Tropospheric Emission Spectrometer (TES) for the Earth Observing System (EOS) CHEM Satellite

NASA Technical Reports Server (NTRS)

Beer, R.; Glavich, T.; Rider, D.

2000-01-01

The Tropospheric Emission Spectrometer (TES) is an imaging infrared Fourier transform spectrometer scheduled to be launched into polar sun-synchronous orbit on the Earth Observing System (EOS) CHEM satellite in December 2002.

Tropospheric and Airborne Emission Spectrometers

NASA Technical Reports Server (NTRS)

Glavich, Thomas; Beer, Reinhard

1996-01-01

X This paper describes the development of two related instruments, the Tropospheric Emission Spectrometer (TES) and the Airborne Emission Spectrometer (AES). Both instruments are infrared imaging Fourier Transform Spectrometers, used for measuring the state of the lower atmosphere, and in particular the measurement of ozone and ozone sources and sinks.

Analytical Properties of Time-of-Flight PET Data

PubMed Central

Cho, Sanghee; Ahn, Sangtae; Li, Quanzheng; Leahy, Richard M.

2015-01-01

We investigate the analytical properties of time-of-flight (TOF) positron emission tomography (PET) sinograms, where the data are modeled as line integrals weighted by a spatially invariant TOF kernel. First, we investigate the Fourier transform properties of 2D TOF data and extend the “bow-tie” property of the 2D Radon transform to the time of flight case. Second, we describe a new exact Fourier rebinning method, TOF-FOREX, based on the Fourier transform in the time-of-flight variable. We then combine TOF-FOREX rebinning with a direct extension of the projection slice theorem to TOF data, to perform fast 3D TOF PET image reconstruction. Finally, we illustrate these properties using simulated data. PMID:18460746

40 CFR 63.5545 - What are my monitoring installation, operation, and maintenance requirements?

Code of Federal Regulations, 2010 CFR

2010-07-01

... measure organic HAP emissions; and (iv) PS-15 of 40 CFR part 60, appendix B, for CEMS that use Fourier transform infrared spectroscopy to measure organic HAP emissions. (2) You must conduct a performance...

Multichannel Dynamic Fourier-Transform IR Spectrometer

NASA Astrophysics Data System (ADS)

Balashov, A. A.; Vaguine, V. A.; Golyak, Il. S.; Morozov, A. N.; Khorokhorin, A. I.

2017-09-01

A design of a multichannel continuous scan Fourier-transform IR spectrometer for simultaneous recording and analysis of the spectral characteristics of several objects is proposed. For implementing the design, a multi-probe fiber is used, constructed from several optical fibers connected into a single optical connector and attached at the output of the interferometer. The Fourier-transform spectrometer is used as a signal modulator. Each fiber is individually mated with an investigated sample and a dedicated radiation detector. For the developed system, the radiation intensity of the spectrometer is calculated from the condition of the minimum spectral resolution and parameters of the optical fibers. Using the proposed design, emission spectra of a gas-discharge neon lamp have been recorded using a single fiber 1 mm in diameter with a numerical aperture NA = 0.22.

EVALUATION OF FUGITIVE EMISSIONS USING GROUND-BASED OPTICAL REMOTE SENSING TECHNOLOGY

EPA Science Inventory

EPA has developed and evaluated a method for characterizing fugitive emissions from large area sources. The method, known as radial plume mapping (RPM) uses multiple-beam, scanning, optical remote sensing (ORS) instrumentation such as open-path Fourier transform infrared spectro...

MEASUREMENT OF FUGITIVE EMISSIONS AT A BIOREACTOR LANDFILL

EPA Science Inventory

This report focuses on three field campaigns performed in 2002 and 2003 to measure fugitive emissions at a bioreactor landfill in Louisville, KY, using an open-path Fourier transform infrared spectrometer. The study uses optical remote sensing-radial plume mapping. The horizontal...

Fourier transform infrared emission spectra of MnH and MnD

NASA Astrophysics Data System (ADS)

Gordon, Iouli E.; Appadoo, Dominique R. T.; Shayesteh, Alireza; Walker, Kaley A.; Bernath, Peter F.

2005-01-01

Fourier transform infrared emission spectra of MnH and MnD were observed in the ground X7Σ + electronic state. The vibration-rotation bands from v = 1 → 0 to v = 3 → 2 for MnH and from v = 1 → 0 to v = 4 → 3 for MnD were recorded at an instrumental resolution of 0.0085 cm -1. Spectroscopic constants were determined for each vibrational level and equilibrium constants were found from a Dunham-type fit. The equilibrium vibrational constant ( ωe) for MnH was found to be 1546.84518(65) cm -1, the equilibrium rotational constant ( Be) is 5.6856789(103) cm -1 and the eqilibrium bond distance ( re) was determined to be 1.7308601(47) Å.

APPLYING OPEN-PATH OPTICAL SPECTROSCOPY TO HEAVY-DUTY DIESEL EMISSIONS

EPA Science Inventory

Non-dispersive infrared absorption has been used to measure gaseous emissions for both stationary and mobile sources. Fourier transform infrared spectroscopy has been used for stationary sources as both extractive and open-path methods. We have applied the open-path method for bo...

OPEN-PATH FTIR MEASUREMENTS OF NOX AND OTHER DIESEL EMISSIONS

EPA Science Inventory

The paper gives results of a demonstration of the feasibility of using an open-path Fourier transform infrared (OP-FTIR) monitoring technique to address the across-road characterization of diesel vehicle emissions of criteria pollutants and hazardous air pollutants. Four sets of ...

VALIDATION OF A METHOD FOR ESTIMATING POLLUTION EMISSION RATES FROM AREA SOURCES USING OPEN-PATH FTIR SEPCTROSCOPY AND DISPERSION MODELING TECHNIQUES

EPA Science Inventory

The paper describes a methodology developed to estimate emissions factors for a variety of different area sources in a rapid, accurate, and cost effective manner. he methodology involves using an open-path Fourier transform infrared (FTIR) spectrometer to measure concentrations o...

Fourier transform spectrometer for spectral emissivity measurement in the temperature range between 60 and 1500°C

NASA Astrophysics Data System (ADS)

Dai, Jingmin; Wang, Xinbei; Yuan, Guibin

2005-01-01

A new spectral emissivity measurement system has been developed at Harbin Institute of Technology (HIT) by using a Fourier transform infrared (FTIR) spectrometer. The spectral range between 0.6 and 25 µm was covered by a photovoltaic HgCdTe and a silicon photodiode detector. A SiC heater with a black hole was employed for heating the sample. The temperature of the sample can be controlled in a range between 60 and 1500°C with an error of less than 1°C. The system was calibrated against two high quality reference blackbodies: a low temperature heat-pipe blackbody operated in the temperature range between 60°C and 300°C and a high temperature blackbody with SiC heater operated in the temperature range between 300°C and 1500°C. Several tests were done for this new system. The estimated uncertainty of emissivity measurement is better than 3%.

Monitoring trace gases in downtown Toronto using open-path Fourier transform infrared spectroscopy

NASA Astrophysics Data System (ADS)

Byrne, B.; Strong, K.; Colebatch, O.; Fogal, P.; Mittermeier, R. L.; Wunch, D.; Jones, D. B. A.

2017-12-01

Emissions of greenhouse gases (GHGs) in urban environments can be highly heterogeneous. For example, vehicles produce point source emissions which can result in heterogeneous GHG concentrations on scales <10 m. The highly localized scale of these emissions can make it difficult to measure mean GHG concentrations on scales of 100-1000 m. Open-Path Fourier Transform Infrared Spectroscopy (OP-FTIR) measurements offer spatial averaging and continuous measurements of several trace gases simultaneously in the same airmass. We have set up an open-path system in downtown Toronto to monitor trace gases in the urban boundary layer. Concentrations of CO2, CO, CH4, and N2O are derived from atmospheric absorption spectra recorded over a two-way atmospheric open path of 320 m using non-linear least squares fitting. Using a simple box model and co-located boundary layer height measurements, we estimate surface fluxes of these gases in downtown Toronto from our OP-FTIR observations.

Detection and measurement of electroreflectance on quantum cascade laser device using Fourier transform infrared microscope

DOE Office of Scientific and Technical Information (OSTI.GOV)

Enobio, Eli Christopher I.; Ohtani, Keita; Ohno, Yuzo

2013-12-02

We demonstrate the use of a Fourier Transform Infrared microscope system to detect and measure electroreflectance (ER) from mid-infrared quantum cascade laser (QCL) device. To characterize intersubband transition (ISBT) energies in a functioning QCL device, a microscope is used to focus the probe on the QCL cleaved mirror. The measured ER spectra exhibit resonance features associated to ISBTs under applied electric field in agreement with the numerical calculations and comparable to observed photocurrent, and emission peaks. The method demonstrates the potential as a characterization tool for QCL devices.

Identification of a Methane Oxidation Intermediate on Solid Oxide Fuel Cell Anode Surfaces with Fourier Transform Infrared Emission.

PubMed

Pomfret, Michael B; Steinhurst, Daniel A; Owrutsky, Jeffrey C

2013-04-18

Fuel interactions on solid oxide fuel cell (SOFC) anodes are studied with in situ Fourier transform infrared emission spectroscopy (FTIRES). SOFCs are operated at 800 °C with CH4 as a representative hydrocarbon fuel. IR signatures of gas-phase oxidation products, CO2(g) and CO(g), are observed while cells are under load. A broad feature at 2295 cm(-1) is assigned to CO2 adsorbed on Ni as a CH4 oxidation intermediate during cell operation and while carbon deposits are electrochemically oxidized after CH4 operation. Electrochemical control provides confirmation of the assignment of adsorbed CO2. FTIRES has been demonstrated as a viable technique for the identification of fuel oxidation intermediates and products in working SOFCs, allowing for the elucidation of the mechanisms of fuel chemistry.

SITELLE: a wide-field imaging Fourier transform spectrometer for the Canada-France-Hawaii Telescope

NASA Astrophysics Data System (ADS)

Drissen, L.; Bernier, A.-P.; Rousseau-Nepton, L.; Alarie, A.; Robert, C.; Joncas, G.; Thibault, S.; Grandmont, F.

2010-07-01

We describe the concept of a new instrument for the Canada-France-Hawaii telescope (CFHT), SITELLE (Spectromètre Imageur à Transformée de Fourier pour l'Etude en Long et en Large de raies d'Emission), as well as a science case and a technical study of its preliminary design. SITELLE will be an imaging Fourier transform spectrometer capable of obtaining the visible (350 nm - 950 nm) spectrum of every source of light in a field of view of 15 arcminutes, with 100% spatial coverage and a spectral resolution ranging from R = 1 (deep panchromatic image) to R = 104 (for gas dynamics). SITELLE will cover a field of view 100 to 1000 times larger than traditional integral field spectrographs, such as GMOS-IFU on Gemini or the future MUSE on the VLT. It is a legacy from BEAR, the first imaging FTS installed on the CFHT and the direct successor of SpIOMM, a similar instrument attached to the 1.6-m telescope of the Observatoire du Mont-Mégantic in Québec. SITELLE will be used to study the structure and kinematics of HII regions and ejecta around evolved stars in the Milky Way, emission-line stars in clusters, abundances in nearby gas-rich galaxies, and the star formation rate in distant galaxies.

Measurement of fugitive volatile organic compound emissions from a petrochemical tank farm using open-path Fourier transform infrared spectrometry

NASA Astrophysics Data System (ADS)

Wu, Chang-Fu; Wu, Tzong-gang; Hashmonay, Ram A.; Chang, Shih-Ying; Wu, Yu-Syuan; Chao, Chun-Ping; Hsu, Cheng-Ping; Chase, Michael J.; Kagann, Robert H.

2014-01-01

Fugitive emission of air pollutants is conventionally estimated based on standard emission factors. The Vertical Radial Plume Mapping (VRPM) technique, as described in the US EPA OTM-10, is designed to measure emission flux by directly monitoring the concentration of the plume crossing a vertical plane downwind of the site of interest. This paper describes the evaluation results of implementing VRPM in a complex industrial setting (a petrochemical tank farm). The vertical plane was constructed from five retroreflectors and an open-path Fourier transform infrared spectrometer. The VRPM configuration was approximately 189.2 m in width × 30.7 m in height. In the accompanying tracer gas experiment, the bias of the VRPM estimate was less than 2% and its 95% confidence interval contained the true release rate. Emission estimates of the target VOCs (benzene, m-xylene, o-xylene, p-xylene, and toluene) ranged from 0.86 to 2.18 g s-1 during the 14-day field campaign, while estimates based on the standard emission factors were one order of magnitude lower, possibly leading to an underestimation of the impact of these fugitive emissions on air quality and human health. It was also demonstrated that a simplified 3-beam geometry (i.e., without one dimensional scanning lines) resulted in higher uncertainties in the emission estimates.

[Combustion temperature measurement of pyrotechnic composition using remote sensing Fourier transform infrared spectrometry].

PubMed

Zhou, Xin-li; Li, Yan; Liu, Zu-liang; Zhu, Chang-jiang; Wang, Jun-de; Lu, Chun-xu

2002-10-01

In this paper, combustion characterization of pyrotechnic composition is investigated using a remote sensing Fourier transform infrared spectrometry. The emission spectra have been recorded between 4,700 and 740 cm-1 with a spectral resolution of 4 cm-1. The combustion temperature can be determined remotely from spectral line intensity distribution of the fine structure of the emission fundamental band of gaseous products such as HF. The relationship between combustion temperature and combustion time has been given. Results show that there is a violent mutative temperature field with bigger temperature gradient near combustion surface. It reveals that the method of temperature measurement using remote sensing FTIR for flame temperature of unstable, violent and short time combustion on real time is a rapid, accurate and sensitive technique without interference the flame temperature field. Potential prospects of temperature measurement, gas product concentration measurement and combustion mechanism are also revealed.

Fourier transform spectra of quantum dots

NASA Astrophysics Data System (ADS)

Damian, V.; Ardelean, I.; Armăşelu, Anca; Apostol, D.

2009-09-01

Semiconductor quantum dots are nanometer-sized crystals with unique photochemical and photophysical properties that are not available from either isolated molecules or bulk solids. These nanocrystals absorb light over a very broad spectral range as compared to molecular fluorophores which have very narrow excitation spectra. High-quality QDs are proper to be use in different biological and medical applications (as fluorescent labels, the cancer treatment and the drug delivery). In this article, we discuss Fourier transform visible spectroscopy of commercial quantum dots. We reveal that QDs produced by Evident Technologies when are enlightened by laser or luminescent diode light provides a spectral shift of their fluorescence spectra correlated to exciting emission wavelengths, as shown by the ARCspectroNIR Fourier Transform Spectrometer. In the final part of this paper we show an important biological application of CdSe/ZnS core-shell ODs as microbial labeling both for pure cultures of cyanobacteria (Synechocystis PCC 6803) and for mixed cultures of phototrophic and heterotrophic microorganisms.

Fourier transform spectra of quantum dots

NASA Astrophysics Data System (ADS)

Damian, V.; Ardelean, I.; Armăşelu, Anca; Apostol, D.

2010-05-01

Semiconductor quantum dots are nanometer-sized crystals with unique photochemical and photophysical properties that are not available from either isolated molecules or bulk solids. These nanocrystals absorb light over a very broad spectral range as compared to molecular fluorophores which have very narrow excitation spectra. High-quality QDs are proper to be use in different biological and medical applications (as fluorescent labels, the cancer treatment and the drug delivery). In this article, we discuss Fourier transform visible spectroscopy of commercial quantum dots. We reveal that QDs produced by Evident Technologies when are enlightened by laser or luminescent diode light provides a spectral shift of their fluorescence spectra correlated to exciting emission wavelengths, as shown by the ARCspectroNIR Fourier Transform Spectrometer. In the final part of this paper we show an important biological application of CdSe/ZnS core-shell ODs as microbial labeling both for pure cultures of cyanobacteria (Synechocystis PCC 6803) and for mixed cultures of phototrophic and heterotrophic microorganisms.

Analytical Chemistry and the Microchip.

ERIC Educational Resources Information Center

Lowry, Robert K.

1986-01-01

Analytical techniques used at various points in making microchips are described. They include: Fourier transform infrared spectrometry (silicon purity); optical emission spectroscopy (quantitative thin-film composition); X-ray photoelectron spectroscopy (chemical changes in thin films); wet chemistry, instrumental analysis (process chemicals);…

The tropical forest and fire emissions experiment: Laboratory fire measurement and synthesis of campaign data

Treesearch

R. J. Yokelson; T. J. Christian; T. G. Karl; A. Guenther

2008-01-01

As part of the Tropical Forest and Fire Emissions Experiment (TROFFEE), tropical forest fuels were burned in a large, biomass-fire simulation facility and the smoke was characterized with open-path Fourier transform infrared spectroscopy (FTIR), proton-transfer reaction mass spectrometry (PTR-MS), gas chromatography (GC), GC/PTRMS, and filter sampling of the particles...

Synthesis and characterization of pure and Li⁺ activated Alq₃ complexes for green and blue organic light emitting diodes and display devices.

PubMed

Bhagat, S A; Borghate, S V; Kalyani, N Thejo; Dhoble, S J

2014-08-01

Pure and Li(+)-doped Alq3 complexes were synthesized by simple precipitation method at room temperature, maintaining the stoichiometric ratio. These complexes were characterized by X-ray diffraction, ultraviolet-visible absorption and Fourier transform infrared and photoluminescence (PL) spectra. X-ray diffraction analysis reveals the crystalline nature of the synthesized complexes, while Fourier transform infrared spectroscopy confirm the molecular structure, the completion of quinoline ring formation and presence of quinoline structure in the metal complex. Ultraviolet-visible and PL spectra revealed that Li(+) activated Alq3 complexes exhibit the highest intensity in comparison to pure Alq3 phosphor. Thus, Li(+) enhances PL emission intensity when doped into Alq3 phosphor. The excitation spectra lie in the range of 383-456 nm. All the synthesized complexes other than Liq give green emission, while Liq gives blue emission with enhanced intensity. Thus, he synthesized phosphors are the best suitable candidates for green- and blue-emitting organic light emitting diode, PL liquid-crystal display and solid-state lighting applications. Copyright © 2013 John Wiley & Sons, Ltd.

Functional biocompatible magnetite-cellulose nanocomposite fibrous networks: Characterization by fourier transformed infrared spectroscopy, X-ray powder diffraction and field emission scanning electron microscopy analysis.

PubMed

Habibi, Neda

2015-02-05

The preparation and characterization of functional biocompatible magnetite-cellulose nano-composite fibrous material is described. Magnetite-cellulose nano-composite was prepared by a combination of the solution-based formation of magnetic nano-particles and subsequent coating with amino celluloses. Characterization was accomplished using X-ray powder diffraction (XRD), fourier transformed infrared (FTIR) and field emission scanning electron microscopy (FESEM) analysis. The peaks of Fe3O4 in the XRD pattern of nanocomposite confirm existence of the nanoparticles in the amino cellulose matrix. Magnetite-cellulose particles exhibit an average diameter of roughly 33nm as demonstrated by field emission scanning electron microscopy. Magnetite nanoparticles were irregular spheres dispersed in the cellulose matrix. The vibration corresponding to the NCH3 functional group about 2850cm(-1) is assigned in the FTIR spectra. Functionalized magnetite-cellulose nano-composite polymers have a potential range of application as targeted drug delivery system in biomedical field. Copyright © 2014 Elsevier B.V. All rights reserved.

Fourier Transform Infrared Spectroscopy Part III. Applications.

ERIC Educational Resources Information Center

Perkins, W. D.

1987-01-01

Discusses the use of the FT-IR spectrometer in analyses that were previously avoided. Examines some of the applications of this spectroscopy with aqueous solutions, circular internal reflection, samples with low transmission, diffuse reflectance, infrared emission, and the infrared microscope. (TW)

Application of an Imaging Fourier-Transform Spectrometer for the Means of Combustion Diagnostics

DTIC Science & Technology

2012-06-14

and P. McCready. Dial measurements of fugitive emissions from natural gas plants and the comparison with emission factor estimates. Proc. 15th...12-J02 Abstract A passive remote sensing technique for accurately monitoring the combustion effi- ciency of petrochemical flares is greatly desired. A...and the spatial distribu- tion of combustion by-products. The flame spectra were characterized by structured emissions from CO2, H2O and CO

An optical Fourier transform coprocessor with direct phase determination.

PubMed

Macfaden, Alexander J; Gordon, George S D; Wilkinson, Timothy D

2017-10-20

The Fourier transform is a ubiquitous mathematical operation which arises naturally in optics. We propose and demonstrate a practical method to optically evaluate a complex-to-complex discrete Fourier transform. By implementing the Fourier transform optically we can overcome the limiting O(nlogn) complexity of fast Fourier transform algorithms. Efficiently extracting the phase from the well-known optical Fourier transform is challenging. By appropriately decomposing the input and exploiting symmetries of the Fourier transform we are able to determine the phase directly from straightforward intensity measurements, creating an optical Fourier transform with O(n) apparent complexity. Performing larger optical Fourier transforms requires higher resolution spatial light modulators, but the execution time remains unchanged. This method could unlock the potential of the optical Fourier transform to permit 2D complex-to-complex discrete Fourier transforms with a performance that is currently untenable, with applications across information processing and computational physics.

Laboratory measurements of trace gas emissions from biomass burning of fuel types from the southeastern and southwestern United States

Treesearch

I. R. Burling; R. J. Yokelson; D. W. T. Griffith; T. J. Johnson; P. Veres; J. M. Roberts; C. Warneke; S. P. Urbanski; J. Reardon; D. R. Weise; W. M. Hao; J. de Gouw

2010-01-01

Vegetation commonly managed by prescribed burning was collected from five southeastern and southwestern US military bases and burned under controlled conditions at the US Forest Service Fire Sciences Laboratory in Missoula, Montana. The smoke emissions were measured with a large suite of state-of-the-art instrumentation including an open-path Fourier transform infrared...

Noninterferometric Two-Dimensional Fourier-Transform Spectroscopy of Multilevel Systems

NASA Astrophysics Data System (ADS)

Davis, J. A.; Dao, L. V.; Do, M. T.; Hannaford, P.; Nugent, K. A.; Quiney, H. M.

2008-06-01

We demonstrate a technique that determines the phase of the photon-echo emission from spectrally resolved intensity data without requiring phase-stabilized input pulses. The full complex polarization of the emission is determined from spectral intensity measurements. The validity of this technique is demonstrated using simulated data, and is then applied to the analysis of two-color data obtained from the light-harvesting molecule lycopene.

Implementation of quantum and classical discrete fractional Fourier transforms.

PubMed

Weimann, Steffen; Perez-Leija, Armando; Lebugle, Maxime; Keil, Robert; Tichy, Malte; Gräfe, Markus; Heilmann, René; Nolte, Stefan; Moya-Cessa, Hector; Weihs, Gregor; Christodoulides, Demetrios N; Szameit, Alexander

2016-03-23

Fourier transforms, integer and fractional, are ubiquitous mathematical tools in basic and applied science. Certainly, since the ordinary Fourier transform is merely a particular case of a continuous set of fractional Fourier domains, every property and application of the ordinary Fourier transform becomes a special case of the fractional Fourier transform. Despite the great practical importance of the discrete Fourier transform, implementation of fractional orders of the corresponding discrete operation has been elusive. Here we report classical and quantum optical realizations of the discrete fractional Fourier transform. In the context of classical optics, we implement discrete fractional Fourier transforms of exemplary wave functions and experimentally demonstrate the shift theorem. Moreover, we apply this approach in the quantum realm to Fourier transform separable and path-entangled biphoton wave functions. The proposed approach is versatile and could find applications in various fields where Fourier transforms are essential tools.

Implementation of quantum and classical discrete fractional Fourier transforms

PubMed Central

Weimann, Steffen; Perez-Leija, Armando; Lebugle, Maxime; Keil, Robert; Tichy, Malte; Gräfe, Markus; Heilmann, René; Nolte, Stefan; Moya-Cessa, Hector; Weihs, Gregor; Christodoulides, Demetrios N.; Szameit, Alexander

2016-01-01

Fourier transforms, integer and fractional, are ubiquitous mathematical tools in basic and applied science. Certainly, since the ordinary Fourier transform is merely a particular case of a continuous set of fractional Fourier domains, every property and application of the ordinary Fourier transform becomes a special case of the fractional Fourier transform. Despite the great practical importance of the discrete Fourier transform, implementation of fractional orders of the corresponding discrete operation has been elusive. Here we report classical and quantum optical realizations of the discrete fractional Fourier transform. In the context of classical optics, we implement discrete fractional Fourier transforms of exemplary wave functions and experimentally demonstrate the shift theorem. Moreover, we apply this approach in the quantum realm to Fourier transform separable and path-entangled biphoton wave functions. The proposed approach is versatile and could find applications in various fields where Fourier transforms are essential tools. PMID:27006089

A Unified Method of Finding Laplace Transforms, Fourier Transforms, and Fourier Series. [and] An Inversion Method for Laplace Transforms, Fourier Transforms, and Fourier Series. Integral Transforms and Series Expansions. Modules and Monographs in Undergraduate Mathematics and Its Applications Project. UMAP Units 324 and 325.

ERIC Educational Resources Information Center

Grimm, C. A.

This document contains two units that examine integral transforms and series expansions. In the first module, the user is expected to learn how to use the unified method presented to obtain Laplace transforms, Fourier transforms, complex Fourier series, real Fourier series, and half-range sine series for given piecewise continuous functions. In…

Fluorescence lifetime imaging and Fourier transform infrared spectroscopy of Michelangelo's David.

PubMed

Comelli, Daniela; Valentini, Gianluca; Cubeddu, Rinaldo; Toniolo, Lucia

2005-09-01

We developed a combined procedure for the analysis of works of art based on a portable system for fluorescence imaging integrated with analytical measurements on microsamples. The method allows us to localize and identify organic and inorganic compounds present on the surface of artworks. The fluorescence apparatus measures the temporal and spectral features of the fluorescence emission, excited by ultraviolet (UV) laser pulses. The kinetic of the emission is studied through a fluorescence lifetime imaging system, while an optical multichannel analyzer measures the fluorescence spectra of selected points. The chemical characterization of the compounds present on the artistic surfaces is then performed by means of analytical measurements on microsamples collected with the assistance of the fluorescence maps. The previous concepts have been successfully applied to study the contaminants on the surface of Michelangelo's David. The fluorescence analysis combined with Fourier transform infrared (FT-IR) measurements revealed the presence of beeswax, which permeates most of the statue surface, and calcium oxalate deposits mainly arranged in vertical patterns and related to rain washing.

Fourier transform emission spectroscopy of the F4Δ- X4Φ system of TiF

NASA Astrophysics Data System (ADS)

Ram, R. S.; Bernath, P. F.

2005-06-01

The emission spectra of TiF have been reinvestigated in the 4200-15 000 cm -1 region using the Fourier transform spectrometer associated with the National Solar Observatory at Kitt Peak. TiF was formed in a microwave discharge lamp operated with 2.5 Torr of He and a trace of TiF 4 vapor, and the spectra were recorded at a resolution of 0.02 cm -1. The TiF bands observed in the 12 000-14 000 cm -1 region have been assigned to a new transition, F4Δ- X4Φ. Each band consists of four sub-bands assigned as, 4Δ 1/2- 4Φ 3/2, 4Δ 3/2- 4Φ 5/2, 4Δ 5/2- 4Φ 7/2, and 4Δ 7/2- 4Φ 9/2. A rotational analysis of the 0-1, 0-0, and 1-0 bands has been obtained and spectroscopic constants have been extracted.

Characterization of near-terahertz complementary metal-oxide semiconductor circuits using a Fourier-transform interferometer

DOE PAGES

Arenas, D. J.; Shim, Dongha; Koukis, D. I.; ...

2011-10-24

Optical methods for measuring of the emission spectra of oscillator circuits operating in the 400-600 GHz range are described. The emitted power from patch antennas included in the circuits is measured by placing the circuit in the source chamber of a Fourier-transform interferometric spectrometer. The results show that this optical technique is useful for measuring circuits pushing the frontier in operating frequency. The technique also allows the characterization of the circuit by measuring the power radiated in the fundamental and in the harmonics. This capability is useful for oscillator architectures designed to cancel the fundamental and use higher harmonics. Themore » radiated power was measured using two techniques: direct measurement of the power by placing the device in front of a bolometer of known responsivity, and by comparison to the estimated power from blackbody sources. The latter technique showed that these circuits have higher emission than blackbody sources at the operating frequencies, and, therefore, offer potential spectroscopy applications.« less

An alternative path to the boundary: The CFT as the Fourier space of AdS

NASA Astrophysics Data System (ADS)

Tolfree, Ian M.

2009-12-01

In this thesis we shed new light on the conjectured duality between an n + 1 dimensional theory of gravity in anti de Sitter space (AdS) and an n dimensional conformal field theory (CFT) by showing that the CFT can be interpreted as the Fourier space of AdS. We then make use of this to gain insight into the nature of black hole entropy. In the first part of this thesis, we give an introduction to the ideas of and review the basics of the AdS/CFT. In the next section we make use of well known integral geometry techniques to derive the Fourier transformation of a function on AdS and see it is a function with compact support on the boundary. Comparing this to the literature, we find that the Green's functions from the literature are actually the Fourier weights of the transformation and that the boundary values of fields appearing in the correspondence are the Fourier coefficients of the transformation. One is thus left to interpret the CFT as the quantized version of a classical theory in AdS and the dual operator as the Fourier coefficients. Group theoretic considerations are discussed in relation to the transformation and its potential use in constructing QCD like theories. In the last section, we then build upon this to study the BTZ black hole. Named after its authors, Banados, Teitelboim and Zanelli, the BTZ black hole is a three dimensional (two space plus one time dimension) black hole in anti de Sitter space. Following standard procedures for modifying Fourier Transformations to accommodate quotient spaces we arrive at a mapping in a black hole background consistent with known results that yields the exact micro-states of a scalar field in a black hole background. We find that the micro-states are the Fourier coefficients on the boundary, which transform under the principal series representation of SL(2, R). Using the knowledge of how to represent a bulk scalar field in the CFT, and knowing how a black hole interacts with a scalar field, we deduce the possible representations of a black hole in the CFT. We find that the black hole micro-states live on the boundary, not on the horizon, and correspond to the possible emission modes of the black hole.

Improving land surface emissivty parameter for land surface models using portable FTIR and remote sensing observation in Taklimakan Desert

NASA Astrophysics Data System (ADS)

Liu, Yongqiang; Mamtimin, Ali; He, Qing

2014-05-01

Because land surface emissivity (ɛ) has not been reliably measured, global climate model (GCM) land surface schemes conventionally set this parameter as simply assumption, for example, 1 as in the National Oceanic and Atmospheric Administration (NOAA) National Centers for Environmental Prediction (NCEP) model, 0.96 for soil and wetland in the Global and Regional Assimilation and Prediction System (GRAPES) Common Land Model (CoLM). This is the so-called emissivity assumption. Accurate broadband emissivity data are needed as model inputs to better simulate the land surface climate. It is demonstrated in this paper that the assumption of the emissivity induces errors in modeling the surface energy budget over Taklimakan Desert where ɛ is far smaller than original value. One feasible solution to this problem is to apply the accurate broadband emissivity into land surface models. The Moderate Resolution Imaging Spectroradiometer (MODIS) instrument has routinely measured spectral emissivities in six thermal infrared bands. The empirical regression equations have been developed in this study to convert these spectral emissivities to broadband emissivity required by land surface models. In order to calibrate the regression equations, using a portable Fourier Transform infrared (FTIR) spectrometer instrument, crossing Taklimakan Desert along with highway from north to south, to measure the accurate broadband emissivity. The observed emissivity data show broadband ɛ around 0.89-0.92. To examine the impact of improved ɛ to radiative energy redistribution, simulation studies were conducted using offline CoLM. The results illustrate that large impacts of surface ɛ occur over desert, with changes up in surface skin temperature, as well as evident changes in sensible heat fluxes. Keywords: Taklimakan Desert, surface broadband emissivity, Fourier Transform infrared spectrometer, MODIS, CoLM

THE CHALLENGE OF QUALITY ASSURANCE FOR EMISSION FLUX MEASUREMENTS OF LARGE AREA SOURCES BY OPTICAL REMOTE SENSING

EPA Science Inventory

The paper examines the quality assurance challenges associated with open path Fourier transform infrared (OPFTIR) measurements of large area pollution sources with plume reconstruction by computed tomography (CT) and how each challenge may be met. Traditionally, pollutant concent...

Synthesis, characterization, in vitro anti-proliferative and hemolytic activity of hydroxyapatite

NASA Astrophysics Data System (ADS)

Palanivelu, R.; Ruban Kumar, A.

2014-06-01

Hydroxyapatite (Ca10(PO4)6(OH)2, HAP) nanoparticles are widely used in several biomedical applications due to its compositional similarities to bone mineral, excellent biocompatibility and bioactivity, osteoconductivity. In this present investigation, HAP nanoparticles synthesized by precipitation technique using calcium nitrate and di-ammonium phosphate. The crystalline nature and the functional group analysis are confirmed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and Fourier transform Raman spectroscopy (FT-Raman) respectively. The morphological observations are ascertained from field emission electron scanning electron microscope (FE-SEM) and transmission electron microscope (TEM). In vitro anti-proliferative and hemolytic activities are carried out on the synthesized HAP samples and the studies reveals that HAP have mild activity against erythrocytes.

Solar radiometry at millimeter wavelengths. [Fast Fourier Transformation solutions

NASA Technical Reports Server (NTRS)

Henze, W.

1974-01-01

In the area of resolution enhancement, the use of Fast Fourier Transform programs was investigated for possible application to millimeter wavelength maps of the sun. A difficulty arises with the La Posta maps in that they are limited to 35 arc-minutes square while the smeared out solar image is larger than that. A list of possible cometary emission lines near 13 millimeters is presented. Although preparation of the list was inspired by the appearance of Comet Kohoutek, the results are applicable to any future comet. The brightness temperature of the sun at 8.6 millimeters was measured using the moon as a calibration source. The result does not confirm a deep absorption feature as apparently observed by earlier workers.

Concerning the Spatial Heterodyne Spectrometer

DOE PAGES

Lenzner, Matthias; Diels, Jean -Claude

2016-01-22

A modified Spatial Heterodyne Spectrometer (SHS) is used for measuring atomic emission spectra with high resolution. This device is basically a Fourier Transform Spectrometer, but the Fourier transform is taken in the directions perpendicular to the optical propagation and heterodyned around one preset wavelength. In recent descriptions of this device, one specific phenomenon - the tilt of the energy front of wave packets when diffracted from a grating - was neglected. This led to an overestimate of the resolving power of this spectrograph, especially in situations when the coherence length of the radiation under test is in the order ofmore » the effective aperture of the device. In conclusion, the limits of usability are shown here together with some measurements of known spectral lines.« less

Emission computerized axial tomography from multiple gamma-camera views using frequency filtering.

PubMed

Pelletier, J L; Milan, C; Touzery, C; Coitoux, P; Gailliard, P; Budinger, T F

1980-01-01

Emission computerized axial tomography is achievable in any nuclear medicine department from multiple gamma camera views. Data are collected by rotating the patient in front of the camera. A simple fast algorithm is implemented, known as the convolution technique: first the projection data are Fourier transformed and then an original filter designed for optimizing resolution and noise suppression is applied; finally the inverse transform of the latter operation is back-projected. This program, which can also take into account the attenuation for single photon events, was executed with good results on phantoms and patients. We think that it can be easily implemented for specific diagnostic problems.

USING TUNABLE DIODE LASERS TO MEASURE EMISSIONS FROM ANIMAL HOUSING AND WASTE LAGOONS

EPA Science Inventory

Open-path optical spectroscopy has been applied to several fugitive sources by scientists at the EPA National Risk Management Research Laboratory for more than a decade. Open-path Fourier transform infrared (OP-FTIR) was used during the initial research phase because of the abil...

FIELD EVALUATION OF A METHOD FOR ESTIMATING GASEOUS FLUXES FROM AREA SOURCES USING OPEN-PATH FOURIER TRANSFORM INFRARED

EPA Science Inventory

The paper describes preliminary results from a field experiment designed to evaluate a new approach to quantifying gaseous fugitive emissions from area air pollution sources. The new approach combines path-integrated concentration data acquired with any path-integrated optical re...

Nondestructive online testing method for friction stir welding using acoustic emission

NASA Astrophysics Data System (ADS)

Levikhina, Anastasiya

2017-12-01

The paper reviews the possibility of applying the method of acoustic emission for online monitoring of the friction stir welding process. It is shown that acoustic emission allows the detection of weld defects and their location in real time. The energy of an acoustic signal and the median frequency are suggested to be used as informative parameters. The method of calculating the median frequency with the use of a short time Fourier transform is applied for the identification of correlations between the defective weld structure and properties of the acoustic emission signals received during welding.

Fugitive coke oven gas emission profile by continuous line averaged open-path Fourier transform infrared monitoring.

PubMed

Lin, Chitsan; Liou, Naiwei; Chang, Pao-Erh; Yang, Jen-Chin; Sun, Endy

2007-04-01

Although most coke oven research is focused on the emission of polycyclic aromatic hydrocarbons, well-known carcinogens, little has been done on the emission of volatile organic compounds, some of which are also thought to be hazardous to workers and the environment. To profile coke oven gas (COG) emissions, we set up an open-path Fourier transform infrared (OP-FTIR) system on top of a battery of coke ovens at a steel mill located in Southern Taiwan and monitored average emissions in a coke processing area for 16.5 hr. Nine COGs were identified, including ammonia, CO, methane, ethane, ethylene, acetylene, propylene, cyclohexane, and O-xylene. Time series plots indicated that the type of pollutants differed over time, suggesting that different emission sources (e.g., coke pushing, quench tower, etc.) were involved at different times over the study period. This observation was confirmed by the low cross-correlation coefficients of the COGs. It was also found that, with the help of meteorological analysis, the data collected by the OP-FTIR system could be analyzed effectively to characterize differences in the location of sources. Although the traditional single-point samplings of emissions involves sampling various sources in a coke processing area at several different times and is a credible profiling of emissions, our findings strongly suggest that they are not nearly as efficient or as cost-effective as the continuous line average method used in this study. This method would make it easier and cheaper for engineers and health risk assessors to identify and to control fugitive volatile organic compound emissions and to improve environmental health.

Compact Microwave Fourier Spectrum Analyzer

NASA Technical Reports Server (NTRS)

Savchenkov, Anatoliy; Matsko, Andrey; Strekalov, Dmitry

2009-01-01

A compact photonic microwave Fourier spectrum analyzer [a Fourier-transform microwave spectrometer, (FTMWS)] with no moving parts has been proposed for use in remote sensing of weak, natural microwave emissions from the surfaces and atmospheres of planets to enable remote analysis and determination of chemical composition and abundances of critical molecular constituents in space. The instrument is based on a Bessel beam (light modes with non-zero angular momenta) fiber-optic elements. It features low power consumption, low mass, and high resolution, without a need for any cryogenics, beyond what is achievable by the current state-of-the-art in space instruments. The instrument can also be used in a wide-band scatterometer mode in active radar systems.

Fourier Plane Image Combination by Feathering

NASA Astrophysics Data System (ADS)

Cotton, W. D.

2017-09-01

Astronomical objects frequently exhibit structure over a wide range of scales whereas many telescopes, especially interferometer arrays, only sample a limited range of spatial scales. To properly image these objects, images from a set of instruments covering the range of scales may be needed. These images then must be combined in a manner to recover all spatial scales. This paper describes the feathering technique for image combination in the Fourier transform plane. Implementations in several packages are discussed and example combinations of single dish and interferometric observations of both simulated and celestial radio emission are given.

A Short Biography of Joseph Fourier and Historical Development of Fourier Series and Fourier Transforms

ERIC Educational Resources Information Center

Debnath, Lokenath

2012-01-01

This article deals with a brief biographical sketch of Joseph Fourier, his first celebrated work on analytical theory of heat, his first great discovery of Fourier series and Fourier transforms. Included is a historical development of Fourier series and Fourier transforms with their properties, importance and applications. Special emphasis is made…

Extracting Micro-Doppler Radar Signatures from Rotating Targets Using Fourier-Bessel Transform and Time-Frequency Analysis

DTIC Science & Technology

2014-10-16

Time-Frequency analysis, Short-Time Fourier Transform, Wigner Ville Distribution, Fourier Bessel Transform, Fractional Fourier Transform. I...INTRODUCTION Most widely used time-frequency transforms are short-time Fourier Transform (STFT) and Wigner Ville distribution (WVD). In STFT, time and...frequency resolutions are limited by the size of window function used in calculating STFT. For mono-component signals, WVD gives the best time and frequency

Synthesis, characterization, in vitro anti-proliferative and hemolytic activity of hydroxyapatite.

PubMed

Palanivelu, R; Ruban Kumar, A

2014-06-05

Hydroxyapatite (Ca10(PO4)6(OH)2, HAP) nanoparticles are widely used in several biomedical applications due to its compositional similarities to bone mineral, excellent biocompatibility and bioactivity, osteoconductivity. In this present investigation, HAP nanoparticles synthesized by precipitation technique using calcium nitrate and di-ammonium phosphate. The crystalline nature and the functional group analysis are confirmed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and Fourier transform Raman spectroscopy (FT-Raman) respectively. The morphological observations are ascertained from field emission electron scanning electron microscope (FE-SEM) and transmission electron microscope (TEM). In vitro anti-proliferative and hemolytic activities are carried out on the synthesized HAP samples and the studies reveals that HAP have mild activity against erythrocytes. Copyright © 2014 Elsevier B.V. All rights reserved.

High-resolution Fourier transform spectroscopy of the Meinel system of OH

NASA Technical Reports Server (NTRS)

Abrams, Mark C.; Davis, Sumner P.; Rao, M. L. P.; Engleman, Rolf, Jr.; Brault, James W.

1994-01-01

The infrared spectrum of the hydroxyl radical OH, between 1850 and 9000/cm has been measured with a Fourier transform spectrometer. The source, a hydrogen-ozone diffusion flame, was designed to study the excitation of rotation-vibration levels of the OH Meinel bands under conditions similar to those in the upper atmosphere which produce the nighttime OH airglow emission. Twenty-three bands were observed: nine bands in the Delta upsilon = 1 sequence, nine bands in the Delta upsilon = 2 sequence, and five bands in the Delta upsilon = 3 sequence. A global nonlinear least-squares fit of 1696 lines yielded molecular parameters with a standard deviation of 0.003/cm. Term values are computed, and transition frequencies in the Delta upsilon = 3, 4, 5, 6 sequences in the near-infrared are predicted.

Rovibrational intensities and electric dipole moment function of the X2 Pi hydroxyl radical

NASA Technical Reports Server (NTRS)

Chackerian, C., Jr.; Goorvitch, D.; Benidar, A.; Farrenq, R.; Guelachvili, G.; Martin, P. M.; Abrams, M. C.; Davis, S. P.

1992-01-01

Recent work aimed at determining the absolute rovibrational transition intensities for the ground electronic state of the hydroxyl radical is reviewed. Two new sets of Fourier transform emission spectra of OH are described which were recorded at the University of Paris and at the Kitt Peak National Solar Observatory.

Bringing a needle to a laser fight: comparing greenhouse gas sampling methods with gas chromatography and fourier transform infrared spectroscopy

USDA-ARS?s Scientific Manuscript database

As scientists, producers, policymakers, and the general public become more concerned about impacts of climate change, there is an increasing need to understand and quantify greenhouse gas emissions from agricultural practices, which often feed into global, multi-institution databases. Current best p...

INNOVATIVE APPROACH FOR MEASURING AMMONIA AND METHANE FLUXES FROM A HOG FARM USING OPEN-PATH FOURIER TRANSFORM INFRARED SPECTROSCOPY

EPA Science Inventory

The paper describes a new approach to quantify emissions from area air pollution sources. The approach combines path-integrated concentration data acquired with any path-integrated optical remote sensing (PI-ORS) technique and computed tomography (CT) technique. In this study, an...

SEASONAL EMISSIONS OF AMMONIA AND METHANE FROM A HOG WASTE LAGOON WITH BIOACTIVE COVER

EPA Science Inventory

The paper discusses the use of plane-integrated (PI) open-path Fourier transform infrared spectrometry (OP-FTIR) to measure the flux of ammonia and methane from a hog waste lagoon before and after the installation of a bioactive cover. A computed tomography algorithm using a smoo...

Fourier transform emission spectroscopy of the TiF radical in the 407 nm region

NASA Astrophysics Data System (ADS)

Imajo, Takashi; Kobayashi, Yuki; Nakashima, Yoshihiro; Tanaka, Keiichi; Tanaka, Takehiko

2005-04-01

Ultraviolet emission spectra of the TiF radical in the 407 nm region have been observed at a resolution of 0.04 cm -1 using a Fourier transform spectrometer. A new electronic assignment of 4Γ- X4Φ has been proposed. Rotational analysis has been obtained for the 0-0 and 1-1 vibrational bands of the 4Γ 5/2- X4Φ 3/2, 4Γ 9/2- X4Φ 7/2, and 4Γ 11/2- X4Φ 9/2 subbands and the 0-0 band of 4Γ 7/2- X4Φ 5/2. The lower state rotational and centrifugal distortion constants are consistent with the previous results [J. Mol. Spectrosc. 184 (1997) 186; J. Chem. Phys. 119 (2003) 9496], to the conformation that the lower state of the 407 nm band is the 4Φ ground electronic state. Rough estimates of the vibrational interval Δ G(1/2) and the spin-orbit coupling constant A in the 4Γ state were also obtained.

Spectroscopy of selected metal-containing diatomic molecules

NASA Astrophysics Data System (ADS)

Gordon, Iouli E.

Fourier transform infrared emission spectra of MnH and MnD were observed in the ground X7Sigma+ electronic state. The vibration-rotation bands from v = 1 → 0 to v = 3 → 2 for MnH, and from v = 1 → 0 to v = 4 → 3 for MnD were recorded at an instrumental resolution of 0.0085 cm-1. Spectroscopic constants were determined for each vibrational level and equilibrium constants were found from a Dunham-type fit. The equilibrium vibrational constant oe for MnH was found to be 1546.84518(65) cm-1, the equilibrium rotational constant Be was found to be 5.6856789(103) cm-1 and the equilibrium bond distance re was determined to be 1.7308601(47) A. New high resolution emission spectra of CoH and CoD molecules have been recorded in the 640 nm to 3.5 mum region using a Fourier transform spectrometer. Many bands were observed for the A'3phi- X3phi electronic transition of CoH and CoD. In addition, a new [13.3]4 electronic state was found by observing the [13.3]4-X3phi3 and [13.3]4- X3phi4 transitions in the spectrum of CoD. Analysis of the transitions with DeltaO = 0, +/-1 provided more accurate values of spin-orbit splittings between O = 4 and O = 3 components. The ground state for both molecules was fitted both to band and Dunham-type constants. The estimated band constants of the perturbed upper states were also obtained. The emission spectrum of gas-phase YbO has been investigated using a Fourier transform spectrometer. A total of 8 red-degraded bands in the range 9 800--11 300 cm-1 were recorded at a resolution of 0.04 cm-1. Because of the multiple isotopomers present in the spectra, only 3 bands were rotationally analyzed. Perturbations were identified in two of these bands and all 3 transitions were found to terminate at the X1Sigma+ ground electronic state. The electronic configurations that give rise to the observed states are discussed and molecular parameters for all of the analyzed bands are reported. Electronic spectra of the previously unobserved EuH and EuD molecules were studied by means of Fourier transform spectroscopy and laser-induced fluorescence. The extreme complexity of these transitions made rotational assignments of EuH bands impossible. However, the spin-spin interaction constant, lambda, and Fermi contact parameter, bF, in the ground X9Sigma- electronic state were estimated for the 151EuH and 153EuH isotopologues. Electronic spectra of SmH, SmCl, TmH and ErF molecules were recorded for the first time using Fourier transform spectrometer. The poor signal to noise ratio of the observed bands coupled with their complexity prevented a rotational analysis. The electronic states that may be involved in the observed transitions are discussed.

Spectroscopy of selected metal-containing diatomic molecules

NASA Astrophysics Data System (ADS)

Gordon, Iouli

Fourier transform infrared emission spectra of MnH and MnD were observed in the ground X7[sigma]+ electronic state. The vibration-rotation bands from v = 1 to 0 to v = 3 to 2 for MnH, and from v = 1 to 0 to v = 4 to 3 for MnD were recorded at an instrumental resolution of 0. 0085 cm-1. Spectroscopic constants were determined for each vibrational level and equilibrium constants were found from a Dunham-type fit. The equilibrium vibrational constant [omega]e for MnH was found to be 1546. 84518(65) cm-1, the equilibrium rotational constant Be was found to be 5. 6856789(103) cm-1 and the equilibrium bond distance re was determined to be 1. 7308601(47) ?. New high resolution emission spectra of CoH and CoD molecules have been recorded in the 640 nm to 3. 5 _m region using a Fourier transform spectrometer. Many bands were observed for the A'3?-X3? electronic transition of CoH and CoD. In addition, a new [13. 3]4 electronic state was found by observing the [13. 3]4- X3?3 and [13. 3]4-X3?4 transitions in the spectrum of CoD. Analysis of the transitions with [delta][omega] = 0, ?1 provided more accurate values of spin-orbit splittings between [omega] = 4 and [omega] = 3 components. The ground state for both molecules was fitted both to band and Dunham-type constants. The estimated band constants of the perturbed upper states were also obtained. The emission spectrum of gas-phase YbO has been investigated using a Fourier transform spectrometer. A total of 8 red-degraded bands in the range 9 800 ? 11 300 cm-1 were recorded at a resolution of 0. 04 cm-1. Because of the multiple isotopomers present in the spectra, only 3 bands were rotationally analyzed. Perturbations were identified in two of these bands and all 3 transitions were found to terminate at the X1[sigma]+ ground electronic state. The electronic configurations that give rise to the observed states are discussed and molecular parameters for all of the analyzed bands are reported. Electronic spectra of the previously unobserved EuH and EuD molecules were studied by means of Fourier transform spectroscopy and laser-induced fluorescence. The extreme complexity of these transitions made rotational assignments of EuH bands impossible. However, the spin-spin interaction constant, [lambda], and Fermi contact parameter, bF, in the ground X9[sigma]- electronic state were estimated for the 151EuH and 153EuH isotopologues. Electronic spectra of SmH, SmCl, TmH and ErF molecules were recorded for the first time using Fourier transform spectrometer. The poor signal to noise ratio of the observed bands coupled with their complexity prevented a rotational analysis. The electronic states that may be involved in the observed transitions are discussed.

Thermal stabilization of static single-mirror Fourier transform spectrometers

NASA Astrophysics Data System (ADS)

Schardt, Michael; Schwaller, Christian; Tremmel, Anton J.; Koch, Alexander W.

2017-05-01

Fourier transform spectroscopy has become a standard method for spectral analysis of infrared light. With this method, an interferogram is created by two beam interference which is subsequently Fourier-transformed. Most Fourier transform spectrometers used today provide the interferogram in the temporal domain. In contrast, static Fourier transform spectrometers generate interferograms in the spatial domain. One example of this type of spectrometer is the static single-mirror Fourier transform spectrometer which offers a high etendue in combination with a simple, miniaturized optics design. As no moving parts are required, it also features a high vibration resistance and high measurement rates. However, it is susceptible to temperature variations. In this paper, we therefore discuss the main sources for temperature-induced errors in static single-mirror Fourier transform spectrometers: changes in the refractive index of the optical components used, variations of the detector sensitivity, and thermal expansion of the housing. As these errors manifest themselves in temperature-dependent wavenumber shifts and intensity shifts, they prevent static single-mirror Fourier transform spectrometers from delivering long-term stable spectra. To eliminate these shifts, we additionally present a work concept for the thermal stabilization of the spectrometer. With this stabilization, static single-mirror Fourier transform spectrometers are made suitable for infrared process spectroscopy under harsh thermal environmental conditions. As the static single-mirror Fourier transform spectrometer uses the so-called source-doubling principle, many of the mentioned findings are transferable to other designs of static Fourier transform spectrometers based on the same principle.

Airborne measurements in the infrared using FTIR-based imaging hyperspectral sensors

NASA Astrophysics Data System (ADS)

Puckrin, E.; Turcotte, C. S.; Lahaie, P.; Dubé, D.; Lagueux, P.; Farley, V.; Marcotte, F.; Chamberland, M.

2009-09-01

Hyperspectral ground mapping is being used in an ever-increasing extent for numerous applications in the military, geology and environmental fields. The different regions of the electromagnetic spectrum help produce information of differing nature. The visible, near-infrared and short-wave infrared radiation (400 nm to 2.5 μm) has been mostly used to analyze reflected solar light, while the mid-wave (3 to 5 μm) and long-wave (8 to 12 μm or thermal) infrared senses the self-emission of molecules directly, enabling the acquisition of data during night time. Push-broom dispersive sensors have been typically used for airborne hyperspectral mapping. However, extending the spectral range towards the mid-wave and long-wave infrared brings performance limitations due to the self emission of the sensor itself. The Fourier-transform spectrometer technology has been extensively used in the infrared spectral range due to its high transmittance as well as throughput and multiplex advantages, thereby reducing the sensor self-emission problem. Telops has developed the Hyper-Cam, a rugged and compact infrared hyperspectral imager. The Hyper-Cam is based on the Fourier-transform technology yielding high spectral resolution and enabling high accuracy radiometric calibration. It provides passive signature measurement capability, with up to 320x256 pixels at spectral resolutions of up to 0.25 cm-1. The Hyper-Cam has been used on the ground in several field campaigns, including the demonstration of standoff chemical agent detection. More recently, the Hyper-Cam has been integrated into an airplane to provide airborne measurement capabilities. A special pointing module was designed to compensate for airplane attitude and forward motion. To our knowledge, the Hyper-Cam is the first commercial airborne hyperspectral imaging sensor based on Fourier-transform infrared technology. The first airborne measurements and some preliminary performance criteria for the Hyper-Cam are presented in this paper.

Airborne measurements in the infrared using FTIR-based imaging hyperspectral sensors

NASA Astrophysics Data System (ADS)

Puckrin, E.; Turcotte, C. S.; Lahaie, P.; Dubé, D.; Farley, V.; Lagueux, P.; Marcotte, F.; Chamberland, M.

2009-05-01

Hyperspectral ground mapping is being used in an ever-increasing extent for numerous applications in the military, geology and environmental fields. The different regions of the electromagnetic spectrum help produce information of differing nature. The visible, near-infrared and short-wave infrared radiation (400 nm to 2.5 μm) has been mostly used to analyze reflected solar light, while the mid-wave (3 to 5 μm) and long-wave (8 to 12 μm or thermal) infrared senses the self-emission of molecules directly, enabling the acquisition of data during night time. Push-broom dispersive sensors have been typically used for airborne hyperspectral mapping. However, extending the spectral range towards the mid-wave and long-wave infrared brings performance limitations due to the self emission of the sensor itself. The Fourier-transform spectrometer technology has been extensively used in the infrared spectral range due to its high transmittance as well as throughput and multiplex advantages, thereby reducing the sensor self-emission problem. Telops has developed the Hyper-Cam, a rugged and compact infrared hyperspectral imager. The Hyper-Cam is based on the Fourier-transform technology yielding high spectral resolution and enabling high accuracy radiometric calibration. It provides passive signature measurement capability, with up to 320x256 pixels at spectral resolutions of up to 0.25 cm-1. The Hyper-Cam has been used on the ground in several field campaigns, including the demonstration of standoff chemical agent detection. More recently, the Hyper-Cam has been integrated into an airplane to provide airborne measurement capabilities. A special pointing module was designed to compensate for airplane attitude and forward motion. To our knowledge, the Hyper-Cam is the first commercial airborne hyperspectral imaging sensor based on Fourier-transform infrared technology. The first airborne measurements and some preliminary performance criteria for the Hyper-Cam are presented in this paper.

The Fourier analysis of biological transients.

PubMed

Harris, C M

1998-08-31

With modern computing technology the digital implementation of the Fourier transform is widely available, mostly in the form of the fast Fourier transform (FFT). Although the FFT has become almost synonymous with the Fourier transform, it is a fast numerical technique for computing the discrete Fourier transform (DFT) of a finite sequence of sampled data. The DFT is not directly equivalent to the continuous Fourier transform of the underlying biological signal, which becomes important when analyzing biological transients. Although this distinction is well known by some, for many it leads to confusion in how to interpret the FFT of biological data, and in how to precondition data so as to yield a more accurate Fourier transform using the FFT. We review here the fundamentals of Fourier analysis with emphasis on the analysis of transient signals. As an example of a transient, we consider the human saccade to illustrate the pitfalls and advantages of various Fourier analyses.

Fourier transform magnitudes are unique pattern recognition templates.

PubMed

Gardenier, P H; McCallum, B C; Bates, R H

1986-01-01

Fourier transform magnitudes are commonly used in the generation of templates in pattern recognition applications. We report on recent advances in Fourier phase retrieval which are relevant to pattern recognition. We emphasise in particular that the intrinsic form of a finite, positive image is, in general, uniquely related to the magnitude of its Fourier transform. We state conditions under which the Fourier phase can be reconstructed from samples of the Fourier magnitude, and describe a method of achieving this. Computational examples of restoration of Fourier phase (and hence, by Fourier transformation, the intrinsic form of the image) from samples of the Fourier magnitude are also presented.

H + O3 Fourier-transform infrared emission and laser absorption studies of OH(X2Pi) radical - An experimental dipole moment function and state-to-state Einstein A coefficients

NASA Technical Reports Server (NTRS)

Nelson, David D., Jr.; Schiffman, Aram; Nesbitt, David J.; Orlando, John J.; Burkholder, James B.

1990-01-01

FTIR emission/absorption spectroscopy is used to measure the relative intensities of 88 pairs of rovibrational transitions of OH(X2Pi) distributed over 16 vibrational bands. The experimental technique used to obtain the Einstein A ratios is discussed. The dipole moment function which follows from the intensity ratios along with Einstein A coefficients calculated from mu(r) is presented.

Reducing aberration effect of Fourier transform lens by modifying Fourier spectrum of diffractive optical element in beam shaping optical system.

PubMed

Zhang, Fang; Zhu, Jing; Song, Qiang; Yue, Weirui; Liu, Jingdan; Wang, Jian; Situ, Guohai; Huang, Huijie

2015-10-20

In general, Fourier transform lenses are considered as ideal in the design algorithms of diffractive optical elements (DOEs). However, the inherent aberrations of a real Fourier transform lens disturb the far field pattern. The difference between the generated pattern and the expected design will impact the system performance. Therefore, a method for modifying the Fourier spectrum of DOEs without introducing other optical elements to reduce the aberration effect of the Fourier transform lens is proposed. By applying this method, beam shaping performance is improved markedly for the optical system with a real Fourier transform lens. The experiments carried out with a commercial Fourier transform lens give evidence for this method. The method is capable of reducing the system complexity as well as improving its performance.

Fractional finite Fourier transform.

PubMed

Khare, Kedar; George, Nicholas

2004-07-01

We show that a fractional version of the finite Fourier transform may be defined by using prolate spheroidal wave functions of order zero. The transform is linear and additive in its index and asymptotically goes over to Namias's definition of the fractional Fourier transform. As a special case of this definition, it is shown that the finite Fourier transform may be inverted by using information over a finite range of frequencies in Fourier space, the inversion being sensitive to noise. Numerical illustrations for both forward (fractional) and inverse finite transforms are provided.

Airborne interferometer for atmospheric emission and solar absorption.

PubMed

Keith, D W; Dykema, J A; Hu, H; Lapson, L; Anderson, J G

2001-10-20

The interferometer for emission and solar absorption (INTESA) is an infrared spectrometer designed to study radiative transfer in the troposphere and lower stratosphere from a NASA ER-2 aircraft. The Fourier-transform spectrometer (FTS) operates from 0.7 to 50 mum with a resolution of 0.7 cm(-1). The FTS observes atmospheric thermal emission from multiple angles above and below the aircraft. A heliostat permits measurement of solar absorption spectra. INTESA's calibration system includes three blackbodies to permit in-flight assessment of radiometric error. Results suggest that the in-flight radiometric accuracy is ~0.5 K in the mid-infrared.

Topics In Chemical Instrumentation: Fourier Transformations for Chemists Part I. Introduction to the Fourier Transform.

ERIC Educational Resources Information Center

Glasser, L.

1987-01-01

This paper explores how Fourier Transform (FT) mimics spectral transformation, how this property can be exploited to advantage in spectroscopy, and how the FT can be used in data treatment. A table displays a number of important FT serial/spectral pairs related by Fourier Transformations. A bibliography and listing of computer software related to…

Using Extractive FTIR to Measure N2O from Medium Heavy Duty Vehicles Powered with Diesel and Biodiesel Fuels

EPA Science Inventory

A Fourier Transform Infrared (FTIR) spectrometer was used to measure N2O and other pollutant gases during an evaluation of two medium heavy-duty diesel trucks equipped with a Diesel Particulate Filter (DPF). The emissions of these trucks were characterized under a variety of oper...

Study of Lamb Waves for Non-Destructive Testing Behind Screens

NASA Astrophysics Data System (ADS)

Kauffmann, P.; Ploix, M.-A.; Chaix, J.-F.; Gueudré, C.; Corneloup, G.; Baqué, F. AF(; )

2018-01-01

The inspection and control of sodium-cooled fast reactors (SFR) is a major issue for the nuclear industry. Ultrasonic solutions are under study because of the opacity of liquid sodium. In this paper, the use of leaky Lamb waves is considered for non-destructive testing (NDT) on parallel and immersed structures assimilated as plates. The first phase of our approach involved studying the propagation properties of leaky Lamb waves. Equations that model the propagation of Lamb waves in an immersed plate were solved numerically. The phase velocity can be experimentally measured using a two dimensional Fourier transform. The group velocity can be experimentally measured using a short-time Fourier transform technique. Attenuation of leaky Lamb waves is mostly due to the re-emission of energy into the surrounding fluid, and it can be measured by these two techniques.

Experimental geometry for simultaneous beam characterization and sample imaging allowing for pink beam Fourier transform holography or coherent diffractive imaging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flewett, Samuel; Eisebitt, Stefan

2011-02-20

One consequence of the self-amplified stimulated emission process used to generate x rays in free electron lasers (FELs) is the intrinsic shot-to-shot variance in the wavelength and temporal coherence. In order to optimize the results from diffractive imaging experiments at FEL sources, it will be advantageous to acquire a means of collecting coherence and spectral information simultaneously with the diffraction pattern from the sample we wish to study. We present a holographic mask geometry, including a grating structure, which can be used to extract both temporal and spatial coherence information alongside the sample scatter from each individual FEL shot andmore » also allows for the real space reconstruction of the sample using either Fourier transform holography or iterative phase retrieval.« less

Computationally efficient method for Fourier transform of highly chirped pulses for laser and parametric amplifier modeling.

PubMed

Andrianov, Alexey; Szabo, Aron; Sergeev, Alexander; Kim, Arkady; Chvykov, Vladimir; Kalashnikov, Mikhail

2016-11-14

We developed an improved approach to calculate the Fourier transform of signals with arbitrary large quadratic phase which can be efficiently implemented in numerical simulations utilizing Fast Fourier transform. The proposed algorithm significantly reduces the computational cost of Fourier transform of a highly chirped and stretched pulse by splitting it into two separate transforms of almost transform limited pulses, thereby reducing the required grid size roughly by a factor of the pulse stretching. The application of our improved Fourier transform algorithm in the split-step method for numerical modeling of CPA and OPCPA shows excellent agreement with standard algorithms.

A Fourier transform method for Vsin i estimations under nonlinear Limb-Darkening laws

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levenhagen, R. S., E-mail: ronaldo.levenhagen@gmail.com

Star rotation offers us a large horizon for the study of many important physical issues pertaining to stellar evolution. Currently, four methods are widely used to infer rotation velocities, namely those related to line width calibrations, on the fitting of synthetic spectra, interferometry, and on Fourier transforms (FTs) of line profiles. Almost all of the estimations of stellar projected rotation velocities using the Fourier method in the literature have been addressed with the use of linear limb-darkening (LD) approximations during the evaluation of rotation profiles and their cosine FTs, which in certain cases, lead to discrepant velocity estimates. In thismore » work, we introduce new mathematical expressions of rotation profiles and their Fourier cosine transforms assuming three nonlinear LD laws—quadratic, square-root, and logarithmic—and study their applications with and without gravity-darkening (GD) and geometrical flattening (GF) effects. Through an analysis of He I models in the visible range accounting for both limb and GD, we find out that, for classical models without rotationally driven effects, all the Vsin i values are too close to each other. On the other hand, taking into account GD and GF, the Vsin i obtained with the linear law result in Vsin i values that are systematically smaller than those obtained with the other laws. As a rule of thumb, we apply these expressions to the FT method to evaluate the projected rotation velocity of the emission B-type star Achernar (α Eri).« less

The fractional Fourier transform and applications

NASA Technical Reports Server (NTRS)

Bailey, David H.; Swarztrauber, Paul N.

1991-01-01

This paper describes the 'fractional Fourier transform', which admits computation by an algorithm that has complexity proportional to the fast Fourier transform algorithm. Whereas the discrete Fourier transform (DFT) is based on integral roots of unity e exp -2(pi)i/n, the fractional Fourier transform is based on fractional roots of unity e exp -2(pi)i(alpha), where alpha is arbitrary. The fractional Fourier transform and the corresponding fast algorithm are useful for such applications as computing DFTs of sequences with prime lengths, computing DFTs of sparse sequences, analyzing sequences with noninteger periodicities, performing high-resolution trigonometric interpolation, detecting lines in noisy images, and detecting signals with linearly drifting frequencies. In many cases, the resulting algorithms are faster by arbitrarily large factors than conventional techniques.

The τq-Fourier transform: Covariance and uniqueness

NASA Astrophysics Data System (ADS)

Kalogeropoulos, Nikolaos

2018-05-01

We propose an alternative definition for a Tsallis entropy composition-inspired Fourier transform, which we call “τq-Fourier transform”. We comment about the underlying “covariance” on the set of algebraic fields that motivates its introduction. We see that the definition of the τq-Fourier transform is automatically invertible in the proper context. Based on recent results in Fourier analysis, it turns that the τq-Fourier transform is essentially unique under the assumption of the exchange of the point-wise product of functions with their convolution.

Hypercomplex Fourier transforms of color images.

PubMed

Ell, Todd A; Sangwine, Stephen J

2007-01-01

Fourier transforms are a fundamental tool in signal and image processing, yet, until recently, there was no definition of a Fourier transform applicable to color images in a holistic manner. In this paper, hypercomplex numbers, specifically quaternions, are used to define a Fourier transform applicable to color images. The properties of the transform are developed, and it is shown that the transform may be computed using two standard complex fast Fourier transforms. The resulting spectrum is explained in terms of familiar phase and modulus concepts, and a new concept of hypercomplex axis. A method for visualizing the spectrum using color graphics is also presented. Finally, a convolution operational formula in the spectral domain is discussed.

Causal Correlation Functions and Fourier Transforms: Application in Calculating Pressure Induced Shifts

NASA Technical Reports Server (NTRS)

Ma, Q.; Tipping, R. H.; Lavrentieva, N. N.

2012-01-01

By adopting a concept from signal processing, instead of starting from the correlation functions which are even, one considers the causal correlation functions whose Fourier transforms become complex. Their real and imaginary parts multiplied by 2 are the Fourier transforms of the original correlations and the subsequent Hilbert transforms, respectively. Thus, by taking this step one can complete the two previously needed transforms. However, to obviate performing the Cauchy principal integrations required in the Hilbert transforms is the greatest advantage. Meanwhile, because the causal correlations are well-bounded within the time domain and band limited in the frequency domain, one can replace their Fourier transforms by the discrete Fourier transforms and the latter can be carried out with the FFT algorithm. This replacement is justified by sampling theory because the Fourier transforms can be derived from the discrete Fourier transforms with the Nyquis rate without any distortions. We apply this method in calculating pressure induced shifts of H2O lines and obtain more reliable values. By comparing the calculated shifts with those in HITRAN 2008 and by screening both of them with the pair identity and the smooth variation rules, one can conclude many of shift values in HITRAN are not correct.

PASSIVELY ESTIMATING INDEX OF REFRACTION FOR SPECULAR REFLECTORS USING POLARIMETRIC HYPERSPECTRAL IMAGING

DTIC Science & Technology

2016-12-22

23 6 Band-averaged radiance image with checkerboard is shown in the upper left. The 2-D Fourier transform of the image is...red is 1) that is multiplied by the Fourier transform of the original image. The inverse Fourier transform is then taken to get the final image with...Polarization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 IFTS Imaging Fourier Transform Spectrometer

Electronic part of the optical correlation function at finite temperature: the S-matrix expansion

NASA Astrophysics Data System (ADS)

Tavares, M.; Marques, G. E.; Tejedor, C.

1998-12-01

We present an extension to finite temperature of the Mahan-Nozières-De Dominicis framework to obtain the electronic part of the current-current correlation function. Its Fourier transform gives the absorption and emission spectra of doped low-dimensional semiconductors. We show the meaning of the new finite-temperature contributions characterizing the electronic part.

Time-frequency analysis of acoustic signals in the audio-frequency range generated during Hadfield's steel friction

NASA Astrophysics Data System (ADS)

Dobrynin, S. A.; Kolubaev, E. A.; Smolin, A. Yu.; Dmitriev, A. I.; Psakhie, S. G.

2010-07-01

Time-frequency analysis of sound waves detected by a microphone during the friction of Hadfield’s steel has been performed using wavelet transform and window Fourier transform methods. This approach reveals a relationship between the appearance of quasi-periodic intensity outbursts in the acoustic response signals and the processes responsible for the formation of wear products. It is shown that the time-frequency analysis of acoustic emission in a tribosystem can be applied, along with traditional approaches, to studying features in the wear and friction process.

Fourier transform spectroscopy for future planetary missions

NASA Astrophysics Data System (ADS)

Brasunas, John C.; Hewagama, Tilak; Kolasinski, John R.; Kostiuk, Theodor

2015-11-01

Thermal-emission infrared spectroscopy is a powerful tool for exploring the composition, temperature structure, and dynamics of planetary atmospheres; and the temperature of solid surfaces. A host of Fourier transform spectrometers (FTS) such as Mariner IRIS, Voyager IRIS, and Cassini CIRS from NASA Goddard have made and continue to make important new discoveries throughout the solar system.Future FTS instruments will have to be more sensitive (when we concentrate on the colder, outer reaches of the solar system), and less massive and less power-hungry as we cope with decreasing resource allotments for future planetary science instruments. With this in mind, NASA Goddard was funded via the Planetary Instrument Definition and Development Progrem (PIDDP) to develop CIRS-lite, a smaller version of the CIRS FTS for future planetary missions. Following the initial validation of CIRS-lite operation in the laboratory, we have been acquiring atmospheric data in the 8-12 micron window at the 1.2 m telescope at the Goddard Geophysical and Astronomical Observatory (GGAO) in Greenbelt, MD. Targets so far have included Earth's atmosphere (in emission, and in absorption against the moon), and Venus.We will present the roadmap for making CIRS-lite a viable candidate for future planetary missions.

Deconvolution of Stark broadened spectra for multi-point density measurements in a flow Z-pinch

DOE PAGES

Vogman, G. V.; Shumlak, U.

2011-10-13

Stark broadened emission spectra, once separated from other broadening effects, provide a convenient non-perturbing means of making plasma density measurements. A deconvolution technique has been developed to measure plasma densities in the ZaP flow Z-pinch experiment. The ZaP experiment uses sheared flow to mitigate MHD instabilities. The pinches exhibit Stark broadened emission spectra, which are captured at 20 locations using a multi-chord spectroscopic system. Spectra that are time- and chord-integrated are well approximated by a Voigt function. The proposed method simultaneously resolves plasma electron density and ion temperature by deconvolving the spectral Voigt profile into constituent functions: a Gaussian functionmore » associated with instrument effects and Doppler broadening by temperature; and a Lorentzian function associated with Stark broadening by electron density. The method uses analytic Fourier transforms of the constituent functions to fit the Voigt profile in the Fourier domain. The method is discussed and compared to a basic least-squares fit. The Fourier transform fitting routine requires fewer fitting parameters and shows promise in being less susceptible to instrumental noise and to contamination from neighboring spectral lines. The method is evaluated and tested using simulated lines and is applied to experimental data for the 229.69 nm C III line from multiple chords to determine plasma density and temperature across the diameter of the pinch. As a result, these measurements are used to gain a better understanding of Z-pinch equilibria.« less

Deconvolution of Stark broadened spectra for multi-point density measurements in a flow Z-pinch

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vogman, G. V.; Shumlak, U.

2011-10-15

Stark broadened emission spectra, once separated from other broadening effects, provide a convenient non-perturbing means of making plasma density measurements. A deconvolution technique has been developed to measure plasma densities in the ZaP flow Z-pinch experiment. The ZaP experiment uses sheared flow to mitigate MHD instabilities. The pinches exhibit Stark broadened emission spectra, which are captured at 20 locations using a multi-chord spectroscopic system. Spectra that are time- and chord-integrated are well approximated by a Voigt function. The proposed method simultaneously resolves plasma electron density and ion temperature by deconvolving the spectral Voigt profile into constituent functions: a Gaussian functionmore » associated with instrument effects and Doppler broadening by temperature; and a Lorentzian function associated with Stark broadening by electron density. The method uses analytic Fourier transforms of the constituent functions to fit the Voigt profile in the Fourier domain. The method is discussed and compared to a basic least-squares fit. The Fourier transform fitting routine requires fewer fitting parameters and shows promise in being less susceptible to instrumental noise and to contamination from neighboring spectral lines. The method is evaluated and tested using simulated lines and is applied to experimental data for the 229.69 nm C III line from multiple chords to determine plasma density and temperature across the diameter of the pinch. These measurements are used to gain a better understanding of Z-pinch equilibria.« less

A method of power analysis based on piecewise discrete Fourier transform

NASA Astrophysics Data System (ADS)

Xin, Miaomiao; Zhang, Yanchi; Xie, Da

2018-04-01

The paper analyzes the existing feature extraction methods. The characteristics of discrete Fourier transform and piecewise aggregation approximation are analyzed. Combining with the advantages of the two methods, a new piecewise discrete Fourier transform is proposed. And the method is used to analyze the lighting power of a large customer in this paper. The time series feature maps of four different cases are compared with the original data, discrete Fourier transform, piecewise aggregation approximation and piecewise discrete Fourier transform. This new method can reflect both the overall trend of electricity change and its internal changes in electrical analysis.

Fourier transform spectroscopy for future planetary missions

NASA Astrophysics Data System (ADS)

Brasunas, John; Kolasinski, John; Kostiuk, Ted; Hewagama, Tilak

2017-01-01

Thermal-emission infrared spectroscopy is a powerful tool for exploring the composition, temperature structure, and dynamics of planetary atmospheres; and the temperature of solid surfaces. A host of Fourier transform spectrometers (FTS) such as Mariner IRIS, Voyager IRIS, and Cassini CIRS from NASA Goddard have made and continue to make important new discoveries throughout the solar system. Future FTS instruments will have to be more sensitive (when we concentrate on the colder, outer reaches of the solar system), and less massive and less power-hungry as we cope with decreasing resource allotments for future planetary science instruments. With this in mind, we have developed CIRS-lite, a smaller version of the CIRS FTS for future planetary missions. We discuss the roadmap for making CIRS-lite a viable candidate for future planetary missions, including the recent increased emphasis on ocean worlds (Europa, Encelatus, Titan) and also on smaller payloads such as CubeSats and SmallSats.

Laser and Fourier transform spectroscopy of 7Li88Sr

NASA Astrophysics Data System (ADS)

Schwanke, Erik; Knöckel, Horst; Stein, Alexander; Pashov, Asen; Ospelkaus, Silke; Tiemann, Eberhard

2017-12-01

LiSr was produced in a heat-pipe oven and its thermal emission spectrum around 9300 cm-1 was recorded by a high resolution Fourier transform spectrometer. In addition, selected lines of the spectrum of deeply bound vibrational levels of the {1}2{{{Σ }}}+ and {2}2{{{Σ }}}+ states were studied using laser excitation to facilitate the assignment of the lines. The ground state could be described for {v}{\\prime\\prime }=0 to 2, {N}{\\prime\\prime } up to 105 and the {2}2{{{Σ }}}+ state for {v}{\\prime }=0 up to {N}{\\prime }=68. For both states, Dunham coefficients, spin-rotation parameters and potential energy curves were evaluated. A coupling of the {2}2{{{Σ }}}+ state to the {1}2{{\\Pi }} state was observed, allowing a local description with Dunham coefficients of the {1}2{{\\Pi }} state and an approximate evaluation of the coupling strength.

Structural and magnetic properties of nanocrystalline NiFe2O4 thin film prepared by spray pyrolysis technique

NASA Astrophysics Data System (ADS)

Chavan, Apparao R.; Chilwar, R. R.; Shisode, M. V.; Hivrekar, Mahesh M.; Mande, V. K.; Jadhav, K. M.

2018-05-01

The nanocrystalline NiFe2O4 thin film has been prepared using a spray pyrolysis technique on glass substrate. The prepared thin film was characterized by using X-ray diffraction (XRD), Fourier transform Infrared spectroscopy (FTIR), and Field Emission-Scanning Electron Microscopy (FE-SEM) characterization techniques for the structural and microstructural analysis. The magnetic property was measured using vibrating sample magnetometer (VSM) at room temperature. X-ray diffraction studies show the formation of single phase spinel structure of the thin film. The octahedral and tetrahedral vibration in the sample was studied by Fourier transform infrared (FT-IR) spectra. Magnetic hysteresis loop was recorded for thin film at room temperature. At 15 kOe, saturation magnetization (Ms) was found to increase while coercivity (Hc) decreases with thickness of the NiFe2O4 thin film.

SYSTEMATIC EFFECTS IN POLARIZING FOURIER TRANSFORM SPECTROMETERS FOR COSMIC MICROWAVE BACKGROUND OBSERVATIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagler, Peter C.; Tucker, Gregory S.; Fixsen, Dale J.

The detection of the primordial B-mode polarization signal of the cosmic microwave background (CMB) would provide evidence for inflation. Yet as has become increasingly clear, the detection of a such a faint signal requires an instrument with both wide frequency coverage to reject foregrounds and excellent control over instrumental systematic effects. Using a polarizing Fourier transform spectrometer (FTS) for CMB observations meets both of these requirements. In this work, we present an analysis of instrumental systematic effects in polarizing FTSs, using the Primordial Inflation Explorer (PIXIE) as a worked example. We analytically solve for the most important systematic effects inherentmore » to the FTS—emissive optical components, misaligned optical components, sampling and phase errors, and spin synchronous effects—and demonstrate that residual systematic error terms after corrections will all be at the sub-nK level, well below the predicted 100 nK B-mode signal.« less

Blind third-order dispersion estimation based on fractional Fourier transformation for coherent optical communication

NASA Astrophysics Data System (ADS)

Yang, Lin; Guo, Peng; Yang, Aiying; Qiao, Yaojun

2018-02-01

In this paper, we propose a blind third-order dispersion estimation method based on fractional Fourier transformation (FrFT) in optical fiber communication system. By measuring the chromatic dispersion (CD) at different wavelengths, this method can estimation dispersion slope and further calculate the third-order dispersion. The simulation results demonstrate that the estimation error is less than 2 % in 28GBaud dual polarization quadrature phase-shift keying (DP-QPSK) and 28GBaud dual polarization 16 quadrature amplitude modulation (DP-16QAM) system. Through simulations, the proposed third-order dispersion estimation method is shown to be robust against nonlinear and amplified spontaneous emission (ASE) noise. In addition, to reduce the computational complexity, searching step with coarse and fine granularity is chosen to search optimal order of FrFT. The third-order dispersion estimation method based on FrFT can be used to monitor the third-order dispersion in optical fiber system.

Spectroscopic Constants and Line Positions for TiO Singlet States

NASA Astrophysics Data System (ADS)

Bittner, Dror M.; Bernath, Peter F.

2018-06-01

A consistent set of spectroscopic constants for the a1Δ, d1Σ+, b1Π, c1Φ, and f1Δ states of 48Ti16O has been determined from analysis of the b1Π–a1Δ, b1Π–d1Σ+, c1Φ–a1Δ, and f1Δ–a1Δ systems. Three Fourier transform emission spectra have been used for the analysis. New bands of the b1Π–a1Δ and c1Φ–a1Δ systems have been fitted. The first analysis of the c1Φ–a1Δ system using Fourier transform spectra is also provided. Extensive and improved line positions are measured. TiO is prominent in the spectra of oxygen-rich cool stellar objects and may be present in hot-Jupiter exoplanet atmospheres.

Maynooth Optical Aeronomical Facility

NASA Technical Reports Server (NTRS)

Mulligan, Francis J.; Niciejewski, Rick J.

1994-01-01

Ground-based measurements of upper atmospheric parameters, such as temperature and wind velocity, can be made by observing airglow emissions that have a well-defined altitude profile and that are known to be representative of the emitting region. We describe the optical observatory at Maynooth (53.23 deg N, 6.4 deg W) at which two instruments, a Fabry-Perot interferometer and a Fourier transform spectrometer, are used to record atmospheric airglow emissions in Ireland at visible and near-infrared wavelengths, respectively. Descriptions of the instruments, data acquisition, and analysis procedures are provided, together with some sample results.

Fourier Transforms Simplified: Computing an Infrared Spectrum from an Interferogram

ERIC Educational Resources Information Center

Hanley, Quentin S.

2012-01-01

Fourier transforms are used widely in chemistry and allied sciences. Examples include infrared, nuclear magnetic resonance, and mass spectroscopies. A thorough understanding of Fourier methods assists the understanding of microscopy, X-ray diffraction, and diffraction gratings. The theory of Fourier transforms has been presented in this "Journal",…

A fast algorithm for vertex-frequency representations of signals on graphs

PubMed Central

Jestrović, Iva; Coyle, James L.; Sejdić, Ervin

2016-01-01

The windowed Fourier transform (short time Fourier transform) and the S-transform are widely used signal processing tools for extracting frequency information from non-stationary signals. Previously, the windowed Fourier transform had been adopted for signals on graphs and has been shown to be very useful for extracting vertex-frequency information from graphs. However, high computational complexity makes these algorithms impractical. We sought to develop a fast windowed graph Fourier transform and a fast graph S-transform requiring significantly shorter computation time. The proposed schemes have been tested with synthetic test graph signals and real graph signals derived from electroencephalography recordings made during swallowing. The results showed that the proposed schemes provide significantly lower computation time in comparison with the standard windowed graph Fourier transform and the fast graph S-transform. Also, the results showed that noise has no effect on the results of the algorithm for the fast windowed graph Fourier transform or on the graph S-transform. Finally, we showed that graphs can be reconstructed from the vertex-frequency representations obtained with the proposed algorithms. PMID:28479645

Missing texture reconstruction method based on error reduction algorithm using Fourier transform magnitude estimation scheme.

PubMed

Ogawa, Takahiro; Haseyama, Miki

2013-03-01

A missing texture reconstruction method based on an error reduction (ER) algorithm, including a novel estimation scheme of Fourier transform magnitudes is presented in this brief. In our method, Fourier transform magnitude is estimated for a target patch including missing areas, and the missing intensities are estimated by retrieving its phase based on the ER algorithm. Specifically, by monitoring errors converged in the ER algorithm, known patches whose Fourier transform magnitudes are similar to that of the target patch are selected from the target image. In the second approach, the Fourier transform magnitude of the target patch is estimated from those of the selected known patches and their corresponding errors. Consequently, by using the ER algorithm, we can estimate both the Fourier transform magnitudes and phases to reconstruct the missing areas.

The Fourier transforms for the spatially homogeneous Boltzmann equation and Landau equation

NASA Astrophysics Data System (ADS)

Meng, Fei; Liu, Fang

2018-03-01

In this paper, we study the Fourier transforms for two equations arising in the kinetic theory. The first equation is the spatially homogeneous Boltzmann equation. The Fourier transform of the spatially homogeneous Boltzmann equation has been first addressed by Bobylev (Sov Sci Rev C Math Phys 7:111-233, 1988) in the Maxwellian case. Alexandre et al. (Arch Ration Mech Anal 152(4):327-355, 2000) investigated the Fourier transform of the gain operator for the Boltzmann operator in the cut-off case. Recently, the Fourier transform of the Boltzmann equation is extended to hard or soft potential with cut-off by Kirsch and Rjasanow (J Stat Phys 129:483-492, 2007). We shall first establish the relation between the results in Alexandre et al. (2000) and Kirsch and Rjasanow (2007) for the Fourier transform of the Boltzmann operator in the cut-off case. Then we give the Fourier transform of the spatially homogeneous Boltzmann equation in the non cut-off case. It is shown that our results cover previous works (Bobylev 1988; Kirsch and Rjasanow 2007). The second equation is the spatially homogeneous Landau equation, which can be obtained as a limit of the Boltzmann equation when grazing collisions prevail. Following the method in Kirsch and Rjasanow (2007), we can also derive the Fourier transform for Landau equation.

Low thermal emissivity surfaces using AgNW thin films

NASA Astrophysics Data System (ADS)

Pantoja, Elisa; Bhatt, Rajendra; Liu, Anping; Gupta, Mool C.

2017-12-01

The properties of silver nanowire (AgNW) films in the optical and infrared spectral regime offer an interesting opportunity for a broad range of applications that require low-emissivity coatings. This work reports a method to reduce the thermal emissivity of substrates by the formation of low-emissivity AgNW coating films from solution. The spectral emissivity was characterized by thermal imaging with an FLIR camera, followed by Fourier transform infrared spectroscopy. In a combined experimental and simulation study, we provide fundamental data of the transmittance, reflectance, haze, and emissivity of AgNW thin films. Emissivity values were finely tuned by modifying the concentration of the metal nanowires in the films. The simulation models based on the transfer matrix method developed for the AgNW thin films provided optical values that show a good agreement with the measurements.

Acousto-optic replication of ultrashort laser pulses

NASA Astrophysics Data System (ADS)

Yushkov, Konstantin B.; Molchanov, Vladimir Ya.; Ovchinnikov, Andrey V.; Chefonov, Oleg V.

2017-10-01

Precisely controlled sequences of ultrashort laser pulses are required in various scientific and engineering applications. We developed a phase-only acousto-optic pulse shaping method for replication of ultrashort laser pulses in a TW laser system. A sequence of several Fourier-transform-limited pulses is generated from a single femtosecond laser pulse by means of applying a piecewise linear phase modulation over the whole emission spectrum. Analysis demonstrates that the main factor which limits maximum delay between the pulse replicas is spectral resolution of the acousto-optic dispersive delay line used for pulse shaping. In experiments with a Cr:forsterite laser system, we obtained delays from 0.3 to 3.5 ps between two replicas of 190 fs transform-limited pulses at the central wavelength of laser emission, 1230 nm.

Precise and fast spatial-frequency analysis using the iterative local Fourier transform.

PubMed

Lee, Sukmock; Choi, Heejoo; Kim, Dae Wook

2016-09-19

The use of the discrete Fourier transform has decreased since the introduction of the fast Fourier transform (fFT), which is a numerically efficient computing process. This paper presents the iterative local Fourier transform (ilFT), a set of new processing algorithms that iteratively apply the discrete Fourier transform within a local and optimal frequency domain. The new technique achieves 2¹⁰ times higher frequency resolution than the fFT within a comparable computation time. The method's superb computing efficiency, high resolution, spectrum zoom-in capability, and overall performance are evaluated and compared to other advanced high-resolution Fourier transform techniques, such as the fFT combined with several fitting methods. The effectiveness of the ilFT is demonstrated through the data analysis of a set of Talbot self-images (1280 × 1024 pixels) obtained with an experimental setup using grating in a diverging beam produced by a coherent point source.

Measurements of reactive trace gases and variable O3 formation rates in some South Carolina biomass burning plumes

Treesearch

S. K. Akagi; R. J. Yokelson; I. R. Burling; S. Meinardi; I. Simpson; D. R. Blake; G. R. McMeeking; A. Sullivan; T. Lee; S. Kreidenweis; S. Urbanski; J. Reardon; D. W. T. Griffith; T. J. Johnson; D. R. Weise

2013-01-01

In October-November 2011 we measured trace gas emission factors from seven prescribed fires in South Carolina (SC), US, using two Fourier transform infrared spectrometer (FTIR) systems and whole air sampling (WAS) into canisters followed by gas- 5 chromatographic analysis. A total of 97 trace gas species were quantified from both airborne and ground-based sampling...

Measurements of trace gases and particles in fresh and aged smoke from a chaparral fire in California

Treesearch

S. K. Akagi; J. S. Craven; J. W. Taylor; G. R. McMeeking; R. J. Yokelson; I. R. Burling; M. J. Alvarado; J. Seinfeld; H. Coe; Shawn Urbanski

2010-01-01

On November 17th 2009 we used a Twin Otter aircraft outfitted with an airborne Fourier transform infrared spectrometer (AFTIR), aerosol mass spectrometer (AMS), single particle soot photometer (SP2), nephelometer, Licor CO2 analyzer, and a chemiluminescence ozone instrument to measure the initial emissions from a 100 hectare prescribed fire in chaparral fuels on the...

Behavior of sulfur during coal pyrolysis

USGS Publications Warehouse

Shao, D.; Hutchinson, E.J.; Heidbrink, J.; Pan, W.-P.; Chou, C.-L.

1994-01-01

The behavior of sulfur in Illinois coals during pyrolysis was evaluated by thermogravimetry/ Fourier transform-infrared spectroscopy (TG/FT-IR) techniques. SO2, COS, and H2S were major gaseous sulfur-containing products observed during coal pyrolysis. The release rates of the gaseous sulfur species showed several peaks within the temperature ranges, which were due to the emission of different forms of sulfur in coal. ?? 1994.

The Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS) on-board blackbody calibration system

NASA Astrophysics Data System (ADS)

Best, Fred A.; Revercomb, Henry E.; Knuteson, Robert O.; Tobin, David C.; Ellington, Scott D.; Werner, Mark W.; Adler, Douglas P.; Garcia, Raymond K.; Taylor, Joseph K.; Ciganovich, Nick N.; Smith, William L., Sr.; Bingham, Gail E.; Elwell, John D.; Scott, Deron K.

2005-01-01

The NASA New Millennium Program's Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS) instrument provides enormous advances in water vapor, wind, temperature, and trace gas profiling from geostationary orbit. The top-level instrument calibration requirement is to measure brightness temperature to better than 1 K (3 sigma) over a broad range of atmospheric brightness temperatures, with a reproducibility of +/-0.2 K. For in-flight radiometric calibration, GIFTS uses views of two on-board blackbody sources (290 K and 255 K) along with cold space, sequenced at regular programmable intervals. The blackbody references are cavities that follow the UW Atmospheric Emitted Radiance Interferometer (AERI) design, scaled to the GIFTS beam size. The cavity spectral emissivity is better than 0.998 with an absolute uncertainty of less than 0.001. Absolute blackbody temperature uncertainties are estimated at 0.07 K. This paper describes the detailed design of the GIFTS on-board calibration system that recently underwent its Critical Design Review. The blackbody cavities use ultra-stable thermistors to measure temperature, and are coated with high emissivity black paint. Monte Carlo modeling has been performed to calculate the cavity emissivity. Both absolute temperature and emissivity measurements are traceable to NIST, and detailed uncertainty budgets have been developed and used to show the overall system meets accuracy requirements. The blackbody controller is housed on a single electronics board and provides precise selectable set point temperature control, thermistor resistance measurement, and the digital interface to the GIFTS instrument. Plans for the NIST traceable ground calibration of the on-board blackbody system have also been developed and are presented in this paper.

Properties of the Magnitude Terms of Orthogonal Scaling Functions.

PubMed

Tay, Peter C; Havlicek, Joseph P; Acton, Scott T; Hossack, John A

2010-09-01

The spectrum of the convolution of two continuous functions can be determined as the continuous Fourier transform of the cross-correlation function. The same can be said about the spectrum of the convolution of two infinite discrete sequences, which can be determined as the discrete time Fourier transform of the cross-correlation function of the two sequences. In current digital signal processing, the spectrum of the contiuous Fourier transform and the discrete time Fourier transform are approximately determined by numerical integration or by densely taking the discrete Fourier transform. It has been shown that all three transforms share many analogous properties. In this paper we will show another useful property of determining the spectrum terms of the convolution of two finite length sequences by determining the discrete Fourier transform of the modified cross-correlation function. In addition, two properties of the magnitude terms of orthogonal wavelet scaling functions are developed. These properties are used as constraints for an exhaustive search to determine an robust lower bound on conjoint localization of orthogonal scaling functions.

Blue light emitting diesel soot for photonic applications

NASA Astrophysics Data System (ADS)

Swapna, M. S.; Sankararaman, S.

2018-01-01

The present work is the first report of producing blue light emission from phosphor free and low-cost material—the diesel soot from the internal combustion engines (ICEs). The structural morphology is analyzed by field emission scanning electron microscopy and high-resolution transmission electron microscopy. The optical characterization is done by recording UV-visible spectrum and photoluminescent Spectrum. The CIE plot and the power spectrum for the sample show blue emission. This is further verified by collecting diesel soot from the ICE of different year of make. A visual confirmation of blue emission is obtained by exciting the sample with UV laser. The presence of various allotropic forms of carbon in the sample is identified by x-ray diffraction, Fourier transform infrared and Raman spectroscopic analysis.

[Study on Differential Optical Absorption Spectroscopy Data Processing Based on Chirp-Z Transformation].

PubMed

Zheng, Hai-ming; Li, Guang-jie; Wu, Hao

2015-06-01

Differential optical absorption spectroscopy (DOAS) is a commonly used atmospheric pollution monitoring method. Denoising of monitoring spectral data will improve the inversion accuracy. Fourier transform filtering method is effectively capable of filtering out the noise in the spectral data. But the algorithm itself can introduce errors. In this paper, a chirp-z transform method is put forward. By means of the local thinning of Fourier transform spectrum, it can retain the denoising effect of Fourier transform and compensate the error of the algorithm, which will further improve the inversion accuracy. The paper study on the concentration retrieving of SO2 and NO2. The results show that simple division causes bigger error and is not very stable. Chirp-z transform is proved to be more accurate than Fourier transform. Results of the frequency spectrum analysis show that Fourier transform cannot solve the distortion and weakening problems of characteristic absorption spectrum. Chirp-z transform shows ability in fine refactoring of specific frequency spectrum.

Fourier removal of stripe artifacts in IRAS images

NASA Technical Reports Server (NTRS)

Van Buren, Dave

1987-01-01

By working in the Fourier plane, approximate removal of stripe artifacts in IRAS images can be effected. The image of interest is smoothed and subtracted from the original, giving the high-spatial-frequency part. This 'filtered' image is then clipped to remove point sources and then Fourier transformed. Subtracting the Fourier components contributing to the stripes in this image from the Fourier transform of the original and transforming back to the image plane yields substantial removal of the stripes.

Remote sensing of the troposphere by infrared emission spectroscopy

NASA Technical Reports Server (NTRS)

Beer, Reinhard; Glavich, Thomas A.

1989-01-01

This paper describes the concept of a cryogenic IR imaging Fourier transform spectrometer, called the Tropospheric Emission Spectrometer (TES), designed for observations of the troposphere and lower stratosphere from a near-earth orbit, using natural thermal emission and reflected sunlight. The principal molecular species to be measured by TES are O3, CO, CO2, N2O, H2O, H2O2, NO, NO2, HNO3, NH3, CH4, C2H6, C2H2, SO2, COS, CFCl3, and CF2Cl2. The TES is scheduled for a launch on the second polar platform of the Earth Observing System in 1998.

Spectral emissivity and transmissivity measurement for zinc sulphide infrared window based on integrating-sphere reflectometry

NASA Astrophysics Data System (ADS)

Zhang, Yu-Feng; Dai, Jing-Min; Zhang, Lei; Pan, Wei-Dong

2013-08-01

The spectral emissivity and transmissivity of zinc sulphide (ZnS) infrared windows in the spectral region from 2 to 12 μm and temperature range from 20 to 700°C is measured by a facility built at the Harbin Institute of Technology (HIT). The facility is based on the integrating-sphere reflectometry. Measurements have been performed on two samples made of ZnS. The results measured at 20°C are in good agreement with those obtained by the method of radiant energy comparison using a Fourier transform infrared spectrometer. Emissivity measurements performed with this facility present an uncertainty of 5.5% (cover factor=2).

Tropospheric Emission Spectrometer for the Earth Observing System

NASA Technical Reports Server (NTRS)

Glavich, Thomas A.; Beer, Reinhard

1991-01-01

A Tropospheric Emission Spectrometer (TES) for the Earth Observing System (EOS) series of polar-orbiting platforms is described. TES is aimed at studying tropospheric chemistry, in particular, the exchange of gases between the surface and the atmosphere, urban and regional pollution, acid rain precursors, sources and sinks of greenhouse gases, and the interchange of gases between the troposphere and the stratosphere. TES is a high-resolution (0.025/cm) infrared Fourier transform spectrometer operating in the passive thermal-emission mode in a very wide spectral range (600 to 4350/cm; 2.3 to 16.7 microns). TES has 32 spatial pixels in each of four optically conjugated linear detector arrays, each optimized for a different spectral region.

Near-infrared emission bands of TeH and TeD

NASA Astrophysics Data System (ADS)

Fink, E. H.; Setzer, K. D.; Ramsay, D. A.; Vervloet, M.

1989-11-01

High-resolution emission spectra of TeH and TeD have been obtained in the region 4200 to 3600 cm -1 using a Bomem DA3.002 Fourier transform spectrometer. Analyses are given for the 0-0 and 1-1 bands of the X 22Π{1}/{2}-X 12Π{3}/{2} system of TeH and for the 0-0 band of TeD. In addition the 2-0 vibrational overtone bands of 130TeH, 128TeH, and 126TeH are observed and analyzed. Accurate molecular constants are given for the first time.

Electro-Optical Imaging Fourier-Transform Spectrometer

NASA Technical Reports Server (NTRS)

Chao, Tien-Hsin; Zhou, Hanying

2006-01-01

An electro-optical (E-O) imaging Fourier-transform spectrometer (IFTS), now under development, is a prototype of improved imaging spectrometers to be used for hyperspectral imaging, especially in the infrared spectral region. Unlike both imaging and non-imaging traditional Fourier-transform spectrometers, the E-O IFTS does not contain any moving parts. Elimination of the moving parts and the associated actuator mechanisms and supporting structures would increase reliability while enabling reductions in size and mass, relative to traditional Fourier-transform spectrometers that offer equivalent capabilities. Elimination of moving parts would also eliminate the vibrations caused by the motions of those parts. Figure 1 schematically depicts a traditional Fourier-transform spectrometer, wherein a critical time delay is varied by translating one the mirrors of a Michelson interferometer. The time-dependent optical output is a periodic representation of the input spectrum. Data characterizing the input spectrum are generated through fast-Fourier-transform (FFT) post-processing of the output in conjunction with the varying time delay.

Measurements of reactive trace gases and variable O3 formation rates in some South Carolina biomass burning plumes [Discussions

Treesearch

S. K. Akagi; R. J. Yokelson; I. R. Burling; S. Meinardi; I. Simpson; D. R. Blake; G. R. McMeeking; A. Sullivan; T. Lee; S. Kreidenweis; S. Urbanski; J. Reardon; D. W. T. Griffith; T. J. Johnson; D. R. Weise

2012-01-01

In October–November 2011 we measured trace gas emission factors from seven prescribed fires in South Carolina (SC), US, using two Fourier transform infrared spectrometer (FTIR) systems and whole air sampling (WAS) into canisters followed by gas-chromatographic analysis. A total of 97 trace gas species were quantified from both airborne and ground-based sampling...

Field evaluation of Fourier transform infrared continuous emissions monitoring (FTIR CEM) systems

NASA Astrophysics Data System (ADS)

Dunder, Thomas A.; Geyer, Thomas J.; Kinner, Laura L.; Plummer, Grant M.

1995-02-01

Recent environmental regulations, including the Clean Air Act and the Enhanced Monitoring Regulations, may require continuous emissions monitoring (CEM) of hazardous air pollutants (HAPs). A promising technique for this application is Fourier transform infrared spectroscopy (FTIR). FTIR spectroscopy can, in principle, be used to monitor virtually any gas phase species. Two evaluations of FTIR CEM systems are discussed. The first study, performed in 1993 - 94, compared two FTIR CEM systems on a side-by-side basis in an extended field test at two coal-fired electric power plants. The FTIR CEM systems monitored the legally mandated criteria pollutants and diluents (CO, CO2, NO, NO2, and SO2) as well as H2O. In addition, one system monitored two HAPs (HCl and HF) and NH3. The FTIR CEM measurements were compared with those from the compliance CEM systems at the facilities. Several relative accuracy test audits were also performed to verify the FTIR CEM accuracy. The second evaluation was recently commenced on behalf of the Environmental Protection Agency. In this study, FTIR CEM systems are evaluated specifically for the monitoring of HAP species by conducting laboratory and field tests. The evaluation culminates in the development of proposed performance specifications and protocols for FTIR CEM systems.

Geometric interpretations of the Discrete Fourier Transform (DFT)

NASA Technical Reports Server (NTRS)

Campbell, C. W.

1984-01-01

One, two, and three dimensional Discrete Fourier Transforms (DFT) and geometric interpretations of their periodicities are presented. These operators are examined for their relationship with the two sided, continuous Fourier transform. Discrete or continuous transforms of real functions have certain symmetry properties. The symmetries are examined for the one, two, and three dimensional cases. Extension to higher dimension is straight forward.

An Introduction to Fast Fourier Transforms through the Study of Oscillating Reactions.

ERIC Educational Resources Information Center

Eastman, M. P.; And Others

1986-01-01

Discusses an experiment designed to introduce students to the basic principles of the fast Fourier transform and Fourier smoothing through transformation of time-dependent optical absorption data from an oscillating reaction. Uses the Belousov-Zhabotinskii reaction. Describes the experimental setup and data analysis techniques.

Fourier Transforms for Chemists Part III. Fourier Transforms in Data Treatment.

ERIC Educational Resources Information Center

Glasser, L.

1987-01-01

Discusses the factors affecting the behavior of a spectral function. Lists some important properties of Fourier transform (FT) pairs that are helpful when using the FT. Notes that these properties of the mathematical formulation have identical counterparts in the physical behavior of FT systems. (TW)

Determination of Fourier Transforms on an Instructional Analog Computer

ERIC Educational Resources Information Center

Anderson, Owen T.; Greenwood, Stephen R.

1974-01-01

An analog computer program to find and display the Fourier transform of some real, even functions is described. Oscilloscope traces are shown for Fourier transforms of a rectangular pulse, a Gaussian, a cosine wave, and a delayed narrow pulse. Instructional uses of the program are discussed briefly. (DT)

The application and improvement of Fourier transform spectrometer experiment

NASA Astrophysics Data System (ADS)

Liu, Zhi-min; Gao, En-duo; Zhou, Feng-qi; Wang, Lan-lan; Feng, Xiao-hua; Qi, Jin-quan; Ji, Cheng; Wang, Luning

2017-08-01

According to teaching and experimental requirements of Optoelectronic information science and Engineering, in order to consolidate theoretical knowledge and improve the students practical ability, the Fourier transform spectrometer ( FTS) experiment, its design, application and improvement are discussed in this paper. The measurement principle and instrument structure of Fourier transform spectrometer are introduced, and the spectrums of several common Laser devices are measured. Based on the analysis of spectrum and test, several possible improvement methods are proposed. It also helps students to understand the application of Fourier transform in physics.

Validating data analysis of broadband laser ranging

NASA Astrophysics Data System (ADS)

Rhodes, M.; Catenacci, J.; Howard, M.; La Lone, B.; Kostinski, N.; Perry, D.; Bennett, C.; Patterson, J.

2018-03-01

Broadband laser ranging combines spectral interferometry and a dispersive Fourier transform to achieve high-repetition-rate measurements of the position of a moving surface. Telecommunications fiber is a convenient tool for generating the large linear dispersions required for a dispersive Fourier transform, but standard fiber also has higher-order dispersion that distorts the Fourier transform. Imperfections in the dispersive Fourier transform significantly complicate the ranging signal and must be dealt with to make high-precision measurements. We describe in detail an analysis process for interpreting ranging data when standard telecommunications fiber is used to perform an imperfect dispersive Fourier transform. This analysis process is experimentally validated over a 27-cm scan of static positions, showing an accuracy of 50 μm and a root-mean-square precision of 4.7 μm.

The morphing of geographical features by Fourier transformation.

PubMed

Li, Jingzhong; Liu, Pengcheng; Yu, Wenhao; Cheng, Xiaoqiang

2018-01-01

This paper presents a morphing model of vector geographical data based on Fourier transformation. This model involves three main steps. They are conversion from vector data to Fourier series, generation of intermediate function by combination of the two Fourier series concerning a large scale and a small scale, and reverse conversion from combination function to vector data. By mirror processing, the model can also be used for morphing of linear features. Experimental results show that this method is sensitive to scale variations and it can be used for vector map features' continuous scale transformation. The efficiency of this model is linearly related to the point number of shape boundary and the interceptive value n of Fourier expansion. The effect of morphing by Fourier transformation is plausible and the efficiency of the algorithm is acceptable.

Mid-infrared, long wave infrared (4-12 μm) molecular emission signatures from pharmaceuticals using laser-induced breakdown spectroscopy (LIBS).

PubMed

Yang, Clayton S-C; Brown, Ei E; Kumi-Barimah, Eric; Hommerich, Uwe H; Jin, Feng; Trivedi, Sudhir B; Samuels, Alan C; Snyder, A Peter

2014-01-01

In an effort to augment the atomic emission spectra of conventional laser-induced breakdown spectroscopy (LIBS) and to provide an increase in selectivity, mid-wave to long-wave infrared (IR), LIBS studies were performed on several organic pharmaceuticals. Laser-induced breakdown spectroscopy signature molecular emissions of target organic compounds are observed for the first time in the IR fingerprint spectral region between 4-12 μm. The IR emission spectra of select organic pharmaceuticals closely correlate with their respective standard Fourier transform infrared spectra. Intact and/or fragment sample molecular species evidently survive the LIBS event. The combination of atomic emission signatures derived from conventional ultraviolet-visible-near-infrared LIBS with fingerprints of intact molecular entities determined from IR LIBS promises to be a powerful tool for chemical detection.

Fast Implicit Methods For Elliptic Moving Interface Problems

DTIC Science & Technology

2015-12-11

analyzed, and tested for the Fourier transform of piecewise polynomials given on d-dimensional simplices in D-dimensional Euclidean space. These transforms...evaluation, and one to three orders of magnitude slower than the classical uniform Fast Fourier Transform. Second, bilinear quadratures ---which...a fast algorithm was derived, analyzed, and tested for the Fourier transform of pi ecewise polynomials given on d-dimensional simplices in D

The scale of the Fourier transform: a point of view of the fractional Fourier transform

NASA Astrophysics Data System (ADS)

Jimenez, C. J.; Vilardy, J. M.; Salinas, S.; Mattos, L.; Torres, C. O.

2017-01-01

In this paper using the Fourier transform of order fractional, the ray transfer matrix for the symmetrical optical systems type ABCD and the formulae by Collins for the diffraction, we obtain explicitly the expression for scaled Fourier transform conventional; this result is the great importance in optical signal processing because it offers the possibility of scaling the size of output the Fourier distribution of the system, only by manipulating the distance of the diffraction object toward the thin lens, this research also emphasizes on practical limits when a finite spherical converging lens aperture is used. Digital simulation was carried out using the numerical platform of Matlab 7.1.

Methane emission estimates using chamber and tracer release experiments for a municipal waste water treatment plant

NASA Astrophysics Data System (ADS)

Yver Kwok, C. E.; Müller, D.; Caldow, C.; Lebègue, B.; Mønster, J. G.; Rella, C. W.; Scheutz, C.; Schmidt, M.; Ramonet, M.; Warneke, T.; Broquet, G.; Ciais, P.

2015-07-01

This study presents two methods for estimating methane emissions from a waste water treatment plant (WWTP) along with results from a measurement campaign at a WWTP in Valence, France. These methods, chamber measurements and tracer release, rely on Fourier transform infrared spectroscopy and cavity ring-down spectroscopy instruments. We show that the tracer release method is suitable for quantifying facility- and some process-scale emissions, while the chamber measurements provide insight into individual process emissions. Uncertainties for the two methods are described and discussed. Applying the methods to CH4 emissions of the WWTP, we confirm that the open basins are not a major source of CH4 on the WWTP (about 10 % of the total emissions), but that the pretreatment and sludge treatment are the main emitters. Overall, the waste water treatment plant is representative of an average French WWTP.

Structural, thermal and electrical characterizations of multiwalled carbon nanotubes and polyaniline composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Kamal, E-mail: singhkamal204@gmail.com; Garg, Leena; Singh, Jaspal

2016-05-06

The undoped and doped composite of MWNTs (Multiwalled Carbon Nanotubes) with PANI (/Polyaniline) was prepared by chemical oxidative polymerization. The MWNTs/PANI composites have been characterized by using various techniques like Thermogravometric Analysis (TGA), Fourier transform infrared (FT-IR) spectrometer and Field emission scanning electron microscope (FE-SEM) and conductivity measurement by using two probe method. TGA results has shown that thermal stability followed the pattern undoped MWNTs/PANI composite < doped MWNTs/PANI composite. FE-SEM micrographs demonstrated the morphological changes on the surface of MWNTs as a result of composite formation. Fourier transformed infrared (FT-IR) spectra ascertained the formation of the composite. Study ofmore » electrical characteristics demonstrated that the doped MWNTs/PANI composite (1.2 × 10{sup 1} Scm{sup −1}) have better conductivity than the undoped MWNTs/PANI composite (10{sup −4} Scm{sup −1}). These CNTs based polymeric composites are of great importance in developing new nano-scale devices for future chemical, mechanical and electronic applications.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deus, R.C.; Cortés, J.A., E-mail: leandrosrr89@gmail.com; Ramirez, M.A.

Highlights: • CeO{sub 2} nanoparticles were obtained by microwave-hydrothermal method. • Rietveld refinement reveals a cubic structure. • KOH mineralizer agent exhibit weak agglomeration at low temperature and shorter time. - Abstract: The structural and photoluminescent properties at room temperature of CeO{sub 2} and La-doped CeO{sub 2} particles were undertaken. The obtained particles were synthesized by a microwave-assisted hydrothermal method (MAH) under different lanthanum contents. X-ray diffraction (XRD), Fourier transform infrared (FT-IR), Fourier transform Raman (FT-Raman), Ultra-violet spectroscopy (UV–vis) and photoluminescence (PL) measurements were carried out. XRD revealed that the powders are free of secondary phases and crystallize in themore » cubic structure. Raman data show that increasing La doping content increase oxygen vacancies due to lattice expansion. The UV/vis absorption spectroscopy suggested the presence of intermediate energy levels in the band gap of structurally ordered powders. Lanthanum addition creates oxygen vacancies and shifts the photoluminescence in the low energy range leading to intense PL emission.« less

Comparison study on biosynthesis of silver nanoparticles using fresh and hot air oven dried IMPERATA CYLINDRICA leaf

NASA Astrophysics Data System (ADS)

Najmi Bonnia, Noor; Fairuzi, Afiza Ahmad; Akhir, Rabiatuladawiyah Md.; Yahya, Sabrina M.; Rani, Mohd Azri Ab; Ratim, Suzana; Rahman, Norafifah A.; Akil, Hazizan Md

2018-01-01

The perennial rhizomatous grass; Imperata cylindrica (I. cylindrica) has been reported rich in various phytochemicals. In present study, silver nanoparticles were synthesized from aqueous leaf extract of I. cylindrica at two different leaf conditions; fresh leaves and hot-air oven dried leaves. Biosynthesized silver nanoparticles were characterized by UV-visible spectroscopy, field emission scanning electron microscopy (FESEM) and Fourier transform infrared spectroscopy (FTIR). Maximum absorption was recorded between 400 nm to 500 nm. FESEM analysis revealed that the silver nanoparticles predominantly form spherical shapes. The particles sizes were ranging from 22-37 nm. The elemental composition of the synthesized silver nanoparticles was confirmed by using energy dispersive X-ray spectroscopy (EDX) analysis. Fourier transform infrared spectroscopy (FTIR) confirmed the reducing and stabilizing actions came from biomolecules associated with I. cylindrica leaf extract. Thus in this investigation, an environmentally safe method to synthesized silver nanoparticles using local plant extract was successfully established.

Challenges in atmospheric monitoring of areal emission sources - an Open-path Fourier transform infrared (OP-FTIR) spectroscopic experience report

NASA Astrophysics Data System (ADS)

Schuetze, C.; Sauer, U.; Dietrich, P.

2015-12-01

Reliable detection and assessment of near-surface CO2 emissions from natural or anthropogenic sources require the application of various monitoring tools at different spatial scales. Especially, optical remote sensing tools for atmospheric monitoring have the potential to measure integrally CO2 emissions over larger scales (> 10.000m2). Within the framework of the MONACO project ("Monitoring approach for geological CO2 storage sites using a hierarchical observation concept"), an integrative hierarchical monitoring concept was developed and validated at different field sites with the aim to establish a modular observation strategy including investigations in the shallow subsurface, at ground surface level and the lower atmospheric boundary layer. The main aims of the atmospheric monitoring using optical remote sensing were the observation of the gas dispersion in to the near-surface atmosphere, the determination of maximum concentration values and identification of the main challenges associated with the monitoring of extended emission sources with the proposed methodological set up under typical environmental conditions. The presentation will give an overview about several case studies using the integrative approach of Open-Path Fourier Transform Infrared spectroscopy (OP FTIR) in combination with in situ measurements. As a main result, the method was validated as possible approach for continuous monitoring of the atmospheric composition, in terms of integral determination of GHG concentrations and to identify target areas which are needed to be investigated more in detail. Especially the data interpretation should closely consider the micrometeorological conditions. Technical aspects concerning robust equipment, experimental set up and fast data processing algorithms have to be taken into account for the enhanced automation of atmospheric monitoring.

Research about vibration characteristics of timing chain system based on short-time Fourier transform

NASA Astrophysics Data System (ADS)

Xi, Jiaxin; Liu, Ning

2017-09-01

Vibration characteristic of timing chain system is very important for an engine. In this study, we used a bush roller chain drive system as an example to explain how to use mulitybody dynamic techniques and short-time Fourier transform to investigate vibration characteristics of timing chain system. Multibody dynamic simulation data as chain tension force and external excitation sources curves were provided for short-time Fourier transform study. The study results of short-time Fourier transform illustrate that there are two main vibration frequency domain of timing chain system, one is the low frequency vibration caused by crankshaft sprocket velocity and camshaft sprocket torque. Another is vibration around 1000Hz lead by hydraulic tensioner. Hence, short-time Fourier transform method is useful for basic research of vibration characteristics for timing chain system.

Fourier transform mass spectrometry.

PubMed

Scigelova, Michaela; Hornshaw, Martin; Giannakopulos, Anastassios; Makarov, Alexander

2011-07-01

This article provides an introduction to Fourier transform-based mass spectrometry. The key performance characteristics of Fourier transform-based mass spectrometry, mass accuracy and resolution, are presented in the view of how they impact the interpretation of measurements in proteomic applications. The theory and principles of operation of two types of mass analyzer, Fourier transform ion cyclotron resonance and Orbitrap, are described. Major benefits as well as limitations of Fourier transform-based mass spectrometry technology are discussed in the context of practical sample analysis, and illustrated with examples included as figures in this text and in the accompanying slide set. Comparisons highlighting the performance differences between the two mass analyzers are made where deemed useful in assisting the user with choosing the most appropriate technology for an application. Recent developments of these high-performing mass spectrometers are mentioned to provide a future outlook.

Fourier Transform Mass Spectrometry

PubMed Central

Scigelova, Michaela; Hornshaw, Martin; Giannakopulos, Anastassios; Makarov, Alexander

2011-01-01

This article provides an introduction to Fourier transform-based mass spectrometry. The key performance characteristics of Fourier transform-based mass spectrometry, mass accuracy and resolution, are presented in the view of how they impact the interpretation of measurements in proteomic applications. The theory and principles of operation of two types of mass analyzer, Fourier transform ion cyclotron resonance and Orbitrap, are described. Major benefits as well as limitations of Fourier transform-based mass spectrometry technology are discussed in the context of practical sample analysis, and illustrated with examples included as figures in this text and in the accompanying slide set. Comparisons highlighting the performance differences between the two mass analyzers are made where deemed useful in assisting the user with choosing the most appropriate technology for an application. Recent developments of these high-performing mass spectrometers are mentioned to provide a future outlook. PMID:21742802

Properly used ''aliasing'' can give better resolution from fewer points in Fourier transform spectroscopy

NASA Astrophysics Data System (ADS)

D'Astous, Y.; Blanchard, M.

1982-05-01

In the past years, the Journal has published a number of articles1-5 devoted to the introduction of Fourier transform spectroscopy in the undergraduate labs. In most papers, the proposed experimental setup consists of a Michelson interferometer, a light source, a light detector, and a chart recorder. The student uses this setup to record an interferogram which is then Fourier transformed to obtain the spectrogram of the light source. Although attempts have been made to ease the task of performing the required Fourier transform,6 the use of computers and Cooley-Tukey's fast Fourier transform (FFT) algorithm7 is by far the simplest method to use. However, to be able to use FFT, one has to get a number of samples of the interferogram, a tedious job which should be kept to a minimum. (AIP)

The morphing of geographical features by Fourier transformation

PubMed Central

Liu, Pengcheng; Yu, Wenhao; Cheng, Xiaoqiang

2018-01-01

This paper presents a morphing model of vector geographical data based on Fourier transformation. This model involves three main steps. They are conversion from vector data to Fourier series, generation of intermediate function by combination of the two Fourier series concerning a large scale and a small scale, and reverse conversion from combination function to vector data. By mirror processing, the model can also be used for morphing of linear features. Experimental results show that this method is sensitive to scale variations and it can be used for vector map features’ continuous scale transformation. The efficiency of this model is linearly related to the point number of shape boundary and the interceptive value n of Fourier expansion. The effect of morphing by Fourier transformation is plausible and the efficiency of the algorithm is acceptable. PMID:29351344

Far-field radiation patterns of aperture antennas by the Winograd Fourier transform algorithm

NASA Technical Reports Server (NTRS)

Heisler, R.

1978-01-01

A more time-efficient algorithm for computing the discrete Fourier transform, the Winograd Fourier transform (WFT), is described. The WFT algorithm is compared with other transform algorithms. Results indicate that the WFT algorithm in antenna analysis appears to be a very successful application. Significant savings in cpu time will improve the computer turn around time and circumvent the need to resort to weekend runs.

Treatment Characteristics of Polysaccharides and Endotoxin Using Oxygen Plasma Produced by RF Discharge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kitazaki, Satoshi; Hayashi, Nobuya; Goto, Masaaki

Treatment of polysaccharides and endotoxin were attempted using oxygen plasma produced by RF discharge. Oxygen radicals observed by optical light emission spectra are factors of decomposition of polysaccharides and endotoxin. Fourier transform infrared spectra indicate that most of chemical bonds in the polysaccharides are dissociated after irradiation of the oxygen plasma. Also, the decomposition rate of endotoxin was approximately 90% after irradiation of the oxygen plasma for 180 min.

Treatment Characteristics of Polysaccharides and Endotoxin Using Oxygen Plasma Produced by RF Discharge

NASA Astrophysics Data System (ADS)

Kitazaki, Satoshi; Hayashi, Nobuya; Goto, Masaaki

2010-10-01

Treatment of polysaccharides and endotoxin were attempted using oxygen plasma produced by RF discharge. Oxygen radicals observed by optical light emission spectra are factors of decomposition of polysaccharides and endotoxin. Fourier transform infrared spectra indicate that most of chemical bonds in the polysaccharides are dissociated after irradiation of the oxygen plasma. Also, the decomposition rate of endotoxin was approximately 90% after irradiation of the oxygen plasma for 180 min.

Representation of Complex Spectra in Auditory Cortex

DTIC Science & Technology

1997-01-01

predict the response to any broadband dynamic sound. Fourier Transform Inverse Transform ∫ [.] exp(±2πjΩx±2πjwt) 2 1 2 / 1 1 a 2 1 2 / 1 1 a...Systems Research University of Maryland Spectro-Temporal Transform Ω wx = log f t w = “ripple velocity” Ω = “ripple frequency” Fourier Transform Inverse ... Transform ∫ [.] exp(±2πjΩx±2πjwt) Real functions in the spectro-temporal domain give rise to complex conjugate symmetric functions in the Fourier

[Optical-fiber Fourier transform spectrometer].

PubMed

Liu, Yong; Li, Bao-sheng; Liu, Yan; Zhai, Yu-feng; Wang, An

2006-10-01

A novel Fourier transform spectrum analyzer based on a single mode fiber Mach-Zehnder interferometer is reported. An optical fiber Fourier transform spectrometer, with bulk optics components replaced by fiber optical components and with the moving mirror replaced by a piezoelectric element fiber stretcher was constructed. The output spectrum of a LD below threshold was measured. Experiment result agrees with that by using grating spectrum analyzer, showing the feasibility of the optic fiber Fourier transform spectrometer for practical spectrum measurement. Spectrum resolution -7 cm(-1) was obtained in our experiment. The resolution can be further improved by increasing the maximum optical path difference.

Building a symbolic computer algebra toolbox to compute 2D Fourier transforms in polar coordinates.

PubMed

Dovlo, Edem; Baddour, Natalie

2015-01-01

The development of a symbolic computer algebra toolbox for the computation of two dimensional (2D) Fourier transforms in polar coordinates is presented. Multidimensional Fourier transforms are widely used in image processing, tomographic reconstructions and in fact any application that requires a multidimensional convolution. By examining a function in the frequency domain, additional information and insights may be obtained. The advantages of our method include: •The implementation of the 2D Fourier transform in polar coordinates within the toolbox via the combination of two significantly simpler transforms.•The modular approach along with the idea of lookup tables implemented help avoid the issue of indeterminate results which may occur when attempting to directly evaluate the transform.•The concept also helps prevent unnecessary computation of already known transforms thereby saving memory and processing time.

Freestanding silicon quantum dots: origin of red and blue luminescence.

PubMed

Gupta, Anoop; Wiggers, Hartmut

2011-02-04

In this paper, we studied the behavior of silicon quantum dots (Si-QDs) after etching and surface oxidation by means of photoluminescence (PL) measurements, Fourier transform infrared spectroscopy (FTIR) and electron paramagnetic resonance spectroscopy (EPR). We observed that etching of red luminescing Si-QDs with HF acid drastically reduces the concentration of defects and significantly enhances their PL intensity together with a small shift in the emission spectrum. Additionally, we observed the emergence of blue luminescence from Si-QDs during the re-oxidation of freshly etched particles. Our results indicate that the red emission is related to the quantum confinement effect, while the blue emission from Si-QDs is related to defect states at the newly formed silicon oxide surface.

Responsivity-based criterion for accurate calibration of FTIR emission spectra: theoretical development and bandwidth estimation.

PubMed

Rowe, Penny M; Neshyba, Steven P; Walden, Von P

2011-03-14

An analytical expression for the variance of the radiance measured by Fourier-transform infrared (FTIR) emission spectrometers exists only in the limit of low noise. Outside this limit, the variance needs to be calculated numerically. In addition, a criterion for low noise is needed to identify properly calibrated radiances and optimize the instrument bandwidth. In this work, the variance and the magnitude of a noise-dependent spectral bias are calculated as a function of the system responsivity (r) and the noise level in its estimate (σr). The criterion σr/r<0.3, applied to downwelling and upwelling FTIR emission spectra, shows that the instrument bandwidth is specified properly for one instrument but needs to be restricted for another.

Atmospheric-Pressure Plasma Interaction with Soft Materials as Fundamental Processes in Plasma Medicine.

PubMed

Takenaka, Kosuke; Miyazaki, Atsushi; Uchida, Giichiro; Setsuhara, Yuichi

2015-03-01

Molecular-structure variation of organic materials irradiated with atmospheric pressure He plasma jet have been investigated. Optical emission spectrum in the atmospheric-pressure He plasma jet has been measured. The spectrum shows considerable emissions of He lines, and the emission of O and N radicals attributed to air. Variation in molecular structure of Polyethylene terephthalate (PET) film surface irradiated with the atmospheric-pressure He plasma jet has been observed via X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR). These results via XPS and FT-IR indicate that the PET surface irradiated with the atmospheric-pressure He plasma jet was oxidized by chemical and/or physical effect due to irradiation of active species.

Automatic Fourier transform and self-Fourier beams due to parabolic potential

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yiqi, E-mail: zhangyiqi@mail.xjtu.edu.cn; Liu, Xing; Belić, Milivoj R., E-mail: milivoj.belic@qatar.tamu.edu

We investigate the propagation of light beams including Hermite–Gauss, Bessel–Gauss and finite energy Airy beams in a linear medium with parabolic potential. Expectedly, the beams undergo oscillation during propagation, but quite unexpectedly they also perform automatic Fourier transform, that is, periodic change from the beam to its Fourier transform and back. In addition to oscillation, the finite-energy Airy beams exhibit periodic inversion during propagation. The oscillating period of parity-asymmetric beams is twice that of the parity-symmetric beams. Based on the propagation in parabolic potential, we introduce a class of optically-interesting beams that are self-Fourier beams—that is, the beams whose Fouriermore » transforms are the beams themselves.« less

A discrete Fourier transform for virtual memory machines

NASA Technical Reports Server (NTRS)

Galant, David C.

1992-01-01

An algebraic theory of the Discrete Fourier Transform is developed in great detail. Examination of the details of the theory leads to a computationally efficient fast Fourier transform for the use on computers with virtual memory. Such an algorithm is of great use on modern desktop machines. A FORTRAN coded version of the algorithm is given for the case when the sequence of numbers to be transformed is a power of two.

A Simple Approach to Fourier Aliasing

ERIC Educational Resources Information Center

Foadi, James

2007-01-01

In the context of discrete Fourier transforms the idea of aliasing as due to approximation errors in the integral defining Fourier coefficients is introduced and explained. This has the positive pedagogical effect of getting to the heart of sampling and the discrete Fourier transform without having to delve into effective, but otherwise long and…

A general spectral transformation simultaneously including a Fourier transformation and a Laplace transformation

NASA Technical Reports Server (NTRS)

Marko, H.

1978-01-01

A general spectral transformation is proposed and described. Its spectrum can be interpreted as a Fourier spectrum or a Laplace spectrum. The laws and functions of the method are discussed in comparison with the known transformations, and a sample application is shown.

Soil emissivity and reflectance spectra measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sobrino, Jose A.; Mattar, Cristian; Pardo, Pablo

We present an analysis of the laboratory reflectance and emissivity spectra of 11 soil samples collected on different field campaigns carried out over a diverse suite of test sites in Europe, North Africa, and South America from 2002 to 2008. Hemispherical reflectance spectra were measured from 2.0 to 14 {mu}m with a Fourier transform infrared spectrometer, and x-ray diffraction analysis (XRD) was used to determine the mineralogical phases of the soil samples. Emissivity spectra were obtained from the hemispherical reflectance measurements using Kirchhoff's law and compared with in situ radiance measurements obtained with a CIMEL Electronique CE312-2 thermal radiometer andmore » converted to emissivity using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) temperature and emissivity separation algorithm. The CIMEL has five narrow bands at approximately the same positions as the ASTER. Results show a root mean square error typically below 0.015 between laboratory emissivity measurements and emissivity measurements derived from the field radiometer.« less

Fourier Analysis and Structure Determination: Part I: Fourier Transforms.

ERIC Educational Resources Information Center

Chesick, John P.

1989-01-01

Provides a brief introduction with some definitions and properties of Fourier transforms. Shows relations, ways of understanding the mathematics, and applications. Notes proofs are not included but references are given. First of three part series. (MVL)

Fourier transform of delayed fluorescence as an indicator of herbicide concentration.

PubMed

Guo, Ya; Tan, Jinglu

2014-12-21

It is well known that delayed fluorescence (DF) from Photosystem II (PSII) of plant leaves can be potentially used to sense herbicide pollution and evaluate the effect of herbicides on plant leaves. The research of using DF as a measure of herbicides in the literature was mainly conducted in time domain and qualitative correlation was often obtained. Fourier transform is often used to analyze signals. Viewing DF signal in frequency domain through Fourier transform may allow separation of signal components and provide a quantitative method for sensing herbicides. However, there is a lack of an attempt to use Fourier transform of DF as an indicator of herbicide. In this work, the relationship between the Fourier transform of DF and herbicide concentration was theoretically modelled and analyzed, which immediately yielded a quantitative method to measure herbicide concentration in frequency domain. Experiments were performed to validate the developed method. Copyright © 2014 Elsevier Ltd. All rights reserved.

Study on sampling of continuous linear system based on generalized Fourier transform

NASA Astrophysics Data System (ADS)

Li, Huiguang

2003-09-01

In the research of signal and system, the signal's spectrum and the system's frequency characteristic can be discussed through Fourier Transform (FT) and Laplace Transform (LT). However, some singular signals such as impulse function and signum signal don't satisfy Riemann integration and Lebesgue integration. They are called generalized functions in Maths. This paper will introduce a new definition -- Generalized Fourier Transform (GFT) and will discuss generalized function, Fourier Transform and Laplace Transform under a unified frame. When the continuous linear system is sampled, this paper will propose a new method to judge whether the spectrum will overlap after generalized Fourier transform (GFT). Causal and non-causal systems are studied, and sampling method to maintain system's dynamic performance is presented. The results can be used on ordinary sampling and non-Nyquist sampling. The results also have practical meaning on research of "discretization of continuous linear system" and "non-Nyquist sampling of signal and system." Particularly, condition for ensuring controllability and observability of MIMO continuous systems in references 13 and 14 is just an applicable example of this paper.

Analysis of aircraft exhausts with Fourier-transform infrared emission spectroscopy.

PubMed

Heland, J; Schäfer, K

1997-07-20

Because of the worldwide growth in air traffic and its increasing effects on the atmospheric environment, it is necessary to quantify the direct aircraft emissions at all altitudes. In this study Fourier-transform infrared emission spectroscopy as a remote-sensing multi-component-analyzing technique for aircraft exhausts was investigated at ground level with a double pendulum interferometer and a line-by-line computer algorithm that was applied to a multilayer radiative transfer problem. Initial measurements were made to specify the spectral windows for traceable compounds, to test the sensitivity of the system, and to develop calibration and continuum handling procedures. To obtain information about the radial temperature and concentration profiles, we developed an algorithm for the analysis of an axial-symmetric multilayered plume by use of the CO(2) hot band at approximately 2400 cm(-1). Measurements were made with several in-service engines. Effects that were due to engine aging were detected but have to be analyzed systematically in the near future. Validation measurements were carried out with a conventional propane gas burner to compare the results with those obtained with standard measurement equipment. These measurements showed good agreement to within +/-20% for the CO and NO(x) results. The overall accuracy of the system was found to be +/-30%. The detection limits of the system for a typical engine plume (380 degrees C, ? = 50 cm) are below 0.1% for CO(2), ~0.7% for H(2)O, ~20 ppmv (parts per million by volume) for CO, and ~90 ppmv for NO.

Optical spectroscopy, 1.06 μm emission properties of Nd3 +-doped phosphate based glasses

NASA Astrophysics Data System (ADS)

Sk. Nayab, Rasool; Sasikala, T.; Mohan Babu, A.; Rama Moorthy, L.; C. K., Jayasankar

2017-06-01

Neodymium doped phosphate based glasses with composition of (P2O5 + K2O + Al2O3 + CaF2) were prepared. The samples were analysed through differential thermal analysis (DTA), Fourier transform infrared (FTIR), absorption, emission and decay measurements. Judd-Ofelt parameters (Ωλ) have been determined from the spectral intensities of absorption bands in order to calculate the radiative parameters like radiative transition probabilities (AR), radiative lifetime (τR) and branching ratios (βR) for the 4F3/2 → 4I11/2 laser transition of Nd3 + ion. The effective emission bandwidths (Δλeff), experimental branching ratios (βexp) and stimulated emission cross-sections (σe) have been determined from the emission spectrum. The decay curves of the 4F3/2 level exhibited almost single exponential nature for all the Nd3 + ion concentrations.

Structure in the 3D Galaxy Distribution. III. Fourier Transforming the Universe: Phase and Power Spectra

NASA Technical Reports Server (NTRS)

Scargle, Jeffrey D.; Way, M. J.; Gazis, P. G.

2017-01-01

We demonstrate the effectiveness of a relatively straightforward analysis of the complex 3D Fourier transform of galaxy coordinates derived from redshift surveys. Numerical demonstrations of this approach are carried out on a volume-limited sample of the Sloan Digital Sky Survey redshift survey. The direct unbinned transform yields a complex 3D data cube quite similar to that from the Fast Fourier Transform of finely binned galaxy positions. In both cases, deconvolution of the sampling window function yields estimates of the true transform. Simple power spectrum estimates from these transforms are roughly consistent with those using more elaborate methods. The complex Fourier transform characterizes spatial distributional properties beyond the power spectrum in a manner different from (and we argue is more easily interpreted than) the conventional multipoint hierarchy. We identify some threads of modern large-scale inference methodology that will presumably yield detections in new wider and deeper surveys.

Building a symbolic computer algebra toolbox to compute 2D Fourier transforms in polar coordinates

PubMed Central

Dovlo, Edem; Baddour, Natalie

2015-01-01

The development of a symbolic computer algebra toolbox for the computation of two dimensional (2D) Fourier transforms in polar coordinates is presented. Multidimensional Fourier transforms are widely used in image processing, tomographic reconstructions and in fact any application that requires a multidimensional convolution. By examining a function in the frequency domain, additional information and insights may be obtained. The advantages of our method include: • The implementation of the 2D Fourier transform in polar coordinates within the toolbox via the combination of two significantly simpler transforms. • The modular approach along with the idea of lookup tables implemented help avoid the issue of indeterminate results which may occur when attempting to directly evaluate the transform. • The concept also helps prevent unnecessary computation of already known transforms thereby saving memory and processing time. PMID:26150988

Performance of the Wavelet Decomposition on Massively Parallel Architectures

NASA Technical Reports Server (NTRS)

El-Ghazawi, Tarek A.; LeMoigne, Jacqueline; Zukor, Dorothy (Technical Monitor)

2001-01-01

Traditionally, Fourier Transforms have been utilized for performing signal analysis and representation. But although it is straightforward to reconstruct a signal from its Fourier transform, no local description of the signal is included in its Fourier representation. To alleviate this problem, Windowed Fourier transforms and then wavelet transforms have been introduced, and it has been proven that wavelets give a better localization than traditional Fourier transforms, as well as a better division of the time- or space-frequency plane than Windowed Fourier transforms. Because of these properties and after the development of several fast algorithms for computing the wavelet representation of any signal, in particular the Multi-Resolution Analysis (MRA) developed by Mallat, wavelet transforms have increasingly been applied to signal analysis problems, especially real-life problems, in which speed is critical. In this paper we present and compare efficient wavelet decomposition algorithms on different parallel architectures. We report and analyze experimental measurements, using NASA remotely sensed images. Results show that our algorithms achieve significant performance gains on current high performance parallel systems, and meet scientific applications and multimedia requirements. The extensive performance measurements collected over a number of high-performance computer systems have revealed important architectural characteristics of these systems, in relation to the processing demands of the wavelet decomposition of digital images.

Realistic Analytical Polyhedral MRI Phantoms

PubMed Central

Ngo, Tri M.; Fung, George S. K.; Han, Shuo; Chen, Min; Prince, Jerry L.; Tsui, Benjamin M. W.; McVeigh, Elliot R.; Herzka, Daniel A.

2015-01-01

Purpose Analytical phantoms have closed form Fourier transform expressions and are used to simulate MRI acquisitions. Existing 3D analytical phantoms are unable to accurately model shapes of biomedical interest. It is demonstrated that polyhedral analytical phantoms have closed form Fourier transform expressions and can accurately represent 3D biomedical shapes. Theory The derivations of the Fourier transform of a polygon and polyhedron are presented. Methods The Fourier transform of a polyhedron was implemented and its accuracy in representing faceted and smooth surfaces was characterized. Realistic anthropomorphic polyhedral brain and torso phantoms were constructed and their use in simulated 3D/2D MRI acquisitions was described. Results Using polyhedra, the Fourier transform of faceted shapes can be computed to within machine precision. Smooth surfaces can be approximated with increasing accuracy by increasing the number of facets in the polyhedron; the additional accumulated numerical imprecision of the Fourier transform of polyhedra with many faces remained small. Simulations of 3D/2D brain and 2D torso cine acquisitions produced realistic reconstructions free of high frequency edge aliasing as compared to equivalent voxelized/rasterized phantoms. Conclusion Analytical polyhedral phantoms are easy to construct and can accurately simulate shapes of biomedical interest. PMID:26479724

A Comparison of Optical versus Hardware Fourier Transforms.

DTIC Science & Technology

1983-10-31

AD- R136 223 A COMPRISON’OF OPTICAL ERSUS HARDWARE FOURIER i/i.TRANSFORMS(U) VIRGINIA POLYTECHNIC INST AND STATE UNIV BLACKSBURG DEPT OF PHYSICS S P...transform and its inverse filtered Fourier transform obtained with the Digital Image Processing (DIP) hardware system located at the School of Aerospace...transparencies, and provided to us by Dr. Ralph G. Allen, Director of the Laser Effects Branch (Division of Radiation Sciences). The DIP system consisted of: an

Fourier analysis and signal processing by use of the Moebius inversion formula

NASA Technical Reports Server (NTRS)

Reed, Irving S.; Yu, Xiaoli; Shih, Ming-Tang; Tufts, Donald W.; Truong, T. K.

1990-01-01

A novel Fourier technique for digital signal processing is developed. This approach to Fourier analysis is based on the number-theoretic method of the Moebius inversion of series. The Fourier transform method developed is shown also to yield the convolution of two signals. A computer simulation shows that this method for finding Fourier coefficients is quite suitable for digital signal processing. It competes with the classical FFT (fast Fourier transform) approach in terms of accuracy, complexity, and speed.

Quantitative Frequency-Domain Passive Cavitation Imaging

PubMed Central

Haworth, Kevin J.; Bader, Kenneth B.; Rich, Kyle T.; Holland, Christy K.; Mast, T. Douglas

2017-01-01

Passive cavitation detection has been an instrumental technique for measuring cavitation dynamics, elucidating concomitant bioeffects, and guiding ultrasound therapies. Recently, techniques have been developed to create images of cavitation activity to provide investigators with a more complete set of information. These techniques use arrays to record and subsequently beamform received cavitation emissions, rather than processing emissions received on a single-element transducer. In this paper, the methods for performing frequency-domain delay, sum, and integrate passive imaging are outlined. The method can be applied to any passively acquired acoustic scattering or emissions, including cavitation emissions. In order to compare data across different systems, techniques for normalizing Fourier transformed data and converting the data to the acoustic energy received by the array are described. A discussion of hardware requirements and alternative imaging approaches are additionally outlined. Examples are provided in MATLAB. PMID:27992331

Double Fourier analysis for Emotion Identification in Voiced Speech

NASA Astrophysics Data System (ADS)

Sierra-Sosa, D.; Bastidas, M.; Ortiz P., D.; Quintero, O. L.

2016-04-01

We propose a novel analysis alternative, based on two Fourier Transforms for emotion recognition from speech. Fourier analysis allows for display and synthesizes different signals, in terms of power spectral density distributions. A spectrogram of the voice signal is obtained performing a short time Fourier Transform with Gaussian windows, this spectrogram portraits frequency related features, such as vocal tract resonances and quasi-periodic excitations during voiced sounds. Emotions induce such characteristics in speech, which become apparent in spectrogram time-frequency distributions. Later, the signal time-frequency representation from spectrogram is considered an image, and processed through a 2-dimensional Fourier Transform in order to perform the spatial Fourier analysis from it. Finally features related with emotions in voiced speech are extracted and presented.

Rapid update of discrete Fourier transform for real-time signal processing

NASA Astrophysics Data System (ADS)

Sherlock, Barry G.; Kakad, Yogendra P.

2001-10-01

In many identification and target recognition applications, the incoming signal will have properties that render it amenable to analysis or processing in the Fourier domain. In such applications, however, it is usually essential that the identification or target recognition be performed in real time. An important constraint upon real-time processing in the Fourier domain is the time taken to perform the Discrete Fourier Transform (DFT). Ideally, a new Fourier transform should be obtained after the arrival of every new data point. However, the Fast Fourier Transform (FFT) algorithm requires on the order of N log2 N operations, where N is the length of the transform, and this usually makes calculation of the transform for every new data point computationally prohibitive. In this paper, we develop an algorithm to update the existing DFT to represent the new data series that results when a new signal point is received. Updating the DFT in this way uses less computational order by a factor of log2 N. The algorithm can be modified to work in the presence of data window functions. This is a considerable advantage, because windowing is often necessary to reduce edge effects that occur because the implicit periodicity of the Fourier transform is not exhibited by the real-world signal. Versions are developed in this paper for use with the boxcar window, the split triangular, Hanning, Hamming, and Blackman windows. Generalization of these results to 2D is also presented.

Evaluation of GasmetTM DX-4015 Series Fourier Transform Infrared Gas Analyzer

DTIC Science & Technology

2009-06-01

penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number PLEASE DO NOT RETURN YOUR...Series FTIR Gas Analyzer Instrument test conditions simulated current ALS Increment 0 conditions. Briefly, unknown samples are collected in a "hot...a 1M cell. Emission radiation can be collected following a reflection or transmission process. Only one system is being considered and that system

The titanium oxide phi system

NASA Technical Reports Server (NTRS)

Galehouse, D. C.; Davis, S. P.

1980-01-01

The phy system of titanium oxide has been studied in emission in the near-infrared, with the Fourier transform spectrometer at a resolution of 8000,000. Approximately 3000 lines from 25 bands of this system have been identified, including all five 0-0 and 0-1 bands corresponding to the five natural titanium isotopes. Eleven vibrational levels have been observed, and all bands have been rotationally analyzed. Band intensities are agreement with known isotopic abundances and calculated Franck-Condon factors.

Infrared Multispectral Sensor Program, Phase 2. Field Measurements, Analysis and Modeling. Volume 1. Fourier Transform Spectrometer Sensor Characterization.

DTIC Science & Technology

1994-05-01

TskY=250K) ... 5-27 6-1. Treeline Correlation With 10.1 Microns ...................... 6-2 6-2. Mean Contrast: CARC Panel vs. Treeline ...6-3 6-3. CARC Panel and Treeline .............................. 6-5 6-4. Signal-to-Clutter Ratio for CARC Panel vs. Treeline ............. 6-6 6...5. Low Emissivity Panel and Treeline ......................... 6-7 xii TABLES 4-1: Sensor Characterization Test Summary ....................... 4-2 4

Synthesis and electrochemical properties of polyaniline nanofibers by interfacial polymerization.

PubMed

Manuel, James; Ahn, Jou-Hyeon; Kim, Dul-Sun; Ahn, Hyo-Jun; Kim, Ki-Won; Kim, Jae-Kwang; Jacobsson, Per

2012-04-01

Polyaniline nanofibers were prepared by interfacial polymerization with different organic solvents such as chloroform and carbon tetrachloride. Field emission scanning electron microscopy and transmission electron microscopy were used to study the morphological properties of polyaniline nanofibers. Chemical characterization was carried out using Fourier transform infrared spectroscopy, UV-Vis spectroscopy, and X-ray diffraction spectroscopy and surface area was measured using BET isotherm. Polyaniline nanofibers doped with lithium hexafluorophosphate were prepared and their electrochemical properties were evaluated.

SITELLE at the CFHT

NASA Astrophysics Data System (ADS)

Rousseau-Nepton, Laurie; Robert, Carmelle; Drissen, Laurent; Martin, R. Pierre; Martin, Thomas; SITELLE Collaboration

2017-03-01

SITELLE is the new imaging Fourier transform spectrograph of the Canada-France-Hawaii Telescope. It produces an impressive 4 million spectra in a single datacube in selected bandpasses from 350 to 900 nm. Its large FOV (11'x11') and its high spatial sampling (0.32''/pixel, seeing limited) allow us to study extended objects with an unprecedented view (Drissen et al. 2014). SITELLE's first observations of nearby galaxies revealed its capabilities to conduct detailed studies of emission line regions.

Reconnaissance gas measurements on the East Rift Zone of Kilauea Volcano, Hawai'i by Fourier transform infrared spectroscopy

USGS Publications Warehouse

McGee, Kenneth A.; Elias, Tamar; Sutton, A. Jefferson; Doukas, Michael P.; Zemek, Peter G.; Gerlach, Terrence M.

2005-01-01

We report the results of a set of measurements of volcanic gases on two small ground level plumes in the vicinity of Pu`u `O`o cone on the middle East Rift Zone (ERZ) of Kilauea volcano, Hawai`i on 15 June 2001 using open-path Fourier transform infrared (FTIR) spectroscopy. The work was carried out as a reconnaissance survey to assess the monitoring and research value of FTIR measurements at this volcano. Despite representing emissions of residual volatiles from lava that has undergone prior degassing, the plumes contained detectable amounts of CO2, CO, SO2, HCl, HF and SiF4. Various processes, including subsurface cooling, condensation of water in the atmospheric plume, oxidation, dissolution in water, and reactions with wall rocks at plume vents affect the abundance of these gases. Low concentrations of volcanic CO2 measured against a high ambient background are not well constrained by FTIR spectroscopy. Although there appear to be some differences between these gases and Pu`u `O`o source gases, ratios of HCl/SO2, HF/SO2 and CO/SO2 determined by FTIR measurements of these two small plumes compare reasonably well with earlier published analyses of ERZ vent samples. The measurements yielded emission rate estimates of 4, 11 and 4 t d-1

Laser and Fourier Transform Emission Spectroscopy of the G4Φ-X4Φ System of TiF

NASA Astrophysics Data System (ADS)

Ram, R. S.; Peers, J. R. D.; Teng, Ying; Adam, A. G.; Muntianu, A.; Bernath, P. F.; Davis, S. P.

1997-07-01

The emission spectrum of theG4Φ-X4Φ transition of TiF has been observed in the region 13 500-16 000 cm-1using a Fourier transform spectrometer (FTS), as well as by laser excitation spectroscopy. In the FTS experiments the bands were excited in a carbon tube furnace by the reaction of titanium metal vapor with CF4at a temperature of about 2300°C. In the laser experiments the TiF molecules were produced by laser vaporization of a Ti rod followed by reaction with SF6using a pulsed supersonic jet source. Three groups of bands with high-wavenumber subband heads at 14 388, 15 033, and 15 576 cm-1have been assigned as 0-1, 0-0, and 1-0 vibrational bands of theG4Φ-X4Φ transition, respectively. Each vibrational band consists of four subbands assigned as4Φ3/2-4Φ3/2,4Φ5/2-4Φ5/2,4Φ7/2-4Φ7/2, and4Φ9/2-4Φ9/2. A rotational analysis has been performed and molecular constants for the ground and excited states have been extracted using the combined FTS and laser excitation measurements. The correspondence between the electronic states of TiF, TiH, and Ti+has also been discussed.

Methane emission estimates using chamber and tracer release experiments for a municipal waste water treatment plant

NASA Astrophysics Data System (ADS)

Yver-Kwok, C. E.; Müller, D.; Caldow, C.; Lebègue, B.; Mønster, J. G.; Rella, C. W.; Scheutz, C.; Schmidt, M.; Ramonet, M.; Warneke, T.; Broquet, G.; Ciais, P.

2015-03-01

This study presents two methods for estimating methane emissions from a waste water treatment plant (WWTP) along with results from a measurement campaign at a WWTP in Valence, France. These methods, chamber measurements and tracer release, rely on Fourier Transform Infrared (FTIR) spectroscopy and Cavity Ring Down Spectroscopy (CRDS) instruments. We show that the tracer release method is suitable to quantify facility- and some process-scale emissions, while the chamber measurements, provide insight into individual process emissions. Uncertainties for the two methods are described and discussed. Applying the methods to CH4 emissions of the WWTP, we confirm that the open basins are not a major source of CH4 on the WWTP (about 10% of the total emissions), but that the pretreatment and sludge treatment are the main emitters. Overall, the waste water treatment plant represents a small part (about 1.5%) of the methane emissions of the city of Valence and its surroundings, which is lower than the national inventories.

Acoustic emission evolution during sliding friction of Hadfield steel single crystal

NASA Astrophysics Data System (ADS)

Lychagin, D. V.; Novitskaya, O. S.; Kolubaev, A. V.; Sizova, O. V.

2017-12-01

Friction is a complex dynamic process. Direct observation of processes occurring in the friction zone is impossible due to a small size of a real contact area and, as a consequence, requires various additional methods applicable to monitor a tribological contact state. One of such methods consists in the analysis of acoustic emission data of a tribological contact. The use of acoustic emission entails the problem of interpreting physical sources of signals. In this paper, we analyze the evolution of acoustic emission signal frames in friction of Hadfield steel single crystals. The chosen crystallographic orientation of single crystals enables to identify four stages related to friction development as well as acoustic emission signals inherent in these stages. Acoustic emission signal parameters are studied in more detail by the short-time Fourier transform used to determine the time variation of the median frequency and its power spectrum. The results obtained will facilitate the development of a more precise method to monitor the tribological contact based on the acoustic emission method.

Fourier transform-wavefront reconstruction for the pyramid wavefront sensor

NASA Astrophysics Data System (ADS)

Quirós-Pacheco, Fernando; Correia, Carlos; Esposito, Simone

The application of Fourier-transform reconstruction techniques to the pyramid wavefront sensor has been investigated. A preliminary study based on end-to-end simulations of an adaptive optics system with ≈40x40 subapertures and actuators shows that the performance of the Fourier-transform reconstructor (FTR) is of the same order of magnitude than the one obtained with a conventional matrix-vector multiply (MVM) method.

Polarization Ratio Determination with Two Identical Linearly Polarized Antennas

DTIC Science & Technology

2017-01-17

Fourier transform analysis of 21 measurements with one of the antennas rotating about its axis a circular polarization ratio is derived which can be...deter- mined directly from a discrete Fourier transform (DFT) of (5). However, leakage between closely spaced DFT bins requires improving the... Fourier transform and a mechanical antenna rotation to separate the principal and opposite circular polarization components followed by a basis

Generalized prolate spheroidal wave functions for optical finite fractional Fourier and linear canonical transforms.

PubMed

Pei, Soo-Chang; Ding, Jian-Jiun

2005-03-01

Prolate spheroidal wave functions (PSWFs) are known to be useful for analyzing the properties of the finite-extension Fourier transform (fi-FT). We extend the theory of PSWFs for the finite-extension fractional Fourier transform, the finite-extension linear canonical transform, and the finite-extension offset linear canonical transform. These finite transforms are more flexible than the fi-FT and can model much more generalized optical systems. We also illustrate how to use the generalized prolate spheroidal functions we derive to analyze the energy-preservation ratio, the self-imaging phenomenon, and the resonance phenomenon of the finite-sized one-stage or multiple-stage optical systems.

Theory and operational rules for the discrete Hankel transform.

PubMed

Baddour, Natalie; Chouinard, Ugo

2015-04-01

Previous definitions of a discrete Hankel transform (DHT) have focused on methods to approximate the continuous Hankel integral transform. In this paper, we propose and evaluate the theory of a DHT that is shown to arise from a discretization scheme based on the theory of Fourier-Bessel expansions. The proposed transform also possesses requisite orthogonality properties which lead to invertibility of the transform. The standard set of shift, modulation, multiplication, and convolution rules are derived. In addition to the theory of the actual manipulated quantities which stand in their own right, this DHT can be used to approximate the continuous forward and inverse Hankel transform in the same manner that the discrete Fourier transform is known to be able to approximate the continuous Fourier transform.

Sequential measurement of conjugate variables as an alternative quantum state tomography.

PubMed

Di Lorenzo, Antonio

2013-01-04

It is shown how it is possible to reconstruct the initial state of a one-dimensional system by sequentially measuring two conjugate variables. The procedure relies on the quasicharacteristic function, the Fourier transform of the Wigner quasiprobability. The proper characteristic function obtained by Fourier transforming the experimentally accessible joint probability of observing "position" then "momentum" (or vice versa) can be expressed as a product of the quasicharacteristic function of the two detectors and that unknown of the quantum system. This allows state reconstruction through the sequence (1) data collection, (2) Fourier transform, (3) algebraic operation, and (4) inverse Fourier transform. The strength of the measurement should be intermediate for the procedure to work.

Photonic fractional Fourier transformer with a single dispersive device.

PubMed

Cuadrado-Laborde, C; Carrascosa, A; Díez, A; Cruz, J L; Andres, M V

2013-04-08

In this work we used the temporal analog of spatial Fresnel diffraction to design a temporal fractional Fourier transformer with a single dispersive device, in this way avoiding the use of quadratic phase modulators. We demonstrate that a single dispersive passive device inherently provides the fractional Fourier transform of an incident optical pulse. The relationships linking the fractional Fourier transform order and scaling factor with the dispersion parameters are derived. We first provide some numerical results in order to prove the validity of our proposal, using a fiber Bragg grating as the dispersive device. Next, we experimentally demonstrate the feasibility of this proposal by using a spool of a standard optical fiber as the dispersive device.

Teaching Fourier optics through ray matrices

NASA Astrophysics Data System (ADS)

Moreno, I.; Sánchez-López, M. M.; Ferreira, C.; Davis, J. A.; Mateos, F.

2005-03-01

In this work we examine the use of ray-transfer matrices for teaching and for deriving some topics in a Fourier optics course, exploiting the mathematical simplicity of ray matrices compared to diffraction integrals. A simple analysis of the physical meaning of the elements of the ray matrix provides a fast derivation of the conditions to obtain the optical Fourier transform. We extend this derivation to fractional Fourier transform optical systems, and derive the order of the transform from the ray matrix. Some examples are provided to stress this point of view, both with classical and with graded index lenses. This formulation cannot replace the complete explanation of Fourier optics provided by the wave theory, but it is a complementary tool useful to simplify many aspects of Fourier optics and to relate them to geometrical optics.

Signal processing applications of massively parallel charge domain computing devices

NASA Technical Reports Server (NTRS)

Fijany, Amir (Inventor); Barhen, Jacob (Inventor); Toomarian, Nikzad (Inventor)

1999-01-01

The present invention is embodied in a charge coupled device (CCD)/charge injection device (CID) architecture capable of performing a Fourier transform by simultaneous matrix vector multiplication (MVM) operations in respective plural CCD/CID arrays in parallel in O(1) steps. For example, in one embodiment, a first CCD/CID array stores charge packets representing a first matrix operator based upon permutations of a Hartley transform and computes the Fourier transform of an incoming vector. A second CCD/CID array stores charge packets representing a second matrix operator based upon different permutations of a Hartley transform and computes the Fourier transform of an incoming vector. The incoming vector is applied to the inputs of the two CCD/CID arrays simultaneously, and the real and imaginary parts of the Fourier transform are produced simultaneously in the time required to perform a single MVM operation in a CCD/CID array.

Acoustic emission analysis for the detection of appropriate cutting operations in honing processes

NASA Astrophysics Data System (ADS)

Buj-Corral, Irene; Álvarez-Flórez, Jesús; Domínguez-Fernández, Alejandro

2018-01-01

In the present paper, acoustic emission was studied in honing experiments obtained with different abrasive densities, 15, 30, 45 and 60. In addition, 2D and 3D roughness, material removal rate and tool wear were determined. In order to treat the sound signal emitted during the machining process, two methods of analysis were compared: Fast Fourier Transform (FFT) and Hilbert Huang Transform (HHT). When density 15 is used, the number of cutting grains is insufficient to provide correct cutting, while clogging appears with densities 45 and 60. The results were confirmed by means of treatment of the sound signal. In addition, a new parameter S was defined as the relationship between energy in low and high frequencies contained within the emitted sound. The selected density of 30 corresponds to S values between 0.1 and 1. Correct cutting operations in honing processes are dependent on the density of the abrasive employed. The density value to be used can be selected by means of measurement and analysis of acoustic emissions during the honing operation. Thus, honing processes can be monitored without needing to stop the process.

Apparatus for direct-to-digital spatially-heterodyned holography

DOEpatents

Thomas, Clarence E.; Hanson, Gregory R.

2006-12-12

An apparatus operable to record a spatially low-frequency heterodyne hologram including spatially heterodyne fringes for Fourier analysis includes: a laser; a beamsplitter optically coupled to the laser; an object optically coupled to the beamsplitter; a focusing lens optically coupled to both the beamsplitter and the object; a digital recorder optically coupled to the focusing lens; and a computer that performs a Fourier transform, applies a digital filter, and performs an inverse Fourier transform. A reference beam and an object beam are focused by the focusing lens at a focal plane of the digital recorder to form a spatially low-frequency heterodyne hologram including spatially heterodyne fringes for Fourier analysis which is recorded by the digital recorder, and the computer transforms the recorded spatially low-frequency heterodyne hologram including spatially heterodyne fringes and shifts axes in Fourier space to sit on top of a heterodyne carrier frequency defined by an angle between the reference beam and the object beam and cuts off signals around an original origin before performing the inverse Fourier transform.

Stratospheric HBr mixing ratio obtained from far infrared emission spectra

NASA Technical Reports Server (NTRS)

Park, J. H.; Carli, B.; Barbis, A.

1989-01-01

Emission features of HBr isotopes have been identified in high-resolution FIR emission spectra obtained with a balloon-borne Fourier-transform spectrometer in the spring of 1979 at 32 deg N latitude. When six single-scan spectra at a zenith angle of 93.2 deg were averaged, two features of HBr isotopes at 50.054 and 50.069/cm were obtained with a signal-to-noise ratio of 2.5. The volume mixing ratio retrieved from the average spectrum is 2.0 x 10 to the -11th, which is assumed to be constant above 28 km, with an uncertainty of 35 percent. This stratospheric amount of HBr is about the same as the current level of tropospheric organic bromine compounds, 25 pptv. Thus HBr could be the major stratospheric bromine species.

Design of a Far-Infrared Spectrometer for Atmospheric Thermal Emission Measurements

NASA Technical Reports Server (NTRS)

Johnson, David G.

2004-01-01

Global measurements of far infrared emission from the upper troposphere are required to test models of cloud radiative forcing, water vapor continuum emission, and cooling rates. Spectra with adequate resolution can also be used for retrieving atmospheric temperature and humidity profiles, and yet there are few spectrally resolved measurements of outgoing longwave flux at wavelengths longer than 16 m. It has been difficult to make measurements in the far infrared due to the need for liquid-helium cooled detectors and large optics to achieve adequate sensitivity and bandwidth. We review design considerations for infrared Fourier transform spectrometers, including the dependence of system performance on basic system parameters, and discuss the prospects for achieving useful sensitivity from a satellite platform with a lightweight spectrometer using uncooled detectors.

Practical Sub-Nyquist Sampling via Array-Based Compressed Sensing Receiver Architecture

DTIC Science & Technology

2016-07-10

different array ele- ments at different sub-Nyquist sampling rates. Signal processing inspired by the sparse fast Fourier transform allows for signal...reconstruction algorithms can be computationally demanding (REF). The related sparse Fourier transform algorithms aim to reduce the processing time nec- essary to...compute the DFT of frequency-sparse signals [7]. In particular, the sparse fast Fourier transform (sFFT) achieves processing time better than the

Discrete fourier transform (DFT) analysis for applications using iterative transform methods

NASA Technical Reports Server (NTRS)

Dean, Bruce H. (Inventor)

2012-01-01

According to various embodiments, a method is provided for determining aberration data for an optical system. The method comprises collecting a data signal, and generating a pre-transformation algorithm. The data is pre-transformed by multiplying the data with the pre-transformation algorithm. A discrete Fourier transform of the pre-transformed data is performed in an iterative loop. The method further comprises back-transforming the data to generate aberration data.

STRUCTURE IN THE 3D GALAXY DISTRIBUTION: III. FOURIER TRANSFORMING THE UNIVERSE: PHASE AND POWER SPECTRA.

PubMed

Scargle, Jeffrey D; Way, M J; Gazis, P R

2017-04-10

We demonstrate the effectiveness of a relatively straightforward analysis of the complex 3D Fourier transform of galaxy coordinates derived from redshift surveys. Numerical demonstrations of this approach are carried out on a volume-limited sample of the Sloan Digital Sky Survey redshift survey. The direct unbinned transform yields a complex 3D data cube quite similar to that from the Fast Fourier Transform (FFT) of finely binned galaxy positions. In both cases deconvolution of the sampling window function yields estimates of the true transform. Simple power spectrum estimates from these transforms are roughly consistent with those using more elaborate methods. The complex Fourier transform characterizes spatial distributional properties beyond the power spectrum in a manner different from (and we argue is more easily interpreted than) the conventional multi-point hierarchy. We identify some threads of modern large scale inference methodology that will presumably yield detections in new wider and deeper surveys.

STRUCTURE IN THE 3D GALAXY DISTRIBUTION: III. FOURIER TRANSFORMING THE UNIVERSE: PHASE AND POWER SPECTRA

PubMed Central

Scargle, Jeffrey D.; Way, M. J.; Gazis, P. R.

2017-01-01

We demonstrate the effectiveness of a relatively straightforward analysis of the complex 3D Fourier transform of galaxy coordinates derived from redshift surveys. Numerical demonstrations of this approach are carried out on a volume-limited sample of the Sloan Digital Sky Survey redshift survey. The direct unbinned transform yields a complex 3D data cube quite similar to that from the Fast Fourier Transform (FFT) of finely binned galaxy positions. In both cases deconvolution of the sampling window function yields estimates of the true transform. Simple power spectrum estimates from these transforms are roughly consistent with those using more elaborate methods. The complex Fourier transform characterizes spatial distributional properties beyond the power spectrum in a manner different from (and we argue is more easily interpreted than) the conventional multi-point hierarchy. We identify some threads of modern large scale inference methodology that will presumably yield detections in new wider and deeper surveys. PMID:29628519

Structure in the 3D Galaxy Distribution: III. Fourier Transforming the Universe: Phase and Power Spectra

NASA Technical Reports Server (NTRS)

Scargle, Jeffrey D.; Way, M. J.; Gazis, P. R.

2017-01-01

We demonstrate the effectiveness of a relatively straightforward analysis of the complex 3D Fourier transform of galaxy coordinates derived from redshift surveys. Numerical demonstrations of this approach are carried out on a volume-limited sample of the Sloan Digital Sky Survey redshift survey. The direct unbinned transform yields a complex 3D data cube quite similar to that from the Fast Fourier Transform (FFT) of finely binned galaxy positions. In both cases deconvolution of the sampling window function yields estimates of the true transform. Simple power spectrum estimates from these transforms are roughly consistent with those using more elaborate methods. The complex Fourier transform characterizes spatial distributional properties beyond the power spectrum in a manner different from (and we argue is more easily interpreted than) the conventional multi-point hierarchy. We identify some threads of modern large scale inference methodology that will presumably yield detections in new wider and deeper surveys.

Structural and Luminescent property of Holmium doped Borate Glasses

NASA Astrophysics Data System (ADS)

Usharani, V. L.; Eraiah, B.

2018-02-01

Holmium doped Lithium Lead Borate glasses of different compositions were prepared by melt quenching technique. Fourier transform infrared investigations on lithium lead borate glasses have been made to study the local order and vibrations of atoms in the glass network and it contains mainly BO3 and BO4 structural units. Photoluminescence techniques were employed to investigate the luminescent property of these glasses excited at 451nm. Blue emission have been observed from the transition 495 (5F3 → 5I8).

Electrical conductivity and morphology of electrochemical synthesized polyaniline/CuO nano composites

NASA Astrophysics Data System (ADS)

Ashokkumar, S. P.; Yesappa, L.; Vijeth, H.; Niranjana, M.; Devendrappa, H.

2018-05-01

Polyaniline (PANI) and Polyaniline/CuO nanocomposite have been synthesized by using electrochemical deposition method. The composite was characterized using Fourier transform infra-red spectroscopy (FT-IR) to confirm the chemical interaction changes, micro structural morphology was done by Field Emission Scanning Electronic Microscopy (FESEM) and High Resolution Transmission Electron Microscopy (HRTEM). The dielectric constant and AC conductivity are found to increases with increase in temperature range (303 to 393K), these results shows enhancement in electrical conductivity due to effect of nanocomposite.

Simulating first order optical systems—algorithms for and composition of discrete linear canonical transforms

NASA Astrophysics Data System (ADS)

Healy, John J.

2018-01-01

The linear canonical transforms (LCTs) are a parameterised group of linear integral transforms. The LCTs encompass a number of well-known transformations as special cases, including the Fourier transform, fractional Fourier transform, and the Fresnel integral. They relate the scalar wave fields at the input and output of systems composed of thin lenses and free space, along with other quadratic phase systems. In this paper, we perform a systematic search of all algorithms based on up to five stages of magnification, chirp multiplication and Fourier transforms. Based on that search, we propose a novel algorithm, for which we present numerical results. We compare the sampling requirements of three algorithms. Finally, we discuss some issues surrounding the composition of discrete LCTs.

Detection of emission sources using passive-remote Fourier transform infrared spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Demirgian, J.C.; Macha, S.M.; Darby, S.M.

1995-12-31

The detection and identification of toxic chemicals released in the environment is important for public safety. Passive-remote Fourier transform infrared (FTIR) spectrometers can be used to detect these releases. Their primary advantages are their small size and ease of setup and use. Open-path FTIR spectrometers are used to detect concentrations of pollutants from a fixed frame of reference. These instruments detect plumes, but they are too large and difficult to aim to be used to track a plume to its source. Passive remote FTIR spectrometers contain an interferometer, optics, and a detector. They can be used on tripods and inmore » some cases can be hand-held. A telescope can be added to most units. The authors will discuss the capability of passive-remote FTIR spectrometers to detect the origin of plumes. Low concentration plumes were released using a custom-constructed vaporizer. These plumes were detected with different spectrometers from different distances. Passive-remote spectrometers were able to detect small 10 cm on a side chemical releases at concentration-pathlengths at the low parts per million-meter (ppm-m) level.« less

Detection of emission sources using passive-remote Fourier transform infrared spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Demirgian, J.C.; Macha, S.M.; Darby, S.M.

1995-04-01

The detection and identification of toxic chemicals released in the environment is important for public safety. Passive-remote Fourier transform infrared (FTIR) spectrometers can be used to detect these releases. Their primary advantages are their small size and ease of setup and use. Open-path FTIR spectrometers are used to detect concentrations of pollutants from a fixed frame of reference. These instruments detect plumes, but they are too large and difficult to aim to be used to track a plume to its source. Passive remote FTIR spectrometers contain an interferometer, optics, and a detector. They can be used on tripods and inmore » some cases can be hand-held. A telescope can be added to most units. We will discuss the capability of passive-remote FTIR spectrometers to detect the origin of plumes. Low concentration plumes were released using a custom-constructed vaporizer. These plumes were detected with different spectrometers from different distances. Passive-remote spectrometers were able to detect small 10 cm on a side chemical releases at concentration-pathlengths at the low parts per million-meter (ppm-m) level.« less

Comparison of Fourier transform infrared spectrometry and 2,4-dinitrophenylhydrazine impinger techniques for the measurement of formaldehyde in vehicle exhaust

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haack, L.P.; LaCourse, D.L.; Korniski, T.J.

1986-01-01

Experiments were conducted to validate a Fourier transform infrared (FT-IR) sampling and analysis system for measurement of trace gases in vehicle exhaust utilizing gasoline-, gasohol-, diesel-, and methanol-fueled vehicles as the emission source and formaldehyde (HCHO) as the test molecule. The 2,4-dinitrophenylhydrazine impinger method was chosen as the reference method. Diluted exhaust was drawn continuously though the FT-IR cell and measured every 3 s. The FT-IR signals were averaged over a complete driving-test cycle and compared to the concentration determined from concurrent impinger sampling. By impinger measurements it was shown that HCHO losses between the tailpipe and the FT-IR cellmore » were on the order of only 5%, independent of vehicle type or HCHO concentration (0.02-8.5 ppm). Comparisons between FT-IR and impinger measurements on 43 tests of methanol-fueled vehicles under transient conditions (diluted-exhaust HCHO 0.28-8.5 ppm) showed FT-IR/impinger = 1.055 +/- 0.095. 19 references, 5 figures, 5 tables.« less

Quantification of microplastic mass and removal rates at wastewater treatment plants applying Focal Plane Array (FPA)-based Fourier Transform Infrared (FT-IR) imaging.

PubMed

Simon, Márta; van Alst, Nikki; Vollertsen, Jes

2018-05-17

This paper presents a method for microplastic (MP) mass quantification using a Focal Plane Array-based Fourier Transform Infrared imaging technique. It discusses the issue that particle number is not a conserved base quantity and hence less suited than mass to compare independent studies on MP in the environment. It concludes that MP mass should be included when quantifying MP pollution in the environment, supplementing the conventional approach of reporting particle numbers. Applying mass as the unit of MP measurement, the paper presents data showing that Danish wastewater treatment plants discharge around 3 t/year of MP in the size range 10-500 μm. This value corresponds to an annual per capita emission from these plants of 0.56 g MP/(capita year). The distribution of polymer types by mass and particle number differed because the size of MP particles of the different material types varied. Copyright © 2018 The Authors. Published by Elsevier Ltd.. All rights reserved.

In situ characterization of the oxidative degradation of a polymeric light emitting device

NASA Astrophysics Data System (ADS)

Cumpston, B. H.; Parker, I. D.; Jensen, K. F.

1997-04-01

Light-emitting devices with polymeric emissive layers have great promise for the production of large-area, lightweight, flexible color displays, but short lifetimes currently limit applications. We address mechanisms of bulk polymer degradation in these devices and show through in situ Fourier transform infrared characterization of working light-emitting devices with active layers of poly[2-methoxy,5-(2'-ethyl-hexoxy)-1,4-phenylene vinylene] that oxygen is responsible for the degradation of the polymer film. A mechanism is given based on the formation of singlet oxygen from oxygen impurities in the film via energy transfer from a nonradiative exciton. Fourier transform infrared and x-ray photoelectron spectroscopy results are consistent with the mechanism, involving singlet oxygen attack followed by free radical processes. We further show that oxygen readily diffuses into the active polymer layer, changing the electrical characteristics of the film even at low concentrations. Thus, polyphenylene-vinylene-based light-emitting devices will self-destruct during operation if fabricated without special attention to eliminating oxygen contamination during fabrication and device operation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zia-ul-Mustafa, M., E-mail: engr.ziamustafa@gmail.com; Ahmad, Faiz; Megat-Yusoff, Puteri S. M.

In this study, intumescent fire retardant coatings (IFRC) were developed to investigate the synergistic effects of reinforced mica and wollastonite fillers based IFRC towards heat shielding, char expansion, char composition and char morphology. Ammonium poly-phosphate (APP) was used as acid source, expandable graphite (EG) as carbon source, melamine as blowing agent, boric acid as additive and Hardener H-2310 polyamide amine in bisphenol A epoxy resin BE-188(BPA) was used as curing agent. Bunsen burner fire test was used for thermal performance according to UL-94 for 1 h. Field Emission Scanning Electron Microscopy (FESEM) was used to observe char microstructure. X-Ray Diffraction (XRD)more » and Fourier transform infrared spectroscopy (FTIR) were used to analyse char composition. The results showed that addition of clay filler in IFRC enhanced the fire protection performance of intumescent coating. X-Ray Diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) results showed the presence of boron phosphate, silicon phosphate oxide, aluminium borate in the char that improved the thermal performance of intumescent fire retardant coating (IFRC). Resultantly, the presence of these developed compounds enhanced the Integrity of structural steel upto 500°C.« less

Synthesis and Characterization of YVO4-Based Phosphor Doped with Eu3+ Ions for Display Devices

NASA Astrophysics Data System (ADS)

Thakur, Shashi; Gathania, Arvind K.

2015-10-01

YVO4:Eu nanophosphor has been synthesized by the sol-gel method. Samples were characterized by x-ray diffraction (XRD), energy-dispersive x-ray spectroscopy, Fourier-transform infrared spectroscopy, ultraviolet-visible (UV-Vis) spectroscopy, photoluminescence, and Raman spectroscopy. The XRD profile confirms the tetragonal phase of the Eu3+-doped YVO4 nanophosphor. The efficiency of the prepared phosphor was analyzed by means of its emission spectral profile. We also observed rich red emission from the prepared phosphor on excitation by an ultraviolet source. The calculated Commission International de l'Éclairage coordinates reveal excellent color purity efficiency. Such luminescent powder is useful as red phosphor in display device applications.

Comparison of the gaseous and particulate matter emissions from the combustion of agricultural and forest biomasses.

PubMed

Brassard, Patrick; Palacios, Joahnn H; Godbout, Stéphane; Bussières, Denis; Lagacé, Robert; Larouche, Jean-Pierre; Pelletier, Frédéric

2014-03-01

The aim of this study was to compare gaseous and particulate matter (PM) emissions from the combustion of agricultural (switchgrass, fast-growing willow and the dried solid fraction of pig manure) and forest (wood mixture of Black Spruce and Jack Pine) biomasses in a small-scale unit (17.58kW). Concentrations of CO2, CO, CH4, NO2, NH3, N2O, SO2, HCl, and H2O were measured by Fourier transform infrared spectroscopy and converted into emission rates. Opacity was also evaluated and particulates were sampled. Results showed significantly higher emissions of SO2, NO2 and PM with the combustion of agricultural biomass compared to the forest biomass. However, further studies should be carried out so regulations can be adapted in order to permit the combustion of agricultural biomass in small-scale combustion units. Copyright © 2013 Elsevier Ltd. All rights reserved.

Infrared reflectance spectra (4-12 micron) of lunar samples

NASA Technical Reports Server (NTRS)

Nash, Douglas B.

1991-01-01

Presented here are infrared reflectance spectra of a typical set of Apollo samples to illustrate spectral character in the mid-infrared (4 to 12 microns) of lunar materials and how the spectra varies among three main forms: soil, breccia, and igneous rocks. Reflectance data, to a close approximation, are the inverse of emission spectra; thus, for a given material the spectral reflectance (R) at any given wavelength is related to emission (E) by 1 - R equals E. Therefore, one can use reflectance spectra of lunar samples to predict how emission spectra of material on the lunar surface will appear to spectrometers on orbiting spacecraft or earthbound telescopes. Spectra were measured in the lab in dry air using a Fourier Transform Infrared spectrometer. Shown here is only the key portion (4 to 12 microns) of each spectrum relating to the principal spectral emission region for sunlit lunar materials and to where the most diagnostic spectral features occur.

An Investigation into the Use of Spatially-Filtered Fourier Transforms to Classify Mammary Lesions.

DTIC Science & Technology

difference in Fourier space between lesioned breast tissue which would enable accurate computer classification of benign and malignant lesions. Low...separate benign and malignant breast tissue. However, no success was achieved when using two-dimensional Fourier transform and power spectrum analysis. (Author)

Detection of Fast Moving and Accelerating Targets Compensating Range and Doppler Migration

DTIC Science & Technology

2014-06-01

Radon -Fourier transform has been introduced to realize long- term coherent integration of the moving targets with range migration [8, 9]. Radon ...2010) Long-time coherent integration for radar target detection base on Radon -Fourier transform, in Proceedings of the IEEE Radar Conference, pp...432–436. 9. Xu, J., Yu, J., Peng, Y. & Xia, X. (2011) Radon -Fourier transform for radar target detection, I: Generalized Doppler filter bank, IEEE

Effect of different surfactants on structural and optical properties of Ce3+ and Tb3+ co-doped BiPO4 nanostructures

NASA Astrophysics Data System (ADS)

Lakshminarayana, G.; Dao, T. D.; Chen, K.; Sharma, Manoj; Takeda, T.; Brik, M. G.; Kityk, I. V.; Singh, Sarabjot; Nagao, T.

2015-01-01

In this paper we report on the Ce3+ and Tb3+ ions co-doped bismuth phosphate (BiPO4) nanostructures that were synthesized by a simple precipitation method using different surfactants such as glycerol/H2O, glycerol/ethylene glycol, oleic acid, and ethylene glycol. The structural (X-ray diffraction, scanning electron microscopy, tunneling electron microscopy), functional groups analysis (Fourier transform infrared and Raman spectroscopy), thermal (thermogravimetry and differential thermal analysis), and optical (photoluminescence, photoluminescence-excitation) properties were investigated. The structural and morphological analysis confirms the pure hexagonal crystal structure of the synthesized nanostructures. From the measured Fourier transform infrared (FTIR) and Raman spectra various functional groups such as υ3 stretching vibration of the PO4 group, and δ(O-P-O) and υ4 (PO4) vibrations including the υ2 and υ1 bending modes of the PO4 units are identified. Based on the thermal analysis, for all the studied samples an exothermic peak between 680 °C and 700 °C was observed due to phase transition from hexagonal to high temperature monoclinic. The Ce3+and Tb3+ codoped samples show spectrally broad 5d → 4f luminescence in the blue (centered at 459 nm) wavelength region under the direct optical excitation of Ce3+ at 417 nm. Similarly, Tb3+ has revealed four main emission bands (5D4 → 7F6, 5, 4 and 3) at 490 nm, 545 nm, 585 nm and 621 nm with 378 nm (7F6 → 5G6) as the excitation wavelength, including three more weak emission bands at 647 nm, 669 nm, and 681 nm which could be assigned to 5D4 → 7F2, 1, 0 emission transitions. Among them, 545 nm (5D4 → 7F5) has shown bright green emission. The Ce3+ and Tb3+ codoped sample synthesized with pure oleic acid have shown relatively high green emission intensity for Tb3+, and relatively weak blue emission intensity for Ce3+ under their respective optical excitation wavelengths.

High resolution emission Fourier transform infrared spectra of the 4p-5s and 5p-6s bands of ArH.

PubMed

Baskakov, O I; Civis, S; Kawaguchi, K

2005-03-15

In the 2500-8500 cm(-1) region several strong emission bands of (40)ArH were observed by Fourier transform spectroscopy through a dc glow discharge in a mixture of argon and hydrogen. Rotational-electronic transitions of the two previously unstudied 4p-5s and 5p-6s,v = 0-0, bands of (40)ArH were measured and assigned in the 6060 and 3770 cm(-1) regions, respectively. A simultaneous fit of the emission transitions of the 4p-5s and 5p-6s bands and an extended set of transitions of the 6s-4p band observed by Dabrowski, Tokaryk, and Watson [J. Mol. Spectrosc. 189, 95 (1998)] and remeasured in the present work yielded consistent values of the spectroscopic parameters of the electronic states under investigation. In the branch of the 4p-5s band with transitions of type (Q)Q(f(3)e) we observed a narrowing in the linewidths with increasing rotational quantum number N. The rotational dependence of the linewidth is caused by predissociation of the 5s state by the repulsive ground 4s state through homogeneous coupling and changes in overlap integrals of the vibrational wave functions with the rotational level. Analysis was based on the Fermi's golden rule approximation model. In the 4p-5s band region a vibrational sequence ofv(')-v(")=1-1, 2-2, and 3-3 were recorded and a number of transitions belonging to the strongest (Q)Q(f(3)e) form branch of the 1-1 band were analyzed.

A Primer of Fourier Transform NMR.

ERIC Educational Resources Information Center

Macomber, Roger S.

1985-01-01

Fourier transform nuclear magnetic resonance (NMR) is a new spectroscopic technique that is often omitted from undergraduate curricula because of lack of instructional materials. Therefore, information is provided to introduce students to the technique of data collection and transformation into the frequency domain. (JN)

Geometric Representations for Discrete Fourier Transforms

NASA Technical Reports Server (NTRS)

Cambell, C. W.

1986-01-01

Simple geometric representations show symmetry and periodicity of discrete Fourier transforms (DFT's). Help in visualizing requirements for storing and manipulating transform value in computations. Representations useful in any number of dimensions, but particularly in one-, two-, and three-dimensional cases often encountered in practice.

Sparsity guided empirical wavelet transform for fault diagnosis of rolling element bearings

NASA Astrophysics Data System (ADS)

Wang, Dong; Zhao, Yang; Yi, Cai; Tsui, Kwok-Leung; Lin, Jianhui

2018-02-01

Rolling element bearings are widely used in various industrial machines, such as electric motors, generators, pumps, gearboxes, railway axles, turbines, and helicopter transmissions. Fault diagnosis of rolling element bearings is beneficial to preventing any unexpected accident and reducing economic loss. In the past years, many bearing fault detection methods have been developed. Recently, a new adaptive signal processing method called empirical wavelet transform attracts much attention from readers and engineers and its applications to bearing fault diagnosis have been reported. The main problem of empirical wavelet transform is that Fourier segments required in empirical wavelet transform are strongly dependent on the local maxima of the amplitudes of the Fourier spectrum of a signal, which connotes that Fourier segments are not always reliable and effective if the Fourier spectrum of the signal is complicated and overwhelmed by heavy noises and other strong vibration components. In this paper, sparsity guided empirical wavelet transform is proposed to automatically establish Fourier segments required in empirical wavelet transform for fault diagnosis of rolling element bearings. Industrial bearing fault signals caused by single and multiple railway axle bearing defects are used to verify the effectiveness of the proposed sparsity guided empirical wavelet transform. Results show that the proposed method can automatically discover Fourier segments required in empirical wavelet transform and reveal single and multiple railway axle bearing defects. Besides, some comparisons with three popular signal processing methods including ensemble empirical mode decomposition, the fast kurtogram and the fast spectral correlation are conducted to highlight the superiority of the proposed method.

Atise: a miniature Fourier-transform spectro-imaging concept for surveying auroras and airglow monitoring from a 6/12u cubesat

NASA Astrophysics Data System (ADS)

Le Courer, E.; Barthelemy, M.; Vialatte, A.; Prugniaux, M.; Bourdarot, G.; Sequies, T.; Monsinjon, P.; Puget, R.; Guerineau, N.

2017-09-01

The nanosatellite ATISE is a mission dedicated to the observation of the emission spectra of the upper atmosphere (i.e. Airglow and Auroras) mainly related to both the solar UV flux and the precipitation of suprathermal particles coming from the solar wind through the magnetosphere. ATISE will measure specifically the auroral emissions, and the airglow (day- and night) in the spectral range between 380 and 900 nm at altitudes between 100 and 350 km. The exposure time will be 1 second in auroral region and 20 s at low latitude regions. The 5 year expected lifetime of this mission should cover almost a half of solar cycle (2 years nominal). This instrument concept is based on an innovative miniaturized Fourier-transform spectrometer (FTS) allowing simultaneous 1 Rayleigh sensitivity detection along six 1.5°x1° limb lines of sight. This 1-2kg payload instrument is hosted in a 12U cubeSat where 6U are allocated to the payload and 6U to the plateform subsystems. This represents a miniaturisation by a factor of 500 on weight and volume compared to previous Arizona-GLO instrument for equivalent performances in the visible. The instrument is based on microSPOC concept developed by ONERA and IPAG using one Fizeau interferometer per line of sight directly glued on top of the half of a very sensitive CMOS Pyxalis HDPYX detector. Three detectors are necessary with a total electrical consumption compatible with a 6U nanoSat. Each interferometer occupies a 1.4 M pixel part of detector, each is placed on an image of the entrance pupil corresponding to a unique direction of the six lines of sight, this in order to have a uniform illumination permitting good spectral Fourier reconstruction from fringes created between the Fizeau plate and the detector itself. Despite a limited 8x6 cm telescope, this configuration takes advantage of FTS multiplex effect and permits us to maximize the throughput and to integrate very faint emission lines over a wide field of view even if the 1 second integrated signal is comparable to the detector noise.

Fourier Transforms of Pulses Containing Exponential Leading and Trailing Profiles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warshaw, S I

2001-07-15

In this monograph we discuss a class of pulse shapes that have exponential rise and fall profiles, and evaluate their Fourier transforms. Such pulses can be used as models for time-varying processes that produce an initial exponential rise and end with the exponential decay of a specified physical quantity. Unipolar examples of such processes include the voltage record of an increasingly rapid charge followed by a damped discharge of a capacitor bank, and the amplitude of an electromagnetic pulse produced by a nuclear explosion. Bipolar examples include acoustic N waves propagating for long distances in the atmosphere that have resultedmore » from explosions in the air, and sonic booms generated by supersonic aircraft. These bipolar pulses have leading and trailing edges that appear to be exponential in character. To the author's knowledge the Fourier transforms of such pulses are not generally well-known or tabulated in Fourier transform compendia, and it is the purpose of this monograph to derive and present these transforms. These Fourier transforms are related to a definite integral of a ratio of exponential functions, whose evaluation we carry out in considerable detail. From this result we derive the Fourier transforms of other related functions. In all Figures showing plots of calculated curves, the actual numbers used for the function parameter values and dependent variables are arbitrary and non-dimensional, and are not identified with any particular physical phenomenon or model.« less

A Short-Segment Fourier Transform Methodology

DTIC Science & Technology

2009-03-01

defined sampling of the continuous-valued discrete-time Fourier transform, superresolution in the frequency domain and allowance of Dirac delta functions associated with pure sinusoidal input data components.

40 CFR 98.414 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... appropriate detector, infrared (IR), fourier transform infrared (FTIR), and nuclear magnetic resonance (NMR... Compounds by Extractive Direct Interface Fourier Transform Infrared (FTIR) Spectroscopy (incorporated by...

40 CFR 98.414 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... appropriate detector, infrared (IR), fourier transform infrared (FTIR), and nuclear magnetic resonance (NMR... Compounds by Extractive Direct Interface Fourier Transform Infrared (FTIR) Spectroscopy (incorporated by...

40 CFR 98.414 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... appropriate detector, infrared (IR), fourier transform infrared (FTIR), and nuclear magnetic resonance (NMR... Compounds by Extractive Direct Interface Fourier Transform Infrared (FTIR) Spectroscopy (incorporated by...

40 CFR 98.414 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... appropriate detector, infrared (IR), fourier transform infrared (FTIR), and nuclear magnetic resonance (NMR... Compounds by Extractive Direct Interface Fourier Transform Infrared (FTIR) Spectroscopy (incorporated by...

Effectiveness of selective catalytic reduction systems on reducing gaseous emissions from an engine using diesel and biodiesel blends.

PubMed

Borillo, Guilherme C; Tadano, Yara S; Godoi, Ana F L; Santana, Simone S M; Weronka, Fernando M; Penteado Neto, Renato A; Rempel, Dennis; Yamamoto, Carlos I; Potgieter-Vermaak, Sanja; Potgieter, Johannes H; Godoi, Ricardo H M

2015-03-03

The aim of this investigation was to quantify organic and inorganic gas emissions from a four-cylinder diesel engine equipped with a urea selective catalytic reduction (SCR) system. Using a bench dynamometer, the emissions from the following mixtures were evaluated using a Fourier transform infrared (FTIR) spectrometer: low-sulfur diesel (LSD), ultralow-sulfur diesel (ULSD), and a blend of 20% soybean biodiesel and 80% ULSD (B20). For all studied fuels, the use of the SCR system yielded statistically significant (p < 0.05) lower NOx emissions. In the case of the LSD and ULSD fuels, the SCR system also significantly reduced emissions of compounds with high photochemical ozone creation potential, such as formaldehyde. However, for all tested fuels, the SCR system produced significantly (p < 0.05) higher emissions of N2O. In the case of LSD, the NH3 emissions were elevated, and in the case of ULSD and B20 fuels, the non-methane hydrocarbon (NMHC) and total hydrocarbon of diesel (HCD) emissions were significantly higher.

Emissions of Trace Gases and Particles from Savanna Fires in Southern Africa

NASA Technical Reports Server (NTRS)

Sinha, Parikhit; Hobbs, Peter V.; Yokelson, Robert J.; Bertschi, Isaac T.; Blake, Donald R.; Simpson, Isobel J.; Gao, Song; Kirchstetter, Thomas W.; Novakov, Tica

2003-01-01

Airborne measurements made on initial smoke from 10 savanna fires in southern Africa provide quantitative data on emissions of 50 gaseous and particulate species, including carbon dioxide, carbon monoxide, sulfur dioxide, nitrogen oxides, methane, ammonia, dimethyl sulfide, nonmethane organic compounds, halocarbons, gaseous organic acids, aerosol ionic components, carbonaceous aerosols, and condensation nuclei (CN). Measurements of several of the gaseous species by gas chromatography and Fourier transform infrared spectroscopy are compared. Emission ratios and emission factors are given for eight species that have not been reported previously for biomass burning of savanna in southern Africa (namely, dimethyl sulfide, methyl nitrate, five hydrocarbons, and particles with diameters from 0.1 to 3 microns). The emission factor that we measured for ammonia is lower by a factor of 4, and the emission factors for formaldehyde, hydrogen cyanide, and CN are greater by factors of about 3, 20, and 3 - 15, respectively, than previously reported values. The new emission factors are used to estimate annual emissions of these species from savanna fires in Africa and worldwide.

Analysis and application of Fourier transform spectroscopy in atmospheric remote sensing

NASA Technical Reports Server (NTRS)

Park, J. H.

1984-01-01

An analysis method for Fourier transform spectroscopy is summarized with applications to various types of distortion in atmospheric absorption spectra. This analysis method includes the fast Fourier transform method for simulating the interferometric spectrum and the nonlinear least-squares method for retrieving the information from a measured spectrum. It is shown that spectral distortions can be simulated quite well and that the correct information can be retrieved from a distorted spectrum by this analysis technique.

Robust alignment of chromatograms by statistically analyzing the shifts matrix generated by moving window fast Fourier transform cross-correlation.

PubMed

Zhang, Mingjing; Wen, Ming; Zhang, Zhi-Min; Lu, Hongmei; Liang, Yizeng; Zhan, Dejian

2015-03-01

Retention time shift is one of the most challenging problems during the preprocessing of massive chromatographic datasets. Here, an improved version of the moving window fast Fourier transform cross-correlation algorithm is presented to perform nonlinear and robust alignment of chromatograms by analyzing the shifts matrix generated by moving window procedure. The shifts matrix in retention time can be estimated by fast Fourier transform cross-correlation with a moving window procedure. The refined shift of each scan point can be obtained by calculating the mode of corresponding column of the shifts matrix. This version is simple, but more effective and robust than the previously published moving window fast Fourier transform cross-correlation method. It can handle nonlinear retention time shift robustly if proper window size has been selected. The window size is the only one parameter needed to adjust and optimize. The properties of the proposed method are investigated by comparison with the previous moving window fast Fourier transform cross-correlation and recursive alignment by fast Fourier transform using chromatographic datasets. The pattern recognition results of a gas chromatography mass spectrometry dataset of metabolic syndrome can be improved significantly after preprocessing by this method. Furthermore, the proposed method is available as an open source package at https://github.com/zmzhang/MWFFT2. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Implementation of the semiclassical quantum Fourier transform in a scalable system.

PubMed

Chiaverini, J; Britton, J; Leibfried, D; Knill, E; Barrett, M D; Blakestad, R B; Itano, W M; Jost, J D; Langer, C; Ozeri, R; Schaetz, T; Wineland, D J

2005-05-13

We report the implementation of the semiclassical quantum Fourier transform in a system of three beryllium ion qubits (two-level quantum systems) confined in a segmented multizone trap. The quantum Fourier transform is the crucial final step in Shor's algorithm, and it acts on a register of qubits to determine the periodicity of the quantum state's amplitudes. Because only probability amplitudes are required for this task, a more efficient semiclassical version can be used, for which only single-qubit operations conditioned on measurement outcomes are required. We apply the transform to several input states of different periodicities; the results enable the location of peaks corresponding to the original periods. This demonstration incorporates the key elements of a scalable ion-trap architecture, suggesting the future capability of applying the quantum Fourier transform to a large number of qubits as required for a useful quantum factoring algorithm.

[Using 2-DCOS to identify the molecular spectrum peaks for the isomer in the multi-component mixture gases Fourier transform infrared analysis].

PubMed

Zhao, An-Xin; Tang, Xiao-Jun; Zhang, Zhong-Hua; Liu, Jun-Hua

2014-10-01

The generalized two-dimensional correlation spectroscopy and Fourier transform infrared were used to identify hydrocarbon isomers in the mixed gases for absorption spectra resolution enhancement. The Fourier transform infrared spectrum of n-butane and iso-butane and the two-dimensional correlation infrared spectrum of concentration perturbation were used for analysis as an example. The all band and the main absorption peak wavelengths of Fourier transform infrared spectrum for single component gas showed that the spectra are similar, and if they were mixed together, absorption peaks overlap and peak is difficult to identify. The synchronous and asynchronous spectrum of two-dimensional correlation spectrum can clearly identify the iso-butane and normal butane and their respective characteristic absorption peak intensity. Iso-butane has strong absorption characteristics spectrum lines at 2,893, 2,954 and 2,893 cm(-1), and n-butane at 2,895 and 2,965 cm(-1). The analysis result in this paper preliminary verified that the two-dimensional infrared correlation spectroscopy can be used for resolution enhancement in Fourier transform infrared spectrum quantitative analysis.

A BASIC program for the removal of noise from reaction traces using Fourier filtering.

PubMed

Brittain, T

1989-04-01

Software for the removal of noise from reaction curves using the principle of Fourier filtering has been written in BASIC to execute on a PC. The program inputs reaction traces which are subjected to a rotation-inversion process, to produce functions suitable for Fourier analysis. Fourier transformation into the frequency domain is followed by multiplication of the transform by a rectangular filter function, to remove the noise frequencies. Inverse transformation then yields a noise-reduced reaction trace suitable for further analysis. The program is interactive at each stage and could easily be modified to remove noise from a range of input data types.

Method for determining and displaying the spacial distribution of a spectral pattern of received light

DOEpatents

Bennett, C.L.

1996-07-23

An imaging Fourier transform spectrometer is described having a Fourier transform infrared spectrometer providing a series of images to a focal plane array camera. The focal plane array camera is clocked to a multiple of zero crossing occurrences as caused by a moving mirror of the Fourier transform infrared spectrometer and as detected by a laser detector such that the frame capture rate of the focal plane array camera corresponds to a multiple of the zero crossing rate of the Fourier transform infrared spectrometer. The images are transmitted to a computer for processing such that representations of the images as viewed in the light of an arbitrary spectral ``fingerprint`` pattern can be displayed on a monitor or otherwise stored and manipulated by the computer. 2 figs.

Trace Gas Measurements in Nascent, Aged and Cloud-processed Smoke from Africa Savanna Fires by Airborne Fourier Transform Infrared Spectroscopy (AFTIR)

NASA Technical Reports Server (NTRS)

Yokelson, Robert J.; Bertschi, Isaac T.; Christian, Ted J.; Hobbs, Peter V.; Ward, Darold E.; Hao, Wei Min

2003-01-01

We measured stable and reactive trace gases with an airborne Fourier transform infrared spectrometer (AFTIR) on the University of Washington Convair-580 research aircraft in August/September 2000 during the SAFARI 2000 dry season campaign in Southern Africa. The measurements included vertical profiles of C02, CO, H20, and CH4 up to 5.5 km on six occasions above instrumented ground sites and below the TERRA satellite and ER-2 high-flying research aircraft. We also measured the trace gas emissions from 10 African savanna fires. Five of these fires featured extensive ground-based fuel characterization, and two were in the humid savanna ecosystem that accounts for most African biomass burning. The major constituents we detected in nascent CH3OOH, HCHO, CH30H, HCN, NH3, HCOOH, and C2H2. These are the first quantitative measurements of the initial emissions of oxygenated volatile organic compounds (OVOC), NH3, and HCN from African savanna fires. On average, we measured 5.3 g/kg of OVOC and 3.6 g/kg of hydrocarbons (including CH4) in the initial emissions from the fires. Thus, the OVOC will have profound, largely unexplored effects on tropical tropospheric chemistry. The HCN emission factor was only weakly dependent on fire type; the average value (0.53 g/kg) is about 20 times that of a previous recommendation. HCN may be useful as a tracer for savanna fires. Delta O3/Delta CO and Delta CH3COO/Delta CO increased to as much as 9% in <1 h of photochemical processing downwind of fires. Direct measurements showed that cloud processing of smoke greatly reduced CH30H, NH3, CH3COOH, SO2, and NO2 levels, but significantly increased HCHO and NO.

Optimal fitting of Gaussian-apodized or under-resolved emission lines in Fourier transform spectra providing new insights on the velocity structure of NGC 6720

NASA Astrophysics Data System (ADS)

Martin, Thomas B.; Prunet, Simon; Drissen, Laurent

2016-12-01

An analysis of the kinematics of NGC 6720 is performed on the commissioning data obtained with SITELLE, the Canada-France-Hawaii Telescope's new imaging Fourier transform spectrometer. In order to measure carefully the small broadening effect of a shell expansion on an unresolved emission line, we have determined a computationally robust implementation of the convolution of a Gaussian with a sinc instrumental line shape which avoids arithmetic overflows. This model can be used to measure line broadening of typically a few km s-1 even at low spectral resolution (R < 5000). We have also designed the corresponding set of Gaussian apodizing functions that are now used by ORBS, the SITELLE's reduction pipeline. We have implemented this model in ORCS, a fitting engine for SITELLE's data, and used it to derive the [S II] density map of the central part of the nebula. The study of the broadening of the [N II] lines shows that the main ring and the central lobe are two different shells with different expansion velocities. We have also derived deep and spatially resolved velocity maps of the halo in [N II] and Hα and found that the brightest bubbles are originating from two bipolar structures with a velocity difference of more than 35 km s-1 lying at the poles of a possibly unique halo shell expanding at a velocity of more than 15 km s-1.

Reducing health risk assigned to organic emissions from a chemical weapons incinerator.

PubMed

Laman, David M; Weiler, B Douglas; Skeen, Rodney S

2013-03-01

Organic emissions from a chemical weapons incinerator have been characterized with an improved set of analytical methods to reduce the human health risk assigned to operations of the facility. A gas chromatography/mass selective detection method with substantially reduced detection limits has been used in conjunction with scanning electron microscopy/energy dispersive X-ray spectrometry and Fourier transform infrared microscopy to improve the speciation of semi-volatile and non-volatile organics emitted from the incinerator. The reduced detection limits have allowed a significant reduction in the assumed polycyclic aromatic hydrocarbon (PAH) and aminobiphenyl (ABP) emission rates used as inputs to the human health risk assessment for the incinerator. A mean factor of 17 decrease in assigned human health risk is realized for six common local exposure scenarios as a result of the reduced PAH and ABP detection limits.

Time-dependent infrared emission following photodissociation of nitromethane and chloropicrin.

PubMed

Wade, Elisabeth A; Reak, Kristina E; Li, Sissi L; Clegg, Samuel M; Zou, Peng; Osborn, David L

2006-04-06

Nitromethane (CH(3)NO(2)) and its chlorinated analogue, chloropicrin (CCl(3)NO(2)), were photolyzed at 193, 248, and 266 nm, and the products were observed by time-dependent Fourier transform infrared emission spectroscopy. At 193 and 248 nm, the primary photodissociation pathway for nitromethane was cleavage of the C-N bond to produce CH(3) + NO(2)(A (2)B(2)). At 266 nm, weak emission was observed following photodissociation of nitromethane, but an infrared spectrum could not be obtained. The photodissociation of chloropicrin at 193 nm produced the analogous product channel CCl(3) + NO(2)(A (2)B(2)) in addition to several other product channels. At 248 and 266 nm, only CCl(3) + NO(2)(A (2)B(2)) was observed. The production of phosgene (CCl(2)O) from chloropicrin photodissociation was not observed in this study.

Transition probabilities of Ce I obtained from Boltzmann analysis of visible and near-infrared emission spectra

NASA Astrophysics Data System (ADS)

Nitz, D. E.; Curry, J. J.; Buuck, M.; DeMann, A.; Mitchell, N.; Shull, W.

2018-02-01

We report radiative transition probabilities for 5029 emission lines of neutral cerium within the wavelength range 417-1110 nm. Transition probabilities for only 4% of these lines have been previously measured. These results are obtained from a Boltzmann analysis of two high resolution Fourier transform emission spectra used in previous studies of cerium, obtained from the digital archives of the National Solar Observatory at Kitt Peak. The set of transition probabilities used for the Boltzmann analysis are those published by Lawler et al (2010 J. Phys. B: At. Mol. Opt. Phys. 43 085701). Comparisons of branching ratios and transition probabilities for lines common to the two spectra provide important self-consistency checks and test for the presence of self-absorption effects. Estimated 1σ uncertainties for our transition probability results range from 10% to 18%.

Proposal of Classification Method of Time Series Data in International Emissions Trading Market Using Agent-based Simulation

NASA Astrophysics Data System (ADS)

Nakada, Tomohiro; Takadama, Keiki; Watanabe, Shigeyoshi

This paper proposes the classification method using Bayesian analytical method to classify the time series data in the international emissions trading market depend on the agent-based simulation and compares the case with Discrete Fourier transform analytical method. The purpose demonstrates the analytical methods mapping time series data such as market price. These analytical methods have revealed the following results: (1) the classification methods indicate the distance of mapping from the time series data, it is easier the understanding and inference than time series data; (2) these methods can analyze the uncertain time series data using the distance via agent-based simulation including stationary process and non-stationary process; and (3) Bayesian analytical method can show the 1% difference description of the emission reduction targets of agent.

Spontaneous ultra-weak light emissions from wheat seedlings are rhythmic and synchronized with the time profile of the local gravimetric tide

NASA Astrophysics Data System (ADS)

Moraes, Thiago A.; Barlow, Peter W.; Klingelé, Emile; Gallep, Cristiano M.

2012-06-01

Semi-circadian rhythms of spontaneous photon emission from wheat seedlings germinated and grown in a constant environment (darkened chamber) were found to be synchronized with the rhythm of the local gravimetric (lunisolar) tidal acceleration. Time courses of the photon-count curves were also found to match the growth velocity profile of the seedlings. Pair-wise analyses of the data—growth, photon count, and tidal—by local tracking correlation always revealed significant coefficients ( P > 0.7) for more than 80% of any of the time periods considered. Using fast Fourier transform, the photon-count data revealed periodic components similar to those of the gravimetric tide. Time courses of biophoton emissions would appear to be an additional, useful, and innovative tool in both chronobiological and biophysical studies.

Nonlinear Fourier transform—towards the construction of nonlinear Fourier modes

NASA Astrophysics Data System (ADS)

Saksida, Pavle

2018-01-01

We study a version of the nonlinear Fourier transform associated with ZS-AKNS systems. This version is suitable for the construction of nonlinear analogues of Fourier modes, and for the perturbation-theoretic study of their superposition. We provide an iterative scheme for computing the inverse of our transform. The relevant formulae are expressed in terms of Bell polynomials and functions related to them. In order to prove the validity of our iterative scheme, we show that our transform has the necessary analytic properties. We show that up to order three of the perturbation parameter, the nonlinear Fourier mode is a complex sinusoid modulated by the second Bernoulli polynomial. We describe an application of the nonlinear superposition of two modes to a problem of transmission through a nonlinear medium.

Reduction and coding of synthetic aperture radar data with Fourier transforms

NASA Technical Reports Server (NTRS)

Tilley, David G.

1995-01-01

Recently, aboard the Space Radar Laboratory (SRL), the two roles of Fourier Transforms for ocean image synthesis and surface wave analysis have been implemented with a dedicated radar processor to significantly reduce Synthetic Aperture Radar (SAR) ocean data before transmission to the ground. The object was to archive the SAR image spectrum, rather than the SAR image itself, to reduce data volume and capture the essential descriptors of the surface wave field. SAR signal data are usually sampled and coded in the time domain for transmission to the ground where Fourier Transforms are applied both to individual radar pulses and to long sequences of radar pulses to form two-dimensional images. High resolution images of the ocean often contain no striking features and subtle image modulations by wind generated surface waves are only apparent when large ocean regions are studied, with Fourier transforms, to reveal periodic patterns created by wind stress over the surface wave field. Major ocean currents and atmospheric instability in coastal environments are apparent as large scale modulations of SAR imagery. This paper explores the possibility of computing complex Fourier spectrum codes representing SAR images, transmitting the coded spectra to Earth for data archives and creating scenes of surface wave signatures and air-sea interactions via inverse Fourier transformations with ground station processors.

Optical spectroscopy, 1.06μm emission properties of Nd3+-doped phosphate based glasses.

PubMed

Sk Nayab, Rasool; T, Sasikala; A, Mohan Babu; L, Rama Moorthy; C K, Jayasankar

2017-06-05

Neodymium doped phosphate based glasses with composition of (P 2 O 5 +K 2 O+Al 2 O 3 +CaF 2 ) were prepared. The samples were analysed through differential thermal analysis (DTA), Fourier transform infrared (FTIR), absorption, emission and decay measurements. Judd-Ofelt parameters (Ω λ ) have been determined from the spectral intensities of absorption bands in order to calculate the radiative parameters like radiative transition probabilities (A R ), radiative lifetime (τ R ) and branching ratios (β R ) for the 4 F 3/2 → 4 I 11/2 laser transition of Nd 3+ ion. The effective emission bandwidths (Δλ eff ), experimental branching ratios (β exp ) and stimulated emission cross-sections (σ e ) have been determined from the emission spectrum. The decay curves of the 4 F 3/2 level exhibited almost single exponential nature for all the Nd 3+ ion concentrations. Copyright © 2017 Elsevier B.V. All rights reserved.

Performance evaluation of a biodiesel fuelled transportation engine retrofitted with a non-noble metal catalysed diesel oxidation catalyst for controlling unregulated emissions.

PubMed

Shukla, Pravesh Chandra; Gupta, Tarun; Agarwal, Avinash Kumar

2018-02-15

In present study, engine exhaust was sampled for measurement and analysis of unregulated emissions from a four cylinder transportation diesel engine using a state-of-the-art FTIR (Fourier transform infrared spectroscopy) emission analyzer. Test fuels used were Karanja biodiesel blend (B20) and baseline mineral diesel. Real-time emission measurements were performed for raw exhaust as well as exhaust sampled downstream of the two in-house prepared non-noble metal based diesel oxidation catalysts (DOCs) and a baseline commercial DOC based on noble metals. Two prepared non-noble metal based DOCs were based on Co-Ce mixed oxide and Lanthanum based perovskite catalysts. Perovskite based DOC performed superior compared to Co-Ce mixed oxide catalyst based DOC. Commercial noble metal based DOC was found to be the most effective in reducing unregulated hydrocarbon emissions in the engine exhaust, followed by the two in-house prepared non-noble metal based DOCs. Copyright © 2017 Elsevier B.V. All rights reserved.

Incorporation of Pr into LuAG ceramics

NASA Astrophysics Data System (ADS)

Marchewka, M. R.; Chapman, M. G.; Qian, H.; Jacobsohn, L. G.

2017-06-01

An investigation of the effects of Pr in (Lu1-xPrx)3Al5O12 (LuAG:Pr) ceramics was carried out by means of x-ray diffraction (XRD), energy dispersive x-ray spectroscopy (EDX), and attenuated total reflection Fourier transform infrared spectroscopy (ATR FTIR) measurements coupled with luminescence measurements. It was found that the Pr concentration that maximizes luminescence emission depends on the thermal processing conditions. While the calcined LuAG:Pr powder showed maximum luminescence emission for Pr concentrations between 0.18 and 0.33 at.%, maximum emission of ceramic bodies sintered at 1500 °C for 20 h was obtained with Pr concentrations between 0.018 and 0.18 at.%. Further, for short sintering times up to about 3 h, luminescence emission intensity is maximum for Pr concentrations around 0.33 at.%. Longer sintering times lead to the formation of PrAlO3 as a secondary phase, concomitant with a reduction of the intensity of luminescence emission.

Use of the fractional Fourier transform in {pi}/2 converters of laser modes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malyutin, A A

2004-02-28

The possibility of using the fractional Fourier transform (FrFT) in optical schemes for astigmatic {pi}/2 converters of Hermite-Gaussian modes to donut Laguerre-Gaussian modes is considered. Several schemes of converters based on the FrFT of the half-integer and irrational orders are presented. The lowest FrFT order than can be used in astigmatic mode converters is found. The properties of converters based on the fractional and ordinary Fourier transforms are compared. (laser beams)

Restoration algorithms for imaging through atmospheric turbulence

DTIC Science & Technology

2017-02-18

the Fourier spectrum of each frame. The reconstructed image is then obtained by taking the inverse Fourier transform of the average of all processed...with wipξq “ Gσp|Fpviqpξq|pq řM j“1Gσp|Fpvjqpξq|pq , where F denotes the Fourier transform (ξ are the frequencies) and Gσ is a Gaussian filter of...a combination of SIFT [26] and ORSA [14] algorithms) in order to remove affine transformations (translations, rotations and homothety). The authors

Tomography: Three Dimensional Image Construction. Applications of Analysis to Medical Radiology. [and] Genetic Counseling. Applications of Probability to Medicine. [and] The Design of Honeycombs. Applications of Differential Equations to Biology. Modules and Monographs in Undergraduate Mathematics and Its Applications Project. UMAP Units 318, 456, 502.

ERIC Educational Resources Information Center

Solomon, Frederick; And Others.

This document consists of three modules. The first looks at applications of analysis to medical radiology. The goals are to provide: 1) acquaintance with a significant applied mathematics problem utilizing Fourier Transforms; 2) generalization of the Fourier Transforms to two dimensions; 3) practice with Fourier Transforms; and 4) introduction to…

A laboratory demonstration of high-resolution hard X-ray and gamma-ray imaging using Fourier-transform techniques

NASA Technical Reports Server (NTRS)

Palmer, David; Prince, Thomas A.

1987-01-01

A laboratory imaging system has been developed to study the use of Fourier-transform techniques in high-resolution hard X-ray and gamma-ray imaging, with particular emphasis on possible applications to high-energy astronomy. Considerations for the design of a Fourier-transform imager and the instrumentation used in the laboratory studies is described. Several analysis methods for image reconstruction are discussed including the CLEAN algorithm and maximum entropy methods. Images obtained using these methods are presented.

Static harmonization of dynamically harmonized Fourier transform ion cyclotron resonance cell.

PubMed

Zhdanova, Ekaterina; Kostyukevich, Yury; Nikolaev, Eugene

2017-08-01

Static harmonization in the Fourier transform ion cyclotron resonance cell improves the resolving power of the cell and prevents dephasing of the ion cloud in the case of any trajectory of the charged particle, not necessarily axisymmetric cyclotron (as opposed to dynamic harmonization). We reveal that the Fourier transform ion cyclotron resonance cell with dynamic harmonization (paracell) is proved to be statically harmonized. The volume of the statically harmonized potential distribution increases with an increase in the number of trap segments.

Fast Fourier Transform algorithm design and tradeoffs

NASA Technical Reports Server (NTRS)

Kamin, Ray A., III; Adams, George B., III

1988-01-01

The Fast Fourier Transform (FFT) is a mainstay of certain numerical techniques for solving fluid dynamics problems. The Connection Machine CM-2 is the target for an investigation into the design of multidimensional Single Instruction Stream/Multiple Data (SIMD) parallel FFT algorithms for high performance. Critical algorithm design issues are discussed, necessary machine performance measurements are identified and made, and the performance of the developed FFT programs are measured. Fast Fourier Transform programs are compared to the currently best Cray-2 FFT program.

REVIEW ARTICLE: Emission measurement techniques for advanced powertrains

NASA Astrophysics Data System (ADS)

Adachi, Masayuki

2000-10-01

Recent developments in high-efficiency low-emission powertrains require the emission measurement technologies to be able to detect regulated and unregulated compounds with very high sensitivity and a fast response. For example, levels of a variety of nitrogen compounds and sulphur compounds should be analysed in real time in order to develop aftertreatment systems to decrease emission of NOx for the lean burning powertrains. Also, real-time information on the emission of particulate matter for the transient operation of diesel engines and direct injection gasoline engines is invaluable. The present paper reviews newly introduced instrumentation for such emission measurement that is demanded for the developments in advanced powertrain systems. They include Fourier transform infrared spectroscopy, mass spectrometry and fast response flame ionization detection. In addition, demands and applications of the fuel reformer developments for fuel cell electric vehicles are discussed. Besides the detection methodologies, sample handling techniques for the measurement of concentrations emitted from low emission vehicles for which the concentrations of the pollutants are significantly lower than the concentrations present in ambient air, are also described.

High Accuracy Evaluation of the Finite Fourier Transform Using Sampled Data

NASA Technical Reports Server (NTRS)

Morelli, Eugene A.

1997-01-01

Many system identification and signal processing procedures can be done advantageously in the frequency domain. A required preliminary step for this approach is the transformation of sampled time domain data into the frequency domain. The analytical tool used for this transformation is the finite Fourier transform. Inaccuracy in the transformation can degrade system identification and signal processing results. This work presents a method for evaluating the finite Fourier transform using cubic interpolation of sampled time domain data for high accuracy, and the chirp Zeta-transform for arbitrary frequency resolution. The accuracy of the technique is demonstrated in example cases where the transformation can be evaluated analytically. Arbitrary frequency resolution is shown to be important for capturing details of the data in the frequency domain. The technique is demonstrated using flight test data from a longitudinal maneuver of the F-18 High Alpha Research Vehicle.

3-D surface profilometry based on modulation measurement by applying wavelet transform method

NASA Astrophysics Data System (ADS)

Zhong, Min; Chen, Feng; Xiao, Chao; Wei, Yongchao

2017-01-01

A new analysis of 3-D surface profilometry based on modulation measurement technique by the application of Wavelet Transform method is proposed. As a tool excelling for its multi-resolution and localization in the time and frequency domains, Wavelet Transform method with good localized time-frequency analysis ability and effective de-noizing capacity can extract the modulation distribution more accurately than Fourier Transform method. Especially for the analysis of complex object, more details of the measured object can be well remained. In this paper, the theoretical derivation of Wavelet Transform method that obtains the modulation values from a captured fringe pattern is given. Both computer simulation and elementary experiment are used to show the validity of the proposed method by making a comparison with the results of Fourier Transform method. The results show that the Wavelet Transform method has a better performance than the Fourier Transform method in modulation values retrieval.

Sparse dictionary for synthetic transmit aperture medical ultrasound imaging.

PubMed

Wang, Ping; Jiang, Jin-Yang; Li, Na; Luo, Han-Wu; Li, Fang; Cui, Shi-Gang

2017-07-01

It is possible to recover a signal below the Nyquist sampling limit using a compressive sensing technique in ultrasound imaging. However, the reconstruction enabled by common sparse transform approaches does not achieve satisfactory results. Considering the ultrasound echo signal's features of attenuation, repetition, and superposition, a sparse dictionary with the emission pulse signal is proposed. Sparse coefficients in the proposed dictionary have high sparsity. Images reconstructed with this dictionary were compared with those obtained with the three other common transforms, namely, discrete Fourier transform, discrete cosine transform, and discrete wavelet transform. The performance of the proposed dictionary was analyzed via a simulation and experimental data. The mean absolute error (MAE) was used to quantify the quality of the reconstructions. Experimental results indicate that the MAE associated with the proposed dictionary was always the smallest, the reconstruction time required was the shortest, and the lateral resolution and contrast of the reconstructed images were also the closest to the original images. The proposed sparse dictionary performed better than the other three sparse transforms. With the same sampling rate, the proposed dictionary achieved excellent reconstruction quality.

A compressive-sensing Fourier-transform on-chip Raman spectrometer

NASA Astrophysics Data System (ADS)

Podmore, Hugh; Scott, Alan; Lee, Regina

2018-02-01

We demonstrate a novel compressive sensing Fourier-transform spectrometer (FTS) for snapshot Raman spectroscopy in a compact format. The on-chip FTS consists of a set of planar-waveguide Mach-Zehnder interferometers (MZIs) arrayed on a photonic chip, effecting a discrete Fourier-transform of the input spectrum. Incoherence between the sampling domain (time), and the spectral domain (frequency) permits compressive sensing retrieval using undersampled interferograms for sparse spectra such as Raman emission. In our fabricated device we retain our chosen bandwidth and resolution while reducing the number of MZIs, e.g. the size of the interferogram, to 1/4th critical sampling. This architecture simultaneously reduces chip footprint and concentrates the interferogram in fewer pixels to improve the signal to noise ratio. Our device collects interferogram samples simultaneously, therefore a time-gated detector may be used to separate Raman peaks from sample fluorescence. A challenge for FTS waveguide spectrometers is to achieve multi-aperture high throughput broadband coupling to a large number of single-mode waveguides. A multi-aperture design allows one to increase the bandwidth and spectral resolution without sacrificing optical throughput. In this device, multi-aperture coupling is achieved using an array of microlenses bonded to the surface of the chip, and aligned with a grid of vertically illuminated waveguide apertures. The microlens array accepts a collimated beam with near 100% fill-factor, and the resulting spherical wavefronts are coupled into the single-mode waveguides using 45& mirrors etched into the waveguide layer via focused ion-beam (FIB). The interferogram from the waveguide outputs is imaged using a CCD, and inverted via l1-norm minimization to correctly retrieve a sparse input spectrum.

An Evaluation of the Environmental Fate and Behavior of Munitions Materiel (Tetryl and Polar Metabolites of TNT) in Soil and Plant Systems. Environmental Fate and Behavior of Tetryl

DTIC Science & Technology

1992-03-01

attempted to verify product identity and purity by GC with either Fourier transform infrared spectro.icopy (FTIR) or mass spectroscopy (MS) detection...ýl0 5 In-1 z U)-’i0oo -3g’i o -6o0 626o a i60 ito1 2i oo I ’ o [JfnVENUII8ER (cm- FIGURE 3,9. Fourier Transform Infrared Spectroscopy Spectrum of...Fourier Transform Infrared Spectroscopy Spectrum of Tetryl I-I F1U~IGUR Fourier Utransformlfret Spcrop S ectrum of TeasomtinPoutrl 0 , -39 i : : : -. . i

Trace gas emissions from biomass burning in tropical Australian savannas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hurst, D.F.; Griffith, D.W.T.; Cook, G.D.

1994-08-20

The trace gas emissions of biomass burning was measured during the 1991 and 1992 dry seasons (April through October) at the Kapalga Research Station in Kakadu National Park, Northern Territory, Australia. Over 100 smoke samples from savannah fires were collected, from the ground and from aircraft flying at 50 to 700 meters above the fires. The samples were analyzed for carbon dioxide, carbon monoxide, nitrous oxides, and other carbon and nitrogen compounds using gas phase Fourier transform infrared (FTIR) spectroscopy, matrix isolation FTIR spectroscopy, and chemiluminescence techniques. This paper describes the results of the gas analyses and discusses the potentialmore » impacts of these gases on regional atmospheric chemistry.49 refs., 4 figs., 7 tabs.« less

The generalization of upper atmospheric wind and temperature based on the Voigt line shape profile.

PubMed

Zhang, Chunmin; He, Jian

2006-12-25

The principle of probing the upper atmospheric wind field, which is the Voigt profile spectral line shape, is presented for the first time. By the Fourier Transform of Voigt profile, with the Imaging Spectroscope and the Doppler effect of electromagnetic wave, the distribution and calculation formulae of the velocity field, temperature field, and pressure field of the upper atmosphere wind field are given. The probed source is the two major aurora emission lines originated from the metastable O(1S) and O(1D) at 557.7nm and 630.0nm. From computer simulation and error analysis, the Voigt profile, which is the correlation of the Gaussian profile and Lorentzian profile, is closest to the actual airglow emission lines.

Surface acoustic wave regulated single photon emission from a coupled quantum dot–nanocavity system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weiß, M.; Kapfinger, S.; Wixforth, A.

2016-07-18

A coupled quantum dot–nanocavity system in the weak coupling regime of cavity-quantumelectrodynamics is dynamically tuned in and out of resonance by the coherent elastic field of a f{sub SAW} ≃ 800 MHz surface acoustic wave. When the system is brought to resonance by the sound wave, light-matter interaction is strongly increased by the Purcell effect. This leads to a precisely timed single photon emission as confirmed by the second order photon correlation function, g{sup (2)}. All relevant frequencies of our experiment are faithfully identified in the Fourier transform of g{sup (2)}, demonstrating high fidelity regulation of the stream of single photonsmore » emitted by the system.« less

Synthesis, Analysis, and Processing of Fractal Signals

DTIC Science & Technology

1991-10-01

coordinator in hockey, squash, volleyball, and softball, but also for reminding me periodically that 1/f noise can exist outside a computer. More...similar signals as Fourier-based representations are for stationary and periodic signals. Furthermore, because wave- let transformations can be...and periodic signals. Furthermore, just as the discovery of fast Fourier transform (FFT) algorithms dramatically increased the viability the Fourier

Wavelets

NASA Astrophysics Data System (ADS)

Strang, Gilbert

1994-06-01

Several methods are compared that are used to analyze and synthesize a signal. Three ways are mentioned to transform a symphony: into cosine waves (Fourier transform), into pieces of cosines (short-time Fourier transform), and into wavelets (little waves that start and stop). Choosing the best basis, higher dimensions, fast wavelet transform, and Daubechies wavelets are discussed. High-definition television is described. The use of wavelets in identifying fingerprints in the future is related.

Nonuniform fast Fourier transform method for numerical diffraction simulation on tilted planes.

PubMed

Xiao, Yu; Tang, Xiahui; Qin, Yingxiong; Peng, Hao; Wang, Wei; Zhong, Lijing

2016-10-01

The method, based on the rotation of the angular spectrum in the frequency domain, is generally used for the diffraction simulation between the tilted planes. Due to the rotation of the angular spectrum, the interval between the sampling points in the Fourier domain is not even. For the conventional fast Fourier transform (FFT)-based methods, a spectrum interpolation is needed to get the approximate sampling value on the equidistant sampling points. However, due to the numerical error caused by the spectrum interpolation, the calculation accuracy degrades very quickly as the rotation angle increases. Here, the diffraction propagation between the tilted planes is transformed into a problem about the discrete Fourier transform on the uneven sampling points, which can be evaluated effectively and precisely through the nonuniform fast Fourier transform method (NUFFT). The most important advantage of this method is that the conventional spectrum interpolation is avoided and the high calculation accuracy can be guaranteed for different rotation angles, even when the rotation angle is close to π/2. Also, its calculation efficiency is comparable with that of the conventional FFT-based methods. Numerical examples as well as a discussion about the calculation accuracy and the sampling method are presented.

Applying wavelet transforms to analyse aircraft-measured turbulence and turbulent fluxes in the atmospheric boundary layer over eastern Siberia

NASA Astrophysics Data System (ADS)

Strunin, M. A.; Hiyama, T.

2004-11-01

The wavelet spectral method was applied to aircraft-based measurements of atmospheric turbulence obtained during joint Russian-Japanese research on the atmospheric boundary layer near Yakutsk (eastern Siberia) in April-June 2000. Practical ways to apply Fourier and wavelet methods for aircraft-based turbulence data are described. Comparisons between Fourier and wavelet transform results are shown and they demonstrate, in conjunction with theoretical and experimental restrictions, that the Fourier transform method is not useful for studying non-homogeneous turbulence. The wavelet method is free from many disadvantages of Fourier analysis and can yield more informative results. Comparison of Fourier and Morlet wavelet spectra showed good agreement at high frequencies (small scales). The quality of the wavelet transform and corresponding software was estimated by comparing the original data with restored data constructed with an inverse wavelet transform. A Haar wavelet basis was inappropriate for the turbulence data; the mother wavelet function recommended in this study is the Morlet wavelet. Good agreement was also shown between variances and covariances estimated with different mathematical techniques, i.e. through non-orthogonal wavelet spectra and through eddy correlation methods.

A Comparison of FTNMR and FTIR Techniques.

ERIC Educational Resources Information Center

Ahn, Myong-Ku

1989-01-01

Nuclear magnetic resonance and infrared are two spectroscopic methods that commonly use the Fourier transform technique. Discussed are the similarities and differences in the use of the Fourier transform in these two spectroscopic techniques. (CW)

A Graphical Presentation to Teach the Concept of the Fourier Transform

ERIC Educational Resources Information Center

Besalu, E.

2006-01-01

A study was conducted to visualize the reason why the Fourier transform technique is useful to detect the originating frequencies of a complicated superposition of waves. The findings reveal that students respond well when instructors adapt pictorial presentation to show how the time-domain function is transformed into the frequency domain.

Novel hybrid optical correlator: theory and optical simulation.

PubMed

Casasent, D; Herold, R L

1975-02-01

The inverse transform of the product of two Fourier transform holograms is analyzed and shown to contain the correlation of the two images from which the holograms were formed. The theory, analysis, and initial experimental demonstration of the feasibility of a novel correlation scheme using this multiplied Fourier transform hologram system are presented.

Fast algorithm for chirp transforms with zooming-in ability and its applications.

PubMed

Deng, X; Bihari, B; Gan, J; Zhao, F; Chen, R T

2000-04-01

A general fast numerical algorithm for chirp transforms is developed by using two fast Fourier transforms and employing an analytical kernel. This new algorithm unifies the calculations of arbitrary real-order fractional Fourier transforms and Fresnel diffraction. Its computational complexity is better than a fast convolution method using Fourier transforms. Furthermore, one can freely choose the sampling resolutions in both x and u space and zoom in on any portion of the data of interest. Computational results are compared with analytical ones. The errors are essentially limited by the accuracy of the fast Fourier transforms and are higher than the order 10(-12) for most cases. As an example of its application to scalar diffraction, this algorithm can be used to calculate near-field patterns directly behind the aperture, 0 < or = z < d2/lambda. It compensates another algorithm for Fresnel diffraction that is limited to z > d2/lambdaN [J. Opt. Soc. Am. A 15, 2111 (1998)]. Experimental results from waveguide-output microcoupler diffraction are in good agreement with the calculations.

Non-stationary component extraction in noisy multicomponent signal using polynomial chirping Fourier transform.

PubMed

Lu, Wenlong; Xie, Junwei; Wang, Heming; Sheng, Chuan

2016-01-01

Inspired by track-before-detection technology in radar, a novel time-frequency transform, namely polynomial chirping Fourier transform (PCFT), is exploited to extract components from noisy multicomponent signal. The PCFT combines advantages of Fourier transform and polynomial chirplet transform to accumulate component energy along a polynomial chirping curve in the time-frequency plane. The particle swarm optimization algorithm is employed to search optimal polynomial parameters with which the PCFT will achieve a most concentrated energy ridge in the time-frequency plane for the target component. The component can be well separated in the polynomial chirping Fourier domain with a narrow-band filter and then reconstructed by inverse PCFT. Furthermore, an iterative procedure, involving parameter estimation, PCFT, filtering and recovery, is introduced to extract components from a noisy multicomponent signal successively. The Simulations and experiments show that the proposed method has better performance in component extraction from noisy multicomponent signal as well as provides more time-frequency details about the analyzed signal than conventional methods.

Potential role of the nitroacidium ion on HONO emissions from the snowpack.

PubMed

Hellebust, Stig; Roddis, Tristan; Sodeau, John R

2007-02-22

The effects of photolysis on frozen, thin films of water-ice containing nitrogen dioxide (as its dimer dinitrogen tetroxide) have been investigated using a combination of Fourier transform reflection-absorption infrared (FT-RAIR) spectroscopy and mass spectrometry. The release of HONO is ascribed to a mechanism in which nitrosonium nitrate (NO+NO3-) is formed. Subsequent solvation of the cation leads to the nitroacidium ion, H2ONO+, i.e., protonated nitrous acid. The pathway proposed explains why the field measurement of HONO at different polar sites is often contradictory.

Solvothermal synthesis of fusiform hexagonal prism SrCO{sub 3} microrods via ethylene glycol solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shi Liange; Du Fanglin

2007-08-07

Fusiform hexagonal prism SrCO{sub 3} microrods were prepared by a simple solvothermal route at 120 deg. C, and characterized by X-ray powder diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and Fourier transform infrared (FT-IR) spectroscopy. By controlling the content of ethylene glycol (EG), it was found that ethylene glycol (EG) played an important role in the formation of such SrCO{sub 3} microrods. Finally, effects of other solvents on the products, including 1,2-propanediol and glycerin, were also investigated.

Structure and thermal decomposition of sulfated β-cyclodextrin intercalated in a layered double hydroxide

NASA Astrophysics Data System (ADS)

Wang, Ji; Wei, Min; Rao, Guoying; Evans, David G.; Duan, Xue

2004-01-01

The sodium salt of hexasulfated β-cyclodextrin has been synthesized and intercalated into a magnesium-aluminum layered double hydroxide by ion exchange. The structure, composition and thermal decomposition behavior of the intercalated material have been studied by variable temperature X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), inductively coupled plasma emission spectroscopy (ICP), and thermal analysis (TG-DTA) and a model for the structure has been proposed. The thermal stability of the intercalated sulfated β-cyclodextrin is significantly enhanced compared with the pure form before intercalation.

Experimental image alignment system

NASA Technical Reports Server (NTRS)

Moyer, A. L.; Kowel, S. T.; Kornreich, P. G.

1980-01-01

A microcomputer-based instrument for image alignment with respect to a reference image is described which uses the DEFT sensor (Direct Electronic Fourier Transform) for image sensing and preprocessing. The instrument alignment algorithm which uses the two-dimensional Fourier transform as input is also described. It generates signals used to steer the stage carrying the test image into the correct orientation. This algorithm has computational advantages over algorithms which use image intensity data as input and is suitable for a microcomputer-based instrument since the two-dimensional Fourier transform is provided by the DEFT sensor.

Modulated Fourier Transform Raman Fiber-Optic Spectroscopy

NASA Technical Reports Server (NTRS)

Jensen, Brian J. (Inventor); Cooper, John B. (Inventor); Wise, Kent L. (Inventor)

2000-01-01

A modification to a commercial Fourier Transform (FT) Raman spectrometer is presented for the elimination of thermal backgrounds in the FT Raman spectra. The modification involves the use of a mechanical optical chopper to modulate the continuous wave laser, remote collection of the signal via fiber optics, and connection of a dual-phase digital-signal-processor (DSP) lock-in amplifier between the detector and the spectrometer's collection electronics to demodulate and filter the optical signals. The resulting Modulated Fourier Transform Raman Fiber-Optic Spectrometer is capable of completely eliminating thermal backgrounds at temperatures exceeding 300 C.

Fourier-transform and global contrast interferometer alignment methods

DOEpatents

Goldberg, Kenneth A.

2001-01-01

Interferometric methods are presented to facilitate alignment of image-plane components within an interferometer and for the magnified viewing of interferometer masks in situ. Fourier-transforms are performed on intensity patterns that are detected with the interferometer and are used to calculate pseudo-images of the electric field in the image plane of the test optic where the critical alignment of various components is being performed. Fine alignment is aided by the introduction and optimization of a global contrast parameter that is easily calculated from the Fourier-transform.

On reliable time-frequency characterization and delay estimation of stimulus frequency otoacoustic emissions

NASA Astrophysics Data System (ADS)

Biswal, Milan; Mishra, Srikanta

2018-05-01

The limited information on origin and nature of stimulus frequency otoacoustic emissions (SFOAEs) necessitates a thorough reexamination into SFOAE analysis procedures. This will lead to a better understanding of the generation of SFOAEs. The SFOAE response waveform in the time domain can be interpreted as a summation of amplitude modulated and frequency modulated component waveforms. The efficiency of a technique to segregate these components is critical to describe the nature of SFOAEs. Recent advancements in robust time-frequency analysis algorithms have staked claims on the more accurate extraction of these components, from composite signals buried in noise. However, their potential has not been fully explored for SFOAEs analysis. Indifference to distinct information, due to nature of these analysis techniques, may impact the scientific conclusions. This paper attempts to bridge this gap in literature by evaluating the performance of three linear time-frequency analysis algorithms: short-time Fourier transform (STFT), continuous Wavelet transform (CWT), S-transform (ST) and two nonlinear algorithms: Hilbert-Huang Transform (HHT), synchrosqueezed Wavelet transform (SWT). We revisit the extraction of constituent components and estimation of their magnitude and delay, by carefully evaluating the impact of variation in analysis parameters. The performance of HHT and SWT from the perspective of time-frequency filtering and delay estimation were found to be relatively less efficient for analyzing SFOAEs. The intrinsic mode functions of HHT does not completely characterize the reflection components and hence IMF based filtering alone, is not recommended for segregating principal emission from multiple reflection components. We found STFT, WT, and ST to be suitable for canceling multiple internal reflection components with marginal altering in SFOAE.

A fast D.F.T. algorithm using complex integer transforms

NASA Technical Reports Server (NTRS)

Reed, I. S.; Truong, T. K.

1978-01-01

Winograd (1976) has developed a new class of algorithms which depend heavily on the computation of a cyclic convolution for computing the conventional DFT (discrete Fourier transform); this new algorithm, for a few hundred transform points, requires substantially fewer multiplications than the conventional FFT algorithm. Reed and Truong have defined a special class of finite Fourier-like transforms over GF(q squared), where q = 2 to the p power minus 1 is a Mersenne prime for p = 2, 3, 5, 7, 13, 17, 19, 31, 61. In the present paper it is shown that Winograd's algorithm can be combined with the aforementioned Fourier-like transform to yield a new algorithm for computing the DFT. A fast method for accurately computing the DFT of a sequence of complex numbers of very long transform-lengths is thus obtained.

A High Resolution Fourier-Transform Spectrometer for the Measurement of Atmospheric Column Abundances

NASA Technical Reports Server (NTRS)

Cageao, R.; Sander, S.; Blavier, J.; Jiang, Y.; Nemtchinov, V.

2000-01-01

A compact, high resolution Fourier-transform spectrometer for atmospheric near ultraviolet spectroscopy has been installed at the Jet Propulsion Laboratory's Table Mountain Facility (34.4N, 117.7 W, elevation 2290m).

Technique for the metrology calibration of a Fourier transform spectrometer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spencer, Locke D.; Naylor, David A

2008-11-10

A method is presented for using a Fourier transform spectrometer (FTS) to calibrate the metrology of a second FTS. This technique is particularly useful when the second FTS is inside a cryostat or otherwise inaccessible.

Method for determining and displaying the spacial distribution of a spectral pattern of received light

DOEpatents

Bennett, Charles L.

1996-01-01

An imaging Fourier transform spectrometer (10, 210) having a Fourier transform infrared spectrometer (12) providing a series of images (40) to a focal plane array camera (38). The focal plane array camera (38) is clocked to a multiple of zero crossing occurrences as caused by a moving mirror (18) of the Fourier transform infrared spectrometer (12) and as detected by a laser detector (50) such that the frame capture rate of the focal plane array camera (38) corresponds to a multiple of the zero crossing rate of the Fourier transform infrared spectrometer (12). The images (40) are transmitted to a computer (45) for processing such that representations of the images (40) as viewed in the light of an arbitrary spectral "fingerprint" pattern can be displayed on a monitor (60) or otherwise stored and manipulated by the computer (45).

Atomic Gaussian type orbitals and their Fourier transforms via the Rayleigh expansion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yükçü, Niyazi

Gaussian type orbitals (GTOs), which are one of the types of exponential type orbitals (ETOs), are used usually as basis functions in the multi-center atomic and molecular integrals to better understand physical and chemical properties of matter. In the Fourier transform method (FTM), basis functions have not simplicity to make mathematical operations, but their Fourier transforms are easier to use. In this work, with the help of FTM, Rayleigh expansion and some properties of unnormalized GTOs, we present new mathematical results for the Fourier transform of GTOs in terms of Laguerre polynomials, hypergeometric and Whittaker functions. Physical and analytical propertiesmore » of GTOs are discussed and some numerical results have been given in a table. Finally, we compare our mathematical results with the other known literature results by using a computer program and details of evaluation are presented.« less

Differentiating Fragmentation Pathways of Cholesterol by Two-Dimensional Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.

PubMed

van Agthoven, Maria A; Barrow, Mark P; Chiron, Lionel; Coutouly, Marie-Aude; Kilgour, David; Wootton, Christopher A; Wei, Juan; Soulby, Andrew; Delsuc, Marc-André; Rolando, Christian; O'Connor, Peter B

2015-12-01

Two-dimensional Fourier transform ion cyclotron resonance mass spectrometry is a data-independent analytical method that records the fragmentation patterns of all the compounds in a sample. This study shows the implementation of atmospheric pressure photoionization with two-dimensional (2D) Fourier transform ion cyclotron resonance mass spectrometry. In the resulting 2D mass spectrum, the fragmentation patterns of the radical and protonated species from cholesterol are differentiated. This study shows the use of fragment ion lines, precursor ion lines, and neutral loss lines in the 2D mass spectrum to determine fragmentation mechanisms of known compounds and to gain information on unknown ion species in the spectrum. In concert with high resolution mass spectrometry, 2D Fourier transform ion cyclotron resonance mass spectrometry can be a useful tool for the structural analysis of small molecules. Graphical Abstract ᅟ.

Component analyses of urinary nanocrystallites of uric acid stone formers by combination of high-resolution transmission electron microscopy, fast Fourier transformation, energy dispersive X-ray spectroscopy, X-ray diffraction and Fourier transform infrared spectroscopy.

PubMed

Sun, Xin-Yuan; Xue, Jun-Fa; Xia, Zhi-Yue; Ouyang, Jian-Ming

2015-06-01

This study aimed to analyse the components of nanocrystallites in urines of patients with uric acid (UA) stones. X-ray diffraction (XRD), Fourier transform infrared spectroscopy, high-resolution transmission electron microscopy (HRTEM), fast Fourier transformation (FFT) of HRTEM, and energy dispersive X-ray spectroscopy (EDS) were performed to analyse the components of these nanocrystallites. XRD and FFT showed that the main component of urinary nanocrystallites was UA, which contains a small amount of calcium oxalate monohydrate and phosphates. EDS showed the characteristic absorption peaks of C, O, Ca and P. The formation of UA stones was closely related to a large number of UA nanocrystallites in urine. A combination of HRTEM, FFT, EDS and XRD analyses could be performed accurately to analyse the components of urinary nanocrystallites.

Application and sensitivity investigation of Fourier transforms for microwave radiometric inversions

NASA Technical Reports Server (NTRS)

Holmes, J. J.; Balanis, C. A.

1974-01-01

Existing microwave radiometer technology now provides a suitable method for remote determination of the ocean surface's absolute brightness temperature. To extract the brightness temperature of the water from the antenna temperature equation, an unstable Fredholm integral equation of the first kind was solved. Fast Fourier Transform techniques were used to invert the integral after it is placed into a cross-correlation form. Application and verification of the methods to a two-dimensional modeling of a laboratory wave tank system were included. The instability of the Fredholm equation was then demonstrated and a restoration procedure was included which smooths the resulting oscillations. With the recent availability and advances of Fast Fourier Transform techniques, the method presented becomes very attractive in the evaluation of large quantities of data. Actual radiometric measurements of sea water are inverted using the restoration method, incorporating the advantages of the Fast Fourier Transform algorithm for computations.

Single Channel Quantum Color Image Encryption Algorithm Based on HSI Model and Quantum Fourier Transform

NASA Astrophysics Data System (ADS)

Gong, Li-Hua; He, Xiang-Tao; Tan, Ru-Chao; Zhou, Zhi-Hong

2018-01-01

In order to obtain high-quality color images, it is important to keep the hue component unchanged while emphasize the intensity or saturation component. As a public color model, Hue-Saturation Intensity (HSI) model is commonly used in image processing. A new single channel quantum color image encryption algorithm based on HSI model and quantum Fourier transform (QFT) is investigated, where the color components of the original color image are converted to HSI and the logistic map is employed to diffuse the relationship of pixels in color components. Subsequently, quantum Fourier transform is exploited to fulfill the encryption. The cipher-text is a combination of a gray image and a phase matrix. Simulations and theoretical analyses demonstrate that the proposed single channel quantum color image encryption scheme based on the HSI model and quantum Fourier transform is secure and effective.

Application of the fractional Fourier transform to the design of LCOS based optical interconnects and fiber switches.

PubMed

Robertson, Brian; Zhang, Zichen; Yang, Haining; Redmond, Maura M; Collings, Neil; Liu, Jinsong; Lin, Ruisheng; Jeziorska-Chapman, Anna M; Moore, John R; Crossland, William A; Chu, D P

2012-04-20

It is shown that reflective liquid crystal on silicon (LCOS) spatial light modulator (SLM) based interconnects or fiber switches that use defocus to reduce crosstalk can be evaluated and optimized using a fractional Fourier transform if certain optical symmetry conditions are met. Theoretically the maximum allowable linear hologram phase error compared to a Fourier switch is increased by a factor of six before the target crosstalk for telecom applications of -40 dB is exceeded. A Gerchberg-Saxton algorithm incorporating a fractional Fourier transform modified for use with a reflective LCOS SLM is used to optimize multi-casting holograms in a prototype telecom switch. Experiments are in close agreement to predicted performance.

Synergistic effects of mica and wollastonite fillers on thermal performance of intumescent fire retardant coating

NASA Astrophysics Data System (ADS)

Zia-ul-Mustafa, M.; Ahmad, Faiz; Megat-Yusoff, Puteri S. M.; Aziz, Hammad

2015-07-01

In this study, intumescent fire retardant coatings (IFRC) were developed to investigate the synergistic effects of reinforced mica and wollastonite fillers based IFRC towards heat shielding, char expansion, char composition and char morphology. Ammonium poly-phosphate (APP) was used as acid source, expandable graphite (EG) as carbon source, melamine as blowing agent, boric acid as additive and Hardener H-2310 polyamide amine in bisphenol A epoxy resin BE-188(BPA) was used as curing agent. Bunsen burner fire test was used for thermal performance according to UL-94 for 1 h. Field Emission Scanning Electron Microscopy (FESEM) was used to observe char microstructure. X-Ray Diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) were used to analyse char composition. The results showed that addition of clay filler in IFRC enhanced the fire protection performance of intumescent coating. X-Ray Diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) results showed the presence of boron phosphate, silicon phosphate oxide, aluminium borate in the char that improved the thermal performance of intumescent fire retardant coating (IFRC). Resultantly, the presence of these developed compounds enhanced the Integrity of structural steel upto 500°C.

Microwave-assisted hydrothermal synthesis of biocompatible silver sulfide nanoworms

NASA Astrophysics Data System (ADS)

Xing, Ruimin; Liu, Shanhu; Tian, Shufang

2011-10-01

In this study, silver sulfide nanoworms were prepared via a rapid microwave-assisted hydrothermal method by reacting silver nitrate and thioacetamide in the aqueous solution of the Bovine Serum Albumin (BSA) protein. The morphology, composition, and crystallinity of the nanoworms were characterized by field emission scanning electron microscopy (FESEM), X-ray powder diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED), X-ray energy dispersive spectroscopy (EDS), and Fourier transform infrared (FTIR) spectroscopy. The results show that the nanoworms were assembled by multiple adjacent Ag2S nanoparticles and stabilized by a layer of BSA attached to their surface. The nanoworms have the sizes of about 50 nm in diameter and hundreds of nanometers in length. The analyses of high-resolution TEM and their correlative Fast Fourier Transform (FFT) indicate that the adjacent Ag2S nanoparticles grow by misoriented attachment at the connective interfaces to form the nanoworm structure. In vitro assays on the human cervical cancer cell line HeLa show that the nanoworms exhibit good biocompatibility due to the presence of BSA coating. This combination of features makes the nanoworms attractive and promising building blocks for advanced materials and devices.

Final design of SITELLE: a wide-field imaging Fourier transform spectrometer for the Canada-France-Hawaii Telescope

NASA Astrophysics Data System (ADS)

Grandmont, F.; Drissen, L.; Mandar, Julie; Thibault, S.; Baril, Marc

2012-09-01

We report here on the current status of SITELLE, an imaging Fourier transform spectrometer to be installed on the Canada-France Hawaii Telescope in 2013. SITELLE is an Integral Field Unit (IFU) spectrograph capable of obtaining the visible (350 nm - 900 nm) spectrum of every pixel of a 2k x 2k CCD imaging a field of view of 11 x 11 arcminutes, with 100% spatial coverage and a spectral resolution ranging from R = 1 (deep panchromatic image) to R < 104 (for gas dynamics). SITELLE will cover a field of view 100 to 1000 times larger than traditional IFUs, such as GMOS-IFU on Gemini or the upcoming MUSE on the VLT. SITELLE follows on the legacy of BEAR, an imaging conversion of the CFHT FTS and the direct successor of SpIOMM, a similar instrument attached to the 1.6-m telescope of the Observatoire du Mont-Mégantic in Québec. SITELLE will be used to study the structure and kinematics of HII regions and ejecta around evolved stars in the Milky Way, emission-line stars in clusters, abundances in nearby gas-rich galaxies, and the star formation rate in distant galaxies.

New possibility on InZnO nano thin film for green emissive optoelectronic devices

NASA Astrophysics Data System (ADS)

Sugumaran, Sathish; Noor Bin Ahmad, Mohd; Faizal Jamlos, Mohd; Bellan, Chandar Shekar; Chandran, Sharmila; Sivaraj, Manoj

2016-04-01

Indium zinc oxide (InZnO) nano thin film was prepared from InZnO nanoparticles (NPs) by thermal evaporation technique. Fourier transform infrared spectroscopy showed the presence of metal-oxide bond. X-ray diffraction pattern revealed the mixed phase structure. The presence of elements In, Zn and O were identified from energy dispersive X-ray analysis. Size of the NPs was found to be 171 and 263 nm by transmission electron microscopy. Scanning electron microscopy image showed the spherical shape uniform morphology with uniform distribution grains. Photoluminescence spectrum exhibited a broad green emission for InZnO nano thin film. The acquired results of structure, smooth morphology and photoluminescence property suggested that the InZnO nano thin film to be a promising material for room temperature green emissive optoelectronic, laser diodes, solar cells and other optical devices.

Study of Ce3+, Dy3+ and Eu3+ activated SrSnO3 for white LEDs

NASA Astrophysics Data System (ADS)

Jain, Neha; Pandey, Deepak Kumar; Singh, Rajan Kumar; Singh, Jai; Singh, R. A.

2018-05-01

Herein, Eu3+- Dy3+-Ce3+ tri-doped SrSnO3 have been prepared by conventional sol-gel method. XRD analysis confirmed its orthorhombic phase with Pnma (62) space group symmetry. The morphology of the sample is flake like which has examined by SEM. SrSnO3 consists of several vibrational modes due to Sn-O bond which was analysed by Fourier transform Infrared (FTIR) spectra. Photoluminescence (PL) emission and excitation spectra have been recorded for optical analysis. It consist characteristic emission peaks of Ce3+, Dy3+ and Eu3. The intensity of 590 nm emission increases with increasing Eu3+ concentration and it is maximum for 3 at% Eu3+ co-doped sample. The CIE chromaticity co-ordinates are found near white region so it would be a promising phosphor for white LEDs.

Real-time processing for full-range Fourier-domain optical-coherence tomography with zero-filling interpolation using multiple graphic processing units.

PubMed

Watanabe, Yuuki; Maeno, Seiya; Aoshima, Kenji; Hasegawa, Haruyuki; Koseki, Hitoshi

2010-09-01

The real-time display of full-range, 2048?axial pixelx1024?lateral pixel, Fourier-domain optical-coherence tomography (FD-OCT) images is demonstrated. The required speed was achieved by using dual graphic processing units (GPUs) with many stream processors to realize highly parallel processing. We used a zero-filling technique, including a forward Fourier transform, a zero padding to increase the axial data-array size to 8192, an inverse-Fourier transform back to the spectral domain, a linear interpolation from wavelength to wavenumber, a lateral Hilbert transform to obtain the complex spectrum, a Fourier transform to obtain the axial profiles, and a log scaling. The data-transfer time of the frame grabber was 15.73?ms, and the processing time, which includes the data transfer between the GPU memory and the host computer, was 14.75?ms, for a total time shorter than the 36.70?ms frame-interval time using a line-scan CCD camera operated at 27.9?kHz. That is, our OCT system achieved a processed-image display rate of 27.23 frames/s.

A new Fourier transform based CBIR scheme for mammographic mass classification: a preliminary invariance assessment

NASA Astrophysics Data System (ADS)

Gundreddy, Rohith Reddy; Tan, Maxine; Qui, Yuchen; Zheng, Bin

2015-03-01

The purpose of this study is to develop and test a new content-based image retrieval (CBIR) scheme that enables to achieve higher reproducibility when it is implemented in an interactive computer-aided diagnosis (CAD) system without significantly reducing lesion classification performance. This is a new Fourier transform based CBIR algorithm that determines image similarity of two regions of interest (ROI) based on the difference of average regional image pixel value distribution in two Fourier transform mapped images under comparison. A reference image database involving 227 ROIs depicting the verified soft-tissue breast lesions was used. For each testing ROI, the queried lesion center was systematically shifted from 10 to 50 pixels to simulate inter-user variation of querying suspicious lesion center when using an interactive CAD system. The lesion classification performance and reproducibility as the queried lesion center shift were assessed and compared among the three CBIR schemes based on Fourier transform, mutual information and Pearson correlation. Each CBIR scheme retrieved 10 most similar reference ROIs and computed a likelihood score of the queried ROI depicting a malignant lesion. The experimental results shown that three CBIR schemes yielded very comparable lesion classification performance as measured by the areas under ROC curves with the p-value greater than 0.498. However, the CBIR scheme using Fourier transform yielded the highest invariance to both queried lesion center shift and lesion size change. This study demonstrated the feasibility of improving robustness of the interactive CAD systems by adding a new Fourier transform based image feature to CBIR schemes.

Discrete Fourier Transform Analysis in a Complex Vector Space

NASA Technical Reports Server (NTRS)

Dean, Bruce H.

2009-01-01

Alternative computational strategies for the Discrete Fourier Transform (DFT) have been developed using analysis of geometric manifolds. This approach provides a general framework for performing DFT calculations, and suggests a more efficient implementation of the DFT for applications using iterative transform methods, particularly phase retrieval. The DFT can thus be implemented using fewer operations when compared to the usual DFT counterpart. The software decreases the run time of the DFT in certain applications such as phase retrieval that iteratively call the DFT function. The algorithm exploits a special computational approach based on analysis of the DFT as a transformation in a complex vector space. As such, this approach has the potential to realize a DFT computation that approaches N operations versus Nlog(N) operations for the equivalent Fast Fourier Transform (FFT) calculation.

Instrument Line Shape Modeling and Correction for Off-Axis Detectors in Fourier Transform Spectrometry

NASA Technical Reports Server (NTRS)

Bowman, K.; Worden, H.; Beer, R.

1999-01-01

Spectra measured by off-axis detectors in a high-resolution Fourier transform spectrometer (FTS) are characterized by frequency scaling, asymmetry and broadening of their line shape, and self-apodization in the corresponding interferogram.

Fourier Transform Mass Spectrometry.

ERIC Educational Resources Information Center

Gross, Michael L.; Rempel, Don L.

1984-01-01

Discusses the nature of Fourier transform mass spectrometry and its unique combination of high mass resolution, high upper mass limit, and multichannel advantage. Examines its operation, capabilities and limitations, applications (ion storage, ion manipulation, ion chemistry), and future applications and developments. (JN)

Fourier Transform Infrared Spectroscopy: Part II. Advantages of FT-IR.

ERIC Educational Resources Information Center

Perkins, W. D.

1987-01-01

This is Part II in a series on Fourier transform infrared spectroscopy (FT-IR). Described are various advantages of FT-IR spectroscopy including energy advantages, wavenumber accuracy, constant resolution, polarization effects, and stepping at grating changes. (RH)

A fast Karhunen-Loeve transform for a class of random processes

NASA Technical Reports Server (NTRS)

Jain, A. K.

1976-01-01

It is shown that for a class of finite first-order Markov signals, the Karhunen-Loeve (KL) transform for data compression is a set of periodic sine functions if the boundary values of the signal are fixed or known. These sine functions are shown to be related to the Fourier transform so that a fast Fourier transform algorithm can be used to implement the KL transform. Extension to two dimensions with reference to images with separable contravariance function is shown.

Cu incorporated amorphous diamond like carbon (DLC) composites: An efficient electron field emitter over a wide range of temperature

NASA Astrophysics Data System (ADS)

Ahmed, Sk Faruque; Alam, Md Shahbaz; Mukherjee, Nillohit

2018-03-01

The effect of temperature on the electron field emission properties of copper incorporated amorphous diamond like carbon (a-Cu:DLC) thin films have been reported. The a-Cu:DLC thin films have been deposited on indium tin oxide (ITO) coated glass and silicon substrate by the radio frequency sputtering process. The chemical composition of the films was investigated using X-ray photoelectron spectroscopy and the micro structure was established using high resolution transmission electron microscopy. The sp2 and sp3 bonding ratio in the a-Cu:DLC have been analyzed by the Fourier transformed infrared spectroscopy studies. The material showed excellent electron field emission properties; which was optimized by varying the copper atomic percentage and temperature of the films. It was found that the threshold field and effective emission barrier were reduced significantly by copper incorporation as well as temperature and a detailed explanation towards emission mechanism has been provided.

Efficient cold cathode emission in crystalline-amorphous hybrid: Study on carbon nanotube-cadmium selenide system

NASA Astrophysics Data System (ADS)

Sarkar, S.; Banerjee, D.; Das, N. S.; Ghorai, U. K.; Sen, D.; Chattopadhyay, K. K.

2018-03-01

Cadmium Selenide (CdSe) quantum dot (QD) decorated amorphous carbon nanotubes (a-CNTs) hybrids have been synthesized by simple chemical process. The samples were characterized by field emission scanning and transmission electron microscopy, Fourier transformed infrared spectroscopy, Raman and UV-Vis spectroscopy. Lattice image obtained from transmission electron microscopic study confirms the successful attachment of CdSe QDs. It is seen that hybrid samples show an enhanced cold emission properties with good stability. The results have been explained in terms of increased roughness, more numbers of emitting sites and favorable band bending induced electron transport. ANSYS software based calculation has also supported the result. Also a first principle based study has been done which shows that due to the formation of hybrid structure there is a profound upward shift in the Fermi level, i.e. a decrease of work function, which is believed to be another key reason for the observed improved field emission performance.

In Situ Measurements of Spectral Emissivity of Materials for Very High Temperature Reactors

DOE Office of Scientific and Technical Information (OSTI.GOV)

G. Cao; S. J. Weber; S. O. Martin

2011-08-01

An experimental facility for in situ measurements of high-temperature spectral emissivity of materials in environments of interest to the gas-cooled very high temperature reactor (VHTR) has been developed. The facility is capable of measuring emissivities of seven materials in a single experiment, thereby enhancing the accuracy in measurements due to even minor systemic variations in temperatures and environments. The system consists of a cylindrical silicon carbide (SiC) block with seven sample cavities and a deep blackbody cavity, a detailed optical system, and a Fourier transform infrared spectrometer. The reliability of the facility has been confirmed by comparing measured spectral emissivitiesmore » of SiC, boron nitride, and alumina (Al2O3) at 600 C against those reported in literature. The spectral emissivities of two candidate alloys for VHTR, INCONEL{reg_sign} alloy 617 (INCONEL is a registered trademark of the Special Metals Corporation group of companies) and SA508 steel, in air environment at 700 C were measured.« less

Rates of volcanic CO2 degassing from airborne determinations of SO2 Emission rates and plume CO2SO2: test study at Pu′u ′O′o Cone, Kilauea Volcano, Hawaii

USGS Publications Warehouse

Gerlach, Terrence M.; McGee, Kenneth A.; Sutton, A. Jefferson; Elias, Tamar

1998-01-01

We present an airborne method that eliminates or minimizes several disadvantages of the customary plume cross-section sampling method for determining volcanic CO2 emission rates. A LI-COR CO2analyzer system (LICOR), a Fourier transform infrared spectrometer system (FTIR), and a correlation spectrometer (COSPEC) were used to constrain the plume CO2/SO2 and the SO2 emission rate. The method yielded a CO2 emission rate of 300 td−1 (metric tons per day) for Pu′u ′O′o cone, Kilauea volcano, on 19 September 1995. The CO2/SO2 of 0.20 determined from airborne LICOR and FTIR plume measurements agreed with the CO2/SO2 of 204 ground-based samples collected from vents over a 14-year period since the Pu′u ′O′o eruption began in January 1983.

KAM Tori Construction Algorithms

NASA Astrophysics Data System (ADS)

Wiesel, W.

In this paper we evaluate and compare two algorithms for the calculation of KAM tori in Hamiltonian systems. The direct fitting of a torus Fourier series to a numerically integrated trajectory is the first method, while an accelerated finite Fourier transform is the second method. The finite Fourier transform, with Hanning window functions, is by far superior in both computational loading and numerical accuracy. Some thoughts on applications of KAM tori are offered.

Generalized fiber Fourier optics.

PubMed

Cincotti, Gabriella

2011-06-15

A twofold generalization of the optical schemes that perform the discrete Fourier transform (DFT) is given: new passive planar architectures are presented where the 2 × 2 3 dB couplers are replaced by M × M hybrids, reducing the number of required connections and phase shifters. Furthermore, the planar implementation of the discrete fractional Fourier transform (DFrFT) is also described, with a waveguide grating router (WGR) configuration and a properly modified slab coupler.

QUANTITATIVE FOURIER TRANSFORM INFRARED SPECTROSCOPIC INVESTIGATION OF HUMIC SUBSTANCE FUNCTIONAL GROUP COMPOSITION

EPA Science Inventory

Infrared (IR) spectroscopy has been widely used for the structural investigation of humic substances. Although Fourier Transform Infrared (FTIR) instrumentation has been available for sometime, relatively little work with these instruments has been reported for humic substances,...

Fast Fourier Transform Spectral Analysis Program

NASA Technical Reports Server (NTRS)

Daniel, J. A., Jr.; Graves, M. L.; Hovey, N. M.

1969-01-01

Fast Fourier Transform Spectral Analysis Program is used in frequency spectrum analysis of postflight, space vehicle telemetered trajectory data. This computer program with a digital algorithm can calculate power spectrum rms amplitudes and cross spectrum of sampled parameters at even time increments.

[Research on spatially modulated Fourier transform imaging spectrometer data processing method].

PubMed

Huang, Min; Xiangli, Bin; Lü, Qun-Bo; Zhou, Jin-Song; Jing, Juan-Juan; Cui, Yan

2010-03-01

Fourier transform imaging spectrometer is a new technic, and has been developed very rapidly in nearly ten years. The data catched by Fourier transform imaging spectrometer is indirect data, can not be used by user, and need to be processed by various approaches, including data pretreatment, apodization, phase correction, FFT, and spectral radicalization calibration. No paper so far has been found roundly to introduce this method. In the present paper, the author will give an effective method to process the interfering data to spectral data, and with this method we can obtain good result.

Deficiencies of the cryptography based on multiple-parameter fractional Fourier transform.

PubMed

Ran, Qiwen; Zhang, Haiying; Zhang, Jin; Tan, Liying; Ma, Jing

2009-06-01

Methods of image encryption based on fractional Fourier transform have an incipient flaw in security. We show that the schemes have the deficiency that one group of encryption keys has many groups of keys to decrypt the encrypted image correctly for several reasons. In some schemes, many factors result in the deficiencies, such as the encryption scheme based on multiple-parameter fractional Fourier transform [Opt. Lett.33, 581 (2008)]. A modified method is proposed to avoid all the deficiencies. Security and reliability are greatly improved without increasing the complexity of the encryption process. (c) 2009 Optical Society of America.

Fourier Transform Emission Spectroscopy of the [7.3] 2Δ- a2Φ and [9.4] 2Φ- a2Φ Systems of ZrCl

NASA Astrophysics Data System (ADS)

Ram, R. S.; Bernath, P. F.

1999-08-01

The emission spectrum of ZrCl has been observed in the 1800-12 000 cm-1 region using a Fourier transform spectrometer. The molecules were excited in a microwave discharge of a mixture of helium and a trace of ZrCl4 vapor. In addition to the C4Δ-X4Φ transition reported previously, numerous new bands observed in the near infrared have been classified into two electronic transitions, [7.3]2Δ-a2Φ and [9.4]2Φ-a2Φ. Five new bands observed in the 6700-7400 cm-1 region have been assigned as 2Δ3/2-2Φ5/2 and 2Δ5/2-2Φ7/2 subbands of a new electronic transition, [7.3]2Δ-a2Φ. The two subbands of the [9.4]2Φ-a2Φ transition were previously observed by G. Phillips, S. P. Davis, and D. C. Galehouse [Astrophys. J. Suppl. 43, 417-434 (1980)], who tentatively labeled them as 2Π1/2-2Π1/2 and 2Π3/2-2Π3/2 subbands. A number of new bands involving higher vibrational levels have been identified for these two subbands. A rotational analysis of a number of bands of both transitions has been obtained and spectroscopic constants have been determined. Global perturbations have been observed in both spin components of the a2Φ state. The assignment of the observed electronic states has been discussed in light of recent theoretical calculations.

Surface-functionalized cockle shell–based calcium carbonate aragonite polymorph as a drug nanocarrier

PubMed Central

Mohd Abd Ghafar, Syairah Liyana; Hussein, Mohd Zobir; Rukayadi, Yaya; Abu Bakar Zakaria, Md Zuki

2017-01-01

Calcium carbonate aragonite polymorph nanoparticles derived from cockle shells were prepared using surface functionalization method followed by purification steps. Size, morphology, and surface properties of the nanoparticles were characterized using transmission electron microscopy, field emission scanning electron microscopy, dynamic light scattering, zetasizer, X-ray powder diffraction, and Fourier transform infrared spectrometry techniques. The potential of surface-functionalized calcium carbonate aragonite polymorph nanoparticle as a drug-delivery agent were assessed through in vitro drug-loading test and drug-release test. Transmission electron microscopy, field emission scanning electron microscopy, and particle size distribution analyses revealed that size, morphology, and surface characterization had been improved after surface functionalization process. Zeta potential of the nanoparticles was found to be increased, thereby demonstrating better dispersion among the nanoparticles. Purification techniques showed a further improvement in the overall distribution of nanoparticles toward more refined size ranges <100 nm, which specifically favored drug-delivery applications. The purity of the aragonite phase and their chemical analyses were verified by X-ray powder diffraction and Fourier transform infrared spectrometry studies. In vitro biological response of hFOB 1.19 osteoblast cells showed that surface functionalization could improve the cytotoxicity of cockle shell–based calcium carbonate aragonite nanocarrier. The sample was also sensitive to pH changes and demonstrated good abilities to load and sustain in vitro drug. This study thus indicates that calcium carbonate aragonite polymorph nanoparticles derived from cockle shells, a natural biomaterial, with modified surface characteristics are promising and can be applied as efficient carriers for drug delivery. PMID:28572724

A 2D Fourier tool for the analysis of photo-elastic effect in large granular assemblies

NASA Astrophysics Data System (ADS)

Leśniewska, Danuta

2017-06-01

Fourier transforms are the basic tool in constructing different types of image filters, mainly those reducing optical noise. Some DIC or PIV software also uses frequency space to obtain displacement fields from a series of digital images of a deforming body. The paper presents series of 2D Fourier transforms of photo-elastic transmission images, representing large pseudo 2D granular assembly, deforming under varying boundary conditions. The images related to different scales were acquired using the same image resolution, but taken at different distance from the sample. Fourier transforms of images, representing different stages of deformation, reveal characteristic features at the three (`macro-`, `meso-` and `micro-`) scales, which can serve as a data to study internal order-disorder transition within granular materials.

Bessel function expansion to reduce the calculation time and memory usage for cylindrical computer-generated holograms.

PubMed

Sando, Yusuke; Barada, Daisuke; Jackin, Boaz Jessie; Yatagai, Toyohiko

2017-07-10

This study proposes a method to reduce the calculation time and memory usage required for calculating cylindrical computer-generated holograms. The wavefront on the cylindrical observation surface is represented as a convolution integral in the 3D Fourier domain. The Fourier transformation of the kernel function involving this convolution integral is analytically performed using a Bessel function expansion. The analytical solution can drastically reduce the calculation time and the memory usage without any cost, compared with the numerical method using fast Fourier transform to Fourier transform the kernel function. In this study, we present the analytical derivation, the efficient calculation of Bessel function series, and a numerical simulation. Furthermore, we demonstrate the effectiveness of the analytical solution through comparisons of calculation time and memory usage.

Enhancement of Signal-to-noise Ratio in Natural-source Transient Magnetotelluric Data with Wavelet Transform

NASA Astrophysics Data System (ADS)

Zhang, Y.; Paulson, K. V.

For audio-frequency magnetotelluric surveys where the signals are lightning-stroke transients, the conventional Fourier transform method often fails to produce a high quality impedance tensor. An alternative approach is to use the wavelet transform method which is capable of localizing target information simultaneously in both the temporal and frequency domains. Unlike Fourier analysis that yields an average amplitude and phase, the wavelet transform produces an instantaneous estimate of the amplitude and phase of a signal. In this paper a complex well-localized wavelet, the Morlet wavelet, has been used to transform and analyze audio-frequency magnetotelluric data. With the Morlet wavelet, the magnetotelluric impedance tensor can be computed directly in the wavelet transform domain. The lightning-stroke transients are easily identified on the dilation-translation plane. Choosing those wavelet transform values where the signals are located, a higher signal-to-noise ratio estimation of the impedance tensor can be obtained. In a test using real data, the wavelet transform showed a significant improvement in the signal-to-noise ratio over the conventional Fourier transform.

Fourier transform spectroscopy of cotton and cotton trash

USDA-ARS?s Scientific Manuscript database

Fourier Transform techniques have been shown to have higher signal-to-noise capabilities, higher throughput, negligible stray light, continuous spectra, and higher resolution. In addition, FT spectroscopy affords for frequencies in spectra to be measured all at once and more precise wavelength calib...

The Fourier Transform in Chemistry. Part 1. Nuclear Magnetic Resonance: Introduction.

ERIC Educational Resources Information Center

King, Roy W.; Williams, Kathryn R.

1989-01-01

Using fourier transformation methods in nuclear magnetic resonance has made possible increased sensitivity in chemical analysis. This article describes these methods as they relate to magnetization, the RF magnetic field, nuclear relaxation, the RF pulse, and free induction decay. (CW)

ENVIRONMENTAL ANALYSIS BY AB INITIO QUANTUM MECHANICAL COMPUTATION AND GAS CHROMATOGRAPHY/FOURIER TRANSFORM INFRARED SPECTROMETRY.

EPA Science Inventory

Computational chemistry, in conjunction with gas chromatography/mass spectrometry/Fourier transform infrared spectrometry (GC/MS/FT-IR), was used to tentatively identify seven tetrachlorobutadiene (TCBD) isomers detected in an environmental sample. Computation of the TCBD infrare...

Modification of fluorescence and optical properties of Rhodamine B dye doped PVA/Chitosan polymer blend films

NASA Astrophysics Data System (ADS)

Padmakumari, R.; Ravindrachary, V.; Mahantesha, B. K.; Sagar, Rohan N.; Sahanakumari, R.; Bhajantri, R. F.

2018-05-01

Pure and Rhodamine B doped Poly (vinyl alcohol)/Chitosan composite films are prepared using solution casting method. Fourier transforms infrared spectra (FTIR), Ultraviolet-Visible (UV-Vis), fluorescence studies were used to characterize the prepared polymer films. The FT-IR results show that the appearance of new peaks along with shift in peak positions indicates the interaction of Rhodamine B with PVA-CS blend. Optical absorption edge, band gap and activation energy were determined from UV-Visible studies. The optical absorption edge increases, band gap decreases and activation energy increases with dopant concentration respectively. The corresponding emission spectra were studied using fluorescence spectroscopy. From the fluorescence study the quenching phenomena are observed in emission wavelength range of 607nm-613nm upon excitation with absorption maxima 443nm.

Hydrothermally synthesized flower like MoS2 microsphere: A highly efficient adsorbent for methylene blue dye removal

NASA Astrophysics Data System (ADS)

Panda, Jnanranjan; Tudu, Bharati

2018-05-01

Herein, a flower like MoS2 (M1) microsphere assembled by layered porous nanosheet was successfully prepared by facile hydrothermal synthesis procedure. The structural, chemical and morphological characterizations for the as synthesized sample (M1) were carried out by powder x-ray diffraction (PXRD), Fourier-transform infrared (FTIR) and Field Emission Scanning Electron microscope (FESEM) respectively and spectroscopic characterization was performed by UV-Vis absorption and photoluminescence emission spectroscopy. The photocatalytic activity of the product was evaluated through photocatalytic degradation of Methylene Blue under visible light irradiation. The results indicate that layered MoS2structures possess significant adsorption ability, which may be useful for further research and practical applications of the layered MoS2 adsorbent in wastewater treatment.

A SITELLE view of M31's central region - I. Calibrations and radial velocity catalogue of nearly 800 emission-line point-like sources

NASA Astrophysics Data System (ADS)

Martin, Thomas B.; Drissen, Laurent; Melchior, Anne-Laure

2018-01-01

We present a detailed description of the wavelength, astrometric and photometric calibration plan for SITELLE, the imaging Fourier transform spectrometer attached to the Canada-France-Hawaii telescope, based on observations of a red (647-685 nm) data cube of the central region (11 arcmin × 11 arcmin) of M 31. The first application, presented in this paper is a radial-velocity catalogue (with uncertainties of ∼2-6 km s-1) of nearly 800 emission-line point-like sources, including ∼450 new discoveries. Most of the sources are likely planetary nebulae, although we also detect five novae (having erupted in the first eight months of 2016) and one new supernova remnant candidate.

Annual and Semi-Annual Temperature Oscillations in the Upper Mesosphere

NASA Technical Reports Server (NTRS)

Niciejewski, R. J.; Killeen, T. L.

1995-01-01

Fourier transform spectrometer observations of the mesosphere have been performed at the University of Michigan (latitude: 42.5 N) on a long term basis. A database of near infrared Meinel hydroxyl spectra has been accumulated from which rotational temperatures have been determined. Harmonic analysis of one-day averaged temperatures for the period 1992.0 to 1994.5 has shown a distinct annual and semi-annual variation. Subsequent fitting of a five term periodic function characterizing the annual and semi-annual temperature oscillations to the daily averaged temperatures was performed. The resultant mean temperature and the amplitudes and phases of the annual and semi-annual variations are shown to coincide with an emission height slightly above 85 km which is consistent with the mean rocket derived altitude for peak nocturnal hydroxyl emission.

A method to perform a fast fourier transform with primitive image transformations.

PubMed

Sheridan, Phil

2007-05-01

The Fourier transform is one of the most important transformations in image processing. A major component of this influence comes from the ability to implement it efficiently on a digital computer. This paper describes a new methodology to perform a fast Fourier transform (FFT). This methodology emerges from considerations of the natural physical constraints imposed by image capture devices (camera/eye). The novel aspects of the specific FFT method described include: 1) a bit-wise reversal re-grouping operation of the conventional FFT is replaced by the use of lossless image rotation and scaling and 2) the usual arithmetic operations of complex multiplication are replaced with integer addition. The significance of the FFT presented in this paper is introduced by extending a discrete and finite image algebra, named Spiral Honeycomb Image Algebra (SHIA), to a continuous version, named SHIAC.

Structure in the 3D Galaxy Distribution. III. Fourier Transforming the Universe: Phase and Power Spectra

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scargle, Jeffrey D.; Way, M. J.; Gazis, P. R., E-mail: Jeffrey.D.Scargle@nasa.gov, E-mail: Michael.J.Way@nasa.gov, E-mail: PGazis@sbcglobal.net

We demonstrate the effectiveness of a relatively straightforward analysis of the complex 3D Fourier transform of galaxy coordinates derived from redshift surveys. Numerical demonstrations of this approach are carried out on a volume-limited sample of the Sloan Digital Sky Survey redshift survey. The direct unbinned transform yields a complex 3D data cube quite similar to that from the Fast Fourier Transform of finely binned galaxy positions. In both cases, deconvolution of the sampling window function yields estimates of the true transform. Simple power spectrum estimates from these transforms are roughly consistent with those using more elaborate methods. The complex Fouriermore » transform characterizes spatial distributional properties beyond the power spectrum in a manner different from (and we argue is more easily interpreted than) the conventional multipoint hierarchy. We identify some threads of modern large-scale inference methodology that will presumably yield detections in new wider and deeper surveys.« less

Algebraic signal processing theory: 2-D spatial hexagonal lattice.

PubMed

Pünschel, Markus; Rötteler, Martin

2007-06-01

We develop the framework for signal processing on a spatial, or undirected, 2-D hexagonal lattice for both an infinite and a finite array of signal samples. This framework includes the proper notions of z-transform, boundary conditions, filtering or convolution, spectrum, frequency response, and Fourier transform. In the finite case, the Fourier transform is called discrete triangle transform. Like the hexagonal lattice, this transform is nonseparable. The derivation of the framework makes it a natural extension of the algebraic signal processing theory that we recently introduced. Namely, we construct the proper signal models, given by polynomial algebras, bottom-up from a suitable definition of hexagonal space shifts using a procedure provided by the algebraic theory. These signal models, in turn, then provide all the basic signal processing concepts. The framework developed in this paper is related to Mersereau's early work on hexagonal lattices in the same way as the discrete cosine and sine transforms are related to the discrete Fourier transform-a fact that will be made rigorous in this paper.

Development of a High-Throughput Microwave Imaging System for Concealed Weapons Detection

DTIC Science & Technology

2016-07-15

hardware. Index Terms—Microwave imaging, multistatic radar, Fast Fourier Transform (FFT). I. INTRODUCTION Near-field microwave imaging is a non-ionizing...configuration, but its computational demands are extreme. Fast Fourier Transform (FFT) imaging has long been used to efficiently construct images sampled with...Simulated image of 25 point scatterers imaged at range 1.5m, with array layout depicted in Fig. 3. Left: image formed with Equation (5) ( Fourier

Fan Beam Emission Tomography for Laminar Fires

NASA Technical Reports Server (NTRS)

Sivathanu, Yudaya; Lim, Jongmook; Feikema, Douglas

2003-01-01

Obtaining information on the instantaneous structure of turbulent and transient flames is important in a wide variety of applications such as fire safety, pollution reduction, flame spread studies, and model validation. Durao et al. has reviewed the different methods of obtaining structure information in reacting flows. These include Tunable Laser Absorption Spectroscopy, Fourier Transform Infrared Spectroscopy, and Emission Spectroscopy to mention a few. Most flames emit significant radiation signatures that are used in various applications such as fire detection, light-off detection, flame diagnostics, etc. Radiation signatures can be utilized to maximum advantage for determining structural information in turbulent flows. Emission spectroscopy is most advantageous in the infrared regions of the spectra, principally because these emission lines arise from transitions in the fundamental bands of stable species such as CO2 and H2O. Based on the above, the objective of this work was to develop a fan beam emission tomography system to obtain the local scalar properties such as temperature and mole fractions of major gas species from path integrated multi-wavelength infrared radiation measurements.

Long-path measurements of pollutants and micrometeorology over Highway 401 in Toronto

NASA Astrophysics Data System (ADS)

You, Yuan; Staebler, Ralf M.; Moussa, Samar G.; Su, Yushan; Munoz, Tony; Stroud, Craig; Zhang, Junhua; Moran, Michael D.

2017-11-01

Traffic emissions contribute significantly to urban air pollution. Measurements were conducted over Highway 401 in Toronto, Canada, with a long-path Fourier transform infrared (FTIR) spectrometer combined with a suite of micrometeorological instruments to identify and quantify a range of air pollutants. Results were compared with simultaneous in situ observations at a roadside monitoring station, and with output from a special version of the operational Canadian air quality forecast model (GEM-MACH). Elevated mixing ratios of ammonia (0-23 ppb) were observed, of which 76 % were associated with traffic emissions. Hydrogen cyanide was identified at mixing ratios between 0 and 4 ppb. Using a simple dispersion model, an integrated emission factor of on average 2.6 g km-1 carbon monoxide was calculated for this defined section of Highway 401, which agreed well with estimates based on vehicular emission factors and observed traffic volumes. Based on the same dispersion calculations, vehicular average emission factors of 0.04, 0.36, and 0.15 g km-1 were calculated for ammonia, nitrogen oxide, and methanol, respectively.

Methane and carbon dioxide emissions from Shan-Chu-Ku landfill site in northern Taiwan.

PubMed

Hegde, Ullas; Chang, Tsan-Chang; Yang, Shang-Shyng

2003-09-01

To investigate the methane and carbon dioxide emissions from landfill, samples were taken of material up to 5 years old from Shan-Chu-Ku landfill located in the northern part of Taiwan. Atmospheric concentrations of carbon dioxide, methane and nitrous oxide ranged from 310 to 530, 2.64 to 20.16 and 0.358 to 1.516 ppmv with the measurement of gas-type open-path Fourier transform infra-red (FTIR) spectroscopy during February 1998 to March 2000, respectively. Average methane emission rate was 13.17, 65.27 and 0.99 mgm(-2)h(-1) measured by the gas chromatography chamber method in 1-2, 2-3 and 5 year-old landfill, respectively. Similarly, average carbon dioxide emission rate was 93.70, 314.60 and 48.46 mgm(-2)h(-1), respectively. About 2-3 year-old landfill had the highest methane and carbon dioxide emission rates among the tested areas, while 5 year-old landfill was the least. Methane emission rate at night in most tested locations was higher than that in the daytime. Total amount of methane and carbon dioxide emission from this landfill was around 171 and 828 ton in 1999, respectively.

Formulation of the rotational transformation of wave fields and their application to digital holography.

PubMed

Matsushima, Kyoji

2008-07-01

Rotational transformation based on coordinate rotation in Fourier space is a useful technique for simulating wave field propagation between nonparallel planes. This technique is characterized by fast computation because the transformation only requires executing a fast Fourier transform twice and a single interpolation. It is proved that the formula of the rotational transformation mathematically satisfies the Helmholtz equation. Moreover, to verify the formulation and its usefulness in wave optics, it is also demonstrated that the transformation makes it possible to reconstruct an image on arbitrarily tilted planes from a wave field captured experimentally by using digital holography.

A Method to Compute the Force Signature of a Body Impacting on a Linear Elastic Structure Using Fourier Analysis

DTIC Science & Technology

1982-09-17

FK * 1PK (2) The convolution of two transforms in time domain is the inverse transform of the product in frequency domain. Thus Rp(s) - Fgc() Ipg(*) (3...its inverse transform by: R,(r)- R,(a.)e’’ do. (5)2w In order to nuke use f a very accurate numerical method to ompute Fourier "ke and coil...taorm. When the inverse transform it tken by using Eq. (15), the cosine transform, because it converges faster than the sine transform refu-ft the

EVALUATION OF A PORTABLE FOURIER TRANSFORM INFRARED GAS ANALYZER FOR MEASUREMENTS OF AIR TOXICS IN POLLUTION PREVENTION RESEARCH

EPA Science Inventory

A portable Fourier transform infrared gas analyzer with a photoacoustic detector performed reliably during pollution prevention research at two industrial facilities. It exhibited good agreement (within approximately 6%) with other analytical instruments (dispersive infrared and ...

PARTICULATE MATTER MEASUREMENTS USING OPEN-PATH FOURIER TRANSFORM INFRARED SPECTROSCOPY

EPA Science Inventory

Open-path Fourier transform infrared (OP-FT1R) spectroscopy is an accepted technology for measuring gaseous air contaminants. OP-FT1R absorbance spectra acquired during changing aerosols conditions reveal related changes in very broad baseline features. Usually, this shearing of ...

Gravity data inversion to determine 3D topographycal density contrast of Banten area, Indonesia based on fast Fourier transform

NASA Astrophysics Data System (ADS)

Windhari, Ayuty; Handayani, Gunawan

2015-04-01

The 3D inversion gravity anomaly to estimate topographical density using a matlab source code from gridded data provided by Parker Oldenburg algorithm based on fast Fourier transform was computed. We extend and improved the source code of 3DINVERT.M invented by Gomez Ortiz and Agarwal (2005) using the relationship between Fourier transform of the gravity anomaly and the sum of the Fourier transform from the topography density. We gave density contrast between the two media to apply the inversion. FFT routine was implemented to construct amplitude spectrum to the given mean depth. The results were presented as new graphics of inverted topography density, the gravity anomaly due to the inverted topography and the difference between the input gravity data and the computed ones. It terminates when the RMS error is lower than pre-assigned value used as convergence criterion or until maximum of iterations is reached. As an example, we used the matlab program on gravity data of Banten region, Indonesia.

Construction of high frame rate images with Fourier transform

NASA Astrophysics Data System (ADS)

Peng, Hu; Lu, Jian-Yu

2002-05-01

Traditionally, images are constructed with a delay-and-sum method that adjusts the phases of received signals (echoes) scattered from the same point in space so that they are summed in phase. Recently, the relationship between the delay-and-sum method and the Fourier transform is investigated [Jian-yu Lu, Anjun Liu, and Hu Peng, ``High frame rate and delay-and-sum imaging methods,'' IEEE Trans. Ultrason. Ferroelectr. Freq. Control (submitted)]. In this study, a generic Fourier transform method is developed. Two-dimensional (2-D) or three-dimensional (3-D) high frame rate images can be constructed using the Fourier transform with a single transmission of an ultrasound pulse from an array as long as the transmission field of the array is known. To verify our theory, computer simulations have been performed with a linear array, a 2-D array, a convex curved array, and a spherical 2-D array. The simulation results are consistent with our theory. [Work supported in part by Grant 5RO1 HL60301 from NIH.

Wavelength-encoded tomography based on optical temporal Fourier transform

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Chi; Wong, Kenneth K. Y., E-mail: kywong@eee.hku.hk

We propose and demonstrate a technique called wavelength-encoded tomography (WET) for non-invasive optical cross-sectional imaging, particularly beneficial in biological system. The WET utilizes time-lens to perform the optical Fourier transform, and the time-to-wavelength conversion generates a wavelength-encoded image of optical scattering from internal microstructures, analogous to the interferometery-based imaging such as optical coherence tomography. Optical Fourier transform, in principle, comes with twice as good axial resolution over the electrical Fourier transform, and will greatly simplify the digital signal processing after the data acquisition. As a proof-of-principle demonstration, a 150 -μm (ideally 36 μm) resolution is achieved based on a 7.5-nm bandwidth swept-pump,more » using a conventional optical spectrum analyzer. This approach can potentially achieve up to 100-MHz or even higher frame rate with some proven ultrafast spectrum analyzer. We believe that this technique is innovative towards the next-generation ultrafast optical tomographic imaging application.« less

The limit distribution in the q-CLT for q\\,\\geqslant \\,1 is unique and can not have a compact support

NASA Astrophysics Data System (ADS)

Umarov, Sabir; Tsallis, Constantino

2016-10-01

In a paper by Umarov et al (2008 Milan J. Math. 76 307-28), a generalization of the Fourier transform, called the q-Fourier transform, was introduced and applied for the proof of a q-generalized central limit theorem (q-CLT). Subsequently, Hilhorst illustrated (2009 Braz. J. Phys. 39 371-9 2010 J. Stat. Mech. P10023) that the q-Fourier transform for q\\gt 1, is not invertible in the space of density functions. Indeed, using an invariance principle, he constructed a family of densities with the same q-Fourier transform and noted that ‘as a consequence, the q-CLT falls short of achieving its stated goal’. The distributions constructed there have compact support. We prove now that the limit distribution in the q-CLT is unique and can not have a compact support. This result excludes all the possible counterexamples which can be constructed using the invariance principle and fills the gap mentioned by Hilhorst.

Application of the fractional Fourier transform to image reconstruction in MRI.

PubMed

Parot, Vicente; Sing-Long, Carlos; Lizama, Carlos; Tejos, Cristian; Uribe, Sergio; Irarrazaval, Pablo

2012-07-01

The classic paradigm for MRI requires a homogeneous B(0) field in combination with linear encoding gradients. Distortions are produced when the B(0) is not homogeneous, and several postprocessing techniques have been developed to correct them. Field homogeneity is difficult to achieve, particularly for short-bore magnets and higher B(0) fields. Nonlinear magnetic components can also arise from concomitant fields, particularly in low-field imaging, or intentionally used for nonlinear encoding. In any of these situations, the second-order component is key, because it constitutes the first step to approximate higher-order fields. We propose to use the fractional Fourier transform for analyzing and reconstructing the object's magnetization under the presence of quadratic fields. The fractional fourier transform provides a precise theoretical framework for this. We show how it can be used for reconstruction and for gaining a better understanding of the quadratic field-induced distortions, including examples of reconstruction for simulated and in vivo data. The obtained images have improved quality compared with standard Fourier reconstructions. The fractional fourier transform opens a new paradigm for understanding the MR signal generated by an object under a quadratic main field or nonlinear encoding. Copyright © 2011 Wiley Periodicals, Inc.

Application of fast Fourier transforms to the direct solution of a class of two-dimensional separable elliptic equations on the sphere

NASA Technical Reports Server (NTRS)

Moorthi, Shrinivas; Higgins, R. W.

1993-01-01

An efficient, direct, second-order solver for the discrete solution of a class of two-dimensional separable elliptic equations on the sphere (which generally arise in implicit and semi-implicit atmospheric models) is presented. The method involves a Fourier transformation in longitude and a direct solution of the resulting coupled second-order finite-difference equations in latitude. The solver is made efficient by vectorizing over longitudinal wave-number and by using a vectorized fast Fourier transform routine. It is evaluated using a prescribed solution method and compared with a multigrid solver and the standard direct solver from FISHPAK.

Eliminating the zero spectrum in Fourier transform profilometry using empirical mode decomposition.

PubMed

Li, Sikun; Su, Xianyu; Chen, Wenjing; Xiang, Liqun

2009-05-01

Empirical mode decomposition is introduced into Fourier transform profilometry to extract the zero spectrum included in the deformed fringe pattern without the need for capturing two fringe patterns with pi phase difference. The fringe pattern is subsequently demodulated using a standard Fourier transform profilometry algorithm. With this method, the deformed fringe pattern is adaptively decomposed into a finite number of intrinsic mode functions that vary from high frequency to low frequency by means of an algorithm referred to as a sifting process. Then the zero spectrum is separated from the high-frequency components effectively. Experiments validate the feasibility of this method.

Angular acceptance analysis of an infrared focal plane array with a built-in stationary Fourier transform spectrometer.

PubMed

Gillard, Frédéric; Ferrec, Yann; Guérineau, Nicolas; Rommeluère, Sylvain; Taboury, Jean; Chavel, Pierre

2012-06-01

Stationary Fourier transform spectrometry is an interesting concept for building reliable field or embedded spectroradiometers, especially for the mid- and far- IR. Here, a very compact configuration of a cryogenic stationary Fourier transform IR (FTIR) spectrometer is investigated, where the interferometer is directly integrated in the focal plane array (FPA). We present a theoretical analysis to explain and describe the fringe formation inside the FTIR-FPA structure when illuminated by an extended source positioned at a finite distance from the detection plane. The results are then exploited to propose a simple front lens design compatible with a handheld package.

Series: Utilization of Differential Equations and Methods for Solving Them in Medical Physics (4).

PubMed

Murase, Kenya

2016-01-01

Partial differential equations are often used in the field of medical physics. In this (final) issue, the methods for solving the partial differential equations were introduced, which include separation of variables, integral transform (Fourier and Fourier-sine transforms), Green's function, and series expansion methods. Some examples were also introduced, in which the integral transform and Green's function methods were applied to solving Pennes' bioheat transfer equation and the Fourier series expansion method was applied to Navier-Stokes equation for analyzing the wall shear stress in blood vessels.Finally, the author hopes that this series will be helpful for people who engage in medical physics.

Direct generation of abruptly focusing vortex beams using a 3/2 radial phase-only pattern.

PubMed

Davis, Jeffrey A; Cottrell, Don M; Zinn, Jonathan M

2013-03-20

Abruptly focusing Airy beams have previously been generated using a radial cubic phase pattern that represents the Fourier transform of the Airy beam. The Fourier transform of this pattern is formed using a system length of 2f, where f is the focal length of the Fourier transform lens. In this work, we directly generate these abruptly focusing Airy beams using a 3/2 radial phase pattern encoded onto a liquid crystal display. The resulting optical system is much shorter. In addition, we can easily produce vortex patterns at the focal point of these beams. Experimental results match theoretical predictions.

A fast rebinning algorithm for 3D positron emission tomography using John's equation

NASA Astrophysics Data System (ADS)

Defrise, Michel; Liu, Xuan

1999-08-01

Volume imaging in positron emission tomography (PET) requires the inversion of the three-dimensional (3D) x-ray transform. The usual solution to this problem is based on 3D filtered-backprojection (FBP), but is slow. Alternative methods have been proposed which factor the 3D data into independent 2D data sets corresponding to the 2D Radon transforms of a stack of parallel slices. Each slice is then reconstructed using 2D FBP. These so-called rebinning methods are numerically efficient but are approximate. In this paper a new exact rebinning method is derived by exploiting the fact that the 3D x-ray transform of a function is the solution to the second-order partial differential equation first studied by John. The method is proposed for two sampling schemes, one corresponding to a pair of infinite plane detectors and another one corresponding to a cylindrical multi-ring PET scanner. The new FORE-J algorithm has been implemented for this latter geometry and was compared with the approximate Fourier rebinning algorithm FORE and with another exact rebinning algorithm, FOREX. Results with simulated data demonstrate a significant improvement in accuracy compared to FORE, while the reconstruction time is doubled. Compared to FOREX, the FORE-J algorithm is slightly less accurate but more than three times faster.

Determination of Structural Parameters from EXAFS (Extended X-Ray Absorption Fine Structure): Application to Solutions and Catalysts.

DTIC Science & Technology

1984-05-23

the disorder was accurately known. Inverse Transform To isolate the EAFS contribution due to a single feature in the Fourier transform, the inverse ...is associated with setting the "fold" components to 27 zero in r-space. An inverse transform (real part) of the major feature of the Fig. 4 Fourier...phase of the resulting inverse transform represents only any differences between the material being studied and the reference. This residual is

Digital filtering of plume emission spectra

NASA Technical Reports Server (NTRS)

Madzsar, George C.

1990-01-01

Fourier transformation and digital filtering techniques were used to separate the superpositioned spectral phenomena observed in the exhaust plumes of liquid propellant rocket engines. Space shuttle main engine (SSME) spectral data were used to show that extraction of spectral lines in the spatial frequency domain does not introduce error, and extraction of the background continuum introduces only minimal error. Error introduced during band extraction could not be quantified due to poor spectrometer resolution. Based on the atomic and molecular species found in the SSME plume, it was determined that spectrometer resolution must be 0.03 nm for SSME plume spectral monitoring.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Srinivasan, Arvind; Czapla, Braden; Narayanaswamy, Arvind, E-mail: arvind.narayanaswamy@columbia.edu

The complex refractive index of polydimethylsiloxane (PDMS) is determined in the wavelength range between 2.5 μm and 16.7 μm. The parameters of a Drude-Lorentz oscillator model (with 15 oscillators) are extracted from Fourier transform infrared spectroscopy reflectance measurements made on both bulk PDMS and thin films of PDMS deposited on the gold coated silicon substrates. It is shown that thin films of PDMS atop gold exhibit selective emission in the 8 μm to 13 μm atmospheric transmittance window, which demonstrates that PDMS, especially due to its ease of deposition, may be a viable material for passive radiative cooling applications.

In-Flight Performance of the TES Loop Heat Pipe Rejection System: Seven Years in Space

NASA Technical Reports Server (NTRS)

Rodriquez, Jose I.; Na-Nakornpanom, Arthur

2012-01-01

The Tropospheric Emission Spectrometer (TES) is an infrared, high spectral resolution Fourier transform spectrometer with a 3.3 to 15.4 micron wavelength coverage. TES is a scanning instrument intended for determining the chemical state of the Earth's lower atmosphere (troposphere) from the surface to 30+ km. TES produces vertical profiles of important pollutant and greenhouse gases such as carbon monoxide, ozone, methane, and water vapor on a global scale every other day. TES was launched into orbit onboard NASA's earth Observing System Aura spacecraft on July 15, 2004 from Vandenberg Air Force Base, California.

Gas Sensitivity Study of Polypyrrole Decorated Graphene Oxide Thick Film

NASA Astrophysics Data System (ADS)

Patil, Pritam; Gaikwad, Ganesh; Patil, Devidas Ramrao; Naik, Jitendra

2016-04-01

Polypyrrole (PPy) and graphene oxide (GO) nanocomposites were prepared by in situ polymerization method. The synthesized nanocomposites were characterized for current-voltage characteristic, Fourier transform infrared spectroscopy, X-ray diffraction and field emission scanning electron microscopy, which gave the evidence of the strong interaction between PPy nanofibers and GO nanosheets. The PPy/GO nanocomposites were used for the sensing of H2S, LPG, CO2 and NH3 gases respectively at room temperature. It was observed that PPy/GO nanocomposites with different GO weight ratios (5, 10 and 20 %) had better selectivity and sensitivity towards NH3 at room temperature.

Fourier-transform imaging of cotton and botanical and field trash mixtures

USDA-ARS?s Scientific Manuscript database

Botanical and field cotton trash comingled with cotton lint can greatly reduce the marketability and quality of cotton. Trash can be found comingled with cotton lint during harvesting, ginning, and processing, thus this study is of interest. Attenuated Total Reflectance-Fourier Transform Infrared (A...

Detection and classification of salmonella serotypes using spectral signatures collected by fourier transform infrared (FT-IR) spectroscopy

USDA-ARS?s Scientific Manuscript database

Spectral signatures of Salmonella serotypes namely Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky were collected using Fourier transform infrared spectroscopy (FT-IR). About 5-10 µL of Salmonella suspensions with concentrations of 1...

Identification and characterization of salmonella serotypes using DNA spectral characteristics by fourier transform infrared (FT-IR) spectroscopy

USDA-ARS?s Scientific Manuscript database

Analysis of DNA samples of Salmonella serotypes (Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky) were performed using Fourier transform infrared spectroscopy (FT-IR) spectrometer by placing directly in contact with a diamond attenua...

Is Fourier analysis performed by the visual system or by the visual investigator.

PubMed

Ochs, A L

1979-01-01

A numerical Fourier transform was made of the pincushion grid illusion and the spectral components orthogonal to the illusory lines were isolated. Their inverse transform creates a picture of the illusion. The spatial-frequency response of cortical, simple receptive field neurons similarly filters the grid. A complete set of these neurons thus approximates a two-dimensional Fourier analyzer. One cannot conclude, however, that the brain actually uses frequency-domain information to interpret visual images.

Scaled nonuniform Fourier transform for image reconstruction in swept source optical coherence tomography

NASA Astrophysics Data System (ADS)

Mezgebo, Biniyam; Nagib, Karim; Fernando, Namal; Kordi, Behzad; Sherif, Sherif

2018-02-01

Swept Source optical coherence tomography (SS-OCT) is an important imaging modality for both medical and industrial diagnostic applications. A cross-sectional SS-OCT image is obtained by applying an inverse discrete Fourier transform (DFT) to axial interferograms measured in the frequency domain (k-space). This inverse DFT is typically implemented as a fast Fourier transform (FFT) that requires the data samples to be equidistant in k-space. As the frequency of light produced by a typical wavelength-swept laser is nonlinear in time, the recorded interferogram samples will not be uniformly spaced in k-space. Many image reconstruction methods have been proposed to overcome this problem. Most such methods rely on oversampling the measured interferogram then use either hardware, e.g., Mach-Zhender interferometer as a frequency clock module, or software, e.g., interpolation in k-space, to obtain equally spaced samples that are suitable for the FFT. To overcome the problem of nonuniform sampling in k-space without any need for interferogram oversampling, an earlier method demonstrated the use of the nonuniform discrete Fourier transform (NDFT) for image reconstruction in SS-OCT. In this paper, we present a more accurate method for SS-OCT image reconstruction from nonuniform samples in k-space using a scaled nonuniform Fourier transform. The result is demonstrated using SS-OCT images of Axolotl salamander eggs.

Spatially-Heterodyned Holography

DOEpatents

Thomas, Clarence E [Knoxville, TN; Hanson, Gregory R [Clinton, TN

2006-02-21

A method of recording a spatially low-frequency heterodyne hologram, including spatially heterodyne fringes for Fourier analysis, includes: splitting a laser beam into a reference beam and an object beam; interacting the object beam with an object; focusing the reference beam and the object beam at a focal plane of a digital recorder to form a spatially low-frequency heterodyne hologram including spatially heterodyne fringes for Fourier analysis; digital recording the spatially low-frequency heterodyne hologram; Fourier transforming axes of the recorded spatially low-frequency heterodyne hologram including spatially heterodyne fringes in Fourier space to sit on top of a heterodyne carrier frequency defined by an angle between the reference beam and the object beam; cutting off signals around an origin; and performing an inverse Fourier transform.

Feature Extraction for Bearing Prognostics and Health Management (PHM) - A Survey (Preprint)

DTIC Science & Technology

2008-05-01

Envelope analysis • Cepstrum analysis • Higher order spectrum • Short-time Fourier Transform (STFT) • Wigner - Ville distribution ( WVD ) • Empirical mode...techniques are the short-time Fourier transform (STFT), the Wigner - Ville distribution , and the wavelet transform. In this paper we categorize wavelets...diagnosis have shown in many publications, for example, [22]. b) Wigner – Ville distribution : The afore-mentioned STFT is conceptually simple. However

Limitations and potential of spectral subtractions in fourier-transform infrared (FTIR) spectroscopy of soil samples

USDA-ARS?s Scientific Manuscript database

Soil science research is increasingly applying Fourier transform infrared (FTIR) spectroscopy for analysis of soil organic matter (SOM). However, the compositional complexity of soils and the dominance of the mineral component can limit spectroscopic resolution of SOM and other minor components. The...

Detection of starch adulteration in onion powder by FT-NIR and FT-IR spectroscopy

USDA-ARS?s Scientific Manuscript database

Adulteration of onion powder with cornstarch was identified by Fourier transform near-infrared (FT-NIR) and Fourier transform infrared (FT-IR) spectroscopy. The reflectance spectra of 180 pure and adulterated samples (1–35 wt% starch) were collected and preprocessed to generate calibration and predi...

Coordinate axes, location of origin, and redundancy for the one and two-dimensional discrete Fourier transform

NASA Technical Reports Server (NTRS)

Ioup, G. E.; Ioup, J. W.

1985-01-01

Appendix 4 of the Study of One- and Two-Dimensional Filtering and Deconvolution Algorithms for a Streaming Array Computer discusses coordinate axes, location of origin, and redundancy for the one- and two-dimensional Fourier transform for complex and real data.

3D spectral imaging with synchrotron Fourier transform infrared spectro-microtomography

Treesearch

Michael C. Martin; Charlotte Dabat-Blondeau; Miriam Unger; Julia Sedlmair; Dilworth Y. Parkinson; Hans A. Bechtel; Barbara Illman; Jonathan M. Castro; Marco Keiluweit; David Buschke; Brenda Ogle; Michael J. Nasse; Carol J. Hirschmugl

2013-01-01

We report Fourier transform infrared spectro-microtomography, a nondestructive three-dimensional imaging approach that reveals the distribution of distinctive chemical compositions throughout an intact biological or materials sample. The method combines mid-infrared absorption contrast with computed tomographic data acquisition and reconstruction to enhance chemical...

Chemometric Analysis of Multicomponent Biodegradable Plastics by Fourier Transform Infrared Spectrometry: The R-Matrix Method

USDA-ARS?s Scientific Manuscript database

A new chemometric method based on absorbance ratios from Fourier transform infrared spectra was devised to analyze multicomponent biodegradable plastics. The method uses the BeerLambert law to directly compute individual component concentrations and weight losses before and after biodegradation of c...

Applications of Fourier transform infrared spectroscopy to quality control of the epoxy matrix

NASA Technical Reports Server (NTRS)

Antoon, M. K.; Starkey, K. M.; Koenig, J. L.

1979-01-01

The object of the paper is to demonstrate the utility of Fourier transform infrared (FT-IR) difference spectra for investigating the composition of a neat epoxy resin, hardener, and catalysts. The composition and degree of cross-linking of the cured matrix is also considered.

The Kinetics of Mo(Co)6 Substitution Monitored by Fourier Transform Infrared Spectrophotometry.

ERIC Educational Resources Information Center

Suslick, Kenneth S.; And Others

1987-01-01

Describes a physical chemistry experiment that uses Fourier transform (FTIR) spectrometers and microcomputers as a way of introducing students to the spectral storage and manipulation techniques associated with digitized data. It can be used to illustrate FTIR spectroscopy, simple kinetics, inorganic mechanisms, and Beer's Law. (TW)

A statistical evaluation of spectral fingerprinting methods using analysis of variance and principal component analysis

USDA-ARS?s Scientific Manuscript database

Six methods were compared with respect to spectral fingerprinting of a well-characterized series of broccoli samples. Spectral fingerprints were acquired for finely-powdered solid samples using Fourier transform-infrared (IR) and Fourier transform-near infrared (NIR) spectrometry and for aqueous met...

Machine Learning-Aided, Robust Wideband Spectrum Sensing for Cognitive Radios

DTIC Science & Technology

2015-06-12

to even Approved for public release; distribution is unlimited. 2 on the order of a giga -Hertz (GHz). Due to wide bandwidth and noncontiguous...Frequency Band CS Compressive Sampling DFT Discrete Fourier Transform EMI Electro Magnetic Interference FFT Fast Fourier Transform GHz Giga Hertz Hz Hertz

Effect of oxygen plasma on field emission characteristics of single-wall carbon nanotubes grown by plasma enhanced chemical vapour deposition system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, Avshish; Parveen, Shama; Husain, Samina

2014-02-28

Field emission properties of single wall carbon nanotubes (SWCNTs) grown on iron catalyst film by plasma enhanced chemical vapour deposition system were studied in diode configuration. The results were analysed in the framework of Fowler-Nordheim theory. The grown SWCNTs were found to be excellent field emitters, having emission current density higher than 20 mA/cm{sup 2} at a turn-on field of 1.3 V/μm. The as grown SWCNTs were further treated with Oxygen (O{sub 2}) plasma for 5 min and again field emission characteristics were measured. The O{sub 2} plasma treated SWCNTs have shown dramatic improvement in their field emission properties with emission current densitymore » of 111 mA/cm{sup 2} at a much lower turn on field of 0.8 V/μm. The as grown as well as plasma treated SWCNTs were also characterized by various techniques, such as scanning electron microscopy, high resolution transmission electron microscopy, Raman spectroscopy, and Fourier transform infrared spectroscopy before and after O{sub 2} plasma treatment and the findings are being reported in this paper.« less

Fourier Deconvolution Methods for Resolution Enhancement in Continuous-Wave EPR Spectroscopy.

PubMed

Reed, George H; Poyner, Russell R

2015-01-01

An overview of resolution enhancement of conventional, field-swept, continuous-wave electron paramagnetic resonance spectra using Fourier transform-based deconvolution methods is presented. Basic steps that are involved in resolution enhancement of calculated spectra using an implementation based on complex discrete Fourier transform algorithms are illustrated. Advantages and limitations of the method are discussed. An application to an experimentally obtained spectrum is provided to illustrate the power of the method for resolving overlapped transitions. © 2015 Elsevier Inc. All rights reserved.

Products of multiple Fourier series with application to the multiblade transformation

NASA Technical Reports Server (NTRS)

Kunz, D. L.

1981-01-01

A relatively simple and systematic method for forming the products of multiple Fourier series using tensor like operations is demonstrated. This symbolic multiplication can be performed for any arbitrary number of series, and the coefficients of a set of linear differential equations with periodic coefficients from a rotating coordinate system to a nonrotating system is also demonstrated. It is shown that using Fourier operations to perform this transformation make it easily understood, simple to apply, and generally applicable.

Diffraction Theory and Almost Periodic Distributions

NASA Astrophysics Data System (ADS)

Strungaru, Nicolae; Terauds, Venta

2016-09-01

We introduce and study the notions of translation bounded tempered distributions, and autocorrelation for a tempered distribution. We further introduce the spaces of weakly, strongly and null weakly almost periodic tempered distributions and show that for weakly almost periodic tempered distributions the Eberlein decomposition holds. For translation bounded measures all these notions coincide with the classical ones. We show that tempered distributions with measure Fourier transform are weakly almost periodic and that for this class, the Eberlein decomposition is exactly the Fourier dual of the Lebesgue decomposition, with the Fourier-Bohr coefficients specifying the pure point part of the Fourier transform. We complete the project by looking at few interesting examples.

Improving the accuracy and efficiency of time-resolved electronic spectra calculations: cellular dephasing representation with a prefactor.

PubMed

Zambrano, Eduardo; Šulc, Miroslav; Vaníček, Jiří

2013-08-07

Time-resolved electronic spectra can be obtained as the Fourier transform of a special type of time correlation function known as fidelity amplitude, which, in turn, can be evaluated approximately and efficiently with the dephasing representation. Here we improve both the accuracy of this approximation-with an amplitude correction derived from the phase-space propagator-and its efficiency-with an improved cellular scheme employing inverse Weierstrass transform and optimal scaling of the cell size. We demonstrate the advantages of the new methodology by computing dispersed time-resolved stimulated emission spectra in the harmonic potential, pyrazine, and the NCO molecule. In contrast, we show that in strongly chaotic systems such as the quartic oscillator the original dephasing representation is more appropriate than either the cellular or prefactor-corrected methods.

MRS3D: 3D Spherical Wavelet Transform on the Sphere

NASA Astrophysics Data System (ADS)

Lanusse, F.; Rassat, A.; Starck, J.-L.

2011-12-01

Future cosmological surveys will provide 3D large scale structure maps with large sky coverage, for which a 3D Spherical Fourier-Bessel (SFB) analysis is natural. Wavelets are particularly well-suited to the analysis and denoising of cosmological data, but a spherical 3D isotropic wavelet transform does not currently exist to analyse spherical 3D data. We present a new fast Discrete Spherical Fourier-Bessel Transform (DSFBT) based on both a discrete Bessel Transform and the HEALPIX angular pixelisation scheme. We tested the 3D wavelet transform and as a toy-application, applied a denoising algorithm in wavelet space to the Virgo large box cosmological simulations and found we can successfully remove noise without much loss to the large scale structure. The new spherical 3D isotropic wavelet transform, called MRS3D, is ideally suited to analysing and denoising future 3D spherical cosmological surveys; it uses a novel discrete spherical Fourier-Bessel Transform. MRS3D is based on two packages, IDL and Healpix and can be used only if these two packages have been installed.

Wavelet based detection of manatee vocalizations

NASA Astrophysics Data System (ADS)

Gur, Berke M.; Niezrecki, Christopher

2005-04-01

The West Indian manatee (Trichechus manatus latirostris) has become endangered partly because of watercraft collisions in Florida's coastal waterways. Several boater warning systems, based upon manatee vocalizations, have been proposed to reduce the number of collisions. Three detection methods based on the Fourier transform (threshold, harmonic content and autocorrelation methods) were previously suggested and tested. In the last decade, the wavelet transform has emerged as an alternative to the Fourier transform and has been successfully applied in various fields of science and engineering including the acoustic detection of dolphin vocalizations. As of yet, no prior research has been conducted in analyzing manatee vocalizations using the wavelet transform. Within this study, the wavelet transform is used as an alternative to the Fourier transform in detecting manatee vocalizations. The wavelet coefficients are analyzed and tested against a specified criterion to determine the existence of a manatee call. The performance of the method presented is tested on the same data previously used in the prior studies, and the results are compared. Preliminary results indicate that using the wavelet transform as a signal processing technique to detect manatee vocalizations shows great promise.

The Use of Continuous Wavelet Transform Based on the Fast Fourier Transform in the Analysis of Multi-channel Electrogastrography Recordings.

PubMed

Komorowski, Dariusz; Pietraszek, Stanislaw

2016-01-01

This paper presents the analysis of multi-channel electrogastrographic (EGG) signals using the continuous wavelet transform based on the fast Fourier transform (CWTFT). The EGG analysis was based on the determination of the several signal parameters such as dominant frequency (DF), dominant power (DP) and index of normogastria (NI). The use of continuous wavelet transform (CWT) allows for better visible localization of the frequency components in the analyzed signals, than commonly used short-time Fourier transform (STFT). Such an analysis is possible by means of a variable width window, which corresponds to the scale time of observation (analysis). Wavelet analysis allows using long time windows when we need more precise low-frequency information, and shorter when we need high frequency information. Since the classic CWT transform requires considerable computing power and time, especially while applying it to the analysis of long signals, the authors used the CWT analysis based on the fast Fourier transform (FFT). The CWT was obtained using properties of the circular convolution to improve the speed of calculation. This method allows to obtain results for relatively long records of EGG in a fairly short time, much faster than using the classical methods based on running spectrum analysis (RSA). In this study authors indicate the possibility of a parametric analysis of EGG signals using continuous wavelet transform which is the completely new solution. The results obtained with the described method are shown in the example of an analysis of four-channel EGG recordings, performed for a non-caloric meal.

Investigations on silver/polyaniline electrodes for electrochemical supercapacitors.

PubMed

Patil, Dipali S; Shaikh, J S; Pawar, S A; Devan, R S; Ma, Y R; Moholkar, A V; Kim, J H; Kalubarme, R S; Park, C J; Patil, P S

2012-09-14

Polyaniline (PANI) and silver doped polyaniline (Ag/PANI) thin films were deposited on stainless steel substrates by a dip coating technique. To study the effect of doping concentration of Ag on the specific capacitance of PANI the concentration of Ag was varied from 0.3 to 1.2 weight percent. Fourier transform-infrared and Fourier transform-Raman spectroscopy, and energy dispersion X-ray techniques were used for the phase identification and determination of the doping content in the PANI films, respectively. The surface morphology of the films was examined by Field Emission Scanning Electron Microscopy, which revealed a nanofiber like structure for PANI and nanofibers with bright spots of Ag particles for the Ag/PANI films. There was decrease in the room temperature electrical resistivity of the Ag/PANI films of the order of 10(2) with increasing Ag concentration. The supercapacitive behavior of the electrodes was tested in a three electrode system using 1.0 M H(2)SO(4) electrolyte. The specific capacitance increased from 285 F g(-1) (for PANI) to 512 F g(-1) for Ag/PANI at 0.9 weight percent doping of Ag, owing to the synergic effect of PANI and silver nanoparticles. This work demonstrates a simple strategy of improving the specific capacitance of polymer electrodes and may also be easily adopted for other dopants.

Internal energy of HCl upon photolysis of 2-chloropropene at 193 nm investigated with time-resolved Fourier-transform spectroscopy and quasiclassical trajectories

NASA Astrophysics Data System (ADS)

Chang, Chih-Min; Huang, Yu-Hsuan; Liu, Suet-Yi; Lee, Yuan-Pern; Pombar-Pérez, Marta; Martínez-Núñez, Emilio; Vázquez, Saulo A.

2008-12-01

Following photodissociation of 2-chloropropene (H2CCClCH3) at 193 nm, vibration-rotationally resolved emission spectra of HCl (υ ≤6) in the spectral region of 1900-2900 cm-1 were recorded with a step-scan time-resolved Fourier-transform spectrometer. All vibrational levels show a small low-J component corresponding to ˜400 K and a major high-J component corresponding to 7100-18 700 K with average rotational energy of 39±311 kJ mol-1. The vibrational population of HCl is inverted at υ =2, and the average vibrational energy is 86±5 kJ mol-1. Two possible channels of molecular elimination producing HCl+propyne or HCl+allene cannot be distinguished positively based on the observed internal energy distribution of HCl. The observed rotational distributions fit qualitatively with the distributions of both channels obtained with quasiclassical trajectories (QCTs), but the QCT calculations predict negligible populations for states at small J. The observed vibrational distribution agrees satisfactorily with the total QCT distribution obtained as a weighted sum of contributions from both four-center elimination channels. Internal energy distributions of HCl from 2-chloropropene and vinyl chloride are compared.

Ferroxidase activity of apoferritin is increased in the presence of platinum nanoparticles.

PubMed

Sennuga, Afolake; van Marwijk, Jacqueline; Whiteley, Chris G

2012-01-27

The ferroxidase activity of horse spleen apoferritin (HSAF) is increased by nine-fold in the presence of platinum nanoparticles. HSAF was mixed with varying concentrations of K2PtCl4 followed by a 20-fold concentration of sodium borohydride to afford Pt:HSAF nanoparticle complexes in a ratio of between 1:250 and 1:4000. Typical colour changes, from colourless or pale yellow to brown, occurred that were dependent on the amount of platinum present. These complexes were characterized by UV/vis, inductively coupled plasma optical emission spectroscopy, Fourier transform infrared, transmission electron microscopy and energy dispersive x-ray spectroscopy. Transmission electron microscopy analysis revealed that the size of nanoparticles increased as the molar ratio of platinum to HSAF increased with an average size diameter of 2-6 nm generated with HSAF:platinum molar ratios of 1:250-1:4000. Fourier transform infrared spectroscopy (FTIR) spectra showed no distinct changes in the structure of HSAF but confirmed that the nanoparticles were attached to the protein. The effect of platinum nanoparticles on the ferroxidase activity of HSAF showed a specific activity of 360 ρmol min(-1) mg(-1), (nine-fold increase over the control) at the molar ratio of HSAF:platinum nanoparticles of 1:1000.

Improving Spectral Results Using Row-by-Row Fourier Transform of Spatial Heterodyne Raman Spectrometer Interferogram.

PubMed

Barnett, Patrick D; Strange, K Alicia; Angel, S Michael

2017-06-01

This work describes a method of applying the Fourier transform to the two-dimensional Fizeau fringe patterns generated by the spatial heterodyne Raman spectrometer (SHRS), a dispersive interferometer, to correct the effects of certain types of optical alignment errors. In the SHRS, certain types of optical misalignments result in wavelength-dependent and wavelength-independent rotations of the fringe pattern on the detector. We describe here a simple correction technique that can be used in post-processing, by applying the Fourier transform in a row-by-row manner. This allows the user to be more forgiving of fringe alignment and allows for a reduction in the mechanical complexity of the SHRS.

The investigation of the bio-oil produced by hydrothermal liquefaction of Spirulina platensis using ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry.

PubMed

Kostyukevich, Yury; Vlaskin, Mikhail; Vladimirov, Gleb; Zherebker, Alexander; Kononikhin, Alexey; Popov, Igor; Nikolaev, Eugene

2017-04-01

We report the investigation of the hydrothermal liquefaction products of the Spirulina platensis microalgae by using the Fourier transform ion cyclotron resonance mass spectrometry. The hydrothermal liquefaction produced two fractions: one with boiling temperature below 300℃ and the dense residue that remained in the reactor. It was observed that N 2 and N classes of compounds that dominate in the positive ESI Fourier transform ion cyclotron resonance spectra for both fractions, and that the light fraction is considerably more saturated then the heavy one. The performed hydrogen/deuterium exchange reaction indicated the presence of the onium compounds in the bio-oil.

The application of digital signal processing techniques to a teleoperator radar system

NASA Technical Reports Server (NTRS)

Pujol, A.

1982-01-01

A digital signal processing system was studied for the determination of the spectral frequency distribution of echo signals from a teleoperator radar system. The system consisted of a sample and hold circuit, an analog to digital converter, a digital filter, and a Fast Fourier Transform. The system is interfaced to a 16 bit microprocessor. The microprocessor is programmed to control the complete digital signal processing. The digital filtering and Fast Fourier Transform functions are implemented by a S2815 digital filter/utility peripheral chip and a S2814A Fast Fourier Transform chip. The S2815 initially simulates a low-pass Butterworth filter with later expansion to complete filter circuit (bandpass and highpass) synthesizing.

Color image cryptosystem using Fresnel diffraction and phase modulation in an expanded fractional Fourier transform domain

NASA Astrophysics Data System (ADS)

Chen, Hang; Liu, Zhengjun; Chen, Qi; Blondel, Walter; Varis, Pierre

2018-05-01

In this letter, what we believe is a new technique for optical color image encryption by using Fresnel diffraction and a phase modulation in an extended fractional Fourier transform domain is proposed. Different from the RGB component separation based method, the color image is converted into one component by improved Chirikov mapping. The encryption system is addressed with Fresnel diffraction and phase modulation. A pair of lenses is placed into the fractional Fourier transform system for the modulation of beam propagation. The structure parameters of the optical system and parameters in Chirikov mapping serve as extra keys. Some numerical simulations are given to test the validity of the proposed cryptosystem.

Application of band-target entropy minimization to infrared emission spectroscopy and the reconstruction of pure component emissivities from thin films and liquid samples.

PubMed

Cheng, Shuying; Rajarathnam, D; Meiling, Tan; Garland, Marc

2006-05-01

Thermal emission spectral data sets were collected for a thin solid film (parafilm) and a thin liquid film (isopropanol) on the interval of 298-348 K. The measurements were performed using a conventional Fourier transform infrared (FT-IR) spectrometer with external optical bench and in-house-designed emission cell. Both DTGS and MCT detectors were used. The data sets were analyzed with band-target entropy minimization (BTEM), which is a pure component spectral reconstruction program. Pure component emissivities of the parafilm, isopropanol, and thermal background were all recovered without any a priori information. Furthermore, the emissivities were obtained with increased signal-to-noise ratios, and the signals due to absorbance of thermal radiation by gas-phase moisture and CO2 were significantly reduced. As expected, the MCT results displayed better signal-to-noise ratios than the DTGS results, but the latter results were still rather impressive given the low temperatures used in this study. Comparison is made with spectral reconstruction using the orthogonal projection approach-alternating least squares (OPA-ALS) technique. This contribution introduces the primary equation for emission spectral reconstruction using BTEM and discusses some of the unusual characteristics of thermal emission and their impact on the analysis.

Direct Quantification of Methane Emissions Across the Supply Chain: Identification of Mitigation Targets

NASA Astrophysics Data System (ADS)

Darzi, M.; Johnson, D.; Heltzel, R.; Clark, N.

2017-12-01

Researchers at West Virginia University's Center for Alternative Fuels, Engines, and Emissions have recently participated in a variety of studies targeted at direction quantification of methane emissions from across the natural gas supply chain. These studies included assessing methane emissions from heavy-duty vehicles and their fuel stations, active unconventional well sites - during both development and production, natural gas compression and storage facilities, natural gas engines - both large and small, two- and four-stroke, and low-throughput equipment associated with coal bed methane wells. Engine emissions were sampled using conventional instruments such as Fourier transform infrared spectrometers and heated flame ionization detection analyzers. However, to accurately quantify a wide range of other sources beyond the tailpipe (both leaks and losses), a full flow sampling system was developed, which included an integrated cavity-enhanced absorption spectrometer. Through these direct quantification efforts and analysis major sources of methane emissions were identified. Technological solutions and best practices exist or could be developed to reduce methane emissions by focusing on the "lowest-hanging fruit." For example, engine crankcases from across the supply chain should employ vent mitigation systems to reduce methane and other emissions. An overview of the direct quantification system and various campaign measurements results will be presented along with the identification of other targets for additional mitigation.

Metasurface Enabled Wide-Angle Fourier Lens.

PubMed

Liu, Wenwei; Li, Zhancheng; Cheng, Hua; Tang, Chengchun; Li, Junjie; Zhang, Shuang; Chen, Shuqi; Tian, Jianguo

2018-06-01

Fourier optics, the principle of using Fourier transformation to understand the functionalities of optical elements, lies at the heart of modern optics, and it has been widely applied to optical information processing, imaging, holography, etc. While a simple thin lens is capable of resolving Fourier components of an arbitrary optical wavefront, its operation is limited to near normal light incidence, i.e., the paraxial approximation, which puts a severe constraint on the resolvable Fourier domain. As a result, high-order Fourier components are lost, resulting in extinction of high-resolution information of an image. Other high numerical aperture Fourier lenses usually suffer from the bulky size and costly designs. Here, a dielectric metasurface consisting of high-aspect-ratio silicon waveguide array is demonstrated experimentally, which is capable of performing 1D Fourier transform for a large incident angle range and a broad operating bandwidth. Thus, the device significantly expands the operational Fourier space, benefitting from the large numerical aperture and negligible angular dispersion at large incident angles. The Fourier metasurface will not only facilitate efficient manipulation of spatial spectrum of free-space optical wavefront, but also be readily integrated into micro-optical platforms due to its compact size. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Ultra-Wideband Radar Transient Detection using Time-Frequency and Wavelet Transforms.

DTIC Science & Technology

1992-12-01

if p==2, mesh(flipud(abs(spdatamatrix).A2)) end 2. Wigner - Ville Distribution function P = wvd (data,winlenstep,begintheendp) % Filename: wvd.m % Title...short time Fourier transform (STFT), the Instantaneous Power Spectrum and the Wigner - Ville distribution , and time-scale methods, such as the a trous...such as the short time Fourier transform (STFT), the Instantaneous Power Spectrum and the Wigner - Ville distribution [1], and time-scale methods, such

SAR image formation with azimuth interpolation after azimuth transform

DOEpatents

Doerry,; Armin W. , Martin; Grant D. , Holzrichter; Michael, W [Albuquerque, NM

2008-07-08

Two-dimensional SAR data can be processed into a rectangular grid format by subjecting the SAR data to a Fourier transform operation, and thereafter to a corresponding interpolation operation. Because the interpolation operation follows the Fourier transform operation, the interpolation operation can be simplified, and the effect of interpolation errors can be diminished. This provides for the possibility of both reducing the re-grid processing time, and improving the image quality.

Delineation of First-Order Elastic Property Closures for Hexagonal Metals Using Fast Fourier Transforms

PubMed Central

Landry, Nicholas W.; Knezevic, Marko

2015-01-01

Property closures are envelopes representing the complete set of theoretically feasible macroscopic property combinations for a given material system. In this paper, we present a computational procedure based on fast Fourier transforms (FFTs) for delineation of elastic property closures for hexagonal close packed (HCP) metals. The procedure consists of building a database of non-zero Fourier transforms for each component of the elastic stiffness tensor, calculating the Fourier transforms of orientation distribution functions (ODFs), and calculating the ODF-to-elastic property bounds in the Fourier space. In earlier studies, HCP closures were computed using the generalized spherical harmonics (GSH) representation and an assumption of orthotropic sample symmetry; here, the FFT approach allowed us to successfully calculate the closures for a range of HCP metals without invoking any sample symmetry assumption. The methodology presented here facilitates for the first time computation of property closures involving normal-shear coupling stiffness coefficients. We found that the representation of these property linkages using FFTs need more terms compared to GSH representations. However, the use of FFT representations reduces the computational time involved in producing the property closures due to the use of fast FFT algorithms. Moreover, FFT algorithms are readily available as opposed to GSH codes. PMID:28793566

Accurate determination of the diffusion coefficient of proteins by Fourier analysis with whole column imaging detection.

PubMed

Zarabadi, Atefeh S; Pawliszyn, Janusz

2015-02-17

Analysis in the frequency domain is considered a powerful tool to elicit precise information from spectroscopic signals. In this study, the Fourier transformation technique is employed to determine the diffusion coefficient (D) of a number of proteins in the frequency domain. Analytical approaches are investigated for determination of D from both experimental and data treatment viewpoints. The diffusion process is modeled to calculate diffusion coefficients based on the Fourier transformation solution to Fick's law equation, and its results are compared to time domain results. The simulations characterize optimum spatial and temporal conditions and demonstrate the noise tolerance of the method. The proposed model is validated by its application for the electropherograms from the diffusion path of a set of proteins. Real-time dynamic scanning is conducted to monitor dispersion by employing whole column imaging detection technology in combination with capillary isoelectric focusing (CIEF) and the imaging plug flow (iPF) experiment. These experimental techniques provide different peak shapes, which are utilized to demonstrate the Fourier transformation ability in extracting diffusion coefficients out of irregular shape signals. Experimental results confirmed that the Fourier transformation procedure substantially enhanced the accuracy of the determined values compared to those obtained in the time domain.

Effect of pressure-assisted thermal annealing on the optical properties of ZnO thin films.

PubMed

Berger, Danielle; Kubaski, Evaldo Toniolo; Sequinel, Thiago; da Silva, Renata Martins; Tebcherani, Sergio Mazurek; Varela, José Arana

2013-01-01

ZnO thin films were prepared by the polymeric precursor method. The films were deposited on silicon substrates using the spin-coating technique, and were annealed at 330 °C for 32 h under pressure-assisted thermal annealing and under ambient pressure. Their structural and optical properties were characterized, and the phases formed were identified by X-ray diffraction. No secondary phase was detected. The ZnO thin films were also characterized by field-emission scanning electron microscopy, Fourier transform infrared spectroscopy, photoluminescence and ultraviolet emission intensity measurements. The effect of pressure on these thin films modifies the active defects that cause the recombination of deep level states located inside the band gap that emit yellow-green (575 nm) and orange (645 nm) photoluminescence. Copyright © 2012 John Wiley & Sons, Ltd.

One-step fabrication of BaMoO4 microstructures with controlled morphologies via a simple EDTA-mediated route

NASA Astrophysics Data System (ADS)

Yin, Yongkui; Li, Ying; Zhang, Haifeng; Ren, Fengyun; Zhang, Dawei; Feng, Wenxu; Shao, Lili; Li, Kaijun; Liu, Yang; Sun, Zhanpeng; Li, Miaojing; Song, Gaochen; Wang, Guan

2013-03-01

A facile strategy has been developed to synthesize BaMoO4 microcrystals with different morphologies, such as octopus-like, flower-like, and Chinese-cabbage-like, by using ethylenediaminetetraacetic acid as chelating and capping reagent at room temperature. X-ray diffraction, field emission scanning electron microscopy, and Fourier transformer infrared spectroscopy were introduced to characterize the composition, morphology, and chemical information of the as-obtained products. The effects of a series of experimental parameters, such as ethylenediaminetetraacetic acid quantity and the reagent concentrations, on the morphology and photoluminescence properties of the consequential BaMoO4 microcrystals were investigated in detail. The photoluminescence spectra of the obtained BaMoO4 microstructures exhibited different emission intensities. This method could be readily extended to synthesize BaWO4 microstructures with various morphologies.

A simple and facile synthesis of MPA capped CdSe and CdSe/CdS core/shell nanoparticles

NASA Astrophysics Data System (ADS)

Sukanya, D.; Sagayaraj, P.

2015-06-01

II-VI semiconductor nanostructures, in particular, CdSe quantum dots have drawn a lot of attention because of their promising potential applications in biological tagging, photovoltaic, display devices etc. due to their excellent optical properties, high emission quantum yield, size dependent emission wavelength and high photostability. In this paper, we describe the synthesis and properties of mercaptopropionic acid capped CdSe and CdSe/CdS nanoparticles through a simple and efficient co-precipitation method followed by hydrothermal treatment. The growth process, characterization and the optical absorption as a function of wavelength for the synthesized MPA capped CdSe and CdSe/CdS nanoparticles have been determined using X-ray diffraction study (XRD), Ultraviolet-Visible spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FT-IR) and High Resolution Transmission Electron Microscopy (HRTEM).

Emission FTIR analyses of thin microscopic patches of jet fuel residues deposited on heated metal surfaces

NASA Technical Reports Server (NTRS)

Lauer, J. L.; Vogel, P.

1986-01-01

The relationship of fuel stability to fuel composition and the development of mechanisms for deposit formation were investigated. Fuel deposits reduce heat transfer efficiency and increase resistance to fuel flow and are highly detrimental to aircraft performance. Infrared emission Fourier transform spectroscopy was chosen as the primary method of analysis because it was sensitive enough to be used in-situ on tiny patches of monolayers or of only a few molecular layers of deposits which generally proved completely insoluble in any nondestructive solvents. Deposits of four base fuels were compared; dodecane, a dodecane/tetralin blend, commercial Jet A fuel, and a broadened-properties jet fuel particularly rich in polynuclear aromatics. Every fuel in turn was provided with and without small additions of such additives as thiophene, furan, pyrrole, and copper and iron naphthenates.

Optimization and analysis of NF3 in situ chamber cleaning plasmas

NASA Astrophysics Data System (ADS)

Ji, Bing; Yang, James H.; Badowski, Peter R.; Karwacki, Eugene J.

2004-04-01

We report on the optimization and analysis of a dilute NF3 in situ plasma-enhanced chemical vapor deposition chamber cleaning plasma for an Applied Materials P-5000 DxL chamber. Using design of experiments methodology, we identified and optimized operating conditions within the following process space: 10-15 mol % NF3 diluted with helium, 200-400 sccm NF3 flow rate, 2.5-3.5 Torr chamber pressure, and 950 W rf power. Optical emission spectroscopy and Fourier transform infrared spectroscopy were used to endpoint the cleaning processes and to quantify plasma effluent emissions, respectively. The results demonstrate that dilute NF3-based in situ chamber cleaning can be a viable alternative to perfluorocarbon-based in situ cleans with added benefits. The relationship between chamber clean time and fluorine atom density in the plasma is also investigated.

Synthesis, Characterization and Comparative Luminescence Studies of Rare-Earth-Doped Gd2O3 Nanoparticles

NASA Astrophysics Data System (ADS)

Pyngrope, D.; Singh, L. R.; Prasad, A. I.; Bora, A.

2018-04-01

A facile direct precipitation method was used for the synthesis of luminescence nanomaterial. Gd2O3 doped with rare earth element Eu3+ is synthesized by polyol route. The synthesized nanoparticles show their characteristic red emission. The nanoparticles are characterized by x-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM) and photoluminescence (PL) study. The synthesized nanoparticles are spherical particles with 30 nm size. The photoluminescence studies show the characteristic Eu3+ red emission. The PL study shows the intensity of the magnetic dipole transition ( 5 D0 \\to 7 F1 ) at 592 nm compared to that of the electronic dipole transition ( 5 D0 \\to 7 F2 ) at 615 nm. The nanomaterials can show significant application in various display devices and biomedical applications for tracking.

Interactions and Supramolecular Organization of Sulfonated Indigo and Thioindigo Dyes in Layered Hydroxide Hosts.

PubMed

Costa, Ana L; Gomes, Ana C; Pereira, Ricardo C; Pillinger, Martyn; Gonçalves, Isabel S; Pineiro, Marta; Seixas de Melo, J Sérgio

2018-01-09

Supramolecularly organized host-guest systems have been synthesized by intercalating water-soluble forms of indigo (indigo carmine, IC) and thioindigo (thioindigo-5,5'-disulfonate, TIS) in zinc-aluminum-layered double hydroxides (LDHs) and zinc-layered hydroxide salts (LHSs) by coprecipitation routes. The colors of the isolated powders were dark blue for hybrids containing only IC, purplish blue or dark lilac for cointercalated samples containing both dyes, and ruby/wine for hybrids containing only TIS. The as-synthesized and thermally treated materials were characterized by Fourier transform infrared, Fourier transform Raman, and nuclear magnetic resonance spectroscopies, powder X-ray diffraction, scanning electron microscopy, and elemental and thermogravimetric analyses. The basal spacings found for IC-LDH, TIS-LDH, IC-LHS, and TIS-LHS materials were 21.9, 21.05, 18.95, and 21.00 Å, respectively, with intermediate spacings being observed for the cointercalated samples that either decreased (LDHs) or increased (LHSs) with increasing TIS content. UV-visible and fluorescence spectroscopies (steady-state and time-resolved) were used to probe the molecular distribution of the immobilized dyes. The presence of aggregates together with the monomer units is suggested for IC-LDH, whereas for TIS-LDH, IC-LHS, and TIS-LHS, the dyes are closer to the isolated situation. Accordingly, while emission from the powder H 2 TIS is strongly quenched, an increment in the emission of about 1 order of magnitude was observed for the TIS-LDH/LHS hybrids. Double-exponential fluorescence decays were obtained and associated with two monomer species interacting differently with cointercalated water molecules. The incorporation of both TIS and IC in the LDH and LHS hosts leads to an almost complete quenching of the fluorescence, pointing to a very efficient energy transfer process from (fluorescent) TIS to (nonfluorescent) IC.

Optical joint transform correlation on the DMD. [deformable mirror device

NASA Technical Reports Server (NTRS)

Knopp, Jerome; Juday, Richard D.

1989-01-01

Initial experimental investigation of the deformable mirror device (DMD) in a joint optical transform correlation is reported. The inverted cloverleaf version of the DMD, in which form the DMD is phase-mostly but of limited phase range, is used. Binarized joint Fourier transforms were calculated for similar and dissimilar objects and written onto the DMD. Inverse Fourier transform was done in a diffraction order for which the DMD shows phase-mostly modulation. Matched test objects produced sharp correlation, distinct objects did not. Further studies are warranted and they are outlined.

Innovative design method of automobile profile based on Fourier descriptor

NASA Astrophysics Data System (ADS)

Gao, Shuyong; Fu, Chaoxing; Xia, Fan; Shen, Wei

2017-10-01

Aiming at the innovation of the contours of automobile side, this paper presents an innovative design method of vehicle side profile based on Fourier descriptor. The design flow of this design method is: pre-processing, coordinate extraction, standardization, discrete Fourier transform, simplified Fourier descriptor, exchange descriptor innovation, inverse Fourier transform to get the outline of innovative design. Innovative concepts of the innovative methods of gene exchange among species and the innovative methods of gene exchange among different species are presented, and the contours of the innovative design are obtained separately. A three-dimensional model of a car is obtained by referring to the profile curve which is obtained by exchanging xenogeneic genes. The feasibility of the method proposed in this paper is verified by various aspects.

Fourier transform wavefront control with adaptive prediction of the atmosphere.

PubMed

Poyneer, Lisa A; Macintosh, Bruce A; Véran, Jean-Pierre

2007-09-01

Predictive Fourier control is a temporal power spectral density-based adaptive method for adaptive optics that predicts the atmosphere under the assumption of frozen flow. The predictive controller is based on Kalman filtering and a Fourier decomposition of atmospheric turbulence using the Fourier transform reconstructor. It provides a stable way to compensate for arbitrary numbers of atmospheric layers. For each Fourier mode, efficient and accurate algorithms estimate the necessary atmospheric parameters from closed-loop telemetry and determine the predictive filter, adjusting as conditions change. This prediction improves atmospheric rejection, leading to significant improvements in system performance. For a 48x48 actuator system operating at 2 kHz, five-layer prediction for all modes is achievable in under 2x10(9) floating-point operations/s.

Turbulence excited frequency domain damping measurement and truncation effects

NASA Technical Reports Server (NTRS)

Soovere, J.

1976-01-01

Existing frequency domain modal frequency and damping analysis methods are discussed. The effects of truncation in the Laplace and Fourier transform data analysis methods are described. Methods for eliminating truncation errors from measured damping are presented. Implications of truncation effects in fast Fourier transform analysis are discussed. Limited comparison with test data is presented.

Comparison and validation of Fourier transform infrared spectroscopic methods for monitoring secondary cell wall cellulose from cotton fibers

USDA-ARS?s Scientific Manuscript database

The amount of secondary cell wall (SCW) cellulose in the fiber affects the quality and commercial value of cotton. Accurate assessments of SCW cellulose are essential for improving cotton fibers. Fourier Transform Infrared (FT-IR) spectroscopy enables distinguishing SCW from other cell wall componen...

CHARACTERIZATION OF AMBIENT PM2.5 AEROSOL AT A SOUTHEASTERN US SITE: FOURIER TRANSFORM INFRARED ANALYSIS OR PARTICLE PHASE

EPA Science Inventory

During a field study in the summer of 2000 in the Research Triangle Park (RTP), aerosol samples were collected using a five stage cascade impactor and subsequently analyzed using Fourier Transform Infrared Spectroscopy (FTIR). The impaction surfaces were stainless steel disks....

Abel inversion using fast Fourier transforms.

PubMed

Kalal, M; Nugent, K A

1988-05-15

A fast Fourier transform based Abel inversion technique is proposed. The method is faster than previously used techniques, potentially very accurate (even for a relatively small number of points), and capable of handling large data sets. The technique is discussed in the context of its use with 2-D digital interferogram analysis algorithms. Several examples are given.

Topics in Chemical Instrumentation: Fourier Transform-Infrared Spectroscopy: Part I. Instrumentation.

ERIC Educational Resources Information Center

Perkins, W. D.

1986-01-01

Discusses: (1) the design of the Fourier Transform-Infrared Spectroscopy (FT-IR) spectrometer; (2) the computation of the spectrum from the interferogram; and (3) the use of apodization. (Part II will discuss advantages of FT-IR over dispersive techniques and show applications of FT-IR to difficult spectroscopic measurements.) (JN)

Diffuse-reflectance fourier-transform mid-infrared spectroscopy as a method of characterizing changes in soil organic matter

USDA-ARS?s Scientific Manuscript database

Diffuse-Reflectance Fourier-Transform Mid-Infrared Spectroscopy (MidIR) can identify the presence of important organic functional groups in soil organic matter (SOM). Soils contain myriad organic and inorganic components that absorb in the MidIR so spectral interpretation needs to be validated in or...

Secondary cell wall development in cotton fibers as examined with attenuated total reflection Fourier transform infrared spectroscopy

USDA-ARS?s Scientific Manuscript database

Cotton fibers harvested at 18, 20, 24, 28, 32, 36 and 40 days after flowering were examined using attenuated total reflection Fourier transform-infrared (ATR FT-IR) spectroscopy. The selected harvesting points coincide with secondary cell wall (SCW) development in the fibers. Progressive but moderat...

Development of secondary cell wall in cotton fibers as examined with Fourier transform-infrared spectroscopy

USDA-ARS?s Scientific Manuscript database

Our presentation will focus on continuing efforts to examine secondary cell wall development in cotton fibers using infrared Spectroscopy. Cotton fibers harvested at 18, 20, 24, 28, 32, 36 and 40 days after flowering were examined using attenuated total reflection Fourier transform-infrared (ATR FT-...

INFFTM: Fast evaluation of 3d Fourier series in MATLAB with an application to quantum vortex reconnections

NASA Astrophysics Data System (ADS)

Caliari, Marco; Zuccher, Simone

2017-04-01

Although Fourier series approximation is ubiquitous in computational physics owing to the Fast Fourier Transform (FFT) algorithm, efficient techniques for the fast evaluation of a three-dimensional truncated Fourier series at a set of arbitrary points are quite rare, especially in MATLAB language. Here we employ the Nonequispaced Fast Fourier Transform (NFFT, by J. Keiner, S. Kunis, and D. Potts), a C library designed for this purpose, and provide a Matlab® and GNU Octave interface that makes NFFT easily available to the Numerical Analysis community. We test the effectiveness of our package in the framework of quantum vortex reconnections, where pseudospectral Fourier methods are commonly used and local high resolution is required in the post-processing stage. We show that the efficient evaluation of a truncated Fourier series at arbitrary points provides excellent results at a computational cost much smaller than carrying out a numerical simulation of the problem on a sufficiently fine regular grid that can reproduce comparable details of the reconnecting vortices.

Vibrational spectroscopy and DFT calculations of flavonoid derriobtusone A

NASA Astrophysics Data System (ADS)

Marques, A. N. L.; Mendes Filho, J.; Freire, P. T. C.; Santos, H. S.; Albuquerque, M. R. J. R.; Bandeira, P. N.; Leite, R. V.; Braz-Filho, R.; Gusmão, G. O. M.; Nogueira, C. E. S.; Teixeira, A. M. R.

2017-02-01

Flavonoids are secondary metabolites of plants which perform various functions. One subclass of flavonoid is auronol that can present immunostimulating activity. In this work Fourier-Transform Infrared with Attenuated Total Reflectance (FTIR-ATR) and Fourier-Transform Raman (FT-Raman) spectra of an auronol, derriobtusone A (C18H12O4), were obtained at room temperature. Theoretical calculations using Density Functional Theory (DFT) were performed in order to assign the normal modes and to interpret the spectra of the derriobtusone A molecule. The FTIR-ATR and FT-Raman spectra of the crystal, were recorded at room temperature in the regions 600 cm-1 to 4000 cm-1 and 40 cm-1 to 4000 cm-1, respectively. The normal modes of vibrations were obtained using Density Functional Theory with B3LYP functional and 6-31G+ (d,p) basis set. The calculated frequencies are in good agreement with those obtained experimentally. Detailed assignments of the normal modes present in both the Fourier-Transform infrared and the Fourier-Transform Raman spectra of the crystal are given.

Extended sources near-field processing of experimental aperture synthesis data and application of the Gerchberg method for enhancing radiometric three-dimensional millimetre-wave images in security screening portals

NASA Astrophysics Data System (ADS)

Salmon, Neil A.

2017-10-01

Aperture synthesis for passive millimetre wave imaging provides a means to screen people for concealed threats in the extreme near-field configuration of a portal, a regime where the imager to subject distance is of the order of both the required depth-of-field and the field-of-view. Due to optical aberrations, focal plane array imagers cannot deliver the large depth-of-fields and field-of-views required in this regime. Active sensors on the other hand can deliver these but face challenges of illumination, speckle and multi-path issues when imaging canyon regions of the body. Fortunately an aperture synthesis passive millimetre wave imaging system can deliver large depth-of-fields and field-of-views, whilst having no speckle effects, as the radiometric emission from the human body is spatially incoherent. Furthermore, as in portal security screening scenarios the aperture synthesis imaging technique delivers a half-wavelength spatial resolution, it can effectively screen the whole of the human body. Some recent measurements are presented that demonstrate the three-dimensional imaging capability of extended sources using a 22 GHz aperture synthesis system. A comparison is made between imagery generated via the analytic Fourier transform and a gridding fast Fourier transform method. The analytic Fourier transform enables aliasing in the imagery to be more clearly identified. Some initial results are also presented of how the Gerchberg technique, an image enhancement algorithm used in radio astronomy, is adapted for three-dimensional imaging in security screening. This technique is shown to be able to improve the quality of imagery, without adding extra receivers to the imager. The requirements of a walk through security screening system for use at entrances to airport departure lounges are discussed, concluding that these can be met by an aperture synthesis imager.

Estimation of waste water treatment plant methane emissions: methodology and results from a short campaign

NASA Astrophysics Data System (ADS)

Yver-Kwok, C. E.; Müller, D.; Caldow, C.; Lebegue, B.; Mønster, J. G.; Rella, C. W.; Scheutz, C.; Schmidt, M.; Ramonet, M.; Warneke, T.; Broquet, G.; Ciais, P.

2013-10-01

This paper describes different methods to estimate methane emissions at different scales. These methods are applied to a waste water treatment plant (WWTP) located in Valence, France. We show that Fourier Transform Infrared (FTIR) measurements as well as Cavity Ring Down Spectroscopy (CRDS) can be used to measure emissions from the process to the regional scale. To estimate the total emissions, we investigate a tracer release method (using C2H2) and the Radon tracer method (using 222Rn). For process-scale emissions, both tracer release and chamber techniques were used. We show that the tracer release method is suitable to quantify facility- and some process-scale emissions, while the Radon tracer method encompasses not only the treatment station but also a large area around. Thus the Radon tracer method is more representative of the regional emissions around the city. Uncertainties for each method are described. Applying the methods to CH4 emissions, we find that the main source of emissions of the plant was not identified with certainty during this short campaign, although the primary source of emissions is likely to be from solid sludge. Overall, the waste water treatment plant represents a small part (3%) of the methane emissions of the city of Valence and its surroundings,which is in agreement with the national inventories.

A technique for phase correction in Fourier transform spectroscopy

NASA Astrophysics Data System (ADS)

Artsang, P.; Pongchalee, P.; Palawong, K.; Buisset, C.; Meemon, P.

2018-03-01

Fourier transform spectroscopy (FTS) is a type of spectroscopy that can be used to analyze components in the sample. The basic setup that is commonly used in this technique is "Michelson interferometer". The interference signal obtained from interferometer can be Fourier transformed into the spectral pattern of the illuminating light source. To experimentally study the concept of the Fourier transform spectroscopy, the project started by setup the Michelson interferometer in the laboratory. The implemented system used a broadband light source in near infrared region (0.81-0.89 μm) and controlled the movable mirror by using computer controlled motorized translation stage. In the early study, there is no sample the interference path. Therefore, the theoretical spectral results after the Fourier transformation of the captured interferogram must be the spectral shape of the light source. One main challenge of the FTS is to retrieve the correct phase information of the inferferogram that relates with the correct spectral shape of the light source. One main source of the phase distortion in FTS that we observed from our system is the non-linear movement of the movable reference mirror of the Michelson interferometer. Therefore, to improve the result, we coupled a monochromatic light source to the implemented interferometer. We simultaneously measured the interferograms of the monochromatic and broadband light sources. The interferogram of the monochromatic light source was used to correct the phase of the interferogram of the broadband light source. The result shows significant improvement in the computed spectral shape.

Three-dimensional Fourier transform evaluation of sequences of spatially and temporally modulated speckle interferograms.

PubMed

Trillo, C; Doval, A F; López-Vázquez, J C

2010-07-05

Phase evaluation methods based on the 2D spatial Fourier transform of a speckle interferogram with spatial carrier usually assume that the Fourier spectrum of the interferogram has a trimodal distribution, i. e. that the side lobes corresponding to the interferential terms do not overlap the other two spectral terms, which are related to the intensity of the object and reference beams, respectively. Otherwise, part of the spectrum of the object beam is inside the inverse-transform window of the selected interference lobe and induces an error in the resultant phase map. We present a technique for the acquisition and processing of speckle interferogram sequences that separates the interference lobes from the other spectral terms when the aforementioned assumption does not apply and regardless of the temporal bandwidth of the phase signal. It requires the recording of a sequence of interferograms with spatial and temporal carriers, and their processing with a 3D Fourier transform. In the resultant 3D spectrum, the spatial and temporal carriers separate the conjugate interferential terms from each other and from the term related to the object beam. Experimental corroboration is provided through the measurement of the amplitude of surface acoustic waves in plates with a double-pulsed TV holography setup. The results obtained with the proposed method are compared to those obtained with the processing of individual interferograms with the regular spatial-carrier 2D Fourier transform method.

Novel laser gain and time-resolved FTIR studies of photochemistry

NASA Technical Reports Server (NTRS)

Leone, Stephen R.

1990-01-01

Several techniques are discussed which can be used to explore laboratory photochemical processes and kinetics relevant to planetary atmospheres; these include time-resolved laser gain-versus-absorption spectroscopy and time-resolved Fourier transform infrared (FTIR) emission studies. The laser gain-versus-absorption method employed tunable diode and F-center lasers to determine the yields of excited photofragments and their kinetics. The time-resolved FTIR technique synchronizes the sweep of a commercial FTIR with a pulsed source of light to obtain emission spectra of novel transient species in the infrared. These methods are presently being employed to investigate molecular photodissociation, the yields of excited states of fragments, their subsequent reaction kinetics, Doppler velocity distributions, and velocity-changing collisions of translationally fast atoms. Such techniques may be employed in future investigations of planetary atmospheres, for example to study polycyclic aromatic hydrocarbons related to cometary emissions, to analyze acetylene decomposition products and reactions, and to determine spectral features in the near infrared and infrared wavelength regions for planetary molecules and clusters.

Effects of multiple organic ligands on size uniformity and optical properties of ZnSe quantum dots

DOE Office of Scientific and Technical Information (OSTI.GOV)

Archana, J., E-mail: archana.jayaram@yahoo.com; Navaneethan, M.; Hayakawa, Y.

2012-08-15

Highlights: ► Highly monodispersed ZnSe quantum dots have been synthesized by wet chemical route. ► Strong quantum confinement effect have been observed in ∼ 4 nm ZnSe quantum dots. ► Enhanced ultraviolet near band emission have been obtained using long chain polymer. -- Abstract: The effects of multi-ligands on the formation and optical transitions of ZnSe quantum dots have been investigated. The dots are synthesized using 3-mercapto-1,2-propanediol and polyvinylpyrrolidone ligands, and have been characterized by X-ray diffraction, transmission electron microscopy (TEM), UV–visible absorption spectroscopy, photoluminescence spectroscopy, and Fourier transform infrared spectroscopy. TEM reveals high monodispersion with an average size ofmore » 4 nm. Polymer-stabilized, organic ligand-passivated ZnSe quantum dots exhibit strong UV emission at 326 nm and strong quantum confinement in the UV–visible absorption spectrum. Uniform size and suppressed surface trap emission are observed when the polymer ligand is used. The possible growth mechanism is discussed.« less

Synthesis and Properties of Gelators Derived from Tetraphenylethylene and Gallic Acid with Aggregation-Induced Emission

NASA Astrophysics Data System (ADS)

Luo, Miao; Zhou, Xie; Chi, Zhenguo; Ma, Chunping; Zhang, Yi; Liu, Siwei; Xu, Jiarui

2013-09-01

Two novel organogelators (TEG and TAG) based on tetraphenylethylene and 3,4,5-tris(dodecyloxy) benzoic acid were synthesized through ester bond and amido bond linkages, respectively. Compounds TEG and TAG were able to induce gelation in ethanol. Aggregation-induced enhanced emission was observed in these organogelator molecules, with increased fluorescence intensity from the solutions to the gels. The completely thermoreversible gelation occurred due to the aggregation of the organogelators. In the process, a fibrous network was formed by a combination of intermolecular hydrogen bonding, π-π stacking and van der Waals interactions. These phenomena were observed in the xerogels by field-emission scanning electron microscopy and Fourier-transform infrared spectroscopy. The results of differential scanning calorimetry and polarized optical microscopy indicated that compound TAG exhibited stable liquid crystalline phases over a wide temperature range. The linking groups have severe influence on the properties of the organogelators, which was mainly attributed to the hydrogen bonding interaction in compound TAG.

Ammonia and methane emissions during drying of dewatered biogas digestate in a two-belt conveyor dryer.

PubMed

Awiszus, S; Meissner, K; Reyer, S; Müller, J

2018-01-01

Aim of the present study was to identify type and amount of emissions during the drying of biogas digestate in a two-belt conveyor dryer at different temperature settings and to investigate the effect on its nutrient content. Furthermore, the possibility of recovering nitrogen from the exhaust air was investigated. Emissions of CH 4 , CO 2 and NH 3 were measured by Fourier transform infrared spectroscopy. Biogas is mainly composed of CH 4 and CO 2 , hence gas release from the digestate during drying was expected to increase the concentration of these components. Although CO 2 concentration was elevated above the background concentration, CH 4 did not exceed the background concentration. Maximum NH 3 concentration of 183.3mg·m -3 was detected during drying. A NH 3 concentration of 10.8mg·m -3 was measured in the exhaust air of the ammonia scrubber, which is equal to a NH 3 reduction rate of 94%. Copyright © 2017 Elsevier Ltd. All rights reserved.

Investigations of the functional states of dendritic cells under different conditioned microenvironments by Fourier transformed infrared spectroscopy.

PubMed

Dong, Rong; Long, Jinhua; Xu, Xiaoli; Zhang, Chunlin; Wen, Zongyao; Li, Long; Yao, Weijuan; Zeng, Zhu

2014-01-10

Dendritic cells are potent and specialized antigen presenting cells, which play a crucial role in initiating and amplifying both the innate and adaptive immune responses. The dendritic cell-based vaccination against cancer has been clinically achieved promising successes. But there are still many challenges in its clinical application, especially for how to identify the functional states. The CD14+ monocytes were isolated from human peripheral blood after plastic adherence and purified to approximately 98% with cocktail immunomagnetic beads. The immature dendritic cells and mature dendritic cells were induced by traditional protocols. The resulting dendritic cells were cocultured with normal cells and cancer cells. The functional state of dendritic cells including immature dendritic cells (imDCs) and mature dendritic cells (mDCs) under different conditioned microenvironments were investigated by Fourier transformed infrared spectroscopy (FTIR) and molecular biological methods. The results of Fourier transformed infrared spectroscopy showed that the gene transcription activity and energy states of dendritic cells were specifically suppressed by tumor cells (P < 0.05 or 0.01). The expression levels of NF-kappa B (NF-κB) in dendritic cells were also specifically inhibited by tumor-derived factors (P < 0.05 or 0.01). Moreover, the ratios of absorption intensities of Fourier transformed infrared spectroscopy at given wave numbers were closely correlated with the expression levels of NF-κB (R2:0.69 and R2:0.81, respectively). Our results confirmed that the ratios of absorption intensities of Fourier transformed infrared spectroscopy at given wave numbers were positively correlated with the expression levels of NF-κB, suggesting that Fourier transformed infrared spectroscopy technology could be clinically applied to identify the functional states of dendritic cell when performing dendritic cell-based vaccination. It's significant for the simplification and standardization of dendritic cell-based vaccination clinical preparation protocols.

Study to define behavior of liquid lubricants in an elastohydrodynamic contact

NASA Technical Reports Server (NTRS)

Lauer, J. L.

1974-01-01

The spectra of an ester and a saturated hydrocarbon polymer were obtained at pressures ranging from ambient to 2 GN/sq m (20 kilobar) and at temperatures between ambient and 180 C in absorption and between 150 C and 210 C in emission. To simulate contact conditions the fluids were contained in the tiny sample volume of a diamond cell, i.e., the hole in a metal spacer separating two diamonds pressed against each other in a nut crackerlike arrangement. Pressures could be deduced from bandshifts and states of aggregation from bandwidths in the fluorescence spectrum of a ruby crystal immersed in the fluids. An infrared Fourier transform spectrometer was used with attachments specially designed to analyze the radiation passed through the sample and both diamonds (absorption technique) or the radiation emanating from the heated sample and passing through only one diamond (emission technique). The latter technique is applicable to operating EHD contacts. Spectral changes pointing to possible glass transitions and composition changes were observed. Emission and absorption spectra were generally equivalent. Some emission bandshapes appear to be temperature sensitive enough to be useful as internal temperature probes.

Thickness and annealing effects on thermally evaporated InZnO thin films for gas sensors and blue, green and yellow emissive optical devices

NASA Astrophysics Data System (ADS)

Sugumaran, Sathish; Jamlos, Mohd Faizal; Ahmad, Mohd Noor; Bellan, Chandar Shekar; Sivaraj, Manoj

2016-08-01

Indium zinc oxide (InZnO) thin films with thicknesses of 100 nm and 200 nm were deposited on glass plate by thermal evaporation technique. Fourier transform infrared spectra showed a strong metal-oxide bond. X-ray diffraction patterns revealed amorphous nature for as-deposited film whereas polycrystalline structure for annealed films. Scanning electron microscope images showed a uniform distribution of spherical shape grains. Grain size was found to be higher for 200 nm film than 100 nm film. The presence of elements (In, Zn and O) was confirmed from energy dispersive X-ray analysis. Photoluminescence study of 200 nm film showed a blue, blue-green and blue-yellow emission whereas 100 nm film showed a broad green and green-yellow emissions. Both 100 nm and 200 nm films showed good oxygen sensitivity from room temperature to 400 °C. The observed optical and sensor results indicated that the prepared InZnO films are highly potential for room temperature gas sensor and blue, green and yellow emissive opto-electronic devices.

Theory of Wavelet-Based Coarse-Graining Hierarchies for Molecular Dynamics

DTIC Science & Technology

2017-04-01

resolution. ............................................... 15 Fig. 6 Fourier transform of the y-component of 1,000 atoms in crystalline PE (100,800 atoms...of magnitude of optimal representation. . 16 Fig. 7 Top row: Fourier transform of the y-component of a 100,800 atom crystalline PE sampled at 1 fs. 3... transform of the z-component of alanine dipeptide in vacuum excluding zero frequency to allow detail at other frequencies. MD at 500 K and 1 atm. Left

Investigating the 3.3 micron infrared fluorescence from naphthalene following ultraviolet excitation

NASA Technical Reports Server (NTRS)

Williams, Richard M.; Leone, Stephen R.

1994-01-01

Polycyclic aromatic hydrocarbon (PAH) type molecules are proposed as the carriers of the unidentified infrared (UIR) bands. Detailed studies of the 3.3 micrometer infrared emission features from naphthalene, the simplest PAH, following ultraviolet laser excitation are used in the interpretation of the 3.29 micrometer (3040 cm(sup -1)) UIR band. A time-resolved Fourier transform spectrometer is used to record the infrared emission spectrum of gas-phase naphthalene subsequent to ultraviolet excitation facilitated by an excimer laser operated at either 193 nm or 248 nm. The emission spectra differ significantly from the absorption spectrum in the same spectral region. Following 193 nm excitation the maximum in the emission profile is red-shifted 45 cm(sup -1) relative to the absorption maximum; a 25 cm(sup -1) red-shift is observed after 248 nm excitation. The red-shifting of the emission spectrum is reduced as collisional and radiative relaxation removes energy from the highly vibrationally excited molecules. Coupling between the various vibrational modes is thought to account for the differences between absorption and emission spectra. Strong visible emission is also observed following ultraviolet excitation. Visible emission may play an important role in the rate of radiative relaxation, which according to the interstellar PAH hypothesis occurs only by the slow emission of infrared photons. Studying the visible emission properties of PAH type molecules may be useful in the interpretation of the DIB's observed in absorption.

Discrete Fourier Transform in a Complex Vector Space

NASA Technical Reports Server (NTRS)

Dean, Bruce H. (Inventor)

2015-01-01

An image-based phase retrieval technique has been developed that can be used on board a space based iterative transformation system. Image-based wavefront sensing is computationally demanding due to the floating-point nature of the process. The discrete Fourier transform (DFT) calculation is presented in "diagonal" form. By diagonal we mean that a transformation of basis is introduced by an application of the similarity transform of linear algebra. The current method exploits the diagonal structure of the DFT in a special way, particularly when parts of the calculation do not have to be repeated at each iteration to converge to an acceptable solution in order to focus an image.

Use of Fourier transforms for asynoptic mapping: Applications to the Upper Atmosphere Research Satellite microwave limb sounder

NASA Technical Reports Server (NTRS)

Elson, Lee S.; Froidevaux, Lucien

1993-01-01

Fourier analysis has been applied to data obtained from limb viewing instruments on the Upper Atmosphere Research Satellite. A coordinate system rotation facilitates the efficient computation of Fourier transforms in the temporal and longitudinal domains. Fields such as ozone (O3), chlorine monoxide (ClO), temperature, and water vapor have been transformed by this process. The transforms have been inverted to provide maps of these quantities at selected times, providing a method of accurate time interpolation. Maps obtained by this process show evidence of both horizontal and vertical transport of important trace species such as O3 and ClO. An examination of the polar regions indicates that large-scale planetary variations are likely to play a significant role in transporting midstratospheric O3 into the polar regions. There is also evidence that downward transport occurs, providing a means of moving O3 into the polar vortex at lower altitudes. The transforms themselves show the structure and propagation characteristics of wave variations.

Electro-optic imaging Fourier transform spectrometer

NASA Technical Reports Server (NTRS)

Chao, Tien-Hsin (Inventor); Znod, Hanying (Inventor)

2009-01-01

An Electro-Optic Imaging Fourier Transform Spectrometer (EOIFTS) for Hyperspectral Imaging is described. The EOIFTS includes an input polarizer, an output polarizer, and a plurality of birefringent phase elements. The relative orientations of the polarizers and birefringent phase elements can be changed mechanically or via a controller, using ferroelectric liquid crystals, to substantially measure the spectral Fourier components of light propagating through the EIOFTS. When achromatic switches are used as an integral part of the birefringent phase elements, the EIOFTS becomes suitable for broadband applications, with over 1 micron infrared bandwidth.

Geometry and dynamics in the fractional discrete Fourier transform.

PubMed

Wolf, Kurt Bernardo; Krötzsch, Guillermo

2007-03-01

The N x N Fourier matrix is one distinguished element within the group U(N) of all N x N unitary matrices. It has the geometric property of being a fourth root of unity and is close to the dynamics of harmonic oscillators. The dynamical correspondence is exact only in the N-->infinity contraction limit for the integral Fourier transform and its fractional powers. In the finite-N case, several options have been considered in the literature. We compare their fidelity in reproducing the classical harmonic motion of discrete coherent states.

A novel recursive Fourier transform for nonuniform sampled signals: application to heart rate variability spectrum estimation.

PubMed

Holland, Alexander; Aboy, Mateo

2009-07-01

We present a novel method to iteratively calculate discrete Fourier transforms for discrete time signals with sample time intervals that may be widely nonuniform. The proposed recursive Fourier transform (RFT) does not require interpolation of the samples to uniform time intervals, and each iterative transform update of N frequencies has computational order N. Because of the inherent non-uniformity in the time between successive heart beats, an application particularly well suited for this transform is power spectral density (PSD) estimation for heart rate variability. We compare RFT based spectrum estimation with Lomb-Scargle Transform (LST) based estimation. PSD estimation based on the LST also does not require uniform time samples, but the LST has a computational order greater than Nlog(N). We conducted an assessment study involving the analysis of quasi-stationary signals with various levels of randomly missing heart beats. Our results indicate that the RFT leads to comparable estimation performance to the LST with significantly less computational overhead and complexity for applications requiring iterative spectrum estimations.

Computing the Power-Density Spectrum for an Engineering Model

NASA Technical Reports Server (NTRS)

Dunn, H. J.

1982-01-01

Computer program for calculating of power-density spectrum (PDS) from data base generated by Advanced Continuous Simulation Language (ACSL) uses algorithm that employs fast Fourier transform (FFT) to calculate PDS of variable. Accomplished by first estimating autocovariance function of variable and then taking FFT of smoothed autocovariance function to obtain PDS. Fast-Fourier-transform technique conserves computer resources.

Using Mathematical Software to Introduce Fourier Transforms in Physical Chemistry to Develop Improved Understanding of Their Applications in Analytical Chemistry

ERIC Educational Resources Information Center

Miller, Tierney C.; Richardson, John N.; Kegerreis, Jeb S.

2016-01-01

This manuscript presents an exercise that utilizes mathematical software to explore Fourier transforms in the context of model quantum mechanical systems, thus providing a deeper mathematical understanding of relevant information often introduced and treated as a "black-box" in analytical chemistry courses. The exercise is given to…

Teaching Stable Two-Mirror Resonators through the Fractional Fourier Transform

ERIC Educational Resources Information Center

Moreno, Ignacio; Garcia-Martinez, Pascuala; Ferreira, Carlos

2010-01-01

We analyse two-mirror resonators in terms of their fractional Fourier transform (FRFT) properties. We use the basic ABCD ray transfer matrix method to show how the resonator can be regarded as the cascade of two propagation-lens-propagation FRFT systems. Then, we present a connection between the geometric properties of the resonator (the g…

Rapid identification and classification of Listeria spp. and serotype assignment of Listeria monocytogenes using fourier transform-infrared spectroscopy and artificial neural network analysis

USDA-ARS?s Scientific Manuscript database

The use of Fourier Transform-Infrared Spectroscopy (FT-IR) in conjunction with Artificial Neural Network software, NeuroDeveloper™ was examined for the rapid identification and classification of Listeria species and serotyping of Listeria monocytogenes. A spectral library was created for 245 strains...

COMPARISON OF AN INNOVATIVE NONLINEAR ALGORITHM TO CLASSICAL LEAST SQUARES FOR ANALYZING OPEN-PATH FOURIER TRANSFORM INFRARED SPECTRA COLLECTED AT A CONCENTRATED SWINE PRODUCTION FACILITY

EPA Science Inventory

Open-path Fourier transform infrared (OP/FTIR) spectrometry was used to measure the concentrations of ammonia, methane, and other atmospheric gases at an integrated swine production facility. The concentration-pathlength products of the target gases at this site often exceeded th...

APPLICATION OF STANDARDIZED QUALITY CONTROL PROCEDURES TO OPEN-PATH FOURIER TRANSFORM INFRARED DATA COLLECTED AT A CONCENTRATED SWINE PRODUCTION FACILITY

EPA Science Inventory

Open-path Fourier transform infrared (OP/FT-IR) spectrometry was used to measure the concentrations of ammonia, methane, and other atmospheric eases at a concentrated swine production facility. A total of 2200 OP/FT-IR spectra were acquired along nine different monitoring paths d...

“Self-absorption” phenomenon in near-infrared Fourier transform Raman spectroscopy of cellulosic and lignocellulosic materials

Treesearch

Umesh P. Agarwal; Nancy Kawai

2005-01-01

While cellulosic and lignocellulosic materials have been studied using conventional Raman spectroscopy, availability of near-infrared (NIR) Fourier transform (FT) Raman instrumentation has made studying these materials much more convenient. This is especially true because the problem of laser-induced fluorescence can be avoided or minimized in FT- Raman (NIR Raman)...

Propagation Characteristics Of Weakly Guiding Optical Fibers

NASA Technical Reports Server (NTRS)

Manshadi, Farzin

1992-01-01

Report discusses electromagnetic propagation characteristics of weakly guiding optical-fiber structures having complicated shapes with cross-sectional dimensions of order of wavelength. Coupling, power-dividing, and transition dielectric-waveguide structures analyzed. Basic data computed by scalar-wave, fast-Fourier-transform (SW-FFT) technique, based on numerical solution of scalar version of wave equation by forward-marching fast-Fourier-transform method.

Electro-optic Imaging Fourier Transform Spectrometer

NASA Technical Reports Server (NTRS)

Chao, Tien-Hsin

2005-01-01

JPL is developing an innovative compact, low mass, Electro-Optic Imaging Fourier Transform Spectrometer (E-O IFTS) for hyperspectral imaging applications. The spectral region of this spectrometer will be 1 - 2.5 micron (1000-4000/cm) to allow high-resolution, high-speed hyperspectral imaging applications. One application will be the remote sensing of the measurement of a large number of different atmospheric gases simultaneously in the same airmass. Due to the use of a combination of birefringent phase retarders and multiple achromatic phase switches to achieve phase delay, this spectrometer is capable of hyperspectral measurements similar to that of the conventional Fourier transform spectrometer but without any moving parts. In this paper, the principle of operations, system architecture and recent experimental progress will be presented.

Electro-optic Imaging Fourier Transform Spectrometer

NASA Technical Reports Server (NTRS)

Chao, Tien-Hsin

2005-01-01

JPL is developing an innovative compact, low mass, Electro-Optic Imaging Fourier Transform Spectrometer (E-0IFTS) for hyperspectral imaging applications. The spectral region of this spectrometer will be 1 - 2.5 pm (1000 -4000 cm-') to allow high-resolution, high-speed hyperspectral imaging applications [l-51. One application will be theremote sensing of the measurement of a large number of different atmospheric gases simultaneously in the sameairmass. Due to the use of a combination of birefiingent phase retarders and multiple achromatic phase switches toachieve phase delay, this spectrometer is capable of hyperspectral measurements similar to that of the conventionalFourier transform spectrometer but without any moving parts. In this paper, the principle of operations, systemarchitecture and recent experimental progress will be presen.

Application of Fourier transforms for microwave radiometric inversions

NASA Technical Reports Server (NTRS)

Holmes, J. J.; Balanis, C. A.; Truman, W. M.

1975-01-01

Existing microwave radiometer technology now provides a suitable method for remote determination of the ocean surface's absolute brightness temperature. To extract the brightness temperature of the water from the antenna temperature, an unstable Fredholm integral equation of the first kind is solved. Fourier transform techniques are used to invert the integral after it is placed into a cross correlation form. Application and verification of the methods to a two-dimensional modeling of a laboratory wave tank system are included. The instability of the ill-posed Fredholm equation is examined and a restoration procedure is included which smooths the resulting oscillations. With the recent availability and advances of fast Fourier transform (FFT) techniques, the method presented becomes very attractive in the evaluation of large quantities of data.

Fourier transform infrared microspectroscopy for the analysis of the biochemical composition of C. elegans worms.

PubMed

Sheng, Ming; Gorzsás, András; Tuck, Simon

2016-01-01

Changes in intermediary metabolism have profound effects on many aspects of C. elegans biology including growth, development and behavior. However, many traditional biochemical techniques for analyzing chemical composition require relatively large amounts of starting material precluding the analysis of mutants that cannot be grown in large amounts as homozygotes. Here we describe a technique for detecting changes in the chemical compositions of C. elegans worms by Fourier transform infrared microspectroscopy. We demonstrate that the technique can be used to detect changes in the relative levels of carbohydrates, proteins and lipids in one and the same worm. We suggest that Fourier transform infrared microspectroscopy represents a useful addition to the arsenal of techniques for metabolic studies of C. elegans worms.

The short time Fourier transform and local signals

NASA Astrophysics Data System (ADS)

Okumura, Shuhei

In this thesis, I examine the theoretical properties of the short time discrete Fourier transform (STFT). The STFT is obtained by applying the Fourier transform by a fixed-sized, moving window to input series. We move the window by one time point at a time, so we have overlapping windows. I present several theoretical properties of the STFT, applied to various types of complex-valued, univariate time series inputs, and their outputs in closed forms. In particular, just like the discrete Fourier transform, the STFT's modulus time series takes large positive values when the input is a periodic signal. One main point is that a white noise time series input results in the STFT output being a complex-valued stationary time series and we can derive the time and time-frequency dependency structure such as the cross-covariance functions. Our primary focus is the detection of local periodic signals. I present a method to detect local signals by computing the probability that the squared modulus STFT time series has consecutive large values exceeding some threshold after one exceeding observation following one observation less than the threshold. We discuss a method to reduce the computation of such probabilities by the Box-Cox transformation and the delta method, and show that it works well in comparison to the Monte Carlo simulation method.

Methane Emissions from Leak and Loss Audits of Natural Gas Compressor Stations and Storage Facilities.

PubMed

Johnson, Derek R; Covington, April N; Clark, Nigel N

2015-07-07

As part of the Environmental Defense Fund's Barnett Coordinated Campaign, researchers completed leak and loss audits for methane emissions at three natural gas compressor stations and two natural gas storage facilities. Researchers employed microdilution high-volume sampling systems in conjunction with in situ methane analyzers, bag samples, and Fourier transform infrared analyzers for emissions rate quantification. All sites had a combined total methane emissions rate of 94.2 kg/h, yet only 12% of the emissions total resulted from leaks. Methane slip from exhausts represented 44% of the total emissions. Remaining methane emissions were attributed to losses from pneumatic actuators and controls, engine crankcases, compressor packing vents, wet seal vents, and slop tanks. Measured values were compared with those reported in literature. Exhaust methane emissions were lower than emissions factor estimates for engine exhausts, but when combined with crankcase emissions, measured values were 11.4% lower than predicted by AP-42 as applicable to emissions factors for four-stroke, lean-burn engines. Average measured wet seal emissions were 3.5 times higher than GRI values but 14 times lower than those reported by Allen et al. Reciprocating compressor packing vent emissions were 39 times higher than values reported by GRI, but about half of values reported by Allen et al. Though the data set was small, researchers have suggested a method to estimate site-wide emissions factors for those powered by four-stroke, lean-burn engines based on fuel consumption and site throughput.

The extended Fourier transform for 2D spectral estimation.

PubMed

Armstrong, G S; Mandelshtam, V A

2001-11-01

We present a linear algebraic method, named the eXtended Fourier Transform (XFT), for spectral estimation from truncated time signals. The method is a hybrid of the discrete Fourier transform (DFT) and the regularized resolvent transform (RRT) (J. Chen et al., J. Magn. Reson. 147, 129-137 (2000)). Namely, it estimates the remainder of a finite DFT by RRT. The RRT estimation corresponds to solution of an ill-conditioned problem, which requires regularization. The regularization depends on a parameter, q, that essentially controls the resolution. By varying q from 0 to infinity one can "tune" the spectrum between a high-resolution spectral estimate and the finite DFT. The optimal value of q is chosen according to how well the data fits the form of a sum of complex sinusoids and, in particular, the signal-to-noise ratio. Both 1D and 2D XFT are presented with applications to experimental NMR signals. Copyright 2001 Academic Press.

Replica Fourier Tansforms on Ultrametric Trees, and Block-Diagonalizing Multi-Replica Matrices

NASA Astrophysics Data System (ADS)

de Dominicis, C.; Carlucci, D. M.; Temesvári, T.

1997-01-01

The analysis of objects living on ultrametric trees, in particular the block-diagonalization of 4-replica matrices M^{α β;γ^δ}, is shown to be dramatically simplified through the introduction of properly chosen operations on those objects. These are the Replica Fourier Transforms on ultrametric trees. Those transformations are defined and used in the present work. On montre que l'analyse d'objets vivant sur un arbre ultramétrique, en particulier, la diagonalisation par blocs d'une matrice M^{α β;γ^δ} dépendant de 4-répliques, se simplifie de façon dramatique si l'on introduit les opérations appropriées sur ces objets. Ce sont les Transformées de Fourier de Répliques sur un arbre ultramétrique. Ces transformations sont définies et utilisées dans le présent travail.

Intelligent Automatic Classification of True and Counterfeit Notes Based on Spectrum Analysis

NASA Astrophysics Data System (ADS)

Matsunaga, Shohei; Omatu, Sigeru; Kosaka, Toshohisa

The purpose of this paper is to classify bank notes into “true” or “counterfeit” ones faster and more precisely compared with a conventional method. We note that thin lines are represented by direct lines in the images of true notes while they are represented in the counterfeit notes by dotted lines. This is due to properties of dot printers or scanner levels. To use the properties, we propose two method to classify a note into true or counterfeited one by checking whether there exist thin lines or dotted lines of the note. First, we use Fourier transform of the note to find quantity of features for classification and we classify a note into true or counterfeit one by using the features by Fourier transform. Then we propose a classification method by using wavelet transform in place of Fourier transform. Finally, some classification results are illustrated to show the effectiveness of the proposed methods.

Au-nanocluster emission based glucose sensing.

PubMed

Hussain, A M P; Sarangi, S N; Kesarwani, J A; Sahu, S N

2011-11-15

Fabrication of a glucose biosensor based on Au-cluster emission quenching in the UV region is reported. The glucose biosensor is highly sensitive to β-d-glucose in 2.5-25.0mM range as confirmed from a linear calibration plot between Au-cluster colloid emission intensity as a function of β-d-glucose concentration. The interaction of β-d-glucose with l-cysteine capped Au cluster colloids has been confirmed from their Fourier transformed infrared spectroscopy (FTIR) measurements. It has been found that the biomolecules present in the serum such as ascorbic and uric acids, proteins and peptides do not interfere and affect in glucose estimation as confirmed from their absorption and fluorescence (FL) emission measurements. Practical utility of this sensor based on FL quenching method has been demonstrated by estimating the glucose level in human serum that includes diabetes and the data were found to be comparable or more accurate than those of the pathological data obtained from a local hospital. In addition, this biosensor is useful to detect glucose level over a wide range with sensor response time of the order of nano to picoseconds that is emission lifetime of Au clusters. Copyright © 2011 Elsevier B.V. All rights reserved.

Measuring NMHC and NMOG emissions from motor vehicles via FTIR spectroscopy

NASA Astrophysics Data System (ADS)

Gierczak, Christine A.; Kralik, Lora L.; Mauti, Adolfo; Harwell, Amy L.; Maricq, M. Matti

2017-02-01

The determination of non-methane organic gases (NMOG) emissions according to United States Environmental Protection Agency (EPA) regulations is currently a multi-step process requiring separate measurement of various emissions components by a number of independent on-line and off-line techniques. The Fourier transform infrared spectroscopy (FTIR) method described in this paper records all required components using a single instrument. It gives data consistent with the regulatory method, greatly simplifies the process, and provides second by second time resolution. Non-methane hydrocarbons (NMHCs) are measured by identifying a group of hydrocarbons, including oxygenated species, that serve as a surrogate for this class, the members of which are dynamically included if they are present in the exhaust above predetermined threshold levels. This yields an FTIR equivalent measure of NMHC that correlates within 5% to the regulatory flame ionization detection (FID) method. NMOG is then determined per regulatory calculation solely from FTIR recorded emissions of NMHC, ethanol, acetaldehyde, and formaldehyde, yielding emission rates that also correlate within 5% with the reference method. Examples are presented to show how the resulting time resolved data benefit aftertreatment development for light duty vehicles.

Doping effect of polyaniline/MWCNT composites on capacitance and cyclic stability of supercapacitors.

PubMed

Karthikeyan, G; Sahoo, S; Nayak, G C; Das, C K

2012-03-01

Polyaniline doped by Zn2+ ions was synthesized as nanocomposites with multiwalled carbon nanotubes (MWCNT) by in-situ oxidative polymerization and investigated as electrode material for supercapacitors. The uniform coating of polyaniline on MWCNT was characterized by field emission scanning electron microscopy (FESEM) and high resolution transmission electron microscopy (HRTEM). The effect of Zn2+ ions on nanocomposites were characterized by Fourier transform infrared (FTIR) spectroscopy. The electrochemical performances were investigated by cyclic voltammetry (CV), constant current charging/discharging cyclic test (CC) and electrochemical impedance spectroscopy (EIS) using a three-electrode system. The doped polyaniline composites show higher specific capacitance and better cyclic stability.

Application of Ni-Oxide@TiO₂ Core-Shell Structures to Photocatalytic Mixed Dye Degradation, CO Oxidation, and Supercapacitors.

PubMed

Lee, Seungwon; Lee, Jisuk; Nam, Kyusuk; Shin, Weon Gyu; Sohn, Youngku

2016-12-20

Performing diverse application tests on synthesized metal oxides is critical for identifying suitable application areas based on the material performances. In the present study, Ni-oxide@TiO₂ core-shell materials were synthesized and applied to photocatalytic mixed dye (methyl orange + rhodamine + methylene blue) degradation under ultraviolet (UV) and visible lights, CO oxidation, and supercapacitors. Their physicochemical properties were examined by field-emission scanning electron microscopy, X-ray diffraction analysis, Fourier-transform infrared spectroscopy, and UV-visible absorption spectroscopy. It was shown that their performances were highly dependent on the morphology, thermal treatment procedure, and TiO₂ overlayer coating.

Mesures spectroscopiques de constituants et de polluants atmosphériques par techniques in situ et à distance, au sol ou embarquéesSpectroscopic measurements of atmospheric constituents and pollutants by in situ and remote techniques from the ground and in flight

NASA Astrophysics Data System (ADS)

Camy-Peyret, Claude; Payan, Sébastien; Jeseck, Pascal; Té, Yao

2001-09-01

Infrared spectroscopy is a powerful tool for precise measurements of atmospheric trace species concentrations through the use of characteristic spectral signatures of the different molecular species and their associated vibration-rotation bands in the mid- or near-infrared. Different methods based on quantitative spectroscopy permit tropospheric or stratospheric measurements: in situ long path absorption, atmospheric absorption/emission by Fourier transform spectroscopy with high spectral resolution instruments on the ground, airborne, balloon-borne or satellite-borne.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gantayat, S., E-mail: subhra-gantayat@rediffmail.com; Rout, D.; Swain, S. K.

The effect of the functionalization of multiwalled carbon nanotube on the structure and electrical properties of composites was investigated. Samples based on epoxy resin with different weight percentage of MWCNTs were prepared and characterized. The interaction between MWCNT & epoxy resin was noticed by Fourier transform infrared spectroscopy (FTIR). The structure of functionalized multiwalled carbon nanotube (f-MWCNT) reinforced epoxy composite was studied by field emission scanning electron microscope (FESEM). The dispersion of f-MWCNT in epoxy resin was evidenced by high resolution transmission electron microscope (HRTEM). Electrical properties of epoxy/f-MWCNT nanocomposites were measured & the result indicated that the conductivity increasedmore » with increasing concentration of f-MWCNTs.« less

Maleic anhydride-g-low density polyethylene: Modification of LDPE molecular structure by γ-irradiation

NASA Astrophysics Data System (ADS)

Sheeja, Manaf, O.; Sujith, A.

2017-06-01

Polymer modification by radiation grafting of monomers onto polymers has received much attention recently. In the current study, γ-irradiation technique was used to achieve graft copolymerization of maleic anhydride (MA) onto low-density polyethylene (LDPE). To optimize, the process was performed at different γ-irradiation doses and MA concentration. The microstructure of grafted polymer film has been characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry, field emission-scanning electron microscopy, and atomic force microscopy. The studies performed made possible the selection of experimental protocols adequate for the production of new copolymeric materials with high grafting yield.

Synthesis of functional carbon nanospheres by a composite-molten-salt method and amperometric sensing of hydrogen peroxide.

PubMed

Wang, Xue; Hu, Chenguo; Xiong, Yufeng; Zhang, Cuiling

2013-02-01

Functional carbon nanospheres have been synthesized from analytically pure glucose by a composite-molten-salt (CMS) method. Field emission scanning electron microscopy, transmission electron microscopy, Raman and Fourier transformation infra-red spectroscopy indicate the carbon nanospheres are solid, bond hybridisation (sp2/sp3) and with many functional groups on their surfaces. Amperometric sensor based on the synthesized carbon nanospheres have been fabricated without pretreatment or modification. The detection of hydrogen peroxide exhibits high sensitivity and good selectivity. The electrochemical measurement of these nanospheres demonstrates much superior performance to those of the carbon nanospheres synthesized by hydrothermal method.

Surface morphology and improved electrical conductivity of camphorsulfonic acid surfactant based PANI nano composite

NASA Astrophysics Data System (ADS)

Niranjana, M.; Yesappa, L.; Ashokkumar, S. P.; Vijeth, H.; Devendrappa, H.

2018-05-01

Polyaniline and its composites at different wt. % of Copper oxide nano (PCC1 and PCC5) were prepared by in-situ chemical reaction method. The composites were characterized by Fourier Transform Infrared (FT-IR) Spectroscopy, Field Emission Scanning Electron Microscopy (FESEM) and the impedance measurement was carried out at different temperature. FTIR and SEM image reveals the presence of copper metal ions uniformly embedded into PANI. The dc electrical conductivity increases with increasing nano concentration in PANI and achieved high conductivity for PCC5. These results are suggesting PCC composite is a prominent candidate for supercapacitor properties and optoelectronics devices applications.

Novel multiform morphologies of hydroxyapatite: Synthesis and growth mechanism

NASA Astrophysics Data System (ADS)

Mary, I. Reeta; Sonia, S.; Viji, S.; Mangalaraj, D.; Viswanathan, C.; Ponpandian, N.

2016-01-01

Morphological evolution of materials becomes a prodigious challenge due to their key role in defining their functional properties and desired applications. Herein, we report the synthesis of hydroxyapatite (HAp) microstructures with multiform morphologies, such as spheres, cubes, hexagonal rods and nested bundles constructed from their respective nanoscale building blocks via a simple cost effective hydro/solvothermal method. A possible formation mechanism of diverse morphologies of HAp has been presented. Structural analysis based on X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy confirms the purity of the HAp microstructures. The multiform morphologies of HAp were corroborated by using Field emission scanning electron microscope (FESEM).

Design of two blackbody sources for millimeter and sub-millimeter wave Fourier transform spectrometry

NASA Astrophysics Data System (ADS)

Colin, Angel

2014-03-01

This paper describes an experimental setup for the spectral calibration of bolometric detectors used in radioastronomy. The system is composed of a Martin-Puplett interferometer with two identical artificial blackbody sources operating in the vacuum mode at 77 K and 300 K simultaneously. One source is integrated into a liquid nitrogen cryostat, and the other one into a vacuum chamber at room temperature. The sources were designed with a combination of conical with cylindrical geometries thus forming an orthogonal configuration to match the internal optics of the interfermometer. With a simple mathematical model we estimated emissivities of ε 0.995 for each source.

The Er3+-Yb3+ codoped La2O3 phosphor in finger print detection and optical heating.

PubMed

Dey, Riya; Pandey, Anurag; Rai, Vineet Kumar

2014-07-15

The presence of impurities and morphological information about the Er(3+)-Yb(3+) codoped La2O3 phosphors prepared by two different synthesis techniques have been obtained with the help of Fourier transform infrared (FTIR) spectroscopy and Scanning electron microscopy (SEM) respectively. The effect of synthesis process on the frequency upconversion (UC) emission with an excitation at 980 nm from laser diode radiation has been performed. The use of codoped phosphor in latent finger print detection and laser induced heat generation has also been explored. Copyright © 2014 Elsevier B.V. All rights reserved.

On the action of Heisenberg's uncertainty principle in discrete linear methods for calculating the components of the deflection of the vertical

NASA Astrophysics Data System (ADS)

Mazurova, Elena; Lapshin, Aleksey

2013-04-01

The method of discrete linear transformations that can be implemented through the algorithms of the Standard Fourier Transform (SFT), Short-Time Fourier Transform (STFT) or Wavelet transform (WT) is effective for calculating the components of the deflection of the vertical from discrete values of gravity anomaly. The SFT due to the action of Heisenberg's uncertainty principle indicates weak spatial localization that manifests in the following: firstly, it is necessary to know the initial digital signal on the complete number line (in case of one-dimensional transform) or in the whole two-dimensional space (if a two-dimensional transform is performed) in order to find the SFT. Secondly, the localization and values of the "peaks" of the initial function cannot be derived from its Fourier transform as the coefficients of the Fourier transform are formed by taking into account all the values of the initial function. Thus, the SFT gives the global information on all frequencies available in the digital signal throughout the whole time period. To overcome this peculiarity it is necessary to localize the signal in time and apply the Fourier transform only to a small portion of the signal; the STFT that differs from the SFT only by the presence of an additional factor (window) is used for this purpose. A narrow enough window is chosen to localize the signal in time and, according to Heisenberg's uncertainty principle, it results in have significant enough uncertainty in frequency. If one chooses a wide enough window it, according to the same principle, will increase time uncertainty. Thus, if the signal is narrowly localized in time its spectrum, on the contrary, is spread on the complete axis of frequencies, and vice versa. The STFT makes it possible to improve spatial localization, that is, it allows one to define the presence of any frequency in the signal and the interval of its presence. However, owing to Heisenberg's uncertainty principle, it is impossible to tell precisely, what frequency is present in the signal at the current moment of time: it is possible to speak only about the range of frequencies. Besides, it is impossible to specify precisely the time moment of the presence of this or that frequency: it is possible to speak only about the time frame. It is this feature that imposes major constrains on the applicability of the STFT. In spite of the fact that the problems of resolution in time and frequency result from a physical phenomenon (Heisenberg's uncertainty principle) and exist independent of the transform applied, there is a possibility to analyze any signal, using the alternative approach - the multiresolutional analysis (MRA). The wavelet-transform is one of the methods for making a MRA-type analysis. Thanks to it, low frequencies can be shown in a more detailed form with respect to time, and high ones - with respect to frequency. The paper presents the results of calculating of the components of the deflection of the vertical, done by the SFT, STFT and WT. The results are presented in the form of 3-d models that visually show the action of Heisenberg's uncertainty principle in the specified algorithms. The research conducted allows us to recommend the application of wavelet-transform to calculate of the components of the deflection of the vertical in the near-field zone. Keywords: Standard Fourier Transform, Short-Time Fourier Transform, Wavelet Transform, Heisenberg's uncertainty principle.

Mathematical Methods for Optical Physics and Engineering

NASA Astrophysics Data System (ADS)

Gbur, Gregory J.

2011-01-01

1. Vector algebra; 2. Vector calculus; 3. Vector calculus in curvilinear coordinate systems; 4. Matrices and linear algebra; 5. Advanced matrix techniques and tensors; 6. Distributions; 7. Infinite series; 8. Fourier series; 9. Complex analysis; 10. Advanced complex analysis; 11. Fourier transforms; 12. Other integral transforms; 13. Discrete transforms; 14. Ordinary differential equations; 15. Partial differential equations; 16. Bessel functions; 17. Legendre functions and spherical harmonics; 18. Orthogonal functions; 19. Green's functions; 20. The calculus of variations; 21. Asymptotic techniques; Appendices; References; Index.

Transfer Functions Via Laplace- And Fourier-Borel Transforms

NASA Technical Reports Server (NTRS)

Can, Sumer; Unal, Aynur

1991-01-01

Approach to solution of nonlinear ordinary differential equations involves transfer functions based on recently-introduced Laplace-Borel and Fourier-Borel transforms. Main theorem gives transform of response of nonlinear system as Cauchy product of transfer function and transform of input function of system, together with memory effects. Used to determine responses of electrical circuits containing variable inductances or resistances. Also possibility of doing all noncommutative algebra on computers in such symbolic programming languages as Macsyma, Reduce, PL1, or Lisp. Process of solution organized and possibly simplified by algebraic manipulations reducing integrals in solutions to known or tabulated forms.

A Modified Empirical Wavelet Transform for Acoustic Emission Signal Decomposition in Structural Health Monitoring.

PubMed

Dong, Shaopeng; Yuan, Mei; Wang, Qiusheng; Liang, Zhiling

2018-05-21

The acoustic emission (AE) method is useful for structural health monitoring (SHM) of composite structures due to its high sensitivity and real-time capability. The main challenge, however, is how to classify the AE data into different failure mechanisms because the detected signals are affected by various factors. Empirical wavelet transform (EWT) is a solution for analyzing the multi-component signals and has been used to process the AE data. In order to solve the spectrum separation problem of the AE signals, this paper proposes a novel modified separation method based on local window maxima (LWM) algorithm. It searches the local maxima of the Fourier spectrum in a proper window, and automatically determines the boundaries of spectrum segmentations, which helps to eliminate the impact of noise interference or frequency dispersion in the detected signal and obtain the meaningful empirical modes that are more related to the damage characteristics. Additionally, both simulation signal and AE signal from the composite structures are used to verify the effectiveness of the proposed method. Finally, the experimental results indicate that the proposed method performs better than the original EWT method in identifying different damage mechanisms of composite structures.

A Modified Empirical Wavelet Transform for Acoustic Emission Signal Decomposition in Structural Health Monitoring

PubMed Central

Dong, Shaopeng; Yuan, Mei; Wang, Qiusheng; Liang, Zhiling

2018-01-01

The acoustic emission (AE) method is useful for structural health monitoring (SHM) of composite structures due to its high sensitivity and real-time capability. The main challenge, however, is how to classify the AE data into different failure mechanisms because the detected signals are affected by various factors. Empirical wavelet transform (EWT) is a solution for analyzing the multi-component signals and has been used to process the AE data. In order to solve the spectrum separation problem of the AE signals, this paper proposes a novel modified separation method based on local window maxima (LWM) algorithm. It searches the local maxima of the Fourier spectrum in a proper window, and automatically determines the boundaries of spectrum segmentations, which helps to eliminate the impact of noise interference or frequency dispersion in the detected signal and obtain the meaningful empirical modes that are more related to the damage characteristics. Additionally, both simulation signal and AE signal from the composite structures are used to verify the effectiveness of the proposed method. Finally, the experimental results indicate that the proposed method performs better than the original EWT method in identifying different damage mechanisms of composite structures. PMID:29883411

Coherent time-stretch transformation for real-time capture of wideband signals.

PubMed

Buckley, Brandon W; Madni, Asad M; Jalali, Bahram

2013-09-09

Time stretch transformation of wideband waveforms boosts the performance of analog-to-digital converters and digital signal processors by slowing down analog electrical signals before digitization. The transform is based on dispersive Fourier transformation implemented in the optical domain. A coherent receiver would be ideal for capturing the time-stretched optical signal. Coherent receivers offer improved sensitivity, allow for digital cancellation of dispersion-induced impairments and optical nonlinearities, and enable decoding of phase-modulated optical data formats. Because time-stretch uses a chirped broadband (>1 THz) optical carrier, a new coherent detection technique is required. In this paper, we introduce and demonstrate coherent time stretch transformation; a technique that combines dispersive Fourier transform with optically broadband coherent detection.

Adaptive Filtering to Enhance Noise Immunity of Impedance and Admittance Spectroscopy: Comparison with Fourier Transformation

NASA Astrophysics Data System (ADS)

Stupin, Daniil D.; Koniakhin, Sergei V.; Verlov, Nikolay A.; Dubina, Michael V.

2017-05-01

The time-domain technique for impedance spectroscopy consists of computing the excitation voltage and current response Fourier images by fast or discrete Fourier transformation and calculating their relation. Here we propose an alternative method for excitation voltage and current response processing for deriving a system impedance spectrum based on a fast and flexible adaptive filtering method. We show the equivalence between the problem of adaptive filter learning and deriving the system impedance spectrum. To be specific, we express the impedance via the adaptive filter weight coefficients. The noise-canceling property of adaptive filtering is also justified. Using the RLC circuit as a model system, we experimentally show that adaptive filtering yields correct admittance spectra and elements ratings in the high-noise conditions when the Fourier-transform technique fails. Providing the additional sensitivity of impedance spectroscopy, adaptive filtering can be applied to otherwise impossible-to-interpret time-domain impedance data. The advantages of adaptive filtering are justified with practical living-cell impedance measurements.

Kinetics and Product Branching Fractions of Reactions between a Cation and a Radical: Ar+ + CH3 and O2+ + CH3 (Postprint)

DTIC Science & Technology

2015-01-13

Gross group using a Chen nozzle coupled to a Fourier transform ion cyclotron reso- nance (FT-ICR) mass spectrometer for reactions of the benzyl radical...reactions: A Fourier transform ion cyclotron resonance study of allyl radical reacting with aromatic radical cations. Int. J. Mass Spectrom. 2009, 287, 8

Introduction to Flight Test Engineering (Introduction aux techniques des essais en vol)

DTIC Science & Technology

2005-07-01

or aircraft parameters • Calculations in the frequency domain ( Fast Fourier Transform) • Data analysis with dedicated software for: • Signal...density Fast Fourier Transform Transfer function analysis Frequency response analysis Etc. PRESENTATION Color/black & white Display screen...envelope by operating the airplane at increasing ranges - representing increasing risk - of engine operation, airspeeds both fast and slow, altitude

Color and surface chemistry changes of extracted wood flour after heating at 120 °C

Treesearch

Yao Chen; Mandla A. Tshabalala; Jianmin Gao; Nicole M. Stark

2013-01-01

To investigate the effect of heat on color and surface chemistry of wood flour (WF), unextracted, extracted and delignified samples of commercial WF were heated at 120 °C for 24 h and analyzed by colorimetry, diffuse reflectance visible (DRV), attenuated total reflectance Fourier transform infrared (ATR-FTIR) and Fourier transform Raman (FT-Raman) spectroscopies....

Characterization of southern yellow pine bark layers by Attenuated Total Reflectance (ATR) and Fourier Transform Infrared (FT-IR) Spectroscopy

Treesearch

Thomas L. Eberhardt

2009-01-01

The outer bark (rhytidome) of the southern yellow pines is a complex structure comprised of alternating layers of obliterated phloem and periderm tissues, with the latter comprised of three layers, those being phellem, phellogen, and phelloderm. An attenuated total reflectance (ATR) sampling accessory, coupled with a Fourier transform infrared (FTIR) spectrometer,...

Determination of diosmin in pharmaceutical formulations using Fourier transform infrared spectrophotometry

PubMed Central

Bunaciu, Andrei A.; Udristioiu, Gabriela Elena; Ruţă, Lavinia L.; Fleschin, Şerban; Aboul-Enein, Hassan Y.

2009-01-01

A Fourier transform infrared (FT-IR) spectrometric method was developed for the rapid, direct measurement of diosmin in different pharmaceutical drugs. Conventional KBr-spectra were compared for best determination of active substance in commercial preparations. The Beer–Lambert law and two chemometric approaches, partial least squares (PLS) and principal component regression (PCR+) methods, were tried in data processing. PMID:23960715

Molecular Isotopic Distribution Analysis (MIDAs) with Adjustable Mass Accuracy

NASA Astrophysics Data System (ADS)

Alves, Gelio; Ogurtsov, Aleksey Y.; Yu, Yi-Kuo

2014-01-01

In this paper, we present Molecular Isotopic Distribution Analysis (MIDAs), a new software tool designed to compute molecular isotopic distributions with adjustable accuracies. MIDAs offers two algorithms, one polynomial-based and one Fourier-transform-based, both of which compute molecular isotopic distributions accurately and efficiently. The polynomial-based algorithm contains few novel aspects, whereas the Fourier-transform-based algorithm consists mainly of improvements to other existing Fourier-transform-based algorithms. We have benchmarked the performance of the two algorithms implemented in MIDAs with that of eight software packages (BRAIN, Emass, Mercury, Mercury5, NeutronCluster, Qmass, JFC, IC) using a consensus set of benchmark molecules. Under the proposed evaluation criteria, MIDAs's algorithms, JFC, and Emass compute with comparable accuracy the coarse-grained (low-resolution) isotopic distributions and are more accurate than the other software packages. For fine-grained isotopic distributions, we compared IC, MIDAs's polynomial algorithm, and MIDAs's Fourier transform algorithm. Among the three, IC and MIDAs's polynomial algorithm compute isotopic distributions that better resemble their corresponding exact fine-grained (high-resolution) isotopic distributions. MIDAs can be accessed freely through a user-friendly web-interface at http://www.ncbi.nlm.nih.gov/CBBresearch/Yu/midas/index.html.

GPU-accelerated non-uniform fast Fourier transform-based compressive sensing spectral domain optical coherence tomography.

PubMed

Xu, Daguang; Huang, Yong; Kang, Jin U

2014-06-16

We implemented the graphics processing unit (GPU) accelerated compressive sensing (CS) non-uniform in k-space spectral domain optical coherence tomography (SD OCT). Kaiser-Bessel (KB) function and Gaussian function are used independently as the convolution kernel in the gridding-based non-uniform fast Fourier transform (NUFFT) algorithm with different oversampling ratios and kernel widths. Our implementation is compared with the GPU-accelerated modified non-uniform discrete Fourier transform (MNUDFT) matrix-based CS SD OCT and the GPU-accelerated fast Fourier transform (FFT)-based CS SD OCT. It was found that our implementation has comparable performance to the GPU-accelerated MNUDFT-based CS SD OCT in terms of image quality while providing more than 5 times speed enhancement. When compared to the GPU-accelerated FFT based-CS SD OCT, it shows smaller background noise and less side lobes while eliminating the need for the cumbersome k-space grid filling and the k-linear calibration procedure. Finally, we demonstrated that by using a conventional desktop computer architecture having three GPUs, real-time B-mode imaging can be obtained in excess of 30 fps for the GPU-accelerated NUFFT based CS SD OCT with frame size 2048(axial) × 1,000(lateral).

Determination of Spectroscopic Properties of Atmospheric Molecules from High Resolution Vacuum Ultraviolet Cross Section and Wavelength Measurements

NASA Technical Reports Server (NTRS)

Parkinson, W. H.; Yoshino, K.

1997-01-01

An account is given of progress during the period 8/l/96-7/31/97 on work on (a) cross section measurements of O2 S-R using a Fourier transform spectrometer (FTS) at the Photon Factory in Japan; (b) the determination of the predissociation linewidths of the Schumann-Runge bands (S-R) of 02; (c) cross section measurements of 02 Herzberg bands using a Fourier transform spectrometer (FTS) at Imperial College; and (d) cross section measurements of H2O in the wavelength region 120-188 nm. The experimental investigations are effected at high resolution with a 6.65 m scanning spectrometer and with the Fourier transform spectrometer. Below 175 nm, synchrotron radiation is most suitable for cross section measurements in combination with spectrometers at the Photon Factory Japan. Cross section measurements of the Doppler limited bands depend on using the very high resolution, available with the Fourier transform spectrometer, (0.025/cm resolution). All of these spectroscopic measurements are needed for accurate calculations of the production of atomic oxygen, the penetration of solar radiation into the Earth's atmosphere, and photochemistry of minor molecules.

Molecular Isotopic Distribution Analysis (MIDAs) with adjustable mass accuracy.

PubMed

Alves, Gelio; Ogurtsov, Aleksey Y; Yu, Yi-Kuo

2014-01-01

In this paper, we present Molecular Isotopic Distribution Analysis (MIDAs), a new software tool designed to compute molecular isotopic distributions with adjustable accuracies. MIDAs offers two algorithms, one polynomial-based and one Fourier-transform-based, both of which compute molecular isotopic distributions accurately and efficiently. The polynomial-based algorithm contains few novel aspects, whereas the Fourier-transform-based algorithm consists mainly of improvements to other existing Fourier-transform-based algorithms. We have benchmarked the performance of the two algorithms implemented in MIDAs with that of eight software packages (BRAIN, Emass, Mercury, Mercury5, NeutronCluster, Qmass, JFC, IC) using a consensus set of benchmark molecules. Under the proposed evaluation criteria, MIDAs's algorithms, JFC, and Emass compute with comparable accuracy the coarse-grained (low-resolution) isotopic distributions and are more accurate than the other software packages. For fine-grained isotopic distributions, we compared IC, MIDAs's polynomial algorithm, and MIDAs's Fourier transform algorithm. Among the three, IC and MIDAs's polynomial algorithm compute isotopic distributions that better resemble their corresponding exact fine-grained (high-resolution) isotopic distributions. MIDAs can be accessed freely through a user-friendly web-interface at http://www.ncbi.nlm.nih.gov/CBBresearch/Yu/midas/index.html.

SHOCK EXCITED MOLECULES IN NGC 1266: ULIRG CONDITIONS AT THE CENTER OF A BULGE-DOMINATED GALAXY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pellegrini, E. W.; Smith, J. D.; Crocker, A. F.

We investigate the far infrared (IR) spectrum of NGC 1266, a S0 galaxy that contains a massive reservoir of highly excited molecular gas. Using the Herschel Fourier Transform Spectrometer, we detect the {sup 12}CO ladder up to J = (13-12), [C I] and [N II] lines, and also strong water lines more characteristic of UltraLuminous IR Galaxies (ULIRGs). The {sup 12}CO line emission is modeled with a combination of a low-velocity C-shock and a photodissociation region. Shocks are required to produce the H{sub 2}O and most of the high-J CO emission. Despite having an IR luminosity 30 times less than a typicalmore » ULIRG, the spectral characteristics and physical conditions of the interstellar medium of NGC 1266 closely resemble those of ULIRGs, which often harbor strong shocks and large-scale outflows.« less

Labeling of HeLa cells using ZrO2:Yb3+-Er3+ nanoparticles with upconversion emission

NASA Astrophysics Data System (ADS)

Ceja-Fdez, Andrea; López-Luke, Tzarara; Oliva, Jorge; Vivero-Escoto, Juan; Gonzalez-Yebra, Ana Lilia; Rojas, Ruben A. Rodriguez; Martínez-Pérez, Andrea; de la Rosa, Elder

2015-04-01

This work reports the synthesis, structural characterization, and optical properties of ZrO2:Yb3+-Er3+ (2-1 mol%) nanocrystals. The nanoparticles were coated with 3-aminopropyl triethoxysilane (APTES) and further modified with biomolecules, such as Biotin-Anti-rabbit (mouse IgG) and rabbit antibody-AntiKi-67, through a conjugation method. The conjugation was successfully confirmed by Fourier transform infrared, zeta potential, and dynamic light scattering. The internalization of the conjugated nanoparticles in human cervical cancer (HeLa) cells was followed by two-photon confocal microscopy. The ZrO2:Yb3+-Er3+ nanocrystals exhibited strong red emission under 970-nm excitation. Moreover, the luminescence change due to the addition of APTES molecules and biomolecules on the nanocrystals was also studied. These results demonstrate that ZrO2:Yb3+-Er3+ nanocrystals can be successfully functionalized with biomolecules to develop platforms for biolabeling and bioimaging.

O2/1 Delta/ emission in the day and night airglow of Venus

NASA Technical Reports Server (NTRS)

Connes, P.; Noxon, J. F.; Traub, W. A.; Carleton, N. P.

1979-01-01

An intense airglow from O2(1 Delta) at 1.27 microns on both the light and the dark sides of Venus has been detected by using a ground-based high-resolution Fourier-transform spectrometer. Both dayglow and nightglow are roughly 1,000 times brighter than the visible O2 nightglow found by Veneras 9 and 10 in 1975. The column emission rate of O2(1 Delta) from Venus is close to the rate at which fresh O atoms are produced from photolysis of CO2 on the day side. Formation of O2(1 Delta) is thus a major step in the removal of O atoms from the atmosphere, and dynamical processes must carry these atoms to the night side fast enough to yield a maximum density near 90 km, which is almost constant over the planet.

Observations of Terrestrial Nightglow (Meinel Bands) at King

NASA Astrophysics Data System (ADS)

Won, Young-In; Cho, Young-Min; Lee, Bang Yong; Kim, Jhoon; Chung, Jong Kyun; Kim, Yong Ha

1999-12-01

A Fourier Transform Spectrometer was used to study upper mesospheric thermodynamic by observing the hydroxyl(OH) emission. Rocket-born and satellited-born photometers place the peak emission near 87 μm. The instrument was installed in February 1999 at King Sejong station (62.22 deg S,301.25 deg E), Antarctica and has been in routine operation since then. An intensive operational effort has resulted in a substantial data between April and June, 1999. A harmonic analysis was carried out to examine information on the tidal characteristics. The measured amplitudes of the 12-hour oscillation are in the range of 2.4-3.7 K, which are in resonable agreement with theoretical model outputs. The harmonic analysis also revealed 8-hour oscillation which is not expected from the traditional theoretical studies. In addition, the observed 8-hour oscillations are apparent and sometimes dominate the temperature variation in the upper mesosphere.

A balloon-borne payload for imaging hard X-rays and gamma rays from solar flares

NASA Technical Reports Server (NTRS)

Crannell, Carol J.; Dennis, Brian R.; Orwig, Larry E.; Schmahl, Edward J.; Lang, Frederic L.; Starr, Richard; Norris, Jay P.; Greene, Michael E.; Hurford, Gordon J.; Johnson, W. N.

1991-01-01

Hard X-rays and gamma rays provide direct evidence of the roles of accelerated particles in solar flares. An approach that employs a spatial Fourier-transform technique for imaging the sources of these emissions is described, and the development of a balloon-borne imaging device based on this instrumental technique is presented. The detectors, together with the imaging optics, are sensitive to hard X-ray and gamma-ray emission in the energy-range from 20 to 700 keV. This payload, scheduled for its first flight in June 1992, will provide 11-arc second angular resolution and millisecond time resolution with a whole-sun field of view. For subsequent flights, the effective detector area can be increased by as much as a factor of four, and imaging optics with angular resolution as fine as 2 arcsec can be added to the existing gondola and metering structures.

Infrared Spectroscopy of Naphthalene Aggregation and Cluster Formation in Argon Matrices

NASA Technical Reports Server (NTRS)

Roser, J. E.; Allamondola, L. J.

2011-01-01

Fourier-transform mid-infrared absorption spectra of mixed argon/naphthalene matrices at 5 K are shown with ratios of argon-to-naphthalene that vary from 1000 to 0. These spectra show the changes as naphthalene clustering and aggregation occurs, with moderate spectral shifts affecting the C-H vibrational modes and relatively small or no shifts to the C-C and C-C-C vibrational modes. The possible contribution of homogeneous naphthalene clusters to the interstellar unidentified infrared bands is discussed. The contribution of polycyclic aromatic hydrocarbon (PAH) clusters to the 7.7 micron emission plateau and the blue shading of the 12.7 micron emission band are identified as promising candidates for future research. In addition, since PAH clusters are model components of Jupiter and Titan's atmospheres, the information presented here may also be applicable to the spectroscopy of these objects.

Near infrared bioluminescence resonance energy transfer from firefly luciferase—quantum dot bionanoconjugates

NASA Astrophysics Data System (ADS)

Alam, Rabeka; Karam, Liliana M.; Doane, Tennyson L.; Zylstra, Joshua; Fontaine, Danielle M.; Branchini, Bruce R.; Maye, Mathew M.

2014-12-01

The bioluminescence resonance energy transfer (BRET) between firefly luciferase enzymes and semiconductive quantum dots (QDs) with near infrared emission is described. The QD were phase transferred to aqueous buffers using a histidine mediated phase transfer route, and incubated with a hexahistidine tagged, green emitting variant of firefly luciferase from Photinus pyralis (PPyGRTS). The PPyGRTS were bound to the QD interface via the hexahistidine tag, which effectively displaces the histidine layer and binds directly to the QD interfaces, allowing for short donor-acceptor distances (˜5.5 nm). Due to this, high BRET efficiency ratios of ˜5 were obtained. These PPyGRTS-QD bio-nano conjugates were characterized by transmission electron microscopy, thermal gravimetric analysis, Fourier transform infrared spectroscopy and BRET emission studies. The final optimized conjugate was easily observable by night vision imaging, demonstrating the potential of these materials in imaging and signaling/sensing applications.

Luminescent properties of Ln3+ doped tellurite glasses containing AlF3

NASA Astrophysics Data System (ADS)

Walas, Michalina; Pastwa, Agata; Lewandowski, Tomasz; Synak, Anna; Gryczyński, Ignacy; Sadowski, Wojciech; Kościelska, Barbara

2016-09-01

The low-phonon energy tellurite glasses TeO2-BaO-Bi2O3 and TeO2-BaO-Bi2O3-AlF3 triply doped with Eu3+, Tb3+, Tm3+ ions in two different molar ratios were synthesized using melt-quenching technique. Their structure and luminescence properties were widely investigated by X-ray Diffraction (XRD), Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR) and Photoluminescence Spectroscopy (PL). The luminescence spectra of Eu3+, Tb3+, Tm3+ co-doped glasses show apart of the bands corresponding to the 4f-4f transitions of lanthanide ions also band corresponding to glass matrix. AlF3 doping increases emission intensity, although to improve overall emission color further studies on molar composition of samples and the molar ratio of the components should be carried out.

Study of dynamic emission spectra from lubricant films in an elastohydrodynamic contact using Fourier transform spectroscopy

NASA Technical Reports Server (NTRS)

Lauer, J. L.

1978-01-01

Infrared emission spectra were obtained through a diamond window from lubricating fluids in an operating sliding elastohydrodynamic contact and analyzed by comparison with static absorption spectra under similar pressures. Different loads, shear rates and temperatures were used. Most of the spectra exhibited polarization characteristics, indicating directional alignment of the lubricant in the EHD contact. Among the fluids studied were a "traction" fluid, an advanced ester, and their mixtures, a synthetic paraffin, a naphthenic reference fluid (N-1), both neat and containing 1 percent of p-tricresyl phosphate as an anti-wear additive, and a C-ether. Traction properties were found to be nearly proportional to mixture composition for traction fluid and ester mixtures. The anti-wear additive reduced traction and fluid temperature under low loads but increased them under higher loads, giving rise to formation of a friction polymer.

A study on the effect of chemically synthesized magnetite nanoparticles on earthworm: Eudrilus eugeniae

NASA Astrophysics Data System (ADS)

Samrot, Antony V.; Justin, C.; Padmanaban, S.; Burman, Ujjala

2017-02-01

Most look into the benefits of the nanoparticles, but keeping aside the benefits; this study focuses on the impacts of nanoparticles on living systems. Improper disposal of nanoparticles into the environment is a subject of pollution or nano-pollution which in turn affects the flora and fauna in the ecosystem, particularly soil ecosystem. Thus, this study was done to understand the impacts of chemically synthesized magnetite nanoparticles on earthworm— Eudrilus eugeniae, a soil-dependent organism which acquires food and nutrition from decaying matters. The chemically synthesized magnetite nanoparticles were characterized by UV-visible spectrophotometry, Fourier transform infrared spectroscopy and field emission scanning electron microscopy. Earthworms were allowed to interact with different concentrations of synthesized nanoparticles and the effect of the nanoparticles was analysed by studying the phenotypic changes followed by histology and inductively coupled plasma optical emission spectrometry analyses.

PRESSURE EFFECTS IN POLYCYCLIC AROMATIC NITROGENATED HETEROCYCLES (PANHs): DIAGNOSTIC QUALITIES AND COSMOBAROMETRY POTENTIAL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montgomery, Wren; Sephton, Mark A., E-mail: w.montgomery@imperial.ac.uk

2016-03-01

The influence of polycyclic aromatic nitrogen heterocycles (PANHs), which have been suggested as contributors to the interstellar IR emission bands, on interstellar emission features is difficult to constrain because their infrared characteristics are strongly similar to those for polycyclic aromatic hydrocarbons (PAHs). One possible solution is to seek a means of visualizing the presence of PANHs that provides information that is distinct from that for PAHs. Although PANHs and PAHs have similar infrared characteristics in many settings, this relationship may not be universally maintained. We have used in situ high-pressure synchrotron-source Fourier transform infrared spectroscopy to determine that the responsesmore » of two representative molecules, acridine and anthracene, differ at high pressures (>ca. 1 GPa). Because there are a number of high-pressure environments that can be remotely observed by infrared spectroscopy, they represent a potential to glimpse the distribution of PANHs across the cosmos.« less

A Discussion of the Discrete Fourier Transform Execution on a Typical Desktop PC

NASA Technical Reports Server (NTRS)

White, Michael J.

2006-01-01

This paper will discuss and compare the execution times of three examples of the Discrete Fourier Transform (DFT). The first two examples will demonstrate the direct implementation of the algorithm. In the first example, the Fourier coefficients are generated at the execution of the DFT. In the second example, the coefficients are generated prior to execution and the DFT coefficients are indexed at execution. The last example will demonstrate the Cooley- Tukey algorithm, better known as the Fast Fourier Transform. All examples were written in C executed on a PC using a Pentium 4 running at 1.7 Ghz. As a function of N, the total complex data size, the direct implementation DFT executes, as expected at order of N2 and the FFT executes at order of N log2 N. At N=16K, there is an increase in processing time beyond what is expected. This is not caused by implementation but is a consequence of the effect that machine architecture and memory hierarchy has on implementation. This paper will include a brief overview of digital signal processing, along with a discussion of contemporary work with discrete Fourier processing.

Stress wave calculations in composite plates using the fast Fourier transform.

NASA Technical Reports Server (NTRS)

Moon, F. C.

1973-01-01

The protection of composite turbine fan blades against impact forces has prompted the study of dynamic stresses in composites due to transient loads. The mathematical model treats the laminated plate as an equivalent anisotropic material. The use of Mindlin's approximate theory of crystal plates results in five two-dimensional stress waves. Three of the waves are flexural and two involve in-plane extensional strains. The initial value problem due to a transient distributed transverse force on the plate is solved using Laplace and Fourier transforms. A fast computer program for inverting the two-dimensional Fourier transform is used. Stress contours for various stresses and times after application of load are obtained for a graphite fiber-epoxy matrix composite plate. Results indicate that the points of maximum stress travel along the fiber directions.

High-speed spectral domain optical coherence tomography using non-uniform fast Fourier transform

PubMed Central

Chan, Kenny K. H.; Tang, Shuo

2010-01-01

The useful imaging range in spectral domain optical coherence tomography (SD-OCT) is often limited by the depth dependent sensitivity fall-off. Processing SD-OCT data with the non-uniform fast Fourier transform (NFFT) can improve the sensitivity fall-off at maximum depth by greater than 5dB concurrently with a 30 fold decrease in processing time compared to the fast Fourier transform with cubic spline interpolation method. NFFT can also improve local signal to noise ratio (SNR) and reduce image artifacts introduced in post-processing. Combined with parallel processing, NFFT is shown to have the ability to process up to 90k A-lines per second. High-speed SD-OCT imaging is demonstrated at camera-limited 100 frames per second on an ex-vivo squid eye. PMID:21258551

Host sensitized near-infrared emission in Nd3+ doped different alkaline-sodium-phosphate phosphors

NASA Astrophysics Data System (ADS)

Balakrishna, A.; Swart, H. C.; Kroon, R. E.; Ntwaeaborwa, O. M.

2018-04-01

Near-infrared (NIR) emitting phosphors of different alkaline based sodium-phosphate (MNa[PO4], where M = Mg, Ca, Sr and Ba were prepared by a conventional solution combustion method with fixed doping concentration of Nd3+ (1.0 mol%). The phosphors were characterized by powder X-ray diffraction, field emission scanning electron microscope, Fourier transform infrared spectroscopy, UV-vis spectroscopy and fluorescent spectrophotometry. The optical properties including reflectance, excitation and emission were investigated. The excitation spectra of the phosphors were characterized by a broadband extending from 450 to 900 nm. Upon excitation with a wavelength of 580 nm, the phosphor emits intensely infrared region at 872 nm, 1060 nm and 1325 nm which correspond to the 4F3/2 → 4I9/2, 4F3/2 → 4I11/2 and 4F3/2 → 4I13/2 transitions of Nd3+ ions and were found to vary for the different hosts. The strongest emission wavelength reaches 1060 nm. The most intense emission of Nd3+ was observed from Ca2+ incorporated host. The down conversion emissions of the material fall in the NIR region suggesting that the prepared phosphors have potential application in the development of photonic devices emitting in the NIR.

Resonant-type MEMS transducers excited by two acoustic emission simulation techniques

NASA Astrophysics Data System (ADS)

Ozevin, Didem; Greve, David W.; Oppenheim, Irving J.; Pessiki, Stephen

2004-07-01

Acoustic emission testing is a passive nondestructive testing technique used to identify the onset and characteristics of damage through the detection and analysis of transient stress waves. Successful detection and implementation of acoustic emission requires good coupling, high transducer sensitivity and ability to discriminate noise from real signals. We report here detection of simulated acoustic emission signals using a MEMS chip fabricated in the multi-user polysilicon surface micromachining (MUMPs) process. The chip includes 18 different transducers with 10 different resonant frequencies in the range of 100 kHz to 1 MHz. It was excited by two different source simulation techniques; pencil lead break and impact loading. The former simulation was accomplished by breaking 0.5 mm lead on the ceramic package. Four transducer outputs were collected simultaneously using a multi-channel oscilloscope. The impact loading was repeated for five different diameter ball bearings. Traditional acoustic emission waveform analysis methods were applied to both data sets to illustrate the identification of different source mechanisms. In addition, a sliding window Fourier transform was performed to differentiate frequencies in time-frequency-amplitude domain. The arrival and energy contents of each resonant frequency were investigated in time-magnitude plots. The advantages of the simultaneous excitation of resonant transducers on one chip are discussed and compared with broadband acoustic emission transducers.

Characterization of microwave plasma in a multicusp using 2D emission based tomography: Bessel modes and wave absorption

NASA Astrophysics Data System (ADS)

Rathore, Kavita; Bhattacharjee, Sudeep; Munshi, Prabhat

2017-06-01

A tomographic method based on the Fourier transform is used for characterizing a microwave plasma in a multicusp (MC), in order to obtain 2D distribution of plasma emissions, plasma (electron) density (Ne) and temperature (Te). The microwave plasma in the MC is characterized as a function of microwave power, gas pressure, and axial distance. The experimentally obtained 2D emission profiles show that the plasma emissions are generated in a circular ring shape. There are usually two bright rings, one at the plasma core and another near the boundary. The experimental results are validated using a numerical code that solves Maxwell's equations inside a waveguide filled with a plasma in a magnetic field, with collisions included. It is inferred that the dark and bright circular ring patterns are a result of superposition of Bessel modes (TE11 and TE21) of the wave electric field inside the plasma filled MC, which are in reasonable agreement with the plasma emission profiles. The tomographically obtained Ne and Te profiles indicate higher densities in the plasma core (˜1010 cm-3) and enhanced electron temperature in the ECR region (˜13 eV), which are in agreement with earlier results using a Langmuir probe and optical emission spectroscopy (OES) diagnostics.

The angular difference function and its application to image registration.

PubMed

Keller, Yosi; Shkolnisky, Yoel; Averbuch, Amir

2005-06-01

The estimation of large motions without prior knowledge is an important problem in image registration. In this paper, we present the angular difference function (ADF) and demonstrate its applicability to rotation estimation. The ADF of two functions is defined as the integral of their spectral difference along the radial direction. It is efficiently computed using the pseudopolar Fourier transform, which computes the discrete Fourier transform of an image on a near spherical grid. Unlike other Fourier-based registration schemes, the suggested approach does not require any interpolation. Thus, it is more accurate and significantly faster.

Application of Fourier analysis to multispectral/spatial recognition

NASA Technical Reports Server (NTRS)

Hornung, R. J.; Smith, J. A.

1973-01-01

One approach for investigating spectral response from materials is to consider spatial features of the response. This might be accomplished by considering the Fourier spectrum of the spatial response. The Fourier Transform may be used in a one-dimensional to multidimensional analysis of more than one channel of data. The two-dimensional transform represents the Fraunhofer diffraction pattern of the image in optics and has certain invariant features. Physically the diffraction pattern contains spatial features which are possibly unique to a given configuration or classification type. Different sampling strategies may be used to either enhance geometrical differences or extract additional features.

The New Physical Optics Notebook: Tutorials in Fourier Optics.

ERIC Educational Resources Information Center

Reynolds, George O.; And Others

This is a textbook of Fourier optics for the classroom or self-study. Major topics included in the 38 chapters are: Huygens' principle and Fourier transforms; image formation; optical coherence theory; coherent imaging; image analysis; coherent noise; interferometry; holography; communication theory techniques; analog optical computing; phase…

Fourier Spectroscopy: A Simple Analysis Technique

ERIC Educational Resources Information Center

Oelfke, William C.

1975-01-01

Presents a simple method of analysis in which the student can integrate, point by point, any interferogram to obtain its Fourier transform. The manual technique requires no special equipment and is based on relationships that most undergraduate physics students can derive from the Fourier integral equations. (Author/MLH)

Emissions of trace gases from Australian temperate forest fires: emission factors and dependence on modified combustion efficiency

NASA Astrophysics Data System (ADS)

Guérette, Elise-Andrée; Paton-Walsh, Clare; Desservettaz, Maximilien; Smith, Thomas E. L.; Volkova, Liubov; Weston, Christopher J.; Meyer, Carl P.

2018-03-01

We characterised trace gas emissions from Australian temperate forest fires through a mixture of open-path Fourier transform infrared (OP-FTIR) measurements and selective ion flow tube mass spectrometry (SIFT-MS) and White cell FTIR analysis of grab samples. We report emission factors for a total of 25 trace gas species measured in smoke from nine prescribed fires. We find significant dependence on modified combustion efficiency (MCE) for some species, although regional differences indicate that the use of MCE as a proxy may be limited. We also find that the fire-integrated MCE values derived from our in situ on-the-ground open-path measurements are not significantly different from those reported for airborne measurements of smoke from fires in the same ecosystem. We then compare our average emission factors to those measured for temperate forest fires elsewhere (North America) and for fires in another dominant Australian ecosystem (savanna) and find significant differences in both cases. Indeed, we find that although the emission factors of some species agree within 20 %, including those of hydrogen cyanide, ethene, methanol, formaldehyde and 1,3-butadiene, others, such as acetic acid, ethanol, monoterpenes, ammonia, acetonitrile and pyrrole, differ by a factor of 2 or more. This indicates that the use of ecosystem-specific emission factors is warranted for applications involving emissions from Australian forest fires.

Characterization of methane emissions in Los Angeles with airborne hyperspectral imaging

NASA Astrophysics Data System (ADS)

Saad, K.; Tratt, D. M.; Buckland, K. N.; Roehl, C. M.; Wennberg, P. O.; Wunch, D.

2017-12-01

As urban areas develop regulations to limit atmospheric methane (CH4), accurate quantification of anthropogenic emissions will be critical for program development and evaluation. However, relating emissions derived from process-level metadata to those determined from assimilating atmospheric observations of CH4 concentrations into models is particularly difficult. Non-methane hydrocarbons (NMHCs) can help differentiate between thermogenic and biogenic CH4 emissions, as they are primarily co-emitted with the former; however, these trace gases are subject to the same limitations as CH4. Remotely-sensed hyperspectral imaging bridges these approaches by measuring emissions plumes directly with spatial coverage on the order of 10 km2 min-1. We identify the sources of and evaluate emissions plumes measured by airborne infrared hyperspectral imagers flown over the Los Angeles (LA) metropolitan area, which encompasses various CH4 sources, including petroleum and natural gas wells and facilities. We quantify total CH4 and NMHC emissions, as well as their relative column densities, at the point-source level to create fingerprints of source types. We aggregate these analyses to estimate the range of variability in chemical composition across source types. These CH4 and NMHC emissions factors are additionally compared to their tropospheric column abundances measured by the Total Carbon Column Observing Network (TCCON) Pasadena Fourier transform infrared spectrometer, which provides a footprint for the LA basin.