Formaldehyde emissions from ventilation filters under different relative humidity conditions.

PubMed

Sidheswaran, Meera; Chen, Wenhao; Chang, Agatha; Miller, Robert; Cohn, Sebastian; Sullivan, Douglas; Fisk, William J; Kumagai, Kazukiyo; Destaillats, Hugo

2013-05-21

Formaldehyde emissions from fiberglass and polyester filters used in building heating, ventilation, and air conditioning (HVAC) systems were measured in bench-scale tests using 10 and 17 cm(2) coupons over 24 to 720 h periods. Experiments were performed at room temperature and four different relative humidity settings (20, 50, 65, and 80% RH). Two different air flow velocities across the filters were explored: 0.013 and 0.5 m/s. Fiberglass filters emitted between 20 and 1000 times more formaldehyde than polyester filters under similar RH and airflow conditions. Emissions increased markedly with increasing humidity, up to 10 mg/h-m(2) at 80% RH. Formaldehyde emissions from fiberglass filters coated with tackifiers (impaction oils) were lower than those from uncoated fiberglass media, suggesting that hydrolysis of other polymeric constituents of the filter matrix, such as adhesives or binders was likely the main formaldehyde source. These laboratory results were further validated by performing a small field study in an unoccupied office. At 80% RH, indoor formaldehyde concentrations increased by 48-64%, from 9-12 μg/m(3) to 12-20 μg/m(3), when synthetic filters were replaced with fiberglass filtration media in the HVAC units. Better understanding of the reaction mechanisms and assessing their overall contributions to indoor formaldehyde levels will allow for efficient control of this pollution source.

Migration to Current Open Source Technologies by MagIC Enables a More Responsive Website, Quicker Development Times, and Increased Community Engagement

NASA Astrophysics Data System (ADS)

Jarboe, N.; Minnett, R.; Koppers, A.; Constable, C.; Tauxe, L.; Jonestrask, L.

2017-12-01

The Magnetics Information Consortium (MagIC) supports an online database for the paleo, geo, and rock magnetic communities ( https://earthref.org/MagIC ). Researchers can upload data into the archive and download data as selected with a sophisticated search system. MagIC has completed the transition from an Oracle backed, Perl based, server oriented website to an ElasticSearch backed, Meteor based thick client website technology stack. Using JavaScript on both the sever and the client enables increased code reuse and allows easy offloading many computational operations to the client for faster response. On-the-fly data validation, column header suggestion, and spreadsheet online editing are some new features available with the new system. The 3.0 data model, method codes, and vocabulary lists can be browsed via the MagIC website and more easily updated. Source code for MagIC is publicly available on GitHub ( https://github.com/earthref/MagIC ). The MagIC file format is natively compatible with the PmagPy ( https://github.com/PmagPy/PmagPy) paleomagnetic analysis software. MagIC files can now be downloaded from the database and viewed and interpreted in the PmagPy GUI based tool, pmag_gui. Changes or interpretations of the data can then be saved by pmag_gui in the MagIC 3.0 data format and easily uploaded to the MagIC database. The rate of new contributions to the database has been increasing with many labs contributing measurement level data for the first time in the last year. Over a dozen file format conversion scripts are available for translating non-MagIC measurement data files into the MagIC format for easy uploading. We will continue to work with more labs until the whole community has a manageable workflow for contributing their measurement level data. MagIC will continue to provide a global repository for archiving and retrieving paleomagnetic and rock magnetic data and, with the new system in place, be able to more quickly respond to the community's requests for changes and improvements.

MAGIC database and interfaces: an integrated package for gene discovery and expression.

PubMed

Cordonnier-Pratt, Marie-Michèle; Liang, Chun; Wang, Haiming; Kolychev, Dmitri S; Sun, Feng; Freeman, Robert; Sullivan, Robert; Pratt, Lee H

2004-01-01

The rapidly increasing rate at which biological data is being produced requires a corresponding growth in relational databases and associated tools that can help laboratories contend with that data. With this need in mind, we describe here a Modular Approach to a Genomic, Integrated and Comprehensive (MAGIC) Database. This Oracle 9i database derives from an initial focus in our laboratory on gene discovery via production and analysis of expressed sequence tags (ESTs), and subsequently on gene expression as assessed by both EST clustering and microarrays. The MAGIC Gene Discovery portion of the database focuses on information derived from DNA sequences and on its biological relevance. In addition to MAGIC SEQ-LIMS, which is designed to support activities in the laboratory, it contains several additional subschemas. The latter include MAGIC Admin for database administration, MAGIC Sequence for sequence processing as well as sequence and clone attributes, MAGIC Cluster for the results of EST clustering, MAGIC Polymorphism in support of microsatellite and single-nucleotide-polymorphism discovery, and MAGIC Annotation for electronic annotation by BLAST and BLAT. The MAGIC Microarray portion is a MIAME-compliant database with two components at present. These are MAGIC Array-LIMS, which makes possible remote entry of all information into the database, and MAGIC Array Analysis, which provides data mining and visualization. Because all aspects of interaction with the MAGIC Database are via a web browser, it is ideally suited not only for individual research laboratories but also for core facilities that serve clients at any distance.

Formaldehyde exposure affects growth and metabolism of common bean

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mutters, R.G.; Madore, M.; Bytnerowicz, A.

Recent state and federal directives have slated a substantial increase in the use of methanol as an alternative to gasoline in both fleet and private vehicles in the coming decade. The incomplete combustion of methanol produces formaldehyde vapor, and catalytic converter technology that completely oxidizes formaldehyde has yet to be developed. The approach of this study was to use a range of methanol concentrations encompassing levels currently found or that may occur in the future in the ambient air of some heavily polluted areas to test the potential phytotoxicity of formaldehyde. The study had the following objectives: (1) design andmore » build a formaldehyde vapor generator with sufficient capacity for long-term plant fumigations; (2) determine growth response of common bean to formaldehyde; (3) evaluate physiological and biochemical changes of bean plants associated with formaldehyde exposures. 20 refs., 2 figs., 2 tabs.« less

A rapid liquid chromatography determination of free formaldehyde in cod.

PubMed

Storey, Joseph M; Andersen, Wendy C; Heise, Andrea; Turnipseed, Sherri B; Lohne, Jack; Thomas, Terri; Madson, Mark

2015-01-01

A rapid method for the determination of free formaldehyde in cod is described. It uses a simple water extraction of formaldehyde which is then derivatised with 2,4-dinitrophenylhydrazine (DNPH) to form a sensitive and specific chromophore for high-performance liquid chromatography (HPLC) detection. Although this formaldehyde derivative has been widely used in past tissue analysis, this paper describes an improved derivatisation procedure. The formation of the DNPH formaldehyde derivative has been shortened to 2 min and a stabilising buffer has been added to the derivative to increase its stability. The average recovery of free formaldehyde in spiked cod was 63% with an RSD of 15% over the range of 25-200 mg kg(-1) (n = 48). The HPLC procedure described here was also compared to a commercial qualitative procedure - a swab test for the determination of free formaldehyde in fish. Several positive samples were compared by both methods.

Determination of naturally occurring formaldehyde levels in sap and wood tissue of maple trees using gas chromatgraphy/mass spectrometry.

PubMed

Lagacé, Luc; Gaudy, Réjean; Perez-Locas, Carolina; Sadiki, Mustapha

2012-01-01

The occurrence of formaldehyde in sap and wood tissue of treated and untreated maple sugar trees was investigated using GC/MS. Samples were collected at different periods of the 2009 season and at different locations in Quebec, Canada. The natural concentration of formaldehyde found in untreated samples varied according to periods and locations and ranged from below the LOQ to 1.82 mg/kg for sap samples and from 2.39 to 8.92 mg/kg of fresh tissue for wood samples. Late season samples tended to have higher concentrations of formaldehyde. Samples of sap and wood tissue from tapholes treated with solutions of formaldehyde showed increased concentrations of formaldehyde for many days after treatment and were clearly distinct from untreated samples. These results will be useful to elaborate new inspection procedures for sugarbushes to control the illegal use of formaldehyde.

Failure mechanisms in wood joints bonded with urea-formaldehyde adhesives

Treesearch

B.H. River; R.O. Ebewele; G.E. Myers

1994-01-01

Wood joints bonded with urea-formaldehyde (UF) are weakened by cyclic swelling and shrinking. To study the failure mechanisms in UF-bonded joints, specimens were bonded with unmodified, modified (amine), or phenol formaldehyde adhesive and subjected to accelerated aging. Modification of the adhesive properties increased the cleavage fracture toughness and shear...

Evaluation of cost-effective sol-gel-based sensor for monitoring of formaldehyde in workplace environment and cancer risk assessment.

PubMed

Bunkoed, Opas; Thavarungkul, Panote; Thammakhet, Chongdee; Kanatharana, Proespichaya

2013-01-01

Formaldehyde was monitored in the workplace environment of an adhesive manufacturer producing formaldehyde and urea-formaldehyde resin using a cost-effective sol-gel-based sensor. The sensor was first evaluated by comparing its performance to the conventional 2,4-dinitrophynylhydrazine-devivatization method (2,4-DNPH) followed by high-performance liquid chromatography coupled to a UV detector. The formaldehyde concentrations obtained by both techniques were not significantly different. The cost-effective sol-gel-based sensor was then used for monitoring formaldehyde levels in the laboratories, production areas and storage room. Formaldehyde concentrations in this adhesive manufacturer workplace environment were lower than the limit value of, 0.75 ppm for an 8-h time weight average and 2 ppm for a short-term exposure (15 min). However, the cancer risk for employees who worked in the laboratories, (1.7±0.7)×10(-4)-(5±2)×10(-4), were higher than the acceptable cancer risk recommended by the US EPA (10(-6)). Therefore, some precaution should be taken to reduce the risk, such as an increase of ventilation to dilute the levels of formaldehyde and use air cleaners to remove formaldehyde.

Effects of formaldehyde gas on the respiratory tract of rhesus monkeys. Pathology and cell proliferation.

PubMed Central

Monticello, T. M.; Morgan, K. T.; Everitt, J. I.; Popp, J. A.

1989-01-01

Formaldehyde is a nasal carcinogen in rats but it remains to be determined what cancer risk this chemical poses in humans. Molecular dosimetry studies of formaldehyde and cellular proliferative responses to formaldehyde-induced cytotoxicity have been studied in the rodent and are important components of the authors' ongoing research, which has now been extended to nonhuman primates, a species more analogous to humans. The present study was designed to characterize formaldehyde injury in the respiratory tract of nonhuman primates to provide a direct comparison to the toxic effects of formaldehyde in rodents. Groups of three rhesus monkeys were exposed to room air, or 6 ppm formaldehyde for 5 days per week for 1 or 6 weeks, and the respiratory tract was assessed for nature and extent of histologic responses, and changes in epithelial cell proliferation rate. Lesions were characterized by mild degeneration and early squamous metaplasia confined to specific regions of the transitional and respiratory epithelia of the nasal passages and the respiratory epithelium of the trachea and major bronchi. There was minimal progression of histologic changes between 1 and 6 weeks; however, the percent of nasal surface area affected significantly increased in the 6-week exposure group. Formaldehyde-induced lesions were associated with increases in cell proliferation rates up to 18-fold over controls, which remained significantly elevated after 6 weeks of exposure. Histologic lesions and increases in cell proliferation were most extensive in the nasal passages and were minimal in the lower airways, whereas the maxillary sinuses exhibited no evidence of a response to formaldehyde exposure. Based on the extent of lesions and cell proliferation data, it appears that the monkey is more sensitive than the rat to the acute and subacute effects of formaldehyde at 6 ppm. The absence of response in the maxillary sinuses in the monkey suggests that combining tumors of the nasal cavity and sinuses in epidemiologic studies may not be appropriate for formaldehyde cancer risk assessment. Results of this study also have provided important information for tissue sample site selection in the monkey respiratory tract for ongoing molecular dosimetry studies. Images Figure 1 Figure 2 Figure 3 Figure 5 Figure 6 Figure 9 PMID:2923182

Determination of partition and diffusion coefficients of formaldehyde in selected building materials and impact of relative humidity.

PubMed

Xu, Jing; Zhang, Jianshun S; Liu, Xiaoyu; Gao, Zhi

2012-06-01

The partition and effective diffusion coefficients of formaldehyde were measured for three materials (conventional gypsum wallboard, "green" gypsum wallboard, and "green" carpet) under three relative humidity (RH) conditions (20%, 50%, and 70% RH). The "green" materials contained recycled materials and were friendly to environment. A dynamic dual-chamber test method was used. Results showed that a higher relative humidity led to a larger effective diffusion coefficient for two kinds of wallboards and carpet. The carpet was also found to be very permeable resulting in an effective diffusion coefficient at the same order of magnitude with the formaldehyde diffusion coefficient in air. The partition coefficient (K(ma)) of formaldehyde in conventional wallboard was 1.52 times larger at 50% RH than at 20% RH, whereas it decreased slightly from 50% to 70% RH, presumably due to the combined effects of water solubility of formaldehyde and micro-pore blocking by condensed moisture at the high RH level. The partition coefficient of formaldehyde increased slightly with the increase of relative humidity in "green" wallboard and "green" carpet. At the same relative humidity level, the "green" wallboard had larger partition coefficient and effective diffusion coefficient than the conventional wallboard, presumably due to the micro-pore structure differences between the two materials. The data generated could be used to assess the sorption effects of formaldehyde on building materials and to evaluate its impact on the formaldehyde concentration in buildings.

TVOC and formaldehyde emission behaviors from flooring materials bonded with environmental-friendly MF/PVAc hybrid resins.

PubMed

Kim, Sumin; Kim, Jin-A; An, Jae-Yoon; Kim, Hyun-Joong; Kim, Shin Do; Park, Jin Chul

2007-10-01

Polyvinyl acetate (PVAc) was added as a replacement for melamine-formaldehyde (MF) resin in the formaldehyde-based resin system to reduce formaldehyde and volatile organic compound (VOC) emissions from the adhesives used between plywoods and fancy veneers. A variety of techniques, including 20-l chamber, field and laboratory emission cell (FLEC), VOC analyzer and standard formaldehyde emission test (desiccator method), were used to determine the formaldehyde and VOC emissions from engineered flooring bonded with five different MF resin and PVAc blends at MF/PVAc ratios of 100:0, 70:30, 50:50, 30:70 and 0:100. Although urea-formaldehyde (UF) resin had the highest formaldehyde emission, the emission as determined by desiccator method was reduced by exchanging with MF resin. Furthermore, the formaldehyde emission level was decreased with increasing addition of PVAc as the replacement for MF resin. UF resin in the case of beech was over 5.0 mg/l, which exceeded E2 (1.5-5.0 mg/l) grade. However, MF30:PVAc70 was

Cohort mortality study of garment industry workers exposed to formaldehyde: update and internal comparisons.

PubMed

Meyers, Alysha R; Pinkerton, Lynne E; Hein, Misty J

2013-09-01

To further evaluate the association between formaldehyde and leukemia, we extended follow-up through 2008 for a cohort mortality study of 11,043 US formaldehyde-exposed garment workers. We computed standardized mortality ratios and standardized rate ratios stratified by year of first exposure, exposure duration, and time since first exposure. Associations between exposure duration and rates of leukemia and myeloid leukemia were further examined using Poisson regression models. Compared to the US population, myeloid leukemia mortality was elevated but overall leukemia mortality was not. In internal analyses, overall leukemia mortality increased with increasing exposure duration and this trend was statistically significant. We continue to see limited evidence of an association between formaldehyde and leukemia. However, the extended follow-up did not strengthen previously observed associations. In addition to continued epidemiologic research, we recommend further research to evaluate the biological plausibility of a causal relation between formaldehyde and leukemia. Copyright © 2013 Wiley Periodicals, Inc.

The influence of α-Al2O3 addition on microstructure, mechanical and formaldehyde adsorption properties of fly ash-based geopolymer products.

PubMed

Huang, Yi; Han, Minfang

2011-10-15

Fly ash-based geopolymer with α-Al(2)O(3) addition were synthesized and used to remove formaldehyde from indoor air. The microstructure, mechanical and formaldehyde adsorption properties of the geopolymer products obtained were investigated. The results showed that α-Al(2)O(3) addition with appropriate amount (such as 5 wt%) increased the geopolymerization extent, resulting in the increase of surface area and compressive strength. In addition, the improvement of structural ordering level for geopolymer sample with 5 wt% α-Al(2)O(3) addition was found through FTIR analysis. By contrast, excessive addition (such as 10 wt%) had the opposite effect. The test of formaldehyde adsorption capacity confirmed that fly ash-based geopolymer product exhibited much better property of adsorbing indoor formaldehyde physically and chemically than fly ash itself. The surface area was an important but not unique factor influencing the adsorption capacity of geopolymers. Copyright © 2011 Elsevier B.V. All rights reserved.

Effect of electric field on adsorption of formaldehyde by β-cellobiose in micro-scale

NASA Astrophysics Data System (ADS)

Xu, Bo; Chen, Zhenqian

2018-05-01

To provide a microcosmic theoretical support for the reduction of formaldehyde in building material by the effect of electric fields, the adsorption between formaldehyde molecule and β-cellobiose was studied by density function theory (DFT). Details of geometric structures, molecule bonds and adsorption energy were discussed respectively. The obtained results indicated the energy of formaldehyde molecule decreased while the energy of β-cellobiose increased with greater electric intensity. In addition, the adsorption energy between formaldehyde molecule and β-cellobiose was greatly influenced by external electric field. The adsorption energy reduced gradually with greater electric intensity, and the changing curve of adsorption energy could be fitted as an exponential function, verified by the experiment. The results of this study confirmed the external electric field would be a good strategy for decreasing formaldehyde within building materials in the microcosmic view.

Role of Transient Receptor Potential Ion Channels and Evoked Levels of Neuropeptides in a Formaldehyde-Induced Model of Asthma in Balb/c Mice

PubMed Central

Wu, Yang; You, Huihui; Ma, Ping; Li, Li; Yuan, Ye; Li, Jinquan; Ye, Xin; Liu, Xudong; Yao, Hanchao; Chen, Ruchong; Lai, Kefang; Yang, Xu

2013-01-01

Objective Asthma is a complex pulmonary inflammatory disease characterized by the hyper-responsiveness, remodeling and inflammation of airways. Formaldehyde is a common indoor air pollutant that can cause asthma in people experiencing long-term exposure. The irritant effect and adjuvant effect are the two possible pathways of formaldehyde promoted asthma. Methodology/Principal Findings To explore the neural mechanisms and adjuvant effect of formaldehyde, 48 Balb/c mice in six experimental groups were exposed to (a) vehicle control; (b) ovalbumin; (c) formaldehyde (3.0 mg/m3); (d) ovalbumin+formaldehyde (3.0 mg/m3); (e) ovalbumin+formaldehyde (3.0 mg/m3)+HC-030031 (transient receptor potential ankyrin 1 antagonist); (f) ovalbumin+formaldehyde (3.0 mg/m3)+ capsazepine (transient receptor potential vanilloid 1 antagonist). Experiments were conducted after 4 weeks of combined exposure and 1-week challenge with aerosolized ovalbumin. Airway hyper-responsiveness, pulmonary tissue damage, eosinophil infiltration, and increased levels of interleukin-4, interleukin-6, interleukin-1β, immunoglobulin E, substance P and calcitonin gene-related peptide in lung tissues were found in the ovalbumin+formaldehyde (3.0 mg/m3) group compared with the values seen in ovalbumin -only immunized mice. Except for interleukin-1β levels, other changes in the levels of biomarker could be inhibited by HC-030031 and capsazepine. Conclusions/Significance Formaldehyde might be a key risk factor for the rise in asthma cases. Transient receptor potential ion channels and neuropeptides have important roles in formaldehyde promoted-asthma. PMID:23671638

The Ghost in the Machine: Why and How the Belief in Magic Survives in the Rational Mind

ERIC Educational Resources Information Center

Subbotsky, Eugene

2011-01-01

Since the time of Galileo (1564-1642), Western civilization has increasingly fallen under the spell of science. Despite this fact, anthropological and psychological research has shown that magical beliefs are present in both children and adults in modern industrial cultures. How can a belief in magic coexist with a belief in science in the mind of…

Does Formaldehyde Increase Cell Free DNA in Maternal Plasma Specimens?

PubMed

Jacob, Rintu R; Saxena, Renu; Verma, Ishwar C

2016-11-01

There have been conflicting observations reported in the literature regarding the effects of formaldehyde in the recovery of cell free fetal DNA (CFF DNA) from maternal plasma. The aim of the present study was to assess the effect of formaldehyde treatment on circulating cell free DNA. We conducted this study using blood specimens collected from 11 pregnant women, each of whom was carrying a male fetus. DYS14 and HBB real time assays were performed to quantify fetal and total circulating cell free DNA from formaldehyde treated and untreated maternal plasma specimens, respectively. The concentration of total circulating cell free DNA in formaldehyde-treated maternal plasma was reduced, compared with untreated maternal plasma (n = 11; P = .02). The percentage of CFF DNA between formaldehyde-treated and untreated maternal plasma specimens did not differ significantly (n = 11; P = .15). Addition of formaldehyde does not significantly enhance the proportion of cell free fetal DNA when blood specimens are processed without delay. © American Society for Clinical Pathology, 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Study on Movable gel Profiling/Flooding System Optimization at Boundary Temperature

NASA Astrophysics Data System (ADS)

Gao, Shanshan; Xie, Gang; Zhang, Tiantian; Wang, Zhiqiang; Jiang, Peijun; Wei, Junjie; Gu, Yi; Lei, Xiaoyang; Guo, Suzhen; Lei, Shi

2017-12-01

65-75°C is the boundary temperature of phenol-formaldehyde resin and organic chrome crosslink with HPAM to generate movable gel. Generally speaking, when the reservoir temperature is below 65-75°C, the crosslinking agent is Organic chrome. Phenol-formaldehyde resin is used when the temperature is above 65-75°C. In this paper the gelation properties of phenol-formaldehyde resin and organic chrome were compared at 70°C. The experiment results showed that the crosslinking time of phenol-formaldehyde resin gel was longer and more conducive to field injection. In addition the phenol-formaldehyde resin gel had greater viscosity, adhesion and shearing resistance compared with the organic chrome gel. So the phenol-formaldehyde resin was chosen for further optimization. The crosslinking time was shortened and the gel viscosity increased with the increase of the polymer concentration. As the polymer crosslinker proportion increased The crosslinking time was shortened and the gel viscosity increased first and then decreased. Reinforcer NC and stabilizer WG were added to improve the temperature and salt tolerance of the gel. The gel formula suitable for the boundary temperature was obtained. The optimum polymer concentration is 1200mg/L, the polymer crosslinker proportion is 1:1.1, the best reinforcer concentration is 400mg/L and the concentration of the stabilizer is 150mg/L. The crosslinking time is 31h, the gel viscosity is above 2100mPa·s. The gel did not shrink and no water separation was observed at 70°C for 150 days. The viscosity retention rate was more than 70%.

Environment-friendly adhesives for surface bonding of wood-based flooring using natural tannin to reduce formaldehyde and TVOC emission.

PubMed

Kim, Sumin

2009-01-01

The objective of this research was to develop environment-friendly adhesives for face fancy veneer bonding of engineered flooring using the natural tannin form bark in the wood. The natural wattle tannin adhesive were used to replace UF resin in the formaldehyde-based resin system in order to reduce formaldehyde and volatile organic compound (VOC) emissions from the adhesives used between plywoods and fancy veneers. PVAc was added to the natural tannin adhesive to increase viscosity of tannin adhesive for surface bonding. For tannin/PVAc hybrid adhesives, 5%, 10%, 20% and 30% of PVAc to the natural tannin adhesives were added. tannin/PVAc hybrid adhesives showed better bonding than the commercial natural tannin adhesive with a higher level of wood penetration. The initial adhesion strength was sufficient to be maintained within the optimum initial tack range. The standard formaldehyde emission test (desiccator method), field and laboratory emission cell (FLEC) and VOC analyzer were used to determine the formaldehyde and VOC emissions from engineered flooring bonded with commercial the natural tannin adhesive and tannin/PVAc hybrid adhesives. By desiccator method and FLEC, the formaldehyde emission level of each adhesive showed the similar tendency. All adhesives satisfied the E(1) grade (below 1.5 mg/L) and E(0) grade (below 0.5 mg/L) with UV coating. VOC emission results by FLEC and VOC analyzer were different with the formaldehyde emission results. TVOC emission was slightly increased as adding PVAc.

Synthesis and Thermal Degradation Studies of Melamine Formaldehyde Resins

PubMed Central

Ullah, Sami; Bustam, M. A.; Nadeem, M.; Tan, W. L.; Shariff, A. M.

2014-01-01

Melamine formaldehyde (MF) resins have been synthesized at different reaction temperature and pH values. Different molar ratios of melamine and formaldehyde were used to synthesize the corresponding resins. The prepared resin samples were characterized by using molecular weight determination viscometry and thermogravimetric analysis (TGA). The maximum percentage of solid content (69.7%) was obtained at pH 8.5 and 75°C temperature. The molecular weight of MF resin was increased with an increase of melamine monomer concentration. The highest residual weight 14.125 wt.% was obtained with sample 10. PMID:25436237

Granular Formulations of Steinernema carpocapsae (strain All) (Nematoda: Rhabditida) with Improved Shelf Life

PubMed Central

Connick, W. J.; Nickle, W. R.; Williams, K. S.; Vinyard, B. T.

1994-01-01

Shelf life (nematode survival) of Steinernema carpocapsae (strain All) nematodes at 21 C in "Pesta" granules, made by a pasta-like process, was increased from 8 to 26 weeks by incorporating low concentrations of formaldehyde. Pesta samples containing an average of 427,000 nematodes/g were prepared with wheat flour (semolina or bread flour), kaolin, bentonite, peat moss, nematode slurry, and formaldehyde (0-1.4% w/w) and were dried to a water content of 23.6-26.9%. Nematodes emerged from Pesta (S. carpocapsae) granules when placed in water or on moist filter paper. Incorporation of 0.2% w/w formaldehyde (nominal; 0.05% by analysis) was optimum for increasing nematode survival in semolina-based Pesta, and also inhibited fungal growth on the granules. Bread flour Pesta samples prepared by formaldehyde addition to the nematode slurry prior to dough preparation, rather than by addition to a mixture of dry ingredients, had longer shelf life. Nematodes recovered from granules made with 0.2% formaldehyde and stored 20 weeks at 21 C caused 100% mortality of wax moth (Galleria mellonella) larvae. PMID:19279903

MAGIC detection of increased activity from FSRQ 3C 279 at very-high-energy gamma rays

NASA Astrophysics Data System (ADS)

Mirzoyan, Razmik

2018-04-01

The MAGIC telescopes observed an increase in the very-high-energy (VHE; > 100 GeV) gamma-ray flux from FSRQ 3C 279 at radio coordinates R.A.=194.04652737 deg and Dec= -5.78931242 deg, J2000.0 (Fey et al. 2004, AJ, 127, 3587).

Performance of optical biosensor using alcohol oxidase enzyme for formaldehyde detection

NASA Astrophysics Data System (ADS)

Sari, A. P.; Rachim, A.; Nurlely, Fauzia, V.

2017-07-01

The recent issue in the world is the long exposure of formaldehyde which is can increase the risk of human health, therefore, that is very important to develop a device and method that can be optimized to detect the formaldehyde elements accurately, have a long lifetime and can be fabricated and produced in large quantities. A new and simple prepared optical biosensor for detection of formaldehyde in aqueous solutions using alcohol oxidase (AOX) enzyme was successfully fabricated. The poly-n-butyl acrylic-co-N-acryloxysuccinimide (nBA-NAS) membranes containing chromoionophore ETH5294 were used for immobilization of alcohol oxidase enzyme (AOX). Biosensor response was based on the colour change of chromoionophore as a result of enzymatic oxidation of formaldehyde and correlated with the detection concentration of formaldehyde. The performance of biosensor parameters were measured through the optical absorption value using UV-Vis spectrophotometer including the repeatability, reproducibility, selectivity and lifetime. The results showed that the prepared biosensor has good repeatability (RSD = 1.9 %) and good reproducibility (RSD = 2.1 %). The biosensor was selective formaldehyde with no disturbance by methanol, ethanol, and acetaldehyde, and also stable before 49 days and decrease by 41.77 % after 49 days.

Contribution of formaldehyde to respiratory cancer.

PubMed Central

Nelson, N; Levine, R J; Albert, R E; Blair, A E; Griesemer, R A; Landrigan, P J; Stayner, L T; Swenberg, J A

1986-01-01

This article reviews the available data on the carcinogenicity of formaldehyde from experimental and epidemiologic studies and makes recommendations for further research. Two definitive chronic inhalation bioassays on rodents have demonstrated that formaldehyde produces nasal cancer in rats and mice at 14 ppm and in rats at 6 ppm, which is within the domain of present permissible human exposure (8-hr time-weighted average of 3 ppm, a 5 ppm ceiling, and a 10 ppm short-term exposure limit). Biochemical and physiologic studies in rats have shown that inhaled formaldehyde can depress respiration, inhibit mucociliary clearance, stimulate cell proliferation, and crosslink DNA and protein in the nasal mucosa. No deaths from nasal cancer have been reported in epidemiologic studies of cohorts exposed to formaldehyde, but three case-control studies suggest the possibility of increased risk. Although excesses of lung cancer deaths have been observed in some studies at industrial plants with formaldehyde exposure, uncertainties in interpretation limit the evaluation of these findings. Excess cancers of the brain and of lymphatic and hematopoietic tissues have been reported in certain studies of industrial groups and in most studies of formaldehyde-exposed professionals, but whether these excesses are related to formaldehyde exposure is not known. Several properties of formaldehyde pose unique problems for future research: the mechanisms responsible for its nonlinear response; its probable mechanism of carcinogenic action as a cross-linking agent; its formation in tissues as a normal metabolite; its possible action as a promoter and/or a cocarcinogen; and the importance of glutathione as a host defense at low exposure. PMID:3830109

The detection of formaldehyde using microelectromechanical acoustic resonator with multiwalled carbon nanotubes-polyethyleneimine composite coating

NASA Astrophysics Data System (ADS)

Wang, Jingjing; Zhan, Da; Wang, Ke; Hang, Weiwei

2018-01-01

A micro-scale gas sensor based on mass-sensitive film bulk acoustic resonator is demonstrated for the detection of trace formaldehyde at room temperature. The composites mixed with multiwalled carbon nanotubes and polyethyleneimine (MWNTs-PEI) were coated on the resonator surface as the sensitive layer to specifically absorb formaldehyde molecules using a facile spray process. The influence of spraying processes on the formaldehyde sensing properties were investigated. Different response behaviors were determined by both the chemical absorption between formaldehyde molecules and the amine functional groups on PEI and the increase of absorption surface came from the nanostructure. The combination of high frequency of the film bulk acoustic resonator (~4.3 GHz) and the specific absorbability of MWNTs-PEI composites provided a high sensitivity in the detections of trace formaldehyde. The obtained ultra-low limit of detection was as low as 60 ppb with linear response, quick response/recovery time, good reproducibility and selectivity. The proposed sensor shows potential as a portable and convenient gas-sensing system for monitoring the low-level concentration of indoor air pollution.

Hollow latex particles functionalized with chitosan for the removal of formaldehyde from indoor air.

PubMed

Nuasaen, Sukanya; Opaprakasit, Pakorn; Tangboriboonrat, Pramuan

2014-01-30

Chitosan and polyethyleneimine (PEI) functionalized hollow latex (HL) particles were conveniently fabricated by coating poly(methyl methacrylate-co-divinyl benzene-co-acrylic acid) (P(MMA/DVB/AA)) HL particles with 5 wt% chitosan or 14 wt% PEI. The materials were used as formaldehyde adsorbent, where their adsorbent activity was examined by Fourier Transform Infrared (FTIR) spectroscopy. The nucleophilic addition of amines to carbonyls generated a carbinolamine intermediate with a characteristic band at 1,020 cm(-1) and Schiff base product at 1650 cm(-1), whose intensity increased with prolonged formaldehyde exposure times. The major products observed in HL-chitosan were carbinolamine and Schiff base, whereas a small amount of Schiff base was obtained in HL-PEI particles, confirming a chemical bond formation without re-emission of formaldehyde. Compared to HL-PEI, HL-chitosan possesses higher formaldehyde adsorption efficiency. Besides providing opacity and whiteness, the multilayer HL-chitosan particles can effectively remove indoor air pollutants, i.e., formaldehyde gas, and, hence, would be useful in special coating applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

Study on the air pollution in typical transportation microenvironment: Characteristics and health risks.

PubMed

Weng, Mili; Jin, Xin

2015-01-01

The concentration of formaldehyde in micro-traffic atmospheric environment (including buses, cars, bus stations, and traffic artery) of Lin'an City was carefully investigated. The results showed that the formaldehyde average concentration was 0.0162 mg/m³ in the buses, 0.0225 mg/m³ in the cars, 0.0047 mg/m³ in the West Bus Stations, and 0.0133 mg/m³ in the East Bus Stations. The concentration of formaldehyde along the traffic artery decreased with the height increased. From 0 to 140 cm, the formaldehyde concentration decreased from 0.031 to 0.018 mg/m³. The formaldehyde concentration decreased when far away from the traffic artery. When the distance reached 200 m, the formaldehyde concentration decreased from 0.018 to 0.005 mg/m³. Based on the health risk assessment model, using 1 hr as the average retention time, the average health risk in buses, cars, and West/East Bus Stations was 2.106 × 10⁻⁴, 2.925 × 10⁻⁴, and 1.157 × 10⁻⁴, respectively.

The curious influence of timing on the magical experience evoked by conjuring tricks involving false transfer: decay of amodal object permanence?

PubMed

Beth, Tessa; Ekroll, Vebjørn

2015-07-01

In magic tricks involving false transfer, the conjurer typically creates the illusion of transferring a coin from one hand into the other, which is then closed into a fist, while in reality the coin is kept hidden in the first hand. The magical experience occurs when the closed fist of the second hand is opened and shown to be empty. According to professional magicians, the magical experience evoked by this kind of tricks becomes noticeably weaker when the time interval between the false transfer and the opening of the fist increases. This observation is surprising, given that neither the length of this interval nor any obvious factors associated with it can be expected to change the spectators' intellectual conviction regarding the true location of the coin. We performed a controlled psychological experiment and obtained results corroborating these informal observations. Increasing the temporal interval from 1 to 32 s led to an average reduction of the strength of the magical experience of 38%. We discuss potential explanations of this curious phenomenon in terms of object persistence, object files and temporal amodal completion.

Undeclared Formaldehyde Levels in Patient Consumer Products: Formaldehyde Test Kit Utility.

PubMed

Ham, Jason E; Siegel, Paul; Maibach, Howard

2018-05-03

Formaldehyde allergic contact dermatitis (ACD) may be due to products with free formaldehyde or formaldehyde-releasing agents, however, assessment of formaldehyde levels in such products is infrequently conducted. The present study quantifies total releasable formaldehyde from "in-use" products associated with formaldehyde ACD and tests the utility of commercially available formaldehyde spot test kits. Personal care products from 2 patients with ACD to formaldehyde were initially screened at the clinic for formaldehyde using a formaldehyde spot test kit. Formaldehyde positive products were sent to the laboratory for confirmation by gas chromatography-mass spectrometry. In addition, 4 formaldehyde spot test kits were evaluated for potential utility in a clinical setting. Nine of the 10 formaldehyde spot test kit positive products obtained from formaldehyde allergic patients had formaldehyde with total releasable formaldehyde levels ranging from 5.4 to 269.4 µg/g. Of these, only 2 shampoos tested listed a formaldehyde-releasing agent in the ingredients or product literature. Subsequently, commercially available formaldehyde spot test kits were evaluated in the laboratory for ability to identify formaldehyde in personal care products. Chemical based formaldehyde spot test were more reliable than the enzymatic based test in identifying product releasable formaldehyde content. It is concluded that product labeled ingredient lists and available information are often inadequate to confirm the potential for formaldehyde exposure and chemical based spot test kits may have utility for identification of potential formaldehyde exposure from personal care products.

Effect of L-Cysteine Pretreatment on the Control of Formaldehyde and Browning of the Culinary-Medicinal Shiitake Mushroom, Lentinus edodes (Higher Basidiomycetes) during Drying and Canning Processes.

PubMed

Li, Guijie; Wang, Qiang; Sun, Peng; Chen, Feng; Chen, Xiaolin; Wang, Cun; Zhao, Xin

2015-01-01

Fresh culinary-medicinal Shiitake mushrooms (Lentinus edodes) were pretreated by soaking in 0.1 mg/mL of L-cysteine solution for 1 hour; then the variation in formaldehyde content and browning degree were studied during hot air-drying and canning processes. The results indicated that L-cysteine pretreatment significantly inhibited the increase of formaldehyde content and browning during the drying process; these increases in the pretreatment groups ranged from 7.0% to 14.0% and 65.4% to 68.9%, respectively, of that of the control groups. While the L-cysteine pretreatment did not seem to have a significant effect on controlling the formaldehyde content during the canning process, the increase of the browning degree of the canned products of the pretreatment groups ranged from 64.8% to 78.5% of that of the control groups, indicating the inhibitive effect of L-cysteine on browning during the canning process of L. edodes. Overall, L-cysteine pretreatment improved the sensory quality of both dried and canned L. edodes.

Modernizing the MagIC Paleomagnetic and Rock Magnetic Database Technology Stack to Encourage Code Reuse and Reproducible Science

NASA Astrophysics Data System (ADS)

Minnett, R.; Koppers, A. A. P.; Jarboe, N.; Jonestrask, L.; Tauxe, L.; Constable, C.

2016-12-01

The Magnetics Information Consortium (https://earthref.org/MagIC/) develops and maintains a database and web application for supporting the paleo-, geo-, and rock magnetic scientific community. Historically, this objective has been met with an Oracle database and a Perl web application at the San Diego Supercomputer Center (SDSC). The Oracle Enterprise Cluster at SDSC, however, was decommissioned in July of 2016 and the cost for MagIC to continue using Oracle became prohibitive. This provided MagIC with a unique opportunity to reexamine the entire technology stack and data model. MagIC has developed an open-source web application using the Meteor (http://meteor.com) framework and a MongoDB database. The simplicity of the open-source full-stack framework that Meteor provides has improved MagIC's development pace and the increased flexibility of the data schema in MongoDB encouraged the reorganization of the MagIC Data Model. As a result of incorporating actively developed open-source projects into the technology stack, MagIC has benefited from their vibrant software development communities. This has translated into a more modern web application that has significantly improved the user experience for the paleo-, geo-, and rock magnetic scientific community.

Do cultural factors affect causal beliefs? Rational and magical thinking in Britain and Mexico.

PubMed

Subbotsky, Eugene; Quinteros, Graciela

2002-11-01

In two experiments, unusual phenomena (spontaneous destruction of objects in an empty wooden box) were demonstrated to adult participants living in rural communities in Mexico. These were accompanied by actions which had no physical link to the destroyed object but could suggest either scientifically based (the effect of an unknown physical device) or non-scientifically based (the effect of a 'magic spell') causal explanations of the event. The results were compared to the results of the matching two experiments from the earlier study made in Britain. The expectation that scientifically based explanations would prevail in British participants' judgments and behaviours, whereas Mexican participants would be more tolerant toward magical explanations, received only partial support. The prevalence of scientific explanations over magical explanations was evident in British participants' verbal judgments but not in Mexican participants' judgments. In their behavioural responses under the low-risk condition, British participants rejected magical explanations more frequently than did Mexican participants. However, when the risk of disregarding the possible causal effect of magic was increased, participants in both samples showed an equal degree of credulity in the possible effect of magic. The data are interpreted in terms of the relationships between scientific and 'folk' representations of causality and object permanence.

Effects of a single inhalative exposure to formaldehyde on the open field behavior of mice.

PubMed

Malek, Fathi A; Möritz, Klaus-Uwe; Fanghänel, Jochen

2004-02-01

The effects of formaldehyde on the explorative behavior and locomotor activity of mice after a single inhalative exposure were examined in an open field. Adult male mice were exposed to approximately 1.1 ppm, 2.3 ppm, or 5.2 ppm formaldehyde vapour for 2 hours and the open field test was carried out two hours after the end of exposure (trial 1) and repeated 24 hours thereafter (trial 2). The following behavioral parameters were quantitatively examined: numbers of crossed floor squares (inner, peripheral, total), sniffing, grooming, rearing, climbing, and incidence of fecal boli. The results of the first trial revealed that the motion activity was significantly reduced in all exposed groups. In the 1.1 ppm group, the frequency of rearing was reduced and that of floor sniffing increased. The exposure to the two higher formaldehyde concentrations caused a significant decrease in total numbers of floor squares crossed by the subjects, air sniffing, and rearing. The open field test on the next day (trial 2) showed that the frequencies of floor sniffing, grooming, and rearing in all formaldehyde groups were significantly altered. In the 2.5 ppm group, an increased incidence of fecal boli was observed. From the results obtained, we conclude that the exposure of male mice to formaldehyde vapour affects their locomotor and explorative activity in the open field, and that some open field parameters are still altered in the exposed animals even after 24 hours.

CONTINUOUS FORMALDEHYDE MEASUREMENT SYSTEM BASED ON MODIFIED FOURIER TRANSFORM INFRARED SPECTROSCOPY

EPA Science Inventory

EPA is developing advanced open-path and cell-based optical techniques for time-resolved measurement of priority hazardous air pollutants such as formaldehyde (HCHO). Due to its high National Air Toxics Assessment risk factor, there is increasing interest in continuous measuremen...

Formaldehyde in cosmetics in patch tested dermatitis patients with and without contact allergy to formaldehyde.

PubMed

Hauksson, Inese; Pontén, Ann; Isaksson, Marléne; Hamada, Haneen; Engfeldt, Malin; Bruze, Magnus

2016-03-01

Formaldehyde is a well-known contact sensitizer. Formaldehyde releasers are widely used preservatives in cosmetics. To survey the release of formaldehyde in cosmetics brought by patients investigated because of suspected allergic contact dermatitis, to compare it with information given by the manufacturers on the packages, and to investigate whether formaldehyde-allergic patients are potentially exposed to more cosmetics releasing formaldehyde than dermatitis patients without contact allergy to formaldehyde. Cosmetics from 10 formaldehyde-allergic and 30 non-allergic patients (controls) matched for age and sex were investigated with the chromotropic acid spot test, which is a semiquantitative method measuring the release of formaldehyde. Formaldehyde was found in 58 of 245 (23.7%) products. Twenty-six of 126 (20.6%) leave-on products released formaldehyde, and 17 of 26 (65.4%) of these were not declared to contain formaldehyde or formaldehyde releasers. Among the rinse-off products, there were 32 of 119 (26.8%) formaldehyde-releasing products, and nine of 32 (28.0%) of these were not labelled as containing formaldehyde or formaldehyde releasers. Five of 10 formaldehyde-allergic patients brought leave-on products with ≥ 40 ppm formaldehyde, as compared with 4 of 30 in the control group (p = 0.029). Cosmetic products used by formaldehyde-allergic patients that are not declared to contain formaldehyde or formaldehyde-releasing preservatives should be analysed. © 2015 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

Creating Magic Squares.

ERIC Educational Resources Information Center

Lyon, Betty Clayton

1990-01-01

One method of making magic squares using a prolongated square is illustrated. Discussed are third-order magic squares, fractional magic squares, fifth-order magic squares, decimal magic squares, and even magic squares. (CW)

Formation of formaldehyde and peroxides by air oxidation of high purity polyoxyethylene surfactants.

PubMed

Bergh, M; Magnusson, K; Nilsson, J L; Karlberg, A T

1998-07-01

Ethoxylated alcohols are non-ionic surfactants. The majority are used in household cleaners, laundry products, toiletries and in industrial and institutional cleaners. In previous studies, an ethoxylated non-ionic surfactant of technical quality showed allergenic activity in guinea pig experiments. Chemical analysis revealed a content of formaldehyde, a well-known contact allergen, and peroxides in the surfactant. Most cases of occupational contact dermatitis are considered to be of irritant origin, caused by contact with water and surfactants, but if allergenic autoxidation products can be formed, allergic contact dermatitis cannot be excluded. The sensitizing potential of a chemically defined high purity ethoxylated alcohol was investigated and oxidation under various storage and handling conditions was studied for this and a homologous product. The pure surfactant showed no significant allergenic activity on predictive testing in guinea pigs. When ethoxylated alcohols were stored in the refrigerator, their deterioration was limited. At room temperature, their content of peroxides and formaldehyde increased with time. Levels of formaldehyde above those capable of causing positive patch test reactions were found. Since such surfactants have wide applications, resulting exposure to formaldehyde could be more frequent than is generally realized, contributing to persistence of dermatitis in individuals allergic to formaldehyde.

Indoor Air Quality and Asthma

PubMed Central

Holm, Stewart

2017-01-01

Numerous contaminants in indoor air and their potential to cause or exacerbate asthma continue to be a subject of public health concern. Many agents are causally associated with or can exacerbate asthma, particularly in children. For formaldehyde, an established respiratory irritant based on numerous studies, the evidence for an association with asthma is still considered only limited or suggestive. However, there is no evidence that indicates increased sensitivity to sensory irritation to formaldehyde in people often regarded as susceptible such as asthmatics. Acrolein, but not formaldehyde, was significantly associated with asthma in a large cohort of children. This prompted an evaluation of this highly irritating chemical that had never previously been considered in the context of the indoor air/childhood asthma issue. Because acrolein is more potent than formaldehyde as a respiratory irritant and ubiquitous in indoor air, it is plausible that previous studies on potential risk factors and childhood asthma may be confounded by formaldehyde acting as an unrecognized proxy for acrolein. PMID:28250718

Organocatalytic removal of formaldehyde adducts from RNA and DNA bases.

PubMed

Karmakar, Saswata; Harcourt, Emily M; Hewings, David S; Scherer, Florian; Lovejoy, Alexander F; Kurtz, David M; Ehrenschwender, Thomas; Barandun, Luzi J; Roost, Caroline; Alizadeh, Ash A; Kool, Eric T

2015-09-01

Formaldehyde is universally used to fix tissue specimens, where it forms hemiaminal and aminal adducts with biomolecules, hindering the ability to retrieve molecular information. Common methods for removing these adducts involve extended heating, which can cause extensive degradation of nucleic acids, particularly RNA. Here, we show that water-soluble bifunctional catalysts (anthranilates and phosphanilates) speed the reversal of formaldehyde adducts of mononucleotides over standard buffers. Studies with formaldehyde-treated RNA oligonucleotides show that the catalysts enhance adduct removal, restoring unmodified RNA at 37 °C even when extensively modified, while avoiding the high temperatures that promote RNA degradation. Experiments with formalin-fixed, paraffin-embedded cell samples show that the catalysis is compatible with common RNA extraction protocols, with detectable RNA yields increased by 1.5-2.4-fold using a catalyst under optimized conditions and by 7-25-fold compared with a commercial kit. Such catalytic strategies show promise for general use in reversing formaldehyde adducts in clinical specimens.

Organocatalytic Removal of Formaldehyde Adducts from RNA and DNA Bases

PubMed Central

Karmakar, Saswata; Harcourt, Emily M.; Hewings, David S.; Lovejoy, Alexander F.; Kurtz, David M.; Ehrenschwender, Thomas; Barandun, Luzi J.; Roost, Caroline; Alizadeh, Ash A.; Kool, Eric T.

2015-01-01

Formaldehyde is universally employed to fix tissue specimens, where it forms hemiaminal and aminal adducts with biomolecules, hindering the ability to retrieve molecular information. Common methods for removing these adducts involve extended heating, which can cause extensive degradation of nucleic acids, particularly RNA. Here we show that water-soluble bifunctional catalysts (anthranilates and phosphanilates) speed the reversal of formaldehyde adducts of mononucleotides over standard buffers. Studies with formaldehyde-treated RNA oligonucleotides show that the catalysts enhance adduct removal, restoring unmodified RNA at 37 °C even when extensively modified, and avoiding high temperatures that promote RNA degradation. Experiments with formalin-fixed, paraffin-embedded cell samples show that the catalysis is compatible with common RNA extraction protocols, with detectable RNA yields increased by 1.5–2.4 fold using a catalyst under optimized conditions, and by 7–25 fold compared to a commercial kit. Such catalytic strategies show promise for general use in reversing formaldehyde adducts in clinical specimens. PMID:26291948

Assessment of lipid peroxidation and p53 as a biomarker of carcinogenesis among workers exposed to formaldehyde in the cosmetic industry.

PubMed

Attia, Dalia; Mansour, Neveen; Taha, Fatma; Seif El Dein, Aisha

2016-06-01

Despite the wide use of cosmetic products, they exert a number of health effects on tissues ranging from irritation to cancer. Our study aimed at assessing the effect of formaldehyde on lipid peroxidation and verifying the susceptibility to carcinogenesis using p53 as a biomarker among workers exposed to formaldehyde in cosmetic industry. Our entire exposed group (n = 40) and the controls (n = 20) were subjected to estimation of formate in urine, serum malondialdehyde (MDA), and p53. Also, complete blood picture, liver, and kidney function tests were carried out. The study revealed significant increase in the levels of formate, MDA, and p53 in the exposed group compared with their control group. Our results showed that workers in cosmetic industry had significant exposure to formaldehyde. Furthermore, the study pointed to the negative impact of formaldehyde as a cause of oxidative stress and suspicious carcinogen. © The Author(s) 2014.

Does magical thinking produce neutralising behaviour? An experimental investigation.

PubMed

Bocci, Laura; Gordon, P Kenneth

2007-08-01

Magical thinking is of relevance to obsessive compulsive disorder (OCD), and has been most widely investigated in relation to the cognitive bias known as thought-action fusion (TAF). This is seen as playing a role in the formation of fears about responsibility for harm. We suggest that magical thinking may also characterise some types of neutralising behaviour, which arise in response to those fears, and are a hallmark of the disorder. In an experimental study of 51 undergraduate students, we assessed whether the use of neutralising behaviours in response to an induction of fears of increasing likelihood for harm is related to a propensity for magical thinking. The 75.5% of participants demonstrated at least one form of neutralising behaviour in response to a TAF-induction task. Neutralising was associated with stronger and more persistent responses to the task, and with questionnaire measures of magical ideation. Those who neutralised did not report higher levels of OCD symptoms. It appears that neutralising is a common response in circumstances that provoke a sense of responsibility for harm. Its occurrence may be linked to magical thinking, however, the results from this experimental investigation suggested that this process may not be specific to OCD.

Measurement of endogenous versus exogenous formaldehyde-induced DNA-protein crosslinks in animal tissues by stable isotope labeling and ultrasensitive mass spectrometry

PubMed Central

Lai, Yongquan; Yu, Rui; Hartwell, Hadley J.; Moeller, Benjamin C.; Bodnar, Wanda M.; Swenberg, James A.

2016-01-01

DNA-protein crosslinks (DPCs) arise from a wide range of endogenous and exogenous chemicals, such as chemotherapeutic drugs and formaldehyde. Importantly, recent identification of aldehydes as endogenous genotoxins in Fanconi anemia has provided new insight into disease causation. Due to their bulky nature, DPCs pose severe threats to genome stability, but previous methods to measure formaldehyde-induced DPCs were incapable of discriminating between endogenous and exogenous sources of chemical. In this study, we developed methods that provide accurate and distinct measurements of both exogenous and endogenous DPCs in a structurally-specific manner. We exposed experimental animals to stable isotope-labeled formaldehyde ([13CD2]-formaldehyde) by inhalation and performed ultrasensitive mass spectrometry to measure endogenous (unlabeled) and exogenous (13CD2-labeled) DPCs. We found that exogenous DPCs readily accumulated in nasal respiratory tissues, but were absent in tissues distant to the site of contact. This observation together with the finding that endogenous formaldehyde-induced DPCs were present in all tissues examined suggests that endogenous DPCs may be responsible for increased risks of bone marrow toxicity and leukemia. Furthermore, the slow rate of DPC repair provided evidence for persistence of DPCs. In conclusion, our method for measuring endogenous and exogenous DPCs presents a new perspective for the potential health risks inflicted by endogenous formaldehyde, and may inform improved disease prevention and treatment strategies. PMID:26984759

Ambidexterity and magical ideation.

PubMed

Barnett, Kylie J; Corballis, Michael C

2002-01-01

In a sample of 250 healthy undergraduate students, scores on a scale of magical ideation rose to a peak at the point of ambilaterality on a scale of hand preference, and fell away with increasing right- or left-handedness. This effect mirrors that reported by Crow, Crow, Done, and Leask (1998) who found a dip in academic abilities at the point of ambilaterality, or what they call ''the point of hemispheric indecision''. We relate these findings to genetic theories of laterality in which one allele (RS+) codes for left-cerebral dominance while the other (RS-) leaves laterality to chance. RS-- homozygotes may be susceptible to a lack of dominance, resulting in a disposition to magical ideation and an increased risk of schizophrenia, but also enhanced creativity and lateral thinking.

A tale of two morphs: modeling pollen transfer, magic traits, and reproductive isolation in parapatry.

PubMed

Haller, Benjamin C; de Vos, Jurriaan M; Keller, Barbara; Hendry, Andrew P; Conti, Elena

2014-01-01

The evolution of the flower is commonly thought to have spurred angiosperm diversification. Similarly, particular floral traits might have promoted diversification within specific angiosperm clades. We hypothesize that traits promoting the precise positional transfer of pollen between flowers might promote diversification. In particular, precise pollen transfer might produce partial reproductive isolation that facilitates adaptive divergence between parapatric populations differing in their reproductive-organ positions. We investigate this hypothesis with an individual-based model of pollen transfer dynamics associated with heterostyly, a floral syndrome that depends on precise pollen transfer. Our model shows that precise pollen transfer can cause sexual selection leading to divergence in reproductive-organ positions between populations served by different pollinators, pleiotropically causing an increase in reproductive isolation through a "magic trait" mechanism. Furthermore, this increased reproductive isolation facilitates adaptive divergence between the populations in an unlinked, ecologically selected trait. In a different pollination scenario, however, precise pollen transfer causes a decrease in adaptive divergence by promoting asymmetric gene flow. Our results highlight the idea that magic traits are not "magic" in isolation; in particular, the effect size of magic traits in speciation depends on the external environment, and also on other traits that modify the strength of the magic trait's influence on non-random mating. Overall, we show that the evolutionary consequences of pollen transfer dynamics can depend strongly on the available pollinator fauna and on the morphological fit between flowers and pollinators. Furthermore, our results illustrate the potential importance of even weak reproductive isolating barriers in facilitating adaptive divergence.

Impact of endophytic colonization patterns on Zamioculcas zamiifolia stress response and in regulating ROS, tryptophan and IAA levels under airborne formaldehyde and formaldehyde-contaminated soil conditions.

PubMed

Khaksar, Gholamreza; Treesubsuntorn, Chairat; Thiravetyan, Paitip

2017-05-01

Deeper understanding of plant-endophyte interactions under abiotic stress would provide new insights into phytoprotection and phytoremediation enhancement. Many studies have investigated the positive role of plant-endophyte interactions in providing protection to the plant against pollutant stress through auxin (indole-3-acetic acid (IAA)) production. However, little is known about the impact of endophytic colonization patterns on plant stress response in relation to reactive oxygen species (ROS) and IAA levels. Moreover, the possible effect of pollutant phase on plant stress response is poorly understood. Here, we elucidated the impact of endophytic colonization patterns on plant stress response under airborne formaldehyde compared to formaldehyde-contaminated soil. ROS, tryptophan and IAA levels in the roots and shoots of endophyte-inoculated and non-inoculated plants in the presence and absence of formaldehyde were measured. Strain-specific quantitative polymerase chain reaction (qPCR) was used to investigate dynamics of endophyte colonization. Under the initial exposure to airborne formaldehyde, non-inoculated plants accumulated more tryptophan in the shoots (compared to the roots) to synthesize IAA. However, endophyte-inoculated plants behaved differently as they synthesized and accumulated more tryptophan in the roots and, hence, higher levels of IAA accumulation and exudation within roots which might act as a signaling molecule to selectively recruit B. cereus ERBP. Under continuous airborne formaldehyde stress, higher levels of ROS accumulation in the shoots pushed the plant to synthesize more tryptophan and IAA in the shoots (compared to the roots). Higher levels of IAA in the shoots might act as the potent driving force to relocalize B. cereus ERBP from roots to the shoots. In contrast, under formaldehyde-contaminated soil, B. cereus ERBP colonized root tissues without moving to the shoots since there was a sharp increase in ROS, tryptophan and IAA levels of the roots without any significant increase in the shoots. Pollutant phase affected endophytic colonization patterns and plant stress responses differently. Copyright © 2017 Elsevier Masson SAS. All rights reserved.

Skincare products containing low concentrations of formaldehyde detected by the chromotropic acid method cannot be safely used in formaldehyde-allergic patients.

PubMed

Hauksson, I; Pontén, A; Gruvberger, B; Isaksson, M; Engfeldt, M; Bruze, M

2016-02-01

Formaldehyde is a well-known contact sensitizer. Formaldehyde releasers are widely used preservatives in skincare products. It has been found that formaldehyde at concentrations allowed by the European Cosmetics Directive can cause allergic contact dermatitis. However, we still lack information on whether formaldehyde at low concentrations affects dermatitis in formaldehyde-allergic individuals. To study the effects of low concentrations of formaldehyde on irritant contact dermatitis in formaldehyde-allergic individuals. Fifteen formaldehyde-allergic individuals and a control group of 12 individuals without contact allergy to formaldehyde and formaldehyde releasers were included in the study. The individuals performed the repeated open application test (ROAT) during 4 weeks with four different moisturizers releasing formaldehyde in concentrations that had been determined as > 40, 20-40, 2·5-10 and 0 p.p.m. by the chromotropic acid (CA) spot test. Dimethyloldimethylhydantoin was used as a formaldehyde releaser in the moisturizers. The ROAT was performed on areas of experimentally induced sodium lauryl sulfate dermatitis. The study was double blind, controlled and randomized. Nine of the 15 formaldehyde-allergic individuals had reappearance or worsening of dermatitis on the areas that were treated with moisturizers containing formaldehyde. No such reactions were observed in the control group (P < 0·001) or for the moisturizers without formaldehyde in the formaldehyde-allergic individuals (P < 0·001). Our results demonstrate that the low concentrations of formaldehyde often found in skincare products by the CA method are sufficient to worsen an existing dermatitis in formaldehyde-allergic individuals. © 2015 British Association of Dermatologists.

Rocket and Missile Container Engineering Guide

DTIC Science & Technology

1982-01-01

impregnated with urea - formaldehyde and melamine - formaldehyde resins , found that a high degree of fungous resistance was imparted to the cotton...34 Phenol-aniline- formaldehyde Resorcinol- formaldehyde Urea - formaldehydes Urea -formaldehydeh Protein- formaldehydes Zein- formaldehyde ("Vicara") Casein...Practically, any cush- ioning material can be made resistant to fungi. The treatment usually involves impregnation

Accelerated cure of phenol-formaldehyde resins : studies with model compounds

Treesearch

Anthony H. Conner; Linda F. Lorenz; Kolby C. Hirth

2002-01-01

2-Hydroxymethylphenol (2-HMP) and 4-hydroxymethylphenol (4-HMP) were used as model compounds to study the reactions that occur during cure of phenol-formaldehyde (PF) resin to which cure accelerators (ethyl formate, propylene carbonate, g-butyrolactone, and triacetin) have been added. The addition of cure accelerators significantly increased the rate of condensation...

Euphorbia milii-native bacteria interactions under airborne formaldehyde stress: Effect of epiphyte and endophyte inoculation in relation to IAA, ethylene and ROS levels.

PubMed

Khaksar, Gholamreza; Treesubsuntorn, Chairat; Thiravetyan, Paitip

2017-02-01

Better understanding of plant-bacteria interactions under stress is of the prime importance for enhancing airborne pollutant phytoremediation. No studies have investigated plant-epiphyte interactions compared to plant-endophyte interactions under airborne formaldehyde stress in terms of plant Indole-3-acetic acid (IAA), ethylene, reactive oxygen species (ROS) levels and pollutant removal efficiency. Euphorbia milii was inoculated with native plant growth-promoting (PGP) endophytic and epiphytic isolates individually to investigate plant-endophyte compared to plant-epiphyte interactions under continuous formaldehyde fumigation. Under airborne formaldehyde stress, endophyte interacts with its host plant closely and provides higher levels of IAA which protected the plant against formaldehyde phytotoxicity by lowering intracellular ROS, ethylene levels and maintaining shoot epiphytic community; hence, higher pollutant removal. However, plant-epiphyte interactions could not provide enough IAA to confer protection against formaldehyde stress; thus, increased ROS and ethylene levels, large decrease in shoot epiphytic population and lower pollutant removal although epiphyte contacts with airborne pollutant directly (has greater access to gaseous formaldehyde). Endophyte-inoculated plant synthesized more tryptophan as a signaling molecule for its associated bacteria to produce IAA compared to the epiphyte-inoculated one. Under stress, PGP endophyte interacts with its host closely; thus, better protection against stress and higher pollutant removal compared to epiphyte which has limited interactions with the host plant; hence, lower pollutant removal. Copyright © 2016 Elsevier Masson SAS. All rights reserved.

Measurement of Endogenous versus Exogenous Formaldehyde-Induced DNA-Protein Crosslinks in Animal Tissues by Stable Isotope Labeling and Ultrasensitive Mass Spectrometry.

PubMed

Lai, Yongquan; Yu, Rui; Hartwell, Hadley J; Moeller, Benjamin C; Bodnar, Wanda M; Swenberg, James A

2016-05-01

DNA-protein crosslinks (DPC) arise from a wide range of endogenous and exogenous chemicals, such as chemotherapeutic drugs and formaldehyde. Importantly, recent identification of aldehydes as endogenous genotoxins in Fanconi anemia has provided new insight into disease causation. Because of their bulky nature, DPCs pose severe threats to genome stability, but previous methods to measure formaldehyde-induced DPCs were incapable of discriminating between endogenous and exogenous sources of chemical. In this study, we developed methods that provide accurate and distinct measurements of both exogenous and endogenous DPCs in a structurally specific manner. We exposed experimental animals to stable isotope-labeled formaldehyde ([(13)CD2]-formaldehyde) by inhalation and performed ultrasensitive mass spectrometry to measure endogenous (unlabeled) and exogenous ((13)CD2-labeled) DPCs. We found that exogenous DPCs readily accumulated in nasal respiratory tissues but were absent in tissues distant to the site of contact. This observation, together with the finding that endogenous formaldehyde-induced DPCs were present in all tissues examined, suggests that endogenous DPCs may be responsible for increased risks of bone marrow toxicity and leukemia. Furthermore, the slow rate of DPC repair provided evidence for the persistence of DPCs. In conclusion, our method for measuring endogenous and exogenous DPCs presents a new perspective for the potential health risks inflicted by endogenous formaldehyde and may inform improved disease prevention and treatment strategies. Cancer Res; 76(9); 2652-61. ©2016 AACR. ©2016 American Association for Cancer Research.

Investigation of formaldehyde interaction with carbon nanotubes and quartz sand

NASA Astrophysics Data System (ADS)

Georgopoulou, Maria P.; Chrysikopoulos, Constantinos V.

2017-04-01

Assessment of the potential impact of synthetic carbon nanotubes on the fate and transport of common chemical contaminants (pesticides, pharmaceuticals, etc.) in groundwater systems is considered to be an increasingly important aspect of environmental research. This study investigates the interaction of formaldehyde with multi-walled carbon nanotubes (MWCNTs) and quartz sand under static and dynamic conditions. Due to polarity, formaldehyde, is expected to develop strong adsorptive interactions with carbon nanotubes. Several batch adsorption experiments were conducted in test tubes, under controlled conditions. Various initial formaldehyde solution concentration (2, 5, 8 ppm), contact times, and temperatures (8, 18, 25 °C) were considered. Supernatant liquid samples were collected at regular intervals, and centrifuged. Subsequently, the formaldehyde concentration in the supernatant was quantified indirectly, by derivatization with Nash reagent and subsequent measurement of the resulting complex using spectrophotometry in the visible spectral range. Experimental results suggested that formaldehyde has a low affinity for quartz sand, but an enhanced potential for adsorption onto carbon nanotubes. Formaldehyde adsorption onto both absorbents (quartz sand and MWCNTs) was more pronounced under dynamic than static conditions, probably, because agitation improves the mixing of the absorbent within the solution. Also, it was shown that the adsorption data were adequately described by the pseudo-second order kinetic model, suggesting that the primary adsorption mechanism was chemisorption, where two or more (sequential or parallel) processes (e.g. surface chemisorption, intraparticle diffusion) were taking place. Therefore, MWCNTs could be promising adsorbent materials for groundwater remediation.

Regulation characteristics of oxide generation and formaldehyde removal by using volume DBD reactor

NASA Astrophysics Data System (ADS)

Bingyan, CHEN; Xiangxiang, GAO; Ke, CHEN; Changyu, LIU; Qinshu, LI; Wei, SU; Yongfeng, JIANG; Xiang, HE; Changping, ZHU; Juntao, FEI

2018-02-01

Discharge plasmas in air can be accompanied by ultraviolet (UV) radiation and electron impact, which can produce large numbers of reactive species such as hydroxyl radical (OH·), oxygen radical (O·), ozone (O3), and nitrogen oxides (NO x ), etc. The composition and dosage of reactive species usually play an important role in the case of volatile organic compounds (VOCs) treatment with the discharge plasmas. In this paper, we propose a volume discharge setup used to purify formaldehyde in air, which is configured by a plate-to-plate dielectric barrier discharge (DBD) channel and excited by an AC high voltage source. The results show that the relative spectral-intensity from DBD cell without formaldehyde is stronger than the case with formaldehyde. The energy efficiency ratios (EERs) of both oxides yield and formaldehyde removal can be regulated by the gas flow velocity in DBD channel, and the most desirable processing effect is the gas flow velocity within the range from 2.50 to 3.33 m s-1. Moreover, the EERs of both the generated dosages of oxides (O3 and NO2) and the amount of removed formaldehyde can also be regulated by both of the applied voltage and power density loaded on the DBD cell. Additionally, the EERs of both oxides generation and formaldehyde removal present as a function of normal distribution with increasing the applied power density, and the peak of the function is appeared in the range from 273.5 to 400.0 W l-1. This work clearly demonstrates the regulation characteristic of both the formaldehyde removal and oxides yield by using volume DBD, and it is helpful in the applications of VOCs removal by using discharge plasma.

Control of formaldehyde and TVOC emission from wood-based flooring composites at various manufacturing processes by surface finishing.

PubMed

Kim, Sumin

2010-04-15

This paper assesses the reproducibility of testing formaldehyde and TVOC emission behavior from wood flooring composites bonded by urea-formaldehyde resin at various manufacturing steps for surface finishing materials. The surface adhesion step of laminate flooring for this research was divided into two steps; HDF only and HDF with LPMs. In the case of engineered flooring, the manufacturing steps were divided into three steps; plywood only, fancy veneer bonded on plywood and UV coated on fancy veneer with plywood. Formaldehyde and VOCs emission decreased at the process of final surface finishing materials; LPMs were applied on the surface of HDF for laminate flooring. Although emissions increased when fancy veneer was bonded onto plywood in the case of engineered flooring, emission was dramatically reduced up to similar level with plywood only when final surface finishing; UV-curable coating was applied on fancy veneer. This study suggests that formaldehyde and VOCs emission from floorings can be controlled at manufacturing steps for surface finishing. 2009 Elsevier B.V. All rights reserved.

Enhanced effect of water vapor on complete oxidation of formaldehyde in air with ozone over MnOx catalysts at room temperature.

PubMed

Zhao, De-Zhi; Shi, Chuan; Li, Xiao-Song; Zhu, Ai-Min; Jang, Ben W-L

2012-11-15

At room temperature, the enhanced effect of water vapor on ozone catalytic oxidation (OZCO) of formaldehyde to CO2 over MnOx catalysts and the reaction stability was reported. In a dry air stream, only below 20% of formaldehyde could be oxidized into CO2 by O3. In humid air streams (RH≥55%), ∼100% of formaldehyde were oxidized into CO2 by O3 and the reaction stability was significantly enhanced. Meanwhile, in situ Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectra of OZCO of HCHO demonstrate that the amount of both monodentate and bidentate carbonate species on MnOx, in the dry stream, increased gradually with time on stream (TOS). However, in the humid stream, almost no accumulation of carbonate species on the catalysts was observed. To clarify the enhanced mechanism, formaldehyde surface reactions and CO2 adsorption/desorption on the fresh, O3 and O3+H2O treated MnOx catalysts were examined comparatively. Copyright © 2012 Elsevier B.V. All rights reserved.

Assessment of Magical Beliefs about Food and Health.

PubMed

Lindeman, M; Keskivaara, P; Roschier, M

2000-03-01

The Magical Beliefs About Food and Health scale (MFH) was developed to assess individual differences in the tendency to adopt eating and health instructions that many magazines, health care books and food ideologies regard as valid but which obey universal laws of similarity and contagion. In a study of 216 individuals, the total MFH score showed good internal consistency and it was associated with various validity criteria as hypothesized (e.g. vegetarianism and other ideological commitments to food choice, female gender, increased neuroticism, experiential thinking, positive attitudes towards alternative medicine, low sensation seeking and endorsement of universalism values). Factor analysis yielded two factors: General Magical Beliefs and Animal Products as Food Contaminants. In addition, three other items (the Animal Products as Personality Contaminants scale) cross-loaded on the two factors. The factor structure and test-retest reliability were confirmed with separate samples. The results showed that the total MFH score is a reliable and valid measure of magical food and health beliefs, and that the subscales may prove useful when a multidimensional assessment of magical beliefs is needed.

78 FR 44090 - Formaldehyde; Third-Party Certification Framework for the Formaldehyde Standards for Composite...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-23

... Formaldehyde; Third-Party Certification Framework for the Formaldehyde Standards for Composite Wood Products..., concerning a third-party certification framework for the formaldehyde standards for composite wood products... Environmental protection, Composite wood products, Formaldehyde, Reporting and recordkeeping, Third-party...

78 FR 34795 - Formaldehyde; Third-Party Certification Framework for the Formaldehyde Standards for Composite...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-10

... Formaldehyde; Third-Party Certification Framework for the Formaldehyde Standards for Composite Wood Products; Formaldehyde Emissions Standards for Composite Wood Products; Proposed Rules #0;#0;Federal Register / Vol. 78... Certification Framework for the Formaldehyde Standards for Composite Wood Products AGENCY: Environmental...

Magic Breakfast: Evaluation Report and Executive Summary

ERIC Educational Resources Information Center

Crawford, Claire; Edwards, Amy; Farquharson, Christine; Greaves, Ellen; Trevelyan, Grace; Wallace, Emma; White, Clarissa

2016-01-01

The Magic Breakfast project provided 106 schools with support and resources to offer a free, universal, before-school breakfast club, including to all Year 2 and Year 6 pupils. The aim of the project was to improve attainment outcomes by increasing the number of children who ate a healthy breakfast. The schools in the project were schools in…

Fire Safety Aspects of Polymeric Materials. Volume 10. Mines and Bunkers

DTIC Science & Technology

1980-01-01

Formaldehyde and Melamine / Formaldehyde Resins The basic chemistry, properties, and applications of urea / formaldehyde and melamine / formaldehyde resins ... Formaldehyde and Melamine Formaldehyde Rosins 71 4.2.3.3 Unsaturated Polyester Resins 71 4.2.3.4 Epoxy Resins 72 4.2.3.5 Furan Resins 72 4.2.3.6 Amine...aldehyde — most frequently formaldehyde . Urea is often used as a modifying agent. The

Exposure to formaldehyde: effects on pulmonary function.

PubMed

Alexandersson, R; Hedenstierna, G; Kolmodin-Hedman, B

1982-01-01

Forty-seven subjects exposed to formaldehyde (mean air concentration 0.45 mg/m3) and 20 unexposed subjects, all of whom were employed at a carpentry shop, were studied with regard to symptoms and pulmonary function. Symptoms involving eyes and throat as well as chest oppression were significantly more common in the exposed subjects than in the unexposed controls. Spirometry and single breath nitrogen washout were normal Monday morning before exposure to formaldehyde. A reduction in forced expiratory volume in 1 sec by an average of 0.2 L (P = .002), percent forced expiratory volume by 2% (P = .04), maximum midexpiratory flow by 0.3 L/sec (P = .04) and an increase in closing volume in percentage of vital capacity by 3.4% (P - .002) were seen after a day of work and exposure to formaldehyde, suggesting bronchoconstriction. Smokers and nonsmokers displayed similar changes in spirometry and nitrogen washout.

The effect of clothing care activities on textile formaldehyde content.

PubMed

Novick, Rachel M; Nelson, Mindy L; McKinley, Meg A; Anderson, Grace L; Keenan, James J

2013-01-01

Textiles are commonly treated with formaldehyde-based residues that may potentially induce allergic contact dermatitis in sensitive individuals. This study examined the initial formaldehyde content in clothing and resulting changes due to care activities. Twenty clothing articles were examined and 17 of them did not have detectable levels of formaldehyde. One shirt contained a formaldehyde concentration of 3172 ppm, and two pairs of pants had formaldehyde concentrations of 1391 ppm and 86 ppm. The two highest results represent formaldehyde levels that are up to 40-fold greater than international textile regulations. The two items with the greatest formaldehyde content were washed and dried in a manner similar to that used by consumers, including hand and machine washing in hot or cold water followed by air or machine drying. The washing and drying procedures reduced formaldehyde levels to between 26 and 72% of untreated controls. Differences in the temperature or type of washing and drying did not result in a clear trend in the subsequent formaldehyde content. In addition, samples were hot ironed, which did not affect the formaldehyde content as significantly. Understanding the formaldehyde content in clothing and its potential reduction through care activities may be useful for manufacturers and formaldehyde-sensitive individuals.

Nature of, and the formaldehyde off-gassing characteristics of, urea-formaldehyde foam insulation (UFFI). Final report to the Canadian Department of Consumer and Corporate Affairs: Product Safety Branch

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gammage, R.B.

1981-07-30

This report is divisible into the following four sections that pertain to the nature, application, and performance of urea-formaldehyde (UF) resins and foams in regard to their formaldehyde outgassing characteristics: elements of basic chemistry that affect hydrolysis and stability; pertinent experimental findings of several studies on the release of formaldehyde from urea-formaldehyde foam insulation (UFFI); studies that model the diffusion of formaldehyde through drywall and correlate the rate of formaldehyde emission with the air exchange rate and the concentration of formaldehyde; and, viability of materials and equipment for the controlled production of UFFI. Results indicate that UFFI is a complexmore » and intrinsically unstable material that releases formaldehyde over long-time periods. Even the best foams available in the US, prepared from low formaldehyde resins according to eight different manufacturers' specifications, have abundant potential for long-term or chronic release of formaldehyde. At the present time it is not possible to state that UFFI is a material whose long-term formaldehyde release characteristics can be adequately controlled or predicted.« less

Adsorption of formaldehyde on graphene and graphyne

NASA Astrophysics Data System (ADS)

Majidi, R.; Karami, A. R.

2014-05-01

The adsorption of formaldehyde on graphene and graphyne was investigated to search high sensitivity sensors for detection of formaldehyde. We have used density functional theory to study the effect of formaldehyde on the electronic properties of graphene and graphyne. It is found that formaldehyde is physisorbed on the graphene and graphyne with small binding energy, large binding distance, and small charge transfer. The calculations also indicate that formaldehyde adsorption modifies the electronic properties of semimetallic graphene, α-graphyne, and β-graphyne and semiconducting γ-graphyne. The graphene and graphyne show semiconducting property in the presence of formaldehyde. The effect of formaldehyde on the electronic properties of graphene and graphyne suggests the potential application of these carbon nanomaterials for formaldehyde detection.

Disinfection of heat-sensitive material by low-temperature steam and formaldehyde

PubMed Central

Alder, V. G.; Brown, Anne M.; Gillespie, W. A.

1966-01-01

Steam under subatmospheric pressure at temperatures below 90°C. rapidly killed nonsporing organisms after air had been removed by a high-vacuum pump. Most bacterial spores were killed but small proportions of the populations were very resistant. The destruction of spores was not logarithmic. The addition of formaldehyde vapour to the steam greatly increased its sterilizing power, with deep penetration into fabrics and destruction of spores. Penetration into wide tubes was good, but was poor in narrow tubes. Most fabrics, plastics, and instruments were unharmed. Low-temperature steam with formaldehyde is probably as efficient a sterilizing agent as ethylene oxide. PMID:5904988

Water-Compatible Polymer Concrete Materials for use in Rapid Repair Systems for Airport Runways

DTIC Science & Technology

1981-03-01

resin systems, resorcinol phenol- formaldehyde (RPF), urea - formaldehyde (UF), melamine - formaldehyde (MF), and furfuryl alcohol (FA), were selected for...type polymer systems. Phenol- formaldehyde (PF), melamine - formaldehyde (MF), urea -formalde- hyde (UF), and furfuryl alcohol (FA) monomers contain OH and...1-1.5) (1-2) Urea - formaldehyde NH2 CONH2 - HCHO Liquid 7150 (1.0) (1.5-2.5) Melamine - formaldehyde NH2 C:NC(NH2 ):NC(N’H2

Environmentally Safe and Effective Processes for Paint Removal

DTIC Science & Technology

1995-04-01

Urea Formaldehyde 3.5 1.5 Type III Melamine Formaldehyde 4.0 1.5 Type IV Phenol Formaldehyde 3.5 1.5...Polyester 3.0 34 - 42 1.04 - 1.46 Type II Urea Formaldehyde 3.5 54 - 62 1.47- 1.54 Type III Melamine Formaldehyde 4.0 64- 72 1.47- 1.52 Type IV Phenol... Melamine Formaldehyde electronics industry and to remove coatings from fibreglass and composite materials. Melamine formaldehyde resin is produced

Effect of temperature and humidity on formaldehyde emissions in temporary housing units.

PubMed

Parthasarathy, Srinandini; Maddalena, Randy L; Russell, Marion L; Apte, Michael G

2011-06-01

The effect of temperature and humidity on formaldehyde emissions from samples collected from temporary housing units (THUs) was studied. The THUs were supplied by the U.S. Federal Emergency Management Administration (FEMA) to families that lost their homes in Louisiana and Mississippi during the Hurricane Katrina and Rita disasters. On the basis of a previous study, four of the composite wood surface materials that dominated contributions to indoor formaldehyde were selected to analyze the effects of temperature and humidity on the emission factors. Humidity equilibration experiments were carried out on two of the samples to determine how long the samples take to equilibrate with the surrounding environmental conditions. Small chamber experiments were then conducted to measure emission factors for the four surface materials at various temperature and humidity conditions. The samples were analyzed for formaldehyde via high-performance liquid chromatography. The experiments showed that increases in temperature or humidity contributed to an increase in emission factors. A linear regression model was built using the natural log of the percent relative humidity (RH) and inverse of temperature (in K) as independent variables and the natural log of emission factors as the dependent variable. The coefficients for the inverse of temperature and log RH with log emission factor were found to be statistically significant for all of the samples at the 95% confidence level. This study should assist in retrospectively estimating indoor formaldehyde exposure of occupants of THUs.

Abject Magic: Reasoning Madness in Justine Larbalestier's "Magic or Madness" Trilogy

ERIC Educational Resources Information Center

Potter, Troy

2013-01-01

This paper explores the representation of magic and madness in Justine Larbalestier's "Magic or Madness" trilogy (2005-2007). Throughout the series, magic is constructed as an abject and disabling force that threatens to disable magic-wielders, either through madness or death. Despite being represented as a ubiquitous force, the…

Origins of magic: review of genetic and epigenetic effects.

PubMed

Ramagopalan, Sreeram V; Knight, Marian; Ebers, George C; Knight, Julian C

2007-12-22

To assess the evidence for a genetic basis to magic. Literature review. Harry Potter novels of J K Rowling. Muggles, witches, wizards, and squibs. Limited. Family and twin studies, magical ability, and specific magical skills. Magic shows strong evidence of heritability, with familial aggregation and concordance in twins. Evidence suggests magical ability to be a quantitative trait. Specific magical skills, notably being able to speak to snakes, predict the future, and change hair colour, all seem heritable. A multilocus model with a dominant gene for magic might exist, controlled epistatically by one or more loci, possibly recessive in nature. Magical enhancers regulating gene expressionmay be involved, combined with mutations at specific genes implicated in speech and hair colour such as FOXP2 and MCR1.

[Features of dyslipidemia development and insulin resistance in female workers engaged in methanol and formaldehyde production].

PubMed

Taranenko, L A

2013-01-01

The article covers data on analyzing occupational risk of carbohydrate and lipid metabolism in female workers exosed to methanol and formaldehyde. Findings are that increased contents of the studied chemicals in the air of workplace cause more probable dyslipidemia, insuline resistence in peri-menopausal female workers, these disorders have reliable correlation with occupation.

Accelerated cure of phenol-formaldehyde by the addition of cure accelerators : studies with model compounds

Treesearch

Linda F. Lorenz; Anthony C. Conner

2000-01-01

Fast curing phenol-formaldehyde (PF) resins could potentially allow wood to be bonded at higher moisture contents and at lower press temperatures than those currently used commercially. Recent reports in the literature have shown that the addition of esters, lactones, or organic carbonates increased the curing rate of PF resins. Several mechanisms have been proposed to...

The Magic of Balanced Groups: Educational Applications of Magic Squares

ERIC Educational Resources Information Center

Bosse, Michael J.; Nandakumar, N. R.; Ore, Melanie L.

2007-01-01

This paper provides students with many interesting observations regarding the nature of magic squares, magic rectangles, and quasi-magic squares and provides tools for teachers to group students into ability-balanced cooperative learning groups.

Formaldehyde emissions from ULEF- and NAF-bonded commercial hardwood plywood as influenced by temperature and relative humidity

Treesearch

Charles R. Frihart; James M. Wescott; Michael J. Birkeland; Kyle M. Gonner

2010-01-01

It is well documented in the literature that temperature and humidity can influence formaldehyde emissions from composite panels that are produced using urea-formaldehyde (UF) adhesives. This work investigates the effect of temperature and humidity on newer, ultra-low emitting formaldehyde urea formaldehyde (ULEF-UF) and no-added formaldehyde (NAF) adhesives. A...

The methods of formaldehyde emission testing of engine: A review

NASA Astrophysics Data System (ADS)

Zhang, Chunhui; Geng, Peng; Cao, Erming; Wei, Lijiang

2015-12-01

A number of measurements have been provided to detect formaldehyde in the atmosphere, but there are no clear unified standards in engine exhaust. Nowadays, formaldehyde, an unregulated emission from methanol engine, has been attracting increasing attention by researchers. This paper presents the detection techniques for formaldehyde emitted from the engines applied in recent market, introducing the approaches in terms of unregulated emission tests of formaldehyde, which involved gas chromatography, liquid chromatography, chromatography-mass spectrometry, chromatography-spectrum, Fourier infrared spectroscopy and spectrophotometry. The author also introduces the comparison regarding to the advantages of the existing detection techniques based on the principle, to compare with engine exhaust sampling method, the treatment in advance of detection, obtaining approaches accessing to the qualitative and quantitative analysis of chromatograms or spectra. The accuratest result obtained was chromatography though it cannot be used continuously. It also can be utilized to develop high requirements of emissions and other regulations. Fourier infrared spectroscopy has the advantage of continuous detection for a variety of unregulated emissions and can be applied to the bench in variable condition. However, its accuracy is not as good as chromatography. As the conclusion, a detection technique is chosen based on different requirements.

Expertise among professional magicians: an interview study.

PubMed

Rissanen, Olli; Pitkänen, Petteri; Juvonen, Antti; Kuhn, Gustav; Hakkarainen, Kai

2014-01-01

The purpose of the present investigation was to analyse interviews of highly regarded Finnish magicians. Social network analysis (N = 120) was used to identify Finland's most highly regarded magicians (N = 16). The selected participants' careers in professional magic and various aspects of their professional conduct were examined by relying on semi-structured interviews. The results revealed that cultivation of professional level competence in magic usually requires an extensive period of time compared with other domains of expertise. Magic is a unique performing art and it differs from other professions focusing on deceiving the audience. A distinctive feature of magical expertise is that the process takes place entirely through informal training supported by communities of magical practitioners. Three interrelated aspects of magical activity were distinguished: magic tricks, performance, and audience. Although magic tricks constitute a central aspect of magic activity, the participants did not talk about their tricks extensively; this is in accordance with the secretive nature of magic culture. The interviews revealed that a core aspect of the magicians' activity is performance in front of an audience that repeatedly validates competence cultivated through years of practice. The interviewees reported investing a great deal of effort in planning, orchestrating, and reflecting on their performances. Close interaction with the audience plays an important role in most interviewees' activity. Many participants put a great deal of effort in developing novel magic tricks. It is common to borrow magic effects from fellow magicians and develop novel methods of implementation. Because magic tricks or programs are not copyrighted, many interviewees considered "stealing" an unacceptable and unethical aspect of magical activity. The interviewees highlighted the importance of personality and charisma in the successful pursuit of magic activity.

Expertise among professional magicians: an interview study

PubMed Central

Rissanen, Olli; Pitkänen, Petteri; Juvonen, Antti; Kuhn, Gustav; Hakkarainen, Kai

2014-01-01

The purpose of the present investigation was to analyse interviews of highly regarded Finnish magicians. Social network analysis (N = 120) was used to identify Finland's most highly regarded magicians (N = 16). The selected participants' careers in professional magic and various aspects of their professional conduct were examined by relying on semi-structured interviews. The results revealed that cultivation of professional level competence in magic usually requires an extensive period of time compared with other domains of expertise. Magic is a unique performing art and it differs from other professions focusing on deceiving the audience. A distinctive feature of magical expertise is that the process takes place entirely through informal training supported by communities of magical practitioners. Three interrelated aspects of magical activity were distinguished: magic tricks, performance, and audience. Although magic tricks constitute a central aspect of magic activity, the participants did not talk about their tricks extensively; this is in accordance with the secretive nature of magic culture. The interviews revealed that a core aspect of the magicians' activity is performance in front of an audience that repeatedly validates competence cultivated through years of practice. The interviewees reported investing a great deal of effort in planning, orchestrating, and reflecting on their performances. Close interaction with the audience plays an important role in most interviewees' activity. Many participants put a great deal of effort in developing novel magic tricks. It is common to borrow magic effects from fellow magicians and develop novel methods of implementation. Because magic tricks or programs are not copyrighted, many interviewees considered “stealing” an unacceptable and unethical aspect of magical activity. The interviewees highlighted the importance of personality and charisma in the successful pursuit of magic activity. PMID:25566156

Reproductive and Developmental Toxicity of Formaldehyde: A Systematic Review

PubMed Central

Duong, Anh; Steinmaus, Craig; McHale, Cliona M.; Vaughan, Charles P.; Zhang, Luoping

2011-01-01

Formaldehyde, the recently classified carcinogen and ubiquitous environmental contaminant, has long been suspected of causing adverse reproductive and developmental effects, but previous reviews were inconclusive, due in part, to limitations in the design of many of the human population studies. In the current review, we systematically evaluated evidence of an association between formaldehyde exposure and adverse reproductive and developmental effects, in human populations and in vivo animal studies, in the peer-reviewed literature. The mostly retrospective human studies provided evidence of an association of maternal exposure with adverse reproductive and developmental effects. Further assessment of this association by meta-analysis revealed an increased risk of spontaneous abortion (1.76, 95% CI 1.20–2.59, p=0.002) and of all adverse pregnancy outcomes combined (1.54, 95% CI 1.27–1.88, p<0.001), in formaldehyde-exposed women, although differential recall, selection bias, or confounding cannot be ruled out. Evaluation of the animal studies including all routes of exposure, doses and dosing regimens studied, suggested positive associations between formaldehyde exposure and reproductive toxicity, mostly in males. Potential mechanisms underlying formaldehyde-induced reproductive and developmental toxicities, including chromosome and DNA damage (genotoxicity), oxidative stress, altered level and/or function of enzymes, hormones and proteins, apoptosis, toxicogenomic and epigenomic effects (such as DNA methylation), were identified. To clarify these associations, well-designed molecular epidemiologic studies, that include quantitative exposure assessment and diminish confounding factors, should examine both reproductive and developmental outcomes associated with exposure in males and females. Together with mechanistic and animal studies, this will allow us to better understand the systemic effect of formaldehyde exposure. PMID:21787879

Sporostatic and sporocidal properties of aqueous formaldehyde.

NASA Technical Reports Server (NTRS)

Trujillo, R.; David, T. J.

1972-01-01

Aqueous formaldehyde is shown to exert both sporostatic and sporocidal effects on Bacillus subtilis spores. The sporostatic effect is a result of the reversible inhibition of spore germination occasioned by aqueous formaldehyde; the sporocidal effect is due to the temperature-dependent inactivation of these spores in aqueous formaldehyde. The physicochemical state of formaldehyde in solution provides a framework with which to interpret both the sporostatic and sporocidal properties of aqueous formaldehyde.

Formaldehyde

EPA Pesticide Factsheets

Information on formaldehyde and the regulation of formaldehyde emissions from composite wood products under the Formaldehyde Standards for Composite Wood Products Act in the Toxic Substances Control Act (TSCA).

Immunoconjugates: Magic Bullets for Cancer Therapy?

NASA Technical Reports Server (NTRS)

Passeri, Daniel R.; Spiegel, Jack

1993-01-01

Conjugating cytotoxic agents to antibodies allows for site-specific delivery of the agent to tumor cells and should provide increased efficacy and reduced non-specific toxicity. These site-specific cytotoxic agents are known as immunoconjugates or 'magic bullets' and have demonstrated great promise as therapeutic agents for cancer and other diseases. The historical developments and future potential of this new approach to cancer therapy are reviewed.

Formaldehyde - An Assessment of its Health Effects.

DTIC Science & Technology

1980-03-01

impregnated with melamine - formaldehyde resin ...1961). Airborne formaldehyde concentrations released from paper treated with urea - formaldehyde or melamine - formaldehyde resin were found to be 0.9-1.6...as preservatives, and in the preparation of vaccines. It is widely used in the manufacture of phenolic, urea , and melamine resins . These materials

78 FR 51696 - Formaldehyde; Third-Party Certification Framework for the Formaldehyde Standards for Composite...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-21

... Formaldehyde; Third-Party Certification Framework for the Formaldehyde Standards for Composite Wood Products..., concerning a third-party certification framework for the formaldehyde standards for composite wood products... INFORMATION CONTACT. List of Subjects in 40 CFR Part 770 Environmental protection, Composite wood products...

Observations of glyoxal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry

NASA Astrophysics Data System (ADS)

Digangi, J. P.; Henry, S. B.; Kammrath, A.; Boyle, E. S.; Kaser, L.; Schnitzhofer, R.; Graus, M.; Turnipseed, A.; Park, J.-H.; Weber, R. J.; Hornbrook, R. S.; Cantrell, C. A.; Maudlin, R. L., III; Kim, S.; Nakashima, Y.; Wolfe, G. M.; Kajii, Y.; Apel, E. C.; Goldstein, A. H.; Guenther, A.; Karl, T.; Hansel, A.; Keutsch, F. N.

2012-02-01

We present simultaneous fast, in-situ measurements of formaldehyde and glyoxal from two rural campaigns, BEARPEX 2009 and BEACHON-ROCS, both located in Pinus Ponderosa forests with emissions dominated by biogenic volatile organic compounds (VOCs). Despite considerable variability in the formaldehyde and glyoxal concentrations, the ratio of glyoxal to formaldehyde, RGF, displayed a very regular diurnal cycle over nearly 2 weeks of measurements. The only deviations in RGF were toward higher values and were the result of a biomass burning event during BEARPEX 2009 and very fresh anthropogenic influence during BEACHON-ROCS. Other rapid changes in glyoxal and formaldehyde concentrations have hardly any affect on RGF and could reflect transitions between low and high NO regimes. The trend of increased RGF from both anthropogenic reactive VOC mixtures and biomass burning compared to biogenic reactive VOC mixtures is robust due to the short timescales over which the observed changes in RGF occurred. Satellite retrievals, which suggest higher RGF for biogenic areas, are in contrast to our observed trends. It remains important to address this discrepancy, especially in view of the importance of satellite retrievals and in-situ measurements for model comparison. In addition, we propose that RGF, together with the absolute concentrations of glyoxal and formaldehyde, represents a useful metric for biogenic or anthropogenic reactive VOC mixtures. In particular, RGF yields information about not simply the VOCs in an airmass, but the VOC processing that directly couples ozone and secondary organic aerosol production.

Evaluation of possible health risk associated with occupational exposure to formaldehyde

NASA Astrophysics Data System (ADS)

Vargova, Maria; Janota, Stanislav; Karelova, Jarmila; Barancokova, Maria; Sulcova, Margita

1993-03-01

Widespread us of formaldehyde in a variety of applications is known to result in appreciable exposure of workers and large segments of the general population. Because of possible genotoxic and immunotoxic effects, we investigated the health condition of people occupationally exposed to formaldehyde in a plant in which woodsplinter materials are manufactured. The concentration of formaldehyde in the workplace was greater than the average and peak concentrations of formaldehyde in Czechoslovakia (0.5 mg/m3 and 1 mg/m3 respectively). Selected parameters of genotoxicity (cytogenetic analysis, nucleolus test) and immunotoxocity (serum immunoglobulin G, A, M; complement C3, C4; alpha-1-anti-trypsine, alpha-2 macroglobulin, ceruloplasmin, transferrin, prealbumin, orosomucoid levels) were determined. The results of the evaluation of mitotic indices and the blastogen transformation point to an effect of the exposure to formaldehyde on r-RNA synthesis inhibition and lymphocyte maturation decrease. The frequency of aberrant cells in the peripheral blood lymphocytes was increased in both, exposed and control group and was above 1.2 - 2% of aberrant cells observed in the normal population in Czechoslovakia. There was no significant differences in the values of natural immunity and specific humoral immunity. Significant differences were observed in the values of mitogen-induced proliferation of lymphocytes between the exposed and the matching and background control groups. These changes are considered to be sensitive indicators of the potential effects on the integrity of a more important immunologic function.

Investigation on formaldehyde release from preservatives in cosmetics.

PubMed

Lv, C; Hou, J; Xie, W; Cheng, H

2015-10-01

To understand formaldehyde residue in cosmetics, an investigation on formaldehyde release from eight preservatives (methenamine - MA, paraformaldehyde - PF, poly(p-toluenesulfonamide-co-formaldehyde) -PTSAF, quaternium-15 - QU, imidazolidinyl urea - IU, diazolidinyl urea - DU, dimethyloldimethyl hydantoin - DMDM and bronopol - BP) under various conditions was performed. The concentration of released formaldehyde was determined by high-performance liquid chromatography with photodiode array detection after derivatization with 2,4-dinitrophenylhydrazine. The amounts of formaldehyde release were in the order of PF > DU > DMDM ≈ QU ≈ IU > MA > BP > PTSAF. The releasing amounts of formaldehyde were the highest in the presence of aqueous matrices for the releasers except QU and IU, and the releasing effect was also relative to pH. More formaldehyde was released with longer storage time and higher temperature. Furthermore, all preservatives in cosmetic matrices released fewer amounts of formaldehyde than in pure aqueous or organic matrices, and the formaldehyde-releasing amounts were also cosmetic specific. Formaldehyde release was dependent on the matrix, pH, time and mainly temperature, and the releasing effect was also cosmetic specific. © 2015 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

Laboratory preparation of DNPH derivatives of carbonyl compounds on Sep-Pak{reg_sign} cartridges for quality assurance purposes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrell, R.M.

1994-12-31

Aldehydes and ketones are receiving increased attention both as hazardous substances and as promoters in the photochemical formation of ozone in the atmosphere. They enter the atmosphere in the exhaust of motor vehicles and other equipment using hydrocarbon and alcohol fuels. Formaldehyde, the most prevalent aldehyde, is widely used as a preservative, a textile-treatment agent, and an intermediate in the manufacture of urea-formaldehyde and phenol-formaldehyde resins. The formaldehyde concentration ranges for several types of environments are presented. Waters Sep-Pak{reg_sign} DNPH-Silica cartridges are convenient, reproducible sampling devices for quantifying aldehydes and ketones in gases, including air. These cartridges trap the compoundsmore » by reacting them with the DNPH, 2,4-Dinitrophenylhydrazine, on the cartridge to form stable hydrazone derivatives. Derivatives are later eluted and analyzed by HPLC. Cartridges spiked in the laboratory are used for quality assurance and instrument performance verification.« less

Forensic Investigation of Formaldehyde in Illicit Products for Hair Treatment by DAD-HPLC: A Case Study.

PubMed

Oiye, Erica N; Ribeiro, Maria Fernanda M; Okumura, Leonardo L; Saczk, Adelir A; Ciancaglini, Pietro; de Oliveira, Marcelo F

2016-07-01

The illegal use of formalin (commercial formaldehyde) in cosmetic products harms the health of individuals exposed to this substance. Over the last years, the commercial availability of these products, especially those containing irregular dosage of formaldehyde, has increased in Brazil. This work analyzes some products for hair treatment available in the Brazilian market and verifies their safety. The adopted analytical methodology involved sample derivatization with 2,4-dinitrophenylhydrazine, followed by high-performance liquid chromatography with ultraviolet detection (UV-VIS) at λ = 365 nm. The limit of quantification is 2.5 × 10 -3% w/w, and the recovery tests were around 93%. Some of the samples contained high and illegal formaldehyde levels ranging from 9% to 19% (w/w) and others presented suitable concentrations of the analyte. On the basis of the results, this work discusses the efficiency and practicality of this analytical method for forensic purposes. © 2016 American Academy of Forensic Sciences.

A Reagentless Amperometric Formaldehyde-Selective Chemosensor Based on Platinized Gold Electrodes

PubMed Central

Demkiv, Olha; Smutok, Oleh; Gonchar, Mykhailo; Nisnevitch, Marina

2017-01-01

Fabrication and characterization of a new amperometric chemosensor for accurate formaldehyde analysis based on platinized gold electrodes is described. The platinization process was performed electrochemically on the surface of 4 mm gold planar electrodes by both electrolysis and cyclic voltamperometry. The produced electrodes were characterized using scanning electron microscopy and X-ray spectral analysis. Using a low working potential (0.0 V vs. Ag/AgCl) enabled an essential increase in the chemosensor’s selectivity for the target analyte. The sensitivity of the best chemosensor prototype to formaldehyde is uniquely high (28180 A·M−1·m−2) with a detection limit of 0.05 mM. The chemosensor remained stable over a one-year storage period. The formaldehye-selective chemosensor was tested on samples of commercial preparations. A high correlation was demonstrated between the results obtained by the proposed chemosensor, chemical and enzymatic methods (R = 0.998). The developed formaldehyde-selective amperometric chemosensor is very promising for use in industry and research, as well as for environmental control. PMID:28772868

A Reagentless Amperometric Formaldehyde-Selective Chemosensor Based on Platinized Gold Electrodes.

PubMed

Demkiv, Olha; Smutok, Oleh; Gonchar, Mykhailo; Nisnevitch, Marina

2017-05-06

Fabrication and characterization of a new amperometric chemosensor for accurate formaldehyde analysis based on platinized gold electrodes is described. The platinization process was performed electrochemically on the surface of 4 mm gold planar electrodes by both electrolysis and cyclic voltamperometry. The produced electrodes were characterized using scanning electron microscopy and X-ray spectral analysis. Using a low working potential (0.0 V vs. Ag/AgCl) enabled an essential increase in the chemosensor's selectivity for the target analyte. The sensitivity of the best chemosensor prototype to formaldehyde is uniquely high (28180 A·M -1 ·m -2 ) with a detection limit of 0.05 mM. The chemosensor remained stable over a one-year storage period. The formaldehye-selective chemosensor was tested on samples of commercial preparations. A high correlation was demonstrated between the results obtained by the proposed chemosensor, chemical and enzymatic methods ( R = 0.998). The developed formaldehyde-selective amperometric chemosensor is very promising for use in industry and research, as well as for environmental control.

Effects of creatine supplementation along with resistance training on urinary formaldehyde and serum enzymes in wrestlers.

PubMed

Nasseri, Azadeh; Jafari, Afshar

2016-04-01

Formaldehyde is a cytotoxic agent produced from creatine through a metabolic pathway, and in this regard, it has been claimed that creatine supplementation could be cytotoxic. Even though the cytotoxic effects of creatine supplementation have been widely studied, yet little is known about how resistance training can alter these toxic effects. This study aimed to determine the effects of short-term creatine supplementation plus resistance training on the level of urinary formaldehyde and concentrations of serum enzymes in young male wrestlers. In a double-blind design twenty-one subjects were randomized into creatine supplementation (Cr), creatine supplementation plus resistance training (Cr + T) and placebo plus resistance training (Pl + T) groups. Participants ingested creatine (0.3 g/kg/day) or placebo for 7 days. The training protocol consisted of 3 sessions in one week, each session including three sets of 6-9 repetitions at 80-85% of one-repetition maximum for whole-body exercise. Urine and blood samples were collected at baseline and at the end of the supplementation. Creatine supplementation significantly increased the excretion rate of urinary formaldehyde in the Cr and Cr + T groups by 63.4% and 30.4%, respectively (P<0.05), indicating that resistance training could partially lower this rate by 17.7%. No significant differences were detected in the levels of serum enzymes across time and groups (P>0.05). These findings indicate that resistance training may lower the increase of urinary formaldehyde excretion induced by creatine supplementation, suggesting that creatine consumption could be relatively less toxic when combined with resistance training.

Determination of formaldehyde levels in 100 furniture workshops in Ankara.

PubMed

Vaizoğlu, Songül Acar; Aycan, Sefer; Akin, Levent; Koçdor, Pelin; Pamukçu, Gül; Muhsinoğlu, Orkun; Ozer, Feyza; Evci, E Didem; Güler, Cağatay

2005-10-01

One of the airborne pollutants in wood products industry is formaldehyde, which may pose some health effects. Therefore this study is conducted to determine formaldehyde levels in 100 furniture-manufacturing workshops in Ankara and also to determine the symptoms, which may be related with formaldehyde exposure among the workers. Indoor formaldehyde levels ranged from 0.02 ppm to 2.22 ppm with a mean of 0.6 +/- 0.3 ppm. Outdoor formaldehyde levels also ranged from 0.0 ppm to 0.08 ppm with a mean of 0.03 +/- 0.03 ppm. Formaldehyde levels were higher in workplaces located at basement than in workplaces located at or above ground level (p < 0.01). An association was found between indoor formaldehyde levels and the types of fuel used (p < 0.05). The levels were higher in workplaces where only sawdust was used for heating, than in workplaces where wood, coal, and sawdust are used (p = 0.02). An association was found between runny nose and indoor formaldehyde levels (p = 0.03). Formaldehyde levels were lower in workplaces where employees had no symptoms than in those where employees had 4 or more symptoms (p = 0.02). Of 229 employees 57 subjects (24.9%) work under the formaldehyde levels of 0.75 ppm and above. Thus, approximately one fourth of the employees in workplaces are working in environments with formaldehyde levels exceeding those permitted by Occupational Safety and Health Administration (OSHA). The employees working in small-scale furniture workshops are at risk of formaldehyde exposure. Measures, such as improved ventilation, have to be taken in these workplaces, in order to decrease the formaldehyde levels.

Performance of the MAGIC telescopes under moonlight

NASA Astrophysics Data System (ADS)

Ahnen, M. L.; Ansoldi, S.; Antonelli, L. A.; Arcaro, C.; Babić, A.; Banerjee, B.; Bangale, P.; Barres de Almeida, U.; Barrio, J. A.; Becerra González, J.; Bednarek, W.; Bernardini, E.; Berti, A.; Bhattacharyya, W.; Biasuzzi, B.; Biland, A.; Blanch, O.; Bonnefoy, S.; Bonnoli, G.; Carosi, R.; Carosi, A.; Chatterjee, A.; Colin, P.; Colombo, E.; Contreras, J. L.; Cortina, J.; Covino, S.; Cumani, P.; Da Vela, P.; Dazzi, F.; De Angelis, A.; De Lotto, B.; de Oña Wilhelmi, E.; Di Pierro, F.; Doert, M.; Domínguez, A.; Dominis Prester, D.; Dorner, D.; Doro, M.; Einecke, S.; Eisenacher Glawion, D.; Elsaesser, D.; Engelkemeier, M.; Fallah Ramazani, V.; Fernández-Barral, A.; Fidalgo, D.; Fonseca, M. V.; Font, L.; Fruck, C.; Galindo, D.; García López, R. J.; Garczarczyk, M.; Gaug, M.; Giammaria, P.; Godinović, N.; Gora, D.; Griffiths, S.; Guberman, D.; Hadasch, D.; Hahn, A.; Hassan, T.; Hayashida, M.; Herrera, J.; Hose, J.; Hrupec, D.; Hughes, G.; Ishio, K.; Konno, Y.; Kubo, H.; Kushida, J.; Kuveždić, D.; Lelas, D.; Lindfors, E.; Lombardi, S.; Longo, F.; López, M.; Maggio, C.; Majumdar, P.; Makariev, M.; Maneva, G.; Manganaro, M.; Mannheim, K.; Maraschi, L.; Mariotti, M.; Martínez, M.; Mazin, D.; Menzel, U.; Minev, M.; Mirzoyan, R.; Moralejo, A.; Moreno, V.; Moretti, E.; Neustroev, V.; Niedzwiecki, A.; Nievas Rosillo, M.; Nilsson, K.; Ninci, D.; Nishijima, K.; Noda, K.; Nogués, L.; Paiano, S.; Palacio, J.; Paneque, D.; Paoletti, R.; Paredes, J. M.; Paredes-Fortuny, X.; Pedaletti, G.; Peresano, M.; Perri, L.; Persic, M.; Prada Moroni, P. G.; Prandini, E.; Puljak, I.; Garcia, J. R.; Reichardt, I.; Rhode, W.; Ribó, M.; Rico, J.; Rugliancich, A.; Saito, T.; Satalecka, K.; Schroeder, S.; Schweizer, T.; Sillanpää, A.; Sitarek, J.; Šnidarić, I.; Sobczynska, D.; Stamerra, A.; Strzys, M.; Surić, T.; Takalo, L.; Tavecchio, F.; Temnikov, P.; Terzić, T.; Tescaro, D.; Teshima, M.; Torres, D. F.; Torres-Albà, N.; Treves, A.; Vanzo, G.; Vazquez Acosta, M.; Vovk, I.; Ward, J. E.; Will, M.; Zarić, D.

2017-09-01

MAGIC, a system of two imaging atmospheric Cherenkov telescopes, achieves its best performance under dark conditions, i.e. in absence of moonlight or twilight. Since operating the telescopes only during dark time would severely limit the duty cycle, observations are also performed when the Moon is present in the sky. Here we develop a dedicated Moon-adapted analysis to characterize the performance of MAGIC under moonlight. We evaluate energy threshold, angular resolution and sensitivity of MAGIC under different background light levels, based on Crab Nebula observations and tuned Monte Carlo simulations. This study includes observations taken under non-standard hardware configurations, such as reducing the camera photomultiplier tubes gain by a factor ∼1.7 (reduced HV settings) with respect to standard settings (nominal HV) or using UV-pass filters to strongly reduce the amount of moonlight reaching the cameras of the telescopes. The Crab Nebula spectrum is correctly reconstructed in all the studied illumination levels, that reach up to 30 times brighter than under dark conditions. The main effect of moonlight is an increase in the analysis energy threshold and in the systematic uncertainties on the flux normalization. The sensitivity degradation is constrained to be below 10%, within 15-30% and between 60 and 80% for nominal HV, reduced HV and UV-pass filter observations, respectively. No worsening of the angular resolution was found. Thanks to observations during moonlight, the maximal duty cycle of MAGIC can be increased from ∼18%, under dark nights only, to up to ∼40% in total with only moderate performance degradation.

A Tale of Two Morphs: Modeling Pollen Transfer, Magic Traits, and Reproductive Isolation in Parapatry

PubMed Central

Haller, Benjamin C.; de Vos, Jurriaan M.; Keller, Barbara; Hendry, Andrew P.; Conti, Elena

2014-01-01

The evolution of the flower is commonly thought to have spurred angiosperm diversification. Similarly, particular floral traits might have promoted diversification within specific angiosperm clades. We hypothesize that traits promoting the precise positional transfer of pollen between flowers might promote diversification. In particular, precise pollen transfer might produce partial reproductive isolation that facilitates adaptive divergence between parapatric populations differing in their reproductive-organ positions. We investigate this hypothesis with an individual-based model of pollen transfer dynamics associated with heterostyly, a floral syndrome that depends on precise pollen transfer. Our model shows that precise pollen transfer can cause sexual selection leading to divergence in reproductive-organ positions between populations served by different pollinators, pleiotropically causing an increase in reproductive isolation through a “magic trait” mechanism. Furthermore, this increased reproductive isolation facilitates adaptive divergence between the populations in an unlinked, ecologically selected trait. In a different pollination scenario, however, precise pollen transfer causes a decrease in adaptive divergence by promoting asymmetric gene flow. Our results highlight the idea that magic traits are not “magic” in isolation; in particular, the effect size of magic traits in speciation depends on the external environment, and also on other traits that modify the strength of the magic trait's influence on non-random mating. Overall, we show that the evolutionary consequences of pollen transfer dynamics can depend strongly on the available pollinator fauna and on the morphological fit between flowers and pollinators. Furthermore, our results illustrate the potential importance of even weak reproductive isolating barriers in facilitating adaptive divergence. PMID:25211280

Application of a Resource Theory for Magic States to Fault-Tolerant Quantum Computing.

PubMed

Howard, Mark; Campbell, Earl

2017-03-03

Motivated by their necessity for most fault-tolerant quantum computation schemes, we formulate a resource theory for magic states. First, we show that robustness of magic is a well-behaved magic monotone that operationally quantifies the classical simulation overhead for a Gottesman-Knill-type scheme using ancillary magic states. Our framework subsequently finds immediate application in the task of synthesizing non-Clifford gates using magic states. When magic states are interspersed with Clifford gates, Pauli measurements, and stabilizer ancillas-the most general synthesis scenario-then the class of synthesizable unitaries is hard to characterize. Our techniques can place nontrivial lower bounds on the number of magic states required for implementing a given target unitary. Guided by these results, we have found new and optimal examples of such synthesis.

Effect of catalyst calcination temperature in the visible light photocatalytic oxidation of gaseous formaldehyde by multi-element doped titanium dioxide.

PubMed

de Luna, Mark Daniel G; Laciste, Maricris T; Tolosa, Nolan C; Lu, Ming-Chun

2018-03-20

The present study investigates the influence of calcination temperature on the properties and photoactivity of multi-element doped TiO 2 . The photocatalysts were prepared by incorporating silver (Ag), fluorine (F), nitrogen (N), and tungsten (W) into the TiO 2 structure via the sol-gel method. Spectroscopic techniques were used to elucidate the correlation between the structural and optical properties of the doped photocatalyst and its photoactivity. XRD results showed that the mean crystallite size increased for undoped photocatalysts and decreased for the doped photocatalysts when calcination was done at higher temperatures. UV-Vis spectra showed that the absorption cut-off wavelength shifted towards the visible light region for the as-synthesized photocatalysts and band gap narrowing was attributed to multi-element doping and calcination. FTIR spectra results showed the shifting of OH-bending absorption bands towards increasing wave numbers. The activity of the photocatalysts was evaluated in terms of gaseous formaldehyde removal under visible light irradiation. The highest photocatalytic removal of gaseous formaldehyde was found at 88%. The study confirms the effectiveness of multi-element doped TiO 2 to remove gaseous formaldehyde in air by visible light photocatalysis and the results have a lot of potential to extend the application to other organic air contaminants.

Plastic Media Blasting Waste Treatments

DTIC Science & Technology

1988-07-01

melamine formaldehyde resin with a Mohr hardness of 4.0. Urea and melamine formaldehydes are highly crosslinked condensation polymers. These two...with either melamine formaldehyde or urea formaldehyde resins , which contain no chlorine. Wet scrubbers followed by demisters are added to remove any...latter problem. NARF chemists believe that methacrylate dust will be more explosive than dust from melamine or urea formaldehyde

Formaldehyde emission and high-temperature stability of cured urea-formaldehyde resins

Treesearch

Shin-ichiro Tohmura; Chung-Yun Hse; Mitsuo Higuchi

2000-01-01

A test method for measuring formaldehyde from urea-formaldehyde (UF) resins at high temperature was developed and used to assess the influence of the reaction pH on the formaldehyde emission and heat stability of the cured resins. Additionally, solid-state 13C CP/MAS nuclear magnetic resonance (NMR) techniques were used to investigate the...

Analysis on cocondensation of melamine and urea through carbon 13 enriched formaldehyde with carbon 13 nuclear magnetic resonance spectroscopy

Treesearch

Bunichiro Tomita; Chung-Yun Hse

1995-01-01

The urea-formaldehyde (UF) resins, melamine-formaldehyde (MF) resins, and melamine-urea-formaldehyde (MUF) cocondensed resins were synthesized using the labeling method of 13C enriched formaldehyde udner neutral conditions and their 13C-NMR (nuclear magnetic resonance) spectra were analyzed. The remarkable down-field shifts...

Analyses of cocondensation of melamine and urea through carbon 13 enriched formaldehyde with carbon 13 nuclear magnetic resonance spectroscopy

Treesearch

Tomita Bunchiro; Chung-Yun Hse

1995-01-01

The urea-formaldehyde (UF) resins, melamine-formaldehyde (MF) resins, and melamine-urea-formaldehyde (MUF) cocondensed resins were synthesized using the labeling method with 13C enriched formaldehyde unde neutral conditions and their 13C-NMR (nuclear magnetic resonance) spectra were analyzed. The remarkable down-field...

Magic star puzzle for educational mathematics

NASA Astrophysics Data System (ADS)

Gan, Yee Siang; Fong, Wan Heng; Sarmin, Nor Haniza

2013-04-01

One of the interesting fields in recreational mathematics is the magic number arrangement. There are different kinds of arrays in the arrangement for a group of numbers. In particular, one of the arrays in magic number arrangement is called magic star. In fact, magic star involves combinatorics that contributes to geometrical analysis and number theory. Hence, magic star is suitable to be introduced as educational mathematics to cultivate interest in different area of mathematics. To obtain the solutions of normal magic stars of order six, the possible sets of numbers for every line in a magic star have been considered. Previously, the calculation for obtaining the solutions has been done manually which is time-consuming. Therefore, a programming code to generate all the fundamental solutions for normal magic star of order six without including the properties of rotation and reflection has been done. In this puzzle, a magic star puzzle is created by using Matlab software, which enables a user to verify the entries for the cells of magic star of order six. Moreover, it is also user-friendly as it provides interactive commands on the inputs given by the user, which enables the user to detect the incorrect inputs. In addition, user can also choose to view all the fundamental solutions as generated by the programming code.

77 FR 58416 - Large Scale Networking (LSN); Middleware and Grid Interagency Coordination (MAGIC) Team

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-20

... Coordination (MAGIC) Team AGENCY: The Networking and Information Technology Research and Development (NITRD.... Dates/Location: The MAGIC Team meetings are held on the first Wednesday of each month, 2:00-4:00pm, at... participation is available for each meeting. Please reference the MAGIC Team Web site for updates. Magic Web...

78 FR 70076 - Large Scale Networking (LSN)-Middleware and Grid Interagency Coordination (MAGIC) Team

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-22

... Coordination (MAGIC) Team AGENCY: The Networking and Information Technology Research and Development (NITRD... MAGIC Team meetings are held on the first Wednesday of each month, 2:00-4:00 p.m., at the National... for each meeting. Please reference the MAGIC Team Web site for updates. Magic Web site: The agendas...

Thermal Properties of Capparis Decidua (ker) Fiber Reinforced Phenol Formaldehyde Composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, G. P.; Mangal, Ravindra; Bhojak, N.

2010-06-29

Simultaneous measurement of effective thermal conductivity ({lambda}), effective thermal diffusivity ({kappa}) and specific heat of Ker fiber reinforced phenol formaldehyde composites have been studied by transient plane source (TPS) technique. The samples of different weight percentage typically (5, 10, 15, 20 and 25%) have been taken. It is found that values of effective thermal conductivity and effective thermal diffusivity of the composites decrease, as compared to pure phenol formaldehyde, as the fraction of fiber loading increases. Experimental data is fitted on Y. Agari model. Values of thermal conductivity of composites are calculated with two models (Rayleigh, Maxwell and Meredith-Tobias model).more » Good agreement between theoretical and experimental result has been found.« less

CO2-based hydrogen storage - Hydrogen generation from formaldehyde/water

NASA Astrophysics Data System (ADS)

Trincado, Monica; Grützmacher, Hansjörg; Prechtl, Martin H. G.

2018-04-01

Formaldehyde (CH2O) is the simplest and most significant industrially produced aldehyde. The global demand is about 30 megatons annually. Industrially it is produced by oxidation of methanol under energy intensive conditions. More recently, new fields of application for the use of formaldehyde and its derivatives as, i.e. cross-linker for resins or disinfectant, have been suggested. Dialkoxymethane has been envisioned as a combustion fuel for conventional engines or aqueous formaldehyde and paraformaldehyde may act as a liquid organic hydrogen carrier molecule (LOHC) for hydrogen generation to be used for hydrogen fuel cells. For the realization of these processes, it requires less energy-intensive technologies for the synthesis of formaldehyde. This overview summarizes the recent developments in low-temperature reductive synthesis of formaldehyde and its derivatives and low-temperature formaldehyde reforming. These aspects are important for the future demands on modern societies' energy management, in the form of a methanol and hydrogen economy, and the required formaldehyde feedstock for the manufacture of many formaldehyde-based daily products.

Report of the Federal Panel on Formaldehyde.

PubMed Central

1982-01-01

The Federal Panel on Formaldehyde concluded that definitive experiments exist which demonstrate the mutagenicity and carcinogenicity of formaldehyde under laboratory conditions. Formaldehyde induces both gene mutations and chromosomal aberrations in a variety of test systems. Inhalation of formaldehyde causes cancer of the nose in rats. The concentrations of formaldehyde in inhaled air that caused nasal cancer in Fisher 344 rats are within the same order of magnitude as those to which humans may be exposed. The data presently available do not permit a direct assessment of the carcinogenicity of formaldehyde to man. Epidemiologic studies on exposed human populations are in progress and may further clarify the situation. Other experimental and human studies on toxic effects such as teratogenicity and reproductive disorders are as yet inadequate for a health risk assessment. The CIIT 24 month study on animal carcinogenicity has not yet been completely evaluated. Additional data are expected on the effects of prolonged exposure to lower doses of formaldehyde and on the possible carcinogenicity of formaldehyde in the mouse. The panel recommends that, for a comprehensive health risk assessment, further experiments be conducted on the effects of other modes of exposure (ingestion and skin penetration), the effects in humans, and on the pharmacokinetics of formaldehyde in man and animals and the possible role for formaldehyde in reproductive and chronic respiratory disorders. It is the conclusion of the panel that formaldehyde should be presumed to pose a carcinogenic risk to humans. PMID:6977445

Heat stability of cured urea-formaldehyde resins by measuring formaldehyde emission

Treesearch

Shin-ichiro Tohmura; Chung-Yun Hse; Mitsuo Higuchi

1999-01-01

A test method for measuring formaldehyde from urea-formaldehyde (UF) resins at high tempera­tures was developed and used to assess the influence of the reaction pH at synthesis on the formaldehyde emission during cure and heat stability of the cured resins without water. Additionally, 13C-CP/MAS solid-state nuclear magnetic resonance (NMR)...

New formaldehyde base disinfectants.

NASA Technical Reports Server (NTRS)

Trujillo, R.; Lindell, K. F.

1973-01-01

Preparations of formaldehyde in various organic liquids - ethylene glycol, glycerol, and propylene glycol - serve as effective disinfectants towards microbial vegetative cells and spores. This disinfection is a temperature-dependent process and is manifest when these formaldehyde base disinfectants are dissolved in water. The irritating vapors associated with formaldehyde disinfection are not present in either of these new formaldehyde base disinfectants or in aqueous solutions of them.

[Magical thinking in healthy people and in schizophrenia].

PubMed

Jarosz, M

1996-01-01

Different conditions of magical thinking have been analyzed. A formation of the proportion "realistic thinking - magical thinking" in paranoid schizophrenia has been discussed and the characteristic features of magical thinking in schizophrenia have been indicated.

Changes in the structure of nuclei between the magic neutron numbers 50 and 82 as indicated by a rotating-cluster analysis of the energy values of the first 2+ excited states of isotopes of cadmium, tin, and tellurium

PubMed Central

Pauling, Linus

1981-01-01

Values of R, the radius of rotation of the rotating cluster, are calculated from the observed values of the energy of the lowest 2+ states of the even isotopes of 48Cd, 50Sn, and 52Te with the assumption that the cluster is α, p2, and α, respectively. R shows a maximum at ≈N = 58, a minimum at ≈N = 62, and a second maximum at ≈N = 70. The increase to the first maximum is interpreted as resulting from the overcrowding of spherons (alphas and tritons) in the mantle (outer layer) of the nuclei, causing the cluster to change from rotating in the mantle to skimming over its surface; the decrease to the minimum results from the addition of three dineutrons to the core, expanding the mantle and permitting the rotating cluster to begin to drop back into it; and the increase to the second maximum results from the overcrowding of the larger mantle surrounding the core containing the semi-magic number 14 of neutrons rather than the magic number 8 for N = 50. The decrease after the second maximum results from the further increase in the number of core neutrons to 20, corresponding to the magic number 82. Some additional evidence for the change to an intermediate structure between N = 50 and N = 82 is also discussed. PMID:16593084

Formaldehyde in Insulation: Villain or Innocent Bystander?

PubMed Central

Lees, R. E. M.

1983-01-01

When urea formaldehyde foam insulation (UFFI) deteriorates, it produces an off-gas mixture whose major constituent is formaldehyde. Most investigative studies of UFFI have concentrated on formaldehyde. Health concerns fall into three groups: irritant characteristics, allergenic capabilities and potential carcinogenicity. Except for the first of these, formaldehyde's hazard potential is not clear. The extent to which formaldehyde may be responsible for UFFI's evil reputation is explored in this paper but the degree to which either substance is a real threat to health still appears to open to debate. PMID:21283296

The Effectors and Sensory Sites of Formaldehyde-responsive Regulator FrmR and Metal-sensing Variant *

PubMed Central

Osman, Deenah; Piergentili, Cecilia; Chen, Junjun; Sayer, Lucy N.; Usón, Isabel; Huggins, Thomas G.; Robinson, Nigel J.; Pohl, Ehmke

2016-01-01

The DUF156 family of DNA-binding transcriptional regulators includes metal sensors that respond to cobalt and/or nickel (RcnR, InrS) or copper (CsoR) plus CstR, which responds to persulfide, and formaldehyde-responsive FrmR. Unexpectedly, the allosteric mechanism of FrmR from Salmonella enterica serovar Typhimurium is triggered by metals in vitro, and variant FrmRE64H gains responsiveness to Zn(II) and cobalt in vivo. Here we establish that the allosteric mechanism of FrmR is triggered directly by formaldehyde in vitro. Sensitivity to formaldehyde requires a cysteine (Cys35 in FrmR) conserved in all DUF156 proteins. A crystal structure of metal- and formaldehyde-sensing FrmRE64H reveals that an FrmR-specific amino-terminal Pro2 is proximal to Cys35, and these residues form the deduced formaldehyde-sensing site. Evidence is presented that implies that residues spatially close to the conserved cysteine tune the sensitivities of DUF156 proteins above or below critical thresholds for different effectors, generating the semblance of specificity within cells. Relative to FrmR, RcnR is less responsive to formaldehyde in vitro, and RcnR does not sense formaldehyde in vivo, but reciprocal mutations FrmRP2S and RcnRS2P, respectively, impair and enhance formaldehyde reactivity in vitro. Formaldehyde detoxification by FrmA requires S-(hydroxymethyl)glutathione, yet glutathione inhibits formaldehyde detection by FrmR in vivo and in vitro. Quantifying the number of FrmR molecules per cell and modeling formaldehyde modification as a function of [formaldehyde] demonstrates that FrmR reactivity is optimized such that FrmR is modified and frmRA is derepressed at lower [formaldehyde] than required to generate S-(hydroxymethyl)glutathione. Expression of FrmA is thereby coordinated with the accumulation of its substrate. PMID:27474740

Formaldehyde Emissions from Urea-Formaldehyde- and no-added-formaldehyde-Bonded particleboard as Influenced by Temperature and Relative Humidity

Treesearch

Charles R. Frihart; James M. Wescott; Timothy L. Chaffee; Kyle M. Gonner

2012-01-01

It is well documented that temperature and humidity can influence formaldehyde emissions from composite panels that are produced using urea-formaldehyde (UF)–type adhesives. This work investigates the effect of temperature and humidity on newer commercial California Air Resources Board (CARB) phase II–compliant particleboard produced with UF-type adhesives. These...

Cystathionine metabolic enzymes play a role in the inflammation resolution of human keratinocytes in response to sub-cytotoxic formaldehyde exposure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Eunyoung

Low-level formaldehyde exposure is inevitable in industrialized countries. Although daily-life formaldehyde exposure level is practically impossible to induce cell death, most of mechanistic studies related to formaldehyde toxicity have been performed in cytotoxic concentrations enough to trigger cell death mechanism. Currently, toxicological mechanisms underlying the sub-cytotoxic exposure to formaldehyde are not clearly elucidated in skin cells. In this study, the genome-scale transcriptional analysis in normal human keratinocytes (NHKs) was performed to investigate cutaneous biological pathways associated with daily life formaldehyde exposure. We selected the 175 upregulated differentially expressed genes (DEGs) and 116 downregulated DEGs in NHKs treated with 200 μMmore » formaldehyde. In the Gene Ontology (GO) enrichment analysis of the 175 upregulated DEGs, the endoplasmic reticulum (ER) unfolded protein response (UPR) was identified as the most significant GO biological process in the formaldeyde-treated NHKs. Interestingly, the sub-cytotoxic formaldehyde affected NHKs to upregulate two enzymes important in the cellular transsulfuration pathway, cystathionine γ-lyase (CTH) and cystathionine-β-synthase (CBS). In the temporal expression analysis, the upregulation of the pro-inflammatory DEGs such as MMP1 and PTGS2 was detected earlier than that of CTH, CBS and other ER UPR genes. The metabolites of CTH and CBS, L-cystathionine and L-cysteine, attenuated the formaldehyde-induced upregulation of pro-inflammatory DEGs, MMP1, PTGS2, and CXCL8, suggesting that CTH and CBS play a role in the negative feedback regulation of formaldehyde-induced pro-inflammatory responses in NHKs. In this regard, the sub-cytotoxic formaldehyde-induced CBS and CTH may regulate inflammation fate decision to resolution by suppressing the early pro-inflammatory response. - Highlights: • Sub-cytotoxic formaldehyde upregulates ER UPR-associated genes in NHKs. • Formaldehyde-induced ER UPR genes includes cystathionine γ-lyase (CTH). • Sub-cytotoxic formaldehyde upregulates cystathionine-β-synthase (CBS) in NHKs. • Cystathionine metabolic enzymes may attenuate formaldehyde-induced inflammation in NHKs. • Cystathionine metabolic enzymes may play a role in the resolution of inflammation in NHKs.« less

Residual formaldehyde after low-temperature steam and formaldehyde sterilization

PubMed Central

Gibson, G. L.; Johnston, H. P.; Turkington, V. E.

1968-01-01

The levels of formaldehyde remaining in various articles have been estimated immediately after a low-temperature steam and formaldehyde sterilizing process and after various periods of aeration. These levels have been compared with the levels of ethylene oxide remaining after exposure to an ethylene oxide sterilizing process. In rubber and polythene and a plastic, formaldehyde levels are low and slowly fall even further. Ethylene oxide levels are relatively much higher even after seven days' aeration. It is not considered that the residual levels of formaldehyde in rubber, polythene, and a plastic should constitute a danger. Residual levels of formaldehyde in fabrics and paper are higher but this may be of value by giving a self-disinfecting action on storage. PMID:5717551

Portable formaldehyde monitoring device using porous glass sensor and its applications in indoor air quality studies.

PubMed

Maruo, Yasuko Yamada; Nakamura, Jiro

2011-09-30

We have developed a portable device for formaldehyde monitoring with both high sensitivity and high temporal resolution, and carried out indoor air formaldehyde concentration analysis. The absorbance difference of the sensor element was measured in the monitoring device at regular intervals of, for example, one hour or 30 min, and the result was converted into the formaldehyde concentration. This was possible because we found that the lutidine derivative that was formed as a yellow product of the reaction between 1-phenyl-1,3-butandione and formaldehyde was stable in porous glass for at least six months. We estimated the reaction rate and to be 0.049 min(-1) and the reaction occurred quickly enough for us to monitor hourly changes in the formaldehyde concentration. The detection limit was 5 μg m(-3) h. We achieved hourly formaldehyde monitoring using the developed device under several indoor conditions, and estimated the air exchange rate and formaldehyde adsorption rate, which we adopted as a new term in the mass balance equation for formaldehyde, in one office. Copyright © 2011 Elsevier B.V. All rights reserved.

Carbonyl compounds in electronic cigarette vapors: effects of nicotine solvent and battery output voltage.

PubMed

Kosmider, Leon; Sobczak, Andrzej; Fik, Maciej; Knysak, Jakub; Zaciera, Marzena; Kurek, Jolanta; Goniewicz, Maciej Lukasz

2014-10-01

Glycerin (VG) and propylene glycol (PG) are the most common nicotine solvents used in e-cigarettes (ECs). It has been shown that at high temperatures both VG and PG undergo decomposition to low molecular carbonyl compounds, including the carcinogens formaldehyde and acetaldehyde. The aim of this study was to evaluate how various product characteristics, including nicotine solvent and battery output voltage, affect the levels of carbonyls in EC vapor. Twelve carbonyl compounds were measured in vapors from 10 commercially available nicotine solutions and from 3 control solutions composed of pure glycerin, pure propylene glycol, or a mixture of both solvents (50:50). EC battery output voltage was gradually modified from 3.2 to 4.8V. Carbonyl compounds were determined using the HPLC/DAD method. Formaldehyde and acetaldehyde were found in 8 of 13 samples. The amounts of formaldehyde and acetaldehyde in vapors from lower voltage EC were on average 13- and 807-fold lower than in tobacco smoke, respectively. The highest levels of carbonyls were observed in vapors generated from PG-based solutions. Increasing voltage from 3.2 to 4.8V resulted in a 4 to more than 200 times increase in formaldehyde, acetaldehyde, and acetone levels. The levels of formaldehyde in vapors from high-voltage device were in the range of levels reported in tobacco smoke. Vapors from EC contain toxic and carcinogenic carbonyl compounds. Both solvent and battery output voltage significantly affect levels of carbonyl compounds in EC vapors. High-voltage EC may expose users to high levels of carbonyl compounds. © The Author 2014. Published by Oxford University Press on behalf of the Society for Research on Nicotine and Tobacco. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Formaldehyde as a carbon and electron shuttle between autotroph and heterotroph populations in acidic hydrothermal vents of Norris Geyser Basin, Yellowstone National Park.

PubMed

Moran, James J; Whitmore, Laura M; Isern, Nancy G; Romine, Margaret F; Riha, Krystin M; Inskeep, William P; Kreuzer, Helen W

2016-05-01

The Norris Geyser Basin in Yellowstone National Park contains a large number of hydrothermal systems, which host microbial populations supported by primary productivity associated with a suite of chemolithotrophic metabolisms. We demonstrate that Metallosphaera yellowstonensis MK1, a facultative autotrophic archaeon isolated from a hyperthermal acidic hydrous ferric oxide (HFO) spring in Norris Geyser Basin, excretes formaldehyde during autotrophic growth. To determine the fate of formaldehyde in this low organic carbon environment, we incubated native microbial mat (containing M. yellowstonensis) from a HFO spring with (13)C-formaldehyde. Isotopic analysis of incubation-derived CO2 and biomass showed that formaldehyde was both oxidized and assimilated by members of the community. Autotrophy, formaldehyde oxidation, and formaldehyde assimilation displayed different sensitivities to chemical inhibitors, suggesting that distinct sub-populations in the mat selectively perform these functions. Our results demonstrate that electrons originally resulting from iron oxidation can energetically fuel autotrophic carbon fixation and associated formaldehyde excretion, and that formaldehyde is both oxidized and assimilated by different organisms within the native microbial community. Thus, formaldehyde can effectively act as a carbon and electron shuttle connecting the autotrophic, iron oxidizing members with associated heterotrophic members in the HFO community.

Does allergic contact dermatitis from formaldehyde in clothes treated with durable-press chemical finishes exist in the USA?

PubMed

de Groot, Anton C; Maibach, Howard I

2010-03-01

Recent US studies have presented case series of patient with allergic contact dermatitis (ACD) allegedly caused by formaldehyde in clothes treated with durable-press chemical finishes (DPCF), which are known formaldehyde releasers. However, the amounts of formaldehyde released by modern DPCF are thought to be well below the levels previously estimated to be able to elicit ACD. The objectives of this review are (i) to investigate whether clothes sold in the USA may contain enough free formaldehyde to elicit ACD in previously sensitized individuals and (ii) to assess the validity of US reports on ACD from formaldehyde in DPCF treated clothes. Literature was examined using various resources. The threshold level for formaldehyde in clothes that may cause ACD in sensitized individuals is unknown; we present data suggesting that levels < 200 ppm will be safe for most patients and that textiles will rarely contain higher amounts. All US studies presenting patients with ACD from formaldehyde in clothes had some weaknesses and in no report was the diagnosis proven beyond doubt. Currently, there is no definite proof that textile ACD from formaldehyde in DPCF in the USA exists. Future research should be directed at establishing the elicitation threshold and the amounts of formaldehyde present in textiles.

Formaldehyde as a carbon and electron shuttle between autotroph and heterotroph populations in acidic hydrothermal vents of Norris Geyser Basin, Yellowstone National Park

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moran, James J.; Whitmore, Laura M.; Isern, Nancy G.

The Norris Geyser Basin in Yellowstone National Park contains a large number of hydrothermal systems, which host microbial populations supported by primary productivity associated with a suite of chemolithotrophic metabolisms. We demonstrate that Metallosphaera yellowstonesis MK1, a facultative autotrophic archaeon isolated from a hyperthermal acidic hydrous ferric oxide (HFO) spring in Norris Geyser Basin, excretes formaldehyde during autotrophic growth. To determine the fate of formaldehyde in this low organic carbon environment, we incubated native microbial mat (containing M. yellowstonensis) from a HFO spring with 13C-formaldehyde. Isotopic analysis of incubation-derived CO2 and biomass showed that formaldehyde was both oxidized and assimilatedmore » by members of the community. Autotrophy, formaldehyde oxidation, and formaldehyde assimilation displayed different sensitivities to chemical inhibitors, suggesting that distinct sub-populations in the mat selectively perform these functions. Our results demonstrate that electrons originally resulting from iron oxidation can energetically fuel autotrophic carbon fixation and associated formaldehyde excretion, and that formaldehyde is both oxidized and assimilated by different organisms within the native microbial community. Thus, formaldehyde can effectively act as a carbon and electron shuttle connecting the autotrophic, iron oxidizing members with associated heterotrophic members in the HFO community.« less

Magic 2010 RASR Team

DTIC Science & Technology

2010-12-15

MAGIC 2010 – FINAL REPORT RASR TEAM - CONTRACT NO: FA2386-10-1-4021 December 15, 2010 Final Report for AOARD Grant FA23861014021 – MAGIC ... MAGIC 2010 Competition - Robotic Research Team (RASR) Abstract: The RASR team developed a system for the coordination of groups of unmanned...accomplish those missions. Our team goal was to develop a system that can provide long term value to the war-fighter, utilizing MAGIC 2010 as a stepping

[Attempt to reduce the formaldehyde concentration by blowing cooled fresh air down in to the breathing zone of medical students from an admission port on the ceiling during gross anatomy class].

PubMed

Takayanagi, Masaaki; Sakai, Makoto; Ishikawa, Youichi; Murakami, Kunio; Kimura, Akihiko; Kakuta, Sachiko; Sato, Fumi

2008-09-01

Cadavers in gross anatomy laboratories at most medical schools are conventionally embalmed in formaldehyde solution, which is carcinogenic to humans. Medical students and instructors are thus exposed to formaldehyde vapors emitted from cadavers during dissection. To reduce high formaldehyde concentrations in the breathing zone above cadavers being examined by anatomy medical students provisionally, dissection beds were located under existing admission ports on the ceiling to supply cooled fresh air from the admission port blowing downward on to the cadaver. In all cases, compared to normal condition, the downward flow of cooled fresh air from an admission port reduced formaldehyde concentrations by 0.09-0.98 ppm and reduced to 12.6-65.4% in the air above a cadaver in the breathing zone of students. The formaldehyde concentrations above cadavers under admission ports were not more than the formaldehyde concentrations between beds representing the indoor formaldehyde concentrations. Although the application of an existing admission port on the ceiling in this study did not remove formaldehyde, the downflow of cooled fresh air using this system reduced the formaldehyde concentration in the air above cadavers being attended by anatomy students during dissections. These results suggest the need for reducing formaldehyde levels in gross anatomy laboratories using fundamental countermeasures in order to satisfy the guidelines of 0.08 ppm established by the World Health Organization and the Japan Ministry of Health, Labor and Welfare.

Magical beliefs and discriminating science from pseudoscience in undergraduate professional students.

PubMed

Garrett, Bernard M; Cutting, Roger L

2017-11-01

Paranormal beliefs and magical thinking exist in the public, and amongst university students. Researchers have found that media can influence such beliefs. A 2012 study suggested pseudoscientific rationales can influence acceptance of reported paranormal phenomena. Using a paranormal belief survey and controlled experiment this work explores the paranormal beliefs and test the effects of three versions of a supernatural news story on undergraduate professional students. One version of the story presented a simple news article, another the same with a pseudoscientific rationale, and another gave a discrediting scientific critique. Results confirmed that many students do hold magical beliefs but discriminated between scientific and pseudoscientific narratives. However, pre-existing paranormal beliefs were associated with an increased likelihood of students finding paranormal reports scientific, believable and credible.

Effect of an ozone-generating air-purifying device on reducing concentrations of formaldehyde in air

DOE Office of Scientific and Technical Information (OSTI.GOV)

Esswein, E.J.; Boeniger, M.F.

1994-02-01

Formaldehyde, an air contaminant found in many indoor air investigations, poses distinct occupational exposure hazards in certain job categories (e.g., mortuary science) but is also of concern when found or suspected in office buildings and homes. A variety of air-purifying devices (APDs) are currently available or marketed for application to reduce or remove concentrations of a variety of indoor air pollutants through the use of ozone as a chemical oxidant. An investigation was conducted to determine if concentrations of formaldehyde similar to those found in industrial hygiene evaluations of funeral homes could be reduced with the use of an ozone-generatingmore » APD. An ozone-generating APD was placed in an exposure chamber and formaldehyde-containing embalming solution was allowed to evaporate naturally, creating peak and mean chamber concentrations of 2.5 and 1.3 ppm, respectively. Continuous-reading instruments were used to sample for formaldehyde and ozone. Active sampling methods were also used to sample simultaneously for formaldehyde and a possible reactant product, formic acid. Triplicate measurements were made in each of three evaluations: formaldehyde alone, ozone alone, and formaldehyde and ozone combined. Concentrations of formaldehyde were virtually identical with and without 0.5 ppm ozone. No reduction in formaldehyde concentration was found during a 90-minute evaluation using ozone at this concentration with peak and average concentrations of approximately 2.5 and 1.3 ppm formaldehyde, respectively. The results of this investigation suggest that the use of ozone is ineffective in reducing concentrations of formaldehyde. Because ozone has demonstrated health hazards, and is a regulated air contaminant in both the occupational and ambient environment, the use of ozone as an air purification agent in indoor air does not seem warranted. 25 refs., 5 figs., 4 tabs.« less

Migration of melamine and formaldehyde from tableware made of melamine resin.

PubMed

Ishiwata, H; Inoue, T; Tanimura, A

1986-01-01

Migration of melamine and formaldehyde into food-simulating solvents from cups made of melamine resin was studied under various conditions. Little migration of melamine was observed in any unused cups kept at 60 degrees C for 30 min, room temperature (26 degrees C) for 1 h or cooled at -20 degrees C for several days. Migration of both compounds was strongly affected by heating and acidity. The highest migration of melamine into 4% acetic acid used as a food-simulating solvent was 42.9 +/- 7.2 ppm when the migration test was repeated seven times at 95 degrees C for 30 min. In this time, the migration of formaldehyde was 14.2 +/- 0.6 ppm into the solvent. The molecular ratio of the migration amount of formaldehyde to melamine decreased according to the formula Y = 9.15X-0.813 over seven repetitions of the test, and was maintained at about 1.6 between the 10th and 20th repetitions. The inner surface of the cups became tarnished during the repetition of the test and their roughness increased from 1 micron before the test to 2.5-5 microns after 20 repetitions of the test. Migration of melamine from the cups being used at a cafeteria was 0.4 +/- 0.5 ppm, but that of formaldehyde was undetectable when the cups were kept at 60 degrees C for 30 min with 4% acetic acid.

Developing a Reference Material for Formaldehyde Emissions Testing; Final Report

EPA Science Inventory

Exposure to formaldehyde has been shown to produce broad and potentially severe adverse human health effects. With ubiquitous formaldehyde sources in the indoor environment, formaldehyde concentrations in indoor air are usually higher than outdoors, ranging from 10 to 4000 μg/m3....

Safety in the Chemical Laboratory: Atmospheric Formaldehyde Levels in an Academic Laboratory.

ERIC Educational Resources Information Center

Clausz, John C.; And Others

1984-01-01

Determined whether improved ventilation and use of "formaldehyde-free" biological specimens could reduce the levels of formaldehyde in air to which students and faculty would be exposed. Both methods were found to be effective in reducing formaldehyde levels in air. (JN)

40 CFR 63.2262 - How do I conduct performance tests and establish operating requirements?

Code of Federal Regulations, 2011 CFR

2011-07-01

... or documentation of inlet methanol or formaldehyde concentration is required) and outlet of the... HAP, formaldehyde, methanol, or total hydrocarbon (THC) emission rates. (2) When showing compliance... acetaldehyde, acrolein, formaldehyde, methanol, phenol, and propionaldehyde), THC, formaldehyde, or methanol in...

40 CFR 63.2262 - How do I conduct performance tests and establish operating requirements?

Code of Federal Regulations, 2010 CFR

2010-07-01

... or documentation of inlet methanol or formaldehyde concentration is required) and outlet of the... HAP, formaldehyde, methanol, or total hydrocarbon (THC) emission rates. (2) When showing compliance... acetaldehyde, acrolein, formaldehyde, methanol, phenol, and propionaldehyde), THC, formaldehyde, or methanol in...

Formaldehyde Exposures in a University Anatomy Laboratory

NASA Astrophysics Data System (ADS)

Winkler, Kyle William

Air sampling studies were conducted within a university anatomical laboratory during the embalmment of a cadaver in order to determine if dangerous concentrations of formaldehyde existed. Three air sampling studies were conducted in the anatomical laboratory on three separate days that a cadaver was being embalmed. Samples were collected and analyzed using the Occupational Safety and Health Administration (OSHA) Sampling and Analytical Methods: Method 52. Each air sampling study sampled for short term exposure limit (STEL) and time weighted mean (TWA) breathing zone formaldehyde concentrations as well as area TWA formaldehyde concentrations. A personal aldehyde monitor was also used in each air sampling study to sample for breathing zone formaldehyde concentrations. Measured TWA mean exposures to formaldehyde ranged from 0.15--1.3 parts per million (ppm), STEL formaldehyde exposures ranged from 0.019--0.64 ppm, and eight-hour TWAs ranged from 0.03 to 3.6 ppm. All 8-hour TWA formaldehyde concentrations sampled in the anatomy laboratory during an embalmment were less than the permissible exposure limit (PEL) required by OSHA.

Magic with Magic Squares.

ERIC Educational Resources Information Center

Wills, Herbert III

1989-01-01

Describes ways to make magic squares of 4 by 4 matrices. Presents two handouts: (1) Sets of 4 Numbers from 1 to 16 Whose Sum is 34; and (2) The Durer Square. Shows patterns which appeared in the magic squares, such as squares, chevrons, rhomboids, and trapezoids. (YP)

The Illusory Beliefs Inventory: a new measure of magical thinking and its relationship with obsessive compulsive disorder.

PubMed

Kingdon, Bianca L; Egan, Sarah J; Rees, Clare S

2012-01-01

Magical thinking has been proposed to have an aetiological role in obsessive compulsive disorder (OCD). To address the limitations of existing measures of magical thinking we developed and validated a new 24-item measure of magical thinking, the Illusory Beliefs Inventory (IBI). The validation sample comprised a total of 1194 individuals across two samples recruited via an Internet based survey. Factor analysis identified three subscales representing domains relevant to the construct of magical thinking: Magical Beliefs, Spirituality, and Internal State and Thought Action Fusion. The scale had excellent internal consistency and evidence of convergent and discriminant validity. Evidence of criterion-related concurrent validity confirmed that magical thinking is a cognitive domain associated with OCD and is largely relevant to neutralizing, obsessing and hoarding symptoms. It is important for future studies to extend the evidence of the psychometric properties of the IBI in new populations and to conduct longitudinal studies to examine the aetiological role of magical thinking.

Unusual formaldehyde-induced hypersensitivity in two schoolgirls

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gammage, R.B.; Hanna, W.T.; Painter, P.B.

1990-01-01

Two schoolgirls developed a syndrome resembling Henoch-Schonlein purpura while attending a recently opened school insulated with urea-formaldehyde foam (UFFI). Skin rashes and swellings were accompanied by bizarre, blue-green discoloration of the skin. Subsequent investigations by county, state and federal authorities, and low measured concentrations of formaldehyde, prompted initial conclusions that in-school formaldehyde exposures were not responsible for the girls' problems. Subsequent controlled exposures to UFFI and formaldehyde while in hospital elicited the whole cascade of symptoms. The chronology of the onset and amplification of systems make it probable that the formaldehyde exposures precipitating the girls' hypersensitivity, occurred in the school.more » 3 refs.« less

Formaldehyde removal from air by a biodegradation system.

PubMed

Xu, Zhongjun; Hou, Haiping

2010-07-01

A biodegradation system was used for the treatment of formaldehyde-polluted air. Air pressure dropped 12 mm water in the trickling biofilter during the experiment of about 4 months. In the range 20-300 mg m(-3) influent formaldehyde, this biodegradation system obtained 4.0-40.0 mg h(-1) degradation capacity, with 100%-66.7% degradation efficiency. The amount of formaldehyde degraded by the trickling biofilter was more than that by the activated sludge bioreactor below 200 mg m(-3) influent gaseous formaldehyde while the amount by the trickling biofilter was less than that by the activated sludge bioreactor over 200 mg m(-3) influent gaseous formaldehyde.

Manufacturing Magic and Computational Creativity

PubMed Central

Williams, Howard; McOwan, Peter W.

2016-01-01

This paper describes techniques in computational creativity, blending mathematical modeling and psychological insight, to generate new magic tricks. The details of an explicit computational framework capable of creating new magic tricks are summarized, and evaluated against a range of contemporary theories about what constitutes a creative system. To allow further development of the proposed system we situate this approach to the generation of magic in the wider context of other areas of application in computational creativity in performance arts. We show how approaches in these domains could be incorporated to enhance future magic generation systems, and critically review possible future applications of such magic generating computers. PMID:27375533

40 CFR 721.3810 - Formaldehyde, polymers with substituted phenols (generic).

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Formaldehyde, polymers with... New Uses for Specific Chemical Substances § 721.3810 Formaldehyde, polymers with substituted phenols... identified generically as Formaldehyde, polymers with substituted phenols (PMN P-99-0558) is subject to...

40 CFR 721.3810 - Formaldehyde, polymers with substituted phenols (generic).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Formaldehyde, polymers with... New Uses for Specific Chemical Substances § 721.3810 Formaldehyde, polymers with substituted phenols... identified generically as Formaldehyde, polymers with substituted phenols (PMN P-99-0558) is subject to...

40 CFR 721.3810 - Formaldehyde, polymers with substituted phenols (generic).

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Formaldehyde, polymers with... New Uses for Specific Chemical Substances § 721.3810 Formaldehyde, polymers with substituted phenols... identified generically as Formaldehyde, polymers with substituted phenols (PMN P-99-0558) is subject to...

40 CFR 721.3810 - Formaldehyde, polymers with substituted phenols (generic).

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Formaldehyde, polymers with... New Uses for Specific Chemical Substances § 721.3810 Formaldehyde, polymers with substituted phenols... identified generically as Formaldehyde, polymers with substituted phenols (PMN P-99-0558) is subject to...

40 CFR 721.3810 - Formaldehyde, polymers with substituted phenols (generic).

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Formaldehyde, polymers with... New Uses for Specific Chemical Substances § 721.3810 Formaldehyde, polymers with substituted phenols... identified generically as Formaldehyde, polymers with substituted phenols (PMN P-99-0558) is subject to...

Development of a formaldehyde biosensor with application to synthetic methylotrophy.

PubMed

Woolston, Benjamin M; Roth, Timothy; Kohale, Ishwar; Liu, David R; Stephanopoulos, Gregory

2018-01-01

Formaldehyde is a prevalent environmental toxin and a key intermediate in single carbon metabolism. The ability to monitor formaldehyde concentration is, therefore, of interest for both environmental monitoring and for metabolic engineering of native and synthetic methylotrophs, but current methods suffer from low sensitivity, complex workflows, or require expensive analytical equipment. Here we develop a formaldehyde biosensor based on the FrmR repressor protein and cognate promoter of Escherichia coli. Optimization of the native repressor binding site and regulatory architecture enabled detection at levels as low as 1 µM. We then used the sensor to benchmark the in vivo activity of several NAD-dependent methanol dehydrogenase (Mdh) variants, the rate-limiting enzyme that catalyzes the first step of methanol assimilation. In order to use this biosensor to distinguish individuals in a mixed population of Mdh variants, we developed a strategy to prevent cross-talk by using glutathione as a formaldehyde sink to minimize intercellular formaldehyde diffusion. Finally, we applied this biosensor to balance expression of mdh and the formaldehyde assimilation enzymes hps and phi in an engineered E. coli strain to minimize formaldehyde build-up while also reducing the burden of heterologous expression. This biosensor offers a quick and simple method for sensitively detecting formaldehyde, and has the potential to be used as the basis for directed evolution of Mdh and dynamic formaldehyde control strategies for establishing synthetic methylotrophy. © 2017 Wiley Periodicals, Inc.

A novel derivatization-free method of formaldehyde and propylene glycol determination in hydrogels by liquid chromatography with refractometric detection.

PubMed

Isakau, Henadz; Robert, Marielle; Shingel, Kirill I

2009-04-05

The paper describes the development and validation of a new derivatization-free liquid chromatography method for simultaneous determination of propylene glycol and formaldehyde in the formulations containing formaldehyde-releasing preservative. Highly swollen hydrogel made of poly(ethylene glycol)-protein conjugates was taken as a model formulation for integration of the propylene glycol and the diazolydinyl urea as formaldehyde releaser. The method is shown to be simple and selective and, more importantly, allows determining an existing level of formaldehyde at the moment of analysis instead of all available formaldehyde that might be released during chemical derivatization. After liquid extraction the propylene glycol (PG) and formaldehyde (FA) amounts are determined chromatographically on a Shodex SH 1011 ligand-exchange column using 0.01 M sulfuric acid mobile phase, a flow rate of 1.0 ml/min and RI detection. The assay is validated showing good linearity, precision, and accuracy. The limits of detection of formaldehyde and propylene glycol in the analyzed solutions were estimated to be 25 ng and 87 ng, respectively. This analytical assay is considered useful for product stability studies and in developing new formaldehyde releaser-containing formulations where the concentration of formaldehyde is a presumable subject of labeling requirements. This method can also provide a rapid and convenient alternative to gas chromatography method of propylene glycol quantification.

Formaldehyde concentrations in household air of asthma patients determined using colorimetric detector tubes

PubMed Central

Dannemiller, Karen C.; Murphy, Johnna S.; Dixon, Sherry L.; Pennell, Kelly G.; Suuberg, Eric M.; Jacobs, David E.; Sandel, Megan

2013-01-01

Formaldehyde is a colorless, pungent gas commonly found in homes that is a respiratory irritant, sensitizer, carcinogen and asthma trigger. Typical household sources include plywood and particleboard, cleaners, cosmetics, pesticides, and others. Development of a fast and simple measurement technique could facilitate continued research on this important chemical. The goal of this research is to apply an inexpensive short-term measurement method to find correlations between formaldehyde sources and concentration, and formaldehyde concentration and asthma control. Formaldehyde was measured using 30-minute grab samples in length-of-stain detector tubes in homes (n=70) of asthmatics in the Boston, MA area. Clinical status and potential formaldehyde sources were determined. The geometric mean formaldehyde level was 35.1 ppb and ranged from 5–132 ppb. Based on one-way ANOVA, t-tests, and linear regression, predictors of log-transformed formaldehyde concentration included absolute humidity, season, and the presence of decorative laminates, fiberglass, or permanent press fabrics (p<0.05), as well as temperature and household cleaner use (p<0.10). The geometric mean formaldehyde concentration was 57% higher in homes of children with very poorly controlled asthma compared to homes of other asthmatic children (p=0.078). This study provides a simple method for measuring household formaldehyde and suggests that exposure is related to poorly controlled asthma. PMID:23278296

Occupational asthma due to formaldehyde.

PubMed Central

Burge, P S; Harries, M G; Lam, W K; O'Brien, I M; Patchett, P A

1985-01-01

Bronchial provocation studies on 15 workers occupationally exposed to formaldehyde are described. The results show that formaldehyde exposure can cause asthmatic reactions, and suggest that these are sometimes due to hypersensitivity and sometimes to a direct irritant effect. Three workers had classical occupational asthma caused by formaldehyde fumes, which was likely to be due to hypersensitivity, with late asthmatic reactions following formaldehyde exposure. Six workers developed immediate asthmatic reactions, which were likely to be due to a direct irritant effect as the reactions were shorter in duration than those seen after soluble allergen exposure and were closely related to histamine reactivity. The breathing zone concentrations of formaldehyde required to elicit these irritant reactions (mean 4.8 mg/m3) were higher than those encountered in buildings recently insulated with urea formaldehyde foam, but within levels sometimes found in industry. Images PMID:4023975

Observations of glyoxal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry

NASA Astrophysics Data System (ADS)

DiGangi, J. P.; Henry, S. B.; Kammrath, A.; Boyle, E. S.; Kaser, L.; Schnitzhofer, R.; Graus, M.; Turnipseed, A.; Park, J.-H.; Weber, R. J.; Hornbrook, R. S.; Cantrell, C. A.; Maudlin, R. L., III; Kim, S.; Nakashima, Y.; Wolfe, G. M.; Kajii, Y.; Apel, E. C.; Goldstein, A. H.; Guenther, A.; Karl, T.; Hansel, A.; Keutsch, F. N.

2012-10-01

We present simultaneous fast, in-situ measurements of formaldehyde and glyoxal from two rural campaigns, BEARPEX 2009 and BEACHON-ROCS, both located in Pinus Ponderosa forests with emissions dominated by biogenic volatile organic compounds (VOCs). Despite considerable variability in the formaldehyde and glyoxal concentrations, the ratio of glyoxal to formaldehyde, RGF, displayed a very regular diurnal cycle over nearly 2 weeks of measurements. The only deviations in RGF were toward higher values and were the result of a biomass burning event during BEARPEX 2009 and very fresh anthropogenic influence during BEACHON-ROCS. Other rapid changes in glyoxal and formaldehyde concentrations have hardly any affect on RGF and could reflect transitions between low and high NO regimes. The trend of increased RGF from both anthropogenic reactive VOC mixtures and biomass burning compared to biogenic reactive VOC mixtures is robust due to the short timescales over which the observed changes in RGF occurred. Satellite retrievals, which suggest higher RGF for biogenic areas, are in contrast to our observed trends. It remains important to address this discrepancy, especially in view of the importance of satellite retrievals and in situ measurements for model comparison. In addition, we propose that RGF represents a useful metric for biogenic or anthropogenic reactive VOC mixtures and, in combination with absolute concentrations of glyoxal and formaldehyde, furthermore represents a useful metric for the extent of anthropogenic influence on overall reactive VOC processing via NOx. In particular, RGF yields information about not simply the VOCs dominating reactivity in an airmass, but the VOC processing itself that is directly coupled to ozone and secondary organic aerosol production.

Carbonyl Compounds Produced by Vaporizing Cannabis Oil Thinning Agents.

PubMed

Troutt, William D; DiDonato, Matthew D

2017-11-01

Cannabis use has increased in the United States, particularly the use of vaporized cannabis oil, which is often mixed with thinning agents for use in vaporizing devices. E-cigarette research shows that heated thinning agents produce potentially harmful carbonyls; however, similar studies have not been conducted (1) with agents that are commonly used in the cannabis industry and (2) at temperatures that are appropriate for cannabis oil vaporization. The goal of this study was to determine whether thinning agents used in the cannabis industry produce potentially harmful carbonyls when heated to a temperature that is appropriate for cannabis oil vaporization. Four thinning agents (propylene glycol [PG], vegetable glycerin [VG], polyethylene glycol 400 [PEG 400], and medium chain triglycerides [MCT]) were heated to 230°C and the resulting vapors were tested for acetaldehyde, acrolein, and formaldehyde. Each agent was tested three times. Testing was conducted in a smoking laboratory. Carbonyl levels were measured in micrograms per puff block. Analyses showed that PEG 400 produced significantly higher levels of acetaldehyde and formaldehyde than PG, MCT, and VG. Formaldehyde production was also significantly greater in PG compared with MCT and VG. Acrolein production did not differ significantly across the agents. PG and PEG 400 produced high levels of acetaldehyde and formaldehyde when heated to 230°C. Formaldehyde production from PEG 400 isolate was particularly high, with one inhalation accounting for 1.12% of the daily exposure limit, nearly the same exposure as smoking one cigarette. Because PG and PEG 400 are often mixed with cannabis oil, individuals who vaporize cannabis oil products may risk exposure to harmful formaldehyde levels. Although more research is needed, consumers and policy makers should consider these potential health effects before use and when drafting cannabis-related legislation.

Assessment of formaldehyde levels in local and imported fresh fish in Ghana: a case study in the Tamale Metropolis of Ghana.

PubMed

Saba, Courage Kosi Setsoafia; Atayure, Seidu Isaac; Adzitey, Frederick

2015-03-01

Fish is an important source of protein all over the world, including in Ghana. The fishery sector plays a major role in meeting the domestic need of animal protein and also contributes greatly in foreign exchange earnings. The domestic supply of fish does not meet the demand, so Ghana imports fish and fish products from other countries. Media reports in Ghana have alleged the use of formaldehyde to preserve fish for increased shelf life and to maintain freshness. This research, therefore, sought to establish the levels of formaldehyde in imported and local fresh fish in the Tamale Metropolis by using a ChemSee formaldehyde and formalin detection test kit. Positive and negative controls were performed by using various concentrations of formalin (1, 10, 30, 50, 100, and 300 ppm) and sterile distilled water, respectively. Three times over a 6-month period, different fish species were obtained from five wholesale cold stores (where fish are sold in cartons) and some local sales points (where locally caught fish are sold). A total of 32 samples were taken during three different sampling sessions: 23 imported fish (mackerel, herring, horse mackerel, salmon, and redfish) and 9 local tilapia. The fish were cut, and 50 g was weighed and blended with an equal volume (50 ml) of sterile distilled water. Samples were transferred to test tubes and centrifuged. A test strip was dipped into the supernatant and observed for a color change. A change in color from white to pink or purple indicated the presence of formaldehyde in fish. The study showed that no formaldehyde was present in the imported and local fish obtained. The appropriate regulatory agencies should carry out this study regularly to ensure that fish consumed in Ghana is safe for consumption.

Identification of formaldehyde as the metabolite responsible for the mutagenicity of methyl tertiary-butyl ether in the activated mouse lymphoma assay.

PubMed

Mackerer, C R; Angelosanto, F A; Blackburn, G R; Schreiner, C A

1996-09-01

Methyl tertiary-butyl ether (MTBE), which is added to gasoline as an octane enhancer and to reduce automotive emissions, has been evaluated in numerous toxicological tests, including those for genotoxicity. MTBE did not show any mutagenic potential in the Ames bacterial assay or any clastogenicity in cytogenetic tests. However, it has been shown to be mutagenic in an in vitro gene mutation assay using mouse lymphoma cells when tested in the presence, but not in the absence, of a rat liver-derived metabolic activation system (S-9). In the present study, MTBE was tested to determine if formaldehyde, in the presence of the S-9, was responsible for the observed mutagenicity. A modification of the mouse lymphoma assay was employed which permits determination of whether a suspect material is mutagenic because it contains or is metabolized to formaldehyde. In the modified assay, the enzyme formaldehyde dehydrogenase (FDH) and its co-factor, NAD+ are added in large excess during the exposure period so that any formaldehyde produced in the system is rapidly converted to formic acid which is not genotoxic. An MTBE dose-responsive increase in the frequency of mutants and in cytotoxicity occurred without FDH present, and this effect was greatly reduced in the presence of FDH NAD+. The findings clearly demonstrate that formaldehyde derived from MTBE is responsible for mutagenicity of MTBE in the activated mouse lymphoma assay. Furthermore, the results suggest that the lack of mutagenicity/clastogenicity seen with MTBE in other in vitro assays might have resulted from inadequacies in the test systems employed for those assays.

Effects of combined exposure to formaldehyde and benzene on immune cells in the blood and spleen in Balb/c mice.

PubMed

Wen, Huaxiao; Yuan, Langyue; Wei, Chenxi; Zhao, Yun; Qian, Yan; Ma, Ping; Ding, Shumao; Yang, Xu; Wang, Xianliang

2016-07-01

Formaldehyde and benzene are the two major indoor air pollutants due to their prevalence and toxicity. This study aimed to explore the toxic effect on the spleen and relevant immune responses of Balb/c mice caused by exposure to a combination of formaldehyde and benzene. Balb/c mice were divided randomly into five groups (n=9/group): blank control group (Ctrl); solvent ([corn] Oil) control; formaldehyde only (FA, 3mg/m(3)); benzene only (BZ, 150mg/kg BW); and, formaldehyde+benzene group (FA+BZ). Exposures were performed for 8h/day, 5 day/week, for 2 weeks. Tail blood was collected after the final exposure; 24-h later, the mice were euthanized to permit assessment of a variety of immune endpoints. The endpoints' three areas were: (1) in living mice, body weight and delayed-type hypersensitivity (DTH) responses; (2) in blood, immune cell counts and serum antibody levels (serum hemagglutination); and, (3) in spleen samples, reactive oxygen species (ROS), malondialdehyde (MDA), glutathione (GSH), caspase-3 (cell apoptosis) levels and lymphocyte proliferation. In this study we fund (1) BZ and FA+BZ exposure can lead to the reduction in the number of some immune cells in peripheral blood; (2) Formaldehyde has certain synergistic effects on benzene-induced cytotoxicity in peripheral blood, (3) FA, BZ and FA+BZ exposure can lead to ROS and GSH depletion in spleen cells, and spleen cell apoptosis (caspase-3 increased) may be one of the downstream events, decreased splenic lymphocyte proliferation; and (4) the FA+BZ combined exposure can lead to the decreased body weight, serum antibody level (by serum hemagglutination assay). Copyright © 2016 Elsevier B.V. All rights reserved.

Comparison of the effects of formaldehyde and gaseous ozone on HBV-contaminated hospital quilts

PubMed Central

Guo, Dan; Li, Ziqiong; Jia, Bei; Che, Xiaoqiong; Song, Tianshuang; Huang, Wenxiang

2015-01-01

Background: Besides being highly infectious, Hepatitis B virus (HBV) is a major cause of liver disease worldwide. In hospital settings, it is easy for the environment and quilts to be contaminated by HBV patient blood and body fluids. Therefore, HBV can be transmitted to other patients via contaminated environmental surfaces or quilts, resulting in an HBV nosocomial infection. Formaldehyde and ozone are commonly used disinfectants that may influence this infectious situation. Objective: To investigate the clinical effectiveness of formaldehyde and gaseous ozone for the terminal cleaning of hospital quilts contaminated by HBV. Methods: Thin cloth and thick cotton soaked with the serum from high HBV copy number patients were prepared and disinfected using formaldehyde fumigation and gaseous ozone at different times. The copy numbers of HBV DNA in the HBV-contaminated cloth and cotton samples were measured quantitatively with fluorescent quantitative polymerase chain reaction (PCR). Results: When gaseous ozone was used to disinfect HBV-contaminated quilts for 23 minutes (min), 36 min, 49 min, and 90 min, the HBV DNA copy number displayed no significant decrease compared with the copy number before disinfection (P > 0.05). In comparison, the copy number of the HBV DNA in the cloth group decreased significantly (P < 0.05) after formaldehyde fumigation disinfection for 1 hour (h), and there was no difference when longer times and increased concentrations were used. In the thick cotton group, there was also a significant decrease (P < 0.05) of the HBV DNA copy numbers, but the decrease was not as dramatic. In addition, in this group, the disinfection effect observed at 4 h was the strongest. Conclusions: The application of ozone to disinfect HBV-contaminated hospital quilts possibly has no effect, whereas, formaldehyde oxide fumigation effectively reduced HBV copy numbers. PMID:26770591

Development of real-time monitors for gaseous formaldehyde. Final report, 1 December 1988-30 September 1989

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kelly, T.J.; Barnes, R.H.

1990-11-01

Two new methods for real-time measurement of gaseous formaldehyde have been developed. One is a spectroscopic method based on direct fluorescence detection of gaseous formaldehyde following excitation with UV light. This method has been developed to the prototype stage by modifications of a commercial fluorescence SO2 detector to convert it to formaldehyde detection. The prototype spectroscopic formaldehyde monitor exhibits a detection limit of <30 ppbv, with a time response of about one minute. The second method is based on derivatization of formaldehyde in aqueous solution to form a fluorescent product. The detection of fluorescent product was made more sensitive bymore » using intense 254 nm light from a mercury lamp for excitation, thereby allowing use of a simple and efficient glass coil scrubber for collection of gaseous formaldehyde. The wet chemical formaldehyde monitor incorportating these improvements exhibits a detection limit for gaseous formaldehyde of 0.2 ppbv and for aqueous formaldehyde of 0.2 micromolar with time response of about one minute, following a lag time of 2 minutes. Both instruments were tested in the laboratory with gaseous formaldehyde standards, and the aqueous scrubbing/analysis method was field tested by continuous operation over a 10-day period in which outdoor and indoor air were sampled for alternate half-hour periods. A comparison of real-time (aqueous scrubbing/analysis) and integrated measurements, using dinitrophenylhydrazine (DNPH) impingers, showed close agreement between the real-time and DNPH data, even at concentrations as low as 1 ppbv.« less

Partially-irreversible sorption of formaldehyde in five polymers

NASA Astrophysics Data System (ADS)

Ye, Wei; Cox, Steven S.; Zhao, Xiaomin; Frazier, Charles E.; Little, John C.

2014-12-01

Due to its environmental ubiquity and concern over its potential toxicity, the mass-transfer characteristics of formaldehyde are of critical importance to indoor air quality research. Previous studies have suggested that formaldehyde mass transfer in polymer is partially irreversible. In this study, mechanisms that could cause the observed irreversibility were investigated. Polycarbonate and four other polymeric matrices were selected and subjected to formaldehyde sorption/desorption cycles. Mass transfer of formaldehyde was partially irreversible in all cases, and three potential mechanisms were evaluated. First, attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) analysis was used to investigate possible formaldehyde polymerization on polymer surfaces. ATR-FTIR showed no detectable paraformaldehyde or formaldehyde on the film surfaces that had been exposed to formaldehyde and air. ATR-FTIR did detect aliphatic acids suggesting oxidation had occurred on film surfaces as a result of exposure to formaldehyde. However, additional study suggested that air is not the primary cause for irreversibility. Second, statistical physics theory was tested as a possible explanation. According to this theory, reversible and irreversible sorption could be taking place simultaneously. The irreversible fraction should be constant during sorption and the fraction could be determined by performing a complete sorption/desorption test. The sorption/desorption data was consistent with this theory. Third, chemisorption was considered as another possible cause for irreversibility. Extraction/fluorimetry testing of post-sorption and post-desorption polymer films showed measurable quantities of formaldehyde suggesting that some of the chemisorbed formaldehyde was reversible at the higher extraction temperature. Further quantitative study on chemical reaction products is needed.

Watching films with magical content facilitates creativity in children.

PubMed

Subbotsky, Eugene; Hysted, Claire; Jones, Nicola

2010-08-01

Two experiments examined the possible link between magical thinking and creativity in preschool children. In Exp. 1, 4- and 6-yr.-old children were shown a film with either a magical or nonmagical theme. Results indicated that the mean scores of children shown the magical film was significantly higher than that of children watching the nonmagical film on the majority of subsequent creativity tests for both age groups. This trend was also found for 6-yr.-olds' drawings of impossible items. In Exp. 2, Exp. 1 was replicated successfully with 6- and 8-yr.-old children. Exposing children to a film with a magical theme did not affect their beliefs about magic. The results were interpreted to accentuate the role of magical thinking in children's cognitive development. Classroom implications of the results were also discussed.

40 CFR 721.7046 - Formaldehyde, polymer with substituted phenols, glycidyl ether.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Formaldehyde, polymer with substituted... New Uses for Specific Chemical Substances § 721.7046 Formaldehyde, polymer with substituted phenols... substance identified as formaldehyde, polymer with substituted phenols, glycidyl ether (PMN P-93-955) is...

24 CFR 3280.309 - Health Notice on formaldehyde emissions.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 24 Housing and Urban Development 5 2010-04-01 2010-04-01 false Health Notice on formaldehyde... Construction Requirements § 3280.309 Health Notice on formaldehyde emissions. (a) Each manufactured home shall have a Health Notice on formaldehyde emissions prominently displayed in a temporary manner in the...

24 CFR 3280.309 - Health Notice on formaldehyde emissions.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 24 Housing and Urban Development 5 2014-04-01 2014-04-01 false Health Notice on formaldehyde... Construction Requirements § 3280.309 Health Notice on formaldehyde emissions. (a) Each manufactured home shall have a Health Notice on formaldehyde emissions prominently displayed in a temporary manner in the...

24 CFR 3280.309 - Health Notice on formaldehyde emissions.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 24 Housing and Urban Development 5 2013-04-01 2013-04-01 false Health Notice on formaldehyde... Construction Requirements § 3280.309 Health Notice on formaldehyde emissions. (a) Each manufactured home shall have a Health Notice on formaldehyde emissions prominently displayed in a temporary manner in the...

40 CFR 721.7046 - Formaldehyde, polymer with substituted phenols, glycidyl ether.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Formaldehyde, polymer with substituted... New Uses for Specific Chemical Substances § 721.7046 Formaldehyde, polymer with substituted phenols... substance identified as formaldehyde, polymer with substituted phenols, glycidyl ether (PMN P-93-955) is...

40 CFR 721.7046 - Formaldehyde, polymer with substituted phenols, glycidyl ether.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Formaldehyde, polymer with substituted... New Uses for Specific Chemical Substances § 721.7046 Formaldehyde, polymer with substituted phenols... substance identified as formaldehyde, polymer with substituted phenols, glycidyl ether (PMN P-93-955) is...

40 CFR 721.10237 - Formaldehyde, polymers with acetone-phenol reaction products and phenol, sodium salts.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Formaldehyde, polymers with acetone... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10237 Formaldehyde, polymers with... subject to reporting. (1) The chemical substance identified as formaldehyde, polymers with acetone-phenol...

40 CFR 721.7046 - Formaldehyde, polymer with substituted phenols, glycidyl ether.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Formaldehyde, polymer with substituted... New Uses for Specific Chemical Substances § 721.7046 Formaldehyde, polymer with substituted phenols... substance identified as formaldehyde, polymer with substituted phenols, glycidyl ether (PMN P-93-955) is...

40 CFR 721.7046 - Formaldehyde, polymer with substituted phenols, glycidyl ether.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Formaldehyde, polymer with substituted... New Uses for Specific Chemical Substances § 721.7046 Formaldehyde, polymer with substituted phenols... substance identified as formaldehyde, polymer with substituted phenols, glycidyl ether (PMN P-93-955) is...

40 CFR 721.3805 - Formaldehyde, reaction products with 1,3-benzenedimethanamine and bisphenol A.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Formaldehyde, reaction products with 1... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.3805 Formaldehyde, reaction products... to reporting. (1) The chemical substance identified as formaldehyde, reaction products with 1,3...

40 CFR 721.3805 - Formaldehyde, reaction products with 1,3-benzenedimethanamine and bisphenol A.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Formaldehyde, reaction products with 1... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.3805 Formaldehyde, reaction products... to reporting. (1) The chemical substance identified as formaldehyde, reaction products with 1,3...

21 CFR 573.460 - Formaldehyde.

Code of Federal Regulations, 2012 CFR

2012-04-01

..., FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES PERMITTED IN FEED AND DRINKING WATER OF ANIMALS Food Additive Listing § 573.460 Formaldehyde. The food additive formaldehyde may be safely used in the manufacture of... each batch. (b)(1) The food additive is formaldehyde (CAS No. 50-00-0; 37 percent aqueous solution). It...

21 CFR 573.460 - Formaldehyde.

Code of Federal Regulations, 2010 CFR

2010-04-01

..., FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES PERMITTED IN FEED AND DRINKING WATER OF ANIMALS Food Additive Listing § 573.460 Formaldehyde. The food additive formaldehyde may be safely used in the manufacture of... each batch. (b)(1) The food additive is formaldehyde (CAS No. 50-00-0; 37 percent aqueous solution). It...

21 CFR 573.460 - Formaldehyde.

Code of Federal Regulations, 2013 CFR

2013-04-01

..., FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES PERMITTED IN FEED AND DRINKING WATER OF ANIMALS Food Additive Listing § 573.460 Formaldehyde. The food additive formaldehyde may be safely used in the manufacture of... each batch. (b)(1) The food additive is formaldehyde (CAS No. 50-00-0; 37 percent aqueous solution). It...

21 CFR 573.460 - Formaldehyde.

Code of Federal Regulations, 2011 CFR

2011-04-01

..., FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES PERMITTED IN FEED AND DRINKING WATER OF ANIMALS Food Additive Listing § 573.460 Formaldehyde. The food additive formaldehyde may be safely used in the manufacture of... each batch. (b)(1) The food additive is formaldehyde (CAS No. 50-00-0; 37 percent aqueous solution). It...

21 CFR 573.460 - Formaldehyde.

Code of Federal Regulations, 2014 CFR

2014-04-01

..., FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES PERMITTED IN FEED AND DRINKING WATER OF ANIMALS Food Additive Listing § 573.460 Formaldehyde. The food additive formaldehyde may be safely used in the manufacture of... each batch. (b)(1) The food additive is formaldehyde (CAS No. 50-00-0; 37 percent aqueous solution). It...

EFFECTS OF FORMALDEHYDE AND PARTICLE-BOUND FORMALDEHYDE ON LUNG MACROPHAGE FUNCTIONS

EPA Science Inventory

Dr. George Jakab and associates exposed mice to varying levels (ranging from 0.5 to 15 parts per million [ppm]) of formaldehyde alone or to formaldehyde (5 and 2.5 ppm) mixed with carbon black particles. Carbon black particles were chosen because of their similarity to comb...

Polar and singular value decomposition of 3×3 magic squares

NASA Astrophysics Data System (ADS)

Trenkler, Götz; Schmidt, Karsten; Trenkler, Dietrich

2013-07-01

In this note, we find polar as well as singular value decompositions of a 3×3 magic square, i.e. a 3×3 matrix M with real elements where each row, column and diagonal adds up to the magic sum s of the magic square.

The MAGIC (Manually Assisted Gaming of Integrated Combat) Model,

DTIC Science & Technology

1982-05-01

IP -6 7 6 7 Zo - A O - ?G O 6 7 9 N L mhhhhh1h8I 1-I THE MAGIC (MANUALLY ASSISTED GAMING OF INTEGRATED COMBAT) MODEL Milton G. Weiner May 1982 L io...Corporation Santa Monica, California 90406 - - ~-. - - -i 77 THE MAGIC (MANUALLY ASSISTED GAMING OF INTEGRATED COMBAT) MODEL Milton G. Weiner May 1982 THE... MAGIC (MANUALLY ASSISTED GAMING OF INTEGRATED COMBAT) MODEL Milton G. Weiner The Rand Corporation, Santa Monica, California The MAGIC model isn’Vt

Measurement of indoor formaldehyde concentrations with a passive sampler

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gillett, R.W.; Kreibich, H.; Ayers, G.P.

2000-05-15

An existing Ferm-type passive sampler technique has been further developed to measure concentrations of formaldehyde gas in indoor air. Formaldehyde forms a derivative after reaction with a filter coated with 2,4-dinitrophenylhydrazine (2,4-DNPH). The formaldehyde 2,4-dinitrophenylhydrazine derivative (formaldehyde-2,4-DNPH) is extracted from the filter, and the concentration is determined by high-performance liquid chromatography. The technique has been validated against an active sampling method, and the agreement is close when the appropriate laminar boundary layer depth is applied to the passive measurement. For this technique an exposure period of 3 days is equivalent to a limit of detection of formaldehyde of 3.4 ppbvmore » and a limit of quantification of 7.6 ppbv. To test the performance of the passive samplers ambient formaldehyde measurements were carried out inside homes and in a range of workplace environments.« less

Visits to physicians before and after exposure to urea formaldehyde foam insulation.

PubMed Central

L'Abbé, K A; Hoey, J R; Hanley, J; Wacholder, S; Nantel, A

1988-01-01

The average number of visits to a physician made by a sample of 351 residents of homes insulated with urea formaldehyde foam insulation in Montreal in the one year period before exposure was 5.25, and in the year following 5.62, an increase of 7 per cent (odds ratio 1.07, 95% CI = 1.00, 1.15). The increase in visits in the post insulation year was limited to subjects who had the product installed in the winter (OR = 1.48, 95% CI = 1.18,1.85), and was not seen for study subjects who insulated their homes during other seasons of the year. PMID:3177730

The formaldehyde problem in wood-based products : an annotated bibliography

Treesearch

F. H. Max Nestler

1977-01-01

Urea-formaldehyde-type adhesives have the inherent characteristic of giving off free formaldehyde under some conditions of use. The vapor can build up to concentrations which can be a nuisance, uncomfortable, or an actual health hazard. The "formaldehyde problem" is reviewed, from literature sources, in five respects : oriqins, analytical, control and removal...

40 CFR 721.10190 - Formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4-methyl-2...

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Formaldehyde, polymer with aliphatic... Formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4-methyl-2-pentanone (generic... identified generically as formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4...

40 CFR 63.1183 - How do I comply with the formaldehyde standards for existing, new, and reconstructed curing ovens?

Code of Federal Regulations, 2014 CFR

2014-07-01

... specification range, record the free-formaldehyde content specification range of the resin used, and the... that requires a binder formulation made with the resin containing the highest free-formaldehyde content specification range. Show compliance with the formaldehyde emission limits while the device for measuring...

40 CFR 63.1183 - How do I comply with the formaldehyde standards for existing, new, and reconstructed curing ovens?

Code of Federal Regulations, 2012 CFR

2012-07-01

... specification range, record the free-formaldehyde content specification range of the resin used, and the... that requires a binder formulation made with the resin containing the highest free-formaldehyde content specification range. Show compliance with the formaldehyde emission limits while the device for measuring...

40 CFR 63.1183 - How do I comply with the formaldehyde standards for existing, new, and reconstructed curing ovens?

Code of Federal Regulations, 2011 CFR

2011-07-01

... specification range, record the free-formaldehyde content specification range of the resin used, and the... that requires a binder formulation made with the resin containing the highest free-formaldehyde content specification range. Show compliance with the formaldehyde emission limits while the device for measuring...

40 CFR 63.1183 - How do I comply with the formaldehyde standards for existing, new, and reconstructed curing ovens?

Code of Federal Regulations, 2013 CFR

2013-07-01

... specification range, record the free-formaldehyde content specification range of the resin used, and the... that requires a binder formulation made with the resin containing the highest free-formaldehyde content specification range. Show compliance with the formaldehyde emission limits while the device for measuring...

40 CFR 63.1183 - How do I comply with the formaldehyde standards for existing, new, and reconstructed curing ovens?

Code of Federal Regulations, 2010 CFR

2010-07-01

... specification range, record the free-formaldehyde content specification range of the resin used, and the... that requires a binder formulation made with the resin containing the highest free-formaldehyde content specification range. Show compliance with the formaldehyde emission limits while the device for measuring...

Analysis of cocondensation of melamine and urea through carbon 13 enriched formaldehyde with C-13 nuclear magnetic resonance spectroscopy

Treesearch

Bunichiro Tomita; Chung-Yun Hse

1995-01-01

The urea-formaldehyde (UF) resins, melamine-formaldehyde (MF) resins, and melamine-ureaformaldehyde (MUF) cocondensed resins were synthesized using the labeling method with 13C enriched formaldehyde under neutral conditions and their 13C-NMR (nuclear magnetic resonance) spectra were analyzed. The remarkable down-field...

Magical ideation is related to questionnaire but not behavioural measures of handedness.

PubMed

Grimshaw, Gina M; Yelle, Serena K; Schoger, Jamie; Bright, Kathleen S

2008-01-01

Magical ideation has repeatedly been shown to be related to handedness, with mixed-handers exhibiting higher levels of magical thinking. However, most previous research has assessed hand preference with a questionnaire measure, leaving open the possibility that the correlation reflects some aspect of questionnaire-taking behaviour and not an underlying neuropsychological relationship. The present study addressed this issue by administering the Magical Ideation Scale (Eckblad & Chapman, 1983), the Waterloo Handedness Questionnaire-Revised (Elias, Bryden, & Bulman-Fleming, 1998), and a manual dot-filling task (Tapley & Bryden, 1985) as a behavioural measure of handedness to an undergraduate student sample. The expected relationship between magical ideation and handedness as assessed by the questionnaire was observed. However, magical ideation was not related to the behavioural measure of handedness. Results cast doubt on a neuropsychological interpretation of the relationship between handedness and magical ideation in sub-clinical populations.

On Super Edge-magic Total Labeling of Modified Watermill Graph

NASA Astrophysics Data System (ADS)

Nurdin; Ungko, T. S.; Gormantara, J.; Abdullah, A.; Aulyah, S.; Nikita

2018-03-01

An edge-magic total labeling on a graph G is one-to-one map from V(G) ∪ E(G) onto the set of integers 1,2, ...,ν + e, where ν = |V(G)| and e = |E(G)|, with the property that, given any edge uv, f(u) + f(u, ν}) + f(ν) = k for every u,v ∈ V(G), and k is called magic valuation. An edge-magic total labeling f is called super edge-magic total if f(v(G)) = {1,2 ...,|V(G)|} and f(E(G)) = {|V(G)| + 1, |V(G)| + 2,... |V(G) + E(G)|}. In this paper we investigate edge-magic total labeling of a new graph called modified Watermill graph. Furthermore, the magic valuation of the modified Watermill graph WM(n) is k=\\frac{1}{2}(21n+3), for n odd, n ≥ 3.

PPM mixtures of formaldehyde in gas cylinders: Stability and analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wong, K.C.; Miller, S.B.; Patterson, L.M.

1999-07-01

Scott Specialty Gases has been successful in producing stable calibration gases of formaldehyde at low concentration. Critical to this success has been the development of a treatment process for high pressure aluminum cylinders. Formaldehyde cylinders having concentrations of 20ppm and 4ppm were found to show only small decline in concentrations over a period of approximately 12 months. Since no NIST traceable formaldehyde standards (or Standard Reference Material) are available, all Scott's formaldehyde cylinders were originally certified by traditional impinger method. This method involves an extremely tedious purification procedure for 2,4-dinitrophenylhydrazine (2,4-DNPH). A modified version of the impinger method has beenmore » developed and does not require extensive reagent purification for formaldehyde analysis. Extremely low formaldehyde blanks have been obtained with the modified method. The HPLC conditions in the original method were used for chromatographic separations. The modified method results in a lower analytical uncertainty for the formaldehyde standard mixtures. Consequently, it is possible to discern small differences between analytical results that are important for stability study.« less

Optical Detection of Formaldehyde

NASA Technical Reports Server (NTRS)

Patty, Kira D.; Gregory, Don A.

2008-01-01

The potential for buildup .of formaldehyde in closed space environments poses a direct health hazard to personnel. The National Aeronautic Space Agency (NASA) has established a maximum permitted concentration of 0.04 ppm for 7 to 180 days for all space craft. Early detection is critical to ensure that formaldehyde levels do not accumulate. above these limits. New sensor technologies are needed to enable real time,in situ detection in a compact and reusable form factor. Addressing this need,research into the use of reactive fluorescent dyes which reversibly bind to formaldehyde (liquid or gas) has been conducted to support the development of a formaldehyde.sensor. In the presence of formaldehyde the dyes' characteristic fluorescence peaks shift providing the basis for an optical detection. Dye responses to formaldehyde exposure were characterized; demonstrating the optical detection of formaldehyde in under 10 seconds and down to concentrations of 0.5 ppm. To .incorporate the dye .in.an optical sensor device requires. a means of containing and manipulating the dye. Multiple form factors using two dissimilar sbstrates were considered to determine a suitable configuration. A prototype sensor was demonstrated and considerations for a field able sensor were presented. This research provides a necessary first step toward the development of a compact, reusable; real time optical formaldehyde sensor suitable for use in the U.S. space program,

78 FR 7464 - Large Scale Networking (LSN)-Middleware And Grid Interagency Coordination (MAGIC) Team

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-01

... Coordination (MAGIC) Team AGENCY: The Networking and Information Technology Research and Development (NITRD... (703) 292-4873. Date/Location: The MAGIC Team meetings are held on the first Wednesday of each month, 2... basis. WebEx participation is available for each meeting. Please reference the MAGIC Team Web site for...

Z3 -vertex magic total labeling and Z3 -edge magic total labelingfor the extended duplicate graph of quadrilateral snake

NASA Astrophysics Data System (ADS)

Indira, P.; Selvam, B.; Thirusangu, K.

2018-04-01

Based on the works of Kotzig, Rosa and MacDougall et.al., we present algorithms and prove the existence of Z3-vertex magic total labeling and Z3-edge magic total labeling for the extended duplicate graph of quadrilateral snake.

Relationships between magical thinking, obsessive-compulsiveness and other forms of anxiety in a sample of non-clinical children.

PubMed

Simonds, Laura M; Demetre, James D; Read, Cristina

2009-06-01

Despite the obvious phenomenological similarities between magical thinking and obsessive-compulsiveness, the relationship between them has been the subject of few empirical investigations in samples of children. The present study aimed to examine the relationship between a general epistemic stance towards magical causation and tendencies towards obsessive-compulsiveness in a non-clinical sample of schoolchildren. One-hundred and two children, aged between 5 and 10 years (48 boys and 54 girls), completed questionnaire measures designed to assess magical thinking, obsessive-compulsiveness, and other forms of anxiety. School teachers completed a measure of strengths and difficulties for each child. General belief in magical causation was correlated with all types of anxiety, not just obsessive-compulsiveness, with significant correlations shown for boys in the sample, but not girls. General belief in magical causation contributed little to the prediction of obsessive-compulsiveness beyond general anxiety. In this study, a general epistemic stance towards magical causation did not differentiate obsessive-compulsiveness from other anxiety dimensions. The findings are considered in the context of developmental theories of magical and scientific causal reasoning.

Indoor aldehydes concentration and emission rate of formaldehyde in libraries and private reading rooms

NASA Astrophysics Data System (ADS)

Kim, Jeonghoon; Kim, Seojin; Lee, Kiyoung; Yoon, Dongwon; Lee, Jiryang; Ju, DaeYoung

2013-06-01

Aldehydes are of particularly interest due to their potential adverse impact on human health. Formaldehyde is one of the most abundant indoor pollutants. To improve indoor air quality, identifying and removing the major emission sources of formaldehyde would be desirable. The purposes of this study were to determine aldehyde concentrations in libraries and reading rooms and to identify emission sources of formaldehyde in private reading rooms. Indoor aldehyde concentrations were quantified at 66 facilities, including public libraries, children's libraries, public reading rooms, and private reading rooms, in the Seoul metropolitan area. Emission fluxes of formaldehyde from the surfaces of desks, chairs, floors, walls, and ceilings in 19 private reading rooms were measured using a passive emission colorimetric sensor. Indoor aldehyde (formaldehyde, acetaldehyde, propioaldehyde, benzaldehyde, and hexaldehyde) levels were significantly higher than outdoor levels. Indoor formaldehyde geometric mean concentrations in private reading rooms (119.3 μg m-3) were significantly higher than in public libraries (29.2 μg m-3), children's libraries (29.3 μg m-3), and public reading rooms (40.8 μg m-3). Indoor formaldehyde levels were associated with relative humidity. In private reading rooms, the emission rates from desks (255.5 ± 214.8 μg h-1) and walls (231.7 ± 192.3 μg h-1) were significantly higher than that from chairs (79.6 ± 88.5 μg h-1). Desks (31%) and walls (29%) were the major emission sources of formaldehyde in 14 facilities in which measurements exceeded the indoor standard of 100 μg m-3. The age of interior materials was a significant factor for indoor formaldehyde emission flux. Controlling the emission rates of desks and walls is recommended to improve formaldehyde concentrations in private reading rooms.

Preliminary study: Formaldehyde exposure in laboratories of Sharjah university in UAE

PubMed Central

Ahmed, Hafiz Omer

2011-01-01

Objectives Laboratory technicians, students, and instructors are at high risk, because they deal with chemicals including formaldehyde. Thus, this preliminary study was conducted to measure the concentration of formaldehyde in the laboratories of the University of Sharjah in UAE. Materials and Methods: Thirty-two air samples were collected and analyzed for formaldehyde using National Institute for Occupational Safety and Health (NIOSH) method 3500. In this method, formaldehyde reacts with chromotropic acid in the presence of sulfuric acid to form a colored solution. The absorbance of the colored solution is read in spectrophotometer at wavelength 580 nm and is proportional to the quantity of the formaldehyde in the solution. Results: For the anatomy laboratory and in the presence of the covered cadaver, the mean concentration of formaldehyde was found to be 0.100 ppm with a range of 0.095–0.105 ppm. Whereas for the other laboratories, the highest mean concentration of formaldehyde was 0.024 ppm in the general microbiology laboratory and the lowest mean concentration of formaldehyde was 0.001 ppm in the environmental health laboratory. The 8-hour (time-weighted average) concentration of formaldehyde was found to be ranging between 0.0003 ppm in environmental health laboratory and 0.026 ppm in the anatomy laboratory. Conclusions: The highest level of concentration of formaldehyde in the presence of the covered cadaver in anatomy laboratory exceeded the recommended ceiling standard established by USA-NIOSH which is 0.1 ppm, but below the ceiling standard established by American Conference of Governmental Industrial Hygienists which is 0.3 ppm. Thus, it is recommended that formaldehyde levels should be measured periodically specially during the dissection in the anatomy laboratory, and local exhaust ventilation system should be installed and personal protective equipment such as safety glass and gloves should be available and be used to prevent direct skin or eye contact. PMID:21808499

40 CFR 721.3807 - Formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Formaldehyde, polymer with phenol and... Significant New Uses for Specific Chemical Substances § 721.3807 Formaldehyde, polymer with phenol and 1,2,3... chemical substance identified as formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated (PMN...

40 CFR 721.3807 - Formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Formaldehyde, polymer with phenol and... Significant New Uses for Specific Chemical Substances § 721.3807 Formaldehyde, polymer with phenol and 1,2,3... chemical substance identified as formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated (PMN...

Hardness evaluation of cured urea-formaldehyde resins with different formaldehyde/urea mole ratios using nanoindentation method

Treesearch

Byung-Dae Park; Charles R. Frihart; Yan Yu; Adya P. Singh

2013-01-01

To understand the influence of formaldehyde/urea (F/U) mole ratio on the properties of urea–formaldehyde (UF) resins, this study investigated hardness of cured UF resins with different F/U mole ratios using a nanoindentation method. The traditional Brinell hardness (HB) method was also used...

40 CFR 721.3807 - Formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Formaldehyde, polymer with phenol and... Significant New Uses for Specific Chemical Substances § 721.3807 Formaldehyde, polymer with phenol and 1,2,3... chemical substance identified as formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated (PMN...

40 CFR 721.3807 - Formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Formaldehyde, polymer with phenol and... Significant New Uses for Specific Chemical Substances § 721.3807 Formaldehyde, polymer with phenol and 1,2,3... chemical substance identified as formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated (PMN...

40 CFR 721.3807 - Formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Formaldehyde, polymer with phenol and... Significant New Uses for Specific Chemical Substances § 721.3807 Formaldehyde, polymer with phenol and 1,2,3... chemical substance identified as formaldehyde, polymer with phenol and 1,2,3-propanetriol, methylated (PMN...

40 CFR 721.10205 - Formaldehyde, polymer with 1,3-benzenediol and 1,1′-methylenebis[isocyanatobenzene].

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Formaldehyde, polymer with 1,3... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10205 Formaldehyde, polymer with 1,3... to reporting. (1) The chemical substance identified as formaldehyde, polymer with 1,3-benzenediol and...

Analyses of cocondensation of melamine and urea through formaldehyde with carbon 13 nuclear magnetic resonance spectroscopy

Treesearch

Tomita Bunchiro; Chung-Yun Hse

1995-01-01

The 13C-NMR (carbon 13 nuclear magnetic resonance) spectra of urea-formaldehyde (UF) resins, melamine-formaldehyde (MF) resins, and melamine-urea-formaldehyde (MUF) cocondensed resins synthesized under various conditions were taken with a frequency of 75 MHz. The main purpose was to investigate whether or not the occurrences of cocondensation...

Analysis of cocondensation of melamine and urea through formaldehyde with carbon 13 nuclear magnetic resonance spectroscopy

Treesearch

Bunichiro Tomita; Chung-Yun Hse

1995-01-01

The 13C-NMR (carbon 13 nuclear magnetic resonance) spectra of urea-formaldehyde (UF) resins, melamine-formaldehyde (MF) resins, and melamine-urea-formaldehyde (MUF) cocondensed resins synthesized under various conditions were taken with a frequency of 75 MHz. The main purpose was to investigate whether or not the occurrences of cocondensation...

Gypsum-wallboard formaldehyde-sorption model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Silberstein, S.

1989-11-01

Gypsum wallboard was shown to absorb formaldehyde in a prototype house and in a measuring chamber, as reported previously by researchers at Oak Ridge National Laboratory (ORNL). Also as reported previously, formaldehyde concentrations attained equilibrium in two phases in response to a change in the air exchange rate or to the removal of the formaldehyde source. A rapid initial phase was followed by a slow phase lasting several days. A formaldehyde sorption model that accounts for the biphasic concentration pattern is presented here. Experiments for testing the predictability of the model are proposed.

2,4 - dinitrophenylhydrazine - coated silica gel cartridge method for determination of formaldehyde in air: Identification of an ozone interference

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnts, R.R.; Tejada, S.B.

1989-01-01

Two versions of the 2,4-dinitrophenylhydrazine method, a coated silica gel cartridge (solid) and acetonitrile impinger (solvent based), were used simultaneously to sample varied concentrations of ozone (0-770 ppb) and formaldehyde (20-140 ppb). Ozone was found to be a negative interference in the determination of formaldehyde by the 2,4-dinitrophenylhydrazine-coated silica gel cartridge method. At 120 ppb of ozone, formaldehyde at 40 ppb was under-reported by the cartridge method by 34% and at 300 ppb of ozone, formaldehyde measurements were 61% low. Greater losses were seen at higher ozone concentrations. Impinger sampling (2,4-DNPH in acetonitrile) showed no formaldehyde losses due to ozone.

The Magic of Magic: The Effect of Magic Tricks on Subsequent Engagement with Lecture Material

ERIC Educational Resources Information Center

Moss, Simon A.; Irons, Melanie; Boland, Martin

2017-01-01

Background and aims: Lecturers often present entertaining videos, or organize a variety of amusing demonstrations, to foster student engagement or to encourage critical analysis. Magic tricks, in particular, have been shown to activate neural circuits that underpin motivation or problem-solving and, therefore, could be beneficial during lectures.…

Characterization of completely k-magic regular graphs

NASA Astrophysics Data System (ADS)

Eniego, A. A.; Garces, I. J. L.

2017-10-01

Let k ∈ ℕ and c ∈ ℤ k . A graph G is said to be c-sum k-magic if there is a labeling ℓ : E(G) → ℤ k {0} such that Σ u∈N(v) ℓ(uv) ≡ c (mod k) for every vertex v of G, where N(v) is the neighborhood of v in G. We say that G is completely k-magic whenever it is c-sum k-magic for every c ∈ ℤ k . In this paper, we characterize all completely k-magic regular graphs.

Atmospheric levels of aldehydes and BTEX and their relationship with vehicular fleet changes in Rio de Janeiro urban area.

PubMed

Martins, Eduardo Monteiro; Arbilla, Graciela; Bauerfeldt, Glauco Favilla; de Paula, Murilo

2007-05-01

A comprehensive monitoring campaign to assess aldehydes and BTEX concentrations was performed during 12 months, in the Tijuca district (Rio de Janeiro), an area with commercial activities and a high flux of vehicles. The mean concentrations of formaldehyde and acetaldehyde were 151 and 30 ppb, respectively. The high formaldehyde/acetaldehyde ratio was attributed to extensive use of compressed natural gas (CNG). The number of CNG vehicles in the metropolitan Region of Rio de Janeiro increased from 23000 in January 2001 to 161000 in January 2005. Monitoring data show that, for the same period, methane and formaldehyde concentrations increased while NO(x) and CO levels diminished. Mean concentrations for benzene, toluene, ethylbenzene, m,p-xylene and o-xylene, were 1.1, 4.8, 3.6, 10.4 and 3.0 micro gm(-3), respectively. Benzene and toluene concentrations were lower than the values determined in 1996, for the same location. The levels of ethylbenzene and xylenes determined in this work are similar to values obtained in 1996. This fact may be explained as a consequence of changes in the gasoline composition.

Low acetaldehyde collection efficiencies for 24-hour sampling with 2,4-dinitrophenylhydrazine (DNPH)-coated solid sorbents.

PubMed

Herrington, Jason S; Fan, Zhi-Hua Tina; Lioy, Paul J; Zhang, Junfeng Jim

2007-01-15

Airborne aldehyde and ketone (carbonyl) sampling methodologies based on derivatization with 2,4-dinitrophenylhydrazine (DNPH)-coated solid sorbents could unequivocally be considered the "gold" standard. Originally developed in the late 1970s, these methods have been extensively evaluated and developed up to the present day. However, these methods have been inadequately evaluated for the long-term (i.e., 24 h or greater) sampling collection efficiency (CE) of carbonyls other than formaldehyde. The current body of literature fails to demonstrate that DNPH-coated solid sorbent sampling methods have acceptable CEs for the long-term sampling of carbonyls other than formaldehyde. Despite this, such methods are widely used to report the concentrations of multiple carbonyls from long-term sampling, assuming approximately 100% CEs. Laboratory experiments were conducted in this study to evaluate the long-term formaldehyde and acetaldehyde sampling CEs for several commonly used DNPH-coated solid sorbents. Results from sampling known concentrations of formaldehyde and acetaldehyde generated in a dynamic atmosphere generation system demonstrate that the 24-hour formaldehyde sampling CEs ranged from 83 to 133%, confirming the findings made in previous studies. However, the 24-hour acetaldehyde sampling CEs ranged from 1 to 62%. Attempts to increase the acetaldehyde CEs by adding acid to the samples post sampling were unsuccessful. These results indicate that assuming approximately 100% CEs for 24-hour acetaldehyde sampling, as commonly done with DNPH-coated solid sorbent methods, would substantially under estimate acetaldehyde concentrations.

The Topo-trigger: a new concept of stereo trigger system for imaging atmospheric Cherenkov telescopes

NASA Astrophysics Data System (ADS)

López-Coto, R.; Mazin, D.; Paoletti, R.; Blanch Bigas, O.; Cortina, J.

2016-04-01

Imaging atmospheric Cherenkov telescopes (IACTs) such as the Major Atmospheric Gamma-ray Imaging Cherenkov (MAGIC) telescopes endeavor to reach the lowest possible energy threshold. In doing so the trigger system is a key element. Reducing the trigger threshold is hampered by the rapid increase of accidental triggers generated by ambient light (the so-called Night Sky Background NSB). In this paper we present a topological trigger, dubbed Topo-trigger, which rejects events on the basis of their relative orientation in the telescope cameras. We have simulated and tested the trigger selection algorithm in the MAGIC telescopes. The algorithm was tested using MonteCarlo simulations and shows a rejection of 85% of the accidental stereo triggers while preserving 99% of the gamma rays. A full implementation of this trigger system would achieve an increase in collection area between 10 and 20% at the energy threshold. The analysis energy threshold of the instrument is expected to decrease by ~ 8%. The selection algorithm was tested on real MAGIC data taken with the current trigger configuration and no γ-like events were found to be lost.

Improvements to the Magnetics Information Consortium (MagIC) Paleo and Rock Magnetic Database

NASA Astrophysics Data System (ADS)

Jarboe, N.; Minnett, R.; Tauxe, L.; Koppers, A. A. P.; Constable, C.; Jonestrask, L.

2015-12-01

The Magnetic Information Consortium (MagIC) database (http://earthref.org/MagIC/) continues to improve the ease of data uploading and editing, the creation of complex searches, data visualization, and data downloads for the paleomagnetic, geomagnetic, and rock magnetic communities. Online data editing is now available and the need for proprietary spreadsheet software is therefore entirely negated. The data owner can change values in the database or delete entries through an HTML 5 web interface that resembles typical spreadsheets in behavior and uses. Additive uploading now allows for additions to data sets to be uploaded with a simple drag and drop interface. Searching the database has improved with the addition of more sophisticated search parameters and with the facility to use them in complex combinations. A comprehensive summary view of a search result has been added for increased quick data comprehension while a raw data view is available if one desires to see all data columns as stored in the database. Data visualization plots (ARAI, equal area, demagnetization, Zijderveld, etc.) are presented with the data when appropriate to aid the user in understanding the dataset. MagIC data associated with individual contributions or from online searches may be downloaded in the tab delimited MagIC text file format for susbsequent offline use and analysis. With input from the paleomagnetic, geomagnetic, and rock magnetic communities, the MagIC database will continue to improve as a data warehouse and resource.

MagIC, a genetically encoded fluorescent indicator for monitoring cellular Mg2+ using a non-Förster resonance energy transfer ratiometric imaging approach

NASA Astrophysics Data System (ADS)

Koldenkova, Vadim Pérez; Matsuda, Tomoki; Nagai, Takeharu

2015-10-01

Intracellular Mg roles are commensurate with its abundance in the cell cytoplasm. However, little is known about Mg subcellular dynamics, primarily due to the lack of suitable Mg-selective tools to monitor this ion in intracellular compartments. To cope with this lack, we developed a Mg-sensitive indicator-MagIC (indicator for Magnesium Imaging in Cell) -composed of a functionalized yellow fluorescent protein (FP) variant fused to a red-emitting FP serving as a reference, thus allowing ratiometric imaging of Mg. MagIC expressed in mammalian cells is homogeneously distributed between the cytosol and nucleus but its fusion with appropriate targeting sequences redirects it to mitochondria or the endoplasmic reticulum. MagIC shows little interference by intracellular Ca [Kd(Mg2+)=5.1 mM Kd(Ca2+)=4.8 mM] and its kinetic properties (k=84 s-1) approach those of indicator dyes. With MagIC, as reported previously, we also observed a cytosolic Mg increase provoked by application of 50 mM MgCl2 in the medium. This effect is, however, mimicked by 75 mM KCl or 150 mM D-sorbitol addition, indicating that it is a response to the associated hyperosmotic shock and not to Mg itself. Our results confirm the functionality of MagIC as a useful tool for the long-awaited possibility of prolonged and organelle-specific monitoring of cellular Mg.

[Interactive augmented reality systems : Aid for personalized patient education and rehabilitation].

PubMed

Bork, F

2018-04-01

During patient education, information exchange plays a critical role both for patient compliance during medical or rehabilitative treatment and for obtaining an informed consent for an operative procedure. In this article the augmented reality system "Magic Mirror" as an additive tool during patient education, rehabilitation as well as anatomical education is highlighted. The Magic Mirror system allows the user of the system to inspect both a detailed model of the 3‑dimensional anatomy of the human body and volumetric slice images in a virtual mirror environment. First preliminary results from the areas of rehabilitation and learning anatomy indicate the broad potential of the Magic Mirror. Similarly, the system also provides interesting advantages for patient education situations in comparison to traditional methods of information exchange. Novel technologies, such as augmented reality are a door opener for many innovations in medicine. In the future, patient-specific systems, such as the Magic Mirror will be used increasingly more in areas such as patient education and rehabilitation. In order to maximize the benefits of such systems, further evaluation studies are necessary to find out about the best use cases and to start an iterative optimization process of these systems.

From MAGIC to CTA: the INAF participation to Cherenkov Telescopes experiments for very high energy astrophysics .

NASA Astrophysics Data System (ADS)

Antonelli, L. A.; INAF MAGIC Collaboration

The next decade can be considered the "golden age" of the Gamma Ray Astronomy with the two satellites for Gamma Ray Astronomy (AGILE and GLAST) in orbit. Therefore, thanks to many other X-ray experiments already in orbit (e.g. Swift, Chandra, NewtonXMM, etc.) it will be possible to image the Universe for the first time all over the electromagnetic spectrum almost contemporarily. The new generations of ground-based very high gamma-ray instruments are ready to extend the observed band also to the very high frequencies. Scientists from the Italian National Institute for Astrophysics (INAF) are involved in many, both space- and ground- based gamma ray experiments, and recently such an involvement has been largely improved in the field of the Imaging Atmospheric Cherenkov Telescopes (IACT). INAF is now member of the MAGIC collaboration and is participating to the realization of the second MAGIC telescope. MAGIC, as well other IACT experiments, is not operated as an observatory so a proper guest observer program does not exist. A consortium of European scientists (including INAF scientists) is thus now thinking to the design of a new research infrastructure: the Cherenkov Telescope Array (CTA). CTA is conceived to provide 10 times the sensitivity of current instruments, combined with increased flexibility and increased coverage from some 10 GeV to some 100 TeV. CTA will be operated as an observatory to serve a wider community of astronomer and astroparticle physicists.

Repair pathways independent of the Fanconi anemia nuclear core complex play a predominant role in mitigating formaldehyde-induced DNA damage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Noda, Taichi; Department of Dermatology, School of Medicine, Nara Medical University, 840 Shijo-cho, Kashihara, Nara 634-8521; Takahashi, Akihisa

2011-01-07

The role of the Fanconi anemia (FA) repair pathway for DNA damage induced by formaldehyde was examined in the work described here. The following cell types were used: mouse embryonic fibroblast cell lines FANCA{sup -/-}, FANCC{sup -/-}, FANCA{sup -/-}C{sup -/-}, FANCD2{sup -/-} and their parental cells, the Chinese hamster cell lines FANCD1 mutant (mt), FANCGmt, their revertant cells, and the corresponding wild-type (wt) cells. Cell survival rates were determined with colony formation assays after formaldehyde treatment. DNA double strand breaks (DSBs) were detected with an immunocytochemical {gamma}H2AX-staining assay. Although the sensitivity of FANCA{sup -/-}, FANCC{sup -/-} and FANCA{sup -/-}C{sup -/-}more » cells to formaldehyde was comparable to that of proficient cells, FANCD1mt, FANCGmt and FANCD2{sup -/-} cells were more sensitive to formaldehyde than the corresponding proficient cells. It was found that homologous recombination (HR) repair was induced by formaldehyde. In addition, {gamma}H2AX foci in FANCD1mt cells persisted for longer times than in FANCD1wt cells. These findings suggest that formaldehyde-induced DSBs are repaired by HR through the FA repair pathway which is independent of the FA nuclear core complex. -- Research highlights: {yields} We examined to clarify the repair pathways of formaldehyde-induced DNA damage. Formaldehyde induces DNA double strand breaks (DSBs). {yields} DSBs are repaired through the Fanconi anemia (FA) repair pathway. {yields} This pathway is independent of the FA nuclear core complex. {yields} We also found that homologous recombination repair was induced by formaldehyde.« less

Influence of indoor formaldehyde pollution on respiratory system health in the urban area of Shenyang, China.

PubMed

Zhai, L; Zhao, J; Xu, B; Deng, Y; Xu, Z

2013-03-01

The decoration of interior spaces can lead to dangerous levels of indoor formaldehyde pollution. Exposure to indoor air pollution may be responsible for nearly 2 million deaths per year in developing countries. To assess the prevalence of indoor formaldehyde pollution caused by decoration and resultant respiratory system symptoms exhibited in exposed adults and children, due to indoor formaldehyde pollution caused by decoration. Survey sites were chosen and indoor formaldehyde concentrations determined according to the standard of formaldehyde in GB50325-2001. Logistic regression models were used to derive odds ratios (ORs) and 95% confidence intervals (95% CIs) after adjusting for potential confounders for this survey. Formaldehyde concentration was above the standard in 64% of Shenyang City. Some adults surveyed complained of common respiratory system disorders, including coughing (11.8%), nasal irritation (39.2%), Heterosmia (14.51%), and throat irritation (25.27%); 12% of children suffered from asthma. The analysis identified formaldehyde pollution and ventilation frequency as risk factors for respiratory system disorders in both adults (OR=2.603, [95% CI: 1.770-3.828], OR=1.604, [95% CI: 1.146-2.244], respectively) and children (OR=4.250, [2.064-8.753], OR=1.831, [1.006-3.333], respectively). The prevalence of common respiratory system disorders was related both to formaldehyde pollution and insufficient ventilation after decorating.

Six years after the NRC review of EPA's Draft IRIS Toxicological Review of Formaldehyde: Regulatory implications of new science in evaluating formaldehyde leukemogenicity.

PubMed

Mundt, Kenneth A; Gentry, P Robinan; Dell, Linda D; Rodricks, Joseph V; Boffetta, Paolo

2018-02-01

Shortly after the International Agency for Research on Cancer (IARC) determined that formaldehyde causes leukemia, the United States Environmental Protection Agency (EPA) released its Draft IRIS Toxicological Review of Formaldehyde ("Draft IRIS Assessment"), also concluding that formaldehyde causes leukemia. Peer review of the Draft IRIS Assessment by a National Academy of Science committee noted that "causal determinations are not supported by the narrative provided in the draft" (NRC 2011). They offered recommendations for improving the Draft IRIS assessment and identified several important research gaps. Over the six years since the NRC peer review, significant new science has been published. We identify and summarize key recommendations made by NRC and map them to this new science, including extended analysis of epidemiological studies, updates of earlier occupational cohort studies, toxicological experiments using a sensitive mouse strain, mechanistic studies examining the role of exogenous versus endogenous formaldehyde in bone marrow, and several critical reviews. With few exceptions, new findings are consistently negative, and integration of all available evidence challenges the earlier conclusions that formaldehyde causes leukemia. Given formaldehyde's commercial importance, environmental ubiquity and endogenous production, accurate hazard classification and risk evaluation of whether exposure to formaldehyde from occupational, residential and consumer products causes leukemia are critical. Copyright © 2017 The Authors. Published by Elsevier Inc. All rights reserved.

Use of LC-MS/MS and Stable Isotopes to Differentiate Hydroxymethyl and Methyl DNA Adducts from Formaldehyde and Nitrosodimethylamine

PubMed Central

Lu, Kun; Craft, Sessaly; Nakamura, Jun; Moeller, Benjamin C.; Swenberg, James A.

2012-01-01

Formaldehyde is a known human and animal carcinogen that forms DNA adducts, and causes mutations. While there is widespread exposure to formaldehyde in the environment, formaldehyde is also an essential biochemical in all living cells. The presence of both endogenous and exogenous sources of formaldehyde makes it difficult to develop exposure-specific DNA biomarkers. Furthermore, chemicals such as nitrosodimethylamine form one mole of formaldehyde for every mole of methylating agent, raising questions about potential co-carcinogenesis. Formaldehyde-induced hydroxymethyl DNA adducts are not stable and need to be reduced to stable methyl adducts for detection, which adds another layer of complexity to identifying the origins of these adducts. In this study, highly sensitive mass spectrometry methods and isotope labeled compounds were used to differentiate between endogenous and exogenous hydroxymethyl and methyl DNA adducts. We demonstrate that N2-hydroxymethyl-dG is the primary DNA adduct formed in cells following formaldehyde exposure. In addition, we show that alkylating agents induce methyl adducts at N2-dG and N6-dA positions, which are identical to the reduced forms of hydroxymethyl adducts arising from formaldehyde. The use of highly sensitive LC-MS/MS and isotope labeled compounds for exposure solves these challenges and provides mechanistic insights on the formation and role of these DNA adducts. PMID:22148432

Cells deficient in the FANC/BRCA pathway are hypersensitive to plasma levels of formaldehyde.

PubMed

Ridpath, John R; Nakamura, Ayumi; Tano, Keizo; Luke, April M; Sonoda, Eiichiro; Arakawa, Hiroshi; Buerstedde, Jean-Marie; Gillespie, David A F; Sale, Julian E; Yamazoe, Mitsuyoshi; Bishop, Douglas K; Takata, Minoru; Takeda, Shunichi; Watanabe, Masami; Swenberg, James A; Nakamura, Jun

2007-12-01

Formaldehyde is an aliphatic monoaldehyde and is a highly reactive environmental human carcinogen. Whereas humans are continuously exposed to exogenous formaldehyde, this reactive aldehyde is a naturally occurring biological compound that is present in human plasma at concentrations ranging from 13 to 97 micromol/L. It has been well documented that DNA-protein crosslinks (DPC) likely play an important role with regard to the genotoxicity and carcinogenicity of formaldehyde. However, little is known about which DNA damage response pathways are essential for cells to counteract formaldehyde. In the present study, we first assessed the DNA damage response to plasma levels of formaldehyde using chicken DT40 cells with targeted mutations in various DNA repair genes. Here, we show that the hypersensitivity to formaldehyde is detected in DT40 mutants deficient in the BRCA/FANC pathway, homologous recombination, or translesion DNA synthesis. In addition, FANCD2-deficient DT40 cells are hypersensitive to acetaldehyde, but not to acrolein, crotonaldehyde, glyoxal, and methylglyoxal. Human cells deficient in FANCC and FANCG are also hypersensitive to plasma levels of formaldehyde. These results indicate that the BRCA/FANC pathway is essential to counteract DPCs caused by aliphatic monoaldehydes. Based on the results obtained in the present study, we are currently proposing that endogenous formaldehyde might have an effect on highly proliferating cells, such as bone marrow cells, as well as an etiology of cancer in Fanconi anemia patients.

Synthesis of phenol-urea-formaldehyde cocondensed resins from UF-concentrate and phenol

Treesearch

Bunchiro Tomita; Mashiko Ohyama; Chung-Yun Hse

1994-01-01

A new synthetic method to obtain phenol-urea-formaldehyde cocondensed resins was developed by reacting phenol with "UF-concentrate", which is a kind of urea-formaldehyde (UF) resin prepared with a high molar ratio of formaldehyde to urea (F/U) such as above 2.5. The products were analyzed with 13C-NMR spectroscopy and gel permeation...

IRIS Toxicological Review of Formaldehyde (Inhalation) ...

EPA Pesticide Factsheets

UPDATE EPA is currently revising its Integrated Risk Information System (IRIS) assessment of formaldehyde to address the 2011 NAS peer review recommendations. This assessment addresses both noncancer and cancer human health effects that are relevant to assessing the risks from chronic inhalation exposure to formaldehyde. To facilitate discussion of several scientific issues pertinent to the assessment, EPA convened a state-of-the-science workshop on April 30 and May 1, 2014. This workshop focused on the following three themes: Evidence pertaining to the influence of formaldehyde that is produced endogenously (by the body during normal biological processes) on the toxicity of inhaled formaldehyde, and implications for the health assessment; Mechanistic evidence relevant to formaldehyde inhalation exposure and lymphohematopoietic cancers (leukemia and lymphomas); and Epidemiological research examining the potential association between formaldehyde exposure and lymphohematopoietic cancers (leukemia and lymphomas). June 2010: EPA is conducting an independent expert peer review by the National Academy of Sciences and public comment of the scientific basis supporting the human health hazard and dose-response assessment of Formaldehyde-Inhalation that when finalized will appear on the Integrated Risk Information System (IRIS) database. This draft IRIS health assessment addresses both noncancer and cancer human health effects that may result from chronic inhal

Quantification of atmospheric formaldehyde by infrared absorption spectroscopy

NASA Astrophysics Data System (ADS)

Hoffnagle, John; Fleck, Derek; Rella, Chris; Kim-Hak, David

2017-04-01

Formaldehyde is a toxic, carcinogenic compound that can contaminate ambient air as a result of combustion or outgassing of commercial products such as adhesives used to fabricate plywood and to affix indoor carpeting. Like many small molecules, formaldehyde has an infrared absorption spectrum exhibiting bands of ro-vibrational transitions that are well resolved at low pressure and therefore well suited for optical analysis of formaldehyde concentration. We describe progress in applying cavity ring-down spectroscopy of the 2v5 band (the first overtone of the asymmetric C-H stretch, origin at 1770 nm) to the quantitative analysis of formaldehyde concentration in ambient air. Preliminary results suggest that a sensitivity of 1-2 ppb in a measurement interval of a few seconds, and 0.1-0.2 ppb in a few minutes, should be achievable with a compact, robust, and field-deployable instrument. Finally, we note that recent satellites monitoring snapshots of formaldehyde columns give insights into global formaldehyde production, migration and lifetime. The ability to monitor formaldehyde with a small and portable analyzer has the potential to aid in validation of these snapshots and to provide complementary data to show vertical dispersions with high spatial accuracy.

Aldehydes in passenger vehicles: An analysis of data from the RIOPA Study 1999-2001

NASA Astrophysics Data System (ADS)

Mapou, Ashley E. M.; Shendell, Derek G.; Therkorn, Jennifer H.; Xiong, Youyou; Meng, Qingyu; Zhang, Junfeng

2013-11-01

In-vehicle air quality (IVAQ) can be a major health concern due to factors such as urban sprawl and increased commuting time spent by individuals in vehicles. Few studies, particularly in the U.S., have considered in-vehicle toxic air contaminants, and none to date collected/analyzed field data in multiple communities across multiple climate zones. This study presents analyses of field data collected during the RIOPA Study from participating non-smoking adults for communities in Los Angeles County, CA, Elizabeth, NJ and Houston, TX. A significant difference (p < 0.001) in in-vehicle formaldehyde concentrations was observed, with the median concentration of in-vehicle formaldehyde in the CA communities about twice as high as in the NJ and TX communities. The highest median concentration of in-vehicle acetaldehyde was observed among the TX participants, over 40% higher than the overall study median. Given small sample sizes, the community (state) differences may be driven independently by differences in individual vehicle conditions and driving habits. Positive correlations were found between average community outdoor relative humidity in CA and NJ and in-vehicle formaldehyde and acetaldehyde concentrations. The amount of time car windows were reported as closed was inversely correlated with in-vehicle formaldehyde across study locations, and for in-vehicle acetaldehyde in CA and TX. Average wind speed and varying sky conditions also had suggested associations to in-vehicle formaldehyde and acetaldehyde. In CA and TX, 88% (7/8) of participants with a diagnosis of bronchitis reported at study baseline had in-vehicle formaldehyde concentrations greater than the overall study median. Every participant with diagnoses of both asthma and bronchitis (n = 3) reported at study baseline had in-vehicle formaldehyde and acetaldehyde concentrations above the overall study median; one participant in TX with two seasonal in-vehicle samplings had in-vehicle concentrations > 75th percentile. IVAQ during commuting may vary based on human behavior and meteorological factors. Additional studies are needed to further characterize ways to help reduce in-vehicle aldehyde exposures, especially for people with existing chronic respiratory illnesses who could experience symptom exacerbations upon such exposures.

Sleightly Persuasive: Using Magic To Teach Principles of Persuasion.

ERIC Educational Resources Information Center

Frasier, C. Jay

Magic can be used in the communication classroom as a means for introducing and/or illustrating the subject of persuasion. A magical effect which fools the class can lead to an early discussion of the need to be a critical consumer of persuasive messages. Magic can also be used to introduce the subject of ethics in persuasion. Each student can be…

Science meets magic: photonic metamaterials

NASA Astrophysics Data System (ADS)

Ozbay, Ekmel

2012-05-01

The word "magic" is usually associated with movies, fiction, children stories, etc. but seldom with the natural sciences. Recent advances in metamaterials have changed this notion, in which we can now speak of "almost magical" properties that scientists could only dream about only a decade ago. In this article, we review some of the recent "almost magical" progress in the field of meta-materials.

Science meets magic: photonic metamaterials

NASA Astrophysics Data System (ADS)

Ozbay, Ekmel

2012-03-01

The word "magic" is usually associated with movies, fiction, children stories, etc. but seldom with the natural sciences. Recent advances in metamaterials have changed this notion, in which we can now speak of "almost magical" properties that scientists could only dream about only a decade ago. In this article, we review some of the recent "almost magical" progress in the field of meta-materials.

Magical Ideation, Creativity, Handedness, and Cerebral Asymmetries: A Combined Behavioural and fMRI Study

ERIC Educational Resources Information Center

Badzakova-Trajkov, Gjurgjica; Haberling, Isabelle S.; Corballis, Michael C.

2011-01-01

Magical ideation has been shown to be related to measures of hand preference, in which those with mixed handedness exhibit higher levels of magical ideation than those with either consistent left- or right-handedness. It is unclear whether the relation between magical ideation and hand preference is the result of a bias in questionnaire-taking…

Compact Magic-T using microstrip-slotline transitions

NASA Technical Reports Server (NTRS)

U-Yen, Kongpop (Inventor); Wollack, Edward J. (Inventor); Doiron, Terence (Inventor); Moseley, Samuel H. (Inventor)

2010-01-01

The design of a compact low-loss Magic-T is described. The planar Magic-T incorporates a compact microstrip-slotline tee junction and small microstrip-slotline transition area to reduce slotline radiation. The Magic-T produces broadband in-phase and out-of-phase power combiner/divider responses, has low in-band insertion loss, and small in-band phase and amplitude imbalance.

[Study on the acquiring data time and intervals for measuring performance of air cleaner on formaldehyde].

PubMed

Tang, Zhigang; Wang, Guifang; Xu, Dongqun; Han, Keqin; Li, Yunpu; Zhang, Aijun; Dong, Xiaoyan

2004-09-01

The measuring time and measuring intervals to evaluate different type of air cleaner performance to remove formaldehyde were provided. The natural decay measurement and formaldehyde removal measurement were conducted in 1.5 m3 and 30 m3 test chamber. The natural decay rate was determined by acquiring formaldehyde concentration data at 15 minute intervals for 2.5 hours. The measured decay rate was determined by acquiring formaldehyde concentration data at 5 minute intervals for 1.2 hours. When the wind power of air cleaner is smaller than 30 m3/h or measuring performance of no wind power air clearing product, the 1.5 m3 test chamber can be used. Both the natural decay rate and the measured decay rate are determined by acquiring formaldehyde concentration data at 8 minute intervals for 64 minutes. There were different measuring time and measuring intervals to evaluate different type of air cleaner performance to remove formaldehyde.

Formaldehyde levels in traditional and portable classrooms: A pilot investigation

PubMed Central

2015-01-01

This pilot study assessed formaldehyde levels in portable classrooms (PCs) and traditional classrooms (TCs) and explored factors influencing indoor air quality (e.g., carbon dioxide (CO2), temperature, and relative humidity). In a cross-sectional design, we evaluated formaldehyde levels in day and overnight indoor air samples from nine PCs renovated within three years previously and three TCs in a school district in metropolitan Atlanta, Georgia. Formaldehyde levels ranged from 0.0068 to 0.038 ppm. In both type of classrooms, overnight formaldehyde median levels (PCs = 0.018 ppm; TCs = 0.019 ppm) were higher than day formaldehyde median levels (PCs = 0.011 ppm; TCs = 0.016 ppm). CO2 levels measured 470–790 parts per million (ppm) at 7AM and 470–1800 ppm at 4PM. Afternoon medians were higher in TCs (1,400 ppm ) than in PCs (780 ppm). Consistent with previous studies, formaldehyde levels were similar among PCs and TCs. Reducing CO2 levels by improving ventilation is recommended for classrooms. PMID:27197349

Magical ideation associated social cognition in adolescents: signs of a negative facial affect recognition deficit.

PubMed

Canli, Derya; Ozdemir, Hatice; Kocak, Orhan Murat

2015-08-01

Studies provide evidence for impaired social cognition in schizotypy and its association with negative symptoms. Cognitive features related to magical ideation - a component of the positive dimension of schizotypy - have been less investigated. We aimed to assess social cognitive functioning among adolescents with high magical ideation scores, mainly focusing on face and emotion recognition. 22 subjects with magical ideation scale scores above the cut off level and 22 controls with lowest scores from among 250 students screened with this scale were included in the study. A face and emotion recognition n-back test, the empathy quotient, theory of mind tests and the Physical Anhedonia Scale were applied to both magical ideation and control groups. The magical ideation group performed significantly worse than controls on both face and emotion recognition tests. Emotion recognition performance was found to be affected by memory load, with sadness, among emotions, revealing a difference between the two groups. Empathy and theory of mind tests did not distinguish the magical ideation group from controls. Our findings provide evidence for a deficit in negative emotion recognition affected by memory load associated with magical ideation in adolescents. Copyright © 2015 Elsevier Inc. All rights reserved.

Magical ideation, creativity, handedness, and cerebral asymmetries: a combined behavioural and fMRI study.

PubMed

Badzakova-Trajkov, Gjurgjica; Häberling, Isabelle S; Corballis, Michael C

2011-08-01

Magical ideation has been shown to be related to measures of hand preference, in which those with mixed handedness exhibit higher levels of magical ideation than those with either consistent left- or right-handedness. It is unclear whether the relation between magical ideation and hand preference is the result of a bias in questionnaire-taking behaviour or of some neuropsychological concomitant of cerebral specialization. We sought to replicate this finding and further investigate how magical ideation is related to other measures of laterality, including handedness based on finger-tapping performance, and cerebral asymmetries for language, spatial judgment, and face processing as revealed by fMRI. Creative achievement was also assessed by questionnaire and correlated with magical ideation and the other measures. Magical ideation and creativity were positively correlated, and both were negatively correlated with absolute hand preference but not with hand performance or with any of the cerebral asymmetries being assessed. The results do not support the notion that the observed association between magical ideation, creativity and hand preference has a neuropsychological explanation based on reduced cerebral lateralization. Copyright © 2011 Elsevier Ltd. All rights reserved.

Isocyanate and total inhalable particulate air measurements in the European wood panel industry.

PubMed

Vangronsveld, E; Berckmans, S; Verbinnen, K; Van Leeuw, C; Bormans, C

2010-11-01

It is well known that the use of MDI (methylene diphenyldiisocyanate) as an alternative for formaldehyde-based resins is seen as a responsible option to reduce formaldehyde emissions for CWP (Composite Wood Products) in buildings. However, there are concerns raised regarding the exposure risk of workers. The purpose of this article is to provide the reader with factual information to demonstrate that the use of MDI compared to other agents used in CWP production processes does not pose increased inhalation exposure risks for workers. Personal and area air measurements were carried out at nine Composite Wood Panel plants throughout Europe to assess potential inhalation exposures to MDI and wood dust as Total Inhalable Particulates (TIP). In total, 446 pairs of samples were collected for MDI and TIP of which 283 pairs were personal samples and the remaining 163 pairs were area samples collected at key locations along the production line. This data together with published formaldehyde exposure data has been used to evaluate the exposure safety margin opposite what are considered relevant occupational exposure limits. The methods used for sampling and analysing MDI and TIP are based on internationally accepted methods, i.e. MDHS 25/3 (or ISO 16702) for MDI, and MDHS 14/3 for TIP. The job functions with an increased exposure profile for TIP were the cleaners, drying operators and quality control staff, and for MDI, the cleaners and quality control staff. The areas with an increased exposure profile for TIP are the conveyor area from OSB blender to former area and the OSB press infeed, and for MDI the OSB weigh belt and OSB former bin area. The exposure safety margin opposite the selected exposure limits can be ranked as MDI>TIP>formaldehyde (high margin of safety to low margin of safety), indicating that the use of MDI also reduces the exposure risks to workers during production of CWP compared to formaldehyde. By reducing the airborne TIP concentrations, a respiratory sensitiser, MDI workplace concentrations in general can be reduced further. This can be achieved by improving design and/or maintenance and testing programmes of existing control measures, which should be in place already to effectively control exposure to TIP and formaldehyde. The airborne concentration of MDI at workstations situated after pressing (curing) is regarded as extremely low and likely mainly constituted by workplace emissions from elsewhere in the plant. Copyright © 2010 Elsevier GmbH. All rights reserved.

40 CFR 86.542-90 - Records required.

Code of Federal Regulations, 2013 CFR

2013-07-01

... formaldehyde sampling system. (6) The formaldehyde calibration information from the HPLC standards. (7) The concentration of the HPLC analysis of the test sample (formaldehyde). (q) Additional required records for...

40 CFR 86.542-90 - Records required.

Code of Federal Regulations, 2014 CFR

2014-07-01

... formaldehyde sampling system. (6) The formaldehyde calibration information from the HPLC standards. (7) The concentration of the HPLC analysis of the test sample (formaldehyde). (q) Additional required records for...

40 CFR 86.542-90 - Records required.

Code of Federal Regulations, 2011 CFR

2011-07-01

... formaldehyde sampling system. (6) The formaldehyde calibration information from the HPLC standards. (7) The concentration of the HPLC analysis of the test sample (formaldehyde). (q) Additional required records for...

40 CFR 86.542-90 - Records required.

Code of Federal Regulations, 2012 CFR

2012-07-01

... formaldehyde sampling system. (6) The formaldehyde calibration information from the HPLC standards. (7) The concentration of the HPLC analysis of the test sample (formaldehyde). (q) Additional required records for...

Novel reaction of N,N'-bisarylmethanediamines with formaldehyde. Synthesis of some new 1,3,5-triaryl-1,3,5-hexahydrotriazines.

PubMed

Ghandi, Mehdi; Salimi, Farshid; Olyaei, Abolfazl

2006-07-26

The acid-catalyzed cyclocondensation of N,N'-bisaryl (aryl = 2-pyrimidinyl, 2-pyrazinyl and 4-nitrophenyl) methanediamines 5a-c with aqueous formaldehyde in refluxing acetonitrile leads to the formation of the corresponding 1,3,5-triaryl-1,3,5-hexa-hydrotriazines 6a-c. The stoichiometric reactions of 2-aminopyrimidine and 2-amino-pyrazine with aqueous formaldehyde in acetonitrile under reflux conditions also afforded 6a and 6b, respectively. Treatment of 2-aminopyrimidine with aqueous formaldehyde in a 3:2 ratio yielded N,N',N"-tris(2-pyrimidinyl)dimethylenetriamine (7a) as a sole product, which upon subsequent reaction with formaldehyde also afforded 6a. The reaction of N,N'-biphenylmethanediamine with formaldehyde was also investigated.

Carbonyl compound emissions from a heavy-duty diesel engine fueled with diesel fuel and ethanol-diesel blend.

PubMed

Song, Chonglin; Zhao, Zhuang; Lv, Gang; Song, Jinou; Liu, Lidong; Zhao, Ruifen

2010-05-01

This paper presents an investigation of the carbonyl emissions from a direct injection heavy-duty diesel engine fueled with pure diesel fuel (DF) and blended fuel containing 15% by volume of ethanol (E/DF). The tests have been conducted under steady-state operating conditions at 1200, 1800, 2600 rpm and idle speed. The experimental results show that acetaldehyde is the most predominant carbonyl, followed by formaldehyde, acrolein, acetone, propionaldehyde and crotonaldehyde, produced from both fuels. The emission factors of total carbonyls vary in the range 13.8-295.9 mg(kWh)(-1) for DF and 17.8-380.2mg(kWh)(-1) for E/DF, respectively. The introduction of ethanol into diesel fuel results in a decrease in acrolein emissions, while the other carbonyls show general increases: at low engine speed (1200 rpm), 0-55% for formaldehyde, 4-44% for acetaldehyde, 38-224% for acetone, and 5-52% for crotonaldehyde; at medium engine speed (1800 rpm), 106-413% for formaldehyde, 4-143% for acetaldehyde, 74-113% for acetone, 114-1216% for propionaldehyde, and 15-163% for crotonaldehyde; at high engine speed (2600 rpm), 36-431% for formaldehyde, 18-61% for acetaldehyde, 22-241% for acetone, and 6-61% for propionaldehyde. A gradual reduction in the brake specific emissions of each carbonyl compound from both fuels is observed with increase in engine load. Among three levels of engine speed employed, both DF and E/DF emit most CBC emissions at high engine speed. On the whole, the presence of ethanol in diesel fuel leads to an increase in aldehyde emissions. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

Old and New Magic Numbers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Talmi, Igal

2008-11-11

The discovery of magic numbers led to the shell model. They indicated closure of major shells and are robust: proton magic numbers are rather independent of the occupation of neutron orbits and vice versa. Recently the magic property became less stringent and we hear a lot about the discovery of new magic numbers. These, however, indicate sub-shell closures and strongly depend on occupation numbers and hence, may be called quasi-magic numbers. Some of these have been known for many years and the mechanism for their appearance as well as disappearance, was well understood within the simple shell model. The situationmore » will be illustrated by a few examples which demonstrate the simple features of the shell model. Will this simplicity emerge from the complex computations of nuclear many-body theory?.« less

Acute airway effects of airborne formaldehyde in sensitized and non-sensitized mice housed in a dry or humid environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Larsen, Søren Thor, E-mail: stl@nrcwe.dk; Wolkoff, Peder, E-mail: pwo@nrcwe.dk; Hammer, Maria, E-mail: mha@nrcwe.dk

We investigated the role of air humidity and allergic sensitization on the acute airway response to inhaled formaldehyde (FA) vapor. Mice were sensitized to the immunogen ovalbumin (OVA) by three intraperitoneal injections followed by two aerosol challenges, giving rise to allergic airway inflammation. Control mice were sham sensitized by saline injections and challenged by saline aerosols. Once sensitized, the mice were housed at high (85–89%) or low (< 10%) relative humidity, respectively for 48 h prior to a 60-min exposure to either 0.4, 1.8 or about 5 ppm FA. Before, during and after exposure, breathing parameters were monitored. These includedmore » the specific markers of nose and lung irritations as well as the expiratory flow rate, the latter being a marker of airflow limitation. The sensory irritation response in the upper airways was not affected by allergic inflammation or changes in humidity. At high relative humidity, the OVA-sensitized mice had a decreased expiratory airflow rate compared to the saline control mice after exposure to approximately 5 ppm FA. This is in accordance with the observations that asthmatics are more sensitive than non-asthmatics to higher concentrations of airway irritants including FA. In the dry environment, the opposite trend was seen; here, the saline control mice had a significantly decreased expiratory airflow rate compared to OVA-sensitized mice when exposed to 1.8 and 4 ppm FA. We speculate that increased mucus production in the OVA-sensitized mice has increased the “scrubber effect” in the nose, consequently protecting the conducting and lower airways. - Highlights: ► Role of air humidity and allergy on sensitivity to an airway irritant was studied. ► In the humid environment, allergy amplified the effects of formaldehyde. ► In the dry environment, allergy reduced the effect of formaldehyde. ► Neither allergy nor humidity changed the formaldehyde-induced nasal irritation.« less

The magic words: Using computers to uncover mental associations for use in magic trick design.

PubMed

Williams, Howard; McOwan, Peter W

2017-01-01

The use of computational systems to aid in the design of magic tricks has been previously explored. Here further steps are taken in this direction, introducing the use of computer technology as a natural language data sourcing and processing tool for magic trick design purposes. Crowd sourcing of psychological concepts is investigated; further, the role of human associative memory and its exploitation in magical effects is explored. A new trick is developed and evaluated: a physical card trick partially designed by a computational system configured to search for and explore conceptual spaces readily understood by spectators.

Melamine-bridged alkyl resorcinol modified urea - formaldehyde resin for bonding hardwood plywood

Treesearch

Chung-Yun Hse; Mitsuo Higuchi

2010-01-01

A powdery product was obtained by the reaction of methylolated melamine with alkyl resorcinols to form melamine-bridged alkyl resorcinols (MARs). The effects of the addition of this powder on the bonding strength and formaldehyde emission of urea–formaldehyde (UF) resins were investigated. Three types of UF resins with a formaldehyde/urea molar ratio of 1.3 synthesized...

Two-photon imaging of formaldehyde in live cells and animals utilizing a lysosome-targetable and acidic pH-activatable fluorescent probe.

PubMed

Xie, Xilei; Tang, Fuyan; Shangguan, Xiaoyan; Che, Shiyi; Niu, Jinye; Xiao, Yongsheng; Wang, Xu; Tang, Bo

2017-06-13

Lyso-TPFP presents lysosomal targetability and an acidic pH-activatable response toward formaldehyde. Thus, it exclusively visualizes lysosomal formaldehyde and is immune against it in neutral cytosol and other organelles. In addition, two-photon fluorescence imaging endows Lyso-TPFP with the capability of in situ tracking formaldehyde in live cells and animals.

How mole ratio of UF resin affects formaldehyde emission and other properties : a literature critique

Treesearch

George E. Myers

1984-01-01

A critical review was made of the literature concerned with how the formaldehyde to urea mole ratio (F/U) affects formaldehyde emission from particleboard and plywood bonded with urea-formaldehyde (UF) adhesives, and how this ratio affects certain other adhesive and board properties. It is difficult to quantify the dependence of various properties on mole ratio or...

Mathematical Construction of Magic Squares Utilizing Base-N Arithmetic

ERIC Educational Resources Information Center

O'Brien, Thomas D.

2006-01-01

Magic squares have been of interest as a source of recreation for over 4,500 years. A magic square consists of a square array of n[squared] positive and distinct integers arranged so that the sum of any column, row, or main diagonal is the same. In particular, an array of consecutive integers from 1 to n[squared] forming an nxn magic square is…

Magical ideation -- defense mechanism or neuropathology? A study with multiple sclerosis patients.

PubMed

te Wildt, Bert Theodor; Schultz-Venrath, Ulrich

2004-01-01

The major psychological stress factor in multiple sclerosis (MS) is loss of control of life. In MS patients with impaired cognition, magical ideation might be a characteristic way of thinking. Proof for this may be the high frequency of alternative treatments used by individuals with MS. The study investigates whether the level of magical ideation in MS patients is higher compared to healthy control subjects and, in case of positive confirmation, with which somatic and psychological features it is associated. Moreover, it is aimed to discuss the modalities of magical ideation in general. A German version of the Magical Ideation Scale was validated with a group of 69 healthy subjects. Ninety-four MS patients were additionally assessed with the Dissociative Experience Scale, the Symptom-Check-List-90-Revised and 5 neuropsychological tests. The Magical Ideation Scale did not reveal a significant difference between MS patients and healthy controls (p = 0.968). Among the MS patients, magical ideation shows a correlation neither with age nor with disability, but a positive correlation (p = 0.007; r = 0.329) with the grade of neuropsychological deficiency. Among the psychological parameters, the highest positive correlation with magical ideation was found in dissociation (p = 0.000; r = 0.520). Magical ideation, sharing common features with dissociation, can be viewed as an early defense mechanism when perceiving a loss of control of life, particularly in early stages of MS. In late stages, when developing neuropsychological deficits, it may occur as a substitute for cognitive coping. The data may encourage clinicians to identify magical ideation. In young and previously diagnosed patients, it is important to acknowledge helplessness and support a rather rational way of coping. Training cognitive skills could be crucial to prevent older patients from losing touch with reality. More generally, the occurrence of a significant amount of magical ideation is discussed both as a psychological and a neurophysiologic regression of thinking. Copyright 2004 S. Karger AG, Basel

Quantification of free formaldehyde in carrageenan and processed Eucheuma seaweed using high-performance liquid chromatography.

PubMed

Hornshøj, Bettina Høj; Kobbelgaard, Sara; Blakemore, William R; Stapelfeldt, Henrik; Bixler, Harris J; Klinger, Markus

2015-01-01

In 2010 the European Commission placed a limit on the amount of free formaldehyde in carrageenan and processed Eucheuma seaweed (PES) of 5 mg kg(-1). Formaldehyde is not used in carrageenan and PES processing and accordingly one would not expect free formaldehyde to be present in carrageenan and PES. However, surprisingly high levels up to 10 mg kg(-1) have been found using the generally accepted AOAC and Hach tests. These findings are, per proposed reaction pathways, likely due to the formation of formaldehyde when sulphated galactose, the backbone of carrageenan, is hydrolysed with the strong acid used in these conventional tests. In order to minimise the risk of false-positives, which may lead to regulatory non-compliance, a new high-performance liquid chromatography (HPLC) method has been developed. Initially, carrageenan or PES is extracted with 2-propanol and subsequently reacted with 2,4-dinitrophenylhydrazine (DNPH) to form the chromophore formaldehyde-DNPH, which is finally quantified by reversed-phase HPLC with ultraviolet light detection at 355 nm. This method has been found to have a limit of detection of 0.05 mg kg(-1) and a limit of quantification of 0.2 mg kg(-1). Recoveries from samples spiked with known quantities of formaldehyde were 95-107%. Using this more specific technique, 20 samples of carrageenan and PES were tested for formaldehyde. Only one sample had a detectable content of formaldehyde (0.40 mg kg(-1)), thus demonstrating that the formaldehyde content of commercial carrageenan and PES products are well below the European Commission maximum limit of 5 mg kg(-1).

Children's and adults' reactions to magical and ordinary suggestion: are suggestibility and magical thinking psychologically close relatives?

PubMed

Subbotsky, Eugene

2007-11-01

In Experiment 1, 6- and 9-year-old children and adults were asked to imagine various types of objects. The experimenter then attempted to change the image of those objects in participants' minds by either suggesting that the objects may change against the participants' will, or by asking participants to change the objects as a favor to the experimenter. Two types of suggestive causation were employed: Magical-suggestion (a magic spell was cast with the aim of changing the imagined objects) and ordinary-suggestion (participants were told that the objects in their minds could alter against their will). Ordinary-suggestion was as effective as magical-suggestion in changing the participants' imagined objects. For adults, a direct request for compliance produced a stronger effect than did magical suggestion. This effect was not found in children. In Experiment 2, the two types of suggestion were tested on an alternative type of imagined objects. Adult participants were asked to imagine their futures. It was then proposed that (a) a magic spell could be cast on their futures with the aim of changing them either for the worse or for the better (magical-suggestion), or (b) changing a numerical pattern on a computer screen could change their futures (ordinary-suggestion). All participants denied that changing a numerical pattern on a computer screen could affect their lives, yet in their actions they demonstrated an element of belief in this possibility. As in Experiment 1, in Experiment 2 ordinary suggestion was as effective as magical suggestion. The hypothesis of an historic contiguity between magical causality and ordinary suggestion is discussed.

A Robust Static Headspace GC-FID Method to Detect and Quantify Formaldehyde Impurity in Pharmaceutical Excipients

PubMed Central

Al-Khayat, Mohammad Ammar; Karabet, Francois; Al-Mardini, Mohammad Amer

2018-01-01

Formaldehyde is a highly reactive impurity that can be found in many pharmaceutical excipients. Trace levels of this impurity may affect drug product stability, safety, efficacy, and performance. A static headspace gas chromatographic method was developed and validated to determine formaldehyde in pharmaceutical excipients after an effective derivatization procedure using acidified ethanol. Diethoxymethane, the derivative of formaldehyde, was then directly analyzed by GC-FID. Despite the simplicity of the developed method, however, it is characterized by its specificity, accuracy, and precision. The limits of detection and quantification of formaldehyde in the samples were of 2.44 and 8.12 µg/g, respectively. This method is characterized by using simple and economic GC-FID technique instead of MS detection, and it is successfully used to analyze formaldehyde in commonly used pharmaceutical excipients. PMID:29686930

Biological indicators for low temperature steam and formaldehyde sterilization: investigation of the effect of change in temperature and formaldehyde concentration on spores of Bacillus stearothermophilus NCIMB 8224.

PubMed

Wright, A M; Hoxey, E V; Soper, C J; Davies, D J

1996-03-01

Five strains of Bacillus stearothermophilus have been studied to identify a spore strain to be used as a biological indicator organism for low temperature steam and formaldehyde sterilization. Three strains gave poor reproducibility of batch size and growth index and were discarded. The other two strains gave good reproducibility with a high growth index and gave rise to linear survivor curves when exposed to 5% aqueous formaldehyde. However, only NCIMB 8224 sporulates on a simpler medium and as it was the most resistant to formaldehyde, it was further studied. Tests were carried out in a modified miniclave and factors studied included temperature of the steam and formaldehyde concentration. All studies confirmed the suitability of this strain as a biological indicator organism.

Monitoring of formaldehyde in air

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balmat, J.L.; Meadows, G.W.

1985-10-01

Any one of several monitoring methods, depending on requirement and circumstance, can be used to measure employee exposure to formaldehyde. Ordinarily, monitoring at DuPont is performed by sampling with impingers containing 1% aqueous sodium bisulfite or with silica gel tubes. The collected formaldehyde is measured spectrophotometrically after reaction with chromotropic acid. Results from studies on a selected number of formaldehyde monitoring methods reveal that reliable methods are available for area and personnel monitoring over both short term and long term. Accurate results are obtained from short-term monitoring (15 min at 1 L/min) with impingers of formaldehyde concentrations as low asmore » 0.14 ppm. The current studies show that long-term monitoring (8 hr at 0.5 L/min) can be performed accurately at concentrations as low as 0.05 ppm. Accurate results also are obtained from short-term monitoring (15 min at 500 mL/min) with silica gel tubes of concentrations as low as 0.11 ppm formaldehyde. Passive monitors provide the most convenient means of obtaining 8-hour time-weighted average (TWA) data. The Pro-Tek Formaldehyde Badge was demonstrated to reliably monitor formaldehyde concentrations varying from 0-0.5 ppm or 0-3 ppm. Investigation of the Lion Formaldemeter disclosed that instantaneous and accurate (+/- 5%) measurement of formaldehyde in air can be made over a concentration range of 0.3-5 ppm in the absence of other substances that are oxidizable in its fuel cell detector.« less

A Note on Magic Squares

ERIC Educational Resources Information Center

Williams, Horace E.

1974-01-01

A method for generating 3x3 magic squares is developed. A series of questions relating to these magic squares is posed. An invesitgation using matrix methods is suggested with some questions for consideration. (LS)

The Versatile Magic Square.

ERIC Educational Resources Information Center

Watson, Gale A.

2003-01-01

Demonstrates the transformations that are possible to construct a variety of magic squares, including modifications to challenge students from elementary grades through algebra. Presents an example of using magic squares with students who have special needs. (YDS)

The Fracture of Thermosetting Resins after Exposure to Water.

DTIC Science & Technology

1980-09-01

formaldehyde , urea - formaldehyde and melamine - formaldehyde resins , epoxides, unsaturated polyesters, diallyl phthalate resins , furanes and certain kinds...linked phenol- formaldehyde (27) and epoxy resins (22), but some work on the fracture surfaces of polyesters with varying flexibiliser additions has been...AO0-A099 975 KINGSTON POLYTECHNIC KINGSTON UPON THAMES (ENGLAND) F/G 11/9 THE FRACTURE OF THERMOSETTING RESINS AFTER EXPOSURE TO WATER.(U) SEP 80 6

Development of melamine modified urea formaldehyde resins based o nstrong acidic pH catalyzed urea formaldehyde polymer

Treesearch

Chung-Yun Hse

2009-01-01

To upgrade the performance of urea-formaldehyde (UF) resin bonded particleboards, melamine modified urea-formaldehyde (MUF) resins based on strong acidic pH catalyzed UF polymers were investigated. The study was conducted in a series of two experiments: 1) formulation of MUF resins based on a UF polymer catalyzed with strong acidic pH and 2) determination of the...

Final Cassini RADAR Observation of Titan's Magic Island Region and Ligeia Mare

NASA Astrophysics Data System (ADS)

Hofgartner, J. D.; Hayes, A.; Lunine, J. I.; Stiles, B. W.; Malaska, M. J.; Wall, S. D.

2017-12-01

Cassini arrived in the Saturn system shortly after the Oct. 2002 northern winter solstice and the mission will end shortly after the May 2017 northern summer solstice. A main objective of the Cassini Solstice mission is to study seasonal and temporal changes and at Titan this includes changes of the hydrocarbon lakes/seas. Titan's Magic Islands are transient bright features in the north polar sea, Ligeia Mare that were observed to be temporal changes in Cassini RADAR images. The Magic Islands were discovered in a July 2013 image as anomalously bright features that were not present in four previous observations from Feb. 2007 - May 2013. The region of the Magic Islands was again anomalously bright in an Aug. 2014 image and the total areal extent of the anomalously bright region had increased by more than a factor of three. The transient features were not, however, observed in a Jan. 2015 image. Thus in seven observations spanning much of the Cassini mission the bright features were observed to appear, increase in extent, and then disappear. They are referred to as Titan's Magic Islands because of their appearing/disappearing behavior and resemblance in appearance to islands. These transient bright features are not actually islands. The transients were concluded to be most consistent with waves, floating solids, suspended solids, and bubbles. Tides, sea level changes, and seafloor changes are unlikely to be the primary cause of these temporal changes. Whether these temporal changes are also seasonal changes was unclear. The final Cassini RADAR imaging observation of Titan in Apr. 2017 included the region of the Magic Islands. The transient bright features were not present during this observation. The geometry of the observation was such that, had the transients been present, their brightness may have ruled out some of the remaining hypotheses. Their absence however, is less constraining but consistent with their transient nature. Waves, floating solids, suspended solids, and bubbles remain the most likely hypotheses. Other regions of Ligeia Mare were also imaged in the Apr. 2017 observation and no transient features were observed elsewhere in the sea. The specific process responsible for these transient features and the role of seasonal changes in their appearance and disappearance remains an open research question.

Differential network analysis reveals the genome-wide landscape of estrogen receptor modulation in hormonal cancers

PubMed Central

Hsiao, Tzu-Hung; Chiu, Yu-Chiao; Hsu, Pei-Yin; Lu, Tzu-Pin; Lai, Liang-Chuan; Tsai, Mong-Hsun; Huang, Tim H.-M.; Chuang, Eric Y.; Chen, Yidong

2016-01-01

Several mutual information (MI)-based algorithms have been developed to identify dynamic gene-gene and function-function interactions governed by key modulators (genes, proteins, etc.). Due to intensive computation, however, these methods rely heavily on prior knowledge and are limited in genome-wide analysis. We present the modulated gene/gene set interaction (MAGIC) analysis to systematically identify genome-wide modulation of interaction networks. Based on a novel statistical test employing conjugate Fisher transformations of correlation coefficients, MAGIC features fast computation and adaption to variations of clinical cohorts. In simulated datasets MAGIC achieved greatly improved computation efficiency and overall superior performance than the MI-based method. We applied MAGIC to construct the estrogen receptor (ER) modulated gene and gene set (representing biological function) interaction networks in breast cancer. Several novel interaction hubs and functional interactions were discovered. ER+ dependent interaction between TGFβ and NFκB was further shown to be associated with patient survival. The findings were verified in independent datasets. Using MAGIC, we also assessed the essential roles of ER modulation in another hormonal cancer, ovarian cancer. Overall, MAGIC is a systematic framework for comprehensively identifying and constructing the modulated interaction networks in a whole-genome landscape. MATLAB implementation of MAGIC is available for academic uses at https://github.com/chiuyc/MAGIC. PMID:26972162

Optimization of formaldehyde concentration on electroless copper deposition on alumina surface

NASA Astrophysics Data System (ADS)

Shahidin, S. A. M.; Fadil, N. A.; Yusop, M. Zamri; Tamin, M. N.; Osman, S. A.

2018-05-01

The effect of formaldehyde concentration on electroless copper plating on alumina wafer was studied. The main composition of plating bath was copper sulphate (CuSO4) as precursor and formaldehyde as a reducing agent. The copper deposition films were assessed by varying the ratio of CuSO4 and formaldehyde. The plating rate was calculated from the weight gained after plating process whilst the surface morphology was observed by field emission scanning electron microscopy (FESEM). The results show that 1:3 ratio of copper to formaldehyde is an optimum ratio to produce most uniform coating with good adhesion between copper layer and alumina wafer substrate.

The tropospheric distribution of formaldehyde

NASA Astrophysics Data System (ADS)

Lowe, D. C.; Schmidt, U.; Ehhalt, D. H.

1981-12-01

A measurement technique for determining the very low formaldehyde concentrations in clean air is described. The method is based on the standard derivation of formaldehyde with 2,4-dinitrophenylhydrazine. The derivative is separated, using high performance liquid chromatography, and detected at 254 nm with a conventional UV absorption detector. The sampling and analysis technique was used to measure tropospheric mixing ratios at various places in Europe and New Zealand as well as during a cruise in the North and South Atlantic. The results of the measurements show that formaldehyde mixing ratios in clean air are very low. In clean maritime air no significant difference in the formaldehyde mixing ratio between the hemispheres is observed.

Release rate of diazinon from microcapsule based on melamine formaldehyde

NASA Astrophysics Data System (ADS)

Noviana Utami C., S.; Rochmadi

2018-04-01

The microcapsule containing diazinon as the core material and melamine formaldehyde as the membrane material have been synthesized by in situ polymerization method. The microcapsule membrane in this research is melamine formaldehyde (MF). This research aims to study the effect of pH and temperature on the release rate of diazinon from microcapsule based on melamine formaldehyde in aqueous medium. The results showed that pH and temperature has little effect on the release rate of diazinon from microcapsule based on melamine formaldehyde. This is due to the diffusion through the microcapsule membrane is not influenced by the pH and temperature of the solution outside of microcapsule.

Formaldehyde

Cancer.gov

Learn about formaldehyde, which can raise your risk of myeloid leukemia and rare cancers of or near the nasal cavity. Formaldehyde is used in pressed-wood building materials, fungicides, germicides, disinfectants, and certain preservatives. Other sources include tobacco smoke and car emissions.

Melamine-formaldehyde aerogels

DOEpatents

Pekala, Richard W.

1992-01-01

Organic aerogels that are transparent and essentially colorless are prepa from the aqueous, sol-gel polymerization of melamine with formaldehyde. The melamine-formaldehyde (MF) aerogels have low densities, high surface areas, continuous porsity, ultrafine cell/pore sizes, and optical clarity.

40 CFR 63.2992 - How do I conduct a performance test?

Code of Federal Regulations, 2010 CFR

2010-07-01

... specified free-formaldehyde content that will be used. (2) You must operate at the maximum feasible urea-formaldehyde resin solids application rate (pounds urea-formaldehyde resin solids applied per hour) that will...

Is {sup 276}U a doubly magic nucleus?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liliani, N., E-mail: netta.liliani@gmail.com; Sulaksono, A.

2016-04-19

We investigate a possible new doubly magic heavy nucleus by using a relativistic mean-field (RMF) model with the addition of a cross interaction term of omega-rho mesons and an electromagnetic exchange term. We propose that {sup 276}U is a doubly magic nucleus. The evidence for {sup 276}U being a doubly magic nucleus is shown through the two-nucleon gaps, the single-particle energies, and the neutron skin thickness of the nucleus. We have also found that the prediction of {sup 276}U as a doubly magic nucleus by the RMF model is not affected by the inclusion of isoscalar-isovector and electromagnetic exchange couplings.

Bound states for magic state distillation in fault-tolerant quantum computation.

PubMed

Campbell, Earl T; Browne, Dan E

2010-01-22

Magic state distillation is an important primitive in fault-tolerant quantum computation. The magic states are pure nonstabilizer states which can be distilled from certain mixed nonstabilizer states via Clifford group operations alone. Because of the Gottesman-Knill theorem, mixtures of Pauli eigenstates are not expected to be magic state distillable, but it has been an open question whether all mixed states outside this set may be distilled. In this Letter we show that, when resources are finitely limited, nondistillable states exist outside the stabilizer octahedron. In analogy with the bound entangled states, which arise in entanglement theory, we call such states bound states for magic state distillation.

The magic words: Using computers to uncover mental associations for use in magic trick design

PubMed Central

2017-01-01

The use of computational systems to aid in the design of magic tricks has been previously explored. Here further steps are taken in this direction, introducing the use of computer technology as a natural language data sourcing and processing tool for magic trick design purposes. Crowd sourcing of psychological concepts is investigated; further, the role of human associative memory and its exploitation in magical effects is explored. A new trick is developed and evaluated: a physical card trick partially designed by a computational system configured to search for and explore conceptual spaces readily understood by spectators. PMID:28792941

Formaldehyde gas inactivation of Bacillus anthracis, Bacillus subtilis, and Geobacillus stearothermophilus spores on indoor surface materials.

PubMed

Rogers, J V; Choi, Y W; Richter, W R; Rudnicki, D C; Joseph, D W; Sabourin, C L K; Taylor, M L; Chang, J C S

2007-10-01

To evaluate the decontamination of Bacillus anthracis, Bacillus subtilis, and Geobacillus stearothermophilus spores on indoor surface materials using formaldehyde gas. B. anthracis, B. subtilis, and G. stearothermophilus spores were dried on seven types of indoor surfaces and exposed to approx. 1100 ppm formaldehyde gas for 10 h. Formaldehyde exposure significantly decreased viable B. anthracis, B. subtilis, and G. stearothermophilus spores on all test materials. Significant differences were observed when comparing the reduction in viable spores of B. anthracis with B. subtilis (galvanized metal and painted wallboard paper) and G. stearothermophilus (industrial carpet and painted wallboard paper). Formaldehyde gas inactivated>or=50% of the biological indicators and spore strips (approx. 1x10(6) CFU) when analyzed after 1 and 7 days. Formaldehyde gas significantly reduced the number of viable spores on both porous and nonporous materials in which the two surrogates exhibited similar log reductions to that of B. anthracis on most test materials. These results provide new comparative information for the decontamination of B. anthracis spores with surrogates on indoor surfaces using formaldehyde gas.

Biofiltration of high formaldehyde loads with ozone additions in long-term operation.

PubMed

Maldonado-Diaz, G; Arriaga, S

2015-01-01

Formaldehyde (FA) biofiltration was evaluated over 310 days with and without ozone addition. Without ozone, the biofilter was able to treat formaldehyde at inlet loads (ILs) lower than 40 g m(-3) h(-1), maintaining, under this condition, an average removal efficiency (RE) of 88 % for a few days before collapsing to zero. The continuous addition of ozone (90 ppbv) helped to recover the RE from zero to 98 ± 2 % and made it possible to operate at an IL of 40 g m(-3) h(-1) for long periods of operation (107 days). Furthermore, the ozone addition aided in operating the biofilter at a formaldehyde IL of up to 120 g m(-3) h(-1) values that have never before been reached. GC-mass spectrometry (MS) analysis showed that dimethoxymethane was the common compound in leachate during the performance decay. Also, the addition of ozone aided in maintaining an optimal pH in the biofilter with values between 7.5 and 8.2, due to the carbonate species formed during the ozone reactions with formaldehyde and its by-products. Thus, the pH control was confirmed and the alkalinity of the biofilter increased from 334.1 ± 100.3 to 1450 ± 127 mg CaCO3 L(-1) when ozone was added. Ozone addition diminished the exopolymeric substances (EPS) content of biofilm and biofilm thickness without affecting cell viability. Kinetic parameters suggested that the best conditions for carrying out FA biofiltration were reached under ozone addition. The addition of ozone during formaldehyde biofiltration could be a good strategy to maintain the pH and the steady state of the system under high ILs and for long periods of operation.

Magic Physics?

ERIC Educational Resources Information Center

Featonby, David

2010-01-01

This article examines several readily available "magic tricks" which base their "trickery" on physics principles, and questions the use of the word "magic" in the 21st century, both in popular children's science and in everyday language. (Contains 18 figures.)

Magical thinking and memory: distinctiveness effect for tv commercials with magical content.

PubMed

Subbotsky, Eugene; Mathews, Jayne

2011-10-01

The aim of this study was to examine whether memorizing advertised products of television advertisements with magical effects (i.e., talking animals, inanimate objects which turn into humans, objects that appear from thin air or instantly turn into other objects) is easier than memorizing products of advertisements without such effects, by testing immediate and delayed retention. Adolescents and adults viewed two films containing television advertisements and were asked to recall and recognize the films' characters, events, and advertised products. Film 1 included magical effects, but Film 2 did not. On a free-recall test, no differences in the number of items recalled were noted for the two films. On the immediate recognition test, adolescents, but not adults, showed significantly better recognition for the magical than the nonmagical film. When this test was repeated two weeks later, results were reversed: adults, but not adolescents, recognized a significantly larger number of items from the magical film than the nonmagical one. These results are interpreted to accentuate the role of magical thinking in cognitive processes.

A Novel Enzyme-Linked Immunosorbent Assay for Diagnosis of Mycobacterium avium subsp. paratuberculosis Infections (Johne's Disease) in Cattle

PubMed Central

Speer, C. A.; Scott, M. Cathy; Bannantine, John P.; Waters, W. Ray; Mori, Yasuyuki; Whitlock, Robert H.; Eda, Shigetoshi

2006-01-01

Enzyme-linked immunosorbent assays (ELISAs) for the diagnosis of Johne's disease (JD), caused by Mycobacterium avium subsp. paratuberculosis, were developed using whole bacilli treated with formaldehyde (called WELISA) or surface antigens obtained by treatment of M. avium subsp. paratuberculosis bacilli with formaldehyde and then brief sonication (called SELISA). ELISA plates were coated with either whole bacilli or sonicated antigens and tested for reactivity against serum obtained from JD-positive and JD-negative cattle or from calves experimentally inoculated with M. avium subsp. paratuberculosis, Mycobacterium avium subsp. avium, or Mycobacterium bovis. Because the initial results obtained from the WELISA and SELISA were similar, most of the subsequent experiments reported herein were performed using the SELISA method. To optimize the SELISA test, various concentrations (3.7 to 37%) of formaldehyde and intervals of sonication (2 to 300 s) were tested. With an increase in formaldehyde concentration and a decreased interval of sonication, there was a concomitant decrease in nonspecific binding by the SELISA. SELISAs prepared by treating M. avium subsp. paratuberculosis with 37% formaldehyde and then a 2-s burst of sonication produced the greatest difference (7×) between M. avium subsp. paratuberculosis-negative and M. avium subsp. paratuberculosis-positive serum samples. The diagnostic sensitivity and specificity for JD by the SELISA were greater than 95%. The SELISA showed subspecies-specific detection of M. avium subsp. paratuberculosis infections in calves experimentally inoculated with M. avium subsp. paratuberculosis or other mycobacteria. Based on diagnostic sensitivity and specificity, the SELISA appears superior to the commercial ELISAs routinely used for the diagnosis of JD. PMID:16682472

Melamine-formaldehyde aerogels

DOEpatents

Pekala, R.W.

1992-01-14

Organic aerogels that are transparent and essentially colorless are prepared from the aqueous, sol-gel polymerization of melamine with formaldehyde. The melamine-formaldehyde (MF) aerogels have low densities, high surface areas, continuous porosity, ultrafine cell/pore sizes, and optical clarity. 3 figs.

Effects of reaction pH on properties and performance of urea-formaldehyde resins

Treesearch

Chung-Yun Hse; Zhi-Yuan Xia; Bunchiro Tomita

1994-01-01

Urea formaldehyde resins were formulated with combination variables of three reaction pH (1.0, 4.8, and 8.0) and four molar ratios of formaldehyde to urea (2.5, 3.0, 3.5, and 4.0). The resins were prepared by placing all formaldehyde and water in reaction kettle and pH was adjusted with sulfuric acid and sodium hydroxide, respectively. Urea was added in 15 equal parts...

Gas chromatographic determination of formaldehyde in maple syrup as 2,4-dinitrophenylhydrazone derivative.

PubMed

Baraniak, Z; Nagpal, D S; Neidert, E

1988-01-01

A procedure is presented for the quantitative extraction and determination of formaldehyde in maple sap and syrup. The method is based on the reaction between formaldehyde and 2,4-dinitrophenylhydrazine and determination of the derivative by gas chromatography. The procedure was used to evaluate formaldehyde in saps and syrups of paraformaldehyde implanted trees. Average recoveries were 101.5 +/- 5.7%. The detection limit was 0.078 mg/kg.

Simple high-performance liquid chromatography method for formaldehyde determination in human tissue through derivatization with 2,4-dinitrophenylhydrazine.

PubMed

Yilmaz, Bilal; Asci, Ali; Kucukoglu, Kaan; Albayrak, Mevlut

2016-08-01

A simple high-performance liquid chromatography method has been developed for the determination of formaldehyde in human tissue. FA Formaldehyde was derivatized with 2,4-dinitrophenylhydrazine. It was extracted from human tissue with ethyl acetate by liquid-liquid extraction and analyzed by high-performance liquid chromatography. The calibration curve was linear in the concentration range of 5.0-200 μg/mL. Intra- and interday precision values for formaldehyde in tissue were <6.9%, and accuracy (relative error) was better than 6.5%. The extraction recoveries of formaldehyde from human tissue were between 88 and 98%. The limits of detection and quantification of formaldehyde were 1.5 and 5.0 μg/mL, respectively. Also, this assay was applied to liver samples taken from a biopsy material. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Level of endogenous formaldehyde in maple syrup as determined by spectrofluorimetry.

PubMed

Lagacé, Luc; Guay, Stéphane; Martin, Nathalie

2003-01-01

The level of endogenous formaldehyde in maple syrup was established from a large number (n = 300) of authentic maple syrup samples collected during 2000 and 2001 in the province of Quebec, Canada. The average level of formaldehyde from these authentic samples was measured at 0.18 mg/kg in 2000 and 0.28 mg/kg in 2001, which is lower than previously published. These average values can be attributed to the improved spectrofluorimetric method used for the determination. However, the formaldehyde values obtained demonstrate a relatively large distribution with maximums observed at 1.04 and 1.54 mg/kg. These values are still under the maximum tolerance level of 2.0 mg/kg paraformaldehyde pesticide residue. Extensive heat treatment of maple syrup samples greatly enhanced the formaldehyde concentration of the samples, suggesting that extensive heat degradation of the sap constituents during evaporation could be responsible for the highest formaldehyde values in maple syrup.

MAGIC Computer Simulation. Volume 2: Analyst Manual, Part 1

DTIC Science & Technology

1971-05-01

A review of the subject Magic Computer Simulation User and Analyst Manuals has been conducted based upon a request received from the US Army...1971 4. TITLE AND SUBTITLE MAGIC Computer Simulation Analyst Manual Part 1 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6...14. ABSTRACT The MAGIC computer simulation generates target description data consisting of item-by-item listings of the target’s components and air

NTRFACE for MAGIC

DTIC Science & Technology

1989-07-31

40. NO NO ACCESSION NO N7 ?I TITLE (inWijuod Security Claisification) NTRFACE FOR MAGIC 𔃼 PERSONAL AUTHOR(S) N.T. GLADD PE OF REPORT T b TIME...the MAGIC Particle-in-Cell Simulation Code. 19 ABSTRACT (Contianue on reverse if nceary and d ntiy by block number) The NTRFACE system was developed...made concret by applying it to a specific application- a mature, highly complex plasma physics particle in cell simulation code name MAGIC . This

Evaluation of magical thinking: validation of the Illusory Beliefs Inventory.

PubMed

Shihata, Sarah; Egan, Sarah J; Rees, Clare S

2014-01-01

Magical thinking has been related to obsessive-compulsive disorder; yet, little research has examined this construct in other anxiety disorders. The Illusory Beliefs Inventory (IBI) is a recently developed measure of magical thinking. The aim of this study was to investigate the psychometric properties of this new measure and to determine if magical thinking accounts for pathological worry beyond the well-researched constructs of intolerance of uncertainty (IU) and perfectionism. A sample of 502 participants completed an online survey. Confirmatory factor analysis identified a three-factor solution for the IBI, and the measure had good internal consistency (α = .92), test-retest reliability (r = .94) and discriminant validity. Magical thinking, IU, and perfectionism all predicted pathological worry; however, magical thinking accounted for less than 1% of unique variance in worry, suggesting that it is not strongly related to worry. Further investigation regarding the validity and clinical utility of the IBI is required.

Development of Formaldehyde Biosensor for Determination of Formalin in Fish Samples; Malabar Red Snapper (Lutjanus malabaricus) and Longtail Tuna (Thunnus tonggol)

PubMed Central

Noor Aini, Bohari; Siddiquee, Shafiquzzaman; Ampon, Kamaruzaman

2016-01-01

Electrochemical biosensors are widely recognized in biosensing devices due to the fact that gives a direct, reliable, and reproducible measurement within a short period. During bio-interaction process and the generation of electrons, it produces electrochemical signals which can be measured using an electrochemical detector. A formaldehyde biosensor was successfully developed by depositing an ionic liquid (IL) (e.g., 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIM][Otf])), gold nanoparticles (AuNPs), and chitosan (CHIT), onto a glassy carbon electrode (GCE). The developed formaldehyde biosensor was analyzed for sensitivity, reproducibility, storage stability, and detection limits. Methylene blue was used as a redox indicator for increasing the electron transfer in the electrochemical cell. The developed biosensor measured the NADH electron from the NAD+ reduction at a potential of 0.4 V. Under optimal conditions, the differential pulse voltammetry (DPV) method detected a wider linear range of formaldehyde concentrations from 0.01 to 10 ppm within 5 s, with a detection limit of 0.1 ppm. The proposed method was successfully detected with the presence of formalin in fish samples, Lutjanus malabaricus and Thunnus Tonggol. The proposed method is a simple, rapid, and highly accurate, compared to the existing technique. PMID:27376338

The relationships between patients’ and caregivers’ beliefs about the causes of schizophrenia and clinical outcomes in Latin American countries

PubMed Central

Caqueo-Urízar, Alejandra; Boyer, Laurent; Baumstarck, Karine; Gilman, Stephen E.

2015-01-01

Beliefs about the causes of schizophrenia are thought to impact treatment outcomes. We investigated 3 theoretically opposing belief systems (biological, psychosocial, magical-religious) in relation to the severity of positive and negative symptoms and to attitudes towards medications. We recruited 253 patients with schizophrenia and their primary caregivers from public mental health clinics in Bolivia, Chile, and Peru. We assessed patients’ and caregivers’ beliefs about the causes of schizophrenia, which were used as predictors of symptom severity and medication attitudes in linear regression analyses. Patients’ scores on biological, psychosocial, and magical-religious beliefs were positively correlated with one another, indicating that these domains were not, as anticipated, “opposing.” Patients with higher levels of biological and psychosocial beliefs had significantly lower levels of positive and negative symptoms; in contrast, higher levels of magical-religious beliefs were associated with increased positive symptoms and less favorable attitudes towards medications. Patients’ belief systems are significant predictors of symptom severity and medication attitudes. Research is needed on the extent to which psychotherapeutic treatments for schizophrenia should bolster patients’ beliefs in the biological and psychosocial domains and weaken beliefs in the magical-religious domain; this research should also attend to the ethical considerations involved in intervening on belief systems cross-culturally. PMID:26188641

Finding All Solutions to the Magic Hexagram

ERIC Educational Resources Information Center

Holland, Jason; Karabegov, Alexander

2008-01-01

In this article, a systematic approach is given for solving a magic star puzzle that usually is accomplished by trial and error or "brute force." A connection is made to the symmetries of a cube, thus the name Magic Hexahedron.

Porphinogen Formation from the Co-Oligomerization of Formaldehyde and Pyrrole: Free Energy Pathways.

PubMed

Kua, Jeremy; Loli, Helen

2017-10-26

We have investigated the nonoxidative stepwise co-oligomerization of formaldehyde and pyrrole to form porphinogen using density functional theory calculations that include free energy corrections. While the addition of formaldehyde to the pyrrole nitrogen is kinetically favored, thermodynamics suggest that this reaction is reversible in aqueous solution. The more thermodynamically favorable addition of formaldehyde to the ortho-carbon of pyrrole begins a stepwise process, forming dipyrromethane via an azafulvene intermediate. Subsequent additions of formaldehyde and pyrrole lead to bilanes (linear tetrapyrroles), which favorably cyclize to form porphinogen. Porphinogen is a precursor to porphin, the simplest unsubstituted porphyrin that could have played a role in primitive metabolism at the origin of life.

Formaldehyde cross-linking and structural proteomics: Bridging the gap.

PubMed

Srinivasa, Savita; Ding, Xuan; Kast, Juergen

2015-11-01

Proteins are dynamic entities constantly moving and altering their structures based on their functions and interactions inside and outside the cell. Formaldehyde cross-linking combined with mass spectrometry can accurately capture interactions of these rapidly changing biomolecules while maintaining their physiological surroundings. Even with its numerous established uses in biology and compatibility with mass spectrometry, formaldehyde has not yet been applied in structural proteomics. However, formaldehyde cross-linking is moving toward analyzing tertiary structure, which conventional cross-linkers have already accomplished. The purpose of this review is to describe the potential of formaldehyde cross-linking in structural proteomics by highlighting its applications, characteristics and current status in the field. Copyright © 2015 Elsevier Inc. All rights reserved.

Effects of formaldehyde-enriched mists on Pseudotsuga menziesii (Mirbel) Franco and Lobaria pulmonaria (L.) Hoffm.

PubMed

Muir, P S; Shirazi, A M

1996-01-01

The atmosphere in some areas is polluted with formaldehyde (HCHO); however, little is known about effects of HCHO on plants at concentrations resembling those in polluted areas. The effects of simulated fogwater enriched with HCHO on seedlings of Pseudotsuga menziesii (Mirbel) Franco (Douglas fir) and pendants of Lobaria pulmonaria (L.) Hoffm. were assessed. Plants were treated with HCHO-enriched fog (target concentrations of 100, 500, and 1000 microm) during five 4-night mist sessions. Growth and nitrogenase activity (acetylene reduction rate) for lichens and growth and timing of bud-break for Douglas fir were monitored. Nitrogenase activity was lowest in lichens treated at the highest HCHO concentration after all but the first mist session, and it declined significantly with increasing HCHO concentration after the final mist session (R(2) = 0.60, p = 0.02). However, differences in nitrogenase activity among treatments were generally not statistically significant (most p values from ANOVAs were >/= 0.20). Formaldehyde did not affect growth of the lichens. Budbreak of Douglas firs was slightly delayed and height growth was slightly depressed with increasing HCHO concentration, although effects were not statistically significant.

Melamine-formaldehyde microcapsules filled sappan dye modified polypropylene composites: encapsulation and thermal properties

NASA Astrophysics Data System (ADS)

Phanyawong, Suphitcha; Siengchin, Suchart; Parameswaranpillai, Jyotishkumar; Asawapirom, Udom; Polpanich, Duangporn

2018-01-01

Sappan dye, a natural dye extracted from sappan wood is widely used in cosmetics, textile dyeing and as food additives. However, it was recognized that natural dyes cannot withstand high temperature. In this study, a protective coating of melamine-formaldehyde shell material was applied over the sappan dye to improve its thermal stability. The percentage of sappan dye used in the microencapsulation was 30, 40, 50, 60 and 70 wt%. The color, shape, size, and thermal stability of sappan dye microcapsules were investigated. It was found that increasing amount of sappan dye content in the microcapsules decreased the particle size. Thermal analysis reveals that the melamine-formaldehyde resin served as an efficient protective shell for sappan dye. Besides, 30 wt% sappan dye microcapsules with different weight percent (1, 3 and 5 wt%) of sappan dye was used as modifier for polypropylene (PP). All the prepared composites are red in color which supports the thermal stability of the microcapsules. The changes in crystallinity and melting behavior of PP by the addition of microcapsules were studied in detail by differential scanning calorimetry. Thermogravimetric studies showed that the thermal stability of PP composites increased by the addition of microcapsules.

Magnetic resonance imaging of DNP enhancements in a rotor spinning at the magic angle

DOE Office of Scientific and Technical Information (OSTI.GOV)

Perras, Frederic A.; Kobayashi, Takeshi; Pruski, Marek

Simulations performed on model, static, samples have shown that the microwave power is non-uniformly distributed in the magic angle spinning (MAS) rotor when using conventional dynamic nuclear polarization (DNP) instrumentation. Here, we applied the stray-field magic angle spinning imaging (STRAFI–MAS) experiment to generate a spatial map of the DNP enhancements in a full rotor, which is spun at a low rate in a commercial DNP–MAS NMR system. Notably, we observed that the enhancement factors produced in the center of the rotor can be twice as large as those produced at the top of the rotor. Surprisingly, we observed that themore » largest enhancement factors are observed along the axis of the rotor as opposed to against its walls, which are most directly irradiated by the microwave beam. We lastly observed that the distribution of enhancement factors can be moderately improved by degassing the sample and increasing the microwave power. The inclusion of dielectric particles greatly amplifies the enhancement factors throughout the rotor. Furthermore, the STRAFI–MAS approach can provide useful guidance for optimizing the access of microwave power to the sample, and thereby lead to further increases in sensitivity of DNP–MAS NMR.« less

Magnetic resonance imaging of DNP enhancements in a rotor spinning at the magic angle

DOE PAGES

Perras, Frederic A.; Kobayashi, Takeshi; Pruski, Marek

2016-02-23

Simulations performed on model, static, samples have shown that the microwave power is non-uniformly distributed in the magic angle spinning (MAS) rotor when using conventional dynamic nuclear polarization (DNP) instrumentation. Here, we applied the stray-field magic angle spinning imaging (STRAFI–MAS) experiment to generate a spatial map of the DNP enhancements in a full rotor, which is spun at a low rate in a commercial DNP–MAS NMR system. Notably, we observed that the enhancement factors produced in the center of the rotor can be twice as large as those produced at the top of the rotor. Surprisingly, we observed that themore » largest enhancement factors are observed along the axis of the rotor as opposed to against its walls, which are most directly irradiated by the microwave beam. We lastly observed that the distribution of enhancement factors can be moderately improved by degassing the sample and increasing the microwave power. The inclusion of dielectric particles greatly amplifies the enhancement factors throughout the rotor. Furthermore, the STRAFI–MAS approach can provide useful guidance for optimizing the access of microwave power to the sample, and thereby lead to further increases in sensitivity of DNP–MAS NMR.« less

MAGIC Computer Simulation. Volume 1: User Manual

DTIC Science & Technology

1970-07-01

vulnerability and MAGIC programs. A three-digit code is assigned to each component of the target, such as armor, gun tube; and a two-digit code is assigned to...A review of the subject Magic Computer Simulation User and Analyst Manuals has been conducted based upon a request received from the US Army...1970 4. TITLE AND SUBTITLE MAGIC Computer Simulation 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT

An Overview of the MAGIC Project

DTIC Science & Technology

1993-12-01

unlimnitedj_ _______ 13. ABSTRACT (Mxmwn WO0 words) This note provides an overview of the MAGIC project1 which is developing a high-speed, wide-area...298Rv.9 16. PRICE COASSDE 3.1 17. SEURITY18. SEURITY19. SEURITY2930.2BIA NO An Overview of the M 93B0000173 MAGIC Project December 1993 Barbara B...Intelligence Division ii ABSTRACT This note provides an overview of the MAGIC project, which is developing a high-speed, wide- area networking testbed

Secrets of the Chinese magic mirror replica

NASA Astrophysics Data System (ADS)

Mak, Se-yuen; Yip, Din-yan

2001-03-01

We examine the structure of five Chinese magic mirror replicas using a special imaging technique developed by the authors. All mirrors are found to have a two-layered structure. The reflecting surface that gives rise to a projected magic pattern on the screen is hidden under a polished half-reflecting top layer. An alternative method of making the magic mirror using ancient technology has been proposed. Finally, we suggest a simple method of reconstructing a mirror replica in the laboratory.

An fMRI investigation of expectation violation in magic tricks.

PubMed

Danek, Amory H; Öllinger, Michael; Fraps, Thomas; Grothe, Benedikt; Flanagin, Virginia L

2015-01-01

Magic tricks violate the expected causal relationships that form an implicit belief system about what is possible in the world around us. Observing a magic effect seemingly invalidates our implicit assumptions about what action causes which outcome. We aimed at identifying the neural correlates of such expectation violations by contrasting 24 video clips of magic tricks with 24 control clips in which the expected action-outcome relationship is upheld. Using fMRI, we measured the brain activity of 25 normal volunteers while they watched the clips in the scanner. Additionally, we measured the professional magician who had performed the magic tricks under the assumption that, in contrast to naïve observers, the magician himself would not perceive his own magic tricks as an expectation violation. As the main effect of magic - control clips in the normal sample, we found higher activity for magic in the head of the caudate nucleus (CN) bilaterally, the left inferior frontal gyrus and the left anterior insula. As expected, the magician's brain activity substantially differed from these results, with mainly parietal areas (supramarginal gyrus bilaterally) activated, supporting our hypothesis that he did not experience any expectation violation. These findings are in accordance with previous research that has implicated the head of the CN in processing changes in the contingency between action and outcome, even in the absence of reward or feedback.

Magic in the machine: a computational magician's assistant.

PubMed

Williams, Howard; McOwan, Peter W

2014-01-01

A human magician blends science, psychology, and performance to create a magical effect. In this paper we explore what can be achieved when that human intelligence is replaced or assisted by machine intelligence. Magical effects are all in some form based on hidden mathematical, scientific, or psychological principles; often the parameters controlling these underpinning techniques are hard for a magician to blend to maximize the magical effect required. The complexity is often caused by interacting and often conflicting physical and psychological constraints that need to be optimally balanced. Normally this tuning is done by trial and error, combined with human intuitions. Here we focus on applying Artificial Intelligence methods to the creation and optimization of magic tricks exploiting mathematical principles. We use experimentally derived data about particular perceptual and cognitive features, combined with a model of the underlying mathematical process to provide a psychologically valid metric to allow optimization of magical impact. In the paper we introduce our optimization methodology and describe how it can be flexibly applied to a range of different types of mathematics based tricks. We also provide two case studies as exemplars of the methodology at work: a magical jigsaw, and a mind reading card trick effect. We evaluate each trick created through testing in laboratory and public performances, and further demonstrate the real world efficacy of our approach for professional performers through sales of the tricks in a reputable magic shop in London.

Factsheet -- EPA’s Rule to Implement the Formaldehyde Standards for Composite Wood Products Act

EPA Pesticide Factsheets

This factsheet explains EPA's final rule to implement the Formaldehyde Standards for Composite Wood Products Act and reduce exposure to formaldehyde vapors from certain wood products produced domestically or imported into the United States.

Formaldehyde risk assessment

EPA Science Inventory

We would like to comment on the paper by Crump et al. (2008), ‘Sensitivity analysis of biologically motivated model for formaldehyde-induced respiratory cancer in humans’. We are authors of the formaldehyde cancer risk assessment described in Conolly et al. (2003, 2004) that is t...

Bio-phenolic resin from oil palm empty fruit bunches

NASA Astrophysics Data System (ADS)

Zakaria, Zuhaili; Zakaria, Sarani; Roslan, Rasidi; Chia, Chin Hua; Jaafar, Sharifah Nabihah Syed; Amran, Umar Adli

2018-04-01

Utilization of oil palm empty fruit bunches (EFB) in the production of bio-phenolic resin is an alternative way to reduce the dependency of petroleum-based phenol. In this study, resol type bio-phenolic resin (BPR) was synthesized from EFB fibers using sulfuric acid as the catalyst to produce liquefied empty fruit bunches (LEFB) followed by resinification reaction with formaldehyde in alkaline condition. The SEM image of LEFB residue showed separation of fiber bundles into individual fibers. This indicate that lignin was destroyed during the liquefaction process. The increased of formaldehyde/LEFB molar ratio has resulted an increase of viscosity, solid content and pH of the resin. The obtained FTIR spectra confirmed that functional groups of BPR resins was almost similar with commercial resin.

A Simple Parameterization of 3 x 3 Magic Squares

ERIC Educational Resources Information Center

Trenkler, Gotz; Schmidt, Karsten; Trenkler, Dietrich

2012-01-01

In this article a new parameterization of magic squares of order three is presented. This parameterization permits an easy computation of their inverses, eigenvalues, eigenvectors and adjoints. Some attention is paid to the Luoshu, one of the oldest magic squares.

Formation, Accumulation, and Hydrolysis of Endogenous and Exogenous Formaldehyde-Induced DNA Damage

PubMed Central

Yu, Rui; Lai, Yongquan; Hartwell, Hadley J.; Moeller, Benjamin C.; Doyle-Eisele, Melanie; Kracko, Dean; Bodnar, Wanda M.; Starr, Thomas B.; Swenberg, James A.

2015-01-01

Formaldehyde is not only a widely used chemical with well-known carcinogenicity but is also a normal metabolite of living cells. It thus poses unique challenges for understanding risks associated with exposure. N2-hydroxymethyl-dG (N2-HOMe-dG) is the main formaldehyde-induced DNA mono-adduct, which together with DNA-protein crosslinks (DPCs) and toxicity-induced cell proliferation, play important roles in a mutagenic mode of action for cancer. In this study, N2-HOMe-dG was shown to be an excellent biomarker for direct adduction of formaldehyde to DNA and the hydrolysis of DPCs. The use of inhaled [13CD2]-formaldehyde exposures of rats and primates coupled with ultrasensitive nano ultra performance liquid chromatography-tandem mass spectrometry permitted accurate determinations of endogenous and exogenous formaldehyde DNA damage. The results show that inhaled formaldehyde only reached rat and monkey noses, but not tissues distant to the site of initial contact. The amounts of exogenous adducts were remarkably lower than those of endogenous adducts in exposed nasal epithelium. Moreover, exogenous adducts accumulated in rat nasal epithelium over the 28-days exposure to reach steady-state concentrations, followed by elimination with a half-life (t1/2) of 7.1 days. Additionally, we examined artifact formation during DNA preparation to ensure the accuracy of nonlabeled N2-HOMe-dG measurements. These novel findings provide critical new data for understanding major issues identified by the National Research Council Review of the 2010 Environmental Protection Agency’s Draft Integrated Risk Information System Formaldehyde Risk Assessment. They support a data-driven need for reflection on whether risks have been overestimated for inhaled formaldehyde, whereas underappreciating endogenous formaldehyde as the primary source of exposure that results in bone marrow toxicity and leukemia in susceptible humans and rodents deficient in DNA repair. PMID:25904104

A novel mass spectrometric method for formaldehyde in children's personal-care products and water via derivatization with acetylacetone.

PubMed

Backe, Will J

2017-06-30

New legislation in the state of Minnesota prohibits the sale of children's personal-care products (PCPs) that contain more than 500 ng/mg formaldehyde. Previous attempts to quantify formaldehyde in PCPs use nonspecific derivatization procedures that employ harsh reagents and/or nonspecific detection. Derivatization of formaldehyde by acetylacetone occurs under mild conditions and is specific for formaldehyde but it has not been investigated using high-performance liquid chromatography/tandem mass-spectrometry (HPLC/MS/MS). To determine formaldehyde, PCPs were dissolved and then interferences were minimized by graphitized-carbon solid-phase extraction. Formaldehyde was derivatized to 3,5-diacetyl-1,4-dihydrolutidine (DDL) using an acetylacetone solution. Post-derivatization, samples were diluted and analyzed by HPLC/MS/MS. Quantification was performed by isotopic dilution. Product-ion spectra were acquired for DDL and D 12 -DDL. The mass shifts between the two product-ion spectra were used to assign fragment structures. To confirm molecular formulas, high-resolution accurate-mass analysis of the DDL product ions was performed by quadrupole time-of-flight MS. Structures were proposed for all product ions of DDL above 10% relative intensity. Method accuracy ranged between 96-104% for all matrices at all concentrations tested. Method precision was less than 4% relative standard deviation. The reporting limit was 10 ng/mg in PCPs and 100 μg/L in water. Twenty children's PCPs were tested to demonstrate the method and formaldehyde was reported in five from 23-1500 ng/mg. Of those five, two samples contained formaldehyde above the Minnesota regulatory limit. The developed method allows for the accurate quantification of formaldehyde in PCPs at levels below those required by a new regulation on children's products in Minnesota. The method includes a derivatization procedure that is newly adapted to HPLC/MS/MS; therefore, structures were proposed for the product ions of the derivative (DDL). Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.

Primary Formation Path of Formaldehyde in Hydrothermal Vents

NASA Astrophysics Data System (ADS)

Inaba, Satoshi

2018-03-01

Formaldehyde is abundant in the universe and one of the fundamental molecules for life. Hydrothermal vents produce a substantial amount of hydrogen molecules by serpentinization and promote reductive reactions of single carbon compounds. The abundance of formaldehyde is expected to be low due to the high Gibbs free energy in hydrothermal vents. We consider two competing formation pathways of formaldehyde: (1) the reduction of CO by H2 and (2) the reduction of HCOOH by H2 to form a methanediol, followed by the dehydration of the methanediol. We performed a number of quantum chemical simulations to examine the formation of formaldehyde in the gas phase as well as in aqueous solution. The energy barrier is significantly reduced by the catalytic effect of water molecules in aqueous solution and becomes lowest when a water cluster consisted of 5 water molecules catalyzes the reduction. The energy barrier to form a methanediol by the reduction of HCOOH is lower by 17.5 kcal/mol than that to form a formaldehyde by the reduction of CO. Considering the low energy barrier to dehydrate methanediol, the primary pathway to form formaldehyde in hydrothermal vents is concluded to be the reduction of HCOOH by H2, followed by the dehydration of methanediol.

Investigation of formaldehyde pollution of tap water and rain water using a novel visual colorimetry.

PubMed

Murai, K; Okano, M; Kuramitz, H; Hata, N; Kawakami, T; Taguchi, S

2008-01-01

The pollution of tap water and rain water with formaldehyde in Toyama Pref., Japan was investigated by means of a simple, rapid and cost-effective visual colorimetry developed by us. The levels of formaldehyde in three tap waters from different sources of dams on mountainside and a well-water pumped in urban area in Toyama Pref. were lower than 0.01 mg L(-1) that was the detection limit of the colorimetry. On the other hand, rain waters were seriously polluted with formaldehyde. Rain waters were sampled from three different sites (urban area, top of hill and industrial area) in Toyama Pref. from autumn to winter in 2006. The levels of formaldehyde in the rain waters ranged from 0.07 to 0.30 mg L(-1). The analytical results by the visual colorimetry were in good agreement with those obtained by GC-MS method. It was confirmed that the colorimetry is excellent for practical use for the determination of formaldehyde. It must be concerned about the pollution of rainwater with formaldehyde, when rain water is applied for tap water and miscellaneous purpose. Copyright IWA Publishing 2008.

Primary Formation Path of Formaldehyde in Hydrothermal Vents.

PubMed

Inaba, Satoshi

2018-03-01

Formaldehyde is abundant in the universe and one of the fundamental molecules for life. Hydrothermal vents produce a substantial amount of hydrogen molecules by serpentinization and promote reductive reactions of single carbon compounds. The abundance of formaldehyde is expected to be low due to the high Gibbs free energy in hydrothermal vents. We consider two competing formation pathways of formaldehyde: (1) the reduction of CO by H 2 and (2) the reduction of HCOOH by H 2 to form a methanediol, followed by the dehydration of the methanediol. We performed a number of quantum chemical simulations to examine the formation of formaldehyde in the gas phase as well as in aqueous solution. The energy barrier is significantly reduced by the catalytic effect of water molecules in aqueous solution and becomes lowest when a water cluster consisted of 5 water molecules catalyzes the reduction. The energy barrier to form a methanediol by the reduction of HCOOH is lower by 17.5 kcal/mol than that to form a formaldehyde by the reduction of CO. Considering the low energy barrier to dehydrate methanediol, the primary pathway to form formaldehyde in hydrothermal vents is concluded to be the reduction of HCOOH by H 2 , followed by the dehydration of methanediol.

Effect of science magic applied in interactive lecture demonstrations on conceptual understanding

NASA Astrophysics Data System (ADS)

Taufiq, Muhammad; Suhandi, Andi; Liliawati, Winny

2017-08-01

Research about the application of science magic-assisting Interactive Lecture Demonstrations (ILD) has been conducted. This research is aimed at providing description about the comparison of the improvement of the conceptual understanding of lesson on pressure between students who receive physics lesson through science magic-assisting ILD and students who receive physics lesson through ILD without science magic. This research used a quasi-experiment methods with Control Group Pretest-Posttest Design. The subject of the research is all students of class VIII in one of MTs (Islamic junior high school) in Pekalongan. Research samples were selected using random sampling technique. Data about students' conceptual understanding was collected using test instrument of conceptual understanding in the form of multiple choices. N-gain average calculation was performed in order to determine the improvement of students' conceptual understanding. The result of the research shows that conceptual understanding of students on lesson about pressure who received lesson with ILD using science magic <0.44> is higher than students who received lesson with ILD without science magic <0.25>. Therefore, the conclusion is that the application of science magic ILD is more effective to improve the conceptual understanding of lesson on pressure.

The role of magical thinking in hallucinations. Comparisons of clinical and non-clinical groups.

PubMed

García-Montes, José M; Pérez-Álvarez, Marino; Odriozola-González, Paula; Vallina-Fernández, Oscar; Perona-Garcelán, Salvador

2014-11-01

Magical thinking consists of accepting the possibility that events that, according to the causal concepts of a culture, cannot have any causal relationship, but might somehow nevertheless have one. Magical thinking has been related to both obsessive-compulsive disorder and schizophrenia. The purpose of this study was to investigate the role of magical thinking in hallucinations of patients diagnosed with schizophrenia. Four groups were recruited for this purpose from a clinical population (hallucinating schizophrenic patients, patients diagnosed with psychoses who had never hallucinated, obsessive-compulsive disorder patients and a clinical control group) and a non-clinical control group, who were given the Magical Ideation Scale. The results show that magical ideation differentiates the group of schizophrenic patients with auditory hallucinations from the rest of the groups that participated in the design. Items related to "mind reading", to the presence of auditory illusions in response to sound stimuli, and to the sense of sometimes being accompanied by an evil presence are the most closely related to the presence of auditory hallucinations. Magical thinking, understood as beliefs in non-consensual modes of causation, is closely linked to auditory hallucinations in patients diagnosed with schizophrenia.

Developing a Reference Material for Diffusion-Controlled Formaldehyde Emissions Testing

EPA Science Inventory

Emissions of formaldehyde from building materials can contaminate indoor air and create significant risks to human health. The need to control formaldehyde emissions from indoor materials is made more urgent by the prevailing drive to improve building energy by decreasing ventil...

Urea formaldehyde foam: a dangerous insulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keough, C.

1980-12-01

Insulating a home with urea formaldehyde foam can lead to severe health problems due to poisoning from formaldehyde gas. Respiratory problems, allergies, memory loss, and mental problems can result from exposure to foam insulation fumes. Research is now under way at the Chemical Industry Inst., Univ. of Washington, and other institutions to learn more about the health effects of formaldehyde foam and to develop possible remedies to these problems. Several states are either banning or controlling the use of this type of home insulation.

Early Childhood Corner: Take the Magic Out of Your Classroom!

ERIC Educational Resources Information Center

Andrews, Angela Giglio

1995-01-01

Students are often as mystified by mathematical procedures as they are by magic tricks. This article suggests ways of making the estimation of how many jelly beans in a jar and the 20-questions game less magical and more understandable. (MKR)

Magical thinking by inpatient staff members.

PubMed

Pilette, W L

1983-01-01

Magical thinking is a primitive form of mental activity which, nevertheless, the author contends, is common among mental health professionals. Four examples of magical thinking by inpatient staff members are presented and briefly explored, in order to shed light on our work and ourselves.

[Further Distinctions between Magic, Reality, Religion, and Fiction. Commentaries.

ERIC Educational Resources Information Center

Boyer, Pascal; Taylor, Marjorie; Harris, Paul L.; Chandler, Michael; Johnson, Carl N.

1997-01-01

Contains the following commentaries: "Further Distinctions between Magic, Reality, Religion, and Fiction"; "The Role of Creative Control and Culture in Children's Fantasy/Reality Judgments"; "The Last of the Magicians? Children, Scientists, and the Invocation of Hidden Causal Powers"; "Rescuing Magical Thinking…

The Magic Background of Pearl Harbor. Volume 1 (February 14, 1941 - May 12, 1941)

DTIC Science & Technology

1977-01-01

1977 2. REPORT TYPE 3. DATES COVERED 00-00-1977 to 00-00-1977 4. TITLE AND SUBTITLE The ’ Magic ’ Background of Pearl Harbor. Volume 1: February...34 MAGIC " BACKGROUND OF PEARL HARBOR VOLUME I (February 14, 1941-May 12,1941) /- / DEPARTMENT OF DEFENSE UNITED STATES OF AMERICA For sale by the...The Department of Defense is releasing for public use and research this multi-volume study giving the " MAGIC " or communications intelligence background

Further Studies of the NRL Collective Particle Accelerator VIA Numerical Modeling with the MAGIC Code.

DTIC Science & Technology

1984-08-01

COLLFCTIVF PAPTTCLE ACCELERATOR VIA NUMERICAL MODFLINC WITH THF MAGIC CODE Robert 1. Darker Auqust 19F4 Final Report for Period I April. qI84 - 30...NUMERICAL MODELING WITH THE MAGIC CODE Robert 3. Barker August 1984 Final Report for Period 1 April 1984 - 30 September 1984 Prepared for: Scientific...Collective Final Report Particle Accelerator VIA Numerical Modeling with April 1 - September-30, 1984 MAGIC Code. 6. PERFORMING ORG. REPORT NUMBER MRC/WDC-R

[Magical thinking and self development].

PubMed

Resch, F

1994-01-01

Based on a historical survey of the term "magic thinking" structural aspects of primary process and prelogical thinking will be elucidated. Developmental necessities for the emergence of magic interpretations in children of pre-school age are proposed. The thesis will be formulated, that magic interpretations may help the developing self in the management of life-circumstances during a period of cognitive egocentrism: feelings of non-competence may be compensated, and the locus of control may be held in the face of experiences of inferiority.

Controlling the magic and normal sizes of white CdSe quantum dots

NASA Astrophysics Data System (ADS)

Su, Yu-Sheng; Chung, Shu-Ru

2017-08-01

In this study, we have demonstrated a facile chemical route to prepare CdSe QDs with white light emission, and the performance of white CdSe-based white light emitting diode (WLED) is also exploded. An organic oleic acid (OA) is used to form Cd-OA complex first and hexadecylamine (HDA) and 1-octadecene (ODE) is used as surfactants. Meanwhile, by varying the reaction time from 1 s to 60 min, CdSe QDs with white light can be obtained. The result shows that the luminescence spectra compose two obvious emission peaks and entire visible light from 400 to 700 nm, when the reaction time less than 10 min. The wide emission wavelength combine two particle sizes of CdSe, magic and normal, and the magic-CdSe has band-edge and surface-state emission, while normal size only possess band-edge emission. The TEM characterization shows that the two different sizes with diameter of 1.5 nm and 2.7 nm for magic and normal size CdSe QDs can be obtained when the reaction time is 4 min. We can find that the magic size of CdSe is produced when the reaction time is less than 3 min. In the time ranges from 3 to 10 min, two sizes of CdSe QDs are formed, and with QY from 20 to 60 %. Prolong the reaction time to 60 min, only normal size of CdSe QD can be observed due to the Ostwald repining, and its QYs is 8 %. Based on the results we can conclude that the two emission peaks are generated from the coexistence of magic size and normal size CdSe to form the white light QDs, and the QY and emission wavelength of CdSe QDs can be increased with prolonging reaction time. The sample reacts for 2 (QY 30 %), 4 (QY 32 %) and 60 min (QY 8 %) are choosing to mixes with transparent acrylic-based UV curable resin for WLED fabrication. The Commission International d'Eclairage (CIE) chromaticity, color rendering index (CRI), and luminous efficacy for magic, mix, and normal size CdSe are (0.49, 0.44), 81, 1.5 lm/W, (0.35, 0.30), 86, 1.9 lm/W, and (0.39, 0.25), 40, 0.3 lm/W, respectively.

Formaldehyde preparation methods for pressure and temperature dependent laser-induced fluorescence measurements

NASA Astrophysics Data System (ADS)

Burkert, A.; Müller, D.; Rieger, S.; Schmidl, G.; Triebel, W.; Paa, W.

2015-12-01

Formaldehyde is an excellent tracer for the early phase of ignition of hydrocarbon fuels and can be used, e.g., for characterization of single droplet ignition. However, due to its fast thermal decomposition at elevated temperatures and pressures, the determination of concentration fields from laser-induced fluorescence (LIF) measurements is difficult. In this paper, we address LIF measurements of this important combustion intermediate using a calibration cell. Here, formaldehyde is created from evaporation of paraformaldehyde. We discuss three setups for preparation of formaldehyde/air mixtures with respect to their usability for well-defined heating of formaldehyde/air mixtures. The "basic setup" uses a resist heater around the measurement cell for investigation of formaldehyde near vacuum conditions or formaldehyde/air samples after sequential admixing of air. The second setup, described for the first time in detail here, takes advantage of a constant flow formaldehyde/air regime which uses preheated air to reduce the necessary time for gas heating. We used the constant flow system to measure new pressure dependent LIF excitation spectra in the 343 nm spectral region (414 absorption band of formaldehyde). The third setup, based on a novel concept for fast gas heating via excitation of SF6 (chemically inert gas) using a TEA (transverse excitation at atmospheric pressure) CO2 laser, allows to further minimize both gas heating time and thermal decomposition. Here, an admixture of CO2 is served for real time temperature measurement based on Raman scattering. The applicability of the fast laser heating system has been demonstrated with gas mixtures of SF6 + air, SF6 + N2, as well as SF6 + N2 + CO2 at 1 bar total pressure.

Antibody production in rats after long-term exposure to formaldehyde

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holmstroem, M.R.; Rynnel-Dagoeoe, B.Wi.; Wilhelmsson, B.

1989-09-01

Sprague-Dawley rats were vaccinated with pneumococcal polysaccharide antigens and tetanus toxoid to evaluate the immunologic effects of long-term formaldehyde exposure. The antibody response to vaccination was measured 3 to 4 weeks later by enzyme-linked immunosorbent assay. An IgG response to pneumococcal polysaccharides and to tetanus toxoid was found in both the formaldehyde-exposed group and a control group of rats not exposed to formaldehyde. The IgM response to tetanus toxoid was significant in both groups but neither group showed a significant IgM response to pneumococcal polysaccharides. There were thus no signs of impaired B-cell function in rats exposed to a highmore » concentration (12.6 ppm) of formaldehyde for nearly 2 years.« less

Measurements of formaldehyde and acetaldehyde in the urban ambient air

NASA Astrophysics Data System (ADS)

Salas, Louis J.; Singh, Hanwant B.

Acetaldehyde and formaldehyde were measured in urban ambient air by analyzing their 2,4-dinitrophenylhydrazine derivatives with reverse-phase, high-performance liquid chromatography (HPLC). A series of nine short term field experiments were performed in eight cities. Concurrent formaldehyde measurements using the chromotropic-acid procedure show reasonable agreement (±30 %) between the two methods. Average summertime ambient urban formaldehyde (HCHO) concentrations of 10-20 ppb (10 -9v/v) are significantly higher than the average acetaldehyde (CH 3CHO) concentrations of 1-2 ppb. There is evidence of much reduced formaldehyde levels in winter months. Exceptionally high, absolute (8.5 ppb av.) and relative ( HCHO/CH 3CHO ~ 2 ) acetaldehyde concentrations are measured in the South Coast Air Basin of California.

[The magic universe of cures: the role of magic practices and witchcraft in the universe of 17th century Mato Grosso].

PubMed

Sá, Mario

2009-01-01

The article analyzes the role of healing agents played by practitioners of magic and witchcraft in Mato Grosso society during the 17th century. It observes that magic and witchcraft were developed as competitors, alternatives or associated with other forms of healing (official and lay). It points out how such roles contributed to the process of subjugating its practitioners, especially Africans, Indians and their descendents, and were appropriated as an opportunity for survival in the colonial slave society. The pastoral visit made by Bruno Pinna in 1785 to Cuiabá and nearby areas served as the principal source of knowledge regarding the practices and practitioners of magic and witchcraft.

40 CFR 721.3812 - Substituted phenols and formaldehyde polymer, alkylated (generic).

Code of Federal Regulations, 2010 CFR

2010-07-01

... polymer, alkylated (generic). 721.3812 Section 721.3812 Protection of Environment ENVIRONMENTAL PROTECTION... New Uses for Specific Chemical Substances § 721.3812 Substituted phenols and formaldehyde polymer... substance identified generically as substituted phenols and formaldehyde polymer, alkylated (PMN P-00-0542...

40 CFR 721.3812 - Substituted phenols and formaldehyde polymer, alkylated (generic).

Code of Federal Regulations, 2011 CFR

2011-07-01

... polymer, alkylated (generic). 721.3812 Section 721.3812 Protection of Environment ENVIRONMENTAL PROTECTION... New Uses for Specific Chemical Substances § 721.3812 Substituted phenols and formaldehyde polymer... substance identified generically as substituted phenols and formaldehyde polymer, alkylated (PMN P-00-0542...

40 CFR 721.3812 - Substituted phenols and formaldehyde polymer, alkylated (generic).

Code of Federal Regulations, 2014 CFR

2014-07-01

... polymer, alkylated (generic). 721.3812 Section 721.3812 Protection of Environment ENVIRONMENTAL PROTECTION... New Uses for Specific Chemical Substances § 721.3812 Substituted phenols and formaldehyde polymer... substance identified generically as substituted phenols and formaldehyde polymer, alkylated (PMN P-00-0542...

40 CFR 721.3812 - Substituted phenols and formaldehyde polymer, alkylated (generic).

Code of Federal Regulations, 2013 CFR

2013-07-01

... polymer, alkylated (generic). 721.3812 Section 721.3812 Protection of Environment ENVIRONMENTAL PROTECTION... New Uses for Specific Chemical Substances § 721.3812 Substituted phenols and formaldehyde polymer... substance identified generically as substituted phenols and formaldehyde polymer, alkylated (PMN P-00-0542...

40 CFR 721.3812 - Substituted phenols and formaldehyde polymer, alkylated (generic).

Code of Federal Regulations, 2012 CFR

2012-07-01

... polymer, alkylated (generic). 721.3812 Section 721.3812 Protection of Environment ENVIRONMENTAL PROTECTION... New Uses for Specific Chemical Substances § 721.3812 Substituted phenols and formaldehyde polymer... substance identified generically as substituted phenols and formaldehyde polymer, alkylated (PMN P-00-0542...

78 FR 51695 - Formaldehyde Emissions Standards for Composite Wood Products; Extension of Comment Period

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-21

... Formaldehyde Emissions Standards for Composite Wood Products; Extension of Comment Period AGENCY: Environmental... composite wood products. After receiving requests for an extension, EPA extended the comment period from... Environmental protection, Formaldehyde, Reporting and recordkeeping requirements, Toxic substances, Wood. Dated...

FORMALDEHYDE-INDUCED GENE EXPRESSION IN F344 RAT NASAL RESPIRATORY EPITHELIUM.

EPA Science Inventory

Formaldehyde-induced gene expression in F344 rat nasal respiratory epithelium

ABSTRACT

Formaldehyde, an occupational and environmental toxicant used extensively in the manufacturing of many household and personal use products, is known to induce squamous cell carci...

Energetics and mechanisms for the unimolecular dissociation of protonated trioses and relationship to proton-mediated formaldehyde polymerization to carbohydrates in interstellar environments.

PubMed

Simakov, Anton; Sekiguchi, Osamu; Bunkan, Arne Joakim C; Uggerud, Einar

2011-12-28

We report the unimolecular decomposition of protonated glyceraldehyde, [HOCH(2)CH(OH)CHO]H(+), and protonated dihydroxyacetone, [HOCH(2)C(O)CH(2)OH]H(+). On the basis of mass spectrometric experiments and computational quantum chemistry, we have found that these isomeric ions interconvert freely at energies below that required for their unimolecular decompositions. The losses of formaldehyde and water (the latter also followed by CO loss) are the dominating processes, with formaldehyde loss having the lower energetic threshold. The reverse of the formaldehyde loss, namely, the addition of formaldehyde to protonated glycolaldehyde, appears to be an inefficient reaction at low temperature and pressure in the gas phase, leading to dissociation products. The relevance of these findings to interstellar chemistry and prebiotic chemistry is discussed, and it is concluded that the suggestion made in the literature that successive addition of formaldehyde by proton-assisted reactions should account for interstellar carbohydrates most likely is incorrect. © 2011 American Chemical Society

A new system to reduce formaldehyde levels improves safety conditions during gross veterinary anatomy learning.

PubMed

Nacher, Víctor; Llombart, Cristina; Carretero, Ana; Navarro, Marc; Ysern, Pere; Calero, Sebastián; Fígols, Enric; Ruberte, Jesús

2007-01-01

Dissection is a very useful method of learning veterinary anatomy. However, formaldehyde, which is widely used to preserve cadavers, is an irritant, and it has recently been classified as a carcinogen. In 1997, the Instituto Nacional de Seguridad e Higiene en el Trabajo [National Institute of Workplace Security and Hygiene] found that the levels of formaldehyde in our dissection room were above the threshold limit values. Unfortunately, no optimal substitute for formaldehyde is currently available. Therefore, we designed a new ventilation system that combines slow propulsion of fresh air from above the dissection table and rapid aspiration of polluted air from the perimeter. Formaldehyde measurements performed in 2004, after the introduction of this new system into our dissection laboratory, showed a dramatic reduction (about tenfold, or 0.03 ppm). A suitable propelling/aspirating air system successfully reduces the concentration of formaldehyde in the dissection room, significantly improving safety conditions for students, instructors, and technical staff during gross anatomy learning.

Mammals divert endogenous genotoxic formaldehyde into one-carbon metabolism.

PubMed

Burgos-Barragan, Guillermo; Wit, Niek; Meiser, Johannes; Dingler, Felix A; Pietzke, Matthias; Mulderrig, Lee; Pontel, Lucas B; Rosado, Ivan V; Brewer, Thomas F; Cordell, Rebecca L; Monks, Paul S; Chang, Christopher J; Vazquez, Alexei; Patel, Ketan J

2017-08-31

The folate-driven one-carbon (1C) cycle is a fundamental metabolic hub in cells that enables the synthesis of nucleotides and amino acids and epigenetic modifications. This cycle might also release formaldehyde, a potent protein and DNA crosslinking agent that organisms produce in substantial quantities. Here we show that supplementation with tetrahydrofolate, the essential cofactor of this cycle, and other oxidation-prone folate derivatives kills human, mouse and chicken cells that cannot detoxify formaldehyde or that lack DNA crosslink repair. Notably, formaldehyde is generated from oxidative decomposition of the folate backbone. Furthermore, we find that formaldehyde detoxification in human cells generates formate, and thereby promotes nucleotide synthesis. This supply of 1C units is sufficient to sustain the growth of cells that are unable to use serine, which is the predominant source of 1C units. These findings identify an unexpected source of formaldehyde and, more generally, indicate that the detoxification of this ubiquitous endogenous genotoxin creates a benign 1C unit that can sustain essential metabolism.

When "Holiday Magic" Hurts.

ERIC Educational Resources Information Center

Goldstein, Karen

2001-01-01

Claims that religious messages in public school are not acceptable and are hurtful to kids who do not subscribe to the beliefs expressed in those messages. Describes the author's personal experience in helping a teacher transform the script for "Christmas Magic" into the more inclusive "Holiday Magic." (RS)

[Investigation into the formation of proportions of "realistic thinking vs magical thinking" in paranoid schizophrenia].

PubMed

Jarosz, M; Pankiewicz, Z; Buczek, I; Poprawska, I; Rojek, J; Zaborowski, A

1993-01-01

Both magical thinking among healthy persons and magical and symbolic thinking in schizophrenia were discussed. The investigation covered 100 paranoid schizophrenics. They also underwent an examination in connection with the formation of the remaining 3 proportions. Both "realistic thinking and magical thinking" scales were used. An ability to think realistically was preserved, to a varying degree, in all patients, with 50% of those examined having shown an explicit or very explicit ability to follow realistic thinking. The above findings deviate from a simplified cognitive model within the discussed range. It was further confirmed that realistic thinking may coexist with magical thinking, and, in some cases, it concerns the same events. That type of disorders of the content of thinking are referred to as magical-realistic interpenetration. The results, and particularly high coefficient of negative correlation within the scales of the examined proportions, confirm the correctness of the assumption that the investigated modes of thinking form an antithetic bipolarity of proportions, aggregating antithetic values, therefore being also complementary.

Magical attachment: Children in magical relations with hospital clowns

PubMed Central

2012-01-01

The aim of the present study was to achieve a theoretical understanding of several different-age children's experiences of magic relations with hospital clowns in the context of medical care, and to do so using psychological theory and a child perspective. The method used was qualitative and focused on nine children. The results showed that age was important to consider in better understanding how the children experienced the relation with the hospital clowns, how they described the magical aspects of the encounter and how they viewed the importance of clown encounters to their own well-being. The present theoretical interpretation characterized the encounter with hospital clowns as a magical safe area, an intermediate area between fantasy and reality. The discussion presented a line of reasoning concerning a magical attachment between the child and the hospital clowns, stating that this attachment: a) comprised a temporary relation; b) gave anonymity; c) entailed reversed roles; and d) created an emotional experience of boundary-transcending opportunities. PMID:22371813

The presence of magical thinking in obsessive compulsive disorder.

PubMed

Einstein, Danielle A; Menzies, Ross G

2004-05-01

Two research groups have raised the possibility that magical ideation may be a fundamental feature of obsessive-compulsive disorder. It has been proposed to underlie thought action fusion and superstitious beliefs. In this study, the Magical Ideation scale, the Lucky Behaviours and Lucky Beliefs scales, the Thought Action Fusion-Revised scale, the Padua Inventory, and the Obsessive Compulsive Inventory-Short Version were completed by 60 obsessive compulsive patients at a hospital clinic. Of all the measures, the Magical Ideation (MI) scale was found to be the most strongly related to obsessive compulsive symptoms. Large and significant relationships between MI scores and the measures of OCD were obtained even when alternative constructs (Lucky Behaviours, Lucky Beliefs, Thought Action Fusion-Revised scales) were held constant. No other variable remained significantly related to the Obsessive Compulsive Inventory-Short Version when magical ideation scores were held constant. The findings suggest that a general magical thinking tendency may underpin previous observed links between superstitiousness, thought action fusion and OCD severity.

Growth of Pseudomonas C on C1 Compounds: Continuous Culture

PubMed Central

Battat, E.; Goldberg, I.; Mateles, R. I.

1974-01-01

Pseudomonas C was grown in continuous culture on methanol, formaldehyde, or formate as sole carbon source. On methanol μmax = 0.49/h and yield constant (Y) = 0.54; on formaldehyde and on unsupplemented media, μmax was about 0.2/h and Y was 0.15, whereas addition of p-aminobenzoic acid, folic acid, serine, or glycine to the medium raised Y to about 0.26 to 0.29, and addition of p-aminobenzoic acid, folic acid, serine, nicotinamide adenine dinucleotide, and Tween 80 raised the yield to 0.35. On formate and on unsupplemented media, μmax = 0.2/h and Y = 0.02, whereas addition of 0.1 mM p-aminobenzoic acid increased μmax to about 0.47 and Y to about 0.23. At low cell concentrations or growth rates a beneficial effect of CO2 was observed. Formaldehyde or formate, when added together with methanol, were utilized simultaneously with the methanol. PMID:4375436

Innovative ventilation system for animal anatomy laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lacey, D.R.; Smith, D.C.

1997-04-01

A unique ventilation system was designed and built to reduce formaldehyde fumes in the large animal anatomy lab at the Vet Medical Center at Cornell University. The laboratory includes four rooms totaling 5,500 ft{sup 2}. The main room has 2,300 ft{sup 2} and houses the laboratory where up to 60 students dissect as many as 12 horses at a time. Other rooms are a cold storage locker, an animal preparation room and a smaller lab for specialized instruction. The large animal anatomy laboratory has a history of air quality complaints despite a fairly high ventilation rate of over 10 airmore » changes/hour. The horses are embalmed, creating a voluminous source of formaldehyde and phenol vapors. Budget constraints and increasingly stringent exposure limits for formaldehyde presented a great challenge to design a ventilation system that yields acceptable air quality. The design solution included two innovative elements: air-to-air heat recovery, and focused ventilation.« less

[Usefulness of the fruit fly for assessment of mutagenicity of benzene, acetaldehyde and formaldehyde].

PubMed

Krogulski, A

1994-01-01

Among the contaminants of water, soil and air the number of mutagenic and carcinogenic substances is increasing. For the assessment of health risk connected with the simple and cheap methods are necessary which could detected and measure the mutagenicity of these substances. The widely used tests using prokaryotes give negative results in the tests of certain substances which are carcinogenic in mammals. In the case of benzene and acetaldehyde Ames test gives false negative results, and in the case of formaldehyde the results are equivocal. An advantage of fruit fly Drosophila melanogaster used for this purpose is that its cell structures, enzymes and metabolic processes are similar to those of mammals. For the demonstration of mutagenicity of benzene, acetaldehyde and formaldehyde the test of somatic mutation and recombination SMART was carried out in these flies. The results confirmed the usefulness of the SMART test for the demonstration of the mutagenicity of contaminants in the environment.

Gaseous and Particulate Emissions from Diesel Engines at Idle and under Load: Comparison of Biodiesel Blend and Ultralow Sulfur Diesel Fuels

PubMed Central

Chin, Jo-Yu; Batterman, Stuart A.; Northrop, William F.; Bohac, Stanislav V.; Assanis, Dennis N.

2015-01-01

Diesel exhaust emissions have been reported for a number of engine operating strategies, after-treatment technologies, and fuels. However, information is limited regarding emissions of many pollutants during idling and when biodiesel fuels are used. This study investigates regulated and unregulated emissions from both light-duty passenger car (1.7 L) and medium-duty (6.4 L) diesel engines at idle and load and compares a biodiesel blend (B20) to conventional ultralow sulfur diesel (ULSD) fuel. Exhaust aftertreatment devices included a diesel oxidation catalyst (DOC) and a diesel particle filter (DPF). For the 1.7 L engine under load without a DOC, B20 reduced brake-specific emissions of particulate matter (PM), elemental carbon (EC), nonmethane hydrocarbons (NMHCs), and most volatile organic compounds (VOCs) compared to ULSD; however, formaldehyde brake-specific emissions increased. With a DOC and high load, B20 increased brake-specific emissions of NMHC, nitrogen oxides (NOx), formaldehyde, naphthalene, and several other VOCs. For the 6.4 L engine under load, B20 reduced brake-specific emissions of PM2.5, EC, formaldehyde, and most VOCs; however, NOx brake-specific emissions increased. When idling, the effects of fuel type were different: B20 increased NMHC, PM2.5, EC, formaldehyde, benzene, and other VOC emission rates from both engines, and changes were sometimes large, e.g., PM2.5 increased by 60% for the 6.4 L/2004 calibration engine, and benzene by 40% for the 1.7 L engine with the DOC, possibly reflecting incomplete combustion and unburned fuel. Diesel exhaust emissions depended on the fuel type and engine load (idle versus loaded). The higher emissions found when using B20 are especially important given the recent attention to exposures from idling vehicles and the health significance of PM2.5. The emission profiles demonstrate the effects of fuel type, engine calibration, and emission control system, and they can be used as source profiles for apportionment, inventory, and exposure purposes. PMID:25722535

Sort-Seq Approach to Engineering a Formaldehyde-Inducible Promoter for Dynamically Regulated Escherichia coli Growth on Methanol

PubMed Central

2017-01-01

Tight and tunable control of gene expression is a highly desirable goal in synthetic biology for constructing predictable gene circuits and achieving preferred phenotypes. Elucidating the sequence–function relationship of promoters is crucial for manipulating gene expression at the transcriptional level, particularly for inducible systems dependent on transcriptional regulators. Sort-seq methods employing fluorescence-activated cell sorting (FACS) and high-throughput sequencing allow for the quantitative analysis of sequence–function relationships in a robust and rapid way. Here we utilized a massively parallel sort-seq approach to analyze the formaldehyde-inducible Escherichia coli promoter (Pfrm) with single-nucleotide resolution. A library of mutated formaldehyde-inducible promoters was cloned upstream of gfp on a plasmid. The library was partitioned into bins via FACS on the basis of green fluorescent protein (GFP) expression level, and mutated promoters falling into each expression bin were identified with high-throughput sequencing. The resulting analysis identified two 19 base pair repressor binding sites, one upstream of the −35 RNA polymerase (RNAP) binding site and one overlapping with the −10 site, and assessed the relative importance of each position and base therein. Key mutations were identified for tuning expression levels and were used to engineer formaldehyde-inducible promoters with predictable activities. Engineered variants demonstrated up to 14-fold lower basal expression, 13-fold higher induced expression, and a 3.6-fold stronger response as indicated by relative dynamic range. Finally, an engineered formaldehyde-inducible promoter was employed to drive the expression of heterologous methanol assimilation genes and achieved increased biomass levels on methanol, a non-native substrate of E. coli. PMID:28463494

Magic and Misdirection: The Influence of Social Cues on the Allocation of Visual Attention While Watching a Cups-and-Balls Routine

PubMed Central

Hergovich, Andreas; Oberfichtner, Bernhard

2016-01-01

In recent years, a body of research that regards the scientific study of magic performances as a promising method of investigating psychological phenomena in an ecologically valid setting has emerged. Seemingly contradictory findings concerning the ability of social cues to strengthen a magic trick’s effectiveness have been published. In this experiment, an effort was made to disentangle the unique influence of different social and physical triggers of attentional misdirection on observers’ overt and covert attention. The ability of 120 participants to detect the mechanism of a cups-and-balls trick was assessed, and their visual fixations were recorded using an eye-tracker while they were watching the routine. All the investigated techniques of misdirection, including sole usage of social cues, were shown to increase the probability of missing the trick mechanism. Depending on the technique of misdirection used, very different gaze patterns were observed. A combination of social and physical techniques of misdirection influenced participants’ overt attention most effectively. PMID:27303327

Determination of ultra-trace formaldehyde in air using ammonium sulfate as derivatization reagent and capillary electrophoresis coupled with on-line electrochemiluminescence detection.

PubMed

Deng, Biyang; Liu, Yang; Yin, Huihui; Ning, Xi; Lu, Hua; Ye, Li; Xu, Quanxiu

2012-03-15

The reaction between formaldehyde and ammonium ion to produce hexamethylenetetramine is well known. The reaction conditions are very easily controlled in situ and the experiment operation is very simple. However, such derivatization reaction for trace formaldehyde determination using capillary electrophoresis (CE) electrochemiluminescence (ECL) has not been reported before. In this study, the application of ammoniun sulfate as derivatization reagent to in-situ determination of formaldehyde in air was reported. Based on ECL enhancement of tris(2,2'-bipyridyl)ruthenium(II) with hexamethylenetetramine, a novel approach for the determination of ultra-trace formaldehyde in air using CE coupled with on-line ECL of tris(2,2'-bipyridyl)ruthenium(II) has been developed. The parameters affecting separation and detection such as detection potential, concentration and pH of phosphate buffer, and electrokinetic voltage, were investigated. Under the optimal conditions, the linear concentration range of formaldehyde in air was from 0.48 μg/m(3) to 96 mg/m(3) (linear range covering 5 orders of magnitude). The limit of detection (3σ) was 0.15 μg/m(3). The relative standard deviations of peak height and migration time for six consecutive injection of 1 ng/mL formaldehyde derivative were 0.9% and 0.8%, respectively. The recoveries of formaldehyde in air were between 99.3% and 101%. Copyright © 2012 Elsevier B.V. All rights reserved.

The genetics of rhizosheath size in a multiparent mapping population of wheat.

PubMed

Delhaize, Emmanuel; Rathjen, Tina M; Cavanagh, Colin R

2015-08-01

Rhizosheaths comprise soil that adheres to plant roots and, in some species, are indicative of root hair length. In this study, the genetics of rhizosheath size in wheat was investigated by screening the progeny of multiparent advanced generation intercrosses (MAGIC). Two MAGIC populations were screened for rhizosheath size using a high throughput method. One MAGIC population was developed from intercrosses between four parents (4-way) and the other from intercrosses between eight parents (8-way). Transgressive segregation for rhizosheath size was observed in both the 4-way and 8-way MAGIC populations. A quantitative trait loci (QTL) analysis of the 4-way population identified six major loci located on chromosomes 2B, 4D, 5A, 5B, 6A, and 7A together accounting for 42% of the variation in rhizosheath size. Rhizosheath size was strongly correlated with root hair length and was robust across different soil types in the absence of chemical constraints. Rhizosheath size in the MAGIC populations was a reliable surrogate for root hair length and, therefore, the QTL identified probably control root hair elongation. Members of the basic helix-loop-helix family of transcription factors have previously been identified to regulate root hair length in Arabidopsis and rice. Since several wheat members of the basic helix-loop-helix family of genes are located within or near the QTL, these genes are candidates for controlling the long root hair trait. The QTL for rhizosheath size identified in this study provides the opportunity to implement marker-assisted selection to increase root hair length for improved phosphate acquisition in wheat. © The Author 2015. Published by Oxford University Press on behalf of the Society for Experimental Biology.

Paracelsus confronts the saints: miracles, healing and the secularization of magic.

PubMed

Webster, C

1995-12-01

The sixteenth and seventeenth centuries witnessed an erosion of the role played by the church in healing. Magical practices mediated by the church were replaced by the resources of medicine. This represented an important cultural development and it is often regarded as a manifestation of increasing secularization, the decline of magic and rise of science. This paper examines this issue with special reference to miraculous healing associated with saints, which constituted one of the most important facets of magic controlled by the church. It will be suggested that Paracelsus (Theophrast von Hohenheim, 1493-1541) played an important part in the argument concerning the miraculous powers of saints. Many works by Paracelsus produced at various points in his career were relevant to this issue, but De causis morborum invisibilium, the sequel to his important Opus Paraminum (1531), was especially significant. The question of miraculous healing was therefore important in the first, full presentation of the new system of medicine developed by Paracelsus. Modern commentators have understandably found De causis morborum invisibilium less intelligible and congenial than the more accessible Opus Paramirum. But the former was important to Paracelsus, and it addressed problems that were fundamental to his audience. This case-study shows how conclusions reached by Paracelsus about medical questions were integrally tied up with his theological standpoint and with his wider reaction to the acute crisis of confidence which affected the church and the established social order at the beginning of the sixteenth century. By eliminating the miraculous intervention of saints and promoting the secularization of magic, Paracelsus was contributing to one of the important cultural changes associated with the Reformation.

Magic in the machine: a computational magician's assistant

PubMed Central

Williams, Howard; McOwan, Peter W.

2014-01-01

A human magician blends science, psychology, and performance to create a magical effect. In this paper we explore what can be achieved when that human intelligence is replaced or assisted by machine intelligence. Magical effects are all in some form based on hidden mathematical, scientific, or psychological principles; often the parameters controlling these underpinning techniques are hard for a magician to blend to maximize the magical effect required. The complexity is often caused by interacting and often conflicting physical and psychological constraints that need to be optimally balanced. Normally this tuning is done by trial and error, combined with human intuitions. Here we focus on applying Artificial Intelligence methods to the creation and optimization of magic tricks exploiting mathematical principles. We use experimentally derived data about particular perceptual and cognitive features, combined with a model of the underlying mathematical process to provide a psychologically valid metric to allow optimization of magical impact. In the paper we introduce our optimization methodology and describe how it can be flexibly applied to a range of different types of mathematics based tricks. We also provide two case studies as exemplars of the methodology at work: a magical jigsaw, and a mind reading card trick effect. We evaluate each trick created through testing in laboratory and public performances, and further demonstrate the real world efficacy of our approach for professional performers through sales of the tricks in a reputable magic shop in London. PMID:25452736

40 CFR 721.10134 - Formaldehyde, polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (generic).

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Formaldehyde, polymer with... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10134 Formaldehyde, polymer..., polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (PMN P-05-1) is subject to...

40 CFR 721.10134 - Formaldehyde, polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (generic).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Formaldehyde, polymer with... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10134 Formaldehyde, polymer..., polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (PMN P-05-1) is subject to...

40 CFR 721.10286 - Formaldehyde, polymer with .alpha.- (2-aminomethylethyl)- .omega. - (2 - aminomethylethoxy)poly...

Code of Federal Regulations, 2013 CFR

2013-07-01

...-aminomethylethyl)- .omega. - (2 - aminomethylethoxy)poly[ oxy(methyl - 1,2 - ethanediyl)] and 4 - (1,1... Specific Chemical Substances § 721.10286 Formaldehyde, polymer with .alpha.- (2-aminomethylethyl)- .omega... formaldehyde, polymer with .alpha.-(2-aminomethylethyl)-.omega.-(2-aminomethylethoxy)poly[oxy(methyl-1,2...

40 CFR 721.10134 - Formaldehyde, polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (generic).

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Formaldehyde, polymer with... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10134 Formaldehyde, polymer..., polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (PMN P-05-1) is subject to...

40 CFR 721.10533 - Amine-modified urea-formaldehyde polymer (generic).

Code of Federal Regulations, 2014 CFR

2014-07-01

... polymer (generic). 721.10533 Section 721.10533 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10533 Amine-modified urea-formaldehyde polymer (generic). (a) Chemical... as amine-modified urea-formaldehyde polymer (PMN P-12-182) is subject to reporting under this section...

40 CFR 721.10134 - Formaldehyde, polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (generic).

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Formaldehyde, polymer with... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10134 Formaldehyde, polymer..., polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (PMN P-05-1) is subject to...

40 CFR 721.10533 - Amine-modified urea-formaldehyde polymer (generic).

Code of Federal Regulations, 2013 CFR

2013-07-01

... polymer (generic). 721.10533 Section 721.10533 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10533 Amine-modified urea-formaldehyde polymer (generic). (a) Chemical... as amine-modified urea-formaldehyde polymer (PMN P-12-182) is subject to reporting under this section...

40 CFR 721.10134 - Formaldehyde, polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (generic).

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Formaldehyde, polymer with... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10134 Formaldehyde, polymer..., polymer with dialkylphenylamine, dialkylphenol and trimethylhexanediamine (PMN P-05-1) is subject to...

40 CFR 721.8085 - Reaction product of substituted aromatic diol, formaldehyde and alkanolamine, propoxylated...

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Reaction product of substituted... Reaction product of substituted aromatic diol, formaldehyde and alkanolamine, propoxylated (generic). (a... generically as reaction product of substituted aromatic diol, formaldehyde and alkanolamine, propoxylated (PMN...

40 CFR 721.8085 - Reaction product of substituted aromatic diol, formaldehyde and alkanolamine, propoxylated...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Reaction product of substituted... Reaction product of substituted aromatic diol, formaldehyde and alkanolamine, propoxylated (generic). (a... generically as reaction product of substituted aromatic diol, formaldehyde and alkanolamine, propoxylated (PMN...

40 CFR 721.3800 - Formaldehyde, condensated polyoxyethylene fatty acid, ester with styrenated phenol, ethylene...

Code of Federal Regulations, 2010 CFR

2010-07-01

... polyoxyethylene fatty acid, ester with styrenated phenol, ethylene oxide adduct. 721.3800 Section 721.3800... Formaldehyde, condensated polyoxyethylene fatty acid, ester with styrenated phenol, ethylene oxide adduct. (a... generically as formaldehyde, condensated polyoxyethylene fatty acid, ester with styrenated phenol, ethylene...

Chinese "Magic" Mirrors.

ERIC Educational Resources Information Center

Swinson, Derek B.

1992-01-01

Chinese "magic" mirrors are made from bronze with the front side a mirror and the reverse side a molded image. When light is reflected from the mirror,the image on the reverse side appears. Discusses reflections of conventional mirrors, possible explanations for the magic mirror phenomenon, and applications of the phenomenon to…

U.S. EPA, Pesticide Product Label, FLEAGO THE MAGIC CRYSTAL, 07/09/1997

EPA Pesticide Factsheets

2011-04-21

... Fleago The Magic Crystal '~~~:ul~~i~;~i~~!;~i~~fat~~I~~n~w~~~~: W~?~:~iA~~~~~r~Y '~~;: ... lhe Magic Crystal ...

Ethanol and air quality: influence of fuel ethanol content on emissions and fuel economy of flexible fuel vehicles.

PubMed

Hubbard, Carolyn P; Anderson, James E; Wallington, Timothy J

2014-01-01

Engine-out and tailpipe emissions of NOx, CO, nonmethane hydrocarbons (NMHC), nonmethane organic gases (NMOG), total hydrocarbons (THC), methane, ethene, acetaldehyde, formaldehyde, ethanol, N2O, and NH3 from a 2006 model year Mercury Grand Marquis flexible fuel vehicle (FFV) operating on E0, E10, E20, E30, E40, E55, and E80 on a chassis dynamometer are reported. With increasing ethanol content in the fuel, the tailpipe emissions of ethanol, acetaldehyde, formaldehyde, methane, and ammonia increased; NOx and NMHC decreased; while CO, ethene, and N2O emissions were not discernibly affected. NMOG and THC emissions displayed a pronounced minimum with midlevel (E20-E40) ethanol blends; 25-35% lower than for E0 or E80. Emissions of NOx decreased by approximately 50% as the ethanol content increased from E0 to E30-E40, with no further decrease seen with E55 or E80. We demonstrate that emission trends from FFVs are explained by fuel chemistry and engine calibration effects. Fuel chemistry effects are fundamental in nature; the same trend of increased ethanol, acetaldehyde, formaldehyde, and CH4 emissions and decreased NMHC and benzene emissions are expected for all FFVs. Engine calibration effects are manufacturer and model specific; emission trends for NOx, THC, and NMOG will not be the same for all FFVs. Implications for air quality are discussed.

40 CFR 86.1320-90 - Gas meter or flow instrumentation calibration; particulate, methanol, and formaldehyde measurement.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 20 2012-07-01 2012-07-01 false Gas meter or flow instrumentation... instrumentation calibration; particulate, methanol, and formaldehyde measurement. (a) Sampling for particulate, methanol and formaldehyde emissions requires the use of gas meters or flow instrumentation to determine...

40 CFR 86.1320-90 - Gas meter or flow instrumentation calibration; particulate, methanol, and formaldehyde measurement.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 20 2013-07-01 2013-07-01 false Gas meter or flow instrumentation... instrumentation calibration; particulate, methanol, and formaldehyde measurement. (a) Sampling for particulate, methanol and formaldehyde emissions requires the use of gas meters or flow instrumentation to determine...

40 CFR 86.1320-90 - Gas meter or flow instrumentation calibration; particulate, methanol, and formaldehyde measurement.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Gas meter or flow instrumentation... instrumentation calibration; particulate, methanol, and formaldehyde measurement. (a) Sampling for particulate, methanol and formaldehyde emissions requires the use of gas meters or flow instrumentation to determine...

40 CFR 86.1320-90 - Gas meter or flow instrumentation calibration; particulate, methanol, and formaldehyde measurement.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Gas meter or flow instrumentation... instrumentation calibration; particulate, methanol, and formaldehyde measurement. (a) Sampling for particulate, methanol and formaldehyde emissions requires the use of gas meters or flow instrumentation to determine...

24 CFR 3280.308 - Formaldehyde emission controls for certain wood products.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 24 Housing and Urban Development 5 2014-04-01 2014-04-01 false Formaldehyde emission controls for certain wood products. 3280.308 Section 3280.308 Housing and Urban Development Regulations Relating to... Body and Frame Construction Requirements § 3280.308 Formaldehyde emission controls for certain wood...

24 CFR 3280.308 - Formaldehyde emission controls for certain wood products.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 24 Housing and Urban Development 5 2012-04-01 2012-04-01 false Formaldehyde emission controls for certain wood products. 3280.308 Section 3280.308 Housing and Urban Development Regulations Relating to... Body and Frame Construction Requirements § 3280.308 Formaldehyde emission controls for certain wood...

24 CFR 3280.308 - Formaldehyde emission controls for certain wood products.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 24 Housing and Urban Development 5 2013-04-01 2013-04-01 false Formaldehyde emission controls for certain wood products. 3280.308 Section 3280.308 Housing and Urban Development Regulations Relating to... Body and Frame Construction Requirements § 3280.308 Formaldehyde emission controls for certain wood...

24 CFR 3280.309 - Health Notice on formaldehyde emissions.

Code of Federal Regulations, 2011 CFR

2011-04-01

... efficiency standards may allow formaldehyde and other contaminants to accumulate in the indoor air. Additional ventilation to dilute the indoor air may be obtained from a passive or mechanical ventilation... offered with this home. High indoor temperatures and humidity raise formaldehyde levels. When a home is to...

Formaldehyde condensation products of model phenols for conifer bark tannins

Treesearch

Richard W. Hemingway; Gerald W. McGraw

1978-01-01

Gel permeation chromatography of the condensation products of phenols and formaldehyde proved effective in understanding the reactions of condensed tannins with formaldehyde. Rates of condensation of phloroglucinols, resorcinols, catechols, (+)catechins, and (-)epicatechin were examined to determine if methylol-tannins from southern pine bark could be prepared as resin...

Formaldehyde condensation products of model phenols for conifer bark tannins

Treesearch

R.W. Hemingway; G.W. McGraw

1978-01-01

Gel permeation chromatograpy of the condensation products of phenols and formaldehyde proved effective in understanding the reactions of condensed tannins with formaldehyde. Rates of condensation of phloroglucinols, resorcinols, catechols, (+)catechin, and (-)epicatechin were examined to determine if methylol-tannins from southern pine bark could be prepared as resin...

FORMALDEHYDE GAS INACTIVATION OF BACILLUS ANTHRACIS, BACILLUS SUBTILIS AND GEOBACILLUS STEAROTHERMOPHILUS SPORES ON INDOOR SURFACE MATERIALS.

EPA Science Inventory

Research evaluated the decontamination of Bacillus anthracis, Bacillus subtilis, and Geobacillus stearothermophilus spores on indoor surface material using formaldehyde gas. Spores were dried on seven types of indoor surfaces and exposed to 1100 ppm formaldehyde gas for 10 hr. Fo...

40 CFR Table 4 to Subpart Zzzz of... - Requirements for Performance Tests

Code of Federal Regulations, 2013 CFR

2013-07-01

... determine O2 concentration must be made at the same time as the measurements for formaldehyde or THC... formaldehyde or THC concentration. iv. If demonstrating compliance with the formaldehyde percent reduction...-hour or longer runs. v. If demonstrating compliance with the THC percent reduction requirement, measure...

40 CFR Table 4 to Subpart Zzzz of... - Requirements for Performance Tests

Code of Federal Regulations, 2014 CFR

2014-07-01

... determine O2 concentration must be made at the same time as the measurements for formaldehyde or THC... formaldehyde or THC concentration. iv. If demonstrating compliance with the formaldehyde percent reduction...-hour or longer runs. v. If demonstrating compliance with the THC percent reduction requirement, measure...

40 CFR 721.10286 - Formaldehyde, polymer with .alpha.-(2-aminomethylethyl)- .omega.-(2- aminomethylethoxy)poly[ oxy...

Code of Federal Regulations, 2014 CFR

2014-07-01

...-aminomethylethyl)- .omega.-(2- aminomethylethoxy)poly[ oxy(methyl- 1,2-ethanediyl)] and 4-(1,1-dimethylethyl)phenol... Specific Chemical Substances § 721.10286 Formaldehyde, polymer with .alpha.-(2-aminomethylethyl)- .omega... formaldehyde, polymer with .alpha.-(2- aminomethylethyl)-.omega.-(2- aminomethylethoxy)poly[oxy(methyl- 1,2...

40 CFR 721.10286 - Formaldehyde, polymer with .alpha.-(2-aminomethylethyl)- .omega.-(2-aminomethylethoxy) poly[oxy...

Code of Federal Regulations, 2012 CFR

2012-07-01

...-aminomethylethyl)- .omega.-(2-aminomethylethoxy) poly[oxy(methyl-1,2-ethanediyl)] and 4-(1,1-dimethylethyl)phenol... Specific Chemical Substances § 721.10286 Formaldehyde, polymer with .alpha.-(2-aminomethylethyl)- .omega... formaldehyde, polymer with .alpha.-(2-aminomethylethyl)-.omega.-(2-aminomethylethoxy)poly[oxy(methyl-1,2...

40 CFR 86.237-08 - Dynamometer test run, gaseous emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... minutes of the end of the sample collection phase of the test. Obtain methanol and formaldehyde sample... collection phase of the test. Obtain methanol and formaldehyde sample analyses, if applicable, within 24... the sample collection phase of the test. Obtain methanol and formaldehyde sample analyses, if...

40 CFR 86.237-08 - Dynamometer test run, gaseous emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... minutes of the end of the sample collection phase of the test. Obtain methanol and formaldehyde sample... collection phase of the test. Obtain methanol and formaldehyde sample analyses, if applicable, within 24... the sample collection phase of the test. Obtain methanol and formaldehyde sample analyses, if...

IDENTIFICATION OF THE ROLE OF APOPTOSIS PATHWAYS POTENTIALLY INVOLVED IN FORMALDEHYDE-INDUCED CARCINOGENESIS USING CDNA ARRAYS

EPA Science Inventory

Identification of the Role of Apoptosis Pathways Potentially Involved in Formaldehyde- Induced Carcinogenesis Using cDNA Arrays.

Formaldehyde (FA) is a genotoxic chemical found in household, medicinal, and industrial products. Although the major source of human exposure is...

24 CFR 3280.308 - Formaldehyde emission controls for certain wood products.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 24 Housing and Urban Development 5 2010-04-01 2010-04-01 false Formaldehyde emission controls for certain wood products. 3280.308 Section 3280.308 Housing and Urban Development Regulations Relating to... Body and Frame Construction Requirements § 3280.308 Formaldehyde emission controls for certain wood...

24 CFR 3280.308 - Formaldehyde emission controls for certain wood products.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 24 Housing and Urban Development 5 2011-04-01 2011-04-01 false Formaldehyde emission controls for certain wood products. 3280.308 Section 3280.308 Housing and Urban Development Regulations Relating to... Body and Frame Construction Requirements § 3280.308 Formaldehyde emission controls for certain wood...

Oligonucleotides as probes for studying polymerization reactions in dilute aqueous solution: II. Polycondensations

NASA Technical Reports Server (NTRS)

Kolb, V.; Orgel, L. E.

1995-01-01

We have prepared a [32P]-labeled oligonucleotide probe carrying a ureido (-NH-CO-NH2) function at its 3'-terminus. This labeled oligomer was used to study polycondensations of urea and formaldehyde and of various phenols and formaldehyde in aqueous solution. The formation of formaldehyde copolymers attached to the amido-function of the probe was monitored by gel electrophoresis. Our results are generally in agreement with those obtained using conventional techniques. Our method is suitable for monitoring potentially prebiotic polycondensation reactions involving formaldehyde.

Gas chromatographic determination of formaldehyde in coffee via thiazolidine derivative

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hayashi, T.; Reece, C.A.; Shibamoto, T.

Thiazolidine formed from trace quantities of formaldehyde in an aqueous solution containing cysteamine at pH 8 was extracted with chloroform and subsequently analyzed by a gas chromatograph equipped with a fused silica capillary column and a thermionic nitrogen-phosphorus specific detector. Recoveries of formaldehyde from the aqueous solutions at levels lower than 1 ppm were slightly over 100%. Quantitative analysis of formaldehyde in commercial brewed and instant coffees showed 3.4-4.5 ppm in the brewed and 10-16.3 ppm in the instant coffee.

Formaldehyde: a candidate toxic air contaminant. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frye, B.; Parker, T.

1988-03-01

Formaldehyde (HCHO) is a gas widely used in adhesives and resins, textiles, embalming fluids, fungicides, air fresheners, and cosmetics. It is directly emitted into the ambient outdoor air from vehicular and stationary sources, and is also produced in the atmosphere from other substances by photochemical smog processes. The International Agency for Research on Cancer (IARC) has determined that there is sufficient evidence for carcinogenicity of formaldehyde to animals, and limited evidence for carcinogenicity to humans. EPA classifies formaldehyde as a probable human carcinogen with a one in a million risk concentration of 0.08 ppb.

Structure-Stability Relationships of Polymers Based on Thermogravimetric Analysis Data. Part 1. Polyaliphatics, Polyalicyclics, Spiro Polymers and Phenylene-R-Polymers

DTIC Science & Technology

1974-12-01

Polymerization 13 9. Polymers with Bridged Ring Systems 14 10. Spiro Polymers 14 11. Polyphenylene s 16 12. Phenol - Formaldehyde Resins 17 13. Polyphenylene... Formaldehyde Resins A wide variety of phenol- formaldehyde resins , cured with various curing agents, has been evaluated. The Tdec’s (N 2 ), which...415 0 570 415 540C 2- 410 0 -CHI - 0- c-Ci.f-CCH = 1-eC.- 390 540 0 (Phenol- Formaldehyde Resins ) -CVH- (aliph.) 390 / F_ 535 0 - CHL" (epoxy

Oligonucleotides as probes for studying polymerization reactions in dilute aqueous solution. 2: Polycondensations

NASA Technical Reports Server (NTRS)

Kolb, Vera; Orgel, Leslie E.

1995-01-01

We have prepared a (P-32)-labeled oligonucleotide probe carrying a ureido (-NH-CO-NH2) function at its 3'-terminus. This labeled oligomer was used to study polycondensations of urea and formaldehyde and of various phenols and formaldehyde in aqueous solution. The formation of formaldehyde copolymers attached to the amido-function of the probe was monitored by gel electrophoresis. Our results are generally in agreement with those obtained using conventional techniques. Our method is suitable for monitoring potentially prebiotic polycondensation reactions involving formaldehyde.

IRIS Toxicological Review of Formaldehyde (Interagency ...

EPA Pesticide Factsheets

On June 2, 2010, the Toxicological Review of Formaldehyde and the charge to external peer reviewers were released for external peer review and public comment. The Toxicological Review and charge were reviewed internally by EPA and by other federal agencies and White House Offices before public release. In the new IRIS process, introduced by the EPA Administrator, all written comments on IRIS assessments submitted by other federal agencies and White House Offices will be made publicly available. Accordingly, interagency comments and the interagency science consultation draft of the IRIS Toxicological Review of Formaldehyde and the charge to external peer reviewers are posted on this site. The draft Toxicological Review of Formaldehyde-Inhalation Assessment provides scientific support and rationale for the hazard and dose-response assessment pertaining to chronic inhalation exposure to formaldehyde.

Increased formaldehyde in jet engine exhaust with changes to JP-8, lower temperature, and lower humidity irritates eyes and respiratory tract.

PubMed

Kobayashi, A; Kikukawa, A

2000-04-01

Formaldehyde (FA) in exhaust from F-4 aircraft with low smoke combustor(LSC) J79 engines has been reported to be of sufficient concentration to cause irritation. It has also been noted that eye and respiratory irritation became more frequent and severe after the fuel was changed from JP-4 to JP-8. The present sturdy investigated the effect of jet fuel and power setting on formaldehyde concentrations in the exhaust. We also investigated the exposure to formaldehyde among pilots and flight line personnel. The exhaust from LSC J79 engines using different types of fuel (JP-8 and JP-4) was sampled 50 m behind the engine at different power settings in July (summer season in Japan) and February (winter season ). It was also sampled at 75% power settings using JP-8 in July. At an idle power setting, the FA concentration was higher in the exhaust of engines using JP-8 (1.31 ppm in July and 2.78 ppm in February) than in engines using JP-4 (0.95 ppm in July and 1.84 ppm in February). The FA concentration increased as both ambient temperature and relative humility decreased in the sampling atmosphere. The FA concentration of JP-8 fuel at an idle power setting (65%) was higher than that at a 71.5% power setting (1.32 ppm and 0.86 ppm, respectively). The FA concentrations in LSCJ79 engine exhaust varies depending on the type of fuel, engine power settings, and ambient air conditions. A high FA concentration at ground level due to a change in the fuel type, low temperature, and humidity, causes frequent severe eye respiratory irritation.

Formaldehyde and TVOC emission behavior of laminate flooring by structure of laminate flooring and heating condition.

PubMed

An, Jae-Yoon; Kim, Sumin; Kim, Hyun-Joong

2011-03-15

Formaldehyde was measured with a desiccator, a 20 L chamber and the FLEC method. The formaldehyde emission rate from laminate was the highest at 32 °C using the desiccator, which then decreased with time. The formaldehyde emission using the 20 L small chamber and FLEC showed a similar tendency. There was a strong correlation between the formaldehyde and total volatile organic compounds (TVOCs) with both types of floorings using the two different methods. The formaldehyde emission rate and TVOC results were higher when tested using the FLEC method than with the 20 L small chamber method. The emission rate was affected by the joint edge length in laminate flooring. Toluene, ethylbenzene and xylene were the main VOCs emitted from laminate flooring, and there were more unidentified VOCs emitted than identified VOCs. The samples heated with a floor heating system emitted more formaldehyde than those heated using an air circulation system due to the temperature difference between the bottom panel and flooring. The TVOC emission level of the samples was higher when an air circulation system was used than when a floor heating system was used due to the high ventilation rate. Copyright © 2010 Elsevier B.V. All rights reserved.

Graphene oxide as efficient high-concentration formaldehyde scavenger and reutilization in supercapacitor.

PubMed

Liang, Hongyu; Bu, Yongfeng; Zhang, Yutian; Zhang, Junyan

2015-04-15

Graphene oxide (GO) was investigated as a low-cost and high-efficient scavenger for high-concentration formaldehyde in alkali media. It showed very high removal capacity, 411 mg of formaldehyde per milligram of GO, and strong resistant to temperature changes. Additionally, the used GO can be easily renewed by a simple electrochemical method. By analyzing the componential and electrochemical characterizations of GO before and after use, the results showed that the degradation mechanism of formaldehyde is a collaborative process of chemical oxidation and physical adsorption, and the former dominates the degradation process. With the aid of oxygen-containing groups in GO, most formaldehyde can be easily oxidized by GO in alkaline media (this is equivalent to GO was reduced by formaldehyde). On the other hand, the used GO (reduced GO, noted as rGO) exhibits more ideal electronic double-layer capacitor (EDLC) feature than GO, along with higher rate capacitance (up to 136 F g(-1) at 50 A g(-1)). In short, GO is not only an efficient formaldehyde scavenger, but the used GO (rGO) can serve as promising electrical energy storage material. This study provides new insights for us to reutilize the discarded adsorbents generated from the environmental protection. Copyright © 2014 Elsevier Inc. All rights reserved.

Nitrogen Doped Graphene Supported Pt Nanoflowers as Electrocatalysts for Oxidation of Formaldehyde.

PubMed

Xie, Aijuan; Zhou, Wenting; Luo, Shiping; Chen, Yu; Zhou, Xiaoqing; Chao, Yao

2017-02-01

A facile Pt nanoflowers/nitrogen-doped graphene (PtNFs/NG) electrocatalyst was prepared via depositing Pt nanoflowers (PtNFs) onto the nitrogen-doped graphene (NG) matrix with urea as the nitrogen source and PtNFs/NG modified glassy carbon electrode (GCE) was prepared by electro-chemical method. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Raman spectroscope, X-ray photoelectron spectroscopy (XPS) and Scanning electron microscope (SEM) were used to characterize the resulting composites. Also oxidation of formaldehyde on the resulting PtNFs/NG modified electrode was investigated. The influence of deposition time, electrodeposition potential and formaldehyde concentration on electrooxidation of formaldehyde was detected, the experimental results indicate the high performance of PtNFs/NG catalyst for formaldehyde oxidation is at electrodeposition time of 300 s with the applied potential of −0.3 V. Electrochemical process, electrocatalytic stability and chronoamperometry were also inspected, it was indicated that formalde-hyde oxidation reaction on the PtNFs/NG electrode is diffusion-controlled and PtNFs/NG exhibits a high catalytic activity, stability as well as excellent poisoning-tolerance towards formaldehyde oxidation, which is attributed to the synergistic effect of PtNFs and NG. It turns out that PtNFs/NG can be used in direct liquid-feed fuel cells as a promising alternative catalyst.

Core pathways operating during methylotrophy of Bacillus methanolicus MGA3 and induction of a bacillithiol-dependent detoxification pathway upon formaldehyde stress.

PubMed

Müller, Jonas E N; Meyer, Fabian; Litsanov, Boris; Kiefer, Patrick; Vorholt, Julia A

2015-12-01

Bacillus methanolicus MGA3 is a model facultative methylotroph of interest for fundamental research and biotechnological applications. Previous research uncovered a number of pathways potentially involved in one-carbon substrate utilization. Here, we applied dynamic (13) C labeling to elucidate which of these pathways operate during growth on methanol and to uncover potentially new ones. B. methanolicus MGA3 uses the assimilatory and dissimilatory ribulose monophosphate (RuMP) cycles for conversion of the central but toxic intermediate formaldehyde. Additionally, the operation of two cofactor-dependent formaldehyde oxidation pathways with distinct roles was revealed. One is dependent on tri- and tetraglutamylated tetrahydrofolate (THF) and is involved in formaldehyde oxidation during growth on methanol. A second pathway was discovered that is dependent on bacillithiol, a thiol cofactor present also in other Bacilli where it is known to function in redox-homeostasis. We show that bacillithiol-dependent formaldehyde oxidation is activated upon an upshift in formaldehyde induced by a substrate switch from mannitol to methanol. The genes and the corresponding enzymes involved in the biosynthesis of bacillithiol were identified by heterologous production of bacillithiol in Escherichia coli. The presented results indicate metabolic plasticity of the methylotroph allowing acclimation to fluctuating intracellular formaldehyde concentrations. © 2015 John Wiley & Sons Ltd.

"You Will": Technology, Magic, and the Cultural Contexts of Technical Communication.

ERIC Educational Resources Information Center

Kitalong, Karla Saari

2000-01-01

Provides some background on the use of magical language in technical contexts, gives examples of magical discourse in technology advertisements and newsmagazine articles, and proposes a technical communication pedagogy of media analysis. Notes that the proposed pedagogy involves students conducting diagnostic critiques of media texts and affords…

Magical Landscapes: Two Love Stories.

ERIC Educational Resources Information Center

Moore, John Noell

2002-01-01

Introduces two books about magic, one a collection of essays "Ex Libris: Confessions of a Common Reader," which describes the author's inherited lifelong passion for books and reading; and the other a novel, "Mangos, Bananas and Coconuts: A Cuban Love Story," which tells a story of love and magic that seems both real and…

Magical Mysteries. Texas Reading Club, 1984. A Librarian's Planning Handbook.

ERIC Educational Resources Information Center

Oliver, Jim

Designed to encourage library use by Texas youth, the Texas Reading Club programs usually include a structured reading program and a variety of entertaining literature-related storyhours, puppet shows, films, and other attractive happenings. This handbook for the 1984 theme--"magical mysteries"--focuses on mysteries, magic, and adventure…

Redefining the magic square on numerical characters

NASA Astrophysics Data System (ADS)

Nasution, M. K. M.; Sawaluddin

2018-02-01

As a number system, the magic square is different from the others. Characteristic depends not only on size but also depends on numerical character in computation. This paper has redefined the term of magic square formally, by exposing the inductive general characteristics of cases to numerical ordering of numbers.

Magic User’s Manual 2006

DTIC Science & Technology

2006-12-01

K (M) M issioin Research MRC/WDC-R-556 MAGIC USER’S MANUAL 2006 Author(s): Larry Ludeking ATK Mission Research Contract No.: F49620-03-C-0030 L¾[iJiD... Magic Tool Suite for Windows. It uses the standard Windows Help so it is pretty self-explanatory. You can use the panel to the left to scan through... MAGIC Go to Part 2. MCL Commands Go to Part 3. Tirnc and Space Go to Part 4. Spatial Extensions Go to Part 5. Properties Go to Part 6. Algorithms Go

A Compact Low-loss Magic-T using Microstrip-Slotline Transitions

NASA Technical Reports Server (NTRS)

U-yen, Kongpop; Wollack, Edward J.; Moseley, Samuel H.; Papapolymerou, John; Laskar, Joy

2007-01-01

The design of a compact low-loss magic-T is proposed. The planar magic-T incorporates the compact microstrip-slotline tee junction and small microstrip-slotline transition area to reduce slotline radiation. The experimental results show that the magic-T produces broadband in-phase and out-of-phase power combiner/divider responses, has an average in-band insertion loss of 0.3 dB and small in-band phase and amplitude imbalance of less than plus or minus 1.6 deg. and plus or minus 0.3 dB, respectively.

Lenz's Law Magic Trick

NASA Astrophysics Data System (ADS)

Ruiz, Michael J.

2006-02-01

The demonstration of Lenz's law by dropping a powerful magnet down a nonmagnetic metal pipe has become a classic lecture-hall demonstration.1,2 An inexpensive version is packaged as a professional magic trick3 called "Newton's Nightmare." Combining sleight-of-hand with a demonstration of Lenz's law is a surefire way to heighten student interest. The subsequent student discussion motivated by a desire to understand the magic trick can lead to a memorable physics lesson. This paper will discuss Lenz's law magic and review literature that reveals the subtlety of the physics.

The use of magical plants by curanderos in the Ecuador highlands

PubMed Central

Cavender, Anthony P; Albán, Manuel

2009-01-01

Although the use of plants for treating supernaturally caused illnesses (e.g., soul loss, evil wind, witchcraft) has been documented in the Ecuador highlands, so-called magical plants have received much less focused attention than plants used for treating naturalistic disorders. Drawing on interviews done in 2002 and 2003 with 116 curanderos residing in the Ecuador highlands, this paper examines the characteristics of plants identified as magical, how they are used, and how the study of magical plants provides insights into the mindscape of residents of the highlands. PMID:19161618

Managing Rock and Paleomagnetic Data Flow with the MagIC Database: from Measurement and Analysis to Comprehensive Archive and Visualization

NASA Astrophysics Data System (ADS)

Koppers, A. A.; Minnett, R. C.; Tauxe, L.; Constable, C.; Donadini, F.

2008-12-01

The Magnetics Information Consortium (MagIC) is commissioned to implement and maintain an online portal to a relational database populated by rock and paleomagnetic data. The goal of MagIC is to archive all measurements and derived properties for studies of paleomagnetic directions (inclination, declination) and intensities, and for rock magnetic experiments (hysteresis, remanence, susceptibility, anisotropy). Organizing data for presentation in peer-reviewed publications or for ingestion into databases is a time-consuming task, and to facilitate these activities, three tightly integrated tools have been developed: MagIC-PY, the MagIC Console Software, and the MagIC Online Database. A suite of Python scripts is available to help users port their data into the MagIC data format. They allow the user to add important metadata, perform basic interpretations, and average results at the specimen, sample and site levels. These scripts have been validated for use as Open Source software under the UNIX, Linux, PC and Macintosh© operating systems. We have also developed the MagIC Console Software program to assist in collating rock and paleomagnetic data for upload to the MagIC database. The program runs in Microsoft Excel© on both Macintosh© computers and PCs. It performs routine consistency checks on data entries, and assists users in preparing data for uploading into the online MagIC database. The MagIC website is hosted under EarthRef.org at http://earthref.org/MAGIC/ and has two search nodes, one for paleomagnetism and one for rock magnetism. Both nodes provide query building based on location, reference, methods applied, material type and geological age, as well as a visual FlashMap interface to browse and select locations. Users can also browse the database by data type (inclination, intensity, VGP, hysteresis, susceptibility) or by data compilation to view all contributions associated with previous databases, such as PINT, GMPDB or TAFI or other user-defined compilations. Query results are displayed in a digestible tabular format allowing the user to descend from locations to sites, samples, specimens and measurements. At each stage, the result set can be saved and, when supported by the data, can be visualized by plotting global location maps, equal area, XY, age, and depth plots, or typical Zijderveld, hysteresis, magnetization and remanence diagrams.

Reductions in commuter exposure to volatile organic compounds in Mexico City due to the environmental program ProAire2002-2010.

PubMed

Shinohara, Naohide; Ángeles, Felipe; Basaldud, Roberto; Cardenas, Beatriz; Wakamatsu, Shinji

2017-05-01

We investigated commuter exposure to volatile organic compounds in the metropolitan area of Mexico City in 2011 in private car, microbus, bus, metro, metrobus, and trolley bus. A similar survey was conducted in 2002 before initiation of the ProAire2002-2010 program aimed at reducing air pollution. Formaldehyde, acetaldehyde, benzene, toluene, ethylbenzene, m/p-xylene, and o-xylene were sampled while traveling during the morning rush hour in May 2011. Compared with the 2002 survey, in-vehicle concentrations were substantially lower in 2011, except for formaldehyde in microbuses (35% higher than in 2002). The reductions were 17-42% (except microbuses), 25-44%, 41-61%, 43-61%, 71-79%, 80-91%, and 79-93% for formaldehyde, acetaldehyde, benzene, toluene, ethylbenzene, m/p-xylene, and o-xylene, respectively. These reductions are considered to be the outcome of some of the actions in the ProAire2002-2010 program. In some microbuses, use of liquid petroleum gas may have increased in-vehicle formaldehyde concentrations. The reduction in predicted excess cancer incidence of commuters because of ProAire2002-2010 was estimated to be 1.4 cases/yr. In addition, if every microbus commuter changed their transport mode to bus, metro, or metrobus in the future, the estimated excess cancer incidence of commuters could be further decreased from 6.4 to 0.88-2.2 cases/year.

The "New Polyethylene Glycol Dilemma": Polyethylene Glycol Impurities and Their Paradox Role in mAb Crystallization.

PubMed

Hildebrandt, Christian; Joos, Lea; Saedler, Rainer; Winter, Gerhard

2015-06-01

Polyethylene glycols (PEG) represent the most successful and frequently applied class of excipients used for protein crystallization. PEG auto-oxidation and formation of impurities such as peroxides and formaldehydes that foster protein drug degradation is known. However, their effect on mAb crystallization has not been studied in detail before. During the present study, a model IgG1 antibody (mAb1) was crystallized in PEG solutions. Aggregate formation was observed during crystallization and storage that was ascribed to PEG degradation products. Reduction of peroxide and formaldehyde levels prior to crystallization by vacuum and freeze-drying was investigated for its effect on protein degradation. Vacuum drying was superior in removal of peroxides but inferior in reducing formaldehyde residues. Consequently, double purification allowed extensive removal of both impurities. Applying of purified PEG led to 50% lower aggregate fractions. Surprisingly, PEG double purification or addition of methionine prior to crystallization prevented crystal formation. With increased PEG concentration or spiking with peroxides and formaldehydes, crystal formation could be recovered again. With these results, we demonstrate that minimum amounts of oxidizing impurities and thus in consequence chemically altered proteins are vital to initiate mAb1 crystallization. The present study calls PEG as good precipitant for therapeutic biopharmaceuticals into question. © 2015 Wiley Periodicals, Inc. and the American Pharmacists Association.

Influence of humidity on the initial emittable concentration of formaldehyde and hexaldehyde in building materials: experimental observation and correlation.

PubMed

Huang, Shaodan; Xiong, Jianyin; Cai, Chaorui; Xu, Wei; Zhang, Yinping

2016-03-30

Humidity is one of the main environmental factors affecting the emission rate and key parameters of formaldehyde and volatile organic compounds (VOCs) from building materials. Meanwhile, the initial emittable concentration (Cm,0) is proved to be the most sensitive key parameter to the emission behaviours. However, there is no report on the relationship between humidity and Cm,0. In this paper, Cm,0 of formaldehyde and hexaldehyde from a type of medium density fiberboard in absolute humidity (AH) range of 4.6-19.6 g/m(3) at 25 °C were tested by virtue of a C-history method. Experimental results indicate that Cm,0 is dramatically dependent on AH, increased by 10 and 2 times for formaldehyde and hexaldehyde when AH rising from 4.6 g/m(3) to 19.6 g/m(3). A linear relationship between the logarithm of Cm,0 and AH is obtained based on the measured results. In addition, a correlation characterizing the association of emission rate and AH is derived. The effectiveness of the correlation is verified with our experimental results as well as data from literature. With the correlations, the Cm,0 or emission rate different from the test AH conditions can be conveniently obtained. This study should be useful for predicting the emission characteristics of humidity changing scenarios and for source control.

Transgenic plants of Petunia hybrida harboring the CYP2E1 gene efficiently remove benzene and toluene pollutants and improve resistance to formaldehyde

PubMed Central

Zhang, Daoxiang; Xiang, Taihe; Li, Peihan; Bao, Lumin

2011-01-01

The CYP2E1 protein belongs to the P450 enzymes family and plays an important role in the metabolism of small molecular and organic pollutants. In this study we generated CYP2E1 transgenic plants of Petunia using Agrobacterium rhizogenes K599. PCR analysis confirmed that the regenerated plants contained the CYP2E1 transgene and the rolB gene of the Ri plasmid. Southern blotting revealed the presence of multiple copies of CYP2E1 in the genome of transgenic plants. Fluorescent quantitative PCR revealed exogenous CYP2E1 gene expression in CYP2E1 transgenic plants at various levels, whereas no like expression was detected in either GUS transgenic plants or wild-types. The absorption of benzene and toluene by transgenic plants was analyzed through quantitative gas chromatography. Transgenic plants with high CYP2E1 expression showed a significant increase in absorption capacity of environmental benzene and toluene, compared to control GUS transgenic and wild type plants. Furthermore, these plants also presented obvious improved resistance to formaldehyde. This study, besides being the first to reveal that the CYP2E1 gene enhances plant resistance to formaldehyde, also furnishes a new method for reducing pollutants, such as benzene, toluene and formaldehyde, by using transgenic flowering horticultural plants. PMID:22215968

The relationships between patients' and caregivers' beliefs about the causes of schizophrenia and clinical outcomes in Latin American countries.

PubMed

Caqueo-Urízar, Alejandra; Boyer, Laurent; Baumstarck, Karine; Gilman, Stephen E

2015-09-30

Beliefs about the causes of schizophrenia are thought to impact treatment outcomes. We investigated 3 theoretically opposing belief systems (biological, psychosocial, magical-religious) in relation to the severity of positive and negative symptoms and to attitudes towards medications. We recruited 253 patients with schizophrenia and their primary caregivers from public mental health clinics in Bolivia, Chile, and Peru. We assessed patients' and caregivers' beliefs about the causes of schizophrenia, which were used as predictors of symptom severity and medication attitudes in linear regression analyses. Patients' scores on biological, psychosocial, and magical-religious beliefs were positively correlated with one another, indicating that these domains were not, as anticipated, "opposing". Patients with higher levels of biological and psychosocial beliefs had significantly lower levels of positive and negative symptoms; in contrast, higher levels of magical-religious beliefs were associated with increased positive symptoms and less favorable attitudes towards medications. Patients' belief systems are significant predictors of symptom severity and medication attitudes. Research is needed on the extent to which psychotherapeutic treatments for schizophrenia should bolster patients' beliefs in the biological and psychosocial domains and weaken beliefs in the magical-religious domain; this research should also attend to the ethical considerations involved in intervening on belief systems cross-culturally. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

Is exposure to formaldehyde in air causally associated with leukemia?—A hypothesis-based weight-of-evidence analysis

PubMed Central

Rhomberg, Lorenz R; Bailey, Lisa A; Goodman, Julie E; Hamade, Ali K; Mayfield, David

2011-01-01

Recent scientific debate has focused on the potential for inhaled formaldehyde to cause lymphohematopoietic cancers, particularly leukemias, in humans. The concern stems from certain epidemiology studies reporting an association, although particulars of endpoints and dosimetry are inconsistent across studies and several other studies show no such effects. Animal studies generally report neither hematotoxicity nor leukemia associated with formaldehyde inhalation, and hematotoxicity studies in humans are inconsistent. Formaldehyde's reactivity has been thought to preclude systemic exposure following inhalation, and its apparent inability to reach and affect the target tissues attacked by known leukemogens has, heretofore, led to skepticism regarding its potential to cause human lymphohematopoietic cancers. Recently, however, potential modes of action for formaldehyde leukemogenesis have been hypothesized, and it has been suggested that formaldehyde be identified as a known human leukemogen. In this article, we apply our hypothesis-based weight-of-evidence (HBWoE) approach to evaluate the large body of evidence regarding formaldehyde and leukemogenesis, attending to how human, animal, and mode-of-action results inform one another. We trace the logic of inference within and across all studies, and articulate how one could account for the suite of available observations under the various proposed hypotheses. Upon comparison of alternative proposals regarding what causal processes may have led to the array of observations as we see them, we conclude that the case fora causal association is weak and strains biological plausibility. Instead, apparent association between formaldehyde inhalation and leukemia in some human studies is better interpreted as due to chance or confounding. PMID:21635189

Future Aspects

NASA Astrophysics Data System (ADS)

Pilato, Louis

There are some disturbing signs that appear on the horizon as phenolic resins enter their second century of existence. The large area of wood adhesives application (~60% of the total volume of phenolic resins in North America) is under intense pressure due to many factors that are contributing to continuing reduction in the sales volume of wood adhesives. These factors include the known slow cure speed of phenolic resins compared to Urea Formaldehyde (UF), Melamine Formaldehyde (MF), or Methylene Diphenyl Isocyanate (MDI); installation of new machinery/ equipment with fast continuous lines; continued decrease in plywood consumption at the expense of Oriented Strand Board (OSB) where phenolic resin is the preferred adhesive for plywood; further reduction in formaldehyde emissions through California Air Resources Board (CARB) Phase I and Phase II; uncertainty of whether formaldehyde will be identified as a human carcinogen pending the anticipated 2009 study; and the environmental movement to reduce or eliminate formaldehyde-containing resins in wood and thermal insulation consumer products (U.S. Green Building Council and other Environmental groups like the Sierra Club). Consumers are being urged by environmental organizations to purchase composite wood products with lower formaldehyde emission levels or none at all. This is illustrated by examining the news media reports after the Hurricane Katrina in 2005. The home trailers provided by the Federal Emergency Management Agency (FEMA) that were used for Louisiana and Mississippi residents after Katrina hurricane as temporary housing further accelerated concerns over formaldehyde emissions since higher than typical indoor exposure levels of formaldehyde in travel trailers and mobile homes were determined for the FEMA trailers.

[Microbial resistance to formaldehyde. I. Comparative quantitative studies in some selected species of vegetative bacteria, bacterial spores, fungi, bacteriophages and viruses].

PubMed

Spicher, G; Peters, J

1976-12-01

The resistence of different microorganisms to formaldehyde was determined. As test objects served gram-negative and gram-positive vegetative germs (Klebsiella pneumoniae, Pseudomonas aeruginosa, Salmonella paratyphi-B, Staphylococcus aureus, Streptococcus faecalis), bacterial spores (Bacillus cereus, Bacillus pumilus, Bacillus stearothermophilus, Bacillus subtilis), fungi (Aspergillus niger, Candida albicans), bacteriophages (Escherichia coli phages, T1, T2, T3), and viruses (adenovirus, poliomyelitis virus, vaccinia virus). For the studies, suspensions of germs were exposed at identical temperature (20 degrees C) and pH (7.0). The microbicidal effect of formaldehyde was measured by the decrease of the proportion of germs capable of multiplication in the suspension (lg (N/N0); where: N0 equals initial number of germs capable of multiplication; N equals number of germs capable of multiplication after exposure to formaldehyde). For all germs the dependence of the microbicidal effect on the concentration of formaldehyde was determined. In all experiments, the duration of exposure was two hours. Pseudomonas aeruginosa, Klebsiella pneumoniae, and Salmonella paratyphi-B were found to be more susceptible than Staphylococcus aureus (vf. Fig. 1 A). The strains of Pseudomonas aeruginosa used were widely varying as to their susceptibility. To obtain equal microbicidal effects, concentrations of formaldehyde almost three times as high had to be used for the most resistant strain than were necessary for the most susceptible strain of Pseudomonas aeruginosa. All strains of Klebsiella pneumoniae examined were found to have an identical resistence to formaldehyde. Streptococcus faecalis was even more resistant to formaldehyde than Staphylococcus aureus. In the case of Streptococcus faecalis, a concentration of formaldehyde about three times as high had to be used to obtain microbicidal effects of identical magnitude. For the killing of Candida albicans cells concentrations of formaldehyde not higher than those needed for the killing of vegetative gram-negative bacteria were necessary. The conidia of Aspergillus niger were found to be more resistant than the cells of Candida albicans but did not require any higher concentrations than for the killing of Staphylococcus aureus (see Fig. 1 B). In the case of bacterial spores, a special phenomenon was observed. If the spores had been exposed to a temperature of 80 and 95 degrees C, respectively (depending on the species involved) for one or two hours following exposure to formaldehyde, a considerably higher number of spores was found to be capable of germination and colony formation than without such treatment (heat activation: cf. Fig. 2A and Fig. 2B). The spores of Bacillus cereus had only a relatively low resistance to formaldehyde. To reduce the proportion of the spores capable of colony formation to 1/10000, a 2.9% formaldehyde concentration was necessary without heat activation and one of 10.8% with heat activation...

Henry’s Law Constant and Overall Mass Transfer Coefficient for Formaldehyde Emission from Small Water Pools under Simulated Indoor Environmental Conditions

EPA Science Inventory

The Henry’s law constant (HLC) and the overall mass transfer coefficient are both important parameters for modeling formaldehyde emissions from aqueous solutions. In this work, the apparent HLCs for aqueous formaldehyde solutions were determined in the concentration range from 0....

40 CFR 63.6620 - What performance tests and other procedures must I use?

Code of Federal Regulations, 2014 CFR

2014-07-01

... Where: Ci = concentration of carbon monoxide (CO), total hydrocarbons (THC), or formaldehyde at the control device inlet, Co = concentration of CO, THC, or formaldehyde at the control device outlet, and R = percent reduction of CO, THC, or formaldehyde emissions. (2) You must normalize the CO, THC, or...

40 CFR 63.6620 - What performance tests and other procedures must I use?

Code of Federal Regulations, 2013 CFR

2013-07-01

... Where: Ci = concentration of carbon monoxide (CO), total hydrocarbons (THC), or formaldehyde at the control device inlet, Co = concentration of CO, THC, or formaldehyde at the control device outlet, and R = percent reduction of CO, THC, or formaldehyde emissions. (2) You must normalize the CO, THC, or...

40 CFR 721.10190 - Formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4-methyl-2...

Code of Federal Regulations, 2011 CFR

2011-07-01

... diamine and phenol, reaction products with 4-methyl-2-pentanone (generic). 721.10190 Section 721.10190... Formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4-methyl-2-pentanone (generic... identified generically as formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4...

40 CFR 721.6181 - Fatty acid, reaction product with substituted oxirane, formaldehyde-phenol polymer glycidyl ether...

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Fatty acid, reaction product with... Specific Chemical Substances § 721.6181 Fatty acid, reaction product with substituted oxirane, formaldehyde... as fatty acid, reaction product with substituted oxirane, formaldehyde-phenol polymer glycidyl ether...

40 CFR 721.10190 - Formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4-methyl-2...

Code of Federal Regulations, 2010 CFR

2010-07-01

... diamine and phenol, reaction products with 4-methyl-2-pentanone (generic). 721.10190 Section 721.10190... Formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4-methyl-2-pentanone (generic... identified generically as formaldehyde, polymer with aliphatic diamine and phenol, reaction products with 4...

40 CFR 721.6181 - Fatty acid, reaction product with substituted oxirane, formaldehyde-phenol polymer glycidyl ether...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Fatty acid, reaction product with... Specific Chemical Substances § 721.6181 Fatty acid, reaction product with substituted oxirane, formaldehyde... as fatty acid, reaction product with substituted oxirane, formaldehyde-phenol polymer glycidyl ether...

Solid phase microextraction method development for measuring Henry's Law constants of formaldehyde in aqueous solutions

EPA Science Inventory

Formaldehyde (HCHO) has been of special concern as an indoor air pollutant because of its existence in a wide range of products and its adverse health effects. The air-water partitioning behavior of volatile organic compounds (VOCs) such as formaldehyde is an important process th...

Effects of Endogenous Formaldehyde in Nasal Tissues on Inhaled Formmaldehyde Dosimetry Predictions in the Rat, Monkey, and Human Nasal Passages

EPA Science Inventory

ABSTRACT Formaldehyde, a nasal carcinogen, is also an endogenous compound that is present in all living cells. Due to its high solubility and reactivity, quantitative risk estimates for inhaled formaldehyde rely on internal dose calculations in the upper respiratory tract which ...

Multicenter Patch Testing With a Resol Resin Based on Phenol and Formaldehyde Within the International Contact Dermatitis Research Group.

PubMed

Isaksson, Marléne; Ale, Iris; Andersen, Klaus; Diepgen, Thomas; Elsner, Peter; Goossens, An; Goh, Chee-Leok; Jerajani, Hemangi; Maibach, Howard; Matsunaga, Kayoko; McFadden, John; Nixon, Rosemary; Sasseville, Denis; Bruze, Magnus

2015-01-01

Contact allergy to phenol-formaldehyde resins (PFRs) based on phenol and formaldehyde is not detected by a p-tertiary-butylphenol-formaldehyde resin included in most baseline patch test series. The aims of this study were to investigate the contact allergy rate to PFR-2 in an international population and to investigate associated simultaneous allergic reactions. Thirteen centers representing the International Contact Dermatitis Research Group included PFR-2 into their patch test baseline series during a period of 6 months in 2012. Of 2259 patients tested, 28 (1.2%) reacted to PFR-2. Of those 28 individuals, one had a positive reaction to formaldehyde and 2 to p-tertiary-butylphenol-formaldehyde resin. Simultaneous allergic reactions were noted to colophonium in 3, to Myroxylon pereirae in 5, and to fragrance mix I in 8. The contact allergy frequency in the tested population (1.2%) merits its inclusion into the international baseline series and possibly also into other baseline series after appropriate investigations. Significantly, overrepresented simultaneous allergic reactions were noted for M. pereirae and fragrance mix I.

Respiratory response to formaldehyde and off-gas of urea formaldehyde foam insulation.

PubMed Central

Day, J H; Lees, R E; Clark, R H; Pattee, P L

1984-01-01

In 18 subjects, 9 of whom had previously complained of various nonrespiratory adverse effects from the urea formaldehyde foam insulation (UFFI) in their homes, pulmonary function was assessed before and after exposure in a laboratory. On separate occasions formaldehyde, 1 part per million (ppm), and UFFI off-gas yielding a formaldehyde concentration of 1.2 ppm, were delivered to each subject in an environmental chamber for 90 minutes and a fume hood for 30 minutes respectively. None of the measures of pulmonary function used (forced vital capacity, forced expiratory volume in 1 second or maximal midexpiratory flow rate) showed any clinically or statistically significant response to the exposure either immediately after or 8 hours after its beginning. There were no statistically significant differences between the responses of the group that had previously complained of adverse effects and of the group that had not. There was no evidence that either formaldehyde or UFFI off-gas operates as a lower airway allergen or important bronchospastic irritant in this heterogeneous population. Images Fig. 1 PMID:6388780

A biodegradable colorimetric film for rapid low-cost field determination of formaldehyde contamination by digital image colorimetry.

PubMed

Wongniramaikul, Worawit; Limsakul, Wadcharawadee; Choodum, Aree

2018-05-30

A biodegradable colorimetric film was fabricated on the lid of portable tube for in-tube formaldehyde detection. Based on the entrapment of colorimetric reagents within a thin film of tapioca starch, the yellow reaction product was observed with formaldehyde. Intensity of the blue channel from the digital image of yellow product showed a linear relationship in the range of 0-25 mg L -1 with low detection limit of 0.7 ± 0.1 mg L -1 . Inter-day precision of 0.61-3.10%RSD were obtained with less than 4.2% relative error from control samples. The developed method was applied for various food samples in Phuket and formaldehyde concentration range was non-detectable to 1.413 mg kg -1 . The quantified concentrations of formaldehyde in fish and squid samples provided relative errors of -7.7% and +10.8% compared to spectrophotometry. This low cost sensor (∼0.04 USD/test) with digital image colorimetry was thus an effective alternative for formaldehyde detection in food sample. Copyright © 2018 Elsevier Ltd. All rights reserved.

Formaldehyde and heavy metal migration from rubber and metallic packaging/utensils in Korea.

PubMed

Kim, Su-Un; Kim, Tae-Rang; Lee, Eun-Soon; Kim, Mi-Sun; Kim, Chang-Kyu; Kim, Li-Ra; Shin, Gi-Young

2015-01-01

The aim of this study was to determine the non-intentionally added substances--formaldehyde and trace metals--at 4% acetic acid conditions in rubber and metallic packaging/utensils. The temperature effect on migration in rubber and metallic packaging/utensils was monitored at 60 °C and 100 °C under acidic (pH < 3) circumstances. The concentrations were: formaldehyde--23.1 μg kg⁻¹, lead--13.41 μg kg⁻¹, cadmium--0.15 μg kg⁻¹, total arsenic--2.02 μg kg⁻¹ and nickel--2.92 μg kg⁻¹ at 60 °C and formaldehyde--148.9 μg kg⁻¹, lead--17.04 μg kg⁻¹, cadmium--0.14 μg kg⁻¹, total arsenic--7.25 μg kg⁻¹ and nickel--8.7 μg kg⁻¹ at 100 °C. A significant difference was noticed in formaldehyde and total arsenic between both temperatures (p < 0.01), which was not present in other trace metals. In conclusion, formaldehyde and total arsenic were more sensitive with cooking temperature than the other metals.

Migration of formaldehyde from melamine-ware: UK 2008 survey results.

PubMed

Potter, E L J; Bradley, E L; Davies, C R; Barnes, K A; Castle, L

2010-06-01

Fifty melamine-ware articles were tested for the migration of formaldehyde - with hexamethylenetetramine (HMTA) expressed as formaldehyde - to see whether the total specific migration limit (SML(T)) was being observed. The SML(T), given in European Commission Directive 2002/72/EC as amended, is 15 mg kg(-1). Fourier transform-infrared (FT-IR) spectroscopy was carried out on the articles to confirm the plastic type. Articles were exposed to the food simulant 3% (w/v) aqueous acetic acid under conditions representing their worst foreseeable use. Formaldehyde and HMTA in food simulants were determined by a spectrophotometric derivatization procedure. Positive samples were confirmed by a second spectrophotometric procedure using an alternative derivatization agent. As all products purchased were intended for repeat use, three sequential exposures to the simulant were carried out. Formaldehyde was detected in the simulant exposed to 43 samples. Most of the levels found were well below the limits set in law such that 84% of the samples tested were compliant. However, eight samples had formaldehyde levels that were clearly above the legal maximum at six to 65 times the SML(T).

Optimization of Formaldehyde Cross-Linking for Protein Interaction Analysis of Non-Tagged Integrin β1

PubMed Central

Klockenbusch, Cordula; Kast, Juergen

2010-01-01

Formaldehyde cross-linking of protein complexes combined with immunoprecipitation and mass spectrometry analysis is a promising technique for analysing protein-protein interactions, including those of transient nature. Here we used integrin β1 as a model to describe the application of formaldehyde cross-linking in detail, particularly focusing on the optimal parameters for cross-linking, the detection of formaldehyde cross-linked complexes, the utility of antibodies, and the identification of binding partners. Integrin β1 was found in a high molecular weight complex after formaldehyde cross-linking. Eight different anti-integrin β1 antibodies were used for pull-down experiments and no loss in precipitation efficiency after cross-linking was observed. However, two of the antibodies could not precipitate the complex, probably due to hidden epitopes. Formaldehyde cross-linked complexes, precipitated from Jurkat cells or human platelets and analyzed by mass spectrometry, were found to be composed of integrin β1, α4 and α6 or β1, α6, α2, and α5, respectively. PMID:20634879

Multicentre patch testing with a resol resin based on phenol and formaldehyde.

PubMed

Isaksson, Marléne; Inerot, Annica; Lidén, Carola; Matura, Mihaly; Stenberg, Berndt; Möller, Halvor; Bruze, Magnus

2011-07-01

Contact allergy to phenol-formaldehyde resins (PFRs) based on phenol and formaldehyde is not detected by a p-tertiary-butylphenol-formaldehyde resin (PTBP-FR) included in most baseline patch test series. To investigate the rate of contact allergy to PFR-2 (a mixture of monomers and dimers from a resol resin based on phenol and formaldehyde) in a Swedish population, and to investigate associated simultaneous allergic reactions. Five centres representing the Swedish Contact Dermatitis Research Group included PFR-2 in their patch test baseline series for a period of 1.5 years. Of 2504 patients tested, 27 (1.1%) reacted to PFR-2. Of those 27 individuals, 2 had a positive reaction to formaldehyde and 2 to PTBP-FR. Simultaneous allergic reactions were noted to colophonium in 6, to Myroxylon pereirae in 14, and to fragrance mix I in 15. The contact allergy frequency in the tested population (1.1%) merits its inclusion in the Swedish baseline series and possibly also in other baseline series. Simultaneous allergic reactions were noted to colophonium, M. pereirae, and fragrance mix I. © 2011 John Wiley & Sons A/S.

Algebra Magic Tricks: Algecadabra! Volume 1.

ERIC Educational Resources Information Center

Edwards, Ronald

This resource book contains 20 magic tricks based on the properties of whole numbers that are intended to spark the interest and imagination of students. Following each activity, students are asked to write about their discoveries and to create their own magic tricks. A matrix of skills for all the activities and lists of the materials required…

Algebra Magic Tricks: Algecadabra! Volume 2.

ERIC Educational Resources Information Center

Edwards, Ronald

This resource book contains 15 magic tricks based on the properties of whole numbers that are intended to spark the interest and imagination of students. Following each activity, students are asked to write about their discoveries and to create their own magic tricks. A matrix of skills for all the activities and lists of the materials required…

A COAXIAL MAGIC-T

DTIC Science & Technology

Three different designs of coaxial hybrid junctions having perf ormance analogous to a wave-guide magic -T are discussed. The experimental results...loads, decoupling greater than 70 db can be obtained. An application of the magic -T in phase measurement is described which is independent of the signal amplitude and is similar to the homodyne system of phase measurement.

A CMOS VLSI IC for Real-Time Opto-Electronic Two-Dimensional Histogram Generation

DTIC Science & Technology

1993-12-01

large scale integration) design; MAGIC ; CMOS; optics; image processing; 93 16. PRICE CODE 17. SECURITY CLASSIFICATION 18. SECURITY CLASSIFICATiON 19...1. Sun SPARCstation ............. .............. 6 2. Magic .................. ................... 6 a. Peg ................. .................. 7 b...38 v APPENDIX B. MAGIC CELL LAYOUTS .... ............ .. 39 APPENDIX C: SIMULATION DATA ....... ............. .. 56 A. FINITE STATE MACHINE

Magical Realist Pathways into and under the Psychotherapeutic Imaginary

ERIC Educational Resources Information Center

Speedy, Jane

2011-01-01

My experience of people's life stories from my work as a narrative therapist consistently destabilised distinctions between imagined/magical and real experiences. I came to realise that the day-to-day magical realist juxtapositions I came upon were encounters with people's daily lives, as lived, that have remained unacknowledged within the…

Glamour and Spelling: Reclaiming Magical Thinking in the Composition Classroom.

ERIC Educational Resources Information Center

Wagner, Julia

It is a good thing to demolish "magical thinking" if it refers to the view of language for which words have fixed, inevitable meanings. Words are often deprived of their meanings and reduced to verbal noises, producing involuntary responses like knee-reflexes. Various critics have discussed and written about the magical aspects of…

Garden Gnomes: Magical or Tacky?

ERIC Educational Resources Information Center

Flynt, Deborah

2012-01-01

Garden gnomes: magical or tacky? Well, art is in the eye of the beholder, and for the author's advanced seventh-grade art class, garden gnomes are magical. Gnomes have a very long history, dating back to medieval times. A fairytale describes them as brownie-like creatures that are nocturnal helpers. In this article, the author describes how her…

A framework for using magic to study the mind.

PubMed

Rensink, Ronald A; Kuhn, Gustav

2014-01-01

Over the centuries, magicians have developed extensive knowledge about the manipulation of the human mind-knowledge that has been largely ignored by psychology. It has recently been argued that this knowledge could help improve our understanding of human cognition and consciousness. But how might this be done? And how much could it ultimately contribute to the exploration of the human mind? We propose here a framework outlining how knowledge about magic can be used to help us understand the human mind. Various approaches-both old and new-are surveyed, in terms of four different levels. The first focuses on the methods in magic, using these to suggest new approaches to existing issues in psychology. The second focuses on the effects that magic can produce, such as the sense of wonder induced by seeing an apparently impossible event. Third is the consideration of magic tricks-methods and effects together-as phenomena of scientific interest in their own right. Finally, there is the organization of knowledge about magic into an informative whole, including the possibility of a science centered around the experience of wonder.

A framework for using magic to study the mind

PubMed Central

Rensink, Ronald A.; Kuhn, Gustav

2015-01-01

Over the centuries, magicians have developed extensive knowledge about the manipulation of the human mind—knowledge that has been largely ignored by psychology. It has recently been argued that this knowledge could help improve our understanding of human cognition and consciousness. But how might this be done? And how much could it ultimately contribute to the exploration of the human mind? We propose here a framework outlining how knowledge about magic can be used to help us understand the human mind. Various approaches—both old and new—are surveyed, in terms of four different levels. The first focuses on the methods in magic, using these to suggest new approaches to existing issues in psychology. The second focuses on the effects that magic can produce, such as the sense of wonder induced by seeing an apparently impossible event. Third is the consideration of magic tricks—methods and effects together—as phenomena of scientific interest in their own right. Finally, there is the organization of knowledge about magic into an informative whole, including the possibility of a science centered around the experience of wonder. PMID:25698983

Tunable magic wavelengths for trapping with focused Laguerre-Gaussian beams

NASA Astrophysics Data System (ADS)

Bhowmik, Anal; Dutta, Narendra Nath; Majumder, Sonjoy

2018-02-01

We present in this paper a theory of dynamic polarizability for an atomic state due to an external field of nonparaxial Laguerre-Gaussian (LG) beam using the sum-over-states technique. A highly correlated relativistic coupled-cluster theory is used to evaluate the most important and correlation-sensitive parts of the sum. The theory is applied on Sr+ to determine the magic wavelengths for 5 s1 /2→4 d3 /2,4 d5 /2 transitions. Results show the variation of magic wavelengths with the choice of orbital and spin angular momenta of the incident LG beam. Also, the tunability of the magic wavelengths is studied by using the focusing angle of the LG beam and its efficiency in the near-infrared region is observed. Evaluations of the wide spectrum of magic wavelengths from infrared to ultraviolet have substantial importance to experimentalists for carrying out high-precision measurements in fundamental physics. These magic wavelengths can be used to confine the atom or ion at the dark central node or at the high-intensity ring of the LG beam.

Determination of formaldehyde in Romanian cosmetic products using coupled GC/MS system after SPME extraction

NASA Astrophysics Data System (ADS)

Feher, I.; Schmutzer, G.; Voica, C.; Moldovan, Z.

2013-11-01

In this study we have made a quick review of some Romanian cosmetic products (shampoo, conditioner, face wash) in order to determine the formaldehyde content as well as other substances called "formaldehyde releasers". The process was performed based on solid-phase microextraction (SPME) followed by gas chromatography/mass spectrometry technique. Prior to SPME extraction we used a derivation step of formaldehyde using pentafluorophenyl hydrazine. The obtained product was adsorbed on SPME devices, then injected and desorbed into the GC/MS injection port. The concentration of formaldehyde (as derived compound) was calculated using calibration curve, having a regression coefficient of 0.9938. The performance parameters of the method were calculated using samples of standard concentration. The method proved to be sensitive, having a quantification limit (LOQ) of 0.15 μg/g.

Radical-induced chemistry from VUV photolysis of interstellar ice analogues containing formaldehyde

NASA Astrophysics Data System (ADS)

Butscher, Teddy; Duvernay, Fabrice; Danger, Grégoire; Chiavassa, Thierry

2016-09-01

Surface processes and radical chemistry within interstellar ices are increasingly suspected to play an important role in the formation of complex organic molecules (COMs) observed in several astrophysical regions and cometary environments. We present new laboratory experiments on the low-temperature solid state formation of complex organic molecules - glycolaldehyde, ethylene glycol, and polyoxymethylene - through radical-induced reactivity from VUV photolysis of formaldehyde in water-free and water-dominated ices. Radical reactivity and endogenous formation of COMs were monitored in situ via infrared spectroscopy in the solid state and post photolysis with temperature programmed desorption (TPD) using a quadripole mass spectrometer. We show the ability of free radicals to be stored when formed at low temperature in water-dominated ices, and to react with other radicals or on double bonds of unsaturated molecules when the temperature increases. It experimentally confirms the role of thermal diffusion in radical reactivity. We propose a new pathway for formaldehyde polymerisation induced by HCO radicals that might explain some observations made by the Ptolemy instrument on board the Rosetta lander Philae. In addition, our results seem to indicate that H-atom additions on H2CO proceed preferentially through CH2OH intermediate radicals rather than the CH3O radical.

Effect of selected organic and inorganic snow and cloud components on the photochemical generation of nitrite by nitrate irradiation.

PubMed

Minero, Claudio; Maurino, Valter; Bono, Francesca; Pelizzetti, Ezio; Marinoni, Angela; Mailhot, Gilles; Carlotti, Maria Eugenia; Vione, Davide

2007-08-01

The effect of selected organic and inorganic compounds, present in snow and cloudwater was studied. Photolysis of solutions of nitrate to nitrite was carried out in the laboratory using a UVB light source. The photolysis and other reactions were then modelled. It is shown that formate, formaldehyde, methanesulphonate, and chloride to a lesser extent, can increase the initial formation rate of nitrite. The effect, particularly significant for formate and formaldehyde, is unlikely to be caused by scavenging of hydroxyl radicals. The experimental data obtained in this work suggest that possible causes are the reduction of nitrogen dioxide and nitrate by radical species formed on photooxidation of the organic compounds. Hydroxyl scavenging by organic and inorganic compounds would not affect the initial formation rate of nitrite, but would protect it from oxidation, therefore, increasing the concentration values reached at long irradiation times. The described processes can be relevant to cloudwater and the quasi-liquid layer on the surface of ice and snow, considering that in the polar regions irradiated snow layers are important sources of nitrous acid to the atmosphere. Formate and (at a lesser extent) formaldehyde are the compounds that play the major role in the described processes of nitrite/nitrous acid photoformation by initial rate enhancement and hydroxyl scavenging.

Observations of VHE γ-Ray Sources with the MAGIC Telescope

NASA Astrophysics Data System (ADS)

Bartko, H.

2008-10-01

The MAGIC telescope with its 17m diameter mirror is today the largest operating single-dish Imaging Air Cherenkov Telescope (IACT). It is located on the Canary Island La Palma, at an altitude of 2200m above sea level, as part of the Roque de los Muchachos European Northern Observatory. The MAGIC telescope detects celestial very high energy γ-radiation in the energy band between about 50 GeV and 10 TeV. Since Autumn of 2004 MAGIC has been taking data routinely, observing various objects like supernova remnants (SNRs), γ-ray binaries, Pulsars, Active Galactic Nuclei (AGN) and Gamma-ray Bursts (GRB). We briefly describe the observational strategy, the procedure implemented for the data analysis, and discuss the results for individual sources. An outlook to the construction of the second MAGIC telescope is given.

[Magical and religious healing in Byzantium].

PubMed

Józsa, László

2010-01-01

Religious and magical ways of healing have been known and practiced since the very beginning of human history. In the present article, the Byzantine philosophical, cultural, historical and "methodological" aspects of this way of healing are discussed. The article outlines the development of magic healing in Byzantium from the 4th to the 15th century. During this period magical therapy included the cult of patron saints--listed by the author--and pleading for divine intervention as well. The activity of "anargyroi" and the use of magical objects and amulets is also discussed in detail. Exorcism was also a part of religious therapy both against psychical and somatical diseases. In early Christianity, and especially in Byzantium the devil or other demons were also supposed to cause various somatical or psychical illnesses by "intrusion" or "internalisation," i.e. by possession or obsession of their victims.

Maximum nonlocality and minimum uncertainty using magic states

NASA Astrophysics Data System (ADS)

Howard, Mark

2015-04-01

We prove that magic states from the Clifford hierarchy give optimal solutions for tasks involving nonlocality and entropic uncertainty with respect to Pauli measurements. For both the nonlocality and uncertainty tasks, stabilizer states are the worst possible pure states, so our solutions have an operational interpretation as being highly nonstabilizer. The optimal strategy for a qudit version of the Clauser-Horne-Shimony-Holt game in prime dimensions is achieved by measuring maximally entangled states that are isomorphic to single-qudit magic states. These magic states have an appealingly simple form, and our proof shows that they are "balanced" with respect to all but one of the mutually unbiased stabilizer bases. Of all equatorial qudit states, magic states minimize the average entropic uncertainties for collision entropy and also, for small prime dimensions, min-entropy, a fact that may have implications for cryptography.

On an algebraic structure of dimensionally reduced magical supergravity theories

NASA Astrophysics Data System (ADS)

Fukuchi, Shin; Mizoguchi, Shun'ya

2018-06-01

We study an algebraic structure of magical supergravities in three dimensions. We show that if the commutation relations among the generators of the quasi-conformal group in the super-Ehlers decomposition are in a particular form, then one can always find a parameterization of the group element in terms of various 3d bosonic fields that reproduces the 3d reduced Lagrangian of the corresponding magical supergravity. This provides a unified treatment of all the magical supergravity theories in finding explicit relations between the 3d dimensionally reduced Lagrangians and particular coset nonlinear sigma models. We also verify that the commutation relations of E 6 (+ 2), the quasi-conformal group for A = C, indeed satisfy this property, allowing the algebraic interpretation of the structure constants and scalar field functions as was done in the F 4 (+ 4) magical supergravity.

Logistical Support of AirLand Operations: Myth or Magic?

DTIC Science & Technology

1992-05-04

I4 May 1992 Master’s Thesis, 4 Aug 91-5 Jun 92 4. TITLE AND SUBTITLE 5. FUNDING NUMBERS .Support of AirLand Operations: Myth or Magic 6. AUTHOR(S) HA•J...SUPPORT OF AIRLAND OPERATIONS: MYTH OR MAGIC A thesis nresented to the Faculty of the U.S. Army Command and General Staff College in oartial fulfillment of...inerati,,,: Myth or Magic . Aprroved by: .Theq is Comni tt-t- fTh~airrnan; J ),I i .5 .a rria A.n . T.T! 3:•, J!. Pnwe r. M’. P. A . " ,ý) VoD" Member

Comparison of HELIX TWT Simulation Using 2-D PIC (Magic), 2-D Modal (Gator), and 1-D Modal (Christine) Methods

DTIC Science & Technology

1998-05-01

Mission Research Corporation MRC/WDC-R-424 COMPARISON OF HELIX TWT SIMULATION USING 2-D PIC ( MAGIC ), 2-D MODAL (GATOR), AND 1-D MODAL (CHRISTINE...BRILLOUIN RUN 9 3.4 OUTLIER ELECTRON EFFECT IN GATOR 12 3.5 EMISSION CONDITION AND NONLAMINAR FLOW IN MAGIC 12 3.6 RADIAL SHEAR 13 SECTION 4. PPM B...Simulation using 2-D PIC ( MAGIC ), 2-D Modal (GATOR) and 1-D Modal (CHRISTINE) methods * D.N. Smithe(a), H. Freund(b), T. M. Antonsen Jr.,(b)’(c), E

Optically guided atom interferometer tuned to magic wavelength

NASA Astrophysics Data System (ADS)

Akatsuka, Tomoya; Takahashi, Tadahiro; Katori, Hidetoshi

2017-11-01

We demonstrate an atom interferometer operating on the 1S0-3P0 clock transition of 87Sr atoms in a “magic” optical guide, where the light shift perturbations of the guiding potential are canceled. As a proof-of-principle demonstration, a Mach-Zehnder interferometer is set horizontally to map the acceleration introduced by the focused optical guide. This magic guide interferometer on the clock transition is applicable to atomic elements where magic wavelengths can be found. Possible applications of the magic guide interferometer, including a hollow-core fiber interferometer and gradiometer, are discussed.

A role for glutathione, independent of oxidative stress, in the developmental toxicity of methanol

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siu, Michelle T.; Shapiro, Aaron M.; Wiley, Michael J.

2013-12-15

Oxidative stress and reactive oxygen species (ROS) have been implicated in the teratogenicity of methanol (MeOH) in rodents, both in vivo and in embryo culture. We explored the ROS hypothesis further in vivo in pregnant C57BL/6J mice. Following maternal treatment with a teratogenic dose of MeOH, 4 g/kg via intraperitoneal (ip) injection on gestational day (GD) 12, there was no increase 6 h later in embryonic ROS formation, measured by 2′,7′-dichlorodihydrofluorescin diacetate (DCFH-DA) fluorescence, despite an increase observed with the positive control ethanol (EtOH), nor was there an increase in embryonic oxidatively damaged DNA, quantified as 8-oxo-2′-deoxyguanosine (8-oxodG) formation. MeOHmore » teratogenicity (primarily ophthalmic anomalies, cleft palate) also was not altered by pre- and post-treatment with varying doses of the free radical spin trapping agent alpha-phenyl-N-tert-butylnitrone (PBN). In contrast, pretreatment with L-buthionine-(S,R)-sulfoximine (BSO), an inhibitor of glutathione (GSH) synthesis, depleted maternal hepatic and embryonic GSH, and enhanced some new anomalies (micrognathia, agnathia, short snout, fused digits, cleft lip, low set ears), but not the most common teratogenic effects of MeOH (ophthalmic anomalies, cleft palate) in this strain. These results suggest that ROS did not contribute to the teratogenic effects of MeOH in this in vivo mouse model, in contrast to results in embryo culture from our laboratory, and that the protective effect of GSH in this model may arise from its role as a cofactor for formaldehyde dehydrogenase in the detoxification of formaldehyde. - Highlights: • In vivo, a free radical scavenger did not block methanol (MeOH) teratogenesis. • MeOH did not increase embryonic reactive oxygen species formation or DNA oxidation. • MeOH teratogenesis was enhanced by glutathione (GSH) depletion. • GSH may protect as the cofactor for formaldehyde dehydrogenase (ADH3). • Formaldehyde may be a ROS-independent proximate teratogenic species in vivo.« less

Chemical allergens stimulate human epidermal keratinocytes to produce lymphangiogenic vascular endothelial growth factor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bae, Ok-Nam; Ahn, Seyeon; Jin, Sun Hee

2015-03-01

Allergic contact dermatitis (ACD) is a cell-mediated immune response that involves skin sensitization in response to contact with various allergens. Angiogenesis and lymphangiogenesis both play roles in the allergic sensitization process. Epidermal keratinocytes can produce vascular endothelial growth factor (VEGF) in response to UV irradiation and during wound healing. However, the effect of haptenic chemical allergens on the VEGF production of human keratinocytes, which is the primary contact site of toxic allergens, has not been thoroughly researched. We systematically investigated whether immune-regulatory cytokines and chemical allergens would lead to the production of VEGF in normal human keratinocytes (NHKs) in culture.more » VEGF production significantly increased when NHKs were treated with IFNγ, IL-1α, IL-4, IL-6, IL-17A, IL-22 or TNFα. Among the human sensitizers listed in the OECD Test Guideline (TG) 429, we found that CMI/MI, DNCB, 4-phenylenediamine, cobalt chloride, 2-mercaptobenzothiazole, citral, HCA, cinnamic alcohol, imidazolidinyl urea and nickel chloride all significantly upregulated VEGF production in NHKs. In addition, common human haptenic allergens such as avobenzone, formaldehyde and urushiol, also induced the keratinocyte-derived VEGF production. VEGF upregulation by pro-inflammatory stimuli, IFNγ, DNCB or formaldehyde is preceded by the production of IL-8, an acute inflammatory phase cytokine. Lymphangiogenic VEGF-C gene transcription was significantly increased when NHKs were treated with formaldehyde, DNCB or urushiol, while transcription of VEGF-A and VEGF-B did not change. Therefore, the chemical allergen-induced VEGF upregulation is mainly due to the increase in lymphangiogenic VEGF-C transcription in NHKs. These results suggest that keratinocyte-derived VEGF may regulate the lymphangiogenic process during the skin sensitization process of ACD. - Highlights: • Pro-inflammatory cytokines induced VEGF production in normal human keratinocytes (NHKs). • Chemical allergens stimulate NHKs to produce VEGF. • VEGF production is preceded by IL-8 production in NHKs. • IFNγ, DNCB and formaldehyde increase lymphangiogenic VEGF-C gene transcription. • VEGF production in NHKs may be a biomarker for the prediction of potential contact allergens.« less

Report on the Consensus Workshop on Formaldehyde.

PubMed Central

1984-01-01

The Consensus Workshop on Formaldehyde consisted of bringing together scientists from academia, government, industry and public interest groups to address some important toxicological questions concerning the health effects of formaldehyde. The participants in the workshop, the Executive Panel which coordinated the meeting, and the questions posed, all were chosen through a broadly based nomination process in order to achieve as comprehensive a consensus as possible. The subcommittees considered the toxicological problems associated with formaldehyde in the areas of exposure, epidemiology, carcinogenicity/histology/genotoxicity, immunology/sensitization/irritation, structure activity/biochemistry/metabolism, reproduction/teratology, behavior/neurotoxicity/psychology and risk estimation. Some questions considered included the possible human carcinogenicity of formaldehyde, as well as other human health effects, and the interpretation of pathology induced by formaldehyde. These reports, plus introductory material on the procedures used in setting up the Consensus Workshop are presented here. Additionally, there is included a listing of the data base that was made available to the panel chairmen prior to the meeting and was readily accessible to the participants during their deliberations in the meeting. This data base, since it was computerized, was also capable of being searched for important terms. These materials were supplemented by information brought by the panelists. The workshop has defined the consensus concerning a number of major points in formaldehyde toxicology and has identified a number of major deficits in understanding which are important guides to future research. PMID:6525992

Biochemical gas sensor (bio-sniffer) for ultrahigh-sensitive gaseous formaldehyde monitoring.

PubMed

Kudo, Hiroyuki; Suzuki, Yuki; Gessei, Tomoko; Takahashi, Daishi; Arakawa, Takahiro; Mitsubayashi, Kohji

2010-10-15

An ultrahigh-sensitive fiber-optic biochemical gas sensor (bio-sniffer) for continuous monitoring of indoor formaldehyde was constructed and tested. The bio-sniffer measures gaseous formaldehyde as fluorescence of nicotinamide adenine dinucleotide (NADH), which is the product of formaldehyde dehydrogenase (FALDH) reaction. The bio-sniffer device was constructed by attaching a flow cell with a FALDH immobilized membrane onto a fiber-optic NADH measurement system. The NADH measurement system utilizes an ultraviolet-light emitting diode (UV-LED) with peak emission of 335 nm as an excitation light source. The excitation light was introduced to an optical fiber probe, and fluorescence emission of neighboring NADH, which was produced by applying formaldehyde vapor to the FALDH membrane, was concentrically measured with a photomultiplier tube. Assessment of the bio-sniffer was carried out using a standard gas generator. Response, calibration range and selectivity to other chemical substances were investigated. Circulating phosphate buffer, which contained NAD+, available for continuous monitoring of formaldehyde vapor. The calibration range of the bio-sniffer was 2.5 ppb to 10 ppm, which covers the guideline value of the World Health Organization (80 ppb). High selectivity to other gaseous substances due to specific activity of FALDH was also confirmed. Considering its high sensitivity, a possible application of the bio-sniffer is continuous indoor formaldehyde monitoring to provide healthy residential atmosphere. Copyright © 2010 Elsevier B.V. All rights reserved.

Review of fundamental physics results with the MAGIC telescopes

NASA Astrophysics Data System (ADS)

Rico, Javier

2017-01-01

The MAGIC Cherenkov telescopes are powerful tools for the exploration of the Physics frontiers, addressing topics such as the nature of dark matter and its distribution in the Universe, or the search for quantum gravitational effects in photon propagation. Since the beginning of operations in 2004, MAGIC has studied these questions thanks to hundreds of hours of observations of different targets, and has produced several high-impact results. Those include, significantly, the most constraining limits to the WIMP annihilation cross-section for particle masses above few hundred GeV, from observations of dwarf spheroidal (dSph) satellite galaxies. More recently, we have completed a combined analysis of MAGIC and Fermi-LAT observations of dSphs, obtaining limits for dark matter particle masses between 10 GeV and 100 TeV - the widest mass range ever explored by a single gamma-ray analysis - and improving the previously published Fermi-LAT and MAGIC results by up to a factor of two at certain masses. In this talk, I present an overview of the status and results of MAGIC Fundamental Physics projects, including our latest results concerning searches for Lorentz Invariance violation (LIV), and dark matter searches. I will propose the use of the framework developed for the MAGIC/Fermi-LAT joint analysis for the combination of results from the current generation of gamma-ray and neutrino detectors.

40 CFR 721.10205 - Formaldehyde, polymer with 1,3-benzenediol and 1,1′-methylenebis[isocyanatobenzene].

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Formaldehyde, polymer with 1,3-benzenediol and 1,1â²-methylenebis[isocyanatobenzene]. 721.10205 Section 721.10205 Protection of Environment... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10205 Formaldehyde, polymer with 1,3...

Military Handbook: General Guidelines for Electronic Equipment

DTIC Science & Technology

1995-04-28

Epoxy- resin PoLyricinoteates Lubricants Polyvinyl chloride Metamine- formaldehyde Polyvinyl chloride-acetate Organic potysuLphides Potyvinyt fluoride...Phenol- formaldehyde Rubbers, natural and synthetic Polydichlorostyrene Urea - formaldehyde 1/Literature shows that under certain conditions polyamides may...Electrical, Synthetic- Resin Composition, Non-Rigid MIL-T-713 Twine, Fibrous: Impregnated , Lacing and Tying MIL-I-3158 Insulation Tape, Electrical Glass

Formaldehyde in Our Environment.

ERIC Educational Resources Information Center

Ojanlatva, Ansa; Weeks, Charlie A.

During the energy crisis of the early 1970s, there was a drive to conserve energy in every segment of society. Citizens were encouraged to insulate their homes and tighten them up to avoid loss of energy. One of the products to emerge from this crisis was urea formaldehyde foam insulation. (Urea formaldehyde is a well-known agent for preserving…

"Greener" hybrid adhesives composed of urea formaldehyde resin and cottonseed meal for wood based composites

USDA-ARS?s Scientific Manuscript database

Urea formaldehyde (UF) resins are one of the most widely used adhesives in wood based composites. The major concerns of the resin utilization are free formaldehyde release and poor water resistance. As a renewable raw materials, water washed conttonseed meal can be used in wood bonding. To produce “...

40 CFR 721.10285 - Formaldehyde, polymer with 4-(1,1-dimethylethyl)phenol, reaction products with 1...

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Formaldehyde, polymer with 4-(1,1... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10285 Formaldehyde, polymer..., polymer with 4-(1,1-dimethylethyl)phenol, reaction products with 1-piperazineethanamine (PMN P-11-33; CAS...

40 CFR 721.3830 - Formaldehyde, reaction products with an alkylated phenol and an aliphatic amine (generic).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Formaldehyde, reaction products with... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.3830 Formaldehyde, reaction..., reaction products with an alkylated phenol and an aliphatic amine (PMN P-99-0531) is subject to reporting...

Effect of synthesis variables on tack in urea-formaldehyde resin

Treesearch

R.J. Leicht; C.Y. Hse; R.C. Tang

1988-01-01

The degree of tack-the ability of resin to adhere to another surface under light pressure and over short time- in urea-formaldehyde resin varies throughout the particle board manufacturing process and affects mill maintenance and board quality. A three-part study was conducted to evaluate the effects of certain synthesis variables- molar formaldehyde:urea ratio,...

40 CFR 721.3830 - Formaldehyde, reaction products with an alkylated phenol and an aliphatic amine (generic).

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Formaldehyde, reaction products with... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.3830 Formaldehyde, reaction..., reaction products with an alkylated phenol and an aliphatic amine (PMN P-99-0531) is subject to reporting...

Formaldehyde emission from particleboard and plywood paneling : measurement, mechanism, and product standards

Treesearch

George E. Myers

1983-01-01

A number of commercial panel products, primarily particleboard and hardwood plywood, were tested for their formaldehyde emission behavior using desiccator, perforator, and dynamic chamber methods. The results were analyzed in terms of the source of formaldehyde observed in the tests (free vs. hydrolytically produced) and the potential utility of the testa as product...

The "Magic" String

ERIC Educational Resources Information Center

Hoover, Todd F.

2010-01-01

The "Magic" String is a discrepant event that includes a canister with what appears to be the end of two strings protruding from opposite sides of it. Due to the way the strings are attached inside the canister, it appears as if the strings can magically switch the way they are connected. When one string end is pulled, the observer's expectation…

Pulling Words Out of a Hat: Magic in ESL Lessons.

ERIC Educational Resources Information Center

Friedenberg, Randi D.

Magic motivates students to talk, and stimulates the affective domain. While watching magic, many people imagine how the effect is accomplished or how they might perform the trick if they were performing. This can be extended into an English lesson by using phrases such as, "If I were a magician, I could..." Total physical response…

The Cultural Work of Magical Realism in Three Young Adult Novels

ERIC Educational Resources Information Center

Latham, Don

2007-01-01

Magical realism as a literary mode is often subversive and transgressive, questioning the values and assumptions of the dominant society that it depicts. Young adult literature, by contrast, is typically thought to serve a socializing function, helping to integrate young readers into adult society. What then is the cultural work of magical realism…

Molecules, magic and forgetful fruit flies: the supernatural science of medical gas research.

PubMed

Mychaskiw, George

2011-09-06

Medical gas research often involves the study of molecules under extraphysiologic conditions, that is, conditions that do not exist in nature. This "supernatural" nature of medical gas research sometimes produces results that appear to be almost "magic" to those schooled in traditional physiology"Any sufficiently advanced technology is indistinguishable from magic".-Arthur C. Clarke.

Development of next-generation mapping populations: Multi-parent Advanced Generation Inter-Cross (MAGIC) and Marker-Assisted Recurrent Selection (MARS) populations in peanut

USDA-ARS?s Scientific Manuscript database

Generation Inter-Cross (MAGIC) and Marker-Assisted Recurrent Selection (MARS) have been proposed and used in many crops to dissect complex traits or QTL. MAGIC allows for dissecting genomic structure, and for improving breeding populations by integrating multiple alleles from different parents. MAR...

Elementary School Teachers' Perceptions toward ICT: The Case of Using Magic Board for Teaching Mathematics

ERIC Educational Resources Information Center

Yuan, Yuan; Lee, Chun-Yi

2012-01-01

This study aims at investigating elementary school teachers' perceptions toward to the use of ICT. Magic Board, an interactive web-based environment which provides a set of virtual manipulatives for elementary mathematics, is used as the case of ICT. After participating in Magic Board workshops, 250 elementary school teachers in Taiwan responded…

77 FR 70432 - Magic Valley Pipeline, L.P.; Notice of Filing

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-26

... Pipeline, L.P.; Notice of Filing Take notice that on November 15, 2012, Magic Valley Pipeline, L.P. (Magic...: 5:00 p.m. Eastern Time on Tuesday, November 27, 2012. Dated: November 19, 2012. Kimberly D. Bose, Secretary. [FR Doc. 2012-28544 Filed 11-23-12; 8:45 am] BILLING CODE 6717-01-P ...

Effect of endophytic Bacillus cereus ERBP inoculation into non-native host: Potentials and challenges for airborne formaldehyde removal.

PubMed

Khaksar, Gholamreza; Treesubsuntorn, Chairat; Thiravetyan, Paitip

2016-10-01

Phytoremediation could be a cost-effective, environmentally friendly approach for the treatment of indoor air. However, some drawbacks still dispute the expediency of phytotechnology. Our objectives were to investigate the competency of plant growth-promoting (PGP) endophytic Bacillus cereus ERBP (endophyte root blue pea), isolated from the root of Clitoria ternatea, to colonize and stabilize within Zamioculcas zamiifolia and Euphorbia milii as non-native hosts without causing any disease or stress symptoms. Moreover, the impact of B. cereus ERBP on the natural shoot endophytic community and for the airborne formaldehyde removal capability of non-native hosts was assessed. Non-native Z. zamiifolia was effectively inoculated with B. cereus ERBP through soil as the most efficient method of endophyte inoculation. Denaturing gradient gel electrophoresis profiling of the shoot endophytic community verified the colonization and stability of B. cereus ERBP within its non-native host during a 20-d fumigation period without interfering with the natural shoot endophytic diversity of Z. zamiifolia. B. cereus ERBP conferred full protection to its non-native host against formaldehyde phytotoxicity and enhanced airborne formaldehyde removal of Z. zamiifolia whereas non-inoculated plants suffered from formaldehyde phytotoxicity because their natural shoot endophytic community was detrimentally affected by formaldehyde. In contrast, B. cereus ERBP inoculation into non-native E. milii deteriorated airborne formaldehyde removal of the non-native host (compared to a non-inoculated one) as B. cereus ERBP interfered with natural shoot endophytic community of E. milii, which caused stress symptoms and stimulated ethylene biosynthesis. Non-native host inoculation with PGP B. cereus ERBP could bear potentials and challenges for airborne formaldehyde removal. Copyright © 2016 Elsevier Masson SAS. All rights reserved.

Aldehyde measurements in indoor environments in Strasbourg (France)

NASA Astrophysics Data System (ADS)

Marchand, C.; Bulliot, B.; Le Calvé, S.; Mirabel, Ph.

Formaldehyde and acetaldehyde concentrations have been measured in indoor environments of various public spaces (railway station, airport, shopping center, libraries, underground parking garage, etc.) of Strasbourg area (east of France). In addition, formaldehyde, acetaldehyde propionaldehyde and hexanal concentrations have been measured in 22 private homes in the same area. In most of the sampling sites, indoor and outdoor formaldehyde and acetaldehyde concentrations were measured simultaneously. Gaseous aldehydes levels were quantified by a conventional DNHP-derivatization method followed by liquid chromatography coupled to UV detection. Outdoor formaldehyde and acetaldehyde concentrations were both in the range 1-10 μg m -3, the highest values being measured at the airport and railway station. Indoor concentrations were strongly dependant upon the sampling sites. In homes, the average concentrations were 37 μg m -3 (living rooms) and 46 μg m -3 (bedrooms) for formaldehyde, 15 μg m -3 (living rooms) and 18 μg m -3 (bedrooms) for acetaldehyde, 1.2 μg m -3 (living rooms) and 1.6 μg m -3 (bedrooms) for propionaldehyde, 9 μg m -3 (living rooms) and 10 μg m -3 (bedrooms) for hexanal. However, concentrations as high as 123, 80 and 47 μg m -3 have been found for formaldehyde, acetaldehyde and hexanal respectively. In public spaces, the highest formaldehyde concentration (62 μg m -3) was found in a library and the highest concentration of acetaldehyde (26 μg m -3) in the hall of a shopping center. Additional measurements of formaldehyde and acetaldehyde were made inside a car both at rest or in a fluid or heavy traffic as well as in a room where cigarettes were smoked. Our data have been discussed and compared with those of previous studies.

Identifying an indoor air exposure limit for formaldehyde considering both irritation and cancer hazards

PubMed Central

Golden, Robert

2011-01-01

Formaldehyde is a well-studied chemical and effects from inhalation exposures have been extensively characterized in numerous controlled studies with human volunteers, including asthmatics and other sensitive individuals, which provide a rich database on exposure concentrations that can reliably produce the symptoms of sensory irritation. Although individuals can differ in their sensitivity to odor and eye irritation, the majority of authoritative reviews of the formaldehyde literature have concluded that an air concentration of 0.3 ppm will provide protection from eye irritation for virtually everyone. A weight of evidence-based formaldehyde exposure limit of 0.1 ppm (100 ppb) is recommended as an indoor air level for all individuals for odor detection and sensory irritation. It has recently been suggested by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), and the US Environmental Protection Agency (US EPA) that formaldehyde is causally associated with nasopharyngeal cancer (NPC) and leukemia. This has led US EPA to conclude that irritation is not the most sensitive toxic endpoint and that carcinogenicity should dictate how to establish exposure limits for formaldehyde. In this review, a number of lines of reasoning and substantial scientific evidence are described and discussed, which leads to a conclusion that neither point of contact nor systemic effects of any type, including NPC or leukemia, are causally associated with exposure to formaldehyde. This conclusion supports the view that the equivocal epidemiology studies that suggest otherwise are almost certainly flawed by identified or yet to be unidentified confounding variables. Thus, this assessment concludes that a formaldehyde indoor air limit of 0.1 ppm should protect even particularly susceptible individuals from both irritation effects and any potential cancer hazard. PMID:21635194

Production and in vitro evaluation of soy protein-based biofilms as a support for human keratinocyte and fibroblast culture.

PubMed

Curt, Sèverine; Subirade, Muriel; Rouabhia, Mahmoud

2009-06-01

This study presents results on soy protein isolate (SPI) biofilm production and the corresponding effect on the stability and toxicity of the derived films. SPI biofilms were prepared from SPI chemically treated with formaldehyde at various concentrations (0%, 1%, 2%, and 3%) as cross-linking agents. In vitro SPI biofilm degradation was evaluated as a function of water absorption leading to weight and size modifications. SPI biofilm toxicity was determined as a function of human keratinocyte and fibroblast adhesion, viability, and proliferation. Cytokine gene expression supported this using reverse transcriptase polymerase chain reaction techniques. Our results confirm that SPI can be used to produce biofilms. The resulting SPI biofilms without formaldehyde swell significantly, which leads to their physical instability. Formaldehyde treatment enhanced the mechanical properties of these biofilms by covalently cross-linking polypeptide chains. The decreased water absorption was dependent on the amount of formaldehyde present. SPI biofilms with 2% and 3% formaldehyde were highly stable and easier to manipulate than those with 0% and 1% formaldehyde. Tissue culture analyses revealed that the SPI biofilms without formaldehyde were non-toxic to human cells (keratinocytes and fibroblasts). The presence of formaldehyde in biofilms did not have any effects on cell viability, adhesion, or proliferation. This was supported by the high level of messenger RNA expression of interleukin-1 beta (IL-1beta) and tumor necrosis factor alpha by the keratinocytes and of IL-6 and IL-8 by the fibroblasts. Overall, we produced a stable, non-toxic soy protein support, which may be of potential interest in medical applications such as cell culture matrices and damaged tissue replacement.

Phytoremediation of VOCs from indoor air by ornamental potted plants: A pilot study using a palm species under the controlled environment.

PubMed

Teiri, Hakimeh; Pourzamani, Hamidreza; Hajizadeh, Yaghoub

2018-04-01

Volatile organic compounds (VOCs) in indoor air have recently raised public concern due to their adverse health effects. One of hazardous VOC is Formaldehyde which can cause sensory irritation and induce nasopharyngeal cancer. The aim of this study was to investigate potted plant-soil system ability in formaldehyde removal from indoor air. We applied one of common interior plant from the palm species, Chamaedorea elegans, inside a chamber under the controlled environment. Entire plant, growing media and roots contribution in formaldehyde were evaluated by continuously introduction of different concentrations of formaldehyde into the chamber (0.66-16.4 mg m -3 ) each over a 48-h period. Our findings showed that the plant efficiently removed formaldehyde from polluted air by 65-100%, depending on the inlet concentrations, for a long time exposure. A maximum elimination capacity of 1.47 mg/m 2 . h was achieved with an inlet formaldehyde concentration of 14.6 mg m -3 . The removal ratio of areal part to pot soil and roots was 2.45:1 (71%: 29%). The plants could remove more formaldehyde in light rather than dark environment. Concentrations up to 16.4 mg m -3 were not high enough to affect the plants growth. However, a trivial decrease in chlorophyll content, carotenoid and water content of the treated plants was observed compared to the control plants. Thus, the palm species tested here showed high tolerance and good potential of formaldehyde removal from interior environments. Therefore, phytoremediation of VOCs from indoor air by the ornamental potted plants is an effective method which can be economically applicable in homes and offices. Copyright © 2018 Elsevier Ltd. All rights reserved.

The Magnetics Information Consortium (MagIC)

NASA Astrophysics Data System (ADS)

Johnson, C.; Constable, C.; Tauxe, L.; Koppers, A.; Banerjee, S.; Jackson, M.; Solheid, P.

2003-12-01

The Magnetics Information Consortium (MagIC) is a multi-user facility to establish and maintain a state-of-the-art relational database and digital archive for rock and paleomagnetic data. The goal of MagIC is to make such data generally available and to provide an information technology infrastructure for these and other research-oriented databases run by the international community. As its name implies, MagIC will not be restricted to paleomagnetic or rock magnetic data only, although MagIC will focus on these kinds of information during its setup phase. MagIC will be hosted under EarthRef.org at http://earthref.org/MAGIC/ where two "integrated" web portals will be developed, one for paleomagnetism (currently functional as a prototype that can be explored via the http://earthref.org/databases/PMAG/ link) and one for rock magnetism. The MagIC database will store all measurements and their derived properties for studies of paleomagnetic directions (inclination, declination) and their intensities, and for rock magnetic experiments (hysteresis, remanence, susceptibility, anisotropy). Ultimately, this database will allow researchers to study "on the internet" and to download important data sets that display paleo-secular variations in the intensity of the Earth's magnetic field over geological time, or that display magnetic data in typical Zijderveld, hysteresis/FORC and various magnetization/remanence diagrams. The MagIC database is completely integrated in the EarthRef.org relational database structure and thus benefits significantly from already-existing common database components, such as the EarthRef Reference Database (ERR) and Address Book (ERAB). The ERR allows researchers to find complete sets of literature resources as used in GERM (Geochemical Earth Reference Model), REM (Reference Earth Model) and MagIC. The ERAB contains addresses for all contributors to the EarthRef.org databases, and also for those who participated in data collection, archiving and analysis in the magnetic studies. Integration with these existing components will guarantee direct traceability to the original sources of the MagIC data and metadata. The MagIC database design focuses around the general workflow that results in the determination of typical paleomagnetic and rock magnetic analyses. This ensures that individual data points can be traced between the actual measurements and their associated specimen, sample, site, rock formation and locality. This permits a distinction between original and derived data, where the actual measurements are performed at the specimen level, and data at the sample level and higher are then derived products in the database. These relations will also allow recalculation of derived properties, such as site means, when new data becomes available for a specific locality. Data contribution to the MagIC database is critical in achieving a useful research tool. We have developed a standard data and metadata template that can be used to provide all data at the same time as publication. Software tools are provided to facilitate easy population of these templates. The tools allow for the import/export of data files in a delimited text format, and they provide some advanced functionality to validate data and to check internal coherence of the data in the template. During and after publication these standardized MagIC templates will be stored in the ERR database of EarthRef.org from where they can be downloaded at all times. Finally, the contents of these template files will be automatically parsed into the online relational database.

Introducing a New Interface for the Online MagIC Database by Integrating Data Uploading, Searching, and Visualization

NASA Astrophysics Data System (ADS)

Jarboe, N.; Minnett, R.; Constable, C.; Koppers, A. A.; Tauxe, L.

2013-12-01

The Magnetics Information Consortium (MagIC) is dedicated to supporting the paleomagnetic, geomagnetic, and rock magnetic communities through the development and maintenance of an online database (http://earthref.org/MAGIC/), data upload and quality control, searches, data downloads, and visualization tools. While MagIC has completed importing some of the IAGA paleomagnetic databases (TRANS, PINT, PSVRL, GPMDB) and continues to import others (ARCHEO, MAGST and SECVR), further individual data uploading from the community contributes a wealth of easily-accessible rich datasets. Previously uploading of data to the MagIC database required the use of an Excel spreadsheet using either a Mac or PC. The new method of uploading data utilizes an HTML 5 web interface where the only computer requirement is a modern browser. This web interface will highlight all errors discovered in the dataset at once instead of the iterative error checking process found in the previous Excel spreadsheet data checker. As a web service, the community will always have easy access to the most up-to-date and bug free version of the data upload software. The filtering search mechanism of the MagIC database has been changed to a more intuitive system where the data from each contribution is displayed in tables similar to how the data is uploaded (http://earthref.org/MAGIC/search/). Searches themselves can be saved as a permanent URL, if desired. The saved search URL could then be used as a citation in a publication. When appropriate, plots (equal area, Zijderveld, ARAI, demagnetization, etc.) are associated with the data to give the user a quicker understanding of the underlying dataset. The MagIC database will continue to evolve to meet the needs of the paleomagnetic, geomagnetic, and rock magnetic communities.

Problems in the disinfection of class 1 microbiology safety cabinets.

PubMed Central

Everall, P H; Morris, C A; Oliver, P R; Becker, J F

1982-01-01

Microbiology safety cabinet disinfection procedures using formaldehyde have been tested. Tubercle bacilli were killed by concentrations of formaldehyde obtained by heating commercial formalin irrespective of whether the bacilli were in the cabinet free space or above the prefilters. However, Bacillus stearothermophilus spore papers for for the testing of low temperature steam/formaldehyde sterilisers were almost never sterilised and a strain of Staphylococcus epidermidis (NCTC 7944) showed a resistance intermediate between the B stearothermophilus spores and the tubercle bacilli. Tests using a vaccine strain of poliovirus type 3 indicated a considerable degree of resistance of the virus to the action of formaldehyde. No such resistance was demonstrated by vaccinia virus or echovirus 14. Chemical and biological evidence is presented which indicates that filter paper discs are an unsuitable carrier material for a challenge organism in testing the efficiency of any formaldehyde sterilising process. Recommendations are made towards developing a satisfactory test procedure. PMID:7047573

Biofiltration of waste gases containing a mixture of formaldehyde and methanol.

PubMed

Prado, Oscar J; Veiga, María C; Kennes, Christian

2004-08-01

Several biofilters and biotrickling filters were used for the treatment of a mixture of formaldehyde and methanol; and their efficiencies were compared. Results obtained with three different inert filter bed materials (lava rock, perlite, activated carbon) suggested that the packing material had only little influence on the performance. The best results were obtained in a biotrickling filter packed with lava rock and fed a nutrient solution that was renewed weekly. A maximum formaldehyde elimination capacity of 180 g m(-3) h(-1) was reached, while the methanol elimination capacity rose occasionally to more than 600 g m(-3) h(-1). Formaldehyde degradation was affected by the inlet methanol concentration. Several combinations of load vs empty bed residence time (EBRTs of 71.9, 46.5, 30.0, 20.7 s) were studied, reaching a formaldehyde elimination capacity of 112 g m(-3) h(-1) with about 80% removal efficiency at the lowest EBRT (20.7 s).

Formaldehyde Surface Distributions and Variability in the Mexico City Basin

NASA Astrophysics Data System (ADS)

Junkermann, W.; Mohr, C.; Steinbrecher, R.; Ruiz Suarez, L.

2007-05-01

Formaldehyde ambient air mole fractions were measured throughout the dry season in March at three different locations in the Mexico City basin. The continuously running instruments were operated at Tenago del Aire, a site located in the Chalco valley in the southern venting area of the basin, at the Intituto Mexicano del Petroleo (IMP) in the northern part of the city and about 30 km north of the city at the campus of the Universidad Tecnològica de Tecamac (UTTEC). The technique used is the Hantzsch technology with a time resolution of 2 minutes and a detection limit of 100 ppt. Daily maxima peaked at 35 ppb formaldehyde in the city and about 15 to 20 ppb at the other sites. During night formaldehyde levels dropped to about 5 ppb or less. It is evident that the observed spatial and temporal variability in near surface formaldehyde distributions is strongly affected by local and regional advection processes.

Edible carbohydrates from formaldehyde in a spacecraft

NASA Technical Reports Server (NTRS)

Weiss, A. H.

1975-01-01

The autocatalytic nature of the base catalyzed condensation of formaldehyde to formose sugars is eliminated by using as a cocatalyst, an aldose, or ketose having an alpha-hydrogen. This is more strongly complexed by base than is formaldehyde and the cocatalyst and sugar products accumulate as catalyst complexes instead of formaldehyde. Because of the presence of alpha-hydrogen atoms in cocatalysts and formose sugars, their removal by cross Cannizzaro reaction of complexed sugars does not occur, so the formose reaction behaves autocatalytically due to this accumulation. It is believed that a given catalytic formose complex is not a discrete complexed sugar, but rather, a scrambled dynamic mixture of sugars having weakened structures. The sugar complexes derive from a common salt-like formaldehyde complex, which, because of the absence of alpha-hydrogen, has a greater tendency to undergo Cannizzaro reaction, rather than formose condensation. Because of this, the Cannizzaro reaction can proceed without measurable formose condensation. The reverse is not possible.

Magical thinking and decision-making strategies among late adolescent regular gamblers: A mediation model.

PubMed

Passanisi, Alessia; Craparo, Giuseppe; Pace, Ugo

2017-08-01

In the present study, the relation between the tendency to seek supernatural connections between external events and one's own thoughts, words, and actions and gambling among late adolescents has been studied. Psychologists have called this tendency magical thinking. The principal aim of the present study was to test the fit of an explanatory model of risk that starts from magical thinking and passes through maladaptive decision-making strategies, culminating with pathological gambling. Two hundred twenty-two Italian late adolescents, regularly attending bingo halls, aged between 19 and 21 years, completed measures on magical thinking, decision-making strategies, and gambling. Results highlight that young adults adopting dysfunctional modes of thought (i.e. magical thinking) tend to engage with maladaptive styles of decision-making that predispose them to gamble. Copyright © 2017 The Foundation for Professionals in Services for Adolescents. Published by Elsevier Ltd. All rights reserved.

Asphaltenes-based polymer nano-composites

DOEpatents

Bowen, III, Daniel E

2013-12-17

Inventive composite materials are provided. The composite is preferably a nano-composite, and comprises an asphaltene, or a mixture of asphaltenes, blended with a polymer. The polymer can be any polymer in need of altered properties, including those selected from the group consisting of epoxies, acrylics, urethanes, silicones, cyanoacrylates, vulcanized rubber, phenol-formaldehyde, melamine-formaldehyde, urea-formaldehyde, imides, esters, cyanate esters, allyl resins.

Preparation and Characterization of Novolak Phenol Formaldehyde Resin from Liquefied Brown-Rotted Wood

Treesearch

Gai-Yun Li; Chung-Yun Hse; Te-Fu Qin

2012-01-01

The brown-rotted wood was liquefied in phenol with phosphoric acid as catalyst and the resulting liquefied products were condensed with formaldehyde to yield novolak liquefied wood-based phenol formaldehyde resin (LWPF). The results showed that brown-rotted wood could be more easily liquefied than sound wood in phenol. The residue content of liquefied wood decreased...

Simultaneous bond degradation and bond formation during phenol-formaldehyde curing with wood

Treesearch

Daniel J. Yelle; John Ralph

2016-01-01

Bonding of wood using phenol–formaldehyde adhesive develops highly durable bonds. Phenol– formaldehyde is believed to form primary bonds with wood cell wall polymers (e.g., lignin). However, it is unclear how this adhesive interacts and bonds to lignin. Through wood solubilisation methodologies, earlywood and latewood bonded assemblies were characterized using two-...

Soy adhesives that can form durable bonds for plywood, laminated wood flooring, and particleboard

Treesearch

Charles R. Frihart; Michael J. Birkeland; Anthony J. Allen; James M. Wescott

2010-01-01

Synthetic adhesives, including urea-formaldehyde (UF) and phenol-formaldehyde (PF), have generally replaced biobased adhesives over the past 70 years because of their durability, low cost, and ease of use. However, in the past few years, concern about formaldehyde emissions, cost, and interest in biobased materials have renewed interest in soy adhesives. The use of soy...

NHEXAS PHASE I ARIZONA STUDY--STANDARD OPERATING PROCEDURE FOR COLLECTION OF FIXED SITE INDOOR AND OUTDOOR FORMALDEHYDE PASSIVE SAMPLES (UA-F-13.1)

EPA Science Inventory

The purpose of this SOP is to describe the methods used to sample residential indoor and outdoor atmospheres for the presence of formaldehyde using the PF-1 passive formaldehyde sampler. The PF-1 passive sampler is used as a fixed location monitor to determine time integrated ex...

Catalytic process for formaldehyde oxidation

NASA Technical Reports Server (NTRS)

Kielin, Erik J. (Inventor); Brown, Kenneth G. (Inventor); D'Ambrosia, Christine M. (Inventor)

1996-01-01

Disclosed is a process for oxidizing formaldehyde to carbon dioxide and water without the addition of energy. A mixture of formaldehyde and an oxidizing agent (e.g., ambient air containing formaldehyde) is exposed to a catalyst which includes a noble metal dispersed on a metal oxide which possesses more than one oxidation state. Especially good results are obtained when the noble metal is platinum, and the metal oxide which possesses more than one oxidation state is tin oxide. A promoter (i.e., a small amount of an oxide of a transition series metal) may be used in association with the tin oxide to provide very beneficial results.

Quantification of Atmospheric Formaldehyde by Near-Infrared Cavity Ring-Down Spectroscopy

NASA Astrophysics Data System (ADS)

Rella, C.; Hoffnagle, J.; Fleck, D.; Kim-Hak, D.

2017-12-01

Formaldehyde is an important species in atmospheric chemistry, especially in urban environments, where it is a decay product of methane and volatile hydrocarbons. It is also a toxic, carcinogenic compound that can contaminate ambient air from incomplete combustion, or outgassing of commercial products such as adhesives used to fabricate plywood or to affix indoor carpeting. Formaldehyde has a clearly resolved ro-vibrational absorption spectrum that is well-suited to optical analysis of formaldehyde concentration. We describe an instrument based on cavity ring-down spectroscopy for the quantitative analysis of formaldehyde concentration in ambient air. The instrument has a precision (1-sigma) of about 1 ppb at a measurement rate of 1 second, and provides measurements of less than 100 ppt with averaging. The instrument provides stable measurements (drift < 1 ppb) over long periods of time (days). The instrument has been ruggedized for mobile applications, and with a fast response time of a couple of seconds, it is suitable for ground-based vehicle deployments for fenceline monitoring of formaldehyde emissions. In addition, we report on ambient atmospheric measurements at a 10m urban tower, which demonstrate the suitability of the instrument for applications in atmospheric chemistry.

Comparison of aldehyde emissions simulation with FTIR measurements in the exhaust of a spark ignition engine fueled by ethanol

NASA Astrophysics Data System (ADS)

Zarante, Paola Helena Barros; Sodré, José Ricardo

2018-07-01

This work presents a numerical simulation model for aldehyde formation and exhaust emissions from ethanol-fueled spark ignition engines. The aldehyde simulation model was developed using FORTRAN software, with the input data obtained from the dedicated engine cycle simulation software AVL BOOST. The model calculates formaldehyde and acetaldehyde concentrations from post-flame partial oxidation of methane, ethane and unburned ethanol. The calculated values were compared with experimental data obtained from a mid-size sedan powered by a 1.4-l spark ignition engine, tested on a chassis dynamometer. Exhaust aldehyde concentrations were determined using a Fourier Transform Infrared (FTIR) Spectroscopy analyzer. In general, the results demonstrate that the concentrations of aldehydes and the source elements increased with engine speed and exhaust gas temperature. The measured acetaldehyde concentrations showed values from 3 to 6 times higher than formaldehyde in the range studied. The model could predict reasonably well the qualitative experimental trends, with the quantitative results showing a maximum discrepancy of 39% for acetaldehyde concentration and 21 ppm for exhaust formaldehyde.

Comparison of aldehyde emissions simulation with FTIR measurements in the exhaust of a spark ignition engine fueled by ethanol

NASA Astrophysics Data System (ADS)

Zarante, Paola Helena Barros; Sodré, José Ricardo

2018-02-01

This work presents a numerical simulation model for aldehyde formation and exhaust emissions from ethanol-fueled spark ignition engines. The aldehyde simulation model was developed using FORTRAN software, with the input data obtained from the dedicated engine cycle simulation software AVL BOOST. The model calculates formaldehyde and acetaldehyde concentrations from post-flame partial oxidation of methane, ethane and unburned ethanol. The calculated values were compared with experimental data obtained from a mid-size sedan powered by a 1.4-l spark ignition engine, tested on a chassis dynamometer. Exhaust aldehyde concentrations were determined using a Fourier Transform Infrared (FTIR) Spectroscopy analyzer. In general, the results demonstrate that the concentrations of aldehydes and the source elements increased with engine speed and exhaust gas temperature. The measured acetaldehyde concentrations showed values from 3 to 6 times higher than formaldehyde in the range studied. The model could predict reasonably well the qualitative experimental trends, with the quantitative results showing a maximum discrepancy of 39% for acetaldehyde concentration and 21 ppm for exhaust formaldehyde.

Investigation of the usage of centrifuging waste of mineral wool melt (CMWW), contaminated with phenol and formaldehyde, in manufacturing of ceramic products.

PubMed

Kizinievič, Olga; Balkevičius, Valdas; Pranckevičienė, Jolanta; Kizinievič, Viktor

2014-08-01

Large amounts of centrifuging waste of mineral wool melt (CMWW) are created during the production of mineral wool. CMWW is technogenic aluminum silicate raw material, formed from the particles of undefibred melt (60-70%) and mineral wool fibers (30-40%). 0.3-0.6% of organic binder with phenol and formaldehyde in its composition exists in this material. Objective of the research is to investigate the possibility to use CMWW as an additive for the production of ceramic products, by neutralising phenol and formaldehyde existing in CMWW. Formation masses were prepared by incorporating 10%, 20% and 30% of CMWW additive and burned at various temperatures. It was identified that the amount of 10-30% of CMWW additive influences the following physical and mechanical properties of the ceramic body: lowers drying and firing shrinkage, density, increases compressive strength and water absorption. Investigations carried out show that CMWW waste can be used for the production of ceramic products of various purposes. Copyright © 2014 Elsevier Ltd. All rights reserved.