently characterized using optical microscopy, scanning electron microscopy, zeta potential, electrophoresis, and X-ray diffraction. Successful formulations presented here may potentially be employed as multicompartmental drug carriers with staggered drug release rates or alternatively as a colloidal excipient for an arsenal of pharmaceutical applications.

  16. Enhanced Raman Scattering on In-plane Anisotropic Layered Materials

    DOE PAGES

    Liang, Liangbo; Meunier, Vincent; Sumpter, Bobby G.; Ling, Xi; Lin, Jingjing; Zhang, Shuqing; Mao, Nannan; Zhang, Na; Tong, Lianming; Zhang, Jin

    2015-11-19

    Surface-enhanced Raman scattering (SERS) on two-dimensional (2D) layered materials has provided a unique platform to study the chemical mechanism (CM) of the enhancement due to its natural separation from electromagnetic enhancement. The CM stems from the basic charge interactions between the substrate and molecules. Despite the extensive studies of the energy alignment between 2D materials and molecules, an understanding of how the electronic properties of the substrate are explicitly involved in the charge interaction is still unclear. Lately, a new group of 2D layered materials with anisotropic structure, including orthorhombic black phosphorus (BP) and triclinic rhenium disulphide (ReS2), has attractedmore » great interest due to their unique anisotropic electrical and optical properties. Herein, we report a unique anisotropic Raman enhancement on few-layered BP and ReS2 using copper phthalocyanine (CuPc) molecules as a Raman probe, which is absent on isotropic graphene and h-BN. According to detailed Raman tensor analysis and density functional theory calculations, anisotropic charge interactions due to the anisotropic carrier mobilities of the 2D materials are responsible for the angular dependence of the Raman enhancement. Our findings not only provide new insights into the CM process in SERS, but also open up new avenues for the exploration and application of the electronic properties of anisotropic 2D layered materials.« less

  17. Enhanced Raman Scattering on In-plane Anisotropic Layered Materials

    SciTech Connect

    Liang, Liangbo; Meunier, Vincent; Sumpter, Bobby G.; Ling, Xi; Lin, Jingjing; Zhang, Shuqing; Mao, Nannan; Zhang, Na; Tong, Lianming; Zhang, Jin

    2015-11-19

    Surface-enhanced Raman scattering (SERS) on two-dimensional (2D) layered materials has provided a unique platform to study the chemical mechanism (CM) of the enhancement due to its natural separation from electromagnetic enhancement. The CM stems from the basic charge interactions between the substrate and molecules. Despite the extensive studies of the energy alignment between 2D materials and molecules, an understanding of how the electronic properties of the substrate are explicitly involved in the charge interaction is still unclear. Lately, a new group of 2D layered materials with anisotropic structure, including orthorhombic black phosphorus (BP) and triclinic rhenium disulphide (ReS2), has attracted great interest due to their unique anisotropic electrical and optical properties. Herein, we report a unique anisotropic Raman enhancement on few-layered BP and ReS2 using copper phthalocyanine (CuPc) molecules as a Raman probe, which is absent on isotropic graphene and h-BN. According to detailed Raman tensor analysis and density functional theory calculations, anisotropic charge interactions due to the anisotropic carrier mobilities of the 2D materials are responsible for the angular dependence of the Raman enhancement. Our findings not only provide new insights into the CM process in SERS, but also open up new avenues for the exploration and application of the electronic properties of anisotropic 2D layered materials.

  18. a New Approach to Bulk Wave Propagation in Anisotropic Media.

    NASA Astrophysics Data System (ADS)

    Tverdokhlebov, Andrey

    A new approach to a theoretical description of ultrasonic bulk wave propagation through anisotropic media is developed from the retarded potential representation which was obtained for the Green's function of the elastic wave equation in anisotropic media. The general formulation of the problem and the method of solution are presented. On the basis of the theoretical development, a quantitative model was obtained that yields and properly describes all major features of the phenomena of an anisotropic filter influence. A comparison with other contemporary methods and models for the quantitative evaluation of the bulk wave propagation in anisotropic media is outlined and briefly discussed. The experimental proof of principle was established by ultrasonic measurements performed on centrifugally cast stainless steel (CCSS) and unidirectional graphite fiber -epoxy composite specimens. The experimental technique used a skip-distance arrangement of the identical quasi -point probes serving as a sender and a receiver. Consistent experimental results were attained allowing us to consider the suggested experimental arrangements as a basis for the future development of NDE technique for anisotropic material characterization. Three different types of pilot computer software were developed from this generalized retarded potential model. The results of the simulation runs turn out to be self- and mutually consistent and supported by experiments. The phenomena, such as beam skewing, beam splitting, beam focusing, unsymmetrical beams and other anisotropic effects, some of which have been already known from earlier experimental observations, emerge as computational results of the software developed from the model.

  19. Process of preparing tritiated porous silicon

    DOEpatents

    Tam, S.W.

    1997-02-18

    A process of preparing tritiated porous silicon is described in which porous silicon is equilibrated with a gaseous vapor containing HT/T{sub 2} gas in a diluent for a time sufficient for tritium in the gas phase to replace hydrogen present in the pore surfaces of the porous silicon. 1 fig.

  20. Process of preparing tritiated porous silicon

    DOEpatents

    Tam, Shiu-Wing

    1997-01-01

    A process of preparing tritiated porous silicon in which porous silicon is equilibrated with a gaseous vapor containing HT/T.sub.2 gas in a diluent for a time sufficient for tritium in the gas phase to replace hydrogen present in the pore surfaces of the porous silicon.

  1. Anisotropic steady-flow hydrodynamic parameters of microporous media applied to pulse tube and Stirling cryocooler regenerators

    NASA Astrophysics Data System (ADS)

    Clearman, W. M.; Cha, J. S.; Ghiaasiaan, S. M.; Kirkconnell, C. S.

    2008-03-01

    The hydrodynamic parameters associated with steady longitudinal and lateral (radial) flow of helium in several widely-used pulse tube and Stirling cryocooler regenerator fillers were measured and correlated in this investigation. Pressure drops in test sections packed with regenerator fillers were experimentally measured. Computational fluid dynamics (CFD) models of the regenerator test sections and their vicinities were developed and simulations were performed in which the regenerator test sections were modeled as porous media. By iterative repetition of the simulations, the longitudinal and radial permeability and Forchheimer inertial coefficients were determined such that they would lead to agreement between experimental measurements and the simulations. The regenerator fillers included 325 and 400 mesh stainless steel screens, stainless steel metal foam, sintered 400 mesh stainless steel screens, and a stack of micromachined perforated plates. The hydrodynamic response of the regenerator fillers were also correlated as friction factors. The results confirm that the aforementioned regenerator fillers are anisotropic.

  2. Plane wave propagation in a rotating anisotropic medium with voids under the action of a uniform magnetic field

    NASA Astrophysics Data System (ADS)

    Maity, Narottam; Barik, S. P.; Chaudhuri, P. K.

    2016-09-01

    In this paper, plane wave propagation in a rotating anisotropic material of general nature under the action of a magnetic field of constant magnitude has been investigated. The material is supposed to be porous in nature and contains voids. Following the concept of [Cowin S. C. and Nunziato, J. W. [1983] “Linear elastic materials with voids,” J. Elasticity 13, 125-147.] the governing equations of motion have been written in tensor notation taking account of rotation, magnetic field effect and presence of voids in the medium and the possibility of plane wave propagation has been examined. A number of particular cases have been derived from our general results to match with previously obtained results in this area. Effects of various parameters on the velocity of wave propagation have been presented graphically.

  3. Modified anisotropic turbulence refractive-index fluctuations spectral model and its application in moderate-to-strong anisotropic turbulence.

    PubMed

    Cui, Linyan; Xue, Bindang; Zhou, Fugen

    2016-04-01

    In this study, the modified anisotropic turbulence refractive-index fluctuations spectral model is derived based on the extended Rytov approximation theory for the theoretical investigations of optical plane and spherical waves propagating through moderate-to-strong anisotropic non-Kolmogorov turbulence. The anisotropic factor which parameterizes the asymmetry of turbulence cells or eddies in the horizontal and vertical directions is introduced. The general spectral power law in the range of 3-4 is also considered compared with the conventional classic value of 11/3 for Kolmogorov turbulence. Based on the modified anisotropic turbulence refractive-index fluctuations spectrum, the analytic expressions of the irradiance scintillation index are also derived for optical plane and spherical waves propagating through moderate-to-strong anisotropic non-Kolmogorov turbulence. They are applicable in a wide range of turbulence strengths and can reduce correctly to the previously published results in the special cases of weak anisotropic turbulence and moderate-to-strong isotropic turbulence. Calculations are performed to analyze the derived models.

  4. Fabrication of porous electrospun nanofibres

    NASA Astrophysics Data System (ADS)

    Zhang, Y. Z.; Feng, Y.; Huang, Z.-M.; Ramakrishna, S.; Lim, C. T.

    2006-02-01

    Immiscible biopolymers of gelatin (Gt) and polycaprolactone (PCL) were first electrospun into a biomimicking composite fibre of Gt/PCL. Based on a phase separation study of the electrospun fibres, a leaching method was employed to generate 3D porous nanofibres by selectively removing the water soluble component of gelatin in a 37 °C aqueous solution of phosphate buffered saline. It was found that leaching treatment gave rise to a unique nanotopography containing grooves, ridges and elliptical pores on the surface as well as inside of the resultant individual nanofibres. Brunauer-Emmett-Teller (BET) area measurement indicated that the formed 3D porous fibres also brought in a pronounced increase of the surface area of fibres. The BET surface area of the porous fibres was observed to be about 2.4 times that of the precursor fibres, up to 15.84 m2 g-1 at its relatively large size of 800 nm diameter. The 3D porous fibres herein prepared could have considerable value for uses in developing highly integrated cell-scaffold tissue complexes and other industrial applications.

  5. Neural Tissue as Porous Media

    SciTech Connect

    Basser, Peter J.

    2008-12-05

    The fields of MR in Porous Media and Neuroradiology have largely developed separately during the past two decades with little appreciation of the problems, challenges and methodologies of the other. However, this trend is clearly changing and possibilities for significant cross-fertilization and synergies are now being realized.

  6. Whey drying on porous carriers

    SciTech Connect

    Mitura, E.; Kaminski, W.

    1996-05-01

    Whey is treated very often as a waste which pollutes the natural environment. Whey which is a valuable source of protein, lacrose, vitamins and mineral salts should be utilized completely. The present paper is a proposal of whey drying on porous carriers. It is proved experimentally that the proposed drying method guarantees good product quality.

  7. Metal recovery from porous materials

    DOEpatents

    Sturcken, E.F.

    1991-01-01

    The present invention relates to recovery of metals. More specifically, the present invention relates to the recovery of plutonium and other metals from porous materials using microwaves. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  8. Hydrostatic testing of porous assemblies

    NASA Technical Reports Server (NTRS)

    Bigelow, W. L.

    1968-01-01

    Pores of the material were plugged with dust particles suspended in water. The plugging material used was a standard test dust prepared as a slurry in distilled water. This technique provides a permanent high-integrity seal for porous material without affecting its physical properties, yet permitting pressure testing to verify structural adequacy.

  9. Wave Propagation in Fractured Anisotropic Media

    NASA Astrophysics Data System (ADS)

    Shao, S.; Pyrak-Nolte, L. J.

    2012-12-01

    Discontinuities such as fractures, joints and faults occur in the Earth's crusts in a variety of rock types. While much theoretical, experimental and computational research have examined seismic wave propagation in fractured isotropic rock, few experimental studies have investigated seismic wave propagation in fractured anisotropic media. The co-existence of fractures and layers can complicate the interpretation of seismic properties because of the discrete guided modes that propagate along or are confined by the fractures. In this study, we use seismic arrays and acoustic wavefront imaging techniques to examine the competing sources of seismic anisotropy from fractures and from layers. Samples with textural anisotropy (100 mm x 100 mm x 100 mm) were fabricated from garolite, an epoxy - cloth laminate, with layer thickness 0f ~ 0.5 mm. Two sets of fractured samples were fabricated: (1) two single fractured samples with one fracture either parallel or (and) perpendicular to layers, and (2) four multi-fractured samples with 5 parallel fractures oriented either parallel, 30 degrees, 60 degrees or perpendicular to the layers. An intact sample containing no fractures was used as a standard orthorhombic medium for reference. Seismic arrays were used on the first set of samples to measure bulk waves and fracture interface waves as a function of stress. The seismic array contained two compressional and five shear-wave source-receiver pairs with a central frequency of 1 MHz. Shear wave transducers were polarized both perpendicular and parallel to the layering as well as to the fracture. Measurements were made for a range of stresses (0.4 - 4MPa). From these measurements it was observed that a fractured layered medium appears more isotropic or anisotropic than the orthorhombic background, depending on the orientation of the fracture relative to layers. The matrix anisotropy was recovered by increasing the normal stress on a fracture (i.e., by closing the fracture). For the

  10. Porous medium convection at large Rayleigh number: Studies of coherent structure, transport, and reduced dynamics

    NASA Astrophysics Data System (ADS)

    Wen, Baole

    Buoyancy-driven convection in fluid-saturated porous media is a key environmental and technological process, with applications ranging from carbon dioxide storage in terrestrial aquifers to the design of compact heat exchangers. Porous medium convection is also a paradigm for forced-dissipative infinite-dimensional dynamical systems, exhibiting spatiotemporally chaotic dynamics if not "true" turbulence. The objective of this dissertation research is to quantitatively characterize the dynamics and heat transport in two-dimensional horizontal and inclined porous medium convection between isothermal plane parallel boundaries at asymptotically large values of the Rayleigh number Ra by investigating the emergent, quasi-coherent flow. This investigation employs a complement of direct numerical simulations (DNS), secondary stability and dynamical systems theory, and variational analysis. The DNS confirm the remarkable tendency for the interior flow to self-organize into closely-spaced columnar plumes at sufficiently large Ra (up to Ra ≃ 105), with more complex spatiotemporal features being confined to boundary layers near the heated and cooled walls. The relatively simple form of the interior flow motivates investigation of unstable steady and time-periodic convective states at large Ra as a function of the domain aspect ratio L. To gain insight into the development of spatiotemporally chaotic convection, the (secondary) stability of these fully nonlinear states to small-amplitude disturbances is investigated using a spatial Floquet analysis. The results indicate that there exist two distinct modes of instability at large Ra: a bulk instability mode and a wall instability mode. The former usually is excited by long-wavelength disturbances and is generally much weaker than the latter. DNS, strategically initialized to investigate the fully nonlinear evolution of the most dangerous secondary instability modes, suggest that the (long time) mean inter-plume spacing in

  11. Collisionless magnetic reconnection under anisotropic MHD approximation

    NASA Astrophysics Data System (ADS)

    Hirabayashi, Kota; Hoshino, Masahiro

    We study the formation of slow-mode shocks in collisionless magnetic reconnection by using one- and two-dimensional collisionless magneto-hydro-dynamic (MHD) simulations based on the double adiabatic approximation, which is an important step to bridge the gap between the Petschek-type MHD reconnection model accompanied by a pair of slow shocks and the observational evidence of the rare occasion of in-situ slow shock observation. According to our results, a pair of slow shocks does form in the reconnection layer. The resultant shock waves, however, are quite weak compared with those in an isotropic MHD from the point of view of the plasma compression and the amount of the magnetic energy released across the shock. Once the slow shock forms, the downstream plasma are heated in highly anisotropic manner and a firehose-sense (P_{||}>P_{⊥}) pressure anisotropy arises. The maximum anisotropy is limited by the marginal firehose criterion, 1-(P_{||}-P_{⊥})/B(2) =0. In spite of the weakness of the shocks, the resultant reconnection rate is kept at the same level compared with that in the corresponding ordinary MHD simulations. It is also revealed that the sequential order of propagation of the slow shock and the rotational discontinuity, which appears when the guide field component exists, changes depending on the magnitude of the guide field. Especially, when no guide field exists, the rotational discontinuity degenerates with the contact discontinuity remaining at the position of the initial current sheet, while with the slow shock in the isotropic MHD. Our result implies that the slow shock does not necessarily play an important role in the energy conversion in the reconnection system and is consistent with the satellite observation in the Earth's magnetosphere.

  12. MOSSFRAC: An anisotropic 3D fracture model

    SciTech Connect

    Moss, W C; Levatin, J L

    2006-08-14

    Despite the intense effort for nearly half a century to construct detailed numerical models of plastic flow and plastic damage accumulation, models for describing fracture, an equally important damage mechanism still cannot describe basic fracture phenomena. Typical fracture models set the stress tensor to zero for tensile fracture and set the deviatoric stress tensor to zero for compressive fracture. One consequence is that the simple case of the tensile fracture of a cylinder under combined compressive radial and tensile axial loads is not modeled correctly. The experimental result is a cylinder that can support compressive radial loads, but no axial load, whereas, the typical numerical result is a cylinder with all stresses equal to zero. This incorrect modeling of fracture locally also has a global effect, because material that is fracturing produces stress release waves, which propagate from the fracture and influence the surrounding material. Consequently, it would be useful to have a model that can describe the stress relief and the resulting anisotropy due to fracture. MOSSFRAC is a material model that simulates three-dimensional tensile and shear fracture in initially isotropic elastic-plastic materials, although its framework is also amenable to initially anisotropic materials. It differs from other models by accounting for the effects of cracks on the constitutive response of the material, so that the previously described experiment, as well as complicated fracture scenarios are simulated more accurately. The model is implemented currently in the LLNL hydrocodes DYNA3D, PARADYN, and ALE3D. The purpose of this technical note is to present a complete qualitative description of the model and quantitative descriptions of salient features.

  13. Porous silicon carbide (SIC) semiconductor device

    NASA Technical Reports Server (NTRS)

    Shor, Joseph S. (Inventor); Kurtz, Anthony D. (Inventor)

    1996-01-01

    Porous silicon carbide is fabricated according to techniques which result in a significant portion of nanocrystallites within the material in a sub 10 nanometer regime. There is described techniques for passivating porous silicon carbide which result in the fabrication of optoelectronic devices which exhibit brighter blue luminescence and exhibit improved qualities. Based on certain of the techniques described porous silicon carbide is used as a sacrificial layer for the patterning of silicon carbide. Porous silicon carbide is then removed from the bulk substrate by oxidation and other methods. The techniques described employ a two-step process which is used to pattern bulk silicon carbide where selected areas of the wafer are then made porous and then the porous layer is subsequently removed. The process to form porous silicon carbide exhibits dopant selectivity and a two-step etching procedure is implemented for silicon carbide multilayers.

  14. The Interaction of Sound and Shock Waves with Flexible Porous Materials

    NASA Astrophysics Data System (ADS)

    Abbott, James Fuller

    Several topics are studied which illustrate the role of flexibility in determining the acoustical properties of flexible porous materials. A power balance relation is obtained for the flexible porous material which explicitly identifies two loss mechanisms for sound absorption: the losses due to the irreversible deformation of the structure, and those attributed to the viscous drag between the fluid and the structure. The finite flexible porous layer backed by a rigid wall is then considered. Irreversible deformation of the structure is shown to be the dominant loss mechanism for closed layers. Three departures from the basic model-- a porous layer with anisotropic flow resistance and structure factor, periodic structures consisting of porous layers separated by air gaps, and the porous medium in bulk with mean fluid flow--are considered. The reflection of shock waves is also studied, and a quasi-linear theory is developed which reproduces the principal features of experimental results obtained previously by Ingard. The theory assumes that the propagating pulses in the air and structure are linear and the gross, zeroth order motion of the porous layer is modeled by including its energy and momentum in the conservation equations; these equations compare the system just before and just after the reflection of the incident shock from the front surface of the layer. The substantial motion of the layer and its dragging against a constraining boundary (in this case the walls of the shock tube) are found to introduce a dependence of the front reflection coefficient and maximal layer deformation on the peak pressure of the incident shock. Lastly, we address the question of measurement of the complex compressibility K, a key parameter used to describe the dynamics of a given flexible porous material. The standard long-wavelength assumption used to determine K from experimental measurements of the frequency dependent velocity transfer function across a sample is shown to

  15. An anisotropically and heterogeneously aligned patterned electrospun scaffold with tailored mechanical property and improved bioactivity for vascular tissue engineering.

    PubMed

    Xu, He; Li, Haiyan; Ke, Qinfei; Chang, Jiang

    2015-04-29

    The development of vascular scaffolds with controlled mechanical properties and stimulatory effects on biological activities of endothelial cells still remains a significant challenge to vascular tissue engineering. In this work, we reported an innovative approach to prepare a new type of vascular scaffolds with anisotropically and heterogeneously aligned patterns using electrospinning technique with unique wire spring templates, and further investigated the structural effects of the patterned electrospun scaffolds on mechanical properties and angiogenic differentiation of human umbilical vein endothelial cells (HUVECs). Results showed that anisotropically aligned patterned nanofibrous structure was obtained by depositing nanofibers on template in a structurally different manner, one part of nanofibers densely deposited on the embossments of wire spring and formed cylindrical-like structures in the transverse direction, while others loosely suspended and aligned along the longitudinal direction, forming a three-dimensional porous microstructure. We further found that such structures could efficiently control the mechanical properties of electrospun vascular scaffolds in both longitudinal and transverse directions by altering the interval distances between the embossments of patterned scaffolds. When HUVECs were cultured on scaffolds with different microstructures, the patterned scaffolds distinctively promoted adhesion of HUVECs at early stage and proliferation during the culture period. Most importantly, cells experienced a large shape change associated with cell cytoskeleton and nuclei remodeling, leading to a stimulatory effect on angiogenesis differentiation of HUVECs by the patterned microstructures of electrospun scaffolds, and the scaffolds with larger distances of intervals showed a higher stimulatory effect. These results suggest that electrospun scaffolds with the anisotropically and heterogeneously aligned patterns, which could efficiently control the

  16. Effects of Petrophysical Anisotropy on Fault Stability in Porous Sandstones

    NASA Astrophysics Data System (ADS)

    Farrell, N. J.; Healy, D.

    2012-12-01

    To examine the relationship of porosity and permeability to fluid flow and understand fault mechanical behaviour in the subsurface, petrophysical and geometrical analyses have been conducted on samples collected from a surface fault zone outcrop. Based on quantitative field, laboratory and digital image data we can begin to understand and predict the behaviour of fluids during and after faulting and infer the impact of petrophysical patterns on rock mechanics. Previous research has shown that changes in pore pressure, associated with fluid flow, can induce changes in the stresses acting on the rock (Teufel et al., 1991). In addition to this, theoretical work suggests that depending on the orientation of anisotropic pore long axes with respect to the principal stresses, anisotropy of porosity may either increase or decrease the stability of the faulted rock (Chen & Nur, 1992; Healy, 2009). Porous sandstones sampled around a normal fault zone show anisotropy of petrophysical properties in three orientations; (x; perpendicular to the fault plane, y; down dip to the fault and z; parallel to the fault plane) with respect to the fault plane (independent of sedimentary fabric permeability) related to microfracture type and distribution and variations in pore geometry. Permeability data collected using a Jones permeameter from over seventy oriented core plugs show overall preferential fluid flow (Kmax) down dip to the fault plane while porosity values measured using a Helium porosimeter are comparatively isotropic. Image analysis from forty corresponding thin sections shows variable porosities between orthogonally oriented sections with samples close to the fault slip surface showing higher porosity in an equivalent orientation to Kmax. Interestingly with distance away from the fault slip surface, image analysis porosities are higher perpendicular to the fault plane compared to down fault dip, in contrast to Kmax orientation. Further investigations using

  17. Neovascularization within porous PEG hydrogels

    NASA Astrophysics Data System (ADS)

    Chiu, Yu-Chieh

    The goal of this work described was to develop techniques that can be used to enhance vascularized tissue formation in PEG-based hydrogels. In the first part of the study a technique was developed to generate porous PEG hydrogels using a salt leaching technique. This technique was then used to examine the role of pore size on vascularization and tissue remodeling in porous PEG hydrogel in vitro and in vitro. Both in vitro and in vivo studies showed that vessel invasion was pore size dependent. In addition, a thin layer of inflammatory tissue was observed between PEG hydrogel and blood vessels that formed within the gels. The porous PEG hydrogels were very stable in vitro and in vivo and did not exhibit any signs of degradation. Hydrogels used in tissue engineering need to exhibit controlled degradation. In order to address the stability of PEG hydrogels, porous hydrogels were rendered using degradable PEG-co-(L-Lactic acid) diacrylate PEG-PLLA-DA. This polymer is degraded via hydrolysis of the PLLA chains. The hydrogels were found to exhibit autofluorescence that allowed for the unique ability to nondestructively image hydrogel structure under fully swelled conditions using confocal microscopy. Interestingly, pore size remained stable though out the study, and was not a function of degradation. In addition, degradation time of porous PEG-LLA-DA hydrogels was influenced by polymer concentration. Compressive modulus was a function of polymer concentration and pore size and decreased during hydrogel degradation. The incorporation of cell adhesion sequences into the hydrogel showed that they can support cell adhesion with morphology varying with pore size. This technique could be used to tailor porous biodegradable scaffolds for tissue engineering applications. In the final portion of this thesis a poly-lysine (PLL) molecule was synthesized in order to allow clustering of adhesion sequences in PEG hydrogels. Clusters of peptide sequences have been shown to enhance cell

  18. 2D seismic reflection tomography in strongly anisotropic media

    NASA Astrophysics Data System (ADS)

    Huang, Guangnan; Zhou, Bing; Li, Hongxi; Zhang, Hua; Li, Zelin

    2014-12-01

    Seismic traveltime tomography is an effective method to reconstruct underground anisotropic parameters. Currently, most anisotropic tomographic methods were developed under the assumption of weak anisotropy. The tomographic method proposed here can be implemented for imaging subsurface targets in strongly anisotropic media with a known tilted symmetry axis, since the adopted ray tracing method is suitable for anisotropic media with arbitrary degree. There are three kinds of reflection waves (qP, qSV and qSH waves) that were separately used to invert the blocky abnormal body model. The reflection traveltime tomographiy is developed here because a surface observation system is the most economical and practical way compared with crosswell and VSP. The numerical examples show that the traveltimes of qP reflection wave have inverted parameters {{c}11},{{c}13},{{c}33} \\text{and} {{c}44} successfully. Traveltimes of qSV reflection wave have inverted parameters {{c}11},{{c}33} \\text{and} {{c}44} successfully, with the exception of the {{c}13}, since it is less sensitive than other parameters. Traveltimes of qSH reflection wave also have inverted parameters {{c}44} \\text{and} {{c}66} successfully. In addition, we find that the velocity sensitivity functions (derivatives of phase velocity with respect to elastic moduli parameters) and raypath illuminating angles have a great influence on the qualities of tomograms according to the inversion of theoretical models. Finally, the numerical examples confirm that the reflection traveltime tomography can be applied to invert strongly anisotropic models.

  19. Anisotropic Solution Adaptive Unstructured Grid Generation Using AFLR

    NASA Technical Reports Server (NTRS)

    Marcum, David L.

    2007-01-01

    An existing volume grid generation procedure, AFLR3, was successfully modified to generate anisotropic tetrahedral elements using a directional metric transformation defined at source nodes. The procedure can be coupled with a solver and an error estimator as part of an overall anisotropic solution adaptation methodology. It is suitable for use with an error estimator based on an adjoint, optimization, sensitivity derivative, or related approach. This offers many advantages, including more efficient point placement along with robust and efficient error estimation. It also serves as a framework for true grid optimization wherein error estimation and computational resources can be used as cost functions to determine the optimal point distribution. Within AFLR3 the metric transformation is implemented using a set of transformation vectors and associated aspect ratios. The modified overall procedure is presented along with details of the anisotropic transformation implementation. Multiple two-and three-dimensional examples are also presented that demonstrate the capability of the modified AFLR procedure to generate anisotropic elements using a set of source nodes with anisotropic transformation metrics. The example cases presented use moderate levels of anisotropy and result in usable element quality. Future testing with various flow solvers and methods for obtaining transformation metric information is needed to determine practical limits and evaluate the efficacy of the overall approach.

  20. Enhanced Raman Scattering on In-Plane Anisotropic Layered Materials.

    PubMed

    Lin, Jingjing; Liang, Liangbo; Ling, Xi; Zhang, Shuqing; Mao, Nannan; Zhang, Na; Sumpter, Bobby G; Meunier, Vincent; Tong, Lianming; Zhang, Jin

    2015-12-16

    Surface-enhanced Raman scattering (SERS) on two-dimensional (2D) layered materials has provided a unique platform to study the chemical mechanism (CM) of the enhancement due to its natural separation from electromagnetic enhancement. The CM stems from the charge interactions between the substrate and molecules. Despite the extensive studies of the energy alignment between 2D materials and molecules, an understanding of how the electronic properties of the substrate are explicitly involved in the charge interaction is still unclear. Lately, a new group of 2D layered materials with anisotropic structures, including orthorhombic black phosphorus (BP) and triclinic rhenium disulfide (ReS2), has attracted great interest due to their unique anisotropic electrical and optical properties. Herein, we report a unique anisotropic Raman enhancement on few-layered BP and ReS2 using copper phthalocyanine (CuPc) molecules as a Raman probe, which is absent on isotropic graphene and h-BN. According to detailed Raman tensor analysis and density functional theory calculations, anisotropic charge interactions between the 2D materials and molecules are responsible for the angular dependence of the Raman enhancement. Our findings not only provide new insights into the CM process in SERS, but also open up new avenues for the exploration and application of the electronic properties of anisotropic 2D layered materials. PMID:26583533

  1. Enhanced Raman Scattering on In-Plane Anisotropic Layered Materials.

    PubMed

    Lin, Jingjing; Liang, Liangbo; Ling, Xi; Zhang, Shuqing; Mao, Nannan; Zhang, Na; Sumpter, Bobby G; Meunier, Vincent; Tong, Lianming; Zhang, Jin

    2015-12-16

    Surface-enhanced Raman scattering (SERS) on two-dimensional (2D) layered materials has provided a unique platform to study the chemical mechanism (CM) of the enhancement due to its natural separation from electromagnetic enhancement. The CM stems from the charge interactions between the substrate and molecules. Despite the extensive studies of the energy alignment between 2D materials and molecules, an understanding of how the electronic properties of the substrate are explicitly involved in the charge interaction is still unclear. Lately, a new group of 2D layered materials with anisotropic structures, including orthorhombic black phosphorus (BP) and triclinic rhenium disulfide (ReS2), has attracted great interest due to their unique anisotropic electrical and optical properties. Herein, we report a unique anisotropic Raman enhancement on few-layered BP and ReS2 using copper phthalocyanine (CuPc) molecules as a Raman probe, which is absent on isotropic graphene and h-BN. According to detailed Raman tensor analysis and density functional theory calculations, anisotropic charge interactions between the 2D materials and molecules are responsible for the angular dependence of the Raman enhancement. Our findings not only provide new insights into the CM process in SERS, but also open up new avenues for the exploration and application of the electronic properties of anisotropic 2D layered materials.

  2. Weibel Instability Driven by Spatially Anisotropic Density Structures

    NASA Astrophysics Data System (ADS)

    Tomita, Sara; Ohira, Yutaka

    2016-07-01

    Observations of afterglows of gamma-ray bursts (GRBs) suggest that post-shock magnetic fields are strongly amplified to about 100 times the shock-compressed value. The Weibel instability appears to play an important role in generating the magnetic field. However, recent simulations of collisionless shocks in homogeneous plasmas show that the magnetic field generated by the Weibel instability rapidly decays. There must be some density fluctuations in interstellar and circumstellar media. The density fluctuations are anisotropically compressed in the downstream region of relativistic shocks. In this paper, we study the Weibel instability in electron-positron plasmas with spatially anisotropic density distributions by means of two-dimensional particle-in-cell simulations. We find that large magnetic fields are maintained for a longer time by the Weibel instability driven by spatially anisotropic density structure. Particles anisotropically escape from the high density region, so that a temperature anisotropy is generated and the Weibel instability becomes unstable. Our simulation results suggest that the Weibel instability driven by an anisotropic density structure can generate sufficiently large magnetic fields and they can cover sufficiently large regions to explain the afterglow emission of GRBs.

  3. Fingering instability and mixing of a blob in porous media

    NASA Astrophysics Data System (ADS)

    Pramanik, Satyajit; Mishra, Manoranjan

    2016-10-01

    The curvature of the unstable part of the miscible interface between a circular blob and the ambient fluid in two-dimensional homogeneous porous media depends on the viscosity of the fluids. The influence of the interface curvature on the fingering instability and mixing of a miscible blob within a rectilinear displacement is investigated numerically. The fluid velocity in porous media is governed by Darcy's law, coupled with a convection-diffusion equation that determines the evolution of the solute concentration controlling the viscosity of the fluids. Numerical simulations are performed using a Fourier pseudospectral method to determine the dynamics of a miscible blob (circular or square). It is shown that for a less viscous circular blob, there exist three different instability regions without any finite R -window for viscous fingering, unlike the case of a more viscous circular blob. Critical blob radius for the onset of instability is smaller for a less viscous blob as compared to its more viscous counterpart. Fingering enhances spreading and mixing of miscible fluids. Hence a less viscous blob mixes with the ambient fluid quicker than the more viscous one. Furthermore, we show that mixing increases with the viscosity contrast for a less viscous blob, while for a more viscous one mixing depends nonmonotonically on the viscosity contrast. For a more viscous blob mixing depends nonmonotonically on the dispersion anisotropy, while it decreases monotonically with the anisotropic dispersion coefficient for a less viscous blob. We also show that the dynamics of a more viscous square blob is qualitatively similar to that of a circular one, except the existence of the lump-shaped instability region in the R -Pe plane. We have shown that the Rayleigh-Taylor instability in a circular blob (heavier or lighter than the ambient fluid) is independent of the interface curvature.

  4. Advances in design and modeling of porous materials

    NASA Astrophysics Data System (ADS)

    Ayral, André; Calas-Etienne, Sylvie; Coasne, Benoit; Deratani, André; Evstratov, Alexis; Galarneau, Anne; Grande, Daniel; Hureau, Matthieu; Jobic, Hervé; Morlay, Catherine; Parmentier, Julien; Prelot, Bénédicte; Rossignol, Sylvie; Simon-Masseron, Angélique; Thibault-Starzyk, Frédéric

    2015-07-01

    This special issue of the European Physical Journal Special Topics is dedicated to selected papers from the symposium "High surface area porous and granular materials" organized in the frame of the conference "Matériaux 2014", held on November 24-28, 2014 in Montpellier, France. Porous materials and granular materials gather a wide variety of heterogeneous, isotropic or anisotropic media made of inorganic, organic or hybrid solid skeletons, with open or closed porosity, and pore sizes ranging from the centimeter scale to the sub-nanometer scale. Their technological and industrial applications cover numerous areas from building and civil engineering to microelectronics, including also metallurgy, chemistry, health, waste water and gas effluent treatment. Many emerging processes related to environmental protection and sustainable development also rely on this class of materials. Their functional properties are related to specific transfer mechanisms (matter, heat, radiation, electrical charge), to pore surface chemistry (exchange, adsorption, heterogeneous catalysis) and to retention inside confined volumes (storage, separation, exchange, controlled release). The development of innovative synthesis, shaping, characterization and modeling approaches enables the design of advanced materials with enhanced functional performance. The papers collected in this special issue offer a good overview of the state-of-the-art and science of these complex media. We would like to thank all the speakers and participants for their contribution to the success of the symposium. We also express our gratitude to the organization committee of "Matériaux 2014". We finally thank the reviewers and the staff of the European Physical Journal Special Topics who made the publication of this special issue possible.

  5. Anisotropic shrinkage characteristics of tape cast alumina

    NASA Astrophysics Data System (ADS)

    Patwardhan, Jaideep Suresh

    Dimensional control during sintering is a major issue in ceramics processing to avoid high post-sintering costs associated with machining of the fired ceramic part to desired tolerances and dimensions. Ceramic forming processes such as tape casting, injection molding, and extrusion involve shear of anisotropic particles resulting in preferential alignment of the particles in the green body. This preferential alignment causes directionality in mechanical, electrical, optical, and magnetic properties and most importantly warpage or distortion during sintering. A large effort has been devoted to synthesizing ceramic green bodies with minimal density gradients and uniform packing and modeling the sintering behavior evolution but little effort has been devoted to characterizing orientation of particles and the effect of preferential alignment on sintering shrinkage anisotropy. A systematic study was initiated to study the effect of processing variables such as shear rate, solids loading, temperature, and binder content on aqueous tape cast alumina. Three different alumina systems: A16-SG, Baikowski RC-UFX DBM and RC-LS DBM were investigated. Aqueous tapes of high solids loading alumina (56 vol. %) were tape cast at various speeds and thicknesses and assuming plane Couette flow a shear rate regime of 21--270 s-1 was investigated. Higher shear rates and high solids loading resulted in higher in-plane anisotropy whereas the anisotropy in the thickness direction was higher for low solids loading systems. The anisotropy was found to be fairly constant above a certain critical shear rate (˜100 s-1) irrespective of the temperature and the solids loading and this correlated with the viscosity-shear rate relationship of the cast slips. The higher shrinkage anisotropy in the thickness direction for the low solids loading systems (35 and 45 vol. %) was attributed to the higher amount of organics in the slip required to sustain the suitable viscosity for tape casting and

  6. Anisotropic viscoelastic-viscoplastic continuum model for high-density cellulose-based materials

    NASA Astrophysics Data System (ADS)

    Tjahjanto, D. D.; Girlanda, O.; Östlund, S.

    2015-11-01

    A continuum material model is developed for simulating the mechanical response of high-density cellulose-based materials subjected to stationary and transient loading. The model is formulated in an infinitesimal strain framework, where the total strain is decomposed into elastic and plastic parts. The model adopts a standard linear viscoelastic solid model expressed in terms of Boltzmann hereditary integral form, which is coupled to a rate-dependent viscoplastic formulation to describe the irreversible plastic part of the overall strain. An anisotropic hardening law with a kinematic effect is particularly adopted in order to capture the complex stress-strain hysteresis typically observed in polymeric materials. In addition, the present model accounts for the effects of material densification associated with through-thickness compression, which are captured using an exponential law typically applied in the continuum description of elasticity in porous media. Material parameters used in the present model are calibrated to the experimental data for high-density (press)boards. The experimental characterization procedures as well as the calibration of the parameters are highlighted. The results of the model simulations are systematically analyzed and validated against the corresponding experimental data. The comparisons show that the predictions of the present model are in very good agreement with the experimental observations for both stationary and transient load cases.

  7. Hydrothermal circulation in an anisotropic sedimentary basin: Application to the Okinawa back arc basin

    SciTech Connect

    Genthon, P.; Rabinowicz, M. ); Foucher, J.P.; Sibuet, J.C. )

    1990-11-10

    The authors explore the pattern of two-dimensional convection in an highly anisotropical porous medium. This physical situation is relevant to passive margin sedimentary basins consisting of interbedded coarse-grained pervious and shale matrix. They show that permeability anisotropies of the order of 10{sup 2}-10{sup 4} allow for long convective cells, of aspect ratio greater than 10, but that a combination of this parameter with a slight slope of the order of a few percent of the sedimentary layers is required to stabilize these long cells. As an example, they present the Okinawa basin, an active submarine back arc basin, with a sedimentary thickness of about 2 km and a heat flow profile across this basin, varying from 32 to 232 mWm{sup {minus}2} over a distance of 30 km. It is shown that this heat flow variation is difficult to explain with conductive mechanisms only but is well reproduced by different convective models relying on permeability anisotropy plus slope. Although the insufficient thermal and structural constraints did not allow them to build a unique model, the whole set of possible fits to the heat flow data may restrict the mean hydraulic parameters of the basin. A vertical permeability of a few tens of milidarcy and an anisotropy greater than 100 are required to produce the expected stable and active large-scale circulation. It is suggested in conclusion that this type of circulation might be active in oil- or oil-forming element migration.

  8. Anisotropic ferromagnetic polymer: A first step for their implementation in microfluidic systems

    NASA Astrophysics Data System (ADS)

    Le Roy, Damien; Dhungana, Daya; Ourry, Laurence; Faivre, Magalie; Ferrigno, Rosaria; Tamion, Alexandre; Dupuis, Véronique; Salles, Vincent; Deman, Anne-Laure

    2016-05-01

    Here we report on the influence of anisotropic microstructure on the performances of magnetically soft micro-patterns intended to integrate microfluidic systems. These micro-patterns are made of a composite obtained by mixing carbonyl iron particles with polydimethylsiloxane, which offers practical integration advantages. We investigated a wide range of magnetic particle loadings, from 10wt% to 83wt%, reaching magnetization as high as 630 kA/m. A homogeneous field was applied during the polymer's cross-linking phase so that to obtain a 1D arrangement of the particles in the solidified polymer, along the field direction. Here we present the results obtained for square-based micro-pillars prepared under a magnetic field applied along one of its diagonal. We assessed the magnetic anisotropy owing to the particles' spatial arrangement by comparing the magnetization processes along the two diagonals of the micro-pillar's base. The magnetic susceptibilities along the two directions differ from a factor greater than three. The results can be described in terms of high aspect ratio and porous magnetic agglomerates.

  9. A constitutive model for plastically anisotropic solids with non-spherical voids

    NASA Astrophysics Data System (ADS)

    Keralavarma, S. M.; Benzerga, A. A.

    2010-06-01

    Plastic constitutive relations are derived for a class of anisotropic porous materials consisting of coaxial spheroidal voids, arbitrarily oriented relative to the embedding orthotropic matrix. The derivations are based on nonlinear homogenization, limit analysis and micromechanics. A variational principle is formulated for the yield criterion of the effective medium and specialized to a spheroidal representative volume element containing a confocal spheroidal void and subjected to uniform boundary deformation. To obtain closed form equations for the effective yield locus, approximations are introduced in the limit-analysis based on a restricted set of admissible microscopic velocity fields. Evolution laws are also derived for the microstructure, defined in terms of void volume fraction, aspect ratio and orientation, using material incompressibility and Eshelby-like concentration tensors. The new yield criterion is an extension of the well known isotropic Gurson model. It also extends previous analyses of uncoupled effects of void shape and material anisotropy on the effective plastic behavior of solids containing voids. Preliminary comparisons with finite element calculations of voided cells show that the model captures non-trivial effects of anisotropy heretofore not picked up by void growth models.

  10. Metal recovery from porous materials

    DOEpatents

    Sturcken, E.F.

    1992-10-13

    A method is described for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF[sub 4] and HNO[sub 3] and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200 C. The porous material can be pulverized before immersion to further increase the leach rate.

  11. POROUS WALL, HOLLOW GLASS MICROSPHERES

    SciTech Connect

    Sexton, W.

    2012-06-30

    Hollow Glass Microspheres (HGM) is not a new technology. All one has to do is go to the internet and Google{trademark} HGM. Anyone can buy HGM and they have a wide variety of uses. HGM are usually between 1 to 100 microns in diameter, although their size can range from 100 nanometers to 5 millimeters in diameter. HGM are used as lightweight filler in composite materials such as syntactic foam and lightweight concrete. In 1968 a patent was issued to W. Beck of the 3M{trademark} Company for 'Glass Bubbles Prepared by Reheating Solid Glass Particles'. In 1983 P. Howell was issued a patent for 'Glass Bubbles of Increased Collapse Strength' and in 1988 H. Marshall was issued a patent for 'Glass Microbubbles'. Now Google{trademark}, Porous Wall, Hollow Glass Microspheres (PW-HGMs), the key words here are Porous Wall. Almost every article has its beginning with the research done at the Savannah River National Laboratory (SRNL). The Savannah River Site (SRS) where SRNL is located has a long and successful history of working with hydrogen and its isotopes for national security, energy, waste management and environmental remediation applications. This includes more than 30 years of experience developing, processing, and implementing special ceramics, including glasses for a variety of Department of Energy (DOE) missions. In the case of glasses, SRS and SRNL have been involved in both the science and engineering of vitreous or glass based systems. As a part of this glass experience and expertise, SRNL has developed a number of niches in the glass arena, one of which is the development of porous glass systems for a variety of applications. These porous glass systems include sol gel glasses, which include both xerogels and aerogels, as well as phase separated glass compositions, that can be subsequently treated to produce another unique type of porosity within the glass forms. The porous glasses can increase the surface area compared to 'normal glasses of a 1 to 2 order of

  12. Porous glasses for optical sensors

    NASA Astrophysics Data System (ADS)

    Dorosz, Dominik; Procyk, Bernadeta

    2006-03-01

    Microporous glasses from the Na II0-B II0 3-Si0 II system can be obtained by appropriate thermal and chemical treatment. During the thermal treatment the separation of the borate phase from the silicon skeleton has been occurred. The borates are in the form small drops joined to each other. In the course of chemical treatment the borates become leached in water, water solutions of acids or basis and the glass becomes porous. Microporous glasses may find application in many branches of science and engineering. The applications depend on the internal arrangement, size and shape of pores. These parameters may be in a wide range modified by a change of the chemical composition. The received porous glass was used as an element in optical fibre NO II sensor. The specific coloration reaction between organic reagents and NO II in the pores was occurred. It is possible to detection of 10-50 ppm NO II level.

  13. Porous-electrode preparation method

    DOEpatents

    Arons, R.M.; Dusek, J.T.

    1981-09-17

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity.

  14. Transport phenomena in porous media

    NASA Astrophysics Data System (ADS)

    Bear, Jacob; Corapcioglu, M. Yavuz

    The Advanced Study Institute on Fundamentals of Transport Phenomena in Porous Media, held July 14-23, 1985 in Newark, Del. and directed by Jacob Bear (Israel Institute of Technology, Haifa) and M. Yavuz Corapcioglu (City College of New York), under the auspices of NATO, was a sequel to the NATO Advanced Study Institute (ASI) held in 1982 (proceedings published as Fundamentals of Transport Phenomena in Porous Media, J. Bear, and M.Y. Corapcioglu (Ed.), Martinus Nijhoff, Dordrecht, the Netherlands, 1984). The meeting was attended by 106 participants and lecturers from 21 countries.As in the first NATO/ASI, the objective of this meeting—which was a combination of a conference of experts and a teaching institute— was to present and discuss selected topics of transport in porous media. In selecting topics and lecturers, an attempt was made to bridge the gap that sometimes exists between research and practice. An effort was also made to demonstrate the unified approach to the transport of mass of a fluid phase, components of a fluid phase, momentum, and heat in a porous medium domain. The void space may be occupied by a single fluid phase or by a number of such phases; each fluid may constitute a multicomponent system; the solid matrix may be deformable; and the whole process of transport in the system may take place under nonisothermal conditions, with or without phase changes. Such phenomena are encountered in a variety of disciplines, e.g., petroleum engineering, civil engineering (in connection with groundwater flow and contamination), soil mechanics, and chemical engineering. One of the goals of the 1985 NATO/ASI, as in the 1982 institute, was to bring together experts from all these disciplines and enhance communication among them.

  15. Geodesic acoustic mode in anisotropic plasma with heat flux

    SciTech Connect

    Ren, Haijun

    2015-10-15

    Geodesic acoustic mode (GAM) in an anisotropic tokamak plasma is investigated in fluid approximation. The collisionless anisotropic plasma is described within the 16-momentum magnetohydrodynamic (MHD) fluid closure model, which takes into account not only the pressure anisotropy but also the anisotropic heat flux. It is shown that the GAM frequency agrees better with the kinetic result than the standard Chew-Goldberger-Low (CGL) MHD model. When zeroing the anisotropy, the 16-momentum result is identical with the kinetic one to the order of 1/q{sup 2}, while the CGL result agrees with the kinetic result only on the leading order. The discrepancies between the results of the CGL fluid model and the kinetic theory are well removed by considering the heat flux effect in the fluid approximation.

  16. Shear-free anisotropic cosmological models in {f (R)} gravity

    NASA Astrophysics Data System (ADS)

    Abebe, Amare; Momeni, Davood; Myrzakulov, Ratbay

    2016-04-01

    We study a class of shear-free, homogeneous but anisotropic cosmological models with imperfect matter sources in the context of f( R) gravity. We show that the anisotropic stresses are related to the electric part of the Weyl tensor in such a way that they balance each other. We also show that within the class of orthogonal f( R) models, small perturbations of shear are damped, and that the electric part of the Weyl tensor and the anisotropic stress tensor decay with the expansion as well as the heat flux of the curvature fluid. Specializing in locally rotationally symmetric spacetimes in orthonormal frames, we examine the late-time behaviour of the de Sitter universe in f( R) gravity. For the Starobinsky model of f( R), we study the evolutionary behavior of the Universe by numerically integrating the Friedmann equation, where the initial conditions for the expansion, acceleration and jerk parameters are taken from observational data.

  17. Reduction of noise in diffusion tensor images using anisotropic smoothing.

    PubMed

    Ding, Zhaohua; Gore, John C; Anderson, Adam W

    2005-02-01

    To improve the accuracy of tissue structural and architectural characterization with diffusion tensor imaging, a novel smoothing technique is developed for reducing noise in diffusion tensor images. The technique extends the traditional anisotropic diffusion filtering method by allowing isotropic smoothing within homogeneous regions and anisotropic smoothing along structure boundaries. This is particularly useful for smoothing diffusion tensor images in which direction information contained in the tensor needs to be restored following noise corruption and preserved around tissue boundaries. The effectiveness of this technique is quantitatively studied with experiments on simulated and human in vivo diffusion tensor data. Illustrative results demonstrate that the anisotropic smoothing technique developed can significantly reduce the impact of noise on the direction as well as anisotropy measures of the diffusion tensor images.

  18. Anisotropic Smoothing Improves DT-MRI-Based Muscle Fiber Tractography

    PubMed Central

    Buck, Amanda K. W.; Ding, Zhaohua; Elder, Christopher P.; Towse, Theodore F.; Damon, Bruce M.

    2015-01-01

    Purpose To assess the effect of anisotropic smoothing on fiber tracking measures, including pennation angle, fiber tract length, and fiber tract number in the medial gastrocnemius (MG) muscle in healthy subjects using diffusion-weighted magnetic resonance imaging (DW-MRI). Materials and Methods 3T DW-MRI data were used for muscle fiber tractography in the MG of healthy subjects. Anisotropic smoothing was applied at three levels (5%, 10%, 15%), and pennation angle, tract length, fiber tract number, fractional anisotropy, and principal eigenvector orientation were quantified for each smoothing level. Results Fiber tract length increased with pre-fiber tracking smoothing, and local heterogeneities in fiber direction were reduced. However, pennation angle was not affected by smoothing. Conclusion Modest anisotropic smoothing (10%) improved fiber-tracking results, while preserving structural features. PMID:26010830

  19. Fermionic collective modes of an anisotropic quark-gluon plasma

    SciTech Connect

    Schenke, Bjoern; Strickland, Michael

    2006-09-15

    We determine the fermionic collective modes of a quark-gluon plasma which is anisotropic in momentum space. We calculate the fermion self-energy in both the imaginary- and real-time formalisms and find that numerically and analytically (for two special cases) there are no unstable fermionic modes. In addition we demonstrate that in the hard-loop limit the Kubo-Martin-Schwinger condition, which relates the off-diagonal components of the real-time fermion self-energy, holds even for the anisotropic, and therefore nonequilibrium, quark-gluon plasma considered here. The results obtained here set the stage for the calculation of the nonequilibrium photon production rate from an anisotropic quark-gluon plasma.

  20. Hemispherical anisotropic patterns of the Earth's inner core.

    PubMed

    Mattesini, Maurizio; Belonoshko, Anatoly B; Buforn, Elisa; Ramírez, María; Simak, Sergei I; Udías, Agustín; Mao, Ho-Kwang; Ahuja, Rajeev

    2010-05-25

    It has been shown that the Earth's inner core has an axisymmetric anisotropic structure with seismic waves traveling approximately 3% faster along polar paths than along equatorial directions. Hemispherical anisotropic patterns of the solid Earth's core are rather complex, and the commonly used hexagonal-close-packed iron phase might be insufficient to account for seismological observations. We show that the data we collected are in good agreement with the presence of two anisotropically specular east and west core hemispheres. The detected travel-time anomalies can only be disclosed by a lattice-preferred orientation of a body-centered-cubic iron aggregate, having a fraction of their [111] crystal axes parallel to the Earth's rotation axis. This is compelling evidence for the presence of a body-centered-cubic Fe phase at the top of the Earth's inner core. PMID:20457937

  1. Cosmic parallax as a probe of late time anisotropic expansion

    SciTech Connect

    Quercellini, Claudia; Cabella, Paolo; Balbi, Amedeo; Amendola, Luca

    2009-09-15

    Cosmic parallax is the change of angular separation between a pair of sources at cosmological distances induced by an anisotropic expansion. An accurate astrometric experiment like Gaia could observe or put constraints on cosmic parallax. Examples of anisotropic cosmological models are Lemaitre-Tolman-Bondi void models for off-center observers (introduced to explain the observed acceleration without the need for dark energy) and Bianchi metrics. If dark energy has an anisotropic equation of state, as suggested recently, then a substantial anisotropy could arise at z < or approx. 1 and escape the stringent constraints from the cosmic microwave background. In this paper we show that such models could be constrained by the Gaia satellite or by an upgraded future mission.

  2. Isotropic and anisotropic bouncing cosmologies in Palatini gravity

    SciTech Connect

    Barragan, Carlos; Olmo, Gonzalo J.

    2010-10-15

    We study isotropic and anisotropic (Bianchi I) cosmologies in Palatini f(R) and f(R,R{sub {mu}{nu}R}{sup {mu}{nu}}) theories of gravity with a perfect fluid and consider the existence of nonsingular bouncing solutions in the early universe. We find that all f(R) models with isotropic bouncing solutions develop shear singularities in the anisotropic case. On the contrary, the simple quadratic model R+aR{sup 2}/R{sub P}+R{sub {mu}{nu}R}{sup {mu}{nu}/}R{sub P} exhibits regular bouncing solutions in both isotropic and anisotropic cases for a wide range of equations of state, including dust (for a<0) and radiation (for arbitrary a). It thus represents a purely gravitational solution to the big bang singularity and anisotropy problems of general relativity without the need for exotic (w>1) sources of matter/energy or extra degrees of freedom.

  3. A hybrid-stress finite element for linear anisotropic elasticity

    NASA Technical Reports Server (NTRS)

    Fly, Gerald W.; Oden, J. Tinsley; Pearson, Mark L.

    1988-01-01

    Standard assumed displacement finite elements with anisotropic material properties perform poorly in complex stress fields such as combined bending and shear and combined bending and torsion. A set of three dimensional hybrid-stress brick elements were developed with fully anisotropic material properties. Both eight-node and twenty-node bricks were developed based on the symmetry group theory of Punch and Atluri. An eight-node brick was also developed using complete polynomials and stress basis functions and reducing the order of the resulting stress parameter matrix by applying equilibrium constraints and stress compatibility constraints. Here the stress compatibility constraints must be formulated assuming anisotropic material properties. The performance of these elements was examined in numerical examples covering a broad range of stress distributions. The stress predictions show significant improvement over the assumed displacement elements but the calculation time is increased.

  4. Hemispherical Anisotropic Patterns of the Earth's Inner Core

    NASA Astrophysics Data System (ADS)

    Mattesini, M.; Belonoshko, A. B.; Buforn, E.; Ramirez, M.; Simak, S. I.; Udias, A.; Mao, H.; Ahuja, R.

    2010-12-01

    It has been shown that the Earth's inner core has an axisymmetric anisotropic structure with seismic waves travelling ˜3% faster along polar paths than along equatorial directions. However, hemispherical anisotropic patterns of solid Earth's core are rather complex, and the commonly used hexagonal-close-packed (hcp) iron phase might be insufficient to account for seismological observations. We show that the data we collected are in good agreement with the presence of two anisotropically specular east and west core hemispheres. The detected travel-time anomalies can only be disclosed by a lattice preferred orientation of a body-centered-cubic iron aggregate (bcc), having a fraction of their [111] crystal axes parallel to the Earth's rotation axis. This is a compelling evidence for the presence of a body-centered-cubic Fe phase at the top 100 km of the Earth's inner core.

  5. Well behaved anisotropic compact star models in general relativity

    NASA Astrophysics Data System (ADS)

    Jasim, M. K.; Maurya, S. K.; Gupta, Y. K.; Dayanandan, B.

    2016-11-01

    Anisotropic compact star models have been constructed by assuming a particular form of a metric function e^{λ}. We solved the Einstein field equations for determining the metric function e^{ν}. For this purpose we have assumed a physically valid expression of radial pressure (pr). The obtained anisotropic compact star model is representing the realistic compact objects such as PSR 1937 +21. We have done an extensive study about physical parameters for anisotropic models and found that these parameters are well behaved throughout inside the star. Along with these we have also determined the equation of state for compact star which gives the radial pressure is purely the function of density i.e. pr=f(ρ).

  6. Adaptive anisotropic meshing for steady convection-dominated problems

    SciTech Connect

    Nguyen, Hoa; Gunzburger, Max; Ju, Lili; Burkardt, John

    2009-01-01

    Obtaining accurate solutions for convection–diffusion equations is challenging due to the presence of layers when convection dominates the diffusion. To solve this problem, we design an adaptive meshing algorithm which optimizes the alignment of anisotropic meshes with the numerical solution. Three main ingredients are used. First, the streamline upwind Petrov–Galerkin method is used to produce a stabilized solution. Second, an adapted metric tensor is computed from the approximate solution. Third, optimized anisotropic meshes are generated from the computed metric tensor by an anisotropic centroidal Voronoi tessellation algorithm. Our algorithm is tested on a variety of two-dimensional examples and the results shows that the algorithm is robust in detecting layers and efficient in avoiding non-physical oscillations in the numerical approximation.

  7. Anisotropic silk fibroin/gelatin scaffolds from unidirectional freezing.

    PubMed

    Asuncion, Maria Christine Tankeh; Goh, James Cho-Hong; Toh, Siew-Lok

    2016-10-01

    Recent studies have underlined the importance of matching scaffold properties to the biological milieu. Tissue, and thus scaffold, anisotropy is one such property that is important yet sometimes overlooked. Methods that have been used to achieve anisotropic scaffolds present challenges such as complicated fabrication steps, harsh processing conditions and toxic chemicals involved. In this study, unidirectional freezing was employed to fabricate anisotropic silk fibroin/gelatin scaffolds in a simple and mild manner. Morphological, mechanical, chemical and cellular compatibility properties were investigated, as well as the effect of the addition of gelatin to certain properties of the scaffold. It was shown that scaffold properties were suitable for cell proliferation and that mesenchymal stem cells were able to align themselves along the directed fibers. The fabricated scaffolds present a platform that can be used for anisotropic tissue engineering applications such as cardiac patches. PMID:27287164

  8. Strongly interacting particles on an anisotropic kagome lattice

    NASA Astrophysics Data System (ADS)

    Hotta, Chisa; Pollmann, Frank

    2009-01-01

    We study a model of strongly interacting spinless fermions and hard-core bosons on an anisotropic kagome lattice near 2/3-filling. Our main focus lies on the strongly anisotropic case in which the nearest-neighbor repulsions V and V' are large compared to the hopping amplitudes |t| and |t'|. When t = t' = 0, the system has a charge ordered insulating ground state where the charges align in striped configurations. Doping one electron or hole into the ground state yields an anisotropic metal at V' > V, where the particle fractionalizes along the V'-bonds while propagates along the V-bonds in a one-body like manner. The sixth order ring exchange processes around the hexagonal unit of the lattice play a crucial role in forming a bound state of fractional charges.

  9. Stochastic Loewner evolution relates anomalous diffusion and anisotropic percolation

    NASA Astrophysics Data System (ADS)

    Credidio, Heitor F.; Moreira, André A.; Herrmann, Hans J.; Andrade, José S.

    2016-04-01

    We disclose the origin of anisotropic percolation perimeters in terms of the stochastic Loewner evolution (SLE) process. Precisely, our results from extensive numerical simulations indicate that the perimeters of multilayered and directed percolation clusters at criticality are the scaling limits of the Loewner evolution of an anomalous Brownian motion, being superdiffusive and subdiffusive, respectively. The connection between anomalous diffusion and fractal anisotropy is further tested by using long-range power-law correlated time series (fractional Brownian motion) as the driving functions in the evolution process. The fact that the resulting traces are distinctively anisotropic corroborates our hypothesis. Under the conceptual framework of SLE, our study therefore reveals different perspectives for mathematical and physical interpretations of non-Markovian processes in terms of anisotropic paths at criticality and vice versa.

  10. Simulating convergent extension by way of anisotropic differential adhesion.

    PubMed

    Zajac, Mark; Jones, Gerald L; Glazier, James A

    2003-05-21

    Simulations using the Extended Potts Model suggest that anisotropic differential adhesion can account for convergent extension, as observed during embryonic development of the frog Xenopus laevis for example. During gastrulation in these frogs, convergent extension produces longitudinal tissue growth from latitudinal elongation and migration of aligned constituent cells. The Extended Potts Model employs clustered points on a grid to represent subdivided cells with probabilistic displacement of cell boundaries such that small changes in energy drive gradual tissue development. For modeling convergent extension, simulations include anisotropic differential adhesion: the degree of attachment between adjacent elongated cells depends on their relative orientation. Without considering additional mechanisms, simulations based on anisotropic differential adhesion reproduce the hallmark stages of convergent extension in the correct sequence, with random fluctuations as sufficient impetus for cell reorganization. PMID:12727459

  11. Scattering of electromagnetic light waves from a deterministic anisotropic medium

    NASA Astrophysics Data System (ADS)

    Li, Jia; Chang, Liping; Wu, Pinghui

    2015-11-01

    Based on the weak scattering theory of electromagnetic waves, analytical expressions are derived for the spectral densities and degrees of polarization of an electromagnetic plane wave scattered from a deterministic anisotropic medium. It is shown that the normalized spectral densities of scattered field is highly dependent of changes of the scattering angle and degrees of polarization of incident plane waves. The degrees of polarization of scattered field are also subjective to variations of these parameters. In addition, the anisotropic effective radii of the dielectric susceptibility can lead essential influences on both spectral densities and degrees of polarization of scattered field. They are highly dependent of the effective radii of the medium. The obtained results may be applicable to determine anisotropic parameters of medium by quantitatively measuring statistics of a far-zone scattered field.

  12. Anisotropic light scattering of individual sickle red blood cells

    NASA Astrophysics Data System (ADS)

    Kim, Youngchan; Higgins, John M.; Dasari, Ramachandra R.; Suresh, Subra; Park, YongKeun

    2012-04-01

    We present the anisotropic light scattering of individual red blood cells (RBCs) from a patient with sickle cell disease (SCD). To measure light scattering spectra along two independent axes of elongated-shaped sickle RBCs with arbitrary orientation, we introduce the anisotropic Fourier transform light scattering (aFTLS) technique and measured both the static and dynamic anisotropic light scattering. We observed strong anisotropy in light scattering patterns of elongated-shaped sickle RBCs along its major axes using static aFTLS. Dynamic aFTLS analysis reveals the significantly altered biophysical properties in individual sickle RBCs. These results provide evidence that effective viscosity and elasticity of sickle RBCs are significantly different from those of the healthy RBCs.

  13. Energy shift due to anisotropic black body radiation

    NASA Astrophysics Data System (ADS)

    Porsev, Sergey; Flambaum, Victor; Safronova, Marianna

    2016-05-01

    In many applications a source of the black-body radiation (BBR) can be highly anisotropic. This leads to the black-body radiation shift that depends on tensor polarizability and on the projection of the total angular momentum of ions and atoms in a trap. We derived formula for the anisotropic BBR shift and performed numerical calculations of this effect for Ca+ and Yb+ transitions of experimental interest. These ions are used for a design of high-precision atomic clocks, fundamental physics tests such as search for the Lorentz invariance violation and space-time variation of the fundamental constants, and quantum information. Anisotropic BBR shift may be one of the major systematic effects in these experiments. This work was supported by U.S. NSF grants and the Australian Research Council.

  14. Analysis of two-dimensional photonic crystal with anisotropic gain.

    PubMed

    Takigawa, Shinichi; Noda, Susumu

    2011-05-01

    Photonic modes in a two-dimensional square-lattice photonic crystal (PC) with anisotropic gain are analyzed for the first time. A plane-wave expansion method is improved to include the gain, which depends on not only the position but also the propagation direction of each plane wave. The anisotropic gain varies the photonic band structure, the near-field distributions, and the gain dispersion curves through variation in PC symmetry. Low-threshold operation of a PC laser with anisotropic-gain material such as nonpolar InGaN requires that the direction of higher gain in the material aligns along the ΓX direction of the PC. PMID:21643205

  15. Microscale transport in porous media

    SciTech Connect

    Rashidi, M.; Rinker, R.

    1996-04-01

    In-pore transport processes in homogeneous and heterogeneous porous media have been investigated using novel 3D imaging techniques. The experimental system consists of a clear column packed with clear particles and a refractive index-matched fluid seeded with fluorescent tracers and an organic solute dye. By illuminating the porous regions within the column with a planar sheet of laser beam, flow and transport processes through the porous medium can be observed microscopically, and qualitative and quantitative in-pore transport information can be obtained at a good resolution and a high accuracy. Fluorescent images are captured and recorded at every vertical plane location while sweeping back and forth across the test section. These digitized transport images are then analyzed and accumulated over a 3D volume within the column. This paper reports on pore-scale observations of velocity, chemical concentration, and fluxes. Tests were undertaken with two separate columns. One is a rectangular column for chemical transport and bioremediation studies in aqueous heterogeneous systems and the other is a cylindrical column for flow and transport investigations in nonaqueous homogeneous systems.

  16. The effects of fracture permeability on acoustic wave propagation in the porous media: A microscopic perspective.

    PubMed

    Wang, Ding; Wang, Liji; Ding, Pinbo

    2016-08-01

    An illustrative theory is developed to analyze the acoustic wave propagation characteristics in the porous media with anisotropic permeability. We focus here on the role of fracture permeability in the unconsolidated porous media, looking in particular at the compressional P-wave phase velocity and attenuation. Two fluid pressure equilibration characteristic time factors are defined, which are corresponding to crack-pore system and crack-crack system, respectively. The theoretical results show that the dispersion and attenuation characteristics of acoustic wave are affected by porous matrix and fracture permeability simultaneously. Due to the fluid exchange that takes place between fractures and pores dominantly, the influence of the fracture connectivity on the wave propagation is very weak when the permeability of background medium is relatively high. However, correlation between wave propagation and fracture permeability is significant when the matrix permeability at a low level. A second attenuation peak occurs for the fluid flow within fractures in high-frequency region for more and more higher fracture permeability. The exact analytical solutions that are compared to numerical forward modeling of wave propagation in fractured media allow us to verify the correctness of the new model. If there exists another approach for obtaining the connectivity information of background media, we can use this model to analyze qualitatively the permeability of fractures or afford an indicator of in-situ permeability changes in a oil reservoir, for example, fracturing operations.

  17. Porous titanium scaffolds fabricated using a rapid prototyping and powder metallurgy technique.

    PubMed

    Ryan, Garrett E; Pandit, Abhay S; Apatsidis, Dimitrios P

    2008-09-01

    One of the main issues in orthopaedic implant design is the fabrication of scaffolds that closely mimic the biomechanical properties of the surrounding bone. This research reports on a multi-stage rapid prototyping technique that was successfully developed to produce porous titanium scaffolds with fully interconnected pore networks and reproducible porosity and pore size. The scaffolds' porous characteristics were governed by a sacrificial wax template, fabricated using a commercial 3D-printer. Powder metallurgy processes were employed to generate the titanium scaffolds by filling around the wax template with titanium slurry. In the attempt to optimise the powder metallurgy technique, variations in slurry concentration, compaction pressure and sintering temperature were investigated. By altering the wax design template, pore sizes ranging from 200 to 400 microm were achieved. Scaffolds with porosities of 66.8 +/- 3.6% revealed compression strengths of 104.4+/-22.5 MPa in the axial direction and 23.5 +/- 9.6 MPa in the transverse direction demonstrating their anisotropic nature. Scaffold topography was characterised using scanning electron microscopy and microcomputed tomography. Three-dimensional reconstruction enabled the main architectural parameters such as pore size, interconnecting porosity, level of anisotropy and level of structural disorder to be determined. The titanium scaffolds were compared to their intended designs, as governed by their sacrificial wax templates. Although discrepancies in architectural parameters existed between the intended and the actual scaffolds, overall the results indicate that the porous titanium scaffolds have the properties to be potentially employed in orthopaedic applications.

  18. Fabrication of alumina porous scaffolds with aligned oriented pores for bone tissue engineering applications

    NASA Astrophysics Data System (ADS)

    Sarhadi, Fatemeh; Shafiee Afarani, Mahdi; Mohebbi-Kalhori, Davod; Shayesteh, Masoud

    2016-04-01

    In the present study, porous alumina scaffolds with specific orientation and anisotropic properties are fabricated for application in bone tissue repair. The scaffolds with double shape pores, tubular oriented and isotropic rounded pores, were prepared using alumina and silica as starting materials by the slip casting route. Milled polyurethane foam and silk fibers were applied as replica materials as well. The effect of fiber types and diameter and number of fibers on the microstructure and pore size was studied. Moreover, different characteristics such as porosity, density, orientation, flexural strength and compressive strength of the samples were investigated. Results showed that various fibers with different diameters and numbers led to forming the pores with different pore sizes, microstructure and consequently changes in the physical and mechanical properties. In addition, the simultaneous presence of fibers and particles led to more porous scaffolds. The oriented tiny micro-tube and rounded pores were observed in all porous ceramic scaffolds. Mechanical testing showed an anisotropy in the mechanical behaviors such that higher strengths were observed in the oriented pore direction than that of transverse. With increasing the number and diameter of silk fibers, the scaffolds with a high porosity up to 68 vol% and proper flexural strength were obtained.

  19. The effects of fracture permeability on acoustic wave propagation in the porous media: A microscopic perspective.

    PubMed

    Wang, Ding; Wang, Liji; Ding, Pinbo

    2016-08-01

    An illustrative theory is developed to analyze the acoustic wave propagation characteristics in the porous media with anisotropic permeability. We focus here on the role of fracture permeability in the unconsolidated porous media, looking in particular at the compressional P-wave phase velocity and attenuation. Two fluid pressure equilibration characteristic time factors are defined, which are corresponding to crack-pore system and crack-crack system, respectively. The theoretical results show that the dispersion and attenuation characteristics of acoustic wave are affected by porous matrix and fracture permeability simultaneously. Due to the fluid exchange that takes place between fractures and pores dominantly, the influence of the fracture connectivity on the wave propagation is very weak when the permeability of background medium is relatively high. However, correlation between wave propagation and fracture permeability is significant when the matrix permeability at a low level. A second attenuation peak occurs for the fluid flow within fractures in high-frequency region for more and more higher fracture permeability. The exact analytical solutions that are compared to numerical forward modeling of wave propagation in fractured media allow us to verify the correctness of the new model. If there exists another approach for obtaining the connectivity information of background media, we can use this model to analyze qualitatively the permeability of fractures or afford an indicator of in-situ permeability changes in a oil reservoir, for example, fracturing operations. PMID:27259119

  20. Anisotropic metamaterials for microwave antennas and infrared nanostructured thin films

    NASA Astrophysics Data System (ADS)

    Jian, Zhihao

    Wave-matter interactions have long been investigated to discover unknown physical phenomena and exploited to achieve improved device performance throughout the electromagnetic spectrum ranging from quasi-static limit to microwave frequencies, and even at infrared and optical wavelengths. As a nascent but fast growing field, metamaterial technology, which relies on clusters of artificially engineered subwavelength structures, has been demonstrated to provide a wide variety of exotic electromagnetic properties unattainable in natural materials. This dissertation presents the research on novel anisotropic metamaterials for tailoring microwave radiation and infrared scattering of nanostructured thin films. First, a new inversion algorithm is proposed for retrieving the anisotropic effective medium parameters of a slab of metamaterial. Secondly, low-loss anisotropic metamaterial lenses and coatings are introduced for improving the gain and/or bandwidth for a variety of antennas. In particular, a quad-beam high-gain lens for a quarter-wave monopole, a low-profile grounded leaky metamaterial coating for slot antenna, and an ultra-thin anisotropic metamaterial bandwidth-enhancing coating for a quarter-wave monopole are experimentally demonstrated. In the infrared regime, novel nanostructured metamaterial free-standing thin-films, which are inherently anisotropic, are introduced for achieving exotic index properties and further for practical photonic devices. In particular, a low-loss near-infrared fishnet zero-index metamaterial, a dispersionengineered optically-thin, low-loss broadband metamaterial filter with a suppressed group delay fluctuation in the mid-infrared, and a conformal dual-band near-perfectly absorbing coating in the mid-infrared are experimentally demonstrated. These explorations show the great promise anisotropic metamaterials hold for the flexible manipulation of electromagnetic waves and their broad applicability in a wide spectrum range.