Sample records for flux estimation methods

  1. Investigation of error sources in regional inverse estimates of greenhouse gas emissions in Canada

    NASA Astrophysics Data System (ADS)

    Chan, E.; Chan, D.; Ishizawa, M.; Vogel, F.; Brioude, J.; Delcloo, A.; Wu, Y.; Jin, B.

    2015-08-01

    Inversion models can use atmospheric concentration measurements to estimate surface fluxes. This study is an evaluation of the errors in a regional flux inversion model for different provinces of Canada, Alberta (AB), Saskatchewan (SK) and Ontario (ON). Using CarbonTracker model results as the target, the synthetic data experiment analyses examined the impacts of the errors from the Bayesian optimisation method, prior flux distribution and the atmospheric transport model, as well as their interactions. The scaling factors for different sub-regions were estimated by the Markov chain Monte Carlo (MCMC) simulation and cost function minimization (CFM) methods. The CFM method results are sensitive to the relative size of the assumed model-observation mismatch and prior flux error variances. Experiment results show that the estimation error increases with the number of sub-regions using the CFM method. For the region definitions that lead to realistic flux estimates, the numbers of sub-regions for the western region of AB/SK combined and the eastern region of ON are 11 and 4 respectively. The corresponding annual flux estimation errors for the western and eastern regions using the MCMC (CFM) method are -7 and -3 % (0 and 8 %) respectively, when there is only prior flux error. The estimation errors increase to 36 and 94 % (40 and 232 %) resulting from transport model error alone. When prior and transport model errors co-exist in the inversions, the estimation errors become 5 and 85 % (29 and 201 %). This result indicates that estimation errors are dominated by the transport model error and can in fact cancel each other and propagate to the flux estimates non-linearly. In addition, it is possible for the posterior flux estimates having larger differences than the prior compared to the target fluxes, and the posterior uncertainty estimates could be unrealistically small that do not cover the target. The systematic evaluation of the different components of the inversion model can help in the understanding of the posterior estimates and percentage errors. Stable and realistic sub-regional and monthly flux estimates for western region of AB/SK can be obtained, but not for the eastern region of ON. This indicates that it is likely a real observation-based inversion for the annual provincial emissions will work for the western region whereas; improvements are needed with the current inversion setup before real inversion is performed for the eastern region.

  2. Improved vertical streambed flux estimation using multiple diurnal temperature methods in series

    USGS Publications Warehouse

    Irvine, Dylan J.; Briggs, Martin A.; Cartwright, Ian; Scruggs, Courtney; Lautz, Laura K.

    2017-01-01

    Analytical solutions that use diurnal temperature signals to estimate vertical fluxes between groundwater and surface water based on either amplitude ratios (Ar) or phase shifts (Δϕ) produce results that rarely agree. Analytical solutions that simultaneously utilize Ar and Δϕ within a single solution have more recently been derived, decreasing uncertainty in flux estimates in some applications. Benefits of combined (ArΔϕ) methods also include that thermal diffusivity and sensor spacing can be calculated. However, poor identification of either Ar or Δϕ from raw temperature signals can lead to erratic parameter estimates from ArΔϕ methods. An add-on program for VFLUX 2 is presented to address this issue. Using thermal diffusivity selected from an ArΔϕ method during a reliable time period, fluxes are recalculated using an Ar method. This approach maximizes the benefits of the Ar and ArΔϕ methods. Additionally, sensor spacing calculations can be used to identify periods with unreliable flux estimates, or to assess streambed scour. Using synthetic and field examples, the use of these solutions in series was particularly useful for gaining conditions where fluxes exceeded 1 m/d.

  3. Uncertainty of streamwater solute fluxes in five contrasting headwater catchments including model uncertainty and natural variability (Invited)

    NASA Astrophysics Data System (ADS)

    Aulenbach, B. T.; Burns, D. A.; Shanley, J. B.; Yanai, R. D.; Bae, K.; Wild, A.; Yang, Y.; Dong, Y.

    2013-12-01

    There are many sources of uncertainty in estimates of streamwater solute flux. Flux is the product of discharge and concentration (summed over time), each of which has measurement uncertainty of its own. Discharge can be measured almost continuously, but concentrations are usually determined from discrete samples, which increases uncertainty dependent on sampling frequency and how concentrations are assigned for the periods between samples. Gaps between samples can be estimated by linear interpolation or by models that that use the relations between concentration and continuously measured or known variables such as discharge, season, temperature, and time. For this project, developed in cooperation with QUEST (Quantifying Uncertainty in Ecosystem Studies), we evaluated uncertainty for three flux estimation methods and three different sampling frequencies (monthly, weekly, and weekly plus event). The constituents investigated were dissolved NO3, Si, SO4, and dissolved organic carbon (DOC), solutes whose concentration dynamics exhibit strongly contrasting behavior. The evaluation was completed for a 10-year period at five small, forested watersheds in Georgia, New Hampshire, New York, Puerto Rico, and Vermont. Concentration regression models were developed for each solute at each of the three sampling frequencies for all five watersheds. Fluxes were then calculated using (1) a linear interpolation approach, (2) a regression-model method, and (3) the composite method - which combines the regression-model method for estimating concentrations and the linear interpolation method for correcting model residuals to the observed sample concentrations. We considered the best estimates of flux to be derived using the composite method at the highest sampling frequencies. We also evaluated the importance of sampling frequency and estimation method on flux estimate uncertainty; flux uncertainty was dependent on the variability characteristics of each solute and varied for different reporting periods (e.g. 10-year, study period vs. annually vs. monthly). The usefulness of the two regression model based flux estimation approaches was dependent upon the amount of variance in concentrations the regression models could explain. Our results can guide the development of optimal sampling strategies by weighing sampling frequency with improvements in uncertainty in stream flux estimates for solutes with particular characteristics of variability. The appropriate flux estimation method is dependent on a combination of sampling frequency and the strength of concentration regression models. Sites: Biscuit Brook (Frost Valley, NY), Hubbard Brook Experimental Forest and LTER (West Thornton, NH), Luquillo Experimental Forest and LTER (Luquillo, Puerto Rico), Panola Mountain (Stockbridge, GA), Sleepers River Research Watershed (Danville, VT)

  4. Updated Magmatic Flux Rate Estimates for the Hawaii Plume

    NASA Astrophysics Data System (ADS)

    Wessel, P.

    2013-12-01

    Several studies have estimated the magmatic flux rate along the Hawaiian-Emperor Chain using a variety of methods and arriving at different results. These flux rate estimates have weaknesses because of incomplete data sets and different modeling assumptions, especially for the youngest portion of the chain (<3 Ma). While they generally agree on the 1st order features, there is less agreement on the magnitude and relative size of secondary flux variations. Some of these differences arise from the use of different methodologies, but the significance of this variability is difficult to assess due to a lack of confidence bounds on the estimates obtained with these disparate methods. All methods introduce some error, but to date there has been little or no quantification of error estimates for the inferred melt flux, making an assessment problematic. Here we re-evaluate the melt flux for the Hawaii plume with the latest gridded data sets (SRTM30+ and FAA 21.1) using several methods, including the optimal robust separator (ORS) and directional median filtering techniques (DiM). We also compute realistic confidence limits on the results. In particular, the DiM technique was specifically developed to aid in the estimation of surface loads that are superimposed on wider bathymetric swells and it provides error estimates on the optimal residuals. Confidence bounds are assigned separately for the estimated surface load (obtained from the ORS regional/residual separation techniques) and the inferred subsurface volume (from gravity-constrained isostasy and plate flexure optimizations). These new and robust estimates will allow us to assess which secondary features in the resulting melt flux curve are significant and should be incorporated when correlating melt flux variations with other geophysical and geochemical observations.

  5. Estimation of regional surface CO2 fluxes with GOSAT observations using two inverse modeling approaches

    NASA Astrophysics Data System (ADS)

    Maksyutov, Shamil; Takagi, Hiroshi; Belikov, Dmitry A.; Saeki, Tazu; Zhuravlev, Ruslan; Ganshin, Alexander; Lukyanov, Alexander; Yoshida, Yukio; Oshchepkov, Sergey; Bril, Andrey; Saito, Makoto; Oda, Tomohiro; Valsala, Vinu K.; Saito, Ryu; Andres, Robert J.; Conway, Thomas; Tans, Pieter; Yokota, Tatsuya

    2012-11-01

    Inverse estimation of surface C02 fluxes is performed with atmospheric transport model using ground-based and GOSAT observations. The NIES-retrieved C02 column mixing (Xc02) and column averaging kernel are provided by GOSAT Level 2 product v. 2.0 and PPDF-DOAS method. Monthly mean C02 fluxes for 64 regions are estimated together with a global mean offset between GOSAT data and ground-based data. We used the fixed-lag Kalman filter to infer monthly fluxes for 42 sub-continental terrestrial regions and 22 oceanic basins. We estimate fluxes and compare results obtained by two inverse modeling approaches. In basic approach adopted in GOSAT Level4 product v. 2.01, we use aggregation of the GOSAT observations into monthly mean over 5x5 degree grids, fluxes are estimated independently for each region, and NIES atmospheric transport model is used for forward simulation. In the alternative method, the model-observation misfit is estimated for each observation separately and fluxes are spatially correlated using EOF analysis of the simulated flux variability similar to geostatistical approach, while transport simulation is enhanced by coupling with a Lagrangian transport model Flexpart. Both methods use using the same set of prior fluxes and region maps. Daily net ecosystem exchange (NEE) is predicted by the Vegetation Integrative Simulator for Trace gases (VISIT) optimized to match seasonal cycle of the atmospheric C02 . Monthly ocean-atmosphere C02 fluxes are produced with an ocean pC02 data assimilation system. Biomass burning fluxes were provided by the Global Fire Emissions Database (GFED); and monthly fossil fuel C02 emissions are estimated with ODIAC inventory. The results of analyzing one year of the GOSAT data suggest that when both GOSAT and ground-based data are used together, fluxes in tropical and other remote regions with lower associated uncertainties are obtained than in the analysis using only ground-based data. With version 2.0 of L2 Xc02 the fluxes appear reasonable for many regions and seasons, however there is a need for improving the L2 bias correction, data filtering and the inverse modeling method to reduce estimated flux anomalies visible in some areas. We also observe that application of spatial flux correlations with EOF­ based approach reduces flux anomalies.

  6. A comparison of sap flux-based evapotranspiration estimates with catchment-scale water balance

    Treesearch

    Chelcy R. Ford; Robert M. Hubbard; Brian D. Kloeppel; James M. Vose

    2007-01-01

    Many researchers are using sap flux to estimate tree-level transpiration, and to scale to stand- and catchment-level transpiration; yet studies evaluating the comparability of sap flux-based estimates of transpiration (E) with alternative methods for estimating Et at this spatial scale are rare. Our ability to...

  7. Application of the Combination Approach for Estimating Evapotranspiration in Puerto Rico

    NASA Technical Reports Server (NTRS)

    Harmsen, Eric; Luvall, Jeffrey; Gonzalez, Jorge

    2005-01-01

    The ability to estimate short-term fluxes of water vapor from the land surface is important for validating latent heat flux estimates from high resolution remote sensing techniques. A new, relatively inexpensive method is presented for estimating t h e ground-based values of the surface latent heat flux or evapotranspiration.

  8. Infrasound Waveform Inversion and Mass Flux Validation from Sakurajima Volcano, Japan

    NASA Astrophysics Data System (ADS)

    Fee, D.; Kim, K.; Yokoo, A.; Izbekov, P. E.; Lopez, T. M.; Prata, F.; Ahonen, P.; Kazahaya, R.; Nakamichi, H.; Iguchi, M.

    2015-12-01

    Recent advances in numerical wave propagation modeling and station coverage have permitted robust inversion of infrasound data from volcanic explosions. Complex topography and crater morphology have been shown to substantially affect the infrasound waveform, suggesting that homogeneous acoustic propagation assumptions are invalid. Infrasound waveform inversion provides an exciting tool to accurately characterize emission volume and mass flux from both volcanic and non-volcanic explosions. Mass flux, arguably the most sought-after parameter from a volcanic eruption, can be determined from the volume flux using infrasound waveform inversion if the volcanic flow is well-characterized. Thus far, infrasound-based volume and mass flux estimates have yet to be validated. In February 2015 we deployed six infrasound stations around the explosive Sakurajima Volcano, Japan for 8 days. Here we present our full waveform inversion method and volume and mass flux estimates of numerous high amplitude explosions using a high resolution DEM and 3-D Finite Difference Time Domain modeling. Application of this technique to volcanic eruptions may produce realistic estimates of mass flux and plume height necessary for volcanic hazard mitigation. Several ground-based instruments and methods are used to independently determine the volume, composition, and mass flux of individual volcanic explosions. Specifically, we use ground-based ash sampling, multispectral infrared imagery, UV spectrometry, and multigas data to estimate the plume composition and flux. Unique tiltmeter data from underground tunnels at Sakurajima also provides a way to estimate the volume and mass of each explosion. In this presentation we compare the volume and mass flux estimates derived from the different methods and discuss sources of error and future improvements.

  9. Evapotranspiration: Mass balance measurements compared with flux estimation methods

    USDA-ARS?s Scientific Manuscript database

    Evapotranspiration (ET) may be measured by mass balance methods and estimated by flux sensing methods. The mass balance methods are typically restricted in terms of the area that can be represented (e.g., surface area of weighing lysimeter (LYS) or equivalent representative area of neutron probe (NP...

  10. Inverse modeling of Asian (222)Rn flux using surface air (222)Rn concentration.

    PubMed

    Hirao, Shigekazu; Yamazawa, Hiromi; Moriizumi, Jun

    2010-11-01

    When used with an atmospheric transport model, the (222)Rn flux distribution estimated in our previous study using soil transport theory caused underestimation of atmospheric (222)Rn concentrations as compared with measurements in East Asia. In this study, we applied a Bayesian synthesis inverse method to produce revised estimates of the annual (222)Rn flux density in Asia by using atmospheric (222)Rn concentrations measured at seven sites in East Asia. The Bayesian synthesis inverse method requires a prior estimate of the flux distribution and its uncertainties. The atmospheric transport model MM5/HIRAT and our previous estimate of the (222)Rn flux distribution as the prior value were used to generate new flux estimates for the eastern half of the Eurasian continent dividing into 10 regions. The (222)Rn flux densities estimated using the Bayesian inversion technique were generally higher than the prior flux densities. The area-weighted average (222)Rn flux density for Asia was estimated to be 33.0 mBq m(-2) s(-1), which is substantially higher than the prior value (16.7 mBq m(-2) s(-1)). The estimated (222)Rn flux densities decrease with increasing latitude as follows: Southeast Asia (36.7 mBq m(-2) s(-1)); East Asia (28.6 mBq m(-2) s(-1)) including China, Korean Peninsula and Japan; and Siberia (14.1 mBq m(-2) s(-1)). Increase of the newly estimated fluxes in Southeast Asia, China, Japan, and the southern part of Eastern Siberia from the prior ones contributed most significantly to improved agreement of the model-calculated concentrations with the atmospheric measurements. The sensitivity analysis of prior flux errors and effects of locally exhaled (222)Rn showed that the estimated fluxes in Northern and Central China, Korea, Japan, and the southern part of Eastern Siberia were robust, but that in Central Asia had a large uncertainty.

  11. Improved Satellite Estimation of Near-Surface Humidity Using Vertical Water Vapor Profile Information

    NASA Astrophysics Data System (ADS)

    Tomita, H.; Hihara, T.; Kubota, M.

    2018-01-01

    Near-surface air-specific humidity is a key variable in the estimation of air-sea latent heat flux and evaporation from the ocean surface. An accurate estimation over the global ocean is required for studies on global climate, air-sea interactions, and water cycles. Current remote sensing techniques are problematic and a major source of errors for flux and evaporation. Here we propose a new method to estimate surface humidity using satellite microwave radiometer instruments, based on a new finding about the relationship between multichannel brightness temperatures measured by satellite sensors, surface humidity, and vertical moisture structure. Satellite estimations using the new method were compared with in situ observations to evaluate this method, confirming that it could significantly improve satellite estimations with high impact on satellite estimation of latent heat flux. We recommend the adoption of this method for any satellite microwave radiometer observations.

  12. Turbulent heat fluxes by profile and inertial dissipation methods: analysis of the atmospheric surface layer from shipboard measurements during the SOFIA/ASTEX and SEMAPHORE experiments

    NASA Astrophysics Data System (ADS)

    Dupuis, Hélène; Weill, Alain; Katsaros, Kristina; Taylor, Peter K.

    1995-10-01

    Heat flux estimates obtained using the inertial dissipation method, and the profile method applied to radiosonde soundings, are assessed with emphasis on the parameterization of the roughness lengths for temperature and specific humidity. Results from the inertial dissipation method show a decrease of the temperature and humidity roughness lengths for increasing neutral wind speed, in agreement with previous studies. The sensible heat flux estimates were obtained using the temperature estimated from the speed of sound determined by a sonic anemometer. This method seems very attractive for estimating heat fluxes over the ocean. However allowance must be made in the inertial dissipation method for non-neutral stratification. The SOFIA/ASTEX and SEMAPHORE results show that, in unstable stratification, a term due to the transport terms in the turbulent kinetic energy budget, has to be included in order to determine the friction velocity with better accuracy. Using the profile method with radiosonde data, the roughness length values showed large scatter. A reliable estimate of the temperature roughness length could not be obtained. The humidity roughness length values were compatible with those found using the inertial dissipation method.

  13. A note on the effective evaluation height for flux-gradient relationships and its application to herbicide fluxes

    USDA-ARS?s Scientific Manuscript database

    Volatilization represents a significant loss pathway for many pesticides, herbicides and other agrochemicals. One common method for measuring the volatilization of agrochemicals is the flux-gradient method. Using this method, the chemical flux is estimated as the product of the vertical concentratio...

  14. Streamflow and Nutrient Fluxes of the Mississippi-Atchafalaya River Basin and Subbasins for the Period of Record Through 2005

    USGS Publications Warehouse

    Aulenbach, Brent T.; Buxton, Herbert T.; Battaglin, William A.; Coupe, Richard H.

    2007-01-01

    U.S. Geological Survey has monitored streamflow and water quality systematically in the Mississippi-Atchafalaya River Basin (MARB) for more than five decades. This report provides streamflow and estimates of nutrient delivery (flux) to the Gulf of Mexico from both the Atchafalaya River and the main stem of the Mississippi River. This report provides streamflow and nutrient flux estimates for nine major subbasins of the Mississippi River. This report also provides streamflow and flux estimates for 21 selected subbasins of various sizes, hydrology, land use, and geographic location within the Basin. The information is provided at each station for the period for which sufficient water-quality data are available to make statistically based flux estimates (starting as early as water year1 1960 and going through water year 2005). Nutrient fluxes are estimated using the adjusted maximum likelihood estimate, a type of regression-model method; nutrient fluxes to the Gulf of Mexico also are estimated using the composite method. Regression models were calibrated using a 5-year moving calibration period; the model was used to estimate the last year of the calibration period. Nutrient flux estimates are provided for six water-quality constituents: dissolved nitrite plus nitrate, total organic nitrogen plus ammonia nitrogen (total Kjeldahl nitrogen), dissolved ammonia, total phosphorous, dissolved orthophosphate, and dissolved silica. Additionally, the contribution of streamflow and net nutrient flux for five large subbasins comprising the MARB were determined from streamflow and nutrient fluxes from seven of the aforementioned major subbasins. These five large subbasins are: 1. Lower Mississippi, 2. Upper Mississippi, 3. Ohio/Tennessee, 4. Missouri, and 5. Arkansas/Red.

  15. Finite Element A Posteriori Error Estimation for Heat Conduction. Degree awarded by George Washington Univ.

    NASA Technical Reports Server (NTRS)

    Lang, Christapher G.; Bey, Kim S. (Technical Monitor)

    2002-01-01

    This research investigates residual-based a posteriori error estimates for finite element approximations of heat conduction in single-layer and multi-layered materials. The finite element approximation, based upon hierarchical modelling combined with p-version finite elements, is described with specific application to a two-dimensional, steady state, heat-conduction problem. Element error indicators are determined by solving an element equation for the error with the element residual as a source, and a global error estimate in the energy norm is computed by collecting the element contributions. Numerical results of the performance of the error estimate are presented by comparisons to the actual error. Two methods are discussed and compared for approximating the element boundary flux. The equilibrated flux method provides more accurate results for estimating the error than the average flux method. The error estimation is applied to multi-layered materials with a modification to the equilibrated flux method to approximate the discontinuous flux along a boundary at the material interfaces. A directional error indicator is developed which distinguishes between the hierarchical modeling error and the finite element error. Numerical results are presented for single-layered materials which show that the directional indicators accurately determine which contribution to the total error dominates.

  16. Evapotranspiration Measurement and Estimation: Weighing Lysimeter and Neutron Probe Based Methods Compared with Eddy Covariance

    NASA Astrophysics Data System (ADS)

    Evett, S. R.; Gowda, P. H.; Marek, G. W.; Alfieri, J. G.; Kustas, W. P.; Brauer, D. K.

    2014-12-01

    Evapotranspiration (ET) may be measured by mass balance methods and estimated by flux sensing methods. The mass balance methods are typically restricted in terms of the area that can be represented (e.g., surface area of weighing lysimeter (LYS) or equivalent representative area of neutron probe (NP) and soil core sampling techniques), and can be biased with respect to ET from the surrounding area. The area represented by flux sensing methods such as eddy covariance (EC) is typically estimated with a flux footprint/source area model. The dimension, position of, and relative contribution of upwind areas within the source area are mainly influenced by sensor height, wind speed, atmospheric stability and wind direction. Footprints for EC sensors positioned several meters above the canopy are often larger than can be economically covered by mass balance methods. Moreover, footprints move with atmospheric conditions and wind direction to cover different field areas over time while mass balance methods are static in space. Thus, EC systems typically sample a much greater field area over time compared with mass balance methods. Spatial variability of surface cover can thus complicate interpretation of flux estimates from EC systems. The most commonly used flux estimation method is EC; and EC estimates of latent heat energy (representing ET) and sensible heat fluxes combined are typically smaller than the available energy from net radiation and soil heat flux (commonly referred to as lack of energy balance closure). Reasons for this are the subject of ongoing research. We compare ET from LYS, NP and EC methods applied to field crops for three years at Bushland, Texas (35° 11' N, 102° 06' W, 1170 m elevation above MSL) to illustrate the potential problems with and comparative advantages of all three methods. In particular, we examine how networks of neutron probe access tubes can be representative of field areas large enough to be equivalent in size to EC footprints, and how the ET data from these methods can address bias and accuracy issues.

  17. Estimation of Turbulent Heat Fluxes by Assimilation of Land Surface Temperature Observations From GOES Satellites Into an Ensemble Kalman Smoother Framework

    NASA Astrophysics Data System (ADS)

    Xu, Tongren; Bateni, S. M.; Neale, C. M. U.; Auligne, T.; Liu, Shaomin

    2018-03-01

    In different studies, land surface temperature (LST) observations have been assimilated into the variational data assimilation (VDA) approaches to estimate turbulent heat fluxes. The VDA methods yield accurate turbulent heat fluxes, but they need an adjoint model, which is difficult to derive and code. They also cannot directly calculate the uncertainty of their estimates. To overcome the abovementioned drawbacks, this study assimilates LST data from Geostationary Operational Environmental Satellite into the ensemble Kalman smoother (EnKS) data assimilation system to estimate turbulent heat fluxes. EnKS does not need to derive the adjoint term and directly generates statistical information on the accuracy of its predictions. It uses the heat diffusion equation to simulate LST. EnKS with the state augmentation approach finds the optimal values for the unknown parameters (i.e., evaporative fraction and neutral bulk heat transfer coefficient, CHN) by minimizing the misfit between LST observations from Geostationary Operational Environmental Satellite and LST estimations from the heat diffusion equation. The augmented EnKS scheme is tested over six Ameriflux sites with a wide range of hydrological and vegetative conditions. The results show that EnKS can predict not only the model parameters and turbulent heat fluxes but also their uncertainties over a variety of land surface conditions. Compared to the variational method, EnKS yields suboptimal turbulent heat fluxes. However, suboptimality of EnKS is small, and its results are comparable to those of the VDA method. Overall, EnKS is a feasible and reliable method for estimation of turbulent heat fluxes.

  18. A Bayesian Framework for Coupled Estimation of Key Unknown Parameters of Land Water and Energy Balance Equations

    NASA Astrophysics Data System (ADS)

    Farhadi, L.; Abdolghafoorian, A.

    2015-12-01

    The land surface is a key component of climate system. It controls the partitioning of available energy at the surface between sensible and latent heat, and partitioning of available water between evaporation and runoff. Water and energy cycle are intrinsically coupled through evaporation, which represents a heat exchange as latent heat flux. Accurate estimation of fluxes of heat and moisture are of significant importance in many fields such as hydrology, climatology and meteorology. In this study we develop and apply a Bayesian framework for estimating the key unknown parameters of terrestrial water and energy balance equations (i.e. moisture and heat diffusion) and their uncertainty in land surface models. These equations are coupled through flux of evaporation. The estimation system is based on the adjoint method for solving a least-squares optimization problem. The cost function consists of aggregated errors on state (i.e. moisture and temperature) with respect to observation and parameters estimation with respect to prior values over the entire assimilation period. This cost function is minimized with respect to parameters to identify models of sensible heat, latent heat/evaporation and drainage and runoff. Inverse of Hessian of the cost function is an approximation of the posterior uncertainty of parameter estimates. Uncertainty of estimated fluxes is estimated by propagating the uncertainty for linear and nonlinear function of key parameters through the method of First Order Second Moment (FOSM). Uncertainty analysis is used in this method to guide the formulation of a well-posed estimation problem. Accuracy of the method is assessed at point scale using surface energy and water fluxes generated by the Simultaneous Heat and Water (SHAW) model at the selected AmeriFlux stations. This method can be applied to diverse climates and land surface conditions with different spatial scales, using remotely sensed measurements of surface moisture and temperature states

  19. Annual sediment flux estimates in a tidal strait using surrogate measurements

    USGS Publications Warehouse

    Ganju, N.K.; Schoellhamer, D.H.

    2006-01-01

    Annual suspended-sediment flux estimates through Carquinez Strait (the seaward boundary of Suisun Bay, California) are provided based on surrogate measurements for advective, dispersive, and Stokes drift flux. The surrogates are landward watershed discharge, suspended-sediment concentration at one location in the Strait, and the longitudinal salinity gradient. The first two surrogates substitute for tidally averaged discharge and velocity-weighted suspended-sediment concentration in the Strait, thereby providing advective flux estimates, while Stokes drift is estimated with suspended-sediment concentration alone. Dispersive flux is estimated using the product of longitudinal salinity gradient and the root-mean-square value of velocity-weighted suspended-sediment concentration as an added surrogate variable. Cross-sectional measurements validated the use of surrogates during the monitoring period. During high freshwater flow advective and dispersive flux were in the seaward direction, while landward dispersive flux dominated and advective flux approached zero during low freshwater flow. Stokes drift flux was consistently in the landward direction. Wetter than average years led to net export from Suisun Bay, while dry years led to net sediment import. Relatively low watershed sediment fluxes to Suisun Bay contribute to net export during the wet season, while gravitational circulation in Carquinez Strait and higher suspended-sediment concentrations in San Pablo Bay (seaward end of Carquinez Strait) are responsible for the net import of sediment during the dry season. Annual predictions of suspended-sediment fluxes, using these methods, will allow for a sediment budget for Suisun Bay, which has implications for marsh restoration and nutrient/contaminant transport. These methods also provide a general framework for estimating sediment fluxes in estuarine environments, where temporal and spatial variability of transport are large. ?? 2006 Elsevier Ltd. All rights reserved.

  20. Quantifying and reducing the differences in forest CO 2-fluxes estimated by eddy covariance, biometric and chamber methods: A global synthesis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Xingchang; Wang, Chuankuan; Bond-Lamberty, Benjamin

    Carbon dioxide (CO 2) fluxes between terrestrial ecosystems and the atmosphere are primarily measured with eddy covariance (EC), biometric, and chamber methods. However, it is unclear why the estimates of CO 2-fluxes, when measured using these different methods, converge at some sites but diverge at others. We synthesized a novel global dataset of forest CO 2-fluxes to evaluate the consistency between EC and biometric or chamber methods for quantifying CO 2 budget in forests. The EC approach, comparing with the other two methods, tended to produce 25% higher estimate of net ecosystem production (NEP, 0.52Mg C ha-1 yr-1), mainly resultingmore » from lower EC-estimated Re; 10% lower ecosystem respiration (Re, 1.39Mg C ha-1 yr-1); and 3% lower gross primary production (0.48 Mg C ha-1 yr-1) The discrepancies between EC and the other methods were higher at sites with complex topography and dense canopies versus those with flat topography and open canopies. Forest age also influenced the discrepancy through the change of leaf area index. The open-path EC system induced >50% of the discrepancy in NEP, presumably due to its surface heating effect. These results provided strong evidence that EC produces biased estimates of NEP and Re in forest ecosystems. A global extrapolation suggested that the discrepancies in CO 2 fluxes between methods were consistent with a global underestimation of Re, and overestimation of NEP, by the EC method. Accounting for these discrepancies would substantially improve the our estimates of the terrestrial carbon budget .« less

  1. Theoretical simulation of the dual-heat-flux method in deep body temperature measurements.

    PubMed

    Huang, Ming; Chen, Wenxi

    2010-01-01

    Deep body temperature reveals individual physiological states, and is important in patient monitoring and chronobiological studies. An innovative dual-heat-flux method has been shown experimentally to be competitive with the conventional zero-heat-flow method in its performance, in terms of measurement accuracy and step response to changes in the deep temperature. We have utilized a finite element method to model and simulate the dynamic process of a dual-heat-flux probe in deep body temperature measurements to validate the fundamental principles of the dual-heat-flux method theoretically, and to acquire a detailed quantitative description of the thermal profile of the dual-heat-flux probe. The simulation results show that the estimated deep body temperature is influenced by the ambient temperature (linearly, at a maximum rate of 0.03 °C/°C) and the blood perfusion rate. The corresponding depth of the estimated temperature in the skin and subcutaneous tissue layer is consistent when using the dual-heat-flux probe. Insights in improving the performance of the dual-heat-flux method were discussed for further studies of dual-heat-flux probes, taking into account structural and geometric considerations.

  2. Flux estimation of the FIFE planetary boundary layer (PBL) with 10.6 micron Doppler lidar

    NASA Technical Reports Server (NTRS)

    Gal-Chen, Tzvi; Xu, Mei; Eberhard, Wynn

    1990-01-01

    A method is devised for calculating wind, momentum, and other flux parameters that characterize the planetary boundary layer (PBL) and thereby facilitate the calibration of spaceborne vs. in situ flux estimates. Single Doppler lidar data are used to estimate the variance of the mean wind and the covariance related to the vertically pointing fluxes of horizontal momentum. The skewness of the vertical velocity and the range of kinetic energy dissipation are also estimated, and the surface heat flux is determined by means of a statistical Navier-Stokes equation. The conclusion shows that the PBL structure combines both 'bottom-up' and 'top-down' processes suggesting that the relevant parameters for the atmospheric boundary layer be revised. The conclusions are of significant interest to the modeling techniques used in General Circulation Models as well as to flux estimation.

  3. Impacts of sampling design and estimation methods on nutrient leaching of intensively monitored forest plots in the Netherlands.

    PubMed

    de Vries, W; Wieggers, H J J; Brus, D J

    2010-08-05

    Element fluxes through forest ecosystems are generally based on measurements of concentrations in soil solution at regular time intervals at plot locations sampled in a regular grid. Here we present spatially averaged annual element leaching fluxes in three Dutch forest monitoring plots using a new sampling strategy in which both sampling locations and sampling times are selected by probability sampling. Locations were selected by stratified random sampling with compact geographical blocks of equal surface area as strata. In each sampling round, six composite soil solution samples were collected, consisting of five aliquots, one per stratum. The plot-mean concentration was estimated by linear regression, so that the bias due to one or more strata being not represented in the composite samples is eliminated. The sampling times were selected in such a way that the cumulative precipitation surplus of the time interval between two consecutive sampling times was constant, using an estimated precipitation surplus averaged over the past 30 years. The spatially averaged annual leaching flux was estimated by using the modeled daily water flux as an ancillary variable. An important advantage of the new method is that the uncertainty in the estimated annual leaching fluxes due to spatial and temporal variation and resulting sampling errors can be quantified. Results of this new method were compared with the reference approach in which daily leaching fluxes were calculated by multiplying daily interpolated element concentrations with daily water fluxes and then aggregated to a year. Results show that the annual fluxes calculated with the reference method for the period 2003-2005, including all plots, elements and depths, lies only in 53% of the cases within the range of the average +/-2 times the standard error of the new method. Despite the differences in results, both methods indicate comparable N retention and strong Al mobilization in all plots, with Al leaching being nearly equal to the leaching of SO(4) and NO(3) with fluxes expressed in mol(c) ha(-1) yr(-1). This illustrates that Al release, which is the clearest signal of soil acidification, is mainly due to the external input of SO(4) and NO(3).

  4. Designing efficient nitrous oxide sampling strategies in agroecosystems using simulation models

    NASA Astrophysics Data System (ADS)

    Saha, Debasish; Kemanian, Armen R.; Rau, Benjamin M.; Adler, Paul R.; Montes, Felipe

    2017-04-01

    Annual cumulative soil nitrous oxide (N2O) emissions calculated from discrete chamber-based flux measurements have unknown uncertainty. We used outputs from simulations obtained with an agroecosystem model to design sampling strategies that yield accurate cumulative N2O flux estimates with a known uncertainty level. Daily soil N2O fluxes were simulated for Ames, IA (corn-soybean rotation), College Station, TX (corn-vetch rotation), Fort Collins, CO (irrigated corn), and Pullman, WA (winter wheat), representing diverse agro-ecoregions of the United States. Fertilization source, rate, and timing were site-specific. These simulated fluxes surrogated daily measurements in the analysis. We ;sampled; the fluxes using a fixed interval (1-32 days) or a rule-based (decision tree-based) sampling method. Two types of decision trees were built: a high-input tree (HI) that included soil inorganic nitrogen (SIN) as a predictor variable, and a low-input tree (LI) that excluded SIN. Other predictor variables were identified with Random Forest. The decision trees were inverted to be used as rules for sampling a representative number of members from each terminal node. The uncertainty of the annual N2O flux estimation increased along with the fixed interval length. A 4- and 8-day fixed sampling interval was required at College Station and Ames, respectively, to yield ±20% accuracy in the flux estimate; a 12-day interval rendered the same accuracy at Fort Collins and Pullman. Both the HI and the LI rule-based methods provided the same accuracy as that of fixed interval method with up to a 60% reduction in sampling events, particularly at locations with greater temporal flux variability. For instance, at Ames, the HI rule-based and the fixed interval methods required 16 and 91 sampling events, respectively, to achieve the same absolute bias of 0.2 kg N ha-1 yr-1 in estimating cumulative N2O flux. These results suggest that using simulation models along with decision trees can reduce the cost and improve the accuracy of the estimations of cumulative N2O fluxes using the discrete chamber-based method.

  5. Water flux characterization through hydraulic head and temperature data assimilation: Numerical modeling and sandbox experiments

    NASA Astrophysics Data System (ADS)

    Ju, Lei; Zhang, Jiangjiang; Chen, Cheng; Wu, Laosheng; Zeng, Lingzao

    2018-03-01

    Spatial distribution of groundwater recharge/discharge fluxes has an important impact on mass and energy exchanges in shallow streambeds. During the last two decades, extensive studies have been devoted to the quantification of one-dimensional (1-D) vertical exchange fluxes. Nevertheless, few studies were conducted to characterize two-dimensional (2-D) heterogeneous flux fields that commonly exist in real-world cases. In this study, we used an iterative ensemble smoother (IES) to quantify the spatial distribution of 2-D exchange fluxes by assimilating hydraulic head and temperature measurements. Four assimilation scenarios corresponding to different potential field applications were tested. In the first three scenarios, the heterogeneous hydraulic conductivity fields were first inferred from hydraulic head and/or temperature measurements, and then the flux fields were derived through Darcy's law using the estimated conductivity fields. In the fourth scenario, the flux fields were estimated directly from the temperature measurements, which is more efficient and especially suitable for the situation that a complete knowledge of flow boundary conditions is unavailable. We concluded that, the best estimation could be achieved through jointly assimilating hydraulic head and temperature measurements, and temperature data were superior to the head data when they were used independently. Overall, the IES method provided more robust and accurate vertical flux estimations than those given by the widely used analytical solution-based methods. Furthermore, IES gave reasonable uncertainty estimations, which were unavailable in traditional methods. Since temperature can be accurately monitored with high spatial and temporal resolutions, the coupling of heat tracing techniques and IES provides promising potential in quantifying complex exchange fluxes under field conditions.

  6. Using "snapshot" measurements of CH4 fluxes from peatlands to estimate annual budgets: interpolation vs. modelling.

    NASA Astrophysics Data System (ADS)

    Green, Sophie M.; Baird, Andy J.

    2016-04-01

    There is growing interest in estimating annual budgets of peatland-atmosphere carbon dioxide (CO2) and methane (CH4) exchanges. Such budgeting is required for calculating peatland carbon balance and the radiative forcing impact of peatlands on climate. There have been multiple approaches used to estimate CO2 budgets; however, there is a limited literature regarding the modelling of annual CH4 budgets. Using data collected from flux chamber tests in an area of blanket peatland in North Wales, we compared annual estimates of peatland-atmosphere CH4 emissions using an interpolation approach and an additive and multiplicative modelling approach. Flux-chamber measurements represent a snapshot of the conditions on a particular site. In contrast to CO2, most studies that have estimated the time-integrated flux of CH4 have not used models. Typically, linear interpolation is used to estimate CH4 fluxes during the time periods between flux-chamber measurements. It is unclear how much error is involved with such a simple integration method. CH4 fluxes generally show a rise followed by a fall through the growing season that may be captured reasonably well by interpolation, provided there are sufficiently frequent measurements. However, day-to-day and week-to-week variability is also often evident in CH4 flux data, and will not necessarily be properly represented by interpolation. Our fits of the CH4 flux models yielded r2 > 0.5 in 38 of the 48 models constructed, with 55% of these having a weighted rw2 > 0.4. Comparison of annualised CH4 fluxes estimated by interpolation and modelling reveals no correlation between the two data sets; indeed, in some cases even the sign of the flux differs. The difference between the methods seems also to be related to the size of the flux - for modest annual fluxes there is a fairly even scatter of points around the 1:1 line, whereas when the modelled fluxes are high, the corresponding interpolated fluxes tend to be low. We consider the implications of these results for the calculation of the radiative forcing effect of peatlands.

  7. The forgotten component of sub-glacial heat flow: Upper crustal heat production and resultant total heat flux on the Antarctic Peninsula

    NASA Astrophysics Data System (ADS)

    Burton-Johnson, Alex; Halpin, Jacqueline; Whittaker, Joanne; Watson, Sally

    2017-04-01

    Seismic and magnetic geophysical methods have both been employed to produce estimates of heat flux beneath the Antarctic ice sheet. However, both methods use a homogeneous upper crustal model despite the variable concentration of heat producing elements within its composite lithologies. Using geological and geochemical datasets from the Antarctic Peninsula we have developed a new methodology for incorporating upper crustal heat production in heat flux models and have shown the greater variability this introduces in to estimates of crustal heat flux, with implications for glaciological modelling.

  8. Imposing strong constraints on tropical terrestrial CO2 fluxes using passenger aircraft based measurements

    NASA Astrophysics Data System (ADS)

    Niwa, Y.; Machida, T.; Sawa, Y.; Matsueda, H.; Schuck, T. J.; Brenninkmeijer, C. A.; Imasu, R.; Satoh, M.

    2011-12-01

    Better understanding of the global and regional carbon budget is needed to perform a reliable prediction of future climate with an earth system model. However, the reliability of CO2 source/sink estimation by inverse modeling, which is one of the promising methods to estimate regional carbon budget, is limited because of sparse observational data coverage. Very few observational data are available in tropics. Therefore, especially the reconstruction of tropical terrestrial fluxes has considerable uncertainties. In this study, regional CO2 fluxes for 2006-2008 are estimated by inverse modeling using the Comprehensive Observation Network for Trace gases by Airliner (CONTRAIL) in addition to the surface measurement dataset of GLOBALVIEW-CO2. CONTRAIL is a recently established CO2 measurement network using in-situ measurement instruments on board commercial aircraft. Five CONTRAIL aircraft travel back and forth between Japan and many areas: Europe, North America, Southeast Asia, South Asia, and Australia. The Bayesian synthesis approach is used to estimate monthly fluxes for 42 regions using NICAM-TM simulations with existing CO2 flux datasets and monthly mean observational data. It is demonstrated that the aircraft data have great impact on estimated tropical terrestrial fluxes. By adding the aircraft data to the surface data, the analyzed uncertainty of tropical fluxes has been reduced by 15 % and more than 30 % uncertainty reduction rate is found in Southeast and South Asia. Specifically, for annual net CO2 fluxes, nearly neutral fluxes of Indonesia, which is estimated using the surface dataset alone, turn to positive fluxes, i.e. carbon sources. In Indonesia, a remarkable carbon release during the severe drought period of October-December in 2006 is estimated, which suggests that biosphere respiration or biomass burning was larger than the prior fluxes. Comparison of the optimized atmospheric CO2 with independent aircraft measurements of CARIBIC tends to validate results of the inversion system. It is expected that the use of instantaneous observational data with more sophisticated inversion methods will provide more accurate estimation of surface CO2 fluxes.

  9. Estimation of suspended sediment flux in streams using continuous turbidity and flow data coupled with laboratory concentrations

    Treesearch

    Jack Lewis

    2002-01-01

    The widening use of sediment surrogate measurements such as turbidity necessitates consideration of new methods for estimating sediment flux. Generally, existing methods can be simply be used in new ways. The effectiveness of a method varies according to the quality of the surrogate data and its relation to suspended sediment concentration (SSC). For this discussion,...

  10. Estimation of nocturnal CO2 and N2O soil emissions from changes in surface boundary layer mass storage

    NASA Astrophysics Data System (ADS)

    Grant, Richard H.; Omonode, Rex A.

    2018-04-01

    Annual budgets of greenhouse and other trace gases require knowledge of the emissions throughout the year. Unfortunately, emissions into the surface boundary layer during stable, calm nocturnal periods are not measurable using most micrometeorological methods due to non-stationarity and uncoupled flow. However, during nocturnal periods with very light winds, carbon dioxide (CO2) and nitrous oxide (N2O) frequently accumulate near the surface and this mass accumulation can be used to determine emissions. Gas concentrations were measured at four heights (one within and three above canopy) and turbulence was measured at three heights above a mature 2.5 m maize canopy from 23 July to 10 September 2015. Nocturnal CO2 and N2O fluxes from the canopy were determined using the accumulation of mass within a 6.3 m control volume and out the top of the control volume within the nocturnal surface boundary layer. Diffusive fluxes were estimated by flux gradient method. The total accumulative and diffusive fluxes during near-calm nights (friction velocities < 0.05 ms-1) averaged 1.16 µmol m-2 s-1 CO2 and 0.53 nmol m-2 s-1 N2O. Fluxes were also measured using chambers. Daily mean CO2 fluxes determined by the accumulation method were 90 to 130 % of those determined using soil chambers. Daily mean N2O fluxes determined by the accumulation method were 60 to 80 % of that determined using soil chambers. The better signal-to-noise ratios of the chamber method for CO2 over N2O, non-stationary flow, assumed Schmidt numbers, and anemometer tilt were likely contributing reasons for the differences in chambers versus accumulated nocturnal mass flux estimates. Near-surface N2O accumulative flux measurements in more homogeneous regions and with greater depth are needed to confirm the conclusion that mass accumulation can be effectively used to estimate soil emissions during nearly calm nights.

  11. A new method for estimating the turbulent heat flux at the bottom of the daily mixed layer

    NASA Technical Reports Server (NTRS)

    Imawaki, Shiro; Niiler, Pearn P.; Gautier, Catherine H.; Knox, Robert A.; Halpern, David

    1988-01-01

    Temperature data in the mixed layer and net solar irradiance data at the sea surface are used to estimate the vertical turbulent heat flux at the bottom of the daily mixed layer. The method is applied to data obtained in the eastern tropical Pacific, where the daily cycle in the temperature field is confined to the upper 10-25 m. Equatorial turbulence measurements indicate that the turbulent heat flux is much greater during nighttime than daytime.

  12. A combined ANN-GA and experimental based technique for the estimation of the unknown heat flux for a conjugate heat transfer problem

    NASA Astrophysics Data System (ADS)

    M K, Harsha Kumar; P S, Vishweshwara; N, Gnanasekaran; C, Balaji

    2018-05-01

    The major objectives in the design of thermal systems are obtaining the information about thermophysical, transport and boundary properties. The main purpose of this paper is to estimate the unknown heat flux at the surface of a solid body. A constant area mild steel fin is considered and the base is subjected to constant heat flux. During heating, natural convection heat transfer occurs from the fin to ambient. The direct solution, which is the forward problem, is developed as a conjugate heat transfer problem from the fin and the steady state temperature distribution is recorded for any assumed heat flux. In order to model the natural convection heat transfer from the fin, an extended domain is created near the fin geometry and air is specified as a fluid medium and Navier Stokes equation is solved by incorporating the Boussinesq approximation. The computational time involved in executing the forward model is then reduced by developing a neural network (NN) between heat flux values and temperatures based on back propagation algorithm. The conjugate heat transfer NN model is now coupled with Genetic algorithm (GA) for the solution of the inverse problem. Initially, GA is applied to the pure surrogate data, the results are then used as input to the Levenberg- Marquardt method and such hybridization is proven to result in accurate estimation of the unknown heat flux. The hybrid method is then applied for the experimental temperature to estimate the unknown heat flux. A satisfactory agreement between the estimated and actual heat flux is achieved by incorporating the hybrid method.

  13. Prognostics Health Management Model for LED Package Failure Under Contaminated Environment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lall, Pradeep; Zhang, Hao; Davis, J Lynn

    2015-06-06

    The reliability consideration of LED products includes both luminous flux drop and color shift. Previous research either talks about luminous maintenance or color shift, because luminous flux degradation usually takes very long time to observe. In this paper, the impact of a VOC (volatile organic compound) contaminated luminous flux and color stability are examined. As a result, both luminous degradation and color shift had been recorded in a short time. Test samples are white, phosphor-converted, high-power LED packages. Absolute radiant flux is measured with integrating sphere system to calculate the luminous flux. Luminous flux degradation and color shift distance weremore » plotted versus aging time to show the degradation pattern. A prognostic health management (PHM) method based on the state variables and state estimator have been proposed in this paper. In this PHM framework, unscented kalman filter (UKF) was deployed as the carrier of all states. During the estimation process, third order dynamic transfer function was used to implement the PHM framework. Both of the luminous flux and color shift distance have been used as the state variable with the same PHM framework to exam the robustness of the method. Predicted remaining useful life is calculated at every measurement point to compare with the tested remaining useful life. The result shows that state estimator can be used as the method for the PHM of LED degradation with respect to both luminous flux and color shift distance. The prediction of remaining useful life of LED package, made by the states estimator and data driven approach, falls in the acceptable error-bounds (20%) after a short training of the estimator.« less

  14. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lall, Pradeep; Zang, Hao; Davis, J Lynn

    The reliability of LED products may be affected by both luminous flux drop and color shift. Previous research on the topic focuses on either luminous maintenance or color shift. However, luminous flux degradation usually takes very long time to observe in LEDs under normal operating conditions. In this paper, the impact of a VOC (volatile organic compound) contaminated luminous flux and color stability are examined. As a result, both luminous degradation and color shift had been recorded in a short time. Test samples are white, phosphorconverted, high-power LED packages. Absolute radiant flux is measured with integrating sphere system to calculatemore » the luminous flux. Luminous flux degradation and color shift distance were plotted versus aging time to show the degradation pattern. A prognostic health management (PHM) method based on the state variables and state estimator have been proposed in this paper. In this PHM framework, unscented kalman filter (UKF) was deployed as the carrier of all states. During the estimation process, third order dynamic transfer function was used to implement the PHM framework. Both of the luminous flux and color shift distance have been used as the state variable with the same PHM framework to exam the robustness of the method. Predicted remaining useful life is calculated at every measurement point to compare with the tested remaining useful life. The result shows that state estimator can be used as the method for the PHM of LED degradation with respect to both luminous flux and color shift distance. The prediction of remaining useful life of LED package, made by the states estimator and data driven approach, falls in the acceptable errorbounds (20%) after a short training of the estimator.« less

  15. Uncertainty in eddy covariance flux estimates resulting from spectral attenuation [Chapter 4

    Treesearch

    W. J. Massman; R. Clement

    2004-01-01

    Surface exchange fluxes measured by eddy covariance tend to be underestimated as a result of limitations in sensor design, signal processing methods, and finite flux-averaging periods. But, careful system design, modern instrumentation, and appropriate data processing algorithms can minimize these losses, which, if not too large, can be estimated and corrected using...

  16. Estimating soil water evaporation using radar measurements

    NASA Technical Reports Server (NTRS)

    Sadeghi, Ali M.; Scott, H. D.; Waite, W. P.; Asrar, G.

    1988-01-01

    Field studies were conducted to evaluate the application of radar reflectivity as compared with the shortwave reflectivity (albedo) used in the Idso-Jackson equation for the estimation of daily evaporation under overcast sky and subhumid climatic conditions. Soil water content, water potential, shortwave and radar reflectivity, and soil and air temperatures were monitored during three soil drying cycles. The data from each cycle were used to calculate daily evaporation from the Idso-Jackson equation and from two other standard methods, the modified Penman and plane of zero-flux. All three methods resulted in similar estimates of evaporation under clear sky conditions; however, under overcast sky conditions, evaporation fluxes computed from the Idso-Jackson equation were consistently lower than the other two methods. The shortwave albedo values in the Idso-Jackson equation were then replaced with radar reflectivities and a new set of total daily evaporation fluxes were calculated. This resulted in a significant improvement in computed soil evaporation fluxes from the Idso-Jackson equation, and a better agreement between the three methods under overcast sky conditions.

  17. Spatial Interpretation of Tower, Chamber and Modelled Terrestrial Fluxes in a Tropical Forest Plantation

    NASA Astrophysics Data System (ADS)

    Whidden, E.; Roulet, N.

    2003-04-01

    Interpretation of a site average terrestrial flux may be complicated in the presence of inhomogeneities. Inhomogeneity may invalidate the basic assumptions of aerodynamic flux measurement. Chamber measurement may miss or misinterpret important temporal or spatial anomalies. Models may smooth over important nonlinearities depending on the scale of application. Although inhomogeneity is usually seen as a design problem, many sites have spatial variance that may have a large impact on net flux, and in many cases a large homogeneous surface is unrealistic. The sensitivity and validity of a site average flux are investigated in the presence of an inhomogeneous site. Directional differences are used to evaluate the validity of aerodynamic methods and the computation of a site average tower flux. Empirical and modelling methods are used to interpret the spatial controls on flux. An ecosystem model, Ecosys, is used to assess spatial length scales appropriate to the ecophysiologic controls. A diffusion model is used to compare tower, chamber, and model data, by spatially weighting contributions within the tower footprint. Diffusion model weighting is also used to improve tower flux estimates by producing footprint averaged ecological parameters (soil moisture, soil temperature, etc.). Although uncertainty remains in the validity of measurement methods and the accuracy of diffusion models, a detailed spatial interpretation is required at an inhomogeneous site. Flux estimation between methods improves with spatial interpretation, showing the importance to an estimation of a site average flux. Small-scale temporal and spatial anomalies may be relatively unimportant to overall flux, but accounting for medium-scale differences in ecophysiological controls is necessary. A combination of measurements and modelling can be used to define the appropriate time and length scales of significant non-linearity due to inhomogeneity.

  18. A simple algorithm to estimate the effective regional atmospheric parameters for thermal-inertia mapping

    USGS Publications Warehouse

    Watson, K.; Hummer-Miller, S.

    1981-01-01

    A method based solely on remote sensing data has been developed to estimate those meteorological effects which are required for thermal-inertia mapping. It assumes that the atmospheric fluxes are spatially invariant and that the solar, sky, and sensible heat fluxes can be approximated by a simple mathematical form. Coefficients are determined from least-squares method by fitting observational data to our thermal model. A comparison between field measurements and the model-derived flux shows the type of agreement which can be achieved. An analysis of the limitations of the method is also provided. ?? 1981.

  19. Influence of aerosols on surface reaching spectral irradiance and introduction to a new technique of estimating aerosol radiative forcing from high resolution spectral flux measurements

    NASA Astrophysics Data System (ADS)

    Rao, Roshan

    2016-04-01

    Aerosol radiative forcing estimates with high certainty are required in climate change studies. The approach in estimating the aerosol radiative forcing by using the chemical composition of aerosols is not effective as the chemical composition data with radiative properties are not widely available. We look into the approach where ground based spectral radiation flux measurement is made and along with an Radtiative transfer (RT) model, radiative forcing is estimated. Measurements of spectral flux were made using an ASD spectroradiometer with 350 - 1050 nm wavelength range and a 3nm resolution during around 54 clear-sky days during which AOD range was around 0.01 to 0.7. Simultaneous measurements of black carbon were also made using Aethalometer (Magee Scientific) which ranged from around 1.5 ug/m3 to 8 ug/m3. The primary study involved in understanding the sensitivity of spectral flux due to change in individual aerosol species (Optical properties of Aerosols and Clouds (OPAC) classified aerosol species) using the SBDART RT model. This made us clearly distinguish the influence of different aerosol species on the spectral flux. Following this, a new technique has been introduced to estimate an optically equivalent mixture of aerosol species for the given location. The new method involves matching different combinations of aerosol species in OPAC model and RT model as long as the combination which gives the minimum root mean squared deviation from measured spectral flux is obtained. Using the optically equivalent aerosol mixture and RT model, aerosol radiative forcing is estimated. Also an alternate method to estimate the spectral SSA is discussed. Here, the RT model, the observed spectral flux and spectral AOD is used. Spectral AOD is input to RT model and SSA is varied till the minimum root mean squared difference between observed and simulated spectral flux from RT model is obtained. The methods discussed are limited to clear sky scenes and its accuracy to derive an optically equivalent aerosol mixture reduces when diffuse component of flux increases. In our analysis, RT model clearly shows that direct component of spectral flux is more sensitive to different aerosol species than total spectral flux which is also supported by our observed data.

  20. Evaluation of unsaturated zone water fluxes in heterogeneous alluvium at a Mojave Basin Site

    USGS Publications Warehouse

    Nimmo, John R.; Deason, Jeffrey A.; Izbicki, John A.; Martin, Peter

    2002-01-01

    Vertical and horizontal water fluxes in the unsaturated zone near intermittent streams critically affect ecosystems, water supply, and contaminant transport in arid and semiarid regions. The subsurface near the Oro Grande Wash is typical in having great textural diversity, pronounced layer contrasts, and extremely low hydraulic conductivities associated with nearly dry media. These features prevent a straightforward application of the Darcian method for recharge estimation, which has provided high‐quality flux estimates at simpler, wetter sites. We have augmented the basic Darcian method with theoretical developments such that a small number of core sample unsaturated hydraulic property measurements, combined with additional, easily obtained data (e.g., drillers' logs) can provide useful flux estimates and knowledge of two‐dimensional water behavior beneath the wash.

  1. Measurement and simulation of thermal neutron flux distribution in the RTP core

    NASA Astrophysics Data System (ADS)

    Rabir, Mohamad Hairie B.; Jalal Bayar, Abi Muttaqin B.; Hamzah, Na'im Syauqi B.; Mustafa, Muhammad Khairul Ariff B.; Karim, Julia Bt. Abdul; Zin, Muhammad Rawi B. Mohamed; Ismail, Yahya B.; Hussain, Mohd Huzair B.; Mat Husin, Mat Zin B.; Dan, Roslan B. Md; Ismail, Ahmad Razali B.; Husain, Nurfazila Bt.; Jalil Khan, Zareen Khan B. Abdul; Yakin, Shaiful Rizaide B. Mohd; Saad, Mohamad Fauzi B.; Masood, Zarina Bt.

    2018-01-01

    The in-core thermal neutron flux distribution was determined using measurement and simulation methods for the Malaysian’s PUSPATI TRIGA Reactor (RTP). In this work, online thermal neutron flux measurement using Self Powered Neutron Detector (SPND) has been performed to verify and validate the computational methods for neutron flux calculation in RTP calculations. The experimental results were used as a validation to the calculations performed with Monte Carlo code MCNP. The detail in-core neutron flux distributions were estimated using MCNP mesh tally method. The neutron flux mapping obtained revealed the heterogeneous configuration of the core. Based on the measurement and simulation, the thermal flux profile peaked at the centre of the core and gradually decreased towards the outer side of the core. The results show a good agreement (relatively) between calculation and measurement where both show the same radial thermal flux profile inside the core: MCNP model over estimation with maximum discrepancy around 20% higher compared to SPND measurement. As our model also predicts well the neutron flux distribution in the core it can be used for the characterization of the full core, that is neutron flux and spectra calculation, dose rate calculations, reaction rate calculations, etc.

  2. Spectral estimates of net radiation and soil heat flux

    USGS Publications Warehouse

    Daughtry, C.S.T.; Kustas, William P.; Moran, M.S.; Pinter, P. J.; Jackson, R. D.; Brown, P.W.; Nichols, W.D.; Gay, L.W.

    1990-01-01

    Conventional methods of measuring surface energy balance are point measurements and represent only a small area. Remote sensing offers a potential means of measuring outgoing fluxes over large areas at the spatial resolution of the sensor. The objective of this study was to estimate net radiation (Rn) and soil heat flux (G) using remotely sensed multispectral data acquired from an aircraft over large agricultural fields. Ground-based instruments measured Rn and G at nine locations along the flight lines. Incoming fluxes were also measured by ground-based instruments. Outgoing fluxes were estimated using remotely sensed data. Remote Rn, estimated as the algebraic sum of incoming and outgoing fluxes, slightly underestimated Rn measured by the ground-based net radiometers. The mean absolute errors for remote Rn minus measured Rn were less than 7%. Remote G, estimated as a function of a spectral vegetation index and remote Rn, slightly overestimated measured G; however, the mean absolute error for remote G was 13%. Some of the differences between measured and remote values of Rn and G are associated with differences in instrument designs and measurement techniques. The root mean square error for available energy (Rn - G) was 12%. Thus, methods using both ground-based and remotely sensed data can provide reliable estimates of the available energy which can be partitioned into sensible and latent heat under nonadvective conditions. ?? 1990.

  3. A modified micrometeorological gradient method for estimating O3 dry depositions over a forest canopy

    NASA Astrophysics Data System (ADS)

    Wu, Z. Y.; Zhang, L.; Wang, X. M.; Munger, J. W.

    2015-07-01

    Small pollutant concentration gradients between levels above a plant canopy result in large uncertainties in estimated air-surface exchange fluxes when using existing micrometeorological gradient methods, including the aerodynamic gradient method (AGM) and the modified Bowen ratio method (MBR). A modified micrometeorological gradient method (MGM) is proposed in this study for estimating O3 dry deposition fluxes over a forest canopy using concentration gradients between a level above and a level below the canopy top, taking advantage of relatively large gradients between these levels due to significant pollutant uptake in the top layers of the canopy. The new method is compared with the AGM and MBR methods and is also evaluated using eddy-covariance (EC) flux measurements collected at the Harvard Forest Environmental Measurement Site, Massachusetts, during 1993-2000. All three gradient methods (AGM, MBR, and MGM) produced similar diurnal cycles of O3 dry deposition velocity (Vd(O3)) to the EC measurements, with the MGM method being the closest in magnitude to the EC measurements. The multi-year average Vd(O3) differed significantly between these methods, with the AGM, MBR, and MGM method being 2.28, 1.45, and 1.18 times that of the EC, respectively. Sensitivity experiments identified several input parameters for the MGM method as first-order parameters that affect the estimated Vd(O3). A 10% uncertainty in the wind speed attenuation coefficient or canopy displacement height can cause about 10% uncertainty in the estimated Vd(O3). An unrealistic leaf area density vertical profile can cause an uncertainty of a factor of 2.0 in the estimated Vd(O3). Other input parameters or formulas for stability functions only caused an uncertainly of a few percent. The new method provides an alternative approach to monitoring/estimating long-term deposition fluxes of similar pollutants over tall canopies.

  4. From Air Temperature to Lake Evaporation on a Daily Time Step: A New Empirical Approach

    NASA Astrophysics Data System (ADS)

    Welch, C.; Holmes, T. L.; Stadnyk, T. A.

    2016-12-01

    Lake evaporation is a key component of the water balance in much of Canada due to the vast surface area covered by open water. Hence, incorporating this flux effectively into hydrological simulation frameworks is essential to effective water management. Inclusion has historically been limited by the intensive data required to apply the energy budget methods previously demonstrated to most effectively capture the timing and volume of the evaporative flux. Widespread, consistent, lake water temperature and net radiation data are not available across much of Canada, particularly the sparsely populated boreal shield. We present a method to estimate lake evaporation on a daily time step that consists of a series of empirical equations applicable to lakes of widely varying morphologies. Specifically, estimation methods that require the single meteorological variable of air temperature are presented for lake water temperature, net radiation, and heat flux. The methods were developed using measured data collected at two small Boreal shield lakes, Lake Winnipeg North and South basins, and Lake Superior in 2008 and 2009. The mean average error (MAE) of the lake water temperature estimates is generally 1.5°C, and the MAE of the heat flux method is 50 W m-2. The simulated values are combined to estimate daily lake evaporation using the Priestley-Taylor method. Heat storage within the lake is tracked and limits the potential heat flux from a lake. Five-day running averages compare well to measured evaporation at the two small shield lakes (Bowen Ratio Energy Balance) and adequately to Lake Superior (eddy covariance). In addition to air temperature, the method requires a mean depth for each lake. The method demonstrably improves the timing and volume of evaporative flux in comparison to existing evaporation methods that depend only on temperature. The method will be further tested in a semi-distributed hydrological model to assess the cumulative effects across a lake-dominated catchment in the Lower Nelson River basin.

  5. Multi-Satellite Estimates of Land-Surface Properties for Determination of Energy and Water Budgets

    NASA Technical Reports Server (NTRS)

    Menzel, W. Paul; Rabin, Robert M.; Neale, Christopher M. U.; Gallo, Kevin; Diak, George R.

    1998-01-01

    Using the WETNET database, existing methods for the estimation of surface wetness from SSM/I data have been assessed and further developed. A physical-statistical method for optimal estimation of daily surface heat flux and Bowen ratio on the mesoscale has been developed and tested. This method is based on observations of daytime planetary boundary layer (PBL) growth from operational ravansonde and daytime land-surface temperature amplitude from Geostationary Operational Environmental (GOES) satellites. The mesoscale patterns of these heat fluxes have been compared with an AVHRR-based vegetation index and surface wetness (separately estimated from SSM/I and in situ observations). Cases of the 1988 Midwest drought and a surface/atmosphere moisture gradient (dry-line) in the southern Plains were studied. The analyses revealed significant variations in sensible heat flux (S(sub 0), and Bowen ratio, B(sub 0)) associated with vegetation cover and antecedent precipitation. Relationships for surface heat flux (and Bowen ratio) from antecedent precipitation and vegetation index have been developed and compared to other findings. Results from this project are reported in the following reviewed literature.

  6. Data-based estimates of the ocean carbon sink variability - results of the Surface Ocean pCO2 Mapping intercomparison (SOCOM)

    NASA Astrophysics Data System (ADS)

    Rödenbeck, Christian; Bakker, Dorothee; Gruber, Nicolas; Iida, Yosuke; Jacobson, Andy; Jones, Steve; Landschützer, Peter; Metzl, Nicolas; Nakaoka, Shin-ichiro; Olsen, Are; Park, Geun-Ha; Peylin, Philippe; Rodgers, Keith; Sasse, Tristan; Schuster, Ute; Shutler, James; Valsala, Vinu; Wanninkhof, Rik; Zeng, Jiye

    2016-04-01

    Using measurements of the surface-ocean COtwo partial pressure (pCOtwo) from the SOCAT and LDEO data bases and 14 different pCOtwo mapping methods recently collated by the Surface Ocean pCOtwo Mapping intercomparison (SOCOM) initiative, variations in regional and global sea-air COtwo fluxes are investigated. Though the available mapping methods use widely different approaches, we find relatively consistent estimates of regional pCOtwo seasonality, in line with previous estimates. In terms of interannual variability (IAV), all mapping methods estimate the largest variations to occur in the Eastern equatorial Pacific. Despite considerable spread in the detailed variations, mapping methods that fit the data more closely also tend to agree more closely with each other in regional averages. Encouragingly, this includes mapping methods belonging to complementary types - taking variability either directly from the pCOtwo data or indirectly from driver data via regression. From a weighted ensemble average, we find an IAV amplitude of the global sea-air COtwo flux of IAVampl (standard deviation over AnalysisPeriod), which is larger than simulated by biogeochemical process models. On a decadal perspective, the global ocean COtwo uptake is estimated to have gradually increased since about 2000, with little decadal change prior to that. The weighted mean net global ocean COtwo sink estimated by the SOCOM ensemble is -1.75 UPgCyr (AnalysisPeriod), consistent within uncertainties with estimates from ocean-interior carbon data or atmospheric oxygen trends. Using data-based sea-air COtwo fluxes in atmospheric COtwo inversions also helps to better constrain land-atmosphere COtwo fluxes.

  7. Tree age, disturbance history, and carbon stocks and fluxes in subalpine Rocky Mountain forests

    Treesearch

    J.B. Bradford; R.A. Birdsey; L.A. Joyce; M.G. Ryan

    2008-01-01

    Forest carbon stocks and fluxes vary with forest age, and relationships with forest age are often used to estimate fluxes for regional or national carbon inventories. Two methods are commonly used to estimate forest age: observed tree age or time since a known disturbance. To clarify the relationships between tree age, time since disturbance and forest carbon storage...

  8. Combined point and distributed techniques for multidimensional estimation of spatial groundwater-stream water exchange in a heterogeneous sand bed-stream.

    NASA Astrophysics Data System (ADS)

    Gaona Garcia, J.; Lewandowski, J.; Bellin, A.

    2017-12-01

    Groundwater-stream water interactions in rivers determine water balances, but also chemical and biological processes in the streambed at different spatial and temporal scales. Due to the difficult identification and quantification of gaining, neutral and losing conditions, it is necessary to combine techniques with complementary capabilities and scale ranges. We applied this concept to a study site at the River Schlaube, East Brandenburg-Germany, a sand bed stream with intense sediment heterogeneity and complex environmental conditions. In our approach, point techniques such as temperature profiles of the streambed together with vertical hydraulic gradients provide data for the estimation of fluxes between groundwater and surface water with the numerical model 1DTempPro. On behalf of distributed techniques, fiber optic distributed temperature sensing identifies the spatial patterns of neutral, down- and up-welling areas by analysis of the changes in the thermal patterns at the streambed interface under certain flow. The study finally links point and surface temperatures to provide a method for upscaling of fluxes. Point techniques provide point flux estimates with essential depth detail to infer streambed structures while the results hardly represent the spatial distribution of fluxes caused by the heterogeneity of streambed properties. Fiber optics proved capable of providing spatial thermal patterns with enough resolution to observe distinct hyporheic thermal footprints at multiple scales. The relation of thermal footprint patterns and temporal behavior with flux results from point techniques enabled the use of methods for spatial flux estimates. The lack of detailed information of the physical driver's spatial distribution restricts the spatial flux estimation to the application of the T-proxy method, whose highly uncertain results mainly provide coarse spatial flux estimates. The study concludes that the upscaling of groundwater-stream water interactions using thermal measurements with combined point and distributed techniques requires the integration of physical drivers because of the heterogeneity of the flux patterns. Combined experimental and modeling approaches may help to obtain more reliable understanding of groundwater-surface water interactions at multiple scales.

  9. Constituent loads in small streams: the process and problems of estimating sediment flux

    Treesearch

    R. B. Thomas

    1989-01-01

    Constituent loads in small streams are often estimated poorly. This is especially true for discharge-related constituents like sediment, since their flux is highly variable and mainly occurs during infrequent high-flow events. One reason for low-quality estimates is that most prevailing data collection methods ignore sampling probabilities and only partly account for...

  10. Applying linear programming to estimate fluxes in ecosystems or food webs: An example from the herpetological assemblage of the freshwater Everglades

    USGS Publications Warehouse

    Diffendorfer, James E.; Richards, Paul M.; Dalrymple, George H.; DeAngelis, Donald L.

    2001-01-01

    We present the application of Linear Programming for estimating biomass fluxes in ecosystem and food web models. We use the herpetological assemblage of the Everglades as an example. We developed food web structures for three common Everglades freshwater habitat types: marsh, prairie, and upland. We obtained a first estimate of the fluxes using field data, literature estimates, and professional judgment. Linear programming was used to obtain a consistent and better estimate of the set of fluxes, while maintaining mass balance and minimizing deviations from point estimates. The results support the view that the Everglades is a spatially heterogeneous system, with changing patterns of energy flux, species composition, and biomasses across the habitat types. We show that a food web/ecosystem perspective, combined with Linear Programming, is a robust method for describing food webs and ecosystems that requires minimal data, produces useful post-solution analyses, and generates hypotheses regarding the structure of energy flow in the system.

  11. Non-stationary (13)C-metabolic flux ratio analysis.

    PubMed

    Hörl, Manuel; Schnidder, Julian; Sauer, Uwe; Zamboni, Nicola

    2013-12-01

    (13)C-metabolic flux analysis ((13)C-MFA) has become a key method for metabolic engineering and systems biology. In the most common methodology, fluxes are calculated by global isotopomer balancing and iterative fitting to stationary (13)C-labeling data. This approach requires a closed carbon balance, long-lasting metabolic steady state, and the detection of (13)C-patterns in a large number of metabolites. These restrictions mostly reduced the application of (13)C-MFA to the central carbon metabolism of well-studied model organisms grown in minimal media with a single carbon source. Here we introduce non-stationary (13)C-metabolic flux ratio analysis as a novel method for (13)C-MFA to allow estimating local, relative fluxes from ultra-short (13)C-labeling experiments and without the need for global isotopomer balancing. The approach relies on the acquisition of non-stationary (13)C-labeling data exclusively for metabolites in the proximity of a node of converging fluxes and a local parameter estimation with a system of ordinary differential equations. We developed a generalized workflow that takes into account reaction types and the availability of mass spectrometric data on molecular ions or fragments for data processing, modeling, parameter and error estimation. We demonstrated the approach by analyzing three key nodes of converging fluxes in central metabolism of Bacillus subtilis. We obtained flux estimates that are in agreement with published results obtained from steady state experiments, but reduced the duration of the necessary (13)C-labeling experiment to less than a minute. These results show that our strategy enables to formally estimate relative pathway fluxes on extremely short time scale, neglecting cellular carbon balancing. Hence this approach paves the road to targeted (13)C-MFA in dynamic systems with multiple carbon sources and towards rich media. © 2013 Wiley Periodicals, Inc.

  12. A quantitative method for estimating dermal benzene absorption from benzene-containing hydrocarbon liquids.

    PubMed

    Petty, Stephen E; Nicas, Mark; Boiarski, Anthony A

    2011-01-01

    This study examines a method for estimating the dermal absorption of benzene contained in hydrocarbon liquids that contact the skin. This method applies to crude oil, gasoline, organic solvents, penetrants, and oils. The flux of benzene through occluded skin as a function of the percent vol/vol benzene in the liquid is derived by fitting a curve to experimental data; the function is supralinear at benzene concentrations < or = 5% vol/vol. When a liquid other than pure benzene is on nonoccluded skin, benzene may preferentially evaporate from the liquid, which thereby decreases the benzene flux. We present a time-averaging method here for estimating the reduced dermal flux during evaporation. Example calculations are presented for benzene at 2% vol/vol in gasoline, and for benzene at 0.1% vol/vol in a less volatile liquid. We also discuss other factors affecting dermal absorption.

  13. Methane and carbon dioxide fluxes over a lake: comparison between eddy covariance, floating chambers and boundary layer method

    NASA Astrophysics Data System (ADS)

    Erkkilä, Kukka-Maaria; Ojala, Anne; Bastviken, David; Biermann, Tobias; Heiskanen, Jouni J.; Lindroth, Anders; Peltola, Olli; Rantakari, Miitta; Vesala, Timo; Mammarella, Ivan

    2018-01-01

    Freshwaters bring a notable contribution to the global carbon budget by emitting both carbon dioxide (CO2) and methane (CH4) to the atmosphere. Global estimates of freshwater emissions traditionally use a wind-speed-based gas transfer velocity, kCC (introduced by Cole and Caraco, 1998), for calculating diffusive flux with the boundary layer method (BLM). We compared CH4 and CO2 fluxes from BLM with kCC and two other gas transfer velocities (kTE and kHE), which include the effects of water-side cooling to the gas transfer besides shear-induced turbulence, with simultaneous eddy covariance (EC) and floating chamber (FC) fluxes during a 16-day measurement campaign in September 2014 at Lake Kuivajärvi in Finland. The measurements included both lake stratification and water column mixing periods. Results show that BLM fluxes were mainly lower than EC, with the more recent model kTE giving the best fit with EC fluxes, whereas FC measurements resulted in higher fluxes than simultaneous EC measurements. We highly recommend using up-to-date gas transfer models, instead of kCC, for better flux estimates. BLM CO2 flux measurements had clear differences between daytime and night-time fluxes with all gas transfer models during both stratified and mixing periods, whereas EC measurements did not show a diurnal behaviour in CO2 flux. CH4 flux had higher values in daytime than night-time during lake mixing period according to EC measurements, with highest fluxes detected just before sunset. In addition, we found clear differences in daytime and night-time concentration difference between the air and surface water for both CH4 and CO2. This might lead to biased flux estimates, if only daytime values are used in BLM upscaling and flux measurements in general. FC measurements did not detect spatial variation in either CH4 or CO2 flux over Lake Kuivajärvi. EC measurements, on the other hand, did not show any spatial variation in CH4 fluxes but did show a clear difference between CO2 fluxes from shallower and deeper areas. We highlight that while all flux measurement methods have their pros and cons, it is important to carefully think about the chosen method and measurement interval, as well as their effects on the resulting flux.

  14. Evaluation of surface renewal and flux-variance methods above agricultural and forest surfaces

    NASA Astrophysics Data System (ADS)

    Fischer, M.; Katul, G. G.; Noormets, A.; Poznikova, G.; Domec, J. C.; Trnka, M.; King, J. S.

    2016-12-01

    Measurements of turbulent surface energy fluxes are of high interest in agriculture and forest research. During last decades, eddy covariance (EC), has been adopted as the most commonly used micrometeorological method for measuring fluxes of greenhouse gases, energy and other scalars at the surface-atmosphere interface. Despite its robustness and accuracy, the costs of EC hinder its deployment at some research experiments and in practice like e.g. for irrigation scheduling. Therefore, testing and development of other cost-effective methods is of high interest. In our study, we tested performance of surface renewal (SR) and flux variance method (FV) for estimates of sensible heat flux density. Surface renewal method is based on the concept of non-random transport of scalars via so-called coherent structures which if accurately identified can be used for the computing of associated flux. Flux variance method predicts the flux from the scalar variance following the surface-layer similarity theory. We tested SR and FV against EC in three types of ecosystem with very distinct aerodynamic properties. First site was represented by agricultural wheat field in the Czech Republic. The second site was a 20-m tall mixed deciduous wetland forest on the coast of North Carolina, USA. The third site was represented by pine-switchgrass intercropping agro-forestry system located in coastal plain of North Carolina, USA. Apart from solving the coherent structures in a SR framework from the structure functions (representing the most common approach), we applied ramp wavelet detection scheme to test the hypothesis that the duration and amplitudes of the coherent structures are normally distributed within the particular 30-minutes time intervals and so just the estimates of their averages is sufficient for the accurate flux determination. Further, we tested whether the orthonormal wavelet thresholding can be used for isolating of the coherent structure scales which are associated with flux transport. Finally, we tested whether low-pass filtering in the Fourier domain based on integral length scale can improve estimates of both SR and FV as it supposedly removes the low frequency portion of the signal not related with the investigated fluxes.

  15. Application of portable gas detector in point and scanning method to estimate spatial distribution of methane emission in landfill.

    PubMed

    Lando, Asiyanthi Tabran; Nakayama, Hirofumi; Shimaoka, Takayuki

    2017-01-01

    Methane from landfills contributes to global warming and can pose an explosion hazard. To minimize these effects emissions must be monitored. This study proposed application of portable gas detector (PGD) in point and scanning measurements to estimate spatial distribution of methane emissions in landfills. The aims of this study were to discover the advantages and disadvantages of point and scanning methods in measuring methane concentrations, discover spatial distribution of methane emissions, cognize the correlation between ambient methane concentration and methane flux, and estimate methane flux and emissions in landfills. This study was carried out in Tamangapa landfill, Makassar city-Indonesia. Measurement areas were divided into basic and expanded area. In the point method, PGD was held one meter above the landfill surface, whereas scanning method used a PGD with a data logger mounted on a wire drawn between two poles. Point method was efficient in time, only needed one person and eight minutes in measuring 400m 2 areas, whereas scanning method could capture a lot of hot spots location and needed 20min. The results from basic area showed that ambient methane concentration and flux had a significant (p<0.01) positive correlation with R 2 =0.7109 and y=0.1544 x. This correlation equation was used to describe spatial distribution of methane emissions in the expanded area by using Kriging method. The average of estimated flux from scanning method was 71.2gm -2 d -1 higher than 38.3gm -2 d -1 from point method. Further, scanning method could capture the lower and higher value, which could be useful to evaluate and estimate the possible effects of the uncontrolled emissions in landfill. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Influence of transport uncertainty on annual mean and seasonal inversions of atmospheric CO2 data

    NASA Astrophysics Data System (ADS)

    Peylin, Philippe; Baker, David; Sarmiento, Jorge; Ciais, Philippe; Bousquet, Philippe

    2002-10-01

    Inversion methods are often used to estimate surface CO2 fluxes from atmospheric CO2 concentration measurements, given an atmospheric transport model to relate the two. The published estimates disagree strongly on the location of the main sources and sinks, however. Are these differences due to the different time spans considered, or are they artifacts of the method and data used? Here we assess the uncertainty in such estimates due to the choice of time discretization of the measurements and fluxes, the spatial resolution of the fluxes, and the transport model. A suite of 27 Bayesian least squares inversions has been run, given by varying the number of flux regions solved for (7, 12, and 17), the time discretization (annual/annual, annual/monthly, and monthly/monthly for the fluxes/data), and the transport model (TM2, TM3, and GCTM), while holding all other inversion details constant. The estimated fluxes from this ensemble of inversions for the land + ocean sum are stable over large zonal bands, but the spread in the results increases when considering the longitudinal flux distribution inside these bands. On average for 1990-1994 the inversions place a large CO2 uptake north of 30°N (3.2 ± 0.3 GtC yr-1), mostly over the land regions, with more in Eurasia than North America. The ocean fluxes are generally smaller than given by [1999], especially south of 15°S and in the global total, where they are less than half as large. A small uptake is found for the tropical land regions, suggesting that growth more than compensates for deforestation there. The results for the different transport models are consistent with their known mixing properties; the longitudinal pattern of their land biosphere rectifier, in particular, strongly influences the regional partitioning of the flux in the north. While differences between the transport models contribute significantly to the spread of the results, an equivalent or even larger spread is due to the time discretization method used: Solving for annual mean fluxes with monthly mean measurements tended to give spurious land/ocean flux partition in the north. We suggest then that this time discretization method be avoided. Overall, the uncertainty quoted for the estimated fluxes should include not only the random error calculated by the inversion equations but also all the systematic errors in the problem, such as those addressed in this study.

  17. An inverse method to estimate stem surface heat flux in wildland fires

    Treesearch

    Anthony S. Bova; Matthew B. Dickinson

    2009-01-01

    Models of wildland fire-induced stem heating and tissue necrosis require accurate estimates of inward heat flux at the bark surface. Thermocouple probes or heat flux sensors placed at a stem surface do not mimic the thermal response of tree bark to flames.We show that data from thin thermocouple probes inserted just below the bark can be used, by means of a one-...

  18. Full-order observer for direct torque control of induction motor based on constant V/F control technique.

    PubMed

    Pimkumwong, Narongrit; Wang, Ming-Shyan

    2018-02-01

    This paper presents another control method for the three-phase induction motor that is direct torque control based on constant voltage per frequency control technique. This method uses the magnitude of stator flux and torque errors to generate the stator voltage and phase angle references for controlling the induction motor by using constant voltage per frequency control method. Instead of hysteresis comparators and optimum switching table, the PI controllers and space vector modulation technique are used to reduce torque and stator-flux ripples and achieve constant switching frequency. Moreover, the coordinate transformations are not required. To implement this control method, a full-order observer is used to estimate stator flux and overcome the problems from drift and saturation in using pure integrator. The feedback gains are designed by simple manner to improve the convergence of stator flux estimation, especially in low speed range. Furthermore, the necessary conditions to maintain the stability for feedback gain design are introduced. The simulation and experimental results show accurate and stable operation of the introduced estimator and good dynamic response of the proposed control method. Copyright © 2017 ISA. Published by Elsevier Ltd. All rights reserved.

  19. Retrieval of Paris CO2 and CO emissions using a boundary layer budget method in the framework of the CO2-MEGAPARIS project

    NASA Astrophysics Data System (ADS)

    Dieudonné, E.; Gibert, F.; Xueref-remy, I. C.; Lopez, M.; Schmidt, M.; Ravetta, F.

    2012-12-01

    The development of anthropogenic activities since the pre-industrial era has greatly increased CO2 concentrations in the atmosphere, very likely causing the observed rise in global temperature. Therefore, accurate estimations of CO2 emission fluxes are very important for climate predictions. At the continental scale, CO2 fluxes can be estimated rather precisely using inverse modeling while tower turbulent flux measurements (eddy-covariance or EC) can provide an estimation of local-scale fluxes. However, this method cannot be applied to monitor urban CO2 emissions due to their large horizontal variability, so that a regional scale approach seems more suited. Unfortunately, at this scale, anthropogenic and biospheric fluxes are mixed, diluted and advected in the atmospheric boundary-layer (ABL) and the balance between these processes is not well known. Yet, independent estimations of CO2 fluxes would be needed to verify existing high resolution emission inventories and assess the efficiency of future mitigation policies. Several experiments dedicated to quantifying CO2 emissions from megacities are ongoing, like the CO2-MEGAPARIS research project [a,b]. In this framework, a network of lidars and in-situ sensors has been set up in Paris region. An original ABL mass budget method is used to infer the properties of advected anthropogenic CO2 and CO emissions from Paris urban area [c]. The method is applied in the center of Paris, at neighboring suburban sites located 20 km away, and at a rural station (100 km downwind). The budget uses ABL depths from elastic lidars, CO2 and CO concentrations from both the ICOS [d] and CO2-MEGAPARIS networks to quantify vertical advection and storage terms in the ABL mass budget. EC measurements are used to monitor biospheric surface fluxes. The budget in Paris provides a direct estimation of the average CO2 and CO fluxes from the city, while the budget at the suburban and rural stations provides an estimation of the advected fluxes. These anthropogenic fluxes are compared to the CITEPA and IER emission inventories using the air mass footprint from a Lagrangian Particle Dispersion Model in backward mode. Results from a case study in March 2012 are presented to assess the propagation of Paris CO2 and CO plume, the precision of the method and its ability to provide an independent verification of urban emission inventories. References: [a] Xueref-Remy et al., Abstract n°A13F-0277, AGU Fall Meeting 2010, San Francisco, USA [b] http://co2-megaparis.lsce.ipsl.fr/ [c] Gibert et al., J. Geophys. Research, 112, D10301 (2007) [d] http://www.icos-infrastructure.eu/

  20. Estimation of aboveground forest carbon flux in Oregon: adding components of change to stock-difference assessments

    Treesearch

    Andrew N. Gray; Thomas R. Whittier; David L. Azuma

    2014-01-01

    A substantial portion of the carbon (C) emitted by human activity is apparently being stored in forest ecosystems in the Northern Hemisphere, but the magnitude and cause are not precisely understood. Current official estimates of forest C flux are based on a combination of field measurements and other methods. The goal of this study was to improve on existing methods...

  1. Regional Carbon Dioxide and Water Vapor Exchange Over Heterogeneous Terrain

    NASA Technical Reports Server (NTRS)

    Mahrt, Larry J.

    2005-01-01

    In spite of setbacks due to forest fires, eviction after a change of landowners and unanticipated need to upgrade and replace much of the instrumentation, substantial progress has been made during the past three years, resulting in major new findings. Although most of the results are in manuscript form, three papers have been published and a fourth was recently submitted. The data has been subjected to extensive quality control. Extra attention has been devoted to the influence of tilt rotation and flux-calculation method, particularly with respect to nocturnal fluxes. Previous/standard methods for calculating nocturnal fluxes with moderate and strong stability are inadequate and lead to large random fluxes errors for individual records, due partly to inadvertent inclusion of mesoscale motions that strongly contaminant the estimation of fluxes by weak turbulence. Such large errors are serious for process studies requiring carbon dioxide fluxes for individual records, but are substantially reduced when averaging fluxes over longer periods as in calculation of annual NEE budgets. We have employed a superior method for estimating fluxes in stable conditions with a variable averaging width . Mesoscale fluxes are generally unimportant except for events and are generally not systematic or predictable. Mesoscale or regional models of our region are not able to reproduce important aspects of the diurnally varying wind field

  2. The potential of using remote sensing data to estimate air-sea CO2 exchange in the Baltic Sea

    NASA Astrophysics Data System (ADS)

    Parard, Gaëlle; Rutgersson, Anna; Parampil, Sindu Raj; Alexandre Charantonis, Anastase

    2017-12-01

    In this article, we present the first climatological map of air-sea CO2 flux over the Baltic Sea based on remote sensing data: estimates of pCO2 derived from satellite imaging using self-organizing map classifications along with class-specific linear regressions (SOMLO methodology) and remotely sensed wind estimates. The estimates have a spatial resolution of 4 km both in latitude and longitude and a monthly temporal resolution from 1998 to 2011. The CO2 fluxes are estimated using two types of wind products, i.e. reanalysis winds and satellite wind products, the higher-resolution wind product generally leading to higher-amplitude flux estimations. Furthermore, the CO2 fluxes were also estimated using two methods: the method of Wanninkhof et al. (2013) and the method of Rutgersson and Smedman (2009). The seasonal variation in fluxes reflects the seasonal variation in pCO2 unvaryingly over the whole Baltic Sea, with high winter CO2 emissions and high pCO2 uptakes. All basins act as a source for the atmosphere, with a higher degree of emission in the southern regions (mean source of 1.6 mmol m-2 d-1 for the South Basin and 0.9 for the Central Basin) than in the northern regions (mean source of 0.1 mmol m-2 d-1) and the coastal areas act as a larger sink (annual uptake of -4.2 mmol m-2 d-1) than does the open sea (-4 mmol m-2 d-1). In its entirety, the Baltic Sea acts as a small source of 1.2 mmol m-2 d-1 on average and this annual uptake has increased from 1998 to 2012.

  3. Why we need to estimate the sampling uncertainty of eddy covariance flux measurement?

    NASA Astrophysics Data System (ADS)

    Kim, W.; Seo, H. H.

    2015-12-01

    Fruitful studies on exchanges of energy, water and carbon dioxide between the atmosphere and terrestrial ecosystem has been produced under a global network (http://fluxnet.ornl.gov). The exchange is defined by a flux, and in traditional the flux is estimated with eddy covariance (EC) method as a mean flux F for 30-min or 1-hr, because no techniques have been established for a direct measurement of a momentary flux itself. Therefore, the exchange analysis with F is to paid attention to estimations of spatial or temporal mean, because the exchange estimated by arithmetic mean Fa might be inappropriate in terms of the sample F used in this averaging having nonidentical inherent quality within one another in accordance with different micrometeorological and ecophysiological conditions while those are measured by the same instruments. To overcome this issue, we propose the weighted mean Fw using a relative sampling uncertainty ɛ estimated by a sampling F and its uncertainty, and introduce Fw performance tested with EC measurements for various sites.

  4. Estimation of groundwater and nutrient fluxes to the Neuse River estuary, North Carolina

    USGS Publications Warehouse

    Spruill, T.B.; Bratton, J.F.

    2008-01-01

    A study was conducted between April 2004 and September 2005 to estimate groundwater and nutrient discharge to the Neuse River estuary in North Carolina. The largest groundwater fluxes were observed to occur generally within 20 m of the shoreline. Groundwater flux estimates based on seepage meter measurements ranged from 2.86??108 to 4.33??108 m3 annually and are comparable to estimates made using radon, a simple water-budget method, and estimates derived by using Darcy's Law and previously published general aquifer characteristics of the area. The lower groundwater flux estimate (equal to about 9 m3 s-1), which assumed the narrowest groundwater discharge zone (20 m) of three zone widths selected for an area west of New Bern, North Carolina, most closely agrees with groundwater flux estimates made using radon (3-9 m3 s-1) and Darcy's Law (about 9 m3 s-1). A groundwater flux of 9 m 3 s-1 is about 40% of the surface-water flow to the Neuse River estuary between Streets Ferry and the mouth of the estuary and about 7% of the surface-water inflow from areas upstream. Estimates of annual nitrogen (333 tonnes) and phosphorus (66 tonnes) fluxes from groundwater to the estuary, based on this analysis, are less than 6% of the nitrogen and phosphorus inputs derived from all sources (excluding oceanic inputs), and approximately 8% of the nitrogen and 17% of the phosphorus annual inputs from surface-water inflow to the Neuse River estuary assuming a mean annual precipitation of 1.27 m. We provide quantitative evidence, derived from three methods, that the contribution of water and nutrients from groundwater discharge to the Neuse River estuary is relatively minor, particularly compared with upstream sources of water and nutrients and with bottom sediment sources of nutrients. Locally high groundwater discharges do occur, however, and could help explain the occurrence of localized phytoplankton blooms, submerged aquatic vegetation, or fish kills. 

  5. An Investigation of the Compatibility of Radiation and Convection Heat Flux Measurements

    NASA Technical Reports Server (NTRS)

    Liebert, Curt H.

    1996-01-01

    A method for determining time-resolved absorbed surface heat flux and surface temperature in radiation and convection environments is described. The method is useful for verification of aerodynamic, heat transfer and durability models. A practical heat flux gage fabrication procedure and a simple one-dimensional inverse heat conduction model and calculation procedure are incorporated in this method. The model provides an estimate of the temperature and heat flux gradient in the direction of heat transfer through the gage. This paper discusses several successful time-resolved tests of this method in hostile convective heating and cooling environments.

  6. Top-of-atmosphere radiative fluxes - Validation of ERBE scanner inversion algorithm using Nimbus-7 ERB data

    NASA Technical Reports Server (NTRS)

    Suttles, John T.; Wielicki, Bruce A.; Vemury, Sastri

    1992-01-01

    The ERBE algorithm is applied to the Nimbus-7 earth radiation budget (ERB) scanner data for June 1979 to analyze the performance of an inversion method in deriving top-of-atmosphere albedos and longwave radiative fluxes. The performance is assessed by comparing ERBE algorithm results with appropriate results derived using the sorting-by-angular-bins (SAB) method, the ERB MATRIX algorithm, and the 'new-cloud ERB' (NCLE) algorithm. Comparisons are made for top-of-atmosphere albedos, longwave fluxes, viewing zenith-angle dependence of derived albedos and longwave fluxes, and cloud fractional coverage. Using the SAB method as a reference, the rms accuracy of monthly average ERBE-derived results are estimated to be 0.0165 (5.6 W/sq m) for albedos (shortwave fluxes) and 3.0 W/sq m for longwave fluxes. The ERBE-derived results were found to depend systematically on the viewing zenith angle, varying from near nadir to near the limb by about 10 percent for albedos and by 6-7 percent for longwave fluxes. Analyses indicated that the ERBE angular models are the most likely source of the systematic angular dependences. Comparison of the ERBE-derived cloud fractions, based on a maximum-likelihood estimation method, with results from the NCLE showed agreement within about 10 percent.

  7. Determining Near-Bottom Fluxes of Passive Tracers in Aquatic Environments

    NASA Astrophysics Data System (ADS)

    Bluteau, Cynthia E.; Ivey, Gregory N.; Donis, Daphne; McGinnis, Daniel F.

    2018-03-01

    In aquatic systems, the eddy correlation method (ECM) provides vertical flux measurements near the sediment-water interface. The ECM independently measures the turbulent vertical velocities w' and the turbulent tracer concentration c' at a high sampling rate (> 1 Hz) to obtain the vertical flux w'c'¯ from their time-averaged covariance. This method requires identifying and resolving all the flow-dependent time (and length) scales contributing to w'c'¯. With increasingly energetic flows, we demonstrate that the ECM's current technology precludes resolving the smallest flux-contributing scales. To avoid these difficulties, we show that for passive tracers such as dissolved oxygen, w'c'¯ can be measured from estimates of two scalar quantities: the rate of turbulent kinetic energy dissipation ɛ and the rate of tracer variance dissipation χc. Applying this approach to both laboratory and field observations demonstrates that w'c'¯ is well resolved by the new method and can provide flux estimates in more energetic flows where the ECM cannot be used.

  8. Comparison of Sensible Heat Flux from Eddy Covariance and Scintillometer over different land surface conditions

    NASA Astrophysics Data System (ADS)

    Zeweldi, D. A.; Gebremichael, M.; Summis, T.; Wang, J.; Miller, D.

    2008-12-01

    The large source of uncertainty in satellite-based evapotranspiration algorithm results from the estimation of sensible heat flux H. Traditionally eddy covariance sensors, and recently large-aperture scintillometers, have been used as ground truth to evaluate satellite-based H estimates. The two methods rely on different physical measurement principles, and represent different foot print sizes. In New Mexico, we conducted a field campaign during summer 2008 to compare H estimates obtained from the eddy covariance and scintillometer methods. During this field campaign, we installed sonic anemometers; one propeller eddy covariance (OPEC) equipped with net radiometer and soil heat flux sensors; large aperture scintillometer (LAS); and weather station consisting of wind speed, direction and radiation sensors over three different experimental areas consisting of different roughness conditions (desert, irrigated area and lake). Our results show the similarities and differences in H estimates obtained from these various methods over the different land surface conditions. Further, our results show that the H estimates obtained from the LAS agree with those obtained from the eddy covariance method when high frequency thermocouple temperature, instead of the typical weather station temperature measurements, is used in the LAS analysis.

  9. Application of a combined measurement and modeling method to quantify windblown dust emissions from the exposed playa at Mono Lake, California.

    PubMed

    Ono, Duane; Kiddoo, Phill; Howard, Christopher; Davis, Guy; Richmond, Kenneth

    2011-10-01

    Particulate matter < or =10 microm (PM10) emissions due to wind erosion can vary dramatically with changing surface conditions. Crust formation, mechanical disturbance, soil texture, moisture, and chemical content of the soil can affect the amount of dust emitted during a wind event. A refined method of quantifying windblown dust emissions was applied at Mono Lake, CA, to account for changing surface conditions. This method used a combination of real-time sand flux monitoring, ambient PM10 monitoring, and dispersion modeling to estimate dust emissions and their downwind impact. The method identified periods with high emissions and periods when the surface was stable (no sand flux), even though winds may have been high. A network of 25 Cox sand catchers (CSCs) was used to measure the mass of saltating particles to estimate sand flux rates across a 2-km2 area. Two electronic sensors (Sensits) were used to time-resolve the CSC sand mass to estimate hourly sand flux rates, and a perimeter tapered element oscillating microbalance (TEOM) monitor measured hourly PM10 concentrations. Hourly sand flux rates were related by dispersion modeling to hourly PM10 concentrations to back-calculate the ratio of vertical PM10 flux to horizontal sand flux (K-factors). Geometric mean K-factor values (K(f)) were found to change seasonally, ranging from 1.3 x 10(-5) to 5.1 x 10(-5) for sand flux measured at 15 cm above the surface (q15). Hourly PM10 emissions, F, were calculated by applying seasonal K-factors to sand flux measurements (F = K(f) x q15). The maximum hourly PM10 emission rate from the study area was 76 g/m2 x hr (10-m wind speed = 23.5 m/sec). Maximum daily PM10 emissions were estimated at 450 g/m2 x day, and annual emissions at 1095 g/m2 x yr. Hourly PM10 emissions were used by the U.S. Environmental Protection Agency (EPA) guideline AERMOD dispersion model to estimate downwind ambient impacts. Model predictions compared well with monitor concentrations, with hourly PM10 ranging from 16 to over 60,000 microg/m3 (slope = 0.89, R2 = 0.77).

  10. Estimating greenhouse gas emissions from a waste lagoon

    USDA-ARS?s Scientific Manuscript database

    A cost-effective approach was used to investigate the relationship between emission of the greenhouse gases (GHG) CO2, CH4, and N2O and energy fluxes from a swine waste lagoon. Energy fluxes were calculated using the Penman method. The energy fluxes showed a diurnal pattern as expected of such flux...

  11. How Well Can a Footpoint Tracking Method Estimate the Magnetic Helicity Influx during Flux Emergence?

    NASA Astrophysics Data System (ADS)

    Choe, Gwangson; Kim, Sunjung; Kim, Kap-Sung; No, Jincheol

    2015-08-01

    As shown by Démoulin and Berger (2003), the magnetic helicity flux through the solar surface into the solar atmosphere can be exactly calculated if we can trace the motion of footpoints with infinite temporal and spatial resolutions. When there is a magnetic flux transport across the solar surface, the horizontal velocity of footpoints becomes infinite at the polarity inversion line, although the surface integral yielding the helicity flux does not diverge. In practical application, a finite temporal and spatial resolution causes an underestimate of the magnetic helicity flux when a magnetic flux emerges from below the surface, because there is an observational blackout area near a polarity inversion line whether it is pre-existing or newly formed. In this paper, we consider emergence of simple magnetic flux ropes and calculate the supremum of the magnitude of the helicity influx that can be estimated from footpoint tracking. The results depend on the ratio of the resolvable length scale and the flux rope diameter. For a Gold-Hoyle flux rope, in which all field lines are uniformly twisted, the observationally estimated helicity influx would be about 90% of the real influx when the flux rope diameter is one hundred times the spatial resolution (for a large flux rope), and about 45% when it is ten times (for a small flux rope). For Lundquist flux ropes, the errors incurred by observational estimation are smaller than the case of the Gold-Hoyle flux rope, but could be as large as 30% of the real influx. Our calculation suggests that the error in the helicity influx estimate is at least half of the real influx or even larger when small scale magnetic structures (less than 10,000 km) emerge into the solar atmosphere.

  12. Influence of aerosols on surface reaching spectral irradiance and introduction to a new technique for estimating aerosol radiative forcing from spectral flux measurements

    NASA Astrophysics Data System (ADS)

    Rao, R. R.

    2015-12-01

    Aerosol radiative forcing estimates with high certainty are required in climate change studies. The approach in estimating the aerosol radiative forcing by using the chemical composition of aerosols is not effective as the chemical composition data with radiative properties are not widely available. In this study we look into the approach where ground based spectral radiation flux measurements along with an RT model is used to estimate radiative forcing. Measurements of spectral flux were made using an ASD spectroradiometer with 350 - 1050 nm wavelength range and 3nm resolution for around 54 clear-sky days during which AOD range was around 0.1 to 0.7. Simultaneous measurements of black carbon were also made using Aethalometer (Magee Scientific) which ranged from around 1.5 ug/m3 to 8 ug/m3. All the measurements were made in the campus of Indian Institute of Science which is in the heart of Bangalore city. The primary study involved in understanding the sensitivity of spectral flux to change in the mass concentration of individual aerosol species (Optical properties of Aerosols and Clouds -OPAC classified aerosol species) using the SBDART RT model. This made us clearly distinguish the region of influence of different aerosol species on the spectral flux. Following this, a new technique has been introduced to estimate an optically equivalent mixture of aerosol species for the given location. The new method involves an iterative process where the mixture of aerosol species are changed in OPAC model and RT model is run as long as the mixture which mimics the measured spectral flux within 2-3% deviation from measured spectral flux is obtained. Using the optically equivalent aerosol mixture and RT model aerosol radiative forcing is estimated. The new method is limited to clear sky scenes and its accuracy to derive an optically equivalent aerosol mixture reduces when diffuse component of flux increases. Our analysis also showed that direct component of spectral flux is more sensitive to different aerosol species than total spectral flux which was also supported by our observed data.

  13. A simple method for estimating frequency response corrections for eddy covariance systems

    Treesearch

    W. J. Massman

    2000-01-01

    A simple analytical formula is developed for estimating the frequency attenuation of eddy covariance fluxes due to sensor response, path-length averaging, sensor separation, signal processing, and flux averaging periods. Although it is an approximation based on flat terrain cospectra, this analytical formula should have broader applicability than just flat-terrain...

  14. Estimation of water flux in urban area using eddy covariance measurements in Riverside, Southern California

    USDA-ARS?s Scientific Manuscript database

    Micrometeorological methods can direct measure the sensible and latent heat flux in specific sites and provide robust estimates of the evaporative fraction (EF), which is the fraction of available surface energy contained in latent heat. Across a vegetation coverage gradient in urban area, an empir...

  15. Comparison of Source Partitioning Methods for CO2 and H2O Fluxes Based on High Frequency Eddy Covariance Data

    NASA Astrophysics Data System (ADS)

    Klosterhalfen, Anne; Moene, Arnold; Schmidt, Marius; Ney, Patrizia; Graf, Alexander

    2017-04-01

    Source partitioning of eddy covariance (EC) measurements of CO2 into respiration and photosynthesis is routinely used for a better understanding of the exchange of greenhouse gases, especially between terrestrial ecosystems and the atmosphere. The most frequently used methods are usually based either on relations of fluxes to environmental drivers or on chamber measurements. However, they often depend strongly on assumptions or invasive measurements and do usually not offer partitioning estimates for latent heat fluxes into evaporation and transpiration. SCANLON and SAHU (2008) and SCANLON and KUSTAS (2010) proposed an promising method to estimate the contributions of transpiration and evaporation using measured high frequency time series of CO2 and H2O fluxes - no extra instrumentation necessary. This method (SK10 in the following) is based on the spatial separation and relative strength of sources and sinks of CO2 and water vapor among the sub-canopy and canopy. Assuming that air from those sources and sinks is not yet perfectly mixed before reaching EC sensors, partitioning is estimated based on the separate application of the flux-variance similarity theory to the stomatal and non-stomatal components of the regarded fluxes, as well as on additional assumptions on stomatal water use efficiency (WUE). The CO2 partitioning method after THOMAS et al. (2008) (TH08 in the following) also follows the argument that the dissimilarities of sources and sinks in and below a canopy affect the relation between H2O and CO2 fluctuations. Instead of involving assumptions on WUE, TH08 directly screens their scattergram for signals of joint respiration and evaporation events and applies a conditional sampling methodology. In spite of their different main targets (H2O vs. CO2), both methods can yield partitioning estimates on both fluxes. We therefore compare various sub-methods of SK10 and TH08 including own modifications (e.g., cluster analysis) to each other, to established source partitioning methods, and to chamber measurements at various agroecosystems. Further, profile measurements and a canopy-resolving Large Eddy Simulation model are used to test the assumptions involved in SK10. Scanlon, T.M., Kustas, W.P., 2010. Partitioning carbon dioxide and water vapor fluxes using correlation analysis. Agricultural and Forest Meteorology 150 (1), 89-99. Scanlon, T.M., Sahu, P., 2008. On the correlation structure of water vapor and carbon dioxide in the atmospheric surface layer: A basis for flux partitioning. Water Resources Research 44 (10), W10418, 15 pp. Thomas, C., Martin, J.G., Goeckede, M., Siqueira, M.B., Foken, T., Law, B.E., Loescher H.W., Katul, G., 2008. Estimating daytime subcanopy respiration from conditional sampling methods applied to multi-scalar high frequency turbulence time series. Agricultural and Forest Meteorology 148 (8-9), 1210-1229.

  16. Magnetic Helicity Estimations in Models and Observations of the Solar Magnetic Field. III. Twist Number Method

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Guo, Y.; Pariat, E.; Moraitis, K.

    We study the writhe, twist, and magnetic helicity of different magnetic flux ropes, based on models of the solar coronal magnetic field structure. These include an analytical force-free Titov–Démoulin equilibrium solution, non-force-free magnetohydrodynamic simulations, and nonlinear force-free magnetic field models. The geometrical boundary of the magnetic flux rope is determined by the quasi-separatrix layer and the bottom surface, and the axis curve of the flux rope is determined by its overall orientation. The twist is computed by the Berger–Prior formula, which is suitable for arbitrary geometry and both force-free and non-force-free models. The magnetic helicity is estimated by the twistmore » multiplied by the square of the axial magnetic flux. We compare the obtained values with those derived by a finite volume helicity estimation method. We find that the magnetic helicity obtained with the twist method agrees with the helicity carried by the purely current-carrying part of the field within uncertainties for most test cases. It is also found that the current-carrying part of the model field is relatively significant at the very location of the magnetic flux rope. This qualitatively explains the agreement between the magnetic helicity computed by the twist method and the helicity contributed purely by the current-carrying magnetic field.« less

  17. Solutions for the diurnally forced advection-diffusion equation to estimate bulk fluid velocity and diffusivity in streambeds from temperature time series

    Treesearch

    Charles H. Luce; Daniele Tonina; Frank Gariglio; Ralph Applebee

    2013-01-01

    Work over the last decade has documented methods for estimating fluxes between streams and streambeds from time series of temperature at two depths in the streambed. We present substantial extension to the existing theory and practice of using temperature time series to estimate streambed water fluxes and thermal properties, including (1) a new explicit analytical...

  18. An evaluation of gas transfer velocity parameterizations during natural convection using DNS

    NASA Astrophysics Data System (ADS)

    Fredriksson, Sam T.; Arneborg, Lars; Nilsson, Hâkan; Zhang, Qi; Handler, Robert A.

    2016-02-01

    Direct numerical simulations (DNS) of free surface flows driven by natural convection are used to evaluate different methods of estimating air-water gas exchange at no-wind conditions. These methods estimate the transfer velocity as a function of either the horizontal flow divergence at the surface, the turbulent kinetic energy dissipation beneath the surface, the heat flux through the surface, or the wind speed above the surface. The gas transfer is modeled via a passive scalar. The Schmidt number dependence is studied for Schmidt numbers of 7, 150 and 600. The methods using divergence, dissipation and heat flux estimate the transfer velocity well for a range of varying surface heat flux values, and domain depths. The two evaluated empirical methods using wind (in the limit of no wind) give reasonable estimates of the transfer velocity, depending however on the surface heat flux and surfactant saturation. The transfer velocity is shown to be well represented by the expression, ks=A |Bν|1/4 Sc-n, where A is a constant, B is the buoyancy flux, ν is the kinematic viscosity, Sc is the Schmidt number, and the exponent n depends on the water surface characteristics. The results suggest that A=0.39 and n≈1/2 and n≈2/3 for slip and no-slip boundary conditions at the surface, respectively. It is further shown that slip and no-slip boundary conditions predict the heat transfer velocity corresponding to the limits of clean and highly surfactant contaminated surfaces, respectively. This article was corrected on 22 MAR 2016. See the end of the full text for details.

  19. Energy fluxes estimation in a juniper tree area of the Donana biological reserve through TSEB method and Landsat-5TM imagery

    USDA-ARS?s Scientific Manuscript database

    Energy fluxes computing (actual evapotranspiration, net radiation, sensible heat and soil heat flux) are essential to improve the knowledge of the hydrological cycle, especially in natural vegetation covers. In this paper we present the first results of the energy fluxes modeling by means of the TSE...

  20. Analytical Modeling of a Double-Sided Flux Concentrating E-Core Transverse Flux Machine with Pole Windings

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Muljadi, Eduard; Hasan, Iftekhar; Husain, Tausif

    In this paper, a nonlinear analytical model based on the Magnetic Equivalent Circuit (MEC) method is developed for a double-sided E-Core Transverse Flux Machine (TFM). The proposed TFM has a cylindrical rotor, sandwiched between E-core stators on both sides. Ferrite magnets are used in the rotor with flux concentrating design to attain high airgap flux density, better magnet utilization, and higher torque density. The MEC model was developed using a series-parallel combination of flux tubes to estimate the reluctance network for different parts of the machine including air gaps, permanent magnets, and the stator and rotor ferromagnetic materials, in amore » two-dimensional (2-D) frame. An iterative Gauss-Siedel method is integrated with the MEC model to capture the effects of magnetic saturation. A single phase, 1 kW, 400 rpm E-Core TFM is analytically modeled and its results for flux linkage, no-load EMF, and generated torque, are verified with Finite Element Analysis (FEA). The analytical model significantly reduces the computation time while estimating results with less than 10 percent error.« less

  1. Numerical simulation of groundwater flow in strongly anisotropic aquifers using multiple-point flux approximation method

    NASA Astrophysics Data System (ADS)

    Lin, S. T.; Liou, T. S.

    2017-12-01

    Numerical simulation of groundwater flow in anisotropic aquifers usually suffers from the lack of accuracy of calculating groundwater flux across grid blocks. Conventional two-point flux approximation (TPFA) can only obtain the flux normal to the grid interface but completely neglects the one parallel to it. Furthermore, the hydraulic gradient in a grid block estimated from TPFA can only poorly represent the hydraulic condition near the intersection of grid blocks. These disadvantages are further exacerbated when the principal axes of hydraulic conductivity, global coordinate system, and grid boundary are not parallel to one another. In order to refine the estimation the in-grid hydraulic gradient, several multiple-point flux approximation (MPFA) methods have been developed for two-dimensional groundwater flow simulations. For example, the MPFA-O method uses the hydraulic head at the junction node as an auxiliary variable which is then eliminated using the head and flux continuity conditions. In this study, a three-dimensional MPFA method will be developed for numerical simulation of groundwater flow in three-dimensional and strongly anisotropic aquifers. This new MPFA method first discretizes the simulation domain into hexahedrons. Each hexahedron is further decomposed into a certain number of tetrahedrons. The 2D MPFA-O method is then extended to these tetrahedrons, using the unknown head at the intersection of hexahedrons as an auxiliary variable along with the head and flux continuity conditions to solve for the head at the center of each hexahedron. Numerical simulations using this new MPFA method have been successfully compared with those obtained from a modified version of TOUGH2.

  2. Full GHG balance of a drained fen peatland cropped to spring barley and reed canary grass using comparative assessment of CO2 fluxes.

    PubMed

    Karki, Sandhya; Elsgaard, Lars; Kandel, Tanka P; Lærke, Poul Erik

    2015-03-01

    Empirical greenhouse gas (GHG) flux estimates from diverse peatlands are required in order to derive emission factors for managed peatlands. This study on a drained fen peatland quantified the annual GHG balance (Carbon dioxide (CO2), nitrous oxide (N2O), methane (CH4), and C exported in crop yield) from spring barley (SB) and reed canary grass (RCG) using static opaque chambers for GHG flux measurements and biomass yield for indirectly estimating gross primary production (GPP). Estimates of ecosystem respiration (ER) and GPP were compared with more advanced but costly and labor-intensive dynamic chamber studies. Annual GHG balance for the two cropping systems was 4.0 ± 0.7 and 8.1 ± 0.2 Mg CO2-Ceq ha(-1) from SB and RCG, respectively (mean ± standard error, n = 3). Annual CH4 emissions were negligible (<0.006 Mg CO2-Ceq ha(-1)), and N2O emissions contributed only 4-13 % of the full GHG balance (0.5 and 0.3 Mg CO2-Ceq ha(-1) for SB and RCG, respectively). The statistical significance of low CH4 and N2O fluxes was evaluated by a simulation procedure which showed that most of CH4 fluxes were within the range that could arise from random variation associated with actual zero-flux situations. ER measured by static chamber and dynamic chamber methods was similar, particularly when using nonlinear regression techniques for flux calculations. A comparison of GPP derived from aboveground biomass and from measuring net ecosystem exchange (NEE) showed that GPP estimation from biomass might be useful, or serve as validation, for more advanced flux measurement methods. In conclusion, combining static opaque chambers for measuring ER of CO2 and CH4 and N2O fluxes with biomass yield for GPP estimation worked well in the drained fen peatland cropped to SB and RCG and presented a valid alternative to estimating the full GHG balance by dynamic chambers.

  3. Comparison of evaporative fluxes from porous surfaces resolved by remotely sensed and in-situ temperature and soil moisture data

    NASA Astrophysics Data System (ADS)

    Wallen, B.; Trautz, A.; Smits, K. M.

    2014-12-01

    The estimation of evaporation has important implications in modeling climate at the regional and global scale, the hydrological cycle and estimating environmental stress on agricultural systems. In field and laboratory studies, remote sensing and in-situ techniques are used to collect thermal and soil moisture data of the soil surface and subsurface which is then used to estimate evaporative fluxes, oftentimes using the sensible heat balance method. Nonetheless, few studies exist that compare the methods due to limited data availability and the complexity of many of the techniques, making it difficult to understand flux estimates. This work compares different methods used to quantify evaporative flux based on remotely sensed and in-situ temperature and soil moisture data. A series of four laboratory experiments were performed under ambient and elevated air temperature conditions with homogeneous and heterogeneous soil configurations in a small two-dimensional soil tank interfaced with a small wind tunnel apparatus. The soil tank and wind tunnel were outfitted with a suite of sensors that measured soil temperature (surface and subsurface), air temperature, soil moisture, and tank weight. Air and soil temperature measurements were obtained using infrared thermography, heat pulse sensors and thermistors. Spatial and temporal thermal data were numerically inverted to obtain the evaporative flux. These values were then compared with rates of mass loss from direct weighing of the samples. Results demonstrate the applicability of different methods under different surface boundary conditions; no one method was deemed most applicable under every condition. Infrared thermography combined with the sensible heat balance method was best able to determine evaporative fluxes under stage 1 conditions while distributed temperature sensing combined with the sensible heat balance method best determined stage 2 evaporation. The approaches that appear most promising for determining the surface energy balance incorporates soil moisture rate of change over time and atmospheric conditions immediately above the soil surface. An understanding of the fidelity regarding predicted evaporation rates based upon stages of evaporation enables a more deliberate selection of the suite of sensors required for data collection.

  4. On the performance of surface renewal analysis to estimate sensible heat flux over two growing rice fields under the influence of regional advection

    NASA Astrophysics Data System (ADS)

    Castellví, F.; Snyder, R. L.

    2009-09-01

    SummaryHigh-frequency temperature data were recorded at one height and they were used in Surface Renewal (SR) analysis to estimate sensible heat flux during the full growing season of two rice fields located north-northeast of Colusa, CA (in the Sacramento Valley). One of the fields was seeded into a flooded paddy and the other was drill seeded before flooding. To minimize fetch requirements, the measurement height was selected to be close to the maximum expected canopy height. The roughness sub-layer depth was estimated to discriminate if the temperature data came from the inertial or roughness sub-layer. The equation to estimate the roughness sub-layer depth was derived by combining simple mixing-length theory, mixing-layer analogy, equations to account for stable atmospheric surface layer conditions, and semi-empirical canopy-architecture relationships. The potential for SR analysis as a method that operates in the full surface boundary layer was tested using data collected over growing vegetation at a site influenced by regional advection of sensible heat flux. The inputs used to estimate the sensible heat fluxes included air temperature sampled at 10 Hz, the mean and variance of the horizontal wind speed, the canopy height, and the plant area index for a given intermediate height of the canopy. Regardless of the stability conditions and measurement height above the canopy, sensible heat flux estimates using SR analysis gave results that were similar to those measured with the eddy covariance method. Under unstable cases, it was shown that the performance was sensitive to estimation of the roughness sub-layer depth. However, an expression was provided to select the crucial scale required for its estimation.

  5. Investigation of Convection and Pressure Treatment with Splitting Techniques

    NASA Technical Reports Server (NTRS)

    Thakur, Siddharth; Shyy, Wei; Liou, Meng-Sing

    1995-01-01

    Treatment of convective and pressure fluxes in the Euler and Navier-Stokes equations using splitting formulas for convective velocity and pressure is investigated. Two schemes - controlled variation scheme (CVS) and advection upstream splitting method (AUSM) - are explored for their accuracy in resolving sharp gradients in flows involving moving or reflecting shock waves as well as a one-dimensional combusting flow with a strong heat release source term. For two-dimensional compressible flow computations, these two schemes are implemented in one of the pressure-based algorithms, whose very basis is the separate treatment of convective and pressure fluxes. For the convective fluxes in the momentum equations as well as the estimation of mass fluxes in the pressure correction equation (which is derived from the momentum and continuity equations) of the present algorithm, both first- and second-order (with minmod limiter) flux estimations are employed. Some issues resulting from the conventional use in pressure-based methods of a staggered grid, for the location of velocity components and pressure, are also addressed. Using the second-order fluxes, both CVS and AUSM type schemes exhibit sharp resolution. Overall, the combination of upwinding and splitting for the convective and pressure fluxes separately exhibits robust performance for a variety of flows and is particularly amenable for adoption in pressure-based methods.

  6. Real Time Radiation Monitoring Using Nanotechnology

    NASA Technical Reports Server (NTRS)

    Li, Jing (Inventor); Hanratty, James J. (Inventor); Wilkins, Richard T. (Inventor); Lu, Yijiang (Inventor)

    2016-01-01

    System and method for monitoring receipt and estimating flux value, in real time, of incident radiation, using two or more nanostructures (NSs) and associated terminals to provide closed electrical paths and to measure one or more electrical property change values .DELTA.EPV, associated with irradiated NSs, during a sequence of irradiation time intervals. Effects of irradiation, without healing and with healing, of the NSs, are separately modeled for first order and second order healing. Change values.DELTA.EPV are related to flux, to cumulative dose received by NSs, and to radiation and healing effectivity parameters and/or.mu., associated with the NS material and to the flux. Flux and/or dose are estimated in real time, based on EPV change values, using measured .DELTA.EPV values. Threshold dose for specified changes of biological origin (usually undesired) can be estimated. Effects of time-dependent radiation flux are analyzed in pre-healing and healing regimes.

  7. Evapotranspiration based on equilibrated relative humidity (ETRHEQ): Evaluation over the continental U.S.

    NASA Astrophysics Data System (ADS)

    Rigden, Angela J.; Salvucci, Guido D.

    2015-04-01

    A novel method of estimating evapotranspiration (ET), referred to as the ETRHEQ method, is further developed, validated, and applied across the U.S. from 1961 to 2010. The ETRHEQ method estimates the surface conductance to water vapor transport, which is the key rate-limiting parameter of typical ET models, by choosing the surface conductance that minimizes the vertical variance of the calculated relative humidity profile averaged over the day. The ETRHEQ method, which was previously tested at five AmeriFlux sites, is modified for use at common weather stations and further validated at 20 AmeriFlux sites that span a wide range of climates and limiting factors. Averaged across all sites, the daily latent heat flux RMSE is ˜26 W·m-2 (or 15%). The method is applied across the U.S. at 305 weather stations and spatially interpolated using ANUSPLIN software. Gridded annual mean ETRHEQ ET estimates are compared with four data sets, including water balance-derived ET, machine-learning ET estimates based on FLUXNET data, North American Land Data Assimilation System project phase 2 ET, and a benchmark product that integrates 14 global ET data sets, with RMSEs ranging from 8.7 to 12.5 cm·yr-1. The ETRHEQ method relies only on data measured at weather stations, an estimate of vegetation height derived from land cover maps, and an estimate of soil thermal inertia. These data requirements allow it to have greater spatial coverage than direct measurements, greater historical coverage than satellite methods, significantly less parameter specification than most land surface models, and no requirement for calibration.

  8. Estimation of Regional Carbon Balance from Atmospheric Observations

    NASA Astrophysics Data System (ADS)

    Denning, S.; Uliasz, M.; Skidmore, J.

    2002-12-01

    Variations in the concentration of CO2 and other trace gases in time and space contain information about sources and sinks at regional scales. Several methods have been developed to quantitatively extract this information from atmospheric measurements. Mass-balance techniques depend on the ability to repeatedly sample the same mass of air, which involves careful attention to airmass trajectories. Inverse and adjoint techniques rely on decomposition of the source field into quasi-independent "basis functions" that are propagated through transport models and then used to synthesize optimal linear combinations that best match observations. A recently proposed method for regional flux estimation from continuous measurements at tall towers relies on time-mean vertical gradients, and requires careful trajectory analysis to map the estimates onto regional ecosystems. Each of these techniques is likely to be applied to measurements made during the North American Carbon Program. We have also explored the use of Bayesian synthesis inversion at regional scales, using a Lagrangian particle dispersion model driven by mesoscale transport fields. Influence functions were calculated for each hypothetical observation in a realistic diurnally-varying flow. These influence functions were then treated as basis functions for the purpose of separate inversions for daytime photosynthesis and 24-hour mean ecosystem respiration. Our results highlight the importance of estimating CO2 fluxes through the lateral boundaries of the model. Respiration fluxes were well constrained by one or two hypothetical towers, regardless of inflow fluxes. Time-varying assimilation fluxes were less well constrained, and much more dependent on knowledge of inflow fluxes. The small net difference between respiration and photosynthesis was the most difficult to determine, being extremely sensitive to knowledge of inflow fluxes. Finally, we explored the feasibility of directly incorporating mid-day concentration values measured at surface-layer flux towers in global inversions for regional surface fluxes. We found that such data would substantially improve the observational constraint on current carbon cycle models, especially if applied selectively to a well-designed subset of the current network of flux towers.

  9. Urban surface energy fluxes based on remotely-sensed data and micrometeorological measurements over the Kansai area, Japan

    NASA Astrophysics Data System (ADS)

    Sukeyasu, T.; Ueyama, M.; Ando, T.; Kosugi, Y.; Kominami, Y.

    2017-12-01

    The urban heat island is associated with land cover changes and increases in anthropogenic heat fluxes. Clear understanding of the surface energy budget at urban area is the most important for evaluating the urban heat island. In this study, we develop a model based on remotely-sensed data for the Kansai area in Japan and clarify temporal transitions and spatial distributions of the surface energy flux from 2000 to 2016. The model calculated the surface energy fluxes based on various satellite and GIS products. The model used land surface temperature, surface emissivity, air temperature, albedo, downward shortwave radiation and land cover/use type from the moderate resolution imaging spectroradiometer (MODIS) under cloud free skies from 2000 to 2016 over the Kansai area in Japan (34 to 35 ° N, 135 to 136 ° E). Net radiation was estimated by a radiation budget of upward/downward shortwave and longwave radiation. Sensible heat flux was estimated by a bulk aerodynamic method. Anthropogenic heat flux was estimated by the inventory data. Latent heat flux was examined with residues of the energy budget and parameterization of bulk transfer coefficients. We validated the model using observed fluxes from five eddy-covariance measurement sites: three urban sites and two forested sites. The estimated net radiation roughly agreed with the observations, but the sensible heat flux were underestimated. Based on the modeled spatial distributions of the fluxes, the daytime net radiation in the forested area was larger than those in the urban area, owing to higher albedo and land surface temperatures in the urban area than the forested area. The estimated anthropogenic heat flux was high in the summer and winter periods due to increases in energy-requirements.

  10. Summertime elemental mercury exchange of temperate grasslands on an ecosystem-scale

    PubMed Central

    Fritsche, J.; Wohlfahrt, G.; Ammann, C.; Zeeman, M.; Hammerle, A.; Obrist, D.; Alewell, C.

    2013-01-01

    In order to estimate the air-surface mercury exchange of grasslands in temperate climate regions, fluxes of gaseous elemental mercury (GEM) were measured at two sites in Switzerland and one in Austria during summer 2006. Two classic micrometeorological methods (aerodynamic and modified Bowen ratio) have been applied to estimate net GEM exchange rates and to determine the response of the GEM flux to changes in environmental conditions (e.g. heavy rain, summer ozone) on an ecosystem-scale. Both methods proved to be appropriate to estimate fluxes on time scales of a few hours and longer. Average dry deposition rates up to 4.3 ng m−2 h−1 and mean deposition velocities up to 0.10 cm s−1 were measured, which indicates that during the active vegetation period temperate grasslands are a small net sink for atmospheric mercury. With increasing ozone concentrations depletion of GEM was observed, but could not be quantified from the flux signal. Night-time deposition fluxes of GEM were measured and seem to be the result of mercury co-deposition with condensing water. Effects of grass cuts could also be observed, but were of minor magnitude. PMID:24348525

  11. Constraining Gas Diffusivity-Soil Water Content Relationships in Forest Soils Using Surface Chamber Fluxes and Depth Profiles of Multiple Trace Gases

    NASA Astrophysics Data System (ADS)

    Dore, J. E.; Kaiser, K.; Seybold, E. C.; McGlynn, B. L.

    2012-12-01

    Forest soils are sources of carbon dioxide (CO2) to the atmosphere and can act as either sources or sinks of methane (CH4) and nitrous oxide (N2O), depending on redox conditions and other factors. Soil moisture is an important control on microbial activity, redox conditions and gas diffusivity. Direct chamber measurements of soil-air CO2 fluxes are facilitated by the availability of sensitive, portable infrared sensors; however, corresponding CH4 and N2O fluxes typically require the collection of time-course physical samples from the chamber with subsequent analyses by gas chromatography (GC). Vertical profiles of soil gas concentrations may also be used to derive CH4 and N2O fluxes by the gradient method; this method requires much less time and many fewer GC samples than the direct chamber method, but requires that effective soil gas diffusivities are known. In practice, soil gas diffusivity is often difficult to accurately estimate using a modeling approach. In our study, we apply both the chamber and gradient methods to estimate soil trace gas fluxes across a complex Rocky Mountain forested watershed in central Montana. We combine chamber flux measurements of CO2 (by infrared sensor) and CH4 and N2O (by GC) with co-located soil gas profiles to determine effective diffusivity in soil for each gas simultaneously, over-determining the diffusion equations and providing constraints on both the chamber and gradient methodologies. We then relate these soil gas diffusivities to soil type and volumetric water content in an effort to arrive at empirical parameterizations that may be used to estimate gas diffusivities across the watershed, thereby facilitating more accurate, frequent and widespread gradient-based measurements of trace gas fluxes across our study system. Our empirical approach to constraining soil gas diffusivity is well suited for trace gas flux studies over complex landscapes in general.

  12. Evaluation of different methods to model near-surface turbulent fluxes for a mountain glacier in the Cariboo Mountains, BC, Canada

    NASA Astrophysics Data System (ADS)

    Radić, Valentina; Menounos, Brian; Shea, Joseph; Fitzpatrick, Noel; Tessema, Mekdes A.; Déry, Stephen J.

    2017-12-01

    As part of surface energy balance models used to simulate glacier melting, choosing parameterizations to adequately estimate turbulent heat fluxes is extremely challenging. This study aims to evaluate a set of four aerodynamic bulk methods (labeled as C methods), commonly used to estimate turbulent heat fluxes for a sloped glacier surface, and two less commonly used bulk methods developed from katabatic flow models. The C methods differ in their parameterizations of the bulk exchange coefficient that relates the fluxes to the near-surface measurements of mean wind speed, air temperature, and humidity. The methods' performance in simulating 30 min sensible- and latent-heat fluxes is evaluated against the measured fluxes from an open-path eddy-covariance (OPEC) method. The evaluation is performed at a point scale of a mountain glacier, using one-level meteorological and OPEC observations from multi-day periods in the 2010 and 2012 summer seasons. The analysis of the two independent seasons yielded the same key findings, which include the following: first, the bulk method, with or without the commonly used Monin-Obukhov (M-O) stability functions, overestimates the turbulent heat fluxes over the observational period, mainly due to a substantial overestimation of the friction velocity. This overestimation is most pronounced during the katabatic flow conditions, corroborating the previous findings that the M-O theory works poorly in the presence of a low wind speed maximum. Second, the method based on a katabatic flow model (labeled as the KInt method) outperforms any C method in simulating the friction velocity; however, the C methods outperform the KInt method in simulating the sensible-heat fluxes. Third, the best overall performance is given by a hybrid method, which combines the KInt approach with the C method; i.e., it parameterizes eddy viscosity differently than eddy diffusivity. An error analysis reveals that the uncertainties in the measured meteorological variables and the roughness lengths produce errors in the modeled fluxes that are smaller than the differences between the modeled and observed fluxes. This implies that further advances will require improvement to model theory rather than better measurements of input variables. Further data from different glaciers are needed to investigate any universality of these findings.

  13. Estimation of transient heat flux density during the heat supply of a catalytic wall steam methane reformer

    NASA Astrophysics Data System (ADS)

    Settar, Abdelhakim; Abboudi, Saïd; Madani, Brahim; Nebbali, Rachid

    2018-02-01

    Due to the endothermic nature of the steam methane reforming reaction, the process is often limited by the heat transfer behavior in the reactors. Poor thermal behavior sometimes leads to slow reaction kinetics, which is characterized by the presence of cold spots in the catalytic zones. Within this framework, the present work consists on a numerical investigation, in conjunction with an experimental one, on the one-dimensional heat transfer phenomenon during the heat supply of a catalytic-wall reactor, which is designed for hydrogen production. The studied reactor is inserted in an electric furnace where the heat requirement of the endothermic reaction is supplied by electric heating system. During the heat supply, an unknown heat flux density, received by the reactive flow, is estimated using inverse methods. In the basis of the catalytic-wall reactor model, an experimental setup is engineered in situ to measure the temperature distribution. Then after, the measurements are injected in the numerical heat flux estimation procedure, which is based on the Function Specification Method (FSM). The measured and estimated temperatures are confronted and the heat flux density which crosses the reactor wall is determined.

  14. Methodology for estimation of time-dependent surface heat flux due to cryogen spray cooling.

    PubMed

    Tunnell, James W; Torres, Jorge H; Anvari, Bahman

    2002-01-01

    Cryogen spray cooling (CSC) is an effective technique to protect the epidermis during cutaneous laser therapies. Spraying a cryogen onto the skin surface creates a time-varying heat flux, effectively cooling the skin during and following the cryogen spurt. In previous studies mathematical models were developed to predict the human skin temperature profiles during the cryogen spraying time. However, no studies have accounted for the additional cooling due to residual cryogen left on the skin surface following the spurt termination. We formulate and solve an inverse heat conduction (IHC) problem to predict the time-varying surface heat flux both during and following a cryogen spurt. The IHC formulation uses measured temperature profiles from within a medium to estimate the surface heat flux. We implement a one-dimensional sequential function specification method (SFSM) to estimate the surface heat flux from internal temperatures measured within an in vitro model in response to a cryogen spurt. Solution accuracy and experimental errors are examined using simulated temperature data. Heat flux following spurt termination appears substantial; however, it is less than that during the spraying time. The estimated time-varying heat flux can subsequently be used in forward heat conduction models to estimate temperature profiles in skin during and following a cryogen spurt and predict appropriate timing for onset of the laser pulse.

  15. Intraseasonal to interannual variability of Kelvin wave momentum fluxes as derived from high-resolution radiosonde data

    DOE PAGES

    Sjoberg, Jeremiah P.; Birner, Thomas; Johnson, Richard H.

    2017-07-26

    Observational estimates of Kelvin wave momentum fluxes in the tropical lower stratosphere remain challenging. Here we extend a method based on linear wave theory to estimate daily time series of these momentum fluxes from high-resolution radiosonde data. Daily time series are produced for sounding sites operated by the US Department of Energy (DOE) and from the recent Dynamics of the Madden–Julian Oscillation (DYNAMO) field campaign. Our momentum flux estimates are found to be robust to different data sources and processing and in quantitative agreement with estimates from prior studies. Testing the sensitivity to vertical resolution, our estimated momentum fluxes aremore » found to be most sensitive to vertical resolution greater than 1 km, largely due to overestimation of the vertical wavelength. Climatological analysis is performed over a selected 11-year span of data from DOE Atmospheric Radiation Measurement (ARM) radiosonde sites. Analyses of this 11-year span of data reveal the expected seasonal cycle of momentum flux maxima in boreal winter and minima in boreal summer, and variability associated with the quasi-biennial oscillation of maxima during easterly phase and minima during westerly phase. Comparison between periods with active convection that is either strongly or weakly associated with the Madden–Julian Oscillation (MJO) suggests that the MJO provides a nontrivial increase in the lowermost stratospheric momentum fluxes.« less

  16. A case study of carbon fluxes from land change in the southwest Brazilian Amazon

    USGS Publications Warehouse

    Barrett, K.; Rogan, J.; Eastman, J.R.

    2009-01-01

    Worldwide, land change is responsible for one-fifth of anthropogenic carbon emissions. In Brazil, three-quarters of carbon emissions originate from land change. This study represents a municipal-scale study of carbon fluxes from vegetation in Rio Branco, Brazil. Land-cover maps of pasture, forest, and secondary growth from 1993, 1996, 1999, and 2003 were produced using an unsupervised classification method (overall accuracy = 89%). Carbon fluxes from land change over the decade of imagery were estimated from transitions between land-cover categories for each time interval. This article presents new methods for estimating emissions reductions from carbon stored in the vegetation that replaces forests (e.g., pasture) and sequestration by new (>10-15 years) forests, which reduced gross emissions by 16, 15, and 22% for the period of 1993-1996, 1996-1999, and 1999-2003, respectively. The methods used in the analysis are broadly applicable and provide a comprehensive characterization of regional-scale carbon fluxes from land change.

  17. Quantifying fluxes and characterizing compositional changes of dissolved organic matter in aquatic systems in situ using combined acoustic and optical measurements

    USGS Publications Warehouse

    Downing, B.D.; Boss, E.; Bergamaschi, B.A.; Fleck, J.A.; Lionberger, M.A.; Ganju, N.K.; Schoellhamer, D.H.; Fujii, R.

    2009-01-01

    Studying the dynamics and geochemical behavior of dissolved and particulate organic material is difficult because concentration and composition may rapidly change in response to aperiodic as well as periodic physical and biological forcing. Here we describe a method useful for quantifying fluxes and analyzing dissolved organic matter (DOM) dynamics. The method uses coupled optical and acoustic measurements that provide robust quantitative estimates of concentrations and constituent characteristics needed to investigate processes and calculate fluxes of DOM in tidal and other lotic environments. Data were collected several times per hour for 2 weeks or more, with the frequency and duration limited only by power consumption and data storage capacity. We assessed the capabilities and limitations of the method using data from a winter deployment in a natural tidal wetland of the San Francisco Bay estuary. We used statistical correlation of in situ optical data with traditional laboratory analyses of discrete water samples to calibrate optical properties suited as proxies for DOM concentrations and characterizations. Coupled with measurements of flow velocity, we calculated long-term residual horizontal fluxes of DOC into and out from a tidal wetland. Subsampling the dataset provides an estimate for the maximum sampling interval beyond which the error in flux estimate is significantly increased.?? 2009, by the American Society of Limnology and Oceanography, Inc.

  18. Evaporation estimation of rift valley lakes: comparison of models.

    PubMed

    Melesse, Assefa M; Abtew, Wossenu; Dessalegne, Tibebe

    2009-01-01

    Evapotranspiration (ET) accounts for a substantial amount of the water flux in the arid and semi-arid regions of the World. Accurate estimation of ET has been a challenge for hydrologists, mainly because of the spatiotemporal variability of the environmental and physical parameters governing the latent heat flux. In addition, most available ET models depend on intensive meteorological information for ET estimation. Such data are not available at the desired spatial and temporal scales in less developed and remote parts of the world. This limitation has necessitated the development of simple models that are less data intensive and provide ET estimates with acceptable level of accuracy. Remote sensing approach can also be applied to large areas where meteorological data are not available and field scale data collection is costly, time consuming and difficult. In areas like the Rift Valley regions of Ethiopia, the applicability of the Simple Method (Abtew Method) of lake evaporation estimation and surface energy balance approach using remote sensing was studied. The Simple Method and a remote sensing-based lake evaporation estimates were compared to the Penman, Energy balance, Pan, Radiation and Complementary Relationship Lake Evaporation (CRLE) methods applied in the region. Results indicate a good correspondence of the models outputs to that of the above methods. Comparison of the 1986 and 2000 monthly lake ET from the Landsat images to the Simple and Penman Methods show that the remote sensing and surface energy balance approach is promising for large scale applications to understand the spatial variation of the latent heat flux.

  19. BACTERIAL FLUX FROM CHAPARRAL INTO THE ATMOSPHERE IN MID-SUMMER AT A HIGH DESERT LOCATION

    EPA Science Inventory

    Estimates of the bacterial flux for a daylight cycle were observed at the Hanford Nuclear Reservation, Richland, WA, during June 1992, using a modified Bowen ratio method. he upward daytime bacterial flux was coupled with the solar radiation/sensible heat cycle, but commenced 2 h...

  20. Estimates of surface humidity and latent heat fluxes over oceans from SSM/I data

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cho, S.H.; Atlas, R.M.; Shie, C.L.

    1995-08-01

    Monthly averages of daily latent heat fluxes over the oceans for February and August 1988 are estimated using a stability-dependent bulk scheme. Daily fluxes are computed from daily SSM/I (Special Sensor Microwave/Imager) wind speeds and EOF-retrieved SSM/I surface humidity, National Meteorological Center sea surface temperatures, and the European Centre for Medium-Range Weather Forecasts analyzed 2-m temperatures. Daily surface specific humidity (Q) is estimated from SSM/I precipitable water of total (W) and a 500-m bottom layer (W{sub B}) using an EOF (empirical orthogonal function) method. This method has six W-based categories of EOFs (independent of geographical locations) and is developed usingmore » 23 177 FGGE IIb humidity soundings over the global oceans. For 1200 FGGE IIb humidity soundings, the accuracy of EOF-retrieved Q is 0.75 g kg{sup -1} for the case without errors in W and W{sub B} and increases to 1.16 g kg{sup -1} for the case with errors in W and W{sub B}. Compared to 342 collocated radiosonde observations, the EOF-retrieved SSM/I Q has an accuracy of 1.7 g kg{sup -1}. The method improves upon the humidity retrieval of Liu and is competitive with that of Schulz et al. The SSM/I surface humidity and latent heat fluxes of these two months agree reasonably well with those of COADS (Comprehensive Ocean-Atmosphere Data Set). Compared to the COADS, the sea-air humidity difference of SSM/I has a positive bias of approximately 1-3 g kg{sup -1} (an overestimation of flux) over the wintertime eastern equatorial Pacific Ocean, it has a negative bias of about 1-2 g kg{sup -1} (an underestimation of flux). The results further suggest that the two monthly flux estimates, computed from daily and monthly mean data, do not differ significantly over the oceans. 35 refs., 12 figs., 4 tabs.« less

  1. Using dynamic flux chambers to estimate the natural attenuation rates in the subsurface at petroleum contaminated sites.

    PubMed

    Verginelli, Iason; Pecoraro, Roberto; Baciocchi, Renato

    2018-04-01

    In this work, we introduce a screening method for the evaluation of the natural attenuation rates in the subsurface at sites contaminated by petroleum hydrocarbons. The method is based on the combination of the data obtained from standard source characterization with dynamic flux chambers measurements. The natural attenuation rates are calculated as difference between the flux of contaminants estimated with a non-reactive diffusive model starting from the concentrations of the contaminants detected in the source (soil and/or groundwater) and the effective emission rate of the contaminants measured using dynamic flux chambers installed at ground level. The reliability of this approach was tested in a contaminated site characterized by the presence of BTEX in soil and groundwater. Namely, the BTEX emission rates from the subsurface were measured in 4 seasonal campaigns using dynamic flux chambers installed in 14 sampling points. The comparison of measured fluxes with those predicted using a non-reactive diffusive model, starting from the source concentrations, showed that, in line with other recent studies, the modelling approach can overestimate the expected outdoor concentration of petroleum hydrocarbons even up to 4 orders of magnitude. On the other hand, by coupling the measured data with the fluxes estimated with the diffusive non-reactive model, it was possible to perform a mass balance to evaluate the natural attenuation loss rates of petroleum hydrocarbons during the migration from the source to ground level. Based on this comparison, the estimated BTEX loss rates in the test site were up to almost 0.5kg/year/m 2 . These rates are in line with the values reported in the recent literature for natural source zone depletion. In short, the method presented in this work can represent an easy-to-use and cost-effective option that can provide a further line of evidence of natural attenuation rates expected at contaminated sites. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. The advantages, and challenges, in using multiple techniques in the estimation of surface water-groundwater fluxes.

    NASA Astrophysics Data System (ADS)

    Shanafield, M.; Cook, P. G.

    2014-12-01

    When estimating surface water-groundwater fluxes, the use of complimentary techniques helps to fill in uncertainties in any individual method, and to potentially gain a better understanding of spatial and temporal variability in a system. It can also be a way of preventing the loss of data during infrequent and unpredictable flow events. For example, much of arid Australia relies on groundwater, which is recharged by streamflow through ephemeral streams during flood events. Three recent surface water/groundwater investigations from arid Australian systems provide good examples of how using multiple field and analysis techniques can help to more fully characterize surface water-groundwater fluxes, but can also result in conflicting values over varying spatial and temporal scales. In the Pilbara region of Western Australia, combining streambed radon measurements, vertical heat transport modeling, and a tracer test helped constrain very low streambed residence times, which are on the order of minutes. Spatial and temporal variability between the methods yielded hyporheic exchange estimates between 10-4 m2 s-1 and 4.2 x 10-2 m2 s-1. In South Australia, three-dimensional heat transport modeling captured heterogeneity within 20 square meters of streambed, identifying areas of sandy soil (flux rates of up to 3 m d-1) and clay (flux rates too slow to be accurately characterized). Streamflow front modeling showed similar flux rates, but averaged over 100 m long stream segments for a 1.6 km reach. Finally, in central Australia, several methods are used to decipher whether any of the flow down a highly ephemeral river contributes to regional groundwater recharge, showing that evaporation and evapotranspiration likely accounts for all of the infiltration into the perched aquifer. Lessons learned from these examples demonstrate the influences of the spatial and temporal variability between techniques on estimated fluxes.

  3. Heat flux estimates over vegetation derived using radiometric surface temperatures and a boundary layer model in comparison with sodar-derived values. M.S. Thesis; [Rock Springs Agricultural Research Center, Pennsylvania

    NASA Technical Reports Server (NTRS)

    Cooper, J. N. (Principal Investigator)

    1981-01-01

    An attempt was made to validate a method that uses radiometric surface temperatures and a boundary layer model to estimate surface energy budgets and characteristics. Surface temperatures from a hand-held radiometer and sodar data were collected simultaneously on seven days between mid-July and mid-October 1980. The comparison of the RDMS and sodar heat fluxes proved disappointing. Free convection conditions, required to produce sodar-derived heat fluxes, were inhibited by a terrain-induced low level inversion. Only three out of seven cases produced meaningful sodar heat fluxes. Of those three cases, one had good agreement and the other two had sodar heat fluxes 15 to 45 w/sq m lower than the RDMS values. Since the RDMS method is relatively untested, it was impossible to conclusively determine its validity from the results. There was evidence that the true heat flux was not underestimated by the RDMS, so it could be concluded that the Bowen ratios over well-watered vegetation were likely to be quite small.

  4. Estimating mean long-term hydrologic budget components for watersheds and counties: An application to the commonwealth of Virginia, USA

    USGS Publications Warehouse

    Sanford, Ward E.; Nelms, David L.; Pope, Jason P.; Selnick, David L.

    2015-01-01

    Mean long-term hydrologic budget components, such as recharge and base flow, are often difficult to estimate because they can vary substantially in space and time. Mean long-term fluxes were calculated in this study for precipitation, surface runoff, infiltration, total evapotranspiration (ET), riparian ET, recharge, base flow (or groundwater discharge) and net total outflow using long-term estimates of mean ET and precipitation and the assumption that the relative change in storage over that 30-year period is small compared to the total ET or precipitation. Fluxes of these components were first estimated on a number of real-time-gaged watersheds across Virginia. Specific conductance was used to distinguish and separate surface runoff from base flow. Specific-conductance (SC) data were collected every 15 minutes at 75 real-time gages for approximately 18 months between March 2007 and August 2008. Precipitation was estimated for 1971-2000 using PRISM climate data. Precipitation and temperature from the PRISM data were used to develop a regression-based relation to estimate total ET. The proportion of watershed precipitation that becomes surface runoff was related to physiographic province and rock type in a runoff regression equation. A new approach to estimate riparian ET using seasonal SC data gave results consistent with those from other methods. Component flux estimates from the watersheds were transferred to flux estimates for counties and independent cities using the ET and runoff regression equations. Only 48 of the 75 watersheds yielded sufficient data, and data from these 48 were used in the final runoff regression equation. Final results for the study are presented as component flux estimates for all counties and independent cities in Virginia. The method has the potential to be applied in many other states in the U.S. or in other regions or countries of the world where climate and stream flow data are plentiful.

  5. SUMOFLUX: A Generalized Method for Targeted 13C Metabolic Flux Ratio Analysis

    PubMed Central

    Kogadeeva, Maria

    2016-01-01

    Metabolic fluxes are a cornerstone of cellular physiology that emerge from a complex interplay of enzymes, carriers, and nutrients. The experimental assessment of in vivo intracellular fluxes using stable isotopic tracers is essential if we are to understand metabolic function and regulation. Flux estimation based on 13C or 2H labeling relies on complex simulation and iterative fitting; processes that necessitate a level of expertise that ordinarily preclude the non-expert user. To overcome this, we have developed SUMOFLUX, a methodology that is broadly applicable to the targeted analysis of 13C-metabolic fluxes. By combining surrogate modeling and machine learning, we trained a predictor to specialize in estimating flux ratios from measurable 13C-data. SUMOFLUX targets specific flux features individually, which makes it fast, user-friendly, applicable to experimental design and robust in terms of experimental noise and exchange flux magnitude. Collectively, we predict that SUMOFLUX's properties realistically pave the way to high-throughput flux analyses. PMID:27626798

  6. Groundwater flux estimation in streams: A thermal equilibrium approach

    USGS Publications Warehouse

    Zhou, Yan; Fox, Garey A.; Miller, Ron B.; Mollenhauer, Robert; Brewer, Shannon K.

    2018-01-01

    Stream and groundwater interactions play an essential role in regulating flow, temperature, and water quality for stream ecosystems. Temperature gradients have been used to quantify vertical water movement in the streambed since the 1960s, but advancements in thermal methods are still possible. Seepage runs are a method commonly used to quantify exchange rates through a series of streamflow measurements but can be labor and time intensive. The objective of this study was to develop and evaluate a thermal equilibrium method as a technique for quantifying groundwater flux using monitored stream water temperature at a single point and readily available hydrological and atmospheric data. Our primary assumption was that stream water temperature at the monitored point was at thermal equilibrium with the combination of all heat transfer processes, including mixing with groundwater. By expanding the monitored stream point into a hypothetical, horizontal one-dimensional thermal modeling domain, we were able to simulate the thermal equilibrium achieved with known atmospheric variables at the point and quantify unknown groundwater flux by calibrating the model to the resulting temperature signature. Stream water temperatures were monitored at single points at nine streams in the Ozark Highland ecoregion and five reaches of the Kiamichi River to estimate groundwater fluxes using the thermal equilibrium method. When validated by comparison with seepage runs performed at the same time and reach, estimates from the two methods agreed with each other with an R2 of 0.94, a root mean squared error (RMSE) of 0.08 (m/d) and a Nash–Sutcliffe efficiency (NSE) of 0.93. In conclusion, the thermal equilibrium method was a suitable technique for quantifying groundwater flux with minimal cost and simple field installation given that suitable atmospheric and hydrological data were readily available.

  7. Groundwater flux estimation in streams: A thermal equilibrium approach

    NASA Astrophysics Data System (ADS)

    Zhou, Yan; Fox, Garey A.; Miller, Ron B.; Mollenhauer, Robert; Brewer, Shannon

    2018-06-01

    Stream and groundwater interactions play an essential role in regulating flow, temperature, and water quality for stream ecosystems. Temperature gradients have been used to quantify vertical water movement in the streambed since the 1960s, but advancements in thermal methods are still possible. Seepage runs are a method commonly used to quantify exchange rates through a series of streamflow measurements but can be labor and time intensive. The objective of this study was to develop and evaluate a thermal equilibrium method as a technique for quantifying groundwater flux using monitored stream water temperature at a single point and readily available hydrological and atmospheric data. Our primary assumption was that stream water temperature at the monitored point was at thermal equilibrium with the combination of all heat transfer processes, including mixing with groundwater. By expanding the monitored stream point into a hypothetical, horizontal one-dimensional thermal modeling domain, we were able to simulate the thermal equilibrium achieved with known atmospheric variables at the point and quantify unknown groundwater flux by calibrating the model to the resulting temperature signature. Stream water temperatures were monitored at single points at nine streams in the Ozark Highland ecoregion and five reaches of the Kiamichi River to estimate groundwater fluxes using the thermal equilibrium method. When validated by comparison with seepage runs performed at the same time and reach, estimates from the two methods agreed with each other with an R2 of 0.94, a root mean squared error (RMSE) of 0.08 (m/d) and a Nash-Sutcliffe efficiency (NSE) of 0.93. In conclusion, the thermal equilibrium method was a suitable technique for quantifying groundwater flux with minimal cost and simple field installation given that suitable atmospheric and hydrological data were readily available.

  8. Instrumentation, methods, and preliminary evaluation of evapotranspiration for a grassland in the Arid Lands Ecology Reserve, Benton County, Washington, May-October 1990

    USGS Publications Warehouse

    Tomlinson, S.A.

    1994-01-01

    The report describes instrumentation, methods, and preliminary results for a study on evapo- transpiration at a grassland in Snively Basin of the Arid Lands Ecology Reserve. Instrumentation was used to collect data from May 30 to October 15, 1990. A combination of the Bowen-ratio and Penman-Monteith methods was used to calculate estimates of evapotranspiration. The Bowen-ratio method could be used to calculate estimates of latent-heat flux and evapotranspiration during only parts of the study period. Latent-heat flux values obtained during these periods were used in the Penman-Monteith method to estimate the canopy resistance. These canopy resistances were averaged for each day and the average values were used to recalculate the laten-heat flux for all periods using the Penman-Monteith method. The canopy resistance ranged from near zero during periods of rainfall to more than 40,000 seconds per meter during periods of extreme dryness. Evapotranspiration estimates varied during the study period. Daily evapotranspiration ranged from less than 0.1 millimeter on some days in August, September, and October to about 2 milli- meters on June 3 and August 22. Monthly totals of evapotranspiration were as follows: June, 28.2 millimeters; July, 10.5 millimeters; August, 15.0 millimeters; September, 5.3 millimeters; and October 1-15, 1.8 millimeters. Evapotranspiration values given in the report are estimates. Some error, perhaps as low as 25 percent on a daily basis and 4 percent on a monthly total basis, is probably introduced into these estimates through complexities of data collection, data analysis, and canopy-resistance estimation, particularly when evapotranspiration was near zero.

  9. Area-averaged evapotranspiration over a heterogeneous land surface: aggregation of multi-point EC flux measurements with a high-resolution land-cover map and footprint analysis

    NASA Astrophysics Data System (ADS)

    Xu, Feinan; Wang, Weizhen; Wang, Jiemin; Xu, Ziwei; Qi, Yuan; Wu, Yueru

    2017-08-01

    The determination of area-averaged evapotranspiration (ET) at the satellite pixel scale/model grid scale over a heterogeneous land surface plays a significant role in developing and improving the parameterization schemes of the remote sensing based ET estimation models and general hydro-meteorological models. The Heihe Watershed Allied Telemetry Experimental Research (HiWATER) flux matrix provided a unique opportunity to build an aggregation scheme for area-averaged fluxes. On the basis of the HiWATER flux matrix dataset and high-resolution land-cover map, this study focused on estimating the area-averaged ET over a heterogeneous landscape with footprint analysis and multivariate regression. The procedure is as follows. Firstly, quality control and uncertainty estimation for the data of the flux matrix, including 17 eddy-covariance (EC) sites and four groups of large-aperture scintillometers (LASs), were carefully done. Secondly, the representativeness of each EC site was quantitatively evaluated; footprint analysis was also performed for each LAS path. Thirdly, based on the high-resolution land-cover map derived from aircraft remote sensing, a flux aggregation method was established combining footprint analysis and multiple-linear regression. Then, the area-averaged sensible heat fluxes obtained from the EC flux matrix were validated by the LAS measurements. Finally, the area-averaged ET of the kernel experimental area of HiWATER was estimated. Compared with the formerly used and rather simple approaches, such as the arithmetic average and area-weighted methods, the present scheme is not only with a much better database, but also has a solid grounding in physics and mathematics in the integration of area-averaged fluxes over a heterogeneous surface. Results from this study, both instantaneous and daily ET at the satellite pixel scale, can be used for the validation of relevant remote sensing models and land surface process models. Furthermore, this work will be extended to the water balance study of the whole Heihe River basin.

  10. A review of models and micrometeorological methods used to estimate wetland evapotranspiration

    USGS Publications Warehouse

    Drexler, J.Z.; Snyder, R.L.; Spano, D.; Paw, U.K.T.

    2004-01-01

    Within the past decade or so, the accuracy of evapotranspiration (ET) estimates has improved due to new and increasingly sophisticated methods. Yet despite a plethora of choices concerning methods, estimation of wetland ET remains insufficiently characterized due to the complexity of surface characteristics and the diversity of wetland types. In this review, we present models and micrometeorological methods that have been used to estimate wetland ET and discuss their suitability for particular wetland types. Hydrological, soil monitoring and lysimetric methods to determine ET are not discussed. Our review shows that, due to the variability and complexity of wetlands, there is no single approach that is the best for estimating wetland ET. Furthermore, there is no single foolproof method to obtain an accurate, independent measure of wetland ET. Because all of the methods reviewed, with the exception of eddy covariance and LIDAR, require measurements of net radiation (Rn) and soil heat flux (G), highly accurate measurements of these energy components are key to improving measurements of wetland ET. Many of the major methods used to determine ET can be applied successfully to wetlands of uniform vegetation and adequate fetch, however, certain caveats apply. For example, with accurate Rn and G data and small Bowen ratio (??) values, the Bowen ratio energy balance method can give accurate estimates of wetland ET. However, large errors in latent heat flux density can occur near sunrise and sunset when the Bowen ratio ?? ??? - 1??0. The eddy covariance method provides a direct measurement of latent heat flux density (??E) and sensible heat flux density (II), yet this method requires considerable expertise and expensive instrumentation to implement. A clear advantage of using the eddy covariance method is that ??E can be compared with Rn-G H, thereby allowing for an independent test of accuracy. The surface renewal method is inexpensive to replicate and, therefore, shows particular promise for characterizing variability in ET as a result of spatial heterogeneity. LIDAR is another method that has special utility in a heterogeneous wetland environment, because it provides an integrated value for ET from a surface. The main drawback of LIDAR is the high cost of equipment and the need for an independent ET measure to assess accuracy. If Rn and G are measured accurately, the Priestley-Taylor equation can be used successfully with site-specific calibration factors to estimate wetland ET. The 'crop' cover coefficient (Kc) method can provide accurate wetland ET estimates if calibrated for the environmental and climatic characteristics of a particular area. More complicated equations such as the Penman and Penman-Monteith equations also can be used to estimate wetland ET, but surface variability and lack of information on aerodynamic and surface resistances make use of such equations somewhat questionable. ?? 2004 John Wiley and Sons, Ltd.

  11. Estimation of electrical conductivity distribution within the human head from magnetic flux density measurement.

    PubMed

    Gao, Nuo; Zhu, S A; He, Bin

    2005-06-07

    We have developed a new algorithm for magnetic resonance electrical impedance tomography (MREIT), which uses only one component of the magnetic flux density to reconstruct the electrical conductivity distribution within the body. The radial basis function (RBF) network and simplex method are used in the present approach to estimate the conductivity distribution by minimizing the errors between the 'measured' and model-predicted magnetic flux densities. Computer simulations were conducted in a realistic-geometry head model to test the feasibility of the proposed approach. Single-variable and three-variable simulations were performed to estimate the brain-skull conductivity ratio and the conductivity values of the brain, skull and scalp layers. When SNR = 15 for magnetic flux density measurements with the target skull-to-brain conductivity ratio being 1/15, the relative error (RE) between the target and estimated conductivity was 0.0737 +/- 0.0746 in the single-variable simulations. In the three-variable simulations, the RE was 0.1676 +/- 0.0317. Effects of electrode position uncertainty were also assessed by computer simulations. The present promising results suggest the feasibility of estimating important conductivity values within the head from noninvasive magnetic flux density measurements.

  12. Estimation of evaporation and sensible heat flux from open water using a large-aperture scintillometer

    NASA Astrophysics Data System (ADS)

    McJannet, D. L.; Cook, F. J.; McGloin, R. P.; McGowan, H. A.; Burn, S.

    2011-05-01

    The use of scintillometers to determine sensible and latent heat flux is becoming increasingly common because of their ability to quantify convective fluxes over distances of hundreds of meters to several kilometers. The majority of investigations using scintillometry have focused on processes above land surfaces, but here we propose a new methodology for obtaining sensible and latent heat fluxes from a scintillometer deployed over open water. This methodology has been tested by comparison with eddy covariance measurements and through comparison with alternative scintillometer calculation approaches that are commonly used in the literature. The methodology is based on linearization of the Bowen ratio, which is a common assumption in models such as Penman's model and its derivatives. Comparison of latent heat flux estimates from the eddy covariance system and the scintillometer showed excellent agreement across a range of weather conditions and flux rates, giving a high level of confidence in scintillometry-derived latent heat fluxes. The proposed approach produced better estimates than other scintillometry calculation methods because of the reliance of alternative methods on measurements of water temperature or water body heat storage, which are both notoriously hard to quantify. The proposed methodology requires less instrumentation than alternative scintillometer calculation approaches, and the spatial scales of required measurements are arguably more compatible. In addition to scintillometer measurements of the structure parameter of the refractive index of air, the only measurements required are atmospheric pressure, air temperature, humidity, and wind speed at one height over the water body.

  13. A comparison of methods for deriving solute flux rates using long-term data from streams in the mirror lake watershed

    USGS Publications Warehouse

    Bukaveckas, P.A.; Likens, G.E.; Winter, T.C.; Buso, D.C.

    1998-01-01

    Calculation of chemical flux rates for streams requires integration of continuous measurements of discharge with discrete measurements of solute concentrations. We compared two commonly used methods for interpolating chemistry data (time-averaging and flow-weighting) to determine whether discrepancies between the two methods were large relative to other sources of error in estimating flux rates. Flux rates of dissolved Si and SO42- were calculated from 10 years of data (1981-1990) for the NW inlet and Outlet of Mirror Lake and for a 40-day period (March 22 to April 30, 1993) during which we augmented our routine (weekly) chemical monitoring with collection of daily samples. The time-averaging method yielded higher estimates of solute flux during high-flow periods if no chemistry samples were collected corresponding to peak discharge. Concentration-discharge relationships should be used to interpolate stream chemistry during changing flow conditions if chemical changes are large. Caution should be used in choosing the appropriate time-scale over which data are pooled to derive the concentration-discharge regressions because the model parameters (slope and intercept) were found to be sensitive to seasonal and inter-annual variation. Both methods approximated solute flux to within 2-10% for a range of solutes that were monitored during the intensive sampling period. Our results suggest that errors arising from interpolation of stream chemistry data are small compared with other sources of error in developing watershed mass balances.

  14. An investigation of the marine boundary layer during cold air outbreak

    NASA Technical Reports Server (NTRS)

    Stage, S. A.

    1986-01-01

    Methods for use in the remote estimation of ocean surface sensible and latent heat fluxes were developed and evaluated. Three different techniques were developed for determining these fluxes. These methods are: (1) Obtaining surface sensible and latent heat fluxes from satellite measurements; (2)Obtaining surface sensible and latent heat fluxes from an MABL model; (3) A method using horizontal transfer coefficients. These techniques are not very sensitive to errors in the data and therefore appear to hold promise of producing useful answers. Questions remain about how closely the structure of the real atmosphere agrees with the assumptions made for each of these techniques, and, therefore about how well these techniques can perform in actual use. The value of these techniques is that they promise to provide methods for the determination of fluxes over regions where very few traditional measurement exist.

  15. Characterizability of metabolic pathway systems from time series data.

    PubMed

    Voit, Eberhard O

    2013-12-01

    Over the past decade, the biomathematical community has devoted substantial effort to the complicated challenge of estimating parameter values for biological systems models. An even more difficult issue is the characterization of functional forms for the processes that govern these systems. Most parameter estimation approaches tacitly assume that these forms are known or can be assumed with some validity. However, this assumption is not always true. The recently proposed method of Dynamic Flux Estimation (DFE) addresses this problem in a genuinely novel fashion for metabolic pathway systems. Specifically, DFE allows the characterization of fluxes within such systems through an analysis of metabolic time series data. Its main drawback is the fact that DFE can only directly be applied if the pathway system contains as many metabolites as unknown fluxes. This situation is unfortunately rare. To overcome this roadblock, earlier work in this field had proposed strategies for augmenting the set of unknown fluxes with independent kinetic information, which however is not always available. Employing Moore-Penrose pseudo-inverse methods of linear algebra, the present article discusses an approach for characterizing fluxes from metabolic time series data that is applicable even if the pathway system is underdetermined and contains more fluxes than metabolites. Intriguingly, this approach is independent of a specific modeling framework and unaffected by noise in the experimental time series data. The results reveal whether any fluxes may be characterized and, if so, which subset is characterizable. They also help with the identification of fluxes that, if they could be determined independently, would allow the application of DFE. Copyright © 2013 Elsevier Inc. All rights reserved.

  16. Characterizability of Metabolic Pathway Systems from Time Series Data

    PubMed Central

    Voit, Eberhard O.

    2013-01-01

    Over the past decade, the biomathematical community has devoted substantial effort to the complicated challenge of estimating parameter values for biological systems models. An even more difficult issue is the characterization of functional forms for the processes that govern these systems. Most parameter estimation approaches tacitly assume that these forms are known or can be assumed with some validity. However, this assumption is not always true. The recently proposed method of Dynamic Flux Estimation (DFE) addresses this problem in a genuinely novel fashion for metabolic pathway systems. Specifically, DFE allows the characterization of fluxes within such systems through an analysis of metabolic time series data. Its main drawback is the fact that DFE can only directly be applied if the pathway system contains as many metabolites as unknown fluxes. This situation is unfortunately rare. To overcome this roadblock, earlier work in this field had proposed strategies for augmenting the set of unknown fluxes with independent kinetic information, which however is not always available. Employing Moore-Penrose pseudo-inverse methods of linear algebra, the present article discusses an approach for characterizing fluxes from metabolic time series data that is applicable even if the pathway system is underdetermined and contains more fluxes than metabolites. Intriguingly, this approach is independent of a specific modeling framework and unaffected by noise in the experimental time series data. The results reveal whether any fluxes may be characterized and, if so, which subset is characterizable. They also help with the identification of fluxes that, if they could be determined independently, would allow the application of DFE. PMID:23391489

  17. CO2 flux determination by closed-chamber methods can be seriously biased by inappropriate application of linear regression

    NASA Astrophysics Data System (ADS)

    Kutzbach, L.; Schneider, J.; Sachs, T.; Giebels, M.; Nykänen, H.; Shurpali, N. J.; Martikainen, P. J.; Alm, J.; Wilmking, M.

    2007-07-01

    Closed (non-steady state) chambers are widely used for quantifying carbon dioxide (CO2) fluxes between soils or low-stature canopies and the atmosphere. It is well recognised that covering a soil or vegetation by a closed chamber inherently disturbs the natural CO2 fluxes by altering the concentration gradients between the soil, the vegetation and the overlying air. Thus, the driving factors of CO2 fluxes are not constant during the closed chamber experiment, and no linear increase or decrease of CO2 concentration over time within the chamber headspace can be expected. Nevertheless, linear regression has been applied for calculating CO2 fluxes in many recent, partly influential, studies. This approach was justified by keeping the closure time short and assuming the concentration change over time to be in the linear range. Here, we test if the application of linear regression is really appropriate for estimating CO2 fluxes using closed chambers over short closure times and if the application of nonlinear regression is necessary. We developed a nonlinear exponential regression model from diffusion and photosynthesis theory. This exponential model was tested with four different datasets of CO2 flux measurements (total number: 1764) conducted at three peatland sites in Finland and a tundra site in Siberia. The flux measurements were performed using transparent chambers on vegetated surfaces and opaque chambers on bare peat surfaces. Thorough analyses of residuals demonstrated that linear regression was frequently not appropriate for the determination of CO2 fluxes by closed-chamber methods, even if closure times were kept short. The developed exponential model was well suited for nonlinear regression of the concentration over time c(t) evolution in the chamber headspace and estimation of the initial CO2 fluxes at closure time for the majority of experiments. CO2 flux estimates by linear regression can be as low as 40% of the flux estimates of exponential regression for closure times of only two minutes and even lower for longer closure times. The degree of underestimation increased with increasing CO2 flux strength and is dependent on soil and vegetation conditions which can disturb not only the quantitative but also the qualitative evaluation of CO2 flux dynamics. The underestimation effect by linear regression was observed to be different for CO2 uptake and release situations which can lead to stronger bias in the daily, seasonal and annual CO2 balances than in the individual fluxes. To avoid serious bias of CO2 flux estimates based on closed chamber experiments, we suggest further tests using published datasets and recommend the use of nonlinear regression models for future closed chamber studies.

  18. Development, evaluation and application of a modified micrometeorological gradient method for long-term estimation of gaseous dry deposition over forest canopies.

    EPA Science Inventory

    Small pollutant concentration gradients between levels above a plant canopy result in large uncertainties in estimated air–surface exchange fluxes when using existing micrometeorological gradient methods, including the aerodynamic gradient method (AGM) and the modified Bowen rati...

  19. On the applicability of surrogate-based Markov chain Monte Carlo-Bayesian inversion to the Community Land Model: Case studies at flux tower sites: SURROGATE-BASED MCMC FOR CLM

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Huang, Maoyi; Ray, Jaideep; Hou, Zhangshuan

    2016-07-04

    The Community Land Model (CLM) has been widely used in climate and Earth system modeling. Accurate estimation of model parameters is needed for reliable model simulations and predictions under current and future conditions, respectively. In our previous work, a subset of hydrological parameters has been identified to have significant impact on surface energy fluxes at selected flux tower sites based on parameter screening and sensitivity analysis, which indicate that the parameters could potentially be estimated from surface flux observations at the towers. To date, such estimates do not exist. In this paper, we assess the feasibility of applying a Bayesianmore » model calibration technique to estimate CLM parameters at selected flux tower sites under various site conditions. The parameters are estimated as a joint probability density function (PDF) that provides estimates of uncertainty of the parameters being inverted, conditional on climatologically-average latent heat fluxes derived from observations. We find that the simulated mean latent heat fluxes from CLM using the calibrated parameters are generally improved at all sites when compared to those obtained with CLM simulations using default parameter sets. Further, our calibration method also results in credibility bounds around the simulated mean fluxes which bracket the measured data. The modes (or maximum a posteriori values) and 95% credibility intervals of the site-specific posterior PDFs are tabulated as suggested parameter values for each site. Analysis of relationships between the posterior PDFs and site conditions suggests that the parameter values are likely correlated with the plant functional type, which needs to be confirmed in future studies by extending the approach to more sites.« less

  20. Sensitivity of Surface Temperature to Oceanic Forcing via q-Flux Green’s Function Experiments. Part I: Linear Response Function

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Fukai; Lu, Jian; Garuba, Oluwayemi

    This paper explores the use of linear response function (LRF) to relate the mean sea surface temperature (SST) response to prescribed ocean heat convergence (q-flux) forcings. Two methods for constructing the LRF based on the fluctuation-dissipation theorem (FDT) and Green’s function (GRF) are examined. A 900-year preindustrial simulation from the Community Earth System Model with a slab ocean (CESM-SOM) is used to estimate the LRF using FDT. For GRF, 106 pairs of CESM-SOM simulations with warm and cold q-flux patches are performed. FDT is found to have skill in estimating the SST response to a q-flux forcing when the localmore » SST response is strong, but it fails in inverse estimation of the q-flux forcing for a given SST pattern. In contrast, GRF is shown to be reasonably accurate in estimating both SST response and q-flux forcing. Possible degradation in FDT may be attributed to insufficient data sampling, significant departures of the SST data from Gaussian, and the non-normality of the constructed operator. The accurately estimated GRF-based LRF is used to (i) generate a global surface temperature sensitivity map that shows the q-flux forcing in higher latitudes to be three to four times more effective than in low latitudes in producing global surface warming; (ii) identify the most excitable SST mode (neutral vector) resembling Interdecadal Pacific Oscillation; and (iii) estimate a time-invariant q-flux forcing needed for maintaining the GHG-induced SST warming pattern. The GRF experiments will be used to construct LRF for other variables to further explore climate sensitivities and feedbacks.« less

  1. On the applicability of surrogate-based MCMC-Bayesian inversion to the Community Land Model: Case studies at Flux tower sites

    DOE PAGES

    Huang, Maoyi; Ray, Jaideep; Hou, Zhangshuan; ...

    2016-06-01

    The Community Land Model (CLM) has been widely used in climate and Earth system modeling. Accurate estimation of model parameters is needed for reliable model simulations and predictions under current and future conditions, respectively. In our previous work, a subset of hydrological parameters has been identified to have significant impact on surface energy fluxes at selected flux tower sites based on parameter screening and sensitivity analysis, which indicate that the parameters could potentially be estimated from surface flux observations at the towers. To date, such estimates do not exist. In this paper, we assess the feasibility of applying a Bayesianmore » model calibration technique to estimate CLM parameters at selected flux tower sites under various site conditions. The parameters are estimated as a joint probability density function (PDF) that provides estimates of uncertainty of the parameters being inverted, conditional on climatologically average latent heat fluxes derived from observations. We find that the simulated mean latent heat fluxes from CLM using the calibrated parameters are generally improved at all sites when compared to those obtained with CLM simulations using default parameter sets. Further, our calibration method also results in credibility bounds around the simulated mean fluxes which bracket the measured data. The modes (or maximum a posteriori values) and 95% credibility intervals of the site-specific posterior PDFs are tabulated as suggested parameter values for each site. As a result, analysis of relationships between the posterior PDFs and site conditions suggests that the parameter values are likely correlated with the plant functional type, which needs to be confirmed in future studies by extending the approach to more sites.« less

  2. On the applicability of surrogate-based MCMC-Bayesian inversion to the Community Land Model: Case studies at Flux tower sites

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Huang, Maoyi; Ray, Jaideep; Hou, Zhangshuan

    The Community Land Model (CLM) has been widely used in climate and Earth system modeling. Accurate estimation of model parameters is needed for reliable model simulations and predictions under current and future conditions, respectively. In our previous work, a subset of hydrological parameters has been identified to have significant impact on surface energy fluxes at selected flux tower sites based on parameter screening and sensitivity analysis, which indicate that the parameters could potentially be estimated from surface flux observations at the towers. To date, such estimates do not exist. In this paper, we assess the feasibility of applying a Bayesianmore » model calibration technique to estimate CLM parameters at selected flux tower sites under various site conditions. The parameters are estimated as a joint probability density function (PDF) that provides estimates of uncertainty of the parameters being inverted, conditional on climatologically average latent heat fluxes derived from observations. We find that the simulated mean latent heat fluxes from CLM using the calibrated parameters are generally improved at all sites when compared to those obtained with CLM simulations using default parameter sets. Further, our calibration method also results in credibility bounds around the simulated mean fluxes which bracket the measured data. The modes (or maximum a posteriori values) and 95% credibility intervals of the site-specific posterior PDFs are tabulated as suggested parameter values for each site. As a result, analysis of relationships between the posterior PDFs and site conditions suggests that the parameter values are likely correlated with the plant functional type, which needs to be confirmed in future studies by extending the approach to more sites.« less

  3. On the applicability of surrogate-based Markov chain Monte Carlo-Bayesian inversion to the Community Land Model: Case studies at flux tower sites

    NASA Astrophysics Data System (ADS)

    Huang, Maoyi; Ray, Jaideep; Hou, Zhangshuan; Ren, Huiying; Liu, Ying; Swiler, Laura

    2016-07-01

    The Community Land Model (CLM) has been widely used in climate and Earth system modeling. Accurate estimation of model parameters is needed for reliable model simulations and predictions under current and future conditions, respectively. In our previous work, a subset of hydrological parameters has been identified to have significant impact on surface energy fluxes at selected flux tower sites based on parameter screening and sensitivity analysis, which indicate that the parameters could potentially be estimated from surface flux observations at the towers. To date, such estimates do not exist. In this paper, we assess the feasibility of applying a Bayesian model calibration technique to estimate CLM parameters at selected flux tower sites under various site conditions. The parameters are estimated as a joint probability density function (PDF) that provides estimates of uncertainty of the parameters being inverted, conditional on climatologically average latent heat fluxes derived from observations. We find that the simulated mean latent heat fluxes from CLM using the calibrated parameters are generally improved at all sites when compared to those obtained with CLM simulations using default parameter sets. Further, our calibration method also results in credibility bounds around the simulated mean fluxes which bracket the measured data. The modes (or maximum a posteriori values) and 95% credibility intervals of the site-specific posterior PDFs are tabulated as suggested parameter values for each site. Analysis of relationships between the posterior PDFs and site conditions suggests that the parameter values are likely correlated with the plant functional type, which needs to be confirmed in future studies by extending the approach to more sites.

  4. Comparison of WindTrax and flux-gradient technique in determining PM10 emission rates from a beef cattle feedlot

    USDA-ARS?s Scientific Manuscript database

    Several emission estimation methods can be used to determine emission fluxes from ground-level area sources, including open-lot beef cattle feedlots. This research determined PM10 emission fluxes from a commercial cattle feedlot in Kansas using WindTrax, a backward Lagrangian stochastic-based atmosp...

  5. Micrometeorologic methods for measuring the post-application volatilization of pesticides

    USGS Publications Warehouse

    Majewski, M.S.

    1999-01-01

    A wide variety of micrometeorological measurement methods can be used to estimate the postapplication volatilization of pesticides from treated fields. All these estimation methods require that the entire study area have the same surficial characteristics, including the area surrounding the actual study site, and that the pesticide under investigation be applied as quickly and as uniformly as possible before any measurements are made. Methods such as aerodynamic profile, energy balance, eddy correlation, and relaxed eddy accumulation require a large (typically 1 or more hectare) study area so that the flux measurements can be made in a well developed atmospheric boundary- layer and that steady-state conditions exist. The area surrounding the study plot should have similar surficial characteristics as the study plot with sufficient upwind extent so the wind speed and temperature gradients are fully developed. Mass balance methods such as integrated horizontal flux and trajectory simulations do not require a large source area, but the area surrounding the study plot should have similar surficial characteristics. None of the micrometeorological techniques for estimating the postapplication volatilization fluxes of pesticides disturb the environment or the soil processes that influence the gas exchange from the surface to the atmosphere. They allow for continuous measurements and provide a temporally averaged flux value over a large area. If the behavior of volatilizing pesticides and the importance of the volatilization process in redistributing pesticides in the environment are to be fully understood, it is critical that we understand not only the processes that govern pesticide entry into the lower atmosphere, but also how much of the millions of kilograms of pesticides that are applied annually are introduced into, and redistributed by, the atmosphere. We also must be aware of the assumptions and limitations of the estimation techniques used, and adapt the field of pesticide volatilization flux measurements to advances in atmospheric science.

  6. Combining tracer flux ratio methodology with low-flying aircraft measurements to estimate dairy farm CH4 emissions

    NASA Astrophysics Data System (ADS)

    Daube, C.; Conley, S.; Faloona, I. C.; Yacovitch, T. I.; Roscioli, J. R.; Morris, M.; Curry, J.; Arndt, C.; Herndon, S. C.

    2017-12-01

    Livestock activity, enteric fermentation of feed and anaerobic digestion of waste, contributes significantly to the methane budget of the United States (EPA, 2016). Studies question the reported magnitude of these methane sources (Miller et. al., 2013), calling for more detailed research of agricultural animals (Hristov, 2014). Tracer flux ratio is an attractive experimental method to bring to this problem because it does not rely on estimates of atmospheric dispersion. Collection of data occurred during one week at two dairy farms in central California (June, 2016). Each farm varied in size, layout, head count, and general operation. The tracer flux ratio method involves releasing ethane on-site with a known flow rate to serve as a tracer gas. Downwind mixed enhancements in ethane (from the tracer) and methane (from the dairy) were measured, and their ratio used to infer the unknown methane emission rate from the farm. An instrumented van drove transects downwind of each farm on public roads while tracer gases were released on-site, employing the tracer flux ratio methodology to assess simultaneous methane and tracer gas plumes. Flying circles around each farm, a small instrumented aircraft made measurements to perform a mass balance evaluation of methane gas. In the course of these two different methane quantification techniques, we were able to validate yet a third method: tracer flux ratio measured via aircraft. Ground-based tracer release rates were applied to the aircraft-observed methane-to-ethane ratios, yielding whole-site methane emission rates. Never before has the tracer flux ratio method been executed with aircraft measurements. Estimates from this new application closely resemble results from the standard ground-based technique to within their respective uncertainties. Incorporating this new dimension to the tracer flux ratio methodology provides additional context for local plume dynamics and validation of both ground and flight-based data.

  7. Two methods for estimating limits to large-scale wind power generation

    PubMed Central

    Miller, Lee M.; Brunsell, Nathaniel A.; Mechem, David B.; Gans, Fabian; Monaghan, Andrew J.; Vautard, Robert; Keith, David W.; Kleidon, Axel

    2015-01-01

    Wind turbines remove kinetic energy from the atmospheric flow, which reduces wind speeds and limits generation rates of large wind farms. These interactions can be approximated using a vertical kinetic energy (VKE) flux method, which predicts that the maximum power generation potential is 26% of the instantaneous downward transport of kinetic energy using the preturbine climatology. We compare the energy flux method to the Weather Research and Forecasting (WRF) regional atmospheric model equipped with a wind turbine parameterization over a 105 km2 region in the central United States. The WRF simulations yield a maximum generation of 1.1 We⋅m−2, whereas the VKE method predicts the time series while underestimating the maximum generation rate by about 50%. Because VKE derives the generation limit from the preturbine climatology, potential changes in the vertical kinetic energy flux from the free atmosphere are not considered. Such changes are important at night when WRF estimates are about twice the VKE value because wind turbines interact with the decoupled nocturnal low-level jet in this region. Daytime estimates agree better to 20% because the wind turbines induce comparatively small changes to the downward kinetic energy flux. This combination of downward transport limits and wind speed reductions explains why large-scale wind power generation in windy regions is limited to about 1 We⋅m−2, with VKE capturing this combination in a comparatively simple way. PMID:26305925

  8. First Extended Catalogue of Galactic bubble infrared fluxes from WISE and Herschel surveys

    NASA Astrophysics Data System (ADS)

    Bufano, F.; Leto, P.; Carey, D.; Umana, G.; Buemi, C.; Ingallinera, A.; Bulpitt, A.; Cavallaro, F.; Riggi, S.; Trigilio, C.; Molinari, S.

    2018-01-01

    In this paper, we present the first extended catalogue of far-infrared fluxes of Galactic bubbles. Fluxes were estimated for 1814 bubbles, defined here as the 'golden sample', and were selected from the Milky Way Project First Data Release (Simpson et al.) The golden sample was comprised of bubbles identified within the Wide-field Infrared Survey Explorer (WISE) dataset (using 12- and 22-μm images) and Herschel data (using 70-, 160-, 250-, 350- and 500-μm wavelength images). Flux estimation was achieved initially via classical aperture photometry and then by an alternative image analysis algorithm that used active contours. The accuracy of the two methods was tested by comparing the estimated fluxes for a sample of bubbles, made up of 126 H II regions and 43 planetary nebulae, which were identified by Anderson et al. The results of this paper demonstrate that a good agreement between the two was found. This is by far the largest and most homogeneous catalogue of infrared fluxes measured for Galactic bubbles and it is a step towards the fully automated analysis of astronomical datasets.

  9. Coupling gross primary production and transpiration for a consistent estimate of canopy water use efficiency

    NASA Astrophysics Data System (ADS)

    Yebra, Marta; van Dijk, Albert

    2015-04-01

    Water use efficiency (WUE, the amount of transpiration or evapotranspiration per unit gross (GPP) or net CO2 uptake) is key in all areas of plant production and forest management applications. Therefore, mutually consistent estimates of GPP and transpiration are needed to analysed WUE without introducing any artefacts that might arise by combining independently derived GPP and ET estimates. GPP and transpiration are physiologically linked at ecosystem level by the canopy conductance (Gc). Estimates of Gc can be obtained by scaling stomatal conductance (Kelliher et al. 1995) or inferred from ecosystem level measurements of gas exchange (Baldocchi et al., 2008). To derive large-scale or indeed global estimates of Gc, satellite remote sensing based methods are needed. In a previous study, we used water vapour flux estimates derived from eddy covariance flux tower measurements at 16 Fluxnet sites world-wide to develop a method to estimate Gc using MODIS reflectance observations (Yebra et al. 2013). We combined those estimates with the Penman-Monteith combination equation to derive transpiration (T). The resulting T estimates compared favourably with flux tower estimates (R2=0.82, RMSE=29.8 W m-2). Moreover, the method allowed a single parameterisation for all land cover types, which avoids artefacts resulting from land cover classification. In subsequent research (Yebra et al, in preparation) we used the same satellite-derived Gc values within a process-based but simple canopy GPP model to constrain GPP predictions. The developed model uses a 'big-leaf' description of the plant canopy to estimate the mean GPP flux as the lesser of a conductance-limited and radiation-limited GPP rate. The conductance-limited rate was derived assuming that transport of CO2 from the bulk air to the intercellular leaf space is limited by molecular diffusion through the stomata. The radiation-limited rate was estimated assuming that it is proportional to the absorbed photosynthetically active radiation (PAR), calculated as the product of the fraction of absorbed PAR (fPAR) and PAR flux. The proposed algorithm performs well when evaluated against flux tower GPP (R2=0.79, RMSE= 1.93 µmol m2 s-1). Here we use GPP and T estimates previously derived at the same 16 Fluxnet sites to analyse WUE. Satellite-derived WUE explained variation in (long-term average) WUE among plant functional types but evergreen needleleaf had higher WUE than predicted. The benefit of our approach is that it uses mutually consistent estimates of GPP and T to derive canopy-level WUE without any land cover classification artefacts. References Baldocchi, D. (2008). Turner Review No. 15: 'Breathing' of the terrestrial biosphere: lessons learned from a global network of carbon dioxide flux measurement systems. Australian Journal of Botany, 56, 26 Kelliher, F.M., Leuning, R., Raupach, M.R., & Schulze, E.D. (1995). Maximum conductances for evaporation from global vegetation types. Agricultural and Forest Meteorology, 73, 1-16 Yebra, M., Van Dijk, A., Leuning, R., Huete, A., & Guerschman, J.P. (2013). Evaluation of optical remote sensing to estimate actual evapotranspiration and canopy conductance. Remote Sensing of Environment, 129, 250-261

  10. An early solar dynamo prediction: Cycle 23 is approximately cycle 22

    NASA Technical Reports Server (NTRS)

    Schatten, Kenneth H.; Pesnell, W. Dean

    1993-01-01

    In this paper, we briefly review the 'dynamo' and 'geomagnetic precursor' methods of long-term solar activity forecasting. These methods depend upon the most basic aspect of dynamo theory to predict future activity, future magnetic field arises directly from the magnification of pre-existing magnetic field. We then generalize the dynamo technique, allowing the method to be used at any phase of the solar cycle, through the development of the 'Solar Dynamo Amplitude' (SODA) index. This index is sensitive to the magnetic flux trapped within the Sun's convection zone but insensitive to the phase of the solar cycle. Since magnetic fields inside the Sun can become buoyant, one may think of the acronym SODA as describing the amount of buoyant flux. Using the present value of the SODA index, we estimate that the next cycle's smoothed peak activity will be about 210 +/- 30 solar flux units for the 10.7 cm radio flux and a sunspot number of 170 +/- 25. This suggests that solar cycle #23 will be large, comparable to cycle #22. The estimated peak is expected to occur near 1999.7 +/- 1 year. Since the current approach is novel (using data prior to solar minimum), these estimates may improve when the upcoming solar minimum is reached.

  11. A sparse reconstruction method for the estimation of multi-resolution emission fields via atmospheric inversion

    DOE PAGES

    Ray, J.; Lee, J.; Yadav, V.; ...

    2015-04-29

    Atmospheric inversions are frequently used to estimate fluxes of atmospheric greenhouse gases (e.g., biospheric CO 2 flux fields) at Earth's surface. These inversions typically assume that flux departures from a prior model are spatially smoothly varying, which are then modeled using a multi-variate Gaussian. When the field being estimated is spatially rough, multi-variate Gaussian models are difficult to construct and a wavelet-based field model may be more suitable. Unfortunately, such models are very high dimensional and are most conveniently used when the estimation method can simultaneously perform data-driven model simplification (removal of model parameters that cannot be reliably estimated) andmore » fitting. Such sparse reconstruction methods are typically not used in atmospheric inversions. In this work, we devise a sparse reconstruction method, and illustrate it in an idealized atmospheric inversion problem for the estimation of fossil fuel CO 2 (ffCO 2) emissions in the lower 48 states of the USA. Our new method is based on stagewise orthogonal matching pursuit (StOMP), a method used to reconstruct compressively sensed images. Our adaptations bestow three properties to the sparse reconstruction procedure which are useful in atmospheric inversions. We have modified StOMP to incorporate prior information on the emission field being estimated and to enforce non-negativity on the estimated field. Finally, though based on wavelets, our method allows for the estimation of fields in non-rectangular geometries, e.g., emission fields inside geographical and political boundaries. Our idealized inversions use a recently developed multi-resolution (i.e., wavelet-based) random field model developed for ffCO 2 emissions and synthetic observations of ffCO 2 concentrations from a limited set of measurement sites. We find that our method for limiting the estimated field within an irregularly shaped region is about a factor of 10 faster than conventional approaches. It also reduces the overall computational cost by a factor of 2. Further, the sparse reconstruction scheme imposes non-negativity without introducing strong nonlinearities, such as those introduced by employing log-transformed fields, and thus reaps the benefits of simplicity and computational speed that are characteristic of linear inverse problems.« less

  12. A sparse reconstruction method for the estimation of multi-resolution emission fields via atmospheric inversion

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ray, J.; Lee, J.; Yadav, V.

    Atmospheric inversions are frequently used to estimate fluxes of atmospheric greenhouse gases (e.g., biospheric CO 2 flux fields) at Earth's surface. These inversions typically assume that flux departures from a prior model are spatially smoothly varying, which are then modeled using a multi-variate Gaussian. When the field being estimated is spatially rough, multi-variate Gaussian models are difficult to construct and a wavelet-based field model may be more suitable. Unfortunately, such models are very high dimensional and are most conveniently used when the estimation method can simultaneously perform data-driven model simplification (removal of model parameters that cannot be reliably estimated) andmore » fitting. Such sparse reconstruction methods are typically not used in atmospheric inversions. In this work, we devise a sparse reconstruction method, and illustrate it in an idealized atmospheric inversion problem for the estimation of fossil fuel CO 2 (ffCO 2) emissions in the lower 48 states of the USA. Our new method is based on stagewise orthogonal matching pursuit (StOMP), a method used to reconstruct compressively sensed images. Our adaptations bestow three properties to the sparse reconstruction procedure which are useful in atmospheric inversions. We have modified StOMP to incorporate prior information on the emission field being estimated and to enforce non-negativity on the estimated field. Finally, though based on wavelets, our method allows for the estimation of fields in non-rectangular geometries, e.g., emission fields inside geographical and political boundaries. Our idealized inversions use a recently developed multi-resolution (i.e., wavelet-based) random field model developed for ffCO 2 emissions and synthetic observations of ffCO 2 concentrations from a limited set of measurement sites. We find that our method for limiting the estimated field within an irregularly shaped region is about a factor of 10 faster than conventional approaches. It also reduces the overall computational cost by a factor of 2. Further, the sparse reconstruction scheme imposes non-negativity without introducing strong nonlinearities, such as those introduced by employing log-transformed fields, and thus reaps the benefits of simplicity and computational speed that are characteristic of linear inverse problems.« less

  13. Diagnosing Undersampling in Monte Carlo Eigenvalue and Flux Tally Estimates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Perfetti, Christopher M; Rearden, Bradley T

    2015-01-01

    This study explored the impact of undersampling on the accuracy of tally estimates in Monte Carlo (MC) calculations. Steady-state MC simulations were performed for models of several critical systems with varying degrees of spatial and isotopic complexity, and the impact of undersampling on eigenvalue and fuel pin flux/fission estimates was examined. This study observed biases in MC eigenvalue estimates as large as several percent and biases in fuel pin flux/fission tally estimates that exceeded tens, and in some cases hundreds, of percent. This study also investigated five statistical metrics for predicting the occurrence of undersampling biases in MC simulations. Threemore » of the metrics (the Heidelberger-Welch RHW, the Geweke Z-Score, and the Gelman-Rubin diagnostics) are commonly used for diagnosing the convergence of Markov chains, and two of the methods (the Contributing Particles per Generation and Tally Entropy) are new convergence metrics developed in the course of this study. These metrics were implemented in the KENO MC code within the SCALE code system and were evaluated for their reliability at predicting the onset and magnitude of undersampling biases in MC eigenvalue and flux tally estimates in two of the critical models. Of the five methods investigated, the Heidelberger-Welch RHW, the Gelman-Rubin diagnostics, and Tally Entropy produced test metrics that correlated strongly to the size of the observed undersampling biases, indicating their potential to effectively predict the size and prevalence of undersampling biases in MC simulations.« less

  14. Energy budgets and resistances to energy transport in sparsely vegetated rangeland

    USGS Publications Warehouse

    Nichols, W.D.

    1992-01-01

    Partitioning available energy between plants and bare soil in sparsely vegetated rangelands will allow hydrologists and others to gain a greater understanding of water use by native vegetation, especially phreatophytes. Standard methods of conducting energy budget studies result in measurements of latent and sensible heat fluxes above the plant canopy which therefore include the energy fluxes from both the canopy and the soil. One-dimensional theoretical numerical models have been proposed recently for the partitioning of energy in sparse crops. Bowen ratio and other micrometeorological data collected over phreatophytes growing in areas of shallow ground water in central Nevada were used to evaluate the feasibility of using these models, which are based on surface and within-canopy aerodynamic resistances, to determine heat and water vapor transport in sparsely vegetated rangelands. The models appear to provide reasonably good estimates of sensible heat flux from the soil and latent heat flux from the canopy. Estimates of latent heat flux from the soil were less satisfactory. Sensible heat flux from the canopy was not well predicted by the present resistance formulations. Also, estimates of total above-canopy fluxes were not satisfactory when using a single value for above-canopy bulk aerodynamic resistance. ?? 1992.

  15. A Method for a Multi-Platform Approach to Generate Gridded Surface Evaporation

    NASA Astrophysics Data System (ADS)

    Badger, A.; Livneh, B.; Small, E. E.; Abolafia-Rosenzweig, R.

    2017-12-01

    Evapotranspiration is an integral component of the surface water balance. While there are many estimates of evapotranspiration, there are fewer estimates that partition evapotranspiration into evaporation and transpiration components. This study aims to generate a CONUS-scale, observationally-based soil evaporation dataset by using the time difference of surface soil moisture by Soil Moisture Active Passive (SMAP) satellite with adjustments for transpiration and a bottom flux out of the surface layer. In concert with SMAP, the Moderate-Resolution Imaging Spectroradiometer (MODIS) satellite, North American Land Data Assimilation Systems (NLDAS) and the Hydrus-1D model are used to fully analyze the surface water balance. A biome specific estimate of the total terrestrial ET is calculated through a variation of the Penman-Monteith equation with NLDAS forcing and NLDAS Noah Model output for meteorological variables. A root density restriction and SMAP-based soil moisture restriction are applied to obtain terrestrial transpiration estimates. By forcing Hydrus-1D with NLDAS meteorology and our terrestrial transpiration estimates, an estimate of the flux between the soil surface and root zone layers (qbot) will dictate the proportion of water that is available for soil evaporation. After constraining transpiration and the bottom flux from the surface layer, we estimate soil evaporation as the residual of the surface water balance. Application of this method at Fluxnet sites shows soil evaporation estimates of approximately 0­3 mm/day and less than ET estimates. Expanding this methodology to produce a gridded product for CONUS, and eventually a global-scale product, will enable a better understanding of water balance processes and contribute a dataset to validate land-surface model's surface flux processes.

  16. Challenges and benefits on long-term eddy covariance measurements over lakes

    NASA Astrophysics Data System (ADS)

    Vesala, Timo; Golub, Malgorzata; Desai, Ankur; Heiskanen, Jouni; Provenzale, Maria; Rantakari, Miitta; Ojala, Anne; Mammarella, Ivan

    2017-04-01

    Eddy Covariance (EC) data on carbon dioxide fluxes is presently available on about 30 lakes but the time series are mostly short, order of one year. Longer EC series together with chamber measurements and appropriate auxiliary data on water column allow for more accurate estimates of the aquatic component in terrestrial carbon balance and analysis of the environmental controls. We discuss on challenges for long-term EC measurements over freshwater ecosystems and demonstrate the benefits of EC data for carbon cycle studies via examples from long-term sites EC sites in Finland. We discuss on the auxiliary measurements needed and the general design of the whole measurement set-up to get representative information. We discuss on challenges related to the CO2 flux partitioning for freshwater ecosystems and introduce a new method to estimate the net primary productivity (NPP) on EC data, which is superior to more traditional methods (bottle incubations, 14C technique) with a poor temporal resolution. Finally, we collected and analyzed CO2 fluxes from 19 globally distributed lakes and reservoirs representing six climate zones. The mean flux was c. 0.3 micro mole / m2 s. We applied a simple upscaling to the direct observations and ended up to the estimate which is about half of the current emission estimate for lentic systems.

  17. Using diurnal temperature signals to infer vertical groundwater-surface water exchange

    USGS Publications Warehouse

    Irvine, Dylan J.; Briggs, Martin A.; Lautz, Laura K.; Gordon, Ryan P.; McKenzie, Jeffrey M.; Cartwright, Ian

    2017-01-01

    Heat is a powerful tracer to quantify fluid exchange between surface water and groundwater. Temperature time series can be used to estimate pore water fluid flux, and techniques can be employed to extend these estimates to produce detailed plan-view flux maps. Key advantages of heat tracing include cost-effective sensors and ease of data collection and interpretation, without the need for expensive and time-consuming laboratory analyses or induced tracers. While the collection of temperature data in saturated sediments is relatively straightforward, several factors influence the reliability of flux estimates that are based on time series analysis (diurnal signals) of recorded temperatures. Sensor resolution and deployment are particularly important in obtaining robust flux estimates in upwelling conditions. Also, processing temperature time series data involves a sequence of complex steps, including filtering temperature signals, selection of appropriate thermal parameters, and selection of the optimal analytical solution for modeling. This review provides a synthesis of heat tracing using diurnal temperature oscillations, including details on optimal sensor selection and deployment, data processing, model parameterization, and an overview of computing tools available. Recent advances in diurnal temperature methods also provide the opportunity to determine local saturated thermal diffusivity, which can improve the accuracy of fluid flux modeling and sensor spacing, which is related to streambed scour and deposition. These parameters can also be used to determine the reliability of flux estimates from the use of heat as a tracer.

  18. Data Driven Estimation of Transpiration from Net Water Fluxes: the TEA Algorithm

    NASA Astrophysics Data System (ADS)

    Nelson, J. A.; Carvalhais, N.; Cuntz, M.; Delpierre, N.; Knauer, J.; Migliavacca, M.; Ogee, J.; Reichstein, M.; Jung, M.

    2017-12-01

    The eddy covariance method, while powerful, can only provide a net accounting of ecosystem fluxes. Particularly with water cycle components, efforts to partitioning total evapotranspiration (ET) into the biotic component (transpiration, T) and the abiotic component (here evaporation, E) have seen limited success, with no one method emerging as a standard.Here we demonstrate a novel method that uses ecosystem WUE to predict transpiration in two steps: (1) a filtration step that to isolate the signal of ET for periods where E is minimized and ET is likely dominated by the signal of T; and (2) a step which predicts the WUE using meteorological variables, as well as information derived from the carbon and energy fluxes. To assess the the underlying assumptions, we tested the proposed method on three ecological models, allowing validation where the underlying carbon:water relationships, as well as the transpiration estimates, are know.The partitioning method shows high correlation (R²>0.8) between Tmodel/ET and TTEA/ET across timescales from half-hourly to annually, as well as capturing spatial variability across sites. Apart from predictive performance, we explore the sensitivities of the method to the underlying assumptions, such as the effects of residual evaporation in the training dataset. Furthermore, we show initial transpiration estimates from the algorithm at global scale, via the FLUXNET dataset.

  19. Scintillometer networks for calibration and validation of energy balance and soil moisture remote sensing algorithms

    NASA Astrophysics Data System (ADS)

    Hendrickx, Jan M. H.; Kleissl, Jan; Gómez Vélez, Jesús D.; Hong, Sung-ho; Fábrega Duque, José R.; Vega, David; Moreno Ramírez, Hernán A.; Ogden, Fred L.

    2007-04-01

    Accurate estimation of sensible and latent heat fluxes as well as soil moisture from remotely sensed satellite images poses a great challenge. Yet, it is critical to face this challenge since the estimation of spatial and temporal distributions of these parameters over large areas is impossible using only ground measurements. A major difficulty for the calibration and validation of operational remote sensing methods such as SEBAL, METRIC, and ALEXI is the ground measurement of sensible heat fluxes at a scale similar to the spatial resolution of the remote sensing image. While the spatial length scale of remote sensing images covers a range from 30 m (LandSat) to 1000 m (MODIS) direct methods to measure sensible heat fluxes such as eddy covariance (EC) only provide point measurements at a scale that may be considerably smaller than the estimate obtained from a remote sensing method. The Large Aperture scintillometer (LAS) flux footprint area is larger (up to 5000 m long) and its spatial extent better constraint than that of EC systems. Therefore, scintillometers offer the unique possibility of measuring the vertical flux of sensible heat averaged over areas comparable with several pixels of a satellite image (up to about 40 Landsat thermal pixels or about 5 MODIS thermal pixels). The objective of this paper is to present our experiences with an existing network of seven scintillometers in New Mexico and a planned network of three scintillometers in the humid tropics of Panama and Colombia.

  20. The role of global cloud climatologies in validating numerical models

    NASA Technical Reports Server (NTRS)

    HARSHVARDHAN

    1991-01-01

    Reliable estimates of the components of the surface radiation budget are important in studies of ocean-atmosphere interaction, land-atmosphere interaction, ocean circulation and in the validation of radiation schemes used in climate models. The methods currently under consideration must necessarily make certain assumptions regarding both the presence of clouds and their vertical extent. Because of the uncertainties in assumed cloudiness, all these methods involve perhaps unacceptable uncertainties. Here, a theoretical framework that avoids the explicit computation of cloud fraction and the location of cloud base in estimating the surface longwave radiation is presented. Estimates of the global surface downward fluxes and the oceanic surface net upward fluxes were made for four months (April, July, October and January) in 1985 to 1986. These estimates are based on a relationship between cloud radiative forcing at the top of the atmosphere and the surface obtained from a general circulation model. The radiation code is the version used in the UCLA/GLA general circulation model (GCM). The longwave cloud radiative forcing at the top of the atmosphere as obtained from Earth Radiation Budget Experiment (ERBE) measurements is used to compute the forcing at the surface by means of the GCM-derived relationship. This, along with clear-sky fluxes from the computations, yield maps of the downward longwave fluxes and net upward longwave fluxes at the surface. The calculated results are discussed and analyzed. The results are consistent with current meteorological knowledge and explainable on the basis of previous theoretical and observational works; therefore, it can be concluded that this method is applicable as one of the ways to obtain the surface longwave radiation fields from currently available satellite data.

  1. Using the Surface Renewal Technique to Estimate CO2 Exchange from a Rice Field to the Atmosphere

    NASA Astrophysics Data System (ADS)

    Suvocarev, K.; Reba, M. L.; Runkle, B.

    2015-12-01

    Measuring CO2 emissions as surface fluxes is crucial for climate change predictions. One major set of techniques to measure surface fluxes is through continuous micrometeorological observations over different landscapes. Recent approaches of the surface renewal method (SR) are becoming important for their capacity to independently measure sensible (H) and latent heat (LE) fluxes while avoiding some of the shortcomings of the eddy covariance method (EC). Unlike EC, SR avoids orientation limitations, leveling requirements and instrumentation separation and shadowing issues. The main advantage of SR over EC method is in its applicability in both roughness and inertial sub-layers. Therefore, SR measurements can be planned in cases where fetch requirements are not adequate for EC application. We applied the recent approach as suggested by Castellvi et al. (2008) over two months (May to July, 2015) of high-frequency data collected by EC equipment from a rice field in Arkansas. The main goal was to extend this SR application to CO2 fluxes (Fc) over agricultural fields. The results show high correlation between EC and SR fluxes (H, LE and Fc) when they are compared for all atmospheric stability conditions (R2 > 0.75). Some overestimation is observed for SR with respect to EC fluxes, similar to the findings of Castellvi et al. (2008) for rangeland grass. For all the data, SR analysis results were about 11%, 18% and 17% higher than the EC results for H, LE and Fc, respectively. These higher flux estimates resulted in better energy balance closure. The root mean square error for Fc was 6.55 μmol m-2 s-1. The observed overestimation will be addressed in the future by using additional methods for the turbulent fluxes quantification.

  2. Potential for using remote sensing to estimate carbon fluxes across northern peatlands - A review.

    PubMed

    Lees, K J; Quaife, T; Artz, R R E; Khomik, M; Clark, J M

    2018-02-15

    Peatlands store large amounts of terrestrial carbon and any changes to their carbon balance could cause large changes in the greenhouse gas (GHG) balance of the Earth's atmosphere. There is still much uncertainty about how the GHG dynamics of peatlands are affected by climate and land use change. Current field-based methods of estimating annual carbon exchange between peatlands and the atmosphere include flux chambers and eddy covariance towers. However, remote sensing has several advantages over these traditional approaches in terms of cost, spatial coverage and accessibility to remote locations. In this paper, we outline the basic principles of using remote sensing to estimate ecosystem carbon fluxes and explain the range of satellite data available for such estimations, considering the indices and models developed to make use of the data. Past studies, which have used remote sensing data in comparison with ground-based calculations of carbon fluxes over Northern peatland landscapes, are discussed, as well as the challenges of working with remote sensing on peatlands. Finally, we suggest areas in need of future work on this topic. We conclude that the application of remote sensing to models of carbon fluxes is a viable research method over Northern peatlands but further work is needed to develop more comprehensive carbon cycle models and to improve the long-term reliability of models, particularly on peatland sites undergoing restoration. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

  3. Fast Estimation of Defect Profiles from the Magnetic Flux Leakage Signal Based on a Multi-Power Affine Projection Algorithm

    PubMed Central

    Han, Wenhua; Shen, Xiaohui; Xu, Jun; Wang, Ping; Tian, Guiyun; Wu, Zhengyang

    2014-01-01

    Magnetic flux leakage (MFL) inspection is one of the most important and sensitive nondestructive testing approaches. For online MFL inspection of a long-range railway track or oil pipeline, a fast and effective defect profile estimating method based on a multi-power affine projection algorithm (MAPA) is proposed, where the depth of a sampling point is related with not only the MFL signals before it, but also the ones after it, and all of the sampling points related to one point appear as serials or multi-power. Defect profile estimation has two steps: regulating a weight vector in an MAPA filter and estimating a defect profile with the MAPA filter. Both simulation and experimental data are used to test the performance of the proposed method. The results demonstrate that the proposed method exhibits high speed while maintaining the estimated profiles clearly close to the desired ones in a noisy environment, thereby meeting the demand of accurate online inspection. PMID:25192314

  4. Fast estimation of defect profiles from the magnetic flux leakage signal based on a multi-power affine projection algorithm.

    PubMed

    Han, Wenhua; Shen, Xiaohui; Xu, Jun; Wang, Ping; Tian, Guiyun; Wu, Zhengyang

    2014-09-04

    Magnetic flux leakage (MFL) inspection is one of the most important and sensitive nondestructive testing approaches. For online MFL inspection of a long-range railway track or oil pipeline, a fast and effective defect profile estimating method based on a multi-power affine projection algorithm (MAPA) is proposed, where the depth of a sampling point is related with not only the MFL signals before it, but also the ones after it, and all of the sampling points related to one point appear as serials or multi-power. Defect profile estimation has two steps: regulating a weight vector in an MAPA filter and estimating a defect profile with the MAPA filter. Both simulation and experimental data are used to test the performance of the proposed method. The results demonstrate that the proposed method exhibits high speed while maintaining the estimated profiles clearly close to the desired ones in a noisy environment, thereby meeting the demand of accurate online inspection.

  5. Evaluating the design of an earth radiation budget instrument with system simulations. Part 2: Minimization of instantaneous sampling errors for CERES-I

    NASA Technical Reports Server (NTRS)

    Stowe, Larry; Hucek, Richard; Ardanuy, Philip; Joyce, Robert

    1994-01-01

    Much of the new record of broadband earth radiation budget satellite measurements to be obtained during the late 1990s and early twenty-first century will come from the dual-radiometer Clouds and Earth's Radiant Energy System Instrument (CERES-I) flown aboard sun-synchronous polar orbiters. Simulation studies conducted in this work for an early afternoon satellite orbit indicate that spatial root-mean-square (rms) sampling errors of instantaneous CERES-I shortwave flux estimates will range from about 8.5 to 14.0 W/m on a 2.5 deg latitude and longitude grid resolution. Rms errors in longwave flux estimates are only about 20% as large and range from 1.5 to 3.5 W/sq m. These results are based on an optimal cross-track scanner design that includes 50% footprint overlap to eliminate gaps in the top-of-the-atmosphere coverage, and a 'smallest' footprint size to increase the ratio in the number of observations lying within to the number of observations lying on grid area boundaries. Total instantaneous measurement error also depends on the variability of anisotropic reflectance and emission patterns and on retrieval methods used to generate target area fluxes. Three retrieval procedures from both CERES-I scanners (cross-track and rotating azimuth plane) are used. (1) The baseline Earth Radiaton Budget Experiment (ERBE) procedure, which assumes that errors due to the use of mean angular dependence models (ADMs) in the radiance-to-flux inversion process nearly cancel when averaged over grid areas. (2) To estimate N, instantaneous ADMs are estimated from the multiangular, collocated observations of the two scanners. These observed models replace the mean models in computation of satellite flux estimates. (3) The scene flux approach, conducts separate target-area retrievals for each ERBE scene category and combines their results using area weighting by scene type. The ERBE retrieval performs best when the simulated radiance field departs from the ERBE mean models by less than 10%. For larger perturbations, both the scene flux and collocation methods produce less error than the ERBE retrieval. The scene flux technique is preferable, however, because it involves fewer restrictive assumptions.

  6. Can we improve top-down GHG inverse methods through informed prior and better representations of atmospheric transport? Insights from the Atmospheric Carbon and Transport (ACT) - America Aircraft Mission

    NASA Astrophysics Data System (ADS)

    Feng, S.; Lauvaux, T.; Keller, K.; Davis, K. J.

    2016-12-01

    Current estimates of biogenic carbon fluxes over North America based on top-down atmospheric inversions are subject to considerable uncertainty. This uncertainty stems to a large part from the uncertain prior fluxes estimates with the associated error covariances and approximations in the atmospheric transport models that link observed carbon dioxide mixing ratios with surface fluxes. Specifically, approximations in the representation of vertical mixing associated with atmospheric turbulence or convective transport and largely under-determined prior fluxes and their error structures significantly hamper our capacity to reliably estimate regional carbon fluxes. The Atmospheric Carbon and Transport - America (ACT-America) mission aims at reducing the uncertainties in inverse fluxes at the regional-scale by deploying airborne and ground-based platforms to characterize atmospheric GHG mixing ratios and the concurrent atmospheric dynamics. Two aircraft measure the 3-dimensional distribution of greenhouse gases at synoptic scales, focusing on the atmospheric boundary layer and the free troposphere during both fair and stormy weather conditions. Here we analyze two main questions: (i) What level of information can we expect from the currently planned observations? (ii) How might ACT-America reduce the hindcast and predictive uncertainty of carbon estimates over North America?

  7. A Global Carbon Assimilation System using a modified EnKF assimilation method

    NASA Astrophysics Data System (ADS)

    Zhang, S.; Zheng, X.; Chen, Z.; Dan, B.; Chen, J. M.; Yi, X.; Wang, L.; Wu, G.

    2014-10-01

    A Global Carbon Assimilation System based on Ensemble Kalman filter (GCAS-EK) is developed for assimilating atmospheric CO2 abundance data into an ecosystem model to simultaneously estimate the surface carbon fluxes and atmospheric CO2 distribution. This assimilation approach is based on the ensemble Kalman filter (EnKF), but with several new developments, including using analysis states to iteratively estimate ensemble forecast errors, and a maximum likelihood estimation of the inflation factors of the forecast and observation errors. The proposed assimilation approach is tested in observing system simulation experiments and then used to estimate the terrestrial ecosystem carbon fluxes and atmospheric CO2 distributions from 2002 to 2008. The results showed that this assimilation approach can effectively reduce the biases and uncertainties of the carbon fluxes simulated by the ecosystem model.

  8. Two-wavelength Method Estimates Heat fluxes over Heterogeneous Surface in North-China

    NASA Astrophysics Data System (ADS)

    Zhang, G.; Zheng, N.; Zhang, J.

    2017-12-01

    Heat fluxes is a key process of hydrological and heat transfer of soil-plant-atmosphere continuum (SPAC), and now it is becoming an important topic in meteorology, hydrology, ecology and other related research areas. Because the temporal and spatial variation of fluxes at regional scale is very complicated, it is still difficult to measure fluxes at the kilometer scale over a heterogeneous surface. A technique called "two-wavelength method" which combines optical scintillometer with microwave scintillometer is able to measure both sensible and latent heat fluxes over large spatial scales at the same time. The main purpose of this study is to investigate the fluxes over non-uniform terrain in North-China. Estimation of heat fluxes was carried out with the optical-microwave scintillometer and an eddy covariance (EC) system over heterogeneous surface in Tai Hang Mountains, China. EC method was set as a benchmark in the study. Structure parameters obtained from scintillometer showed that the typical measurement values of Cn2 are around 10-13 m-2/3 for microwave scintillometer, and values of Cn2 were around 10-15 m-2/3 for optical scintillometer. The correlation of heat fluxes (H) derived from scintillometer and EC system showed as a ratio of 1.05,and with R2=0.75, while the correlation of latent heat fluxes (LE) showed as 1.29 with R2=0.67. It was also found that heat fluxes derived from the two system showed good agreement (R2=0.9 for LE, R2=0.97 for H) when the Bowen ratio (β) was 1.03, while discrepancies showed significantly when β=0.75, and RMSD in H was 139.22 W/m2, 230.85 W/m2 in LE respectively.Experiment results in our research shows that, the two-wavelength method gives a larger heat fluxes over the study area, and a deeper study should be conduct. We expect that our investigate and analysis can be promoted the application of scintillometry method in regional evapotranspiration measurements and relevant disciplines.

  9. Position Estimation for Switched Reluctance Motor Based on the Single Threshold Angle

    NASA Astrophysics Data System (ADS)

    Zhang, Lei; Li, Pang; Yu, Yue

    2017-05-01

    This paper presents a position estimate model of switched reluctance motor based on the single threshold angle. In view of the relationship of between the inductance and rotor position, the position is estimated by comparing the real-time dynamic flux linkage with the threshold angle position flux linkage (7.5° threshold angle, 12/8SRM). The sensorless model is built by Maltab/Simulink, the simulation are implemented under the steady state and transient state different condition, and verified its validity and feasibility of the method..

  10. A method for simulating a flux-locked DC SQUID

    NASA Technical Reports Server (NTRS)

    Gutt, G. M.; Kasdin, N. J.; Condron, M. R., II; Muhlfelder, B.; Lockhart, J. M.; Cromar, M. W.

    1993-01-01

    The authors describe a computationally efficient and accurate method for simulating a dc SQUID's V-Phi (voltage-flux) and I-V characteristics which has proven valuable in evaluating and improving various SQUID readout methods. The simulation of the SQUID is based on fitting of previously acquired data from either a real or a modeled device using the Fourier transform of the V-Phi curve. This method does not predict SQUID behavior, but rather is a way of replicating a known behavior efficiently with portability into various simulation programs such as SPICE. The authors discuss the methods used to simulate the SQUID and the flux-locking control electronics, and present specific examples of this approach. Results include an estimate of the slew rate and linearity of a simple flux-locked loop using a characterized dc SQUID.

  11. Entropy and climate. I - ERBE observations of the entropy production of the earth

    NASA Technical Reports Server (NTRS)

    Stephens, G. L.; O'Brien, D. M.

    1993-01-01

    An approximate method for estimating the global distributions of the entropy fluxes flowing through the upper boundary of the climate system is introduced, and an estimate of the entropy exchange between the earth and space and the entropy production of the planet is provided. Entropy fluxes calculated from the Earth Radiation Budget Experiment measurements show how the long-wave entropy flux densities dominate the total entropy fluxes at all latitudes compared with the entropy flux densities associated with reflected sunlight, although the short-wave flux densities are important in the context of clear sky-cloudy sky net entropy flux differences. It is suggested that the entropy production of the planet is both constant for the 36 months of data considered and very near its maximum possible value. The mean value of this production is 0.68 x 10 exp 15 W/K, and the amplitude of the annual cycle is approximately 1 to 2 percent of this value.

  12. Gravity wave momentum flux estimation from CRISTA satellite data

    NASA Astrophysics Data System (ADS)

    Ern, M.; Preusse, P.; Alexander, M. J.; Offermann, D.

    2003-04-01

    Temperature altitude profiles measured by the CRISTA satellite were analyzed for gravity waves (GWs). Amplitudes, vertical and horizontal wavelengths of GWs are retrieved by applying a combination of maximum entropy method (MEM) and harmonic analysis (HA) to the temperature height profiles and subsequently comparing the so retrieved GW phases of adjacent altitude profiles. From these results global maps of the absolute value of the vertical flux of horizontal momentum have been estimated. Significant differences between distributions of the temperature variance and distributions of the momentum flux exist. For example, global maps of the momentum flux show a pronounced northward shift of the equatorial maximum whereas temperature variance maps of the tropics/subtropics are nearly symmetric with respect to the equator. This indicates the importance of the influence of horizontal and vertical wavelength distribution on global structures of the momentum flux.

  13. Using excess 4He to quantify variability in aquitard leakage

    NASA Astrophysics Data System (ADS)

    Gardner, W. Payton; Harrington, Glenn A.; Smerdon, Brian D.

    2012-10-01

    SummaryFluid flux through aquitards controls the rate of recharge, discharge, cross-formational fluid flow and contaminant transport in subsurface systems. In this paper, concentrations of 4He are used to investigate the spatial distribution of vertical fluid flux through the regionally extensive Great Artesian Basin aquitard system in northern South Australia. Two vertical profiles of 4He concentration in aquitard pore water, augmented with regional sampling of aquifers above and below the aquitard were used to estimate fluid flux at multiple locations over a large spatial area. 4He concentrations in the shallow aquifer above the Great Artesian Basin range from atmospheric equilibrium to 1000 times enriched over atmosphere. Fluid flux through the aquitard was estimated by fitting observed helium concentrations at each sampling site with a 1-D model of helium transport through the aquitard. Estimated fluid fluxes through the aquitard vary over three orders of magnitude across the study area. In areas of competent aquitard, fluid fluxes are less than 0.003 mm/yr, and mass transport of helium is dominated by molecular diffusion. Preferential discharge zones are clearly identifiable with fluid fluxes up to 3 mm/yr. Our results show that fluid flux through a regionally extensive aquitard can be highly variable at large spatial scales, and that 4He concentrations in aquifers bounding the aquitard system provide a convenient and sensitive method for investigating aquitard flux at the regional scale.

  14. Seasonal patterns in the soil water balance of a Spartina marsh site at North Inlet, South Carolina, USA

    USGS Publications Warehouse

    Gardner, L.R.; Reeves, H.W.

    2002-01-01

    Time series of ground-water head at a mid-marsh site near North Inlet, South Carolina, USA can be classified into five types of forcing signatures based on the dominant water flux governing water-level dynamics during a given time interval. The fluxes that can be recognized are recharge by tides and rain, evapotranspiration (ET), seepage into the near surface soil from below, and seepage across the soil surface to balance either ET losses or seepage influxes from below. Minimal estimates for each flux can be made by multiplying the head change induced by it by the measured specific yield of the soil. These flux estimates are provide minimal values because ET fluxes resulting from this method are about half as large as those estimated from calculated potential evapotranspiration (PET), which place an upper limit on the actual ET. As evapotranspiration is not moisture-limited at this regularly submerged site, the actual ET is probably nearly equal to PET. Thus, all of the other fluxes are probably twice as large as those given by this method. Application of this method shows that recharge by tides and rain only occurs during spring and summer when ET exceeds upward seepage from below and is thereby able to draw down the water table below the marsh surface occasionally. During fall and winter, seepage of fresh water from below is largely balanced by seepage out of the soil into overlying tidal water or into sheet flow during tidal exposure. The resulting reduction in soil water salinity may thereby enhance the growth of Spartina in the following spring. ?? 2002, The Society of Wetland Scientists.

  15. Using heat to characterize streambed water flux variability in four stream reaches

    USGS Publications Warehouse

    Essaid, H.I.; Zamora, C.M.; McCarthy, K.A.; Vogel, J.R.; Wilson, J.T.

    2008-01-01

    Estimates of streambed water flux are needed for the interpretation of streambed chemistry and reactions. Continuous temperature and head monitoring in stream reaches within four agricultural watersheds (Leary Weber Ditch, IN; Maple Creek, NE; DR2 Drain, WA; and Merced River, CA) allowed heat to be used as a tracer to study the temporal and spatial variability of fluxes through the streambed. Synoptic methods (seepage meter and differential discharge measurements) were compared with estimates obtained by using heat as a tracer. Water flux was estimated by modeling one-dimensional vertical flow of water and heat using the model VS2DH. Flux was influenced by physical heterogeneity of the stream channel and temporal variability in stream and ground-water levels. During most of the study period (April-December 2004), flux was upward through the streambeds. At the IN, NE, and CA sites, high-stage events resulted in rapid reversal of flow direction inducing short-term surface-water flow into the streambed. During late summer at the IN site, regional ground-water levels dropped, leading to surface-water loss to ground water that resulted in drying of the ditch. Synoptic measurements of flux generally supported the model flux estimates. Water flow through the streambed was roughly an order of magnitude larger in the humid basins (IN and NE) than in the arid basins (WA and CA). Downward flux, in response to sudden high streamflows, and seasonal variability in flux was most pronounced in the humid basins and in high conductivity zones in the streambed. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  16. Estimation of land surface heat fluxes based on visible infrared imaging radiometer suite data: case study in northern China

    NASA Astrophysics Data System (ADS)

    Li, Xiaojun; Xin, Xiaozhou; Peng, Zhiqing; Zhang, Hailong; Li, Li; Shao, Shanshan; Liu, Qinhuo

    2017-10-01

    Evapotranspiration (ET) plays an important role in surface-atmosphere interactions and can be monitored using remote sensing data. The visible infrared imaging radiometer suite (VIIRS) sensor is a generation of optical satellite sensors that provide daily global coverage at 375- to 750-m spatial resolutions with 22 spectral channels (0.412 to 12.05 μm) and capable of monitoring ET from regional to global scales. However, few studies have focused on methods of acquiring ET from VIIRS images. The objective of this study is to introduce an algorithm that uses the VIIRS data and meteorological variables to estimate the energy budgets of land surfaces, including the net radiation, soil heat flux, sensible heat flux, and latent heat fluxes. A single-source model that based on surface energy balance equation is used to obtain surface heat fluxes within the Zhangye oasis in China. The results were validated using observations collected during the HiWATER (Heihe Watershed Allied Telemetry Experimental Research) project. To facilitate comparison, we also use moderate resolution imaging spectrometer (MODIS) data to retrieve the regional surface heat fluxes. The validation results show that it is feasible to estimate the turbulent heat flux based on the VIIRS sensor and that these data have certain advantages (i.e., the mean bias error of sensible heat flux is 15.23 W m-2) compared with MODIS data (i.e., the mean bias error of sensible heat flux is -29.36 W m-2). Error analysis indicates that, in our model, the accuracies of the estimated sensible heat fluxes rely on the errors in the retrieved surface temperatures and the canopy heights.

  17. A Semi-parametric Multivariate Gap-filling Model for Eddy Covariance Latent Heat Flux

    NASA Astrophysics Data System (ADS)

    Li, M.; Chen, Y.

    2010-12-01

    Quantitative descriptions of latent heat fluxes are important to study the water and energy exchanges between terrestrial ecosystems and the atmosphere. The eddy covariance approaches have been recognized as the most reliable technique for measuring surface fluxes over time scales ranging from hours to years. However, unfavorable micrometeorological conditions, instrument failures, and applicable measurement limitations may cause inevitable flux gaps in time series data. Development and application of suitable gap-filling techniques are crucial to estimate long term fluxes. In this study, a semi-parametric multivariate gap-filling model was developed to fill latent heat flux gaps for eddy covariance measurements. Our approach combines the advantages of a multivariate statistical analysis (principal component analysis, PCA) and a nonlinear interpolation technique (K-nearest-neighbors, KNN). The PCA method was first used to resolve the multicollinearity relationships among various hydrometeorological factors, such as radiation, soil moisture deficit, LAI, and wind speed. The KNN method was then applied as a nonlinear interpolation tool to estimate the flux gaps as the weighted sum latent heat fluxes with the K-nearest distances in the PCs’ domain. Two years, 2008 and 2009, of eddy covariance and hydrometeorological data from a subtropical mixed evergreen forest (the Lien-Hua-Chih Site) were collected to calibrate and validate the proposed approach with artificial gaps after standard QC/QA procedures. The optimal K values and weighting factors were determined by the maximum likelihood test. The results of gap-filled latent heat fluxes conclude that developed model successful preserving energy balances of daily, monthly, and yearly time scales. Annual amounts of evapotranspiration from this study forest were 747 mm and 708 mm for 2008 and 2009, respectively. Nocturnal evapotranspiration was estimated with filled gaps and results are comparable with other studies. Seasonal and daily variability of latent heat fluxes were also discussed.

  18. Investigating carbon flux variability in subtropical peat soils of the Everglades using hydrogeophysical methods

    NASA Astrophysics Data System (ADS)

    Comas, Xavier; Wright, William

    2014-08-01

    The spatial and temporal variability in accumulation and release of greenhouse gases (mainly methane and carbon dioxide) to the atmosphere from peat soils remains very uncertain. The use of near-surface geophysical methods such as ground penetrating radar (GPR) has proven useful during the last decade to expand scales of measurement as related to in situ gas distribution and dynamics beyond traditional methods (i.e., gas chambers). However, this approach has focused exclusively on boreal peatlands, while no studies in subtropical systems like the Everglades using these techniques exist. In this paper GPR is combined with gas traps, time-lapse cameras, gas chromatography, and surface deformation measurements to explore biogenic gas dynamics (mainly gas buildup and release) in two locations in the Everglades. Similar to previous studies in northern peatlands, our data in the Everglades show a statistically significant correlation between the following: (1) GPR-estimated gas content and gas fluxes, (2) GPR-estimated gas content and surface deformation, and (3) atmospheric pressure and both GPR-estimated gas content and gas flux. From these results several gas-releasing events ranging between 33.8 and 718.8 mg CH4 m-2 d-1 were detected as identified by the following: (1) decreases in GPR-estimated gas content within the peat matrix, (2) increases in gas fluxes captured by gas traps and time-lapse cameras, and (3) decreases in surface deformation. Furthermore, gas-releasing events corresponded to periods of high atmospheric pressure. Changes in gas accumulation and release were attributed to differences in seasonality and peat soil type between sites. These results suggest that biogenic gas releases in the Everglades are spatially and temporarily variable. For example, flux events measured at hourly scales were up to threefold larger when compared to daily fluxes, therefore suggesting that flux measurements decline when averaged over longer time spans. This research therefore questions what the appropriate spatial and temporal scale of measurement is necessary to properly capture the dynamics of biogenic gas release in subtropical peat soils.

  19. Estimating surface fluxes over middle and upper streams of the Heihe River Basin with ASTER imagery

    NASA Astrophysics Data System (ADS)

    Ma, W.; Ma, Y.; Hu, Z.; Su, Z.; Wang, J.; Ishikawa, H.

    2011-05-01

    Land surface heat fluxes are essential measures of the strengths of land-atmosphere interactions involving energy, heat and water. Correct parameterization of these fluxes in climate models is critical. Despite their importance, state-of-the-art observation techniques cannot provide representative areal averages of these fluxes comparable to the model grid. Alternative methods of estimation are thus required. These alternative approaches use (satellite) observables of the land surface conditions. In this study, the Surface Energy Balance System (SEBS) algorithm was evaluated in a cold and arid environment, using land surface parameters derived from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data. Field observations and estimates from SEBS were compared in terms of net radiation flux (Rn), soil heat flux (G0), sensible heat flux (H) and latent heat flux (λE) over a heterogeneous land surface. As a case study, this methodology was applied to the experimental area of the Watershed Allied Telemetry Experimental Research (WATER) project, located on the mid-to-upstream sections of the Heihe River in northwest China. ASTER data acquired between 3 May and 4 June 2008, under clear-sky conditions were used to determine the surface fluxes. Ground-based measurements of land surface heat fluxes were compared with values derived from the ASTER data. The results show that the derived surface variables and the land surface heat fluxes furnished by SEBS in different months over the study area are in good agreement with the observed land surface status under the limited cases (some cases looks poor results). So SEBS can be used to estimate turbulent heat fluxes with acceptable accuracy in areas where there is partial vegetation cover in exceptive conditions. It is very important to perform calculations using ground-based observational data for parameterization in SEBS in the future. Nevertheless, the remote-sensing results can provide improved explanations of land surface fluxes over varying land coverage at greater spatial scales.

  20. A comparison of selection at list time and time-stratified sampling for estimating suspended sediment loads

    Treesearch

    Robert B. Thomas; Jack Lewis

    1993-01-01

    Time-stratified sampling of sediment for estimating suspended load is introduced and compared to selection at list time (SALT) sampling. Both methods provide unbiased estimates of load and variance. The magnitude of the variance of the two methods is compared using five storm populations of suspended sediment flux derived from turbidity data. Under like conditions,...

  1. Optimisation of flux calculation in rivers from discrete water quality surveys, a step towards an expert system

    NASA Astrophysics Data System (ADS)

    Raymond, S.; Moatar, F.; Meybeck, M.; Bustillo, V.

    2009-04-01

    Good estimates of fluxes of suspended particulate matter (SPM), total dissolved solids (TDS) and nutrients and contaminants are required for both Earth System science and river basin management. However, in most cases discrete sampling (weekly to monthly) is the rule. Few flux calculation methods are commonly used, yet their performances, i.e. uncertainties for given frequencies, at given stations and for each water quality variables, remain unknown. Based on a rare set of 1085 station-year of daily flux record for SPM, TDS and nutrients (dissolved and total), the performance of 9 calculations methods is explored. Discrete surveys at various frequencies (3days to 30 days) are simulated by Monte-Carlo sorting (100 runs) on which the 9 fluxes are calculated (annual and interannual). At this stage, the sub-daily variations of fluxes for the medium and large basins are not considered. The dataset for SPM corresponds to 55 stations (600 to 600 000 km2 basin area), 34 stations (700 to 1000000 km2) for TDS and for nutrients we consider 9 stations for NO3-, NH4+, PO43- and Ptot (600 to 30 000 km2). About 80% of the dataset originates from US records (USGS and Lake Erie tributaries survey) and 20% from French stations, this covering a wide range of hydrological and geochemical conditions in the temperate zone. Each sorted flux is compared to known fluxes established on daily records: percentiles of their relative errors (e10, e50 and e90) are used to determine the biases (e50) and the imprecisions (e90-e10) (Walling and Webb, 1981) which are then compared for each of the 6 water quality variables, for each flux methods and for various simulated survey frequencies. The calculation methods include 5 rating-curve approaches (linear"M1", "M2", Phillipps et al, 1999) with and without Ferguson correction (Ferguson, 1987), polynomial, truncated at discharges exceeding median annual or long-term water discharge), 2 methods based on hydrograph separation (Phillips et al, 1999) including a quadratic runoff module (Bustillo, 2005), 1 linear interpolation method and 2 discharge-weighted concentration methods ("M18", "M19", Philipps et al, 1999). As expected, based on 55 stations and 430 years, SPM fluxes are the most uncertain ones with maximum biases determined on annual fluxes (monthly sampling simulations). ranging at stations from -75% to +55% by the classical rating-curves approach ("M1", "M2") droping to -60% to +5% for the M18 method. At this frequency, biases are much less for Ptot and PO4-3 (-30% to +10%), nitrate (-5% to +10%) and are negligible for TDS. For higher frequencies, the biases are reduced: for instance for weekly surveys they drop to -25% for SPM and to -20% to 5% for Ptot for the M18 method. The river basin size is influencing the performance of calculations methods: SPM flux errors are much higher for smaller basins (103 to 104 km2) than for larger ones (> 104 km2), probably in relation with the flow duration in 2% of time which is a key control factor of flux duration in 2% of time (Moatar et al, 2006). This indicator based on daily flow (Q) records is generally available at water quality stations. Other indicators based on discrete water quality surveys are being tested to explain the performance of flux methods for each variable: concentrations (C) variability, C vs Q relationship, concentration seasonality. For each variable and each station the optimal flux calculation method will be derived from the future expert system. BUSTILLO V., Biogéochimie et hydroclimatologie appliquées à l'aménagement des bassins fluviaux .PhD Thesis, INP Toulouse,232 p+annexes (2005). FERGUSON R.I., Accuracy and precision of methods for estimating river loads. Earth Surface Processes and Landforms, vol. 12,95-104 (1987). MOATAR F., PERSON G., MEYBECK M., COYNEL A., ETCHEBER H., CROUZET P., The influence of contrasting suspended particulate matter transport regimes on the bias and precision of flux estimates Science of the Total Environment 370, 515-531 (2006). PHILLIPS. J.M., WEBB B.W., WALLING D.E., LEEKS G.J.L., Estimating the suspended sediment load of rivers in the LOIS study area using infrequent samples. Hydrol Process, 13:1035-50 (1999). WALLING D.E. et WEBB B.W., The reliability of suspended sediment load data IAHS Publ., 133, 177-94 (1981).

  2. An Investigation on the role of Planetary Boundary Layer Parameterization scheme on the performance of a hydrostatic atmospheric model over a Coastal Region

    NASA Astrophysics Data System (ADS)

    Anurose, J. T.; Subrahamanyam, Bala D.

    2012-07-01

    As part of the ocean/land-atmosphere interaction, more than half of the total kinetic energy is lost within the lowest part of atmosphere, often referred to as the planetary boundary layer (PBL). A comprehensive understanding of the energetics of this layer and turbulent processes responsible for dissipation of kinetic energy within the PBL require accurate estimation of sensible and latent heat flux and momentum flux. In numerical weather prediction (NWP) models, these quantities are estimated through different surface-layer and PBL parameterization schemes. This research article investigates different factors influencing the accuracy of a surface-layer parameterization scheme used in a hydrostatic high-resolution regional model (HRM) in the estimation of surface-layer turbulent fluxes of heat, moisture and momentum over the coastal regions of the Indian sub-continent. Results obtained from this sensitivity study of a parameterization scheme in HRM revealed the role of surface roughness length (z_{0}) in conjunction with the temperature difference between the underlying ground surface and atmosphere above (ΔT = T_{G} - T_{A}) in the estimated values of fluxes. For grid points over the land surface where z_{0} is treated as a constant throughout the model integration time, ΔT showed relative dominance in the estimation of sensible heat flux. In contrast to this, estimation of sensible and latent heat flux over ocean were found to be equally sensitive on the method adopted for assigning the values of z_{0} and also on the magnitudes of ΔT.

  3. 1km Global Terrestrial Carbon Flux: Estimations and Evaluations

    NASA Astrophysics Data System (ADS)

    Murakami, K.; Sasai, T.; Kato, S.; Saito, M.; Matsunaga, T.; Hiraki, K.; Maksyutov, S. S.

    2017-12-01

    Estimating global scale of the terrestrial carbon flux change with high accuracy and high resolution is important to understand global environmental changes. Furthermore the estimations of the global spatiotemporal distribution may contribute to the political and social activities such as REDD+. In order to reveal the current state of terrestrial carbon fluxes covering all over the world and a decadal scale. The satellite-based diagnostic biosphere model is suitable for achieving this purpose owing to observing on the present global land surface condition uniformly at some time interval. In this study, we estimated the global terrestrial carbon fluxes with 1km grids by using the terrestrial biosphere model (BEAMS). And we evaluated our new carbon flux estimations on various spatial scales and showed the transition of forest carbon stocks in some regions. Because BEAMS required high resolution meteorological data and satellite data as input data, we made 1km interpolated data using a kriging method. The data used in this study were JRA-55, GPCP, GOSAT L4B atmospheric CO2 data as meteorological data, and MODIS land product as land surface satellite data. Interpolating process was performed on the meteorological data because of insufficient resolution, but not on MODIS data. We evaluated our new carbon flux estimations using the flux tower measurement (FLUXNET2015 Datasets) in a point scale. We used 166 sites data for evaluating our model results. These flux sites are classified following vegetation type (DBF, EBF, ENF, mixed forests, grass lands, croplands, shrub lands, Savannas, wetlands). In global scale, the BEAMS estimations was underestimated compared to the flux measurements in the case of carbon uptake and release. The monthly variations of NEP showed relatively high correlations in DBF and mixed forests, but the correlation coefficients of EBF, ENF, and grass lands were less than 0.5. In the meteorological factors, air temperature and solar radiation showed very high correlations, and slight variations were showed in precipitation data. LAI data that was another large driving factor of terrestrial carbon cycle was not included in FLUXNET2015 datasets and it could not be evaluated.

  4. Evaluating Uncertainties in Sap Flux Scaled Estimates of Forest Transpiration, Canopy Conductance and Photosynthesis

    NASA Astrophysics Data System (ADS)

    Ward, E. J.; Bell, D. M.; Clark, J. S.; Kim, H.; Oren, R.

    2009-12-01

    Thermal dissipation probes (TDPs) are a common method for estimating forest transpiration and canopy conductance from sap flux rates in trees, but their implementation is plagued by uncertainties arising from missing data and variability in the diameter and canopy position of trees, as well as sapwood conductivity within individual trees. Uncertainties in estimates of canopy conductance also translate into uncertainties in carbon assimilation in models such as the Canopy Conductance Constrained Carbon Assimilation (4CA) model that combine physiological and environmental data to estimate photosynthetic rates. We developed a method to propagate these uncertainties in the scaling and imputation of TDP data to estimates of canopy transpiration and conductance using a state-space Jarvis-type conductance model in a hierarchical Bayesian framework. This presentation will focus on the impact of these uncertainties on estimates of water and carbon fluxes using 4CA and data from the Duke Free Air Carbon Enrichment (FACE) project, which incorporates both elevated carbon dioxide and soil nitrogen treatments. We will also address the response of canopy conductance to vapor pressure deficit, incident radiation and soil moisture, as well as the effect of treatment-related stand structure differences in scaling TDP measurements. Preliminary results indicate that in 2006, a year of normal precipitation (1127 mm), canopy transpiration increased in elevated carbon dioxide ~8% on a ground area basis. In 2007, a year with a pronounced drought (800 mm precipitation), this increase was only present in the combined carbon dioxide and fertilization treatment. The seasonal dynamics of water and carbon fluxes will be discussed in detail.

  5. Using Diurnal Temperature Signals to Infer Vertical Groundwater-Surface Water Exchange.

    PubMed

    Irvine, Dylan J; Briggs, Martin A; Lautz, Laura K; Gordon, Ryan P; McKenzie, Jeffrey M; Cartwright, Ian

    2017-01-01

    Heat is a powerful tracer to quantify fluid exchange between surface water and groundwater. Temperature time series can be used to estimate pore water fluid flux, and techniques can be employed to extend these estimates to produce detailed plan-view flux maps. Key advantages of heat tracing include cost-effective sensors and ease of data collection and interpretation, without the need for expensive and time-consuming laboratory analyses or induced tracers. While the collection of temperature data in saturated sediments is relatively straightforward, several factors influence the reliability of flux estimates that are based on time series analysis (diurnal signals) of recorded temperatures. Sensor resolution and deployment are particularly important in obtaining robust flux estimates in upwelling conditions. Also, processing temperature time series data involves a sequence of complex steps, including filtering temperature signals, selection of appropriate thermal parameters, and selection of the optimal analytical solution for modeling. This review provides a synthesis of heat tracing using diurnal temperature oscillations, including details on optimal sensor selection and deployment, data processing, model parameterization, and an overview of computing tools available. Recent advances in diurnal temperature methods also provide the opportunity to determine local saturated thermal diffusivity, which can improve the accuracy of fluid flux modeling and sensor spacing, which is related to streambed scour and deposition. These parameters can also be used to determine the reliability of flux estimates from the use of heat as a tracer. © 2016, National Ground Water Association.

  6. Using the Solar Polar Magnetic Field for Longterm Predictions of Solar Activity, Solar Cycles 21-25

    NASA Astrophysics Data System (ADS)

    Pesnell, W. D.; Schatten, K. H.

    2017-12-01

    We briefly review the dynamo and geomagnetic precursor methods of long-term solar activity forecasting. These methods depend upon the most basic aspect of dynamo theory to predict future activity, future magnetic field arises directly from the amplification of pre-existing magnetic field. We then generalize the dynamo technique, allowing the method to be used at any phase of the solar cycle, to the Solar Dynamo Amplitude (SODA) index. This index is sensitive to the magnetic flux trapped within the Sun's convection zone but insensitive to the phase of the solar cycle. Since magnetic fields inside the Sun can become buoyant, one may think of the acronym SODA as describing the amount of buoyant flux. We will show how effective the SODA Index has been in predicting Solar Cycles 23 and 24, and present a unified picture of earlier estimates of the polar magnetic configuration in Solar Cycle 21 and 22. Using the present value of the SODA index, we estimate that the next cycle's smoothed peak activity will be about 125 ± 30 solar flux units for the 10.7 cm radio flux and a sunspot number of 70 ± 25. This suggests that Solar Cycle 25 will be comparable to Solar Cycle 24. Since the current approach uses data prior to solar minimum, these estimates may improve when the upcoming solar minimum is reached.

  7. Turbulence Variance Characteristics in the Unstable Atmospheric Boundary Layer above Flat Pine Forest

    NASA Astrophysics Data System (ADS)

    Asanuma, Jun

    Variances of the velocity components and scalars are important as indicators of the turbulence intensity. They also can be utilized to estimate surface fluxes in several types of "variance methods", and the estimated fluxes can be regional values if the variances from which they are calculated are regionally representative measurements. On these motivations, variances measured by an aircraft in the unstable ABL over a flat pine forest during HAPEX-Mobilhy were analyzed within the context of the similarity scaling arguments. The variances of temperature and vertical velocity within the atmospheric surface layer were found to follow closely the Monin-Obukhov similarity theory, and to yield reasonable estimates of the surface sensible heat fluxes when they are used in variance methods. This gives a validation to the variance methods with aircraft measurements. On the other hand, the specific humidity variances were influenced by the surface heterogeneity and clearly fail to obey MOS. A simple analysis based on the similarity law for free convection produced a comprehensible and quantitative picture regarding the effect of the surface flux heterogeneity on the statistical moments, and revealed that variances of the active and passive scalars become dissimilar because of their different roles in turbulence. The analysis also indicated that the mean quantities are also affected by the heterogeneity but to a less extent than the variances. The temperature variances in the mixed layer (ML) were examined by using a generalized top-down bottom-up diffusion model with some combinations of velocity scales and inversion flux models. The results showed that the surface shear stress exerts considerable influence on the lower ML. Also with the temperature and vertical velocity variances ML variance methods were tested, and their feasibility was investigated. Finally, the variances in the ML were analyzed in terms of the local similarity concept; the results confirmed the original hypothesis by Panofsky and McCormick that the local scaling in terms of the local buoyancy flux defines the lower bound of the moments.

  8. A Practical Torque Estimation Method for Interior Permanent Magnet Synchronous Machine in Electric Vehicles.

    PubMed

    Wu, Zhihong; Lu, Ke; Zhu, Yuan

    2015-01-01

    The torque output accuracy of the IPMSM in electric vehicles using a state of the art MTPA strategy highly depends on the accuracy of machine parameters, thus, a torque estimation method is necessary for the safety of the vehicle. In this paper, a torque estimation method based on flux estimator with a modified low pass filter is presented. Moreover, by taking into account the non-ideal characteristic of the inverter, the torque estimation accuracy is improved significantly. The effectiveness of the proposed method is demonstrated through MATLAB/Simulink simulation and experiment.

  9. A Practical Torque Estimation Method for Interior Permanent Magnet Synchronous Machine in Electric Vehicles

    PubMed Central

    Zhu, Yuan

    2015-01-01

    The torque output accuracy of the IPMSM in electric vehicles using a state of the art MTPA strategy highly depends on the accuracy of machine parameters, thus, a torque estimation method is necessary for the safety of the vehicle. In this paper, a torque estimation method based on flux estimator with a modified low pass filter is presented. Moreover, by taking into account the non-ideal characteristic of the inverter, the torque estimation accuracy is improved significantly. The effectiveness of the proposed method is demonstrated through MATLAB/Simulink simulation and experiment. PMID:26114557

  10. CO2 flux determination by closed-chamber methods can be seriously biased by inappropriate application of linear regression

    NASA Astrophysics Data System (ADS)

    Kutzbach, L.; Schneider, J.; Sachs, T.; Giebels, M.; Nykänen, H.; Shurpali, N. J.; Martikainen, P. J.; Alm, J.; Wilmking, M.

    2007-11-01

    Closed (non-steady state) chambers are widely used for quantifying carbon dioxide (CO2) fluxes between soils or low-stature canopies and the atmosphere. It is well recognised that covering a soil or vegetation by a closed chamber inherently disturbs the natural CO2 fluxes by altering the concentration gradients between the soil, the vegetation and the overlying air. Thus, the driving factors of CO2 fluxes are not constant during the closed chamber experiment, and no linear increase or decrease of CO2 concentration over time within the chamber headspace can be expected. Nevertheless, linear regression has been applied for calculating CO2 fluxes in many recent, partly influential, studies. This approach has been justified by keeping the closure time short and assuming the concentration change over time to be in the linear range. Here, we test if the application of linear regression is really appropriate for estimating CO2 fluxes using closed chambers over short closure times and if the application of nonlinear regression is necessary. We developed a nonlinear exponential regression model from diffusion and photosynthesis theory. This exponential model was tested with four different datasets of CO2 flux measurements (total number: 1764) conducted at three peatlands sites in Finland and a tundra site in Siberia. Thorough analyses of residuals demonstrated that linear regression was frequently not appropriate for the determination of CO2 fluxes by closed-chamber methods, even if closure times were kept short. The developed exponential model was well suited for nonlinear regression of the concentration over time c(t) evolution in the chamber headspace and estimation of the initial CO2 fluxes at closure time for the majority of experiments. However, a rather large percentage of the exponential regression functions showed curvatures not consistent with the theoretical model which is considered to be caused by violations of the underlying model assumptions. Especially the effects of turbulence and pressure disturbances by the chamber deployment are suspected to have caused unexplainable curvatures. CO2 flux estimates by linear regression can be as low as 40% of the flux estimates of exponential regression for closure times of only two minutes. The degree of underestimation increased with increasing CO2 flux strength and was dependent on soil and vegetation conditions which can disturb not only the quantitative but also the qualitative evaluation of CO2 flux dynamics. The underestimation effect by linear regression was observed to be different for CO2 uptake and release situations which can lead to stronger bias in the daily, seasonal and annual CO2 balances than in the individual fluxes. To avoid serious bias of CO2 flux estimates based on closed chamber experiments, we suggest further tests using published datasets and recommend the use of nonlinear regression models for future closed chamber studies.

  11. Validation of two innovative methods to measure contaminant mass flux in groundwater

    NASA Astrophysics Data System (ADS)

    Goltz, Mark N.; Close, Murray E.; Yoon, Hyouk; Huang, Junqi; Flintoft, Mark J.; Kim, Sehjong; Enfield, Carl

    2009-04-01

    The ability to quantify the mass flux of a groundwater contaminant that is leaching from a source area is critical to enable us to: (1) evaluate the risk posed by the contamination source and prioritize cleanup, (2) evaluate the effectiveness of source remediation technologies or natural attenuation processes, and (3) quantify a source term for use in models that may be applied to predict maximum contaminant concentrations in downstream wells. Recently, a number of new methods have been developed and subsequently applied to measure contaminant mass flux in groundwater in the field. However, none of these methods has been validated at larger than the laboratory-scale through a comparison of measured mass flux and a known flux that has been introduced into flowing groundwater. A couple of innovative flux measurement methods, the tandem circulation well (TCW) and modified integral pumping test (MIPT) methods, have recently been proposed. The TCW method can measure mass flux integrated over a large subsurface volume without extracting water. The TCW method may be implemented using two different techniques. One technique, the multi-dipole technique, is relatively simple and inexpensive, only requiring measurement of heads, while the second technique requires conducting a tracer test. The MIPT method is an easily implemented method of obtaining volume-integrated flux measurements. In the current study, flux measurements obtained using these two methods are compared with known mass fluxes in a three-dimensional, artificial aquifer. Experiments in the artificial aquifer show that the TCW multi-dipole and tracer test techniques accurately estimated flux, within 2% and 16%, respectively; although the good results obtained using the multi-dipole technique may be fortuitous. The MIPT method was not as accurate as the TCW method, underestimating flux by as much as 70%. MIPT method inaccuracies may be due to the fact that the method assumptions (two-dimensional steady groundwater flow to fully-screened wells) were not well-approximated. While fluxes measured using the MIPT method were consistently underestimated, the method's simplicity and applicability to the field may compensate for the inaccuracies that were observed in this artificial aquifer test.

  12. Urban Evapotranspiration and Carbon Dioxide Flux in Miami - Dade, Florida

    NASA Astrophysics Data System (ADS)

    Bernier, T.; Hopper, W.

    2010-12-01

    Atmospheric Carbon Dioxide (CO2) concentrations are leading indicators of secular climate change. With increasing awareness of the consequences of climate change, methods for monitoring this change are becoming more important daily. Of particular interest is the carbon dioxide exchange between natural and urban landscapes and the correlation of atmospheric CO2 concentrations. Monitoring Evapotranspiration (ET) is important for assessments of water availability for growing populations. ET is surprisingly understudied in the hydrologic cycle considering ET removes as much as 80 to over 100% of precipitation back into the atmosphere as water vapor. Lack of understanding in spatial and temporal ET estimates can limit the credibility of hydrologic water budgets designed to promote sustainable water use and resolve water-use conflicts. Eddy covariance (EC) methods are commonly used to estimate ET and CO2 fluxes. The EC platform consist of a (CSAT) 3-D Sonic Anemometer and a Li-Cor Open Path CO2/ H2O Analyzer. Measurements collected at 10 Hz create a very large data sets. A EC flux tower located in the Snapper Creek Well Field as part of a study to estimate ET for the Miami Dade County Water and Sewer project. Data has been collected from December 17, 2009 to August 30, 2010. QA/QC is performed with the EdiRe data processing software according to Ameri-flux protocols. ET estimates along with other data--latent-heat flux, sensible-heat flux, rainfall, air temperature, wind speed and direction, solar irradiance, net radiation, soil-heat flux and relative humidity--can be used to aid in the development of water management policies and regulations. Currently, many financial institutions have adopted an understanding about baseline environmental monitoring. The “Equator Principle” is an example of a voluntary standard for managing social and environmental risk in project financing and has changed the way in which projects are financed.

  13. Alternating steady state free precession for estimation of current-induced magnetic flux density: A feasibility study.

    PubMed

    Lee, Hyunyeol; Jeong, Woo Chul; Kim, Hyung Joong; Woo, Eung Je; Park, Jaeseok

    2016-05-01

    To develop a novel, current-controlled alternating steady-state free precession (SSFP)-based conductivity imaging method and corresponding MR signal models to estimate current-induced magnetic flux density (Bz ) and conductivity distribution. In the proposed method, an SSFP pulse sequence, which is in sync with alternating current pulses, produces dual oscillating steady states while yielding nonlinear relation between signal phase and Bz . A ratiometric signal model between the states was analytically derived using the Bloch equation, wherein Bz was estimated by solving a nonlinear inverse problem for conductivity estimation. A theoretical analysis on the signal-to-noise ratio of Bz was given. Numerical and experimental studies were performed using SSFP-FID and SSFP-ECHO with current pulses positioned either before or after signal encoding to investigate the feasibility of the proposed method in conductivity estimation. Given all SSFP variants herein, SSFP-FID with alternating current pulses applied before signal encoding exhibits the highest Bz signal-to-noise ratio and conductivity contrast. Additionally, compared with conventional conductivity imaging, the proposed method benefits from rapid SSFP acquisition without apparent loss of conductivity contrast. We successfully demonstrated the feasibility of the proposed method in estimating current-induced Bz and conductivity distribution. It can be a promising, rapid imaging strategy for quantitative conductivity imaging. © 2015 Wiley Periodicals, Inc.

  14. Estimation of Reconnection Flux Using Post-Eruption Arcades and Its Relevance to Magnetic Clouds at 1 AU

    NASA Technical Reports Server (NTRS)

    Gopalswamy, N.; Yashiro, S.; Akiyama, S.; Xie, H.

    2017-01-01

    We report on a new method to compute the flare reconnection (RC) flux from post-eruption arcades (PEAs) and the underlying photospheric magnetic fields. In previous works, the RC flux has been computed using the cumulative flare ribbon area. Here we obtain the RC flux as the flux in half of the area underlying the PEA in EUV imaged after the flare maximum. We apply this method to a set of 21 eruptions that originated near the solar disk center in Solar Cycle 23. We find that the RC flux from the arcade method ((Phi)rA) has excellent agreement with the flux from the flare-ribbon method ((Phi)rR) according to (Phi)rA = 1.24((Phi)rR)(sup 0.99). We also find (Phi)rA to be correlated with the poloidal flux ((Phi)P) of the associated magnetic cloud at 1 AU: (Phi)P = 1.20((Phi)rA)(sup 0.85). This relation is nearly identical to that obtained by Qiu et al. (Astrophys. J. 659, 758, 2007) using a set of only 9 eruptions. Our result supports the idea that flare reconnection results in the formation of the flux rope and PEA as a common process.

  15. Seepage through a hazardous-waste trench cover

    USGS Publications Warehouse

    Healy, R.W.

    1989-01-01

    Water movement through a waste-trench cover under natural conditions at a low-level radioactive waste disposal site in northwestern Illinois was studied from July 1982 to June 1984, using tensiometers, a moisture probe, and meteorological instruments. Four methods were used to estimate seepage: the Darcy, zero-flux plane, surface-based water-budget, and groundwater-based water-budget methods. Annual seepage estimates ranged from 48 to 216 mm (5-23% of total precipitation), with most seepage occurring in spring. The Darcy method, although limited in accuracy by uncertainty in hydraulic conductivity, was capable of discretizing seepage in space and time and indicated that seepage varied by almost an order of magnitude across the width of the trench. Lowest seepage rates occurred near the center of the cover, where seepage was gradual. Highest rates occurred along the edge of the cover, where seepage was highly episodic, with 84% of the total there being traced to wetting fronts from 28 individual storms. Limitations of the zero-flux-plane method were severe enough for the method to be judged inappropriate for use in this study.Water movement through a waste-trench cover under natural conditions at a low-level radioactive waste disposal site in northwestern Illinois was studied from July 1982 to June 1984, using tensiometers, a moisture probe, and meteorological instruments. Four methods were used to estimate seepage: the Darcy, zero-flux plane, surface-based water-budget, and groundwater-based water-budget methods. Annual seepage estimates ranged from 48 to 216mm (5-23% of total precipitation), with most seepage occurring in spring. The Darcy method, although limited in accuracy by uncertainty in hydraulic conductivity, was capable of discretizing seepage in space and time and indicated that seepage varied by almost an order of magnitude across the width of the trench. Lowest seepage rates occurred near the center of the cover, where seepage was gradual. Highest rates occurred along the edge of the cover, where seepage was highly episodic, with 84% of the total there being traced to wetting fronts from 28 individual storms. Limitations of the zero-flux-plane method were severe enough for the method to be judged inappropriate for use in this study.

  16. Evapotranspiration under advective conditions.

    PubMed

    Figuerola, Patricia I; Berliner, Pedro R

    2005-07-01

    Arid and semi-arid regions are heterogeneous landscapes in which irrigated fields are surrounded by arid areas. The advection of sensible heat flux from dry surfaces is a significant source of energy that has to be taken into consideration when evaluating the evaporation from crops growing in these areas. The basic requirement of most of the common methods for estimating evapotranspiration [Bowen ratio, aerodynamic and Penman-Monteith (PM) equation] is that the horizontal fluxes of sensible and latent heat are negligible when compared to the corresponding vertical fluxes. We carried out measurements above an irrigated tomato field in a desert area. Latent and sensible heat fluxes were measured using a four-level Bowen machine with aspirated psychrometers. Our results indicate that under advective conditions only measurements carried out in the lowest layer are satisfactory for the estimation of latent heat fluxes and that the use of the PM equation with an appropriately parameterized canopy resistance may be preferable.

  17. Evaluation of energy balance closure adjustment methods by independent evapotranspiration estimates from lysimeters and hydrological simulations

    DOE PAGES

    Mauder, Matthias; Genzel, Sandra; Fu, Jin; ...

    2017-11-10

    Here, we report non-closure of the surface energy balance is a frequently observed phenomenon of hydrometeorological field measurements, when using the eddy-covariance method, which can be ascribed to an underestimation of the turbulent fluxes. Several approaches have been proposed in order to adjust the measured fluxes for this apparent systematic error. However, there are uncertainties about partitioning of the energy balance residual between the sensible and latent heat flux and whether such a correction should be applied on 30-minute data or longer time scales. The data for this study originate from two grassland sites in southern Germany, where measurements frommore » weighable lysimeters are available as reference. The adjusted evapotranspiration rates are also compared with joint energy and water balance simulations using a physically-based distributed hydrological model. We evaluate two adjustment methods: the first one preserves the Bowen ratio and the correction factor is determined on a daily basis. The second one attributes a smaller portion of the residual energy to the latent heat flux than to the sensible heat flux for closing the energy balance for every 30-minute flux integration interval. Both methods lead to an improved agreement of the eddy-covariance based fluxes with the independent lysimeter estimates and the physically-based model simulations. The first method results in a better comparability of evapotranspiration rates, and the second method leads to a smaller overall bias. These results are similar between both sites despite considerable differences in terrain complexity and grassland management. Moreover, we found that a daily adjustment factor leads to less scatter than a complete partitioning of the residual for every half-hour time interval. Lastly, the vertical temperature gradient in the surface layer and friction velocity were identified as important predictors for a potential future parameterization of the energy balance residual.« less

  18. Evaluation of energy balance closure adjustment methods by independent evapotranspiration estimates from lysimeters and hydrological simulations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mauder, Matthias; Genzel, Sandra; Fu, Jin

    Here, we report non-closure of the surface energy balance is a frequently observed phenomenon of hydrometeorological field measurements, when using the eddy-covariance method, which can be ascribed to an underestimation of the turbulent fluxes. Several approaches have been proposed in order to adjust the measured fluxes for this apparent systematic error. However, there are uncertainties about partitioning of the energy balance residual between the sensible and latent heat flux and whether such a correction should be applied on 30-minute data or longer time scales. The data for this study originate from two grassland sites in southern Germany, where measurements frommore » weighable lysimeters are available as reference. The adjusted evapotranspiration rates are also compared with joint energy and water balance simulations using a physically-based distributed hydrological model. We evaluate two adjustment methods: the first one preserves the Bowen ratio and the correction factor is determined on a daily basis. The second one attributes a smaller portion of the residual energy to the latent heat flux than to the sensible heat flux for closing the energy balance for every 30-minute flux integration interval. Both methods lead to an improved agreement of the eddy-covariance based fluxes with the independent lysimeter estimates and the physically-based model simulations. The first method results in a better comparability of evapotranspiration rates, and the second method leads to a smaller overall bias. These results are similar between both sites despite considerable differences in terrain complexity and grassland management. Moreover, we found that a daily adjustment factor leads to less scatter than a complete partitioning of the residual for every half-hour time interval. Lastly, the vertical temperature gradient in the surface layer and friction velocity were identified as important predictors for a potential future parameterization of the energy balance residual.« less

  19. A Method for Assessing the Quality of Model-Based Estimates of Ground Temperature and Atmospheric Moisture Using Satellite Data

    NASA Technical Reports Server (NTRS)

    Wu, Man Li C.; Schubert, Siegfried; Lin, Ching I.; Stajner, Ivanka; Einaudi, Franco (Technical Monitor)

    2000-01-01

    A method is developed for validating model-based estimates of atmospheric moisture and ground temperature using satellite data. The approach relates errors in estimates of clear-sky longwave fluxes at the top of the Earth-atmosphere system to errors in geophysical parameters. The fluxes include clear-sky outgoing longwave radiation (CLR) and radiative flux in the window region between 8 and 12 microns (RadWn). The approach capitalizes on the availability of satellite estimates of CLR and RadWn and other auxiliary satellite data, and multiple global four-dimensional data assimilation (4-DDA) products. The basic methodology employs off-line forward radiative transfer calculations to generate synthetic clear-sky longwave fluxes from two different 4-DDA data sets. Simple linear regression is used to relate the clear-sky longwave flux discrepancies to discrepancies in ground temperature ((delta)T(sub g)) and broad-layer integrated atmospheric precipitable water ((delta)pw). The slopes of the regression lines define sensitivity parameters which can be exploited to help interpret mismatches between satellite observations and model-based estimates of clear-sky longwave fluxes. For illustration we analyze the discrepancies in the clear-sky longwave fluxes between an early implementation of the Goddard Earth Observing System Data Assimilation System (GEOS2) and a recent operational version of the European Centre for Medium-Range Weather Forecasts data assimilation system. The analysis of the synthetic clear-sky flux data shows that simple linear regression employing (delta)T(sub g)) and broad layer (delta)pw provides a good approximation to the full radiative transfer calculations, typically explaining more thin 90% of the 6 hourly variance in the flux differences. These simple regression relations can be inverted to "retrieve" the errors in the geophysical parameters, Uncertainties (normalized by standard deviation) in the monthly mean retrieved parameters range from 7% for (delta)T(sub g) to approx. 20% for the lower tropospheric moisture between 500 hPa and surface. The regression relationships developed from the synthetic flux data, together with CLR and RadWn observed with the Clouds and Earth Radiant Energy System instrument, ire used to assess the quality of the GEOS2 T(sub g) and pw. Results showed that the GEOS2 T(sub g) is too cold over land, and pw in upper layers is too high over the tropical oceans and too low in the lower atmosphere.

  20. Volatile Emissions from Subduction-related Volcanoes: Major and Trace Elements

    NASA Astrophysics Data System (ADS)

    Fischer, T. P.; Hilton, D. R.

    2003-12-01

    Present-day volatile emissions associated with subduction zone volcanism can be estimated in two ways. One approach is to assume magma production rate at arcs is 20% that of MOR and scale to the MOR 3He flux (1000 mol/yr) to obtain a mantle-derived arc He-3 flux of 200+/-40 mol/yr. This flux and measured gas ratios (xI/3He where xI is the gas species of interest) obtained from volcanic and hydrothermal samples is then used to calculate volatile emissions. A global arc CO2 flux of 0.3 to 3.1 x 1012 mol/yr has been obtained in this way. Another approach is to use individual arc volcano SO2 fluxes (determined by remote sensing) in combination with CO2/SO2 ratios of high temperature fumaroles to calculate volcanic CO2 fluxes. Integrating over an individual arc, and using a power-law distribution to include non-measured volcanoes, it is possible to produce a volatile flux estimate for a particular arc. Summing over all arcs allows a global estimate (e.g. ˜ 1.6 x1012 mol/yr for arc CO2). There are caveats with both methods. In the former case, it is assumed that the mantle wedge is characterized by a similar 3He content to MORB-source. In the latter case, the distribution of SO2 fluxes is decidedly uneven necessitating poorly-justified extrapolations. For example, there is little data available from the I-B-M, Lesser Antilles and Philippines whereas Central American volcanoes have numerous published SO2 fluxes. A further issue (in addition to geographical bias), is the absence of volatile fluxes from submarine arcs. Despite these problems, global estimates of SO2 and CO2 fluxes by both methods vary by only one order of magnitude [1]. It is emphasized that these are present-day estimates as paleo-degassing rates of arc magmas are poorly constrained and depend entirely on estimates of magma intrusion and extrusion rates [2]. The same approach has been used for other species although the flux of magmatic N2, H2O, HCl, HF from arcs remains poorly constrained (N2: ˜ 6 x108 to 2 x1010 mol/yr; H2O: ˜ 8 x1012 mol/yr; HCl ˜1 x1010 to 4x1011 mol/yr, HF: ˜3 x109 to 3 x1011 mol/yr)[1,3]. Due to the preferential partitioning of HCl and HF into volcano hosted hydrothermal systems, fluxes from magma bodies are probably much larger than what is emitted into the atmosphere. Trace element emissions from subduction related volcanoes are also poorly constrained but are potentially significant. High temperature (>700C) volcanic gas samples show that concentrations of Be, Rb, Sr, Ru, Rh, Pd, Cd, W, Re, Pt, Pb, Bi, Se, Sc are in the 5 to 1300 ug/L range and up to 25000 ug/L of B have been measured [4,5]. Using these concentrations and the global arc SO2 flux gives estimates of trace element fluxes on the order of 3 x104 to 8 x106 mol/yr (and 3 x109 mol/yr of B). These flux estimates are certainly upper limits because low temperature (<200C) gases that make up the majority of emissions have much lower trace element concentrations. Further work is needed to better constrain volatile contributions of volcanoes to the atmosphere, and to improve global geochemical models which assess the impact of volcanic gases on the atmosphere. {[1]} Hilton, Fischer & Marty (2002) Rev. Min. vol 47 for review [2] Kerrick Rev. Geophys. (2001) vol. 39 #4. [3] Symnods, Rose & Reed (1988) nature vol 334, p. 415 [4] Fischer, Shuttleworth & O'Day (1998) Fres. J. Anal. Chem. vol 362, p. 457 [5] Taran et al., (1995) Gochim. Cosmochim. Acta vol. 59, p. 1749

  1. Metabolite-balancing techniques vs. 13C tracer experiments to determine metabolic fluxes in hybridoma cells.

    PubMed

    Bonarius, H P; Timmerarends, B; de Gooijer, C D; Tramper, J

    The estimation of intracellular fluxes of mammalian cells using only mass balances of the relevant metabolites is not possible because the set of linear equations defined by these mass balances is underdetermined. In order to quantify fluxes in cyclic pathways the mass balance equations can be complemented with several constraints: (1) the mass balances of co-metabolites, such as ATP or NAD(P)H, (2) linear objective functions, (3) flux data obtained by isotopic-tracer experiments. Here, these three methods are compared for the analysis of fluxes in the primary metabolism of continuously cultured hybridoma cells. The significance of different theoretical constraints and different objective functions is discussed after comparing their resulting flux distributions to the fluxes determined using 13CO2 and 13C-lactate measurements of 1 - 13C-glucose-fed hybridoma cells. Metabolic fluxes estimated using the objective functions "maximize ATP" and "maximize NADH" are relatively similar to the experimentally determined fluxes. This is consistent with the observation that cancer cells, such as hybridomas, are metabolically hyperactive, and produce ATP and NADH regardless of the need for these cofactors. Copyright 1998 John Wiley & Sons, Inc.

  2. Forest Ecosystem respiration estimated from eddy covariance and chamber measurements under high turbulence and substantial tree mortality from bark beetles

    USGS Publications Warehouse

    Speckman, Heather N.; Frank, John M.; Bradford, John B.; Miles, Brianna L.; Massman, William J.; Parton, William J.; Ryan, Michael G.

    2015-01-01

    Eddy covariance nighttime fluxes are uncertain due to potential measurement biases. Many studies report eddy covariance nighttime flux lower than flux from extrapolated chamber measurements, despite corrections for low turbulence. We compared eddy covariance and chamber estimates of ecosystem respiration at the GLEES Ameriflux site over seven growing seasons under high turbulence (summer night mean friction velocity (u*) = 0.7 m s−1), during which bark beetles killed or infested 85% of the aboveground respiring biomass. Chamber-based estimates of ecosystem respiration during the growth season, developed from foliage, wood and soil CO2 efflux measurements, declined 35% after 85% of the forest basal area had been killed or impaired by bark beetles (from 7.1 ±0.22 μmol m−2 s−1 in 2005 to 4.6 ±0.16 μmol m−2 s−1 in 2011). Soil efflux remained at ~3.3 μmol m−2 s−1 throughout the mortality, while the loss of live wood and foliage and their respiration drove the decline of the chamber estimate. Eddy covariance estimates of fluxes at night remained constant over the same period, ~3.0 μmol m−2 s−1 for both 2005 (intact forest) and 2011 (85% basal area killed or impaired). Eddy covariance fluxes were lower than chamber estimates of ecosystem respiration (60% lower in 2005, and 32% in 2011), but the mean night estimates from the two techniques were correlated within a year (r2 from 0.18-0.60). The difference between the two techniques was not the result of inadequate turbulence, because the results were robust to a u* filter of > 0.7 m s−1. The decline in the average seasonal difference between the two techniques was strongly correlated with overstory leaf area (r2=0.92). The discrepancy between methods of respiration estimation should be resolved to have confidence in ecosystem carbon flux estimates.

  3. Momentum Flux Determination Using the Multi-beam Poker Flat Incoherent Scatter Radar

    NASA Technical Reports Server (NTRS)

    Nicolls, M. J.; Fritts, D. C.; Janches, Diego; Heinselman, C. J.

    2012-01-01

    In this paper, we develop an estimator for the vertical flux of horizontal momentum with arbitrary beam pointing, applicable to the case of arbitrary but fixed beam pointing with systems such as the Poker Flat Incoherent Scatter Radar (PFISR). This method uses information from all available beams to resolve the variances of the wind field in addition to the vertical flux of both meridional and zonal momentum, targeted for high-frequency wave motions. The estimator utilises the full covariance of the distributed measurements, which provides a significant reduction in errors over the direct extension of previously developed techniques and allows for the calculation of an error covariance matrix of the estimated quantities. We find that for the PFISR experiment, we can construct an unbiased and robust estimator of the momentum flux if sufficient and proper beam orientations are chosen, which can in the future be optimized for the expected frequency distribution of momentum-containing scales. However, there is a potential trade-off between biases and standard errors introduced with the new approach, which must be taken into account when assessing the momentum fluxes. We apply the estimator to PFISR measurements on 23 April 2008 and 21 December 2007, from 60-85 km altitude, and show expected results as compared to mean winds and in relation to the measured vertical velocity variances.

  4. Estimating Water and Heat Fluxes with a Four-dimensional Weak-constraint Variational Data Assimilation Approach

    NASA Astrophysics Data System (ADS)

    Bateni, S. M.; Xu, T.

    2015-12-01

    Accurate estimation of water and heat fluxes is required for irrigation scheduling, weather prediction, and water resources planning and management. A weak-constraint variational data assimilation (WC-VDA) scheme is developed to estimate water and heat fluxes by assimilating sequences of land surface temperature (LST) observations. The commonly used strong-constraint VDA systems adversely affect the accuracy of water and heat flux estimates as they assume the model is perfect. The WC-VDA approach accounts for structural and model errors and generates more accurate results via adding a model error term into the surface energy balance equation. The two key unknown parameters of the WC-VDA system (i.e., CHN, the bulk heat transfer coefficient and EF, evaporative fraction) and the model error term are optimized by minimizing the cost function. The WC-VDA model was tested at two sites with contrasting hydrological and vegetative conditions: the Daman site (a wet site located in an oasis area and covered by seeded corn) and the Huazhaizi site (a dry site located in a desert area and covered by sparse grass) in middle stream of Heihe river basin, northwest China. Compared to the strong-constraint VDA system, the WC-VDA method generates more accurate estimates of water and energy fluxes over the desert and oasis sites with dry and wet conditions.

  5. Analysis of temperature time series to estimate direction and magnitude of water fluxes in near-surface sediments

    NASA Astrophysics Data System (ADS)

    Munz, Matthias; Oswald, Sascha E.; Schmidt, Christian

    2017-04-01

    The application of heat as a hydrological tracer has become a standard method for quantifying water fluxes between groundwater and surface water. Typically, time series of temperatures in the surface water and in the sediment are observed and are subsequently evaluated by a vertical 1D representation of heat transport by advection and dispersion. Several analytical solutions as well as their implementation into user-friendly software exist in order to estimate water fluxes from the observed temperatures. The underlying assumption of a stationary, one-dimensional vertical flow field is frequently violated in natural systems. Here subsurface water flow often has a significant horizontal component. We developed a methodology for identifying the geometry of the subsurface flow field based on the variations of diurnal temperature amplitudes with depths. For instance: Purely vertical heat transport is characterized by an exponential decline of temperature amplitudes with increasing depth. Pure horizontal flow would be indicated by a constant, depth independent vertical amplitude profile. The decline of temperature amplitudes with depths could be fitted by polynomials of different order whereby the best fit was defined by the highest Akaike Information Criterion. The stepwise model optimization and selection, evaluating the shape of vertical amplitude ratio profiles was used to determine the predominant subsurface flow field, which could be systematically categorized in purely vertical and horizontal (hyporheic, parafluvial) components. Analytical solutions to estimate water fluxes from the observed temperatures are restricted to specific boundary conditions such as a sinusoidal upper temperature boundary. In contrast numerical solutions offer higher flexibility and can handle temperature data which is characterized by irregular variations such as storm-event induced temperature changes and thus cannot readily be incorporated in analytical solutions. There are several numerical models that simulate heat transport in porous media (e.g. VS2DH, HydroGeoSphere, FEFLOW) but there can be a steep learning curve to the modelling frameworks and may therefore not readily accessible to routinely infer water fluxes between groundwater and surface water. We developed a user-friendly, straightforeward to use software to estimate water FLUXes Based On Temperatures- FLUX-BOT. FLUX-BOT is a numerical code written in MATLAB that calculates time variable vertical water fluxes in saturated sediments based on the inversion of measured temperature time series observed at multiple depths. It applies a cell-centered Crank-Nicolson implicit finite difference scheme to solve the one-dimensional heat advection-conduction equation (FLUX-BOT can be downloaded from the following web site: https://bitbucket.org/flux-bot/flux-bot). We provide applications of FLUX-BOT to generic as well as to measured temperature data to demonstrate its performance. Both, the empirical analysis of temperature amplitudes as well as the numerical inversion of measured temperature time series to estimate the vertical magnitude of water fluxes extent the suite of current heat tracing methods and may provide insight into temperature data from an additional perspective.

  6. Monte Carlo Perturbation Theory Estimates of Sensitivities to System Dimensions

    DOE PAGES

    Burke, Timothy P.; Kiedrowski, Brian C.

    2017-12-11

    Here, Monte Carlo methods are developed using adjoint-based perturbation theory and the differential operator method to compute the sensitivities of the k-eigenvalue, linear functions of the flux (reaction rates), and bilinear functions of the forward and adjoint flux (kinetics parameters) to system dimensions for uniform expansions or contractions. The calculation of sensitivities to system dimensions requires computing scattering and fission sources at material interfaces using collisions occurring at the interface—which is a set of events with infinitesimal probability. Kernel density estimators are used to estimate the source at interfaces using collisions occurring near the interface. The methods for computing sensitivitiesmore » of linear and bilinear ratios are derived using the differential operator method and adjoint-based perturbation theory and are shown to be equivalent to methods previously developed using a collision history–based approach. The methods for determining sensitivities to system dimensions are tested on a series of fast, intermediate, and thermal critical benchmarks as well as a pressurized water reactor benchmark problem with iterated fission probability used for adjoint-weighting. The estimators are shown to agree within 5% and 3σ of reference solutions obtained using direct perturbations with central differences for the majority of test problems.« less

  7. Adaptive framework to better characterize errors of apriori fluxes and observational residuals in a Bayesian setup for the urban flux inversions.

    NASA Astrophysics Data System (ADS)

    Ghosh, S.; Lopez-Coto, I.; Prasad, K.; Karion, A.; Mueller, K.; Gourdji, S.; Martin, C.; Whetstone, J. R.

    2017-12-01

    The National Institute of Standards and Technology (NIST) supports the North-East Corridor Baltimore Washington (NEC-B/W) project and Indianapolis Flux Experiment (INFLUX) aiming to quantify sources of Greenhouse Gas (GHG) emissions as well as their uncertainties. These projects employ different flux estimation methods including top-down inversion approaches. The traditional Bayesian inversion method estimates emission distributions by updating prior information using atmospheric observations of Green House Gases (GHG) coupled to an atmospheric and dispersion model. The magnitude of the update is dependent upon the observed enhancement along with the assumed errors such as those associated with prior information and the atmospheric transport and dispersion model. These errors are specified within the inversion covariance matrices. The assumed structure and magnitude of the specified errors can have large impact on the emission estimates from the inversion. The main objective of this work is to build a data-adaptive model for these covariances matrices. We construct a synthetic data experiment using a Kalman Filter inversion framework (Lopez et al., 2017) employing different configurations of transport and dispersion model and an assumed prior. Unlike previous traditional Bayesian approaches, we estimate posterior emissions using regularized sample covariance matrices associated with prior errors to investigate whether the structure of the matrices help to better recover our hypothetical true emissions. To incorporate transport model error, we use ensemble of transport models combined with space-time analytical covariance to construct a covariance that accounts for errors in space and time. A Kalman Filter is then run using these covariances along with Maximum Likelihood Estimates (MLE) of the involved parameters. Preliminary results indicate that specifying sptio-temporally varying errors in the error covariances can improve the flux estimates and uncertainties. We also demonstrate that differences between the modeled and observed meteorology can be used to predict uncertainties associated with atmospheric transport and dispersion modeling which can help improve the skill of an inversion at urban scales.

  8. Characterization of potential EC flux underestimation of "sticky" trace gas species

    NASA Astrophysics Data System (ADS)

    Neftel, Albrecht; Hensen, Arjan; Ibrom, Andreas; Ammann, Christof; Voglmeier, Karl; Brümmer, Christian

    2017-04-01

    Eddy covariance (EC) flux measurements of "sticky" trace gas species are affected of damping of high frequency variations of the gas concentration. Several approaches have been developed to correct for this effect (see e.g. Ibrom et al., 2007, Ammann et al., 2006). These approaches have in common that the spectral properties of the scalar are compared with the sonic temperature deduced from the Sonic anemometer data that is only marginally damped. A main difference between the two method is that one uses power spectra, while the other is based on co-spectra of the gas concentration with the vertical wind speed. NH3 fluxes used in the analysis stem from two field experiments: a) Posieux intercomparison October 2015: NH3 emissions of a grazed pasture measured with Eddy Covariance using an Aerodyne quantum cascade laser and with a horizontal gradient measurement using MiniDOAS systems (Sintermann et al., 2016) in conjunction with a dispersion model. b) Dronten experiment June 2016 in the Netherlands: NH3 emissions from two manured circles within 40m diameters have been determined with four different approaches (Eddy Covariance, Integrated Horizontal Flux approach, horizontal gradients and plume measurements). Despite correction with standard methods, turbulent NH3 flux measurements with the eddy covariance method seem still be underestimated when, e.g., compared to flux estimated using gradient methods. We discuss possible correction algorithms and how such underestimations can be recognized in the usual case, where no alternative flux estimation methods are available. References: Ammann, C., Brunner, A., Spirig, C., and Neftel, A. 2006: Technical note: Water vapour concentration and flux measurements with PTR-MS, Atmos. Chem. Phys., 6, 4643-4651 Ibrom, A., Dellwik, E., Jensen, N.O., Flyvbjerg, H. and Pilegaard, K., 2007. Strong low-pass filtering effects on water vapour flux measurements with closed-path eddy correlation systems. Agricultural and Forest Meteorology, 147: 140 -156. Sintermann, J., Dietrich, K., Hani, C., Bell, M., Jocher, M., and Neftel, A. 2016 A miniDOAS instrument optimised for ammonia field measurements, Atmos Meas Tech, 9, 2721-2734

  9. Comparison Of Landscape-level Carbon Flux Estimates from Budgeting The Planetary Boundary Layer And Footprinting On Remote Sensing Images

    NASA Astrophysics Data System (ADS)

    Chen, B.; Chen, J. M.; Mo, G.

    2006-12-01

    Carbon balance estimation at the landscape/regional scale is a challenge because of the heterogeneity of the land surface and the nonlinearity inherent in ecophysiological processes. Two methodologies, a simple atmospheric boundary-layer budgeting method and an integrated modeling method, were explored and compared in this study. Studies of the atmospheric boundary-layer (ABL) budget of CO2 have the potential to provide information on carbon balance of the land surface on a regional scale. Indeed, the surface area of integration by the ABL moving through a tower in one day was estimated to be ~104 km2. Two novel methodologies to retrieve the landscape/regional carbon balance information captured by the CO2 concentration measurements are explored and compared in this study: boundary-layer budgeting and remote sensing-based footprint integration. We investigated four boreal continental sites in this study. Boundary-layer budgeting: By assuming the horizontal advection is negligible, the regional surface net flux (representative of an upwind area ~105 km2) can be calculated as, Fc=(Cm-CFT)ù+dC/dt*zi, where ù is the mean vertical velocity, zi is the mean ABL height, and and are the biweekly mean mixing ratio of CO2 in the ABL and the free troposphere, respectively. ù is from the NCEP (National Centers for Environmental Prediction) reanalysis data, while zi was simulated by an one-dimensional ABL model. The CO2 flux in the upwind area of the tower was also estimated based on ecosystem modeling using remote sensing measurements. Remote sensing-based footprint integration: The total regional flux captured by the sensor on a tower (mixing ratio) is the weighted sum of the upwind footprint source areas (Ømega), Fc= Σ FiWi, where Fi and Wi are the CO2 flux and its weighting factor for each pixel, respectively. Fiis calculated using an ecosystem model (BEPS: Boreal Ecosystem Productivity Simulator). Wiis comparative contribution factor of footprint function for each pixel within the whole footprint area as, Wi= fi/Σ fi, while the footprint function fi (the pixel i with x,y coordinates; x and y are along and the cross daily mean wind direction, respectively) is computed using a concentration footprint model as, fi(x,y,zm-z0)=Dy(x,y)Dz(x,zm)/U(x) Where Dy and Dz are the crosswind and vertical concentration distribution function, respectively and U(x) is the effective speed of plume advection. They are dependant on standard surface-layer scaling parameters and based on an analytical solution of Eulerian theory. Methodology comparison: The regional fluxes estimated using these two methods matched well. These regional net CO2 flux estimates were also comparable to local-scale measurements by eddy covariance techniques. The calculated upwind regional CO2 flux shows considerable seasonal and inter-annual variations. Annual regional flux was sensitive to air temperature in boreal regions and the temperature-sensitivities were region dependent. Larger fluxes are found in the warmer growing seasons and warmer years in the boreal forest regions.

  10. Studying emissions of CO2 in the Baltimore/Washington area using airborne measurements: source attribution, flux quantification, and model comparison

    NASA Astrophysics Data System (ADS)

    Ahn, D.; Hansford, J. R.; Salawitch, R. J.; Ren, X.; Cohen, M.; Karion, A.; Whetstone, J. R.; Salmon, O. E.; Shepson, P. B.; Gurney, K. R.; Osterman, G. B.; Dickerson, R. R.

    2017-12-01

    We study emissions of CO2 in the Baltimore-Washington area using airborne in-situ measurements, obtained during the February 2015 Fluxes of Greenhouse Gases in Maryland (FLAGG-MD) campaign. In this study, we attributed enhanced signals of CO2 to several power plants and two urban areas (Baltimore City and Washington, DC), using the NOAA HYSPLIT air parcel trajectory model as well as the analysis of chemical ratios to quantify the source/receptor relationship. Then, the fluxes of attributed CO2 are estimated using a mass balance approach. The uncertainty in the aircraft-based mass balance approach is estimated by conducting a detailed sensitivity analysis of CO2 fluxes, considering factors such as the background mixing ratio of CO2, wind direction and speed, PBL heights, the horizontal boundary, and vertical interpolation methods. Estimated fluxes of CO2 with estimated uncertainty ranges are then compared to output from various emissions data and models, such as CEMS, CarbonTracker, FFDAS, and ODIAC. Finally, column CO2 data over the Baltimore-Washington region observed by the OCO-2 satellite instrument are statistically compared to aircraft in-situ observations, to assess how well OCO-2 is able to quantify geographic and synoptic-scale variability.

  11. The Vertical Flux Method (VFM) for regional estimates of temporally and spatially varying nitrate fluxes in unsaturated zone and groundwater

    NASA Astrophysics Data System (ADS)

    Green, C. T.; Liao, L.; Nolan, B. T.; Juckem, P. F.; Ransom, K.; Harter, T.

    2017-12-01

    Process-based modeling of regional NO3- fluxes to groundwater is critical for understanding and managing water quality. Measurements of atmospheric tracers of groundwater age and dissolved-gas indicators of denitrification progress have potential to improve estimates of NO3- reactive transport processes. This presentation introduces a regionalized version of a vertical flux method (VFM) that uses simple mathematical estimates of advective-dispersive reactive transport with regularization procedures to calibrate estimated tracer concentrations to observed equivalents. The calibrated VFM provides estimates of chemical, hydrologic and reaction parameters (source concentration time series, recharge, effective porosity, dispersivity, reaction rate coefficients) and derived values (e.g. mean unsaturated zone travel time, eventual depth of the NO3- front) for individual wells. Statistical learning methods are used to extrapolate parameters and predictions from wells to continuous areas. The regional VFM was applied to 473 well samples in central-eastern Wisconsin. Chemical measurements included O2, NO3-, N2 from denitrification, and atmospheric tracers of groundwater age including carbon-14, chlorofluorocarbons, tritium, and triogiogenic helium. VFM results were consistent with observed chemistry, and calibrated parameters were in-line with independent estimates. Results indicated that (1) unsaturated zone travel times were a substantial portion of the transit time to wells and streams (2) fractions of N leached to groundwater have changed over time, with increasing fractions from manure and decreasing fractions from fertilizer, and (3) under current practices and conditions, 60% of the shallow aquifer will eventually be affected by NO3- contamination. Based on GIS coverages of variables related to soils, land use and hydrology, the VFM results at individual wells were extrapolated regionally using boosted regression trees, a statistical learning approach, that related the GIS variables to the VFM parameters and predictions. Future work will explore applications at larger scales with direct integration of the statistical prediction model with the mechanistic VFM.

  12. A review of land-based greenhouse gas flux estimates in Indonesia

    NASA Astrophysics Data System (ADS)

    Austin, Kemen G.; Harris, Nancy L.; Wijaya, Arief; Murdiyarso, Daniel; Harvey, Tom; Stolle, Fred; Kasibhatla, Prasad S.

    2018-05-01

    This study examines underlying reasons for differences among land-based greenhouse gas flux estimates in Indonesia, where six national inventories reported average emissions of between 0.4 and 1.1 Gt CO2e yr‑1 over the 2000–2012 period. The large range among estimates is only somewhat smaller than Indonesia’s GHG mitigation commitment. To determine the reasons for these differences, we compared input data and estimation methods, including the definitions and assumptions used for setting accounting boundaries, including emitting activities, incorporating fluxes from various carbon pools, and handling legacy fluxes. We also tested the sensitivity of methodological differences by generating our own reference emissions estimate and iteratively modifying individual components of the inventory. We found that the largest changes stem from the inclusion of legacy GHG emissions due to peat drainage (which increased emissions by at least +94% compared to the reference), methane emissions due to peat fires (+35%), and GHG emissions from belowground biomass and necromass carbon pools (+61%), modifications to assumptions of the mass of fuel burnt in peat fire events (+88%), and accounting for regrowth following a deforestation event (‑31%). These differences cumulatively explain more than half of the observed difference among inventory estimates. Understanding the various approaches to emissions estimation, and how these influence the magnitude of component GHG fluxes, is an important first step towards reconciling GHG inventories. The Indonesian government’s success in achieving its mitigation goal will depend on its ability to measure progress and evaluate the effectiveness of abatement actions, for which reliable harmonized greenhouse gas inventories are an essential foundation.

  13. Chemical and isotopic methods for quantifying ground-water recharge in a regional, semiarid environment

    USGS Publications Warehouse

    Wood, Warren W.; Sanford, Ward E.

    1995-01-01

    The High Plains aquifer underlying the semiarid Southern High Plains of Texas and New Mexico, USA was used to illustrate solute and isotopic methods for evaluating recharge fluxes, runoff, and spatial and temporal distribution of recharge. The chloride mass-balance method can provide, under certain conditions, a time-integrated technique for evaluation of recharge flux to regional aquifers that is independent of physical parameters. Applying this method to the High Plains aquifer of the Southern High Plains suggests that recharge flux is approximately 2% of precipitation, or approximately 11 ± 2 mm/y, consistent with previous estimates based on a variety of physically based measurements. The method is useful because long-term average precipitation and chloride concentrations in rain and ground water have less uncertainty and are generally less expensive to acquire than physically based parameters commonly used in analyzing recharge. Spatial and temporal distribution of recharge was evaluated by use of δ2H, δ18O, and tritium concentrations in both ground water and the unsaturated zone. Analyses suggest that nearly half of the recharge to the Southern High Plains occurs as piston flow through playa basin floors that occupy approximately 6% of the area, and that macropore recharge may be important in the remaining recharge. Tritium and chloride concentrations in the unsaturated zone were used in a new equation developed to quantify runoff. Using this equation and data from a representative basin, runoff was found to be 24 ± 3 mm/y; that is in close agreement with values obtained from water-balance measurements on experimental watersheds in the area. Such geochemical estimates are possible because tritium is used to calculate a recharge flux that is independent of precipitation and runoff, whereas recharge flux based on chloride concentration in the unsaturated zone is dependent upon the amount of runoff. The difference between these two estimates yields the amount of runoff to the basin.

  14. Spatio-temporal variability of lake CH4 fluxes and its influence on annual estimates

    NASA Astrophysics Data System (ADS)

    Natchimuthu, S.; Sundgren, I.; Gålfalk, M.; Klemedtsson, L.; Crill, P. M.; Danielsson, Å.; Bastviken, D.

    2014-12-01

    Lakes are major sources of methane (CH4) to the atmosphere and it has been shown that lakes contribute significantly to the global CH4 budget. However, the data behind these global estimates are snapshots in time and space only and they typically lack information on spatial and temporal variability of fluxes which can potentially lead to biased estimates. Recent studies have shown that diffusive flux, gas exchange velocity (k), ebullition and concentration of CH4 in the surface water can vary significantly in space within lakes. CH4 fluxes can also change at a broad range of temporal scales in response to seasons, temperature, lake mixing events, short term weather events like pressure variations, shifting winds and diel cycles. We sampled CH4 fluxes and surface water concentrations from three lakes of differing characteristics in southwest Sweden over two annual cycles, approximately every 14 days from April to October 2012 and from April to November 2013. CH4 fluxes were measured using floating chambers distributed in the lakes based on depth categories and dissolved CH4 concentrations were determined by a headspace equilibration method. We observed significant differences in CH4 concentration, diffusion, ebullition and total fluxes between and within the lakes. The fluxes increased exponentially with temperature in all three lakes and water temperature, for example, explained 53-78% of variations in total fluxes in the lakes. Based on our data which relied on improved spatial and temporal information, we demonstrate that measurements which do not take into account of the spatial variability in the lakes could substantially bias the whole lake estimates. For instance, in one of the lakes, measurements from the central parts of the lake represented only 58% of our estimates from all chambers on an average. In addition, we consider how intensive sampling in one season of the year may affect the annual estimates due to the complex interaction of temperature, air pressure and lake mixing events on CH4 fluxes. For example, samples collected when the average air temperatures during chamber deployments were above 15 °C overestimated the total fluxes by 17-157% in all lakes when compared to averages from all measurement times.

  15. The inverse Numerical Computer Program FLUX-BOT for estimating Vertical Water Fluxes from Temperature Time-Series.

    NASA Astrophysics Data System (ADS)

    Trauth, N.; Schmidt, C.; Munz, M.

    2016-12-01

    Heat as a natural tracer to quantify water fluxes between groundwater and surface water has evolved to a standard hydrological method. Typically, time series of temperatures in the surface water and in the sediment are observed and are subsequently evaluated by a vertical 1D representation of heat transport by advection and dispersion. Several analytical solutions as well as their implementation into user-friendly software exist in order to estimate water fluxes from the observed temperatures. Analytical solutions can be easily implemented but assumptions on the boundary conditions have to be made a priori, e.g. sinusoidal upper temperature boundary. Numerical models offer more flexibility and can handle temperature data which is characterized by irregular variations such as storm-event induced temperature changes and thus cannot readily be incorporated in analytical solutions. This also reduced the effort of data preprocessing such as the extraction of the diurnal temperature variation. We developed a software to estimate water FLUXes Based On Temperatures- FLUX-BOT. FLUX-BOT is a numerical code written in MATLAB which is intended to calculate vertical water fluxes in saturated sediments, based on the inversion of measured temperature time series observed at multiple depths. It applies a cell-centered Crank-Nicolson implicit finite difference scheme to solve the one-dimensional heat advection-conduction equation. Besides its core inverse numerical routines, FLUX-BOT includes functions visualizing the results and functions for performing uncertainty analysis. We provide applications of FLUX-BOT to generic as well as to measured temperature data to demonstrate its performance.

  16. Evaluation of new flux attribution methods for mapping N2O emissions at the landscape scale from EC measurements

    NASA Astrophysics Data System (ADS)

    Grossel, Agnes; Bureau, Jordan; Loubet, Benjamin; Laville, Patricia; Massad, Raia; Haas, Edwin; Butterbach-Bahl, Klaus; Guimbaud, Christophe; Hénault, Catherine

    2017-04-01

    The objective of this study was to develop and evaluate an attribution method based on a combination of Eddy Covariance (EC) and chamber measurements to map N2O emissions over a 3-km2 area of croplands and forests in France. During 2 months of spring 2015, N2O fluxes were measured (i) by EC at 15 m height and (ii) punctually with a mobile chamber at 16 places within 1-km of EC mast. The attribution method was based on coupling the EC measurements, information on footprints (Loubet et al., 20101) and emission ratios based on crops and fertilizations, calculated based on chamber measurements. The results were evaluated against an independent flux dataset measured by automatic chambers in a wheat field within the area. At the landscape scale, the method estimated a total emission of 114-271 kg N-N2O during the campaign. This new approach allowed estimating continuously N2O emission and better accounting for the spatial variability of N2O emission at the landscape scale.

  17. Determining Accuracy of Thermal Dissipation Methods-based Sap Flux in Japanese Cedar Trees

    NASA Astrophysics Data System (ADS)

    Su, Man-Ping; Shinohara, Yoshinori; Laplace, Sophie; Lin, Song-Jin; Kume, Tomonori

    2017-04-01

    Thermal dissipation method, one kind of sap flux measurement method that can estimate individual tree transpiration, have been widely used because of its low cost and uncomplicated operation. Although thermal dissipation method is widespread, the accuracy of this method is doubted recently because some tree species materials in previous studies were not suitable for its empirical formula from Granier due to difference of wood characteristics. In Taiwan, Cryptomeria japonica (Japanese cedar) is one of the dominant species in mountainous area, quantifying the transpiration of Japanese cedar trees is indispensable to understand water cycling there. However, no one have tested the accuracy of thermal dissipation methods-based sap flux for Japanese cedar trees in Taiwan. Thus, in this study we conducted calibration experiment using twelve Japanese cedar stem segments from six trees to investigate the accuracy of thermal dissipation methods-based sap flux in Japanese cedar trees in Taiwan. By pumping water from segment bottom to top and inserting probes into segments to collect data simultaneously, we compared sap flux densities calculated from real water uptakes (Fd_actual) and empirical formula (Fd_Granier). Exact sapwood area and sapwood depth of each sample were obtained from dying segment with safranin stain solution. Our results showed that Fd_Granier underestimated 39 % of Fd_actual across sap flux densities ranging from 10 to 150 (cm3m-2s-1); while applying sapwood depth corrected formula from Clearwater, Fd_Granier became accurately that only underestimated 0.01 % of Fd_actual. However, when sap flux densities ranging from 10 to 50 (cm3m-2s-1)which is similar with the field data of Japanese cedar trees in a mountainous area of Taiwan, Fd_Granier underestimated 51 % of Fd_actual, and underestimated 26 % with applying Clearwater sapwood depth corrected formula. These results suggested sapwood depth significantly impacted on the accuracy of thermal dissipation method; hence, careful determination of sapwood depth is the key for the accurate transpiration estimates. This study also apply the derived results to long-term field data in the mountainous area in Taiwan.

  18. Atmospheric mercury in Changbai Mountain area, northeastern China II. The distribution of reactive gaseous mercury and particulate mercury and mercury deposition fluxes.

    PubMed

    Wan, Qi; Feng, Xinbin; Lu, Julia; Zheng, Wei; Song, Xinjie; Li, Ping; Han, Shijie; Xu, Hao

    2009-08-01

    Reactive gaseous mercury (RGM) and particulate mercury (Hgp) concentrations in ambient air from a remote site at Changbai Mountain area in northeastern China were intermittently monitored from August 2005 to July 2006 totaling 93 days representing fall, winter-spring and summer season, respectively. Rainwater and snow samples were collected during a whole year, and total mercury (THg) in rain samples were used to calculate wet depositional flux. A throughfall method and a model method were used to estimate dry depositional flux. Results showed mean concentrations of RGM and Hgp are 65 and 77 pg m(-3). Compared to background concentrations of atmospheric mercury species in Northern Hemisphere, RGM and Hgp are significantly elevated in Changbai area. Large values for standard deviation indicated fast reactivity and a low residence time for these mercury species. Seasonal variability is also important, with lower mercury levels in summer compared to other seasons, which is attributed to scavenging by rainfall and low local mercury emissions in summer. THg concentrations ranged from 11.5 to 15.9 ng L(-1) in rainwater samples and 14.9-18.6 ng L(-1) in throughfall samples. Wet depositional flux in Changbai area is calculated to be 8.4 microg m(-2) a(-1), and dry deposition flux is estimated to be 16.5 microg m(-2) a(-1) according to a throughfall method and 20.2 microg m(-2) a(-1) using a model method.

  19. Mapping land water and energy balance relations through conditional sampling of remote sensing estimates of atmospheric forcing and surface states

    NASA Astrophysics Data System (ADS)

    Farhadi, Leila; Entekhabi, Dara; Salvucci, Guido

    2016-04-01

    In this study, we develop and apply a mapping estimation capability for key unknown parameters that link the surface water and energy balance equations. The method is applied to the Gourma region in West Africa. The accuracy of the estimation method at point scale was previously examined using flux tower data. In this study, the capability is scaled to be applicable with remotely sensed data products and hence allow mapping. Parameters of the system are estimated through a process that links atmospheric forcing (precipitation and incident radiation), surface states, and unknown parameters. Based on conditional averaging of land surface temperature and moisture states, respectively, a single objective function is posed that measures moisture and temperature-dependent errors solely in terms of observed forcings and surface states. This objective function is minimized with respect to parameters to identify evapotranspiration and drainage models and estimate water and energy balance flux components. The uncertainty of the estimated parameters (and associated statistical confidence limits) is obtained through the inverse of Hessian of the objective function, which is an approximation of the covariance matrix. This calibration-free method is applied to the mesoscale region of Gourma in West Africa using multiplatform remote sensing data. The retrievals are verified against tower-flux field site data and physiographic characteristics of the region. The focus is to find the functional form of the evaporative fraction dependence on soil moisture, a key closure function for surface and subsurface heat and moisture dynamics, using remote sensing data.

  20. An analysis and implications of alternative methods of deriving the density (WPL) terms for eddy covariance flux measurements

    Treesearch

    W. J. Massman; J. -P. Tuovinen

    2006-01-01

    We explore some of the underlying assumptions used to derive the density or WPL terms (Webb et al. (1980) Quart J RoyMeteorol Soc 106:85-100) required for estimating the surface exchange fluxes by eddy covariance. As part of this effort we recast the origin of the density terms as an assumption regarding the density fluctuations rather than as a (dry air) flux...

  1. Estimates of evapotranspiration in alkaline scrub and meadow communities of Owens Valley, California, using the Bowen-ratio, eddy-correlation, and Penman-combination methods

    USGS Publications Warehouse

    Duell, L. F. W.

    1988-01-01

    In Owens Valley, evapotranspiration (ET) is one of the largest components of outflow in the hydrologic budget and the least understood. ET estimates for December 1983 through October 1985 were made for seven representative locations selected on the basis of geohydrology and the characteristics of phreatophytic alkaline scrub and meadow communities. The Bowen-ratio, eddy-correlation, and Penman-combination methods were used to estimate ET. The results of the analyses appear satisfactory when compared to other estimates of ET. Results by the eddy-correlation method are for a direct and a residual latent-heat flux that is based on sensible-heat flux and energy budget measurements. Penman-combination potential ET estimates were determined to be unusable because they overestimated actual ET. Modification in the psychrometer constant of this method to account for differences between heat-diffusion resistance and vapor-diffusion resistance permitted actual ET to be estimated. The methods may be used for studies in similar semiarid and arid rangeland areas in the Western United States. Meteorological data for three field sites are included in the appendix. Simple linear regression analysis indicates that ET estimates are correlated to air temperature, vapor-density deficit, and net radiation. Estimates of annual ET range from 300 mm at a low-density scrub site to 1,100 mm at a high-density meadow site. The monthly percentage of annual ET was determined to be similar for all sites studied. (Author 's abstract)

  2. Estimation of Surface Heat Flux and Surface Temperature during Inverse Heat Conduction under Varying Spray Parameters and Sample Initial Temperature

    PubMed Central

    Aamir, Muhammad; Liao, Qiang; Zhu, Xun; Aqeel-ur-Rehman; Wang, Hong

    2014-01-01

    An experimental study was carried out to investigate the effects of inlet pressure, sample thickness, initial sample temperature, and temperature sensor location on the surface heat flux, surface temperature, and surface ultrafast cooling rate using stainless steel samples of diameter 27 mm and thickness (mm) 8.5, 13, 17.5, and 22, respectively. Inlet pressure was varied from 0.2 MPa to 1.8 MPa, while sample initial temperature varied from 600°C to 900°C. Beck's sequential function specification method was utilized to estimate surface heat flux and surface temperature. Inlet pressure has a positive effect on surface heat flux (SHF) within a critical value of pressure. Thickness of the sample affects the maximum achieved SHF negatively. Surface heat flux as high as 0.4024 MW/m2 was estimated for a thickness of 8.5 mm. Insulation effects of vapor film become apparent in the sample initial temperature range of 900°C causing reduction in surface heat flux and cooling rate of the sample. A sensor location near to quenched surface is found to be a better choice to visualize the effects of spray parameters on surface heat flux and surface temperature. Cooling rate showed a profound increase for an inlet pressure of 0.8 MPa. PMID:24977219

  3. Improving Global Net Surface Heat Flux with Ocean Reanalysis

    NASA Astrophysics Data System (ADS)

    Carton, J.; Chepurin, G. A.; Chen, L.; Grodsky, S.

    2017-12-01

    This project addresses the current level of uncertainty in surface heat flux estimates. Time mean surface heat flux estimates provided by atmospheric reanalyses differ by 10-30W/m2. They are generally unbalanced globally, and have been shown by ocean simulation studies to be incompatible with ocean temperature and velocity measurements. Here a method is presented 1) to identify the spatial and temporal structure of the underlying errors and 2) to reduce them by exploiting hydrographic observations and the analysis increments produced by an ocean reanalysis using sequential data assimilation. The method is applied to fluxes computed from daily state variables obtained from three widely used reanalyses: MERRA2, ERA-Interim, and JRA-55, during an eight year period 2007-2014. For each of these seasonal heat flux errors/corrections are obtained. In a second set of experiments the heat fluxes are corrected and the ocean reanalysis experiments are repeated. This second round of experiments shows that the time mean error in the corrected fluxes is reduced to within ±5W/m2 over the interior subtropical and midlatitude oceans, with the most significant changes occuring over the Southern Ocean. The global heat flux imbalance of each reanalysis is reduced to within a few W/m2 with this single correction. Encouragingly, the corrected forms of the three sets of fluxes are also shown to converge. In the final discussion we present experiments beginning with a modified form of the ERA-Int reanalysis, produced by the DAKKAR program, in which state variables have been individually corrected based on independent measurements. Finally, we discuss the separation of flux error from model error.

  4. Mantle Volatiles and Global Carbon Flux and Budget

    NASA Astrophysics Data System (ADS)

    Zhang, Y.

    2014-12-01

    The global volcanic carbon flux to the surface of Earth is a fundamental parameter in understanding the global carbon cycle that includes deep carbon as well as the degassing history of the mantle. The flux has been estimated before (e.g., Marty and Tolstikhin, 1998). Recent progress has significantly revised some of the parameters used in the estimation, e.g., the oceanic 3He flux has been re-evaluated (Bianchi et al., 2010) to be only about half of the earlier widely-used estimate, and numerous subaerial volcanic degassing data are now available. In this report, a new attempt is made to assess the global carbon flux and budget. Rather than dividing the carbon flux by categories of MORB, Plumes and Arcs, we estimate the global carbon flux by considering oceanic and subaerial volcanism. The oceanic 3He flux is 527±102 mol/yr (Bianchi et al., 2010). Most of the flux is from spreading ridges with only minor contributions from submarine oceanic hotspots or arc volcanism. Hence, the mean CO2/3He ratio in MORB is applied to estimate oceanic flux of CO2. The subaerial CO2 flux is based on evaluation of different arc segments and is messier to compute. Literature estimates use estimated SO2 flux in the last tens of years combined with estimated CO2/SO2 degassing ratios (Hilton et al., 2002; Fischer, 2008). Assuming that the last tens of years are representative of recent geological times in terms of volcanic degassing, the estimated global CO2 flux still depends critically on a couple of arcs that are main contributors of the subaerial volcanic CO2 flux, and those seem to have been rather loosely constrained before. Using recently available data (although there are still holes), we derive a new global subaerial volcanic CO2 flux. By combining with oceanic volcanic CO2 flux, we obtain at a new global flux. The significance of the new estimate to the global volatile budget will be discussed.

  5. Carbon Flux to the Atmosphere from Land-Use Changes 1850-2005 (NDP-050)

    DOE Data Explorer

    Houghton, Robert [Woods Hole Research Center, Falmouth, MA (United States)

    2008-01-01

    The methods and data sources used to derive this time series of flux estimates are described in Houghton (1999, 2003), Houghton and Hackler (1995), and Houghton et al. (1983). In summary, this database provides estimates of regional and global net carbon fluxes, on a year-by-year basis from 1850 through 2005, resulting from changes in land use (such as harvesting of forest products and clearing for agriculture), taking into account not only the initial removal and oxidation of the carbon in the vegetation, but also subsequent regrowth and changes in soil carbon. The net flux of carbon to the atmosphere from changes in land use from 1850 to 2005 was modeled as a function of documented land-use change and changes in aboveground and belowground carbon following changes in land use.

  6. The Estimation of Surface Latent Heat Flux over the Ocean and its Relationship to Marine Atmospheric Boundary Layer (MABL) Structure

    NASA Technical Reports Server (NTRS)

    Palm, Stephen P.; Schwemmer, Geary K.; Vandemark, Doug; Evans, Keith; Miller, David O.; Demoz, Belay B.; Starr, David OC. (Technical Monitor)

    2001-01-01

    A new technique combining active and passive remote sensing instruments for the estimation of surface latent heat flux over the ocean is presented. This synergistic method utilizes aerosol lidar backscatter data, multi-channel infrared radiometer data, and microwave scatterometer data acquired onboard the NASA P-313 research aircraft during an extended field campaign over the Atlantic ocean in support of the Lidar In-space Technology Experiment (LITE) in September of 1994. The 10 meter wind speed derived from scatterometers and lidar-radiometer inferred near-surface moisture are used to obtain an estimate of the surface flux of moisture via a bulk aerodynamic formula. The results are compared with the Special Sensor Microwave Imager (SSM/I) daily average latent heat flux and show reasonable agreement. However, the SSM/I values are biased low by about 15 W/sq m. In addition, the Marine Atmospheric Boundary Layer (MABL) height, entrainment zone thickness and integrated lidar backscatter intensity are computed from the lidar data and compared with the magnitude of the surface fluxes. The results show that the surface latent heat flux is most strongly correlated with entrainment zone depth, MABL height and the integrated MABL lidar backscatter, with corresponding correlation coefficients of 0.39, 0.43 and 0.71, respectively.

  7. The Estimation of Surface Latent Heat Flux Over the Ocean and its Relationship to Marine Atmospheric Boundary Layer (MABL) Structure

    NASA Technical Reports Server (NTRS)

    Palm, Stephen P.; Miller, David O.; Schwemmer, Geary

    2000-01-01

    A new technique combining active and passive remote sensing instruments for the estimation of surface latent heat flux over the ocean is presented. This synergistic method uses aerosol lidar backscatter data, multi-channel infrared radiometer data and microwave scatterometer data acquired onboard the NASA P-3B research aircraft during an extended field campaign over the Atlantic ocean in support of the Lidar In-space Technology Experiment (LITE) in September of 1994. The 10 meter wind speed derived from the scatterometers and the lidar-radiometer inferred near-surface moisture are used to obtain an estimate of the surface flux of moisture via bulk aerodynamic formulae. The results are compared with the Special Sensor Microwave Imager (SSM/I) daily average latent heat flux and show reasonable agreement with an rms error and bias of about 50 and 25 W per square meters, respectively. In addition, the MABL height, entrainment zone thickness and integrated lidar backscatter intensity are computed from the lidar data and compared with the magnitude of the surface fluxes. The results show that the surface latent heat flux is most strongly correlated with entrainment zone top, bottom and the integrated MABL lidar backscatter, with corresponding correlation coefficients of 0.62, 0.67 and 0.61, respectively.

  8. Flux density calibration in diffuse optical tomographic systems.

    PubMed

    Biswas, Samir Kumar; Rajan, Kanhirodan; Vasu, Ram M

    2013-02-01

    The solution of the forward equation that models the transport of light through a highly scattering tissue material in diffuse optical tomography (DOT) using the finite element method gives flux density (Φ) at the nodal points of the mesh. The experimentally measured flux (Umeasured) on the boundary over a finite surface area in a DOT system has to be corrected to account for the system transfer functions (R) of various building blocks of the measurement system. We present two methods to compensate for the perturbations caused by R and estimate true flux density (Φ) from Umeasuredcal. In the first approach, the measurement data with a homogeneous phantom (Umeasuredhomo) is used to calibrate the measurement system. The second scheme estimates the homogeneous phantom measurement using only the measurement from a heterogeneous phantom, thereby eliminating the necessity of a homogeneous phantom. This is done by statistically averaging the data (Umeasuredhetero) and redistributing it to the corresponding detector positions. The experiments carried out on tissue mimicking phantom with single and multiple inhomogeneities, human hand, and a pork tissue phantom demonstrate the robustness of the approach.

  9. Estimating Turbulent Surface Fluxes from Small Unmanned Aircraft: Evaluation of Current Abilities

    NASA Astrophysics Data System (ADS)

    de Boer, G.; Lawrence, D.; Elston, J.; Cassano, J. J.; Mack, J.; Wildmann, N.; Nigro, M. A.; Ivey, M.; Wolfe, D. E.; Muschinski, A.

    2014-12-01

    Heat transfer between the atmosphere and Earth's surface represents a key component to understanding Earth energy balance, making it important in understanding and simulating climate. Arguably, the oceanic air-sea interface and Polar sea-ice-air interface are amongst the most challenging in which to measure these fluxes. This difficulty results partially from challenges associated with infrastructure deployment on these surfaces and partially from an inability to obtain spatially representative values over a potentially inhomogeneous surface. Traditionally sensible (temperature) and latent (moisture) fluxes are estimated using one of several techniques. A preferred method involves eddy-correlation where cross-correlation between anomalies in vertical motion (w) and temperature (T) or moisture (q) is used to estimate heat transfer. High-frequency measurements of these quantities can be derived using tower-mounted instrumentation. Such systems have historically been deployed over land surfaces or on ships and buoys to calculate fluxes at the air-land or air-sea interface, but such deployments are expensive and challenging to execute, resulting in a lack of spatially diverse measurements. A second ("bulk") technique involves the observation of horizontal windspeed, temperature and moisture at a given altitude over an extended time period in order to estimate the surface fluxes. Small Unmanned Aircraft Systems (sUAS) represent a unique platform from which to derive these fluxes. These sUAS can be small ( 1 m), lightweight ( 700 g), low cost ( $2000) and relatively easy to deploy to remote locations and over inhomogeneous surfaces. We will give an overview of the ability of sUAS to provide measurements necessary for estimating surface turbulent fluxes. This discussion is based on flights in the vicinity of the 1000 ft. Boulder Atmospheric Observatory (BAO) tower, and over the US Department of Energy facility at Oliktok Point, Alaska. We will present initial comparisons between UAS-derived turbulent fluxes and those derived from tower-based instrumentation and discuss differences in the context of sensor technology and flight patterns employed to collect data.

  10. A comparison of top-down and bottom-up carbon dioxide fluxes in the UK using a multi-platform measurement network.

    NASA Astrophysics Data System (ADS)

    White, Emily; Rigby, Matt; O'Doherty, Simon; Stavert, Ann; Lunt, Mark; Nemitz, Eiko; Helfter, Carole; Allen, Grant; Pitt, Joe; Bauguitte, Stéphane; Levy, Pete; van Oijen, Marcel; Williams, Mat; Smallman, Luke; Palmer, Paul

    2016-04-01

    Having a comprehensive understanding, on a countrywide scale, of both biogenic and anthropogenic CO2 emissions is essential for knowing how best to reduce anthropogenic emissions and for understanding how the terrestrial biosphere is responding to global fossil fuel emissions. Whilst anthropogenic CO2 flux estimates are fairly well constrained, fluxes from biogenic sources are not. This work will help to verify existing anthropogenic emissions inventories and give a better understanding of biosphere - atmosphere CO2 exchange. Using an innovative top-down inversion scheme; a hierarchical Bayesian Markov Chain Monte Carlo approach with reversible jump "trans-dimensional" basis function selection, we aim to find emissions estimates for biogenic and anthropogenic sources simultaneously. Our approach allows flux uncertainties to be derived more comprehensively than previous methods, and allows the resolved spatial scales in the solution to be determined using the data. We use atmospheric CO2 mole fraction data from the UK Deriving Emissions related to Climate Change (DECC) and Greenhouse gAs UK and Global Emissions (GAUGE) projects. The network comprises of 6 tall tower sites, flight campaigns and a ferry transect along the east coast, and enables us to derive high-resolution monthly flux estimates across the UK and Ireland for the period 2013-2015. We have derived UK total fluxes of 675 PIC 78 Tg/yr during January 2014 (seasonal maximum) and 23 PIC 96 Tg/yr during May 2014 (seasonal minimum). Our disaggregated anthropogenic and biogenic flux estimates are compared to a new high-resolution time resolved anthropogenic inventory that will underpin future UNFCCC reports by the UK, and to DALEC carbon cycle model. This allows us to identify where significant differences exist between these "bottom-up" and "top-down" flux estimates and suggest reasons for discrepancies. We will highlight the strengths and limitations of the UK's CO2 emissions verification infrastructure at present and outline improvements that could be made in the future.

  11. Comparison of three methods to derive canopy-scale flux measurements above a mixed oak and hornbeam forest in Northern Italy

    NASA Astrophysics Data System (ADS)

    Acton, William; Schallhart, Simon; Langford, Ben; Valach, Amy; Rantala, Pekka; Fares, Silvano; Carriero, Giulia; Mentel, Thomas; Tomlinson, Sam; Dragosits, Ulrike; Hewitt, Nicholas; Nemitz, Eiko

    2015-04-01

    Plants emit a wide range of Biogenic Volatile Organic Compounds (BVOCs) into the atmosphere. These BVOCs are a major source of reactive carbon into the troposphere and play an important role in atmospheric chemistry by, for example, acting as an OH sink and contributing to the formation of secondary organic aerosol. While the emission rates of some of these compounds are relatively well understood, large uncertainties are still associated with the emission estimates of many compounds. Here the fluxes and mixing ratios of BVOCs recorded during June/July 2012 over the Bosco Fontana forest reserve in northern Italy are reported and discussed, together with a comparison of three methods of flux calculation. This work was carried out as a part of the EC FP7 project ECLAIRE (Effects of Climate Change on Air Pollution and Response Strategies for European Ecosystems). The Bosco Fontana reserve is a semi natural deciduous forest dominated by Carpinus betulus (hornbeam), Quercus robur (pedunculate oak) and Quercus rubra (northern red oak). Virtual disjunct eddy covariance measurements made using Proton Transfer Reaction-Mass Spectrometry (PTR-MS) and Proton Transfer Reaction-Time of Flight-Mass Spectrometry (PTR-ToF-MS) were used to calculate fluxes and mixing ratios of BVOCs above the forest canopy at Bosco Fontana. BVOC mixing ratios were dominated by methanol with acetaldehyde, acetone, acetic acid, isoprene, the sum of methyl vinyl ketone and methacrolein, methyl ethyl ketone and monoterpenes also recorded. A large flux of isoprene was observed as well as significant fluxes of monoterpenes, methanol, acetaldehyde and methyl vinyl ketone / methacrolein. The fluxes recorded using the PTR-MS and PTR-ToF-MS showed good agreement. Comparison of the isoprene fluxes calculated using these instruments also agreed well with fluxes modelled using the MEGAN algorithms (Guenther et al. 2006). The detailed tree distribution maps for the forest at Bosco Fontana compiled by Dalponte et al. 2007 enable the estimation of flux from leaf level emissions data. This 'bottom up' estimate will be compared with the fluxes recorded using PTR-MS and PTR-ToF-MS. References Dalponte M., Gianelle D. and Bruzzone L.: Use of hyperspectral and LIDAR data for classification of complex forest areas. Canopy Analysis and Dynamics of a Floodplain Forest: 25-37, 2007 Guenther A., Karl T., Harley P., Wiedinmyer C., Palmer P.I. and Geron C.: Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature). Atmospheric Chemistry and Physics, 6, 3180-3210, 2006

  12. A Method to Constrain Genome-Scale Models with 13C Labeling Data

    PubMed Central

    García Martín, Héctor; Kumar, Vinay Satish; Weaver, Daniel; Ghosh, Amit; Chubukov, Victor; Mukhopadhyay, Aindrila; Arkin, Adam; Keasling, Jay D.

    2015-01-01

    Current limitations in quantitatively predicting biological behavior hinder our efforts to engineer biological systems to produce biofuels and other desired chemicals. Here, we present a new method for calculating metabolic fluxes, key targets in metabolic engineering, that incorporates data from 13C labeling experiments and genome-scale models. The data from 13C labeling experiments provide strong flux constraints that eliminate the need to assume an evolutionary optimization principle such as the growth rate optimization assumption used in Flux Balance Analysis (FBA). This effective constraining is achieved by making the simple but biologically relevant assumption that flux flows from core to peripheral metabolism and does not flow back. The new method is significantly more robust than FBA with respect to errors in genome-scale model reconstruction. Furthermore, it can provide a comprehensive picture of metabolite balancing and predictions for unmeasured extracellular fluxes as constrained by 13C labeling data. A comparison shows that the results of this new method are similar to those found through 13C Metabolic Flux Analysis (13C MFA) for central carbon metabolism but, additionally, it provides flux estimates for peripheral metabolism. The extra validation gained by matching 48 relative labeling measurements is used to identify where and why several existing COnstraint Based Reconstruction and Analysis (COBRA) flux prediction algorithms fail. We demonstrate how to use this knowledge to refine these methods and improve their predictive capabilities. This method provides a reliable base upon which to improve the design of biological systems. PMID:26379153

  13. Coastal ocean and shelf-sea biogeochemical cycling of trace elements and isotopes: lessons learned from GEOTRACES

    PubMed Central

    Lam, Phoebe J.; Lohan, Maeve C.; Kwon, Eun Young; Hatje, Vanessa; Shiller, Alan M.; Cutter, Gregory A.; Thomas, Alex; Milne, Angela; Thomas, Helmuth; Andersson, Per S.; Porcelli, Don; Tanaka, Takahiro; Geibert, Walter; Dehairs, Frank; Garcia-Orellana, Jordi

    2016-01-01

    Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES programme as well as a proof of concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium (T1/2 = 5.75 yr), which is continuously supplied to the shelf from coastal aquifers, sediment porewater exchange and rivers. Model-derived shelf 228Ra fluxes are combined with TEI/ 228Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn and Zn inputs and exceed published estimates of atmospheric deposition by factors of approximately 3–23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving shelf-derived TEI fluxes to the ocean. This article is part of the themed issue ‘Biological and climatic impacts of ocean trace element chemistry’. PMID:29035267

  14. Coastal ocean and shelf-sea biogeochemical cycling of trace elements and isotopes: lessons learned from GEOTRACES

    NASA Astrophysics Data System (ADS)

    Charette, Matthew A.; Lam, Phoebe J.; Lohan, Maeve C.; Kwon, Eun Young; Hatje, Vanessa; Jeandel, Catherine; Shiller, Alan M.; Cutter, Gregory A.; Thomas, Alex; Boyd, Philip W.; Homoky, William B.; Milne, Angela; Thomas, Helmuth; Andersson, Per S.; Porcelli, Don; Tanaka, Takahiro; Geibert, Walter; Dehairs, Frank; Garcia-Orellana, Jordi

    2016-11-01

    Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES programme as well as a proof of concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium (T1/2 = 5.75 yr), which is continuously supplied to the shelf from coastal aquifers, sediment porewater exchange and rivers. Model-derived shelf 228Ra fluxes are combined with TEI/ 228Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn and Zn inputs and exceed published estimates of atmospheric deposition by factors of approximately 3-23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving shelf-derived TEI fluxes to the ocean. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.

  15. Coastal ocean and shelf-sea biogeochemical cycling of trace elements and isotopes: lessons learned from GEOTRACES.

    PubMed

    Charette, Matthew A; Lam, Phoebe J; Lohan, Maeve C; Kwon, Eun Young; Hatje, Vanessa; Jeandel, Catherine; Shiller, Alan M; Cutter, Gregory A; Thomas, Alex; Boyd, Philip W; Homoky, William B; Milne, Angela; Thomas, Helmuth; Andersson, Per S; Porcelli, Don; Tanaka, Takahiro; Geibert, Walter; Dehairs, Frank; Garcia-Orellana, Jordi

    2016-11-28

    Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES programme as well as a proof of concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium ( T 1/2  = 5.75 yr), which is continuously supplied to the shelf from coastal aquifers, sediment porewater exchange and rivers. Model-derived shelf 228 Ra fluxes are combined with TEI/ 228 Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn and Zn inputs and exceed published estimates of atmospheric deposition by factors of approximately 3-23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving shelf-derived TEI fluxes to the ocean.This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'. © 2015 The Authors.

  16. A simplified method for power-law modelling of metabolic pathways from time-course data and steady-state flux profiles.

    PubMed

    Kitayama, Tomoya; Kinoshita, Ayako; Sugimoto, Masahiro; Nakayama, Yoichi; Tomita, Masaru

    2006-07-17

    In order to improve understanding of metabolic systems there have been attempts to construct S-system models from time courses. Conventionally, non-linear curve-fitting algorithms have been used for modelling, because of the non-linear properties of parameter estimation from time series. However, the huge iterative calculations required have hindered the development of large-scale metabolic pathway models. To solve this problem we propose a novel method involving power-law modelling of metabolic pathways from the Jacobian of the targeted system and the steady-state flux profiles by linearization of S-systems. The results of two case studies modelling a straight and a branched pathway, respectively, showed that our method reduced the number of unknown parameters needing to be estimated. The time-courses simulated by conventional kinetic models and those described by our method behaved similarly under a wide range of perturbations of metabolite concentrations. The proposed method reduces calculation complexity and facilitates the construction of large-scale S-system models of metabolic pathways, realizing a practical application of reverse engineering of dynamic simulation models from the Jacobian of the targeted system and steady-state flux profiles.

  17. Evaluations of carbon fluxes estimated by top-down and bottom-up approaches

    NASA Astrophysics Data System (ADS)

    Murakami, K.; Sasai, T.; Kato, S.; Hiraki, K.; Maksyutov, S. S.; Yokota, T.; Nasahara, K.; Matsunaga, T.

    2013-12-01

    There are two types of estimating carbon fluxes using satellite observation data, and these are referred to as top-down and bottom-up approaches. Many uncertainties are however still remain in these carbon flux estimations, because the true values of carbon flux are still unclear and estimations vary according to the type of the model (e.g. a transport model, a process based model) and input data. The CO2 fluxes in these approaches are estimated by using different satellite data such as the distribution of CO2 concentration in the top-down approach and the land cover information (e.g. leaf area, surface temperature) in the bottom-up approach. The satellite-based CO2 flux estimations with reduced uncertainty can be used efficiently for identifications of large emission area and carbon stocks of forest area. In this study, we evaluated the carbon flux estimates from two approaches by comparing with each other. The Greenhouse gases Observing SATellite (GOSAT) has been observing atmospheric CO2 concentrations since 2009. GOSAT L4A data product is the monthly CO2 flux estimations for 64 sub-continental regions and is estimated by using GOSAT FTS SWIR L2 XCO2 data and atmospheric tracer transport model. We used GOSAT L4A CO2 flux as top-down approach estimations and net ecosystem productions (NEP) estimated by the diagnostic type biosphere model BEAMS as bottom-up approach estimations. BEAMS NEP is only natural land CO2 flux, so we used GOSAT L4A CO2 flux after subtraction of anthropogenic CO2 emissions and oceanic CO2 flux. We compared with two approach in temperate north-east Asia region. This region is covered by grassland and crop land (about 60 %), forest (about 20 %) and bare ground (about 20 %). The temporal variation for one year period was indicated similar trends between two approaches. Furthermore we show the comparison of CO2 flux estimations in other sub-continental regions.

  18. Volatiles and energy released by Puracé volcano

    NASA Astrophysics Data System (ADS)

    Maldonado, Luisa Fernanda Meza; Inguaggiato, Salvatore; Jaramillo, Marco Tulio; Valencia, Gustavo Garzón; Mazot, Agnes

    2017-12-01

    Total CO2 output of Puracé volcano (Colombia) was estimated on the basis of fluids discharged by fumaroles, soil gases, and dissolved carbon species in the aquifer. The soil CO2 emission was computed from a field survey of 512 points of CO2 soil flux measurements at the main degassing areas of Puracé volcano. The CO2 flux from Puracé's plume was estimated using an indirect method, that used the SO2 plume flux and CO2/SO2 ratio of the main high temperature fumarole. The total output of CO2 was estimated at ≅ 1500 t/day. The main contribution of CO2 comes from the plume (summit degassing) and from soil degassing that emit 673 and 812 t/day, respectively. The contributions of summit and soil degassing areas are comparable, indicating an intermediate degassing style partitioned between closed and open conduit systems. The estimated water vapor discharge (as derived from the chemical composition of the fumaroles, the H2O/CO2 ratio, and the SO2 plume flux) allowed calculation of the total thermal energy (fumarolic, soil degassing, and aquifer) released from the Puracé volcanic system. This was 360 MW.

  19. Comparison of methods for quantifying surface sublimation over seasonally snow-covered terrain

    USGS Publications Warehouse

    Sexstone, Graham A.; Clow, David W.; Stannard, David I.; Fassnacht, Steven R.

    2016-01-01

    Snow sublimation can be an important component of the snow-cover mass balance, and there is considerable interest in quantifying the role of this process within the water and energy balance of snow-covered regions. In recent years, robust eddy covariance (EC) instrumentation has been used to quantify snow sublimation over snow-covered surfaces in complex mountainous terrain. However, EC can be challenging for monitoring turbulent fluxes in snow-covered environments because of intensive data, power, and fetch requirements, and alternative methods of estimating snow sublimation are often relied upon. To evaluate the relative merits of methods for quantifying surface sublimation, fluxes calculated by the EC, Bowen ratio–energy balance (BR), bulk aerodynamic flux (BF), and aerodynamic profile (AP) methods and their associated uncertainty were compared at two forested openings in the Colorado Rocky Mountains. Biases between methods are evaluated over a range of environmental conditions, and limitations of each method are discussed. Mean surface sublimation rates from both sites ranged from 0.33 to 0.36 mm day−1, 0.14 to 0.37 mm day−1, 0.10 to 0.17 mm day−1, and 0.03 to 0.10 mm day−1 for the EC, BR, BF and AP methods, respectively. The EC and/or BF methods are concluded to be superior for estimating surface sublimation in snow-covered forested openings. The surface sublimation rates quantified in this study are generally smaller in magnitude compared with previously published studies in this region and help to refine sublimation estimates for forested openings in the Colorado Rocky Mountains.

  20. Volatile Outputs From Subduction-Related Magmatism in the Oregon Cascades Estimated From Melt Inclusions, Spring Discharges, Heat Flow Data and Geochronology

    NASA Astrophysics Data System (ADS)

    Wallace, P.; Ruscitto, D.; Rowe, M.; Kent, A.

    2008-12-01

    Estimates of volatile fluxes provide a primary test for models of magmatism and volatile cycling during subduction in the endmember "hot and dry" Cascadia subduction zone, which is caused by slow convergence (4 cm/a) of the young (~10-12 Ma) Juan de Fuca plate with Western North America. Intra- arc rifting in the Central Oregon segment of the Cascade arc during the past 2 Ma has caused this region to have the highest mafic output along the arc. However, estimates of major volatile (H2O, CO2, S, Cl) fluxes and comparisons with other arcs (e.g. Central America) are not straightforward because there are no passively degassing volcanoes in the area. We estimate volatile outputs for the Central Oregon Cascades by combining data for olivine-hosted melt inclusions with regional heat flow (e.g. Ingebritsen, 1989; Blackwell,1990) and geochronological (Sherrod and Smith, 1990) studies. These flux estimates can be compared with those obtained from spring water studies (e.g. James, 1999; Hurwitz, 2005). This multidisciplinary approach allows us to more accurately constrain volatile fluxes, given that uncertainties in all methods are large and difficult to evaluate. Reported fluxes for Central Oregon springs are 3.4E5 CO2 and 1.5E4 Cl kg/yr/km of arc (James, 1999; Hurwitz, 2005). Melt inclusion data indicate primitive basaltic magmas in the Central Oregon Cascades have 1.0-3.5 wt% H2O, 800-1900 ppm S, and 300-1100 ppm Cl. Assuming global arc magma CO2 contents of ~1 wt% (Wallace, 2005), we estimate H2O/CO2 (1.0-3.5), S/CO2 (0.08-0.19), and Cl/CO2 (0.03-0.11) in magmas, which when combined with spring CO2 estimates, yield an H2O flux of 0.34-1.2E6, a S flux of 2.6-6.5E4, and a Cl flux of 1.0-3.7E4 kg/yr/km of arc. Alternatively, by combining melt inclusion data with magma flux estimates (14-38 km3/Myr/km of arc; Ingebritsen et al. 1989; Sherrod and Smith 1990) we estimate volatile fluxes for H2O: 0.39-5.4E6; S: 0.39-3.9E5; and Cl: 0.16- 2.3E5 kg/yr/km of arc. Given the uncertainties involved, these are highly consistent with the estimates based on spring data. For comparison, Central Oregon S and CO2 fluxes are 6-31% and 13-80%, respectively, of the fluxes estimated for the Central American arc on a kg/yr/km of arc basis (Sadofsky, 2008; Hilton, 1992). Comparison of Central Oregon volatile outputs with slab inputs (Ito, 1983; Hilton, 1992; Jarrard, 2003) suggests low recycling efficiencies via magmatism for H2O (3-26%) and S (1-7%) and more variable recycling efficiencies for CO2 (9-55%) and Cl (9-87%). Low volatile recycling efficiencies via magmatism are consistent with both the high temperatures estimated for the subducted slab beneath the Cascades and the presence of a shallow reservoir for early devolatilized material in the serpentinized forearc mantle wedge. Low but non-zero recycling efficiencies could indicate that 1) slab devolatilization beneath the forearc is incomplete and/or 2) downdragging of the serpentinized forearc mantle by corner flow in the mantle wedge is significant in this hot arc setting.

  1. How to choose methods for lake greenhouse gas flux measurements?

    NASA Astrophysics Data System (ADS)

    Bastviken, David

    2017-04-01

    Lake greenhouse gas (GHG) fluxes are increasingly recognized as important for lake ecosystems as well as for large scale carbon and GHG budgets. However, many of our flux estimates are uncertain and it can be discussed if the presently available data is representative for the systems studied or not. Data are also very limited for some important flux pathways. Hence, many ongoing efforts try to better constrain fluxes and understand flux regulation. A fundamental challenge towards improved knowledge and when starting new studies is what methods to choose. A variety of approaches to measure aquatic GHG exchange is used and data from different methods and methodological approaches have often been treated as equally valid to create large datasets for extrapolations and syntheses. However, data from different approaches may cover different flux pathways or spatio-temporal domains and are thus not always comparable. Method inter-comparisons and critical method evaluations addressing these issues are rare. Emerging efforts to organize systematic multi-lake monitoring networks for GHG fluxes leads to method choices that may set the foundation for decades of data generation and therefore require fundamental evaluation of different approaches. The method choices do not only regard the equipment but also for example consideration of overall measurement design and field approaches, relevant spatial and temporal resolution for different flux components, and accessory variables to measure. In addition, consideration of how to design monitoring approaches being affordable, suitable for widespread (global) use, and comparable across regions is needed. Inspired by discussions with Prof. Dr. Cristian Blodau during the EGU General Assembly 2016, this presentation aims to (1) illustrate fundamental pros and cons for a number of common methods, (2) show how common methodological approaches originally adapted for other environments can be improved for lake flux measurements, (3) suggest how consideration of spatio-temporal dimensions of flux variability can lead to more optimized approaches, and (4) highlight possibilities of efficient ways forward including low-cost technologies that has potential for world-wide use.

  2. Linking Air Quality and Watershed Models for Environmental Assessments: Analysis of the Effects of Model-Specific Precipitation Estimates on Calculated Water Flux

    EPA Science Inventory

    Directly linking air quality and watershed models could provide an effective method for estimating spatially-explicit inputs of atmospheric contaminants to watershed biogeochemical models. However, to adequately link air and watershed models for wet deposition estimates, each mod...

  3. Lidar and Hyperspectral Remote Sensing for the Analysis of Coniferous Biomass Stocks and Fluxes

    NASA Astrophysics Data System (ADS)

    Halligan, K. Q.; Roberts, D. A.

    2006-12-01

    Airborne lidar and hyperspectral data can improve estimates of aboveground carbon stocks and fluxes through their complimentary responses to vegetation structure and biochemistry. While strong relationships have been demonstrated between lidar-estimated vegetation structural parameters and field data, research is needed to explore the portability of these methods across a range of topographic conditions, disturbance histories, vegetation type and climate. Additionally, research is needed to evaluate contributions of hyperspectral data in refining biomass estimates and determination of fluxes. To address these questions we are a conducting study of lidar and hyperspectral remote sensing data across sites including coniferous forests, broadleaf deciduous forests and a tropical rainforest. Here we focus on a single study site, Yellowstone National Park, where tree heights, stem locations, above ground biomass and basal area were mapped using first-return small-footprint lidar data. A new method using lidar intensity data was developed for separating the terrain and vegetation components in lidar data using a two-scale iterative local minima filter. Resulting Digital Terrain Models (DTM) and Digital Canopy Models (DCM) were then processed to retrieve a diversity of vertical and horizontal structure metrics. Univariate linear models were used to estimate individual tree heights while stepwise linear regression was used to estimate aboveground biomass and basal area. Three small-area field datasets were compared for their utility in model building and validation of vegetation structure parameters. All structural parameters were linearly correlated with lidar-derived metrics, with higher accuracies obtained where field and imagery data were precisely collocated . Initial analysis of hyperspectral data suggests that vegetation health metrics including measures of live and dead vegetation and stress indices may provide good indicators of carbon flux by mapping vegetation vigor or senescence. Additionally, the strength of hyperspectral data for vegetation classification suggests these data have additional utility for modeling carbon flux dynamics by allowing more accurate plant functional type mapping.

  4. Synthesizing Global and Local Datasets to Estimate Jurisdictional Forest Carbon Fluxes in Berau, Indonesia.

    PubMed

    Griscom, Bronson W; Ellis, Peter W; Baccini, Alessandro; Marthinus, Delon; Evans, Jeffrey S; Ruslandi

    2016-01-01

    Forest conservation efforts are increasingly being implemented at the scale of sub-national jurisdictions in order to mitigate global climate change and provide other ecosystem services. We see an urgent need for robust estimates of historic forest carbon emissions at this scale, as the basis for credible measures of climate and other benefits achieved. Despite the arrival of a new generation of global datasets on forest area change and biomass, confusion remains about how to produce credible jurisdictional estimates of forest emissions. We demonstrate a method for estimating the relevant historic forest carbon fluxes within the Regency of Berau in eastern Borneo, Indonesia. Our method integrates best available global and local datasets, and includes a comprehensive analysis of uncertainty at the regency scale. We find that Berau generated 8.91 ± 1.99 million tonnes of net CO2 emissions per year during 2000-2010. Berau is an early frontier landscape where gross emissions are 12 times higher than gross sequestration. Yet most (85%) of Berau's original forests are still standing. The majority of net emissions were due to conversion of native forests to unspecified agriculture (43% of total), oil palm (28%), and fiber plantations (9%). Most of the remainder was due to legal commercial selective logging (17%). Our overall uncertainty estimate offers an independent basis for assessing three other estimates for Berau. Two other estimates were above the upper end of our uncertainty range. We emphasize the importance of including an uncertainty range for all parameters of the emissions equation to generate a comprehensive uncertainty estimate-which has not been done before. We believe comprehensive estimates of carbon flux uncertainty are increasingly important as national and international institutions are challenged with comparing alternative estimates and identifying a credible range of historic emissions values.

  5. Data-based estimates of the ocean carbon sink variability - first results of the Surface Ocean pCO2 Mapping intercomparison (SOCOM)

    NASA Astrophysics Data System (ADS)

    Rödenbeck, C.; Bakker, D. C. E.; Gruber, N.; Iida, Y.; Jacobson, A. R.; Jones, S.; Landschützer, P.; Metzl, N.; Nakaoka, S.; Olsen, A.; Park, G.-H.; Peylin, P.; Rodgers, K. B.; Sasse, T. P.; Schuster, U.; Shutler, J. D.; Valsala, V.; Wanninkhof, R.; Zeng, J.

    2015-08-01

    Using measurements of the surface-ocean CO2 partial pressure (pCO2) and 14 different pCO2 mapping methods recently collated by the Surface Ocean pCO2 Mapping intercomparison (SOCOM) initiative, variations in regional and global sea-air CO2 fluxes have been investigated. Though the available mapping methods use widely different approaches, we find relatively consistent estimates of regional pCO2 seasonality, in line with previous estimates. In terms of interannual variability (IAV), all mapping methods estimate the largest variations to occur in the Eastern equatorial Pacific. Despite considerable spead in the detailed variations, mapping methods with closer match to the data also tend to be more consistent with each other. Encouragingly, this includes mapping methods belonging to complementary types - taking variability either directly from the pCO2 data or indirectly from driver data via regression. From a weighted ensemble average, we find an IAV amplitude of the global sea-air CO2 flux of 0.31 PgC yr-1 (standard deviation over 1992-2009), which is larger than simulated by biogeochemical process models. On a decadal perspective, the global CO2 uptake is estimated to have gradually increased since about 2000, with little decadal change prior to 2000. The weighted mean total ocean CO2 sink estimated by the SOCOM ensemble is consistent within uncertainties with estimates from ocean-interior carbon data or atmospheric oxygen trends.

  6. Satellite Estimates of Surface Short-wave Fluxes: Issues of Implementation

    NASA Technical Reports Server (NTRS)

    Wang, H.; Pinker, Rachel; Minnis, Patrick

    2006-01-01

    Surface solar radiation reaching the Earth's surface is the primary forcing function of the land surface energy and water cycle. Therefore, there is a need for information on this parameter, preferably, at global scale. Satellite based estimates are now available at accuracies that meet the demands of many scientific objectives. Selection of an approach to estimate such fluxes requires consideration of trade-offs between the use of multi-spectral observations of cloud optical properties that are more difficult to implement at large scales, and methods that are simplified but easier to implement. In this study, an evaluation of such trade-offs will be performed. The University of Maryland Surface Radiation Model (UMD/SRB) has been used to reprocess five years of GOES-8 satellite observations over the United States to ensure updated calibration and improved cloud detection over snow. The UMD/SRB model was subsequently modified to allow input of information on aerosol and cloud optical depth with information from independent satellite sources. Specifically, the cloud properties from the Atmospheric Radiation Measurement (ARM) Satellite Data Analysis Program (Minnis et al., 1995) are used to drive the modified version of the model to estimate surface short-wave fluxes over the Southern Great Plain ARM sites for a twelve month period. The auxiliary data needed as model inputs such as aerosol optical depth, spectral surface albedo, water vapor and total column ozone amount were kept the same for both versions of the model. The estimated shortwave fluxes are evaluated against ground observations at the ARM Central Facility and four satellite ARM sites. During summer, the estimated fluxes based on cloud properties derived from the multi-spectral approach were in better agreement with ground measurements than those derived from the UMD/SRB model. However, in winter, the fluxes derived with the UMD/SRB model were in better agreement with ground observations than those estimated from cloud properties provided by the ARM Satellite Data Analysis Program. During the transition periods, the results were comparable.

  7. Intercomparison of methods for the estimation of displacement height and roughness length from single-level eddy covariance data

    NASA Astrophysics Data System (ADS)

    Graf, Alexander; van de Boer, Anneke; Schüttemeyer, Dirk; Moene, Arnold; Vereecken, Harry

    2013-04-01

    The displacement height d and roughness length z0 are parameters of the logarithmic wind profile and as such these are characteristics of the surface, that are required in a multitude of meteorological modeling applications. Classically, both parameters are estimated from multi-level measurements of wind speed over a terrain sufficiently homogeneous to avoid footprint-induced differences between the levels. As a rule-of thumb, d of a dense, uniform crop or forest canopy is 2/3 to 3/4 of the canopy height h, and z0 about 10% of canopy height in absence of any d. However, the uncertainty of this rule-of-thumb becomes larger if the surface of interest is not "dense and uniform", in which case a site-specific determination is required again. By means of the eddy covariance method, alternative possibilities to determine z0 and d have become available. Various authors report robust results if either several levels of sonic anemometer measurements, or one such level combined with a classic wind profile is used to introduce direct knowledge on the friction velocity into the estimation procedure. At the same time, however, the eddy covariance method to measure various fluxes has superseded the profile method, leaving many current stations without a wind speed profile with enough levels sufficiently far above the canopy to enable the classic estimation of z0 and d. From single-level eddy covariance measurements at one point in time, only one parameter can be estimated, usually z0 while d is assumed to be known. Even so, results tend to scatter considerably. However, it has been pointed out, that the use of multiple points in time providing different stability conditions can enable the estimation of both parameters, if they are assumed constant over the time period regarded. These methods either rely on flux-variance similarity (Weaver 1990 and others following), or on the integrated universal function for momentum (Martano 2000 and others following). In both cases, iterations over the range of possible d values are necessary. We extended this set of methods by a non-iterative, regression based approach. Only a stability range of data is used in which the universal function is known to be approximately linear. Then, various types of multiple linear regression can be used to relate the terms of the logarithmic wind profile equation to each other, and derive z0 and d from the regression parameters. Two examples each of the two existing iterative approaches, and the new non-iterative one are compared to each other and to plausibility limits in three different agricultural crops. The study contains periods of growth as well as of constant crop height, also allowing for an examination of the relations between z0, d, and canopy height. Results indicate that estimated z0 values, even in absence of prescribed d values, are fairly robust, plausible and consistent across all methods. The largest deviations are produced by the two flux-variance similarity based methods. Estimates of d, in contrast, can be subject to implausible deviations with all methods, even after quality-filtering of input data. Again, the largest deviations occur with flux-variance similarity based methods. Ensemble averaging between all methods can reduce this problem, offering a potentially useful way of estimating d at more complex sites where the rule-of-thumb cannot be applied easily. Martano P (2000): Estimation of surface roughness length and displacement height from single-level sonic anemometer data. Journal of Applied Meteorology 39:708-715. Weaver HL (1990): Temperature and Humidity flux-variance relations determined by one-dimensional eddy correlation. Boundary-Layer Meteorology 53:77-91.

  8. Uncertainty analysis of the Operational Simplified Surface Energy Balance (SSEBop) model at multiple flux tower sites

    USGS Publications Warehouse

    Chen, Mingshi; Senay, Gabriel B.; Singh, Ramesh K.; Verdin, James P.

    2016-01-01

    Evapotranspiration (ET) is an important component of the water cycle – ET from the land surface returns approximately 60% of the global precipitation back to the atmosphere. ET also plays an important role in energy transport among the biosphere, atmosphere, and hydrosphere. Current regional to global and daily to annual ET estimation relies mainly on surface energy balance (SEB) ET models or statistical and empirical methods driven by remote sensing data and various climatological databases. These models have uncertainties due to inevitable input errors, poorly defined parameters, and inadequate model structures. The eddy covariance measurements on water, energy, and carbon fluxes at the AmeriFlux tower sites provide an opportunity to assess the ET modeling uncertainties. In this study, we focused on uncertainty analysis of the Operational Simplified Surface Energy Balance (SSEBop) model for ET estimation at multiple AmeriFlux tower sites with diverse land cover characteristics and climatic conditions. The 8-day composite 1-km MODerate resolution Imaging Spectroradiometer (MODIS) land surface temperature (LST) was used as input land surface temperature for the SSEBop algorithms. The other input data were taken from the AmeriFlux database. Results of statistical analysis indicated that the SSEBop model performed well in estimating ET with an R2 of 0.86 between estimated ET and eddy covariance measurements at 42 AmeriFlux tower sites during 2001–2007. It was encouraging to see that the best performance was observed for croplands, where R2 was 0.92 with a root mean square error of 13 mm/month. The uncertainties or random errors from input variables and parameters of the SSEBop model led to monthly ET estimates with relative errors less than 20% across multiple flux tower sites distributed across different biomes. This uncertainty of the SSEBop model lies within the error range of other SEB models, suggesting systematic error or bias of the SSEBop model is within the normal range. This finding implies that the simplified parameterization of the SSEBop model did not significantly affect the accuracy of the ET estimate while increasing the ease of model setup for operational applications. The sensitivity analysis indicated that the SSEBop model is most sensitive to input variables, land surface temperature (LST) and reference ET (ETo); and parameters, differential temperature (dT), and maximum ET scalar (Kmax), particularly during the non-growing season and in dry areas. In summary, the uncertainty assessment verifies that the SSEBop model is a reliable and robust method for large-area ET estimation. The SSEBop model estimates can be further improved by reducing errors in two input variables (ETo and LST) and two key parameters (Kmax and dT).

  9. A gap-filling model for eddy covariance latent heat flux: Estimating evapotranspiration of a subtropical seasonal evergreen broad-leaved forest as an example

    NASA Astrophysics Data System (ADS)

    Chen, Yi-Ying; Chu, Chia-Ren; Li, Ming-Hsu

    2012-10-01

    SummaryIn this paper we present a semi-parametric multivariate gap-filling model for tower-based measurement of latent heat flux (LE). Two statistical techniques, the principal component analysis (PCA) and a nonlinear interpolation approach were integrated into this LE gap-filling model. The PCA was first used to resolve the multicollinearity relationships among various environmental variables, including radiation, soil moisture deficit, leaf area index, wind speed, etc. Two nonlinear interpolation methods, multiple regressions (MRS) and the K-nearest neighbors (KNNs) were examined with random selected flux gaps for both clear sky and nighttime/cloudy data to incorporate into this LE gap-filling model. Experimental results indicated that the KNN interpolation approach is able to provide consistent LE estimations while MRS presents over estimations during nighttime/cloudy. Rather than using empirical regression parameters, the KNN approach resolves the nonlinear relationship between the gap-filled LE flux and principal components with adaptive K values under different atmospheric states. The developed LE gap-filling model (PCA with KNN) works with a RMSE of 2.4 W m-2 (˜0.09 mm day-1) at a weekly time scale by adding 40% artificial flux gaps into original dataset. Annual evapotranspiration at this study site were estimated at 736 mm (1803 MJ) and 728 mm (1785 MJ) for year 2008 and 2009, respectively.

  10. Derivation of the Energy and Flux Morphology in an Aurora Observed at Midlatitude Using Multispectral Imaging

    NASA Astrophysics Data System (ADS)

    Aryal, Saurav; Finn, Susanna C.; Hewawasam, Kuravi; Maguire, Ryan; Geddes, George; Cook, Timothy; Martel, Jason; Baumgardner, Jeffrey L.; Chakrabarti, Supriya

    2018-05-01

    Energies and fluxes of precipitating electrons in an aurora over Lowell, MA on 22-23 June 2015 were derived based on simultaneous, high-resolution (≈ 0.02 nm) brightness measurements of N2+ (427.8 nm, blue line), OI (557.7 nm, green line), and OI (630.0 nm, red line) emissions. The electron energies and energy fluxes as a function of time and look direction were derived by nonlinear minimization of model predictions with respect to the measurements. Three different methods were compared; in the first two methods, we constrained the modeled brightnesses and brightness ratios, respectively, with measurements to simultaneously derive energies and fluxes. Then we used a hybrid method where we constrained the individual modeled brightness ratios with measurements to derive energies and then constrained modeled brightnesses with measurements to derive fluxes. Derived energy, assuming Maxwellian distribution, during this storm ranged from 109 to 262 eV and the total energy flux ranged from 0.8 to 2.2 ergs·cm-2·s-1. This approach provides a way to estimate energies and energy fluxes of the precipitating electrons using simultaneous multispectral measurements.

  11. Study of compact radio sources using interplanetary scintillations at 111 MHz. The Pearson-Readhead sample

    NASA Astrophysics Data System (ADS)

    Tyul'Bashev, S. A.

    2009-01-01

    A complete sample of radio sources has been studied using the interplanetary scintillation method. In total, 32 sources were observed, with scintillations detected in 12 of them. The remaining sources have upper limits for the flux densities of their compact components. Integrated flux densities are estimated for 18 sources.

  12. Flux-Based Deadbeat Control of Induction-Motor Torque

    NASA Technical Reports Server (NTRS)

    Kenny, Barbara H.; Lorenz, Robert D.

    2003-01-01

    An improved method and prior methods of deadbeat direct torque control involve the use of pulse-width modulation (PWM) of applied voltages. The prior methods are based on the use of stator flux and stator current as state variables, leading to mathematical solutions of control equations in forms that do not lend themselves to clear visualization of solution spaces. In contrast, the use of rotor and stator fluxes as the state variables in the present improved method lends itself to graphical representations that aid in understanding possible solutions under various operating conditions. In addition, the present improved method incorporates the superposition of high-frequency carrier signals for use in a motor-self-sensing technique for estimating the rotor shaft angle at any speed (including low or even zero speed) without need for additional shaft-angle-measuring sensors.

  13. Are landscapes buffered to high-frequency climate change? A comparison of sediment fluxes and depositional volumes in the Corinth rift, central Greece, over the past 130 kyrs

    NASA Astrophysics Data System (ADS)

    Watkins, Stephen E.; Whittaker, Alexander C.; Bell, Rebecca E.; McNeill, Lisa C.; Gawthope, Robert L.

    2017-04-01

    Sediment supply is a fundamental control on the stratigraphic record. However, a key question is the extent to which tectonics and climate affect sediment fluxes in time and space. To address this question, estimates of sediment fluxes must be compared with measured sediment volumes within a closed basin, for which the tectonic and climatic boundary conditions are constrained. The Corinth rift, Greece is one of the most actively extending basins on Earth, with modern day extension rates of up to 15 mm/yr. The Gulf of Corinth is a closed system and has periodically become a lake during marine lowstands over the late Pleistocene. We estimated suspended sediment fluxes through time for rivers draining into the Gulf of Corinth using an empirically-derived BQART method. WorldClim climate data, palaeoclimate models and palaeoclimate proxies were used to estimate discharges and temperatures over the last 130 ky. We used high-resolution 2D seismic surveys to interpret three seismic units over this period and we used this data to derive independent time series of basin sedimentary volumes to compare with our sediment input flux estimates. Our results predict total Holocene sediment fluxes into the Corinth Gulf of 20 km3, within a factor of 2 of the measured sediment volume in the central depocentres over this timescale. Sediment fluxes vary spatially around the Gulf, but imply catchment-averaged erosion rates of 0.2 to 0.4 mm/yr. Moreover, BQART predicted sediment fluxes and sedimentation rate measurements both indicate a 25% reduction during the last glacial period compared to the Holocene. At the last glacial maximum mean annual temperatures were lower by 5 degrees, although precipitation was similar, or lower, than present. Consequently, our results demonstrate that sediment export to the basin is sensitive to glacial-interglacial cycles. However, precipitation constraints alone are insufficient to understand sediment flux sensitivity to climate change.

  14. a Borehole-Dilution Method for Quantifying Vertical Darcy Fluxes in the Hyporheic Zone

    NASA Astrophysics Data System (ADS)

    Augustine, S. D.; Annable, M. D.; Cho, J.

    2017-12-01

    The borehole dilution method has consistently and successfully been used for estimating local water fluxes, however, this method can be relatively labor intensive and expensive. The focus of this research is aimed at developing a low-cost, borehole dilution method for quantifying vertical water fluxes in the hyporheic zone at the surface-groundwater interface. This would allow for the deployment of multiple units within a targeted surface water body and thus produce high-resolution, spatially distributed data on the infiltration rates over a short period of time with minimal set-up requirements. The device consists of a 2-inch, inner diameter PVC pipe containing short, screened sections in its upper and lower segments. The working unit is driven into the sediment and acts as a continuous flow reactor creating a pathway between the subsurface pore-water and the overlying surface water where the presence of a hydraulic gradient facilitates vertical movement. We developed a simple electrode and tracer-injection system housed within the unit to inject and measure salt tracer concentrations at the desired intervals while monitoring and storing those measurements using open-source Arduino technology. Preliminary lab and field scale trials provided data that was fit to both zero and first order reaction rate functions for analysis. The field test was conducted over approximately one day within a wet retention basin. The initial results estimated a vertical Darcy flux of 113.5 cm/d. Additional testing over a range of expected Darcy fluxes will be presented along with an evaluation considering enhanced water flow due to the high hydraulic conductivity of the device.

  15. Spatiotemporal variability of water and energy fluxes: TERENO- prealpine hydrometeorological data analysis and inverse modeling with GEOtop and PEST

    NASA Astrophysics Data System (ADS)

    Soltani, M.; Kunstmann, H.; Laux, P.; Mauder, M.

    2016-12-01

    In mountainous and prealpine regions echohydrological processes exhibit rapid changes within short distances due to the complex orography and strong elevation gradients. Water- and energy fluxes between the land surface and the atmosphere are crucial drivers for nearly all ecosystem processes. The aim of this research is to analyze the variability of surface water- and energy fluxes by both comprehensive observational hydrometeorological data analysis and process-based high resolution hydrological modeling for a mountainous and prealpine region in Germany. We particularly focus on the closure of the observed energy balance and on the added value of energy flux observations for parameter estimation in our hydrological model (GEOtop) by inverse modeling using PEST. Our study area is the catchment of the river Rott (55 km2), being part of the TERENO prealpine observatory in Southern Germany, and we focus particularly on the observations during the summer episode May to July 2013. We present the coupling of GEOtop and the parameter estimation tool PEST, which is based on the Gauss-Marquardt-Levenberg method, a gradient-based nonlinear parameter estimation algorithm. Estimation of the surface energy partitioning during the data analysis process revealed that the latent heat flux was considered as the main consumer of available energy. The relative imbalance was largest during nocturnal periods. An energy imbalance was observed at the eddy-covariance site Fendt due to either underestimated turbulent fluxes or overestimated available energy. The calculation of the simulated energy and water balances for the entire catchment indicated that 78% of net radiation leaves the catchment as latent heat flux, 17% as sensible heat, and 5% enters the soil in the form of soil heat flux. 45% of the catchment aggregated precipitation leaves the catchment as discharge and 55% as evaporation. Using the developed GEOtop-PEST interface, the hydrological model is calibrated by comparing simulated and observed discharge, soil moisture and -temperature, sensible-, latent-, and soil heat fluxes. A reasonable quality of fit could be achieved. Uncertainty- and covariance analyses are performed, allowing the derivation of confidence intervals for all estimated parameters.

  16. Gap-filling methods to impute eddy covariance flux data by preserving variance.

    NASA Astrophysics Data System (ADS)

    Kunwor, S.; Staudhammer, C. L.; Starr, G.; Loescher, H. W.

    2015-12-01

    To represent carbon dynamics, in terms of exchange of CO2 between the terrestrial ecosystem and the atmosphere, eddy covariance (EC) data has been collected using eddy flux towers from various sites across globe for more than two decades. However, measurements from EC data are missing for various reasons: precipitation, routine maintenance, or lack of vertical turbulence. In order to have estimates of net ecosystem exchange of carbon dioxide (NEE) with high precision and accuracy, robust gap-filling methods to impute missing data are required. While the methods used so far have provided robust estimates of the mean value of NEE, little attention has been paid to preserving the variance structures embodied by the flux data. Preserving the variance of these data will provide unbiased and precise estimates of NEE over time, which mimic natural fluctuations. We used a non-linear regression approach with moving windows of different lengths (15, 30, and 60-days) to estimate non-linear regression parameters for one year of flux data from a long-leaf pine site at the Joseph Jones Ecological Research Center. We used as our base the Michaelis-Menten and Van't Hoff functions. We assessed the potential physiological drivers of these parameters with linear models using micrometeorological predictors. We then used a parameter prediction approach to refine the non-linear gap-filling equations based on micrometeorological conditions. This provides us an opportunity to incorporate additional variables, such as vapor pressure deficit (VPD) and volumetric water content (VWC) into the equations. Our preliminary results indicate that improvements in gap-filling can be gained with a 30-day moving window with additional micrometeorological predictors (as indicated by lower root mean square error (RMSE) of the predicted values of NEE). Our next steps are to use these parameter predictions from moving windows to gap-fill the data with and without incorporation of potential driver variables of the parameters traditionally used. Then, comparisons of the predicted values from these methods and 'traditional' gap-filling methods (using 12 fixed monthly windows) will be assessed to show the scale of preserving variance. Further, this method will be applied to impute artificially created gaps for analyzing if variance is preserved.

  17. Constraining Night Time Ecosystem Respiration by Inverse Approaches

    NASA Astrophysics Data System (ADS)

    Juang, J.; Stoy, P. C.; Siqueira, M. B.; Katul, G. G.

    2004-12-01

    Estimating nighttime ecosystem respiration remains a key challenge in quantifying ecosystem carbon budgets. Currently, nighttime eddy-covariance (EC) flux measurements are plagued by uncertainties often attributed to poor mixing within the canopy volume, non-turbulent transport of CO2 into and out of the canopy, and non-stationarity and intermittency. Here, we explore the use of second-order closure models to estimate nighttime ecosystem respiration by mathematically linking sources of CO2 to mean concentration profiles via the continuity and the CO2 flux budget equation modified to include thermal stratification. By forcing this model to match, in a root-mean squared sense, the nighttime measured mean CO2 concentration profiles within the canopy the above ground CO2 production and forest floor respiration can be estimated via multi-dimensional optimization techniques. We show that in a maturing pine and a mature hardwood forest, these optimized CO2 sources are (1) consistently larger than the eddy covariance flux measurements above the canopy, and (2) agree well with chamber-based measurements. We also show that by linking the optimized nighttime ecosystem respiration to temperature measurements, the estimated annual ecosystem respiration from this approach agrees well with biometric estimates, at least when compared to eddy-covariance methods conditioned on a friction velocity threshold. The difference between the annual ecosystem respiration obtained by this optimization method and the friction-velocity thresholded night-time EC fluxes can be as large as 700 g C m-2 (in 2003) for the maturing pine forest, which is about 40% of the ecosystem respiration. For 2001 and 2002, the annual ecosystem respiration differences between the EC-based and the proposed approach were on the order of 300 to 400 g C m-2.

  18. South American smoke coverage and flux estimations from the Fire Locating and Modeling of Burning Emissions (FLAMBE') system.

    NASA Astrophysics Data System (ADS)

    Reid, J. S.; Westphal, D. L.; Christopher, S. A.; Prins, E. M.; Gasso, S.; Reid, E.; Theisen, M.; Schmidt, C. C.; Hunter, J.; Eck, T.

    2002-05-01

    The Fire Locating and Modeling of Burning Emissions (FLAMBE') project is a joint Navy, NOAA, NASA and university project to integrate satellite products with numerical aerosol models to produce a real time fire and emissions inventory. At the center of the program is the Wildfire Automated Biomass Burning Algorithm (WF ABBA) which provides real-time fire products and the NRL Aerosol Analysis and Prediction System to model smoke transport. In this presentation we give a brief overview of the system and methods, but emphasize new estimations of smoke coverage and emission fluxes from the South American continent. Temporal and smoke patterns compare reasonably well with AERONET and MODIS aerosol optical depth products for the 2000 and 2001 fire seasons. Fluxes are computed by relating NAAPS output fields and MODIS optical depth maps with modeled wind fields. Smoke emissions and transport fluxes out of the continent can then be estimated by perturbing the modeled emissions to gain agreement with the satellite and wind products. Regional smoke emissions are also presented for grass and forest burning.

  19. The surface renewal method for better spatial resolution of evapotranspiration measurements

    NASA Astrophysics Data System (ADS)

    Suvocarev, K.; Fischer, M.; Massey, J. H.; Reba, M. L.; Runkle, B.

    2017-12-01

    Evaluating feasible irrigation strategies when water is scarce requires measurements or estimations of evapotranspiration (ET). Direct observations of ET from agricultural fields are preferred, and micrometeorological methods such as eddy covariance (EC) provide a high quality, continuous time series of ET. However, when replicates of the measurements are needed to compare irrigation strategies, the cost of such experiments is often prohibitive and limits experimental scope. An alternative micrometeorological approach to ET, the surface renewal (SR) method, may be reduced to a thermocouple and a propeller anemometer (Castellvi and Snyder, 2009). In this case, net radiation, soil and sensible heat flux (H) are measured and latent heat flux (an energy equivalent for ET) is estimated as the residual of the surface energy-balance equation. In our experiment, thermocouples (Type E Fine-Wire Thermocouple, FW3) were deployed next to the EC system and combined with mean horizontal wind speed measurements to obtain H using SR method for three weeks. After compensating the temperature signal for non-ideal frequency response in the wavelet half-plane and correcting the sonic anemometer for the flow distortion (Horst et al., 2015), the SR H fluxes compared well to those measured by EC (r2 = 0.9, slope = 0.92). This result encouraged us to install thermocouples over 16 rice fields under different irrigation treatments (continuous cascade flood, continuous multiple inlet rice irrigation, alternate wetting and drying, and furrow irrigation). The EC measurements with net radiometer and soil heat flux plates are deployed at three of these fields to provide a direct comparison. The measurement campaign will finish soon and the data will be processed to evaluate the SR approach for ET estimation. The results will be used to show better spatial resolution of ET measurements to support irrigation decisions in agricultural crops.

  20. Anisotropic diffusion in mesh-free numerical magnetohydrodynamics

    NASA Astrophysics Data System (ADS)

    Hopkins, Philip F.

    2017-04-01

    We extend recently developed mesh-free Lagrangian methods for numerical magnetohydrodynamics (MHD) to arbitrary anisotropic diffusion equations, including: passive scalar diffusion, Spitzer-Braginskii conduction and viscosity, cosmic ray diffusion/streaming, anisotropic radiation transport, non-ideal MHD (Ohmic resistivity, ambipolar diffusion, the Hall effect) and turbulent 'eddy diffusion'. We study these as implemented in the code GIZMO for both new meshless finite-volume Godunov schemes (MFM/MFV). We show that the MFM/MFV methods are accurate and stable even with noisy fields and irregular particle arrangements, and recover the correct behaviour even in arbitrarily anisotropic cases. They are competitive with state-of-the-art AMR/moving-mesh methods, and can correctly treat anisotropic diffusion-driven instabilities (e.g. the MTI and HBI, Hall MRI). We also develop a new scheme for stabilizing anisotropic tensor-valued fluxes with high-order gradient estimators and non-linear flux limiters, which is trivially generalized to AMR/moving-mesh codes. We also present applications of some of these improvements for SPH, in the form of a new integral-Godunov SPH formulation that adopts a moving-least squares gradient estimator and introduces a flux-limited Riemann problem between particles.

  1. Improving Estimation of Submarine Groundwater Discharge Using Radium and Radon Tracers: Application in Jiaozhou Bay, China

    NASA Astrophysics Data System (ADS)

    Zhang, Yan; Li, Hailong; Xiao, Kai; Wang, Xuejing; Lu, Xiaoting; Zhang, Meng; An, An; Qu, Wenjing; Wan, Li; Zheng, Chunmiao; Wang, Xusheng; Jiang, Xiaowei

    2017-10-01

    Radium and radon mass balance models have been widely used to quantify submarine groundwater discharge (SGD) in the coastal areas. However, the losses of radium or radon in seawater caused by recirculated saline groundwater discharge (RSGD) are ignored in most of the previous studies for tracer-based models and this can lead to an underestimation of SGD. Here we present an improved method which considers the losses of tracers caused by RSGD to enhance accuracy in estimating SGD and SGD-associated material loadings. Theoretical analysis indicates that neglecting the losses of tracers induced by RSGD would underestimate the SGD by a percentage approximately equaling the tracer activity ratio of nearshore seawater to groundwater. The data analysis of previous typical case studies shows that the existing old models underestimated the SGD by 1.9-93%, with an average of 32.2%. The method is applied in Jiaozhou Bay (JZB), North China, which is experiencing significant environmental pollution. The SGD flux into JZB estimated by the improved method is ˜1.44 and 1.34 times of that estimated by the old method for 226Ra mass balance model and 228Ra mass balance model, respectively. Both SGD and RSGD fluxes are significantly higher than the discharge rate of Dagu River (the largest one running into JZB). The fluxes of nutrients and metals through SGD are comparable to or even higher than those from local rivers, which indicates that SGD is an important source of chemicals into JZB and has important impact on marine ecological system.

  2. The HartX-synthesis: An experimental approach to water and carbon exchange of a Scots pine plantation

    NASA Astrophysics Data System (ADS)

    Bernhofer, Ch.; Gay, L. W.; Granier, A.; Joss, U.; Kessler, A.; Köstner, B.; Siegwolf, R.; Tenhunen, J. D.; Vogt, R.

    1996-03-01

    In May 1992 during the interdisciplinary measurement campaign HartX (Hartheim eXperiment), several independent estimates of stand water vapor flux were compared at a 12-m high Scots pine ( Pinus silvestris) plantation on a flat fluvial terrace of the Rhine close to Freiburg, Germany. Weather during the HartX period was characterized by ten consecutive clear days with exceptionally high input of available energy for this time of year and with a slowly shifting diurnal pattern in atmospheric variables like vapor pressure deficit. Methods utilized to quantify components of stand water flux included porometry measurements on understory graminoid leaves and on pine needles and three different techniques for determining individual tree xylem sap flow. Micrometeorological methods included eddy covariance and eddy covariance energy balance techniques with six independent systems on two towers separated by 40 m. Additionally, Bowen ratio energy balance estimates of water flux were conducted and measurements of the gradients in water vapor, CO2, and trace gases within and above the stand were carried out with an additional, portable 30 m high telescoping mast. Biologically-based estimates of overstory transpiration were obtained by up-scaling tree sap flow rates to stand level via cumulative sapwood area. Tree transpiration contributed between 2.2 and 2.6 mm/day to ET for a tree leaf area index (LAI) of 2.8. The pine stand had an understory dominated by sedge and grass species with overall average LAI of 1.5. Mechanistic canopy gas exchange models that quantify both water vapor and CO2 exchange were applied to both understory and tree needle ecosystem compartments. Thus, the transpiration by graminoid species was estimated at approximately 20% of total stand ET. The modelled estimates for understory contribution to stand water flux compared well with micrometeorologically-based determinations. Maximum carbon gain was estimated from the canopy models at approximately 425 mmol/(m2day) for the tree needles and at 100 mmol/(m2day) for the understory. Carbon gain was suggested by the modelling analysis to remain relatively constant during the HartX period, while water use efficiency in carbon fixation increased with decreasing vapor pressure deficit. Biologically- and micrometeorologically-based estimates of stand water flux showed good general agreement with variation of up to 20% that reflects both errors due to the inherent assumptions associated with different methods as well as natural spatial variability in fluxes. The various methods support a reliable estimate of average ET from this homogeneous canopy during HartX of about 2.6 mm/day (a maximum of about 3.1 mm/day) with an insignificant decreasing trend in correlation with decreasing vapor pressure deficit and possibly soil moisture. Findings during HartX were embedded in local scale heterogeneity with greater roughness over the forest and much higher ET over the surrounding agricultural fields which results in weak but clearly existant circulation patterns. A variety of measurements were continued after the HartX campaign. They allow us to extend our findings for six months with changing environmental conditions, including shortage of soil moisture. Hydrological estimates of soil water extractions and micrometeorological estimates of ET by the one-propeller eddy covariance (OPEC) system were in very good agreement, supporting the use of this robust eddy covariance energy balance technique for long-term monitoring.

  3. Mechanistic analysis of multi-omics datasets to generate kinetic parameters for constraint-based metabolic models.

    PubMed

    Cotten, Cameron; Reed, Jennifer L

    2013-01-30

    Constraint-based modeling uses mass balances, flux capacity, and reaction directionality constraints to predict fluxes through metabolism. Although transcriptional regulation and thermodynamic constraints have been integrated into constraint-based modeling, kinetic rate laws have not been extensively used. In this study, an in vivo kinetic parameter estimation problem was formulated and solved using multi-omic data sets for Escherichia coli. To narrow the confidence intervals for kinetic parameters, a series of kinetic model simplifications were made, resulting in fewer kinetic parameters than the full kinetic model. These new parameter values are able to account for flux and concentration data from 20 different experimental conditions used in our training dataset. Concentration estimates from the simplified kinetic model were within one standard deviation for 92.7% of the 790 experimental measurements in the training set. Gibbs free energy changes of reaction were calculated to identify reactions that were often operating close to or far from equilibrium. In addition, enzymes whose activities were positively or negatively influenced by metabolite concentrations were also identified. The kinetic model was then used to calculate the maximum and minimum possible flux values for individual reactions from independent metabolite and enzyme concentration data that were not used to estimate parameter values. Incorporating these kinetically-derived flux limits into the constraint-based metabolic model improved predictions for uptake and secretion rates and intracellular fluxes in constraint-based models of central metabolism. This study has produced a method for in vivo kinetic parameter estimation and identified strategies and outcomes of kinetic model simplification. We also have illustrated how kinetic constraints can be used to improve constraint-based model predictions for intracellular fluxes and biomass yield and identify potential metabolic limitations through the integrated analysis of multi-omics datasets.

  4. Mechanistic analysis of multi-omics datasets to generate kinetic parameters for constraint-based metabolic models

    PubMed Central

    2013-01-01

    Background Constraint-based modeling uses mass balances, flux capacity, and reaction directionality constraints to predict fluxes through metabolism. Although transcriptional regulation and thermodynamic constraints have been integrated into constraint-based modeling, kinetic rate laws have not been extensively used. Results In this study, an in vivo kinetic parameter estimation problem was formulated and solved using multi-omic data sets for Escherichia coli. To narrow the confidence intervals for kinetic parameters, a series of kinetic model simplifications were made, resulting in fewer kinetic parameters than the full kinetic model. These new parameter values are able to account for flux and concentration data from 20 different experimental conditions used in our training dataset. Concentration estimates from the simplified kinetic model were within one standard deviation for 92.7% of the 790 experimental measurements in the training set. Gibbs free energy changes of reaction were calculated to identify reactions that were often operating close to or far from equilibrium. In addition, enzymes whose activities were positively or negatively influenced by metabolite concentrations were also identified. The kinetic model was then used to calculate the maximum and minimum possible flux values for individual reactions from independent metabolite and enzyme concentration data that were not used to estimate parameter values. Incorporating these kinetically-derived flux limits into the constraint-based metabolic model improved predictions for uptake and secretion rates and intracellular fluxes in constraint-based models of central metabolism. Conclusions This study has produced a method for in vivo kinetic parameter estimation and identified strategies and outcomes of kinetic model simplification. We also have illustrated how kinetic constraints can be used to improve constraint-based model predictions for intracellular fluxes and biomass yield and identify potential metabolic limitations through the integrated analysis of multi-omics datasets. PMID:23360254

  5. Quantitative evaluation of high-energy O- ion particle flux in a DC magnetron sputter plasma with an indium-tin-oxide target

    NASA Astrophysics Data System (ADS)

    Suyama, Taku; Bae, Hansin; Setaka, Kenta; Ogawa, Hayato; Fukuoka, Yushi; Suzuki, Haruka; Toyoda, Hirotaka

    2017-11-01

    O- ion flux from the indium tin oxide (ITO) sputter target under Ar ion bombardment is quantitatively evaluated using a calorimetry method. Using a mass spectrometer with an energy analyzer, O- energy distribution is measured with spatial dependence. Directional high-energy O- ion ejected from the target surface is observed. Using a calorimetry method, localized heat flux originated from high-energy O- ion is measured. From absolute evaluation of the heat flux from O- ion, O- particle flux in order of 1018 m-2 s-1 is evaluated at a distance of 10 cm from the target. Production yield of O- ion on the ITO target by one Ar+ ion impingement at a kinetic energy of 244 eV is estimated to be 3.3  ×  10-3 as the minimum value.

  6. Estimates of evapotranspiration in alkaline scrub and meadow communities of Owens Valley, California, using the Bowen-ratio, eddy-correlation, and penman-combination methods

    USGS Publications Warehouse

    Duell, Lowell F. W.

    1990-01-01

    In Owens Valley, evapotranspiration (ET) is one of the largest components of outflow in the hydrologic budget and the least understood. ET estimates for December 1983 through October 1985 were made for seven representative locations selected on the basis of geohydrology and the characteristics of phreatophytic alkaline scrub and meadow communities. The Bowen-ratio, eddy-correlation, and Penman-combination methods were used to estimate ET. The results of the analyses appear satisfactory when compared with other estimates of ET. Results by the eddy-correlation method are for a direct and a residual latent-heat flux that is based on sensible-heat flux and energy-budget measurements. Penman-combination potential-ET estimates were determined to be unusable because they overestimated actual ET. Modification of the psychrometer constant of this method to account for differences between heat-diffusion resistance and vapor-diffusion resistance permitted actual ET to be estimated. The methods described in this report may be used for studies in similar semiarid and arid rangeland areas in the Western United States. Meteorological data for three field sites are included in the appendix of this report. Simple linear regression analysis indicates that ET estimates are correlated to air temperature, vapor-density deficit, and net radiation. Estimates of annual ET range from 301 millimeters at a low-density scrub site to 1,137 millimeters at a high-density meadow site. The monthly percentage of annual ET was determined to be similar for all sites studied.

  7. A method to quantify and value floodplain sediment and nutrient retention ecosystem services

    USGS Publications Warehouse

    Hopkins, Kristina G.; Noe, Gregory; Franco, Fabiano; Pindilli, Emily J.; Gordon, Stephanie; Metes, Marina J.; Claggett, Peter; Gellis, Allen; Hupp, Cliff R.; Hogan, Dianna

    2018-01-01

    Floodplains provide critical ecosystem services to local and downstream communities by retaining floodwaters, sediments, and nutrients. The dynamic nature of floodplains is such that these areas can both accumulate sediment and nutrients through deposition, and export material downstream through erosion. Therefore, estimating floodplain sediment and nutrient retention should consider the net flux of both depositional and erosive processes. An ecosystem services framework was used to quantify and value the sediment and nutrient ecosystem service provided by floodplains in the Difficult Run watershed, a small (151 km2) suburban watershed located in the Piedmont of Virginia (USA). A sediment balance was developed for Difficult Run and two nested watersheds. The balance included upland sediment delivery to streams, stream bank flux, floodplain flux, and stream load. Upland sediment delivery was estimated using geospatial datasets and a modified Revised Universal Soil Loss Equation. Predictive models were developed to extrapolate field measurements of the flux of sediment, sediment-bound nitrogen (N), and sediment-bound phosphorus (P) from stream banks and floodplains to 3232 delineated stream segments in the study area. A replacement cost approach was used to estimate the economic value of the sediment and nutrient retention ecosystem service based on estimated net stream bank and floodplain flux of sediment-bound N for all streams in the study area. Results indicated the net fluvial fluxes of sediment, sediment-bound N, and sediment-bound P were −10,439 Mg yr−1 (net export), 57,300 kg-N yr−1(net trapping), and 98 kg-P yr−1(net trapping), respectively. For sediment, floodplain retention was offset by substantial losses from stream bank erosion, particularly in headwater catchments, resulting in a net export of sediment. Nutrient retention in the floodplain exceeded that lost through stream bank erosion resulting in net retention of nutrients (TN and TP). Using a conservative cost estimate of $12.69 (USD) per kilogram of nitrogen, derived from wastewater treatment costs, the estimated annual value for sediment and nutrient retention on Difficult Run floodplains was $727,226 ± 194,220 USD/yr. Values and differences in floodplain nitrogen retention among stream reaches can be used to target areas for floodplain conservation and stream restoration. The methods presented are scalable and transferable to other areas if appropriate datasets are available for validation.

  8. Methane emissions from termites - landscape level estimates and methods of measurement

    NASA Astrophysics Data System (ADS)

    Jamali, Hizbullah; Livesley, Stephen J.; Hutley, Lindsay B.; Arndt, Stefan K.

    2013-04-01

    Termites contribute between <5 and 19% of the global methane emissions. These estimates have large uncertainties because of the limited number of field-based studies and species investgated, as well as issues of diurnal and seasonal variations. We measured methane fluxes from four common mound-building termite species diurnally and seasonally in tropical savannas in the Northern Territory, Australia. Our results showed that there were significant diel and seasonal variations of methane emissions from termite mounds and we observed large species-specific differences. On a diurnal basis, methane fluxes were least at the coolest time of the day and greatest at the warmest for all species for both wet and dry seasons. We observed a strong and significant positive correlation between methane flux and mound temperature for all species. Fluxes in the wet season were 5-26-fold greater than those in the dry season and this was related to population dynamics of the termites. We observed significant relationships between mound methane flux and mound carbon dioxide flux, enabling the prediction of methane flux from measured carbon dioxide flux. However, these relationships were clearly termite species specific. We also determined significant relationships between mound flux and gas concentration inside mound, for both gases, and for all termite species, thereby enabling the prediction of flux from measured mound internal gas concentration. However, these relationships were also termite species specific. Consequently, there was no generic relationship that would enable an easier prediction of methane flux from termite mounds. On a landscape scale we estimated that termites were a methane source of +0.24 kg methane-C ha-1 year-1 whilst savanna soils were a methane sink of 1.14 kg methane-C ha-1 year-1. Termites therefore only offset 21% of methane consumed by savanna soil resulting in net sink strength of -0.90 kg methane-C ha-1 year-1 for these savannas. Assuming a similar contribution of termites in the savannas and tropical rain forests worldwide, termites would globally produce around 27 Tg CO2-e year-1, which is 0.2% of the global methane source budget or an order of magnitude smaller than many of the previous estimates.

  9. Evaluation of Methods to Estimate the Surface Downwelling Longwave Flux during Arctic Winter

    NASA Technical Reports Server (NTRS)

    Chiacchio, Marc; Francis, Jennifer; Stackhouse, Paul, Jr.

    2002-01-01

    Surface longwave radiation fluxes dominate the energy budget of nighttime polar regions, yet little is known about the relative accuracy of existing satellite-based techniques to estimate this parameter. We compare eight methods to estimate the downwelling longwave radiation flux and to validate their performance with measurements from two field programs in thc Arctic: the Coordinated Eastern Arctic Experiment (CEAREX ) conducted in the Barents Sea during the autumn and winter of 1988, and the Lead Experiment performed in the Beaufort Sea in the spring of 1992. Five of the eight methods were developed for satellite-derived quantities, and three are simple parameterizations based on surface observations. All of the algorithms require information about cloud fraction, which is provided from the NASA-NOAA Television and Infrared Observation Satellite (TIROS) Operational Vertical Sounder (TOVS) polar pathfinder dataset (Path-P): some techniques ingest temperature and moisture profiles (also from Path-P): one-half of the methods assume that clouds are opaque and have a constant geometric thickness of 50 hPa, and three include no thickness information whatsoever. With a somewhat limited validation dataset, the following primary conclusions result: (1) all methods exhibit approximately the same correlations with measurements and rms differences, but the biases range from -34 W sq m (16% of the mean) to nearly 0; (2) the error analysis described here indicates that the assumption of a 50-hPa cloud thickness is too thin by a factor of 2 on average in polar nighttime conditions; (3) cloud-overlap techniques. which effectively increase mean cloud thickness, significantly improve the results; (4) simple Arctic-specific parameterizations performed poorly, probably because they were developed with surface-observed cloud fractions; and (5) the single algorithm that includes an estimate of cloud thickness exhibits the smallest differences from observations.

  10. Monitoring carbon dioxide from space: Retrieval algorithm and flux inversion based on GOSAT data and using CarbonTracker-China

    NASA Astrophysics Data System (ADS)

    Yang, Dongxu; Zhang, Huifang; Liu, Yi; Chen, Baozhang; Cai, Zhaonan; Lü, Daren

    2017-08-01

    Monitoring atmospheric carbon dioxide (CO2) from space-borne state-of-the-art hyperspectral instruments can provide a high precision global dataset to improve carbon flux estimation and reduce the uncertainty of climate projection. Here, we introduce a carbon flux inversion system for estimating carbon flux with satellite measurements under the support of "The Strategic Priority Research Program of the Chinese Academy of Sciences—Climate Change: Carbon Budget and Relevant Issues". The carbon flux inversion system is composed of two separate parts: the Institute of Atmospheric Physics Carbon Dioxide Retrieval Algorithm for Satellite Remote Sensing (IAPCAS), and CarbonTracker-China (CT-China), developed at the Chinese Academy of Sciences. The Greenhouse gases Observing SATellite (GOSAT) measurements are used in the carbon flux inversion experiment. To improve the quality of the IAPCAS-GOSAT retrieval, we have developed a post-screening and bias correction method, resulting in 25%-30% of the data remaining after quality control. Based on these data, the seasonal variation of XCO2 (column-averaged CO2 dry-air mole fraction) is studied, and a strong relation with vegetation cover and population is identified. Then, the IAPCAS-GOSAT XCO2 product is used in carbon flux estimation by CT-China. The net ecosystem CO2 exchange is -0.34 Pg C yr-1 (±0.08 Pg C yr-1), with a large error reduction of 84%, which is a significant improvement on the error reduction when compared with in situ-only inversion.

  11. Comparison of two regression-based approaches for determining nutrient and sediment fluxes and trends in the Chesapeake Bay watershed

    USGS Publications Warehouse

    Moyer, Douglas; Hirsch, Robert M.; Hyer, Kenneth

    2012-01-01

    Nutrient and sediment fluxes and changes in fluxes over time are key indicators that water resource managers can use to assess the progress being made in improving the structure and function of the Chesapeake Bay ecosystem. The U.S. Geological Survey collects annual nutrient (nitrogen and phosphorus) and sediment flux data and computes trends that describe the extent to which water-quality conditions are changing within the major Chesapeake Bay tributaries. Two regression-based approaches were compared for estimating annual nutrient and sediment fluxes and for characterizing how these annual fluxes are changing over time. The two regression models compared are the traditionally used ESTIMATOR and the newly developed Weighted Regression on Time, Discharge, and Season (WRTDS). The model comparison focused on answering three questions: (1) What are the differences between the functional form and construction of each model? (2) Which model produces estimates of flux with the greatest accuracy and least amount of bias? (3) How different would the historical estimates of annual flux be if WRTDS had been used instead of ESTIMATOR? One additional point of comparison between the two models is how each model determines trends in annual flux once the year-to-year variations in discharge have been determined. All comparisons were made using total nitrogen, nitrate, total phosphorus, orthophosphorus, and suspended-sediment concentration data collected at the nine U.S. Geological Survey River Input Monitoring stations located on the Susquehanna, Potomac, James, Rappahannock, Appomattox, Pamunkey, Mattaponi, Patuxent, and Choptank Rivers in the Chesapeake Bay watershed. Two model characteristics that uniquely distinguish ESTIMATOR and WRTDS are the fundamental model form and the determination of model coefficients. ESTIMATOR and WRTDS both predict water-quality constituent concentration by developing a linear relation between the natural logarithm of observed constituent concentration and three explanatory variables—the natural log of discharge, time, and season. ESTIMATOR uses two additional explanatory variables—the square of the log of discharge and time-squared. Both models determine coefficients for variables for a series of estimation windows. ESTIMATOR establishes variable coefficients for a series of 9-year moving windows; all observed constituent concentration data within the 9-year window are used to establish each coefficient. Conversely, WRTDS establishes variable coefficients for each combination of discharge and time using only observed concentration data that are similar in time, season, and discharge to the day being estimated. As a result of these distinguishing characteristics, ESTIMATOR reproduces concentration-discharge relations that are closely approximated by a quadratic or linear function with respect to both the log of discharge and time. Conversely, the linear model form of WRTDS coupled with extensive model windowing for each combination of discharge and time allows WRTDS to reproduce observed concentration-discharge relations that are more sinuous in form. Another distinction between ESTIMATOR and WRTDS is the reporting of uncertainty associated with the model estimates of flux and trend. ESTIMATOR quantifies the standard error of prediction associated with the determination of flux and trends. The standard error of prediction enables the determination of the 95-percent confidence intervals for flux and trend as well as the ability to test whether the reported trend is significantly different from zero (where zero equals no trend). Conversely, WRTDS is unable to propagate error through the many (over 5,000) models for unique combinations of flow and time to determine a total standard error. As a result, WRTDS flux estimates are not reported with confidence intervals and a level of significance is not determined for flow-normalized fluxes. The differences between ESTIMATOR and WRTDS, with regard to model form and determination of model coefficients, have an influence on the determination of nutrient and sediment fluxes and associated changes in flux over time as a result of management activities. The comparison between the model estimates of flux and trend was made for combinations of five water-quality constituents at nine River Input Monitoring stations. The major findings with regard to nutrient and sediment fluxes are as follows: (1)WRTDS produced estimates of flux for all combinations that were more accurate, based on reduction in root mean squared error, than flux estimates from ESTIMATOR; (2) for 67 percent of the combinations, WRTDS and ESTIMATOR both produced estimates of flux that were minimally biased compared to observed fluxes(flux bias = tendency to over or underpredict flux observations); however, for 33 percent of the combinations, WRTDS produced estimates of flux that were considerably less biased (by at least 10 percent) than flux estimates from ESTIMATOR; (3) the average percent difference in annual fluxes generated by ESTIMATOR and WRTDS was less than 10 percent at 80 percent of the combinations; and (4) the greatest differences related to flux bias and annual fluxes all occurred for combinations where the pattern in observed concentration-discharge relation was sinuous (two points of inflection) rather than linear or quadratic (zero or one point of inflection). The major findings with regard to trends are as follows: (1) both models produce water-quality trends that have factored in the year-to-year variations in flow; (2) trends in water-quality condition are represented by ESTIMATOR as a trend in flow-adjusted concentration and by WRTDS as a flow normalized flux; (3) for 67 percent of the combinations with trend estimates, the WRTDS trends in flow-normalized flux are in the same direction and magnitude to the ESTIMATOR trends in flow-adjusted concentration, and at the remaining 33 percent the differences in trend magnitude and direction are related to fundamental differences between concentration and flux; and (4) the majority (85 percent) of the total nitrogen, nitrate, and orthophosphorus combinations exhibited long-term (1985 to 2010) trends in WRTDS flow-normalized flux that indicate improvement or reduction in associated flux and the majority (83 percent) of the total phosphorus (from 1985 to 2010) and suspended sediment (from 2001 to 2010) combinations exhibited trends in WRTDS flow-normalized flux that indicate degradation or increases in the flux delivered.

  12. Flux Sampling Errors for Aircraft and Towers

    NASA Technical Reports Server (NTRS)

    Mahrt, Larry

    1998-01-01

    Various errors and influences leading to differences between tower- and aircraft-measured fluxes are surveyed. This survey is motivated by reports in the literature that aircraft fluxes are sometimes smaller than tower-measured fluxes. Both tower and aircraft flux errors are larger with surface heterogeneity due to several independent effects. Surface heterogeneity may cause tower flux errors to increase with decreasing wind speed. Techniques to assess flux sampling error are reviewed. Such error estimates suffer various degrees of inapplicability in real geophysical time series due to nonstationarity of tower time series (or inhomogeneity of aircraft data). A new measure for nonstationarity is developed that eliminates assumptions on the form of the nonstationarity inherent in previous methods. When this nonstationarity measure becomes large, the surface energy imbalance increases sharply. Finally, strategies for obtaining adequate flux sampling using repeated aircraft passes and grid patterns are outlined.

  13. Comparison of ammonia emissions determined using different sampling methods

    USDA-ARS?s Scientific Manuscript database

    Dynamic, flow-through flux chambers are sometimes used to estimate ammonia emissions from livestock operations; however, ammonia emissions from the surfaces are affected by many factors which can be affected by the chamber. Ammonia emissions estimated using environmental flow-through chambers may be...

  14. Exchange across the sediment-water interface quantified from porewater radon profiles

    NASA Astrophysics Data System (ADS)

    Cook, Peter G.; Rodellas, Valentí; Andrisoa, Aladin; Stieglitz, Thomas C.

    2018-04-01

    Water recirculation through permeable sediments induced by wave action, tidal pumping and currents enhances the exchange of solutes and fine particles between sediments and overlying waters, and can be an important hydro-biogeochemical process. In shallow water, most of the recirculation is likely to be driven by the interaction of wave-driven oscillatory flows with bottom topography which can induce pressure fluctuations at the sediment-water interface on very short timescales. Tracer-based methods provide the most reliable means for characterizing this short-timescale exchange. However, the commonly applied approaches only provide a direct measure of the tracer flux. Estimating water fluxes requires characterizing the tracer concentration in discharging porewater; this implies collecting porewater samples at shallow depths (usually a few mm, depending on the hydrodynamic dispersivity), which is very difficult with commonly used techniques. In this study, we simulate observed vertical profiles of radon concentration beneath shallow coastal lagoons using a simple water recirculation model that allows us to estimate water exchange fluxes as a function of depth below the sediment-water interface. Estimated water fluxes at the sediment water interface at our site were 0.18-0.25 m/day, with fluxes decreasing exponentially with depth. Uncertainty in dispersivity is the greatest source of error in exchange flux, and results in an uncertainty of approximately a factor-of-five.

  15. Are Low-order Covariance Estimates Useful in Error Analyses?

    NASA Astrophysics Data System (ADS)

    Baker, D. F.; Schimel, D.

    2005-12-01

    Atmospheric trace gas inversions, using modeled atmospheric transport to infer surface sources and sinks from measured concentrations, are most commonly done using least-squares techniques that return not only an estimate of the state (the surface fluxes) but also the covariance matrix describing the uncertainty in that estimate. Besides allowing one to place error bars around the estimate, the covariance matrix may be used in simulation studies to learn what uncertainties would be expected from various hypothetical observing strategies. This error analysis capability is routinely used in designing instrumentation, measurement campaigns, and satellite observing strategies. For example, Rayner, et al (2002) examined the ability of satellite-based column-integrated CO2 measurements to constrain monthly-average CO2 fluxes for about 100 emission regions using this approach. Exact solutions for both state vector and covariance matrix become computationally infeasible, however, when the surface fluxes are solved at finer resolution (e.g., daily in time, under 500 km in space). It is precisely at these finer scales, however, that one would hope to be able to estimate fluxes using high-density satellite measurements. Non-exact estimation methods such as variational data assimilation or the ensemble Kalman filter could be used, but they achieve their computational savings by obtaining an only approximate state estimate and a low-order approximation of the true covariance. One would like to be able to use this covariance matrix to do the same sort of error analyses as are done with the full-rank covariance, but is it correct to do so? Here we compare uncertainties and `information content' derived from full-rank covariance matrices obtained from a direct, batch least squares inversion to those from the incomplete-rank covariance matrices given by a variational data assimilation approach solved with a variable metric minimization technique (the Broyden-Fletcher- Goldfarb-Shanno algorithm). Two cases are examined: a toy problem in which CO2 fluxes for 3 latitude bands are estimated for only 2 time steps per year, and for the monthly fluxes for 22 regions across 1988-2003 solved for in the TransCom3 interannual flux inversion of Baker, et al (2005). The usefulness of the uncertainty estimates will be assessed as a function of the number of minimization steps used in the variational approach; this will help determine whether they will also be useful in the high-resolution cases that we would most like to apply the non-exact methods to. Baker, D.F., et al., TransCom3 inversion intercomparison: Impact of transport model errors on the interannual variability of regional CO2 fluxes, 1988-2003, Glob. Biogeochem. Cycles, doi:10.1029/2004GB002439, 2005, in press. Rayner, P.J., R.M. Law, D.M. O'Brien, T.M. Butler, and A.C. Dilley, Global observations of the carbon budget, 3, Initial assessment of the impact of satellite orbit, scan geometry, and cloud on measuring CO2 from space, J. Geophys. Res., 107(D21), 4557, doi:10.1029/2001JD000618, 2002.

  16. Comparison of sea surface flux measured by instrumented aircraft and ship during SOFIA and SEMAPHORE experiments

    NASA Astrophysics Data System (ADS)

    Durand, Pierre; Dupuis, HéLèNe; Lambert, Dominique; BéNech, Bruno; Druilhet, Aimé; Katsaros, Kristina; Taylor, Peter K.; Weill, Alain

    1998-10-01

    Two major campaigns (Surface of the Oceans, Fluxes and Interactions with the Atmosphere (SOFIA) and Structure des Echanges Mer-Atmosphère, Propriétés des Hétérogénéités Océaniques: Recherche Expérimentale (SEMAPHORE)) devoted to the study of ocean-atmosphere interaction were conducted in 1992 and 1993, respectively, in the Azores region. Among the various platforms deployed, instrumented aircraft and ship allowed the measurement of the turbulent flux of sensible heat, latent heat, and momentum. From coordinated missions we can evaluate the sea surface fluxes from (1) bulk relations and mean measurements performed aboard the ship in the atmospheric surface layer and (2) turbulence measurements aboard aircraft, which allowed the flux profiles to be estimated through the whole atmospheric boundary layer and therefore to be extrapolated toward the sea surface level. Continuous ship fluxes were calculated with bulk coefficients deduced from inertial-dissipation measurements in the same experiments, whereas aircraft fluxes were calculated with eddy-correlation technique. We present a comparison between these two estimations. Although momentum flux agrees quite well, aircraft estimations of sensible and latent heat flux are lower than those of the ship. This result is surprising, since aircraft momentum flux estimates are often considered as much less accurate than scalar flux estimates. The various sources of errors on the aircraft and ship flux estimates are discussed. For sensible and latent heat flux, random errors on aircraft estimates, as well as variability of ship flux estimates, are lower than the discrepancy between the two platforms, whereas the momentum flux estimates cannot be considered as significantly different. Furthermore, the consequence of the high-pass filtering of the aircraft signals on the flux values is analyzed; it is weak at the lowest altitudes flown and cannot therefore explain the discrepancies between the two platforms but becomes considerable at upper levels in the boundary layer. From arguments linked to the imbalance of the surface energy budget, established during previous campaigns performed over land surfaces with aircraft, we conclude that aircraft heat fluxes are probably also underestimated over the sea.

  17. Storage flux uncertainty impact on eddy covariance net ecosystem exchange measurements

    NASA Astrophysics Data System (ADS)

    Nicolini, Giacomo; Aubinet, Marc; Feigenwinter, Christian; Heinesch, Bernard; Lindroth, Anders; Mamadou, Ossénatou; Moderow, Uta; Mölder, Meelis; Montagnani, Leonardo; Rebmann, Corinna; Papale, Dario

    2017-04-01

    Complying with several assumption and simplifications, most of the carbon budget studies based on eddy covariance (EC) measurements, quantify the net ecosystem exchange (NEE) by summing the flux obtained by EC (Fc) and the storage flux (Sc). Sc is the rate of change of CO2, within the so called control volume below the EC measurement level, given by the difference in the instantaneous profiles of concentration at the beginning and end of the EC averaging period, divided by the averaging period. While cumulating over time led to a nullification of Sc, it can be significant at short time periods. The approaches used to estimate Sc fluxes largely vary, from measurements based only on a single sampling point (usually located at the EC measurement height) to measurements based on several sampling profiles distributed within the control volume. Furthermore, the number of sampling points within each profile vary, according to their height and the ecosystem typology. It follows that measurement accuracy increases with the sampling intensity within the control volume. In this work we use the experimental dataset collected during the ADVEX campaign in which Sc flux has been measured in three similar forest sites by the use of 5 sampling profiles (towers). Our main objective is to quantify the impact of Sc measurement uncertainty on NEE estimates. Results show that different methods may produce substantially different Sc flux estimates, with problematic consequences in case high frequency (half-hourly) data are needed for the analysis. However, the uncertainty on long-term estimates may be tolerate.

  18. Estimated infiltration, percolation, and recharge rates at the Rillito Creek focused recharge investigation site, Pima County, Arizona: Chapter H in Ground-water recharge in the arid and semiarid southwestern United States (Professional Paper 1703)

    USGS Publications Warehouse

    Hoffmann, John P.; Blasch, Kyle W.; Pool, Don R.; Bailey, Matthew A.; Callegary, James B.; Stonestrom, David A.; Constantz, Jim; Ferré, Ty P.A.; Leake, Stanley A.

    2007-01-01

    A large fraction of ground water stored in the alluvial aquifers in the Southwest is recharged by water that percolates through ephemeral stream-channel deposits. The amount of water currently recharging many of these aquifers is insufficient to meet current and future demands. Improving the understanding of streambed infiltration and the subsequent redistribution of water within the unsaturated zone is fundamental to quantifying and forming an accurate description of streambed recharge. In addition, improved estimates of recharge from ephemeral-stream channels will reduce uncertainties in water-budget components used in current ground-water models.This chapter presents a summary of findings related to a focused recharge investigation along Rillito Creek in Tucson, Arizona. A variety of approaches used to estimate infiltration, percolation, and recharge fluxes are presented that provide a wide range of temporal- and spatial-scale measurements of recharge beneath Rillito Creek. The approaches discussed include analyses of (1) cores and cuttings for hydraulic and textural properties, (2) environmental tracers from the water extracted from the cores and cuttings, (3) seepage measurements made during sustained streamflow, (4) heat as a tracer and numerical simulations of the movement of heat through the streambed sediments, (5) water-content variations, (6) water-level responses to streamflow in piezometers within the stream channel, and (7) gravity changes in response to recharge events. Hydraulic properties of the materials underlying Rillito Creek were used to estimate long-term potential recharge rates. Seepage measurements and analyses of temperature and water content were used to estimate infiltration rates, and environmental tracers were used to estimate percolation rates through the thick unsaturated zone. The presence or lack of tritium in the water was used to determine whether or not water in the unsaturated zone infiltrated within the past 40 years. Analysis of water-level and temporal-gravity data were used to estimate recharge volumes. Data presented in this chapter were collected from 1999 though 2002. Precipitation and streamflow during this period were less than the long-term average; however, two periods of significant streamflow resulted in recharge—one in the summer of 1999 and the other in the fall/winter of 2000.Flux estimates of infiltration and recharge vary from less than 0.1 to 1.0 cubic meter per second per kilometer of streamflow. Recharge-flux estimates are larger than infiltration estimates. Larger recharge fluxes than infiltration fluxes are explained by the scale of measurements. Methods used to estimate recharge rates incorporate the largest volumetric and temporal scales and are likely to have fluxes from other nearby sources, such as unmeasured tributaries, whereas the methods used to estimate infiltration incorporate the smallest scales, reflecting infiltration rates at individual measurement sites.

  19. Estimating surface fluxes over middle and upper streams of the Heihe River Basin with ASTER imagery

    NASA Astrophysics Data System (ADS)

    Ma, W.; Ma, Y.; Hu, Z.; Su, B.; Wang, J.; Ishikawa, H.

    2009-06-01

    Surface fluxes are important boundary conditions for climatological modeling and the Asian monsoon system. Recent availability of high-resolution, multi-band imagery from the ASTER (Advanced Space-borne Thermal Emission and Reflection Radiometer) sensor has enabled us to estimate surface fluxes to bridge the gap between local scale flux measurements using micrometeorological instruments and regional scale land-atmosphere exchanges of water and heat fluxes that are fundamental for the understanding of the water cycle in the Asian monsoon system. A Surface Energy Balance System (SEBS) method based on ASTER data and field observations has been proposed and tested for deriving net radiation flux (Rn), soil heat flux (G0), sensible heat flux (H) and latent heat flux (λ E) over heterogeneous land surface in this paper. As a case study, the methodology was applied to the experimental area of the WATER (Watershed Allied Telemetry Experimental Research), located at the mid-to-upstream sections of the Heihe River, northwest China. The ASTER data of 3 May and 4 June in 2008 was used in this paper for the case of mid-to-upstream sections of the Heihe River Basin. To validate the proposed methodology, the ground-measured land surface heat fluxes (net radiation flux (Rn), soil heat flux (G0), sensible heat flux (H) and latent heat flux (λ E)) were compared to the ASTER derived values. The results show that the derived surface variables and land surface heat fluxes in different months over the study area are in good accordance with the land surface status. It is therefore concluded that the proposed methodology is successful for the retrieval of land surface heat fluxes using the ASTER data and filed observation over the study area.

  20. Mapping AmeriFlux footprints: Towards knowing the flux source area across a network of towers

    NASA Astrophysics Data System (ADS)

    Menzer, O.; Pastorello, G.; Metzger, S.; Poindexter, C.; Agarwal, D.; Papale, D.

    2014-12-01

    The AmeriFlux network collects long-term carbon, water and energy flux measurements obtained with the eddy covariance method. In order to attribute fluxes to specific areas of the land surface, flux source calculations are essential. Consequently, footprint models can support flux up-scaling exercises to larger regions, often based on remote sensing data. However, flux footprints are not currently being routinely calculated; different approaches exist but have not been standardized. In part, this is due to varying instrumentation and data processing methods at the site level. The goal of this work is to map tower footprints for a future standardized AmeriFlux product to be generated at the network level. These footprints can be estimated by analytical models, Lagrangian simulations, and large-eddy simulations. However, for many sites, the datasets currently submitted to central databases generally do not include all variables required. The AmeriFlux network is moving to collection of raw data and expansion of the variables requested from sites, giving the possibility to calculate all parameters and variables needed to run most of the available footprint models. In this pilot study, we are applying state of the art footprint models across a subset of AmeriFlux sites, to evaluate the feasibility and merit of developing standardized footprint results. In addition to comparing outcomes from several footprint models, we will attempt to verify and validate the results in two ways: (i) Verification of our footprint calculations at sites where footprints have been experimentally estimated. (ii) Validation at towers situated in heterogeneous landscapes: here, variations in the observed fluxes are expected to correlate with spatiotemporal variations of the source area composition. Once implemented, the footprint results can be used as additional information within the AmeriFlux database that can support data interpretation and data assimilation. Lastly, we will explore the expandability of this approach to other flux networks by collaborating with and including sites from the ICOS and NEON networks in our analyses. This can enable utilizing the footprint model output to improve network interoperability, thus further promoting synthesis analyses and understanding of system-level questions in the future.

  1. Multi-year Estimates of Methane Fluxes in Alaska from an Atmospheric Inverse Model

    NASA Astrophysics Data System (ADS)

    Miller, S. M.; Commane, R.; Chang, R. Y. W.; Miller, C. E.; Michalak, A. M.; Dinardo, S. J.; Dlugokencky, E. J.; Hartery, S.; Karion, A.; Lindaas, J.; Sweeney, C.; Wofsy, S. C.

    2015-12-01

    We estimate methane fluxes across Alaska over a multi-year period using observations from a three-year aircraft campaign, the Carbon Arctic Reservoirs Vulnerability Experiment (CARVE). Existing estimates of methane from Alaska and other Arctic regions disagree in both magnitude and distribution, and before the CARVE campaign, atmospheric observations in the region were sparse. We combine these observations with an atmospheric particle trajectory model and a geostatistical inversion to estimate surface fluxes at the model grid scale. We first use this framework to estimate the spatial distribution of methane fluxes across the state. We find the largest fluxes in the south-east and North Slope regions of Alaska. This distribution is consistent with several estimates of wetland extent but contrasts with the distribution in most existing flux models. These flux models concentrate methane in warmer or more southerly regions of Alaska compared to the estimate presented here. This result suggests a discrepancy in how existing bottom-up models translate wetland area into methane fluxes across the state. We next use the inversion framework to explore inter-annual variability in regional-scale methane fluxes for 2012-2014. We examine the extent to which this variability correlates with weather or other environmental conditions. These results indicate the possible sensitivity of wetland fluxes to near-term variability in climate.

  2. From discrete auroral arcs to the magnetospheric generator: numerical model and case study

    NASA Astrophysics Data System (ADS)

    Lamy, H.; Echim, M.; Cessateur, G.; Simon Wedlund, C.; Gustavsson, B.; Maggiolo, R.; Gunell, H.; Darrouzet, F.; De Keyser, J.

    2017-12-01

    We discuss an analysis method developed to estimate some of the properties of auroral generators (electron density, ne and temperature, Te), from ionospheric observations of the energy flux of precipitating electrons, e, measured across an auroral arc. The method makes use of a quasi-static magnetosphere-ionosphere coupling model. Assuming that the generator is a magnetospheric plasma interface, one obtains a parametric description of the generator electric field as a function of the kinetic and MHD properties of the interface. This description of the generator is introduced in a stationary M-I coupling model based on the current continuity in the topside ionosphere (Echim et al, 2007). The model is run iteratively for typical values of the magnetospheric ne and Te that are adjusted until the precipitating energy flux ɛ provided by the model at ionospheric altitudes fits the observations. The latter can be provided either in-situ by spacecraft measurements or remotely from optical ground-based observations. The method is illustrated by using the precipitating energy flux observed in-situ by DMSP on April 28, 2001, above a discrete auroral arc. For this particular date we have been able to compare the generator properties determined with our method with actual magnetospheric in-situ data provided by Cluster. The results compare very well and hence validate the method. The methodology is then applied on the energy flux of precipitating electrons estimated from optical images of a discrete auroral arc obtained simultaneously with the CCD cameras of the ALIS (Auroral Large Imaging System) network located in Scandinavia on 5 March 2008 (Simon Wedlund et al, 2013). Tomography-like techniques are used to retrieve the three-dimensional volume emission rates at 4278 Å from which the energy spectra of precipitating magnetospheric electrons can be further derived. These spectra are obtained along and across the arc, with a spatial resolution of approximately 3 km and provide E0, the characteristic energy and ɛ, the total flux energy of precipitating electrons. The generator properties are then estimated using the iterative technique validated with data from the DMSP-Cluster conjunction.

  3. Direct estimation of mass flow and diffusion of nitrogen compounds in solution and soil.

    PubMed

    Oyewole, Olusegun Ayodeji; Inselsbacher, Erich; Näsholm, Torgny

    2014-02-01

    Plant nutrient uptake from soil is mainly governed by diffusion and transpirationally induced mass flow, but the current methods for assessing the relative importance of these processes are indirect. We developed a microdialysis method using solutions of different osmotic potentials as perfusates to simulate diffusion and mass flow processes, and assessed how induced mass flow affected fluxes of nitrogen (N) compounds in solution and in boreal forest soil. Varying the osmotic potential of perfusates induced vertical fluxes in the direction of the dialysis membranes at rates of between 1 × 10(-8) and 3 × 10(-7)  m s(-1) , thus covering the estimated range of water velocities perpendicular to root surfaces and induced by transpiration. Mass flow increased N fluxes in solution but even more so in soil. This effect was explained by an indirect effect of mass flow on rates of diffusive fluxes, possibly caused by the formation of steeper gradients in concentrations of N compounds from membrane surfaces out in the soil. Our results suggest that transpiration may be an essential driver of plant N acquisition. © 2013 The Authors. New Phytologist © 2013 New Phytologist Trust.

  4. A COMPARISON OF METHODS FOR ESTIMATING GLOBAL METHANE EMISSIONS FROM LANDFILLS

    EPA Science Inventory

    Landfills are a significant source of methane, ranking third in anthropogenic sources after rice paddies and ruminants. Estimating the contribution of landfills to global methane flux is hampered by a lack of accurate refuse and landfill data, and therefore depends heavily on the...

  5. Comparative soil CO2 flux measurements and geostatistical estimation methods on Masaya volcano, Nicaragua

    USGS Publications Warehouse

    Lewicki, Jennifer L.; Bergfeld, Deborah; Cardellini, Carlo; Chiodini, Giovanni; Granieri, Domenico; Varley, Nick; Werner, Cynthia A.

    2005-01-01

    We present a comparative study of soil CO2 flux (FCO2">FCO2) measured by five groups (Groups 1–5) at the IAVCEI-CCVG Eighth Workshop on Volcanic Gases on Masaya volcano, Nicaragua. Groups 1–5 measured FCO2 using the accumulation chamber method at 5-m spacing within a 900 m2 grid during a morning (AM) period. These measurements were repeated by Groups 1–3 during an afternoon (PM) period. Measured FCO2 ranged from 218 to 14,719 g m−2 day−1. The variability of the five measurements made at each grid point ranged from ±5 to 167%. However, the arithmetic means of fluxes measured over the entire grid and associated total CO2 emission rate estimates varied between groups by only ±22%. All three groups that made PM measurements reported an 8–19% increase in total emissions over the AM results. Based on a comparison of measurements made during AM and PM times, we argue that this change is due in large part to natural temporal variability of gas flow, rather than to measurement error. In order to estimate the mean and associated CO2 emission rate of one data set and to map the spatial FCO2 distribution, we compared six geostatistical methods: arithmetic and minimum variance unbiased estimator means of uninterpolated data, and arithmetic means of data interpolated by the multiquadric radial basis function, ordinary kriging, multi-Gaussian kriging, and sequential Gaussian simulation methods. While the total CO2 emission rates estimated using the different techniques only varied by ±4.4%, the FCO2 maps showed important differences. We suggest that the sequential Gaussian simulation method yields the most realistic representation of the spatial distribution of FCO2, but a variety of geostatistical methods are appropriate to estimate the total CO2 emission rate from a study area, which is a primary goal in volcano monitoring research.

  6. Estimating Carbon Flux Phenology with Satellite-Derived Land Surface Phenology and Climate Drivers for Different Biomes: A Synthesis of AmeriFlux Observations

    PubMed Central

    Zhu, Wenquan; Chen, Guangsheng; Jiang, Nan; Liu, Jianhong; Mou, Minjie

    2013-01-01

    Carbon Flux Phenology (CFP) can affect the interannual variation in Net Ecosystem Exchange (NEE) of carbon between terrestrial ecosystems and the atmosphere. In this study, we proposed a methodology to estimate CFP metrics with satellite-derived Land Surface Phenology (LSP) metrics and climate drivers for 4 biomes (i.e., deciduous broadleaf forest, evergreen needleleaf forest, grasslands and croplands), using 159 site-years of NEE and climate data from 32 AmeriFlux sites and MODIS vegetation index time-series data. LSP metrics combined with optimal climate drivers can explain the variability in Start of Carbon Uptake (SCU) by more than 70% and End of Carbon Uptake (ECU) by more than 60%. The Root Mean Square Error (RMSE) of the estimations was within 8.5 days for both SCU and ECU. The estimation performance for this methodology was primarily dependent on the optimal combination of the LSP retrieval methods, the explanatory climate drivers, the biome types, and the specific CFP metric. This methodology has a potential for allowing extrapolation of CFP metrics for biomes with a distinct and detectable seasonal cycle over large areas, based on synoptic multi-temporal optical satellite data and climate data. PMID:24386441

  7. Estimating Carbon Flux Phenology with Satellite-Derived Land Surface Phenology and Climate Drivers for Different Biomes: A Synthesis of AmeriFlux Observations

    DOE PAGES

    Zhu, Wenquan; Chen, Guangsheng; Jiang, Nan; ...

    2013-12-27

    Carbon Flux Phenology (CFP) can affect the interannual variation in Net Ecosystem Exchange (NEE) of carbon between terrestrial ecosystems and the atmosphere. In this paper, we proposed a methodology to estimate CFP metrics with satellite-derived Land Surface Phenology (LSP) metrics and climate drivers for 4 biomes (i.e., deciduous broadleaf forest, evergreen needleleaf forest, grasslands and croplands), using 159 site-years of NEE and climate data from 32 AmeriFlux sites and MODIS vegetation index time-series data. LSP metrics combined with optimal climate drivers can explain the variability in Start of Carbon Uptake (SCU) by more than 70% and End of Carbon Uptakemore » (ECU) by more than 60%. The Root Mean Square Error (RMSE) of the estimations was within 8.5 days for both SCU and ECU. The estimation performance for this methodology was primarily dependent on the optimal combination of the LSP retrieval methods, the explanatory climate drivers, the biome types, and the specific CFP metric. In conclusion, this methodology has a potential for allowing extrapolation of CFP metrics for biomes with a distinct and detectable seasonal cycle over large areas, based on synoptic multi-temporal optical satellite data and climate data.« less

  8. The relationships between termite mound CH4/CO2 emissions and internal concentration ratios are species specific

    NASA Astrophysics Data System (ADS)

    Jamali, H.; Livesley, S. J.; Hutley, L. B.; Fest, B.; Arndt, S. K.

    2013-04-01

    We investigated the relative importance of CH4 and CO2 fluxes from soil and termite mounds at four different sites in the tropical savannas of northern Australia near Darwin and assessed different methods to indirectly predict CH4 fluxes based on CO2 fluxes and internal gas concentrations. The annual flux from termite mounds and surrounding soil was dominated by CO2 with large variations among sites. On a carbon dioxide equivalent (CO2-e) basis, annual CH4 flux estimates from termite mounds were 5- to 46-fold smaller than the concurrent annual CO2 flux estimates. Differences between annual soil CO2 and soil CH4 (CO2-e) fluxes were even greater, soil CO2 fluxes being almost three orders of magnitude greater than soil CH4 (CO2-e) fluxes at site. The contribution of CH4 and CO2 emissions from termite mounds to the total CH4 and CO2 emissions from termite mounds and soil in CO2-e was less than 1%. There were significant relationships between mound CH4 flux and mound CO2 flux, enabling the prediction of CH4 flux from measured CO2 flux; however, these relationships were clearly termite species specific. We also observed significant relationships between mound flux and gas concentration inside mound, for both CH4 and CO2, and for all termite species, thereby enabling the prediction of flux from measured mound internal gas concentration. However, these relationships were also termite species specific. Using the relationship between mound internal gas concentration and flux from one species to predict mound fluxes from other termite species (as has been done in the past) would result in errors of more than 5-fold for mound CH4 flux and 3-fold for mound CO2 flux. This study highlights that CO2 fluxes from termite mounds are generally more than one order of magnitude greater than CH4 fluxes. There are species-specific relationships between CH4 and CO2 fluxes from a mound, and between the inside mound concentration of a gas and the mound flux emission of the same gas, but these relationships vary greatly among termite species. Thus, there is no generic relationship that will allow for the accurate prediction of CH4 fluxes from termite mounds of all species, but given the data limitations, the above methods may still be used with caution.

  9. Identifying model error in metabolic flux analysis - a generalized least squares approach.

    PubMed

    Sokolenko, Stanislav; Quattrociocchi, Marco; Aucoin, Marc G

    2016-09-13

    The estimation of intracellular flux through traditional metabolic flux analysis (MFA) using an overdetermined system of equations is a well established practice in metabolic engineering. Despite the continued evolution of the methodology since its introduction, there has been little focus on validation and identification of poor model fit outside of identifying "gross measurement error". The growing complexity of metabolic models, which are increasingly generated from genome-level data, has necessitated robust validation that can directly assess model fit. In this work, MFA calculation is framed as a generalized least squares (GLS) problem, highlighting the applicability of the common t-test for model validation. To differentiate between measurement and model error, we simulate ideal flux profiles directly from the model, perturb them with estimated measurement error, and compare their validation to real data. Application of this strategy to an established Chinese Hamster Ovary (CHO) cell model shows how fluxes validated by traditional means may be largely non-significant due to a lack of model fit. With further simulation, we explore how t-test significance relates to calculation error and show that fluxes found to be non-significant have 2-4 fold larger error (if measurement uncertainty is in the 5-10 % range). The proposed validation method goes beyond traditional detection of "gross measurement error" to identify lack of fit between model and data. Although the focus of this work is on t-test validation and traditional MFA, the presented framework is readily applicable to other regression analysis methods and MFA formulations.

  10. FLUXNET to MODIS: Connecting the dots to capture heterogenious biosphere metabolism

    NASA Astrophysics Data System (ADS)

    Woods, K. D.; Schwalm, C.; Huntzinger, D. N.; Massey, R.; Poulter, B.; Kolb, T.

    2015-12-01

    Eddy co-variance flux towers provide our most widely distributed network of direct observations for land-atmosphere carbon exchange. Carbon flux sensitivity analysis is a method that uses in situ networks to understand how ecosystems respond to changes in climatic variables. Flux towers concurrently observe key ecosystem metabolic processes (e..g. gross primary productivity) and micrometeorological variation, but only over small footprints. Remotely sensed vegetation indices from MODIS offer continuous observations of the vegetated land surface, but are less direct, as they are based on light use efficiency algorithms, and not on the ground observations. The marriage of these two data products offers an opportunity to validate remotely sensed indices with in situ observations and translate information derived from tower sites to globally gridded products. Here we provide correlations between Enhanced Vegetation Index (EVI), Leaf Area Index (LAI) and MODIS gross primary production with FLUXNET derived estimates of gross primary production, respiration and net ecosystem exchange. We demonstrate remotely sensed vegetation products which have been transformed to gridded estimates of terrestrial biosphere metabolism on a regional-to-global scale. We demonstrate anomalies in gross primary production, respiration, and net ecosystem exchange as predicted by both MODIS-carbon flux sensitivities and meteorological driver-carbon flux sensitivities. We apply these sensitivities to recent extreme climatic events and demonstrate both our ability to capture changes in biosphere metabolism, and differences in the calculation of carbon flux anomalies based on method. The quantification of co-variation in these two methods of observation is important as it informs both how remotely sensed vegetation indices are correlated with on the ground tower observations, and with what certainty we can expand these observations and relationships.

  11. Data-based estimates of the ocean carbon sink variability - first results of the Surface Ocean pCO2 Mapping intercomparison (SOCOM)

    NASA Astrophysics Data System (ADS)

    Rödenbeck, C.; Bakker, D. C. E.; Gruber, N.; Iida, Y.; Jacobson, A. R.; Jones, S.; Landschützer, P.; Metzl, N.; Nakaoka, S.; Olsen, A.; Park, G.-H.; Peylin, P.; Rodgers, K. B.; Sasse, T. P.; Schuster, U.; Shutler, J. D.; Valsala, V.; Wanninkhof, R.; Zeng, J.

    2015-12-01

    Using measurements of the surface-ocean CO2 partial pressure (pCO2) and 14 different pCO2 mapping methods recently collated by the Surface Ocean pCO2 Mapping intercomparison (SOCOM) initiative, variations in regional and global sea-air CO2 fluxes are investigated. Though the available mapping methods use widely different approaches, we find relatively consistent estimates of regional pCO2 seasonality, in line with previous estimates. In terms of interannual variability (IAV), all mapping methods estimate the largest variations to occur in the eastern equatorial Pacific. Despite considerable spread in the detailed variations, mapping methods that fit the data more closely also tend to agree more closely with each other in regional averages. Encouragingly, this includes mapping methods belonging to complementary types - taking variability either directly from the pCO2 data or indirectly from driver data via regression. From a weighted ensemble average, we find an IAV amplitude of the global sea-air CO2 flux of 0.31 PgC yr-1 (standard deviation over 1992-2009), which is larger than simulated by biogeochemical process models. From a decadal perspective, the global ocean CO2 uptake is estimated to have gradually increased since about 2000, with little decadal change prior to that. The weighted mean net global ocean CO2 sink estimated by the SOCOM ensemble is -1.75 PgC yr-1 (1992-2009), consistent within uncertainties with estimates from ocean-interior carbon data or atmospheric oxygen trends.

  12. Canopy-scale flux measurements and bottom-up emission estimates of volatile organic compounds from a mixed oak and hornbeam forest in northern Italy

    NASA Astrophysics Data System (ADS)

    Acton, W. Joe F.; Schallhart, Simon; Langford, Ben; Valach, Amy; Rantala, Pekka; Fares, Silvano; Carriero, Giulia; Tillmann, Ralf; Tomlinson, Sam J.; Dragosits, Ulrike; Gianelle, Damiano; Hewitt, C. Nicholas; Nemitz, Eiko

    2016-06-01

    This paper reports the fluxes and mixing ratios of biogenically emitted volatile organic compounds (BVOCs) 4 m above a mixed oak and hornbeam forest in northern Italy. Fluxes of methanol, acetaldehyde, isoprene, methyl vinyl ketone + methacrolein, methyl ethyl ketone and monoterpenes were obtained using both a proton-transfer-reaction mass spectrometer (PTR-MS) and a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) together with the methods of virtual disjunct eddy covariance (using PTR-MS) and eddy covariance (using PTR-ToF-MS). Isoprene was the dominant emitted compound with a mean daytime flux of 1.9 mg m-2 h-1. Mixing ratios, recorded 4 m above the canopy, were dominated by methanol with a mean value of 6.2 ppbv over the 28-day measurement period. Comparison of isoprene fluxes calculated using the PTR-MS and PTR-ToF-MS showed very good agreement while comparison of the monoterpene fluxes suggested a slight over estimation of the flux by the PTR-MS. A basal isoprene emission rate for the forest of 1.7 mg m-2 h-1 was calculated using the Model of Emissions of Gases and Aerosols from Nature (MEGAN) isoprene emission algorithms (Guenther et al., 2006). A detailed tree-species distribution map for the site enabled the leaf-level emission of isoprene and monoterpenes recorded using gas-chromatography mass spectrometry (GC-MS) to be scaled up to produce a bottom-up canopy-scale flux. This was compared with the top-down canopy-scale flux obtained by measurements. For monoterpenes, the two estimates were closely correlated and this correlation improved when the plant-species composition in the individual flux footprint was taken into account. However, the bottom-up approach significantly underestimated the isoprene flux, compared with the top-down measurements, suggesting that the leaf-level measurements were not representative of actual emission rates.

  13. Canopy-scale flux measurements and bottom-up emission estimates of volatile organic compounds from a mixed oak and hornbeam forest in northern Italy

    NASA Astrophysics Data System (ADS)

    Acton, W. J. F.; Schallhart, S.; Langford, B.; Valach, A.; Rantala, P.; Fares, S.; Carriero, G.; Tillmann, R.; Tomlinson, S. J.; Dragosits, U.; Gianelle, D.; Hewitt, C. N.; Nemitz, E.

    2015-10-01

    This paper reports the fluxes and mixing ratios of biogenically emitted volatile organic compounds (BVOCs) 4 m above a mixed oak and hornbeam forest in northern Italy. Fluxes of methanol, acetaldehyde, isoprene, methyl vinyl ketone + methacrolein, methyl ethyl ketone and monoterpenes were obtained using both a proton transfer reaction-mass spectrometer (PTR-MS) and a proton transfer reaction-time of flight-mass spectrometer (PTR-ToF-MS) together with the methods of virtual disjunct eddy covariance (PTR-MS) and eddy covariance (PTR-ToF-MS). Isoprene was the dominant emitted compound with a mean day-time flux of 1.9 mg m-2 h-1. Mixing ratios, recorded 4 m above the canopy, were dominated by methanol with a mean value of 6.2 ppbv over the 28 day measurement period. Comparison of isoprene fluxes calculated using the PTR-MS and PTR-ToF-MS showed very good agreement while comparison of the monoterpene fluxes suggested a slight over estimation of the flux by the PTR-MS. A basal isoprene emission rate for the forest of 1.7 mg m-2 h-1 was calculated using the MEGAN isoprene emissions algorithms (Guenther et al., 2006). A detailed tree species distribution map for the site enabled the leaf-level emissions of isoprene and monoterpenes recorded using GC-MS to be scaled up to produce a "bottom-up" canopy-scale flux. This was compared with the "top-down" canopy-scale flux obtained by measurements. For monoterpenes, the two estimates were closely correlated and this correlation improved when the plant species composition in the individual flux footprint was taken into account. However, the bottom-up approach significantly underestimated the isoprene flux, compared with the top-down measurements, suggesting that the leaf-level measurements were not representative of actual emission rates.

  14. A straightforward method for Vacuum-Ultraviolet flux measurements: The case of the hydrogen discharge lamp and implications for solid-phase actinometry

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fulvio, D., E-mail: daniele.fulvio@uni-jena.de, E-mail: dfu@oact.inaf.it; Brieva, A. C.; Jäger, C.

    2014-07-07

    Vacuum-Ultraviolet (VUV) radiation is responsible for the photo-processing of simple and complex molecules in several terrestrial and extraterrestrial environments. In the laboratory such radiation is commonly simulated by inexpensive and easy-to-use microwave-powered hydrogen discharge lamps. However, VUV flux measurements are not trivial and the methods/devices typically used for this purpose, mainly actinometry and calibrated VUV silicon photodiodes, are not very accurate or expensive and lack of general suitability to experimental setups. Here, we present a straightforward method for measuring the VUV photon flux based on the photoelectric effect and using a gold photodetector. This method is easily applicable to mostmore » experimental setups, bypasses the major problems of the other methods, and provides reliable flux measurements. As a case study, the method is applied to a microwave-powered hydrogen discharge lamp. In addition, the comparison of these flux measurements to those obtained by O{sub 2} actinometry experiments allow us to estimate the quantum yield (QY) values QY{sub 122} = 0.44 ± 0.16 and QY{sub 160} = 0.87 ± 0.30 for solid-phase O{sub 2} actinometry.« less

  15. Using a thermal-based two source energy balance model with time-differencing to estimate surface energy fluxes with day-night MODIS observations

    NASA Astrophysics Data System (ADS)

    Guzinski, R.; Anderson, M. C.; Kustas, W. P.; Nieto, H.; Sandholt, I.

    2013-02-01

    The Dual Temperature Difference (DTD) model, introduced by Norman et al. (2000), uses a two source energy balance modelling scheme driven by remotely sensed observations of diurnal changes in land surface temperature (LST) to estimate surface energy fluxes. By using a time differential temperature measurement as input, the approach reduces model sensitivity to errors in absolute temperature retrieval. The original formulation of the DTD required an early morning LST observation (approximately 1 h after sunrise) when surface fluxes are minimal, limiting application to data provided by geostationary satellites at sub-hourly temporal resolution. The DTD model has been applied primarily during the active growth phase of agricultural crops and rangeland vegetation grasses, and has not been rigorously evaluated during senescence or in forested ecosystems. In this paper we present modifications to the DTD model that enable applications using thermal observation from polar orbiting satellites, such as Terra and Aqua, with day and night overpass times over the area of interest. This allows the application of the DTD model in high latitude regions where large viewing angles preclude the use of geostationary satellites, and also exploits the higher spatial resolution provided by polar orbiting satellites. A method for estimating nocturnal surface fluxes and a scheme for estimating the fraction of green vegetation are developed and evaluated. Modification for green vegetation fraction leads to significantly improved estimation of the heat fluxes from the vegetation canopy during senescence and in forests. Land-cover based modifications to the Priestley-Taylor scheme, used to estimate transpiration fluxes, are explored based on prior findings for conifer forests. When the modified DTD model is run with LST measurements acquired with the Moderate Resolution Imaging Spectroradiometer (MODIS) on board the Terra and Aqua satellites, generally satisfactory agreement with field measurements is obtained for a number of ecosystems in Denmark and the United States. Finally, regional maps of energy fluxes are produced for the Danish Hydrological ObsErvatory (HOBE) in western Denmark, indicating realistic patterns based on land use.

  16. On the coupled use of eddy covariance, sap flow sensors and remote sensing information for Evapotranspiration estimates in a typical heterogeneous Mediterranean ecosystem.

    NASA Astrophysics Data System (ADS)

    Corona, R.; Montaldo, N.

    2017-12-01

    Mediterranean ecosystems are typically heterogeneous, with contrasting plant functional types (PFT, woody vegetation and grass) that compete for water use. Due to the complexity of these ecosystems there is still uncertainty on the estimate of the evapotranspiration (ET). Micrometerological measurements (e.g. eddy covariance method based, EC ) are widely used for ET estimate, but in heterogeneous systems one of the main assumption (surface homogeneity) is not preserved and the method may become less robust. In this sense, the coupled use of sap flow sensors for tree transpiration estimate, surface temperature sensors, remote sensing information for land surface characterization allow to estimate the ET components and the energy balances of the three main land surface components (woody vegetation, grass and bare soil), overtaking the EC method uncertainties. The experimental site of Orroli, in Sardinia (Italy), is a typical Mediterranean heterogeneous ecosystem, monitored from the University of Cagliari since 2003. With the intent to perform an intensive field campaign for the ET estimation, we verified the potentiality of coupling eddy covariance (EC) method, infrared sensors and thermal dissipation methods (i.e. sap flow technique) for tree transpiration estimate. As a first step 3 commercial sap flux sensors were installed in a wild olive clump where the skin temperature of one tree in the clump was monitored with an infrared transducer. Then, other 54 handmade sensors were installed in 14 clumps in the EC footprint. Measurements of diameter were recorded in all the clumps and the sapwood depth was derived from measurements in several trees. The field ET estimation from the 4 commercial sensors was obtained assuming 4 different relationship between the monitored sap flux and the diameter of the species in the footprint. Instead for the 54 handmade sensors a scaling procedure was applied based on the allometric relationships between sapwood area, diameter and canopy cover area within the EC footprint. Furthermore, the hydrologic relationships between soil moisture content and ET of woody vegetation has been computed from sap flux measurements. The ET components are well estimated, highlighting the strong water resistance of wild olive, which survive in drastic dry conditions, in contrast with grass species.

  17. CarbonTracker-Lagrange: A Framework for Greenhouse Gas Flux Estimation at Regional to Continental Scales

    NASA Astrophysics Data System (ADS)

    Andrews, A. E.

    2016-12-01

    CarbonTracker-Lagrange (CT-L) is a flexible modeling framework developed to take advantage of newly available atmospheric data for CO2 and other long-lived gases such as CH4 and N2O. The North American atmospheric CO2 measurement network has grown from three sites in 2004 to >100 sites in 2015. The US network includes tall tower, mountaintop, surface, and aircraft sites in the NOAA Global Greenhouse Gas Reference Network along with sites maintained by university, government and private sector researchers. The Canadian network is operated by Environment and Climate Change Canada. This unprecedented dataset can provide spatially and temporally resolved CO2 emissions and uptake flux estimates and quantitative information about drivers of variability, such as drought and temperature. CT-L is a platform for systematic comparison of data assimilation techniques and evaluation of assumed prior, model and observation errors. A novel feature of CT-L is the optimization of boundary values along with surface fluxes, leveraging vertically resolved data available from NOAA's aircraft sampling program. CT-L uses observation footprints (influence functions) from the Weather Research and Forecasting/Stochastic Time-Inverted Lagrangian Transport (WRF-STILT) modeling system to relate atmospheric measurements to upwind fluxes and boundary values. Footprints are pre-computed and the optimization algorithms are efficient, so many variants of the calculation can be performed. Fluxes are adjusted using Bayesian or Geostatistical methods to provide optimal agreement with observations. Satellite measurements of CO2 and CH4 from GOSAT are available starting in July 2009 and from OCO-2 since September 2014. With support from the NASA Carbon Monitoring System, we are developing flux estimation strategies that use remote sensing and in situ data together, including geostatistical inversions using satellite retrievals of solar-induced chlorophyll fluorescence. CT-L enables quantitative investigation of what new measurements would best complement the existing carbon observing system. We are also working to implement multi-species inversions for CO2 flux estimation using CO2 data along with CO, δ13CO2, COS and radiocarbon observations and for CH4 flux estimation using data for various hydrocarbons.

  18. Sediment-water gas exchange in two Swedish lakes measured by Eddy Correlation

    NASA Astrophysics Data System (ADS)

    Kokic, J.; Sahlee, E.; Brand, A.; Sobek, S.

    2014-12-01

    Lake sediments are hotspots for carbon (C) cycling, acting both as sinks and sources through C burial and production of carbon dioxide (CO2) and methane. The fate of this CO2 in the water column is controlled by bottom water turbulence, a factor not accounted for in current estimates of sediment CO2 fluxes. This study is aimed to quantify the turbulent CO2 flux across the sediment-water interface (SWI) by measuring the oxygen (O2) flux with the non-invasive Eddy Correlation (EC) method that combines measurements of 3D velocity (ADV) and O2 fluctuations with a microsensor. Using the metabolic relation (respiratory quotient, RQ) of O2 and CO2 derived from a sediment incubation experiment we present the first estimates of turbulent lake sediment CO2 flux from two boreal lakes in Sweden (Erssjön and Erken, 0.07 km2 and 23.7 km2 respectively). Only ~10 % of the total dataset was extracted for flux calculations due to poor signal-to-noise ratio in the velocity and O2 signals. The sediment in Lake Erssjön was both consuming and producing O2, related to bacterial respiration and photosynthesis. Mean O2 flux was -0.19 and 0.17 μmol O2 m-2 sec-1, comparing to 0.04 μmol O2 m-2 sec-1 derived from the sediment incubation experiment. Fluxes for Lake Erken are still to be determined. Experimentally derived RQ of the both lake sediments were close to unity implying that in-situ CO2 fluxes are of similar magnitude as O2 fluxes, varying between -0.15 and 0.18 μmol C m-2 sec-1. The first measurement of turbulent sediment O2 flux and estimate of turbulent CO2 flux from a small boreal lake show higher and more variable fluxes than previously found in experimental studies. The low amount of data extracted for flux calculations (~10%) point towards the difficulties in EC measurement in low-turbulence environments. On-going work focuses on the turbulence structure in lakes and its influence on the gas fluxes at the SWI.

  19. Evaluating the two-source energy balance model using local thermal and surface flux observations in a strongly advective irrigated agricultural area

    NASA Astrophysics Data System (ADS)

    Kustas, William P.; Alfieri, Joseph G.; Anderson, Martha C.; Colaizzi, Paul D.; Prueger, John H.; Evett, Steven R.; Neale, Christopher M. U.; French, Andrew N.; Hipps, Lawrence E.; Chávez, José L.; Copeland, Karen S.; Howell, Terry A.

    2012-12-01

    Application and validation of many thermal remote sensing-based energy balance models involve the use of local meteorological inputs of incoming solar radiation, wind speed and air temperature as well as accurate land surface temperature (LST), vegetation cover and surface flux measurements. For operational applications at large scales, such local information is not routinely available. In addition, the uncertainty in LST estimates can be several degrees due to sensor calibration issues, atmospheric effects and spatial variations in surface emissivity. Time differencing techniques using multi-temporal thermal remote sensing observations have been developed to reduce errors associated with deriving the surface-air temperature gradient, particularly in complex landscapes. The Dual-Temperature-Difference (DTD) method addresses these issues by utilizing the Two-Source Energy Balance (TSEB) model of Norman et al. (1995) [1], and is a relatively simple scheme requiring meteorological input from standard synoptic weather station networks or mesoscale modeling. A comparison of the TSEB and DTD schemes is performed using LST and flux observations from eddy covariance (EC) flux towers and large weighing lysimeters (LYs) in irrigated cotton fields collected during BEAREX08, a large-scale field experiment conducted in the semi-arid climate of the Texas High Plains as described by Evett et al. (2012) [2]. Model output of the energy fluxes (i.e., net radiation, soil heat flux, sensible and latent heat flux) generated with DTD and TSEB using local and remote meteorological observations are compared with EC and LY observations. The DTD method is found to be significantly more robust in flux estimation compared to the TSEB using the remote meteorological observations. However, discrepancies between model and measured fluxes are also found to be significantly affected by the local inputs of LST and vegetation cover and the representativeness of the remote sensing observations with the local flux measurement footprint.

  20. Flux balance analysis of primary metabolism in Chlamydomonas reinhardtii.

    PubMed

    Boyle, Nanette R; Morgan, John A

    2009-01-07

    Photosynthetic organisms convert atmospheric carbon dioxide into numerous metabolites along the pathways to make new biomass. Aquatic photosynthetic organisms, which fix almost half of global inorganic carbon, have great potential: as a carbon dioxide fixation method, for the economical production of chemicals, or as a source for lipids and starch which can then be converted to biofuels. To harness this potential through metabolic engineering and to maximize production, a more thorough understanding of photosynthetic metabolism must first be achieved. A model algal species, C. reinhardtii, was chosen and the metabolic network reconstructed. Intracellular fluxes were then calculated using flux balance analysis (FBA). The metabolic network of primary metabolism for a green alga, C. reinhardtii, was reconstructed using genomic and biochemical information. The reconstructed network accounts for the intracellular localization of enzymes to three compartments and includes 484 metabolic reactions and 458 intracellular metabolites. Based on BLAST searches, one newly annotated enzyme (fructose-1,6-bisphosphatase) was added to the Chlamydomonas reinhardtii database. FBA was used to predict metabolic fluxes under three growth conditions, autotrophic, heterotrophic and mixotrophic growth. Biomass yields ranged from 28.9 g per mole C for autotrophic growth to 15 g per mole C for heterotrophic growth. The flux balance analysis model of central and intermediary metabolism in C. reinhardtii is the first such model for algae and the first model to include three metabolically active compartments. In addition to providing estimates of intracellular fluxes, metabolic reconstruction and modelling efforts also provide a comprehensive method for annotation of genome databases. As a result of our reconstruction, one new enzyme was annotated in the database and several others were found to be missing; implying new pathways or non-conserved enzymes. The use of FBA to estimate intracellular fluxes also provides flux values that can be used as a starting point for rational engineering of C. reinhardtii. From these initial estimates, it is clear that aerobic heterotrophic growth on acetate has a low yield on carbon, while mixotrophically and autotrophically grown cells are significantly more carbon efficient.

  1. Some advance on the comprehension of SR analysis for estimating the flux of a scalar

    NASA Astrophysics Data System (ADS)

    Castellví, Dr

    2009-04-01

    In agronomy, the eddy covariance, EC, method likely is the preferred for measuring surface scalar fluxes. For latent heat flux, however, weighing lysimeters maybe preferred in agriculture, but they are rarely affordable and not portable. The dissipation method, DM, is considered the most reliable technique for measuring scalar fluxes over open water because instrument motion contaminates the EC measurements. The main advantage of DM over EC is that it is less sensitive to low frequency instrument platform motions (such as ship and buoys), sensor alignment, precise orientation and stringent steadiness in the mean meteorological conditions (Fairall and Larsen, 1986; Kader, 1992; Edson and Fairall, 1998). Over land, keeping in mind that the EC and DM methods require the same measurements for scalar flux measurement, the DM has several disadvantages versus the EC. Direct measurement of the scalar variance dissipation rate, VDR, requires to capture eddies in the Kolmogorov's microscale (thus scalar time series measured at frequencies in the order of kHz are needed). Therefore, it is not practical. Indirect methods to estimate VDR (such as spectral analysis and second or third order structure functions) requires implementing iterative methods involving similarity relationships that are not well established (Hsieh and Katul, 1997; Castellvi and Snyder, 2008). Currently, there is ample evidence that the DM as explained in traditional micrometeorological books (such as, Panofsky and Dutton, 1984; Brutsaert, 1988; Kaimal and Finnigan; 1994) is, in general, not correct. Accordingly, it likely explains why DM is typically omitted in revisits of micrometeorological methods for estimating scalar fluxes in agronomy. Within the last decade, over some agricultural surfaces, evidence has been shown on the advantages over other micrometeorological methods and the reliability (i.e., close performance to the EC method) of Surface Renewal, SR, theory in conjunction with the Analysis of the scalar time trace to estimate scalar surface fluxes (Paw U et al., 1995). The analysis consists on determination of the mean ramp-pattern dimensions observed in the trace measured at one height. SR analysis is a simple transilient theory that is Lagrangian in nature and based on the scalar conservation equation. Here, it is shown (indirectly) that for a steady, incompressible and horizontally homogeneous flow, the production term in the budget equation of the mean turbulent variance of a scalar can be expressed in terms of the mean ramp dimensions observed in the trace. Therefore, the budget equation provides a link between the contrasting DM and SR analysis methods for estimating scalar surface fluxes. The dissipation method is based on the finest turbulence scales, whereas the SR analysis is based on canopy-scale coherent structures. By normalizing the budget equation, and invoking similarity, it is shown that DM and SR analysis are closely related (details were given in Castellvi and Snyder, 2008). However, SR analysis avoids the disadvantages of DM and it also overcomes potential problems related with the EC method (such as perfect alignment, rotation of the wind field, sensor separation, shadowing, etc.) because the velocity field (i.e., the sonic anemometer) is not required in SR analysis. The relation between SR analysis and DM allows to better interpret a crucial parameter (originally, denoted as ) involved in SR analysis. The parameter  was implemented to account for three assumptions made to solve the scalar flux conservation equation coupled with the Lagrangian scalar mass conservation equation. Considering an air parcel that suddenly moves down to the surface which volume covers all the vertical extend of the surface sources (sinks), the assumptions made are the following; (1) The air parcel remains in contact with the sources (sinks) for a period during which it has been enriched (depleted) of scalar, (2) During the enrichment phase there is not loss of scalar (heat for temperature) through the air parcel top, and (3) Molecular diffusion within the air parcel can be neglected. According to the new  parameter expression derived, it is shown that the half-hourly value is related to the capability of turbulence to mix the scalar within the air parcel during the enrichment (depletion) phase. The expression depends on the variance of the scalar associated to isotropic turbulence over the total (organized and isotropic). The  expression suggests that half-hourly values are in the range, 0 <  ≤ 1, at least when measurements are taken in the inertial sub-layer over vegetated surfaces. Acknowledgments The author gratefully acknowledges K.T. Paw U and R.L Snyder for his encouragement in doing this study. This work was supported by the TRANSCLA project and a fellowship from the Ministerio de Ciencia y Innovación of Spain. References Brutsaert W. 1988. Evaporation into the atmosphere. D. Reidel P.C: Doordrech; 299. Castellvi F, Snyder RL. 2008. Combining the Dissipation method and Surface Renewal analysis to estimate Scalar Fluxes from the time traces over rangeland grass near Ione (California). Hydrol. Proccesses, In Press. Edson JB, Fairall CW. 1998. Similarity Relationships in the Marine Atmospheric Surface Layer for terms on the TKE and Scalar Variance Budgets. Journal of Atmospheric Sciences 55: 2311-2328. Fairall CW, Larsen SE. 1986. Inertial-dissipation methods and turbulent fluxes at the air-ocean interface. Boundary Layer Meteorology 34: 287-301. Hsieh CI, Katul GG. 1997. Dissipation methods, Taylor's hypothesis, and stability correction functions in the atmospheric surface layer. Journal of Geophysical Research 102: (14), 16391-16405. Kader BA. 1992. Determination of turbulent momentum and heat fluxes by spectral methods. Boundary Layer Meteorology 61: 323-347. Kaimal JC, Finnigan JJ. 1994. Atmospheric Boundary Layer Flows. Oxford Univ. Press; 289. Panofsky H, Dutton J. 1984. Atmospheric Turbulence: Models and Methods for Engineering Aplications. John Wiley, NY:397.

  2. Comparison of Landfill Methane Oxidation Measured Using Stable Isotope Analysis and CO2/CH4 Fluxes Measured by the Eddy Covariance Method

    NASA Astrophysics Data System (ADS)

    Xu, L.; Chanton, J.; McDermitt, D. K.; Li, J.; Green, R. B.

    2015-12-01

    Methane plays a critical role in the radiation balance and chemistry of the atmosphere. Globally, landfill methane emission contributes about 10-19% of the anthropogenic methane burden into the atmosphere. In the United States, 18% of annual anthropogenic methane emissions come from landfills, which represent the third largest source of anthropogenic methane emissions, behind enteric fermentation and natural gas and oil production. One uncertainty in estimating landfill methane emissions is the fraction of methane oxidized when methane produced under anaerobic conditions passes through the cover soil. We developed a simple stoichiometric model to estimate methane oxidation fraction when the anaerobic CO2 / CH4 production ratio is known, or can be estimated. The model predicts a linear relationship between CO2 emission rates and CH4 emission rates, where the slope depends on anaerobic CO2 / CH4 production ratio and the fraction of methane oxidized, and the intercept depends on non-methane-dependent oxidation processes. The model was tested using carbon dioxide emission rates (fluxes) and methane emission rates (fluxes) measured using the eddy covariance method over a one year period at the Turkey Run landfill in Georgia, USA. The CO2 / CH4 production ratio was estimated by measuring CO2 and CH4 concentrations in air sampled under anaerobic conditions deep inside the landfill. We also used a mass balance approach to independently estimate fractional oxidation based on stable isotope measurements (δ13C of methane) of gas samples taken from deep inside the landfill and just above the landfill surface. Results from the two independent methods agree well. The model will be described and methane oxidation will be discussed in relation to wind direction, location at the landfill, and age of the deposited refuse.

  3. An Optimal Estimation Method to Obtain Surface Layer Turbulent Fluxes from Profile Measurements

    NASA Astrophysics Data System (ADS)

    Kang, D.

    2015-12-01

    In the absence of direct turbulence measurements, the turbulence characteristics of the atmospheric surface layer are often derived from measurements of the surface layer mean properties based on Monin-Obukhov Similarity Theory (MOST). This approach requires two levels of the ensemble mean wind, temperature, and water vapor, from which the fluxes of momentum, sensible heat, and water vapor can be obtained. When only one measurement level is available, the roughness heights and the assumed properties of the corresponding variables at the respective roughness heights are used. In practice, the temporal mean with large number of samples are used in place of the ensemble mean. However, in many situations the samples of data are taken from multiple levels. It is thus desirable to derive the boundary layer flux properties using all measurements. In this study, we used an optimal estimation approach to derive surface layer properties based on all available measurements. This approach assumes that the samples are taken from a population whose ensemble mean profile follows the MOST. An optimized estimate is obtained when the results yield a minimum cost function defined as a weighted summation of all error variance at each sample altitude. The weights are based one sample data variance and the altitude of the measurements. This method was applied to measurements in the marine atmospheric surface layer from a small boat using radiosonde on a tethered balloon where temperature and relative humidity profiles in the lowest 50 m were made repeatedly in about 30 minutes. We will present the resultant fluxes and the derived MOST mean profiles using different sets of measurements. The advantage of this method over the 'traditional' methods will be illustrated. Some limitations of this optimization method will also be discussed. Its application to quantify the effects of marine surface layer environment on radar and communication signal propagation will be shown as well.

  4. Integrated thermal infrared imaging and Structure-from-Motion photogrametry to map apparent temperature and radiant hydrothermal heat flux at Mammoth Mountain, CA USA

    USGS Publications Warehouse

    Lewis, Aaron; George Hilley,; Lewicki, Jennifer L.

    2015-01-01

    This work presents a method to create high-resolution (cm-scale) orthorectified and georeferenced maps of apparent surface temperature and radiant hydrothermal heat flux and estimate the radiant hydrothermal heat emission rate from a study area. A ground-based thermal infrared (TIR) camera was used to collect (1) a set of overlapping and offset visible imagery around the study area during the daytime and (2) time series of co-located visible and TIR imagery at one or more sites within the study area from pre-dawn to daytime. Daytime visible imagery was processed using the Structure-from-Motion photogrammetric method to create a digital elevation model onto which pre-dawn TIR imagery was orthorectified and georeferenced. Three-dimensional maps of apparent surface temperature and radiant hydrothermal heat flux were then visualized and analyzed from various computer platforms (e.g., Google Earth, ArcGIS). We demonstrate this method at the Mammoth Mountain fumarole area on Mammoth Mountain, CA. Time-averaged apparent surface temperatures and radiant hydrothermal heat fluxes were observed up to 73.7 oC and 450 W m-2, respectively, while the estimated radiant hydrothermal heat emission rate from the area was 1.54 kW. Results should provide a basis for monitoring potential volcanic unrest and mitigating hydrothermal heat-related hazards on the volcano.

  5. Evapotranspiration and microclimate at a low-level radioactive-waste disposal site in northwestern Illinois

    USGS Publications Warehouse

    Healy, R.W.; DeVries, M.P.; Sturrock, A.M.

    1987-01-01

    From July 1982 through June 1984, a study was made of the microclimate and evapotranspiration at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois. Vegetation at the site consists of mixed pasture grasses, primarily brome (Bromus inermis) and red clover (Trifoleum pratense). Three methods were used to estimate evapotranspiration: (1) an energy-budget with the Bowen ratio, (2) an aerodynamic-profile, and (3) a soil-based water-budget. For the aerodynamic-profile method, sensible-heat flux was estimated by a profile equation and evapotranspiration was then calculated as the residual in the energy-balance equation. Estimates by the energy-budget and aerodynamic-profile methods were computed from hourly data, then summed by days and months. Yearly estimates for March through November, by these methods, were quite close--648 and 626 millimeters, respectively. Daily estimates range up to a maximum of about 6 millimeters. The water-budget method produced only monthly estimates based on weekly or biweekly soil-moisture content measurements. The yearly evapotranspiration estimated by this method (which actually included only the months of April through October) was 655 millimeters. The March-through-November average for the three methods of 657 millimeters was equivalent to 70 percent of precipitation. Continuous measurements were made of incoming and reflected shortwave radiation, incoming and emitted longwave radiation, net radiation, soil-heat flux, soil temperature, horizontal windspeed, and wet- and dry-bulb air temperature. Windspeed and air temperature were measured at heights of 0.5 and 2.0 meters (and also at 1.0 meter after September 1983). Soil-moisture content of the soil zone was measured with a gamma-attenuation gage. Annual precipitation (938 millimeters) and average temperature (10.8 degrees Celsius) were virtually identical to long-term averages from nearby National Weather Service stations. Solar radiation averaged 65 percent of that normally expected under clear skies. Net radiation averaged 70.1 watts per square meter and was highest in July and negative during some winter months. Wind direction varied but was predominately out of the south-southeast. Wind speed at the 2-meter height averaged 3.5 meters per second and was slightly higher in winter months than the rest of the year. The amount of water stored within the soil zone was greatest in early spring and least in late summer. Seasonal and diurnal trends in evapotranspiration rates mirrored those in net radiation; July was usually the month with the highest rate. The ratio of sensible- to latent-heat fluxes (commonly called the Bowen ratio) for the 2-year period was 0.38, as averaged from the three methods. Monthly Bowen ratios fluctuated somewhat but averaged about 0.35 for late spring through summer. In fall, the ratio declined to zero or to slightly negative values. When the ratio was negative, the latent-heat flux was slightly greater than the net radiation because of additional energy supplied by the cooling soil and air. Evapotranspiration calculated by the three methods averaged 75 percent of potential evapotranspiration, as estimated by the Penman equation. There was no apparent seasonal trend in the relation between actual and potential evapotranspiration rates.

  6. Difference of stand-scale transpiration between ridge and riparian area in a watershed with Japanese cypress plantation

    NASA Astrophysics Data System (ADS)

    Kume, T.; Tsuruta, K.; Komatsu, H.; Shinohara, Y.; Otsuki, K.

    2011-12-01

    Several different methods to assess water use are available, and the sap flux measurement technique is one of the most promising methods, especially in monotonous watershed. Previously, three spatial levels of scaling have been used to obtain bottom-up transpiration estimates based on the sap flux technique: from within-tree to tree, from tree to stand, and from stand to watershed or landscape. Although there are considerable variations that must be taken into account at each step, few studies have examined plot-to-plot variability of stand-scale transpirations. To design optimum sampling method to accurately estimate transpiration at the watershed-scale, it is indispensable to understand heterogeneity of stand-scale transpiration in a forested watershed and the factors determining the heterogeneity. This study was undertaken to clarify differences of stand-scale transpirations within a watershed and the factors determining the differences. To this aim, we conducted sap flux-based transpiration estimates in two plots such as a lower riparian (RZ) and an upper ridge (UZ) zone in a watershed with Japanese cypress plantation, Kyushu, Japan in two years. Tree height and diameter of breast height (DBH) were lager in RZ than those of UZ. The stand sapwood area (As) was lager in RZ than UZ (21.9 cm2h a-1, 16.8 cm2ha-1, respectively). Stand mean sap flux (Js) in RZ was almost same as that of UZ when relatively lower Js, while, Js in RZ was higher than that of UZ when relatively higher Js (i.e., bright days in summer season). Consequently, daily stand-scale transpiration (E), which is the multiple of As and Js, differed by two times between RZ and UZ in summer season. This study found significant heterogeneity of stand-scale transpiration within the watershed and that the differences could be caused by two aspects such as stand structure and sap flux velocity.

  7. MUSE deep-fields: the Ly α luminosity function in the Hubble Deep Field-South at 2.91 < z < 6.64

    NASA Astrophysics Data System (ADS)

    Drake, Alyssa B.; Guiderdoni, Bruno; Blaizot, Jérémy; Wisotzki, Lutz; Herenz, Edmund Christian; Garel, Thibault; Richard, Johan; Bacon, Roland; Bina, David; Cantalupo, Sebastiano; Contini, Thierry; den Brok, Mark; Hashimoto, Takuya; Marino, Raffaella Anna; Pelló, Roser; Schaye, Joop; Schmidt, Kasper B.

    2017-10-01

    We present the first estimate of the Ly α luminosity function using blind spectroscopy from the Multi Unit Spectroscopic Explorer, MUSE, in the Hubble Deep Field-South. Using automatic source-detection software, we assemble a homogeneously detected sample of 59 Ly α emitters covering a flux range of -18.0 < log10 (F) < -16.3 (erg s-1 cm-2), corresponding to luminosities of 41.4 < log10 (L) < 42.8 (erg s-1). As recent studies have shown, Ly α fluxes can be underestimated by a factor of 2 or more via traditional methods, and so we undertake a careful assessment of each object's Ly α flux using a curve-of-growth analysis to account for extended emission. We describe our self-consistent method for determining the completeness of the sample, and present an estimate of the global Ly α luminosity function between redshifts 2.91 < z < 6.64 using the 1/Vmax estimator. We find that the luminosity function is higher than many number densities reported in the literature by a factor of 2-3, although our result is consistent at the 1σ level with most of these studies. Our observed luminosity function is also in good agreement with predictions from semi-analytic models, and shows no evidence for strong evolution between the high- and low-redshift halves of the data. We demonstrate that one's approach to Ly α flux estimation does alter the observed luminosity function, and caution that accurate flux assessments will be crucial in measurements of the faint-end slope. This is a pilot study for the Ly α luminosity function in the MUSE deep-fields, to be built on with data from the Hubble Ultra Deep Field that will increase the size of our sample by almost a factor of 10.

  8. The role of plant phenology in stomatal ozone flux modeling.

    PubMed

    Anav, Alessandro; Liu, Qiang; De Marco, Alessandra; Proietti, Chiara; Savi, Flavia; Paoletti, Elena; Piao, Shilong

    2018-01-01

    Plant phenology plays a pivotal role in the climate system as it regulates the gas exchange between the biosphere and the atmosphere. The uptake of ozone by forest is estimated through several meteorological variables and a specific function describing the beginning and the termination of plant growing season; actually, in many risk assessment studies, this function is based on a simple latitude and topography model. In this study, using two satellite datasets, we apply and compare six methods to estimate the start and the end dates of the growing season across a large region covering all Europe for the year 2011. Results show a large variability between the green-up and dormancy dates estimated using the six different methods, with differences greater than one month. However, interestingly, all the methods display a common spatial pattern in the uptake of ozone by forests with a marked change in the magnitude, up to 1.9 TgO 3 /year, and corresponding to a difference of 25% in the amount of ozone that enters the leaves. Our results indicate that improved estimates of ozone fluxes require a better representation of plant phenology in the models used for O 3 risk assessment. © 2017 John Wiley & Sons Ltd.

  9. In vivo stationary flux analysis by 13C labeling experiments.

    PubMed

    Wiechert, W; de Graaf, A A

    1996-01-01

    Stationary flux analysis is an invaluable tool for metabolic engineering. In the last years the metabolite balancing technique has become well established in the bioengineering community. On the other hand metabolic tracer experiments using 13C isotopes have long been used for intracellular flux determination. Only recently have both techniques been fully combined to form a considerably more powerful flux analysis method. This paper concentrates on modeling and data analysis for the evaluation of such stationary 13C labeling experiments. After reviewing recent experimental developments, the basic equations for modeling carbon labeling in metabolic systems, i.e. metabolite, carbon label and isotopomer balances, are introduced and discussed in some detail. Then the basics of flux estimation from measured extracellular fluxes combined with carbon labeling data are presented and, finally, this method is illustrated by using an example from C. glutamicum. The main emphasis is on the investigation of the extra information that can be obtained with tracer experiments compared with the metabolite balancing technique alone. As a principal result it is shown that the combined flux analysis method can dispense with some rather doubtful assumptions on energy balancing and that the forward and backward flux rates of bidirectional reaction steps can be simultaneously determined in certain situations. Finally, it is demonstrated that the variant of fractional isotopomer measurement is even more powerful than fractional labeling measurement but requires much higher numerical effort to solve the balance equations.

  10. Wind Velocity and Position Sensor-less Operation for PMSG Wind Generator

    NASA Astrophysics Data System (ADS)

    Senjyu, Tomonobu; Tamaki, Satoshi; Urasaki, Naomitsu; Uezato, Katsumi; Funabashi, Toshihisa; Fujita, Hideki

    Electric power generation using non-conventional sources is receiving considerable attention throughout the world. Wind energy is one of the available non-conventional energy sources. Electrical power generation using wind energy is possible in two ways, viz. constant speed operation and variable speed operation using power electronic converters. Variable speed power generation is attractive, because maximum electric power can be generated at all wind velocities. However, this system requires a rotor speed sensor, for vector control purpose, which increases the cost of the system. To alleviate the need of rotor speed sensor in vector control, we propose a new sensor-less control of PMSG (Permanent Magnet Synchronous Generator) based on the flux linkage. We can estimate the rotor position using the estimated flux linkage. We use a first-order lag compensator to obtain the flux linkage. Furthermore‚we estimate wind velocity and rotation speed using a observer. The effectiveness of the proposed method is demonstrated thorough simulation results.

  11. Spatial Estimation of Evapotranspiration in an Irrigated Semi-arid Region Using LSMs Driven by Remote Sensing Data.

    NASA Astrophysics Data System (ADS)

    Etchanchu, J.; Delogu, E.; Saadi, S.; Chebbi, W.; Trapon, D.; Rivalland, V.; Boulet, G.; Boone, A. A.; Fanise, P.; Mougenot, B.; LE Dantec, V.

    2017-12-01

    Evapotranspiration and sensible-latent heat flux partition are important decision critera to manage crops, detect water stress and plan irrigation, particularly in a semi-arid context. Nowadays, remote sensing information (at medium -MODIS- and high resolution -LANDSAT, SPOT-) allows us to spatially estimate the different terms of the energy balance at daily and infra-daily time step through various approaches, either by forcing data in an energy balance model (EVASPA, Gallego-Elvira et al., 2013, and SPARSE, Boulet et al., 2015) or data assimilation in coupled water/energy balance models (SURFEX-ISBA, Noilhan et Planton, 1989). However, these different methods of flux estimations still require an evaluation through comparison to in-situ measurements and inter-comparison.The area selected for this study is the Kairouan agricultural plain, a semi-arid region in central Tunisia. Different flux datasets were acquired over two years, on an extensive rainfed oliveyard with very low vegetation cover, and on irrigated and rainfed wheat plots. In the same time, a third dataset has been acquired over a complex agricultural landscape with an eXtra-Large Aperture Scintillometer (XLAS) set-up on a 4 km transect.First, EC fluxes from towers are compared to the different model simulations at plot scale. Then a spatial comparison with retrievals of sensible and latent heat fluxes from XLAS is performed which allows to take into account the heterogeneity of the landscape (mix of wheat, irrigated oliveyards and bare soil). Effects on irrigation scenarios, through an automatic irrigation triggering method are tested and discussed. Finally, we cross-compare the different modeling approaches.We tackle the various issues: the accuracy of the measurements, the temporal frequency of remote sensing data, and the difficulty to calibrate the models.

  12. Vertical flux of respiratory carbon by oceanic diel migrant biota

    NASA Astrophysics Data System (ADS)

    Longhurst, A. R.; Bedo, A. W.; Harrison, W. G.; Head, E. J. H.; Sameoto, D. D.

    1990-04-01

    Interzonal diel migrant plankton and nekton obtain organic carbon by feeding at night above the main pycnoline of subtropical and tropical oceans, and respire part of it by day in the interior of the ocean below the pycnocline. Using data from seven oceanic stations, and conservative models to compute respiration at depth, we show that this flux of respiratory carbon ranged from 20 to 430 mg C m -2 d -1 or 13-58% of computed particulate sinking flux across the pycnocline. If this flux occurs consistently between 50°N and 50°S, it will add about 5-20% (depending on method of calculation) to current estimates of global sinking flux of organic carbon across the pycnocline.

  13. Combining remote sensing and water-balance evapotranspiration estimates for the conterminous United States

    USGS Publications Warehouse

    Reitz, Meredith; Senay, Gabriel; Sanford, Ward E.

    2017-01-01

    Evapotranspiration (ET) is a key component of the hydrologic cycle, accounting for ~70% of precipitation in the conterminous U.S. (CONUS), but it has been a challenge to predict accurately across different spatio-temporal scales. The increasing availability of remotely sensed data has led to significant advances in the frequency and spatial resolution of ET estimates, derived from energy balance principles with variables such as temperature used to estimate surface latent heat flux. Although remote sensing methods excel at depicting spatial and temporal variability, estimation of ET independently of other water budget components can lead to inconsistency with other budget terms. Methods that rely on ground-based data better constrain long-term ET, but are unable to provide the same temporal resolution. Here we combine long-term ET estimates from a water-balance approach with the SSEBop (operational Simplified Surface Energy Balance) remote sensing-based ET product for 2000–2015. We test the new combined method, the original SSEBop product, and another remote sensing ET product (MOD16) against monthly measurements from 119 flux towers. The new product showed advantages especially in non-irrigated areas where the new method showed a coefficient of determination R2 of 0.44, compared to 0.41 for SSEBop or 0.35 for MOD16. The resulting monthly data set will be a useful, unique contribution to ET estimation, due to its combination of remote sensing-based variability and ground-based long-term water balance constraints.

  14. Estimation of Sea Ice Thickness Distributions through the Combination of Snow Depth and Satellite Laser Altimetry Data

    NASA Technical Reports Server (NTRS)

    Kurtz, Nathan T.; Markus, Thorsten; Cavalieri, Donald J.; Sparling, Lynn C.; Krabill, William B.; Gasiewski, Albin J.; Sonntag, John G.

    2009-01-01

    Combinations of sea ice freeboard and snow depth measurements from satellite data have the potential to provide a means to derive global sea ice thickness values. However, large differences in spatial coverage and resolution between the measurements lead to uncertainties when combining the data. High resolution airborne laser altimeter retrievals of snow-ice freeboard and passive microwave retrievals of snow depth taken in March 2006 provide insight into the spatial variability of these quantities as well as optimal methods for combining high resolution satellite altimeter measurements with low resolution snow depth data. The aircraft measurements show a relationship between freeboard and snow depth for thin ice allowing the development of a method for estimating sea ice thickness from satellite laser altimetry data at their full spatial resolution. This method is used to estimate snow and ice thicknesses for the Arctic basin through the combination of freeboard data from ICESat, snow depth data over first-year ice from AMSR-E, and snow depth over multiyear ice from climatological data. Due to the non-linear dependence of heat flux on ice thickness, the impact on heat flux calculations when maintaining the full resolution of the ICESat data for ice thickness estimates is explored for typical winter conditions. Calculations of the basin-wide mean heat flux and ice growth rate using snow and ice thickness values at the 70 m spatial resolution of ICESat are found to be approximately one-third higher than those calculated from 25 km mean ice thickness values.

  15. Physical principles of neutron-gamma materials monitoring

    NASA Astrophysics Data System (ADS)

    Pekarskii, G. Sh.

    1986-03-01

    The physical principles of secondary radiation methods in nondestructive testing are discussed. Among the techniques considered are: neutron activation analysis (NAA); the induced-radiation method; and quasialbedo recording of secondary gamma-radiation. Emphasis is given to the neutron-gamma method which consists of exposing test material to a neutron flux and recording the secondary gamma-radiation by means of a spectrometer. The limitations of the method in detecting local inhomogeneous defects (filled pores cracks, and inclusions) in metal layers and multicomponents materials are described, and some advantages of the method over NAA are discussed. Formulas are derived for estimating the optimum density of the gamma-ray flux which is received by the detector.

  16. Physical principles of neutron-gamma materials monitoring

    NASA Astrophysics Data System (ADS)

    Pekarskii, G. Sh.

    1985-07-01

    The physical principles of secondary radiation methods in nondestructive testing are discussed. Among the techniques considered are: neutron activation analysis (NAA); the induced-radiation method; and quasialbedo recording of secondary gamma-radiation. Emphasis is given to the neutron-gamma method which consists of exposing test material to a neutron flux and recording the secondary gamma-radiation by means of a spectrometer. The limitations of the method in detecting local inhomogeneous defects (filled pores cracks, and inclusions) in metal layers and multicomponents materials are described, and some advantages of the method over NAA are discussed. Formulas are derived for estimating the optimum density of the gamma-ray flux which is received by the detector.

  17. Technical note: Using distributed temperature sensing for Bowen ratio evaporation measurements

    NASA Astrophysics Data System (ADS)

    Schilperoort, Bart; Coenders-Gerrits, Miriam; Luxemburg, Willem; Jiménez Rodríguez, César; Cisneros Vaca, César; Savenije, Hubert

    2018-01-01

    Rapid improvements in the precision and spatial resolution of distributed temperature sensing (DTS) technology now allow its use in hydrological and atmospheric sciences. Introduced by ) is the use of DTS for measuring the Bowen ratio (BR-DTS), to estimate the sensible and latent heat flux. The Bowen ratio is derived from DTS-measured vertical profiles of the air temperature and wet-bulb temperature. However, in previous research the measured temperatures were not validated, and the cables were not shielded from solar radiation. Additionally, the BR-DTS method has not been tested above a forest before, where temperature gradients are small and energy storage in the air column becomes important. In this paper the accuracy of the wet-bulb and air temperature measurements of the DTS are verified, and the resulting Bowen ratio and heat fluxes are compared to eddy covariance data. The performance of BR-DTS was tested on a 46 m high tower in a mixed forest in the centre of the Netherlands in August 2016. The average tree height is 26 to 30 m, and the temperatures are measured below, in, and above the canopy. Using the vertical temperature profiles the storage of latent and sensible heat in the air column was calculated. We found a significant effect of solar radiation on the temperature measurements, leading to a deviation of up to 3 K. By installing screens, the error caused by sunlight is reduced to under 1 K. Wind speed seems to have a minimal effect on the measured wet-bulb temperature, both below and above the canopy. After a simple quality control, the Bowen ratio measured by DTS correlates well with eddy covariance (EC) estimates (r2 = 0.59). The average energy balance closure between BR-DTS and EC is good, with a mean underestimation of 3.4 W m-2 by the BR-DTS method. However, during daytime the BR-DTS method overestimates the available energy, and during night-time the BR-DTS method estimates the available energy to be more negative. This difference could be related to the biomass heat storage, which is neglected in this study. The BR-DTS method overestimates the latent heat flux on average by 18.7 W m-2, with RMSE = 90 W m-2. The sensible heat flux is underestimated on average by 10.6 W m-2, with RMSE = 76 W m-2. Estimates of the BR-DTS can be improved once the uncertainties in the energy balance are reduced. However, applying, for example, Monin-Obukhov similarity theory could provide independent estimates for the sensible heat flux. This would make the determination of the highly uncertain and difficult to determine net available energy redundant.

  18. Effects of land-use change on the carbon balance of terrestrial ecosystems

    NASA Astrophysics Data System (ADS)

    Houghton, R. A.; Goodale, C. L.

    Most changes in land use affect the amount of carbon held in vegetation and soil, thereby, either releasing carbon dioxide (a greenhouse gas) to, or removing it from, the atmosphere. The greatest fluxes of carbon result from conversion of forests to open lands (and vice versa). Model-based estimates of the flux of carbon attributable to land-use change are highly variable, however, largely as a result of uncertainties in the areas annually affected by different types of land-use change. Uncertain rates of tropical deforestation, for example, account for more than half of the range in estimates of the global carbon flux. Three other factors account for much of the rest of the uncertainty: (1) the initial stocks of carbon in ecosystems affected by land-use change (i.e., spatial heterogeneity), (2) per hectare changes in carbon stocks in response to different types of land-use change, and (3) legacy effects; that is, the time it takes for carbon stocks to equilibrate following a change in land use. For the tropics, recent satellite-based estimates of deforestation are lower than previous estimates and yield calculated carbon emissions from land-use change that are similar to independently-derived estimates of the total net flux for the region. The similarity suggests that changes in land use account for the net flux of carbon from the tropics. For the northern mid-latitudes, the carbon sink attributed to land-use change is less than the sink obtained by other methods, suggesting either an incomplete accounting of land-use change or the importance of other factors in explaining the current carbon sink in that region.

  19. The Characterization of Atmospheric Boundary Layer Depth and Turbulence in a Mixed Rural and Urban Convective Environment

    NASA Astrophysics Data System (ADS)

    Hicks, Micheal M.

    A comprehensive analysis of surface-atmosphere flux exchanges over a mixed rural and urban convective environment is conducted at Howard University Beltsville, MD Research Campus. This heterogeneous site consists of rural, suburban and industrial surface covers to its south, east and west, within a 2 km radius of a flux sensor. The eddy covariance method is utilized to estimate surface-atmosphere flux exchanges of momentum, heat and moisture. The attributes of these surface flux exchanges are contrasted to those of classical homogeneous sites and assessed for accuracy, to evaluate the following: (I) their similarity to conventional convective boundary layer (CBL) processes and (II) their representativeness of the surrounding environment's turbulent properties. Both evaluations are performed as a function of upwind surface conditions. In particular, the flux estimates' obedience to spectrum power laws and similarity theory relationships is used for performing the first evaluation, and their ability to close the surface energy balance and accurately model CBL heights is used for the latter. An algorithm that estimates atmospheric boundary layer heights from observed lidar extinction backscatter was developed, tested and applied in this study. The derived lidar based CBL heights compared well with those derived from balloon borne soundings, with an overall Pearson correlation coefficient and standard deviation of 0.85 and 223 m, respectively. This algorithm assisted in the evaluation of the response of CBL processes to surface heterogeneity, by deriving high temporal CBL heights and using them as independent references of the surrounding area averaged sensible heat fluxes. This study found that the heterogeneous site under evaluation was rougher than classical homogeneous sites, with slower dissipation rates of turbulent kinetic energy. Flux measurements downwind of the industrial complexes exhibited enhanced efficiency in surface-atmosphere momentum, heat, and moisture transport relative to their similarity theory predictions. In addition, these enhanced heat flux estimates ingested into the CBL slab model overestimated observed CBL heights. More spatial flux observations are needed to better understand the role that the industrial complexes are playing in enhancing the efficiency of turbulent processes, which may have important implications on the role humans are assuming in regional climate change.

  20. Incorporating both physical and kinetic limitations in quantifying dissolved oxygen flux to aquatic sediments

    USGS Publications Warehouse

    O'Connor, B.L.; Hondzo, Miki; Harvey, J.W.

    2009-01-01

    Traditionally, dissolved oxygen (DO) fluxes have been calculated using the thin-film theory with DO microstructure data in systems characterized by fine sediments and low velocities. However, recent experimental evidence of fluctuating DO concentrations near the sediment-water interface suggests that turbulence and coherent motions control the mass transfer, and the surface renewal theory gives a more mechanistic model for quantifying fluxes. Both models involve quantifying the mass transfer coefficient (k) and the relevant concentration difference (??C). This study compared several empirical models for quantifying k based on both thin-film and surface renewal theories, as well as presents a new method for quantifying ??C (dynamic approach) that is consistent with the observed DO concentration fluctuations near the interface. Data were used from a series of flume experiments that includes both physical and kinetic uptake limitations of the flux. Results indicated that methods for quantifying k and ??C using the surface renewal theory better estimated the DO flux across a range of fluid-flow conditions. ?? 2009 ASCE.

  1. Numerical approach for ECT by using boundary element method with Laplace transform

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Enokizono, M.; Todaka, T.; Shibao, K.

    1997-03-01

    This paper presents an inverse analysis by using BEM with Laplace transform. The method is applied to a simple problem in the eddy current testing (ECT). Some crack shapes in a conductive specimen are estimated from distributions of the transient eddy current on its sensing surface and magnetic flux density in the liftoff space. Because the transient behavior includes information on various frequency components, the method is applicable to the shape estimation of a comparative small crack.

  2. A direct passive method for measuring water and contaminant fluxes in porous media

    NASA Astrophysics Data System (ADS)

    Hatfield, Kirk; Annable, Michael; Cho, Jaehyun; Rao, P. S. C.; Klammler, Harald

    2004-12-01

    This paper introduces a new direct method for measuring water and contaminant fluxes in porous media. The method uses a passive flux meter (PFM), which is essentially a self-contained permeable unit properly sized to fit tightly in a screened well or boring. The meter is designed to accommodate a mixed medium of hydrophobic and/or hydrophilic permeable sorbents, which retain dissolved organic/inorganic contaminants present in the groundwater flowing passively through the meter. The contaminant mass intercepted and retained on the sorbent is used to quantify cumulative contaminant mass flux. The sorptive matrix is also impregnated with known amounts of one or more water soluble 'resident tracers'. These tracers are displaced from the sorbent at rates proportional to the groundwater flux; hence, in the current meter design, the resident tracers are used to quantify cumulative groundwater flux. Theory is presented and quantitative tools are developed to interpret the water flux from tracers possessing linear and nonlinear elution profiles. The same theory is extended to derive functional relationships useful for quantifying cumulative contaminant mass flux. To validate theory and demonstrate the passive flux meter, results of multiple box-aquifer experiments are presented and discussed. From these experiments, it is seen that accurate water flux measurements are obtained when the tracer used in calculations resides in the meter at levels representing 20 to 70 percent of the initial condition. 2,4-Dimethyl-3-pentanol (DMP) is used as a surrogate groundwater contaminant in the box aquifer experiments. Cumulative DMP fluxes are measured within 5% of known fluxes. The accuracy of these estimates generally increases with the total volume of water intercepted.

  3. Evaluate the Relative Importance of Subsurface Lateral Energy Exchange to Ground Heat Flux and Energy Balance over the Heterogeneous Surface of a Sub-tropical Wetland

    NASA Astrophysics Data System (ADS)

    CUI, W.; Chui, T. F. M.

    2016-12-01

    Subsurface lateral water and energy exchanges are often ignored in methods involving a surface energy balance under the homogeneity assumption, which may affect the estimation of evapotranspiration over a heterogeneous surface. Wetlands, however, are heterogeneous with vegetated areas and open water, making it difficult to accurately measure and estimate evapotranspiration. This study estimated the subsurface lateral energy exchange between the reed bed and shallow open water of a wetland within Mai Po Nature Reserve in Hong Kong, and further discussed its relative importance to the ground heat flux and energy balance over the wetland surface. An array of water level and temperature sensors were installed in the reed bed and the adjacent water, together with an eddy covariance system. The results suggested that the lateral energy exchange was over 30% of ground heat flux for half of the monitoring period, and should therefore be accounted for during the measurement of ground heat flux. However, the lateral energy exchange could not explain the energy balance disclosure at the site, as the variation was in phase with the residual of energy budget during the summer but was out of phase during the winter. Furthermore, this study developed a convolution model to estimate the lateral energy exchange based on air temperature which is readily available at many sites worldwide. This study overall enhanced our understanding of the subsurface lateral energy exchange, and possibly our estimation of evapotranspiration in heterogeneous environment.

  4. Estimating Biases for Regional Methane Fluxes using Co-emitted Tracers

    NASA Astrophysics Data System (ADS)

    Bambha, R.; Safta, C.; Michelsen, H. A.; Cui, X.; Jeong, S.; Fischer, M. L.

    2017-12-01

    Methane is a powerful greenhouse gas, and the development and improvement of emissions models rely on understanding the flux of methane released from anthropogenic sources relative to releases from other sources. Increasing production of shale oil and gas in the mid-latitudes and associated fugitive emissions are suspected to be a dominant contributor to the global methane increase. Landfills, sewage treatment, and other sources may be dominant sources in some parts of the U.S. Large discrepancies between emissions models present a great challenge to reconciling atmospheric measurements with inventory-based estimates for various emissions sectors. Current approaches for measuring regional emissions yield highly uncertain estimates because of the sparsity of measurement sites and the presence of multiple simultaneous sources. Satellites can provide wide spatial coverage at the expense of much lower measurement precision compared to ground-based instruments. Methods for effective assimilation of data from a variety of sources are critically needed to perform regional GHG attribution with existing measurements and to determine how to structure future measurement systems including satellites. We present a hierarchical Bayesian framework to estimate surface methane fluxes based on atmospheric concentration measurements and a Lagrangian transport model (Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport). Structural errors in the transport model are estimated with the help of co-emitted traces species with well defined decay rates. We conduct the analyses at regional scales that are based on similar geographical and meteorological conditions. For regions where data are informative, we further refine flux estimates by emissions sector and infer spatially and temporally varying biases parameterized as spectral random field representations.

  5. Using a thermal-based two source energy balance model with time-differencing to estimate surface energy fluxes with day-night MODIS observations

    NASA Astrophysics Data System (ADS)

    Guzinski, R.; Anderson, M. C.; Kustas, W. P.; Nieto, H.; Sandholt, I.

    2013-07-01

    The Dual Temperature Difference (DTD) model, introduced by Norman et al. (2000), uses a two source energy balance modelling scheme driven by remotely sensed observations of diurnal changes in land surface temperature (LST) to estimate surface energy fluxes. By using a time-differential temperature measurement as input, the approach reduces model sensitivity to errors in absolute temperature retrieval. The original formulation of the DTD required an early morning LST observation (approximately 1 h after sunrise) when surface fluxes are minimal, limiting application to data provided by geostationary satellites at sub-hourly temporal resolution. The DTD model has been applied primarily during the active growth phase of agricultural crops and rangeland vegetation grasses, and has not been rigorously evaluated during senescence or in forested ecosystems. In this paper we present modifications to the DTD model that enable applications using thermal observations from polar orbiting satellites, such as Terra and Aqua, with day and night overpass times over the area of interest. This allows the application of the DTD model in high latitude regions where large viewing angles preclude the use of geostationary satellites, and also exploits the higher spatial resolution provided by polar orbiting satellites. A method for estimating nocturnal surface fluxes and a scheme for estimating the fraction of green vegetation are developed and evaluated. Modification for green vegetation fraction leads to significantly improved estimation of the heat fluxes from the vegetation canopy during senescence and in forests. When the modified DTD model is run with LST measurements acquired with the Moderate Resolution Imaging Spectroradiometer (MODIS) on board the Terra and Aqua satellites, generally satisfactory agreement with field measurements is obtained for a number of ecosystems in Denmark and the United States. Finally, regional maps of energy fluxes are produced for the Danish Hydrological ObsErvatory (HOBE) in western Denmark, indicating realistic patterns based on land use.

  6. Overview of the Bushland Evapotranspiration and Agricultural Remote sensing EXperiment 2008 (BEAREX08): A field experiment evaluating methods for quantifying ET at multiple scales

    NASA Astrophysics Data System (ADS)

    Evett, Steven R.; Kustas, William P.; Gowda, Prasanna H.; Anderson, Martha C.; Prueger, John H.; Howell, Terry A.

    2012-12-01

    In 2008, scientists from seven federal and state institutions worked together to investigate temporal and spatial variations of evapotranspiration (ET) and surface energy balance in a semi-arid irrigated and dryland agricultural region of the Southern High Plains in the Texas Panhandle. This Bushland Evapotranspiration and Agricultural Remote sensing EXperiment 2008 (BEAREX08) involved determination of micrometeorological fluxes (surface energy balance) in four weighing lysimeter fields (each 4.7 ha) containing irrigated and dryland cotton and in nearby bare soil, wheat stubble and rangeland fields using nine eddy covariance stations, three large aperture scintillometers, and three Bowen ratio systems. In coordination with satellite overpasses, flux and remote sensing aircraft flew transects over the surrounding fields and region encompassing an area contributing fluxes from 10 to 30 km upwind of the USDA-ARS lysimeter site. Tethered balloon soundings were conducted over the irrigated fields to investigate the effect of advection on local boundary layer development. Local ET was measured using four large weighing lysimeters, while field scale estimates were made by soil water balance with a network of neutron probe profile water sites and from the stationary flux systems. Aircraft and satellite imagery were obtained at different spatial and temporal resolutions. Plot-scale experiments dealt with row orientation and crop height effects on spatial and temporal patterns of soil surface temperature, soil water content, soil heat flux, evaporation from soil in the interrow, plant transpiration and canopy and soil radiation fluxes. The BEAREX08 field experiment was unique in its assessment of ET fluxes over a broad range in spatial scales; comparing direct and indirect methods at local scales with remote sensing based methods and models using aircraft and satellite imagery at local to regional scales, and comparing mass balance-based ET ground truth with eddy covariance and remote sensing-based methods. Here we present an overview of the experiment and a summary of preliminary findings described in this special issue of AWR. Our understanding of the role of advection in the measurement and modeling of ET is advanced by these papers integrating measurements and model estimates.

  7. An Empirical Orthogonal Function-Based Algorithm for Estimating Terrestrial Latent Heat Flux from Eddy Covariance, Meteorological and Satellite Observations

    PubMed Central

    Feng, Fei; Li, Xianglan; Yao, Yunjun; Liang, Shunlin; Chen, Jiquan; Zhao, Xiang; Jia, Kun; Pintér, Krisztina; McCaughey, J. Harry

    2016-01-01

    Accurate estimation of latent heat flux (LE) based on remote sensing data is critical in characterizing terrestrial ecosystems and modeling land surface processes. Many LE products were released during the past few decades, but their quality might not meet the requirements in terms of data consistency and estimation accuracy. Merging multiple algorithms could be an effective way to improve the quality of existing LE products. In this paper, we present a data integration method based on modified empirical orthogonal function (EOF) analysis to integrate the Moderate Resolution Imaging Spectroradiometer (MODIS) LE product (MOD16) and the Priestley-Taylor LE algorithm of Jet Propulsion Laboratory (PT-JPL) estimate. Twenty-two eddy covariance (EC) sites with LE observation were chosen to evaluate our algorithm, showing that the proposed EOF fusion method was capable of integrating the two satellite data sets with improved consistency and reduced uncertainties. Further efforts were needed to evaluate and improve the proposed algorithm at larger spatial scales and time periods, and over different land cover types. PMID:27472383

  8. An Empirical Orthogonal Function-Based Algorithm for Estimating Terrestrial Latent Heat Flux from Eddy Covariance, Meteorological and Satellite Observations.

    PubMed

    Feng, Fei; Li, Xianglan; Yao, Yunjun; Liang, Shunlin; Chen, Jiquan; Zhao, Xiang; Jia, Kun; Pintér, Krisztina; McCaughey, J Harry

    2016-01-01

    Accurate estimation of latent heat flux (LE) based on remote sensing data is critical in characterizing terrestrial ecosystems and modeling land surface processes. Many LE products were released during the past few decades, but their quality might not meet the requirements in terms of data consistency and estimation accuracy. Merging multiple algorithms could be an effective way to improve the quality of existing LE products. In this paper, we present a data integration method based on modified empirical orthogonal function (EOF) analysis to integrate the Moderate Resolution Imaging Spectroradiometer (MODIS) LE product (MOD16) and the Priestley-Taylor LE algorithm of Jet Propulsion Laboratory (PT-JPL) estimate. Twenty-two eddy covariance (EC) sites with LE observation were chosen to evaluate our algorithm, showing that the proposed EOF fusion method was capable of integrating the two satellite data sets with improved consistency and reduced uncertainties. Further efforts were needed to evaluate and improve the proposed algorithm at larger spatial scales and time periods, and over different land cover types.

  9. The Chandra Source Catalog: X-ray Aperture Photometry

    NASA Astrophysics Data System (ADS)

    Kashyap, Vinay; Primini, F. A.; Glotfelty, K. J.; Anderson, C. S.; Bonaventura, N. R.; Chen, J. C.; Davis, J. E.; Doe, S. M.; Evans, I. N.; Evans, J. D.; Fabbiano, G.; Galle, E. C.; Gibbs, D. G., II; Grier, J. D.; Hain, R.; Hall, D. M.; Harbo, P. N.; He, X.; Houck, J. C.; Karovska, M.; Lauer, J.; McCollough, M. L.; McDowell, J. C.; Miller, J. B.; Mitschang, A. W.; Morgan, D. L.; Nichols, J. S.; Nowak, M. A.; Plummer, D. A.; Refsdal, B. L.; Rots, A. H.; Siemiginowska, A. L.; Sundheim, B. A.; Tibbetts, M. S.; van Stone, D. W.; Winkelman, S. L.; Zografou, P.

    2009-09-01

    The Chandra Source Catalog (CSC) represents a reanalysis of the entire ACIS and HRC imaging observations over the 9-year Chandra mission. We describe here the method by which fluxes are measured for detected sources. Source detection is carried out on a uniform basis, using the CIAO tool wavdetect. Source fluxes are estimated post-facto using a Bayesian method that accounts for background, spatial resolution effects, and contamination from nearby sources. We use gamma-function prior distributions, which could be either non-informative, or in case there exist previous observations of the same source, strongly informative. The current implementation is however limited to non-informative priors. The resulting posterior probability density functions allow us to report the flux and a robust credible range on it.

  10. Calibration of Ocean Forcing with satellite Flux Estimates (COFFEE)

    NASA Astrophysics Data System (ADS)

    Barron, Charlie; Jan, Dastugue; Jackie, May; Rowley, Clark; Smith, Scott; Spence, Peter; Gremes-Cordero, Silvia

    2016-04-01

    Predicting the evolution of ocean temperature in regional ocean models depends on estimates of surface heat fluxes and upper-ocean processes over the forecast period. Within the COFFEE project (Calibration of Ocean Forcing with satellite Flux Estimates, real-time satellite observations are used to estimate shortwave, longwave, sensible, and latent air-sea heat flux corrections to a background estimate from the prior day's regional or global model forecast. These satellite-corrected fluxes are used to prepare a corrected ocean hindcast and to estimate flux error covariances to project the heat flux corrections for a 3-5 day forecast. In this way, satellite remote sensing is applied to not only inform the initial ocean state but also to mitigate errors in surface heat flux and model representations affecting the distribution of heat in the upper ocean. While traditional assimilation of sea surface temperature (SST) observations re-centers ocean models at the start of each forecast cycle, COFFEE endeavors to appropriately partition and reduce among various surface heat flux and ocean dynamics sources. A suite of experiments in the southern California Current demonstrates a range of COFFEE capabilities, showing the impact on forecast error relative to a baseline three-dimensional variational (3DVAR) assimilation using operational global or regional atmospheric forcing. Experiment cases combine different levels of flux calibration with assimilation alternatives. The cases use the original fluxes, apply full satellite corrections during the forecast period, or extend hindcast corrections into the forecast period. Assimilation is either baseline 3DVAR or standard strong-constraint 4DVAR, with work proceeding to add a 4DVAR expanded to include a weak constraint treatment of the surface flux errors. Covariance of flux errors is estimated from the recent time series of forecast and calibrated flux terms. While the California Current examples are shown, the approach is equally applicable to other regions. These approaches within a 3DVAR application are anticipated to be useful for global and larger regional domains where a full 4DVAR methodology may be cost-prohibitive.

  11. Fluxes of Nitrous Acid (HONO) above an Agricultural Field Side near Paris

    NASA Astrophysics Data System (ADS)

    Laufs, S.; Cazaunau, M.; Stella, P.; Loubet, B.; Kurtenbach, R.; Cellier, P.; Mellouki, W.; Kleffmann, J.

    2012-04-01

    HONO is an important precursor of the OH radical, the detergent of the atmosphere. Field measurements show high diurnal HONO mixing ratios that cannot be explained by chemical models with known gas phase chemistry. Therefore, daytime sources of HONO are still under discussion. During the last decade many experimental investigation were performed to study heterogeneous production of HONO like the photo enhanced reduction of NO2 on humic acids or photolysis of HNO3 on surfaces. Recently, nitrite produced by bacteria, present in soil, was discussed as a source of HONO as well. In addition gas phase sources like the photolysis of nitrophenols, or the reaction of excited NO2 are discussed. Gradient measurements show high mixing ratios of HONO even above the boundary layer. However, beside intensive investigations on the sources of HONO, it is still an open question whether heterogeneous or gas phase sources are more important in the atmosphere. Flux measurements could represent a method to find the origin of missing sources of HONO. Until now instruments are not sensitive and fast enough to do Eddy correlation measurements for HONO. Alternatively, HONO fluxes are estimated by the Aerodynamic Gradient (AGM), or Relaxed Eddy Accumulation (REA) methods. Here we present HONO fluxes estimated by AGM and the LOPAP technique (Long Path Absorption Photometer) above an agricultural field in Grignon, Paris (48°51'N, 1°58'E). Fluxes during different seasons and different types of vegetations including bare soil will be presented and compared with chemical corrected fluxes of NO, NO2 and O3, or other parameters.

  12. Evaluation of NASA's Carbon Monitoring System (CMS) Flux Pilot: Terrestrial CO2 Fluxes

    NASA Astrophysics Data System (ADS)

    Fisher, J. B.; Polhamus, A.; Bowman, K. W.; Collatz, G. J.; Potter, C. S.; Lee, M.; Liu, J.; Jung, M.; Reichstein, M.

    2011-12-01

    NASA's Carbon Monitoring System (CMS) flux pilot project combines NASA's Earth System models in land, ocean and atmosphere to track surface CO2 fluxes. The system is constrained by atmospheric measurements of XCO2 from the Japanese GOSAT satellite, giving a "big picture" view of total CO2 in Earth's atmosphere. Combining two land models (CASA-Ames and CASA-GFED), two ocean models (ECCO2 and NOBM) and two atmospheric chemistry and inversion models (GEOS-5 and GEOS-Chem), the system brings together the stand-alone component models of the Earth System, all of which are run diagnostically constrained by a multitude of other remotely sensed data. Here, we evaluate the biospheric land surface CO2 fluxes (i.e., net ecosystem exchange, NEE) as estimated from the atmospheric flux inversion. We compare against the prior bottom-up estimates (e.g., the CASA models) as well. Our evaluation dataset is the independently derived global wall-to-wall MPI-BGC product, which uses a machine learning algorithm and model tree ensemble to "scale-up" a network of in situ CO2 flux measurements from 253 globally-distributed sites in the FLUXNET network. The measurements are based on the eddy covariance method, which uses observations of co-varying fluxes of CO2 (and water and energy) from instruments on towers extending above ecosystem canopies; the towers integrate fluxes over large spatial areas (~1 km2). We present global maps of CO2 fluxes and differences between products, summaries of fluxes by TRANSCOM region, country, latitude, and biome type, and assess the time series, including timing of minimum and maximum fluxes. This evaluation shows both where the CMS is performing well, and where improvements should be directed in further work.

  13. Large biases in regression-based constituent flux estimates: causes and diagnostic tools

    USGS Publications Warehouse

    Hirsch, Robert M.

    2014-01-01

    It has been documented in the literature that, in some cases, widely used regression-based models can produce severely biased estimates of long-term mean river fluxes of various constituents. These models, estimated using sample values of concentration, discharge, and date, are used to compute estimated fluxes for a multiyear period at a daily time step. This study compares results of the LOADEST seven-parameter model, LOADEST five-parameter model, and the Weighted Regressions on Time, Discharge, and Season (WRTDS) model using subsampling of six very large datasets to better understand this bias problem. This analysis considers sample datasets for dissolved nitrate and total phosphorus. The results show that LOADEST-7 and LOADEST-5, although they often produce very nearly unbiased results, can produce highly biased results. This study identifies three conditions that can give rise to these severe biases: (1) lack of fit of the log of concentration vs. log discharge relationship, (2) substantial differences in the shape of this relationship across seasons, and (3) severely heteroscedastic residuals. The WRTDS model is more resistant to the bias problem than the LOADEST models but is not immune to them. Understanding the causes of the bias problem is crucial to selecting an appropriate method for flux computations. Diagnostic tools for identifying the potential for bias problems are introduced, and strategies for resolving bias problems are described.

  14. An Integrated Approach to Estimate Instantaneous Near-Surface Air Temperature and Sensible Heat Flux Fields during the SEMAPHORE Experiment.

    NASA Astrophysics Data System (ADS)

    Bourras, Denis; Eymard, Laurence; Liu, W. Timothy; Dupuis, Hélène

    2002-03-01

    A new technique was developed to retrieve near-surface instantaneous air temperatures and turbulent sensible heat fluxes using satellite data during the Structure des Echanges Mer-Atmosphere, Proprietes des Heterogeneites Oceaniques: Recherche Experimentale (SEMAPHORE) experiment, which was conducted in 1993 under mainly anticyclonic conditions. The method is based on a regional, horizontal atmospheric temperature advection model whose inputs are wind vectors, sea surface temperature fields, air temperatures around the region under study, and several constants derived from in situ measurements. The intrinsic rms error of the method is 0.7°C in terms of air temperature and 9 W m2 for the fluxes, both at 0.16° × 0.16° and 1.125° × 1.125° resolution. The retrieved air temperature and flux horizontal structures are in good agreement with fields from two operational general circulation models. The application to SEMAPHORE data involves the First European Remote Sensing Satellite (ERS-1) wind fields, Advanced Very High Resolution Radiometer (AVHRR) SST fields, and European Centre for Medium-Range Weather Forecasts (ECMWF) air temperature boundary conditions. The rms errors obtained by comparing the estimations with research vessel measurements are 0.3°C and 5 W m2.

  15. Protection of Space Vehicles from Micrometeoroid/Orbital Debris (MMOD) Damages

    NASA Technical Reports Server (NTRS)

    Barr, Stephanie

    2007-01-01

    As the environment that puts space vehicles at risk can never be eliminated, space vehicles must implement protection against the MMOD environment. In general, this protection has been implemented on a risk estimate basis, largely focused on estimates of impactor size and estimated flux. However, there is some uncertainty in applying these methods from data gathered in earth orbit to excursions outside. This paper discusses different past thresholds and processes of the past and suggests additional refinement or methods that could be used for future space endeavors.

  16. The Impact of Prior Biosphere Models in the Inversion of Global Terrestrial CO2 Fluxes by Assimilating OCO-2 Retrievals

    NASA Technical Reports Server (NTRS)

    Philip, Sajeev; Johnson, Matthew S.

    2018-01-01

    Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emissions and biospheric fluxes. The processes controlling terrestrial biosphere-atmosphere carbon exchange are currently not fully understood, resulting in terrestrial biospheric models having significant differences in the quantification of biospheric CO2 fluxes. Atmospheric transport models assimilating measured (in situ or space-borne) CO2 concentrations to estimate "top-down" fluxes, generally use these biospheric CO2 fluxes as a priori information. Most of the flux inversion estimates result in substantially different spatio-temporal posteriori estimates of regional and global biospheric CO2 fluxes. The Orbiting Carbon Observatory 2 (OCO-2) satellite mission dedicated to accurately measure column CO2 (XCO2) allows for an improved understanding of global biospheric CO2 fluxes. OCO-2 provides much-needed CO2 observations in data-limited regions facilitating better global and regional estimates of "top-down" CO2 fluxes through inversion model simulations. The specific objectives of our research are to: 1) conduct GEOS-Chem 4D-Var assimilation of OCO-2 observations, using several state-of-the-science biospheric CO2 flux models as a priori information, to better constrain terrestrial CO2 fluxes, and 2) quantify the impact of different biospheric model prior fluxes on OCO-2-assimilated a posteriori CO2 flux estimates. Here we present our assessment of the importance of these a priori fluxes by conducting Observing System Simulation Experiments (OSSE) using simulated OCO-2 observations with known "true" fluxes.

  17. Results of the determination of He in cenozoic aquifers using the GC method.

    PubMed

    Kotowski, Tomasz; Najman, Joanna

    2015-04-01

    Applications of the Helium (He) method known so far consisted mainly of 4He measurements using a special mass spectrometer. 4He measurements for groundwater dating purposes can be replaced by total He (3He+4He) concentration measurements because the content of 3He can be ignored. The concentrations of 3He are very low and 3He/4 He ratios do not exceed 1.0·10(-5) in most cases. In this study, the total He concentrations in groundwater were determined using the gas chromatographic (GC) method as an alternative to methods based on spectrometry measurement. He concentrations in groundwater were used for the determination of residence time and groundwater circulation. Additionally, the radiocarbon method was used to determine the value of the external He flux (JHe) in the study area. Obtained low He concentrations and their small variation within the ca. 65 km long section along which groundwater flows indicate that it is likely there is relatively short residence time and a strong hydraulic connection between the aquifers. The estimated residence time (ca. 3000 years) is heavily dependent on the great uncertainty of the He concentration resulting from the low concentrations of He, the external 4He flux value adopted for calculation purposes and the 14C ages used to estimate the external 4He flux. © 2015, National Ground Water Association.

  18. A comparison of ground-based and aircraft-based methane emission flux estimates in a western oil and natural gas production basin

    NASA Astrophysics Data System (ADS)

    Snare, Dustin A.

    Recent increases in oil and gas production from unconventional reservoirs has brought with it an increase of methane emissions. Estimating methane emissions from oil and gas production is complex due to differences in equipment designs, maintenance, and variable product composition. Site access to oil and gas production equipment can be difficult and time consuming, making remote assessment of emissions vital to understanding local point source emissions. This work presents measurements of methane leakage made from a new ground-based mobile laboratory and a research aircraft around oil and gas fields in the Upper Green River Basin (UGRB) of Wyoming in 2014. It was recently shown that the application of the Point Source Gaussian (PSG) method, utilizing atmospheric dispersion tables developed by US EPA (Appendix B), is an effective way to accurately measure methane flux from a ground-based location downwind of a source without the use of a tracer (Brantley et al., 2014). Aircraft measurements of methane enhancement regions downwind of oil and natural gas production and Planetary Boundary Layer observations are utilized to obtain a flux for the entire UGRB. Methane emissions are compared to volumes of natural gas produced to derive a leakage rate from production operations for individual production sites and basin-wide production. Ground-based flux estimates derive a leakage rate of 0.14 - 0.78 % (95 % confidence interval) per site with a mass-weighted average (MWA) of 0.20 % for all sites. Aircraft-based flux estimates derive a MWA leakage rate of 0.54 - 0.91 % for the UGRB.

  19. Isotopically nonstationary 13C flux analysis of changes in Arabidopsis thaliana leaf metabolism due to high light acclimation

    PubMed Central

    Ma, Fangfang; Jazmin, Lara J.; Young, Jamey D.; Allen, Doug K.

    2014-01-01

    Improving plant productivity is an important aim for metabolic engineering. There are few comprehensive methods that quantitatively describe leaf metabolism, although such information would be valuable for increasing photosynthetic capacity, enhancing biomass production, and rerouting carbon flux toward desirable end products. Isotopically nonstationary metabolic flux analysis (INST-MFA) has been previously applied to map carbon fluxes in photoautotrophic bacteria, which involves model-based regression of transient 13C-labeling patterns of intracellular metabolites. However, experimental and computational difficulties have hindered its application to terrestrial plant systems. We performed in vivo isotopic labeling of Arabidopsis thaliana rosettes with 13CO2 and estimated fluxes throughout leaf photosynthetic metabolism by INST-MFA. Plants grown at 200 µmol m-2s−1 light were compared with plants acclimated for 9 d at an irradiance of 500 µmol⋅m−2⋅s−1. Approximately 1,400 independent mass isotopomer measurements obtained from analysis of 37 metabolite fragment ions were regressed to estimate 136 total fluxes (54 free fluxes) under each condition. The results provide a comprehensive description of changes in carbon partitioning and overall photosynthetic flux after long-term developmental acclimation of leaves to high light. Despite a doubling in the carboxylation rate, the photorespiratory flux increased from 17 to 28% of net CO2 assimilation with high-light acclimation (Vc/Vo: 3.5:1 vs. 2.3:1, respectively). This study highlights the potential of 13C INST-MFA to describe emergent flux phenotypes that respond to environmental conditions or plant physiology and cannot be obtained by other complementary approaches. PMID:25368168

  20. Towards Improved Estimates of Ocean Heat Flux

    NASA Astrophysics Data System (ADS)

    Bentamy, Abderrahim; Hollman, Rainer; Kent, Elisabeth; Haines, Keith

    2014-05-01

    Recommendations and priorities for ocean heat flux research are for instance outlined in recent CLIVAR and WCRP reports, eg. Yu et al (2013). Among these is the need for improving the accuracy, the consistency, and the spatial and temporal resolution of air-sea fluxes over global as well as at region scales. To meet the main air-sea flux requirements, this study is aimed at obtaining and analyzing all the heat flux components (latent, sensible and radiative) at the ocean surface over global oceans using multiple satellite sensor observations in combination with in-situ measurements and numerical model analyses. The fluxes will be generated daily and monthly for the 20-year (1992-2011) period, between 80N and 80S and at 0.25deg resolution. Simultaneous estimates of all surface heat flux terms have not yet been calculated at such large scale and long time period. Such an effort requires a wide range of expertise and data sources that only recently are becoming available. Needed are methods for integrating many data sources to calculate energy fluxes (short-wave, long wave, sensible and latent heat) across the air-sea interface. We have access to all the relevant, recently available satellite data to perform such computations. Yu, L., K. Haines, M. Bourassa, M. Cronin, S. Gulev, S. Josey, S. Kato, A. Kumar, T. Lee, D. Roemmich: Towards achieving global closure of ocean heat and freshwater budgets: Recommendations for advancing research in air-sea fluxes through collaborative activities. INTERNATIONAL CLIVAR PROJECT OFFICE, 2013: International CLIVAR Publication Series No 189. http://www.clivar.org/sites/default/files/ICPO189_WHOI_fluxes_workshop.pdf

  1. Reconciling estimates of the ratio of heat and salt fluxes at the ice-ocean interface

    NASA Astrophysics Data System (ADS)

    Keitzl, T.; Mellado, J. P.; Notz, D.

    2016-12-01

    The heat exchange between floating ice and the underlying ocean is determined by the interplay of diffusive fluxes directly at the ice-ocean interface and turbulent fluxes away from it. In this study, we examine this interplay through direct numerical simulations of free convection. Our results show that an estimation of the interface flux ratio based on direct measurements of the turbulent fluxes can be difficult because the flux ratio varies with depth. As an alternative, we present a consistent evaluation of the flux ratio based on the total heat and salt fluxes across the boundary layer. This approach allows us to reconcile previous estimates of the ice-ocean interface conditions. We find that the ratio of heat and salt fluxes directly at the interface is 83-100 rather than 33 as determined by previous turbulence measurements in the outer layer. This can cause errors in the estimated ice-ablation rate from field measurements of up to 40% if they are based on the three-equation formulation.

  2. Some advance on the comprehension of SR analysis for estimating the flux of a scalar

    NASA Astrophysics Data System (ADS)

    Castellví, Dr

    2009-04-01

    In agronomy, the eddy covariance, EC, method likely is the preferred for measuring surface scalar fluxes. For latent heat flux, however, weighing lysimeters maybe preferred in agriculture, but they are rarely affordable and not portable. The dissipation method, DM, is considered the most reliable technique for measuring scalar fluxes over open water because instrument motion contaminates the EC measurements. The main advantage of DM over EC is that it is less sensitive to low frequency instrument platform motions (such as ship and buoys), sensor alignment, precise orientation and stringent steadiness in the mean meteorological conditions (Fairall and Larsen, 1986; Kader, 1992; Edson and Fairall, 1998). Over land, keeping in mind that the EC and DM methods require the same measurements for scalar flux measurement, the DM has several disadvantages versus the EC. Direct measurement of the scalar variance dissipation rate, VDR, requires to capture eddies in the Kolmogorov's microscale (thus scalar time series measured at frequencies in the order of kHz are needed). Therefore, it is not practical. Indirect methods to estimate VDR (such as spectral analysis and second or third order structure functions) requires implementing iterative methods involving similarity relationships that are not well established (Hsieh and Katul, 1997; Castellvi and Snyder, 2008). Currently, there is ample evidence that the DM as explained in traditional micrometeorological books (such as, Panofsky and Dutton, 1984; Brutsaert, 1988; Kaimal and Finnigan; 1994) is, in general, not correct. Accordingly, it likely explains why DM is typically omitted in revisits of micrometeorological methods for estimating scalar fluxes in agronomy. Within the last decade, over some agricultural surfaces, evidence has been shown on the advantages over other micrometeorological methods and the reliability (i.e., close performance to the EC method) of Surface Renewal, SR, theory in conjunction with the Analysis of the scalar time trace to estimate scalar surface fluxes (Paw U et al., 1995). The analysis consists on determination of the mean ramp-pattern dimensions observed in the trace measured at one height. SR analysis is a simple transilient theory that is Lagrangian in nature and based on the scalar conservation equation. Here, it is shown (indirectly) that for a steady, incompressible and horizontally homogeneous flow, the production term in the budget equation of the mean turbulent variance of a scalar can be expressed in terms of the mean ramp dimensions observed in the trace. Therefore, the budget equation provides a link between the contrasting DM and SR analysis methods for estimating scalar surface fluxes. The dissipation method is based on the finest turbulence scales, whereas the SR analysis is based on canopy-scale coherent structures. By normalizing the budget equation, and invoking similarity, it is shown that DM and SR analysis are closely related (details were given in Castellvi and Snyder, 2008). However, SR analysis avoids the disadvantages of DM and it also overcomes potential problems related with the EC method (such as perfect alignment, rotation of the wind field, sensor separation, shadowing, etc.) because the velocity field (i.e., the sonic anemometer) is not required in SR analysis. The relation between SR analysis and DM allows to better interpret a crucial parameter (originally, denoted as α) involved in SR analysis. The parameter α was implemented to account for three assumptions made to solve the scalar flux conservation equation coupled with the Lagrangian scalar mass conservation equation. Considering an air parcel that suddenly moves down to the surface which volume covers all the vertical extend of the surface sources (sinks), the assumptions made are the following; (1) The air parcel remains in contact with the sources (sinks) for a period during which it has been enriched (depleted) of scalar, (2) During the enrichment phase there is not loss of scalar (heat for temperature) through the air parcel top, and (3) Molecular diffusion within the air parcel can be neglected. According to the new α parameter expression derived, it is shown that the half-hourly α value is related to the capability of turbulence to mix the scalar within the air parcel during the enrichment (depletion) phase. The expression depends on the variance of the scalar associated to isotropic turbulence over the total (organized and isotropic). The α expression suggests that half-hourly α values are in the range, 0 < α ≤ 1, at least when measurements are taken in the inertial sub-layer over vegetated surfaces. Acknowledgments The author gratefully acknowledges K.T. Paw U and R.L Snyder for his encouragement in doing this study. This work was supported by the TRANSCLA project and a fellowship from the Ministerio de Ciencia y Innovaci

  3. An intercomparison and validation of satellite-based surface radiative energy flux estimates over the Arctic

    NASA Astrophysics Data System (ADS)

    Riihelä, Aku; Key, Jeffrey R.; Meirink, Jan Fokke; Kuipers Munneke, Peter; Palo, Timo; Karlsson, Karl-Göran

    2017-05-01

    Accurate determination of radiative energy fluxes over the Arctic is of crucial importance for understanding atmosphere-surface interactions, melt and refreezing cycles of the snow and ice cover, and the role of the Arctic in the global energy budget. Satellite-based estimates can provide comprehensive spatiotemporal coverage, but the accuracy and comparability of the existing data sets must be ascertained to facilitate their use. Here we compare radiative flux estimates from Clouds and the Earth's Radiant Energy System (CERES) Synoptic 1-degree (SYN1deg)/Energy Balanced and Filled, Global Energy and Water Cycle Experiment (GEWEX) surface energy budget, and our own experimental FluxNet / Satellite Application Facility on Climate Monitoring cLoud, Albedo and RAdiation (CLARA) data against in situ observations over Arctic sea ice and the Greenland Ice Sheet during summer of 2007. In general, CERES SYN1deg flux estimates agree best with in situ measurements, although with two particular limitations: (1) over sea ice the upwelling shortwave flux in CERES SYN1deg appears to be underestimated because of an underestimated surface albedo and (2) the CERES SYN1deg upwelling longwave flux over sea ice saturates during midsummer. The Advanced Very High Resolution Radiometer-based GEWEX and FluxNet-CLARA flux estimates generally show a larger range in retrieval errors relative to CERES, with contrasting tendencies relative to each other. The largest source of retrieval error in the FluxNet-CLARA downwelling shortwave flux is shown to be an overestimated cloud optical thickness. The results illustrate that satellite-based flux estimates over the Arctic are not yet homogeneous and that further efforts are necessary to investigate the differences in the surface and cloud properties which lead to disagreements in flux retrievals.

  4. Synthesizing Global and Local Datasets to Estimate Jurisdictional Forest Carbon Fluxes in Berau, Indonesia

    PubMed Central

    Griscom, Bronson W.; Ellis, Peter W.; Baccini, Alessandro; Marthinus, Delon; Evans, Jeffrey S.; Ruslandi

    2016-01-01

    Background Forest conservation efforts are increasingly being implemented at the scale of sub-national jurisdictions in order to mitigate global climate change and provide other ecosystem services. We see an urgent need for robust estimates of historic forest carbon emissions at this scale, as the basis for credible measures of climate and other benefits achieved. Despite the arrival of a new generation of global datasets on forest area change and biomass, confusion remains about how to produce credible jurisdictional estimates of forest emissions. We demonstrate a method for estimating the relevant historic forest carbon fluxes within the Regency of Berau in eastern Borneo, Indonesia. Our method integrates best available global and local datasets, and includes a comprehensive analysis of uncertainty at the regency scale. Principal Findings and Significance We find that Berau generated 8.91 ± 1.99 million tonnes of net CO2 emissions per year during 2000–2010. Berau is an early frontier landscape where gross emissions are 12 times higher than gross sequestration. Yet most (85%) of Berau’s original forests are still standing. The majority of net emissions were due to conversion of native forests to unspecified agriculture (43% of total), oil palm (28%), and fiber plantations (9%). Most of the remainder was due to legal commercial selective logging (17%). Our overall uncertainty estimate offers an independent basis for assessing three other estimates for Berau. Two other estimates were above the upper end of our uncertainty range. We emphasize the importance of including an uncertainty range for all parameters of the emissions equation to generate a comprehensive uncertainty estimate–which has not been done before. We believe comprehensive estimates of carbon flux uncertainty are increasingly important as national and international institutions are challenged with comparing alternative estimates and identifying a credible range of historic emissions values. PMID:26752298

  5. Measuring Evapotranspiration of five Alley Cropping systems in Germany using the Eddy-Covariance- and Bowen-Ratio Energy-Balance methods

    NASA Astrophysics Data System (ADS)

    Markwitz, Christian; Knohl, Alexander; Siebicke, Lukas

    2017-04-01

    The inclusion of trees into the agricultural landscape of Europe is gaining popularity as a source for energy production. Fast growing tree species such as poplar or willow are included as short rotation coppice or alley cropping systems, which consist of tree alleys interleaved by annual rotating crops or perennial grasslands. Estimating turbulent fluxes of those systems using the eddy-covariance- (ECEB) and bowen-ratio energy-balance (BREB) method is challenging due to the methods limitation to horizontally homogeneous terrain and steady state conditions. As the conditions are not fulfilled for those systems the energy-balance is commonly not fully closed, with the non-closure being site specific. An underestimation of measured heat fluxes leads to an overestimation of the latent heat fluxes inferred from the ECEB method. The aim of our study is to 1) quantify the site specific non-closure of the energy-balance and 2) characterize the performance of both methods, compared to direct eddy-covariance measurements using a high frequency infra-red gas analyzer (LI-7200, Licor Inc.). To assess continuous evapotranspiration (ET) rates on a 30-minute time scale we installed a combined ECEB and BREB system at five alley cropping and five agricultural reference sites across Germany. For time periods of four weeks we performed direct eddy covariance flux measurements for H2O and CO2 over one crop- and one grassland alley cropping- and their respective reference systems during the growing season of 2016. We found a non-closure between 21 and 26 % for all sites, considering all day- and night-time data. The residual energy was highest during the morning and lowest in the afternoon. Related to that the energy-balance ratio (EBR), i.e. the ratio between the turbulent heat fluxes and available energy, was below one in the morning hours and increased slightly during the day up to 1.8, until the EBR decreased sharply after sunset. The EBR correlated to the daily cycle of solar radiation, the main driver of turbulent fluxes. Corresponding, we found an increasing EBR with increasing friction velocity, indicating, that under turbulent condition the energy-balance closure improves. Further, we found that the turbulent fluxes estimated by the BREB method compared well with direct eddy-covariance measurements and that the accuracy improved with increasing sensor distance. We conclude, when calculating ET rates on a 30-minute time scale using the ECEB method the site specific non-closure should be assessed beforehand by eddy-covariance. In the current study, ignoring the non-closure would have lead to an overestimation of the latent heat flux of about 25 % for the ECEB method. For a longer averaging period of one day the overestimation was reduced to less than 5 %.

  6. Estimation of Surface Temperature and Heat Flux by Inverse Heat Transfer Methods Using Internal Temperatures Measured While Radiantly Heating a Carbon/Carbon Specimen up to 1920 F

    NASA Technical Reports Server (NTRS)

    Pizzo, Michelle; Daryabeigi, Kamran; Glass, David

    2015-01-01

    The ability to solve the heat conduction equation is needed when designing materials to be used on vehicles exposed to extremely high temperatures; e.g. vehicles used for atmospheric entry or hypersonic flight. When using test and flight data, computational methods such as finite difference schemes may be used to solve for both the direct heat conduction problem, i.e., solving between internal temperature measurements, and the inverse heat conduction problem, i.e., using the direct solution to march forward in space to the surface of the material to estimate both surface temperature and heat flux. The completed research first discusses the methods used in developing a computational code to solve both the direct and inverse heat transfer problems using one dimensional, centered, implicit finite volume schemes and one dimensional, centered, explicit space marching techniques. The developed code assumed the boundary conditions to be specified time varying temperatures and also considered temperature dependent thermal properties. The completed research then discusses the results of analyzing temperature data measured while radiantly heating a carbon/carbon specimen up to 1920 F. The temperature was measured using thermocouple (TC) plugs (small carbon/carbon material specimens) with four embedded TC plugs inserted into the larger carbon/carbon specimen. The purpose of analyzing the test data was to estimate the surface heat flux and temperature values from the internal temperature measurements using direct and inverse heat transfer methods, thus aiding in the thermal and structural design and analysis of high temperature vehicles.

  7. Measuring SO2 ship emissions with an ultra-violet imaging camera

    NASA Astrophysics Data System (ADS)

    Prata, A. J.

    2013-11-01

    Over the last few years fast-sampling ultra-violet (UV) imaging cameras have been developed for use in measuring SO2 emissions from industrial sources (e.g. power plants; typical fluxes ~1-10 kg s-1) and natural sources (e.g. volcanoes; typical fluxes ~10-100 kg s-1). Generally, measurements have been made from sources rich in SO2 with high concentrations and fluxes. In this work, for the first time, a UV camera has been used to measure the much lower concentrations and fluxes of SO2 (typical fluxes ~0.01-0.1 kg s-1) in the plumes from moving and stationary ships. Some innovations and trade-offs have been made so that estimates of the fluxes and path concentrations can be retrieved in real-time. Field experiments were conducted at Kongsfjord in Ny Ålesund, Svalbard, where emissions from cruise ships were made, and at the port of Rotterdam, Netherlands, measuring emissions from more than 10 different container and cargo ships. In all cases SO2 path concentrations could be estimated and fluxes determined by measuring ship plume speeds simultaneously using the camera, or by using surface wind speed data from an independent source. Accuracies were compromised in some cases because of the presence of particulates in some ship emissions and the restriction of single-filter UV imagery, a requirement for fast-sampling (>10 Hz) from a single camera. Typical accuracies ranged from 10-30% in path concentration and 10-40% in flux estimation. Despite the ease of use and ability to determine SO2 fluxes from the UV camera system, the limitation in accuracy and precision suggest that the system may only be used under rather ideal circumstances and that currently the technology needs further development to serve as a method to monitor ship emissions for regulatory purposes.

  8. Metabolic flux estimation using particle swarm optimization with penalty function.

    PubMed

    Long, Hai-Xia; Xu, Wen-Bo; Sun, Jun

    2009-01-01

    Metabolic flux estimation through 13C trace experiment is crucial for quantifying the intracellular metabolic fluxes. In fact, it corresponds to a constrained optimization problem that minimizes a weighted distance between measured and simulated results. In this paper, we propose particle swarm optimization (PSO) with penalty function to solve 13C-based metabolic flux estimation problem. The stoichiometric constraints are transformed to an unconstrained one, by penalizing the constraints and building a single objective function, which in turn is minimized using PSO algorithm for flux quantification. The proposed algorithm is applied to estimate the central metabolic fluxes of Corynebacterium glutamicum. From simulation results, it is shown that the proposed algorithm has superior performance and fast convergence ability when compared to other existing algorithms.

  9. The relationship between termite mound CH4/CO2 emissions and internal concentration ratios are species specific

    NASA Astrophysics Data System (ADS)

    Jamali, H.; Livesley, S. J.; Hutley, L. B.; Fest, B.; Arndt, S. K.

    2012-12-01

    1. We investigated the relative importance of CH4 and CO2 fluxes from soil and termite mounds at four different sites in the tropical savannas of Northern Australia near Darwin and assessed different methods to indirectly predict CH4 fluxes based on CO2 fluxes and internal gas concentrations. 2. The annual flux from termite mounds and surrounding soil was dominated by CO2 with large variations among sites. On a CO2-e basis, annual CH4 flux estimates from termite mounds were 5- to 46-fold smaller than the concurrent annual CO2 flux estimates. Differences between annual soil CO2 and soil CH4 (CO2-e) fluxes were even greater, soil CO2 fluxes being almost three orders of magnitude greater than soil CH4 (CO2-e) fluxes at site. 3. There were significant relationships between mound CH4 flux and mound CO2 flux, enabling the prediction of CH4 flux from measured CO2 flux, however, these relationships were clearly termite species specific. 4. We also observed significant relationships between mound flux and gas concentration inside mound, for both CH4 and CO2, and for all termite species, thereby enabling the prediction of flux from measured mound internal gas concentration. However, these relationships were also termite species specific. Using the relationship between mound internal gas concentration and flux from one species to predict mound fluxes from other termite species (as has been done in past) would result in errors of more than 5-fold for CH4 and 3-fold for CO2. 5. This study highlights that CO2 fluxes from termite mounds are generally more than one order of magnitude greater than CH4 fluxes. There are species-specific relationships between CH4 and CO2 fluxes from a~mound, and between the inside mound concentration of a gas and the mound flux emission of the same gas, but these relationships vary greatly among termite species. Consequently, there is no generic relationship that will allow for the prediction of CH4 fluxes from termite mounds of all species.

  10. Particle Filter-Based Recursive Data Fusion With Sensor Indexing for Large Core Neutron Flux Estimation

    NASA Astrophysics Data System (ADS)

    Tamboli, Prakash Kumar; Duttagupta, Siddhartha P.; Roy, Kallol

    2017-06-01

    We introduce a sequential importance sampling particle filter (PF)-based multisensor multivariate nonlinear estimator for estimating the in-core neutron flux distribution for pressurized heavy water reactor core. Many critical applications such as reactor protection and control rely upon neutron flux information, and thus their reliability is of utmost importance. The point kinetic model based on neutron transport conveniently explains the dynamics of nuclear reactor. The neutron flux in the large core loosely coupled reactor is sensed by multiple sensors measuring point fluxes located at various locations inside the reactor core. The flux values are coupled to each other through diffusion equation. The coupling facilitates redundancy in the information. It is shown that multiple independent data about the localized flux can be fused together to enhance the estimation accuracy to a great extent. We also propose the sensor anomaly handling feature in multisensor PF to maintain the estimation process even when the sensor is faulty or generates data anomaly.

  11. Use of ground-based remotely sensed data for surface energy balance evaluation of a semiarid rangeland

    USGS Publications Warehouse

    Moran, M.S.; Kustas, William P.; Vidal, A.; Stannard, D.I.; Blanford, J.H.; Nichols, W.D.

    1994-01-01

    An interdisciplinary field experiment was conducted to study the water and energy balance of a semiarid rangeland watershed in southeast Arizona during the summer of 1990. Two subwatersheds, one grass dominated and the other shrub dominated, were selected for intensive study with ground-based remote sensing systems and hydrometeorological instrumentation. Surface energy balance was evaluated at both sites using direct and indirect measurements of the turbulent fluxes (eddy correlation, variance, and Bowen ratio methods) and using an aerodynamic approach based on remote measurements of surface reflectance and temperature and conventional meteorological information. Estimates of net radiant flux density (Rn), derived from measurements of air temperature, incoming solar radiation, and surface temperature and radiance compared well with values measured using a net radiometer (mean absolute difference (MAD) ≃ 50 W/m2 over a range from 115 to 670 W/m2). Soil heat flux density (G) was estimated using a relation between G/Rn and a spectral vegetation index computed from the red and near-infrared surface reflectance. These G estimates compared well with conventional measurements of G using buried soil heat flux plates (MAD ≃ 20 W/m2 over a range from −13 to 213 W/m2). In order to account for the effects of sparse vegetation, semiempirical adjustments to the single-layer bulk aerodynamic resistance approach were required for evaluation of sensible heat flux density (H). This yielded differences between measurements and remote estimates of H of approximately 33 W/m2 over a range from 13 to 303 W/m2. The resulting estimates of latent heat flux density, LE, were of the same magnitude and trend as measured values; however, a significant scatter was still observed: MAD ≃ 40 W/m2 over a range from 0 to 340 W/m2. Because LE was solved as a residual, there was a cumulative effect of errors associated with remote estimates of Rn, G, and H.

  12. Adaptation of an urban land surface model to a tropical suburban area: Offline evaluation, sensitivity analysis, and optimization of TEB/ISBA (SURFEX)

    NASA Astrophysics Data System (ADS)

    Harshan, Suraj

    The main objective of the present thesis is the improvement of the TEB/ISBA (SURFEX) urban land surface model (ULSM) through comprehensive evaluation, sensitivity analysis, and optimization experiments using energy balance and radiative and air temperature data observed during 11 months at a tropical sub-urban site in Singapore. Overall the performance of the model is satisfactory, with a small underestimation of net radiation and an overestimation of sensible heat flux. Weaknesses in predicting the latent heat flux are apparent with smaller model values during daytime and the model also significantly underpredicts both the daytime peak and nighttime storage heat. Surface temperatures of all facets are generally overpredicted. Significant variation exists in the model behaviour between dry and wet seasons. The vegetation parametrization used in the model is inadequate to represent the moisture dynamics, producing unrealistically low latent heat fluxes during a particularly dry period. The comprehensive evaluation of the USLM shows the need for accurate estimation of input parameter values for present site. Since obtaining many of these parameters through empirical methods is not feasible, the present study employed a two step approach aimed at providing information about the most sensitive parameters and an optimized parameter set from model calibration. Two well established sensitivity analysis methods (global: Sobol and local: Morris) and a state-of-the-art multiobjective evolutionary algorithm (Borg) were employed for sensitivity analysis and parameter estimation. Experiments were carried out for three different weather periods. The analysis indicates that roof related parameters are the most important ones in controlling the behaviour of the sensible heat flux and net radiation flux, with roof and road albedo as the most influential parameters. Soil moisture initialization parameters are important in controlling the latent heat flux. The built (town) fraction has a significant influence on all fluxes considered. Comparison between the Sobol and Morris methods shows similar sensitivities, indicating the robustness of the present analysis and that the Morris method can be employed as a computationally cheaper alternative of Sobol's method. Optimization as well as the sensitivity experiments for the three periods (dry, wet and mixed), show a noticeable difference in parameter sensitivity and parameter convergence, indicating inadequacies in model formulation. Existence of a significant proportion of less sensitive parameters might be indicating an over-parametrized model. Borg MOEA showed great promise in optimizing the input parameters set. The optimized model modified using the site specific values for thermal roughness length parametrization shows an improvement in the performances of outgoing longwave radiation flux, overall surface temperature, heat storage flux and sensible heat flux.

  13. Variation in fluxes estimated from nitrogen isotope discrimination corresponds with independent measures of nitrogen flux in Populus balsamifera L.

    PubMed

    Kalcsits, Lee A; Guy, Robert D

    2016-02-01

    Acquisition of mineral nitrogen by roots from the surrounding environment is often not completely efficient, in which a variable amount of leakage (efflux) relative to gross uptake (influx) occurs. The efflux/influx ratio (E/I) is, therefore, inversely related to the efficiency of nutrient uptake at the root level. Time-integrated estimates of E/I and other nitrogen-use traits may be obtainable from variation in stable isotope ratios or through compartmental analysis of tracer efflux (CATE) using radioactive or stable isotopes. To compare these two methods, Populus balsamifera L. genotypes were selected, a priori, for high or low nitrogen isotope discrimination. Vegetative cuttings were grown hydroponically, and E/I was calculated using an isotope mass balance model (IMB) and compared to E/I calculated using (15) N CATE. Both methods indicated that plants grown with ammonium had greater E/I than nitrate-grown plants. Genotypes with high or low E/I using CATE also had similarly high or low estimates of E/I using IMB, respectively. Genotype-specific means were linearly correlated (r = 0.77; P = 0.0065). Discrepancies in E/I between methods may reflect uncertainties in discrimination factors for the assimilatory enzymes, or temporal differences in uptake patterns. By utilizing genotypes with known variation in nitrogen isotope discrimination, a relationship between nitrogen isotope discrimination and bidirectional nitrogen fluxes at the root level was observed. © 2015 John Wiley & Sons Ltd.

  14. Flux Calculation Using CARIBIC DOAS Aircraft Measurements: SO2 Emission of Norilsk

    NASA Technical Reports Server (NTRS)

    Walter, D.; Heue, K.-P.; Rauthe-Schoech, A.; Brenninkmeijer, C. A. M.; Lamsal, L. N.; Krotkov, N. A.; Platt, U.

    2012-01-01

    Based on a case-study of the nickel smelter in Norilsk (Siberia), the retrieval of trace gas fluxes using airborne remote sensing is discussed. A DOAS system onboard an Airbus 340 detected large amounts of SO2 and NO2 near Norilsk during a regular passenger flight within the CARIBIC project. The remote sensing data were combined with ECMWF wind data to estimate the SO2 output of the Norilsk industrial complex to be around 1 Mt per year, which is in agreement with independent estimates. This value is compared to results using data from satellite remote sensing (GOME, OMI). The validity of the assumptions underlying our estimate is discussed, including the adaptation of this method to other gases and sources like the NO2 emissions of large industries or cities.

  15. A new method to measure Bowen ratios using high-resolution vertical dry and wet bulb temperature profiles

    NASA Astrophysics Data System (ADS)

    Euser, T.; Luxemburg, W. M. J.; Everson, C. S.; Mengistu, M. G.; Clulow, A. D.; Bastiaanssen, W. G. M.

    2014-06-01

    The Bowen ratio surface energy balance method is a relatively simple method to determine the latent heat flux and the actual land surface evaporation. The Bowen ratio method is based on the measurement of air temperature and vapour pressure gradients. If these measurements are performed at only two heights, correctness of data becomes critical. In this paper we present the concept of a new measurement method to estimate the Bowen ratio based on vertical dry and wet bulb temperature profiles with high spatial resolution. A short field experiment with distributed temperature sensing (DTS) in a fibre optic cable with 13 measurement points in the vertical was undertaken. A dry and a wetted section of a fibre optic cable were suspended on a 6 m high tower installed over a sugar beet trial plot near Pietermaritzburg (South Africa). Using the DTS cable as a psychrometer, a near continuous observation of vapour pressure and air temperature at 0.20 m intervals was established. These data allowed the computation of the Bowen ratio with a high spatial and temporal precision. The daytime latent and sensible heat fluxes were estimated by combining the Bowen ratio values from the DTS-based system with independent measurements of net radiation and soil heat flux. The sensible heat flux, which is the relevant term to evaluate, derived from the DTS-based Bowen ratio (BR-DTS) was compared with that derived from co-located eddy covariance (R2 = 0.91), surface layer scintillometer (R2 = 0.81) and surface renewal (R2 = 0.86) systems. By using multiple measurement points instead of two, more confidence in the derived Bowen ratio values is obtained.

  16. Effect of rapidly changing river stage on uranium flux through the hyporheic zone.

    PubMed

    Fritz, Brad G; Arntzen, Evan V

    2007-01-01

    Measurement of ground water/surface water interaction within the hyporheic zone is increasingly recognized as an important aspect of subsurface contaminant fate and transport. Understanding the interaction between ground water and surface water is critical in developing a complete conceptual model of contaminant transport through the hyporheic zone. At the Hanford Site near Richland, Washington, ground water contaminated with uranium discharges to the Columbia River through the hyporheic zone. Ground water flux varies according to changes in hydraulic gradient caused by fluctuating river stage, which changes in response to operation of dams on the Columbia River. Piezometers and continuous water quality monitoring probes were installed in the hyporheic zone to provide long-term, high-frequency measurement of hydraulic gradient and estimated uranium concentrations. Subsequently, the flux of water and uranium was calculated for each half-hour time period over a 15-month study period. In addition, measurement of water levels in the near-shore unconfined aquifer enhanced the understanding of the relationship between river stage, aquifer elevation, and uranium flux. Changing river stage resulted in fluctuating hydraulic gradient within the hyporheic zone. Further, influx of river water caused lower uranium concentrations as a result of dilution. The methods employed in this study provide a better understanding of the interaction between surface and ground water in a situation with a dynamically varying vertical hydraulic gradient and illustrate how the combination of relatively standard methods can be used to derive an accurate estimation of water and contaminant flux through the hyporheic zone.

  17. A global carbon assimilation system based on a dual optimization method

    NASA Astrophysics Data System (ADS)

    Zheng, H.; Li, Y.; Chen, J. M.; Wang, T.; Huang, Q.; Huang, W. X.; Wang, L. H.; Li, S. M.; Yuan, W. P.; Zheng, X.; Zhang, S. P.; Chen, Z. Q.; Jiang, F.

    2015-02-01

    Ecological models are effective tools for simulating the distribution of global carbon sources and sinks. However, these models often suffer from substantial biases due to inaccurate simulations of complex ecological processes. We introduce a set of scaling factors (parameters) to an ecological model on the basis of plant functional type (PFT) and latitudes. A global carbon assimilation system (GCAS-DOM) is developed by employing a dual optimization method (DOM) to invert the time-dependent ecological model parameter state and the net carbon flux state simultaneously. We use GCAS-DOM to estimate the global distribution of the CO2 flux on 1° × 1° grid cells for the period from 2001 to 2007. Results show that land and ocean absorb -3.63 ± 0.50 and -1.82 ± 0.16 Pg C yr-1, respectively. North America, Europe and China contribute -0.98 ± 0.15, -0.42 ± 0.08 and -0.20 ± 0.29 Pg C yr-1, respectively. The uncertainties in the flux after optimization by GCAS-DOM have been remarkably reduced by more than 60%. Through parameter optimization, GCAS-DOM can provide improved estimates of the carbon flux for each PFT. Coniferous forest (-0.97 ± 0.27 Pg C yr-1) is the largest contributor to the global carbon sink. Fluxes of once-dominant deciduous forest generated by the Boreal Ecosystems Productivity Simulator (BEPS) are reduced to -0.78 ± 0.23 Pg C yr-1, the third largest carbon sink.

  18. Comparison and analysis of empirical equations for soil heat flux for different cropping systems and irrigation methods

    USGS Publications Warehouse

    Irmak, A.; Singh, Ramesh K.; Walter-Shea, Elizabeth; Verma, S.B.; Suyker, A.E.

    2011-01-01

    We evaluated the performance of four models for estimating soil heat flux density (G) in maize (Zea mays L.) and soybean (Glycine max L.) fields under different irrigation methods (center-pivot irrigated fields at Mead, Nebraska, and subsurface drip irrigated field at Clay Center, Nebraska) and rainfed conditions at Mead. The model estimates were compared against measurements made during growing seasons of 2003, 2004, and 2005 at Mead and during 2005, 2006, and 2007 at Clay Center. We observed a strong relationship between the G and net radiation (Rn) ratio (G/Rn) and the normalized difference vegetation index (NDVI). When a significant portion of the ground was bare soil, G/Rn ranged from 0.15 to 0.30 and decreased with increasing NDVI. In contrast to the NDVI progression, the G/Rn ratio decreased with crop growth and development. The G/Rn ratio for subsurface drip irrigated crops was smaller than for the center-pivot irrigated crops. The seasonal average G was 13.1%, 15.2%, 10.9%, and 12.8% of Rn for irrigated maize, rainfed maize, irrigated soybean, and rainfed soybean, respectively. Statistical analyses of the performance of the four models showed a wide range of variation in G estimation. The root mean square error (RMSE) of predictions ranged from 15 to 81.3 W m-2. Based on the wide range of RMSE, it is recommended that local calibration of the models should be carried out for remote estimation of soil heat flux.

  19. Efficient dynamical correction of the transition state theory rate estimate for a flat energy barrier.

    PubMed

    Mökkönen, Harri; Ala-Nissila, Tapio; Jónsson, Hannes

    2016-09-07

    The recrossing correction to the transition state theory estimate of a thermal rate can be difficult to calculate when the energy barrier is flat. This problem arises, for example, in polymer escape if the polymer is long enough to stretch between the initial and final state energy wells while the polymer beads undergo diffusive motion back and forth over the barrier. We present an efficient method for evaluating the correction factor by constructing a sequence of hyperplanes starting at the transition state and calculating the probability that the system advances from one hyperplane to another towards the product. This is analogous to what is done in forward flux sampling except that there the hyperplane sequence starts at the initial state. The method is applied to the escape of polymers with up to 64 beads from a potential well. For high temperature, the results are compared with direct Langevin dynamics simulations as well as forward flux sampling and excellent agreement between the three rate estimates is found. The use of a sequence of hyperplanes in the evaluation of the recrossing correction speeds up the calculation by an order of magnitude as compared with the traditional approach. As the temperature is lowered, the direct Langevin dynamics simulations as well as the forward flux simulations become computationally too demanding, while the harmonic transition state theory estimate corrected for recrossings can be calculated without significant increase in the computational effort.

  20. Net anthropogenic nitrogen inputs and nitrogen fluxes from Indian watersheds: An initial assessment

    NASA Astrophysics Data System (ADS)

    Swaney, D. P.; Hong, B.; Paneer Selvam, A.; Howarth, R. W.; Ramesh, R.; Purvaja, R.

    2015-01-01

    In this paper, we apply an established methodology for estimating Net Anthropogenic Nitrogen Inputs (NANI) to India and its major watersheds. Our primary goal here is to provide initial estimates of major nitrogen inputs of NANI for India, at the country level and for major Indian watersheds, including data sources and parameter estimates, making some assumptions as needed in areas of limited data availability. Despite data limitations, we believe that it is clear that the main anthropogenic N source is agricultural fertilizer, which is being produced and applied at a growing rate, followed by N fixation associated with rice, leguminous crops, and sugar cane. While India appears to be a net exporter of N in food/feed as reported elsewhere (Lassaletta et al., 2013b), the balance of N associated with exports and imports of protein in food and feedstuffs is sensitive to protein content and somewhat uncertain. While correlating watershed N inputs with riverine N fluxes is problematic due in part to limited available riverine data, we have assembled some data for comparative purposes. We also suggest possible improvements in methods for future studies, and the potential for estimating riverine N fluxes to coastal waters.

  1. Regional surface soil heat flux estimate from multiple remote sensing data in a temperate and semiarid basin

    NASA Astrophysics Data System (ADS)

    Li, Nana; Jia, Li; Lu, Jing; Menenti, Massimo; Zhou, Jie

    2017-01-01

    The regional surface soil heat flux (G0) estimation is very important for the large-scale land surface process modeling. However, most of the regional G0 estimation methods are based on the empirical relationship between G0 and the net radiation flux. A physical model based on harmonic analysis was improved (referred to as "HM model") and applied over the Heihe River Basin northwest China with multiple remote sensing data, e.g., FY-2C, AMSR-E, and MODIS, and soil map data. The sensitivity analysis of the model was studied as well. The results show that the improved model describes the variation of G0 well. Land surface temperature (LST) and thermal inertia (Γ) are the two key input variables to the HM model. Compared with in situ G0, there are some differences, mainly due to the differences between remote-sensed LST and the in situ LST. The sensitivity analysis shows that the errors from -7 to -0.5 K in LST amplitude and from -300 to 300 J m-2 K-1 s-0.5 in Γ will cause about 20% errors, which are acceptable for G0 estimation.

  2. Tropospheric ozone fluxes in Norway spruce forest during the transition period from autumn to winter

    NASA Astrophysics Data System (ADS)

    Juran, Stanislav; Fares, Silvano; Zapletal, Miloš; Cudlín, Pavel; Večeřa, Zbyněk; Urban, Otmar

    2017-04-01

    Norway spruce exhibits seasonal variations in stomatal conductance and photosynthetic activity typical for overwintering plants, with a decline during autumn and a complete recovery during spring. We investigated ozone fluxes during this transient period (November 2016). Fluxes of tropospheric ozone, the major phytotoxic near-ground pollutant causing injuries to plant tissues, were measured at Bily Kriz experimental station in Beskydy Mountains, the Czech Republic. Dry chemiluminescence fast-response ozone sensor coupled with sonic anemometer was used to measure fast fluctuations in ozone concentration and three-dimensional wind speed, respectively. Apart from this eddy covariance technique, within-canopy ozone concentration gradient was simultaneously measured by UV-absorption based slow-response ozone analysers. Ozone fluxes were subsequently modelled by an Inverse Lagrangian Transport Model (ILTM). A comparison of measured and calculated fluxes is thus available. Moreover, stomatal ozone flux was calculated based on Evaporative/Resistive method assuming stomata are the most relevant sink in the spruce forest. The low NOx concentration throughout the year and low concentrations of volatile organic compounds (VOCs) during the transition period led to hypothesize that non-stomatal flux here estimated by difference between total ozone flux and stomatal ozone flux is represented mainly by dry soil deposition and wet deposition during the snow period. We discuss here the ILTM parameterisation with comparison to measured ozone fluxes. Correct estimation of stomatal ozone flux is essential, especially in transition periods, where main scientific emphasis is put rarely. In addition, this research should help to develop metrics for ozone-risk assessment and advance our knowledge in biosphere-atmosphere exchange over Norway spruce forest. Acknowledgement This work was supported by the Ministry of Education, Youth and Sports within the National Programme for Sustainability (grant No. LO1415) and project CzeCOS (grant No. LM2015061).

  3. Estimation of m.w.e (meter water equivalent) depth of the salt mine of Slanic Prahova, Romania

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mitrica, B.; Margineanu, R.; Stoica, S.

    2010-11-24

    A new mobile detector was developed in IFIN-HH, Romania, for measuring muon flux at surface and in underground. The measurements have been performed in the salt mines of Slanic Prahova, Romania. The muon flux was determined for 2 different galleries of the Slanic mine at different depths. In order to test the stability of the method, also measurements of the muon flux at surface at different altitudes were performed. Based on the results, the depth of the 2 galleries was established at 610 and 790 m.w.e. respectively.

  4. Evapotranspiration and microclimate at a low-level radioactive-waste disposal site in northwestern Illinois

    USGS Publications Warehouse

    Healy, R.W.; DeVries, M.P.; Sturrock, Alex M.

    1989-01-01

    From July 1982 through June 1984, a study was made of the evapotranspiration and microclimate at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois. Vegetation at the site consists of mixed pasture grasses, primarily awnless brome (Bromus inermis) and red clover (Trifoleum pratense). Three methods were used to estimate evapotranspiration: (1) an energy budget with the Bowen ratio, (2) an aerodynamic profile, and (3) a soil-based water budget. For the aerodynamic-profile method, sensible-heat flux was estimated by a profile equation and evapotranspiration was then calculated as the residual in the energy-balance equation. Estimates by the energy-budget and aerodynamic-profile methods were computed from hourly data and then summed by days and months. Yearly estimates (for March through November) by these methods were in close agreement: 648 and 626 millimeters, respectively. Daily estimates reach a maximum of about 6 millimeters. The water-budget method produced only monthly estimates based on weekly or biweekly soil-moisture content measurements. The yearly evapotranspiration estimated by this method (which actually included only the months of April through October) was 655 millimeters. The March-through-November average for the three methods of 657 millimeters was equivalent to 70 percent of total precipitation. Continuous measurements were made of incoming and reflected shortwave radiation, incoming and emitted longwave radiation, net radiation, soil-heat flux, soil temperature, horizontal windspeed, and wet- and dry-bulb air temperature. Windspeed and air temperature were measured at heights of 0.5 and 2.0 meters (and also at 1.0 meter after September 1983). Soilmoisture content of the soil zone was measured with a gamma-attenuation gage. Annual precipitation (938 millimeters) and average temperature (10.8 degrees Celsius) at the Sheffield site were virtually identical to long-term averages from nearby National Weather Service stations. Solar radiation averaged 65 percent of that normally expected under clear skies. Net radiation averaged 70.1 watts per square meter and was highest in July and negative during some winter months. Wind direction varied but was predominately south-southeasterly. Wind speed at the 2-meter height averaged 3.5 meters per second and was slightly higher in winter months than the rest of the year. The amount of water stored within the soil zone was greatest in early spring and least in late summer. Seasonal and diurnal trends of evapotranspiration rates mirrored those of net radiation; July was usually the month with the highest evapotranspiration rate. The ratio of sensible- to latentheat fluxes (commonly called the Bowen ratio) for the 2-year study period was 0.38, as averaged from the three methods. Monthly Bowen ratios fluctuated somewhat but averaged about 0.35 for late spring through summer. In fall, the ratio declined to zero or to slightly negative values. When the ratio was negative, the latent-heat flux was slightly greater than the net radiation because of additional energy supplied by' the cooling soil and air. Evapotranspiration calculated by the three methods averaged 75 percent of potential evapotranspiration, as estimated by the Penman equation. There was no apparent seasonal trend in the relation between actual and potential evapotranspiration rates.

  5. Estimating regional CO2 and CH4 fluxes using GOSAT XCO2 and XCH4 observations

    NASA Astrophysics Data System (ADS)

    Fraser, A. C.; Palmer, P. I.; Feng, L.; Parker, R.; Boesch, H.; Cogan, A. J.

    2012-12-01

    We infer regional monthly surface flux estimates for CO2 and CH4, June 2009-December 2010, from proxy dry-air column-averaged mole fractions of CO2 and CH4 from the Greenhouse gases Observing SATellite (GOSAT) using an ensemble Kalman Filter combined with the GEOS-Chem chemistry transport model. We compare these flux estimates with estimates inferred from in situ surface mole fraction measurements and from combining in situ and GOSAT measurements in order to quantify the added value of GOSAT data above the conventional surface measurement network. We find that the error reduction, a measure of how much the posterior fluxes are being informed by the assimilated data, at least doubles when GOSAT measurements are used versus the surface only inversions, with the exception of regions that are well covered by the surface network at the spatial and temporal resolution of our flux estimation calculation. We have incorporated a new online bias correction scheme to account for GOSAT biases. We report global and regional flux estimates inferred from GOSAT and/or in situ measurements. While the global posterior fluxes from GOSAT and in situ measurements agree, we find significant differences in the regional fluxes, particularly over the tropics. We evaluate the posterior fluxes by comparing them against independent surface mole fraction, column, and aircraft measurements using the GEOS-Chem model as an intermediary.

  6. Global atmospheric carbon budget: results from an ensemble of atmospheric CO2 inversions

    NASA Astrophysics Data System (ADS)

    Peylin, P.; Law, R. M.; Gurney, K. R.; Chevallier, F.; Jacobson, A. R.; Maki, T.; Niwa, Y.; Patra, P. K.; Peters, W.; Rayner, P. J.; Rödenbeck, C.; Zhang, X.

    2013-03-01

    Atmospheric CO2 inversions estimate surface carbon fluxes from an optimal fit to atmospheric CO2 measurements, usually including prior constraints on the flux estimates. Eleven sets of carbon flux estimates are compared, generated by different inversions systems that vary in their inversions methods, choice of atmospheric data, transport model and prior information. The inversions were run for at least 5 yr in the period between 1990 and 2009. Mean fluxes for 2001-2004, seasonal cycles, interannual variability and trends are compared for the tropics and northern and southern extra-tropics, and separately for land and ocean. Some continental/basin-scale subdivisions are also considered where the atmospheric network is denser. Four-year mean fluxes are reasonably consistent across inversions at global/latitudinal scale, with a large total (land plus ocean) carbon uptake in the north (-3.3 Pg Cy-1 (±0.6 standard deviation)) nearly equally spread between land and ocean, a significant although more variable source over the tropics (1.6 ± 1.0 Pg Cy-1) and a compensatory sink of similar magnitude in the south (-1.4 ± 0.6 Pg Cy-1) corresponding mainly to an ocean sink. Largest differences across inversions occur in the balance between tropical land sources and southern land sinks. Interannual variability (IAV) in carbon fluxes is larger for land than ocean regions (standard deviation around 1.05 versus 0.34 Pg Cy-1 for the 1996-2007 period), with much higher consistency amoung the inversions for the land. While the tropical land explains most of the IAV (stdev ∼ 0.69 Pg Cy-1), the northern and southern land also contribute (stdev ∼ 0.39 Pg Cy-1). Most inversions tend to indicate an increase of the northern land carbon uptake through the 2000s (around 0.11 Pg Cy-1), shared by North America and North Asia. The mean seasonal cycle appears to be well constrained by the atmospheric data over the northern land (at the continental scale), but still highly dependent on the prior flux seasonality over the ocean. Finally we provide recommendations to interpret the regional fluxes, along with the uncertainty estimates.

  7. Negligible contribution of reservoir dams to organic and inorganic transport in the lower Mimi River, Japan

    NASA Astrophysics Data System (ADS)

    Nukazawa, Kei; Kihara, Kousuke; Suzuki, Yoshihiro

    2017-12-01

    Rivers fulfill an essential ecological role by forming networks for material transport from upland forests to coastal areas. The way in which dams affect the organic and inorganic cycles in such systems is not well understood. Herein, we investigated the longitudinal profiles of the various components of the water chemistry across three cascade dams in Japan: the Yamasubaru Dam, Saigou Dam, and Ohuchibaru Dam, which are situated along the sediment-productive Mimi River in different flow conditions. We analyzed the following water quality components: suspended solids (SS), turbidity, total iron (TFe), dissolved iron (DFe), total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP), humic substance (HS), and major ionic components (Na+, Mg2+, Ca2+, Cl-, NO3-, and SO42-) in the downstream channels of the three dams during the low-intermediate-flow and high-flow events from 2012 to 2014. We estimated hourly loads of each component using hourly turbidity data and discharge data (i.e., L-Q model) separately, and the results are integrated to estimate the annual fluxes. The annual fluxes between the methods were compared to verify predictability of the conventional L-Q models. Annual flux of TOC, TN, DFe, and HS estimated by the turbidity displayed similar values, whereas the flux of SS, TFe, and TP tended to increase downstream of the dams. Among the dams, estimated flux proportions for TP and TFe were higher during high-flow events (74%-94%). Considering geographic conditions (e.g., absence of major tributary between the dams), the result implies that accumulated TP and TFe in the reservoirs may be flushed and transported downstream with SS over the short height dams during flood events. Assuming this process, the reservoir dams probably make only a fractional contribution to the organic and inorganic transport in the catchment studied. The percent flux errors for SS, TFe, and TP fluxes ranged from -7.2% to -97% (except for the TP flux in 2013), which highlights the risk of underestimating these components when using an L-Q model.

  8. Resolving hyporheic and groundwater components of streambed water flux

    USGS Publications Warehouse

    Bhaskar, Aditi S.; Harvey, Judson W.; Henry, Eric J.

    2012-01-01

    Hyporheic and groundwater fluxes typically occur together in permeable sediments beneath flowing stream water. However, streambed water fluxes quantified using the thermal method are usually interpreted as representing either groundwater or hyporheic fluxes. Our purpose was to improve understanding of co-occurring groundwater and hyporheic fluxes using streambed temperature measurements and analysis of one-dimensional heat transport in shallow streambeds. First, we examined how changes in hyporheic and groundwater fluxes affect their relative magnitudes by reevaluating previously published simulations. These indicated that flux magnitudes are largely independent until a threshold is crossed, past which hyporheic fluxes are diminished by much larger (1000-fold) groundwater fluxes. We tested accurate quantification of co-occurring fluxes using one-dimensional approaches that are appropriate for analyzing streambed temperature data collected at field sites. The thermal analytical method, which uses an analytical solution to the one-dimensional heat transport equation, was used to analyze results from a numerical heat transport model, in which hyporheic flow was represented as increased thermal dispersion at shallow depths. We found that co-occurring groundwater and hyporheic fluxes can be quantified in streambeds, although not always accurately. For example, using a temperature time series collected in a sandy streambed, we found that hyporheic and groundwater flow could both be detected when thermal dispersion due to hyporheic flow was significant compared to thermal conduction. We provide guidance for when thermal data can be used to quantify both hyporheic and groundwater fluxes, and we show that neglecting thermal dispersion may affect accuracy and interpretation of estimated streambed water fluxes.

  9. Investigating spatial variability of vertical water fluxes through the streambed in distinctive stream morphologies using temperature and head data

    NASA Astrophysics Data System (ADS)

    Wang, Liping; Jiang, Weiwei; Song, Jinxi; Dou, Xinyi; Guo, Hongtao; Xu, Shaofeng; Zhang, Guotao; Wen, Ming; Long, Yongqing; Li, Qi

    2017-08-01

    Investigating the interaction of groundwater and surface water is key to understanding the hyporheic processes. The vertical water fluxes through a streambed were determined using Darcian flux calculations and vertical sediment temperature profiles to assess the pattern and magnitude of groundwater/surface-water interaction in Beiluo River, China. Field measurements were taken in January 2015 at three different stream morphologies including a meander bend, an anabranching channel and a straight stream channel. Despite the differences of flux direction and magnitude, flux directions based on vertical temperature profiles are in good agreement with results from Darcian flux calculations at the anabranching channel, and the Kruskal-Wallis tests show no significant differences between the estimated upward fluxes based on the two methods at each site. Also, the upward fluxes based on the two methods show similar spatial distributions on the streambed, indicating (1) that higher water fluxes at the meander bend occur from the center of the channel towards the erosional bank, (2) that water fluxes at the anabranching channel are higher near the erosional bank and in the center of the channel, and (3) that in the straight channel, higher water fluxes appear from the center of the channel towards the depositional bank. It is noted that higher fluxes generally occur at certain locations with higher streambed vertical hydraulic conductivity ( K v) or where a higher vertical hydraulic gradient is observed. Moreover, differences of grain size, induced by stream morphology and contrasting erosional and depositional conditions, have significant effects on streambed K v and water fluxes.

  10. Application of Satellite Altimeter Data to Studies of Ocean Surface Heat Flux and Upper Ocean Thermal Processes

    NASA Technical Reports Server (NTRS)

    Yan, Xiao-Hal

    2003-01-01

    This is a one-year cost extension of previous grant but carrying a new award number for the administrative purpose. Supported by this one-year extension, the following research has continued and obtained significant results. 20 papers have been published (9) or submitted (11) to scientific journals in this one-year period. A brief summary of scientific results on: 1. A new method for estimation of the sensible heat flux using satellite vector winds, 2. Pacific warm pool excitation, earth rotation and El Nino Southern Oscillations, 3. A new study of the Mediterranean outflow and Meddies at 400-meter isopycnal surface using multi-sensor data, 4. Response of the coastal ocean to extremely high wind, and 5. Role of wind on the estimation of heat flux using satellite data, are provided below as examples of our many research results conducted in the last year,

  11. A method to estimate the additional uncertainty in gap-filled NEE resulting from long gaps in the CO2 flux record

    Treesearch

    Andrew D. Richardson; David Y. Hollinger

    2007-01-01

    Missing values in any data set create problems for researchers. The process by which missing values are replaced, and the data set is made complete, is generally referred to as imputation. Within the eddy flux community, the term "gap filling" is more commonly applied. A major challenge is that random errors in measured data result in uncertainty in the gap-...

  12. A COMBINED MODELING AND MEASUREMENT TECHNIQUE FOR ESTIMATING WIND-BLOWN DUST EMISSIONS AT OWENS (DRY) LAKE, CA

    EPA Science Inventory

    A refined method of modeling atmospheric dust concentrations due to wind erosion was developed using real-time saltation flux measurements and ambient dust monitoring data at Owens Lake, California. This modeling method may have practical applications for modeling the atmospheric...

  13. A simple method for estimating gross carbon budgets for vegetation in forest ecosystems.

    PubMed

    Ryan, Michael G.

    1991-01-01

    Gross carbon budgets for vegetation in forest ecosystems are difficult to construct because of problems in scaling flux measurements made on small samples over short periods of time and in determining belowground carbon allocation. Recently, empirical relationships have been developed to estimate total belowground carbon allocation from litterfall, and maintenance respiration from tissue nitrogen content. I outline a method for estimating gross carbon budgets using these empirical relationships together with data readily available from ecosystem studies (aboveground wood and canopy production, aboveground wood and canopy biomass, litterfall, and tissue nitrogen contents). Estimates generated with this method are compared with annual carbon fixation estimates from the Forest-BGC model for a lodgepole pine (Pinus contorta Dougl.) and a Pacific silver fir (Abies amabilis Dougl.) chronosequence.

  14. Estimating Thermal Inertia with a Maximum Entropy Boundary Condition

    NASA Astrophysics Data System (ADS)

    Nearing, G.; Moran, M. S.; Scott, R.; Ponce-Campos, G.

    2012-04-01

    Thermal inertia, P [Jm-2s-1/2K-1], is a physical property the land surface which determines resistance to temperature change under seasonal or diurnal heating. It is a function of volumetric heat capacity, c [Jm-3K-1], and thermal conductivity, k [Wm-1K-1] of the soil near the surface: P=√ck. Thermal inertia of soil varies with moisture content due the difference between thermal properties of water and air, and a number of studies have demonstrated that it is feasible to estimate soil moisture given thermal inertia (e.g. Lu et al, 2009, Murray and Verhoef, 2007). We take the common approach to estimating thermal inertia using measurements of surface temperature by modeling the Earth's surface as a 1-dimensional homogeneous diffusive half-space. In this case, surface temperature is a function of the ground heat flux (G) boundary condition and thermal inertia and a daily value of P was estimated by matching measured and modeled diurnal surface temperature fluctuations. The difficulty is in measuring G; we demonstrate that the new maximum entropy production (MEP) method for partitioning net radiation into surface energy fluxes (Wang and Bras, 2011) provides a suitable boundary condition for estimating P. Adding the diffusion representation of heat transfer in the soil reduces the number of free parameters in the MEP model from two to one, and we provided a sensitivity analysis which suggests that, for the purpose of estimating P, it is preferable to parameterize the coupled MEP-diffusion model by the ratio of thermal inertia of the soil to the effective thermal inertia of convective heat transfer to the atmosphere. We used this technique to estimate thermal inertia at two semiarid, non-vegetated locations in the Walnut Gulch Experimental Watershed in southeast AZ, USA and compared these estimates to estimates of P made using the Xue and Cracknell (1995) solution for a linearized ground heat flux boundary condition, and we found that the MEP-diffusion model produced superior thermal inertia estimates. The MEP-diffusion estimates also agreed well with P estimates made using a boundary condition measured with buried flux plates. We further demonstrated the new method using diurnal surface temperature fluctuations estimated from day/night MODIS image pairs and, excluding instances where the soil was extremely dry, found a strong relationship between estimated thermal inertia and measured 5 cm soil moisture. Lu, S., Ju, Z.Q., Ren, T.S. & Horton, R. (2009). A general approach to estimate soil water content from thermal inertia. Agricultural and Forest Meteorology, 149, 1693-1698. Murray, T. & Verhoef, A. (2007). Moving towards a more mechanistic approach in the determination of soil heat flux from remote measurements - I. A universal approach to calculate thermal inertia. Agricultural and Forest Meteorology, 147, 80-87. Wang, J.F. & Bras, R.L. (2011). A model of evapotranspiration based on the theory of maximum entropy production. Water Resources Research, 47. Xue, Y. & Cracknell, A.P. (1995). Advanced thermal inertia modeling. International Journal of Remote Sensing, 16, 431-446.

  15. Estimating sensible heat flux in agricultural screenhouses by the flux-variance and half-order time derivative methods

    NASA Astrophysics Data System (ADS)

    Achiman, Ori; Mekhmandarov, Yonatan; Pirkner, Moran; Tanny, Josef

    2016-04-01

    Previous studies have established that the eddy covariance (EC) technique is reliable for whole canopy flux measurements in agricultural crops covered by porous screens, i.e., screenhouses. Nevertheless, the eddy covariance technique remains difficult to apply in the farm due to costs, operational complexity, and post-processing of data - thereby inviting alternative techniques to be developed. The subject of this research was estimating the sensible heat flux by two turbulent transport techniques, namely, Flux-Variance (FV) and Half-order Time Derivative (HTD) whose instrumentation needs and operational demands are not as elaborate as the EC. The FV is based on the standard deviation of high frequency temperature measurements and a similarity constant CT. The HTD method requires mean air temperature and air velocity data. Measurements were carried out in two types of screenhouses: (i) a banana plantation in a light shading (8%) screenhouse; (ii) a pepper crop in a dense insect-proof (50-mesh) screenhouse. In each screenhouse an EC system was deployed for reference and high frequency air temperature measurements were conducted using miniature thermocouples installed at several levels to identify the optimal measurement height. Quality control analysis showed that turbulence development and flow stationarity conditions in the two structures were suitable for flux measurements by the EC technique. Energy balance closure slopes in the two screenhouses were larger than 0.71, in agreement with results for open fields. Regressions between sensible heat flux measured by EC and estimated by FV resulted with CT values that were usually larger than 1, the typical value for open field. In both shading and insect-proof screenhouses the CT value generally increased with height. The optimal measurement height, defined as the height with maximum R2 of the regression between EC and FV sensible heat fluxes, was just above the screen. CT value at optimal height was 2.64 and 1.52 for the shading and insect-proof screenhouses, respectively, with R2 = 0.73 in both types of structures. FV data analysis of the temperature signal at frequencies lower than 10 Hz showed that R2 of these regressions was insensitive to the data analysis frequency up to 0.5 Hz. This suggests that turbulent transport in the screenhouses was governed by large scale vortices. Regressions between EC and HTD sensible heat fluxes resulted with R2 which slightly decreased with height and had values between 0.3 and 0.4 for both screenhouses. The regression slopes also decreased with height and had values between 0.4 and 0.6. We conclude that in screenhouses the FV technique provides a more reliable estimate of the sensible heat flux than the HTD; however, the latter is simpler and more robust in terms of equipment, operation and data analysis and hence may be more attainable for day-to-day use by the growers.

  16. North American CO2 fluxes for 2007-2015 from NOAA's CarbonTracker-Lagrange Regional Inverse Modeling Framework

    NASA Astrophysics Data System (ADS)

    Andrews, A. E.; Hu, L.; Thoning, K. W.; Nehrkorn, T.; Mountain, M. E.; Jacobson, A. R.; Michalak, A.; Dlugokencky, E. J.; Sweeney, C.; Worthy, D. E. J.; Miller, J. B.; Fischer, M. L.; Biraud, S.; van der Velde, I. R.; Basu, S.; Tans, P. P.

    2017-12-01

    CarbonTracker-Lagrange (CT-L) is a new high-resolution regional inverse modeling system for improved estimation of North American CO2 fluxes. CT-L uses footprints from the Stochastic Time-Inverted Lagrangian Transport (STILT) model driven by high-resolution (10 to 30 km) meteorological fields from the Weather Research and Forecasting (WRF) model. We performed a suite of synthetic-data experiments to evaluate a variety of inversion configurations, including (1) solving for scaling factors to an a priori flux versus additive corrections, (2) solving for fluxes at 3-hrly resolution versus at coarser temporal resolution, (3) solving for fluxes at 1o × 1o resolution versus at large eco-regional scales. Our framework explicitly and objectively solves for the optimal solution with a full error covariance matrix with maximum likelihood estimation, thereby enabling rigorous uncertainty estimates for the derived fluxes. In the synthetic-data inversions, we find that solving for weekly scaling factors of a priori Net Ecosystem Exchange (NEE) at 1o × 1o resolution with optimization of diurnal cycles of CO2 fluxes yields faithful retrieval of the specified "true" fluxes as those solved at 3-hrly resolution. In contrast, a scheme that does not allow for optimization of diurnal cycles of CO2 fluxes suffered from larger aggregation errors. We then applied the optimal inversion setup to estimate North American fluxes for 2007-2015 using real atmospheric CO2 observations, multiple prior estimates of NEE, and multiple boundary values estimated from the NOAA's global Eulerian CarbonTracker (CarbonTracker) and from an empirical approach. Our derived North American land CO2 fluxes show larger seasonal amplitude than those estimated from the CarbonTracker, removing seasonal biases in the CarbonTracker's simulated CO2 mole fractions. Independent evaluations using in-situ CO2 eddy covariance flux measurements and independent aircraft profiles also suggest an improved estimation on North American CO2 fluxes from CT-L. Furthermore, our derived CO2 flux anomalies over North America corresponding to the 2012 North American drought and the 2015 El Niño are larger than derived by the CarbonTracker. They also indicate different responses of ecosystems to those anomalous climatic events.

  17. Gaetice depressus (Crustacea, Varunidae): Species profile and its role in organic carbon and nitrogen flow

    NASA Astrophysics Data System (ADS)

    Wahyudi, A'an. J.; Wada, Shigeki; Aoki, Masakazu; Hama, Takeo

    2015-06-01

    Gaetice depressus is one of the most dominant macrozoobenthos species in boulder shores of intertidal coastal ecosystems in Japan. As recorded in previous studies, this species is also considered as having high density and biomass. Consequently, it is thought to be one of the more important species in the organic matter flow of boulder shores, especially through the food web. In this study, some taxonomic problems related to G. depressus were tackled and the autoecology and ecological processes in the intertidal ecosystem of G. depressus, such as organic matter flow, were investigated. Furthermore, in order to clarify the taxonomy description, resolve inconsistencies in the scientific name, and learn about the life history, a literature review was conducted. Seasonal changes in density, morphology pattern and population structure were determined based on the data obtained in Ebisu Island, Japan. Then, the role of G. depressus was determined by estimating the intake and emittance fluxes of organic carbon and nitrogen through ingestion and egestion process in the boulder shores of Ebisu Island. A feeding rate experiment was also conducted in order to estimate the intake flux by using the catch-release-recapture method. Meanwhile, to estimate the emittance flux, a defecation rate experiment was conducted by catching some individuals of G. depressus, and then incubating them in the laboratory. The feeding rate measured by the speed of diet consumption of G. depressus was about 12.6 mg ind-1 h-1. Considering the average density, the intake flux through the feeding process could be estimated as 25.2 mgC m-2 h-1 and 2.6 mgN m-2 h-1. On the other hand, G. depressus egested fecal pellet at the rate of 5.4 mg ind-1 h-1. The average emittance flux through the fecal pellet egesting process is estimated at 5.6 mgC m-2 h-1 and 0.7 mgN m-2 h-1. Therefore, it can be estimated that about 25% of organic matter from diet is egested as fecal pellet, which means that about 75% of the intake flux of organic carbon and nitrogen is used for the total assimilation of G. depressus. Intake flux was also considered as affecting the high dynamism of primary producer consumption. The total population of G. depressus is estimated to consume about 18.4% of primary producer in average throughout the year. Therefore, the turnover time of primary producer by consumption of G. depressus was about five days.

  18. Stepwise inference of likely dynamic flux distributions from metabolic time series data.

    PubMed

    Faraji, Mojdeh; Voit, Eberhard O

    2017-07-15

    Most metabolic pathways contain more reactions than metabolites and therefore have a wide stoichiometric matrix that corresponds to infinitely many possible flux distributions that are perfectly compatible with the dynamics of the metabolites in a given dataset. This under-determinedness poses a challenge for the quantitative characterization of flux distributions from time series data and thus for the design of adequate, predictive models. Here we propose a method that reduces the degrees of freedom in a stepwise manner and leads to a dynamic flux distribution that is, in a statistical sense, likely to be close to the true distribution. We applied the proposed method to the lignin biosynthesis pathway in switchgrass. The system consists of 16 metabolites and 23 enzymatic reactions. It has seven degrees of freedom and therefore admits a large space of dynamic flux distributions that all fit a set of metabolic time series data equally well. The proposed method reduces this space in a systematic and biologically reasonable manner and converges to a likely dynamic flux distribution in just a few iterations. The estimated solution and the true flux distribution, which is known in this case, show excellent agreement and thereby lend support to the method. The computational model was implemented in MATLAB (version R2014a, The MathWorks, Natick, MA). The source code is available at https://github.gatech.edu/VoitLab/Stepwise-Inference-of-Likely-Dynamic-Flux-Distributions and www.bst.bme.gatech.edu/research.php . mojdeh@gatech.edu or eberhard.voit@bme.gatech.edu. Supplementary data are available at Bioinformatics online. © The Author (2017). Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com

  19. 13C-Labeled Gluconate Tracing as a Direct and Accurate Method for Determining the Pentose Phosphate Pathway Split Ratio in Penicillium chrysogenum

    PubMed Central

    Kleijn, Roelco J.; van Winden, Wouter A.; Ras, Cor; van Gulik, Walter M.; Schipper, Dick; Heijnen, Joseph J.

    2006-01-01

    In this study we developed a new method for accurately determining the pentose phosphate pathway (PPP) split ratio, an important metabolic parameter in the primary metabolism of a cell. This method is based on simultaneous feeding of unlabeled glucose and trace amounts of [U-13C]gluconate, followed by measurement of the mass isotopomers of the intracellular metabolites surrounding the 6-phosphogluconate node. The gluconate tracer method was used with a penicillin G-producing chemostat culture of the filamentous fungus Penicillium chrysogenum. For comparison, a 13C-labeling-based metabolic flux analysis (MFA) was performed for glycolysis and the PPP of P. chrysogenum. For the first time mass isotopomer measurements of 13C-labeled primary metabolites are reported for P. chrysogenum and used for a 13C-based MFA. Estimation of the PPP split ratio of P. chrysogenum at a growth rate of 0.02 h−1 yielded comparable values for the gluconate tracer method and the 13C-based MFA method, 51.8% and 51.1%, respectively. A sensitivity analysis of the estimated PPP split ratios showed that the 95% confidence interval was almost threefold smaller for the gluconate tracer method than for the 13C-based MFA method (40.0 to 63.5% and 46.0 to 56.5%, respectively). From these results we concluded that the gluconate tracer method permits accurate determination of the PPP split ratio but provides no information about the remaining cellular metabolism, while the 13C-based MFA method permits estimation of multiple fluxes but provides a less accurate estimate of the PPP split ratio. PMID:16820467

  20. Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

    NASA Astrophysics Data System (ADS)

    Brioude, J.; Angevine, W. M.; Ahmadov, R.; Kim, S.-W.; Evan, S.; McKeen, S. A.; Hsie, E.-Y.; Frost, G. J.; Neuman, J. A.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Holloway, J.; Brown, S. S.; Nowak, J. B.; Roberts, J. M.; Wofsy, S. C.; Santoni, G. W.; Oda, T.; Trainer, M.

    2013-04-01

    We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% in LA County and by 37% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% in LA County and by 27% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 Tg yr-1 in SoCAB. A flight during ITCT (Intercontinental Transport and Chemical Transformation) in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% in LA County but decreased by 4% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, a gridded CARB inventory and the posterior inventories derived in this study. The biases in WRF-Chem ozone were reduced and correlations were increased using the posterior from this study compared with simulations with the two bottom-up inventories, suggesting that improving the spatial distribution of ozone precursor surface emissions is also important in mesoscale chemistry simulations.

  1. Canopy Level Emissions of 2-methyl-3-buten-2-ol ...

    EPA Pesticide Factsheets

    Emissions of biogenic volatile organic compounds (BVOC) observed during 2007 from a Pinus taeda experimental plantation in Central North Carolina are compared with model estimates from MEGAN 2.1. Relaxed Eddy Accumulation (REA) estimates of 2-methyl-3-buten-2-ol (MBO) fluxes are a factor of 3-4 higher than model estimates. MEGAN2.1 monoterpene emission estimates were approximately a factor of two higher than REA flux measurements. MEGAN2.1 β-caryophyllene emission estimates were within 60% of growing season REA flux estimates, but were several times higher than REA fluxes during cooler, dormant season periods. The sum of other sesquiterpene emissions estimated by MEGAN2.1 was several times higher than REA estimates throughout the year. Model components are examined to understand these discrepancies. Summertime LAI (and therefore foliar biomass) is a factor of two higher than assumed in MEGAN for the Pinus taeda default. Increasing the canopy mean MBO emission factor from 0.35 to 1.0 mg m-2 hr-1 also reduces MEGAN2.1 vs flux differences. This increase is within current emission factor uncertainties. The algorithm within MEGAN which adjusts isoprene emission estimates as a function of the previous 24 hour’s temperatures and light seems to also improve seasonal MEGAN MBO correlation with REA fluxes. Including the effects of the previous 240 hours, however, seems to degrade temporal model correlation with fluxes. This paper describes an emission inventory and mod

  2. Turbulent fluxes by "Conditional Eddy Sampling"

    NASA Astrophysics Data System (ADS)

    Siebicke, Lukas

    2015-04-01

    Turbulent flux measurements are key to understanding ecosystem scale energy and matter exchange, including atmospheric trace gases. While the eddy covariance approach has evolved as an invaluable tool to quantify fluxes of e.g. CO2 and H2O continuously, it is limited to very few atmospheric constituents for which sufficiently fast analyzers exist. High instrument cost, lack of field-readiness or high power consumption (e.g. many recent laser-based systems requiring strong vacuum) further impair application to other tracers. Alternative micrometeorological approaches such as conditional sampling might overcome major limitations. Although the idea of eddy accumulation has already been proposed by Desjardin in 1972 (Desjardin, 1977), at the time it could not be realized for trace gases. Major simplifications by Businger and Oncley (1990) lead to it's widespread application as 'Relaxed Eddy Accumulation' (REA). However, those simplifications (flux gradient similarity with constant flow rate sampling irrespective of vertical wind velocity and introduction of a deadband around zero vertical wind velocity) have degraded eddy accumulation to an indirect method, introducing issues of scalar similarity and often lack of suitable scalar flux proxies. Here we present a real implementation of a true eddy accumulation system according to the original concept. Key to our approach, which we call 'Conditional Eddy Sampling' (CES), is the mathematical formulation of conditional sampling in it's true form of a direct eddy flux measurement paired with a performant real implementation. Dedicated hardware controlled by near-real-time software allows full signal recovery at 10 or 20 Hz, very fast valve switching, instant vertical wind velocity proportional flow rate control, virtually no deadband and adaptive power management. Demonstrated system performance often exceeds requirements for flux measurements by orders of magnitude. The system's exceptionally low power consumption is ideal for the field (one to two orders of magnitude lower compared to current closed-path laser based eddy covariance systems). Potential applications include fluxes of CO2, CH4, N2O, VOCs and other tracers. Finally we assess the flux accuracy of the Conditional Eddy Sampling (CES) approach as in our real implementation relative to alternative techniques including eddy covariance (EC) and relaxed eddy accumulation (REA). We further quantify various sources of instrument and method specific measurement errors. This comparison uses real measurements of 20 Hz turbulent time series of 3D wind velocity, sonic temperature and CO2 mixing ratio over a mixed decidious forest at the 'ICOS' flux tower site 'Hainich', Germany. Results from a simulation using real wind and CO2 timeseries from the Hainich site from 30 April to 3 November 2014 and real instrument performance suggest that the maximum flux estimates error (50% and 75% error quantiles) from Conditional Eddy Sampling (CES) relative to the true flux is 1.3% and 10%, respectively for monthly net fluxes, 1.6% and 7%, respectively for daily net fluxes and 8% and 35%, respectively for 30-minute CO2 flux estimates. Those results from CES are promising and outperform our REA estimates by about a factor of 50 assuming REA with constant b value. Results include flux time series from the EC, CES and REA approaches from 30-min to annual resolution.

  3. A New Approach to Quantify Shallow Water Hydrologic Exchanges in a Large Regulated River Reach

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhou, Tian; Huang, Maoyi; Bao, Jie

    Hyporheic exchange is a crucial component in the water cycle. The strength of the exchange directly affects the biogeochemical and ecological processes occurred in the hyporheic zone from micro to reach scale. Hyporheic fluxes can be quantified using many direct and indirect measurements as well as analytical and numerical modeling tools. However, in a relatively large river, these methods are limited by accessibility, the difficulty of performing representative sampling, and complexity of geomorphologic features and subsurface properties. In rivers regulated by hydroelectric dams, quantifying hyporheic fluxes becomes more challenging due to frequent hydropeaking events, featured by hourly to daily variationsmore » in flow and river stages created by dam operations(Hancock 2002). In this study, we developed and validated methods that based on field measurements to estimate shallow water hyporheic fluxes across the river bed at five locations along the shoreline of the Columbia River. Vertical thermal profiles measured by self-recording thermistors were combined with time series of hydraulic gradients derived from river stage and water level at in-land wells to estimate the hyporheic flux rate. The results suggested that the hyporheic exchange rate had high spatial and temporal heterogeneities over the riverbed, with predicted flux rate varies from +1×10 -6 m s-1 to -1.5×10 -6 m s -1 under various flow conditions at the some locations, and with a magnitude of fluxes 6-9 times higher in the primary channel than that in the secondary channel. Furthermore, the variations on shallow water hyporheic flow dynamics may further lead to different biogeochemical and ecological consequences at different river segments.« less

  4. A New Approach to Quantify Shallow Water Hydrologic Exchanges in a Large Regulated River Reach

    DOE PAGES

    Zhou, Tian; Huang, Maoyi; Bao, Jie; ...

    2017-09-15

    Hyporheic exchange is a crucial component in the water cycle. The strength of the exchange directly affects the biogeochemical and ecological processes occurred in the hyporheic zone from micro to reach scale. Hyporheic fluxes can be quantified using many direct and indirect measurements as well as analytical and numerical modeling tools. However, in a relatively large river, these methods are limited by accessibility, the difficulty of performing representative sampling, and complexity of geomorphologic features and subsurface properties. In rivers regulated by hydroelectric dams, quantifying hyporheic fluxes becomes more challenging due to frequent hydropeaking events, featured by hourly to daily variationsmore » in flow and river stages created by dam operations(Hancock 2002). In this study, we developed and validated methods that based on field measurements to estimate shallow water hyporheic fluxes across the river bed at five locations along the shoreline of the Columbia River. Vertical thermal profiles measured by self-recording thermistors were combined with time series of hydraulic gradients derived from river stage and water level at in-land wells to estimate the hyporheic flux rate. The results suggested that the hyporheic exchange rate had high spatial and temporal heterogeneities over the riverbed, with predicted flux rate varies from +1×10 -6 m s-1 to -1.5×10 -6 m s -1 under various flow conditions at the some locations, and with a magnitude of fluxes 6-9 times higher in the primary channel than that in the secondary channel. Furthermore, the variations on shallow water hyporheic flow dynamics may further lead to different biogeochemical and ecological consequences at different river segments.« less

  5. Isotopically nonstationary 13C flux analysis of changes in Arabidopsis thaliana leaf metabolism due to high light acclimation

    DOE PAGES

    Ma, Fangfang; Jazmin, Lara J.; Young, Jamey D.; ...

    2014-11-03

    Improving plant productivity is an important aim for metabolic engineering. There are few comprehensive methods that quantitatively describe leaf metabolism, although such information would be valuable for increasing photosynthetic capacity, enhancing biomass production, and rerouting carbon flux toward desirable end products. Isotopically nonstationary metabolic flux analysis (INST-MFA) has been previously applied to map carbon fluxes in photoautotrophic bacteria, which involves model-based regression of transient 13C-labeling patterns of intracellular metabolites. However, experimental and computational difficulties have hindered its application to terrestrial plant systems. Here, we performed in vivo isotopic labeling of Arabidopsis thaliana rosettes with 13CO 2 and estimated fluxes throughoutmore » leaf photosynthetic metabolism by INST-MFA. Plants grown at 200 µmol m $-$2s $-$1 light were compared with plants acclimated for 9 d at an irradiance of 500 µmol∙m $-$2∙s $-$1. Approximately 1,400 independent mass isotopomer measurements obtained from analysis of 37 metabolite fragment ions were regressed to estimate 136 total fluxes (54 free fluxes) under each condition. The results provide a comprehensive description of changes in carbon partitioning and overall photosynthetic flux after long-term developmental acclimation of leaves to high light. Despite a doubling in the carboxylation rate, the photorespiratory flux increased from 17 to 28% of net CO 2 assimilation with high-light acclimation (Vc/Vo: 3.5:1 vs. 2.3:1, respectively). In conclusion, this study highlights the potential of 13C INST-MFA to describe emergent flux phenotypes that respond to environmental conditions or plant physiology and cannot be obtained by other complementary approaches.« less

  6. Emissions of organic compounds from produced water ponds I: Characteristics and speciation.

    PubMed

    Lyman, Seth N; Mansfield, Marc L; Tran, Huy N Q; Evans, Jordan D; Jones, Colleen; O'Neil, Trevor; Bowers, Ric; Smith, Ann; Keslar, Cara

    2018-04-01

    We measured fluxes of methane, a suite of non-methane hydrocarbons (C2-C11), light alcohols, and carbon dioxide from oil and gas produced water storage and disposal ponds in Utah (Uinta Basin) and Wyoming (Upper Green River Basin) United States during 2013-2016. In this paper, we discuss the characteristics of produced water composition and air-water fluxes, with a focus on flux chamber measurements. In companion papers, we will (1) report on inverse modeling methods used to estimate emissions from produced water ponds, including comparisons with flux chamber measurements, and (2) discuss the development of mass transfer coefficients to estimate emissions and place emissions from produced water ponds in the context of all regional oil and gas-related emissions. Alcohols (made up mostly of methanol) were the most abundant organic compound group in produced water (91% of total volatile organic concentration, with upper and lower 95% confidence levels of 89 and 93%) but accounted for only 34% (28 to 41%) of total organic compound fluxes from produced water ponds. Non-methane hydrocarbons, which are much less water-soluble than methanol and less abundant in produced water, accounted for the majority of emitted organics. C6-C9 alkanes and aromatics dominated hydrocarbon fluxes, perhaps because lighter hydrocarbons had already volatilized from produced water prior to its arrival in storage or disposal ponds, while heavier hydrocarbons are less water soluble and less volatile. Fluxes of formaldehyde and other carbonyls were low (1% (1 to 2%) of total organic compound flux). The speciation and magnitude of fluxes varied strongly across the facilities measured and with the amount of time water had been exposed to the atmosphere. The presence or absence of ice also impacted fluxes. Copyright © 2017 Elsevier B.V. All rights reserved.

  7. A new estimation of global soil greenhouse gas fluxes using a simple data-oriented model.

    PubMed

    Hashimoto, Shoji

    2012-01-01

    Soil greenhouse gas fluxes (particularly CO(2), CH(4), and N(2)O) play important roles in climate change. However, despite the importance of these soil greenhouse gases, the number of reports on global soil greenhouse gas fluxes is limited. Here, new estimates are presented for global soil CO(2) emission (total soil respiration), CH(4) uptake, and N(2)O emission fluxes, using a simple data-oriented model. The estimated global fluxes for CO(2) emission, CH(4) uptake, and N(2)O emission were 78 Pg C yr(-1) (Monte Carlo 95% confidence interval, 64-95 Pg C yr(-1)), 18 Tg C yr(-1) (11-23 Tg C yr(-1)), and 4.4 Tg N yr(-1) (1.4-11.1 Tg N yr(-1)), respectively. Tropical regions were the largest contributor of all of the gases, particularly the CO(2) and N(2)O fluxes. The soil CO(2) and N(2)O fluxes had more pronounced seasonal patterns than the soil CH(4) flux. The collected estimates, including both the previous and the present estimates, demonstrate that the means of the best estimates from each study were 79 Pg C yr(-1) (291 Pg CO(2) yr(-1); coefficient of variation, CV = 13%, N = 6) for CO(2), 21 Tg C yr(-1) (29 Tg CH(4) yr(-1); CV = 24%, N = 24) for CH(4), and 7.8 Tg N yr(-1) (12.2 Tg N(2)O yr(-1); CV = 38%, N = 11) for N(2)O. For N(2)O, the mean of the estimates that was calculated by excluding the earliest two estimates was 6.6 Tg N yr(-1) (10.4 Tg N(2)O yr(-1); CV = 22%, N = 9). The reported estimates vary and have large degrees of uncertainty but their overall magnitudes are in general agreement. To further minimize the uncertainty of soil greenhouse gas flux estimates, it is necessary to build global databases and identify key processes in describing global soil greenhouse gas fluxes.

  8. A New Estimation of Global Soil Greenhouse Gas Fluxes Using a Simple Data-Oriented Model

    PubMed Central

    Hashimoto, Shoji

    2012-01-01

    Soil greenhouse gas fluxes (particularly CO2, CH4, and N2O) play important roles in climate change. However, despite the importance of these soil greenhouse gases, the number of reports on global soil greenhouse gas fluxes is limited. Here, new estimates are presented for global soil CO2 emission (total soil respiration), CH4 uptake, and N2O emission fluxes, using a simple data-oriented model. The estimated global fluxes for CO2 emission, CH4 uptake, and N2O emission were 78 Pg C yr−1 (Monte Carlo 95% confidence interval, 64–95 Pg C yr−1), 18 Tg C yr−1 (11–23 Tg C yr−1), and 4.4 Tg N yr−1 (1.4–11.1 Tg N yr−1), respectively. Tropical regions were the largest contributor of all of the gases, particularly the CO2 and N2O fluxes. The soil CO2 and N2O fluxes had more pronounced seasonal patterns than the soil CH4 flux. The collected estimates, including both the previous and the present estimates, demonstrate that the means of the best estimates from each study were 79 Pg C yr−1 (291 Pg CO2 yr−1; coefficient of variation, CV = 13%, N = 6) for CO2, 21 Tg C yr−1 (29 Tg CH4 yr−1; CV = 24%, N = 24) for CH4, and 7.8 Tg N yr−1 (12.2 Tg N2O yr−1; CV = 38%, N = 11) for N2O. For N2O, the mean of the estimates that was calculated by excluding the earliest two estimates was 6.6 Tg N yr−1 (10.4 Tg N2O yr−1; CV = 22%, N = 9). The reported estimates vary and have large degrees of uncertainty but their overall magnitudes are in general agreement. To further minimize the uncertainty of soil greenhouse gas flux estimates, it is necessary to build global databases and identify key processes in describing global soil greenhouse gas fluxes. PMID:22876295

  9. Revisiting the global surface energy budgets with maximum-entropy-production model of surface heat fluxes

    NASA Astrophysics Data System (ADS)

    Huang, Shih-Yu; Deng, Yi; Wang, Jingfeng

    2017-09-01

    The maximum-entropy-production (MEP) model of surface heat fluxes, based on contemporary non-equilibrium thermodynamics, information theory, and atmospheric turbulence theory, is used to re-estimate the global surface heat fluxes. The MEP model predicted surface fluxes automatically balance the surface energy budgets at all time and space scales without the explicit use of near-surface temperature and moisture gradient, wind speed and surface roughness data. The new MEP-based global annual mean fluxes over the land surface, using input data of surface radiation, temperature data from National Aeronautics and Space Administration-Clouds and the Earth's Radiant Energy System (NASA CERES) supplemented by surface specific humidity data from the Modern-Era Retrospective Analysis for Research and Applications (MERRA), agree closely with previous estimates. The new estimate of ocean evaporation, not using the MERRA reanalysis data as model inputs, is lower than previous estimates, while the new estimate of ocean sensible heat flux is higher than previously reported. The MEP model also produces the first global map of ocean surface heat flux that is not available from existing global reanalysis products.

  10. Neutrino flux prediction at MiniBooNE

    NASA Astrophysics Data System (ADS)

    Aguilar-Arevalo, A. A.; Anderson, C. E.; Bazarko, A. O.; Brice, S. J.; Brown, B. C.; Bugel, L.; Cao, J.; Coney, L.; Conrad, J. M.; Cox, D. C.; Curioni, A.; Djurcic, Z.; Finley, D. A.; Fleming, B. T.; Ford, R.; Garcia, F. G.; Garvey, G. T.; Green, C.; Green, J. A.; Hart, T. L.; Hawker, E.; Imlay, R.; Johnson, R. A.; Karagiorgi, G.; Kasper, P.; Katori, T.; Kobilarcik, T.; Kourbanis, I.; Koutsoliotas, S.; Laird, E. M.; Linden, S. K.; Link, J. M.; Liu, Y.; Liu, Y.; Louis, W. C.; Mahn, K. B. M.; Marsh, W.; Martin, P. S.; McGregor, G.; Metcalf, W.; Meyers, P. D.; Mills, F.; Mills, G. B.; Monroe, J.; Moore, C. D.; Nelson, R. H.; Nguyen, V. T.; Nienaber, P.; Nowak, J. A.; Ouedraogo, S.; Patterson, R. B.; Perevalov, D.; Polly, C. C.; Prebys, E.; Raaf, J. L.; Ray, H.; Roe, B. P.; Russell, A. D.; Sandberg, V.; Schirato, R.; Schmitz, D.; Shaevitz, M. H.; Shoemaker, F. C.; Smith, D.; Soderberg, M.; Sorel, M.; Spentzouris, P.; Stancu, I.; Stefanski, R. J.; Sung, M.; Tanaka, H. A.; Tayloe, R.; Tzanov, M.; van de Water, R.; Wascko, M. O.; White, D. H.; Wilking, M. J.; Yang, H. J.; Zeller, G. P.; Zimmerman, E. D.

    2009-04-01

    The booster neutrino experiment (MiniBooNE) searches for νμ→νe oscillations using the O(1GeV) neutrino beam produced by the booster synchrotron at the Fermi National Accelerator Laboratory). The booster delivers protons with 8 GeV kinetic energy (8.89GeV/c momentum) to a beryllium target, producing neutrinos from the decay of secondary particles in the beam line. We describe the Monte Carlo simulation methods used to estimate the flux of neutrinos from the beam line incident on the MiniBooNE detector for both polarities of the focusing horn. The simulation uses the Geant4 framework for propagating particles, accounting for electromagnetic processes and hadronic interactions in the beam line materials, as well as the decay of particles. The absolute double differential cross sections of pion and kaon production in the simulation have been tuned to match external measurements, as have the hadronic cross sections for nucleons and pions. The statistical precision of the flux predictions is enhanced through reweighting and resampling techniques. Systematic errors in the flux estimation have been determined by varying parameters within their uncertainties, accounting for correlations where appropriate.

  11. Observations of enhanced aerosol longwave radiative forcing over an urban environment

    NASA Astrophysics Data System (ADS)

    Panicker, A. S.; Pandithurai, G.; Safai, P. D.; Kewat, S.

    2008-02-01

    Collocated measurements of sun/sky radiance, aerosol chemical composition and radiative fluxes have been utilized to estimate longwave aerosol radiative forcing over Pune, an Indian urban site during dry winter [Dec2004 to Feb2005] by two methods. Hybrid method which uses observed downwelling and modeled upwelling longwave fluxes for different aerosol loadings yielded a surface forcing of 9.4 Wm-2. Model approach includes utilization of skyradiometer derived spectral aerosol optical properties in the visible and near infra-red wavelengths, modeled aerosol properties in 1.2-40 μm using observed soot and chemical composition data, MODIS water vapor and TOMS column ozone in a radiative transfer model. Estimates from model method showed longwave enhancement of 6.5 and 8.2 Wm-2 at the surface with tropical model atmosphere and temporally varying profiles of temperature and humidity, respectively. Study reveals that about 25% of the aerosol shortwave cooling is being compensated by increase in longwave radiation due to aerosol absorption.

  12. Error estimation for CFD aeroheating prediction under rarefied flow condition

    NASA Astrophysics Data System (ADS)

    Jiang, Yazhong; Gao, Zhenxun; Jiang, Chongwen; Lee, Chunhian

    2014-12-01

    Both direct simulation Monte Carlo (DSMC) and Computational Fluid Dynamics (CFD) methods have become widely used for aerodynamic prediction when reentry vehicles experience different flow regimes during flight. The implementation of slip boundary conditions in the traditional CFD method under Navier-Stokes-Fourier (NSF) framework can extend the validity of this approach further into transitional regime, with the benefit that much less computational cost is demanded compared to DSMC simulation. Correspondingly, an increasing error arises in aeroheating calculation as the flow becomes more rarefied. To estimate the relative error of heat flux when applying this method for a rarefied flow in transitional regime, theoretical derivation is conducted and a dimensionless parameter ɛ is proposed by approximately analyzing the ratio of the second order term to first order term in the heat flux expression in Burnett equation. DSMC simulation for hypersonic flow over a cylinder in transitional regime is performed to test the performance of parameter ɛ, compared with two other parameters, Knρ and MaṡKnρ.

  13. All-sky brightness monitoring of light pollution with astronomical methods.

    PubMed

    Rabaza, O; Galadí-Enríquez, D; Estrella, A Espín; Dols, F Aznar

    2010-06-01

    This paper describes a mobile prototype and a protocol to measure light pollution based on astronomical methods. The prototype takes three all-sky images using BVR filters of the Johnson-Cousins astronomical photometric system. The stars are then identified in the images of the Hipparcos and General Catalogue of Photometric Data II astronomical catalogues, and are used as calibration sources. This method permits the measurement of night-sky brightness and facilitates an estimate of which fraction is due to the light up-scattered in the atmosphere by a wide variety of man-made sources. This is achieved by our software, which compares the sky background flux to that of many stars of known brightness. The reduced weight and dimensions of the prototype allow the user to make measurements from virtually any location. This prototype is capable of measuring the sky distribution of light pollution, and also provides an accurate estimate of the background flux at each photometric band. (c) 2010 Elsevier Ltd. All rights reserved.

  14. A model of heat transfer in sapwood and implications for sap flux density measurements using thermal dissipation probes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wullschleger, Stan D; Childs, Kenneth W; King, Anthony Wayne

    2011-01-01

    A variety of thermal approaches are used to estimate sap flux density in stems of woody plants. Models have proven valuable tools for interpreting the behavior of heat pulse, heat balance, and heat field deformation techniques, but have seldom been used to describe heat transfer dynamics for the heat dissipation method. Therefore, to better understand the behavior of heat dissipation probes, a model was developed that takes into account the thermal properties of wood, the physical dimensions and thermal characteristics of the probes, and the conductive and convective heat transfer that occurs due to water flow in the sapwood. Probesmore » were simulated as aluminum tubes 20 mm in length and 2 mm in diameter, whereas sapwood, heartwood, and bark each had a density and water fraction that determined their thermal properties. Base simulations assumed a constant sap flux density with sapwood depth and no wounding or physical disruption of xylem beyond the 2 mm diameter hole drilled for probe installation. Simulations across a range of sap flux densities showed that the dimensionless quantity k defined as ( Tm T)/ T where Tm is the temperature differential ( T) between the heated and unheated probe under zero flow conditions was dependent on the thermal conductivity of the sapwood. The relationship between sap flux density and k was also sensitive to radial gradients in sap flux density and to xylem disruption near the probe. Monte Carlo analysis in which 1000 simulations were conducted while simultaneously varying thermal conductivity and wound diameter revealed that sap flux density and k showed considerable departure from the original calibration equation used with this technique. The departure was greatest for abrupt patterns of radial variation typical of ring-porous species. Depending on the specific combination of thermal conductivity and wound diameter, use of the original calibration equation resulted in an 81% under- to 48% over-estimation of sap flux density at modest flux rates. Future studies should verify these simulations and assess their utility in estimating sap flux density for this widely used technique.« less

  15. Evaluation of stormwater micropollutant source control and end-of-pipe control strategies using an uncertainty-calibrated integrated dynamic simulation model.

    PubMed

    Vezzaro, L; Sharma, A K; Ledin, A; Mikkelsen, P S

    2015-03-15

    The estimation of micropollutant (MP) fluxes in stormwater systems is a fundamental prerequisite when preparing strategies to reduce stormwater MP discharges to natural waters. Dynamic integrated models can be important tools in this step, as they can be used to integrate the limited data provided by monitoring campaigns and to evaluate the performance of different strategies based on model simulation results. This study presents an example where six different control strategies, including both source-control and end-of-pipe treatment, were compared. The comparison focused on fluxes of heavy metals (copper, zinc) and organic compounds (fluoranthene). MP fluxes were estimated by using an integrated dynamic model, in combination with stormwater quality measurements. MP sources were identified by using GIS land usage data, runoff quality was simulated by using a conceptual accumulation/washoff model, and a stormwater retention pond was simulated by using a dynamic treatment model based on MP inherent properties. Uncertainty in the results was estimated with a pseudo-Bayesian method. Despite the great uncertainty in the MP fluxes estimated by the runoff quality model, it was possible to compare the six scenarios in terms of discharged MP fluxes, compliance with water quality criteria, and sediment accumulation. Source-control strategies obtained better results in terms of reduction of MP emissions, but all the simulated strategies failed in fulfilling the criteria based on emission limit values. The results presented in this study shows how the efficiency of MP pollution control strategies can be quantified by combining advanced modeling tools (integrated stormwater quality model, uncertainty calibration). Copyright © 2014 Elsevier Ltd. All rights reserved.

  16. Uncertainty analysis technique for OMEGA Dante measurements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    May, M. J.; Widmann, K.; Sorce, C.

    2010-10-15

    The Dante is an 18 channel x-ray filtered diode array which records the spectrally and temporally resolved radiation flux from various targets (e.g., hohlraums, etc.) at x-ray energies between 50 eV and 10 keV. It is a main diagnostic installed on the OMEGA laser facility at the Laboratory for Laser Energetics, University of Rochester. The absolute flux is determined from the photometric calibration of the x-ray diodes, filters and mirrors, and an unfold algorithm. Understanding the errors on this absolute measurement is critical for understanding hohlraum energetic physics. We present a new method for quantifying the uncertainties on the determinedmore » flux using a Monte Carlo parameter variation technique. This technique combines the uncertainties in both the unfold algorithm and the error from the absolute calibration of each channel into a one sigma Gaussian error function. One thousand test voltage sets are created using these error functions and processed by the unfold algorithm to produce individual spectra and fluxes. Statistical methods are applied to the resultant set of fluxes to estimate error bars on the measurements.« less

  17. Uncertainty Analysis Technique for OMEGA Dante Measurements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    May, M J; Widmann, K; Sorce, C

    2010-05-07

    The Dante is an 18 channel X-ray filtered diode array which records the spectrally and temporally resolved radiation flux from various targets (e.g. hohlraums, etc.) at X-ray energies between 50 eV to 10 keV. It is a main diagnostics installed on the OMEGA laser facility at the Laboratory for Laser Energetics, University of Rochester. The absolute flux is determined from the photometric calibration of the X-ray diodes, filters and mirrors and an unfold algorithm. Understanding the errors on this absolute measurement is critical for understanding hohlraum energetic physics. We present a new method for quantifying the uncertainties on the determinedmore » flux using a Monte-Carlo parameter variation technique. This technique combines the uncertainties in both the unfold algorithm and the error from the absolute calibration of each channel into a one sigma Gaussian error function. One thousand test voltage sets are created using these error functions and processed by the unfold algorithm to produce individual spectra and fluxes. Statistical methods are applied to the resultant set of fluxes to estimate error bars on the measurements.« less

  18. In situ measurement of atomic oxygen flux using a silver film sensor onboard "TianTuo 1" nanosatellite

    NASA Astrophysics Data System (ADS)

    Cheng, Yun; Chen, Xiaoqian; Sheng, Tao

    2016-01-01

    Research into the measurement of atomic oxygen (AO) flux in a low Earth orbit (LEO) is highly significant for the development of spacecraft surface materials as well as for enhancing the reliability of space instruments. In the present study, we studied a silver film resistance method for AO flux measurement and we established a quantitative calculation model. Moreover, we designed a silver film sensor for space flight tests with a mass of about 100 g and a peak power consumption of less than 0.2 W. The effect of AO on the silver film was demonstrated in a ground-based simulation experiment and compared with the Kapton-mass-loss method. For the space flight test, the AO flux was estimated by monitoring the change in the resistance in the linear part of the silver/AO reaction regime. Finally, the sensor was carried onboard our nanosatellite ;TianTuo 1; to obtain in situ measurements of the AO flux during a 476 km sun synchronous orbit. The result was critically compared with theoretical predictions, which validated the design of this sensor.

  19. A second-order bulk boundary-layer model

    NASA Technical Reports Server (NTRS)

    Randall, David A.; Shao, Qingqiu; Moeng, Chin-Hoh

    1992-01-01

    Bulk mass-flux models represent the large eddies that are primarily responsible for the turbulent fluxes in the planetary boundary layer as convective circulations, with an associated convective mass flux. In order for such models to be useful, it is necessary to determine the fractional area covered by rising motion in the convective circulations. This fraction can be used as an estimate of the cloud amount, under certain conditions. 'Matching' conditions have been developed that relate the convective mass flux to the ventilation and entrainment mass fluxes. These are based on conservation equations for the scalar means and variances in the entrainment and ventilation layers. Methods are presented to determine both the fractional area covered by rising motion and the convective mass flux. The requirement of variance balance is used to relax the 'well-mixed' assumption. The vertical structures of the mean state and the turbulent fluxes are determined analytically. Several aspects of this simple model's formulation are evaluated using results from large-eddy simulations.

  20. A New Unified Analysis of Estimate Errors by Model-Matching Phase-Estimation Methods for Sensorless Drive of Permanent-Magnet Synchronous Motors and New Trajectory-Oriented Vector Control, Part I

    NASA Astrophysics Data System (ADS)

    Shinnaka, Shinji; Sano, Kousuke

    This paper presents a new unified analysis of estimate errors by model-matching phase-estimation methods such as rotor-flux state-observers, back EMF state-observers, and back EMF disturbance-observers, for sensorless drive of permanent-magnet synchronous motors. Analytical solutions about estimate errors, whose validity is confirmed by numerical experiments, are rich in universality and applicability. As an example of universality and applicability, a new trajectory-oriented vector control method is proposed, which can realize directly quasi-optimal strategy minimizing total losses with no additional computational loads by simply orienting one of vector-control coordinates to the associated quasi-optimal trajectory. The coordinate orientation rule, which is analytically derived, is surprisingly simple. Consequently the trajectory-oriented vector control method can be applied to a number of conventional vector control systems using one of the model-matching phase-estimation methods.

  1. Bottom-up assessment of the Net Ecosystem Carbon Balance of Russian forests in 2010 for comparison to Top-down estimates.

    NASA Astrophysics Data System (ADS)

    Maksyutov, S. S.; Shvidenko, A.; Shchepashchenko, D.

    2014-12-01

    The verified full carbon assessment of Russian forests (FCA) is based on an Integrated Land Information System (ILIS) that includes a multi-layer and multi-scale GIS with basic resolution of 1 km and corresponding attributive databases. The ILIS aggregates all available information about ecosystems and landscapes, sets of empirical and semi-empirical data and aggregations, data of different inventories and surveys, and multi-sensor remote sensing data. The ILIS serves as an information base for application of the landscape-ecosystem approach (LEA) of the FCA and as a systems design for comparison and mutual constraints with other methods of study of carbon cycling of forest ecosystems (eddy covariance; process models; inverse modeling; and multi-sensor application of remote sensing). The LEA is based on a complimentary use of the flux-based method with some elements of the pool-based method. Introduction of climatic parameters of individual years in the LEA, as well as some process-based elements, allows providing a substantial decrease of the uncertainties of carbon cycling yearly indicators of forest ecosystems. Major carbon pools (live biomass, coarse woody debris, soil organic carbon) are estimated based on data on areas, distribution and major biometric characteristics of Russian forests presented in form of the ILIS for the country. The major fluxes accounted for include Net Primary Production (NPP), Soil Heterotrophic Respiration (SHR), as well as fluxes caused by decomposition of Coarse Woody Debris (CWD), harvest and use of forest products, fluxes caused by natural disturbances (fire, insect outbreaks, impacts of unfavorable environment) and lateral fluxes to hydrosphere and lithosphere. Use of landscape-ecosystem approach resulted in the NECB at 573±140 Tg C yr-1 (CI 0.9). While the total carbon sink is high, large forest areas, particularly on permafrost, serve as a carbon source. The ratio between net primary production and soil heterotrophic respiration, together with natural and human-induced disturbances are major drivers of the magnitude and spatial distribution of the NECB of forest ecosystems. We also present comparison to the recent top-down estimates of the Siberian carbon sink.

  2. Sparse Reconstruction of Electric Fields from Radial Magnetic Data

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yeates, Anthony R.

    2017-02-10

    Accurate estimates of the horizontal electric field on the Sun’s visible surface are important not only for estimating the Poynting flux of magnetic energy into the corona but also for driving time-dependent magnetohydrodynamic models of the corona. In this paper, a method is developed for estimating the horizontal electric field from a sequence of radial-component magnetic field maps. This problem of inverting Faraday’s law has no unique solution. Unfortunately, the simplest solution (a divergence-free electric field) is not realistically localized in regions of nonzero magnetic field, as would be expected from Ohm’s law. Our new method generates instead a localizedmore » solution, using a basis pursuit algorithm to find a sparse solution for the electric field. The method is shown to perform well on test cases where the input magnetic maps are flux balanced in both Cartesian and spherical geometries. However, we show that if the input maps have a significant imbalance of flux—usually arising from data assimilation—then it is not possible to find a localized, realistic, electric field solution. This is the main obstacle to driving coronal models from time sequences of solar surface magnetic maps.« less

  3. Estimating spatially distributed turbulent heat fluxes from high-resolution thermal imagery acquired with a UAV system

    PubMed Central

    Brenner, Claire; Thiem, Christina Elisabeth; Wizemann, Hans-Dieter; Bernhardt, Matthias; Schulz, Karsten

    2017-01-01

    ABSTRACT In this study, high-resolution thermal imagery acquired with a small unmanned aerial vehicle (UAV) is used to map evapotranspiration (ET) at a grassland site in Luxembourg. The land surface temperature (LST) information from the thermal imagery is the key input to a one-source and two-source energy balance model. While the one-source model treats the surface as a single uniform layer, the two-source model partitions the surface temperature and fluxes into soil and vegetation components. It thus explicitly accounts for the different contributions of both components to surface temperature as well as turbulent flux exchange with the atmosphere. Contrary to the two-source model, the one-source model requires an empirical adjustment parameter in order to account for the effect of the two components. Turbulent heat flux estimates of both modelling approaches are compared to eddy covariance (EC) measurements using the high-resolution input imagery UAVs provide. In this comparison, the effect of different methods for energy balance closure of the EC data on the agreement between modelled and measured fluxes is also analysed. Additionally, the sensitivity of the one-source model to the derivation of the empirical adjustment parameter is tested. Due to the very dry and hot conditions during the experiment, pronounced thermal patterns developed over the grassland site. These patterns result in spatially variable turbulent heat fluxes. The model comparison indicates that both models are able to derive ET estimates that compare well with EC measurements under these conditions. However, the two-source model, with a more complex treatment of the energy and surface temperature partitioning between the soil and vegetation, outperformed the simpler one-source model in estimating sensible and latent heat fluxes. This is consistent with findings from prior studies. For the one-source model, a time-variant expression of the adjustment parameter (to account for the difference between aerodynamic and radiometric temperature) that depends on the surface-to-air temperature gradient yielded the best agreement with EC measurements. This study showed that the applied UAV system equipped with a dual-camera set-up allows for the acquisition of thermal imagery with high spatial and temporal resolution that illustrates the small-scale heterogeneity of thermal surface properties. The UAV-based thermal imagery therefore provides the means for analysing patterns of LST and other surface properties with a high level of detail that cannot be obtained by traditional remote sensing methods. PMID:28515537

  4. Estimating spatially distributed turbulent heat fluxes from high-resolution thermal imagery acquired with a UAV system.

    PubMed

    Brenner, Claire; Thiem, Christina Elisabeth; Wizemann, Hans-Dieter; Bernhardt, Matthias; Schulz, Karsten

    2017-05-19

    In this study, high-resolution thermal imagery acquired with a small unmanned aerial vehicle (UAV) is used to map evapotranspiration (ET) at a grassland site in Luxembourg. The land surface temperature (LST) information from the thermal imagery is the key input to a one-source and two-source energy balance model. While the one-source model treats the surface as a single uniform layer, the two-source model partitions the surface temperature and fluxes into soil and vegetation components. It thus explicitly accounts for the different contributions of both components to surface temperature as well as turbulent flux exchange with the atmosphere. Contrary to the two-source model, the one-source model requires an empirical adjustment parameter in order to account for the effect of the two components. Turbulent heat flux estimates of both modelling approaches are compared to eddy covariance (EC) measurements using the high-resolution input imagery UAVs provide. In this comparison, the effect of different methods for energy balance closure of the EC data on the agreement between modelled and measured fluxes is also analysed. Additionally, the sensitivity of the one-source model to the derivation of the empirical adjustment parameter is tested. Due to the very dry and hot conditions during the experiment, pronounced thermal patterns developed over the grassland site. These patterns result in spatially variable turbulent heat fluxes. The model comparison indicates that both models are able to derive ET estimates that compare well with EC measurements under these conditions. However, the two-source model, with a more complex treatment of the energy and surface temperature partitioning between the soil and vegetation, outperformed the simpler one-source model in estimating sensible and latent heat fluxes. This is consistent with findings from prior studies. For the one-source model, a time-variant expression of the adjustment parameter (to account for the difference between aerodynamic and radiometric temperature) that depends on the surface-to-air temperature gradient yielded the best agreement with EC measurements. This study showed that the applied UAV system equipped with a dual-camera set-up allows for the acquisition of thermal imagery with high spatial and temporal resolution that illustrates the small-scale heterogeneity of thermal surface properties. The UAV-based thermal imagery therefore provides the means for analysing patterns of LST and other surface properties with a high level of detail that cannot be obtained by traditional remote sensing methods.

  5. The Ability of Atmospheric Data to Reduce Disagreements in Wetland Methane Flux Estimates over North America

    NASA Astrophysics Data System (ADS)

    Miller, S. M.; Andrews, A. E.; Benmergui, J. S.; Commane, R.; Dlugokencky, E. J.; Janssens-Maenhout, G.; Melton, J. R.; Michalak, A. M.; Sweeney, C.; Worthy, D. E. J.

    2015-12-01

    Existing estimates of methane fluxes from wetlands differ in both magnitude and distribution across North America. We discuss seven different bottom-up methane estimates in the context of atmospheric methane data collected across the US and Canada. In the first component of this study, we explore whether the observation network can even detect a methane pattern from wetlands. We find that the observation network can identify a methane pattern from Canadian wetlands but not reliably from US wetlands. Over Canada, the network can even identify spatial patterns at multi-provence scales. Over the US, by contrast, anthropogenic emissions and modeling errors obscure atmospheric patterns from wetland fluxes. In the second component of the study, we then use these observations to reconcile disagreements in the magnitude, seasonal cycle, and spatial distribution of existing estimates. Most existing estimates predict fluxes that are too large with a seasonal cycle that is too narrow. A model known as LPJ-Bern has a spatial distribution most consistent with atmospheric observations. By contrast, a spatially-constant model outperforms the distribution of most existing flux estimates across Canada. The results presented here provide several pathways to reduce disagreements among existing wetland flux estimates across North America.

  6. Techniques for measuring intercepted and absorbed PAR in corn canopies

    NASA Technical Reports Server (NTRS)

    Gallo, K. P.; Daughtry, C. S. T.

    1984-01-01

    The quantity of radiation potentially available for photosynthesis that is captured by the crop is best described as absorbed photosynthetically active radiation (PAR). Absorbed PAR (APAR) is the difference between descending and ascending fluxes. The four components of APAR were measured above and within two planting densities of corn (Zea mays L.) and several methods of measuring and estimating APAR were examined. A line quantum sensor that spatially averages the photosynthetic photon flux density provided a rapid and portable method of measuring APAR. PAR reflectance from the soil (Typic Argiaquoll) surface decreased from 10% to less than 1% of the incoming PAR as the canopy cover increased. PAR reflectance from the canopy decreased to less than 3% at maximum vegetative cover. Intercepted PAR (1 - transmitted PAR) generally overestimated absorbed PAR by less than 4% throughout most of the growing season. Thus intercepted PAR appears to be a reasonable estimate of absorbed PAR.

  7. Maize and prairie root contributions to soil CO2 emissions in the field

    USDA-ARS?s Scientific Manuscript database

    Background and aims: A major hurdle in closing carbon budgets is partitioning soil-surface CO2 fluxes by source. This study aims to estimate CO2 resulting from root growth (RG) in the field. Methods: We used periodic 48-hour shading over two seasons to estimate and compare RG-derived CO2 in one annu...

  8. Current forest and woodland carbon storage and flux in California: An estimate for the 2010 statewide assessment

    Treesearch

    Timothy A. Robards

    2012-01-01

    This study used USDA Forest Service Forest Inventory and Analysis (FIA) plot data, forest growth models, wildland fire emission estimates and timber harvest data to estimate the live tree carbon storage and flux of California's forests and woodlands. Approximately 30 Tg C02e per year was estimated as the annual flux for all California forests. The forest inventory...

  9. Long-term measurement of terpenoid flux above a Larix kaempferi forest using a relaxed eddy accumulation method

    NASA Astrophysics Data System (ADS)

    Mochizuki, Tomoki; Tani, Akira; Takahashi, Yoshiyuki; Saigusa, Nobuko; Ueyama, Masahito

    2014-02-01

    Terpenoids emitted from forests contribute to the formation of secondary organic aerosols and affect the carbon budgets of forest ecosystems. To investigate seasonal variation in terpenoid flux involved in the aerosol formation and carbon budget, we measured the terpenoid flux of a Larix kaempferi forest between May 2011 and May 2012 by using a relaxed eddy accumulation method. Isoprene was emitted from a fern plant species Dryopteris crassirhizoma on the forest floor and monoterpenes from the L. kaempferi. α-Pinene was the dominant compound, but seasonal variation of the monoterpene composition was observed. High isoprene and monoterpene fluxes were observed in July and August. The total monoterpene flux was dependent on temperature, but several unusual high positive fluxes were observed after rain fall events. We found a good correlation between total monoterpene flux and volumetric soil water content (r = 0.88), and used this correlation to estimate monoterpene flux after rain events and calculate annual terpenoid emissions. Annual carbon emission in the form of total monoterpenes plus isoprene was determined to be 0.93% of the net ecosystem exchange. If we do not consider the effect of rain fall, carbon emissions may be underestimated by about 50%. Our results suggest that moisture conditions in the forest soil is a key factor controlling the monoterpene emissions from the forest ecosystem.

  10. Estimation of total discharged mass from the phreatic eruption of Ontake Volcano, central Japan, on September 27, 2014

    NASA Astrophysics Data System (ADS)

    Takarada, Shinji; Oikawa, Teruki; Furukawa, Ryuta; Hoshizumi, Hideo; Itoh, Jun'ichi; Geshi, Nobuo; Miyagi, Isoji

    2016-08-01

    The total mass discharged by the phreatic eruption of Ontake Volcano, central Japan, on September 27, 2014, was estimated using several methods. The estimated discharged mass was 1.2 × 106 t (segment integration method), 8.9 × 105 t (Pyle's exponential method), and varied from 8.6 × 103 to 2.5 × 106 t (Hayakawa's single isopach method). The segment integration and Pyle's exponential methods gave similar values. The single isopach method, however, gave a wide range of results depending on which contour was used. Therefore, the total discharged mass of the 2014 eruption is estimated at between 8.9 × 105 and 1.2 × 106 t. More than 90 % of the total mass accumulated within the proximal area. This shows how important it is to include a proximal area field survey for the total mass estimation of phreatic eruptions. A detailed isopleth mass distribution map was prepared covering as far as 85 km from the source. The main ash-fall dispersal was ENE in the proximal and medial areas and E in the distal area. The secondary distribution lobes also extended to the S and NW proximally, reflecting the effects of elutriation ash and surge deposits from pyroclastic density currents during the phreatic eruption. The total discharged mass of the 1979 phreatic eruption was also calculated for comparison. The resulting volume of 1.9 × 106 t (using the segment integration method) indicates that it was about 1.6-2.1 times larger than the 2014 eruption. The estimated average discharged mass flux rate of the 2014 eruption was 1.7 × 108 kg/h and for the 1979 eruption was 1.0 × 108 kg/h. One of the possible reasons for the higher flux rate of the 2014 eruption is the occurrence of pyroclastic density currents at the summit area.

  11. Land Ice Freshwater Budget of the Arctic and North Atlantic Oceans: 1. Data, Methods, and Results

    NASA Astrophysics Data System (ADS)

    Bamber, J. L.; Tedstone, A. J.; King, M. D.; Howat, I. M.; Enderlin, E. M.; van den Broeke, M. R.; Noel, B.

    2018-03-01

    The freshwater budget of the Arctic and sub-polar North Atlantic Oceans has been changing due, primarily, to increased river runoff, declining sea ice and enhanced melting of Arctic land ice. Since the mid-1990s this latter component has experienced a pronounced increase. We use a combination of satellite observations of glacier flow speed and regional climate modeling to reconstruct the land ice freshwater flux from the Greenland ice sheet and Arctic glaciers and ice caps for the period 1958-2016. The cumulative freshwater flux anomaly exceeded 6,300 ± 316 km3 by 2016. This is roughly twice the estimate of a previous analysis that did not include glaciers and ice caps outside of Greenland and which extended only to 2010. From 2010 onward, the total freshwater flux is about 1,300 km3/yr, equivalent to 0.04 Sv, which is roughly 40% of the estimated total runoff to the Arctic for the same time period. Not all of this flux will reach areas of deep convection or Arctic and Sub-Arctic seas. We note, however, that the largest freshwater flux anomalies, grouped by ocean basin, are located in Baffin Bay and Davis Strait. The land ice freshwater flux displays a strong seasonal cycle with summer time values typically around five times larger than the annual mean. This will be important for understanding the impact of these fluxes on fjord circulation, stratification, and the biogeochemistry of, and nutrient delivery to, coastal waters.

  12. Estimating regional greenhouse gas fluxes: An uncertainty analysis of planetary boundary layer techniques and bottom-up inventories

    USDA-ARS?s Scientific Manuscript database

    Quantification of regional greenhouse gas (GHG) fluxes is essential for establishing mitigation strategies and evaluating their effectiveness. Here, we used multiple top-down approaches and multiple trace gas observations at a tall tower to estimate GHG regional fluxes and evaluate the GHG fluxes de...

  13. Estimated damage from the Cascadia Subduction Zone tsunami: A model comparisons using fragility curves

    NASA Astrophysics Data System (ADS)

    Wiebe, D. M.; Cox, D. T.; Chen, Y.; Weber, B. A.; Chen, Y.

    2012-12-01

    Building damage from a hypothetical Cascadia Subduction Zone tsunami was estimated using two methods and applied at the community scale. The first method applies proposed guidelines for a new ASCE 7 standard to calculate the flow depth, flow velocity, and momentum flux from a known runup limit and estimate of the total tsunami energy at the shoreline. This procedure is based on a potential energy budget, uses the energy grade line, and accounts for frictional losses. The second method utilized numerical model results from previous studies to determine maximum flow depth, velocity, and momentum flux throughout the inundation zone. The towns of Seaside and Canon Beach, Oregon, were selected for analysis due to the availability of existing data from previously published works. Fragility curves, based on the hydrodynamic features of the tsunami flow (inundation depth, flow velocity, and momentum flux) and proposed design standards from ASCE 7 were used to estimate the probability of damage to structures located within the inundations zone. The analysis proceeded at the parcel level, using tax-lot data to identify construction type (wood, steel, and reinforced-concrete) and age, which was used as a performance measure when applying the fragility curves and design standards. The overall probability of damage to civil buildings was integrated for comparison between the two methods, and also analyzed spatially for damage patterns, which could be controlled by local bathymetric features. The two methods were compared to assess the sensitivity of the results to the uncertainty in the input hydrodynamic conditions and fragility curves, and the potential advantages of each method discussed. On-going work includes coupling the results of building damage and vulnerability to an economic input output model. This model assesses trade between business sectors located inside and outside the induction zone, and is used to measure the impact to the regional economy. Results highlight critical businesses sectors and infrastructure critical to the economic recovery effort, which could be retrofitted or relocated to survive the event. The results of this study improve community understanding of the tsunami hazard for civil buildings.

  14. Relevance of methodological choices for accounting of land use change carbon fluxes

    NASA Astrophysics Data System (ADS)

    Pongratz, Julia; Hansis, Eberhard; Davis, Steven

    2015-04-01

    To understand and potentially steer how humans shape land-climate interactions it is important to accurately attribute greenhouse gas fluxes from land use and land cover change (LULCC) in space and time. However, such accounting of carbon fluxes from LULCC generally requires choosing from multiple options of how to attribute the fluxes to regions and to LULCC activities. Applying a newly-developed and spatially-explicit bookkeeping model, BLUE ("bookkeeping of land use emissions"), we quantify LULCC carbon fluxes and attribute them to land-use activities and countries by a range of different accounting methods. We present results with respect to a Kyoto Protocol-like ``commitment'' accounting period, using land use emissions of 2008-12 as example scenario. We assess the effect of accounting methods that vary (1) the temporal evolution of carbon stocks, (2) the state of the carbon stocks at the beginning of the period, (3) the temporal attribution of carbon fluxes during the period, and (4) treatment of LULCC fluxes that occurred prior to the beginning of the period. We show that the methodological choices result in grossly different estimates of carbon fluxes for the different attribution definitions. The global net flux in the accounting period varies between 4.3 Pg(C) uptake and 15.2 Pg(C) emissions, depending on the accounting method. Regional results show different modes of variation. This finding has implications for both political and scientific considerations: Not all methodological choices are currently specified under the UNFCCC treaties on land use, land-use change and forestry. Yet, a consistent accounting scheme is crucial to assure comparability of individual LULCC activities, quantify their relevance for the global annual carbon budget, and assess the effects of LULCC policies.

  15. Towards physiologically meaningful water-use efficiency estimates from eddy covariance data.

    PubMed

    Knauer, Jürgen; Zaehle, Sönke; Medlyn, Belinda E; Reichstein, Markus; Williams, Christopher A; Migliavacca, Mirco; De Kauwe, Martin G; Werner, Christiane; Keitel, Claudia; Kolari, Pasi; Limousin, Jean-Marc; Linderson, Maj-Lena

    2018-02-01

    Intrinsic water-use efficiency (iWUE) characterizes the physiological control on the simultaneous exchange of water and carbon dioxide in terrestrial ecosystems. Knowledge of iWUE is commonly gained from leaf-level gas exchange measurements, which are inevitably restricted in their spatial and temporal coverage. Flux measurements based on the eddy covariance (EC) technique can overcome these limitations, as they provide continuous and long-term records of carbon and water fluxes at the ecosystem scale. However, vegetation gas exchange parameters derived from EC data are subject to scale-dependent and method-specific uncertainties that compromise their ecophysiological interpretation as well as their comparability among ecosystems and across spatial scales. Here, we use estimates of canopy conductance and gross primary productivity (GPP) derived from EC data to calculate a measure of iWUE (G 1 , "stomatal slope") at the ecosystem level at six sites comprising tropical, Mediterranean, temperate, and boreal forests. We assess the following six mechanisms potentially causing discrepancies between leaf and ecosystem-level estimates of G 1 : (i) non-transpirational water fluxes; (ii) aerodynamic conductance; (iii) meteorological deviations between measurement height and canopy surface; (iv) energy balance non-closure; (v) uncertainties in net ecosystem exchange partitioning; and (vi) physiological within-canopy gradients. Our results demonstrate that an unclosed energy balance caused the largest uncertainties, in particular if it was associated with erroneous latent heat flux estimates. The effect of aerodynamic conductance on G 1 was sufficiently captured with a simple representation. G 1 was found to be less sensitive to meteorological deviations between canopy surface and measurement height and, given that data are appropriately filtered, to non-transpirational water fluxes. Uncertainties in the derived GPP and physiological within-canopy gradients and their implications for parameter estimates at leaf and ecosystem level are discussed. Our results highlight the importance of adequately considering the sources of uncertainty outlined here when EC-derived water-use efficiency is interpreted in an ecophysiological context. © 2017 John Wiley & Sons Ltd.

  16. A global carbon assimilation system based on a dual optimization method

    NASA Astrophysics Data System (ADS)

    Zheng, H.; Li, Y.; Chen, J. M.; Wang, T.; Huang, Q.; Huang, W. X.; Li, S. M.; Yuan, W. P.; Zheng, X.; Zhang, S. P.; Chen, Z. Q.; Jiang, F.

    2014-10-01

    Ecological models are effective tools to simulate the distribution of global carbon sources and sinks. However, these models often suffer from substantial biases due to inaccurate simulations of complex ecological processes. We introduce a set of scaling factors (parameters) to an ecological model on the basis of plant functional type (PFT) and latitudes. A global carbon assimilation system (GCAS-DOM) is developed by employing a Dual Optimization Method (DOM) to invert the time-dependent ecological model parameter state and the net carbon flux state simultaneously. We use GCAS-DOM to estimate the global distribution of the CO2 flux on 1° ×1° grid cells for the period from 2000 to 2007. Results show that land and ocean absorb -3.69 ± 0.49 Pg C year-1 and -1.91 ± 0.16 Pg C year-1, respectively. North America, Europe and China contribut -0.96 ± 0.15 Pg C year-1, -0.42 ± 0.08 Pg C year-1 and -0.21 ± 0.28 Pg C year-1, respectively. The uncertainties in the flux after optimization by GCAS-DOM have been remarkably reduced by more than 60%. Through parameter optimization, GCAS-DOM can provide improved estimates of the carbon flux for each PFT. Coniferous forest (-0.97 ± 0.27 Pg C year-1) is the largest contributor to the global carbon sink. Fluxes of once-dominant deciduous forest generated by BEPS is reduced to -0.79 ± 0.22 Pg C year-1, being the third largest carbon sink.

  17. Indirect rotor position sensing in real time for brushless permanent magnet motor drives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ertugrul, N.; Acarnley, P.P.

    1998-07-01

    This paper describes a modern solution to real-time rotor position estimation of brushless permanent magnet (PM) motor drives. The position estimation scheme, based on flux linkage and line-current estimation, is implemented in real time by using the abc reference frame, and it is tested dynamically. The position estimation model of the test motor, development of hardware, and basic operation of the digital signal processor (DSP) are discussed. The overall position estimation strategy is accomplished with a fast DSP (TMS320C30). The method is a shaft position sensorless method that is applicable to a wide range of excitation types in brushless PMmore » motors without any restriction on the motor model and the current excitation. Both rectangular and sinewave-excited brushless PM motor drives are examined, and the results are given to demonstrate the effectiveness of the method with dynamic loads in closed estimated position loop.« less

  18. Aspects of spatial and temporal aggregation in estimating regional carbon dioxide fluxes from temperate forest soils

    NASA Technical Reports Server (NTRS)

    Kicklighter, David W.; Melillo, Jerry M.; Peterjohn, William T.; Rastetter, Edward B.; Mcguire, A. David; Steudler, Paul A.; Aber, John D.

    1994-01-01

    We examine the influence of aggregation errors on developing estimates of regional soil-CO2 flux from temperate forests. We find daily soil-CO2 fluxes to be more sensitive to changes in soil temperatures (Q(sub 10) = 3.08) than air temperatures (Q(sub 10) = 1.99). The direct use of mean monthly air temperatures with a daily flux model underestimates regional fluxes by approximately 4%. Temporal aggregation error varies with spatial resolution. Overall, our calibrated modeling approach reduces spatial aggregation error by 9.3% and temporal aggregation error by 15.5%. After minimizing spatial and temporal aggregation errors, mature temperate forest soils are estimated to contribute 12.9 Pg C/yr to the atmosphere as carbon dioxide. Georeferenced model estimates agree well with annual soil-CO2 fluxes measured during chamber studies in mature temperate forest stands around the globe.

  19. A New Expanded Mixed Element Method for Convection-Dominated Sobolev Equation

    PubMed Central

    Wang, Jinfeng; Li, Hong; Fang, Zhichao

    2014-01-01

    We propose and analyze a new expanded mixed element method, whose gradient belongs to the simple square integrable space instead of the classical H(div; Ω) space of Chen's expanded mixed element method. We study the new expanded mixed element method for convection-dominated Sobolev equation, prove the existence and uniqueness for finite element solution, and introduce a new expanded mixed projection. We derive the optimal a priori error estimates in L 2-norm for the scalar unknown u and a priori error estimates in (L 2)2-norm for its gradient λ and its flux σ. Moreover, we obtain the optimal a priori error estimates in H 1-norm for the scalar unknown u. Finally, we obtained some numerical results to illustrate efficiency of the new method. PMID:24701153

  20. Measurements of CO2 exchange with an automated chamber system throughout the year: challenges in measuring night-time respiration on porous peat soil

    NASA Astrophysics Data System (ADS)

    Koskinen, M.; Minkkinen, K.; Ojanen, P.; Kämäräinen, M.; Laurila, T.; Lohila, A.

    2014-01-01

    We built an automatic chamber system to measure greenhouse gas (GHG) exchange in forested peatland ecosystems. We aimed to build a system robust enough which would work throughout the year and could measure through a changing snowpack in addition to producing annual GHG fluxes by integrating the measurements without the need of using models. The system worked rather well throughout the year, but it was not service free. Gap filling of data was still necessary. We observed problems in carbon dioxide (CO2) respiration flux estimation during calm summer nights, when a CO2 concentration gradient from soil/moss system to atmosphere builds up. Chambers greatly overestimated the night-time respiration. This was due to the disturbance caused by the chamber to the soil-moss CO2 gradient and consequent initial pulse of CO2 to the chamber headspace. We tested different flux calculation and measurement methods to solve this problem. The estimated flux was strongly dependent on (1) the starting point of the fit after closing the chamber, (2) the length of the fit, (3) the type of the fit (linear and polynomial), (4) the speed of the fan mixing the air inside the chamber, and (5) atmospheric turbulence (friction velocity, u*). The best fitting method (the most robust, least random variation) for respiration measurements on our sites was linear fitting with the period of 120-240 s after chamber closure. Furthermore, the fan should be adjusted to spin at minimum speed to avoid the pulse-effect, but it should be kept on to ensure mixing. If night-time problems cannot be solved, emissions can be estimated using daytime data from opaque chambers.

  1. Estimates of CO2 fluxes over the city of Cape Town, South Africa, through Bayesian inverse modelling

    NASA Astrophysics Data System (ADS)

    Nickless, Alecia; Rayner, Peter J.; Engelbrecht, Francois; Brunke, Ernst-Günther; Erni, Birgit; Scholes, Robert J.

    2018-04-01

    We present a city-scale inversion over Cape Town, South Africa. Measurement sites for atmospheric CO2 concentrations were installed at Robben Island and Hangklip lighthouses, located downwind and upwind of the metropolis. Prior estimates of the fossil fuel fluxes were obtained from a bespoke inventory analysis where emissions were spatially and temporally disaggregated and uncertainty estimates determined by means of error propagation techniques. Net ecosystem exchange (NEE) fluxes from biogenic processes were obtained from the land atmosphere exchange model CABLE (Community Atmosphere Biosphere Land Exchange). Uncertainty estimates were based on the estimates of net primary productivity. CABLE was dynamically coupled to the regional climate model CCAM (Conformal Cubic Atmospheric Model), which provided the climate inputs required to drive the Lagrangian particle dispersion model. The Bayesian inversion framework included a control vector where fossil fuel and NEE fluxes were solved for separately.Due to the large prior uncertainty prescribed to the NEE fluxes, the current inversion framework was unable to adequately distinguish between the fossil fuel and NEE fluxes, but the inversion was able to obtain improved estimates of the total fluxes within pixels and across the domain. The median of the uncertainty reductions of the total weekly flux estimates for the inversion domain of Cape Town was 28 %, but reach as high as 50 %. At the pixel level, uncertainty reductions of the total weekly flux reached up to 98 %, but these large uncertainty reductions were for NEE-dominated pixels. Improved corrections to the fossil fuel fluxes would be possible if the uncertainty around the prior NEE fluxes could be reduced. In order for this inversion framework to be operationalised for monitoring, reporting, and verification (MRV) of emissions from Cape Town, the NEE component of the CO2 budget needs to be better understood. Additional measurements of Δ14C and δ13C isotope measurements would be a beneficial component of an atmospheric monitoring programme aimed at MRV of CO2 for any city which has significant biogenic influence, allowing improved separation of contributions from NEE and fossil fuel fluxes to the observed CO2 concentration.

  2. Assessing the Importance of Prior Biospheric Fluxes on Inverse Model Estimates of CO2

    NASA Astrophysics Data System (ADS)

    Philip, S.; Johnson, M. S.; Potter, C. S.; Genovese, V. B.

    2017-12-01

    Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emissions and biospheric sources/sinks. The processes controlling terrestrial biosphere-atmosphere carbon exchange are currently not fully understood, resulting in models having significant differences in the quantification of biospheric CO2 fluxes. Currently, atmospheric chemical transport models (CTM) and global climate models (GCM) use multiple different biospheric CO2 flux models resulting in large differences in simulating the global carbon cycle. The Orbiting Carbon Observatory 2 (OCO-2) satellite mission was designed to allow for the improved understanding of the processes involved in the exchange of carbon between terrestrial ecosystems and the atmosphere, and therefore allowing for more accurate assessment of the seasonal/inter-annual variability of CO2. OCO-2 provides much-needed CO2 observations in data-limited regions allowing for the evaluation of model simulations of greenhouse gases (GHG) and facilitating global/regional estimates of "top-down" CO2 fluxes. We conduct a 4-D Variation (4D-Var) data assimilation with the GEOS-Chem (Goddard Earth Observation System-Chemistry) CTM using 1) OCO-2 land nadir and land glint retrievals and 2) global in situ surface flask observations to constrain biospheric CO2 fluxes. We apply different state-of-the-science year-specific CO2 flux models (e.g., NASA-CASA (NASA-Carnegie Ames Stanford Approach), CASA-GFED (Global Fire Emissions Database), Simple Biosphere Model version 4 (SiB-4), and LPJ (Lund-Postdam-Jena)) to assess the impact of "a priori" flux predictions to "a posteriori" estimates. We will present the "top-down" CO2 flux estimates for the year 2015 using OCO-2 and in situ observations, and a complete indirect evaluation of the a priori and a posteriori flux estimates using independent in situ observations. We will also present our assessment of the variability of "top-down" CO2 flux estimates when using different biospheric CO2 flux models. This work will improve our understanding of the global carbon cycle, specifically, how OCO-2 observations can be used to constrain biospheric CO2 flux model estimates.

  3. A novel adaptive control method for induction motor based on Backstepping approach using dSpace DS 1104 control board

    NASA Astrophysics Data System (ADS)

    Ben Regaya, Chiheb; Farhani, Fethi; Zaafouri, Abderrahmen; Chaari, Abdelkader

    2018-02-01

    This paper presents a new adaptive Backstepping technique to handle the induction motor (IM) rotor resistance tracking problem. The proposed solution leads to improve the robustness of the control system. Given the presence of static error when estimating the rotor resistance with classical methods, and the sensitivity to the load torque variation at low speed, a new Backstepping observer enhanced with an integral action of the tracking errors is presented, which can be established in two steps. The first one consists to estimate the rotor flux using a Backstepping observer. The second step, defines the adaptation mechanism of the rotor resistance based on the estimated rotor-flux. The asymptotic stability of the observer is proven by Lyapunov theory. To validate the proposed solution, a simulation and experimental benchmarking of a 3 kW induction motor are presented and analyzed. The obtained results show the effectiveness of the proposed solution compared to the model reference adaptive system (MRAS) rotor resistance observer presented in other recent works.

  4. Influence of Sky Conditions on Estimation of Photosynthetic Photon Flux Density for Agricultural Ecosystem

    NASA Astrophysics Data System (ADS)

    Yamashita, M.; Yoshimura, M.

    2018-04-01

    Photosynthetic photon flux density (PPFD: µmol m-2 s-1) is indispensable for plant physiology processes in photosynthesis. However, PPFD is seldom measured, so that PPFD has been estimated by using solar radiation (SR: W m-2) measured in world wide. In method using SR, there are two steps: first to estimate photosynthetically active radiation (PAR: W m-2) by the fraction of PAR to SR (PF) and second: to convert PAR to PPFD using the ratio of quanta to energy (Q / E: µmol J-1). PF and Q/E usually have been used as the constant values, however, recent studies point out that PF and Q / E would not be constants under various sky conditions. In this study, we use the numeric data of sky-conditions factors such cloud cover, sun appearance/hiding and relative sky brightness derived from whole-sky image processing and examine the influences of sky-conditions factors on PF and Q / E of global and diffuse PAR. Furthermore, we discuss our results by comparing with the existing methods.

  5. Tritium Plume Dynamics in the Shallow Unsaturated Zone Adjacent to an Arid Waste Disposal Facility

    NASA Astrophysics Data System (ADS)

    Maples, S.; Andraski, B. J.; Stonestrom, D. A.; Cooper, C. A.; Michel, R. L.; Pohll, G. M.

    2012-12-01

    Previous studies at the U.S. Geological Survey's Amargosa Desert Research Site (ADRS) in southern Nevada have documented two plumes of tritiated water-vapor (3HHOg) adjacent to a closed, commercial low-level radioactive waste disposal facility. Wastes were disposed on-site from 1962-92. Tritium has moved long distances (> 400 m) through a shallow (1-2-m depth) dry gravelly layer—orders of magnitude further than anticipated by standard transport models. Geostatistical methods, spatial moment analyses and tritium flux calculations were applied to assess shallow plume dynamics. A grid-based plant-water sampling method was utilized to infer detailed, field-scale 3HHOg concentrations at 5-yr intervals during 2001-11. Results indicate that gravel-layer 3HHOg mass diminished faster than would be expected from radioactive decay (~70% in 10 yr). Both plumes exhibited center-of-mass stability, suggesting that bulk-plume movement is minimal during the period of study. Nonetheless, evidence of localized lateral advancement along some margins, combined with increases in the spatial covariance of concentration distribution, indicates intra-plume mass redistribution is ongoing. Previous studies have recognized that vertical movement of tritiated water from sub-root-zone gravel into the root-zone contributes to atmospheric release via evapotranspiration. Estimates of lateral and vertical tritium fluxes during the study period indicate (1) vertical tritiated water fluxes were dominated by diffusive-vapor fluxes (> 90%), and (2) vertical diffusive-vapor fluxes were roughly an order of magnitude greater than lateral diffusive-vapor fluxes. This behavior highlights the importance of the atmosphere as a tritium sink. Estimates of cumulative vertical diffusive-vapor flux and radioactive decay with time were comparable to observed declines in total shallow plume mass with time. This suggests observed changes in plume mass may (1) be attributed, in considerable part, to these removal mechanisms, and (2) appreciable input from the adjacent disposal facility is not occurring at this time.

  6. Sensitivity of Global Methane Bayesian Inversion to Surface Observation Data Sets and Chemical-Transport Model Resolution

    NASA Astrophysics Data System (ADS)

    Lew, E. J.; Butenhoff, C. L.; Karmakar, S.; Rice, A. L.; Khalil, A. K.

    2017-12-01

    Methane is the second most important greenhouse gas after carbon dioxide. In efforts to control emissions, a careful examination of the methane budget and source strengths is required. To determine methane surface fluxes, Bayesian methods are often used to provide top-down constraints. Inverse modeling derives unknown fluxes using observed methane concentrations, a chemical transport model (CTM) and prior information. The Bayesian inversion reduces prior flux uncertainties by exploiting information content in the data. While the Bayesian formalism produces internal error estimates of source fluxes, systematic or external errors that arise from user choices in the inversion scheme are often much larger. Here we examine model sensitivity and uncertainty of our inversion under different observation data sets and CTM grid resolution. We compare posterior surface fluxes using the data product GLOBALVIEW-CH4 against the event-level molar mixing ratio data available from NOAA. GLOBALVIEW-CH4 is a collection of CH4 concentration estimates from 221 sites, collected by 12 laboratories, that have been interpolated and extracted to provide weekly records from 1984-2008. Differently, the event-level NOAA data records methane mixing ratios field measurements from 102 sites, containing sampling frequency irregularities and gaps in time. Furthermore, the sampling platform types used by the data sets may influence the posterior flux estimates, namely fixed surface, tower, ship and aircraft sites. To explore the sensitivity of the posterior surface fluxes to the observation network geometry, inversions composed of all sites, only aircraft, only ship, only tower and only fixed surface sites, are performed and compared. Also, we investigate the sensitivity of the error reduction associated with the resolution of the GEOS-Chem simulation (4°×5° vs 2°×2.5°) used to calculate the response matrix. Using a higher resolution grid decreased the model-data error at most sites, thereby increasing the information at that site. These different inversions—event-level and interpolated data, higher and lower resolutions—are compared using an ensemble of descriptive and comparative statistics. Analyzing the sensitivity of the inverse model leads to more accurate estimates of the methane source category uncertainty.

  7. Uncertainty in predictions of forest carbon dynamics: separating driver error from model error.

    PubMed

    Spadavecchia, L; Williams, M; Law, B E

    2011-07-01

    We present an analysis of the relative magnitude and contribution of parameter and driver uncertainty to the confidence intervals on estimates of net carbon fluxes. Model parameters may be difficult or impractical to measure, while driver fields are rarely complete, with data gaps due to sensor failure and sparse observational networks. Parameters are generally derived through some optimization method, while driver fields may be interpolated from available data sources. For this study, we used data from a young ponderosa pine stand at Metolius, Central Oregon, and a simple daily model of coupled carbon and water fluxes (DALEC). An ensemble of acceptable parameterizations was generated using an ensemble Kalman filter and eddy covariance measurements of net C exchange. Geostatistical simulations generated an ensemble of meteorological driving variables for the site, consistent with the spatiotemporal autocorrelations inherent in the observational data from 13 local weather stations. Simulated meteorological data were propagated through the model to derive the uncertainty on the CO2 flux resultant from driver uncertainty typical of spatially extensive modeling studies. Furthermore, the model uncertainty was partitioned between temperature and precipitation. With at least one meteorological station within 25 km of the study site, driver uncertainty was relatively small ( 10% of the total net flux), while parameterization uncertainty was larger, 50% of the total net flux. The largest source of driver uncertainty was due to temperature (8% of the total flux). The combined effect of parameter and driver uncertainty was 57% of the total net flux. However, when the nearest meteorological station was > 100 km from the study site, uncertainty in net ecosystem exchange (NEE) predictions introduced by meteorological drivers increased by 88%. Precipitation estimates were a larger source of bias in NEE estimates than were temperature estimates, although the biases partly compensated for each other. The time scales on which precipitation errors occurred in the simulations were shorter than the temporal scales over which drought developed in the model, so drought events were reasonably simulated. The approach outlined here provides a means to assess the uncertainty and bias introduced by meteorological drivers in regional-scale ecological forecasting.

  8. Towards Improved High-Resolution Land Surface Hydrologic Reanalysis Using a Physically-Based Hydrologic Model and Data Assimilation

    NASA Astrophysics Data System (ADS)

    Shi, Y.; Davis, K. J.; Zhang, F.; Duffy, C.; Yu, X.

    2014-12-01

    A coupled physically based land surface hydrologic model, Flux-PIHM, has been developed by incorporating a land surface scheme into the Penn State Integrated Hydrologic Model (PIHM). The land surface scheme is adapted from the Noah land surface model. Flux-PIHM has been implemented and manually calibrated at the Shale Hills watershed (0.08 km2) in central Pennsylvania. Model predictions of discharge, point soil moisture, point water table depth, sensible and latent heat fluxes, and soil temperature show good agreement with observations. When calibrated only using discharge, and soil moisture and water table depth at one point, Flux-PIHM is able to resolve the observed 101 m scale soil moisture pattern at the Shale Hills watershed when an appropriate map of soil hydraulic properties is provided. A Flux-PIHM data assimilation system has been developed by incorporating EnKF for model parameter and state estimation. Both synthetic and real data assimilation experiments have been performed at the Shale Hills watershed. Synthetic experiment results show that the data assimilation system is able to simultaneously provide accurate estimates of multiple parameters. In the real data experiment, the EnKF estimated parameters and manually calibrated parameters yield similar model performances, but the EnKF method significantly decreases the time and labor required for calibration. The data requirements for accurate Flux-PIHM parameter estimation via data assimilation using synthetic observations have been tested. Results show that by assimilating only in situ outlet discharge, soil water content at one point, and the land surface temperature averaged over the whole watershed, the data assimilation system can provide an accurate representation of watershed hydrology. Observations of these key variables are available with national and even global spatial coverage (e.g., MODIS surface temperature, SMAP soil moisture, and the USGS gauging stations). National atmospheric reanalysis products, soil databases and land cover databases (e.g., NLDAS-2, SSURGO, NLCD) can provide high resolution forcing and input data. Therefore the Flux-PIHM data assimilation system could be readily expanded to other watersheds to provide regional scale land surface and hydrologic reanalysis with high spatial temporal resolution.

  9. Assessment of land surface temperature and heat fluxes over Delhi using remote sensing data.

    PubMed

    Chakraborty, Surya Deb; Kant, Yogesh; Mitra, Debashis

    2015-01-15

    Surface energy processes has an essential role in urban weather, climate and hydrosphere cycles, as well in urban heat redistribution. The research was undertaken to analyze the potential of Landsat and MODIS data in retrieving biophysical parameters in estimating land surface temperature & heat fluxes diurnally in summer and winter seasons of years 2000 and 2010 and understanding its effect on anthropogenic heat disturbance over Delhi and surrounding region. Results show that during years 2000-2010, settlement and industrial area increased from 5.66 to 11.74% and 4.92 to 11.87% respectively which in turn has direct effect on land surface temperature (LST) and heat fluxes including anthropogenic heat flux. Based on the energy balance model for land surface, a method to estimate the increase in anthropogenic heat flux (Has) has been proposed. The settlement and industrial areas has higher amounts of energy consumed and has high values of Has in all seasons. The comparison of satellite derived LST with that of field measured values show that Landsat estimated values are in close agreement within error of ±2 °C than MODIS with an error of ±3 °C. It was observed that, during 2000 and 2010, the average change in surface temperature using Landsat over settlement & industrial areas of both seasons is 1.4 °C & for MODIS data is 3.7 °C. The seasonal average change in anthropogenic heat flux (Has) estimated using Landsat & MODIS is up by around 38 W/m(2) and 62 W/m(2) respectively while higher change is observed over settlement and concrete structures. The study reveals that the dynamic range of Has values has increased in the 10 year period due to the strong anthropogenic influence over the area. The study showed that anthropogenic heat flux is an indicator of the strength of urban heat island effect, and can be used to quantify the magnitude of the urban heat island effect. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. A test of the ADV-based Reynolds flux method for in situ estimation of sediment settling velocity in a muddy estuary

    NASA Astrophysics Data System (ADS)

    Cartwright, Grace M.; Friedrichs, Carl T.; Smith, S. Jarrell

    2013-12-01

    Under conditions common in muddy coastal and estuarine environments, acoustic Doppler velocimeters (ADVs) can serve to estimate sediment settling velocity ( w s) by assuming a balance between upward turbulent Reynolds flux and downward gravitational settling. Advantages of this method include simple instrument deployment, lack of flow disturbance, and relative insensitivity to biofouling and water column stratification. Although this method is being used with increasing frequency in coastal and estuarine environments, to date it has received little direct ground truthing. This study compared in situ estimates of w s inferred by a 5-MHz ADV to independent in situ observations from a high-definition video settling column over the course of a flood tide in the bottom boundary layer of the York River estuary, Virginia, USA. The ADV-based measurements were found to agree with those of the settling column when the current speed at about 40 cm above the bed was greater than about 20 cm/s. This corresponded to periods when the estimated magnitude of the settling term in the suspended sediment continuity equation was four or more times larger than the time rate of change of concentration. For ADV observations restricted to these conditions, ADV-based estimates of w s (mean 0.48±0.04 mm/s) were highly consistent with those observed by the settling column (mean 0.45±0.02 mm/s). However, the ADV-based method for estimating w s was sensitive to the prescribed concentration of the non-settling washload, C wash. In an objective operational definition, C wash can be set equal to the lowest suspended solids concentration observed around slack water.

  11. A Preliminary Study of CO2 Flux Measurements by Lidar

    NASA Technical Reports Server (NTRS)

    Gibert, Fabien; Koch, Grady J.; Beyon, Jeffrey Y.; Hilton, T.; Davis, Kenneth J.; Andrews, Arlyn; Ismail, Syed; Singh, Upendra N.

    2008-01-01

    A mechanistic understanding of the global carbon cycle requires quantification of terrestrial ecosystem CO2 fluxes at regional scales. In this paper, we analyze the potential of a Doppler DIAL system to make flux measurements of atmospheric CO2 using the eddy-covariance and boundary layer budget methods and present results from a ground based experiment. The goal of this study is to put CO2 flux point measurements in a mesoscale context. In June 2007, a field experiment combining a 2-m Doppler Heterodyne Differential Absorption Lidar (HDIAL) and in-situ sensors of a 447-m tall tower (WLEF) took place in Wisconsin. The HDIAL measures simultaneously: 1) CO2 mixing ratio, 2) atmosphere structure via aerosol backscatter and 3) radial velocity. We demonstrate how to synthesize these data into regional flux estimates. Lidar-inferred fluxes are compared with eddy-covariance fluxes obtained in-situ at 396m AGL from the tower. In cases where the lidar was not yet able to measure the fluxes with acceptable precision, we discuss possible modifications to improve system performance.

  12. Simulation study of geometric shape factor approach to estimating earth emitted flux densities from wide field-of-view radiation measurements

    NASA Technical Reports Server (NTRS)

    Weaver, W. L.; Green, R. N.

    1980-01-01

    A study was performed on the use of geometric shape factors to estimate earth-emitted flux densities from radiation measurements with wide field-of-view flat-plate radiometers on satellites. Sets of simulated irradiance measurements were computed for unrestricted and restricted field-of-view detectors. In these simulations, the earth radiation field was modeled using data from Nimbus 2 and 3. Geometric shape factors were derived and applied to these data to estimate flux densities on global and zonal scales. For measurements at a satellite altitude of 600 km, estimates of zonal flux density were in error 1.0 to 1.2%, and global flux density errors were less than 0.2%. Estimates with unrestricted field-of-view detectors were about the same for Lambertian and non-Lambertian radiation models, but were affected by satellite altitude. The opposite was found for the restricted field-of-view detectors.

  13. Estimation of maximum transdermal flux of nonionized xenobiotics from basic physicochemical determinants

    PubMed Central

    Milewski, Mikolaj; Stinchcomb, Audra L.

    2012-01-01

    An ability to estimate the maximum flux of a xenobiotic across skin is desirable both from the perspective of drug delivery and toxicology. While there is an abundance of mathematical models describing the estimation of drug permeability coefficients, there are relatively few that focus on the maximum flux. This article reports and evaluates a simple and easy-to-use predictive model for the estimation of maximum transdermal flux of xenobiotics based on three common molecular descriptors: logarithm of octanol-water partition coefficient, molecular weight and melting point. The use of all three can be justified on the theoretical basis of their influence on the solute aqueous solubility and the partitioning into the stratum corneum lipid domain. The model explains 81% of the variability in the permeation dataset comprised of 208 entries and can be used to obtain a quick estimate of maximum transdermal flux when experimental data is not readily available. PMID:22702370

  14. Beyond Hammers and Nails: Mitigating and Verifying Greenhouse Gas Emissions

    NASA Astrophysics Data System (ADS)

    Gurney, Kevin Robert

    2013-05-01

    One of the biggest challenges to future international agreements on climate change is an independent, science-driven method of verifying reductions in greenhouse gas emissions (GHG) [Niederberger and Kimble, 2011]. The scientific community has thus far emphasized atmospheric measurements to assess changes in emissions. An alternative is direct measurement or estimation of fluxes at the source. Given the many challenges facing the approach that uses "top-down" atmospheric measurements and recent advances in "bottom-up" estimation methods, I challenge the current doctrine, which has the atmospheric measurement approach "validating" bottom-up, "good-faith" emissions estimation [Balter, 2012] or which holds that the use of bottom-up estimation is like "dieting without weighing oneself" [Nisbet and Weiss, 2010].

  15. Recent global methane trends: an investigation using hierarchical Bayesian methods

    NASA Astrophysics Data System (ADS)

    Rigby, M. L.; Stavert, A.; Ganesan, A.; Lunt, M. F.

    2014-12-01

    Following a decade with little growth, methane concentrations began to increase across the globe in 2007, and have continued to rise ever since. The reasons for this renewed growth are currently the subject of much debate. Here, we discuss the recent observed trends, and highlight some of the strengths and weaknesses in current "inverse" methods for quantifying fluxes using observations. In particular, we focus on the outstanding problems of accurately quantifying uncertainties in inverse frameworks. We examine to what extent the recent methane changes can be explained by the current generation of flux models and inventories. We examine the major modes of variability in wetland models along with the Global Fire Emissions Database (GFED) and the Emissions Database for Global Atmospheric Research (EDGAR). Using the Model for Ozone and Related Tracers (MOZART), we determine whether the spatial and temporal atmospheric trends predicted using these emissions can be brought into consistency with in situ atmospheric observations. We use a novel hierarchical Bayesian methodology in which scaling factors applied to the principal components of the flux fields are estimated simultaneously with the uncertainties associated with the a priori fluxes and with model representations of the observations. Using this method, we examine the predictive power of methane flux models for explaining recent fluctuations.

  16. Global Flux Balance in the Terrestrial H2O Cycle: Reconsidering the Post-Arc Subducted H2O Flux

    NASA Astrophysics Data System (ADS)

    Parai, R.; Mukhopadhyay, S.

    2010-12-01

    Quantitative estimates of H2O fluxes between the mantle and the exosphere (i.e., the atmosphere, oceans and crust) are critical to our understanding of the chemistry and dynamics of the solid Earth: the abundance and distribution of water in the mantle has dramatic impacts upon mantle melting, degassing history, structure and style of convection. Water is outgassed from the mantle is association with volcanism at mid-ocean ridges, ocean islands and convergent margins. H2O is removed from the exosphere at subduction zones, and some fraction of the subducted flux may be recycled past the arc into the Earth’s deep interior. Estimates of the post-arc subducted H2O flux are primarily based on the stability of hydrous phases at subduction zone pressures and temperatures (e.g. Schmidt and Poli, 1998; Rüpke et al., 2004; Hacker, 2008). However, the post-arc H2O flux remains poorly quantified, in part due to large uncertainties in the water content of the subducting slab. Here we evaluate estimated post-arc subducted fluxes in the context of mantle-exosphere water cycling, using a Monte Carlo simulation of the global H2O cycle. Literature estimates of primary magmatic H2O abundances and magmatic production rates at different tectonic settings are used with estimates of the total subducted H2O flux to establish the parameter space under consideration. Random sampling of the allowed parameter space affords insight into which input and output fluxes satisfy basic constraints on global flux balance, such as a limit on sea-level change over time. The net flux of H2O between mantle and exosphere is determined by the total mantle output flux (via ridges and ocean islands, with a small contribution from mantle-derived arc output) and the input flux subducted beyond the arc. Arc and back-arc output is derived mainly from the slab, and therefore cancels out a fraction of the trench intake in an H2O subcycle. Limits on sea-level change since the end of the Archaean place constraints on the magnitude of the post-arc subducted H2O flux that can be accommodated by the global water cycle. Estimates of the post-arc subducted flux are up to an order of magnitude larger than the estimated mantle output flux. If the marked imbalance in the estimated global water cycle is accurate, then it must be a recent phenomenon: if propagated back in time, modeled net inward fluxes would consume half a present-day ocean volume of water in as little as 500 Myr (corresponding to ~1200 meters of sea level change given present-day hypsometry). Such changes are inconsistent with the limited sea level changed inferred from the geologic record since the end of the Archaean. The literature post-arc flux estimates reflect water carried to depth via a layer of serpentinized lithospheric mantle within the slab; however, the extent to which oceanic lithosphere may be serpentinized remains poorly constrained. A smaller post-arc subducted H2O flux of 2.3 x108 Tg/Ma would perfectly balance our mean modeled total mantle output. Such a post-arc flux corresponds to ~2% serpentinization of a 10 km thick layer of lithospheric mantle (i.e., a mean water content of ~0.25 wt% H2O).

  17. Comparison of methods to determine methane emissions from dairy cows in farm conditions.

    PubMed

    Huhtanen, P; Cabezas-Garcia, E H; Utsumi, S; Zimmerman, S

    2015-05-01

    Nutritional and animal-selection strategies to mitigate enteric methane (CH4) depend on accurate, cost-effective methods to determine emissions from a large number of animals. The objective of the present study was to compare 2 spot-sampling methods to determine CH4 emissions from dairy cows, using gas quantification equipment installed in concentrate feeders or automatic milking stalls. In the first method (sniffer method), CH4 and carbon dioxide (CO2) concentrations were measured in close proximity to the muzzle of the animal, and average CH4 concentrations or CH4/CO2 ratio was calculated. In the second method (flux method), measurement of CH4 and CO2 concentration was combined with an active airflow inside the feed troughs for capture of emitted gas and measurements of CH4 and CO2 fluxes. A muzzle sensor was used allowing data to be filtered when the muzzle was not near the sampling inlet. In a laboratory study, a model cow head was built that emitted CO2 at a constant rate. It was found that CO2 concentrations using the sniffer method decreased up to 39% when the distance of the muzzle from the sampling inlet increased to 30cm, but no muzzle-position effects were observed for the flux method. The methods were compared in 2 on-farm studies conducted using 32 (experiment 1) or 59 (experiment 2) cows in a switch-back design of 5 (experiment 1) or 4 (experiment 2) periods for replicated comparisons between methods. Between-cow coefficient of variation (CV) in CH4 was smaller for the flux than the sniffer method (experiment 1, CV=11.0 vs. 17.5%, and experiment 2, 17.6 vs. 28.0%). Repeatability of the measurements from both methods were high (0.72-0.88), but the relationship between the sniffer and flux methods was weak (R(2)=0.09 in both experiments). With the flux method CH4 was found to be correlated to dry matter intake or body weight, but this was not the case with the sniffer method. The CH4/CO2 ratio was more highly correlated between the flux and sniffer methods (R(2)=0.30), and CV was similar (6.4-8.8%). In experiment 2, cow muzzle position was highly repeatable (0.82) and influenced sniffer and flux method results when not filtered for muzzle position. It was concluded that the flux method provides more reliable estimates of CH4 emissions than the sniffer method. The sniffer method appears to be affected by variable air-mixing conditions created by geometry of feed trough, muzzle movement, and muzzle position. Copyright © 2015 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

  18. Flux control coefficients determined by inhibitor titration: the design and analysis of experiments to minimize errors.

    PubMed Central

    Small, J R

    1993-01-01

    This paper is a study into the effects of experimental error on the estimated values of flux control coefficients obtained using specific inhibitors. Two possible techniques for analysing the experimental data are compared: a simple extrapolation method (the so-called graph method) and a non-linear function fitting method. For these techniques, the sources of systematic errors are identified and the effects of systematic and random errors are quantified, using both statistical analysis and numerical computation. It is shown that the graph method is very sensitive to random errors and, under all conditions studied, that the fitting method, even under conditions where the assumptions underlying the fitted function do not hold, outperformed the graph method. Possible ways of designing experiments to minimize the effects of experimental errors are analysed and discussed. PMID:8257434

  19. Environmental controls of daytime leaf carbon exchange: Implications for estimates of ecosystem fluxes in a deciduous forest

    NASA Astrophysics Data System (ADS)

    Heskel, M.; Tang, J.

    2017-12-01

    Leaf-level photosynthesis and respiration are sensitive to short- and long-term changed in temperature, and how these processes respond to phenological and seasonal transitions and daily temperature variation dictate how carbon is first assimilated and released in terrestrial ecosystems. We examined the short-term temperature response of daytime leaf carbon exchange at Harvard Forest across growing season, with the specific objective to quantify the light inhibition of dark respiration and photorespiration in leaves and use this to better inform daytime carbon assimilation and efflux estimates at the canopy scale. Dark and light respiration increased with measurement temperature and varied seasonally in a proportional manner, with the level of inhibition remaining relatively constant through the growing season. Higher rates of mitochondrial respiration and photorespiration at warmer temperatures drove a lower carbon use efficiency. Using temperature, light, and canopy leaf area index values to drive models, we estimate partitioned ecosystem fluxes and re-calculate gross primary production under multiple scenarios that include and exclude the impact of light inhibition, thermal acclimation, and seasonal variation in physiology. Quantifying the contribution of these `small fluxes' to ecosystem carbon exchange in forests provides a nuanced approach for integrating physiology into regional model estimates derived from eddy covariance and remote-sensing methods.

  20. Modeling the Relative Importance of Nutrient and Carbon Loads, Boundary Fluxes, and Sediment Fluxes on Gulf of Mexico Hypoxia.

    PubMed

    Feist, Timothy J; Pauer, James J; Melendez, Wilson; Lehrter, John C; DePetro, Phillip A; Rygwelski, Kenneth R; Ko, Dong S; Kreis, Russell G

    2016-08-16

    The Louisiana continental shelf in the northern Gulf of Mexico experiences bottom water hypoxia in the summer. In this study, we applied a biogeochemical model that simulates dissolved oxygen concentrations on the shelf in response to varying riverine nutrient and organic carbon loads, boundary fluxes, and sediment fluxes. Five-year model simulations demonstrated that midsummer hypoxic areas were most sensitive to riverine nutrient loads and sediment oxygen demand from settled organic carbon. Hypoxic area predictions were also sensitive to nutrient and organic carbon fluxes from lateral boundaries. The predicted hypoxic area decreased with decreases in nutrient loads, but the extent of change was influenced by the method used to estimate model boundary concentrations. We demonstrated that modeling efforts to predict changes in hypoxic area on the continental shelf in relationship to changes in nutrients should include representative boundary nutrient and organic carbon concentrations and functions for estimating sediment oxygen demand that are linked to settled organic carbon derived from water-column primary production. On the basis of our model analyses using the most representative boundary concentrations, nutrient loads would need to be reduced by 69% to achieve the Gulf of Mexico Nutrient Task Force Action Plan target hypoxic area of 5000 km(2).

  1. Geostationary Enhanced Temporal Interpolation for CERES Flux Products

    NASA Technical Reports Server (NTRS)

    Doelling, David R.; Loeb, Norman G.; Keyes, Dennis F.; Nordeen, Michele L.; Morstad, Daniel; Nguyen, Cathy; Wielicki, Bruce A.; Young, David F.; Sun, Moguo

    2013-01-01

    The Clouds and the Earth's Radiant Energy System (CERES) instruments on board the Terra and Aqua spacecraft continue to provide an unprecedented global climate record of the earth's top-of-atmosphere (TOA) energy budget since March 2000. A critical step in determining accurate daily averaged flux involves estimating the flux between CERES Terra or Aqua overpass times. CERES employs the CERES-only (CO) and the CERES geostationary (CG) temporal interpolation methods. The CO method assumes that the cloud properties at the time of the CERES observation remain constant and that it only accounts for changes in albedo with solar zenith angle and diurnal land heating, by assuming a shape for unresolved changes in the diurnal cycle. The CG method enhances the CERES data by explicitly accounting for changes in cloud and radiation between CERES observation times using 3-hourly imager data from five geostationary (GEO) satellites. To maintain calibration traceability, GEO radiances are calibrated against Moderate Resolution Imaging Spectroradiometer (MODIS) and the derived GEO fluxes are normalized to the CERES measurements. While the regional (1 deg latitude x 1 deg longitude) monthly-mean difference between the CG and CO methods can exceed 25 W m(sub -2) over marine stratus and land convection, these regional biases nearly cancel in the global mean. The regional monthly CG shortwave (SW) and longwave (LW) flux uncertainty is reduced by 20%, whereas the daily uncertainty is reduced by 50% and 20%, respectively, over the CO method, based on comparisons with 15-min Geostationary Earth Radiation Budget (GERB) data.

  2. A new method to determine magnetic properties of the unsaturated-magnetized rotor of a novel gyro

    NASA Astrophysics Data System (ADS)

    Li, Hai; Liu, Xiaowei; Dong, Changchun; Zhang, Haifeng

    2016-06-01

    A new method is proposed to determine magnetic properties of the unsaturated-magnetized, small and irregular shaped rotor of a novel gyro. The method is based on finite-element analysis and the measurements of the magnetic flux density distribution, determining magnetic parameters by comparing the magnetic flux intensity distribution differences between the modeling results under different parameters and the measured ones. Experiment on a N30 Grade NdFeB magnet shows that its residual magnetic flux density is 1.10±0.01 T, and coercive field strength is 801±3 kA/m, which are consistent with the given parameters of the material. The method was applied to determine the magnetic properties of the rotor of the gyro, and the magnetic properties acquired were used to predict the open-loop gyro precession frequency. The predicted precession frequency should be larger than 12.9 Hz, which is close to the experimental result 13.5 Hz. The result proves that the method is accurate in estimating the magnetic properties of the rotor of the gyro.

  3. Estimating discharge of shallow groundwater by transpiration from greasewood in the Northern Great Basin

    USGS Publications Warehouse

    Nichols, William D.

    1993-01-01

    Evapotranspiration from bare soil and phreatophytes is a principal mechanism of groundwater discharge in arid and semiarid regions of the midwestern and western United States including the Great Basin. The imbalance between independent estimates of groundwater recharge from precipitation and of groundwater discharge based on estimates of groundwater evapotranspiration leads to large uncertainties in groundwater budgets. Few studies have addressed this problem. Energy budget micrometeorological field studies were conducted in a stand of sparse-canopy greasewood growing in an area of shallow groundwater in the western Great Basin during the summer of 1989. The data were used to calculate above-canopy fluxes of sensible and latent heat using the energy budget-Bowen ratio method. The calculated energy budget fluxes were used, with soil surface and plant canopy temperature measurements, to calibrate and apply a two-component, energy-combination model that partitions the energy and heat fluxes between bare soil and the canopy. This permitted the separation of evaporation from the soil and transpiration from greasewood. The calibrated model was used to estimate daily transpiration of groundwater by greasewood growing in an area with a depth to water of about 2 m. The daily rate of groundwater discharge by transpiration during July and August was estimated to be 2.4 mm. A period of 100 days for groundwater discharge at this rate was assumed to estimate an annual discharge of groundwater of 24 cm at the study site.

  4. Investigation of chamber methods and a micrometeorological mass balance method for quantifying greenhouse gas emissions from animal manure

    NASA Astrophysics Data System (ADS)

    Park, Kyu-Hyun

    Various measurement methods to quantify greenhouse gas (GHG) emissions from manure storage or treatment facilities have been used. However, it is difficult to directly compare emission data measured with different methods, which causes uncertainties in national GHG inventories. In the micrometeorological mass balance (MMB) method, a gas flux consists of a horizontal mean flux (MF) and horizontal turbulent flux (TF) terms. In Chapter 2, methane (GH4 ) TF measurements obtained using a sonic anemometer and a tunable diode laser trace gas analyzer are presented. Contrary to previous studies in wind tunnels and flat-level field conditions, an overestimation of only 0.5% was observed by only considering the MF term. This means the MMB method without consideration of TF is suitable in complex field conditions with uneven topography, and farm buildings. In Chapter 3, the MMB method was compared to a floating chamber method. Of these, the floating chamber method has been extensively used for CH4 flux quantification. The MMB method, although providing advantages such as spatial integration of fluxes, requires fast response trace gas analyzers which are not widely available. The mean ratio of CH4 flux measured with the floating chamber method to that measured using the MMB method was 1.25, ranging from 1.07 to 1.83. Flux overestimation by the floating chamber could have been caused by location of the chamber and potential disturbances by the chamber. Frequent changes of the chamber location, use of several chambers, and/or avoiding chamber placement on 'hot spots' are recommended to decrease flux overestimation. In Chapter 4, CH4 fluxes measured with a mega chamber and eight small chambers during the in-vessel composting phase showed similar temporal variation, while nitrous oxide (N2O) fluxes were, significantly lower for the small chambers. The ratios of CH4 fluxes measured with a mega chamber to eight small chambers during the in-vessel composting phase were 0.72 and 1.01, while the ratios of N2O fluxes were 2.74 and 2.01 during two in-vessel composting batches, respectively. Positioning the small chambers on the center line of the composting channels was suitable for quantifying CH4 fluxes, but was not for N 2O. It is recommended to position some chambers in peripheral regions of the composting channel, in order to capture N2O emissions. Methane and N2O fluxes over the initial 50 d of the curing phase were higher than during the in-vessel composting phase. Methane and N2O emissions during the curing phase contributed 95% and 64%, respectively, to overall CH4 and N2O emissions during the composting process (in-vessel composting phase and curing phase). In comparison to liquid swine manure storage over an equivalent time period, composting was estimated to reduce emissions of GHG on a carbon dioxide equivalent (CO2-eq) basis by 35%, which was mainly contributed by a decrease of CH4 emissions. Composting of liquid swine manure with straw has potential for decreasing GHG emissions.

  5. Spacebased Observation of Water Balance Over Global Oceans

    NASA Astrophysics Data System (ADS)

    Liu, W.; Xie, X.

    2008-12-01

    We demonstrated that ocean surface fresh water flux less the water discharge into the ocean from river and ice melt balances the mass loss in the ocean both in magnitude and in the phase of annual variation. The surface water flux was computed from the divergence of the water transport integrated over the depth of the atmosphere. The atmospheric water transport is estimated from the precipitable water measured by Special Sensor Microwave Imager, the surface wind vector by QuikSCAT, and the NOAA cloud drift wind through a statistical model. The transport has been extensively validated using global radiosonde and data and operational numerical weather prediction results. Its divergence has been shown to agree with the difference between evaporation estimated from the Advanced Microwave Scanning Radiometer data and the precipitation measured by Tropical Rain Measuring Mission over the global tropical and subtropical oceans both in magnitude and geographical distribution for temporal scales ranging from intraseasonal to interannual. The water loss rate in the ocean is estimated by two methods, one is from Gravity Recovery and Climate Experiment and the other is by subtracting the climatological steric change from the sea level change measured by radar altimeter on Jason. Only climatological river discharge and ice melt from in situ measurements are available and the lack of temporal variation may contribute to discrepancies in the balance. We have successfully used the spacebased surface fluxes to estimate to climatological mean heat transport in the Atlantic ocean and is attempting to estimate the meridional fresh water (or salt) transport from the surface flux. The approximate closure of the water balance gives a powerful indirect validation of the spacebased products.

  6. Estimating Total Heliospheric Magnetic Flux from Single-Point in Situ Measurements

    NASA Technical Reports Server (NTRS)

    Owens, M. J.; Arge, C. N.; Crooker, N. U.; Schwardron, N. A.; Horbury, T. S.

    2008-01-01

    A fraction of the total photospheric magnetic flux opens to the heliosphere to form the interplanetary magnetic field carried by the solar wind. While this open flux is critical to our understanding of the generation and evolution of the solar magnetic field, direct measurements are generally limited to single-point measurements taken in situ by heliospheric spacecraft. An observed latitude invariance in the radial component of the magnetic field suggests that extrapolation from such single-point measurements to total heliospheric magnetic flux is possible. In this study we test this assumption using estimates of total heliospheric flux from well-separated heliospheric spacecraft and conclude that single-point measurements are indeed adequate proxies for the total heliospheric magnetic flux, though care must be taken when comparing flux estimates from data collected at different heliocentric distances.

  7. Gradient flux measurements of sea-air DMS transfer during the Surface Ocean Aerosol Production (SOAP) experiment

    NASA Astrophysics Data System (ADS)

    Smith, Murray J.; Walker, Carolyn F.; Bell, Thomas G.; Harvey, Mike J.; Saltzman, Eric S.; Law, Cliff S.

    2018-04-01

    Direct measurements of marine dimethylsulfide (DMS) fluxes are sparse, particularly in the Southern Ocean. The Surface Ocean Aerosol Production (SOAP) voyage in February-March 2012 examined the distribution and flux of DMS in a biologically active frontal system in the southwest Pacific Ocean. Three distinct phytoplankton blooms were studied with oceanic DMS concentrations as high as 25 nmol L-1. Measurements of DMS fluxes were made using two independent methods: the eddy covariance (EC) technique using atmospheric pressure chemical ionization-mass spectrometry (API-CIMS) and the gradient flux (GF) technique from an autonomous catamaran platform. Catamaran flux measurements are relatively unaffected by airflow distortion and are made close to the water surface, where gas gradients are largest. Flux measurements were complemented by near-surface hydrographic measurements to elucidate physical factors influencing DMS emission. Individual DMS fluxes derived by EC showed significant scatter and, at times, consistent departures from the Coupled Ocean-Atmosphere Response Experiment gas transfer algorithm (COAREG). A direct comparison between the two flux methods was carried out to separate instrumental effects from environmental effects and showed good agreement with a regression slope of 0.96 (r2 = 0.89). A period of abnormal downward atmospheric heat flux enhanced near-surface ocean stratification and reduced turbulent exchange, during which GF and EC transfer velocities showed good agreement but modelled COAREG values were significantly higher. The transfer velocity derived from near-surface ocean turbulence measurements on a spar buoy compared well with the COAREG model in general but showed less variation. This first direct comparison between EC and GF fluxes of DMS provides confidence in compilation of flux estimates from both techniques, as well as in the stable periods when the observations are not well predicted by the COAREG model.

  8. Recovery strategies for fluxes affected by the Gill-Solent WindMaster-Pro "w-boost" firmware bug

    NASA Astrophysics Data System (ADS)

    Billesbach, D. P.; Chan, S. W.; Biraud, S.; David, C. R.

    2017-12-01

    In late 2015 and early 2016, work done by the AmeriFlux Tech Team helped to uncover a bug in the Gill WindMaster Pro sonic anemometers used by many researchers for eddy covariance flux measurements. Gill has addressed this issue and has since sent out a notice that the vertical wind speed component (a critical piece of all eddy covariance fluxes) was being erroneously computed and reported. The problem (known as the w-boost bug) resulted in positive (upward) wind speeds being under-reported by 16.6% and negative (downward) wind speeds being under-reported by 28.9%. This has the potential to cause similar underestimates in fluxes obtained from these instruments. While the manufacturer has offered a firmware upgrade to fix this bug, there exist many data sets that have already been affected by it. Researchers who use the affected units have contributed to numerous data archives (AmeriFlux, FluxNet, ICOS, etc.), and third-party scientists have, in turn used these data in many types of research projects. The volume of affected data over such a long period of time makes a complete reprocessing of the raw data sets impractical. To address this, the AmeriFlux Tech Team has endeavored to develop a method of correcting affected fluxes using only the downloadable data sets that are available from these archives. In a previous poster, we reported preliminary results from a pair of Arctic tundra flux towers, and showed that fluxes could be underestimated by 15% to 20%. In this poster, we present results that extend our study to include a forested site in Equatorial Africa. We also have evaluated methods to estimate flux errors without accessing the raw data sets.

  9. Nutrient fluxes across sediment-water interface in Bohai Bay Coastal Zone, China.

    PubMed

    Mu, Di; Yuan, Dekui; Feng, Huan; Xing, Fangwei; Teo, Fang Yenn; Li, Shuangzhao

    2017-01-30

    Sediment cores and overlying water samples were collected at four sites in Tianjin Coastal Zone, Bohai Bay, to investigate nutrient (N, P and Si) exchanges across the sediment-water interface. The exchange fluxes of each nutrient species were estimated based on the porewater profiles and laboratory incubation experiments. The results showed significant differences between the two methods, which implied that molecular diffusion alone was not the dominant process controlling nutrient exchanges at these sites. The impacts of redox conditions and bioturbation on the nutrient fluxes were confirmed by the laboratory incubation experiments. The results from this study showed that the nutrient fluxes measured directly from the incubation experiment were more reliable than that predicted from the porewater profiles. The possible impacts causing variations in the nutrient fluxes include sewage discharge and land reclamation. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. On the interpretation of energy and energy fluxes of nonlinear internal waves: An example from Massachusetts Bay

    USGS Publications Warehouse

    Scotti, A.; Beardsley, R.; Butman, B.

    2006-01-01

    A self-consistent formalism to estimate baroclinic energy densities and fluxes resulting from the propagation of internal waves of arbitrary amplitude is derived using the concept of available potential energy. The method can be applied to numerical, laboratory or field data. The total energy flux is shown to be the sum of the linear energy flux ??? u??? p??? dz (primes denote baroclinic quantities), plus contributions from the non-hydrostatic pressure anomaly and the self-advection of kinetic and available potential energy. Using highly resolved observations in Massachusetts Bay, it is shown that due to the presence of nonlinear internal waves periodically propagating in the area, ??? u??? p??? dz accounts for only half of the total flux. The same data show that equipartition of available potential and kinetic energy can be violated, especially when the nonlinear waves begin to interact with the bottom. ?? 2006 Cambridge University Press.

  11. A passive guard for low thermal conductivity measurement of small samples by the hot plate method

    NASA Astrophysics Data System (ADS)

    Jannot, Yves; Degiovanni, Alain; Grigorova-Moutiers, Veneta; Godefroy, Justine

    2017-01-01

    Hot plate methods under steady state conditions are based on a 1D model to estimate the thermal conductivity, using measurements of the temperatures T 0 and T 1 of the two sides of the sample and of the heat flux crossing it. To be consistent with the hypothesis of the 1D heat flux, either a hot plate guarded apparatus is used, or the temperature is measured at the centre of the sample. On one hand the latter method can be used only if the ratio thickness/width of the sample is sufficiently low and on the other hand the guarded hot plate method requires large width samples (typical cross section of 0.6  ×  0.6 m2). That is why both methods cannot be used for low width samples. The method presented in this paper is based on an optimal choice of the temperatures T 0 and T 1 compared to the ambient temperature T a, enabling the estimation of the thermal conductivity with a centered hot plate method, by applying the 1D heat flux model. It will be shown that these optimal values do not depend on the size or on the thermal conductivity of samples (in the range 0.015-0.2 W m-1 K-1), but only on T a. The experimental results obtained validate the method for several reference samples for values of the ratio thickness/width up to 0.3, thus enabling the measurement of the thermal conductivity of samples having a small cross-section, down to 0.045  ×  0.045 m2.

  12. Detecting the position of the moving-iron solenoid by non-displacement sensor based on parameter identification of flux linkage characteristics

    NASA Astrophysics Data System (ADS)

    Wang, Xuping; Quan, Long; Xiong, Guangyu

    2013-11-01

    Currently, most researches use signals, such as the coil current or voltage of solenoid, to identify parameters; typically, parameter identification method based on variation rate of coil current is applied for position estimation. The problem exists in these researches that the detected signals are prone to interference and difficult to obtain. This paper proposes a new method for detecting the core position by using flux characteristic quantity, which adds a new group of secondary winding to the coil of the ordinary switching electromagnet. On the basis of electromagnetic coupling theory analysis and simulation research of the magnetic field regarding the primary and secondary winding coils, and in accordance with the fact that under PWM control mode varying core position and operating current of windings produce different characteristic of flux increment of the secondary winding. The flux increment of the electromagnet winding can be obtained by conducting time domain integration for the induced voltage signal of the extracted secondary winding, and the core position from the two-dimensional fitting curve of the operating winding current and flux-linkage characteristic quantity of solenoid are calculated. The detecting and testing system of solenoid core position is developed based on the theoretical research. The testing results show that the flux characteristic quantity of switching electromagnet magnetic circuit is able to effectively show the core position and thus to accomplish the non-displacement transducer detection of the said core position of the switching electromagnet. This paper proposes a new method for detecting the core position by using flux characteristic quantity, which provides a new theory and method for switch solenoid to control the proportional valve.

  13. 13C metabolic flux analysis: optimal design of isotopic labeling experiments.

    PubMed

    Antoniewicz, Maciek R

    2013-12-01

    Measuring fluxes by 13C metabolic flux analysis (13C-MFA) has become a key activity in chemical and pharmaceutical biotechnology. Optimal design of isotopic labeling experiments is of central importance to 13C-MFA as it determines the precision with which fluxes can be estimated. Traditional methods for selecting isotopic tracers and labeling measurements did not fully utilize the power of 13C-MFA. Recently, new approaches were developed for optimal design of isotopic labeling experiments based on parallel labeling experiments and algorithms for rational selection of tracers. In addition, advanced isotopic labeling measurements were developed based on tandem mass spectrometry. Combined, these approaches can dramatically improve the quality of 13C-MFA results with important applications in metabolic engineering and biotechnology. Copyright © 2013 Elsevier Ltd. All rights reserved.

  14. Radiation environment for ATS-F. [including ambient trapped particle fluxes

    NASA Technical Reports Server (NTRS)

    Stassinopoulos, E. G.

    1974-01-01

    The ambient trapped particle fluxes incident on the ATS-F satellite were determined. Several synchronous circular flight paths were evaluated and the effect of parking longitude on vehicle encountered intensities was investigated. Temporal variations in the electron environment were considered and partially accounted for. Magnetic field calculations were performed with a current field model extrapolated to a later epoch with linear time terms. Orbital flux integrations were performed with the latest proton and electron environment models using new improved computational methods. The results are presented in graphical and tabular form; they are analyzed, explained, and discussed. Estimates of energetic solar proton fluxes are given for a one year mission at selected integral energies ranging from 10 to 100 Mev, calculated for a year of maximum solar activity during the next solar cycle.

  15. Estimating soil labile organic carbon and potential turnover rates using a sequential fumigation–incubation procedure.

    Treesearch

    X.M. Zoua; H.H. Ruanc; Y. Fua; X.D. Yanga; L.Q. Sha

    2005-01-01

    Labile carbon is the fraction of soil organic carbon with most rapid turnover times and its oxidation drives the flux of CO2 between soils and atmosphere. Available chemical and physical fractionation methods for estimating soil labile organic carbon are indirect and lack a clear biological definition. We have modified the well-established Jenkinson and Powlson’s...

  16. Estimating watershed evapotranspiration across the United States using multiple methods

    Treesearch

    Ge Sun; Shanlei Sun; Jingfeng Xiao; Peter Caldwell; Devendra Amatya; Suat Irmak; Prasanna H. Gowda; Sudhanshu Panda; Steve McNulty; Yang Zhang

    2016-01-01

    Evapotranspiration (ET) is the largest watershed water balance component only next to precipitation in the United States. ET is closely coupled with ecosystem carbon and energy fluxes, affects flooding or drought magnitude, and is also a good predictor for biodiversity at a regional scale.Thus, accurately estimating ET is of paramount importance to quantify the effects...

  17. Surface energy balance estimates at local and regional scales using optical remote sensing from an aircraft platform and atmospheric data collected over semiarid rangelands

    USGS Publications Warehouse

    Kustas, William P.; Moran, M.S.; Humes, K.S.; Stannard, D.I.; Pinter, P. J.; Hipps, L.E.; Swiatek, E.; Goodrich, D.C.

    1994-01-01

    Remotely sensed data in the visible, near-infrared, and thermal-infrared wave bands were collected from a low-flying aircraft during the Monsoon '90 field experiment. Monsoon '90 was a multidisciplinary experiment conducted in a semiarid watershed. It had as one of its objectives the quantification of hydrometeorological fluxes during the “monsoon” or wet season. The remote sensing observations along with micrometeprological and atmospheric boundary layer (ABL) data were used to compute the surface energy balance over a range of spatial scales. The procedure involved averaging multiple pixels along transects flown over the meteorological and flux (METFLUX) stations. Average values of the spectral reflectance and thermal-infrared temperatures were computed for pixels of order 10−1 to 101 km in length and were used with atmospheric data for evaluating net radiation (Rn), soil heat flux (G), and sensible (H) and latent (LE) heat fluxes at these same length scales. The model employs a single-layer resistance approach for estimating H that requires wind speed and air temperature in the ABL and a remotely sensed surface temperature. The values of Rn and G are estimated from remote sensing information together with near-surface observations of air temperature, relative humidity, and solar radiation. Finally, LE is solved as the residual term in the surface energy balance equation. Model calculations were compared to measurements from the METFLUX network for three days having different environmental conditions. Average percent differences for the three days between model and the METFLUX estimates of the local fluxes were about 5% for Rn, 20% for Gand H, and 15% for LE. Larger differences occurred during partly cloudy conditions because of errors in interpreting the remote sensing data and the higher spatial and temporal variation in the energy fluxes. Minor variations in modeled energy fluxes were observed when the pixel size representing the remote sensing inputs changed from 0.2 to 2 km. Regional scale estimates of the surface energy balance using bulk ABL properties for the model parameters and input variables and the 10-km pixel data differed from the METFLUX network averages by about 4% for Rn, 10% for G and H, and 15% for LE. Model sensitivity in calculating the turbulent fluxes H and LE to possible variations in key model parameters (i.e., the roughness lengths for heat and momentum) was found to be fairly significant. Therefore the reliability of the methods for estimating key model parameters and potential errors needs further testing over different ecosystems and environmental conditions.

  18. A statistical method for estimating wood thermal diffusivity and probe geometry using in situ heat response curves from sap flow measurements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chen, Xingyuan; Miller, Gretchen R.; Rubin, Yoram

    2012-09-13

    The heat pulse method is widely used to measure water flux through plants; it works by inferring the velocity of water through a porous medium from the speed at which a heat pulse is propagated through the system. No systematic, non-destructive calibration procedure exists to determine the site-specific parameters necessary for calculating sap velocity, e.g., wood thermal diffusivity and probe spacing. Such parameter calibration is crucial to obtain the correct transpiration flux density from the sap flow measurements at the plant scale; and consequently, to up-scale tree-level water fluxes to canopy and landscape scales. The purpose of this study ismore » to present a statistical framework for estimating the wood thermal diffusivity and probe spacing simutaneously from in-situ heat response curves collected by the implanted probes of a heat ratio apparatus. Conditioned on the time traces of wood temperature following a heat pulse, the parameters are inferred using a Bayesian inversion technique, based on the Markov chain Monte Carlo sampling method. The primary advantage of the proposed methodology is that it does not require known probe spacing or any further intrusive sampling of sapwood. The Bayesian framework also enables direct quantification of uncertainty in estimated sap flow velocity. Experiments using synthetic data show that repeated tests using the same apparatus are essential to obtain reliable and accurate solutions. When applied to field conditions, these tests are conducted during different seasons and automated using the existing data logging system. The seasonality of wood thermal diffusivity is obtained as a by-product of the parameter estimation process, and it is shown to be affected by both moisture content and temperature. Empirical factors are often introduced to account for the influence of non-ideal probe geometry on the estimation of heat pulse velocity, and they are estimated in this study as well. The proposed methodology can be applied for the calibration of existing heat ratio sap flow systems at other sites. It is especially useful when an alternative transpiration calibration device, such as a lysimeter, is not available.« less

  19. Surface-layer turbulence, energy balance and links to atmospheric circulations over a mountain glacier in the French Alps

    NASA Astrophysics Data System (ADS)

    Litt, Maxime; Sicart, Jean-Emmanuel; Six, Delphine; Wagnon, Patrick; Helgason, Warren D.

    2017-04-01

    Over Saint-Sorlin Glacier in the French Alps (45° N, 6.1° E; ˜ 3 km2) in summer, we study the atmospheric surface-layer dynamics, turbulent fluxes, their uncertainties and their impact on surface energy balance (SEB) melt estimates. Results are classified with regard to large-scale forcing. We use high-frequency eddy-covariance data and mean air-temperature and wind-speed vertical profiles, collected in 2006 and 2009 in the glacier's atmospheric surface layer. We evaluate the turbulent fluxes with the eddy-covariance (sonic) and the profile method, and random errors and parametric uncertainties are evaluated by including different stability corrections and assuming different values for surface roughness lengths. For weak synoptic forcing, local thermal effects dominate the wind circulation. On the glacier, weak katabatic flows with a wind-speed maximum at low height (2-3 m) are detected 71 % of the time and are generally associated with small turbulent kinetic energy (TKE) and small net turbulent fluxes. Radiative fluxes dominate the SEB. When the large-scale forcing is strong, the wind in the valley aligns with the glacier flow, intense downslope flows are observed, no wind-speed maximum is visible below 5 m, and TKE and net turbulent fluxes are often intense. The net turbulent fluxes contribute significantly to the SEB. The surface-layer turbulence production is probably not at equilibrium with dissipation because of interactions of large-scale orographic disturbances with the flow when the forcing is strong or low-frequency oscillations of the katabatic flow when the forcing is weak. In weak forcing when TKE is low, all turbulent fluxes calculation methods provide similar fluxes. In strong forcing when TKE is large, the choice of roughness lengths impacts strongly the net turbulent fluxes from the profile method fluxes and their uncertainties. However, the uncertainty on the total SEB remains too high with regard to the net observed melt to be able to recommend one turbulent flux calculation method over another.

  20. Atmospheric deposition of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and dioxin-like polychlorinated biphenyls in the Kanto Region, Japan.

    PubMed

    Ogura, I; Masunaga, S; Nakanishi, J

    2001-09-01

    The atmospheric bulk (dry and wet) deposition of dioxins was investigated at four locations (Tokyo, Yokohama, Tsukuba, and Tanzawa) in the Kanto region (in Japan) over one year using a stainless-steel pot. Annual average polychlorinated dibenzo-p-dioxins/polychlorinated dibenzofurans (PCDD/PCDF) deposition fluxes were estimated to be from 450 to 1300 ng/m2/yr, and the annual average TEQ fluxes from 5.7 to 17 ng-TEQ/m2/yr at the four locations. The PCDD/PCDF deposition flux was higher in winter than in summer. The deposition flux could be related to ambient temperature, particularly for less chlorinated PCDDs/PCDFs, while the deposition flux is not necessarily related to the amount of precipitation. The PCDD/PCDF deposition flux increased as the particle deposition flux increased, for the winter samples. Based on the ratio of the PCDD/PCDF deposition fluxes to the particle deposition fluxes, the contribution of the reentrainment of soil particles to the TEQ of PCDD/PCDF deposition was considered to be negligible in this region. Based on the air concentrations monitored near our deposition sampling points by the municipalities, the ratio of the annual deposition flux to the annual average air concentration was roughly estimated to be 0.082 cm/s. The range of deposition flux in the Kanto region was estimated to be from 1.5 to 31 (median: 9.8) ng-TEQ/m2/yr based on the range of air concentration data measured by the municipalities. The total annual deposition flux in the entire Kanto region was estimated to range from 50 to 900 g-TEQ/yr (median 320 g-TEQ/yr). This estimated flux was of the same order as the sum of estimated emissions from municipal solid waste incinerators and industrial waste incinerators in the Kanto region. The contributions of dioxin-like PCBs in Yokohama, Tsukuba, and Tanzawa depositions were less than 10% of the total TEQ; however, in Tokyo it was almost equal to or more than 50%.

  1. Mass, heat and nutrient fluxes in the Atlantic Ocean determined by inverse methods. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Rintoul, Stephen Rich

    1988-01-01

    Inverse methods are applied to historical hydrographic data to address two aspects of the general circulation of the Atlantic Ocean. The method allows conservation statements for mass and other properties, along with a variety of other constraints, to be combined in a dynamically consistent way to estimate the absolute velocity field and associated property transports. The method was first used to examine the exchange of mass and heat between the South Atlantic and the neighboring ocean basins. The second problem addressed concerns the circulation and property fluxes across the 24 and 36 deg N in the subtropical North Atlantic. Conservation statements are considered for the nutrients as well as mass, and the nutrients are found to contribute significant information independent of temperature and salinity.

  2. CYGNSS Surface Wind Observations and Surface Flux Estimates within Low-Latitude Extratropical Cyclones

    NASA Astrophysics Data System (ADS)

    Crespo, J.; Posselt, D. J.

    2017-12-01

    The Cyclone Global Navigation Satellite System (CYGNSS), launched in December 2016, aims to improve estimates of surface wind speeds over the tropical oceans. While CYGNSS's core mission is to provide better estimates of surface winds within the core of tropical cyclones, previous research has shown that the constellation, with its orbital inclination of 35°, also has the ability to observe numerous extratropical cyclones that form in the lower latitudes. Along with its high spatial and temporal resolution, CYGNSS can provide new insights into how extratropical cyclones develop and evolve, especially in the presence of thick clouds and precipitation. We will demonstrate this by presenting case studies of multiple extratropical cyclones observed by CYGNSS early on in its mission in both Northern and Southern Hemispheres. By using the improved estimates of surface wind speeds from CYGNSS, we can obtain better estimates of surface latent and sensible heat fluxes within and around extratropical cyclones. Surface heat fluxes, driven by surface winds and strong vertical gradients of water vapor and temperature, play a key role in marine cyclogenesis as they increase instability within the boundary layer and may contribute to extreme marine cyclogenesis. In the past, it has been difficult to estimate surface heat fluxes from space borne instruments, as these fluxes cannot be observed directly from space, and deficiencies in spatial coverage and attenuation from clouds and precipitation lead to inaccurate estimates of surface flux components, such as surface wind speeds. While CYGNSS only contributes estimates of surface wind speeds, we can combine this data with other reanalysis and satellite data to provide improved estimates of surface sensible and latent heat fluxes within and around extratropical cyclones and throughout the entire CYGNSS mission.

  3. Estimation of Land Surface Fluxes and Their Uncertainty via Variational Data Assimilation Approach

    NASA Astrophysics Data System (ADS)

    Abdolghafoorian, A.; Farhadi, L.

    2016-12-01

    Accurate estimation of land surface heat and moisture fluxes as well as root zone soil moisture is crucial in various hydrological, meteorological, and agricultural applications. "In situ" measurements of these fluxes are costly and cannot be readily scaled to large areas relevant to weather and climate studies. Therefore, there is a need for techniques to make quantitative estimates of heat and moisture fluxes using land surface state variables. In this work, we applied a novel approach based on the variational data assimilation (VDA) methodology to estimate land surface fluxes and soil moisture profile from the land surface states. This study accounts for the strong linkage between terrestrial water and energy cycles by coupling the dual source energy balance equation with the water balance equation through the mass flux of evapotranspiration (ET). Heat diffusion and moisture diffusion into the column of soil are adjoined to the cost function as constraints. This coupling results in more accurate prediction of land surface heat and moisture fluxes and consequently soil moisture at multiple depths with high temporal frequency as required in many hydrological, environmental and agricultural applications. One of the key limitations of VDA technique is its tendency to be ill-posed, meaning that a continuum of possibilities exists for different parameters that produce essentially identical measurement-model misfit errors. On the other hand, the value of heat and moisture flux estimation to decision-making processes is limited if reasonable estimates of the corresponding uncertainty are not provided. In order to address these issues, in this research uncertainty analysis will be performed to estimate the uncertainty of retrieved fluxes and root zone soil moisture. The assimilation algorithm is tested with a series of experiments using a synthetic data set generated by the simultaneous heat and water (SHAW) model. We demonstrate the VDA performance by comparing the (synthetic) true measurements (including profile of soil moisture and temperature, land surface water and heat fluxes, and root water uptake) with VDA estimates. In addition, the feasibility of extending the proposed approach to use remote sensing observations is tested by limiting the number of LST observations and soil moisture observations.

  4. Global atmospheric carbon budget: results from an ensemble of atmospheric CO2 inversions

    NASA Astrophysics Data System (ADS)

    Peylin, P.; Law, R. M.; Gurney, K. R.; Chevallier, F.; Jacobson, A. R.; Maki, T.; Niwa, Y.; Patra, P. K.; Peters, W.; Rayner, P. J.; Rödenbeck, C.; van der Laan-Luijkx, I. T.; Zhang, X.

    2013-10-01

    Atmospheric CO2 inversions estimate surface carbon fluxes from an optimal fit to atmospheric CO2 measurements, usually including prior constraints on the flux estimates. Eleven sets of carbon flux estimates are compared, generated by different inversions systems that vary in their inversions methods, choice of atmospheric data, transport model and prior information. The inversions were run for at least 5 yr in the period between 1990 and 2010. Mean fluxes for 2001-2004, seasonal cycles, interannual variability and trends are compared for the tropics and northern and southern extra-tropics, and separately for land and ocean. Some continental/basin-scale subdivisions are also considered where the atmospheric network is denser. Four-year mean fluxes are reasonably consistent across inversions at global/latitudinal scale, with a large total (land plus ocean) carbon uptake in the north (-3.4 Pg C yr-1 (±0.5 Pg C yr-1 standard deviation), with slightly more uptake over land than over ocean), a significant although more variable source over the tropics (1.6 ± 0.9 Pg C yr-1) and a compensatory sink of similar magnitude in the south (-1.4 ± 0.5 Pg C yr-1) corresponding mainly to an ocean sink. Largest differences across inversions occur in the balance between tropical land sources and southern land sinks. Interannual variability (IAV) in carbon fluxes is larger for land than ocean regions (standard deviation around 1.06 versus 0.33 Pg C yr-1 for the 1996-2007 period), with much higher consistency among the inversions for the land. While the tropical land explains most of the IAV (standard deviation ~ 0.65 Pg C yr-1), the northern and southern land also contribute (standard deviation ~ 0.39 Pg C yr-1). Most inversions tend to indicate an increase of the northern land carbon uptake from late 1990s to 2008 (around 0.1 Pg C yr-1, predominantly in North Asia. The mean seasonal cycle appears to be well constrained by the atmospheric data over the northern land (at the continental scale), but still highly dependent on the prior flux seasonality over the ocean. Finally we provide recommendations to interpret the regional fluxes, along with the uncertainty estimates.

  5. Linking annual N2O emission in organic soils to mineral nitrogen input as estimated by heterotrophic respiration and soil C/N ratio.

    PubMed

    Mu, Zhijian; Huang, Aiying; Ni, Jiupai; Xie, Deti

    2014-01-01

    Organic soils are an important source of N2O, but global estimates of these fluxes remain uncertain because measurements are sparse. We tested the hypothesis that N2O fluxes can be predicted from estimates of mineral nitrogen input, calculated from readily-available measurements of CO2 flux and soil C/N ratio. From studies of organic soils throughout the world, we compiled a data set of annual CO2 and N2O fluxes which were measured concurrently. The input of soil mineral nitrogen in these studies was estimated from applied fertilizer nitrogen and organic nitrogen mineralization. The latter was calculated by dividing the rate of soil heterotrophic respiration by soil C/N ratio. This index of mineral nitrogen input explained up to 69% of the overall variability of N2O fluxes, whereas CO2 flux or soil C/N ratio alone explained only 49% and 36% of the variability, respectively. Including water table level in the model, along with mineral nitrogen input, further improved the model with the explanatory proportion of variability in N2O flux increasing to 75%. Unlike grassland or cropland soils, forest soils were evidently nitrogen-limited, so water table level had no significant effect on N2O flux. Our proposed approach, which uses the product of soil-derived CO2 flux and the inverse of soil C/N ratio as a proxy for nitrogen mineralization, shows promise for estimating regional or global N2O fluxes from organic soils, although some further enhancements may be warranted.

  6. Implications of overestimated anthropogenic CO2 emissions on East Asian and global land CO2 flux inversion

    NASA Astrophysics Data System (ADS)

    Saeki, Tazu; Patra, Prabir K.

    2017-12-01

    Measurement and modelling of regional or country-level carbon dioxide (CO2) fluxes are becoming critical for verification of the greenhouse gases emission control. One of the commonly adopted approaches is inverse modelling, where CO2 fluxes (emission: positive flux, sink: negative flux) from the terrestrial ecosystems are estimated by combining atmospheric CO2 measurements with atmospheric transport models. The inverse models assume anthropogenic emissions are known, and thus the uncertainties in the emissions introduce systematic bias in estimation of the terrestrial (residual) fluxes by inverse modelling. Here we show that the CO2 sink increase, estimated by the inverse model, over East Asia (China, Japan, Korea and Mongolia), by about 0.26 PgC year-1 (1 Pg = 1012 g) during 2001-2010, is likely to be an artifact of the anthropogenic CO2 emissions increasing too quickly in China by 1.41 PgC year-1. Independent results from methane (CH4) inversion suggested about 41% lower rate of East Asian CH4 emission increase during 2002-2012. We apply a scaling factor of 0.59, based on CH4 inversion, to the rate of anthropogenic CO2 emission increase since the anthropogenic emissions of both CO2 and CH4 increase linearly in the emission inventory. We find no systematic increase in land CO2 uptake over East Asia during 1993-2010 or 2000-2009 when scaled anthropogenic CO2 emissions are used, and that there is a need of higher emission increase rate for 2010-2012 compared to those calculated by the inventory methods. High bias in anthropogenic CO2 emissions leads to stronger land sinks in global land-ocean flux partitioning in our inverse model. The corrected anthropogenic CO2 emissions also produce measurable reductions in the rate of global land CO2 sink increase post-2002, leading to a better agreement with the terrestrial biospheric model simulations that include CO2-fertilization and climate effects.

  7. Evaluation of surface layer flux parameterizations using in-situ observations

    NASA Astrophysics Data System (ADS)

    Katz, Jeremy; Zhu, Ping

    2017-09-01

    Appropriate calculation of surface turbulent fluxes between the atmosphere and the underlying ocean/land surface is one of the major challenges in geosciences. In practice, the surface turbulent fluxes are estimated from the mean surface meteorological variables based on the bulk transfer model combined with the Monnin-Obukhov Similarity (MOS) theory. Few studies have been done to examine the extent to which such a flux parameterization can be applied to different weather and surface conditions. A novel validation method is developed in this study to evaluate the surface flux parameterization using in-situ observations collected at a station off the coast of Gulf of Mexico. The main findings are: (a) the theoretical prediction that uses MOS theory does not match well with those directly computed from the observations. (b) The largest spread in exchange coefficients is shown in strong stable conditions with calm winds. (c) Large turbulent eddies, which depend strongly on the mean flow pattern and surface conditions, tend to break the constant flux assumption in the surface layer.

  8. The Multi-Step CADIS method for shutdown dose rate calculations and uncertainty propagation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ibrahim, Ahmad M.; Peplow, Douglas E.; Grove, Robert E.

    2015-12-01

    Shutdown dose rate (SDDR) analysis requires (a) a neutron transport calculation to estimate neutron flux fields, (b) an activation calculation to compute radionuclide inventories and associated photon sources, and (c) a photon transport calculation to estimate final SDDR. In some applications, accurate full-scale Monte Carlo (MC) SDDR simulations are needed for very large systems with massive amounts of shielding materials. However, these simulations are impractical because calculation of space- and energy-dependent neutron fluxes throughout the structural materials is needed to estimate distribution of radioisotopes causing the SDDR. Biasing the neutron MC calculation using an importance function is not simple becausemore » it is difficult to explicitly express the response function, which depends on subsequent computational steps. Furthermore, the typical SDDR calculations do not consider how uncertainties in MC neutron calculation impact SDDR uncertainty, even though MC neutron calculation uncertainties usually dominate SDDR uncertainty.« less

  9. Distribution and sources of polyfluoroalkyl substances (PFAS) in the River Rhine watershed.

    PubMed

    Möller, Axel; Ahrens, Lutz; Surm, Renate; Westerveld, Joke; van der Wielen, Frans; Ebinghaus, Ralf; de Voogt, Pim

    2010-10-01

    The concentration profile of 40 polyfluoroalkyl substances (PFAS) in surface water along the River Rhine watershed from the Lake Constance to the North Sea was investigated. The aim of the study was to investigate the influence of point as well as diffuse sources, to estimate fluxes of PFAS into the North Sea and to identify replacement compounds of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA). In addition, an interlaboratory comparison of the method performance was conducted. The PFAS pattern was dominated by perfluorobutane sulfonate (PFBS) and perfluorobutanoic acid (PFBA) with concentrations up to 181 ng/L and 335 ng/L, respectively, which originated from industrial point sources. Fluxes of SigmaPFAS were estimated to be approximately 6 tonnes/year which is much higher than previous estimations. Both, the River Rhine and the River Scheldt, seem to act as important sources of PFAS into the North Sea. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  10. Top-of-the-atmosphere shortwave flux estimation from satellite observations: an empirical neural network approach applied with data from the A-train constellation

    NASA Astrophysics Data System (ADS)

    Gupta, Pawan; Joiner, Joanna; Vasilkov, Alexander; Bhartia, Pawan K.

    2016-07-01

    Estimates of top-of-the-atmosphere (TOA) radiative flux are essential for the understanding of Earth's energy budget and climate system. Clouds, aerosols, water vapor, and ozone (O3) are among the most important atmospheric agents impacting the Earth's shortwave (SW) radiation budget. There are several sensors in orbit that provide independent information related to these parameters. Having coincident information from these sensors is important for understanding their potential contributions. The A-train constellation of satellites provides a unique opportunity to analyze data from several of these sensors. In this paper, retrievals of cloud/aerosol parameters and total column ozone (TCO) from the Aura Ozone Monitoring Instrument (OMI) have been collocated with the Aqua Clouds and Earth's Radiant Energy System (CERES) estimates of total reflected TOA outgoing SW flux (SWF). We use these data to develop a variety of neural networks that estimate TOA SWF globally over ocean and land using only OMI data and other ancillary information as inputs and CERES TOA SWF as the output for training purposes. OMI-estimated TOA SWF from the trained neural networks reproduces independent CERES data with high fidelity. The global mean daily TOA SWF calculated from OMI is consistently within ±1 % of CERES throughout the year 2007. Application of our neural network method to other sensors that provide similar retrieved parameters, both past and future, can produce similar estimates TOA SWF. For example, the well-calibrated Total Ozone Mapping Spectrometer (TOMS) series could provide estimates of TOA SWF dating back to late 1978.

  11. Top-of-the-Atmosphere Shortwave Flux Estimation from Satellite Observations: An Empirical Neural Network Approach Applied with Data from the A-Train Constellation

    NASA Technical Reports Server (NTRS)

    Gupta, Pawan; Joiner, Joanna; Vasilkov, Alexander; Bhartia, Pawan K.

    2016-01-01

    Estimates of top-of-the-atmosphere (TOA) radiative flux are essential for the understanding of Earth's energy budget and climate system. Clouds, aerosols, water vapor, and ozone (O3) are among the most important atmospheric agents impacting the Earth's shortwave (SW) radiation budget. There are several sensors in orbit that provide independent information related to these parameters. Having coincident information from these sensors is important for understanding their potential contributions. The A-train constellation of satellites provides a unique opportunity to analyze data from several of these sensors. In this paper, retrievals of cloud/aerosol parameters and total column ozone (TCO) from the Aura Ozone Monitoring Instrument (OMI) have been collocated with the Aqua Clouds and Earth's Radiant Energy System (CERES) estimates of total reflected TOA outgoing SW flux (SWF). We use these data to develop a variety of neural networks that estimate TOA SWF globally over ocean and land using only OMI data and other ancillary information as inputs and CERES TOA SWF as the output for training purposes. OMI-estimated TOA SWF from the trained neural networks reproduces independent CERES data with high fidelity. The global mean daily TOA SWF calculated from OMI is consistently within 1% of CERES throughout the year 2007. Application of our neural network method to other sensors that provide similar retrieved parameters, both past and future, can produce similar estimates TOA SWF. For example, the well-calibrated Total Ozone Mapping Spectrometer (TOMS) series could provide estimates of TOA SWF dating back to late 1978.

  12. The importance of landscape diversity for carbon fluxes at the landscape level: small-scale heterogeneity matters

    Treesearch

    Katrin Premke; Katrin Attermeyer; Jurgen Augustin; Alvaro Cabezas; Peter Casper; Detlef Deumlich; Jorg Gelbrecht; Horst H. Gerke; Arthur Gessler; Hans-Peter Grossart; Sabine Hilt; Michael Hupfer; Thomas Kalettka; Zachary Kayler; Gunnar Lischeid; Michael Sommer; Dominik Zak

    2016-01-01

    Landscapes can be viewed as spatially heterogeneous areas encompassing terrestrial and aquatic domains. To date, most landscape carbon (C) fluxes have been estimated by accounting for terrestrial ecosystems, while aquatic ecosystems have been largely neglected. However, a robust assessment of C fluxes on the landscape scale requires the estimation of fluxes within and...

  13. Inverse estimation of Vcmax, leaf area index, and the Ball-Berry parameter from carbon and energy fluxes

    Treesearch

    Adam Wolf; Kanat Akshalov; Nicanor Saliendra; Douglas A. Johnson; Emilio A. Laca

    2006-01-01

    Canopy fluxes of CO2 and energy can be modeled with high fidelity using a small number of environmental variables and ecosystem parameters. Although these ecosystem parameters are critically important for modeling canopy fluxes, they typically are not measured with the same intensity as ecosystem fluxes. We developed an algorithm to estimate leaf...

  14. Effects of measurement resolution on the analysis of temperature time series for stream-aquifer flux estimation

    NASA Astrophysics Data System (ADS)

    Soto-López, Carlos D.; Meixner, Thomas; Ferré, Ty P. A.

    2011-12-01

    From its inception in the mid-1960s, the use of temperature time series (thermographs) to estimate vertical fluxes has found increasing use in the hydrologic community. Beginning in 2000, researchers have examined the impacts of measurement and parameter uncertainty on the estimates of vertical fluxes. To date, the effects of temperature measurement discretization (resolution), a characteristic of all digital temperature loggers, on the determination of vertical fluxes has not been considered. In this technical note we expand the analysis of recently published work to include the effects of temperature measurement resolution on estimates of vertical fluxes using temperature amplitude and phase shift information. We show that errors in thermal front velocity estimation introduced by discretizing thermographs differ when amplitude or phase shift data are used to estimate vertical fluxes. We also show that under similar circumstances sensor resolution limits the range over which vertical velocities are accurately reproduced more than uncertainty in temperature measurements, uncertainty in sensor separation distance, and uncertainty in the thermal diffusivity combined. These effects represent the baseline error present and thus the best-case scenario when discrete temperature measurements are used to infer vertical fluxes. The errors associated with measurement resolution can be minimized by using the highest-resolution sensors available. But thoughtful experimental design could allow users to select the most cost-effective temperature sensors to fit their measurement needs.

  15. Mercury flux from salt marsh sediments: Insights from a comparison between 224Ra/228Th disequilibrium and core incubation methods

    NASA Astrophysics Data System (ADS)

    Shi, Xiangming; Mason, Robert P.; Charette, Matthew A.; Mazrui, Nashaat M.; Cai, Pinghe

    2018-02-01

    In aquatic environments, sediments are the main location of mercury methylation. Thus, accurate quantification of methylmercury (MeHg) fluxes at the sediment-water interface is vital to understanding the biogeochemical cycling of mercury, especially the toxic MeHg species, and their bioaccumulation. Traditional approaches, such as core incubations, are difficult to maintain at in-situ conditions during assays, leading to over/underestimation of benthic fluxes. Alternatively, the 224Ra/228Th disequilibrium method for tracing the transfer of dissolved substances across the sediment-water interface, has proven to be a reliable approach for quantifying benthic fluxes. In this study, the 224Ra/228Th disequilibrium and core incubation methods were compared to examine the benthic fluxes of both 224Ra and MeHg in salt marsh sediments of Barn Island, Connecticut, USA from May to August, 2016. The two methods were comparable for 224Ra but contradictory for MeHg. The radiotracer approach indicated that sediments were always the dominant source of both total mercury (THg) and MeHg. The core incubation method for MeHg produced similar results in May and August, but an opposite pattern in June and July, which suggested sediments were a sink of MeHg, contrary to the evidence of significant MeHg gradients between overlying water and porewater at the sediment-water interface. The potential reasons for such differences are discussed. Overall, we conclude that the 224Ra/228Th disequilibrium approach is preferred for estimating the benthic flux of MeHg and that sediment is indeed an important MeHg source in this marshland, and likely in other shallow coastal waters.

  16. Sea ice - atmosphere interaction: Application of multispectral satellite data in polar surface energy flux estimates

    NASA Technical Reports Server (NTRS)

    Steffen, Konrad; Schweiger, A.; Maslanik, J.; Key, J.; Haefliger, M.; Weaver, R.

    1991-01-01

    In the past six months, work has continued on energy flux sensitivity studies, ice surface temperature retrievals, corrections to Advanced Very High Resolution Radiometer (AVHRR) thermal infrared data, modelling of cloud fraction retrievals, and radiation climatologies. We tentatively conclude that the SSM/I may not provide accurate enough estimates of ice concentration and type to improve our shorter term energy flux estimates. SSM/I derived parameters may still be applicable in longer term climatological flux characterizations. We hold promise for a system coupling observation to a ice deformation model. Such a model may provide information on ice distribution which can be used in energy flux calculations. Considerable variation was found in modelled energy flux estimates when bulk transfer coefficients are modulated by lead fetch. It is still unclear what the optimum formulation is and this will be the subject of further work. Data sets for ice surface temperature retrievals were assembled and preliminary data analysis was started. Finally, construction of a conceptual framework for further modelling of the Arctic radiation flux climatology was started.

  17. Forest inventory-based estimation of carbon stocks and flux in California forests in 1990.

    Treesearch

    Jeremy S. Fried; Xiaoping Zhou

    2008-01-01

    Estimates of forest carbon stores and flux for California circa 1990 were modeled from forest inventory data in support of California’s legislatively mandated greenhouse gas inventory. Reliable estimates of live-tree carbon stores and flux on timberlands outside of national forest could be calculated from periodic inventory data collected in the 1980s and 1990s;...

  18. Turbulent CO2 Flux Measurements by Lidar: Length Scales, Results and Comparison with In-Situ Sensors

    NASA Technical Reports Server (NTRS)

    Gilbert, Fabien; Koch, Grady J.; Beyon, Jeffrey Y.; Hilton, Timothy W.; Davis, Kenneth J.; Andrews, Arlyn; Ismail, Syed; Singh, Upendra N.

    2009-01-01

    The vertical CO2 flux in the atmospheric boundary layer (ABL) is investigated with a Doppler differential absorption lidar (DIAL). The instrument was operated next to the WLEF instrumented tall tower in Park Falls, Wisconsin during three days and nights in June 2007. Profiles of turbulent CO2 mixing ratio and vertical velocity fluctuations are measured by in-situ sensors and Doppler DIAL. Time and space scales of turbulence are precisely defined in the ABL. The eddy-covariance method is applied to calculate turbulent CO2 flux both by lidar and in-situ sensors. We show preliminary mean lidar CO2 flux measurements in the ABL with a time and space resolution of 6 h and 1500 m respectively. The flux instrumental errors decrease linearly with the standard deviation of the CO2 data, as expected. Although turbulent fluctuations of CO2 are negligible with respect to the mean (0.1 %), we show that the eddy-covariance method can provide 2-h, 150-m range resolved CO2 flux estimates as long as the CO2 mixing ratio instrumental error is no greater than 10 ppm and the vertical velocity error is lower than the natural fluctuations over a time resolution of 10 s.

  19. Ephemeral-stream channel and basin-floor infiltration and recharge in the Sierra Vista subwatershed of the Upper San Pedro Basin, Southeastern Arizona: Chapter J in Ground-water recharge in the arid and semiarid southwestern United States (Professional Paper 1703)

    USGS Publications Warehouse

    Coes, A.L.; Pool, D.R.; Stonestrom, David A.; Constantz, Jim; Ferré, Ty P.A.; Leake, Stanley A.

    2007-01-01

    The timing and location of streamflow in the San Pedro River are partially dependent on the aerial distribution of recharge in the Sierra Vista subwatershed. Previous investigators have assumed that recharge in the subwatershed occurs only along the mountain fronts by way of stream-channel infiltration near the contact between low-permeability rocks of the mountains and the basin fill. Recent studies in other alluvial basins of the Southwestern United States, however, have shown that significant recharge can occur through the sediments of ephemeral stream channels at locations several kilometers distant from the mountains. The purpose of this study was to characterize the spatial distribution of infiltration and subsequent recharge through the ephemeral channels in the Sierra Vista subwatershed.Infiltration fluxes in ephemeral channels and through the basin floor of the subwatershed were estimated by using several methods. Data collected during the drilling and coring of 16 boreholes included physical, thermal, and hydraulic properties of sediments; chloride concentrations of sediments; and pore-water stable-isotope values and tritium activity. Surface and subsurface sediment temperatures were continuously measured at each borehole.Twelve boreholes were drilled in five ephemeral stream channels to estimate infiltration within ephemeral channels. Active infiltration was verified to at least 20 meters at 11 of the 12 borehole sites on the basis of low sediment-chloride concentrations, high soil-water contents, and pore-water tritium activity similar to present-day precipitation. Consolidated sediments at the twelfth site prevented core recovery and estimation of infiltration. Analytical and numerical methods were applied to determine the surface infiltration flux required to produce the observed sediment-temperature fluctuations at six sites. Infiltration fluxes were determined for summer ephemeral flow events only because no winter flows were recorded at the sites during the monitoring period.Four boreholes were drilled in the basin floor to estimate infiltration in areas between ephemeral channels. Infiltration fluxes through the basin floor ranged from less than 1 centimeter to 6 centimeters per year. At a site in semiconsolidated to consolidated basin-fill conglomerate, the long-term infiltration fluxes were very low (less than 1 centimeter per year). Chloride, tritium, and stable-isotope data indicate long periods of no net deep downward percolation flux beneath the basin floor. At a site in unconsolidated to semiconsolidated basin-fill sand and gravel, infiltration fluxes were high (2 to 6 centimeters per year). Chloride, tritium, and stable-isotope data indicate active infiltration to 8 meters, and a decrease in infiltration below 8 meters. The change in the infiltration rate below 8 meters is controlled by an increase in the silt and clay content of the sediment.Ephemeral-channel recharge for the entire subwatershed was estimated by upscaling the calculated infiltration fluxes and weighting the fluxes by streamflow duration, evaporation, and transpiration. In contrast to previous assumptions, recharge from ephemeral-streamflow infiltration occurs not only near the mountain fronts, but also along significant lengths of ephemeral channels. Although most of the ephemeral streams in the subwatershed flow less than a few days per year, the available streamflow quickly infiltrates past depths where it is available for evapotranspiration. This water likely stays in the unsaturated zone until it is vertically displaced by infiltrated water from subsequent streamflows and eventually recharges the regional aquifer. Ephemeral-channel infiltration during 2001 and 2002 was estimated to account for about 12 to 19 percent of the estimated average annual recharge in the Sierra Vista subwatershed.

  20. Synthesis of urban greenhouse gas emission estimates from the Indianapolis Flux Experiment (INFLUX)

    NASA Astrophysics Data System (ADS)

    Turnbull, J. C.; Davis, K. J.; Deng, A.; Lauvaux, T.; Miles, N. L.; Richardson, S.; Sarmiento, D. P.; Wu, K.; Brewer, A.; Hardesty, R. M.; McKain, K.; Sweeney, C.; Gurney, K. R.; Liang, J.; O'Keeffe, D.; Patarasuk, R.; Cambaliza, M. O. L.; Harvey, R. M.; Heimburger, A. M. F.; Shepson, P. B.; Karion, A.; Lopez-Coto, I.; Prasad, K.; Whetstone, J. R.

    2016-12-01

    The Indianapolis Flux Experiment (INFLUX) is testing the boundaries of our ability to use atmospheric measurements to quantify urban greenhouse gas (GHG) emissions. The project brings together high-resolution (in both space and time) inventory assessments, a multi-year record of in situ CO2, CH4and CO from tower-based and aircraft-based atmospheric measurements along with a complementary suite of 35 trace gases and isotopes from flasks collected at the same sites, and atmospheric modelling. Together, these provide high-accuracy, high-resolution, continuous monitoring of emissions of GHGs from the city. Here we synthesize the results to date, and demonstrate broad agreement amongst city-wide emission rates determined from the various top-down and bottom-up methods. We highlight the areas where ongoing efforts are reducing uncertainties in the overall flux estimation, including accurate representation of atmospheric transport, partitioning of GHG source types and the influence of background atmospheric GHG mole fractions.

  1. Regularized Biot-Savart Laws for Modeling Magnetic Configurations with Flux Ropes

    NASA Astrophysics Data System (ADS)

    Titov, V. S.; Downs, C.; Mikic, Z.; Torok, T.; Linker, J.

    2017-12-01

    Many existing models assume that magnetic flux ropes play a key role in solar flares and coronal mass ejections (CMEs). It is therefore important to develop efficient methods for constructing flux-rope configurations constrained by observed magnetic data and the initial morphology of CMEs. For this purpose, we have derived and implemented a compact analytical form that represents the magnetic field of a thin flux rope with an axis of arbitrary shape and a circular cross-section. This form implies that the flux rope carries axial current I and axial flux F, so that the respective magnetic field is the curl of the sum of toroidal and poloidal vector potentials proportional to I and F, respectively. We expressed the vector potentials in terms of modified Biot-Savart laws whose kernels are regularized at the axis in such a way that these laws define a cylindrical force-free flux rope with a parabolic profile of the axial current density, when the axis is straight. For the cases we have studied so far, we determined the shape of the rope axis by following the polarity inversion line of the eruptions' source region, using observed magnetograms. The height variation along the axis and other flux-rope parameters are estimated by means of potential field extrapolations. Using this heuristic approach, we were able to construct pre-eruption configurations for the 2009 February13 and 2011 October 1 CME events. These applications demonstrate the flexibility and efficiency of our new method for energizing pre-eruptive configurations in MHD simulations of CMEs. We discuss possible ways of optimizing the axis paths and other extensions of the method in order to make it more useful and robust. Research supported by NSF, NASA's HSR and LWS Programs, and AFOSR.

  2. Aircraft- and tower-based fluxes of carbon dioxide, latent, and sensible heat

    NASA Technical Reports Server (NTRS)

    Desjardins, R. L.; Hart, R. L.; Macpherson, J. I.; Schuepp, P. H.; Verma, S. B.

    1992-01-01

    Fluxes of carbon dioxide, water vapor, and sensible heat obtained over a grassland ecosystem, during the First International Satellite Land Surface Climatology Project (ISLSCP) Field Experiment (FIFE), using an aircraft- and two tower-based systems are compared for several days in 1987 and in 1989. The tower-based cospectral estimates of CO2, sensible heat, water vapor, and momentum, expressed as a function of wavenumber K times sampling height z, are relatively similar to the aircraft-based estimates for K x z greater than 0.1. A measurable contribution to the fluxes is observed by tower-based systems at K x z less than 0.01 but not by the aircraft-based system operating at an altitude of approximately 100 m over a 15 x 15 km area. Using all available simultaneous aircraft and tower data, flux estimates by both systems were shown to be highly correlated. As expected from the spatial variations of the greenness index, surface extrapolation of airborne flux estimates tended to lie between those of the two tower sites. The average fluxes obtained, on July 11, 1987, and August 4, 1989, by flying a grid pattern over the FIFE site agreed with the two tower data sets for CO2, but sensible and latent heat were smaller than those obtained by the tower-based systems. However, in general, except for a small underestimation due to the long wavelength contributions and due to flux divergence with height, the differences between the aircraft- and tower-based surface estimates of fluxes appear to be mainly attributable to differences in footprint, that is, differences in the area contributing to the surface flux estimates.

  3. Error estimates for ice discharge calculated using the flux gate approach

    NASA Astrophysics Data System (ADS)

    Navarro, F. J.; Sánchez Gámez, P.

    2017-12-01

    Ice discharge to the ocean is usually estimated using the flux gate approach, in which ice flux is calculated through predefined flux gates close to the marine glacier front. However, published results usually lack a proper error estimate. In the flux calculation, both errors in cross-sectional area and errors in velocity are relevant. While for estimating the errors in velocity there are well-established procedures, the calculation of the error in the cross-sectional area requires the availability of ground penetrating radar (GPR) profiles transverse to the ice-flow direction. In this contribution, we use IceBridge operation GPR profiles collected in Ellesmere and Devon Islands, Nunavut, Canada, to compare the cross-sectional areas estimated using various approaches with the cross-sections estimated from GPR ice-thickness data. These error estimates are combined with those for ice-velocities calculated from Sentinel-1 SAR data, to get the error in ice discharge. Our preliminary results suggest, regarding area, that the parabolic cross-section approaches perform better than the quartic ones, which tend to overestimate the cross-sectional area for flight lines close to the central flowline. Furthermore, the results show that regional ice-discharge estimates made using parabolic approaches provide reasonable results, but estimates for individual glaciers can have large errors, up to 20% in cross-sectional area.

  4. Evaluation of fluxes of suspended matters and bedload in the small granitic Strengbach catchment (Vosges massif, France)

    NASA Astrophysics Data System (ADS)

    Cotel, Solenn; Viville, Daniel; Pierret, Marie Claire; Benarioumlil, Sylvain; Chabaux, François

    2016-04-01

    Transport of suspended matters (SM) and bedload in river controls the erosion process and elements export of a catchment. Furthermore, the SM are heavily involved in the migration of organic matter, metals and pollutants. The knowledge of the dynamics of the SM export is also essential to better understand the hydrogeochemical functioning of natural ecosystem. We investigated this question at the scale of a catchment; the Strengbach basin (site of OHGE - Observatoire Hydro-Géochimique de l'Environnement) where meteorological and hydrological data are monitored since 30 years. This small granitic basin (0,8km²) is located in the Vosges massif at altitudes between 883m and 1146m with 1400mm mean annual precipitations. A first evaluation of the solid fluxes exported at the Strengbach catchment was carried out on the basis of fortnightly sampling and measurement (Viville et al., 2012). Two automatic water samplers have been set up at the outlet of the basin in december 2012, in order to 1) evaluate the potential bias generated by the sampling frequency and 2) improve the SM flux calculation accuracy especially by taking into account the high flow events. These two samplers allowed regular sampling at 16h time step as well as high flow events sampling. At the same time, the bedload flux was estimated fortnightly by measuring the volume of sediments accumulated in a flume. However, the characteristics of the small Strengbach catchment (low water level, low SM concentration and mountainous winter climatic conditions) required to adapt the conventionally used systems. In this way, the SM annual flux estimated with the data from the two samplers varied between 7,5T and 8,8T during the three years of the study. By comparison, the SM annual flux obtained with previous method (only fortnightly sampling) was significantly different with values ranging from 2,8T to 16,6T. The contribution from each sampler and thus each sampling strategy to the improvement of the SM flux estimation has been calculated and is discussed below. When the SM flux due to high flow events is added to the SM flux based on 16h time step samples, the annual SM flux was improved of only 3% to 12% depending on the year, which can be surprising. During the three years of the study, the annual bedload flux was estimated between 1,3T and 5,0T, indicating that the solid export is dominated by SM transport in this catchment. Between 2004 and 2010, the mean weathering net flux (exports at the outlet corrected by atmospheric inputs) was of 1,6T/yr for the basic cations and of 2,3T/yr for the silica (Viville et al., 2012). Thus, in the Strengbach catchment, the SM and bedload exports represent a significant portion of the global chemical elements export. In such catchments, theses solid fluxes can not be neglected.

  5. 13C tracer experiments and metabolite balancing for metabolic flux analysis: comparing two approaches

    PubMed

    Schmidt; Marx; de Graaf AA; Wiechert; Sahm; Nielsen; Villadsen

    1998-04-05

    Conventional metabolic flux analysis uses the information gained from determination of measurable fluxes and a steady-state assumption for intracellular metabolites to calculate the metabolic fluxes in a given metabolic network. The determination of intracellular fluxes depends heavily on the correctness of the assumed stoichiometry including the presence of all reactions with a noticeable impact on the model metabolite balances. Determination of fluxes in complex metabolic networks often requires the inclusion of NADH and NADPH balances, which are subject to controversial debate. Transhydrogenation reactions that transfer reduction equivalents from NADH to NADPH or vice versa can usually not be included in the stoichiometric model, because they result in singularities in the stoichiometric matrix. However, it is the NADPH balance that, to a large extent, determines the calculated flux through the pentose phosphate pathway. Hence, wrong assumptions on the presence or activity of transhydrogenation reactions will result in wrong estimations of the intracellular flux distribution. Using 13C tracer experiments and NMR analysis, flux analysis can be performed on the basis of only well established stoichiometric equations and measurements of the labeling state of intracellular metabolites. Neither NADH/NADPH balancing nor assumptions on energy yields need to be included to determine the intracellular fluxes. Because metabolite balancing methods and the use of 13C labeling measurements are two different approaches to the determination of intracellular fluxes, both methods can be used to verify each other or to discuss the origin and significance of deviations in the results. Flux analysis based entirely on metabolite balancing and flux analysis, including labeling information, have been performed independently for a wild-type strain of Aspergillus oryzae producing alpha-amylase. Two different nitrogen sources, NH4+ and NO3-, have been used to investigate the influence of the NADPH requirements on the intracellular flux distribution. The two different approaches to the calculation of fluxes are compared and deviations in the results are discussed. Copyright 1998 John Wiley & Sons, Inc.

  6. Scalar flux modeling in turbulent flames using iterative deconvolution

    NASA Astrophysics Data System (ADS)

    Nikolaou, Z. M.; Cant, R. S.; Vervisch, L.

    2018-04-01

    In the context of large eddy simulations, deconvolution is an attractive alternative for modeling the unclosed terms appearing in the filtered governing equations. Such methods have been used in a number of studies for non-reacting and incompressible flows; however, their application in reacting flows is limited in comparison. Deconvolution methods originate from clearly defined operations, and in theory they can be used in order to model any unclosed term in the filtered equations including the scalar flux. In this study, an iterative deconvolution algorithm is used in order to provide a closure for the scalar flux term in a turbulent premixed flame by explicitly filtering the deconvoluted fields. The assessment of the method is conducted a priori using a three-dimensional direct numerical simulation database of a turbulent freely propagating premixed flame in a canonical configuration. In contrast to most classical a priori studies, the assessment is more stringent as it is performed on a much coarser mesh which is constructed using the filtered fields as obtained from the direct simulations. For the conditions tested in this study, deconvolution is found to provide good estimates both of the scalar flux and of its divergence.

  7. Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

    NASA Astrophysics Data System (ADS)

    Brioude, Jerome; Angevine, Wayne; Ahmadov, Ravan; Kim, Si Wan; Evan, Stephanie; McKeen, Stuart; Hsie, Eirh Yu; Frost, Greg; Neuman, Andy; Pollack, Ilana; Peischl, Jeff; Ryerson, Tom; Holloway, John; Brown, Steeve; Nowak, John; Roberts, Jim; Wofsy, Steeve; Santoni, Greg; Trainer, Michael

    2013-04-01

    We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% ± 6% in LA County and by 37% ± 10% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% ± 10% in LA County and by 27% ± 15% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 ± 18 Tg yr-1 in SoCAB. A flight during ITCT in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% ± 14% in LA County but decreased by 4% ± 10% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, CARB 2010 and the posterior inventories derived in this study. The biases in WRF-Chem ozone were reduced and correlations were increased using the posterior from this study compared with simulations with the two bottom-up inventories, showing that improving the spatial distribution of ozone precursor surface emissions is also important in mesoscale chemistry forecasts.

  8. Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

    NASA Astrophysics Data System (ADS)

    Brioude, J.; Angevine, W. M.; Ahmadov, R.; Kim, S.-W.; Evan, S.; McKeen, S. A.; Hsie, E.-Y.; Frost, G. J.; Neuman, J. A.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Holloway, J.; Brown, S. S.; Nowak, J. B.; Roberts, J. M.; Wofsy, S. C.; Santoni, G. W.; Trainer, M.

    2012-12-01

    We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% ± 6% in LA County and by 37% ± 10% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% ± 10% in LA County and by 27% ± 15% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 ± 18 Tg yr-1 in SoCAB. A flight during ITCT in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% ± 14% in LA County but decreased by 4% ± 10% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, CARB 2010 and the posterior inventories derived in this study. The biases in WRF-Chem ozone were reduced and correlations were increased using the posterior from this study compared with simulations with the two bottom-up inventories, showing that improving the spatial distribution of ozone precursor surface emissions is also important in mesoscale chemistry forecasts.

  9. Multiple Flux Footprints, Flux Divergences and Boundary Layer Mixing Ratios: Studies of Ecosystem-Atmosphere CO2 Exchange Using the WLEF Tall Tower.

    NASA Astrophysics Data System (ADS)

    Davis, K. J.; Bakwin, P. S.; Yi, C.; Cook, B. D.; Wang, W.; Denning, A. S.; Teclaw, R.; Isebrands, J. G.

    2001-05-01

    Long-term, tower-based measurements using the eddy-covariance method have revealed a wealth of detail about the temporal dynamics of netecosystem-atmosphere exchange (NEE) of CO2. The data also provide a measure of the annual net CO2 exchange. The area represented by these flux measurements, however, is limited, and doubts remain about possible systematic errors that may bias the annual net exchange measurements. Flux and mixing ratio measurements conducted at the WLEF tall tower as part of the Chequamegon Ecosystem-Atmosphere Study (ChEAS) allow for unique assessment of the uncertainties in NEE of CO2. The synergy between flux and mixing ratio observations shows the potential for comparing inverse and eddy-covariance methods of estimating NEE of CO2. Such comparisons may strengthen confidence in both results and begin to bridge the huge gap in spatial scales (at least 3 orders of magnitude) between continental or hemispheric scale inverse studies and kilometer-scale eddy covariance flux measurements. Data from WLEF and Willow Creek, another ChEAS tower, are used to estimate random and systematic errors in NEE of CO2. Random uncertainty in seasonal exchange rates and the annual integrated NEE, including both turbulent sampling errors and variability in enviromental conditions, is small. Systematic errors are identified by examining changes in flux as a function of atmospheric stability and wind direction, and by comparing the multiple level flux measurements on the WLEF tower. Nighttime drainage is modest but evident. Systematic horizontal advection occurs during the morning turbulence transition. The potential total systematic error appears to be larger than random uncertainty, but still modest. The total systematic error, however, is difficult to assess. It appears that the WLEF region ecosystems were a small net sink of CO2 in 1997. It is clear that the summer uptake rate at WLEF is much smaller than that at most deciduous forest sites, including the nearby Willow Creek site. The WLEF tower also allows us to study the potential for monitoring continental CO2 mixing ratios from tower sites. Despite concerns about the proximity to ecosystem sources and sinks, it is clear that boundary layer CO2 mixing ratios can be monitored using typical surface layer towers. Seasonal and annual land-ocean mixing ratio gradients are readily detectable, providing the motivation for a flux-tower based mixing ratio observation network that could greatly improve the accuracy of inversion-based estimates of NEE of CO2, and enable inversions to be applied on smaller temporal and spatial scales. Results from the WLEF tower illustrate the degree to which local flux measurements represent interannual, seasonal and synoptic CO2 mixing ratio trends. This coherence between fluxes and mixing ratios serves to "regionalize" the eddy-covariance based local NEE observations.

  10. Concentration, flux, and the analysis of trends of total and dissolved phosphorus, total nitrogen, and chloride in 18 tributaries to Lake Champlain, Vermont and New York, 1990–2011

    USGS Publications Warehouse

    Medalie, Laura

    2013-01-01

    Annual concentration, flux, and yield for total phosphorus, dissolved phosphorus, total nitrogen, and chloride for 18 tributaries to Lake Champlain were estimated for 1990 through 2011 using a weighted regression method based on time, tributary streamflows (discharges), and seasonal factors. The weighted regression method generated two series of daily estimates of flux and concentration during the period of record: one based on observed discharges and a second based on a flow-normalization procedure that removes random variation due to year-to-year climate-driven effects. The flownormalized estimate for a given date is similar to an average estimate of concentration or flux that would be made if all of the observed discharges for that date were equally likely to have occurred. The flux bias statistic showed that 68 of the 72 flux regression models were minimally biased. Temporal trends in the concentrations and fluxes were determined by calculating percent changes in flow-normalized annual fluxes for the full period of analysis (1990 through 2010) and for the decades 1990–2000 and 2000–2010. Basinwide, flow-normalized total phosphorus flux decreased by 42 metric tons per year (t/yr) between 1990 and 2010. This net result reflects a basinwide decrease in flux of 21 metric tons (t) between 1990 and 2000, followed by a decrease of 20 t between 2000 and 2010; both results were largely influenced by flux patterns in the large tributaries on the eastern side of the basin. A comparison of results for total phosphorus for the two separate decades of analysis found that more tributaries had decreasing concentrations and flux rates in the second decade than the first. An overall reduction in dissolved phosphorus flux of 0.7 t/yr was seen in the Lake Champlain Basin during the full period of analysis. That very small net change in flux reflects substantial reductions between 1990 and 2000 from eastern tributaries, especially in Otter Creek and the LaPlatte and Winooski Rivers that largely were offset by increases in the Missisquoi and Saranac Rivers in the second decade (between 2000 and 2010). The number of tributaries that had increases in dissolved phosphorus concentrations stayed constant at 13 or 14 during the period of analysis. Total nitrogen concentration and flux for most of the monitored tributaries in the Lake Champlain Basin have decreased since 1990. Between 1990 and 2010, flow-normalized total nitrogen flux decreased by 386 t/yr, which reflects an increase of 440 t/yr between 1990 and 2000 and a decrease of 826 t/yr between 2000 and 2010. All individual tributaries except the Winooski River had decreases in total nitrogen concentration and flux between 2000 and 2010. The decrease in total nitrogen flux over the period of record could be related to the decrease in nitrogen from atmospheric deposition observed in Vermont or to concurrent benefits realized from the implementation of agricultural best-management practices in the Lake Champlain Basin that were designed primarily to reduce phosphorus runoff. For chloride, large increases in flow-normalized concentrations and flux between 1990 and 2000 for 17 of the 18 tributaries diminished to small increases or decreases between 2000 and 2010. Between 1990 and 2010, flow-normalized flux increased by 32,225 t/yr, 78 percent of which (25,163 t) was realized during the first decade, from 1990 through 2000. The five tributaries that had decreasing concentration and flux of chloride between 2000 and 2010 were all on the eastern side of Lake Champlain, possibly related to reductions since 1999 in winter road salt application in Vermont. Positive correlations of phosphorus flux and changes in phosphorus concentration and flux in tributaries with phosphorus inputs to basins from point sources, suggest that point sources have an effect on stream phosphorus chemistry. Several measures of changes in agricultural statistics, such as agricultural land use, acres of land in farms, acres of cropland, and acres of corn for grain or seed, are positively correlated with changes in phosphorus concentration or flux in the tributaries. Negative correlations of the amount of money spent on agricultural best-management practices with changes in phosphorus concentration or flux in the tributaries, suggest that best-management practices may be an effective tool, along with point-source reductions, in making progress towards management goals for phosphorus reductions in Lake Champlain.

  11. [A review on research of land surface water and heat fluxes].

    PubMed

    Sun, Rui; Liu, Changming

    2003-03-01

    Many field experiments were done, and soil-vegetation-atmosphere transfer(SVAT) models were stablished to estimate land surface heat fluxes. In this paper, the processes of experimental research on land surface water and heat fluxes are reviewed, and three kinds of SVAT model(single layer model, two layer model and multi-layer model) are analyzed. Remote sensing data are widely used to estimate land surface heat fluxes. Based on remote sensing and energy balance equation, different models such as simplified model, single layer model, extra resistance model, crop water stress index model and two source resistance model are developed to estimate land surface heat fluxes and evapotranspiration. These models are also analyzed in this paper.

  12. Gaussian Process Regression for Uncertainty Estimation on Ecosystem Data

    NASA Astrophysics Data System (ADS)

    Menzer, O.; Moffat, A.; Lasslop, G.; Reichstein, M.

    2011-12-01

    The flow of carbon between terrestrial ecosystems and the atmosphere is mainly driven by nonlinear, complex and time-lagged processes. Understanding the associated ecosystem responses and climatic feedbacks is a key challenge regarding climate change questions such as increasing atmospheric CO2 levels. Usually, the underlying relationships are implemented in models as prescribed functions which interlink numerous meteorological, radiative and gas exchange variables. In contrast, supervised Machine Learning algorithms, such as Artificial Neural Networks or Gaussian Processes, allow for an insight into the relationships directly from a data perspective. Micrometeorological, high resolution measurements at flux towers of the FLUXNET observational network are an essential tool for obtaining quantifications of the ecosystem variables, as they continuously record e.g. CO2 exchange, solar radiation and air temperature. In order to facilitate the investigation of the interactions and feedbacks between these variables, several challenging data properties need to be taken into account: noisy, multidimensional and incomplete (Moffat, Accepted). The task of estimating uncertainties in such micrometeorological measurements can be addressed by Gaussian Processes (GPs), a modern nonparametric method for nonlinear regression. The GP approach has recently been shown to be a powerful modeling tool, regardless of the input dimensionality, the degree of nonlinearity and the noise level (Rasmussen and Williams, 2006). Heteroscedastic Gaussian Processes (HGPs) are a specialized GP method for data with a varying, inhomogeneous noise variance (Goldberg et al., 1998; Kersting et al., 2007), as usually observed in CO2 flux measurements (Richardson et al., 2006). Here, we showed by an evaluation of the HGP performance in several artificial experiments and a comparison to existing nonlinear regression methods, that their outstanding ability is to capture measurement noise levels, concurrently providing reasonable data fits under relatively few assumptions. On the basis of incomplete, half-hourly measured ecosystem data, a HGP was trained to model NEP (Net Ecosystem Production), only with the drivers PPFD (Photosynthetic Photon Flux Density) and Air Temperature. Time information was added to account for the autocorrelation in the flux measurements. Provided with a gap-filled, meteorological time series, NEP and the corresponding random error estimates can then be predicted empirically at high temporal resolution. We report uncertainties in annual sums of CO2 exchange at two flux tower sites in Hainich, Germany and Hesse, France. Similar noise patterns, but different magnitudes between sites were detected, with annual random error estimates of +/- 14.1 gCm^-2yr^-1 and +/- 23.5 gCm^-2yr^-1, respectively, for the year 2001. Existing models calculate uncertainties by evaluating the standard deviation of the model residuals. A comparison to the methods of Reichstein et al. (2005) and Lasslop et al. (2008) showed confidence both in the predictive uncertainties and the annual sums modeled with the HGP approach.

  13. Turbulent variance characteristics of temperature and humidity over a non-uniform land surface for an agricultural ecosystem in China

    NASA Astrophysics Data System (ADS)

    Gao, Z. Q.; Bian, L. G.; Chen, Z. G.; Sparrow, M.; Zhang, J. H.

    2006-05-01

    This paper describes the application of the variance method for flux estimation over a mixed agricultural region in China. Eddy covariance and flux variance measurements were conducted in a near-surface layer over a non-uniform land surface in the central plain of China from 7 June to 20 July 2002. During this period, the mean canopy height was about 0.50 m. The study site consisted of grass (10% of area), beans (15%), corn (15%) and rice (60%). Under unstable conditions, the standard deviations of temperature and water vapor density (normalized by appropriate scaling parameters), observed by a single instrument, followed the Monin-Obukhov similarity theory. The similarity constants for heat (C-T) and water vapor (C-q) were 1.09 and 1.49, respectively. In comparison with direct measurements using eddy covariance techniques, the flux variance method, on average, underestimated sensible heat flux by 21% and latent heat flux by 24%, which may be attributed to the fact that the observed slight deviations (20% or 30% at most) of the similarity "constants" may be within the expected range of variation of a single instrument from the generally-valid relations.

  14. Predictive models for radial sap flux variation in coniferous, diffuse-porous and ring-porous temperate trees.

    PubMed

    Berdanier, Aaron B; Miniat, Chelcy F; Clark, James S

    2016-08-01

    Accurately scaling sap flux observations to tree or stand levels requires accounting for variation in sap flux between wood types and by depth into the tree. However, existing models for radial variation in axial sap flux are rarely used because they are difficult to implement, there is uncertainty about their predictive ability and calibration measurements are often unavailable. Here we compare different models with a diverse sap flux data set to test the hypotheses that radial profiles differ by wood type and tree size. We show that radial variation in sap flux is dependent on wood type but independent of tree size for a range of temperate trees. The best-fitting model predicted out-of-sample sap flux observations and independent estimates of sapwood area with small errors, suggesting robustness in the new settings. We develop a method for predicting whole-tree water use with this model and include computer code for simple implementation in other studies. Published by Oxford University Press 2016. This work is written by (a) US Government employee(s) and is in the public domain in the US.

  15. Electric flux tube in a magnetic plasma

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liao Jinfeng; Shuryak, Edward

    2008-06-15

    In this paper we study a methodical problem related to the magnetic scenario recently suggested and initiated by Liao and Shuryak [Phys. Rev. C 75, 054907 (2007)] to understand the strongly coupled quark-gluon plasma (sQGP): the electric flux tube in a monopole plasma. A macroscopic approach, in which we interpolate between a Bose condensed (dual superconductor) medium and a classical gas medium, is developed first. Then we work out a microscopic approach based on detailed quantum mechanical calculations of the monopole scattering on the electric flux tube, evaluating induced currents for all partial waves. As expected, the flux tube losesmore » its stability when particles can penetrate it: We make this condition precise by calculating the critical value for the product of the flux tube size times the particle momentum, above which the flux tube dissolves. Lattice static potentials indicate that flux tubes seem to dissolve at T>T{sub dissolution}{approx_equal}1.3T{sub c}. Using our criterion one gets an estimate of the magnetic density n{approx_equal}4.4-6.6 fm{sup -3} at this temperature.« less

  16. Parameter sensitivity analysis of a 1-D cold region lake model for land-surface schemes

    NASA Astrophysics Data System (ADS)

    Guerrero, José-Luis; Pernica, Patricia; Wheater, Howard; Mackay, Murray; Spence, Chris

    2017-12-01

    Lakes might be sentinels of climate change, but the uncertainty in their main feedback to the atmosphere - heat-exchange fluxes - is often not considered within climate models. Additionally, these fluxes are seldom measured, hindering critical evaluation of model output. Analysis of the Canadian Small Lake Model (CSLM), a one-dimensional integral lake model, was performed to assess its ability to reproduce diurnal and seasonal variations in heat fluxes and the sensitivity of simulated fluxes to changes in model parameters, i.e., turbulent transport parameters and the light extinction coefficient (Kd). A C++ open-source software package, Problem Solving environment for Uncertainty Analysis and Design Exploration (PSUADE), was used to perform sensitivity analysis (SA) and identify the parameters that dominate model behavior. The generalized likelihood uncertainty estimation (GLUE) was applied to quantify the fluxes' uncertainty, comparing daily-averaged eddy-covariance observations to the output of CSLM. Seven qualitative and two quantitative SA methods were tested, and the posterior likelihoods of the modeled parameters, obtained from the GLUE analysis, were used to determine the dominant parameters and the uncertainty in the modeled fluxes. Despite the ubiquity of the equifinality issue - different parameter-value combinations yielding equivalent results - the answer to the question was unequivocal: Kd, a measure of how much light penetrates the lake, dominates sensible and latent heat fluxes, and the uncertainty in their estimates is strongly related to the accuracy with which Kd is determined. This is important since accurate and continuous measurements of Kd could reduce modeling uncertainty.

  17. Validation of a Solid Rocket Motor Internal Environment Model

    NASA Technical Reports Server (NTRS)

    Martin, Heath T.

    2017-01-01

    In a prior effort, a thermal/fluid model of the interior of Penn State University's laboratory-scale Insulation Test Motor (ITM) was constructed to predict both the convective and radiative heat transfer to the interior walls of the ITM with a minimum of empiricism. These predictions were then compared to values of total and radiative heat flux measured in a previous series of ITM test firings to assess the capabilities and shortcomings of the chosen modeling approach. Though the calculated fluxes reasonably agreed with those measured during testing, this exercise revealed means of improving the fidelity of the model to, in the case of the thermal radiation, enable direct comparison of the measured and calculated fluxes and, for the total heat flux, compute a value indicative of the average measured condition. By replacing the P1-Approximation with the discrete ordinates (DO) model for the solution of the gray radiative transfer equation, the radiation intensity field in the optically thin region near the radiometer is accurately estimated, allowing the thermal radiation flux to be calculated on the heat-flux sensor itself, which was then compared directly to the measured values. Though the fully coupling the wall thermal response with the flow model was not attempted due to the excessive computational time required, a separate wall thermal response model was used to better estimate the average temperature of the graphite surfaces upstream of the heat flux gauges and improve the accuracy of both the total and radiative heat flux computations. The success of this modeling approach increases confidence in the ability of state-of-the-art thermal and fluid modeling to accurately predict SRM internal environments, offers corrections to older methods, and supplies a tool for further studies of the dynamics of SRM interiors.

  18. Demagnetization using a determined estimated magnetic state

    DOEpatents

    Denis, Ronald J; Makowski, Nathanael J

    2015-01-13

    A method for demagnetizing comprising positioning a core within the electromagnetic field generated by a first winding until the generated first electrical current is not substantially increasing, thereby determining a saturation current. A second voltage, having the opposite polarity, is then applied across the first winding until the generated second electrical current is approximately equal to the magnitude of the determined saturation current. The maximum magnetic flux within the core is then determined using the voltage across said first winding and the second current. A third voltage, having the opposite polarity, is then applied across the first winding until the core has a magnetic flux equal to approximately half of the determined maximum magnetic flux within the core.

  19. Local energy flux estimates for unstable conditions using variance data in semiarid rangelands

    USGS Publications Warehouse

    Kustas, William P.; Blanford, J.H.; Stannard, D.I.; Daughtry, C.S.T.; Nichols, W.D.; Weltz, M.A.

    1994-01-01

    A network of meteorological stations was installed during the Monsoon '90 field campaign in the Walnut Gulch experimental watershed. The study area has a fairly complex surface. The vegetation cover is heterogeneous and sparse, and the terrain is mildly hilly, but dissected by ephemeral channels. Besides measurement of some of the standard weather data such as wind speed, air temperature, and solar radiation, these sites also contained instruments for estimating the local surface energy balance. The approach utilized measurements of net radiation (Rn), soil heat flux (G) and Monin-Obukhov similarity theory applied to first- and second-order turbulent statistics of wind speed and temperature for determining the sensible heat flux (H). The latent heat flux (LE) was solved as a residual in the surface energy balance equation, namely, LE = −(Rn + G + H). This procedure (VAR-RESID) for estimating the energy fluxes satisfied monetary constraints and the requirement for low maintenance and continued operation through the harsh environmental conditions experienced in semiarid regions. Comparison of energy fluxes using this approach with more traditional eddy correlation techniques showed differences were within 20% under unstable conditions. Similar variability in flux estimates over the study area was present in the eddy correlation data. Hence, estimates of H and LE using the VAR-RESID approach under unstable conditions were considered satisfactory. Also, with second-order statistics of vertical velocity collected at several sites, the local momentum roughness length was estimated. This is an important parameter used in modeling the turbulent transfer of momentum and sensible heat fluxes across the surface-atmosphere interface.

  20. Quantification of Methane and VOC Emissions from Natural Gas Production in Two Basins with High Ozone Events

    NASA Astrophysics Data System (ADS)

    Edie, R.; Robertson, A.; Snare, D.; Soltis, J.; Field, R. A.; Murphy, S. M.

    2015-12-01

    Since 2005, the Uintah Basin of Utah and the Upper Green River Basin of Wyoming frequently exceeded the EPA 8-hour allowable ozone level of 75 ppb, spurring interest in volatile organic compounds (VOCs) emitted during oil and gas production. Debate continues over which stage of production (drilling, flowback, normal production, transmission, etc.) is the most prevalent VOC source. In this study, we quantify emissions from normal production on well pads by using the EPA-developed Other Test Method 33a. This methodology combines ground-based measurements of fugitive emissions with 3-D wind data to calculate the methane and VOC emission fluxes from a point source. VOC fluxes are traditionally estimated by gathering a canister of air during a methane flux measurement. The methane:VOC ratio of this canister is determined at a later time in the laboratory, and applied to the known methane flux. The University of Wyoming Mobile Laboratory platform is equipped with a Picarro methane analyzer and an Ionicon Proton Transfer Reaction-Time of Flight-Mass Spectrometer, which provide real-time methane and VOC data for each well pad. This independent measurement of methane and VOCs in situ reveals multiple emission sources on one well pad, with varying methane:VOC ratios. Well pad emission estimates of methane, benzene, toluene and xylene for the two basins will be presented. The different emission source VOC profiles and the limitations of real-time and traditional VOC measurement methods will also be discussed.

  1. Refinement of the nocturnal boundary layer budget method for quantifying agricultural greenhouse gas emissions

    NASA Astrophysics Data System (ADS)

    Wittebol, Laura A.

    Measuring greenhouse gas (GHG) emissions directly at the farm scale is most relevant to the agricultural sector and has the potential to eliminate some of the uncertainty arising from scaling up from plot or field studies or down from regional or national levels. The stable nighttime atmosphere acts as a chamber within which sequentially-measured GHG concentration profiles determine the flux of GHGs. With the overall goal of refining the nocturnal boundary layer (NBL) budget method to obtain reliable flux estimates at a scale representative of the typical eastern Canadian farm (approximately 1 km2), fluxes of CO2, N2O, and CH4 were measured at two agricultural farms in Eastern Canada. Field sites in 1998 and 2002 were located on an experimental farm adjacent to a suburb southwest of the city of Ottawa, ON, a relatively flat area with corn, hay, and soy as the dominant crops. The field site in 2003 was located in the rural community of Coteau-du-Lac, QC, about 20 km southwest of the island of Montreal, a fairly flat area bordered by the St. Lawrence River to the south, consisting mainly of corn and hay with a mixture of soy and vegetable crops. A good agreement was obtained between the overall mean NBL budget-measured CO2 flux at both sites, near-in-time windy night eddy covariance data and previously published results. The mean NBL-measured N2O flux from all wind directions and farming management was of the same order of magnitude as, but slightly higher than, previously published baseline N2O emissions from agroecosystems. Methane fluxes results were judged to be invalid as they were extremely sensitive to wind direction change. Spatial sampling of CO 2, N2O, and CH4 around the two sites confirmed that [CH4] distribution was particularly sensitive to the nature of the emission source, field conditions, and wind direction. Optimal NBL conditions for measuring GHG fluxes, present approximately 60% of the time in this study, consisted of a very stable boundary layer in which GHG profiles converged at the top of the layer allowing a quick determination of the NBL flux integration height. For suboptimal NBL conditions consisting of intermittent turbulence where GHG profiles did not converge, a flux integration method was developed which yielded estimates similar to those obtained during optimal conditions. Eighty percent of the GHG flux in optimal NBL conditions corresponded to a footprint-modelled source area of approximately 2 km upwind, slightly beyond the typical length of a farm in Coteau-du-Lac. A large portion (50%) of the flux came from within 1 km upwind of the measurement site, showing the influence of local sources. 'Top-down' NBL-measured flux values were compared with aggregated field, literature and IPCC flux values for four footprint model-defined areas across both sites, with results indicating that in baseline climatic and farm management conditions, with no apparent intermittent NBL phenomena, the aggregated flux was a good approximation of the NBL-measured flux.

  2. Submarine fresh groundwater discharge into Laizhou Bay comparable to the Yellow River flux

    PubMed Central

    Wang, Xuejing; Li, Hailong; Jiao, Jiu Jimmy; Barry, D. A.; Li, Ling; Luo, Xin; Wang, Chaoyue; Wan, Li; Wang, Xusheng; Jiang, Xiaowei; Ma, Qian; Qu, Wenjing

    2015-01-01

    Near- and off-shore fresh groundwater resources become increasingly important with the social and economic development in coastal areas. Although large scale (hundreds of km) submarine groundwater discharge (SGD) to the ocean has been shown to be of the same magnitude order as river discharge, submarine fresh groundwater discharge (SFGD) with magnitude comparable to large river discharge is never reported. Here, we proposed a method coupling mass-balance models of water, salt and radium isotopes based on field data of 223Ra, 226Ra and salinity to estimate the SFGD, SGD. By applying the method in Laizhou Bay (a water area of ~6000 km2), we showed that the SFGD and SGD are 0.57 ~ 0.88 times and 7.35 ~ 8.57 times the annual Yellow River flux in August 2012, respectively. The estimate of SFGD ranges from 4.12 × 107 m3/d to 6.36 × 107 m3/d, while SGD ranges from 5.32 × 108 m3/d to 6.20 × 108 m3/d. The proportion of the Yellow River input into Laizhou Bay was less than 14% of the total in August 2012. Our method can be used to estimate SFGD in various coastal waters. PMID:25742712

  3. Improving Evapotranspiration Estimates Using Multi-Platform Remote Sensing

    NASA Astrophysics Data System (ADS)

    Knipper, Kyle; Hogue, Terri; Franz, Kristie; Scott, Russell

    2016-04-01

    Understanding the linkages between energy and water cycles through evapotranspiration (ET) is uniquely challenging given its dependence on a range of climatological parameters and surface/atmospheric heterogeneity. A number of methods have been developed to estimate ET either from primarily remote-sensing observations, in-situ measurements, or a combination of the two. However, the scale of many of these methods may be too large to provide needed information about the spatial and temporal variability of ET that can occur over regions with acute or chronic land cover change and precipitation driven fluxes. The current study aims to improve the spatial and temporal variability of ET utilizing only satellite-based observations by incorporating a potential evapotranspiration (PET) methodology with satellite-based down-scaled soil moisture estimates in southern Arizona, USA. Initially, soil moisture estimates from AMSR2 and SMOS are downscaled to 1km through a triangular relationship between MODIS land surface temperature (MYD11A1), vegetation indices (MOD13Q1/MYD13Q1), and brightness temperature. Downscaled soil moisture values are then used to scale PET to actual ET (AET) at a daily, 1km resolution. Derived AET estimates are compared to observed flux tower estimates, the North American Land Data Assimilation System (NLDAS) model output (i.e. Variable Infiltration Capacity (VIC) Macroscale Hydrologic Model, Mosiac Model, and Noah Model simulations), the Operational Simplified Surface Energy Balance Model (SSEBop), and a calibrated empirical ET model created specifically for the region. Preliminary results indicate a strong increase in correlation when incorporating the downscaling technique to original AMSR2 and SMOS soil moisture values, with the added benefit of being able to decipher small scale heterogeneity in soil moisture (riparian versus desert grassland). AET results show strong correlations with relatively low error and bias when compared to flux tower estimates. In addition, AET results show improved bias to those reported by SSEBop, with similar correlations and errors when compared to the empirical ET model. Spatial patterns of estimated AET display patterns representative of the basin's elevation and vegetation characteristics, with improved spatial resolution and temporal heterogeneity when compared to previous models.

  4. Comparative study of elemental mercury flux measurement techniques over a Fennoscandian boreal peatland

    NASA Astrophysics Data System (ADS)

    Osterwalder, S.; Sommar, J.; Åkerblom, S.; Jocher, G.; Fritsche, J.; Nilsson, M. B.; Bishop, K.; Alewell, C.

    2018-01-01

    Quantitative estimates of the land-atmosphere exchange of gaseous elemental mercury (GEM) are biased by the measurement technique employed, because no standard method or scale in space and time are agreed upon. Here we present concurrent GEM exchange measurements over a boreal peatland using a novel relaxed eddy accumulation (REA) system, a rectangular Teflon® dynamic flux chamber (DFC) and a DFC designed according to aerodynamic considerations (Aero-DFC). During four consecutive days the DFCs were placed alternately on two measurement plots in every cardinal direction around the REA sampling mast. Spatial heterogeneity in peat surface characteristics (0-34 cm) was identified by measuring total mercury in eight peat cores (57 ± 8 ng g-1, average ± SE), vascular plant coverage (32-52%), water table level (4.5-14.1 cm) and dissolved gaseous elemental mercury concentrations (28-51 pg L-1) in the peat water. The GEM fluxes measured by the DFCs showed a distinct diel pattern, but no spatial difference in the average fluxes was detected (ANOVA, α = 0.05). Even though the correlation between the Teflon® DFC and Aero-DFC was significant (r = 0.76, p < 0.05) the cumulative flux of the Aero-DFC was a factor of three larger. The average flux of the Aero-DFC (1.9 ng m-2 h-1) and REA (2 ng m-2 h-1) were in good agreement. The results indicate that the novel REA design is in agreement for cumulative flux estimates with the Aero-DFC, which incorporates the effect of atmospheric turbulence. The comparison was performed over a fetch with spatially rather homogenous GEM flux dynamics under fairly consistent weather conditions, minimizing the effect of weather influence on the data from the three measurement systems. However, in complex biomes with heterogeneous surface characteristics where there can be large spatial variability in GEM gas exchange, the small footprint of chambers (<0.2 m2) makes for large coefficients of variation. Thus many chamber measurement replications are needed to establish a credible biome GEM flux estimate, even for a single point in time. Dynamic flux chambers will, however, be able to resolve systematic differences between small scale features, such as experimentally manipulated plots or small scale spatial heterogeneity.

  5. Variability of Kelvin wave momentum flux from high-resolution radiosonde and radio occultation data

    NASA Astrophysics Data System (ADS)

    Sjoberg, J. P.; Zeng, Z.; Ho, S. P.; Birner, T.; Anthes, R. A.; Johnson, R. H.

    2017-12-01

    Direct measurement of momentum flux from Kelvin waves in the stratosphere remains challenging. Constraining this flux from observations is an important step towards constraining the flux from models. Here we present results from analyses using linear theory to estimate the Kelvin wave amplitudes and momentum fluxes from both high-resolution radiosondes and from radio occultation (RO) data. These radiosonde data are from a contiguous 11-year span of soundings performed at two Department of Energy Atmospheric Radiation Measurement sites, while the RO data span 14 years from multiple satellite missions. Daily time series of the flux from both sources are found to be in quantitative agreement with previous studies. Climatological analyses of these data reveal the expected seasonal cycle and variability associated with the quasi-biennial oscillation. Though both data sets provide measurements on distinct spatial and temporal scales, the estimated flux from each provides insight into separate but complimentary aspects of how the Kelvin waves affect the stratosphere. Namely, flux derived from radiosonde sites provide details on the regional Kelvin wave variability, while the flux from RO data are zonal mean estimates.

  6. Helium Flux from the Earth's Mantle as Estimated from Hawaiian Fumarolic Degassing.

    PubMed

    Naughton, J J; Lee, J H; Keeling, D; Finlayson, J B; Dority, G

    1973-04-06

    Averaged helium to carbon dioxide ratios measured from systematic collections of gases from Sulphur Bank fumarole. Kilauea, Hawaii, when coupled with estimates of carbon in the earth's crust, give a helium flux of 1 x 105 atoms per square centimeter per second. This is within the lower range of other estimates, and may represent the flux from deep-seated sources in the upper mantle.

  7. A Mechanistically Informed User-Friendly Model to Predict Greenhouse Gas (GHG) Fluxes and Carbon Storage from Coastal Wetlands

    NASA Astrophysics Data System (ADS)

    Abdul-Aziz, O. I.; Ishtiaq, K. S.

    2015-12-01

    We present a user-friendly modeling tool on MS Excel to predict the greenhouse gas (GHG) fluxes and estimate potential carbon sequestration from the coastal wetlands. The dominant controls of wetland GHG fluxes and their relative mechanistic linkages with various hydro-climatic, sea level, biogeochemical and ecological drivers were first determined by employing a systematic data-analytics method, including Pearson correlation matrix, principal component and factor analyses, and exploratory partial least squares regressions. The mechanistic knowledge and understanding was then utilized to develop parsimonious non-linear (power-law) models to predict wetland carbon dioxide (CO2) and methane (CH4) fluxes based on a sub-set of climatic, hydrologic and environmental drivers such as the photosynthetically active radiation, soil temperature, water depth, and soil salinity. The models were tested with field data for multiple sites and seasons (2012-13) collected from the Waquoit Bay, MA. The model estimated the annual wetland carbon storage by up-scaling the instantaneous predicted fluxes to an extended growing season (e.g., May-October) and by accounting for the net annual lateral carbon fluxes between the wetlands and estuary. The Excel Spreadsheet model is a simple ecological engineering tool for coastal carbon management and their incorporation into a potential carbon market under a changing climate, sea level and environment. Specifically, the model can help to determine appropriate GHG offset protocols and monitoring plans for projects that focus on tidal wetland restoration and maintenance.

  8. Thermodynamics-based Metabolite Sensitivity Analysis in metabolic networks.

    PubMed

    Kiparissides, A; Hatzimanikatis, V

    2017-01-01

    The increasing availability of large metabolomics datasets enhances the need for computational methodologies that can organize the data in a way that can lead to the inference of meaningful relationships. Knowledge of the metabolic state of a cell and how it responds to various stimuli and extracellular conditions can offer significant insight in the regulatory functions and how to manipulate them. Constraint based methods, such as Flux Balance Analysis (FBA) and Thermodynamics-based flux analysis (TFA), are commonly used to estimate the flow of metabolites through genome-wide metabolic networks, making it possible to identify the ranges of flux values that are consistent with the studied physiological and thermodynamic conditions. However, unless key intracellular fluxes and metabolite concentrations are known, constraint-based models lead to underdetermined problem formulations. This lack of information propagates as uncertainty in the estimation of fluxes and basic reaction properties such as the determination of reaction directionalities. Therefore, knowledge of which metabolites, if measured, would contribute the most to reducing this uncertainty can significantly improve our ability to define the internal state of the cell. In the present work we combine constraint based modeling, Design of Experiments (DoE) and Global Sensitivity Analysis (GSA) into the Thermodynamics-based Metabolite Sensitivity Analysis (TMSA) method. TMSA ranks metabolites comprising a metabolic network based on their ability to constrain the gamut of possible solutions to a limited, thermodynamically consistent set of internal states. TMSA is modular and can be applied to a single reaction, a metabolic pathway or an entire metabolic network. This is, to our knowledge, the first attempt to use metabolic modeling in order to provide a significance ranking of metabolites to guide experimental measurements. Copyright © 2016 International Metabolic Engineering Society. Published by Elsevier Inc. All rights reserved.

  9. Quasar Photometric Redshifts and Candidate Selection: A New Algorithm Based on Optical and Mid-infrared Photometric Data

    NASA Astrophysics Data System (ADS)

    Yang, Qian; Wu, Xue-Bing; Fan, Xiaohui; Jiang, Linhua; McGreer, Ian; Green, Richard; Yang, Jinyi; Schindler, Jan-Torge; Wang, Feige; Zuo, Wenwen; Fu, Yuming

    2017-12-01

    We present a new algorithm to estimate quasar photometric redshifts (photo-zs), by considering the asymmetries in the relative flux distributions of quasars. The relative flux models are built with multivariate Skew-t distributions in the multidimensional space of relative fluxes as a function of redshift and magnitude. For 151,392 quasars in the SDSS, we achieve a photo-z accuracy, defined as the fraction of quasars with the difference between the photo-z z p and the spectroscopic redshift z s , | {{Δ }}z| =| {z}s-{z}p| /(1+{z}s) within 0.1, of 74%. Combining the WISE W1 and W2 infrared data with the SDSS data, the photo-z accuracy is enhanced to 87%. Using the Pan-STARRS1 or DECaLS photometry with WISE W1 and W2 data, the photo-z accuracies are 79% and 72%, respectively. The prior probabilities as a function of magnitude for quasars, stars, and galaxies are calculated, respectively, based on (1) the quasar luminosity function, (2) the Milky Way synthetic simulation with the Besançon model, and (3) the Bayesian Galaxy Photometric Redshift estimation. The relative fluxes of stars are obtained with the Padova isochrones, and the relative fluxes of galaxies are modeled through galaxy templates. We test our classification method to select quasars using the DECaLS g, r, z, and WISE W1 and W2 photometry. The quasar selection completeness is higher than 70% for a wide redshift range 0.5< z< 4.5, and a wide magnitude range 18< r< 21.5 mag. Our photo-z regression and classification method has the potential to extend to future surveys. The photo-z code will be publicly available.

  10. New data-driven estimation of terrestrial CO2 fluxes in Asia using a standardized database of eddy covariance measurements, remote sensing data, and support vector regression

    NASA Astrophysics Data System (ADS)

    Ichii, Kazuhito; Ueyama, Masahito; Kondo, Masayuki; Saigusa, Nobuko; Kim, Joon; Alberto, Ma. Carmelita; Ardö, Jonas; Euskirchen, Eugénie S.; Kang, Minseok; Hirano, Takashi; Joiner, Joanna; Kobayashi, Hideki; Marchesini, Luca Belelli; Merbold, Lutz; Miyata, Akira; Saitoh, Taku M.; Takagi, Kentaro; Varlagin, Andrej; Bret-Harte, M. Syndonia; Kitamura, Kenzo; Kosugi, Yoshiko; Kotani, Ayumi; Kumar, Kireet; Li, Sheng-Gong; Machimura, Takashi; Matsuura, Yojiro; Mizoguchi, Yasuko; Ohta, Takeshi; Mukherjee, Sandipan; Yanagi, Yuji; Yasuda, Yukio; Zhang, Yiping; Zhao, Fenghua

    2017-04-01

    The lack of a standardized database of eddy covariance observations has been an obstacle for data-driven estimation of terrestrial CO2 fluxes in Asia. In this study, we developed such a standardized database using 54 sites from various databases by applying consistent postprocessing for data-driven estimation of gross primary productivity (GPP) and net ecosystem CO2 exchange (NEE). Data-driven estimation was conducted by using a machine learning algorithm: support vector regression (SVR), with remote sensing data for 2000 to 2015 period. Site-level evaluation of the estimated CO2 fluxes shows that although performance varies in different vegetation and climate classifications, GPP and NEE at 8 days are reproduced (e.g., r2 = 0.73 and 0.42 for 8 day GPP and NEE). Evaluation of spatially estimated GPP with Global Ozone Monitoring Experiment 2 sensor-based Sun-induced chlorophyll fluorescence shows that monthly GPP variations at subcontinental scale were reproduced by SVR (r2 = 1.00, 0.94, 0.91, and 0.89 for Siberia, East Asia, South Asia, and Southeast Asia, respectively). Evaluation of spatially estimated NEE with net atmosphere-land CO2 fluxes of Greenhouse Gases Observing Satellite (GOSAT) Level 4A product shows that monthly variations of these data were consistent in Siberia and East Asia; meanwhile, inconsistency was found in South Asia and Southeast Asia. Furthermore, differences in the land CO2 fluxes from SVR-NEE and GOSAT Level 4A were partially explained by accounting for the differences in the definition of land CO2 fluxes. These data-driven estimates can provide a new opportunity to assess CO2 fluxes in Asia and evaluate and constrain terrestrial ecosystem models.

  11. Thorium-derived dust fluxes to the tropical Pacific Ocean, 58 Ma

    NASA Astrophysics Data System (ADS)

    Woodard, Stella C.; Thomas, Deborah J.; Marcantonio, Franco

    2012-06-01

    Eolian dust in pelagic deep sea sediments can be used to reconstruct ancient wind patterns and paleoenvironmental response to climate change. Traditional methods to determine dust accumulation involve isolating the non-dissolvable aluminosilicate minerals from deep sea sediments through a series of chemical leaches, but cannot differentiate between minerals from eolian, authigenic and volcanogenic sources. Other geochemical proxies, such as sedimentary 232Th and crustal 4He content, have been used to construct high-resolution records of atmospheric dust fluxes to the deep sea during the Quaternary. Here we use sedimentary Th content as a proxy for terrigenous material (eolian dust) in ˜58 Myr-old sediments from the Shatsky Rise (ODP Site 1209) and compare our results with previous dust estimates generated using the traditional chemical extraction method and sedimentary 4Hecrustal concentrations. We find excellent agreement between Th-based dust estimates and those generated using the traditional method. In addition our results show a correlation between sedimentary Th and 4Hecrustal content, which suggests a source older than present day Asian loess supplied dust to the central subtropical Pacific Ocean during the early Paleogene.

  12. Estimating contamination potential at waste-disposal sites using a natural tracer

    NASA Astrophysics Data System (ADS)

    Stone, William J.

    1992-05-01

    Chloride is a conservative, natural tracer found in precipitation, soil water, and groundwater. The chloride mass-balance approach, long used to estimate groundwater recharge, also provides a downward flux of moisture and solute at sites where there is a potential for groundwater contamination. The flux is obtained by dividing the product of the mean annual precipitation and total annual chloride input (via precipitation and dust) by the mean soil-water chloride content. Chlorideversusdepth profiles can also be used to determine optimum depth of waste burial to minimize deterioration of waste containers. The method has been applied to three sites in arid alluvial-basin settings in New Mexico, U.S.A.: a proposed landfill, a battery recycling plant, and a hazardous-waste disposal facility. It is concluded that the method is reliable, economical, and practical. Furthermore, it can be applied at any stage in the development of a site. The chloride method should apply in any recharge area where the base of the root zone is separated from the water table by at least 3 m or so and chloride in soil water comes only from precipitation and dust.

  13. Linking Annual N2O Emission in Organic Soils to Mineral Nitrogen Input as Estimated by Heterotrophic Respiration and Soil C/N Ratio

    PubMed Central

    Mu, Zhijian; Huang, Aiying; Ni, Jiupai; Xie, Deti

    2014-01-01

    Organic soils are an important source of N2O, but global estimates of these fluxes remain uncertain because measurements are sparse. We tested the hypothesis that N2O fluxes can be predicted from estimates of mineral nitrogen input, calculated from readily-available measurements of CO2 flux and soil C/N ratio. From studies of organic soils throughout the world, we compiled a data set of annual CO2 and N2O fluxes which were measured concurrently. The input of soil mineral nitrogen in these studies was estimated from applied fertilizer nitrogen and organic nitrogen mineralization. The latter was calculated by dividing the rate of soil heterotrophic respiration by soil C/N ratio. This index of mineral nitrogen input explained up to 69% of the overall variability of N2O fluxes, whereas CO2 flux or soil C/N ratio alone explained only 49% and 36% of the variability, respectively. Including water table level in the model, along with mineral nitrogen input, further improved the model with the explanatory proportion of variability in N2O flux increasing to 75%. Unlike grassland or cropland soils, forest soils were evidently nitrogen-limited, so water table level had no significant effect on N2O flux. Our proposed approach, which uses the product of soil-derived CO2 flux and the inverse of soil C/N ratio as a proxy for nitrogen mineralization, shows promise for estimating regional or global N2O fluxes from organic soils, although some further enhancements may be warranted. PMID:24798347

  14. Satellite-based Calibration of Heat Flux at the Ocean Surface

    NASA Astrophysics Data System (ADS)

    Barron, C. N.; Dastugue, J. M.; May, J. C.; Rowley, C. D.; Smith, S. R.; Spence, P. L.; Gremes-Cordero, S.

    2016-02-01

    Model forecasts of upper ocean heat content and variability on diurnal to daily scales are highly dependent on estimates of heat flux through the air-sea interface. Satellite remote sensing is applied to not only inform the initial ocean state but also to mitigate errors in surface heat flux and model representations affecting the distribution of heat in the upper ocean. Traditional assimilation of sea surface temperature (SST) observations re-centers ocean models at the start of each forecast cycle. Subsequent evolution depends on estimates of surface heat fluxes and upper-ocean processes over the forecast period. The COFFEE project (Calibration of Ocean Forcing with satellite Flux Estimates) endeavors to correct ocean forecast bias through a responsive error partition among surface heat flux and ocean dynamics sources. A suite of experiments in the southern California Current demonstrates a range of COFFEE capabilities, showing the impact on forecast error relative to a baseline three-dimensional variational (3DVAR) assimilation using Navy operational global or regional atmospheric forcing. COFFEE addresses satellite-calibration of surface fluxes to estimate surface error covariances and links these to the ocean interior. Experiment cases combine different levels of flux calibration with different assimilation alternatives. The cases may use the original fluxes, apply full satellite corrections during the forecast period, or extend hindcast corrections into the forecast period. Assimilation is either baseline 3DVAR or standard strong-constraint 4DVAR, with work proceeding to add a 4DVAR expanded to include a weak constraint treatment of the surface flux errors. Covariance of flux errors is estimated from the recent time series of forecast and calibrated flux terms. While the California Current examples are shown, the approach is equally applicable to other regions. These approaches within a 3DVAR application are anticipated to be useful for global and larger regional domains where a full 4DVAR methodology may be cost-prohibitive.

  15. Measurement of NOx and CO Fluxes from a Tall Tower in Beijing.

    NASA Astrophysics Data System (ADS)

    Squires, F. A.; Drysdale, W. S.; Hamilton, J.; Lee, J. D.; Vaughan, A. R.; Wild, O.; Mullinger, N.; Nemitz, E.; Metzger, S.; Zhang, Q.

    2017-12-01

    China's air quality problems are well publicised; in 2010, 1.2 million premature deaths were attributed to outdoor air pollution in China. One of the major air quality issues is high concentrations of nitrogen oxides (NOx). China is the largest NOx emitter, contributing an estimated 18 % to global NOx emissions. Beijing itself is reported to have NO2 concentrations 42 % higher than the annual national standard. Given the high levels of pollution, increased focus has been placed on improving emissions estimates which are typically developed using a `bottom-up' approach where emissions are predicted from their sources. Emission inventories in China have large uncertainties and are rapidly changing with time in response to economic development, environmental regulation and new technologies. In fact, China is the largest contributor to the uncertainty in the source and the magnitude of air pollutants in air quality models. Recent studies have shown a discrepancy between NOx inventories and measured NOx emissions for UK cities, highlighting the limitations of bottom-up emissions inventories and the importance of accurate measurement data to improve the estimates. 5 Hz measurements of NOx and CO concentration were made as part of the Air Pollutants in Beijing (AIRPOLL-Beijing) project during two field campaigns in Nov-Dec 2016 and May-June 2017. Sampling took place from an inlet co-located with a sonic anemometer at 102 m on a meteorological tower in central Beijing. Analysis of the covariance between vertical wind speed and concentration enabled the calculation of emission flux, with an estimated footprint of between 2 - 5 km from the tower (which typically included some major ring roads and expressways). Fluxes were quantified using the continuous wavelet transformation (CWT) method, which enabled one minute resolved fluxes to be calculated. These data were compared to existing emissions estimates from the Multi-resolution Emission Inventory for China (MEIC). It is anticipated that this work will be used to evaluate the accuracy of emissions inventories for Beijing and to develop improved emissions estimates.

  16. Quantifying the imprint of mesoscale and synoptic-scale atmospheric transport on total column carbon dioxide measurements

    NASA Astrophysics Data System (ADS)

    Torres, A. D.; Keppel-Aleks, G.; Doney, S. C.; Feng, S.; Lauvaux, T.; Fendrock, M. A.; Rheuben, J.

    2017-12-01

    Remote sensing instruments provide an unprecedented density of observations of the atmospheric CO2 column average mole fraction (denoted as XCO2), which can be used to constrain regional scale carbon fluxes. Inferring fluxes from XCO2 observations is challenging, as measurements and inversion methods are sensitive to not only the imprint local and large-scale fluxes, but also mesoscale and synoptic-scale atmospheric transport. Quantifying the fine-scale variability in XCO2 from mesoscale and synoptic-scale atmospheric transport will likely improve overall error estimates from flux inversions by improving estimates of representation errors that occur when XCO2 observations are compared to modeled XCO2 in relatively coarse transport models. Here, we utilize various statistical methods to quantify the imprint of atmospheric transport on XCO2 observations. We compare spatial variations along Orbiting Carbon Observatory (OCO-2) satellite tracks to temporal variations observed by the Total Column Carbon Observing Network (TCCON). We observe a coherent seasonal cycle of both within-day temporal and fine-scale spatial variability (of order 10 km) of XCO2 from these two datasets, suggestive of the imprint of mesoscale systems. To account for other potential sources of error in XCO2 retrieval, we compare observed temporal and spatial variations of XCO2 to high-resolution output from the Weather Research and Forecasting (WRF) model run at 9 km resolution. In both simulations and observations, the Northern hemisphere mid-latitude XCO2 showed peak variability during the growing season when atmospheric gradients are largest. These results are qualitatively consistent with our expectations of seasonal variations of the imprint of synoptic and mesoscale atmospheric transport on XCO2 observations; suggesting that these statistical methods could be sensitive to the imprint of atmospheric transport on XCO2 observations.

  17. Synergy of the SimSphere land surface process model with ASTER imagery for the retrieval of spatially distributed estimates of surface turbulent heat fluxes and soil moisture content

    NASA Astrophysics Data System (ADS)

    Petropoulos, George; Wooster, Martin J.; Carlson, Toby N.; Drake, Nick

    2010-05-01

    Accurate information on spatially explicit distributed estimates of key land-atmosphere fluxes and related land surface parameters is of key importance in a range of disciplines including hydrology, meteorology, agriculture and ecology. Estimation of those parameters from remote sensing frequently employs the integration of such data with mathematical representations of the transfers of energy, mass and radiation between soil, vegetation and atmosphere continuum, known as Soil Vegetation Atmosphere Transfer (SVAT) models. The ability of one such inversion modelling scheme to resolve for key surface energy fluxes and of soil surface moisture content is examined here using data from a multispectral high spatial resolution imaging instrument, the Advanced Spaceborne Thermal Emission and Reflection Scanning Radiometer (ASTER) and SimSphere one-dimensional SVAT model. Accuracy of the investigated methodology, so-called as the "triangle" method, is verified using validated ground observations obtained from selected days collected from nine CARBOEUROPE IP sites representing a variety of climatic, topographic and environmental conditions. Subsequently, a new framework is suggested for the retrieval of two additional parameters by the investigated method, namely the Evaporative (EF) and the Non-Evaporative (NEF) Fractions. Results indicated a close agreement between the inverted surface fluxes and surface moisture availability maps as well as of the EF and NEF parameters with the observations both spatially and temporally with accuracies comparable to those obtained in similar experiments with high spatial resolution data. Inspection of the inverted surface fluxes maps regionally, showed an explainable distribution in the range of the inverted parameters in relation with the surface heterogeneity. Overall performance of the "triangle" inversion methodology was found to be affected predominantly by the SVAT model "correct" initialisation representative of the test site environment, most importantly the atmospheric conditions required in the SVAT model initial conditions. This study represents the first comprehensive evaluation of the performance of this particular methodological implementation at a European setting using the SimSphere SVAT with the ASTER data. The present work is also very timely in that, a variation of this specific inversion methodology has been proposed for the operational retrieval of the soil surface moisture content by National Polar-orbiting Operational Environmental Satellite System (NPOESS), in a series of satellite platforms that are due to be launched in the next 12 years starting from 2012. KEYWORDS: micrometeorology, surface heat fluxes, soil moisture content, ASTER, triangle method, SimSphere, CarboEurope IP

  18. Contrasts between chemical and physical estimates of baseflow help discern multiple sources of water contributing to rivers

    NASA Astrophysics Data System (ADS)

    Cartwright, I.; Gilfedder, B.; Hofmann, H.

    2013-05-01

    This study compares geochemical and physical methods of estimating baseflow in the upper reaches of the Barwon River, southeast Australia. Estimates of baseflow from physical techniques such as local minima and recursive digital filters are higher than those based on chemical mass balance using continuous electrical conductivity (EC). Between 2001 and 2011 the baseflow flux calculated using chemical mass balance is between 1.8 × 103 and 1.5 × 104 ML yr-1 (15 to 25% of the total discharge in any one year) whereas recursive digital filters yield baseflow fluxes of 3.6 × 103 to 3.8 × 104 ML yr-1 (19 to 52% of discharge) and the local minimum method yields baseflow fluxes of 3.2 × 103 to 2.5 × 104 ML yr-1 (13 to 44% of discharge). These differences most probably reflect how the different techniques characterise baseflow. Physical methods probably aggregate much of the water from delayed sources as baseflow. However, as many delayed transient water stores (such as bank return flow or floodplain storage) are likely to be geochemically similar to surface runoff, chemical mass balance calculations aggregate them with the surface runoff component. The mismatch between geochemical and physical estimates is greatest following periods of high discharge in winter, implying that these transient stores of water feed the river for several weeks to months. Consistent with these interpretations, modelling of bank storage indicates that bank return flows provide water to the river for several weeks after flood events. EC vs. discharge variations during individual flow events also imply that an inflow of low EC water stored within the banks or on the floodplain occurs as discharge falls. The joint use of physical and geochemical techniques allows a better understanding of the different components of water that contribute to river flow, which is important for the management and protection of water resources.

  19. Slowdown of N2O emissions from China's croplands

    NASA Astrophysics Data System (ADS)

    Zhou, F.; Shang, Z.; Ciais, P.; Piao, S.; Tian, H.; Saikawa, E.; Zaehle, S.; Del Grosso, S. J.; Galloway, J. N.

    2016-12-01

    To feed the increasing population, China has experienced a rapid agricultural development over past decades, accompanied by increased fertilizer consumptions in croplands, but the magnitude, trend, and causes of the associated nitrous oxide (N2O) emissions has remain unclear. The primary sources of this uncertainty are conflicting estimates of fertilizer consumption and emission factors, the latter being uncertain because of very few regional representativeness of the Nrate-flux relationships in China. Here we re-estimate China's N2O emissions from croplands using three different methods: flux upscaling technique, process-based models and atmospheric inversion, and also analyze the corresponding drivers using an attribution approach. The three methods produce similar estimates of N2O emissions in the range of 0.67 ± 0.08 to 0.62± 0.11 Tg nitrogen per year, which is 29% larger than the estimates by the Emission Database for Global Atmospheric Research (EDGAR) that is adopted by Intergovernmental Panel on Climate Change (IPCC) as the emission baseline and twofold larger than the latest Chinese national report submitted to the United Nations Framework Convention on Climate Change, but the revised trend slows down after 2005. Fertilizer N application per area is the dominant factor driving the increase in N2O emissions across most cropping regions from 1990 to 2004, but climate-induced change of emission factors has also controlled N2O flux from 2005 onwards. Our findings suggest that, as precipitation would increase in North China but decline in the South in future, EF will increasingly control China's agri. soil emissions of N2O, unless offset by larger reductions of fertilizer consumptions.

  20. Microbial imprint on soil-atmosphere H2, COS, and CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Meredith, L. K.; Commane, R.; Munger, J. W.; Wofsy, S. C.; Prinn, R. G.

    2013-12-01

    Microorganisms drive large trace gas fluxes between soil and atmosphere, but the signal can be difficult to detect and quantify in the presence of stronger exchange processes in an ecosystem. Partitioning methods are often needed to estimate trace gas budgets and to develop process-based models to explore the sensitivity of microbe-mediated fluxes. In this study, we test the performance of trace gases with predominantly microbe-mediated soil fluxes as a metric of the soil microbial uptake activity of other trace gases. Using simultaneous, collocated measurements at Harvard Forest, we consider three trace gases with microbe-mediated soil fluxes of various importance relative to their other (mainly plant-mediated) ecosystem fluxes: molecular hydrogen (H2), carbonyl sulfide (COS), and carbon dioxide (CO2). These gases probe different aspects of the soil trace-gas microbiology. Soil H2 uptake is a redox reaction driving the energy metabolism of a portion of the microbial community, while soil CO2 respiration is a partial proxy for the overall soil microbial metabolism. In comparison, very little is understood about the microbiological and environmental drivers of soil COS uptake and emissions. In this study, we find that H2, COS, and CO2 soil uptake rates are often correlated, but the relative soil uptake between gases is not constant, and is influenced by seasonality and local environmental conditions. We also consider how differences in the microbial communities and pathways involved in the soil fluxes may explain differences in the observations. Our results are important for informing previous studies using tracer approaches. For example, H2 has been used to estimate COS soil uptake, which must be accounted for to use COS as a carbon cycle tracer. Furthermore, the global distribution of H2 deposition velocity has been inferred from net primary productivity (CO2). Given that insufficient measurement frequency and spatial distribution exists to partition global net ecosystem fluxes of many climate-relevant trace gases, insight into the use of certain trace gases to estimate rates of more general biogeochemical processes is useful.

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