Development of surface coatings for air-lubricated, compliant journal bearings to 650 C

NASA Technical Reports Server (NTRS)

Bhushan, B.; Gray, S.

1978-01-01

Surface coatings for an air-lubricated, compliant journal for an automotive gas turbine engine were tested to find those capable of withstanding temperatures of either 540 C (1000 F) or 650 C (1200 F). Also, the coatings have to be capable of surviving the start-stop sliding contact cycles prior to rotor lift-off and at touchdown. Selected coating combinations were tested in start-stop tests at 14 kPa (2 psi) loading for 2000 cycles at room and maximum temperatures. Specific coating recommendations are: Cdo and graphite on foil versus chrome carbide on journal up to 370 C (700 F); NASA PS-120 (Tribaloy 400, silver, and CaF2) on journal versus uncoated foil up to 540 C (1000 F); and chemically adherent Cr2O3 on journal and foil up to 650 C (1200 F). The chemically adherent Cr2O3 coating system was further tested successfully at 35 kPa (5 psi) loading for 2000 start-stop cycles.

Tribological composition optimization of chromium-carbide-based solid lubricant coatings for foil gas bearings at temperatures to 650 C

NASA Technical Reports Server (NTRS)

Dellacorte, Christopher

1988-01-01

The determination of the tribilogically optimum composition of chromium-carbide-based solid lubricant coatings using a foil gas bearing test apparatus is described. The coatings contain a wear resistant chromium carbide `base stock' with the lubricant additives silver and BaF2-CaF2 eutectic. The coating composition is optimized for air-lubricated foil gas bearings at temperatures ranging from 25 to 650 C. The various compositions were prepared by powder blending, then plasma sprayed onto Inconel 718 test journals and diamond ground to the desired coating thickness and surface finish. The journals were operated against preoxidized Ni-Cr alloy foils, and the test bearings were subjected to repeated start-stop cycles under a bearing unit of 14 kPa. Sliding contact between the coated journal and the smooth foil occurs during bearing start-up before lift-off or hydrodynamic lubrication by the air film and during bearing coast-down. The bearings were tested for 9000 start-stop cycles or until specimen reached a predetermined failure level.

Composition optimization of chromium carbide based solid lubricant coatings for foil gas bearings at temperatures to 650 C

NASA Technical Reports Server (NTRS)

Dellacorte, Christopher

1987-01-01

A test program to determine the optimum composition of chromium carbide based solid lubricant coatings for compliant gas bearings is described. The friction and wear properties of the coatings are evaluated using a foil gas bearing test apparatus. The various coatings were prepared by powder blending, then plasma sprayed onto Inconel 718 test journals and diamond ground to the desired coating thickness and surface finish. The journals were operated against preoxidized nickel-chromium alloy foils. The test bearings were subjected to repeated start/stop cycles under a 14 kPa (2 psi) bearing unit load. The bearings were tested for 9000 start/stop cycles or until the specimen wear reached a predetermined failure level. In general, the addition of silver and eutectic to the chromium carbide base stock significantly reduced foil wear and increased journal coating wear. The optimum coating composition, PS212 (70 wt% metal bonded Cr3C2, 15 wt% Ag, 15% BaF2/CaF2 eutectic), reduced foil wear by a factor of two and displayed coating wear well within acceptable limits. The load capacity of the bearing using the plasma-sprayed coating prior to and after a run-in period was ascertained and compared to polished Inconel 718 specimens.

An experimental and theoretical study of structural damping in compliant foil bearings

NASA Technical Reports Server (NTRS)

Ku, C.-P. Roger

1994-01-01

This paper describes an experimental investigation into the dynamic characteristics of corrugated foil (bump foil) strips used in compliant surface foil bearings. This study provided and opportunity to quantify the structural damping of bump foil strips. The experimental data were compared to results obtained by a theoretical model developed earlier. The effects of bearing design parameters, such as static loads, dynamic displacement amplitudes, bump configurations, pivot locations, surface coatings, and lubricant were also evaluated. An understanding of the dynamic characteristics of bump foil strips resulting from this work offers designers a means for enhancing the design of high-performance compliant foil bearings.

Bi-metal foil gas dynamic bearings with bimorph piezoelectric foils

NASA Astrophysics Data System (ADS)

Sytin, A.; Rodichev, A.; Kulkov, A.

2017-08-01

The present paper considers application of bi-metal materials and coatings to provide necessary strength and wear resistance of the surfaces of rigid and elastic gas dynamic bearings. Authors suggest using multi-layer foils with bimorph piezoelectric elements that operate in the generator regime to determine the deformation of elastic elements, and in the actuator regime to form an optimal shape of the surface of the bearing.

Evaluation of selected thermal control coatings for long-life space structures

NASA Technical Reports Server (NTRS)

Teichman, Louis A.; Slemp, Wayne S.; Witte, William G., Jr.

1992-01-01

Graphite-reinforced resin matrix composites are being considered for spacecraft structural applications because of their light weight, high stiffness, and lower thermal expansion. Thin protective coatings with stable optical properties and the proper ratio of solar absorption (alpha sub s) to thermal emittance (epsilon) minimize orbital thermal extremes and protect these materials against space environment degradation. Sputtered coatings applied directly to graphite/epoxy composite surfaces and anodized coatings applied to thin aluminum foil were studied for use both as an atomic oxygen barrier and as thermal control coatings. Additional effort was made to develop nickel-based coatings which could be applied directly to composites. These coating systems were selected because their inherent tenacity made them potentially more reliable than commercial white paints for long-life space missions. Results indicate that anodized aluminum foil coatings are suitable for tubular and flat composite structures on large platforms in low Earth orbit. Anodized foil provides protection against some elements of the natural space environment (atomic oxygen, ultraviolet, and particulate radiation) and offers a broad range of tailored alpha sub s/epsilon. The foil is readily available and can be produced in large quantities, while the anodizing process is a routine commercial technique.

Solid Lubricants for Oil-Free Turbomachinery

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher

2005-01-01

Recent breakthroughs in gas foil bearing solid lubricants and computer based modeling has enabled the development of revolulionary Oil-Free turbomachinery systems. These innovative new and solid lubricants at low speeds (start-up and shut down). Foil bearings are hydrodynamic, self acting fluid film bearings made from thin, flexible sheet metal foils. These thin foils trap a hydrodynamic lubricating air film between their surfaces and moving shaft surface. For low temperature applications, like ainrafl air cycle machines (ACM's), polymer coatings provide important solid lubrication during start-up and shut down prior to the development of the lubricating fluid film. The successful development of Oil-Free gas turbine engines requires bearings which can operate at much higher temperatures (greater than 300 C). To address this extreme solid lubrication need, NASA has invented a new family of compostie solid lubricant coatings, NASA PS300.

Protective coatings for composite tubes in space applications

NASA Technical Reports Server (NTRS)

Dursch, Harry W.; Hendricks, Carl L.

1987-01-01

Protective coatings for graphite/epoxy (Gr/Ep) tubular structures for a manned Space Station truss structure were evaluated. The success of the composite tube truss structure depends on its stability to long-term exposure to the low earth orbit (LEO) environment, with particular emphasis placed on atomic oxygen. Concepts for protectively coating Gr/Ep tubes include use of inorganic coated metal foils and electroplating. These coatings were applied to Gr/Ep tubes and then subjected to simulated LEO environment to evaluate survivability of coatings and coated tubes. Evaluation included: atomic oxygen resistance, changes in optical properties and adhesion, abrasion resistance, surface preparation required, coating uniformity, and formation of microcracks in the Gr/Ep tubes caused by thermal cycling. Program results demonstrated that both phosphoric and chromic acid anodized Al foil provided excellent adhesion to Gr/Ep tubes and exhibited stable optical properties when subjected to simulated LEO environment. The SiO2/Al coatings sputtered onto Al foils also resulted in an excellent protective coating. Electroplated Ni exhibited unacceptable adhesion loss to Gr/Ep tubes during atomic oxygen exposure.

Protective coatings for composite tubes in space applications

NASA Technical Reports Server (NTRS)

Dursch, Harry W.; Hendricks, Carl L.

1987-01-01

Protective coatings for graphite/epoxy (Gr/Ep) tubular structures for a Manned Space Station truss structure were evaluated. The success of the composite tube truss structure depends on its stability to long-term exposure to the Low Earth Orbit (LEO) environment with particular emphasis placed on atomic oxygen. Concepts for protectively coating Gr/Ep tubes include use of inorganic coated metal foils and electroplating. These coatings were applied to Gr/Ep tubes and then subjected to simulated LEO environmnet to evaluate survivability of coatings and coated tubes. Evaluation included: atomic oxygen resistance, changes in optical properties and adhesion, abrasion resistancem surface preparation required, coating uniformity, and formation of microcracks in the Gr/Ep tubes caused by thermal cycling. Program results demonstrated that both phosphoric and chromic acid anodized Al foil provided excellent adhesion to Gr/Ep tubes and exhibited stable optical properties when subjected to simulated LEO environment. The SiO2/Al coatings speuttered onto Al foils also resulted in an excellent protective coating. Electroplated Ni exhibited unaccepatble adhesion loss to Gr/Ep tubes during atomic oxygen exposure.

A nanometric Rh overlayer on a metal foil surface as a highly efficient three-way catalyst.

PubMed

Misumi, Satoshi; Yoshida, Hiroshi; Hinokuma, Satoshi; Sato, Tetsuya; Machida, Masato

2016-07-08

Pulsed arc-plasma (AP) deposition of an Rh overlayer on an Fe-Cr-Al stainless steel foil produced a composite material that exhibited high activity for automotive three-way catalysis (TWC). The AP pulses deposited metallic Rh nanoparticles 1-3 nm in size, whose density on the surface increased with the number of pulses. This led to coalescence and grain growth on the foil surface and the eventual formation of a uniform two-dimensional Rh overlayer. Full coverage of the 51 μm-thick flat foil by a 3.2 nm-thick Rh overlayer was achieved after 1,000 pulses. A simulated TWC reaction using a miniature honeycomb fabricated using flat and corrugated foils with the Rh overlayers exhibited successful light-off at a practical gaseous hourly space velocity of 1.2 × 10(5) h(-1). The turnover frequency for the NO-CO reaction over the metallic honeycomb catalyst was ca. 80-fold greater than that achieved with a reference Rh/ZrO2-coated cordierite honeycomb prepared using a conventional wet impregnation and slurry coating procedure. Despite the nonporosity and low surface area of the foil-supported Rh overlayer compared with conventional powder catalysts (Rh/ZrO2), it is a promising alternative design for more efficient automotive catalysts that use less Rh loading.

Analytical study of graphite-epoxy tube response to thermal loads

NASA Technical Reports Server (NTRS)

Knott, Tamara W.; Hyer, M. W.

1988-01-01

The thermally-induced stresses and deformations in graphite-epoxy tubes with aluminum foil bonded to both inner and outer surfaces, and to the outer surface only are computed. Tubes fabricated from three material systems, T300/934, P75s/934, and P75s/BP907, and having a 1 inch inner radius and a lamination sequence of (+15/0 + or - 10/0)sub s are studied. Radial, axial, and circumferential stresses in the various layers of the tube, in the foil, and in the adhesive bonding the foil to the tubes are computed using an elasticity solution. The results indicate that the coatings have no detrimental effect on the stress state in the tube, particularly those stresses that lead to microcracking. The addition of the aluminum foil does, however, significantly influence the axial expansion of the T300/934 tube, the tube with the softer graphite fibers. The addition of foil can change the sign of the axial coefficient of thermal expansion. Twist tendencies of the tubes are only slightly affected by the addition of the coatings, but are of second order compared to the axial response.

Shock Wave Based Biolistic Device for DNA and Drug Delivery

NASA Astrophysics Data System (ADS)

Nakada, Mutsumi; Menezes, Viren; Kanno, Akira; Hosseini, S. Hamid R.; Takayama, Kazuyoshi

2008-03-01

A shock wave assisted biolistic (biological ballistic) device has been developed to deliver DNA/drug-coated micro-projectiles into soft living targets. The device consists of an Nd:YAG laser, an optical setup to focus the laser beam and, a thin aluminum (Al) foil (typically 100 µm thick) which is a launch pad for the micro-projectiles. The DNA/drug-coated micro-particles to be delivered are deposited on the anterior surface of the foil and the posterior surface of the foil is ablated using the laser beam with an energy density of about 32×109 W/cm2. The ablation launches a shock wave through the foil that imparts an impulse to the foil surface, due to which the deposited particles accelerate and acquire sufficient momentum to penetrate soft targets. The device has been tested for particle delivery by delivering 1 µm size tungsten particles into liver tissues of experimental rats and in vitro test models made of gelatin. The penetration depths of about 90 and 800 µm have been observed in the liver and gelatin targets, respectively. The device has been tested for in vivo DNA [encoding β-glucuronidase (GUS) gene] transfer by delivering plasmid DNA-coated, 1-µm size gold (Au) particles into onion scale, tobacco leaf and soybean seed cells. The GUS activity was detected in the onion, tobacco and soybean cells after the DNA delivery. The present device is totally non-intrusive in nature and has a potential to get miniaturized to suit the existing medical procedures for DNA and/or drug delivery.

Performance and Durability of High Temperature Foil Air Bearings for Oil-Free Turbomachinery

NASA Technical Reports Server (NTRS)

DellaCorte, C.; Lukaszewicz, V.; Valco, M. J.; Radil, K. C.; Heshmat, H.

2000-01-01

The performance and durability of advanced, high temperature foil air bearings are evaluated under a wide range (10-50 kPa) of loads at temperatures from 25 to 650 C. The bearings are made from uncoated nickel based superalloy foils. The foil surface experiences sliding contact with the shaft during initial start/stop operation. To reduce friction and wear, the solid lubricant coating, PS304, is applied to the shaft by plasma spraying. PS304 is a NiCr based Cr2O3 coating with silver and barium fluoride/calcium fluoride solid lubricant additions. The results show that the bearings provide lives well in excess of 30,000 cycles under all of the conditions tested. Several bearings exhibited lives in excess of 100,000 cycles. Wear is a linear function of the bearing load. The excellent performance measured in this study suggests that these bearings and the PS304 coating are well suited for advanced high temperature, oil-free turbomachinery applications.

75 FR 81555 - Approval and Promulgation of Air Quality Implementation Plans; Pennsylvania; Allegheny County's...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-28

... Techniques Guidelines for Large Appliance and Metal Furniture; Flat Wood Paneling; Paper, Film, and Foil... appliance and metal furniture; flat wood paneling; and paper, film, and foil surface coating processes. In... Control Techniques Guidelines for Large Appliance and Metal Furniture; Flat Wood Paneling; Paper, Film...

Hydrodynamic air lubricated compliant surface bearing for an automotive gas turbine engine. 2: Materials and coatings

NASA Technical Reports Server (NTRS)

Bhushan, B.; Ruscitto, D.; Gray, S.

1978-01-01

Material coatings for an air-lubricated, compliant journal bearing for an automotive gas turbine engine were exposed to service test temperatures of 540 C or 650 C for 300 hours, and to 10 temperature cycles from room temperatures to the service test temperatures. Selected coatings were then put on journal and partial-arc foils and tested in start-stop cycle tests at 14 kPa (2 psi) loading for 2000 cycles. Half of the test cycles were performed at a test chamber service temperature of 540 C (1000 F) or 650 C (1200 F); the other half were performed at room temperature. Based on test results, the following combinations and their service temperature limitations are recommended: HL-800 TM (CdO and graphite) on foil versus chrome carbide on journal up to 370 C (700 F); NASA PS 120 (Tribaloy 400, silver and CaF2 on journal versus uncoated foil up to 540 C (1000 F); and Kaman DES on journal and foil up to 640 C (1200 F). Kaman DES coating system was further tested successfully at 35 kPa (5 psi) loading for 2000 start-stop cycles.

Heat Treatment Used to Strengthen Enabling Coating Technology for Oil-Free Turbomachinery

NASA Technical Reports Server (NTRS)

Edmonds, Brian J.; DellaCorte, Christopher

2002-01-01

The PS304 high-temperature solid lubricant coating is a key enabling technology for Oil- Free turbomachinery propulsion and power systems. Breakthroughs in the performance of advanced foil air bearings and improvements in computer-based finite element modeling techniques are the key technologies enabling the development of Oil-Free aircraft engines being pursued by the Oil-Free Turbomachinery team at the NASA Glenn Research Center. PS304 is a plasma spray coating applied to the surface of shafts operating against foil air bearings or in any other component requiring solid lubrication at high temperatures, where conventional materials such as graphite cannot function.

Carbon-Coated Current Collectors for High-Power Lithium-Ion Secondary Batteries

DTIC Science & Technology

2011-09-20

foils have been used as the current collectors for LiFePO4 and Li4Ti5O12. It was found that the C-coating has remarkably enhance the power performance...chemical vapor deposition (T-CVD) to produce surface C-coating, and the resulting foils were used as current collectors for LiFePO4 and Li4Ti5O12. The C...2 mm x 2 mm. Two types of active electrode materials have been used for test, and they are LiFePO4 (LFPO) and Li4Ti5O12 (LTO) as cathode and anode

Tubular hydrogen permeable metal foil membrane and method of fabrication

DOEpatents

Paglieri, Stephen N.; Birdsell, Stephen A.; Barbero, Robert S.; Snow, Ronny C.; Smith, Frank M.

2006-04-04

A tubular hydrogen permeable metal membrane and fabrication process comprises obtaining a metal alloy foil having two surfaces, coating the surfaces with a metal or metal alloy catalytic layer to produce a hydrogen permeable metal membrane, sizing the membrane into a sheet with two long edges, wrapping the membrane around an elongated expandable rod with the two long edges aligned and overlapping to facilitate welding of the two together, placing the foil wrapped rod into a surrounding fixture housing with the two aligned and overlapping foil edges accessible through an elongated aperture in the surrounding fixture housing, expanding the elongated expandable rod within the surrounding fixture housing to tighten the foil about the expanded rod, welding the two long overlapping foil edges to one another generating a tubular membrane, and removing the tubular membrane from within the surrounding fixture housing and the expandable rod from with the tubular membrane.

Piezoelectric characterization of Pb(Zr,Ti)O3 thin films deposited on metal foil substrates by dip coating

NASA Astrophysics Data System (ADS)

Hida, Hirotaka; Hamamura, Tomohiro; Nishi, Takahito; Tan, Goon; Umegaki, Toshihito; Kanno, Isaku

2017-10-01

We fabricated the piezoelectric bimorphs composed of Pb(Zr,Ti)O3 (PZT) thin films on metal foil substrates. To efficiently inexpensively manufacture piezoelectric bimorphs with high flexibility, 1.2-µm-thick PZT thin films were directly deposited on both surfaces of 10- and 20-µm-thick bare stainless-steel (SS) foil substrates by dip coating with a sol-gel solution. We confirmed that the PZT thin films deposited on the SS foil substrates at 500 °C or above have polycrystalline perovskite structures and the measured relative dielectric constant and dielectric loss were 323-420 and 0.12-0.17, respectively. The PZT bimorphs were demonstrated by comparing the displacements of the cantilever specimens driven by single- and double-side PZT thin films on the SS foil substrates under the same applied voltage. We characterized the piezoelectric properties of the PZT bimorphs and the calculated their piezoelectric coefficient |e 31,f| to be 0.3-0.7 C/m2.

SR-XRD and SR-FTIR study of the alteration of silver foils in medieval paintings.

PubMed

Salvadó, Nati; Butí, Salvador; Labrador, Ana; Cinque, Gianfelice; Emerich, Hermann; Pradell, Trinitat

2011-03-01

Altarpieces and polychrome carved wood from the fifteenth century AD usually exhibit golden and silvery areas by the application of a very thin foil of metal. The metal foils were normally protected from the atmosphere by a varnish or resin which maybe either preserved or absent. Moreover, they were glued to the background surface by adhesive substances (egg yolk, drying oil or animal glue). The high proportion of the glueing substances often renders the development of reaction compounds. With time, silver alters blacken or simply disappear completely. In this paper, we study the alterations to metal foils from a selection of fifteenth century artworks showing different glueing agents, organic coatings and several degrees of conservation of the organic coatings and metal leafs. The submillimetric layered structure and the high variability and low amount of most of the compounds present in the different layers, as well as their differing nature (organic and inorganic) make the use of micron-sensitive high-resolution techniques essential for their study. In particular, the high resolution, high brilliance and small footprint renders synchrotron radiation most adequate for their study. SR-XRD was performed to identify the reaction compounds formed in the different layers; μFTIR was used at to identify the silver protecting organic coatings, the metal foil glueing layers and the corresponding reaction compounds. The results obtained suggest that atmospheric corrosion is the dominant mechanism, and therefore that the degree of corrosion of the metal foils is mainly related to the conservation state of the protecting coatings.

Effect of LID (Registered) processing on the microstructure and mechanical properties of Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo titanium foil-gauge materials

NASA Technical Reports Server (NTRS)

Balckburn, Linda B.

1987-01-01

A study was undertaken to determine the mechanical properties and microstructures resulting from Liquid Interface Diffusion (LID -Registered) processing of foil-gauge specimens of Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo coated with varying amounts of LID material. In addition, the effects of various elevated temperature exposures on the concentration profiles of the LID alloying elements were investigated, using specimens with a narrow strip of LID material applied to the surface. Room and elevated temperature tensile properties were determined for both coated and uncoated specimens. Optical microscopy was used to examine alloy microstructures, and scanning electron microscopy to examine fracture surface morphologies. The chemical concentration profiles of the strip-coated specimens were determined with an electron microprobe.

Structural Assessment of Tungsten-Epoxy Bonding in Spacecraft Composite Enclosures with Enhanced Radiation Protection

NASA Astrophysics Data System (ADS)

Kanerva, M.; Koerselman, J. R.; Revitzer, H.; Johansson, L.-S.; Sarlin, E.; Rautiainen, A.; Brander, T.; Saarela, O.

2014-06-01

Spacecraft include sensitive electronics that must be protected against radiation from the space environment. Hybrid laminates consisting of tungsten layers and carbon- fibre-reinforced epoxy composite are a potential solution for lightweight, efficient, and protective enclosure material. Here, we analysed six different surface treatments for tungsten foils in terms of the resulting surface tension components, composition, and bonding strength with epoxy. A hydrofluoric-nitric-sulfuric-acid method and a diamond-like carbon-based DIARC® coating were found the most potential surface treatments for tungsten foils in this study.

A simple method for the measurement of reflective foil emissivity

NASA Astrophysics Data System (ADS)

Ballico, M. J.; van der Ham, E. W. M.

2013-09-01

Reflective metal foil is widely used to reduce radiative heat transfer within the roof space of buildings. Such foils are typically mass-produced by vapor-deposition of a thin metallic coating onto a variety of substrates, ranging from plastic-coated reinforced paper to "bubble-wrap". Although the emissivity of such surfaces is almost negligible in the thermal infrared, typically less than 0.03, an insufficiently thick metal coating, or organic contamination of the surface, can significantly increase this value. To ensure that the quality of the installed insulation is satisfactory, Australian building code AS/NZS 4201.5:1994 requires a practical agreed method for measurement of the emissivity, and the standard ASTM-E408 is implied. Unfortunately this standard is not a "primary method" and requires the use of specified expensive apparatus and calibrated reference materials. At NMIA we have developed a simple primary technique, based on an apparatus to thermally modulate the sample and record the apparent modulation in infra-red radiance with commercially available radiation thermometers. The method achieves an absolute accuracy in the emissivity of approximately 0.004 (k=2). This paper theoretically analyses the equivalence between the thermal emissivity measured in this manner, the effective thermal emissivity in application, and the apparent emissivity measured in accordance with ASTM-E408.

A simple method for the measurement of reflective foil emissivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ballico, M. J.; Ham, E. W. M. van der

Reflective metal foil is widely used to reduce radiative heat transfer within the roof space of buildings. Such foils are typically mass-produced by vapor-deposition of a thin metallic coating onto a variety of substrates, ranging from plastic-coated reinforced paper to 'bubble-wrap'. Although the emissivity of such surfaces is almost negligible in the thermal infrared, typically less than 0.03, an insufficiently thick metal coating, or organic contamination of the surface, can significantly increase this value. To ensure that the quality of the installed insulation is satisfactory, Australian building code AS/NZS 4201.5:1994 requires a practical agreed method for measurement of the emissivity,more » and the standard ASTM-E408 is implied. Unfortunately this standard is not a 'primary method' and requires the use of specified expensive apparatus and calibrated reference materials. At NMIA we have developed a simple primary technique, based on an apparatus to thermally modulate the sample and record the apparent modulation in infra-red radiance with commercially available radiation thermometers. The method achieves an absolute accuracy in the emissivity of approximately 0.004 (k=2). This paper theoretically analyses the equivalence between the thermal emissivity measured in this manner, the effective thermal emissivity in application, and the apparent emissivity measured in accordance with ASTM-E408.« less

Characterization of films formed by the aluminizing of T91 steel

NASA Astrophysics Data System (ADS)

Sanabria Cala, J. A.; Conde Rodríguez, G. R.; Y Peña Ballesteros, D.; Laverde Cataño, D.; Quintero Rangel, L. S.

2017-12-01

The aluminizing of a T91 martensitic ferritic steel was carried out by a novel modification to the traditional technique of packed cementation, with the objective of producing a diffusion coating of aluminum in a shorter time and operating cost, from a technique that allows the reuse of powder packaging and which the coating of metal parts with complex shapes can be secured. As an aluminum source, commercial foil is used to wrap the piece to be coated, while the powder packaging contains aluminum oxide Al2O3 and an activating salt, ammonium chloride NH4Cl. During the deposition process of the coating, the NH4Cl is decomposed by reacting with foil, and thus, aluminum halides can be transferred to the metallic substrate, which deposit aluminum on the T91 steel surface while Al2O3 can be recycled for subsequent processes. The results of the diffractograms and micrographs indicated the strong influence of temperature, exposure time and ammonium chloride concentration in the formation and growth evolution of a stable coating of iron-aluminum and iron-aluminum-nickel on the T91 steel surface, which was effectively deposited at a temperature of 700°C and an exposure period of 9 hours. The coating formed on the T91 steel surface could play a protective role towards the material by acting as a physical barrier between the alloy and other corrosive species in high temperature operated systems.

Studies of PMMA sintering foils with and without coating by magnetron sputtering Pd

NASA Astrophysics Data System (ADS)

Cutroneo, M.; Mackova, A.; Torrisi, L.; Vad, K.; Csik, A.; Ando', L.; Svecova, B.

2017-09-01

Polymethylmethacrylate thin foils were prepared by using physical and chemical processes aimed at changing certain properties. The density and the optical properties were changed obtaining clear and opaque foils. DC magnetron sputtering method was used to cover the foils with thin metallic palladium layers. The high optical absorbent foils were obtained producing microstructured PMMA microbeads with and without thin metallic coatings. Rutherford Backscattering Spectroscopy, optical investigation and microscopy were employed to characterize the prepared foils useful in the field study of laser-matter interaction.

NASA PS400: A New Temperature Solid Lubricant Coating for High Temperature Wear Applications

NASA Technical Reports Server (NTRS)

DellaCorte, C.; Edmonds, B. J.

2009-01-01

A new solid lubricant coating, NASA PS400, has been developed for high temperature tribological applications. This plasma sprayed coating is a variant of the patented PS304 coating and has been formulated to provide higher density, smoother surface finish and better dimensional stability than PS304. PS400 is comprised of a nickel-molybdenum binder that provides strength, creep resistance and extreme oxidative and dimensional stability. Chromium oxide, silver and barium-calcium fluoride eutectic are added to the binder to form PS400.Tribological properties were evaluated with a pin-on-disk test rig in sliding contact to 650 C. Coating material samples were exposed to air, argon and vacuum at 760 C followed by cross section microscopic analysis to assess microstructure stability. Oil-Free microturbine engine hot section foil bearing tests were undertaken to assess PS400 s suitability for hot foil gas bearing applications. The preliminary results indicate that PS400 exhibits tribological characteristics comparable to the PS304 coating but with enhanced creep resistance and dimensional stability suitable for demanding, dynamic applications.

Conductive copper sulfide thin films on polyimide foils

NASA Astrophysics Data System (ADS)

Cardoso, J.; Gomez Daza, O.; Ixtlilco, L.; Nair, M. T. S.; Nair, P. K.

2001-02-01

Kapton polyimide is known for its high thermal stability, >400 °C. Copper sulfide thin films of 75 and 100 nm thickness were coated on DuPont Kapton HN polyimide foils of 25 µm thickness by floating them on a chemical bath containing copper complexes and thiourea. The coated foils were annealed at 150-400 °C in nitrogen, converting the coating from CuS to Cu1.8S. The sheet resistance of the annealed coatings (100 nm) is 10-50 Ω/□ and electrical conductivity, 2-10×103 Ω-1 cm- 1, which remain nearly constant even after the foils are immersed in 0.1-1 M HCl for 30-120 min. The coated polyimide has a transmittance (25-35%) peak located in the wavelength region 550-600 nm, with transmittance dropping to near zero below 450 nm and below 10% in the near-infrared spectral region. These characteristics are relevant in solar radiation control applications. The coated foils might also be used as conductive substrates for electrolytic deposition of metals and semiconductors and for optoelectronic device structures.

The Environmental Assessment and Management (TEAM) Guide: Iowa Supplement

DTIC Science & Technology

2010-02-01

limited to, paper shredding, copying, photographic activities, and blueprinting machines. This does not include incinerators. r. Laundry dryers ...exemptions from these standards may apply. (Part 63, Subpart IIII) cj. Emission standards for hazardous air pollutants: paper and other web ...coating. This standard applies to a facility that is engaged in the coating of paper , plastic film, metallic foil, and other web surfaces located at a

Commercialization of NASA PS304 Solid Lubricant Coating Enhanced by Fundamental Powder Flow Research

NASA Technical Reports Server (NTRS)

Stanford, Malcolm K.

2003-01-01

The NASA Glenn Research Center has developed a patented high-temperature solid lubricant coating, designated PS304, for reducing friction and wear in bearing systems. The material used to produce the coating is initially a blend of metallic and ceramic powders that are deposited on the bearing surface by the plasma spray process. PS304 was developed to lubricate foil air bearings in Oil-Free turbomachinery, where the moving surfaces are coated with a hydrodynamic air film except at the beginning and end of an operation cycle when the air film is not present. The coating has been successful in several applications including turbochargers, land-based turbines, and industrial drying furnace conveyor components, with current development activities directed at implementation in Oil-Free aeropropulsion engines.

Bimorph material/structure designs for high sensitivity flexible surface acoustic wave temperature sensors.

PubMed

Tao, R; Hasan, S A; Wang, H Z; Zhou, J; Luo, J T; McHale, G; Gibson, D; Canyelles-Pericas, P; Cooke, M D; Wood, D; Liu, Y; Wu, Q; Ng, W P; Franke, T; Fu, Y Q

2018-06-13

A fundamental challenge for surface acoustic wave (SAW) temperature sensors is the detection of small temperature changes on non-planar, often curved, surfaces. In this work, we present a new design methodology for SAW devices based on flexible substrate and bimorph material/structures, which can maximize the temperature coefficient of frequency (TCF). We performed finite element analysis simulations and obtained theoretical TCF values for SAW sensors made of ZnO thin films (~5 μm thick) coated aluminum (Al) foil and Al plate substrates with thicknesses varied from 1 to 1600 μm. Based on the simulation results, SAW devices with selected Al foil or plate thicknesses were fabricated. The experimentally measured TCF values were in excellent agreements with the simulation results. A normalized wavelength parameter (e.g., the ratio between wavelength and sample thickness, λ/h) was applied to successfully describe changes in the TCF values, and the TCF readings of the ZnO/Al SAW devices showed dramatic increases when the normalized wavelength λ/h was larger than 1. Using this design approach, we obtained the highest reported TCF value of -760 ppm/K for a SAW device made of ZnO thin film coated on Al foils (50 μm thick), thereby enabling low cost temperature sensor applications to be realized on flexible substrates.

Titanium conversion coatings on the aluminum foil AA 8021 used for lithium-ion battery package

NASA Astrophysics Data System (ADS)

Xia, Xu-Feng; Gu, Ying-Ying; Xu, Shi-Ai

2017-10-01

In this study, an environment-friendly titanium (Ti) conversion coating was successfully deposited on the aluminum foil AA 8021 in the solution containing hexafluorotitanic acid (H2TiF6), and its morphology, composition, growth process, hydrophilicity and corrosion resistance were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), energy dispersive spectroscopy (EDS), X-ray photoelectric spectroscopy (XPS), contact-angle measurements (CAM) and salt spray exposure. The peeling strength between the Ti treated Al foil and the modified polypropylene (PP) film (PP grafted with maleic anhydride, PP-g-MAH) (Al/PP-g-MAH) was measured by T-peeling test. The results show that the Ti conversion coating is a multi-component coating composed primarily of metal oxides (TiO2 and Al2O3) and metal fluoride (AlF3). Ti treated Al foil shows better corrosion resistance than untreated and alkali-cleaned Al foils. The peeling strength of PP-g-MAH film with Ti treated Al foils is approximately 30 times higher than that with untreated Al foils. Thus, Ti treatment is a promising approach to improve the corrosion resistance and peeling strength of aluminum/polymer composite film (Al/P) used in the lithium-ion battery package.

System and process for aluminization of metal-containing substrates

DOEpatents

Chou, Yeong-Shyung; Stevenson, Jeffry W.

2017-12-12

A system and method are detailed for aluminizing surfaces of metallic substrates, parts, and components with a protective alumina layer in-situ. Aluminum (Al) foil sandwiched between the metallic components and a refractory material when heated in an oxidizing gas under a compression load at a selected temperature forms the protective alumina coating on the surface of the metallic components. The alumina coating minimizes evaporation of volatile metals from the metallic substrates, parts, and components in assembled devices that can degrade performance during operation at high temperature.

System and process for aluminization of metal-containing substrates

DOEpatents

Chou, Yeong-Shyung; Stevenson, Jeffry W

2015-11-03

A system and method are detailed for aluminizing surfaces of metallic substrates, parts, and components with a protective alumina layer in-situ. Aluminum (Al) foil sandwiched between the metallic components and a refractory material when heated in an oxidizing gas under a compression load at a selected temperature forms the protective alumina coating on the surface of the metallic components. The alumina coating minimizes evaporation of volatile metals from the metallic substrates, parts, and components in assembled devices during operation at high temperature that can degrade performance.

Security hologram foil labels with a design facilitating authenticity testing: effects of mechanical bending of substrates with the glued on holograms

NASA Astrophysics Data System (ADS)

Aubrecht, Ivo

2015-05-01

Optimal design of security holograms or diffractive optically variable image devices (DOVIDs) that would be complex enough to deter counterfeiters from attempts of mimicking but contains features readily recognizable by laymen has been addressed by many experts. This paper tries to discuss effects of mechanical bending of a flexible substrate to visual appearance of a glued-on foil DOVID. Initially plane, the DOVID is deformed to a convex- or concave-shaped curved surface. Theoretical analyses and experimental results assume the surface to be a cylindrical segment and concern rainbow-type surface-relief holograms that are recorded piecewise in a photoresist material, coated on planar and non-planar substrates.

Metallic glass coating on metals plate by adjusted explosive welding technique

NASA Astrophysics Data System (ADS)

Liu, W. D.; Liu, K. X.; Chen, Q. Y.; Wang, J. T.; Yan, H. H.; Li, X. J.

2009-09-01

Using an adjusted explosive welding technique, an aluminum plate has been coated by a Fe-based metallic glass foil in this work. Scanning electronic micrographs reveal a defect-free metallurgical bonding between the Fe-based metallic glass foil and the aluminum plate. Experimental evidence indicates that the Fe-based metallic glass foil almost retains its amorphous state and mechanical properties after the explosive welding process. Additionally, the detailed explosive welding process has been simulated by a self-developed hydro-code and the bonding mechanism has been investigated by numerical analysis. The successful welding between the Fe-based metallic glass foil and the aluminum plate provides a new way to obtain amorphous coating on general metal substrates.

Anti-Fog Solution for Air-Purifying Respirator Lenses

DTIC Science & Technology

2010-06-01

INTRODUCTION Fogging of respirator and protective eyewear lenses occurs when water vapor condenses on the surface of the lens. Topical coatings, such as... safety goggles and six full-facepiece APRs to create 12 Snellen visual acuity conditions. The foils were calibrated during prior unpublished human

MULPEX: A compact multi-layered polymer foil collector for micrometeoroids and orbital debris

NASA Astrophysics Data System (ADS)

Kearsley, A. T.; Graham, G. A.; Burchell, M. J.; Taylor, E. A.; Drolshagen, G.; Chater, R. J.; McPhail, D.

Detailed studies of preserved hypervelocity impact residues on spacecraft multi-layer insulation foils have yielded important information about the flux of small particles from different sources in low-Earth orbit (LEO). We have extended our earlier research on impacts occurring in LEO to design and testing of a compact capture device. MUlti- Layer Polymer EXperiment (MULPEX) is simple, cheap to build, lightweight, of no power demand, easy to deploy, and optimised for the efficient collection of impact residue for analysis on return to Earth. The capture medium is a stack of very thin (8 and 40 μm) polyimide foils, supported on poly-tetrafluoroethylene sheet frames, surrounded by a protective aluminium casing. The uppermost foil has a very thin metallic coating for thermal protection and resistance to atomic oxygen and ultra-violet exposure. The casing provides a simple detachable interface for deployment on the spacecraft, facing into the desired direction for particle collection. On return to the laboratory, the stacked foils are separated for examination in a variable pressure scanning electron microscope, without need for surface coating. Analysis of impact residue is performed using energy dispersive X-ray spectrometers. Our laboratory experiments, utilising buck-shot firings of analogues to micrometeoroids (35-38 μm olivine) and space debris (4 μm alumina and 1 mm stainless steel) in a light gas gun, have shown that impact residue is abundant within the foil layers, and preserves a record of the impacting particle, whether of micrometer or millimetre dimensions. Penetrations of the top foil are easily recognised, and act as a proxy for dimensions of the penetrating particle. Impact may cause disruption and melting, but some residue retains sufficient crystallographic structure to show clear Raman lines, diagnostic of the original mineral.

MULPEX: a compact multi-layered polymer foil collector for micrometeoroids and orbital debris.

NASA Astrophysics Data System (ADS)

Kearsley, A. T.; Graham, G. A.; Burchell, M. J.; Taylor, E. A.; Drolshagen, G.; Chater, R. J.; McPhail, D.

Detailed studies of preserved hypervelocity impact residues on spacecraft multi-layer insulation foils have yielded important information about the flux of small particles from different sources in low-Earth orbit (LEO). We have extended our earlier research on impacts occurring in LEO to design and testing of a compact capture device. MULPEX (MUlti-Layer Polymer EXperiment) is simple, cheap to build, lightweight, of no power demand, easy to deploy, and optimised for the efficient collection of impact residue for analysis on return to Earth. The capture medium is a stack of very thin (8 micron and 40 micron) polyimide foils, supported on poly-tetrafluoroethylene sheet frames, surrounded by a protective aluminium casing. The uppermost foil has a very thin metallic coating for thermal protection and resistance to atomic oxygen and ultra-violet exposure. The casing provides a simple detachable interface for deployment on the spacecraft, facing into the desired direction for particle collection. On return to the laboratory, the stacked foils are separated for examination in a variable pressure scanning electron microscope, without need for surface coating. Analysis of impact residue is performed using energy dispersive X-ray spectrometers. Our laboratory experiments, utilising buck-shot firings of analogues to micrometeoroids (35-38 micron olivine) and space debris (4 micron alumina and 1mm stainless steel) in a light gas gun, have shown that impact residue is abundant within the foil layers, and preserves a record of the impacting particle, whether of micrometer or millimetre dimensions. Penetrations of the top foil are easily recognised, and act as a proxy for dimensions of the penetrating particle. Impact may cause disruption and melting, but some residue retains sufficient crystallographic structure to show clear Raman lines, diagnostic of the original mineral.

Studies into the transfer and migration of phthalate esters from aluminium foil-paper laminates to butter and margarine.

PubMed

Page, B D; Lacroix, G M

1992-01-01

Retail samples of Canadian butter and margarine wrapped in aluminium foil-paper laminate were found to contain dibutyl, butyl benzyl and/or di-2-ethylhexyl phthalate (DBP, BBP, DEHP) as packaging migrants at levels up to 10.6, 47.8 and 11.9 micrograms/g, respectively. These phthalates were determined by capillary gas chromatography with flame ionization detection (GC-FID) after clean-up of the separated oil by sweep co-distillation. The phthalate esters found in the contacted butter or margarine were also found in the contacting wrappers. They were determined in wrapper extracts by liquid chromatography with diode array detection or by GC-FID. Analysis of unused wrappers showed 76-88% of the total DBP and DEHP to be present on the foil (outer) surface as a component of the protective coating (washcoat). The remainder of the DBP and DEHP was found on the food-contacting paper surface, presumably by transfer from the outer to inner surface during storage in tightly wound rolls, although transfer of phthalate esters, if present in the paper-foil adhesive, cannot be ruled out. Food-contacting surface concentrations of DBP and DEHP were found to be 2.4 to 4.7 and 2.8 to 3.6 micrograms/cm2, respectively. Samples of each packaging component: paper, foil, adhesive, washcoat and inks were analysed for phthalate esters and only the washcoat was found to contain phthalate esters.

High-Temperature Solid Lubricants Developed by NASA Lewis Offer Virtually "Unlimited Life" for Oil-Free Turbomachinery

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher; Valco, Mark J.

1999-01-01

The NASA Lewis Research Center is capitalizing on breakthroughs in foil air bearing performance, tribological coatings, and computer analyses to formulate the Oil-free Turbomachinery Program. The program s long-term goal is to develop an innovative, yet practical, oil-free aeropropulsion gas turbine engine that floats on advanced air bearings. This type of engine would operate at higher speeds and temperatures with lower weight and friction than conventional oil-lubricated engines. During startup and shutdown, solid lubricant coatings are required to prevent wear in such engines before the self-generating air-lubrication film develops. NASA s Tribology Branch has created PS304, a chrome-oxide-based plasma spray coating specifically tailored for shafts run against foil bearings. PS304 contains silver and barium fluoride/calcium fluoride eutectic (BaF2/CaF2) lubricant additives that, together, provide lubrication from cold start temperatures to over 650 C, the maximum use temperature for foil bearings. Recent lab tests show that bearings lubricated with PS304 survive over 100 000 start-stop cycles without experiencing any degradation in performance due to wear. The accompanying photograph shows a test bearing after it was run at 650 C. The rubbing process created a "polished" surface that enhances bearing load capacity.

Development of RF sputtered chromium oxide coating for wear application

NASA Technical Reports Server (NTRS)

Bhushan, B.

1979-01-01

The radio frequency sputtering technique was used to deposite a hard refractory, chromium oxide coating on an Inconel X-750 foil 0.1 mm thick. Optimized sputtering parameters for a smooth and adherent coating were found to be as follows: target-to-substrate spacing, 41.3 mm; argon pressure, 5-10 mTorr; total power to the sputtering module, 400 W (voltage at the target, 1600 V), and a water-cooled substrate. The coating on the annealed foil was more adherent than that on the heat-treated foil. Substrate biasing during the sputter deposition of Cr2O3 adversely affected adherence by removing naturally occurring interfacial oxide layers. The deposited coatings were amorphous and oxygen deficient. Since amorphous materials are extremely hard, the structure was considered to be desirable.

Chromic acid anodizing of aluminum foil

NASA Technical Reports Server (NTRS)

Dursch, H.

1988-01-01

The success of the Space Station graphite/epoxy truss structure depends on its ability to endure long-term exposure to the LEO environment, primarily the effects of atomic oxygen and the temperture cycling resulting from the 94 minute orbit. This report describes the development and evaluation of chromic acid anodized (CAA) aluminum foil as protective coatings for these composite tubes. Included are: development of solar absorptance and thermal emittance properties required of Al foil and development of CAA parameters to achieve these optical properties; developing techniques to CAA 25 ft lengths of Al foil; developing bonding processes for wrapping the Al foil to graphite/epoxy tubes; and atomic oxygen testing of the CAA Al foil. Two specifications were developed and are included in the report: Chromic Acid Anodizing of Aluminum Foil Process Specification and Bonding of Anodized Aluminum Foil to Graphite/Epoxy Tubes. Results show that CAA Al foil provides and excellent protective and thermal control coating for the Space Station truss structure.

Experimental test program for evaluation of solid lubricant coating as applied to compliant foil gas bearings to 315 deg C

NASA Technical Reports Server (NTRS)

Wagner, R. C.

1985-01-01

An experimental apparatus and test procedure was developed to compare the performance of two solid lubricant coatings for air lubricated compliant foil gas bearings in the temperature range of 25 to 315 C. Polyimide bonded additive (SBGC) were tested extensively for durability and frictional characteristics. A partial arc bearing constructed of Inconel X-750 was coated on the bore with one of these coatings. The foil was subjected to repeated start/stop cycles. Performance comparisons reveal that although both coatings survive thousands of start/stop cycles, only the PBGF coated bearing achieves the specified 9000 start/stops. There is enough wear on the SBGC coated bearing to warrant termination of the test prior to 9000 start/stop cycles due to coating failure. The frictional characteristics of the PBGF are better at the elevated temperatures than at lower temperatures; a marked increase in sliding friction occurs as the temperature decreases. The SBGC maintains relatively constant frictional characteristics independent of operating temperature.

77 FR 15329 - Approval and Promulgation of Air Quality Implementation Plans; Maine; Reasonably Available...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-15

... Guideline for Paper, Film, and Foil Coatings; September 2007, EPA-453/R-07-003). Also, because the revised... Coating of Cans, Paper, and Fabrics (May 1977, EPA-450/2-77-008). CMR Chapter 123, Paper 57 FR 3946... and the Paper, Film, Foil Coating CTG (which were due October 9, 2008) nor the Lithographic Printing...

Magnet-induced temporary superhydrophobic coatings from one-pot synthesized hydrophobic magnetic nanoparticles.

PubMed

Fang, Jian; Wang, Hongxia; Xue, Yuhua; Wang, Xungai; Lin, Tong

2010-05-01

In this paper, we report on the production of superhydrophobic coatings on various substrates (e.g., glass slide, silicon wafer, aluminum foil, plastic film, nanofiber mat, textile fabrics) using hydrophobic magnetic nanoparticles and a magnet-assembly technique. Fe(3)O(4) magnetic nanoparticles functionalized with a thin layer of fluoroalkyl silica on the surface were synthesized by one-step coprecipitation of Fe(2+)/Fe(3+) under an alkaline condition in the presence of a fluorinated alkyl silane. Under a magnetic field, the magnetic nanoparticles can be easily deposited on any solid substrate to form a thin superhydrophobic coating with water contact angle as high as 172 degrees , and the surface superhydrophobicity showed very little dependence on the substrate type. The particulate coating showed reasonable durability because of strong aggregation effect of nanoparticles, but the coating layer can be removed (e.g., by ultrasonication) to restore the original surface feature of the substrates. By comparison, the thin particle layer deposited under no magnetic field showed much lower hydrophobicity. The main reason for magnet-induced superhydrophobic surfaces is the formation of nano- and microstructured surface features. Such a magnet-induced temporary superhydrophobic coating may have wide applications in electronic, biomedical, and defense-related areas.

Shock wave driven microparticles for pharmaceutical applications

NASA Astrophysics Data System (ADS)

Menezes, V.; Takayama, K.; Gojani, A.; Hosseini, S. H. R.

2008-10-01

Ablation created by a Q-switched Nd:Yttrium Aluminum Garnet (Nd:YAG) laser beam focusing on a thin aluminum foil surface spontaneously generates a shock wave that propagates through the foil and deforms it at a high speed. This high-speed foil deformation can project dry micro- particles deposited on the anterior surface of the foil at high speeds such that the particles have sufficient momentum to penetrate soft targets. We used this method of particle acceleration to develop a drug delivery device to deliver DNA/drug coated microparticles into soft human-body targets for pharmaceutical applications. The device physics has been studied by observing the process of particle acceleration using a high-speed video camera in a shadowgraph system. Though the initial rate of foil deformation is over 5 km/s, the observed particle velocities are in the range of 900-400 m/s over a distance of 1.5-10 mm from the launch pad. The device has been tested by delivering microparticles into liver tissues of experimental rats and artificial soft human-body targets, modeled using gelatin. The penetration depths observed in the experimental targets are quite encouraging to develop a future clinical therapeutic device for treatments such as gene therapy, treatment of cancer and tumor cells, epidermal and mucosal immunizations etc.

Development of composite tube protective coatings

NASA Technical Reports Server (NTRS)

Dursch, H.; Hendricks, C.

1986-01-01

Protective coatings for graphite/epoxy (Gr/Ep) tubular structures proposed for the Space Station are evaluated. The program was divided into four parts; System Definition, Coating Concept Selection and Evaluation, Scale-up and Assembly, and Reporting. System Definition involved defining the structural and environmental properties required of the Gr/Ep tubes. The prepreg and ply sequence selected was a P75S/934 (O2, + or - 20, O2)sub s layup which meets the various structural requirements of the Space Station. Coating Concept and Selection comprised the main emphasis of the effort. Concepts for protectively coating the Gr/Ep tubes included the use of metal foil and electroplating. The program results demonstrated that both phosphoric and chromic acid anodized Al foil provided adequate adhesion to the Gr/Ep tubes and stability of optical properties when subjected to atomic oxygen and thermal cycling representative of the LEO environment. SiO2/Al coatings sputtered onto Al foils also resulted in an excellent protective coating. The electroplated Ni possessed unacceptable adhesion loss to the Gr/Ep tubes during atomic oxygen testing. Scale-Up and Assembly involved fabricating and wrapping 8-ft-long by 2-in-diameter Gr/EP tubes with chromic acid anodized foil and delivering these tubes, along with representative Space Station erectable end fittings, to NASA LaRC.

Sputtering of sub-micrometer aluminum layers as compact, high-performance, light-weight current collector for supercapacitors

NASA Astrophysics Data System (ADS)

Busom, J.; Schreiber, A.; Tolosa, A.; Jäckel, N.; Grobelsek, I.; Peter, N. J.; Presser, V.

2016-10-01

Supercapacitors are devices for rapid and efficient electrochemical energy storage and commonly employ carbon coated aluminum foil as the current collector. However, the thickness of the metallic foil and the corresponding added mass lower the specific and volumetric performance on a device level. A promising approach to drastically reduce the mass and volume of the current collector is to directly sputter aluminum on the freestanding electrode instead of adding a metal foil. Our work explores the limitations and performance perspectives of direct sputter coating of aluminum onto carbon film electrodes. The tight and interdigitated interface between the metallic film and the carbon electrode enables high power handling, exceeding the performance and stability of a state-of-the-art carbon coated aluminum foil current collector. In particular, we find an enhancement of 300% in specific power and 186% in specific energy when comparing aluminum sputter coated electrodes with conventional electrodes with Al current collectors.

Properties of Lightning Strike Protection Coatings

NASA Astrophysics Data System (ADS)

Gagne, Martin

Composite materials are being increasingly used by many industries. In the case of aerospace companies, those materials are installed on their aircraft to save weight, and thus, fuel costs. These aircraft are lighter, but the loss of electrical conductivity makes aircraft vulnerable to lightning strikes, which hit commercial aircrafts on average once per year. This makes lightning strike protection very important, and while current metallic expanded copper foils offer good protection, they increase the weight of composites. Therefore, under the CRIAQ COMP-502 project, a team of industrial partners and academic researchers are investigating new conductive coatings with the following characteristics: High electromagnetic protection, high mechanical resistance, good environmental protection, manufacturability and moderate cost. The main objectives of this thesis, as part of this project, was to determine the main characteristics, such as electrical and tribomechanical properties, of conductive coatings on composite panels. Their properties were also to be tested after destructive tests such as current injection and environmental testing. Bombardier Aerospace provided the substrate, a composite of carbon fiber reinforced epoxy matrix, and the current commercial product, a surfacing film that includes an expanded copper foil used to compare with the other coatings. The conductive coatings fabricated by the students are: silver nanoparticles inside a binding matrix (PEDOT:PSS or a mix of Epoxy and PEDOT:PSS), silvered carbon nanofibers embedded in the surfacing film, cold sprayed tin, graphene oxide functionalized with silver nanowires, and electroless plated silver. Additionally as part of the project and thesis, magnetron sputtered aluminum coated samples were fabricated. There are three main types of tests to characterize the conductive coatings: electrical, mechanical and environmental. Electrical tests consist of finding the sheet resistance and specific resistivity of conductive coatings. Mechanical tests include adhesion, scratch, hardness and Young's modulus of the coatings. The environmental tests are temperature cycling and salt spray cycling. These basic characteristics were investigated first, but further tests also combine the categories, such as electrical tests before, during and after environmental tests, and the effects on the sample's mechanical properties after high electrical current injections. The electrical properties of the conductive coatings have improved and are very close to that of current expanded metallic foil or within an order of magnitude. The mechanical properties of most of these coatings are also good. They exhibit good adhesion, hardness, and no significant loss of flexion properties after current injections. The environmental tests are more mitigated, with some conductive coatings losing their surface conductivity, others having a small increase in specific resistivity, and some were simply unaffected. Tests such as thermogravimetric analysis, scanning electron microscope analysis of scratch tests, and optical microscope observations are included to provide additional analysis of the results of the conductive coatings. The conductive coatings were characterized and tested as part of the CRIAQ project. Lightning strike tests are required to gather further information on these conductive coatings. The main application for these coatings is for lightning strike protection of aircraft, but they can also be used for ground based lightning strike protection and general electromagnetic shielding.

Battery plate containing filler with conductive coating

NASA Technical Reports Server (NTRS)

Rowlette, John J. (Inventor)

1986-01-01

The plate (10) comprises a matrix or binder resin phase (12) in which is dispersed particulate, conductive tin oxide such as tin oxide coated glass fibers (14). A monopolar plate (11) is prepared by coating a layer (18) of electrolytically active material onto a surface of the plate (10). Tin oxide is prevented from reduction by coating a surface of the plate (10) with a conductive, impervious layer resistant to reduction such as a thin film (22) of lead adhered to the plate with a layer (21) of conductive adhesive. The plate (10) can be formed by casting a molten dispersion from mixer (36) onto a sheet (30) of lead foil or by passing an assembly of a sheet (41) of resin, a sheet (43) of fiberglass and a sheet (45) of lead between the nip of heated rollers (48, 50).

Battery plate containing filler with conductive coating

NASA Technical Reports Server (NTRS)

Rowlette, John J. (Inventor)

1985-01-01

The plate (10) comprises a matrix or binder resin phase (12) in which is dispersed particulate, conductive tin oxide such as tin oxide coated glass fibers (14). A monopolar plate (11) is prepared by coating a layer (18) of electrolytically active material onto a surface of the plate (10). Tin oxide is prevented from reduction by coating a surface of the plate (10) with a conductive, impervious layer resistant to reduction such as a thin film (22) of lead adhered to the plate with a layer (21) of conductive adhesive. The plate (10) can be formed by casting a molten dispersion from mixer (36) onto a sheet (30) of lead foil or by passing an assembly of a sheet (41) of resin, a sheet (43) of fiberglass and a sheet (45) of lead between the nip of heated rollers (48, 50).

Large-area thin self-supporting carbon foils with MgO coatings

NASA Astrophysics Data System (ADS)

Stolarz, Anna; Maier-Komor, Peter

2002-03-01

Large area self-supporting carbon foils in the thickness of range of 8-22 μg/cm 2, coated with approximately 4 μg/cm 2 MgO have been prepared by e-gun evaporation. They were mounted on frames with apertures of 130 cm 2. Problems related to the parting agent preparation, floating procedure, and mounting onto frames are discussed. Special precautions necessary to avoid damage during foil drying, storage and transportation are suggested.

Direct synthesis of carbon nanotubes using Cu-Sn catalyst on Cu substrates and their corrosion behavior in 0.6 M NaCl solution

NASA Astrophysics Data System (ADS)

Jeong, Namjo; Jwa, Eunjin; Kim, Chansoo; Choi, Ji Yeon; Nam, Joo-youn; Park, Soon-chul; Jang, Moon-seok

2017-11-01

We report the high-yield and large-area synthesis of a spaghetti-like carbon nanotubes (CNTs) on macroscopic Cu substrates (foil and foam) using a Cu-Sn alloy catalyst. In addition, we investigate the corrosion properties of the as-synthesized CNT/Cu foil system in 0.6 M NaCl solution. Electrochemical analysis showed that the corrosion resistance of the CNT/Cu foil system improved by a factor of ∼100 compared to the as-received Cu foil. Thus, it is concluded that a dense network of CNT was uniformly coated on the Cu foil and this coating functioned as an efficient barrier to corrosion under simulated seawater conditions.

Electroform replication of smooth mirrors from sapphire masters

NASA Technical Reports Server (NTRS)

Altkorn, R.; Chang, J.; Haidle, R.; Takacs, P. Z.; Ulmer, M. P.

1992-01-01

A sapphire master was used to produce mirrors that exhibit mid-to-high-frequency roughness as low as 3 A. The fabrication procedure and potential applications in X-ray astronomy are discussed. It is shown that foils replicated from flat smooth mandrels should offer at least equivalent HF roughness and significantly lower mid-frequency ripple than those coated with lacquer. A ceramic-surface mandrel could also be expected to last far longer without the need for repolishing than electroless nickel-coated mandrels.

75 FR 59084 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Control Technique...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-27

... Promulgation of Air Quality Implementation Plans; Maryland; Control Technique Guidelines for Paper, Film, and... from paper, film, and foil coatings. Specifically, Maryland is amending its regulations by adopting the requirements of EPA's Control Technique Guidelines (CTG) for Paper, Film, and Foil Coatings. These amendments...

High temperature self-lubricating coatings for air lubricated foil bearings for the automotive gas turbine engine

NASA Technical Reports Server (NTRS)

Bhushan, B.

1980-01-01

coating combinations were developed for compliant surface bearings and journals to be used in an automotive gas turbine engine. The coatings were able to withstand the sliding start/stops during rotor liftoff and touchdown and occasional short time, high speed rubs under representative loading of the engine. Some dozen coating variations of CdO-graphite, Cr2O3 (by sputtering) and CaF2 (plasma sprayed) were identified. The coatings were optimized and they were examined for stoichiometry, metallurgical condition, and adhesion. Sputtered Cr2O3 was most adherent when optimum parameters were used and it was applied on an annealed (soft) substrate. Metallic binders and interlayers were used to improve the ductility and the adherence.

Catalytic activity and stability of nanometic Rh overlayers prepared by pulsed arc-plasma deposition and r.f. magnetron-sputtering

NASA Astrophysics Data System (ADS)

Misumi, Satoshi; Matsumoto, Akinori; Yoshida, Hiroshi; Sato, Tetsuya; Machida, Masato

2018-01-01

50 μm-thick Fe-Cr-Al metal foils covered by 7 nm-thick Rh overlayers were prepared by pulsed arc-plasma (AP) and r.f. magnetron sputtering technique to compare their catalytic activities. As-prepared metal foil catalysts were wrapped into a honeycomb structure with a density of 900 cells per square inches and the stoichiometric NO-CO-C3H6-O2 reaction was performed at space velocity of 1.2 × 105 h-1. During temperature ramp at 10 °C min-1, honeycomb catalysts showed steep light-off of NO, CO, and C3H6 at above 200 °C and their conversions soon reached to almost 100%. Both catalysts exhibited high turnover frequencies close to or more than 50-fold greater compared with those for a reference Rh/ZrO2 powder-coated cordierite honeycomb prepared using a conventional slurry coating. When the temperature ramping was repeated, however, the catalytic activity was decreased to the different extent depending on the preparation procedure. Significant deactivation occurred only when prepared by sputtering, whereas the sample prepared by AP showed no signs of deactivation. The deactivation is associated with the formation of passivation layers consisting of Fe, Cr, and Al oxides, which covered the surface and decreased the surface concentration of Rh. The Rh overlayer formed by AP was found to be thermally stable because of the strong adhesion to the metal foil surface, compared to the sample prepared by sputtering.

Transferable and flexible thin film devices for engineering applications

NASA Astrophysics Data System (ADS)

Mutyala, Madhu Santosh K.; Zhou, Jingzhou; Li, Xiaochun

2014-05-01

Thin film devices can be of significance for manufacturing, energy conversion systems, solid state electronics, wireless applications, etc. However, these thin film sensors/devices are normally fabricated on rigid silicon substrates, thus neither flexible nor transferrable for engineering applications. This paper reports an innovative approach to transfer polyimide (PI) embedded thin film devices, which were fabricated on glass, to thin metal foils. Thin film thermocouples (TFTCs) were fabricated on a thin PI film, which was spin coated and cured on a glass substrate. Another layer of PI film was then spin coated again on TFTC/PI and cured to obtain the embedded TFTCs. Assisted by oxygen plasma surface coarsening of the PI film on the glass substrate, the PI embedded TFTC was successfully transferred from the glass substrate to a flexible copper foil. To demonstrate the functionality of the flexible embedded thin film sensors, they were transferred to the sonotrode tip of an ultrasonic metal welding machine for in situ process monitoring. The dynamic temperatures near the sonotrode tip were effectively measured under various ultrasonic vibration amplitudes. This technique of transferring polymer embedded electronic devices onto metal foils yield great potentials for numerous engineering applications.

Changes in oxidation state of chromium during LDEF exposure

NASA Technical Reports Server (NTRS)

Golden, Johnny L.

1992-01-01

The solar collector used for the McDonnell-Douglas Cascade Variable Heat Pipe, Experiment A0076 (Michael Grote - Principal Investigator) was finished with black chromium plating as a thermal control coating. The coating is metallic for low emittance, and is finely microcrystalline to a dimension which yields its high absorptivity. An underplate of nickel was applied to the aluminum absorber plate in order to achieve optimal absorptance characteristics from the black chromium plate surface. Experiment A0076 was located at tray position F9, receiving a projected 8.7 x 10 exp 21 atomic oxygen atoms/sq cm and 11,200 ESH solar radiation. During retrieval, it was observed that the aluminized kapton thermal blankets covering most of the tray were severely eroded by atomic oxygen, and that a 'flap' of aluminum foil was overlaying a roughly triangular shaped portion of the absorber panel. The aluminum foil 'flap' was lost sometime between the Long Duration Exposure Facility (LDEF) retrieval and deintegration. At deintegration, the black chromium was observed to have discolored where it had been covered by the foil 'flap'. A summary of the investigation into the cause of the discoloration is presented.

Protective coating for ceramic materials

NASA Technical Reports Server (NTRS)

Kourtides, Demetrius A. (Inventor); Churchward, Rex A. (Inventor); Lowe, David M. (Inventor)

1994-01-01

A protective coating for ceramic materials such as those made of silicon carbide, aluminum oxide, zirconium oxide, aluminoborosilicate and silicon dioxide, and a thermal control structure comprising a ceramic material having coated thereon the protective coating. The protective coating contains, in admixture, silicon dioxide powder, colloidal silicon dioxide, water, and one or more emittance agents selected from silicon tetraboride, silicon hexaboride, silicon carbide, molybdenum disilicide, tungsten disilicide and zirconium diboride. In another aspect, the protective coating is coated on a flexible ceramic fabric which is the outer cover of a composite insulation. In yet another aspect, a metallic foil is bonded to the outer surface of a ceramic fabric outer cover of a composite insulation via the protective coating. A primary application of this invention is as a protective coating for ceramic materials used in a heat shield for space vehicles subjected to very high aero-convective heating environments.

Mini-BRU/BIPS foil bearing development

NASA Technical Reports Server (NTRS)

Dobler, F. X.; Miller, L. J.

1978-01-01

The analysis revealed the failure agent to be a combination of poor teflon coating adhesion, a decrease in bearing sway space and, possibly, lack of flushing flow through the bearing. A change in Teflon coating vendors provided substantially improved coating quality and surface finish. The sway space was increased and the cooling bleed flow was adjusted to flush the bearing. These changes were included in a test conducted in the WHL from 6 April to 22 May 1978 which resulted in the completion of 1006.9 hours of operation at temperature and load. Post-test inspection revealed the bearings to be in excellent condition and capable of completing a much longer test.

Dependence of Pentacene Crystal Growth on Dielectric Roughness for Fabrication of Flexible Field-Effect Transistors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, H.; Yang, C; Kim, S

2010-01-01

The dependence of pentacene nanostructures on gate dielectric surfaces were investigated for flexible organic field-effect transistor (OFET) applications. Two bilayer types of polymer/aluminum oxide (Al{sub 2}O{sub 3}) gate dielectrics were fabricated on commercial Al foils laminated onto a polymer back plate. Some Al foils were directly used as gate electrodes, and others were smoothly polished by an electrolytic etching. These Al surfaces were then anodized and coated with poly({alpha}-methyl styrene) (PAMS). For PAMS/Al{sub 2}O{sub 3} dielectrics onto etched Al foils, surface roughness up to 1 nm could be reached, although isolated dimples with a lateral diameter of several micrometers weremore » still present. On PAMS/Al{sub 2}O{sub 3} dielectrics (surface roughness >40 nm) containing mechanical grooves of Al foil, average hole mobility ({mu}FET) of 50 nm thick pentacene-FETs under the low operating voltages (|V| < 6 V) was {approx}0.15 cm{sup 2} V{sup -1} s{sup -1}. In contrast, pentacene-FETs employing the etched Al gates exhibited {mu}FET of 0.39 cm{sup 2} V{sup -1} s{sup -1}, which was comparable to that of reference samples with PAMS/Al{sub 2}O{sub 3} dielectrics onto flat sputtered Al gates. Conducting-probe atomic force microscopy and two-dimensional X-ray diffraction of pentacene films with various thicknesses revealed different out-of-plane and in-plane crystal orderings of pentacene, depending on the surface roughness of the gate dielectrics.« less

Direct Printing of Graphene onto Plastic Substrates.

NASA Astrophysics Data System (ADS)

Hines, Daniel; Lock, Evgeniya; Walton, Scott; Baraket, Mira; Laskoski, Matthew; Mulvaney, Shawn; Sheehan, Paul; Lee, Woo; Robinson, Jeremy

2011-03-01

Graphene films have been synthesized on metal foils using CVD growth and have the potential to be compatible with roll-to-roll printing. To be usable in electronic devices, these films need to be removed from the metallic substrate. Currently this is accomplished by spin coating a polymer film over the graphene and chemically etching away the metal substrate. We have developed a direct printing method that allows graphene films to be printed off the metal substrate onto a polymer substrate. This printing process does not generate chemical waste, is compatible with roll-to-toll processing and renders the metal foil reusable. Adhesion of the graphene film to the polymer substrate is established by attaching perfluorophenylazides (PFPA) azide linker molecules to a plasma activated polymer surface. The transfer printing was performed by placing the PFPA treated polymer surface in contact with a graphene covered Cu foil and heating under pressure. Graphene films successfully printed onto a polystyrene substrate have been characterized by Raman spectroscopy and electrical measurements revealed the presence of Gr on the polymer surface. Details of the printing process along with characteristics of the graphene film after printing will be presented.

The Evaluation of a Modified Chrome Oxide Based High Temperature Solid Lubricant Coating for Foil Gas Bearings

NASA Technical Reports Server (NTRS)

DellaCorte, Chris

1998-01-01

This paper describes the friction and wear performance of PS304, a modified chrome oxide based coating, for foil gas bearings. PS304 contains 60 wt% NiCr binder, 20 wt% Cr2O3 hardener, and 10 wt% each Ag, and BaF2/CaF2 lubricants. For evaluation, the coating is plasma spray deposited onto test journals which are slid against a superalloy partial arc foil bearing. The test load was 10 KPa (1.5 psi) and the bearings were run under start/stop cyclic conditions. The data show good wear performance of the bearing, especially at temperatures above 25 deg. C. Bearing friction was moderate (micron approx. or equal to 0.4) over the entire temperature range. Based upon the results obtained, the PS304 coating has promise for high temperature, oil-free turbomachinery applications.

Vacuum brazing of electroless Ni-P alloy-coated SiCp/Al composites using aluminum-based filler metal foil

NASA Astrophysics Data System (ADS)

Wang, Peng; Xu, Dongxia; Niu, Jitai

2016-12-01

Using rapidly cooled (Al-10Si-20Cu-0.05Ce)-1Ti (wt%) foil as filler metal, the research obtained high-performance joints of electroless Ni-P alloy-coated aluminum matrix composites with high SiC particle content (60 vol%, SiCp/Al-MMCs). The effect of brazing process on joint properties and the formation of Al-Ni and Al-Cu-Ni intermetallic compounds were investigated, respectively. Due to the presence of Ni-P alloy coating, the wettability of liquid filler metal on the composites was improved obviously and its contact angle was only 21°. The formation of Al3Ni2 and Al3(CuNi)2 intermetallic compounds indicated that well metallurgical bonding occurred along the 6063Al matrix alloy/Ni-P alloy layer/filler metal foil interfaces by mutual diffusion and dissolution. And the joint shear strength increased with increasing the brazing temperature from 838 to 843 K or prolonging the soaking time from 15 to 35 min, while it decreased a lot because of corrosion occurring in the 6063Al matrix at high brazing temperature of 848 K. Sound joints with maximum shear strength of 112.5 MPa were obtained at 843 K for soaking time of 35 min. In this research, the beneficial effect of surface metallization by Ni-P alloy deposits on improving wettability on SiCp/Al-MMCs was demonstrated, and capable welding parameters were broadened as well.

Adhesive bonding and brazing of nanocrystalline diamond foil onto different substrate materials

NASA Astrophysics Data System (ADS)

Lodes, Matthias A.; Sailer, Stefan; Rosiwal, Stefan M.; Singer, Robert F.

2013-10-01

Diamond coatings are used in heavily stressed industrial applications to reduce friction and wear. Hot-filament chemical vapour deposition (HFCVD) is the favourable coating method, as it allows a coating of large surface areas with high homogeneity. Due to the high temperatures occurring in this CVD-process, the selection of substrate materials is limited. With the desire to coat light materials, steels and polymers a new approach has been developed. First, by using temperature-stable templates in the HFCVD and stripping off the diamond layer afterwards, a flexible, up to 150 μm thick and free standing nanocrystalline diamond foil (NCDF) can be produced. Afterwards, these NCDF can be applied on technical components through bonding and brazing, allowing any material as substrate. This two-step process offers the possibility to join a diamond layer on any desired surface. With a modified scratch test and Rockwell indentation testing the adhesion strength of NCDF on aluminium and steel is analysed. The results show that sufficient adhesion strength is reached both on steel and aluminium. The thermal stress in the substrates is very low and if failure occurs, cracks grow undercritically. Adhesion strength is even higher for the brazed samples, but here crack growth is critical, delaminating the diamond layer to some extent. In comparison to a sample directly coated with diamond, using a high-temperature CVD interlayer, the brazed as well as the adhesively bonded samples show very good performance, proving their competitiveness. A high support of the bonding layer could be identified as crucial, though in some cases a lower stiffness of the latter might be acceptable considering the possibility to completely avoid thermal stresses which occur during joining at higher temperatures.

Vapor-phase polymerization of poly(3,4-ethylenedioxythiophene) (PEDOT) on commercial carbon coated aluminum foil as enhanced electrodes for supercapacitors

NASA Astrophysics Data System (ADS)

Tong, Linyue; Skorenko, Kenneth H.; Faucett, Austin C.; Boyer, Steven M.; Liu, Jian; Mativetsky, Jeffrey M.; Bernier, William E.; Jones, Wayne E.

2015-11-01

Laminar composite electrodes are prepared for application in supercapacitors using a catalyzed vapor-phase polymerization (VPP) of 3,4-ethylenedioxythiophene (EDOT) on the surface of commercial carbon coated aluminum foil. These highly electrically conducting polymer films provide for rapid and stable power storage per gram at room temperature. The chemical composition, surface morphology and electrical properties are characterized by Raman spectroscopy, scanning electron microscopy (SEM), and conducting atomic force microscopy (C-AFM). A series of electrical measurements including cyclic voltammetry (CV), charge-discharge (CD) and electrochemical impedance spectroscopy are also used to evaluate electrical performance. The processing temperature of VPP shows a significant effect on PEDOT morphology, the degree of orientation and its electrical properties. The relatively high temperature leads to high specific area and large conductive domains of PEDOT layer which benefits the capacitive behavior greatly according to the data presented. Since the substrate is already highly conductive, the PEDOT based composite can be used as electrode materials directly without adding current collector. By this simple and efficient process, PEDOT based composites exhibit specific capacitance up to 134 F g-1 with the polymerization temperature of 110 °C.

In situ coupling of chitosan onto polypropylene foils by an Atmospheric Pressure Air Glow Discharge with a liquid cathode.

PubMed

Nikitin, D; Choukourov, A; Titov, V; Kuzmicheva, L; Lipatova, I; Mezina, E; Aleksandriiskii, V; Shelemin, A; Khalakhan, I; Slavinska, D; Biederman, H

2016-12-10

Atmospheric air plasma treatment of chitosan solutions leads to degradation of chitosan molecules by OH radicals and is accompanied by a predominant cleavage of glycosidic linkages and by a decrease of the molecular weight. The degradation proceeds via first order kinetics with the rate constant of (5.73±0.22)×10(-6)s(-1) and the energetic yield of chitosan bond scission of (2.4±0.2)×10(-8)mol/J. Products of degradation together with intact chitosan molecules adsorb and form coatings on polypropylene foils immersed into the solution that is being plasma treated. The plasma treatment results in strong binding of chitosan to polypropylene due to the formation of covalent bonds between the activated polymer surface and chitosan molecules. Plasma-driven crosslinking is responsible for the accumulation of compressive stress which leads to the development of buckling instabilities in the chitosan coatings. Copyright © 2016 Elsevier Ltd. All rights reserved.

TEM Observation of the Ti Interlayer Between SiC Substrates During Diffusion Bonding

NASA Technical Reports Server (NTRS)

Tsuda, Hiroshi; Mori, Shigeo; Halbig, Michael C.; Singh, Mori

2012-01-01

Diffusion bonding was carried out to join SiC to SiC substrates using titanium interlayers. In this study, 10 m and 20 m thick physical vapor deposited (PVD) Ti surface coatings, and 10 and 20 m thick Ti foils were used. Diffusion bonding was performed at 1250 C for PVD Ti coatings and 1200 C for Ti foil. This study investigates the microstructures of the phases formed during diffusion bonding through TEM and selected-area diffraction analysis of a sample prepared with an FIB, which allows samples to be taken from the reacted area. In all samples, Ti3SiC2, Ti5Si3Cx and TiSi2 phases were identified. In addition, TiC and unknown phases also appeared in the samples in which Ti foils were used as interlayers. Furthermore, Ti3SiC2 phases show high concentration and Ti5Si3Cx formed less when samples were processed at a higher temperature and thinner interlayer samples were used. It appears that the formation of microcracks is caused by the presence of intermediate phase Ti5Si3Cx, which has anisotropic thermal expansion, and by the presence of an unidentified Ti-Si-C ternary phase with relatively low Si content.

Methods of making metallic glass foil laminate composites

DOEpatents

Vianco, P.T.; Fisher, R.W.; Hosking, F.M.; Zanner, F.J.

1996-08-20

A process for the fabrication of a rapidly solidified foil laminate composite. An amorphous metallic glass foil is flux treated and coated with solder. Before solidification of the solder the foil is collected on a take-up spool which forms the composite into a solid annular configuration. The resulting composite exhibits high strength, resiliency and favorable magnetic and electrical properties associated with amorphous materials. The composite also exhibits bonding strength between the foil layers which significantly exceeds the bulk strength of the solder alone. 6 figs.

Methods of making metallic glass foil laminate composites

DOEpatents

Vianco, Paul T.; Fisher, Robert W.; Hosking, Floyd M.; Zanner, Frank J.

1996-01-01

A process for the fabrication of a rapidly solidified foil laminate composite. An amorphous metallic glass foil is flux treated and coated with solder. Before solidification of the solder the foil is collected on a take-up spool which forms the composite into a solid annular configuration. The resulting composite exhibits high strength, resiliency and favorable magnetic and electrical properties associated with amorphous materials. The composite also exhibits bonding strength between the foil layers which significantly exceeds the bulk strength of the solder alone.

A Non Rigid Reusable Surface Insulation Concept for the Space Shuttle Thermal Protection System

NASA Technical Reports Server (NTRS)

Alexander, J. G.

1973-01-01

A reusable thermal protection system concept was developed for the space shuttle that utilizes a flexible, woven ceramic mat insulation beneath an aerodynamic skin and moisture barrier consisting of either a dense ceramic coating or a super alloy metallic foil. The resulting heat shield material has unique structural characteristics. The shear modulus of the woven mat is very low such that bending and membrane loads introduced into the underlying structural panel remain isolated from the surface skin.

The effect of gypsum products and separating materials on the typography of denture base materials.

PubMed

Firtell, D N; Walsh, J F; Elahi, J M

1980-09-01

The typography of polymethyl methacrylate processed against various gypsum products coated with various separating materials was studied under an SEM. Tinfoil and two commercial tin foil substitutes were used as separating material during processing, and the surfaces of the resulting acrylic resin forms were studied for topographical differences. Tinfoil and alpha 2 hemihydrates produced the smoothest surfaces. As a practical solution, a good quality tinfoil substitute and alpha 1 hemihydrate could be used when processing polymethyl methacrylate resin.

Development of selective surfaces. Semiannual technical progress report, September 11, 1978-April 30, 1979. [Multilayer coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thornton, J.A.

1979-06-15

Magnetron sputtering technology, which permits coatings to be deposited over large areas with significantly increased deposition rates, is reviewed with particular emphasis on cylindrical magnetrons and their application to reactive sputtering. Work is reported in which cylindrical-post magnetron sputtering sources have been used to deposit both graded and multi-layered cermet-type coatings by sputtering chromium and type 304 stainless steel in Ar and O/sub 2/ and Ar and CO gas mixtures under various conditions of reactive gas injection. The substrates are aluminum-coated glass and aluminum foil. The coatings are of an interference type, typically about 100 nm thick, with a metal-rich,more » highly absorbing layer adjacent to the substrate and a dielectric material at the surface. In some cases a reactively sputtered aluminum oxide anti-reflective surface layer has also been used. No advantages have been found for using chromium as opposed to the more readily available stainless steel. The reactive sputtering with CO is attractive because under many conditions the sputtering rates are relatively large compared to oxygen. Hemispherical absorptance and emittance data are reported. Typical absorptances are about 0.90 with emittances of 0.10.« less

Manufacturing of polymer optical waveguides using self-assembly effect on pre-conditioned 3D-thermoformed flexible substrates

NASA Astrophysics Data System (ADS)

Hoffmann, Gerd-Albert; Wolfer, Tim; Zeitler, Jochen; Franke, Jörg; Suttmann, Oliver; Overmeyer, Ludger

2017-02-01

Optical data communication is increasingly interesting for many applications in industrial processes. Therefore mass production is required to meet the requested price and lot sizes. Polymer optical waveguides show great promises to comply with price requirements while providing sufficient optical quality for short range data transmission. A high efficient fabrication technology using polymer materials could be able to create the essential backbone for 3D-optical data transmission in the future. The approach for high efficient fabrication technology of micro optics described in this paper is based on a self-assembly effect of fluids on preconditioned 3D-thermoformed polymer foils. Adjusting the surface energy on certain areas on the flexible substrate by flexographic printing mechanism is presented in this paper. With this technique conditioning lines made of silicone containing UV-varnish are printed on top of the foils and create gaps with the exposed substrate material in between. Subsequent fabrication processes are selected whether the preconditioned foil is coated with acrylate containing waveguide material prior or after the thermoforming process. Due to the different surface energy this material tends to dewet from the conditioning lines. It acts like regional barriers and sets the width of the arising waveguides. With this fabrication technology it is possible to produce multiple waveguides with a single coating process. The relevant printing process parameters that affect the quality of the generated waveguides are discussed and results of the produced waveguides with width ranging from 10 to 300 μm are shown.

Strong thin membrane structure for use as solar sail comprising substrate with reflective coating on one surface and an infra red emissivity increasing coating on the other surface

NASA Technical Reports Server (NTRS)

Frazer, Robert E. (Inventor)

1982-01-01

Production of strong lightweight membrane structure by applying a thin reflective coating such as aluminum to a rotating cylinder, applying a mesh material such as nylon over the aluminum coating, coating the mesh overlying the aluminum with a polymerizing material such as a para-xylylene monomer gas to polymerize as a film bound to the mesh and the aluminum, and applying an emissivity increasing material such as chromium and silicon monoxide to the polymer film to disperse such material colloidally into the growing polymer film, or applying such material to the final polymer film, and removing the resulting membrane structure from the cylinder. Alternatively, such membrane structure can be formed by etching a substrate in the form of an organic film such as a polyimide, or a metal foil, to remove material from the substrate and reduce its thickness, applying a thin reflective coating such as aluminum on one side of the substrate and applying an emissivity increasing coating such as chromium and silicon monoxide on the reverse side of the substrate.

Development of a method for total inorganic arsenic analysis using anodic stripping voltammetry and a Au-coated, diamond thin-film electrode.

PubMed

Song, Yang; Swain, Greg M

2007-03-15

We demonstrate that a Au-coated, boron-doped, diamond thin-film electrode provides a sensitive, reproducible, and stable response for total inorganic arsenic (As(III) and As(V)) using differential pulse anodic stripping voltammetry (DPASV). As is preconcentrated with Au on the diamond surface during the deposition step and detected oxidatively during the stripping step. Au deposition was uniform over the electrode surface with a nominal particle size of 23 +/- 5 nm and a particle density of 109 cm-2. The electrode and method were used to measure the As(III) concentration in standard and river water samples. The detection figures of merit were compared with those obtained using conventional Au-coated glassy carbon and Au foil electrodes. The method was also used to determine the As(V) concentration in standard solutions after first being chemically reduced to As(III) with Na2SO3, followed by the normal DPASV determination of As(III). Sharp and symmetric stripping peaks were generally observed for the Au-coated diamond electrode. LODs were 0.005 ppb (S/N = 3) for As(III) and 0.08 ppb (S/N = 3) for As(V) in standard solutions. An As(III) concentration of 0.6 ppb was found in local river water. The relative standard deviation of the As stripping peak current for river water was 1.5% for 10 consecutive measurements and was less than 9.1% over a 10-h period. Excellent electrode response stability was observed even in the presence of up to 5 ppm of added humic acid. In summary, the Au-coated diamond electrode exhibited better performance for total inorganic As analysis than did Au-coated glassy carbon or Au foil electrodes. Clearly, the substrate on which the Au is supported influences the detection figures of merit.

Organic-inorganic hybrid optical foils with strong visible reflection, excellent near infrared-shielding ability and high transparency

NASA Astrophysics Data System (ADS)

Zhou, Yijie; Huang, Aibin; Zhou, Huaijuan; Ji, Shidong; Jin, Ping

2018-03-01

Research on functional flexible films has recently been attracting widespread attention especially with regards to foils, which can be designed artificially on the basis of the practical requirements. In this work, a foil with high visible reflection and a strong near infrared shielding efficiency was prepared by a simple wet chemical method. In the process of making this kind of optical foil, emulsion polymerization was first introduced to synthesize polymer opals, which were further compressed between two pieces of polyethylene terephthalate (PET) foil under polymer melting temperature to obtain a photonic crystal film with a strong reflection in the visible region to block blue rays. The following step was to coat a layer of the inorganic nano paint, which was synthesized by dispersing Cs-doped WO3 (CWO) nanoparticles homogenously into organic resin on the surface of the PET to achieve a high near infrared shielding ability. The final composite foil exhibited unique optical properties such as high visible reflectance (23.9%) to block blue rays, and excellent near infrared shielding efficiency (98.0%), meanwhile it still maintained a high transparency meaning that this foil could potentially be applied in energy-saving window films. To sum up, this study provides new insight into devising flexible hybrid films with novel optical properties, which could be further extended to prepare other optical films for potential use in automobile, architectural and other decorative fields.

The dissimilar brazing of Kovar alloy to SiCp/Al composites using silver-based filler metal foil

NASA Astrophysics Data System (ADS)

Wang, Peng; Xu, Dongxia; Zhai, Yahong; Niu, Jitai

2017-09-01

Aluminum metal matrix composites with high SiC content (60 vol.% SiCp/Al MMCs) were surface metallized with a Ni-P alloy coating, and vacuum brazing between the composites and Kovar alloy were performed using rapidly cooled Ag-22.0Cu-15.9In-10.86Sn-1.84Ti (wt%) foil. The effects of Ni-P alloy coating and brazing parameters on the joint microstructures and properties were researched by SEM, EDS, and single lap shear test, respectively. Results show that Ag-Al intermetallic strips were formed in the 6063Al matrix and filler metal layer because of diffusion, and they were arranged regularly and accumulated gradually as the brazing temperature was increased ( T/°C = 550-600) or the soaking time was prolonged ( t/min = 10-50). However, excessive strips would destroy the uniformity of seams and lead to a reduced bonding strength (at most 70 MPa). Using a Ni-P alloy coating, void free joints without those strips were obtained at 560 °C after 20 min soaking time, and a higher shear strength of 90 MPa was achieved. The appropriate interface reaction ( 2 μm transition layer) that occurred along the Ni-P alloy coating/filler metal/Kovar alloy interfaces resulted in better metallurgical bonding. In this research, the developed Ag-based filler metal was suitable for brazing the dissimilar materials of Ni-P alloy-coated SiCp/Al MMCs and Kovar alloy, and capable welding parameters were also broadened.

Sputtered silver films to improve chromium carbide based solid lubricant coatings for use to 900 C

NASA Technical Reports Server (NTRS)

Dellacorte, Christopher; Sliney, Harold E.; Deadmore, Daniel L.

1988-01-01

Thin silver films, 250 to 3500 A thick, were sputtered onto PS200, a plasma sprayed, chromium carbide based solid lubricant coating, to reduce run-in wear and improve tribological properties. The coating contains bonded chromium carbide as the wear resistant base stock with silver and barium fluoride/calcium fluoride eutectic added as low and high temperature lubricants, respectively. Potential applications for the PS200 coating are cylinder wall/piston ring lubrication for Stirling engines and foil bearing journal lubrication. In this preliminary program, the silver film overlay thickness was optimized based on tests using a pin-on-disk tribometer. The friction and wear studies were performed in a helium atmosphere at temperatures from 25 to 760 C with a sliding velocity of 2.7 m/s under a 4.9 N load. Films between 1000 and 1500 A provide the best lubrication of the counterface material. The films enrich the sliding surface with lubricant and reduce the initial abrasiveness of the as ground, plasma-sprayed coating surface, thus reducing wear.

Sputtered silver films to improve chromium carbide based solid lubricant coatings for use to 900 C

NASA Technical Reports Server (NTRS)

Dellacorte, Christopher; Sliney, Harold E.; Deadmore, Daniel L.

1988-01-01

Thin silver films, 250 to 3500 A thick, were sputtered onto PS200, a plasma sprayed, chromium carbide based solid lubricant coating, to reduce run-in wear and improve tribological properties. The coating contains bonded chromium carbide as the wear resistant base stock with silver and barium fluoride/calcium fluoride eutectic added as low and high temperature lubricants respectively. Potential applications for the PS200 coating are cylinder wall/piston ring lubrication for Stirling engines and foil bearing journal lubrication. In this preliminary program, the silver film overlay thickness was optimized based on tests using a pin-on-disk tribometer. The friction and wear studies were performed in a helium atmosphere at temperatures from 25 to 760 C with a sliding velocity of 2.7 m/s under a 4.9 N load. Films between 1000 and 1500 A provide the best lubrication of the counterface material. The films enrich the sliding surface with lubricant and reduce the initial abrasiveness of the as ground, plasma-sprayed coating surface, thus reducing wear.

Achieving Stable Radiation Pressure Acceleration of Heavy Ions via Successive Electron Replenishment from Ionization of a High-Z Material Coating

NASA Astrophysics Data System (ADS)

Shen, X. F.; Qiao, B.; Zhang, H.; Kar, S.; Zhou, C. T.; Chang, H. X.; Borghesi, M.; He, X. T.

2017-05-01

A method to achieve stable radiation pressure acceleration (RPA) of heavy ions from laser-irradiated ultrathin foils is proposed, where a high-Z material coating in front is used. The coated high-Z material, acting as a moving electron repository, continuously replenishes the accelerating heavy ion foil with comoving electrons in the light-sail acceleration stage due to its successive ionization under laser fields with Gaussian temporal profile. As a result, the detrimental effects such as foil deformation and electron loss induced by the Rayleigh-Taylor-like and other instabilities in RPA are significantly offset and suppressed so that stable acceleration of heavy ions are maintained. Particle-in-cell simulations show that a monoenergetic Al13 + beam with peak energy 3.8 GeV and particle number 1 010 (charge >20 nC ) can be obtained at intensity 1 022 W /cm2 .

Calibration of a thin metal foil for infrared imaging video bolometer to estimate the spatial variation of thermal diffusivity using a photo-thermal technique.

PubMed

Pandya, Shwetang N; Peterson, Byron J; Sano, Ryuichi; Mukai, Kiyofumi; Drapiko, Evgeny A; Alekseyev, Andrey G; Akiyama, Tsuyoshi; Itomi, Muneji; Watanabe, Takashi

2014-05-01

A thin metal foil is used as a broad band radiation absorber for the InfraRed imaging Video Bolometer (IRVB), which is a vital diagnostic for studying three-dimensional radiation structures from high temperature plasmas in the Large Helical Device. The two-dimensional (2D) heat diffusion equation of the foil needs to be solved numerically to estimate the radiation falling on the foil through a pinhole geometry. The thermal, physical, and optical properties of the metal foil are among the inputs to the code besides the spatiotemporal variation of temperature, for reliable estimation of the exhaust power from the plasma illuminating the foil. The foil being very thin and of considerable size, non-uniformities in these properties need to be determined by suitable calibration procedures. The graphite spray used for increasing the surface emissivity also contributes to a change in the thermal properties. This paper discusses the application of the thermographic technique for determining the spatial variation of the effective in-plane thermal diffusivity of the thin metal foil and graphite composite. The paper also discusses the advantages of this technique in the light of limitations and drawbacks presented by other calibration techniques being practiced currently. The technique is initially applied to a material of known thickness and thermal properties for validation and finally to thin foils of gold and platinum both with two different thicknesses. It is observed that the effect of the graphite layer on the estimation of the thermal diffusivity becomes more pronounced for thinner foils and the measured values are approximately 2.5-3 times lower than the literature values. It is also observed that the percentage reduction in thermal diffusivity due to the coating is lower for high thermal diffusivity materials such as gold. This fact may also explain, albeit partially, the higher sensitivity of the platinum foil as compared to gold.

Calibration of a thin metal foil for infrared imaging video bolometer to estimate the spatial variation of thermal diffusivity using a photo-thermal technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pandya, Shwetang N., E-mail: pandya.shwetang@LHD.nifs.ac.jp; Sano, Ryuichi; Peterson, Byron J.

A thin metal foil is used as a broad band radiation absorber for the InfraRed imaging Video Bolometer (IRVB), which is a vital diagnostic for studying three-dimensional radiation structures from high temperature plasmas in the Large Helical Device. The two-dimensional (2D) heat diffusion equation of the foil needs to be solved numerically to estimate the radiation falling on the foil through a pinhole geometry. The thermal, physical, and optical properties of the metal foil are among the inputs to the code besides the spatiotemporal variation of temperature, for reliable estimation of the exhaust power from the plasma illuminating the foil.more » The foil being very thin and of considerable size, non-uniformities in these properties need to be determined by suitable calibration procedures. The graphite spray used for increasing the surface emissivity also contributes to a change in the thermal properties. This paper discusses the application of the thermographic technique for determining the spatial variation of the effective in-plane thermal diffusivity of the thin metal foil and graphite composite. The paper also discusses the advantages of this technique in the light of limitations and drawbacks presented by other calibration techniques being practiced currently. The technique is initially applied to a material of known thickness and thermal properties for validation and finally to thin foils of gold and platinum both with two different thicknesses. It is observed that the effect of the graphite layer on the estimation of the thermal diffusivity becomes more pronounced for thinner foils and the measured values are approximately 2.5–3 times lower than the literature values. It is also observed that the percentage reduction in thermal diffusivity due to the coating is lower for high thermal diffusivity materials such as gold. This fact may also explain, albeit partially, the higher sensitivity of the platinum foil as compared to gold.« less

Preparation of titanium dioxide films on etched aluminum foil by vacuum infiltration and anodizing

NASA Astrophysics Data System (ADS)

Xiang, Lian; Park, Sang-Shik

2016-12-01

Al2O3-TiO2 (Al-Ti) composite oxide films are a promising dielectric material for future use in capacitors. In this study, TiO2 films were prepared on etched Al foils by vacuum infiltration. TiO2 films prepared using a sol-gel process were annealed at various temperatures (450, 500, and 550 °C) for different time durations (10, 30, and 60 min) for 4 cycles, and then anodized at 100 V. The specimens were characterized using X-ray diffraction, field emission scanning electron microscopy, and field emission transmission electron microscopy. The results show that the tunnels of the specimens feature a multi-layer structure consisting of an Al2O3 outer layer, an Al-Ti composite oxide middle layer, and an aluminum hydrate inner layer. The electrical properties of the specimens, such as the withstanding voltage and specific capacitance, were also measured. Compared to specimens without TiO2 coating, the specific capacitances of the TiO2-coated specimens are increased. The specific capacitance of the anode Al foil with TiO2 coating increased by 42% compared to that of a specimen without TiO2 coating when annealed at 550 °C for 10 min. These composite oxide films could enhance the specific capacitance of anode Al foils used in dielectric materials.

Coating and functionalization of high density ion track structures by atomic layer deposition

NASA Astrophysics Data System (ADS)

Mättö, Laura; Szilágyi, Imre M.; Laitinen, Mikko; Ritala, Mikko; Leskelä, Markku; Sajavaara, Timo

2016-10-01

In this study flexible TiO2 coated porous Kapton membranes are presented having electron multiplication properties. 800 nm crossing pores were fabricated into 50 μm thick Kapton membranes using ion track technology and chemical etching. Consecutively, 50 nm TiO2 films were deposited into the pores of the Kapton membranes by atomic layer deposition using Ti(iOPr)4 and water as precursors at 250 °C. The TiO2 films and coated membranes were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray reflectometry (XRR). Au metal electrode fabrication onto both sides of the coated foils was achieved by electron beam evaporation. The electron multipliers were obtained by joining two coated membranes separated by a conductive spacer. The results show that electron multiplication can be achieved using ALD-coated flexible ion track polymer foils.

Surface treatment using metal foil liner

NASA Technical Reports Server (NTRS)

Garvey, Ray

1989-01-01

A metal foil liner can be used to seal large area surfaces. Characteristics of the two-layer foil liner are discussed. Micrographs for foil-to-foil, foil-to-composite, visible seams, and hidden seams are examined.

Development of Fractal Ultra-Hydrophobic Coating Films to Prevent Water Vapor Dewing and to Delay Frosting

NASA Astrophysics Data System (ADS)

Quan, Yun-Yun; Jiang, Pei-Guo; Zhang, Li-Zhi

2014-09-01

Superhydrophobic films fabricated on copper and aluminum surfaces have potential applications to solve water condensation and frosting problems on chilled ceiling system. The rough surfaces of copper foils obtained by solution immersion method exhibit the existence of fractal structures. The hydrophobicity of copper surfaces is enhanced with fractal structures. The relationship between contact angles (CAs) and the fractal dimensions (FDs) for surface roughness of Cu samples with different etching time is investigated. Moisture condensation and frosting experiments on the two kinds of surfaces are conducted in natural environment under different chilling temperatures. During condensation, micro water condensate droplets drift down the surface like dust floating in the air. Several larger condensate droplets about 1-2 mm appear on the substrates after 3 h condensation. This continuous jumping motion of the condensate will be beneficial in delaying frosting. The results demonstrate that dense nanostructures on copper surfaces are superior to loose lattice-like microstructures on aluminum surfaces for preventing the formation of large droplets condensate and in delaying the icing. The large water droplets of 2-3 mm in diameter that would form on a common metal foil are sharply decreased to dozens of microns and small droplets are formed on a modified surface, which will then drift down like a fog.

Optical Property Enhancement and Durability Evaluation of Heat Receiver Aperture Shield Materials

NASA Technical Reports Server (NTRS)

deGroh, Kim K.; Jaworske, Donald A.; Smith, Daniela C.

1998-01-01

Under the Solar Dynamic Flight Demonstration (SDFD) program, NASA Lewis Research Center worked with AlliedSignal Aerospace, the heat receiver contractor, on the development, characterization and durability testing of refractory metals to obtain appropriate optical and thermal properties for the SDFD heat receiver aperture shield. Molybdenum and tungsten foils were grit-blasted using silicon carbide or alumina grit under various grit-blasting conditions for optical property enhancement. Black rhenium coated tungsten foil was also evaluated. Tungsten, black rhenium-coated tungsten, and grit-blasted tungsten screens of various mesh sizes were placed over the pristine and grit-blasted foils for optical property characterization. Grit-blasting was found to be effective in decreasing the specular reflectance and the absorptance/emittance ratio of the refractory foils. The placement of a screen further enhanced these optical properties, with a grit-blasted screen over a grit-blasted foil producing the best results. Based on the optical property enhancement results, samples were tested for atomic oxygen and vacuum heat treatment durability. Grit-blasted (Al2O3 grit) 2 mil tungsten foil was chosen for the exterior layer of the SDFD heat receiver aperture shield. A 0.007 in. wire diameter, 20 x 20 mesh tungsten screen was chosen to cover the tungsten foil. Based on these test results, a heat receiver aperture shield test unit has been built with the screen covered grit-blast tungsten foil exterior layers. The aperture shield was tested and verified the thermal and structural durability of the outer foil layers during an off-pointing period.

Elevated-temperature Deformation Mechanisms in Ta2C: An Experimental Study

DTIC Science & Technology

2013-01-01

result, tan- talum carbides have found uses in a variety of wear- resis - tant applications including machine tooling, coatings for injection molding...HIP billet. In addition , the near surface of the bil- let was mechanically ground to remove any possible inter- diffusion reaction zone between the...mounted in a conductive epoxy for handling. TEM foils were prepared by ultrasonically drilling 3 mm discs from the cross-sections using a Fischione

Heat Transfer in High Temperature Multilayer Insulation

NASA Technical Reports Server (NTRS)

Daryabeigi, Kamran; Miller, Steve D.; Cunnington, George R.

2007-01-01

High temperature multilayer insulations have been investigated as an effective component of thermal-protection systems for atmospheric re-entry of reusable launch vehicles. Heat transfer in multilayer insulations consisting of thin, gold-coated, ceramic reflective foils and Saffil(TradeMark) fibrous insulation spacers was studied both numerically and experimentally. A finite volume numerical thermal model using combined conduction (gaseous and solid) and radiation in porous media was developed. A two-flux model with anisotropic scattering was used for radiation heat transfer in the fibrous insulation spacers between the reflective foils. The thermal model was validated by comparison with effective thermal conductivity measurements in an apparatus based on ASTM standard C201. Measurements were performed at environmental pressures in the range from 1x10(exp -4) to 760 torr over the temperature range from 300 to 1300 K. Four multilayer samples with nominal densities of 48 kg/cu m were tested. The first sample was 13.3 mm thick and had four evenly spaced reflective foils. The other three samples were 26.6 mm thick and utilized either one, two, or four reflective foils, located near the hot boundary with nominal foil spacing of 1.7 mm. The validated thermal model was then used to study relevant design parameters, such as reflective foil spacing and location in the stack-up and coating of one or both sides of foils.

Surface Modifications of Titanium Implants by Multilayer Bioactive Coatings with Drug Delivery Potential: Antimicrobial, Biological, and Drug Release Studies

NASA Astrophysics Data System (ADS)

Ordikhani, Farideh; Zustiak, Silviya Petrova; Simchi, Abdolreza

2016-04-01

Recent strategies to locally deliver antimicrobial agents to combat implant-associated infections—one of the most common complications in orthopedic surgery—are gaining interest. However, achieving a controlled release profile over a desired time frame remains a challenge. In this study, we present an innovative multifactorial approach to combat infections which comprises a multilayer chitosan/bioactive glass/vancomycin nanocomposite coating with an osteoblastic potential and a drug delivery capacity. The bioactive drug-eluting coating was prepared on the surface of titanium foils by a multistep electrophoretic deposition technique. The adopted deposition strategy allowed for a high antibiotic loading of 1038.4 ± 40.2 µg/cm2. The nanocomposite coating exhibited a suppressed burst release with a prolonged sustained vancomycin release for up to 6 weeks. Importantly, the drug release profile was linear with respect to time, indicating a zero-order release kinetics. An in vitro bactericidal assay against Staphylococcus aureus confirmed that releasing the drug reduced the risk of bacterial infection. Excellent biocompatibility of the developed coating was also demonstrated by in vitro cell studies with a model MG-63 osteoblast cell line.

A thin gold coated hydrogen heat pipe-cryogenic target for external experiments at COSY

NASA Astrophysics Data System (ADS)

Abdel-Bary, M.; Abdel-Samad, S.; Elawadi, G. A.; Kilian, K.; Ritman, J.

2009-05-01

A gravity assisted Gold coated heat pipe (GCHP) with 5-mm diameter has been developed and tested to cool a liquid hydrogen target for external beam experiments at COSY. The need for a narrow target diameter leads us to study the effect of reducing the heat pipe diameter to 5 mm instead of 7 mm, to study the effect of coating the external surface of the heat pipe by a shiny gold layer (to decrease the radiation heat load), and to study the effect of using the heat pipe without using 20 layers of' super-insulation around it (aluminized Mylar foil) to keep the target diameter as small as possible. The developed gold coated heat pipe was tested with 20 layers of super-insulation (WI) and without super-insulation (WOI). The operating characteristics for both conditions were compared to show the advantages and disadvantages.

Targeting In-Stent-Stenosis with RGD- and CXCL1-Coated Mini-Stents in Mice.

PubMed

Simsekyilmaz, Sakine; Liehn, Elisa A; Weinandy, Stefan; Schreiber, Fabian; Megens, Remco T A; Theelen, Wendy; Smeets, Ralf; Jockenhövel, Stefan; Gries, Thomas; Möller, Martin; Klee, Doris; Weber, Christian; Zernecke, Alma

2016-01-01

Atherosclerotic lesions that critically narrow the artery can necessitate an angioplasty and stent implantation. Long-term therapeutic effects, however, are limited by excessive arterial remodeling. We here employed a miniaturized nitinol-stent coated with star-shaped polyethylenglycole (star-PEG), and evaluated its bio-functionalization with RGD and CXCL1 for improving in-stent stenosis after implantation into carotid arteries of mice. Nitinol foils or stents (bare metal) were coated with star-PEG, and bio-functionalized with RGD, or RGD/CXCL1. Cell adhesion to star-PEG-coated nitinol foils was unaltered or reduced, whereas bio-functionalization with RGD but foremost RGD/CXCL1 increased adhesion of early angiogenic outgrowth cells (EOCs) and endothelial cells but not smooth muscle cells when compared with bare metal foils. Stimulation of cells with RGD/CXCL1 furthermore increased the proliferation of EOCs. In vivo, bio-functionalization with RGD/CXCL1 significantly reduced neointima formation and thrombus formation, and increased re-endothelialization in apoE-/- carotid arteries compared with bare-metal nitinol stents, star-PEG-coated stents, and stents bio-functionalized with RGD only. Bio-functionalization of star-PEG-coated nitinol-stents with RGD/CXCL1 reduced in-stent neointima formation. By supporting the adhesion and proliferation of endothelial progenitor cells, RGD/CXCL1 coating of stents may help to accelerate endothelial repair after stent implantation, and thus may harbor the potential to limit the complication of in-stent restenosis in clinical approaches.

Targeting In-Stent-Stenosis with RGD- and CXCL1-Coated Mini-Stents in Mice

PubMed Central

Weinandy, Stefan; Schreiber, Fabian; Megens, Remco T. A.; Theelen, Wendy; Smeets, Ralf; Jockenhövel, Stefan; Gries, Thomas; Möller, Martin; Klee, Doris; Weber, Christian; Zernecke, Alma

2016-01-01

Atherosclerotic lesions that critically narrow the artery can necessitate an angioplasty and stent implantation. Long-term therapeutic effects, however, are limited by excessive arterial remodeling. We here employed a miniaturized nitinol-stent coated with star-shaped polyethylenglycole (star-PEG), and evaluated its bio-functionalization with RGD and CXCL1 for improving in-stent stenosis after implantation into carotid arteries of mice. Nitinol foils or stents (bare metal) were coated with star-PEG, and bio-functionalized with RGD, or RGD/CXCL1. Cell adhesion to star-PEG-coated nitinol foils was unaltered or reduced, whereas bio-functionalization with RGD but foremost RGD/CXCL1 increased adhesion of early angiogenic outgrowth cells (EOCs) and endothelial cells but not smooth muscle cells when compared with bare metal foils. Stimulation of cells with RGD/CXCL1 furthermore increased the proliferation of EOCs. In vivo, bio-functionalization with RGD/CXCL1 significantly reduced neointima formation and thrombus formation, and increased re-endothelialization in apoE-/- carotid arteries compared with bare-metal nitinol stents, star-PEG-coated stents, and stents bio-functionalized with RGD only. Bio-functionalization of star-PEG-coated nitinol-stents with RGD/CXCL1 reduced in-stent neointima formation. By supporting the adhesion and proliferation of endothelial progenitor cells, RGD/CXCL1 coating of stents may help to accelerate endothelial repair after stent implantation, and thus may harbor the potential to limit the complication of in-stent restenosis in clinical approaches. PMID:27192172

Low absorptance porcelain-on-aluminum coating

NASA Technical Reports Server (NTRS)

Leggett, H.

1979-01-01

Porcelain thermal-control coating for aluminum sheet and foil has solar absorptance of 0.22. Specially formulated coating absorptance is highly stable, changing only 0.03 after 1,000 hours of exposure to simulated sunlight and can be applied by standard commercial methods.

Achieving Stable Radiation Pressure Acceleration of Heavy Ions via Successive Electron Replenishment from Ionization of a High-Z Material Coating.

PubMed

Shen, X F; Qiao, B; Zhang, H; Kar, S; Zhou, C T; Chang, H X; Borghesi, M; He, X T

2017-05-19

A method to achieve stable radiation pressure acceleration (RPA) of heavy ions from laser-irradiated ultrathin foils is proposed, where a high-Z material coating in front is used. The coated high-Z material, acting as a moving electron repository, continuously replenishes the accelerating heavy ion foil with comoving electrons in the light-sail acceleration stage due to its successive ionization under laser fields with Gaussian temporal profile. As a result, the detrimental effects such as foil deformation and electron loss induced by the Rayleigh-Taylor-like and other instabilities in RPA are significantly offset and suppressed so that stable acceleration of heavy ions are maintained. Particle-in-cell simulations show that a monoenergetic Al^{13+} beam with peak energy 3.8 GeV and particle number 10^{10} (charge >20  nC) can be obtained at intensity 10^{22}  W/cm^{2}.

Development and testing of advanced fire-resistant photovoltaic modules

NASA Technical Reports Server (NTRS)

Sugimura, R. S.; Otth, D. H.; Ross, R. G., Jr.

1985-01-01

The evaluation of back-surface materials flammability in order to identify fire resistant module designs is examined. The fire test apparatus, burning-brand test sequence, and spread-of-flame test sequence are described. Video recordings and time-temperature profiles of module back surfaces are utilized to study the flammability failure mechanism and identify high-temperature materials. A table of flammability test results for various module designs is provided. The data reveals that 2-mil kapton, fiberglass cloth coated or impregnated with a material to plug pores, and metal foil back-surface materials achieve class A and B fire-resistance levels, and are applicable for photovoltaic module designs.

Method of accurate thickness measurement of boron carbide coating on copper foil

DOEpatents

Lacy, Jeffrey L.; Regmi, Murari

2017-11-07

A method is disclosed of measuring the thickness of a thin coating on a substrate comprising dissolving the coating and substrate in a reagent and using the post-dissolution concentration of the coating in the reagent to calculate an effective thickness of the coating. The preferred method includes measuring non-conducting films on flexible and rough substrates, but other kinds of thin films can be measure by matching a reliable film-substrate dissolution technique. One preferred method includes determining the thickness of Boron Carbide films deposited on copper foil. The preferred method uses a standard technique known as inductively coupled plasma optical emission spectroscopy (ICPOES) to measure boron concentration in a liquid sample prepared by dissolving boron carbide films and the Copper substrates, preferably using a chemical etch known as ceric ammonium nitrate (CAN). Measured boron concentration values can then be calculated.

Chemical etching of stainless steel 301 for improving performance of electrochemical capacitors in aqueous electrolyte

NASA Astrophysics Data System (ADS)

Jeżowski, P.; Nowicki, M.; Grzeszkowiak, M.; Czajka, R.; Béguin, F.

2015-04-01

The main purpose of the study was to increase the surface roughness of stainless steel 301 current collectors by etching, in order to improve the electrochemical performance of electrical double-layer capacitors (EDLC) in 1 mol L-1 lithium sulphate electrolyte. Etching was realized in 1:3:30 (HNO3:HCl:H2O) solution with times varying up to 10 min. For the considered 15 μm thick foil and a mass loss around 0.4 wt.%, pitting was uniform, with diameter of pits ranging from 100 to 300 nm. Atomic force microscopy (AFM) showed an increase of average surface roughness (Ra) from 5 nm for the as-received stainless steel foil to 24 nm for the pitted material. Electrochemical impedance spectroscopy realized on EDLCs with coated electrodes either on as-received or pitted foil in 1 mol L-1 Li2SO4 gave equivalent distributed resistance (EDR) of 8 Ω and 2 Ω, respectively, demonstrating a substantial improvement of collector/electrode interface after pitting. Correlatively, the EDLCs with pitted collector displayed a better charge propagation and low ohmic losses even at relatively high current of 20 A g-1. Hence, chemical pitting of stainless steel current collectors is an appropriate method for optimising the performance of EDLCs in neutral aqueous electrolyte.

Characterization and antibacterial performance of electrodeposited chitosan-vancomycin composite coatings for prevention of implant-associated infections.

PubMed

Ordikhani, F; Tamjid, E; Simchi, A

2014-08-01

Orthopaedic implant-associated infections are one of the most serious complications in orthopaedic surgery and a major cause of implant failure. In the present work, drug-eluting coatings based on chitosan containing various amounts of vancomycin were prepared by a cathodic electrophoretic deposition process on titanium foils. A three-step release mechanism of the antibiotic from the films in a phosphate-buffered saline solution was noticed. At the early stage, physical encapsulation of the drug in the hydrogel network controlled the release rate. At the late stage, however, in vitro degradation/deattachment of chitosan was responsible for the controlled release. Cytotoxicity evaluation of the drug-eluting coatings via culturing in human osteosarcoma cells (MG-63 osteoblast-like cell line) showed no adverse effect on the biocompatibility. Antibacterial tests against Gram-positive Staphylococcus aureus also demonstrated that the infection risk of titanium foils was significantly reduced due to the antibiotic release. Additionally, in vitro electrochemical corrosion studies by polarization technique revealed that the corrosion current density was significantly lower for the titanium foils with drug-eluting coatings compared to that of uncoated titanium. Copyright © 2014 Elsevier B.V. All rights reserved.

Dual-Chamber/Dual-Anode Proportional Counter Incorporating an Intervening Thin-Foil Solid Neutron Converter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boatner, Lynn A; Neal, John S; Blackston, Matthew A

2012-01-01

A dual-chamber/dual-anode gas proportional counter utilizing thin solid 6LiF or 10B neutron converters coated on a 2-micon-thick Mylar film that is positioned between the two counter chambers and anodes has been designed, fabricated, and tested using a variety of fill gases including naturally abundant helium. In this device, neutron conversion products emitted from both sides of the coated converter foil are detected rather than having half of the products absorbed in the wall of a conventional tube type counter where the solid neutron converter is deposited on the tube wall. Geant4-based radiation transport calculations were used to determine the optimummore » neutron converter coating thickness for both isotopes. Solution methods for applying these optimized-thickness coatings on a Mylar film were developed that were carried out at room temperature without any specialized equipment and that can be adapted to standard coating methods such as silk screen or ink jet printing. The performance characteristics of the dual-chamber/dual-anode neutron detector were determined for both types of isotopically enriched converters. The experimental performance of the 6LiF converter-based detector was described well by modeling results from Geant4. Additional modeling studies of multiple-foil/multiple-chamber/anode configurations addressed the basic issue of the relatively longer absorption range of neutrons versus the shorter range of the conversion products for 6LiF and 10B. Combined with the experimental results, these simulations indicate that a high-performance neutron detector can be realized in a single device through the application of these multiple-foil/solid converter, multiple-chamber detector concepts.« less

Infrared particle detection for battery electrode foils

NASA Astrophysics Data System (ADS)

Just, P.; Ebert, L.; Echelmeyer, T.; Roscher, M. A.

2013-11-01

Failures of electrochemical cells caused by internal shorts still are an important issue to be faced by the cell manufacturers and their customers. A major cause for internal shorts are contaminated electrode foils. These contaminations have to be detected securely via a non-destructive inspection technique integrated into the electrode manufacturing process. While optical detection already is state of the art, infrared detection of particles finds a new field of application in the battery electrode manufacturing process. This work presents two approaches focusing on electrode inspection by electromagnetic radiation (visible and infrared). Copper foils with a carbon based coating were intentionally contaminated by slivers of aluminum and copper as well as by abraded coating particles. Optical excitation by a flash and a luminescent lamp was applied at different angles in order to detect the reflected visible radiation. A laser impulse was used to heat up the specimen for infrared inspection. Both approaches resulted in setups providing a high contrast between contaminations and the coated electrode foil. It is shown that infrared detection offers a higher security thanks to its reliance on absorbance and emissivity instead of reflectivity as it is used for optical detection. Infrared Detection offers a potential since it is hardly influenced by the particle's shape and orientation and the electrode's waviness.

78 FR 5290 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Reasonably Available...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-01-25

...: Paper, film, and foil coatings; industrial cleaning solvents; miscellaneous metal and plastic parts... solvents; (3) miscellaneous metal and plastic parts coatings; (4) large appliance coatings; (5) offset... protection, Air pollution control, Incorporation by reference, Intergovernmental relations, Ozone, Reporting...

Reactive multilayer synthesis of hard ceramic foils and films

DOEpatents

Makowiecki, Daniel M.; Holt, Joseph B.

1996-01-01

A method for synthesizing hard ceramic materials such as carbides, borides nd aluminides, particularly in the form of coatings provided on another material so as to improve the wear and abrasion performance of machine tools, for example. The method involves the sputter deposition of alternating layers of reactive metals with layers of carbon, boron, or aluminum and the subsequent reaction of the multilayered structure to produce a dense crystalline ceramic. The material can be coated on a substrate or formed as a foil which can be coild as a tape for later use.

Copper foils with gradient structure in thickness direction and different roughnesses on two surfaces fabricated by double rolling

NASA Astrophysics Data System (ADS)

Wang, Xi-yong; Liu, Xue-feng; Zou, Wen-jiang; Xie, Jian-xin

2013-12-01

Copper foils with gradient structure in thickness direction and different roughnesses on two surfaces were fabricated by double rolling. The two surface morphologies of double-rolled copper foils are quite different, and the surface roughness values are 61 and 1095 nm, respectively. The roughness value of matt surface can meet the requirement for bonding the resin matrix with copper foils used for flexible printed circuit boards, thus may omit traditional roughening treatment; the microstructure of double-rolled copper foils demonstrates an obviously asymmetric gradient feature. From bright surface to matt surface in thickness direction, the average grain size first increases from 2.3 to 7.4 μm and then decreases to 3.6 μm; compared with conventional rolled copper foils, the double-rolled copper foils exhibit a remarkably increased bending fatigue life, and the increased range is about 16.2%.

In situ calibration of the foil detector for an infrared imaging video bolometer using a carbon evaporation technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mukai, K., E-mail: mukai.kiyofumi@LHD.nifs.ac.jp; Peterson, B. J.; SOKENDAI

The InfraRed imaging Video Bolometer (IRVB) is a useful diagnostic for the multi-dimensional measurement of plasma radiation profiles. For the application of IRVB measurement to the neutron environment in fusion plasma devices such as the Large Helical Device (LHD), in situ calibration of the thermal characteristics of the foil detector is required. Laser irradiation tests of sample foils show that the reproducibility and uniformity of the carbon coating for the foil were improved using a vacuum evaporation method. Also, the principle of the in situ calibration system was justified.

Explosive-driven, high speed, arcless switch

DOEpatents

Skogmo, P.J.; Tucker, T.J.

1986-05-02

An explosive-actuated, fast-acting arcless switch contains a highly conductive foil to carry high currents positioned adjacent a dielectric surface within a casing. At one side of the foil opposite the dielectric surface is an explosive which, when detonated, drives the conductive foil against the dielectric surface. A pattern of grooves in the dielectric surface ruptures the foil to establish a rupture path having a pattern corresponding to the pattern of the grooves. The impedance of the ruptured foil is greater than that of the original foil to divert high current to a load. Planar and cylindrical embodiments of the switch are disclosed.

Explosive-driven, high speed, arcless switch

DOEpatents

Skogmo, Phillip J.; Tucker, Tillman J.

1987-01-01

An explosive-actuated, fast-acting arcless switch contains a highly conductive foil to carry high currents positioned adjacent a dielectric surface within a casing. At one side of the foil opposite the dielectric surface is an explosive which, when detonated, drives the conductive foil against the dielectric surface. A pattern of grooves in the dielectric surface ruptures the foil to establish a rupture path having a pattern corresponding to the pattern of the grooves. The impedance of the ruptured foil is greater than that of the original foil to divert high current to a load. Planar and cylindrical embodiments of the switch are disclosed.

Lead zirconate titanate (PZT)-based thin film capacitors for embedded passive applications

NASA Astrophysics Data System (ADS)

Kim, Taeyun

Investigations on the key processing parameters and properties relationship for lead zirconate titanate (PZT, 52/48) based thin film capacitors for embedded passive capacitor application were performed using electroless Ni coated Cu foils as substrates. Undoped and Ca-doped PZT (52/48) thin film capacitors were prepared on electroless Ni coated Cu foil by chemical solution deposition. For PZT (52/48) thin film capacitors on electroless Ni coated Cu foil, voltage independent (zero tunability) capacitance behavior was observed. Dielectric constant reduced to more than half of the identical capacitor processed on Pt/SiO2/Si. Dielectric properties of the capacitors were mostly dependent on the crystallization temperature. Capacitance densities of almost 350 nF/cm2 and 0.02˜0.03 of loss tangent were routinely measured for capacitors crystallized at 575˜600°C. Leakage current showed dependence on film thickness and crystallization temperature. From a two-capacitor model, the existence of a low permittivity interface layer (permittivity ˜30) was suggested. For Ca-doped PZT (52/48) thin film capacitors prepared on Pt, typical ferroelectric and dielectric properties were measured up to 5 mol% Ca doping. When Ca-doped PZT (52/48) thin film capacitors were prepared on electroless Ni coated Cu foil, phase stability was influenced by Ca doping and phosphorous content. Dielectric properties showed dependence on the crystallization temperature and phosphorous content. Capacitance density of ˜400 nF/cm2 was achieved, which is an improvement by more than 30% compared to undoped composition. Ca doping also reduced the temperature coefficient of capacitance (TCC) less than 10%, all of them were consistent in satisfying the requirements of embedded passive capacitor. Leakage current density was not affected significantly by doping. To tailor the dielectric and reliability properties, ZrO2 was selected as buffer layer between PZT and electroless Ni. Only RF magnetron sputtering process could yield stable ZrO2 layers on electroless Ni coated Cu foil. Other processes resulted in secondary phase formation, which supports the reaction between PZT capacitor and electroless Ni might be dominated by phosphorous component. (Abstract shortened by UMI.)

Oxygen diffusion barrier coating

NASA Technical Reports Server (NTRS)

Unnam, Jalaiah (Inventor); Clark, Ronald K. (Inventor)

1987-01-01

A method for coating a titanium panel or foil with aluminum and amorphous silicon to provide an oxygen barrier abrogating oxidation of the substrate metal is developed. The process is accomplished with known inexpensive procedures common in materials research laboratories, i.e., electron beam deposition and sputtering. The procedures are conductive to treating foil gage titanium and result in submicron layers which virtually add no weight to the titanium. There are no costly heating steps. The coatings blend with the substrate titanium until separate mechanical properties are subsumed by those of the substrate without cracking or spallation. This method appreciably increases the ability of titanium to mechanically perform in high thermal environments such as those witnessed on structures of space vehicles during re-entry

Industry Needs Fulfilled by Patented NASA PS300 Solid Lubricant Technology

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher

2003-01-01

In 1999, the NASA Glenn Research Center was awarded a patent (#5866518) for a new high-temperature solid lubricant coating material, PS300. A combination of wear-resistant metals and ceramics with solid lubricant additives, PS300 reduces friction and wear in sliding contacts from below ambient to over 650 C. This lubricant is an outgrowth of over three decades of high-temperature tribological research and was specifically developed as a shaft lubricant to protect foil air bearings used in Oil-Free turbomachinery, like gas turbines. Foil bearings are lubricated by air at high speeds but experience sliding and wear during initial startup and shut down when a lubricating film of air has not yet developed. PS300 shaft coatings have successfully lubricated foil bearings for over 100 000 cycles without wearing out.

Carbon-Coated Current Collectors for High-Power Li-ion Secondary Batteries III

DTIC Science & Technology

2013-12-02

surface. Electron-performance for use modified Al foil as current collector of the cathode. LiFePO4 (LFPO) was used as active materials for test...kinds of current collectors were shown in Fig. 4. It shows the rate capacity of LiFePO4 (LFPO) get poorer when using PAT-Al as current collector, and...commercial LiFePO4 (Ale84) on different current collector Figure 4. Rate capacities of LFPO electrodes with different current collectors. 0 20

Electrical Microengineering of Redox Enzymes

DTIC Science & Technology

1994-03-31

coating applied to the electrode 41 to prevent lose of mediator graphite foil potassium -~0.02a 0.03  electrolyte wus dioxane with 15% 42...hexacyanoferrats(ll)d aqueous buffer carbon fiber’ none h 40-5000 biotin/avidin complex used to obtain a 43 surface layer of HRP Pt organic metal, potassium ...OFFICE OF NAVAL RESEARCH AD-A279 015 FINAL REPORT FOR CONTRACT NOOO 14-91 -J- 1656 R&T CODE 413h007---05 ELECTRICAL MICROENGINEERING OF REDOX ENZYMES

Explosive-driven, high speed, arcless switch

DOEpatents

Skogmo, P.J.; Tucker, T.J.

1987-07-14

An explosive-actuated, fast-acting arcless switch contains a highly conductive foil to carry high currents positioned adjacent a dielectric surface within a casing. At one side of the foil opposite the dielectric surface is an explosive which, when detonated, drives the conductive foil against the dielectric surface. A pattern of grooves in the dielectric surface ruptures the foil to establish a rupture path having a pattern corresponding to the pattern of the grooves. The impedance of the ruptured foil is greater than that of the original foil to divert high current to a load. Planar and cylindrical embodiments of the switch are disclosed. 7 figs.

Lead foil in dental X-ray film: Backscattering rejection or image intensifier?

NASA Astrophysics Data System (ADS)

Hönnicke, M. G.; Delben, G. J.; Godoi, W. C.; Swinka-Filho, V.

2014-11-01

Dental X-ray films are still largely used due to sterilization issues, simplicity and, mainly, economic reasons. These films almost always are double coated (double emulsion) and have a lead foil in contact with the film for X-ray backscattering rejection. Herein we explore the use of the lead foil as an image intensifier. In these studies, spatial resolution was investigated when images were acquired on the dental X-ray films with and without the lead foil. Also, the lead foil was subjected to atomic analysis (fluorescent measurements) and structure analysis (X-ray diffraction). We determined that the use of the lead foil reduces the exposure time, however, does not affect the spatial resolution on the acquired images. This suggests that the fluorescent radiation spread is smaller than the grain sizes of the dental X-ray films.

Reactive multilayer synthesis of hard ceramic foils and films

DOEpatents

Makowiecki, D.M.; Holt, J.B.

1996-02-13

A method is disclosed for synthesizing hard ceramic materials such as carbides, borides and aluminides, particularly in the form of coatings provided on another material so as to improve the wear and abrasion performance of machine tools, for example. The method involves the sputter deposition of alternating layers of reactive metals with layers of carbon, boron, or aluminum and the subsequent reaction of the multilayered structure to produce a dense crystalline ceramic. The material can be coated on a substrate or formed as a foil which can be coiled as a tape for later use.

40 CFR 60.741 - Definitions, symbols, and cross-reference tables.

Code of Federal Regulations, 2010 CFR

2010-07-01

... prepolymers to a supporting web other than paper, plastic film, metallic foil, or metal coil. Substrate means... (i) entering the emission control device, in dry standard cubic meters per hour when Method 18 or 25... coats a continuous web to produce a substrate with a polymeric coating. Should the coating process not...

Palladium coated porous anodic alumina membranes for gas reforming processes

NASA Astrophysics Data System (ADS)

Wu, Jeremy P.; Brown, Ian W. M.; Bowden, Mark E.; Kemmitt, Timothy

2010-11-01

Nanostructured ceramic membranes with ultrathin coatings of palladium metal have been demonstrated to separate hydrogen gas from a gas mixture containing nitrogen with 10% carbon dioxide and 10% hydrogen at temperatures up to 550 °C. The mechanically robust and thermally durable membranes were fabricated using a combination of conventional and high-efficiency anodisation processes on high purity aluminium foils. A pH-neutral plating solution has also been developed to enable electroless deposition of palladium metal on templates which were normally prone to chemical corrosion in strong acid or base environment. Activation and thus seeding of palladium nuclei on the surface of the template were essential to ensure uniform and fast deposition, and the thickness of the metal film was controlled by time of deposition. The palladium coated membranes showed improved hydrogen selectivity with increased temperature as well as after prolonged exposure to hydrogen, demonstrating excellent potential for gas separation technologies.

Laser-Based Production of Metallic Conducting Paths

NASA Astrophysics Data System (ADS)

Vedder, Christian; Stollenwerk, Jochen; Wissenbach, Konrad; Pirch, Norbert

For numerous devices such as OLEDs, solar cells or heated windows conducting paths are needed for collecting or distributing electricity on poorly or non-conducting surfaces. With established techniques the metallic paths can only be produced with a great deal of effort, incurring high costs for plant, equipment and energy. A new laser based process to manufacture conducting paths allows for writing narrow paths (down to 35 μm width) of Al, Cu, Ag or similar materials onto flat surfaces of glass (plain or coated with ITO) and silicon wafers by melting and vaporizing a metal foil through optical energy at high speeds of up to 2.5 m/s.

Thin Shell, Segmented X-Ray Mirrors

NASA Technical Reports Server (NTRS)

Petre, Robert

2010-01-01

Thin foil mirrors were introduced as a means of achieving high throughput in an X-ray astronomical imaging system in applications for which high angular resolution were not necessary. Since their introduction, their high filling factor, modest mass, relative ease of construction, and modest cost have led to their use in numerous X-ray observatories, including the Broad Band X-ray Telescope, ASCA, and Suzaku. The introduction of key innovations, including epoxy replicated surfaces, multilayer coatings, and glass mirror substrates, has led to performance improvements, and in their becoming widely used for X-ray astronomical imaging at energies above 10 keV. The use of glass substrates has also led to substantial improvement in angular resolution, and thus their incorporation into the NASA concept for the International X-ray Observatory with a planned 3 in diameter aperture. This paper traces the development of foil mirrors from their inception in the 1970's through their current and anticipated future applications.

Ag out-surface diffusion in crystalline SiC with an effective SiO 2 diffusion barrier

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xue, H.; Xiao, H. Y.; Zhu, Z.

2015-05-07

For applications of tristructural isotropic (TRISO) fuel particles in high temperature reactors, release of radioactive Ag isotope ( 110mAg) through the SiC coating layer is a safety concern. In order to understand the diffusion mechanism, Ag ion implantations near the surface and in the bulk were performed by utilizing different ion energies and energy-degrader foils. High temperature annealing was carried out on the as-irradiated samples to study the possible out-surface diffusion. Before and after annealing, Rutherford backscattering spectrometry (RBS) and secondary ion mass spectrometry (SIMS) measurements were employed to obtain the elemental profiles of the implanted samples. Our results suggestmore » little migration of buried Ag in the bulk, and an out-diffusion of the implanted Ag in the near-surface region of single crystal SiC. It is also found that a SiO 2 layer, which was formed during annealing, may serve as an effective barrier to reduce or prevent Ag out diffusion through the SiC coating layer.« less

Ag Out-surface Diffusion In Crystalline SiC With An Effective SiO2 Diffusion Barrier

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xue, H.; Xiao, Haiyan Y.; Zhu, Zihua

2015-09-01

For applications of tristructural isotropic (TRISO) fuel particles in high temperature reactors, release of radioactive Ag isotope (110mAg) through the SiC coating layer is a safety concern. To understand the diffusion mechanism, Ag ion implantations near the surface and in the bulk were performed by utilizing different ion energies and energy-degrader foils. High temperature annealing was carried out on the as-irradiated samples to study the possible out-surface diffusion. Before and after annealing, Rutherford backscattering spectrometry (RBS) and secondary ion mass spectrometry (SIMS) measurements were employed to obtain the elemental profiles of the implanted samples. The results suggest little migration ofmore » buried Ag in the bulk, and an out-diffusion of the implanted Ag in the near-surface region of single crystal SiC. It is also found that a SiO2 layer, which was formed during annealing, may serve as an effective barrier to reduce or prevent Ag out diffusion through the SiC coating layer.« less

Fabrication of High-Temperature Heat Exchangers by Plasma Spraying Exterior Skins on Nickel Foams

NASA Astrophysics Data System (ADS)

Hafeez, P.; Yugeswaran, S.; Chandra, S.; Mostaghimi, J.; Coyle, T. W.

2016-06-01

Thermal-sprayed heat exchangers were tested at high temperatures (750 °C), and their performances were compared to the foam heat exchangers made by brazing Inconel sheets to their surface. Nickel foil was brazed to the exterior surface of 10-mm-thick layers of 10 and 40 PPI nickel foam. A plasma torch was used to spray an Inconel coating on the surface of the foil. A burner test rig was built to produce hot combustion gases that flowed over exposed face of the heat exchanger. Cooling air flowed through the foam heat exchanger at rates of up to 200 SLPM. Surface temperature and air inlet/exit temperature were measured. Heat transfer to air flowing through the foam was significantly higher for the thermally sprayed heat exchangers than for the brazed heat exchangers. On an average, thermally sprayed heat exchangers show 36% higher heat transfer than conventionally brazed foam heat exchangers. At low flow rates, the convective resistance is large (~4 × 10-2 m2 K/W), and the effect of thermal contact resistance is negligible. At higher flow rates, the convective resistance decreases (~2 × 10-3 m2 K/W), and the lower contact resistance of the thermally sprayed heat exchanger provides better performance than the brazed heat exchangers.

The Effects of Sn Addition on the Microstructure and Surface Properties of Laser Deposited Al-Si-Sn Coatings on ASTM A29 Steel

NASA Astrophysics Data System (ADS)

Fatoba, Olawale S.; Akinlabi, Stephen A.; Akinlabi, Esther T.

2018-03-01

Aluminium and its alloys have been successful metal materials used for many applications like commodity roles, automotive and vital structural components in aircrafts. A substantial portion of Al-Fe-Si alloy is also used for manufacturing the packaging foils and sheets for common heat exchanger applications. The present research was aimed at studying the morphology and surface analyses of laser deposited Al-Sn-Si coatings on ASTM A29 steel. These Fe-intermetallic compounds influence the material properties during rapid cooling by laser alloying technique and play a crucial role for the material quality. Thus, it is of considerable technological interest to control the morphology and distribution of these phases in order to eliminate the negative effects on microstructure. A 3 kW continuous wave ytterbium laser system (YLS) attached to a KUKA robot which controls the movement of the alloying process was utilized for the fabrication of the coatings at optimum laser parameters. The fabricated coatings were investigated for its hardness and wear resistance performance. The field emission scanning electron microscope equipped with energy dispersive spectroscopy (SEM/EDS) was used to study the morphology of the fabricated coatings and X-ray diffractometer (XRD) for the identification of the phases present in the coatings. The coatings were free of cracks and pores with homogeneous and refined microstructures. The enhanced hardness and wear resistance performance were attributed to metastable intermetallic compounds formed.

A Preliminary Foil Gas Bearing Performance Map

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher; Radil, Kevin C.; Bruckner, Robert J.; Howard, S. Adam

2006-01-01

Recent breakthrough improvements in foil gas bearing load capacity, high temperature tribological coatings and computer based modeling have enabled the development of increasingly larger and more advanced Oil-Free Turbomachinery systems. Successful integration of foil gas bearings into turbomachinery requires a step wise approach that includes conceptual design and feasibility studies, bearing testing, and rotor testing prior to full scale system level demonstrations. Unfortunately, the current level of understanding of foil gas bearings and especially their tribological behavior is often insufficient to avoid developmental problems thereby hampering commercialization of new applications. In this paper, a new approach loosely based upon accepted hydrodynamic theory, is developed which results in a "Foil Gas Bearing Performance Map" to guide the integration process. This performance map, which resembles a Stribeck curve for bearing friction, is useful in describing bearing operating regimes, performance safety margins, the effects of load on performance and limiting factors for foil gas bearings.

Improvement of Surface Layer Characteristics by Shot Lining

NASA Astrophysics Data System (ADS)

Harada, Yasunori

In the present study, lining of the metal with foils using shot peening was investigated to improve the surface layer characteristics. In the shot peening experiment, the foils set on the metal are pelted with hard particles traveling at a high velocity. The foils are bonded to the metal surface due to plastic deformation induced by the collision of the particles. The foils and the metal are heated to heighten the bondability because of the reduction of flow stress. Lining the metal with the hard powder sandwiched between two aluminum foil sheets was also attempted. In this experiment, a centrifugal shot peening machine wite an electrical heater was employed. The metals are commercially aluminium alloys and magnesium alloys, and the foils are commercially aluminum, titanium and nickel. The effects of shot speed and the heating temperature on the bondability were examined. Wear resistance was also evaluated by grinding. The foils were successfully bonded to the metal surface. It was found that the present method is effective in improving of surface layer characteristics.

Epitaxial lift-off of electrodeposited single-crystal gold foils for flexible electronics

NASA Astrophysics Data System (ADS)

Mahenderkar, Naveen K.; Chen, Qingzhi; Liu, Ying-Chau; Duchild, Alexander R.; Hofheins, Seth; Chason, Eric; Switzer, Jay A.

2017-03-01

We introduce a simple and inexpensive procedure for epitaxial lift-off of wafer-size flexible and transparent foils of single-crystal gold using silicon as a template. Lateral electrochemical undergrowth of a sacrificial SiOx layer was achieved by photoelectrochemically oxidizing silicon under light irradiation. A 28-nanometer-thick gold foil with a sheet resistance of 7 ohms per square showed only a 4% increase in resistance after 4000 bending cycles. A flexible organic light-emitting diode based on tris(bipyridyl)ruthenium(II) that was spin-coated on a foil exploited the transmittance and flexibility of the gold foil. Cuprous oxide as an inorganic semiconductor that was epitaxially electrodeposited onto the gold foils exhibited a diode quality factor n of 1.6 (where n = 1.0 for an ideal diode), compared with a value of 3.1 for a polycrystalline deposit. Zinc oxide nanowires electrodeposited epitaxially on a gold foil also showed flexibility, with the nanowires intact up to 500 bending cycles.

NASA PS304 Lubricant Tested in World's First Commercial Oil-Free Gas Turbine

NASA Technical Reports Server (NTRS)

Weaver, Harold F.

2003-01-01

In a marriage of research and commercial technology, a 30-kW Oil-Free Capstone microturbine electrical generator unit has been installed and is serving as a test bed for long-term life-cycle testing of NASA-developed PS304 shaft coatings. The coatings are used to reduce friction and wear of the turbine engine s foil air bearings during startup and shut down when sliding occurs, prior to the formation of a lubricating air film. This testing supports NASA Glenn Research Center s effort to develop Oil-Free gas turbine aircraft propulsion systems, which will employ advanced foil air bearings and NASA s PS304 high temperature solid lubricant to replace the ball bearings and lubricating oil found in conventional engines. Glenn s Oil-Free Turbomachinery team s current project is the demonstration of an Oil-Free business jet engine. In anticipation of future flight certification of Oil-Free aircraft engines, long-term endurance and durability tests are being conducted in a relevant gas turbine environment using the Capstone microturbine engine. By operating the engine now, valuable performance data for PS304 shaft coatings and for industry s foil air bearings are being accumulated.

Fission fragment assisted reactor concept for space propulsion: Foil reactor

NASA Technical Reports Server (NTRS)

Wright, Steven A.

1991-01-01

The concept is to fabricate a reactor using thin films or foils of uranium, uranium oxide and then to coat them on substrates. These coatings would be made so thin as to allow the escaping fission fragments to directly heat a hydrogen propellant. The idea was studied of direct gas heating and direct gas pumping in a nuclear pumped laser program. Fission fragments were used to pump lasers. In this concept two substrates are placed opposite each other. The internal faces are coated with thin foil of uranium oxide. A few of the advantages of this technology are listed. In general, however, it is felt that if one look at all solid core nuclear thermal rockets or nuclear thermal propulsion methods, one is going to find that they all pretty much look the same. It is felt that this reactor has higher potential reliability. It has low structural operating temperatures, very short burn times, with graceful failure modes, and it has reduced potential for energetic accidents. Going to a design like this would take the NTP community part way to some of the very advanced engine designs, such as the gas core reactor, but with reduced risk because of the much lower temperatures.

All-inorganic large-area low-cost and durable flexible perovskite solar cells using copper foil as a substrate.

PubMed

Abdollahi Nejand, B; Nazari, P; Gharibzadeh, S; Ahmadi, V; Moshaii, A

2017-01-05

Here, a low-cost perovskite solar cell using CuI and ZnO as the respective inorganic hole and electron transport layers is introduced. Copper foil is chosen as a cheap and low-weight conductive substrate which has a similar work function to ITO. Besides, copper foil is an interesting copper atom source for the growth of the upper cuprous iodide layer on copper foil. A spray coating of a transparent silver nanowire electrode is used as a top contact. The prepared device shows a maximum power conversion efficiency of 12.80% and long-term durability providing an environmentally and market friendly perovskite solar cell.

Influence of surface structure and chemistry on water droplet splashing.

PubMed

Koch, Kerstin; Grichnik, Roland

2016-08-06

Water droplet splashing and aerosolization play a role in human hygiene and health systems as well as in crop culturing. Prevention or reduction of splashing can prevent transmission of diseases between animals and plants and keep technical systems such as pipe or bottling systems free of contamination. This study demonstrates to what extent the surface chemistry and structures influence the water droplet splashing behaviour. Smooth surfaces and structured replicas of Calathea zebrina (Sims) Lindl. leaves were produced. Modification of their wettability was done by coating with hydrophobizing and hydrophilizing agents. Their wetting was characterized by contact angle measurement and splashing behaviour was observed with a high-speed video camera. Hydrophobic and superhydrophilic surfaces generally showed fewer tendencies to splash than hydrophobic ones. Structuring amplified the underlying behaviour of the surface chemistries, increasing hydrophobic surfaces' tendency to splash and decreasing splash on hydrophilic surfaces by quickly transporting water off the impact point by capillary forces. The non-porous surface structures found in C. zebrina could easily be applied to technical products such as plastic foils or mats and coated with hydrophilizing agents to suppress splash in areas of increased hygiene requirements or wherever pooling of liquids is not desirable.This article is part of the themed issue 'Bioinspired hierarchically structured surfaces for green science'. © 2016 The Author(s).

Method of Suppressing Sublimation in Advanced Thermoelectric Devices

NASA Technical Reports Server (NTRS)

Sakamoto, Jeffrey S. (Inventor); Caillat, Thierry (Inventor); Fleurial, Jean-Pierre (Inventor); Snyder, G. Jeffrey (Inventor)

2009-01-01

A method of applying a physical barrier to suppress thermal decomposition near a surface of a thermoelectric material including applying a continuous metal foil to a predetermined portion of the surface of the thermoelectric material, physically binding the continuous metal foil to the surface of the thermoelectric material using a binding member, and heating in a predetermined atmosphere the applied and physically bound continuous metal foil and the thermoelectric material to a sufficient temperature in order to promote bonding between the continuous metal foil and the surface of the thermoelectric material. The continuous metal foil forms a physical barrier to enclose a predetermined portion of the surface. Thermal decomposition is suppressed at the surface of the thermoelectric material enclosed by the physical barrier when the thermoelectric element is in operation.

Mechanical tearing of graphene on an oxidizing metal surface.

PubMed

George, Lijin; Gupta, Aparna; Shaina, P R; Das Gupta, Nandita; Jaiswal, Manu

2015-12-11

Graphene, the thinnest possible anticorrosion and gas-permeation barrier, is poised to transform the protective coatings industry for a variety of surface applications. In this work, we have studied the structural changes of graphene when the underlying copper surface undergoes oxidation upon heating. Single-layer graphene directly grown on a copper surface by chemical vapour deposition was annealed under ambient atmosphere conditions up to 400 °C. The onset temperature of the surface oxidation of copper is found to be higher for graphene-coated foils. Parallel arrays of graphene nanoripples are a ubiquitous feature of pristine graphene on copper, and we demonstrate that these form crucial sites for the onset of the oxidation of copper, particularly for ∼0.3-0.4 μm ripple widths. In these regions, the oxidation proceeds along the length of the nanoripples, resulting in the formation of parallel stripes of oxidized copper regions. We demonstrate from temperature-dependent Raman spectroscopy that the primary defect formation process in graphene involves boundary-type defects rather than vacancy or sp(3)-type defects. This observation is consistent with a mechanical tearing process that splits graphene into small polycrystalline domains. The size of these is estimated to be sub-50 nm.

Controlled porous pattern of anodic aluminum oxide by foils laminate approach.

PubMed

Wang, Gou-Jen; Peng, Chi-Sheng

2006-04-01

A novel, much simpler, and low-cost method to fabricate the porous pattern of the anodic aluminum oxide (AAO) based on the aluminum foils laminate approach was carried out. During our experiments, it was found that the pores of the AAO on the upper foil grew bi-directionally from both the top and the bottom surfaces. Experimental results further indicate that the upward porous pattern of the upper foil is determined by the surface structure of the bottom surface of the upper foil. The porous pattern of AAO can be controlled by a pre-made pattern on the bottom surface. Furthermore, no Aluminum (Al) layer removing process is required in this novel laminate method.

Intense pulsed light annealing of copper zinc tin sulfide nanocrystal coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, Bryce A.; Smeaton, Michelle A.; Holgate, Collin S.

2016-09-15

A promising method for forming the absorber layer in copper zinc tin sulfide [Cu{sub 2}ZnSnS{sub 4} (CZTS)] thin film solar cells is thermal annealing of coatings cast from dispersions of CZTS nanocrystals. Intense pulsed light (IPL) annealing utilizing xenon flash lamps is a potential high-throughput, low-cost, roll-to-roll manufacturing compatible alternative to thermal annealing in conventional furnaces. The authors studied the effects of flash energy density (3.9–11.6 J/cm{sup 2}) and number of flashes (1–400) during IPL annealing on the microstructure of CZTS nanocrystal coatings cast on molybdenum-coated soda lime glass substrates (Mo-coated SLG). The annealed coatings exhibited cracks with two distinct linearmore » crack densities, 0.01 and 0.2 μm{sup −1}, depending on the flash intensity and total number of flashes. Low density cracking (0.01 μm{sup −1}, ∼1 crack per 100 μm) is caused by decomposition of CZTS at the Mo-coating interface. Vapor decomposition products at the interface cause blisters as they escape the coating. Residual decomposition products within the blisters were imaged using confocal Raman spectroscopy. In support of this hypothesis, replacing the Mo-coated SLG substrate with quartz eliminated blistering and low-density cracking. High density cracking is caused by rapid thermal expansion and contraction of the coating constricted on the substrate as it is heated and cooled during IPL annealing. Finite element modeling showed that CZTS coatings on low thermal diffusivity materials (i.e., SLG) underwent significant differential heating with respect to the substrate with rapid rises and falls of the coating temperature as the flash is turned on and off, possibly causing a build-up of tensile stress within the coating prompting cracking. Use of a high thermal diffusivity substrate, such as a molybdenum foil (Mo foil), reduces this differential heating and eliminates the high-density cracking. IPL annealing in presence of sulfur vapor prevented both low- and high-density cracking as well as blistering. However, grain growth was limited even after annealing with 400 flashes. This lack of grain growth is attributed to a difficulty of maintaining high sulfur vapor pressure and absence of alkali metal impurities when Mo foil substrates are used.« less

Neutron scattering study of the freezing of water near a cupric oxide surface

NASA Astrophysics Data System (ADS)

Torres, J.; Buck, Z. N.; Zhang, F. Z.; Chen, T.; Winholtz, R. A.; Kaiser, H.; Ma, H. B.; Taub, H.; Tyagi, M.

Oscillating heat pipes (OHP) offer promising two-phase heat transfer for a variety of applications, including cooling of electronic devices.2 Recently, it has been shown that a hydrophilic CuO coating on either the evaporator or condenser sections of a flat-plate OHP can significantly enhance its thermal performance.3 This finding has motivated us to assess the strength of the CuO/H2O interaction by investigating the freezing behavior of H2O in proximity to a CuO surface. Using the High-Flux Backscattering Spectrometer at NIST, we have measured the intensity of neutrons scattered elastically from a well-hydrated sample of CuO-coated Cu foils that mimic the oxide surfaces in a flat-plate OHP. We observe abrupt freezing of bulk-like H2O above the CuO surface at 270 K followed by continuous freezing of the interfacial H2O down to 265 K. This freezing behavior is qualitatively similar to that found for water near a zwitterionic single-supported bilayer lipid membrane.3 Further studies are planned to compare the diffusion coefficients of the interfacial water for the coated and uncoated OHPs.22F.Z. Zhang et al., submitted to J. Heat Transfer. 3M. Bai et al., Europhys. Lett. 98, 48006 (2012); Miskowiec et al., Europhys. Lett. 107, 28008 (2014). Supported by NSF Grant Nos. DMR-0944772 and DGE-1069091.

Composite multilayer insulations for thermal protection of aerospace vehicles

NASA Technical Reports Server (NTRS)

Kourtides, Demetrius A.; Pitts, William C.

1989-01-01

Composite flexible multilayer insulation systems (MLI), consisting of alternating layers of metal foil and scrim cloth or insulation quilted together using ceramic thread, were evaluated for thermal performance and compared with a silica fibrous (baseline) insulation system. The systems studied included: (1) alternating layers of aluminoborosilicate (ABS) scrim cloth and stainless steel foil, with silica, ABS, or alumina insulation; (2) alternating layers of scrim cloth and aluminum foil, with silica or ABS insulation; (3) alternating layers of aluminum foil and silica or ABS insulation; and (4) alternating layers of aluminum-coated polyimide placed on the bottom of the silica insulation. The MLIs containing aluminum were the most efficient, measuring as little as half the backface temperature increase of the baseline system.

Chirality and grain boundary effects on indentation mechanical properties of graphene coated on nickel foil

NASA Astrophysics Data System (ADS)

Yan, Yuping; Lv, Jiajiang; Liu, Sheng

2018-04-01

We investigate chirality and grain boundary (GB) effects on indentation mechanical properties of graphene coated on nickel foil using molecular dynamics simulations. The models of graphene with different chirality angles, different numbers of layers and tilt GBs were established. It was found that the chirality angle of few-layer graphene had a significant effect on the load bearing capacity of graphene/nickel systems, and this turns out to be more significant when the number of layers is greater than one. The enhancement to the contact stiffness, elastic capacity and the load bearing capacity of graphene with tilt GBs was lower than that of pristine graphene.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balachandran, U.

The purpose of this CRADA is to develop a fabrication process to reduce the manufacturing cost for a very compact, high temperature, film-on-foil high energy-density PLZT (Pb-La-Zr- Ti-O) capacitor. Motivation for this CRADA is derived from the DOE’s Office of Vehicle Technologies (OVT) program, which seeks to advance technologies to improve vehicle fuel efficiency in the mid-term and facilitate the transition to electric drive vehicles over the longterm. The objective of Argonne’s work is to develop and characterize high-performance capacitors on base-metal foils. The PLZT film-on-foil prepared using a spin-coating technique

Effects of laser shock peening with contacting foil on micro laser texturing surface of Ti6Al4V

NASA Astrophysics Data System (ADS)

Dai, Fengze; Zhang, Zidong; Ren, Xudong; Lu, Jinzhong; Huang, Shu

2018-02-01

Ti6Al4V samples with micro-dimple arrays were subjected to laser shock peening in contact with foil (HCLSP). The surface roughness, micro-hardness, the residual stress distribution and the surface morphology of the micro-dimple arrays were studied to evaluate the effects of HCLSP. Moreover, the surface topography of the foils in contact was also analyzed. The gap existence between the foil and the to-be treated surface led the mechanism of HCLSP to be different compared to regular laser shock peening. The surface roughness reduction, the work-hardening effects, the compressive residual stress and the micro crack enclosure were achieved. A simplified ball-hitting-surface model was utilized to analyze the HCLSP impact. The model could well explain the experimental results. When treated by the HCLSP with H62 foil at the laser power density of 4.24 GW/cm2, the Ti6Al4V samples with micro-dimple arrays exhibit well surface topography and mechanical performance.

Oil-Free Turbomachinery Being Developed

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher; Valco, Mark J.

2001-01-01

NASA and the Army Research Laboratory (ARL) along with industry and university researchers, are developing Oil-Free technology that will have a revolutionary impact on turbomachinery systems used in commercial and military applications. System studies have shown that eliminating an engine's oil system can yield significant savings in weight, maintenance, and operational costs. The Oil-Free technology (foil air bearings, high-temperature coatings, and advanced modeling) is being developed to eliminate the need for oil lubrication systems on high-speed turbomachinery such as turbochargers and gas turbine engines that are used in aircraft propulsion systems. The Oil-Free technology is enabled by recent breakthroughs in foil bearing load capacity, solid lubricant coatings, and computer-based analytical modeling. During the past fiscal year, a U.S. patent was awarded for the NASA PS300 solid lubricant coating, which was developed at the NASA Glenn Research Center. PS300 has enabled the successful operation of foil air bearings to temperatures over 650 C and has resulted in wear lives in excess of 100,000 start/stop cycles. This leapfrog improvement in performance over conventional solid lubricants (limited to 300 C) creates new application opportunities for high-speed, high-temperature Oil-Free gas turbine engines. On the basis of this break-through coating technology and the world's first successful demonstration of an Oil-Free turbocharger in fiscal year 1999, industry is partnering with NASA on a 3-year project to demonstrate a small, Oil-Free turbofan engine for aeropropulsion.

Handheld Reflective Foil Emissometer with 0.007 Absolute Accuracy at 0.05

NASA Astrophysics Data System (ADS)

van der Ham, E. W. M.; Ballico, M. J.

2014-07-01

The development and performance of a handheld emissometer for the measurement of the emissivity of highly reflective metallic foils used for the insulation of domestic and commercial buildings are described. Reflective roofing insulation based on a thin coating of metal on a more robust substrate is very widely used in hotter climates to reduce the radiant heat transfer between the ceiling and roof in commercial and residential buildings. The required normal emissivity of these foils is generally below 0.05, so stray reflected ambient infrared radiation (IR) makes traditional reflectance-based measurements of emissivity very difficult to achieve with the required accuracy. Many manufacturers apply additional coatings onto the metallic foil to reduce visible glare during installation on a roof, and to provide protection to the thin reflective layer; however, this layer can also substantially increase the IR emissivity. The system as developed at the National Measurement Institute, Australia (NMIA) is based on the principle of measurement of the modulation in thermal infrared radiation, as the sample is thermally modulated by hot and cold air streams. A commercial infrared to band radiation thermometer with a highly specialized stray and reflected radiation shroud attachment is used as the detector system, allowing for convenient handheld field measurements. The performance and accuracy of the system have been compared with NMIA's reference emissometer systems for a number of typical material samples, demonstrating its capability to measure the absolute thermal emissivity of these very highly reflective foils with an uncertainty of better than.

The possibility of using platinum foils with a rippled surface as diffraction gratings

NASA Astrophysics Data System (ADS)

Korsukov, V. E.; Ankudinov, A. V.; Butenko, P. N.; Knyazev, S. A.; Korsukova, M. M.; Obidov, B. A.; Shcherbakov, I. P.

2014-09-01

The atomic structure and surface relief of thin cold-rolled platinum foils upon recrystallization annealing and loading under ultrahigh vacuum conditions have been studied by low energy electron diffraction (LEED), atomic force microscopy (AFM), and scanning tunneling microscopy (STM). The surface of samples upon high-temperature annealing and subsequent uniaxial extension of recrystallized Pt foils represents a fractal structure of unidirectional ripples on various spatial scales. The total fractal dimension of this surface is D GW = 2.3, while the fractal dimensions along and across ripples are D ‖ ≈ 1 and D ⊥ ≈ 1.3, respectively. The optical spectra of a halogen lamp and a PRK-2 mercury lamp were recorded using these rippled Pt foils as reflection diffraction gratings. It is shown that Pt foils with this surface relief can be used as reflection diffraction gratings for electromagnetic radiation in a broad spectral range.

Silicon oxide permeation barrier coating of PET bottles and foils

NASA Astrophysics Data System (ADS)

Steves, Simon; Deilmann, Michael; Awakowicz, Peter

2009-10-01

Modern packaging materials such as polyethylene terephthalate (PET) have displaced established materials in many areas of food and beverage packaging. Plastic packing materials offer are various advantages concerning production and handling. PET bottles for instance are non-breakable and lightweight compared to glass and metal containers. However, PET offers poor barrier properties against gas permeation. Therefore, the shelf live of packaged food is reduced. Permeation of gases can be reduced by depositing transparent plasma polymerized silicon oxide (SiOx) barrier coatings. A microwave (2.45 GHz) driven low pressure plasma reactor is developed based on a modified Plasmaline antenna to treat PET foils or bottles. To increase the barrier properties of the coatings furthermore a RF substrate bias (13.56 MHz) is applied. The composition of the coatings is analyzed by means of Fourier transform infrared (FTIR) spectroscopy regarding carbon and hydrogen content. Influence of gas phase composition and substrate bias on chemical composition of the coatings is discussed. A strong relation between barrier properties and film composition is found: good oxygen barriers are observed as carbon content is reduced and films become quartz-like. Regarding oxygen permeation a barrier improvement factor (BIF) of 70 is achieved.

Multi-element microelectropolishing method

DOEpatents

Lee, Peter J.

1994-01-01

A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle.

X-ray optics made from thin plastic foils

NASA Astrophysics Data System (ADS)

Schnopper, Herbert W.; Silver, Eric H.; Ingram, Russell H.; Christensen, Finn E.; Hussain, Ahsen M.; Barbera, Marco; Romaine, Suzanne E.; Collura, Alfonso; Kenter, Almus T.; Bandler, Simon; Murray, Stephen S.

1999-09-01

New design concepts and materials can be used to produce very lightweight, thin foil approximations, to Wolter I and other x-ray optics. Structures are designed around a central hub and spacers that connect one spoked wheels. Figure defining, thin pins span the distance between the wheels. Thin, metal coated or multilayered, plastic foils can be formed into cones, cylinders or spirals for x-ray telescopes or lenses. Imaging and spectroscopic data obtained with x- ray lenses are presented and they indicate that a 60 cm diameter, 4.65 m focal length x-ray telescope can have a half power diameter of < 2 arcmin.

Eddy current probe with foil sensor mounted on flexible probe tip and method of use

DOEpatents

Viertl, John R. M.; Lee, Martin K.

2001-01-01

A pair of copper coils are embedded in the foil strip. A first coil of the pair generates an electromagnetic field that induces eddy currents on the surface, and the second coil carries a current influenced by the eddy currents on the surface. The currents in the second coil are analyzed to obtain information on the surface eddy currents. An eddy current probe has a metal housing having a tip that is covered by a flexible conductive foil strip. The foil strip is mounted on a deformable nose at the probe tip so that the strip and coils will conform to the surface to which they are applied.

Foil Artists

ERIC Educational Resources Information Center

Szekely, George

2010-01-01

Foil can be shaped into almost anything--it is the all-purpose material for children's art. Foil is a unique drawing surface. It reflects, distorts and plays with light and imagery as young artists draw over it. Foil permits quick impressions of a model or object to be sketched. Foil allows artists to track their drawing moves, seeing the action…

Method for fabricating .sup.99 Mo production targets using low enriched uranium, .sup.99 Mo production targets comprising low enriched uranium

DOEpatents

Wiencek, Thomas C.; Matos, James E.; Hofman, Gerard L.

1997-01-01

A radioisotope production target and a method for fabricating a radioisotope production target is provided, wherein the target comprises an inner cylinder, a foil of fissionable material circumferentially contacting the outer surface of the inner cylinder, and an outer hollow cylinder adapted to receive the substantially foil-covered inner cylinder and compress tightly against the foil to provide good mechanical contact therewith. The method for fabricating a primary target for the production of fission products comprises preparing a first substrate to receive a foil of fissionable material so as to allow for later removal of the foil from the first substrate, preparing a second substrate to receive the foil so as to allow for later removal of the foil from the second substrate; attaching the first substrate to the second substrate such that the foil is sandwiched between the first substrate and second substrate to prevent foil exposure to ambient atmosphere, and compressing the exposed surfaces of the first and second substrate to assure snug mechanical contact between the foil, the first substrate and the second substrate.

Method for fabricating .sup.99 Mo production targets using low enriched uranium, .sup.99 Mo production targets comprising low enriched uranium

DOEpatents

Wiencek, Thomas C [Orland Park, IL; Matos, James E [Oak Park, IL; Hofman, Gerard L [Downers Grove, IL

2000-12-12

A radioisotope production target and a method for fabricating a radioisotope production target is provided, wherein the target comprises an inner cylinder, a foil of fissionable material circumferentially contacting the outer surface of the inner cylinder, and an outer hollow cylinder adapted to receive the substantially foil-covered inner cylinder and compress tightly against the foil to provide good mechanical contact therewith. The method for fabricating a primary target for the production of fission products comprises preparing a first substrate to receive a foil of fissionable material so as to allow for later removal of the foil from the first substrate, preparing a second substrate to receive the foil so as to allow for later removal of the foil from the second substrate; attaching the first substrate to the second substrate such that the foil is sandwiched between the first substrate and second substrate to prevent foil exposure to ambient atmosphere, and compressing the exposed surfaces of the first and second substrate to assure snug mechanical contact between the foil, the first substrate and the second substrate.

Evidence of circular Rydberg states in beam-foil experiments: Role of the surface wake field

NASA Astrophysics Data System (ADS)

Sharma, Gaurav; Puri, Nitin K.; Kumar, Pravin; Nandi, T.

2017-12-01

We have employed the concept of the surface wake field to model the formation of the circular Rydberg states in the beam-foil experiments. The experimental studies of atomic excitation processes show the formation of circular Rydberg states either in the bulk of the foil or at the exit surface, and the mechanism is explained by several controversial theories. The present model is based on the interesting fact that the charge state fraction as well as the surface wake field depend on the foil thickness and it resolves a long-standing discrepancy on the mechanism of the formation of circular Rydberg states. The influence of exit layers is twofold. Initially, the high angular momentum Rydberg states are produced in the last layers of the foil by the Stark switching due to the bulk wake field and finally, they are transferred to the circular Rydberg states as a single multiphoton process due to the influence of the surface wake field.

Structure, biomimetics, and fluid dynamics of fish skin surfaces*

NASA Astrophysics Data System (ADS)

Lauder, George V.; Wainwright, Dylan K.; Domel, August G.; Weaver, James C.; Wen, Li; Bertoldi, Katia

2016-10-01

The interface between the fluid environment and the surface of the body in swimming fishes is critical for both physiological and hydrodynamic functions. The skin surface in most species of fishes is covered with bony scales or toothlike denticles (in sharks). Despite the apparent importance of fish surfaces for understanding aquatic locomotion and near-surface boundary layer flows, relatively little attention has been paid to either the nature of surface textures in fishes or possible hydrodynamic effects of variation in roughness around the body surface within an individual and among species. Fish surfaces are remarkably diverse and in many bony fishes scales can have an intricate surface texture with projections, ridges, and comblike extensions. Shark denticles (or scales) are toothlike and project out of the skin to form a complexly textured surface that interacts with free-stream flow. Manufacturing biomimetic foils with fishlike surfaces allows hydrodynamic testing and we emphasize here the importance of dynamic test conditions where the effect of surface textures is assessed under conditions of self-propulsion. We show that simple two-dimensional foils with patterned cuts do not perform as well as a smooth control surface, but that biomimetic shark skin foils can swim at higher self-propelled speeds than smooth controls. When the arrangement of denticles on the foil surface is altered, we find that a staggered-overlapped pattern outperforms other arrangements. Flexible foils made of real shark skin outperform sanded controls when foils are moved with a biologically realistic motion program. We suggest that focus on the mechanisms of drag reduction by fish surfaces has been too limiting and an additional role of fish surface textures may be to alter leading edge vortices and flow patterns on moving surfaces in a way that enhances thrust. Analysis of water flow over an artificial shark skin foil under both static and dynamic conditions shows that a shear layer develops over the denticle surface and we propose that there is limited flow under the expanded surfaces of shark denticles. The diversity of fish scale types and textures and the effect of these surfaces on boundary layer flows and fish locomotor energetics is a rich area for future investigation.

Multi-element microelectropolishing method

DOEpatents

Lee, P.J.

1994-10-11

A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle. 10 figs.

Robust Pinhole-free Li3N Solid Electrolyte Grown from Molten Lithium

PubMed Central

2017-01-01

Lithium metal is the ultimate anode choice for high energy density rechargeable lithium batteries. However, it suffers from inferior electrochemical performance and safety issues due to its high reactivity and the growth of lithium dendrites. It has long been desired to develop a materials coating on Li metal, which is pinhole-free, mechanically robust without fracture during Li metal deposition and stripping, and chemically stable against Li metal and liquid electrolytes, all while maintaining adequate ionic conductivity. However, such an ideal material coating has yet to be found. Here we report a novel synthesis method by reacting clean molten lithium foil directly with pure nitrogen gas to generate instantaneously a pinhole-free and ionically conductive α-Li3N film directly bonded onto Li metal foil. The film consists of highly textured large Li3N grains (tens of μm) with (001) crystalline planes parallel to the Li metal surface. The bonding between textured grains is strong, resulting in a mechanically robust film which does not crack even when bent to a 0.8 cm curvature radius and is found to maintain pinhole-free coverage during Li metal deposition and stripping. The measured ionic conductivity is up to 5.2 × 10–4 S cm–1, sufficient for maintaining regular current densities for controllable film thicknesses ranging from 2 to 30 μm. This Li3N coating is chemically stable, isolating the reactive metallic lithium from liquid electrolyte, prevents continuous electrolyte consumption during battery cycling, and promotes dendrite-free uniform lithium plating/stripping underneath. We demonstrated Li|Li4Ti5O12 cells with stable and flat potential profiles for 500 cycles without capacity decay or an increase in potential hysteresis. PMID:29392181

Method of sintering ceramic materials

DOEpatents

Holcombe, Cressie E.; Dykes, Norman L.

1992-01-01

A method for sintering ceramic materials is described. A ceramic article is coated with layers of protective coatings such as boron nitride, graphite foil, and niobium. The coated ceramic article is embedded in a container containing refractory metal oxide granules and placed within a microwave oven. The ceramic article is heated by microwave energy to a temperature sufficient to sinter the ceramic article to form a densified ceramic article having a density equal to or greater than 90% of theoretical density.

Passive Thermal Management of Foil Bearings

NASA Technical Reports Server (NTRS)

Bruckner, Robert J. (Inventor)

2015-01-01

Systems and methods for passive thermal management of foil bearing systems are disclosed herein. The flow of the hydrodynamic film across the surface of bearing compliant foils may be disrupted to provide passive cooling and to improve the performance and reliability of the foil bearing system.

Method for fabricating {sup 99}Mo production targets using low enriched uranium, {sup 99}Mo production targets comprising low enriched uranium

DOEpatents

Wiencek, T.C.; Matos, J.E.; Hofman, G.L.

1997-03-25

A radioisotope production target and a method for fabricating a radioisotope production target is provided, wherein the target comprises an inner cylinder, a foil of fissionable material circumferentially contacting the outer surface of the inner cylinder, and an outer hollow cylinder adapted to receive the substantially foil-covered inner cylinder and compress tightly against the foil to provide good mechanical contact therewith. The method for fabricating a primary target for the production of fission products comprises preparing a first substrate to receive a foil of fissionable material so as to allow for later removal of the foil from the first substrate, preparing a second substrate to receive the foil so as to allow for later removal of the foil from the second substrate; attaching the first substrate to the second substrate such that the foil is sandwiched between the first substrate and second substrate to prevent foil exposure to ambient atmosphere, and compressing the exposed surfaces of the first and second substrate to assure snug mechanical contact between the foil, the first substrate and the second substrate. 3 figs.

A novel approach for the fabrication of a flexible glucose biosensor: The combination of vertically aligned CNTs and a conjugated polymer.

PubMed

Gokoglan, Tugba Ceren; Soylemez, Saniye; Kesik, Melis; Dogru, Itir Bakis; Turel, Onur; Yuksel, Recep; Unalan, Husnu Emrah; Toppare, Levent

2017-04-01

A novel flexible glucose biosensor using vertically aligned carbon nanotubes (VACNT) and a conjugated polymer (CP) was fabricated. A scaffold based on VACNT grown on aluminum foil (VACNT-Al foil) with poly (9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl)-end capped with 2,5-diphenyl-1,2,4-oxadiazole (PFLO) was used as the immobilization matrix for the glucose biosensor. Glucose oxidase (GOx) was immobilized on a modified indium tin oxide (ITO) coated polyethylene terephthalate (PET) electrode surface. The biosensor response at a potential of -0.7V versus Ag wire was followed by the decrease in oxygen level as a result of enzymatic reaction. The biosensor exhibited a linear range between 0.02mM and 0.5mM glucose and kinetic parameters (K M app , I max , limit of detection (LOD) and sensitivity) were estimated as 0.193mM, 8.170μA, 7.035×10 -3 mM and 65.816μA/mMcm 2 , respectively. Scanning electron microscopy (SEM) was used for surface characterization. The constructed biosensor was applied to determine the glucose content in several beverages. Copyright © 2016 Elsevier Ltd. All rights reserved.

Fabrication of rippled surfaces for diffraction gratings by plastic deformation of platinum foils and metallic glasses

NASA Astrophysics Data System (ADS)

Korsukov, V. E.; Malygin, G. A.; Korsukova, M. M.; Nyapshaev, I. A.; Obidov, B. A.

2015-12-01

Thin platinum foils and metallic glass ribbons with a fractal surface consisting of different-scale unidirectionally oriented ripples have been fabricated using special thermoplastic processing. The general fractal dimension of the rippled surface and dimensions along and across the ripples have been measured. The optical spectra of a PRK-4 lamp using rippled Pt(111) foils as reflective diffraction gratings have been determined. A model describing the mechanism of the formation of surface unidirectional fractal structures during deformation has been proposed.

Silver-Foil Psychrometer for Measuring Leaf Water Potential in situ.

PubMed

Hoffman, G J; Rawlins, S L

1972-09-01

The water potential of leaves in situ can be measured without temperature control with a miniature, single-junction psychrometer constructed from silver foil and attached to the leaf with a silver-impregnated, conductive coating. The temperature of the psychrometer has been found to stay within 0.025 degrees C of the temperature of a simulated leaf when the latter temperature was changing at a rate of 1 degrees C per minute. Leaf water potentials can be measured with a precision of +/- 1 bar, or better.

Electron beams in research and technology

NASA Astrophysics Data System (ADS)

Mehnert, R.

1995-11-01

Fast electrons lose their energy by inelastic collisions with electrons of target molecules forming secondary electrons and excited molecules. Coulomb interaction of secondary electrons with valence electrons of neighboring molecules leads to the formation of radical cations, thermalized electrons, excited molecular states and radicals. The primary reactive species initiate chemical reactions in the materials irradiated. Polymer modifications using accelerated electrons such as cross-linking of cable insulation, tubes, pipes and moldings, vulcanization of elastomers, grafting of polymer surfaces, processing of foamed plastics and heat shrinkable materials have gained wide industrial acceptance. A steadily growing electron beam technology is curing of paints, lacquers, printing inks and functional coatings. Electron beam processing offers high productivity, the possibility to treat the materials at normal temperature and pressure, excellent process control and clean production conditions. On an industrial scale the most important application of fast electrons is curing of 100% reactive monomer/prepolymer systems. Mainly acrylates and epoxides are used to formulate functional coatings on substrates such as paper, foil, wood, fibre board and high pressure laminates. A survey is given about the reaction mechanism of curing, the characterization of cured coatings, and of some industrial application.

Additional security features for optically variable foils

NASA Astrophysics Data System (ADS)

Marshall, Allan C.; Russo, Frank

1998-04-01

For thousands of years, man has exploited the attraction and radiance of pure gold to adorn articles of great significance. Today, designers decorate packaging with metallic gold foils to maintain the prestige of luxury items such as perfumes, chocolates, wine and whisky, and to add visible appeal and value to wide range of products. However, today's products do not call for the hand beaten gold leaf of the Ancient Egyptians, instead a rapid production technology exists which makes use of accurately coated thin polymer films and vacuum deposited metallic layers. Stamping Foils Technology is highly versatile since several different layers may be combined into one product, each providing a different function. Not only can a foil bring visual appeal to an article, it can provide physical and chemical resistance properties and also protect an article from human forms of interference, such as counterfeiting, copying or tampering. Stamping foils have proved to be a highly effective vehicle for applying optical devices to items requiring this type of protection. Credit cards, bank notes, personal identification documents and more recently high value packaged items such as software and perfumes are protected by optically variable devices applied using stamping foil technology.

Method of sintering ceramic materials

DOEpatents

Holcombe, C.E.; Dykes, N.L.

1992-11-17

A method for sintering ceramic materials is described. A ceramic article is coated with layers of protective coatings such as boron nitride, graphite foil, and niobium. The coated ceramic article is embedded in a container containing refractory metal oxide granules and placed within a microwave oven. The ceramic article is heated by microwave energy to a temperature sufficient to sinter the ceramic article to form a densified ceramic article having a density equal to or greater than 90% of theoretical density. 2 figs.

Instability Coupling Experiments*

NASA Astrophysics Data System (ADS)

Chrien, R. E.; Hoffman, N. M.; Magelssen, G. R.; Schappert, G. T.; Smitherman, D. P.

1996-11-01

The coupling of Richtmyer-Meshkov (RM) and ablative Rayleigh-Taylor (ART) instabilities is being studied with indirectly-driven planar foil experiments on the Nova laser at Livermore. The foil is attached to a 1.6-mm-diameter, 2.75-mm-long Au hohlraum driven by a 2.2-ns long, 1:5-contrast-ratio shaped laser pulse. A shock is generated in 35-μm or 86-μm thick Al foils with a 50-μm-wavelength, 4-μm-amplitude sinusoidal perturbation on its rear surface. In some experiments, the perturbation is applied to a 10-μm Be layer on the Al. A RM instability develops when the shock encounters the perturbed surface. The flow field of the RM instability can ``feed out'' to the ablation surface of the foil and provide the seed for ART perturbation growth. Face-on and side-on x-radiography are used to observe areal density perturbations in the foil. For the 86-μm foil, the perturbation arrives at the ablation surface while the hohlraum drive is dropping and the data are consistent with RM instability alone. For the 35-μm foil, the perturbation feeds out while the hohlraum drive is close to its peak and the data appear to show strong ART perturbation growth. Comparisons with LASNEX simulations will be presented. *This work supported under USDOE contract W-7405-ENG-36.

Method of using deuterium-cluster foils for an intense pulsed neutron source

DOEpatents

Miley, George H.; Yang, Xiaoling

2013-09-03

A method is provided for producing neutrons, comprising: providing a converter foil comprising deuterium clusters; focusing a laser on the foil with power and energy sufficient to cause deuteron ions to separate from the foil; and striking a surface of a target with the deuteron ions from the converter foil with energy sufficient to cause neutron production by a reaction selected from the group consisting of D-D fusion, D-T fusion, D-metal nuclear spallation, and p-metal. A further method is provided for assembling a plurality of target assemblies for a target injector to be used in the previously mentioned manner. A further method is provided for producing neutrons, comprising: splitting a laser beam into a first beam and a second beam; striking a first surface of a target with the first beam, and an opposite second surface of the target with the second beam with energy sufficient to cause neutron production.

Structure and mechanical properties of a multilayer carbide-hardened niobium composite material fabricated by diffusion welding

NASA Astrophysics Data System (ADS)

Korzhov, V. P.; Ershov, A. E.; Stroganova, T. S.; Prokhorov, D. V.

2016-04-01

The structure, the bending strength, and the fracture mechanism of an artificial niobium-based composite material, which is fabricated by high-pressure diffusion welding of multilayer stacks assembled from niobium foils with a two-sided carbon coating, are studied. The microstructure of the composite material is found to consist of alternating relatively plastic layers of the solid solution of carbon in niobium and hardening niobium carbide layers. The room-temperature proportional limit of the developed composite material is threefold that of the composite material fabricated from coating-free niobium foils using the proposed technology. The proportional limit of the developed composite material and the stress corresponding to the maximum load at 1100°C are 500 and 560 MPa, respectively. The developed material is considered as an alternative to Ni-Al superalloys.

Fabrication of high-performance supercapacitors based on transversely oriented carbon nanotubes

NASA Astrophysics Data System (ADS)

Markoulidis, F.; Lei, C.; Lekakou, C.

2013-04-01

High-performance supercapacitors with organic electrolyte 1 M TEABF4 (tetraethyl ammonium tetrafluoroborate) in PC (propylene carbonate) were fabricated and tested, based on multiwall carbon nanotubes (MWNTs) deposited by electrophoresis on three types of alternative substrates: aluminium foil, ITO (indium tin oxide) coated PET (polyethylene terephthalate) film and PET film. In all cases, SEM (scanning electron microscopy) and STEM (scanning transmission electron microscopy) micrographs demonstrated that protruding, transversely oriented MWNT structures were formed, which should increase the transverse conductivity of these MWNT electrodes. The best supercapacitor cell of MWNT electrodes deposited on aluminium foil displayed good transverse orientation of the MWNT structures as well as an in-plane MWNT network at the feet of the protruding structures, which ensured good in-plane conductivity. Capacitor cells with MWNT electrodes deposited either on ITO-coated PET film or on PET film demonstrated lower but still very good performance due to the high density of transversely oriented MWNT structures (good transverse conductivity) but some in-plane inhomogeneities. Capacitor cells with drop-printed MWNTs on aluminium foil, without any transverse orientation, had 16-30 times lower specific capacitance and 5-40 times lower power density than the capacitor cells with the electrophoretically deposited MWNT electrodes.

Advancements Toward Oil-Free Rotorcraft Propulsion

NASA Technical Reports Server (NTRS)

Howard, Samuel A.; Bruckner, Robert J.; Radil, Kevin C.

2010-01-01

NASA and the Army have been working for over a decade to advance the state-of-the-art (SOA) in Oil-Free Turbomachinery with an eye toward reduced emissions and maintenance, and increased performance and efficiency among other benefits. Oil-Free Turbomachinery is enabled by oil-free gas foil bearing technology and relatively new high-temperature tribological coatings. Rotorcraft propulsion is a likely candidate to apply oil-free bearing technology because the engine size class matches current SOA for foil bearings and because foil bearings offer the opportunity for higher speeds and temperatures and lower weight, all critical issues for rotorcraft engines. This paper describes an effort to demonstrate gas foil journal bearing use in the hot section of a full-scale helicopter engine core. A production engine hot-core location is selected as the candidate foil bearing application. Rotordynamic feasibility, bearing sizing, and load capability are assessed. The results of the program will help guide future analysis and design in this area by documenting the steps required and the process utilized for successful application of oil-free technology to a full-scale engine.

ELECTRIC DISCHARGE APPARATUS

DOEpatents

Ryan, T.M.

1962-04-01

A steel or aluminum small diameter (1/4 in.) tube-type neutron detector containing an inert atmosphere and having a coating of fissionable material on its inner circumference is described. A conducting wire, positioned along the axis of the tube by spaced insulators, is connected to a power source. The coating of fissionable material is brushed onto a nickel foil which is inserted into the tube and supported between the insulators. (AEC)

An Experimental Investigation Into the Temperature Profile of a Compliant Foil Air Bearing

NASA Technical Reports Server (NTRS)

Radil, Kevin; Zeszotek, Michelle

2004-01-01

A series of tests was performed to determine the internal temperature profile in a compliant bump-type foil journal air bearing operating at room temperature under various speeds and load conditions. The temperature profile was collected by instrumenting a foil bearing with nine, type K thermocouples arranged in the center and along the bearing s edges in order to measure local temperatures and estimate thermal gradients in the axial and circumferential directions. To facilitate the measurement of maximum temperatures from viscous shearing in the air film, the thermocouples were tack welded to the backside of the bumps that were in direct contact with the top foil. The mating journal was coated with a high temperature solid lubricant that, together with the bearing, underwent high temperature start-stop cycles to produce a smooth, steady-state run-in surface. Tests were conducted at speeds from 20 to 50 krpm and loads ranging from 9 to 222 N. The results indicate that, over the conditions tested, both journal rotational speed and radial load are responsible for heat generation with speed playing a more significant role in the magnitude of the temperatures. The temperature distribution was nearly symmetric about the bearing center at 20 and 30 krpm but became slightly skewed toward one side at 40 and 50 krpm. Surprisingly, the maximum temperatures did not occur at the bearing edge where the minimum film thickness is expected but rather in the middle of the bearing where analytical investigations have predicted the air film to be much thicker. Thermal gradients were common during testing and were strongest in the axial direction from the middle of the bearing to its edges, reaching 3.78 8C/mm. The temperature profile indicated the circumferential thermal gradients were negligible.

Induction of subterahertz surface waves on a metal wire by intense laser interaction with a foil

NASA Astrophysics Data System (ADS)

Teramoto, Kensuke; Inoue, Shunsuke; Tokita, Shigeki; Yasuhara, Ryo; Nakamiya, Yoshihide; Nagashima, Takeshi; Mori, Kazuaki; Hashida, Masaki; Sakabe, Shuji

2018-02-01

We have demonstrated that a pulsed electromagnetic wave (Sommerfeld wave) of subterahertz frequency and 11-MV/m field strength can be induced on a metal wire by the interaction of an intense femtosecond laser pule with an adjacent metal foil at a laser intensity of 8.5 × 1018W /c m2 . The polarity of the electric field of this surface wave is opposite to that obtained by the direct interaction of the laser with the wire. Numerical simulations suggest that an electromagnetic wave associated with electron emission from the foil induces the surface wave. A tungsten wire is placed normal to an aluminum foil with a gap so that the wire is not irradiated and damaged by the laser pulse, thus making it possible to generate surface waves on the wire repeatedly.

Compliant Foil Journal Bearing Performance at Alternate Pressures and Temperatures

NASA Technical Reports Server (NTRS)

Bruckner, Robert J.; Puleo, Bernadette J.

2008-01-01

An experimental test program has been conducted to determine the highly loaded performance of current generation gas foil bearings at alternate pressures and temperatures. Typically foil bearing performance has been reported at temperatures relevant to turbomachinery applications but only at an ambient pressure of one atmosphere. This dearth of data at alternate pressures has motivated the current test program. Two facilities were used in the test program, the ambient pressure rig and the high pressure rig. The test program utilized a 35 mm diameter by 27 mm long foil journal bearing having an uncoated Inconel X-750 top foil running against a shaft with a PS304 coated journal. Load capacity tests were conducted at 3, 6, 9, 12, 15, 18, and 21 krpm at temperatures from 25 to 500 C and at pressures from 0.1 to 2.5 atmospheres. Results show an increase in load capacity with increased ambient pressure and a reduction in load capacity with increased ambient temperature. Below one-half atmosphere of ambient pressure a dramatic loss of load capacity is experienced. Additional lightly loaded foil bearing performance in nitrogen at 25 C and up to 48 atmospheres of ambient pressure has also been reported. In the lightly loaded region of operation the power loss increases for increasing pressure at a fixed load. Knowledge of foil bearing performance at operating conditions found within potential machine applications will reduce program development risk of future foil bearing supported turbomachines.

Bending fatigue of electron-beam-welded foils. Application to a hydrodynamic air bearing in the Chrysler/DOE upgraded automotive gas tubine engine

NASA Technical Reports Server (NTRS)

Saltsman, J. F.; Halford, G. R.

1984-01-01

A hydrodynamic air bearing with a compliment surface is used in the gas generator of an upgraded automotive gas turbine engine. In the prototype design, the compliant surface is a thin foil spot welded at one end to the bearing cartridge. During operation, the foil failed along the line of spot welds which acted as a series of stress concentrators. Because of its higher degree of geometric uniformity, electron beam welding of the foil was selected as an alternative to spot welding. Room temperature bending fatigue tests were conducted to determine the fatigue resistance of the electron beam welded foils. Equations were determined relating cycles to crack initiation and cycles to failure to nominal total strain range. A scaling procedure is presented for estimating the reduction in cyclic life when the foil is at its normal operating temperature of 260 C (500 F).

Studies of Surface Charging of Polymers by Indirect Triboelectrification

NASA Astrophysics Data System (ADS)

Mantovani, James; Calle, Carlos; Groop, Ellen; Buehler, Martin

2001-03-01

Charge is known to develop on the surface of an insulating polymer by frictional charging through direct physical contact with another material. We will present results of recent triboelectrification studies of polymer surfaces that utilized an indirect method of frictional charging. This method first involves placing a grounded thin metal foil in stationary contact over the polymer surface. The exposed metal foil is then rubbed with the surface of the material that generates the triboelectric charge. Data is presented for five types of polymers: fiberglass/epoxy, polycarbonate (Lexan), polytetraflouroethylene (Teflon), Rulon J, and polymethylmethacrylate (PMMA, Lucite). The amount of charge that develops on an insulator's surface is measured using the MECA Electrometer, which was developed jointly by NASA Kennedy Space Center and the Jet Propulsion Laboratory to study the electrostatic properties of soil on the surface of Mars. Even though the insulator's surface is electrically shielded from the rubbing material by the grounded metal foil, charge measurements obtained by the MECA Electrometer after the metal foil is separated from the insulator's surface reveal that the insulator's surface does accumulate charge by indirect frictional charging. A possible explanation of the observations will be presented based on a simple contact barrier model.

High Capacity Cathode and Carbon Nanotube-Supported Anode for Enhanced Energy Density Batteries

DTIC Science & Technology

2017-09-07

energy density of typical lithium ion cells and enables twice the run time or a reduction of cell mass by 50%. This work investigated a variety of...foil for the anode) by a doctor blade on one or both sides of the foil. The composite is dried in a vacuum oven, then calendared to compress the...composite slurry was coated onto the MWCNT paper using a doctor blade . The electrode was then dried overnight in a vacuum oven at 100°C and

Graphene Oxide-Based Nanocomposites Decorated with Silver Nanoparticles as an Antibacterial Agent

NASA Astrophysics Data System (ADS)

Jaworski, Sławomir; Wierzbicki, Mateusz; Sawosz, Ewa; Jung, Anna; Gielerak, Grzegorz; Biernat, Joanna; Jaremek, Henryk; Łojkowski, Witold; Woźniak, Bartosz; Wojnarowicz, Jacek; Stobiński, Leszek; Małolepszy, Artur; Mazurkiewicz-Pawlicka, Marta; Łojkowski, Maciej; Kurantowicz, Natalia; Chwalibog, André

2018-04-01

One of the most promising methods against drug-resistant bacteria can be surface-modified materials with biocidal nanoparticles and nanocomposites. Herein, we present a nanocomposite with silver nanoparticles (Ag-NPs) on the surface of graphene oxide (GO) as a novel multifunctional antibacterial and antifungal material. Ultrasonic technologies have been used as an effective method of coating polyurethane foils. Toxicity on gram-negative bacteria ( Escherichia coli), gram-positive bacteria ( Staphylococcus aureus and Staphylococcus epidermidis), and pathogenic yeast ( Candida albicans) was evaluated by analysis of cell morphology, assessment of cell viability using the PrestoBlue assay, analysis of cell membrane integrity using the lactate dehydrogenase assay, and reactive oxygen species production. Compared to Ag-NPs and GO, which have been widely used as antibacterial agents, our nanocomposite shows much higher antimicrobial efficiency toward bacteria and yeast cells.

Graphene Oxide-Based Nanocomposites Decorated with Silver Nanoparticles as an Antibacterial Agent.

PubMed

Jaworski, Sławomir; Wierzbicki, Mateusz; Sawosz, Ewa; Jung, Anna; Gielerak, Grzegorz; Biernat, Joanna; Jaremek, Henryk; Łojkowski, Witold; Woźniak, Bartosz; Wojnarowicz, Jacek; Stobiński, Leszek; Małolepszy, Artur; Mazurkiewicz-Pawlicka, Marta; Łojkowski, Maciej; Kurantowicz, Natalia; Chwalibog, André

2018-04-23

One of the most promising methods against drug-resistant bacteria can be surface-modified materials with biocidal nanoparticles and nanocomposites. Herein, we present a nanocomposite with silver nanoparticles (Ag-NPs) on the surface of graphene oxide (GO) as a novel multifunctional antibacterial and antifungal material. Ultrasonic technologies have been used as an effective method of coating polyurethane foils. Toxicity on gram-negative bacteria (Escherichia coli), gram-positive bacteria (Staphylococcus aureus and Staphylococcus epidermidis), and pathogenic yeast (Candida albicans) was evaluated by analysis of cell morphology, assessment of cell viability using the PrestoBlue assay, analysis of cell membrane integrity using the lactate dehydrogenase assay, and reactive oxygen species production. Compared to Ag-NPs and GO, which have been widely used as antibacterial agents, our nanocomposite shows much higher antimicrobial efficiency toward bacteria and yeast cells.

Experimental demonstration of laser imprint reduction using underdense foams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delorme, B.; Casner, A.; CELIA, University of Bordeaux-CNRS-CEA, F-33400 Talence

2016-04-15

Reducing the detrimental effect of the Rayleigh-Taylor (RT) instability on the target performance is a critical challenge. In this purpose, the use of targets coated with low density foams is a promising approach to reduce the laser imprint. This article presents results of ablative RT instability growth measurements, performed on the OMEGA laser facility in direct-drive for plastic foils coated with underdense foams. The laser beam smoothing is explained by the parametric instabilities developing in the foam and reducing the laser imprint on the plastic (CH) foil. The initial perturbation pre-imposed by the means of a specific phase plate wasmore » shown to be smoothed using different foam characteristics. Numerical simulations of the laser beam smoothing in the foam and of the RT growth are performed with a suite of paraxial electromagnetic and radiation hydrodynamic codes. They confirmed the foam smoothing effect in the experimental conditions.« less

High-Z Coating Experiments on Omega EP

NASA Astrophysics Data System (ADS)

Karasik, Max; Oh, J.; Stoeckl, C.; Schmitt, A. J.; Aglitskiy, Y.; Obenschain, S. P.

2016-10-01

Previous experiments on Nike KrF laser (λ=248nm) at NRL found that a thin (400-800 Å) high-Z (Au or Pd) overcoat on the target is effective in suppressing broadband imprint. Implementation of this technique on the tripled Nd:glass (351nm) NIF would enable higher uniformity direct-drive experiments there. To this end, we are carrying out experiments using the NIF-like beams of Omega EP. On Nike, a low-intensity, highly smooth prepulse heats and pre-expands the low thermal mass metallic coating to 100 um scale length. This likely improves imprint reduction for longer spatial scales because of increased distance between laser absorption and the ablation surface. The 3 ω beams of Omega EP do not have this feature due to nonlinear harmonic conversion. We introduced a means of pre-expanding the high-Z coating to similar length scale on Omega EP using a soft x-ray prepulse, generated by irradiating an auxiliary Au foil 1cm in front of the main target tens of ns prior to the main target drive. Coating dynamics are measured using side-on radiography. The effectiveness of pre-expansion on imprint reduction will be assessed by measurements of the RT-amplified imprint using monochromatic curved crystal radiography. Work supported by the Department of Energy/NNSA.

Bearings: Technology and needs

NASA Technical Reports Server (NTRS)

Anderson, W. J.

1982-01-01

A brief status report on bearing technology and present and near-term future problems that warrant research support is presented. For rolling element bearings a material with improved fracture toughness, life data in the low Lambda region, a comprehensive failure theory verified by life data and incorporated into dynamic analyses, and an improved corrosion resistant alloy are perceived as important needs. For hydrodynamic bearings better definition of cavitation boundaries and pressure distributions for squeeze film dampers, and geometry optimization for minimum power loss in turbulent film bearings are needed. For gas film bearings, foil bearing geometries that form more nearly optimum film shapes for maximum load capacity, and more effective surface protective coatings for high temperature operation are needed.

Novel target design for enhanced laser driven proton acceleration

NASA Astrophysics Data System (ADS)

Dalui, Malay; Kundu, M.; Tata, Sheroy; Lad, Amit D.; Jha, J.; Ray, Krishanu; Krishnamurthy, M.

2017-09-01

We demonstrate a simple method of preparing structured target for enhanced laser-driven proton acceleration under target-normal-sheath-acceleration scheme. A few layers of genetically modified, clinically grown micron sized E. Coli bacteria cell coated on a thin metal foil has resulted in an increase in the maximum proton energy by about 1.5 times and the total proton yield is enhanced by approximately 25 times compared to an unstructured reference foil at a laser intensity of 1019 W/cm2. Particle-in-cell simulations on the system shows that the structures on the target-foil facilitates anharmonic resonance, contributing to enhanced hot electron production which leads to stronger accelerating field. The effect is observed to grow as the number of structures is increased in the focal area of the laser pulse.

Gas insulated transmission line having low inductance intercalated sheath

DOEpatents

Cookson, Alan H.

1978-01-01

A gas insulated transmission line including an outer sheath, an inner conductor disposed within the outer sheath, and an insulating gas between the inner conductor and the outer sheath. The outer sheath comprises an insulating tube having first and second ends, and having interior and exterior surfaces. A first electrically conducting foil is secured to the interior surface of the insulating tube, is spirally wound from one tube end to the second tube end, and has a plurality of overlapping turns. A second electrically conducting foil is secured to the exterior surface of the insulating tube, and is spirally wound in the opposite direction from the first electrically conducting foil. By winding the foils in opposite directions, the inductances within the intercalated sheath will cancel each other out.

Electrical properties of Al foil/n-4H-SiC Schottky junctions fabricated by surface-activated bonding

NASA Astrophysics Data System (ADS)

Morita, Sho; Liang, Jianbo; Matsubara, Moeko; Dhamrin, Marwan; Nishio, Yoshitaka; Shigekawa, Naoteru

2018-02-01

We fabricate 17-µm-thick Al foil/n-4H-SiC Schottky junctions by surface-activated bonding. Their current-voltage and capacitance-voltage characteristics are compared with those of Schottky junctions fabricated by evaporating Al layers on n-4H-SiC epilayers. We find that the ideality factor of Al foil/SiC junctions is larger than that of conventional junctions, which is due to the irradiation of the fast atom beam (FAB) of Ar. The ideality factor of Al foil/SiC junctions is improved by annealing at 400 °C. We also find that the Schottky barrier height is increased by FAB irradiation, which is likely to be due to the negative charges formed at SiC surfaces.

Spectrometry and filtering with high rejection of stray light

DOEpatents

Ferrell, Thomas L.; Thundat, Thomas G.

2004-12-14

A microoptoelectromechanical integrated spectrometer with a photonic element assembly having metal foil removably disposed on a first transparent substrate surface, the substrate having no foil on any other surface. A means is provided for directing source photons that are reflected from or transmitted through a sample, over a range of angles of incidence, into the transparent substrate and onto the metal foil such that source photons are incident at the Brewsters angle. A means is also provided for detecting an induced exponential field in the metal foil. A means is also provided for relating the induced exponential field to a known exponential field for the sample and determining the identity of the sample. The spectrometer performs ultraviolet-to-visible-to-infrared spectroscopy using photon tunneling and surface plasmon excitation.

Multi-dimensional effects in radiation pressure acceleration of ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tripathi, V. K., E-mail: tripathivipin@yahoo.co.in

A laser carries momentum. On reflection from an ultra-thin overdense plasma foil, it deposits recoil momentum on the foil, i.e. exerts radiation pressure on the foil electrons and pushes them to the rear. The space charge field thus created takes the ions along, accelerating the electron-ion double layer as a single unit. When the foil has surface ripple, of wavelength comparable to laser wavelength, the radiation pressure acts non-uniformly on the foil and the perturbation grows as Reyleigh-Taylor (RT) instability as the foil moves. The finite spot size of the laser causes foil to bend. These effects limit the quasi-monomore » energy acceleration of ions. Multi-ion foils, e.g., diamond like carbon foil embedded with protons offer the possibility of suppressing RT instability.« less

Fabrication and icing property of superhydrophilic and superhydrophobic aluminum surfaces derived from anodizing aluminum foil in a sodium chloride aqueous solution

NASA Astrophysics Data System (ADS)

Song, Meirong; Liu, Yuru; Cui, Shumin; Liu, Long; Yang, Min

2013-10-01

An aluminum foil with a rough surface was first prepared by anodic treatment in a neutral aqueous solution with the help of pitting corrosion of chlorides. First, the hydrophobic Al surface (contact angle around 79°) became superhydrophilic (contact angle smaller than 5°) after the anodizing process. Secondly, the superhydrophilic Al surface became superhydrophobic (contact angle larger than 150°) after being modified by oleic acid. Finally, the icing property of superhydrophilic, untreated, and superhydrophobic Al foils were investigated in a refrigerated cabinet at -12 °C. The mean total times to freeze a water droplet (6 μL) on the three foils were 17 s, 158 s and 1604 s, respectively. Thus, the superhydrophilic surface accelerates the icing process, while the superhydrophobic surface delays the process. The main reason for this transition might mainly result from the difference of the contact area of the water droplet with Al substrate: the increase in contact area with Al substrate will accelerate the heat conduct process, as well as the icing process; the decrease in contact area with Al substrate will delay the heat conduct process, as well as the icing process. Compared to the untreated Al foil, the contact area of the water droplet with the Al substrate was higher on superhydrophilic surface and smaller on the superhydrophobic surface, which led to the difference of the heat transfer time as well as the icing time.

Preparation and investigation of diamond-like carbon stripper foils by filtered cathodic vacuum arc

NASA Astrophysics Data System (ADS)

Fan, Qiwen; Du, Yinghui; Zhang, Rong; Xu, Guoji

2013-04-01

Thin diamond-like carbon (DLC) stripper foils ˜5 μg/cm2 in thickness were produced and evaluated as heavy-ion strippers for the Beijing HI-13 Tandem Accelerator. The DLC layers ˜4 μg/cm2 in thickness were produced by the filtered cathodic vacuum arc technology onto glass slides coated with betaine-saccharose as releasing agent, which were previously covered with evaporated carbon layers ˜1 μg/cm2 in thickness by the controlled ac arc-discharge method. Irradiation lifetimes of the DLC stripper foils were tested using the heavy-ion beams at the terminal of the Beijing HI-13 Tandem Accelerator, and compared with those of the standard carbon stripper foils made by the combined dc and ac arc-discharge method. The measurements indicate that the DLC stripper foils outlast the standard combined dc and ac arc-discharge carbon stripper foils by a factor of at least 13 and 4for the 197Au- (˜9 MeV, ˜1 μA) and 63Cu- (˜9 MeV, ˜1 μA) ion beams, respectively. The structure and properties of the DLC foils deposited onto silicon substrates by the filtered cathodic vacuum arc technology were also evaluated and analyzed by scanning electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The scanning electron microscopy images show that the DLC foils contain hardly droplets through the double 90° filters. The X-ray photoelectron spectrum indicates that sp3 bonds of the DLC foils exceed 70%. The integral intensity ratio of the D peak to the G peak (ID/IG) measured by the Raman spectroscopy is0.78.

System Being Developed to Measure the Rotordynamic Characteristics of Air Foil Bearings

NASA Technical Reports Server (NTRS)

Howard, Samuel A.; DellaCorte, Christopher; Valco, Mark J.

2000-01-01

Because of the many possible advantages of oil-free engine operation, interest in using air lubricated foil-bearing technology in advanced oil-free engine concepts has recently increased. The Oil-Free Turbomachinery Program at the NASA Glenn Research Center at Lewis Field has partially driven this recent push for oil-free technology. The program's goal of developing an innovative, practical, oil-free gas turbine engine for aeropropulsion began with the development of NASA's high-temperature solid-lubricant coating, PS304. This coating virtually eliminates the life-limiting wear that occurs during the startup and shutdown of the bearings. With practically unlimited life, foil air bearings are now very attractive to rotating machinery designers for use in turbomachinery. Unfortunately, the current knowledge base of these types of bearings is limited. In particular, the understanding of how these types of bearings contribute to the rotordynamic stability of turbomachinery is insufficient for designers to design with confidence. Recent work in oil-free turbomachinery has concentrated on advancing the understanding of foil bearings. A high-temperature fiber-optic displacement probe system and measurement method were developed to study the effects of speed, load, temperature, and other environmental issues on the stiffness characteristics of air foil bearings. Since high temperature data are to be collected in future testing, the testing method was intentionally simplified to minimize the need for expensive test hardware. The method measures the displacement induced upon a bearing in response to an applied perturbation load. The early results of these studies, which are shown in the accompanying figure, indicate trends in steady state stiffness that suggest stiffness increases with load and decreases with speed. It can be seen, even from these data, that stiffness is not expected to change by orders of magnitude over the normal operating range of most turbomachinery; a promising sign for their eventual integration into oil-free turbomachines. Planned future testing will generate similar plots for stiffness changes with temperature and geometry, as well as damping data. The data collected by this method represent a critical step toward understanding how to successfully apply foil air bearings to future oil-free turbomachinery systems.

Multilayer Regulation of Atomic Boron Nitride Films to Improve Oxidation and Corrosion Resistance of Cu.

PubMed

Ren, Siming; Cui, Mingjun; Pu, Jibin; Xue, Qunji; Wang, Liping

2017-08-16

The boron nitride (BN) monolayer (1L) with high impermeability and resistivity seems to hold promise as a long-term corrosion barrier for Cu under ambient condition, which is supported by recent researches. Here, we perform a complete study of the alternating temperature tests (the sample is exposed in air for 30 days and subsequently heated at 200 °C for 2 h) and electrochemical measurements on 1L and multilayer BN-coated Cu foils. Results imply that the BN-coated Cu foils are less oxidized than uncoated Cu foils after alternating temperature tests, regardless of the layers of BN. Particularly, the oxidation process proceeds slowly in multilayers because most of the underlying defects are covered with BN layers to suppress the oxygen diffusion in the vertical direction and the oxidation mainly occurs on the wrinkled region of BN films. Electrochemical analyses reveal that the BN layers provide an effective physical barrier against the corrosive medium and inhibit the electron diffusion because of their high electrical insulating behavior and the corrosion resistance of the samples increases with increasing BN layers. These findings indicate that BN films with adequate layers are good candidates for oxidation and corrosion protection at the atomic level, which is vital to many industrial and academic applications.

Treatment of poly(ethylene terephthalate) foils by atmospheric pressure air dielectric barrier discharge and its influence on cell growth

NASA Astrophysics Data System (ADS)

Kuzminova, Anna; Vandrovcová, Marta; Shelemin, Artem; Kylián, Ondřej; Choukourov, Andrei; Hanuš, Jan; Bačáková, Lucie; Slavínská, Danka; Biederman, Hynek

2015-12-01

In this contribution an effect of dielectric barrier discharge (DBD) sustained in air at atmospheric pressure on surface properties of poly(ethylene terephthalate) (PET) foils is studied. It is found that exposure of PET to DBD plasma leads to rapid changes of surface chemical composition, wettability, surface morphology as well as mechanical properties of PET surface. In addition, based on biological tests that were performed using two cell types (Saos-2 human osteoblast-like cells and HUVEC human umbilical vein endothelial cells), it may be concluded that DBD plasma treatment positively influences cell growth on PET. This effect was found to be connected predominantly with increased surface energy and oxygen content of the surface of treated PET foils.

Final Report: Posttest Analysis of Omega II Optical Specimens

DOE Office of Scientific and Technical Information (OSTI.GOV)

Newlander, C D; Fisher, J H

Preliminary posttest analyses have been completed on optical specimens exposed during the Omega II test series conducted on 14 July 2006. The Omega Facility, located at the Laboratory for Laser Energetics (LLE) at the University of Rochester was used to produce X-ray environments through the interaction of intense pulsed laser radiation upon germanium-loaded silica aerogels. The optical specimen testing was supported by GH Systems through experiment design, pre- and post-test analyses, specimen acquisition, and overall technical experience. The test specimens were fabricated and characterized by Surface Optics Corporation (SOC), San Diego, CA and were simple protected gold coatings on silicamore » substrates. Six test specimens were exposed, five filtered with thin beryllium foil filters, and one unfiltered which was exposed directly to the raw environment. The experimental objectives were: (1) demonstrate that tests of optical specimens could be performed at the Omega facility; (2) evaluate the use and survivability of beryllium foil filters as a function of thickness; (3) obtain damage data on optical specimens which ranged from no damage to damage; (4) correlate existing thermal response models with the damage data; (5) evaluate the use of the direct raw environment upon the specimen response and the ability/desirability to conduct sensitive optical specimen tests using the raw environment; and (6) initiate the development of a protocol for performing optical coatings/mirror tests. This report documents the activities performed by GH Systems in evaluating and using the environments provided by LLNL, the PUFFTFT analyses performed using those environments, and the calculated results compared to the observed and measured posttest data.« less

Braze system and method for reducing strain in a braze joint

DOEpatents

Cadden, Charles H.; Goods, Steven H.; Prantil, Vincent C.

2004-05-11

A system for joining a pair of structural members having widely differing coefficients of thermal expansion is disclosed. A mechanically "thick" foil is made by dispersing a refractory metal powder, such as molybdenum, niobium, tantalum, or tungsten into a quantity of a liquid, high expansion metal such as copper, silver, or gold, casting an ingot of the mixture, and then cutting sections of the ingot about 1 mm thick to provide the foil member. These foil members are shaped, and assembled between surfaces of structural members for joining, together with a layer of a braze alloy on either side of the foil member capable of wetting both the surfaces of the structural members and the foil. The assembled body is then heated to melt the braze alloy and join the assembled structure. The foil member subsequently absorbs the mechanical strain generated by the differential contraction of the cooling members that results from the difference in the coefficients of thermal expansion of the members.

Method of high-density foil fabrication

DOEpatents

Blue, Craig A.; Sikka, Vinod K.; Ohriner, Evan K.

2003-12-16

A method for preparing flat foils having a high density includes the steps of mixing a powdered material with a binder to form a green sheet. The green sheet is exposed to a high intensity radiative source adapted to emit radiation of wavelengths corresponding to an absorption spectrum of the powdered material. The surface of the green sheet is heated while a lower sub-surface temperature is maintained. An apparatus for preparing a foil from a green sheet using a radiation source is also disclosed.

A dilute Cu(Ni) alloy for synthesis of large-area Bernal stacked bilayer graphene using atmospheric pressure chemical vapour deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Madito, M. J.; Bello, A.; Dangbegnon, J. K.

2016-01-07

A bilayer graphene film obtained on copper (Cu) foil is known to have a significant fraction of non-Bernal (AB) stacking and on copper/nickel (Cu/Ni) thin films is known to grow over a large-area with AB stacking. In this study, annealed Cu foils for graphene growth were doped with small concentrations of Ni to obtain dilute Cu(Ni) alloys in which the hydrocarbon decomposition rate of Cu will be enhanced by Ni during synthesis of large-area AB-stacked bilayer graphene using atmospheric pressure chemical vapour deposition. The Ni doped concentration and the Ni homogeneous distribution in Cu foil were confirmed with inductively coupledmore » plasma optical emission spectrometry and proton-induced X-ray emission. An electron backscatter diffraction map showed that Cu foils have a single (001) surface orientation which leads to a uniform growth rate on Cu surface in early stages of graphene growth and also leads to a uniform Ni surface concentration distribution through segregation kinetics. The increase in Ni surface concentration in foils was investigated with time-of-flight secondary ion mass spectrometry. The quality of graphene, the number of graphene layers, and the layers stacking order in synthesized bilayer graphene films were confirmed by Raman and electron diffraction measurements. A four point probe station was used to measure the sheet resistance of graphene films. As compared to Cu foil, the prepared dilute Cu(Ni) alloy demonstrated the good capability of growing large-area AB-stacked bilayer graphene film by increasing Ni content in Cu surface layer.« less

A dilute Cu(Ni) alloy for synthesis of large-area Bernal stacked bilayer graphene using atmospheric pressure chemical vapour deposition

NASA Astrophysics Data System (ADS)

Madito, M. J.; Bello, A.; Dangbegnon, J. K.; Oliphant, C. J.; Jordaan, W. A.; Momodu, D. Y.; Masikhwa, T. M.; Barzegar, F.; Fabiane, M.; Manyala, N.

2016-01-01

A bilayer graphene film obtained on copper (Cu) foil is known to have a significant fraction of non-Bernal (AB) stacking and on copper/nickel (Cu/Ni) thin films is known to grow over a large-area with AB stacking. In this study, annealed Cu foils for graphene growth were doped with small concentrations of Ni to obtain dilute Cu(Ni) alloys in which the hydrocarbon decomposition rate of Cu will be enhanced by Ni during synthesis of large-area AB-stacked bilayer graphene using atmospheric pressure chemical vapour deposition. The Ni doped concentration and the Ni homogeneous distribution in Cu foil were confirmed with inductively coupled plasma optical emission spectrometry and proton-induced X-ray emission. An electron backscatter diffraction map showed that Cu foils have a single (001) surface orientation which leads to a uniform growth rate on Cu surface in early stages of graphene growth and also leads to a uniform Ni surface concentration distribution through segregation kinetics. The increase in Ni surface concentration in foils was investigated with time-of-flight secondary ion mass spectrometry. The quality of graphene, the number of graphene layers, and the layers stacking order in synthesized bilayer graphene films were confirmed by Raman and electron diffraction measurements. A four point probe station was used to measure the sheet resistance of graphene films. As compared to Cu foil, the prepared dilute Cu(Ni) alloy demonstrated the good capability of growing large-area AB-stacked bilayer graphene film by increasing Ni content in Cu surface layer.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jankowski, A.F.; Hayes, J.P.; Kanna, R.L.

The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer.more » A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.« less

Carnage interrupted : an analysis of fifteen terrorist plots against public surface transportation.

DOT National Transportation Integrated Search

2012-04-01

This report examines 13 terrorist plots against public surface transportation that were uncovered and foiled by authorities between 1997 and 2010 and two failed attempts to carry out attacks. Certainly, this is not the total universe of foiled or fai...

Achieving Stable Radiation Pressure Acceleration of Heavy Ions via Successive Electron Replenishment from Ionization of a High-Z Material Coating

NASA Astrophysics Data System (ADS)

Qiao, Bin; Shen, X. F.; Zhang, H.; Kar, S.; Zhou, C. T.; Chang, H. X.; Borghesi, M.; He, X. T.

2017-10-01

Among various laser-driven acceleration schemes, radiation pressure acceleration (RPA) is regarded as one of the most promising schemes to obtain high-quality ion beams. Although RPA is very attractive in principle, it is difficult to be achieved experimentally. One of the most important reasons is the dramatic growth of the multi-dimensional Rayleigh-Taylor-like (RT) instabilities. In this talk, we report a novel method to achieve stable RPA of ions from laser-irradiated ultrathin foils, where a high-Z material coating in front is used. The coated high-Z material, acting as a moving electron repository, continuously replenishes the accelerating ion foil with comoving electrons in the light-sail acceleration stage due to its successive ionization under laser fields with Gaussian temporal profile. As a result, the detrimental effects such as electron loss induced by the RT and other instabilities are significantly offset and suppressed so that stable acceleration of ions are maintained. Supported by the NSAF, Grant No. U1630246; the NNSF China Grants No. 11575298; and the National Key Program of S&T Research and Development, Grant No. 2016YFA0401100.

Long lifetime hollow cathodes for 30-cm mercury ion thrusters

NASA Technical Reports Server (NTRS)

Mirtich, M. J.; Kerslake, W. R.

1976-01-01

An experimental investigation of hollow cathodes for 30-cm Hg bombardment thrusters was carried out. Both main and neutralizer cathode configurations were tested with both rolled foil inserts coated with low work function material and impregnated porous tungsten inserts. Temperature measurements of an impregnated insert at various positions in the cathode were made. These, along with the cathode thermal profile are presented. A theory for rolled foil and impregnated insert operation and lifetime in hollow cathodes is developed. Several endurance tests, as long as 18000 hours at emission currents of up to 12 amps were attained with no degradation in performance.

Applying a potential difference to minimise damage to carbon fibres during carbon nanotube grafting by chemical vapour deposition.

PubMed

Anthony, David B; Qian, Hui; Clancy, Adam J; Greenhalgh, Emile S; Bismarck, Alexander; Shaffer, Milo S P

2017-07-28

The application of an in situ potential difference between carbon fibres and a graphite foil counter electrode (300 V, generating an electric field ca 0.3-0.7 V μm -1 ), during the chemical vapour deposition synthesis of carbon nanotube (CNT) grafted carbon fibres, significantly improves the uniformity of growth without reducing the tensile properties of the underlying carbon fibres. Grafted CNTs with diameters 55 nm ± 36 nm and lengths around 10 μm were well attached to the carbon fibre surface, and were grown without the requirement for protective barrier coatings. The grafted CNTs increased the surface area to 185 m 2 g -1 compared to the as-received sized carbon fibre 0.24 m 2 g -1 . The approach is not restricted to batch systems and has the potential to improve CNT grafted carbon fibre production for continuous processing.

Multilayer coatings for flexible high-barrier materials

NASA Astrophysics Data System (ADS)

Vaško, Karol; Noller, Klaus; Mikula, Milan; Amberg-Schwab, Sabine; Weber, Ulrike

2009-06-01

A multilayer, flexible, and transparent high-barrier system based on flexible plastic foils, polyethyleneterephthalate (PET) and ethylene-tetrafluoroethylene-copolymer (ETFE), combined with vacuum-deposited, inorganic SiOx layers and hybrid ORMOCER® varnish layers were prepared in different orders on a semiproduction level. Barrier properties of prepared systems, as water vapour transmission (WVTR) and oxygen transmission (OTR), were measured and studied in connection with surface energy, surface topography, and water vapour adsorption properties. Correlations among layers sequence, barrier properties, and other parameters are presented, including some basic principles of permeation of substances through multilayer barrier systems. A combination of several inorganic and hybrid varnish layers is necessary to achieve the technological demands from a barrier standpoint. It is easier to suppress the oxygen transport than the water transport, due to the additional active penetration of water through hydrogen bonds and silanol creations at oxide interfaces, capillary condensation, and swelling with high internal pressure, leading to new defects.

Candidate materials for advanced fire-resistant photovoltaic modules

NASA Technical Reports Server (NTRS)

Sugimura, R. S.; Otth, D. H.; Ross, R. G., Jr.; Arnett, J. C.; Samuelson, G.

1985-01-01

A cooperative, cost-sharing research effort to develop a technology base required to construct fire-ratable photovoltaic modules has resulted in the identification of several high-temperature, back-surface candidate materials capable of raising the fire-resistance of modules using hydrocarbon encapsulants to Class A and B levels. Advanced experimental module configurations have been developed using back surfaces consisting of Kapton, Tedlar laminates, metal-foils, and fiberglass materials with high-temperature coatings. Test results (October 1984; March 1985; May 1985; and October 1985) indicate that several of these advanced module configurations are capable of achieving Class B fire-resistance levels, while a few configurations can achieve Class A levels. The paper summarizes activities to date, discussing flammability failure mechanisms, time-temperature profiles, and results of Block V environmental exposure tests of a candidate material suitable for both Class B and Class A fire-resistance levels.

Applying a potential difference to minimise damage to carbon fibres during carbon nanotube grafting by chemical vapour deposition

NASA Astrophysics Data System (ADS)

Anthony, David B.; Qian, Hui; Clancy, Adam J.; Greenhalgh, Emile S.; Bismarck, Alexander; Shaffer, Milo S. P.

2017-07-01

The application of an in situ potential difference between carbon fibres and a graphite foil counter electrode (300 V, generating an electric field ca 0.3-0.7 V μm-1), during the chemical vapour deposition synthesis of carbon nanotube (CNT) grafted carbon fibres, significantly improves the uniformity of growth without reducing the tensile properties of the underlying carbon fibres. Grafted CNTs with diameters 55 nm ± 36 nm and lengths around 10 μm were well attached to the carbon fibre surface, and were grown without the requirement for protective barrier coatings. The grafted CNTs increased the surface area to 185 m2 g-1 compared to the as-received sized carbon fibre 0.24 m2 g-1. The approach is not restricted to batch systems and has the potential to improve CNT grafted carbon fibre production for continuous processing.

SUMMARY OF THE SEVENTH MEETING OF THE REFRACTORY COMPOSITES WORKING GROUP

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gibeaut, W.A.; Ogden, H.R.

1963-05-30

Information on refractory composites for use above 2500 deg F is summarized. Reports are concerned with protective coatings, insulating ceramics, materials for rocket thrust chambers, dispersion strengthening of metals, joining of refractory materials, and testing techniques. The problem of accelerated failure of silicide coatings under conditions of very low air pressure at high temperatures is studied. Although the maximum temperature capability of most silicide coatings is reduced about 50 theta deg at low air pressures, several coatings can protect molybdenum for 1/2 hr at 2800 to 3000 deg F under these conditions. The tin-aluminum coating also is susceptible to earlymore » failure at reduced pressure. An evaluation of the mechanical properties of 6-mil foils of D- 36, B-68, and TZM coated with commercial coatings demonstrated that some coatings seriously degrade substrate mechanical properties. Research on thermal- protection systems for re-entry vehicles whose surface temperatures reach from 3300 to 5500 deg F has resulted in agreement upon oxide coatings and thick metal- reinforced oxide composites. Simple plasmaarc-sprayed oxide coatings have demonstrated adequate oxidation resistance, but their structural stability in cyclic thermal exposure is inferior to metal-reinforced oxide. Thin unreinforced oxide coatings tend to spall in tests involving cyclic heating. A metal- reinforced oxide composite (reinforcement welded to substrate) has survived cyclic tests such as five 3-minute exposures at 4500 deg F without failing. A new carbon material called glassy carbon has demonstrnted better oxidation resistance than pyrolytic graphite at very high temperatures. The erosion resistance of pyrolytic graphite coatings on regular graphite in rocket firing tests using solid propellants is encouraging. There is considerable interest in fabricating small radiation-cooled rocket thrust chambers by plasma arc spraying. The design concept of internal reinforcement of sprayed-metal rocket chambers with wrought ductile wife appears impractical because of poor bonding and porosity around the wire. (auth)« less

Crystallographic texture of straight-rolled ?-uranium foils via neutron and X-ray diffraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Einhorn, J. R.; Steiner, M. A.; Vogel, S. C.

The texture of recrystallized straight-rolled ?-uranium foils, a component in prospective irradiation target designs for medical isotope production, has been measured by neutron diffraction, as well as X-ray diffraction using both Cu and Mo sources. Variations in the penetration depth of neutron and X-ray radiation allow for determination of both the bulk and surface textures. The bulk ?-uranium foil texture is similar to the warm straight-rolled plate texture, with the addition of a notable splitting of the (001) poles along the transverse direction. The surface texture of the foils is similar to the bulk, with an additional (001) texture componentmore » that is oriented between the rolling and normal directions. Differences between the surface and bulk textures are expected to arise from shear forces during the rolling process and the influence that distinct strain histories have on subsequent texture evolution during recrystallization.« less

Crystallographic texture of straight-rolled ?-uranium foils via neutron and X-ray diffraction

DOE PAGES

Einhorn, J. R.; Steiner, M. A.; Vogel, S. C.; ...

2017-05-25

The texture of recrystallized straight-rolled ?-uranium foils, a component in prospective irradiation target designs for medical isotope production, has been measured by neutron diffraction, as well as X-ray diffraction using both Cu and Mo sources. Variations in the penetration depth of neutron and X-ray radiation allow for determination of both the bulk and surface textures. The bulk ?-uranium foil texture is similar to the warm straight-rolled plate texture, with the addition of a notable splitting of the (001) poles along the transverse direction. The surface texture of the foils is similar to the bulk, with an additional (001) texture componentmore » that is oriented between the rolling and normal directions. Differences between the surface and bulk textures are expected to arise from shear forces during the rolling process and the influence that distinct strain histories have on subsequent texture evolution during recrystallization.« less

Field Trials of Attenuated Salmonella Typhi Live Oral Vaccine TY21A in Liquid and Enteric-Coated Capsule Formulations in Santiago, Chile

DTIC Science & Technology

1990-06-01

inactive piacebo, children in the control group received viable Lactobacillus acidophilus because some experimental data suggest that L. acidophilus may...was the enteric-coating used to make the capsules acid-resistant. Such capsules, each containing 1-3 x 109 viable vaccine (or Lactobacillus ) organisms...formulation of vaccine (or of the Lactobacillus control preparation) consisted of two aluminum foil packets, one containing lyophilized vaccine (or

Nanostructured Coatings with Self-Healing and Temperature Homogenization Functions for High Temperature Sliding Interfaces

DTIC Science & Technology

2010-10-01

showing the stainless steel chamber (A), the rotatable substrate holder (B), the plasma burning between substrate holder and magnetrons (C) and three...Final Report University of Leoben, Austria 3 The sputtering system consists of a cylindrical stainless steel chamber (Ø 380 x 235mm) (A) which...are used. All coatings were deposited on three different substrates: AlSI M2 high speed steel , Si (100) wafers, and Fe foil. M2 substrates which

Study of irradiated Hadfield steel using transmission Mössbauer spectroscopy with high velocity resolution and conversion electron Mössbauer spectroscopy

NASA Astrophysics Data System (ADS)

Semionkin, V. A.; Neshev, F. G.; Tsurin, V. A.; Milder, O. B.; Oshtrakh, M. I.

2010-03-01

Proton irradiated Hadfield steel foil was studied using transmission Mössbauer spectroscopy with high velocity resolution and conversion electron Mössbauer spectroscopy. It was shown that proton irradiation leads to structural changes in the foil as well as to surface oxidation with ferric hydrous oxide formation (ferrihydrite). Moreover, oxidation on the foil underside was higher than on the foil right side.

Foil Gas Thrust Bearings for High-Speed Turbomachinery

NASA Technical Reports Server (NTRS)

Edmonds, Brian; DellaCorte, Christopher; Dykas, Brian

2010-01-01

A methodology has been developed for the design and construction of simple foil thrust bearings intended for parametric performance testing and low marginal costs, supporting continued development of oil-free turbomachinery. A bearing backing plate is first machined and surface-ground to produce flat and parallel faces. Partial-arc slots needed to retain the foil components are then machined into the plate by wire electrical discharge machining. Slot thicknesses achievable by a single wire pass are appropriate to accommodate the practical range of foil thicknesses, leaving a small clearance in this hinged joint to permit limited motion. The backing plate is constructed from a nickel-based superalloy (Inconel 718) to allow heat treatment of the entire assembled bearing, as well as to permit hightemperature operation. However, other dimensionally stable materials, such as precipitation-hardened stainless steel, can also be used for this component depending on application. The top and bump foil blanks are cut from stacks of annealed Inconel X-750 foil by the same EDM process. The bump foil has several azimuthal slits separating it into five individual bump strips. This configuration allows for variable bump spacing, which helps to accommodate the effects of the varying surface velocity, thermal crowning, centrifugal dishing, and misalignment. Rectangular tabs on the foil blanks fit into the backing plate slots. For this application, a rather traditional set of conventionally machined dies is selected, and bump foil blanks are pressed into the dies for forming. This arrangement produces a set of bump foil dies for foil thrust bearings that provide for relatively inexpensive fabrication of various bump configurations, and employing methods and features from the public domain.

Design and Operation of a Calorimeter for Advanced Multilayer Insulation Testing

NASA Technical Reports Server (NTRS)

Chato, David J.; Johnson, Wesley L.; Van Dresar, Neil

2016-01-01

A calorimeter has been constructed to accurately measure insulation performance with a nominal 90K outer boundary and a 20K inner boundary. Unique features of this design include use of mechanical cryocoolers instead of cryogens and measurement of the heat load with a calibrated heat conduction rod. The calorimeter is operational and has completed its first test series. The initial test series was designed to look for differences in performance between a single layer of aluminum foil and a sheet of double aluminized Mylar (DAM). Although it has been speculated that the aluminum foil would perform better, since the aluminum coating on the Mylar might not be thick enough to stop the transmission of long wave length infrared radiation, our testing showed a higher heat load for the aluminum foil than the DAM. The aluminum foil showed a heat load of 132 mW at an 87 K outer temperature and 152 mW at a 107K outer temperature, whereas the DAM showed a heat load of 66 mW at an 88 K outer temperature and 81 mW at 108 K.

Design and Operation of a Calorimeter for Advanced Multilayer Insulation Testing

NASA Technical Reports Server (NTRS)

Chato, David; Johnson, Wesley; Dresar, Neil Van

2016-01-01

A calorimeter has been constructed to accurately measure insulation performance with a nominal 90K cold outer boundary and a 20K inner boundary. Unique features of this design include use of mechanical cryocoolers instead cryogens and measurement of the heat load with a calibrated rod to serve as a conduction path. The calorimeter is operational and has completed its first test series. The initial test series was designed to look for differences in performance between a single layer of aluminum foil and a sheet of double aluminized mylar (DAM). Although it has been speculated that the aluminum foil would perform better, since the mylar coating might not thick enough to stop the transmission of long wave length infrared radiation, our testing showed a higher heat load for the aluminum foil than the DAM. The aluminum foil showed a heat load of 132 mW at an 87 K outer temperature and 152 mW at a 107K outer temperature. Whereas the DAM showed a heat load of 66 mW at an 88 K outer temperature and 81 mW at 108 K.

Development of CIGS2 Thin Films on Ultralightweight Flexible Large Area Foil Sunstrates

NASA Technical Reports Server (NTRS)

Dhere, Neelkanth G.; Gade, Vivek S.; Kadam, Ankur A.; Jahagirdar, Anant H.; Kulkarni, Sachin S.; Bet, Sachin M.

2005-01-01

The development of thin film solar cells is aimed at reducing the costs for photovoltaic systems. Use of thin film technology and thin foil substrate such as 5-mil thick stainless steel foil or 1-mil thick Ti would result in considerable costs savings. Another important aspect is manufacturing cost. Current single crystal technology for space power can cost more than $ 300 per watt at the array level and weigh more than 1 kg/sq m equivalent to specific power of approx. 65 W/kg. Thin film material such as CuIn1-xGaxS2 (CIGS2), CuIn(1-x)Ga(x)Se(2-y)S(y) (CIGSS) or amorphous hydrogenated silicon (a-Si:H) may be able to reduce both the cost and mass per unit area by an order of magnitude. Manufacturing costs for solar arrays are an important consideration for total spacecraft budget. For a medium sized 5kW satellite for example, the array manufacturing cost alone may exceed $ 2 million. Moving to thin film technology could reduce this expense to less than $ 500K. Earlier publications have demonstrated the potential of achieving higher efficiencies from CIGSS thin film solar cells on 5-mil thick stainless steel foil as well as initial stages of facility augmentation for depositing thin film solar cells on larger (6 in x 4 in) substrates. This paper presents the developmental study of achieving stress free Mo coating; uniform coatings of Mo back contact and metallic precursors. The paper also presents the development of sol gel process, refurbishment of selenization/sulfurization furnace, chemical bath deposition (CBD) for n-type CdS and scrubber for detoxification of H2S and H2Se gases.

Effect of Liquid Feed-Stock Composition on the Morphology of Titanium Dioxide Films Deposited by Thermal Plasma Spray.

PubMed

Adán, C; Marugán, J; van Grieken, R; Chien, K; Pershin, L; Coyle, T; Mostaghimi, J

2015-09-01

Titanium dioxide coatings were deposited on the surface of titanium foils by Thermal Plasma Spray (TPS) process. Three different TiO2 coatings were prepared using the commercial TiO2-P25 nanopowder and titanium isopropoxide precursor solution as feed-stocks. Structure and morphology of the TiO2-P25 powder and the plasma sprayed coatings were analyzed by X-ray diffraction (XRD), Raman spectroscopy, N2 adsorption-desorption isotherms, UV-visible spectroscopy and Scanning Electron Microscopy (SEM). XRD and Raman results indicate that the TiO2 coatings were composed of an anatase/rutile mixture that is conditioned by the suspension composition used to be sprayed. Coatings prepared from TiO2-P25 nanoparticles in water suspension (NW-P25) and titanium isopropoxide solution suspension (NSP-P25) are incorporated into the coatings without phase transformation and their anatase/rutile ratio percentage remains very similar to the starting TiO2-P25 powder. On the contrary, when titanium isopropoxide solution is used for spraying (SP), the amount of rutile increases in the final TiO2 coating. SEM analysis also reveals different microstructure morphology, coating thickness, density and porosity of the three TiO2 films that depend significantly on the type of feed-stock employed. Interestingly, we have observed the role of titanium isopropoxide in the formation of more porous and cohesive layers of TiO2. The NSP-P25 coating, prepared with a mix of titanium isopropoxide solution based on TiO2 nanoparticles, presents higher deposition efficiencies and higher coating thickness than the film prepared with nanoparticles suspended in water (NW-P25) or with titanium isopropoxide solutions (SP). This is due to the precursor solution is acting as the cement between TiO2 nanoparticles, improving the cohesive strength of the coating. In sum, NSP-P25 and NW-P25 coatings display a good photocatalytic potential, based on their light absorption properties and mechanical stability. Band gap of the nanoparticulated coatings displays a light absorption at wavelengths below 379 and 399 nm for NW-P25 and NSP-P25 respectively. On the contrary, the SP coating, despite to present lower band-gap value, has bad cohesive properties with surface crackings that makes it mechanically unstable. Therefore, mixtures of P25 nanoparticles with titanium isopropoxide as feed-stock materials can produce promising photocatalytic coatings.

Surface-assisted DNA self-assembly: An enzyme-free strategy towards formation of branched DNA lattice

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhanjadeo, Madhabi M.; Academy of Scientific and Innovative Research; Nayak, Ashok K.

DNA based self-assembled nanostructures and DNA origami has proven useful for organizing nanomaterials with firm precision. However, for advanced applications like nanoelectronics and photonics, large-scale organization of self-assembled branched DNA (bDNA) into periodic lattices is desired. In this communication for the first time we report a facile method of self-assembly of Y-shaped bDNA nanostructures on the cationic surface of Aluminum (Al) foil to prepare periodic two dimensional (2D) bDNA lattice. Particularly those Y-shaped bDNA structures having smaller overhangs and unable to self-assemble in solution, they are easily assembled on the surface of Al foil in the absence of ligase. Fieldmore » emission scanning electron microscopy (FESEM) analysis shows homogenous distribution of two-dimensional bDNA lattices across the Al foil. When the assembled bDNA structures were recovered from the Al foil and electrophoresed in nPAGE only higher order polymeric bDNA structures were observed without a trace of monomeric structures which confirms the stability and high yield of the bDNA lattices. Therefore, this enzyme-free economic and efficient strategy for developing bDNA lattices can be utilized in assembling various nanomaterials for functional molecular components towards development of DNA based self-assembled nanodevices. - Highlights: • Al foil surface-assisted self-assembly of monomeric structures into larger branched DNA lattice. • FESEM study confirms the uniform distribution of two-dimensional bDNA lattice structures across the surface of Al foil. • Enzyme-free and economic strategy to prepare higher order structures from simpler DNA nanostructures have been confirmed by recovery assay. • Use of well proven sequences for the preparation of pure Y-shaped monomeric DNA nanostructure with high yield.« less

Quantitative Inspection Technologies for Aging Military Aircraft

DTIC Science & Technology

2013-11-01

Continue exploring the application of THz/FTIR for advanced aerospace materials, e.g., Thermal Barrier Coatings (TBCs) and Ceramic Matrix Composites...With On-Board Impedance- Matching Buffers ...Specimen. The Inverted Foil Conductivity Of 1.348%IACS Agrees With The DCPD Value Of 1.342%IACS

Effects of temperature and holding time on bonding W and W-Cu composites with an amorphous W-Fe coated copper foil as the interlayer by hot-pressing

NASA Astrophysics Data System (ADS)

Zhao, Pei; Wang, Song; Guo, Shibin; Chen, Yixiang; Ling, Yunhan; Li, Jiangtao

2013-07-01

W and W-Cu composites were bonded with an amorphous W-Fe coated copper foil as the interlayer at different temperature and holding time by hot pressing method. Effects of the bonding temperature and holding time on the microstructure and thermal conductivity of the bonded specimens were investigated. The thermal conductivity of the bonded sample increased with the bonding temperature and reached the maximum at 1000 °C, but essentially unchanged with the holding time. Because at 1000 °C more W-Fe compounds would be formed at the interlayer, which were helpful for tight bonding of W and W-Cu composites, and the grain size was larger which could reduce thermal resistance. The W-Cu FGM bonded by this method showed good resistance to thermal load, and performed well when facing to short pulse plasma in experimental advanced superconducting tokamak (the first full superconductive fusion device in the world).

Investigation of hexagonal boron nitride as an atomically thin corrosion passivation coating in aqueous solution.

PubMed

Zhang, Jing; Yang, Yingchao; Lou, Jun

2016-09-09

Hexagonal boron nitride (h-BN) atomic layers were utilized as a passivation coating in this study. A large-area continuous h-BN thin film was grown on nickel foil using a chemical vapor deposition method and then transferred onto sputtered copper as a corrosion passivation coating. The corrosion passivation performance in a Na2SO4 solution of bare and coated copper was investigated by electrochemical methods including cyclic voltammetry (CV), Tafel polarization and electrochemical impedance spectroscopy (EIS). CV and Tafel analysis indicate that the h-BN coating could effectively suppress the anodic dissolution of copper. The EIS fitting result suggests that defects are the dominant leakage source on h-BN films, and improved anti-corrosion performances could be achieved by further passivating these defects.

Growth kinetics of white graphene (h-BN) on a planarised Ni foil surface

PubMed Central

Cho, Hyunjin; Park, Sungchan; Won, Dong-Il; Kang, Sang Ook; Pyo, Seong-Soo; Kim, Dong-Ik; Kim, Soo Min; Kim, Hwan Chul; Kim, Myung Jong

2015-01-01

The morphology of the surface and the grain orientation of metal catalysts have been considered to be two important factors for the growth of white graphene (h-BN) by chemical vapour deposition (CVD). We report a correlation between the growth rate of h-BN and the orientation of the nickel grains. The surface of the nickel (Ni) foil was first polished by electrochemical polishing (ECP) and subsequently annealed in hydrogen at atmospheric pressure to suppress the effect of the surface morphology. Atmospheric annealing with hydrogen reduced the nucleation sites of h-BN, which induced a large crystal size mainly grown from the grain boundary with few other nucleation sites in the Ni foil. A higher growth rate was observed from the Ni grains that had the {110} or {100} orientation due to their higher surface energy. PMID:26156068

Detailed in situ laser calibration of the infrared imaging video bolometer for the JT-60U tokamak

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parchamy, H.; Peterson, B. J.; Konoshima, S.

2006-10-15

The infrared imaging video bolometer (IRVB) in JT-60U includes a single graphite-coated gold foil with an effective area of 9x7 cm{sup 2} and a thickness of 2.5 {mu}m. The thermal images of the foil resulting from the plasma radiation are provided by an IR camera. The calibration technique of the IRVB gives confidence in the absolute levels of the measured values of the plasma radiation. The in situ calibration is carried out in order to obtain local foil properties such as the thermal diffusivity {kappa} and the product of the thermal conductivity k and the thickness t{sub f} of themore » foil. These quantities are necessary for solving the two-dimensional heat diffusion equation of the foil which is used in the experiments. These parameters are determined by comparing the measured temperature profiles (for kt{sub f}) and their decays (for {kappa}) with the corresponding results of a finite element model using the measured HeNe laser power profile as a known radiation power source. The infrared camera (Indigo/Omega) is calibrated by fitting the temperature rise of a heated plate to the resulting camera data using the Stefan-Boltzmann law.« less

Graphene-Armored Aluminum Foil with Enhanced Anticorrosion Performance as Current Collectors for Lithium-Ion Battery.

PubMed

Wang, Mingzhan; Tang, Miao; Chen, Shulin; Ci, Haina; Wang, Kexin; Shi, Liurong; Lin, Li; Ren, Huaying; Shan, Jingyuan; Gao, Peng; Liu, Zhongfan; Peng, Hailin

2017-12-01

Aluminum (Al) foil, as the most accepted cathode current collector for lithium-ion batteries (LIBs), is susceptible to local anodic corrosions during long-term operations. Such corrosions could lead to the deterioration or even premature failure of the batteries and are generally believed to be a bottleneck for next-generation 5 V LIBs. Here, it is demonstrated that Al foil armored by conformal graphene coating exhibits significantly reinforced anodic corrosion resistance in both LiPF 6 and lithium bis(trifluoromethanesulphonyl) imide (LiTFSI) based electrolytes. Moreover, LiMn 2 O 4 cells using graphene-armored Al foil as current collectors (LMO/GA) demonstrate enhanced electrochemical performance in comparison with those using pristine Al foil (LMO/PA). The long-term discharge capacity retention of LMO/GA cell after ≈950 h straight operations at low rate (0.5 C) reaches up to 91%, remarkably superior to LMO/PA cell (75%). The self-discharge propensity of LMO/GA is clearly relieved and the rate/power performance is also improved with graphene mediations. This work not only contributes to the long-term stable operations of LIBs but also might catalyze the deployment of 5 V LIBs in the future. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Dual isotope notch observer for isotope identification, assay and imaging with mono-energetic gamma-ray sources

DOEpatents

Barty, Christopher P.J.

2013-02-05

A dual isotope notch observer for isotope identification, assay and imaging with mono-energetic gamma-ray sources includes a detector arrangement consists of three detectors downstream from the object under observation. The latter detector, which operates as a beam monitor, is an integrating detector that monitors the total beam power arriving at its surface. The first detector and the middle detector each include an integrating detector surrounding a foil. The foils of these two detectors are made of the same atomic material, but each foil is a different isotope, e.g., the first foil may comprise U235 and second foil may comprise U238. The integrating detectors surrounding these pieces of foil measure the total power scattered from the foil and can be similar in composition to the final beam monitor. Non-resonant photons will, after calibration, scatter equally from both foils.

Radiation pressure acceleration of corrugated thin foils by Gaussian and super-Gaussian beams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adusumilli, K.; Goyal, D.; Tripathi, V. K.

Rayleigh-Taylor instability of radiation pressure accelerated ultrathin foils by laser having Gaussian and super-Gaussian intensity distribution is investigated using a single fluid code. The foil is allowed to have ring shaped surface ripples. The radiation pressure force on such a foil is non-uniform with finite transverse component F{sub r}; F{sub r} varies periodically with r. Subsequently, the ripple grows as the foil moves ahead along z. With a Gaussian beam, the foil acquires an overall curvature due to non-uniformity in radiation pressure and gets thinner. In the process, the ripple perturbation is considerably washed off. With super-Gaussian beam, the ripplemore » is found to be more strongly washed out. In order to avoid transmission of the laser through the thinning foil, a criterion on the foil thickness is obtained.« less

Analysis of Counterfeit Coated Tablets and Multi-Layer Packaging Materials Using Infrared Microspectroscopic Imaging.

PubMed

Winner, Taryn L; Lanzarotta, Adam; Sommer, André J

2016-06-01

An effective method for detecting and characterizing counterfeit finished dosage forms and packaging materials is described in this study. Using attenuated total internal reflection Fourier transform infrared spectroscopic imaging, suspect tablet coating and core formulations as well as multi-layered foil safety seals, bottle labels, and cigarette tear tapes were analyzed and compared directly with those of a stored authentic product. The approach was effective for obtaining molecular information from structures as small as 6 μm.

A heater made from graphite composite material for potential deicing application

NASA Technical Reports Server (NTRS)

Hung, C. C.; Stahl, M.; Stahl, M.; Stahl, M.

1986-01-01

A surface heater was developed using a graphite fiber-epoxy composite as the heating element. This heater can be thin, highly electrically and thermally conductive, and can conform to an irregular surface. Therefore it may be used in an aircraft's thermal deicing system to quickly and uniformly heat the aircraft surface. One-ply of unidirectional graphite fiber-epoxy composite was laminated between two plies of fiber glass-epoxy composite, with nickel foil contacting the end portions of the composite and partly exposed beyond the composites for electrical contact. The model heater used brominated P-100 fibers from Amoco. The fiber's electrical resistivity, thermal conductivity and density were 50 micro ohms per centimeter, 270 W/m-K and 2.30 gm/cubic cm, respectively. The electricity was found to penetrate through the composite in the transverse direction to make an acceptably low foil-composite contact resistance. When conducting current, the heater temperature increase reached 50 percent of the steady state value within 20 sec. There was no overheating at the ends of the heater provided there was no water corrosion. If the foil-composite bonding failed during storage, liquid water exposure was found to oxidize the foil. Such bonding failure may be avoided if perforated nickel foil is used, so that the composite plies can bond to each other through the perforated holes and therefore lock the foil in place.

The effect of copper pre-cleaning on graphene synthesis.

PubMed

Kim, Soo Min; Hsu, Allen; Lee, Yi-Hsien; Dresselhaus, Mildred; Palacios, Tomás; Kim, Ki Kang; Kong, Jing

2013-09-13

Copper foil is the most common substrate to synthesize monolayer graphene by chemical vapor deposition (CVD). The surface morphology and conditions of the copper foil can be very different depending on the various suppliers or different batches. These surface properties of copper strongly affect the growth behavior of graphene, thus rendering the growth conditions irreproducible when different batches of Cu foil are used. Furthermore, the quality of the graphene is severely affected as well. In this work, we report a facile method of copper pre-cleaning to improve the graphene quality and the reproducibility of the growth process. We found that the commercial Ni etchant (based on nitric acid) or nitric acid is the most effective cleaning agent among various acidic or basic solutions. The graphene grown on thus-treated copper surfaces is very clean and mostly monolayer when observed under scanning electron microscopy (SEM) and optical imaging, as compared to the graphene grown on untreated copper foil. Different batches (but with the same catalog number) of copper foil from Alfa Aesar Company were examined to explore the effect of copper pre-cleaning; consistent growth results were obtained when pre-cleaning was used. This method overcomes a commonly encountered problem in graphene growth and could become one of the standard protocols for preparing the copper foil substrate for growing graphene or other 2D materials.

Growth of a sea urchin-like rutile TiO2 hierarchical microsphere film on Ti foil for a quasi-solid-state dye-sensitized solar cell.

PubMed

Ri, Jin Hyok; Wu, Shufang; Jin, Jingpeng; Peng, Tianyou

2017-11-30

A sea urchin-like rutile TiO 2 microsphere (RMS) film was fabricated on Ti foil via a hydrothermal process. The resulting rutile TiO 2 hierarchical microspheres with a diameter of 5-6 μm are composed of nanorods with a diameter of ∼200 nm and a length of 1-2 μm. The sea urchin-like hierarchical structure leads to the Ti foil-based RMS film possessing much better light-scattering capability in the visible region than the bare Ti foil. By using it as an underlayer of a nanosized anatase TiO 2 film (bTPP3) derived from a commercially available paste (TPP3), the corresponding bilayer Ti foil-based quasi-solid-state dye-sensitized solar cell (DSSC) only gives a conversion efficiency of 4.05%, much lower than the single bTPP3 film-based one on Ti foil (5.97%). By spin-coating a diluted TPP3 paste (sTPP3) on the RMS film prior to scraping the bTPP3 film, the resulting RMS/sTPP3/bTPP3 film-based DSSC achieves a significantly enhanced efficiency (7.27%). The electrochemical impedance spectra (EIS) show that the RMS/sTPP3/bTPP3 film possesses better electron transport capability and longer electron lifetime than the bTPP3 film. This work not only provides the first example of directly growing rutile TiO 2 hierarchically structured microsphere film on Ti foil suitable for replacing the rigid, heavy and expensive transparent conductive oxide (TCO) glass substrate to serve as a light-scattering underlayer of Ti foil-based quasi-solid-state DSSCs, but also paves a new route to develop Ti foil-based flexible DSSCs with high efficiency, low cost and a wide application field through optimizing the composition and structure of the photoanode.

Development of damage suppression system using embedded SMA foil in CFRP laminates

NASA Astrophysics Data System (ADS)

Ogisu, Toshimichi; Nomura, Masato; Ando, Norio; Takaki, Junji; Kobayashi, Masakazu; Okabe, Tomonaga; Takeda, Nobuo

2001-07-01

Some recent studies have suggested possible applications of Shape Memory Alloy (SMA) for a smart health monitoring and suppression of damage growth. The authors have been conducting research and development studies on applications of embedded SMA foil actuators in CFRP laminates as the basic research for next generation aircrafts. First the effective surface treatment for improvement of bonding properties between SMA and CFRP was studied. It was certified that the anodic oxide treatment by 10% NaOH solution was the most effective treatment from the results of peel resistance test and shear strength test. Then, CFRP laminates with embedded SMA foils were successfully fabricated using this effective surface treatment. The damage behavior of quasi-isotropic CFRP laminates with embedded SMA foils was characterized in both quasi-static load-unload and fatigue tests. The relationship between crack density and applied strain was obtained. The recovery stress generated by embedded SMA foils could increase the onset strain of transverse cracking by 0.2%. The onset strain of delmination in CFRP laminates was also increased accordingly. The shear-lag analysis was also conducted to predict the damage evolution in CFRP laminates with embedded SMA foils. The adhesive layers on both sides of SMA foils were treated as shear elements. The theoretical analysis successfully predicted the experimental results.

Hot foil transducer skin friction sensor

NASA Technical Reports Server (NTRS)

Vranas, T. (Inventor)

1982-01-01

The device utilizes foil transducers with only one edge exposed to the fluid flow. The surfaces are polished producing a foil transducer that does not generate turbulence while sufficiently thick to carry the required electrical current for high temperature fluid flow. The assembly utilizes a precut layered metal sandwich with attached electrodes eliminating a need for welding and individual sensor calibration.

Applying a foil queue micro-electrode in micro-EDM to fabricate a 3D micro-structure

NASA Astrophysics Data System (ADS)

Xu, Bin; Guo, Kang; Wu, Xiao-yu; Lei, Jian-guo; Liang, Xiong; Guo, Deng-ji; Ma, Jiang; Cheng, Rong

2018-05-01

Applying a 3D micro-electrode in a micro electrical discharge machining (micro-EDM) can fabricate a 3D micro-structure with an up and down reciprocating method. However, this processing method has some shortcomings, such as a low success rate and a complex process for fabrication of 3D micro-electrodes. By focusing on these shortcomings, this paper proposed a novel 3D micro-EDM process based on the foil queue micro-electrode. Firstly, a 3D micro-electrode was discretized into several foil micro-electrodes and these foil micro-electrodes constituted a foil queue micro-electrode. Then, based on the planned process path, foil micro-electrodes were applied in micro-EDM sequentially and the micro-EDM results of each foil micro-electrode were able to superimpose the 3D micro-structure. However, the step effect will occur on the 3D micro-structure surface, which has an adverse effect on the 3D micro-structure. To tackle this problem, this paper proposes to reduce this adverse effect by rounded corner wear at the end of the foil micro-electrode and studies the impact of machining parameters on rounded corner wear and the step effect on the micro-structure surface. Finally, using a wire cutting voltage of 80 V, a current of 0.5 A and a pulse width modulation ratio of 1:4, the foil queue micro-electrode was fabricated by wire electrical discharge machining. Also, using a pulse width of 100 ns, a pulse interval of 200 ns, a voltage of 100 V and workpiece material of 304# stainless steel, the foil queue micro-electrode was applied in micro-EDM for processing of a 3D micro-structure with hemispherical features, which verified the feasibility of this process.

Thermal infrared reference sources fabricated from low-cost components and materials

NASA Astrophysics Data System (ADS)

Hovland, Harald; Skauli, Torbjørn

2018-04-01

Mass markets, including mobile phones and automotive sensors, drive rapid developments of imaging technologies toward high performance, low cost sensors, even for the thermal infrared. Good infrared calibration blackbody sources have remained relatively costly, however. Here we demonstrate how to make low-cost reference sources, making quantitative infrared radiometry more accessible to a wider community. Our approach uses ordinary construction materials combined with low cost microcontrollers, digital temperature sensors and foil heater elements from massmarket 3D printers. Blackbodies are constructed from a foil heater of some chosen size and shape, attached to the back of a similarly shaped aluminum plate coated with commercial black paint, which normally exhibits high emissivity. The emissivity can be readily checked by using a thermal imager to view the reflection of a hot object. A digital temperature sensor is attached to the back of the plate. Thermal isolation of the backside minimizes temperature gradients through the plate, ensuring correct readings of the front temperature. The isolation also serves to minimize convection gradients and keeps power consumption low, which is useful for battery powered operation in the field. We demonstrate surface blackbodies (200x200 mm2) with surface homogeneities as low as 0.1°C at 100°C. Homogeneous heating and low thermal mass provides for fast settling time and setup/pack-down time. The approach is scalable to larger sizes by tiling, enabling portable and foldable square-meter-size or larger devices.

TiO2 micro-flowers composed of nanotubes and their application to dye-sensitized solar cells.

PubMed

Kim, Woong-Rae; Park, Hun; Choi, Won-Youl

2014-02-24

TiO2 micro-flowers were made to bloom on Ti foil by the anodic oxidation of Ti-protruding dots with a cylindrical shape. Arrays of the Ti-protruding dots were prepared by photolithography, which consisted of coating the photoresists, attaching a patterned mask, illuminating with UV light, etching the Ti surface by reactive ion etching (RIE), and stripping the photoresist on the Ti foil. The procedure for the blooming of the TiO2 micro-flowers was analyzed by field emission scanning electron microscopy (FESEM) as the anodizing time was increased. Photoelectrodes of dye-sensitized solar cells (DSCs) were fabricated using TiO2 micro-flowers. Bare TiO2 nanotube arrays were used for reference samples. The short-circuit current (Jsc) and the power conversion efficiency of the DSCs based on the TiO2 micro-flowers were 4.340 mA/cm2 and 1.517%, respectively. These values of DSCs based on TiO2 micro-flowers were higher than those of bare samples. The TiO2 micro-flowers had a larger surface area for dye adsorption compared to bare TiO2 nanotube arrays, resulting in improved Jsc characteristics. The structure of the TiO2 micro-flowers allowed it to adsorb dyes very effectively, also demonstrating the potential to achieve higher power conversion efficiency levels for DSCs compared to a bare TiO2 nanotube array structure and the conventional TiO2 nanoparticle structure.

TiO2 micro-flowers composed of nanotubes and their application to dye-sensitized solar cells

PubMed Central

2014-01-01

TiO2 micro-flowers were made to bloom on Ti foil by the anodic oxidation of Ti-protruding dots with a cylindrical shape. Arrays of the Ti-protruding dots were prepared by photolithography, which consisted of coating the photoresists, attaching a patterned mask, illuminating with UV light, etching the Ti surface by reactive ion etching (RIE), and stripping the photoresist on the Ti foil. The procedure for the blooming of the TiO2 micro-flowers was analyzed by field emission scanning electron microscopy (FESEM) as the anodizing time was increased. Photoelectrodes of dye-sensitized solar cells (DSCs) were fabricated using TiO2 micro-flowers. Bare TiO2 nanotube arrays were used for reference samples. The short-circuit current (Jsc) and the power conversion efficiency of the DSCs based on the TiO2 micro-flowers were 4.340 mA/cm2 and 1.517%, respectively. These values of DSCs based on TiO2 micro-flowers were higher than those of bare samples. The TiO2 micro-flowers had a larger surface area for dye adsorption compared to bare TiO2 nanotube arrays, resulting in improved Jsc characteristics. The structure of the TiO2 micro-flowers allowed it to adsorb dyes very effectively, also demonstrating the potential to achieve higher power conversion efficiency levels for DSCs compared to a bare TiO2 nanotube array structure and the conventional TiO2 nanoparticle structure. PMID:24565201

TiO2 micro-flowers composed of nanotubes and their application to dye-sensitized solar cells

NASA Astrophysics Data System (ADS)

Kim, Woong-Rae; Park, Hun; Choi, Won-Youl

2014-02-01

TiO2 micro-flowers were made to bloom on Ti foil by the anodic oxidation of Ti-protruding dots with a cylindrical shape. Arrays of the Ti-protruding dots were prepared by photolithography, which consisted of coating the photoresists, attaching a patterned mask, illuminating with UV light, etching the Ti surface by reactive ion etching (RIE), and stripping the photoresist on the Ti foil. The procedure for the blooming of the TiO2 micro-flowers was analyzed by field emission scanning electron microscopy (FESEM) as the anodizing time was increased. Photoelectrodes of dye-sensitized solar cells (DSCs) were fabricated using TiO2 micro-flowers. Bare TiO2 nanotube arrays were used for reference samples. The short-circuit current ( J sc) and the power conversion efficiency of the DSCs based on the TiO2 micro-flowers were 4.340 mA/cm2 and 1.517%, respectively. These values of DSCs based on TiO2 micro-flowers were higher than those of bare samples. The TiO2 micro-flowers had a larger surface area for dye adsorption compared to bare TiO2 nanotube arrays, resulting in improved J sc characteristics. The structure of the TiO2 micro-flowers allowed it to adsorb dyes very effectively, also demonstrating the potential to achieve higher power conversion efficiency levels for DSCs compared to a bare TiO2 nanotube array structure and the conventional TiO2 nanoparticle structure.

Study made of dielectric properties of promising materials for cryogenic capacitors

NASA Technical Reports Server (NTRS)

Mathes, K. N.; Minnich, S. H.

1967-01-01

Experimental investigations were conducted to determine dielectric properties of promising materials for cryogenic capacitors to be used in energy storage and pulse applications. The three classes of materials investigated were inorganic bonded ferroelectric materials, anodic coatings on metal foils, and polar low temperature liquids.

Long lifetime hollow cathodes for 30-cm mercury ion thrusters

NASA Technical Reports Server (NTRS)

Mirtich, M. J.; Kerslake, W. R.

1976-01-01

An experimental investigation of hollow cathodes for 30-cm Hg bombardment thrusters was carried out. Both main and neutralizer cathode configurations were tested with both rolled foil inserts coated with low work function material and impregnated porous tungsten inserts. Temperature measurements of an impregnated insert at various positions in the cathode were made. These, along with the cathode thermal profile are presented. A theory for rolled foil and impregnated insert operation and lifetime in hollow cathodes is developed. Several endurance tests, as long as 18,000 hours at emission currents of up to 12 amps were attained with no degradation in performance.

Laser-assisted immobilization of colloid silver nanoparticles on polyethyleneterephthalate

NASA Astrophysics Data System (ADS)

Siegel, Jakub; Lyutakov, Oleksiy; Polívková, Markéta; Staszek, Marek; Hubáček, Tomáš; Švorčík, Václav

2017-10-01

Immobilization of nanoobjects on the surface of underlying material belongs to current issues of material science. Such altered materials exhibits completely exceptional properties exploitable in a broad spectrum of industrially important applications ranging from catalysts up to health-care industry. Here we present unique approach for immobilization of electrochemically synthesized silver nanoparticles on polyethyleneterephthalate (PET) foil whose essence lies in physical incorporation of particles into thin polymer surface layer induced by polarized excimer laser light. Changes in chemical composition and surface structure of polymer after particle immobilization were recorded by wide range of analytical techniques such as ARXPS, EDX, RBS, AAS, Raman, ICP-MS, DLS, UV-vis, SEM, TEM, and AFM. Thorough analysis of both nanoparticles entering the immobilization step as well as modified PET surface allowed revealing the mechanism of immobilization process itself. Silver nanoparticles were physically embedded into a thin surface layer of polymer reaching several nanometers beneath the surface rather than chemically bonded to PET macromolecules. Laser-implanted nanoparticles open up new possibilities especially in the development of the next generation cell-conform antimicrobial coatings of polymeric materials, namely due to the considerable immobilization strength which is strong enough to prevent particle release into the surrounding environment.

The influence of perforation of foil reactors on greenhouse gas emission rates during aerobic biostabilization of the undersize fraction of municipal wastes.

PubMed

Stegenta, Sylwia; Dębowski, Marcin; Bukowski, Przemysław; Randerson, Peter F; Białowiec, Andrzej

2018-02-01

The opinion, that the use of foil reactors for the aerobic biostabilization of municipal wastes is not a valid method, due to vulnerability to perforation, and risk of uncontrolled release of exhaust gasses, was verified. This study aimed to determine the intensity of greenhouse gas (GHG) emissions to the atmosphere from the surface of foil reactors in relation to the extent of foil surface perforation. Three scenarios were tested: intact (airtight) foil reactor, perforated foil reactor, and torn foil reactor. Each experimental variant was triplicated, and the duration of each experiment cycle was 5 weeks. Temperature measurements demonstrated a significant decrease in temperature of the biostabilization in the torn reactor. The highest emissions of CO 2 , CO and SO 2 were observed at the beginning of the process, and mostly in the torn reactor. During the whole experiment, observed emissions of CO, H 2 S, NO, NO 2 , and SO 2 were at a very low level which in extreme cases did not exceed 0.25 mg t -1 .h -1 (emission of gasses mass unit per waste mass unit per unit time). The lowest average emissions of greenhouse gases were determined in the case of the intact reactor, which shows that maintaining the foil reactors in an airtight condition during the process is extremely important. Copyright © 2017 Elsevier Ltd. All rights reserved.

Experimental Investigation of the Electrothermal Instability on Planar Foil Ablation Experiments

NASA Astrophysics Data System (ADS)

Steiner, Adam; Patel, Sonal; Yager-Elorriaga, David; Jordan, Nicholas; Gilgenbach, Ronald; Lau, Y. Y.

2014-10-01

The electrothermal instability (ETI) is an important early-time physical effect on pulsed power foil ablation experiments due to its ability to seed the destructive magneto-Rayleigh-Taylor (MRT) instability. ETI occurs whenever electrical resistivity has temperature dependence; when resistivity increases with temperature, as with solid metal liners or foils, ETI forms striation structures perpendicular to current flow. These striations provide an initial perturbation for the MRT instability, which is the dominant late-time instability in planar foil ablations. The MAIZE linear transformer driver was used to drive current pulses of approximately 600 kA into 400 nm-thick aluminum foils in order to study ETI in planar geometry. Shadowgraph images of the aluminum plasmas were taken for multiple shots at various times within approximately 50 ns of current start. Fourier analysis extracted the approximate wavelengths of the instability structures on the plasma-vacuum interface. Surface metrology of pre-shot foils was performed to provide a comparison between surface roughness features and resulting plasma structure. This work was supported by US DoE. S.G. Patel and A.M. Steiner supported by NPSC funded by Sandia. D.A. Yager supported by NSF fellowship Grant # DGE 1256260.

Surface Control of Actuated Hybrid Space Mirrors

DTIC Science & Technology

2010-10-01

precision Nanolaminate foil facesheet and Silicon Carbide ( SiC ) substrate embedded with electroactive ceramic actuators. Wavefront sensors are used to...integrate precision Nanolaminate foil facesheet with Silicon Carbide ( SiC ) substrate equipped with embedded electroactive ceramic actuators...IAC-10.C2.5.8 SURFACE CONTROL OF ACTUATED HYBRID SPACE MIRRORS Brij. N. Agrawal Naval Postgraduate School, Monterey, CA, 93943, agrawal

40 CFR 63.3094 - What work practice standards must I meet?

Code of Federal Regulations, 2010 CFR

2010-07-01

..., mixing, and conveying of coatings, thinners, and cleaning materials used in, and waste materials... approved alternative. (A) Use of masking materials (contact paper, plastic sheet, or other similar type of... (paper, foil, plastic, or similar type of material). (B) Use of manual and/or mechanical scrubbers, rags...

75 FR 59180 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Control Technique...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-27

... Promulgation of Air Quality Implementation Plans; Maryland; Control Technique Guidelines for Paper, Film, and... Technique Guidelines (CTG) for paper, film, and foil coatings. These amendments will reduce volatile organic... Promulgation of Air Quality Implementation Plans; Maryland; Control Technique Guidelines for Paper, Film, and...

Cost-Cutting Powdered Lubricant

NASA Technical Reports Server (NTRS)

2005-01-01

Scientists at NASA's Glenn Research Center developed a high-temperature, solid lubricant coating material that is saving the manufacturing industry millions of dollars. The material came out of 3 decades of tribological research, work studying high-temperature friction, lubrication, and the wearing of interacting surfaces that are in relative motion. It was developed as a shaft coating deposited by thermal spraying to protect foil air bearings used in oil-free turbomachinery, like gas turbines, and is meant to be part of a larger project: an oil-free aircraft engine capable of operating at high temperatures with increased reliability, lowered weight, reduced maintenance requirements, and increased power. This advanced coating, PS300, is a self-lubricating bearing material containing chromium oxide, with additions of a low-temperature start up lubricant (silver) and a high-temperature lubricant, making it remarkably stable at high temperatures, and better suited than previously available materials for high-stress conditions. It improves efficiency, lowers friction, reduces emissions, and has been used by NASA in advanced aeropropulsion engines, refrigeration compressors, turbochargers, and hybrid electrical turbogenerators. PS300 is ideal in any application where lowered weight and reduced maintenance are desired, and high-temperature uses and heavy operating speeds are expected. It has notable uses for the Space Agency, but it has even further-reaching potential for the industrial realm.

Hypersonic force measurements using internal balance based on optical micromachined Fabry-Perot interferometry.

PubMed

Qiu, Huacheng; Min, Fu; Zhong, Shaolong; Song, Xin; Yang, Yanguang

2018-03-01

Force measurements using wind tunnel balance are necessary for determining a variety of aerodynamic performance parameters, while the harsh environment in hypersonic flows requires that the measurement instrument should be reliable and robust, in against strong electromagnetic interference, high vacuum, or metal (oxide) dusts. In this paper, we demonstrated a three-component internal balance for hypersonic aerodynamic force measurements, using novel optical micromachined Fabry-Perot interferometric (FPI) strain gauges as sensing elements. The FPI gauges were fabricated using Micro-Opto-Electro-Mechanical Systems (MOEMS) surface and bulk fabrication techniques. High-reflectivity coatings are used to form a high-finesse Fabry-Perot cavity, which benefits a high resolution. Antireflective and passivation coatings are used to reduce unwanted interferences. The FPI strain gauge based balance has been calibrated and evaluated in a Mach 5 hypersonic flow. The results are compared with the traditional technique using the foil resistive strain gauge balance, indicating that the proposed balance based on the MOEMS FPI strain gauge is reliable and robust and is potentially suitable for the hypersonic wind tunnel harsh environment.

Hypersonic force measurements using internal balance based on optical micromachined Fabry-Perot interferometry

NASA Astrophysics Data System (ADS)

Qiu, Huacheng; Min, Fu; Zhong, Shaolong; Song, Xin; Yang, Yanguang

2018-03-01

Force measurements using wind tunnel balance are necessary for determining a variety of aerodynamic performance parameters, while the harsh environment in hypersonic flows requires that the measurement instrument should be reliable and robust, in against strong electromagnetic interference, high vacuum, or metal (oxide) dusts. In this paper, we demonstrated a three-component internal balance for hypersonic aerodynamic force measurements, using novel optical micromachined Fabry-Perot interferometric (FPI) strain gauges as sensing elements. The FPI gauges were fabricated using Micro-Opto-Electro-Mechanical Systems (MOEMS) surface and bulk fabrication techniques. High-reflectivity coatings are used to form a high-finesse Fabry-Perot cavity, which benefits a high resolution. Antireflective and passivation coatings are used to reduce unwanted interferences. The FPI strain gauge based balance has been calibrated and evaluated in a Mach 5 hypersonic flow. The results are compared with the traditional technique using the foil resistive strain gauge balance, indicating that the proposed balance based on the MOEMS FPI strain gauge is reliable and robust and is potentially suitable for the hypersonic wind tunnel harsh environment.

Extraction of Solar Wind Nitrogen and Noble Gases From the Genesis Gold Foil Collector

NASA Astrophysics Data System (ADS)

Schlutter, D. J.; Pepin, R. O.

2005-12-01

The Genesis gold foil is a bulk solar wind collector, integrating fluences from all three of the wind regimes. Pyrolytic extraction of small foil samples at Minnesota yielded He fluences, corrected for backscatter, in good agreement with measurements by on-board spacecraft instruments, and He/Ne elemental ratios close to those implanted in collector foils deployed on the lunar surface during the Apollo missions. Isotopic distributions of He, Ne and Ar are under study. Pyrolysis to temperatures above the gold melting point generates nitrogen blanks large enough to obscure the solar-wind nitrogen component. An alternative technique for nitrogen and noble gas extraction, by room-temperature amalgamation of the gold foil surface, will be discussed. Ne and Ar releases in preliminary tests of this technique on small foil samples were close to 100% of the amounts expected from the high-temperature pyrolysis yields, indicating that amalgamation quantitatively liberates gases from several hundred angstroms deep in the gold, beyond the implantation depth of most of the solar wind. Present work is focused on two problems currently interfering with accurate nitrogen measurements at the required picogram to sub-picogram levels: a higher than expected blank likely due to tiny air bubbles rolled into the gold sheet during fabrication, and the presence of a refractory hydrocarbon film on Genesis collector surfaces (the "brown stain") that, if left in place on the foil, shields the underlying gold from mercury attack. We have found, however, that the film is efficiently removed within tens of seconds by oxygen plasma ashing. Potential nitrogen contaminants introduced during the crash of the sample return canister are inert in amalgamation, and so are not hazards to the measurements.

Precise method to determine points on isentropic release curve on copper

NASA Astrophysics Data System (ADS)

Remiot, C.; Mexmain, J. M.; Bonnet, L.

1996-05-01

When a higher shock impedance foil (with several hundreds of μm in thickness) is set on the studied material surface, the release phase occurs by steps, whose duration of each plateau corresponds to a go and return of the shock wave in the foil. Step velocity levels can be easily measured by D.L.I. technique. The intermediate velocity values, connected with the knowledge of the foil Hugoniot, allow us to determine a few points on the isentropic release curve. The experiments have been achieved on a two stage light gas gun with a projectile velocity varying from 1400 to 3000 m/s. The caliber of the launcher is 30 mm. For this study concerning copper, the target is composed of a 2 mm thickness copper transmitter on which the sample is mechanically held. The tungsten (W) thick foil is, under pressure, sticked on the sample with UV stick-cord. The free surface velocity measurement accuracy of the tungsten foil is 0.4% for values between 1500 to 3500 m/s. The first shock in the sample is varying from 40 to 120 GPa and the mass velocity from 800 to 2000 m/s. By impedance matching between the copper sample and the tungsten thick foil, we deduce for each experiment three points on the copper isentropic release curve and the final free surface velocity. The accuracy we obtain is in order of 0.4 GPa for the pressure and 10 m/s for the mass velocity.

Thin silicon foils produced by epoxy-induced spalling of silicon for high efficiency solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martini, R., E-mail: roberto.martini@imec.be; imec, Kapeldreef 75, 3001 Leuven; Kepa, J.

2014-10-27

We report on the drastic improvement of the quality of thin silicon foils produced by epoxy-induced spalling. In the past, researchers have proposed to fabricate silicon foils by spalling silicon substrates with different stress-inducing materials to manufacture thin silicon solar cells. However, the reported values of effective minority carrier lifetime of the fabricated foils remained always limited to ∼100 μs or below. In this work, we investigate epoxy-induced exfoliated foils by electron spin resonance to analyze the limiting factors of the minority carrier lifetime. These measurements highlight the presence of disordered dangling bonds and dislocation-like defects generated by the exfoliation process.more » A solution to remove these defects compatible with the process flow to fabricate solar cells is proposed. After etching off less than 1 μm of material, the lifetime of the foil increases by more than a factor of 4.5, reaching a value of 461 μs. This corresponds to a lower limit of the diffusion length of more than 7 times the foil thickness. Regions with different lifetime correlate well with the roughness of the crack surface which suggests that the lifetime is now limited by the quality of the passivation of rough surfaces. The reported values of the minority carrier lifetime show a potential for high efficiency (>22%) thin silicon solar cells.« less

The feed-out process: Rayleigh-Taylor and Richtmyer-Meshkov instabilities in thin, laser-driven foils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smitherman, D.P.

Eight beams carrying a shaped pulse from the NOVA laser were focused into a hohlraum with a total energy of about 25 kJ. A planar foil was placed on the side of the hohlraum with perturbations facing away from the hohlraum. All perturbations were 4 {micro}m in amplitude and 50 {micro}m in wavelength. Three foils of pure aluminum were shot with thicknesses and pulse lengths respectively of 86 {micro}m and 2. 2 ns, 50 {micro}m and 4.5 ns, and 35 {micro}m with both 2.2 ns and 4. 5 ns pulses. Two composite foils constructed respectively of 32 and 84 {micro}mmore » aluminum on the ablative side and 10 {micro}m beryllium on the cold surface were also shot using the 2.2 ns pulse. X-ray framing cameras recorded perturbation growth using both face- and side-on radiography. The LASNEX code was used to model the experiments. A shock wave interacted with the perturbation on the cold surface generating growth from a Richtmyer-Meshkov instability and a strong acoustic mode. The cold surface perturbation fed-out to the Rayleigh-Taylor unstable ablation surface, both by differential acceleration and interface coupling, where it grew. A density jump did not appear to have a large effect on feed-out from interface coupling. The Rayleigh-Taylor instability`s vortex pairs overtook and reversed the direction of flow of the Richtmyer-Meshkov vortices, resulting in the foil moving from a sinuous to a bubble and spike configuration. The Rayleigh-Taylor instability may have acted as an ablative instability on the hot surface, and as a classical instability on the cold surface, on which grew second and third order harmonics.« less

Carbon-based coating containing ultrafine MoO2 nanoparticles as an integrated anode for high-performance lithium-ion batteries

NASA Astrophysics Data System (ADS)

Li, Quanyi; Yang, Qi; Zhao, Yanhong; Wan, Bin

2017-10-01

Copper-supported MoO2-C composite as an integrated anode with excellent battery performance was synthesized by a facile knife coating technique followed by heat treatment in a vacuum. The obtained samples were characterized by X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), thermal analysis, nitrogen adsorption and desorption analysis, field emission scanning microscopy (FESEM), and transmission electron microscopy (TEM). The results show the MoO2-C composite coating is comprised of a porous carbon matrix with a pore size of 1-3 nm and ultrafine MoO2 nanoparticles with a size of 5-10 nm encapsulated inside, the coating is tightly attached on the surface of copper foil, and the interface between them is free of cracks. Stable PAN-DMF-H2O system containing ammonium molybdate suitable for knife coating technique and the MoO2-C composite with ultrafine MoO2 nanoparticles encapsulated in the carbon matrix can be prepared through controlling amount of added ammonium molybdate solution. The copper-supported MoO2-C composite coating can be directly utilized as the integrated anode for lithium-ion batteries (LIBs). It delivers a capacity of 814 mA h g-1 at a current density of 100 mA g-1 after 100 cycles without apparent capacity fading. Furthermore, with increase of current densities to 200, 500, 1000, 2000, and 5000 mA g-1, it exhibits average capacities of 809, 697, 568, 383, and 188 mA h g-1. Its outstanding electrochemical performance is attributed to combined merits of integrated anode and structure with ultrafine MoO2 nanoparticles embedded in the porous carbon matrix.

Radiative property degradation of water impinging on thermally-controlled surfaces under space conditions.

NASA Technical Reports Server (NTRS)

Maples, D.; Spiller, M. H.; Maples, G.

1973-01-01

Review of the results of an investigation aimed at determining experimentally the directional monochromatic reflectance changes caused under high-vacuum space conditions by a water spray impinging on thermally controlled surfaces consisting of three paint specimens (Z93, S13G, and 92-007) and an aluminum foil. The first two paints and the aluminum foil suffered considerable physical damage, but only small changes resulted in the reflectance of the paints while the reflectance of the aluminum foil decreased with increase in exposure time to the water jet. Only the 92-007 Dow Corning paint retained the same physical and reflective characteristics.

Development of Flexible, Free-Standing, Thin Films for Additive Manufacturing and Localized Energy Generation

DTIC Science & Technology

2015-08-10

stainless steel foil substrates that were 50 microns thick. The coatings were then placed in an oven at 60oC for 24 hours to evaporate the solvent. After...drying, the coatings were cooled at room temperature in a fume hood for 24 hours. The free standing film is photographed in Figure 2. The film was cut...composition were examined and flame speeds were measured. A glass slide with the sample strip attached was placed on a steel block housed in a

Fabrication and Characterization of Diffusion Bonds for Silicon Carbide

NASA Technical Reports Server (NTRS)

Halbig, Michael; Singh, Mrityunjay; Martin, Richard E.; Cosgriff, Laura M.

2007-01-01

Diffusion bonds of silicon carbide (SiC) were fabricated using several different types of titanium (Ti) based interlayers between the SiC substrates. The interlayers were an alloyed Ti foil, a pure Ti foil, and a physically vapor deposited (PVD) Ti coating. Microscopy was conducted to evaluate the cross-sections of the resulting bonds. Microprobe analysis identified reaction formed phases in the diffusion bonded region. Uniform and well adhered bonds were formed between the SiC substrates. In the case where the alloyed Ti foil or a thick Ti coating (i.e. 20 micron) was used as the interlayer, microcracks and several phases were present in the diffusion bonds. When a thinner interlayer was used (i.e. 10 micron PVD Ti), no microcracks were observed and only two reaction formed phases were present. The two phases were preferred and fully reacted phases that did not introduce thermal stresses or microcracks during the cool-down stage after processing. Diffusion bonded samples were evaluated with the non-destructive evaluation (NDE) methods of pulsed thermography and immersion ultrasonic testing. Joined SiC substrates that were fully bonded and that had simulated bond flaws in the interlayer were also evaluated using immersion ultrasound. Pull testing was conducted on the bonds to determine the tensile strength. To demonstrate the joining approach for a complex multilayered component for a low NOx injector application, the diffusion bonding approach was used to join three 4" diameter SiC discs that contained complex fuel and air flow channels.

Slumped glass foils as substrate for adjustable x-ray optics

NASA Astrophysics Data System (ADS)

Salmaso, Bianca; Basso, Stefano; Civitani, Marta; Ghigo, Mauro; Hołyszko, Joanna; Pelliciari, Carlo; Spiga, Daniele; Vecchi, Gabriele; Pareschi, Giovanni

2016-09-01

Thin glass modular mirrors are a viable solution to build future X-ray telescopes with high angular resolution and large collecting area. In our laboratories, we shape thin glass foils by hot slumping and we apply pressure to assist the replication of a cylindrical mould figure; this technology is coupled with an integration process able to damp low frequency errors and produces optics in the Wolter I configuration, typical for the X-ray telescopes. From the point of view of the hot slumping process, the efforts were focused in reducing low-, mid- and high- frequency errors of the formed Eagle glass foils. Some of our slumped glass foils were used for the development of active X-ray optics, where piezoelectric actuators are used to correct the slumped glass foil deviations from the ideal shape. In particular, they were used for the Adjustable X-raY optics for astrOnoMy project (AXYOM) developed in Italy, and the X-ray Surveyor mission, as developed at the Smithsonian Astrophysical Observatory / Center for Astrophysics (SAO/CfA) in USA. In this paper we describe the optimisation of the hot slumping process, comparing the results with the requirements of the considered active optics projects. Finally, since the present configuration of the Pennsylvania State University (PSU) coating equipment is limited to 100 x 100 mm2, the slumped glass foils used for the SAO project were cut from 200 x 200 mm2 to 100 x 100 mm2, and a low-frequency change was observed. A characterisation of the profile change upon cutting is presented.

A flexible top-emitting organic light-emitting diode on steel foil

NASA Astrophysics Data System (ADS)

Xie, Zhiyuan; Hung, Liang-Sun; Zhu, Furong

2003-11-01

An efficient flexible top-emitting organic light-emitting diode (FTOLED) was developed on a thin steel foil. The FTOLED was constructed on the spin-on-glass (SOG)-coated steel substrate with an organic stack of NPB/Alq 3 sandwiched by a highly reflective Ag anode and a semitransparent Sm cathode. An ultrathin plasma-polymerized hydrocarbon film (CF X) was interposed between the Ag anode and the NPB layer to enhance hole-injection, and an additional Alq 3 layer was overlaid on the Sm cathode to increase light output. The FTOLED showed a peak efficiency of 4.4 cd/A higher than 3.7 cd/A of a convention NPB/Alq 3-based bottom-emitting OLED.

Influence of UV and Gamma radiations on the induced birefringence of stretched poly(vinyl) alcohol foils

NASA Astrophysics Data System (ADS)

Nechifor, Cristina-Delia; Zelinschi, Carmen Beatrice; Dorohoi, Dana-Ortansa

2014-03-01

The aim of our paper is to evidence the influence of Gamma and UV radiations on the induced birefringence of poly(vinyl alcohol) stretched foils. Thin foils of PVA were prepared and dried without modifying their surfaces. The polymeric foils were irradiated from 15 min to 6 h using UV and Gamma radiations. The induced by stretching under heating birefringence of PVA films was measured at λ = 589.3 nm with a Babinet Compensator. Physico-chemical processes (photo stabilization, photo degradation, oxidation) induced by irradiation of polymer matrix influence both the stretching degree and the anisotropy of etired foils. An increase of birefringence versus the stretching ratio of the PVA foils was evidenced for all studied samples. The dependence of the birefringence on the exposure time, stretching ratio and nature of radiation was also confirmed.

NEUTRONIC REACTOR FUEL ELEMENT

DOEpatents

Horning, W.A.; Lanning, D.D.; Donahue, D.J.

1959-10-01

A fuel slug for a reactor which acts as a safety device is described. The fuel slug is an aluminum tube with a foil lining the inside surface of the tube, the foil being fabricated of uranium in a lead matrix.

Energy-Storing Structures: Composite Capacitors and Batteries

DTIC Science & Technology

2012-07-30

with Li ions, busses electrons, and provides structural reinforcement - Example: Perforated stainless steel foil coated with LiFePO4 + acetylene...m A h /g ) LiFePO4 LiCoO2 Theoretical maximum for LiFePO4 Theoretical maximum for LiCoO2 500 m Expanded Perforated Woven Cathode and

Model and Subcomponent Development for a Pulse-Combustor-Driven Microgenerator

DTIC Science & Technology

2004-08-31

sputtering of thin magnetic and dielectric layers [4]; and mechanical lamination of polymer -coated NiFe foils [5]. Although these approaches have...photomicrograph of the fabricated device is given in Figure 4.2-6. 3d solenoid- like Cu coil EPOXY SU8 NIFE LAMINATE D CORE Figure 4.2-6 Photomicrograph

Nanosecond laser-induced ablation and laser-induced shockwave structuring of polymer foils down to sub-μm patterns

NASA Astrophysics Data System (ADS)

Lorenz, P.; Bayer, L.; Ehrhardt, M.; Zimmer, K.; Engisch, L.

2015-03-01

Micro- and nanostructures exhibit a growing commercial interest where a fast, cost-effective, and large-area production is attainable. Laser methods have a great potential for the easy fabrication of surface structures into flexible polymer foils like polyimide (PI). In this study two different concepts for the structuring of polymer foils using a KrF excimer laser were tested and compared: the laser-induced ablation and the laser-induced shock wave structuring. The direct front side laser irradiation of these polymers allows the fabrication of different surface structures. For example: The low laser fluence treatment of PI results in nano-sized cone structures where the cone density can be controlled by the laser parameters. This allows inter alia the laser fabrication of microscopic QR code and high-resolution grey-tone images. Furthermore, the laser treatment of the front side of the polymer foil allows the rear side structuring due to a laserinduced shock wave. The resultant surface structures were analysed by optical and scanning electron microscopy (SEM) as well as white light interferometry (WLI).

Nanocomposite of polystyrene foil grafted with metallaboranes for antimicrobial activity

NASA Astrophysics Data System (ADS)

Benkocká, Monika; Kolářová, Kateřina; Matoušek, Jindřich; Semerádtová, Alena; Šícha, Václav; Kolská, Zdeňka

2018-05-01

The surface of polystyrene foil (PS) was chemically modified. Firstly, the surface was pre-treated with Piranha solution. The activated surface was grafted by selected amino-compounds (cysteamine, ethylenediamine or chitosan) and/or subsequently grafted with five members of inorganic metallaboranes. Selected surface properties were studied by using various methods in order to indicate significant changes before and after individual modification steps of polymer foil. Elemental composition of surface was conducted by using X-ray photoelectron spectroscopy, chemistry and polarity by infrared spectroscopy and by electrokinetic analysis, wettability by goniometry, surface morphology by atomic force microscopy. Antimicrobial tests were performed on individual samples in order to confirm antimicrobial impact. Our results show slight antibacterial activity of PS modified with SK5 for Escherichia coli in comparison with the rest of the tested borane. On the other hand molecules of all tested metallaboranes could easier pierce through bacterial cell of Staphylococcus epidermidis due to absence of outer membrane (phospholipid bilayer). Some borane grafted on PS surface embodies the strong activity for Staphylococcus epidermidis and also for Desmodesmus quadricauda growth inhibition.

FeCoNi coated glass fibers in composite sheets for electromagnetic absorption and shielding behaviors

NASA Astrophysics Data System (ADS)

Lee, Joonsik; Jung, Byung Mun; Lee, Sang Bok; Lee, Sang Kwan; Kim, Ki Hyeon

2017-09-01

To evaluate the electromagnetic (EM) absorption and shield of magnetic composite sheet, we prepared the FeCoNi coated glass fibers filled in composite sheet. The FeCoNi was coated by electroless plating on glass fiber as a filler. The coated FeCoNi found that consist of mixtures of bcc and fcc phase. The magnetization and coercivity of coated FeCoNi are about 110 emu/g and 57 Oe, respectively. The permittivity and permeability of the FeCoNi composite sheet were about 21 and 1, respectively. Power absorption increased 95% with the increment of frequency up to 10 GHz. Inter-decoupling of this composite sheet showed maximum 30 dB at around 5.3 GHz, which is comparable to that of a conductive Cu foil. Shielding effectiveness (SE) was measured by using rectangular waveguide method. SE of composite obtained about 37 dB at X-band frequency region.

Effects of laser power density and initial grain size in laser shock punching of pure copper foil

NASA Astrophysics Data System (ADS)

Zheng, Chao; Zhang, Xiu; Zhang, Yiliang; Ji, Zhong; Luan, Yiguo; Song, Libin

2018-06-01

The effects of laser power density and initial grain size on forming quality of holes in laser shock punching process were investigated in the present study. Three different initial grain sizes as well as three levels of laser power densities were provided, and then laser shock punching experiments of T2 copper foil were conducted. Based upon the experimental results, the characteristics of shape accuracy, fracture surface morphology and microstructures of punched holes were examined. It is revealed that the initial grain size has a noticeable effect on forming quality of holes punched by laser shock. The shape accuracy of punched holes degrades with the increase of grain size. As the laser power density is enhanced, the shape accuracy can be improved except for the case in which the ratio of foil thickness to initial grain size is approximately equal to 1. Compared with the fracture surface morphology in the quasistatic loading conditions, the fracture surface after laser shock can be divided into three zones including rollover, shearing and burr. The distribution of the above three zones strongly relates with the initial grain size. When the laser power density is enhanced, the shearing depth is not increased, but even diminishes in some cases. There is no obvious change of microstructures with the enhancement of laser power density. However, while the initial grain size is close to the foil thickness, single-crystal shear deformation may occur, suggesting that the ratio of foil thickness to initial grain size has an important impact on deformation behavior of metal foil in laser shock punching process.

Producing Foils From Direct Cast Titanium Alloy Strip

NASA Technical Reports Server (NTRS)

Stuart, T. A.; Gaspar, T. A.; Sukonnik, I. M.; Semiatan, S. L.; Batawi, E.; Peters, J. A.; Fraser, H. L.

1996-01-01

This research was undertaken to demonstrate the feasibility of producing high-quality, thin-gage, titanium foil from direct cast titanium strip. Melt Overflow Rapid Solidification Technology (MORST) was used to cast several different titanium alloys into 500 microns thick strip, 10 cm wide and up to 3 m long. The strip was then either ground, hot pack rolled or cold rolled, as appropriate, into foil. Gamma titanium aluminide (TiAl) was cast and ground to approximately 100 microns thick foil and alpha-2 titanium aluminide (Ti3AI) was cast and hot pack rolled to approximately 70 microns thick foil. CP Ti, Ti6Al2Sn4Zr2Mo, and Ti22AI23Nb (Orthorhombic), were successfully cast and cold-rolled into good quality foil (less than 125 microns thick). The foils were generally fully dense with smooth surfaces, had fine, uniform microstructures, and demonstrated mechanical properties equivalent to conventionally produced titanium. By eliminating many manufacturing steps, this technology has the potential to produce thin gage, titanium foil with good engineering properties at significantly reduced cost relative to conventional ingot metallurgy processing.

Foil Face Seal Testing

NASA Technical Reports Server (NTRS)

Munson, John

2009-01-01

In the seal literature you can find many attempts by various researchers to adapt film riding seals to the gas turbine engine. None have been successful, potential distortion of the sealing faces is the primary reason. There is a film riding device that does accommodate distortion and is in service in aircraft applications, namely the foil bearing. More specifically a foil thrust bearing. These are not intended to be seals, and they do not accommodate large axial movement between shaft & static structure. By combining the 2 a unique type of face seal has been created. It functions like a normal face seal. The foil thrust bearing replaces the normal primary sealing surface. The compliance of the foil bearing allows the foils to track distortion of the mating seal ring. The foil seal has several perceived advantages over existing hydrodynamic designs, enumerated in the chart. Materials and design methodology needed for this application already exist. Also the load capacity requirements for the foil bearing are low since it only needs to support itself and overcome friction forces at the antirotation keys.

Angular distributions of reflected and refracted relativistic electron beams crossing a thin planar target at a small angle to its surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serov, A. V., E-mail: serov@x4u.lebedev.ru; Mamonov, I. A.; Kol’tsov, A. V., E-mail: koltsov@x4u.lebedev.ru

2015-10-15

The scattering of electrons by aluminum, copper, and lead foils, as well as by bimetallic aluminum-lead and aluminum-copper foils, has been studied experimentally. A microtron with an energy of particles of 7.4 MeV has been used as a source of electrons. The beam of particles incident on a target at small angles is split into particles reflected from the foil, which constitute a reflected beam, and particles crossing the foil, which constitute a refracted beam. The effect of the material and thickness of the foil, as well as the angle between the initial trajectory of the beam and the planemore » of the target, on the direction of motion and the angular divergence of the beam crossing the foil and the beam reflected from the foil has been analyzed. Furthermore, the effect of the sequence of metal layers in bimetallic films on the angles of refraction and reflection of the beam has been examined.« less

The reference cube: A new ballistic model to generate staining in firearm barrels.

PubMed

Schyma, Christian; Bauer, Kristina; Brünig, Julia

2017-06-01

After contact shots to the head biological traces can be found inside firearm barrels. So far silicone coated, gelatin filled box models were used to generate such staining according to the triple contrast method (mixture of acrylic paint, barium sulfate and blood sealed in a thin foil bag). This study was conducted to develop a transparent ballistic model allowing contact shots. Gelatin filled polyethylene bottles with and without a silicone coat were tested in comparison to non-covered gelatin blocks. Finally, thin foil bags of 5 cm × 5 cm dimension were glued on a synthetic absorbent kitchen wipe on top of which 1 L 10% gelatin solution was molded to create blocks of 8.5 cm length. A kitchen wipe with a paint pad on its inside formed the front of the cube. Three contact shots each with a 9 mm Luger pistol and a .38 special revolver were performed on all model variations. The staining was documented by endoscopy and swabs gathered from both ends of the barrel were analyzed by quantitative PCR. Reliable staining was achieved using the front covered gelatin block with comparable results to the silicone coated box model used before. For further research using ballistic models to simulate a human head a symmetric form of the gelatin block such as a cube is recommended.

Hydrogenated amorphous carbon coatings on implants drastically reduce biofilm formation and water permeation

NASA Astrophysics Data System (ADS)

Bernsmann, Falk; Laube, Norbert; Baldsiefen, Gerhard; Castellucci, Mattia

2014-11-01

Inflammations and crystalline bacterial biofilms (encrustations) remain a major complication in long-term artificial urinary tract drainage. To solve this problem we present urological implants with coatings made of amorphous hydrogenated carbon (a-C:H) that show excellent protection from encrustation in-vitro as well as in-vivo. Part of the success of a-C:H coatings is attributed to their ability to act as a diffusion barrier between an implant and the body, which prevents leaching of solvents from polymeric implants. To further enhance their barrier properties a-C:H coatings are combined with parylene coatings to develop diffusion-barrier multilayer coatings with a total thickness between 0.2 μm and 0.8 μm. The combination of the two types of coatings leads to a reduction of water diffusion by a factor of up to ten with respect to uncoated 25 μm thick polyimide sub-strates. The diffusion of water vapour from a controlled atmospheric pressure chamber through coated foils to a vacuum chamber is measured in a custom-built device.

Transition of PS300 Solid Lubricant Coating Technology to Field Aided by Demonstration on Key Substrate Alloys

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher

2003-01-01

PS300 is a high-temperature solid lubricant coating originally developed to lubricate nickel-based superalloy shafts operating against foil air bearings in Oil-Free turbomachinery applications. PS300 is a plasma-spray-deposited coating developed at the NASA Glenn Research Center. It is available for non-exclusive licensing and has found applications in aerospace and industry. PS300 reduces friction and wear from below room temperature to over 650 C in both oxidizing and reducing environments. Early development centered on coating nickel-based shafts for use in turbomachinery. Potential industrial and aerospace customers, however, expressed interest in using the coating on a wide variety of substrates including steels, stainless steels, and nonferrous alloys like aluminum and titanium. To support this interest, a research program was carried out at Glenn in which nine different substrate candidate materials were evaluated for suitability with the PS300 coating. The materials were first coated with PS300 and then tested for coating strength and adhesion both before and after exposure to high-temperature air.

Concept Feasibility Report for Electroplating Zirconium onto Uranium Foil - Year 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Coffey, Greg W.; Meinhardt, Kerry D.; Joshi, Vineet V.

2015-03-01

The Fuel Fabrication Capability within the U.S. High Performance Research Reactor Conversion Program is funded through the National Nuclear Security Administration (NNSA) NA-26 (Office of Material Management and Minimization). An investigation was commissioned to determine the feasibility of using electroplating techniques to apply a coating of zirconium onto depleted uranium/molybdenum alloy (U-10Mo). Electroplating would provide an alternative method to the existing process of hot roll-bonding zirconium foil onto the U-10Mo fuel foil during the fabrication of fuel elements for high-performance research reactors. The objective of this research was to develop a reproducible and scalable plating process that will produce amore » uniform, 25 μm thick zirconium metal coating on U-10Mo foil. In previous work, Pacific Northwest National Laboratory (PNNL) established a molten salt electroplating apparatus and protocol to plate zirconium metal onto molybdenum foil (Coffey 2015). During this second year of the research, PNNL furthered this work by moving to the U-10Mo alloy system (90 percent uranium:10 percent molybdenum). The original plating apparatus was disassembled and re-assembled in a laboratory capable of handling low-level radioactive materials. Initially, the work followed the previous year’s approach, and the salt bath composition was targeted at the eutectic composition (LiF:NaF:ZrF4 = 26:37:37 mol%). Early results indicated that the formation of uranium fluoride compounds would be problematic. Other salt bath compositions were investigated in order to eliminate the uranium fluoride production (LiF:NaF = 61:39 mol% and LiF:NaF:KF = 46.5:11.5:42 mol% ). Zirconium metal was used as the crucible for the molten salt. Three plating methods were used—isopotential, galvano static, and pulsed plating. The molten salt method for zirconium metal application provided high-quality plating on molybdenum in PNNL’s previous work. A key advantage of this approach is that plating can be performed under conditions that would greatly reduce the quantity of intermetallics that form at the interface between the zirconium and U-10Mo; unlike roll bonding, the molten salt plating approach would allow for complete coverage of the U-10Mo foil with zirconium. When utilizing the experimental parameters developed for zirconium plating onto molybdenum, a uranium fluoride reaction product was formed at the Zr/U-10Mo interface. By controlling the initial plating potential, the uranium fluoride could be prevented; however, the targeted zirconium thickness (25 ±12.5 μm) could not be achieved while maintaining 100% coverage.« less

Barrier mechanism of multilayers graphene coated copper against atomic oxygen irradiation

NASA Astrophysics Data System (ADS)

Zhang, Haijing; Ren, Siming; Pu, Jibin; Xue, Qunji

2018-06-01

Graphene has been demonstrated as a protective coating for Cu under ambient condition because of its high impermeability and light-weight oxidation barrier. However, it lacks the research of graphene as a protective coating in space environment. Here, we experimentally and theoretically study the oxidation behavior of graphene-coated Cu in vacuum atomic oxygen (AO) condition. After AO irradiation, the experimental results show multilayer graphene has better anti-oxidation than monolayer graphene. Meanwhile, the calculation results show the oxidation appeared on the graphene's grain boundaries or the film's vacancy defects for the monolayer graphene coated Cu foil. Moreover, the calculation results show the oxidation process proceeds slowly in multilayers because of the matched defects overlaps each other to form a steric hindrance to suppress the O atom diffusion in the vertical direction, and the mismatched defects generates potential energy barriers for interlayer to suppress the O atom diffusion in the horizontal direction. Hence, multilayer graphene films could serve as protection coatings to prevent diffusion of O atom.

Methods for and products of processing nanostructure nitride, carbonitride and oxycarbonitride electrode power materials by utilizing sol gel technology for supercapacitor applications

DOEpatents

Huang, Yuhong; Wei, Oiang; Chu, Chung-tse; Zheng, Haixing

2001-01-01

Metal nitride, carbonitride, and oxycarbonitride powder with high surface area (up to 150 m.sup.2 /g) is prepared by using sol-gel process. The metal organic precursor, alkoxides or amides, is synthesized firstly. The metal organic precursor is modified by using unhydrolyzable organic ligands or templates. A wet gel is formed then by hydrolysis and condensation process. The solvent in the wet gel is then be removed supercritically to form porous amorphous hydroxide. This porous hydroxide materials is sintered to 725.degree. C. under the ammonia flow and porous nitride powder is formed. The other way to obtain high surface area nitride, carbonitride, and oxycarbonitride powder is to pyrolyze polymerized templated metal amides aerogel in an inert atmosphere. The electrochemical capacitors are prepared by using sol-gel prepared nitride, carbonitride, and oxycarbonitride powder. Two methods are used to assemble the capacitors. Electrode is formed either by pressing the mixture of nitride powder and binder to a foil, or by depositing electrode coating onto metal current collector. The binder or coating is converted into a continuous network of electrode material after thermal treatment to provide enhanced energy and power density. Liquid electrolyte is soaked into porous electrode. The electrochemical capacitor assembly further has a porous separator layer between two electrodes/electrolyte and forming a unit cell.

Interaction of irradiation-induced prismatic dislocation loops with free surfaces in tungsten

NASA Astrophysics Data System (ADS)

Fikar, Jan; Gröger, Roman; Schäublin, Robin

2017-02-01

The prismatic dislocation loops appear in metals as a result of high-energy irradiation. Understanding their formation and interaction is important for quantification of irradiation-induced deterioration of mechanical properties. Characterization of dislocation loops in thin foils is commonly made using transmission electron microscopy (TEM), but the results are inevitably influenced by the proximity of free surfaces. The prismatic loops are attracted to free surfaces by image forces. Depending on the type, size and depth of the loop in the foil, they can escape to the free surface, thus invalidating TEM observations and conclusions. In this article small prismatic hexagonal and circular dislocation loops in tungsten with the Burgers vectors 1/2 〈 1 1 1 〉 and 〈 1 0 0 〉 are studied by molecular statics simulations using three embedded atom method (EAM) potentials. The calculated image forces are compared to known elastic solutions. A particular attention is paid to the critical stress to move edge dislocations. The escape of the loop to the free surface is quantified by a combination of atomistic simulations and elastic calculations. For example, for the 1/2 〈 1 1 1 〉 loop with diameter 7.4 nm in a 55 nm thick foil we calculated that about one half of the loops will escape to the free surface. This implies that TEM observations detect only approx. 50% of the loops that were originally present in the foil.

{001} Oriented piezoelectric films prepared by chemical solution deposition on Ni foils

NASA Astrophysics Data System (ADS)

Yeo, Hong Goo; Trolier-McKinstry, Susan

2014-07-01

Flexible metal foil substrates are useful in some microelectromechanical systems applications including wearable piezoelectric sensors or energy harvesters based on Pb(Zr,Ti)O3 (PZT) thin films. Full utilization of the potential of piezoelectrics on metal foils requires control of the film crystallographic texture. In this study, {001} oriented PZT thin films were grown by chemical solution deposition (CSD) on Ni foil and Si substrates. Ni foils were passivated using HfO2 grown by atomic layer deposition in order to suppress substrate oxidation during subsequent thermal treatment. To obtain the desired orientation of PZT film, strongly (100) oriented LaNiO3 films were integrated by CSD on the HfO2 coated substrates. A high level of {001} LaNiO3 and PZT film orientation were confirmed by X-ray diffraction patterns. Before poling, the low field dielectric permittivity and loss tangents of (001) oriented PZT films on Ni are near 780 and 0.04 at 1 kHz; the permittivity drops significantly on poling due to in-plane to out-of-plane domain switching. (001) oriented PZT film on Ni displayed a well-saturated hysteresis loop with a large remanent polarization ˜36 μC/cm2, while (100) oriented PZT on Si showed slanted P-E hysteresis loops with much lower remanent polarizations. The |e31,f| piezoelectric coefficient was around 10.6 C/m2 for hot-poled (001) oriented PZT film on Ni.

The Role of Radial Clearance on the Performance of Foil Air Bearings

NASA Technical Reports Server (NTRS)

Radil, Kevin; Howard, Samuel; Dykas, Brian

2002-01-01

Load capacity tests were conducted to determine how radial clearance variations affect the load capacity coefficient of foil air bearings. Two Generation III foil air bearings with the same design but possessing different initial radial clearances were tested at room temperature against an as-ground PS304 coated journal operating at 30,000 rpm. Increases in radial clearance were accomplished by reducing the journal's outside diameter via an in-place grinding system. From each load capacity test the bearing load capacity coefficient was calculated from the rule-of-thumb (ROT) model developed for foil air bearings. The test results indicate that, in terms of the load capacity coefficient, radial clearance has a direct impact on the performance of the foil air bearing. Each test bearing exhibited an optimum radial clearance that resulted in a maximum load capacity coefficient. Relative to this optimum value are two separate operating regimes that are governed by different modes of failure. Bearings operating with radial clearances less than the optimum exhibit load capacity coefficients that are a strong function of radial clearance and are prone to a thermal runaway failure mechanism and bearing seizure. Conversely, a bearing operating with a radial clearance twice the optimum suffered only a 20 percent decline in its maximum load capacity coefficient and did not experience any thermal management problems. However, it is unknown to what degree these changes in radial clearance had on other performance parameters, such as the stiffness and damping properties of the bearings.

Surface properties, crystallinity and optical properties of anodised titanium in mixture of β-glycerophosphate (β-GP) and calcium acetate (CA)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chuan, Lee Te, E-mail: gd130079@siswa.uthm.edu.my; Abdullah, Hasan Zuhudi, E-mail: hasan@uthm.edu.my; Idris, Maizlinda Izwana, E-mail: izwana@uthm.edu.my

Anodic oxidation is an electrochemical method for the production of ceramic films on a metallic substrate. It had been widely used to deposit the ceramic coatings on the metals surface. This method has been widely used in surface modification of biomaterials especially for dental implants. In this study, the surface morphology, crystallinity and optical properties of titanium foil was modified by anodising in mixture of β-glycerophosphate disodium salt pentahydrate (β-GP) and calcium acetate monohydrate (CA). The experiments were carried out at high voltage (350 V), different anodising time (5 and 10 minutes) and current density (10-70 mA.cm{sup −2}) at room temperature. Anodisedmore » titanium was characterised by using field emission scanning electron microscopy (FESEM), X-ray diffractometer (XRD), and UV-Vis spectrometry. The result of the experiment showed that surface morphology, crystallinity and optical properties depended strongly on the current density and anodising time. More porous surface and large amount of anatase and rutile was produced at higher current density and longer anodising time. Apart from that, it is also revealed that the energy band gap of anodised titanium increases as the increase in current density due to the presence of anatase and rutile TiO{sub 2}.« less

Surface properties, crystallinity and optical properties of anodised titanium in mixture of β-glycerophosphate (β-GP) and calcium acetate (CA)

NASA Astrophysics Data System (ADS)

Chuan, Lee Te; Abdullah, Hasan Zuhudi; Idris, Maizlinda Izwana

2015-07-01

Anodic oxidation is an electrochemical method for the production of ceramic films on a metallic substrate. It had been widely used to deposit the ceramic coatings on the metals surface. This method has been widely used in surface modification of biomaterials especially for dental implants. In this study, the surface morphology, crystallinity and optical properties of titanium foil was modified by anodising in mixture of β-glycerophosphate disodium salt pentahydrate (β-GP) and calcium acetate monohydrate (CA). The experiments were carried out at high voltage (350 V), different anodising time (5 and 10 minutes) and current density (10-70 mA.cm-2) at room temperature. Anodised titanium was characterised by using field emission scanning electron microscopy (FESEM), X-ray diffractometer (XRD), and UV-Vis spectrometry. The result of the experiment showed that surface morphology, crystallinity and optical properties depended strongly on the current density and anodising time. More porous surface and large amount of anatase and rutile was produced at higher current density and longer anodising time. Apart from that, it is also revealed that the energy band gap of anodised titanium increases as the increase in current density due to the presence of anatase and rutile TiO2.

Flapping foil power generator performance enhanced with a spring-connected tail

NASA Astrophysics Data System (ADS)

Liu, Zhengliang; Tian, Fang-Bao; Young, John; Lai, Joseph C. S.

2017-12-01

The flexibility effects on the performance of a flapping foil power generator are numerically studied by using the immersed boundary-lattice Boltzmann method at a Reynolds number of 1100. The flapping foil system consists of a rigid NACA0015 foil undergoing harmonic pitch and plunge motions and a passively actuated flat plate pinned to the trailing edge of the rigid foil. The flexibility is modeled by a torsional spring model at the conjuncture of the rigid foil and the tail. Here, a parametric study on mass density and natural frequency is conducted under the optimum kinematic condition of the rigid system identified from the literature and numerical simulations made for reduced frequency f* = 0.04-0.24 and pitch amplitude θ0 = 40°-90°. Four typical cases are discussed in detail by considering time histories of hydrodynamic loads and tail deformations under the optimal and non-optimal kinematic conditions. Results show that under the rigid-system optimal kinematic condition, a tail with appropriate mass density (μ = 0.60) and resonant frequency ( fr*=1.18 ) can improve the maximum efficiency by 7.24% accompanied by an increase of 6.63% in power compared to those of a rigid foil with a rigid tail. This is because the deflection of the tail reduces the low pressure region on the pressure surface (i.e., the lower surface during the upstroke or the upper surface during the downstroke) caused by the leading edge vortex after the stroke reversal, resulting in a higher efficiency. At high flapping frequencies, a spring-connected tail ( fr*=0.13 ) eliminates the large spike in the moment observed in high stiffness cases, reducing the power required for the pitch motion, resulting in 117% improvement in efficiency over that with a rigid tail at a reduced frequency of 0.24.

Coating Thermoelectric Devices To Suppress Sublimation

NASA Technical Reports Server (NTRS)

Sakamoto, Jeffrey; Caillat, Thierry; Fleurial, Jean-Pierre; Snyder, G. Jeffrey

2007-01-01

A technique for suppressing sublimation of key elements from skutterudite compounds in advanced thermoelectric devices has been demonstrated. The essence of the technique is to cover what would otherwise be the exposed skutterudite surface of such a device with a thin, continuous film of a chemically and physically compatible metal. Although similar to other sublimation-suppression techniques, this technique has been specifically tailored for application to skutterudite antimonides. The primary cause of deterioration of most thermoelectric materials is thermal decomposition or sublimation - one or more elements sublime from the hot side of a thermoelectric couple, changing the stoichiometry of the device. Examples of elements that sublime from their respective thermoelectric materials are Ge from SiGe, Te from Pb/Te, and now Sb from skutterudite antimonides. The skutterudite antimonides of primary interest are CoSb3 [electron-donor (n) type] and CeFe(3-x)Co(x)Sb12 [electron-acceptor (p) type]. When these compounds are subjected to typical operating conditions [temperature of 700 C and pressure <10(exp -5) torr (0.0013 Pa)], Sb sublimes from their surfaces, with the result that Sb depletion layers form and advance toward their interiors. As the depletion layer advances in a given device, the change in stoichiometry diminishes the thermal-to-electric conversion efficiency of the device. The problem, then, is to prevent sublimation, or at least reduce it to an acceptably low level. In preparation for an experiment on suppression of sublimation, a specimen of CoSb3 was tightly wrapped in a foil of niobium, which was selected for its chemical stability. In the experiment, the wrapped specimen was heated to a temperature of 700 C in a vacuum of residual pressure <10(exp -5) torr (0.0013 Pa), then cooled and sectioned. Examination of the sectioned specimen revealed that no depletion layer had formed, indicating the niobium foil prevented sublimation of antimony at 700 C. This was a considerable improvement, considering that uncoated CoSb3 had been found to decompose to form the lowest antimonide at the surface at only 600 C. Evidently, because the mean free path of Sb at the given temperature and pressure was of the order of tens of centimeters, any barrier closer than tens of centimeters (as was the niobium foil) would have suppressed transport of Sb vapor, thereby suppressing sublimation of Sb

High-performance lithium-ion batteries with 1.5 μm thin copper nanowire foil as a current collector

NASA Astrophysics Data System (ADS)

Chu, Hsun-Chen; Tuan, Hsing-Yu

2017-04-01

Cu Foil, a thin sheet of Cu, is the common anode current collector in commercial lithium ion batteries (LIBs) which accounts for ∼ 10 wt% of the total cell weight. However, thickness reduction of LIB-based Cu foils below 6 μm has been limited by the incapability of conventional rolling annealing or electrodeposition process. We here report a new type of Cu foil, so called Cu nanowire foil (CuNW foil), for use as an LIB anode current collector. We fabricate Cu NW foils by rolling press Cu nanowire fabric to reduce the thickness down to ∼1.5 μm with an areal weight down to ∼1.2 mg cm-2 and a density approximately 96% to that of bulk Cu. The rough surface and porous structure of CuNW foil enable better wetting and adhering properties of graphite slurry on foil. In full cell examination, a cell of a areal capacity of 3 mAh cm-2 exhibits 83.6% capacity retention for 600 cycles at 0.6 C that meets the standard specification of most commercial LIBs. As a proof-of-concept of demonstration, we fabricate a 700 mA pouch-type battery implemented with graphite-Cu NWs foil anodes to serve as energy supply to operate electronic devices.

Pulsed electric discharge laser technology. Electron beam window foil material

NASA Astrophysics Data System (ADS)

McGeoch, M. W.; Defuria, A. J.; Pike, C. T.

1984-01-01

An experimental and theoretical study of titanium alloy foil windows is described. The alloys considered are Ti 15-3-3-3, Ti 3-2.5, and CP Ti(4). The foil thickness ranges from 0.5 mil to 1.0 mil. Tensile strength data is presented for 75 F and 600 F. High-cycle (10 to the 7th power) fatigue data is presented to Ti 15-3-3-3 and Ti 3-2.5 at 75 F and 600 F. Crystal structures are shown for all the alloys. Measurements of the biaxial, or membrane, strength of the alloys is presented. A simulation of laser pulsed overpressure conditions is described, and the foil fatigue under these conditions is documented. The stresses in pressure loaded foil windows were calculated by the finite element method, both for static and dynamic loading. The shape of the foil support rib was optimized to minimize the foil stresses. A correlation was performed between the computed stress cycling under pulsed loading and the measured fatigue strength in uniaxial tension. As a check on the pulse simulation, the actual movement of an electron-beam foil window was measured by interferometry. A speckle interferometer which allows measurement of the movement of unpolished foil surfaces is described.

Satellite Spacecraft Charging Control Materials.

DTIC Science & Technology

1980-04-01

Surface potential in terms of beam energy 923.4.4 Typical current recordings 92 3 - 5 Analysis III 3.5.1 Background ill 3.5.2 Silica fabric behaviour 114...3521 surface potentials, leakage and secondary electron emission currents 114 3521-1 variation with time 114I 3521-2 variation with the beam energy ...Irradiations 51 Figure 15 Silica Fabric - FEP - Aluminum Foil Composite 56 Figure 16 Electron Energy Spectrum After Scattering through and Aluminum Foil

Influence of micromachined targets on laser accelerated proton beam profiles

NASA Astrophysics Data System (ADS)

Dalui, Malay; Permogorov, Alexander; Pahl, Hannes; Persson, Anders; Wahlström, Claes-Göran

2018-03-01

High intensity laser-driven proton acceleration from micromachined targets is studied experimentally in the target-normal-sheath-acceleration regime. Conical pits are created on the front surface of flat aluminium foils of initial thickness 12.5 and 3 μm using series of low energy pulses (0.5-2.5 μJ). Proton acceleration from such micromachined targets is compared with flat foils of equivalent thickness at a laser intensity of 7 × 1019 W cm-2. The maximum proton energy obtained from targets machined from 12.5 μm thick foils is found to be slightly lower than that of flat foils of equivalent remaining thickness, and the angular divergence of the proton beam is observed to increase as the depth of the pit approaches the foil thickness. Targets machined from 3 μm thick foils, on the other hand, show evidence of increasing the maximum proton energy when the depths of the structures are small. Furthermore, shallow pits on 3 μm thick foils are found to be efficient in reducing the proton beam divergence by a factor of up to three compared to that obtained from flat foils, while maintaining the maximum proton energy.

Edge-on dislocation loop in anisotropic hcp zirconium thin foil

NASA Astrophysics Data System (ADS)

Wu, Wenwang; Xia, Re; Qian, Guian; Xu, Shucai; Zhang, Jinhuan

2015-10-01

Edge-on dislocation loops with 〈 a 〉 -type and 〈 c 〉 -type of Burgers vectors can be formed on prismatic or basel habit planes of hexagonal close-packed (hcp) zirconium alloys during in-situ ion irradiation and neutron irradiation experiments. In this work, an anisotropic image stress method was employed to analyze the free surface effects of dislocation loops within hcp Zr thin foils. Calculation results demonstrate that image stress has a remarkable effect on the distortion fields of dislocation loops within infinite medium, and the image energy becomes remarkable when dislocation loops are situated close to the free surfaces. Moreover, image forces of the 1 / 2 〈 0001 〉 (0001) dislocation loop within (0001) thin foil is much stronger than that of the 1 / 3 〈 11 2 bar 0 〉 (11 2 bar 0) dislocation loop within (11 2 bar 0) thin foil of identical geometrical configurations. Finally, image stress effect on the physical behaviors of loops during in-situ ion irradiation experiments is discussed.

Automated X-ray quality control of catalytic converters

NASA Astrophysics Data System (ADS)

Shashishekhar, N.; Veselitza, D.

2017-02-01

Catalytic converters are devices attached to the exhaust system of automobile or other engines to eliminate or substantially reduce polluting emissions. They consist of coated substrates enclosed in a stainless steel housing. The substrate is typically made of ceramic honeycombs; however stainless steel foil honeycombs are also used. The coating is usually a slurry of alumina, silica, rare earth oxides and platinum group metals. The slurry also known as the wash coat is applied to the substrate in two doses, one on each end of the substrate; in some cases multiple layers of coating are applied. X-ray imaging is used to inspect the applied coating depth on a substrate to confirm compliance with quality requirements. Automated image analysis techniques are employed to measure the coating depth from the X-ray image. Coating depth is assessed by analysis of attenuation line profiles in the image. Edge detection algorithms with noise reduction and outlier rejection are used to calculate the coating depth at a specified point along an attenuation line profile. Quality control of the product is accomplished using several attenuation line profile regions for coating depth measurements, with individual pass or fail criteria specified for each region.

Development of long-lived thick carbon stripper foils for high energy heavy ion accelerators by a heavy ion beam sputtering method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muto, Hideshi; Ohshiro, Yukimitsu; Kawasaki, Katsunori

2013-04-19

In the past decade, we have developed extremely long-lived carbon stripper foils of 1-50 {mu}g/cm{sup 2} thickness prepared by a heavy ion beam sputtering method. These foils were mainly used for low energy heavy ion beams. Recently, high energy negative Hydrogen and heavy ion accelerators have started to use carbon stripper foils of over 100 {mu}g/cm{sup 2} in thickness. However, the heavy ion beam sputtering method was unsuccessful in production of foils thicker than about 50 {mu}g/cm{sup 2} because of the collapse of carbon particle build-up from substrates during the sputtering process. The reproduction probability of the foils was lessmore » than 25%, and most of them had surface defects. However, these defects were successfully eliminated by introducing higher beam energies of sputtering ions and a substrate heater during the sputtering process. In this report we describe a highly reproducible method for making thick carbon stripper foils by a heavy ion beam sputtering with a Krypton ion beam.« less

Unitary plate electrode

NASA Technical Reports Server (NTRS)

Rowlette, John J. (Inventor); Clough, Thomas J. (Inventor); Josefowicz, Jack Y. (Inventor); Sibert, John W. (Inventor)

1985-01-01

The unitary electrode (10) comprises a porous sheet (12) of fiberglass the strands (14) of which contain a coating (16) of conductive tin oxide. The lower portion of the sheet contains a layer (18) of resin and the upper layer (20) contains lead dioxide forming a positive active electrode on an electrolyte-impervious layer. The strands (14) form a continuous conduction path through both layers (16, 18). Tin oxide is prevented from reduction by coating the surface of the plate facing the negative electrode with a conductive, impervious layer resistant to reduction such as a thin film (130) of lead or graphite filled resin adhered to the plate with a layer (31) of conductive adhesive. The plate (10) can be formed by casting a molten resin from kettle (60) onto a sheet of glass wool (56) overlying a sheet of lead foil and then applying positive active paste from hopper (64) into the upper layer (68). The plate can also be formed by passing an assembly of a sheet ( 80) of resin, a sheet (86) of sintered glass and a sheet (90) of lead between the nip (92) of heated rollers (93, 95) and then filling lead oxide into the pores (116) of the upper layer (118).

Oil-Free Rotor Support Technologies for Long Life, Closed Cycle Brayton Turbines

NASA Technical Reports Server (NTRS)

Lucero, John M.; DellaCorte, Christopher

2004-01-01

The goal of this study is to provide technological support to ensure successful life and operation of a 50-300 kW dynamic power conversion system specifically with response to the rotor support system. By utilizing technical expertise in tribology, bearings, rotordynamic, solid lubricant coatings and extensive test facilities, valuable input for mission success is provided. A discussion of the history of closed cycle Brayton turboalternators (TA) will be included. This includes the 2 kW Mini-Brayton Rotating Unit (Mini-BRU), the 10kW Brayton Rotating Unit (BRU) and the 125 kW turboalternator-compressor (TAC) designed in mid 1970's. Also included is the development of air-cycle machines and terrestrial oil-free gas turbine power systems in the form of microturbines, specifically Capstone microturbines. A short discussion of the self-acting compliant surface hydrodynamic fluid film bearings, or foil bearings, will follow, including a short history of the load capacity advances, the NASA coatings advancements as well as design model advances. Successes in terrestrial based machines will be noted and NASA tribology and bearing research test facilities will be described. Finally, implementation of a four step integration process will be included in the discussion.

An investigation on the effect of deposition parameters on nanostructured electrode of lithium ion batteries and their performance

NASA Astrophysics Data System (ADS)

Dorri, Mehrdad; Zamani, Cyrus; Babaei, Alireza

2018-01-01

Nanostructured plate-like manganese cobalt oxide (MCO) was synthesized as the anode material for lithium-ion batteries. Under basic conditions and using a molar ratio of OH- /NO3-= 1.5, crystallite size of 14 nm was found for samples calcined at 350°C. The electrodes were fabricated by mixing MCO as the active material, Super P carbon as the conducting material and polyvinylidene fluoride (PVDF) as the binder in N-methyl-2-pyrrolidone (NMP) solvent. The slurry was coated onto a copper foil substrate. The aim of this investigation is the assessment of deposition parameters on different plausible defects (such as agglomeration/blisters, pinholes/divots, cracks and non-uniform coating) and also electrical behavior of the deposited layer. Because of high degree of agglomeration, mortar method was found to be ineffective while mixing using magnetic stirrer was proved to be more appropriate in terms of final rheology. The optimum value for the binder was found to be 2.73 wt% of the NMP solvent. Effective drying was achieved using hotplate followed by oven drying. SEM analysis revealed the disappearance of the surface cracks when samples are pressed after drying stage.

Effect of applied voltage on surface properties of anodised titanium in mixture of β-glycerophosphate (β-GP) and calcium acetate (CA)

NASA Astrophysics Data System (ADS)

Chuan, Lee Te; Rathi, Muhammad Fareez Mohamad; Abidin, Muhamad Yusuf Zainal; Abdullah, Hasan Zuhudi; Idris, Maizlinda Izwana

2015-07-01

Anodic oxidation is a surface modification method which combines electric field driven metal and oxygen ion diffusion for formation of oxide layer on the anode surface. This method has been widely used to modify the surface morphology of biomaterial especially titanium. This study aimed to investigate the effect of applied voltage on titanium. Specifically, the titanium foil was anodised in mixture of β-glycerophosphate disodium salt pentahydrate (β-GP) and calcium acetate monohydrate (CA) with different applied voltage (50-350 V), electrolyte concentration (0.04 M β-GP + 0.4 M CA), anodising time (10minutes) and current density (50 and 70 mA.cm-2) at room temperature. Surface oxide properties of anodised titanium were characterised by digital single-lens reflex camera (DSLR camera), field emission scanning electron microscope (FESEM) and atomic force microscopy (AFM). At lower applied voltage (≤150 V), surface of titanium foils were relatively smooth. With increasing applied voltage (≥250 V), the oxide layer became more porous and donut-shaped pores were formed on the surface of titanium foils. The AFM results indicated that the surface roughness of anodised titanium increases with increasing of applied voltage. The porous and rough surface is able to promote the osseointegration and reduce the suffering time of patient.

Non-destructive Quantitative Phase Analysis and Microstructural Characterization of Zirconium Coated U-10Mo Fuel Foils via Neutron Diffraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cummins, Dustin Ray; Vogel, Sven C.; Hollis, Kendall Jon

2016-10-18

This report uses neutron diffraction to investigate the crystal phase composition of uranium-molybdenum alloy foils (U-10Mo) for the CONVERT MP-1 Reactor Conversion Project, and determines the effect on alpha-uranium contamination following the deposition of a Zr metal diffusion layer by various methods: plasma spray deposition of Zr powders at LANL and hot co-rolling with Zr foils at BWXT. In summary, there is minimal decomposition of the gamma phase U-10Mo foil to alpha phase contamination following both plasma spraying and hot co-rolling. The average unit cell volume, i.e. lattice spacing, of the Zr layer can be mathematically extracted from the diffractionmore » data; co-rolled Zr matches well with literature values of bulk Zr, while plasma sprayed Zr shows a slight increase in the lattice spacing, indicative of interstitial oxygen in the lattice. Neutron diffraction is a beneficial alternative to conventional methods of phase composition, i.e. x ray diffraction (XRD) and destructive metallography. XRD has minimal penetration depth in high atomic number materials, particularly uranium, and can only probe the first few microns of the fuel plate; neutrons pass completely through the foil, allowing for bulk analysis of the foil composition and no issues with addition of cladding layers, as in the final, aluminum-clad reactor fuel plates. Destructive metallography requires skilled technicians, cutting of the foil into small sections, hazardous etching conditions, long polishing and microscopy times, etc.; the neutron diffraction system has an automated sample loader and can fit larger foils, so there is minimal analysis preparation; the total spectrum acquisition time is ~ 1 hour per sample. The neutron diffraction results are limited by spectra refinement/calculation times and the availability of the neutron beam source. In the case of LANSCE at Los Alamos, the beam operates ~50% of the year. Following the lessons learned from these preliminary results, optimizations to the process and analysis can be made, and neutron diffraction can become a viable and efficient technique for gamma/alpha phase composition determination for nuclear fuels.« less

Evaluation of Defects inside Beryllium Foils using X-ray Computed Tomography and Shearing Interferometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sakurai, Tatsuyuki; Kohmura, Yoshiki; Takeuchi, Akihisa

2007-01-19

When beryllium is used in transmission X-ray optical elements for spatially coherent beams, speckles are usually observed in the transmission images. These speckles seem to be caused by defects either inside or on the surface of beryllium foil. We measured highly polished beryllium foil using two methods, X-ray computed tomography and X-ray shearing interferometry. The results indicate that observed speckle pattern is caused by many voids inside beryllium or inner low-density regions.

Effect of oxide particles on the stabilization and final microstructure in aluminium

PubMed Central

Bachmaier, Andrea; Pippan, Reinhard

2011-01-01

Bulk aluminium samples containing alumina particles have been produced by different severe plastic deformation methods. Aluminium foils with different initial foil thicknesses were cold rolled to different amounts of strain and aluminium powders were consolidated and deformed by high pressure torsion (HPT). During processing, alumina particles from the foil or particle surface are easily incorporated and dispersed in the bulk material. The influence of these alumina particles on the developing microstructures and the mechanical properties has been studied. PMID:21976787

Designing robust alumina nanowires-on-nanopores structures: superhydrophobic surfaces with slippery or sticky water adhesion.

PubMed

Peng, Shan; Tian, Dong; Miao, Xinrui; Yang, Xiaojun; Deng, Wenli

2013-11-01

Hierarchical alumina surfaces with different morphologies were fabricated by a simple one-step anodization method. These alumina films were fabricated by a new raw material: silica gel plate (aluminum foil with a low purity of 97.17%). The modulation of anodizing time enabled the formation of nanowires-on-nanopores hybrid nanostructures having controllable nanowires topographies through a self-assembly process. The resultant structures were demonstrated to be able to achieve superhydrophobicity without any hydrophobic coating layer. More interestingly, it is found that the as-prepared superhydrophobic alumina surfaces exhibited high contrast water adhesion. Hierarchical alumina film with nanowire bunches-on-nanopores (WBOP) morphology presents extremely slippery property which can obtain a sliding angle (SA) as low as 1°, nanowire pyramids-on-nanopores (WPOP) structure shows strongly sticky water adhesion with the adhesive ability to support 15 μL inverted water droplet at most. The obtained superhydrophobic alumina surfaces show remarkable mechanical durability even treated by crimping or pressing without impact on the water-repellent performance. Moreover, the created surfaces also show excellent resistivity to ice water, boiling water, high temperature, organic solvent and oil contamination, which could expand their usefulness and efficacy in harsh conditions. Copyright © 2013 Elsevier Inc. All rights reserved.

Fuel Retention Improvement at High Temperatures in Tungsten-Uranium Dioxide Dispersion Fuel Elements by Plasma-Spray Cladding

NASA Technical Reports Server (NTRS)

Grisaffe, Salvatore J.; Caves, Robert M.

1964-01-01

An investigation was undertaken to determine the feasibility of depositing integrally bonded plasma-sprayed tungsten coatings onto 80-volume-percent tungsten - 20-volume-percent uranium dioxide composites. These composites were face clad with thin tungsten foil to inhibit uranium dioxide loss at elevated temperatures, but loss at the unclad edges was still significant. By preheating the composite substrates to approximately 3700 degrees F in a nitrogen environment, metallurgically bonded tungsten coatings could be obtained directly by plasma spraying. Furthermore, even though these coatings were thin and somewhat porous, they greatly inhibited the loss of uranium dioxide. For example, a specimen that was face clad but had no edge cladding lost 5.8 percent uranium dioxide after 2 hours at 4750 dgrees F in flowing hydrogen. A similar specimen with plasma-spray-coated edges, however, lost only 0.75 percent uranium dioxide under the same testing conditions.

Study of Electric Explosion of Flat Micron-Thick Foils at Current Densities of (5-50)×108 A/cm2

NASA Astrophysics Data System (ADS)

Shelkovenko, T. A.; Pikuz, S. A.; Tilikin, I. N.; Mingaleev, A. R.; Atoyan, L.; Hammer, D. A.

2018-02-01

Electric explosions of flat Al, Ti, Ni, Cu, and Ta foils with thicknesses of 1-16 μm, widths of 1-8 mm, and lengths of 5-11 mm were studied experimentally on the BIN, XP, and COBRA high-current generators at currents of 40-1000 kA and current densities of (5-50) × 108 A/cm2. The images of the exploded foils were taken at different angles to the foil surface by using point projection radiography with an X-pinch hot spot as the radiation source, the spatial resolution and exposure time being 3 μm and 50 ps, respectively, as well by the laser probing method with a spatial resolution of 20 μm and an exposure time of 180 ps. In the course of foil explosion, rapidly expanding objects resembling the core and corona of an exploded wire were observed. It is shown that the core of the exploded foil has a complicated time-varying structure.

Hierarchically Mesostructured Aluminum Current Collector for Enhancing the Performance of Supercapacitors.

PubMed

Huang, Yilun; Li, Yuyao; Gong, Qianming; Zhao, Guanlei; Zheng, Pengjie; Bai, Junfei; Gan, Jianning; Zhao, Ming; Shao, Yang; Wang, Dazhi; Liu, Lei; Zou, Guisheng; Zhuang, Daming; Liang, Ji; Zhu, Hongwei; Nan, Cewen

2018-05-16

Aluminum (Al) current collector is one of the most important components of supercapacitors, and its performance has vital effects on the electrochemical performance and cyclic stability of supercapacitors. In the present work, a scalable and low-cost, yet highly efficient, picosecond laser processing method of Al current collectors was developed to improve the overall performance of supercapacitors. The laser treatment resulted in hierarchical micro-nanostructures on the surface of the commercial Al foil and reduced the surface oxygen content of the foil. The electrochemical performance of the Al foil with the micro-nanosurface structures was examined in the symmetrical activated carbon-based coin supercapacitors with an organic electrolyte. The results suggest that the laser-treated Al foil (laser-Al) increased the capacitance density of supercapacitors up to 110.1 F g -1 and promoted the rate capability due to its low contact resistance with the carbonaceous electrode and high electrical conductivity derived from its larger specific surface areas and deoxidized surface. In addition, the capacitor with the laser-Al current collector exhibited high cyclic stability with 91.5% capacitance retention after 10 000 cycles, 21.3% higher than that with pristine-Al current collector due to its stronger bonding with the carbonaceous electrode that prevented any delamination during aging. Our work has provided a new strategy for improving the electrochemical performance of supercapacitors.

76 FR 42560 - Approval and Promulgation of Air Quality Implementation Plans; Vermont; Reasonably Available...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-19

... 2006, EPA-453/R-06-003) 3. Paper, Film, and Foil Coatings (September 2007, EPA-453/R-07- 003) 4. Metal....regulations.gov Web site is an ``anonymous access'' system, which means EPA will not know your identity or... is not publicly available, i.e., CBI or other information whose disclosure is restricted by statute...

Flexible foils formed by a prolonged electron beam irradiation in scanning electron microscope

NASA Astrophysics Data System (ADS)

Čechal, Jan; Šikola, Tomáš

2017-11-01

The ubiquitous presence of hydrocarbon contamination on solid surfaces alters their inherent physical properties and complicates the surface analyses. An irradiation of sample surface with electron beam can lead to the chemical transformation of the hydrocarbon layer to carbon films, which are flexible and capable of acting as a barrier for chemical etching of an underlying material. The growth of these foils is limited by supply of hydrocarbons to the writing beam position rather than the electron dose or electron beam current. The prepared films can find their applications in fabrication of surface nanostructures without a need of an electron sensitive resist material.

Studies of the Use of Electrochemical Impedance Spectroscopy to Characterize and Assess the Performance of Lacquers Used to Protect Aluminum Sheet and Can Ends

NASA Astrophysics Data System (ADS)

Ali, Mohammad

This study involved investigating the feasibility of using Electrochemical Impedance Spectroscopy to assess the performance of coatings used to protect aluminum in beverage containers, and developing an accelerated testing procedure. In the preliminary investigation, tests were performed to ensure that the EIS systems at hand are capable, functional and consistent. This was followed by EIS testing of kitchen-aluminum foil and high-impedance epoxy polymer as a baseline for chemically-active and chemically-inert systems. The ability of EIS to differentiate between intact and flawed coatings was tested by investigating deliberately damaged coatings. The effects of varying the pH and oxygen content on the performance of the coated aluminum samples were also tested. From this investigation, it has been concluded that EIS can be used to differentiate between intact and flawed coatings and detect corrosion before it is visually observable. Signatures of corrosion have been recorded and a preliminary testing procedure has been drawn.

Strong thin membrane structure. [solar sails

NASA Technical Reports Server (NTRS)

Frazer, R. E. (Inventor)

1979-01-01

A continuous process is described for producing strong lightweight structures for use as solar sails for spacecraft propulsion by radiation pressure. A thin reflective coating, such as aluminum, is applied to a rotating cylinder. A nylon mesh, applied over the aluminum coating, is then coated with a polymerizing material such as a para-xylylene monomer gas to polymerize as a film bound to the mesh and the aluminum. An emissivity increasing material such as chromium or silicon monoxide is applied to the polymer film to disperse such material colloidally into the growing polymer film, or to the final polymer film. The resulting membrane structure is then removed from the cylinder. Alternately, the membrane structure can be formed by etching a substrate in the form of an organic film such as a polymide, or a metal foil, to remove material from the substrate and reduce its thickness. A thin reflective coating (aluminum) is applied on one side of the substrate, and an emissivity increasing coating is applied on the reverse side of the substrate.

Friction and Wear Characteristics of a Modified Composite Solid Lubricant Plasma Spray Coating

NASA Technical Reports Server (NTRS)

Stanford, M. K.; DellaCorte, C.

2004-01-01

LCR304 is a solid lubricant coating composed of Ni-10Cr, Cr2O3, BaF2-CaF2 and Ag and developed for dimensional stability in high temperature air. This coating is a modification of PS304, which differs in that the Ni-Cr constituent contains 20wt% Cr. The tribological characteristics of LCR304 were evaluated by pin-on-disk and foil air bearing rig testing from 25 to 650 C and compared to previous test results with PS304. For both tests, the friction coefficient decreased as temperature increased from 25 to 650 C. Wear generally decreased with increasing temperature for all pin-on-disk tests. LCR304 coated components produced the least wear of Inconel X-750 counterface materials at 427 and 650 C. These results indicate that the LCR304 coating has potential as a replacement for PS304 in, for example, low cycle (minimum wear) applications where dimensional stability is imperative.

Investigation of the crater-like microdefects induced by laser shock processing with aluminum foil as absorbent layer

NASA Astrophysics Data System (ADS)

Ye, Y. X.; Xuan, T.; Lian, Z. C.; Feng, Y. Y.; Hua, X. J.

2015-06-01

This paper reports that 3D crater-like microdefects form on the metal surface when laser shock processing (LSP) is applied. LSP was conducted on pure copper block using the aluminum foil as the absorbent material and water as the confining layer. There existed the bonding material to attach the aluminum foil on the metal target closely. The surface morphologies and metallographs of copper surfaces were characterized with 3D profiler, the optical microscopy (OM) or the scanning electron microscopy (SEM). Temperature increases of metal surface due to LSP were evaluated theoretically. It was found that, when aluminum foil was used as the absorbent material, and if there existed air bubbles in the bonding material, the air temperatures within the bubbles rose rapidly because of the adiabatic compression. So at the locations of the air bubbles, the metal materials melted and micromelting pool formed. Then under the subsequent expanding of the air bubbles, a secondary shock wave was launched against the micromelting pool and produced the crater-like microdefects on the metal surface. The temperature increases due to shock heat and high-speed deformation were not enough to melt the metal target. The temperature increase induced by the adiabatic compression of the air bubbles may also cause the gasification of the metal target. This will also help form the crater-like microdefects. The results of this paper can help to improve the surface quality of a metal target during the application of LSP. In addition, the results provide another method to fabricate 3D crater-like dents on metal surface. This has a potential application in mechanical engineering.

Foil Panel Mirrors for Nonimaging Applications

NASA Technical Reports Server (NTRS)

Kuyper, D. J.; Castillo, A. A.

1984-01-01

Large durable, lightweight mirrors made by bonding thick aluminum foil to honeycomb panels or other rigid, flat backings. Mirrors suitable for use as infrared shields, telescope doors, solar-furnance doors, advertising displays, or other reflectors that require low thermal emissivity and high specularity but do not require precise surface figure necessary for imaging.

Genesis Field Recovery

NASA Technical Reports Server (NTRS)

McNamara, K. M.

2005-01-01

The Genesis mission returned to Earth on September 8, 2004 after a nearly flawless three-year mission to collect solar matter. The intent was to deploy a drogue chute and parafoil high over the Utah desert and to catch the fragile payload capsule in mid-air by helicopter. The capsule would then be opened in a clean-room constructed for that purpose at UTTR, and a nitrogen purge was to be installed before transporting the science canister to JSC. Unfortunately, both chutes failed to deploy, causing the capsule to fall to the desert floor at a speed of nearly 200 MPH. Still, Genesis represents a milestone in the US space program, comprising the first sample return since the Apollo Missions as well as the first return of materials exposed to the space environment outside of low Earth orbit and beyond the Earth s magnetosphere for an extended period. We have no other comparable materials in all of our collections on Earth. The goal of the Genesis Mission was to collect a representative sample of the composition of the solar wind and thus, the solar nebula from which our solar system originated. This was done by allowing the naturally accelerated species to implant shallowly in the surfaces of ultra-pure, ultra-clean collector materials. These collectors included single crystal silicon (FZ and CZ), sapphire, silicon carbide; those materials coated with aluminum, silicon, diamond like carbon, and gold; and isotopically enriched polycrystalline diamond and amorphous carbon. The majority of these materials were distributed on five collector arrays. Three of the materials were housed in an electrostatic concentrator designed to increase the flux of low-mass ions. There was also a two-inch diameter bulk metallic glass collector and a gold foil, polished aluminum, and molybdenum coated platinum foil collector. An excellent review of the Genesis collector materials is offered in reference [1].

Preparation of Graphene Sheets by Electrochemical Exfoliation of Graphite in Confined Space and Their Application in Transparent Conductive Films.

PubMed

Wang, Hui; Wei, Can; Zhu, Kaiyi; Zhang, Yu; Gong, Chunhong; Guo, Jianhui; Zhang, Jiwei; Yu, Laigui; Zhang, Jingwei

2017-10-04

A novel electrochemical exfoliation mode was established to prepare graphene sheets efficiently with potential applications in transparent conductive films. The graphite electrode was coated with paraffin to keep the electrochemical exfoliation in confined space in the presence of concentrated sodium hydroxide as the electrolyte, yielding ∼100% low-defect (the D band to G band intensity ratio, I D /I G = 0.26) graphene sheets. Furthermore, ozone was first detected with ozone test strips, and the effect of ozone on the exfoliation of graphite foil and the microstructure of the as-prepared graphene sheets was investigated. Findings indicate that upon applying a low voltage (3 V) on the graphite foil partially coated with paraffin wax that the coating can prevent the insufficiently intercalated graphite sheets from prematurely peeling off from the graphite electrode thereby affording few-layer (<5 layers) holey graphene sheets in a yield of as much as 60%. Besides, the ozone generated during the electrochemical exfoliation process plays a crucial role in the exfoliation of graphite, and the amount of defect in the as-prepared graphene sheets is dependent on electrolytic potential and electrode distance. Moreover, the graphene-based transparent conductive films prepared by simple modified vacuum filtration exhibit an excellent transparency and a low sheet resistance after being treated with NH 4 NO 3 and annealing (∼1.21 kΩ/□ at ∼72.4% transmittance).

Transparent electrodes made with ultrasonic spray coating technique for flexible heaters

NASA Astrophysics Data System (ADS)

Wroblewski, G.; Krzemiński, J.; Janczak, D.; Sowiński, J.; Jakubowska, M.

2017-08-01

Transparent electrodes are one of the basic elements of various electronic components. The paper presents the preliminary results related to novel method of ultrasonic spray coating used for fabrication of transparent flexible electrodes. Experiments were conducted by means of specially made laboratory setup composed of ultrasonic spray generator and XYZ plotter. In the first part of the paper diverse solvents were used to determine the crucial technological parameters such as atomization voltage and fluid flow velocity. Afterwards paint containing carbon nanotubes suspended in the two solvent system was prepared and deposited on the polyethylene terephthalate foil. Thickness, roughness and electrical measurements were performed to designate the relations of technological parameters of ultrasonic spray coating on thickness, roughness, sheet resistance and optical transmission of fabricated samples.

Method for fabrication of ceramic dielectric films on copper foils

DOEpatents

Ma, Beihai; Narayanan, Manoj; Dorris, Stephen E.; Balachandran, Uthamalingam

2017-06-14

The present invention provides copper substrate coated with a lead-lanthanum-zirconium-titanium (PLZT) ceramic film, which is prepared by a method comprising applying a layer of a sol-gel composition onto a copper foil. The sol-gel composition comprises a precursor of a ceramic material suspended in 2-methoxyethanol. The layer of sol-gel is then dried at a temperature up to about 250.degree. C. The dried layer is then pyrolyzed at a temperature in the range of about 300 to about 450.degree. C. to form a ceramic film from the ceramic precursor. The ceramic film is then crystallized at a temperature in the range of about 600 to about 750.degree. C. The drying, pyrolyzing and crystallizing are performed under a flowing stream of an inert gas.

The measurement of radiation exposure of astronauts by radiochemical techniques

NASA Technical Reports Server (NTRS)

Brodzinski, R. L.

1971-01-01

Gamma analyses of the neutron-activated fecal samples from the Apollo 12 and 13 missions were completed, and the data are being evaluated. Samples of the exposed Apollo 12 solar wind composition foil and blank foils were obtained for analysis of the Po-2/0 (Pb-210, Rn-222) content. It is expected that the determination of the Po-210 content of these foils will yield the concentration of radon atoms incident on the foil while exposed to the lunar atmosphere, and this indirectly will permit an estimate of the average uranium concentration of the lunar surface. Proposals to measure the cosmic-ray intensity and energy spectra inside and outside of late Apollo and Project Skylab spacecraft by exposing and subsequently analyzing pure metal foils, and to measure the elemental mass balance in Project Skylab astronauts by instrumental neutron activation analysis of the intake and excreta are summarized.

Versatile transfer of aligned carbon nanotubes with polydimethylsiloxane as the intermediate

NASA Astrophysics Data System (ADS)

Zhu, Yanwu; Lim, Xiaodai; Chea Sim, Mong; Teck Lim, Chwee; Haur Sow, Chorng

2008-08-01

A simple technique to transfer aligned multi-walled carbon nanotubes (MWCNTs) is demonstrated in this work. With polydimethylsiloxane (PDMS) as the transfer medium, as-grown or patterned MWCNT arrays are directly transferred onto a wide variety of Pt-coated substrates such as glossy paper, cloth, polymers, glass slides, and metal foils at low temperatures. The surface of the transferred CNTs is cleaner with better alignment, compared with the as-grown one. Furthermore, the transferred CNTs show strong adhesion and good electric contact with the target substrates. A maximal current density of ~104 A cm-2 has been achieved from the CNT interconnects prepared with this technique. Because of the lower density and open-ended structures, improved field emission performance has been obtained from CNTs transferred on polymers, based on which flexible emitter devices can be fabricated. In addition, the surface of transferred CNTs becomes more hydrophilic, with an averaged contact angle of 93.4 ± 5.8°, in contrast to the super-hydrophobic as-grown CNT surface (contact angle 151.6 ± 5.5°). With versatile properties and flexible applications, the technique provides a simple and cost-effective way towards future nanodevices based on CNTs.

Surface-assisted DNA self-assembly: An enzyme-free strategy towards formation of branched DNA lattice.

PubMed

Bhanjadeo, Madhabi M; Nayak, Ashok K; Subudhi, Umakanta

2017-04-01

DNA based self-assembled nanostructures and DNA origami has proven useful for organizing nanomaterials with firm precision. However, for advanced applications like nanoelectronics and photonics, large-scale organization of self-assembled branched DNA (bDNA) into periodic lattices is desired. In this communication for the first time we report a facile method of self-assembly of Y-shaped bDNA nanostructures on the cationic surface of Aluminum (Al) foil to prepare periodic two dimensional (2D) bDNA lattice. Particularly those Y-shaped bDNA structures having smaller overhangs and unable to self-assemble in solution, they are easily assembled on the surface of Al foil in the absence of ligase. Field emission scanning electron microscopy (FESEM) analysis shows homogenous distribution of two-dimensional bDNA lattices across the Al foil. When the assembled bDNA structures were recovered from the Al foil and electrophoresed in nPAGE only higher order polymeric bDNA structures were observed without a trace of monomeric structures which confirms the stability and high yield of the bDNA lattices. Therefore, this enzyme-free economic and efficient strategy for developing bDNA lattices can be utilized in assembling various nanomaterials for functional molecular components towards development of DNA based self-assembled nanodevices. Copyright © 2017 Elsevier Inc. All rights reserved.

High efficiency graphene coated copper based thermocells connected in series

NASA Astrophysics Data System (ADS)

Sindhuja, Mani; Indubala, Emayavaramban; Sudha, Venkatachalam; Harinipriya, Seshadri

2018-04-01

Conversion of low-grade waste heat into electricity had been studied employing single thermocell or flowcells so far. Graphene coated copper electrodes based thermocells connected in series displayed relatively high efficiency of thermal energy harvesting. The maximum power output of 49.2W/m2 for normalized cross sectional electrode area is obtained at 60ºC of inter electrode temperature difference. The relative carnot efficiency of 20.2% is obtained from the device. The importance of reducing the mass transfer and ion transfer resistance to improve the efficiency of the device is demonstrated. Degradation studies confirmed mild oxidation of copper foil due to corrosion caused by the electrolyte.

Erosion of mylar and protection by thin metal films

NASA Technical Reports Server (NTRS)

Fraundorf, P.; Lindstrom, D.; Sandford, S.; Swan, P.; Walker, R.; Zinner, E.; Pailer, N.

1983-01-01

Mylar strips, 2.5 microns thick, uncoated and coated with 50A, 100A and 200A of Al, Pd, and Au/Pd were exposed on STS-5 in order to measure the erosion of mylar and to test means of protecting thin plastic foils commonly used for space experiments in low earth orbit. Analysis by optical microscopy, SEM and STEM investigation, EDX measurements, FTIR spectroscopy and weight loss measurements showed that while up to 75 percent of the uncoated mylar was eroded during exposure, thin coatings of the above metals can protect mylar for integrated oxygen-fluxes of at least 10 to the 21st atoms/sq cm.

Electric current heating calibration of a laser holographic nondestructive test system

NASA Technical Reports Server (NTRS)

Liu, H.-K.; Kurtz, R. L.

1975-01-01

Holographic NDT was used to measure small surface displacements controlled by electric heating by detecting the difference of the interference fringe patterns as viewed through the hologram on a real time basis. A perforated aluminum test plate, with the holes used to position thin metal foils, was used in the experiment. One of the foils was connected to an electric power source and small displacements of the foil were caused and controlled by Ohmic heating. An He-Ne laser was used to perform the holography.

A novel fast-neutron detector concept for energy-selective imaging and imaging spectroscopy.

PubMed

Cortesi, M; Dangendorf, V; Zboray, R; Prasser, H-M

2014-07-01

We present and discuss the operational principle of a new fast-neutron detector concept suitable for either energy-selective imaging or for imaging spectroscopy. The detector is comprised of a series of energy-selective stacks of converter foils immersed in a noble-gas based mixture, coupled to a position-sensitive charge readout. Each foil in the various stacks is made of two layers of different thicknesses, fastened together: a hydrogen-rich (plastic) layer for neutron-to-proton conversion, and a hydrogen-free coating to selectively stop/absorb the recoil protons below a certain energy cut-off. The neutron-induced recoil protons, that escape the converter foils, release ionization electrons in the gas gaps between consecutive foils. The electrons are then drifted towards and localized by a position-sensitive charge amplification and readout stage. Comparison of the images detected by stacks with different energy cut-offs allows energy-selective imaging. Neutron energy spectrometry is realized by analyzing the responses of a sufficient large number of stacks of different energy response and unfolding techniques. In this paper, we present the results of computer simulation studies and discuss the expected performance of the new detector concept. Potential applications in various fields are also briefly discussed, in particularly, the application of energy-selective fast-neutron imaging for nuclear safeguards application, with the aim of determining the plutonium content in Mixed Oxide (MOX) fuels.

X-ray optics made from thin plastic foils

NASA Astrophysics Data System (ADS)

Schnopper, H. W.; Barbera, M.; Ingram, R.; Silver, E.; Romaine, S.; Bandler, S.; Murray, S.; Christensen, F. E.; Hussain, A.; Collura, A.

2000-10-01

New design concepts and materials can be used to produce lightweight, thin foil approximations, to Wolter I and other X-ray optics. Structures are designed around a central hub and spacers that connect two (or three) spoked wheels. Figure defining, thin pins span the distance between the wheels. Thin, metal coated or multilayered, plastic foils can be formed into full cones, cylinders or spirals for X-ray telescopes or lenses. High resolution X-ray scattering data were obtained for single foils at Cu K (8 KeV). Multi-energy (0.28 - 8 KeV) data were obtained with a multichannel plate imager in a 17 m beam line with a point-to-point focusing, cylindrical X-ray lens with 14 shells. The largest shell has a diameter of 175 mm and a length of 100 mm. Typical images have a FWHM of 20 arcsec. The results indicate that a 60 cm diameter, 4.65 m focal length X-ray telescope can have an HPD of considerably less than 2 arcmin. This research is supported, in part by NASA Grant NAG5-5268, ONR Grant N00014-95-1-1248, and by institutional funding from the Smithsonian Astrophysical Observatory. The SAO multilayer facility receives support from NASA Grant NAG5-5095. This work made use of the MRSEC Shared Experimental Facilities at MIT supported by NSF Grant DMR94-00334.

Thin film rechargeable electrodes based on conductive blends of nanostructured olivine LiFePO4 and sucrose derived nanocarbons for lithium ion batteries.

PubMed

Praveen, P; Jyothsna, U; Nair, Priya; Ravi, Soumya; Balakrishnan, A; Subramanian, K R V; Nair, A Sreekumaran; Nair, V Shantikumar; Sivakumar, N

2013-08-01

The present study provides the first reports of a novel approach of electrophoretic co-deposition technique by which titanium foils are coated with LiFePO4-carbon nanocomposites synthesized by sol gel route and processed into high-surface area cathodes for lithium ion batteries. The study elucidates how sucrose additions as carbon source can affect the surface morphology and the redox reaction behaviors underlying these cathodes and thereby enhance the battery performance. The phase and morphological analysis were done using XRD and XPS where the LiFePO4 formed was confirmed to be a high purity orthorhombic system. From the analysis of the relevant electrochemical parameters using cyclic voltammetry and electrochemical impedance spectroscopy, a 20% increment and 90% decrement in capacity and impedance values were observed respectively. The composite electrodes also exhibited a specific capacity of 130 mA h/g. It has been shown that cathodes based on such composite systems can allow significant room for improvement in the cycling performance at the electrode/electrolyte interface.

Hybrid Physical Chemical Vapor Deposition of Magnesium Diboride Inside 3.9 GHz Mock Cavities

DOE PAGES

Lee, Namhoon; Withanage, Wenura K.; Tan, Teng; ...

2016-12-21

Magnesium diboride (MgB 2) is considered a candidate for the next generation superconducting radio frequency (SRF) cavities due to its higher critical temperature T c (40 K) and increased superheating field (H sh) compared to other conventional superconductors. These properties can lead to reduced BCS surface resistance (R BCS S) and residual resistance (R res), according to theoretical studies, and enhanced accelerating field (E acc) values. Here, we investigated the possibility of coating the inner surface of a 3.9 GHz SRF cavity with MgB 2 by using a hybrid physical-vapor deposition (HPCVD) system designed for this purpose. To simulate themore » actual 3.9 GHz SRF cavity, we also employed a stainless steel mock cavity for the study. The film qualities were characterized on small substrates that were placed at the selected positions within the cavity. MgB 2 films on stainless steel foils, niobium pieces, and SiC substrates showed transition temperatures in the range of 30-38 K with a c-axis-oriented crystallinity observed for films grown on SiC substrates. Dielectric resonator measurements at 18 GHz resulted in a quality factor of over 30 000 for the MgB 2 film grown on a SiC substrate. Furthermore, by employing the HPCVD technique, a uniform film was achieved across the cavity interior, demonstrating the feasibility of HPCVD for MgB 2 coatings for SRF cavities.« less

Hybrid Physical Chemical Vapor Deposition of Magnesium Diboride Inside 3.9 GHz Mock Cavities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Namhoon; Withanage, Wenura K.; Tan, Teng

Magnesium diboride (MgB 2) is considered a candidate for the next generation superconducting radio frequency (SRF) cavities due to its higher critical temperature T c (40 K) and increased superheating field (H sh) compared to other conventional superconductors. These properties can lead to reduced BCS surface resistance (R BCS S) and residual resistance (R res), according to theoretical studies, and enhanced accelerating field (E acc) values. Here, we investigated the possibility of coating the inner surface of a 3.9 GHz SRF cavity with MgB 2 by using a hybrid physical-vapor deposition (HPCVD) system designed for this purpose. To simulate themore » actual 3.9 GHz SRF cavity, we also employed a stainless steel mock cavity for the study. The film qualities were characterized on small substrates that were placed at the selected positions within the cavity. MgB 2 films on stainless steel foils, niobium pieces, and SiC substrates showed transition temperatures in the range of 30-38 K with a c-axis-oriented crystallinity observed for films grown on SiC substrates. Dielectric resonator measurements at 18 GHz resulted in a quality factor of over 30 000 for the MgB 2 film grown on a SiC substrate. Furthermore, by employing the HPCVD technique, a uniform film was achieved across the cavity interior, demonstrating the feasibility of HPCVD for MgB 2 coatings for SRF cavities.« less

Quantification and micron-scale imaging of spatial distribution of trace beryllium in shrapnel fragments and metallurgic samples with correlative fluorescence detection method and secondary ion mass spectrometry (SIMS)

PubMed Central

Abraham, Jerrold L.; Chandra, Subhash; Agrawal, Anoop

2014-01-01

Recently, a report raised the possibility of shrapnel-induced chronic beryllium disease (CBD) from long-term exposure to the surface of retained aluminum shrapnel fragments in the body. Since the shrapnel fragments contained trace beryllium, methodological developments were needed for beryllium quantification and to study its spatial distribution in relation to other matrix elements, such as aluminum and iron, in metallurgic samples. In this work, we developed methodology for quantification of trace beryllium in samples of shrapnel fragments and other metallurgic sample-types with main matrix of aluminum (aluminum cans from soda, beer, carbonated water, and aluminum foil). Sample preparation procedures were developed for dissolving beryllium for its quantification with the fluorescence detection method for homogenized measurements. The spatial distribution of trace beryllium on the sample surface and in 3D was imaged with a dynamic secondary ion mass spectrometry (SIMS) instrument, CAMECA IMS 3f SIMS ion microscope. The beryllium content of shrapnel (~100 ppb) was the same as the trace quantities of beryllium found in aluminum cans. The beryllium content of aluminum foil (~25 ppb) was significantly lower than cans. SIMS imaging analysis revealed beryllium to be distributed in the form of low micron-sized particles and clusters distributed randomly in X-Y-and Z dimensions, and often in association with iron, in the main aluminum matrix of cans. These observations indicate a plausible formation of Be-Fe or Al-Be alloy in the matrix of cans. Further observations were made on fluids (carbonated water) for understanding if trace beryllium in cans leached out and contaminated the food product. A direct comparison of carbonated water in aluminum cans and plastic bottles revealed that beryllium was below the detection limits of the fluorescence detection method (~0.01 ppb). These observations indicate that beryllium present in aluminum matrix was either present in an immobile form or its mobilization into the food product was prevented by a polymer coating on the inside of cans, a practice used in food industry to prevent contamination of food products. The lack of such coating in retained shrapnel fragments renders their surface a possible source of contamination for long-term exposure of tissues and fluids and induction of disease, as characterized in a recent study. Methodological developments reported here can be extended to studies of beryllium in electronics devices and components. PMID:25146877

Quantification and micron-scale imaging of spatial distribution of trace beryllium in shrapnel fragments and metallurgic samples with correlative fluorescence detection method and secondary ion mass spectrometry (SIMS).

PubMed

Abraham, J L; Chandra, S; Agrawal, A

2014-11-01

Recently, a report raised the possibility of shrapnel-induced chronic beryllium disease from long-term exposure to the surface of retained aluminum shrapnel fragments in the body. Since the shrapnel fragments contained trace beryllium, methodological developments were needed for beryllium quantification and to study its spatial distribution in relation to other matrix elements, such as aluminum and iron, in metallurgic samples. In this work, we developed methodology for quantification of trace beryllium in samples of shrapnel fragments and other metallurgic sample-types with main matrix of aluminum (aluminum cans from soda, beer, carbonated water and aluminum foil). Sample preparation procedures were developed for dissolving beryllium for its quantification with the fluorescence detection method for homogenized measurements. The spatial distribution of trace beryllium on the sample surface and in 3D was imaged with a dynamic secondary ion mass spectrometry instrument, CAMECA IMS 3f secondary ion mass spectrometry ion microscope. The beryllium content of shrapnel (∼100 ppb) was the same as the trace quantities of beryllium found in aluminum cans. The beryllium content of aluminum foil (∼25 ppb) was significantly lower than cans. SIMS imaging analysis revealed beryllium to be distributed in the form of low micron-sized particles and clusters distributed randomly in X-Y- and Z dimensions, and often in association with iron, in the main aluminum matrix of cans. These observations indicate a plausible formation of Be-Fe or Al-Be alloy in the matrix of cans. Further observations were made on fluids (carbonated water) for understanding if trace beryllium in cans leached out and contaminated the food product. A direct comparison of carbonated water in aluminum cans and plastic bottles revealed that beryllium was below the detection limits of the fluorescence detection method (∼0.01 ppb). These observations indicate that beryllium present in aluminum matrix was either present in an immobile form or its mobilization into the food product was prevented by a polymer coating on the inside of cans, a practice used in food industry to prevent contamination of food products. The lack of such coating in retained shrapnel fragments renders their surface a possible source of contamination for long-term exposure of tissues and fluids and induction of disease, as characterized in a recent study. Methodological developments reported here can be extended to studies of beryllium in electronics devices and components. © 2014 The Authors Journal of Microscopy © 2014 Royal Microscopical Society.

Study of Electric Explosion of Flat Micron-Thick Foils at Current Densities of (5-50)×10 8A/cm 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shelkovenko, T. A.; Pikuz, S. A.; Tilikin, I. N.

Electric explosions of flat Al, Тi, Ni, Cu, and Та foils with thicknesses of 1-16 μm, widths of 1-8 mm, and lengths of 5-11 mm were studied experimentally on the BIN, XP, and COBRA high-current generators at currents of 40-1000 kA and current densities of (5–50) × 10 8 A/cm 2. The images of the exploded foils were taken at different angles to the foil surface by using point projection radiography with an X-pinch hot spot as the radiation source, the spatial resolution and exposure time being 3 μm and 50 ps, respectively, as well by the laser probing methodmore » with a spatial resolution of 20 μm and an exposure time of 180 ps. In the course of foil explosion, rapidly expanding objects resembling the core and corona of an exploded wire were observed. It is shown that the core of the exploded foil has a complicated time-varying structure.« less

Study of Electric Explosion of Flat Micron-Thick Foils at Current Densities of (5-50)×10 8A/cm 2

DOE PAGES

Shelkovenko, T. A.; Pikuz, S. A.; Tilikin, I. N.; ...

2018-01-01

Electric explosions of flat Al, Тi, Ni, Cu, and Та foils with thicknesses of 1-16 μm, widths of 1-8 mm, and lengths of 5-11 mm were studied experimentally on the BIN, XP, and COBRA high-current generators at currents of 40-1000 kA and current densities of (5–50) × 10 8 A/cm 2. The images of the exploded foils were taken at different angles to the foil surface by using point projection radiography with an X-pinch hot spot as the radiation source, the spatial resolution and exposure time being 3 μm and 50 ps, respectively, as well by the laser probing methodmore » with a spatial resolution of 20 μm and an exposure time of 180 ps. In the course of foil explosion, rapidly expanding objects resembling the core and corona of an exploded wire were observed. It is shown that the core of the exploded foil has a complicated time-varying structure.« less

Structural stiffness and Coulomb damping in compliant foil journal bearings: Theoretical considerations

NASA Astrophysics Data System (ADS)

Ku, C.-P. Roger; Heshmat, Hooshang

1994-07-01

Compliant foil bearings operate on either gas or liquid, which makes them very attractive for use in extreme environments such as in high-temperature aircraft turbine engines and cryogenic turbopumps. However, a lack of analytical models to predict the dynamic characteristics of foil bearings forces the bearing designer to rely on prototype testing, which is time-consuming and expensive. In this paper, the authors present a theoretical model to predict the structural stiffness and damping coefficients of the bump foil strip in a journal bearing or damper. Stiffness is calculated based on the perturbation of the journal center with respect to its static equilibrium position. The equivalent viscous damping coefficients are determined based on the area of a closed hysteresis loop of the journal center motion. The authors found, theoretically, that the energy dissipated from this loop was mostly contributed by the frictional motion between contact surfaces. In addition, the source and mechanism of the nonlinear behavior of the bump foil strips were examined. With the introduction of this enhanced model, the analytical tools are now available for the design of compliant foil bearings.

Effect of applied voltage on surface properties of anodised titanium in mixture of β-glycerophosphate (β-GP) and calcium acetate (CA)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chuan, Lee Te, E-mail: gd130079@siswa.uthm.edu.my; Rathi, Muhammad Fareez Mohamad, E-mail: cd110238@siswa.uthm.edu.my; Abidin, Muhamad Yusuf Zainal, E-mail: cd110221@siswa.uthm.edu.my

Anodic oxidation is a surface modification method which combines electric field driven metal and oxygen ion diffusion for formation of oxide layer on the anode surface. This method has been widely used to modify the surface morphology of biomaterial especially titanium. This study aimed to investigate the effect of applied voltage on titanium. Specifically, the titanium foil was anodised in mixture of β-glycerophosphate disodium salt pentahydrate (β-GP) and calcium acetate monohydrate (CA) with different applied voltage (50-350 V), electrolyte concentration (0.04 M β-GP + 0.4 M CA), anodising time (10minutes) and current density (50 and 70 mA.cm{sup −2}) at room temperature. Surfacemore » oxide properties of anodised titanium were characterised by digital single-lens reflex camera (DSLR camera), field emission scanning electron microscope (FESEM) and atomic force microscopy (AFM). At lower applied voltage (≤150 V), surface of titanium foils were relatively smooth. With increasing applied voltage (≥250 V), the oxide layer became more porous and donut-shaped pores were formed on the surface of titanium foils. The AFM results indicated that the surface roughness of anodised titanium increases with increasing of applied voltage. The porous and rough surface is able to promote the osseointegration and reduce the suffering time of patient.« less

Desorption of SVOCs from Heated Surfaces in the Form of Ultrafine Particles.

PubMed

Wallace, Lance A; Ott, Wayne R; Weschler, Charles J; Lai, Alvin C K

2017-02-07

Ultrafine particles (UFP) produced by electric heating of stoves and metal cooking pans, absent food, have been hypothesized to be created from a surface film of semivolatile organic compounds (SVOCs) sorbed from the surrounding air. This study tests that hypothesis by size-resolved measurements extending the lower range of the UFP studied from 10 to 2.3 nm, and including other surfaces (glass, aluminum, and porcelain). Heating glass Petri dishes or squares of aluminum foil to about 350-400 °C for 4-6 min removed all sorbed organic substances completely. Subsequent exposure of these "clean" Petri dishes and foil squares to indoor air in two different residences for successively longer periods (1 h to 281 days), followed by heating the materials for 4-6 min, indicated a strong relationship of the number, size distribution, and mass of the UFP to the time exposed. Estimates of the accumulation rate of SVOCs on surfaces were similar to those in studies of organic film buildup on indoor windows. Transfer of skin oils by touching the glass or foil surfaces, or after washing the glass surface with detergent and bare hands, was also observed, with measured particle production comparable with that produced by long-term exposure to indoor air.

Roll-to-roll production of spray coated N-doped carbon nanotube electrodes for supercapacitors

NASA Astrophysics Data System (ADS)

Karakaya, Mehmet; Zhu, Jingyi; Raghavendra, Achyut J.; Podila, Ramakrishna; Parler, Samuel G.; Kaplan, James P.; Rao, Apparao M.

2014-12-01

Although carbon nanomaterials are being increasingly used in energy storage, there has been a lack of inexpensive, continuous, and scalable synthesis methods. Here, we present a scalable roll-to-roll (R2R) spray coating process for synthesizing randomly oriented multi-walled carbon nanotubes electrodes on Al foils. The coin and jellyroll type supercapacitors comprised such electrodes yield high power densities (˜700 mW/cm3) and energy densities (1 mW h/cm3) on par with Li-ion thin film batteries. These devices exhibit excellent cycle stability with no loss in performance over more than a thousand cycles. Our cost analysis shows that the R2R spray coating process can produce supercapacitors with 10 times the energy density of conventional activated carbon devices at ˜17% lower cost.

X-ray mirror prototype based on cold shaping of thin glass foils

NASA Astrophysics Data System (ADS)

Basso, Stefano; Civitani, Marta; Ghigo, Mauro; Hołyszko, Joanna; Pareschi, Giovanni; Salmaso, Bianca; Vecchi, Gabriele; Burwitz, Vadim; Pelliciari, Carlo; Hartner, Gisela D.; Breunig, Elias

2017-08-01

The Slumping Glass Optics technology for the fabrication of astronomical X-ray mirrors has been developed in recent years in USA and Europe. The process has been used for making the mirrors of the Nustar, mission. The process starts with very thin glass foils hot formed to copy the profile of replication moulds. At INAF - Osservatorio Astronomico di Brera a process based on cold shaping is being developed, based on an integration method involving the use of interconnecting ribs for making stacks. Each glass foil in the stack is shaped onto a very precise integration mould and the correct shape is frozen by means of glued ribs that act as spacers between one layer and the next one (the first layers being attached to a thick substrate). Therefore, the increasing availability of flexible glass foils with a thickness of a few tens of microns (driven by electronic market for ultra-thin displays) opens new possibilities for the fabrication of X-ray mirrors. This solution appears interesting especially for the fabrication of mirrors for hard X-rays (with energy > 10 keV) based on multilayer coatings, taking advantage from the intrinsic low roughness of the glass foils that should grant a low scattering level. The stress frozen on the glass due to the cold shaping is not negligible, but it is kept into account in the errors of the X-ray optics design. As an exercise, we have considered the requirements and specs of the FORCE hard Xray mission concept (being studied by JAXA) and we have designed the mirror modules assuming the cold slumping as a fabrication method. In the meantime, a prototype (representative of the FORCE mirror modules) is being design and integrated in order to demonstrate the feasibility and the capacity to reach good angular resolution.

Mini-Brayton heat source assembly design study. Volume 2: Titan 3C mission. [minimum weight modifications

NASA Technical Reports Server (NTRS)

1973-01-01

Major conclusions of the space shuttle heat source assembly study are reported that project a minimum weight design for a Titan 3 C synchronous orbit mission; requirements to recover the heat source in orbit are eliminated. This concept permits location of the heat source end enclosure supports and heat source assembly support housing in a low temperature region external to the insulation enclosure and considers titanium and beryllium alloys for these support elements. A high melting insulation blanket consisting of nickel foil coated with zirconia, or of gold foil separated with glass fiber layers, is selected to provide emergency cooling in the range 2000 to 2700 F to prevent the isotope heat source from reaching unsafe temperatures. A graphic view of the baseline heat source assembly is included.

Nanolaminate deformable mirrors

DOEpatents

Papavasiliou, Alexandros P.; Olivier, Scot S.

2009-04-14

A deformable mirror formed out of two layers of a nanolaminate foil attached to a stiff substrate is introduced. Deformation is provided by an electrostatic force between two of the layers. The internal stiffness of the structure allows for high-spatial-frequency shapes. The nanolaminate foil of the present invention allows for a high-quality mirror surface. The device achieves high precision in the vertical direction by using foils with accurately controlled thicknesses, but does not require high precision in the lateral dimensions, allowing such mirrors to be fabricated using crude lithography techniques. Such techniques allow structures up to about the meter scale to be fabricated.

Multilayer based lab-on-a-chip-systems for substance testing

NASA Astrophysics Data System (ADS)

Sonntag, Frank; Grünzner, Stefan; Schmieder, Florian; Busek, Mathias; Klotzbach, Udo; Franke, Volker

2015-03-01

An integrated technology chain for laser-microstructuring and bonding of polymer foils for fast, flexible and low-cost manufacturing of multilayer lab-on-a-chip devices especially for complex cell and tissue culture applications, which provides pulsatile fluid flow within physiological ranges at low media-to-cells ratio, was developed and established. Initially the microfluidic system is constructively divided into individual layers which are formed by separate foils or plates. Based on the functional boundary conditions and the necessary properties of each layer the corresponding foils and plates are chosen. In the third step the foils and plates are laser microstructured and functionalized from both sides. In the fourth and last manufacturing step the multiple plates and foils are joined using thermal diffusion bonding. Membranes for pneumatically driven valves and micropumps where bonded via chemical surface modification. Based on the established lab-on-a-chip platform for perfused cell-based assays, a multilayer microfluidic system with two parallel connected cell culture chambers was successfully implemented.

Preventing the dissolution of lithium polysulfides in lithium-sulfur cells by using Nafion-coated cathodes.

PubMed

Oh, Soo Jung; Lee, Jun Kyu; Yoon, Woo Young

2014-09-01

The principal drawback of lithium-sulfur batteries is the dissolution of long-chain lithium polysulfides into the electrolyte, which limits cycling performance. To overcome this problem, we focused on the development of a novel cathode as well as anode material and designed Nafion-coated NiCrAl/S as a cathode and lithium powder as an anode. Nafion-coated NiCrAl/S cathode was synthesized using a two-step dip-coating technique. The lithium-powder anode was used instead of a lithium-foil anode to prohibit dendrite growth and to improve on the electrochemical behaviors. The cells showed an initial discharge capacity of about 900 mA g(-1) and a final discharge capacity of 772 mA g(-1) after 100 cycles at 0.1 C-rate. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) demonstrate that using the Nafion-coated NiCrAl/S cathode can suppress the dissolution of long-chain lithium polysulfides. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Evidence for Coincident Fusion Products Using Silicon Surface-barrier Detectors

NASA Astrophysics Data System (ADS)

Jones, Steven; Scott, Mark; Keeney, Frank

2002-10-01

We report experimental results showing coincident proton and triton production from the reaction: d + d --> t (1.01 MeV) + p (3.02 MeV). Partially-deuterided thin titanium foils were positioned between two silicon surface-barrier detectors which were mounted in a small cylindrical vacuum chamber which also served as a Faraday cage. We performed Monte Carlo studies using the SRIM code to determine the expected energies of arriving particles after they exit the host foil. The dual-coincidence requirement reduces background to very low levels so that low yields from very thin TiD foils can be readily detected. In one sequence of experiments, we observed 74 foreground coincidences in the regions of interest compared with 24 background counts; the statistical significance is approximately ten standard deviations. A striking advance is that the repeatability from the dual-coincidence experiments is currently greater than 70%.

Facile preparation of dendritic Ag-Pd bimetallic nanostructures on the surface of Cu foil for application as a SERS-substrate

NASA Astrophysics Data System (ADS)

Yi, Zao; Tan, Xiulan; Niu, Gao; Xu, Xibin; Li, Xibo; Ye, Xin; Luo, Jiangshan; Luo, Binchi; Wu, Weidong; Tang, Yongjian; Yi, Yougen

2012-05-01

Dendritic Ag-Pd bimetallic nanostructures have been synthesized on the surface of Cu foil via a multi-stage galvanic replacement reaction (MGRR) of Ag dendrites in a Na2PdCl4 solution. After five stages of replacement reaction, one obtained structures with protruding Ag-Pd flakes; these will mature into many porous structures with a few Ag atoms that are left over dendrites. The dendritic Ag-Pd bimetallic nanostructures were characterized by transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray (EDX), selected area electron diffraction (SAED) and X-ray photoelectron spectroscopy (XPS). The morphology of the products strongly depended on the stage of galvanic replacement reaction and reaction temperature. The morphology and composition-dependent surface-enhanced Raman scattering (SERS) of the as-synthesized Ag-Pd bimetallic nanostructures were investigated. The effectiveness of these dendritic Ag-Pd bimetallic nanostructures on the surface of Cu foil as substrates toward SERS detection was evaluated by using rhodamine 6G (R6G) as a probe molecule. The results indicate that as-synthesized dendritic Ag-Pd bimetallic nanostructures are good candidates for SERS spectroscopy.

Carbon Dioxide Electroreduction using a Silver-Zinc Alloy [CO 2 Electroreduction on a Ag-Zn Alloy

DOE PAGES

Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R.; ...

2017-02-20

We report on CO 2 electroreduction activity and selectivity of a polycrystalline AgZn foil in aqueous bicarbonate electrolyte. X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) measurements show that the alloy foil was slightly enriched in zinc both at the surface and in the bulk, with a surface alloy composition of 61.3±5.4 at % zinc and with Ag 5Zn 8 as the most prominent bulk phase. AgZn is active for CO 2 reduction; CO is the main product, likely due to the weak CO binding energy of the surface, with methane and methanol emerging as minor products. Compared to puremore » silver and pure zinc foils, enhancements in activity and selectivity for methane and methanol are observed. A five-fold increase is observed in the combined partial current densities for methane and methanol at –1.43 V vs. the reversible hydrogen electrode (RHE), representing a four- to six-fold increase in faradaic efficiency. Here, such enhancements indicate the existence of a synergistic effect between silver and zinc at the surface of the alloy that contributes to the enhanced formation of further reduced products.« less

Some composite bearing and seal materials for gas turbine applications: A review

NASA Technical Reports Server (NTRS)

Sliney, Harold E.

1989-01-01

A review is made of the selection and tribological testing of materials for high-temperature bearings and seals. The goal is to achieve good tribological properties over a wide range of temperatures because bearings and seals must be functional from low temperature start-up conditions on up to the maximum temperatures encountered during engine operation. Plasma sprayed composite coatings with favorable tribological properties from 25 to 900 C are discussed. The performance of these coatings in simple tribological bench tests is described. Examples are also given of their performance in high-speed sliding contact seals and as Stirling cylinder liner materials, and as back up lubricants for compliant foil gas bearings.

Direct hot slumping and accurate integration process to manufacture prototypal x-ray optical units made of glass

NASA Astrophysics Data System (ADS)

Civitani, M.; Ghigo, M.; Basso, S.; Proserpio, L.; Spiga, D.; Salmaso, B.; Pareschi, G.; Tagliaferri, G.; Burwitz, V.; Hartner, G.; Menz, B.; Bavdaz, M.; Wille, E.

2013-09-01

X-ray telescopes with very large collecting area, like the proposed International X-ray Observatory (IXO, with around 3 m2 at 1 keV), need to be composed of a large number high quality mirror segments, aiming at achieving an angular resolution better than 5 arcsec HEW (Half-Energy-Width). A possible technology to manufacture the modular elements that will compose the entire optical module, named X-ray Optical Units (XOUs), consists of stacking in Wolter-I configuration several layers of thin foils of borosilicate glass, previously formed by hot slumping. The XOUs are subsequently assembled to form complete multi-shell optics with Wolter-I geometry. The achievable global angular resolution of the optic relies on the required surface shape accuracy of slumped foils, on the smoothness of the mirror surfaces and on the correct integration and co-alignment of the mirror segments. The Brera Astronomical Observatory (INAF-OAB) is leading a study, supported by ESA, concerning the implementation of the IXO telescopes based on thin slumped glass foils. In addition to the opto-mechanical design, the study foresees the development of a direct hot slumping thin glass foils production technology. Moreover, an innovative assembly concept making use of Wolter-I counter-form moulds and glass reinforcing ribs is under development. The ribs connect pairs of consecutive foils in an XOU stack, playing a structural and a functional role. In fact, as the ribs constrain the foil profile to the correct shape during the bonding, they damp the low-frequency profile errors still present on the foil after slumping. A dedicated semirobotic Integration MAchine (IMA) has been realized to this scope and used to build a few integrated prototypes made of several layers of slumped plates. In this paper we provide an overview of the project, we report the results achieved so far, including full illumination intra-focus X-ray tests of the last integrated prototype that are compliant with a HEW of around 17''.

Laser-induced structure formation on stretched polymer foils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bityurin, Nikita; Arnold, Nikita; Baeuerle, Dieter

2007-04-15

Noncoherent structures that develop during UV laser ablation of stretched semicrystalline polymer foils are a very general phenomenon. A thermodynamic model based on stress relaxation within the modified layer of the polymer surface describes the main features of the observed phenomena, and, in particular, the dependence of the period of structures on laser wavelength, fluence, and number of laser pulses.

Heat and mass transfer are in the interaction of multi-pulsed spray with vertical surfaces in the regime of evaporative cooling

NASA Astrophysics Data System (ADS)

Karpov, P. N.; Nazarov, A. D.; Serov, A. F.; Terekhov, V. I.

2017-10-01

Sprays with a periodic supply drop phase have great opportunities to control the processes of heat transfer. We can achieve optimal evaporative modes of cooling by changing the pulse duration and the repetition frequency while minimizing flow of the liquid phase. Experimental data of investigation of local heat transfer for poorly heated large surface obtained on the original stand with multi nozzle managed the irrigation system impact of the gas-droplet flow present in this work. Researches on the contribution to the intensification of spray options were conducted. Also the growth rate was integral and local heat. Information instantaneous distribution of the heat flux in the description of the processes have helped us. Managed to describe two basic modes of heat transfer: Mode “insular” foil cooling and thick foil with forming of streams. Capacitive sensors allow to monitor the dynamics of the foil thickness, the birth-belt flow, forming and the evolution of waves generated by “bombing” the surface with the droplets.

Investigation into flow boiling heat transfer in a minichannel with enhanced heating surface

NASA Astrophysics Data System (ADS)

Piasecka, Magdalena

2012-04-01

The paper presents results of flow boiling in a minichannel of 1.0 mm depth. The heating element for the working fluid (FC-72) that flows along the minichannel is a single-sided enhanced alloy foil made from Haynes-230. Microrecesses were formed on the selected area of the heating foil by laser technology. The observations of the flow structure were carried out through a piece of glass. Simultaneously, owing to the liquid crystal layer placed on the opposite side of the enhanced foil surface, it was possible to measure temperature distribution on the heating wall through another piece of glass. The experimental research has been focused on the transition from single phase forced convection to nucleate boiling, i.e. the zone of boiling incipience and further development of boiling. The objective of the paper is determining of the void fraction for some cross-sections of selected images for increasing heat fluxes supplied to the heating surface. The flow structure photos were processed in Corel graphics software and binarized. The analysis of phase volumes was developed in Techystem Globe software.

Applications of beam-foil spectroscopy to atomic collisions in solids

NASA Technical Reports Server (NTRS)

Sellin, I. A.

1976-01-01

Some selected papers presented at the Fourth International Conference on Beam-Foil Spectroscopy, whose results are of particular pertinence to ionic collision phenomena in solids, are reviewed. The topics discussed include solid target effects and means of surmounting them in the measurement of excited projectile ion lifetimes for low-energy heavy element ions; the electron emission accompanying the passage of heavy particles through solid targets; the collision broadening of X rays emitted from 100 keV ions moving in solids; residual K-shell excitation in chlorine ions penetrating carbon; comparison between 40 MeV Si on gaseous SiH4 targets at 300 mtorr and 40 MeV Si on Al; and the emergent surface interaction in beam-foil spectroscopy. A distinct overlap of interests between the sciences of beam-foil spectroscopy and atomic collisions in solids is pointed out.

Total inorganic arsenic detection in real water samples using anodic stripping voltammetry and a gold-coated diamond thin-film electrode.

PubMed

Song, Yang; Swain, Greg M

2007-06-12

An accurate method for total inorganic arsenic determination in real water samples was developed using differential pulse anodic stripping voltammetry (DPASV) and a Au-coated boron-doped diamond thin-film electrode. Keys to the method are the use of a conducting diamond platform and solid phase extraction for sample preparation. In the method, the As(III) present in the sample is first detected by DPASV. The As(V) present is then reduced to As(III) by reaction with Na2SO3 and this is followed by a second detection of As(III) by DPASV. Interfering metal ions (e.g., Cu(II)) that cause decreased electrode response sensitivity for arsenic in real samples are removed by solid phase extraction as part of the sample preparation. For example, Cu(II) caused a 30% decrease in the As stripping peak current at a solution concentration ratio of 3:1 (Cu(II)/As(III)). This loss was mitigated by passage of the solution through a Chelex 100 cation exchange resin. After passage, only a 5% As stripping current response loss was seen. The effect of organic matter on the Au-coated diamond electrode response for As(III) was also evaluated. Humic acid at a 5 ppm concentration caused only a 9% decrease in the As stripping peak charge for Au-coated diamond. By comparison, a 50% response decrease was observed for Au foil. Clearly, the chemical properties of the diamond surface in the vicinity of the metal deposits inhibit molecular adsorption on at least some of the Au surface. The method provided reproducible and accurate results for total inorganic arsenic in two contaminated water samples provided by the U.S. Bureau of Reclamation. The total inorganic As concentration in the two samples, quantified by the standard addition method, was 23.2+/-2.9 ppb for UV plant influent water and 16.4+/-0.9 ppb for Well 119 water (n=4). These values differed from the specified concentrations by less than 4%.

An ultrasonic method for determination of elastic moduli, density, attenuation and thickness of a polymer coating on a stiff plate.

PubMed

Lavrentyev, A I; Rokhlin, S I

2001-04-01

An ultrasonic method proposed by us for determination of the complete set of acoustical and geometrical properties of a thin isotropic layer between semispaces (J. Acoust. Soc. Am. 102 (1997) 3467) is extended to determination of the properties of a coating on a thin plate. The method allows simultaneous determination of the coating thickness, density, elastic moduli and attenuation (longitudinal and shear) from normal and oblique incidence reflection (transmission) frequency spectra. Reflection (transmission) from the coated plate is represented as a function of six nondimensional parameters of the coating which are determined from two experimentally measured spectra: one at normal and one at oblique incidence. The introduction of the set of nondimensional parameters allows one to transform the reconstruction process from one search in a six-dimensional space to two searches in three-dimensional spaces (one search for normal incidence and one for oblique). Thickness, density, and longitudinal and shear elastic moduli of the coating are calculated from the nondimensional parameters determined. The sensitivity of the method to individual properties and its stability against experimental noise are studied and the inversion algorithm is accordingly optimized. An example of the method and experimental measurement for comparison is given for a polypropylene coating on a steel foil.

Highly intensified emission of laser-accelerated electrons from a foil target through an additional rear laser plasma

NASA Astrophysics Data System (ADS)

Inoue, Shunsuke; Nakamiya, Yoshihide; Teramoto, Kensuke; Hashida, Masaki; Sakabe, Shuji

2018-04-01

Intensification of electrons escaping from an intense laser-produced plasma is demonstrated by using double femtosecond laser pulses. The electron density distribution at the rear surface of a laser-irradiated foil target is controlled by preirradiation to suppress sheath field growth and to expand the plasma into which the fast electrons are released. Consequently, the number of electrons escaping from the plasma that have an energy of 380 keV increases by a factor of 7. The experimental results are well explained by numerical simulations of a foil plasma with a preformed plasma and analytical evaluations considering the plasma expansion.

FoilSim: Basic Aerodynamics Software Created

NASA Technical Reports Server (NTRS)

Peterson, Ruth A.

1999-01-01

FoilSim is interactive software that simulates the airflow around various shapes of airfoils. The graphical user interface, which looks more like a video game than a learning tool, captures and holds the students interest. The software is a product of NASA Lewis Research Center s Learning Technologies Project, an educational outreach initiative within the High Performance Computing and Communications Program (HPCCP).This airfoil view panel is a simulated view of a wing being tested in a wind tunnel. As students create new wing shapes by moving slider controls that change parameters, the software calculates their lift. FoilSim also displays plots of pressure or airspeed above and below the airfoil surface.

Synthetic Graphene Grown by Chemical Vapor Deposition on Copper Foils

DTIC Science & Technology

2013-04-11

b) Transparent PMMA /graphene membrane floating on copper etchant. (c) Three layers of stacked CVD graphene on a cover glass made by consecutively...insulating substrate is a critical step for fabricating electronic devices. PMMA -assisted transfer techniques are commonly applied because of their...simplicity and repeatability.13 In a typical transfer, a graphene film on Cu substrate was first coated with PMMA (950PMMA-A4, MicroChem)b by spin

Advanced Neutron Radiographic Equipment within the US Army

DTIC Science & Technology

2014-01-29

generator was then placed into a moderator assembly made mainly of high density polyethylene ( HDPE ), with a collimator that was a gadolinium (Gd) coated...port made with various slabs, bricks, sheets, and foils of materials containing lead, boron, and HDPE . This port merely functioned as a scatter...conical inserts made of HDPE , lead, and Gd infused paint. The trial experiments have shown that with the system running at its designed maximum power

Induction Bonding of Prepreg Tape and Titanium Foil

NASA Technical Reports Server (NTRS)

Messier, Bernadette C.; Hinkley, Jeffrey A.; Johnston, Norman J.

1998-01-01

Hybrid structural laminates made of titanium foil and carbon fiber reinforced polymer composite offer a potential for improved performance in aircraft structural applications. To obtain information needed for the automated fabrication of hybrid laminates, a series of bench scale tests were conducted of the magnetic induction bonding of titanium foil and thermoplastic prepreg tape. Foil and prepreg specimens were placed in the gap of a toroid magnet mounted in a bench press. Several magnet power supplies were used to study power at levels from 0.5 to 1.75 kW and frequencies from 50 to 120 kHz. Sol-gel surface-treated titanium foil, 0.0125 cm thick, and PIXA/IM7 prepreg tape were used in several lay-up configurations. Data were obtained on wedge peel bond strength, heating rate, and temperature ramp over a range of magnet power levels and frequencies at different "power-on" times for several magnet gap dimensions. These data will be utilized in assessing the potential for automated processing. Peel strengths of foil-tape bonds depended on the maximum temperature reached during heating and on the applied pressure. Maximum peel strengths were achieved at 1.25kW and 8OkHz. Induction heating of the foil appears to be capable of good bonding up to 10 plies of tape. Heat transfer calculations indicate that a 20-40 C temperature difference exists across the tape thickness during heat-up.

First-Principle Investigation on the Bonding Mechanism of the Silicon Particles on the Copper Foil in Cold Spraying

NASA Astrophysics Data System (ADS)

Song, Jun; Liu, Juanfang; Chen, Qinghua

For lithium-ion batteries, the composite silicon-based electrodes can prevent from losing electrical contact and hence retain the capacity over many cycles. To uncover the adhesion mechanism on the interface formed by the copper foil and the thin silicon coatings during the cold gas dynamic spraying (CGDS) at the microscopic level, the first-principle calculations are performed to investigate the interface properties between them. The ideal work of adhesion, fracture toughness and the interface electronic properties are analyzed. It is found that all the atoms on the interface have vertical displacements, and covalent and ionic bonds are formed between the interfacial Cu and Si atoms which increases the bonding strength. However, the ideal work of adhesion on the interface is lower than one of the Cu bulk and Si bulk, so that fracture would be easier to take place on the interface.

Large-area beryllium metal foils

NASA Astrophysics Data System (ADS)

Stoner, J. O., Jr.

1997-02-01

To manufacture beryllium filters having diameters up to 82 mm and thicknesses in the range 0.1-1 μm, it was necessary to construct apparatus in which the metal could safely be evaporated, and then to find an acceptable substrate and evaporation procedure. The metal was evaporated resistively from a tantalum dimple boat mounted in a baffled enclosure that could be placed in a conventional vacuum bell jar, obviating the need for a dedicated complete vacuum system. Substrates were 102 mm × 127 mm × 0.05 mm cleaved mica sheets, coated with 0.1 μm of NaCl, then with approximately 50 μg/cm 2 of cellulose nitrate. These were mounted on poly(methyl methacrylate) sheets 3 mm thick that were in turn clamped to a massive aluminum block for thermal stability. Details of the processes for evaporation, float off, and mounting are given, and the resulting foils described.

Neutron-driven gamma-ray laser

DOEpatents

Bowman, Charles D.

1990-01-01

A lasing cylinder emits laser radiation at a gamma-ray wavelength of 0.87 .ANG. when subjected to an intense neutron flux of about 400 eV neutrons. A 250 .ANG. thick layer of Be is provided between two layers of 100 .ANG. thick layer of .sup.57 Co and these layers are supported on a foil substrate. The coated foil is coiled to form the lasing cylinder. Under the neutron flux .sup.57 Co becomes .sup.58 Co by neutron absorption. The .sup.58 Co then decays to .sup.57 Fe by 1.6 MeV proton emission. .sup.57 Fe then transitions by mesne decay to a population inversion for lasing action at 14.4 keV. Recoil from the proton emission separates the .sup.57 Fe from the .sup.57 Co and into the Be, where Mossbauer emission occurs at a gamma-ray wavelength.

Enhancement of light yield and stability of radio-pure tetraphenyl-butadiene based coatings for VUV light detection in cryogenic environments

NASA Astrophysics Data System (ADS)

Baudis, L.; Benato, G.; Dressler, R.; Piastra, F.; Usoltsev, I.; Walter, M.

2015-09-01

The detection of VUV scintillation light in (liquid) argon (LAr) detectors commonly includes a reflector with a fluorescent coating, converting UV photons to visible light. The light yield of these detectors depends directly on the conversion efficiency. Several coating/reflector combinations were produced using VM2000, a specular reflecting multi-layer polymer, and Tetratex®, a diffuse reflecting PTFE fabric, as reflector foils. The light yield of these coatings was optimised and has been measured in a dedicated liquid argon setup built at the University of Zurich. It employs a small, 1.3 kg LAr cell viewed by a 3-inch, low radioactivity PMT of type R11065-10 from Hamamatsu. The cryogenic stability of these coatings was additionally studied. The optimum reflector/coating combination was found to be Tetratex® dip-coated with Tetraphenyl-butadiene with a thickness of 0.9 mg/cm2, resulting in a 3.6 times higher light yield compared to uncoated VM2000. Its performance was stable in long-term measurements, performed up to 100 days in liquid argon. This coated reflector was also investigated concerning radioactive impurities and found to be suitable for current and upcoming low-background experiments. Therefore it is used for the liquid argon veto in Phase II of the GERDA neutrinoless double beta decay experiment.

Tunable growth of TiO2 nanostructures on Ti substrates

NASA Astrophysics Data System (ADS)

Peng, Xinsheng; Wang, Jingpeng; Thomas, Dan F.; Chen, Aicheng

2005-10-01

A simple and facile method is described to directly synthesize TiO2 nanostructures on titanium substrates by oxidizing Ti foil using small organic molecules as the oxygen source. The effect of reaction temperature and oxygen source on the formation of the TiO2 nanostructures has been studied using scanning electron microscopy, x-ray diffraction, transmission electron microscopy, Raman spectroscopy and water contact angle measurement. Polycrystalline grains are formed when pure oxygen and formic acid are used as the oxygen source; elongated micro-crystals are produced when water vapour is used as the oxygen source; oriented and aligned TiO2 nanorod arrays are synthesized when ethanol, acetaldehyde or acetone are used as the oxygen source. The growth mechanism of the TiO2 nanostructures is discussed. The diffusion of Ti atoms to the oxide/gas interface via the network of the grain boundaries of the thin oxide layer is the determining factor for the formation of well-aligned TiO2 nanorod arrays. The wetting properties of the TiO2 nanostructured surfaces formed are dictated by their structure, varying from a hydrophilic surface to a strongly hydrophobic surface as the surface structure changes from polycrystalline grains to well-aligned nanorod arrays. This tunable growth of TiO2 nanostructures is desirable for promising applications of TiO2 nanostructures in the development of optical devices, sensors, photo-catalysts and self-cleaning coatings.

3D Structure of the Inverse Karman Vortex Street in the Wake of a Flapping Foil

NASA Astrophysics Data System (ADS)

Bozkurttas, Meliha; Mittal, Rajat; Dong, Haibo

2004-11-01

Flapping foils are being considered for lift generation and/or propulsion in Micro Aerial Vehicles (MAVs) and Autonomous Underwater Vehicles (AUVs). In the present study, a DNS/LES solver that is capable of simulating these flows in all their complexity will be used. The flow around a NACA 0012 foil undergoing pitch oscillation at a chord Reynolds number of 12600 has been investigated and the comparison of mean thrust coefficient results with the experiment has indicated significant under-prediction of the thrust although good match is observed with a 2D RANS calculation. This discrepancy could be related to the absence of 3D effects in both numerical simulations. Although this conclusion has also been reached in other studies, the details of the physical mechanism that lead to inaccurate prediction of surface pressure and ultimately to thrust force for pitching and heaving flapping foils have not been clarified yet. In this study, the streamwise (secondary) vortical structures in the inverse Karman Vortex Street generated in the wake of a thrust producing flapping foil will be studied.

Fuel processing for PEM fuel cells: transport and kinetic issues of system design

NASA Astrophysics Data System (ADS)

Zalc, J. M.; Löffler, D. G.

In light of the distribution and storage issues associated with hydrogen, efficient on-board fuel processing will be a significant factor in the implementation of PEM fuel cells for automotive applications. Here, we apply basic chemical engineering principles to gain insight into the factors that limit performance in each component of a fuel processor. A system consisting of a plate reactor steam reformer, water-gas shift unit, and preferential oxidation reactor is used as a case study. It is found that for a steam reformer based on catalyst-coated foils, mass transfer from the bulk gas to the catalyst surface is the limiting process. The water-gas shift reactor is expected to be the largest component of the fuel processor and is limited by intrinsic catalyst activity, while a successful preferential oxidation unit depends on strict temperature control in order to minimize parasitic hydrogen oxidation. This stepwise approach of sequentially eliminating rate-limiting processes can be used to identify possible means of performance enhancement in a broad range of applications.

Measurement of radiation exposure of astronauts by radiochemical techniques

NASA Technical Reports Server (NTRS)

Brodzinski, R. L.

1972-01-01

Only two of the fecal specimens collected inflight during the Apollo 15 mission were returned for analysis. Difficulty in obtaining reasonably accurate radiation dose estimates based on the cosmogenic radionuclide content of the specimens was encountered due to the limited sampling. The concentrations of Na-22, K-40, Cr-51, Fe-59, and Cs-137 are reported. The concentrations of 24 major, minor, and trace elements in these two specimens were determined. Most concentrations are typical of those observed previously. Major exceptions are extremely low values for selenium and extraordinarily high values for rare earth elements. The net Po-210 activities in the Apollo 11 and 12 Solar Wind Composition foils and in the Apollo 8 and 12 spacecraft reflective coatings due to lunar exposure have been determined. Equilibrium concentrations of 0.082 + or - 0.012 disintegrations /sq cm sec of Rn-222 in the lunar atmosphere and 0.0238 + or - 0.0035 disintegrations /sq cm sec of Po-210 on the lunar surface have been calculated for Oceanus Procellarum.

Rapid epitaxy-free graphene synthesis on silicidated polycrystalline platinum

PubMed Central

Babenko, Vitaliy; Murdock, Adrian T.; Koós, Antal A.; Britton, Jude; Crossley, Alison; Holdway, Philip; Moffat, Jonathan; Huang, Jian; Alexander-Webber, Jack A.; Nicholas, Robin J.; Grobert, Nicole

2015-01-01

Large-area synthesis of high-quality graphene by chemical vapour deposition on metallic substrates requires polishing or substrate grain enlargement followed by a lengthy growth period. Here we demonstrate a novel substrate processing method for facile synthesis of mm-sized, single-crystal graphene by coating polycrystalline platinum foils with a silicon-containing film. The film reacts with platinum on heating, resulting in the formation of a liquid platinum silicide layer that screens the platinum lattice and fills topographic defects. This reduces the dependence on the surface properties of the catalytic substrate, improving the crystallinity, uniformity and size of graphene domains. At elevated temperatures growth rates of more than an order of magnitude higher (120 μm min−1) than typically reported are achieved, allowing savings in costs for consumable materials, energy and time. This generic technique paves the way for using a whole new range of eutectic substrates for the large-area synthesis of 2D materials. PMID:26175062

Feasibility demonstration for electroplating ultra-thin polyimide film. [fabricating film for space erectable structures

NASA Technical Reports Server (NTRS)

Schneier, R.; Braswell, T. V.; Vaughn, R. W.

1978-01-01

The effect of electrodeposition variables on film thickness was investigated using a dilute polyimide solution as a bath into which aluminum (as foil or as a vapor deposited coating) was immersed. The electrodeposited film was dried for 2 hours at 93 C (primarily to remove solvent) and cured for 18 hours at 186 C. Infrared studies indicate that imide formation (curing) occurs at 149 C under vacuum. From a conceptual viewpoint, satisfactory film metallized on one side can be obtained by this method. The cured ultra thin polyimide film exhibits properties equivalent to those of commercial film, and the surface appearance of the strippable polyimide film compares favorably with that of a sample of commercial film of thicker gauge. The feasibility of manufacturing approximately one million sq m of ultra thin film capable of being joined to fabricate an 800 m by 9 800 m square from starting material 0.5 to 1 m wide for space erectable structures was demonstrated.

Slow positron beam production by a 14 MeV C.W. electron accelerator

NASA Astrophysics Data System (ADS)

Begemann, M.; Gräff, G.; Herminghaus, H.; Kalinowsky, H.; Ley, R.

1982-10-01

A 14 MeV c.w. electron accelerator is used for pair production in a tungsten target of 0.7 radiation lengths thickness. A small fraction of the positrons is thermalized and diffuses out of the surface ofsurface of a well annealed tungsten foil coated with MgO which is positioned immediately behind the target. The slow positrons are extracted from the target region and magnetically guided over a distance of 10 m onto a channelplate multiplier at the end of an S-shaped solenoid. The positrons are identified by their annihilation radiation using two NaI-detectors. The intensity of the slow positrons is proportional to the accelerator electron beam current. The maximum intensity of 2.2 × 10 5 slow positrons per second reaching thedetector at an accelerator current of 15 μA was limited by the power deposited in the uncooled target. The energy of the positrons is concentrated in a small region at about 1 eV and clearly demonstrates the emission of thermal positrons.

Mapping the local reaction kinetics by PEEM: CO oxidation on individual (100)-type grains of Pt foil

PubMed Central

Vogel, D.; Spiel, C.; Suchorski, Y.; Urich, A.; Schlögl, R.; Rupprechter, G.

2011-01-01

The locally-resolved reaction kinetics of CO oxidation on individual (100)-type grains of a polycrystalline Pt foil was monitored in situ using photoemission electron microscopy (PEEM). Reaction-induced surface morphology changes were studied by optical differential interference contrast microscopy and atomic force microscopy (AFM). Regions of high catalytic activity, low activity and bistability in a (p,T)-parameter space were determined, allowing to establish a local kinetic phase diagram for CO oxidation on (100) facets of Pt foil. PEEM observations of the reaction front propagation on Pt(100) domains reveal a high degree of propagation anisotropy both for oxygen and CO fronts on the apparently isotropic Pt(100) surface. The anisotropy vanishes for oxygen fronts at temperatures above 465 K, but is maintained for CO fronts at all temperatures studied, i.e. in the range of 417 to 513 K. A change in the front propagation mechanism is proposed to explain the observed effects. PMID:22140277

Enhanced Carbon Dioxide Electroreduction to Carbon Monoxide over Defect-Rich Plasma-Activated Silver Catalysts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mistry, Hemma; Choi, Yong-Wook; Bagger, Alexander

Efficient, stable catalysts with high selectivity for a single product are essential if electroreduction of CO 2 is to become a viable route to the synthesis of industrial feedstocks and fuels. A plasma oxidation pre-treatment of silver foil enhances the number of low-coordinated catalytically active sites, which dramatically lowers the overpotential and increases the activity of CO 2 electroreduction to CO. At -0.6 V versus RHE more than 90 % Faradaic efficiency towards CO was achieved on a pre-oxidized silver foil. While transmission electron microscopy (TEM) and operando X-ray absorption spectroscopy showed that oxygen species can survive in the bulkmore » of the catalyst during the reaction, quasi in situ X-ray photoelectron spectroscopy showed that the surface is metallic under reaction conditions. Finally, DFT calculations reveal that the defect-rich surface of the plasma-oxidized silver foils in the presence of local electric fields drastically decrease the overpotential of CO 2 electroreduction.« less

Evolution of graphene islands growing on Cu foils

NASA Astrophysics Data System (ADS)

Wofford, Joseph; Nie, Shu; Bartelt, Norman; McCarty, Kevin; Dubon, Oscar

2011-03-01

Using low-energy electron microscopy we investigate, in real time, the growth of graphene monolayers on Cu foils. Graphene islands evolve from an initially compact form into an increasingly ramified, four-lobed shape, reflecting the symmetry of the (100)-textured Cu surface. Diffraction analysis reveals that each lobe is an individual graphene domain, differentiated by a rotation about the film normal, making the islands polycrystalline. An inspection of the morphological evolution of the graphene lobes shows the growth fronts posses an angularly dependent velocity, which is consistent with a growth mode dominated by edge kinetics. The fast growth direction of each lobe tends to align with the 001 in-plane directions of the Cu surface but not with a high symmetry direction of the graphene lattice. Finally, the implications of this unexpected growth mechanism on the formation of high-quality graphene films on Cu foils are evaluated. Supported by BES/USDOE under contracts #DE-AC04-94AL85000 and #DE-AC02-05CH11231.

Macroscopic inhomogeneous deformation behavior arising in single crystal Ni-Mn-Ga foils under tensile loading

NASA Astrophysics Data System (ADS)

Murasawa, Go; Yeduru, Srinivasa R.; Kohl, Manfred

2016-12-01

This study investigated macroscopic inhomogeneous deformation occurring in single-crystal Ni-Mn-Ga foils under uniaxial tensile loading. Two types of single-crystal Ni-Mn-Ga foil samples were examined as-received and after thermo-mechanical training. Local strain and the strain field were measured under tensile loading using laser speckle and digital image correlation. The as-received sample showed a strongly inhomogeneous strain field with intermittence under progressive deformation, but the trained sample result showed strain field homogeneity throughout the specimen surface. The as-received sample is a mainly polycrystalline-like state composed of the domain structure. The sample contains many domain boundaries and large domain structures in the body. Its structure would cause large local strain band nucleation with intermittence. However, the trained one is an ideal single-crystalline state with a transformation preferential orientation of variants after almost all domain boundary and large domain structures vanish during thermo-mechanical training. As a result, macroscopic homogeneous deformation occurs on the trained sample surface during deformation.

In-situ grown nanoporous Zn-Cu catalysts on brass foils for enhanced electrochemical reduction of carbon dioxide

NASA Astrophysics Data System (ADS)

Hu, Hanjun; Tang, Yang; Hu, Qing; Wan, Pingyu; Dai, Liming; Yang, Xiao Jin

2018-07-01

In-situ grown nanoporous Zn-Cu catalysts were prepared by simply annealing a commercial brass foil at 500 °C in air, followed by electrochemical reduction. During the annealing process, Zn preferentially melted and migrated out of the framework of the alloy to form a thin layer of ZnO on its surface. Subsequent electroreduction created nanoporous Zn-enriched surface. The Zn concentration increased from 36% to 50% by 10 min, to 81% by 3 h, and to 87% by 12 h annealing treatment while the average pore size decreased from 290 nm to 120 nm as the annealing time increased from 1 h to 12 h. Faradaic efficiency of CO2 reduction to CO and HCOOH was enhanced by nearly 4 and 6 times, respectively, as compared to untreated brass foils. The nanoporous Zn-Cu catalyst presented a stable ratio of CO/H2 and a steady working current density in a continuous electrolysis of 18 h in 0.5 M KHCO3 solution.

Enhanced Carbon Dioxide Electroreduction to Carbon Monoxide over Defect-Rich Plasma-Activated Silver Catalysts

DOE PAGES

Mistry, Hemma; Choi, Yong-Wook; Bagger, Alexander; ...

2017-07-14

Efficient, stable catalysts with high selectivity for a single product are essential if electroreduction of CO 2 is to become a viable route to the synthesis of industrial feedstocks and fuels. A plasma oxidation pre-treatment of silver foil enhances the number of low-coordinated catalytically active sites, which dramatically lowers the overpotential and increases the activity of CO 2 electroreduction to CO. At -0.6 V versus RHE more than 90 % Faradaic efficiency towards CO was achieved on a pre-oxidized silver foil. While transmission electron microscopy (TEM) and operando X-ray absorption spectroscopy showed that oxygen species can survive in the bulkmore » of the catalyst during the reaction, quasi in situ X-ray photoelectron spectroscopy showed that the surface is metallic under reaction conditions. Finally, DFT calculations reveal that the defect-rich surface of the plasma-oxidized silver foils in the presence of local electric fields drastically decrease the overpotential of CO 2 electroreduction.« less

Requirements, Technology and Configuration Evaluation for Crash Survivable Flight Data Recording (CSFDR) System

DTIC Science & Technology

1981-03-23

25% Rotational angle - 350 degrees Temperature range - -65°C to + 125°C Vibration - 15 g Shock - 50 g Rotational load life - 25,000,000...structed of multi-layered metal foils, vacuum deposited on thin films of Mylar, Kapton, or similar plastics) slowly outgas and contaminate their own...armor. Intumescent coating is a paint derivative, which swells 5 to 50 times its original thickness when exposed to high temperatures ( 350 ° to 500

Tunable TiO2 Nanotube Arrays for Flexible Bio-Sensitized Solar Cells

DTIC Science & Technology

2012-08-01

microid extender followed by a colloidal silica /wetted imperial cloth. The foil was then cut into 1- × 2-cm samples. Then, the substrates were...17. Lei, B.; Liao, J.; Wang, R. J.; Su, C.; Kuang, D. Ordered Crystalline Ti02 Nanotube Arrays on Transparent FTO Glass for Efficient Dye...combined with a transparent , Indium Tin Dioxide coated PET film are attractive candidates for efficient, flexible DSSC’s. Flexible solar cells offer

Grazing Incidence Nickel Replicated Optics for Hard X-ray Telescopes

NASA Technical Reports Server (NTRS)

Peturzzo, J. J., III; Elsner, R. F.; Joy, M. K.; ODell, S. L.; Weisskopf, M. C.

1997-01-01

The requirements for future hard x-ray (up to 50 keV) telescopes are lightweight, high angular resolution optics with large collecting areas. Grazing incidence replicated optics are an excellent candidate for this, type of mission, providing better angular resolution, comparable area/unit mass, and simpler fabrication than multilayer-coated foils. Most importantly, the technology to fabricate the required optics currently exists. A comparison of several hard x-ray telescope designs will be presented.

Advances in maskless and mask-based optical lithography on plastic flexible substrates

NASA Astrophysics Data System (ADS)

Barbu, Ionut; Ivan, Marius G.; Giesen, Peter; Van de Moosdijk, Michel; Meinders, Erwin R.

2009-12-01

Organic flexible electronics is an emerging technology with huge potential growth in the future which is likely to open up a complete new series of potential applications such as flexible OLED-based displays, urban commercial signage, and flexible electronic paper. The transistor is the fundamental building block of all these applications. A key challenge in patterning transistors on flexible plastic substrates stems from the in-plane nonlinear deformations as a consequence of foil expansion/shrinkage, moisture uptake, baking etc. during various processing steps. Optical maskless lithography is one of the potential candidates for compensating for these foil distortions by in-situ adjustment prior to exposure of the new layer image with respect to the already patterned layers. Maskless lithography also brings the added value of reducing the cost-of-ownership related to traditional mask-based tools by eliminating the need for expensive masks. For the purpose of this paper, single-layer maskless exposures at 355 nm were performed on gold-coated poly(ethylenenaphthalate) (PEN) flexible substrates temporarily attached to rigid carriers to ensure dimensional stability during processing. Two positive photoresists were employed for this study and the results on plastic foils were benchmarked against maskless as well as mask-based (ASML PAS 5500/100D stepper) exposures on silicon wafers.

Stepwise shockwave velocity determinator

NASA Technical Reports Server (NTRS)

Roth, Timothy E.; Beeson, Harold

1992-01-01

To provide an uncomplicated and inexpensive method for measuring the far-field velocity of a surface shockwave produced by an explosion, a stepwise shockwave velocity determinator (SSVD) was developed. The velocity determinator is constructed of readily available materials and works on the principle of breaking discrete sensors composed of aluminum foil contacts. The discrete sensors have an average breaking threshold of approximately 7 kPa. An incremental output step of 250 mV is created with each foil contact breakage and is logged by analog-to-digital instrumentation. Velocity data obtained from the SSVD is within approximately 11 percent of the calculated surface shockwave velocity of a muzzle blast from a 30.06 rifle.

Mystery of Foil Air Bearings for Oil-free Turbomachinery Unlocked: Load Capacity Rule-of-thumb Allows Simple Estimation of Performance

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher; Valco, Mark J.

2002-01-01

The Oil-Free Turbomachinery team at the NASA Glenn Research Center has unlocked one of the mysteries surrounding foil air bearing performance. Foil air bearings are self-acting hydrodynamic bearings that use ambient air, or any fluid, as their lubricant. In operation, the motion of the shaft's surface drags fluid into the bearing by viscous action, creating a pressurized lubricant film. This lubricating film separates the stationary foil bearing surface from the moving shaft and supports load. Foil bearings have been around for decades and are widely employed in the air cycle machines used for cabin pressurization and cooling aboard commercial jetliners. The Oil-Free Turbomachinery team is fostering the maturation of this technology for integration into advanced Oil-Free aircraft engines. Elimination of the engine oil system can significantly reduce weight and cost and could enable revolutionary new engine designs. Foil bearings, however, have complex elastic support structures (spring packs) that make the prediction of bearing performance, such as load capacity, difficult if not impossible. Researchers at Glenn recently found a link between foil bearing design and load capacity performance. The results have led to a simple rule-of-thumb that relates a bearing's size, speed, and design to its load capacity. Early simple designs (Generation I) had simple elastic (spring) support elements, and performance was limited. More advanced bearings (Generation III) with elastic supports, in which the stiffness is varied locally to optimize gas film pressures, exhibit load capacities that are more than double those of the best previous designs. This is shown graphically in the figure. These more advanced bearings have enabled industry to introduce commercial Oil-Free gas-turbine-based electrical generators and are allowing the aeropropulsion industry to incorporate the technology into aircraft engines. The rule-of-thumb enables engine and bearing designers to easily size and select bearing technology for a new application and determine the level of complexity required in the bearings. This new understanding enables industry to assess the feasibility of new engine designs and provides critical guidance toward the future development of Oil-Free turbomachinery propulsion systems.

Nanoporous, Metal Carbide, Surface Diffusion Membranes for High Temperature Hydrogen Separations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Way, J. Douglas; Wolden, Colin A.

2013-09-30

Colorado School of Mines (CSM) developed high temperature, hydrogen permeable membranes that contain no platinum group metals with the goal of separating hydrogen from gas mixtures representative of gasification of carbon feedstocks such as coal or biomass in order to meet DOE NETL 2015 hydrogen membrane performance targets. We employed a dual synthesis strategy centered on transition metal carbides. In the first approach, novel, high temperature, surface diffusion membranes based on nanoporous Mo 2C were fabricated on ceramic supports. These were produced in a two step process that consisted of molybdenum oxide deposition followed by thermal carburization. Our best Momore » 2C surface diffusion membrane achieved a pure hydrogen flux of 367 SCFH/ft 2 at a feed pressure of only 20 psig. The highest H 2/N 2 selectivity obtained with this approach was 4.9. A transport model using “dusty gas” theory was derived to describe the hydrogen transport in the Mo 2C coated, surface diffusion membranes. The second class of membranes developed were dense metal foils of BCC metals such as vanadium coated with thin (< 60 nm) Mo 2C catalyst layers. We have fabricated a Mo 2C/V composite membrane that in pure gas testing delivered a H 2 flux of 238 SCFH/ft 2 at 600 °C and 100 psig, with no detectable He permeance. This exceeds the 2010 DOE Target flux. This flux is 2.8 times that of pure Pd at the same membrane thickness and test conditions and over 79% of the 2015 flux target. In mixed gas testing we achieved a permeate purity of ≥99.99%, satisfying the permeate purity milestone, but the hydrogen permeance was low, ~0.2 SCFH/ft 2.psi. However, during testing of a Mo 2C coated Pd alloy membrane with DOE 1 feed gas mixture a hydrogen permeance of >2 SCFH/ft 2.psi was obtained which was stable during the entire test, meeting the permeance associated with the 2010 DOE target flux. Lastly, the Mo 2C/V composite membranes were shown to be stable for at least 168 hours = one week, including cycling at high temperature and alternating He/H 2 exposure.« less

SU-F-T-424: Mitigation of Increased Surface Dose When Treating Through A Carbon Fiber Couch Top

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, E; Misgina, F

Purpose: To study the effect of the Varian carbon fiber couch top on surface dose for patients being treated using single PA beams in the supine position and to identify simple methods for surface dose reduction. Methods: Measurements of surface dose were obtained in Solid Water phantoms using both a parallel plate ionization chamber (PTW Advanced Markus) and EBT2 Radiochromic films for both 6 and 10MV photons. All measurements were referenced to a depth considered a typical for PA Spine fields. Techniques used to reduce the surface dose included introducing an air standoff using Styrofoam sheets to suspend the phantommore » surface above the couch top and by adding a thin high Z scattering foil on the table surface. Surface doses were evaluated for typical field sizes, standoff heights, and various scattering materials. Comparisons were made to the surface dose obtainable when treating through a Varian Mylar covered tennis racket style couch top. Results: Dependence on typical spine field sizes was relatively minor. Dependence on air gap was much more significant. Surface doses decreased exponentially with increases in air standoff distance. Surface doses were reduced by approximately 50% for an air gap of 10cm and 40% for a 15cm air gap. Surface doses were reduced by an additional 15% by the addition of a 1mm Tin scattering foil. Conclusion: Using simple techniques, it is possible to reduce the surface dose when treating single PA fields through the Varian carbon fiber couch top. Surface doses can be reduced to levels observed when treating though transparent Mylar tops by adding about 15 cm of air gap. Further reductions are possible by adding thin scattering foils, such as Tin or Lead, on the couch surface. This is a low cost approach to reduce surface dose when using the Varian carbon fiber couch top.« less

Annealing of (DU-10Mo)-Zr Co-Rolled Foils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pacheco, Robin Montoya; Alexander, David John; Mccabe, Rodney James

2017-01-20

Producing uranium-10wt% molybdenum (DU-10Mo) foils to clad with Al first requires initial bonding of the DU-10Mo foil to zirconium (Zr) by hot rolling, followed by cold rolling to final thickness. Rolling often produces wavy (DU-10Mo)-Zr foils that should be flattened before further processing, as any distortions could affect the final alignment and bonding of the Al cladding to the Zr co-rolled surface layer; this bonding is achieved by a hot isostatic pressing (HIP) process. Distortions in the (DU-10Mo)-Zr foil may cause the fuel foil to press against the Al cladding and thus create thinner or thicker areas in the Almore » cladding layer during the HIP cycle. Post machining is difficult and risky at this stage in the process since there is a chance of hitting the DU-10Mo. Therefore, it is very important to establish a process to flatten and remove any waviness. This study was conducted to determine if a simple annealing treatment could flatten wavy foils. Using the same starting material (i.e. DU-10Mo coupons of the same thickness), five different levels of hot rolling and cold rolling, combined with five different annealing treatments, were performed to determine the effect of these processing variables on flatness, bonding of layers, annealing response, microstructure, and hardness. The same final thickness was reached in all cases. Micrographs, textures, and hardness measurements were obtained for the various processing combinations. Based on these results, it was concluded that annealing at 650°C or higher is an effective treatment to appreciably reduce foil waviness.« less

Analysis of LDEF experiment AO187-2 chemical and isotopic measurements of micrometeoroids by secondary ion mass spectrometry

NASA Technical Reports Server (NTRS)

Zinner, Ernst

1995-01-01

#Experiment AO187-2, that was flown on board the Long Duration Exposure Facility(LDEF), was designed to measure the chemical and isotopic compositions of interplanetary dust impinging on the spacecraft from outer space. Information on the nature and composition of orbital debris was also anticipated. The spacecraft maintained a constant orientation with respect to its velocity vector thereby defining leading and trailing edges that faced respectively into and away from the direction of motion. Arrays of individual capture cells each 80.8 sq cm in size and totaling 237 in number were exposed on both the leading and trailing edges of LDEF. Each cell consisted of a pure Ge target surface slightly separated from a thin (2.5 micrometers) metallized plastic 'entrance foil.' The basic concept was that incoming projectiles would penetrate the foil, strike the Ge target plate at high velocity producing a vapor-liquid cloud that would re-deposit material on the underside of the plastic foil. This material would then be analyzed using the sensitive surface analysis technique of Secondary Ion Mass Spectrometry (SIMS). In practice, most of the plastic entrance foils failed during the extended period of orbital exposure probably due to a combination of UV embrittlement, large densities of impact events and (for the leading edge) the effects of atomic oxygen erosion in orbit. However the foils failed gradually and most remained in place on the capture cells for a significant fraction of the duration of the flight . Because most of the impactors were small (less than 10 micrometers) they were heated and dispersed in traversing the entrance foils producing clouds of molten droplets and vapor that produced easily identifiable 'extended impacts' on the Ge target plates. Fortunately, it proved possible to make ion probe measurements of projectile compositions from material deposited on the Ge in the extended impact structures.

Visualization of terahertz surface waves propagation on metal foils

PubMed Central

Wang, Xinke; Wang, Sen; Sun, Wenfeng; Feng, Shengfei; Han, Peng; Yan, Haitao; Ye, Jiasheng; Zhang, Yan

2016-01-01

Exploitation of surface plasmonic devices (SPDs) in the terahertz (THz) band is always beneficial for broadening the application potential of THz technologies. To clarify features of SPDs, a practical characterization means is essential for accurately observing the complex field distribution of a THz surface wave (TSW). Here, a THz digital holographic imaging system is employed to coherently exhibit temporal variations and spectral properties of TSWs activated by a rectangular or semicircular slit structure on metal foils. Advantages of the imaging system are comprehensively elucidated, including the exclusive measurement of TSWs and fall-off of the time consumption. Numerical simulations of experimental procedures further verify the imaging measurement accuracy. It can be anticipated that this imaging system will provide a versatile tool for analyzing the performance and principle of SPDs. PMID:26729652

Barrier layers against oxygen transmission on the basis of electron beam cured methacrylated gelatin

NASA Astrophysics Data System (ADS)

Scherzer, Tom

1997-08-01

The development of barrier layers against oxygen transmission on the basis of radiation-curable methacrylated gelatin will be reported. The electron beam cured gelatin coatings show an extremely low oxygen permeability and a high resistance against boiling water. Moreover, the methacrylated gelatins possess good adhesion characteristics. Therefore, they are suited as barrier adhesives in laminates for food packaging applications. If substrate foils from biodegradable polymers are used, the development of completely biodegradable packaging materials seems to be possible.

Shock compression response of highly reactive Ni + Al multilayered thin foils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kelly, Sean C.; Thadhani, Naresh N., E-mail: naresh.thadhani@mse.gatech.edu

2016-03-07

The shock-compression response of Ni + Al multilayered thin foils is investigated using laser-accelerated thin-foil plate-impact experiments over the pressure range of 2 to 11 GPa. The foils contain alternating Ni and Al layers (parallel but not flat) of nominally 50 nm bilayer spacing. The goal is to determine the equation of state and shock-induced reactivity of these highly reactive fully dense thin-foil materials. The laser-accelerated thin-foil impact set-up involved combined use of photon-doppler-velocimetry to monitor the acceleration and impact velocity of an aluminum flyer, and VISAR interferometry was used to monitor the back free-surface velocity of the impacted Ni + Al multilayered target. The shock-compressionmore » response of the Ni + Al target foils was determined using experimentally measured parameters and impedance matching approach, with error bars identified considering systematic and experimental errors. Meso-scale CTH shock simulations were performed using real imported microstructures of the cross-sections of the multilayered Ni + Al foils to compute the Hugoniot response (assuming no reaction) for correlation with their experimentally determined equation of state. It was observed that at particle velocities below ∼150 m/s, the experimentally determined equation of state trend matches the CTH-predicted inert response and is consistent with the observed unreacted state of the recovered Ni + Al target foils from this velocity regime. At higher particle velocities, the experimentally determined equation of state deviates from the CTH-predicted inert response. A complete and self-sustained reaction is also seen in targets recovered from experiments performed at these higher particle velocities. The deviation in the measured equation of state, to higher shock speeds and expanded volumes, combined with the observation of complete reaction in the recovered multilayered foils, confirmed via microstructure characterization, is indicative of the occurrence of shock-induced chemical reaction occurring in the time-scale of the high-pressure state. TEM characterization of recovered shock-compressed (unreacted) Ni + Al multilayered foils exhibits distinct features of constituent mixing revealing jetted layers and inter-mixed regions. These features were primarily observed in the proximity of the undulations present in the alternating layers of the Ni + Al starting foils, suggesting the important role of such instabilities in promoting shock-induced intermetallic-forming reactions in the fully dense highly exothermic multilayered thin foils.« less

Finding Interstellar Particle Impacts on Stardust Aluminium Foils: The Safe Handling, Imaging, and Analysis of Samples Containing Femtogram Residues

NASA Technical Reports Server (NTRS)

Kearsley, A. T.; Westphal, A. J.; Stadermann, F. J.; Armes, S. P.; Ball, A. D.; Borg, J.; Bridges, J. C.; Brownlee, D. E.; Burchell, M. J.; Chater, R. J.;

Thrust Generation with Low-Power Continuous-Wave Laser and Aluminum Foil Interaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Horisawa, Hideyuki; Sumida, Sota; Funaki, Ikkoh

2010-05-06

The micro-newton thrust generation was observed through low-power continuous-wave laser and aluminum foil interaction without any remarkable ablation of the target surface. To evaluate the thrust characteristics, a torsion-balance thrust stand capable for the measurement of the thrust level down to micro-Newton ranges was developed. In the case of an aluminum foil target with 12.5 micrometer thickness, the maximum thrust level was 15 micro-newtons when the laser power was 20 W, or about 0.75 N/MW. It was also found that the laser intensity, or laser power per unit area, irradiated on the target was significantly important on the control ofmore » the thrust even under the low-intensity level.« less

Impact of the De-Alloying Kinetics and Alloy Microstructure on the Final Morphology of De-Alloyed Meso-Porous Metal Films

PubMed Central

Lin, Bao; Kong, Lingxue; Hodgson, Peter D.; Dumée, Ludovic F.

2014-01-01

Nano-textured porous metal materials present unique surface properties due to their enhanced surface energy with potential applications in sensing, molecular separation and catalysis. In this paper, commercial alloy foils, including brass (Cu85Zn15 and Cu70Zn30) and white gold (Au50Ag50) foils have been chemically de-alloyed to form nano-porous thin films. The impact of the initial alloy micro-structure and number of phases, as well as chemical de-alloying (DA) parameters, including etchant concentration, time and solution temperature on the final nano-porous thin film morphology and properties were investigated by electron microscopy (EM). Furthermore, the penetration depth of the pores across the alloys were evaluated through the preparation of cross sections by focus ion beam (FIB) milling. It is demonstrated that ordered pores ranging between 100 nm and 600 nm in diameter and 2–5 μm in depth can be successfully formed for the range of materials tested. The microstructure of the foils were obtained by electron back-scattered diffraction (EBSD) and linked to development of pits across the material thickness and surface during DA. The role of selective etching of both noble and sacrificial metal phases of the alloy were discussed in light of the competitive surface etching across the range of microstructures and materials tested. PMID:28344253

Experimental evidence of beam-foil plasma creation during ion-solid interaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, Prashant, E-mail: prashant@iuac.res.in; Nandi, Tapan

2016-08-15

Charge state evolution of the energetic projectile ions during the passage through thin carbon foils has been revisited using the X-ray spectroscopy technique. Contributions from the bulk and the solid surface in the charge changing processes have been segregated by measuring the charge state distribution of the projectile ions in the bulk of the target during the ion–solid interaction. Interestingly, the charge state distribution measured in the bulk exhibits Lorentzian profile in contrast to the well-known Gaussian structure observed using the electromagnetic methods and the theoretical predictions. The occurrence of such behavior is a direct consequence of the imbalance betweenmore » charge changing processes, which has been seen in various cases of the laboratory plasma. It suggests that the ion-solid collisions constitute high-density, localized plasma in the bulk of the solid target, called the beam-foil plasma. This condensed beam-foil plasma is similar to the high-density solar and stellar plasma which may have practical implementations in various fields, in particular, plasma physics and nuclear astrophysics. The present work suggests further modification in the theoretical charge state distribution calculations by incorporating the plasma coupling effects during the ion–solid interactions. Moreover, the multi-electron capture from the target exit surface has been confirmed through comparison between experimentally measured and theoretically predicted values of the mean charge state of the projectile ions.« less

A simple and inclusive method to determine the habit plane in transmission electron microscope based on accurate measurement of foil thickness

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qiu, Dong, E-mail: d.qiu@uq.edu.au; Zhang, Mingxing

2014-08-15

A simple and inclusive method is proposed for accurate determination of the habit plane between bicrystals in transmission electron microscope. Whilst this method can be regarded as a variant of surface trace analysis, the major innovation lies in the improved accuracy and efficiency of foil thickness measurement, which involves a simple tilt of the thin foil about a permanent tilting axis of the specimen holder, rather than cumbersome tilt about the surface trace of the habit plane. Experimental study has been done to validate this proposed method in determining the habit plane between lamellar α{sub 2} plates and γ matrixmore » in a Ti–Al–Nb alloy. Both high accuracy (± 1°) and high precision (± 1°) have been achieved by using the new method. The source of the experimental errors as well as the applicability of this method is discussed. Some tips to minimise the experimental errors are also suggested. - Highlights: • An improved algorithm is formulated to measure the foil thickness. • Habit plane can be determined with a single tilt holder based on the new algorithm. • Better accuracy and precision within ± 1° are achievable using the proposed method. • The data for multi-facet determination can be collected simultaneously.« less

Multi-layered foil capture of micrometeoroids and orbital debris in low Earth orbit

NASA Astrophysics Data System (ADS)

Kearsley, A.; Graham, G.

Much of our knowledge concerning the sub-millimetre orbital debris population that poses a threat to orbiting satellites has been gleaned from examination of surfaces retrieved and subsequently analysed as part of post-flight investigations. The preservation of the hypervelocity impact-derived remnants located on these surfaces is very variable, whether of space debris or micrometeoroid origin. Whilst glass and metallic materials show highly visible impact craters when examined using optical and electron microscopes, complex mixing between the target material and the impacting particle may make unambiguous interpretation of the impactor origin difficult or impossible. Our recent detailed examination of selected multi-layered insulation (MLI) foils from the ISAS Space Flyer Unit (SFU), and our preliminary study of NASA's Trek blanket, exposed on the Mir station, show that these constructions have the potential to preserve abundant residue material of a quality sufficient for detailed analysis. Although there are still limitations on the recognition of certain sources of orbital debris, the foils complement the metal and glass substrates. We suggest that a purpose-built multi-layered foil structure may prove to be extremely effective for rapid collection and unambiguous analysis of impact- derived residues. Such a collector could be used an environmental monitor for ISS, as it would have low mass, high durability, easy deployment, recovery and storage, making it an economically viable and attractive option.

Evidence for age-related performance degradation of (241)Am foil sources commonly used in UK schools.

PubMed

Whitcher, R; Page, R D; Cole, P R

2014-06-01

The characteristics of alpha radiation have for decades been demonstrated in UK schools using small sealed (241)Am sources. There is a small but steady number of schools who report a considerable reduction in the alpha count rate detected by an end-window GM detector compared with when the source was new. This cannot be explained by incorrect apparatus or set-up, foil surface contamination, or degradation of the GM detector. The University of Liverpool and CLEAPSS collaborated to research the cause of this performance degradation. The aim was to find what was causing the performance degradation and the ramifications for both the useful and safe service life of the sources. The research shows that these foil sources have greater energy straggling with a corresponding reduction in spectral peak energy. A likely cause for this increase in straggling is a significant diffusion of the metals over time. There was no evidence to suggest the foils have become unsafe, but precautionary checks should be made on old sources.

Demonstration of femtosecond laser ablation inductively coupled plasma mass spectrometry for uranium isotopic measurements in U-10Mo nuclear fuel foils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Havrilla, George Joseph; Gonzalez, Jhanis

2015-06-10

The use of femtosecond laser ablation inductively coupled plasma mass spectrometry was used to demonstrate the feasibility of measuring the isotopic ratio of uranium directly in U-10Mo fuel foils. The measurements were done on both the flat surface and cross sections of bare and Zr clad U-10Mo fuel foil samples. The results for the depleted uranium content measurements were less than 10% of the accepted U235/238 ratio of 0.0020. Sampling was demonstrated for line scans and elemental mapping over large areas. In addition to the U isotopic ratio measurement, the Zr thickness could be measured as well as trace elementalmore » composition if required. A number of interesting features were observed during the feasibility measurements which could provide the basis for further investigation using this methodology. The results demonstrate the feasibility of using fs-LA-ICP-MS for measuring the U isotopic ratio in U-10Mo fuel foils.« less

Neutron production in the interaction of 12 and 18 MeV electrons with a scattering foil inside a simple LINAC head.

PubMed

Soto-Bernal, Tzinnia Gabriela; Baltazar-Raigosa, Antonio; Medina-Castro, Diego; Vega-Carrillo, Hector Rene

2018-04-18

The characteristics of photons and neutrons produced during the interaction between a monoenergetic (12 and 18 MeV) electron beam and a tungsten scattering foil enclosed into a 10 cm-thick tungsten shell have been determined using Monte Carlo methods. This model was used aiming to represent a linac head working in electron-mode for cancer treatment. Photon and neutron spectra were determined around the scattering foil and to 50 and 100 cm below the electron source. Induced photons are mainly produced along the direction of the incoming electron beam. On the other hand, neutrons are produced in two sites, mainly in the inner surface of the linac head and in less extent in the scattering foil. The neutron spectra are evaporation neutrons which are emitted isotropically from the site where are produced leaking out from the linac head, reaching locations were the patient is allocated. Copyright © 2018 Elsevier Ltd. All rights reserved.

Quasi-monoenergetic proton beam from a proton-layer embedded metal foil irradiated by an intense laser pulse

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Kyung Nam; Lee, Kitae, E-mail: klee@kaeri.re.kr; Kumar, Manoj

A target structure, ion-layer embedded foil (ILEF) is proposed for producing a quasi-monoenergetic proton beam by utilizing a bulk electrostatic field, which is generated by irradiating the target with an ultra-intense laser pulse, inside the plasma. Compared with the case of a single metal foil in which the proton layer is initially present on the surface, in the ILEF target, the proton layer is initially located inside a metal foil. A two-dimensional particle-in-cell (PIC) simulation shows that the target generates a proton beam with a narrow energy spread. With a laser intensity of 2 × 10{sup 19 }W/cm{sup 2}, a 22-MeV proton beammore » with an energy spread of 8% at the full-width-half-maximum (FWHM) is obtained when the proton layer is located at 0.4 μm inside the rear surface of a 2.4 μm-thick copper foil. When the proton layer moves toward the front side, a proton beam with a flat-top energy distribution ranging from 15 MeV to 35 MeV is obtained. Further, with a higher laser intensity of 10{sup 21 }W/cm{sup 2}, a proton beam with the maximum energy of 345 MeV and FWHM energy spread of 7.2% is obtained. The analysis of the PIC simulation with an aid of a fluid analysis shows that the spectrum is affected by the initial position of the proton layer, its initial spread during the formation of the sheath field, and the space charge effect.« less

Selection of Sustainable Technology for VOC Abatement in an Industry: An Integrated AHP-QFD Approach

NASA Astrophysics Data System (ADS)

Gupta, Alok Kumar; Modi, Bharat A.

2018-04-01

Volatile organic compounds (VOCs) are universally present in global atmospheric pollutants. These VOCs are responsible for photo chemical reaction in atmosphere leading to serious harmful effects on human health and environment. VOCs are produced from both natural and man-made sources and may have good commercial value if it can be utilized as alternate fuel. As per data from US EPA, 15% of total VOC emissions are generated from surface coating industry but VOC concentration and exhaust air volume varies to a great extent and is dependent on processes used by industry. Various technologies are available for abatement of VOCs. Physical, Chemical and Biological technologies are available to remove VOCs by either recovery or destruction with many advantages and limitations. With growing environmental awareness and considering the resource limitations of medium and small scale industries, requirement of a tool for selecting appropriate techno economically viable solution for removal of VOCs from industrial process exhaust is envisaged. The aim of the present study is to provide management a tool to determine the overall effect of implementation of VOC abatement technology on business performance and VOC emissions. The primary purpose of this work is to outline a methodology to rate various VOC abatement technologies with respect to the constraint of meeting current and foreseeable future regulatory requirements, operational flexibility and Over All Economics Parameters considering conservation of energy. In this paper an integrated approach has been proposed to select most appropriate abatement technology strategically. Analytical hierarchy process and Quality function deployment have been integrated for Techno-commercial evaluation. A case study on selection of VOC abatement technology for a leading aluminium foil surface coating, lamination and printing facility using this methodology is presented in this study.

Uniformly coated highly porous graphene/MnO2 foams for flexible asymmetric supercapacitors

NASA Astrophysics Data System (ADS)

Drieschner, Simon; von Seckendorff, Maximilian; del Corro, Elena; Wohlketzetter, Jörg; Blaschke, Benno M.; Stutzmann, Martin; Garrido, Jose A.

2018-06-01

Supercapacitors are called to play a prominent role in the newly emerging markets of electric vehicles, flexible displays and sensors, and wearable electronics. In order to compete with current battery technology, supercapacitors have to be designed with highly conductive current collectors exhibiting high surface area per unit volume and uniformly coated with pseudocapacitive materials, which is crucial to boost the energy density while maintaining a high power density. Here, we present a versatile technique to prepare thickness-controlled thin-film micro graphene foams (μGFs) with pores in the lower micrometer range grown by chemical vapor deposition which can be used as highly conductive current collectors in flexible supercapacitors. To fabricate the μGF, we use porous metallic catalytic substrates consisting of nickel/copper alloy synthesized on nickel foil by electrodeposition in an electrolytic solution. Changing the duration of the electrodeposition allows the control of the thickness of the metal foam, and thus of the μGF, ranging from a few micrometers to the millimeter scale. The resulting μGF with a thickness and pores in the micrometer regime exhibits high structural quality which leads to a very low intrinsic resistance of the devices. Transferred onto flexible substrates, we demonstrate a uniform coating of the μGFs with manganese oxide, a pseudocapacitively active material. Considering the porous structure and the thickness of the μGFs, square wave potential pulses are used to ensure uniform coverage by the oxide material boosting the volumetric and areal capacitance to 14 F cm‑3 and 0.16 F cm‑2. The μGF with a thickness and pores in the micrometer regime in combination with a coating technique tuned to the porosity of the μGF is of great relevance for the development of supercapacitors based on state-of-the-art graphene foams.

Uniformly coated highly porous graphene/MnO2 foams for flexible asymmetric supercapacitors.

PubMed

Drieschner, Simon; Seckendorff, Maximilian von; Corro, Elena Del; Wohlketzetter, Jörg; Blaschke, Benno M; Stutzmann, Martin; Garrido, Jose A

2018-06-01

Supercapacitors are called to play a prominent role in the newly emerging markets of electric vehicles, flexible displays and sensors, and wearable electronics. In order to compete with current battery technology, supercapacitors have to be designed with highly conductive current collectors exhibiting high surface area per unit volume and uniformly coated with pseudocapacitive materials, which is crucial to boost the energy density while maintaining a high power density. Here, we present a versatile technique to prepare thickness-controlled thin-film micro graphene foams (μGFs) with pores in the lower micrometer range grown by chemical vapor deposition which can be used as highly conductive current collectors in flexible supercapacitors. To fabricate the μGF, we use porous metallic catalytic substrates consisting of nickel/copper alloy synthesized on nickel foil by electrodeposition in an electrolytic solution. Changing the duration of the electrodeposition allows the control of the thickness of the metal foam, and thus of the μGF, ranging from a few micrometers to the millimeter scale. The resulting μGF with a thickness and pores in the micrometer regime exhibits high structural quality which leads to a very low intrinsic resistance of the devices. Transferred onto flexible substrates, we demonstrate a uniform coating of the μGFs with manganese oxide, a pseudocapacitively active material. Considering the porous structure and the thickness of the μGFs, square wave potential pulses are used to ensure uniform coverage by the oxide material boosting the volumetric and areal capacitance to 14 F cm -3 and 0.16 F cm -2 . The μGF with a thickness and pores in the micrometer regime in combination with a coating technique tuned to the porosity of the μGF is of great relevance for the development of supercapacitors based on state-of-the-art graphene foams.

Observation of Li Diffusion in Cathode Sheets of Li-ion Battery by μ+SR

NASA Astrophysics Data System (ADS)

Umegaki, Izumi; Kawauchi, Shigehiro; Nozaki, Hiroshi; Sawada, Hiroshi; Nakano, Hiroyuki; Harada, Masashi; Cottrell, Stephen P.; Coomer, Fiona C.; Telling, Mark; Sugiyama, Jun

In order to know the change in Li diffusion during the operation of Li-ion batteries, we have initiated to measure Li diffusion not only in a powder sample but also in a cathode sheet with μ+SR. As the first step, we have measured μ+SR spectra on a cathode sheet, in which a mixture of a cathode material Li(Ni, Co)O2, a binder, and conducting additives is coated on an Al foil. The zero-field μ+SR spectrum exhibited a typical Kubo-Toyabe (KT) type relaxation at 100 K. By subtracting the contribution of the muons stopped in the Al foil, we found that Li+ ion starts to diffuse above 100 K in the Li(Ni, Co)O2. A self diffusion coefficient (DLi) at 300 K was estimated as 10-11 (cm2/s), which comparable with DLi (300 K) in the cathode materials previously reported. This leads to the future "in operando" measurements of DLi in Li-ion batteries.

Nanostructuring of thin Au films deposited on ordered Ti templates for applications in SERS

NASA Astrophysics Data System (ADS)

Grochowska, Katarzyna; Siuzdak, Katarzyna; Macewicz, Łukasz; Skiba, Franciszek; Szkoda, Mariusz; Karczewski, Jakub; Burczyk, Łukasz; Śliwiński, Gerard

2017-10-01

In this work the results on thermal nanostructuring of the Au films on Ti templates as well as morphology and optical properties of the obtained structures are reported. The bimetal nanostructures are fabricated in a multi-step process. First, the titania nanotubes are produced on the surface of Ti foil by anodization in an ethylene glycol-water solution containing fluoride ions. This is followed by chemical etching in oxalic acid and results in a highly ordered dimpled surface. Subsequently, thin gold films (5-20 nm) are deposited onto prepared Ti substrates by magnetron sputtering. The as-prepared layers are then dewetted by the UV nanosecond laser pulses or alternatively in the furnace (temperature < 500 °C). The SEM inspection reveals formation of honeycomb nanostructures (cavity diameter: ∼100 nm) covered with Au nanoparticles (NPs). It is observed that both the laser annealing and continuous thermal treatment in furnace can lead to the creation of NPs inside every Ti dimple and result in uniform coating of the whole area of structured templates. The size and localization of NPs obtained via both dewetting processes as well as their shape can be tuned by the annealing time and the laser processing parameters and also by initial thickness of Au layer and presence of the dimples themselves in the substrate. Results confirm that the prepared material can be used as substrate for SERS (Surface Enhanced Raman Spectroscopy).

Load Capacity Estimation of Foil Air Journal Bearings for Oil-Free Turbomachinery Applications

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher; Valco, Mark J.

2000-01-01

This paper introduces a simple "Rule of Thumb" (ROT) method to estimate the load capacity of foil air journal bearings, which are self-acting compliant-surface hydrodynamic bearings being considered for Oil-Free turbo-machinery applications such as gas turbine engines. The ROT is based on first principles and data available in the literature and it relates bearing load capacity to the bearing size and speed through an empirically based load capacity coefficient, D. It is shown that load capacity is a linear function of bearing surface velocity and bearing projected area. Furthermore, it was found that the load capacity coefficient, D, is related to the design features of the bearing compliant members and operating conditions (speed and ambient temperature). Early bearing designs with basic or "first generation" compliant support elements have relatively low load capacity. More advanced bearings, in which the compliance of the support structure is tailored, have load capacities up to five times those of simpler designs. The ROT enables simplified load capacity estimation for foil air journal bearings and can guide development of new Oil-Free turbomachinery systems.

Preliminary Analysis of an Oscillating Surge Wave Energy Converter with Controlled Geometry: Preprint

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tom, Nathan; Lawson, Michael; Yu, Yi-Hsiang

The aim of this paper is to present a novel wave energy converter device concept that is being developed at the National Renewable Energy Laboratory. The proposed concept combines an oscillating surge wave energy converter with active control surfaces. These active control surfaces allow for the device geometry to be altered, which leads to changes in the hydrodynamic properties. The device geometry will be controlled on a sea state time scale and combined with wave-to-wave power-take-off control to maximize power capture, increase capacity factor, and reduce design loads. The paper begins with a traditional linear frequency domain analysis of themore » device performance. Performance sensitivity to foil pitch angle, the number of activated foils, and foil cross section geometry is presented to illustrate the current design decisions; however, it is understood from previous studies that modeling of current oscillating wave energy converter designs requires the consideration of nonlinear hydrodynamics and viscous drag forces. In response, a nonlinear model is presented that highlights the shortcomings of the linear frequency domain analysis and increases the precision in predicted performance.« less

Hot slumping glass technology for the grazing incidence optics of future missions with particular reference to IXO

NASA Astrophysics Data System (ADS)

Ghigo, M.; Basso, S.; Bavdaz, M.; Conconi, P.; Citterio, O.; Civitani, M.; Friedrich, P.; Gallieni, D.; Guldimann, B.; Martelli, F.; Negri, R.; Pagano, G.; Pareschi, G.; Parodi, G.; Proserpio, L.; Salmaso, B.; Scaglione, F.; Spiga, D.; Tagliaferri, G.; Terzi, L.; Tintori, M.; Vongehr, M.; Wille, E.; Winter, A.; Zambra, A.

2010-07-01

The mirrors of the International X-ray Observatory (IXO) consist of a large number of high quality segments delivering a spatial resolution better than 5 arcsec. A study concerning the slumping of thin glass foils for the IXO mirrors is under development in Europe, funded by ESA and led by the Brera Observatory. We are investigating two approaches, the "Direct" and "Indirect" slumping technologies, being respectively based on the use of convex and concave moulds. In the first case during the thermal cycle the optical surface of the glass is in direct contact with the mould surface, while in the second case it is the rear side of the foil which touches the master. Both approaches present pros and cons and aim of this study is also to make an assessment of both processes and to perform a trade-off between the two. The thin plates are made of D263glass produced by Schott. Each plate is 0.4 mm thick, with a reflecting area of 200 mm x 200 mm; the mould are made of Fused Silica. After the thermal cycle the slumped MPs are characterized to define their optical quality and microroughness. The adopted integration process foresees the bonding of the slumped foils to a rigid backplane by means of reinforcing ribs. During the bonding process the plates are constrained to stay in close contact to the surface of the master (i.e. the same mould used for the hot slumping process) by the application of a vacuum pump suction. In this way spring-back deformations and low frequency errors still present on the foil profile after slumping can be corrected. In this paper we present the preliminary results concerning achieved during the first part of the project.

Gelatin Nano-coating for Inhibiting Surface Crystallization of Amorphous Drugs.

PubMed

Teerakapibal, Rattavut; Gui, Yue; Yu, Lian

2018-01-05

Inhibit the fast surface crystallization of amorphous drugs with gelatin nano-coatings. The free surface of amorphous films of indomethacin or nifedipine was coated by a gelatin solution (type A or B) and dried. The coating's effect on surface crystallization was evaluated. Coating thickness was estimated from mass change after coating. For indomethacin (weak acid, pK a  = 4.5), a gelatin coating of either type deposited at pH 5 and 10 inhibited its fast surface crystal growth. The coating thickness was 20 ± 10 nm. A gelatin coating deposited at pH 3, however, provided no protective effect. These results suggest that an effective gelatin coating does not require that the drug and the polymer have opposite charges. The ineffective pH 3 coating might reflect the poor wetting of indomethacin's neutral, hydrophobic surface by the coating solution. For nifedipine (weak base, pK a  = 2.6), a gelatin coating of either type deposited at pH 5 inhibited its fast surface crystal growth. Gelatin nano-coatings can be conveniently applied to amorphous drugs from solution to inhibit fast surface crystallization. Unlike strong polyelectrolyte coatings, a protective gelatin coating does not require strict pairing of opposite charges. This could make gelatin coating a versatile, pharmaceutically acceptable coating for stabilizing amorphous drugs.

Ultrasonically spray coated silver layers from designed precursor inks for flexible electronics.

PubMed

Marchal, W; Vandevenne, G; D'Haen, J; Calmont de Andrade Almeida, A; Durand Sola, M A; van den Ham, E J; Drijkoningen, J; Elen, K; Deferme, W; Van Bael, M K; Hardy, A

2017-05-26

Integration of electronic circuit components onto flexible materials such as plastic foils, paper and textiles is a key challenge for the development of future smart applications. Therefore, conductive metal features need to be deposited on temperature sensitive substrates in a fast and straightforward way. The feasibility of these emerging (nano-) electronic technologies depends on the availability of well-designed deposition techniques and on novel functional metal inks. As ultrasonic spray coating (USSC) is one of the most promising techniques to meet the above requirements, innovative metal organic decomposition (MOD) inks are designed to deposit silver features on plastic foils. Various amine ligands were screened and their influence on the ink stability and the characteristics of the resulting metal depositions were evaluated to determine the optimal formulation. Eventually, silver layers with excellent performance in terms of conductivity (15% bulk silver conductivity), stability, morphology and adhesion could be obtained, while operating in a very low temperature window of 70 °C-120 °C. Moreover, the optimal deposition conditions were determined via an in-depth analysis of the ultrasonically sprayed silver layers. Applying these tailored MOD inks, the USSC technique enabled smooth, semi-transparent silver layers with a tunable thickness on large areas without time-consuming additional sintering steps after deposition. Therefore, this novel combination of nanoparticle-free Ag-inks and the USSC process holds promise for high throughput deposition of highly conductive silver features on heat sensitive substrates and even 3D objects.

Ultrasonically spray coated silver layers from designed precursor inks for flexible electronics

NASA Astrophysics Data System (ADS)

Marchal, W.; Vandevenne, G.; D'Haen, J.; Almeida, A. Calmont de Andrade; Durand Sola, M. A., Jr.; van den Ham, E. J.; Drijkoningen, J.; Elen, K.; Deferme, W.; Van Bael, M. K.; Hardy, A.

2017-05-01

Integration of electronic circuit components onto flexible materials such as plastic foils, paper and textiles is a key challenge for the development of future smart applications. Therefore, conductive metal features need to be deposited on temperature sensitive substrates in a fast and straightforward way. The feasibility of these emerging (nano-) electronic technologies depends on the availability of well-designed deposition techniques and on novel functional metal inks. As ultrasonic spray coating (USSC) is one of the most promising techniques to meet the above requirements, innovative metal organic decomposition (MOD) inks are designed to deposit silver features on plastic foils. Various amine ligands were screened and their influence on the ink stability and the characteristics of the resulting metal depositions were evaluated to determine the optimal formulation. Eventually, silver layers with excellent performance in terms of conductivity (15% bulk silver conductivity), stability, morphology and adhesion could be obtained, while operating in a very low temperature window of 70 °C-120 °C. Moreover, the optimal deposition conditions were determined via an in-depth analysis of the ultrasonically sprayed silver layers. Applying these tailored MOD inks, the USSC technique enabled smooth, semi-transparent silver layers with a tunable thickness on large areas without time-consuming additional sintering steps after deposition. Therefore, this novel combination of nanoparticle-free Ag-inks and the USSC process holds promise for high throughput deposition of highly conductive silver features on heat sensitive substrates and even 3D objects.

Preparation and radar absorptive properties of BaFe12O19 -coated glass fiber

NASA Astrophysics Data System (ADS)

Jia, F.; Xu, M.; Bao, H. Q.; Cui, K.; Zhang, F.

2016-07-01

Traditional passive jamming materials such as chaff and foil showed some limitations in use because they can only reflect the electromagnetic wave. Therefore, to develop a kind of absorptive passive jamming material to make up for deficiencies of traditional passive jamming materials and improve the jamming efficiency is of great significance. In this paper, the BaFe12O19-coated glass fiber, used as a kind of radar absorptive chaff, was prepared by sol-gel dip-coating method. The effects of heat treatment temperature, heat treatment time and coating times on film quality, tensile strength and attenuation efficiency of the samples were discussed. The study shows that an increase of the heat treatment temperature and an extension of the heat treatment time is conducive to the growth of barium ferrite grain, while they would introduce the loss of chaff strength at the same time. In addition, multi-coating process can improve the film quality and attenuation efficiency of the sample. Data show that the 10 times coated samples have a best reflectivity of (15GHz, -6.65dB) and the bandwidth of reflectivity lower than -5dB is11.8 GHz. According to the test results, the prepared material has certain attenuation efficiency in the range of 2GHz-18GHz, having a high practical value.

Production and Performance of the InFOCmicronS 20-40 keV Graded Multilayer Mirror

NASA Technical Reports Server (NTRS)

Berendse, F.; Owens, S. M.; Serlemitsos, P. J.; Tueller, J.; Chan, K.-W.; Soong, Y.; Krimm, H.; Baumgartner, W. H.; Tamura, K.; Okajima, T.;

Single-jet gas cooling of in-beam foils or specimens: Prediction of the convective heat-transfer coefficient

NASA Astrophysics Data System (ADS)

Steyn, Gideon; Vermeulen, Christiaan

2018-05-01

An experiment was designed to study the effect of the jet direction on convective heat-transfer coefficients in single-jet gas cooling of a small heated surface, such as typically induced by an accelerated ion beam on a thin foil or specimen. The hot spot was provided using a small electrically heated plate. Heat-transfer calculations were performed using simple empirical methods based on dimensional analysis as well as by means of an advanced computational fluid dynamics (CFD) code. The results provide an explanation for the observed turbulent cooling of a double-foil, Havar beam window with fast-flowing helium, located on a target station for radionuclide production with a 66 MeV proton beam at a cyclotron facility.

Three-dimensional simulations of ion acceleration from a foil irradiated by a short-pulse laser.

PubMed

Pukhov, A

2001-04-16

Using 3D particle-in-cell simulations we study ion acceleration from a foil irradiated by a laser pulse at 10(19) W/cm(2) intensity. At the front side, the laser ponderomotive force pushes electrons inwards, thus creating the electric field by charge separation, which drags the ions. At the back side of the foil, the ions are accelerated by space charge of the hot electrons exiting into vacuum, as suggested by Hatchett et al. [Phys. Plasmas 7, 2076 (2000)]. The transport of hot electrons through the overdense plasma and their exit into vacuum are strongly affected by self-generated magnetic fields. The fast ions emerge from the rear surface in cones similar to those detected by Clark et al. [Phys. Rev. Lett. 84, 670 (2000)].

Investigation of the aluminium-aluminium oxide reversible transformation as observed by hot stage electron microscopy.

NASA Technical Reports Server (NTRS)

Grove, C. A.; Judd, G.; Ansell, G. S.

1972-01-01

Thin foils of high purity aluminium and an Al-Al2O3 SAP type of alloy were oxidised in a specially designed hot stage specimen chamber in an electron microscope. Below 450 C, amorphous aluminium oxide formed on the foil surface and was first detectable at foil edges, holes, and pits. Islands of aluminium then nucleated in this amorphous oxide. The aluminium islands displayed either a lateral growth with eventual coalescence with other islands, or a reoxidation process which caused the islands to disappear. The aluminium island formation was determined to be related to the presence of the electron beam. A mechanism based upon electron charging due to the electron beam was proposed to explain the nucleation, growth, coalescence, disappearance, and geometry of the aluminium islands.

Effects of atmosphere on the tribological properties of a chromium carbide based coating for use to 760 deg C

NASA Technical Reports Server (NTRS)

Dellacorte, Chris; Sliney, Harold E.

1986-01-01

The effect of atmosphere on the tribological properties of a plasma-sprayed chromium carbide based self-lubricating coating is reported. The coating contains bonded chromium carbide as the wear resistant base stock to which the lubricants silver and barium fluoride/calcium fluoride eutectic are added. It has been denoted as NASA PS200. Potential applications for the PS200 coating are cylinder wall/piston ring couples for Stirling engines and foil bearing journal lubrication. Friction and wear studies were performed in helium, hydrogen, and moist air at temperatures from 25 to 760 C. In general, the atmosphere had a significant effect on both the friction and the wear of the coating and counterface material. Specimens tested in hydrogen, a reducing environment, exhibited the best tribological properties. Friction and wear increased in helium and air but are still within acceptable limits for intended applications. A variety of X-ray analyses was performed on the test specimens in an effort to explain the results. The following conclusions are made: (1) As the test atmosphere becomes less reducing, the coating experiences a higher concentration level of chromic oxide at the sliding interface which increases both the friction and wear. (2) Beneficial silver transfer from the parent coating to the counter-face material is less effective in air than in helium or hydrogen. (3) There may be a direct relationship between chromic oxide level present at the sliding interface and the friction coefficient.

The effects of atmosphere on the tribological properties of a chromium carbide based coating for use to 760 C

NASA Technical Reports Server (NTRS)

Dellacorte, Christopher; Sliney, Harold E.

1988-01-01

The effect of atmosphere on the tribological properties of a plasma-sprayed chromium carbide based self-lubricating coating is reported. The coating contains bonded chromium carbide as the wear resistant base stock to which the lubricants silver and barium fluoride/calcium fluoride eutectic are added. It has been denoted as NASA PS200. Potential applications for the PS200 coating are cylinder wall/piston ring couples Stirling engines and foil bearing journal lubrication. Friction and wear studies were performed in helium, hydrogen, and moist air at temperatures from 25 to 760 C. In general, the atmosphere had a significant effect on both the friction and the wear of the coating and counterface material. Specimens tested in hydrogen, a reducing environment, exhibited the best tribological properties. Friction and wear increased in helium and air but are still within acceptable limits for intended applications. A variety of X-ray analyses was performed on the test specimens in an effort to explain the results. The following conclusions are made: (1) As the test atmosphere becomes less reducing, the coating experiences a higher concentration level of chromic oxide at the sliding interface which increases both the friction and wear. (2) Beneficial silver transfer from the parent coating to the counter-face material is less effective in air than in helium or hydrogen. (3) There may be a direct relationship between chromic oxide level present at the sliding interface and the friction coefficient.

High Temperature Degradation of Advanced Thermal and Environmental Barrier Coatings (TEBCs) by CaO-MgO-Al2O3-SiO2 (CMAS)

NASA Technical Reports Server (NTRS)

Costa, Gustavo; Zhu, Dongming

2017-01-01

There is increasing interest in the degradation studies of thermal and environmental barrier coatings (TEBCs) of gas turbines by molten CaO-MgO-Al2O3-SiO2 (CMAS). CMAS minerals are usually referred as silica-containing sand dust and volcano ash materials that are carried by the intake air into gas turbines, e.g. aircraft engines. The low-melting deposits react at high temperatures (1000C) with the coating materials. This causes degradation and accelerated coating failure of the static and rotating components of the turbine engines. We discuss some preliminary results of the reactions between CMAS and Rare-Earth (RE Y, Yb, Dy, Gd, Nd and Sm) oxide stabilized ZrO2 or HfO2 systems, and the stability of the resulting oxides and silicates. Plasma sprayed hollow tube samples (outer diameter 4.7 mm, wall thickness 0.76 mm and 26 mm height) were half filled with CMAS powder, wrapped and sealed with platinum foil, and heat- treated at 1310 C for 5h. Samples were characterized by differential scanning calorimetry, X-ray diffraction and cross section electron microscopy analysis.

Friction surfaced Stellite6 coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, K. Prasad; Damodaram, R.; Rafi, H. Khalid, E-mail: khalidrafi@gmail.com

2012-08-15

Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material formore » friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.« less

Does the liquid method of electret forming influence the adhesion of blood platelets?

PubMed

Lowkis, B; Szymanowicz, M

1995-01-01

This work presents the results of the effect of the electric charge on the adhesion of blood platelets. All experiments were carried out on polyethylene foil. The liquid method was used to form electrets. The evaluation of the electret effect influence on the adhesion of blood platelets was made on the basis of the observation of the electret surface after the contact with fresh citrate human blood group O Rh+ in an electron scanning microscope. Experimental results confirmed the essential influence of the electric charge on the process of adhesion of blood platelets. It was noticed that the preliminary aging of electrets decreases the density of the surface charge and improves the athrombogenic characteristics of polyethylene foil.

In-Roll Stress Analysis Considering Air-Entrainment at the Roll-Inlet with the Effect of Grooves on Nip Roll Surface

NASA Astrophysics Data System (ADS)

Sasaki, Masashi; Tanimoto, Koshi; Kohno, Kazukiyo; Takahashi, Sadamu; Kometani, Hideo; Hashimoto, Hiromu

High-speed winding of paper web sometimes leads the winding system into unstable states, interlayer slippage of wound roll, paper breakage and so on, due to the excessive air-entrainment at the roll-inlet of nip contact region. These phenomena are more frequently observed on coated paper or plastic film comparing with newspaper, because the former allows little permeation of air and their surface roughness is small. Therefore, it is of vital importance to clarify the in-roll stress of wound roll considering the effect of air-entrainment. Generally, it is known that the amount of air-entrainment is affected by grooving shape of nip roll surface. In this paper, we focused on the grooving shape and investigated the relationship with the air-entrainment into two rolls being pressed each other and the grooving shape in order to achieve stable winding at high speed. We conducted experiments using small sized test machine. Entrained air-film thickness was evaluated applying the solution of the elasto-hydrodynamic lubrication for foil bearing with the consideration of nip profile at the grooved area. Air film thickness was measured to ensure the applicability of the above theory. Consequently, we found that the air film thickness can be estimated considering the effect of grooves on the nip roll surface, and that the validity of the above estimations was ensured from experimental investigations. Furthermore, it became to be able to propose the optimal shape of grooves on nip roll surface to maintain the stable winding at high speed and at large-diameter in reel.

Insulator coating for high temperature alloys method for producing insulator coating for high temperature alloys

DOEpatents

Park, J.H.

1998-06-23

A method for fabricating an electrically insulating coating on a surface is disclosed comprising coating the surface with a metal, and reacting the metal coated surface with a nonmetal so as to create a film on the metal-coated surface. Alternatively, the invention provides for a method for producing a noncorrosive, electrically insulating coating on a surface saturated with a nonmetal comprising supplying a molten fluid, dissolving a metal in the molten fluid to create a mixture, and contacting the mixture with the saturated surface. Lastly, the invention provides an electrically insulative coating comprising an underlying structural substrate coated with an oxide or nitride compound. 2 figs.

X-ray imaging and 3D reconstruction of in-flight exploding foil initiator flyers

DOE PAGES

Willey, T. M.; Champley, K.; Hodgin, R.; ...

2016-06-17

Exploding foil initiators (EFIs), also known as slapper initiators or detonators, offer clear safety and timing advantages over other means of initiating detonation in high explosives. The work described here outlines a new capability for imaging and reconstructing three-dimensional images of operating EFIs. Flyer size and intended velocity were chosen based on parameters of the imaging system. The EFI metal plasma and plastic flyer traveling at 2.5 km/s were imaged with short ~80 ps pulses spaced 153.4 ns apart. A four-camera system acquired 4 images from successive x-ray pulses from each shot. The first frame was prior to bridge burst,more » the 2 nd images the flyer about 0.16 mm above the surface but edges of the foil and/or flyer are still attached to the substrate. The 3 rd frame captures the flyer in flight, while the 4 th shows a completely detached flyer in a position that is typically beyond where slappers strike initiating explosives. Multiple acquisitions at different incident angles and advanced computed tomography reconstruction algorithms were used to produce a 3-dimensional image of the flyer at 0.16 and 0.53 mm above the surface. Both the x-ray images and the 3D reconstruction show a strong anisotropy in the shape of the flyer and underlying foil parallel vs. perpendicular to the initiating current and electrical contacts. These results provide detailed flyer morphology during the operation of the EFI.« less

X-ray imaging and 3D reconstruction of in-flight exploding foil initiator flyers

NASA Astrophysics Data System (ADS)

Willey, T. M.; Champley, K.; Hodgin, R.; Lauderbach, L.; Bagge-Hansen, M.; May, C.; Sanchez, N.; Jensen, B. J.; Iverson, A.; van Buuren, T.

2016-06-01

Exploding foil initiators (EFIs), also known as slapper initiators or detonators, offer clear safety and timing advantages over other means of initiating detonation in high explosives. This work outlines a new capability for imaging and reconstructing three-dimensional images of operating EFIs. Flyer size and intended velocity were chosen based on parameters of the imaging system. The EFI metal plasma and plastic flyer traveling at 2.5 km/s were imaged with short ˜80 ps pulses spaced 153.4 ns apart. A four-camera system acquired 4 images from successive x-ray pulses from each shot. The first frame was prior to bridge burst, the 2nd images the flyer about 0.16 mm above the surface but edges of the foil and/or flyer are still attached to the substrate. The 3rd frame captures the flyer in flight, while the 4th shows a completely detached flyer in a position that is typically beyond where slappers strike initiating explosives. Multiple acquisitions at different incident angles and advanced computed tomography reconstruction algorithms were used to produce a 3-dimensional image of the flyer at 0.16 and 0.53 mm above the surface. Both the x-ray images and the 3D reconstruction show a strong anisotropy in the shape of the flyer and underlying foil parallel vs. perpendicular to the initiating current and electrical contacts. These results provide detailed flyer morphology during the operation of the EFI.

Efficient rolling texture predictions and texture-sensitive properties of α-uranium foils

DOE PAGES

Steiner, Matthew A.; Klein, Robert W.; Calhoun, Christopher A.; ...

2017-01-01

Here, finite element (FE) analysis was used to simulate the strain history of an α-uranium foil during cold-rolling, with the sheet modeled as an isotropic elastoplastic continuum. The resulting strain history was then used as input for a viscoplastic self-consistent (VPSC) polycrystal plasticity model to simulate crystallographic texture evolution. Mid-plane textures predicted via the combined FE→VPSC approach show alignment of the (010) poles along the rolling direction (RD), and the (001) poles along the normal direction (ND) with a symmetric splitting along RD. The surface texture is similar to that of the mid-plane, but with a shear-induced asymmetry that favorsmore » one of the RD split features of the (001) pole figure. Both the mid-plane and surface textures predicted by the FE→VPSC approach agree with published experimental results for cold-rolled α-uranium plates, as well as predictions made by a more computationally intensive full-field crystal plasticity based finite element model. α-uranium foils produced by cold-rolling must typically undergo a final recrystallization anneal to restore ductility prior to their final application, resulting in significant texture evolution from the cold-rolled plate deformation texture. Using the texture measured from a foil in the final recrystallized state, coefficients of the thermal expansion and elastic stiffness tensors were calculated using a thermo-elastic self-consistent model, and the anisotropic yield loci and flow curves along the RD, TD, and ND were predicted using the VPSC code.« less

Efficient rolling texture predictions and texture-sensitive properties of α-uranium foils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steiner, Matthew A.; Klein, Robert W.; Calhoun, Christopher A.

Here, finite element (FE) analysis was used to simulate the strain history of an α-uranium foil during cold-rolling, with the sheet modeled as an isotropic elastoplastic continuum. The resulting strain history was then used as input for a viscoplastic self-consistent (VPSC) polycrystal plasticity model to simulate crystallographic texture evolution. Mid-plane textures predicted via the combined FE→VPSC approach show alignment of the (010) poles along the rolling direction (RD), and the (001) poles along the normal direction (ND) with a symmetric splitting along RD. The surface texture is similar to that of the mid-plane, but with a shear-induced asymmetry that favorsmore » one of the RD split features of the (001) pole figure. Both the mid-plane and surface textures predicted by the FE→VPSC approach agree with published experimental results for cold-rolled α-uranium plates, as well as predictions made by a more computationally intensive full-field crystal plasticity based finite element model. α-uranium foils produced by cold-rolling must typically undergo a final recrystallization anneal to restore ductility prior to their final application, resulting in significant texture evolution from the cold-rolled plate deformation texture. Using the texture measured from a foil in the final recrystallized state, coefficients of the thermal expansion and elastic stiffness tensors were calculated using a thermo-elastic self-consistent model, and the anisotropic yield loci and flow curves along the RD, TD, and ND were predicted using the VPSC code.« less

X-ray imaging and 3D reconstruction of in-flight exploding foil initiator flyers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Willey, T. M., E-mail: willey1@llnl.gov; Champley, K., E-mail: champley1@llnl.gov; Hodgin, R.

Exploding foil initiators (EFIs), also known as slapper initiators or detonators, offer clear safety and timing advantages over other means of initiating detonation in high explosives. This work outlines a new capability for imaging and reconstructing three-dimensional images of operating EFIs. Flyer size and intended velocity were chosen based on parameters of the imaging system. The EFI metal plasma and plastic flyer traveling at 2.5 km/s were imaged with short ∼80 ps pulses spaced 153.4 ns apart. A four-camera system acquired 4 images from successive x-ray pulses from each shot. The first frame was prior to bridge burst, the 2nd images themore » flyer about 0.16 mm above the surface but edges of the foil and/or flyer are still attached to the substrate. The 3rd frame captures the flyer in flight, while the 4th shows a completely detached flyer in a position that is typically beyond where slappers strike initiating explosives. Multiple acquisitions at different incident angles and advanced computed tomography reconstruction algorithms were used to produce a 3-dimensional image of the flyer at 0.16 and 0.53 mm above the surface. Both the x-ray images and the 3D reconstruction show a strong anisotropy in the shape of the flyer and underlying foil parallel vs. perpendicular to the initiating current and electrical contacts. These results provide detailed flyer morphology during the operation of the EFI.« less

X-ray imaging and 3D reconstruction of in-flight exploding foil initiator flyers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Willey, T. M.; Champley, K.; Hodgin, R.

Exploding foil initiators (EFIs), also known as slapper initiators or detonators, offer clear safety and timing advantages over other means of initiating detonation in high explosives. The work described here outlines a new capability for imaging and reconstructing three-dimensional images of operating EFIs. Flyer size and intended velocity were chosen based on parameters of the imaging system. The EFI metal plasma and plastic flyer traveling at 2.5 km/s were imaged with short ~80 ps pulses spaced 153.4 ns apart. A four-camera system acquired 4 images from successive x-ray pulses from each shot. The first frame was prior to bridge burst,more » the 2 nd images the flyer about 0.16 mm above the surface but edges of the foil and/or flyer are still attached to the substrate. The 3 rd frame captures the flyer in flight, while the 4 th shows a completely detached flyer in a position that is typically beyond where slappers strike initiating explosives. Multiple acquisitions at different incident angles and advanced computed tomography reconstruction algorithms were used to produce a 3-dimensional image of the flyer at 0.16 and 0.53 mm above the surface. Both the x-ray images and the 3D reconstruction show a strong anisotropy in the shape of the flyer and underlying foil parallel vs. perpendicular to the initiating current and electrical contacts. These results provide detailed flyer morphology during the operation of the EFI.« less

Efficient rolling texture predictions and texture-sensitive thermomechanical properties of α-uranium foils

NASA Astrophysics Data System (ADS)

Steiner, Matthew A.; Klein, Robert W.; Calhoun, Christopher A.; Knezevic, Marko; Garlea, Elena; Agnew, Sean R.

2017-11-01

Finite element (FE) analysis was used to simulate the strain history of an α-uranium foil during cold straight-rolling, with the sheet modeled as an isotropic elastoplastic continuum. The resulting strain history was then used as input for a viscoplastic self-consistent (VPSC) polycrystal plasticity model to simulate crystallographic texture evolution. Mid-plane textures predicted via the combined FE→VPSC approach show alignment of the (010) poles along the rolling direction (RD), and the (001) poles along the normal direction (ND) with a symmetric splitting along RD. The surface texture is similar to that of the mid-plane, but with a shear-induced asymmetry that favors one of the RD split features of the (001) pole figure. Both the mid-plane and surface textures predicted by the FE→VPSC approach agree with published experimental results for cold straight-rolled α-uranium plates, as well as predictions made by a more computationally intensive full-field crystal plasticity based finite element model. α-uranium foils produced by cold-rolling must typically undergo a recrystallization anneal to restore ductility prior to their final application, resulting in significant texture evolution from the cold-rolled plate deformation texture. Using the texture measured from a foil in the final recrystallized state, coefficients of thermal expansion and the elastic stiffness tensors were calculated using a thermo-elastic self-consistent model, and the anisotropic yield loci and flow curves along the RD, TD, and ND were predicted using the VPSC code.

Hostile environments and high temperature measurements; Proceedings of the Conference, Kansas City, MO, Nov. 6-8, 1989

NASA Astrophysics Data System (ADS)

Topics presented include the identification of stagnant region in a fluidized bed combustor, high sensitivity objective grating speckle, an X-ray beam method for displacement and strain distributions using the moire method, and high-temperature deformation of a Ti-alloy composite under complex loading. Also addressed are a hybrid procedure for dynamic characterization of ceramics at elevated temperature, thermo-structural measurements in a SiC coated carbon-carbon hypersonic glide vehicle, and recent experience with elevated-temperature foil strain gages with application to thin-gage materials.

Flexible organic light emitting diodes fabricated on biocompatible silk fibroin substrate

NASA Astrophysics Data System (ADS)

Liu, Yuqiang; Xie, Yuemin; Liu, Yuan; Song, Tao; Zhang, Ke-Qin; Liao, Liangsheng; Sun, Baoquan

2015-10-01

Flexible and biodegradable electronics are currently under extensive investigation for biocompatible and environmentally-friendly applications. Synthetic plastic foils are widely used as substrates for flexible electronics. But typical plastic substrates such as polyethylene naphthalate (PEN) could not be degraded in a natural bio-environment. A great demand still exists for a next-generation biocompatible and biodegradable substrate for future application. For example, electronic devices can be potentially integrated into the human body. In this work, we demonstrate that the biocompatible and biodegradable natural silk fibroin (SF) films embedded with silver nanowires (AgNWs) mesh could be employed as conductive transparent substrates to fabricate flexible organic light emitting diodes (OLEDs). Compared with commercial PEN substrates coated with indium tin oxide, the AgNWs/SF composite substrates exhibit a similar sheet resistance of 12 Ω sq-1, a lower surface roughness, as well as a broader light transmission range. Flexible OLEDs based on AgNWs/SF substrates achieve a current efficiency of 19 cd A-1, demonstrating the potential of the flexible AgNWs/SF films as conductive and transparent substrates for next-generation biodegradable devices.

Near monochromatic 20 Me V proton acceleration using fs laser irradiating Au foils in target normal sheath acceleration regime

DOE Office of Scientific and Technical Information (OSTI.GOV)

Torrisi, L., E-mail: Lorenzo.Torrisi@unime.it; Ceccio, G.; Cannavò, A.

2016-04-15

A 200 mJ laser pulse energy, 39 fs-pulse duration, 10 μm focal spot, p-polarized radiation has been employed to irradiate thin Au foils to produce proton acceleration in the forward direction. Gold foils were employed to produce high density relativistic electrons emission in the forward direction to generate a high electric field driving the ion acceleration. Measurements were performed by changing the focal position in respect of the target surface. Proton acceleration was monitored using fast SiC detectors in time-of-flight configuration. A high proton energy, up to about 20 Me V, with a narrow energy distribution, was obtained in particular conditions dependingmore » on the laser parameters, the irradiation conditions, and a target optimization.« less

Heat and mass transfer scale-up issues during freeze-drying, I: atypical radiation and the edge vial effect.

PubMed

Rambhatla, Shailaja; Pikal, Michael J

2003-01-01

The aim of this study is to determine whether radiation heat transfer is responsible for the position dependence of heat transfer known as the edge vial effect. Freeze drying was performed on a laboratory-scale freeze dryer using pure water with vials that were fully stoppered but had precision cut metal tubes inserted in them to ensure uniformity in resistance to vapor flow. Sublimation rates were determined gravimetrically. Vials were sputter-coated with gold and placed at selected positions on the shelf. Average sublimation rates were determined for vials located at the front, side, and center of an array of vials. Sublimation rates were also determined with and without the use of aluminum foil as a radiation shield. The effect of the guardrail material and its contribution to the edge vial effect by conduction heat transfer was studied by replacing the stainless steel band with a low-thermal conductivity material (styrofoam). The emissivities (epsilon) of relevant surfaces were measured using an infrared thermometer. Sublimation rate experiments were also conducted with vials suspended off the shelf to study the role of convection heat transfer. It was found that sublimation rates were significantly higher for vials located in the front compared to vials in the center. Additional radiation shields in the form of aluminum foil on the inside door resulted in a decrease in sublimation rates for the front vials and to a lesser extent, the center vials. There was a significant decrease in sublimation rate for gold-coated vials (epsilon approximately 0.4) placed at the front of an array when compared to that of clear vials (epsilon approximately 0.9). In the case of experiments with vials suspended off the shelf, the heat transfer coefficient was found to be independent of chamber pressure, indicating that pure convection plays no significant role in heat transfer. Higher sublimation rates were observed when the steel band was used instead of Styrofoam while the highest sublimation rates were obtained in the absence of the guardrail, indicating that the metal band can act as a thermal shield but also transmits some heat from the shelf via conduction and radiation. Atypical radiation heat transfer is responsible for higher sublimation rates for vials located at the front and side of an array. However, the guardrail contributes a little to heat transfer by conduction.

Corrosion prevention of magnesium surfaces via surface conversion treatments using ionic liquids

DOEpatents

Qu, Jun; Luo, Huimin

2016-09-06

A method for conversion coating a magnesium-containing surface, the method comprising contacting the magnesium-containing surface with an ionic liquid compound under conditions that result in decomposition of the ionic liquid compound to produce a conversion coated magnesium-containing surface having a substantially improved corrosion resistance relative to the magnesium-containing surface before said conversion coating. Also described are the resulting conversion-coated magnesium-containing surface, as well as mechanical components and devices containing the conversion-coated magnesium-containing surface.

Carnage interrupted : an analysis of fifteen terrorist plots against public surface transportation [research brief].

DOT National Transportation Integrated Search

2012-04-01

Since 1997, terrorists have focused much attention on public surface transportation as a target for attacks. Many of the plots have failed or been foiled, but those that have succeeded have resulted in large numbers of casualties and caused widesprea...

Apparatus and method for treating a cathode material provided on a thin-film substrate

DOEpatents

Hanson, Eric J.; Kooyer, Richard L.

2001-01-01

An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

Apparatus and method for treating a cathode material provided on a thin-film substrate

DOEpatents

Hanson, Eric J.; Kooyer, Richard L.

2003-01-01

An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

Electrocurtain coating process for coating solar mirrors

DOEpatents

Kabagambe, Benjamin; Boyd, Donald W.; Buchanan, Michael J.; Kelly, Patrick; Kutilek, Luke A.; McCamy, James W.; McPheron, Douglas A.; Orosz, Gary R.; Limbacher, Raymond D.

2013-10-15

An electrically conductive protective coating or film is provided over the surface of a reflective coating of a solar mirror by flowing or directing a cation containing liquid and an anion containing liquid onto the conductive surface. The cation and the anion containing liquids are spaced from, and preferably out of contact with one another on the surface of the reflective coating as an electric current is moved through the anion containing liquid, the conductive surface between the liquids and the cation containing liquid to coat the conductive surface with the electrically conductive coating.

Chemical synthesis of hierarchical NiCo2S4 nanosheets like nanostructure on flexible foil for a high performance supercapacitor.

PubMed

Kim, D -Y; Ghodake, G S; Maile, N C; Kadam, A A; Sung Lee, Dae; Fulari, V J; Shinde, S K

2017-08-29

In this study, hierarchical interconnected nickel cobalt sulfide (NiCo 2 S 4 ) nanosheets were effectively deposited on a flexible stainless steel foil by the chemical bath deposition method (CBD) for high-performance supercapacitor applications. The resulting NiCo 2 S 4 sample was characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), and electrochemical measurements. XRD and X-ray photoelectron spectroscopy (XPS) results confirmed the formation of the ternary NiCo 2 S 4 sample with a pure cubic phase. FE-SEM and HR-TEM revealed that the entire foil surface was fully covered with the interconnected nanosheets like surface morphology. The NiCo 2 S 4 nanosheets demonstrated impressive electrochemical characteristics with a specific capacitance of 1155 F g -1 at 10 mV s -1 and superior cycling stability (95% capacity after 2000 cycles). These electrochemical characteristics could be attributed to the higher active area and higher conductivity of the sample. The results demonstrated that the interconnected NiCo 2 S 4 nanosheets are promising as electrodes for supercapacitor and energy storage applications.

Activation of Osteoblastic Function on Titanium Surface with Titanium-Doped Hydroxyapatite Nanoparticle Coating: An In Vitro Study.

PubMed

Nakazawa, Masahiro; Yamada, Masahiro; Wakamura, Masato; Egusa, Hiroshi; Sakurai, Kaoru

Titanium-doped hydroxyapatite (TiHA) nanoparticles contain titanium atoms in the hydroxyapatite lattice, which can physicochemically functionalize the titanium surface without modification of the surface topography. This study aimed to evaluate the physicochemical properties of machined or microroughened titanium surfaces coated with TiHA nanoparticles and the functions of osteoblasts cultured on them. Titanium disks with commercially available surface topography, such as machined or sandblasted, large-grit, and acid-etched (SLA) surfaces, were coated with TiHA. The disks with original or TiHA-coated surfaces were evaluated in topography, wettability, and chemical composition. Osteoblastic cells from rat femurs were cultured on the disks and evaluated in proliferation and differentiation. TiHA coating changed from hydrophobicity to hydrophilicity on both machined and SLA surfaces. Calcium and phosphate atoms were detected all over the surface with TiHA coating regardless of the surface topography. However, the considerable change in the inherent surface topographies was not observed on both types of surfaces after TiHA coating. Osteoblastic proliferative activity at day 4 was increased by TiHA coating on both types of surfaces. TiHA coating did not enhance expressions of bone matrix-related genes such as osteocalcin, osteopontin, bone sialoprotein, alkaline phosphatase, and collagen I. However, depositions of collagen, osteocalcin, and calcium in the culture at days 7 and 20 were increased on both types of surface topographies with TiHA coating. TiHA coating enhanced extracellular matrix formation on smooth and microroughened titanium surfaces by increasing osteoblastic proliferative activity without the deterioration of differentiation through hydrophilic and chemical functionalization.

Polymeric film application for phase change heat transfer

NASA Astrophysics Data System (ADS)

Bart, Hans-Jörg; Dreiser, Christian

2018-06-01

The paper gives a concise review on polymer film heat exchangers (PFHX) with a focus on polyether ether ketone (PEEK) foil as heat transfer element, mechanically supported by a grid structure. In order to promote PFHX applications, heat transfer performance and wetting behavior are studied in detail. Surface modifications to improve wetting are discussed and correlations are presented for critical Reynolds numbers to sustain a stable liquid film. Scaling phenomena related to surface properties and easily adaptable cleaning-in-place (CIP) procedures are further content. The contribution of the foil thickness and material selection on thermal performance is quantified and a correlation for enhanced aqueous film heat transfer for the grid supported PFHX is given. The basic research results and the design criteria enable early stage material selection and conceptual apparatus design.

Polymeric film application for phase change heat transfer

NASA Astrophysics Data System (ADS)

Bart, Hans-Jörg; Dreiser, Christian

2018-01-01

The paper gives a concise review on polymer film heat exchangers (PFHX) with a focus on polyether ether ketone (PEEK) foil as heat transfer element, mechanically supported by a grid structure. In order to promote PFHX applications, heat transfer performance and wetting behavior are studied in detail. Surface modifications to improve wetting are discussed and correlations are presented for critical Reynolds numbers to sustain a stable liquid film. Scaling phenomena related to surface properties and easily adaptable cleaning-in-place (CIP) procedures are further content. The contribution of the foil thickness and material selection on thermal performance is quantified and a correlation for enhanced aqueous film heat transfer for the grid supported PFHX is given. The basic research results and the design criteria enable early stage material selection and conceptual apparatus design.

Interface control and mechanical property improvements in silicon carbide/titanium composites

NASA Technical Reports Server (NTRS)

Brewer, W. D.; Unnam, J.

1982-01-01

Several composite systems made of titanium matrix reinforced with silicon carbide fiber were investigated to obtain a better understanding of composite-degradation mechanisms and to develop techniques to minimize loss of mechanical properties during fabrication and in service. Emphasis was on interface control by fiber or matrix coatings. X-ray diffraction studies on planar samples showed that the formation of titanium silicides was greatly inhibited by the presence of aluminum or Ti3A1 layers at the fiber-matrix interface, with the Ti3A1 being more effective in reducing the reactions. Fiber studies showed that coating the fiber with a 1-micron-thick layer of aluminum improved the as-fabricated strength of a stoichiometric SiC fiber and reduced the fiber degradation during exposure to composite-fabrication conditions. Applying an interfacial barrier by coating the matrix foils instead of the fibers was found to be an effective method for improving composite strength. Reducing the fabrication temperature also resulted in significant improvements in composite strengths. Good-quality, well-consolidated composites were fabricated at temperatures well below those currently used for SiC-Ti composite fabrication.

Engineering Multifunctional Living Paints: Thin, Convectively-Assembled Biocomposite Coatings of Live Cells and Colloidal Latex Particles Deposited by Continuous Convective-Sedimentation Assembly

NASA Astrophysics Data System (ADS)

Jenkins, Jessica Shawn

Advanced composite materials could be revolutionized by the development of methods to incorporate living cells into functional materials and devices. This could be accomplished by continuously and rapidly depositing thin ordered arrays of adhesive colloidal latex particles and live cells that maintain stability and preserve microbial reactivity. Convective assembly is one method of rapidly assembling colloidal particles into thin (<10 microm thick), ordered films with engineered compositions, thicknesses, and particle packing that offer several advantages over thicker randomly ordered composites, including enhanced cell stability and increased reactivity through minimized diffusion resistance to nutrients and reduced light scattering. This method can be used to precisely deposit live bacteria, cyanobacteria, yeast, and algae into biocomposite coatings, forming reactive biosensors, photoabsorbers, or advanced biocatalysts. This dissertation developed new continuous deposition and coating characterization methods for fabricating and characterizing <10 microm thick colloid coatings---monodispersed latex particle or cell suspensions, bimodal blends of latex particles or live cells and microspheres, and trimodal formulations of biomodal latex and live cells on substrates such as aluminum foil, glass, porous Kraft paper, polyester, and polypropylene. Continuous convective-sedimentation assembly (CSA) is introduced to enable fabrication of larger surface area and long coatings by constantly feeding coating suspension to the meniscus, thus expanding the utility of convective assembly to deposit monolayer or very thin films or multi-layer coatings composed of thin layers on a large scale. Results show thin, tunable coatings can be fabricated from diverse coating suspensions and critical coating parameters that control thickness and structure. Particle size ratio and charge influence deposition, convective mixing or demixing and relative particle locations. Substrate wettability and suspension composition influence coating microstructure by controlling suspension delivery and spreading across the substrate. Microbes behave like colloidal particles during CSA, allowing for deposition of very thin stable biocomposite coatings of latex-live cell blends. CSA of particle-cell blends result in open-packed structures (15-45% mean void space), instead of tightly packed coatings attainable with single component systems, confirming the existence of significant polymer particle-cell interactions and formation of particle aggregates that disrupt coating microstructure during deposition. Tunable process parameters, such as particle concentration, fluid sonication, and fluid density, influence coating homogeneity when the meniscus is continuously supplied. Fluid density modification and fluid sonication affect particle sedimentation and distribution in the coating growth front whereas the suspended particle concentration strongly affects coating thickness, but has almost no effect on void space. Changing the suspension delivery mode (topside versus underside CCSA) yields disparate meniscus volumes and uneven particle delivery to the drying front, which enables control of the coating microstructure by varying the total number of particles available for deposition. The judicious combination of all these parameters will enable deposition of uniform, thin, latex-cell monolayers over areas on the order of tens of square centimeters or larger. To demonstrate the utility of biocomposite coatings, this dissertation investigated photoreactive coatings (artificial leaves) from suspensions of latex particles and nitrogen-limited Rps. palustris CGA009 or sulfur-limited C. reinhardtii CC-124. These coatings demonstrated stable, sustained (>90 hours) photohydrogen production under anoxygenic conditions. Nutrient reduction slows cell division, minimizing coating outgrowth, and promotes photohydrogen generation, improving coating reactivity. Scanning electron microscopy of microstructure revealed how coating reactivity can be controlled by the size and distribution of the nanopores in the biocomposite layers. Variations in colloid microsphere size and suspension composition do not affect coating reactivity, but both parameters alter coating microstructure. Porous paper coated with thin coatings of colloidal particles and cells to enable coatings to be used in a gas-phase without dehydration may offer higher volumetric productivity for hydrogen production. Future work should focus on optimization of cell density, light intensity, media cycling, and acetate concentration.

Biological Response of Human Bone Marrow-Derived Mesenchymal Stem Cells to Commercial Tantalum Coatings with Microscale and Nanoscale Surface Topographies

NASA Astrophysics Data System (ADS)

Skoog, Shelby A.; Kumar, Girish; Goering, Peter L.; Williams, Brian; Stiglich, Jack; Narayan, Roger J.

2016-06-01

Tantalum is a promising orthopaedic implant coating material due to its robust mechanical properties, corrosion resistance, and excellent biocompatibility. Previous studies have demonstrated improved biocompatibility and tissue integration of surface-treated tantalum coatings compared to untreated tantalum. Surface modification of tantalum coatings with biologically inspired microscale and nanoscale features may be used to evoke optimal tissue responses. The goal of this study was to evaluate commercial tantalum coatings with nanoscale, sub-microscale, and microscale surface topographies for orthopaedic and dental applications using human bone marrow-derived mesenchymal stem cells (hBMSCs). Tantalum coatings with different microscale and nanoscale surface topographies were fabricated using a diffusion process or chemical vapor deposition. Biological evaluation of the tantalum coatings using hBMSCs showed that tantalum coatings promote cellular adhesion and growth. Furthermore, hBMSC adhesion to the tantalum coatings was dependent on surface feature characteristics, with enhanced cell adhesion on sub-micrometer- and micrometer-sized surface topographies compared to hybrid nano-/microstructures. Nanostructured and microstructured tantalum coatings should be further evaluated to optimize the surface coating features to promote osteogenesis and enhance osseointegration of tantalum-based orthopaedic implants.

Electrical contact arrangement for a coating process

DOEpatents

Kabagambe, Benjamin; McCamy, James W; Boyd, Donald W

2013-09-17

A protective coating is applied to the electrically conductive surface of a reflective coating of a solar mirror by biasing a conductive member having a layer of a malleable electrically conductive material, e.g. a paste, against a portion of the conductive surface while moving an electrodepositable coating composition over the conductive surface. The moving of the electrodepositable coating composition over the conductive surface includes moving the solar mirror through a flow curtain of the electrodepositable coating composition and submerging the solar mirror in a pool of the electrodepositable coating composition. The use of the layer of a malleable electrically conductive material between the conductive member and the conductive surface compensates for irregularities in the conductive surface being contacted during the coating process thereby reducing the current density at the electrical contact area.

A new ring-shaped graphite monitor ionization chamber

NASA Astrophysics Data System (ADS)

Yoshizumi, M. T.; Caldas, L. V. E.

2010-07-01

A ring-shaped monitor ionization chamber was developed at the Instituto de Pesquisas Energéticas e Nucleares. This ionization chamber presents an entrance window of aluminized polyester foil. The guard ring and collecting electrode are made of graphite coated Lucite plates. The main difference between this new ionization chamber and commercial monitor chambers is its ring-shaped design. The new monitor chamber has a central hole, allowing the passage of the direct radiation beam without attenuation; only the penumbra radiation is measured by the sensitive volume. This kind of ionization chamber design has already been tested, but using aluminium electrodes. By changing the electrode material from aluminium to a graphite coating, an improvement in the chamber response stability was expected. The pre-operational tests, as saturation curve, recombination loss and polarity effect showed satisfactory results. The repeatability and the long-term stability tests were also evaluated, showing good agreement with international recommendations.

A titania nanotube-array room-temperature sensor for selective detection of hydrogen at low concentrations.

PubMed

Varghese, Oomman K; Mor, Gopal K; Grimes, Craig A; Paulose, Maggie; Mukherjee, Niloy

2004-09-01

A tremendous variation in electrical resistance, from the semiconductor to metallic range, has been observed in titania nanotube arrays at room temperature, approximately 25 degrees C, in the presence of < or = 1000 ppm hydrogen gas. The nanotube arrays are fabricated by anodizing titanium foil in an aqueous electrolyte solution containing hydrofluoric acid and acetic acid. Subsequently, the arrays are coated with a 10 nm layer of palladium by evaporation. Electrical contacts are made by sputtering a 2 mm diameter platinum disk atop the Pd-coated nanotube array. These sensors exhibit a resistance variation of the order of 10(4) in the presence of 100 ppm hydrogen at 25 degrees C. The sensors demonstrate complete reversibility, repeatability, high selectivity, negligible drift and wide dynamic range. The nanoscale geometry of the nanotubes, in particular the points of tube-to-tube contact, is believed to be responsible for the outstanding hydrogen gas sensitivities.

Heat Transfer In High-Temperature Multilayer Insulation

NASA Technical Reports Server (NTRS)

Daryabeigi, Kamran; Miller, Stephen D.; Cunnington, George R.

2006-01-01

The combined radiation/conduction heat transfer in high-temperature multilayer insulations for typical reentry of reusable launch vehicles from low Earth orbit was investigated experimentally and numerically. The high-temperature multilayer insulation investigated consisted of gold-coated reflective foils separated by alumina fibrous insulation spacers. The steady-state heat transfer through four multilayer insulation configurations was investigated experimentally over the temperature range of 300-1300 K and environmental pressure range of 1.33 10(exp -5)-101.32 kPa. It was shown that including the reflective foils reduced the effective thermal conductivity compared to fibrous insulation sample at 1.5 times the density of the multilayer sample. A finite volume numerical model was developed to solve the governing combined radiation/conduction heat transfer equations. The radiation heat transfer in the fibrous insulation spacers was modeled using the modified two-flux approximation assuming anisotropic scattering and gray medium. The numerical model was validated by comparison with steady-state experimental data. The root mean square deviation between the predicted and measured effective thermal conductivity of the samples was 9.5%.

Metal-free supercapacitor with aqueous electrolyte and low-cost carbon materials

NASA Astrophysics Data System (ADS)

Blomquist, Nicklas; Wells, Thomas; Andres, Britta; Bäckström, Joakim; Forsberg, Sven; Olin, Håkan

2017-01-01

Electric double-layer capacitors (EDLCs) or supercapacitors (SCs) are fast energy storage devices with high pulse efficiency and superior cyclability, which makes them useful in various applications including electronics, vehicles and grids. Aqueous SCs are considered to be more environmentally friendly than those based on organic electrolytes. Because of the corrosive nature of the aqueous environment, however, expensive electrochemically stable materials are needed for the current collectors and electrodes in aqueous SCs. This results in high costs for a given energy-storage capacity. To address this, we developed a novel low-cost aqueous SC using graphite foil as the current collector and a mix of graphene, nanographite, simple water-purification carbons and nanocellulose as electrodes. The electrodes were coated directly onto the graphite foil by using casting frames and the SCs were assembled in a pouch cell design. With this approach, we achieved a material cost reduction of greater than 90% while maintaining approximately one-half of the specific capacitance of a commercial unit, thus demonstrating that the proposed SC can be an environmentally friendly, low-cost alternative to conventional SCs.

Converting sunlight into audible sound by means of the photoacoustic effect: The Heliophone.

PubMed

Roozen, N B; Glorieux, C; Liu, L; Rychtáriková, M; Van der Donck, T; Jacobs, A

2016-09-01

One hundred and thirty-five years after Alexander Graham Bell and his assistant Charles Sumner Tainter explored the photoacoustic effect, and about 40 years after Rosencwaig and Gersho modeled the effect in a photoacoustic cell configuration, the phenomenon is revisited in a "Heliophone" device that converts sunlight into sound. The light is focused on a carbon blackened copper coated Kapton foil in an acoustic cell by means of a compound parabolic collimator, and its intensity is modulated by a mechanical chopper. A horn is employed to make the sound audible without electronic amplification. The description of the photoacoustic effect that was introduced by Rosencwaig and Gersho is extended to a cell-horn configuration, in which the periodically heated air above the foil acts as an oscillating piston, driving acoustic waves in the horn. The pressure in the cavity-horn assembly is calculated by considering the air layer piston as an equivalent volume velocity source. The importance of the carbon black (soot) layer to enhance light absorption, but above all to enhance the photothermal excitation efficiency, is elucidated by means of an experimentally supported physical model.

Double-chimera proteins to enhance recruitment of endothelial cells and their progenitor cells.

PubMed

Behjati, M; Kazemi, M; Hashemi, M; Zarkesh-Esfahanai, S H; Bahrami, E; Hashemi-Beni, B; Ahmadi, R

2013-08-20

Enhanced attraction of selective vascular reparative cells is of great importance in order to increase vascular patency after endovascular treatments. We aimed to evaluate efficient attachment of endothelial cells and their progenitors on surfaces coated with mixture of specific antibodies, L-selectin and VE-cadherin, with prohibited platelet attachment. The most efficient conditions for coating of L-selectin-Fc chimera and VE-cadherin-Fc chimera proteins were first determined by protein coating on ELISA plates. The whole processes were repeated on titanium substrates, which are commonly used to coat stents. Endothelial progenitor cells (EPCs) and human umbilical vein endothelial cells (HUVECs) were isolated and characterized by flow cytometry. Cell attachment, growth, proliferation, viability and surface cytotoxicity were evaluated using nuclear staining and MTT assay. Platelet and cell attachment were evaluated using scanning electron microscopy. Optimal concentration of each protein for surface coating was 50 ng/ml. The efficacy of protein coating was both heat and pH independent. Calcium ions had significant impact on simultaneous dual-protein coating (P<0.05). Coating stability data revealed more than one year stability for these coated proteins at 4°C. L-selectin and VE-cadherin (ratio of 50:50) coated surface showed highest EPC and HUVEC attachment, viability and proliferation compared to single protein coated and non-coated titanium surfaces (P<0.05). This double coated surface did not show any cytotoxic effect. Surfaces coated with L-selectin and VE-cadherin are friendly surface for EPC and endothelial cell attachment with less platelet attachment. These desirable factors make the L-selectin and VE-cadherin coated surfaces perfect candidate endovascular device. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ma, Tianyuan; Xu, Gui-Liang; Li, Yan

The corrosion of aluminum current collectors and the oxidation of solvents at a relatively high potential have been widely investigated with an aim to stabilize the electrochemical performance of lithium-ion batteries using such components. The corrosion behavior of aluminum current collectors was revisited using a home-build high-precision electrochemical measurement system, and the impact of electrolyte components and the surface protection layer on aluminum foil was systematically studied. The electrochemical results showed that the corrosion of aluminum foil was triggered by the electrochemical oxidation of solvent molecules, like ethylene carbonate, at a relative high potential. The organic radical cations generated frommore » the electrochemical oxidation are energetically unstable, and readily undergo a deprotonation reaction that generates protons and promote the dissolution of Al3+ from the aluminum foil. This new reaction mechanism can also shed light on the dissolution of transitional metal at high potentials.« less

Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries

DOE PAGES

Ma, Tianyuan; Xu, Gui -Liang; Li, Yan; ...

2017-02-16

The corrosion of aluminum current collectors and the oxidation of solvents at a relatively high potential have been widely investigated with an aim to stabilize the electrochemical performance of lithium-ion batteries using such components. The corrosion behavior of aluminum current collectors was revisited using a home-build high-precision electrochemical measurement system, and the impact of electrolyte components and the surface protection layer on aluminum foil was systematically studied. The electrochemical results showed that the corrosion of aluminum foil was triggered by the electrochemical oxidation of solvent molecules, like ethylene carbonate, at a relative high potential. The organic radical cations generated frommore » the electrochemical oxidation are energetically unstable, and readily undergo a deprotonation reaction that generates protons and promote the dissolution of Al 3+ from the aluminum foil. Finally, this new reaction mechanism can also shed light on the dissolution of transitional metal at high potentials.« less

Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries.

PubMed

Ma, Tianyuan; Xu, Gui-Liang; Li, Yan; Wang, Li; He, Xiangming; Zheng, Jianming; Liu, Jun; Engelhard, Mark H; Zapol, Peter; Curtiss, Larry A; Jorne, Jacob; Amine, Khalil; Chen, Zonghai

2017-03-02

The corrosion of aluminum current collectors and the oxidation of solvents at a relatively high potential have been widely investigated with an aim to stabilize the electrochemical performance of lithium-ion batteries using such components. The corrosion behavior of aluminum current collectors was revisited using a home-build high-precision electrochemical measurement system, and the impact of electrolyte components and the surface protection layer on aluminum foil was systematically studied. The electrochemical results showed that the corrosion of aluminum foil was triggered by the electrochemical oxidation of solvent molecules, like ethylene carbonate, at a relative high potential. The organic radical cations generated from the electrochemical oxidation are energetically unstable and readily undergo a deprotonation reaction that generates protons and promotes the dissolution of Al 3+ from the aluminum foil. This new reaction mechanism can also shed light on the dissolution of transitional metal at high potentials.

Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ma, Tianyuan; Xu, Gui -Liang; Li, Yan

The corrosion of aluminum current collectors and the oxidation of solvents at a relatively high potential have been widely investigated with an aim to stabilize the electrochemical performance of lithium-ion batteries using such components. The corrosion behavior of aluminum current collectors was revisited using a home-build high-precision electrochemical measurement system, and the impact of electrolyte components and the surface protection layer on aluminum foil was systematically studied. The electrochemical results showed that the corrosion of aluminum foil was triggered by the electrochemical oxidation of solvent molecules, like ethylene carbonate, at a relative high potential. The organic radical cations generated frommore » the electrochemical oxidation are energetically unstable, and readily undergo a deprotonation reaction that generates protons and promote the dissolution of Al 3+ from the aluminum foil. Finally, this new reaction mechanism can also shed light on the dissolution of transitional metal at high potentials.« less

Method of coating metal surfaces to form protective metal coating thereon

DOEpatents

Krikorian, Oscar H.; Curtis, Paul G.

1992-01-01

A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof.

Method of coating metal surfaces to form protective metal coating thereon

DOEpatents

Krikorian, O.H.; Curtis, P.G.

1992-03-31

A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof. 1 figure.

Electrospinning Robot for Regenerative Coating of Implants

NASA Astrophysics Data System (ADS)

Gerstenhaber, Jonathan A.

Electrospinning of nanofibrous mats and scaffolds enables generation of scaffolding that is not only highly porous, but also has a structure that essentially mimics the natural basement membrane. As a result, the method has proliferated extensively, and is commonly used for diverse applications such as water filtration or tissue engineering, the latter of which may involve the use of natural or synthetic materials. Common laboratory scale electrospinning setups can be built inexpensively with merely a syringe pump, a high voltage supply, and an aluminum foil target. These systems, however, are limited to flat target surface geometries that span several centimeters. While a scaffold can be cut or folded to conform to a bone or other biological surface, spinning directly onto a surface with significant peaks and troughs results in poor fiber uniformity. Furthermore, if an alteration of fiber properties is preferred, the high voltage setup limits user access and customization of parameters during the spinning period. Finally, control of the electric field is compromised by the proximity of grounded electrical components. As its first aim, this project develops a robotic control system to enable custom coatings of arbitrary surfaces. By augmenting the traditional electrospinning system with a three-dimensional robotic control system, electric field focusing fibers, and additional aerodynamic forces terms 'electroblowing', the device can be produced across targets with strong topographic anisotropy. The second aim continues to enhance these attributes with biocompatible soy based scaffolds. Craniofacial implants are often complex in geometry, and conformal bandages are particularly hard to produce in these areas. Soy based scaffolds will be produced for 3D-printed replicas of these situations. Finally, the methods developed across this aim enables the development and use of a handheld electrospinning system that combines a coaxial high velocity air flow with the high voltage spinning element to reduce effects of operator error. The final goal of the thesis is to test whether fiber control successfully reduces effects of fiber anisotropy in vitro and to use the enhanced fiber control mechanisms to produce scaffolds with significant anisotropy, depositing aligned fibers at a target point to eventually enable generation of scaffolds with programmable variable spatial alignment similar to tendon. When completed, the systems described will enable custom production of coatings or scaffolds for functionality as scaffolding on medically relevant surfaces. Specifically, this means first, that scaffolds can be used with confidence to improve fixation even of non-cylindrical implants and enhance local tissue integration, and second, that implants can be customized with areas of 'guidance' fibers or local drug depots to either promote regeneration and population by surrounding tissue or mimic natural anisotropic cues necessary for mechanical or biological functionality.

Effect of surface topological structure and chemical modification of flame sprayed aluminum coatings on the colonization of Cylindrotheca closterium on their surfaces

NASA Astrophysics Data System (ADS)

Chen, Xiuyong; He, Xiaoyan; Suo, Xinkun; Huang, Jing; Gong, Yongfeng; Liu, Yi; Li, Hua

2016-12-01

Biofouling is one of the major problems for the coatings used for protecting marine infrastructures during their long-term services. Regulation in surface structure and local chemistry is usually the key for adjusting antifouling performances of the coatings. In this study, flame sprayed multi-layered aluminum coatings with micropatterned surfaces were constructed and the effects of their surface structure and chemistry on the settlement of typical marine diatoms were investigated. Micropatterned topographical morphology of the coatings was constructed by employing steel mesh as a shielding plate during the coating deposition. A silicone elastomer layer for sealing and interconnection was further brush-coated on the micropatterned coatings. Additional surface modification was made using zwitterionic molecules via DOPA linkage. The surface-modified coatings resist effectively colonization of Cylindrotheca closterium. This is explained by the quantitative examination of a simplified conditioning layer that deteriorated adsorption of bovine calf serum proteins on the zwitterionic molecule-treated samples is revealed. The colonization behaviors of the marine diatoms are markedly influenced by the micropatterned topographical morphology. Either the surface micropatterning or the surface modification by zwitterionic molecules enhances antimicrobial ability of the coatings. However, the combined micropatterned structure and zwitterionic modification do not show synergistic effect. The results give insight into anti-corrosion/fouling applications of the modified aluminum coatings in the marine environment.

The M-band transmission flux of the plastic foil with a coated layer of silicon or germanium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Liling; Zhang, Lu; Jiang, Shaoen, E-mail: jiangshn@vip.sina.com

2014-02-03

Silicon (Si) and Germanium (Ge) can be used as the dopant in the ablator material for the purpose of reducing preheating in indirect-drive inertial confinement fusion. Their performances in reducing preheating are quite different. A method to evaluate the difference of these two kinds of dopants has been presented in this letter. In the Shenguang-II high power laser facility, the M-band (1.6–4.4 keV) transmission flux of Si-coated plastic (CH) and Ge-coated plastic (CH) has been measured by using the M-band x-ray diode. In the experiment, we find that the Si-coated CH can absorb more M-band x-rays and thus reduce the preheatingmore » of the fuel in our experiment condition. By using the radiation hydrodynamic code MULTI-1D, we got the simulation result which was well suited for the experiment. The comparison of their opacities (T{sub e} = 60–100 eV and ρ = 0.1–0.5 g/cm{sup 3}) also shows that the opacity of Si is higher than that of Ge almost in the whole range of 1.6–4.4 keV.« less

Effect of the Cold-Sprayed Aluminum Coating-Substrate Interface Morphology on Bond Strength for Aircraft Repair Application

NASA Astrophysics Data System (ADS)

Blochet, Quentin; Delloro, Francesco; N'Guyen, Franck; Jeulin, Dominique; Borit, François; Jeandin, Michel

2017-04-01

This article is dealing with the effects of surface preparation of the substrate on aluminum cold-sprayed coating bond strength. Different sets of AA2024-T3 specimens have been coated with pure Al 1050 feedstock powder, using a conventional cold spray coating technique. The sets were grit-blasted (GB) before coating. The study focuses on substrate surface topography evolution before coating and coating-substrate interface morphology after coating. To study coating adhesion by LASAT® technique for each set, specimens with and without preceding GB treatment were tested in load-controlled conditions. Then, several techniques were used to evaluate the effects of substrate surface treatment on the final coating mechanical properties. Irregularities induced by the GB treatment modify significantly the interface morphology. Results showed that particle anchoring was improved dramatically by the presence of craters. The substrate surface was characterized by numerous anchors. Numerical simulation results exhibited the increasing deformation of particle onto the grit-blasted surface. In addition, results showed a strong relationship between the coating-substrate bond strength on the deposited material and surface preparation.

Chromatic Titanium Photoanode for Dye-Sensitized Solar Cells under Rear Illumination.

PubMed

Huang, Chih-Hsiang; Chen, Yu-Wen; Chen, Chih-Ming

2018-01-24

Titanium (Ti) has high potential in many practical applications such as biomedicine, architecture, aviation, and energy. In this study, we demonstrate an innovative application of dye-sensitized solar cells (DSSCs) based on Ti photoanodes that can be integrated into the roof engineering of large-scale architectures. A chromatic Ti foil produced by anodizing oxidation (coloring) technology is an attractive roof material for large-scale architecture, showing a colorful appearance due to the formation of a reflective TiO 2 thin layer on both surfaces of Ti. The DSSC is fabricated on the backside of the chromatic Ti foil using the Ti foil as the working electrode, and this roof-DSSC hybrid configuration can be designed as an energy harvesting device for indoor artificial lighting. Our results show that the facet-textured TiO 2 layer on the chromatic Ti foil not only improves the optical reflectance for better light utilization but also effectively suppresses the charge recombination for better electron collection. The power conversion efficiency of the roof-DSSC hybrid system is improved by 30-40% with a main contribution from an improvement of short-circuit current density under standard 1 sun and dim-light (600-1000 lx) illumination.

The BiPo-3 detector for the measurement of ultra low natural radioactivities of thin materials

NASA Astrophysics Data System (ADS)

Barabash, A. S.; Basharina-Freshville, A.; Birdsall, E.; Blondel, S.; Blot, S.; Bongrand, M.; Boursette, D.; Brudanin, V.; Busto, J.; Caffrey, A. J.; Calvez, S.; Cascella, M.; Cebrián, S.; Cerna, C.; Cesar, J. P.; Chauveau, E.; Chopra, A.; Dafní, T.; De Capua, S.; Duchesneau, D.; Durand, D.; Egorov, V.; Eurin, G.; Evans, J. J.; Fajt, L.; Filosofov, D.; Flack, R.; Garrido, X.; Gómez, H.; Guillon, B.; Guzowski, P.; Holý, K.; Hodák, R.; Huber, A.; Hugon, C.; Iguaz, F. J.; Irastorza, I. G.; Jeremie, A.; Jullian, S.; Kauer, M.; Klimenko, A.; Kochetov, O.; Konovalov, S. I.; Kovalenko, V.; Lang, K.; Lemière, Y.; Le Noblet, T.; Liptak, Z.; Liu, X. R.; Loaiza, P.; Lutter, G.; Luzón, G.; Macko, M.; Mamedov, F.; Marquet, C.; Mauger, F.; Morgan, B.; Mott, J.; Nemchenok, I.; Nomachi, M.; Nova, F.; Ohsumi, H.; Oliviéro, G.; Ortiz de Solórzano, A.; Pahlka, R. B.; Pater, J.; Perrot, F.; Piquemal, F.; Povinec, P.; Přidal, P.; Ramachers, Y. A.; Remoto, A.; Richards, B.; Riddle, C. L.; Rukhadze, E.; Saakyan, R.; Salazar, R.; Sarazin, X.; Shitov, Yu.; Simard, L.; Šimkovic, F.; Smetana, A.; Smolek, K.; Smolnikov, A.; Söldner-Rembold, S.; Soulé, B.; Štekl, I.; Thomas, J.; Timkin, V.; Torre, S.; Tretyak, Vl. I.; Tretyak, V. I.; Umatov, V. I.; Vilela, C.; Vorobel, V.; Waters, D.; Žukauskas, A.

2017-06-01

The BiPo-3 detector, running at the Canfranc Underground Laboratory (Laboratorio Subterr&aposaneo de Canfranc, LSC, Spain) since 2013, is a low-radioactivity detector dedicated to measuring ultra low natural radionuclide contaminations of 208Tl (232Th chain) and 214Bi (238U chain) in thin materials. The total sensitive surface area of the detector is 3.6 m2. The detector has been developed to measure the radiopurity of the selenium double β-decay source foils of the SuperNEMO experiment. In this paper the design and performance of the detector, and results of the background measurements in 208Tl and 214Bi, are presented, and the validation of the BiPo-3 measurement with a calibrated aluminium foil is discussed. Results of the 208Tl and 214Bi activity measurements of the first enriched 82Se foils of the double β-decay SuperNEMO experiment are reported. The sensitivity of the BiPo-3 detector for the measurement of the SuperNEMO 82Se foils is Script A(208Tl) <2 μBq/kg (90% C.L.) and Script A(214Bi) <140 μBq/kg (90% C.L.) after 6 months of measurement.

Development of damage suppression system using embedded SMA foil sensor and actuator

NASA Astrophysics Data System (ADS)

Ogisu, Toshimichi; Nomura, Masato; Ando, Norio; Takaki, Junji; Song, Dong Y.; Takeda, Nobuo

2000-06-01

The recent studies suggest possible applications of shape memory alloy (SMA) for a smart health monitoring and suppression of damage growth. The authors have been conducting research and development studies on applications of embedded SMA foil sensors and actuators in CFRP laminates. The goal of this research is suppression of damage growth in CFRP laminates. At first, the authors proposed a concept of damage suppression in CFRP laminates. Then, the development studies are conducted in three phases. The first phase is the improvement of interlaminar shear strength between SMA and CFRP laminates. Some surface treatments were investigated for the improvement of bonding property by peel resistance test and single lap shear strength test. The second phase is the investigation of fabrication technique for producing a CFRP panel with embedded SMA foils. Fixture jigs were devised to introduce tensile loads during the fabrication process. The third phase is the strength demonstration of CFRP laminates with embedded SMA foils. Some strength test were conducted to obtain the design data for aircraft structures. It is confirmed that the shrinking force of pre-strained SMA influences to the strength and the crack density of CFRP panel.

Antibacterial isoeugenol coating on stainless steel and polyethylene surfaces prevents biofilm growth.

PubMed

Nielsen, C K; Subbiahdoss, G; Zeng, G; Salmi, Z; Kjems, J; Mygind, T; Snabe, T; Meyer, R L

2018-01-01

Pathogenic bacteria can spread between individuals or between food items via the surfaces they share. Limiting the survival of pathogens on surfaces, therefore, presents an opportunity to limit at least one route of how pathogens spread. In this study, we propose that a simple coating with the essential oil isoeugenol can be used to circumvent the problem of bacterial transfer via surfaces. Two commonly used materials, stainless steel and polyethylene, were coated by physical adsorption, and the coatings were characterized by Raman spectroscopy, atomic force microscopy and water contact angle measurements. We quantified and visualized the colonization of coated and uncoated surfaces by three bacteria: Staphylococcus aureus, Listeria monocytogenes and Pseudomonas fluorescens. No viable cells were detected on surfaces coated with isoeugenol. The isoeugenol coating prepared with simple adsorption proved effective in preventing biofilm formation on stainless steel and polyethylene surfaces. The result was caused by the antibacterial effect of isoeugenol, as the coating did not diminish the adhesive properties of the surface. Our study demonstrates that a simple isoeugenol coating can prevent biofilm formation of S. aureus, L. monocytogenes and P. fluorescens on two commonly used surfaces. © 2017 The Society for Applied Microbiology.

Effect of surface roughness of hydroxyapatite-coated titanium on the bone-implant interface shear strength.

PubMed

Hayashi, K; Inadome, T; Tsumura, H; Nakashima, Y; Sugioka, Y

1994-11-01

We have investigated the bone-implant interface shear strength of hydroxyapatite (HA)-coated Ti-6Al-4V (HA-coating A) (roughness average, Ra = 3.4 +/- 0.5 microns) and HA-coated Ti-6Al-4V with a rougher surface (HA-coating B) (Ra = 8.4 +/- 1.8 microns). There was no significant difference between HA-coating A and HA-coating B implants with respect to the bone-implant interface shear strength as determined in push-out tests using the transcortical model in adult dogs. The bone-implant interface shear strength of bead-coated porous Ti-6Al-4V was significantly greater than that of both HA-coating A and HA-coating B implants. The failure site, as determined by scanning electron microscopy, was the coating-substrate interface, not the coating-bone interface. This indicates a need to protect the HA coating from the direct shear forces. HA coating enhances early bone growth into the porous surface of the implant. Long-term fixation should depend on bone anchoring to this porous surface. Hydroxyapatite coatings must be developed which do not obstruct the pores of the surface of the implant.

Characterization of in situ synthesized TiB 2 reinforcements in iron-based composite coating

NASA Astrophysics Data System (ADS)

Zhang, Panpan; Wang, Xibao; Guo, Lijie; Cai, Lijuan; Sun, Hongling

2011-12-01

TiB2 reinforced iron-based composite coatings can be fabricated on the mild steel substrate with a powder mixture of Ti and B4C by plasma transferred arc (PTA) powder surfacing process. Characterizations of the TiB2 reinforcements in the coated surface were investigated in this paper. The experimental work enables the following findings to be obtained: (i) acicular shaped and blocky formed TiB2 phases could be synthesized in situ using PTA powder surfacing process in the iron-based composite coating. (ii) Gradient distributions of TiB2 reinforcements appeared in the composite coating from both the vertical and horizontal direction of the coating's cross-section. Significant changes of the size, shape and volume fraction for TiB2 particles appeared in different regions of the surface coating, due to the effects of the dilution rate and mass density. (iii) Values of coating dilution could have profound impacts on the characterization of TiB2 reinforcements in the coated surfaces. With the increase of coating dilution, TiB2 grain tends to be acicular shaped at the edge of the surface coating, while it remains to be granular formed in the center of the composite coating.

Method for smoothing the surface of a protective coating

DOEpatents

Sangeeta, D.; Johnson, Curtis Alan; Nelson, Warren Arthur

2001-01-01

A method for smoothing the surface of a ceramic-based protective coating which exhibits roughness is disclosed. The method includes the steps of applying a ceramic-based slurry or gel coating to the protective coating surface; heating the slurry/gel coating to remove volatile material; and then further heating the slurry/gel coating to cure the coating and bond it to the underlying protective coating. The slurry/gel coating is often based on yttria-stabilized zirconia, and precursors of an oxide matrix. Related articles of manufacture are also described.

Degradation of nonmodified and rhodium modified aluminide coating deposited on CMSX 4 superalloy.

PubMed

Zagula-Yavorska, Maryana; Wierzbińska, Małgorzata; Gancarczyk, Kamil; Sieniawski, Jan

2016-07-01

The Ni-base superalloy CMSX 4 used in the turbine blades of aircraft engines was coated with rhodium layer (0.5-μm thick). Next coated CMSX 4 superalloy was aluminized by the CVD method. The rhodium modified aluminide coating and nonmodified aluminide coating were oxidized at 1100°C at the air atmosphere. The rhodium modified aluminide coating showed about twice better oxidation resistance than the nonmodified one. The spallation equal 62% of the total area was observed on the surface of the nonmodified coating whereas only 36% spallation area was observed on the surface of the rhodium modified aluminide coating after the oxidation test. The oxide layer formed on the surface of the nonmodified coating was composed of nonprotective (Ni,Cr)Al2 O4 and (Ni,Cr)O phases. Aluminium in the coating reacts with oxygen, forming a protective α-Al2 O3 oxide on the surface of the rhodium modified aluminide coating. When the oxide cracks and spalls due to oxidation, additional aluminium from the coating diffuses to the surface to form the oxide. The presence of protective Al2 O3 oxide on the surface of the rhodium modified aluminide coating slows coating degradation. Therefore, rhodium modified aluminide coating has better oxidation resistance than the nonmodified one. © 2016 The Authors Journal of Microscopy © 2016 Royal Microscopical Society.

Comparison of two surface temperature measurement using thermocouples and infrared camera

NASA Astrophysics Data System (ADS)

Michalski, Dariusz; Strąk, Kinga; Piasecka, Magdalena

This paper compares two methods applied to measure surface temperatures at an experimental setup designed to analyse flow boiling heat transfer. The temperature measurements were performed in two parallel rectangular minichannels, both 1.7 mm deep, 16 mm wide and 180 mm long. The heating element for the fluid flowing in each minichannel was a thin foil made of Haynes-230. The two measurement methods employed to determine the surface temperature of the foil were: the contact method, which involved mounting thermocouples at several points in one minichannel, and the contactless method to study the other minichannel, where the results were provided with an infrared camera. Calculations were necessary to compare the temperature results. Two sets of measurement data obtained for different values of the heat flux were analysed using the basic statistical methods, the method error and the method accuracy. The experimental error and the method accuracy were taken into account. The comparative analysis showed that although the values and distributions of the surface temperatures obtained with the two methods were similar but both methods had certain limitations.

40 CFR 63.5743 - What standards must I meet for aluminum recreational boat surface coating operations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... aluminum recreational boat surface coating operations? 63.5743 Section 63.5743 Protection of Environment... Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat Surface Coating Operations § 63.5743 What standards must I meet for aluminum recreational boat surface coating operations? (a) For...

Spectrum of sodiumlike selenium - Se XXIV

NASA Technical Reports Server (NTRS)

Brown, C. M.; Seely, J. F.; Feldman, U.; Richardson, M. C.; Behring, W. E.; Cohen, L.

1986-01-01

High-resolution spectra of Se XXIV have been obtained with a 3-m grazing-incidence spectrograph. Thin plastic foils coated with selenium were irradiated with four or eight beams of the OMEGA laser in a line-focus configuration. Spectrograms were obtained by viewing the plasma axially. Prominent in the spectra were the 3s-3p and 3p-3d transitions in the 150-240-A region and the transitions nl-(n + 1)l-prime with n = 3, 4 in the 24-80-A region. The energy levels and ionization limit derived from the measured wavelengths are also presented.

Oxidation-assisted graphene heteroepitaxy on copper foil.

PubMed

Reckinger, Nicolas; Tang, Xiaohui; Joucken, Frédéric; Lajaunie, Luc; Arenal, Raul; Dubois, Emmanuel; Hackens, Benoît; Henrard, Luc; Colomer, Jean-François

2016-11-10

We propose an innovative, easy-to-implement approach to synthesize aligned large-area single-crystalline graphene flakes by chemical vapor deposition on copper foil. This method doubly takes advantage of residual oxygen present in the gas phase. First, by slightly oxidizing the copper surface, we induce grain boundary pinning in copper and, in consequence, the freezing of the thermal recrystallization process. Subsequent reduction of copper under hydrogen suddenly unlocks the delayed reconstruction, favoring the growth of centimeter-sized copper (111) grains through the mechanism of abnormal grain growth. Second, the oxidation of the copper surface also drastically reduces the nucleation density of graphene. This oxidation/reduction sequence leads to the synthesis of aligned millimeter-sized monolayer graphene domains in epitaxial registry with copper (111). The as-grown graphene flakes are demonstrated to be both single-crystalline and of high quality.

Laser surface modification of Yttria Stabilized Zirconia (YSZ) thermal barrier coating on AISI H13 tool steel substrate

NASA Astrophysics Data System (ADS)

Reza, M. S.; Aqida, S. N.; Ismail, I.

2018-03-01

This paper presents laser surface modification of plasma sprayed yttria stabilized zirconia (YSZ) coating to seal porosity defect. Laser surface modification on plasma sprayed YSZ was conducted using 300W JK300HPS Nd: YAG laser at different operating parameters. Parameters varied were laser power and pulse frequency with constant residence time. The coating thickness was measured using IM7000 inverted optical microscope and surface roughness was analysed using two-dimensional Mitutoyo Surface Roughness Tester. Surface roughness of laser surface modification of YSZ H-13 tool steel decreased significantly with increasing laser power and decreasing pulse frequency. The re-melted YSZ coating showed higher hardness properties compared to as-sprayed coating surface. These findings were significant to enhance thermal barrier coating surface integrity for dies in semi-solid processing.

Foil Electron Multiplier

DOEpatents

Funsten, Herbert O.; Baldonado, Juan R.; Dors, Eric E.; Harper, Ronnie W.; Skoug, Ruth M.

2006-03-28

An apparatus for electron multiplication by transmission that is designed with at least one foil having a front side for receiving incident particles and a back side for transmitting secondary electrons that are produced from the incident particles transiting through the foil. The foil thickness enables the incident particles to travel through the foil and continue on to an anode or to a next foil in series with the first foil. The foil, or foils, and anode are contained within a supporting structure that is attached within an evacuated enclosure. An electrical power supply is connected to the foil, or foils, and the anode to provide an electrical field gradient effective to accelerate negatively charged incident particles and the generated secondary electrons through the foil, or foils, to the anode for collection.

Tribological performance of quaternary CrSiCN coatings under dry and lubricated conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lorenzo-Martin, C.; Ajayi, O.; Erdemir, A.

This paper presents an experimental study of friction and wear performance of quaternary CrSiCN coatings deposited on a hardened H-13 steel substrate by a plasma enhanced magnetron sputtering (PEMS) technique. Friction and wear tests were conducted with a reciprocating line contact between a hardened 4370 steel roller and coated and uncoated flat specimens under dry and lubricated conditions. The effects of coating thickness (1, 3.5 and 7.5 μm) on the mechanical properties, friction and wear performance were also assessed. In dry sliding, the friction of coated surfaces was about the same as for uncoated surfaces, except for the 1-μm coating,more » which had higher friction. Friction for coated surfaces under lubricated contact was in general higher than for uncoated surfaces. There was no measurable wear on any of the coated surfaces, under either dry or lubricated conditions. However, wear was higher on the steel roller counterface sliding against the coated surfaces, with the amount of wear proportional to the mating coating thickness. The effectiveness of formulated lubricant additives was also modified by the coating, resulting in major effects on friction and wear behavior. Finally, this reduction in lubricant additive efficacy is due to the fact that the additives were designed and optimized for ferrous surfaces.« less

Tribological performance of quaternary CrSiCN coatings under dry and lubricated conditions

DOE PAGES

Lorenzo-Martin, C.; Ajayi, O.; Erdemir, A.; ...

2017-06-15

This paper presents an experimental study of friction and wear performance of quaternary CrSiCN coatings deposited on a hardened H-13 steel substrate by a plasma enhanced magnetron sputtering (PEMS) technique. Friction and wear tests were conducted with a reciprocating line contact between a hardened 4370 steel roller and coated and uncoated flat specimens under dry and lubricated conditions. The effects of coating thickness (1, 3.5 and 7.5 μm) on the mechanical properties, friction and wear performance were also assessed. In dry sliding, the friction of coated surfaces was about the same as for uncoated surfaces, except for the 1-μm coating,more » which had higher friction. Friction for coated surfaces under lubricated contact was in general higher than for uncoated surfaces. There was no measurable wear on any of the coated surfaces, under either dry or lubricated conditions. However, wear was higher on the steel roller counterface sliding against the coated surfaces, with the amount of wear proportional to the mating coating thickness. The effectiveness of formulated lubricant additives was also modified by the coating, resulting in major effects on friction and wear behavior. Finally, this reduction in lubricant additive efficacy is due to the fact that the additives were designed and optimized for ferrous surfaces.« less

Comparison of self-cleaning properties of three titania coatings on float glass

NASA Astrophysics Data System (ADS)

Piispanen, Minna; Hupa, Leena

2011-11-01

This work compares the self-cleaning properties of experimental TiO2 and TiO2-Ag coatings on float glass with a commercial self-cleaning glass. In the experimental surfaces, TiO2 coating was applied to float glass via the sol-gel route, while TiO2-Ag coating was applied by the liquid flame spray method, which deposits TiO2-Ag composite nanoparticles on the surface. The effect of the coatings on the surface wettability and the activation time for achieving hydrophilicity was studied through water contact angle as a function of exposure time to UV light. The surface morphology was investigated by using scanning electron microscopy (SEM) and confocal optical microscopy. The photocatalytic activity of the coatings was examined with methylene blue and stearic acid degradation tests. Finally, the soil attachment to the surfaces was tested with a sebum-based model soil. The sol-gel TiO2 coating became superhydrophilic within a few hours, while the activation time needed for the commercial titania coated glass was several days. The surface with the TiO2-Ag nanoparticles did not show any marked changes in the water contact angle. The commercial titania coated and the sol-gel TiO2 surfaces showed self-cleaning properties and clearly lower attachment of soil than the uncoated and TiO2-Ag coated surfaces. The difference in the interaction of the surfaces with the organic contaminants was assumed to depend mainly on differences in the thickness of the coatings.

Cathodic Polarization Coats Titanium Based Implant Materials with Enamel Matrix Derivate (EMD)

PubMed Central

Frank, Matthias J.; Walter, Martin S.; Rubert, Marina; Thiede, Bernd; Monjo, Marta; Reseland, Janne E.; Haugen, Håvard J.; Lyngstadaas, Ståle Petter

2014-01-01

The idea of a bioactive surface coating that enhances bone healing and bone growth is a strong focus of on-going research for bone implant materials. Enamel matrix derivate (EMD) is well documented to support bone regeneration and activates growth of mesenchymal tissues. Thus, it is a prime candidate for coating of existing implant surfaces. The aim of this study was to show that cathodic polarization can be used for coating commercially available implant surfaces with an immobilized but functional and bio-available surface layer of EMD. After coating, XPS revealed EMD-related bindings on the surface while SIMS showed incorporation of EMD into the surface. The hydride layer of the original surface could be activated for coating in an integrated one-step process that did not require any pre-treatment of the surface. SEM images showed nano-spheres and nano-rods on coated surfaces that were EMD-related. Moreover, the surface roughness remained unchanged after coating, as it was shown by optical profilometry. The mass peaks observed in the matrix-assisted laser desorption/ionization time-of-flight mass spectroscopy (MALDI-TOF MS) analysis confirmed the integrity of EMD after coating. Assessment of the bioavailability suggested that the modified surfaces were active for osteoblast like MC3M3-E1 cells in showing enhanced Coll-1 gene expression and ALP activity. PMID:28788564

Scratch and wear behaviour of plasma sprayed nano ceramics bilayer Al2O3-13 wt%TiO2/hydroxyapatite coated on medical grade titanium substrates in SBF environment

NASA Astrophysics Data System (ADS)

Palanivelu, R.; Ruban Kumar, A.

2014-10-01

Among the various coating techniques, plasma spray coating is an efficient technique to protect the metal surface from the various surface problems like wear and corrosion. The aim of this present work is to design and produce a bilayer coating on the non- toxic commercially pure titanium (denoted as CP-Ti) implant substrate in order to improve the biocompatibility and surface properties. To achieve that, Al2O3-13 wt%TiO2 (AT13) and hydroxyapatite (HAP) were coated on CP-Ti implant substrate using plasma spray coating technique. Further, the coated substrates were subjected to various characterization techniques. The crystallite size of coated HAP and its morphological studies were carried out using X-ray diffractometer (XRD) and scanning electron microscopy (SEM) respectively. The wear test on the bilayer (AT13/HAP) coated CP-Ti implant surface was conducted using ball-on-disc tester under SBF environment at 37 °C, in order to determine the wear rate and the coefficient of friction. The adhesion strength of the bilayer coated surface was evaluated by micro scratch tester under the ramp load conditions with load range of 14-20 N. The above said studies were repeated on the single layer coated HAP and AT13 implant surfaces. The results reveal that the bilayer (AT13/HAP) coated CP-Ti surface has the improved wear rate, coefficient of friction in compared to single layer coated HAP and AT13 surfaces.

Toward Dendrite-Free Lithium Deposition via Structural and Interfacial Synergistic Effects of 3D Graphene@Ni Scaffold.

PubMed

Xie, Keyu; Wei, Wenfei; Yuan, Kai; Lu, Wei; Guo, Min; Li, Zhihua; Song, Qiang; Liu, Xingrui; Wang, Jian-Gan; Shen, Chao

2016-10-05

Owing to its ultrahigh specific capacity and low electrochemical potential, lithium (Li) metal is regarded as one of the most attractive anode materials for next-generation lithium batteries. Nevertheless, the commercialization of Li-metal-based rechargeable batteries (LiMBs) has been retarded by the uncontrollable growth of Li dendrites, as well as the resulting poor cycle stability and safety hazards. In this work, a 3D graphene@Ni scaffold has been proposed to accomplish dendrite-free Li deposition via structural and interfacial synergistic effects. Due to the intrinsic high surface area used to reduce the effective electrode current density and the surface-coated graphene working as an artificial protection layer to provide high cycle stability as well as suppress the growth of Li dendrites, the Coulombic efficiencies of Li deposition on 3D graphene@Ni foam after 100 cycles can be sustained as high as 96, 98, and 92% at the current densities of 0.25, 0.5, and 1.0 mA cm -2 , respectively, which shows more excellent cycle stability than that of its planar Cu foil and bare Ni foam counterparts. The results obtained here demonstrate that the comprehensive consideration of multiaspect factors could be more help to enhance the performance of Li metal anode so as to achieve its real application in next-generation LiMBs.

Low-temperature relative reflectivity measurements of reflective and scintillating foils used in rare event searches

NASA Astrophysics Data System (ADS)

Langenkämper, A.; Ulrich, A.; Defay, X.; Feilitzsch, F. v.; Lanfranchi, J.-C.; Mondragón, E.; Münster, A.; Oppenheimer, C.; Potzel, W.; Roth, S.; Schönert, S.; Steiger, H.; Trinh Thi, H. H.; Wawoczny, S.; Willers, M.; Zöller, A.

2018-03-01

In this work we investigate the reflectivity of highly reflective multilayer polymer foils used in the CRESST experiment. The CRESST experiment searches directly for dark matter via operating scintillating CaWO4 crystals as targets for elastic dark matter-nucleon scattering. In order to suppress background events, the experiment employs the so-called phonon-light technique which is based on the simultaneous measurement of the heat signal in the main CaWO4 target crystal and of the emitted scintillation light with a separate cryogenic light detector. Both detectors are surrounded by a highly reflective and scintillating multilayer polymer foil to increase the light collection efficiency and to veto surface backgrounds. While this study is motivated by the CRESST experiment, the results are also relevant for other rare event searches using scintillating cryogenic bolometers in the field of the search of dark matter and neutrinoless double beta decay (0 νββ). In this work a dedicated experiment has been set up to determine the relative reflectivity at 300 K and 20 K of three multilayer foils ("VM2000", "VM2002", "Vikuiti") produced by the company 3M. The intensity of a light beam reflected off the foil is measured with a CCD camera. The ratio of the intensities at 300 K and 20 K corresponds to the relative reflectivity change. The measurements performed in this work show no variation of the reflectivity with temperature at a level of ∼1%.

Wideband characterization of printed circuit board materials up to 50 ghz

NASA Astrophysics Data System (ADS)

Rakov, Aleksei

A traveling-wave technique developed a few years ago in the Missouri S&T EMC Laboratory has been employed until now for characterization of PCB materials over a broad frequency range up to 30 GHz. This technique includes measuring S-parameters of the specially designed PCB test vehicles. An extension of the frequency range of printed circuit board laminate dielectric and copper foil characterization is an important problem. In this work, a new PCB test vehicle design for operating up to 50 GHz has been proposed. As the frequency range of measurements increases, the analysis of errors and uncertainties in measuring dielectric properties becomes increasingly important. Formulas for quantification of two major groups of errors, repeatability (manufacturing variability) and reproducibility (systematic) errors, in extracting dielectric constant (DK) and dissipation factor (DK) have been derived, and computations for a number of cases are presented. Conductor (copper foil) surface roughness of PCB interconnects is an important factor, which affects accuracy of DK and DF measurements. This work describes a new algorithm for semi-automatic characterization of copper foil profiles on optical or scanning electron microscopy (SEM) pictures of signal traces. The collected statistics of numerous copper foil roughness profiles allows for introducing a new metric for roughness characterization of PCB interconnects. This is an important step to refining the measured DK and DF parameters from roughness contributions. The collected foil profile data and its analysis allow for developing "design curves", which could be used by SI engineers and electronics developers in their designs.

Vascular stents with submicrometer-scale surface patterning realized via titanium deep reactive ion etching

NASA Astrophysics Data System (ADS)

Gott, Shannon C.; Jabola, Benjamin A.; Rao, Masaru P.

2015-08-01

Herein, we report progress towards realization of vascular stents that will eventually provide opportunity for evaluating cellular response to rationally-designed, submicrometer-scale surface patterning in physiologically-relevant contexts, i.e. those that provide exposure to the complex multicellular milieu, flow-induced shear, and tissue-device interactions present in vivo. Specifically, using our novel titanium deep reactive ion etching technique (Ti DRIE), we discuss recent advances that have enabled: (a) fabrication of precisely-defined, grating-based surface patterns on planar Ti foils with minimum feature sizes as small as 0.15 μm (b) creation of cylindrical stents from micromachined planar Ti foils; and (c) integration of these processes to produce the first submicrometer-scale surface-patterned Ti stents that are compatible with conventional balloon catheter deployment techniques. We also discuss results from elastoplastic finite element simulations and preliminary mechanical testing of these devices to assess their mechanical performance. These efforts represent key steps towards our long-term goal of developing a new paradigm in stenting, where rationally-designed surface patterning provides a physical means for facilitating healing, and thus, improving outcomes in vascular intervention applications.

Monte Carlo simulation for scanning technique with scattering foil free electron beam: A proof of concept study

PubMed Central

Sung, Wonmo; Park, Jong In; Kim, Jung-in; Carlson, Joel; Ye, Sung-Joon

2017-01-01

This study investigated the potential of a newly proposed scattering foil free (SFF) electron beam scanning technique for the treatment of skin cancer on the irregular patient surfaces using Monte Carlo (MC) simulation. After benchmarking of the MC simulations, we removed the scattering foil to generate SFF electron beams. Cylindrical and spherical phantoms with 1 cm boluses were generated and the target volume was defined from the surface to 5 mm depth. The SFF scanning technique with 6 MeV electrons was simulated using those phantoms. For comparison, volumetric modulated arc therapy (VMAT) plans were also generated with two full arcs and 6 MV photon beams. When the scanning resolution resulted in a larger separation between beams than the field size, the plan qualities were worsened. In the cylindrical phantom with a radius of 10 cm, the conformity indices, homogeneity indices and body mean doses of the SFF plans (scanning resolution = 1°) vs. VMAT plans were 1.04 vs. 1.54, 1.10 vs. 1.12 and 5 Gy vs. 14 Gy, respectively. Those of the spherical phantom were 1.04 vs. 1.83, 1.08 vs. 1.09 and 7 Gy vs. 26 Gy, respectively. The proposed SFF plans showed superior dose distributions compared to the VMAT plans. PMID:28493940

Monte Carlo simulation for scanning technique with scattering foil free electron beam: A proof of concept study.

PubMed

Sung, Wonmo; Park, Jong In; Kim, Jung-In; Carlson, Joel; Ye, Sung-Joon; Park, Jong Min

2017-01-01

This study investigated the potential of a newly proposed scattering foil free (SFF) electron beam scanning technique for the treatment of skin cancer on the irregular patient surfaces using Monte Carlo (MC) simulation. After benchmarking of the MC simulations, we removed the scattering foil to generate SFF electron beams. Cylindrical and spherical phantoms with 1 cm boluses were generated and the target volume was defined from the surface to 5 mm depth. The SFF scanning technique with 6 MeV electrons was simulated using those phantoms. For comparison, volumetric modulated arc therapy (VMAT) plans were also generated with two full arcs and 6 MV photon beams. When the scanning resolution resulted in a larger separation between beams than the field size, the plan qualities were worsened. In the cylindrical phantom with a radius of 10 cm, the conformity indices, homogeneity indices and body mean doses of the SFF plans (scanning resolution = 1°) vs. VMAT plans were 1.04 vs. 1.54, 1.10 vs. 1.12 and 5 Gy vs. 14 Gy, respectively. Those of the spherical phantom were 1.04 vs. 1.83, 1.08 vs. 1.09 and 7 Gy vs. 26 Gy, respectively. The proposed SFF plans showed superior dose distributions compared to the VMAT plans.

Slumped glass optics for x-ray telescopes: advances in the hot slumping assisted by pressure

NASA Astrophysics Data System (ADS)

Salmaso, B.; Brizzolari, C.; Basso, S.; Civitani, M.; Ghigo, M.; Pareschi, G.; Spiga, D.; Tagliaferri, G.; Vecchi, G.

2015-09-01

Slumped Glass Optics is a viable solution to build future X-ray telescopes. In our laboratories we use a direct hot slumping approach assisted by pressure, in which the glass optical surface is in contact with the mould, and a pressure is applied to enforce the replication of the mould shape on the glass optical surface. Several prototypes have been already produced and tested in X-rays, showing a continuous improvement in our technology. In this paper, we present the advances in our technology, in terms of slumped glass foils quality and expected performances upon an ideal integration. By using Eagle XG glass foils and Zerodur K20 for the slumping mould, we have fine tuned several process parameters: we present a critical analysis correlating the changes in the process to the improvements in different spatial frequency ranges encompassing the profile and roughness measurements. The use of a re-polished K20 mould, together with the optimized process parameters, lead to the latest result of glass foils with expected performance of less than 3 arcsec in single reflection at 1 keV X-ray energy. This work presents all the relevant steps forward in the hot slumping technology assisted by pressure, aimed at reaching angular resolutions of 5 arcsec for the whole mirror assembly.

[Surface modification of dental alumina ceramic with silica coating].

PubMed

Xie, Hai-Feng; Zhang, Fei-Min; Wang, Xiao-Zu; Xia, Yang

2006-12-01

To make silica coating through sol-gel process, and to evaluate the wettability of dental alumina ceramic with or without coating. Silica coating was prepared with colloidal silica sol on In-Ceram alumina ceramic surface which had been treated with air particle abrasion. Coating gel after heat treatment was observed with atomic force microscope (AFM), and was analyzed by infrared spectrum (IR) with gel without sintered as control. Contact angles of oleic acid to be finished, sandblasted and coated ceramic surface of were measured. AFM pictures showed that some parts of nano-particles in coating gel conglomerated after heat treatment. It can be seen from the IR picture that bending vibration absorption kurtosis of Si-OH also vanished after heat treatment. Among contact angles of three treated surface, the ones on polished surface were the biggest (P = 0.000, P = 0.000), and sandblasting+silica coating surface the smallest (P = 0.000, P = 0.003). Silica coating can be made with sol-gel process successfully. Heat treatment may reinforce Si-O-Si net structure of coating gel. Wettability of dental alumina ceramic with silica coating is higher than with sandblasting and polishing.