Predicting the pKa and stability of organic acids and bases at an oil-water interface.

PubMed

Andersson, M P; Olsson, M H M; Stipp, S L S

2014-06-10

We have used density functional theory and the implicit solvent model, COSMO-RS, to investigate how the acidity constant, pKa, of organic acids and bases adsorbed at the organic compound-aqueous solution interface changes, compared to its value in the aqueous phase. The pKa determine the surface charge density of the molecules that accumulate at the fluid-fluid interface. We have estimated the pKa by comparing the stability of the protonated and unprotonated forms of a series of molecules in the bulk aqueous solution and at an interface where parts of each molecule reside in the hydrophobic phase and the rest remains in the hydrophilic phase. We found that the pKa for acids is shifted by ∼1 pH unit to higher values compared to the bulk water pKa, whereas they are shifted to lower values by a similar amount for bases. Because this pKa shift is similar in magnitude for each of the molecules studied, we propose that the pKa for molecules at a water-organic compound interface can easily be predicted by adding a small shift to the aqueous pKa. This shift is general and correlates with the functional group. We also found that the relative composition of molecules at the fluid-fluid interface is not the same as in the bulk. For example, species such as carboxylic acids are enriched at the interface, where they can dominate surface properties, even when they are a modest component in the bulk fluid. For high surface concentrations of carboxylic acid groups at an interface, such as a self-assembled monolayer, we have demonstrated that the pKa depends on the degree of deprotonation through direct hydrogen bonding between protonated and deprotonated acidic headgroups.

Splay fault branching from the Hikurangi subduction shear zone: Implications for slow slip and fluid flow

NASA Astrophysics Data System (ADS)

Plaza-Faverola, A.; Henrys, S.; Pecher, I.; Wallace, L.; Klaeschen, D.

2016-12-01

Prestack depth migration data across the Hikurangi margin, East Coast of the North Island, New Zealand, are used to derive subducting slab geometry, upper crustal structure, and seismic velocities resolved to ˜14 km depth. We investigate the potential relationship between the crustal architecture, fluid migration, and short-term geodetically determined slow slip events. The subduction interface is a shallow dipping thrust at <7 km depth near the trench and steps down to 14 km depth along an ˜18 km long ramp, beneath Porangahau Ridge. This apparent step in the décollement is associated with splay fault branching and coincides with a zone of maximum slip (90 mm) inferred on the subduction interface during slow slip events in June and July 2011. A low-velocity zone beneath the plate interface, updip of the plate interface ramp, is interpreted as fluid-rich overpressured sediments capped with a low permeability condensed layer of chalk and interbedded mudstones. Fluid-rich sediments have been imbricated by splay faults in a region that coincides with the step down in the décollement from the top of subducting sediments to the oceanic crust and contribute to spatial variation in frictional properties of the plate interface that may promote slow slip behavior in the region. Further, transient fluid migration along splay faults at Porangahau Ridge may signify stress changes during slow slip.

Ferrofluid patterns in Hele-Shaw cells: Exact, stable, stationary shape solutions.

PubMed

Lira, Sérgio A; Miranda, José A

2016-01-01

We investigate a quasi-two-dimensional system composed of an initially circular ferrofluid droplet surrounded by a nonmagnetic fluid of higher density. These immiscible fluids flow in a rotating Hele-Shaw cell, under the influence of an in-plane radial magnetic field. We focus on the situation in which destabilizing bulk magnetic field effects are balanced by stabilizing centrifugal forces. In this framing, we consider the interplay of capillary and magnetic normal traction effects in determining the fluid-fluid interface morphology. By employing a vortex-sheet formalism, we have been able to find a family of exact stationary N-fold polygonal shape solutions for the interface. A weakly nonlinear theory is then used to verify that such exact interfacial solutions are in fact stable.

On the nonlinear interfacial instability of rotating core-annular flow

NASA Technical Reports Server (NTRS)

Coward, Aidrian V.; Hall, Philip

1993-01-01

The interfacial stability of rotating core-annular flows is investigated. The linear and nonlinear effects are considered for the case when the annular region is very thin. Both asymptotic and numerical methods are used to solve the flow in the core and film regions which are coupled by a difference in viscosity and density. The long-term behavior of the fluid-fluid interface is determined by deriving its nonlinear evolution in the form of a modified Kuramoto-Sivashinsky equation. We obtain a generalization of this equation to three dimensions. The flows considered are applicable to a wide array of physical problems where liquid films are used to lubricate higher or lower viscosity core fluids, for which a concentric arrangement is desired. Linearized solutions show that the effects of density and viscosity stratification are crucial to the stability of the interface. Rotation generally destabilizes non-axisymmetric disturbances to the interface, whereas the centripetal forces tend to stabilize flows in which the film contains the heavier fluid. Nonlinear affects allow finite amplitude helically travelling waves to exist when the fluids have different viscosities.

Ultrasonic fluid densitometer for process control

DOEpatents

Greenwood, Margaret S.

2000-01-01

The present invention is an ultrasonic fluid densitometer that uses at least one pair of transducers for transmitting and receiving ultrasonic signals internally reflected within a material wedge. A temperature sensor is provided to monitor the temperature of the wedge material. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface and comparing a transducer voltage and wedge material temperature to a tabulation as a function of density.

Nucleation processes of nanobubbles at a solid/water interface

NASA Astrophysics Data System (ADS)

Fang, Chung-Kai; Ko, Hsien-Chen; Yang, Chih-Wen; Lu, Yi-Hsien; Hwang, Ing-Shouh

2016-04-01

Experimental investigations of hydrophobic/water interfaces often return controversial results, possibly due to the unknown role of gas accumulation at the interfaces. Here, during advanced atomic force microscopy of the initial evolution of gas-containing structures at a highly ordered pyrolytic graphite/water interface, a fluid phase first appeared as a circular wetting layer ~0.3 nm in thickness and was later transformed into a cap-shaped nanostructure (an interfacial nanobubble). Two-dimensional ordered domains were nucleated and grew over time outside or at the perimeter of the fluid regions, eventually confining growth of the fluid regions to the vertical direction. We determined that interfacial nanobubbles and fluid layers have very similar mechanical properties, suggesting low interfacial tension with water and a liquid-like nature, explaining their high stability and their roles in boundary slip and bubble nucleation. These ordered domains may be the interfacial hydrophilic gas hydrates and/or the long-sought chemical surface heterogeneities responsible for contact line pinning and contact angle hysteresis. The gradual nucleation and growth of hydrophilic ordered domains renders the original homogeneous hydrophobic/water interface more heterogeneous over time, which would have great consequence for interfacial properties that affect diverse phenomena, including interactions in water, chemical reactions, and the self-assembly and function of biological molecules.

Analytical solution for the transient response of a fluid/saturated porous medium halfspace system subjected to an impulsive line source

NASA Astrophysics Data System (ADS)

Shan, Zhendong; Ling, Daosheng; Jing, Liping; Li, Yongqiang

2018-05-01

In this paper, transient wave propagation is investigated within a fluid/saturated porous medium halfspace system with a planar interface that is subjected to a cylindrical P-wave line source. Assuming the permeability coefficient is sufficiently large, analytical solutions for the transient response of the fluid/saturated porous medium halfspace system are developed. Moreover, the analytical solutions are presented in simple closed forms wherein each term represents a transient physical wave, especially the expressions for head waves. The methodology utilised to determine where the head wave can emerge within the system is also given. The wave fields within the fluid and porous medium are first defined considering the behaviour of two compressional waves and one tangential wave in the saturated porous medium and one compressional wave in the fluid. Substituting these wave fields into the interface continuity conditions, the analytical solutions in the Laplace domain are then derived. To transform the solutions into the time domain, a suitable distortion of the contour is provided to change the integration path of the solution, after which the analytical solutions in the Laplace domain are transformed into the time domain by employing Cagniard's method. Numerical examples are provided to illustrate some interesting features of the fluid/saturated porous medium halfspace system. In particular, the interface wave and head waves that propagate along the interface between the fluid and saturated porous medium can be observed.

A sharp interface method for compressible liquid–vapor flow with phase transition and surface tension

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fechter, Stefan, E-mail: stefan.fechter@iag.uni-stuttgart.de; Munz, Claus-Dieter, E-mail: munz@iag.uni-stuttgart.de; Rohde, Christian, E-mail: Christian.Rohde@mathematik.uni-stuttgart.de

The numerical approximation of non-isothermal liquid–vapor flow within the compressible regime is a difficult task because complex physical effects at the phase interfaces can govern the global flow behavior. We present a sharp interface approach which treats the interface as a shock-wave like discontinuity. Any mixing of fluid phases is avoided by using the flow solver in the bulk regions only, and a ghost-fluid approach close to the interface. The coupling states for the numerical solution in the bulk regions are determined by the solution of local two-phase Riemann problems across the interface. The Riemann solution accounts for the relevantmore » physics by enforcing appropriate jump conditions at the phase boundary. A wide variety of interface effects can be handled in a thermodynamically consistent way. This includes surface tension or mass/energy transfer by phase transition. Moreover, the local normal speed of the interface, which is needed to calculate the time evolution of the interface, is given by the Riemann solution. The interface tracking itself is based on a level-set method. The focus in this paper is the description of the two-phase Riemann solver and its usage within the sharp interface approach. One-dimensional problems are selected to validate the approach. Finally, the three-dimensional simulation of a wobbling droplet and a shock droplet interaction in two dimensions are shown. In both problems phase transition and surface tension determine the global bulk behavior.« less

Transient Interfacial Phenomena in Miscible Polymer Systems (TIPMPS)

NASA Technical Reports Server (NTRS)

Pojman, John A.; Bessonov, Nicholas; Volpert, Vitaly; Wilke, Hermann

2003-01-01

Almost one hundred years ago Korteweg published a theory of how stresses could be induced in miscible fluids by concentration gradients, causing phenomena that would appear to be the same as with immiscible fluids. Miscible fluids could manifest a transient or effective interfacial tension (EIT). To this day, there has been no definitive experiment to confirm Korteweg's model but numerous fascinating and suggestive experiments have been reported. The goal of TIPMPS is to answer the question: Can concentration and temperature gradients in miscible materials induce stresses that cause convection? Many polymer processes involving miscible monomer and polymer systems could be affected by fluid flow and so this work could help understand miscible polymer processing, not only in microgravity, but also on earth. Demonstrating the existence of this phenomenon in miscible fluids will open up a new area of study for materials science. The science objectives of TIPMPS are: (1) Determine if convection can be induced by variation of the width of a miscible interface; (2) Determine if convection can be induced by variation of temperature along a miscible interface; (3) Determine if convection can be induced by variation of conversion along a miscible interface An interface between two miscible fluids can best be created via a spatially-selective photopolymerization of dodecyl acrylate with a photoinitiator, which allows the creation of precise and accurate concentration gradients between polymer and monomer. Optical techniques will be used to measure the refractive index variation caused by the resultant temperature and concentration fields. The viscosity of the polymer will be measured from the increase in the fluorescence of pyrene. Because the large concentration and temperature gradients cause buoyancy-driven convection that prevents the observation of the predicted flows, the experiment must be done in microgravity. In this report, we will consider our efforts to estimate the square gradient parameter, k, and our use of the estimates in modeling of the planned TIPMPS experiments. We developed a model consisting of the heat and diffusion equations with convective terms and of the Navier-Stokes equations with an additional volume force written in the form of the Korteweg stresses arising from nonlocal interaction in the fluid. The fluid's viscosity dependence on polymer conversion and temperature was taken from measurements of poly(dodecyl acrylate). Numerical modeling demonstrated that significant flows would arise for conditions corresponding to the planned experiments.

Interface instabilities during displacements of two miscible fluids in a vertical pipe

NASA Astrophysics Data System (ADS)

Scoffoni, J.; Lajeunesse, E.; Homsy, G. M.

2001-03-01

We study experimentally the downward vertical displacement of one miscible fluid by another in a vertical pipe at sufficiently high velocities for diffusive effects to be negligible. For certain viscosity ratios and flow rates, the interface between the two fluids can destabilize. We determine the dimensionless flow rate Uc above which the instability is triggered and its dependence on the viscous ratio M, resulting in a stability map Uc=Uc(M). Two different instability modes have been observed: an asymmetric "corkscrew" mode and an axisymmetric one. We remark that the latter is always eventually disturbed by "corkscrew" type instabilities. We speculate that these instabilities are driven by the viscosity stratification and are analogous to those already observed in core annular flows of immiscible fluids.

Method for measuring liquid viscosity and ultrasonic viscometer

DOEpatents

Sheen, Shuh-Haw; Lawrence, William P.; Chien, Hual-Te; Raptis, Apostolos C.

1994-01-01

An ultrasonic viscometer and method for measuring fluid viscosity are provided. Ultrasonic shear and longitudinal waves are generated and coupled to the fluid. Reflections from the generated ultrasonic shear and longitudinal waves are detected. Phase velocity of the fluid is determined responsive to the detected ultrasonic longitudinal waves reflections. Viscosity of the fluid is determined responsive to the detected ultrasonic shear waves reflections. Unique features of the ultrasonic viscometer include the use of a two-interface fluid and air transducer wedge to measure relative signal change and to enable self calibration and the use of a ratio of reflection coefficients for two different frequencies to compensate for environmental changes, such as temperature.

A General Approach for Fluid Patterning and Application in Fabricating Microdevices.

PubMed

Huang, Zhandong; Yang, Qiang; Su, Meng; Li, Zheng; Hu, Xiaotian; Li, Yifan; Pan, Qi; Ren, Wanjie; Li, Fengyu; Song, Yanlin

2018-06-19

Engineering the fluid interface such as the gas-liquid interface is of great significance for solvent processing applications including functional material assembly, inkjet printing, and high-performance device fabrication. However, precisely controlling the fluid interface remains a great challenge owing to its flexibility and fluidity. Here, a general method to manipulate the fluid interface for fluid patterning using micropillars in the microchannel is reported. The principle of fluid patterning for immiscible fluid pairs including air, water, and oils is proposed. This understanding enables the preparation of programmable multiphase fluid patterns and assembly of multilayer functional materials to fabricate micro-optoelectronic devices. This general strategy of fluid patterning provides a promising platform to study the fundamental processes occurring on the fluid interface, and benefits applications in many subjects, such as microfluidics, microbiology, chemical analysis and detection, material synthesis and assembly, device fabrication, etc. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Insect flight on fluid interfaces: a chaotic interfacial oscillator

NASA Astrophysics Data System (ADS)

Mukundarajan, Haripriya; Prakash, Manu

2013-11-01

Flight is critical to the dominance of insect species on our planet, with about 98 percent of insect species having wings. How complex flight control systems developed in insects is unknown, and arboreal or aquatic origins have been hypothesized. We examine the biomechanics of aquatic origins of flight. We recently reported discovery of a novel mode of ``2D flight'' in Galerucella beetles, which skim along an air-water interface using flapping wing flight. This unique flight mode is characterized by a balance between capillary forces from the interface and biomechanical forces exerted by the flapping wings. Complex interactions on the fluid interface form capillary wave trains behind the insect, and produce vertical oscillations at the surface due to non-linear forces arising from deformation of the fluid meniscus. We present both experimental observations of 2D flight kinematics and a dynamic model explaining the observed phenomena. Careful examination of this interaction predicts the chaotic nature of interfacial flight and takeoff from the interface into airborne flight. The role of wingbeat frequency, stroke plane angle and body angle in determining transition between interfacial and fully airborne flight is highlighted, shedding light on the aquatic theory of flight evolution.

Behavior of fluids in a weightless environment

NASA Technical Reports Server (NTRS)

Fester, D. A.; Eberhardt, R. N.; Tegart, J. R.

1977-01-01

Fluid behavior in a low-g environment is controlled primarily by surface tension forces. Certain fluid and system characteristics determine the magnitude of these forces for both a free liquid surface and liquid in contact with a solid. These characteristics, including surface tension, wettability or contact angle, system geometry, and the relationships governing their interaction, are discussed. Various aspects of fluid behavior in a low-g environment are then presented. This includes the formation of static interface shapes, oscillation and rotation of drops, coalescence, the formation of foams, tendency for cavitation, and diffusion in liquids which were observed during the Skylab fluid mechanics science demonstrations. Liquid reorientation and capillary pumping to establish equilibrium configurations for various system geometries, observed during various free-fall (drop-tower) low-g tests, are also presented. Several passive low-g fluid storage and transfer systems are discussed. These systems use surface tension forces to control the liquid/vapor interface and provide gas-free liquid transfer and liquid-free vapor venting.

Slit-lamp technique of draining interface fluid following Descemet's stripping endothelial keratoplasty.

PubMed

Srinivasan, Sathish; Rootman, David S

2007-09-01

To describe a new slit-lamp technique for draining interface fluid to manage complete donor disc detachments following Descemet's stripping (automated) endothelial keratoplasty (DSEK/DSAEK). Interventional case series. Five DSEK/DSAEK patients presented on the first postoperative day with complete detachment of the donor lenticule. Slit-lamp biomicroscopy showed interface fluid preventing attachment of the donor disc to the host stromal bed. A new slit-lamp technique is described to drain the interface fluid. This technique involved completely filling the anterior chamber with an air bubble using a 30-gauge needle on a 3 ml syringe. Following this, a 0.12 forceps was used to open the inferior mid-peripheral corneal drainage slit to drain the interface fluid. This technique was successful in draining the interface fluid in all five patients, leading to immediate complete reattachment of the donor disc. Donor disc detachments following DSEK/DSAEK can be successfully managed by this slit-lamp technique of draining the interface fluid.

Magneto-Rayleigh-Taylor instability in solid media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Y. B.; School of Physical Science and Technology, Lanzhou University, Lanzhou 73000; University of Chinese Academy of Sciences, Beijing 100049

2014-07-15

A linear analysis of the magneto-Rayleigh-Taylor instability at the interface between a Newtonian fluid and an elastic-plastic solid is performed by considering a uniform magnetic B{sup →}, parallel to the interface, which has diffused into the fluid but not into the solid. It is found that the magnetic field attributes elastic properties to the viscous fluid which enhance the stability region by stabilizing all the perturbation wavelengths shorter than λ{sub 0}∝B{sup 2} for any initial perturbation amplitude. Longer wavelengths are stabilized by the mechanical properties of the solid provided that the initial perturbation wavelength is smaller than a threshold valuemore » determined by the yield strength and the shear modulus of the solid. Beyond this threshold, the amplitude grows initially with a growth rate reduced by the solid strength properties. However, such properties do not affect the asymptotic growth rate which is only determined by the magnetic field and the fluid viscosity. The described physical situation intends to resemble some of the features present in recent experiments involving the magnetic shockless acceleration of flyers plates.« less

Interfacial layering and capillary roughness in immiscible liquids.

PubMed

Geysermans, P; Pontikis, V

2010-08-21

The capillary roughness and the atomic density profiles of extended interfaces between immiscible liquids are determined as a function of the interface area by using molecular dynamics and Lennard-Jones (12-6) potentials. We found that with increasing area, the interface roughness diverges logarithmically, thus fitting the theoretical mean-field prediction. In systems small enough for the interfacial roughness not to blur the structural details, atomic density profiles across the fluid interface are layered with correlation length in the range of molecular correlations in liquids. On increasing the system size, the amplitude of the thermally excited position fluctuations of the interface increases, thus causing layering to rapidly vanish, if density profiles are computed without special care. In this work, we present and validate a simple method, operating in the direct space, for extracting from molecular dynamics trajectories the "intrinsic" structure of a fluid interface that is the local density profile of the interface cleaned from capillary wave effects. Estimated values of interfacial properties such as the tension, the intrinsic width, and the lower wavelength limit of position fluctuations are in agreement with results collected from the literature.

Diffuse interface immersed boundary method for multi-fluid flows with arbitrarily moving rigid bodies

NASA Astrophysics Data System (ADS)

Patel, Jitendra Kumar; Natarajan, Ganesh

2018-05-01

We present an interpolation-free diffuse interface immersed boundary method for multiphase flows with moving bodies. A single fluid formalism using the volume-of-fluid approach is adopted to handle multiple immiscible fluids which are distinguished using the volume fractions, while the rigid bodies are tracked using an analogous volume-of-solid approach that solves for the solid fractions. The solution to the fluid flow equations are carried out using a finite volume-immersed boundary method, with the latter based on a diffuse interface philosophy. In the present work, we assume that the solids are filled with a "virtual" fluid with density and viscosity equal to the largest among all fluids in the domain. The solids are assumed to be rigid and their motion is solved using Newton's second law of motion. The immersed boundary methodology constructs a modified momentum equation that reduces to the Navier-Stokes equations in the fully fluid region and recovers the no-slip boundary condition inside the solids. An implicit incremental fractional-step methodology in conjunction with a novel hybrid staggered/non-staggered approach is employed, wherein a single equation for normal momentum at the cell faces is solved everywhere in the domain, independent of the number of spatial dimensions. The scalars are all solved for at the cell centres, with the transport equations for solid and fluid volume fractions solved using a high-resolution scheme. The pressure is determined everywhere in the domain (including inside the solids) using a variable coefficient Poisson equation. The solution to momentum, pressure, solid and fluid volume fraction equations everywhere in the domain circumvents the issue of pressure and velocity interpolation, which is a source of spurious oscillations in sharp interface immersed boundary methods. A well-balanced algorithm with consistent mass/momentum transport ensures robust simulations of high density ratio flows with strong body forces. The proposed diffuse interface immersed boundary method is shown to be discretely mass-preserving while being temporally second-order accurate and exhibits nominal second-order accuracy in space. We examine the efficacy of the proposed approach through extensive numerical experiments involving one or more fluids and solids, that include two-particle sedimentation in homogeneous and stratified environment. The results from the numerical simulations show that the proposed methodology results in reduced spurious force oscillations in case of moving bodies while accurately resolving complex flow phenomena in multiphase flows with moving solids. These studies demonstrate that the proposed diffuse interface immersed boundary method, which could be related to a class of penalisation approaches, is a robust and promising alternative to computationally expensive conformal moving mesh algorithms as well as the class of sharp interface immersed boundary methods for multibody problems in multi-phase flows.

Deciphering the 3-D distribution of fluid along the shallow Hikurangi subduction zone using P- and S-wave attenuation

NASA Astrophysics Data System (ADS)

Eberhart-Phillips, Donna; Bannister, Stephen; Reyners, Martin

2017-11-01

We use local earthquake velocity spectra to solve for the 3-D distribution of P- and S-wave attenuation in the shallow Hikurangi subduction zone in the North Island of New Zealand to gain insight into how fluids control both the distribution of slip rate deficit and slow-slip events at the shallow plate interface. Qs/Qp gives us information on the 3-D distribution of fluid saturation, which we can compare with the previously determined 3-D distribution of Vp/Vs, which gives information on pore fluid pressure. The Hikurangi margin is unusual, in that a large igneous province (the Hikurangi Plateau) is being subducted. This plateau has had two episodes of subduction-first at 105-100 Ma during north-south convergence with Gondwana, and currently during east-west convergence between the Pacific and Australian plates. We find that in the southern part of the subduction zone, where there is a large deficit in slip rate at the plate interface, the plate interface region is only moderately fluid-rich because the underlying plateau had already had an episode of dehydration during Gondwana subduction. But fluid pressure is relatively high, due to an impermeable terrane in the upper plate trapping fluids below the plate interface. The central part of the margin, where the slip rate deficit is very low, is the most fluid-rich part of the shallow subduction zone. We attribute this to an excess of fluid from the subducted plateau. Our results suggest this part of the plateau has unusually high fracture permeability, on account of it having had two episodes of bending-first at the Gondwana trench and now at the Hikurangi Trough. Qs/Qp is consistent with fluids migrating across the plate interface in this region, leaving it drained and producing high fluid pressure in the overlying plate. The northern part of the margin is a region of heterogeneous deficit in slip rate. Here the Hikurangi Plateau is subducting for the first time, so there is less fluid available from its dehydration than in the central region. Fluid pressure in the overlying plate is high, but Qs/Qp indicates that it is not uniformly fluid-rich. This heterogeneity is consistent with the rough topography of the plateau, including seamounts which entrain fluid-rich sediments. Deep slow-slip events in the southern part of the margin occur where the Moho of the overlying plate meets the plate interface, as typically seen in other deep slow-slip events worldwide. But in the central and northern parts of the margin, the locations of shallow slow-slip events appear to be controlled by a shallow brittle-viscous transition within the fluid-rich upper plate. There is also evidence that a major fault zone in the overlying plate might bleed off some of the high fluid pressure promoting slow-slip events.

Laboratory and numerical investigations of kinetic interface sensitive tracers transport for immiscible two-phase flow porous media systems

NASA Astrophysics Data System (ADS)

Tatomir, Alexandru Bogdan A. C.; Sauter, Martin

2017-04-01

A number of theoretical approaches estimating the interfacial area between two fluid phases are available (Schaffer et al.,2013). Kinetic interface sensitive (KIS) tracers are used to describe the evolution of fluid-fluid interfaces advancing in two phase porous media systems (Tatomir et al., 2015). Initially developed to offer answers about the supercritical (sc)CO2 plume movement and the efficiency of trapping in geological carbon storage reservoirs, KIS tracers are tested in dynamic controlled laboratory conditions. N-octane and water, analogue to a scCO2 - brine system, are used. The KIS tracer is dissolved in n-octane, which is injected as the non-wetting phase in a fully water saturated porous media column. The porous system is made up of spherical glass beads with sizes of 100-250 μm. Subsequently, the KIS tracer follows a hydrolysis reaction over the n-octane - water interface resulting in an acid and phenol which are both water soluble. The fluid-fluid interfacial area is described numerically with the help of constitutive-relationships derived from the Brooks-Corey model. The specific interfacial area is determined numerically from pore scale calculations, or from different literature sources making use of pore network model calculations (Joekar-Niasar et al., 2008). This research describes the design of the laboratory setup and compares the break-through curves obtained with the forward model and in the laboratory experiment. Furthermore, first results are shown in the attempt to validate the immiscible two phase flow reactive transport numerical model with dynamic laboratory column experiments. Keywords: Fluid-fluid interfacial area, KIS tracers, model validation, CCS, geological storage of CO2

Particles at fluid-fluid interfaces: A new Navier-Stokes-Cahn-Hilliard surface- phase-field-crystal model.

PubMed

Aland, Sebastian; Lowengrub, John; Voigt, Axel

2012-10-01

Colloid particles that are partially wetted by two immiscible fluids can become confined to fluid-fluid interfaces. At sufficiently high volume fractions, the colloids may jam and the interface may crystallize. The fluids together with the interfacial colloids form an emulsion with interesting material properties and offer an important route to new soft materials. A promising approach to simulate these emulsions was presented in Aland et al. [Phys. Fluids 23, 062103 (2011)], where a Navier-Stokes-Cahn-Hilliard model for the macroscopic two-phase fluid system was combined with a surface phase-field-crystal model for the microscopic colloidal particles along the interface. Unfortunately this model leads to spurious velocities which require very fine spatial and temporal resolutions to accurately and stably simulate. In this paper we develop an improved Navier-Stokes-Cahn-Hilliard-surface phase-field-crystal model based on the principles of mass conservation and thermodynamic consistency. To validate our approach, we derive a sharp interface model and show agreement with the improved diffuse interface model. Using simple flow configurations, we show that the new model has much better properties and does not lead to spurious velocities. Finally, we demonstrate the solid-like behavior of the crystallized interface by simulating the fall of a solid ball through a colloid-laden multiphase fluid.

Ultrasonic fluid densitometer having liquid/wedge and gas/wedge interfaces

DOEpatents

Greenwood, Margaret S.

2000-01-01

The present invention is an ultrasonic liquid densitometer that uses a material wedge having two sections, one with a liquid/wedge interface and another with a gas/wedge interface. It is preferred that the wedge have an acoustic impedance that is near the acoustic impedance of the liquid, specifically less than a factor of 11 greater than the acoustic impedance of the liquid. Ultrasonic signals are internally reflected within the material wedge. Density of a liquid is determined by immersing the wedge into the liquid and measuring reflections of ultrasound at the liquid/wedge interface and at the gas/wedge interface.

Optical position sensor for determining the interface between a clear and an opaque fluid

DOEpatents

Weiss, Jonathan D [Albuquerque, NM

2006-05-23

An inexpensive, optical position sensor for measuring a position or length, x, along a one-dimensional curvilinear, coordinate system. The sensor can be used, for example, to determine the position of an interface between a clear and an opaque fluid (such as crude oil and water). In one embodiment, the sensor utilizes the principle of dual-fluorescence, where a primary fiber emits primary fluorescent light and a parallel secondary fiber collects a portion of the primary fluorescent light that is not blocked by the opaque fluid. This, in turn, excites secondary fluorescence in the secondary fiber at a longer wavelength. A light detector measures the intensity of secondary fluorescence emitted from an end of the secondary fiber, which is used to calculate the unknown position or length, x. Side-emitting fibers can be used in place of, or in addition to, fluorescent fibers. The all-optical sensor is attractive for applications involving flammable liquids.

A Study of Fluid Interface Configurations in Exploration Vehicle Propellant Tanks

NASA Technical Reports Server (NTRS)

Zimmerli, Gregory A.; Asipauskas, Marius; Chen, Yongkang; Weislogel, Mark M.

2010-01-01

The equilibrium shape and location of fluid interfaces in spacecraft propellant tanks while in low-gravity is of interest to system designers, but can be challenging to predict. The propellant position can affect many aspects of the spacecraft such as the spacecraft center of mass, response to thruster firing due to sloshing, liquid acquisition, propellant mass gauging, and thermal control systems. We use Surface Evolver, a fluid interface energy minimizing algorithm, to investigate theoretical equilibrium liquid-vapor interfaces for spacecraft propellant tanks similar to those that have been considered for NASA's new class of Exploration vehicles. The choice of tank design parameters we consider are derived from the NASA Exploration Systems Architecture Study report. The local acceleration vector employed in the computations is determined by estimating low-Earth orbit (LEO) atmospheric drag effects and centrifugal forces due to a fixed spacecraft orientation with respect to the Earth or Moon, and rotisserie-type spacecraft rotation. Propellant/vapor interface positions are computed for the Earth Departure Stage and Altair lunar lander descent and ascent stage tanks for propellant loads applicable to LEO and low-lunar orbit. In some of the cases investigated the vapor ullage bubble is located at the drain end of the tank, where propellant management device hardware is often located.

Tracking interface and common curve dynamics for two-fluid flow in porous media

DOE PAGES

Mcclure, James E.; Miller, Cass T.; Gray, W. G.; ...

2016-04-29

Pore-scale studies of multiphase flow in porous medium systems can be used to understand transport mechanisms and quantitatively determine closure relations that better incorporate microscale physics into macroscale models. Multiphase flow simulators constructed using the lattice Boltzmann method provide a means to conduct such studies, including both the equilibrium and dynamic aspects. Moving, storing, and analyzing the large state space presents a computational challenge when highly-resolved models are applied. We present an approach to simulate multiphase flow processes in which in-situ analysis is applied to track multiphase flow dynamics at high temporal resolution. We compute a comprehensive set of measuresmore » of the phase distributions and the system dynamics, which can be used to aid fundamental understanding and inform closure relations for macroscale models. The measures computed include microscale point representations and macroscale averages of fluid saturations, the pressure and velocity of the fluid phases, interfacial areas, interfacial curvatures, interface and common curve velocities, interfacial orientation tensors, phase velocities and the contact angle between the fluid-fluid interface and the solid surface. Test cases are studied to validate the approach and illustrate how measures of system state can be obtained and used to inform macroscopic theory.« less

Colloidal Particles at Fluid Interfaces and the Interface of Colloidal Fluids

NASA Astrophysics Data System (ADS)

McGorty, Ryan

Holographic microscopy is a unifying theme in the different projects discussed in this thesis. The technique allows one to observe microscopic objects, like colloids and droplets, in a three-dimensional (3D) volume. Unlike scanning 3D optical techniques, holography captures a sample's 3D information in a single image: the hologram. Therefore, one can capture 3D information at video frame rates. The price for such speed is paid in computation time. The 3D information must be extracted from the image by methods such as reconstruction or fitting the hologram to scattering calculations. Using holography, we observe a single colloidal particle approach, penetrate and then slowly equilibrate at an oil--water interface. Because the particle moves along the optical axis (z-axis) and perpendicular to the interface holography is used to determine its position. We are able to locate the particle's z-position to within a few nanometers with a time resolution below a millisecond. We find that the capillary force pulling the particle into the interface is not balanced by a hydrodynamic force. Rather, a larger-than-viscous dissipation associated with the three-phase contact-line slipping over the particle's surface results in equilibration on time scales orders of magnitude longer than the minute time scales over which our setup allows us to examine. A separate project discussed here also examines colloidal particles and fluid-fluid interfaces. But the fluids involved are composed of colloids. With a colloid and polymer water-based mixture we study the phase separation of the colloid-rich (or liquid) and colloid-poor (or gas) region. In comparison to the oil--water interface in the previously mentioned project, the interface between the colloidal liquid and gas phases has a surface tension nearly six orders of magnitude smaller. So interfacial fluctuations are observable under microscopy. We also use holographic microscopy to study this system but not to track particles with great time and spatial resolution. Rather, holography allows us to observe nucleation of the liquid phase occurring throughout our sample volume.

Capillary Flow Experiment in Node 2

NASA Image and Video Library

2013-06-15

Astronaut Karen Nyberg,Expedition 36 flight engineer,works on the Capillary Flow Experiment (CFE) Vane Gap-1 (VG-1) setup in the Node 2/Harmony. The CFE-2 vessel is used to observe fluid interface and critical wetting behavior in a cylindrical chamber with elliptic cross-section and an adjustable central perforated vane. The primary objective of the Vane Gap experiments is to determine equilibrium interface configurations and critical wetting conditions for interfaces between interior corners separated by a gap.

Fluid flow in solidifying monotectic alloys

NASA Technical Reports Server (NTRS)

Ecker, A.; Frazier, D. O.; Alexander, J. Iwan D.

1989-01-01

Use of a two-wavelength holographic technique results in a simultaneous determination of temperature and composition profiles during directional solidification in a system with a miscibility gap. The relationships among fluid flow, phase separation, and mass transport during the solidification of the monotectic alloy are discussed. The primary sources of fluid motion in this system are buoyancy and thermocapillary forces. These forces act together when phase separation results in the formation of droplets (this occurs at the solid-liquid interface and in the bulk melt). In the absence of phase separation, buoyancy results from density gradients related to temperature and compositional gradients in the single-phase bulk melt. The effects of buoyancy are especially evident in association with water- or ethanol-rich volumes created at the solid-liquid growth interface.

Linear Rayleigh-Taylor instability in an accelerated Newtonian fluid with finite width

NASA Astrophysics Data System (ADS)

Piriz, S. A.; Piriz, A. R.; Tahir, N. A.

2018-04-01

The linear theory of Rayleigh-Taylor instability is developed for the case of a viscous fluid layer accelerated by a semi-infinite viscous fluid, considering that the top interface is a free surface. Effects of the surface tensions at both interfaces are taken into account. When viscous effects dominate on surface tensions, an interplay of two mechanisms determines opposite behaviors of the instability growth rate with the thickness of the heavy layer for an Atwood number AT=1 and for sufficiently small values of AT. In the former case, viscosity is a less effective stabilizing mechanism for the thinnest layers. However, the finite thickness of the heavy layer enhances its viscous effects that, in general, prevail on the viscous effects of the semi-infinite medium.

Particles at fluid-fluid interfaces: A new Navier-Stokes-Cahn-Hilliard surface-phase-field-crystal model

PubMed Central

Aland, Sebastian; Lowengrub, John; Voigt, Axel

2013-01-01

Colloid particles that are partially wetted by two immiscible fluids can become confined to fluid-fluid interfaces. At sufficiently high volume fractions, the colloids may jam and the interface may crystallize. The fluids together with the interfacial colloids form an emulsion with interesting material properties and offer an important route to new soft materials. A promising approach to simulate these emulsions was presented in Aland et al. [Phys. Fluids 23, 062103 (2011)], where a Navier-Stokes-Cahn-Hilliard model for the macroscopic two-phase fluid system was combined with a surface phase-field-crystal model for the microscopic colloidal particles along the interface. Unfortunately this model leads to spurious velocities which require very fine spatial and temporal resolutions to accurately and stably simulate. In this paper we develop an improved Navier-Stokes-Cahn-Hilliard-surface phase-field-crystal model based on the principles of mass conservation and thermodynamic consistency. To validate our approach, we derive a sharp interface model and show agreement with the improved diffuse interface model. Using simple flow configurations, we show that the new model has much better properties and does not lead to spurious velocities. Finally, we demonstrate the solid-like behavior of the crystallized interface by simulating the fall of a solid ball through a colloid-laden multiphase fluid. PMID:23214691

Novel Shapes of Miscible Interfaces Observed

NASA Technical Reports Server (NTRS)

Balasubramaniam, Ramaswamy; Rashidnia, Nasser

2001-01-01

The dynamics of miscible displacements in a cylindrical tube are being investigated experimentally and numerically, with a view to understand the complex processes that occur, for example, in enhanced oil recovery, hydrology, and filtration. We have observed complex shapes of the interface between two liquids that mix with each other when the less viscous liquid is displaced by the more viscous one in a tube. A less viscous fluid that displaces a more viscous fluid is known to propagate in the form of a "finger," and a flight experiment proposed by Maxworthy et al. to investigate the miscible-interface dynamics is currently being developed by NASA. From the current theory of miscible displacements, which was developed for a porous medium satisfying Darcy's law, it can be shown that in the absence of gravity the interface between the fluids is destabilized and thus susceptible to fingering only when a more viscous fluid is displaced by a less viscous one. Therefore, if the interface is initially flat and the more viscous fluid displaces the less viscous fluid, the interface ought to be stable and remain flat. However, numerical simulations by Chen and Meiburg for such displacement in a cylindrical tube show that the interface is unstable and a finger of the more viscous fluid is indeed formed. Preliminary experiments performed at the NASA Glenn Research Center show that not only can fingering occur when the more viscous fluid displaces a less viscous one in a cylindrical tube, but also that under certain conditions the advancing finger achieves a sinuous or snakelike shape. These experiments were performed using silicone oils in a vertical pipette of small diameter. In the initial configuration, the more viscous fluid rested on top of the less viscous one, and the interface was nominally flat. A dye was added to the upper liquid for ease of observation of the interface between the fluids. The flow was initiated by draining the lower fluid from the bottom of the pipette, at speeds less than 0.1 mm/sec.

A level set method for determining critical curvatures for drainage and imbibition.

PubMed

Prodanović, Masa; Bryant, Steven L

2006-12-15

An accurate description of the mechanics of pore level displacement of immiscible fluids could significantly improve the predictions from pore network models of capillary pressure-saturation curves, interfacial areas and relative permeability in real porous media. If we assume quasi-static displacement, at constant pressure and surface tension, pore scale interfaces are modeled as constant mean curvature surfaces, which are not easy to calculate. Moreover, the extremely irregular geometry of natural porous media makes it difficult to evaluate surface curvature values and corresponding geometric configurations of two fluids. Finally, accounting for the topological changes of the interface, such as splitting or merging, is nontrivial. We apply the level set method for tracking and propagating interfaces in order to robustly handle topological changes and to obtain geometrically correct interfaces. We describe a simple but robust model for determining critical curvatures for throat drainage and pore imbibition. The model is set up for quasi-static displacements but it nevertheless captures both reversible and irreversible behavior (Haines jump, pore body imbibition). The pore scale grain boundary conditions are extracted from model porous media and from imaged geometries in real rocks. The method gives quantitative agreement with measurements and with other theories and computational approaches.

Fluid and mass transfer at subduction interfaces-The field metamorphic record

NASA Astrophysics Data System (ADS)

Bebout, Gray E.; Penniston-Dorland, Sarah C.

2016-01-01

The interface between subducting oceanic slabs and the hanging wall is a structurally and lithologically complex region. Chemically disparate lithologies (sedimentary, mafic and ultramafic rocks) and mechanical mixtures thereof show heterogeneous deformation. These lithologies are tectonically juxtaposed at mm to km scales, particularly in more intensely sheared regions (mélange zones, which act as fluid channelways). This juxtaposition, commonly in the presence of a mobile fluid phase, offers up huge potential for mass transfer and related metasomatic alteration. Fluids in this setting appear capable of transporting mass over scales of kms, along flow paths with widely varying geometries and P-T trajectories. Current models of arc magmatism require km-scale migration of fluids from the interface into mantle wedge magma source regions and implicit in these models is the transport of any fluids generated in the subducting slab along and ultimately through the subduction interface. Field and geochemical studies of high- and ultrahigh-pressure metamorphic rocks elucidate the sources and compositions of fluids in subduction interfaces and the interplay between deformation and fluid and mass transfer in this region. Recent geophysical studies of the subduction interface - its thickness, mineralogy, density, and H2O content - indicate that its rheology greatly influences the ways in which the subducting plate is coupled with the hanging wall. Field investigation of the magnitude and styles of fluid-rock interaction in metamorphic rocks representing "seismogenic zone" depths (and greater) yields insight regarding the roles of fluids and elevated fluid pore pressure in the weakening of plate interface rocks and the deformation leading to seismic events. From a geochemical perspective, the plate interface contributes to shaping the "slab signature" observed in studies of the composition of arc volcanic rocks. Understanding the production of fluids with hybridized chemical/isotopic compositions could improve models aimed at identifying the relative contributions of end-member rock reservoirs through analyses of arc volcanic rocks. Production of rocks rich in hydrous minerals, along the subduction interface, could stabilize H2O to great depths in subduction zones and influence deep-Earth H2O cycling. Enhancement of decarbonation reactions and dissolution by fluid infiltration facilitated by deformation at the interface could influence the C flux from subducting slabs entering the sub-arc mantle wedge and various forearc reservoirs. In this paper, we consider records of fluid and mass transfer at localities representing various depths and structural expressions of evolving paleo-interfaces, ranging widely in structural character, the rock types involved (ultramafic, mafic, sedimentary), and the rheology of these rocks. We stress commonalities in styles of fluid and mass transfer as related to deformation style and the associated geometries of fluid mobility at subduction interfaces. Variations in thermal structure among individual margins will lead to significant differences in not only the rheology of subducting rocks, and thus seismicity, but also the profiles of devolatilization and melting, through the forearc and subarc, and the element/mineral solubilities in any aqueous fluids or silicate melts that are produced. One key factor in considering fluid and mass transfer in the subduction interface, influencing C cycling and other chemical additions to arcs, is the uncertain degree to which sub-crustal ultramafic rocks in downgoing slabs are hydrated and release H2O-rich fluids.

Conductivity measurements on H 2O-bearing CO 2-rich fluids

DOE PAGES

Capobianco, Ryan M.; Miroslaw S. Gruszkiewicz; Bodnar, Robert J.; ...

2014-09-10

Recent studies report rapid corrosion of metals and carbonation of minerals in contact with carbon dioxide containing trace amounts of dissolved water. One explanation for this behavior is that addition of small amounts of H 2O to CO 2 leads to significant ionization within the fluid, thus promoting reactions at the fluid-solid interface analogous to corrosion associated with aqueous fluids. The extent of ionization in the bulk CO 2 fluid was determined using a flow-through conductivity cell capable of detecting very low conductivities. Experiments were conducted from 298 to 473 K and 7.39 to 20 MPa with H 2O concentrationsmore » up to ~1600 ppmw (xH 2O ≈ 3.9 x 10 -3), corresponding to the H 2O solubility limit in liquid CO 2 at ambient temperature. All solutions showed conductivities <10 nS/cm, indicating that the solutions were essentially ion-free. Furthermore, this observation suggests that the observed corrosion and carbonation reactions are not the result of ionization in CO 2-rich bulk phase, but does not preclude ionization in the fluid at the fluid-solid interface.« less

The Impact of Solid Surface Features on Fluid-Fluid Interface Configuration

NASA Astrophysics Data System (ADS)

Araujo, J. B.; Brusseau, M. L. L.

2017-12-01

Pore-scale fluid processes in geological media are critical for a broad range of applications such as radioactive waste disposal, carbon sequestration, soil moisture distribution, subsurface pollution, land stability, and oil and gas recovery. The continued improvement of high-resolution image acquisition and processing have provided a means to test the usefulness of theoretical models developed to simulate pore-scale fluid processes, through the direct quantification of interfaces. High-resolution synchrotron X-ray microtomography is used in combination with advanced visualization tools to characterize fluid distributions in natural geologic media. The studies revealed the presence of fluid-fluid interface associated with macroscopic features on the surfaces of the solids such as pits and crevices. These features and respective fluid interfaces, which are not included in current theoretical or computational models, may have a significant impact on accurate simulation and understanding of multi-phase flow, energy, heat and mass transfer processes.

Fluid mechanics in crystal growth - The 1982 Freeman scholar lecture

NASA Technical Reports Server (NTRS)

Ostrach, S.

1983-01-01

An attempt is made to unify the current state of knowledge in crystal growth techniques and fluid mechanics. After identifying important fluid dynamic problems for such representative crystal growth processes as closed tube vapor transport, open reactor vapor deposition, and the Czochralski and floating zone melt growth techniques, research results obtained to date are presented. It is noted that the major effort to date has been directed to the description of the nature and extent of bulk transport under realistic conditions, where bulk flow determines the heat and solute transport which strongly influence the temperature and concentration fields in the vicinity of the growth interface. Proper treatment of near field, or interface, problems cannot be given until the far field, or global flow, involved in a given crystal growth technique has been adequately described.

Understanding deviations in lithographic patterns near interfaces: Characterization of bottom anti-reflective coatings (BARC) and the BARC resist interface

NASA Astrophysics Data System (ADS)

Lenhart, Joseph L.; Fischer, Daniel; Sambasivan, Sharadha; Lin, Eric K.; Wu, Wen-Li; Guerrero, Douglas J.; Wang, Yubao; Puligadda, Rama

2007-02-01

Interactions between a bottom anti-reflective coating (BARC) and a photoresist can critically impact lithographic patterns. For example, a lithographic pattern can shrink or spread near a BARC interface, a process called undercutting or footing respectively, due to incompatibility between the two materials. Experiments were conducted on two industrial BARC coatings in an effort to determine the impact of BARC surface chemistry on the footing and undercutting phenomena. The BARC coatings were characterized by near edge X-ray absorption fine structure (NEXAFS), contact angle measurements, and neutron and X-ray reflectivity. Contact angle measurement using a variety of fluids showed that the fluid contact angles were independent of the type of BARC coating or the BARC processing temperature. NEXAFS measurements showed that the surface chemistry of each BARC was also independent of the processing temperature. These results suggest that acid-base interactions at the BARC-resist interface are not the cause of the footing-undercutting phenomena encountered in lithographic patterns.

How are soap bubbles blown? Fluid dynamics of soap bubble blowing

NASA Astrophysics Data System (ADS)

Davidson, John; Lambert, Lori; Sherman, Erica; Wei, Timothy; Ryu, Sangjin

2013-11-01

Soap bubbles are a common interfacial fluid dynamics phenomenon having a long history of delighting not only children and artists but also scientists. In contrast to the dynamics of liquid droplets in gas and gas bubbles in liquid, the dynamics of soap bubbles has not been well documented. This is possibly because studying soap bubbles is more challenging due to there existing two gas-liquid interfaces. Having the thin-film interface seems to alter the characteristics of the bubble/drop creation process since the interface has limiting factors such as thickness. Thus, the main objective of this study is to determine how the thin-film interface differentiates soap bubbles from gas bubbles and liquid drops. To investigate the creation process of soap bubbles, we constructed an experimental model consisting of air jet flow and a soap film, which consistently replicates the conditions that a human produces when blowing soap bubbles, and examined the interaction between the jet and the soap film using the high-speed videography and the particle image velocimetry.

Drainage Asperities on Subduction Megathrusts

NASA Astrophysics Data System (ADS)

Sibson, R. H.

2012-12-01

Geophysical observations coupled with force-balance analyses suggest that the seismogenic shear zone interface of subduction megathrusts is generally fluid-overpressured to near-lithostatic values (λv = Pf/σv > 0.9) below the forearc hanging-wall, strongly modulating the profile of frictional shear resistance. Fluid sources include the accretionary prism at shallow levels and, with increasing depth, metamorphic dehydration of material entrained within the subduction shear zone together with progressive metamorphism of oceanic crust in the downgoing slab. Solution transfer in fine-grained material contained within the deeper subduction shear zone (150 < T < 350°C) likely contributes to hydrothermal sealing of fractures. A dramatic difference may therefore exist between low prefailure permeability surrounding the megathrust and high postfailure fracture permeability along the rupture zone and adjacent areas of aftershock activity. Observed postseismic changes in the velocity structure of the fore-arc hanging-wall led Husen and Kissling (2001) to propose massive fluid loss across the subduction interface following the 1995 Antofagasta, Chile, Mw8.0 megathrust rupture. Such trans-megathrust discharges represent a variant of 'fault-valve' action in which the subduction interface itself acts as a seal trapping overpressured fluids derived from metamorphic dehydration beneath. In low-permeability assemblages the maximum sustainable overpressure is limited by the activation or reactivation of brittle faults and fractures under the prevailing stress state. Highest overpressures tend to occur at low differential stress in compressional stress regimes. Loci for fluid discharge are likely determined by stress heterogeneities along the megathrust (e.g. the hangingwall of the rupture at its downdip termination). Discharge sites may be defined by swarm aftershocks defining activated fault-fracture meshes. However, fluid loss across a subduction interface will be enhanced when the stress-state in the forearc hanging-wall switches from compressional reverse-slip faulting before failure to extensional normal-slip faulting postfailure, as occurred during the 2011 Mw9.0 Tohoku megathrust rupture. Mean stress and fault-normal stress then change from being greater than vertical stress prefailure, to less than vertical stress postfailure. Postfailure reductions in overpressure are expected from a combination of poroelastic effects and fluid loss through fault-fracture networks, enhancing vertical permeability. Mineralised fault-fracture meshes in exhumed fore-arc assemblages (e.g. the Alaska-Juneau Au-quartz vein swarm) testify to the episodic discharge of substantial volumes of hydrothermal fluid (< tens of km3). Localized drainage from the subduction interface shear zone increases frictional strength significantly, giving rise to a postfailure strength asperities. Anticipated strength increases from such fluid discharge depends on the magnitude of the drop in overpressure but are potentially large (< hundreds of MPa). Time to the subsequent failure is then governed by reaccumulation of fluid overpressure as well as shear stress along the subduction interface.

Linear stability of an active fluid interface

NASA Astrophysics Data System (ADS)

Nagilla, Amarender; Prabhakar, Ranganathan; Jadhav, Sameer

2018-02-01

Motivated by studies suggesting that the patterns exhibited by the collectively expanding fronts of thin cells during the closing of a wound [S. Mark et al., "Physical model of the dynamic instability in an expanding cell culture," Biophys. J. 98(3), 361-370 (2010)] and the shapes of single cells crawling on surfaces [A. C. Callan-Jones et al., "Viscous-fingering-like instability of cell fragments," Phys. Rev. Lett. 100(25), 258106 (2008)] are due to fingering instabilities, we investigate the stability of actively driven interfaces under the Hele-Shaw confinement. An initially radial interface between a pair of viscous fluids is driven by active agents. Surface tension and bending rigidity resist the deformation of the interface. A point source at the origin and a distributed source are also included to model the effects of injection or suction and growth or depletion, respectively. Linear stability analysis reveals that for any given initial radius of the interface, there are two key dimensionless driving rates that determine interfacial stability. We discuss stability regimes in a state space of these parameters and their implications for biological systems. An interesting finding is that an actively mobile interface is susceptible to the fingering instability irrespective of viscosity contrast.

A fictitious domain method for fluid/solid coupling applied to the lithosphere/asthenosphere interaction.

NASA Astrophysics Data System (ADS)

Cerpa, Nestor; Hassani, Riad; Gerbault, Muriel

2014-05-01

A large variety of geodynamical problems can be viewed as a solid/fluid interaction problem coupling two bodies with different physics. In particular the lithosphere/asthenosphere mechanical interaction in subduction zones belongs to this kind of problem, where the solid lithosphere is embedded in the asthenospheric viscous fluid. In many fields (Industry, Civil Engineering,etc.), in which deformations of solid and fluid are "small", numerical modelers consider the exact discretization of both domains and fit as well as possible the shape of the interface between the two domains, solving the discretized physic problems by the Finite Element Method (FEM). Although, in a context of subduction, the lithosphere is submitted to large deformation, and can evolve into a complex geometry, thus leading to important deformation of the surrounding asthenosphere. To alleviate the precise meshing of complex geometries, numerical modelers have developed non-matching interface methods called Fictitious Domain Methods (FDM). The main idea of these methods is to extend the initial problem to a bigger (and simpler) domain. In our version of FDM, we determine the forces at the immersed solid boundary required to minimize (at the least square sense) the difference between fluid and solid velocities at this interface. This method is first-order accurate and the stability depends on the ratio between the fluid background mesh size and the interface discretization. We present the formulation and provide benchmarks and examples showing the potential of the method : 1) A comparison with an analytical solution of a viscous flow around a rigid body. 2) An experiment of a rigid sphere sinking in a viscous fluid (in two and three dimensional cases). 3) A comparison with an analog subduction experiment. Another presentation aims at describing the geodynamical application of this method to Andean subduction dynamics, studying cyclic slab folding on the 660 km discontinuity, and its relationship with flat subduction.

Toward direct pore-scale modeling of three-phase displacements

NASA Astrophysics Data System (ADS)

Mohammadmoradi, Peyman; Kantzas, Apostolos

2017-12-01

A stable spreading film between water and gas can extract a significant amount of bypassed non-aqueous phase liquid (NAPL) through immiscible three-phase gas/water injection cycles. In this study, the pore-scale displacement mechanisms by which NAPL is mobilized are incorporated into a three-dimensional pore morphology-based model under water-wet and capillary equilibrium conditions. The approach is pixel-based and the sequence of invasions is determined by the fluids' connectivity and the threshold capillary pressure of the advancing interfaces. In addition to the determination of three-phase spatial saturation profiles, residuals, and capillary pressure curves, dynamic finite element simulations are utilized to predict the effective permeabilities of the rock microtomographic images as reasonable representations of the geological formations under study. All the influential features during immiscible fluid flow in pore-level domains including wetting and spreading films, saturation hysteresis, capillary trapping, connectivity, and interface development strategies are taken into account. The capabilities of the model are demonstrated by the successful prediction of saturation functions for Berea sandstone and the accurate reconstruction of three-phase fluid occupancies through a micromodel.

Equilibrium fluid interface behavior under low- and zero-gravity conditions

NASA Technical Reports Server (NTRS)

Concus, Paul; Finn, Robert

1994-01-01

We describe here some of our recent mathematical work, which forms a basis for the Interface Configuration Experiment scheduled for USML-2. The work relates to the design of apparatus that exploits microgravity conditions for accurate determination of contact angle. The underlying motivation for the procedures rests on a discontinuous dependence of the capillary free surface interface S on the contact angle gamma, in a cylindrical capillary tube whose section (base) omega contains a protruding corner with opening angle 2 alpha. Specifically, in a gravity-free environment, omega can be chosen so that, for all sufficiently large fluid volume, the height of S is uniquely determined as a (single-valued) function mu(x,y) entirely covering the base; the height mu is bounded over omega uniformly in gamma throughout the range absolute value of (gamma -(pion/2)) less than or equal to alpha, while for absolute value of (gamma - (pion/2)) greater than alpha fluid will necessarily move to the corner and uncover the base, rising to infinity (or falling to negative infinity) at the vertex, regardless of volume. We mention here only that procedures based on the phenomenon promise excellent accuracy when gamma is close pion/2 but may be subject to experimental error when gamma is close to zero (orpion), as the 'singular' part of the domain over which the fluid accumulates (or disappears) when a critical angle gamma theta is crossed then becomes very small and may be difficult to observe. We ignore the trivial case gamma is equal to pion/2 (planar free surface), to simplify the discussion.

Transport properties at fluids interfaces: a molecular study for a macroscopic modelling

NASA Astrophysics Data System (ADS)

Russo, Antonio; Morciano, Matteo; Sibley, David N.; Nold, Andreas; Goddard, Benjamin D.; Asinari, Pietro; Kalliadasis, Serafim

2017-11-01

Rapid developments in the field of micro- and nano-fluidics require detailed analysis of the properties of matter at the molecular level. But despite numerous works in the literature, appropriate macroscopic relations able to integrate a microscopic description of fluid and soft matter properties at liquid-vapour and multi-fluid interfaces are missing. As a consequence, studies on interfacial phenomena and micro-device designs often rely on oversimplified assumptions, e.g. that the viscosities can be considered constant across interfaces. In our work, we present non-equilibrium MD simulations to scrutinise efficiently and systematically, through the tools of statistical mechanics, the anisotropic properties of fluids, namely density variations, stress tensor, and shear viscosity, at the fluid interfaces between liquid and vapour and between two partially miscible fluids. Our analysis has led to the formulation of a general relation between shear viscosity and density variations validated for a wide spectrum of interfacial fluid problems. In addition, it provides a rational description of other interfacial quantities of interest, including surface tension and its origins, and more generally, it offers valuable insight of molecular transport phenomena at interfaces.

Settling of a sphere through a fluid-fluid interface: influence of the Reynolds number

NASA Astrophysics Data System (ADS)

Pierson, Jean-Lou; Magnaudet, Jacques

2015-11-01

When a particle sediments through a horizontal fluid-fluid interface (a situation frequently encountered in oceanography as well as in coating processes), it often tows a tail of the upper fluid into the lower one. This feature is observed in both inertia- and viscosity-dominated regimes. Nevertheless the tail evolution and the particle motion are found to highly depend on the ratio of the two effects, i.e. on the Reynolds number. In this work we study numerically the settling of a sphere through a horizontal fluid-fluid interface using an Immersed Boundary Method combined with a Volume of Fluid approach. To get some more insight into the underlying physical mechanisms, we combine this computational approach with a semi-analytical description based on the concept of Darwin ''drift'' which allows us to predict the interface evolution, hence the thickness of the film encapsulating the sphere, in the two limits of Stokes flow and potential flow. This work was funded by DGA whose financial support is greatly appreciated.

Universality Results for Multi-Layer Hele-Shaw and Porous Media Flows

NASA Astrophysics Data System (ADS)

Daripa, Prabir

2012-11-01

Saffman-Taylor instability is a well known viscosity driven instability of an interface. Motivated by a need to understand the effect of various injection policies currently in practice for chemical enhanced oil recovery, we study linear stability of displacement processes in a Hele-Shaw cell involving injection of an arbitrary number of immiscible fluid phases in succession. This is a problem involving many interfaces. Universal stability results have been obtained for this multi-layer (multi-region) flow in the sense that the results hold with arbitrary number of interfaces. These stability results have been applied to design injection policies that are considerably less unstable than the pure Saffman-Taylor case. In particular, we determine specific values of the viscosity of the fluid layers corresponding to smallest unstable band. Moreover, we discuss universal selection principle of optimal viscous profiles. The talk is based on following papers. Qatar National Fund (a member of the Qatar Foundation).

Using evaporation to control capillary instabilities in micro-systems.

PubMed

Ledesma-Aguilar, Rodrigo; Laghezza, Gianluca; Yeomans, Julia M; Vella, Dominic

2017-12-06

The instabilities of fluid interfaces represent both a limitation and an opportunity for the fabrication of small-scale devices. Just as non-uniform capillary pressures can destroy micro-electrical mechanical systems (MEMS), so they can guide the assembly of novel solid and fluid structures. In many such applications the interface appears during an evaporation process and is therefore only present temporarily. It is commonly assumed that this evaporation simply guides the interface through a sequence of equilibrium configurations, and that the rate of evaporation only sets the timescale of this sequence. Here, we use Lattice-Boltzmann simulations and a theoretical analysis to show that, in fact, the rate of evaporation can be a factor in determining the onset and form of dynamical capillary instabilities. Our results shed light on the role of evaporation in previous experiments, and open the possibility of exploiting diffusive mass transfer to directly control capillary flows in MEMS applications.

Mapping two-dimensional polar active fluids to two-dimensional soap and one-dimensional sandblasting

NASA Astrophysics Data System (ADS)

Chen, Leiming; Lee, Chiu Fan; Toner, John

2016-07-01

Active fluids and growing interfaces are two well-studied but very different non-equilibrium systems. Each exhibits non-equilibrium behaviour distinct from that of their equilibrium counterparts. Here we demonstrate a surprising connection between these two: the ordered phase of incompressible polar active fluids in two spatial dimensions without momentum conservation, and growing one-dimensional interfaces (that is, the 1+1-dimensional Kardar-Parisi-Zhang equation), in fact belong to the same universality class. This universality class also includes two equilibrium systems: two-dimensional smectic liquid crystals, and a peculiar kind of constrained two-dimensional ferromagnet. We use these connections to show that two-dimensional incompressible flocks are robust against fluctuations, and exhibit universal long-ranged, anisotropic spatio-temporal correlations of those fluctuations. We also thereby determine the exact values of the anisotropy exponent ζ and the roughness exponents χx,y that characterize these correlations.

Mapping two-dimensional polar active fluids to two-dimensional soap and one-dimensional sandblasting.

PubMed

Chen, Leiming; Lee, Chiu Fan; Toner, John

2016-07-25

Active fluids and growing interfaces are two well-studied but very different non-equilibrium systems. Each exhibits non-equilibrium behaviour distinct from that of their equilibrium counterparts. Here we demonstrate a surprising connection between these two: the ordered phase of incompressible polar active fluids in two spatial dimensions without momentum conservation, and growing one-dimensional interfaces (that is, the 1+1-dimensional Kardar-Parisi-Zhang equation), in fact belong to the same universality class. This universality class also includes two equilibrium systems: two-dimensional smectic liquid crystals, and a peculiar kind of constrained two-dimensional ferromagnet. We use these connections to show that two-dimensional incompressible flocks are robust against fluctuations, and exhibit universal long-ranged, anisotropic spatio-temporal correlations of those fluctuations. We also thereby determine the exact values of the anisotropy exponent ζ and the roughness exponents χx,y that characterize these correlations.

The development of an intelligent interface to a computational fluid dynamics flow-solver code

NASA Technical Reports Server (NTRS)

Williams, Anthony D.

1988-01-01

Researchers at NASA Lewis are currently developing an 'intelligent' interface to aid in the development and use of large, computational fluid dynamics flow-solver codes for studying the internal fluid behavior of aerospace propulsion systems. This paper discusses the requirements, design, and implementation of an intelligent interface to Proteus, a general purpose, 3-D, Navier-Stokes flow solver. The interface is called PROTAIS to denote its introduction of artificial intelligence (AI) concepts to the Proteus code.

The development of an intelligent interface to a computational fluid dynamics flow-solver code

NASA Technical Reports Server (NTRS)

Williams, Anthony D.

1988-01-01

Researchers at NASA Lewis are currently developing an 'intelligent' interface to aid in the development and use of large, computational fluid dynamics flow-solver codes for studying the internal fluid behavior of aerospace propulsion systems. This paper discusses the requirements, design, and implementation of an intelligent interface to Proteus, a general purpose, three-dimensional, Navier-Stokes flow solver. The interface is called PROTAIS to denote its introduction of artificial intelligence (AI) concepts to the Proteus code.

Diffuse-Interface Methods in Fluid Mechanics

NASA Technical Reports Server (NTRS)

Anderson, D. M.; McFadden, G. B.; Wheeler, A. A.

1997-01-01

The authors review the development of diffuse-interface models of hydrodynamics and their application to a wide variety of interfacial phenomena. The authors discuss the issues involved in formulating diffuse-interface models for single-component and binary fluids. Recent applications and computations using these models are discussed in each case. Further, the authors address issues including sharp-interface analyses that relate these models to the classical free-boundary problem, related computational approaches to describe interfacial phenomena, and related approaches describing fully-miscible fluids.

4D synchrotron X-ray imaging to understand porosity development in shales during exposure to hydraulic fracturing fluid

NASA Astrophysics Data System (ADS)

Kiss, A. M.; Bargar, J.; Kohli, A. H.; Harrison, A. L.; Jew, A. D.; Lim, J. H.; Liu, Y.; Maher, K.; Zoback, M. D.; Brown, G. E.

2016-12-01

Unconventional (shale) reservoirs have emerged as the most important source of petroleum resources in the United States and represent a two-fold decrease in greenhouse gas emissions compared to coal. Despite recent progress, hydraulic fracturing operations present substantial technical, economic, and environmental challenges, including inefficient recovery, wastewater production and disposal, contaminant and greenhouse gas pollution, and induced seismicity. A relatively unexplored facet of hydraulic fracturing operations is the fluid-rock interface, where hydraulic fracturing fluid (HFF) contacts shale along faults and fractures. Widely used, water-based fracturing fluids contain oxidants and acid, which react strongly with shale minerals. Consequently, fluid injection and soaking induces a host of fluid-rock interactions, most notably the dissolution of carbonates and sulfides, producing enhanced or "secondary" porosity networks, as well as mineral precipitation. The competition between these mechanisms determines how HFF affects reactive surface area and permeability of the shale matrix. The resultant microstructural and chemical changes may also create capillary barriers that can trap hydrocarbons and water. A mechanistic understanding of the microstructure and chemistry of the shale-HFF interface is needed to design new methodologies and fracturing fluids. Shales were imaged using synchrotron micro-X-ray computed tomography before, during, and after exposure to HFF to characterize changes to the initial 3D structure. CT reconstructions reveal how the secondary porosity networks advance into the shale matrix. Shale samples span a range of lithologies from siliceous to calcareous to organic-rich. By testing shales of different lithologies, we have obtained insights into the mineralogic controls on secondary pore network development and the morphologies at the shale-HFF interface and the ultimate composition of produced water from different facies. These results show that mineral texture is a major control over secondary porosity network morphology.

Systems and methods for separating particles and/or substances from a sample fluid

DOEpatents

Mariella, Jr., Raymond P.; Dougherty, George M.; Dzenitis, John M.; Miles, Robin R.; Clague, David S.

2016-11-01

Systems and methods for separating particles and/or toxins from a sample fluid. A method according to one embodiment comprises simultaneously passing a sample fluid and a buffer fluid through a chamber such that a fluidic interface is formed between the sample fluid and the buffer fluid as the fluids pass through the chamber, the sample fluid having particles of interest therein; applying a force to the fluids for urging the particles of interest to pass through the interface into the buffer fluid; and substantially separating the buffer fluid from the sample fluid.

Adsorption of PFOA at the Air-Water Interface during Transport in Unsaturated Porous Media.

PubMed

Lyu, Ying; Brusseau, Mark L; Chen, Wei; Yan, Ni; Fu, Xiaori; Lin, Xueyu

2018-06-26

Miscible-displacement experiments are conducted with perfluorooctanoic acid (PFOA) to determine the contribution of adsorption at the air-water interface to retention during transport in water-unsaturated porous media. Column experiments were conducted with two sands of different diameter at different PFOA input concentrations, water saturations, and pore-water velocities to evaluate the impact of system variables on retardation. The breakthrough curves for unsaturated conditions exhibited greater retardation than those obtained for saturated conditions, demonstrating the significant impact of air-water interfacial adsorption on PFOA retention. Retardation was greater for lower water saturations and smaller grain diameter, consistent with the impact of system conditions on the magnitude of air-water interfacial area in porous media. Retardation was greater for lower input concentrations of PFOA for a given water saturation, consistent with the nonlinear nature of surfactant fluid-fluid interfacial adsorption. Retardation factors predicted using independently determined parameter values compared very well to the measured values. The results showed that adsorption at the air-water interface is a significant source of retention for PFOA, contributing approximately 50-75% of total retention, for the test systems. The significant magnitude of air-water interfacial adsorption measured in this work has ramifications for accurate determination of PFAS migration potential in vadose zones.

A mixed-penalty biphasic finite element formulation incorporating viscous fluids and material interfaces.

PubMed

Chan, B; Donzelli, P S; Spilker, R L

2000-06-01

The fluid viscosity term of the fluid phase constitutive equation and the interface boundary conditions between biphasic, solid and fluid domains have been incorporated into a mixed-penalty finite element formulation of the linear biphasic theory for hydrated soft tissue. The finite element code can now model a single-phase viscous incompressible fluid, or a single-phase elastic solid, as limiting cases of a biphasic material. Interface boundary conditions allow the solution of problems involving combinations of biphasic, fluid and solid regions. To incorporate these conditions, the volume-weighted mixture velocity is introduced as a degree of freedom at interface nodes so that the kinematic continuity conditions are satisfied by conventional finite element assembly techniques. Results comparing our numerical method with an independent, analytic solution for the problem of Couette flow over rigid and deformable porous biphasic layers show that the finite element code accurately predicts the viscous fluid flows and deformation in the porous biphasic region. Thus, the analysis can be used to model the interface between synovial fluid and articular cartilage in diarthrodial joints. This is an important step toward modeling and understanding the mechanisms of joint lubrication and another step toward fully modeling the in vivo behavior of a diarthrodial joint.

Pressurized-Flat-Interface Heat Exchanger

NASA Technical Reports Server (NTRS)

Voss, F. E.; Howell, H. R.; Winkler, R. V.

1990-01-01

High thermal conductance obtained without leakage between loops. Heat-exchanger interface enables efficient transfer of heat between two working fluids without allowing fluids to intermingle. Interface thin, flat, and easy to integrate into thermal system. Possible application in chemical or pharmaceutical manufacturing when even trace contamination of process stream with water or other coolant ruins product. Reduces costs when highly corrosive fluids must be cooled or heated.

Nano- and microparticles at fluid and biological interfaces.

PubMed

Dasgupta, S; Auth, T; Gompper, G

2017-09-20

Systems with interfaces are abundant in both technological applications and biology. While a fluid interface separates two fluids, membranes separate the inside of vesicles from the outside, the interior of biological cells from the environment, and compartmentalize cells into organelles. The physical properties of interfaces are characterized by interface tension, those of membranes are characterized by bending and stretching elasticity. Amphiphilic molecules like surfactants that are added to a system with two immiscible fluids decrease the interface tension and induce a bending rigidity. Lipid bilayer membranes of vesicles can be stretched or compressed by osmotic pressure; in biological cells, also the presence of a cytoskeleton can induce membrane tension. If the thickness of the interface or the membrane is small compared with its lateral extension, both can be described using two-dimensional mathematical surfaces embedded in three-dimensional space. We review recent work on the interaction of particles with interfaces and membranes. This can be micrometer-sized particles at interfaces that stabilise emulsions or form colloidosomes, as well as typically nanometer-sized particles at membranes, such as viruses, parasites, and engineered drug delivery systems. In both cases, we first discuss the interaction of single particles with interfaces and membranes, e.g. particles in external fields, non-spherical particles, and particles at curved interfaces, followed by interface-mediated interaction between two particles, many-particle interactions, interface and membrane curvature-induced phenomena, and applications.

Nano- and microparticles at fluid and biological interfaces

NASA Astrophysics Data System (ADS)

Dasgupta, S.; Auth, T.; Gompper, G.

2017-09-01

Systems with interfaces are abundant in both technological applications and biology. While a fluid interface separates two fluids, membranes separate the inside of vesicles from the outside, the interior of biological cells from the environment, and compartmentalize cells into organelles. The physical properties of interfaces are characterized by interface tension, those of membranes are characterized by bending and stretching elasticity. Amphiphilic molecules like surfactants that are added to a system with two immiscible fluids decrease the interface tension and induce a bending rigidity. Lipid bilayer membranes of vesicles can be stretched or compressed by osmotic pressure; in biological cells, also the presence of a cytoskeleton can induce membrane tension. If the thickness of the interface or the membrane is small compared with its lateral extension, both can be described using two-dimensional mathematical surfaces embedded in three-dimensional space. We review recent work on the interaction of particles with interfaces and membranes. This can be micrometer-sized particles at interfaces that stabilise emulsions or form colloidosomes, as well as typically nanometer-sized particles at membranes, such as viruses, parasites, and engineered drug delivery systems. In both cases, we first discuss the interaction of single particles with interfaces and membranes, e.g. particles in external fields, non-spherical particles, and particles at curved interfaces, followed by interface-mediated interaction between two particles, many-particle interactions, interface and membrane curvature-induced phenomena, and applications.

Interfacial gauge methods for incompressible fluid dynamics

PubMed Central

Saye, Robert

2016-01-01

Designing numerical methods for incompressible fluid flow involving moving interfaces, for example, in the computational modeling of bubble dynamics, swimming organisms, or surface waves, presents challenges due to the coupling of interfacial forces with incompressibility constraints. A class of methods, denoted interfacial gauge methods, is introduced for computing solutions to the corresponding incompressible Navier-Stokes equations. These methods use a type of “gauge freedom” to reduce the numerical coupling between fluid velocity, pressure, and interface position, allowing high-order accurate numerical methods to be developed more easily. Making use of an implicit mesh discontinuous Galerkin framework, developed in tandem with this work, high-order results are demonstrated, including surface tension dynamics in which fluid velocity, pressure, and interface geometry are computed with fourth-order spatial accuracy in the maximum norm. Applications are demonstrated with two-phase fluid flow displaying fine-scaled capillary wave dynamics, rigid body fluid-structure interaction, and a fluid-jet free surface flow problem exhibiting vortex shedding induced by a type of Plateau-Rayleigh instability. The developed methods can be generalized to other types of interfacial flow and facilitate precise computation of complex fluid interface phenomena. PMID:27386567

Locking of the Chile subduction zone controlled by fluid pressure before the 2010 earthquake

NASA Astrophysics Data System (ADS)

Moreno, Marcos; Haberland, Christian; Oncken, Onno; Rietbrock, Andreas; Angiboust, Samuel; Heidbach, Oliver

2014-04-01

Constraints on the potential size and recurrence time of strong subduction-zone earthquakes come from the degree of locking between the down-going and overriding plates, in the period between large earthquakes. In many cases, this interseismic locking degree correlates with slip during large earthquakes or is attributed to variations in fluid content at the plate interface. Here we use geodetic and seismological data to explore the links between pore-fluid pressure and locking patterns at the subduction interface ruptured during the magnitude 8.8 Chile earthquake in 2010. High-resolution three-dimensional seismic tomography reveals variations in the ratio of seismic P- to S-wave velocities (Vp/Vs) along the length of the subduction-zone interface. High Vp/Vs domains, interpreted as zones of elevated pore-fluid pressure, correlate spatially with parts of the plate interface that are poorly locked and slip aseismically. In contrast, low Vp/Vs domains, interpreted as zones of lower pore-fluid pressure, correlate with locked parts of the plate interface, where unstable slip and earthquakes occur. Variations in pore-fluid pressure are caused by the subduction and dehydration of a hydrothermally altered oceanic fracture zone. We conclude that variations in pore-fluid pressure at the plate interface control the degree of interseismic locking and therefore the slip distribution of large earthquake ruptures.

Rayleigh-Taylor instability at spherical interfaces between viscous fluids: Fluid/vacuum interface

DOE PAGES

Terrones, Guillermo; Carrara, Mark D.

2015-05-01

For a spherical interface of radius R separating two different homogeneous regions of incompressible viscous fluids under the action of a radially directed acceleration, we perform a linear stability analysis in terms of spherical surface harmonics Y n to derive the dispersion relation. The instability behavior is investigated by computing the growth rates and the most-unstable modes as a function of the spherical harmonic degree n. This general methodology is applicable to the entire parameter space spanned by the Atwood number, the viscosity ratio, and the dimensionless number B = (α RΡ² 2/μ² ²)¹ /³ R (where α R, Ρmore » 2 and μ 2 are the local radial acceleration at the interface, and the density and viscosity of the denser overlying fluid, respectively). While the mathematical formulation here is general, this paper focuses on instability that arises at a spherical viscous fluid/vacuum interface as there is a great deal to be learned from the effects of one-fluid viscosity and sphericity alone. To quantify and understand the effect that curvature and radial accelerationhave on the Rayleigh-Taylor instability, a comparison of the growth rates, under homologous driving conditions, between the planar and spherical interfaces is performed. The derived dispersion relation for the planar interface accounts for an underlying finite fluid region of thickness L and normal acceleration α R. Under certain conditions, the development of the most-unstable modes at a spherical interface can take place via the superposition of two adjacent spherical harmonics Y n and Y n+1. This bimodality in the evolution of disturbances in the linear regime does not have a counterpart in the planar configuration where the most-unstable modes are associated with a unique wave number.« less

An investigation of the fluid-structure interaction of piston/cylinder interface

NASA Astrophysics Data System (ADS)

Pelosi, Matteo

The piston/cylinder lubricating interface represents one of the most critical design elements of axial piston machines. Being a pure hydrodynamic bearing, the piston/cylinder interface fulfills simultaneously a bearing and sealing function under oscillating load conditions. Operating in an elastohydrodynamic lubrication regime, it also represents one of the main sources of power loss due to viscous friction and leakage flow. An accurate prediction of the time changing tribological interface characteristics in terms of fluid film thickness, dynamic pressure field, load carrying ability and energy dissipation is necessary to create more efficient interface designs. The aim of this work is to deepen the understanding of the main physical phenomena defining the piston/cylinder fluid film and to discover the impact of surface elastic deformations and heat transfer on the interface behavior. For this purpose, a unique fully coupled multi-body dynamics model has been developed to capture the complex fluid-structure interaction phenomena affecting the non-isothermal fluid film conditions. The model considers the squeeze film effect due to the piston micro-motion and the change in fluid film thickness due to the solid boundaries elastic deformations caused by the fluid film pressure and by the thermal strain. The model has been verified comparing the numerical results with measurements taken on special designed test pumps. The fluid film calculated dynamic pressure and temperature fields have been compared. Further validation has been accomplished comparing piston/cylinder axial viscous friction forces with measured data. The model has been used to study the piston/cylinder interface behavior of an existing axial piston unit operating at high load conditions. Numerical results are presented in this thesis.

Acoustic auditing as a real-time, non-invasive quality control process for both source and assay plates.

PubMed

Olechno, Joseph; Ellson, Richard; Browning, Brent; Stearns, Richard; Mutz, Mitchell; Travis, Michael; Qureshi, Shehrzad; Shieh, Jean

2005-08-01

Acoustic auditing is a non-destructive, non-invasive technique to monitor the composition and volume of fluids in open or sealed microplates and storage tubes. When acoustic energy encounters an interface between two materials, some of the energy passes through the interface, while the remainder is reflected. Acoustic energy applied to the bottom of a multi-well plate or a storage tube is reflected by the fluid contents of the microplate or tube. The amplitude of these reflections or echoes correlates directly with properties of the fluid, including the speed of sound and the concentration of water in the fluid. Once the speed of sound in the solution is known from the analysis of these echoes, it is easy to determine the depth of liquid and, thereby, the volume by monitoring how long it takes for sound energy to reflect off the fluid meniscus. This technique is rapid (>100,000 samples per day), precise (<1% coefficient of variation for hydration measurements, <4% coefficient of variation for volume measurements), and robust. It does not require uncapping tubes or unsealing or unlidding microplates. The sound energy is extremely gentle and has no deleterious impact upon the fluid or compounds dissolved in it.

Time-Dependent Thermally-Driven Interfacial Flows in Multilayered Fluid Structures

NASA Technical Reports Server (NTRS)

Haj-Hariri, Hossein; Borhan, A.

1996-01-01

A computational study of thermally-driven convection in multilayered fluid structures will be performed to examine the effect of interactions among deformable fluid-fluid interfaces on the structure of time-dependent flow in these systems. Multilayered fluid structures in two models configurations will be considered: the differentially heated rectangular cavity with a free surface, and the encapsulated cylindrical liquid bridge. An extension of a numerical method developed as part of our recent NASA Fluid Physics grant will be used to account for finite deformations of fluid-fluid interfaces.

Interfacial patterns in magnetorheological fluids: Azimuthal field-induced structures.

PubMed

Dias, Eduardo O; Lira, Sérgio A; Miranda, José A

2015-08-01

Despite their practical and academic relevance, studies of interfacial pattern formation in confined magnetorheological (MR) fluids have been largely overlooked in the literature. In this work, we present a contribution to this soft matter research topic and investigate the emergence of interfacial instabilities when an inviscid, initially circular bubble of a Newtonian fluid is surrounded by a MR fluid in a Hele-Shaw cell apparatus. An externally applied, in-plane azimuthal magnetic field produced by a current-carrying wire induces interfacial disturbances at the two-fluid interface, and pattern-forming structures arise. Linear stability analysis, weakly nonlinear theory, and a vortex sheet approach are used to access early linear and intermediate nonlinear time regimes, as well as to determine stationary interfacial shapes at fully nonlinear stages.

Deformation of a free interface pierced by a tilted cylinder

NASA Astrophysics Data System (ADS)

Raufaste, C.; Kirstetter, G.; Celestini, F.; Cox, S. J.

2012-07-01

We investigate the interaction between an infinite cylinder and a free fluid-fluid interface governed only by its surface tension. We study the deformation of an initially flat interface when it is deformed by the presence of a cylindrical object, tilted at an arbitrary angle, that the interface “totally wets”. Our simulations predict all significant quantities such as the interface shape, the position of the contact line, and the force exerted by the interface on the cylinder. These results are compared with an experimental study of the penetration of a soap film by a cylindrical liquid jet. This dynamic situation exhibits all the characteristics of a totally wetting interface. We show that whatever the inclination, the force is always perpendicular to the plane of the interface, and its amplitude diverges as the inclination angle increases. Such results should bring new insights in both fluid and solid mechanics, from animal locomotion to surface micro-processing.

The importance of experimental design on measurement of dynamic interfacial tension and interfacial rheology in diffusion-limited surfactant systems

DOE PAGES

Reichert, Matthew D.; Alvarez, Nicolas J.; Brooks, Carlton F.; ...

2014-09-24

Pendant bubble and drop devices are invaluable tools in understanding surfactant behavior at fluid–fluid interfaces. The simple instrumentation and analysis are used widely to determine adsorption isotherms, transport parameters, and interfacial rheology. However, much of the analysis performed is developed for planar interfaces. Moreover, the application of a planar analysis to drops and bubbles (curved interfaces) can lead to erroneous and unphysical results. We revisit this analysis for a well-studied surfactant system at air–water interfaces over a wide range of curvatures as applied to both expansion/contraction experiments and interfacial elasticity measurements. The impact of curvature and transport on measured propertiesmore » is quantified and compared to other scaling relationships in the literature. Our results provide tools to design interfacial experiments for accurate determination of isotherm, transport and elastic properties.« less

Fluid content along the subduction plate interface: how it impacts the long- (and short-) term rheology and exhumation modes

NASA Astrophysics Data System (ADS)

Agard, Philippe; Angiboust, Samuel; Guillot, Stéphane; Burov, Evgueni

2015-04-01

Over the last decade, many studies based on field, petrological and geophysical evidence have emphasized the link between mineral reactions, fluid release and seismogenesis, either along the whole plate interface (eg., Hacker et al., 2003) or at specific depths (e.g., ~30 km: Audet et al., 2009; ~70-80 km: Angiboust et al., 2012). Although they argue for a crucial influence of fluids on subduction processes, large uncertainties remain when assessing their impact on the rheology of the plate interface across space and time. Kilometer-scale accreted terranes/units in both ancient and present-day subduction zones potentially allow to track changes in mechanical coupling along the plate interface. Despite some potential biases (exhumation is limited and episodic, lasting no more than a few My if any, from prefered depths -- mainly 30-40 and 70-80 km, and there are so far only few examples precisely located with respect to the plate interface) their record of changes in fluid regime and strain localisation is extremely valuable. One striking example of the role of fluids on plate interface rheology during nascent subduction is provided by metamorphic soles (i.e., ~500 m thick tectonic slices welded to the base of ophiolites). We show that their accretion to the ophiolite indeed only happens across a transient, optimal time-T-P window (after < 1-2 My, at 1±0.2 GPa, 750-850°C) associated with fluid release and infiltration, leading to similar effective rheology on both sides (i.e., downgoing crust and mantle wedge). This maximizes interplate mechanical coupling, as deformation gets distributed over a large band encompassing the plate interface (i.e., a few km), and promotes detachment of the sole from the sinking slab. We also show how tectonic slicing during mature subduction likely relates to short-term fluid release and repeated seismicity, based on the Monviso exposures (W. Alps, a relatively continuous, 15 km long fragment of oceanic lithosphere exhumed from ~80 km depths), which preserve evidence of intraslab fluid flow and eclogitic, intermediate-depth seismicity of Mw ~4. We finally address how, in the long-term and at subduction scale, the overall fluid content and fluid regime may control the slicing, size and metastability of exhumed units. We propose that mechanical coupling varies through time, from weak to strong, as a function of the contrast of effective viscosity on either side of the interface: a young and wet subduction interface will promote the formation of knockers and sole accretion, whereas a fluid-present yet drier and colder one will lead to mainly metasedimentary underplated material and large-scale slivers of (metastable) oceanic lithosphere. This interpretation is supported by bi-phase numerical models (allowing for fluid migration driven by concentrations in the rocks, non-lithostatic pressure gradients and deformation, mantle wedge hydration and mechanical weakening of the plate interface) showing that the detachment of large-scale oceanic tectonic slices is in particular promoted by fluid migration along the subduction interface. [Hacker et al., Journal of Geophysical Research 2003; Audet et al., Nature, 2009; Angiboust et al., Geology 2012

Instability of multi-layer fluid configurations in the presence of time-dependent accelerations in a microgravity environment

NASA Technical Reports Server (NTRS)

Lyell, M. J.; Roh, Michael

1991-01-01

The increasing number of research opportunities in a microgravity environment will benefit not only fundamental studies in fluid dynamics, but also technological applications such as those involving materials processing. In particular, fluid configurations which involve fluid-fluid interfaces would occur in a variety of experimental investigations. This work investigates the stability of a configuration involving fluid-fluid interfaces in the presence of a time-dependent forcing. Both periodic (g-jitter) and nonperiodic accelerations are considered. The fluid configuration is multilayered, and infinite in extent. The analysis is linear and inviscid, and the acceleration vector is oriented perpendicular to each interface. A Floquet analysis is employed in the case of the periodic forcing. In the problem of nonperiodic forcing, the resulting system of equations are integrated in time. Specific nondimensional parameters appear in each problem. The configuration behavior is investigated for a range of parameter values.

Comparing the Richtmyer-Meshkov instability of thermal and ion-species interfaces in two-fluid plasmas

NASA Astrophysics Data System (ADS)

Wheatley, Vincent; Bond, Daryl; Li, Yuan; Samtaney, Ravi; Pullin, Dale

2017-11-01

The Richtmyer-Meshkov instability (RMI) of a shock accelerated perturbed density interface is important in both inertial confinement fusion and astrophysics, where the materials involved are typically in the plasma state. Initial density interfaces can be due to either temperature or ion-species discontinuities. If the Atwood number of the interfaces and specific heat ratios of the fluids are matched, these two cases behave similarly when modeled using the equations of either hydrodynamics or magnetohydrodynamics. In the two-fluid ion-electron plasma model, however, there is a significant difference between them: In the thermal interface case, there is a discontinuity in electron density that is also subject to the RMI, while for the ion-species interface case there is not. It will be shown via ideal two-fluid plasma simulations that this causes substantial differences in the dynamics of the flow between the two cases. This work was partially supported by the KAUST Office of Sponsored Research under Award URF/1/2162-01.

Fluid-fluid interfacial mobility from random walks

NASA Astrophysics Data System (ADS)

Barclay, Paul L.; Lukes, Jennifer R.

2017-12-01

Dual control volume grand canonical molecular dynamics is used to perform the first calculation of fluid-fluid interfacial mobilities. The mobility is calculated from one-dimensional random walks of the interface by relating the diffusion coefficient to the interfacial mobility. Three different calculation methods are employed: one using the interfacial position variance as a function of time, one using the mean-squared interfacial displacement, and one using the time-autocorrelation of the interfacial velocity. The mobility is calculated for two liquid-liquid interfaces and one liquid-vapor interface to examine the robustness of the methods. Excellent agreement between the three calculation methods is shown for all the three interfaces, indicating that any of them could be used to calculate the interfacial mobility.

Translational and rotational diffusion of Janus nanoparticles at liquid interfaces

NASA Astrophysics Data System (ADS)

Rezvantalab, Hossein; Shojaei-Zadeh, Shahab

2014-11-01

We use molecular dynamics simulations to understand the thermal motion of nanometer-sized Janus particles at the interface between two immiscible fluids. We consider spherical nanoparticles composed of two sides with different affinity to fluid phases, and evaluate their dynamics and changes in fluid structure as a function of particle size and surface chemistry. We show that as the amphiphilicity increases upon enhancing the wetting of each side with its favored fluid, the in-plane diffusivity at the interface becomes slower. Detail analysis of the fluid structure reveals that this is mainly due to formation of a denser adsorption layer around more amphiphilic particles, which leads to increased drag acting against nanoparticle motion. Similarly, the rotational thermal motion of Janus particles is reduced compared to their homogeneous counterparts as a result of the higher resistance of neighboring fluid species against rotation. We also incorporate the influence of fluid density and surface tension on the interfacial dynamics of such Janus nanoparticles. Our findings may have implications in understanding the adsorption mechanism of drugs and protein molecules with anisotropic surface properties to biological interfaces including cell membranes.

Richtmyer-Meshkov instability for elastic-plastic solids in converging geometries

NASA Astrophysics Data System (ADS)

López Ortega, A.; Lombardini, M.; Barton, P. T.; Pullin, D. I.; Meiron, D. I.

2015-03-01

We present a detailed study of the interface instability that develops at the boundary between a shell of elastic-plastic material and a cylindrical core of confined gas during the inbound implosive motion generated by a shock-wave. The main instability in this configuration is the so-called Richtmyer-Meshkov instability that arises when the shock wave crosses the material interface. Secondary instabilities, such as Rayleigh-Taylor, due to the acceleration of the interface, and Kelvin-Helmholtz, due to slip between solid and fluid, arise as the motion progresses. The reflection of the shock wave at the axis and its second interaction with the material interface as the shock moves outbound, commonly known as re-shock, results in a second Richtmyer-Meshkov instability that potentially increases the growth rate of interface perturbations, resulting in the formation of a mixing zone typical of fluid-fluid configurations and the loss of the initial perturbation length scales. The study of this problem is of interest for achieving stable inertial confinement fusion reactions but its complexity and the material conditions produced by the implosion close to the axis prove to be challenging for both experimental and numerical approaches. In this paper, we attempt to circumvent some of the difficulties associated with a classical numerical treatment of this problem, such as element inversion in Lagrangian methods or failure to maintain the relationship between the determinant of the deformation tensor and the density in Eulerian approaches, and to provide a description of the different events that occur during the motion of the interface. For this purpose, a multi-material numerical solver for evolving in time the equations of motion for solid and fluid media in an Eulerian formalism has been implemented in a Cartesian grid. Equations of state are derived using thermodynamically consistent hyperelastic relations between internal energy and stresses. The resolution required for capturing the state of solid and fluid materials close to the origin is achieved by making use of adaptive mesh refinement techniques. Rigid-body rotations contained in the deformation tensor have been shown to have a negative effect on the accuracy of the method in extreme compression conditions and are removed by transforming the deformation tensor into a stretch tensor at each time step. With this methodology, the evolution of the interface can be tracked up to a point at which numerical convergence cannot be achieved due to the inception of numerical Kelvin-Helmholtz instabilities caused by slip between materials. From that point, only qualitative conclusions can be extracted from this analysis. The influence of different geometrical parameters, initial conditions, and material properties on the motion of the interface are investigated. Some major differences are found with respect to the better understood fluid-fluid case. For example, increasing the wave number of the interface perturbations leads to a second phase reversal of the interface (i.e., the first phase reversal of the interface naturally occurs due to the initial negative growth-rate of the instability as the shock wave transitions from the high-density material to the low-density one). This phenomenon is caused by the compressive effect of the converging geometry and the low density of the gas with respect to the solid, which allows for the formation of an incipient spike in the center of an already existing bubble. Multiple solid-gas density ratios are also considered. Results show that the motion of the interface asymptotically converges to the solid-vacuum case. When a higher initial density for the gas is considered, the growth rate of interface perturbations decreases and, in some situations, its sign may reverse, as the fluid becomes more dense than the solid due to having higher compressibility. Finally, the influence of the Mach number of the driving shock and the yield stress on the mixing-zone is examined. We find that the width of the mixing zone produced after the re-shock increases in proportion to the strength of the incident shock. An increased yield stress in the solid material makes the interface less unstable due to vorticity being carried away from the interface by shear waves and limits the generation of smaller length scales after the re-shock.

Soft particles at a fluid interface

NASA Astrophysics Data System (ADS)

Mehrabian, Hadi; Harting, Jens; Snoeijer, Jacco H.

2015-11-01

Particles added to a fluid interface can be used as a surface stabilizer in the food, oil and cosmetic industries. As an alternative to rigid particles, it is promising to consider highly deformable particles that can adapt their conformation at the interface. In this study, we compute the shapes of soft elastic particles using molecular dynamics simulations of a cross-linked polymer gel, complemented by continuum calculations based on the linear elasticity. It is shown that the particle shape is not only affected by the Young's modulus of the particle, but also strongly depends on whether the gel is partially or completely wetting the fluid interface. We find that the molecular simulations for the partially wetting case are very accurately described by the continuum theory. By contrast, when the gel is completely wetting the fluid interface the linear theory breaks down and we reveal that molecular details have a strong influence on the equilibrium shape.

Interface Fluid Syndrome After Laser In Situ Keratomileusis (LASIK) Because of Fuchs Endothelial Dystrophy Reversed by Descemet Membrane Endothelial Keratoplasty (DMEK).

PubMed

Luceri, Salvatore; Baksoellah, Zainab; Ilyas, Abbas; Baydoun, Lamis; Melles, Gerrit R J

2016-12-01

To describe a case that developed "interface fluid syndrome" after previous laser in situ keratomileusis (LASIK) because of Fuchs endothelial dystrophy (FED), which was reversed by Descemet membrane endothelial keratoplasty (DMEK). A 58-year-old male patient presented with bilateral visual impairment owing to FED and visually significant cataract. Cataract surgery was carried out in both eyes followed by DMEK in his left eye. After cataract surgery, visual acuity did not improve sufficiently because corneal thickness increased and a fine cleft with interface fluid developed between the LASIK-flap and the residual stromal bed. After uneventful DMEK in his left eye, the fluid resolved within a week and visual acuity improved rapidly. This case demonstrates that "interface fluid syndrome" after LASIK caused by concomitant endothelial dysfunction may be reversed by DMEK allowing fast visual recovery.

Interfacial gauge methods for incompressible fluid dynamics

DOE PAGES

Saye, R.

2016-06-10

Designing numerical methods for incompressible fluid flow involving moving interfaces, for example, in the computational modeling of bubble dynamics, swimming organisms, or surface waves, presents challenges due to the coupling of interfacial forces with incompressibility constraints. A class of methods, denoted interfacial gauge methods, is introduced for computing solutions to the corresponding incompressible Navier-Stokes equations. These methods use a type of "gauge freedom" to reduce the numerical coupling between fluid velocity, pressure, and interface position, allowing high-order accurate numerical methods to be developed more easily. Making use of an implicit mesh discontinuous Galerkin framework, developed in tandem with this work,more » high-order results are demonstrated, including surface tension dynamics in which fluid velocity, pressure, and interface geometry are computed with fourth-order spatial accuracy in the maximum norm. Applications are demonstrated with two-phase fluid flow displaying fine-scaled capillary wave dynamics, rigid body fluid-structure interaction, and a fluid-jet free surface flow problem exhibiting vortex shedding induced by a type of Plateau-Rayleigh instability. The developed methods can be generalized to other types of interfacial flow and facilitate precise computation of complex fluid interface phenomena.« less

Diffusion-limited retention of porous particles at density interfaces

PubMed Central

Kindler, Kolja; Khalili, Arzhang; Stocker, Roman

2010-01-01

Downward carbon flux in the ocean is largely governed by particle settling. Most marine particles settle at low Reynolds numbers and are highly porous, yet the fluid dynamics of this regime have remained unexplored. We present results of an experimental investigation of porous particles settling through a density interface at Reynolds numbers between 0.1 and 1. We tracked 100 to 500 μm hydrogel spheres with 95.5% porosity and negligible permeability. We found that a small negative initial excess density relative to the lower (denser) fluid layer, a common scenario in the ocean, results in long retention times of particles at the interface. We hypothesized that the retention time was determined by the diffusive exchange of the stratifying agent between interstitial and ambient fluid, which increases excess density of particles that have stalled at the interface, enabling their settling to resume. This hypothesis was confirmed by observations, which revealed a quadratic dependence of retention time on particle size, consistent with diffusive exchange. These results demonstrate that porosity can control retention times and therefore accumulation of particles at density interfaces, a mechanism that could underpin the formation of particle layers frequently observed at pycnoclines in the ocean. We estimate retention times of 3 min to 3.3 d for the characteristic size range of marine particles. This enhancement in retention time can affect carbon transformation through increased microbial colonization and utilization of particles and release of dissolved organics. The observed size dependence of the retention time could further contribute to improve quantifications of vertical carbon flux. PMID:21135242

Dynamics and Instabilities of Acoustically Stressed Interfaces

NASA Astrophysics Data System (ADS)

Shi, William Tao

An intense sound field exerts acoustic radiation pressure on a transitional layer between two continuous fluid media, leading to the unconventional dynamical behavior of the interface in the presence of the sound field. An understanding of this behavior has applications in the study of drop dynamics and surface rheology. Acoustic fields have also been utilized in the generation of interfacial instability, which may further encourage the dispersion or coalescence of liquids. Therefore, the study of the dynamics of the acoustically stressed interfaces is essential to infer the mechanism of the various phenomena related to interfacial dynamics and to acquire the properties of liquid surfaces. This thesis studies the dynamics of acoustically stressed interfaces through a theoretical model of surface interactions on both closed and open interfaces. Accordingly, a boundary integral method is developed to simulate the motions of a stressed interface. The method has been employed to determine the deformation, oscillation and instability of acoustically levitated drops. The generalized computations are found to be in good agreement with available experimental results. The linearized theory is also derived to predict the instability threshold of the flat interface, and is then compared with experiments conducted to observe and measure the unstable motions of the horizontal interface. This thesis is devoted to describing and classifying the simplest mechanisms by which acoustic fields provide a surface interaction with a fluid. A physical picture of the competing processes introduced by the evolution of an interface in a sound field is presented. The development of an initial small perturbation into a sharp form is observed on either a drop surface or a horizontal interface, indicating a strong focusing of acoustic energy at certain spots of the interface. Emphasis is placed on understanding the basic coupling mechanisms, rather than on particular applications that may involve this coupling. The dynamical behavior of a stressed drop can be determined in terms of a given form of an incident sound field and three dimensionless quantities. Thus, the behavior of a complex dynamic system has been clarified, permitting the exploration and interpretation of the nature of liquid surface phenomena.

The Voronoi Implicit Interface Method for computing multiphase physics

PubMed Central

Saye, Robert I.; Sethian, James A.

2011-01-01

We introduce a numerical framework, the Voronoi Implicit Interface Method for tracking multiple interacting and evolving regions (phases) whose motion is determined by complex physics (fluids, mechanics, elasticity, etc.), intricate jump conditions, internal constraints, and boundary conditions. The method works in two and three dimensions, handles tens of thousands of interfaces and separate phases, and easily and automatically handles multiple junctions, triple points, and quadruple points in two dimensions, as well as triple lines, etc., in higher dimensions. Topological changes occur naturally, with no surgery required. The method is first-order accurate at junction points/lines, and of arbitrarily high-order accuracy away from such degeneracies. The method uses a single function to describe all phases simultaneously, represented on a fixed Eulerian mesh. We test the method’s accuracy through convergence tests, and demonstrate its applications to geometric flows, accurate prediction of von Neumann’s law for multiphase curvature flow, and robustness under complex fluid flow with surface tension and large shearing forces. PMID:22106269

The Voronoi Implicit Interface Method for computing multiphase physics.

PubMed

Saye, Robert I; Sethian, James A

2011-12-06

We introduce a numerical framework, the Voronoi Implicit Interface Method for tracking multiple interacting and evolving regions (phases) whose motion is determined by complex physics (fluids, mechanics, elasticity, etc.), intricate jump conditions, internal constraints, and boundary conditions. The method works in two and three dimensions, handles tens of thousands of interfaces and separate phases, and easily and automatically handles multiple junctions, triple points, and quadruple points in two dimensions, as well as triple lines, etc., in higher dimensions. Topological changes occur naturally, with no surgery required. The method is first-order accurate at junction points/lines, and of arbitrarily high-order accuracy away from such degeneracies. The method uses a single function to describe all phases simultaneously, represented on a fixed Eulerian mesh. We test the method's accuracy through convergence tests, and demonstrate its applications to geometric flows, accurate prediction of von Neumann's law for multiphase curvature flow, and robustness under complex fluid flow with surface tension and large shearing forces.

The Voronoi Implicit Interface Method for computing multiphase physics

DOE PAGES

Saye, Robert I.; Sethian, James A.

2011-11-21

In this paper, we introduce a numerical framework, the Voronoi Implicit Interface Method for tracking multiple interacting and evolving regions (phases) whose motion is determined by complex physics (fluids, mechanics, elasticity, etc.), intricate jump conditions, internal constraints, and boundary conditions. The method works in two and three dimensions, handles tens of thousands of interfaces and separate phases, and easily and automatically handles multiple junctions, triple points, and quadruple points in two dimensions, as well as triple lines, etc., in higher dimensions. Topological changes occur naturally, with no surgery required. The method is first-order accurate at junction points/lines, and of arbitrarilymore » high-order accuracy away from such degeneracies. The method uses a single function to describe all phases simultaneously, represented on a fixed Eulerian mesh. Finally, we test the method’s accuracy through convergence tests, and demonstrate its applications to geometric flows, accurate prediction of von Neumann’s law for multiphase curvature flow, and robustness under complex fluid flow with surface tension and large shearing forces.« less

Mars aqueous chemistry experiment

NASA Technical Reports Server (NTRS)

Clark, Benton C.; Mason, Larry W.

1993-01-01

The Mars Aqueous Chemistry Experiment (MACE) is designed to conduct a variety of measurements on regolith samples, encompassing mineral phase analyses, chemical interactions with H2O, and physical properties determinations. From these data, much can be learned or inferred regarding the past weathering environment, the contemporaneous soil micro-environments, and the general chemical and physical state of the Martian regolith. By analyzing both soil and duricrust samples, the nature of the latter may become more apparent. Sites may be characterized for comparative purposes and criteria could be set for selection of high priority materials on future sample return missions. Progress for the first year MACE PIDDP is reported in two major areas of effort: (1) fluids handling concepts, definition, and breadboard fabrication and (2) aqueous chemistry ion sensing technology and test facility integration. A fluids handling breadboard was designed, fabricated, and tested at Mars ambient pressure. The breadboard allows fluid manipulation scenarios to be tested under the reduced pressure conditions expected in the Martian atmosphere in order to validate valve operations, orchestrate analysis sequences, investigate sealing integrity, and to demonstrate efficacy of the fluid handling concept. Additional fluid manipulation concepts have also been developed based on updated MESUR spacecraft definition. The Mars Aqueous Chemistry Experiment Ion Selective Electrode (ISE) facility was designed as a test bed to develop a multifunction interface for measurements of chemical ion concentrations in aqueous solution. The interface allows acquisition of real time data concerning the kinetics and heats of salt dissolution, and transient response to calibration and solubility events. An array of ion selective electrodes has been interfaced and preliminary calibration studies performed.

Mars aqueous chemistry experiment

NASA Astrophysics Data System (ADS)

Clark, Benton C.; Mason, Larry W.

1993-06-01

The Mars Aqueous Chemistry Experiment (MACE) is designed to conduct a variety of measurements on regolith samples, encompassing mineral phase analyses, chemical interactions with H2O, and physical properties determinations. From these data, much can be learned or inferred regarding the past weathering environment, the contemporaneous soil micro-environments, and the general chemical and physical state of the Martian regolith. By analyzing both soil and duricrust samples, the nature of the latter may become more apparent. Sites may be characterized for comparative purposes and criteria could be set for selection of high priority materials on future sample return missions. Progress for the first year MACE PIDDP is reported in two major areas of effort: (1) fluids handling concepts, definition, and breadboard fabrication and (2) aqueous chemistry ion sensing technology and test facility integration. A fluids handling breadboard was designed, fabricated, and tested at Mars ambient pressure. The breadboard allows fluid manipulation scenarios to be tested under the reduced pressure conditions expected in the Martian atmosphere in order to validate valve operations, orchestrate analysis sequences, investigate sealing integrity, and to demonstrate efficacy of the fluid handling concept. Additional fluid manipulation concepts have also been developed based on updated MESUR spacecraft definition. The Mars Aqueous Chemistry Experiment Ion Selective Electrode (ISE) facility was designed as a test bed to develop a multifunction interface for measurements of chemical ion concentrations in aqueous solution. The interface allows acquisition of real time data concerning the kinetics and heats of salt dissolution, and transient response to calibration and solubility events. An array of ion selective electrodes has been interfaced and preliminary calibration studies performed.

3D CFD Modeling of the LMF System: Desulfurization Kinetics

NASA Astrophysics Data System (ADS)

Cao, Qing; Pitts, April; Zhang, Daojie; Nastac, Laurentiu; Williams, Robert

A fully transient 3D CFD modeling approach capable of predicting the three phase (gas, slag and steel) fluid flow characteristics and behavior of the slag/steel interface in the argon gas bottom stirred ladle with two off-centered porous plugs (Ladle Metallurgical Furnace or LMF) has been recently developed. The model predicts reasonably well the fluid flow characteristics in the LMF system and the observed size of the slag eyes for both the high-stirring and low-stirring conditions. A desulfurization reaction kinetics model considering metal/slag interface characteristics is developed in conjunction with the CFD modeling approach. The model is applied in this study to determine the effects of processing time, and gas flow rate on the efficiency of desulfurization in the studied LMF system.

Kuipers during photo documentation of the fluid and electrical interfaces on the UIA

NASA Image and Video Library

2012-01-27

ISS030-E-156468 (27 Jan. 2012) --- European Space Agency astronaut Andre Kuipers, Expedition 30 flight engineer, is pictured in the Quest airlock of the International Space Station during photo documentation of the fluid and electrical interfaces on the Umbilical Interface Assembly (UIA) Connector Shelf.

Interfacing a General Purpose Fluid Network Flow Program with the SINDA/G Thermal Analysis Program

NASA Technical Reports Server (NTRS)

Schallhorn, Paul; Popok, Daniel

1999-01-01

A general purpose, one dimensional fluid flow code is currently being interfaced with the thermal analysis program Systems Improved Numerical Differencing Analyzer/Gaski (SINDA/G). The flow code, Generalized Fluid System Simulation Program (GFSSP), is capable of analyzing steady state and transient flow in a complex network. The flow code is capable of modeling several physical phenomena including compressibility effects, phase changes, body forces (such as gravity and centrifugal) and mixture thermodynamics for multiple species. The addition of GFSSP to SINDA/G provides a significant improvement in convective heat transfer modeling for SINDA/G. The interface development is conducted in multiple phases. This paper describes the first phase of the interface which allows for steady and quasi-steady (unsteady solid, steady fluid) conjugate heat transfer modeling.

Structure and Dynamics of Forsterite-scCO2/H2O Interfaces as a Function of Water Content

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kerisit, Sebastien N.; Weare, John H.; Felmy, Andrew R.

Molecular dynamics (MD) simulations of forsterite surfaces in contact with supercritical carbon dioxide (scCO2) fluids of varying water content were performed to determine the partition of water between the scCO2 fluid and the mineral surface, the nature of CO2 and H2O bonding at the interface, and the regions of the interface that may be conducive to HxCO3(2-x)- formation. Calculations of the free energy of the associative adsorption of water onto the (010) forsterite surface from the scCO2 phase indicated that the formation of a water film up to three-monolayer thick can be exothermic even for water contents below the watermore » saturation concentration of the scCO2 fluid. In MD simulations of scCO2/H2O mixtures in contact with the (010) forsterite surface, H2O was found to readily displace CO2 at the surface and, therefore, CO2 directly contacted the surface only for water coverages below two monolayers. For thicker water films, a two-monolayer hydration layer formed that CO2 could not penetrate. Simulations of the hydroxylated (010) surface and of the (011) surface suggested that this conclusion can be extended to forsterite surfaces with different surface structures and/or compositions. The density, diffusion, and degree of hydration of CO2 as well as the extent of CO2/H2O mixing at the interface were all predicted to depend strongly on the thickness of the water-rich film, i.e., on the water content of the scCO2 fluid.« less

Capillary bending of a thin polymer film floating on a liquid bath

NASA Astrophysics Data System (ADS)

Twohig, Timothy; Croll, Andrew B.

Thin elastic films and shells are very important in schemes for the encapsulation and protection of fluids from their environment. Capillary origami is a particularly poignant example of how useful fluid/film structures can be formed. The interactions of fluids on thin-films which themselves lie on another surface (fluid or low friction solid) need to be studied if the differences from fluid-fluid and fluid-solid film interfaces are to be fully appreciated. In this experiment, we examine the triple line that occurs when a fluid is resting on a thin polymer film which is itself floating on a second fluid. The top fluid has a high-energy air/fluid interface which can be minimized by deforming the film in a manner that reduces the total air/fluid interface. We create a one-dimensional experiment in order to isolate the basic physics that occurs as the tension of the top fluid pulls on the thin film. Notably, the 1D geometry removes all the complexity incurred by thin films in biaxial stress states (such as wrinkling, folding and crumpling) from the problem. AFOSR under the Young Investigator Program (FA9550-15-1-0168).

Surface Instability of Liquid Propellant under Vertical Oscillatory Forcing

NASA Technical Reports Server (NTRS)

Yang, H. Q.; Peugeot, John

2011-01-01

Fluid motion in a fuel tank produced during thrust oscillations can circulate sub-cooled hydrogen near the liquid-vapor interface resulting in increased condensation and ullage pressure collapse. The first objective of this study is to validate the capabilities of a Computational Fluid Dynamics (CFD) tool, CFD-ACE+, in modeling the fundamental interface transition physics occurring at the propellant surface. The second objective is to use the tool to assess the effects of thrust oscillations on surface dynamics. Our technical approach is to first verify the CFD code against known theoretical solutions, and then validate against existing experiments for small scale tanks and a range of transition regimes. A 2D axisymmetric, multi-phase model of gases, liquids, and solids is used to verify that CFD-ACE+ is capable of modeling fluid-structure interaction and system resonance in a typical thrust oscillation environment. Then, the 3D mode is studied with an assumed oscillatory body force to simulate the thrust oscillating effect. The study showed that CFD modeling can capture all of the transition physics from solid body motion to standing surface wave and to droplet ejection from liquid-gas interface. Unlike the analytical solutions established during the 1960 s, CFD modeling is not limited to the small amplitude regime. It can extend solutions to the nonlinear regime to determine the amplitude of surface waves after the onset of instability. The present simulation also demonstrated consistent trends from numerical experiments through variation of physical properties from low viscous fluid to high viscous fluids, and through variation of geometry and input forcing functions. A comparison of surface wave patterns under various forcing frequencies and amplitudes showed good agreement with experimental observations. It is concluded that thrust oscillations can cause droplet formation at the interface, which results in increased surface area and enhanced heat transfer between the liquid and gas phases as the ejected droplets travel well into the warmer gas region.

Comparison of Microleakage of Composite Resin Veneering Systems at the Alloy Interface

DTIC Science & Technology

1988-09-01

of oral fluids at the metal- resin interface and breakdown of the acrylic resin were factors that have limited the acceptance and widespread use of...percolation of oral fluids at the resin -metal interface, and low resistance to toothbrush abrasion. If chemical means could be used to achieve resin -metal...bonding, 1) esthetics could be improved because of a more uniform layer of the opaque and composite resin , and 2) percolation of fluids at the metal

Nanoparticle Assemblies at Fluid Interfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, Thomas P.

2015-03-10

A systematic study of the structure and dynamics of nanoparticles (NP) and NP-surfactants was performed. The ligands attached to both the NPs and NP-surfactants dictate the manner in which the nanoscopic materials assemble at fluid interfaces. Studies have shown that a single layer of the nanoscpic materials form at the interface to reduce the interactions between the two immiscible fluids. The shape of the NP is, also, important, where for spherical particles, a disordered, liquid-like monolayer forms, and, for nanorods, ordered domains at the interface is found and, if the monolayers are compressed, the orientation of the nanorods with respectmore » to the interface can change. By associating end-functionalized polymers to the NPs assembled at the interface, NP-surfactants are formed that increase the energetic gain in segregating each NP at the interface which allows the NP-surfactants to jam at the interface when compressed. This has opened the possibility of structuring the two liquids by freezing in shape changes of the liquids.« less

Formation of curvature singularities on the interface between dielectric liquids in a strong vertical electric field.

PubMed

Kochurin, Evgeny A; Zubarev, Nikolay M; Zubareva, Olga V

2013-08-01

The nonlinear dynamics of the interface between two deep dielectric fluids in the presence of a vertical electric field is studied. We consider the limit of a strong external electric field where electrostatic forces dominate over gravitational and capillary forces. The nonlinear integrodifferential equations for the interface motion are derived under the assumption of small interfacial slopes. It is shown in the framework of these equations that, in the generic case, the instability development leads to the formation of root singularities at the interface in a finite time. The interfacial curvature becomes infinite at singular points, while the slope angles remain relatively small. The curvature is negative in the vicinity of singularities if the ratio of the permittivities of the fluids exceeds the inverse ratio of their densities, and it is positive in the opposite case (we consider that the lower fluid is heavier than the upper one). In the intermediate case, the interface evolution equations describe the formation and sharpening of dimples at the interface. The results obtained are applicable for the description of the instability of the interface between two magnetic fluids in a vertical magnetic field.

Immersed Boundary Simulations of Active Fluid Droplets

PubMed Central

Hawkins, Rhoda J.

2016-01-01

We present numerical simulations of active fluid droplets immersed in an external fluid in 2-dimensions using an Immersed Boundary method to simulate the fluid droplet interface as a Lagrangian mesh. We present results from two example systems, firstly an active isotropic fluid boundary consisting of particles that can bind and unbind from the interface and generate surface tension gradients through active contractility. Secondly, a droplet filled with an active polar fluid with homeotropic anchoring at the droplet interface. These two systems demonstrate spontaneous symmetry breaking and steady state dynamics resembling cell motility and division and show complex feedback mechanisms with minimal degrees of freedom. The simulations outlined here will be useful for quantifying the wide range of dynamics observable in these active systems and modelling the effects of confinement in a consistent and adaptable way. PMID:27606609

The Effect of Ambient Ozone on Unsaturated Tear Film Wax Esters.

PubMed

Paananen, Riku O; Rantamäki, Antti H; Parshintsev, Jevgeni; Holopainen, Juha M

2015-12-01

Tear film lipid layer (TFLL) is constantly exposed to reactive ozone in the surrounding air, which may have detrimental effects on ocular health. Behenyl oleate (BO), a representative tear film wax ester, was used to study the reaction with ozone at the air-water interface. Time-dependent changes in mean molecular area of BO monolayers were measured at different ozone concentrations and surface pressures. In addition, the effect of ascorbic acid on the reaction rate was determined. Reaction was followed using thin-layer chromatography and reaction products were identified using liquid chromatography-electrospray ionization mass spectrometry (LC-MS). Tear fluid samples from healthy subjects were analyzed with LC-MS for any ozonolysis reaction products. Behenyl oleate was found to undergo rapid ozonolysis at the air-water interface at normal indoor ozone concentrations. The reaction was observed as an initial expansion followed by a contraction of the film area. Ascorbic acid was found to decrease the rate of ozonolysis. Main reaction products were identified as behenyl 9-oxononanoate and behenyl 8-(5-octyl-1,2,4-trioxolan-3-yl)octanoate. Similar ozonolysis products were not detected in the tear fluid samples. At the air-water interface, unsaturated wax esters react readily with ozone in ambient air. However, no signs of ozonolysis products were found in the tear fluid. This is most likely due to the antioxidant systems present in tear fluid. Last, the results show that ozonolysis needs to be controlled in future surface chemistry studies on tear film lipids.

Approaching a flat boundary with a block copolymer coated emulsion drop: late stage drainage dynamics

NASA Astrophysics Data System (ADS)

Rozairo, Damith; Croll, Andrew

Understanding the dynamics of the formation and drainage of the thin fluid film that becomes trapped by a deformable droplet as it approaches another object is crucial to the advancement of many industrial and biomedical applications. Adding amphiphilic diblock copolymers, which are becoming more commonly used in drug delivery and oil recovery, only add to the complexity. Despite their increased use, little is known about how long polymer chains fill an emulsion drop's interface or how the molecules influence hydrodynamic processes. We study the drainage dynamics of a thin water film trapped between mica and a diblock copolymer saturated oil droplet. Specifically, we examine several different polystyrene-b-poly(ethylene oxide) (PS-PEO) molecules self-assembled at a toluene-water interface using laser scanning confocal microscopy. Our experiments reveal that the molecular details of the polymer chains deeply influence the drainage times, indicating that they are not acting as a 'simple' surfactant. The presence of the chains creates a much slower dynamic as fluid is forced to drain through an effective polymer brush, the brush itself determined by chain packing at the interface. We present a simple model which accounts for the basic physics of the interface.

Optical interferometry study of film formation in lubrication of sliding and/or rolling contacts

NASA Technical Reports Server (NTRS)

Stejskal, E. O.; Cameron, A.

1972-01-01

Seventeen fluids of widely varying physical properties and molecular structure were chosen for study. Film thickness and traction were measured simultaneously in point contacts by interferometry, from which a new theory of traction was proposed. Film thickness was measured in line contacts by interferometry and electrical capacitance to establish correlation between these two methods. An interferometric method for the absolute determination of refractive index in the contact zone was developed and applied to point contact fluid entrapments. Electrical capacitance was used to study the thickness and properties of the soft surface film which sometimes forms near a metal-fluid interface.

Dynamics of Liquids in Edges and Corners (DYLCO): IML-2 Experiment for the BDPU

NASA Technical Reports Server (NTRS)

Langbein, D.; Weislogel, M.

1998-01-01

Knowledge of the behavior of fluids possessing free surfaces is important to many fluid systems, particularly in space, where the normally subtle effects of surface wettability play a more dramatic and often surprising role. DYLCO for the IML-2 mission was proposed as a simple experiment to probe the particular behavior of capillary surfaces in containers of irregular cross section. Temperature control was utilized to vary the fluid-solid contact angle, a questionable thermodynamic parameter of the system, small changes in which can dramatically influence the configuration, stability, and flow of a capillary surface. Container shapes, test fluid, and temperature ranges were selected for observing both local changes in interface curvature as well as a global change in fluid orientation due to a critical wetting phenomenon. The experiment hardware performed beyond what was expected and fluid interfaces could be readily digitized post flight to show the dependence of the interface curvature on temperature. For each of the containers tested surfaces were observed which did not satisfy the classic equations for the prediction of interface shape with constant contact angle boundary condition. This is explained by the presence of contact angle hysteresis arising from expansion and contraction of the liquid during the heating and cooling steps of the test procedure. More importantly, surfaces exceeding the critical surface curvature required for critical wetting were measured, yet no wetting was observed. These findings are indeed curious and pose key questions concerning the role of hysteresis for this critical wetting phenomena. The stability of such surfaces was determined numerically and it is shown that stability is enhance (reduced) when a surface is in its 'advancing' ('receding') state, The analysis shows complete instability as the critical wetting condition is reached. The case of ideal dynamic wetting is addressed analytically in detail with results of significant flow characteristics presented in closed form. The solutions indicate a square root of T dependence of the capillary 'rise' rate which is corroborated by drop tower tests. The analysis clearly shows that infinite time is necessary for surfaces to reorient at the critical wetting transition.

Stokesian swimming of a helical swimmer across an interface

NASA Astrophysics Data System (ADS)

Godinez, Francisco; Ramos, Armando; Zenit, Roberto

2016-11-01

Microorganisms swim in flows dominated by viscous effects but in many instances the motion occurs across heterogeneous environments where the fluid properties may vary. To our knowledge, the effect of such in-homogeneity has not been addressed in depth. We conduct experiments in which a magnetic self-propelled helical swimmer displaces across the interface between two immiscible density stratified fluids. As the swimmer crosses the interface, at a fixed rotation rate, its speed is reduced and a certain volume of the lower fluid is dragged across. We quantify the drift volume and the change of swimming speed for different swimming speeds and different fluid combinations. We relate the reduction of the swimming speed with the interfacial tension of the interface. We also compare the measurements of the drift volume with some recent calculations found in the literature.

A numerical method for electro-kinetic flow with deformable fluid interfaces

NASA Astrophysics Data System (ADS)

Booty, Michael; Ma, Manman; Siegel, Michael

2013-11-01

We consider two-phase flow of ionic fluids whose motion is driven by an imposed electric field. At a fluid interface, a screening cloud of ions develops and forms an electro-chemical double layer or Debye layer. The imposed field acts on this induced charge distribution, resulting in a strong slip flow near the interface. We formulate a ``hybrid'' or multiscale numerical method in the thin Debye layer limit that incorporates an asymptotic analysis of the electrostatic potential and fluid dynamics in the Debye layer into a boundary integral solution of the full moving boundary problem. Results of the method are presented that show time-dependent deformation and steady state drop interface shapes when the timescale for charge-up of the Debye layer is either much less than or comparable to the timescale of the flow.

The rotating movement of three immiscible fluids - A benchmark problem

USGS Publications Warehouse

Bakker, M.; Oude, Essink G.H.P.; Langevin, C.D.

2004-01-01

A benchmark problem involving the rotating movement of three immiscible fluids is proposed for verifying the density-dependent flow component of groundwater flow codes. The problem consists of a two-dimensional strip in the vertical plane filled with three fluids of different densities separated by interfaces. Initially, the interfaces between the fluids make a 45??angle with the horizontal. Over time, the fluids rotate to the stable position whereby the interfaces are horizontal; all flow is caused by density differences. Two cases of the problem are presented, one resulting in a symmetric flow field and one resulting in an asymmetric flow field. An exact analytical solution for the initial flow field is presented by application of the vortex theory and complex variables. Numerical results are obtained using three variable-density groundwater flow codes (SWI, MOCDENS3D, and SEAWAT). Initial horizontal velocities of the interfaces, as simulated by the three codes, compare well with the exact solution. The three codes are used to simulate the positions of the interfaces at two times; the three codes produce nearly identical results. The agreement between the results is evidence that the specific rotational behavior predicted by the models is correct. It also shows that the proposed problem may be used to benchmark variable-density codes. It is concluded that the three models can be used to model accurately the movement of interfaces between immiscible fluids, and have little or no numerical dispersion. ?? 2003 Elsevier B.V. All rights reserved.

System for concentrating and analyzing particles suspended in a fluid

DOEpatents

Fiechtner, Gregory J [Bethesda, MD; Cummings, Eric B [Livermore, CA; Singh, Anup K [Danville, CA

2011-04-26

Disclosed is a device for separating and concentrating particles suspended in a fluid stream by using dielectrophoresis (DEP) to trap and/or deflect those particles as they migrate through a fluid channel. The method uses fluid channels designed to constrain a liquid flowing through it to uniform electrokinetic flow velocities. This behavior is achieved by connecting deep and shallow sections of channels, with the channel depth varying abruptly along an interface. By careful design of abrupt changes in specific permeability at the interface, an abrupt and spatially uniform change in electrokinetic force can be selected. Because these abrupt interfaces also cause a sharp gradient in applied electric fields, a DEP force also can be established along the interface. Depending on the complex conductivity of the suspended particles and the immersion liquid, the DEP force can controllably complement or oppose the local electrokinetic force transporting the fluid through the channel allowing for manipulation of particles suspended in the transporting liquid.

Apparatus and method for concentrating and filtering particles suspended in a fluid

DOEpatents

Fiechtner, Gregory J [Bethesda, MD; Cummings, Eric B [Livermore, CA; Singh, Anup K [Danville, CA

2009-05-19

Disclosed is a device for separating and concentrating particles suspended in a fluid stream by using dielectrophoresis (DEP) to trap and/or deflect those particles as they migrate through a fluid channel. The method uses fluid channels designed to constrain a liquid flowing through it to uniform electrokinetic flow velocities. This behavior is achieved by connecting deep and shallow sections of channels, with the channel depth varying abruptly along an interface. By careful design of abrupt changes in specific permeability at the interface, an abrupt and spatially uniform change in electrokinetic force can be selected. Because these abrupt interfaces also cause a sharp gradient in applied electric fields, a DEP force also can be established along the interface. Depending on the complex conductivity of the suspended particles and the immersion liquid, the DEP force can controllably complement or oppose the local electrokinetic force transporting the fluid through the channel allowing for manipulation of particles suspended in the transporting liquid.

Noninvasive method for determining the liquid level and density inside of a container

DOEpatents

Sinha, Dipen N.

2000-01-01

Noninvasive method for determining the liquid level and density inside of a container having arbitrary dimension and shape. By generating a flexural acoustic wave in the container shell and measuring the phase difference of the detected flexural wave from that of the originally generated wave a small distance from the generated wave, while moving the generation and detection means through the liquid/vapor interface, this interface can be detected. Both the wave generation and wave detection may be achieved by transducers on the surface of the container. A change in the phase difference over the outer surface of the vessel signifies that a liquid/vapor interface has been crossed, while the magnitude of the phase difference can be related to fluid density immediately opposite the measurement position on the surface of the vessel.

Stability of Contact Lines in Fluids: 2D Stokes Flow

NASA Astrophysics Data System (ADS)

Guo, Yan; Tice, Ian

2018-02-01

In an effort to study the stability of contact lines in fluids, we consider the dynamics of an incompressible viscous Stokes fluid evolving in a two-dimensional open-top vessel under the influence of gravity. This is a free boundary problem: the interface between the fluid in the vessel and the air above (modeled by a trivial fluid) is free to move and experiences capillary forces. The three-phase interface where the fluid, air, and solid vessel wall meet is known as a contact point, and the angle formed between the free interface and the vessel is called the contact angle. We consider a model of this problem that allows for fully dynamic contact points and angles. We develop a scheme of a priori estimates for the model, which then allow us to show that for initial data sufficiently close to equilibrium, the model admits global solutions that decay to equilibrium exponentially quickly.

Splay Fault Branching from the Hikurangi Subduction Shear Zone: Implications for Slow Slip and Fluid Flow

NASA Astrophysics Data System (ADS)

Henrys, S. A.; Plaza-Faverola, A. A.; Pecher, I. A.; Klaeschen, D.; Wallace, L.

2016-12-01

Seismic reflection data along the East Coast of the New Zealand North Island are used to map the offshore character and geometry of the central Hikurangi subduction thrust and outer wedge in a region of short term ( 2-3 weeks duration) geodetically determined slow-slip events (SSEs). Pre-stack depth migration of line 05CM-38 was used to derive subducting slab geometry and upper crustal structure together with a Vp image of the crust that is resolved to 14 km depth. The subduction interface is a shallow dipping thrust at < 7 km deep near the trench and steps down to 14 km depth along an approximately 18 km long ramp, beneath Porangahau Ridge. This bend in the subducted plate is associated with splay fault branching and coincides with the zone of maximum slip (90 mm) inferred on the subduction interface during slow slip events in June and July 2011. We infer that the step down in the décollement transfers slip on the plate interface from the top of subducting sediments to the oceanic crust and drives underplating beneath the inner margin of central Hikurangi margin. Low-velocity subducting sediments (LVZ) beneath the plate interface, updip of the plate interface ramp, are interpreted as being capped with a low permeability condensed layer of chalk and interbedded mudstones. We interpret this LVZ as fluid-rich overpressured sediments that have been displaced and later imbricated by splay faults in a region that may mark the up-dip transition from seismic to aseismic behavior. Further, we hypothesize that fluids derived from the overpressured sediment are channeled along splay faults to the shallow sub-seafloor near Porangahau Ridge where seafloor seepage and an upwarping of the gas hydrate Bottom-Simulating Reflector have been documented.

An upper bound on the particle-laden dependency of shear stresses at solid-fluid interfaces

NASA Astrophysics Data System (ADS)

Zohdi, T. I.

2018-03-01

In modern advanced manufacturing processes, such as three-dimensional printing of electronics, fine-scale particles are added to a base fluid yielding a modified fluid. For example, in three-dimensional printing, particle-functionalized inks are created by adding particles to freely flowing solvents forming a mixture, which is then deposited onto a surface, which upon curing yields desirable solid properties, such as thermal conductivity, electrical permittivity and magnetic permeability. However, wear at solid-fluid interfaces within the machinery walls that deliver such particle-laden fluids is typically attributed to the fluid-induced shear stresses, which increase with the volume fraction of added particles. The objective of this work is to develop a rigorous strict upper bound for the tolerable volume fraction of particles that can be added, while remaining below a given stress threshold at a fluid-solid interface. To illustrate the bound's utility, the expression is applied to a series of classical flow regimes.

On Energy Inequality for the Problem on the Evolution of Two Fluids of Different Types Without Surface Tension

NASA Astrophysics Data System (ADS)

Denisova, Irina Vlad.

2015-03-01

The paper deals with the motion of two immiscible viscous fluids in a container, one of the fluids being compressible while another one being incompressible. The interface between the fluids is an unknown closed surface where surface tension is neglected. We assume the compressible fluid to be barotropic, the pressure being given by an arbitrary smooth increasing function. This problem is considered in anisotropic Sobolev-Slobodetskiǐ spaces. We show that the L 2-norms of the velocity and deviation of compressible fluid density from the mean value decay exponentially with respect to time. The proof is based on a local existence theorem (Denisova, Interfaces Free Bound 2:283-312, 2000) and on the idea of constructing a function of generalized energy, proposed by Padula (J Math Fluid Mech 1:62-77, 1999). In addition, we eliminate the restrictions for the viscosities which appeared in Denisova (Interfaces Free Bound 2:283-312, 2000).

Droplet Deformation in an Extensional Flow: The Role of Surfactant Physical Chemistry

NASA Technical Reports Server (NTRS)

Stebe, Kathleen J.

1996-01-01

Surfactant-induced Marangoni effects strongly alter the stresses exerted along fluid particle interfaces. In low gravity processes, these stresses can dictate the system behavior. The dependence of Marangoni effects on surfactant physical chemistry is not understood, severely impacting our ability to predict and control fluid particle flows. A droplet in an extensional flow allows the controlled study of stretching and deforming interfaces. The deformations of the drop allow both Marangoni stresses, which resist tangential shear, and Marangoni elasticities, which resist surface dilatation, to develop. This flow presents an ideal model system for studying these effects. Prior surfactant-related work in this flow considered a linear dependence of the surface tension on the surface concentration, valid only at dilute surface concentrations, or a non-linear framework at concentrations sufficiently dilute that the linear approximation was valid. The linear framework becomes inadequate for several reasons. The finite dimensions of surfactant molecules must be taken into account with a model that includes surfaces saturation. Nonideal interactions between adsorbed surfactant molecules alter the partitioning of surfactant between the bulk and the interface, the dynamics of surfactant adsorptive/desorptive exchange, and the sensitivity of the surface tension to adsorbed surfactant. For example, cohesion between hydrocarbon chains favors strong adsorption. Cohesion also slows the rate of desorption from interfaces, and decreases the sensitivity of the surface tension to adsorbed surfactant. Strong cohesive interactions result in first order surface phase changes with a plateau in the surface tension vs surface concentration. Within this surface concentration range, the surface tension is decoupled from surface concentration gradients. We are engaged in the study of the role of surfactant physical chemistry in determining the Marangoni stresses on a drop in an extensional flow in a numerical and experimental program. Using surfactants whose dynamics and equilibrium behavior have been characterized in our laboratory, drop deformation will be studied in ground-based experiment. In an accompanying numerical study, predictive drop deformations will be determined based on the isotherm and equation of state determined in our laboratory. This work will improve our abilities to predict and control all fluid particle flows.

Fluid management systems technology summaries

NASA Technical Reports Server (NTRS)

Stark, J. A.; Blatt, M. H.; Bennett, F. O., Jr.; Campbell, B. J.

1974-01-01

A summarization and categorization of the pertinent literature associated with fluid management systems technology having potential application to in-orbit fluid transfer and/or associated storage are presented. A literature search was conducted to obtain pertinent documents for review. Reports determined to be of primary significance were summarized in the following manner: (1) report identification, (2) objective(s) of the work, (3) description of pertinent work performed, (4) major results, and (5) comments of the reviewer. Pertinent figures are presented on a single facing page separate from the text. Specific areas covered are: fluid line dynamics and thermodynamics, low-g mass gauging, other instrumentation, stratification/pressurization, low-g vent systems, fluid mixing refrigeration and reliquefaction, and low-g interface control and liquid acquisition systems. Reports which were reviewed and not summarized, along with reasons for not summarizing, are also listed.

Molecular Momentum Transport at Fluid-Solid Interfaces in MEMS/NEMS: A Review

PubMed Central

Cao, Bing-Yang; Sun, Jun; Chen, Min; Guo, Zeng-Yuan

2009-01-01

This review is focused on molecular momentum transport at fluid-solid interfaces mainly related to microfluidics and nanofluidics in micro-/nano-electro-mechanical systems (MEMS/NEMS). This broad subject covers molecular dynamics behaviors, boundary conditions, molecular momentum accommodations, theoretical and phenomenological models in terms of gas-solid and liquid-solid interfaces affected by various physical factors, such as fluid and solid species, surface roughness, surface patterns, wettability, temperature, pressure, fluid viscosity and polarity. This review offers an overview of the major achievements, including experiments, theories and molecular dynamics simulations, in the field with particular emphasis on the effects on microfluidics and nanofluidics in nanoscience and nanotechnology. In Section 1 we present a brief introduction on the backgrounds, history and concepts. Sections 2 and 3 are focused on molecular momentum transport at gas-solid and liquid-solid interfaces, respectively. Summary and conclusions are finally presented in Section 4. PMID:20087458

Effective Field Theory of Surface-mediated Forces in Soft Matter

NASA Astrophysics Data System (ADS)

Yolcu, Cem

We propose a field theoretic formalism for describing soft surfaces modified by the presence of inclusions. Examples include particles trapped at a fluid-fluid interface, proteins attached to (or embedded in) a biological membrane, etc. We derive the energy functional for near-flat surfaces by an effective field theory approach. The two disparate length scales, particle sizes and inter-particle separations, afford the expansion parameters for controlling the accuracy of the effective theory, which is arbitrary in principle. We consider the following two surface types: (i) one where tension determines the behavior, such as a fluid-fluid interface (referred to as a film), and (ii) one where bending-elasticity dominates (referred to as a membrane). We also restrict to rigid inclusions with a circular footprint, and discuss generalizations briefly. As a result of the localized constraints imposed on the surface by the inclusions, the free energy of the system depends on their spatial arrangement, i.e. forces arise between them. Such surface-mediated interactions are believed to play an important role in the aggregation behavior of colloidal particles at interfaces and proteins on membranes. The interaction free energy consists of two parts: (i) the ground-state of the surface determined by possible deformations imposed by the particles, and (ii) the fluctuation correction. The former is analogous to classical electrostatics with the height profile of the surface playing the role of the electrostatic potential, while the latter is analogous to the Casimir effect and originates from the mere presence of constraints. We compute both interactions in truncated expansions. The efficiency of the formalism allows us to predict, with remarkable ease, quite a few orders of subleading corrections to existing results which are only valid when the inclusions are infinitely far apart. We also found that the few previous studies on finite distance corrections were incomplete. In addition to pairwise additive interactions, we compute the leading behavior of several many-body interactions, as well as subleading corrections where the leading contribution was previously calculated.

Study of the long-time dynamics of a viscous vortex sheet with a fully adaptive nonstiff method

NASA Astrophysics Data System (ADS)

Ceniceros, Hector D.; Roma, Alexandre M.

2004-12-01

A numerical investigation of the long-time dynamics of two immiscible two-dimensional fluids shearing past one another is presented. The fluids are incompressible and the interface between the bulk phases is subjected to surface tension. The simple case of density and viscosity matched fluids is considered. The two-dimensional Navier-Stokes equations are solved numerically with a fully adaptive nonstiff strategy based on the immersed boundary method. Dynamically adaptive mesh refinements are used to cover at all times the separately tracked fluid interface at the finest grid level. In addition, by combining adaptive front tracking, in the form of continuous interface marker equidistribution, with a predictor-corrector discretization an efficient method is introduced to successfully treat the well-known numerical difficulties associated with surface tension. The resulting numerical method can be used to compute stably and with high resolution the flow for wide-ranging Weber numbers but this study focuses on the computationally challenging cases for which elongated fingering and interface roll-up are observed. To assess the importance of the viscous and vortical effects in the interfacial dynamics the full viscous flow simulations are compared with inviscid counterparts computed with a state-of-the-art boundary integral method. In the examined cases of roll-up, it is found that in contrast to the inviscid flow in which the interface undergoes a topological reconfiguration, the viscous interface remarkably escapes self-intersection and rich long-time dynamics due to separation, transport, and diffusion of vorticity is observed. An even more striking motion occurs at an intermediate Weber number for which elongated interpenetrating fingers of fluid develop. In this case, it is found that the Kelvin-Helmholtz instability weakens due to shedding of vorticity and unlike the inviscid counterpart in which there is indefinite finger growth the viscous interface is pulled back by surface tension. As the interface recedes, thin necks connecting pockets of fluid with the rest of the fingers form. Narrow jets are observed at the necking regions but the vorticity there ultimately appears to be insufficient to drain all the fluid and cause reconnection. However, at another point, two disparate portions of the interface come in close proximity as the interface continues to contract. Large curvature points and an intense concentration of vorticity are observed in this region and then the motion is abruptly terminated by the collapse of the interface.

Wave turbulence in a two-layer fluid: Coupling between free surface and interface waves

NASA Astrophysics Data System (ADS)

Falcon, Eric; Issenmann, Bruno; Laroche, Claude

2017-11-01

We experimentally study gravity-capillary wave turbulence on the interface between two immiscible fluids of close density with free upper surface. We locally measure the wave height at the interface between both fluids by means of a highly sensitive laser Doppler vibrometer. We show that the inertial range of the capillary wave turbulence regime is significantly extended when the upper fluid depth is increased: The crossover frequency between the gravity and capillary wave turbulence regimes is found to decrease whereas the dissipative cut-off frequency of the spectrum is found to increase. We explain these observations by the progressive decoupling between waves propagating at the interface and the ones at the free surface, using the full dispersion relation of gravity-capillary waves in a two-layer fluid of finite depths. The cut-off evolution is due to the disappearance of parasitic capillaries responsible for the main wave dissipation for a single fluid. B. Issenmann, C. Laroche & E. Falcon, EPL 116, 64005 (2016) published online 16 feb. 2017. This work has been partially supported by CNRS (1-year postdoctoral funding), ANR Turbulon 12-BS04-0005, and ANR Dysturb 2017.

Dust Tolerant Commodity Transfer Interface Mechanisms for Planetary Surfaces

NASA Technical Reports Server (NTRS)

Townsend, Ivan I.; Mueller, Robert P.; Tamasy, Gabor J.

2014-01-01

Regolith is present on most planetary surfaces such as Earth's moon, Mars, and Asteroids. If human crews and robotic machinery are to operate on these regolith covered surfaces, they must face the consequences of interacting with regolith fines which consist of particles below 100 microns in diameter down to as small as submicron scale particles. Such fine dust will intrude into mechanisms and interfaces causing a variety of problems such as contamination of clean fluid lines, jamming of mechanisms and damaging connector seals and couplings. Since multiple elements must be assembled in space for system level functionality, it will be inevitable that interfaces will be necessary for structural connections, and to pass commodities such as cryogenic liquid propellants, purge and buffer gases, water, breathing air, pressurizing gases, heat exchange fluids, power and data. When fine regolith dust is present in the environment it can be lofted into interfaces where it can compromise the utility of the interface by preventing the connections from being successfully mated, or by inducing fluid leaks or degradation of power and data transmission. A dust tolerant, hand held "quick-disconnect" cryogenic fluids connector housing has been developed at NASA KSC which can be used by astronaut crews to connect flex lines that will transfer propellants and other useful fluids to the end user. In addition, a dust tolerant, automated, cryogenic fluid, multiple connector, power and data interface mechanism prototype has been developed, fabricated and demonstrated by NASA at Kennedy Space Center (KSC). The design and operation of these prototypes are explained and discussed.

An interface tracking model for droplet electrocoalescence.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Erickson, Lindsay Crowl

This report describes an Early Career Laboratory Directed Research and Development (LDRD) project to develop an interface tracking model for droplet electrocoalescence. Many fluid-based technologies rely on electrical fields to control the motion of droplets, e.g. microfluidic devices for high-speed droplet sorting, solution separation for chemical detectors, and purification of biodiesel fuel. Precise control over droplets is crucial to these applications. However, electric fields can induce complex and unpredictable fluid dynamics. Recent experiments (Ristenpart et al. 2009) have demonstrated that oppositely charged droplets bounce rather than coalesce in the presence of strong electric fields. A transient aqueous bridge forms betweenmore » approaching drops prior to pinch-off. This observation applies to many types of fluids, but neither theory nor experiments have been able to offer a satisfactory explanation. Analytic hydrodynamic approximations for interfaces become invalid near coalescence, and therefore detailed numerical simulations are necessary. This is a computationally challenging problem that involves tracking a moving interface and solving complex multi-physics and multi-scale dynamics, which are beyond the capabilities of most state-of-the-art simulations. An interface-tracking model for electro-coalescence can provide a new perspective to a variety of applications in which interfacial physics are coupled with electrodynamics, including electro-osmosis, fabrication of microelectronics, fuel atomization, oil dehydration, nuclear waste reprocessing and solution separation for chemical detectors. We present a conformal decomposition finite element (CDFEM) interface-tracking method for the electrohydrodynamics of two-phase flow to demonstrate electro-coalescence. CDFEM is a sharp interface method that decomposes elements along fluid-fluid boundaries and uses a level set function to represent the interface.« less

A Matlab user interface for the statistically assisted fluid registration algorithm and tensor-based morphometry

NASA Astrophysics Data System (ADS)

Yepes-Calderon, Fernando; Brun, Caroline; Sant, Nishita; Thompson, Paul; Lepore, Natasha

2015-01-01

Tensor-Based Morphometry (TBM) is an increasingly popular method for group analysis of brain MRI data. The main steps in the analysis consist of a nonlinear registration to align each individual scan to a common space, and a subsequent statistical analysis to determine morphometric differences, or difference in fiber structure between groups. Recently, we implemented the Statistically-Assisted Fluid Registration Algorithm or SAFIRA,1 which is designed for tracking morphometric differences among populations. To this end, SAFIRA allows the inclusion of statistical priors extracted from the populations being studied as regularizers in the registration. This flexibility and degree of sophistication limit the tool to expert use, even more so considering that SAFIRA was initially implemented in command line mode. Here, we introduce a new, intuitive, easy to use, Matlab-based graphical user interface for SAFIRA's multivariate TBM. The interface also generates different choices for the TBM statistics, including both the traditional univariate statistics on the Jacobian matrix, and comparison of the full deformation tensors.2 This software will be freely disseminated to the neuroimaging research community.

Understanding the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions

NASA Astrophysics Data System (ADS)

Dahms, Rainer N.

2016-04-01

A generalized framework for multi-component liquid injections is presented to understand and predict the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions. The analysis focuses on the thermodynamic structure and the immiscibility state of representative gas-liquid interfaces. The most modern form of Helmholtz energy mixture state equation is utilized which exhibits a unique and physically consistent behavior over the entire two-phase regime of fluid densities. It is combined with generalized models for non-linear gradient theory and for liquid injections to quantify multi-component two-phase interface structures in global thermal equilibrium. Then, the Helmholtz free energy is minimized which determines the interfacial species distribution as a consequence. This minimal free energy state is demonstrated to validate the underlying assumptions of classic two-phase theory and spray atomization. However, under certain engine-relevant conditions for which corroborating experimental data are presented, this requirement for interfacial thermal equilibrium becomes unsustainable. A rigorously derived probability density function quantifies the ability of the interface to develop internal spatial temperature gradients in the presence of significant temperature differences between injected liquid and ambient gas. Then, the interface can no longer be viewed as an isolated system at minimal free energy. Instead, the interfacial dynamics become intimately connected to those of the separated homogeneous phases. Hence, the interface transitions toward a state in local equilibrium whereupon it becomes a dense-fluid mixing layer. A new conceptual view of a transitional liquid injection process emerges from a transition time scale analysis. Close to the nozzle exit, the two-phase interface still remains largely intact and more classic two-phase processes prevail as a consequence. Further downstream, however, the transition to dense-fluid mixing generally occurs before the liquid length is reached. The significance of the presented modeling expressions is established by a direct comparison to a reduced model, which utilizes widely applied approximations but fundamentally fails to capture the physical complexity discussed in this paper.

Marangoni Effects of a Drop in an Extensional Flow: The Role of Surfactant Physical Chemistry

NASA Technical Reports Server (NTRS)

Stebe, Kathleen J.; Balasubramaniam, R. (Technical Monitor)

2002-01-01

While the changes in stresses caused by surfactant adsorption on non-deforming interfaces have been fairly well established, prior to this work, there were few studies addressing how surfactants alter stresses on strongly deforming interfaces. We chose the model problem of a drop in a uniaxial extensional flow to study these stress conditions To model surfactant effects at fluid interfaces, a proper description of the dependence of the surface tension on surface concentration, the surface equation of state, is required. We have adopted a surface equation of state that accounts for the maximum coverage limit; that is, because surfactants have a finite cross sectional area, there is an upper bound to the amount of surfactant that can adsorb in a monolayer. The surface tension reduces strongly only when this maximum coverage is approached. Since the Marangoni stresses go as the derivative of the surface equation of state times the surface concentration gradient, the non-linear equation of state determines both the effect of surfactants in the normal stress jump, (which is balanced by the product of the mean curvature of the interface times the surface tension), and the tangential stress jump, which is balanced by Marangoni stresses. First, the effects of surface coverage and intermolecular interactions among surfactants which drive aggregation of surfactants in the interface were studied. (see Pawar and Stebe, Physics of Fluids).

A Steady State and Quasi-Steady Interface Between the Generalized Fluid System Simulation Program and the SINDA/G Thermal Analysis Program

NASA Technical Reports Server (NTRS)

Schallhorn, Paul; Majumdar, Alok; Tiller, Bruce

2001-01-01

A general purpose, one dimensional fluid flow code is currently being interfaced with the thermal analysis program SINDA/G. The flow code, GFSSP, is capable of analyzing steady state and transient flow in a complex network. The flow code is capable of modeling several physical phenomena including compressibility effects, phase changes, body forces (such as gravity and centrifugal) and mixture thermodynamics for multiple species. The addition of GFSSP to SINDA/G provides a significant improvement in convective heat transfer modeling for SINDA/G. The interface development is conducted in multiple phases. This paper describes the first phase of the interface which allows for steady and quasisteady (unsteady solid, steady fluid) conjugate heat transfer modeling.

Focal cartilage defect compromises fluid-pressure dependent load support in the knee joint.

PubMed

Dabiri, Yaghoub; Li, LePing

2015-06-01

A focal cartilage defect involves tissue loss or rupture. Altered mechanics in the affected joint may play an essential role in the onset and progression of osteoarthritis. The objective of the present study was to determine the compromised load support in the human knee joint during defect progression from the cartilage surface to the cartilage-bone interface. Ten normal and defect cases were simulated with a previously tested 3D finite element model of the knee. The focal defects were considered in both condyles within high load-bearing regions. Fluid pressurization, anisotropic fibril-reinforcement, and depth-dependent mechanical properties were considered for the articular cartilages and menisci. The results showed that a small cartilage defect could cause 25% reduction in the load support of the knee joint due to a reduced capacity of fluid pressurization in the defect cartilage. A partial-thickness defect could cause a fluid pressure decrease or increase in the remaining underlying cartilage depending on the defect depth. A cartilage defect also increased the shear strain at the cartilage-bone interface, which was more significant with a full-thickness defect. The effect of cartilage defect on the fluid pressurization also depended on the defect sites and contact conditions. In conclusion, a focal cartilage defect causes a fluid-pressure dependent load reallocation and a compromised load support in the joint, which depend on the defect depth, site, and contact condition. Copyright © 2015 John Wiley & Sons, Ltd.

Calculation of nanodrop profile from fluid density distribution.

PubMed

Berim, Gersh O; Ruckenstein, Eli

2016-05-01

Two approaches are examined, which can be used to determine the drop profile from the fluid density distributions (FDDs) obtained on the basis of microscopic theories. For simplicity, only two-dimensional (cylindrical, or axisymmetrical) distributions are examined and it is assumed that the fluid is either in contact with a smooth solid or separated from the smooth solid by a lubricating liquid film. The first approach is based on the sharp-kink interface approximation in which the density of the liquid inside and the density of the vapor outside the drop are constant with the exception of the surface layer of the drop where the density is different from the above ones. In this case, the drop profile was calculated by minimizing the total potential energy of the system. The second approach is based on a nonuniform FDD obtained either by the density functional theory or molecular dynamics simulations. To determine the drop profile from such an FDD, which does not contain sharp interfaces, three procedures can be used. In the first two procedures, P1 and P2, the one-dimensional FDDs along straight lines which are parallel to the surface of the solid are extracted from the two-dimensional FDD. Each of those one-dimensional FDDs has a vapor-liquid interface at which the fluid density changes from vapor-like to liquid-like values. Procedure P1 uses the locations of the equimolar dividing surfaces for the one-dimensional FDDs as points of the drop profile. Procedure P2 is based on the assumption that the fluid density is constant on the surface of the drop, that density being selected either arbitrarily or as a fluid density at the location of the equimolar dividing surface for one of the one-dimensional FDDs employed in procedure P1. In the third procedure, P3, which is suggested for the first time in this paper, the one-dimensional FDDs are taken along the straight lines passing through a selected point inside the drop (radial line). Then, the drop profile is calculated like in procedure P1. It is shown, that procedure P3 provides a drop profile which is more reasonable than the other ones. Relationship of the discussed procedures to those used in image analysis is briefly discussed. Copyright © 2016 Elsevier B.V. All rights reserved.

Drag penalty due to the asperities in the substrate of super-hydrophobic and liquid infused surfaces

NASA Astrophysics Data System (ADS)

Garcia Cartagena, Edgardo J.; Arenas, Isnardo; Leonardi, Stefano

2017-11-01

Direct numerical simulations of two superposed fluids in a turbulent channel with a textured surface made of pinnacles of random height have been performed. The viscosity ratio between the two fluids are N =μo /μi = 50 (μo and μi are the viscosities of outer and inner fluid respectively) mimicking a super-hydrophobic surface (water over air) and N=2.5 (water over heptane) resembling a liquid infused surface. Two set of simulations have been performed varying the Reynolds number, Reτ = 180 and Reτ = 390 . The interface between the two fluids is flat simulating infinite surface tension. The position of the interface between the two fluids has been varied in the vertical direction from the base of the substrate (what would be a rough wall) to the highest point of the roughness. Drag reduction is very sensitive to the position of the interface between the two fluids. Asperities above the interface induce a large form drag and diminish considerably the drag reduction. When the mean height of the surface measured from the interface in the outer fluid is greater than one wall unit, k+ > 1 , the drag increases with respect to a smooth wall. Present results provide a guideline to the accuracy required in manufacturing super-hydrophobic and liquid infused surfaces. This work was supported under ONR MURI Grants N00014-12-0875 and N00014-12- 1-0962, Program Manager Dr. Ki-Han Kim. Numerical simulations were performed on the Texas Advanced Computer Center.

Effects of surface tension and intraluminal fluid on mechanics of small airways.

PubMed

Hill, M J; Wilson, T A; Lambert, R K

1997-01-01

Airway constriction is accompanied by folding of the mucosa to form ridges that run axially along the inner surface of the airways. The mucosa has been modeled (R. K. Lambert. J. Appl. Physiol. 71:666-673, 1991) as a thin elastic layer with a finite bending stiffness, and the contribution of its bending stiffness to airway elastance has been computed. In this study, we extend that work by including surface tension and intraluminal fluid in the model. With surface tension, the pressure on the inner surface of the elastic mucosa is modified by the pressure difference across the air-liquid interface. As folds form in the mucosa, intraluminal fluid collects in pools in the depressions formed by the folds, and the curvature of the air-liquid interface becomes nonuniform. If the amount of intraluminal fluid is small, < 2% of luminal volume, the pools of intraluminal fluid are small, the air-liquid interface nearly coincides with the surface of the mucosa, and the area of the air-liquid interface remains constant as airway cross-sectional area decreases. In that case, surface energy is independent of airway area, and surface tension has no effect on airway mechanics. If the amount of intraluminal fluid is > 2%, the area of the air-liquid interface decreases as airway cross-sectional area decreases. and surface tension contributes to airway compression. The model predicts that surface tension plus intraluminal fluid can cause an instability in the area-pressure curve of small airways. This instability provides a mechanism for abrupt airway closure and abrupt reopening at a higher opening pressure.

HPC in Basin Modeling: Simulating Mechanical Compaction through Vertical Effective Stress using Level Sets

NASA Astrophysics Data System (ADS)

McGovern, S.; Kollet, S. J.; Buerger, C. M.; Schwede, R. L.; Podlaha, O. G.

2017-12-01

In the context of sedimentary basins, we present a model for the simulation of the movement of ageological formation (layers) during the evolution of the basin through sedimentation and compactionprocesses. Assuming a single phase saturated porous medium for the sedimentary layers, the modelfocuses on the tracking of the layer interfaces, through the use of the level set method, as sedimentationdrives fluid-flow and reduction of pore space by compaction. On the assumption of Terzaghi's effectivestress concept, the coupling of the pore fluid pressure to the motion of interfaces in 1-D is presented inMcGovern, et.al (2017) [1] .The current work extends the spatial domain to 3-D, though we maintain the assumption ofvertical effective stress to drive the compaction. The idealized geological evolution is conceptualized asthe motion of interfaces between rock layers, whose paths are determined by the magnitude of a speedfunction in the direction normal to the evolving layer interface. The speeds normal to the interface aredependent on the change in porosity, determined through an effective stress-based compaction law,such as the exponential Athy's law. Provided with the speeds normal to the interface, the level setmethod uses an advection equation to evolve a potential function, whose zero level set defines theinterface. Thus, the moving layer geometry influences the pore pressure distribution which couplesback to the interface speeds. The flexible construction of the speed function allows extension, in thefuture, to other terms to represent different physical processes, analogous to how the compaction rulerepresents material deformation.The 3-D model is implemented using the generic finite element method framework Deal II,which provides tools, building on p4est and interfacing to PETSc, for the massively parallel distributedsolution to the model equations [2]. Experiments are being run on the Juelich Supercomputing Center'sJureca cluster. [1] McGovern, et.al. (2017). Novel basin modelling concept for simulating deformation from mechanical compaction using level sets. Computational Geosciences, SI:ECMOR XV, 1-14.[2] Bangerth, et. al. (2011). Algorithms and data structures for massively parallel generic adaptive finite element codes. ACM Transactions on Mathematical Software (TOMS), 38(2):14.

Lattice Boltzmann Method for Spacecraft Propellant Slosh Simulation

NASA Technical Reports Server (NTRS)

Orr, Jeb S.; Powers, Joseph F.; Yang, Hong Q

2015-01-01

A scalable computational approach to the simulation of propellant tank sloshing dynamics in microgravity is presented. In this work, we use the lattice Boltzmann equation (LBE) to approximate the behavior of two-phase, single-component isothermal flows at very low Bond numbers. Through the use of a non-ideal gas equation of state and a modified multiple relaxation time (MRT) collision operator, the proposed method can simulate thermodynamically consistent phase transitions at temperatures and density ratios consistent with typical spacecraft cryogenic propellants, for example, liquid oxygen. Determination of the tank forces and moments is based upon a novel approach that relies on the global momentum conservation of the closed fluid domain, and a parametric wall wetting model allows tuning of the free surface contact angle. Development of the interface is implicit and no interface tracking approach is required. A numerical example illustrates the method's application to prediction of bulk fluid behavior during a spacecraft ullage settling maneuver.

Lattice Boltzmann Method for Spacecraft Propellant Slosh Simulation

NASA Technical Reports Server (NTRS)

Orr, Jeb S.; Powers, Joseph F.; Yang, Hong Q.

2015-01-01

A scalable computational approach to the simulation of propellant tank sloshing dynamics in microgravity is presented. In this work, we use the lattice Boltzmann equation (LBE) to approximate the behavior of two-phase, single-component isothermal flows at very low Bond numbers. Through the use of a non-ideal gas equation of state and a modified multiple relaxation time (MRT) collision operator, the proposed method can simulate thermodynamically consistent phase transitions at temperatures and density ratios consistent with typical spacecraft cryogenic propellants, for example, liquid oxygen. Determination of the tank forces and moments relies upon the global momentum conservation of the fluid domain, and a parametric wall wetting model allows tuning of the free surface contact angle. Development of the interface is implicit and no interface tracking approach is required. Numerical examples illustrate the method's application to predicting bulk fluid motion including lateral propellant slosh in low-g conditions.

The Investigation of Ghost Fluid Method for Simulating the Compressible Two-Medium Flow

NASA Astrophysics Data System (ADS)

Lu, Hai Tian; Zhao, Ning; Wang, Donghong

2016-06-01

In this paper, we investigate the conservation error of the two-dimensional compressible two-medium flow simulated by the front tracking method. As the improved versions of the original ghost fluid method, the modified ghost fluid method and the real ghost fluid method are selected to define the interface boundary conditions, respectively, to show different effects on the conservation error. A Riemann problem is constructed along the normal direction of the interface in the front tracking method, with the goal of obtaining an efficient procedure to track the explicit sharp interface precisely. The corresponding Riemann solutions are also used directly in these improved ghost fluid methods. Extensive numerical examples including the sod tube and the shock-bubble interaction are tested to calculate the conservation error. It is found that these two ghost fluid methods have distinctive performances for different initial conditions of the flow field, and the related conclusions are made to suggest the best choice for the combination.

Interface projection techniques for fluid-structure interaction modeling with moving-mesh methods

NASA Astrophysics Data System (ADS)

Tezduyar, Tayfun E.; Sathe, Sunil; Pausewang, Jason; Schwaab, Matthew; Christopher, Jason; Crabtree, Jason

2008-12-01

The stabilized space-time fluid-structure interaction (SSTFSI) technique developed by the Team for Advanced Flow Simulation and Modeling (T★AFSM) was applied to a number of 3D examples, including arterial fluid mechanics and parachute aerodynamics. Here we focus on the interface projection techniques that were developed as supplementary methods targeting the computational challenges associated with the geometric complexities of the fluid-structure interface. Although these supplementary techniques were developed in conjunction with the SSTFSI method and in the context of air-fabric interactions, they can also be used in conjunction with other moving-mesh methods, such as the Arbitrary Lagrangian-Eulerian (ALE) method, and in the context of other classes of FSI applications. The supplementary techniques currently consist of using split nodal values for pressure at the edges of the fabric and incompatible meshes at the air-fabric interfaces, the FSI Geometric Smoothing Technique (FSI-GST), and the Homogenized Modeling of Geometric Porosity (HMGP). Using split nodal values for pressure at the edges and incompatible meshes at the interfaces stabilizes the structural response at the edges of the membrane used in modeling the fabric. With the FSI-GST, the fluid mechanics mesh is sheltered from the consequences of the geometric complexity of the structure. With the HMGP, we bypass the intractable complexities of the geometric porosity by approximating it with an “equivalent”, locally-varying fabric porosity. As test cases demonstrating how the interface projection techniques work, we compute the air-fabric interactions of windsocks, sails and ringsail parachutes.

STABILITY OF A CYLINDRICAL SOLUTE-SOLVENT INTERFACE: EFFECT OF GEOMETRY, ELECTROSTATICS, AND HYDRODYNAMICS.

PubMed

Li, B O; Sun, Hui; Zhou, Shenggao

The solute-solvent interface that separates biological molecules from their surrounding aqueous solvent characterizes the conformation and dynamics of such molecules. In this work, we construct a solvent fluid dielectric boundary model for the solvation of charged molecules and apply it to study the stability of a model cylindrical solute-solvent interface. The motion of the solute-solvent interface is defined to be the same as that of solvent fluid at the interface. The solvent fluid is assumed to be incompressible and is described by the Stokes equation. The solute is modeled simply by the ideal-gas law. All the viscous force, hydrostatic pressure, solute-solvent van der Waals interaction, surface tension, and electrostatic force are balanced at the solute-solvent interface. We model the electrostatics by Poisson's equation in which the solute-solvent interface is treated as a dielectric boundary that separates the low-dielectric solute from the high-dielectric solvent. For a cylindrical geometry, we find multiple cylindrically shaped equilibrium interfaces that describe polymodal (e.g., dry and wet) states of hydration of an underlying molecular system. These steady-state solutions exhibit bifurcation behavior with respect to the charge density. For their linearized systems, we use the projection method to solve the fluid equation and find the dispersion relation. Our asymptotic analysis shows that, for large wavenumbers, the decay rate is proportional to wavenumber with the proportionality half of the ratio of surface tension to solvent viscosity, indicating that the solvent viscosity does affect the stability of a solute-solvent interface. Consequences of our analysis in the context of biomolecular interactions are discussed.

Surface effects on friction-induced fluid heating in nanochannel flows.

PubMed

Li, Zhigang

2009-02-01

We investigate the mechanism of friction-induced fluid heating under the influence of surfaces. The temperature distributions of liquid argon and helium in nanoscale Poiseuille flows are studied through molecular dynamics simulations. It is found that the fluid heating is mainly caused by the viscous friction in the fluid when the external force is small and there is no slip at the fluid-solid interface. When the external force is larger than the fluid-surface binding force, the friction at the fluid-solid interface dominates over the internal friction of the fluid and is the major contribution to fluid heating. An asymmetric temperature gradient in the fluid is developed in the case of nonidentical walls and the general temperature gradient may change sign as the dominant heating factor changes from internal to interfacial friction with increasing external force. The effect of temperature on the fluid heating is also discussed.

Structure, thermodynamics, and solubility in tetromino fluids.

PubMed

Barnes, Brian C; Siderius, Daniel W; Gelb, Lev D

2009-06-16

To better understand the self-assembly of small molecules and nanoparticles adsorbed at interfaces, we have performed extensive Monte Carlo simulations of a simple lattice model based on the seven hard "tetrominoes", connected shapes that occupy four lattice sites. The equations of state of the pure fluids and all of the binary mixtures are determined over a wide range of density, and a large selection of multicomponent mixtures are also studied at selected conditions. Calculations are performed in the grand canonical ensemble and are analogous to real systems in which molecules or nanoparticles reversibly adsorb to a surface or interface from a bulk reservoir. The model studied is athermal; objects in these simulations avoid overlap but otherwise do not interact. As a result, all of the behavior observed is entropically driven. The one-component fluids all exhibit marked self-ordering tendencies at higher densities, with quite complex structures formed in some cases. Significant clustering of objects with the same rotational state (orientation) is also observed in some of the pure fluids. In all of the binary mixtures, the two species are fully miscible at large scales, but exhibit strong species-specific clustering (segregation) at small scales. This behavior persists in multicomponent mixtures; even in seven-component mixtures of all the shapes there is significant association between objects of the same shape. To better understand these phenomena, we calculate the second virial coefficients of the tetrominoes and related quantities, extract thermodynamic volume of mixing data from the simulations of binary mixtures, and determine Henry's law solubilities for each shape in a variety of solvents. The overall picture obtained is one in which complementarity of both the shapes of individual objects and the characteristic structures of different fluids are important in determining the overall behavior of a fluid of a given composition, with sometimes counterintuitive results. Finally, we note that no sharp phase transitions are observed but that this appears to be due to the small size of the objects considered. It is likely that complex phase behavior may be found in systems of larger polyominoes.

Quantification of the Mass Transfer at Fluid Interfaces in Microfluidic Channels

NASA Astrophysics Data System (ADS)

Wismeth, Carina; Manhart, Michael; Niessner, Reinhard; Baumann, Thomas

2017-04-01

Mass transfer rates at interfaces in a complex porous media are relevant in many environmental applications and control the functions of natural filter systems in subsurface environments. The mass transfer at fluid interfaces is associated with interface convection caused by local inhomogeneities in interface tension and hydrodynamic instabilities at the interface. If there is a surface tension gradient along the surface a shear stress jump is generated that results in fluid motion along the surface that is called Marangoni effect. These spontaneous convection currents can lead to an increased mass transfer of the transition component at the phase boundary and to an increased mixing of the phases. Therefore compensatory currents at the interface can have a significant influence on the subsurface transport of contaminants in the groundwater area, especially in the vadose zone. Using microfluidic channels and advanced experimental techniques it is possible to measure the fluid flow and mass transfer rates directly and to quantify the effect of the Marangoni convection on the mass transfer at interfaces between a non-aqueous liquid and water with high temporal and spatial resolution. The use of fluorescent particles as well as the recording and analysis of their trajectories is intended to visualize interfacial processes and to quantify the mass transfer at fluid phase boundaries. Concentration gradients at the interface are analysed by spectroscopic methods and allow an assessment of the enrichment and depletion at the phase boundaries. Extensive test series provide the experimental basis for quantifying and analysing the impact of the Marangoni effect on the mass transfer rates at interfaces in porous media in subsurface aquatic environments. Within this research project we concentrate on the effect of Marangoni convection on the mass transfer near an 1-octanol-water interface, which serves as a well defined proxy for non-aqueous phase liquids in porous media. Experiments and a numerical simulation are closely coupled to provide a generic data set with high reproducibility and used to obtain highly resolved three-dimensional data of mass transfer in two- and three-phase systems to foster the understanding of subsurface transport, especially in the vadose zone.

The importance of fluctuations in fluid mixing.

PubMed

Kadau, Kai; Rosenblatt, Charles; Barber, John L; Germann, Timothy C; Huang, Zhibin; Carlès, Pierre; Alder, Berni J

2007-05-08

A ubiquitous example of fluid mixing is the Rayleigh-Taylor instability, in which a heavy fluid initially sits atop a light fluid in a gravitational field. The subsequent development of the unstable interface between the two fluids is marked by several stages. At first, each interface mode grows exponentially with time before transitioning to a nonlinear regime characterized by more complex hydrodynamic mixing. Unfortunately, traditional continuum modeling of this process has generally been in poor agreement with experiment. Here, we indicate that the natural, random fluctuations of the flow field present in any fluid, which are neglected in continuum models, can lead to qualitatively and quantitatively better agreement with experiment. We performed billion-particle atomistic simulations and magnetic levitation experiments with unprecedented control of initial interface conditions. A comparison between our simulations and experiments reveals good agreement in terms of the growth rate of the mixing front as well as the new observation of droplet breakup at later times. These results improve our understanding of many fluid processes, including interface phenomena that occur, for example, in supernovae, the detachment of droplets from a faucet, and ink jet printing. Such instabilities are also relevant to the possible energy source of inertial confinement fusion, in which a millimeter-sized capsule is imploded to initiate nuclear fusion reactions between deuterium and tritium. Our results suggest that the applicability of continuum models would be greatly enhanced by explicitly including the effects of random fluctuations.

Microfluidic on-chip fluorescence-activated interface control system

PubMed Central

Haiwang, Li; Nguyen, N. T.; Wong, T. N.; Ng, S. L.

2010-01-01

A microfluidic dynamic fluorescence-activated interface control system was developed for lab-on-a-chip applications. The system consists of a straight rectangular microchannel, a fluorescence excitation source, a detection sensor, a signal conversion circuit, and a high-voltage feedback system. Aqueous NaCl as conducting fluid and aqueous glycerol as nonconducting fluid were introduced to flow side by side into the straight rectangular microchannel. Fluorescent dye was added to the aqueous NaCl to work as a signal representing the interface position. Automatic control of the liquid interface was achieved by controlling the electroosmotic effect that exists only in the conducting fluid using a high-voltage feedback system. A LABVIEW program was developed to control the output of high-voltage power supply according the actual interface position, and then the interface position is modified as the output of high-voltage power supply. At last, the interface can be moved to the desired position automatically using this feedback system. The results show that the system presented in this paper can control an arbitrary interface location in real time. The effects of viscosity ratio, flow rates, and polarity of electric field were discussed. This technique can be extended to switch the sample flow and droplets automatically. PMID:21173886

Hydraulic pressures generated in magnetic ionic liquids by paramagnetic fluid/air interfaces inside of uniform tangential magnetic fields.

PubMed

Scovazzo, Paul; Portugal, Carla A M; Rosatella, Andreia A; Afonso, Carlos A M; Crespo, João G

2014-08-15

Magnetic Ionic Liquid (MILs), novel magnetic molecules that form "pure magnetic liquids," will follow the Ferrohydrodynamic Bernoulli Relationship. Based on recent literature, the modeling of this fluid system is an open issue and potentially controversial. We imposed uniform magnetic fields parallel to MIL/air interfaces where the capillary forces were negligible, the Quincke Problem. The size and location of the bulk fluid as well as the size and location of the fluid/air interface inside of the magnetic field were varied. MIL properties varied included the density, magnetic susceptibility, chemical structure, and magnetic element. Uniform tangential magnetic fields pulled the MILs up counter to gravity. The forces per area were not a function of the volume, the surface area inside of the magnetic field, or the volume displacement. However, the presence of fluid/air interfaces was necessary for the phenomena. The Ferrohydrodynamic Bernoulli Relationship predicted the phenomena with the forces being directly related to the fluid's volumetric magnetic susceptibility and the square of the magnetic field strength. [emim][FeCl4] generated the greatest hydraulic head (64-mm or 910 Pa at 1.627 Tesla). This work could aid in experimental design, when free surfaces are involved, and in the development of MIL applications. Copyright © 2014 Elsevier Inc. All rights reserved.

Experiments on the Richtmyer-Meshkov Instability of Incompressible Fluids

NASA Technical Reports Server (NTRS)

Jacobs, J.; Niederhaus, C.

2000-01-01

Richtmyer-Meshkov (R-M) instability occurs when two different density fluids are impulsively accelerated in the direction normal to their nearly planar interface. The instability causes small perturbations on the interface to grow and possibly become turbulent given the proper initial conditions. R-M instability is similar to the Rayleigh-Taylor (R-T) instability, which is generated when the two fluids undergo a constant acceleration. R-M instability is a fundamental fluid instability that is important to fields ranging from astrophysics to high-speed combustion. For example, R-M instability is currently the limiting factor in achieving a net positive yield with inertial confinement fusion. The experiments described here utilize a novel technique that circumvents many of the experimental difficulties previously limiting the study of the R-M instability. A Plexiglas tank contains two unequal density liquids and is gently oscillated horizontally to produce a controlled initial fluid interface shape. The tank is mounted to a sled on a high speed, low friction linear rail system, constraining the main motion to the vertical direction. The sled is released from an initial height and falls vertically until it bounces off of a movable spring, imparting an impulsive acceleration in the upward direction. As the sled travels up and down the rails, the spring retracts out of the way, allowing the instability to evolve in free-fall until impacting a shock absorber at the end of the rails. The impulsive acceleration provided to the system is measured by a piezoelectric accelerometer mounted on the tank, and a capacitive accelerometer measures the low-level drag of the bearings. Planar Laser-Induced Fluorescence is used for flow visualization, which uses an Argon ion laser to illuminate the flow and a CCD camera, mounted to the sled, to capture images of the interface. This experimental study investigates the instability of an interface between incompressible, miscible liquids with an initial sinusoidal perturbation. The amplitude of the disturbance during the experiment is measured and compared to theory. The results show good agreement (within 10%) with linear stability theory up to nondimensional amplitude ka = 0.7 (wavenumber x amplitude). These results hold true for an initial ka (before acceleration) of -0.7 less than ka less than -0.06, while the linear theory was developed for absolute value of ka much less than 1. In addition, a third order weakly nonlinear perturbation theory is shown to be accurate for amplitudes as large as ka = 1.3, even though the interface becomes double-valued at ka = 1.1. As time progresses, the vorticity on the interface concentrates, and the interface spirals around the alternating sign vortex centers to form a mushroom pattern. At higher Reynolds Number (based on circulation), an instability of the vortex cores has been observed. While time limitations of the apparatus prevent determination of a critical Reynolds Number, the lowest Reynolds Number this vortex instability has been observed at is 5000.

Computational and Experimental Investigations of the Molecular Scale Structure and Dynamics of Gologically Important Fluids and Mineral-Fluid Interfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bowers, Geoffrey

United States Department of Energy grant DE-FG02-10ER16128, “Computational and Spectroscopic Investigations of the Molecular Scale Structure and Dynamics of Geologically Important Fluids and Mineral-Fluid Interfaces” (Geoffrey M. Bowers, P.I.) focused on developing a molecular-scale understanding of processes that occur in fluids and at solid-fluid interfaces using the combination of spectroscopic, microscopic, and diffraction studies with molecular dynamics computer modeling. The work is intimately tied to the twin proposal at Michigan State University (DOE DE-FG02-08ER15929; same title: R. James Kirkpatrick, P.I. and A. Ozgur Yazaydin, co-P.I.).

Shock interaction with a two-gas interface in a novel dual-driver shock tube

NASA Astrophysics Data System (ADS)

Labenski, John R.

Fluid instabilities exist at the interface between two fluids having different densities if the flow velocity and density gradient are anti-parallel or if a shock wave crosses the boundary. The former case is called the Rayleigh-Taylor (R-T) instability and the latter, the Richtmyer-Meshkov (R-M) instability. Small initial perturbations on the interface destabilize and grow into larger amplitude structures leading to turbulent mixing. Instabilities of this type are seen in inertial confinement fusion (ICF) experiments, laser produced plasmas, supernova explosions, and detonations. A novel dual-driver shock tube was used to investigate the growth rate of the R-M instability. One driver is used to create an argon-refrigerant interface, and the other at the opposite end of the driven section generates a shock to force the interface with compressible flows behind the shock. The refrigerant gas in the first driver is seeded with sub-micron oil droplets for visualization of the interface. The interface travels down the driven section past the test section for a fixed amount of time. A stronger shock of Mach 1.1 to 1.3 drives the interface back past the test section where flow diagnostics are positioned. Two schlieren systems record the density fluctuations while light scattering detectors record the density of the refrigerant as a function of position over the interface. A pair of digital cameras take stereo images of the interface, as mapped out by the tracer particles under illumination by a Q-switched ruby laser. The amount of time that the interface is allowed to travel up the driven section determines the interaction time as a control. Comparisons made between the schlieren signals, light scattering detector outputs, and the images quantify the fingered characteristics of the interface and its growth due to shock forcing. The results show that the interface has a distribution of thickness and that the interaction with a shock further broadens the interface. The growth rate was found to exhibit a dependence on the shock strength.

A molecular theory of liquid interfaces.

PubMed

Kovalenko, Andriy; Hirata, Fumio

2005-04-21

We propose a site site generalization of the Lovett-Mow-Buff-Wertheim integro-differential equation for the one-particle density distributions to polyatomic fluids. The method provides microscopic description of liquid interfaces of molecular fluids and solutions. It uses the inhomogeneous site-site direct correlation function of molecular fluid consistently constructed by nonlinear interpolation between the homogeneous ones. The site site correlations of the coexisting bulk phases are obtained from the reference interaction site model (RISM) integral equation with our closure approximation. For illustration, we calculated the structure of the planar liquid-vapor as well as liquid-liquid interfaces of n-hexane and methanol at ambient conditions.

Stability of miscible core?annular flows with viscosity stratification

NASA Astrophysics Data System (ADS)

Selvam, B.; Merk, S.; Govindarajan, Rama; Meiburg, E.

The linear stability of variable viscosity, miscible core-annular flows is investigated. Consistent with pipe flow of a single fluid, the flow is stable at any Reynolds number when the magnitude of the viscosity ratio is less than a critical value. This is in contrast to the immiscible case without interfacial tension, which is unstable at any viscosity ratio. Beyond the critical value of the viscosity ratio, the flow can be unstable even when the more viscous fluid is in the core. This is in contrast to plane channel flows with finite interface thickness, which are always stabilized relative to single fluid flow when the less viscous fluid is in contact with the wall. If the more viscous fluid occupies the core, the axisymmetric mode usually dominates over the corkscrew mode. It is demonstrated that, for a less viscous core, the corkscrew mode is inviscidly unstable, whereas the axisymmetric mode is unstable for small Reynolds numbers at high Schmidt numbers. For the parameters under consideration, the switchover occurs at an intermediate Schmidt number of about 500. The occurrence of inviscid instability for the corkscrew mode is shown to be consistent with the Rayleigh criterion for pipe flows. In some parameter ranges, the miscible flow is seen to be more unstable than its immiscible counterpart, and the physical reasons for this behaviour are discussed.A detailed parametric study shows that increasing the interface thickness has a uniformly stabilizing effect. The flow is least stable when the interface between the two fluids is located at approximately 0.6 times the tube radius. Unlike for channel flow, there is no sudden change in the stability with radial location of the interface. The instability originates mainly in the less viscous fluid, close to the interface.

A sharp interface Cartesian grid method for viscous simulation of shocked particle-laden flows

NASA Astrophysics Data System (ADS)

Das, Pratik; Sen, Oishik; Jacobs, Gustaaf; Udaykumar, H. S.

2017-09-01

A Cartesian grid-based sharp interface method is presented for viscous simulations of shocked particle-laden flows. The moving solid-fluid interfaces are represented using level sets. A moving least-squares reconstruction is developed to apply the no-slip boundary condition at solid-fluid interfaces and to supply viscous stresses to the fluid. The algorithms developed in this paper are benchmarked against similarity solutions for the boundary layer over a fixed flat plate and against numerical solutions for moving interface problems such as shock-induced lift-off of a cylinder in a channel. The framework is extended to 3D and applied to calculate low Reynolds number steady supersonic flow over a sphere. Viscous simulation of the interaction of a particle cloud with an incident planar shock is demonstrated; the average drag on the particles and the vorticity field in the cloud are compared to the inviscid case to elucidate the effects of viscosity on momentum transfer between the particle and fluid phases. The methods developed will be useful for obtaining accurate momentum and heat transfer closure models for macro-scale shocked particulate flow applications such as blast waves and dust explosions.

A computational method for sharp interface advection.

PubMed

Roenby, Johan; Bredmose, Henrik; Jasak, Hrvoje

2016-11-01

We devise a numerical method for passive advection of a surface, such as the interface between two incompressible fluids, across a computational mesh. The method is called isoAdvector, and is developed for general meshes consisting of arbitrary polyhedral cells. The algorithm is based on the volume of fluid (VOF) idea of calculating the volume of one of the fluids transported across the mesh faces during a time step. The novelty of the isoAdvector concept consists of two parts. First, we exploit an isosurface concept for modelling the interface inside cells in a geometric surface reconstruction step. Second, from the reconstructed surface, we model the motion of the face-interface intersection line for a general polygonal face to obtain the time evolution within a time step of the submerged face area. Integrating this submerged area over the time step leads to an accurate estimate for the total volume of fluid transported across the face. The method was tested on simple two-dimensional and three-dimensional interface advection problems on both structured and unstructured meshes. The results are very satisfactory in terms of volume conservation, boundedness, surface sharpness and efficiency. The isoAdvector method was implemented as an OpenFOAM ® extension and is published as open source.

An efficient mass-preserving interface-correction level set/ghost fluid method for droplet suspensions under depletion forces

NASA Astrophysics Data System (ADS)

Ge, Zhouyang; Loiseau, Jean-Christophe; Tammisola, Outi; Brandt, Luca

2018-01-01

Aiming for the simulation of colloidal droplets in microfluidic devices, we present here a numerical method for two-fluid systems subject to surface tension and depletion forces among the suspended droplets. The algorithm is based on an efficient solver for the incompressible two-phase Navier-Stokes equations, and uses a mass-conserving level set method to capture the fluid interface. The four novel ingredients proposed here are, firstly, an interface-correction level set (ICLS) method; global mass conservation is achieved by performing an additional advection near the interface, with a correction velocity obtained by locally solving an algebraic equation, which is easy to implement in both 2D and 3D. Secondly, we report a second-order accurate geometric estimation of the curvature at the interface and, thirdly, the combination of the ghost fluid method with the fast pressure-correction approach enabling an accurate and fast computation even for large density contrasts. Finally, we derive a hydrodynamic model for the interaction forces induced by depletion of surfactant micelles and combine it with a multiple level set approach to study short-range interactions among droplets in the presence of attracting forces.

Interface Configuration Experiments (ICE) Explore the Effects of Microgravity on Fluids

NASA Technical Reports Server (NTRS)

1996-01-01

The Interface Configuration Experiment (ICE) is actually a series of experiments that explore the striking behavior of liquid-vapor interfaces (i.e., fluid surfaces) in a low gravity environment under which major shifts in liquid position can arise from small changes in container shape or contact angle. Although these experiments are designed to test current mathematical theory, there are numerous practical applications that could result from these studies. When designing fluid management systems for space-based operations, it is important to be able to predict the locations and configurations that fluids will assume in containers under low-gravity conditions. The increased ability to predict, and hence control, fluid interfaces is vital to systems and/or processes where capillary forces play a significant role both in space and on the Earth. Some of these applications are in general coating processes (paints, pesticides, printing, etc.), fluid transport in porous media (ground water flows, oil recovery, etc.), liquid propellant systems in space (liquid fuel and oxygen), capillary-pumped loops and heat pipes, and space-based life-support systems. In space, almost every fluid system is affected, if not dominated, by capillarity. Knowledge of the liquid-vapor interface behavior, and in particular the interface shape from which any analysis must begin, is required as a foundation to predict how these fluids will react in microgravity and on Earth. With such knowledge, system designs can be optimized, thereby decreasing costs and complexity, while increasing performance and reliability. ICE has increased, and will continue to increase this knowledge, as it probes the specific peculiarities of current theory upon which our current understanding of these effects is based. Several versions of ICE were conducted in NASA Lewis Research Center's drop towers and on the space shuttle during the first and second United States Microgravity Laboratory missions (USML-1 and USML-2). Additional tests are planned for the space shuttle and for the Russian Mir space station. These studies will focus on interfacial problems concerning surface existence, uniqueness, configuration, stability, and flow characteristics.

Implementation of Interaction Algorithm to Non-Matching Discrete Interfaces Between Structure and Fluid Mesh

NASA Technical Reports Server (NTRS)

Chen, Shu-Po

1999-01-01

This paper presents software for solving the non-conforming fluid structure interfaces in aeroelastic simulation. It reviews the algorithm of interpolation and integration, highlights the flexibility and the user-friendly feature that allows the user to select the existing structure and fluid package, like NASTRAN and CLF3D, to perform the simulation. The presented software is validated by computing the High Speed Civil Transport model.

Advanced subgrid-scale modeling for convection-dominated species transport at fluid interfaces with application to mass transfer from rising bubbles

NASA Astrophysics Data System (ADS)

Weiner, Andre; Bothe, Dieter

2017-10-01

This paper presents a novel subgrid scale (SGS) model for simulating convection-dominated species transport at deformable fluid interfaces. One possible application is the Direct Numerical Simulation (DNS) of mass transfer from rising bubbles. The transport of a dissolving gas along the bubble-liquid interface is determined by two transport phenomena: convection in streamwise direction and diffusion in interface normal direction. The convective transport for technical bubble sizes is several orders of magnitude higher, leading to a thin concentration boundary layer around the bubble. A true DNS, fully resolving hydrodynamic and mass transfer length scales results in infeasible computational costs. Our approach is therefore a DNS of the flow field combined with a SGS model to compute the mass transfer between bubble and liquid. An appropriate model-function is used to compute the numerical fluxes on all cell faces of an interface cell. This allows to predict the mass transfer correctly even if the concentration boundary layer is fully contained in a single cell layer around the interface. We show that the SGS-model reduces the resolution requirements at the interface by a factor of ten and more. The integral flux correction is also applicable to other thin boundary layer problems. Two flow regimes are investigated to validate the model. A semi-analytical solution for creeping flow is used to assess local and global mass transfer quantities. For higher Reynolds numbers ranging from Re = 100 to Re = 460 and Péclet numbers between Pe =104 and Pe = 4 ṡ106 we compare the global Sherwood number against correlations from literature. In terms of accuracy, the predicted mass transfer never deviates more than 4% from the reference values.

Attachment of composite porous supra-particles to air-water and oil-water interfaces: theory and experiment.

PubMed

Paunov, Vesselin N; Al-Shehri, Hamza; Horozov, Tommy S

2016-09-29

We developed and tested a theoretical model for the attachment of fluid-infused porous supra-particles to a fluid-liquid interface. We considered the wetting behaviour of agglomerated clusters of particles, typical of powdered materials dispersed in a liquid, as well as of the adsorption of liquid-infused colloidosomes at the liquid-fluid interface. The free energy of attachment of a composite spherical porous supra-particle made from much smaller aggregated spherical particles to the oil-water interface was calculated. Two cases were considered: (i) a water-filled porous supra-particle adsorbed at the oil-water interface from the water phase, and, (ii) an oil-filled porous supra-particle adsorbed at the oil-water interface from the oil-phase. We derived equations relating the three-phase contact angle of the smaller "building block" particles and the contact angle of the liquid-infused porous supra-particles. The theory predicts that the porous supra-particle contact angle attached at the liquid interface strongly depends on the type of fluid infused in the particle pores and the fluid phase from which it approaches the liquid interface. We tested the theory by using millimetre-sized porous supra-particles fabricated by evaporation of droplets of polystyrene latex suspension on a pre-heated super-hydrophobic surface, followed by thermal annealing at the glass transition temperature. Such porous particles were initially infused with water or oil and approached to the oil-water interface from the infusing phase. The experiment showed that when attaching at the hexadecane-water interface, the porous supra-particles behaved as hydrophilic when they were pre-filled with water and hydrophobic when they were pre-filled with hexadecane. The results agree with the theoretically predicted contact angles for the porous composite supra-particles based on the values of the contact angles of their building block latex particles measured with the Gel Trapping Technique. The experimental data for the attachment of porous supra particles to the air-water interface from both air and water also agree with the theoretical model. This study gives important insights about how porous particles and particle aggregates attach to the oil-water interface in Pickering emulsions and the air-water surface in particle-stabilised aqueous foams relevant in ore flotation and a range of cosmetic, pharmaceutical, food, home and personal care formulations.

Analysis of hybrid interface cooling system using air ventilation and nanofluid

NASA Astrophysics Data System (ADS)

Rani, M. F. H.; Razlan, Z. M.; Bakar, S. A.; Desa, H.; Wan, W. K.; Ibrahim, I.; Kamarrudin, N. S.; Bin-Abdun, Nazih A.

2017-09-01

The hybrid interface cooling system needs to be designed for maintaining the electric vehicle's battery cell temperature at 25°C. The hybrid interface cooling system is a combination of two individual systems, where the primary cooling system (R-134a) and the secondary cooling system (CuO + Water) will be used to absorb the heat generated by the battery cells. The ventilation system is designed using air as the medium to transfer the heat from the batteries to the refrigeration system (R-134a). Research will focus on determining the suitable compressor displacement, the heat exchanger volume and the expansion valve resistance value. The analysis for the secondary cooling system is focused on the cooling coil where low temperature nanofluid is passing through each interval of the battery cells. For analysing purposes, the thermal properties of the mixture of 50 grams, Copper (II) Oxide and the base fluid have been determined. The hybrid interface cooling system are able to achieve 57.82% increments in term of rate of heat transfer as compared to the individual refrigeration system.

Feedback Controlled Colloidal Assembly at Fluid Interfaces

NASA Astrophysics Data System (ADS)

Bevan, Michael

The autonomous and reversible assembly of colloidal nano- and micro- scale components into ordered configurations is often suggested as a scalable process capable of manufacturing meta-materials with exotic electromagnetic properties. As a result, there is strong interest in understanding how thermal motion, particle interactions, patterned surfaces, and external fields can be optimally coupled to robustly control the assembly of colloidal components into hierarchically structured functional meta-materials. We approach this problem by directly relating equilibrium and dynamic colloidal microstructures to kT-scale energy landscapes mediated by colloidal forces, physically and chemically patterned surfaces, multiphase fluid interfaces, and electromagnetic fields. 3D colloidal trajectories are measured in real-space and real-time with nanometer resolution using an integrated suite of evanescent wave, video, and confocal microscopy methods. Equilibrium structures are connected to energy landscapes via statistical mechanical models. The dynamic evolution of initially disordered colloidal fluid configurations into colloidal crystals in the presence of tunable interactions (electromagnetic field mediated interactions, particle-interface interactions) is modeled using a novel approach based on fitting the Fokker-Planck equation to experimental microscopy and computer simulated assembly trajectories. This approach is based on the use of reaction coordinates that capture important microstructural features of crystallization processes and quantify both statistical mechanical (free energy) and fluid mechanical (hydrodynamic) contributions. Ultimately, we demonstrate real-time control of assembly, disassembly, and repair of colloidal crystals using both open loop and closed loop control to produce perfectly ordered colloidal microstructures. This approach is demonstrated for close packed colloidal crystals of spherical particles at fluid-solid interfaces and is being extended to anisotropic particles and multiphase fluid interfaces.

Crystal Growth of ZnSe and Related Ternary Compound Semiconductors by Vapor Transport

NASA Technical Reports Server (NTRS)

Su, Ching-Hua; Brebrick, R. F.; Burger, A.; Dudley, M.; Ramachandran, N.

2003-01-01

The objective of the project is to determine the relative contributions of gravity-driven fluid flows to the compositional distribution, incorporation of impurities and defects, and deviation from stoichiometry observed in the crystals grown by vapor transport as results of buoyance-driven convection and growth interface fluctuations caused by irregular fluid-flows. ZnSe and related ternary compounds, such as ZnSeS and ZnSeTe, were grown by vapor transport technique with real time in-situ non-invasive monitoring techniques. The grown crystals were characterized extensively to correlate the grown crystal properties with the growth conditions.

Diffuse-interface approach to rotating Hele-Shaw flows.

PubMed

Chen, Ching-Yao; Huang, Yu-Sheng; Miranda, José A

2011-10-01

When two fluids of different densities move in a rotating Hele-Shaw cell, the interface between them becomes centrifugally unstable and deforms. Depending on the viscosity contrast of the system, distinct types of complex patterns arise at the fluid-fluid boundary. Deformations can also induce the emergence of interfacial singularities and topological changes such as droplet pinch-off and self-intersection. We present numerical simulations based on a diffuse-interface model for this particular two-phase displacement that capture a variety of pattern-forming behaviors. This is implemented by employing a Boussinesq Hele-Shaw-Cahn-Hilliard approach, considering the whole range of possible values for the viscosity contrast, and by including inertial effects due to the Coriolis force. The role played by these two physical contributions on the development of interface singularities is illustrated and discussed.

Lagrangian transport properties of pulmonary interfacial flows

PubMed Central

Smith, Bradford J.; Lukens, Sarah; Yamaguchi, Eiichiro; Gaver, Donald P.

2012-01-01

Disease states characterized by airway fluid occlusion and pulmonary surfactant insufficiency, such as respiratory distress syndrome, have a high mortality rate. Understanding the mechanics of airway reopening, particularly involving surfactant transport, may provide an avenue to increase patient survival via optimized mechanical ventilation waveforms. We model the occluded airway as a liquid-filled rigid tube with the fluid phase displaced by a finger of air that propagates with both mean and sinusoidal velocity components. Finite-time Lyapunov exponent (FTLE) fields are employed to analyse the convective transport characteristics, taking note of Lagrangian coherent structures (LCSs) and their effects on transport. The Lagrangian perspective of these techniques reveals flow characteristics that are not readily apparent by observing Eulerian measures. These analysis techniques are applied to surfactant-free velocity fields determined computationally, with the boundary element method, and measured experimentally with micro particle image velocimetry (μ-PIV). We find that the LCS divides the fluid into two regimes, one advected upstream (into the thin residual film) and the other downstream ahead of the advancing bubble. At higher oscillatory frequencies particles originating immediately inside the LCS experience long residence times at the air–liquid interface, which may be conducive to surfactant transport. At high frequencies a well-mixed attractor region is identified; this volume of fluid cyclically travels along the interface and into the bulk fluid. The Lagrangian analysis is applied to velocity data measured with 0.01 mg ml−1 of the clinical pulmonary surfactant Infasurf in the bulk fluid, demonstrating flow field modifications with respect to the surfactant-free system that were not visible in the Eulerian frame. PMID:23049141

A continuum treatment of sliding in Eulerian simulations of solid-solid and solid-fluid interfaces

NASA Astrophysics Data System (ADS)

Subramaniam, Akshay; Ghaisas, Niranjan; Lele, Sanjiva

2017-11-01

A novel treatment of sliding is developed for use in an Eulerian framework for simulating elastic-plastic deformations of solids coupled with fluids. In this method, embedded interfacial boundary conditions for perfect sliding are imposed by enforcing the interface normal to be a principal direction of the Cauchy stress and appropriate consistency conditions ensure correct transmission and reflection of waves at the interface. This sliding treatment may be used either to simulate a solid-solid sliding interface or to incorporate an internal slip boundary condition at a solid-fluid interface. Sliding laws like the Coulomb friction law can also be incorporated with relative ease into this framework. Simulations of sliding interfaces are conducted using a 10th order compact finite difference scheme and a Localized Artificial Diffusivity (LAD) scheme for shock and interface capturing. 1D and 2D simulations are used to assess the accuracy of the sliding treatment. The Richmyer-Meshkov instability between copper and aluminum is simulated with this sliding treatment as a demonstration test case. Support for this work was provided through Grant B612155 from the Lawrence Livermore National Laboratory, US Department of Energy.

The importance of fluctuations in fluid mixing

PubMed Central

Kadau, Kai; Rosenblatt, Charles; Barber, John L.; Germann, Timothy C.; Huang, Zhibin; Carlès, Pierre; Alder, Berni J.

2007-01-01

A ubiquitous example of fluid mixing is the Rayleigh–Taylor instability, in which a heavy fluid initially sits atop a light fluid in a gravitational field. The subsequent development of the unstable interface between the two fluids is marked by several stages. At first, each interface mode grows exponentially with time before transitioning to a nonlinear regime characterized by more complex hydrodynamic mixing. Unfortunately, traditional continuum modeling of this process has generally been in poor agreement with experiment. Here, we indicate that the natural, random fluctuations of the flow field present in any fluid, which are neglected in continuum models, can lead to qualitatively and quantitatively better agreement with experiment. We performed billion-particle atomistic simulations and magnetic levitation experiments with unprecedented control of initial interface conditions. A comparison between our simulations and experiments reveals good agreement in terms of the growth rate of the mixing front as well as the new observation of droplet breakup at later times. These results improve our understanding of many fluid processes, including interface phenomena that occur, for example, in supernovae, the detachment of droplets from a faucet, and ink jet printing. Such instabilities are also relevant to the possible energy source of inertial confinement fusion, in which a millimeter-sized capsule is imploded to initiate nuclear fusion reactions between deuterium and tritium. Our results suggest that the applicability of continuum models would be greatly enhanced by explicitly including the effects of random fluctuations. PMID:17470811

Thin film instabilities: Rayleigh-Taylor with thermocapillarity and Kolmogorov flow in a soap film

NASA Astrophysics Data System (ADS)

Burgess, John Matthew

The Rayleigh-Taylor instability occurs when a more dense fluid layer is suspended above a less dense fluid layer in a gravitational field. The horizontal interface between the two fluids is unstable to infinitesimal deformations and the dense fluid falls. To counteract the destabilizing effects of gravity on the interface between two thin fluid layers, we apply a vertical temperature gradient, heating from below. The dependence of surface tension on temperature (``thermocapillarity'') can cause spatially-varying interfacial forces between two immiscible fluid layers if a variation in temperature along the interface is introduced. With an applied vertical temperature gradient, the deforming interface spontaneously develops temperature variations which locally adjust the surface tension to restore a flat interface. We find that these surface tension gradients can stabilize a more dense thin fluid layer (silicone oil, 0.015 cm thick) above a less dense thin fluid layer (air, 0.025 cm thick) in a gravitational field, in qualitative agreement with linear stability analysis. This is the first experimental observation of the stabilization of Rayleigh-Taylor instability by thermocapillary forces. We also examine the instability of a soap film flow driven by a time-independent force that is spatially periodic in the direction perpendicular to the forcing (Kolmogorov flow). The film is in the x- y plane, where the forcing approximates a shape sin (y)x̂. Linear stability analysis of an idealized model of this flow predicts a critical Reynolds number Rc~2 . In our soap film experiment, we find a critical value Rc~70 . This discrepancy can be ascribed to frictional effects from viscous coupling of gas to the film, which is neglected in the idealized model. The kinematic viscosity of the surrounding gas and the thickness of gas layers on each side of the soap film are varied in the experiments to better understand these frictional effects. We conclude that flows in soap films cannot be decoupled from flows in the surrounding gas.

Direct Numerical Simulation of Low Capillary Number Pore Scale Flows

NASA Astrophysics Data System (ADS)

Esmaeilzadeh, S.; Soulaine, C.; Tchelepi, H.

2017-12-01

The arrangement of void spaces and the granular structure of a porous medium determines multiple macroscopic properties of the rock such as porosity, capillary pressure, and relative permeability. Therefore, it is important to study the microscopic structure of the reservoir pores and understand the dynamics of fluid displacements through them. One approach for doing this, is direct numerical simulation of pore-scale flow that requires a robust numerical tool for prediction of fluid dynamics and a detailed understanding of the physical processes occurring at the pore-scale. In pore scale flows with a low capillary number, Eulerian multiphase methods are well-known to produce additional vorticity close to the interface. This is mainly due to discretization errors which lead to an imbalance of capillary pressure and surface tension forces that causes unphysical spurious currents. At the pore scale, these spurious currents can become significantly stronger than the average velocity in the phases, and lead to unphysical displacement of the interface. In this work, we first investigate the capability of the algebraic Volume of Fluid (VOF) method in OpenFOAM for low capillary number pore scale flow simulations. Afterward, we compare VOF results with a Coupled Level-Set Volume of Fluid (CLSVOF) method and Iso-Advector method. It has been shown that the former one reduces the VOF's unphysical spurious currents in some cases, and both are known to capture interfaces sharper than VOF. As the conclusion, we will investigate that whether the use of CLSVOF or Iso-Advector will lead to less spurious velocities and more accurate results for capillary driven pore-scale multiphase flows or not. Keywords: Pore-scale multiphase flow, Capillary driven flows, Spurious currents, OpenFOAM

Statistical substantiation of the van der Waals theory of inhomogeneous fluids

NASA Astrophysics Data System (ADS)

Baidakov, V. G.; Protsenko, S. P.; Chernykh, G. G.; Boltachev, G. Sh.

2002-04-01

Computer experiments on simulation of thermodynamic properties and structural characteristics of a Lennard-Jones fluid in one- and two-phase models have been performed for the purpose of checking the base concepts of the van der Waals theory. Calculations have been performed by the method of molecular dynamics at cutoff radii of the intermolecular potential rc,1=2.6σ and rc,2=6.78σ. The phase equilibrium parameters, surface tension, and density distribution have been determined in a two-phase model with a flat liquid-vapor interface. The strong dependence of these properties on the value of rc is shown. The p,ρ,T properties and correlation functions have been calculated in a homogeneous model for a stable and a metastable fluid. An equation of state for a Lennard-Jones fluid describing stable, metastable, and labile regions has been built. It is shown that at T>=1.1 the properties of a flat interface within the computer experimental error can be described by the van der Waals square-gradient theory with an influence parameter κ independent of the density. Taking into account the density dependence of κ through the second moment of the direct correlation function will deteriorate the agreement of the theory with data of computer simulation. The contribution of terms of a higher order than (∇ρ)2 to the Helmholtz free energy of an inhomogeneous system has been considered. It is shown that taking into account terms proportional to (∇ρ)4 leaves no way of obtaining agreement between the theory and simulation data, while taking into consideration of terms proportional to (∇ρ)6 makes it possible to describe with adequate accuracy all the properties of a flat interface in the temperature range from the triple to the critical point.

Centrifugally Driven Rayleigh-Taylor Instability

NASA Astrophysics Data System (ADS)

Scase, Matthew; Hill, Richard

2017-11-01

The instability that develops at the interface between two fluids of differing density due to the rapid rotation of the system may be considered as a limit of high-rotation rate Rayleigh-Taylor instability. Previously the authors have considered the effect of rotation on a gravitationally dominated Rayleigh-Taylor instability and have shown that some growth modes of instability may be suppressed completely by the stabilizing effect of rotation (Phys. Rev. Fluids 2:024801, Sci. Rep. 5:11706). Here we consider the case of very high rotation rates and a negligible gravitational field. The initial condition is of a dense inner cylinder of fluid surrounded by a lighter layer of fluid. As the system is rotated about the generating axis of the cylinder, the dense inner fluid moves away from the axis and the familiar bubbles and spikes of Rayleigh-Taylor instability develop at the interface. The system may be thought of as a ``fluid-fluid centrifuge''. By developing a model based on an Orr-Sommerfeld equation, we consider the effects of viscosity, surface tension and interface diffusion on the growth rate and modes of instability. We show that under particular circumstances some modes may be stabilized. School of Mathematical Sciences.

A transition in the viscous fingering instability in miscible fluids

NASA Astrophysics Data System (ADS)

Videbaek, Thomas; Nagel, Sidney R.

2017-11-01

The viscous fingering instability in a quasi-two dimensional Hele-Shaw cell is an example of complex structure formation from benign initial conditions. When the invading fluid has the lesser viscosity, the interface between the two fluids is unstable to finger formation. Here, we study the instability between pairs of miscible fluids in a circular cell with fluid injected at its center. As the injection rate is decreased, diffusion will smooth out the discontinuity in the gap-averaged viscosity at the interface between the fluids. At high injection rates (i.e., high Péclet number, Pe), fingering is associated with three-dimensional structure within the gap between the confining plates. On lowering Pe, we find a sharp transition in the finger morphology at a critical value, Pec (ηi /ηo) 1 / 2 , with ηi (ηo) being the viscosity of the inner (outer) fluid; at this point, the width of the fingers jumps, the length of the fingers shrinks towards zero and the three-dimensional structure goes from half filling to fully filling the gap. Thus, by controlling the viscosity contrast at the interface, one can alter and even completely suppress the instability.

Slump Flows inside Pipes: Numerical Results and Comparison with Experiments

NASA Astrophysics Data System (ADS)

Malekmohammadi, S.; Naccache, M. F.; Frigaard, I. A.; Martinez, D. M.

2008-07-01

In this work an analysis of the buoyancy-driven slumping flow inside a pipe is presented. This flow usually occurs when an oil well is sealed by a plug cementing process, where a cement plug is placed inside the pipe filled with a lower density fluid, displacing it towards the upper cylinder wall. Both the cement and the surrounding fluids have a non Newtonian behavior. The cement is viscoplastic and the surrounding fluid presents a shear thinning behavior. A numerical analysis was performed to evaluate the effects of some governing parameters on the slump length development. The conservation equations of mass and momentum were solved via a finite volume technique, using Fluent software (Ansys Inc.). The Volume of Fluid surface-tracking method was used to obtain the interface between the fluids and the slump length as a function of time. The results were obtained for different values of fluids densities differences, fluids rheology and pipe inclinations. The effects of these parameters on the interface shape and on the slump length versus time curve were analyzed. Moreover, the numerical results were compared to experimental ones, but some differences are observed, possibly due to chemical effects at the interface.

Numerical simulation of bubble deformation in magnetic fluids by finite volume method

NASA Astrophysics Data System (ADS)

Yamasaki, Haruhiko; Yamaguchi, Hiroshi

2017-06-01

Bubble deformation in magnetic fluids under magnetic field is investigated numerically by an interface capturing method. The numerical method consists of a coupled level-set and VOF (Volume of Fluid) method, combined with conservation CIP (Constrained Interpolation Profile) method with the self-correcting procedure. In the present study considering actual physical properties of magnetic fluid, bubble deformation under given uniform magnetic field is analyzed for internal magnetic field passing through a magnetic gaseous and liquid phase interface. The numerical results explain the mechanism of bubble deformation under presence of given magnetic field.

Asymmetric bubble collapse and jetting in generalized Newtonian fluids

NASA Astrophysics Data System (ADS)

Shukla, Ratnesh K.; Freund, Jonathan B.

2017-11-01

The jetting dynamics of a gas bubble near a rigid wall in a non-Newtonian fluid are investigated using an axisymmetric simulation model. The bubble gas is assumed to be homogeneous, with density and pressure related through a polytropic equation of state. An Eulerian numerical description, based on a sharp interface capturing method for the shear-free bubble-liquid interface and an incompressible Navier-Stokes flow solver for generalized fluids, is developed specifically for this problem. Detailed simulations for a range of rheological parameters in the Carreau model show both the stabilizing and destabilizing non-Newtonian effects on the jet formation and impact. In general, for fixed driving pressure ratio, stand-off distance and reference zero-shear-rate viscosity, shear-thinning and shear-thickening promote and suppress jet formation and impact, respectively. For a sufficiently large high-shear-rate limit viscosity, the jet impact is completely suppressed. Thresholds are also determined for the Carreau power-index and material time constant. The dependence of these threshold rheological parameters on the non-dimensional driving pressure ratio and wall stand-off distance is similarly established. Implications for tissue injury in therapeutic ultrasound will be discussed.

Observation of a new surface mode on a fluid-saturated permeable solid

NASA Astrophysics Data System (ADS)

Nagy, Peter B.

1992-06-01

Almost ten years ago, S. Feng and D. L. Johnson predicted the presence of a new surface mode on a fluid/fluid-saturated porous solid interface with closed surface pores [J. Acoust. Soc. Am. 74, 906 (1983)]. We found that, due to surface tension, practically closed-pore boundary conditions can prevail at an interface between a nonwetting fluid (e.g., air) and a porous solid saturated with a wetting fluid (e.g., water or alcohol). Surface wave velocity and attenuation measurements were made on alcohol-saturated porous sintered glass at 100 kHz. The experimental results show clear evidence of the new ``slow'' surface mode predicted by Feng and Johnson.

Computer program for computing the properties of seventeen fluids. [cryogenic liquids

NASA Technical Reports Server (NTRS)

Brennan, J. A.; Friend, D. G.; Arp, V. D.; Mccarty, R. D.

1992-01-01

The present study describes modifications and additions to the MIPROPS computer program for calculating the thermophysical properties of 17 fluids. These changes include adding new fluids, new properties, and a new interface to the program. The new program allows the user to select the input and output parameters and the units to be displayed for each parameter. Fluids added to the MIPROPS program are carbon dioxide, carbon monoxide, deuterium, helium, normal hydrogen, and xenon. The most recent modifications to the MIPROPS program are the addition of viscosity and thermal conductivity correlations for parahydrogen and the addition of the fluids normal hydrogen and xenon. The recently added interface considerably increases the program's utility.

Centrifugal fingering in a curved Hele-Shaw cell: A generalized Euler's elastica shape for the two-fluid interface

NASA Astrophysics Data System (ADS)

Miranda, Jose; Brandao, Rodolfo

2017-11-01

We study a family of generalized elastica-like equilibrium shapes that arise at the interface separating two fluids in a curved rotating Hele-Shaw cell. This family of stationary interface solutions consists of shapes that balance the competing capillary and centrifugal forces in such a curved flow environment. We investigate how the emerging interfacial patterns are impacted by changes in the geometric properties of the curved Hele-Shaw cell. A vortex-sheet formalism is used to calculate the two-fluid interface curvature, and a gallery of possible shapes is provided to highlight a number of peculiar morphological features. A linear perturbation theory is employed to show that the most prominent aspects of these complex stationary patterns can be fairly well reproduced by the interplay of just two interfacial modes. The connection of these dominant modes to the geometry of the curved cell, as well as to the fluid dynamic properties of the flow, is discussed. We thank CNPq (Brazilian Research Council) for financial support under Grant No. 304821/2015-2.

Young-Laplace equation for liquid crystal interfaces

NASA Astrophysics Data System (ADS)

Rey, Alejandro D.

2000-12-01

This letter uses the classical theories of liquid crystal physics to derive the Young-Laplace equation of capillary hydrostatics for interfaces between viscous isotropic (I) fluids and nematic liquid crystals (NLC's), and establishes the existence of four energy contributions to pressure jumps across these unusual anisotropic interfaces. It is shown that in addition to the usual curvature contribution, bulk and surface gradient elasticity, elastic stress, and anchoring energy contribute to pressure differentials across the interface. The magnitude of the effect is proportional to the elastic moduli of the NLC, and to the bulk and surface orientation gradients that may be present in the nematic phase. In contrast to the planar interface between isotropic fluids, flat liquid crystal interfaces support pressure jumps if elastic stresses, bulk and surface gradient energy, and/or anchoring energies are finite.

Using SEM Analysis on Ion-Milled Shale Surface to Determine Shale-Fracturing Fluid Interaction

NASA Astrophysics Data System (ADS)

Lu, J.; Mickler, P. J.; Nicot, J. P.

2014-12-01

It is important to document and assess shale-fluid interaction during hydraulic fracturing (HF) in order to understand its impact on flowback water chemistry and rock property. A series of autoclave experiments were conducted to react shale samples from major oil and gas shales with synthetic HF containing various additives. To better determine mineral dissolution and precipitation at the rock-fluid interface, ion-milling technique was applied to create extremely flat rock surfaces that were examined before and after the autoclave experiments using a scanning electron microscope (SEM) coupled with energy dispersive spectroscopy (EDS) detectors. This method is able to reveal a level of detail not observable on broken surface or mechanically polished surface. It allows direct comparison of the same mineral and organic matter particles before and after the reaction experiments. Minerals undergone dissolution and newly precipitated materials are readily determined by comparing to the exact locations before reaction. The dissolution porosity and the thickness of precipitates can be quantified by tracing and measuring the geometry of the pores and precipitates. Changes in porosity and permeability were confirmed by mercury intrusion capillary tests.

The interaction of evaporative and convective instabilities

NASA Astrophysics Data System (ADS)

Ozen, O.

Evaporative convection arises in a variety of natural and industrial processes, such as drying of lakebeds, heat pipe technology and dry-eye syndrome. The phenomenon of evaporative convection leads to an interfacial instability where an erstwhile flat surface becomes undulated as a control variable, such as temperature drop, exceeds a critical value. This instability has been investigated by others assuming that the vapor phase is infinitely deep and passive, i.e. vapor fluid dynamics has been ignored. However, when we look at some engineering processes, such as distillation columns, heat pipes and drying technologies where phase change takes place we might imagine that the assumption of an infinitely deep vapor layer or at least that of a passive vapor is inappropriate. Previous work on convection in bilayer systems with no phase-change suggests that active vapor layers play a major role in determining the stability of an interface. Hence, for the case of convection with phase-change, we will address this issue and try to answer the question whether the infinitely deep and passive vapor layer is a valid assumption. We have also investigated, theoretically, the gravity and surface tension gradient-driven instabilities occurring during the evaporation of a liquid into its own vapor taking into account the fluid dynamics of both phases and the finiteness of the domains of each phase, i.e. the liquid and its vapor are assumed to be confined between two horizontal plates, and different heating arrangements are applied. The effects of fluid layer depths, the evaporation rate and the temperature gradient applied across the fluids on the stability of the interface are studied. The modes of the flow pattern are determined for each scenario. The physics of the instability are explained and a comparison is made with the results of similar, yet physically different problems.

Particle-bearing currents in uniform density and two-layer fluids

NASA Astrophysics Data System (ADS)

Sutherland, Bruce R.; Gingras, Murray K.; Knudson, Calla; Steverango, Luke; Surma, Christopher

2018-02-01

Lock-release gravity current experiments are performed to examine the evolution of a particle bearing flow that propagates either in a uniform-density fluid or in a two-layer fluid. In all cases, the current is composed of fresh water plus micrometer-scale particles, the ambient fluid is saline, and the current advances initially either over the surface as a hypopycnal current or at the interface of the two-layer fluid as a mesopycnal current. In most cases the tank is tilted so that the ambient fluid becomes deeper with distance from the lock. For hypopycnal currents advancing in a uniform density fluid, the current typically slows as particles rain out of the current. While the loss of particles alone from the current should increase the current's buoyancy and speed, in practice the current's speed decreases because the particles carry with them interstitial fluid from the current. Meanwhile, rather than settling on the sloping bottom of the tank, the particles form a hyperpycnal (turbidity) current that advances until enough particles rain out that the relatively less dense interstitial fluid returns to the surface, carrying some particles back upward. When a hypopycnal current runs over the surface of a two-layer fluid, the particles that rain out temporarily halt their descent as they reach the interface, eventually passing through it and again forming a hyperpycnal current. Dramatically, a mesopycnal current in a two-layer fluid first advances along the interface and then reverses direction as particles rain out below and fresh interstitial fluid rises above.

A computational method for sharp interface advection

PubMed Central

Bredmose, Henrik; Jasak, Hrvoje

2016-01-01

We devise a numerical method for passive advection of a surface, such as the interface between two incompressible fluids, across a computational mesh. The method is called isoAdvector, and is developed for general meshes consisting of arbitrary polyhedral cells. The algorithm is based on the volume of fluid (VOF) idea of calculating the volume of one of the fluids transported across the mesh faces during a time step. The novelty of the isoAdvector concept consists of two parts. First, we exploit an isosurface concept for modelling the interface inside cells in a geometric surface reconstruction step. Second, from the reconstructed surface, we model the motion of the face–interface intersection line for a general polygonal face to obtain the time evolution within a time step of the submerged face area. Integrating this submerged area over the time step leads to an accurate estimate for the total volume of fluid transported across the face. The method was tested on simple two-dimensional and three-dimensional interface advection problems on both structured and unstructured meshes. The results are very satisfactory in terms of volume conservation, boundedness, surface sharpness and efficiency. The isoAdvector method was implemented as an OpenFOAM® extension and is published as open source. PMID:28018619

A new model for fluid velocity slip on a solid surface.

PubMed

Shu, Jian-Jun; Teo, Ji Bin Melvin; Chan, Weng Kong

2016-10-12

A general adsorption model is developed to describe the interactions between near-wall fluid molecules and solid surfaces. This model serves as a framework for the theoretical modelling of boundary slip phenomena. Based on this adsorption model, a new general model for the slip velocity of fluids on solid surfaces is introduced. The slip boundary condition at a fluid-solid interface has hitherto been considered separately for gases and liquids. In this paper, we show that the slip velocity in both gases and liquids may originate from dynamical adsorption processes at the interface. A unified analytical model that is valid for both gas-solid and liquid-solid slip boundary conditions is proposed based on surface science theory. The corroboration with the experimental data extracted from the literature shows that the proposed model provides an improved prediction compared to existing analytical models for gases at higher shear rates and close agreement for liquid-solid interfaces in general.

The surface diffusion coefficient for an arbitrarily curved fluid-fluid interface. (I). General expression

NASA Astrophysics Data System (ADS)

M. C. Sagis, Leonard

2001-03-01

In this paper, we develop a theory for the calculation of the surface diffusion coefficient for an arbitrarily curved fluid-fluid interface. The theory is valid for systems in hydrodynamic equilibrium, with zero mass-averaged velocities in the bulk and interfacial regions. We restrict our attention to systems with isotropic bulk phases, and an interfacial region that is isotropic in the plane parallel to the dividing surface. The dividing surface is assumed to be a simple interface, without memory effects or yield stresses. We derive an expression for the surface diffusion coefficient in terms of two parameters of the interfacial region: the coefficient for plane-parallel diffusion D (AB)aa(ξ) , and the driving force d(B)I||(ξ) . This driving force is the parallel component of the driving force for diffusion in the interfacial region. We derive an expression for this driving force using the entropy balance.

Modeling of Non-Isothermal Cryogenic Fluid Sloshing

NASA Technical Reports Server (NTRS)

Agui, Juan H.; Moder, Jeffrey P.

2015-01-01

A computational fluid dynamic model was used to simulate the thermal destratification in an upright self-pressurized cryostat approximately half-filled with liquid nitrogen and subjected to forced sinusoidal lateral shaking. A full three-dimensional computational grid was used to model the tank dynamics, fluid flow and thermodynamics using the ANSYS Fluent code. A non-inertial grid was used which required the addition of momentum and energy source terms to account for the inertial forces, energy transfer and wall reaction forces produced by the shaken tank. The kinetics-based Schrage mass transfer model provided the interfacial mass transfer due to evaporation and condensation at the sloshing interface. The dynamic behavior of the sloshing interface, its amplitude and transition to different wave modes, provided insight into the fluid process at the interface. The tank pressure evolution and temperature profiles compared relatively well with the shaken cryostat experimental test data provided by the Centre National D'Etudes Spatiales.

Molecular mechanics and structure of the fluid-solid interface in simple fluids

NASA Astrophysics Data System (ADS)

Wang, Gerald J.; Hadjiconstantinou, Nicolas G.

2017-09-01

Near a fluid-solid interface, the fluid spatial density profile is highly nonuniform at the molecular scale. This nonuniformity can have profound effects on the dynamical behavior of the fluid and has been shown to play an especially important role when modeling a wide variety of nanoscale heat and momentum transfer phenomena. We use molecular-mechanics arguments and molecular-dynamics (MD) simulations to develop a better understanding of the structure of the first fluid layer directly adjacent to the solid in the layering regime, as delineated by a nondimensional number that compares the effects of wall-fluid interaction to thermal energy. Using asymptotic analysis of the Nernst-Planck equation, we show that features of the fluid density profile close to the wall, such as the areal density of the first layer ΣFL (defined as the number of atoms in this layer per unit of fluid-solid interfacial area), can be expressed as polynomial functions of the fluid average density ρave. This is found to be in agreement with MD simulations, which also show that the width of the first layer hFL is a linear function of the average density and only a weak function of the temperature T . These results can be combined to show that, for system average densities corresponding to a dense fluid (ρave≥0.7 ), the ratio C ≡ΣFLρavehFL, representing a density enhancement with respect to the bulk fluid, depends only weakly on temperature and is essentially independent of density. Further MD simulations suggest that the above results, nominally valid for large systems (solid in contact with semi-infinite fluid), also describe fluid-solid interfaces under considerable nanoconfinement, provided ρave is appropriately defined.

Understanding the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dahms, Rainer N.

A generalized framework for multi-component liquid injections is presented to understand and predict the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions. The analysis focuses on the thermodynamic structure and the immiscibility state of representative gas-liquid interfaces. The most modern form of Helmholtz energy mixture state equation is utilized which exhibits a unique and physically consistent behavior over the entire two-phase regime of fluid densities. It is combined with generalized models for non-linear gradient theory and for liquid injections to quantify multi-component two-phase interface structures in global thermal equilibrium. Then, the Helmholtz free energy is minimized whichmore » determines the interfacial species distribution as a consequence. This minimal free energy state is demonstrated to validate the underlying assumptions of classic two-phase theory and spray atomization. However, under certain engine-relevant conditions for which corroborating experimental data are presented, this requirement for interfacial thermal equilibrium becomes unsustainable. A rigorously derived probability density function quantifies the ability of the interface to develop internal spatial temperature gradients in the presence of significant temperature differences between injected liquid and ambient gas. Then, the interface can no longer be viewed as an isolated system at minimal free energy. Instead, the interfacial dynamics become intimately connected to those of the separated homogeneous phases. Hence, the interface transitions toward a state in local equilibrium whereupon it becomes a dense-fluid mixing layer. A new conceptual view of a transitional liquid injection process emerges from a transition time scale analysis. Close to the nozzle exit, the two-phase interface still remains largely intact and more classic two-phase processes prevail as a consequence. Further downstream, however, the transition to dense-fluid mixing generally occurs before the liquid length is reached. As a result, the significance of the presented modeling expressions is established by a direct comparison to a reduced model, which utilizes widely applied approximations but fundamentally fails to capture the physical complexity discussed in this paper.« less

Understanding the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dahms, Rainer N., E-mail: Rndahms@sandia.gov

A generalized framework for multi-component liquid injections is presented to understand and predict the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions. The analysis focuses on the thermodynamic structure and the immiscibility state of representative gas-liquid interfaces. The most modern form of Helmholtz energy mixture state equation is utilized which exhibits a unique and physically consistent behavior over the entire two-phase regime of fluid densities. It is combined with generalized models for non-linear gradient theory and for liquid injections to quantify multi-component two-phase interface structures in global thermal equilibrium. Then, the Helmholtz free energy is minimized whichmore » determines the interfacial species distribution as a consequence. This minimal free energy state is demonstrated to validate the underlying assumptions of classic two-phase theory and spray atomization. However, under certain engine-relevant conditions for which corroborating experimental data are presented, this requirement for interfacial thermal equilibrium becomes unsustainable. A rigorously derived probability density function quantifies the ability of the interface to develop internal spatial temperature gradients in the presence of significant temperature differences between injected liquid and ambient gas. Then, the interface can no longer be viewed as an isolated system at minimal free energy. Instead, the interfacial dynamics become intimately connected to those of the separated homogeneous phases. Hence, the interface transitions toward a state in local equilibrium whereupon it becomes a dense-fluid mixing layer. A new conceptual view of a transitional liquid injection process emerges from a transition time scale analysis. Close to the nozzle exit, the two-phase interface still remains largely intact and more classic two-phase processes prevail as a consequence. Further downstream, however, the transition to dense-fluid mixing generally occurs before the liquid length is reached. The significance of the presented modeling expressions is established by a direct comparison to a reduced model, which utilizes widely applied approximations but fundamentally fails to capture the physical complexity discussed in this paper.« less

Understanding the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions

DOE PAGES

Dahms, Rainer N.

2016-04-26

A generalized framework for multi-component liquid injections is presented to understand and predict the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions. The analysis focuses on the thermodynamic structure and the immiscibility state of representative gas-liquid interfaces. The most modern form of Helmholtz energy mixture state equation is utilized which exhibits a unique and physically consistent behavior over the entire two-phase regime of fluid densities. It is combined with generalized models for non-linear gradient theory and for liquid injections to quantify multi-component two-phase interface structures in global thermal equilibrium. Then, the Helmholtz free energy is minimized whichmore » determines the interfacial species distribution as a consequence. This minimal free energy state is demonstrated to validate the underlying assumptions of classic two-phase theory and spray atomization. However, under certain engine-relevant conditions for which corroborating experimental data are presented, this requirement for interfacial thermal equilibrium becomes unsustainable. A rigorously derived probability density function quantifies the ability of the interface to develop internal spatial temperature gradients in the presence of significant temperature differences between injected liquid and ambient gas. Then, the interface can no longer be viewed as an isolated system at minimal free energy. Instead, the interfacial dynamics become intimately connected to those of the separated homogeneous phases. Hence, the interface transitions toward a state in local equilibrium whereupon it becomes a dense-fluid mixing layer. A new conceptual view of a transitional liquid injection process emerges from a transition time scale analysis. Close to the nozzle exit, the two-phase interface still remains largely intact and more classic two-phase processes prevail as a consequence. Further downstream, however, the transition to dense-fluid mixing generally occurs before the liquid length is reached. As a result, the significance of the presented modeling expressions is established by a direct comparison to a reduced model, which utilizes widely applied approximations but fundamentally fails to capture the physical complexity discussed in this paper.« less

Controlling the Mobility of the Fluid Interface of Moving Gas Bubbles or Liquid Drops by Using Micellar Solutions of Surfactants

NASA Technical Reports Server (NTRS)

Maldarelli, Charles; Papageorgiou, Demetrios

1998-01-01

Microgravity processes must rely on mechanisms other than buoyancy to move bubbles or droplets from one region to another in a continuous liquid phase. One suggested method is thermocapillary migration in which a temperature gradient is applied to the continuous phase. A significant and as yet unresolved impediment to the use of thermocapillary migration to direct bubble or drop motion is that these migrations can be significantly retarded by the adsorption onto the fluid particle surface of surface active impurities unavoidably present in the continuous or (if the particle is a liquid) droplet phases. The focus of our research was to develop a theory for remobilizing fluid particle interfaces retarded by a surfactant impurity in an effort to make more viable the use of thermocapillary migrations for the management of bubbles and drops in microgravity. We postulated that a surfactant at high bulk concentration which kinetically exchanges rapidly with the surface can restore interface mobility. The scaling arguments along with a discussion of the previous literature is reviewed in the context of the scaling framework. The specific objectives of the research were twofold. The first was to prove the remobilization theory by studying a model problem. As the mechanism for remobilization is independent of the force which drives the particle, the fluid particle shape and the presence of fluid inertia, we chose the simplest model consisting of a spherical bubble rising steadily by buoyancy in creeping flow. We solved the hydrodynamic and surfactant transport equations for rapid kinetic exchange to demonstrate that as the concentration increases, the Marangoni retardation at first increases (the low k behavior) and then decreases (the high k behavior). The second objective was to develop a method to determine the kinetic rate constants of a surfactant molecule, since this information is necessary to select surfactants which will exchange rapidly enough relative to the convective rate in the thermocapillary process of interest. To measure the kinetic rate, we measure the dynamic tension change accompanying adsorption onto an initially clean interface, or the re-equilibration in tension when an equilibrium interface is compressed. The dynamic tension measurements are made by a pendant bubble method, in which surfactant adsorbs onto a pendant bubble, and the tension is measured by analyzing the shape change in the bubble. We conclude this report by detailing the publications, presentations and doctoral thesis completed under the auspices of this grant.

Boundary slip and wetting properties of interfaces: correlation of the contact angle with the slip length.

PubMed

Voronov, Roman S; Papavassiliou, Dimitrios V; Lee, Lloyd L

2006-05-28

Correlations between contact angle, a measure of the wetting of surfaces, and slip length are developed using nonequilibrium molecular dynamics for a Lennard-Jones fluid in Couette flow between graphitelike hexagonal-lattice walls. The fluid-wall interaction is varied by modulating the interfacial energy parameter epsilonr=epsilonsfepsilonff and the size parameter sigmar=sigmasfsigmaff, (s=solid, f=fluid) to achieve hydrophobicity (solvophobicity) or hydrophilicity (solvophilicity). The effects of surface chemistry, as well as the effects of temperature and shear rate on the slip length are determined. The contact angle increases from 25 degrees to 147 degrees on highly hydrophobic surfaces (as epsilonr decreases from 0.5 to 0.1), as expected. The slip length is functionally dependent on the affinity strength parameters epsilonr and sigmar: increasing logarithmically with decreasing surface energy epsilonr (i.e., more hydrophobic), while decreasing with power law with decreasing size sigmar. The mechanism for the latter is different from the energetic case. While weak wall forces (small epsilonr) produce hydrophobicity, larger sigmar smoothes out the surface roughness. Both tend to increase the slip. The slip length grows rapidly with a high shear rate, as wall velocity increases three decades from 100 to 10(5) ms. We demonstrate that fluid-solid interfaces with low epsilonr and high sigmar should be chosen to increase slip and are prime candidates for drag reduction.

Alpine Serpentinite Geochemistry As Key To Define Timing Of Oceanic Lithosphere Accretion To The Subduction Plate Interface

NASA Astrophysics Data System (ADS)

Gilio, M.; Scambelluri, M.; Agostini, S.; Godard, M.; Pettke, D. T.; Angiboust, S.

2016-12-01

Isotopic (Pb, Sr and B) and trace element (B, Be, As, Sb, U, Th) signatures of serpentinites are useful geochemical tools to assess element exchange and fluid-rock interactions in subduction zone settings. They help to unravel geological history and tectonic evolution of subduction serpentinites and associated meta-oceanic crust. Sedimentary-derived fluid influx within HP plate interface environments strongly enriches serpentinites in As, Sb, B, U and Th and resets their B, Sr and Pb isotopic compositions. This HP metasomatic signature is preserved during exhumation and/or released at higher PT through de-serpentinization, fueling partial melting in the sub-arc mantle and recycling such fingerprint into arc magmas. This study focuses on the subduction recrystallization, geochemical diversity and fluid-rock interaction recorded by high- to ultra-high pressure (HP, UHP) Alpine serpentinites from the subducted oceanic plate (Cignana Unit, Zermatt-Saas Complex, Monviso and Lanzo Ultramafic Massifs). The As and Sb compositions of the HP-UHP Alpine ophiolitic rocks reveal the interaction between serpentinite and crust-derived fluids during their emplacement along the plate interface. This enables to define a hypothetical architecture of the Alpine subduction interface, considering large ultramafic slices. In this scenario, the Lanzo peridotite and serpentinite retain an As-Sb composition comparable to DM and PM: i.e. they experienced little exchange with sediment-derived fluids. Lanzo thus belonged to sections of the subducting plate, afar from the plate interface. Serpentinites from the Lago di Cignana Unit and Monviso and Voltri are richer in As and Sb, showing moderate to strong interaction with sediment- and crust-derived fluids during subduction (i.e. they behaved as open systems). These serpentinite slices accreted at the plate interface and exchanged with slab-derived fluids at different depths during Alpine subduction: Voltri accreted at shallower conditions (50-60 km) than Monviso Unit (around 80 km depth) and Lago di Cignana (about 100 km depth), and exchanged with sedimentary and crustal systems during the entire burial history. Their relatively lower density might act as buoyancy force, triggering the exhumation of much denser lithologies (eclogite and peridotite).

Nonlinear effects on the natural modes of oscillation of a finite length inviscid fluid column, supplement 2

NASA Technical Reports Server (NTRS)

Lyell, M. J.; Zhang, L.

1994-01-01

The aspects of nonlinear behavior of a finite length liquid column is investigated with an emphasis on bridge dynamics. The primary objectives are to determine the nonlinear corrections to the interface shape of a naturally oscillating finite length liquid column and to determine the nonlinear corrections to the oscillation frequencies for various modes of oscillation. Application of the Lindstedt-Poincare expansion in conjunction with the domain perturbation techniques results in an hierarchical system of equations.

Electrical impedance imaging in two-phase, gas-liquid flows: 1. Initial investigation

NASA Technical Reports Server (NTRS)

Lin, J. T.; Ovacik, L.; Jones, O. C.

1991-01-01

The determination of interfacial area density in two-phase, gas-liquid flows is one of the major elements impeding significant development of predictive tools based on the two-fluid model. Currently, these models require coupling of liquid and vapor at interfaces using constitutive equations which do not exist in any but the most rudimentary form. Work described herein represents the first step towards the development of Electrical Impedance Computed Tomography (EICT) for nonintrusive determination of interfacial structure and evolution in such flows.

Geochemical and Geomechanical Effects on Wellbore Cement Fractures

DOE PAGES

Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; ...

2014-12-31

Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnectionmore » of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is much lower than that of CO2-saturated brine. The study suggests that in deep geological reservoirs the geochemical and geomechanical processes have coupled effects on the wellbore cement fracture evolution and fluid flow along the fracture surfaces.« less

Hydro-Mechanical Modelling of Slow Slip Phenomena at the Subduction Interface.

NASA Astrophysics Data System (ADS)

Petrini, C.; Gerya, T.; Madonna, C.; van Dinther, Y.

2016-12-01

Subduction zones experience a spectrum of slip phenomena, ranging from large devastating megathrust earthquakes to aseismic slow slip events. Slow slip events, lasting hours to years and being perceptible only by instruments, are believed to have the capability to induce large earthquakes. It is also repeatedly proposed that such slow events are controlled by fluid-rock interactions along the subduction interface, thus calling for development of fully coupled seismo-hydro-mechanical modeling approaches to identify their physics and controlling parameters. We present a newly developed finite difference visco-elasto-plastic numerical code with marker-in-cell technique, which fully couples mechanical deformation and fluid flow. We use this to investigate how the presence of fluids in the pore space of a (de)compacting rock matrix affects elastic stress accumulation and release along a fluid-bearing subduction interface. The model simulates the spontaneous occurrence of quasi-periodic slow slip phenomena along self-consistently forming highly localized shearbands, which accommodate shear displacement between two plates. The produced elastic rebound events show a slip velocity on the order of cm/yr, which is in good agreement with measured data. The governing gradual strength decrease along the slowly propagating shear bands is related to a drop in total pressure caused by shear localization at nearly constant (slightly decreasing) fluid pressure. Gradual reduction of the difference between the total and fluid pressure decreases brittle/plastic strength of fluid-bearing rocks along the shear bands, thus providing a dynamic feedback mechanism for the accumulated elastic stress release at the subduction interface.

Turbulent entrainment across turbulent-nonturbulent interfaces in stably stratified mixing layers

NASA Astrophysics Data System (ADS)

Watanabe, T.; Riley, J. J.; Nagata, K.

2017-10-01

The entrainment process in stably stratified mixing layers is studied in relation to the turbulent-nonturbulent interface (TNTI) using direct numerical simulations. The statistics are calculated with the interface coordinate in an Eulerian frame as well as with the Lagrangian fluid particles entrained from the nonturbulent to the turbulent regions. The characteristics of entrainment change as the buoyancy Reynolds number Reb decreases and the flow begins to layer. The baroclinic torque delays the enstrophy growth of the entrained fluids at small Reb, while this effect is less efficient for large Reb. The entrained particle movement within the TNTI layer is dominated by the small dissipative scales, and the rapid decay of the kinetic energy dissipation rate due to buoyancy causes the entrained particle movement relative to the interface location to become slower. Although the Eulerian statistics confirm that there exists turbulent fluid with strong vorticity or with large buoyancy frequency near the TNTI, the entrained fluid particles circumvent these regions by passing through the TNTI in strain-dominant regions or in regions with small buoyancy frequency. The multiparticle statistics show that once the nonturbulent fluid volumes are entrained, they are deformed into flattened shapes in the vertical direction and diffuse in the horizontal direction. When Reb is large enough for small-scale turbulence to exist, the entrained fluid is able to penetrate into the turbulent core region. Once the flow begins to layer with decreasing Reb, however, the entrained fluid volume remains near the outer edge of the turbulent region and forms a stably stratified layer without vertical overturning.

Experimental Evaluation and Optimization of Flank Wear During Turning of AISI 4340 Steel with Coated Carbide Inserts Using Different Cutting Fluids

NASA Astrophysics Data System (ADS)

Lawal, S. A.; Choudhury, I. A.; Nukman, Y.

2015-01-01

The understanding of cutting fluids performance in turning process is very important in order to improve the efficiency of the process. This efficiency can be determined based on certain process parameters such as flank wear, cutting forces developed, temperature developed at the tool chip interface, surface roughness on the work piece, etc. In this study, the objective is to determine the influence of cutting fluids on flank wear during turning of AISI 4340 with coated carbide inserts. The performances of three types of cutting fluids were compared using Taguchi experimental method. The results show that palm kernel oil based cutting fluids performed better than the other two cutting fluids in reducing flank wear. Mathematical models for cutting parameters such as cutting speed, feed rate, depth of cut and cutting fluids were obtained from regression analysis using MINITAB 14 software to predict flank wear. Experiments were conducted based on the optimized values to validate the regression equations for flank wear and 5.82 % error was obtained. The optimal cutting parameters for the flank wear using S/N ratio were 160 m/min of cutting speed (level 1), 0.18 mm/rev of feed (level 1), 1.75 mm of depth of cut (level 2) and 2.97 mm2/s palm kernel oil based cutting fluid (level 3). ANOVA shows cutting speed of 85.36 %; and feed rate 4.81 %) as significant factors.

A single-scattering correction for the seismo-acoustic parabolic equation.

PubMed

Collins, Michael D

2012-04-01

An efficient single-scattering correction that does not require iterations is derived and tested for the seismo-acoustic parabolic equation. The approach is applicable to problems involving gradual range dependence in a waveguide with fluid and solid layers, including the key case of a sloping fluid-solid interface. The single-scattering correction is asymptotically equivalent to a special case of a single-scattering correction for problems that only have solid layers [Küsel et al., J. Acoust. Soc. Am. 121, 808-813 (2007)]. The single-scattering correction has a simple interpretation (conservation of interface conditions in an average sense) that facilitated its generalization to problems involving fluid layers. Promising results are obtained for problems in which the ocean bottom interface has a small slope.

A Gas-Kinetic Method for Hyperbolic-Elliptic Equations and Its Application in Two-Phase Fluid Flow

NASA Technical Reports Server (NTRS)

Xu, Kun

1999-01-01

A gas-kinetic method for the hyperbolic-elliptic equations is presented in this paper. In the mixed type system, the co-existence and the phase transition between liquid and gas are described by the van der Waals-type equation of state (EOS). Due to the unstable mechanism for a fluid in the elliptic region, interface between the liquid and gas can be kept sharp through the condensation and evaporation process to remove the "averaged" numerical fluid away from the elliptic region, and the interface thickness depends on the numerical diffusion and stiffness of the phase change. A few examples are presented in this paper for both phase transition and multifluid interface problems.

Simulating shock-bubble interactions at water-gelatin interfaces

NASA Astrophysics Data System (ADS)

Adami, Stefan; Kaiser, Jakob; Bermejo-Moreno, Ivan; Adams, Nikolaus

2016-11-01

Biomedical problems are often driven by fluid dynamics, as in vivo organisms are usually composed of or filled with fluids that (strongly) affected their physics. Additionally, fluid dynamical effects can be used to enhance certain phenomena or destroy organisms. As examples, we highlight the benign potential of shockwave-driven kidney-stone lithotripsy or sonoporation (acoustic cavitation of microbubbles) to improve drug delivery into cells. During the CTR SummerProgram 2016 we have performed axisymmetric three-phase simulations of a shock hitting a gas bubble in water near a gelatin interface mimicking the fundamental process during sonoporation. We used our multi-resolution finite volume method with sharp interface representation (level-set), WENO-5 shock capturing and interface scale-separation and compared the results with a diffuse-interface method. Qualitatively our simulation results agree well with the reference. Due to the interface treatment the pressure profiles are sharper in our simulations and bubble collapse dynamics are predicted at shorter time-scales. Validation with free-field collapse (Rayleigh collapse) shows very good agreement. The project leading to this application has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant agreement No 667483).

The influence of a surface tension minimum on the convective motion of a fluid in microgravity (D1 mission results)

NASA Astrophysics Data System (ADS)

Limbourg, M. C.; Legros, J. C.; Petre, G.

The experiment STEM (Surface Tension Minimum) was performed in an experimental cell integrated in the FMP (Fluid Physics Module) during the D1 mission of Spacelab. The observation volume (1×2×3) cm3 was constituted by a stainless steel frame and by two optical Pyrex windows. It was fixed on the front disk of the FPM. The cell was filled under microgravity conditions by an aqueous solution of n-heptanol 6,04 10-3 molal. At equilibrium this system presents a minimum of surface tension as a function of temperature around 40°C. The fluid was heated from the front disk side of the cell. A temperature difference of 35°C was maintained between two opposite sides of the cell, by using the large heat capacity of a water reservoir in thermal contact with the cold side of the cell. The thermal gradient was parallel to the liquid/gas interface. The motions of the fluid were recorded on video-tapes and the velocities were determined by following latex particles used as tracers. The convective pattern is analysed and compared with ground experiments. In this case the tracer trajectories allow to determine the convective patterns and the velocities are determined by laser doppler anemometry.

A new method for ultrasound detection of interfacial position in gas-liquid two-phase flow.

PubMed

Coutinho, Fábio Rizental; Ofuchi, César Yutaka; de Arruda, Lúcia Valéria Ramos; Neves, Flávio; Morales, Rigoberto E M

2014-05-22

Ultrasonic measurement techniques for velocity estimation are currently widely used in fluid flow studies and applications. An accurate determination of interfacial position in gas-liquid two-phase flows is still an open problem. The quality of this information directly reflects on the accuracy of void fraction measurement, and it provides a means of discriminating velocity information of both phases. The algorithm known as Velocity Matched Spectrum (VM Spectrum) is a velocity estimator that stands out from other methods by returning a spectrum of velocities for each interrogated volume sample. Interface detection of free-rising bubbles in quiescent liquid presents some difficulties for interface detection due to abrupt changes in interface inclination. In this work a method based on velocity spectrum curve shape is used to generate a spatial-temporal mapping, which, after spatial filtering, yields an accurate contour of the air-water interface. It is shown that the proposed technique yields a RMS error between 1.71 and 3.39 and a probability of detection failure and false detection between 0.89% and 11.9% in determining the spatial-temporal gas-liquid interface position in the flow of free rising bubbles in stagnant liquid. This result is valid for both free path and with transducer emitting through a metallic plate or a Plexiglas pipe.

A New Method for Ultrasound Detection of Interfacial Position in Gas-Liquid Two-Phase Flow

PubMed Central

Coutinho, Fábio Rizental; Ofuchi, César Yutaka; de Arruda, Lúcia Valéria Ramos; Jr., Flávio Neves; Morales, Rigoberto E. M.

2014-01-01

Ultrasonic measurement techniques for velocity estimation are currently widely used in fluid flow studies and applications. An accurate determination of interfacial position in gas-liquid two-phase flows is still an open problem. The quality of this information directly reflects on the accuracy of void fraction measurement, and it provides a means of discriminating velocity information of both phases. The algorithm known as Velocity Matched Spectrum (VM Spectrum) is a velocity estimator that stands out from other methods by returning a spectrum of velocities for each interrogated volume sample. Interface detection of free-rising bubbles in quiescent liquid presents some difficulties for interface detection due to abrupt changes in interface inclination. In this work a method based on velocity spectrum curve shape is used to generate a spatial-temporal mapping, which, after spatial filtering, yields an accurate contour of the air-water interface. It is shown that the proposed technique yields a RMS error between 1.71 and 3.39 and a probability of detection failure and false detection between 0.89% and 11.9% in determining the spatial-temporal gas-liquid interface position in the flow of free rising bubbles in stagnant liquid. This result is valid for both free path and with transducer emitting through a metallic plate or a Plexiglas pipe. PMID:24858961

The formation of spikes in the displacement of miscible fluids

NASA Technical Reports Server (NTRS)

Rashidnia, N.; Balasubramaniam, R.; Schroer, R. T.

2004-01-01

We report on experiments in which a more viscous fluid displaces a less viscous one in a vertical cylindrical tube. These experiments were performed using silicone oils in a vertical pipette of small diameter. The more viscous fluid also had a slightly larger density than the less viscous fluid. In the initial configuration, the fluids were at rest, and the interface was nominally flat. A dye was added to the more viscous fluid for ease of observation of the interface between the fluids. The flow was initiated by pumping the more viscous fluid into the less viscous one. The displacement velocity was such that the Reynolds number was smaller than unity and the Peclet number for mass transfer between the fluids was large compared to unity. For upward displacement of the more viscous fluid from an initially stable configuration, an axisymmetric finger was observed under all conditions. However, a needle-shaped spike was seen to propagate from the main finger in many cases, similar to that observed by Petitjeans and Maxworthy for the displacement of a more viscous fluid by a less viscous one.

Numerical Simulations for Turbulent Drag Reduction Using Liquid Infused Surfaces

NASA Astrophysics Data System (ADS)

Arenas-Navarro, Isnardo

Numerical simulations of the turbulent flow over Super Hydrophobic and Liquid Infused Surfaces have been performed in this work. Three different textured surfaces have been considered: longitudinal square bars, transversal square bars and staggered cubes. The numerical code combines an immersed boundary method to mimic the substrate and a level set method to track the interface. Liquid Infused Surfaces reduce the drag by locking a lubricant within structured roughness to facilitate a slip velocity at the surface interface. The conceptual idea is similar to Super Hydrophobic Surfaces, which rely on a lubricant air layer, whereas liquid-infused surfaces use a preferentially wetting liquid lubricant to create a fluid-fluid interface. This slipping interface has been shown to be an effective method of passively reducing skin friction drag in turbulent flows. Details are given on the effect of the viscosity ratio between the two fluids and the dynamics of the interface on drag reduction. An attempt has been made to reconcile Super-Hydrophobic, Liquid Infused and rough wall under the same framework by correlating the drag to the wall normal velocity fluctuations.

Interfacing the Generalized Fluid System Simulation Program with the SINDA/G Thermal Program

NASA Technical Reports Server (NTRS)

Schallhorn, Paul; Palmiter, Christopher; Farmer, Jeffery; Lycans, Randall; Tiller, Bruce

2000-01-01

A general purpose, one dimensional fluid flow code has been interfaced with the thermal analysis program SINDA/G. The flow code, GFSSP, is capable of analyzing steady state and transient flow in a complex network. The flow code is capable of modeling several physical phenomena including compressibility effects, phase changes, body forces (such as gravity and centrifugal) and mixture thermodynamics for multiple species. The addition of GFSSP to SINDA/G provides a significant improvement in convective heat transfer modeling for SINDA/G. The interface development was conducted in two phases. This paper describes the first (which allows for steady and quasi-steady - unsteady solid, steady fluid - conjugate heat transfer modeling). The second (full transient conjugate heat transfer modeling) phase of the interface development will be addressed in a later paper. Phase 1 development has been benchmarked to an analytical solution with excellent agreement. Additional test cases for each development phase demonstrate desired features of the interface. The results of the benchmark case, three additional test cases and a practical application are presented herein.

Experimental investigation and numerical simulation of a copper micro-channel heat exchanger with HFE-7200 working fluid

NASA Astrophysics Data System (ADS)

Borquist, Eric

Ever increasing cost and consumption of global energy resources has inspired the development of energy harvesting techniques which increase system efficiency, sustainability, and environmental impact by using waste energy otherwise lost to the surroundings. As part of a larger effort to produce a multi-energy source prototype, this study focused on the fabrication and testing of a waste heat recovery micro-channel heat exchanger. Reducing cost and facility requirements were a priority for potential industry and commercial adoption of such energy harvesting devices. During development of the micro-channel heat exchanger, a new fabrication process using mature technologies was created that reduced cost, time, and required equipment. Testing involved filling the micro-channel heat exchanger with 3MTM NovecTM HFE-7200 working fluid. The working fluid was chosen for appropriate physical and environmental properties for the prototypes intended application. Using a dry heat exchanger as the baseline, the addition of the working fluid proved advantageous by increasing energy output by 8% while decreasing overall device temperatures. Upon successful experimental testing of the physical device, internal operation was determined based on implementation of the lattice Boltzmann method, a physics-based statistical method that actively tracked the phase change occurring in a simulated micro-channel. The simulation demonstrated three primary areas of phase change occurring, surfaces adjacent to where the heat source and heat sink were located and the bulk vapor-liquid interface, which agreed with initial device design intentions. Condensation film thickness grew to 5microm over the time interval, while the bulk interface tracked from initial 12microm from the lid to 20microm from the lid. Surface tension effects dominating vapor pressure kept the liquid near the heat source; however, the temperature and pressure VLE data suggested vapor interface growth from the heated surface to 5microm above the heated copper plate. Reinforcing the simulation results, including location and movement of phase interfaces, was accomplished through a thorough ten dimensionless number analyses. These specialized ratios indicated dominant fluid and heat transfer behavior including phase change conditions. Thus, fabrication and empirical results for the heat energy harvesting prototype were successful and computational modeling provided understanding of applicable internal system behavior.

Potential application of artificial concepts to aerodynamic simulation

NASA Technical Reports Server (NTRS)

Kutler, P.; Mehta, U. B.; Andrews, A.

1984-01-01

The concept of artificial intelligence as it applies to computational fluid dynamics simulation is investigated. How expert systems can be adapted to speed the numerical aerodynamic simulation process is also examined. A proposed expert grid generation system is briefly described which, given flow parameters, configuration geometry, and simulation constraints, uses knowledge about the discretization process to determine grid point coordinates, computational surface information, and zonal interface parameters.

A Theoretical Study of Remobilizing Surfactant Retarded Fluid Particle Interfaces

NASA Technical Reports Server (NTRS)

Wang, Yanping; Papageorgiou, Dimitri; Maldarelli, Charles

1996-01-01

Microgravity processes must rely on mechanisms other than bouyancy to move bubbles or droplets from one region to another in a continuous liquid phase. One suggested method is thermocapillary migration in which a temperature gradient is applied to the continuous phase. When a fluid particle contacts this gradient, one pole of the particle becomes warmer than the opposing pole. The interfacial tension between the drop or bubble phase and the continuous phase usually decreases with temperature. Thus the cooler pole is of higher interfacial tension than the warmer pole, and the interface is tugged in the direction of the cooler end. This thermocapillary or thermally induced Marangoni surface stress causes a fluid streaming in the continuous phase from which develops a viscous shear traction and pressure gradient which together propel the particle in the direction of the warmer fluid. In this paper, we provide a theoretical basis for remobilizing surfactant retarded fluid particle interfaces in an effort to make viable the use of thermocapillary migrations for the management of bubbles and drops in microgravity,

Vibroconvective mixing applied to vertical Bridgman growth

NASA Astrophysics Data System (ADS)

Zawilski, Kevin T.; Claudia, M.; Custodio, C.; DeMattei, Robert C.; Feigelson, Robert S.

2003-10-01

A promising method for stirring melts during vertical Bridgman growth is the coupled vibrational stirring (CVS) method. It involves the application of low frequency vibrations to the outside of the growth ampoule and produces strong flows emanating from the fluid surface. Although the technique was pioneered a number of years ago, previous studies have not provided sufficient information to explain how to control CVS generated flows in a particular system. This paper examines both the fluid flow produced by CVS and the effect of these flows on a model oxide growth system. CVS generated flows were studied using tracer particles in a water/glycerin system. The particle velocities were measured as a function of distance from the fluid surface. A large velocity gradient, decreasing from the surface, was found to be present. The velocity profile produced was dependent on the vibrational amplitude and frequency, the crucible diameter, and the fluid viscosity. The effects of CVS flows on the crystal growth interface were studied using NaNO 3 as a model oxide. Under non-growth conditions (i.e. no furnace or crucible translation), the solid-liquid interface position was found to be a strong function of vibrational frequency once CVS generated flows approached the interface. During crystal growth, undesirable growth rate fluctuations were found as the growth interface moved into regions of increasing fluid flow. This data suggests that a control system in which CVS flows are continuously decreased during growth to maintain a constant flow rate in the vicinity of the growth interface is necessary in order to prevent or reduce growth rate fluctuations.

Spherical solid model system: Exact evaluation of the van der Waals interaction between a microscopic or submacroscopic spherical solid and a deformable fluid interface

NASA Astrophysics Data System (ADS)

Wang, Y. Z.; Wang, B.; Xiong, X. M.; Zhang, J. X.

2011-03-01

In many previous research work associated with studying the deformation of the fluid interface interacting with a solid, the theoretical calculation of the surface energy density on the deformed fluid interface (or its interaction surface pressure) is often approximately obtained by using the expression for the interaction energy per unit area (or pressure) between two parallel macroscopic plates, e.g. σ(D) = - A / 12 πD2or π(D) = - A / 6 πD3for the van der Waals (vdW) interaction, through invoking the Derjaguin approximation (DA). This approximation however would result in over- or even inaccurate-prediction of the interaction force and the corresponding deformation of the fluid interface due to the invalidation of Derjaguin approximation in cases of microscopic or submacroscopic solids. To circumvent the above limitations existing in the previous DA-based theoretical work, a more accurate and quantitative theoretical model, available for exactly calculating the vdW-induced deformation of a planar fluid interface interacting with a sphere, and the interaction forces taking into account its change, is presented in this paper. The validity and advantage of the new mathematical and physical technique is rigorously verified by comparison with the numerical results on basis of the previous Paraboloid solid (PS) model and the Hamaker's sphere-flat expression (viz. F = - 2 Aa3 / (3 D2( D + 2 a) 2)), as well as its well-known DA-based general form of F / a = - A / 6z p02.

Spatiotemporal distribution of low-frequency earthquakes in Southwest Japan: Evidence for fluid migration and magmatic activity

NASA Astrophysics Data System (ADS)

Yu, Zhiteng; Zhao, Dapeng; Niu, Xiongwei; Li, Jiabiao

2018-01-01

Low-frequency earthquakes (LFEs) in the lower crust and uppermost mantle are widely observed in Southwest Japan, and they occur not only along the subducting Philippine Sea (PHS) slab interface but also beneath active arc volcanoes. The volcanic LFEs are still not well understood because of their limited quantities and less reliable hypocenter locations. In this work, seismic tomography is used to determine detailed three-dimensional (3-D) P- and S-wave velocity (Vp and Vs) models of the crust and upper mantle beneath Southwest Japan, and then the obtained 3-D Vp and Vs models are used to relocate the volcanic LFEs precisely. The results show that the volcanic LFEs can be classified into two types: pipe-like and swarm-like LFEs, and both of them are located in or around zones of low-velocity and high-Poisson's ratio anomalies in the crust and uppermost mantle beneath the active volcanoes. The pipe-like LFEs may be related to the fluid migration from the lower crust or the uppermost mantle, whereas the swarm-like LFEs may be related to local magmatic activities or small magma chambers. The number of LFEs sometimes increases sharply before or after a nearby large crustal earthquake which may cause cracks and fluid migration. The spatiotemporal distribution of the LFEs may indicate the track of migrating fluids. As compared with the tectonic LFEs along the PHS slab interface, the volcanic LFEs are more sensitive to fluid migration and local magmatic activities. High pore pressures play an important role in triggering both types of LFEs in Southwest Japan.

Microencapsulation and Electrostatic Processing Device

NASA Technical Reports Server (NTRS)

Morrison, Dennis R. (Inventor); Mosier, Benjamin (Inventor); Cassanto, John M. (Inventor)

2001-01-01

A microencapsulation and electrostatic processing (MEP) device is provided for forming microcapsules. In one embodiment, the device comprises a chamber having a filter which separates a first region in the chamber from a second region in the chamber. An aqueous solution is introduced into the first region through an inlet port, and a hydrocarbon/ polymer solution is introduced into the second region through another inlet port. The filter acts to stabilize the interface and suppress mixing between the two immiscible solutions as they are being introduced into their respective regions. After the solutions have been introduced and have become quiescent, the interface is gently separated from the filter. At this point, spontaneous formation of microcapsules at the interface may begin to occur, or some fluid motion may be provided to induce microcapsule formation. In any case, the fluid shear force at the interface is limited to less than 100 dynes/sq cm. This low-shear approach to microcapsule formation yields microcapsules with good sphericity and desirable size distribution. The MEP device is also capable of downstream processing of microcapsules, including rinsing, re-suspension in tertiary fluids, electrostatic deposition of ancillary coatings, and free-fluid electrophoretic separation of charged microcapsules.

Visualization of the equilibrium position of colloidal particles at fluid-water interfaces by deposition of nanoparticles

NASA Astrophysics Data System (ADS)

Sabapathy, Manigandan; Kollabattula, Viswas; Basavaraj, Madivala G.; Mani, Ethayaraja

2015-08-01

We present a general yet simple method to measure the contact angle of colloidal particles at fluid-water interfaces. In this method, the particles are spread at the required fluid-water interface as a monolayer. In the water phase a chemical reaction involving reduction of a metal salt such as aurochloric acid is initiated. The metal grows as a thin film or islands of nanoparticles on the particle surface exposed to the water side of the interface. Analyzing the images of particles by high resolution scanning microscopy (HRSEM), we trace the three phase contact line up to which deposition of the metal film occurs. From geometrical relations, the three phase contact angle is then calculated. We report the measurements of the contact angle of silica and polystyrene (PS) particles at different interfaces such as air-water, decane-water and octanol-water. We have also applied this method to measure the contact angle of surfactant treated polystyrene particles at the air-water interface, and we find a non-monotonic change of the contact angle with the concentration of the surfactant. Our results are compared with the well-known gel trapping technique and we find good comparison with previous measurements.We present a general yet simple method to measure the contact angle of colloidal particles at fluid-water interfaces. In this method, the particles are spread at the required fluid-water interface as a monolayer. In the water phase a chemical reaction involving reduction of a metal salt such as aurochloric acid is initiated. The metal grows as a thin film or islands of nanoparticles on the particle surface exposed to the water side of the interface. Analyzing the images of particles by high resolution scanning microscopy (HRSEM), we trace the three phase contact line up to which deposition of the metal film occurs. From geometrical relations, the three phase contact angle is then calculated. We report the measurements of the contact angle of silica and polystyrene (PS) particles at different interfaces such as air-water, decane-water and octanol-water. We have also applied this method to measure the contact angle of surfactant treated polystyrene particles at the air-water interface, and we find a non-monotonic change of the contact angle with the concentration of the surfactant. Our results are compared with the well-known gel trapping technique and we find good comparison with previous measurements. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr03369a

Numerical Modelling of Three-Fluid Flow Using The Level-set Method

NASA Astrophysics Data System (ADS)

Li, Hongying; Lou, Jing; Shang, Zhi

2014-11-01

This work presents a numerical model for simulation of three-fluid flow involving two different moving interfaces. These interfaces are captured using the level-set method via two different level-set functions. A combined formulation with only one set of conservation equations for the whole physical domain, consisting of the three different immiscible fluids, is employed. Numerical solution is performed on a fixed mesh using the finite volume method. Surface tension effect is incorporated using the Continuum Surface Force model. Validation of the present model is made against available results for stratified flow and rising bubble in a container with a free surface. Applications of the present model are demonstrated by a variety of three-fluid flow systems including (1) three-fluid stratified flow, (2) two-fluid stratified flow carrying the third fluid in the form of drops and (3) simultaneous rising and settling of two drops in a stationary third fluid. The work is supported by a Thematic and Strategic Research from A*STAR, Singapore (Ref. #: 1021640075).

Experimental and Numerical Study of the Evaporation of Water at Low Pressures.

PubMed

Kazemi, Mohammad Amin; Nobes, David S; Elliott, Janet A W

2017-05-09

Although evaporation is considered to be a surface phenomenon, the rate of molecular transport across a liquid-vapor boundary is strongly dependent on the coupled fluid dynamics and heat transfer in the bulk fluids. Recent experimental thermocouple measurements of the temperature field near the interface of evaporating water into its vapor have begun to show the role of heat transfer in evaporation. However, the role of fluid dynamics has not been explored sufficiently. Here, we have developed a mathematical model to describe the coupling of the heat, mass, and momentum transfer in the fluids with the transport phenomena at the interface. The model was used to understand the experimentally obtained velocity field in the liquid and temperature profiles in the liquid and vapor, in evaporation from a concave meniscus for various vacuum pressures. By using the model, we have shown that an opposing buoyancy flow suppressed the thermocapillary flow in the liquid during evaporation at low pressures in our experiments. As such, in the absence of thermocapillary convection, the evaporation is controlled by heat transfer to the interface, and the predicted behavior of the system is independent of choosing between the existing theoretical expressions for evaporation flux. Furthermore, we investigated the temperature discontinuity at the interface and confirmed that the discontinuity strongly depends on the heat flux from the vapor side, which depends on the geometrical shape of the interface.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Antonelli, Perry Edward

A low-level model-to-model interface is presented that will enable independent models to be linked into an integrated system of models. The interface is based on a standard set of functions that contain appropriate export and import schemas that enable models to be linked with no changes to the models themselves. These ideas are presented in the context of a specific multiscale material problem that couples atomistic-based molecular dynamics calculations to continuum calculations of fluid ow. These simulations will be used to examine the influence of interactions of the fluid with an adjacent solid on the fluid ow. The interface willmore » also be examined by adding it to an already existing modeling code, Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) and comparing it with our own molecular dynamics code.« less

Cryogenic Propellant Feed System Analytical Tool Development

NASA Technical Reports Server (NTRS)

Lusby, Brian S.; Miranda, Bruno M.; Collins, Jacob A.

2011-01-01

The Propulsion Systems Branch at NASA s Lyndon B. Johnson Space Center (JSC) has developed a parametric analytical tool to address the need to rapidly predict heat leak into propellant distribution lines based on insulation type, installation technique, line supports, penetrations, and instrumentation. The Propellant Feed System Analytical Tool (PFSAT) will also determine the optimum orifice diameter for an optional thermodynamic vent system (TVS) to counteract heat leak into the feed line and ensure temperature constraints at the end of the feed line are met. PFSAT was developed primarily using Fortran 90 code because of its number crunching power and the capability to directly access real fluid property subroutines in the Reference Fluid Thermodynamic and Transport Properties (REFPROP) Database developed by NIST. A Microsoft Excel front end user interface was implemented to provide convenient portability of PFSAT among a wide variety of potential users and its ability to utilize a user-friendly graphical user interface (GUI) developed in Visual Basic for Applications (VBA). The focus of PFSAT is on-orbit reaction control systems and orbital maneuvering systems, but it may be used to predict heat leak into ground-based transfer lines as well. PFSAT is expected to be used for rapid initial design of cryogenic propellant distribution lines and thermodynamic vent systems. Once validated, PFSAT will support concept trades for a variety of cryogenic fluid transfer systems on spacecraft, including planetary landers, transfer vehicles, and propellant depots, as well as surface-based transfer systems. The details of the development of PFSAT, its user interface, and the program structure will be presented.

A non-oscillatory energy-splitting method for the computation of compressible multi-fluid flows

NASA Astrophysics Data System (ADS)

Lei, Xin; Li, Jiequan

2018-04-01

This paper proposes a new non-oscillatory energy-splitting conservative algorithm for computing multi-fluid flows in the Eulerian framework. In comparison with existing multi-fluid algorithms in the literature, it is shown that the mass fraction model with isobaric hypothesis is a plausible choice for designing numerical methods for multi-fluid flows. Then we construct a conservative Godunov-based scheme with the high order accurate extension by using the generalized Riemann problem solver, through the detailed analysis of kinetic energy exchange when fluids are mixed under the hypothesis of isobaric equilibrium. Numerical experiments are carried out for the shock-interface interaction and shock-bubble interaction problems, which display the excellent performance of this type of schemes and demonstrate that nonphysical oscillations are suppressed around material interfaces substantially.

Shock wave-free interface interaction

NASA Astrophysics Data System (ADS)

Frolov, Roman; Minev, Peter; Krechetnikov, Rouslan

2016-11-01

The problem of shock wave-free interface interaction has been widely studied in the context of compressible two-fluid flows using analytical, experimental, and numerical techniques. While various physical effects and possible interaction patterns for various geometries have been identified in the literature, the effects of viscosity and surface tension are usually neglected in such models. In our study, we apply a novel numerical algorithm for simulation of viscous compressible two-fluid flows with surface tension to investigate the influence of these effects on the shock-interface interaction. The method combines together the ideas from Finite Volume adaptation of invariant domains preserving algorithm for systems of hyperbolic conservation laws by Guermond and Popov and ADI parallel solver for viscous incompressible NSEs by Guermond and Minev. This combination has been further extended to a two-fluid flow case, including surface tension effects. Here we report on a quantitative study of how surface tension and viscosity affect the structure of the shock wave-free interface interaction region.

Capillary equilibrium and sintering kinetics in dispersed media and catalysts

NASA Astrophysics Data System (ADS)

Delannay, Francis

2016-06-01

The evolution of an aggregate of particles embedded in a fluid phase, no matter whether a liquid, a vapor, or a mixture of both, is determined by the dependence of the equilibrium interface area on porosity volume fraction. In system with open porosity, this equilibrium can be analyzed using a model representing the particles as a collection of cones of revolution, the number of which is the average particle coordination number. The accuracy of the model has been assessed using in situ X-ray microtomography. The model makes possible the computation of the driving force for sintering, commonly called sintering stress. It allows the mapping of the domains of relative density, coordination number, and dihedral angle that bring about aggregate densification or expansion. The contribution of liquid/vapor interfaces is enlightened, as well as the dependence of the equilibrium fluid phase distribution on particle size. Applied to foams and emulsions, the model provides insight into the relationship between osmotic pressure and coordination. Interface-governed transport mechanisms are considered dominant in the macroscopic viscosity. Both sintering stress and viscosity parameters strongly depend on particle size. The capacity of modeling the simultaneous particle growth is thus essential. The analysis highlights the microstructural parameters and material properties needed for kinetics simulation.

Massive radius-dependent flow slippage in carbon nanotubes.

PubMed

Secchi, Eleonora; Marbach, Sophie; Niguès, Antoine; Stein, Derek; Siria, Alessandro; Bocquet, Lydéric

2016-09-08

Measurements and simulations have found that water moves through carbon nanotubes at exceptionally high rates owing to nearly frictionless interfaces. These observations have stimulated interest in nanotube-based membranes for applications including desalination, nano-filtration and energy harvesting, yet the exact mechanisms of water transport inside the nanotubes and at the water-carbon interface continue to be debated because existing theories do not provide a satisfactory explanation for the limited number of experimental results available so far. This lack of experimental results arises because, even though controlled and systematic studies have explored transport through individual nanotubes, none has met the considerable technical challenge of unambiguously measuring the permeability of a single nanotube. Here we show that the pressure-driven flow rate through individual nanotubes can be determined with unprecedented sensitivity and without dyes from the hydrodynamics of water jets as they emerge from single nanotubes into a surrounding fluid. Our measurements reveal unexpectedly large and radius-dependent surface slippage in carbon nanotubes, and no slippage in boron nitride nanotubes that are crystallographically similar to carbon nanotubes, but electronically different. This pronounced contrast between the two systems must originate from subtle differences in the atomic-scale details of their solid-liquid interfaces, illustrating that nanofluidics is the frontier at which the continuum picture of fluid mechanics meets the atomic nature of matter.

Massive radius-dependent flow slippage in carbon nanotubes

NASA Astrophysics Data System (ADS)

Secchi, Eleonora; Marbach, Sophie; Niguès, Antoine; Stein, Derek; Siria, Alessandro; Bocquet, Lydéric

2016-09-01

Measurements and simulations have found that water moves through carbon nanotubes at exceptionally high rates owing to nearly frictionless interfaces. These observations have stimulated interest in nanotube-based membranes for applications including desalination, nano-filtration and energy harvesting, yet the exact mechanisms of water transport inside the nanotubes and at the water-carbon interface continue to be debated because existing theories do not provide a satisfactory explanation for the limited number of experimental results available so far. This lack of experimental results arises because, even though controlled and systematic studies have explored transport through individual nanotubes, none has met the considerable technical challenge of unambiguously measuring the permeability of a single nanotube. Here we show that the pressure-driven flow rate through individual nanotubes can be determined with unprecedented sensitivity and without dyes from the hydrodynamics of water jets as they emerge from single nanotubes into a surrounding fluid. Our measurements reveal unexpectedly large and radius-dependent surface slippage in carbon nanotubes, and no slippage in boron nitride nanotubes that are crystallographically similar to carbon nanotubes, but electronically different. This pronounced contrast between the two systems must originate from subtle differences in the atomic-scale details of their solid-liquid interfaces, illustrating that nanofluidics is the frontier at which the continuum picture of fluid mechanics meets the atomic nature of matter.

Instability of two-layer film flows due to the interacting effects of surfactants, inertia, and gravity

NASA Astrophysics Data System (ADS)

Kalogirou, Anna

2018-03-01

We consider a two-fluid shear flow where the interface between the two fluids is coated with an insoluble surfactant. An asymptotic model is derived in the thin-layer approximation, consisting of a set of nonlinear partial differential equations describing the evolution of the film and surfactant disturbances at the interface. The model includes important physical effects such as Marangoni forces (caused by the presence of surfactant), inertial forces arising in the thick fluid layer, as well as gravitational forces. The aim of this study is to investigate the effect of density stratification or gravity—represented through the Bond number Bo—on the flow stability and the interplay between the different (de)stabilisation mechanisms. It is found that gravity can either stabilise or destabilise the interface (depending on fluid properties) but not always as intuitively anticipated. Different traveling-wave branches are presented for varying Bo, and the destabilising mechanism associated with the Marangoni forces is discussed.

The ISS Fluids and Combustion Facility: Experiment Accommodations Summary

NASA Technical Reports Server (NTRS)

Corban, Robert R.; Simons, Stephen N. (Technical Monitor)

2001-01-01

The International Space Station's (ISS's) Fluids and Combustion Facility (FCF) is in the process of final design and development activities to accommodate a wide range of experiments in the fields of combustion science and fluid physics. The FCF is being designed to provide potential experiments with well defined interfaces that can meet the experimenters requirements, provide the flexibility for on-orbit reconfiguration, and provide the maximum capability within the ISS resources and constraints. As a multi-disciplined facility, the FCF supports various experiments and scientific objectives, which will be developed in the future and are not completely defined at this time. Since developing experiments to be performed within FCF is a continuous process throughout the FCF's operational lifetime, each individual experiment must determine the best configuration of utilizing facility capabilities and resources with augmentation of specific experiment hardware. Configurations of potential experiments in the FCF has been on-going to better define the FCF interfaces and provide assurances that the FCF design will meet its design requirements. This paper provides a summary of ISS resources and FCF capabilities, which are available for potential ISS FCF users. Also, to better understand the utilization of the FCF a description of a various experiment layouts and associated operations in the FCF are provided.

Flow-Control Unit For Nitrogen And Hydrogen Gases

NASA Technical Reports Server (NTRS)

Chang, B. J.; Novak, D. W.

1990-01-01

Gas-flow-control unit installed and removed as one piece replaces system that included nine separately serviced components. Unit controls and monitors flows of nitrogen and hydrogen gases. Designed for connection via fluid-interface manifold plate, reducing number of mechanical fluid-interface connections from 18 to 1. Unit provides increasing reliability, safety, and ease of maintenance, and for reducing weight, volume, and power consumption.

Computational study of a self-cleaning process on superhydrophobic surface

NASA Astrophysics Data System (ADS)

Farokhirad, Samaneh

All substances around us are bounded by interfaces. In general, interface between different phases of materials are categorized as fluid-fluid, solid-fluid, and solid-solid. Fluid-fluid interfaces exhibit a distinct behavior by adapting their shape in response to external stimulus. For example, a liquid droplet on a substrate can undergo different wetting morphologies depending on topography and chemical composition of the surface. Fundamentally, interfacial phenomena arise at the limit between two immiscible phases, namely interface. The interface dynamic governs, to a great extent, physical processes such as impact and spreading of two immiscible media, and stabilization of foams and emulsions from break-up and coalescence. One of the recent challenging problems in the interface-driven fluid dynamics is the self-propulsion mechanism of droplets by means of different types of external forces such as electrical potential, or thermal Marangoni effect. Rapid removal of self-propelled droplet from the surface is an essential factor in terms of expense and efficiency for many applications including self-cleaning and enhanced heat and mass transfer to save energy and natural resources. A recent study on superhydrophobic nature of micro- and nanostructures of cicada wings offers a unique way for the self-propulsion process with no external force, namely coalescence-induced self-propelled jumping of droplet which can act effectively at any orientation. The biological importance of this new mechanism is associated with protecting such surfaces from long term exposure to colloidal particles such as microbial colloids and virus particles. Different interfacial phenomena can occur after out-of-plane jumping of droplet. If the departed droplet is landed back by gravity, it may impact and spread on the surface or coalesce with another droplet and again self-peopled itself to jump away from the surface. The complete removal of the propelled droplet to a sufficient distance beyond the boundary layer of the surface can be accomplished with a surface-parallel shear flow. This thesis presents an investigation of the physics involved in the mechanism of coalescence-induced self-propelled jumping of droplet with and without particle presence, through the use of numerical simulation. (Abstract shortened by ProQuest.).

Modeling pinchoff and reconnection in a Hele-Shaw cell. I. The models and their calibration

NASA Astrophysics Data System (ADS)

Lee, Hyeong-Gi; Lowengrub, J. S.; Goodman, J.

2002-02-01

This is the first paper in a two-part series in which we analyze two model systems to study pinchoff and reconnection in binary fluid flow in a Hele-Shaw cell with arbitrary density and viscosity contrast between the components. The systems stem from a simplification of a general system of equations governing the motion of a binary fluid (NSCH model [Lowengrub and Truskinovsky, Proc. R. Soc. London, Ser. A 454, 2617 (1998)]) to flow in a Hele-Shaw cell. The system takes into account the chemical diffusivity between different components of a fluid mixture and the reactive stresses induced by inhomogeneity. In one of the systems we consider (HSCH), the binary fluid may be compressible due to diffusion. In the other system (BHSCH), a Boussinesq approximation is used and the fluid is incompressible. In this paper, we motivate, present and calibrate the HSCH/BHSCH equations so as to yield the classical sharp interface model as a limiting case. We then analyze their equilibria, one dimensional evolution and linear stability. In the second paper [paper II, Phys. Fluids 14, 514 (2002)], we analyze the behavior of the models in the fully nonlinear regime. In the BHSCH system, the equilibrium concentration profile is obtained using the classical Maxwell construction [Rowlinson and Widom, Molecular Theory of Capillarity (Clarendon, Oxford, 1979)] and does not depend on the orientation of the gravitational field. We find that the equilibria in the HSCH model are somewhat surprising as the gravitational field actually affects the internal structure of an isolated interface by driving additional stratification of light and heavy fluids over that predicted in the Boussinesq case. A comparison of the linear growth rates indicates that the HSCH system is slightly more diffusive than the BHSCH system. In both, linear convergence to the sharp interface growth rates is observed in a parameter controlling the interface thickness. In addition, we identify the effect that each of the parameters, in the HSCH/BHSCH models, has on the linear growth rates. We then show how this analysis may be used to suggest a set of modified parameters which, when used in the HSCH/BHSCH systems, yield improved agreement with the sharp interface model at a finite interface thickness. Evidence of this improved agreement may be found in paper II.

Flow regimes for fluid injection into a confined porous medium

DOE PAGES

Zheng, Zhong; Guo, Bo; Christov, Ivan C.; ...

2015-02-24

We report theoretical and numerical studies of the flow behaviour when a fluid is injected into a confined porous medium saturated with another fluid of different density and viscosity. For a two-dimensional configuration with point source injection, a nonlinear convection–diffusion equation is derived to describe the time evolution of the fluid–fluid interface. In the early time period, the fluid motion is mainly driven by the buoyancy force and the governing equation is reduced to a nonlinear diffusion equation with a well-known self-similar solution. In the late time period, the fluid flow is mainly driven by the injection, and the governingmore » equation is approximated by a nonlinear hyperbolic equation that determines the global spreading rate; a shock solution is obtained when the injected fluid is more viscous than the displaced fluid, whereas a rarefaction wave solution is found when the injected fluid is less viscous. In the late time period, we also obtain analytical solutions including the diffusive term associated with the buoyancy effects (for an injected fluid with a viscosity higher than or equal to that of the displaced fluid), which provide the structure of the moving front. Numerical simulations of the convection–diffusion equation are performed; the various analytical solutions are verified as appropriate asymptotic limits, and the transition processes between the individual limits are demonstrated.« less

A 3D, fully Eulerian, VOF-based solver to study the interaction between two fluids and moving rigid bodies using the fictitious domain method

NASA Astrophysics Data System (ADS)

Pathak, Ashish; Raessi, Mehdi

2016-04-01

We present a three-dimensional (3D) and fully Eulerian approach to capturing the interaction between two fluids and moving rigid structures by using the fictitious domain and volume-of-fluid (VOF) methods. The solid bodies can have arbitrarily complex geometry and can pierce the fluid-fluid interface, forming contact lines. The three-phase interfaces are resolved and reconstructed by using a VOF-based methodology. Then, a consistent scheme is employed for transporting mass and momentum, allowing for simulations of three-phase flows of large density ratios. The Eulerian approach significantly simplifies numerical resolution of the kinematics of rigid bodies of complex geometry and with six degrees of freedom. The fluid-structure interaction (FSI) is computed using the fictitious domain method. The methodology was developed in a message passing interface (MPI) parallel framework accelerated with graphics processing units (GPUs). The computationally intensive solution of the pressure Poisson equation is ported to GPUs, while the remaining calculations are performed on CPUs. The performance and accuracy of the methodology are assessed using an array of test cases, focusing individually on the flow solver and the FSI in surface-piercing configurations. Finally, an application of the proposed methodology in simulations of the ocean wave energy converters is presented.

Rheology of sediment transported by a laminar flow

NASA Astrophysics Data System (ADS)

Houssais, M.; Ortiz, C. P.; Durian, D. J.; Jerolmack, D. J.

2016-12-01

Understanding the dynamics of fluid-driven sediment transport remains challenging, as it occurs at the interface between a granular material and a fluid flow. Boyer, Guazzelli, and Pouliquen [Phys. Rev. Lett. 107, 188301 (2011)], 10.1103/PhysRevLett.107.188301 proposed a local rheology unifying dense dry-granular and viscous-suspension flows, but it has been validated only for neutrally buoyant particles in a confined and homogeneous system. Here we generalize the Boyer, Guazzelli, and Pouliquen model to account for the weight of a particle by addition of a pressure P0 and test the ability of this model to describe sediment transport in an idealized laboratory river. We subject a bed of settling plastic particles to a laminar-shear flow from above, and use refractive-index-matching to track particles' motion and determine local rheology—from the fluid-granular interface to deep in the granular bed. Data from all experiments collapse onto a single curve of friction μ as a function of the viscous number Iv over the range 3 ×10-5 ≤Iv≤2 , validating the local rheology model. For Iv<3 ×10-5 , however, data do not collapse. Instead of undergoing a jamming transition with μ →μs as expected, particles transition to a creeping regime where we observe a continuous decay of the friction coefficient μ ≤μs as Iv decreases. The rheology of this creep regime cannot be described by the local model, and more work is needed to determine whether a nonlocal rheology model can be modified to account for our findings.

Turbulent/non-turbulent interfaces detected in DNS of incompressible turbulent boundary layers

NASA Astrophysics Data System (ADS)

Watanabe, T.; Zhang, X.; Nagata, K.

2018-03-01

The turbulent/non-turbulent interface (TNTI) detected in direct numerical simulations is studied for incompressible, temporally developing turbulent boundary layers at momentum thickness Reynolds number Reθ ≈ 2000. The outer edge of the TNTI layer is detected as an isosurface of the vorticity magnitude with the threshold determined with the dependence of the turbulent volume on a threshold level. The spanwise vorticity magnitude and passive scalar are shown to be good markers of turbulent fluids, where the conditional statistics on a distance from the outer edge of the TNTI layer are almost identical to the ones obtained with the vorticity magnitude. Significant differences are observed for the conditional statistics between the TNTI detected by the kinetic energy and vorticity magnitude. A widely used grid setting determined solely from the wall unit results in an insufficient resolution in a streamwise direction in the outer region, whose influence is found for the geometry of the TNTI and vorticity jump across the TNTI layer. The present results suggest that the grid spacing should be similar for the streamwise and spanwise directions. Comparison of the TNTI layer among different flows requires appropriate normalization of the conditional statistics. Reference quantities of the turbulence near the TNTI layer are obtained with the average of turbulent fluids in the intermittent region. The conditional statistics normalized by the reference turbulence characteristics show good quantitative agreement for the turbulent boundary layer and planar jet when they are plotted against the distance from the outer edge of the TNTI layer divided by the Kolmogorov scale defined for turbulent fluids in the intermittent region.

A dynamic pressure view cell for acoustic stimulation of fluids--Micro-bubble generation and fluid movement in porous media.

PubMed

Stewart, Robert A; Shaw, J M

2015-09-01

The development and baseline operation of an acoustic view cell for observing fluids, and fluid-fluid and fluid-solid interfaces in porous media over the frequency range of 10-5000 Hz is described. This range includes the industrially relevant frequency range 500-5000 Hz that is not covered by existing devices. Pressure waveforms of arbitrary shape are generated in a 17.46 mm ID by 200 mm and 690.5 mm long glass tubes at flow rates up to 200 ml/min using a syringe pump. Peak-to-peak amplitudes exceeding 80 kPa are readily realized at frequencies from 10 to 5000 Hz in bubble free fluids when actuated with 20 Vpp as exemplified using castor oil. At resonant frequencies, peak-to-peak pressure amplitudes exceeding 500 kPa were obtained (castor oil at 2100 Hz when actuated with 20 Vpp). Impacts of vibration on macroscopic liquid-liquid and liquid-vapour interfaces and interface movement are illustrated. Pressure wave transmission and attenuation in a fluid saturated porous medium, randomly packed 250-330 μm spherical silica beads, is also demonstrated. Attenuation differences and frequency shifts in resonant peaks are used to detect the presence and generation of dispersed micro-bubbles (<180 μm diameter), and bubbles within porous media that are not readily visualized. Envisioned applications include assessment of the impacts of vibration on reaction, mass transfer, and flow/flow pattern outcomes. This knowledge will inform laboratory and pilot scale process studies, where nuisance vibrations may affect the interpretation of process outcomes, and large scale or in situ processes in aquifers or hydrocarbon reservoirs where imposed vibration may be deployed to improve aspects of process performance. Future work will include miscible interface observation and quantitative measurements in the bulk and in porous media where the roles of micro-bubbles comprise subjects of special interest.

Experimental growth of inertial forced Richtmyer-Meshkov instabilities for different Atwood numbers

NASA Astrophysics Data System (ADS)

Redondo, J. M.; Castilla, R.

2009-04-01

Richtmyer-Meshkov instability occurs when a shock wave impinges on an interface separating two fluids having different densities [1,2]. The instability causes perturbations on the interface to grow, bubbles and spikes, producing vortical structures which potentially result in a turbulent mixing layer. In addition to shock tube experiments, the incompressible Richtmyer-Meshkov instability has also been studied by impulsively accelerating containers of incompressible fluids. Castilla and Redondo (1994) [3] first exploited this technique by dropping tanks containing a liquid and air or two liquids onto a cushioned surface. This technique was improved upon by Niederhaus and Jacobs (2003)[4] by mounting the tank onto a rail system and then allowing it to bounce off of a fixed spring. A range of both miscible and inmiscible liquids were used, giving a wide range of Atwood numbers using the combinations of air, water, alcohol, oil and mercury. Experimental results show the different pattern selection of both the bubbles and spikes for the different Atwood numbers. Visual analysis of the marked interfaces allows to distinguish the regions of strong mixing and compare self-similarity growth of the mixing region. [1] Meshkov, E. E. 1969 Instability of the interface of two gases accelerated by a shock wave. Fluid Dynamics 4, 101-104. [2] Brouillette, M. & Sturtevant, B. 1994 Experiments on the Richtmyer-Meshkov instability: single-scale perturbations on a continuous interface. Journal of Fluid Mechanics 263, 271-292. [3] Castilla, R. & Redondo, J. M. 1994 Mixing Front Growth in RT and RM Instabilities. Proceedings of the Fourth International Workshop on the Physics of Compressible Turbulent Mixing, Cambridge, United Kingdom, edited by P. F. Linden, D. L. Youngs, and S. B. Dalziel, 11-31. [4] Niederhaus, C. E. & Jacobs, J. W. 2003 Experimental study of the Richtmyer-Meshkov instability of incompressible fluids. Journal of Fluid Mechanics 485, 243-277.

Self-pressurization of a spherical liquid hydrogen storage tank in a microgravity environment

NASA Technical Reports Server (NTRS)

Lin, C. S.; Hasan, M. M.

1992-01-01

Thermal stratification and self-pressurization of partially filled liquid hydrogen (LH2) storage tanks under microgravity condition is studied theoretically. A spherical tank is subjected to a uniform and constant wall heat flux. It is assumed that a vapor bubble is located in the tank center such that the liquid-vapor interface and tank wall form two concentric spheres. This vapor bubble represents an idealized configuration of a wetting fluid in microgravity conditions. Dimensionless mass and energy conservation equations for both vapor and liquid regions are numerically solved. Coordinate transformation is used to capture the interface location which changes due to liquid thermal expansion, vapor compression, and mass transfer at liquid-vapor interface. The effects of tank size, liquid fill level, and wall heat flux on the pressure rise and thermal stratification are studied. Liquid thermal expansion tends to cause vapor condensation and wall heat flux tends to cause liquid evaporation at the interface. The combined effects determine the direction of mass transfer at the interface. Liquid superheat increases with increasing wall heat flux and liquid fill level and approaches an asymptotic value.

A Hele-Shaw-Cahn-Hilliard Model for Incompressible Two-Phase Flows with Different Densities

NASA Astrophysics Data System (ADS)

Dedè, Luca; Garcke, Harald; Lam, Kei Fong

2017-07-01

Topology changes in multi-phase fluid flows are difficult to model within a traditional sharp interface theory. Diffuse interface models turn out to be an attractive alternative to model two-phase flows. Based on a Cahn-Hilliard-Navier-Stokes model introduced by Abels et al. (Math Models Methods Appl Sci 22(3):1150013, 2012), which uses a volume-averaged velocity, we derive a diffuse interface model in a Hele-Shaw geometry, which in the case of non-matched densities, simplifies an earlier model of Lee et al. (Phys Fluids 14(2):514-545, 2002). We recover the classical Hele-Shaw model as a sharp interface limit of the diffuse interface model. Furthermore, we show the existence of weak solutions and present several numerical computations including situations with rising bubbles and fingering instabilities.

Physics, mathematics and numerics of particle adsorption on fluid interfaces

NASA Astrophysics Data System (ADS)

Schmuck, Markus; Pavliotis, Grigorios A.; Kalliadasis, Serafim

2012-11-01

We study two arbitrary immiscible fuids where one phase contains small particles of the size of the interface and smaller. We primarily focus on charge-free particles with wetting characteristics described by the contact angle formed at the interface between the two phases and the particles. Based on the experimental observation that particles are adsorbed on the interface to reduce the interfacial energy and hence the surface tension as well, we formulate a free-energy functional that accounts for these physical effects. Using elements from calculus of variations and formal gradient flow theory, we derive partial differential equations describing the location of the interface and the density of the particles in the fluid phases. Via numerical experiments we analyse the time evolution of the surface tension, the particle concentration, and the free energy over time and reflect basic experimentally observed phenomena.

Communication: A method to compute the transport coefficient of pure fluids diffusing through planar interfaces from equilibrium molecular dynamics simulations.

PubMed

Vermorel, Romain; Oulebsir, Fouad; Galliero, Guillaume

2017-09-14

The computation of diffusion coefficients in molecular systems ranks among the most useful applications of equilibrium molecular dynamics simulations. However, when dealing with the problem of fluid diffusion through vanishingly thin interfaces, classical techniques are not applicable. This is because the volume of space in which molecules diffuse is ill-defined. In such conditions, non-equilibrium techniques allow for the computation of transport coefficients per unit interface width, but their weak point lies in their inability to isolate the contribution of the different physical mechanisms prone to impact the flux of permeating molecules. In this work, we propose a simple and accurate method to compute the diffusional transport coefficient of a pure fluid through a planar interface from equilibrium molecular dynamics simulations, in the form of a diffusion coefficient per unit interface width. In order to demonstrate its validity and accuracy, we apply our method to the case study of a dilute gas diffusing through a smoothly repulsive single-layer porous solid. We believe this complementary technique can benefit to the interpretation of the results obtained on single-layer membranes by means of complex non-equilibrium methods.

Dynamics of solid nanoparticles near a liquid-liquid interface

NASA Astrophysics Data System (ADS)

Daher, Ali; Ammar, Amine; Hijazi, Abbas

2018-05-01

The liquid - liquid interface can be used as a suitable medium for generating some nanostructured films of metals, or inorganic materials such as semi conducting metals. This process can be controlled well if we study the dynamics of nanoparticles (NPs) at the liquid-liquid interface which is a new field of study, and is not understood well yet. The dynamics of NPs at liquid-liquid interfaces is investigated by solving the fluid-particle and particle-particle interactions. Our work is based on the Molecular Dynamics (MD) simulation in addition to Phase Field (PF) method. We modeled the liquid-liquid interface using the diffuse interface model, where the interface is considered to have a characteristic thickness. We have shown that the concentration gradient of one fluid in the other gives rise to a hydrodynamic force that drives the NPs to agglomerate at the interface. These obtained results may introduce new applications where certain interfaces can be considered to be suitable mediums for the synthesis of nanostructured materials. In addition, some liquid interfaces can play the role of effective filters for different species of biological NPs and solid state waste NPs, which will be very important in many industrial and biomedical domains.

Universality Results for Multi-phase Hele-Shaw Flows

NASA Astrophysics Data System (ADS)

Daripa, Prabir

2013-03-01

Saffman-Taylor instability is a well known viscosity driven instability of an interface separating two immiscible fluids. We study linear stability of displacement processes in a Hele-Shaw cell involving an arbitrary number of immiscible fluid phases. This is a problem involving many interfaces. Universal stability results have been obtained for this multi-phase immiscible flow in the sense that the results hold for arbitrary number of interfaces. These stability results have been applied to design displacement processes that are considerably less unstable than the pure Saffman-Taylor case. In particular, we derive universal formula which gives specific values of the viscosities of the fluid layers corresponding to smallest unstable band. Other similar universal results will also be presented. The talk is based on the following paper. This work was supported by the Qatar National Research Fund (a member of The Qatar Foundation).

Into the subduction plate interface: insights from exhumed terranes (Invited)

NASA Astrophysics Data System (ADS)

Agard, P.; Angiboust, S.; Plunder, A.

2013-12-01

In order to place constraints on the still elusive lithological and physical nature of the subduction plate interface, we herein present critical petrological (and modelling) data from intermediate depths along the subduction interface. Their implications, ranging from long-term underplating and exhumation to short-lived seismic events, are confronted with the recent wealth of geophysical/chemical data from the literature. Emphasis is placed on findings from two major localities showing deeply subducted ophiolitic remnants (Zermatt-Saas, Monviso), which crop out in the classic, well-preserved fossil subduction setting of the Western Alps. Both ophiolite remnants in fact represent large, relatively continuous fragments of oceanic lithosphere (i.e., several km-thick tectonic slices across tens of km) exhumed from ~80 km depths and thereby provide important constraints on interplate coupling mechanisms. We show that pervasive hydrothermal processes and seafloor alteration promoting fluid incorporation in both mafic and associated ultramafic rocks was essential, together with the presence of km-thick serpentinite soles, to decrease the density of the tectonic slices and prevent them from an irreversible sinking into the mantle. The Monviso case sudy (particularly the Lago Superiore Unit) provides further insights on both seismicity and fluid flow along the subduction plate interface at ~80 km depths: (1) Eclogite breccias, reported here for the first time, mark the locus of an ancient fault zone associated with intraslab, intermediate-depth earthquakes at ~80 km depth. They correspond to m-sized blocks made of 1-10 cm large fragments of eclogite mylonite later embedded in serpentinite in a ~100m thick eclogite facies shear zone. We suggest that seismic brecciation (possibly at magnitudes Mw ~4) occurred in the middle part of the oceanic crust, accompanied by the input of externally-derived fluids. (2) Prominent fluid-rock interactions, as attested by ubiquitous metasomatic rinds, affected the fragments of mylonitic basaltic eclogites and calcschists dragged and dismembered within serpentinite during eclogite-facies deformation. Detailed petrological and geochemical investigations point to a massive, pulse-like, fluid-mediated element transfer essentially originating from serpentinite. Antigorite breakdown, occurring ca. 15 km deeper than the maximum depth reached by these eclogites, is regarded as the likely source of this highly focused fluid/rock interaction and element transfer. Such a pulse-like, subduction-parallel fluid migration pathway within the downgoing oceanic lithosphere may have been promoted by transient slip behaviour along the LSZ under eclogite-facies conditions. Bi-phase numerical models allowing for fluid migration (driven by concentrations in the rocks, non-lithostatic pressure gradients and deformation), mantle wedge hydration and mechanical weakening of the plate interface indicate that the detachment of such large-scale oceanic tectonic slices is promoted by fluid circulation along the subduction interface (as well as by subducting a strong and originally discontinuous mafic crust).

Reflection and transmission coefficients of a single layer in poroelastic media.

PubMed

Corredor, Robiel Martinez; Santos, Juan E; Gauzellino, Patricia M; Carcione, José M

2014-06-01

Wave propagation in poroelastic media is a subject that finds applications in many fields of research, from geophysics of the solid Earth to material science. In geophysics, seismic methods are based on the reflection and transmission of waves at interfaces or layers. It is a relevant canonical problem, which has not been solved in explicit form, i.e., the wave response of a single layer, involving three dissimilar media, where the properties of the media are described by Biot's theory. The displacement fields are recast in terms of potentials and the boundary conditions at the two interfaces impose continuity of the solid and fluid displacements, normal and shear stresses, and fluid pressure. The existence of critical angles is discussed. The results are verified by taking proper limits-zero and 100% porosity-by comparison to the canonical solutions corresponding to single-phase solid (elastic) media and fluid media, respectively, and the case where the layer thickness is zero, representing an interface separating two poroelastic half-spaces. As examples, it was calculated the reflection and transmission coefficients for plane wave incident at a highly permeable and compliant fluid-saturated porous layer, and the case where the media are saturated with the same fluid.

Wetting of heterogeneous substrates. A classical density-functional-theory approach

NASA Astrophysics Data System (ADS)

Yatsyshin, Peter; Parry, Andrew O.; Rascón, Carlos; Duran-Olivencia, Miguel A.; Kalliadasis, Serafim

2017-11-01

Wetting is a nucleation of a third phase (liquid) on the interface between two different phases (solid and gas). In many experimentally accessible cases of wetting, the interplay between the substrate structure, and the fluid-fluid and fluid-substrate intermolecular interactions leads to the appearance of a whole ``zoo'' of exciting interface phase transitions, associated with the formation of nano-droplets/bubbles, and thin films. Practical applications of wetting at small scales are numerous and include the design of lab-on-a-chip devices and superhydrophobic surfaces. In this talk, we will use a fully microscopic approach to explore the phase space of a planar wall, decorated with patches of different hydrophobicity, and demonstrate the highly non-trivial behaviour of the liquid-gas interface near the substrate. We will present fluid density profiles, adsorption isotherms and wetting phase diagrams. Our analysis is based on a formulation of statistical mechanics, commonly known as classical density-functional theory. It provides a computationally-friendly and rigorous framework, suitable for probing small-scale physics of classical fluids and other soft-matter systems. EPSRC Grants No. EP/L027186,EP/K503733;ERC Advanced Grant No. 247031.

New Numerical Approaches for Modeling Thermochemical Convection in a Compositionally Stratified Fluid

NASA Astrophysics Data System (ADS)

Puckett, E. G.; Turcotte, D. L.; He, Y.; Lokavarapu, H. V.; Robey, J.; Kellogg, L. H.

2017-12-01

Geochemical observations of mantle-derived rocks favor a nearly homogeneous upper mantle, the source of mid-ocean ridge basalts (MORB), and heterogeneous lower mantle regions.Plumes that generate ocean island basalts are thought to sample the lower mantle regions and exhibit more heterogeneity than MORB.These regions have been associated with lower mantle structures known as large low shear velocity provinces below Africa and the South Pacific.The isolation of these regions is attributed to compositional differences and density stratification that, consequently, have been the subject of computational and laboratory modeling designed to determine the parameter regime in which layering is stable and understanding how layering evolves.Mathematical models of persistent compositional interfaces in the Earth's mantle may be inherently unstable, at least in some regions of the parameter space relevant to the mantle.Computing approximations to solutions of such problems presents severe challenges, even to state-of-the-art numerical methods.Some numerical algorithms for modeling the interface between distinct compositions smear the interface at the boundary between compositions, such as methods that add numerical diffusion or `artificial viscosity' in order to stabilize the algorithm. We present two new algorithms for maintaining high-resolution and sharp computational boundaries in computations of these types of problems: a discontinuous Galerkin method with a bound preserving limiter and a Volume-of-Fluid interface tracking algorithm.We compare these new methods with two approaches widely used for modeling the advection of two distinct thermally driven compositional fields in mantle convection computations: a high-order accurate finite element advection algorithm with entropy viscosity and a particle method.We compare the performance of these four algorithms on three problems, including computing an approximation to the solution of an initially compositionally stratified fluid at Ra = 105 with buoyancy numbers {B} that vary from no stratification at B = 0 to stratified flow at large B.

Complex Fluids at Interfaces and Interfaces of Complex Fluids

NASA Astrophysics Data System (ADS)

Nouri, Mariam

The present thesis deals with two independent projects and is consequently divided into two parts. The first part details a computational study of the fluid structure of ring-shaped molecules and their positional and orientational molecular organizations in different degrees of confinement, while the second part concerns an experimental study of phase behavior and interfacial phenomena in confined colloid-polymer systems. In the first part, ring-shaped molecules are studied using Monte Carlo simulation techniques in one, two and three dimensions. The model used to describe ring-shaped molecules is composed of hard-spheres linked together to form planar rigid rings. For rings of various sizes and for a wide range of densities, positional and orientational orderings are reported in forms of pair distribution functions of the ring centers and correlation functions of the ring normal orientations. Special emphasis is given to understand structural formation at interfaces, i.e., the structure and orderings of these molecules when they are confined to two dimensions. In a plane but the rings themselves are free to rotate around all axes, nematic ordering is observed at sufficiently high densities. In the second part, phase equilibria of confined aqueous colloid-polymer systems are studied experimentally using fluorescence microscopy. Aqueous mixtures of fluorescent polystyrene spheres and polyacrylamide are confined between a glass slide and a coverslip. The phase diagram is determined as a function of the colloidal and polymer concentrations. Liquid-liquid phase coexistence between a colloid-rich phase and a polymer-rich phase occurs at intermediate polymer concentrations, while liquid-solid phase coexistence between a polymer-rich liquid and a colloid-rich solid is observed at high polymer concentrations. Interfacial thickness and tension of the interface between these coexisting phases are measured using image analysis techniques. It is also observed that the colloid-rich solid and liquid domains coarsen mainly by Ostwald ripening.

Mineral replacement reactions and element mobilization

NASA Astrophysics Data System (ADS)

Putnis, Christine V.; Ruiz-Agudo, Encarnacion; King, Helen E.; Hövelmann, Jörn; Renard, François

2016-04-01

When a mineral is out of equilibrium with an aqueous fluid, reactions will take place in an attempt to reach a new equilibrium. Commonly in the Earth dissolution at a mineral-fluid interface initiates a coupled reaction involving dissolution and precipitation (Ruiz-Agudo et al., 2014). This is a ubiquitous reaction during such processes as metamorphism, metasomatism and weathering. When rock-forming minerals such as feldspars, olivine, pyroxenes are in contact with aqueous fluids (typically NaCl-rich) resultant new phases are formed and elements present in the parent mineral are released to the fluid and therefore mobilized for transport elsewhere. This has been shown in a number of systems such as the albitisation of feldspars (Hövelmann et al., 2010) when a Ca-bearing plagioclase is replaced by albite (NaAlSi3O8). However during this reaction not only is Ca released to the fluid but most other minor elements, such as Mg, Pb, rare earth elements amongst others, are almost totally mobilized and removed in solution. This interface-coupled dissolution-precipitation reaction has many implications for the redistributon of elements in the crust of the Earth. It is also of note that albitisation occurs often in areas of high mineralization, such as in the Curnamona Province in S. Australia (Au-Cu and Ag-Pb-Zn deposits) and the Bamble District of S. Norway. Secondly atomic force microscopy (AFM) has been used to image these reactions at a nanoscale, especially at the calcite-fluid interface, such as the formation of apatite from phosphate-bearing solutions, and the sequestration of toxic elements, eg., Se and As. References Ruiz-Agudo E., Putnis C.V., Putnis A. (2014) Coupled dissolution and precipitation at mineral-fluid interfaces. Chemical Geology, 383, 132-146. Putnis C.V. and Ruiz-Agudo E. (2013) The mineral-water interface: where minerals react with the environment. Elements, 9, 177-182. Hövelmann J., Putnis A., Geisler T., Schmidt B.C., Golla-Schindler U. (2009) The replacement of plagioclase feldspars by albite: observations from hydrothermal experiments. Contrib. Min. and Pet. 159, 43-59.

Hyperbolic Interfaces

NASA Astrophysics Data System (ADS)

Giomi, Luca

2012-09-01

Fluid interfaces, such as soap films, liquid droplets, or lipid membranes, are known to give rise to several special geometries, whose complexity and beauty continue to fascinate us, as observers of the natural world, and challenge us as scientists. Here I show that a special class of surfaces of constant negative Gaussian curvature can be obtained in fluid interfaces equipped with an orientational ordered phase. These arise in various soft and biological materials, such as nematic liquid crystals, cytoskeletal assemblies, or hexatic colloidal suspensions. The purely hyperbolic morphology originates from the competition between surface tension, that reduces the area of the interface at the expense of increasing its Gaussian curvature, and the orientational elasticity of the ordered phase, that in turn suffers for the distortion induced by the underlying curvature.

Hydrodynamically induced fluid transfer and non-convective double-diffusion in microgravity sliding solvent diffusion cells

NASA Technical Reports Server (NTRS)

Pollmann, Konrad W.; Stodieck, Louis S.; Luttges, Marvin W.

1994-01-01

Microgravity can provide a diffusion-dominated environment for double-diffusion and diffusion-reaction experiments otherwise disrupted by buoyant convection or sedimentation. In sliding solvent diffusion cells, a diffusion interface between two liquid columns is achieved by aligning two offset sliding wells. Fluid in contact with the sliding lid of the cavities is subjected to an applied shear stress. The momentum change by the start/stop action of the well creates an additional hydrodynamical force. In microgravity, these viscous and inertial forces are sufficiently large to deform the diffusion interface and induce hydrodynamic transfer between the wells. A series of KC-135 parabolic flight experiments were conducted to characterize these effects and establish baseline data for microgravity diffusion experiments. Flow visualizations show the diffusion interface to be deformed in a sinusoidal fashion following well alignment. After the wells were separated again in a second sliding movement, the total induced liquid transfer was determined and normalized by the well aspect ratio. The normalized transfer decreased linearly with Reynolds number from 3.3 to 4.0% (w/v) for Re = 0.4 (Stokes flow) to a minimum of 1.0% for Re = 23 to 30. Reynolds numbers that provide minimum induced transfers are characterized by an interface that is highly deformed and unsuitable for diffusion measurements. Flat diffusion interfaces acceptable for diffusion measurements are obtained with Reynolds numbers on the order of 7 to 10. Microgravity experiments aboard a sounding rocket flight verified counterdiffusion of different solutes to be diffusion dominated. Ground control experiments showed enhanced mixing by double-diffusive convection. Careful selection of experimental parameters improves initial conditions and minimizes induced transfer rates.

Sharp Interface Tracking in Rotating Microflows of Solvent Extraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Glimm, James; Almeida, Valmor de; Jiao, Xiangmin

2013-01-08

The objective of this project is to develop a specialized sharp interface tracking simulation capability for predicting interaction of micron-sized drops and bubbles in rotating flows relevant to optimized design of contactor devices used in solvent extraction processes of spent nuclear fuel reprocessing. The primary outcomes of this project include the capability to resolve drops and bubbles micro-hydrodynamics in solvent extraction contactors, determining from first principles continuum fluid mechanics how micro-drops and bubbles interact with each other and the surrounding shearing fluid for realistic flows. In the near term, this effort will play a central role in providing parameters andmore » insight into the flow dynamics of models that average over coarser scales, say at the millimeter unit length. In the longer term, it will prove to be the platform to conduct full-device, detailed simulations as parallel computing power reaches the exaflop level. The team will develop an accurate simulation tool for flows containing interacting droplets and bubbles with sharp interfaces under conditions that mimic those found in realistic contactor operations. The main objective is to create an off-line simulation capability to model drop and bubble interactions in a domain representative of the averaged length scale. The technical approach is to combine robust interface tracking software, subgrid modeling, validation quality experiments, powerful computational hardware, and a team with simulation modeling, physical modeling and technology integration experience. Simulations will then fully resolve the microflow of drops and bubbles at the microsecond time scale. This approach is computationally intensive but very accurate in treating important coupled physical phenomena in the vicinity of interfaces. The method makes it possible to resolve spatial scales smaller than the typical distance between bubbles and to model some non-equilibrium thermodynamic features such as finite critical tension in cavitating liquids« less

Transport Phenomena of Water in Molecular Fluidic Channels

PubMed Central

Vo, Truong Quoc; Kim, BoHung

2016-01-01

In molecular-level fluidic transport, where the discrete characteristics of a molecular system are not negligible (in contrast to a continuum description), the response of the molecular water system might still be similar to the continuum description if the time and ensemble averages satisfy the ergodic hypothesis and the scale of the average is enough to recover the classical thermodynamic properties. However, even in such cases, the continuum description breaks down on the material interfaces. In short, molecular-level liquid flows exhibit substantially different physics from classical fluid transport theories because of (i) the interface/surface force field, (ii) thermal/velocity slip, (iii) the discreteness of fluid molecules at the interface and (iv) local viscosity. Therefore, in this study, we present the result of our investigations using molecular dynamics (MD) simulations with continuum-based energy equations and check the validity and limitations of the continuum hypothesis. Our study shows that when the continuum description is subjected to the proper treatment of the interface effects via modified boundary conditions, the so-called continuum-based modified-analytical solutions, they can adequately predict nanoscale fluid transport phenomena. The findings in this work have broad effects in overcoming current limitations in modeling/predicting the fluid behaviors of molecular fluidic devices. PMID:27650138

Effect of pressure fluctuations on Richtmyer-Meshkov coherent structures

NASA Astrophysics Data System (ADS)

Bhowmick, Aklant K.; Abarzhi, Snezhana

2016-11-01

We investigate the formation and evolution of Richtmyer Meshkov bubbles after the passage of a shock wave across a two fluid interface in the presence of pressure fluctuations. The fluids are ideal and incompressible and the pressure fluctuations are scale invariant in space and time, and are modeled by a power law time dependent acceleration field with exponent -2. Solutions indicate sensitivity to pressure fluctuations. In the linear regime, the growth of curvature and bubble velocity is linear. The growth rate is dominated by the initial velocity for weak pressure fluctuations, and by the acceleration term for strong pressure fluctuations. In the non-linear regime, the bubble curvature is constant and the solutions form a one parameter family (parametrized by the bubble curvature). The solutions are shown to be convergent and asymptotically stable. The physical solution (stable fastest growing) is a flat bubble for small pressure fluctuations and a curved bubble for large pressure fluctuations. The velocity field (in the frame of references accounting for the background motion) involves intense motion of the fluids in a vicinity of the interface, effectively no motion of the fluids away from the interfaces, and formation of vortical structures at the interface. The work is supported by the US National Science Foundation.

Effect of pressure fluctuations on Richtmyer-Meshkov coherent structures

NASA Astrophysics Data System (ADS)

Bhowmick, Aklant K.; Abarzhi, Snezhana

2016-10-01

We investigate the formation and evolution of Richtmyer Meshkov bubbles after the passage of a shock wave across a two fluid interface in the presence of pressure fluctuations. The fluids are ideal and incompressible and the pressure fluctuations are scale invariant in space and time, and are modeled by a power law time dependent acceleration field with exponent -2. Solutions indicate sensitivity to pressure fluctuations. In the linear regime, the growth of curvature and bubble velocity is linear. The growth rate is dominated by the initial velocity for weak pressure fluctuations, and by the acceleration term for strong pressure fluctuations. In the non-linear regime, the bubble curvature is constant and the solutions form a one parameter family (parametrized by the bubble curvature). The solutions are shown to be convergent and asymptotically stable. The physical solution (stable fastest growing) is a flat bubble for small pressure fluctuations and a curved bubble for large pressure fluctuations. The velocity field (in the frame of references accounting for the background motion) involves intense motion of the fluids in a vicinity of the interface, effectively no motion of the fluids away from the interfaces, and formation of vortical structures at the interface. The work is supported by the US National Science Foundation.

Density and Phase State of a Confined Nonpolar Fluid

NASA Astrophysics Data System (ADS)

Kienle, Daniel F.; Kuhl, Tonya L.

2016-07-01

Measurements of the mean refractive index of a spherelike nonpolar fluid, octamethytetracylclosiloxane (OMCTS), confined between mica sheets, demonstrate direct and conclusive experimental evidence of the absence of a first-order liquid-to-solid phase transition in the fluid when confined, which has been suggested to occur from previous experimental and simulation results. The results also show that the density remains constant throughout confinement, and that the fluid is incompressible. This, along with the observation of very large increases (many orders of magnitude) in viscosity during confinement from the literature, demonstrate that the molecular motion is limited by the confining wall and not the molecular packing. In addition, the recently developed refractive index profile correction method, which enables the structural perturbation inherent at a solid-liquid interface and that of a liquid in confinement to be determined independently, was used to show that there was no measurable excess or depleted mass of OMCTS near the mica surface in bulk films or confined films of only two molecular layers.

Interfacial profiles in fluid/liquid systems: a description based on the storing of elastic energy.

PubMed

Castellanos-Suárez, Aly J; Toro-Mendoza, Jhoan; García-Sucre, Máximo

2011-06-01

An analytical expression for the interfacial energy is found by solving a Poisson equation and assuming a Boltzmann distribution of volume elements forming the fluid/liquid system. Interfacial phenomena are treated as a result of the response of a liquid when it makes contact with other fluid phase, in order to reach thermal and mechanical equilibrium. This model gives a quantitative description of the interface, obtaining values for its molar, force and energy density profiles. Also, our model allows the determination of the proportion of the fluids present in the interfacial zone, the values of interfacial tension and thickness. In the case of water+n-alkanes systems, the tensions are in agreement with the behavior shown by the experimental data. Finally, the values for interfacial thickness predicted from molar density profiles are lower than the range of influence of the elastic energy and elastic field. Copyright © 2011 Elsevier Inc. All rights reserved.

Time scales of relaxation dynamics during transient conditions in two-phase flow: RELAXATION DYNAMICS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schlüter, Steffen; Berg, Steffen; Li, Tianyi

2017-06-01

The relaxation dynamics toward a hydrostatic equilibrium after a change in phase saturation in porous media is governed by fluid reconfiguration at the pore scale. Little is known whether a hydrostatic equilibrium in which all interfaces come to rest is ever reached and which microscopic processes govern the time scales of relaxation. Here we apply fast synchrotron-based X-ray tomography (X-ray CT) to measure the slow relaxation dynamics of fluid interfaces in a glass bead pack after fast drainage of the sample. The relaxation of interfaces triggers internal redistribution of fluids, reduces the surface energy stored in the fluid interfaces, andmore » relaxes the contact angle toward the equilibrium value while the fluid topology remains unchanged. The equilibration of capillary pressures occurs in two stages: (i) a quick relaxation within seconds in which most of the pressure drop that built up during drainage is dissipated, a process that is to fast to be captured with fast X-ray CT, and (ii) a slow relaxation with characteristic time scales of 1–4 h which manifests itself as a spontaneous imbibition process that is well described by the Washburn equation for capillary rise in porous media. The slow relaxation implies that a hydrostatic equilibrium is hardly ever attained in practice when conducting two-phase experiments in which a flux boundary condition is changed from flow to no-flow. Implications for experiments with pressure boundary conditions are discussed.« less

Fingering patterns in magnetic fluids: Perturbative solutions and the stability of exact stationary shapes

NASA Astrophysics Data System (ADS)

Anjos, Pedro H. A.; Lira, Sérgio A.; Miranda, José A.

2018-04-01

We examine the formation of interfacial patterns when a magnetic liquid droplet (ferrofluid, or a magnetorheological fluid), surrounded by a nonmagnetic fluid, is subjected to a radial magnetic field in a Hele-Shaw cell. By using a vortex-sheet formalism, we find exact stationary solutions for the fluid-fluid interface in the form of n -fold polygonal shapes. A weakly nonlinear, mode-coupling method is then utilized to find time-evolving perturbative solutions for the interfacial patterns. The stability of such nonzero surface tension exact solutions is checked and discussed, by trying to systematically approach the exact stationary shapes through perturbative solutions containing an increasingly larger number of participating Fourier modes. Our results indicate that the exact stationary solutions of the problem are stable, and that a good matching between exact and perturbative shape solutions is achieved just by using a few Fourier modes. The stability of such solutions is substantiated by a linearization process close to the stationary shape, where a system of mode-coupling equations is diagonalized, determining the eigenvalues which dictate the stability of a fixed point.

A new syringe pump apparatus for the retrieval and temporal analysis of helium in groundwaters and geothermal fluids

USGS Publications Warehouse

Barry, P.H.; Hilton, David R.; Tryon, M.D.; Brown, K.M.; Kulongoski, J.T.

2009-01-01

[1] We present details of a newly designed syringe pump apparatus for the retrieval and temporal analysis of helium (SPARTAH). The device is composed of a commercially available syringe pump connected to coils of Cu tubing, which interface the syringe and the groundwater or geothermal wellhead. Through test deployments at geothermal wells in Iceland and California, we show that well fluids are drawn smoothly, accurately, and continuously into the Cu tubing and can be time-stamped through user-determined operating parameters. In the laboratory, the tubing is sectioned to reveal helium (He) characteristics of the fluids at times and for durations of interest. The device is capable of prolonged deployments, up to 6 months or more, with minimal maintenance. It can be used to produce detailed time series records of He, or any other geochemical parameter, in groundwaters and geothermal fluids. SPARTAH has application in monitoring projects assessing the relationship between external transient events (e.g., earthquakes) and geochemical signals in aqueous fluids. ?? 2009 by the American Geophysical Union.

Designing optical-fiber modulators by using magnetic fluids.

PubMed

Horng, H E; Chieh, J J; Chao, Y H; Yang, S Y; Hong, Chin-Yih; Yang, H C

2005-03-01

To reduce interface loss between optical fibers and devices in telecommunication systems, the development of an optical-fiber-based device that can be fused directly with fibers is important. A novel optical modulator consisting of a bare fiber core surrounded by magnetic fluids instead of by a SiO2 cladding layer is proposed. Applying a magnetic field raises the refractive index of the magnetic fluid. Thus we can control the occurrence of total reflection at the interface between the fiber core and the magnetic fluid when light propagates along the fiber. As a result, the intensity of the outgoing light is modulated by variation in field strength. Details of the design, fabrication, and working properties of such a modulator are presented.

Seismoelectric couplings in a poroelastic material containing two immiscible fluid phases

NASA Astrophysics Data System (ADS)

Jardani, A.; Revil, A.

2015-08-01

A new approach of seismoelectric imaging has been recently proposed to detect saturation fronts in which seismic waves are focused in the subsurface to scan its heterogeneous nature and determine saturation fronts. Such type of imaging requires however a complete modelling of the seismoelectric properties of porous media saturated by two immiscible fluid phases, one being usually electrically insulating (for instance water and oil). We combine an extension of Biot dynamic theory, valid for porous media containing two immiscible Newtonian fluids, with an extension of the electrokinetic theory based on the notion of effective volumetric charge densities dragged by the flow of each fluid phase. These effective charge densities can be related directly to the permeability and saturation of each fluid phase. The coupled partial differential equations are solved with the finite element method. We also derive analytically the transfer function connecting the macroscopic electrical field to the acceleration of the fast P wave (coseismic electrical field) and we study the influence of the water content on this coupling. We observe that the amplitude of the co-seismic electrical disturbance is very sensitive to the water content with an increase in amplitude with water saturation. We also investigate the seismoelectric conversions (interface effect) occurring at the water table. We show that the conversion response at the water table can be identifiable only when the saturation contrasts between the vadose and saturated zones are sharp enough. A relatively dry vadose zone represents the best condition to identify the water table through seismoelectric measurements. Indeed, in this case, the coseismic electrical disturbances are vanishingly small compared to the seismoelectric interface response.

Diffuse interface models of locally inextensible vesicles in a viscous fluid

PubMed Central

Aland, Sebastian; Egerer, Sabine; Lowengrub, John; Voigt, Axel

2014-01-01

We present a new diffuse interface model for the dynamics of inextensible vesicles in a viscous fluid with inertial forces. A new feature of this work is the implementation of the local inextensibility condition in the diffuse interface context. Local inextensibility is enforced by using a local Lagrange multiplier, which provides the necessary tension force at the interface. We introduce a new equation for the local Lagrange multiplier whose solution essentially provides a harmonic extension of the multiplier off the interface while maintaining the local inextensibility constraint near the interface. We also develop a local relaxation scheme that dynamically corrects local stretching/compression errors thereby preventing their accumulation. Asymptotic analysis is presented that shows that our new system converges to a relaxed version of the inextensible sharp interface model. This is also verified numerically. To solve the equations, we use an adaptive finite element method with implicit coupling between the Navier-Stokes and the diffuse interface inextensibility equations. Numerical simulations of a single vesicle in a shear flow at different Reynolds numbers demonstrate that errors in enforcing local inextensibility may accumulate and lead to large differences in the dynamics in the tumbling regime and smaller differences in the inclination angle of vesicles in the tank-treading regime. The local relaxation algorithm is shown to prevent the accumulation of stretching and compression errors very effectively. Simulations of two vesicles in an extensional flow show that local inextensibility plays an important role when vesicles are in close proximity by inhibiting fluid drainage in the near contact region. PMID:25246712

Deformation and Metasomatic Evolution at the Subduction Plate Interface As Viewed from Study of HP/UHP Metamorphic Rocks

NASA Astrophysics Data System (ADS)

Bebout, G. E.; Penniston-Dorland, S.

2014-12-01

We provide a view of lithologic makeup, deformation, and fluid-rock interaction along the deep forearc to subarc plate interface, based on insights gained from study of HP/UHP metamorphic rocks. Exposures of plate-boundary shear zones on which we base our perspective represent 30-80 km depths and are on Catalina Island and at Monviso, Syros, and New Caledonia. Each contains highly deformed zones with schistose matrix, commonly with a large ultramafic component, containing bodies of less deformed mafic, sedimentary, and ultramafic rocks. These "blocks" have varying geometries, are up to km-scale, and can preserve disparate P-T histories reflecting dynamics of incorporation and entrainment. Sheared matrices contain high-variance, hydrous mineral assemblages in some cases resembling metasomatic zones ("rinds") at block-matrix contacts, and rinds and matrices have homogenized isotopic compositions reflecting extensive fluid-rock interaction. Shearing and related physical juxtaposition of disparate metasomatic rocks can result in mixed or 'hybrid' chemical compositions. The chlorite-, talc-, and amphibole-rich schists developed by these processes can stabilize H2O to great depth and influence its cycling. Fluids (hydrous fluids, silicate melts) released within slabs necessarily interact with highly deformed, lithologically hybridized zones at the plate interface as they ascend to potentially enter mantle wedges. Fluids bearing chemical/isotopic signatures of hybrid rocks appear capable of producing arc magma compositions interpreted as reflecting multiple, chemically distinct fluids sources. Geophysical signatures of these rheologically weak zones are equivocal but many recognize the presence of zones of low seismic velocity at/near the top of slabs and attribute them to hydrated rocks. Whether rocks from this interface buoyantly ascend into mantle wedges, indicated in some theoretical models, remains largely untested by field and geophysical observations.

Critical conditions for the buoyancy-driven detachment of a wall-bound pendant drop

NASA Astrophysics Data System (ADS)

Lamorgese, A.; Mauri, R.

2016-03-01

We investigate numerically the critical conditions for detachment of an isolated, wall-bound emulsion droplet acted upon by surface tension and wall-normal buoyancy forces alone. To that end, we present a simple extension of a diffuse-interface model for partially miscible binary mixtures that was previously employed for simulating several two-phase flow phenomena far and near the critical point [A. G. Lamorgese et al. "Phase-field approach to multiphase flow modeling," Milan J. Math. 79(2), 597-642 (2011)] to allow for static contact angles other than 90°. We use the same formulation of the Cahn boundary condition as first proposed by Jacqmin ["Contact-line dynamics of a diffuse fluid interface," J. Fluid Mech. 402, 57-88 (2000)], which accommodates a cubic (Hermite) interpolation of surface tensions between the wall and each phase at equilibrium. We show that this model can be successfully employed for simulating three-phase contact line problems in stable emulsions with nearly immiscible components. We also show a numerical determination of critical Bond numbers as a function of static contact angle by phase-field simulation.

Hierarchy of on-orbit servicing interfaces

NASA Technical Reports Server (NTRS)

Moe, Rud V.

1989-01-01

A series of equipment interfaces is involved in on-orbit servicing operations. The end-to-end hierarchy of servicing interfaces is presented. The interface concepts presented include structure and handling, and formats for transfer of resources (power, data, fluids, etc.). Consequences on cost, performance, and service ability of the use of standard designs or unique designs with interface adapters are discussed. Implications of the interface designs compatibility with remote servicing using telerobotic servicers are discussed.

Nonequilibrium Interfacial Tension in Simple and Complex Fluids

NASA Astrophysics Data System (ADS)

Truzzolillo, Domenico; Mora, Serge; Dupas, Christelle; Cipelletti, Luca

2016-10-01

Interfacial tension between immiscible phases is a well-known phenomenon, which manifests itself in everyday life, from the shape of droplets and foam bubbles to the capillary rise of sap in plants or the locomotion of insects on a water surface. More than a century ago, Korteweg generalized this notion by arguing that stresses at the interface between two miscible fluids act transiently as an effective, nonequilibrium interfacial tension, before homogenization is eventually reached. In spite of its relevance in fields as diverse as geosciences, polymer physics, multiphase flows, and fluid removal, experiments and theoretical works on the interfacial tension of miscible systems are still scarce, and mostly restricted to molecular fluids. This leaves crucial questions unanswered, concerning the very existence of the effective interfacial tension, its stabilizing or destabilizing character, and its dependence on the fluid's composition and concentration gradients. We present an extensive set of measurements on miscible complex fluids that demonstrate the existence and the stabilizing character of the effective interfacial tension, unveil new regimes beyond Korteweg's predictions, and quantify its dependence on the nature of the fluids and the composition gradient at the interface. We introduce a simple yet general model that rationalizes nonequilibrium interfacial stresses to arbitrary mixtures, beyond Korteweg's small gradient regime, and show that the model captures remarkably well both our new measurements and literature data on molecular and polymer fluids. Finally, we briefly discuss the relevance of our model to a variety of interface-driven problems, from phase separation to fracture, which are not adequately captured by current approaches based on the assumption of small gradients.

Boundary layers at a dynamic interface: Air-sea exchange of heat and mass

NASA Astrophysics Data System (ADS)

Szeri, Andrew J.

2017-04-01

Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and anthropogenic gases involved in the study of climate. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble nonreactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity w' and gas concentration c' are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither w' nor c' can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from measurements that can be taken by an infrared (IR) camera. An equation is derived with inputs being the surface temperature and heat flux, and a solution method developed for the surface-normal strain experienced over time by boundary layers at the interface. Because the thermal and concentration boundary layers experience the same near-surface fluid motions, the solution for the surface-normal strain determines the gas flux or gas transfer velocity. Examples illustrate the approach in the cases of complete surface renewal, partial surface renewal, and insolation. The prospects for use of the approach in flows characterized by sheared interfaces or rapid boundary layer straining are explored.

Process modelling for Space Station experiments

NASA Technical Reports Server (NTRS)

Alexander, J. Iwan D.; Rosenberger, Franz; Nadarajah, Arunan; Ouazzani, Jalil; Amiroudine, Sakir

1990-01-01

Examined here is the sensitivity of a variety of space experiments to residual accelerations. In all the cases discussed the sensitivity is related to the dynamic response of a fluid. In some cases the sensitivity can be defined by the magnitude of the response of the velocity field. This response may involve motion of the fluid associated with internal density gradients, or the motion of a free liquid surface. For fluids with internal density gradients, the type of acceleration to which the experiment is sensitive will depend on whether buoyancy driven convection must be small in comparison to other types of fluid motion, or fluid motion must be suppressed or eliminated. In the latter case, the experiments are sensitive to steady and low frequency accelerations. For experiments such as the directional solidification of melts with two or more components, determination of the velocity response alone is insufficient to assess the sensitivity. The effect of the velocity on the composition and temperature field must be considered, particularly in the vicinity of the melt-crystal interface. As far as the response to transient disturbances is concerned, the sensitivity is determined by both the magnitude and frequency of the acceleration and the characteristic momentum and solute diffusion times. The microgravity environment, a numerical analysis of low gravity tolerance of the Bridgman-Stockbarger technique, and modeling crystal growth by physical vapor transport in closed ampoules are discussed.

Probes and monitors for the study of solidification of molten semiconductors

NASA Technical Reports Server (NTRS)

Sadoway, D. R.

1986-01-01

The purpose is to examine solidification in the LiCl-KCl system to determine if phenomena such as solute rejection can be obseved by laser schlieren imaging. Molten salts have attributes that make them attractive as physical models in solidification studies. With optical techniques of investigation such as schlieren imaging, it is possible to study fluid flow phenomena in molten salts and to watch the trajectory of the solid-liquid interface.

Thermodynamics and simulation of hard-sphere fluid and solid: Kinetic Monte Carlo method versus standard Metropolis scheme

NASA Astrophysics Data System (ADS)

Ustinov, E. A.

2017-01-01

The paper aims at a comparison of techniques based on the kinetic Monte Carlo (kMC) and the conventional Metropolis Monte Carlo (MC) methods as applied to the hard-sphere (HS) fluid and solid. In the case of the kMC, an alternative representation of the chemical potential is explored [E. A. Ustinov and D. D. Do, J. Colloid Interface Sci. 366, 216 (2012)], which does not require any external procedure like the Widom test particle insertion method. A direct evaluation of the chemical potential of the fluid and solid without thermodynamic integration is achieved by molecular simulation in an elongated box with an external potential imposed on the system in order to reduce the particle density in the vicinity of the box ends. The existence of rarefied zones allows one to determine the chemical potential of the crystalline phase and substantially increases its accuracy for the disordered dense phase in the central zone of the simulation box. This method is applicable to both the Metropolis MC and the kMC, but in the latter case, the chemical potential is determined with higher accuracy at the same conditions and the number of MC steps. Thermodynamic functions of the disordered fluid and crystalline face-centered cubic (FCC) phase for the hard-sphere system have been evaluated with the kinetic MC and the standard MC coupled with the Widom procedure over a wide range of density. The melting transition parameters have been determined by the point of intersection of the pressure-chemical potential curves for the disordered HS fluid and FCC crystal using the Gibbs-Duhem equation as a constraint. A detailed thermodynamic analysis of the hard-sphere fluid has provided a rigorous verification of the approach, which can be extended to more complex systems.

Nanoparticle monolayers under stress: mechanically forced desorption from a fluid-fluid interface

NASA Astrophysics Data System (ADS)

Garbin, Valeria; Crocker, John C.; Stebe, Kathleen J.

2011-11-01

Nanoparticle-laden interfaces are studied for applications to materials with tunable electronic and optical properties, as emulsion stabilizers, and in catalysis. The mechanical response of nanoparticle monolayers under applied stress is of emerging interest since it impacts the success of these applications. Here we focus on the response of nanoparticle-laden interfaces to compression. A monolayer of nanoparticles is allowed to spontaneously form by adsorption from an aqueous suspension onto a pendant drop of oil. The effective surface pressure Π of the composite interface is monitored by pendant drop tensiometry. As the drop is compressed, the nanoparticles are mechanically forced out of the interface into the aqueous phase. A new optical method is developed to measure the nanoparticle area density in situ. We show that desorption occurs at a coverage that corresponds to close packing of the ligand-capped particles, suggesting that ligand-induced repulsion plays a crucial role in the desorption process.

Porosity developed during mineral replacement reactions: implications for fluid flux in the Earth

NASA Astrophysics Data System (ADS)

Putnis, Christine V.; Trindade Pedrosa, Elisabete; Hövelmann, Jörn; Renard, François; Ruiz-Agudo, Encarnacion

2017-04-01

Aqueous fluids, that are ubiquitous in the crust of the Earth, will move through possible pathways in rocks. Rocks characteristically have low permeability but fractures can provide fast fluid channels. Mineral grain boundaries also present easy fluid pathways. However, porosity within minerals forms when a mineral is out of equilibrium with an aqueous fluid and reactions take place in an attempt to reach a new equilibrium. Commonly, dissolution at a mineral-fluid interface initiates one or several coupled reactions involving dissolution and precipitation (Putnis C.V. and Ruiz-Agudo E., 2013; Ruiz-Agudo et al., 2014). In pseudomorphic volume-deficit reactions, a new phase forms while porosity is created, and thereby reactive fluid flow through the originally solid mineral is enhanced. These coupled dissolution-replacement reactions therefore will constrain the flux of material carried by the fluid. These reactions are common during such processes as metamorphism, metasomatism, and weathering. When rock-forming minerals such as feldspars, olivine, pyroxenes and carbonates are in contact with aqueous fluids (typically NaCl-rich) porosity is formed during the interfacial replacement reactions. Elements present in the parent mineral are released to the fluid and therefore mobilized for transport elsewhere. Porosity formation has been shown in a number of systems, such as during the albitisation of feldspars (Hövelmann et al., 2009) and the replacement of carbonates by apatite phases (Pedrosa et al., 2016). Some of these examples will be presented as well as examples from atomic force microscopy (AFM) experiments used to image these reactions at a nanoscale, especially at the calcite-fluid interface, when new phases can be directly observed forming. This mechanism has also been shown as a means of carbon and phosphorus sequestration and for the removal of toxic elements from superficial waters, such as Se and As. References Ruiz-Agudo E., Putnis C.V., Putnis A. (2014) Coupled dissolution and precipitation at mineral-fluid interfaces. Chem. Geol., 383, 132-146. Putnis C.V. and Ruiz-Agudo E. (2013) The mineral-water interface: where minerals react with the environment. Elements, 9, 177-182. Hövelmann J., Putnis A., Geisler T., Schmidt B.C., Golla-Schindler U. (2009) The replacement of plagioclase feldspars by albite: observations from hydrothermal experiments. Contrib. Min. and Pet. 159, 43-59. Pedrosa E.T., Putnis C.V., Putnis A. (2016) The pseudomorphic replacement of marble by apatite: the role of fluid composition. Chem. Geol., 425, 1-11.

Adsorbed Layers of Ferritin at Solid and Fluid Interfaces Studied by Atomic Force Microscopy.

PubMed

Johnson; Yuan; Lenhoff

2000-03-15

The adsorption of the iron storage protein ferritin was studied by liquid tapping mode atomic force microscopy in order to obtain molecular resolution in the adsorbed layer within the aqueous environment in which the adsorption was carried out. The surface coverage and the structure of the adsorbed layer were investigated as functions of ionic strength and pH on two different charged surfaces, namely chemically modified glass slides and mixed surfactant films at the air-water interface, which were transferred to graphite substrates after adsorption. Surface coverage trends with both ionic strength and pH indicate the dominance of electrostatic effects, with the balance shifting between intermolecular repulsion and protein-surface attraction. The resulting behavior is more complex than that seen for larger colloidal particles, which appear to follow a modified random sequential adsorption model monotonically. The structure of the adsorbed layers at the solid surfaces is random, but some indication of long-range order is apparent at fluid interfaces, presumably due to the higher protein mobility at the fluid interface. Copyright 2000 Academic Press.

Implicit mesh discontinuous Galerkin methods and interfacial gauge methods for high-order accurate interface dynamics, with applications to surface tension dynamics, rigid body fluid-structure interaction, and free surface flow: Part I

NASA Astrophysics Data System (ADS)

Saye, Robert

2017-09-01

In this two-part paper, a high-order accurate implicit mesh discontinuous Galerkin (dG) framework is developed for fluid interface dynamics, facilitating precise computation of interfacial fluid flow in evolving geometries. The framework uses implicitly defined meshes-wherein a reference quadtree or octree grid is combined with an implicit representation of evolving interfaces and moving domain boundaries-and allows physically prescribed interfacial jump conditions to be imposed or captured with high-order accuracy. Part one discusses the design of the framework, including: (i) high-order quadrature for implicitly defined elements and faces; (ii) high-order accurate discretisation of scalar and vector-valued elliptic partial differential equations with interfacial jumps in ellipticity coefficient, leading to optimal-order accuracy in the maximum norm and discrete linear systems that are symmetric positive (semi)definite; (iii) the design of incompressible fluid flow projection operators, which except for the influence of small penalty parameters, are discretely idempotent; and (iv) the design of geometric multigrid methods for elliptic interface problems on implicitly defined meshes and their use as preconditioners for the conjugate gradient method. Also discussed is a variety of aspects relating to moving interfaces, including: (v) dG discretisations of the level set method on implicitly defined meshes; (vi) transferring state between evolving implicit meshes; (vii) preserving mesh topology to accurately compute temporal derivatives; (viii) high-order accurate reinitialisation of level set functions; and (ix) the integration of adaptive mesh refinement. In part two, several applications of the implicit mesh dG framework in two and three dimensions are presented, including examples of single phase flow in nontrivial geometry, surface tension-driven two phase flow with phase-dependent fluid density and viscosity, rigid body fluid-structure interaction, and free surface flow. A class of techniques known as interfacial gauge methods is adopted to solve the corresponding incompressible Navier-Stokes equations, which, compared to archetypical projection methods, have a weaker coupling between fluid velocity, pressure, and interface position, and allow high-order accurate numerical methods to be developed more easily. Convergence analyses conducted throughout the work demonstrate high-order accuracy in the maximum norm for all of the applications considered; for example, fourth-order spatial accuracy in fluid velocity, pressure, and interface location is demonstrated for surface tension-driven two phase flow in 2D and 3D. Specific application examples include: vortex shedding in nontrivial geometry, capillary wave dynamics revealing fine-scale flow features, falling rigid bodies tumbling in unsteady flow, and free surface flow over a submersed obstacle, as well as high Reynolds number soap bubble oscillation dynamics and vortex shedding induced by a type of Plateau-Rayleigh instability in water ripple free surface flow. These last two examples compare numerical results with experimental data and serve as an additional means of validation; they also reveal physical phenomena not visible in the experiments, highlight how small-scale interfacial features develop and affect macroscopic dynamics, and demonstrate the wide range of spatial scales often at play in interfacial fluid flow.

Implicit mesh discontinuous Galerkin methods and interfacial gauge methods for high-order accurate interface dynamics, with applications to surface tension dynamics, rigid body fluid-structure interaction, and free surface flow: Part II

NASA Astrophysics Data System (ADS)

Saye, Robert

2017-09-01

In this two-part paper, a high-order accurate implicit mesh discontinuous Galerkin (dG) framework is developed for fluid interface dynamics, facilitating precise computation of interfacial fluid flow in evolving geometries. The framework uses implicitly defined meshes-wherein a reference quadtree or octree grid is combined with an implicit representation of evolving interfaces and moving domain boundaries-and allows physically prescribed interfacial jump conditions to be imposed or captured with high-order accuracy. Part one discusses the design of the framework, including: (i) high-order quadrature for implicitly defined elements and faces; (ii) high-order accurate discretisation of scalar and vector-valued elliptic partial differential equations with interfacial jumps in ellipticity coefficient, leading to optimal-order accuracy in the maximum norm and discrete linear systems that are symmetric positive (semi)definite; (iii) the design of incompressible fluid flow projection operators, which except for the influence of small penalty parameters, are discretely idempotent; and (iv) the design of geometric multigrid methods for elliptic interface problems on implicitly defined meshes and their use as preconditioners for the conjugate gradient method. Also discussed is a variety of aspects relating to moving interfaces, including: (v) dG discretisations of the level set method on implicitly defined meshes; (vi) transferring state between evolving implicit meshes; (vii) preserving mesh topology to accurately compute temporal derivatives; (viii) high-order accurate reinitialisation of level set functions; and (ix) the integration of adaptive mesh refinement. In part two, several applications of the implicit mesh dG framework in two and three dimensions are presented, including examples of single phase flow in nontrivial geometry, surface tension-driven two phase flow with phase-dependent fluid density and viscosity, rigid body fluid-structure interaction, and free surface flow. A class of techniques known as interfacial gauge methods is adopted to solve the corresponding incompressible Navier-Stokes equations, which, compared to archetypical projection methods, have a weaker coupling between fluid velocity, pressure, and interface position, and allow high-order accurate numerical methods to be developed more easily. Convergence analyses conducted throughout the work demonstrate high-order accuracy in the maximum norm for all of the applications considered; for example, fourth-order spatial accuracy in fluid velocity, pressure, and interface location is demonstrated for surface tension-driven two phase flow in 2D and 3D. Specific application examples include: vortex shedding in nontrivial geometry, capillary wave dynamics revealing fine-scale flow features, falling rigid bodies tumbling in unsteady flow, and free surface flow over a submersed obstacle, as well as high Reynolds number soap bubble oscillation dynamics and vortex shedding induced by a type of Plateau-Rayleigh instability in water ripple free surface flow. These last two examples compare numerical results with experimental data and serve as an additional means of validation; they also reveal physical phenomena not visible in the experiments, highlight how small-scale interfacial features develop and affect macroscopic dynamics, and demonstrate the wide range of spatial scales often at play in interfacial fluid flow.

Is localised dehydration and vein generation the tremor-generating mechanism in subduction zones?

NASA Astrophysics Data System (ADS)

Fagereng, Ake; Meneghini, Francesca; Diener, Johann; Harris, Chris

2017-04-01

The phenomena of tectonic, non-volcanic, tremor was first discovered at the down-dip end of the seismogenic zone in Japan early this millennium. Now this low amplitude, low frequency, noise-like seismic signal has been observed at and/or below the deep limit of interseismic coupling along most well-instrumented subduction thrust interfaces. Data and models from these examples suggest a link between tremor and areas of elevated fluid pressure, or at least fluid presence. Tremor locations appear to also correlate with margin-specific locations of metamorphic fluid release, determined by composition and thermal structure. We therefore hypothesise that: (i) tremor on the deep subduction thrust interface is related to localised fluid release; and (ii) accretionary complex rocks exhumed from appropriate pressure - temperature conditions should include a record of this process, and allow a test for the hypothesis. Hydrothermal veins are a record of mineral precipitation at non-equilibrium conditions, commonly caused by fracture, fluid influx, and precipitation of dissolved minerals from this fluid. Quartz veins are ubiquitous in several accretionary complexes, including the Chrystalls Beach Complex, New Zealand, and the Kuiseb Schist of the Namibian Damara Belt. In both locations, representing temperatures of deformation of < 300 and < 600 °C respectively, there are networks of foliation-parallel and oblique veins, which developed incrementally and record a combination of shear and dilation. Required to have formed at differential stresses less than four times the tensile strength, and at fluid pressures exceeding the least compressive stress, these veins are consistent with tremorgenic conditions of low effective stress and mixed-mode deformation kinematically in agreement with shear on the plate interface. We have analysed the oxygen isotope composition of syntectonic quartz veins in both Chrystalls Beach Complex and Kuiseb Schist accretionary complexes, to unravel the geochemical characteristics of the fluid source potentially required to produce tremor. In the Chrystalls Beach Complex, quartz δ18O values range from 14.1 ‰ to 17.0 ‰ (n = 18), whereas in the Kuiseb schist, values range from 9.4 ‰ to 17.9 ‰ (n = 30). In the latter, values less than 14.0‰ are associated with long-lived shear zones. Excluding the lower values in the Kuiseb schist, the δ18O values are consistent with metamorphic fluids in near equilibrium with the host rocks. We thus infer that the veins that developed on the prograde path formed at a small range of temperatures from a local fluid source. This interpretation is consistent with the veins forming in response to a spatially localised metamorphic fluid release. If vein swarms are formed by the mechanism geophysically recorded as tremor, this implies that tremor is, at least in some locations, triggered by metamorphic fluid release and associated hydrofracture and low effective stress shear activation of low permeability shear zone rocks. If this is correct, then a corollary may be that the near-periodic nature of tremor events is related to a regular nature in the build-up and release of fluid pressure.

Generalized elastica patterns in a curved rotating Hele-Shaw cell

NASA Astrophysics Data System (ADS)

Brandão, Rodolfo; Miranda, José A.

2017-08-01

We study a family of generalized elasticalike equilibrium shapes that arise at the interface separating two fluids in a curved rotating Hele-Shaw cell. This family of stationary interface solutions consists of shapes that balance the competing capillary and centrifugal forces in such a curved flow environment. We investigate how the emerging interfacial patterns are impacted by changes in the geometric properties of the curved Hele-Shaw cell. A vortex-sheet formalism is used to calculate the two-fluid interface curvature, and a gallery of possible shapes is provided to highlight a number of peculiar morphological features. A linear perturbation theory is employed to show that the most prominent aspects of these complex stationary patterns can be fairly well reproduced by the interplay of just two interfacial modes. The connection of these dominant modes to the geometry of the curved cell, as well as to the fluid dynamic properties of the flow, is discussed.

Milestone Deliverable: FY18-Q1: Deploy production sliding mesh capability with linear solver benchmarking.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Domino, Stefan P.

2017-12-01

This milestone was focused on deploying and verifying a “sliding-mesh interface,” and establishing baseline timings for blade-resolved simulations of a sub-MW-scale turbine. In the ExaWind project, we are developing both sliding-mesh and overset-mesh approaches for handling the rotating blades in an operating wind turbine. In the sliding-mesh approach, the turbine rotor and its immediate surrounding fluid are captured in a “disk” that is embedded in the larger fluid domain. The embedded fluid is simulated in a coordinate system that rotates with the rotor. It is important that the coupling algorithm (and its implementation) between the rotating and inertial discrete modelsmore » maintains the accuracy of the numerical methods on either side of the interface, i.e., the interface is “design order.”« less

Atomistic Modeling of the Fluid-Solid Interface in Simple Fluids

NASA Astrophysics Data System (ADS)

Hadjiconstantinou, Nicolas; Wang, Gerald

2017-11-01

Fluids can exhibit pronounced structuring effects near a solid boundary, typically manifested in a layered structure that has been extensively shown to directly affect transport across the interface. We present and discuss several results from molecular-mechanical modeling and molecular-dynamics (MD) simulations aimed at characterizing the structure of the first fluid layer directly adjacent to the solid. We identify a new dimensionless group - termed the Wall number - which characterizes the degree of fluid layering, by comparing the competing effects of wall-fluid interaction and thermal energy. We find that in the layering regime, several key features of the first layer layer - including its distance from the solid, its width, and its areal density - can be described using mean-field-energy arguments, as well as asymptotic analysis of the Nernst-Planck equation. For dense fluids, the areal density and the width of the first layer can be related to the bulk fluid density using a simple scaling relation. MD simulations show that these results are broadly applicable and robust to the presence of a second confining solid boundary, different choices of wall structure and thermalization, strengths of fluid-solid interaction, and wall geometries.

Adaptive beam tracking and steering via electrowetting-controlled liquid prism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, JT; Chen, CL

2011-11-07

We report an electrowetting-controlled optofluidic system for adaptive beam tracking and agile steering. With two immiscible fluids in a transparent cell, we can actively control the contact angle along the fluid-fluid-solid tri-junction line and hence the orientation of the fluid-fluid interface via electrowetting. The naturally formed meniscus between the two liquids can function as an optical prism. We have fabricated a liquid prism module with an aperture size of 10 mm -10mm. With 1 wt.% KCl and 1 wt.% Sodium Dodecyl Sulfate added into deionized water, the orientation of the water-silicone oil interface has been modulated between -26 degrees andmore » 26 degrees that can deflect and steer beam within the incidence angle of 0 degrees-15 degrees. The wide-range beam tracking and steering enables the liquid prism work as an electrowetting solar cell. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3660578]« less

Adaptive beam tracking and steering via electrowetting-controlled liquid prism

NASA Astrophysics Data System (ADS)

Cheng, Jiangtao; Chen, Chung-Lung

2011-11-01

We report an electrowetting-controlled optofluidic system for adaptive beam tracking and agile steering. With two immiscible fluids in a transparent cell, we can actively control the contact angle along the fluid-fluid-solid tri-junction line and hence the orientation of the fluid-fluid interface via electrowetting. The naturally formed meniscus between the two liquids can function as an optical prism. We have fabricated a liquid prism module with an aperture size of 10 mm × 10mm. With 1 wt. % KCl and 1 wt. % Sodium Dodecyl Sulfate added into deionized water, the orientation of the water-silicone oil interface has been modulated between -26° and 26° that can deflect and steer beam within the incidence angle of 0°-15°. The wide-range beam tracking and steering enables the liquid prism work as an electrowetting solar cell.

Pairwise Force Smoothed Particle Hydrodynamics model for multiphase flow: Surface tension and contact line dynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tartakovsky, Alexandre M.; Panchenko, Alexander

2016-01-01

We present a novel formulation of the Pairwise Force Smoothed Particle Hydrodynamics Model (PF-SPH) and use it to simulate two- and three-phase flows in bounded domains. In the PF-SPH model, the Navier-Stokes equations are discretized with the Smoothed Particle Hydrodynamics (SPH) method and the Young-Laplace boundary condition at the fluid-fluid interface and the Young boundary condition at the fluid-fluid-solid interface are replaced with pairwise forces added into the Navier-Stokes equations. We derive a relationship between the parameters in the pairwise forces and the surface tension and static contact angle. Next, we demonstrate the accuracy of the model under static andmore » dynamic conditions. Finally, to demonstrate the capabilities and robustness of the model we use it to simulate flow of three fluids in a porous material.« less

Curvilinear Immersed Boundary Method for Simulating Fluid Structure Interaction with Complex 3D Rigid Bodies

PubMed Central

Borazjani, Iman; Ge, Liang; Sotiropoulos, Fotis

2010-01-01

The sharp-interface CURVIB approach of Ge and Sotiropoulos [L. Ge, F. Sotiropoulos, A Numerical Method for Solving the 3D Unsteady Incompressible Navier-Stokes Equations in Curvilinear Domains with Complex Immersed Boundaries, Journal of Computational Physics 225 (2007) 1782–1809] is extended to simulate fluid structure interaction (FSI) problems involving complex 3D rigid bodies undergoing large structural displacements. The FSI solver adopts the partitioned FSI solution approach and both loose and strong coupling strategies are implemented. The interfaces between immersed bodies and the fluid are discretized with a Lagrangian grid and tracked with an explicit front-tracking approach. An efficient ray-tracing algorithm is developed to quickly identify the relationship between the background grid and the moving bodies. Numerical experiments are carried out for two FSI problems: vortex induced vibration of elastically mounted cylinders and flow through a bileaflet mechanical heart valve at physiologic conditions. For both cases the computed results are in excellent agreement with benchmark simulations and experimental measurements. The numerical experiments suggest that both the properties of the structure (mass, geometry) and the local flow conditions can play an important role in determining the stability of the FSI algorithm. Under certain conditions unconditionally unstable iteration schemes result even when strong coupling FSI is employed. For such cases, however, combining the strong-coupling iteration with under-relaxation in conjunction with the Aitken’s acceleration technique is shown to effectively resolve the stability problems. A theoretical analysis is presented to explain the findings of the numerical experiments. It is shown that the ratio of the added mass to the mass of the structure as well as the sign of the local time rate of change of the force or moment imparted on the structure by the fluid determine the stability and convergence of the FSI algorithm. The stabilizing role of under-relaxation is also clarified and an upper bound of the required for stability under-relaxation coefficient is derived. PMID:20981246

Curvilinear immersed boundary method for simulating fluid structure interaction with complex 3D rigid bodies

NASA Astrophysics Data System (ADS)

Borazjani, Iman; Ge, Liang; Sotiropoulos, Fotis

2008-08-01

The sharp-interface CURVIB approach of Ge and Sotiropoulos [L. Ge, F. Sotiropoulos, A numerical method for solving the 3D unsteady incompressible Navier-Stokes equations in curvilinear domains with complex immersed boundaries, Journal of Computational Physics 225 (2007) 1782-1809] is extended to simulate fluid structure interaction (FSI) problems involving complex 3D rigid bodies undergoing large structural displacements. The FSI solver adopts the partitioned FSI solution approach and both loose and strong coupling strategies are implemented. The interfaces between immersed bodies and the fluid are discretized with a Lagrangian grid and tracked with an explicit front-tracking approach. An efficient ray-tracing algorithm is developed to quickly identify the relationship between the background grid and the moving bodies. Numerical experiments are carried out for two FSI problems: vortex induced vibration of elastically mounted cylinders and flow through a bileaflet mechanical heart valve at physiologic conditions. For both cases the computed results are in excellent agreement with benchmark simulations and experimental measurements. The numerical experiments suggest that both the properties of the structure (mass, geometry) and the local flow conditions can play an important role in determining the stability of the FSI algorithm. Under certain conditions the FSI algorithm is unconditionally unstable even when strong coupling FSI is employed. For such cases, however, combining the strong coupling iteration with under-relaxation in conjunction with the Aitken's acceleration technique is shown to effectively resolve the stability problems. A theoretical analysis is presented to explain the findings of the numerical experiments. It is shown that the ratio of the added mass to the mass of the structure as well as the sign of the local time rate of change of the force or moment imparted on the structure by the fluid determine the stability and convergence of the FSI algorithm. The stabilizing role of under-relaxation is also clarified and the upper bound of the under-relaxation coefficient, required for stability, is derived.

Multiphase Fluid Dynamics for Spacecraft Applications

NASA Astrophysics Data System (ADS)

Shyy, W.; Sim, J.

2011-09-01

Multiphase flows involving moving interfaces between different fluids/phases are observed in nature as well as in a wide range of engineering applications. With the recent development of high fidelity computational techniques, a number of challenging multiphase flow problems can now be computed. We introduce the basic notion of the main categories of multiphase flow computation; Lagrangian, Eulerian, and Eulerian-Lagrangian techniques to represent and follow interface, and sharp and continuous interface methods to model interfacial dynamics. The marker-based adaptive Eulerian-Lagrangian method, which is one of the most popular methods, is highlighted with microgravity and space applications including droplet collision and spacecraft liquid fuel tank surface stability.

A comparative study of interface reconstruction methods for multi-material ALE simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kucharik, Milan; Garimalla, Rao; Schofield, Samuel

2009-01-01

In this paper we compare the performance of different methods for reconstructing interfaces in multi-material compressible flow simulations. The methods compared are a material-order-dependent Volume-of-Fluid (VOF) method, a material-order-independent VOF method based on power diagram partitioning of cells and the Moment-of-Fluid method (MOF). We demonstrate that the MOF method provides the most accurate tracking of interfaces, followed by the VOF method with the right material ordering. The material-order-independent VOF method performs some-what worse than the above two while the solutions with VOF using the wrong material order are considerably worse.

Film bonded fuel cell interface configuration

DOEpatents

Kaufman, Arthur; Terry, Peter L.

1989-01-01

The present invention relates to improved elements for use in fuel cell stacks, and more particularly, to a stack having a corrosion-resistant, electrally conductive, fluid-impervious interface member therein.

Transition from Selective Withdrawal to Light Layer Entrainment in an Oil-Water System

NASA Astrophysics Data System (ADS)

Hartenberger, Joel; O'Hern, Timothy; Webb, Stephen; James, Darryl

2010-11-01

Selective withdrawal refers to the selective removal of fluid of one density without entraining an adjacent fluid layer of a different density. Most prior literature has examined removal of the lower density fluid and the transition to entraining the higher density fluid. In the present experiments, a higher density liquid is removed through a tube that extends just below its interface with a lower density fluid. The critical depth for a given flow rate at which the liquid-liquid interface transitions to entrain the lighter fluid was measured. Experiments were performed for a range of different light layer silicone oils and heavy layer water or brine, covering a range of density and viscosity ratios. Applications include density-stratified reservoirs and brine removal from oil storage caverns. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Interfacial fluid instabilities and Kapitsa pendula.

PubMed

Krieger, Madison S

2017-07-01

The onset and development of instabilities is one of the central problems in fluid mechanics. Here we develop a connection between instabilities of free fluid interfaces and inverted pendula. When acted upon solely by the gravitational force, the inverted pendulum is unstable. This position can be stabilized by the Kapitsa phenomenon, in which high-frequency low-amplitude vertical vibrations of the base creates a fictitious force which opposes the gravitational force. By transforming the dynamical equations governing a fluid interface into an appropriate pendulum-type equation, we demonstrate how stability can be induced in fluid systems by properly tuned vibrations. We construct a "dictionary"-type relationship between various pendula and the classical Rayleigh-Taylor, Kelvin-Helmholtz, Rayleigh-Plateau and the self-gravitational instabilities. This makes several results in control theory and dynamical systems directly applicable to the study of tunable fluid instabilities, where the critical wavelength depends on the external forces or the instability is suppressed entirely. We suggest some applications and instances of the effect ranging in scale from microns to the radius of a galaxy.

Three-dimensional user interfaces for scientific visualization

NASA Technical Reports Server (NTRS)

Vandam, Andries

1995-01-01

The main goal of this project is to develop novel and productive user interface techniques for creating and managing visualizations of computational fluid dynamics (CFD) datasets. We have implemented an application framework in which we can visualize computational fluid dynamics user interfaces. This UI technology allows users to interactively place visualization probes in a dataset and modify some of their parameters. We have also implemented a time-critical scheduling system which strives to maintain a constant frame-rate regardless of the number of visualization techniques. In the past year, we have published parts of this research at two conferences, the research annotation system at Visualization 1994, and the 3D user interface at UIST 1994. The real-time scheduling system has been submitted to SIGGRAPH 1995 conference. Copies of these documents are included with this report.

Vapor-Gas Bubble Evolution and Growth in Extremely Viscous Fluids Under Vacuum

NASA Technical Reports Server (NTRS)

Kizito, John; Balasubramaniam, R.; Nahra, Henry; Agui, Juan; Truong, Duc

2008-01-01

Formation of vapor and gas bubbles and voids is normal and expected in flow processes involving extremely viscous fluids in normal gravity. Practical examples of extremely viscous fluids are epoxy-like filler materials before the epoxy fluids cure to their permanent form to create a mechanical bond between two substrates. When these fluids flow with a free liquid interface exposed to vacuum, rapid bubble expansion process may ensue. Bubble expansion might compromise the mechanical bond strength. The potential sources for the origin of the gases might be incomplete out-gassing process prior to filler application; regasification due to seal leakage in the filler applicator; and/or volatiles evolved from cure reaction products formed in the hardening process. We embarked on a study that involved conducting laboratory experiments with imaging diagnostics in order to deduce the seriousness of bubbling caused by entrained air and volatile fluids under space vacuum and low gravity environment. We used clear fluids with the similar physical properties as the epoxy-like filler material to mimic the dynamics of bubbles. Another aspect of the present study was to determine the likelihood of bubbling resulting from dissolved gases nucleating from solution. These experimental studies of the bubble expansion are compared with predictions using a modified Rayleigh- Plesset equation, which models the bubble expansion.

Electrostatic interaction between dissimilar colloids at fluid interfaces

NASA Astrophysics Data System (ADS)

Majee, Arghya; Schmetzer, Timo; Bier, Markus

2018-04-01

The electrostatic interaction between two nonidentical, moderately charged colloids situated in close proximity of each other at a fluid interface is studied. By resorting to a well-justified model system, this problem is analytically solved within the framework of linearized Poisson-Boltzmann density functional theory. The resulting interaction comprises a surface and a line part, both of which, as functions of the interparticle separation, show a rich behavior including monotonic as well as nonmonotonic variations. In almost all cases, these variations cannot be captured correctly by using the superposition approximation. Moreover, expressions for the surface tensions, the line tensions and the fluid-fluid interfacial tension, which are all independent of the interparticle separation, are obtained. Our results are expected to be particularly useful for emulsions stabilized by oppositely charged particles.

Edge Fracture in Complex Fluids.

PubMed

Hemingway, Ewan J; Kusumaatmaja, Halim; Fielding, Suzanne M

2017-07-14

We study theoretically the edge fracture instability in sheared complex fluids, by means of linear stability analysis and direct nonlinear simulations. We derive an exact analytical expression for the onset of edge fracture in terms of the shear-rate derivative of the fluid's second normal stress difference, the shear-rate derivative of the shear stress, the jump in shear stress across the interface between the fluid and the outside medium (usually air), the surface tension of that interface, and the rheometer gap size. We provide a full mechanistic understanding of the edge fracture instability, carefully validated against our simulations. These findings, which are robust with respect to choice of rheological constitutive model, also suggest a possible route to mitigating edge fracture, potentially allowing experimentalists to achieve and accurately measure flows stronger than hitherto possible.

Dynamic fluid connectivity during steady-state multiphase flow in a sandstone.

PubMed

Reynolds, Catriona A; Menke, Hannah; Andrew, Matthew; Blunt, Martin J; Krevor, Samuel

2017-08-01

The current conceptual picture of steady-state multiphase Darcy flow in porous media is that the fluid phases organize into separate flow pathways with stable interfaces. Here we demonstrate a previously unobserved type of steady-state flow behavior, which we term "dynamic connectivity," using fast pore-scale X-ray imaging. We image the flow of N 2 and brine through a permeable sandstone at subsurface reservoir conditions, and low capillary numbers, and at constant fluid saturation. At any instant, the network of pores filled with the nonwetting phase is not necessarily connected. Flow occurs along pathways that periodically reconnect, like cars controlled by traffic lights. This behavior is consistent with an energy balance, where some of the energy of the injected fluids is sporadically converted to create new interfaces.

Dynamics of immiscible liquids in a rotating horizontal cylinder

NASA Astrophysics Data System (ADS)

Kozlov, N. V.; Kozlova, A. N.; Shuvalova, D. A.

2016-11-01

The dynamics of an interface between two immiscible liquids of different density is studied experimentally in a horizontal cylinder at rotation in the gravity field. Two liquids entirely fill the cavity volume, and the container is rotated sufficiently fast so that the liquids are centrifuged. The light liquid forms a column extended along the rotation axis, and the heavy liquid forms an annular layer. Under the action of gravity, the light liquid column displaces steadily along the radius, downwards in the laboratory frame. As a result, fluid oscillations in the cavity frame are excited at the interface, which lead to the generation of a steady streaming, and the fluid comes into a slow lagging rotation with respect to the cylinder walls. The dynamics of the studied system is determined by the ratio of the gravity acceleration to the centrifugal one—the dimensionless acceleration. In experiments, the system is controlled by the means of variation of the rotation rate, i.e., of the centrifugal force. At a critical value of the dimensionless acceleration the circular interface looses stability, and an azimuthal wave is excited. This leads to a strong increase in the interface differential velocity. A theoretical analysis is done based on the theory of centrifugal waves and a frequency equation is obtained. Experimental results are in good agreement with the theory at the condition of small wave amplitudes. Mechanism of steady streaming generation is analyzed based on previously published theoretical results obtained for the limiting case when the light phase is a solid cylinder. A qualitative agreement is found.

A finite element model of conduction, convection, and phase change near a solid/melt interface. Ph.D. Thesis - Michigan Univ.

NASA Technical Reports Server (NTRS)

Viterna, Larry A.

1991-01-01

Detailed understanding of heat transfer and fluid flow is required for many aerospace thermal systems. These systems often include phase change and operate over a range of accelerations or effective gravitational fields. An approach to analyzing such systems is presented which requires the simultaneous solution of the conservation laws of energy, momentum, and mass, as well as an equation of state. The variable property form of the governing equations are developed in two-dimensional Cartesian coordinates for a Newtonian fluid. A numerical procedure for solving the governing equations is presented and implemented in a computer program. The Galerkin form of the finite element method is used to solve the spatial variation of the field variables, along with the implicit Crank-Nicolson time marching algorithm. Quadratic Langrangian elements are used for the internal energy and the two components of velocity. Linear Lagrangian elements are used for the pressure. The location of the solid/liquid interface as well as the temperatures are determined form the calculated internal energy and pressure. This approach is quite general in that it can describe heat transfer without phase change, phase change with a sharp interface, and phase change without an interface. Analytical results from this model are compared to those of other researchers studying transient conduction, convection, and phase change and are found to be in good agreement. The numerical procedure presented requires significant computer resources, but this is not unusual when compared to similar studies by other researchers. Several methods are suggested to reduce the computational times.

Axisymmetric flows from fluid injection into a confined porous medium

NASA Astrophysics Data System (ADS)

Guo, Bo; Zheng, Zhong; Celia, Michael A.; Stone, Howard A.

2016-02-01

We study the axisymmetric flows generated from fluid injection into a horizontal confined porous medium that is originally saturated with another fluid of different density and viscosity. Neglecting the effects of surface tension and fluid mixing, we use the lubrication approximation to obtain a nonlinear advection-diffusion equation that describes the time evolution of the sharp fluid-fluid interface. The flow behaviors are controlled by two dimensionless groups: M, the viscosity ratio of displaced fluid relative to injected fluid, and Γ, which measures the relative importance of buoyancy and fluid injection. For this axisymmetric geometry, the similarity solution involving R2/T (where R is the dimensionless radial coordinate and T is the dimensionless time) is an exact solution to the nonlinear governing equation for all times. Four analytical expressions are identified as asymptotic approximations (two of which are new solutions): (i) injection-driven flow with the injected fluid being more viscous than the displaced fluid (Γ ≪ 1 and M < 1) where we identify a self-similar solution that indicates a parabolic interface shape; (ii) injection-driven flow with injected and displaced fluids of equal viscosity (Γ ≪ 1 and M = 1), where we find a self-similar solution that predicts a distinct parabolic interface shape; (iii) injection-driven flow with a less viscous injected fluid (Γ ≪ 1 and M > 1) for which there is a rarefaction wave solution, assuming that the Saffman-Taylor instability does not occur at the reservoir scale; and (iv) buoyancy-driven flow (Γ ≫ 1) for which there is a well-known self-similar solution corresponding to gravity currents in an unconfined porous medium [S. Lyle et al. "Axisymmetric gravity currents in a porous medium," J. Fluid Mech. 543, 293-302 (2005)]. The various axisymmetric flows are summarized in a Γ-M regime diagram with five distinct dynamic behaviors including the four asymptotic regimes and an intermediate regime. The implications of the regime diagram are discussed using practical engineering projects of geological CO2 sequestration, enhanced oil recovery, and underground waste disposal.

Conductivity dependence of seismoelectric wave phenomena in fluid-saturated sediments

NASA Astrophysics Data System (ADS)

Block, Gareth I.; Harris, John G.

2006-01-01

Seismoelectric phenomena in sediments arise from acoustic wave-induced fluid motion in the pore space, which perturbs the electrostatic equilibrium of the electric double layer on the grain surfaces. Experimental techniques and the apparatus built to study the conductivity dependence of the electrokinetic (EK) effect are described, and outcomes for studies in loose glass microspheres and medium-grain sand are presented. By varying the NaCl concentration in the pore fluid, we measured the conductivity dependence of two kinds of EK behavior: (1) the electric fields generated within the samples by the passage of transmitted acoustic waves and (2) the electromagnetic waves produced at the fluid-sediment interface by the incident acoustic wave. Both phenomena are caused by relative fluid motion in the sediment pores; this feature is characteristic of poroelastic (Biot) media but is not predicted by either viscoelastic fluid or solid models. A model of plane wave reflection from a fluid-sediment interface using EK-Biot theory leads to theoretical predictions that compare well to the experimental data for both loose glass microspheres and medium-grain sand.

Getting in shape: molten wax drop deformation and solidification at an immiscible liquid interface.

PubMed

Beesabathuni, Shilpa N; Lindberg, Seth E; Caggioni, Marco; Wesner, Chris; Shen, Amy Q

2015-05-01

The controlled production of non-spherical shaped particles is important for many applications such as food processing, consumer goods, adsorbents, drug delivery, and optical sensing. In this paper, we investigated the deformation and simultaneous solidification of millimeter size molten wax drops as they impacted an immiscible liquid interface of higher density. By varying initial temperature and viscoelasticity of the molten drop, drop size, impact velocity, viscosity and temperature of the bath fluid, and the interfacial tension between the molten wax and bath fluid, spherical molten wax drops impinged on a cooling water bath and were arrested into non-spherical solidified particles in the form of ellipsoid, mushroom, disc, and flake-like shapes. We constructed cursory phase diagrams for the various particle shapes generated over a range of Weber, Capillary, Reynolds, and Stefan numbers, governed by the interfacial, inertial, viscous, and thermal effects. We solved a simplified heat transfer problem to estimate the time required to initiate the solidification at the interface of a spherical molten wax droplet and cooling aqueous bath after impact. By correlating this time with the molten wax drop deformation history captured from high speed imaging experiments, we elucidate the delicate balance of interfacial, inertial, viscous, and thermal forces that determine the final morphology of wax particles. Copyright © 2015 Elsevier Inc. All rights reserved.

Massive radius-dependent flow slippage in carbon nanotubes

PubMed Central

Secchi, Eleonora; Marbach, Sophie; Niguès, Antoine; Stein, Derek; Siria, Alessandro; Bocquet, Lydéric

2016-01-01

Simulations and measurements have established that water moves through carbon nanotubes with exceptionally high rates due to nearly frictionless interfaces1–4. These observations have stimulated interest in nanotube-based membranes for applications that range from desalination to nano-filtration and energy harvesting5–10, yet the exact water transport mechanisms inside the nanotubes and at the water-carbon interface continue to be controversially discussed11,12 because existing theories fail to provide a satisfying explanation for the limited number of experimental results available to date13. This is because even though controlled and systematic studies have explored transport through individual nanotubes8,9,14–7, none has met the considerable technical challenge of unambiguously measuring the permeability of a single nanotube11. Here we show that the pressure-driven flow rate across individual nanotubes can be determined with unprecedented sensitivity and without dyes from the hydrodynamics of water jets as they emerge from single nanotubes into a surrounding fluid. Our measurements reveal unexpectedly large and radius-dependent surface slippage in carbon nanotubes (CNT), and no slippage in boron-nitride nanotubes (BNNT) that are crystallographically similar to CNTs but differ electronically. This pronounced contrast between the two systems must originate from subtle differences in atomic-scale details of their solid-liquid interfaces, strikingly illustrating that nanofluidics is the frontier where the continuum picture of fluid mechanics confronts the atomic nature of matter. PMID:27604947

Tracer SWIW tests in propped and un-propped fractures: parameter sensitivity issues, revisited

NASA Astrophysics Data System (ADS)

Ghergut, Julia; Behrens, Horst; Sauter, Martin

2017-04-01

Single-well injection-withdrawal (SWIW) or 'push-then-pull' tracer methods appear attractive for a number of reasons: less uncertainty on design and dimensioning, and lower tracer quantities required than for inter-well tests; stronger tracer signals, enabling easier and cheaper metering, and shorter metering duration required, reaching higher tracer mass recovery than in inter-well tests; last not least: no need for a second well. However, SWIW tracer signal inversion faces a major issue: the 'push-then-pull' design weakens the correlation between tracer residence times and georeservoir transport parameters, inducing insensitivity or ambiguity of tracer signal inversion w. r. to some of those georeservoir parameters that are supposed to be the target of tracer tests par excellence: pore velocity, transport-effective porosity, fracture or fissure aperture and spacing or density (where applicable), fluid/solid or fluid/fluid phase interface density. Hydraulic methods cannot measure the transport-effective values of such parameters, because pressure signals correlate neither with fluid motion, nor with material fluxes through (fluid-rock, or fluid-fluid) phase interfaces. The notorious ambiguity impeding parameter inversion from SWIW test signals has nourished several 'modeling attitudes': (i) regard dispersion as the key process encompassing whatever superposition of underlying transport phenomena, and seek a statistical description of flow-path collectives enabling to characterize dispersion independently of any other transport parameter, as proposed by Gouze et al. (2008), with Hansen et al. (2016) offering a comprehensive analysis of the various ways dispersion model assumptions interfere with parameter inversion from SWIW tests; (ii) regard diffusion as the key process, and seek for a large-time, asymptotically advection-independent regime in the measured tracer signals (Haggerty et al. 2001), enabling a dispersion-independent characterization of multiple-scale diffusion; (iii) attempt to determine both advective and non-advective transport parameters from one and the same conservative-tracer signal (relying on 'third-party' knowledge), or from twin signals of a so-called 'dual' tracer pair, e. g.: using tracers with contrasting reactivity and partitioning behavior to determine residual saturation in depleted oilfields (Tomich et al. 1973), or to determine advective parameters (Ghergut et al. 2014); using early-time signals of conservative and sorptive tracers for propped-fracture characterization (Karmakar et al. 2015); using mid-time signals of conservative tracers for a reservoir-borne inflow profiling in multi-frac systems (Ghergut et al. 2016), etc. The poster describes new uses of type-(iii) techniques for the specific purposes of shale-gas reservoir characterization, productivity monitoring, diagnostics and engineering of 're-frac' treatments, based on parameter sensitivity findings from German BMWi research project "TRENDS" (Federal Ministry for Economic Affairs and Energy, FKZ 0325515) and from the EU-H2020 project "FracRisk" (grant no. 640979).

Rayleigh-Taylor instability-fascinating gateway to the study of fluid dynamics

NASA Astrophysics Data System (ADS)

Benjamin, Robert F.

1999-09-01

A series of low-cost simple, "kitchen-physics" experiments demonstrates Rayleigh-Taylor Instability (RTI), the growth of ripples at an interface between fluids when the higher-density fluid is on top. We also describe the importance of RTI in ocean dynamics and commercial products.

Nonlinear theory of classical cylindrical Richtmyer-Meshkov instability for arbitrary Atwood numbers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Wan Hai; HEDPS and CAPT, Peking University, Beijing 100871; Ping Yu, Chang, E-mail: champion-yu@163.com

2014-06-15

A nonlinear theory is developed to describe the cylindrical Richtmyer-Meshkov instability (RMI) of an impulsively accelerated interface between incompressible fluids, which is based on both a technique of Padé approximation and an approach of perturbation expansion directly on the perturbed interface rather than the unperturbed interface. When cylindrical effect vanishes (i.e., in the large initial radius of the interface), our explicit results reproduce those [Q. Zhang and S.-I. Sohn, Phys. Fluids 9, 1106 (1996)] related to the planar RMI. The present prediction in agreement with previous simulations [C. Matsuoka and K. Nishihara, Phys. Rev. E 73, 055304(R) (2006)] leads usmore » to better understand the cylindrical RMI at arbitrary Atwood numbers for the whole nonlinear regime. The asymptotic growth rate of the cylindrical interface finger (bubble or spike) tends to its initial value or zero, depending upon mode number of the initial cylindrical interface and Atwood number. The explicit conditions, directly affecting asymptotic behavior of the cylindrical interface finger, are investigated in this paper. This theory allows a straightforward extension to other nonlinear problems related closely to an instable interface.« less

Asymptotic modeling of transport phenomena at the interface between a fluid and a porous layer: Jump conditions

NASA Astrophysics Data System (ADS)

Angot, Philippe; Goyeau, Benoît; Ochoa-Tapia, J. Alberto

2017-06-01

We develop asymptotic modeling for two- or three-dimensional viscous fluid flow and convective transfer at the interface between a fluid and a porous layer. The asymptotic model is based on the fact that the thickness d of the interfacial transition region Ωfp of the one-domain representation is very small compared to the macroscopic length scale L . The analysis leads to an equivalent two-domain representation where transport phenomena in the transition layer of the one-domain approach are represented by algebraic jump boundary conditions at a fictive dividing interface Σ between the homogeneous fluid and porous regions. These jump conditions are thus stated up to first-order in O (d /L ) with d /L ≪1 . The originality and relevance of this asymptotic model lies in its general and multidimensional character. Indeed, it is shown that all the jump interface conditions derived for the commonly used 1D-shear flow are recovered by taking the tangential component of the asymptotic model. In that case, the comparison between the present model and the different models available in the literature gives explicit expressions of the effective jump coefficients and their associated scaling. In addition for multi-dimensional flows, the general asymptotic model yields the different components of the jump conditions including a new specific equation for the cross-flow pressure jump on Σ .

Asymptotic modeling of transport phenomena at the interface between a fluid and a porous layer: Jump conditions.

PubMed

Angot, Philippe; Goyeau, Benoît; Ochoa-Tapia, J Alberto

2017-06-01

We develop asymptotic modeling for two- or three-dimensional viscous fluid flow and convective transfer at the interface between a fluid and a porous layer. The asymptotic model is based on the fact that the thickness d of the interfacial transition region Ω_{fp} of the one-domain representation is very small compared to the macroscopic length scale L. The analysis leads to an equivalent two-domain representation where transport phenomena in the transition layer of the one-domain approach are represented by algebraic jump boundary conditions at a fictive dividing interface Σ between the homogeneous fluid and porous regions. These jump conditions are thus stated up to first-order in O(d/L) with d/L≪1. The originality and relevance of this asymptotic model lies in its general and multidimensional character. Indeed, it is shown that all the jump interface conditions derived for the commonly used 1D-shear flow are recovered by taking the tangential component of the asymptotic model. In that case, the comparison between the present model and the different models available in the literature gives explicit expressions of the effective jump coefficients and their associated scaling. In addition for multi-dimensional flows, the general asymptotic model yields the different components of the jump conditions including a new specific equation for the cross-flow pressure jump on Σ.

Direct Deposition of Gas Phase Generated Aerosol Gold Nanoparticles into Biological Fluids - Corona Formation and Particle Size Shifts

PubMed Central

Svensson, Christian R.; Messing, Maria E.; Lundqvist, Martin; Schollin, Alexander; Deppert, Knut; Pagels, Joakim H.; Rissler, Jenny; Cedervall, Tommy

2013-01-01

An ongoing discussion whether traditional toxicological methods are sufficient to evaluate the risks associated with nanoparticle inhalation has led to the emergence of Air-Liquid interface toxicology. As a step in this process, this study explores the evolution of particle characteristics as they move from the airborne state into physiological solution. Airborne gold nanoparticles (AuNP) are generated using an evaporation-condensation technique. Spherical and agglomerate AuNPs are deposited into physiological solutions of increasing biological complexity. The AuNP size is characterized in air as mobility diameter and in liquid as hydrodynamic diameter. AuNP:Protein aggregation in physiological solutions is determined using dynamic light scattering, particle tracking analysis, and UV absorption spectroscopy. AuNPs deposited into homocysteine buffer form large gold-aggregates. Spherical AuNPs deposited in solutions of albumin were trapped at the Air-Liquid interface but was readily suspended in the solutions with a size close to that of the airborne particles, indicating that AuNP:Protein complex formation is promoted. Deposition into serum and lung fluid resulted in larger complexes, reflecting the formation of a more complex protein corona. UV absorption spectroscopy indicated no further aggregation of the AuNPs after deposition in solution. The corona of the deposited AuNPs shows differences compared to AuNPs generated in suspension. Deposition of AuNPs from the aerosol phase into biological fluids offers a method to study the protein corona formed, upon inhalation and deposition in the lungs in a more realistic way compared to particle liquid suspensions. This is important since the protein corona together with key particle properties (e.g. size, shape and surface reactivity) to a large extent may determine the nanoparticle effects and possible translocation to other organs. PMID:24086363

Fluid Pressures at the Shoe-Floor-Contaminant Interface During Slips: Effects of Tread & Implications on Slip Severity

PubMed Central

Beschorner, Kurt E.; Albert, Devon L.; Chambers, April J.; Redfern, Mark S.

2018-01-01

Previous research on slip and fall accidents has suggested that pressurized fluid between the shoe and floor is responsible for initiating slips yet this effect has not been verified experimentally. This study aimed to 1) measure hydrodynamic pressures during slipping for treaded and untreaded conditions; 2) determine the effects of fluid pressure on slip severity; and 3) quantify how fluid pressures vary with instantaneous resultant slipping speed, position on the shoe surface, and throughout the progression of the slip. Eighteen subjects walked on known dry and unexpected slippery floors, while wearing treaded and untreaded shoes. Fluid pressure sensors, embedded in the floor, recorded hydrodynamic pressures during slipping. The maximum fluid pressures (mean+/−standard deviation) were significantly higher for the untreaded conditions (124 +/−75 kPa) than the treaded conditions (1.1 +/−0.29 kPa). Maximum fluid pressures were positively correlated with peak slipping speed (r = 0.87), suggesting that higher fluid pressures, which are associated with untreaded conditions, resulted in more severe slips. Instantaneous resultant slipping speed and position of sensor relative to the shoe sole and walking direction explained 41% of the fluid pressure variability. Fluid pressures were primarily observed for untreaded conditions. This study confirms that fluid pressures are relevant to slipping events, consistent with fluid dynamics theory (i.e. the Reynolds equation), and can be modified with shoe tread design. The results suggest that the occurrence and severity of unexpected slips can be reduced by designing shoes/floors that reduce underfoot fluid pressures. PMID:24267270

Fluid and element transfer at the slab-mantle interface: insights from the serpentinized Livingstone Fault, New Zealand

NASA Astrophysics Data System (ADS)

Smith, S. A. F.; Scott, J.; Tarling, M.; Tulley, C. J.; le Roux, P. J.

2017-12-01

At the slab-mantle interface in subduction zones, hydrous fluids released by dehydration reactions are fluxed upwards into the fore-arc mantle corner. The extent to which these fluids can move across the plate interface shear zone has significant implications for understanding the composition of the mantle wedge and the origin of episodic tremor and slow slip. The >1000 km long Livingstone Fault in New Zealand provides a superbly exposed analogue (both in terms of scale and the rock types involved) for the serpentinite shear zone likely to be present along the slab-mantle interface. The Livingstone Fault is a sheared serpentinite mélange up to several hundreds of meters wide that separates greenschist-facies quartzofeldspathic metasediments (e.g. analogue for slab sediments) from variably-serpentinized harzburgitic peridotite (e.g. analogue for mantle wedge). To track element mobility and paleo-fluid flow across the shear zone, Sr and Nd isotopes were measured in five transects across the metasediments, mélange and serpentinized peridotites. Results show that the mélange and serpentinized peridotites (originally with Sr and Nd similar to Permian MORB) were progressively overprinted with the isotopic composition of the metasediments at distances of up to c. 400 m from the mélange-metasediment contact. Mass balance calculations require that many elements were mobile across the mélange shear zone, but permeability modeling indicates that diffusive transfer of such elements is unrealistically slow. Instead, it appears that fluid and element percolation in to and across the mélange was aided by episodic over-pressuring and fracturing, as indicated by the widespread presence of tremolite-bearing breccias and veins that mutually cross-cut the serpentinite mélange fabrics. Overall, the field and isotopic results indicate that fluid and element redistribution within major serpentinite-bearing shear zones is strongly aided by fracturing and brecciation that are triggered by episodic fluid over-pressuring. By comparison to recent geophysical and experimental results, we infer that high fluid pressures and the resultant brittle failure processes may contribute to the slow slip and tremor signal near the forearc mantle corner.

Crystal Growth of ZnSe and Related Ternary Compound Semiconductors by Vapor Transport

NASA Technical Reports Server (NTRS)

2003-01-01

The objective of the project is to determine the relative contributions of gravity-driven fluid flows to the compositional distribution, incorporation of impurities and defects, and deviation from stoichiometry observed in the crystals grown by vapor transport as results of buoyancy-driven convection and growth interface fluctuations caused by irregular fluid-flows. ZnSe and related ternary compounds, such as ZnSeS and ZnSeTe, were grown by vapor transport technique with real time in situ non-invasive monitoring techniques. The grown crystals were characterized extensively to correlate the grown crystal properties with the growth conditions. Significant effects of gravity vector orientation on the growth crystal morphology and point defect distribution were observed.

Wave radiation and diffraction by a two-dimensional floating body with an opening near a side wall

NASA Astrophysics Data System (ADS)

Zhang, Hong-sheng; Zhou, Hua-wei

2013-08-01

The radiation and diffraction problem of a two-dimensional rectangular body with an opening floating on a semi-infinite fluid domain of finite water depth is analysed based on the linearized velocity potential theory through an analytical solution procedure. The expressions for potentials are obtained by the method of variation separation, in which the unknown coefficients are determined by the boundary condition and matching requirement on the interface. The effects of the position of the hole and the gap between the body and side wall on hydrodynamic characteristics are investigated. Some resonance is observed like piston motion in a moon pool and sloshing in a closed tank because of the existence of restricted fluid domains.

A Parametric Study of Slag Skin Formation in Electroslag Remelting

NASA Astrophysics Data System (ADS)

Yanke, Jeff; Krane, Matthew John M.

In electroslag remelting (ESR), the slag generates heat, chemically refines the melting electrode material, and forms frozen skin on the mold. An axisymmetric model is used to simulate fluid flow, heat transfer, solidification, and electromagnetics and their interaction with slag skin formation in ESR. A volume of fluid (VOF) method is used to track the slag/metal interface, allowing simulation of slag freezing to the mold. Mold diameter and applied current are varied to determine how these parameters affect melt rate and formation of slag skin during ESR. Variations in the slag skin thickness within the slag cap are found to have a significant impact on melt rate and depth of metal sump. Changes in slag cap volume resulted in small changes in melt rate.

Theories of binary fluid mixtures: from phase-separation kinetics to active emulsions

NASA Astrophysics Data System (ADS)

Cates, Michael E.; Tjhung, Elsen

2018-02-01

Binary fluid mixtures are examples of complex fluids whose microstructure and flow are strongly coupled. For pairs of simple fluids, the microstructure consists of droplets or bicontinuous demixed domains and the physics is controlled by the interfaces between these domains. At continuum level, the structure is defined by a composition field whose gradients which are steep near interfaces drive its diffusive current. These gradients also cause thermodynamic stresses which can drive fluid flow. Fluid flow in turn advects the composition field, while thermal noise creates additional random fluxes that allow the system to explore its configuration space and move towards the Boltzmann distribution. This article introduces continuum models of binary fluids, first covering some well-studied areas such as the thermodynamics and kinetics of phase separation, and emulsion stability. We then address cases where one of the fluid components has anisotropic structure at mesoscopic scales creating nematic (or polar) liquid-crystalline order; this can be described through an additional tensor (or vector) order parameter field. We conclude by outlining a thriving area of current research, namely active emulsions, in which one of the binary components consists of living or synthetic material that is continuously converting chemical energy into mechanical work.

Cellular lining of the sheep pineal recess studied by light-, transmission-, and scanning electron microscopy: morphologic indications for a direct secretion of melatonin from the pineal gland to the cerebrospinal fluid.

PubMed

Tricoire, Hélène; Malpaux, Benoit; Møller, Morten

2003-01-27

In the sheep, the pineal hormone melatonin displays nocturnal levels 20 times as high in the cerebrospinal fluid of the third ventricle as in the jugular blood. Moreover, in the pineal recess, the evagination of the third ventricle into the pineal stalk, the levels of melatonin in the cerebrospinal fluid are even higher than in the ventral part of the third ventricle. This finding suggests melatonin to be secreted directly from the pineal gland to the ventricular lumen of the pineal recess of this species. We have, therefore, studied the interface between the sheep pineal gland and the cerebrospinal fluid by light-, scanning-, and electron microscopy of the pineal recess, as well as the permeability of the interface by tracer injections into the third ventricle. First, we show that the classic ependymal lining of the third ventricle disappears in the superior part of the recess. In this area, bulging pinealocytes, displaying immunoreactivity for serotonin, directly appose the cerebrospinal fluid. This pineal-cerebrospinal fluid interface of the sheep is large compared with other species, especially rodent species. Intraventricular injections of horseradish peroxidase and fluorescein isothiocyanate showed that both these tracers could permeate from the pineal recess into the sheep pineal parenchyma. This permeation was due to the presence of gap and intermediate junctions connecting the pinealocytes apposing the ventricular lumen. Thus, our results show that endocrine cells in this specialized area of the ventricular system are in direct contact with the cerebrospinal fluid. This finding supports the physiological concept of a direct secretion of melatonin into the cerebrospinal fluid of the sheep pineal recess. Copyright 2002 Wiley-Liss, Inc.

A weak-coupling immersed boundary method for fluid-structure interaction with low density ratio of solid to fluid

NASA Astrophysics Data System (ADS)

Kim, Woojin; Lee, Injae; Choi, Haecheon

2018-04-01

We present a weak-coupling approach for fluid-structure interaction with low density ratio (ρ) of solid to fluid. For accurate and stable solutions, we introduce predictors, an explicit two-step method and the implicit Euler method, to obtain provisional velocity and position of fluid-structure interface at each time step, respectively. The incompressible Navier-Stokes equations, together with these provisional velocity and position at the fluid-structure interface, are solved in an Eulerian coordinate using an immersed-boundary finite-volume method on a staggered mesh. The dynamic equation of an elastic solid-body motion, together with the hydrodynamic force at the provisional position of the interface, is solved in a Lagrangian coordinate using a finite element method. Each governing equation for fluid and structure is implicitly solved using second-order time integrators. The overall second-order temporal accuracy is preserved even with the use of lower-order predictors. A linear stability analysis is also conducted for an ideal case to find the optimal explicit two-step method that provides stable solutions down to the lowest density ratio. With the present weak coupling, three different fluid-structure interaction problems were simulated: flows around an elastically mounted rigid circular cylinder, an elastic beam attached to the base of a stationary circular cylinder, and a flexible plate, respectively. The lowest density ratios providing stable solutions are searched for the first two problems and they are much lower than 1 (ρmin = 0.21 and 0.31, respectively). The simulation results agree well with those from strong coupling suggested here and also from previous numerical and experimental studies, indicating the efficiency and accuracy of the present weak coupling.

Determination of Interfacial Rheological Properties through Microgravity Oscillations of Bubbles and Drops

NASA Technical Reports Server (NTRS)

Nadim, Ali; Rush, Brian M.

2000-01-01

This report summarizes our derivations of analytical expressions for the frequencies and damping constants for small-amplitude axisymmetric shape oscillations of a liquid drop suspended in an immiscible fluid host in microgravity. In particular, this work addresses large Reynolds number shape oscillations and focuses on the surface rheological effects that arise from the presence of insoluble surfactants at the interface. Parameters characterizing viscous effects from the bulk phases, surface viscous effects, Marangoni effects from the surface advection and diffusion of surfactants, and the Gibbs elasticity are all considered and analyzed to determine the relative importance of each contribution. Supplementing the analytical treatment for small-amplitude oscillations, a numerical boundary integral equation formulation is developed for the study of large-amplittide axisymmetric oscillations of a drop in vacuum. The boundary integral formulation is an extension of classical potential flow theory and approximately accounts for viscous effects in the bulk fluid as well as the surface viscous and Marangoni effects resulting from an insoluble surfactant contaminating the interface. Theoretical and numerical results are presented for four distinct cases. These, range from the case when the effects of the surfactants are 'negligible' to 'large' when compared to the viscous effects in the bulk phases. The feasibility of the non-contact measurement of the surface parameters, using experimental observations for the oscillation frequencies and damping constants of drops and bubbles, is discussed.

Effect of synovial fluid, phosphate-buffered saline solution, and water on the dissolution and corrosion properties of CoCrMo alloys as used in orthopedic implants.

PubMed

Lewis, A C; Kilburn, M R; Papageorgiou, I; Allen, G C; Case, C P

2005-06-15

The corrosion and dissolution of high- and low-carbon CoCrMo alloys, as used in orthopedic joint replacements, were studied by immersing samples in phosphate-buffered saline (PBS), water, and synovial fluid at 37 degrees C for up to 35 days. Bulk properties were analyzed with a fine ion beam microscope. Surface analyses by X-ray photoelectron spectroscopy and Auger electron spectroscopy showed surprisingly that synovial fluid produced a thin oxide/hydroxide layer. Release of ions into solution from the alloy also followed an unexpected pattern where synovial fluid, of all the samples, had the highest Cr concentration but the lowest Co concentration. The presence of carbide inclusions in the alloy did not affect the corrosion or the dissolution mechanisms, although the carbides were a significant feature on the metal surface. Only one mechanism was recognized as controlling the thickness of the oxide/hydroxide interface. The analysis of the dissolved metal showed two mechanisms at work: (1) a protein film caused ligand-induced dissolution, increasing the Cr concentration in synovial fluid, and was explained by the equilibrium constants; (2) corrosion at the interface increased the Co in PBS. The effect of prepassivating the samples (ASTM F-86-01) did not always have the desired effect of reducing dissolution. The release of Cr into PBS increased after prepassivation. The metal-synovial fluid interface did not contain calcium phosphate as a deposit, typically found where samples are exposed to calcium rich bodily fluids. (c) 2005 Wiley Periodicals, Inc.

A partially penalty immersed Crouzeix-Raviart finite element method for interface problems.

PubMed

An, Na; Yu, Xijun; Chen, Huanzhen; Huang, Chaobao; Liu, Zhongyan

2017-01-01

The elliptic equations with discontinuous coefficients are often used to describe the problems of the multiple materials or fluids with different densities or conductivities or diffusivities. In this paper we develop a partially penalty immersed finite element (PIFE) method on triangular grids for anisotropic flow models, in which the diffusion coefficient is a piecewise definite-positive matrix. The standard linear Crouzeix-Raviart type finite element space is used on non-interface elements and the piecewise linear Crouzeix-Raviart type immersed finite element (IFE) space is constructed on interface elements. The piecewise linear functions satisfying the interface jump conditions are uniquely determined by the integral averages on the edges as degrees of freedom. The PIFE scheme is given based on the symmetric, nonsymmetric or incomplete interior penalty discontinuous Galerkin formulation. The solvability of the method is proved and the optimal error estimates in the energy norm are obtained. Numerical experiments are presented to confirm our theoretical analysis and show that the newly developed PIFE method has optimal-order convergence in the [Formula: see text] norm as well. In addition, numerical examples also indicate that this method is valid for both the isotropic and the anisotropic elliptic interface problems.

Surfactant effects on contact line alteration of a liquid drop in a capillary tube

NASA Astrophysics Data System (ADS)

Yulianti, K.; Marwati, R.

2018-05-01

In this paper, the effect of an insoluble surfactant on the moving contact line of an interface between two fluids filling a capillary tube is studied. The governing equations are the incompressible Navier-Stokes equations with the couple of Eulerian fluid variables and Lagrangian interfacial markers. In our model, capillary force plays a role in the fluids motion. Here, we propose that besides lowering the interfacial tension which affects the capillary force, the surfactant also decreases the surface tension between fluids and a solid surface. That condition is applied to the unbalanced Young condition at the contact line. The front-tracking method is used to solve numerically the free boundary motion of the interface. Results show that the surfactant has a significant effect on the motion of the contact line.

The subscale orbital fluid transfer experiment

NASA Technical Reports Server (NTRS)

Meserole, J. S.; Collins, Frank G.; Jones, Ogden; Antar, Basil; Menzel, Reinhard; Gray, Perry

1995-01-01

The work during the present year consisted of examining concepts for visual observation of the fluid transfer process, examination of methods for accurately metering the amount of liquid transferred between the two tanks, examination of possible test fluids, and consideration of the materials to use for the elastomeric diaphragm. The objective of the visual observation is to locate the fluid-vapor interfaces and, if possible, quantify the amount of vapor and the area of the interface. It is proposed to use video cameras to view the overall process in each tank and to place borescopes or other devices through the tank walls to obtain detailed, undistorted views inside the tanks of critical portions of the transfer process. Further work will continue to find an economical means for providing this detailed view, which clearly would increase the data obtained from the experiment.

A soft porous drop in linear flows

NASA Astrophysics Data System (ADS)

Young, Yuan-Nan; Miksis, Michael; Mori, Yoichiro; Shelley, Michael

2017-11-01

The cellular cytoplasm consists a viscous fluid filled with fibrous networks that also have their own dynamics. Such fluid-structure interactions have been modeled as a soft porous material immersed in a viscous fluid. In this talk we focus on the hydrodynamics of a viscous drop filled with soft porous material inside. Suspended in a Stokes flow, such a porous viscous drop is allowed to deform, both the drop interface and the porous structures inside. Special focus is on the deformation dynamics of both the porosity and the shape of the drop under simple flows such as a uniform streaming flow and linear flows. We examine the effects of flow boundary conditions at interface between the porous drop and the surrounding viscous fluid. We also examine the dynamics of a porous drop with active stress from the porous network.

Surface capillary currents: Rediscovery of fluid-structure interaction by forced evolving boundary theory

NASA Astrophysics Data System (ADS)

Wang, Chunbai; Mitra, Ambar K.

2016-01-01

Any boundary surface evolving in viscous fluid is driven with surface capillary currents. By step function defined for the fluid-structure interface, surface currents are found near a flat wall in a logarithmic form. The general flat-plate boundary layer is demonstrated through the interface kinematics. The dynamics analysis elucidates the relationship of the surface currents with the adhering region as well as the no-slip boundary condition. The wall skin friction coefficient, displacement thickness, and the logarithmic velocity-defect law of the smooth flat-plate boundary-layer flow are derived with the advent of the forced evolving boundary method. This fundamental theory has wide applications in applied science and engineering.

Microfluidic hubs, systems, and methods for interface fluidic modules

DOEpatents

Bartsch, Michael S; Claudnic, Mark R; Kim, Hanyoup; Patel, Kamlesh D; Renzi, Ronald F; Van De Vreugde, James L

2015-01-27

Embodiments of microfluidic hubs and systems are described that may be used to connect fluidic modules. A space between surfaces may be set by fixtures described herein. In some examples a fixture may set substrate-to-substrate spacing based on a distance between registration surfaces on which the respective substrates rest. Fluidic interfaces are described, including examples where fluid conduits (e.g. capillaries) extend into the fixture to the space between surfaces. Droplets of fluid may be introduced to and/or removed from microfluidic hubs described herein, and fluid actuators may be used to move droplets within the space between surfaces. Continuous flow modules may be integrated with the hubs in some examples.

Comprehensive proteomic analysis of mineral nanoparticles derived from human body fluids and analyzed by liquid chromatography-tandem mass spectrometry.

PubMed

Martel, Jan; Young, David; Young, Andrew; Wu, Cheng-Yeu; Chen, Chi-De; Yu, Jau-Song; Young, John D

2011-11-01

Mineralo-protein nanoparticles (NPs) formed spontaneously in the body have been associated with ectopic calcifications seen in atherosclerosis, chronic degenerative diseases, and kidney stone formation. Synthetic NPs are also known to become coated with proteins when they come in contact with body fluids. Identifying the proteins found in NPs should help unravel how NPs are formed in the body and how NPs in general, be they synthetic or naturally formed, interact within the body. Here, we developed a proteomic approach based on liquid chromatography (LC) and tandem mass spectrometry (MS/MS) to determine the protein composition of carbonate-apatite NPs derived from human body fluids (serum, urine, cerebrospinal fluid, ascites, pleural effusion, and synovial fluid). LC-MS/MS provided not only an efficient and comprehensive determination of the protein constituents, but also a semiquantitative ranking of the identified proteins. Notably, the identified NP proteins mirrored the protein composition of the contacting body fluids, with albumin, fetuin-A, complement C3, α-1-antitrypsin, prothrombin, and apolipoproteins A1 and B-100 being consistently associated with the particles. Since several coagulation factors, calcification inhibitors, complement proteins, immune regulators, protease inhibitors, and lipid/molecule carriers can all become NP constituents, our results suggest that mineralo-protein complexes may interface with distinct biochemical pathways in the body depending on their protein composition. We propose that LC-MS/MS be used to characterize proteins found in both synthetic and natural NPs. Copyright © 2011 Elsevier Inc. All rights reserved.

Robust and general method for determining surface fluid flow boundary conditions in articular cartilage contact mechanics modeling.

PubMed

Pawaskar, Sainath Shrikant; Fisher, John; Jin, Zhongmin

2010-03-01

Contact detection in cartilage contact mechanics is an important feature of any analytical or computational modeling investigation when the biphasic nature of cartilage and the corresponding tribology are taken into account. The fluid flow boundary conditions will change based on whether the surface is in contact or not, which will affect the interstitial fluid pressurization. This in turn will increase or decrease the load sustained by the fluid phase, with a direct effect on friction, wear, and lubrication. In laboratory experiments or clinical hemiarthroplasty, when a rigid indenter or metallic prosthesis is used to apply load to the cartilage, there will not be any fluid flow normal to the surface in the contact region due to the impermeable nature of the indenter/prosthesis. In the natural joint, on the other hand, where two cartilage surfaces interact, flow will depend on the pressure difference across the interface. Furthermore, in both these cases, the fluid would flow freely in non-contacting regions. However, it should be pointed out that the contact area is generally unknown in advance in both cases and can only be determined as part of the solution. In the present finite element study, a general and robust algorithm was proposed to decide nodes in contact on the cartilage surface and, accordingly, impose the fluid flow boundary conditions. The algorithm was first tested for a rigid indenter against cartilage model. The algorithm worked well for two-dimensional four-noded and eight-noded axisymmetric element models as well as three-dimensional models. It was then extended to include two cartilages in contact. The results were in excellent agreement with the previous studies reported in the literature.

Software Tools for Stochastic Simulations of Turbulence

DTIC Science & Technology

2015-08-28

client interface to FTI. Specefic client programs using this interface include the weather forecasting code WRF ; the high energy physics code, FLASH...client programs using this interface include the weather forecasting code WRF ; the high energy physics code, FLASH; and two locally constructed fluid...45 4.4.2.2 FLASH . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 4.4.2.3 WRF

Indirect measurement of the solid/liquid interface using the minimization technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choi, H.; Chun, M.

1985-11-01

The phenomenon of solidification of a flowing fluid in a vertical tube is closely related to the relocation dynamics of molten nuclear fuels in hypothetical core-disruptive accidents of a liquid-metal fast breeder reactor. The knowledge of the transient shape and the position of the liquid/solid interface is of practical importance in analysis of phase change processes. Sparrow and Broadbent directly measured the solid liquid interface via experiments, whereas Viskanta observed the solid/liquid interface motion via a photographic method. In this paper, a new method to predict the transient position of the solid/liquid interface is developed. This method is based onmore » the minimization technique. To use this method one needs the temperature of the wall on which the phase change is to take place. The new technique is useful, in particular, for the case of inward solidification of a flowing fluid in a tube where direct measurement of the solid/liquid interface is not possible, whereas the tube wall temperature measurement is relatively easy.« less

Interfacial dilatational deformation accelerates particle formation in monoclonal antibody solutions.

PubMed

Lin, Gigi L; Pathak, Jai A; Kim, Dong Hyun; Carlson, Marcia; Riguero, Valeria; Kim, Yoen Joo; Buff, Jean S; Fuller, Gerald G

2016-04-14

Protein molecules are amphiphilic moieties that spontaneously adsorb at the air/solution (A/S) interface to lower the surface energy. Previous studies have shown that hydrodynamic disruptions to these A/S interfaces can result in the formation of protein aggregates that are of concern to the pharmaceutical industry. Interfacial hydrodynamic stresses encountered by protein therapeutic solutions under typical manufacturing, filling, and shipping conditions will impact protein stability, prompting a need to characterize the contribution of basic fluid kinematics to monoclonal antibody (mAb) destabilization. We demonstrate that dilatational surface deformations are more important to antibody stability when compared to constant-area shear of the A/S interface. We have constructed a dilatational interfacial rheometer that utilizes simultaneous pressure and bubble shape measurements to study the mechanical stability of mAbs under interfacial aging. It has a distinct advantage over methods utilizing the Young-Laplace equation, which incorrectly describes viscoelastic interfaces. We provide visual evidence of particle ejection from dilatated A/S interfaces and spectroscopic data of ejected mAb particles. These rheological studies frame a molecular understanding of the protein-protein interactions at the complex-fluid interface.

Charging and discharging of single colloidal particles at oil/water interfaces

PubMed Central

Gao, Peng; Xing, XiaoChen; Li, Ye; Ngai, To; Jin, Fan

2014-01-01

The physical behavior of solid colloids trapped at a fluid-fluid interface remains in itself an open fundamental issue. Here, we show that the gradients of surface tension can induce particles to jet towards the oil/water interface with velocities as high as ≈ 60 mm/s when particle suspensions come in contact with the interface. We hypothesize that rubbing between the particles and oil lead to the spontaneous accumulation of negative charges on the hemisphere of those interfacial particles that contact the oil phase by means of triboelectrification. The charging process is highly dependent on the sliding distances, and gives rise to long-ranged repulsions that protect interfacial particles from coagulating at the interface by the presence of electrolyte. These triboelectric charges, however, are compensated within several hours, which affect the stability of interfacial particles. Importantly, by charging different kinds of colloidal particles using various spreading solvents and dispersion methods, we have demonstrated that charging and discharging of single colloidal particles at oil/water interfaces impacts a broad range of dynamical behavior. PMID:24786477

Study of density distribution in a near-critical simple fluid (19-IML-1)

NASA Technical Reports Server (NTRS)

Michels, Teun

1992-01-01

This experiment uses visual observation, interferometry, and light scattering techniques to observe and analyze the density distribution in SF6 above and below the critical temperature. Below the critical temperature, the fluid system is split up into two coexisting phases, liquid and vapor. The spatial separation of these phases on earth, liquid below and vapor above, is not an intrinsic property of the fluid system; it is merely an effect of the action of the gravity field. At a fixed temperature, the density of each of the coexisting phases is in principle fixed. However, near T sub c where the fluid is strongly compressible, gravity induced hydrostatic forces will result in a gradual decrease in density with increasing height in the sample container. This hydrostatic density profile is even more pronounced in the one phase fluid at temperatures slightly above T sub c. The experiment is set up to study the intrinsic density distributions and equilibration rates of a critical sample in a small container. Interferometry will be used to determine local density and thickness of surface and interface layers. The light scattering data will reveal the size of the density fluctuations on a microscopic scale.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barbante, Paolo; Frezzotti, Aldo; Gibelli, Livio

The unsteady evaporation of a thin planar liquid film is studied by molecular dynamics simulations of Lennard-Jones fluid. The obtained results are compared with the predictions of a diffuse interface model in which capillary Korteweg contributions are added to hydrodynamic equations, in order to obtain a unified description of the liquid bulk, liquid-vapor interface and vapor region. Particular care has been taken in constructing a diffuse interface model matching the thermodynamic and transport properties of the Lennard-Jones fluid. The comparison of diffuse interface model and molecular dynamics results shows that, although good agreement is obtained in equilibrium conditions, remarkable deviationsmore » of diffuse interface model predictions from the reference molecular dynamics results are observed in the simulation of liquid film evaporation. It is also observed that molecular dynamics results are in good agreement with preliminary results obtained from a composite model which describes the liquid film by a standard hydrodynamic model and the vapor by the Boltzmann equation. The two mathematical model models are connected by kinetic boundary conditions assuming unit evaporation coefficient.« less

Universal emulsion stabilization from the arrested adsorption of rough particles at liquid-liquid interfaces

PubMed Central

Zanini, Michele; Marschelke, Claudia; Anachkov, Svetoslav E.; Marini, Emanuele; Synytska, Alla; Isa, Lucio

2017-01-01

Surface heterogeneities, including roughness, significantly affect the adsorption, motion and interactions of particles at fluid interfaces. However, a systematic experimental study, linking surface roughness to particle wettability at a microscopic level, is currently missing. Here we synthesize a library of all-silica microparticles with uniform surface chemistry, but tuneable surface roughness and study their spontaneous adsorption at oil–water interfaces. We demonstrate that surface roughness strongly pins the particles' contact lines and arrests their adsorption in long-lived metastable positions, and we directly measure the roughness-induced interface deformations around isolated particles. Pinning imparts tremendous contact angle hysteresis, which can practically invert the particle wettability for sufficient roughness, irrespective of their chemical nature. As a unique consequence, the same rough particles stabilize both water-in-oil and oil-in-water emulsions depending on the phase they are initially dispersed in. These results both shed light on fundamental phenomena concerning particle adsorption at fluid interfaces and indicate future design rules for particle-based emulsifiers. PMID:28589932

Films of Bacteria at Interfaces (FBI): Remodeling of Fluid Interfaces by Pseudomonas aeruginosa.

PubMed

Niepa, Tagbo H R; Vaccari, Liana; Leheny, Robert L; Goulian, Mark; Lee, Daeyeon; Stebe, Kathleen J

2017-12-19

Bacteria at fluid interfaces endure physical and chemical stresses unique to these highly asymmetric environments. The responses of Pseudomonas aeruginosa PAO1 and PA14 to a hexadecane-water interface are compared. PAO1 cells form elastic films of bacteria, excreted polysaccharides and proteins, whereas PA14 cells move actively without forming an elastic film. Studies of PAO1 mutants show that, unlike solid-supported biofilms, elastic interfacial film formation occurs in the absence of flagella, pili, or certain polysaccharides. Highly induced genes identified in transcriptional profiling include those for putative enzymes and a carbohydrate metabolism enzyme, alkB2; this latter gene is not upregulated in PA14 cells. Notably, PAO1 mutants lacking the alkB2 gene fail to form an elastic layer. Rather, they form an active film like that formed by PA14. These findings demonstrate that genetic expression is altered by interfacial confinement, and suggest that the ability to metabolize alkanes may play a role in elastic film formation at oil-water interfaces.

Pore-scale modeling of phase change in porous media

NASA Astrophysics Data System (ADS)

Juanes, Ruben; Cueto-Felgueroso, Luis; Fu, Xiaojing

2017-11-01

One of the main open challenges in pore-scale modeling is the direct simulation of flows involving multicomponent mixtures with complex phase behavior. Reservoir fluid mixtures are often described through cubic equations of state, which makes diffuse interface, or phase field theories, particularly appealing as a modeling framework. What is still unclear is whether equation-of-state-driven diffuse-interface models can adequately describe processes where surface tension and wetting phenomena play an important role. Here we present a diffuse interface model of single-component, two-phase flow (a van der Waals fluid) in a porous medium under different wetting conditions. We propose a simplified Darcy-Korteweg model that is appropriate to describe flow in a Hele-Shaw cell or a micromodel, with a gap-averaged velocity. We study the ability of the diffuse-interface model to capture capillary pressure and the dynamics of vaporization/condensation fronts, and show that the model reproduces pressure fluctuations that emerge from abrupt interface displacements (Haines jumps) and from the break-up of wetting films.

Universal emulsion stabilization from the arrested adsorption of rough particles at liquid-liquid interfaces

NASA Astrophysics Data System (ADS)

Zanini, Michele; Marschelke, Claudia; Anachkov, Svetoslav E.; Marini, Emanuele; Synytska, Alla; Isa, Lucio

2017-06-01

Surface heterogeneities, including roughness, significantly affect the adsorption, motion and interactions of particles at fluid interfaces. However, a systematic experimental study, linking surface roughness to particle wettability at a microscopic level, is currently missing. Here we synthesize a library of all-silica microparticles with uniform surface chemistry, but tuneable surface roughness and study their spontaneous adsorption at oil-water interfaces. We demonstrate that surface roughness strongly pins the particles' contact lines and arrests their adsorption in long-lived metastable positions, and we directly measure the roughness-induced interface deformations around isolated particles. Pinning imparts tremendous contact angle hysteresis, which can practically invert the particle wettability for sufficient roughness, irrespective of their chemical nature. As a unique consequence, the same rough particles stabilize both water-in-oil and oil-in-water emulsions depending on the phase they are initially dispersed in. These results both shed light on fundamental phenomena concerning particle adsorption at fluid interfaces and indicate future design rules for particle-based emulsifiers.

Competitive Adsorption between Nanoparticles and Surface Active Ions for the Oil-Water Interface.

PubMed

Hua, Xiaoqing; Bevan, Michael A; Frechette, Joelle

2018-04-24

Nanoparticles (NPs) can add functionality (e.g., catalytic, optical, rheological) to an oil-water interface. Adsorption of ∼10 nm NPs can be reversible; however, the mechanisms for adsorption and its effects on surface pressure remain poorly understood. Here we demonstrate how the competitive reversible adsorption of NPs and surfactants at fluid interfaces can lead to independent control of both the adsorbed amount and surface pressure. In contrast to prior work, both species investigated (NPs and surfactants) interact reversibly with the interface and without the surface active species binding to NPs. Independent measurements of the adsorption and surface pressure isotherms allow determination of the equation of state (EOS) of the interface under conditions where the NPs and surfactants are both in dynamic equilibrium with the bulk phase. The adsorption and surface pressure measurements are performed with gold NPs of two different sizes (5 and 10 nm), at two pH values, and across a wide concentration range of surfactant (tetrapentylammonium, TPeA + ) and NPs. We show that free surface active ions compete with NPs for the interface and give rise to larger surface pressures upon the adsorption of NPs. Through a competitive adsorption model, we decouple the contributions of NPs wetting at the interface and their surface activity on the measured surface pressure. We also demonstrate reversible control of adsorbed amount via changes in the surfactant concentration or the aqueous phase pH.

Exploring a multi-scale method for molecular simulation in continuum solvent model: Explicit simulation of continuum solvent as an incompressible fluid.

PubMed

Xiao, Li; Luo, Ray

2017-12-07

We explored a multi-scale algorithm for the Poisson-Boltzmann continuum solvent model for more robust simulations of biomolecules. In this method, the continuum solvent/solute interface is explicitly simulated with a numerical fluid dynamics procedure, which is tightly coupled to the solute molecular dynamics simulation. There are multiple benefits to adopt such a strategy as presented below. At this stage of the development, only nonelectrostatic interactions, i.e., van der Waals and hydrophobic interactions, are included in the algorithm to assess the quality of the solvent-solute interface generated by the new method. Nevertheless, numerical challenges exist in accurately interpolating the highly nonlinear van der Waals term when solving the finite-difference fluid dynamics equations. We were able to bypass the challenge rigorously by merging the van der Waals potential and pressure together when solving the fluid dynamics equations and by considering its contribution in the free-boundary condition analytically. The multi-scale simulation method was first validated by reproducing the solute-solvent interface of a single atom with analytical solution. Next, we performed the relaxation simulation of a restrained symmetrical monomer and observed a symmetrical solvent interface at equilibrium with detailed surface features resembling those found on the solvent excluded surface. Four typical small molecular complexes were then tested, both volume and force balancing analyses showing that these simple complexes can reach equilibrium within the simulation time window. Finally, we studied the quality of the multi-scale solute-solvent interfaces for the four tested dimer complexes and found that they agree well with the boundaries as sampled in the explicit water simulations.

Phase-field-based lattice Boltzmann model for incompressible binary fluid systems with density and viscosity contrasts.

PubMed

Zu, Y Q; He, S

2013-04-01

A lattice Boltzmann model (LBM) is proposed based on the phase-field theory to simulate incompressible binary fluids with density and viscosity contrasts. Unlike many existing diffuse interface models which are limited to density matched binary fluids, the proposed model is capable of dealing with binary fluids with moderate density ratios. A new strategy for projecting the phase field to the viscosity field is proposed on the basis of the continuity of viscosity flux. The new LBM utilizes two lattice Boltzmann equations (LBEs): one for the interface tracking and the other for solving the hydrodynamic properties. The LBE for interface tracking can recover the Chan-Hilliard equation without any additional terms; while the LBE for hydrodynamic properties can recover the exact form of the divergence-free incompressible Navier-Stokes equations avoiding spurious interfacial forces. A series of 2D and 3D benchmark tests have been conducted for validation, which include a rigid-body rotation, stationary and moving droplets, a spinodal decomposition, a buoyancy-driven bubbly flow, a layered Poiseuille flow, and the Rayleigh-Taylor instability. It is shown that the proposed method can track the interface with high accuracy and stability and can significantly and systematically reduce the parasitic current across the interface. Comparisons with momentum-based models indicate that the newly proposed velocity-based model can better satisfy the incompressible condition in the flow fields, and eliminate or reduce the velocity fluctuations in the higher-pressure-gradient region and, therefore, achieve a better numerical stability. In addition, the test of a layered Poiseuille flow demonstrates that the proposed scheme for mixture viscosity performs significantly better than the traditional mixture viscosity methods.

Determination of Critical Parameters Based on the Intensity of Transmitted Light Around Gas-Liquid Interface: Critical Parameters of CO

NASA Astrophysics Data System (ADS)

Nakayama, Masaki; Katano, Hiroaki; Sato, Haruki

2014-05-01

A precise determination of the critical temperature and density for technically important fluids would be possible on the basis of the digital image for the visual observation of the phase boundary in the vicinity of the critical point since the sensitivity and resolution are higher than those of naked eyes. In addition, the digital image can avoid the personal uncertainty of an observer. A strong density gradient occurs in a sample cell at the critical point due to gravity. It was carefully assessed to determine the critical density, where the density profile in the sample cell can be observed from the luminance profile of a digital image. The density-gradient profile becomes symmetric at the critical point. One of the best fluids, whose thermodynamic properties have been measured with the highest reliability among technically important fluids, would be carbon dioxide. In order to confirm the reliability of the proposed method, the critical temperature and density of carbon dioxide were determined using the digital image. The critical temperature and density values of carbon dioxide are ( and ( kg m, respectively. The critical temperature and density values agree with the existing best values within estimated uncertainties. The reliability of the method was confirmed. The critical pressure, 7.3795 MPa, corresponding to the determined critical temperature of 304.143 K is also proposed. A new set of parameters for the vapor-pressure equation is also provided.

Variations in fluid transport and seismogenic properties in the Lesser Antilles subduction zone: constraints from joint active-source and local earthquake tomography

NASA Astrophysics Data System (ADS)

Paulatto, M.; Laigle, M.; Charvis, P.; Galve, A.

2015-12-01

The degree of coupling and the seismogenic properties of the plate interface at subduction zones are affected by the abundance of slab fluids and subducted sediments. High fluid input can cause high pore-fluid pressures in the subduction channel and decrease coupling leading to aseismic behaviour. Constraining fluid input and transfer is therefore important for understanding plate coupling and large earthquake hazard, particularly in places where geodetic and seismological constraints are scarce. We use P-wave traveltimes from several active source seismic experiments and P- and S-wave traveltimes from shallow and intermediate depth (< 150 km) local earthquakes recorded on a vast amphibious array of OBSs and land stations to recover the Vp and Vp/Vs structure of the central Lesser Antilles subduction zone. Our model extends between Martinique and Antigua from the prism to the arc and from the surface to a depth of 160 km. We find low Vp and high Vp/Vs ratio (> 1.80) on the top of the slab, at depths of up to 100 km. We interpret this high Vp/Vs ratio anomaly as evidence of elevated fluid content either as free fluids or as bound fluids in hydrated minerals (e.g. serpentinite). The strength and depth extent of the anomaly varies strongly from south to north along the subduction zone and correlates with variations in forearc morphology and with sediment input constrained by multi-channel seismic reflection profiles. The anomaly is stronger and extends to greater depth in the south, offshore Martinique, where sediment input is elevated due to the vicinity of the Orinoco delta. The gently dipping forearc slope observed in this region may be the result of weak coupling of the plate interface. A high Vp/Vs ratio is also observed in the forearc likely indicating a fractured and water-saturated overriding plate. On the other hand the anomaly is weaker and shallower offshore Guadeloupe, where sediment input is low due to subduction of the Barracuda ridge. Here a strong plate coupling is likely responsible for uplifting the inner forearc and formation of the Karukera spur. We infer that variations in plate coupling modulated by slab fluid transport and release are a major factor in determining the distribution of seismic slip in the Lesser Antilles subduction zone.

How the gas hydrate system gives insight into subduction wedge dewatering processes in a zone of highly-oblique convergence on the southern Hikurangi margin of New Zealand

NASA Astrophysics Data System (ADS)

Crutchley, Gareth; Klaeschen, Dirk; Pecher, Ingo; Henrys, Stuart

2017-04-01

The southern end of New Zealand's Hikurangi subduction margin is characterised by highly-oblique convergence as it makes a southward transition into a right-lateral transform plate boundary at the Alpine Fault. Long-offset seismic data that cross part of the offshore portion of this transition zone give new insight into the nature of the plate boundary. We have carried out 2D pre-stack depth migrations, with an iterative reflection tomography to update the velocity field, on two seismic lines in this area to investigate fluid flow processes that have implications for the mechanical stability of the subduction interface. The results show distinct and focused fluid expulsion pathways from the subduction interface to the shallow sub-surface. For example, on one of the seismic lines there is a clear disruption of the gas hydrate system at its intersection with a splay fault - a clear indication of focused fluid release from the subduction interface. The seismic velocities derived from tomography also highlight a broad, pronounced low velocity zone beneath the deforming wedge that we interpret as a thick zone of gas-charged fluids that may have important implications for the long-term frictional stability of the plate boundary in this area. The focused flow upward toward the seafloor has the potential to result in the formation of concentrated gas hydrate deposits. Our on-going work on these data will include amplitude versus offset analysis in an attempt to better characterise the nature of the subduction interface, the fluids in that region, and also the shallower gas hydrate system.

Mobility Effect on Poroelastic Seismic Signatures in Partially Saturated Rocks With Applications in Time-Lapse Monitoring of a Heavy Oil Reservoir

NASA Astrophysics Data System (ADS)

Zhao, Luanxiao; Yuan, Hemin; Yang, Jingkang; Han, De-hua; Geng, Jianhua; Zhou, Rui; Li, Hui; Yao, Qiuliang

2017-11-01

Conventional seismic analysis in partially saturated rocks normally lays emphasis on estimating pore fluid content and saturation, typically ignoring the effect of mobility, which decides the ability of fluids moving in the porous rocks. Deformation resulting from a seismic wave in heterogeneous partially saturated media can cause pore fluid pressure relaxation at mesoscopic scale, thereby making the fluid mobility inherently associated with poroelastic reflectivity. For two typical gas-brine reservoir models, with the given rock and fluid properties, the numerical analysis suggests that variations of patchy fluid saturation, fluid compressibility contrast, and acoustic stiffness of rock frame collectively affect the seismic reflection dependence on mobility. In particular, the realistic compressibility contrast of fluid patches in shallow and deep reservoir environments plays an important role in determining the reflection sensitivity to mobility. We also use a time-lapse seismic data set from a Steam-Assisted Gravity Drainage producing heavy oil reservoir to demonstrate that mobility change coupled with patchy saturation possibly leads to seismic spectral energy shifting from the baseline to monitor line. Our workflow starts from performing seismic spectral analysis on the targeted reflectivity interface. Then, on the basis of mesoscopic fluid pressure diffusion between patches of steam and heavy oil, poroelastic reflectivity modeling is conducted to understand the shift of the central frequency toward low frequencies after the steam injection. The presented results open the possibility of monitoring mobility change of a partially saturated geological formation from dissipation-related seismic attributes.

Numerical Treatment of Stokes Solvent Flow and Solute-Solvent Interfacial Dynamics for Nonpolar Molecules.

PubMed

Sun, Hui; Zhou, Shenggao; Moore, David K; Cheng, Li-Tien; Li, Bo

2016-05-01

We design and implement numerical methods for the incompressible Stokes solvent flow and solute-solvent interface motion for nonpolar molecules in aqueous solvent. The balance of viscous force, surface tension, and van der Waals type dispersive force leads to a traction boundary condition on the solute-solvent interface. To allow the change of solute volume, we design special numerical boundary conditions on the boundary of a computational domain through a consistency condition. We use a finite difference ghost fluid scheme to discretize the Stokes equation with such boundary conditions. The method is tested to have a second-order accuracy. We combine this ghost fluid method with the level-set method to simulate the motion of the solute-solvent interface that is governed by the solvent fluid velocity. Numerical examples show that our method can predict accurately the blow up time for a test example of curvature flow and reproduce the polymodal (e.g., dry and wet) states of hydration of some simple model molecular systems.

Nonarteritic ischemic optic neuropathy secondary to severe ocular hypertension masked by interface fluid in a post-LASIK eye.

PubMed

Pham, Mai T; Peck, Rachel E; Dobbins, Kendall R B

2013-06-01

We report a case of ischemic optic neuropathy arising from elevated intraocular pressure (IOP) masked by interface fluid in a post-laser in situ keratomileusis (LASIK) eye. A 51-year-old man, who had had LASIK 6 years prior to presentation, sustained blunt trauma to the left eye that resulted in a hyphema and ocular hypertension. Elevated IOP resulted in accumulation of fluid in the stromal bed-LASIK flap interface, leading to underestimation of IOP when measured centrally over the flap. After days of unrecognized ocular hypertension, ischemic optic neuropathy developed. To our knowledge, this is the first reported case of ischemic optic neuropathy resulting from underestimated IOP measurements in a post-LASIK patient. It highlights the inaccuracy of IOP measurements in post-LASIK eyes and a vision-threatening potential complication. No author has a financial or proprietary interest in any material or method mentioned. Copyright © 2013 ASCRS and ESCRS. Published by Elsevier Inc. All rights reserved.

Fluid Force-Induced Detachment Criteria for Nonmetallic Inclusions Adhered to a Refractory/Molten Steel Interface

NASA Astrophysics Data System (ADS)

Dieguez Salgado, Uxia; Weiß, Christian; Michelic, Susanne K.; Bernhard, Christian

2018-05-01

Since nonmetallic inclusions (NMIs) in steel cannot be completely avoided, a greater understanding of their development and evolution during the steelmaking process is required. In particular, this includes the adhesion of microinclusions to the refractory/steel interface in the flow control system between the tundish and the mold. This phenomenon, commonly referred to as clogging, causes losses in productivity and product quality. Inclusions transported from the bulk melt to the boundary layer may adhere to the refractory/steel interface due to formation of a fluid cavity. A detailed model was derived for the detachment of NMIs adhering to a nozzle wall and is based on the local hydrodynamic conditions combined with the specific interfacial properties in the system consisting of the inclusions, the refractories, and the steel. The model is evaluated for three different application-oriented cases. This study has been focused on providing a better understanding of fluid flow in the near-wall region in order to reduce clogging during steelmaking.

Numerical Treatment of Stokes Solvent Flow and Solute-Solvent Interfacial Dynamics for Nonpolar Molecules

PubMed Central

Sun, Hui; Zhou, Shenggao; Moore, David K.; Cheng, Li-Tien; Li, Bo

2015-01-01

We design and implement numerical methods for the incompressible Stokes solvent flow and solute-solvent interface motion for nonpolar molecules in aqueous solvent. The balance of viscous force, surface tension, and van der Waals type dispersive force leads to a traction boundary condition on the solute-solvent interface. To allow the change of solute volume, we design special numerical boundary conditions on the boundary of a computational domain through a consistency condition. We use a finite difference ghost fluid scheme to discretize the Stokes equation with such boundary conditions. The method is tested to have a second-order accuracy. We combine this ghost fluid method with the level-set method to simulate the motion of the solute-solvent interface that is governed by the solvent fluid velocity. Numerical examples show that our method can predict accurately the blow up time for a test example of curvature flow and reproduce the polymodal (e.g., dry and wet) states of hydration of some simple model molecular systems. PMID:27365866

A Software Upgrade of the NASA Aeroheating Code "MINIVER"

NASA Technical Reports Server (NTRS)

Louderback, Pierce Mathew

2013-01-01

Computational Fluid Dynamics (CFD) is a powerful and versatile tool simulating fluid and thermal environments of launch and re-entry vehicles alike. Where it excels in power and accuracy, however, it lacks in speed. An alternative tool for this purpose is known as MINIVER, an aeroheating code widely used by NASA and within the aerospace industry. Capable of providing swift, reasonably accurate approximations of the fluid and thermal environment of launch vehicles, MINIVER is used where time is of the essence and accuracy need not be exact. However, MINIVER is an old, aging tool: running on a user-unfriendly, legacy command-line interface, it is difficult for it to keep pace with more modem software tools. Florida Institute of Technology was tasked with the construction of a new Graphical User Interface (GUI) that implemented the legacy version's capabilities and enhanced them with new tools and utilities. This thesis provides background to the legacy version of the program, the progression and final version of a modem user interface, and benchmarks to demonstrate its usefulness.

A monotonicity preserving conservative sharp interface flow solver for high density ratio two-phase flows

DOE Office of Scientific and Technical Information (OSTI.GOV)

Le Chenadec, Vincent, E-mail: vlechena@stanford.edu; Pitsch, Heinz; Institute for Combustion Technology, RWTH Aachen, Templergraben 64, 52056 Aachen

2013-09-15

This paper presents a novel approach for solving the conservative form of the incompressible two-phase Navier–Stokes equations. In order to overcome the numerical instability induced by the potentially large density ratio encountered across the interface, the proposed method includes a Volume-of-Fluid type integration of the convective momentum transport, a monotonicity preserving momentum rescaling, and a consistent and conservative Ghost Fluid projection that includes surface tension effects. The numerical dissipation inherent in the Volume-of-Fluid treatment of the convective transport is localized in the interface vicinity, enabling the use of a kinetic energy conserving discretization away from the singularity. Two- and three-dimensionalmore » tests are presented, and the solutions shown to remain accurate at arbitrary density ratios. The proposed method is then successfully used to perform the detailed simulation of a round water jet emerging in quiescent air, therefore suggesting the applicability of the proposed algorithm to the computation of realistic turbulent atomization.« less

Active microrheology and simultaneous visualization of sheared phospholipid monolayers

PubMed Central

Choi, S.Q.; Steltenkamp, S.; Zasadzinski, J.A.; Squires, T.M.

2011-01-01

Two-dimensional films of surface-active agents—from phospholipids and proteins to nanoparticles and colloids—stabilize fluid interfaces, which are essential to the science, technology and engineering of everyday life. The 2D nature of interfaces present unique challenges and opportunities: coupling between the 2D films and the bulk fluids complicates the measurement of surface dynamic properties, but allows the interfacial microstructure to be directly visualized during deformation. Here we present a novel technique that combines active microrheology with fluorescence microscopy to visualize fluid interfaces as they deform under applied stress, allowing structure and rheology to be correlated on the micron-scale in monolayer films. We show that even simple, single-component lipid monolayers can exhibit viscoelasticity, history dependence, a yield stress and hours-long time scales for elastic recoil and aging. Simultaneous visualization of the monolayer under stress shows that the rich dynamical response results from the cooperative dynamics and deformation of liquid-crystalline domains and their boundaries. PMID:21587229

Establishing mesh topology in multi-material cells: enabling technology for robust and accurate multi-material simulations

DOE PAGES

Kikinzon, Evgeny; Shashkov, Mikhail Jurievich; Garimella, Rao Veerabhadra

2018-05-29

Real world problems are typically multi-material, combining materials such as gases, liquids and solids that have very different properties. The material interfaces may be fixed in time or can be a part of the solution, as in fluid-structure interactions or air-water dynamics, and therefore move and change shape. In such problems the computational mesh may be non-conformal to interfaces due to complexity of these interfaces, presence of small fractions of materials, or because the mesh does not move with the flow, as in the arbitrary Lagrangian–Eulerian (ALE) methods. In order to solve problems of interest on such meshes, interface reconstructionmore » methods are usually used to recover an approximation of material regions within the cells. For a cell intersecting multiple material regions, these approximations of contained subregions can be considered as single-material subcells in a local mesh that we call a minimesh. In this paper, we discuss some of the requirements that discretization methods have on topological information in the resulting hierarchical meshes and present an approach that allows incorporating the buildup of sufficiently detailed topology into the nested dissections based PLIC-type reconstruction algorithms (e.g. Volume-of-Fluid, Moment-of-Fluid) in an efficient and robust manner. Specifically, we describe the X-MOF interface reconstruction algorithm in 2D, which extends the Moment-Of-Fluid (MOF) method to include the topology of minimeshes created inside of multi-material cells and parent-child relations between corresponding mesh entities on different hierarchy levels. X-MOF retains the property of being local to a cell and not requiring external communication, which makes it suitable for massively parallel applications. Here, we demonstrate some scaling results for the X-MOF implementation in Tangram, a modern interface reconstruction framework for exascale computing.« less

Interface fluid syndrome in human eye bank corneas after LASIK: causes and pathogenesis.

PubMed

Dawson, Daniel G; Schmack, Ingo; Holley, Glenn P; Waring, George O; Grossniklaus, Hans E; Edelhauser, Henry F

2007-10-01

To evaluate the effects of corneal edema on human donor corneas that had previous LASIK using a laboratory model with histologic and ultrastructural correlations. Experimental study. Thirty human eye bank corneas from 15 donors (mean age +/- standard deviation, 49.9+/-8.9 years) who had had previous LASIK surgery (2-8 years before death). The corneas were mounted in an artificial anterior chamber and the corneal endothelium was perfused for up to 5.0 hours with 0.9% saline solution (endothelial cell damage group) or BSS Plus at a pressure of 15 mmHg (control group), or BSS Plus at a pressure of 55 mmHg (high-pressure group). The corneas were evaluated by confocal and specular microscopy before, during, and at the end of the experimental period. Subsequently, the specimens were evaluated by light and electron microscopy. Corneal thickness, reflectivity, histology, and ultrastructure. Endothelial cell damage resulted in an increased (141.5+/-38.8 microm) total corneal thickness relative to controls (52.3+/-33.7 microm), whereas high pressure resulted in a decreased thickness (24.8+/-14.1 microm) relative to controls. This ultimately was due to swelling of the LASIK interface in both groups and swelling of the residual stromal bed (RSB) in the endothelial cell damage group or compression of the RSB and, possibly, the flap in the high-pressure group. A significant increase in corneal reflectivity at the LASIK interface occurred in both groups, primarily due to varying degrees of fluid accumulation and associated hydropic keratocyte degeneration, as well as increased corneal reflectivity in the RSB only in the endothelial cell damage group. After LASIK surgery, edematous corneas preferentially hydrate and swell in the paracentral and central interface wound, commonly resulting in a hazy corneal appearance primarily due to keratocyte hydropic degeneration. More severe corneal edema is characterized by the formation of an optically empty space corresponding to an interface fluid pocket. The spectrum of interface fluid syndrome can be described in 3 stages.

Establishing mesh topology in multi-material cells: enabling technology for robust and accurate multi-material simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kikinzon, Evgeny; Shashkov, Mikhail Jurievich; Garimella, Rao Veerabhadra

Real world problems are typically multi-material, combining materials such as gases, liquids and solids that have very different properties. The material interfaces may be fixed in time or can be a part of the solution, as in fluid-structure interactions or air-water dynamics, and therefore move and change shape. In such problems the computational mesh may be non-conformal to interfaces due to complexity of these interfaces, presence of small fractions of materials, or because the mesh does not move with the flow, as in the arbitrary Lagrangian–Eulerian (ALE) methods. In order to solve problems of interest on such meshes, interface reconstructionmore » methods are usually used to recover an approximation of material regions within the cells. For a cell intersecting multiple material regions, these approximations of contained subregions can be considered as single-material subcells in a local mesh that we call a minimesh. In this paper, we discuss some of the requirements that discretization methods have on topological information in the resulting hierarchical meshes and present an approach that allows incorporating the buildup of sufficiently detailed topology into the nested dissections based PLIC-type reconstruction algorithms (e.g. Volume-of-Fluid, Moment-of-Fluid) in an efficient and robust manner. Specifically, we describe the X-MOF interface reconstruction algorithm in 2D, which extends the Moment-Of-Fluid (MOF) method to include the topology of minimeshes created inside of multi-material cells and parent-child relations between corresponding mesh entities on different hierarchy levels. X-MOF retains the property of being local to a cell and not requiring external communication, which makes it suitable for massively parallel applications. Here, we demonstrate some scaling results for the X-MOF implementation in Tangram, a modern interface reconstruction framework for exascale computing.« less

Recent experimental advances on hydrophobic interactions at solid/water and fluid/water interfaces.

PubMed

Zeng, Hongbo; Shi, Chen; Huang, Jun; Li, Lin; Liu, Guangyi; Zhong, Hong

2015-03-15

Hydrophobic effects play important roles in a wide range of natural phenomena and engineering processes such as coalescence of oil droplets in water, air flotation of mineral particles, and folding and assembly of proteins and biomembranes. In this work, the authors highlight recent experimental attempts to reveal the physical origin of hydrophobic effects by directly quantifying the hydrophobic interaction on both solid/water and fluid/water interfaces using state-of-art nanomechanical techniques such as surface forces apparatus and atomic force microscopy (AFM). For solid hydrophobic surfaces of different hydrophobicity, the range of hydrophobic interaction was reported to vary from ∼10 to >100 nm. With various characterization techniques, the very long-ranged attraction (>100 nm) has been demonstrated to be mainly attributed to nonhydrophobic interaction mechanisms such as pre-existing nanobubbles and molecular rearrangement. By ruling out these factors, intrinsic hydrophobic interaction was measured to follow an exponential law with decay length of 1-2 nm with effective range less than 20 nm. On the other hand, hydrophobic interaction measured at fluid interfaces using AFM droplet/bubble probe technique was found to decay with a much shorter length of ∼0.3 nm. This discrepancy of measured decay lengths is proposed to be attributed to inherent physical distinction between solid and fluid interfaces, which impacts the structure of interface-adjacent water molecules. Direct measurement of hydrophobic interaction on a broader range of interfaces and characterization of interfacial water molecular structure using spectroscopic techniques are anticipated to help unravel the origin of this rigidity-related mismatch of hydrophobic interaction and hold promise to uncover the physical nature of hydrophobic effects. With improved understanding of hydrophobic interaction, intrinsic interaction mechanisms of many biological and chemical pathways can be better elucidated, and novel devices/processes can be developed with capacity to modulate and control the hydrophobic effects from the molecular to the macroscopic scale.

Simulation of two-phase flow in horizontal fracture networks with numerical manifold method

NASA Astrophysics Data System (ADS)

Ma, G. W.; Wang, H. D.; Fan, L. F.; Wang, B.

2017-10-01

The paper presents simulation of two-phase flow in discrete fracture networks with numerical manifold method (NMM). Each phase of fluids is considered to be confined within the assumed discrete interfaces in the present method. The homogeneous model is modified to approach the mixed fluids. A new mathematical cover formation for fracture intersection is proposed to satisfy the mass conservation. NMM simulations of two-phase flow in a single fracture, intersection, and fracture network are illustrated graphically and validated by the analytical method or the finite element method. Results show that the motion status of discrete interface significantly depends on the ratio of mobility of two fluids rather than the value of the mobility. The variation of fluid velocity in each fracture segment and the driven fluid content are also influenced by the ratio of mobility. The advantages of NMM in the simulation of two-phase flow in a fracture network are demonstrated in the present study, which can be further developed for practical engineering applications.

Thermal Marangoni convection in two-phase flow of dusty Casson fluid

NASA Astrophysics Data System (ADS)

Mahanthesh, B.; Gireesha, B. J.

2018-03-01

This paper deals with the thermal Marangoni convection effects in magneto-Casson liquid flow through suspension of dust particles. The transpiration cooling aspect is accounted. The surface tension is assumed to be fluctuating linearly with temperature. The fluid and dust particle's temperature of the interface is chosen as a quadratic function of interface arc length. The governing problem is modelled by conservation laws of mass, momentum and energy for fluid and dust particle phase. Stretching transformation technique is utilized to form ordinary differential equations from the partial differential equations. Later, the numerical solutions based on Runge-Kutta-Fehlberg method are established. The momentum and heat transport distributions are focused on the outcome of distinct governing parameters. The results of Nusselt number is also presented and discussed. It is established that the heat transfer rate is higher in the case of dusty non-Newtonian fluid than dusty Newtonian fluid. The rate of heat transfer can be enhanced by suspending dust particles in a base liquid.

The behavior of surface tension on steady-state rotating fluids in the low gravity environments

NASA Technical Reports Server (NTRS)

Hung, R. J.; Leslie, Fred W.

1987-01-01

The effect of surface tension on steady-state rotating fluids in a low gravity environment is studied. All the values of the physical parameters used in these calculations, except in the low gravity environments, are based on the measurements carried out by Leslie (1985) in the low gravity environment of a free-falling aircraft. The profile of the interface of two fluids is derived from Laplace's equation relating the pressure drop across an interface to the radii of curvature which has been applied to a low gravity rotating bubble that contacts the container boundary. The interface shape depends on the ratio of gravity to surface tension forces, the ratio of centrifugal to surface tension forces, the contact radius of the interface to the boundary, and the contact angle. The shape of the bubble is symmetric about its equator in a zero-gravity environment. This symmetry disappears and gradually shifts to parabolic profiles as the gravity environment becomes non-zero. The location of the maximum radius of the bubble moves upward from the center of the depth toward the top boundary of the cylinder as gravity increases. The contact radius of interface to the boundary r0 at the top side of cylinder increases and r0 at the bottom side of the cylinder decreases as the gravity environment increases from zero to 1 g.

Carbon Mobility at Subduction Interfaces via Deformation-Enhanced Fluid Infiltration: Evidence from the Swiss/Italian Alps

NASA Astrophysics Data System (ADS)

Jaeckel, K. P.; Bebout, G. E.; Angiboust, S.

2016-12-01

The interplay between fluid flow and deformation along subduction interfaces, and the extent to which deformation-enhanced fluid infiltration can drive decarbonation and carbonate dissolution, remain poorly understood. Recent work on HP/UHP decarbonation in W. Alps suites has indicated that, in intact volumes of metasediment, metabasalt, and ophicarbonate away from major shear zones and with few veins, carbonate is largely retained to 80-90 km depths (Cook-Kollars et al., 2014; Collins et al., 2015; Chem. Geol.). Yet uncertain is whether forearc fluid infiltration focused in intensely sheared and fractured zones could result in greater mobilization of C from subducting sections, in quantities sufficient to impact subduction zone C cycling. Lower-plate rocks at Arosa and Dent Blanche interface exposures (Bachmann et al., 2009, JGR; Angiboust et al., 2015, G3) are primarily calc-schist intercalated with meta-ultramafic and metamafic schist and contain carbonate-bearing veins of varying abundance and texture. At some localities, these sections contain blocks of carbonate, metabasalt, and upper-plate gneiss. Strongly deformed veins concordant with the foliation parallel to the thrust interface commonly contain carbonate and quartz. In highly sheared regions in the Arosa Zone, δ18O(VSMOW) values of some host-rocks and veins are shifted from +20 ± 2‰, values observed regionally for the Schistes Lustres, to values of +11 to +13‰. These shifts can be explained by interaction with externally-derived H2O-rich fluids with δ18O of +9 to +11‰. Smaller datasets for Dent Blanche localities hint at similar δ18O shifts. Most of these rocks contain little evidence of C release by decarbonation reactions. Evidence exists for local-scale dissolution of carbonate, during pressure solution, and carbonate-bearing veins reflect C mobility in fluids. Ongoing work assesses whether volumes of carbonate removed in some regions balance with those precipitated nearby in veins and pressure shadows.

Simulation of Two-Fluid Flows by the Least-Squares Finite Element Method Using a Continuum Surface Tension Model

NASA Technical Reports Server (NTRS)

Wu, Jie; Yu, Sheng-Tao; Jiang, Bo-nan

1996-01-01

In this paper a numerical procedure for simulating two-fluid flows is presented. This procedure is based on the Volume of Fluid (VOF) method proposed by Hirt and Nichols and the continuum surface force (CSF) model developed by Brackbill, et al. In the VOF method fluids of different properties are identified through the use of a continuous field variable (color function). The color function assigns a unique constant (color) to each fluid. The interfaces between different fluids are distinct due to sharp gradients of the color function. The evolution of the interfaces is captured by solving the convective equation of the color function. The CSF model is used as a means to treat surface tension effect at the interfaces. Here a modified version of the CSF model, proposed by Jacqmin, is used to calculate the tension force. In the modified version, the force term is obtained by calculating the divergence of a stress tensor defined by the gradient of the color function. In its analytical form, this stress formulation is equivalent to the original CSF model. Numerically, however, the use of the stress formulation has some advantages over the original CSF model, as it bypasses the difficulty in approximating the curvatures of the interfaces. The least-squares finite element method (LSFEM) is used to discretize the governing equation systems. The LSFEM has proven to be effective in solving incompressible Navier-Stokes equations and pure convection equations, making it an ideal candidate for the present applications. The LSFEM handles all the equations in a unified manner without any additional special treatment such as upwinding or artificial dissipation. Various bench mark tests have been carried out for both two dimensional planar and axisymmetric flows, including a dam breaking, oscillating and stationary bubbles and a conical liquid sheet in a pressure swirl atomizer.

Residual stress at fluid interfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murray, P.E.

We extend the Navier-Stokes equations to allow for residual stress in Newtonian fluids. A fluid, which undergoes a constrained volume change, will have residual stress. Corresponding to every constrained volume change is an eigenstrain. We present a method to include in the equations of fluid motion the eigenstrain that is a result of the presence in a fluid of a soluble chemical species. This method is used to calculate the residual stress associated with a chemical transformation. 9 refs., 1 fig.

Soft particles at fluid interfaces: wetting, structure, and rheology

NASA Astrophysics Data System (ADS)

Isa, Lucio

Most of our current knowledge concerning the behavior of colloidal particles at fluid interfaces is limited to model spherical, hard and uniform objects. Introducing additional complexity, in terms of shape, composition or surface chemistry or by introducing particle softness, opens up a vast range of possibilities to address new fundamental and applied questions in soft matter systems at fluid interfaces. In this talk I will focus on the role of particle softness, taking the case of core-shell microgels as a paradigmatic example. Microgels are highly swollen and cross-linked hydrogel particles that, in parallel with their practical applications, e.g. for emulsion stabilization and surface patterning, are increasingly used as model systems to capture fundamental properties of bulk materials. Most microgel particles develop a core-shell morphology during synthesis, with a more cross-linked core surrounded by a corona of loosely linked and dangling polymer chains. I will first discuss the difference between the wetting of a hard spherical colloid and a core-shell microgel at an oil-water interface, pinpointing the interplay between adsorption at the interface and particle deformation. I will then move on to discuss the interplay between particle morphology and the microstructure and rheological properties of the interface. In particular, I will demonstrate that synchronizing the compression of a core-shell microgel-laden fluid interface with the deposition of the interfacial monolayer makes it possible to transfer the 2D phase diagram of the particles onto a solid substrate, where different positions correspond to different values of the surface pressure and the specific area. Using atomic force microscopy, we analyzed the microstructure of the monolayer and discovered a phase transition between two crystalline phases with the same hexagonal symmetry, but with two different lattice constants. The two phases correspond to shell-shell or core-core inter-particle contacts, respectively, where with increasing surface pressure the former mechanically fail enabling the particle cores to come into contact. In the phase-transition region, clusters of particles in core-core contacts nucleate, melting the surrounding shell-shell crystal, until the whole monolayer moves into the second phase. We furthermore extended our analysis to measure the interfacial rheology of the monolayers as a function of the surface pressure using an interfacial microdisk rheometer; the interfaces always show a strong elastic response, with a dip in the elastic modulus in correspondence of the melting of the shell-shell phase, followed by a steep increase upon formation of a percolating network of the core-core contacts. The presented results highlight the complex interplay between the wetting and deformation of individual soft particles at fluid interfaces and the overall interface microstructure and mechanics. They show strong connections to fundamental studies on phase transitions in two-dimensional systems and pave the way for novel nanoscale surface patterning routes. The author acknowledges financial support from the Swiss National Science Foundation Grant PP00P2-144646/1.

Infectious Prions in the Pregnancy Microenvironment of Chronic Wasting Disease-Infected Reeves' Muntjac Deer

PubMed Central

Nalls, Amy V.; McNulty, Erin; Hoover, Clare E.; Pulscher, Laura A.; Hoover, Edward A.

2017-01-01

ABSTRACT Ample evidence exists for the presence of infectious agents at the maternal-fetal interface, often with grave outcomes to the developing fetus (i.e., Zika virus, brucella, cytomegalovirus, and toxoplasma). While less studied, pregnancy-related transmissible spongiform encephalopathies (TSEs) have been implicated in several species, including humans. Our previous work has shown that prions can be transferred from mother to offspring, resulting in the development of clinical TSE disease in offspring born to muntjac dams infected with chronic wasting disease (CWD) (1). We further demonstrated protein misfolding cyclic amplification (PMCA)-competent prions within the female reproductive tract and in fetal tissues harvested from CWD experimentally and naturally exposed cervids (1, 2). To assess whether the PMCA-competent prions residing at the maternal-fetal interface were infectious and to determine if the real-time quaking-induced conversion (RT-QuIC) methodology may enhance our ability to detect amyloid fibrils within the pregnancy microenvironment, we employed a mouse bioassay and RT-QuIC. In this study, we have demonstrated RT-QuIC seeding activity in uterus, placentome, ovary, and amniotic fluid but not in allantoic fluids harvested from CWD-infected Reeves' muntjac dams showing clinical signs of infection (clinically CWD-infected) and in some placentomes from pre-clinically CWD-infected dams. Prion infectivity was confirmed within the uterus, amniotic fluid, and the placentome, the semipermeable interface that sustains the developing fetus, of CWD-infected dams. This is the first report of prion infectivity within the cervid pregnancy microenvironment, revealing a source of fetal CWD exposure prior to the birthing process, maternal grooming, or encounters with contaminated environments. IMPORTANCE The facile dissemination of chronic wasting disease within captive and free-range cervid populations has led to questions regarding the transmission dynamics of this disease. Direct contact with infected animals and indirect contact with infectious prions in bodily fluids and contaminated environments are suspected to explain the majority of this transmission. A third mode of transmission, from mother to offspring, may be underappreciated. The presence of pregnancy-related prion infectivity within the uterus, amniotic fluid, and the placental structure reveals that the developing fetus is exposed to a source of prions long before exposure to the infectious agent during and after the birthing process or via contact with contaminated environments. These findings have impact on our current concept of CWD disease transmission. PMID:28539446

A new limiting procedure for discontinuous Galerkin methods applied to compressible multiphase flows with shocks and interfaces

NASA Astrophysics Data System (ADS)

Henry de Frahan, Marc T.; Varadan, Sreenivas; Johnsen, Eric

2015-01-01

Although the Discontinuous Galerkin (DG) method has seen widespread use for compressible flow problems in a single fluid with constant material properties, it has yet to be implemented in a consistent fashion for compressible multiphase flows with shocks and interfaces. Specifically, it is challenging to design a scheme that meets the following requirements: conservation, high-order accuracy in smooth regions and non-oscillatory behavior at discontinuities (in particular, material interfaces). Following the interface-capturing approach of Abgrall [1], we model flows of multiple fluid components or phases using a single equation of state with variable material properties; discontinuities in these properties correspond to interfaces. To represent compressible phenomena in solids, liquids, and gases, we present our analysis for equations of state belonging to the Mie-Grüneisen family. Within the DG framework, we propose a conservative, high-order accurate, and non-oscillatory limiting procedure, verified with simple multifluid and multiphase problems. We show analytically that two key elements are required to prevent spurious pressure oscillations at interfaces and maintain conservation: (i) the transport equation(s) describing the material properties must be solved in a non-conservative weak form, and (ii) the suitable variables must be limited (density, momentum, pressure, and appropriate properties entering the equation of state), coupled with a consistent reconstruction of the energy. Further, we introduce a physics-based discontinuity sensor to apply limiting in a solution-adaptive fashion. We verify this approach with one- and two-dimensional problems with shocks and interfaces, including high pressure and density ratios, for fluids obeying different equations of state to illustrate the robustness and versatility of the method. The algorithm is implemented on parallel graphics processing units (GPU) to achieve high speedup.

Helium microwave-induced plasmas for element specific detection in chromatography

NASA Astrophysics Data System (ADS)

Long, Gary L.; Ducatte, Gerald R.; Lancaster, Edwin D.

1994-01-01

This review addresses the development and use of the microwave-induced plasma (MIP) using optical emission spectrometry for the purpose of element specific detection in chromatography. The plasma source that is the focus of this article is the He-based MIP operated at atmospheric pressure. The forms of chromatography that are covered include gas chromatography, liquid chromatography, and supercritical fluid chromatography. Concepts in plasma cavity design and the chromatograph-plasma interface are discussed along with the application of these hybrid systems to analytical determinations.

Blistering of Graphite/Polymer Composites Galvanically Coupled with Metals in Sea Water

DTIC Science & Technology

1993-01-01

pressure Vi = molar volume of species T Yi = activity coefficient for species T (p = electrical potential Using the flux definition, the conservation...at = aJi/ax ...(11) (b) determine the rate of volume increase of water Vw’ cm3 1s in the blister cavity by the following expression: Vw’ = iVw/at = 1a...induced in the polymer and the fiber/matrix interface region due to the above volume change: The volume increase of the fluid in blister given by

A well-posed numerical method to track isolated conformal map singularities in Hele-Shaw flow

NASA Technical Reports Server (NTRS)

Baker, Gregory; Siegel, Michael; Tanveer, Saleh

1995-01-01

We present a new numerical method for calculating an evolving 2D Hele-Shaw interface when surface tension effects are neglected. In the case where the flow is directed from the less viscous fluid into the more viscous fluid, the motion of the interface is ill-posed; small deviations in the initial condition will produce significant changes in the ensuing motion. This situation is disastrous for numerical computation, as small round-off errors can quickly lead to large inaccuracies in the computed solution. Our method of computation is most easily formulated using a conformal map from the fluid domain into a unit disk. The method relies on analytically continuing the initial data and equations of motion into the region exterior to the disk, where the evolution problem becomes well-posed. The equations are then numerically solved in the extended domain. The presence of singularities in the conformal map outside of the disk introduces specific structures along the fluid interface. Our method can explicitly track the location of isolated pole and branch point singularities, allowing us to draw connections between the development of interfacial patterns and the motion of singularities as they approach the unit disk. In particular, we are able to relate physical features such as finger shape, side-branch formation, and competition between fingers to the nature and location of the singularities. The usefulness of this method in studying the formation of topological singularities (self-intersections of the interface) is also pointed out.

Development of a coupled level set and immersed boundary method for predicting dam break flows

NASA Astrophysics Data System (ADS)

Yu, C. H.; Sheu, Tony W. H.

2017-12-01

Dam-break flow over an immersed stationary object is investigated using a coupled level set (LS)/immersed boundary (IB) method developed in Cartesian grids. This approach adopts an improved interface preserving level set method which includes three solution steps and the differential-based interpolation immersed boundary method to treat fluid-fluid and solid-fluid interfaces, respectively. In the first step of this level set method, the level set function ϕ is advected by a pure advection equation. The intermediate step is performed to obtain a new level set value through a new smoothed Heaviside function. In the final solution step, a mass correction term is added to the re-initialization equation to ensure the new level set is a distance function and to conserve the mass bounded by the interface. For accurately calculating the level set value, the four-point upwinding combined compact difference (UCCD) scheme with three-point boundary combined compact difference scheme is applied to approximate the first-order derivative term shown in the level set equation. For the immersed boundary method, application of the artificial momentum forcing term at points in cells consisting of both fluid and solid allows an imposition of velocity condition to account for the presence of solid object. The incompressible Navier-Stokes solutions are calculated using the projection method. Numerical results show that the coupled LS/IB method can not only predict interface accurately but also preserve the mass conservation excellently for the dam-break flow.

Partial coalescence of drops at liquid interfaces

NASA Astrophysics Data System (ADS)

Blanchette, François; Bigioni, Terry P.

2006-04-01

When two separate masses of the same fluid are brought gently into contact, they are expected to fully merge into a single larger mass to minimize surface energy. However, when a stationary drop coalesces with an underlying reservoir of identical fluid, merging does not always proceed to completion. Occasionally, a drop in the process of merging apparently defies surface tension by `pinching off' before total coalescence occurs, leaving behind a smaller daughter droplet. Moreover, this process can repeat itself for subsequent generations of daughter droplets, resulting in a cascade of self-similar events. Such partial coalescence behaviour has implications for the dynamics of a variety of systems, including the droplets in clouds, ocean mist and airborne salt particles, emulsions, and the generation of vortices near an interface. Although it was first observed almost half a century ago, little is known about its precise mechanism. Here, we combine high-speed video imaging with numerical simulations to determine the conditions under which partial coalescence occurs, and to reveal a dynamic pinch-off mechanism. This mechanism is critically dependent on the ability of capillary waves to vertically stretch the drop by focusing energy on its summit.

Replacement processes in crystalline rocks

NASA Astrophysics Data System (ADS)

John, Timm; Putnis, Andrew

2010-05-01

A substantial question in metamorphism is what is the mechanism that dominates the conversion of one mineral assemblage to another in response to a change in the ambient physical and/or chemical conditions. Petrological, microstructural, and isotopic data indicate that aqueous fluids must be involved even in the reequilibration of large-scale systems. Fluid-mineral reactions take place by dissolution - precipitation processes, but converting one solid rock to another requires pervasive, either dominantly advective or diffusive fluid-mediated transport through the entire rock. The generation of reaction-induced porosity and the spatial and temporal coupling of dissolution and precipitation can account for fluid and element transport through rocks and the replacement of one mineral assemblage by another. To determine the mechanism of metamorphic reactions we refer to examples of interfaces and reaction textures which contain both the "before" (precursor) and "after" mineral assemblages - case studies where the process of conversion is frozen in. We will illustrate some aspects of the role of fluids in metamorphic reactions and discuss how reactive fluids can pervasively infiltrate a rock. The examples we will use are focussed on crystalline rocks and include reactions from the lower continental crust, the subducting oceanic crust, and the continental upper crust to show that except at very high-temperature conditions, essentially the same mechanisms are responsible for converting rocks to thermodynamically more stable mineral assemblages for given Pressure-Temperature-fluid composition (P-T-X) conditions.

Multiparticle imaging technique for two-phase fluid flows using pulsed laser speckle velocimetry. Final report, September 1988--November 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hassan, T.A.

1992-12-01

The practical use of Pulsed Laser Velocimetry (PLV) requires the use of fast, reliable computer-based methods for tracking numerous particles suspended in a fluid flow. Two methods for performing tracking are presented. One method tracks a particle through multiple sequential images (minimum of four required) by prediction and verification of particle displacement and direction. The other method, requiring only two sequential images uses a dynamic, binary, spatial, cross-correlation technique. The algorithms are tested on computer-generated synthetic data and experimental data which was obtained with traditional PLV methods. This allowed error analysis and testing of the algorithms on real engineering flows.more » A novel method is proposed which eliminates tedious, undersirable, manual, operator assistance in removing erroneous vectors. This method uses an iterative process involving an interpolated field produced from the most reliable vectors. Methods are developed to allow fast analysis and presentation of sets of PLV image data. Experimental investigation of a two-phase, horizontal, stratified, flow regime was performed to determine the interface drag force, and correspondingly, the drag coefficient. A horizontal, stratified flow test facility using water and air was constructed to allow interface shear measurements with PLV techniques. The experimentally obtained local drag measurements were compared with theoretical results given by conventional interfacial drag theory. Close agreement was shown when local conditions near the interface were similar to space-averaged conditions. However, theory based on macroscopic, space-averaged flow behavior was shown to give incorrect results if the local gas velocity near the interface as unstable, transient, and dissimilar from the average gas velocity through the test facility.« less

Multiparticle imaging technique for two-phase fluid flows using pulsed laser speckle velocimetry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hassan, T.A.

1992-12-01

The practical use of Pulsed Laser Velocimetry (PLV) requires the use of fast, reliable computer-based methods for tracking numerous particles suspended in a fluid flow. Two methods for performing tracking are presented. One method tracks a particle through multiple sequential images (minimum of four required) by prediction and verification of particle displacement and direction. The other method, requiring only two sequential images uses a dynamic, binary, spatial, cross-correlation technique. The algorithms are tested on computer-generated synthetic data and experimental data which was obtained with traditional PLV methods. This allowed error analysis and testing of the algorithms on real engineering flows.more » A novel method is proposed which eliminates tedious, undersirable, manual, operator assistance in removing erroneous vectors. This method uses an iterative process involving an interpolated field produced from the most reliable vectors. Methods are developed to allow fast analysis and presentation of sets of PLV image data. Experimental investigation of a two-phase, horizontal, stratified, flow regime was performed to determine the interface drag force, and correspondingly, the drag coefficient. A horizontal, stratified flow test facility using water and air was constructed to allow interface shear measurements with PLV techniques. The experimentally obtained local drag measurements were compared with theoretical results given by conventional interfacial drag theory. Close agreement was shown when local conditions near the interface were similar to space-averaged conditions. However, theory based on macroscopic, space-averaged flow behavior was shown to give incorrect results if the local gas velocity near the interface as unstable, transient, and dissimilar from the average gas velocity through the test facility.« less

New numerical approaches for modeling thermochemical convection in a compositionally stratified fluid

NASA Astrophysics Data System (ADS)

Puckett, Elbridge Gerry; Turcotte, Donald L.; He, Ying; Lokavarapu, Harsha; Robey, Jonathan M.; Kellogg, Louise H.

2018-03-01

Geochemical observations of mantle-derived rocks favor a nearly homogeneous upper mantle, the source of mid-ocean ridge basalts (MORB), and heterogeneous lower mantle regions. Plumes that generate ocean island basalts are thought to sample the lower mantle regions and exhibit more heterogeneity than MORB. These regions have been associated with lower mantle structures known as large low shear velocity provinces (LLSVPS) below Africa and the South Pacific. The isolation of these regions is attributed to compositional differences and density stratification that, consequently, have been the subject of computational and laboratory modeling designed to determine the parameter regime in which layering is stable and understanding how layering evolves. Mathematical models of persistent compositional interfaces in the Earth's mantle may be inherently unstable, at least in some regions of the parameter space relevant to the mantle. Computing approximations to solutions of such problems presents severe challenges, even to state-of-the-art numerical methods. Some numerical algorithms for modeling the interface between distinct compositions smear the interface at the boundary between compositions, such as methods that add numerical diffusion or 'artificial viscosity' in order to stabilize the algorithm. We present two new algorithms for maintaining high-resolution and sharp computational boundaries in computations of these types of problems: a discontinuous Galerkin method with a bound preserving limiter and a Volume-of-Fluid interface tracking algorithm. We compare these new methods with two approaches widely used for modeling the advection of two distinct thermally driven compositional fields in mantle convection computations: a high-order accurate finite element advection algorithm with entropy viscosity and a particle method that carries a scalar quantity representing the location of each compositional field. All four algorithms are implemented in the open source finite element code ASPECT, which we use to compute the velocity, pressure, and temperature associated with the underlying flow field. We compare the performance of these four algorithms on three problems, including computing an approximation to the solution of an initially compositionally stratified fluid at Ra =105 with buoyancy numbers B that vary from no stratification at B = 0 to stratified flow at large B .

Instability of fluid flow over saturated porous medium

NASA Astrophysics Data System (ADS)

Lyubimova, Tatyana; Kolchanova, Ekaterina; Lyubimov, Dmitry

2013-04-01

We investigate the stability of a fluid flow over a saturated porous medium. The problem is of importance due to the applications to washing out of contaminants from the bottom layer of vegetation, whose properties are similar to the properties of porous medium. In the case of porous medium with the relatively high permeability and porosity the flow involves a part of the fluid saturating the porous medium, with the tangential fluid velocity drop occurring because of the resistance of the solid matrix. The drop leads to the instability analogous to Kelvin-Helmholtz one accompanied by the formation of travelling waves. In the present paper we consider a two-layer system consisting of a pure fluid layer and a porous layer saturated by the fluid located underneath. The system is bounded by a rigid surface at the bottom and a non-deformable free surface at the top. It is under the gravity and inclined at a slight angle to the horizontal axis. The boundary conditions at the interface between the fluid and porous layers are the continuity of fluid velocities and the balance of normal and tangential stresses taking into account the resistance of the solid matrix with respect to the fluid flow near the interface [1-2]. The problem is solved in the framework of the Brinkman model applying the classical shooting algorithm with orthogonalization. The stability boundaries of the stationary fluid flow over the saturated porous medium with respect to the small oscillatory perturbations are obtained for the various values of the Darcy number and the ratio of the porous layer thickness to the full thickness of the system d. It was shown that at the d > 0.5 with increasing the porous layer thickness (or with decreasing of the fluid layer thickness) the stability threshold rises. This is because of the fact that the instability is primarily caused by perturbations located in the fluid layer. At the d < 0.5 the reduction of the porous layer thickness leads to the stability threshold growth. The numerical calculations were also conducted for nonlinear regimes of the flow applying the finite-element method. Flow characteristics are determined at supercritical values of parameters. The work was made under the financial support of Russian Foundation for Basic Research (Grant 12-01-00795). 1. Ochoa-Tapia J. A. and Whitaker S. Momentum transfer at the boundary between a porous medium and a homogeneous fluid-I. Theoretical development. Int. J. Heat Mass Transfer. 1995. N 38. P. 2635-2646. 2. Ochoa-Tapia J. A. and Whitaker S. Momentum transfer at the boundary between a porous medium and a homogeneous fluid-II. Comparison with experiment. Int. J. Heat Mass Transfer. 1995. N 38. P. 2647-2655.

Carbonation of Subduction Interface Ultramafic Rocks and Implications for Deep Carbon Cycling: Evidence from Hybrid Serpentinite-Marble in the Voltri Massif, Italy

NASA Astrophysics Data System (ADS)

Scambelluri, M.; Bebout, G. E.; Gilio, M.; Belmonte, D.; Campomenosi, N.; Crispini, L.

2015-12-01

Release of COH fluids from hydrous minerals and carbonates influences element recycling and magmatism at subduction zones. Contradictory interpretations exist regarding the retention/storage of C in subducting plates and in the forearc to subarc mantle. Multiple lines of evidence indicate mobility of C in forearcs; however, the magnitude of this loss is highly uncertain[1-5]. A poorly constrained fraction of the 40-115 Mt/y of C initially subducted is released into fluids (e.g., by decarbonation, carbonate dissolution), and 18-43 Mt/y is returned at arc volcanoes[2-5, refs. therein]. The imbalance could reflect subduction into the deeper mantle or forearc/subarc storage[4-7]. We examine the fate of C in slab/interface ultramafic rocks, and by analogy serpentinized mantle wedge, via study of fluid-rock evolution of marble and variably carbonated serpentinite (Ligurian Alps). Based on petrography, and major/trace element and C and O isotope compositions, we demonstrate that serpentinite dehydration at 2-2.5 GPa, 550°C released aqueous fluids triggering breakdown of dolomite in nearby marbles, thus releasing C into fluids. Carbonate + olivine veins document flow of COH fluids; interaction of these COH fluids with serpentinite led to formation of high-pressure carbonated ultramafic-rock domains, thus resulting in retention of C in some rocks at an ancient subduction interface. We stress that lithologically complex interfaces could contain sites of both C release and C addition, further confounding estimates of net C loss at forearc and subarc depths [cf 4,5]. Sites of C retention, also including carbonate veins and graphite as reduced carbonate[7], could influence the transfer of slab C to at least the depths beneath volcanic fronts. 1. Poli S et al. 2009 EPSL; 2. Ague and Nicolescu 2014 Nat Geosci; 3. Cook-Collars et al. 2014 Chem Geol; 4. Collins et al. 2015 Chem Geol; 5. Kelemen and Manning 2015 PNAS; 6. Sapienza et al. 2009 CMP; 7 Galvez et al. 2013 Nat Geosci

Analysis of two-phase flow inter-subchannel mass and momentum exchanges by the two-fluid model approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ninokata, H.; Deguchi, A.; Kawahara, A.

1995-09-01

A new void drift model for the subchannel analysis method is presented for the thermohydraulics calculation of two-phase flows in rod bundles where the flow model uses a two-fluid formulation for the conservation of mass, momentum and energy. A void drift model is constructed based on the experimental data obtained in a geometrically simple inter-connected two circular channel test sections using air-water as working fluids. The void drift force is assumed to be an origin of void drift velocity components of the two-phase cross-flow in a gap area between two adjacent rods and to overcome the momentum exchanges at themore » phase interface and wall-fluid interface. This void drift force is implemented in the cross flow momentum equations. Computational results have been successfully compared to experimental data available including 3x3 rod bundle data.« less

Filament capturing with the multimaterial moment-of-fluid method*

DOE PAGES

Jemison, Matthew; Sussman, Mark; Shashkov, Mikhail

2015-01-15

A novel method for capturing two-dimensional, thin, under-resolved material configurations, known as “filaments,” is presented in the context of interface reconstruction. This technique uses a partitioning procedure to detect disconnected regions of material in the advective preimage of a cell (indicative of a filament) and makes use of the existing functionality of the Multimaterial Moment-of-Fluid interface reconstruction method to accurately capture the under-resolved feature, while exactly conserving volume. An algorithm for Adaptive Mesh Refinement in the presence of filaments is developed so that refinement is introduced only near the tips of filaments and where the Moment-of-Fluid reconstruction error is stillmore » large. Comparison to the standard Moment-of-Fluid method is made. As a result, it is demonstrated that using filament capturing at a given resolution yields gains in accuracy comparable to introducing an additional level of mesh refinement at significantly lower cost.« less

Mesoscopic electrohydrodynamic simulations of binary colloidal suspensions.

PubMed

Rivas, Nicolas; Frijters, Stefan; Pagonabarraga, Ignacio; Harting, Jens

2018-04-14

A model is presented for the solution of electrokinetic phenomena of colloidal suspensions in fluid mixtures. We solve the discrete Boltzmann equation with a Bhatnagar-Gross-Krook collision operator using the lattice Boltzmann method to simulate binary fluid flows. Solvent-solvent and solvent-solute interactions are implemented using a pseudopotential model. The Nernst-Planck equation, describing the kinetics of dissolved ion species, is solved using a finite difference discretization based on the link-flux method. The colloids are resolved on the lattice and coupled to the hydrodynamics and electrokinetics through appropriate boundary conditions. We present the first full integration of these three elements. The model is validated by comparing with known analytic solutions of ionic distributions at fluid interfaces, dielectric droplet deformations, and the electrophoretic mobility of colloidal suspensions. Its possibilities are explored by considering various physical systems, such as breakup of charged and neutral droplets and colloidal dynamics at either planar or spherical fluid interfaces.

Mesoscopic electrohydrodynamic simulations of binary colloidal suspensions

NASA Astrophysics Data System (ADS)

Rivas, Nicolas; Frijters, Stefan; Pagonabarraga, Ignacio; Harting, Jens

2018-04-01

A model is presented for the solution of electrokinetic phenomena of colloidal suspensions in fluid mixtures. We solve the discrete Boltzmann equation with a Bhatnagar-Gross-Krook collision operator using the lattice Boltzmann method to simulate binary fluid flows. Solvent-solvent and solvent-solute interactions are implemented using a pseudopotential model. The Nernst-Planck equation, describing the kinetics of dissolved ion species, is solved using a finite difference discretization based on the link-flux method. The colloids are resolved on the lattice and coupled to the hydrodynamics and electrokinetics through appropriate boundary conditions. We present the first full integration of these three elements. The model is validated by comparing with known analytic solutions of ionic distributions at fluid interfaces, dielectric droplet deformations, and the electrophoretic mobility of colloidal suspensions. Its possibilities are explored by considering various physical systems, such as breakup of charged and neutral droplets and colloidal dynamics at either planar or spherical fluid interfaces.

Waste heat recovery system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ernst, Timothy C.; Zigan, James A.

A waste heat recovery system includes a Rankine cycle (RC) circuit having a pump, a boiler, an energy converter, and a condenser fluidly coupled via conduits in that order, to provide additional work. The additional work is fed to an input of a gearbox assembly including a capacity for oil by mechanically coupling to the energy converter to a gear assembly. An interface is positioned between the RC circuit and the gearbox assembly to partially restrict movement of oil present in the gear assembly into the RC circuit and partially restrict movement of working fluid present in the RC circuitmore » into the gear assembly. An oil return line is fluidly connected to at least one of the conduits fluidly coupling the RC components to one another and is operable to return to the gear assembly oil that has moved across the interface from the gear assembly to the RC circuit.« less

Application of Biot Theory to the Study of Acoustic Reflection from Sediments

DTIC Science & Technology

1992-09-08

of bottom loss at all frequencies. To predict propagation loss, a multipath expansion propagation model [15] was used. The sound velocity profile in...public release; distribution unlimited. 13. AISTRACT (Maximum 200 wovov Wave Propagation in fluid-saturated poroelastic media may be described using...of grazing angle and frequency is compared against the more common fluid-fluid and fluid-solid interface models . Finally, shallow water propagation

Quick connect coupling

NASA Technical Reports Server (NTRS)

Lomax, Curtis (Inventor); Webbon, Bruce (Inventor)

1995-01-01

A cooling apparatus includes a container filled with a quantity of coolant fluid initially cooled to a solid phase, a cooling loop disposed between a heat load and the container, a pump for circulating a quantity of the same type of coolant fluid in a liquid phase through the cooling loop, and a pair of couplings for communicating the liquid phase coolant fluid into the container in a direct interface with the solid phase coolant fluid.

Hydrodynamic instabilities in miscible fluids

NASA Astrophysics Data System (ADS)

Truzzolillo, Domenico; Cipelletti, Luca

2018-01-01

Hydrodynamic instabilities in miscible fluids are ubiquitous, from natural phenomena up to geological scales, to industrial and technological applications, where they represent the only way to control and promote mixing at low Reynolds numbers, well below the transition from laminar to turbulent flow. As for immiscible fluids, the onset of hydrodynamic instabilities in miscible fluids is directly related to the physics of their interfaces. The focus of this review is therefore on the general mechanisms driving the growth of disturbances at the boundary between miscible fluids, under a variety of forcing conditions. In the absence of a regularizing mechanism, these disturbances would grow indefinitely. For immiscible fluids, interfacial tension provides such a regularizing mechanism, because of the energy cost associated to the creation of new interface by a growing disturbance. For miscible fluids, however, the very existence of interfacial stresses that mimic an effective surface tension is debated. Other mechanisms, however, may also be relevant, such as viscous dissipation. We shall review the stabilizing mechanisms that control the most common hydrodynamic instabilities, highlighting those cases for which the lack of an effective interfacial tension poses deep conceptual problems in the mathematical formulation of a linear stability analysis. Finally, we provide a short overview on the ongoing research on the effective, out of equilibrium interfacial tension between miscible fluids.

Petrological insights into intermediate-depths of a subduction plate interface

NASA Astrophysics Data System (ADS)

Angiboust, Samuel; Agard, Philippe

2013-04-01

Understanding processes acting along the subduction interface is crucial to assess lithospheric scale coupling between tectonic plates, exhumation of deep-seated rocks and mechanisms causing intermediate-depth seismicity. Yet, despite a wealth of geophysical studies aimed at better characterizing the subduction interface, we still lack critical petrological data constraining such processes as intermediate-seismicity within oceanic subduction zones. This contribution reviews recent findings from two major localities showing deeply subducted ophiolitic remnants (Zermatt-Saas, Monviso), which crop out in the classic, well-preserved fossil subduction setting of the Western Alps. We herein show that both ophiolite remnants represent large, relatively continuous fragments of oceanic lithosphere (i.e., several km-thick tectonic slices across tens of km) exhumed from ~80 km depths and thereby provide important constraints on interplate coupling mechanisms. In both fragments (but even more so in the Zermatt-Saas one) pervasive hydrothermal processes and seafloor alteration, promoting fluid incorporation in both mafic and associated ultramafic rocks, was essential, together with the presence of km-thick serpentinite soles, to decrease the density of the tectonic slices and prevent them from an irreversible sinking into the mantle. The Monviso case sudy provides further insights into the subduction plate interface at ~80 km depths. The Lago Superiore Unit, in particular, is made of a 50-500 m thick eclogitized mafic crust (associated with minor calcschist lenses) overlying a 100-400 m thick metagabbroic body and a km-thick serpentinite sole, and is cut by two 10 to 100m thick eclogite-facies shear zones, respectively located at the boundary between basalts and gabbros, and between gabbros and serpentinites (the Lower Shear Zone: LSZ). The LSZ gives precious information on both seismicity and fluid flow: (1) Eclogite breccias, reported here for the first time, mark the locus of an ancient fault zone associated with intraslab, intermediate-depth earthquakes at ~80 km depth. They correspond to m-sized blocks made of 1-10 cm large fragments of eclogite mylonite later embedded in serpentinite in the eclogite facies LSZ. We suggest that seismic brecciation (possibly at magnitudes Mw ~4) occurred in the middle part of the oceanic crust, accompanied by the input of externally-derived fluids. (2) Prominent fluid-rock interactions, as attested by ubiquitous metasomatic rinds, affected the fragments of mylonitic basaltic eclogites and calcschists dragged and dismembered within serpentinite during eclogite-facies deformation. Detailed petrological and geochemical investigations point to a massive, pulse-like, fluid-mediated element transfer essentially originating from serpentinite. Antigorite breakdown, occurring ca. 15 km deeper than the maximum depth reached by these eclogites, is regarded as the likely source of this highly focused fluid/rock interaction and element transfer. Such a pulse-like, subduction-parallel fluid migration pathway within the downgoing oceanic lithosphere may have been promoted by transient slip behaviour along the LSZ under eclogite-facies conditions. These petrological data are finally tied to bi-phase numerical models in which fluid migration is driven by fluid concentrations in the rocks, non-lithostatic pressure gradients and deformation, and that allow for mantle wedge hydration and mechanical weakening of the plate interface. We suggest that the detachment of such oceanic tectonic slices is largely promoted by fluid circulation along the subduction interface, as well as by subducting a strong and originally discontinuous mafic crust.

On a two-phase Hele-Shaw problem with a time-dependent gap and distributions of sinks and sources

NASA Astrophysics Data System (ADS)

Savina, Tatiana; Akinyemi, Lanre; Savin, Avital

2018-01-01

A two-phase Hele-Shaw problem with a time-dependent gap describes the evolution of the interface, which separates two fluids sandwiched between two plates. The fluids have different viscosities. In addition to the change in the gap width of the Hele-Shaw cell, the interface is driven by the presence of some special distributions of sinks and sources located in both the interior and exterior domains. The effect of surface tension is neglected. Using the Schwarz function approach, we give examples of exact solutions when the interface belongs to a certain family of algebraic curves and the curves do not form cusps. The family of curves are defined by the initial shape of the free boundary.

Designing an information search interface for younger and older adults.

PubMed

Pak, Richard; Price, Margaux M

2008-08-01

The present study examined Web-based information retrieval as a function of age for two information organization schemes: hierarchical organization and one organized around tags or keywords. Older adults' performance in information retrieval tasks has traditionally been lower compared with younger adults'. The current study examined the degree to which information organization moderated age-related performance differences on an information retrieval task. The theory of fluid and crystallized intelligence may provide insight into different kinds of information architectures that may reduce age-related differences in computer-based information retrieval performance. Fifty younger (18-23 years of age) and 50 older (55-76 years of age) participants browsed a Web site for answers to specific questions. Half of the participants browsed the hierarchically organized system (taxonomy), which maintained a one-to-one relationship between menu link and page, whereas the other half browsed the tag-based interface, with a many-to-one relationship between menu and page. This difference was expected to interact with age-related differences in fluid and crystallized intelligence. Age-related differences in information retrieval performance persisted; however, a tag-based retrieval interface reduced age-related differences, as compared with a taxonomical interface. Cognitive aging theory can lead to interface interventions that reduce age-related differences in performance with technology. In an information retrieval paradigm, older adults may be able to leverage their increased crystallized intelligence to offset fluid intelligence declines in a computer-based information search task. More research is necessary, but the results suggest that information retrieval interfaces organized around keywords may reduce age-related differences in performance.

Evaporation of Lennard-Jones fluids.

PubMed

Cheng, Shengfeng; Lechman, Jeremy B; Plimpton, Steven J; Grest, Gary S

2011-06-14

Evaporation and condensation at a liquid/vapor interface are ubiquitous interphase mass and energy transfer phenomena that are still not well understood. We have carried out large scale molecular dynamics simulations of Lennard-Jones (LJ) fluids composed of monomers, dimers, or trimers to investigate these processes with molecular detail. For LJ monomers in contact with a vacuum, the evaporation rate is found to be very high with significant evaporative cooling and an accompanying density gradient in the liquid domain near the liquid/vapor interface. Increasing the chain length to just dimers significantly reduces the evaporation rate. We confirm that mechanical equilibrium plays a key role in determining the evaporation rate and the density and temperature profiles across the liquid/vapor interface. The velocity distributions of evaporated molecules and the evaporation and condensation coefficients are measured and compared to the predictions of an existing model based on kinetic theory of gases. Our results indicate that for both monatomic and polyatomic molecules, the evaporation and condensation coefficients are equal when systems are not far from equilibrium and smaller than one, and decrease with increasing temperature. For the same reduced temperature T/T(c), where T(c) is the critical temperature, these two coefficients are higher for LJ dimers and trimers than for monomers, in contrast to the traditional viewpoint that they are close to unity for monatomic molecules and decrease for polyatomic molecules. Furthermore, data for the two coefficients collapse onto a master curve when plotted against a translational length ratio between the liquid and vapor phase.

Anatomical and morphogenetic analysis of seismoelectric conversion patterns at geological units

NASA Astrophysics Data System (ADS)

Kröger, B.; Kemna, A.

2012-04-01

Characterisation of the hydraulic properties of a reservoir, such as porosity and permeability, and their spatial distribution plays an important role in many subsurface geophysical investigations. A fully developed seismoelectric exploration method is very appealing since it would offer the potential to directly determine these parameters in field-scale applications. In fluid-saturated rocks, seismic waves can generate electromagnetic fields, due to electrokinetic coupling mechanisms at the fluid-mineral interface. Using numerical modelling, we investigated the spatio-temporal occurrence and evolution of the seismoelectric effects that occur in spatially confined lithological units. Such geometries may represent clay lenses embedded in an aquifer or petroleum deposits in a host rock. For the modelling, we use a simplified time-domain formulation of the coupled physical problem and its efficient implementation in a 2D finite-element framework. Two occurring seismoelectric phenomena are investigated: (1) the co-seismic field associated with the seismic displacement at each point and (2) the interface response generated at layer boundaries. To gain insight into the morphogenetic field behaviour of the seismoelectric effects, we run numerical simulations using several material parameter set-ups for various target geometries. Accordingly, we varied both the thickness of the confined units and the value of the electrical bulk conductivity in the considered media. The analysis of the seismoelectric effects revealed an important difference in the generation of the interface response at either electrically conductive or resistive units. We find that the contrast in the electrical bulk conductivity between the host rock and the target geological unit controls the shape and structure of the seismoelectric conversion patterns. Our results show that the seismoelectric interface response captures both the petrophysical and geometrical characteristics of the converting geological unit. The considered models indicate the general potential of using the seismoelectric interface response for reservoir characterisation in hydrogeological or hydrocarbon exploration studies.

Droplet microfluidics driven by gradients of confinement.

PubMed

Dangla, Rémi; Kayi, S Cagri; Baroud, Charles N

2013-01-15

The miniaturization of droplet manipulation methods has led to drops being proposed as microreactors in many applications of biology and chemistry. In parallel, microfluidic methods have been applied to generate monodisperse emulsions for applications in the pharmaceuticals, cosmetics, and food industries. To date, microfluidic droplet production has been dominated by a few designs that use hydrodynamic forces, resulting from the flowing fluids, to break drops at a junction. Here we present a platform for droplet generation and manipulation that does not depend on the fluid flows. Instead, we use devices that incorporate height variations to subject the immiscible interfaces to gradients of confinement. The resulting curvature imbalance along the interface causes the detachment of monodisperse droplets, without the need for a flow of the external phase. Once detached, the drops are self-propelled due to the gradient of surface energy. We show that the size of the drops is determined by the device geometry; it is insensitive to the physical fluid properties and depends very weakly on the flow rate of the dispersed phase. This allows us to propose a geometric theoretical model that predicts the dependence of droplet size on the geometric parameters, which is in agreement with experimental measurements. The approach presented here can be applied in a wide range of standard applications, while simplifying the device operations. We demonstrate examples for single-droplet operations and high-throughput generation of emulsions, all of which are performed in simple and inexpensive devices.

Droplet microfluidics driven by gradients of confinement

PubMed Central

Dangla, Rémi; Kayi, S. Cagri; Baroud, Charles N.

2013-01-01

The miniaturization of droplet manipulation methods has led to drops being proposed as microreactors in many applications of biology and chemistry. In parallel, microfluidic methods have been applied to generate monodisperse emulsions for applications in the pharmaceuticals, cosmetics, and food industries. To date, microfluidic droplet production has been dominated by a few designs that use hydrodynamic forces, resulting from the flowing fluids, to break drops at a junction. Here we present a platform for droplet generation and manipulation that does not depend on the fluid flows. Instead, we use devices that incorporate height variations to subject the immiscible interfaces to gradients of confinement. The resulting curvature imbalance along the interface causes the detachment of monodisperse droplets, without the need for a flow of the external phase. Once detached, the drops are self-propelled due to the gradient of surface energy. We show that the size of the drops is determined by the device geometry; it is insensitive to the physical fluid properties and depends very weakly on the flow rate of the dispersed phase. This allows us to propose a geometric theoretical model that predicts the dependence of droplet size on the geometric parameters, which is in agreement with experimental measurements. The approach presented here can be applied in a wide range of standard applications, while simplifying the device operations. We demonstrate examples for single-droplet operations and high-throughput generation of emulsions, all of which are performed in simple and inexpensive devices. PMID:23284169

Fluid Pressure in the Shallow Plate Interface at the Nankai Trough Subduction Zone

NASA Astrophysics Data System (ADS)

Tobin, H. J.; Saffer, D.

2003-12-01

The factors controlling the occurrence, magnitude, and other characteristics of great earthquakes is a fundamental outstanding question in fault physics. Pore fluid pressure is perhaps the most critical yet poorly known parameter governing the strength and seismogenic character of plate boundary faults, but unfortunately cannot be directly inferred through available geophysical sensing methods. Moreover, true in situ fluid pressure has proven difficult to measure even in boreholes. At the Nankai Trough, several hundred meters of sediment are subducted beneath the frontal portion of the accretionary prism. The up-dip portion of the plate interface is therefore hosted in these fine-grained marine sedimentary rocks. ODP Leg 190 and 196 showed that these rapidly-loaded underthrust sediments are significantly overpressured near the deformation front. Here, we attempt to quantitatively infer porosity, pore pressure, and effective normal stress at the plate interface at depths currently inaccessible to drilling. Using seismic reflection interval velocity calibrated at the boreholes to porosity, we quantitatively infer pore pressure to ˜ 20 km down-dip of the deformation front, to a plate interface depth of ˜ 6 km. We have developed a Nankai-specific velocity-porosity transform using ODP cores and logs. We use this function to derive a porosity profile for each of two down-dip seismic sections extracted from a 3-D dataset from the Cape Muroto region. We then calculate pore fluid pressure and effective vertical (fault-normal) stress for the underthrust sediment section using a compaction disequilibrium approach and core-based consolidation test data. Because the pore fluid pressure at the fault interface is likely controlled by that of the top of the underthrust section, this calculation represents a quantitative profile of effective stress and pore pressure at the plate interface. Results show that seismic velocity and porosity increase systematically downdip in the underthrust section, but the increase is suppressed relative to that expected from normally consolidating sediments. The computed pore pressure increases landward from an overpressure ratio (λ * = hydrostatic pressure divided by the lithostatic overburden) of ˜ 0.6 at the deformation front to ˜ 0.77 where sediments have been subducted 15 km. The results of this preliminary analysis suggest that a 3-dimensional mapping of predicted effective normal stress in the seismic data volume is possible.

Aseismic Slip of a Thin Slab Due to a Fluid Source

NASA Astrophysics Data System (ADS)

Aubin, P. W.; Viesca, R. C.

2017-12-01

We explore the effects of an increase of pore pressure on the frictional interface along the base of a thin slab. The thin slab approximation corresponds to a layer overriding a substrate in which variations along the layer's length occur over distances much greater than the layer thickness. We consider deformation that may be in-plane or anti-plane, but approximately uniform in depth, such that spatial variations of displacement (and hence, slip) occur only along one direction parallel to the interface. Such a thin-sheet model may well represent the deformation of landslides and glacial ice streams, and also serves as a first-pass for fault systems, which, while better represented by elastic half-spaces in frictional contact, nonetheless show qualitatively similar behavior. We consider that the friction coefficient at the layer's interface remains (approximately) constant, and that aseismic slip is initiated by a (line) source of fluid at constant pressure, with one-dimensional diffusion parallel to the interface. As posed, the problem yields a self-similar expansion of slip, whose extent grows proportionally to (α * t)^(1/2) (where α is the hydraulic diffusivity) and can either lag behind or outpace the fluid diffusion front. The problem is controlled by a single parameter, accounting for the friction coefficient and the initial (pre-injection) states of stress and pore pressure. The problem solution consists of the self-similar slip profile and the coefficient of proportionality for the crack-front motion. Within the problem parameter range, two end-member scenarios result: one in which the initial level of shear stress on the interface is close to the value of the pre-injection strength (critically stressed) or another in which fluid pressure is just enough to induce slip (marginally pressurized). For the critically stressed and marginally pressurized cases, the aseismic slip front lies far ahead or far behind, respectively, the fluid diffusion front. We find closed-form solutions for both end-members, and in the former case, via matched asymptotics. These solutions provide a basis to solve the general problem, which we also solve numerically for comparison. The solutions also provide a starting point for examining the progression of slip and locking following the shutoff of the fluid source.

Coal-rock interface detector

NASA Technical Reports Server (NTRS)

Rose, S. D.; Crouch, C. E.; Jones, E. W. (Inventor)

1979-01-01

A coal-rock interface detector is presented which employs a radioactive source and radiation sensor. The source and sensor are separately and independently suspended and positioned against a mine surface of hydraulic pistons, which are biased from an air cushioned source of pressurized hydraulic fluid.

Cascadia Slow Earthquakes: Strategies for Time Independent Inversion of Displacement Fields

NASA Astrophysics Data System (ADS)

Szeliga, W. M.; Melbourne, T. I.; Miller, M. M.; Santillan, V. M.

2004-12-01

Continuous observations using Global Positioning System geodesy (CGPS) have revealed periodic slow or silent earthquakes along the Cascadia subduction zone with a spectrum of timing and periodicity. These creep events perturb time series of GPS observations and yield coherent displacement fields that relate to the extent and magnitude of fault displacement. In this study, time independent inversions of the surface displacement fields that accompany eight slow earthquakes characterize slip distributions along the plate interface for each event. The inversions employed in this study utilize Okada's elastic dislocation model and a non- negative least squares approach. Methodologies for optimizing the slip distribution smoothing parameter for a particular station distribution have also been investigated, significantly reducing the number of possible slip distributions and the range of estimates for total moment release for each event. The discretized slip distribution calculated for multiple creep events identifies areas of the Cascadia plate interface where slip persistently recurs. The current hypothesis, that slow earthquakes are modulated by forced fluid flow, leads to the possibility that some regions of the Cascadia plate interface may display fault patches preferentially exploited by fluid flow. Thus, the identification of regions of the plate interface that repeatedly slip during slow events may yield important information regarding the identification of these fluid pathways.

The Earth's mantle in a microwave oven: thermal convection driven by a heterogeneous distribution of heat sources

NASA Astrophysics Data System (ADS)

Fourel, Loïc; Limare, Angela; Jaupart, Claude; Surducan, Emanoil; Farnetani, Cinzia G.; Kaminski, Edouard C.; Neamtu, Camelia; Surducan, Vasile

2017-08-01

Convective motions in silicate planets are largely driven by internal heat sources and secular cooling. The exact amount and distribution of heat sources in the Earth are poorly constrained and the latter is likely to change with time due to mixing and to the deformation of boundaries that separate different reservoirs. To improve our understanding of planetary-scale convection in these conditions, we have designed a new laboratory setup allowing a large range of heat source distributions. We illustrate the potential of our new technique with a study of an initially stratified fluid involving two layers with different physical properties and internal heat production rates. A modified microwave oven is used to generate a uniform radiation propagating through the fluids. Experimental fluids are solutions of hydroxyethyl cellulose and salt in water, such that salt increases both the density and the volumetric heating rate. We determine temperature and composition fields in 3D with non-invasive techniques. Two fluorescent dyes are used to determine temperature. A Nd:YAG planar laser beam excites fluorescence, and an optical system, involving a beam splitter and a set of colour filters, captures the fluorescence intensity distribution on two separate spectral bands. The ratio between the two intensities provides an instantaneous determination of temperature with an uncertainty of 5% (typically 1K). We quantify mixing processes by precisely tracking the interfaces separating the two fluids. These novel techniques allow new insights on the generation, morphology and evolution of large-scale heterogeneities in the Earth's lower mantle.

Adhesion mechanisms of bituminous crack sealant to aggregate and laboratory test development

NASA Astrophysics Data System (ADS)

Hajialiakbari Fini, Elham

Crack sealing is a common pavement maintenance treatment because it extends pavement service life. However, crack sealant often fails prematurely due to a loss of adhesion. Since current test methods are mostly empirical and only provide a qualitative measure of bond strength, they cannot predict sealant adhesive failure accurately. Hence, there is an urgent need for test methods based on bituminous sealant rheology that can better predict sealant field performance. This study introduces three laboratory tests aimed to assess the bond property of hot-poured crack sealant to pavement crack walls. The three tests are designed to serve the respective needs of producers, engineers, and researchers. The first test implements the principle of surface energy to measure the thermodynamic work of adhesion, which is the energy spent in separating the two materials at the interface. The work of adhesion is reported as a measure of material compatibility at an interface. The second test is a direct adhesion test, a mechanical test which is designed to closely resemble both the installation process and the crack expansion due to thermal loading. This test uses the Direct Tension Test (DTT) device. The principle of the test is to apply a tensile force to detach the sealant from its aggregate counterpart. The maximum load, Pmax, and the energy to separation, E, are calculated and reported to indicate interface bonding. The third test implements the principles of fracture mechanics in a pressurized circular blister test. The apparatus is specifically designed to conduct the test for bituminous crack sealant, asphalt binder, or other bitumen-based materials. In this test, a fluid is injected at a constant rate at the interface between the substrate (aggregate or a standard material) and the adhesive (crack sealant) to create a blister. The fluid pressure and blister height are measured as functions of time; the data is used to calculate Interfacial Fracture Energy (IFE), which is a fundamental property that can be used to predict adhesion. The stable interface debonding process makes this test attractive. This test also may be used to estimate the optimum annealing time, and to quantify other interface characteristics, such as the moisture susceptibility of a bond. In addition, the elastic modulus of the sealant and its residual stresses can be determined analytically. While the direct adhesion test is proposed as part of newly-developed performance-based guidelines for the selection of hot-poured crack sealant, the blister test may be used to estimate the optimum annealing time, in addition to IFE determination.

Two sides of the coin. Part 1. Lipid and surfactant self-assembly revisited.

PubMed

Ninham, Barry W; Larsson, Kåre; Lo Nostro, Pierandrea

2017-04-01

Hofmeister, specific ion effects, hydration and van der Waals forces at and between interfaces are factors that determine curvature and microstructure in self assembled aggregates of surfactants and lipids; and in microemulsions. Lipid and surfactant head group interactions and between aggregates vary enormously and are highly specific. They act on the hydrophilic side of a bilayer, micelle or other self assembled aggregate. It is only over the last three decades that the origin of Hofmeister effects has become generally understood. Knowledge of their systematics now provides much flexibility in designing nanostructured fluids. The other side of the coin involves equally specific forces. These (opposing) forces work on the hydrophobic side of amphiphilic interfaces. They are due to the interaction of hydrocarbons and other "oils" with hydrophobic tails of surfactants and lipids. The specificity of oleophilic solutes in microemulsions and lipid membranes provides a counterpoint to Hofmeister effects and hydration. Together with global packing constraints these effects determine microstructure. Another factor that has hardly been recognised is the role of dissolved gas. This introduces further, qualitative changes in forces that prescribe microstructure. The systematics of these effects and their interplay are elucidated. Awareness of these competing factors facilitates formulation of self assembled nanostructured fluids. New and predictable geometries that emerge naturally provide insights into a variety of biological phenomena like anaesthetic and pheromone action and transmission of the nervous impulse (see Part 2). Copyright © 2017 Elsevier B.V. All rights reserved.

Determining solid-fluid interface temperature distribution during phase change of cryogenic propellants using transient thermal modeling

NASA Astrophysics Data System (ADS)

Bellur, K.; Médici, E. F.; Hermanson, J. C.; Choi, C. K.; Allen, J. S.

2018-04-01

Control of boil-off of cryogenic propellants is a continuing technical challenge for long duration space missions. Predicting phase change rates of cryogenic liquids requires an accurate estimation of solid-fluid interface temperature distributions in regions where a contact line or a thin liquid film exists. This paper described a methodology to predict inner wall temperature gradients with and without evaporation using discrete temperature measurements on the outer wall of a container. Phase change experiments with liquid hydrogen and methane in cylindrical test cells of various materials and sizes were conducted at the Neutron Imaging Facility at the National Institute of Standards and Technology. Two types of tests were conducted. The first type of testing involved thermal cycling of an evacuated cell (dry) and the second involved controlled phase change with cryogenic liquids (wet). During both types of tests, temperatures were measured using Si-diode sensors mounted on the exterior surface of the test cells. Heat is transferred to the test cell by conduction through a helium exchange gas and through the cryostat sample holder. Thermal conduction through the sample holder is shown to be the dominant mode with the rate of heat transfer limited by six independent contact resistances. An iterative methodology is employed to determine contact resistances between the various components of the cryostat stick insert, test cell and lid using the dry test data. After the contact resistances are established, inner wall temperature distributions during wet tests are calculated.

Contact angle and detachment energy of shape anisotropic particles at fluid-fluid interfaces.

PubMed

Anjali, Thriveni G; Basavaraj, Madivala G

2016-09-15

The three phase contact angle of particles, a measure of its wettability, is an important factor that greatly influences their behaviour at interfaces. It is one of the principal design parameters for potential applications of particles as emulsion/foam stabilizers, functional coatings and other novel materials. In the present work, the effect of size, shape and surface chemistry of particles on their contact angle is investigated using the gel trapping technique, which facilitates the direct visualization of the equilibrium position of particles at interfaces. The contact angle of hematite particles of spherocylindrical, peanut and cuboidal shapes, hematite-silica core-shell and silica shells is reported at a single particle level. The spherocylindrical and peanut shaped particles are always positioned with their major axis parallel to the interface. However, for cuboidal particles at air-water as well as decane-water interfaces, different orientations namely - face-up, edge-up and the vertex-up - are observed. The influence of gravity on the equilibrium position of the colloidal particles at the interface is studied using the hematite-silica core-shell particles and the silica shells. The measured contact angle values are utilized in the calculations of the detachment and surface energies of the hematite particles adsorbed at the interface. Copyright © 2016 Elsevier Inc. All rights reserved.

HPTAM, a two-dimensional Heat Pipe Transient Analysis Model, including the startup from a frozen state

NASA Technical Reports Server (NTRS)

Tournier, Jean-Michel; El-Genk, Mohamed S.

1995-01-01

A two-dimensional Heat Pipe Transient Analysis Model, 'HPTAM,' was developed to simulate the transient operation of fully-thawed heat pipes and the startup of heat pipes from a frozen state. The model incorporates: (a) sublimation and resolidification of working fluid; (b) melting and freezing of the working fluid in the porous wick; (c) evaporation of thawed working fluid and condensation as a thin liquid film on a frozen substrate; (d) free-molecule, transition, and continuum vapor flow regimes, using the Dusty Gas Model; (e) liquid flow and heat transfer in the porous wick; and (f) thermal and hydrodynamic couplings of phases at their respective interfaces. HPTAM predicts the radius of curvature of the liquid meniscus at the liquid-vapor interface and the radial location of the working fluid level (liquid or solid) in the wick. It also includes the transverse momentum jump condition (capillary relationship of Pascal) at the liquid-vapor interface and geometrically relates the radius of curvature of the liquid meniscus to the volume fraction of vapor in the wick. The present model predicts the capillary limit and partial liquid recess (dryout) in the evaporator wick, and incorporates a liquid pooling submodel, which simulates accumulation of the excess liquid in the vapor core at the condenser end.

Oscillations of a standing shock wave generated by the Richtmyer-Meshkov instability

NASA Astrophysics Data System (ADS)

Mikaelian, Karnig O.

2016-07-01

In a typical Richtmyer-Meshkov experiment a fast moving flat shock strikes a stationary perturbed interface between fluids A and B creating a transmitted and a reflected shock, both of which are perturbed. We propose shock tube experiments in which the reflected shock is stationary in the laboratory. Such a standing perturbed shock undergoes well-known damped oscillations. We present the conditions required for producing such a standing shock wave, which greatly facilitates the measurement of the oscillations and their rate of damping. We define a critical density ratio Rcritical, in terms of the adiabatic indices of the two fluids, and a critical Mach number Mscritical of the incident shock wave, which produces a standing reflected wave. If the initial density ratio R of the two fluids is less than Rcritical then a standing shock wave is possible at Ms=Mscritical . Otherwise a standing shock is not possible and the reflected wave always moves in the direction opposite the incident shock. Examples are given for present-day operating shock tubes with sinusoidal or inclined interfaces. We consider the effect of viscosity, which affects the damping rate of the oscillations. We point out that nonlinear bubble and spike amplitudes depend relatively weakly on the viscosity of the fluids and that the interface area is a better diagnostic.

Elastic contact mechanics: percolation of the contact area and fluid squeeze-out.

PubMed

Persson, B N J; Prodanov, N; Krick, B A; Rodriguez, N; Mulakaluri, N; Sawyer, W G; Mangiagalli, P

2012-01-01

The dynamics of fluid flow at the interface between elastic solids with rough surfaces depends sensitively on the area of real contact, in particular close to the percolation threshold, where an irregular network of narrow flow channels prevails. In this paper, numerical simulation and experimental results for the contact between elastic solids with isotropic and anisotropic surface roughness are compared with the predictions of a theory based on the Persson contact mechanics theory and the Bruggeman effective medium theory. The theory predictions are in good agreement with the experimental and numerical simulation results and the (small) deviation can be understood as a finite-size effect. The fluid squeeze-out at the interface between elastic solids with randomly rough surfaces is studied. We present results for such high contact pressures that the area of real contact percolates, giving rise to sealed-off domains with pressurized fluid at the interface. The theoretical predictions are compared to experimental data for a simple model system (a rubber block squeezed against a flat glass plate), and for prefilled syringes, where the rubber plunger stopper is lubricated by a high-viscosity silicon oil to ensure functionality of the delivery device. For the latter system we compare the breakloose (or static) friction, as a function of the time of stationary contact, to the theory prediction.

OpenFLUID: an open-source software environment for modelling fluxes in landscapes

NASA Astrophysics Data System (ADS)

Fabre, Jean-Christophe; Rabotin, Michaël; Crevoisier, David; Libres, Aline; Dagès, Cécile; Moussa, Roger; Lagacherie, Philippe; Raclot, Damien; Voltz, Marc

2013-04-01

Integrative landscape functioning has become a common concept in environmental management. Landscapes are complex systems where many processes interact in time and space. In agro-ecosystems, these processes are mainly physical processes, including hydrological-processes, biological processes and human activities. Modelling such systems requires an interdisciplinary approach, coupling models coming from different disciplines, developed by different teams. In order to support collaborative works, involving many models coupled in time and space for integrative simulations, an open software modelling platform is a relevant answer. OpenFLUID is an open source software platform for modelling landscape functioning, mainly focused on spatial fluxes. It provides an advanced object-oriented architecture allowing to i) couple models developed de novo or from existing source code, and which are dynamically plugged to the platform, ii) represent landscapes as hierarchical graphs, taking into account multi-scale, spatial heterogeneities and landscape objects connectivity, iii) run and explore simulations in many ways : using the OpenFLUID software interfaces for users (command line interface, graphical user interface), or using external applications such as GNU R through the provided ROpenFLUID package. OpenFLUID is developed in C++ and relies on open source libraries only (Boost, libXML2, GLib/GTK, OGR/GDAL, …). For modelers and developers, OpenFLUID provides a dedicated environment for model development, which is based on an open source toolchain, including the Eclipse editor, the GCC compiler and the CMake build system. OpenFLUID is distributed under the GPLv3 open source license, with a special exception allowing to plug existing models licensed under any license. It is clearly in the spirit of sharing knowledge and favouring collaboration in a community of modelers. OpenFLUID has been involved in many research applications, such as modelling of hydrological network transfer, diagnosis and prediction of water quality taking into account human activities, study of the effect of spatial organization on hydrological fluxes, modelling of surface-subsurface water exchanges, … At LISAH research unit, OpenFLUID is the supporting development platform of the MHYDAS model, which is a distributed model for agrosystems (Moussa et al., 2002, Hydrological Processes, 16, 393-412). OpenFLUID web site : http://www.openfluid-project.org

Numerical Study on the Effect of Electrode Polarity on Desulfurization in Direct Current Electroslag Remelting Process

NASA Astrophysics Data System (ADS)

Wang, Qiang; Liu, Yu; Wang, Fang; Li, Guangqiang; Li, Baokuan; Qiao, Wenwei

2017-10-01

In order to clarify the influence of electrode polarity on desulfurization in direct current (DC) electroslag remelting process, a transient three-dimensional coupled mathematical model has been established. The finite volume method was invoked to simultaneously solve the mass, momentum, energy, and species conservation equations. The Joule heating and Lorentz force were fully coupled through calculating Maxwell's equations with the assistance of the magnetic potential vector. The motion of the metal-slag interface was described by using the volume of fluid approach. An auxiliary metallurgical kinetics module was introduced to determine the thermochemical and the electrochemical reaction rates. A reasonable agreement between the measured data and the simulated results are observed. A longer time and a larger area for the desulfurization can be provided by the metal pool-slag interface when compared with the metal droplet-slag interface. The electrochemical transfer rate at the metal pool-slag interface is positive in the DC reverse polarity (DCRP) remelting, while in the DC straight polarity (DCSP) remelting, the electrochemical transfer rate is negative at this interface. The desulfurization progress in the DCSP remelting thus is fall behind that in the DCRP remelting. The desulfurization rate of the DCRP remelting is around 70 pct and the rate of the DCSP remelting is about 40 pct.

The wavefield of acoustic logging in a cased-hole with a single casing - Part I: a monopole tool

NASA Astrophysics Data System (ADS)

Wang, Hua; Fehler, Michael

2018-01-01

The bonding quality of the seal formed by the cement or collapse material between casing and formation rock is critical for the hydraulic isolation of reservoir layers with shallow aquifers, production and environmental safety, and plug and abandonment issues. Acoustic logging is a very good tool for evaluating the condition of the bond between different interfaces. The understanding of the acoustic logging wavefields in wells with single casing is still incomplete. We use a 3-D finite difference method to simulate wireline monopole wavefields in a single cased borehole with different bonding conditions at two locations: (1) between the cement and casing and (2) between the cement and formation. Pressure snapshots and waveforms for different models are shown, which allow us to better understand the wave propagation. Modal dispersion curves and data processing methods such as velocity-time semblance and dispersion analysis facilitate the identification of propagation modes in the different models. We find that the P wave is submerged in the casing modes and the S wave has poor coherency when the cement is replaced with fluid. The casing modes are strong when cement next to the casing is partially or fully replaced with fluid. The amplitude of these casing modes can be used to determine the bonding condition of the interface between casing and cement. However, the limited variation of the amplitude with fluid thickness means that amplitude measurements may lead to an ambiguous interpretation. When the cement next to the formation is partially replaced with fluid, the modes propagate in the combination of steel casing and cement and the velocities are highly dependent on the cement thickness. However, if the cement thickness is large (more than 2/3 of the annulus between casing and rock), the arrival time of the first arrival approximates that of the formation compressional wave when cement is good. It would highly likely that an analyst could misjudge cement quality because the amplitudes of these modes are very small and their arrival times are very near to the formation P arrival time. It is possible to use the amplitude to estimate the thickness of the cement sheath because the variation of amplitude with thickness is strong. While the Stoneley mode (ST1) propagates in the borehole fluid, a slow Stoneley mode (ST2) appears when there is a fluid column in the annulus between the casing and formation rock. The velocity of ST2 is sensitive to the total thickness of the fluid column in the annulus independent of the location of the fluid in the casing annulus. We propose a full waveform method, which includes the utilization of the amplitude of the first arrival and also the velocity of the ST2 wave, to estimate the bonding condition of multiple interfaces. These two measurements provide more information than the current method that uses only the first arrival to evaluate the bonding interfa next to the casing.

Ionic structure in liquids confined by dielectric interfaces

NASA Astrophysics Data System (ADS)

Jing, Yufei; Jadhao, Vikram; Zwanikken, Jos W.; Olvera de la Cruz, Monica

2015-11-01

The behavior of ions in liquids confined between macromolecules determines the outcome of many nanoscale assembly processes in synthetic and biological materials such as colloidal dispersions, emulsions, hydrogels, DNA, cell membranes, and proteins. Theoretically, the macromolecule-liquid boundary is often modeled as a dielectric interface and an important quantity of interest is the ionic structure in a liquid confined between two such interfaces. The knowledge gleaned from the study of ionic structure in such models can be useful in several industrial applications, such as in the design of double-layer supercapacitors for energy storage and in the extraction of metal ions from wastewater. In this article, we compute the ionic structure in a model system of electrolyte confined by two planar dielectric interfaces using molecular dynamics simulations and liquid state theory. We explore the effects of high electrolyte concentrations, multivalent ions, dielectric contrasts, and external electric field on the ionic distributions. We observe the presence of non-monotonic ionic density profiles leading to a layered structure in the fluid which is attributed to the competition between electrostatic and steric (entropic) interactions. We find that thermal forces that arise from symmetry breaking at the interfaces can have a profound effect on the ionic structure and can oftentimes overwhelm the influence of the dielectric discontinuity. The combined effect of ionic correlations and inhomogeneous dielectric permittivity significantly changes the character of the effective interaction between the two interfaces.

Numerical Simulation of Multiphase Magnetohydrodynamic Flow and Deformation of Electrolyte-Metal Interface in Aluminum Electrolysis Cells

NASA Astrophysics Data System (ADS)

Hua, Jinsong; Rudshaug, Magne; Droste, Christian; Jorgensen, Robert; Giskeodegard, Nils-Haavard

2018-06-01

A computational fluid dynamics based multiphase magnetohydrodynamic (MHD) flow model for simulating the melt flow and bath-metal interface deformation in realistic aluminum reduction cells is presented. The model accounts for the complex physics of the MHD problem in aluminum reduction cells by coupling two immiscible fluids, electromagnetic field, Lorentz force, flow turbulence, and complex cell geometry with large length scale. Especially, the deformation of bath-metal interface is tracked directly in the simulation, and the condition of constant anode-cathode distance (ACD) is maintained by moving anode bottom dynamically with the deforming bath-metal interface. The metal pad deformation and melt flow predicted by the current model are compared to the predictions using a simplified model where the bath-metal interface is assumed flat. The effects of the induced electric current due to fluid flow and the magnetic field due to the interior cell current on the metal pad deformation and melt flow are investigated. The presented model extends the conventional simplified box model by including detailed cell geometry such as the ledge profile and all channels (side, central, and cross-channels). The simulations show the model sensitivity to different side ledge profiles and the cross-channel width by comparing the predicted melt flow and metal pad heaving. In addition, the model dependencies upon the reduction cell operation conditions such as ACD, current distribution on cathode surface and open/closed channel top, are discussed.

Experimental study of an isochorically heated heterogeneous interface. A progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fernandez, Juan Carlos

2015-08-20

Outline of the presentation: Studying possible mix / interface motion between heterogeneous low/high Z interfaces driven by 2-fluid or kinetic plasma effects (Heated to few eV, Sharp (sub µm) interface); Isochoric heating to initialize interface done with Al quasimonoenergetic ion beams on Trident; Have measured isochoric heating in individual materials intended for compound targets; Fielded experiments on Trident to measure interface motion (Gold-diamond, tin-aluminium); Measured heated-sample temperature with streaked optical pyrometry (SOP) (UT Austin led (research contract), SOP tests → heating uniformity Vs thickness on Al foils. Results are being analyzed.

Well-posedness of the Cauchy problem for models of large amplitude internal waves

NASA Astrophysics Data System (ADS)

Guyenne, Philippe; Lannes, David; Saut, Jean-Claude

2010-02-01

We consider in this paper the 'shallow-water/shallow-water' asymptotic model obtained in Choi and Camassa (1999 J. Fluid Mech. 396 1-36), Craig et al (2005 Commun. Pure. Appl. Math. 58 1587-641) (one-dimensional interface) and Bona et al (2008 J. Math. Pures Appl. 89 538-66) (two-dimensional interface) from the two-layer system with rigid lid, for the description of large amplitude internal waves at the interface of two layers of immiscible fluids of different densities. For one-dimensional interfaces, this system is of hyperbolic type and its local well-posedness does not raise serious difficulties, although other issues (blow-up, loss of hyperbolicity, etc) turn out to be delicate. For two-dimensional interfaces, the system is nonlocal. Nevertheless, we prove that it conserves some properties of 'hyperbolic type' and show that the associated Cauchy problem is locally well posed in suitable Sobolev classes provided some natural restrictions are imposed on the data. These results are illustrated by numerical simulations with emphasis on the formation of shock waves.

Extension of lattice Boltzmann flux solver for simulation of compressible multi-component flows

NASA Astrophysics Data System (ADS)

Yang, Li-Ming; Shu, Chang; Yang, Wen-Ming; Wang, Yan

2018-05-01

The lattice Boltzmann flux solver (LBFS), which was presented by Shu and his coworkers for solving compressible fluid flow problems, is extended to simulate compressible multi-component flows in this work. To solve the two-phase gas-liquid problems, the model equations with stiffened gas equation of state are adopted. In this model, two additional non-conservative equations are introduced to represent the material interfaces, apart from the classical Euler equations. We first convert the interface equations into the full conservative form by applying the mass equation. After that, we calculate the numerical fluxes of the classical Euler equations by the existing LBFS and the numerical fluxes of the interface equations by the passive scalar approach. Once all the numerical fluxes at the cell interface are obtained, the conservative variables at cell centers can be updated by marching the equations in time and the material interfaces can be identified via the distributions of the additional variables. The numerical accuracy and stability of present scheme are validated by its application to several compressible multi-component fluid flow problems.

Experimental study of the solid-liquid interface in a yield-stress fluid flow upstream of a step

NASA Astrophysics Data System (ADS)

Luu, Li-Hua; Pierre, Philippe; Guillaume, Chambon

2014-11-01

We present an experimental study where a yield-stress fluid is implemented to carefully examine the interface between a liquid-like unyielded region and a solid-like yielded region. The studied hydrodynamics consists of a rectangular pipe-flow disturbed by the presence of a step. Upstream of the step, a solid-liquid interface between a dead zone and a flow zone appears. This configuration can both model geophysical erosion phenomenon in debris flows or find applications for industrial extrusion processes. We aim to investigate the dominant physical mechanism underlying the formation of the static domain, by combining the rheological characterization of the yield-stress fluid with local measurements of the related hydrodynamic parameters. In this work, we use a model fluid, namely polymer micro-gel Carbopol, that exhibits a Hershel-Bulkley viscoplastic rheology. Exploiting the fluid transparency, the flow is monitored by Particle Image Velocimetry thanks to internal visualization technique. In particular, we demonstrate that the flow above the dead zone roughly behaves as a plug flow whose velocity profile can successfully be described by a Poiseuille equation including a Hershel-Bulkley rheology (PHB theory), with exception of a thin zone at the close vicinity of the static domain. The border inside the flow zone above which the so-called PHB flow starts, is found to be the same regardless of the flow rate and to move with a constant velocity that increases with the flow rate. We interpret this feature as a slip frontier.

Interfacial instabilities in vibrated fluids

NASA Astrophysics Data System (ADS)

Porter, Jeff; Laverón-Simavilla, Ana; Tinao Perez-Miravete, Ignacio; Fernandez Fraile, Jose Javier

2016-07-01

Vibrations induce a range of different interfacial phenomena in fluid systems depending on the frequency and orientation of the forcing. With gravity, (large) interfaces are approximately flat and there is a qualitative difference between vertical and horizontal forcing. Sufficient vertical forcing produces subharmonic standing waves (Faraday waves) that extend over the whole interface. Horizontal forcing can excite both localized and extended interfacial phenomena. The vibrating solid boundaries act as wavemakers to excite traveling waves (or sloshing modes at low frequencies) but they also drive evanescent bulk modes whose oscillatory pressure gradient can parametrically excite subharmonic surface waves like cross-waves. Depending on the magnitude of the damping and the aspect ratio of the container, these locally generated surfaces waves may interact in the interior resulting in temporal modulation and other complex dynamics. In the case where the interface separates two fluids of different density in, for example, a rectangular container, the mass transfer due to vertical motion near the endwalls requires a counterflow in the interior region that can lead to a Kelvin-Helmholtz type instability and a ``frozen wave" pattern. In microgravity, the dominance of surface forces favors non-flat equilibrium configurations and the distinction between vertical and horizontal applied forcing can be lost. Hysteresis and multiplicity of solutions are more common, especially in non-wetting systems where disconnected (partial) volumes of fluid can be established. Furthermore, the vibrational field contributes a dynamic pressure term that competes with surface tension to select the (time averaged) shape of the surface. These new (quasi-static) surface configurations, known as vibroequilibria, can differ substantially from the hydrostatic state. There is a tendency for the interface to orient perpendicular to the vibrational axis and, in some cases, a bulge or cavity is induced that leads to splitting (fluid separation). We investigate the interaction of these prominent interfacial instabilities in the absence of gravity, concentrating on harmonically vibrated rectangular containers of fluid. We compare vibroequilibria theory with direct numerical simulations and consider the effect of surfaces waves, which can excite sloshing motion of the vibroequilibria. We systematically investigate the saddle-node bifurcation experienced by a symmetric singly connected vibroequilibria solution, for sufficiently deep containers, as forcing is increased. Beyond this instability, the fluid rapidly separates into (at least) two distinct masses. Pronounced hysteresis is associated with this transition, even in the presence of gravity. The interaction of vibroequilibria and frozen waves is investigated in two-fluid systems. Preparations for a parabolic flight experiment on fluids vibrated at high frequencies are discussed.

Computer program MCAP-TOSS calculates steady-state fluid dynamics of coolant in parallel channels and temperature distribution in surrounding heat-generating solid

NASA Technical Reports Server (NTRS)

Lee, A. Y.

1967-01-01

Computer program calculates the steady state fluid distribution, temperature rise, and pressure drop of a coolant, the material temperature distribution of a heat generating solid, and the heat flux distributions at the fluid-solid interfaces. It performs the necessary iterations automatically within the computer, in one machine run.

A well-posed numerical method to track isolated conformal map singularities in Hele-Shaw flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baker, G.; Siegel, M.; Tanveer, S.

1995-09-01

We present a new numerical method for calculating an evolving 2D Hele-Shaw interface when surface tension effects are neglected. In the case where the flow is directed from the less viscous fluid into the more viscous fluid, the motion of the interface is ill-posed; small deviations in the initial condition will produce significant changes in the ensuing motion. The situation is disastrous for numerical computation, as small roundoff errors can quickly lead to large inaccuracies in the computed solution. Our method of computation is most easily formulated using a conformal map from the fluid domain into a unit disk. Themore » method relies on analytically continuing the initial data and equations of motion into the region exterior to the disk, where the evolution problem becomes well-posed. The equations are then numerically solved in the extended domain. The presence of singularities in the conformal map outside of the disk introduces specific structures along the fluid interface. Our method can explicitly track the location of isolated pole and branch point singularities, allowing us to draw connections between the development of interfacial patterns and the motion of singularities as they approach the unit disk. In particular, we are able to relate physical features such as finger shape, side-branch formation, and competition between fingers to the nature and location of the singularities. The usefulness of this method in studying the formation of topological singularities (self-intersections of the interface) is also pointed out. 47 refs., 10 figs., 1 tab.« less

Electric field induced self-assembly of monolayers of gold nanoparticles for surface enhanced Raman scattering applications

NASA Astrophysics Data System (ADS)

Das, Suchandra; Musunuri, Naga; Kucheryavy, Pavel; Lockard, Jenny; Fischer, Ian; Singh, Pushpendra; New Jersey Institute of Technology Collaboration; Rutgers University Newark Collaboration

2017-11-01

We present a technique that uses an electric field in the direction normal to the interface for self-assembling monolayers of gold nanoparticles on fluid-liquid interfaces and freezing these monolayers onto the surface of a flexible thin film. The electric field gives rise to dipole-dipole and capillary forces which cause the particles to arrange in a triangular pattern. The technique involves assembling the monolayer on the interface between a UV-curable resin and another fluid by applying an electric field, and then curing the resin by applying UV light. The monolayer becomes embedded on the surface of the solidified resin film. We are using these films for surface enhanced Raman scattering (SERS) applications. Initial measurements indicate improved performance over commercially available SERS substrates.

Influence of granulometry in the Hurst exponent of air liquid interfaces formed during capillary rising in a granular media

NASA Astrophysics Data System (ADS)

Gontijo, Guilherme L.; Souza, Flávia B.; Braga, Rafael M. L.; Silva, Pedro H. E.; Correia, Maury D.; Atman, A. P. F.

2017-06-01

We report results concerning the fractal dimension of a air/fluid interface formed during the capillary rising of a fluid into a dense granular media. The system consists in a modified Hele-Shaw cell filled with grains at different granulometries and confined in a narrow gap between the glass plates. The system is then placed onto a water reservoir, and the liquid penetrates the medium due to capillary forces. We measure the Hurst exponent of the liquid/air interface with help of image processing, and follow the temporal evolution of the profiles. We observe that the Hurst exponent can be related with the granulometry, but the range of values are odd to the predicted values from models or theory.

Musical Interfaces: Visualization and Reconstruction of Music with a Microfluidic Two-Phase Flow

PubMed Central

Mak, Sze Yi; Li, Zida; Frere, Arnaud; Chan, Tat Chuen; Shum, Ho Cheung

2014-01-01

Detection of sound wave in fluids can hardly be realized because of the lack of approaches to visualize the very minute sound-induced fluid motion. In this paper, we demonstrate the first direct visualization of music in the form of ripples at a microfluidic aqueous-aqueous interface with an ultra-low interfacial tension. The interfaces respond to sound of different frequency and amplitude robustly with sufficiently precise time resolution for the recording of musical notes and even subsequent reconstruction with high fidelity. Our work shows the possibility of sensing and transmitting vibrations as tiny as those induced by sound. This robust control of the interfacial dynamics enables a platform for investigating the mechanical properties of microstructures and for studying frequency-dependent phenomena, for example, in biological systems. PMID:25327509

Coherent structures over Super Hydrophobic and Liquid Infused Surfaces

NASA Astrophysics Data System (ADS)

Arenas, Isnardo; Bernardini, Matteo; Leonardi, Stefano

2017-11-01

Numerical Simulations of two superposed fluids in a turbulent channel have been performed. Both walls of the channel are made of longitudinal riblets with a gas fractions of 0.5 and several pitch values p+ = 18 , 36 , 72 , 144 . For Liquid Infused Surfaces, LIS, with a viscosity ratio m =μ1 /μ2 = 0.4 (where the subscripts 1 and 2 indicate the fluid in the cavities and the overlying fluid respectively) two cases have been considered varying the Weber number: We = 0 , implying an interface sustained by the surface tension and We = 1000 with the dynamics of the interface between the two fluids modeled with a Level Set Approach. Results are compared to the case mimicking water over air (Super hydrophobic Surface SHS m = 0.02) and We = 0 . A smooth channel with one fluid only at Reτ = 180 is used as reference and to assess how the LIS and SHS modify coherent structures near the wall. Numerical simulations were performed on XSEDE TACC under Grant CTS070066. This work was supported by ONR MURI Grants N00014-12-01-0875 and N00014-12-01-0962.

Novel on-demand droplet generation for selective fluid sample extraction

PubMed Central

Lin, Robert; Fisher, Jeffery S.; Simon, Melinda G.; Lee, Abraham P.

2012-01-01

A novel microfluidic device enabling selective generation of droplets and encapsulation of targets is presented. Unlike conventional methods, the presented mechanism generates droplets with unique selectivity by utilizing a K-junction design. The K-junction is a modified version of the classic T-junction with an added leg that serves as the exit channel for waste. The dispersed phase fluid enters from one diagonal of the K and exits the other diagonal while the continuous phase travels in the straight leg of the K. The intersection forms an interface that allows the dispersed phase to be controllably injected through actuation of an elastomer membrane located above the inlet channel near the interface. We have characterized two critical components in controlling the droplet size—membrane actuation pressure and timing as well as identified the region of fluid in which the droplet will be formed. This scheme will have applications in fluid sampling processes and selective encapsulation of materials. Selective encapsulation of a single cell from the dispersed phase fluid is demonstrated as an example of functionality of this design. PMID:22655015

A numerical model of two-phase flow at the micro-scale using the volume-of-fluid method

NASA Astrophysics Data System (ADS)

Shams, Mosayeb; Raeini, Ali Q.; Blunt, Martin J.; Bijeljic, Branko

2018-03-01

This study presents a simple and robust numerical scheme to model two-phase flow in porous media where capillary forces dominate over viscous effects. The volume-of-fluid method is employed to capture the fluid-fluid interface whose dynamics is explicitly described based on a finite volume discretization of the Navier-Stokes equations. Interfacial forces are calculated directly on reconstructed interface elements such that the total curvature is preserved. The computed interfacial forces are explicitly added to the Navier-Stokes equations using a sharp formulation which effectively eliminates spurious currents. The stability and accuracy of the implemented scheme is validated on several two- and three-dimensional test cases, which indicate the capability of the method to model two-phase flow processes at the micro-scale. In particular we show how the co-current flow of two viscous fluids leads to greatly enhanced flow conductance for the wetting phase in corners of the pore space, compared to a case where the non-wetting phase is an inviscid gas.

Microscopic aspects of wetting using classical density functional theory

NASA Astrophysics Data System (ADS)

Yatsyshin, P.; Durán-Olivencia, M.-A.; Kalliadasis, S.

2018-07-01

Wetting is a rather efficient mechanism for nucleation of a phase (typically liquid) on the interface between two other phases (typically solid and gas). In many experimentally accessible cases of wetting, the interplay between the substrate structure, and the fluid–fluid and fluid–substrate intermolecular interactions brings about an entire ‘zoo’ of possible fluid configurations, such as liquid films with a thickness of a few nanometers, liquid nanodrops and liquid bridges. These fluid configurations are often associated with phase transitions occurring at the solid–gas interface and at lengths of just several molecular diameters away from the substrate. In this special issue article, we demonstrate how a fully microscopic classical density-functional framework can be applied to the efficient, rational and systematic exploration of the rich phase space of wetting phenomena. We consider a number of model prototype systems such as wetting on a planar wall, a chemically patterned wall and a wedge. Through density-functional computations we demonstrate that for these simply structured substrates the behaviour of the solid–gas interface is already highly complex and non-trivial.

Dynamics of two-phase interfaces and surface tensions: A density-functional theory perspective

NASA Astrophysics Data System (ADS)

Yatsyshin, Petr; Sibley, David N.; Duran-Olivencia, Miguel A.; Kalliadasis, Serafim

2016-11-01

Classical density functional theory (DFT) is a statistical mechanical framework for the description of fluids at the nanoscale, where the inhomogeneity of the fluid structure needs to be carefully accounted for. By expressing the grand free-energy of the fluid as a functional of the one-body density, DFT offers a theoretically consistent and computationally accessible way to obtain two-phase interfaces and respective interfacial tensions in a ternary solid-liquid-gas system. The dynamic version of DFT (DDFT) can be rigorously derived from the Smoluchowsky picture of the dynamics of colloidal particles in a solvent. It is generally agreed that DDFT can capture the diffusion-driven evolution of many soft-matter systems. In this context, we use DDFT to investigate the dynamic behaviour of two-phase interfaces in both equilibrium and dynamic wetting and discuss the possibility of defining a time-dependent surface tension, which still remains in debate. We acknowledge financial support from the European Research Council via Advanced Grant No. 247031 and from the Engineering and Physical Sciences Research Council of the UK via Grants No. EP/L027186 and EP/L020564.

Vibration isolation technology: Sensitivity of selected classes of experiments to residual accelerations

NASA Technical Reports Server (NTRS)

Alexander, J. Iwan D.

1990-01-01

The solution was sought of a 2-D axisymmetric moving boundary problem for the sensitivity of isothermal and nonisothermal liquid columns and the sensitivity of thermo-capillary flows to buoyancy driven convection caused by residual accelerations. The sensitivity of a variety of space experiments to residual accelerations are examined. In all the cases discussed, the sensitivity is related to the dynamic response of a fluid. In some cases the sensitivity can be defined by the magnitude of the response of the velocity field. This response may involve motion of the fluid associated with internal density gradients, or the motion of a free liquid surface. For fluids with internal density gradients, the type of acceleration to which the experiment is sensitive will depend on whether buoyancy driven convection must be small in comparison to other types of fluid motion (such as thermocapillary flow), or fluid motion must be suppressed or eliminated (such as in diffusion studies, or directional solidification experiments). The effect of the velocity on the composition and temperature field must be considered, particularly in the vicinity of the melt crystal interface. As far as the response to transient disturbances is concerned the sensitivity is determined by both the magnitude and frequency the acceleration and the characteristic momentum and solute diffusion times.

Effects of aperture variability and wettability on immiscible displacement in fractures

NASA Astrophysics Data System (ADS)

Yang, Zhibing; Méheust, Yves; Neuweiler, Insa

2017-04-01

Fluid-fluid displacement in porous and fractured media is an important process. Understanding and controlling this process is key to many practical applications, such as hydrocarbon recovery, geological storage of CO2, groundwater remediation, etc. Here, we numerically study fluid-fluid displacement in rough-walled fractures. We focus on the combined effect of wettability and fracture surface topography on displacement patterns and interface growth. We develop a novel numerical model to simulate dynamic fluid invasion under the influence of capillary and viscous forces. The capillary force is calculated using the two principal curvatures (aperture-induced curvature and in-plane curvature) at the fluid-fluid interface, and the viscous force is taken into account by solving the fluid pressure distribution. The aperture field of a fracture is represented by a spatially correlated random field, which is described by a power spectrum for the fracture wall topography and a cutoff wave-length. We numerically produce displacement patterns ranging from stable displacement, capillary fingering, and viscous fingering, as well as the transitions between them. We show that both reducing the aperture variability and increasing the contact angle (from drainage to weak imbibition) stabilize the displacement due to the influence of the in-plane curvature, an effect analogous to that of the cooperative pore filling in porous media. Implications of these results will be discussed.

Effect of adsorption on the surface tensions of solid-fluid interfaces.

PubMed

Ward, C A; Wu, Jiyu

2007-04-12

A method is proposed for determining the surface tensions of a solid in contact with either a liquid or a vapor. Only an equilibrium adsorption isotherm at the solid-vapor interface needs to be added to Gibbsian thermodynamics to obtain the expressions for the solid-vapor and the solid-liquid surface tensions, gamma[1](SV) and gamma[1](SL), respectively. An equilibrium adsorption isotherm relation is formulated that has the essential property of not predicting an infinite amount adsorbed when the pressure is equal to the saturation-vapor pressure. Five different solid-vapor systems from the literature are examined, and found to be well described by the new isotherm relation. The surface-tension expressions obtained from the isotherm relation are examined by determining the surface tension of the solid in the absence of adsorption, gamma[1](S0), a material property of a solid surface. The value of gamma[1](S0) can be determined by adsorbing different vapors on the same solid, determining the isotherm parameters in each case, and then from the expression for gamma[1](SV) taking the limit of the pressure vanishing to determine gamma[1](S0). From previously reported measurements of benzene and of n-hexane adsorbing on graphitized carbon, the same value of gamma[1](S0) is obtained.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fujiwara, K., E-mail: ku.fujiwara@screen.co.jp; Department of Mechanical Engineering, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871; Shibahara, M., E-mail: siba@mech.eng.osaka-u.ac.jp

A classical molecular dynamics simulation was conducted for a system composed of fluid molecules between two planar solid surfaces, and whose interactions are described by the 12-6 Lennard-Jones form. This paper presents a general description of the pressure components and interfacial tension at a fluid-solid interface obtained by the perturbative method on the basis of statistical thermodynamics, proposes a method to consider the pressure components tangential to an interface which are affected by interactions with solid atoms, and applies this method to the calculation system. The description of the perturbative method is extended to subsystems, and the local pressure componentsmore » and interfacial tension at a liquid-solid interface are obtained and examined in one- and two-dimensions. The results are compared with those obtained by two alternative methods: (a) an evaluation of the intermolecular force acting on a plane, and (b) the conventional method based on the virial expression. The accuracy of the numerical results is examined through the comparison of the results obtained by each method. The calculated local pressure components and interfacial tension of the fluid at a liquid-solid interface agreed well with the results of the two alternative methods at each local position in one dimension. In two dimensions, the results showed a characteristic profile of the tangential pressure component which depended on the direction tangential to the liquid-solid interface, which agreed with that obtained by the evaluation of the intermolecular force acting on a plane in the present study. Such good agreement suggests that the perturbative method on the basis of statistical thermodynamics used in this study is valid to obtain the local pressure components and interfacial tension at a liquid-solid interface.« less

Nanoscale Structure at Mineral-Fluid Interfaces

NASA Astrophysics Data System (ADS)

Sturchio, N. C.; Sturchio, N. C.; Fenter, P.; Cheng, L.; Park, C.; Zhang, Z.; Zhang, Z.; Nagy, K. L.; Schlegel, M. L.

2001-12-01

The nature of nanoparticles and their role in the natural environment is currently a subject of renewed interest. The high surface area (and surface area-to-volume ratio) of nanoparticles exerts a widespread influence on geochemical reactions and transport processes. A thorough understanding of the nanoscale world remains largely hypothetical, however, because of the challenges associated with characterizing nanoscale structures and processes. Recent insights gained from high-resolution synchrotron x-ray reflectivity measurements at the solid-fluid interfaces of macroscopic (i.e., mm-scale) mineral particles may provide relevant guidelines for expected nanoparticle surface structures. For example, at calcite-water and barite-water interfaces, undercoordinated surface cations bond with water species of variable protonation, and modest relaxations (to several hundredths of a nanometer) affect the outermost unit cells [1,2]. Undercoordinated tetrahedral ions at aluminosilicate surfaces also bond with water species, whereas interstitial or interlayer alkali or alkaline earth ions at the surface may readily exchange with hydronium or other ions; modest relaxations also affect the outermost unit cells [3,4]. Modulation of liquid water structure out to about one nanometer has been observed at the (001) cleavage surface of muscovite in deionized water, and may be present at other mineral-fluid interfaces [4]. Dissolution mechanisms at the orthoclase-water interface have been clarified by combining x-ray reflectivity and scanning force microscopy measurements [5]. Further progress in understanding nanoscale structures and processes at macroscopic mineral-water interfaces is likely to benefit nanoparticle studies. [1] Fenter et al. (2000) Geochim. Cosmochim. Acta 64, 1221-1228. [2] Fenter et al. (2001) J. Phys. Chem. B 105(34), 8112-8119. [3] Fenter et al. (2000) Geochim. Cosmochim. Acta 64, 3663-3673. [4] Cheng et al. (2001) Phys. Rev. Lett., (in press). [5] Teng et al. (2001) Geochim. Cosmochim. Acta 65, (in press).

IMPACT OF PHYSICAL AND CHEMICAL MUD CONTAMINATION ON WELLBORE CEMENT- FORMATION SHEAR BOND STRENGTH Authors: Arome Oyibo1 and Mileva Radonjic1 * 1. Craft and Hawkins Department of Petroleum Engineering, 2131 Patrick F. Taylor Hall, Louisiana State University, Baton Rouge, LA 70803, aoyibo1@tigers.lsu.edu, mileva@lsu.edu

NASA Astrophysics Data System (ADS)

Oyibo, A. E.

2013-12-01

Wellbore cement has been used to provide well integrity through zonal isolation in oil & gas wells and geothermal wells. Cementing is also used to provide mechanical support for the casing and protect the casing from corrosive fluids. Failure of cement could be caused by several factors ranging from poor cementing, failure to completely displace the drilling fluids to failure on the path of the casing. A failed cement job could result in creation of cracks and micro annulus through which produced fluids could migrate to the surface which could lead to sustained casing pressure, contamination of fresh water aquifer and blow out in some cases. In addition, cement failures could risk the release of chemicals substances from hydraulic fracturing into fresh water aquifer during the injection process. To achieve proper cementing, the drilling fluid should be completely displaced by the cement slurry. However, this is hard to achieve in practice, some mud is usually left on the wellbore which ends up contaminating the cement afterwards. The purpose of this experimental study is to investigate the impact of both physical and chemical mud contaminations on cement-formation bond strength for different types of formations. Physical contamination occurs when drilling fluids (mud) dries on the surface of the formation forming a mud cake. Chemical contamination on the other hand occurs when the drilling fluids which is still in the liquid form interacts chemically with the cement during a cementing job. We investigated the impact of the contamination on the shear bond strength and the changes in the mineralogy of the cement at the cement-formation interface to ascertain the impact of the contamination on the cement-formation bond strength. Berea sandstone and clay rich shale cores were bonded with cement cores with the cement-formation contaminated either physically or chemically. For the physically contaminated composite cores, we have 3 different sample designs: clean/not contaminated, scrapped and washed composite cores. Similarly, for the chemically contaminated samples we had 3 different sample designs: 0%, 5% and 10% mud contaminated composite cores. Shear test were performed on the composite cores to determine the shear bond strength and the results suggested that the detrimental impact of the contamination is higher when the cores are physically contaminated i.e. when we have mud cake present at the surface of the wellbore before a cement job is performed. Also, the results showed that shear bond strength is higher for sandstone formations as compared to shale formations. Material characterization analysis was carried out to determine the micro structural changes at the cement-formation interface. The results obtained from the SEM and micro CT images taken at the bond interface confirmed that chemical contamination caused substantial changes in the spatial distribution of minerals that impacted bond strength. Keywords: Cement-Formation bond strength, mud contamination, shale, sandstone and material characterization *Corresponding author

Actively dewatering fluid-rich zones along the Costa Rica plate boundary fault

NASA Astrophysics Data System (ADS)

Bangs, N. L.; McIntosh, K. D.; Silver, E. A.; Kluesner, J. W.; Ranero, C. R.; von Huene, R.

2012-12-01

New 3D seismic reflection data reveal distinct evidence for active dewatering above a 12 km wide segment of the plate boundary fault within the Costa Rica subduction zone NW of the Osa Peninsula. In the spring of 2011 we acquired a 11 x 55 km 3D seismic reflection data set on the R/V Langseth using four 6,000 m streamers and two 3,300 in3 airgun arrays to examine the structure of the Costa Rica margin from the trench into the seismogenic zone. We can trace the plate-boundary interface from the trench across our entire survey to where the plate-boundary thrust lies > 10 km beneath the margin shelf. Approximately 20 km landward of the trench beneath the mid slope and at the updip edge of the seismogenic zone, a 12 km wide zone of the plate-boundary interface has a distinctly higher-amplitude seismic reflection than deeper or shallower segments of the fault. Directly above and potentially directly connected with this zone are high-amplitude, reversed-polarity fault-plane reflections that extend through the margin wedge and into overlying slope sediment cover. Within the slope cover, high-amplitude reversed-polarity reflections are common within the network of closely-spaced nearly vertical normal faults and several broadly spaced, more gently dipping thrust faults. These faults appear to be directing fluids vertically toward the seafloor, where numerous seafloor fluid flow indicators, such as pockmarks, mounds and ridges, and slope failure features, are distinct in multibeam and backscatter images. There are distinctly fewer seafloor and subsurface fluid flow indicators both updip and downdip of this zone. We believe these fluids come from a 12 km wide fluid-rich segment of the plate-boundary interface that is likely overpressured and has relatively low shear stress.

Investigation of Conjugate Heat Transfer in Turbine Blades and Vanes

NASA Technical Reports Server (NTRS)

Kassab, A. J.; Kapat, J. S.

2001-01-01

We report on work carried out to develop a 3-D coupled Finite Volume/BEM-based temperature forward/flux back (TFFB) coupling algorithm to solve the conjugate heat transfer (CHT) which arises naturally in analysis of systems exposed to a convective environment. Here, heat conduction within a structure is coupled to heat transfer to the external fluid which is convecting heat into or out of the solid structure. There are two basic approaches to solving coupled fluid structural systems. The first is a direct coupling where the solution of the different fields is solved simultaneously in one large set of equations. The second approach is a loose coupling strategy where each set of field equations is solved to provide boundary conditions for the other. The equations are solved in turn until an iterated convergence criterion is met at the fluid-solid interface. The loose coupling strategy is particularly attractive when coupling auxiliary field equations to computational fluid dynamics codes. We adopt the latter method in which the BEM is used to solve heat conduction inside a structure which is exposed to a convective field which in turn is resolved by solving the NASA Glenn compressible Navier-Stokes finite volume code Glenn-HT. The BEM code features constant and bi-linear discontinuous elements and an ILU-preconditioned GMRES iterative solver for the resulting non-symmetric algebraic set arising in the conduction solution. Interface of flux and temperature is enforced at the solid/fluid interface, and a radial-basis function scheme is used to interpolated information between the CFD and BEM surface grids. Additionally, relaxation is implemented in passing the fluxes from the conduction solution to the fluid solution. Results from a simple test example are reported.

Flight evaluation of Spacelab 1 payload thermal/ECS interfaces

NASA Technical Reports Server (NTRS)

Ray, C. D.; Humphries, W. R.; Patterson, W. C.

1984-01-01

The Spacelab (SL-1) thermal/Environmental Control Systems (ECS) are discussed. Preflight analyses and flight data are compared in order to validate payload to Spacelab interfaces as well as corroborate modeling/analysis techniques. In doing so, a brief description of the Spacelab 1 payload configuration and the interactive Spacelab thermal/ECS systems are given. In particular, these interfaces address equipment cooling air, thermal and fluid conditions, humidity levels, both freon and water loop temperatures and load states, as well as passive radiant environment interfaces.

Moffatt eddies at an interface

NASA Astrophysics Data System (ADS)

Shtern, Vladimir

2014-12-01

It is shown that an infinite set of eddies can develop near the interface-wall intersection in a two-fluid flow. A striking feature is that the eddy occurrence depends on from what side of the interface the flow is driven. In air-water flows where the viscosity ratio is 0.018, the eddies develop if a driving source is located on (i) the air side for , (ii) any side for , and (iii) the water side for , where is the upper interface-wall angle.

Numerical Modeling of Fluid Flow, Heat Transfer and Arc-Melt Interaction in Tungsten Inert Gas Welding

NASA Astrophysics Data System (ADS)

Li, Linmin; Li, Baokuan; Liu, Lichao; Motoyama, Yuichi

2017-04-01

The present work develops a multi-region dynamic coupling model for fluid flow, heat transfer and arc-melt interaction in tungsten inert gas (TIG) welding using the dynamic mesh technique. The arc-weld pool unified model is developed on basis of magnetohydrodynamic (MHD) equations and the interface is tracked using the dynamic mesh method. The numerical model for arc is firstly validated by comparing the calculated temperature profiles and essential results with the former experimental data. For weld pool convection solution, the drag, Marangoni, buoyancy and electromagnetic forces are separately validated, and then taken into account. Moreover, the model considering interface deformation is adopted in a stationary TIG welding process with SUS304 stainless steel and the effect of interface deformation is investigated. The depression of weld pool center and the lifting of pool periphery are both predicted. The results show that the weld pool shape calculated with considering the interface deformation is more accurate.

Two-Fluid Models and Interfacial Area Transport in Microgravity Condition

NASA Technical Reports Server (NTRS)

Ishii, Mamoru; Sun, Xiao-Dong; Vasavada, Shilp

2004-01-01

The objective of the present study is to develop a two-fluid model formulation with interfacial area transport equation applicable for microgravity conditions. The new model is expected to make a leapfrog improvement by furnishing the constitutive relations for the interfacial interaction terms with the interfacial area transport equation, which can dynamically model the changes of the interfacial structures. In the first year of this three-year project supported by the U.S. NASA, Office of Biological and Physics Research, the primary focus is to design and construct a ground-based, microgravity two-phase flow simulation facility, in which two immiscible fluids with close density will be used. In predicting the two-phase flow behaviors in any two-phase flow system, the interfacial transfer terms are among the most essential factors in the modeling. These interfacial transfer terms in a two-fluid model specify the rate of phase change, momentum exchange, and energy transfer at the interface between the two phases. For the two-phase flow under the microgravity condition, the stability of the fluid particle interface and the interfacial structures are quite different from those under normal gravity condition. The flow structure may not reach an equilibrium condition and the two fluids may be loosely coupled such that the inertia terms of each fluid should be considered separately by use of the two-fluid model. Previous studies indicated that, unless phase-interaction terms are accurately modeled in the two-fluid model, the complex modeling does not necessarily warrant an accurate solution.

Fluid Dynamics Problems of Vehicles Operating Near or in the Air-Sea Interface (Problemes de Dynamique des Fluides des Vehicules Evoluant dans ou pres de L’interface Air-Mer).

DTIC Science & Technology

1999-02-01

articulated rotor systems, the rotor blade can deflect several feet and contact the fuselage of the helicopter, resulting in a "tunnel strike " in...tandem rotor configurations; or the tailboom, resulting in a "tailboom strike " in single rotor configurations. The H-46 Sea Knight, a tandem rotor...helicopter used by the U.S. Navy and Marines, has encountered over 100 tunnel strikes since 1964 and still occasionally experiences them. Most tunnel

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Velikovich, A. L.; Schmit, P. F.

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. In the limit of small shell thickness, exact thin-shell perturbation equations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Velikovich, A. L.; Schmit, P. F.

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE PAGES

Velikovich, A. L.; Schmit, P. F.

2015-12-28

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Impact of mineral precipitation on flow and mixing in porous media determined by microcomputed tomography and MRI

DOE PAGES

Bray, Joshua M.; Lauchnor, Ellen G.; Redden, George D.; ...

2016-12-21

Here, precipitation reactions in porous media influence transport properties of the environment and can control advective and dispersive transport. In subsurface environments, mixing of saline groundwater or injected solutions for remediation with fresh groundwater can induce supersaturation of constituents and drive precipitation reactions. Magnetic resonance imaging (MRI) and micro-computed tomography (µ-CT) were employed as complimentary techniques to evaluate advection, dispersion and formation of precipitate in a 3D porous media flow cell. Two parallel fluids were flowed concentrically through the porous media under two flow rate conditions with Na 2CO 3 and CaCl 2 in the inner and outer fluids, respectively.more » Upon mixing, calcium carbonate became supersaturated and formed a precipitate at the interface of the two fluids. Spatial maps of changing local velocity fields and dispersion in the flow cell were generated from MRI, while high resolution imaging of the precipitate formed in the porous media was achieved via µ-CT imaging. Formation of a precipitate layer minimized dispersive and advective transport between the two fluids and the shape of the precipitation was influenced by the flow rate condition.« less

Impact of mineral precipitation on flow and mixing in porous media determined by microcomputed tomography and MRI

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bray, Joshua M.; Lauchnor, Ellen G.; Redden, George D.

Here, precipitation reactions in porous media influence transport properties of the environment and can control advective and dispersive transport. In subsurface environments, mixing of saline groundwater or injected solutions for remediation with fresh groundwater can induce supersaturation of constituents and drive precipitation reactions. Magnetic resonance imaging (MRI) and micro-computed tomography (µ-CT) were employed as complimentary techniques to evaluate advection, dispersion and formation of precipitate in a 3D porous media flow cell. Two parallel fluids were flowed concentrically through the porous media under two flow rate conditions with Na 2CO 3 and CaCl 2 in the inner and outer fluids, respectively.more » Upon mixing, calcium carbonate became supersaturated and formed a precipitate at the interface of the two fluids. Spatial maps of changing local velocity fields and dispersion in the flow cell were generated from MRI, while high resolution imaging of the precipitate formed in the porous media was achieved via µ-CT imaging. Formation of a precipitate layer minimized dispersive and advective transport between the two fluids and the shape of the precipitation was influenced by the flow rate condition.« less

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

NASA Astrophysics Data System (ADS)

Velikovich, A. L.; Schmit, P. F.

2015-12-01

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining the "instantaneous growth rate" are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. In the limit of small shell thickness, exact thin-shell perturbation equations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].

Optimal probes for withdrawal of uncontaminated fluid samples

NASA Astrophysics Data System (ADS)

Sherwood, J. D.

2005-08-01

Withdrawal of fluid by a composite probe pushed against the face z =0 of a porous half-space z >0 is modeled assuming incompressible Darcy flow. The probe is circular, of radius a, with an inner sampling section of radius αa and a concentric outer guard probe αa βa is saturated with fluid 2; the two fluids have the same viscosity. It is assumed that the interface between the two fluids is sharp and remains so as it moves through the rock. The pressure in the probe is lower than that of the pore fluid in the rock, so that the fluid interface is convected with the fluids towards the probe. This idealized axisymmetric problem is solved numerically, and it is shown that an analysis based on far-field spherical flow towards a point sink is a good approximation when the nondimensional depth of fluid 1 is large, i.e., β ≫1. The inner sampling probe eventually produces pure fluid 2, and this technique has been proposed for sampling pore fluids in rock surrounding an oil well [A. Hrametz, C. Gardner, M. Wais, and M. Proett, U.S. Patent No. 6,301,959 B1 (16 October 2001)]. Fluid 1 is drilling fluid filtrate, which has displaced the original pore fluid (fluid 2), a pure sample of which is required. The time required to collect an uncontaminated sample of original pore fluid can be minimized by a suitable choice of the probe geometry α [J. Sherwood, J. Fitzgerald and B. Hill, U.S. Patent No. 6,719,049 B2 (13 April 2004)]. It is shown that the optimal choice of α depends on the depth of filtrate invasion β and the volume of sample required.

Electric Field Induced Interfacial Instabilities

NASA Technical Reports Server (NTRS)

Kusner, Robert E.; Min, Kyung Yang; Wu, Xiao-lun; Onuki, Akira

1999-01-01

The study of the interface in a charge-free, critical and near-critical binary fluid in the presence of an externally applied electric field is presented. At sufficiently large fields, the interface between the two phases of the binary fluid should become unstable and exhibit an undulation with a predefined wavelength on the order of the capillary length. As the critical point is approached, this wavelength is reduced, potentially approaching length-scales such as the correlation length or critical nucleation radius. At this point the critical properties of the system may be affected. In this paper, the flat interface of a marginally polar binary fluid mixture is stressed by a perpendicular alternating electric field and the resulting instability is characterized by the critical electric field E(sub c) and the pattern observed. The character of the surface dynamics at the onset of instability is found to be strongly dependent on the frequency f of the field applied. The plot of E(sub c) vs. f for a fixed temperature shows a sigmoidal shape, whose low and high frequency limits are well described by a power-law relationship, E(sub c) = epsilon(exp zeta) with zeta = 0.35 and zeta = 0.08, respectively. The low-limit exponent compares well with the value zeta = 4 for a system of conducting and non-conducting fluids. On the other hand, the high-limit exponent coincides with what was first predicted by Onuki. The instability manifests itself as the conducting phase penetrates the non-conducting phase. As the frequency increases, the shape of the pattern changes from an array of bifurcating strings to an array of column-like (or rod-like) protrusions, each of which spans the space between the plane interface and one of the electrodes. For an extremely high frequency, the disturbance quickly grows into a parabolic cone pointing toward the upper plate. As a result, the interface itself changes its shape from that of a plane to that of a high sloping pyramid.

Metasomatism, Fluid Overpressure and Brecciation at the Slab-Mantle Interface: Insights from the Livingstone Fault, New Zealand

NASA Astrophysics Data System (ADS)

Tarling, M.; Smith, S. A. F.; Scott, J.

2017-12-01

Juxtaposition of mantle peridotite and serpentinite against quartzofeldspathic and mafic schists occurs along the shallow slab-mantle interface in some subduction zones. This part of the subduction interface has been invoked as a possible source region of episodic tremor and slow slip, yet geological observations of fault zone structures and chemical reactions pertinent to this region are quite rare. The >1000 km long Livingstone Fault in New Zealand is a superbly exposed fault zone that provides a suitable analogue (both in terms of scale and the rock types involved) for the shallow slab-mantle interface. The fault is characterized by a foliated and highly sheared serpentinite mélange tens to several hundreds of meters wide that separates (partially serpentinised) peridotites from quartzofeldspathic schists. Talc- and tremolite-forming metasomatic reactions occurred along the margins of the mélange and around entrained pods due to mixing of serpentinite with silica- and calcium-rich fluids derived from the adjacent quartzofeldspathic schist. The metasomatic reactions generated significant volumes of water at the melange-schist contact that became trapped between the two relatively impermeable fault zone lithologies. On the schist side of the contact, brittle faulting was promoted by the formation of a laterally-continuous silicified zone up to tens of metres wide. On the melange side, a zone up to tens of metres wide of `crackle-breccias' containing veined stockworks of tremolite indicates periodic increases of pore pressure sufficient to cause hydraulic fracture of serpentinite. The crackle-breccias are multi-generational indicating that this process was episodic. Sr and Nd isotope data and permeability calculations suggest that the episodic brecciation process was critical to the transfer of fluids across the melange. Our observations suggest that fluid-producing metasomatic reactions along the shallow slab-mantle interface may contribute to the tremor signal by triggering brecciation events and promoting brittle failure in serpentinite and schist.

Modelling Earthquakes Using a Poro-Elastic Two-Phase Flow Formulation

NASA Astrophysics Data System (ADS)

Petrini, C.; Gerya, T.; van Dinther, Y.; Connolly, J. A.; Madonna, C.

2017-12-01

Seismicity along subduction zones ranges from large devastating megathrust earthquakes to aseismic slow slip events. These different slip phenomena are widely believed to be influenced by fluids and interactions of fluids with the host rock. To understand the slip or strain mode along the megathrust interface, it is thus crucial to understand the role of fluids. Considering the spatiotemporal limitations of observations, a promising approach is to develop a numerical model that couples the deformation of both fluids and solids in a single framework. The objective of this study is the development of such a seismo-hydro-mechanical approach and the subsequent identification of parameters that control the mode of slip. We present a newly developed finite difference visco-elasto-plastic numerical code with marker-in-cell technique, which fully couples inertial mechanical deformation and fluid flow. It allows for the accurate treatment of localised brittle/plastic deformation through global iterations. To accurately simulate both long- and short-term deformation an adaptive time step is introduced. This makes it possible to resolve seismic event with time steps on the order of milliseconds. We use this new tool to investigate how the presence of fluids in the pore space of an visco-elasto-brittle/plastic (de)compacting rock matrix affects elastic stress accumulation and release along a fluid-bearing subduction interface. The model is able to simulate spontaneous quasi-periodic seismic events, nucleating near the brittle-ductile transition zone, along self-consistently forming highly localized ruptures, which accommodate shear displacement between two plates. The generated elastic rebound events show slip velocities on the order of m/s. The governing gradual strength decrease along the propagating fracture is related to a drop in total pressure due to shear localization in combination with an increase in fluid pressure due to elastic compaction of the pore space in a rock with low permeability (6e-19 m2). Reduction of the differential pressure decreases brittle/plastic strength of fluid-bearing rocks along the rupture, thus providing a dynamic feedback mechanism for the accumulated elastic stress release at the subduction interface.

Superfluid Helium Tanker (SFHT) study

NASA Technical Reports Server (NTRS)

1988-01-01

The accomplishments and recommendations of the two-phase Superfluid Helium Tanker (SFHT) study are presented. During the first phase of the study, the emphasis was on defining a comprehensive set of user requirements, establishing SFHT interface parameters and design requirements, and selecting a fluid subsystem design concept. During the second phase, an overall system design concept was constructed based on appropriate analyses and more detailed definition of requirements. Modifications needed to extend the baseline for use with cryogens other than SFHT have been determined, and technology development needs related to the recommended design have been assessed.

The inner CSF–brain barrier: developmentally controlled access to the brain via intercellular junctions

PubMed Central

Whish, Sophie; Dziegielewska, Katarzyna M.; Møllgård, Kjeld; Noor, Natassya M.; Liddelow, Shane A.; Habgood, Mark D.; Richardson, Samantha J.; Saunders, Norman R.

2015-01-01

In the adult the interface between the cerebrospinal fluid and the brain is lined by the ependymal cells, which are joined by gap junctions. These intercellular connections do not provide a diffusional restrain between the two compartments. However, during development this interface, initially consisting of neuroepithelial cells and later radial glial cells, is characterized by “strap” junctions, which limit the exchange of different sized molecules between cerebrospinal fluid and the brain parenchyma. Here we provide a systematic study of permeability properties of this inner cerebrospinal fluid-brain barrier during mouse development from embryonic day, E17 until adult. Results show that at fetal stages exchange across this barrier is restricted to the smallest molecules (286Da) and the diffusional restraint is progressively removed as the brain develops. By postnatal day P20, molecules the size of plasma proteins (70 kDa) diffuse freely. Transcriptomic analysis of junctional proteins present in the cerebrospinal fluid-brain interface showed expression of adherens junctional proteins, actins, cadherins and catenins changing in a development manner consistent with the observed changes in the permeability studies. Gap junction proteins were only identified in the adult as was claudin-11. Immunohistochemistry was used to localize at the cellular level some of the adherens junctional proteins of genes identified from transcriptomic analysis. N-cadherin, β - and α-catenin immunoreactivity was detected outlining the inner CSF-brain interface from E16; most of these markers were not present in the adult ependyma. Claudin-5 was present in the apical-most part of radial glial cells and in endothelial cells in embryos, but only in endothelial cells including plexus endothelial cells in adults. Claudin-11 was only immunopositive in the adult, consistent with results obtained from transcriptomic analysis. These results provide information about physiological, molecular and morphological-related permeability changes occurring at the inner cerebrospinal fluid-brain barrier during brain development. PMID:25729345

Numerical modeling of materials processes with fluid-fluid interfaces

NASA Astrophysics Data System (ADS)

Yanke, Jeffrey Michael

A numerical model has been developed to study material processes that depend on the interaction between fluids with a large discontinuity in thermophysical properties. A base model capable of solving equations of mass, momentum, energy conservation, and solidification has been altered to enable tracking of the interface between two immiscible fluids and correctly predict the interface deformation using a volume of fluid (VOF) method. Two materials processes investigated using this technique are Electroslag Remelting (ESR) and plasma spray deposition. ESR is a secondary melting technique that passes an AC current through an electrically resistive slag to provide the heat necessary to melt the alloy. The simulation tracks the interface between the slag and metal. The model was validated against industrial scale ESR ingots and was able to predict trends in melt rate, sump depth, macrosegregation, and liquid sump depth. In order to better understand the underlying physics of the process, several constant current ESR runs simulated the effects of freezing slag in the model. Including the solidifying slag in the imulations was found to have an effect on the melt rate and sump shape but there is too much uncertainty in ESR slag property data at this time for quantitative predictions. The second process investigated in this work is the deposition of ceramic coatings via plasma spray deposition. In plasma spray deposition, powderized coating material is injected into a plasma that melts and carries the powder towards the substrate were it impacts, flattening out and freezing. The impacting droplets pile up to form a porous coating. The model is used to simulate this rain of liquid ceramic particles impacting the substrate and forming a coating. Trends in local solidification time and porosity are calculated for various particle sizes and velocities. The predictions of decreasing porosity with increasing particle velocity matches previous experimental results. Also, a preliminary study was conducted to investigate the effects of substrate surface defects and droplet impact angle on the propensity to form columnar porosity.

MISCIBLE FLUID DISPLACEMENT STABILITY IN UNCONFINED POROUS MEDIA: TWO-DIMENSIONAL FLOW EXPERIMENTS AND SIMULATIONS

EPA Science Inventory

In situ flushing groundwater remediation technologies, such as cosolvent flushing, rely on the stability of the interface between the resident and displacing fluids for efficient removal of contaminants. Contrasts in density and viscosity between the resident and displacing flui...

Membrane Transport Phenomena (MTP)

NASA Technical Reports Server (NTRS)

Mason, Larry W.

1996-01-01

The development of the seal between the membrane and the Fluid Optical Cells (FOC) has been a high priority activity. This seal occurs at an interface in the instrument where three key functions must be realized: (1) physical membrane support, (2) fluid sealing, and (3) unobscured optical transmission.

Swimming near an interface in a viscoelastic fluid

NASA Astrophysics Data System (ADS)

Yazdi, Shahrzad; Ardekani, Arezoo; Borhan, Ali

2014-11-01

Given the versatility of their natural habitats, microorganisms often encounter the presence of confining boundaries while moving in polymeric solutions. Some examples include swimming of spermatozoa in the mammalian reproductive tract or bacteria in extracellular polymeric matrices during biofilm formation. It has been shown that both confinement and fluid elasticity can have significant impacts on the locomotion of microswimmers. However, the combined effect of these environmental conditions has not been fully understood yet. In this work, we present a fully resolved solution of a low-Reynolds-number microorganism swimming near an interface in a viscoelastic fluid. The kinematics of locomotion for a squirmer in a viscoelastic fluid is compared to its Newtonian counterpart using a perturbation analysis. The results suggest that extracellular polymers dramatically alter the swimming hydrodynamics, and in general increase the residence time of the microswimmer near a no-slip boundary that can consequently facilitate its adhesion rate. The emergence of a limit cycle can also enhance cell-cell communication in the form of quorum sensing and consequently biofilm formation.

Axisymmetric capillary-gravity waves at the interface of two viscous, immiscible fluids - Initial value problem

NASA Astrophysics Data System (ADS)

Farsoiya, Palas Kumar; Dasgupta, Ratul

2017-11-01

When the interface between two radially unbounded, viscous fluids lying vertically in a stable configuration (denser fluid below) at rest, is perturbed, radially propagating capillary-gravity waves are formed which damp out with time. We study this process analytically using a recently developed linearised theory. For small amplitude initial perturbations, the analytical solution to the initial value problem, represented as a linear superposition of Bessel modes at time t = 0 , is found to agree very well with results obtained from direct numerical simulations of the Navier-Stokes equations, for a range of initial conditions. Our study extends the earlier work by John W. Miles who studied this initial value problem analytically, taking into account, a single viscous fluid only. Implications of this study for the mechanistic understanding of droplet impact into a deep pool, will be discussed. Some preliminary, qualitative comparison with experiments will also be presented. We thank SERB Dept. Science & Technology, Govt. of India, Grant No. EMR/2016/000830 for financial support.

Adhesion of bubbles and drops to solid surfaces, and anisotropic surface tensions studied by capillary meniscus dynamometry.

PubMed

Danov, Krassimir D; Stanimirova, Rumyana D; Kralchevsky, Peter A; Marinova, Krastanka G; Stoyanov, Simeon D; Blijdenstein, Theodorus B J; Cox, Andrew R; Pelan, Eddie G

2016-07-01

Here, we review the principle and applications of two recently developed methods: the capillary meniscus dynamometry (CMD) for measuring the surface tension of bubbles/drops, and the capillary bridge dynamometry (CBD) for quantifying the bubble/drop adhesion to solid surfaces. Both methods are based on a new data analysis protocol, which allows one to decouple the two components of non-isotropic surface tension. For an axisymmetric non-fluid interface (e.g. bubble or drop covered by a protein adsorption layer with shear elasticity), the CMD determines the two different components of the anisotropic surface tension, σs and σφ, which are acting along the "meridians" and "parallels", and vary throughout the interface. The method uses data for the instantaneous bubble (drop) profile and capillary pressure, but the procedure for data processing is essentially different from that of the conventional drop shape analysis (DSA) method. In the case of bubble or drop pressed against a substrate, which forms a capillary bridge, the CBD method allows one to determine also the capillary-bridge force for both isotropic (fluid) and anisotropic (solidified) adsorption layers. The experiments on bubble (drop) detachment from the substrate show the existence of a maximal pulling force, Fmax, that can be resisted by an adherent fluid particle. Fmax can be used to quantify the strength of adhesion of bubbles and drops to solid surfaces. Its value is determined by a competition of attractive transversal tension and repulsive disjoining pressure forces. The greatest Fmax values have been measured for bubbles adherent to glass substrates in pea-protein solutions. The bubble/wall adhesion is lower in solutions containing the protein HFBII hydrophobin, which could be explained with the effect of sandwiched protein aggregates. The applicability of the CBD method to emulsion systems is illustrated by experiments with soybean-oil drops adherent to hydrophilic and hydrophobic substrates in egg yolk solutions. The results reveal how the interfacial rigidity, as well as the bubble/wall and drop/wall adhesion forces, can be quantified and controlled in relation to optimizing the properties of foams and emulsions. Copyright © 2015 Elsevier B.V. All rights reserved.

Multi-scale diffuse interface modeling of multi-component two-phase flow with partial miscibility

NASA Astrophysics Data System (ADS)

Kou, Jisheng; Sun, Shuyu

2016-08-01

In this paper, we introduce a diffuse interface model to simulate multi-component two-phase flow with partial miscibility based on a realistic equation of state (e.g. Peng-Robinson equation of state). Because of partial miscibility, thermodynamic relations are used to model not only interfacial properties but also bulk properties, including density, composition, pressure, and realistic viscosity. As far as we know, this effort is the first time to use diffuse interface modeling based on equation of state for modeling of multi-component two-phase flow with partial miscibility. In numerical simulation, the key issue is to resolve the high contrast of scales from the microscopic interface composition to macroscale bulk fluid motion since the interface has a nanoscale thickness only. To efficiently solve this challenging problem, we develop a multi-scale simulation method. At the microscopic scale, we deduce a reduced interfacial equation under reasonable assumptions, and then we propose a formulation of capillary pressure, which is consistent with macroscale flow equations. Moreover, we show that Young-Laplace equation is an approximation of this capillarity formulation, and this formulation is also consistent with the concept of Tolman length, which is a correction of Young-Laplace equation. At the macroscopical scale, the interfaces are treated as discontinuous surfaces separating two phases of fluids. Our approach differs from conventional sharp-interface two-phase flow model in that we use the capillary pressure directly instead of a combination of surface tension and Young-Laplace equation because capillarity can be calculated from our proposed capillarity formulation. A compatible condition is also derived for the pressure in flow equations. Furthermore, based on the proposed capillarity formulation, we design an efficient numerical method for directly computing the capillary pressure between two fluids composed of multiple components. Finally, numerical tests are carried out to verify the effectiveness of the proposed multi-scale method.

Multi-scale diffuse interface modeling of multi-component two-phase flow with partial miscibility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kou, Jisheng; Sun, Shuyu, E-mail: shuyu.sun@kaust.edu.sa; School of Mathematics and Statistics, Xi'an Jiaotong University, Xi'an 710049

2016-08-01

In this paper, we introduce a diffuse interface model to simulate multi-component two-phase flow with partial miscibility based on a realistic equation of state (e.g. Peng–Robinson equation of state). Because of partial miscibility, thermodynamic relations are used to model not only interfacial properties but also bulk properties, including density, composition, pressure, and realistic viscosity. As far as we know, this effort is the first time to use diffuse interface modeling based on equation of state for modeling of multi-component two-phase flow with partial miscibility. In numerical simulation, the key issue is to resolve the high contrast of scales from themore » microscopic interface composition to macroscale bulk fluid motion since the interface has a nanoscale thickness only. To efficiently solve this challenging problem, we develop a multi-scale simulation method. At the microscopic scale, we deduce a reduced interfacial equation under reasonable assumptions, and then we propose a formulation of capillary pressure, which is consistent with macroscale flow equations. Moreover, we show that Young–Laplace equation is an approximation of this capillarity formulation, and this formulation is also consistent with the concept of Tolman length, which is a correction of Young–Laplace equation. At the macroscopical scale, the interfaces are treated as discontinuous surfaces separating two phases of fluids. Our approach differs from conventional sharp-interface two-phase flow model in that we use the capillary pressure directly instead of a combination of surface tension and Young–Laplace equation because capillarity can be calculated from our proposed capillarity formulation. A compatible condition is also derived for the pressure in flow equations. Furthermore, based on the proposed capillarity formulation, we design an efficient numerical method for directly computing the capillary pressure between two fluids composed of multiple components. Finally, numerical tests are carried out to verify the effectiveness of the proposed multi-scale method.« less

Fluid inclusion gas chemistry as a potential minerals exploration tool: Case studies from Creede, CO, Jerritt Canyon, NV, Coeur d'Alene district, ID and MT, southern Alaska mesothermal veins, and mid-continent MVT's

USGS Publications Warehouse

Landis, G.P.; Hofstra, A.H.

1991-01-01

Recent advances in instrumentation now permit quantitative analysis of gas species from individual fluid inclusions. Fluid inclusion gas data can be applied to minerals exploration empirically to establish chemical (gas composition) signatures of the ore fluids, and conceptually through the development of genetic models of ore formation from a framework of integrated geologic, geochemical, and isotopic investigations. Case studies of fluid inclusion gas chemistry from ore deposits representing a spectrum of ore-forming processes and environments are presented to illustrate both the empirical and conceptual approaches. We consider epithermal silver-gold deposits of Creede, Colorado, Carlin-type sediment-hosted disseminated gold deposits of Jerritt Canyon, Nevada, metamorphic silver-base-metal veins of the Coeur d'Alene district, Idaho and Montana, gold-quartz veins in accreted terranes of southern Alaska, and the mid-continent base-metal sulfide deposits of Mississippi Valley-Type (MVT's). Variations in gas chemistry determine the redox state of the ore fluids, provide compositional input for gas geothermometers, characterize ore fluid chemistry (e.g., CH4CO2, H2SSO2, CO2/H2S, organic-rich fluids, gas-rich and gas-poor fluids), identify magmatic, meteoric, metamorphic, shallow and deep basin fluids in ore systems, locate upwelling plumes of magmatic-derived volatiles, zones of boiling and volatile separation, interfaces between contrasting fluids, and important zones of fluid mixing. Present techniques are immediately applicable to exploration programsas empirical studies that monitor fluid inclusion gas threshold concentration levels, presence or absence of certain gases, or changes in gas ratios. We suggest that the greater contribution of fluid inclusion gas analysis is in the integrated and comprehensive chemical dimension that gas data impart to genetic models, and in the exploration concepts based on processes and environments of ore formation derived from these genetic models. ?? 1991.

Molecular Probe Fluorescence Monitoring of Polymerization

NASA Technical Reports Server (NTRS)

Bunton, Patrick

2002-01-01

This project investigated the feasibility of using fluorescence spectroscopy to determine viscosity of polymer/monomer in support of Transient Interfacial Phenomena in Miscible Polymer Systems (TIPMPS). This project will attempt to measure gradient induced flow at a miscible interface during and / or after in-flight polymerization of dodecyl acrylate (lauryl acrylate). Concentration and temperature gradients will be intentionally introduced during polymerization and the resultant fluid flow determined by Particle Imaging Velocimetry (PIV). This report describes an investigation of the feasibility of using fluorescence of a probe molecule to monitor viscosity and/or concentration during and after polymerization. The probe used was pyrene which has been shown to be sensitive to its local environment in methyl methacrylate.

A vacuum manifold for rapid world-to-chip connectivity of complex PDMS microdevices.

PubMed

Cooksey, Gregory A; Plant, Anne L; Atencia, Javier

2009-05-07

The lack of simple interfaces for microfluidic devices with a large number of inlets significantly limits production and utilization of these devices. In this article, we describe the fabrication of a reusable manifold that provides rapid world-to-chip connectivity. A vacuum network milled into a rigid manifold holds microdevices and prevents leakage of fluids injected into the device from ports in the manifold. A number of different manifold designs were explored, and all performed similarly, yielding an average of 100 kPa (15 psi) fluid holding pressure. The wide applicability of this manifold concept is demonstrated by interfacing with a 51-inlet microfluidic chip containing 144 chambers and hundreds of embedded pneumatic valves. Due to the speed of connectivity, the manifolds are ideal for rapid prototyping and are well suited to serve as "universal" interfaces.

Formation of droplet interface bilayers in a Teflon tube

NASA Astrophysics Data System (ADS)

Walsh, Edmond; Feuerborn, Alexander; Cook, Peter R.

2016-09-01

Droplet-interface bilayers (DIBs) have applications in disciplines ranging from biology to computing. We present a method for forming them manually using a Teflon tube attached to a syringe pump; this method is simple enough it should be accessible to those without expertise in microfluidics. It exploits the properties of interfaces between three immiscible liquids, and uses fluid flow through the tube to pack together drops coated with lipid monolayers to create bilayers at points of contact. It is used to create functional nanopores in DIBs composed of phosphocholine using the protein α-hemolysin (αHL), to demonstrate osmotically-driven mass transfer of fluid across surfactant-based DIBs, and to create arrays of DIBs. The approach is scalable, and thousands of DIBs can be prepared using a robot in one hour; therefore, it is feasible to use it for high throughput applications.

Lateral movements in Rayleigh-Taylor instabilities due to frontiers. Experimental study

NASA Astrophysics Data System (ADS)

Binda, L.; Fernández, D.; El Hasi, C.; Zalts, A.; D'Onofrio, A.

2018-01-01

Lateral movements of the fingers in Rayleigh-Taylor hydrodynamic instabilities at the interface between two fluids are studied. We show that transverse movements appear when a physical boundary is present; these phenomena have not been explained until now. The boundary prevents one of the fluids from crossing it. Such frontiers can be buoyancy driven as, for example, the frontier to the passage of a less dense solution through a denser solution or when different aggregation states coexist (liquid and gaseous phases). An experimental study of the lateral movement velocity of the fingers was performed for different Rayleigh numbers (Ra), and when oscillations were detected, their amplitudes were studied. Liquid-liquid (L-L) and gas-liquid (G-L) systems were analysed. Aqueous HCl and Bromocresol Green (sodium salt, NaBCG) solutions were used in L-L experiments, and CO2 (gas) and aqueous NaOH, NaHCO3, and CaCl2 solutions were employed for the G-L studies. We observed that the lateral movement of the fingers and finger collapses near the interface are more notorious when Ra increases. The consequences of this, for each experience, are a decrease in the number of fingers and an increase in the velocity of the lateral finger movement close to the interface as time evolves. We found that the amplitude of the oscillations did not vary significantly within the considered Ra range. These results have an important implication when determining the wave number of instabilities in an evolving system. The wave number could be strongly diminished if there is a boundary.

Adsorption of organic ligands on low surface charge clay minerals: the composition in the aqueous interface region.

PubMed

Jelavić, S; Stipp, S L S; Bovet, N

2018-06-27

An understanding of the mechanisms that control the adsorption of organic molecules on clay minerals is of interest in several branches of science and industry. Oil production using low salinity injection fluids can increase yields by as much as 40% over standard injection with seawater or formation water. The mechanism responsible for the low salinity response is still debated, but one hypothesis is a change in pore surface wettability. Organic contamination in soil and drinking water aquifers is a challenge for municipal water suppliers and for agriculture. A better understanding is needed for how mineral species, solution composition and pH affect the desorption of low molecular weight organic ligands from clay minerals and consequently their wettability. We used X-ray photoelectron spectroscopy under cryogenic conditions to investigate the in situ composition in the mineral-solution interface region in a series of experiments with a range of pH and ion concentrations. We demonstrate that both chlorite and kaolinite release organic molecules under conditions relevant for low salinity water flooding. This release increases with a higher solution pH but is only slightly affected by the character of the organic ligand. This is consistent with the observation that low salinity enhanced oil recovery correlates with the presence of chlorite and kaolinite. Our results indicate that the pore surface charge and salinity of formation water and injection fluids are key parameters in determining the low salinity response. In general, our results imply that clay mineral surface charge influences the composition in the interface through an affinity for organic molecules.

Imaging across the interface of small-scale breaking waves

NASA Astrophysics Data System (ADS)

Techet, Alexandra H.; Belden, Jesse L.

2007-11-01

Flow characteristics on both the air and water side of small scale spilling and plunging waves are investigated using fully time-resolved particle image velocimetry (PIV). PIV at 1000 frames per second (fps) is used to capture the flow field in both the air and water for waves generated by shoaling. Reynolds number of the waves is on the order of Re = 9x10^4 to 2x10^6, where Re = ρ√g 3̂μ, ρ is fluid density, μ is fluid dynamic viscosity, g is gravity, and λ is the characteristic wavelength of the breaking wave before breaking. Isopropyl alcohol is mixed with the distilled water in the tank to reduce surface tension and thus achieve plunging breakers on this scale. Flow in the water is seeded using conventional silver-coated hollow glass spheres, whereas the quiescent air side (i.e. no wind) is seeded using micro-air balloons with high stokes drag and thus long settling times. Imaging of both the air and water are performed simultaneously and advanced image processing is performed to determine the water surface location and to avoid surface tracking during PIV processing. Repeatable, coherent vortical structures are revealed on the air-side of the waves and are considered mechanisms for energy transfer across the interface.

Temperature anisotropy at equilibrium reveals nonlocal entropic contributions to interfacial properties.

PubMed

Wilhelmsen, Øivind; Trinh, Thuat T; Lervik, Anders

2018-01-01

Density gradient theory for fluids has played a key role in the study of interfacial phenomena for a century. In this work, we revisit its fundamentals by examining the vapor-liquid interface of argon, represented by the cut and shifted Lennard-Jones fluid. The starting point has traditionally been a Helmholtz energy functional using mass densities as arguments. By using rather the internal energy as starting point and including the entropy density as an additional argument, following thereby the phenomenological approach from classical thermodynamics, the extended theory suggests that the configurational part of the temperature has different contributions from the parallel and perpendicular directions at the interface, even at equilibrium. We find a similar anisotropy by examining the configurational temperature in molecular dynamics simulations and obtain a qualitative agreement between theory and simulations. The extended theory shows that the temperature anisotropy originates in nonlocal entropic contributions, which are currently missing from the classical theory. The nonlocal entropic contributions discussed in this work are likely to play a role in the description of both equilibrium and nonequilibrium properties of interfaces. At equilibrium, they influence the temperature- and curvature-dependence of the surface tension. Across the vapor-liquid interface of the Lennard Jones fluid, we find that the maximum in the temperature anisotropy coincides precisely with the maximum in the thermal resistivity relative to the equimolar surface, where the integral of the thermal resistivity gives the Kapitza resistance. This links the temperature anisotropy at equilibrium to the Kapitza resistance of the vapor-liquid interface at nonequilibrium.

Temperature anisotropy at equilibrium reveals nonlocal entropic contributions to interfacial properties

NASA Astrophysics Data System (ADS)

Wilhelmsen, Øivind; Trinh, Thuat T.; Lervik, Anders

2018-01-01

Density gradient theory for fluids has played a key role in the study of interfacial phenomena for a century. In this work, we revisit its fundamentals by examining the vapor-liquid interface of argon, represented by the cut and shifted Lennard-Jones fluid. The starting point has traditionally been a Helmholtz energy functional using mass densities as arguments. By using rather the internal energy as starting point and including the entropy density as an additional argument, following thereby the phenomenological approach from classical thermodynamics, the extended theory suggests that the configurational part of the temperature has different contributions from the parallel and perpendicular directions at the interface, even at equilibrium. We find a similar anisotropy by examining the configurational temperature in molecular dynamics simulations and obtain a qualitative agreement between theory and simulations. The extended theory shows that the temperature anisotropy originates in nonlocal entropic contributions, which are currently missing from the classical theory. The nonlocal entropic contributions discussed in this work are likely to play a role in the description of both equilibrium and nonequilibrium properties of interfaces. At equilibrium, they influence the temperature- and curvature-dependence of the surface tension. Across the vapor-liquid interface of the Lennard Jones fluid, we find that the maximum in the temperature anisotropy coincides precisely with the maximum in the thermal resistivity relative to the equimolar surface, where the integral of the thermal resistivity gives the Kapitza resistance. This links the temperature anisotropy at equilibrium to the Kapitza resistance of the vapor-liquid interface at nonequilibrium.

Integration Process for Payloads in the Fluids and Combustion Facility

NASA Technical Reports Server (NTRS)

Free, James M.; Nall, Marsha M.

2001-01-01

The Fluids and Combustion Facility (FCF) is an ISS research facility located in the United States Laboratory (US Lab), Destiny. The FCF is a multi-discipline facility that performs microgravity research primarily in fluids physics science and combustion science. This facility remains on-orbit and provides accommodations to multi-user and Principal investigator (PI) unique hardware. The FCF is designed to accommodate 15 PI's per year. In order to allow for this number of payloads per year, the FCF has developed an end-to-end analytical and physical integration process. The process includes provision of integration tools, products and interface management throughout the life of the payload. The payload is provided with a single point of contact from the facility and works with that interface from PI selection through post flight processing. The process utilizes electronic tools for creation of interface documents/agreements, storage of payload data and rollup for facility submittals to ISS. Additionally, the process provides integration to and testing with flight-like simulators prior to payload delivery to KSC. These simulators allow the payload to test in the flight configuration and perform final facility interface and science verifications. The process also provides for support to the payload from the FCF through the Payload Safety Review Panel (PSRP). Finally, the process includes support in the development of operational products and the operation of the payload on-orbit.

Design study of RL10 derivatives. Volume 3, part 1: Preliminary interface control document. [development of baseline engines for space tug vehicles

NASA Technical Reports Server (NTRS)

Adams, A.

1973-01-01

The Interface Control Document contains engine information necessary for installation of the baseline RL10 Derivative engines in the Space Tug vehicle. The ICD presents a description of the baseline engines and their operating characteristics, mass and load characteristics, and environmental criteria. The document defines the engine/vehicle mechanical, electrical, fluid and pneumatic interface requirements.

Pressurization of a Flightweight, Liquid Hydrogen Tank: Evaporation and Condensation at a Liquid Vapor Interface

NASA Technical Reports Server (NTRS)

Stewart, Mark

2017-01-01

Evaporation and condensation at a liquid-vapor interface is important for long-term, in-space cryogenic propellant storage. Yet the current understanding of inter-facial physics does not consistently predict behavior of evaporation or condensation rates. The proposed paper will present a physical model, based on the 1-D Heat equation and Schrage's equation, which demonstrates thin thermal layers at the fluid vapor interface.

Accurate fluid force measurement based on control surface integration

NASA Astrophysics Data System (ADS)

Lentink, David

2018-01-01

Nonintrusive 3D fluid force measurements are still challenging to conduct accurately for freely moving animals, vehicles, and deforming objects. Two techniques, 3D particle image velocimetry (PIV) and a new technique, the aerodynamic force platform (AFP), address this. Both rely on the control volume integral for momentum; whereas PIV requires numerical integration of flow fields, the AFP performs the integration mechanically based on rigid walls that form the control surface. The accuracy of both PIV and AFP measurements based on the control surface integration is thought to hinge on determining the unsteady body force associated with the acceleration of the volume of displaced fluid. Here, I introduce a set of non-dimensional error ratios to show which fluid and body parameters make the error negligible. The unsteady body force is insignificant in all conditions where the average density of the body is much greater than the density of the fluid, e.g., in gas. Whenever a strongly deforming body experiences significant buoyancy and acceleration, the error is significant. Remarkably, this error can be entirely corrected for with an exact factor provided that the body has a sufficiently homogenous density or acceleration distribution, which is common in liquids. The correction factor for omitting the unsteady body force, {{{ {ρ f}} {1 - {ρ f} ( {{ρ b}+{ρ f}} )}.{( {{{{ρ }}b}+{ρ f}} )}}} , depends only on the fluid, {ρ f}, and body, {{ρ }}b, density. Whereas these straightforward solutions work even at the liquid-gas interface in a significant number of cases, they do not work for generalized bodies undergoing buoyancy in combination with appreciable body density inhomogeneity, volume change (PIV), or volume rate-of-change (PIV and AFP). In these less common cases, the 3D body shape needs to be measured and resolved in time and space to estimate the unsteady body force. The analysis shows that accounting for the unsteady body force is straightforward to non-intrusively and accurately determine fluid force in most applications.

Curvature computation in volume-of-fluid method based on point-cloud sampling

NASA Astrophysics Data System (ADS)

Kassar, Bruno B. M.; Carneiro, João N. E.; Nieckele, Angela O.

2018-01-01

This work proposes a novel approach to compute interface curvature in multiphase flow simulation based on Volume of Fluid (VOF) method. It is well documented in the literature that curvature and normal vector computation in VOF may lack accuracy mainly due to abrupt changes in the volume fraction field across the interfaces. This may cause deterioration on the interface tension forces estimates, often resulting in inaccurate results for interface tension dominated flows. Many techniques have been presented over the last years in order to enhance accuracy in normal vectors and curvature estimates including height functions, parabolic fitting of the volume fraction, reconstructing distance functions, coupling Level Set method with VOF, convolving the volume fraction field with smoothing kernels among others. We propose a novel technique based on a representation of the interface by a cloud of points. The curvatures and the interface normal vectors are computed geometrically at each point of the cloud and projected onto the Eulerian grid in a Front-Tracking manner. Results are compared to benchmark data and significant reduction on spurious currents as well as improvement in the pressure jump are observed. The method was developed in the open source suite OpenFOAM® extending its standard VOF implementation, the interFoam solver.

Three-dimensional local ALE-FEM method for fluid flow in domains containing moving boundaries/objects interfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carrington, David Bradley; Monayem, A. K. M.; Mazumder, H.

2015-03-05

A three-dimensional finite element method for the numerical simulations of fluid flow in domains containing moving rigid objects or boundaries is developed. The method falls into the general category of Arbitrary Lagrangian Eulerian methods; it is based on a fixed mesh that is locally adapted in the immediate vicinity of the moving interfaces and reverts to its original shape once the moving interfaces go past the elements. The moving interfaces are defined by separate sets of marker points so that the global mesh is independent of interface movement and the possibility of mesh entanglement is eliminated. The results is amore » fully robust formulation capable of calculating on domains of complex geometry with moving boundaries or devises that can also have a complex geometry without danger of the mesh becoming unsuitable due to its continuous deformation thus eliminating the need for repeated re-meshing and interpolation. Moreover, the boundary conditions on the interfaces are imposed exactly. This work is intended to support the internal combustion engines simulator KIVA developed at Los Alamos National Laboratories. The model's capabilities are illustrated through application to incompressible flows in different geometrical settings that show the robustness and flexibility of the technique to perform simulations involving moving boundaries in a three-dimensional domain.« less

Formative evaluation of a mobile liquid portion size estimation interface for people with varying literacy skills.

PubMed

Chaudry, Beenish Moalla; Connelly, Kay; Siek, Katie A; Welch, Janet L

2013-12-01

Chronically ill people, especially those with low literacy skills, often have difficulty estimating portion sizes of liquids to help them stay within their recommended fluid limits. There is a plethora of mobile applications that can help people monitor their nutritional intake but unfortunately these applications require the user to have high literacy and numeracy skills for portion size recording. In this paper, we present two studies in which the low- and the high-fidelity versions of a portion size estimation interface, designed using the cognitive strategies adults employ for portion size estimation during diet recall studies, was evaluated by a chronically ill population with varying literacy skills. The low fidelity interface was evaluated by ten patients who were all able to accurately estimate portion sizes of various liquids with the interface. Eighteen participants did an in situ evaluation of the high-fidelity version incorporated in a diet and fluid monitoring mobile application for 6 weeks. Although the accuracy of the estimation cannot be confirmed in the second study but the participants who actively interacted with the interface showed better health outcomes by the end of the study. Based on these findings, we provide recommendations for designing the next iteration of an accurate and low literacy-accessible liquid portion size estimation mobile interface.

Phase behavior of charged colloids at a fluid interface

NASA Astrophysics Data System (ADS)

Kelleher, Colm P.; Guerra, Rodrigo E.; Hollingsworth, Andrew D.; Chaikin, Paul M.

2017-02-01

We study the phase behavior of a system of charged colloidal particles that are electrostatically bound to an almost flat interface between two fluids. We show that, despite the fact that our experimental system consists of only 103-104 particles, the phase behavior is consistent with the theory of melting due to Kosterlitz, Thouless, Halperin, Nelson, and Young. Using spatial and temporal correlations of the bond-orientational order parameter, we classify our samples into solid, isotropic fluid, and hexatic phases. We demonstrate that the topological defect structure we observe in each phase corresponds to the predictions of Kosterlitz-Thouless-Halperin-Nelson-Young theory. By measuring the dynamic Lindemann parameter γL(τ ) and the non-Gaussian parameter α2(τ ) of the displacements of the particles relative to their neighbors, we show that each of the phases displays distinctive dynamical behavior.

Charge interaction between particle-laden fluid interfaces.

PubMed

Xu, Hui; Kirkwood, John; Lask, Mauricio; Fuller, Gerald

2010-03-02

Experiments are described where two oil/water interfaces laden with charged particles move at close proximity relative to one another. The particles on one of the interfaces were observed to be attracted toward the point of closest approach, forming a denser particle monolayer, while the particles on the opposite interface were repelled away from this point, forming a particle depletion zone. Such particle attraction/repulsion was observed even if one of the interfaces was free of particles. This phenomenon can be explained by the electrostatic interaction between the two interfaces, which causes surface charges (charged particles and ions) to redistribute in order to satisfy surface electric equipotential at each interface. In a forced particle oscillation experiment, we demonstrated the control of charged particle positions on the interface by manipulating charge interaction between interfaces.

Oscillations of a standing shock wave generated by the Richtmyer-Meshkov instability

DOE PAGES

Mikaelian, Karnig O.

2016-07-13

In a typical Richtmyer-Meshkov experiment a fast moving flat shock strikes a stationary perturbed interface between fluids A and B creating a transmitted and a reflected shock, both of which are perturbed. We propose shock tube experiments in which the reflected shock is stationary in the laboratory. Such a standing perturbed shock undergoes well-known damped oscillations. We present the conditions required for producing such a standing shock wave, which greatly facilitates the measurement of the oscillations and their rate of damping. We define a critical density ratio R critical, in terms of the adiabatic indices of the two fluids, andmore » a critical Mach number M critical s of the incident shock wave, which produces a standing reflected wave. If the initial density ratio R of the two fluids is less than R critical then a standing shock wave is possible at M s=M critical s. Otherwise a standing shock is not possible and the reflected wave always moves in the direction opposite the incident shock. Examples are given for present-day operating shock tubes with sinusoidal or inclined interfaces. We consider the effect of viscosity, which affects the damping rate of the oscillations. Furthermore, we point out that nonlinear bubble and spike amplitudes depend relatively weakly on the viscosity of the fluids and that the interface area is a better diagnostic.« less

Running interfacial waves in a two-layer fluid system subject to longitudinal vibrations.

PubMed

Goldobin, D S; Pimenova, A V; Kovalevskaya, K V; Lyubimov, D V; Lyubimova, T P

2015-05-01

We study the waves at the interface between two thin horizontal layers of immiscible fluids subject to high-frequency horizontal vibrations. Previously, the variational principle for energy functional, which can be adopted for treatment of quasistationary states of free interface in fluid dynamical systems subject to vibrations, revealed the existence of standing periodic waves and solitons in this system. However, this approach does not provide regular means for dealing with evolutionary problems: neither stability problems nor ones associated with propagating waves. In this work, we rigorously derive the evolution equations for long waves in the system, which turn out to be identical to the plus (or good) Boussinesq equation. With these equations one can find all the time-independent-profile solitary waves (standing solitons are a specific case of these propagating waves), which exist below the linear instability threshold; the standing and slow solitons are always unstable while fast solitons are stable. Depending on initial perturbations, unstable solitons either grow in an explosive manner, which means layer rupture in a finite time, or falls apart into stable solitons. The results are derived within the long-wave approximation as the linear stability analysis for the flat-interface state [D.V. Lyubimov and A.A. Cherepanov, Fluid Dynamics 21, 849 (1986)] reveals the instabilities of thin layers to be long wavelength.

Infectious Prions in the Pregnancy Microenvironment of Chronic Wasting Disease-Infected Reeves' Muntjac Deer.

PubMed

Nalls, Amy V; McNulty, Erin; Hoover, Clare E; Pulscher, Laura A; Hoover, Edward A; Mathiason, Candace K

2017-08-01

Ample evidence exists for the presence of infectious agents at the maternal-fetal interface, often with grave outcomes to the developing fetus (i.e., Zika virus, brucella, cytomegalovirus, and toxoplasma). While less studied, pregnancy-related transmissible spongiform encephalopathies (TSEs) have been implicated in several species, including humans. Our previous work has shown that prions can be transferred from mother to offspring, resulting in the development of clinical TSE disease in offspring born to muntjac dams infected with chronic wasting disease (CWD) (1). We further demonstrated protein misfolding cyclic amplification (PMCA)-competent prions within the female reproductive tract and in fetal tissues harvested from CWD experimentally and naturally exposed cervids (1, 2). To assess whether the PMCA-competent prions residing at the maternal-fetal interface were infectious and to determine if the real-time quaking-induced conversion (RT-QuIC) methodology may enhance our ability to detect amyloid fibrils within the pregnancy microenvironment, we employed a mouse bioassay and RT-QuIC. In this study, we have demonstrated RT-QuIC seeding activity in uterus, placentome, ovary, and amniotic fluid but not in allantoic fluids harvested from CWD-infected Reeves' muntjac dams showing clinical signs of infection (clinically CWD-infected) and in some placentomes from pre-clinically CWD-infected dams. Prion infectivity was confirmed within the uterus, amniotic fluid, and the placentome, the semipermeable interface that sustains the developing fetus, of CWD-infected dams. This is the first report of prion infectivity within the cervid pregnancy microenvironment, revealing a source of fetal CWD exposure prior to the birthing process, maternal grooming, or encounters with contaminated environments. IMPORTANCE The facile dissemination of chronic wasting disease within captive and free-range cervid populations has led to questions regarding the transmission dynamics of this disease. Direct contact with infected animals and indirect contact with infectious prions in bodily fluids and contaminated environments are suspected to explain the majority of this transmission. A third mode of transmission, from mother to offspring, may be underappreciated. The presence of pregnancy-related prion infectivity within the uterus, amniotic fluid, and the placental structure reveals that the developing fetus is exposed to a source of prions long before exposure to the infectious agent during and after the birthing process or via contact with contaminated environments. These findings have impact on our current concept of CWD disease transmission. Copyright © 2017 American Society for Microbiology.

The Fluid Interface Reactions Structures and Transport (FIRST) EFRC (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wesolowski, David J.; FIRST Staff

2011-05-01

'The Fluid Interface Reactions Structures and Transport (FIRST) EFRC' was submitted by FIRST to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. FIRST, an EFRC directed by David J. Wesolowski at the Oak Ridge National Laboratory is a partnership of scientists from nine institutions: Oak Ridge National Laboratory (lead), Argonne National Laboratory, Drexel University, Georgia State University, Northwestern University, Pennsylvania State University, Suffolk University, Vanderbilt University, and University ofmore » Virginia. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Fluid Interface Reactions, Structures and Transport Center is 'to develop quantitative and predictive models of the unique nanoscale environment at fluid-solid interfaces that will enable transformational advances in electrical energy storage and heterogeneous catalysis for solar fuels.' Research topics are: catalysis (biomass, CO{sub 2}, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar fuels, solar electrodes, electrical energy storage, batteries, capacitors, battery electrodes, electrolytes, extreme environment, CO{sub 2} (convert), greenhouse gas, microelectromechanical systems (MEMS), interfacial characterization, matter by design, novel materials synthesis, and charge transport.« less

Phase behavior of charged hydrophobic colloids on flat and spherical surfaces

NASA Astrophysics Data System (ADS)

Kelleher, Colm P.

For a broad class of two-dimensional (2D) materials, the transition from isotropic fluid to crystalline solid is described by the theory of melting due to Kosterlitz, Thouless, Halperin, Nelson and Young (KTHNY). According to this theory, long-range order is achieved via elimination of the topological defects which proliferate in the fluid phase. However, many natural and man-made 2D systems posses spatial curvature and/or non-trivial topology, which require the presence of topological defects, even at T=0. In principle, the presence of these defects could profoundly affect the phase behavior of such a system. In this thesis, we develop and characterize an experimental system of charged colloidal particles that bind electrostatically to the interface between an oil and an aqueous phase. Depending on how we prepare the sample, this fluid interface may be flat, spherical, or have a more complicated geometry. Focusing on the cases where the interface is flat or spherical, we measure the interactions between the particles, and probe various aspects of their phase behavior. On flat interfaces, this phase behavior is well-described by KTHNY theory. In spherical geometries, however, we observe spatial structures and inhomogeneous dynamics that cannot be captured by the measures traditionally used to describe flat-space phase behavior. We show that, in the spherical system, ordering is achieved by a novel mechanism: sequestration of topological defects into freely-terminating grain boundaries ("scars"), and simultaneous spatial organization of the scars themselves on the vertices of an icosahedron. The emergence of icosahedral order coincides with the localization of mobility into isolated "lakes" of fluid or glassy particles, situated at the icosahedron vertices. These lakes are embedded in a rigid, connected "continent" of locally crystalline particles.

The Fluid Interface Reactions Structures and Transport (FIRST) EFRC (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

ScienceCinema

Wesolowski, David J. (Director, FIRST - Fluid Interface Reactions, Structures, and Transport Center); FIRST Staff

2017-12-09

'The Fluid Interface Reactions Structures and Transport (FIRST) EFRC' was submitted by FIRST to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. FIRST, an EFRC directed by David J. Wesolowski at the Oak Ridge National Laboratory is a partnership of scientists from nine institutions: Oak Ridge National Laboratory (lead), Argonne National Laboratory, Drexel University, Georgia State University, Northwestern University, Pennsylvania State University, Suffolk University, Vanderbilt University, and University of Virginia. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Fluid Interface Reactions, Structures and Transport Center is 'to develop quantitative and predictive models of the unique nanoscale environment at fluid-solid interfaces that will enable transformational advances in electrical energy storage and heterogeneous catalysis for solar fuels.' Research topics are: catalysis (biomass, CO{sub 2}, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar fuels, solar electrodes, electrical energy storage, batteries, capacitors, battery electrodes, electrolytes, extreme environment, CO{sub 2} (convert), greenhouse gas, microelectromechanical systems (MEMS), interfacial characterization, matter by design, novel materials synthesis, and charge transport.

An object-oriented and quadrilateral-mesh based solution adaptive algorithm for compressible multi-fluid flows

NASA Astrophysics Data System (ADS)

Zheng, H. W.; Shu, C.; Chew, Y. T.

2008-07-01

In this paper, an object-oriented and quadrilateral-mesh based solution adaptive algorithm for the simulation of compressible multi-fluid flows is presented. The HLLC scheme (Harten, Lax and van Leer approximate Riemann solver with the Contact wave restored) is extended to adaptively solve the compressible multi-fluid flows under complex geometry on unstructured mesh. It is also extended to the second-order of accuracy by using MUSCL extrapolation. The node, edge and cell are arranged in such an object-oriented manner that each of them inherits from a basic object. A home-made double link list is designed to manage these objects so that the inserting of new objects and removing of the existing objects (nodes, edges and cells) are independent of the number of objects and only of the complexity of O( 1). In addition, the cells with different levels are further stored in different lists. This avoids the recursive calculation of solution of mother (non-leaf) cells. Thus, high efficiency is obtained due to these features. Besides, as compared to other cell-edge adaptive methods, the separation of nodes would reduce the memory requirement of redundant nodes, especially in the cases where the level number is large or the space dimension is three. Five two-dimensional examples are used to examine its performance. These examples include vortex evolution problem, interface only problem under structured mesh and unstructured mesh, bubble explosion under the water, bubble-shock interaction, and shock-interface interaction inside the cylindrical vessel. Numerical results indicate that there is no oscillation of pressure and velocity across the interface and it is feasible to apply it to solve compressible multi-fluid flows with large density ratio (1000) and strong shock wave (the pressure ratio is 10,000) interaction with the interface.

Probing the transition between seismically coupled and decoupled segments along an ancient subduction interface

NASA Astrophysics Data System (ADS)

Angiboust, Samuel; Kirsch, Josephine; Oncken, Onno; Glodny, Johannes; Monié, Patrick; Rybacki, Erik

2015-06-01

The transition zone at the downdip end of seismic coupling along subduction interfaces is often the site of megathrust earthquake nucleation and concentrated postseismic afterslip, as well as the focus site of episodic tremor and slip features. Exhumed remnants of the former Alpine subduction zone found in the Swiss Alps allow analyzing fluid and deformation processes near the transition zone region (30-40 km paleodepth). The Dent Blanche Thrust (DBT) is a lower blueschist-facies shear zone interpreted as a fossilized subduction interface where granitic mylonites overlie a metamorphosed accretionary wedge. We report field observations from the DBT region where multiple, several tens of meters thick foliated cataclastic networks are interlayered within the basal DBT mylonites. Petrological results and microstructural observations indicate that the various cataclasis events took place at near-peak metamorphic conditions (400-500°C, 1.1-1.3 GPa) during subduction of the Tethyan seafloor in Eocene times (42-48 Ma). Some of these networks exhibit mutual crosscutting relationships between mylonites, foliated cataclasites, and vein systems indicating mutual overprinting between brittle deformation and ductile creep. Whole-rock chemical compositions, in situ 40Ar-39Ar age data of recrystallized phengite, and Sr isotopic signatures reveal that DBT rocks also underwent multiple hydrofracturing and metasomatic events via the infiltration of fluids mainly derived from the oceanic metasediments underneath the DBT. From the rock fabrics, we infer strain rate fluctuations of several orders of magnitude beyond subduction strain rates (˜10-12 s-1) accompanied by fluctuation of supralithostatic and quasi-lithostatic fluid pressures (1 ≥ λ > 0.95). DBT brittle-plastic deformation switches highlight the diversity of deformation processes and fluid-rock interactions in the transition zone region of the subduction interface.

On the transition between two-phase and single-phase interface dynamics in multicomponent fluids at supercritical pressures

NASA Astrophysics Data System (ADS)

Dahms, Rainer N.; Oefelein, Joseph C.

2013-09-01

A theory that explains the operating pressures where liquid injection processes transition from exhibiting classical two-phase spray atomization phenomena to single-phase diffusion-dominated mixing is presented. Imaging from a variety of experiments have long shown that under certain conditions, typically when the pressure of the working fluid exceeds the thermodynamic critical pressure of the liquid phase, the presence of discrete two-phase flow processes become diminished. Instead, the classical gas-liquid interface is replaced by diffusion-dominated mixing. When and how this transition occurs, however, is not well understood. Modern theory still lacks a physically based model to quantify this transition and the precise mechanisms that lead to it. In this paper, we derive a new model that explains how the transition occurs in multicomponent fluids and present a detailed analysis to quantify it. The model applies a detailed property evaluation scheme based on a modified 32-term Benedict-Webb-Rubin equation of state that accounts for the relevant real-fluid thermodynamic and transport properties of the multicomponent system. This framework is combined with Linear Gradient Theory, which describes the detailed molecular structure of the vapor-liquid interface region. Our analysis reveals that the two-phase interface breaks down not necessarily due to vanishing surface tension forces, but due to thickened interfaces at high subcritical temperatures coupled with an inherent reduction of the mean free molecular path. At a certain point, the combination of reduced surface tension, the thicker interface, and reduced mean free molecular path enter the continuum length scale regime. When this occurs, inter-molecular forces approach that of the multicomponent continuum where transport processes dominate across the interfacial region. This leads to a continuous phase transition from compressed liquid to supercritical mixture states. Based on this theory, a regime diagram for liquid injection is developed that quantifies the conditions under which classical sprays transition to dense-fluid jets. It is shown that the chamber pressure required to support diffusion-dominated mixing dynamics depends on the composition and temperature of the injected liquid and ambient gas. To illustrate the method and analysis, we use conditions typical of diesel engine injection. We also present a companion set of high-speed images to provide experimental validation of the presented theory. The basic theory is quite general and applies to a wide range of modern propulsion and power systems such as liquid rockets, gas turbines, and reciprocating engines. Interestingly, the regime diagram associated with diesel engine injection suggests that classical spray phenomena at typical injection conditions do not occur.

Mathematical modeling of impact of two metal plates using two-fluid approach

NASA Astrophysics Data System (ADS)

Utkin, P. S.; Fortova, S. V.

2018-01-01

The paper is devoted to the development of the two-fluid mathematical model and the computational algorithm for the modeling of two metal plates impact. In one-dimensional case the governing system of equations comprises seven equations: three conservation laws for each fluid and transfer equation for the volume fraction of one of the fluids. Both fluids are considered to be compressible and equilibrium on velocities. Pressures equilibrium is used as fluids interface condition. The system has hyperbolic type but could not be written in the conservative form because of nozzling terms in the right-hand side of the equations. The algorithm is based on the Harten-Lax-van Leer numerical flux function. The robust computation in the presence of the interface boundary is carried out due to the special pressure relaxation procedure. The problem is solved using stiffened gas equations of state for each fluid. The parameters in the equations of state are calibrated using the results of computations using wide-range equations of state for the metals. In simulations of metal plates impact we get two shocks after the initial impact that propagate to the free surfaces of the samples. The characteristics of shock waves are close (maximum relative error in characteristics of shocks is not greater than 7%) to the data from the wide-range equations of states computations.

Two-dimensional patterns in bacterial veils arise from self-generated, three-dimensional fluid flows.

PubMed

Cogan, N G; Wolgemuth, C W

2011-01-01

The behavior of collections of oceanic bacteria is controlled by metabolic (chemotaxis) and physical (fluid motion) processes. Some sulfur-oxidizing bacteria, such as Thiovulum majus, unite these two processes via a material interface produced by the bacteria and upon which the bacteria are transiently attached. This interface, termed a bacterial veil, is formed by exo-polymeric substances (EPS) produced by the bacteria. By adhering to the veil while continuing to rotate their flagella, the bacteria are able to exert force on the fluid surroundings. This behavior induces a fluid flow that, in turn, causes the bacteria to aggregate leading to the formation of a physical pattern in the veil. These striking patterns are very similar in flavor to the classic convection instability observed when a shallow fluid is heated from below. However, the physics are very different since the flow around the veil is mediated by the bacteria and affects the bacterial densities. In this study, we extend a model of a one-dimensional veil in a two-dimensional fluid to the more realistic two-dimensional veil in a three-dimensional fluid. The linear stability analysis indicates that the Peclet number serves as a bifurcation parameter, which is consistent with experimental observations. We also solve the nonlinear problem numerically and are able to obtain patterns that are similar to those observed in the experiments.

Pore-scale observation and 3D simulation of wettability effects on supercritical CO2 - brine immiscible displacement in drainage

NASA Astrophysics Data System (ADS)

Hu, R.; Wan, J.; Chen, Y.

2016-12-01

Wettability is a factor controlling the fluid-fluid displacement pattern in porous media and significantly affects the flow and transport of supercritical (sc) CO2 in geologic carbon sequestration. Using a high-pressure micromodel-microscopy system, we performed drainage experiments of scCO2 invasion into brine-saturated water-wet and intermediate-wet micromodels; we visualized the scCO2 invasion morphology at pore-scale under reservoir conditions. We also performed pore-scale numerical simulations of the Navier-Stokes equations to obtain 3D details of fluid-fluid displacement processes. Simulation results are qualitatively consistent with the experiments, showing wider scCO2 fingering, higher percentage of scCO2 and more compact displacement pattern in intermediate-wet micromodel. Through quantitative analysis based on pore-scale simulation, we found that the reduced wettability reduces the displacement front velocity, promotes the pore-filling events in the longitudinal direction, delays the breakthrough time of invading fluid, and then increases the displacement efficiency. Simulated results also show that the fluid-fluid interface area follows a unified power-law relation with scCO2 saturation, and show smaller interface area in intermediate-wet case which suppresses the mass transfer between the phases. These pore-scale results provide insights for the wettability effects on CO2 - brine immiscible displacement in geologic carbon sequestration.

Fluid-structure interactions of photo-responsive polymer cantilevers

NASA Astrophysics Data System (ADS)

Bin, Jonghoon; Oates, William S.; Yousuff Hussaini, M.

2013-02-01

A new class of photomechanical liquid crystal networks (LCNs) has emerged, which generate large bending deformation and fast response times that scale with the resonance of the polymer films. Here, a numerical study is presented that describes the photomechanical structural dynamic behavior of an LCN in a fluid medium; however, the methodology is also applicable to fluid-structure interactions of a broader range of adaptive structures. Here, we simulate the oscillation of photomechanical cantilevers excited by light while simultaneously modeling the effect of the surrounding fluid at different ambient pressures. The photoactuated LCN is modeled as an elastic thin cantilever plate, and gradients in photostrain from the external light are computed from the assumptions of light absorption and photoisomerization through the film thickness. Numerical approximations of the equations governing the plate are based on cubic B-spline shape functions and a second order implicit Newmark central scheme for time integration. For the fluid, three dimensional unsteady incompressible Navier-Stokes equations are solved using the arbitrary Lagrangian-Eulerian (ALE) method, which employs a structured body-fitted curvilinear coordinate system where the solid-fluid interface is a mesh line of the system, and the complicated interface boundary conditions are accommodated in a conventional finite-volume formulation. Numerical examples are given which provide new insight into material behavior in a fluid medium as a function of ambient pressure.

Determination of rock properties by low-frequency AC electrokinetics

NASA Astrophysics Data System (ADS)

Pengra, David B.; Xi Li, Sidney; Wong, Po-Zen

1999-12-01

In brine-saturated rock the existence of a mobile space charge at the fluid/solid interface leads to the electrokinetic phenomena of electroosmotic pressure and streaming potential. The coupling coefficients of these electrokinetic effects, when combined with the conductivity of the brine-saturated rock, determine the brine permeability of rock exactly. A sensitive low-frequency AC technique has been used to measure electrokinetic response of a collection of eight rock and four glass bead samples saturated with NaCl brine as a function of salt concentration (fluid conductivity of 0.5 to 6.38 S/m); the response of four of the original 12 samples has also been measured as a function of temperature from 0° to 50°C. All data verify the predicted permeability relationship. Additionally, the frequency response of the electroosmotic pressure signal alone can also be used to determine the permeability, given knowledge of experimental parameters. The concentration and temperature dependence of electroosmosis and streaming potential is found to mostly conform to the predictions of a simple model based on the Helmholtz-Smoluchowski equation, the Stern model of the electrochemical double layer, and an elementary theory of ionic conduction.

First evidence of non-locality in real band-gap metamaterials: determining parameters in the relaxed micromorphic model

PubMed Central

Barbagallo, Gabriele; d’Agostino, Marco Valerio; Placidi, Luca; Neff, Patrizio

2016-01-01

In this paper, we propose the first estimate of some elastic parameters of the relaxed micromorphic model on the basis of real experiments of transmission of longitudinal plane waves across an interface separating a classical Cauchy material (steel plate) and a phononic crystal (steel plate with fluid-filled holes). A procedure is set up in order to identify the parameters of the relaxed micromorphic model by superimposing the experimentally based profile of the reflection coefficient (plotted as function of the wave-frequency) with the analogous profile obtained via numerical simulations. We determine five out of six constitutive parameters which are featured by the relaxed micromorphic model in the isotropic case, plus the determination of the micro-inertia parameter. The sixth elastic parameter, namely the Cosserat couple modulus μc, still remains undetermined, since experiments on transverse incident waves are not yet available. A fundamental result of this paper is the estimate of the non-locality intrinsically associated with the underlying microstructure of the metamaterial. We show that the characteristic length Lc measuring the non-locality of the phononic crystal is of the order of 13 of the diameter of its fluid-filled holes. PMID:27436984

First evidence of non-locality in real band-gap metamaterials: determining parameters in the relaxed micromorphic model.

PubMed

Madeo, Angela; Barbagallo, Gabriele; d'Agostino, Marco Valerio; Placidi, Luca; Neff, Patrizio

2016-06-01

In this paper, we propose the first estimate of some elastic parameters of the relaxed micromorphic model on the basis of real experiments of transmission of longitudinal plane waves across an interface separating a classical Cauchy material (steel plate) and a phononic crystal (steel plate with fluid-filled holes). A procedure is set up in order to identify the parameters of the relaxed micromorphic model by superimposing the experimentally based profile of the reflection coefficient (plotted as function of the wave-frequency) with the analogous profile obtained via numerical simulations. We determine five out of six constitutive parameters which are featured by the relaxed micromorphic model in the isotropic case, plus the determination of the micro-inertia parameter. The sixth elastic parameter, namely the Cosserat couple modulus μ c , still remains undetermined, since experiments on transverse incident waves are not yet available. A fundamental result of this paper is the estimate of the non-locality intrinsically associated with the underlying microstructure of the metamaterial. We show that the characteristic length L c measuring the non-locality of the phononic crystal is of the order of [Formula: see text] of the diameter of its fluid-filled holes.

Image pre-processing method for near-wall PIV measurements over moving curved interfaces

NASA Astrophysics Data System (ADS)

Jia, L. C.; Zhu, Y. D.; Jia, Y. X.; Yuan, H. J.; Lee, C. B.

2017-03-01

PIV measurements near a moving interface are always difficult. This paper presents a PIV image pre-processing method that returns high spatial resolution velocity profiles near the interface. Instead of re-shaping or re-orientating the interrogation windows, interface tracking and an image transformation are used to stretch the particle image strips near a curved interface into rectangles. Then the adaptive structured interrogation windows can be arranged at specified distances from the interface. Synthetic particles are also added into the solid region to minimize interfacial effects and to restrict particles on both sides of the interface. Since a high spatial resolution is only required in high velocity gradient region, adaptive meshing and stretching of the image strips in the normal direction is used to improve the cross-correlation signal-to-noise ratio (SN) by reducing the velocity difference and the particle image distortion within the interrogation window. A two dimensional Gaussian fit is used to compensate for the effects of stretching particle images. The working hypothesis is that fluid motion near the interface is ‘quasi-tangential flow’, which is reasonable in most fluid-structure interaction scenarios. The method was validated against the window deformation iterative multi-grid scheme (WIDIM) using synthetic image pairs with different velocity profiles. The method was tested for boundary layer measurements of a supersonic turbulent boundary layer on a flat plate, near a rotating blade and near a flexible flapping flag. This image pre-processing method provides higher spatial resolution than conventional WIDIM and good robustness for measuring velocity profiles near moving interfaces.

On the temperature derivative of the surface tension at a critical end point

NASA Astrophysics Data System (ADS)

Robert, M.; Tavan, P.

1983-03-01

It is shown that, according to the van der Waals theory of fluid interfaces, the surface tension of the interface between a This result holds for any number of phases and independently varying densities and is not restricted to classical values of the critical exponents.

Nano-inspired smart interfaces: fluidic interactivity and its impact on heat transfer

NASA Astrophysics Data System (ADS)

Kim, Beom Seok; Lee, Byoung In; Lee, Namkyu; Choi, Geehong; Gemming, Thomas; Cho, Hyung Hee

2017-03-01

Interface-inspired convection is a key heat transfer scheme for hot spot cooling and thermal energy transfer. An unavoidable trade-off of the convective heat transfer is pressure loss caused by fluidic resistance on an interface. To overcome this limitation, we uncover that nano-inspired interfaces can trigger a peculiar fluidic interactivity, which can pursue all the two sides of the coin: heat transfer and fluidic friction. We demonstrate the validity of a quasi-fin effect of Si-based nanostructures based on conductive capability of heat dissipation valid under the interactivity with fluidic viscous sublayer. The exclusive fluid-interface friction is achieved when the height of the nanostructures is much less than the thickness of the viscous sublayers in the turbulent regime. The strategic nanostructures show an enhancement of heat transfer coefficients in the wall jet region by more than 21% without any significant macroscale pressure loss under single-phase impinging jet. Nanostructures guaranteeing fluid access via an equivalent vacancy larger than the diffusive path length of viscid flow lead to local heat transfer enhancement of more than 13% at a stagnation point. Functional nanostructures will give shape to possible breakthroughs in heat transfer and its optimization can be pursued for engineered systems.

Hyphenation of supercritical fluid chromatography with tandem mass spectrometry for fast determination of four aflatoxins in edible oil.

PubMed

Lei, Fang; Li, Chenglong; Zhou, Shuang; Wang, Dan; Zhao, Yunfeng; Wu, Yongning

2016-08-01

Aflatoxins (AFTs) are of great concern all over the world. Supercritical fluid chromatography (SFC) has the advantage of fast, high resolution and excellent compatibility with a broad range of organic solvents and samples, thus hyphenating SFC with tandem mass spectrometry (MS/MS) can be used for the easy and fast determination of AFTs in edible oils. Edible oil was spiked with isotope-labeled aflatoxin standards, diluted with hexane and extracted with acetonitrile. The extraction was directly loaded to an SFC apparatus and separated on a UPC(2) 2-EP column with CO2 -methanol gradient elution. A post-column make-up flow was introduced to facilitate mass spectrometry performance, and the mixture was analyzed by MS/MS with an electrospray ionization (ESI) source. The SFC conditions including separation column, modifier and sample solvent were optimized, and the four target aflatoxins were baseline separated. The ESI interface parameters were also investigated, implicating the make-up flow as a critical factor for sensitive determination by SFC-MS/MS. The LOQs for the AFTs were 0.05-0.12 μg L(-1) , while the RSDs were lower than 8.5%. Supercritical fluid chromatography was successfully coupled to tandem mass spectrometry to establish a simple, fast and sensitive method for the analysis of four aflatoxins in edible oil. This shows the combination of SFC-MS/MS has great potential in determination of trace contaminants in food. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Could Fluid Seeps Originate from the Seismogenic Zone? Evidence from Southern Costa Rica

NASA Astrophysics Data System (ADS)

Silver, E. A.; Kluesner, J. W.; Nale, S. M.; Bangs, N. L.; McIntosh, K. D.; Ranero, C. R.; Tryon, M. D.; Spinelli, G. A.; Rathburn, T.; von Huene, R.

2013-12-01

The prevailing conceptual model of convergent margin hydrogeology is one in which fluid sourced from porosity loss and dehydration reactions seaward of the updip limit of the seismogenic zone reach the seafloor via relatively low angle splay faults that act as high permeability conduits through an otherwise nearly impermeable upper plate [e.g., Lauer and Saffer, GRL, 39:L13604, 2012; Saffer and Tobin, Ann. Rev. Earth Planet. Sci., 39:157-186, 2011]. Interpretation of newly acquired 3D seismic reflection data and high resolvability multibeam and backscatter data, showing evidence for abundant potential fluid seeps sourced beneath the sediment cover and farther landward than previously thought possible, may require reevaluation of this concept. Kluesner et al. [2013, G3, doi:10.1002/ggge.20058], identified 160 potential fluid seeps in an 11 km wide swath off southern Costa Rica, based on pockmarks and high backscatter mounds, each showing subsurface indicators of fluid migration in the seismic data. Approximately half of these potential seeps are on the outer continental shelf; these are landward of the updip limit of the seismogenic zone, as estimated by both the transition from high to low reflectivity of the plate boundary and the intersection of the 150°C isotherm with the plate boundary [Ranero et al., 2008, G3, doi:10.1029/2007GC001679; Bangs et al., 2012, AGU Fall Meeting, T13A-2587; Bangs et al., this meeting]. We have mapped high probability fluid pathways beneath these potential seeps, based on seismic meta-attribute volumes calculated using user-trained neural network algorithms [Kluesner et al., this meeting]. The mapped fluid pathways are high-angle through the sedimentary section, and they root into basement highs and basement faults. Fluids could originate along the plate interface, where potential sources and pathways are known (Mid-slope sites: Hensen et al., 2004, Geology, 32:201-204), or above or below the interface, although sources from these regions have not been reported. They could travel near vertical paths through the crustal rocks, or along a landward-dipping path, because the seismic data show landward dips but not seaward dips. If the fluids do come from the plate interface, they originate in the seismogenic zone. This inference can be tested by geochemical study of the outer shelf fluid seeps, where such sampling has not yet occurred.

Shear Stress Sensing using Elastomer Micropillar Arrays

NASA Technical Reports Server (NTRS)

Wohl, Christopher J.; Palmieri, Frank L.; Lin, Yi; Jackson, Allen M.; Cissoto, Alexxandra; Sheplak, Mark; Connell, John W.

2013-01-01

The measurement of shear stress developed as a fluid moves around a solid body is difficult to measure. Stresses at the fluid-solid interface are very small and the nature of the fluid flow is easily disturbed by introducing sensor components to the interface. To address these challenges, an array of direct and indirect techniques have been investigated with various advantages and challenges. Hot wire sensors and other indirect sensors all protrude significantly into the fluid flow. Microelectromechanical systems (MEMS) devices, although facilitating very accurate measurements, are not durable, are prone to contamination, and are difficult to implement into existing model geometries. One promising approach is the use of engineered surfaces that interact with fluid flow in a detectable manner. To this end, standard lithographic techniques have been utilized to generate elastomeric micropillar arrays of various lengths and diameters. Micropillars of controlled length and width were generated in polydimethylsiloxane (PDMS) elastomer using a soft-lithography technique. The 3D mold for micropillar replication was fabricated using laser ablative micromachining and contact lithography. Micropillar dimensions and mechanical properties were characterized and compared to shear sensing requirements. The results of this characterization as well as shear stress detection techniques will be discussed.