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Sample records for front-illuminated photodiode array

  1. Integrated avalanche photodiode arrays

    DOEpatents

    Harmon, Eric S.

    2015-07-07

    The present disclosure includes devices for detecting photons, including avalanche photon detectors, arrays of such detectors, and circuits including such arrays. In some aspects, the detectors and arrays include a virtual beveled edge mesa structure surrounded by resistive material damaged by ion implantation and having side wall profiles that taper inwardly towards the top of the mesa structures, or towards the direction from which the ion implantation occurred. Other aspects are directed to masking and multiple implantation and/or annealing steps. Furthermore, methods for fabricating and using such devices, circuits and arrays are disclosed.

  2. Enhanced performance of reversely transferred, doubly open-ended TiO2 nanotube arrays for front-illuminated dye-sensitized solar cells

    NASA Astrophysics Data System (ADS)

    Kim, Hyunsoo; Lee, Soo-Yong; Kim, Jae-Hong; Ahn, Kwang-Soon; Kang, Soon-Hyung

    2016-01-01

    Doubly open-ended conventional TiO2 nanotube arrays (Type I) and nanoporous-layer-covered nanotube arrays (Type II) were transferred to transparent fluorine-doped tin oxides (FTOs) for front-illuminated dye-sensitized solar cells (DSSCs). FTO/Type II exhibited a long electron lifetime ( τ e ) and rapid electron transport compared to FTO/Type I because of the reduced surface defect-state-mediated recombination rate. In particular, Type II transferred reversely to the FTO (FTO/Type II-rev) had beneficial geometric effects, leading to a decrease in pore size from the bottom to the top and a nanoporous TiO2 thin bottom layer. These enabled more effective light scattering near the FTO and facilitated lateral electron movement toward the FTO, leading to a shortened electron pathway and a reduced recombination rate. The significantly enhanced electron lifetime and the shortened electron transit time of the FTO/Type II-rev improved the charge collection efficiency significantly. Furthermore, the enhanced light scattering increased the light harvesting efficiency. These beneficial geometric effects of FTO/Type II-rev contributed to the greatly enhanced overall cell efficiency (7.61%) of the DSSC compared to the DSSCs with FTO/Type I (5.27%) and FTO/Type II (6.65%).

  3. Hybrid Avalanche Photodiode Array Imaging

    NASA Astrophysics Data System (ADS)

    Aihara, Hiroaki

    A hybrid avalanche photodiode (APD) array is a vacuum tube containing a photocathode and an array of avalanche photodiodes. It is a hybrid device that combines a traditional phototube technology and an advanced semiconductor technology. A photon produces a photoelectron with quantum efficiency at the photocathode. Unlike a phototube with dynodes, multiplication of the photoelectron is provided by a bombardment of the accelerated photoelectron into the avalanche photodiode resulting in a number of electron-hole pairs and a subsequent avalanche multiplication of the secondary electrons at the pn junction of the reverse-biased diode. The resulting total gain ranging from 104 to 105 is large enough to retain a single-photon sensitivity by using low-noise amplifiers. Segmentation of the pn junction of the diode provides the position information of an incident photoelectron and enables imaging of an incident photon. We report the recent progress on R&D of a single-pixel large format hybrid APD and a multipixel hybrid APD array. A hybrid avalanche photodiode (APD) array is a vacuum tube containing a photocathode and an array of avalanche photodiodes. It is a hybrid device that combines a traditional phototube technology and an advanced semiconductor technology. A photon produces a photoelectron with quantum efficiency at the photocathode. Unlike a phototube with dynodes, multiplication of the photoelectron is provided by a bombardment of the accelerated photoelectron into the avalanche photodiode resulting in a number of electron-hole pairs and a subsequent avalanche multiplication of the secondary electrons at the pn junction of the reverse-biased diode. The resulting total gain ranging from 104 to 105 is large enough to retain a single-photon sensitivity by using low-noise amplifiers. Segmentation of the pn junction of the diode provides the position information of an incident photoelectron and enables imaging of an incident photon. We report the recent progress on R

  4. Optical Demonstrations with a Scanning Photodiode Array.

    ERIC Educational Resources Information Center

    Turman, Bobby N.

    1980-01-01

    Describes the photodiode array and the electrical connections necessary for it. Also shows a few of the optical demonstration possibilities-shadowgraphs for measuring small objects, interference and diffraction effects, angular resolution of an optical system, and a simple spectrometer. (Author/DS)

  5. Avalanche Photodiode Arrays for Optical Communications Receivers

    NASA Technical Reports Server (NTRS)

    Srinivasan, M.; Vilnrotter, V.

    2001-01-01

    An avalanche photodiode (APD) array for ground-based optical communications receivers is investigated for the reception of optical signals through the turbulent atmosphere. Kolmogorov phase screen simulations are used to generate realistic spatial distributions of the received optical field. It is shown that use of an APD array for pulse-position modulation detection can improve performance by up to 4 dB over single APD detection in the presence of turbulence, but that photon-counting detector arrays yield even greater gains.

  6. Current isolating epitaxial buffer layers for high voltage photodiode array

    DOEpatents

    Morse, Jeffrey D.; Cooper, Gregory A.

    2002-01-01

    An array of photodiodes in series on a common semi-insulating substrate has a non-conductive buffer layer between the photodiodes and the semi-insulating substrate. The buffer layer reduces current injection leakage between the photodiodes of the array and allows optical energy to be converted to high voltage electrical energy.

  7. Interference effects in reticon photodiode array detectors.

    PubMed

    Mount, G H; Sanders, R W; Brault, J W

    1992-03-01

    A detector system incorporating the Reticon RL1024S photodiode array has been constructed at the National Oceanic and Atmospheric Administration Aeronomy Laboratory as part of a double spectrograph to be used to study the Earth's atmosphere from ground-based and aircraft-based platforms. To determine accurately the abundances of atmospheric trace gases, this new system must be able to measure spectral absorptions as small as 0.02%. The detector, manufactured by EG&G Reticon, exhibits superior signal-to-noise characteristics at the light levels characteristic of scattered skylights, but interference in the passivating layer (a thin layer of SiO(2) that is deposited during the manufacture to protect the silicon active area from water vapor) causes major problems in achieving the required precision. The mechanism of the problems and the solution we have implemented are described in detail.

  8. Quality assurance using a photodiode array.

    PubMed

    Balderson, M J; Spencer, D P; Nygren, I; Brown, D W

    2011-01-31

    Improved treatment techniques in radiation therapy provide incentive to reduce treatment margins, thereby increasing the necessity for more accurate geometrical setup of the linear accelerator and accompanying components. In the present paper, we describe the development of a novel device that enables precise and automated measurement of geometric parameters for the purpose of improving initial setup accuracy, and for standardizing repeated quality control activities. The device consists of a silicon photodiode array, an evaluation board, a data acquisition card, and a laptop. Measurements that demonstrate the utility of the device are also presented. Using the device, we show that the radiation light field congruence for both 6 and 15 MV beams is within 1.3 mm. The maximum measured disagreement between radiation field edges and light field edges was 1.290 ± 0.002 mm, while the smallest disagreement between the light field and radiation field edge was 0.016 ± 0.003 mm. Because measurements are automated, ambiguities resulting from interobserver variability are removed, greatly improving the reproducibility of measurements across observers. We expect the device to find use in consistency measurements on linear accelerators used for stereotactic radiosurgery, during the commissioning of new linear accelerators, or as an alternative to film or other commercially available devices for performing monthly or annual quality control checks.

  9. Photodiode arrays having minimized cross-talk between diodes

    DOEpatents

    Guckel, Henry; McNamara, Shamus P.

    2000-10-17

    Photodiode arrays are formed with close diode-to-diode spacing and minimized cross-talk between diodes in the array by isolating the diodes from one another with trenches that are formed between the photodiodes in the array. The photodiodes are formed of spaced regions in a base layer, each spaced region having an impurity type opposite to that of the base layer to define a p-n junction between the spaced regions and the base layer. The base layer meets a substrate at a boundary, with the substrate being much more heavily doped than the base layer with the same impurity type. The trenches extend through the base layer and preferably into the substrate. Minority carriers generated by absorption of light photons in the base layer can only migrate to an adjacent photodiode through the substrate. The lifetime and the corresponding diffusion length of the minority carriers in the substrate is very short so that all minority carriers recombine in the substrate before reaching an adjacent photodiode.

  10. High-power flip-chip mounted photodiode array.

    PubMed

    Cross, Allen S; Zhou, Qiugui; Beling, Andreas; Fu, Yang; Campbell, Joe C

    2013-04-22

    Four-element modified uni-traveling-carrier (MUTC) photodiode arrays (PDA) flip-chip bonded onto transmission lines on AlN substrates are demonstrated. High RF output powers of 26.2 dBm and 21.0 dBm are achieved at 35 GHz and 48 GHz, respectively, using a PDA with 28-μm diameter photodiodes. A systematic comparison between a PDA with four 20 μm-diameter elements and a discrete detector with the same active area (40-μm diameter) is presented. The PDA achieved higher output power and thermal dissipation compared to its discrete counterpart.

  11. Photon counting photodiode array detector for far ultraviolet (FUV) astronomy

    NASA Technical Reports Server (NTRS)

    Hartig, G. F.; Moos, H. W.; Pembroke, R.; Bowers, C.

    1982-01-01

    A compact, stable, single-stage intensified photodiode array detector designed for photon-counting, far ultraviolet astronomy applications employs a saturable, 'C'-type MCP (Galileo S. MCP 25-25) to produce high gain pulses with a narrowly peaked pulse height distribution. The P-20 output phosphor exhibits a very short decay time, due to the high current density of the electron pulses. This intensifier is being coupled to a self-scanning linear photodiode array which has a fiber optic input window which allows direct, rigid mechanical coupling with minimal light loss. The array was scanned at a 250 KHz pixel rate. The detector exhibits more than adequate signal-to-noise ratio for pulse counting and event location. Previously announced in STAR as N82-19118

  12. Photon counting photodiode array detector for far ultraviolet (FUV) astronomy

    NASA Technical Reports Server (NTRS)

    Hartig, G. F.; Moos, H. W.; Pembroke, R.; Bowers, C.

    1982-01-01

    A compact, stable, single-stage intensified photodiode array detector designed for photon-counting, far ultraviolet astronomy applications employs a saturable, 'C'-type MCP (Galileo S. MCP 25-25) to produce high gain pulses with a narrowly peaked pulse height distribution. The P-20 output phosphor exhibits a very short decay time, due to the high current density of the electron pulses. This intensifier is being coupled to a self-scanning linear photodiode array which has a fiber optic input window which allows direct, rigid mechanical coupling with minimal light loss. The array was scanned at a 250 KHz pixel rate. The detector exhibits more than adequate signal-to-noise ratio for pulse counting and event location. Previously announced in STAR as N82-19118

  13. High Density HGCDTE Avalanche Photodiode Array Performance

    DTIC Science & Technology

    1999-08-01

    Laboratory for the Physical Sciences 8050 Greenmead Drive College Park, MD. 20740 W. Trussell, J. Nettleton , A. Hutchinson, and D. Barr Night Vision and...Electronic Sensors Directorate AMSEL RD NV LPD LT Ft. Belvoir, VA 22060-5806 1 This Work Supported in Part by NVESD Laser Technology Branch Contract...advantageous in the development of APD arrays for 3D LADAR imaging applications. HCT APDs show promise for laser range finders with increased range and 3D

  14. Photon-to-digital photodiode imaging array

    NASA Astrophysics Data System (ADS)

    Mandl, William J.

    2001-10-01

    MOSAD©, Multiplexed OverSample Analog to Digital conversion, is a low power on focal plane analog to digital, A/D, process that places an oversample A/D at each pixel site. Two designs for a visible light staring array were developed with this approach. One used a silicon photo diode and the other used a photo gate for detection. The array was designed with a 320 X 240 format with the pixels placed on 16 micron centers. There are a total of 76,800 A/D's on the chip. The device is a monolithic integrated circuit that includes the sensors, A/D's and readout circuitry. A production 1.2 micron CCD/CMOS process was used in it construction. The A/D uses charge well switching at the pixel to convert the accumulated analog signal to digital data. There was negligible impact on the pixel area due to the A/D such that a fill factor of 73% was achieved with front side illumination for both approaches. At 400 samples per second, measured on chip power consumption is under 10 milliwatts. Noise measurements at sample rates from 400 samples per second to 1,600 samples per second were taken for both parts. It was found that the photo gate noise performance was four times better than the photo diode. At a nominal 28 times oversample, the photo diode obtained 8 to 9 bits performance and the photo gate achieved 10 to 11 bits. Nonuniformity variation was below the noise floor. No explanation for the difference in noise performance has yet been determined. This development was sponsored by NASA under a SBIR program.

  15. ASIC Readout Circuit Architecture for Large Geiger Photodiode Arrays

    NASA Technical Reports Server (NTRS)

    Vasile, Stefan; Lipson, Jerold

    2012-01-01

    The objective of this work was to develop a new class of readout integrated circuit (ROIC) arrays to be operated with Geiger avalanche photodiode (GPD) arrays, by integrating multiple functions at the pixel level (smart-pixel or active pixel technology) in 250-nm CMOS (complementary metal oxide semiconductor) processes. In order to pack a maximum of functions within a minimum pixel size, the ROIC array is a full, custom application-specific integrated circuit (ASIC) design using a mixed-signal CMOS process with compact primitive layout cells. The ROIC array was processed to allow assembly in bump-bonding technology with photon-counting infrared detector arrays into 3-D imaging cameras (LADAR). The ROIC architecture was designed to work with either common- anode Si GPD arrays or common-cathode InGaAs GPD arrays. The current ROIC pixel design is hardwired prior to processing one of the two GPD array configurations, and it has the provision to allow soft reconfiguration to either array (to be implemented into the next ROIC array generation). The ROIC pixel architecture implements the Geiger avalanche quenching, bias, reset, and time to digital conversion (TDC) functions in full-digital design, and uses time domain over-sampling (vernier) to allow high temporal resolution at low clock rates, increased data yield, and improved utilization of the laser beam.

  16. Nonlinear Time-Variant Response in an Avalanche Photodiode Array Based Laser Detection and Ranging System

    DTIC Science & Technology

    2007-03-01

    Nonlinear Time-Variant Response in an Avalanche Photodiode Array Based Laser Detection and Ranging System THESIS Michael D. Seal, Captain, USAF AFIT...DISTRIBUTION UNLIMITED. AFIT/GEO/ENG/07-03 Nonlinear Time-Variant Response in an Avalanche Photodiode Array Based Laser Detection and Ranging System...time-variant behavior exhibited by an avalanche photodiode (APD) array based laser ranging and detec- tion (LADAR) system. This examination was

  17. Compact multispectral photodiode arrays using micropatterned dichroic filters

    NASA Astrophysics Data System (ADS)

    Chandler, Eric V.; Fish, David E.

    2014-05-01

    The next generation of multispectral instruments requires significant improvements in both spectral band customization and portability to support the widespread deployment of application-specific optical sensors. The benefits of spectroscopy are well established for numerous applications including biomedical instrumentation, industrial sorting and sensing, chemical detection, and environmental monitoring. In this paper, spectroscopic (and by extension hyperspectral) and multispectral measurements are considered. The technology, tradeoffs, and application fits of each are evaluated. In the majority of applications, monitoring 4-8 targeted spectral bands of optimized wavelength and bandwidth provides the necessary spectral contrast and correlation. An innovative approach integrates precision spectral filters at the photodetector level to enable smaller sensors, simplify optical designs, and reduce device integration costs. This method supports user-defined spectral bands to create application-specific sensors in a small footprint with scalable cost efficiencies. A range of design configurations, filter options and combinations are presented together with typical applications ranging from basic multi-band detection to stringent multi-channel fluorescence measurement. An example implementation packages 8 narrowband silicon photodiodes into a 9x9mm ceramic LCC (leadless chip carrier) footprint. This package is designed for multispectral applications ranging from portable color monitors to purpose- built OEM industrial and scientific instruments. Use of an eight-channel multispectral photodiode array typically eliminates 10-20 components from a device bill-of-materials (BOM), streamlining the optical path and shrinking the footprint by 50% or more. A stepwise design approach for multispectral sensors is discussed - including spectral band definition, optical design tradeoffs and constraints, and device integration from prototype through scalable volume production

  18. Nano-Multiplication-Region Avalanche Photodiodes and Arrays

    NASA Technical Reports Server (NTRS)

    Zheng, Xinyu; Pain, Bedabrata; Cunningham, Thomas

    2008-01-01

    Nano-multiplication-region avalanche photodiodes (NAPDs), and imaging arrays of NAPDs integrated with complementary metal oxide/semiconductor (CMOS) active-pixel-sensor integrated circuitry, are being developed for applications in which there are requirements for high-sensitivity (including photoncounting) detection and imaging at wavelengths from about 250 to 950 nm. With respect to sensitivity and to such other characteristics as speed, geometric array format, radiation hardness, power demand of associated circuitry, size, weight, and robustness, NAPDs and arrays thereof are expected to be superior to prior photodetectors and arrays including CMOS active-pixel sensors (APSs), charge-coupled devices (CCDs), traditional APDs, and microchannelplate/ CCD combinations. Figure 1 depicts a conceptual NAPD array, integrated with APS circuitry, fabricated on a thick silicon-on-insulator wafer (SOI). Figure 2 presents selected aspects of the structure of a typical single pixel, which would include a metal oxide/semiconductor field-effect transistor (MOSFET) integrated with the NAPD. The NAPDs would reside in silicon islands formed on the buried oxide (BOX) layer of the SOI wafer. The silicon islands would be surrounded by oxide-filled insulation trenches, which, together with the BOX layer, would constitute an oxide embedding structure. There would be two kinds of silicon islands: NAPD islands for the NAPDs and MOSFET islands for in-pixel and global CMOS circuits. Typically, the silicon islands would be made between 5 and 10 m thick, but, if necessary, the thickness could be chosen outside this range. The side walls of the silicon islands would be heavily doped with electron-acceptor impurities (p+-doped) to form anodes for the photodiodes and guard layers for the MOSFETs. A nanoscale reach-through structure at the front (top in the figures) central position of each NAPD island would contain the APD multiplication region. Typically, the reach-through structure would be

  19. Nano-multiplication region avalanche photodiodes and arrays

    NASA Technical Reports Server (NTRS)

    Zheng, Xinyu (Inventor); Pain, Bedabrata (Inventor); Cunningham, Thomas J. (Inventor)

    2011-01-01

    An avalanche photodiode with a nano-scale reach-through structure comprising n-doped and p-doped regions, formed on a silicon island on an insulator, so that the avalanche photodiode may be electrically isolated from other circuitry on other silicon islands on the same silicon chip as the avalanche photodiode. For some embodiments, multiplied holes generated by an avalanche reduces the electric field in the depletion region of the n-doped and p-doped regions to bring about self-quenching of the avalanche photodiode. Other embodiments are described and claimed.

  20. Measurement of Radiation - Light Field Congruence using a Photodiode Array

    NASA Astrophysics Data System (ADS)

    Balderson, Michael J.

    Improved treatment techniques in radiation therapy provide incentive to reduce treatment margins, thereby increasing the necessity for more accurate geometrical setup of the linear accelerator and accompanying components. In this thesis, we describe the development of a novel device that enables precise and automated measurement of radiation-light field congruence of medical linear accelerators for the purpose of improving setup accuracy, and standardizing repeated quality control activities. The device consists of a silicon photodiode array, an evaluation board, a data acquisition card, and a laptop. Using the device, we show that the radiation-light field congruence for both 6 and 15 MV beams is within 2 mm on a Varian Clinac 21 EX medical linear accelerator. Because measurements are automated, ambiguities resulting from observer variability are removed, greatly improving the reproducibility of measurements over time and across observers. We expect the device to be useful in providing consistent measurements on linear accelerators used for stereotactic radiosurgery, during the commissioning of new linear accelerators, and as an alternative to film or other commercially available devices for performing monthly or annual quality control checks.

  1. Interdigitated microelectrode array-coupled bipolar semiconductor photodiode array (IMEA-PDA) microchip for on-chip electrochemiluminescence detection.

    PubMed

    Pal, Sukdeb; Kim, Min Jung; Tak, Yu Kyung; Kwon, Ho Taik; Song, Joon Myong

    2009-10-01

    This paper reports the design, fabrication and testing of a microchip wherein interdigitated microelectrode arrays (IMEA) were integrated with bipolar semiconductor photodiode array (PDA) chip to fabricate a highly compact embodiment for on-chip handling of solutions and electrochemiluminescence (ECL) detection. A 12 x 12 micro array of photodiodes, each coupled with an interdigitated microelectrode array (IMEA), an array of current amplifiers, and a photodiode element-addressing circuit were integrated into a single 2 x 2 cm² IC chip. Each photodiode had dimensions of 300 x 300 μm² and the photodiode-to-photodiode distance was 100 μm. The chip was successfully applied to the on-chip quantification of electro-chemiluminescing probe-labeled single stranded oligonucleotides. The minimum detectable limit at signal/noise ≥ 3 was found to be 5 x 10⁻¹⁴ moles of oligonucleotides with a sample volume as low as 5 microl (i.e., 10 fmole/μl). The attractive features of the developed IMEA-PDA microchip are that a plurality of samples can be analyzed simultaneously using a chip and that for a given sample the data can be averaged from values obtained from multiple, individually addressed pixels. These in turn bring in speed and statistical confidence in analysis. The IMEA-PDA microchip system has the potential to be used as a versatile and highly compact chemical analysis tool for chemical sensing and metrology applications.

  2. X-ray imaging sensor arrays on foil using solution processed organic photodiodes and organic transistors

    NASA Astrophysics Data System (ADS)

    Kumar, Abhishek; Moet, Date; van der Steen, Jan-Laurens; Tripathi, Ashutosh; Rodriguez, Francisco G.; Maas, Joris; Simon, Matthias; Reutten, Walter; Douglas, Alexander; Raaijmakers, Rob; Malinowski, Pawel E.; Myny, Kris; Shafique, Umar; Andriessen, Ronn; Heremans, Paul; Gelinck, Gerwin

    2014-05-01

    We demonstrate organic imaging sensor arrays fabricated on flexible plastic foil with the solution processing route for both photodiodes and thin film transistors. We used the photovoltaic P3HT:PCBM blend for fabricating the photodiodes using spin coating and pentacene as semiconductor material for the TFTs. Photodiodes fabricated with P3HT:PCBM absorb in the green part of the visible spectrum which matches with the typical scintillator output wavelength. The arrays consist of 32x32 pixels with variation in pixel resolution of 200μmx200μm, 300μmx300μm and of 1mmx1mm. The accurate reproducibility of shadow images of the objects demonstrates the potential of these arrays for imaging purposes. We also demonstrate that the crosstalk is relatively insignificant despite the fact that the active photodiode forms a continuous layer in the array. Since both photodiodes and TFTs are made of organic material, they are processed at low temperatures below 150°C on foil which means that these imaging sensors can be flexible, light weight and low cost when compared to conventional amorphous silicon based imaging sensors on rigid substrates. In combination with a scintillator on top of the arrays, we show the potential of these arrays for the X-ray imaging applications.

  3. Development of Fuses for Protection of Geiger-Mode Avalanche Photodiode Arrays

    NASA Astrophysics Data System (ADS)

    Grzesik, Michael; Bailey, Robert; Mahan, Joe; Ampe, Jim

    2015-11-01

    Current-limiting fuses composed of Ti/Al/Ni were developed for use in Geiger-mode avalanche photodiode arrays for each individual pixel in the array. The fuses were designed to burn out at ˜4.5 × 10-3 A and maintain post-burnout leakage currents less than 10-7 A at 70 V sustained for several minutes. Experimental fuse data are presented and successful incorporation of the fuses into a 256 × 64 pixel InP-based Geiger-mode avalanche photodiode array is reported.

  4. 64-element photodiode array for scintillation detection of x-rays

    NASA Astrophysics Data System (ADS)

    Wegrzecki, Maciej; Wolski, Dariusz; Bar, Jan; Budzyński, Tadeusz; Chłopik, Arkadiusz; Grabiec, Piotr; Kłos, Helena; Panas, Andrzej; Piotrowski, Tadeusz; Słysz, Wojciech; Stolarski, Maciej; Szmigiel, Dariusz; Wegrzecka, Iwona; Zaborowski, Michał

    2014-08-01

    The paper presents the design, technology and parameters of a new, silicon 64-element linear photodiode array developed at the Institute of Electron Technology (ITE) for the detection of scintillations emitted by CsI scintillators (λ≈550 nm). The arrays are used in a device for examining the content of containers at border crossings under development at the National Centre for Nuclear Research. Two arrays connected with a scintillator block (128 CsI scintillators) form a 128-channel detection module. The array consists of 64 epiplanar photodiode structures (5.1 × 7.2 mm) and a 5.3 mm module. p+-ν-n+ photodiode structures are optimised for the detection of radiation of λ≈ 550 nm wavelength with no voltage applied (photovoltaic mode). The structures are mounted on an epoxy-glass laminate substrate, copper-clad on both sides, on which connections with a common anode and separate cathode leads are located. The photosensitive surface of photodiodes is covered with a special silicone gel, which protects photodiodes against the mechanical impact of scintillators

  5. Surface plasmon resonance imaging biosensor based on silicon photodiode array

    NASA Astrophysics Data System (ADS)

    Yin, Shaoyun; Sun, Xiuhui; Deng, Qiling; Xia, Liangping; Du, Chunlei

    2010-11-01

    The detection limit of surface plasmon resonance imaging (SPRI) biosensor is constrained in part by the SPR biochip and in part by the resolution of the optical intensity of detecting instruments. In this paper, silicon photodiode is proposed as the optical intensity detecting element instead of the traditionally used charge coupled device (CCD), combining with high resolution analog/digital converter, this method can efficiently reduce the cost and increase the sensitivity of the SPRI system while keeping its virtue of multiple channels real time detecting. Based on this method, An SPRI experimental system with two channels is designed and the optical intensity of each channel is detected by a photodiode. By carrying out testing experiments using sucrose solution with different concentrations (corresponding to different refractive index), the system sensitivity of 10-6 refractive index unit (RIU) is obtained.

  6. Fast, Deep-Record-Length, Fiber-Coupled Photodiode Imaging Array for Plasma Diagnostics

    NASA Astrophysics Data System (ADS)

    Brockington, Samuel; Case, Andrew; Witherspoon, F. Douglas

    2014-10-01

    HyperV Technologies has been developing an imaging diagnostic comprised of an array of fast, low-cost, long-record-length, fiber-optically-coupled photodiode channels to investigate plasma dynamics and other fast, bright events. By coupling an imaging fiber bundle to a bank of amplified photodiode channels, imagers and streak imagers of 100 to 1000 pixels can be constructed. By interfacing analog photodiode systems directly to commercial analog-to-digital converters and modern memory chips, a prototype 100 pixel array with an extremely deep record length (128 k points at 20 Msamples/s) and 10 bit pixel resolution has already been achieved. HyperV now seeks to extend these techniques to construct a prototype 1000 Pixel framing camera with up to 100 Msamples/sec rate and 10 to 12 bit depth. Preliminary experimental results as well as Phase 2 plans will be discussed. Work supported by USDOE Phase 2 SBIR Grant DE-SC0009492.

  7. Geiger-Mode Avalanche Photodiode Arrays Integrated to All-Digital CMOS Circuits.

    PubMed

    Aull, Brian

    2016-04-08

    This article reviews MIT Lincoln Laboratory's work over the past 20 years to develop photon-sensitive image sensors based on arrays of silicon Geiger-mode avalanche photodiodes. Integration of these detectors to all-digital CMOS readout circuits enable exquisitely sensitive solid-state imagers for lidar, wavefront sensing, and passive imaging.

  8. Geiger-Mode Avalanche Photodiode Arrays Integrated to All-Digital CMOS Circuits

    PubMed Central

    Aull, Brian

    2016-01-01

    This article reviews MIT Lincoln Laboratory's work over the past 20 years to develop photon-sensitive image sensors based on arrays of silicon Geiger-mode avalanche photodiodes. Integration of these detectors to all-digital CMOS readout circuits enable exquisitely sensitive solid-state imagers for lidar, wavefront sensing, and passive imaging. PMID:27070609

  9. Fast, Deep-Record-Length, Fiber-Coupled Photodiode Imaging Array for Plasma Diagnostics

    NASA Astrophysics Data System (ADS)

    Brockington, Samuel; Case, Andrew; Witherspoon, F. Douglas

    2015-11-01

    HyperV Technologies has been developing an imaging diagnostic comprised of an array of fast, low-cost, long-record-length, fiber-optically-coupled photodiode channels to investigate plasma dynamics and other fast, bright events. By coupling an imaging fiber bundle to a bank of amplified photodiode channels, imagers and streak imagers can be constructed. By interfacing analog photodiode systems directly to commercial analog-to-digital converters and modern memory chips, a scalable solution for 100 to 1000 pixel systems with 14 bit resolution and record-lengths of 128k frames has been developed. HyperV is applying these techniques to construct a prototype 1000 Pixel framing camera with up to 100 Msamples/sec rate and 10 to 14 bit depth. Preliminary experimental results as well as future plans will be discussed. Work supported by USDOE Phase 2 SBIR Grant DE-SC0009492.

  10. A photon-counting photodiode array detector for far ultraviolet (FUV) astronomy

    NASA Technical Reports Server (NTRS)

    Hartig, G. F.; Moos, H. W.; Pembroke, R.; Bowers, C.

    1982-01-01

    A compact, stable, single-stage intensified photodiode array detector designed for photon-counting, far ultraviolet astronomy applications employs a saturable, 'C'-type MCP (Galileo S. MCP 25-25) to produce high gain pulses with a narrowly peaked pulse height distribution. The P-20 output phosphor exhibits a very short decay time, due to the high current density of the electron pulses. This intensifier is being coupled to a self-scanning linear photodiode array which has a fiber optic input window which allows direct, rigid mechanical coupling with minimal light loss. The array was scanned at a 250 KHz pixel rate. The detector exhibits more than adequate signal-to-noise ratio for pulse counting and event location.

  11. Application of a silicon photodiode array for solar edge tracking in the Halogen Occultation Experiment

    NASA Technical Reports Server (NTRS)

    Mauldin, L. E., III; Moore, A. S.; Stump, C. S.; Mayo, L. S.

    1985-01-01

    The optical and electronic design of the Halogen Occultation Experiment (HALOE) elevation sunsensor is described. This system uses a Galilean telescope to form a solar image on a linear silicon photodiode array. The array is a self-scanned, monolithic charge coupled device. The addresses of both solar edges imaged on the array are used by the control/pointing system to scan the HALOE science instantaneous-field-of-view (IFOV) across the vertical solar diameter during instrument calibration, and then maintain the science IFOV four arcmin below the top edge during the science data occultation event. Vertical resolution of 16 arcsec and a radiometric dynamic range of 100 are achieved at the 0.7 micrometer operating wavelength. The design provides for loss of individual photodiode elements without loss of angular tracking capability. The HALOE instrument is a gas correlation radiometer that is now being developed by NASA Langley Research Center for the Upper Atmospheric Research Satellite.

  12. Application of a silicon photodiode array for solar edge tracking in the Halogen Occultation Experiment

    NASA Technical Reports Server (NTRS)

    Mauldin, L. E., III; Moore, A. S.; Stump, C. S.; Mayo, L. S.

    1985-01-01

    The optical and electronic design of the Halogen Occultation Experiment (HALOE) elevation sunsensor is described. This system uses a Galilean telescope to form a solar image on a linear silicon photodiode array. The array is a self-scanned, monolithic charge coupled device. The addresses of both solar edges imaged on the array are used by the control/pointing system to scan the HALOE science instantaneous-field-of-view (IFOV) across the vertical solar diameter during instrument calibration, and then maintain the science IFOV four arcmin below the top edge during the science data occultation event. Vertical resolution of 16 arcsec and a radiometric dynamic range of 100 are achieved at the 0.7 micrometer operating wavelength. The design provides for loss of individual photodiode elements without loss of angular tracking capability. The HALOE instrument is a gas correlation radiometer that is now being developed by NASA Langley Research Center for the Upper Atmospheric Research Satellite.

  13. Integrated organic optical sensor arrays based on ring-shaped organic photodiodes

    NASA Astrophysics Data System (ADS)

    Sagmeister, Martin; Lamprecht, Bernhard; Kraker, Elke; Haase, Anja; Jakopic, Georg; Köstler, Stefan; Ditlbacher, Harald; Galler, Nicole; Abel, Tobias; Mayr, Torsten

    2011-10-01

    We present an integrated optical sensor platform suitable for the parallel detection of multiple parameters in an array format. This sensor technology combines fluorescent sensor layers with ring-shaped thin-film organic photodiodes (OPDs), serving as integrated fluorescence detectors. The sensing layers are deposited by screen-printing on the upper side of a PET substrate, which is exposed to an analyte, whereas the ring-shaped photodiodes are monolithically integrated, by vapour phase deposition, on the backside of the transparent substrate, in correct alignment to the sensing layers. The monolithic integration of sensor layers and detectors on one common substrate as well as the special ring shaped form of the photodiodes guarantees that a maximum of the fluorescent light emitted from the sensor layers is collected. A key advantage of the above described sensor geometry is the straightforward potential to realise sensor arrays for the parallel detection of multiple parameters: different sensor spots are illuminated by commercial LEDs or alternatively with one large area OLED, and are read-out by individual integrated organic photodiodes, surrounding the respective sensor layers. Three different sensing principles including absorption, fluorescence and surface plasmon resonance can be applied in the same basic sensor platform. The functionality of the concept is demonstrated by an integrated oxygen sensor. Sensor schemes for the analytical parameters carbon dioxide, temperature and ammonia, are proposed. Efficient front end electronics enabling intensity and time domain detection of sensor signals for the testing and characterisation of the integrated sensor devices have been developed.

  14. Large Format Geiger Mode Avalanche Photodiode Arrays and Readout Circuits

    DTIC Science & Technology

    2017-06-01

    a detector wafer with a transparent substrate; the arrays can therefore be bump bonded to CMOS readouts by the same process used for InP- based... bump bond to a more advanced 3D integration requires heterogeneous integration technique. We have demonstrated wafer bonding of InP detector arrays...digital CMOS readout circuits using bump bonding or 3D integration techniques. Silicon is the material of choice for ultraviolet, visible, and near

  15. Characterization of InGaAs avalanche photodiode arrays with varying geometries for free-space optical communication

    NASA Astrophysics Data System (ADS)

    Ferraro, Mike S.; Burris, Harris R.; Mahon, Rita; Rabinovich, William S.; Freeman, Wade T.; Murphy, James L.; Goetz, Peter G.; Moore, Christopher I.; Thomas, Linda M.; Clark, William R.; Waters, William D.; Vaccaro, Kenneth; Krejca, Brian D.

    2012-06-01

    Photodiode arrays are instrumental in providing pointing and tracking information for free space optical communication systems. Recent advances in the fabrication and development of low noise, high bandwidth avalanche photodiode (APD) arrays have enabled these devices to be used not only as position sensitive detectors (PSD) for tracking but also as communications receivers. In a collaborative effort with Optogration, Inc., the U.S. Naval Research Laboratory has developed avalanche photodiode arrays with three different geometries: a 3x3 square pixel array, a centered hexagonal pixel array, and a 5 pixel concentric array configuration with a center pixel and four periphery pixels. The characterization and performance of each array geometry will be described along with associated front-end and digital electronics. Design tradeoffs for maximizing the performance of a given array geometry will also be discussed.

  16. Self-scanned photodiode array - High performance operation in high dispersion astronomical spectrophotometry

    NASA Technical Reports Server (NTRS)

    Vogt, S. S.; Tull, R. G.; Kelton, P.

    1978-01-01

    A multichannel spectrophotometric detector system has been developed using a 1024 element self-scanned silicon photodiode array, which is now in routine operation with the high-dispersion coude spectrograph of the University of Texas McDonald Observatory 2.7-m telescope. Operational considerations in the use of such arrays for high precision and low light level spectrophotometry are discussed. A detailed description of the system is presented. Performance of the detector as measured in the laboratory and on astronomical program objects is described, and it is shown that these arrays are highly effective detectors for high dispersion astronomical spectroscopy.

  17. An InN/InGaN/GaN nanowire array guided wave photodiode on silicon

    NASA Astrophysics Data System (ADS)

    Hazari, Arnab; Zunaid Baten, Md.; Yan, Lifan; Millunchick, Joanna M.; Bhattacharya, Pallab

    2016-11-01

    The III-nitride nanowire heterostructure arrays with multiple InN disk light absorbing regions have been grown by plasma-assisted molecular beam epitaxy on (001)Si substrates, and guided wave photodiodes have been fabricated and characterized. The spectral photocurrent of the devices has been measured under reverse bias, and the data exhibit distinct shoulders in the range of 0.69-3.2 eV (0.39-1.8 μm). The estimated responsivity at a wavelength of 1.3 μm is 0.2 A/W. The nanowire photodiode response was also measured with an excitation at one facet provided by an edge-emitting laser fabricated with the same nanowire array and emitting at 1.3 μm.

  18. Silicon Geiger-mode avalanche photodiode arrays for photon-starved imaging

    NASA Astrophysics Data System (ADS)

    Aull, Brian F.

    2015-05-01

    Geiger-mode avalanche photodiodes (GMAPDs) are capable of detecting single photons. They can be operated to directly trigger all-digital circuits, so that detection events are digitally counted or time stamped in each pixel. An imager based on an array of GMAPDs therefore has zero readout noise, enabling quantum-limited sensitivity for photon-starved imaging applications. In this review, we discuss devices developed for 3D imaging, wavefront sensing, and passive imaging.

  19. Vacuum photodiode detector array for broadband UV detection in a tokamak plasma.

    PubMed

    Zweben, S J; Menyuk, C R; Taylor, R J

    1979-08-01

    An array of vacuum photodiode detectors has been used to monitor discharge equilibrium, stability, and cleanliness in the Macrotor tokamak. These detectors use the photoelectric effect on small tungsten plates to measure UV emission in the band lambda approximately 200-1200 angstroms, and so are sensitive mainly to impurity line radiation in Macrotor. The response of this system to controlled impurity contamination experiments and to disruptions is described. The design, construction, and background problems associated with these detectors are discussed in detail.

  20. Performance of a PET detector module utilizing an array of silicon photodiodes to identify the crystal of interaction

    SciTech Connect

    Moses, W.W.; Derenzo, S.E. ); Nutt, R.; Digby, W.M.; Williams, C.W.; Andreaco, M. )

    1992-11-01

    We present initial performance results for a new multi-layer PET detector module consisting of an array of 3 mm square by 30 mm deep BGO crystals coupled on one end to a single photomultiplier tube and on the opposite end to an array of 3 mm square silicon photodiodes. The photomultiplier tube provides an accurate timing pulse and energy discrimination for the all the crystals in the module, while the silicon photodiodes identify the crystal of interaction. When a single BGO crystal at +25[degree]C is excited with 511 key photons, we measure a photodiode signal centered at 700 electrons (e[sup [minus

  1. 16-element photodiode array for the angular microdeflection detector and for stabilization of a laser radiation direction

    NASA Astrophysics Data System (ADS)

    Wegrzecki, Maciej; Piotrowski, Tadeusz; Bar, Jan; Dobrowolski, Rafał; Klimov, Andrii; Klos, Helena; Marchewka, Michał; Nieprzecki, Marek; Panas, Andrzej; Prokaryn, Piotr; Seredyński, Bartłomiej; Sierakowski, Andrzej; Słysz, Wojciech; Szmigiel, Dariusz; Zaborowski, Michal

    2016-12-01

    In this paper, the design and technology of two types of 16-element photodiode arrays is described. The arrays were developed by the ITE and are to be used in detection of microdeflection of laser radiation at the Institute of Metrology and Biomedical Engineering in the Faculty of Mechatronics of Warsaw University of Technology. The electrical and photoelectrical parameters of the arrays are presented.

  2. Bright Spots: UV Measurements Using a Vacuum Photodiode Array

    NASA Astrophysics Data System (ADS)

    Perkins, Rory; Bellan, Paul

    2010-11-01

    Solar coronal loops typically erupt abruptly after long quiescent periods. Such eruptions might be initiated by interactions between adjacent loops; this possibility was explored in a laboratory experiment where two plasma-filled flux tubes merge in either a co-or counter-helicity arrangement (J.F. Hansen, S.K.P. Tripathi, and P.M. Bellan, Phys. Plasma 2, 3177(2004)). The latter arrangement produces a bright region with enhanced soft x-ray emission. We investigate such mergings with a new array of EUV photo-detectors (based on S.J. Zweben, R.J. Taylor, Plasma Physics, Vol. 23, No. 4(1981)) that provides spatially and temporally resolved measurements of radiation between 10 and 120 nm. The detector boasts a sub-microsecond rise-time and provides a large signal without amplification. The detector is shielded from the charged particle background by permanent magnets. A novel two-step scheme diverts RF ground loop currents and greatly improves the signal-to-noise ratio.

  3. Development of a testbed for flexible a-Si:H photodiode sensing arrays

    NASA Astrophysics Data System (ADS)

    Dominguez, Alfonso; Kunnen, George; Vetrano, Michael; Smith, Joseph; Marrs, Michael; Allee, David R.

    2013-05-01

    Large area, flexible sensing arrays for imaging, biochemical sensing and radiation detection are now possible with the development of flexible active matrix display technology. In particular, large-area flexible imaging arrays can provide considerable advancement in defense and security industries because of their inherent low manufacturing costs and physical plasticity that allows for increased adaptability to non-planar mounting surfaces. For example, a flexible array of photodetectors and lenslets formed into a cylinder could image simultaneously with a 360 degree view without the need for expensive bulky optics or a gimbaled mount. Here we report the design and development of a scalable 16x16 pixel testbed for flexible sensor arrays using commercial-off-the-shelf (COTS) parts and demonstrate the capture of a shadow image with an array of photodiodes and active pixel sensors on a plastic substrate. The image capture system makes use of an array of low-noise, InGaZnO active pixel amplifiers to detect changes in current in 2.4 μm-thick reverse-biased a-Si:H PIN diodes. A thorough characterization of the responsivity, detectivity, and optical gain of an a- Si:H photodiode is also provided. At the back end, analog capture circuitry progressively scans the array and constructs an image based on the electrical activity in each pixel. The use of correlated-double-sampling to remove fixed pattern noise is shown to significantly improve spatial resolution due to process variations. The testbed can be readily adapted for the development of neutron, alpha-particle, or X-ray detection arrays given an appropriate conversion layer.

  4. Linear array of photodiodes to track a human speaker for video recording

    NASA Astrophysics Data System (ADS)

    DeTone, D.; Neal, H.; Lougheed, R.

    2012-12-01

    Communication and collaboration using stored digital media has garnered more interest by many areas of business, government and education in recent years. This is due primarily to improvements in the quality of cameras and speed of computers. An advantage of digital media is that it can serve as an effective alternative when physical interaction is not possible. Video recordings that allow for viewers to discern a presenter's facial features, lips and hand motions are more effective than videos that do not. To attain this, one must maintain a video capture in which the speaker occupies a significant portion of the captured pixels. However, camera operators are costly, and often do an imperfect job of tracking presenters in unrehearsed situations. This creates motivation for a robust, automated system that directs a video camera to follow a presenter as he or she walks anywhere in the front of a lecture hall or large conference room. Such a system is presented. The system consists of a commercial, off-the-shelf pan/tilt/zoom (PTZ) color video camera, a necklace of infrared LEDs and a linear photodiode array detector. Electronic output from the photodiode array is processed to generate the location of the LED necklace, which is worn by a human speaker. The computer controls the video camera movements to record video of the speaker. The speaker's vertical position and depth are assumed to remain relatively constant- the video camera is sent only panning (horizontal) movement commands. The LED necklace is flashed at 70Hz at a 50% duty cycle to provide noise-filtering capability. The benefit to using a photodiode array versus a standard video camera is its higher frame rate (4kHz vs. 60Hz). The higher frame rate allows for the filtering of infrared noise such as sunlight and indoor lighting-a capability absent from other tracking technologies. The system has been tested in a large lecture hall and is shown to be effective.

  5. InAlAs/InGaAs avalanche photodiode arrays for free space optical communication.

    PubMed

    Ferraro, Mike S; Clark, William R; Rabinovich, William S; Mahon, Rita; Murphy, James L; Goetz, Peter G; Thomas, Linda M; Burris, Harris R; Moore, Christopher I; Waters, William D; Vaccaro, Kenneth; Krejca, Brian D

    2015-11-01

    In free space optical communication, photodetectors serve not only as communications receivers but also as position sensitive detectors (PSDs) for pointing, tracking, and stabilization. Typically, two separate detectors are utilized to perform these tasks, but recent advances in the fabrication and development of large-area, low-noise avalanche photodiode (APD) arrays have enabled these devices to be used both as PSDs and as communications receivers. This combined functionality allows for more flexibility and simplicity in optical system design without sacrificing the sensitivity and bandwidth performance of smaller, single-element data receivers. This work presents the development of APD arrays rated for bandwidths beyond 1 GHz with measured carrier ionization ratios of approximately 0.2 at moderate APD gains. We discuss the fabrication and characterization of three types of APD arrays along with their performance as high-speed photodetectors.

  6. A Geiger-mode avalanche photodiode array for X-ray photon correlation spectroscopy.

    PubMed

    Johnson, I; Sadygov, Z; Bunk, O; Menzel, A; Pfeiffer, F; Renker, D

    2009-01-01

    X-ray photon correlation spectroscopy (XPCS) provides an opportunity to study the dynamics of systems by measuring the temporal fluctuations in a far-field diffraction pattern. A two-dimensional detector system has been developed to investigate fluctuations in the frequency range of several Hz to kHz. The X-ray detector system consists of a thin 100 microm scintillation crystal coupled to a Geiger-mode avalanche photodiode array. In this article the elements of the system are detailed and the detector for XPCS measurements is demonstrated.

  7. Large-Format AlGaN PIN Photodiode Arrays for UV Images

    NASA Technical Reports Server (NTRS)

    Aslam, Shahid; Franz, David

    2010-01-01

    A large-format hybridized AlGaN photodiode array with an adjustable bandwidth features stray-light control, ultralow dark-current noise to reduce cooling requirements, and much higher radiation tolerance than previous technologies. This technology reduces the size, mass, power, and cost of future ultraviolet (UV) detection instruments by using lightweight, low-voltage AlGaN detectors in a hybrid detector/multiplexer configuration. The solar-blind feature eliminates the need for additional visible light rejection and reduces the sensitivity of the system to stray light that can contaminate observations.

  8. Performance of a process, near infrared, photo-diode array based instrument for hydrocarbon fuels analysis

    SciTech Connect

    Workman, J. Jr; McDermott, L.

    1995-12-31

    The use of a 1024 element silicon photodiode-array (PDA) detector for the design of analytical spectrophotometers has been proposed since the early 1970s. The practical implementation of this technology did not occur for another decade. Traditional problems associated with interferometer-and moving dispersive grating based systems arise from mechanical misalignment and wear of critical moving parts with time. PDA technology represents the potential of increased measurement longevity due to a fixed grating and detector assembly. The purpose of this paper is to delineate the particulars of design and performance characteristics associated with using PDA-based spectrophotometer for hydrocarbon fuels analysis.

  9. Performance of a PET detector module utilizing an array of silicon photodiodes to identify the crystal of interaction

    SciTech Connect

    Moses, W.W.; Derenzo, S.E.; Nutt, R.; Digby, W.M.; Williams, C.W.; Andreaco, M.

    1992-11-01

    We present initial performance results for a new multi-layer PET detector module consisting of an array of 3 mm square by 30 mm deep BGO crystals coupled on one end to a single photomultiplier tube and on the opposite end to an array of 3 mm square silicon photodiodes. The photomultiplier tube provides an accurate timing pulse and energy discrimination for the all the crystals in the module, while the silicon photodiodes identify the crystal of interaction. When a single BGO crystal at +25{degree}C is excited with 511 key photons, we measure a photodiode signal centered at 700 electrons (e{sup {minus}}) with noise of 375 e{sup {minus}} fwhm. When a four crystal / photodiode module is excited with a collimated line source of 511 key photons, the crystal of interaction is correctly identified 82% of the time. The misidentification rate can be greatly reduced and an 8{times}8 crystal / photodiode module constructed by using thicker depletion layer photodiodes or cooling to 0{degrees}C.

  10. Application of HPLC with photodiode array detection for systematic toxicological analyses of drug groups.

    PubMed

    Balíková, M

    1994-01-01

    During four years experience high performance liquid chromatography (HPLC) with photodiode array detection has been proved to be the demanded method of systematic toxicological analysis (STA) for unknown drugs in biological sample because of separation efficiency, sensitivity, flexibility and identification potential. HPLC can be an easy way of quantitation as well. Ultraviolet spectra acquired with Waters 990+ photodiode array detector together with retention data are used to identify unknown or suspected drugs and metabolites in various biological material often after basic TLC examination of urine. At present spectrum library used for comparison involves 180 spectra of standards in acid and neutral media. Various sample preparation procedures have been tested and till now eight isocratic liquid chromatographic systems have been used routinely for sensitive screening in small samples, identification and/or quantitative assays of drug groups. These analytical systems are suitable for toxicological examinations of forensic cases, acute poisonings, drug abuse. They are convenient to subsequent monitoring of serum drug levels during treatment of an intoxication as well.

  11. A 16-channel avalanche photodiode detector array for visible and near-infrared flow cytometry

    NASA Astrophysics Data System (ADS)

    Lawrence, William G.; Stapels, Christopher; Farrell, Richard; Tario, Joseph D., Jr.; Podniesinski, Edward; Wallace, Paul K.; Christian, James F.

    2006-02-01

    We report on the development and application of a flow cytometer using a 16-channel avalanche photodiode (APD) linear detector array. The array is configured with a dispersive grating to simultaneously record emission over a broad wavelength range using the 16 APD channels of the linear APD array. The APD detector elements have a peak quantum efficiency of 80% near 900 nm and have at least 40% quantum efficiency over the 400-nm to 1000-nm wavelength range. The extended red sensitivity of the detector array facilitates the use of lower energy excitation sources and near IR emitting dyes which reduces the impact of autofluorescence in signal starved measurements. The wide wavelength sensitivity of the APD array permits the use of multiple excitation sources and many different fluorescent labels to maximize the number of independent parameters in a given experiment. We show the sensitivity and linearity measurements for a single APD detector. Initial results for the flow cytometer with the 16-element APD array and the 16-channel readout ASIC (application specific integrated circuit) are presented.

  12. Monolithic and hybrid near infrared detection and imaging based on poly-Ge photodiode arrays

    NASA Astrophysics Data System (ADS)

    Masini, G.; Colace, L.; Petulla, F.; Assanto, G.; Cencelli, V.; DeNotaristefani, F.

    2005-02-01

    In recent years, several Ge-on-Si technologies for the fabrication of near infrared photodetectors on Si substrates were proposed. In particular, using a low temperature (300 °C) technique, we have demonstrated poly-Ge_on_Si detectors with high speed and good NIR responsivity. The low process temperature allows the monolithic integration of the detectors as a final step in the fabrication of Si CMOS integrated circuits. After an introduction on poly-Ge, we describe a novel integrated chip (NIRCAM-1) designed as a readout/control circuit for arrays of 64 (32) poly-Ge_on_Si photodetectors. The photodiodes, monolithically integrated (wire-bonded with a hybrid approach) on the IC, generate a photocurrent which is then ADC converted after subtraction of the dark component, thus allowing a convenient digital readout of the array. The extensive optoelectronic characterization of the IC is presented.

  13. Optoelectronic measurement for parameters of high-speed flying objects based on laser screen and photodiode array

    NASA Astrophysics Data System (ADS)

    Zhao, Donge; Zhang, Bin; Liu, Ji; Xiao, Kai-jia; Wang, Lei

    2013-09-01

    The impacting or penetrating power of high-speed flying object can be evaluated by its mass and velocity, so the velocity and the mass are two key parameters. Here we present an optoelectronic measurement method for parameters of high-speed flying objects based on parallel laser screen and photodiode array. The system consists of two thin laser screens with parallel each other and certain distance, orthogonal two dimensional photodiode arrays, data acquisition module, control module and data transmission processing module. When the object flies through the thin screen, the incident light of some photodiodes at the corresponding position is blocked and the output states of the corresponding photodiodes are changed. The flying position, which can be used to correct the distance error, velocity and the overall dimension of the object are determined by high-speed sampling and storing all the output states of photodiode array at any sampling moment when the object flying through the thin screens. We employed a line-shaped laser diode and a Fresnel lens with long-focal-length and aberration-free to generate parallel laser screen. The high-speed large-amount parallel data sampling module is comprised of four FPGA-based boards with built-in FIFO buffer memory, and the control module is constructed by one FPGA board and a FLASH memory. Functions simulation and experiment results of the FPGA-based data acquisition storage and the LabVIEW-based data processing indicate that the method and the design are feasible.

  14. InGaAs/InP avalanche photodiode arrays for eye-safe three-dimensional imaging

    NASA Astrophysics Data System (ADS)

    Dries, John C.; Martin, Tara; Huang, Wei; Lange, Michael J.; Cohen, Marshall J.

    2003-09-01

    We report on recent progress in developing 2-dimensional arrays of InGaAs/InP avalanche photodiodes. Advances in compound semiconductor epitaxy and device processing technologies enable large (128x128) element focal plane arrays with breakdown voltage standard deviations < 0.3%. The uniformity in breakdown voltage simplifies readout integrated circuit designs, in that a single bias voltage may be used for all elements in the array. Each element in the array achieves responsivities greater than 10 A/W at a wavelength of 1550 nm, while maintaining dark currents less than 20 nA. The APD arrays stand to enable new cameras for such applications as three-dimensional imaging, and various other laser radar and communications systems. In particular, the improved responsivity of avalanche photodiodes over their pin photodiode counterparts can improve sensitivities by as much as 6 - 10 dB depending upon the readout integrated circuit bandwidth. So-called "flash" laser radar systems wherein a single high energy laser pulse is used to image a target require the extra sensitivity afforded by avalanche photodiodes due to the low return photon count from distant targets.

  15. Impact ionization engineered avalanche photodiode arrays for free space optical communication

    NASA Astrophysics Data System (ADS)

    Ferraro, Mike S.; Rabinovich, William S.; Clark, William R.; Waters, William D.; Campbell, Joe C.; Mahon, Rita; Vaccaro, Kenneth; Krejca, Brian D.

    2016-03-01

    High sensitivity photodetectors serve two purposes in free space optical communication: data reception and position sensing for pointing, tracking, and stabilization. Because of conflicting performance criteria, two separate detectors are traditionally utilized to perform these tasks but recent advances in the fabrication and development of large area, low noise avalanche photodiode (APD) arrays have enabled these devices to be used both as position sensitive detectors (PSD) and as communications receivers. Combining these functionalities allows for more flexibility and simplicity in optical assembly design without sacrificing the sensitivity and bandwidth performance of smaller, single element data receivers. Beyond eliminating the need to separate the return beam into two separate paths, these devices enable implementation of adaptive approaches to compensate for focal plane beam wander and breakup often seen in highly scintillated terrestrial and maritime optical links. While the Naval Research Laboratory (NRL) and Optogration Inc, have recently demonstrated the performance of single period, InAlAs/InGaAs APD arrays as combined data reception and tracking sensors, an impact ionization engineered (I2E) epilayer design achieves even lower carrier ionization ratios by incorporating multiple multiplication periods engineered to suppress lower ionization rate carriers while enhancing the higher ionization rate carriers of interest. This work presents a three period I2E concentric, five element avalanche photodiode array rated for bandwidths beyond 1GHz with measured carrier ionization ratios of 0.05-0.1 at moderate APD gains. The epilayer design of the device will be discussed along with initial device characterization and high speed performance measurements.

  16. Determination of diarylheptanoids from Alpinia officinarum (Lesser Galangal) by HPLC with photodiode array and electrochemical detection.

    PubMed

    Liu, Zhihua; Sang, Shengmin; Hartman, Thomas G; Ho, Chi-Tang; Rosen, Robert T

    2005-01-01

    Normal-phase column chromatography followed by semi-preparative reversed-phase HPLC has been used to isolate, from the rhizomes of Alpinia officinarum, five diarylheptanoids identified as 5-hydroxy-7-(4"-hydroxy-3"-methoxyphenyl)-1-phenyl-3-heptanone, 5-methoxy-7-(4"-hydroxy-3"-methoxyphenyl)-1-phenyl-3-heptanone, 7-(4"-hydroxyphenyl)-1-phenylhept-4-en-3-one, 7-(4"-hydroxy-3"-methoxyphenyl)-1-phenyl-hept-4-en-3-one, 1,7-diphenylhept-4-en-3-one. The levels of these five diarylheptanoids in root material were determined quantitatively by HPLC with UV detection and the assay methods so developed were simple, rapid and accurate. Four of the diarylheptanoids could also be detected by HPLC with electrochemical detection (ECD) in the oxidative mode, and ECD was found to have a higher sensitivity than photodiode array detection.

  17. Determination of acaricides in honey by high-performance liquid chromatography with photodiode array detection.

    PubMed

    Martel, Anne-Claire; Zeggane, Sarah

    2002-04-19

    Rapid analytical methods are described to control quality of honeys, concerning residues of acaricides applied in hives to prevent Varroa jacobsoni infestation. A liquid-liquid extraction with hexane-propanol-2-ammonia (60 ml:30 ml:0.28%) was used for the simultaneous analysis of coumaphos, bromopropylate, amitraz and fluvalinate. For thymol, one clean up on a solid-phase extraction C18 (500 mg, 6 ml) column was performed; for rotenone, a liquid extraction with dichloromethane was realised. Quantitative recoveries obtained with honey were satisfactory and were superior to 80%. All acaricides are identified by reversed-phase high-performance liquid chromatography with photodiode array detection. Quantification limits obtained were below maximal residue limits when these exist.

  18. High-speed Imaging and Wavefront Sensing with an Infrared Avalanche Photodiode Array

    NASA Astrophysics Data System (ADS)

    Baranec, Christoph; Atkinson, Dani; Riddle, Reed; Hall, Donald; Jacobson, Shane; Law, Nicholas M.; Chun, Mark

    2015-08-01

    Infrared avalanche photodiode (APD) arrays represent a panacea for many branches of astronomy by enabling extremely low-noise, high-speed, and even photon-counting measurements at near-infrared wavelengths. We recently demonstrated the use of an early engineering-grade infrared APD array that achieves a correlated double sampling read noise of 0.73 e- in the lab, and a total noise of 2.52 e- on sky, and supports simultaneous high-speed imaging and tip-tilt wavefront sensing with the Robo-AO visible-light laser adaptive optics (AO) system at the Palomar Observatory 1.5 m telescope. Here we report on the improved image quality simultaneously achieved at visible and infrared wavelengths by using the array as part of an image stabilization control loop with AO-sharpened guide stars. We also discuss a newly enabled survey of nearby late M-dwarf multiplicity, as well as future uses of this technology in other AO and high-contrast imaging applications.

  19. HIGH-SPEED IMAGING AND WAVEFRONT SENSING WITH AN INFRARED AVALANCHE PHOTODIODE ARRAY

    SciTech Connect

    Baranec, Christoph; Atkinson, Dani; Hall, Donald; Jacobson, Shane; Chun, Mark; Riddle, Reed; Law, Nicholas M.

    2015-08-10

    Infrared avalanche photodiode (APD) arrays represent a panacea for many branches of astronomy by enabling extremely low-noise, high-speed, and even photon-counting measurements at near-infrared wavelengths. We recently demonstrated the use of an early engineering-grade infrared APD array that achieves a correlated double sampling read noise of 0.73 e{sup −} in the lab, and a total noise of 2.52 e{sup −} on sky, and supports simultaneous high-speed imaging and tip-tilt wavefront sensing with the Robo-AO visible-light laser adaptive optics (AO) system at the Palomar Observatory 1.5 m telescope. Here we report on the improved image quality simultaneously achieved at visible and infrared wavelengths by using the array as part of an image stabilization control loop with AO-sharpened guide stars. We also discuss a newly enabled survey of nearby late M-dwarf multiplicity, as well as future uses of this technology in other AO and high-contrast imaging applications.

  20. A cesium iodide (thallium)-photodiode array for remote geochemical analysis

    NASA Astrophysics Data System (ADS)

    Evans, Robert James

    To improve our understanding of the mechanism of the formation of the Solar System, information is needed on the global chemical composition of the planets outside of the Earth-Moon system. Thus, the measurement of the chemical composition of Mars and Mercury is a high priority for both the ESA and NASA space programmes. Remote geochemical analysis (RGA), by neutron activation gamma-ray spectroscopy, is a proven technique for remotely mapping the chemical composition of a planet with a thin or no atmosphere and as a result future missions to other terrestrial planets will probably include a gamma-ray spectrometer. The spectrometer must have sufficient sensitivity to resolve the most important emission fines radiating from the planet, whilst remaining within the mass, power and budget limitations of the mission specification. Therefore, there is a requirement for a spectrometer that will provide sufficient sensitivity, to determine the ratio's of elements such as Fe, O, Si and the naturally occurring radionucides K, U and Th, without incurring the high costs of a cooled HPGe detector. This work considers the factors that will determine the sensitivity of a scintillator gamma-ray spectrometer for RGA and demonstrates that a 61 element, pixelated, CsI(Tl)-phtodiode array will have a greater sensitivity than an, equivalent mass, NaI(Tl)-PMT or BGO-PMT detector. This is a result of the high mass ratio of sensitive material in the CsI(Tl)-photodiode array and the improved energy resolution, when compared to a NaI(Tl)-PMT detector, at energies above 2MeV. A prototype 7-element array has been designed, constructed and, tested at energies up to 4.44MeV, to demonstrate the potential performance of a larger 61-element array. The energy resolution of the 7 element array was found to be 2.93% FWHM at 4.44MeV, when operating in simple summation mode, which compares to 3.5% FWHM for a 2' NaI(Tl)-PMT detector. Consideration is also given to the different methods of spectral

  1. Radiation tolerance of a Geiger-mode avalanche photodiode imaging array

    NASA Astrophysics Data System (ADS)

    Kolb, Kimberly E.; Figer, Donald F.; Lee, Joong; Hanold, Brandon J.

    2016-07-01

    Radiation testing results for a Geiger-mode avalanche photodiode (GM-APD) array-based imager are reviewed. Radiation testing is a crucial step in technology development that assesses the readiness of a specific device or instrument for space-based missions or other missions in high-radiation environments. Pre- and postradiation values for breakdown voltage, dark count rate (DCR), after pulsing probability, photon detection efficiency (PDE), crosstalk probability, and intrapixel sensitivity are presented. Details of the radiation testing setup and experiment are provided. The devices were exposed to a total dose of 50 krad(Si) at the Massachusetts General Hospital's Francis H. Burr Proton Therapy Center, using monoenergetic 60 MeV protons as the radiation source. This radiation dose is equivalent to radiation absorbed over 10 solar cycles at an L2 orbit with 1-cm aluminum shielding. The DCR increased by 2.3 e-/s/pix/krad(Si) at 160 K, the afterpulsing probability increased at all temperatures and settings by a factor of ˜2, and the effective breakdown voltage shifted by +1.5 V. PDE, crosstalk probability, and intrapixel sensitivity were unchanged by radiation damage. The performance of the GM-APD imaging array is compared to the performance of the CCD on board the ASCA satellite with a similar radiation shield and radiation environment.

  2. Lutetium oxyorthosilicate block detector readout by avalanche photodiode arrays for high resolution animal PET.

    PubMed

    Pichler, B J; Swann, B K; Rochelle, J; Nutt, R E; Cherry, S R; Siegel, S B

    2004-09-21

    Avalanche photodiodes (APDs) have proven to be useful as light detectors for high resolution positron emission tomography (PET). Their compactness makes these devices excellent candidates for replacing bulky photomultiplier tubes (PMTs) in PET systems where space limitations are an issue. The readout of densely packed, 10 x 10 lutetium oxyorthosilicate (LSO) block detectors (crystal size 2.0 x 2.0 x 12 mm3) with custom-built monolithic 3 x 3 APD arrays was investigated. The APDs had a 5 x 5 mm2 active surface and were arranged on a 6.25 mm pitch. The dead space on the edges of the array was 1.25 mm. The APDs were operated at a bias voltage of approximately 380 V for a gain of 100 and a dark current of 10 nA per APD. The standard deviation in gain between the APDs in the array ranged from 1.8 to 6.5% as the gain was varied from 50 to 108. A fast, low-noise, multi-channel charge sensitive preamplifier application-specific integrated circuit (ASIC) was developed for the APD readout. The amplifier had a rise time of 8 ns, a noise floor of 515 e- rms and a 9 e- pF(-1) noise slope. An acquired flood image showed that all 100 crystals from the block detector could be resolved. Timing measurements with single-channel LSO-APD detectors, as well as with the array, against a plastic scintillator and PMT assembly showed a time resolution of 1.2 ns and 2.5 ns, respectively. The energy resolution measured with a single 4.0 x 4.0 x 10 mm3 LSO crystal, wrapped in four-layer polytetrafluoroethylene (PTFE) tape and coupled with optical grease on a single APD of the array, yielded 15% (full width at half maximum, FWHM) at 511 keV. Stability tests over 9 months of operation showed that the APD arrays do not degrade appreciably. These results demonstrate the ability to decode densely packed LSO scintillation blocks with compact APD arrays. The good timing and energy resolution makes these detectors suitable for high resolution PET.

  3. Fully tileable photodiode matrix for medical imaging by using through-wafer interconnects

    NASA Astrophysics Data System (ADS)

    Juntunen, Mikko; Ji, Fan; Henttinen, Kimmo; Luusua, Ismo; Hietanen, Iiro; Eränen, Simo

    2007-10-01

    This paper presents a technology for a fully tileable two-dimensional (2D) photodiode matrix for medical imaging, specifically X-ray computed tomography (CT). A key trend in the CT industry is to build machines with larger area detector to speed up the measurements and to avoid image blurring due to patient movement during scanning. In current CT detector constructions, a major limiting factor in providing more detector coverage is the need to read out the signals from the individual photo-detector elements of the detector array through lines along the surface facing the radiation source and wire bonds down to a substrate or to an electronics chip. Using this method, there is a physical limitation on the size of a photo-detector array that may be manufactured. A photo-detector with the possibility of expansion in all directions is known as a 'tileable' detector. A technology of integrating through-wafer interconnects (TWIs) with traditional front illuminated photodiodes is introduced. Photocurrent can be read out from back side of the photodiode chip through interconnects, giving possibility of constructing arbitrarily large area of photo-detector for CT machine. Results of a sample 2D demonstrator detector array are presented showing that the requirements of modern CT systems can be met.

  4. Impact-ionization-engineered avalanche photodiode arrays for free-space optical communication

    NASA Astrophysics Data System (ADS)

    Ferraro, Mike S.; Rabinovich, William S.; Clark, William R.; Waters, William D.; Campbell, Joe C.; Mahon, Rita; Vaccaro, Kenneth; Krejca, Brian D.; D'Ambrosio, Philip

    2016-11-01

    High-sensitivity photodetectors serve two purposes in free-space optical communication: data reception and position sensing for pointing, tracking, and stabilization. Two separate detectors are traditionally utilized to perform these tasks, but recent advances in the fabrication and development of large area, low-noise avalanche photodiode (APD) arrays have enabled these devices to be used both as position-sensitive detectors and communications receivers because of the conflicting performance criteria. Combining these functionalities allows for more flexibility and simplicity in optical assembly design without sacrificing the sensitivity and bandwidth performance of smaller, single-element data receivers. Beyond eliminating the need to separate the return beam into two separate paths, these devices enable implementation of adaptive approaches to compensate for focal plane beam wander and breakup, which is often seen in highly scintillated terrestrial and maritime optical links. While the Naval Research Laboratory and Optogration, Inc. have recently demonstrated the performance of single period, InAlAs/InGaAs APD arrays as combined data reception and tracking sensors, an impact-ionization-engineered epilayer design achieves even lower carrier ionization ratios by incorporating multiple multiplication periods engineered to suppress lower ionization rate carriers while enhancing the higher ionization rate carriers of interest. This work presents a three-period I2E concentric, five-element APD array rated for bandwidths beyond 1 GHz with measured carrier ionization ratios of 0.05 to 0.1 at moderate APD gains. The epilayer design of the device will be discussed along with initial device characterization and high-speed performance measurements.

  5. Analysis of cephalexin from canine skin biopsy by liquid chromatography with ultraviolet-visible photodiode-array detection.

    PubMed

    Tyczkowska, K; Aronson, A L

    1988-05-13

    A sensitive and selective ion-paired liquid chromatographic method with UV-VIS photodiode-array detection was developed to measure cephalexin in skin biopsy samples. The method involved a sonication of minced canine skin with ethanol-acetonitrile-water (30:20:50, v/v/v) and ultrafiltration of received extract through 10,000 daltons. Separation of cephalexin from other components was by liquid chromatography using a reversed-phase column which was eluted with an ion-paired acetonitrile-water solution. Detection was achieved with a UV-VIS photodiode-array detector scanning from 230 to 320 nm. Cephalexin in the eluate was quantitated at its wavelength maximum of 260 nm. The evaluation of chromatographic peak homogeneity was performed by absorbance ratios, contour maps, first-derivative spectra and a three-dimensional spectrochromatogram. Additionally, the cephalexin peak identity was confirmed by liquid chromatography-mass spectrometry.

  6. Simultaneous determination of five aluminum lake dyes in chewing gum by HPLC with photodiode array detection.

    PubMed

    Yang, Yi; Yin, Jie; Shao, Bing

    2011-09-01

    A simple and rapid method has been developed and validated for the determination of five food aluminum lake dyes (Tartrazine Al lake, Sunset Yellow Al lake, Ponceau 4R Al lake, Allura Red Al lake and Brilliant Blue Al lake) in chewing gum. The dye portions of the target aluminum lakes were simultaneous extracted with 0.25 M NaOH and cleaned up by liquid-liquid extraction with dichloromethane, followed by further purification using Oasis WAX solid-phase extraction (SPE) cartridges. Analytes were separated by HPLC using an Inertsil ® ODS-3 column coupled to a photodiode array detector. The amounts of the aluminum lake dyes were finally quantified and indicated as their dye portions using corresponding calibration curves over ranges of 0.5 to 50 µg ml(-1), with correlation coefficients >0.9999. Recoveries of the dye parts in aluminum lake dyes (spiked at levels of 1, 5, 25 µg g(-1)) ranged from 72.5 to 116.4%, with relative standard deviations between 0.9 and 6.5%. Limits of detection and limits of quantification for all analytes were 0.15 and 0.50 µg g(-1), respectively. This method was successfully applied in real samples of chewing gum. © 2011 Taylor & Francis

  7. Radiation tolerant compact image sensor using CdTe photodiode and field emitter array (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Masuzawa, Tomoaki; Neo, Yoichiro; Mimura, Hidenori; Okamoto, Tamotsu; Nagao, Masayoshi; Akiyoshi, Masafumi; Sato, Nobuhiro; Takagi, Ikuji; Tsuji, Hiroshi; Gotoh, Yasuhito

    2016-10-01

    A growing demand on incident detection is recognized since the Great East Japan Earthquake and successive accidents in Fukushima nuclear power plant in 2011. Radiation tolerant image sensors are powerful tools to collect crucial information at initial stages of such incidents. However, semiconductor based image sensors such as CMOS and CCD have limited tolerance to radiation exposure. Image sensors used in nuclear facilities are conventional vacuum tubes using thermal cathodes, which have large size and high power consumption. In this study, we propose a compact image sensor composed of a CdTe-based photodiode and a matrix-driven Spindt-type electron beam source called field emitter array (FEA). A basic principle of FEA-based image sensors is similar to conventional Vidicon type camera tubes, but its electron source is replaced from a thermal cathode to FEA. The use of a field emitter as an electron source should enable significant size reduction while maintaining high radiation tolerance. Current researches on radiation tolerant FEAs and development of CdTe based photoconductive films will be presented.

  8. A slot-scanned photodiode-array/CCD hybrid detector for digital mammography.

    PubMed

    Mainprize, James G; Ford, Nancy L; Yin, Shi; Tümer, Türmay; Yaffe, Martin J

    2002-02-01

    We have developed a novel direct conversion detector for use in a slot-scanning digital mammography system. The slot-scan concept allows for dose efficient scatter rejection and the ability to use small detectors to produce a large-area image. The detector is a hybrid design with a 1.0 mm thick silicon PIN photodiode array (the x-ray absorber) indium-bump bonded to a CCD readout that is operated in time-delay integration (TDI) mode. Because the charge capacity requirement for good image quality exceeds the capabilities of standard CCDs, a novel CCD was developed. This CCD consists of 24 independent sections, each acting as a miniature CCD with eight rows for TDI. The signal from each section is combined off-chip to produce a full signal image. The MTF and DQE for the device was measured at several exposures and compared to a linear systems model of signal and noise propagation. Because of the scanning nature of TDI imaging, both the MTF(f) and DQE(f) are reduced along the direction of the scanning motion. For a 26 kVp spectrum, the DQE(0) was measured to be 0.75+/-0.02 for an exposure of 1.29 x 10(-5) C/kg (50 mR).

  9. Saturation effects in heterodyne detection with Geiger-mode InGaAs avalanche photodiode detector arrays.

    PubMed

    Luu, Jane X; Jiang, Leaf A

    2006-06-01

    We report, to the best of our knowledge, the first demonstration of heterodyne detection of a glint target using an InGaAs avalanche photodiode detector (APD) array in the Geiger mode. Due to the finite number of pixels, all such photon-counting arrays necessarily suffer from saturation effects. At large photon fluxes, saturation of the APD degrades the Doppler frequency resolution and the signal-to-noise ratio (SNR). We derive analytical expressions for the Doppler resolution and SNR, taking saturation effects into account. The optimal local oscillator power can be obtained numerically from the SNR expression.

  10. Three-dimensional imaging laser radar with a photon-counting avalanche photodiode array and microchip laser.

    PubMed

    Albota, Marius A; Heinrichs, Richard M; Kocher, David G; Fouche, Daniel G; Player, Brian E; O'Brien, Michael E; Aull, Brian F; Zayhowski, John J; Mooney, James; Willard, Berton C; Carlson, Robert R

    2002-12-20

    We have developed a threedimensional imaging laser radar featuring 3-cm range resolution and single-photon sensitivity. This prototype direct-detection laser radar employs compact, all-solid-state technology for the laser and detector array. The source is a Nd:YAG microchip laser that is diode pumped, passively Q-switched, and frequency doubled. The detector is a gated, passively quenched, two-dimensional array of silicon avalanche photodiodes operating in Geigermode. After describing the system in detail, we present a three-dimensional image, derive performance characteristics, and discuss our plans for future imaging three-dimensional laser radars.

  11. Linear terrestrial laser scanning using array avalanche photodiodes as detectors for rapid three-dimensional imaging.

    PubMed

    Cai, Yinqiao; Tong, Xiaohua; Tong, Peng; Bu, Hongyi; Shu, Rong

    2010-12-01

    As an active remote sensor technology, the terrestrial laser scanner is widely used for direct generation of a three-dimensional (3D) image of an object in the fields of geodesy, surveying, and photogrammetry. In this article, a new laser scanner using array avalanche photodiodes, as designed by the Shanghai Institute of Technical Physics of the Chinese Academy of Sciences, is introduced for rapid collection of 3D data. The system structure of the new laser scanner is first presented, and a mathematical model is further derived to transform the original data to the 3D coordinates of the object in a user-defined coordinate system. The performance of the new laser scanner is tested through a comprehensive experiment. The result shows that the new laser scanner can scan a scene with a field view of 30° × 30° in 0.2 s and that, with respect to the point clouds obtained on the wall and ground floor surfaces, the root mean square errors for fitting the two planes are 0.21 and 0.01 cm, respectively. The primary advantages of the developed laser scanner include: (i) with a line scanning mode, the new scanner achieves simultaneously the 3D coordinates of 24 points per single laser pulse, which enables it to scan faster than traditional scanners with a point scanning mode and (ii) the new scanner makes use of two galvanometric mirrors to deflect the laser beam in both the horizontal and the vertical directions. This capability makes the instrument smaller and lighter, which is more acceptable for users.

  12. An experimental photodiode array unit for ultrahigh-resolution recording of X-ray images

    NASA Astrophysics Data System (ADS)

    Fedotov, M. G.; Panchenko, V. E.

    1995-02-01

    The geometrical resolution of modern solid-state X-ray imagers (photodiode arrays, PDA, and charge-coupled devices, CCD) is defined by their sensitive-pixel sizes and ranges from 10 up to 20 μm, i.e. these imagers yield considerably to photoemulsions in the resolution (0.1-1 μm of emulsions). In the present paper, an attempt to create a recording unit with a spatial resolution comparable to that of photoemulsions is described. First results of testing of the unit is described. The last was fabricated on the basis of a PDA containing 1024 sensitive pixels which are 150 μm high and are positioned with a 25 μm step. The feature of the given PDA consists of the presence of an individual charge-sensitive amplifier in each pixel. This allowed us to realize an algorithm of the digital double correlated sampling and to remove KTC noise which, under ordinary conditions, limits the PDA sensitivity. To diminish the noise level, the unit is provided with a double-correlated-sampling analog highway, which removes {1}/{f} noises of the on-chip read preamplifiers and possesses the LF filter qualities, and with cooling of the PDA by a two-stage battery of Peltier cells. The unit was tested in the mode of the integrating X-ray imager. It is expected, by corresponding computer processing of the separate X-ray photon absorption events, that one will succeed in determining each event coordinate while allowing for the signal charge distribution between pixels due to charge diffusion in the PDA substratum.

  13. High-speed, large-area, p-i-n InGaAs photodiode linear array at 2-micron wavelength

    NASA Astrophysics Data System (ADS)

    Joshi, Abhay; Datta, Shubhashish

    2012-06-01

    We present 16-element and 32-element lattice-mismatched InGaAs photodiode arrays having a cut-off wavelength of ~2.2 um. Each 100 um × 200 um large pixel of the 32-element array has a capacitance of 2.5 pF at 5 V reverse bias, thereby allowing a RC-limited bandwidth of ~1.3 GHz. At room temperature, each pixel demonstrates a dark current of 25 uA at 5 V reverse bias. Corresponding results for the 16-element array having 200 um × 200 um pixels are also reported. Cooling the photodiode array to 150K is expected to reduce its dark current to < 50 nA per pixel at 5 V reverse bias. Additionally, measurement results of 2-micron single photodiodes having 16 GHz bandwidth and corresponding PIN-TIA photoreceiver having 6 GHz bandwidth are also reported.

  14. P-InAsSbP/n-InAs single heterostructure back-side illuminated 8 × 8 photodiode array

    NASA Astrophysics Data System (ADS)

    Brunkov, P. N.; Il'inskaya, N. D.; Karandashev, S. A.; Lavrov, A. A.; Matveev, B. A.; Remennyi, M. A.; Stus', N. M.; Usikova, A. A.

    2016-09-01

    P-InAsSbP/n-InAs/n+-InAs single heterostructure photodiode monolithic array with linear impurity distribution in the space charge region and "bulk" n-InAs absorbing layer has been fabricated by the LPE method and studied for the first time. Unlike all known InAsSbP/InAs PDs with an abrupt p-n junction the linear impurity distribution PDs potentially suggest lower compared with analogs capacitance and tunneling current. Indeed the developed photodiodes showed good perspectives for use in low temperature pyrometry as low dark current (8 × 10-6 A/cm2, Ubias = -0.5 V, 164 K) and background limited infrared photodetector (BLIP) regime starting from 190 K (2π field of view, D3.1μm ∗ = 1.1 × 1012 cm Hz1/2/W) have been demonstrated. High photodiode performance is thought to be due to above peculiarities of the impurity distribution as well as low defect density in P-InAsSbP/n-InAs/n+-InAs single heterostructure.

  15. A discrete component low-noise preamplifier readout for a linear (1×16) SiC photodiode array

    NASA Astrophysics Data System (ADS)

    Kahle, Duncan; Aslam, Shahid; Herrero, Federico A.; Waczynski, Augustyn

    2016-09-01

    A compact, low-noise and inexpensive preamplifier circuit has been designed and fabricated to optimally readout a common cathode (1×16) channel 4H-SiC Schottky photodiode array for use in ultraviolet experiments. The readout uses an operational amplifier with 10 pF capacitor in the feedback loop in parallel with a low leakage switch for each of the channels. This circuit configuration allows for reiterative sample, integrate and reset. A sampling technique is given to remove Johnson noise, enabling a femtoampere level readout noise performance. Commercial-off-the-shelf acquisition electronics are used to digitize the preamplifier analog signals. The data logging acquisition electronics has a different integration circuit, which allows the bandwidth and gain to be independently adjusted. Using this readout, photoresponse measurements across the array between spectral wavelengths 200 nm and 370 nm are made to establish the array pixels external quantum efficiency, current responsivity and noise equivalent power.

  16. Nonlinearity and image persistence of P-20 phosphor-based intensified photodiode array detectors used in CARS spectroscopy.

    PubMed

    Snelling, D R; Smallwood, G J; Sawchuk, R A

    1989-08-01

    Several self-scanning photodiode arrays (IPDA) used for CARS spectroscopy are shown to exhibit a greater image persistence than has generally been realized, and to exhibit a falloff in sensitivity that is logarithmic with decreasing output signal. These effects are attributed to the P-20 phosphor based intensifiers used in the IPDAs and are probably generic to all such detectors. A strategy for minimizing the image persistence in CARS spectroscopy is presented. A prototype detector incorporating a much faster rare earth phosphor is evaluated and shown to be more suited to single pulse CARS measurements in turbulent combustion than the IPDAs incorporating P-20 phosphors.

  17. Linear arrays of InGaAs/InP avalanche photodiodes for 1.0-1.7 micron

    NASA Technical Reports Server (NTRS)

    Ackley, D. E.; Hladky, J.; Lange, M. J.; Mason, S.; Erickson, G.; Olsen, G. H.; Ban, V. S.; Forrest, S. R.; Staller, C.

    1990-01-01

    Separate absorption and multiplication InGaAs/InP avalanche photodiodes (SAM-APDs) with a floating guard ring structure that is well-suited to array applications have been successfully demonstrated. Individual APDs have breakdown voltages greater than 80 V, multiplications over 40 at 100 nA dark current, and uniform spatial gain profiles. Uniform I-V characteristics and gains have been measured over linear dimensions as large as 1.2 cm. Gains over 10 at low multiplied dark currents were measured on 21 consecutive devices at the wafer level.

  18. Nonlinearity and image persistence of P-20 phosphor-based intensified photodiode array detectors used in CARS spectroscopy

    SciTech Connect

    Snelling, D. R.; Smallwood, G. J.; Sawchuk, R.

    1989-08-01

    Several self-scanning photodiode arrays (IPDA) used for CARS spectroscopy are shown to exhibit a greater image persistence than has generally been realized, and to exhibit a falloff in sensitivity that is logarithmic with decreasing output signal. These effects are attributed to the P-20 phosphor based intensifiers used in the IPDAs and are probably generic to all such detectors. A strategy for minimizing the image persistence in CARS spectroscopy is presented. A prototype detector incorporating a much faster rare earth phosphor is evaluated and shown to be more suited to single pulse CARS measurements in turbulent combustion than the IPDAs incorporating P-20 phosphors.

  19. Linear arrays of InGaAs/InP avalanche photodiodes for 1.0-1.7 micron

    NASA Technical Reports Server (NTRS)

    Ackley, D. E.; Hladky, J.; Lange, M. J.; Mason, S.; Erickson, G.; Olsen, G. H.; Ban, V. S.; Forrest, S. R.; Staller, C.

    1990-01-01

    Separate absorption and multiplication InGaAs/InP avalanche photodiodes (SAM-APDs) with a floating guard ring structure that is well-suited to array applications have been successfully demonstrated. Individual APDs have breakdown voltages greater than 80 V, multiplications over 40 at 100 nA dark current, and uniform spatial gain profiles. Uniform I-V characteristics and gains have been measured over linear dimensions as large as 1.2 cm. Gains over 10 at low multiplied dark currents were measured on 21 consecutive devices at the wafer level.

  20. A prototype high-resolution animal positron tomograph with avalanche photodiode arrays and LSO crystals.

    PubMed

    Ziegler, S I; Pichler, B J; Boening, G; Rafecas, M; Pimpl, W; Lorenz, E; Schmitz, N; Schwaiger, M

    2001-02-01

    To fully utilize positron emission tomography (PET) as a non-invasive tool for tissue characterization, dedicated instrumentation is being developed which is specially suited for imaging mice and rats. Semiconductor detectors, such as avalanche photodiodes (APDs), may offer an alternative to photomultiplier tubes for the readout of scintillation crystals. Since the scintillation characteristics of lutetium oxyorthosilicate (LSO) are well matched to APDs, the combination of LSO and APDs seems favourable, and the goal of this study was to build a positron tomograph with LSO-APD modules to prove the feasibility of such an approach. A prototype PET scanner based on APD readout of small, individual LSO crystals was developed for tracer studies in mice and rats. The tomograph consists of two sectors (86 mm distance), each comprising three LSO-APD modules, which can be rotated for the acquisition of complete projections. In each module, small LSO crystals (3.7 x 3.7 x 12 mm3) are individually coupled to one channel within matrices containing 2x8 square APDs (2.6 x 2.6 mm2 sensitive area per channel). The list-mode data are reconstructed with a penalized weighted least squares algorithm which includes the spatially dependent line spread function of the tomograph. Basic performance parameters were measured with phantoms and first experiments with rats and mice were conducted to introduce this methodology for biomedical imaging. The reconstructed field of view covers 68 mm, which is 80% of the total detector diameter. Image resolution was shown to be 2.4 mm within the whole reconstructed field of view. Using a lower energy threshold of 450 keV, the system sensitivity was 350 Hz/MBq for a line source in air in the centre of the field of view. In a water-filled cylinder of 4.6 cm diameter, the scatter fraction at the centre of the field of view was 16% (450 keV threshold). The count rate was linear up to 700 coincidence counts per second. In vivo studies of anaesthetized rats

  1. Pin-photodiode array for the measurement of fan-beam energy and air kerma distributions of X-ray CT scanners.

    PubMed

    Haba, Tomonobu; Koyama, Shuji; Aoyama, Takahiko; Kinomura, Yutaka; Ida, Yoshihiro; Kobayashi, Masanao; Kameyama, Hiroshi; Tsutsumi, Yoshinori

    2016-07-01

    Patient dose estimation in X-ray computed tomography (CT) is generally performed by Monte Carlo simulation of photon interactions within anthropomorphic or cylindrical phantoms. An accurate Monte Carlo simulation requires an understanding of the effects of the bow-tie filter equipped in a CT scanner, i.e. the change of X-ray energy and air kerma along the fan-beam arc of the CT scanner. To measure the effective energy and air kerma distributions, we devised a pin-photodiode array utilizing eight channels of X-ray sensors arranged at regular intervals along the fan-beam arc of the CT scanner. Each X-ray sensor consisted of two plate type of pin silicon photodiodes in tandem - front and rear photodiodes - and of a lead collimator, which only allowed X-rays to impinge vertically to the silicon surface of the photodiodes. The effective energy of the X-rays was calculated from the ratio of the output voltages of the photodiodes and the dose was calculated from the output voltage of the front photodiode using the energy and dose calibration curves respectively. The pin-photodiode array allowed the calculation of X-ray effective energies and relative doses, at eight points simultaneously along the fan-beam arc of a CT scanner during a single rotation of the scanner. The fan-beam energy and air kerma distributions of CT scanners can be effectively measured using this pin-photodiode array. Copyright © 2016 Associazione Italiana di Fisica Medica. Published by Elsevier Ltd. All rights reserved.

  2. Simultaneous determination of seven main alkaloids of Chelidonium majus L. by ultra-performance LC with photodiode-array detection.

    PubMed

    Gu, Yue; Qian, Dawei; Duan, Jin-ao; Wang, Zhenzhong; Guo, Jianming; Tang, Yuping; Guo, Sheng

    2010-04-01

    A simple and rapid method for the simultaneous determination of seven isoquinoline alkaloids, protopine, chelidonine, coptisine, stylopine, sanguinarine, berberine, and chelerythrine, in Chelidonium majus L. (Ch. majus) samples by ultra-performance LC method with photodiode array detection is described. The baseline separation of these compounds was performed with (A) acetonitrile-(B) ammonium acetate (10 mM, adjusted to pH 3.0 with acetic acid) as the mobile phase using a C18 RP column (2.1x100 mm, 1.7 microm). Optimized conditions resulted in excellent peak shapes. The seven alkaloids were completely separated within 20 min. Good linear behaviors (r > or = 0.9992) over the investigated concentration ranges were observed for all the analytes. Validation proved the repeatability of the method was good and recovery was satisfactory. The validated method was successfully applied for 20 batches of Ch. majus. These results demonstrated that the ultra-performance LC photodiode array method proposed was very useful in the analysis and quality control of Ch. majus.

  3. Simultaneous data communication and position sensing with an impact ionization engineered avalanche photodiode array for free space optical communication

    NASA Astrophysics Data System (ADS)

    Ferraro, Mike S.; Mahon, Rita; Rabinovich, William S.; Murphy, James L.; Dexter, James L.; Clark, William R.; Waters, William D.; Vaccaro, Kenneth; Krejca, Brian D.

    2017-02-01

    Photodetectors in free space optical communication systems perform two functions: reception of data communication signals and position sensing for pointing, tracking, and stabilization. Traditionally, the optical receive path in an FSO system is split into separate paths for data detection and position sensing. The need for separate paths is a consequence of conflicting performance criteria between position sensitive detectors (PSD) and data detectors. Combining the functionality of both detector types requires that the combinational sensor not only have the bandwidth to support high data rate communication but the active area and spatial discrimination to accommodate position sensing. In this paper we present a large area, concentric five element impact ionization engineered avalanche photodiode array rated for bandwidths beyond 1GHz with a measured carrier ionization ratio of less than 0.1 at moderate APD gains. The integration of this array as a combinational sensor in an FSO system is discussed along with the development of a pointing and stabilization algorithm.

  4. The Trace Analysis of DEET in Water using an On-line Preconcentration Column and Liquid Chromatography with UV Photodiode Array Detection

    EPA Science Inventory

    A method for the detection of trace levels of N,N-diethyl-m-toluamide (DEET) in water is discussed. The method utilizes an on-line preconcentration column in series with high performance liquid chromatography (HPLC) and UV photodiode array detection. DEET, a common insect repel...

  5. Microfluidic biosensor array with integrated poly(2,7-carbazole)/fullerene-based photodiodes for rapid multiplexed detection of pathogens.

    PubMed

    Matos Pires, Nuno Miguel; Dong, Tao

    2013-11-25

    A multiplexed microfluidic biosensor made of poly(methylmethacrylate) (PMMA) was integrated into an array of organic blend heterojunction photodiodes (OPDs) for chemiluminescent detection of pathogens. Waterborne Escherichia coli O157:H7, Campylobacter jejuni and adenovirus were targeted in the PMMA chip, and detection of captured pathogens was conducted by poly(2,7-carbazole)/fullerene OPDs which showed a responsivity over 0.20 A/W at 425 nm. The limits of chemiluminescent detection were 5 × 10(5) cells/mL for E. coli, 1 × 10(5) cells/mL for C. jejuni, and 1 × 10(-8) mg/mL for adenovirus. Parallel analysis for all three analytes in less than 35 min was demonstrated. Further recovery tests illustrated the potential of the integrated biosensor for detecting bacteria in real water samples.

  6. Microfluidic Biosensor Array with Integrated Poly(2,7-Carbazole)/Fullerene-Based Photodiodes for Rapid Multiplexed Detection of Pathogens

    PubMed Central

    Pires, Nuno Miguel Matos; Dong, Tao

    2013-01-01

    A multiplexed microfluidic biosensor made of poly(methylmethacrylate) (PMMA) was integrated into an array of organic blend heterojunction photodiodes (OPDs) for chemiluminescent detection of pathogens. Waterborne Escherichia coli O157:H7, Campylobacter jejuni and adenovirus were targeted in the PMMA chip, and detection of captured pathogens was conducted by poly(2,7-carbazole)/fullerene OPDs which showed a responsivity over 0.20 A/W at 425 nm. The limits of chemiluminescent detection were 5 × 105 cells/mL for E. coli, 1 × 105 cells/mL for C. jejuni, and 1 × 10−8 mg/mL for adenovirus. Parallel analysis for all three analytes in less than 35 min was demonstrated. Further recovery tests illustrated the potential of the integrated biosensor for detecting bacteria in real water samples. PMID:24287522

  7. Identification of fish species by reversed-phase high-performance liquid chromatography with photodiode-array detection.

    PubMed

    Knuutinen, J; Harjula, P

    1998-01-23

    A method for the separation of sarcoplasmic fish proteins by RP-HPLC is described. The procedure revealed significant differences useful for reliable identification of fish species. Sixteen of the most common Finnish freshwater fish species were differentiated by species-specific HPLC chromatograms obtained using photodiode-array detection (PAD) at 200-350 nm. The analytical column was a Hi-Pore RP-304 reversed-phase column. The separation was performed by a linear gradient of acetonitrile and water with a small amount of trifluoracetic acid (TFA). Star-symbol plots were constructed from the chromatograms to visualize the data. Clearly different HPLC protein profiles for most fish species were obtained. The chromatograms of salmonoids show similarities, whereas the protein profiles of cyprinids are dissimilar. Minor intraspecific differences were obtained for three types of powan (Coregonus lavaretus).

  8. Determination of aliphatic alcohols after on-line microwave-assisted derivatization by liquid chromatography-photodiode array detection.

    PubMed

    Chávez, Gerson; Bravo, Bélgica; Piña, Nolberto; Arias, Mónica; Vivas, Eliseo; Ysambertt, Fredy; Márquez, Nelson; Cáceres, Ana

    2004-12-15

    In this study, high-performance liquid chromatography (HPLC) in conjunction with continuous derivatization for the determination of aliphatic and polyethoxylated alcohol is reported. Reaction of alcohol group with phenyl isocyanate or benzyl chloride reagents assisted with microwaves (MW) irradiation is carried out in an on-line system coupled to HPLC with photodiode array detection (PDA). Reactor was placed into a microwave oven at 450W. The flow rate, reagent amounts, irradiation time, and chromatographic conditions were optimized. The continuous analysis using the system MW-HPLC-PDA provided high sensitivity, reduce the amount of reagents and analysis time. This proposed method can be used for the analysis of commercial alcohol polyethoxylated mixture.

  9. Evaluation of resazurin microtiter plate assay and HPLC- photodiode array analysis of the roots of Asparagus adscendens.

    PubMed

    Khan, Kashif Maqbool; Nahar, Lutfun; Mannan, Abdul; Arfan, Muhammad; Khan, Ghazanfar Ali; Hobbs, Glyn; Sarker, Satyajit D

    2017-07-19

    Asparagus adscendens Roxb. (Asparagaceae), is native to the Himalayas. The present study, for the first time, was undertaken to explore the antimicrobial potential, to determine the minimum inhibitory concentration (MIC) values of the methanol extract of the roots of A. adscendens and its solid-phase extraction (SPE) fractions using resazurin microtitre assay against Gram-positive and negative bacterial-registered strains and to carry out HPLC-photodiode array analysis of the SPE fractions. The methanol extract and all SPE exhibited considerable level of antibacterial potential against Gram-positive bacteria (MIC: 2.5-0.009 mg/mL) than against Gram-negative bacteria (MIC: 1.25-2.5 mg/mL). The use of microtitre plates has the advantage of lower cost, fast and quantitative results. Like other Asparagus species, the presence of phenolic compounds in all SPE fractions was evident in the HPLC-PDA data.

  10. Coincident Observations of Lightning by the FORTE Photodiode Detector and the New Mexico Tech Lightning Mapping Array During STEPS 2000

    NASA Astrophysics Data System (ADS)

    Noble, C. M.; Beasley, W. H.; Light, T. E.; Suszcynsky, D. M.; Hamlin, T.

    2001-12-01

    During the STEPS 2000 experiment, the Fast On-Orbit Recording of Transient Events (FORTE) satellite passed over a thunderstorm which was also within view of New Mexico Tech's 3-D Lightning Mapping Array (LMA). The FORTE pass occurred on June 25, 2000 from approximately 7:52:00 UTC to 7:54:40 UTC. During that time, the PhotoDiode Detector (PDD) aboard FORTE triggered for approximately 60 events classified as lightning and the LMA mapped approximately 200 lightning flashes. This paper investigates the relationship between the physical characteristics of the lightning channels, as mapped by the LMA, and whether those flashes were also detected by the PDD. Maximum height reached by the lightning discharge, horizontal dimensions of the discharge, flash complexity, and the length of time for the extended flash are examined.

  11. Conversion of a sequential inductively coupled plasma emission spectrometer into a multichannel simultaneous system using a photodiode array detector

    PubMed Central

    Araújo, Mário César Ugulino; Neto, Benício de Barros; Pasquini, Célio

    1998-01-01

    A monochannel plasma emission spectrometer was converted to a multichannel instrument by the introduction of a detection system based on an array of 1024 photodiodes and a low-resolution dispersion device. The new, relatively inexpensive equipment, features both the high speed typical of simultaneous instruments and the versatility of scanning systems. This paper reports on an evaluation of the modified equipment for quantitative analysis with the simultaneous determination of Al, Mn, Mg, Ca, Fe and Cu in a natural water matrix. An average relative prediction error of 2.4% was found which is the same as the error obtained with the conventional analytical method. Data acquisition with the modified instrument is up to 40 times faster. PMID:18924819

  12. Liquid chromatography-mass spectroscopy and liquid chromatography-ultraviolet/visible photodiode array analysis of selected colchicum species.

    PubMed

    Gharaibeh, Ahmad A; Al-Serini, Ala'a; Qasaymeh, Rana M; Ma'aya'h, Amani S; Tawaha, Khaled; El-Elimat, Tamam; Alali, Feras Q

    2012-01-01

    An in-house strategy to dereplicate colchicinoid alkaloids was recently developed by our team. It aimed at quickly identifying Colchicum constituents using LC-MS (liquid chromatography-mass spectroscopy) and LC-UV/Vis PDA (liquid chromatography-ultraviolet/ visible photodiode array) techniques. In this project, our goal was to validate the developed method through analysing the alkaloid-rich fractions of three Colchicum species that had been previously studied phytochemically using the traditional bioactivity-guided fractionation methodology. The analysed species were Colchicum tauri Siehe ex Stefanoff, Colchicum stevenii Kunth, and Colchicum tunicatum Feinbr., all belonging to the family Colchicaceae. In addition to identifying the compounds previously isolated and characterized by the traditional methodology, the new strategy succeeded in tentatively identifying a set of known compounds, but new to the species.

  13. Determination of synthetic acaricides residues in beeswax by high-performance liquid chromatography with photodiode array detector.

    PubMed

    Adamczyk, Sabine; Lázaro, Regina; Pérez-Arquillué, Consuelo; Herrera, Antonio

    2007-01-02

    A multiresidue HPLC method for identification and quantification of the synthetic acaricides fluvalinate, coumaphos, bromopropylate and its metabolite 4,4'-dibromobenzophenone in beeswax has been developed. Different techniques were tested and modified. The method consists of a sample preparation with isooctane followed by solid phase extraction using Florisil columns. Determination of the synthetic acaricides is achieved by HPLC with a photodiode array detector. Analytical performance of the proposed method, including sensitivity, accuracy and precision was satisfactory. The LOD for the analytes varied between 0.1 and 0.2 microg g(-1) wax and the recoveries between 70 and 110%. Relative standard deviation of the repeatability of the method is <15% and reproducibility is <31%.

  14. A theoretical study of improved front-illuminated avalanche drift detectors

    NASA Astrophysics Data System (ADS)

    Liang, K.; Yuan, J.; Li, H. R.; Yang, R.; Han, D. J.

    2013-06-01

    In this study, two avalanche drift detector (ADD) concepts were theoretically examined. One was an improved detector with an avalanche photodiode (APD) collecting and double pn-junction drift configuration, and the other was a combination of an APD collecting and metal oxide semiconductor (MOS) drift structure. The feasibility of the devices was theoretically investigated by the ISE-TCAD program. ADD can be operated in either Geiger mode or linear mode. In the former case, the detector was found to be appropriate for a single photon avalanche detector with a large collection area. In the latter case, the detector was observed to be well suited to be coupled to a scintillator for gamma-ray detection. The improved ADDs are considered to have good performances in the short wavelength optical detection and in matching common scintillation crystals with more flexibility.

  15. Enhanced photoresponse of conformal TiO{sub 2}/Ag nanorod array-based Schottky photodiodes fabricated via successive glancing angle and atomic layer deposition

    SciTech Connect

    Haider, Ali; Biyikli, Necmi; Cansizoglu, Hilal; Cansizoglu, Mehmet Fatih; Karabacak, Tansel; Okyay, Ali Kemal

    2015-01-01

    In this study, the authors demonstrate a proof of concept nanostructured photodiode fabrication method via successive glancing angle deposition (GLAD) and atomic layer deposition (ALD). The fabricated metal-semiconductor nanorod (NR) arrays offer enhanced photoresponse compared to conventional planar thin-film counterparts. Silver (Ag) metallic NR arrays were deposited on Ag-film/Si templates by utilizing GLAD. Subsequently, titanium dioxide (TiO{sub 2}) was deposited conformally on Ag NRs via ALD. Scanning electron microscopy studies confirmed the successful formation of vertically aligned Ag NRs deposited via GLAD and conformal deposition of TiO{sub 2} on Ag NRs via ALD. Following the growth of TiO{sub 2} on Ag NRs, aluminum metallic top contacts were formed to complete the fabrication of NR-based Schottky photodiodes. Nanostructured devices exhibited a photo response enhancement factor of 1.49 × 10{sup 2} under a reverse bias of 3 V.

  16. Instrumentation: Photodiode Array Detectors in UV-VIS Spectroscopy. Part II.

    ERIC Educational Resources Information Center

    Jones, Dianna G.

    1985-01-01

    A previous part (Analytical Chemistry; v57 n9 p1057A) discussed the theoretical aspects of diode ultraviolet-visual (UV-VIS) spectroscopy. This part describes the applications of diode arrays in analytical chemistry, also considering spectroelectrochemistry, high performance liquid chromatography (HPLC), HPLC data processing, stopped flow, and…

  17. Instrumentation: Photodiode Array Detectors in UV-VIS Spectroscopy. Part II.

    ERIC Educational Resources Information Center

    Jones, Dianna G.

    1985-01-01

    A previous part (Analytical Chemistry; v57 n9 p1057A) discussed the theoretical aspects of diode ultraviolet-visual (UV-VIS) spectroscopy. This part describes the applications of diode arrays in analytical chemistry, also considering spectroelectrochemistry, high performance liquid chromatography (HPLC), HPLC data processing, stopped flow, and…

  18. Control and dynamic range extension of linear photodiode arrays by a single board computer

    NASA Astrophysics Data System (ADS)

    McGeorge, Scott W.; Salin, Eric D.

    A complete interface for data acquisition and control of Reticon Series arrays utilizing an inexpensive microcomputer (Rockwell AIM-65) is described and with specific application to atomic spectra (ICP), data collection techniques are illustrated that provide a dynamic range extension for intense signals.

  19. High-performance liquid chromatographic peak identification of 2,4-dinitrophenylhydrazine derivatives of lipid peroxidation aldehydes by photodiode array detection.

    PubMed

    Cordis, G A; Das, D K; Riedel, W

    1998-03-06

    Malonaldehyde (MDA), a product of lipid peroxidation, is a presumptive marker for the development of oxidative stress in tissues and plasmas. In this study we report the photodiode array detection of the 2,4-dinitrophenylhydrazine (DNPH) derivatives of MDA using HPLC. Oxidative stress was produced by injecting (i.p.) bacterial lipopolysaccharide (LPS) into rats at a dose of 100 micrograms/kg, or i.v. into rabbits (1 microgram/kg), or added to freshly drawn human blood (200 ng/ml). Blood was collected at several time points up to 5 h, centrifuged, and equal volumes of 20% TCA were used to precipitate proteins from the plasma. The supernatants were derivatized with DNPH, and the aldehyde-DNPHs were extracted with pentane. After evaporation, aliquots of 10 microliters in acetonitrile were injected onto a Beckman Ultrasphere C18 (3 microns) column, chromatographed with an acetonitrile-water-acetic acid gradient mobile phase and scanned using Waters 996 photodiode array detector. Peak identification and homogeneity was determined by comparing the experimental peaks and UV scans with those of authentic standards. A significant increase in the DNPH derivative of malonaldehyde (MDA-DNPH), but not of the other aldehyde-DNPH derivatives of formaldehyde (FDA), acetaldehyde (ADA), acetone and propionaldehyde (PDA) was seen over the first hour after LPS administration in anesthetized rats, while in conscious rabbits this trend lasted up to 3 h. The retention times as well as the UV scans of the derivatized aldehydes matched the authentic standards. Thus, photodiode array detection has proved valuable in establishing this HPLC method for estimating oxidative stress. This technique could accurately measure pmol amounts of MDA-DNPH indicating the usefulness of photodiode array detection method for estimating small changes in the oxidative stress.

  20. Quantitative analysis and chromatographic fingerprinting for the quality evaluation of Forsythia suspensa extract by HPLC coupled with photodiode array detector.

    PubMed

    Xia, Yonggang; Yang, Bingyou; Wang, Qiuhong; Liang, Jun; Wei, Youhe; Yu, Hedan; Zhang, Qingbo; Kuang, Haixue

    2009-12-01

    A simple and reproducible HPLC-photodiode array detector method has been described for evaluating and controlling quality of Forsythia suspensa extract (FSE). First, by analysis of chromatographic fingerprints, the similarities of chromatograms of FSE samples from the same pharmaceutical company exceeded 0.999, 0.997 and 0.960, respectively, although they were much lower from different pharmaceutical companies. Second, by further comparing many batches of extract chromatograph charts with the corresponding reference herb materials, the "common peaks" 3, 5, 7 and 10 were defined as "marker peaks", which were identified as (+)-pinoresinol-beta-D-glucoside, forsythiaside, phillyrin and phillygenin, respectively. Third, four "marker peaks" were simultaneously determined based on fingerprint chromatogram for further controlling the quality of FSE quantitatively. Namely, the newly developed method was successfully applied to analyze 38 batches of FSE samples supplied by three pharmaceutical factories, which showed acceptable linearity, intra-day precision (RSD<2.76%), inter-day precision (RSD<3.43%) and the average recovery rates in the range of (95.38+/-2.96)% to (101.60+/-3.08)%. At last, hierarchical clustering analysis and Bayes discriminant analysis statistical methods were used to classify and differentiate the 38 FSE samples to provide the basis for guiding reasonable use of FSE and controlling its quality better.

  1. Optimization and validation of an HPLC-photodiode array detector method for determination of organic acids in vinegar.

    PubMed

    Zong, Yingying; Lin, Jia; Xu, Hua; Jia, Zhihui; Yang, Xiupei; Choi, Martin M F

    2015-01-01

    A novel isocratic RP-HPLC method with UV photodiode array detection for the determination of seven organic acids in vinegar samples was developed and optimized. Samples were analyzed on a C18 (150 × 4.6 mm id, 5 μm) analytical column. Methanol-0.010 M sodium dihydrogen phosphate buffer adjusted with H3PO4 to pH 2.80 (2 + 98, v/v), was used as the mobile phase. The column oven temperature was optimized at 23.0°C, the flow rate was 0.80 mL/min, and the detection wavelength was 210 nm. Matrix-matched calibration curves were prepared for all analytes, and the correlation coefficients were greater than 0.99. LOD and LOQ ranged from 0.10 to 10.0 and 0.30 to 30.0 μg/mL, respectively. The results for interday and intraday precision and accuracy fell within the ranges specified. Vinegar samples were quantified by the standard addition method. The main advantages of this method are its selectivity, which is one of the main weaknesses of most methods when determining organic acids in complex matrixes, and its simplicity since little sample preparation is needed. Moreover, it is safe and inexpensive with low organic solvent usage.

  2. Study of flavonoids of Sechium edule (Jacq) Swartz (Cucurbitaceae) different edible organs by liquid chromatography photodiode array mass spectrometry.

    PubMed

    Siciliano, Tiziana; De Tommasi, Nunziatina; Morelli, Ivano; Braca, Alessandra

    2004-10-20

    A liquid chromatography-mass spectrometry (LC-MS)-based method was developed for the characterization of flavonoids from Sechium edule (Jacq) Swartz (Cucurbitaceae) edible organs, a plant cultivated since pre-Colombian times in Mexico where the fruit is called chayote. Chayote is used for human consumption in many countries; in addition to the fruits, stems, leaves and the tuberous part of the roots are also eaten. Eight flavonoids, including three C-glycosyl and five O-glycosyl flavones, were detected, characterized by nuclear magnetic resonance spectroscopic data, and quantified in roots, leaves, stems, and fruits of the plant by LC-photodiode array-MS. The aglycone moieties are represented by apigenin and luteolin, while the sugar units are glucose, apiose, and rhamnose. The results indicated that the highest total amount of flavonoids was in the leaves (35.0 mg/10 g of dried part), followed by roots (30.5 mg/10 g), and finally by stems (19.3 mg/10 g). Copyright 2004 American Chemical Society

  3. Identification of chlorophylls and carotenoids in major teas by high-performance liquid chromatography with photodiode array detection.

    PubMed

    Suzuki, Yasuyo; Shioi, Yuzo

    2003-08-27

    The separation and identification of pigments, chlorophylls, and carotenoids of seven teas and fresh leaf of tea (Camellia sinensis) by high-performance liquid chromatography (HPLC) are described. HPLC was carried out using a Symmetry C(8) column with a photodiode array detector. Pigments were eluted with a binary gradient of aqueous pyridine solution at a flow rate of 1.0 mL/min at 25 degrees C. HPLC analyses achieved the separation of more than 100 pigment peaks, and 79 pigment species, 41 chlorophylls, and 38 carotenoids were detected. The presence of degraded chlorophylls was a common feature, and the number and the variety of pigments differed with tea species. Generally, the numbers of chlorophyll species tended to increase with processing steps, while carotenoid species were decreased, especially by heating. Particularly in green teas, a change of carotenoid structure, conversion of violaxanthin to auroxanthin, occurred. In hot water extracts of teas, both chlorophylls and carotenoids were also detected, but the concentration of chlorophylls was less than 2% as compared with acetone extracts. The pigment compositions were compared between tea species, and they are discussed in terms of the differences in their manufacturing processes.

  4. Determination of total phthalates in edible oils by high-performance liquid chromatography coupled with photodiode array detection.

    PubMed

    Xie, Qilong; Sun, Dekui; Han, Yangying; Jia, Litao; Hou, Bo; Liu, Shuhui; Li, Debao

    2016-03-01

    The previously reported procedure for the determination of the total phthalate in fatty food involved the extraction of phthalates using chloroform/methanol followed by the removal of the solvents before alkaline hydrolysis requiring 20 h and derivatization of phthalic acid. In this study, a phase-transfer catalyst (tetrabutylammonium chloride) was used in the liquid-liquid heterogeneous hydrolysis of phthalates in oil matrix shortening the reaction time to within 25 min. The resulting phthalic acid in the hydrolysate was extracted by a novel molecular complex based dispersive liquid-liquid microextraction method coupled with back-extraction before high-performance liquid chromatography coupled with photodiode array detection. Under the optimal experimental conditions, the linearity of the method was in the range of 0.5-12 nmol/g with the correlation coefficients (r) >0.997. The detection limit (S/N = 3) was 0.11 nmol/g. Intraday and interday repeatability values expressed as relative standard deviation were 3.9 and 7.1%, respectively. The recovery rates ranged from 82.4 to 99.0%. The developed method was successfully applied for the analysis of total phthalate in seven edible oils.

  5. Cytotoxicity, In vitro anti-Leishmanial and fingerprint HPLC- photodiode array analysis of the roots of Trillium govanianum.

    PubMed

    Khan, Kashif Maqbool; Nahar, Lutfun; Mannan, Abdul; Ul-Haq, Ihsan; Arfan, Muhammad; Ali Khan, Ghazanfar; Hussain, Izhar; Sarker, Satyajit D

    2017-09-05

    Trillium govanianum Wall. ex D. Don (Melanthiaceae alt. Trilliaceae), commonly known as 'nagchhatry' or 'teen patra', distributed from Pakistan to Bhutan about 2500-3800 m altitude is indigenous to Himalayas region. In folk medicine the plant has been reported for the treatment of wound healing, sepsis and in various sexual disorders. This paper reports, for the first time, to evaluate the cytotoxicity, in vitro anti-leishmanial (promastigotes) and fingerprint HPLC-photodiode array analysis of the MeOH extract of the roots of T. govanianum and its solid phase extraction fractions. Reverse phase HPLC-PDA based quantification revealed the presence of significant amount of quercetin, myrecetin and kaemferol ranging from 0.221to 0.528 μg/mg DW. MeOH extract revealed distinguishable protein kinase inhibitory activity against Streptomyces 85E strain with 18 mm bald phenotype. The remarkable toxicity profile against brine shrimps and leishmanial was manifested by MeOH extract with LC50 10 and 38.5 μg/mL, respectively.

  6. Fingerprint Analysis of Desmodium Triquetrum L. Based on Ultra Performance Liquid Chromatography with Photodiode Array Detector Combined with Chemometrics Methods.

    PubMed

    Zhang, Meiling; Zhao, Cui; Liang, Xianrui; Ying, Yin; Han, Bing; Yang, Bo; Jiang, Cheng

    2016-01-01

    A fingerprinting approach was developed by means of ultra high-performance liquid chromatography with photodiode array detector for the quality control of Desmodium triquetrum L., an herbal medicine widely used for clinical purposes. Ten batches of raw material samples of D. triquetrum were collected from different regions of China. All UPLC analyses were carried out on a Waters ACQUITY UPLC BEH shield RP18 column (2.1 × 50 mm, 1.7 µm particle size) at 60°C, with a gradient mobile phase composed of 0.1% aqueous formic acid and acetonitrile at a flow rate of 0.45 mL/min. The method validation results demonstrated the developed method possessing desirable reproducibility, efficiency, and allowing fingerprint analysis in one chromatographic run within 13 min. The quality assessment was achieved by using chemometrics methods including similarity analysis, hierarchical clustering analysis and principal component analysis. The developed method can be used for further quality control of D. triquetrum.

  7. Chromatographic fingerprinting analysis of Zhizhu Wan preparation by high-performance liquid chromatography coupled with photodiode array detector.

    PubMed

    Sun, Hui; Chen, Xi; Zhang, Aihua; Sakurai, Tetsuro; Jiang, Jinzhong; Wang, Xijun

    2014-10-01

    Traditional Chinese medicine (TCM) formula has been used for over 1000 years and most of them contain complicate chemical constituents. Chromatographic fingerprinting has been widely accepted as a crucial method for qualitative and quantitative analyses for TCM. Zhi Zhu Wan (ZZW), a classical Chinese medical formula, has been commonly used for the treatment of gastrointestinal disease, which pose a serious challenge to its quality control. In this work, a sensitive and reliable method of high-performance liquid chromatography coupled with photodiode array detector (HPLC-PDA) was developed to control the quality of ZZW for chemical fingerprint analysis and quantitative analysis of four major bioactive constituents, including hesperidin, naringin, neohesperidin, and atractylenolide I. The chromatographic separation was performed on a Waters Symmetry C18 column (4.6 mm × 250 mm, 5 μm particle size), with an aqueous 0.095% phosphate acid and acetonitrile mobile phase gradient. Optimization of other experimental conditions was validated with satisfactory accuracy, precision, repeatability, and recovery. In quantitative analysis, the four components showed good regression (R > 0.9994) within test ranges, and the recovery method ranged from 99.32% to 100.630%. HPLC fingerprints of the ZZW samples were compared by performing similarity analysis. The results indicated that the newly developed HPLC-PDA fingerprint method would be suitable for quality control of ZZW.

  8. Geiger-Mode Avalanche Photodiode Arrays Integrated to All-Digital CMOS Circuits

    DTIC Science & Technology

    2016-01-20

    bump bonds or through-silicon vias used in some wafer stacking processes. The process can be...function as bump bonds, but are much smaller) are patterned on each wafer and planarized along with the bonding oxide. When the wafers are bonded and...pads, the APD array is integrated with a CMOS readout circuit, using either bump bonding or a 3D integration technique. During this process

  9. The SAPHIRA Near-Infrared Avalanche Photodiode Array: Telescope Deployments and Future Developments

    NASA Astrophysics Data System (ADS)

    Atkinson, Dani Eleanor; Hall, Donald; Baranec, Christoph

    2015-01-01

    We present our recent achievements of the Selex SAPHIRA APD arrays, which this year have seen deployment at three different telescopes, most notably demonstrating tip-tilt wavefront sensing in conjunction with the Palomar 1.5-m Telescope's Robo-AO system. A cooperative effort to provide enhanced speckle nulling capability to the SCExAO instrument on the Subaru telescope is also underway. We present the progress and development timeframe for the SAPHIRA and expected future applications, including targets and observational parameter space we expect the detectors to open to the astronomical community.

  10. Range imaging pulsed laser sensor with two-dimensional scanning of transmitted beam and scanless receiver using high-aspect avalanche photodiode array for eye-safe wavelength

    NASA Astrophysics Data System (ADS)

    Tsuji, Hidenobu; Imaki, Masaharu; Kotake, Nobuki; Hirai, Akihito; Nakaji, Masaharu; Kameyama, Shumpei

    2017-03-01

    We demonstrate a range imaging pulsed laser sensor with two-dimensional scanning of a transmitted beam and a scanless receiver using a high-aspect avalanche photodiode (APD) array for the eye-safe wavelength. The system achieves a high frame rate and long-range imaging with a relatively simple sensor configuration. We developed a high-aspect APD array for the wavelength of 1.5 μm, a receiver integrated circuit, and a range and intensity detector. By combining these devices, we realized 160×120 pixels range imaging with a frame rate of 8 Hz at a distance of about 50 m.

  11. Mechanics of cadmium telluride-zinc telluride nucleation on (112) Si for mercury cadmium telluride infrared photo-diode arrays

    NASA Astrophysics Data System (ADS)

    Dhar, Nibir Kumar

    , suggesting growth nucleates on and propagates two dimensionally along step edges. The present study treats the mechanics of ZnTe nucleation on Si. The associated kinetic barriers can be tailored to improve epitaxy. An improved HgCdTe planar heterojunction p/n infrared photodiode array was fabricated using the new CADRE technique.

  12. Residue level and dissipation pattern of lepimectin in shallots using high-performance liquid chromatography coupled with photodiode array detection.

    PubMed

    Kim, Sung-Woo; Rahman, Md Musfiqur; Abd El-Aty, A M; Truong, Lieu T B; Choi, Jeong-Heui; Park, Joon-Seong; Kim, Mi-Ra; Shin, Ho-Chul; Shim, Jae-Han

    2016-11-01

    Lepimectin, as an emulsifiable concentrate, was sprayed on shallots at the recommended dose rate (10 mL/20 L) to determine its residue levels, dissipation pattern, pre-harvest residue limits (PHRLs), and health risk. Samples were randomly collected over 10 days, extracted with acetonitrile, purified using an amino solid-phase extraction (NH2 -SPE) cartridge and analyzed using a high-performance liquid chromatography-photodiode array detection method. Field-incurred samples were confirmed using ultra-performance liquid chromatography-tandem mass spectrometry. The linearity was excellent, with a determination coefficient (R(2) ) of ≥0.9991. The recoveries at two spiking levels (0.2 and 1.0 mg/kg) ranged from 84.49 to 87.64% with relative standard deviations of ≤7.04%. The developed method was applied to field samples grown in separate greenhouses, one located in Naju and one in Muan, in the Republic of Korea. The dissipation pattern was described by first-order kinetics with half-lives of 1.9 (Naju) and 1.7 days (Muan). The PHRL curves indicated that, if the lepimectin residues are <0.18 (Naju) and <0.13 mg/kg (Muan) 5 days before harvest, the residue levels will be lower than the maximum residue limit (0.05 mg/kg) upon harvesting. The risk assessment data indicated that lepimectin is safe for use in the cultivation of shallots, with no risk of detrimental effects to the consumer.

  13. Simultaneous determination of eperisone hydrochloride and paracetamol in mouse plasma by high performance liquid chromatography-photodiode array detector.

    PubMed

    Locatelli, Marcello; Cifelli, Roberta; Di Legge, Cristina; Barbacane, Renato Carmine; Costa, Nicola; Fresta, Massimo; Celia, Christian; Capolupo, Carlo; Di Marzio, Luisa

    2015-04-03

    This paper reports the validation of a quantitative high performance liquid chromatography-photodiode array (HPLC-PDA) method for the simultaneous analysis, in mouse plasma, of eperisone hydrochloride and paracetamol by protein precipitation using zinc sulphate-methanol-acetonitrile. The analytes were resolved on a Gemini C18 column (4.6 mm × 250 mm; 5 μm particle size) using a gradient elution mode with a run time of 15 min, comprising re-equilibration, at 60°C (± 1°C). The method was validated over the concentration range from 0.5 to 25 μg/mL for eperisone hydrochloride and paracetamol, in mouse plasma. Ciprofloxacin was used as Internal Standard. Results from assay validations show that the method is selective, sensitive and robust. The limit of quantification of the method was 0.5 μg/mL for eperisone hydrochloride and paracetamol, and matrix-matched standard curves showed a good linearity, up to 25 μg/mL with correlation coefficients (r(2))≥ 0.9891. In the entire analytical range the intra and inter-day precision (RSD%) values were ≤ 1.15% and ≤ 1.46% for eperisone hydrochloride, and ≤ 0.35% and ≤ 1.65% for paracetamol. For both analytes the intra and inter-day trueness (bias%) values ranged, respectively, from -5.33% to 4.00% and from -11.4% to -4.00%. The method was successfully tested in pharmacokinetic studies after oral administration in mouse. Furthermore, the application of this method results in a significant reduction in terms of animal number, dosage, and improvement in speed, rate of analysis, and quality of pharmacokinetic parameters related to serial blood sampling. Copyright © 2015 Elsevier B.V. All rights reserved.

  14. Computer-aided strategies for archive retrieval and sensitivity enhancement in the identification of drugs by photodiode array detection in high-performance liquid chromatography.

    PubMed

    Fell, A F; Clark, B J; Scott, H P

    1984-12-21

    An archive retrieval algorithm for high-performance liquid chromatography with UV detection (HPLC-UV) has been developed for the first time for the rapid identification of spectra acquired by rapid-scanning photodiode array detection in HPLC. The algorithm is based on a database of spectra (normalised with respect to area), inverse files of key spectral features, a selective search window, with parabolic weighting factors and least-squares comparison of test and retrieved spectra. The performance of the library search system is demonstrated with respect to a small library of solutes, including: cortisone acetate, ethynyl estradiol, ethisterone, progesterone; caffeine, theobromine, theophylline and 8-chlorotheophylline; morphine and diamorphine; and cycloserine. Since photodiode array detection operates in the domains of both wavelength and time, to generate a matrix of (A, lambda, t) data, the optimum conditions for sensitivity enhancement by ensemble averaging in these domains have been examined. At a given observation wavelength, increase in the detector bandwidth (or "diode bunching") yields a value of delta lambda which gives optimum sensitivity; this value is systematically related to the spectral bandwidth of the analyte. Sensitivity can also be optimised by varying the integration period in the time domain. Sensitivity can be further increased by combination of these instrumental optima, for which there is evidence of dependence on the particular instrument design. Response was found to be linear for detector bandwidths up to twice the optimum value. The comparative sensitivity of some commercially-available photodiode array detectors has been assessed relative to that of conventional detectors under strictly controlled conditions.

  15. Integration of a concentric five element InAIAs/InGaAs avalanche photodiode array in a stabilized bi-static optical assembly

    NASA Astrophysics Data System (ADS)

    Ferraro, Mike S.; Mahon, Rita; Rabinovich, William S.; Murphy, James L.; Freeman, Wade T.; Frawley, Steve; Goetz, Peter G.; Burris, Harris R.; Thomas, Linda M.; Clark, William R.; Waters, William D.; Vaccaro, Kenneth; Krejca, Brian; Mathieu, Barry M.

    2014-06-01

    In free space optical communication, photodetectors serve not only as communications receivers but as position sensitive detectors (PSD) for pointing, tracking, and stabilization. Typically, two separate detectors are utilized to perform these tasks but recent advances in the fabrication and development of large area, low noise avalanche photodiode (APD) arrays have enabled these devices to be used both as PSDs and as data communication receivers. This combined functionality allows for more flexibility and simplicity in optical assembly design without sacrificing the sensitivity and bandwidth performance of smaller, single element data receivers. This work presents a large area, five element concentric avalanche photodiode array rated for bandwidths beyond 1GHz with a measured carrier ionization ratio of approximately 0.2 at moderate APD gains. We discuss the integration of this array in a bi-static optical interrogator where it acts as a data receiver and provides position information for pointing and stabilization. In addition to front-end and digital electronics design, we also describe the optical assembly design and the development of a pointing and stabilization algorithm.

  16. A linear photodiode array employed in a short range laser triangulation obstacle avoidance sensor. M.S. Thesis; [Martian roving vehicle sensor

    NASA Technical Reports Server (NTRS)

    Odenthal, J. P.

    1980-01-01

    An opto-electronic receiver incorporating a multi-element linear photodiode array as a component of a laser-triangulation rangefinder was developed as an obstacle avoidance sensor for a Martian roving vehicle. The detector can resolve the angle of laser return in 1.5 deg increments within a field of view of 30 deg and a range of five meters. A second receiver with a 1024 elements over 60 deg and a 3 meter range is also documented. Design criteria, circuit operation, schematics, experimental results and calibration procedures are discussed.

  17. High-performance liquid chromatography with photodiode array detection for determination of nobiletin content in the brain and serum of mice administrated the natural compound.

    PubMed

    Saigusa, Daisuke; Shibuya, Masatoshi; Jinno, Daisuke; Yamakoshi, Hiroyuki; Iwabuchi, Yoshiharu; Yokosuka, Akihito; Mimaki, Yoshihiro; Naganuma, Akira; Ohizumi, Yasushi; Tomioka, Yoshihisa; Yamakuni, Tohru

    2011-07-01

    We recently demonstrated that nobiletin, a citrus flavonoid, exhibits anti-dementia action in animals. However, no determination methods for the content of nobiletin with beneficial action in the brain of nobiletin-administered animals have been developed, nor has its pharmacokinetics been revealed completely. Here, we established the high-performance liquid chromatography/photodiode array detection method for nobiletin determination using Bond Elut C18 SPE cartridges for extraction, where the calibration curve was linear over 0.025-10 ng, with coefficient of variation of less than 6.76%. This method enabled us to determine pharmacokinetic parameters of nobiletin given intraperitoneally or per os in the brain of mice.

  18. Front-illuminated CCD with open pinned-phase region and two-phase transfer gate regions

    NASA Technical Reports Server (NTRS)

    Janesick, James R. (Inventor)

    1991-01-01

    A front-illuminated CCD of relative high quantum efficiency (QE) and high charge transfer efficiency (CTE) utilizes an open-phase region for receiving photons and two-phase gate regions (.phi..sub.1 and .phi..sub.2) for transferring electrons collected in one pixel to the next. The open-phase region is implanted with additional n-type elements (phosphorus) in order to increase the potential of the CCD channel in the open-phase region for collection of electrons and additionally implanted with concentrated and very shallow p-type elements (boron) to pin the surface of the n-channel in the open-phase region to OV, while gate region .phi..sub.1 and .phi..sub.2 are biased to -3.5V and driven to +10V by a two-phase transfer clock. The open pinned-phase (OPP) region thus permits two-phase transfer clocking and optimum reception of photons during the integration periods between transfer clock pulses.

  19. Simultaneous determination of seven lignans in Justicia procumbens by high performance liquid chromatography-photodiode array detection using relative response factors.

    PubMed

    Luo, Zuliang; Kong, Weijun; Qiu, Feng; Yang, Meihua; Li, Qian; Wei, Riwei; Yang, Xiaoli; Qin, Jieping

    2013-02-01

    A simple and sensitive HPLC coupled with photodiode array (HPLC-PDA) method was developed for simultaneous determination of seven lignans in Justicia procumbens using relative response factors (RRFs). The chromatographic separation was performed on a Shiseido Capcell Pak C(18) column (250 × 4.6 mm id, 5 μm), a gradient elution of acetonitrile/water, and a photodiode array detector. The column temperature was maintained at 35°C and the detection wavelength was set at 256 nm. Chinensinaphthol methyl ether was selected as the reference compound for calculating the relative response factors of the lignans. It has shown that the RRFs for lignans are quite similar at 256 nm of detection under different analytical conditions (different columns and HPLC instruments). Using RRFs, not every lignan is needed as a reference standard, making the method ideal for rapid, routine analysis, especially for those laboratories where lignans standards are not readily available. An economic and practicable HPLC method using RRFs was established for the determination of seven lignans in J. procumbens. This method not only can determine multiple indexes in traditional Chinese medicines (TCMs) simultaneously, but also resolve the problem of lacking of chemical standards. It will be a good quality evaluation method and pattern for TCMs. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Simultaneous determination of flavonoids in different parts of Citrus reticulata 'Chachi' fruit by high performance liquid chromatography-photodiode array detection.

    PubMed

    Sun, Yinshi; Wang, Jianhua; Gu, Shubo; Liu, Zhengbo; Zhang, Yujie; Zhang, Xiaoxia

    2010-08-05

    Flavonoids are important polyphenolic secondary metabolites in plant. Citrus reticulata 'Chachi' fruit are rich in flavonoids and are being used as functional antioxidant ingredients for the treatment of atherosclerosis and cancer, etc. A high performance liquid chromatography-photodiode array detection system was used to analyze five flavonoids, namely, naringin, hesperidin, didymin, tangeretin and nobiletin, in different parts of C. reticulata 'Chachi' fruit. The chromatographic analysis was performed on a C(18) column with a gradient elution of acetonitrile and water at a flow rate of 1.0 mL/min. Detection was carried out using a photodiode array detector at 280 nm. The calibration curves for the determination of all analytes showed good linearity over the investigated ranges (R2 > 0.9995). Precision and reproducibility were evaluated by six replicated analyses, and the R.S.D. values were less than 0.9% and 2.7%. The recoveries were between 98.37 and 103.89%. This method is promising to improve the quality control of different parts of C. reticulata 'Chachi' fruit.

  1. Spectroscopic characterization by photodiode array detection of human urinary and amniotic protein HC subpopulations fractionated by anion-exchange and size-exclusion high-performance liquid chromatography.

    PubMed

    Calero, M; Escribano, J; Soriano, F; Grubb, A; Brew, K; Méndez, E

    1996-01-05

    A procedure for spectroscopic characterization and partial fractionation of human protein HC populations by high-performance liquid chromatography-photodiode array ultraviolet-visible detection is reported. Human protein HC from urine or amniotic fluid fractionated by anion-exchange HPLC in a protein Pak DEAE 5PW appeared to be heterogeneous as judged by the asymmetric elution pattern, consisting of a continuous irregular broad peak with several shoulders distributed along the whole chromatogram. Selected fractions containing shoulders were rechromatographed and finally six symmetrical homogeneous peaks with different retention times were obtained from each protein HC preparation. The direct automatic absorption spectra analyses at each peak maximum, indicated that all of the homogeneous peaks seemed to be protein HC, all of them associated to the same chromophore although with different stoichiometry ratios. Isoelectric focusing showed that each peak was composed of a limited number of subpopulations of protein HC with different isoelectric points. Size microheterogeneity has been also demonstrated in both urinary and amniotic protein HC preparations by a combination of size-exclusion HPLC on a TSK 3000 SW6 column and photodiode array detection. Partial fractionation of human albumin on an analytical anion-exchange Mono-Q PC 1.6/5 column, has allowed the identification of heterogeneous chromophore-containing populations displaying significant absorption in the visible region in resemblance to that of protein HC.

  2. Nuclear resonant scattering measurements on {sup 57}Fe by multichannel scaling with a 64-pixel silicon avalanche photodiode linear-array detector

    SciTech Connect

    Kishimoto, S. Haruki, R.; Mitsui, T.; Yoda, Y.; Taniguchi, T.; Shimazaki, S.; Ikeno, M.; Saito, M.; Tanaka, M.

    2014-11-15

    We developed a silicon avalanche photodiode (Si-APD) linear-array detector for use in nuclear resonant scattering experiments using synchrotron X-rays. The Si-APD linear array consists of 64 pixels (pixel size: 100 × 200 μm{sup 2}) with a pixel pitch of 150 μm and depletion depth of 10 μm. An ultrafast frontend circuit allows the X-ray detector to obtain a high output rate of >10{sup 7} cps per pixel. High-performance integrated circuits achieve multichannel scaling over 1024 continuous time bins with a 1 ns resolution for each pixel without dead time. The multichannel scaling method enabled us to record a time spectrum of the 14.4 keV nuclear radiation at each pixel with a time resolution of 1.4 ns (FWHM). This method was successfully applied to nuclear forward scattering and nuclear small-angle scattering on {sup 57}Fe.

  3. A Comparison of DEF X-Ray Film and a Photodiode Array (Reticon) as Detectors for an X-Ray Crystal Spectrometer.

    PubMed

    Goodman, D A; Eason, R W; Shiwai, B; Allinson, N; Magorrian, B; Grande, M; Ridgley, A

    1989-01-01

    A crystal spectrometer with a photodiode array (PDA) detector was tested for a range of x-ray energies between 1 and 2 keV. A laser-produced plasma has been used as an x-ray source and was generated by the high-power (Vulcan) glass laser system at the SERC Rutherford Appleton Laboratory, UK. The performance of the array was directly compared with the response of Kodak DEF x-ray film. In order to compare quantitatively the performances of the PDA and the film, detective quantum efficiency (DQE) considerations are presented for both devices. It is demonstrated that the PDA has a useful dynamic range which is approximately seven times greater than that of film, a peak DQE of approximately six times that of film, and a greatly superior low-signal performance. The operational characteristics of the PDA are discussed.

  4. Nuclear resonant scattering measurements on (57)Fe by multichannel scaling with a 64-pixel silicon avalanche photodiode linear-array detector.

    PubMed

    Kishimoto, S; Mitsui, T; Haruki, R; Yoda, Y; Taniguchi, T; Shimazaki, S; Ikeno, M; Saito, M; Tanaka, M

    2014-11-01

    We developed a silicon avalanche photodiode (Si-APD) linear-array detector for use in nuclear resonant scattering experiments using synchrotron X-rays. The Si-APD linear array consists of 64 pixels (pixel size: 100 × 200 μm(2)) with a pixel pitch of 150 μm and depletion depth of 10 μm. An ultrafast frontend circuit allows the X-ray detector to obtain a high output rate of >10(7) cps per pixel. High-performance integrated circuits achieve multichannel scaling over 1024 continuous time bins with a 1 ns resolution for each pixel without dead time. The multichannel scaling method enabled us to record a time spectrum of the 14.4 keV nuclear radiation at each pixel with a time resolution of 1.4 ns (FWHM). This method was successfully applied to nuclear forward scattering and nuclear small-angle scattering on (57)Fe.

  5. Readout characteristics of integrated monolithic InGaAs active pixel sensor array

    NASA Astrophysics Data System (ADS)

    Kim, Quiesup; Cunningham, Thomas J.; Pain, Bedabrata; Lange, Michael J.; Olsen, Gregory H.

    1997-12-01

    A newly fabricated monolithic InGaAs active pixel image sensor is presented, and its readout characteristics are described. The sensor is fabricated from InGaAs epitaxially deposited on an InP substrate. It consists of an InGaAs photodiode connected to InP depletion-mode junction field effect transistors (JFETs) for signal buffering, selection and reset. The monolithic sensor eliminates the need for hybridization with a silicon multiplexer, and in addition, allows the sensor to be front illuminated, making it sensitive to visible as well as IR radiation. With further development, the sensor is ideal for dual band (visible/IR) applications, including optical communication. It is also well suited to applications requiring near room temperature, broad band response such as for atmospheric gas sensing and target identification. Two different types of small 4 by 1 test arrays have been fabricated. One is a source follower per detector architecture. Here the signal charge is integrated on the photodiode capacitance. The photodiode is connected to a gate of a JFET configured as a source-follower, which buffers the photodiode voltage. The other test circuit uses a capacitive transimpedance amplifier. This circuit contains an invertor using an input JFET with a passive JFET load. The photodiode is connected to the JFET gate. A feedback capacitor causes the circuit to act as an integrator, while keeping the diode input bias relatively constant. Both circuits also contain JFET switches for reset and selection. Selection connects the output of the chosen cell onto a common output bus. In this exploratory development effort, the effectiveness of these two different readout circuits will be discussed in terms of leakage, operating frequency, and temperature. These results then will guide for the second phase demonstration of integrated two dimensional monolithic active pixel sensor arrays for application in transportable shipboard surveillance, night vision and emission

  6. Design of Low Power CMOS Read-Out with TDI Function for Infrared Linear Photodiode Array Detectors

    NASA Technical Reports Server (NTRS)

    Vizcaino, Paul; Ramirez-Angulo, Jaime; Patel, Umesh D.

    2007-01-01

    A new low voltage CMOS infrared readout circuit using the buffer-direct injection method is presented. It uses a single supply voltage of 1.8 volts and a bias current of 1uA. The time-delay integration technique is used to increase the signal to noise ratio. A current memory circuit with faulty diode detection is used to remove dark current for background compensation and to disable a photodiode in a cell if detected as faulty. Simulations are shown that verify the circuit that is currently in fabrication in 0.5ym CMOS technology.

  7. Autofocus technique for three-dimensional imaging, direct-detection laser radar using Geiger-mode avalanche photodiode focal-plane array.

    PubMed

    Oh, Min Seok; Kong, Hong Jin; Kim, Tae Hoon; Jo, Sung Eun

    2010-12-15

    An autofocus technique is proposed for a three-dimensional imaging, direct-detection laser radar system that uses a Geiger-mode avalanche photodiode focal plane array (GmAPD-FPA). This technique is implemented by pointing laser pulses on a target of interest and observing its scattered photon distribution on a GmAPD-FPA. Measuring the standard deviation of the photon distribution on a GmAPD-FPA enables the best focus condition to be found. The feasibility of this technique is demonstrated experimentally by employing a 1 × 8 pixel GmAPD-FPA. It is shown that the spatial resolution improves when the GmAPD-FPA is located in the best focus position found by the autofocus technique.

  8. Quantitative and chemical fingerprint analysis for the quality evaluation of Isatis indigotica based on ultra-performance liquid chromatography with photodiode array detector combined with chemometric methods.

    PubMed

    Shi, Yan-Hong; Xie, Zhi-Yong; Wang, Rui; Huang, Shan-Jun; Li, Yi-Ming; Wang, Zheng-Tao

    2012-01-01

    A simple and reliable method of ultra-performance liquid chromatography with photodiode array detector (UPLC-PDA) was developed to control the quality of Radix Isatidis (dried root of Isatis indigotica) for chemical fingerprint analysis and quantitative analysis of eight bioactive constituents, including R,S-goitrin, progoitrin, epiprogoitrin, gluconapin, adenosine, uridine, guanosine, and hypoxanthine. In quantitative analysis, the eight components showed good regression (R > 0.9997) within test ranges, and the recovery method ranged from 99.5% to 103.0%. The UPLC fingerprints of the Radix Isatidis samples were compared by performing chemometric procedures, including similarity analysis, hierarchical clustering analysis, and principal component analysis. The chemometric procedures classified Radix Isatidis and its finished products such that all samples could be successfully grouped according to crude herbs, prepared slices, and adulterant Baphicacanthis cusiae Rhizoma et Radix. The combination of quantitative and chromatographic fingerprint analysis can be used for the quality assessment of Radix Isatidis and its finished products.

  9. High-performance liquid chromatographic confirmation of cocaine and benzoylecgonine in biological samples using photodiode-array detection after toxicological screening.

    PubMed

    Balíková, M; Vecerková, J

    1994-06-03

    In the later stages after intake, the important markers of cocaine abuse are its main metabolites in urine, benzoylecgonine and ecgonine methyl ester. The efficiency of the extraction of amphoteric benzoylecgonine together with cocaine from aqueous media by means of various solvents at various pH values and by means of a mixed solid phase was tested. The extraction of benzoylecgonine with diethyl ether is not efficient, whereas chloroform, dichloromethane or mixed solid-phase extraction give satisfactory results. The analytical strategy for the general chromatographic screening and identification of unknown drugs in biological samples based on diethyl ether extraction was modified to permit the sensitive detection of cocaine abuse also on the basis of benzoylecgonine. A complementary high-performance liquid chromatographic method with photodiode-array detection after solid-phase extraction was introduced for specific confirmation and determination of cocaine and benzoylecgonine.

  10. Simultaneous determination of 16 polycyclic aromatic hydrocarbons in reclaimed water using solid-phase extraction followed by ultra-performance convergence chromatography with photodiode array detection.

    PubMed

    Zhang, Yun; Xiao, Zhiyong; Lv, Surong; Du, Zhenxia; Liu, Xiaoxia

    2016-03-01

    A new fast and effective analysis method has been developed to simultaneously determine 16 polycyclic aromatic hydrocarbons in reclaimed water samples by ultra-performance convergence chromatography with photodiode array detection and solid-phase extraction. The parameters of ultra-performance convergence chromatography on the separation behaviors and the crucial condition of solid-phase extraction were investigated systematically. Under optimal conditions, the 16 polycyclic aromatic hydrocarbons could be separated within 4 min. The limits of detection and quantification were in the range of 0.4-4 and 1-10 μg/L in water, respectively. This approach has been applied to a real industrial wastewater treatment plant successfully. The results showed that polycyclic aromatic hydrocarbons were dramatically decreased after chemical treatment procedure, and the oxidation procedure was effective to remove trace polycyclic aromatic hydrocarbons.

  11. Evaluation of principal components analysis with high-performance liquid chromatography and photodiode array detection for the forensic differentiation of ballpoint pen inks.

    PubMed

    Kher, A A; Green, E V; Mulholland, M I

    2001-07-01

    Inks from seven black and eight blue ballpoint pens were separated by a high-performance liquid chromatography (HPLC) method utilizing a photodiode array detection (PDA). A classifier flowchart was designed for the chromatographic data based on the presence or absence of certain peaks at different wavelengths to qualitatively discriminate between the inks. The same data were quantitatively classified by principal components analysis (PCA) to estimate the separation between a pair of classes of ink samples. It was found that the black ballpoint pen inks were discriminated satisfactorily utilizing two-dimensional data of the peak areas and retention times at the optimum wavelengths. The blue pens were discriminated by analyzing the chromatographic data at four different wavelengths simultaneously with a cross-validated PCA. The results of this study indicated that HPLC-PDA coupled with chemometrics could make a powerful discriminating tool for the forensic chemist, especially when analyzing extensive and/or complex data.

  12. Determination of residues of UV filters in natural waters by solid-phase extraction coupled to liquid chromatography-photodiode array detection and gas chromatography-mass spectrometry.

    PubMed

    Giokas, Dimosthenis L; Sakkas, Vasilios A; Albanis, Triantafyllos A

    2004-02-13

    This study describes a procedure for the enrichment, separation and quantification of four major UV filters in natural waters. Solid-phase extraction combined with liquid chromatography and photodiode array detection (LC-UV-DAD), and gas chromatography with mass spectroscopy (GC-MS) were employed for the analyses. LC of the four compounds with surfactant-modified hydro-organic eluents gave satisfactory resolution of overlapping peaks. In GC, a significant improvement of the detection limits was attained, but only three compounds could be detected. The method was validated for, and applied to, various water samples prone to UV filter accumulation due to recreational activities. Recoveries from real samples were 86-99% with LOQs as low as 0.5 ng/l depending on the sample volume and the analytical procedure.

  13. Simultaneous determination of 12 chemical constituents in the traditional Chinese Medicinal Prescription Xiao-Yao-San-Jia-Wei by HPLC coupled with photodiode array detection.

    PubMed

    Zhang, Hongmin; Chen, Shiwei; Qin, Feng; Huang, Xi; Ren, Ping; Gu, Xinqi

    2008-12-15

    An HPLC-photodiode array (PDA) detection method was established for the simultaneous determination of 12 components in Xiao-Yao-San-Jia-Wei (XYSJW): geniposide, puerarin, paeoniflorin, ferulic acid, liquiritin, hesperidin, naringin, paeonol, daidzein, glycyrrhizic acid, honokiol, and magnolol. These were separated in less than 70 min using a Waters Symmetry Shield RP 18 column with gradient elution using (A) acetonitrile, (B) water, and (C) acetic acid at a flow rate of 1 ml/min, and with a PDA detector. All calibration curves showed good linear regression (r(2)>0.9992) within the test ranges. The method was validated for specificity, accuracy, precision, and limits of detection. The proposed method enables in a single run the simultaneous identification and determination for quality control of 12 multi-structural components of XYSJW forming the basis of its therapeutic effect.

  14. Separation of some mono-, di- and tri-unsaturated fatty acids containing 18 carbon atoms by high-performance liquid chromatography and photodiode array detection.

    PubMed

    Czauderna, M; Kowalczyk, J

    2001-08-25

    Positional and geometric isomers of mono-, di- and tri-unsaturated fatty acids containing 18 carbon atoms were separated on commercially available reversed-phase columns in gradient systems composed of acetonitrile and water, utilizing photodiode array detection. The biological samples were hydrolyzed with 2 M NaOH for 35-40 min at 85-90 degrees C. After cooling, the hydrolysates were acidified with 4 M HCl and the free fatty acids were extracted with dichloromethane. The organic solvent was removed in a gentle stream of argon. The fatty acids were determined after pre-column derivatization with dibromacetophenone in the presence of triethylamine. The reaction components were mixed and reacted for 2 h at 50 degrees C. Separations of derivatized fatty acids were performed on two C18 columns (Nova Pak C18, 4 microm, 250x4.6 mm, Waters) by binary or ternate gradient programs and UV detection at 254 and 235 nm. The geometric and positional isomers of some unsaturated fatty acids were substantially retained on the C18 columns and were distinct from some saturated fatty acids, endogenous substances in biological samples or background interference. Only slight separation of critical pairs of cis-9 C18:1/cis-11 C18:1 and cis-6 C18:1/trans-11 C18:1 was obtained. A ternate gradient program can be used for complete fractionation of a mixture of conjugated linoleic acid isomers (CLA) from cis-9, cis-12 and trans-9, trans-12 isomers of C18:2. The CLA isomers in the effluent were monitored at 235 nm. The CLA isomers were differentiated from saturated and unsaturated fatty acids using a photodiode array detector. The utility of the method was demonstrated by evaluating the fatty acid composition of duodenal digesta, rapeseed and maize oils.

  15. Multi-channel photon counting three-dimensional imaging laser radar system using fiber array coupled Geiger-mode avalanche photodiode

    NASA Astrophysics Data System (ADS)

    Shu, Rong; Huang, Genghua; Hou, Libing; He, Zhiping; Hu, Yihua

    2012-09-01

    Photon counting laser radar is the most sensitive and efficiency detection method of direct-detection laser radar. With the use of Geiger-mode avalanche photodiode (APD) or other single photon detectors, every laser photon could be sufficiently used for ranging and three-dimensional imaging. The average energy of received laser signal could be as low as a single photon, or even less than one. This feature of photon counting laser radar enables ranging under conditions of long range, low laser pulse energy, and multi-pixel detection, while receiver size, mass, power, and complexity of laser radar are reduced. In this paper, a latest multi-channel photon counting 3D imaging laser radar system using fiber array coupled Geiger-mode avalanche photodiode (APD) is introduced. Detection model based on Poisson statistics of a photon counting laser radar is discussed. A laser radar system, working under daylight condition with ultra-low signal level (less than single photon per pulse), has been designed and analyzed with the detection model and photon counting three-dimensional imaging theory. A passively Q-switched microchip laser is used to transmit short sub-nanosecond laser pulses at 532nm. The output laser is divided into 1×8 laser spots, which correspond to 8 Geiger-mode avalanche photodiodes coupled by a 1×8-pixel fiber array. A FPGA based time-to-digital converter (TDC), which is designed by delay line interpolation technology, is used for multi-hit signal acquisition. The algorithm of photon counting three-dimensional imaging is developed for signal photon events extraction and noise filter. Three-dimensional images under daylight conditions were acquired and analyzed. The results show that system could operate at strong solar background. The ranging accuracy of the system is 6.3cm (σ) while received laser pulse signal level is only 0.04 photoelectrons on average. The advantages and feasibility of photon counting laser radar working at daylight have been

  16. Quantifying direct DQPSK receiver with integrated photodiode array by assessing an adapted common-mode rejection ratio

    NASA Astrophysics Data System (ADS)

    Wang, J.; Lauermann, M.; Zawadzki, C.; Brinker, W.; Zhang, Z.; de Felipe, D.; Keil, N.; Grote, N.; Schell, M.

    2011-12-01

    In this work, a direct DQPSK receiver was fabricated, which comprises a polymer waveguide based delay-line interferometer (DLI); a polymer based optical hybrid, and two monolithic pairs of > 25 GHz bandwidth photodiodes that are vertically coupled to the polymer planar lightwave circuit (PLC) via integrated 45° mirrors. The common mode rejection ratio (CMRR) is used to characterize the performance of coherent receivers, by indicating the electrical power balance between the balanced detectors. However, the standard CMRR can only be measured when the PDs can be illuminated separately. Also, the standard CMRR does not take into account the errors in the relative phases of the receiver outputs. We introduce an adapted CMRR to characterize the direct receiver, which takes into account the unequal responsivities of the PDs, the uneven split of the input power by the DLI and hybrid, the phase error and the extinction ratio of the DLI and hybrid.

  17. Developing Seedless Growth of ZnO Micro/Nanowire Arrays towards ZnO/FeS2/CuI P-I-N Photodiode Application

    PubMed Central

    Yang, Zhi; Wang, Minqiang; Shukla, Sudhanshu; Zhu, Yue; Deng, Jianping; Ge, Hu; Wang, Xingzhi; Xiong, Qihua

    2015-01-01

    A seedless hydrothermal method is developed to grow high density and vertically aligned ZnO micro/nanowire arrays with low defect density on metal films under the saturated nutrition solution. In particular, the mechanism of seedless method is discussed here. A buffer layer can be confirmed by transmission electron microscopy (TEM), which may release the elastic strain between ZnO and substrate to achieve this highly mismatched heteroepitaxial structures. Based on ZnO micro/nanowire arrays with excellent wettability surface, we prepared ZnO-FeS2-CuI p-i-n photodiode by all-solution processed method with the high rectifying ratio of 197 at ±1 V. Under AM 1.5 condition, the Jsc of 0.5 mA/cm2, on-off current ratio of 371 and fast photoresponse at zero bias voltage were obtained. This good performance comes from excellent collection ability of photogenerated electrons and holes due to the increased depletion layer width for p-i-n structure. Finally, the high responsivity around 900 nm shows the potential as near infrared photodetectors applications. PMID:26077658

  18. Developing Seedless Growth of ZnO Micro/Nanowire Arrays towards ZnO/FeS2/CuI P-I-N Photodiode Application

    NASA Astrophysics Data System (ADS)

    Yang, Zhi; Wang, Minqiang; Shukla, Sudhanshu; Zhu, Yue; Deng, Jianping; Ge, Hu; Wang, Xingzhi; Xiong, Qihua

    2015-06-01

    A seedless hydrothermal method is developed to grow high density and vertically aligned ZnO micro/nanowire arrays with low defect density on metal films under the saturated nutrition solution. In particular, the mechanism of seedless method is discussed here. A buffer layer can be confirmed by transmission electron microscopy (TEM), which may release the elastic strain between ZnO and substrate to achieve this highly mismatched heteroepitaxial structures. Based on ZnO micro/nanowire arrays with excellent wettability surface, we prepared ZnO-FeS2-CuI p-i-n photodiode by all-solution processed method with the high rectifying ratio of 197 at ±1 V. Under AM 1.5 condition, the Jsc of 0.5 mA/cm2, on-off current ratio of 371 and fast photoresponse at zero bias voltage were obtained. This good performance comes from excellent collection ability of photogenerated electrons and holes due to the increased depletion layer width for p-i-n structure. Finally, the high responsivity around 900 nm shows the potential as near infrared photodetectors applications.

  19. Hybrid photomultiplier tube and photodiode parallel detection array for wideband optical spectroscopy of the breast guided by magnetic resonance imaging

    NASA Astrophysics Data System (ADS)

    El-Ghussein, Fadi; Mastanduno, Michael A.; Jiang, Shudong; Pogue, Brian W.; Paulsen, Keith D.

    2014-01-01

    A new optical parallel detection system of hybrid frequency and continuous-wave domains was developed to improve the data quality and accuracy in recovery of all breast optical properties. This new system was deployed in a previously existing system for magnetic resonance imaging (MRI)-guided spectroscopy, and allows incorporation of additional near-infrared wavelengths beyond 850 nm, with interlaced channels of photomultiplier tubes (PMTs) and silicon photodiodes (PDs). The acquisition time for obtaining frequency-domain data at six wavelengths (660, 735, 785, 808, 826, and 849 nm) and continuous-wave data at three wavelengths (903, 912, and 948 nm) is 12 min. The dynamic ranges of the detected signal are 105 and 106 for PMT and PD detectors, respectively. Compared to the previous detection system, the SNR ratio of frequency-domain detection was improved by nearly 103 through the addition of an RF amplifier and the utilization of programmable gain. The current system is being utilized in a clinical trial imaging suspected breast cancer tumors as detected by contrast MRI scans.

  20. Hybrid photomultiplier tube and photodiode parallel detection array for wideband optical spectroscopy of the breast guided by magnetic resonance imaging.

    PubMed

    El-Ghussein, Fadi; Mastanduno, Michael A; Jiang, Shudong; Pogue, Brian W; Paulsen, Keith D

    2014-01-01

    A new optical parallel detection system of hybrid frequency and continuous-wave domains was developed to improve the data quality and accuracy in recovery of all breast optical properties. This new system was deployed in a previously existing system for magnetic resonance imaging (MRI)-guided spectroscopy, and allows incorporation of additional near-infrared wavelengths beyond 850 nm, with interlaced channels of photomultiplier tubes (PMTs) and silicon photodiodes (PDs). The acquisition time for obtaining frequency-domain data at six wavelengths (660, 735, 785, 808, 826, and 849 nm) and continuous-wave data at three wavelengths (903, 912, and 948 nm) is 12 min. The dynamic ranges of the detected signal are 105 and 106 for PMT and PD detectors, respectively. Compared to the previous detection system, the SNR ratio of frequency-domain detection was improved by nearly 103 through the addition of an RF amplifier and the utilization of programmable gain. The current system is being utilized in a clinical trial imaging suspected breast cancer tumors as detected by contrast MRI scans.

  1. Hybrid photomultiplier tube and photodiode parallel detection array for wideband optical spectroscopy of the breast guided by magnetic resonance imaging

    PubMed Central

    Mastanduno, Michael A.; Jiang, Shudong; Pogue, Brian W.; Paulsen, Keith D.

    2013-01-01

    Abstract. A new optical parallel detection system of hybrid frequency and continuous-wave domains was developed to improve the data quality and accuracy in recovery of all breast optical properties. This new system was deployed in a previously existing system for magnetic resonance imaging (MRI)-guided spectroscopy, and allows incorporation of additional near-infrared wavelengths beyond 850 nm, with interlaced channels of photomultiplier tubes (PMTs) and silicon photodiodes (PDs). The acquisition time for obtaining frequency-domain data at six wavelengths (660, 735, 785, 808, 826, and 849 nm) and continuous-wave data at three wavelengths (903, 912, and 948 nm) is 12 min. The dynamic ranges of the detected signal are 105 and 106 for PMT and PD detectors, respectively. Compared to the previous detection system, the SNR ratio of frequency-domain detection was improved by nearly 103 through the addition of an RF amplifier and the utilization of programmable gain. The current system is being utilized in a clinical trial imaging suspected breast cancer tumors as detected by contrast MRI scans. PMID:23979460

  2. High efficiency n-Si/ p-Cu2O core-shell nanowires photodiode prepared by atomic layer deposition of Cu2O on well-ordered Si nanowires array

    NASA Astrophysics Data System (ADS)

    Kim, Hangil; Kim, Soo-Hyun; Ko, Kyung Yong; Kim, Hyungjun; Kim, Jaehoon; Oh, Jihun; Lee, Han-Bo-Ram

    2016-05-01

    A highly efficient n-Si/ p-Cu2O core-shell (C-S) nanowire (NW) photodiode was fabricated using Cu2O grown by atomic layer deposition (ALD) on a well-ordered Si NW array. Ordered Si nanowires arrays were fabricated by nano-sphere lithography to pattern metal catalysts for the metal-assisted etching of silicon, resulting in a Si NW arrays with a good arrangement, smooth surface and small diameter distribution. The ALD-Cu2O thin films were grown using a new non-fluorinated Cu precursor, bis(1-dimethylamino-2-methyl-2-butoxy)copper (C14H32N2O2Cu), and water vapor (H2O) at 140°C. Transmission electron microscopy equipped with an energy dispersive spectrometer confirmed that p-Cu2O thin films had been coated over arrayed Si NWs with a diameter of 150 nm (aspect ratio of ˜7.6). The C-S NW photodiode exhibited more sensitive photodetection performance under ultraviolet illumination as well as an enhanced photocurrent density in the forward biasing region than the planar structure diode. The superior performance of C-S NWs photodiode was explained by the lower reflectance of light and the effective carrier separation and collection originating from the C-S NWs structure. [Figure not available: see fulltext.

  3. Development of a Validated HPLC/Photodiode Array Method for the Determination of Isomenthone in the Aerial Parts of Ziziphora tenuior L.

    PubMed Central

    Ghassemi, Nasrollah; Ghanadian, Mustafa; Ghaemmaghami, Lili; Kiani, Haran

    2013-01-01

    Background Ziziphora tenuior L. known as Kakuti in Persian, is used in traditional medicine for fever, dysentery, uterus infection and as an analgesic. It is used also in the treatment of gastrointestinal disorders as carminative, or remedy of diarrhea or nausea. Major components of plant essential oil including pulegone, isomenthone, thymol, menthone, and piperitone are suggested to be responsible for the mentioned medicinal properties. Objectives In the present study, a normal high performance liquid chromatography (HPLC)/photodiode array validated method for quantification of isomenthone, one of the major constituents of Ziziphora, was established for the first time with a simple, rapid and accurate method. Materials and Methods HPLC analysis was done on a Waters system, equipped with 515 HPLC pump and waters 2996 photodiode array detector. The column was a Nova-Pak Silica (3.9 × 150 mm), and Empower software was used for the determination of the compounds and processing the data. The method was validated according to USP 32 requirements. Results A selective method for the resolution of isomenthone from two nearest peaks, thymol, and carvacrol was obtained with gradient system of hexane (A), and hexane: ethyl acetate (9:1) (B), starting with A: B (100:0) for 2 minutes, then 0−20% B in 5 minutes, A:B (80:20) for 5 minutes, then 20-30% B in 3 minutes, 30-100% B for 5 minutes, A:B (0:100) for 4 minutes following with equilibrating for 10 minutes. The flow rate was 1 mL/min at 22˚C and the injection volume for the standards and the samples was 20 μL. The retention time for isomenthone was found to be 7.45 minutes. The regression equation was y = 143235x - 2433 with the correlation co-factor R2 = 0.9992 and the percent recovery of 65.4 ± 3.85%. The sample obtained from 5 g of Z. teniour dried powder in 6 mL extract was standardized to contain 1.14 ± 0.030 μL/mL isomenthone which is equivalent to % 1.37 μL/g of the dried powdered plant. Limit of detection

  4. Determination of nitroaromatic explosives and their degradation products in unsaturated-zone water samples by high-performance liquid chromatography with photodiode-array, mass spectrometric, and tandem mass spectrometric detection

    USGS Publications Warehouse

    Gates, Paul M.; Furlong, E.T.; Dorsey, T.F.; Burkhardt, M.R.

    1996-01-01

    Mass spectrometry and tandem mass spectrometry, coupled by a thermospray interface to a high-performance liguid chromatography system and equipped with a photodiode array detector, were used to determine the presence of nitroaromatic explosives and their degradation products in USA unsaturated-zone water samples. Using this approach, the lower limits of quantitation for explosives determined by mass spectrometry in this study typically ranged from 10 to 100 ng/l.

  5. Determination of nitrofurans in animal feeds by liquid chromatography-UV photodiode array detection and liquid chromatography-ionspray tandem mass spectrometry.

    PubMed

    Barbosa, Jorge; Moura, Sara; Barbosa, Rita; Ramos, Fernando; da Silveira, Maria Irene Noronha

    2007-03-14

    Within the EU, the use of nitrofurans is prohibited in food production animals. For this reason detection of these compounds in feedingstuffs, at whatever limit, constitutes an offence under EU legislation. This detection generally involves the use of analytical methods with limits of quantification lowers than 1 mg kg(-1). These procedures are unsuitable for the detection and confirmation of trace amounts of nitrofurans in feedingstuffs due to contamination. It is well known that very low concentrations of these compounds can be the source of residues of nitrofuran metabolites in meat and other edible products obtained from animals consuming the contaminated feed. The present multi-compound method was capable of measuring very low concentrations of nitrofurantoin (NFT), nitrofurazone (NFZ), furazolidone (FZD) and furaltadone (FTD) in animal feed using nifuroxazide (NXZ) as internal standard. Following ethyl acetate extraction at mild alkaline conditions and purification on NH2 column, the nitrofurans are determined using liquid chromatography with photodiode-array detection (LC-DAD). It was observed a CCalpha ranged from 50 to 100 microg kg(-1). The liquid chromatography-tandem mass spectrometric (LC-MS/MS) procedure was used to confirm the identity of the suspected presence of any of the nitrofuran compounds.

  6. Fingerprint analysis of Hibiscus mutabilis L. leaves based on ultra performance liquid chromatography with photodiode array detector combined with similarity analysis and hierarchical clustering analysis methods

    PubMed Central

    Liang, Xianrui; Ma, Meiling; Su, Weike

    2013-01-01

    Background: A method for chemical fingerprint analysis of Hibiscus mutabilis L. leaves was developed based on ultra performance liquid chromatography with photodiode array detector (UPLC-PAD) combined with similarity analysis (SA) and hierarchical clustering analysis (HCA). Materials and Methods: 10 batches of Hibiscus mutabilis L. leaves samples were collected from different regions of China. UPLC-PAD was employed to collect chemical fingerprints of Hibiscus mutabilis L. leaves. Results: The relative standard deviations (RSDs) of the relative retention times (RRT) and relative peak areas (RPA) of 10 characteristic peaks (one of them was identified as rutin) in precision, repeatability and stability test were less than 3%, and the method of fingerprint analysis was validated to be suitable for the Hibiscus mutabilis L. leaves. Conclusions: The chromatographic fingerprints showed abundant diversity of chemical constituents qualitatively in the 10 batches of Hibiscus mutabilis L. leaves samples from different locations by similarity analysis on basis of calculating the correlation coefficients between each two fingerprints. Moreover, the HCA method clustered the samples into four classes, and the HCA dendrogram showed the close or distant relations among the 10 samples, which was consistent to the SA result to some extent. PMID:23930008

  7. Determination of plant hormones in fertilizers by high-performance liquid chromatography with photodiode array detection: method development and single-laboratory validation.

    PubMed

    Gambino, Grazia Laura; Pagano, Pietro; Scordino, Monica; Sabatino, Leonardo; Scollo, Emanuele; Traulo, Pasqualino; Gagliano, Giacomo

    2008-01-01

    A simple and reliable high-performance liquid chromatographic method that uses photodiode array detection was developed for the simultaneous determination of 12 native and synthetic plant hormones, i.e., plant growth regulators (PGRs), in fertilizers, such as 1-naphthol, 2,4-dichlorophenoxyacetic acid, 4-(2,4-dichlorophenoxy)butyric acid, 4-chlorophenoxyacetic acid, indole-3-acetic acid, 4-(3-indolyl)butyric acid, dichlorprop, (4-chloro-2-methylphenoxy)acetic acid, alpha-naphthaleneacetic acid, 1-naphthaleneacetamide, beta-naphthoxyacetic acid, and thidiazuron. The method was experimentally validated for routine regulatory application, and the following analytical parameters were assessed for all PGRs studied: linearity; specificity; precision (relative standard deviation) and accuracy, both measured at 3 concentration levels (0.1, 0.05, and 0.01%, w/w); ruggedness; limit of detection; and limit of quantification. Results were satisfactory for all method validation parameters tested and for all PGRs studied, demonstrating the suitability of the method for the determination of PGRs in fertilizers. The uncertainty of measurement was also estimated at 3 concentration levels for all PGRs by using the approach of the International Organization for Standardization, described in its Guide to the Expression of Uncertainty in Measurement. The method was applied to 20 samples of liquid fertilizer with declared biostimulant properties.

  8. Simultaneous determination of catechins, caffeine and gallic acids in green, Oolong, black and pu-erh teas using HPLC with a photodiode array detector.

    PubMed

    Zuo, Yuegang; Chen, Hao; Deng, Yiwei

    2002-05-16

    A simple and fast HPLC method using a photodiode array detector was developed for simultaneous determination of four major catechins, gallic acid and caffeine. After multiple extractions with aqueous methanol and acidic methanol solutions, tea extract was separated within 20 min using a methanol-acetate-water buffer gradient elution system on a C(18) column. The sample extraction data demonstrated that the single extraction used in the previous studies with aqueous acetonitrile or methanol is not sufficient; the multiple extraction procedure is essential for the quantitative analysis of catechins, phenolic acids and caffeine in teas. Several green, Oolong, black and pu-erh teas were successfully analyzed by this method. The analytical results obtained indicated that green teas contain higher content of catechins [(-)-epigallocatechin gallate, (-)-epigallocatechin, (-)-epicatechin gallate, and (-)-epicatechin] than both Oolong, pu-erh and black teas because fermentation process during the tea manufacturing reduced the levels of catechins significantly. The fermentation process also remarkably elevated the levels of gallic acid in full-fermented pu-erh and black teas. Another interesting finding is the low level of caffeine in Oolong teas, especially in Fujian Oolong tea.

  9. A strategy for detecting absorbed bioactive compounds for quality control in the water extract of rhubarb by ultra performance liquid chromatography with photodiode array detector.

    PubMed

    Wang, Yang; Huang, Xi; Liang, Qing-Hua; Fan, Rong; Qin, Feng; Guo, Yong; Yan, Kui-Po; Liu, Wei; Luo, Jie-Kun; Li, Yun-Hui; Mao, Xi-Lian; Liu, Zhao-Qian; Zhou, Hong-Hao

    2012-09-01

    To detect absorbed bioactive compounds of the water extract whose pharmacodynamic effect was craniocerebral protection for quality control assessment. Anthraquinones in water extract of rhubarb (WER), in cerebrospinal fluid (CSF) of patients with traumatic brain injury (TBI) and in ipsilateral cortex of TBI rats following oral WER were respectively explored by ultra performance liquid chromatography with photodiode array detector (UPLC-PDA) method developed in the present study. The effects of anthraquinones absorbed into injured cortex on superoxidase dismutase (SOD) activity in TBI rats were detected. The antioxidative anthraquinones absorbed into target organ were evaluated for quality control of WER. Anthraquinones in WER were aloe-emodin, rhein, emodin, chrysophanol, and physcion. Only the last anthraquinone was found in CSF and in ipsilateral cortex under this chromatographic condition. Physcion increased SOD activity in TBI rats significantly. Physcion was the main active compound of rhubarb against craniocerebral injury via antioxidant pathway. According to our strategy, the exploration of physcion suggested the possibility of a novel quality control of WER in treating TBI injury.

  10. Identification and chemical profiling of monacolins in red yeast rice using high-performance liquid chromatography with photodiode array detector and mass spectrometry.

    PubMed

    Li, Yong-Guo; Zhang, Fang; Wang, Zheng-Tao; Hu, Zhi-Bi

    2004-09-03

    Monascus purpureus-fermented rice (red yeast rice) was one of the food supplements that had the ability of lowering the blood-lipid levels, and monacolins have been proved to be main active constituents. In total 14 monacolin compounds such as monacolin K (mevinolin), J, L, M, X, and their hydroxy acid form, as well as dehydromonacolin K, dihydromonacolin L, compactin, 3alpha-hydroxy-3,5-dihydromonacolin L, etc. were identified in red yeast rice, using high-performance liquid chromatography with photodiode array detector and tandem mass spectrometry. A chemical fingerprint profiling method to display bioactive monacolins in red yeast rice was established and could be used for the quality control of the target material and its related products. Ten finish products labeled as red yeast rice from different manufacturers in marketing were traced using the chromatographic chemical profiling method, and the results show that only two of them were similar while the other eight were significantly different from the reference red yeast rice. All of these materials including raw material powder and finished products available were quantified and the contents of monacolins were calculated with reference of monacolin K (mevinolin) as the standard.

  11. Characterisation of chemical components for identifying historical Chinese textile dyes by ultra high performance liquid chromatography - photodiode array - electrospray ionisation mass spectrometer.

    PubMed

    Han, Jing; Wanrooij, Jantien; van Bommel, Maarten; Quye, Anita

    2017-01-06

    This research makes the first attempt to apply Ultra High Performance Liquid Chromatography (UHPLC) coupled to both Photodiode Array detection (PDA) and Electrospray Ionisation Mass Spectrometer (ESI-MS) to the chemical characterisation of common textile dyes in ancient China. Three different extraction methods, respectively involving dimethyl sulfoxide (DMSO)-oxalic acid, DMSO and hydrochloric acid, are unprecedentedly applied together to achieve an in-depth understanding of the chemical composition of these dyes. The first LC-PDA-MS database of the chemical composition of common dyes in ancient China has been established. The phenomena of esterification and isomerisation of the dye constituents of gallnut, gardenia and saffron, and the dye composition of acorn cup dyed silk are clarified for the first time. 6-Hydroxyrubiadin and its glycosides are first reported on a dyed sample with Rubia cordifolia from China. UHPLC-PDA-ESI-MS with a C18 BEH shield column shows significant advantages in the separation and identification of similar dye constituents, particularly in the cases of analysing pagoda bud and turmeric dyed sample extracts.

  12. Quality evaluation of Salvia miltiorrhiza Bge. by ultra high performance liquid chromatography with photodiode array detection and chemical fingerprinting coupled with chemometric analysis.

    PubMed

    Luo, Hongli; Kong, Weijun; Hu, Yichen; Chen, Ping; Wu, Xiaoru; Wan, Li; Yang, Meihua

    2015-05-01

    An ultra high performance liquid chromatography with photodiode array detection method is developed for the simultaneous quantitative determination of five water-soluble compounds including danshensu, protocatechualdehyde, rosmarinic acid, salvianolic acid B, and salvianolic acid A in Salvia miltiorrhiza Bge. Through method optimization, the five compounds all expressed good linearity (R(2) > 0.9990) in a wide concentration range together with satisfactory accuracy, precision, and stability. Moreover, through qualitative analysis of the chemical fingerprint combined with similarity analysis, hierarchical cluster analysis, principle component analysis, and partial least-squares discriminate analysis, we determined that the 13 batches of Salvia miltiorrhiza Bge. were similar in internal quality and the differences resulted from various cultivation environments, recovery elements, and others. Seen from the results of hierarchical cluster analysis and principle component analysis, the classification of 13 batches was in accordance, and partial least-squares discriminate analysis technique was more suitable than the principle component analysis model to provide a distinct classification of test samples on the basis of their different components. Moreover, a permutation test verified the rationality of partial least-squares discriminate analysis and variable importance plot showed that peaks 37 and 38 were the most significant variables in distinguishing the Salvia miltiorrhiza Bge. The idea of the quantitative and qualitative analysis of Salvia miltiorrhiza Bge. was convenient, sensitive, and comprehensive, which could be applied to evaluate the quality of more traditional Chinese medicines. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Simultaneous Quantification of Antioxidant Compounds in Phellinus igniarius Using Ultra Performance Liquid Chromatography-Photodiode Array Detection-Electrospray Ionization Tandem Mass Spectrometry

    PubMed Central

    Wang, Nani; Li, Hongyu; Zhang, Yang; Zhu, Yan

    2016-01-01

    Natural antioxidants are widely used in the life sciences. Phellinus igniarius is a historically used natural antioxidant containing a variety of active compounds. Phenols, particularly Inoscavin A and Hypholomine B, are found in the high concentrations. Better quantitative methods are needed to perform quality control in order to support further research of this mushroom. An ultra-performance liquid chromatography method coupled to photodiode-array detection and an electrospray ionization tandem mass spectrometry method (UPLC-PAD-MS) was developed to simultaneously quantify Inoscavin A and Hypholomine B levels in the medicinal fungus Phellinus igniarius. The two compounds were quantified using UPLC-PAD and UPLC-MS. The methods were accurate (mean accuracy for spiked matrix ranged from 101.5% to 105.8%), sensitive (limit of detection ranged from 0.28 to 1.14 mg L-1) and precise (the relative standard deviations ranged from 0.13 to 2.8%). Inoscavin A and Hypholomine B were purified using high-speed counter-current chromatography (HSCCC), structural evaluated to meet the request of standard substances. UPLC separation was performed on a reversed-phase C18 column using gradient elution with acetonitrile and 0.1% formic acid over 10 min. The developed method was successfully applied to determine Inoscavin A and Hypholomine B in twelve Phellinus igniarius samples of different origins and the results showed that it was suitable for the analysis of these active components in Phellinus igniarius samples. PMID:27689891

  14. Simultaneous Quantification of Antioxidant Compounds in Phellinus igniarius Using Ultra Performance Liquid Chromatography-Photodiode Array Detection-Electrospray Ionization Tandem Mass Spectrometry.

    PubMed

    Shou, Dan; Dong, Yu; Wang, Nani; Li, Hongyu; Zhang, Yang; Zhu, Yan

    Natural antioxidants are widely used in the life sciences. Phellinus igniarius is a historically used natural antioxidant containing a variety of active compounds. Phenols, particularly Inoscavin A and Hypholomine B, are found in the high concentrations. Better quantitative methods are needed to perform quality control in order to support further research of this mushroom. An ultra-performance liquid chromatography method coupled to photodiode-array detection and an electrospray ionization tandem mass spectrometry method (UPLC-PAD-MS) was developed to simultaneously quantify Inoscavin A and Hypholomine B levels in the medicinal fungus Phellinus igniarius. The two compounds were quantified using UPLC-PAD and UPLC-MS. The methods were accurate (mean accuracy for spiked matrix ranged from 101.5% to 105.8%), sensitive (limit of detection ranged from 0.28 to 1.14 mg L-1) and precise (the relative standard deviations ranged from 0.13 to 2.8%). Inoscavin A and Hypholomine B were purified using high-speed counter-current chromatography (HSCCC), structural evaluated to meet the request of standard substances. UPLC separation was performed on a reversed-phase C18 column using gradient elution with acetonitrile and 0.1% formic acid over 10 min. The developed method was successfully applied to determine Inoscavin A and Hypholomine B in twelve Phellinus igniarius samples of different origins and the results showed that it was suitable for the analysis of these active components in Phellinus igniarius samples.

  15. Initial performance studies of a wearable brain positron emission tomography camera based on autonomous thin-film digital Geiger avalanche photodiode arrays.

    PubMed

    Schmidtlein, Charles R; Turner, James N; Thompson, Michael O; Mandal, Krishna C; Häggström, Ida; Zhang, Jiahan; Humm, John L; Feiglin, David H; Krol, Andrzej

    2017-01-01

    Using analytical and Monte Carlo modeling, we explored performance of a lightweight wearable helmet-shaped brain positron emission tomography (PET), or BET camera, based on thin-film digital Geiger avalanche photodiode arrays with Lutetium-yttrium oxyorthosilicate (LYSO) or [Formula: see text] scintillators for imaging in vivo human brain function of freely moving and acting subjects. We investigated a spherical cap BET and cylindrical brain PET (CYL) geometries with 250-mm diameter. We also considered a clinical whole-body (WB) LYSO PET/CT scanner. The simulated energy resolutions were 10.8% (LYSO) and 3.3% ([Formula: see text]), and the coincidence window was set at 2 ns. The brain was simulated as a water sphere of uniform F-18 activity with a radius of 100 mm. We found that BET achieved [Formula: see text] better noise equivalent count (NEC) performance relative to the CYL and [Formula: see text] than WB. For 10-mm-thick [Formula: see text] equivalent mass systems, LYSO (7-mm thick) had [Formula: see text] higher NEC than [Formula: see text]. We found that [Formula: see text] scintillator crystals achieved [Formula: see text] full-width-half-maximum spatial resolution without parallax errors. Additionally, our simulations showed that LYSO generally outperformed [Formula: see text] for NEC unless the timing resolution for [Formula: see text] was considerably smaller than that presently used for LYSO, i.e., well below 300 ps.

  16. A fast and validated method for the determination of malondialdehyde in fish liver using high-performance liquid chromatography with a photodiode array detector.

    PubMed

    Faizan, Mohammad; Esatbeyoglu, Tuba; Bayram, Banu; Rimbach, Gerald

    2014-04-01

    Malondialdehyde (MDA) is a biomarker of lipid peroxidation and is present in foods and biological samples such as plasma. A high-performance liquid chromatography (HPLC) method was applied to determine MDA in fish liver samples after derivatization with 2,4-dinitrophenylhydrazine (DNPH) using a ODS2 column (10 cm × 4.6 mm, 3 μm) and a photodiode array detector. The mobile phase consisted of 0.2% acetic acid (v/v) in distilled water and acetonitrile (42:58, v/v). The present method was validated in terms of linearity, lower limit of quantification, lower limit of detection, precision, accuracy, recovery, and stability of MDA according to U.S. Food and Drug Administration (FDA) guidelines. The limit of quantification of MDA was 0.39 μmol/L, which is comparable to other methods. The recovery of the spiked MDA liver samples was in the range of 92.4% to 104.2%. This newly modified HPLC method is specific, sensitive, and accurate and allows the analysis of MDA within 4 min in fish liver but also in other tissues and plasma. © 2014 Institute of Food Technologists®

  17. High-performance liquid chromatography with photodiode array detection and chemometrics method for the analysis of multiple components in the traditional Chinese medicine Shuanghuanglian oral liquid.

    PubMed

    Li, Bao Qiong; Chen, Jing; Li, Jiao Jiao; Wang, Xue; Zhai, Hong Lin; Zhang, Xiao Yun

    2015-12-01

    Shuanghuanlian oral liquid, a traditional Chinese medicine preparation, is a mixture of three herbs (Flos Lonicerae, Radix Scutellariae and Fructus Forsythiae). In this study, the quantitative analysis of three main active compounds, chlorogenic acid, forsythin and baicalin in samples from different manufacturers was performed rapidly by high-performance liquid chromatography coupled with photodiode array detection followed by Contour Projection coupled to stepwise regression treatment of the obtained three-dimensional spectra in which the partial overlap between adjacent target components existed. The method was validated for linearity (R>0.9940), precision (RSD<1.25%), recovery (92.20-102.50%), limit of detection (0.01-0.02 μg/mL) and limit of quantification (0.03-0.07 μg/mL). The results indicated that the combination of the three-dimensional spectra of traditional Chinese medicine and Contour Projection-stepwise regression offered an accurate, simple, low-cost and eco-friendly way for the rapid quantitative analysis of Shuanghuanlian oral liquid samples.

  18. Simultaneous determination of water-soluble whitening ingredients and adenosine in different cosmetic formulations by high-performance liquid chromatography coupled with photodiode array detection.

    PubMed

    Jeon, J-S; Kim, H-T; Kim, M-G; Oh, M-S; Hong, S-R; Yoon, M-H; Cho, S-M; Shin, H-C; Shim, J-H; Ramadan, A; Abd El-Aty, A M

    2016-06-01

    The Korean Cosmetic Act regulates the use of functional cosmetics) by the law. Four functional cosmetic groups, whitening, anti-wrinkle, UV protection and combination of whitening and anti-wrinkle, were categorized according to the Korean Cosmetic Act and Functional Cosmetics Codex. In this study, high-performance liquid chromatography (HPLC) coupled with photodiode array detection (DAD) was employed for the simultaneous detection of arbutin (and its decomposition product, hydroquinone), niacinamide, ascorbyl glucoside, ethyl ascorbyl ether and adenosine in functional cosmetic products such as creams, emulsions and lotions. Separation by HPLC-DAD was conducted using a C18 column with a gradient elution of 5 mm KH2PO4 buffer (containing 0.1% phosphoric acid) and methanol (containing 0.1% phosphoric acid). The wavelengths for the detection of arbutin, hydroquinone, niacinamide, adenosine, ascorbyl glucoside and ethyl ascorbyl ether were 283, 289, 261, 257, 238 and 245 nm, respectively. This method exhibited good linearity (R(2) ≥ 0.999), precision (expressed as relative standard deviation (RSD) < 2%) and mean recoveries (89.42-104.89%). The results obtained by monitoring 100 market samples showed that the detected levels of the tested materials are within the acceptable authorized concentration. The method developed herein is simple and can be used for market survey and quality control of functional cosmetics. © 2015 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

  19. Determination of 40 synthetic food colors in drinks and candies by high-performance liquid chromatography using a short column with photodiode array detection.

    PubMed

    Yoshioka, N; Ichihashi, K

    2008-02-15

    Forty synthetic food colors were determined in drinks and candies by reversed-phase high-performance liquid chromatography with photodiode array detection. The following food colors were analyzed within 19 min using a short analytical column (50 mm x 4.6 mm i.d., 1.8 microm) at 50 degrees C with gradient elution: Ponceau 6R, Tartrazine, Fast yellow AB, Amaranth, Indigotine, Naphthol yellow S, Chrysoine, Ponceau 4R, Sunset yellow FCF, Red 10B, Orange G, Acid violet 7, Brilliant black PN, Allura red AC, Yellow 2G, Red 2G, Uranine, Fast red E, Green S, Ponceau 2R, Azorubine, Orange I, Quinoline yellow, Martius yellow, Ponceau SX, Ponceau 3R, Fast green FCF, Eosine, Brilliant blue FCF, Orange II, Orange RN, Acid blue 1, Erythrosine, Amido black 10B, Acid red 52, Patent blue V, Acid green 9, Phloxine B, Benzyl violet 4B, and Rose bengal. The recoveries of these compounds added to soft drinks and candies at 5 microg/g ranged from 76.6 to 115.0%, and relative standard deviations (R.S.D.s) were within 6.0%. The limits of detection and the limits of quantitation were 0.03 and 0.1 microg/g, respectively.

  20. Determination of polymer additives-antioxidants and ultraviolet (UV) absorbers by high-performance liquid chromatography coupled with UV photodiode array detection in food simulants.

    PubMed

    Gao, Yali; Gu, Yanxiang; Wei, Yun

    2011-12-28

    An analytical method for the quantitative determination of migration levels of polymer additives such as antioxidants and UV absorbers in food packages by high-performance liquid chromatography coupled with UV-vis photodiode array detection has been developed. The pretreatment step involved solid-phase extraction with silica C18 cartridges. The analytical method showed good linearity, presenting regression coefficients (R(2)) ≥ 0.9990 for all compounds. This optimized method was also validated with respect to precision, reproducibility, stability, and accuracy. The limits of detection and quantification were between 0.09 and 1.72 μg mL(-1) and between 0.20 and 5.64 μg mL(-1) for 12 analytes, respectively. Recoveries were in the range of 67.48 and 108.55%, with relative standard deviations between 2.76 and 9.81%. Migration levels of antioxidants and UV absorbers were determined. Butylated hydroxyanisole, 2,6-di-tert-butyl-4-methylphenol (BHT), 2,4-di-tert-butylphenol, Cyanox 2246, Irganox 1035, Tinuvin 326, Tinuvin 328, Irganox 1010, and Irganox 1330 were detected; BHT and Cyanox 2246 were at higher levels than the specific migration levels in some food simulants.

  1. Detection by coupled LC-photodiode array detection and high-resolution Orbitrap MS of dimethyl and diethyl yellow dyes used illegally in processed soymilk curd.

    PubMed

    Fang, Mingchih; Tsai, Chia-Fen; Kuo, Ching-Hao; Cheng, Hwei-Fang

    2015-01-01

    An efficient non-target dye-screening system consisting of a liquid chromatography photodiode array coupled with a high-resolution mass spectrometer (HRMS) is described. Visible absorption spectroscopy assisted in locating the peak of an unknown dye in HRMS chromatograms which allowed the accurate molecular weight of the unknown to be obtained. In a study of the adulteration of processed soymilk curd (tofu) with dimethyl yellow, an unexpected unknown dye was discovered. The compound was further purified by gel permeation chromatography and identified by HRMS and proton nuclear magnetic resonance (NMR) as diethyl yellow (solvent yellow 56). This is the first time that diethyl yellow has been reported in foods. The authentic diethyl yellow was then purchased and used as a quantitative standard. Tofu products and their ingredients associated with tofu processing were surveyed. Analysis showed the source of diethyl yellow could be traced to emulsifiers used as ingredient in tofu products. Surveillance work found the concentrations of diethyl yellow ranged from several μg kg(-1) (ppb) in the tofu products to up to hundreds of mg kg(-1) (ppm) in the emulsifiers.

  2. Relative detection efficiency of back- and front-illuminated charge-coupled device cameras for X-rays between 1 keV and 18 keV.

    PubMed

    Szlachetko, J; Dousse, J-Cl; Hoszowska, J; Berset, M; Cao, W; Szlachetko, M; Kavcic, M

    2007-09-01

    High-resolution x-ray measurements were performed with a von Hamos-type bent crystal spectrometer using for the detection of the diffracted photons either a back-illuminated charge-coupled device (CCD) camera or a front-illuminated one. For each CCD the main x-ray emission lines (e.g., Kalpha, Kbeta, Lalpha, and Lbeta) of a variety of elements were measured in order to probe the performances of the two detectors between 1 and 18 keV. From the observed x-ray lines the linearity of the energy response, the noise level, the energy resolution, and the quantum efficiency ratio of the two CCDs were determined.

  3. Determination of quinolones in animal tissues and eggs by high-performance liquid chromatography with photodiode-array detection.

    PubMed

    Gigosos, P G; Revesado, P R; Cadahía, O; Fente, C A; Vazquez, B I; Franco, C M; Cepeda, A

    2000-02-25

    A rapid, specific reversed-phase HPLC method is described, with solid-phase extraction, for assaying five quinolones (ciprofloxacin, difloxacin, enrofloxacin, norfloxacin and marbofloxacin) with confirmative diode-array detection in samples of bovine kidney, muscle and eggs. The least efficient extraction was marbofloxacin from kidney tissue (64%). The lower detection limit for each quinolone was: enrofloxacin and ciprofloxacin, 1 ng; norfloxacin and difloxacin, 2 ng; marbofloxacin, 4 ng injected. The intra-day relative standard deviations were lower than 7.9% and lower than 8.6% for inter-day assays. These results indicate that the developed method had an acceptable precision.

  4. Simultaneous determination of pseudoephedrine hydrochloride, chlorpheniramine maleate, and dextromethorphan hydrobromide by second-derivative photodiode array spectroscopy.

    PubMed

    Murtha, J L; Julian, T N; Radebaugh, G W

    1988-08-01

    The simultaneous determination of the active ingredients in multicomponent pharmaceutical products normally requires the use of a separation technique, such as HPLC or GC, followed by quantitation. Presented here is a rapid, validated, analytical method that does not require prior separation for the simultaneous determination of three drugs, pseudoephedrine hydrochloride, chlorpheniramine maleate, and dextromethorphan hydrobromide, in a tablet formulation. A diode array spectrophotometer, capable of multicomponent analysis, was used for the quantitation. The utility of this method was demonstrated in two ways: the analysis of a chewable pediatric tablet (formulation CP) containing 7.5 mg of pseudoephedrine hydrochloride, 0.5 mg of chlorpheniramine maleate, and 2.5 mg of dextromethorphan hydrobromide, and the dissolution analysis of a hydroxypropyl methylcellulose-based sustained-release tablet (formulation SR) containing 120 mg of pseudoephedrine hydrochloride, 8 mg of chlorpheniramine maleate, and 60 mg of dextromethorphan hydrobromide. The sensitivity of this assay is 7.5 micrograms/mL for pseudoephedrine hydrochloride, 1.0 micrograms/mL for chlorpheniramine maleate, and 5.0 micrograms/mL for dextromethorphan hydrobromide, using the second-derivative spectra of the absorbance with respect to wavelength. Determinations were made in 0.1 M sodium acetate buffer at pH 5.0 using a 1-cm quartz cell. Absorbance spectra, and their first and second derivatives, from 240 to 300 nm were used for the determination. The results obtained by this method compared favorably with the results obtained by a validated HPLC method.

  5. Characteristics of Monolithically Integrated InGaAs Active Pixel Imager Array

    NASA Technical Reports Server (NTRS)

    Kim, Q.; Cunningham, T. J.; Pain, B.; Lange, M. J.; Olsen, G. H.

    2000-01-01

    Switching and amplifying characteristics of a newly developed monolithic InGaAs Active Pixel Imager Array are presented. The sensor array is fabricated from InGaAs material epitaxially deposited on an InP substrate. It consists of an InGaAs photodiode connected to InP depletion-mode junction field effect transistors (JFETs) for low leakage, low power, and fast control of circuit signal amplifying, buffering, selection, and reset. This monolithically integrated active pixel sensor configuration eliminates the need for hybridization with silicon multiplexer. In addition, the configuration allows the sensor to be front illuminated, making it sensitive to visible as well as near infrared signal radiation. Adapting the existing 1.55 micrometer fiber optical communication technology, this integration will be an ideal system of optoelectronic integration for dual band (Visible/IR) applications near room temperature, for use in atmospheric gas sensing in space, and for target identification on earth. In this paper, two different types of small 4 x 1 test arrays will be described. The effectiveness of switching and amplifying circuits will be discussed in terms of circuit effectiveness (leakage, operating frequency, and temperature) in preparation for the second phase demonstration of integrated, two-dimensional monolithic InGaAs active pixel sensor arrays for applications in transportable shipboard surveillance, night vision, and emission spectroscopy.

  6. Photodiode array to charged aerosol detector response ratio enables comprehensive quantitative monitoring of basic drugs in blood by ultra-high performance liquid chromatography.

    PubMed

    Viinamäki, Jenni; Ojanperä, Ilkka

    2015-03-20

    Quantitative screening for a broad range of drugs in blood is regularly required to assess drug abuse and poisoning within analytical toxicology. Mass spectrometry-based procedures suffer from the large amount of work required to maintain quantitative calibration in extensive multi-compound methods. In this study, a quantitative drug screening method for blood samples was developed based on ultra-high performance liquid chromatography with two consecutive detectors: a photodiode array detector and a corona charged aerosol detector (UHPLC-DAD-CAD). The 2.1 mm × 150 mm UHPLC column contained a high-strength silica C18 bonded phase material with a particle size of 1.8 μm, and the mobile phase consisted of methanol/0.1% trifluoroacetic acid in gradient mode. Identification was based on retention time, UV spectrum and the response ratio from the two detectors. Using historic calibration over a one-month period, the median precision (RSD) of retention times was 0.04% and the median accuracy (bias) of quantification 6.75%. The median precision of the detector response ratio over two orders of magnitude was 12%. The applicable linear ranges were generally 0.05-5 mg L(-1). The method was validated for 161 compounds, including antipsychotics, antidepressants, antihistamines, opioid analgesics, and adrenergic beta blocking drugs, among others. The main novelty of the method was the proven utility of the response ratio of DAD to CAD, which provided the additional identification efficiency required. Unlike with mass spectrometry, the high stability of identification and quantification allowed the use of facile historic calibration. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. Determination of HT-2 and T-2 toxins in oats and wheat by ultra-performance liquid chromatography with photodiode array detection.

    PubMed

    Pascale, Michelangelo; Panzarini, Giuseppe; Visconti, Angelo

    2012-01-30

    European intake estimates indicate that the presence of HT-2 and T-2 toxins in cereals, mainly in oats, can be of concern for human health. Therefore, the development of sensitive, rapid and reliable methods for determining these mycotoxins in cereals, in particular oats, has high priority. A rapid ultra-performance liquid chromatographic (UPLC) method has been developed for the simultaneous determination of HT-2 and T-2 toxins in oats and wheat at μg kg(-1) level. Ground samples were extracted with methanol/water (90:10, v/v) and the diluted extracts were cleaned up through immunoaffinity columns. HT-2 and T-2 toxins were separated and quantified by UPLC with photodiode array (PDA) detector (λ=202 nm) in less than 5 min. Mean recoveries from blank oats samples spiked with HT-2 and T-2 toxins at levels of 50-1000 μg kg(-1) ranged from 87 to 96%, with relative standard deviations (RSDs) lower than 7%; mean recoveries from wheat spiked with HT-2 and T-2 toxins at levels of 25-100 μg kg(-1) ranged from 91 to 103%, with RSDs lower than 5%. The limit of detection of the method was 8 μg kg(-1) for both toxins (signal-to-noise ratio 3:1). The method was successfully applied to the analysis of HT-2 and T-2 toxins in naturally contaminated oats and wheat samples. A good correlation was found by comparative analysis of naturally contaminated samples of oats (r=0.9985) and wheat (r=0.9058) using the proposed method or a reliable HPLC method with fluorescence detection after pre-column derivatization with 1-anthroylnitrile.

  8. Determination of eleutheroside E and eleutheroside B in rat plasma and tissue by high-performance liquid chromatography using solid-phase extraction and photodiode array detection.

    PubMed

    Feng, Shi lan; Hu, Fang di; Zhao, Jian Xiong; Liu, Xi; Li, Y'un

    2006-04-01

    A HPLC method with photodiode array detection (PDA) was developed for the determination and a pharmacokinetic study of eleutheroside E (ELU E) and eleutheroside B (ELU B) in rat plasma and tissue following an eleutherococcus injection. The analysis was performed on a Kromasil C18 column, using water-acetonitrile as the gradient mobile phase and 0.8 mL/min flow rate. Detection wavelengths of ELU E and ELU B were 220 and 206 nm, respectively. Protein from the biological sample was deposited using acetonitrile. ELU E and ELU B were extracted from the biological samples using acetonitrile, separated by solid-phase extraction, and eluted from the cartridge using 60% methanol. The extraction recovery of ELU E and ELU B was 91.2 and 88.8%, respectively. The limit of detection was 37.6 ng/mL for ELU E and 37.0 ng/mL for ELU B (S/N = 3) in plasma. Blood drug level-time cuvers of ELU E and ELU B in Wister rats following administration of an eleutherococcus injection into femoral vein were shown to fit a three-compartment model. The half-life (t1/2) was 4.662 h for ELU E and 2.494 h for ELU B. Following administration of a single eleutherococcus injection, the concentration of ELU E and ELU B in the tissue was Cliver > Ckidney > Cspleen > Cheart and Ckidney > Cliver > Cheart. We believe the method described in the present paper is accurate and reliable and can be used for pharmacokinetic studies of ELU E and ELU B in rats. In addition, the method for sample preparation, using solid phase extraction, is precise, simple and rapid.

  9. An accurate and reproducible method for the quantitative analysis of isoflavones and their metabolites in rat plasma using liquid chromatography/mass spectrometry combined with photodiode array detection.

    PubMed

    Sepehr, Estatira; Robertson, Patrick; Gilani, G Sarwar; Cooke, Gerard; Lau, Benjamin Pui-Yan

    2006-01-01

    To study the safety and potential health benefits of soy isoflavones, a rapid and simple method based on liquid chromatography combined with mass spectrometry (LC/MS) and photodiode array detector (PDA) was developed for the determination of isoflavones in rat plasma. The analytes included daidzein, genistein, glycitein, equol, 4-ethyl phenol, and biochanin A over a concentration range of 1.0-4320.0 nM using 75 microL of rat plasma. Rat plasma samples were hydrolyzed by adding an enzyme mixture from Helix pomatia containing glucuronidase and sulfatase to convert the isoflavone beta-glycosides daidzin, genistin, and glycitin to their active aglycone forms. A liquid-liquid extraction method using ethyl acetate as the extraction solvent was used to extract aglycones and the internal standards (phenolphthalein beta-D glucuronide, 4-methylumbelliferyl sulfate, and apigenin) from digested plasma samples. The extract was evaporated to dryness under a nitrogen stream, reconstituted with 0.1% formic acid in water-acetonitrile (85 + 15), and injected into a Zorbax SB-CN reversed-phase column (4.6 x 75 mm, 3.5 microm particle size). The Micromass ZQ detector was operated in the positive ion selected-ion monitoring mode. The flow rate for LC was 1.0 mL/min, with a split where 25% of the effluent was introduced into the electrospray ionization probe of the MS instrument and 75% into the PDA. The chromatographic run time was 16.0 min, with delay of 10 min/injection. The interday precision and accuracy of the standard samples were <2.6% relative standard deviation and <10% relative error, respectively. Recovery of the reported isoflavones with this method varied from 86 to 100%.

  10. [Determination of flavonol glycosides in tea samples by ultra-high performance liquid chromatography-photodiode array detection-tandem mass spectrometry].

    PubMed

    Wang, Zhicong; Sha, Yuebing; Yu, Xiaobo; Liang, Yuerong

    2015-09-01

    An ultra-high performance liquid chromatography-photodiode array detection-tandem mass spectrometry (UPLC-PDA-MS/MS) method was developed for the determination of flavonol glycosides in tea samples. The chromatographic separation was performed on an UPLC HSS T3 column by gradient elution with the mobile phases of acetonitrile and water both containing 0.1% (v/v) formic acid. A total of 15 flavonol glycosides which include 3 myricetin glycosides, 6 quercetin glycosides and 6 kaempferol glycosides were positively identified in green and black tea samples by comparing the retention times and mass spectra of the samples with standards and publications. The quantities of flavonol glycosides were relatively calculated with the stand- ard quercetin-3-rhamnosylglucoside (Q-GRh) which was calibrated with external quantification method using multi-reaction monitoring (MRM) mode. The results showed that there were different flavonol glycoside distributions in green tea and black tea. The total amount of flavonol glycosides in green tea was 1. 7 times of that in black tea. The major flavonol glycosides in green tea were myricetin-3-galactoside (M-Ga), myricetin-3-glucoside (M-G), quercetin-3-glucosyl-rhamnosyl-galactoside (Q-GaRhG), quercetin-3-glucosyl-rhamnosyl-glucoside (Q-GRhG), kaempferol-3-glucosyl-rhamnosyl-galactoside (K-GaRhG) and kaempferol-3-glucosyl- rhamnosyl-glucoside (K-GRhG), but for black tea, the major flavonol glycosides were quercetin-3-rhamnosylglucoside (Q-GRh), quercetin-3-glucoside (Q-G), kaempferol-3-rhamnosylglucoside (K-GRh) and kaempferol-3-galactoside (K-Ga). The present method is accurate, convenient for the rapid identification of flavonol glycosides and analysis of constituent distribution for green and black teas.

  11. Intelligent peak deconvolution through in-depth study of the data matrix from liquid chromatography coupled with a photo-diode array detector applied to pharmaceutical analysis.

    PubMed

    Arase, Shuntaro; Horie, Kanta; Kato, Takashi; Noda, Akira; Mito, Yasuhiro; Takahashi, Masatoshi; Yanagisawa, Toshinobu

    2016-10-21

    Multivariate curve resolution-alternating least squares (MCR-ALS) method was investigated for its potential to accelerate pharmaceutical research and development. The fast and efficient separation of complex mixtures consisting of multiple components, including impurities as well as major drug substances, remains a challenging application for liquid chromatography in the field of pharmaceutical analysis. In this paper we suggest an integrated analysis algorithm functioning on a matrix of data generated from HPLC coupled with photo-diode array detector (HPLC-PDA) and consisting of the mathematical program for the developed multivariate curve resolution method using an expectation maximization (EM) algorithm with a bidirectional exponentially modified Gaussian (BEMG) model function as a constraint for chromatograms and numerous PDA spectra aligned with time axis. The algorithm provided less than ±1.0% error between true and separated peak area values at resolution (Rs) of 0.6 using simulation data for a three-component mixture with an elution order of a/b/c with similarity (a/b)=0.8410, (b/c)=0.9123 and (a/c)=0.9809 of spectra at peak apex. This software concept provides fast and robust separation analysis even when method development efforts fail to achieve complete separation of the target peaks. Additionally, this approach is potentially applicable to peak deconvolution, allowing quantitative analysis of co-eluted compounds having exactly the same molecular weight. This is complementary to the use of LC-MS to perform quantitative analysis on co-eluted compounds using selected ions to differentiate the proportion of response attributable to each compound.

  12. Identification and quantification of stilbenes in fruits of transgenic tomato plants (Lycopersicon esculentum Mill.) by reversed phase HPLC with photodiode array and mass spectrometry detection.

    PubMed

    Nicoletti, Isabella; De Rossi, Antonella; Giovinazzo, Giovanna; Corradini, Danilo

    2007-05-02

    Reversed-phase high-performance liquid chromatography (RP-HPLC) with photodiode array (PDA) and mass spectrometry (MS) detection was employed to study the accumulation of stilbenes and other naturally occurring polyphenol intermediates of flavonoid pathway in tomato fruits of plants genetically modified to synthesize resveratrol. The transgenic tomato fruits were obtained by overexpression of a grapevine gene encoding the enzyme stilbene synthase in tomato plants (Lycopersicon esculentum Mill.). Stilbenes and flavonoids, either glycosylated or free, were simultaneosly identified by electrospray interface (ESI)-MS in negative ionization mode and were quantified by PDA detection at the wavelength corresponding to their maximum absorbance. The two detectors were coupled online with an HPLC system utilizing a narrow-bore C18 reversed-phase column, which was eluted by a multistep gradient of increasing concentration of acetonitrile in water containing 0.5% (v/v) formic acid. The results of these analysis revealed that the genetic modification of the tomato plants originated different levels of accumulation of four stilbenes (i.e., trans- and cis-piceid and trans- and cis-resveratrol) in their fruit depending on the stages of ripening. Either at immature or at mature stages of ripening the stilbenes were preferentially accumulated in the fruit peel as the glycosylated form. The highest amount of trans-piceid and trans-resveratrol were found in the peel of fruits harvested at mature stage of ripening. The variations in the levels of rutin, naringenin, and chlorogenic acid found in the samples extracted from the fruits of transgenic tomato plants, in comparison to that determined in the control lines, seemed to be related to the genetic transformation, whose effect on the flavonoid biosynthetic pathway needs to be elucidated by additional studies.

  13. Decarboxylation Study of Acidic Cannabinoids: A Novel Approach Using Ultra-High-Performance Supercritical Fluid Chromatography/Photodiode Array-Mass Spectrometry.

    PubMed

    Wang, Mei; Wang, Yan-Hong; Avula, Bharathi; Radwan, Mohamed M; Wanas, Amira S; van Antwerp, John; Parcher, Jon F; ElSohly, Mahmoud A; Khan, Ikhlas A

    2016-01-01

    Introduction: Decarboxylation is an important step for efficient production of the major active components in cannabis, for example, Δ(9)-tetrahydrocannabinol (Δ(9)-THC), cannabidiol (CBD), and cannabigerol (CBG). These cannabinoids do not occur in significant concentrations in cannabis but can be formed by decarboxylation of their corresponding acids, the predominant cannabinoids in the plant. Study of the kinetics of decarboxylation is of importance for phytocannabinoid isolation and dosage formulation for medical use. Efficient analytical methods are essential for simultaneous detection of both neutral and acidic cannabinoids. Methods:C. sativa extracts were used for the studies. Decarboxylation conditions were examined at 80°C, 95°C, 110°C, 130°C, and 145°C for different times up to 60 min in a vacuum oven. An ultra-high performance supercritical fluid chromatography/photodiode array-mass spectrometry (UHPSFC/PDA-MS) method was used for the analysis of acidic and neutral cannabinoids before and after decarboxylation. Results: Decarboxylation at different temperatures displayed an exponential relationship between concentration and time indicating a first-order or pseudo-first-order reaction. The rate constants for Δ(9)-tetrahydrocannabinolic acid-A (THCA-A) were twice those of the cannabidiolic acid (CBDA) and cannabigerolic acid (CBGA). Decarboxylation of THCA-A was forthright with no side reactions or by-products. Decarboxylation of CBDA and CBGA was not as straightforward due to the unexplained loss of reactants or products. Conclusion: The reported UHPSFC/PDA-MS method provided consistent and sensitive analysis of phytocannabinoids and their decarboxylation products and degradants. The rate of change of acidic cannabinoid concentrations over time allowed for determination of rate constants. Variations of rate constants with temperature yielded values for reaction energy.

  14. Decarboxylation Study of Acidic Cannabinoids: A Novel Approach Using Ultra-High-Performance Supercritical Fluid Chromatography/Photodiode Array-Mass Spectrometry

    PubMed Central

    Wang, Mei; Wang, Yan-Hong; Avula, Bharathi; Radwan, Mohamed M.; Wanas, Amira S.; van Antwerp, John; Parcher, Jon F.; ElSohly, Mahmoud A.; Khan, Ikhlas A.

    2016-01-01

    Abstract Introduction: Decarboxylation is an important step for efficient production of the major active components in cannabis, for example, Δ9-tetrahydrocannabinol (Δ9-THC), cannabidiol (CBD), and cannabigerol (CBG). These cannabinoids do not occur in significant concentrations in cannabis but can be formed by decarboxylation of their corresponding acids, the predominant cannabinoids in the plant. Study of the kinetics of decarboxylation is of importance for phytocannabinoid isolation and dosage formulation for medical use. Efficient analytical methods are essential for simultaneous detection of both neutral and acidic cannabinoids. Methods: C. sativa extracts were used for the studies. Decarboxylation conditions were examined at 80°C, 95°C, 110°C, 130°C, and 145°C for different times up to 60 min in a vacuum oven. An ultra-high performance supercritical fluid chromatography/photodiode array-mass spectrometry (UHPSFC/PDA-MS) method was used for the analysis of acidic and neutral cannabinoids before and after decarboxylation. Results: Decarboxylation at different temperatures displayed an exponential relationship between concentration and time indicating a first-order or pseudo-first-order reaction. The rate constants for Δ9-tetrahydrocannabinolic acid-A (THCA-A) were twice those of the cannabidiolic acid (CBDA) and cannabigerolic acid (CBGA). Decarboxylation of THCA-A was forthright with no side reactions or by-products. Decarboxylation of CBDA and CBGA was not as straightforward due to the unexplained loss of reactants or products. Conclusion: The reported UHPSFC/PDA-MS method provided consistent and sensitive analysis of phytocannabinoids and their decarboxylation products and degradants. The rate of change of acidic cannabinoid concentrations over time allowed for determination of rate constants. Variations of rate constants with temperature yielded values for reaction energy. PMID:28861498

  15. New silicon photodiodes for detection of the 1064nm wavelength radiation

    NASA Astrophysics Data System (ADS)

    Wegrzecki, Maciej; Piotrowski, Tadeusz; Puzewicz, Zbigniew; Bar, Jan; Czarnota, Ryszard; Dobrowolski, Rafal; Klimov, Andrii; Kulawik, Jan; Kłos, Helena; Marchewka, Michał; Nieprzecki, Marek; Panas, Andrzej; Seredyński, Bartłomiej; Sierakowski, Andrzej; Słysz, Wojciech; Synkiewicz, Beata; Szmigiel, Dariusz; Zaborowski, Michał

    2016-12-01

    In this paper a concept of a new bulk structure of p+-υ-n+ silicon photodiodes optimized for the detection of fast-changing radiation at the 1064 nm wavelength is presented. The design and technology for two types of quadrant photodiodes, the 8-segment photodiode and the 32-element linear photodiode array that were developed according to the concept are described. Electric and photoelectric parameters of the photodiodes mentioned above are presented.

  16. Using Photodiodes in the Laboratory.

    ERIC Educational Resources Information Center

    Jenkins, T. E.

    1995-01-01

    Describes the most popular optical detector in the design of photodiode detector circuits. Discusses how a photodiode works, points to consider in the design of a photodiode, and photodiode hybrids. (AIM)

  17. Synchronous Photodiode-Signal Sampler

    NASA Technical Reports Server (NTRS)

    Primus, Howard K.

    1988-01-01

    Synchronous sampling circuit increases signal-to-noise ratio of measurements of chopped signal of known phase and frequency in presence of low-frequency or dc background noise. Used with linear array of photoelectric sensors for locating edge of metal plate. Multiplexing circuit cycles through 16 light-emitting-diode/photodiode pairs, under computer control. Synchronized with multiplexer so edge detector makes one background-subtracted signal measurement per emitter/detector pair in turn.

  18. Two-way and three-way approaches to ultra high performance liquid chromatography-photodiode array dataset for the quantitative resolution of a two-component mixture containing ciprofloxacin and ornidazole.

    PubMed

    Dinç, Erdal; Ertekin, Zehra Ceren; Büker, Eda

    2016-09-01

    Two-way and three-way calibration models were applied to ultra high performance liquid chromatography with photodiode array data with coeluted peaks in the same wavelength and time regions for the simultaneous quantitation of ciprofloxacin and ornidazole in tablets. The chromatographic data cube (tensor) was obtained by recording chromatographic spectra of the standard and sample solutions containing ciprofloxacin and ornidazole with sulfadiazine as an internal standard as a function of time and wavelength. Parallel factor analysis and trilinear partial least squares were used as three-way calibrations for the decomposition of the tensor, whereas three-way unfolded partial least squares was applied as a two-way calibration to the unfolded dataset obtained from the data array of ultra high performance liquid chromatography with photodiode array detection. The validity and ability of two-way and three-way analysis methods were tested by analyzing validation samples: synthetic mixture, interday and intraday samples, and standard addition samples. Results obtained from two-way and three-way calibrations were compared to those provided by traditional ultra high performance liquid chromatography. The proposed methods, parallel factor analysis, trilinear partial least squares, unfolded partial least squares, and traditional ultra high performance liquid chromatography were successfully applied to the quantitative estimation of the solid dosage form containing ciprofloxacin and ornidazole.

  19. Electro-Optical Characteristics of P+n In0.53Ga0.47As Hetero-Junction Photodiodes in Large Format Dense Focal Plane Arrays

    NASA Astrophysics Data System (ADS)

    DeWames, R.; Littleton, R.; Witte, K.; Wichman, A.; Bellotti, E.; Pellegrino, J.

    2015-08-01

    This paper is concerned with focal plane array (FPA) data and use of analytical and three-dimensional numerical simulation methods to determine the physical effects and processes limiting performance. For shallow homojunction P+n designs the temperature dependence of dark current for T < 300 K depends on the intrinsic carrier concentration of the In0.53Ga0.47As material, implying that the dominant dark currents are generation and recombination (G-R) currents originating in the depletion regions of the double layer planar heterostructure (DLPH) photodiode. In the analytical model differences from bulk G-R behavior are modeled with a G-R like perimeter-dependent shunt current conjectured to originate at the InP/InGaAs interface. In this description the fitting property is the effective conductivity, σ eff( T), in mho cm-1. Variation in the data suggests σ eff (300 K) values of 1.2 × 10-11-4.6 × 10-11 mho cm-1). Substrate removal extends the quantum efficiency (QE) spectral band into the visible region. However, dead-layer effects limit the QE to 10% at a wavelength of 0.5 μm. For starlight-no moon illumination conditions, the signal-to-noise ratio is estimated to be 50 at an operating temperature of 300 K. A major result of the 3D numerical simulation of the device is the prediction of a perimeter G-R current not associated with the properties of the metallurgical interface. Another is the prediction that for a junction positioned in the larger band gap InP cap layer the QE is bias-dependent and that a relatively large reverse bias ≥0.9 V is needed for the QE to saturate to the shallow homojunction value. At this higher bias the dark current is larger than the shallow homojunction value. The 3D numerical model and the analytical model agree in predicting and explaining the measured radiatively limited diffusion current originating at the n-side of the junction. The calculations of the area-dependent G-R current for the condition studied are also in agreement

  20. Isocratic high-performance liquid chromatography-photodiode-array detection method for determination of lysine- and arginine-vasopressins and oxytocin in biological samples.

    PubMed

    Rao, P S; Weinstein, G S; Wilson, D W; Rujikarn, N; Tyras, D H

    1991-01-04

    A simple, isocratic, sensitive (1 ng), and specific high-performance liquid chromatographic (HPLC) method based on photodiode-array detection (PAD) is described for simultaneous quantitation of the bioactive peptides, lysine vasopressin (LVP), arginine vasopressin (AVP) and oxytocin (OXY). Acidified pig plasma and left ventricular (LV) tissue samples were first extracted with Sep-Pak C18 columns, and the bioactive peptides were eluted with methanol, then dried at 37 degrees C and reconstituted with HPLC mobile phase. The bioactive peptides were separated by HPLC on a Dynamax 3009-A C8 column with a mobile phase of 0.1% trichloroacetic acid-50 mM heptanesulfonic acid-30mM triethylamine-20% acetonitrile in water, pH 2.5 and identified with a Waters 990-PAD system (spectrum index plots in the range 200-400 nm). Standards of LVP, AVP and OXY and their mixtures showed a linear increase in the range 5 to 100 ng and were eluted at 6.1, 6.9 and 4.6 min, respectively. Spectrum analysis showed a distinct absorption peak at 280 nm, corresponding to peptide bonds. The reproducibility of the method coefficient of variation for standards is 6.9, 5.8 and 4.7% for LVP, AVP and OXY, respectively. In plasma and tissue it is much higher: 12.9% (LV tissue) and 18.6% (plasma) for LVP. Pig plasma contains negligible amounts of AVP and OXY; LVP is much higher (0.28 +/- 0.19 ng/ml). In pig tissue, LVP predominates (6.95 ng/g wet weight) compared to AVP (1.45) and OXY (1.50). Spectral analysis is necessary to identify the bioactive peptide peaks among interfering substances and to increase the sensitivity four-fold. The method described here is useful for the simultaneous determination of LVP, AVP and OXY in the nanogram range and can be extended to picogram levels by employing PAD spectral analysis techniques.

  1. Gallium-based avalanche photodiode optical crosstalk

    NASA Astrophysics Data System (ADS)

    Blazej, Josef; Prochazka, Ivan; Hamal, Karel; Sopko, Bruno; Chren, Dominik

    2006-11-01

    Solid-state single photon detectors based on avalanche photodiode are getting more attention in various areas of applied physics: optical sensors, quantum key distribution, optical ranging and Lidar, time-resolved spectroscopy, X-ray laser diagnostics, and turbid media imaging. Avalanche photodiodes specifically designed for single photon counting semiconductor avalanche structures have been developed on the basis of various materials: Si, Ge, GaP, GaAsP, and InGaP/InGaAs at the Czech Technical University in Prague during the last 20 years. They have been tailored for numerous applications. Trends in demand are focused on detection array construction recently. Even extremely small arrays containing a few cells are of great importance for users. Electrical crosstalk between individual gating and quenching circuits and optical crosstalk between individual detecting cells are serious limitation for array design and performance. Optical crosstalk is caused by the parasitic light emission of the avalanche which accompanies the photon detection process. We have studied in detail the optical emission of the avalanche photon counting structure in the silicon- and gallium-based photodiodes. The timing properties and spectral distribution of the emitted light have been measured for different operating conditions to quantify optical crosstalk. We conclude that optical crosstalk is an inherent property of avalanche photodiode operated in Geiger mode. The only way to minimize optical crosstalk in avalanche photodiode array is to build active quenching circuit with minimum response time.

  2. Development and application of a validated stability-indicating high-performance liquid chromatographic method using photodiode array detection for simultaneous determination of granisetron, methylparaben, propylparaben, sodium benzoate, and their main degradation products in oral pharmaceutical preparations.

    PubMed

    Hewala, Ismail; El-Fatatry, Hamed; Emam, Ehab; Mabrouk, Mokhtar

    2011-01-01

    A simple, rapid, and sensitive RP-HPLC method using photodiode array detection was developed and validated for the simultaneous determination of granisetron hydrochloride, 1-methyl-1H-indazole-3-carboxylic acid (the main degradation product of granisetron), sodium benzoate, methylparaben, propylparaben, and 4-hydroxybenzoic acid (the main degradation product of parabens) in granisetron oral drops and solutions. The separation of the compounds was achieved within 8 min on a SymmetryShield RP18 column (100 x 4.6 mm id, 3.5 microm particle size) using the mobile phase acetonitrile--0.05 M KH2PO4 buffered to pH 3 using H3PO4 (3+7, v/v). The photodiode array detector was used to test the purity of the peaks, and the chromatograms were extracted at 240 nm. The method was validated, and validation acceptance criteria were met in all cases. The robust method was successfully applied to the determination of granisetron and preservatives, as well as their degradation products in different batches of granisetron oral drops and solutions. The method proved to be sensitive for determination down to 0.04% (w/w) of granisetron degradation product relative to granisetron and 0.03% (w/w) 4-hydroxybenzoic acid relative to total parabens.

  3. Photodiodes based on self-assembled GeSi/Si(001) nanoisland arrays grown by the combined sublimation molecular-beam epitaxy of silicon and vapor-phase epitaxy of germanium

    SciTech Connect

    Filatov, D. O.; Gorshkov, A. P.; Volkova, N. S.; Guseinov, D. V.; Alyabina, N. A.; Ivanova, M. M.; Chalkov, V. Yu.; Denisov, S. A.; Shengurov, V. G.

    2015-03-15

    We investigate the photosensitivity spectra of photodiodes based on Si p-i-n structures with single-layered and multilayer self-assembled GeSi/Si(001) nanoisland arrays in the i region, which are grown using a technique combining Si molecular-beam epitaxy and Ge vapor-phase epitaxy, in dependence on the temperature, diode bias, and GeSi nanoisland parameters. We show that the temperature and field dependences of the diode photosensitivity in the spectral range of the interband optical absorption in GeSi nanoislands are determined by the ratio between the rate of emission of photoexcited holes from the nanoislands and the rate of the recombination of excess carriers in them. We demonstrate the possibility of determination of the hole recombination lifetime in GeSi nanoislands from the temperature and field dependences of the photosensitivity.

  4. Phytochemical and morphological characterization of hop (Humulus lupulus L.) cones over five developmental stages using high performance liquid chromatography coupled to time-of-flight mass spectrometry, ultrahigh performance liquid chromatography photodiode array detection, and light microscopy techniques.

    PubMed

    Kavalier, Adam R; Litt, Amy; Ma, Chunhui; Pitra, Nicholi J; Coles, Mark C; Kennelly, Edward J; Matthews, Paul D

    2011-05-11

    Hop (Humulus lupulus L.) inflorescences, commonly known as "hop cones", are prized for their terpenophenolic contents, used in beer production and, more recently, in biomedical applications. In this study we investigated morphological and phytochemical characteristics of hop cones over five developmental stages, using liquid chromatography coupled to time-of-flight mass spectrometry (LC-TOF-MS), and ultrahigh performance liquid chromatography photodiode array detection (UHPLC-PDA) methods to quantitate 21 polyphenolics and seven terpenophenolics. Additionally, we used light microscopy to correlate phytochemical quantities with changes in the morphology of the cones. Significant increases in terpenophenolics, concomitant with glandular trichome development and associated gross morphological changes, were mapped over development to fluctuations in contents of polyphenolic constituents and their metabolic precursor compounds. The methods reported here can be used for targeted metabolic profiling of flavonoids, phenolic acids, and terpenophenolics in hops, and are applicable to quantitation in other crops.

  5. A polychromator-type near-infrared spectrometer with a high-sensitivity and high-resolution photodiode array detector for pharmaceutical process monitoring on the millisecond time scale

    NASA Astrophysics Data System (ADS)

    Murayama, Kodai; Genkawa, Takuma; Ishikawa, Daitaro; Komiyama, Makoto; Ozaki, Yukihiro

    2013-02-01

    In the fine chemicals industry, particularly in the pharmaceutical industry, advanced sensing technologies have recently begun being incorporated into the process line in order to improve safety and quality in accordance with process analytical technology. For estimating the quality of powders without preparation during drug formulation, near-infrared (NIR) spectroscopy has been considered the most promising sensing approach. In this study, we have developed a compact polychromator-type NIR spectrometer equipped with a photodiode (PD) array detector. This detector is consisting of 640 InGaAs-PD elements with 20-μm pitch. Some high-specification spectrometers, which use InGaAs-PD with 512 elements, have a wavelength resolution of about 1.56 nm when covering 900-1700 nm range. On the other hand, the newly developed detector, having the PD with one of the world's highest density, enables wavelength resolution of below 1.25 nm. Moreover, thanks to the combination with a highly integrated charge amplifier array circuit, measurement speed of the detector is higher by two orders than that of existing PD array detectors. The developed spectrometer is small (120 mm × 220 mm × 200 mm) and light (6 kg), and it contains various key devices including the high-density and high-sensitivity PD array detector, NIR technology, and spectroscopy technology for a spectroscopic analyzer that has the required detection mechanism and high sensitivity for powder measurement, as well as a high-speed measuring function for blenders. Moreover, we have evaluated the characteristics of the developed NIR spectrometer, and the measurement of powder samples confirmed that it has high functionality.

  6. A polychromator-type near-infrared spectrometer with a high-sensitivity and high-resolution photodiode array detector for pharmaceutical process monitoring on the millisecond time scale.

    PubMed

    Murayama, Kodai; Genkawa, Takuma; Ishikawa, Daitaro; Komiyama, Makoto; Ozaki, Yukihiro

    2013-02-01

    In the fine chemicals industry, particularly in the pharmaceutical industry, advanced sensing technologies have recently begun being incorporated into the process line in order to improve safety and quality in accordance with process analytical technology. For estimating the quality of powders without preparation during drug formulation, near-infrared (NIR) spectroscopy has been considered the most promising sensing approach. In this study, we have developed a compact polychromator-type NIR spectrometer equipped with a photodiode (PD) array detector. This detector is consisting of 640 InGaAs-PD elements with 20-μm pitch. Some high-specification spectrometers, which use InGaAs-PD with 512 elements, have a wavelength resolution of about 1.56 nm when covering 900-1700 nm range. On the other hand, the newly developed detector, having the PD with one of the world's highest density, enables wavelength resolution of below 1.25 nm. Moreover, thanks to the combination with a highly integrated charge amplifier array circuit, measurement speed of the detector is higher by two orders than that of existing PD array detectors. The developed spectrometer is small (120 mm × 220 mm × 200 mm) and light (6 kg), and it contains various key devices including the high-density and high-sensitivity PD array detector, NIR technology, and spectroscopy technology for a spectroscopic analyzer that has the required detection mechanism and high sensitivity for powder measurement, as well as a high-speed measuring function for blenders. Moreover, we have evaluated the characteristics of the developed NIR spectrometer, and the measurement of powder samples confirmed that it has high functionality.

  7. Sensitive chiral high-performance liquid chromatographic determination of anthelmintic flubendazole and its phase I metabolites in blood plasma using UV photodiode-array and fluorescence detection Application to pharmacokinetic studies in sheep.

    PubMed

    Nobilis, Milan; Vybíralová, Zuzana; Krízová, Veronika; Kubícek, Vladimír; Soukupová, Marie; Lamka, Jirí; Szotáková, Barbora; Skálová, Lenka

    2008-12-01

    Although benzimidazole anthelmintic flubendazole, methyl ester of [5-(4-fluorobenzoyl)-1H-benzimidazol-2-yl]carbamic acid, is extensively used in veterinary and human medicine for the treatment of gastrointestinal parasitic helminth infections, reliable data about its pharmacokinetics in various species have not been reported. Our previous work [M. Nobilis, Th. Jira, M. Lísa, M. Holcapek, B. Szotáková, J. Lamka, L.Skálová, J. Chromatogr. A 1149 (2007) 112-120] had described the stereospecificity of carbonyl reduction during phase I metabolic experiments in vitro. For in vivo pharmacokinetic studies, further improvement and optimization of bioanalytical HPLC method in terms of sensitivity and selectivity was necessary. Hence, a modified chiral bioanalytical HPLC method involving both UV photodiode-array and fluorescence detection for the determination of flubendazole, both enantiomers of reduced flubendazole and hydrolyzed flubendazole in the extracts from plasma samples was tested and validated. Albendazole was used as an internal standard. Sample preparation process involved a pH-dependent extraction of the analytes from the blood plasma into tert-butylmethyl ether. Chromatographic separations were performed on a Chiralcel OD-R 250 mm x 4.6mm column with mobile phase methanol-1M NaClO(4) (75:25, v/v) at the flow rate 0.5 ml min(-1). In quantitation, selective UV absorption maxima of 290 nm (for reduced flubendazole), 295 nm (for albendazole), 310 nm (for flubendazole) and 330 nm (for hydrolyzed flubendazole) were used in the UV photodiode-array detection, and lambda(exc.)/lambda(emis.)=228 nm/310 nm (for reduced flubendazole) and lambda(exc.)/lambda(emis.)=236 nm/346 nm (for albendazole) were set on the fluorescence detector. The fluorescence detection was approximately 10-times more sensitive than the UV detection. Each HPLC run lasted 27 min. The validated chiral HPLC-PDA-FL method was employed in the pharmacokinetic studies of flubendazole in sheep. The

  8. Recent advances in avalanche photodiode technology

    NASA Astrophysics Data System (ADS)

    Squillante, Michael R.; Gordon, Jeffrey S.; Farrell, Richard; Vasile, Stefan A.; Daley, Kathleen; Oakes, Carlton E.; Vanderpuye, K.

    1993-12-01

    Avalanche photodiodes (APDs) are solid state devices having an internal signal gain which gives them a better signal-to-noise ratio than standard photodiodes. Although they have been studied for years, recent advances in the fabrication techniques have allowed the construction of multielement arrays (up to 10 X 10) with high performance capability. This progress has resulted in increased potential for exploiting the advantages of APDs in a variety of important applications including measurements requiring fast response such as nuclear and high energy physics research, industrial nondestructive testing, medical instrumentation, and biomedical research using low energy particles. Recent experimental data characterizing APDs and APD arrays used as x-ray, particle, and low level light detectors are presented.

  9. A 1.5k x 1.5k class photon counting HgCdTe linear avalanche photo-diode array for low background space astronomy in the 1-5micron infrared

    NASA Astrophysics Data System (ADS)

    Hall, Donald

    Under a current award, NASA NNX 13AC13G "EXTENDING THE ASTRONOMICAL APPLICATION OF PHOTON COUNTING HgCdTe LINEAR AVALANCHE PHOTODIODE ARRAYS TO LOW BACKGROUND SPACE OBSERVATIONS" UH has used Selex SAPHIRA 320 x 256 MOVPE L-APD HgCdTe arrays developed for Adaptive Optics (AO) wavefront (WF) sensing to investigate the potential of this technology for low background space astronomy applications. After suppressing readout integrated circuit (ROIC) glow, we have placed upper limits on gain normalized dark current of 0.01 e-/sec at up to 8 volts avalanche bias, corresponding to avalanche gain of 5, and have operated with avalanche gains of up to several hundred at higher bias. We have also demonstrated detection of individual photon events. The proposed investigation would scale the format to 1536 x 1536 at 12um (the largest achievable in a standard reticule without requiring stitching) while incorporating reference pixels required at these low dark current levels. The primary objective is to develop, produce and characterize a 1.5k x 1.5k at 12um pitch MOVPE HgCdTe L-APD array, with nearly 30 times the pixel count of the 320 x 256 SAPHIRA, optimized for low background space astronomy. This will involve: 1) Selex design of a 1.5k x 1.5k at 12um pitch ROIC optimized for low background operation, silicon wafer fabrication at the German XFab foundry in 0.35 um 3V3 process and dicing/test at Selex, 2) provision by GL Scientific of a 3-side close-buttable carrier building from the heritage of the HAWAII xRG family, 3) Selex development and fabrication of 1.5k x 1.5k at 12 um pitch MOVPE HgCdTe L-APD detector arrays optimized for low background applications, 4) hybridization, packaging into a sensor chip assembly (SCA) with initial characterization by Selex and, 5) comprehensive characterization of low background performance, both in the laboratory and at ground based telescopes, by UH. The ultimate goal is to produce and eventually market a large format array, the L

  10. Concurrent liquid chromatographic separation and photodiode array detection of retinol, tocopherols, all-trans-alpha-carotene, all-trans-beta-carotene and the mono-cis isomers of beta-carotene in extracts of human plasma.

    PubMed

    Lane, J R; Webb, L W; Acuff, R V

    1997-11-07

    In this report we describe the development of a method for the concurrent reversed-phase high-performance liquid chromatographic separation and photodiode array detection of human plasma retinol, tocopherols and carotenes. For a single sample injection, retinol, retinyl acetate, alpha-tocopherol, gamma-tocopherol, alpha-tocopheryl acetate, all-trans-alpha-carotene and all-trans-beta-carotene, as well as the mono-cis geometrical isomers of beta-carotene were separated and detected. Analytical separations were performed at a subambient temperature (0 degree C) over a Suplex pKb-100 reversed-phase analytical column with an isocratic mobile phase of methanol-methyl tert.-butyl ether-water (80:20:5, v/v/v) at a flow-rate of 0.8 ml/min for 60 min. Standards and samples were reconstituted in ethanol, and typically, 50 microliters was injected for analysis. By HPLC, compounds of interest were clearly resolved and detectable at the picomole level.

  11. Characterization and identification of the chemical constituents from tartary buckwheat (Fagopyrum tataricum Gaertn) by high performance liquid chromatography/photodiode array detector/linear ion trap FTICR hybrid mass spectrometry.

    PubMed

    Ren, Qiang; Wu, Caisheng; Ren, Yan; Zhang, Jinlan

    2013-02-15

    In recent years tartary buckwheat has become popular healthful food due to its antioxidant, antidiabetic and antitumor activities. However, its chemical constituents have not yet been fully characterized and identified. In this paper, a novel high performance liquid chromatography coupled with photodiode array detector and linear ion trap FTICR hybrid mass spectrometry (HPLC-PDA/LTQ-FTICRMS) method was established to characterize and identify a total of 36 compounds by a single run. The retention time, maximum UV absorption wavelength, accurate mass weight and characteristic fragment ions were collected on line. To confirm the structures, 11 compounds were isolated and identified by MS and NMR experiments. 1, 3, 6, 6'-tetra-feruloyl sucrose named taroside was a new phenlypropanoid glycoside, together with 3, 6-di-p-coumaroyl-1, 6'-di-feruloyl sucrose, 1, 6, 6'-tri-feruloyl-3-p-coumaroyl sucrose, N-trans-feruloyltyramine and quercetin-3-O-[β-D-xyloxyl-(1→2)-α-L-rhamnoside] were isolated for the first time from the Fagopyrum species. The research enriched the chemical information of tartary buckwheat. Copyright © 2012 Elsevier Ltd. All rights reserved.

  12. Quantitative Determination of Spermidine in 50 German Cheese Samples on a Core-Shell Column by High-Performance Liquid Chromatography with a Photodiode Array Detector Using a Fully Validated Method.

    PubMed

    Esatbeyoglu, Tuba; Ehmer, Andreas; Chaize, Delphine; Rimbach, Gerald

    2016-03-16

    In the current study, the spermidine (8) contents of 51 German and 9 international cheese samples (from France, Ireland, Italy, The Netherlands, and Switzerland) were analyzed by a modified and fully validated method using high-performance liquid chromatography with photodiode array detection. After precolumn derivatization of biogenic amines with dansyl chloride (11), the compounds were separated on a Kinetex C18 column and detected at λ = 254 nm. This method for compound 8 analysis in cheese was validated for the first time according to U.S. Food and Drug Administration (FDA) guidelines for bioanalytical method validation with regard to selectivity, precision, accuracy, recovery, linearity, lower limit of detection (LOD), lower limit of quantitation (LOQ), standard solution stability, short- and long-term stability, freeze-thaw stability, and benchtop stability. The detector response was linear from 0.002 to 8 mg/L 8 (R(2) > 0.999). Low LOD and LOQ values of 1 and 2 μg/L, respectively, reflected the high sensitivity of the method. The intra- and interday recoveries of the 8-spiked cheese samples ranged between 87.7 and 102.6%. This validated method was selective, accurate, and precise and was successfully applied for the quantitative analysis of compound 8 in 60 cheese samples. Furthermore, the simultaneous detection of eight additional biogenic amines is possible but not validated.

  13. Determination and purification of sesamin and sesamolin in sesame seed oil unsaponified matter using reversed-phase liquid chromatography coupled with photodiode array and tandem mass spectrometry and high-speed countercurrent chromatography.

    PubMed

    Takahashi, Miki; Nishizaki, Yuzo; Sugimoto, Naoki; Takeuchi, Hiroaki; Nakagawa, Kazuya; Akiyama, Hiroshi; Sato, Kyoko; Inoue, Koichi

    2016-10-01

    In Asian countries, sesame seed oil unsaponified matter is used as a natural food additive due to its associated antioxidant effects. We determined and purified the primary lignans sesamin and sesamolin in sesame seed oil unsaponified matter using reversed-phase liquid chromatography coupled with photodiode array and tandem mass spectrometry and high-speed countercurrent chromatography. Calibration curves showed good correlation coefficients (r(2) > 0.999, range 0.08 and/or 0.15 to 5 μg/mL) with a limit of detection (at 290 nm) of 0.02 μg/mL for sesamin and 0.04 μg/mL for sesamolin. Sesame seed oil unsaponified matter contained 2.82% sesamin and 2.54% sesamolin, respectively. Direct qualitative analysis of sesamin and sesamolin was achieved using quadrupole mass spectrometry with positive-mode electrospray ionization. Pure (>99%) sesamin and sesamolin standards were obtained using high-speed countercurrent chromatographic purification (hexane/ethyl acetate/methanol/water; 7:3:7:3). An effective method for determining and purifying sesamin and sesamolin from sesame seed oil unsaponified matter was developed by combining these separation techniques for standardized food additives.

  14. Analysis of flavonoids from lotus (Nelumbo nucifera) leaves using high performance liquid chromatography/photodiode array detector tandem electrospray ionization mass spectrometry and an extraction method optimized by orthogonal design.

    PubMed

    Chen, Sha; Wu, Ben-Hong; Fang, Jin-Bao; Liu, Yan-Ling; Zhang, Hao-Hao; Fang, Lin-Chuan; Guan, Le; Li, Shao-Hua

    2012-03-02

    The extraction protocol of flavonoids from lotus (Nelumbo nucifera) leaves was optimized through an orthogonal design. The solvent was the most important factor comparing solvent, solvent:tissue ratio, extraction time, and temperature. The highest yield of flavonoids was achieved with 70% methanol-water and a solvent:tissue ratio of 30:1 at 4 °C for 36 h. The optimized analytical method for HPLC was a multi-step gradient elution using 0.5% formic acid (A) and CH₃CN containing 0.1% formic acid (B), at a flow rate of 0.6 mL/min. Using this optimized method, thirteen flavonoids were simultaneously separated and identified by high performance liquid chromatography coupled with photodiode array detection/electrospray ionization mass spectrometry (HPLC/DAD/ESI-MS(n)). Five of the bioactive compounds are reported in lotus leaves for the first time. The flavonoid content of the leaves of three representative cultivars was assessed under the optimized extraction and HPLC analytical conditions, and the seed-producing cultivar 'Baijianlian' had the highest flavonoid content compared with rhizome-producing 'Zhimahuoulian' and wild floral cultivar 'Honglian'. Copyright © 2012 Elsevier B.V. All rights reserved.

  15. Robust method for investigating nitrogen metabolism of 15N labeled amino acids using AccQ•Tag ultra performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry: application to a parasitic plant-plant interaction.

    PubMed

    Gaudin, Zachary; Cerveau, Delphine; Marnet, Nathalie; Bouchereau, Alain; Delavault, Philippe; Simier, Philippe; Pouvreau, Jean-Bernard

    2014-01-21

    An AccQ•Tag ultra performance liquid chromatography-photodiode array-electrospray ionization-mass spectrometry (AccQ•Tag-UPLC-PDA-ESI-MS) method is presented here for the fast, robust, and sensitive quantification of (15)N isotopologue enrichment of amino acids in biological samples, as for example in the special biotic interaction between the cultivated specie Brassica napus (rapeseed) and the parasitic weed Phelipanche ramosa (broomrape). This method was developed and validated using amino acid standard solutions containing (15)N amino acid isotopologues and/or biological unlabeled extracts. Apparatus optimization, limits of detection and quantification, quantification reproducibility, and calculation method of (15)N isotopologue enrichment are presented. Using this method, we could demonstrate that young parasite tubercles assimilate inorganic nitrogen as (15)N-ammonium when supplied directly through batch incubation but not when supplied by translocation from host root phloem, contrary to (15)N2-glutamine. (15)N2-glutamine mobility from host roots to parasite tubercles followed by its low metabolism in tubercles suggests that the host-derived glutamine acts as an important nitrogen containing storage compound in the young tubercle of Phelipanche ramosa.

  16. 2.5-μm InGaAs photodiodes grown on GaAs substrates by interfacial misfit array technique

    NASA Astrophysics Data System (ADS)

    Jurczak, Pamela; Sablon, Kimberly A.; Gutiérrez, Marina; Liu, Huiyun; Wu, Jiang

    2017-03-01

    In0.85Ga0.15As photodetectors grown on GaAs substrates using an interfacial misfit array-based simple buffer are studied. The material quality is assessed with a range of characterization tools showing low surface roughness and low density of threading dislocations. These results indicate a significant improvement on crystal quality compared to structures grown on InP substrates by using metamorphic buffers. Quantum efficiency and responsivity measurements show good performance of the fabricated devices between 1.5 and 2.5 μm, making them highly suitable for short-wavelength infrared applications.

  17. ZnO homojunction photodiodes based on Sb-doped p-type nanowire array and n-type film for ultraviolet detection

    SciTech Connect

    Wang Guoping; Chu Sheng; Zhan Ning; Liu Jianlin; Lin Yuqing; Chernyak, Leonid

    2011-01-24

    ZnO p-n homojunctions based on Sb-doped p-type nanowire array and n-type film were grown by combining chemical vapor deposition (for nanowires) with molecular-beam epitaxy (for film). Indium tin oxide and Ti/Au were used as contacts to the ZnO nanowires and film, respectively. Characteristics of field-effect transistors using ZnO nanowires as channels indicate p-type conductivity of the nanowires. Electron beam induced current profiling confirmed the existence of ZnO p-n homojunction. Rectifying I-V characteristic showed a turn-on voltage of around 3 V. Very good response to ultraviolet light illumination was observed from photocurrent measurements.

  18. ZnO homojunction photodiodes based on Sb-doped p-type nanowire array and n-type film for ultraviolet detection

    NASA Astrophysics Data System (ADS)

    Wang, Guoping; Chu, Sheng; Zhan, Ning; Lin, Yuqing; Chernyak, Leonid; Liu, Jianlin

    2011-01-01

    ZnO p-n homojunctions based on Sb-doped p-type nanowire array and n-type film were grown by combining chemical vapor deposition (for nanowires) with molecular-beam epitaxy (for film). Indium tin oxide and Ti/Au were used as contacts to the ZnO nanowires and film, respectively. Characteristics of field-effect transistors using ZnO nanowires as channels indicate p-type conductivity of the nanowires. Electron beam induced current profiling confirmed the existence of ZnO p-n homojunction. Rectifying I-V characteristic showed a turn-on voltage of around 3 V. Very good response to ultraviolet light illumination was observed from photocurrent measurements.

  19. Cuban and Brazilian red propolis: botanical origin and comparative analysis by high-performance liquid chromatography-photodiode array detection/electrospray ionization tandem mass spectrometry.

    PubMed

    Piccinelli, Anna Lisa; Lotti, Cinzia; Campone, Luca; Cuesta-Rubio, Osmany; Campo Fernandez, Mercedes; Rastrelli, Luca

    2011-06-22

    Chemical composition of propolis depends on the specificity of the local flora at the site of collection and thus on the geographic and climatic characteristics of this place. This paper describes a comparative analysis of Cuban red propolis (CRP), Brazilian red propolis (BRP), and Dalbergia ecastophyllum exudates (DEE) by high-performance liquid chromatography with diode-array detection and tandem mass spectrometry. The aim of this study was to investigate the overall chemical profile and the botanical origin of red propolis and to suggest similarities and differences between samples collected in different tropical regions. Isoliquiritigenin (1), liquiritigenin and naringenin (2 and 17), isoflavones (3-4 and 16), isoflavans (5-7 and 18), and pterocarpans (8-13) were detected in CRP, BRP, and DEE, whereas polyisoprenylated benzophenones (PPBs) guttiferone E/xanthochymol (14a,b) and oblongifolin A (15) were detected only in BRP. Pigments responsible for the red color of DEE and red propolis were also identified as two C30 isoflavans, the new retusapurpurin B (19) and retusapurpurin A (20). PPBs and pigments were isolated and unambiguously characterized by 1D and 2D NMR analysis. These results show that red propolis samples from different tropical zones have a similar chemical composition. DEE is the main red propolis source, but the presence of PPBs in BRP suggests the contribution of different botanical sources for Brazilian samples. This chemical information is important for quality control of red propolis and its commercial products and for biological study.

  20. Comparison of Stability-Indicating LC Methods Using Light Scattering and Photodiode Array Detection with Monolithic Column for Determination of Quinapril and Hydrochlorothiazide.

    PubMed

    de Diego, Marta; Godoy, Ricardo; Mennickent, Sigrid; Vergara, Carola; Charnock, Henry; Hernández, Camilo

    2016-09-01

    Rapid stability-indicating LC methods for simultaneous analysis of quinapril and hydrochlorothiazide were developed, validated and compared using evaporative light scattering detection (ELSD) and diode array detection (DAD). For the separation of quinapril, hydrochlorothiazide and its major degradation products, a monolithic column was used and the analytes were eluted within 7 min, applying gradient mobile phase in both methods. Quinapril was subjected to hydrolytic, oxidative, thermal, humidity and photolytic stress conditions. Degradation products were well resolved from main peaks and from each other, proving the stability-indicating power of the methods. The response with DAD was linear and the response with ELSD was fitted to a power function, for quinapril and hydrochlorothiazide concentrations of 20-160 and 12.5-100 µg mL(-1), respectively. DAD method achieved better precision than ELSD method, the LOQ of DAD was lower and the accuracy of the methods was similar. Quinapril degrade by hydrolysis and thermal stress, showing the formation of quinaprilat and quinapril diketopiperazine as degradants, which were identified by MS-MS. The methods were successfully applied to quantify quinapril and hydrochlorothiazide in commercial tablets. LC-DAD and LC-ELSD methods are suitable to assess the stability and routine analysis of quinapril and hydrochlorothiazide in pharmaceutical industry.

  1. Simultaneous determination of three diarylheptanoids and an alpha-tetralone derivative in the green walnut husks (Juglans regia L.) by high-performance liquid chromatography with photodiode array detector.

    PubMed

    Liu, Junxi; Meng, Min; Li, Chen; Huang, Xinyi; Di, Duolong

    2008-05-09

    By optimizing extraction, separation and analytical conditions, a reliable and accurate high-performance liquid chromatographic (HPLC) method coupled with photodiode array detector (DAD) at room temperature is developed for simultaneous determination of three diarylheptanoids (juglanin A, juglanin B, rhoiptelol) and an alpha-tetralone derivative (regiolone) in methanol extracts from the green walnut husks (Juglans regia L.) The sample pretreatment process involved the reflux extraction using methanol as the extract with a ratio of liquor to sample of 15 mL/g. The separation was achieved on a SinoChrom ODS-AP C(18) column with gradient elution using acetonitrile and 2% (v/v) acetic acid in water. The intra-day and inter-day precision (RSD%) for the analytes ranged from 1.08 to 1.51 and 0.60 to 1.13, respectively. The average recoveries obtained were from 88.4% to 96.2% for the analytes with RSDs below 3.13%. The correlation coefficients of the calibration curve exceeded 0.999. The detection limits were 0.51, 0.25, 0.32 and 0.35 ng at a signal-to-noise ratio of 3, respectively. Quantitative analyses of the samples from different grown sites and in obtained different months showed that the contents of the analytes varied significantly. The method was then successfully applied for the detection and isolation of a new diarylheptanoid derivative in the green walnut husks (J. regia L.). The structure of the new compound was elucidated by various spectroscopic methods including 2D NMR techniques (COSY, HMQC, HMBC), HR-ESI-MS and X-ray single-crystal diffraction analysis.

  2. Simultaneous determination of arbutin and its decomposed product hydroquinone in whitening creams using high-performance liquid chromatography with photodiode array detection: Effect of temperature and pH on decomposition.

    PubMed

    Jeon, J S; Kim, B H; Lee, S H; Kwon, H J; Bae, H J; Kim, S K; Park, J A; Shim, J H; Abd El-Aty, A M; Shin, H C

    2015-12-01

    Arbutin is an effective agent for the treatment of melanin disorders. Arbutin may be converted to hydroquinone under conditions of high temperature, ultraviolet (UV) radiation and dilute acid. The aim of the current study was to develop an analytical method to determine the levels of arbutin and hydroquinone in whitening cosmetic products using high-performance liquid chromatography with photodiode array detection (HPLC-DAD). In addition, we investigated the effects of high temperature and pH on the decomposition of arbutin. Samples extracted using two-step sonications were separated on a C18 column using a gradient mobile phase consisting of water and methanol. A 60-mm (40 μL) DAD cell was used to enhance the sensitivity of hydroquinone determination. Thermal decomposition of arbutin was evaluated at temperatures ranging from 60 to 120°C for 1-36 h. The method showed good linearity (R(2) ≥ 0.9997), precision (relative standard deviation, RSD < 5%) and acceptable extraction recovery (90-102.6%). The limits of quantitation for arbutin and hydroquinone were 0.0085 and 0.0119 μg mL(-1) , respectively. One sample of 21 cosmetic products tested contained arbutin at a concentration 1.61 g 100 g(-1) cream and 0.12 g 100 g(-1) cream of hydroquinone. Arbutin (327.18 ppm) decomposed after 6 h at 120°C and produced 10.73 ppm of hydroquinone. The developed method is simple to detect both arbutin and hydroquinone simultaneously in cosmetic products, at an adequate level of sensitivity. Notably, temperature and pH did not influence the decomposition of arbutin to hydroquinone in a 2% arbutin cream. © 2015 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

  3. An improved high performance liquid chromatography-photodiode array detection-atmospheric pressure chemical ionization-mass spectrometry method for determination of chlorophylls and their derivatives in freeze-dried and hot-air-dried Rhinacanthus nasutus (L.) Kurz.

    PubMed

    Kao, Tsai Hua; Chen, Chia Ju; Chen, Bing Huei

    2011-10-30

    Rhinacanthus nasutus (L.) Kurz, a traditional Chinese herb possessing antioxidant and anti-cancer activities, has been reported to contain functional components like carotenoids and chlorophylls. However, the variety and amount of chlorophylls remain uncertain. The objectives of this study were to develop a high performance liquid chromatography-photodiode array detection-atmospheric pressure chemical ionization-mass spectrometry (HPLC-DAD-APCI-MS) method for determination of chlorophylls and their derivatives in hot-air-dried and freeze-dried R. nasutus. An Agilent Eclipse XDB-C18 column and a gradient mobile phase composed of methanol/N,N-dimethylformamide (97:3, v/v), acetonitrile and acetone were employed to separate internal standard zinc-phthalocyanine plus 12 cholorophylls and their derivatives within 21 min, including chlorophyll a, chlorophyll a', hydroxychlorophyll a, 15-OH-lactone chlorophyll a, chlorophyll b, chlorophyll b', hydroxychlorophyll b, pheophytin a, pheophytin a', hydroxypheophytin a, hydroxypheophytin a' and pheophytin b in hot-air-dried R. nasutus with flow rate at 1 mL/min and detection at 660 nm. But, in freeze-dried R. nasutus, only 4 chlorophylls and their derivatives, including chlorophyll a, chlorophyll a', chlorophyll b and pheophytin a were detected. Zinc-phthalocyanine was found to be an appropriate internal standard to quantify all the chlorophyll compounds. After quantification by HPLC-DAD, both chlorophyll a and pheophytin a were the most abundant in hot-air-dried R. nasutus, while in freeze-dried R. nasutus, chlorophyll a and chlorophyll b dominated.

  4. Simultaneous determination of vitexin-2"-O-glucoside, vitexin-2"-O-rhamnoside, rutin, and hyperoside in the extract of hawthorn (Crataegus pinnatifida Bge.) leaves by RP-HPLC with ultraviolet photodiode array detection.

    PubMed

    Cheng, Shan; Qiu, Feng; Huang, Jia; He, Junqi

    2007-03-01

    RP-HPLC with UV photodiode array detection (UV-DAD) was developed and validated for the simultaneous determination of vitexin-2"-O-glucoside, vitexin-2"-O-rhamnoside, rutin, and hyperoside in the extract of hawthorn (Crataegus pinnatifida Bge.) leaves. The analytes of interest were separated on a Diamonsil C18 column (250 x 4.6 mm id, 5 microm) with the mobile phase consisting of THF/ACN/methanol/ 0.05% phosphoric acid solution (pH 5.0) (18:1:1:80 v/vl/v). The flow rate was set at 1.0 mL/min and the eluent was detected at 340 nm for the four flavonoids. The method was linear over the studied range of 1.00-100 microg/mL for the four analytes of interest with the correlation coefficient for each analyte greater than 0.999. The LOD and LOQwere 0.03 and 0.10 microg/mL, 0.03 and 0.10 microg/mL, 0.05 and 0.15 pg/mL, 0.10 and 0.30 microg/mL for vitexin-2"-O-glucoside, vitexin-2"-0-rhamnoside, rutin, and hyperoside, respectively. The optimized method was successfully applied to the analysis of four important flavonoids in the extract of hawthorn leaves. The total amounts of the four flavonoids were 22.2, 62.3, 4.27, and 8.24 mg/g dry weight for vitexin-2"-O-glucoside, vitexin-2"-O-rhamnoside, rutin, and hyperoside in the extract of hawthorn leaves, respectively.

  5. Rapid separation and identification of anthocyanins from flowers of Viola yedoensis and V. prionantha by high-performance liquid chromatography-photodiode array detection-electrospray ionisation mass spectrometry.

    PubMed

    Zhang, Jie; Wang, Liang-Sheng; Gao, Jin-Ming; Xu, Yan-Jun; Li, Lian-Fang; Li, Chong-Hui

    2012-01-01

    Anthocyanins are important plant secondary metabolites. They show strong antioxidant activities and have potential as anti-cancer agents. Viola yedoensis and V. prionantha are traditional Chinese medicines and ornamental plants. However, the anthocyanin compositions of these two species are still unresolved. To develop a rapid and reliable high-performance liquid chromatography (HPLC) method for the separation and identification of anthocyanins from V. yedoensis and V. prionantha. Samples were extracted in methanol-water-formic acid-TFA (70:27:2:1, v/v). HPLC analysis was done on a C(18) column (TSK-GEL ODS-80Ts: 150 × 4.6 mm i.d.). Four solvent systems were tested to optimise the separation of anthocyanins using different gradient separation systems. HPLC-photodiode array detection (DAD) coupled to electrospray ionisation mass spectrometry (ESI-MS) was used to carry out the comprehensive characterisation of anthocyanins. Fourteen anthocyanins were characterised within 40 min with satisfactory peak resolution by a gradient composed of 10% aqueous formic acid and formic acid-acetonitrile-water (10:40:50, v/v). The calibration curve showed an excellent linear regression (r(2)  = 0.9995) and low intra- and inter-day variations (RSD < 3.67%). The detected anthocyanins derived from Dp, Cy, Pt, Mv and Pn, could be divided into three groups: non-acylated glycosides, acetylglycosides and coumaroylglycosides. Anthocyanins distribution exhibited remarkable differences in aglycone levels and acylation patterns. The optimised method was successfully applied for the analysis of 14 anthocyanins from V. yedoensis and V. prionantha. The identification of anthocyanin constitutions is valuable for breeding and will open up new prospects for their medicinal application. Copyright © 2011 John Wiley & Sons, Ltd.

  6. Determination of selected water-soluble vitamins using hydrophilic chromatography: a comparison of photodiode array, fluorescence, and coulometric detection, and validation in a breakfast cereal matrix.

    PubMed

    Langer, Swen; Lodge, John K

    2014-06-01

    Water-soluble vitamins are an important class of compounds that require quantification from food sources to monitor nutritional value. In this study we have analysed six water-soluble B vitamins ([thiamine (B1), riboflavin (B2), nicotinic acid (B3, NAc), nicotinamide (B3, NAm), pyridoxal (B6), folic acid (B9)], and ascorbic acid (vit C) with hydrophilic interaction liquid chromatography (HILIC), and compared UV, fluorescent (FLD) and coulometric detection to optimise a method to quantitate the vitamins from food sources. Employing UV/diode array (DAD) and fluorimetric detection, six B vitamins were detected in a single run using gradient elution from 100% to 60% solvent B [10mM ammonium acetate, pH 5.0, in acetonitrile and water 95:5 (v:v)] over 18 min. UV detection was performed at 268 nm for B1, 260 nm for both B3 species and 284 nm for B9. FLD was employed for B2 at excitation wavelength of 268 nm, emission of 513 nm, and 284 nm/317 nm for B6. Coulometric detection can be used to detect B6 and B9, and vit C, and was performed isocratically at 75% and 85% of solvent B, respectively. B6 was analysed at a potential of 720 mV, while B9 was analysed at 600 mV, and vit C at 30 mV. Retention times (0.96 to 11.81 min), intra-day repeatability (CV 1.6 to 3.6), inter-day variability (CV 1.8 to 11.1), and linearity (R 0.9877 to 0.9995) remained good under these conditions with limits of detection varying from 6.6 to 164.6 ng mL(-1), limits of quantification between 16.8 and 548.7 ng mL(-1). The method was successfully applied for quantification of six B vitamins from a fortified food product and is, to our knowledge, the first to simultaneously determine multiple water-soluble vitamins extracted from a food matrix using HILIC. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. Reversed-phase high-performance Liquid Chromatography-ultraviolet Photodiode Array Detector Validated Simultaneous Quantification of six Bioactive Phenolic Acids in Roscoea purpurea Tubers and their In vitro Cytotoxic Potential against Various Cell Lines

    PubMed Central

    Srivastava, Sharad; Misra, Ankita; Kumar, Dharmesh; Srivastava, Amit; Sood, Anil; Rawat, AKS

    2015-01-01

    Background: Roscoea purpurea or Roscoea procera Wall. (Zingiberaceae) is traditionally used for nutrition and in the treatment of various ailments. Objective: Simultaneous reversed-phase high-performance liquid chromatography-ultraviolet (RP-HPLC) photodiode array detector identification of phenolic acids (PA's) was carried out in whole extract of tuber and their cytotoxic potential was estimated along with radical scavenging action. Bioactivity guided fractionation was also done to check the response potential against the same assay. Materials and Methods: Identification and method validation was performed on RP-HPLC column and in vitro assays were used for bioactivity. Results: Protocatechuic acid, syringic acid, ferulic acid, rutin, apigenin, and kaempferol were quantified as 0.774%, 0.064%, 0.265%, 1.125%, 0.128%, and 0.528%, respectively. Validated method for simultaneous determination of PA's was found to be accurate, reproducible, and linearity was observed between peak area response and concentration. Recovery of identified PA's was within the acceptable limit of 97.40–104.05%. Significant pharmacological response was observed in whole extract against in vitro cytotoxic assay, that is, Sulforhodamine B assay, however, fractionation results in decreased action potential. Similar pattern of results were observed in the antioxidant assay, as total phenolic content and total flavonoid content were highest in whole extract and decreases with fractionation. Radical scavenging activity was prominent in chloroform fraction, exhibiting IC50 at 0.25 mg/mL. Conclusion: Study, thus, reveals that R. purpurea exhibit significant efficacy in cytotoxic activity with the potentiality of scavenging free radicals due the presence of PA's as reported through RP-HPLC. SUMMARY Proto-catechuic acid, syringic acid, ferulic acid, rutin, apigenin and kaempferol were quantified as 0.774, 0.064, 0.265, 1.125, 0.128 and 0.528 %Preliminary cytotoxic activity revealed that whole

  8. Dark current study for CMOS fully integrated-PIN-photodiodes

    NASA Astrophysics Data System (ADS)

    Teva, Jordi; Jessenig, Stefan; Jonak-Auer, Ingrid; Schrank, Franz; Wachmann, Ewald

    2011-05-01

    PIN photodiodes are semiconductor devices widely used in a huge range of applications, such as photoconductors, charge-coupled devices and pulse oximeters for medical applications. The possibility to combine and to integrate the fabrication of the sensor with its signal conditioning circuitry in a CMOS process allows device miniaturization in addition to enhance its properties lowering the production and assembly costs. This paper presents the design and characterization of silicon based PIN photodiodes integrated in a CMOS commercial process. A high-resistivity, low impurity substrate is chosen as the start material for the PIN photodiode array fabrication in order to fabricate devices with a minimum dark current. The dark current is studied, analyzed and measured for two different starting materials and for different geometries. A model previously proposed is reviewed and compared with experimental data.

  9. Gathering effect on dark current for CMOS fully integrated-, PIN-photodiodes

    NASA Astrophysics Data System (ADS)

    Teva, Jordi; Jonak-Auer, Ingrid; Schrank, Franz; Kraft, Jochen; Siegert, Joerg; Wachmann, Ewald

    2010-02-01

    PIN photodiodes are semiconductor devices widely used in a huge range of applications, such as photoconductors, charge-coupled devices, and pulse oximeters. The possibility to combine and to integrate the fabrication of the sensor with its signal conditioning circuitry in a CMOS process flow opens the window to device miniaturization enhancing its properties and lowering the production and assembly costs. This paper presents the design and characterization of silicon based PIN photodiodes integrated in a CMOS commercial process. A high-resistivity, low impurity float zone substrate is chosen as the start material for the PIN photodiode array fabrication in order to fabricate devices with a minimum dark current. The photodiodes in the array are isolated by a guard ring consisting of a n+-p+ diffusions. However, the introduction of the guard ring design, necessary for photodiode-to-photodiode isolation, leads to an increase of the photodiodes dark current. In this article, the new parasitic term on the dark current is identified, formulated, modelled and experimental proven and has finally been used for an accurate design of the guard ring.

  10. Breadboard linear array scan imager program

    NASA Technical Reports Server (NTRS)

    1975-01-01

    The performance was evaluated of large scale integration photodiode arrays in a linear array scan imaging system breadboard for application to multispectral remote sensing of the earth's resources. Objectives, approach, implementation, and test results of the program are presented.

  11. Silicon avalanche photodiodes for direct detection of X-rays.

    PubMed

    Baron, Alfred Q R; Kishimoto, Shunji; Morse, John; Rigal, Jean Marie

    2006-03-01

    Silicon avalanche photodiodes (APDs) are discussed as fast X-ray detectors for synchrotron radiation. The emphasis is on ;direct' detection, where the X-ray is absorbed within the silicon APD itself, and, therefore, on use with medium-energy X-rays, <30 keV. The impact of APD structure on device performance is examined, and representative data from many different commercial devices are presented. Specific areas discussed include signal shapes, high-rate behavior, time resolution and pulse-height response. Data from several APD arrays are also presented, as is a detailed description of an integrated package system. Tables are included comparing commercially available devices, including arrays.

  12. Recent advances in organic photodiodes (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Kippelen, Bernard; Khan, Talha M.; Fuentes-Hernandez, Canek; Diniz, Larissa; Lukens, Julia M.; Larrain, Felipe

    2016-09-01

    Although the detection of photons is ubiquitous, man-made photon detectors still limits the effectiveness of applications such as light/laser detection, photography, astronomy, quantum information science, medical imaging, microscopy, communications, and others. The performance of the technologically most advanced detectors based on CMOS semiconductor technology has improved during the last decades but at the detriment of increased complexity, higher cost, limited portability and compactness, and limited area. On the other hand, nature has produced a relatively simple detector with remarkable properties: the human eye. The exploration of new paradigms in photon detection using new material platforms might therefore provide a path to further challenge the frontiers of applications enabled by light. In this talk, we will report on the realization of solution-processed organic semiconductor visible spectrum photodetectors with a high specific detectivity above 1014 Jones, at least an order of magnitude larger than values found in photodiodes based on silicon. These detectors demonstrate a sub-pA current under reverse bias in the dark, making them suitable for detecting very low levels of light. The small dark current under reverse bias allows the characterization of these devices over 9 orders of magnitude of increasing light irradiance. The detectors are based on the device structure: tin-doped indium oxide / ethoxylated polyethylenimine / poly(3-hexylthiophene) : indene C60 bisadduct / molybdenum oxide / silver and present a path toward fabrication on flexible substrates. We will show that these detectors can operate over a large dynamic range in the self-powered photovoltaic mode where the light produces a photovoltage that can be measured directly without any external bias source. We believe that large-area flexible photodetectors with detectivity values comparable to or better than those displayed by silicon-based photodiodes will enable a wide variety of

  13. Photodiode circuits for retinal prostheses.

    PubMed

    Loudin, J D; Cogan, S F; Mathieson, K; Sher, A; Palanker, D V

    2011-10-01

    Photodiode circuits show promise for the development of high-resolution retinal prostheses. While several of these systems have been constructed and some even implanted in humans, existing descriptions of the complex optoelectronic interaction between light, photodiode, and the electrode/electrolyte load are limited. This study examines this interaction in depth with theoretical calculations and experimental measurements. Actively biased photoconductive and passive photovoltaic circuits are investigated, with the photovoltaic circuits consisting of one or more diodes connected in series, and the photoconductive circuits consisting of a single diode in series with a pulsed bias voltage. Circuit behavior and charge injection levels were markedly different for platinum and sputtered iridium-oxide film (SIROF) electrodes. Photovoltaic circuits were able to deliver 0.038 mC/cm(2) (0.75 nC/phase) per photodiode with 50- μm platinum electrodes, and 0.54-mC/cm(2) (11 nC/phase) per photodiode with 50-μ m SIROF electrodes driven with 0.5-ms pulses of light at 25 Hz. The same pulses applied to photoconductive circuits with the same electrodes were able to deliver charge injections as high as 0.38 and 7.6 mC/cm(2) (7.5 and 150 nC/phase), respectively. We demonstrate photovoltaic stimulation of rabbit retina in-vitro, with 0.5-ms pulses of 905-nm light using peak irradiance of 1 mW/mm(2). Based on the experimental data, we derive electrochemical and optical safety limits for pixel density and charge injection in various circuits. While photoconductive circuits offer smaller pixels, photovoltaic systems do not require an external bias voltage. Both classes of circuits show promise for the development of high-resolution optoelectronic retinal prostheses.

  14. Some n-p (Hg,Cd)Te photodiodes for 8-14 micrometer heterodyne applications

    NASA Technical Reports Server (NTRS)

    Shanley, J. F.; Flanagan, C. T.

    1980-01-01

    The results describing the dc and CO2 laser heterodyne characteristics of a three element photodiode array and single element and four element photodiode arrays are presented. The measured data shows that the n(+)-p configuration is capable of achieving bandwidths of 475 to 725 MHz and noise equivalent powers of 3.2 x 10 to the minus 20th power W/Hz at 77 K and 1.0 x 10 to the minus 19th power W/Hz at 145 K. The n(+)-n(-)-p photodiodes exhibited wide bandwidths (approximately 2.0 GHz) and fairly good effective heterodyne quantum efficiencies (approximately 13-30 percent at 2.0 GHz). Noise equivalent powers ranging from 1.44 x 10 to the minus 19th power W/Hz to 6.23 x 10 to the minus 20th power W/Hz were measured at 2.0 GHz.

  15. X ray and charged particle detection with CsI(Tl) layer coupled to a-Si:H photodiode layers

    NASA Astrophysics Data System (ADS)

    Fujieda, I.; Cho, G.; Drewery, J.; Gee, T.; Jing, T.; Kaplan, S. N.; Perez-Mendez, V.; Wildermuth, D.; Street, R. A.

    1990-10-01

    A compact real-time X ray and charged particle imager with digitized position output can built either by coupling a fast scintillator to a photodiode array or by forming one on a photodiode array directly. CsI(Tl) layers 100 to 1000 microns thick were evaporated on glass substrates from a crystal CsI(Tl). When coupled to a crystalline Si or amorphous silicon (a-Si:H) photodiode and exposed to calibrated X ray pulses, their light yields and speed were found to be comparable to those of a crystal CsI(Tl). Single beta particle detection was demonstrated with this combination. The light spread inside evaporated CsI(Tl) was suppressed by its columnar structure. Scintillation detection gives much larger signals than direct X ray detection due to the increased energy deposition in the detector material. Fabrication of monolithic type X-ray sensors consisting of CsI + a-Si:H photodiodes is discussed.

  16. Silicon photodiode characterization from 1 eV to 10 keV

    SciTech Connect

    Idzorek, G.C.; Bartlett, R.J.

    1997-10-01

    Silicon photodiodes offer a number of advantages over conventional photocathode type soft x-ray detectors in pulsed power experiments. These include a nominally flat response, insensitivity to surface contamination, low voltage biasing requirements, sensitivity to low energy photons, excellent detector to detector response reproducibility, and ability to operate in poor vacuum or gas backfilled experiments. Silicon photodiodes available from International Radiation Detectors (IRD), Torrance, California have been characterized for absolute photon response from 1 eV to 10 keV photon energy, time response, and signal saturation levels. The authors have assembled individually filtered photodiodes into an array designated the XUV-7. The XUV-7 provides seven photodiodes in a vacuum leak tight, electrically isolated, low noise, high bandwidth, x-ray filtered assembly in a compact package with a 3.7 cm outside diameter. In addition they have assembled the diodes in other custom configurations as detectors for spectrometers. Their calibration measurements show factor of ten deviations from the silicon photodiode theoretical flat response due to diode sensitivity outside the center `sensitive area`. Detector response reproducibility between diodes appears to be better than 5%. Time response measurements show a 10-90% rise time of about 0.1 nanoseconds and a fall time of about 0.5 nanoseconds. Silicon photodiodes have proven to be a versatile and useful complement to the standard photocathode detectors for soft x-ray measurement and are very competitive with diamond for a number of applications.

  17. Multichannel intensified photodiode for near infrared single photon detection

    NASA Astrophysics Data System (ADS)

    Aebi, Verle W.; Sykora, Derek F.; Jurkovic, Michael J.; Costello, Kenneth A.

    2011-05-01

    An overview of the Intensified Photodiode (IPD) is presented with an emphasis on IPDs optimized for use in the 950nm to 1350nm spectral range for single photon detection applications. The theory of operation of the IPD, two different electron optics designs, and device performance for a multichannel, 4x4 pixel array, low jitter IPD optimized for operation at 1060nm are presented in this paper. Key results include greater than 15% quantum efficiency, large active area, and less than 550ps impulse response.

  18. Measurement of the acyl-CoA intermediates of beta-oxidation by h.p.l.c. with on-line radiochemical and photodiode-array detection. Application to the study of [U-14C]hexadecanoate oxidation by intact rat liver mitochondria.

    PubMed Central

    Watmough, N J; Turnbull, D M; Sherratt, H S; Bartlett, K

    1989-01-01

    The quantitative isolation of acyl-CoA esters of chain length C2-C17 from mitochondrial incubations and their analysis by reverse-phase radio-h.p.l.c. is described. Photodiode-array detection was used to characterize 2-enoyl-CoA esters. The chromatographic behaviour of all 27 intermediates of the beta-oxidation of hexadecanoyl-CoA is documented. Only C16, C14 and C12 intermediates were detected in uncoupled mitochondria oxidizing [U-14C]hexadecanoyl-CoA in the presence of fluorocitrate and carnitine, providing evidence for some organization of the enzymes of beta-oxidation [Garland, Shepherd & Yates (1965) Biochem. J. 97, 587-594; Sumegi & Srere (1984) J. Biol. Chem. 259, 8748-8752]. Rotenone increased concentrations of 3-hydroxyacyl-CoA and 2-enoyl-CoA esters and inhibited flux. These experiments provide the first direct unambiguous measurements of acyl-CoA esters in intact respiring rat liver mitochondrial fractions. PMID:2818568

  19. Avalanche photodiodes for anticoincidence detectors

    NASA Astrophysics Data System (ADS)

    Cirignano, Leonard J.; Farrell, Richard; Redus, Robert H.; Squillante, Michael R.; Hunter, Stanley D.; Cuddapah, Rajani; Mukherjee, Reshmi

    1996-10-01

    Anticoincidence detectors are required for a variety of satellite instruments, including high energy gamma-ray telescopes, in order to differentiate ambient background radiation from signals of interest. Presently, most anticoincidence systems use scintillators coupled to photomultiplier tubes. We have demonstrated that it is now possible to use very high gain solid state avalanche photodiodes (APDs) as photodetectors for this application. A single APD coupled to a 30 cm multiplied by 30 cm multiplied by 0.95 cm plastic scintillator tile demonstrated 100% detection efficiency for minimum ionizing particles, with a low false positive rate. Multiple APDs enhance the signal to noise ratio in addition to providing redundancy. Relative to PMTs, APDs are compact, low power, and mechanically robust devices. Ground test data of APDs for anticoincidence shields is presented.

  20. Organic photodiodes for biosensor miniaturization.

    PubMed

    Wojciechowski, Jason R; Shriver-Lake, Lisa C; Yamaguchi, Mariko Y; Füreder, Erwin; Pieler, Roland; Schamesberger, Martin; Winder, Christoph; Prall, Hans Jürgen; Sonnleitner, Max; Ligler, Frances S

    2009-05-01

    Biosensors have successfully demonstrated the capability to detect multiple pathogens simultaneously at very low levels. Miniaturization of biosensors is essential for use in the field or at the point of care. While microfluidic systems reduce the footprint for biochemical processing devices and electronic components are continually becoming smaller, optical components suitable for integration--such as LEDs and CMOS chips--are generally still too expensive for disposable components. This paper describes the integration of polymer diodes onto a biosensor chip to create a disposable device that includes both the detector and the sensing surface coated with immobilized capture antibody. We performed a chemiluminescence immunoassay on the OPD substrate and measured the results using a hand-held reader attached to a laptop computer. The miniaturized biosensor with the disposable slide including the organic photodiode detected Staphylococcal enterotoxin B at concentrations as low as 0.5 ng/mL.

  1. A room temperature LSO/PIN photodiode PET detector module that measures depth of interaction

    SciTech Connect

    Moses, W.W.; Derenzo, S.E.; Melcher, C.L.; Manente, R.A.

    1994-11-01

    We present measurements of a 4 element PET detector module that uses a 2{times}2 array of 3 mm square PIN photodiodes to both measure the depth of interaction (DOI) and identify the crystal of interaction. Each photodiode is coupled to one end of a 3{times}3{times}25 mm LSO crystal, with the opposite ends of all 4 crystals attached to a single PMT that provides a timing signal and initial energy discrimination. Each LSO crystal is coated with a {open_quotes}lossy{close_quotes} reflector, so the ratio of light detected in the photodiode and PMT depends on the position of interaction in the crystal, and is used to determine this position on an event by event basis. This module is operated at +25{degrees}C with a photodiode amplifier peaking time of 2 {mu}s. When excited by a collimated beam of 511 keV photons at the photodiode end of the module (i.e. closest to the patient), the DOI resolution is 4 mm fwhm and the crystal of interaction is identified correctly 95% of the time. When excited at the opposite end of the module, the DOI resolution is 13 mm fwhm and the crystal of interaction is identified correctly 73% of the time. The channel to channel variations in performance are minimal.

  2. Performances of photodiode detectors for top and bottom counting detectors of ISS-CREAM experiment

    NASA Astrophysics Data System (ADS)

    Hyun, H. J.; Anderson, T.; Angelaszek, D.; Baek, S. J.; Copley, M.; Coutu, S.; Han, J. H.; Huh, H. G.; Hwang, Y. S.; Im, S.; Jeon, H. B.; Kah, D. H.; Kang, K. H.; Kim, H. J.; Kim, K. C.; Kwashnak, K.; Lee, J.; Lee, M. H.; Link, J. T.; Lutz, L.; Mitchell, J. W.; Nutter, S.; Ofoha, O.; Park, H.; Park, I. H.; Park, J. M.; Patterson, P.; Seo, E. S.; Wu, J.; Yoon, Y. S.

    2015-07-01

    The Cosmic Ray Energetics and Mass (CREAM) experiment at the International Space Station (ISS) aims to elucidate the source and acceleration mechanisms of high-energy cosmic rays by measuring the energy spectra from protons to iron. The instrument is planned for launch in 2015 at the ISS, and it comprises a silicon charge detector, a carbon target, top and bottom counting detectors, a calorimeter, and a boronated scintillator detector. The top and bottom counting detectors are developed for separating the electrons from the protons, and each of them comprises a plastic scintillator and a 20×20 silicon photodiode array. Each photodiode is 2.3 cm×2.3 cm in size and exhibits good electrical characteristics. The leakage current is measured to be less than 20 nA/cm2 at an operating voltage. The signal-to-noise ratio is measured to be better than 70 using commercial electronics, and the radiation hardness is tested using a proton beam. A signal from the photodiode is amplified by VLSI (very-large-scale integration) charge amp/hold circuits, the VA-TA viking chip. Environmental tests are performed using whole assembled photodiode detectors of a flight version. Herein, we present the characteristics of the developed photodiode along with the results of the environmental tests.

  3. Modeling of high-precision wavefront sensing with new generation of CMT avalanche photodiode infrared detectors.

    PubMed

    Gousset, Silvère; Petit, Cyril; Michau, Vincent; Fusco, Thierry; Robert, Clelia

    2015-12-01

    Near-infrared wavefront sensing allows for the enhancement of sky coverage with adaptive optics. The recently developed HgCdTe avalanche photodiode arrays are promising due to their very low detector noise, but still present an imperfect cosmetic that may directly impact real-time wavefront measurements for adaptive optics and thus degrade performance in astronomical applications. We propose here a model of a Shack-Hartmann wavefront measurement in the presence of residual fixed pattern noise and defective pixels. To adjust our models, a fine characterization of such an HgCdTe array, the RAPID sensor, is proposed. The impact of the cosmetic defects on the Shack-Hartmann measurement is assessed through numerical simulations. This study provides both a new insight on the applicability of cadmium mercury telluride (CMT) avalanche photodiodes detectors for astronomical applications and criteria to specify the cosmetic qualities of future arrays.

  4. Photodiode-Based, Passive Ultraviolet Dosimeters

    NASA Technical Reports Server (NTRS)

    Vaughn, Jason A.; Gray, Perry

    2004-01-01

    Simple, passive instruments have been developed for measuring the exposure of material specimens to vacuum ultraviolet (VUV) radiation from the Sun. Each instrument contains a silicon photodiode and a coulometer. The photocharge generated in the photodiode is stored in the coulometer. The accumulated electric charge measured by use of the coulometer is assumed to be proportional to the cumulative dose of VUV radiation expressed in such convenient units as equivalent Sun hours (ESH) [defined as the number of hours of exposure to sunlight at normal incidence]. Intended originally for use aboard spacecraft, these instruments could also be adapted to such terrestrial uses as monitoring the curing of ultraviolet-curable epoxies. Each instrument includes a photodiode and a coulometer assembly mounted on an interface plate (see figure). The photodiode assembly includes an aluminum housing that holds the photodiode, a poly(tetrafluoroehylene) cosine receptor, and a narrow-band optical filter. The cosine receptor ensures that the angular response of the instrument approximates the ideal angular response (proportional to the cosine of the angle of incidence). The filter is chosen to pass the ultraviolet wavelength of interest in a specific experiment. The photodiode is electrically connected to the coulometer. The factor of proportionality between the charge stored in the coulometer and ultraviolet dosage (in units of ESH) is established, prior to use, in calibration experiments that involve the use of lamps and current sources traceable to the National Institute of Standards and Technology.

  5. Adaptive optics wavefront sensors based on photon-counting detector arrays

    DTIC Science & Technology

    2010-01-01

    latency readout and selective region-of· interest readout. Lincoln Laboratory has developed arrays of Geiger · mode avalanche photodiodes ...hybridized to all·digital CMOS readout circuits for applications such as lidar’ and low· light passive imaging. In Geiger mode , the avalanche photodiode (APD...Lincoln Laboratory has been investigating Geiger - mode avalanche photodiode arrays integrated with CMOS readout circuits as a potential solution. This type

  6. Test of DEP hybrid photodiodes

    SciTech Connect

    Baumbaugh, A.; Binkley, M.; Elias, J.

    1997-08-01

    The goal of the measurement was to study some parameters of DEP HYBRID PHOTODIODES (HPD), and the check its performance for CMS calorimetry at LHC. The principal of the HPD operation is described. The schematic view of the HPD. The HPD is vacuum photo device composed of photocathode (PC) and a silicon PIN diode (Si) as multiplication system in a very close proximity geometry. The distance between PC and Si is of the order of several mm and has an electric field < 10 kV. The photoelectron emited by the photocathode multiply by a factor of several thousand in the silicon and the charge is collected on the HPD`s anode. Several types of HPD`s were tested. There was a single channel HPD, called {open_quotes}E-type{close_quotes} with p-side of the silicon facing the HPD`s photocathode and two multipixel HPD (DEP) namely a 25 pixel HPD and a 7 pixel HPD. Both were of {open_quotes}T-type{close_quotes} structure with n-side of silicon facing the photocathode.

  7. Solid state image sensing arrays

    NASA Technical Reports Server (NTRS)

    Sadasiv, G.

    1972-01-01

    The fabrication of a photodiode transistor image sensor array in silicon, and tests on individual elements of the array are described along with design for a scanning system for an image sensor array. The spectral response of p-n junctions was used as a technique for studying the optical-absorption edge in silicon. Heterojunction structures of Sb2S3- Si were fabricated and a system for measuring C-V curves on MOS structures was built.

  8. Silicon-on-insulator shortwave infrared wavelength meter with integrated photodiodes for on-chip laser monitoring.

    PubMed

    Muneeb, M; Ruocco, A; Malik, A; Pathak, S; Ryckeboer, E; Sanchez, D; Cerutti, L; Rodriguez, J B; Tournié, E; Bogaerts, W; Smit, M K; Roelkens, G

    2014-11-03

    This paper demonstrates a very compact wavelength meter for on-chip laser monitoring in the shortwave infrared wavelength range based on an optimized arrayed waveguide grating (AWG) filter with an integrated photodiode array. The AWG response is designed to obtain large nearest neighbor crosstalk (i.e. large overlap) between output channels, which allows accurately measuring the wavelength of a laser under test using the centroid detection technique. The passive AWG is fabricated on a 220 nm silicon-on-insulator (SOI) platform and is combined with GaInAsSb-based photodiodes. The photodiodes are heterogeneously integrated on the output grating couplers of the AWG using DVS-BCB adhesive bonding. The complete device with AWG and detectors has a footprint of only 2 mm(2) while the measured accuracy and resolution of the detected wavelength is better than 20pm.

  9. Vertical Isolation for Photodiodes in CMOS Imagers

    NASA Technical Reports Server (NTRS)

    Pain, Bedabrata

    2008-01-01

    In a proposed improvement in complementary metal oxide/semi conduct - or (CMOS) image detectors, two additional implants in each pixel would effect vertical isolation between the metal oxide/semiconductor field-effect transistors (MOSFETs) and the photodiode of the pixel. This improvement is expected to enable separate optimization of the designs of the photodiode and the MOSFETs so as to optimize their performances independently of each other. The purpose to be served by enabling this separate optimization is to eliminate or vastly reduce diffusion cross-talk, thereby increasing sensitivity, effective spatial resolution, and color fidelity while reducing noise.

  10. SWIR HgCdTe photodiodes for LADAR applications

    NASA Astrophysics Data System (ADS)

    Boieriu, Paul; Park, J. H.; Hahn, S.-R.; Wijewarnasuriya, Priyalal; Stan, Barry; Sivananthan, S.

    2016-09-01

    The detection of infrared radiation is of great importance for many defense and civilian applications. Eyesafe short-wavelength infrared (SWIR) spectral range is particularly interesting due to atmospheric propagation through obscurants. Applications include low-cost, long-range target identification, identification of heavily obscured targets, obstacle avoidance, and high resolution imaging from a variety of platforms including hand-held devices, unmanned air vehicles, or ground vehicles. HgCdTe grown on CdTe/Si by molecular beam epitaxy (MBE) was processed into mini-arrays for 1.55 μm LADAR applications. Low-capacitance photodiodes (<10 pF) were demonstrated at room temperature with frequency responses exceeding 100 MHz. This paper discusses the device architecture and device performance results.

  11. Robust Quantum Random Number Generator Based on Avalanche Photodiodes

    NASA Astrophysics Data System (ADS)

    Wang, Fang-Xiang; Wang, Chao; Chen, Wei; Wang, Shuang; Lv, Fu-Sheng; He, De-Yong; Yin, Zhen-Qiang; Li, Hong-Wei; Guo, Guang-Can; Han, Zheng-Fu

    2015-08-01

    We propose and demonstrate a scheme to realize a high-efficiency truly quantum random number generator (RNG) at room temperature (RT). Using an effective extractor with simple time bin encoding method, the avalanche pulses of avalanche photodiode (APD) are converted into high-quality random numbers (RNs) that are robust to slow varying noise such as fluctuations of pulse intensity and temperature. A light source is compatible but not necessary in this scheme. Therefor the robustness of the system is effective enhanced. The random bits generation rate of this proof-of-principle system is 0.69 Mbps with double APDs and 0.34 Mbps with single APD. The results indicate that a high-speed RNG chip based on the scheme is potentially available with an integrable APD array.

  12. Note: Galvanic isolated voltage source using a single photodiode.

    PubMed

    Stoican, O S

    2010-04-01

    A galvanic isolated voltage source able to provide several volts by using a single photodiode is described. A pulse-modulated laser beam is sent to a photodiode. By using a step-up transformer the amplitude of the variable voltage generated by the photodiode is increased. Adding a rectifier cell the variable voltage is converted back into a dc voltage.

  13. Photodiode and photomultiplier areal sensitivity anomalies

    NASA Technical Reports Server (NTRS)

    Youngbluth, O., Jr.

    1977-01-01

    Several silicon photodiodes and photomultipliers were tested to determine signal variations as a light spot was scanned over the photosensitive surface of these detectors. Qualitative and quantitative data is presented to demonstrate the areal sensitivity anomalies. These anomalies are related back to the fabrication techniques of the manufacturers.

  14. MRS photodiode in strong magnetic field

    SciTech Connect

    Beznosko, D.; Blazey, G.; Dyshkant, A.; Francis, K.; Kubik, D.; Rykalin, V.; Tartaglia, M.A.; Zutshi, v.; /Northern Illinois U.

    2004-12-01

    The experimental results on the performance of the MRS (Metal/Resistor/Semiconductor) photodiode in the strong magnetic field of 4.4T, and the possible impact of the quench of the magnet at 4.5T on sensor's operation are reported.

  15. A photodiode based miniature sun sensor

    NASA Astrophysics Data System (ADS)

    Lü, Xiaozhou; Tao, Yebo; Xie, Kai; Wang, Songlin; Li, Xiaoping; Bao, Weimin; Chen, Renjie

    2017-04-01

    The solar vector is one of the most important parameters for attitude control of nanosatellites. This attitude control must be achieved without the sensors adding significantly to its size or mass. This paper presents a photodiode-based miniature sun sensor, which consists of two triangular pyramidal sensor unit structures, with each unit comprising three micro-silicon photodiodes. The two sensor units are installed on the diagonal of the nanosatellite to form a complete sun sensor capable of achieving a full-field range of solar vector measurements. In this paper, the mathematical model of the short-circuit currents of the silicon photodiodes as a function of the solar vector coordinates is deduced. A sensor sample was built and installed on a nanosatellite model, and the temperature compensation coefficient of the silicon photodiodes was obtained experimentally. The dynamic characteristic, linearity, hysteresis and repeatability of the component were measured. The sun sensor introduced in this paper can be placed on any satellite platform to allow a full range solar vector measurement, and this would result in an increase of only 1.86 g and 0.9 cm3 of the satellite’s mass and volume, respectively.

  16. Recent advances in very large area avalanche photodiodes

    NASA Astrophysics Data System (ADS)

    Squillante, Michael R.; Christian, James; Entine, Gerald; Farrell, Richard; Karger, Arieh M.; McClish, Mickel; Myers, Richard; Shah, Kanai S.; Taylor, David; Vanderpuye, Kofi; Waer, Peter; Woodring, Mitchell

    2003-09-01

    The Avalanche Photodiode (APD) is a unique device that combines the advantages of solid state photodetectors with those of high gain devices such as photomultiplier tubes (PMTs). APDs have internal gain that provides a high signal-to-noise ratio. APDs have high quantum efficiency, are fast, compact, and rugged. These properties make them suitable detectors for important applications such as LADAR, detection and identification toxic chemicals and bio-warfare agents, LIDAR fluorescence detection, stand-off laser induced breakdown spectroscopy (LIBS), and nuclear detectors and imagers. Recently there have been significant technical breakthroughs in fabricating very large APDs, APD arrays, and position sensitive APD arrays (PSAPD). Signal gain of over 10,000 has been achieved, single element APDs have been fabricated with active area greater than 40 cm2, monolithic pixelated arrays with up to 28 x 28 elements have been fabricated, and position sensitive APDs have been developed and tested. Additionally, significant progress has been made in improving the fabrication process to provide better uniformity and high yield, permitting cost effective manufacturing of APDs for reduced cost.

  17. A two-dimensional intensified photodiode array for imaging spectroscopy

    NASA Astrophysics Data System (ADS)

    Tennyson, P. D.; Dymond, K.; Moos, H. W.; Feldman, P. D.; Mackey, E. F.

    1986-01-01

    The Johns Hopkins University is currently developing an instrument to fly aboard NASA's Space Shuttle as a Spartan payload in the late 1980s. This Spartan free flyer will obtain spatially resolved spectra of faint extended emission line objects in the wavelength range 750-1150 A at about 2-A resolution. The use of two-dimensional photon counting detectors will give simultaneous coverage of the 400 A spectral range and the 9 arc-minute spatial resolution along the spectrometer slit. The progress towards the flight detector is reported here with preliminary results from a laboratory breadboard detector, and a comparison with the one-dimensional detector developed for the Hopkins Ultraviolet Telescope. A hardware digital centroiding algorithm has been successfully implemented. The system is ultimately capable of 15-micron resolution in two dimensions at the image plane and can handle continuous counting rates of up to 8000 counts/s.

  18. InP-based waveguide photodiodes heterogeneously integrated on silicon-on-insulator for photonic microwave generation.

    PubMed

    Beling, Andreas; Cross, Allen S; Piels, Molly; Peters, Jon; Zhou, Qiugui; Bowers, John E; Campbell, Joe C

    2013-11-04

    High-linearity modified uni-traveling carrier photodiodes on silicon-on-insulator with low AM-to-PM conversion factor are demonstrated. The devices deliver more than 2.5 dBm RF output power up to 40 GHz and have an output third order intercept point of 30 dBm at 20 GHz. Photodiode arrays exceed a saturation current-bandwidth-product of 630 mA · GHz and reach unsaturated RF output power levels of 10 dBm at 20 GHz.

  19. Photodiode Camera Measurement of Surface Strains on Tendons during Multiple Cyclic Tests

    NASA Astrophysics Data System (ADS)

    Chun, Keyoung Jin; Hubbard, Robert Philip

    The objectives of this study are to introduce the use of a photodiode camera for measuring surface strain on soft tissue and to present some representative responses of the tendon. Tendon specimens were obtained from the hindlimbs of canines and frozen to -70°C. After thawing, specimens were mounted in the immersion bath at a room temperature (22°C), preloaded to 0.13N and then subjected to 3% of the initial length at a strain rate of 2%/sec. In tendons which were tested in two blocks of seven repeated extensions to 3% strain with a 120 seconds wait period between, the surface strains were measured with a photodiode camera and near the gripped ends generally were greater than the surface strains in the middle segment of the tendon specimens. The recovery for peak load after the rest period was consistent but the changes in patterns of surface strains after the rest period were not consistent. The advantages of a photodiode measurement of surface strains include the followings: 1) it is a noncontacting method which eliminates errors and distortions caused by clip gauges or mechanical/electronic transducers; 2) it is more accurate than previous noncontact methods, e.g. the VDA and the high speed photographic method; 3) it is a fully automatic, thus reducing labor for replaying video tapes or films and potential errors from human judgement which can occur during digitizing data from photographs. Because the photodiode camera, employs a solid state photodiode array to sense black and white images, scan targets (black image) on the surface of the tendon specimen and back lighting system (white image), and stored automatically image data for surface strains of the tendon specimen on the computer during cyclic extensions.

  20. Optochemical sensor based on screenprinted fluorescent sensorspots surrounded by organic photodiodes for multianalyte detection

    NASA Astrophysics Data System (ADS)

    Kraker, E.; Lamprecht, B.; Haase, A.; Jakopic, G.; Abel, T.; Konrad, C.; Köstler, S.; Tscherner, M.; Stadlober, B.; Mayr, T.

    2010-08-01

    A compact, integrated photoluminescence based oxygen sensor, utilizing an organic light emitting device (OLED) as the light source and an organic photodiode (OPD) as the detection unit, is described. The detection system of the sensor array consists of an array of circular screen-printed fluorescent sensor spots surrounded by organic photodiodes as integrated fluorescence detectors. The OPD originates from the well-known Tang photodiode, consisting of a stacked layer of copper phthalocyanine (CuPc, p-type material) and perylene tetracarboxylic bisbenzimidazole (PTCBi, n-type material). An additional layer of tris-8-hydroxyquinolinatoaluminium (Alq3, n-type material) was inserted between the PTCBi layer and cathode. An ORMOCERR layer was used as encapsulation layer. For excitation an organic light emitting diode is used. The sensor spot and the detector are processed on the same flexible substrate. This approach not only simplifies the detection system by minimizing the numbers of required optical components - no optical filters have to be used for separating the excitation light and the luminescent emission-, but also has a large potential for low-cost sensor applications. The feasibility of the concept is demonstrated by an integrated oxygen sensor, indicating good performance. Sensor schemes for other chemical parameters are proposed.

  1. Modeling scintillator-photodiodes as detectors for megavoltage CT.

    PubMed

    Monajemi, T T; Steciw, S; Fallone, B G; Rathee, S

    2004-05-01

    The use of cadmium tungstate (CdWO4) and cesium iodide [CsI(Tl)] scintillation detectors is studied in megavoltage computed tomography (MVCT). A model describing the signal acquired from a scintillation detector has been developed which contains two steps: (1) the calculation of the energy deposited in the crystal due to MeV photons using the EGSnrc Monte Carlo code; and (2) the transport of the optical photons generated in the crystal voxels to photodiodes using the optical Monte Carlo code DETECT2000. The measured detector signals in single CdWO4 and CsI(Tl) scintillation crystals of base 0.275 x 0.8 cm2 and heights 0.4, 1, 1.2, 1.6 and 2 cm were, generally, in good agreement with the signals calculated with the model. A prototype detector array which contains 8 CdWO4 crystals, each 0.275 x 0.8 x 1 cm3, in contact with a 16-element array of photodiodes was built. The measured attenuation of a Cobalt-60 beam as a function of solid water thickness behaves linearly. The frequency dependent modulation transfer function [MTF(f)], noise power spectrum [NPS(f)], and detective quantum efficiency [DQE(f)] were measured for 1.25 MeV photons (in a Cobalt-60 beam). For 6 MV photons, only the MTF(f) was measured from a linear accelerator, where large pulse-to-pulse fluctuations in the output of the linear accelerator did not allow the measurement of the NPS(f). A two-step Monte Carlo simulation was used to model the detector's MTF(f), NPS(f) and DQE(f). The DQE(0) of the detector array was found to be 26% and 19% for 1.25 MeV and 6 MV photons, respectively. For 1.25 MeV photons, the maximum discrepancies between the measured and modeled MTF(f), relative NPS(f) and the DQE(f) were found to be 1.5%, 1.2%, and 1.9%, respectively. For the 6 MV beam, the maximum discrepancy between the modeled and the measured MTF(f) was found to be 2.5%. The modeling is sufficiently accurate for designing appropriate detectors for MVCT.

  2. HgCdTe avalanche photodiode detectors for airborne and spaceborne lidar at infrared wavelengths.

    PubMed

    Sun, Xiaoli; Abshire, James B; Beck, Jeffrey D; Mitra, Pradip; Reiff, Kirk; Yang, Guangning

    2017-07-10

    We report results from characterizing the HgCdTe avalanche photodiode (APD) arrays developed for lidar at infrared wavelengths by using the high density vertically integrated photodiodes (HDVIP(®)) technique. The results show >90% quantum efficiencies between 0.8 μm and the cut-off wavelength, >600 APD gain, near unity excess noise factor, 6-10 MHz electrical bandwidth and <0.5 fW/Hz(1/2) noise equivalent power (NEP). The detectors provide linear analog output with a dynamic range of 2-3 orders of magnitude at a fixed APD gain without averaging, and over 5 orders of magnitude by adjusting the APD gain settings. They have been used successfully in airborne CO2 and CH4 integrated path differential absorption (IPDA) lidar as precursors for use in space lidar.

  3. Reduction of Photodiode Nonlinearities by Adaptive Biasing

    DTIC Science & Technology

    2016-10-14

    on modulated optical carriers as a method of transporting high frequency and microwave information over sizeable distances. If the system bandwidth...Williams I EXECUTIVE SUMMARY RF photonic links impress information on modulated optical carriers as a method of transporting high frequency and microwave ...boards, and the light from each is combined and sent to the photodiode under test. Polarization rotators permitted the states of polarization to be

  4. Shot noise suppression in avalanche photodiodes.

    PubMed

    Ma, Feng; Wang, Shuling; Campbell, Joe C

    2005-10-21

    We identify a new shot noise suppression mechanism in a thin (approximately 100 nm) heterostructure avalanche photodiode. In the low-gain regime the shot noise is suppressed due to temporal correlations within amplified current pulses. We demonstrate in a Monte Carlo simulation that the effective excess noise factors can be < 1, and reconcile the apparent conflict between theory and experiments. This shot noise suppression mechanism is independent of known mechanisms such as Coulomb interaction, or reflection at heterojunction interfaces.

  5. Type-II Superlattice Avalanche Photodiodes

    NASA Astrophysics Data System (ADS)

    Huang, Jun

    Type-II superlattice avalanche photodiodes have shown advantages compared to conventional mercury cadmium telluride photodiodes for infrared wavelength detection. However, surface or interface leakage current has been a major issue for superlattice avalanche photodiodes, especially in infrared wavelength region. First, passivation of the superlattice device with ammonium sulfide and thioacetamide was carried out, and its surface quality was studied by X-ray Photoelectron Spectroscopy. The study showed that both ammonium sulfide and thiacetamide passivation can actively remove the native oxide at the surface. Thiacetamide passivation combine more sulfur bonds with III-V elements than that of ammonium sulfide. Another X-ray photoelectron spectra of thiacetamide-treated atomic layer deposited zinc sulfide capped InAs/GaSb superlattice was performed to investigate the interface sulfur bond conditions. Sb--S and As--S bonds disappear while In-S bond gets enhanced, indicating that Indium Sulfide should be the major components at the interface after ZnS deposition. Second, the simulation of electrical characteristics for zinc sulfide, silicon nitride and silicon dioxide passivated superlattice devices was performed by SILVACO software to fit the experimental results and to discover the surface current mechanism. Different surface current mechanism strengths were found. Third, several novel dual-carrier avalanche photodiode structures were designed and simulated. The structures had alternate carrier multiplication regions, placed next to a wider electron multiplication region, creating dual-carrier multiplication feedback systems. Gain and excess noise factor of these structures were simulated and compared based on the dead space multiplication theory under uniform electric field. From the simulation, the applied bias can be greatly lowered or the thickness can be shrunk to achieve the same gain from the conventional device. The width of the thin region was the most

  6. A New Positioning Algorithm for Position-Sensitive Avalanche Photodiodes

    PubMed Central

    Zhang, Jin; Olcott, Peter D.; Levin, Craig S.

    2013-01-01

    We are using a novel position sensitive avalanche photodiode (PSAPD) for the construction of a high resolution positron emission tomography (PET) camera. Up to now most researchers working with PSAPDs have been using an Anger-like positioning algorithm involving the four corner readout signals of the PSAPD. This algorithm yields a significant non-linear spatial “pin-cushion” distortion in raw crystal positioning histograms. In this paper, we report an improved positioning algorithm, which combines two diagonal corner signals of the PSAPD followed by a 45° rotation to determine the X or Y position of the interaction. We present flood positioning histogram data generated with the old and new positioning algorithms using a 3 × 4 array of 2 × 2 × 3 mm3 and a 3 × 8 array of 1 × 1 × 3 mm3 of LSO crystals coupled to 8 × 8 mm2 PSAPDs. This new algorithm significantly reduces the pin-cushion distortion in raw flood histogram image. PMID:24307743

  7. A New Positioning Algorithm for Position-Sensitive Avalanche Photodiodes.

    PubMed

    Zhang, Jin; Olcott, Peter D; Levin, Craig S

    2007-06-01

    We are using a novel position sensitive avalanche photodiode (PSAPD) for the construction of a high resolution positron emission tomography (PET) camera. Up to now most researchers working with PSAPDs have been using an Anger-like positioning algorithm involving the four corner readout signals of the PSAPD. This algorithm yields a significant non-linear spatial "pin-cushion" distortion in raw crystal positioning histograms. In this paper, we report an improved positioning algorithm, which combines two diagonal corner signals of the PSAPD followed by a 45° rotation to determine the X or Y position of the interaction. We present flood positioning histogram data generated with the old and new positioning algorithms using a 3 × 4 array of 2 × 2 × 3 mm(3) and a 3 × 8 array of 1 × 1 × 3 mm(3) of LSO crystals coupled to 8 × 8 mm(2) PSAPDs. This new algorithm significantly reduces the pin-cushion distortion in raw flood histogram image.

  8. Depth of interaction resolution measurements for a high resolution PET detector using position sensitive avalanche photodiodes.

    PubMed

    Yang, Yongfeng; Dokhale, Purushottam A; Silverman, Robert W; Shah, Kanai S; McClish, Mickel A; Farrell, Richard; Entine, Gerald; Cherry, Simon R

    2006-05-07

    We explore dual-ended read out of LSO arrays with two position sensitive avalanche photodiodes (PSAPDs) as a high resolution, high efficiency depth-encoding detector for PET applications. Flood histograms, energy resolution and depth of interaction (DOI) resolution were measured for unpolished LSO arrays with individual crystal sizes of 1.0, 1.3 and 1.5 mm, and for a polished LSO array with 1.3 mm pixels. The thickness of the crystal arrays was 20 mm. Good flood histograms were obtained for all four arrays, and crystals in all four arrays can be clearly resolved. Although the amplitude of each PSAPD signal decreases as the interaction depth moves further from the PSAPD, the sum of the two PSAPD signals is essentially constant with irradiation depth for all four arrays. The energy resolutions were similar for all four arrays, ranging from 14.7% to 15.4%. A DOI resolution of 3-4 mm (including the width of the irradiation band which is approximately 2 mm) was obtained for all the unpolished arrays. The best DOI resolution was achieved with the unpolished 1 mm array (average 3.5 mm). The DOI resolution for the 1.3 mm and 1.5 mm unpolished arrays was 3.7 and 4.0 mm respectively. For the polished array, the DOI resolution was only 16.5 mm. Summing the DOI profiles across all crystals for the 1 mm array only degraded the DOI resolution from 3.5 mm to 3.9 mm, indicating that it may not be necessary to calibrate the DOI response separately for each crystal within an array. The DOI response of individual crystals in the array confirms this finding. These results provide a detailed characterization of the DOI response of these PSAPD-based PET detectors which will be important in the design and calibration of a PET scanner making use of this detector approach.

  9. Silicon photodiode as the two-color detector

    NASA Astrophysics Data System (ADS)

    Ponomarev, D. B.; Zakharenko, V. A.

    2015-11-01

    This paper describes a silicon photodiode as the two-color photodetector. The work of one photodiode in two spectral ranges is achieved due to the changes of the spectral sensitivity of the photodiodes in the transition from photodiode mode for photovoltaic in the short circuit mode. On the basis of silicon photodiode FD-256 the layout of the spectral ratio pyrometer was assembled and the results of theoretical calculations was confirmed experimentally. The calculated dependences of the coefficient of error of the spectral ratio pyrometer from temperature reverse voltage 10 and 100 V was presented. The calculated dependence of the instrumental error and the assessment of methodological errors of the proposed photodetector spectral ratio was done. According to the results of the presented research was set the task of development photodiode detectors which change the spectral sensitivity depending on the applied voltage.

  10. Silicon photodiodes with high photoconductive gain at room temperature.

    PubMed

    Li, X; Carey, J E; Sickler, J W; Pralle, M U; Palsule, C; Vineis, C J

    2012-02-27

    Silicon photodiodes with high photoconductive gain are demonstrated. The photodiodes are fabricated in a complementary metal-oxide-semiconductor (CMOS)-compatible process. The typical room temperature responsivity at 940 nm is >20 A/W and the dark current density is ≈ 100 nA/cm2 at 5 V reverse bias, yielding a detectivity of ≈ 10(14) Jones. These photodiodes are good candidates for applications that require high detection sensitivity and low bias operation.

  11. Monte Carlo simulations of compact gamma cameras based on avalanche photodiodes.

    PubMed

    Després, Philippe; Funk, Tobias; Shah, Kanai S; Hasegawa, Bruce H

    2007-06-07

    Avalanche photodiodes (APDs), and in particular position-sensitive avalanche photodiodes (PSAPDs), are an attractive alternative to photomultiplier tubes (PMTs) for reading out scintillators for PET and SPECT. These solid-state devices offer high gain and quantum efficiency, and can potentially lead to more compact and robust imaging systems with improved spatial and energy resolution. In order to evaluate this performance improvement, we have conducted Monte Carlo simulations of gamma cameras based on avalanche photodiodes. Specifically, we investigated the relative merit of discrete and PSAPDs in a simple continuous crystal gamma camera. The simulated camera was composed of either a 4 x 4 array of four channels 8 x 8 mm2 PSAPDs or an 8 x 8 array of 4 x 4 mm2 discrete APDs. These configurations, requiring 64 channels readout each, were used to read the scintillation light from a 6 mm thick continuous CsI:Tl crystal covering the entire 3.6 x 3.6 cm2 photodiode array. The simulations, conducted with GEANT4, accounted for the optical properties of the materials, the noise characteristics of the photodiodes and the nonlinear charge division in PSAPDs. The performance of the simulated camera was evaluated in terms of spatial resolution, energy resolution and spatial uniformity at 99mTc (140 keV) and 125I ( approximately 30 keV) energies. Intrinsic spatial resolutions of 1.0 and 0.9 mm were obtained for the APD- and PSAPD-based cameras respectively for 99mTc, and corresponding values of 1.2 and 1.3 mm FWHM for 125I. The simulations yielded maximal energy resolutions of 7% and 23% for 99mTc and 125I, respectively. PSAPDs also provided better spatial uniformity than APDs in the simple system studied. These results suggest that APDs constitute an attractive technology especially suitable to build compact, small field of view gamma cameras dedicated, for example, to small animal or organ imaging.

  12. Photon detection with cooled avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Robinson, D. L.; Metscher, B. D.

    1987-01-01

    Commercial avalanche photodiodes have been operated as single-photon detectors at an optimum operating temperature and bias voltage. These detectors were found to be 1.5-3 times more sensitive than presently available photomultiplier tubes (PMTs). Both single-photon detection probability and detector noise increase with bias voltage; detection probabilities greater than twice that of a PMT were obtained with detector noise levels below 100 counts per second. Higher probabilities were measured at higher noise levels. The sources of noise and their dependence on temperature and bias voltage are discussed.

  13. Cooled avalanche photodiode used for photon detection

    NASA Technical Reports Server (NTRS)

    Robinson, Deborah L.; Metscher, Brian D.

    1987-01-01

    Commercial avalanche photodiodes have been operated as single-photon detectors at an optimum operating temperature and bias voltage. These detectors were found to be 1.5 to 3 times more sensitive than presently-available photomultiplier tubes (PPMTs). Both single-photon detection probability and detector noise increase with bias voltage; detection probabilities greater than 25 percent were obtained with detector noise levels comparable to the noise of a PMT; higher probabilities were measured at higher noise levels. The sources of noise and their dependence on temperature and bias voltage are discussed.

  14. Cooled avalanche photodiode used for photon detection

    NASA Technical Reports Server (NTRS)

    Robinson, Deborah L.; Metscher, Brian D.

    1987-01-01

    Commercial avalanche photodiodes have been operated as single-photon detectors at an optimum operating temperature and bias voltage. These detectors were found to be 1.5 to 3 times more sensitive than presently-available photomultiplier tubes (PPMTs). Both single-photon detection probability and detector noise increase with bias voltage; detection probabilities greater than 25 percent were obtained with detector noise levels comparable to the noise of a PMT; higher probabilities were measured at higher noise levels. The sources of noise and their dependence on temperature and bias voltage are discussed.

  15. Photon detection with cooled avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Robinson, D. L.; Metscher, B. D.

    1987-01-01

    Commercial avalanche photodiodes have been operated as single-photon detectors at an optimum operating temperature and bias voltage. These detectors were found to be 1.5-3 times more sensitive than presently available photomultiplier tubes (PMTs). Both single-photon detection probability and detector noise increase with bias voltage; detection probabilities greater than twice that of a PMT were obtained with detector noise levels below 100 counts per second. Higher probabilities were measured at higher noise levels. The sources of noise and their dependence on temperature and bias voltage are discussed.

  16. Photodiodes for ten micrometer laser communication systems

    NASA Technical Reports Server (NTRS)

    Cohen, S. C.

    1972-01-01

    The performance is discussed of 10-micron mercury-cadmiumtelluride and lead-tin-telluride photodiodes in laser heterodyne communication systems. The dependence of detector quantum efficiency, resistance, frequency response, and signal-to-noise ratio on temperature, bias, and local oscillator power are examined. Included in the discussion is an analysis of the feasibility of high temperature operation, and ability of the detector to dissipate power to a heat sink is explored. Some aspects of direct detection response are considered and figures showing flux levels from a blackbody presented.

  17. A cooled avalanche photodiode with high photon detection probability

    NASA Technical Reports Server (NTRS)

    Robinson, D. L.; Metscher, B. D.

    1986-01-01

    An avalanche photodiode has been operated as a photon-counting detector with 2 to 3 times the sensitivity of currently-available photomultiplier tubes. APD (avalanche photodiodes) detection probabilities that exceed 27% and approach 50% have been measured at an optimum operating temperature which minimizes noise. The sources of noise and their dependence on operating temperature and bias voltage are discussed.

  18. A compact 64-pixel CsI(T1)/Si PIN photodiode imaging module with IC readout

    SciTech Connect

    Gruber, Gregory J.; Choong, Woon-Seng; Moses, William W.; Derenzo, Stephen E.; Holland, Stephen E.; Pedrali-Noy, Marzio; Krieger, Brad; Mandelli, Emanuele; Meddeler, Gerrit; Wang, Nadine W.

    2001-08-09

    We characterize the performance of a complete 64-pixel compact gamma camera imaging module consisting of optically isolated 3 mm 3 mm 5 mm CsI(Tl) crystals coupled to a custom array of low-noise Si PIN photodiodes read out by a custom IC. At 50 V bias the custom 64-pixel photodiode arrays demonstrate an average leakage current of 28 pA per 3 mm 3 mm pixel, a 98.5 percent yield of pixels with <100 pA leakage, and a quantum efficiency of about 80 percent for 540 nm CsI(Tl) scintillation photons. The custom 64-channel readout IC uses low-noise preamplifiers, shaper amplifiers, and a winner-take-all (WTA) multiplexer. The IC demonstrates maximum gain of 120 mV / 1000 e-, the ability to select the largest input signal in less than 150 ns, and low electronic noise at 8 ms peaking time ranging from 25 e- rms (unloaded) to an estimated 180 e- rms (photodiode load of 3 pF, 50 pA). At room temperature a complete 64-pixel detector module employing a custom photodiode array and readout IC demonstrates an average energy resolution of 23.4 percent fwhm and an intrinsic spatial resolution of 3.3 mm fwhm for the 140 keV emissions of 99mTc. Construction of an array of such imaging modules is straightforward, hence this technology shows strong potential for numerous compact gamma camera applications, including scintimammography.

  19. Hybrid UV Imager Containing Face-Up AlGaN/GaN Photodiodes

    NASA Technical Reports Server (NTRS)

    Zheng, Xinyu; Pain, Bedabrata

    2005-01-01

    A proposed hybrid ultraviolet (UV) image sensor would comprise a planar membrane array of face-up AlGaN/GaN photodiodes integrated with a complementary metal oxide/semiconductor (CMOS) readout-circuit chip. Each pixel in the hybrid image sensor would contain a UV photodiode on the AlGaN/GaN membrane, metal oxide/semiconductor field-effect transistor (MOSFET) readout circuitry on the CMOS chip underneath the photodiode, and a metal via connection between the photodiode and the readout circuitry (see figure). The proposed sensor design would offer all the advantages of comparable prior CMOS active-pixel sensors and AlGaN UV detectors while overcoming some of the limitations of prior (AlGaN/sapphire)/CMOS hybrid image sensors that have been designed and fabricated according to the methodology of flip-chip integration. AlGaN is a nearly ideal UV-detector material because its bandgap is wide and adjustable and it offers the potential to attain extremely low dark current. Integration of AlGaN with CMOS is necessary because at present there are no practical means of realizing readout circuitry in the AlGaN/GaN material system, whereas the means of realizing readout circuitry in CMOS are well established. In one variant of the flip-chip approach to integration, an AlGaN chip on a sapphire substrate is inverted (flipped) and then bump-bonded to a CMOS readout circuit chip; this variant results in poor quantum efficiency. In another variant of the flip-chip approach, an AlGaN chip on a crystalline AlN substrate would be bonded to a CMOS readout circuit chip; this variant is expected to result in narrow spectral response, which would be undesirable in many applications. Two other major disadvantages of flip-chip integration are large pixel size (a consequence of the need to devote sufficient area to each bump bond) and severe restriction on the photodetector structure. The membrane array of AlGaN/GaN photodiodes and the CMOS readout circuit for the proposed image sensor would

  20. Detection probabilities for photon-counting avalanche photodiodes applied to a laser radar system.

    PubMed

    Henriksson, Markus

    2005-08-20

    Arrays of photon-counting avalanche photodiodes with time-resolved readout can improve the performance of three-dimensional laser radars. A comparison of the detection and false-alarm probabilities for detectors in linear mode and in Geiger mode is shown. With low background radiation their performance is comparable. It is shown that in both cases it will be necessary to process several laser shots of the same scene to improve detection and reduce the false-alarm rate. Additional calculations show that the linear mode detector is much better at detecting targets behind semitransparent obscurations such as vegetation and camouflage nets.

  1. Radon measurements with a PIN photodiode.

    PubMed

    Martín-Martín, A; Gutiérrez-Villanueva, J L; Muñoz, J M; García-Talavera, M; Adamiec, G; Iñiguez, M P

    2006-01-01

    Silicon photodiodes are well suited to detect alphas coming from different sources as neutron reactions or radon daughters. In this work a radon in air detecting device, using an 18x18 mm silicon PIN photodiode is studied. The ionized airborne decay products formed during radon diffusion were focused by an accelerating high voltage to the PIN surface. Several conducting rings were disposed inside a cylindrical PVC vessel in such a way that they reproduced the electric field created by a punctual charge located behind PIN position. Alpha spectra coming from the neutral and ionized species deposited on the PIN surface, dominated by 218Po and 214Po progeny peaks, were recorded for varying conditions. Those include radon concentration from a Pylon source, high voltage (thousands of volts) and PIN inverse bias voltage. Different parameters such as temperature and humidity were also registered during data acquisition. The increase in the particle collection efficiency with respect to zero electric field was compared with the corresponding to a parallel plates configuration. A discussion is made in terms of the most appropriate voltages for different radon concentrations.

  2. Foliage penetration optimization for Geiger-mode avalanche photodiode lidar

    NASA Astrophysics Data System (ADS)

    Johnson, Steven E.

    2013-05-01

    Geiger-mode avalanche photodiode (GMAPD) Lidar systems can be used to image targets that are partially concealed by foliage. This application of GMAPD Lidar is challenging because most APDs operating in Geiger- mode report only one range measurement per transmitted laser pulse. If a GMAPD makes a foliage range measurement, it cannot make a range measurement to a target concealed by the foliage. When too much laser energy is received, the vast majority of range measurements are from the foliage and only a small percentage are from the target. Some GMAPD Lidar systems can report their average detection probability during operation. The average detection probability, which is often called "P-det", is calculated over an array of GMAPDs, over multiple laser pulses, or over both. However, the detection probability does not distinguish between target range measurements, foliage range measurements, and noise events. In this paper, it is shown that when certain collection parameters are known, that the probability of detecting a target obscured by foliage can be maximized by selecting the appropriate "P-det". It is also shown that for a typical foliage penetration scenario where most of the reflected laser energy is from the foliage that operating with a "P-det" between 65% and 80% produces a near-maximum target detection probability.

  3. Multilevel photonic modules for millimeter-wave phased-array antennas

    NASA Astrophysics Data System (ADS)

    Paolella, Arthur C.; Joshi, Abhay M.; Wright, James G.; Coryell, Louis A.

    1998-11-01

    Optical signal distribution for phased array antennas in communication system is advantageous to designers. By distributing the microwave and millimeter wave signal through optical fiber there is the potential for improved performance and lower weight. In addition when applied to communication satellites this weight saving translates into substantially reduced launch costs. The goal of the Phase I Small Business Innovation Research (SBIR) Program is the development of multi-level photonic modules for phased array antennas. The proposed module with ultimately comprise of a monolithic, InGaAs/InP p-i-n photodetector-p-HEMT power amplifier, opto-electronic integrated circuit, that has 44 GHz bandwidth and output power of 50 mW integrated with a planar antenna. The photodetector will have a high quantum efficiency and will be front-illuminated, thereby improved optical performance. Under Phase I a module was developed using standard MIC technology with a high frequency coaxial feed interconnect.

  4. Photon counting techniques with silicon avalanche photodiodes.

    PubMed

    Dautet, H; Deschamps, P; Dion, B; Macgregor, A D; Macsween, D; McIntyre, R J; Trottier, C; Webb, P P

    1993-07-20

    The properties of avalanche photodiodes and associated electronics required for photon counting in the Geiger and the sub-Geiger modes are reviewed. When the Geiger mode is used, there are significant improvements reported in overall photon detection efficiencies (approaching 70% at 633 nm), and a timing jitter (under 200 ps) is achieved with passive quenching at high overvoltages (20-30 V). The results obtained by using an active-mode fast quench circuit capable of switching overvoltages as high as 15 V (giving photon detection efficiencies in the 50% range) with a dead time of less than 50 ns are reported. Larger diodes (up to 1 mm in diameter) that are usable in the Geiger mode and that have quantum efficiencies over 80% in the 500-800-nm range are also reported.

  5. Avalanche speed in thin avalanche photodiodes

    NASA Astrophysics Data System (ADS)

    Ong, D. S.; Rees, G. J.; David, J. P. R.

    2003-04-01

    The duration of the avalanche multiplication process in thin GaAs avalanche photodiodes is investigated using a full band Monte Carlo (FBMC) model. The results are compared with those of a simple random path length (RPL) model which makes the conventional assumptions of a displaced exponential for the ionization path length probability distribution function and that carriers always travel at their saturated drift velocities. We find that the avalanche duration calculated by the RPL model is almost twice of that predicted by the FBMC model, although the constant drift velocities used in the former model are estimated using the latter. The faster response predicted by FBMC model arises partly from the reduced dead space but mainly from the velocity overshoot of ionizing carriers. While the feedback multiplication processes forced by the effects of dead space extend the avalanche duration in short structures, the effects of velocity overshoot in the realistic model more than compensate, significantly improving multiplication bandwidth.

  6. Diamond photodiodes for x-ray application

    SciTech Connect

    Distel, James R; Smedley, John; Keister, Jeffrey W; Muller, Erik; Jordan - Sweet, Jean; Bohon, Jen; Dong, Bin

    2009-01-01

    Single crystal high purity CVD diamonds have been metallized and calibrated as photodiodes at the National Synchrotron Light Source (NSLS). Current mode responsivity measurements have been made over a wide range (0.2-28 keV) of photon energies across several beamlines. Linear response has been achieved over ten orders of magnitude of incident flux, along with uniform spatial response. A simple model of responsivity has been used to describe the results, yielding a value of 13.3 {+-} 0.5 eV for the mean pair creation energy. The responsivity vs. photon energy data show a dip for photon energies near the carbon edge (284 eV), indicating incomplete charge collection for carriers created less than one micron from the metallized layer.

  7. Internal quantum efficiency modeling of silicon photodiodes.

    PubMed

    Gentile, T R; Brown, S W; Lykke, K R; Shaw, P S; Woodward, J T

    2010-04-01

    Results are presented for modeling of the shape of the internal quantum efficiency (IQE) versus wavelength for silicon photodiodes in the 400 nm to 900 nm wavelength range. The IQE data are based on measurements of the external quantum efficiencies of three transmission optical trap detectors using an extensive set of laser wavelengths, along with the transmittance of the traps. We find that a simplified version of a previously reported IQE model fits the data with an accuracy of better than 0.01%. These results provide an important validation of the National Institute of Standards and Technology (NIST) spectral radiant power responsivity scale disseminated through the NIST Spectral Comparator Facility, as well as those scales disseminated by other National Metrology Institutes who have employed the same model.

  8. Characterization of avalanche photodiodes for lidar atmospheric return signal detectors

    NASA Technical Reports Server (NTRS)

    Antill, C. W., Jr.; Holloway, R. M.

    1988-01-01

    Results are presented from tests to characterize noise, dark current, overload, and gain versus bias, relationships of ten avalanche photodiodes. The advantages of avalanche photodiodes over photomultiplier tubes for given laser wavelengths and return signal amplitudes are outlined. The relationship between responsivity and temperature and dark current and temperature are examined. Also, measurements of the noise equivalent power, the excess noise factor, and linearity are given. The advantages of using avalanche photodiodes in the Lidar Atmospheric Sensing Experiment and the Lidar In-Space Technology Experiment are discussed.

  9. Chopped Radiation Measurements With Large Area Si Photodiodes

    PubMed Central

    Eppeldauer, George

    1998-01-01

    Frequency dependent response characteristics of photocurrent meters using large area, radiometric quality Si photodiodes have been analyzed. The current responsivity, the voltage noise and drift amplification, and the gain and bandwidth of the photocurrent-measuring analog control loop were calculated. The photodiodes were selected for high shunt resistance. The effect of the photodiode junction capacitance on the response characteristics was also analyzed. As a result of photocurrent gain dependent frequency compensations, the noise boosting effect was minimized at the output of the current meter. The loop gain and bandwidth were maximized. High-accuracy photocurrent measurements can be achieved using the described procedures for both dc and modulated optical radiation. PMID:28009366

  10. Characterization of avalanche photodiodes for lidar atmospheric return signal detectors

    NASA Technical Reports Server (NTRS)

    Antill, C. W., Jr.; Holloway, R. M.

    1988-01-01

    Results are presented from tests to characterize noise, dark current, overload, and gain versus bias, relationships of ten avalanche photodiodes. The advantages of avalanche photodiodes over photomultiplier tubes for given laser wavelengths and return signal amplitudes are outlined. The relationship between responsivity and temperature and dark current and temperature are examined. Also, measurements of the noise equivalent power, the excess noise factor, and linearity are given. The advantages of using avalanche photodiodes in the Lidar Atmospheric Sensing Experiment and the Lidar In-Space Technology Experiment are discussed.

  11. Application of a backside-illuminated charge-coupled-device camera for single-pulse coherent anti-Stokes Raman spectroscopy N(2) thermometry.

    PubMed

    Plath, I; Meier, W; Stricker, W

    1992-01-01

    The application of an unintensified backside-illuminated CCD for the acquisition of broadband single-pulse coherent anti-Stokes Raman spectroscopy (CARS) spectra is demonstrated. This CCD shows a quantum efficiency 5 times higher than a front-illuminated CCD and offers significant advantages compared with intensified linear photodiode array detectors generally used for single-pulse CARS thermometry. It overcomes the main drawbacks of the intensified linear photodiode array detector in single-pulse CARS N(2) spectroscopy: nonlinearity, limited dynamic range, and image persistence. A method for extending the dynamic range is demonstrated in a highly turbulent flame.

  12. Photodiode-Based X-Ray Beam-Position Monitor With High Spatial-Resolution for the NSLS-II Beamlines

    SciTech Connect

    Yoon, P.S.; Siddons, D. P.

    2009-05-25

    We developed a photodiode-based monochromatic X-ray beam-position monitor (X-BPM) with high spatial resolution for the project beamlines of the NSLS-II. A ring array of 32 Si PIN-junction photodiodes were designed for use as a position sensor, and a low-noise HERMES4 ASIC chip was integrated into the electronic readout system. A series of precision measurements to characterize electrically the Si-photodiode sensor and the ASIC chip demonstrated that the inherent noise is sufficiently below tolerance levels. Following up modeling of detector's performance, including geometrical optimization using a Gaussian beam, we fabricated and assembled a first prototype. In this paper, we describe the development of this new state-of-the-art X-ray BPM along the beamline, in particular, downstream from the monochromator.

  13. Relative degradation of near infrared avalanche photodiodes from proton irradiation

    NASA Technical Reports Server (NTRS)

    Becker, Heidi; Johnston, Allan H.

    2004-01-01

    InGaAs and Ge avalanche photodiodes are compared for the effects of 63-MeV protons on dark current. Differences in displacement damage factors are discussed as they relate to structural differences between devices.

  14. A functional material based photodiode for solar tracking systems

    NASA Astrophysics Data System (ADS)

    Dere, A.; Tataroğlu, A.; Al-Sehemi, Abdullah G.; Al-Ghamdi, Ahmed A.; El-Tantawy, F. Farid; Farooq, W. A.; Yakuphanoglu, F.

    2017-09-01

    To prepare phosphotungstic acid (PTA) thin film was used drop-coating method. The film was dropped on p-Si having ohmic contact. The electrical and photovoltaic properties the fabricated Al/p-Si/phospotungstic acid(PTA)/Al photodiode were investigated. The current-voltage (I-V) measurements were carried out under dark and various illumination intensities. Under illumination, the photocurrent of the photodiode was found to be higher than the dark current. The prepared photodiode exhibited photovoltaic behavior. Also, the transient photocurrent measurement confirms that the photocurrent is sensitive to the illumination intensities. In addition, the capacitance/conductance-voltage (C/G-V) measurements were studied in the frequency range of 10 kHz to 1 MHz. The capacitance decreases with increasing frequency, suggesting a continuous distribution of interface states. As result, the prepared photodiode can be used in optoelectronic device applications.

  15. Irradiation stability of silicon photodiodes for extreme-ultraviolet radiation

    NASA Astrophysics Data System (ADS)

    Scholze, Frank; Klein, Roman; Bock, Thomas

    2003-10-01

    Photodiodes are used as easy-to-operate detectors in the extreme-ultraviolet spectral range. At the Physikalisch-Technische Bundesanstalt photodiodes are calibrated with an uncertainty of spectral responsivity of 0.3% or less. Stable photodiodes are a prerequisite for the dissemination of these high-accuracy calibrations to customers. Silicon photodiodes with different top layers were exposed to intense extreme-ultraviolet irradiation. Diodes coated with diamondlike carbon or TiSiN proved to be stable within a few percent up to a radiant exposure of 100 kJ/cm2. The changes in responsivity could be explained as being due to carbon contamination and to changes in the internal charge collection efficiency. In ultrahigh vacuum, no indication of oxidation was found.

  16. Optimum Receiver Structure for PPM Signals with Avalanche Photodiode Statistics

    NASA Technical Reports Server (NTRS)

    Vilnrotter, V.; Srinivasan, M.

    1998-01-01

    The maximum likelihood decision statistic for detection of pulse-position modulated signals with an avalanche photodiode is derived, using the more accurate Webb density rather than Poisson or Gaussian approximations for the distribution of avalanche photodiode output electrons. It is shown that for Webb-distributed output electtrons, the maximum likelihood rule is to choose the PPM word corresponding to the slot with the maximum electron count.

  17. Radiation threshold levels for noise degradation of photodiodes. Technical report

    SciTech Connect

    Aukerman, L.W.; Vernon, F.L.; Song, Y.

    1986-09-30

    Space radiation can increase the noise of photodiodes as a result of either a sustained ionizing-dose-rate effect or displacement damage. Elementary, straightforward models are presented for calculating radiation threshold levels and rad hit susceptibility. Radiation-effects experiments that verify these models are discussed. Calculations for room-temperature silicon p-i-n photodetectors, an avalanche photodiode, and a hypothetical cooled staring detector indicate that this damage mechanism should not be ignored for space and nuclear environments.

  18. Optimum Receiver Structure for PPM Signals with Avalanche Photodiode Statistics

    NASA Technical Reports Server (NTRS)

    Vilnrotter, V.; Srinivasan, M.

    1998-01-01

    The maximum likelihood decision statistic for detection of pulse-position modulated signals with an avalanche photodiode is derived, using the more accurate Webb density rather than Poisson or Gaussian approximations for the distribution of avalanche photodiode output electrons. It is shown that for Webb-distributed output electtrons, the maximum likelihood rule is to choose the PPM word corresponding to the slot with the maximum electron count.

  19. Signal and noise properties of position-sensitive avalanche photodiodes.

    PubMed

    Yang, Yongfeng; Wu, Yibao; Farrell, Richard; Dokhale, Purushottam A; Shah, Kanai S; Cherry, Simon R

    2011-10-07

    After many years of development, position-sensitive avalanche photodiodes (PSAPDs) are now being incorporated into a range of scintillation detector systems, including those used in high-resolution small-animal PET and PET/MR scanners. In this work, the signal, noise, signal-to-noise ratio (SNR), flood histogram and timing resolution were measured for lutetium oxyorthosilicate (LSO) scintillator arrays coupled to PSAPDs ranging in size from 10 to 20 mm, and the optimum bias voltage and working temperature were determined. Variations in the SNR performance of PSAPDs with the same dimensions were small, but the SNR decreased significantly with increasing PSAPD size and increasing temperature. Smaller PSAPDs (10 mm and 15 mm in width) produced acceptable flood histograms at 24 °C, and cooling lower than 16 °C produced little improvement. The optimum bias voltage was about 25 V below the break down voltage. The larger 20 mm PSAPDs have lower SNR and require cooling to 0-7 °C for acceptable performance. The optimum bias voltage is also lower (35 V or more below the break down voltage depending on the temperature). Significant changes in the timing resolution were observed as the bias voltage and temperature varied. Higher bias voltages provided better timing resolution. The best timing resolution obtained for individual crystals was 2.8 ns and 3.3 ns for the 10 mm and 15 mm PSAPDs, respectively. The results of this work provide useful guidance for selecting the bias voltage and working temperature for scintillation detectors that incorporate PSAPDs as the photodetector.

  20. Signal and Noise Properties of Position-Sensitive Avalanche Photodiodes

    PubMed Central

    Yang, Yongfeng; Wu, Yibao; Farrell, Richard; Dokhale, Purushottam A.; Shah, Kanai S.; Cherry, Simon R.

    2011-01-01

    After many years of development, position-sensitive avalanche photodiodes (PSAPDs) are now being incorporated into a range of scintillation detector systems, including those used in high-resolution small-animal PET and PET/MR scanners. In this work, the signal, noise, signal-to-noise ratio (SNR), flood histogram and timing resolution were measured for lutetium oxyorthosilicate (LSO) scintillator arrays coupled to PSAPDs ranging in size from 10–20 mm, and the optimum bias voltage and working temperature determined. Variations in the SNR performance of PSAPDs with the same dimensions were small, but the SNR decreased significantly with increasing PSAPD size and increasing temperature. Smaller PSAPDs (10 mm and 15 mm in width) produced acceptable flood histograms at 24 °C, and cooling lower than 16 °C produced little improvement. The optimum bias voltage was about 25 V below the break down voltage. The larger 20 mm PSAPDs have lower SNR and require cooling to 0–7 °C for acceptable performance. The optimum bias voltage also is lower (35 V or more below the break down voltage depending on the temperature). Significant changes in the timing resolution were observed as the bias voltage and temperature were varied. Higher bias voltages provided better timing resolution. The best timing resolution obtained for individual crystals was 2.8 ns and 3.3 ns for the 10 mm and 15 mm PSAPDs, respectively. The results of this work provide useful guidance for selecting the bias voltage and working temperature for scintillation detectors that incorporate PSAPDs as the photodetector. PMID:21896961

  1. I-V and noise performance in MWIR to VLWIR large area Hg1-xCdxTe photodiodes

    NASA Astrophysics Data System (ADS)

    D'Souza, A. I.; Stapelbroek, M. G.; Dolan, P. N.; Wijewarnasuriya, P. S.; Boehmer, E.; Smith, D. S.; Ehlert, J. C.; Andrews, J. E.

    2005-05-01

    The National Polar-orbiting Operational Environmental Satellite System (NPOESS), is overseen by the Integrated Program Office (IPO), a joint effort of the Department of Defense, Department of Commerce and NASA. One of the instruments on the NPOESS satellite is the Cross-track Infrared Sounder (CrIS) instrument. CrIS is a Fourier Transform interferometric infrared (FTIR) sensor used to measure earth radiance at high spectral resolution to derive pressure, temperature, and moisture profiles of the atmosphere from the ground on up. Each CrIS instrument contains three different cutoff wavelength (λc)focal plane modules (FPMs): an SWIR FPM [λc(98 K) ~ 5 mm], MWIR FPM [λc(98 K) ~ 9 mm] and a LWIR FPM [λc(81 K) ~ 15.5 mm]. There are nine large (850 mm diameter) photodiodes per FPM, the nine detectors being arranged in a 3 x 3 array. The nine detectors are placed under tight tolerances in the X, Y, and Z dimensions. The steps involved in the transfer of photodiodes as part of a newly fabricated wafer to the mounting of the photodiodes on the FPM involves many processing steps including a significant amount of dicing, cleaning, wire bonding and baking at elevated temperatures. Quantum efficiency and 1/f noise in Hg1-xCdxTe photodiodes are critical parameters that limit the sensitivity of infrared sounders. The ratio α, defined as the noise current in unit bandwidth in(f = 1 Hz, Vd, Δf = 1 Hz) to the dark current Id(Vd), that is, α = in/Id is one of the parameters used to select photodiodes for placement in FPMs. α is equivalent to √αH/N that appears in the well-known Hooge expression. For the sixty-one, λc ~ 9 μm photodiodes measured at 60 mV reverse bias and at 98 K, the average value of αdark = 1.3 x 10-4 in the dark and αPHOTO = in/IPHOTO is ~ 2 x 10-6 under illuminated conditions. These values of α are a factor of two lower than that reported previously. The λc ~ 15.5 μm photodiodes have average αdark = 1.3 x 10-5 with the highest performance

  2. Dye based photodiodes for solar energy applications

    NASA Astrophysics Data System (ADS)

    Mensah-Darkwa, K.; Ocaya, R.; Dere, A.; Al-Sehemi, Abdullah G.; Al-Ghamdi, Ahmed A.; Soylu, M.; Gupta, R. K.; Yakuphanoglu, F.

    2017-10-01

    Coumarin (CO) doped methylene blue (MB) organic photo-devices were fabricated. The CO-doped MB (0.00, 0.01, 0.03, 0.05, 0.1 wt% CO) were coated onto the surface of a p-type Si substrate by drop casting method. Some electrical parameters of the devices have been examined by current-voltage ( I- V), capacitance-voltage ( C- V), and conductance-voltage ( G- V) measurements. The fabricated devices had excellent rectifying properties. The diode exhibits a non-ideal diode behavior due to the series resistance and interface layer. The ideality factor, the barrier height, and the series resistance values of the diode as a function of doping and light illumination have been estimated using modified Cheung-Cheung and Norde's method. The highest I photo/ I dark photosensitivity of 5606 was observed for the diode having 0.01 CO doping at 100 mW/cm2 under -3 V. Furthermore, change of capacitance and conductance measurements with frequency is related to the existence of interface states. A maximum power conversion efficiency of 2.4% is estimated for the fabricated devices. The results reveal that coumarin-doped methylene blue/ p-Si heterojunction can be used as a photodiode in optoelectronic applications. It is also usable in low-power photovoltaic applications.

  3. Transparent organic photodiodes stacked with electroluminescence devices

    NASA Astrophysics Data System (ADS)

    Komatsu, Takahiro; Sakanoue, Kei; Fujita, Katsuhiko; Tsutsui, Tetsuo

    2005-10-01

    Stacked devices that consisted of transparent organic photodiodes (TOPDs) and organic electroluminescence devices (OELs) were demonstrated. TOPDs were prepared by poly-(2-methoxy-5- (2'-ethylhexyloxy)-1,4-phenylene vinylene (MEH-PPV) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM) blend films as an active layer and transparent Au cathode (10 nm thick). These TOPDs showed about 45 % transmittance on average in visible light region (380-780 nm) and good correlation between incident light intensity and output photocurrent. Based on these results, the stacked devices were prepared by introducing OELs on TOPDs through a SiO insulating layer. The structure of OELs was ITO/Carbon/TPD/Alq3/LiF/Al. These stacked devices work as light emitting devices and also photo diodes. Since TOPDs have transparency, OELs can illuminate a paper put on the glass substrate through TOPDs and TOPDs can receive reflective light from the paper. Although the TOPDs also absorb light from OELs directly, the output signals from TOPDs changed according to the black and white pattern of the paper. These results show that the devices act as an image sensor having light emitting layer and light receiving layer in a same area.

  4. X-ray and charged particle detection with CsI(Tl) layer coupled to a-Si:H photodiode layers

    SciTech Connect

    Fujieda, I.; Cho, G.; Drewery, J.; Gee, T.; Jing, T.; Kaplan, S.N.; Perez-Mendez, V.; Wildermuth, D. ); Street, R.A. )

    1990-10-01

    A compact real-time X-ray and charged particle imager with digitized position output can built either by coupling a fast scintillator to a photodiode array or by forming one on a photodiode array directly. CsI(Tl) layers 100--1000{mu}m thick were evaporated on glass substrates from a crystal CsI(Tl). When coupled to a crystalline Si or amorphous silicon (a-Si:H) photodiode and exposed to calibrated X-ray pulses, their light yields and speed were found to be comparable to those of a crystal CsI(Tl). Single {beta} particle detection was demonstrated with this combination. The light spread inside evaporated CsI(Tl) was suppressed by its columnar structure. Scintillation detection gives much larger signals than direct X-ray detection due to the increased energy deposition in the detector material. Fabrication of monolithic type X-ray sensors consisting of CsI + a-Si:H photodiodes is discussed. 20 refs., 16 figs.

  5. A compact, discrete CsI(Tl) scintillator/Si photodiode gamma camera for breast cancer imaging

    SciTech Connect

    Gruber, Gregory J.

    2000-01-01

    Recent clinical evaluations of scintimammography (radionuclide breast imaging) are promising and suggest that this modality may prove a valuable complement to X-ray mammography and traditional breast cancer detection and diagnosis techniques. Scintimammography, however, typically has difficulty revealing tumors that are less than 1 cm in diameter, are located in the medial part of the breast, or are located in the axillary nodes. These shortcomings may in part be due to the use of large, conventional Anger cameras not optimized for breast imaging. In this thesis I present compact single photon camera technology designed specifically for scintimammography which strives to alleviate some of these limitations by allowing better and closer access to sites of possible breast tumors. Specific applications are outlined. The design is modular, thus a camera of the desired size and geometry can be constructed from an array (or arrays) of individual modules and a parallel hole lead collimator for directional information. Each module consists of: (1) an array of 64 discrete, optically-isolated CsI(Tl) scintillator crystals 3 x 3 x 5 mm3 in size, (2) an array of 64 low-noise Si PIN photodiodes matched 1-to-1 to the scintillator crystals, (3) an application-specific integrated circuit (ASIC) that amplifies the 64 photodiode signals and selects the signal with the largest amplitude, and (4) connectors and hardware for interfacing the module with a motherboard, thereby allowing straightforward computer control of all individual modules within a camera.

  6. Organic light detectors: photodiodes and phototransistors.

    PubMed

    Baeg, Kang-Jun; Binda, Maddalena; Natali, Dario; Caironi, Mario; Noh, Yong-Young

    2013-08-21

    While organic electronics is mostly dominated by light-emitting diodes, photovoltaic cells and transistors, optoelectronics properties peculiar to organic semiconductors make them interesting candidates for the development of innovative and disruptive applications also in the field of light signal detection. In fact, organic-based photoactive media combine effective light absorption in the region of the spectrum from ultraviolet to near-infrared with good photogeneration yield and low-temperature processability over large areas and on virtually every substrate, which might enable innovative optoelectronic systems to be targeted for instance in the field of imaging, optical communications or biomedical sensing. In this review, after a brief resume of photogeneration basics and of devices operation mechanisms, we offer a broad overview of recent progress in the field, focusing on photodiodes and phototransistors. As to the former device category, very interesting values for figures of merit such as photoconversion efficiency, speed and minimum detectable signal level have been attained, and even though the simultaneous optimization of all these relevant parameters is demonstrated in a limited number of papers, real applications are within reach for this technology, as it is testified by the increasing number of realizations going beyond the single-device level and tackling more complex optoelectronic systems. As to phototransistors, a more recent subject of study in the framework of organic electronics, despite a broad distribution in the reported performances, best photoresponsivities outperform amorphous silicon-based devices. This suggests that organic phototransistors have a large potential to be used in a variety of optoelectronic peculiar applications, such as a photo-sensor, opto-isolator, image sensor, optically controlled phase shifter, and opto-electronic switch and memory.

  7. Development of Gated Pinned Avalanche Photodiode Pixels for High-Speed Low-Light Imaging

    PubMed Central

    Resetar, Tomislav; De Munck, Koen; Haspeslagh, Luc; Rosmeulen, Maarten; Süss, Andreas; Puers, Robert; Van Hoof, Chris

    2016-01-01

    This work explores the benefits of linear-mode avalanche photodiodes (APDs) in high-speed CMOS imaging as compared to different approaches present in literature. Analysis of APDs biased below their breakdown voltage employed in single-photon counting mode is also discussed, showing a potentially interesting alternative to existing Geiger-mode APDs. An overview of the recently presented gated pinned avalanche photodiode pixel concept is provided, as well as the first experimental results on a 8 × 16 pixel test array. Full feasibility of the proposed pixel concept is not demonstrated; however, informative data is obtained from the sensor operating under −32 V substrate bias and clearly exhibiting wavelength-dependent gain in frontside illumination. The readout of the chip designed in standard 130 nm CMOS technology shows no dependence on the high-voltage bias. Readout noise level of 15 e- rms, full well capacity of 8000e-, and the conversion gain of 75 µV/e- are extracted from the photon-transfer measurements. The gain characteristics of the avalanche junction are characterized on separate test diodes showing a multiplication factor of 1.6 for red light in frontside illumination. PMID:27537882

  8. Development of Gated Pinned Avalanche Photodiode Pixels for High-Speed Low-Light Imaging.

    PubMed

    Resetar, Tomislav; De Munck, Koen; Haspeslagh, Luc; Rosmeulen, Maarten; Süss, Andreas; Puers, Robert; Van Hoof, Chris

    2016-08-15

    This work explores the benefits of linear-mode avalanche photodiodes (APDs) in high-speed CMOS imaging as compared to different approaches present in literature. Analysis of APDs biased below their breakdown voltage employed in single-photon counting mode is also discussed, showing a potentially interesting alternative to existing Geiger-mode APDs. An overview of the recently presented gated pinned avalanche photodiode pixel concept is provided, as well as the first experimental results on a 8 × 16 pixel test array. Full feasibility of the proposed pixel concept is not demonstrated; however, informative data is obtained from the sensor operating under -32 V substrate bias and clearly exhibiting wavelength-dependent gain in frontside illumination. The readout of the chip designed in standard 130 nm CMOS technology shows no dependence on the high-voltage bias. Readout noise level of 15 e - rms, full well capacity of 8000 e - , and the conversion gain of 75 µV / e - are extracted from the photon-transfer measurements. The gain characteristics of the avalanche junction are characterized on separate test diodes showing a multiplication factor of 1.6 for red light in frontside illumination.

  9. GaAs/AlGaAs quantum well infrared photoconductors versus HgCdTe photodiodes for long-wavelength infrared applications

    SciTech Connect

    Rogalski, A.; Jozwikowski, K. . Inst. of Technical Physics)

    1994-05-01

    Investigations of the performance of GaAs/AlGaAs quantum well IR photoconductors (QWIPs) as compared to HgCdTe photodiodes operated at temperatures below 77 K in the long-wavelength IR (LWIR) region are presented. In comparative studies, the current standard n[sup +]-p HgCdTe photodiodes as well as p[sup +]-n photodiodes are considered. Investigations of the fundamental physical limitations of HgCdTe photodiodes indicate better performance of this type of detector in comparison with QWIPs operated in the range 40 to 77 K. At 40 K, QWIPs with a cutoff wavelength of about 8 [mu]m indicate higher detectivity. The advantage of QWIPs increases in wider spectral regions and at temperatures below 40 K. Usually, in the temperature range below 50 K the performance of n[sup +]-p HgCdTe photodiodes is determined by trap-assisted tunneling. As a result, the advantage of GaAs/AlGaAs QWIPs increases in wider spectral regions ([lambda][sub c] [approx]8 to 12 [mu]m) and at temperatures below 50 K. The comparison with p[sup +]-n HgCdTe photodiodes is more complicated for lack of precisely modeled current transport in these junctions. GaAs/AlGaAs QWIPs at 40 K are background limited in low-background conditions. This observation plus the maturity of GaAs/AlGaAs technology and its radiation hardness characteristics promise that QWIP technology can produce high-quality focal plane arrays for space applications.

  10. A quantum efficiency analytical model for complementary metal—oxide—semiconductor image pixels with a pinned photodiode structure

    NASA Astrophysics Data System (ADS)

    Cao, Chen; Zhang, Bing; Wu, Long-Sheng; Li, Na; Wang, Jun-Feng

    2014-12-01

    A quantum efficiency analytical model for complementary metal—oxide—semiconductor (CMOS) image pixels with a pinned photodiode structure is developed. The proposed model takes account of the non-uniform doping distribution in the N-type region due to the impurity compensation formed by the actual fabricating process. The characteristics of two boundary PN junctions located in the N-type region for the particular spectral response of a pinned photodiode, are quantitatively analyzed. By solving the minority carrier steady-state diffusion equations and the barrier region photocurrent density equations successively, the analytical relationship between the quantum efficiency and the corresponding parameters such as incident wavelength, N-type width, peak doping concentration, and impurity density gradient of the N-type region is established. The validity of the model is verified by the measurement results with a test chip of 160 × 160 pixels array, which provides the accurate process with a theoretical guidance for quantum efficiency design in pinned photodiode pixels.

  11. Analysis of the photodiode boundary layer transition indicator

    SciTech Connect

    Kuntz, D.W.; Wilken, A.C.; Payne, J.L.

    1994-01-01

    The photodiode transition indicator is a device which has been successfully used to determine the onset of boundary layer transition on numerous hypersonic flight vehicles. The exact source of the electromagnetic radiation detected by the photodiode at transition was not understood. In some cases early saturation of the device occurred, and the device failed to detect transition. Analyses have been performed to determine the source of the radiation producing the photodiode signal. The results of these analyses indicate that the most likely source of the radiation is blackbody emission from the heatshield material bordering the quartz window of the device. Good agreement between flight data and calculations based on this radiation source has been obtained. Analyses also indicate that the most probable source of the radiation causing early saturation is blackbody radiation from carbon particles which break away from the nosetip during the ablation process.

  12. Recent advances in telecommunication avalanche photodiodes with nano-sized multiplication region

    NASA Astrophysics Data System (ADS)

    Zhao, Yanli; Zhang, Shibo; He, Suxiang

    2015-11-01

    This paper reviews the recent advances in telecommunication avalanche photodiodes with nano-sized multiplication region. A new low noise avalanche photodiode based on InP traditional material has been proposed for high speed optical communication.

  13. III-V alloy heterostructure high speed avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Law, H. D.; Nakano, K.; Tomasetta, L. R.

    1979-01-01

    Heterostructure avalanche photodiodes have been successfully fabricated in several III-V alloy systems: GaAlAs/GaAs, GaAlSb/GaAlSb, and InGaAsP/InP. These diodes cover optical wavelengths from 0.4 to 1.8 micron. Early stages of development show very encouraging results. High speed response of less than 35 ps and high quantum efficiency more than 95 percent have been obtained. The dark currents and the excess avalanche noise are also dicussed. A direct comparison of GaAlSb, GaAlAsSb, and In GaAsP avalanche photodiodes is given.

  14. III-V alloy heterostructure high speed avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Law, H. D.; Nakano, K.; Tomasetta, L. R.

    1979-01-01

    Heterostructure avalanche photodiodes have been successfully fabricated in several III-V alloy systems: GaAlAs/GaAs, GaAlSb/GaAlSb, and InGaAsP/InP. These diodes cover optical wavelengths from 0.4 to 1.8 micron. Early stages of development show very encouraging results. High speed response of less than 35 ps and high quantum efficiency more than 95 percent have been obtained. The dark currents and the excess avalanche noise are also dicussed. A direct comparison of GaAlSb, GaAlAsSb, and In GaAsP avalanche photodiodes is given.

  15. Study on avalanche photodiode influence on heterodyne laser interferometer linearity

    SciTech Connect

    Budzyn, Grzegorz Podzorny, Tomasz

    2016-06-28

    In the paper we analyze factors reducing the possible accuracy of the heterodyne laser interferometers. The analysis is performed for the avalanche-photodiode input stages but is in main points valid also for stages with other type of photodetectors. Instrumental error originating from optical, electronic and digital signal processing factors is taken into consideration. We stress factors which are critical and those which can be neglected at certain accuracy requirements. In the work we prove that it is possible to reduce errors of the laser instrument below 1 nm point for multiaxial APD based interferometers by precise control of incident optical power and the temperature of the photodiode.

  16. Monolithic integration of a silica AWG and Ge photodiodes on Si photonic platform for one-chip WDM receiver.

    PubMed

    Nishi, Hidetaka; Tsuchizawa, Tai; Kou, Rai; Shinojima, Hiroyuki; Yamada, Takashi; Kimura, Hideaki; Ishikawa, Yasuhiko; Wada, Kazumi; Yamada, Koji

    2012-04-09

    On the silicon (Si) photonic platform, we monolithically integrated a silica-based arrayed-waveguide grating (AWG) and germanium (Ge) photodiodes (PDs) using low-temperature fabrication technology. We confirmed demultiplexing by the AWG, optical-electrical signal conversion by Ge PDs, and high-speed signal detection at all channels. In addition, we mounted a multichannel transimpedance amplifier/limiting amplifier (TIA/LA) circuit on the fabricated AWG-PD device using flip-chip bonding technology. The results show the promising potential of our Si photonic platform as a photonics-electronics convergence.

  17. Analysis of genetically modified organisms by pyrosequencing on a portable photodiode-based bioluminescence sequencer.

    PubMed

    Song, Qinxin; Wei, Guijiang; Zhou, Guohua

    2014-07-01

    A portable bioluminescence analyser for detecting the DNA sequence of genetically modified organisms (GMOs) was developed by using a photodiode (PD) array. Pyrosequencing on eight genes (zSSIIb, Bt11 and Bt176 gene of genetically modified maize; Lectin, 35S-CTP4, CP4EPSPS, CaMV35S promoter and NOS terminator of the genetically modified Roundup ready soya) was successfully detected with this instrument. The corresponding limit of detection (LOD) was 0.01% with 35 PCR cycles. The maize and soya available from three different provenances in China were detected. The results indicate that pyrosequencing using the small size of the detector is a simple, inexpensive, and reliable way in a farm/field test of GMO analysis. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Linear Mode HgCdTe Avalanche Photodiodes for Photon Counting Applications

    NASA Technical Reports Server (NTRS)

    Sullivan, William, III; Beck, Jeffrey; Scritchfield, Richard; Skokan, Mark; Mitra, Pradip; Sun, Xiaoli; Abshire, James; Carpenter, Darren; Lane, Barry

    2015-01-01

    An overview of recent improvements in the understanding and maturity of linear mode photon counting with HgCdTe electron-initiated avalanche photodiodes is presented. The first HgCdTe LMPC 2x8 format array fabricated in 2011 with 64 micron pitch was a remarkable success in terms of demonstrating a high single photon signal to noise ratio of 13.7 with an excess noise factor of 1.3-1.4, a 7 ns minimum time between events, and a broad spectral response extending from 0.4 micron to 4.2 micron. The main limitations were a greater than 10x higher false event rate than expected of greater than 1 MHz, a 5-7x lower than expected APD gain, and a photon detection efficiency of only 50% when greater than 60% was expected. This paper discusses the reasons behind these limitations and the implementation of their mitigations with new results.

  19. An avalanche photodiode photon counting camera for high-resolution astronomy

    NASA Astrophysics Data System (ADS)

    Ryan, Oliver; Redfern, Mike; Shearer, Andrew

    2006-02-01

    A system is described which makes best use of the high quantum efficiency and high count rate capability of avalanche photodiodes for high time resolution observations of optical pulsars. The use of three APDs allows simultaneous photometry of the target and a reference star, and the monitoring of the sky background. By minimising the optical components in the light path the optical efficiency of the system is maximised. The TRIFFID (Shearer, A., Stappers, B., O'Connor, P., Golden, A., Strom, R., Redfern, M., Ryan, O.: Science 301, 493 495 (2003)) and OPTIMA (Straubmeier, C., Kanbach, G., Schrey, F.: Exp. Astron. 11, 157 170 (2001)) have shown that fibre-fed APD arrays can produce excellent results. This, new, system was used on the 6m BTA in November 2003 results on the Crab pulsar are presented.

  20. Measurement of charge transfer potential barrier in pinned photodiode CMOS image sensors

    NASA Astrophysics Data System (ADS)

    Chen, Cao; Bing, Zhang; Junfeng, Wang; Longsheng, Wu

    2016-05-01

    The charge transfer potential barrier (CTPB) formed beneath the transfer gate causes a noticeable image lag issue in pinned photodiode (PPD) CMOS image sensors (CIS), and is difficult to measure straightforwardly since it is embedded inside the device. From an understanding of the CTPB formation mechanism, we report on an alternative method to feasibly measure the CTPB height by performing a linear extrapolation coupled with a horizontal left-shift on the sensor photoresponse curve under the steady-state illumination. The theoretical study was performed in detail on the principle of the proposed method. Application of the measurements on a prototype PPD-CIS chip with an array of 160 × 160 pixels is demonstrated. Such a method intends to shine new light on the guidance for the lag-free and high-speed sensors optimization based on PPD devices. Project supported by the National Defense Pre-Research Foundation of China (No. 51311050301095).

  1. Characterization and simulation of linear scintillator arrays for low-energy x-ray detection

    NASA Astrophysics Data System (ADS)

    Franco, L.; Gómez, F.; Badano, A.

    2008-11-01

    Current x-ray imaging in many industrial and medical applications uses different scintillator materials coupled to photodiode arrays. Knowledge of the light distribution and photoelectron signal allows for the improvement of the imaging properties of such devices. We have measured and simulated the pixel scintillation light distribution collected by the photodiode arrays for four commercial scintillator arrays made of cesium iodide, cadmium tungstate and gadolinium oxysulfide with pitches of 0.8 mm and 1.6 mm. We used a collimated low-energy x-ray beam to study the collected signal in each array element and the effective fill factors determined from the photodiode geometry, backing material and radiation transport in the scintillator. A proper description of the optical parameters of these detectors provides excellent agreement of the experimental results with Monte Carlo simulations performed with MANTIS.

  2. Demonstration of Lasercom and Spatial Tracking with a Silicon Geiger-Mode APD Array

    DTIC Science & Technology

    2016-02-26

    Demonstration of lasercom and spatial tracking with a silicon Geiger-Mode APD array Timothy M. Yarnalla, Benjamin W. Horkleya,b, Ajay S. Garga, and...per information bit. 4. SPATIAL TRACKING A GM-APD array such as this one has a great deal of potential for use in a tracking system. The spatial ...counting receiver with the potential to act as a spatial tracker based on a silicon Geiger-mode avalanche photodiode array (GM-APD). This array enables

  3. Metalorganic chemical vapor deposition of HgCdTe for photodiode applications

    NASA Astrophysics Data System (ADS)

    Mitra, P.; Schimert, T. R.; Case, F. C.; Starr, R.; Weiler, M. H.; Kestigian, M.; Reine, M. B.

    1995-05-01

    Metalorganic chemical vapor depositon (MOCVD) in situ growth of p-on-n junctions for long wavelength infrared (LWIR) and medium wavelength infrared (MWIR) photodiodes is reported. The interdiffused multilayer process was used for the growth of the HgCdTe junctions on CdTe and CdZnTe substrates. The n-type region was grown undoped while the p-type layer was arsenic doped using tertiarybutylarsine. Following a low temperature anneal in Hg vapor, carrier densities of (0.2-2) x 1015 cm3 and mobilities of (0.7-1.2) x 105 cm2/V-s were obtained for n-type LWIR (x ~ 0.22) layers at 80K. Carrier lifetimes of these layers at 80 K are ~l-2 μs. For the p-type region arsenic doping was controlled in the range of (1-20) x 1016 cm-3. Arsenic doping levels in the junctions were determined by calibrated secondary ion mass spectroscopy depth profile measurements. Composition and doping of the p-on-n heterojunctions could be independently controlled so that the electrical junction could be located deeper than the change in the composition. The graded composition region between the narrow and wide (x = 0.28-0.30) bandgap regions are 1 2 μm depending on the growth temperature. Backside-illuminated variable-area circular mesa photodiode arrays were fabricated on the grown junctions as well as on ion implanted n-on-p MWIR junctions. The spectral responses are classical in shape. Quantum efficiencies at 80K are 42 77% for devices without anti-reflection coating and with cutoff wavelengths of 4.8 11.0 μm. Quantum efficiencies are independent of reverse bias voltage and do not decrease strongly at lower temperatures indicating that valence band barrier effects are not present. 80K RoA of 15.9 Ω-cm2 was obtained for an array with 11.0 μm cutoff. Detailed measurements of the characteristics of the MOCVD in situ grown and implanted photodiodes are reported.

  4. Synthetic Array Heterodyne Detection: Developments within the Caliope CO{sub 2} DIAL Program

    SciTech Connect

    Rehse, S.J.; Strauss, E.M.

    1995-09-01

    A new technique, Synthetic Array Heterodyne Detection, offers a wider field of view and improved signal to noise for coherent DIAL systems by reducing speckle interference. We have implemented a synthetic multi-pixel array using a CO{sub 2} laser on a single element HgCdTe photodiode.

  5. Optical phased-array ladar.

    PubMed

    Montoya, Juan; Sanchez-Rubio, Antonio; Hatch, Robert; Payson, Harold

    2014-11-01

    We demonstrate a ladar with 0.5 m class range resolution obtained by integrating a continuous-wave optical phased-array transmitter with a Geiger-mode avalanche photodiode receiver array. In contrast with conventional ladar systems, an array of continuous-wave sources is used to effectively pulse illuminate a target by electro-optically steering far-field fringes. From the reference frame of a point in the far field, a steered fringe appears as a pulse. Range information is thus obtained by measuring the arrival time of a pulse return from a target to a receiver pixel. This ladar system offers a number of benefits, including broad spectral coverage, high efficiency, small size, power scalability, and versatility.

  6. Future sensor system needs for staring arrays

    NASA Astrophysics Data System (ADS)

    Miller, John Lester

    2011-05-01

    This is a systems application paper regarding how sensor systems may use future technology FPAs. A historical perspective is discussed along with lessons learned from previous technologies. Future system requirements for strained super-lattice (SLS), quantum dots (QDOT) and traditional quantum well infrared photo-diodes (QWIP) arrays will be presented from both a commercial and military perspective. New potential markets will open up in the future if certain FPA technologies can reduce cost and provide higher sensitivities at higher operating temperatures.

  7. High quantum efficiency GaP avalanche photodiodes.

    PubMed

    McIntosh, Dion; Zhou, Qiugui; Chen, Yaojia; Campbell, Joe C

    2011-09-26

    Gallium Phosphide (GaP) reach-through avalanche photodiodes (APDs) are reported. The APDs exhibited dark current less than a pico-ampere at unity gain. A quantum efficiency of 70% was achieved with a recessed window structure; this is almost two times higher than previous work. © 2011 Optical Society of America

  8. Novel vertical silicon photodiodes based on salicided polysilicon trenched contacts

    SciTech Connect

    Kaminski, Yelena; Shauly, Eitan; Paz, Yaron

    2015-12-07

    The classical concept of silicon photodiodes comprises of a planar design characterized by heavily doped emitters. Such geometry has low collection efficiency of the photons absorbed close to the surface. An alternative, promising, approach is to use a vertical design. Nevertheless, realization of such design is technologically challenged, hence hardly explored. Herein, a novel type of silicon photodiodes, based on salicided polysilicon trenched contacts, is presented. These contacts can be prepared up to 10 μm in depth, without showing any leakage current associated with the increase in the contact area. Consequently, the trenched photodiodes revealed better performance than no-trench photodiodes. A simple two dimensional model was developed, allowing to estimate the conditions under which a vertical design has the potential to have better performance than that of a planar design. At large, the deeper the trench is, the better is the vertical design relative to the planar (up to 10 μm for silicon). The vertical design is more advantageous for materials characterized by short diffusion lengths of the carriers. Salicided polysilicon trenched contacts open new opportunities for the design of solar cells and image sensors. For example, these contacts may passivate high contact area buried contacts, by virtue of the conformity of polysilicon interlayer, thus lowering the via resistance induced recombination enhancement effect.

  9. Photonic nanojet-enhanced nanometer-scale germanium photodiode.

    PubMed

    Hasan, Mehdi; Simpson, Jamesina J

    2013-08-01

    A design challenge for photodiodes yielding both high speed and responsivity is the necessity to concentrate incident light into a subwavelength active volume region. Photonic nanojets have been reported in the literature as a means to focus an incident plane wave to a subwavelength-waist propagating beam with applications ranging from next-generation DVDs to characterizing subwavelength features within dielectric targets. In the present work, a new application of photonic nanojets is proposed, focusing electromagnetic energy into a photodiode. Three-dimensional finite-difference time-domain solutions are conducted to determine the advantages of photonic nanojet-enhanced photodiodes at near-infrared wavelengths (1310 nm). We find that photonic nanojets provide a factor of 26 increase in the volume-integrated electric field within the subwavelength active volume of the photodiode of size 0.0045 μm³. Furthermore, this increase is achieved independent of the incident polarization and over a broad bandwidth. Photonic nanojets may thus serve as an attractive alternative to plasmonics for some applications.

  10. Test of the DEP hybrid photodiode in 5 Tesla Magnet

    SciTech Connect

    Green, D; Freeman, J.; Ronzhin, A.; Cushman, R.; Heering, A.

    1997-10-01

    The CMS detector is designed so that the tile/fiber hadronic calorimeter (HCAL) is immersed in a 4 Tesla magnetic field. The Hybrid Photodiode (HPD) will be used as the photodetector. Below we present the experiment data which we obtained on the HPD behavior in a magnetic field.

  11. Radiation and Temperature Hard Multi-Pixel Avalanche Photodiodes

    NASA Technical Reports Server (NTRS)

    Bensaoula, Abdelhak (Inventor); Starikov, David (Inventor); Pillai, Rajeev (Inventor)

    2017-01-01

    The structure and method of fabricating a radiation and temperature hard avalanche photodiode with integrated radiation and temperature hard readout circuit, comprising a substrate, an avalanche region, an absorption region, and a plurality of Ohmic contacts are presented. The present disclosure provides for tuning of spectral sensitivity and high device efficiency, resulting in photon counting capability with decreased crosstalk and reduced dark current.

  12. Increasing the dynamic range of CMOS photodiode imagers

    NASA Technical Reports Server (NTRS)

    Pain, Bedabrata (Inventor); Cunningham, Thomas J. (Inventor); Hancock, Bruce R. (Inventor)

    2007-01-01

    A multiple-step reset process and circuit for resetting a voltage stored on a photodiode of an imaging device. A first stage of the reset occurs while a source and a drain of a pixel source-follower transistor are held at ground potential and the photodiode and a gate of the pixel source-follower transistor are charged to an initial reset voltage having potential less that of a supply voltage. A second stage of the reset occurs after the initial reset voltage is stored on the photodiode and the gate of the pixel source-follower transistor and the source and drain voltages of the pixel source-follower transistor are released from ground potential thereby allowing the source and drain voltages of the pixel source-follower transistor to assume ordinary values above ground potential and resulting in a capacitive feed-through effect that increases the voltage on the photodiode to a value greater than the initial reset voltage.

  13. Some studies of avalanche photodiode readout of fast scintillators

    SciTech Connect

    Holl, I.; Lorenz, E.; Natkaniez, S.; Renker, D.; Schmelz, C. |; Schwartz, B.

    1995-08-01

    Photomultipliers (PMs) are the classical readout element for scintillation detectors in high energy particle physics, nuclear physics, medical physics, industrial radiation monitors etc. Here, large area avalanche photodiodes with high performance, narrow operation tolerances and high reliability have recently become available. The authors report on some tests of their performance in the readout of fast scintillators.

  14. Reading a CD-ROM without a photodiode

    NASA Astrophysics Data System (ADS)

    Wishon, Michael J.; Mourozeau, G.; Ng, K.; Sahai, A. A.; Locquet, Alexandre; Citrin, D. S.

    2016-04-01

    We use a laser diode from a commercial CD/DVD-ROM drive to detect changes in the surface of a diffraction grating without a photodiode. Specifically, we exploit the changing terminal voltage in the laser-diode due to changing feedback strength as the laser is rastered across the grating's surface.

  15. BiCMOS-integrated photodiode exploiting drift enhancement

    NASA Astrophysics Data System (ADS)

    Swoboda, Robert; Schneider-Hornstein, Kerstin; Wille, Holger; Langguth, Gernot; Zimmermann, Horst

    2014-08-01

    A vertical pin photodiode with a thick intrinsic layer is integrated in a 0.5-μm BiCMOS process. The reverse bias of the photodiode can be increased far above the circuit supply voltage, enabling a high-drift velocity. Therefore, a highly efficient and very fast photodiode is achieved. Rise/fall times down to 94 ps/141 ps at a bias of 17 V were measured for a wavelength of 660 nm. The bandwidth was increased from 1.1 GHz at 3 V to 2.9 GHz at 17 V due to the drift enhancement. A quantum efficiency of 85% with a 660-nm light was verified. The technological measures to avoid negative effects on an NPN transistor due to the Kirk effect caused by the low-doped I-layer epitaxy are described. With a high-energy collector implant, the NPN transit frequency is held above 20 GHz. CMOS devices are unaffected. This photodiode is suitable for a wide variety of high-sensitivity optical sensor applications, for optical communications, for fiber-in-the-home applications, and for optical interconnects.

  16. Traveling wave model of uni-traveling carrier photodiode

    NASA Astrophysics Data System (ADS)

    Khanra, Senjuti; Das Barman, Abhirup

    2015-06-01

    A traveling wave time domain model of bulk InGaAs/InP uni-traveling carrier photodiode is presented in terms of integral carrier density rate equation. The wavelength dependent responsivity at different absorption width has been derived from quantum mechanical principle. Output photocurrent response with time is found in close agreement with the experimental value.

  17. Novel vertical silicon photodiodes based on salicided polysilicon trenched contacts

    NASA Astrophysics Data System (ADS)

    Kaminski, Yelena; Shauly, Eitan; Paz, Yaron

    2015-12-01

    The classical concept of silicon photodiodes comprises of a planar design characterized by heavily doped emitters. Such geometry has low collection efficiency of the photons absorbed close to the surface. An alternative, promising, approach is to use a vertical design. Nevertheless, realization of such design is technologically challenged, hence hardly explored. Herein, a novel type of silicon photodiodes, based on salicided polysilicon trenched contacts, is presented. These contacts can be prepared up to 10 μm in depth, without showing any leakage current associated with the increase in the contact area. Consequently, the trenched photodiodes revealed better performance than no-trench photodiodes. A simple two dimensional model was developed, allowing to estimate the conditions under which a vertical design has the potential to have better performance than that of a planar design. At large, the deeper the trench is, the better is the vertical design relative to the planar (up to 10 μm for silicon). The vertical design is more advantageous for materials characterized by short diffusion lengths of the carriers. Salicided polysilicon trenched contacts open new opportunities for the design of solar cells and image sensors. For example, these contacts may passivate high contact area buried contacts, by virtue of the conformity of polysilicon interlayer, thus lowering the via resistance induced recombination enhancement effect.

  18. Hybrid AlGaN-SiC Avalanche Photodiode for Deep-UV Photon Detection

    NASA Technical Reports Server (NTRS)

    Aslam, Shahid; Herrero, Federico A.; Sigwarth, John; Goldsman, Neil; Akturk, Akin

    2010-01-01

    The proposed device is capable of counting ultraviolet (UV) photons, is compatible for inclusion into space instruments, and has applications as deep- UV detectors for calibration systems, curing systems, and crack detection. The device is based on a Separate Absorption and Charge Multiplication (SACM) structure. It is based on aluminum gallium nitride (AlGaN) absorber on a silicon carbide APD (avalanche photodiode). The AlGaN layer absorbs incident UV photons and injects photogenerated carriers into an underlying SiC APD that is operated in Geiger mode and provides current multiplication via avalanche breakdown. The solid-state detector is capable of sensing 100-to-365-nanometer wavelength radiation at a flux level as low as 6 photons/pixel/s. Advantages include, visible-light blindness, operation in harsh environments (e.g., high temperatures), deep-UV detection response, high gain, and Geiger mode operation at low voltage. Furthermore, the device can also be designed in array formats, e.g., linear arrays or 2D arrays (micropixels inside a superpixel).

  19. Antimonide-based Geiger-mode avalanche photodiodes for SWIR and MWIR photon counting

    NASA Astrophysics Data System (ADS)

    Duerr, Erik K.; Manfra, Michael J.; Diagne, Mohamed A.; Bailey, Robert J.; Zayhowski, John J.; Donnelly, Joseph P.; Connors, Michael K.; Grzesik, Michael J.; Turner, George W.

    2010-04-01

    At MIT Lincoln Laboratory, avalanche photodiodes (APDs) have been developed for both 2-μm and 3.4-μm detection using the antimonide material system. These bulk, lattice-matched detectors operate in Geiger mode at temperatures up to 160 K. The 2-μm APDs use a separate-absorber-multiplier design with an InGaAsSb absorber and electron-initiated avalanching in the multiplier. These APDs have exhibited normalized avalanche probability (product of avalanche probability and photo-carrier-injection probability) of 0.4 and dark count rates of ~150 kHz at 77 K for a 30-μm-diameter device. A 1000- element imaging array of the 2-μm detectors has been demonstrated, which operate in a 5 kg dewar with an integrated Stirling-cycle cooler. The APD array is interfaced with a CMOS readout circuit, which provides photon time-of-arrival information for each pixel, allowing the focal plane array to be used in a photon-counting laser radar system. The 3.4-μm APDs use an InAsSb absorber and hole-initiated avalanching and have shown dark count rates of ~500 kHz at 77 K but normalized avalanche probability of < 1%. Research is ongoing to determine the cause of the low avalanche probability and improve the device performance.

  20. Analysis and modeling of optical crosstalk in InP-based Geiger-mode avalanche photodiode FPAs

    NASA Astrophysics Data System (ADS)

    Chau, Quan; Jiang, Xudong; Itzler, Mark A.; Entwistle, Mark; Piccione, Brian; Owens, Mark; Slomkowski, Krystyna

    2015-05-01

    Optical crosstalk is a major factor limiting the performance of Geiger-mode avalanche photodiode (GmAPD) focal plane arrays (FPAs). This is especially true for arrays with increased pixel density and broader spectral operation. We have performed extensive experimental and theoretical investigations on the crosstalk effects in InP-based GmAPD FPAs for both 1.06-μm and 1.55-μm applications. Mechanisms responsible for intrinsic dark counts are Poisson processes, and their inter-arrival time distribution is an exponential function. In FPAs, intrinsic dark counts and cross talk events coexist, and the inter-arrival time distribution deviates from purely exponential behavior. From both experimental data and computer simulations, we show the dependence of this deviation on the crosstalk probability. The spatial characteristics of crosstalk are also demonstrated. From the temporal and spatial distribution of crosstalk, an efficient algorithm to identify and quantify crosstalk is introduced.

  1. Quantitative Analysis of Spectral Impacts on Silicon Photodiode Radiometers: Preprint

    SciTech Connect

    Myers, D. R.

    2011-04-01

    Inexpensive broadband pyranometers with silicon photodiode detectors have a non-uniform spectral response over the spectral range of 300-1100 nm. The response region includes only about 70% to 75% of the total energy in the terrestrial solar spectral distribution from 300 nm to 4000 nm. The solar spectrum constantly changes with solar position and atmospheric conditions. Relative spectral distributions of diffuse hemispherical irradiance sky radiation and total global hemispherical irradiance are drastically different. This analysis convolves a typical photodiode response with SMARTS 2.9.5 spectral model spectra for different sites and atmospheric conditions. Differences in solar component spectra lead to differences on the order of 2% in global hemispherical and 5% or more in diffuse hemispherical irradiances from silicon radiometers. The result is that errors of more than 7% can occur in the computation of direct normal irradiance from global hemispherical irradiance and diffuse hemispherical irradiance using these radiometers.

  2. 10 Gbps silicon waveguide-integrated infrared avalanche photodiode.

    PubMed

    Ackert, Jason J; Karar, Abdullah S; Paez, Dixon J; Jessop, Paul E; Cartledge, John C; Knights, Andrew P

    2013-08-26

    We have fabricated monolithic silicon avalanche photodiodes capable of 10 Gbps operation at a wavelength of 1550 nm. The photodiodes are entirely CMOS process compatible and comprise a p-i-n junction integrated with a silicon-on-insulator (SOI) rib waveguide. Photo-generation is initiated via the presence of deep levels in the silicon bandgap, introduced by ion implantation and modified by subsequent annealing. The devices show a small signal 3 dB bandwidth of 2.0 GHz as well as an open eye pattern at 10 Gbps. A responsivity of 4.7 ± 0.5 A/W is measured for a 600 µm device at a reverse bias of 40 V.

  3. Planar InAs photodiodes fabricated using He ion implantation.

    PubMed

    Sandall, Ian; Tan, Chee Hing; Smith, Andrew; Gwilliam, Russell

    2012-04-09

    We have performed Helium (He) ion implantation on InAs and performed post implant annealing to investigate the effect on the sheet resistance. Using the transmission line model (TLM) we have shown that the sheet resistance of a p⁺ InAs layer, with a nominal doping concentration of 1x10¹⁸ cm⁻³, can increase by over 5 orders of magnitude upon implantation. We achieved a sheet resistance of 1x10⁵ Ω/Square in an 'as-implanted' sample and with subsequent annealing this can be further increased to 1x10⁷ Ω/Square. By also performing implantation on p-i-n structures we have shown that it is possible to produce planar photodiodes with comparable dark currents and quantum efficiencies to chemically etched reference mesa InAs photodiodes.

  4. Experimental verification of the photodiode theory of SIS mixers

    NASA Technical Reports Server (NTRS)

    Woody, David P.; Wengler, Michael J.

    1993-01-01

    The authors describe the characterization and interpretation of the performance of SIS receivers within the framework of the photodiode theory of mixing. The quantum efficiency plays a dominant role in the theory, and a simple method of accurately measuring this parameter is presented. It is demonstrated that the quantum efficiency measurements can be conveniently made on a standard radio astronomy receiver and combined with the usual hot and cold load characterization to improve the understanding of the receiver's performance. The measurements verify that the photodiode theory of mixing accurately describes the receiver noise even at local-oscillator power levels well above the linear response range. The results for receivers operating at 100 and 240 GHz verify the utility of this approach. These methods should also prove useful in evaluating submillimeter receivers.

  5. Heteroleptic neutral Ru(II) complexes based photodiodes

    NASA Astrophysics Data System (ADS)

    Elgazzar, Elsayed; Dayan, O.; Serbetci, Z.; Dere, A.; Al-Sehemi, Abdullah G.; Al-Ghamdi, Ahmed A.; El-Tantawy, Farid; Farooq, W. A.; Yakuphanoglu, F.

    2017-07-01

    The two complexes Ru (II) containing 2,6-bis(benzimidazol-2-yl)pyridine and 2-pyridine and 2-quinoline carboxylates were synthesized to fabricate organic photodiodes. The electrical properties of Au / Ru (II) complex (I) / n - Si / Al and Au / Ru (II) complex (II) / n - Si / Al diodes were investigated by current-voltage and capacitance-voltage measurements. The fabricated devices give a high rectification behavior with rectification ratio of 2.4 × 104 -2.1 × 103 at ± 4 V. The diodes exhibited a high photoconductivity based on trap levels within band gap. The series resistance and barrier height were calculated from (C - V) measurements and compared to other of (I - V) . The obtained results indicate that the prepared photodiodes can be used as photosensor for optoelectronic applications.

  6. Flexible germanium nanomembrane metal-semiconductor-metal photodiodes

    SciTech Connect

    Kim, Munho; Seo, Jung-Hun; Yu, Zongfu; Ma, Zhenqiang; Zhou, Weidong

    2016-08-01

    We demonstrate flexible Ge nanomembrane (Ge NM) based metal-semiconductor-metal photodiodes. The effect of uniaxial tensile strain on Ge NM based photodiodes was investigated using bending fixtures. Dark current density is decreased from 21.5 to 4.8 mA/cm{sup 2} at 3 V by a tensile strain of 0.42% while photon responsivity is increased from 0.2 to 0.45 A/W at the wavelength of 1.5 μm. Enhanced responsivity is also observed at longer wavelengths up to 1.64 μm. The uniaxial tensile strain effectively reduces the direct bandgap energy of the Ge NM, leading to a shift of the absorption edge toward a longer wavelength.

  7. Design, fabrication, and characterization of InSb avalanche photodiode

    NASA Astrophysics Data System (ADS)

    Abautret, J.; Evirgen, A.; Perez, J. P.; Christol, P.; Rouvié, A.; Cluzel, R.; Cordat, A.; Rothman, J.

    2013-12-01

    In this communication, the potentiality of InSb material as an avalanche photodiode (APD) device is investigated. Current density-voltage (J-V) characteristics at 77K of InSb pin photodiodes were simulated by using ATLAS software from SILVACO, in dark conditions and under illumination. In order to validate parameter values used for the modeling, theoretical J-V results were compared with experimental measurements performed on InSb diodes fabricated by molecular beam epitaxy. Next, assuming a multiplication process only induced by the electrons (e-APD), different designs of separate absorption and multiplication (SAM) APD structure were theoretically investigated and the first InSb SAM APD structure with 1μm thick multiplication layer was then fabricated and characterized.

  8. 3D integration of Geiger-mode avalanche photodiodes aimed to very high fill-factor pixels for future linear colliders

    NASA Astrophysics Data System (ADS)

    Vilella, E.; Alonso, O.; Diéguez, A.

    2013-12-01

    This paper presents an analysis of the maximum achievable fill-factor by a pixel detector of Geiger-mode avalanche photodiodes with the Chartered 130 nm/Tezzaron 3D process. The analysis shows that fill-factors between 66% and 96% can be obtained with different array architectures and a time-gated readout circuit of minimum area. The maximum fill-factor is achieved when the two-layer vertical stack is used to overlap the non-sensitive areas of one layer with the sensitive areas of the other one. Moreover, different sensor areas are used to further increase the fill-factor. A chip containing a pixel detector of the Geiger-mode avalanche photodiodes and aimed to future linear colliders has been designed with the Chartered 130 nm/Tezzaron 3D process to increase the fill-factor.

  9. Infrared to visible image up-conversion using optically addressed spatial light modulator utilizing liquid crystal and InGaAs photodiodes

    SciTech Connect

    Solodar, A. Arun Kumar, T.; Sarusi, G.; Abdulhalim, I.

    2016-01-11

    Combination of InGaAs/InP heterojunction photodetector with nematic liquid crystal (LC) as the electro-optic modulating material for optically addressed spatial light modulator for short wavelength infra-red (SWIR) to visible light image conversion was designed, fabricated, and tested. The photodetector layer is composed of 640 × 512 photodiodes array based on heterojunction InP/InGaAs having 15 μm pitch on InP substrate and with backside illumination architecture. The photodiodes exhibit extremely low, dark current at room temperature, with optimum photo-response in the SWIR region. The photocurrent generated in the heterojunction, due to the SWIR photons absorption, is drifted to the surface of the InP, thus modulating the electric field distribution which modifies the orientation of the LC molecules. This device can be attractive for SWIR to visible image upconversion, such as for uncooled night vision goggles under low ambient light conditions.

  10. Infrared to visible image up-conversion using optically addressed spatial light modulator utilizing liquid crystal and InGaAs photodiodes

    NASA Astrophysics Data System (ADS)

    Solodar, A.; Arun Kumar, T.; Sarusi, G.; Abdulhalim, I.

    2016-01-01

    Combination of InGaAs/InP heterojunction photodetector with nematic liquid crystal (LC) as the electro-optic modulating material for optically addressed spatial light modulator for short wavelength infra-red (SWIR) to visible light image conversion was designed, fabricated, and tested. The photodetector layer is composed of 640 × 512 photodiodes array based on heterojunction InP/InGaAs having 15 μm pitch on InP substrate and with backside illumination architecture. The photodiodes exhibit extremely low, dark current at room temperature, with optimum photo-response in the SWIR region. The photocurrent generated in the heterojunction, due to the SWIR photons absorption, is drifted to the surface of the InP, thus modulating the electric field distribution which modifies the orientation of the LC molecules. This device can be attractive for SWIR to visible image upconversion, such as for uncooled night vision goggles under low ambient light conditions.

  11. Avalanche Photodiode Statistics in Triggered-avalanche Detection Mode

    NASA Technical Reports Server (NTRS)

    Tan, H. H.

    1984-01-01

    The output of a triggered avalanche mode avalanche photodiode is modeled as Poisson distributed primary avalanche events plus conditionally Poisson distributed trapped carrier induced secondary events. The moment generating function as well as the mean and variance of the diode output statistics are derived. The dispersion of the output statistics is shown to always exceed that of the Poisson distribution. Several examples are considered in detail.

  12. III-Nitride Visible- and Solar-Blind Avalanche Photodiodes

    DTIC Science & Technology

    2007-12-01

    Manager: Dr. Donald Silversmith – Air Force Office of Scientific Research Principal Investigator: Professor Manijeh Razeghi Center for...photodiodes K. Minder, J.L. Pau, R. McClintock, P. Kung, C. Bayram, M. Razeghi and D. Silversmith Applied Physics Letters, Vol. 91, No. 7, p. 073513-1...M. Razeghi, E. Muñoz, and D. Silversmith Applied Physics Letters, Vol. 91, No. 04, p. 041104 -1-- July 23, 2007 3. Hole-initiated multiplication

  13. Wavelength dependence of silicon avalanche photodiode fabricated by CMOS process

    NASA Astrophysics Data System (ADS)

    Mohammed Napiah, Zul Atfyi Fauzan; Hishiki, Takuya; Iiyama, Koichi

    2017-07-01

    Avalanche photodiodes fabricated by CMOS process (CMOS-APDs) have features of high avalanche gain below 10 V, wide bandwidth over 5 GHz, and easy integration with electronic circuits. In CMOS-APDs, guard ring structure is introduced for high-speed operation by canceling photo-generated carriers in the substrate at the sacrifice of the responsivity. We describe here wavelength dependence of the responsivity and the bandwidth of the CMOS-APDs with shorted and opened guard ring structure.

  14. Receiver characteristics of laser altimeters with avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Sun, Xiaoli; Davidson, Frederic M.; Boutsikaris, Leo; Abshire, James B.

    1992-01-01

    The receiver characteristics of a laser altimeter system containing an avalanche photodiode photodetector are analyzed using the Gaussian approximation, the saddle-point approximation, and a nearly exact analysis. The last two methods are shown to yield very similar results except when the background noise is extremely low and the probability of false alarm is high. However, the Gaussian approximation method is shown to cause significant errors even under relatively high levels of background noise and received signal energy.

  15. Receiver characteristics of laser altimeters with avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Sun, Xiaoli; Davidson, Frederic M.; Boutsikaris, Leo; Abshire, James B.

    1992-01-01

    The receiver characteristics of a laser altimeter system containing an avalanche photodiode photodetector are analyzed using the Gaussian approximation, the saddle-point approximation, and a nearly exact analysis. The last two methods are shown to yield very similar results except when the background noise is extremely low and the probability of false alarm is high. However, the Gaussian approximation method is shown to cause significant errors even under relatively high levels of background noise and received signal energy.

  16. Avalanche Photodiode Statistics in Triggered-avalanche Detection Mode

    NASA Technical Reports Server (NTRS)

    Tan, H. H.

    1984-01-01

    The output of a triggered avalanche mode avalanche photodiode is modeled as Poisson distributed primary avalanche events plus conditionally Poisson distributed trapped carrier induced secondary events. The moment generating function as well as the mean and variance of the diode output statistics are derived. The dispersion of the output statistics is shown to always exceed that of the Poisson distribution. Several examples are considered in detail.

  17. Automated Sky-Compensating Photometer with a Silicon Photodiode

    NASA Astrophysics Data System (ADS)

    Riggs, J. D.; Alexander, D. R.

    1983-12-01

    This article describes the automated, sky-compensating filter photometer, currently being built and tested for the Lake Afton Public Observatory (LAPO) at Wichita State University, for use on the 16-inch Ritchey-Chretien telescope. Design emphasis is directed toward minimal user intervention due to varying user backgrounds. The instrumentation consists of a sky-compensating photometer, a Hamamatsu S1133-01 silicon photodiode detector, a programmable DC amplifier, and a computer dedicated to data collection and photometer control.

  18. Design and fabrication of dioxyphenylcoumarin substituted cyclotriphosphazene compounds photodiodes

    NASA Astrophysics Data System (ADS)

    Elgazzar, Elsayed; Dere, A.; Özen, Furkan; Koran, Kenan; Al-Sehemi, Abdullah G.; Al-Ghamdi, Ahmed A.; Orhan Görgülü, Ahmet; El-Tantawy, F.; Yakuphanoglu, F.

    2017-06-01

    The present study introduces cyclotriphosphazene compounds substituted by dioxyphenylcoumarin as a photodiode application. Firstly, 7,8-dihydroxy-3-(3-methylphenyl)coumarin (1b) has been obtained by conventional as well as microwave assisted methods. Novel optoelectronic device characteristics for both mono and disubstituted dioxyphenylcoumarin bearing cyclotriphosphazene compounds (HCP-2 and HCP-4) have been synthesized from the reactions of cyclotriphosphazene containing dioxybiphenyl (HCP-1 and HCP-3) with compound 1b, respectively. The structures of compounds HCP 1-4 were identified by using elemental analysis, 1H, 13C-APT, 31P NMR and 2D HETCOR NMR and FT-IR spectroscopy methods. The Al/HCP-2/p-Si/Al and Al/HCP-4/-p-Si/Al photodiodes properties have been investigated from current-voltage (I - V) and capacitance-voltage (C - V) measurements. The electrical parameters of the prepared diodes such as ideality factor n and series resistance Rs were investigated in dark and at room temperature from (I - V) curve and Nord's method. As can be seen, the Al/HCP-2/p-Si/Al diode of high rectification ratio RR and with ideality factor greater than unity. The influence of light illuminations on the diode shows that the device can be used as photodiode with good efficiency. The barrier height ϕb and series resistance Rs have been calculated from the capacitance-voltage (C - V) and conductance-voltage (G - V) measurements under various applied frequencies from 10 kHz to 1 MHz. the high difference in the results of barrier height obtained from I-V and C-V calculations confirm the influence of series resistance and localized states on transport of charge carriers and the photodiode performance.

  19. Geiger-mode avalanche photodiodes, history, properties and problems

    NASA Astrophysics Data System (ADS)

    Renker, D.

    2006-11-01

    Geiger-mode avalanche photodiodes (G-APDs) have been developed during recent years and promise to be an alternative to photomultiplier tubes. They have many advantages like single photon response, high detection efficiency, high gain at low bias voltage and very good timing properties but some of their properties, the dark count rate for example, can be a problem. Several types of G-APDs are on the market and should be selected carefully for a given application.

  20. Investigation of avalanche photodiodes radiation hardness for baryonic matter studies

    NASA Astrophysics Data System (ADS)

    Kushpil, V.; Mikhaylov, V.; Ladygin, V. P.; Kugler, A.; Kushpil, S.; Svoboda, O.; Tlustý, P.

    2016-01-01

    Modern avalanche photodiodes (APDs) with high gain are good device candidates for light readout from detectors applied in relativistic heavy ion collisions experiments. The results of the investigations of the APDs properties from Zecotek, Ketek and Hamamatsu manufacturers after irradiation using secondary neutrons from cyclotron facility U120M at NPI of ASCR in Řež are presented. The results of the investigations can be used for the design of the detectors for the experiments at NICA and FAIR.

  1. Nanoscale avalanche photodiodes for highly sensitive and spatially resolved photon detection.

    PubMed

    Hayden, Oliver; Agarwal, Ritesh; Lieber, Charles M

    2006-05-01

    Integrating nanophotonics with electronics could enhance and/or enable opportunities in areas ranging from communications and computing to novel diagnostics. Light sources and detectors are important elements for integration, and key progress has been made using semiconducting nanowires and carbon nanotubes to yield electrically driven sources and photoconductor detectors. Detection with photoconductors has relatively poor sensitivity at the nanometre scale, and thus large amplification is required to detect low light levels and ultimately single photons with reasonable response time. Here, we report avalanche multiplication of the photocurrent in nanoscale p-n diodes consisting of crossed silicon-cadmium sulphide nanowires. Electrical transport and optical measurements demonstrate that the nanowire avalanche photodiodes (nanoAPDs) have ultrahigh sensitivity with detection limits of less than 100 photons, and subwavelength spatial resolution of at least 250 nm. Crossed nanowire arrays also show that nanoAPDs are reproducible and can be addressed independently without cross-talk. NanoAPDs and arrays could open new opportunities for ultradense integrated systems, sensing and imaging applications.

  2. Developments in HgCdTe avalanche photodiode technology and applications

    NASA Astrophysics Data System (ADS)

    Ashcroft, Andrew; Baker, Ian

    2010-04-01

    SELEX Galileo has developed avalanche photodiode technology in HgCdTe to serve a whole range of applications in defence, security, commercial and space research. Burst-illumination LIDAR (BIL), using a near-infrared pulse laser and a fast, gated detector, is now adopted for most long range imaging applications. New results from range trials using prototype systems based on multifunctional and 3D detectors are reported. In the astronomy field, APD arrays at 2.5 μm cutoff can provide near-single photon sensitivity for future wavefront sensors and interferometric applications. Under a contract from European Southern Observatories arrays have been successfully demonstrated with gains up to 20× and negligible dark current at 77K. Under a European Space Agency contract, a large area, single element detector has been designed for the 2.015μm CO2 absorption line. The sensor is specifically designed to be operated at 200K so that thermoelectric cooling is viable. The element is made up of many sub-pixel diodes each deselectable to ensure high breakdown in the macro-pixel. The latest results of the detector and its associated transimpedance amplifier (TIA) are presented.

  3. Avalanche photodiode based detector for beam emission spectroscopy.

    PubMed

    Dunai, D; Zoletnik, S; Sárközi, J; Field, A R

    2010-10-01

    An avalanche photodiode based (APD) detector for the visible wavelength range was developed for low light level, high frequency beam emission spectroscopy (BES) experiments in fusion plasmas. This solid state detector has higher quantum efficiency than photomultiplier tubes, and unlike normal photodiodes, it has internal gain. This paper describes the developed detector as well as the noise model of the electronic circuit. By understanding the noise sources and the amplification process, the optimal amplifier and APD reverse voltage setting can be determined, where the signal-to-noise ratio is the highest for a given photon flux. The calculations are compared to the absolute calibration results of the implemented circuit. It was found that for a certain photon flux range, relevant for BES measurements (≈10(8)-10(10) photons/s), the new detector is superior to both photomultipliers and photodiodes, although it does not require cryogenic cooling of any component. The position of this photon flux window sensitively depends on the parameters of the actual experimental implementation (desired bandwidth, detector size, etc.) Several detector units based on these developments have been built and installed in various tokamaks. Some illustrative results are presented from the 8-channel trial BES system installed at Mega-Ampere Spherical Tokamak (MAST) and the 16-channel BES system installed at the Torus Experiment for Technology Oriented Research (TEXTOR).

  4. Amplifiers dedicated for large area SiC photodiodes

    NASA Astrophysics Data System (ADS)

    Doroz, P.; Duk, M.; Korwin-Pawlowski, M. L.; Borecki, M.

    2016-09-01

    Large area SiC photodiodes find applications in optoelectronic sensors working at special conditions. These conditions include detection of UV radiation in harsh environment. Moreover, the mentioned sensors have to be selective and resistant to unwanted signals. For this purpose, the modulation of light at source unit and the rejection of constant current and low frequency component of signal at detector unit are used. The popular frequency used for modulation in such sensor is 1kHz. The large area photodiodes are characterized by a large capacitance and low shunt resistance that varies with polarization of the photodiode and can significantly modify the conditions of signal pre-amplification. In this paper two pre-amplifiers topology are analyzed: the transimpedance amplifier and the non-inverting voltage to voltage amplifier with negative feedback. The feedback loops of both pre-amplifiers are equipped with elements used for initial constant current and low frequency signals rejections. Both circuits are analyzed and compared using simulation and experimental approaches.

  5. Vertically illuminated TW-UTC photodiodes for terahertz generation

    NASA Astrophysics Data System (ADS)

    Barrientos Z., Claudio M.; Calle G., Victor H.; Alvarez, Jaime A.; Mena, F. Patricio; Vukusic, Josip; Stake, Jan; Michael, Ernest A.

    2012-09-01

    More efficient and powerful continuous-wave photonic mixers as terahertz sources are motivated by the need of more versatile local oscillators for submillimeter/terahertz receiver systems. Uni-Travelling Carrier (UTC) photodiodes are very prospective candidates for reaching this objective, but so far only have been reported as lumped-elements or as edge-illuminated optical-waveguide travelling-wave (TW) devices. To overcome the associated power limitations of those implementations, we are developing a novel implementation of the UTC photodiodes which combines a travelingwave photomixer with vertical velocity-matched illumination in a distributed structure. In this implementation called velocity-matched travelling-wave uni-travelling carrier photodiode, it is possible to obtain in-situ velocity matching of the beat-fringes of the two angled laser beams with the submm/THz-wave on the stripline. In this way, minimum frequency roll-off is achieved by tuning the angle between the two laser beams. A first design of these TW-UTC PDs from our Terahertz Photonics Laboratory at University of Chile has been micro-fabricated at the MC2 cleanroom facility at Chalmers Technical University.

  6. Pulsed irradiation of optimized, MBE grown, AlGaAs/GaAs radiation hardened photodiodes. Rev

    SciTech Connect

    Wiczer, J.J.; Fischer, T.A.; Dawson, L.R.; Osbourn, G.C.; Zipperian, T.E.; Barnes, C.E.

    1984-01-01

    An AlGaAs/GaAs double heterojunction, mesa isolated, photodiode grown by molecular beam epitaxy was irradiated with 18 MeV electrons, 1 to 10 MeV x-rays, and neutrons from a pulsed reactor. Test results indicate that the AlGaAs/GaAs photodiodes generate approximately 10 to 20 times less photocurrent during exposure to a pulse of ionizing-radiation than radiation hardened silicon PIN photodiodes. Studies of neutron induced permanent damage in the AlGaAs/GaAs photodiode show only small changes in optical responsivity and a factor of 8 increase in leakage currents after exposure to 3.6 x 10/sup 15/ neutrons/cm/sup 2/ and 900 krad gamma. The silicon PIN photodiode was exposed to only 28% of the fluence used on the AlGaAs photodiodes and we observed a 40% decrease in optical responsivity and a factor of 7000 increase in leakage current.

  7. Study of EUV and x-ray radiation hardness of silicon photodiodes

    NASA Astrophysics Data System (ADS)

    Zabrodsky, Vladimir V.; Aruev, Pavel; Filimonov, Vladimir V.; Sobolev, Nikolay A.; Sherstnev, Evgeniy V.; Belik, Viktor P.; Nikolenko, Anton D.; Ivlyushkin, Denis V.; Pindyurin, Valery F.; Shadrin, Nikita S.; Soldatov, Artem E.; Mashkovtsev, Mikhail R.

    2013-05-01

    This work presents the results of long-term observation of the silicon photodiodes spatial profile response and the silicon photodiodes dark current after their exposure to 10.2 eV quanta and in the spectral range of 150-300 eV. Exposure of the photodiodes to quanta of an energy of 10.2 eV was repeated. Several other photodiodes have been irradiated in the spectral range of 700-1800 eV with a dose of 8 J/cm2. The spatial profile of the irradiated photodiodes was studied with 3.49 eV, 10.2 eV and 100 eV quanta. The effect of the recovery of the response spatial profile has been proved for the p+-n diode. An additional useful method of visualization of irradiated photodiode area is also presented.

  8. Development and validation of highly selective screening and confirmatory methods for the qualitative forensic analysis of organic explosive compounds with high performance liquid chromatography coupled with (photodiode array and) LTQ ion trap/Orbitrap mass spectrometric detections (HPLC-(PDA)-LTQOrbitrap).

    PubMed

    Xu, Xiaoma; Koeberg, Mattijs; Kuijpers, Chris-Jan; Kok, Eric

    2014-01-01

    An LTQ-Orbitrap FTMS is a new (hybrid) mass spectrometric (MS) analyzer. It allows for the acquisition of full scan MS(n) (n-stage fragmentations, n=1-n) spectra with the linear ion trap detector (LTQ) at high speed and/or with the Fourier Transform-detector (Orbitrap) with ultra high mass resolution (>60,000 at m/z<400amu) and high mass accuracy (≤1ppm with internal calibration). In addition it may be coupled with liquid chromatography (LC) with photo diode array (PDA) detection. Two methods for the forensic screening and confirmation of all common trace explosives in post-blast residues have been developed on this instrument using atmospheric pressure chemical ionization (APCI). In one run, the nitrogen-containing explosives are analyzed with the combination of "LC-(PDA)-APCI(-)-LTQ MS(2)/Orbitrap FTMS" (Method 1). In another run, peroxide explosives are analyzed with "LC-APCI(+)-LTQ MS(2)/Orbitrap FTMS" (Method 2). The performance of both methods has been validated according to procedures defined in the EU COMMISSION DECISION implementing Council Directive 96/23/EC concerning the performance of analytical methods and the interpretation of results (DC 2002/657/EC) and other standards (NEN 17025 and NEN 7777). The methods are highly selective due to the simultaneous utilization of the Orbitrap FTMS and LTQ MS(2), both of which are highly selective detectors Tested explosive compounds can be detected in the molecular ion form by the Orbitrap analyzer with minimal mass interference in different matrices when using an extremely narrow mass tolerance detection window (≤2ppm). The identification of a detected compound follows an identification point system. Experimental results show that almost all explosive compounds meet the confirmation criteria (minimum 4 points) required for the positive identification by the DC 2002/657/EC. © 2013. Published by Elsevier Ireland Ltd on behalf of Forensic Science Society. All rights reserved.

  9. Low-cost, High Performance Avalanche Photodiodes for Enabling High Sensitivity Bio-fluorescence Detection

    DTIC Science & Technology

    2012-04-01

    Detection Efficiency Avalanche Photodiode in Geiger - mode Operation. IEEE Phot. Tech. Lett. 2007, 19, 378–80. 5. Vurgaftman, I.; Meyer, J. R. Band...Low-cost, High Performance Avalanche Photodiodes for Enabling High Sensitivity Bio-fluorescence Detection (Final Report) by Anand V. Sampath...Research Laboratory Adelphi, MD 20783-1197 ARL-TR-5981 April 2012 Low-cost, High Performance Avalanche Photodiodes for Enabling High

  10. Highly enhanced avalanche probability using sinusoidally-gated silicon avalanche photodiode

    SciTech Connect

    Suzuki, Shingo; Namekata, Naoto Inoue, Shuichiro; Tsujino, Kenji

    2014-01-27

    We report on visible light single photon detection using a sinusoidally-gated silicon avalanche photodiode. Detection efficiency of 70.6% was achieved at a wavelength of 520 nm when an electrically cooled silicon avalanche photodiode with a quantum efficiency of 72.4% was used, which implies that a photo-excited single charge carrier in a silicon avalanche photodiode can trigger a detectable avalanche (charge) signal with a probability of 97.6%.

  11. Guided-wave photodiode using through-absorber quantum-well-intermixing and methods thereof

    SciTech Connect

    Skogen, Erik J.

    2016-10-25

    The present invention includes a high-speed, high-saturation power detector (e.g., a photodiode) compatible with a relatively simple monolithic integration process. In particular embodiments, the photodiode includes an intrinsic bulk absorption region, which is grown above a main waveguide core including a number of quantum wells (QWs) that are used as the active region of a phase modulator. The invention also includes methods of fabricating integrated photodiode and waveguide assemblies using a monolithic, simplified process.

  12. Electrodynamics of a planar photodiode discharge for an obliquely incident initiating laser pulse

    SciTech Connect

    Lazarev, Y. N. Syrtsova, Yu. G.

    2012-01-15

    An approximate analytic solution of Maxwell's equations is obtained inside a photodiode. Analysis of this solution shows that the earlier discovered significant decrease in the radiation field characteristics over an anode is caused by a considerable increase in the amplitude of a wave generated inside the photodiode, which for angles of incidence {theta} {yields} {pi}/2 achieves a value comparable to the initial electric field strength applied to the photodiode. In this case, the electromagnetic energy flux density inside the photodiode exceeds tens times or more the electromagnetic energy flux density over the anode. The results of numerical calculations confirm the analytic results.

  13. A new approach to investigate leakage current mechanisms in infrared photodiodes from illuminated current-voltage characteristics

    SciTech Connect

    Gopal, Vishnu

    2014-08-28

    This paper presents a new approach to investigate leakage current mechanisms in infrared photodiodes from the illuminated current–voltage characteristics. The example of mid-wave mercury cadmium telluride photodiodes is presented to illustrate the new approach. The new method is suitable for evaluating diodes in an array environment as advance knowledge of any of the material or device parameters are not required. The thermal saturation current is estimated from the observed open circuit voltage and zero-bias current (photo-current) of the diode. The ohmic shunt resistance is estimated from the observed maximum dynamic impedance of the diode. The experimentally observed reverse bias diode current in excess of thermal current, photo-current, and ohmic shunt current is reported to be best described by an exponential function of the type, I{sub excess} = I{sub r0} + K{sub 1} exp (K{sub 2} V), where I{sub r0}, K{sub 1}, and K{sub 2} are fitting parameters and V is the applied bias voltage. Our investigations reveal a close link between the excess current and the sources of ohmic currents in the diode. Exponential growth of excess current with the applied bias voltage has been interpreted as an indication of soft breakdown of the diodes.

  14. Tapered LSO arrays for small animal PET

    NASA Astrophysics Data System (ADS)

    Yang, Yongfeng; St. James, Sara; Wu, Yibao; Du, Huini; Qi, Jinyi; Farrell, Richard; Dokhale, Purushottam A.; Shah, Kanai S.; Vaigneur, Keith; Cherry, Simon R.

    2011-01-01

    By using detectors with good depth encoding accuracy (~2 mm), an animal PET scanner can be built with a small ring diameter and thick crystals to simultaneously obtain high spatial resolution and high sensitivity. However, there will be large wedge-shaped gaps between detector modules in such a scanner if traditional cuboid crystal arrays are used in a polygonal arrangement. The gaps can be minimized by using tapered scintillator arrays enabling the sensitivity of the scanner to be further improved. In this work, tapered lutetium oxyorthosilicate (LSO) arrays with different crystal dimensions and different combinations of inter-crystal reflector and crystal surface treatments were manufactured and their performance was evaluated. Arrays were read out from both ends by position-sensitive avalanche photodiodes (PSAPDs). In the optimal configuration, arrays consisting of 0.5 mm LSO elements could be clearly resolved and a depth of interaction resolution of 2.6 mm was obtained for a 20 mm thick array. For this tapered array, the intrinsic spatial is degraded from 0.67 to 0.75 mm compared to a standard cuboidal array with similar dimensions, while the increase in efficiency is 41%. Tapered scintillator arrays offer the prospect of improvements in sensitivity and sampling for small-bore scanners, without large increases in manufacturing complexity.

  15. Tapered LSO Arrays for Small Animal PET

    PubMed Central

    Yang, Yongfeng; James, Sara St.; Wu, Yibao; Du, Huini; Qi, Jinyi; Farrell, Richard; Dokhale, Purushottam A.; Shah, Kanai S.; Vaigneur, Keith; Cherry, Simon R.

    2011-01-01

    By using detectors with good depth encoding accuracy (~ 2 mm), an animal PET scanner can be built with a small ring diameter and thick crystals to simultaneously obtain high spatial resolution and high sensitivity. However, there will be large wedge-shaped gaps between detector modules in such a scanner if traditional cuboid crystal arrays are used in a polygonal arrangement. The gaps can be minimized by using tapered scintillator arrays enabling the sensitivity of the scanner to be further improved. In this work, tapered lutetium oxyorthosilicate (LSO) arrays with different crystal dimensions and different combinations of inter-crystal reflector and crystal surface treatments were manufactured and their performance was evaluated. Arrays were read out from both ends by position-sensitive avalanche photodiodes (PSAPDs). In the optimal configuration, arrays consisting of 0.5 mm LSO elements could be clearly resolved and a depth of interaction resolution of 2.6 mm was obtained for a 20-mm thick array. For this tapered array, the intrinsic spatial is degraded from 0.67 mm to 0.75 mm compared to a standard cuboidal array with similar dimensions, while the increase in efficiency is 41%. Tapered scintillator arrays offer the prospect of improvements in sensitivity and sampling for small-bore scanners, without large increases in manufacturing complexity. PMID:21119228

  16. High performance x-ray imaging detectors on foil using solution-processed organic photodiodes with extremely low dark leakage current (Presentation Recording)

    NASA Astrophysics Data System (ADS)

    Kumar, Abhishek; Moet, Date; van der Steen, Jan Laurens; van Breemen, Albert; Shanmugam, Santhosh; Gilot, Jan; Andriessen, Ronn; Simon, Matthias; Ruetten, Walter; Douglas, Alexander; Raaijmakers, Rob; Malinowski, Pawel E.; Myny, Kris; Gelinck, Gerwin

    2015-10-01

    High performance X-ray imaging detectors on foil using solution-processed organic photodiodes with extremely low dark leakage current Abhishek Kumara, Date Moeta, Albert van Breemena, Santhosh Shanmugama, Jan-Laurens van der Steena, Jan Gilota, Ronn Andriessena, Matthias Simonb, Walter Ruettenb, Alexander U. Douglasb, Rob Raaijmakersc, Pawel E. Malinowskid, Kris Mynyd and Gerwin H. Gelincka,e a. Holst Centre/TNO, High Tech Campus 31, Eindhoven 5656 AE, The Netherlands b. Philips Research, High Tech Campus 34, 5656 AE Eindhoven, The Netherlands c. Philips Healthcare, Veenpluis 6-8, 5684 PC Best, The Netherlands d. Department of Large Area Electronics, imec vzw, Kapeldreef 75, Leuven B3001, Belgium e. Applied Physics Department, TU Eindhoven, Eindhoven, The Netherlands We demonstrate high performance X-ray imaging detectors on foil suitable for medical grade X-ray imaging applications. The detectors are based on solution-processed organic photodiodes forming bulk-heterojunctions from photovoltaic donor and acceptor blend. The organic photodiodes are deposited using an industrially compatible slot die coating technique with end of line processing temperature below 100°C. These photodiodes have extremely low dark leakage current density of 10-7 mA/cm2 at -2V bias with very high yield and have peak absorption around 550 nm wavelength. We combine these organic photodiodes with high mobility metal oxide semiconductor based thin film transistor arrays with high pixel resolution of 200ppi on thin plastic substrate. When combined with a typical CsI(TI) scintillator material on top, they are well suited for low dose X-ray imaging applications. The optical crosstalk is insignificant upto resolution of 200 ppi despite the fact that the photodiode layer is one continuous layer and is non-pixelated. Low processing temperatures are another key advantage since they can be fabricated on plastic substrate. This implies that we can make X-ray detectors on flexible foil. Those

  17. Application of photodiodes to the detection of electromagnetic bursts

    NASA Technical Reports Server (NTRS)

    Fukushima, Y.; Saito, T.; Sakata, M.; Shima, M.; Yamamoto, Y.

    1985-01-01

    A new type of photodiode + scintillator (1 m2 x 1 cm) detector is developed to detect the large electro-magnetic burst under an EX-chamber. The threshold burst size is found to be 4.3 x 10 the 5 particles at the center of the scintillator. Therefore a gamma-ray family of 10 TeV is detectable by it, when it is set under 14 r.1. of iron. In addition, a very fast (2.4 nsec width) and very bright (correspond to 10 to the 6 particles) scintillation pulse has become avarable for this study.

  18. Silicon avalanche photodiode operation and lifetime analysis for small satellites.

    PubMed

    Tan, Yue Chuan; Chandrasekara, Rakhitha; Cheng, Cliff; Ling, Alexander

    2013-07-15

    Silicon avalanche photodiodes (APDs) are sensitive to operating temperature fluctuations and are also susceptible to radiation flux expected in satellite-based quantum experiments. We introduce a low power voltage adjusting mechanism to overcome the effects of in-orbit temperature fluctuations. We also present data on the performance of Si APDs after irradiation (γ-ray and proton beam). Combined with an analysis of expected orbital irradiation, we propose that a Si APD in a 400 km equatorial orbit may operate beyond the lifetime of the satellite.

  19. Thermal calibration of photodiode sensitivity for atomic force microscopy

    SciTech Connect

    Attard, Phil; Pettersson, Torbjoern; Rutland, Mark W.

    2006-11-15

    The photodiode sensitivity in the atomic force microscope is calibrated by relating the voltage noise to the thermal fluctuations of the cantilever angle. The method accounts for the ratio of the thermal fluctuations measured in the fundamental vibration mode to the total, and also for the tilt and extended tip of the cantilever. The method is noncontact and is suitable for soft or deformable surfaces where the constant compliance method cannot be used. For hard surfaces, the method can also be used to calibrate the cantilever spring constant.

  20. A 1.06 micrometer avalanche photodiode receiver

    NASA Technical Reports Server (NTRS)

    Eden, R. C.

    1975-01-01

    The development of a complete solid state 1.06 micron optical receiver which can be used in optical communications at data rates approaching 1.5 Gb/s, or in other applications requiring sensitive, short pulse detection, is reported. This work entailed both the development of a new type of heterojunction III-V semiconductor alloy avalanche photodiode and an extremely charge-sensitive wideband low noise preamp design making use of GaAs Schottky barrier-gate field effect transistors (GAASFET's) operating in in the negative-feedback transimpedance mode. The electrical characteristics of the device are described.

  1. 400-ps time resolution with a passively quenched avalanche photodiode.

    PubMed

    Grayson, T P; Wang, L J

    1993-06-01

    Avalanche photodiodes (APD's) operated in a single-photon-counting Geiger mode are becoming attractive alternatives to photomultiplier tubes for low-light-level detection and signal timing. By paying careful attention to the design and construction of a simple APD passive quenching circuit to reduce stray capacitances, we directly measured a time resolution of 410 ps FWHM for a commercial APD. A more detailed data analysis shows the actual time resolution to be ~ 390 ps FWHM. This is believed to be the most accurate time response for such a simple, inexpensive, and widely available device achieved to date.

  2. Photon counting modules using RCA silicon avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Lightstone, Alexander W.; Macgregor, Andrew D.; Macsween, Darlene E.; Mcintyre, Robert J.; Trottier, Claude; Webb, Paul P.

    1989-01-01

    Avalanche photodiodes (APD) are excellent small area, solid state detectors for photon counting. Performance possibilities include: photon detection efficiency in excess of 50 percent; wavelength response from 400 to 1000 nm; count rate to 10 (exp 7) counts per sec; afterpulsing at negligible levels; timing resolution better than 1 ns. Unfortunately, these performance levels are not simultaneously available in a single detector amplifier configuration. By considering theoretical performance predictions and previous and new measurements of APD performance, the anticipated performance of a range of proposed APD-based photon counting modules is derived.

  3. Radiation Threshold Levels for Noise Degradation of Photodiodes.

    DTIC Science & Technology

    1986-09-30

    for Noise Degradation of Photodiodes L. W. AUKERMAN , F. L. VERNON, Jr., and Y. SONG Electronics Research Laboratory Laboratory Operations The...PERFORMING ORG. REPORT NUMBER TR-0086 (6925-04)-2 7. AUTHOR(e) S. CONTRACT OR GRANT NUMBER(a) Lee W. Aukerman , Frank L. Vernon, Jr., and Yeong Song...Agency, Washington, D.C. (December 1971). 8. D. H. Seib and L. W. Aukerman , "Photodetectors for the 0.1 to 1.0 4m Spectral Region," Advances in

  4. Reliability assessment of multiple quantum well avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Yun, Ilgu; Menkara, Hicham M.; Wang, Yang; Oguzman, Isamil H.; Kolnik, Jan; Brennan, Kevin F.; May, Gray S.; Wagner, Brent K.; Summers, Christopher J.

    1995-01-01

    The reliability of doped-barrier AlGaAs/GsAs multi-quantum well avalanche photodiodes fabricated by molecular beam epitaxy is investigated via accelerated life tests. Dark current and breakdown voltage were the parameters monitored. The activation energy of the degradation mechanism and median device lifetime were determined. Device failure probability as a function of time was computed using the lognormal model. Analysis using the electron beam induced current method revealed the degradation to be caused by ionic impurities or contamination in the passivation layer.

  5. Photon counting modules using RCA silicon avalanche photodiodes

    NASA Technical Reports Server (NTRS)

    Lightstone, Alexander W.; Macgregor, Andrew D.; Macsween, Darlene E.; Mcintyre, Robert J.; Trottier, Claude; Webb, Paul P.

    1989-01-01

    Avalanche photodiodes (APD) are excellent small area, solid state detectors for photon counting. Performance possibilities include: photon detection efficiency in excess of 50 percent; wavelength response from 400 to 1000 nm; count rate to 10 (exp 7) counts per sec; afterpulsing at negligible levels; timing resolution better than 1 ns. Unfortunately, these performance levels are not simultaneously available in a single detector amplifier configuration. By considering theoretical performance predictions and previous and new measurements of APD performance, the anticipated performance of a range of proposed APD-based photon counting modules is derived.

  6. Vertically illuminated TW-UTC photodiodes for terahertz generation

    NASA Astrophysics Data System (ADS)

    Barrientos Z., Claudio; Calle, Victor; Diaz, Marcos; Mena, F. Patricio; Vukusic, Josip; Stake, Jan; Michael, Ernest A.

    2010-07-01

    More efficient continuous-wave photonic nearinfrared mixers as terahertz sources are investigated with the motivation to develop a universal photonic local oscillator for astronomical submillimeter/terahertz receiver systems. For this, we develop new concepts for vertically illuminated traveling-wave (TW) photomixers, TW Uni-Travelling Carrier (UTC) photodiodes. Device simulation/modeling and optical/terahertz testing is being done in the new terahertz photonics laboratory at the Electrical Engineering Department of the University of Chile, whereas device fabrication is performed at the MC2 cleanroom facility at Chalmers Technical University. We report on first progress in this direction.

  7. Vertically Illuminated TW-UTC Photodiodes for Terahertz Generation

    NASA Astrophysics Data System (ADS)

    Barrientos, C.; Calle, V.; Diaz, M.; Mena, F. P.; Vukusic, J.; Stake, J.; Michael, E. A.

    2010-03-01

    More efficient continuous-wave photonic near-infrared mixers as terahertz sources are investigated with the motivation to develop a universal photonic local oscillator for astronomical submillimeter/terahertz receiver systems. For this, our group has developed new concepts for vertically illuminated traveling-wave (TW) photomixers. The new device called TW-Uni-Travelling Carrier photodiodes (TW-UTC PD) was simulated, modeled and shall be optical/terahertz tested at the Electrical Engineering Department of the University of Chile, whereas device fabrication is performed at the MC2 cleanroom facility at Chalmers University of technology. We are reporting on first progresses in this direction.

  8. Electrically tuneable spectral responsivity in gated silicon photodiodes

    NASA Astrophysics Data System (ADS)

    Abid, Kamran; Wang, Xingsheng; Khokhar, Ali Z.; Watson, Scott; Al-Hasani, Sulaiman; Rahman, Faiz

    2011-12-01

    We report the observation of electrically tuneable spectral responsivity in silicon-based photodetectors. The current flowing through a lateral p-i-n junction photodiode can be changed by changing either the gate bias or the intensity of incident light, with the devices exhibiting typical optical responsivities of 65 A/W. The peak sensitivity of the device can be changed over the entire visible region by changing the gate voltage in a 5 V range. This happens because with increasing gate bias, an accumulation layer of holes is pulled closer to the Si-SiO2 interface, enhancing the blue response of the device.

  9. Waveguide-integrated telecom-wavelength photodiode in deposited silicon.

    PubMed

    Preston, Kyle; Lee, Yoon Ho Daniel; Zhang, Mian; Lipson, Michal

    2011-01-01

    We demonstrate photodiodes in deposited polycrystalline silicon at 1550 nm wavelength with 0.15 A/W responsivity, 40 nA dark current, and gigahertz time response. Subband absorption is mediated by defects that are naturally present in the polycrystalline material structure. The material exhibits a moderate absorption coefficient of 6 dB/cm, which allows the same microring resonator device to act as both a demultiplexing filter and a photodetector. We discuss the use of deposited silicon-based complementary metal-oxide semiconductor materials for nanophotonic interconnects.

  10. MRS Photodiode, LED and extruded scintillator performance in magnetic field

    SciTech Connect

    Beznosko, D.; Blazey, G.; Dyshkant, A.; Francis, K.; Kubik, D.; Rykalin, V.; Zutshi, V.; /Northern Illinois U.

    2005-05-01

    The experimental results on the performance of the MRS (Metal/Resistor/Semiconductor) photodiode in the strong magnetic field of 4.4T, and the possible impact of the quench of the magnet at 4.5T on sensor's operation are reported. In addition, the experimental results on the performance of the extruded scintillator and WLS fiber, and various LEDs in the magnetic fields of 1.8T and 2.3T respectively, are detailed. The measurement method used is being described.

  11. Effect of temperature on silicon PIN photodiode radiation detectors

    NASA Astrophysics Data System (ADS)

    Kim, Han Soo; Jeong, Manhee; Kim, Young Soo; Ha, Jang Ho; Cho, Seong Yeon

    2014-03-01

    One of the noise sources of a semiconductor radiation detector is thermal noise, which degrades the performance, such as the energy resolution and unexpected random pulse signals. In this study, PIN photodiode radiation detectors, with different active areas were designed and fabricated for an experimental comparison of the energy resolutions for different temperatures and capacitances by using a Ba-133 calibration gamma-ray source. The experimental temperature was approximately in the range from -7 to 24 °C and was controlled by using a peltier device. The design considerations and the electrical characteristics, such as the I-V and the C-V characteristics, are also addressed.

  12. Initial results from the Sherbrooke avalanche photodiode positron tomograph

    SciTech Connect

    Lecomte, R.; Cadorette, J.; Rodrigue, S.; Lapointe, D.; Rouleau, D.; Bentourkia, M.; Yao, R.; Msaki, P.

    1996-06-01

    The design features and engineering constraints of a PET system based on avalanche photodiode (APD) detectors have been described in a previous report. In this paper, the authors present the initial results obtained with the Sherbrooke APD-PET scanner, a very high spatial resolution device designed for dynamic imaging of small and medium-sized laboratory animals such as rats, cats, rabbits and small monkeys. Its physical performance has been evaluated in terms of resolution, sensitivity, count rate, random and scatter fractions, contrast and relative activity recovery as a function of object size. The capabilities of the scanner for biomedical research applications have been demonstrated using phantom and animal studies.

  13. Current Kink and Capacitance Frequency Dispersion in Silicon PIN Photodiodes

    NASA Astrophysics Data System (ADS)

    Guo, Xia; Feng, Yajie; Liu, Qiaoli; Wang, Huaqiang; Li, Chong; Hu, Zonghai; He, Xiaoying

    2017-09-01

    Silicon PIN photodiodes in the visible wavelength range have been widely applied in aerospace, defense, security, medical, and scientific instruments because of their high sensitivity and low cost. In this paper, the phenomena of the current kink and the capacitance frequency dispersion are observed. Contamination at the p-type Ohmic contact interface is proposed to explain the current kink effect and capacitance frequency dispersion, according to the temperature-dependent I-V measurement results in which trap-assisted tunneling process demonstrated.

  14. Analysis and Enhancement of Low-Light-Level Performance of Photodiode-Type CMOS Active Pixel Images Operated with Sub-Threshold Reset

    NASA Technical Reports Server (NTRS)

    Pain, Bedabrata; Yang, Guang; Ortiz, Monico; Wrigley, Christopher; Hancock, Bruce; Cunningham, Thomas

    2000-01-01

    Noise in photodiode-type CMOS active pixel sensors (APS) is primarily due to the reset (kTC) noise at the sense node, since it is difficult to implement in-pixel correlated double sampling for a 2-D array. Signal integrated on the photodiode sense node (SENSE) is calculated by measuring difference between the voltage on the column bus (COL) - before and after the reset (RST) is pulsed. Lower than kTC noise can be achieved with photodiode-type pixels by employing "softreset" technique. Soft-reset refers to resetting with both drain and gate of the n-channel reset transistor kept at the same potential, causing the sense node to be reset using sub-threshold MOSFET current. However, lowering of noise is achieved only at the expense higher image lag and low-light-level non-linearity. In this paper, we present an analysis to explain the noise behavior, show evidence of degraded performance under low-light levels, and describe new pixels that eliminate non-linearity and lag without compromising noise.

  15. Spectral method for characterization of avalanche photodiode working as single-photon detector.

    PubMed

    Cavalcanti, Maria Daniela Santabaia; Mendonça, Fábio Alencar; Ramos, Rubens Viana

    2011-09-01

    In this Letter, a new method for avalanche photodiode characterization, based on the spectral analysis of the photocurrent produced during an avalanche, is proposed. The theory is developed, and an experimental characterization of an avalanche photodiode working in the Geiger mode with CW laser is performed.

  16. Characteristics of Various Photodiode Structures in CMOS Technology with Monolithic Signal Processing Electronics

    SciTech Connect

    Mukhopadhyay, Sourav; Chandratre, V. B.; Sukhwani, Menka; Pithawa, C. K.

    2011-10-20

    Monolithic optical sensor with readout electronics are needed in optical communication, medical imaging and scintillator based gamma spectroscopy system. This paper presents the design of three different CMOS photodiode test structures and two readout channels in a commercial CMOS technology catering to the need of nuclear instrumentation. The three photodiode structures each of 1 mm{sup 2} with readout electronics are fabricated in 0.35 um, 4 metal, double poly, N-well CMOS process. These photodiode structures are based on available P-N junction of standard CMOS process i.e. N-well/P-substrate, P+/N-well/P-substrate and inter-digitized P+/N-well/P-substrate. The comparisons of typical characteristics among three fabricated photo sensors are reported in terms of spectral sensitivity, dark current and junction capacitance. Among the three photodiode structures N-well/P-substrate photodiode shows higher spectral sensitivity compared to the other two photodiode structures. The inter-digitized P+/N-well/P-substrate structure has enhanced blue response compared to N-well/P-substrate and P+/N-well/P-substrate photodiode. Design and test results of monolithic readout electronics, for three different CMOS photodiode structures for application related to nuclear instrumentation, are also reported.

  17. Material and design engineering of (Al)GaN for high-performance avalanche photodiodes and intersubband applications

    NASA Astrophysics Data System (ADS)

    Razeghi, M.; Bayram, C.

    2009-05-01

    Numerous applications in scientific, medical, and military areas demand robust, compact, sensitive, and fast ultraviolet (UV) detection. Our (Al)GaN photodiodes pose high avalanche gain and single-photon detection efficiency that can measure up to these requirements. Inherit advantage of back-illumination in our devices offers an easier integration and layout packaging via flip-chip hybridization for UV focal plane arrays that may find uses from space applications to hostile-agent detection. Thanks to the recent (Al)GaN material optimization, III-Nitrides, known to have fast carrier dynamics and short relaxation times, are employed in (Al)GaN based superlattices that absorb in near-infrared regime. In this work, we explain the origins of our high performance UV APDs, and employ our (Al)GaN material knowledge for intersubband applications. We also discuss the extension of this material engineering into the far infrared, and even the terahertz (THz) region.

  18. Fault tolerant photodiode and photogate active pixel sensors

    NASA Astrophysics Data System (ADS)

    Jung, Cory; Chapman, Glenn H.; La Haye, Michelle L.; Djaja, Sunjaya; Cheung, Desmond Y. H.; Lin, Henry; Loo, Edward; Audet, Yves R.

    2005-03-01

    As the pixel counts of digital imagers increase, the challenge of maintaining high yields and ensuring reliability over an imager"s lifetime increases. A fault tolerant active pixel sensor (APS) has been designed to meet this need by splitting an APS in half and operating both halves in parallel. The fault tolerant APS will perform normally in the no defect case and will produce approximately half the output for single defects. Thus, the entire signal can be recovered by multiplying the output by two. Since pixels containing multiple defects are rare, this design can correct for most defects allowing for higher production yields. Fault tolerant photodiode and photogate APS" were fabricated in 0.18-micron technology. Testing showed that the photodiode APS could correct for optically induced and electrically induced faults, within experimental error. The photogate APS was only tested for optically induced defects and also corrects for defects within experimental error. Further testing showed that the sensitivity of fault tolerant pixels was approximately 2-3 times more sensitive than the normal pixels. HSpice simulations of the fault tolerant APS circuit did not show increased sensitivity, however an equivalent normal APS circuit with twice width readout and row transistors was 1.90 times more sensitive than a normal pixel.

  19. Update on Linear Mode Photon Counting with the HgCdTe Linear Mode Avalanche Photodiode

    NASA Technical Reports Server (NTRS)

    Beck, Jeffrey D.; Kinch, Mike; Sun, Xiaoli

    2014-01-01

    The behavior of the gain-voltage characteristic of the mid-wavelength infrared cutoff HgCdTe linear mode avalanche photodiode (e-APD) is discussed both experimentally and theoretically as a function of the width of the multiplication region. Data are shown that demonstrate a strong dependence of the gain at a given bias voltage on the width of the n- gain region. Geometrical and fundamental theoretical models are examined to explain this behavior. The geometrical model takes into account the gain-dependent optical fill factor of the cylindrical APD. The theoretical model is based on the ballistic ionization model being developed for the HgCdTe APD. It is concluded that the fundamental theoretical explanation is the dominant effect. A model is developed that combines both the geometrical and fundamental effects. The model also takes into account the effect of the varying multiplication width in the low bias region of the gain-voltage curve. It is concluded that the lower than expected gain seen in the first 2 × 8 HgCdTe linear mode photon counting APD arrays, and higher excess noise factor, was very likely due to the larger than typical multiplication region length in the photon counting APD pixel design. The implications of these effects on device photon counting performance are discussed.

  20. Fast single photon avalanche photodiode-based time-resolved diffuse optical tomography scanner

    PubMed Central

    Mu, Ying; Niedre, Mark

    2015-01-01

    Resolution in diffuse optical tomography (DOT) is a persistent problem and is primarily limited by high degree of light scatter in biological tissue. We showed previously that the reduction in photon scatter between a source and detector pair at early time points following a laser pulse in time-resolved DOT is highly dependent on the temporal response of the instrument. To this end, we developed a new single-photon avalanche photodiode (SPAD) based time-resolved DOT scanner. This instrument uses an array of fast SPADs, a femto-second Titanium Sapphire laser and single photon counting electronics. In combination, the overall instrument temporal impulse response function width was 59 ps. In this paper, we report the design of this instrument and validate its operation in symmetrical and irregularly shaped optical phantoms of approximately small animal size. We were able to accurately reconstruct the size and position of up to 4 absorbing inclusions, with increasing image quality at earlier time windows. We attribute these results primarily to the rapid response time of our instrument. These data illustrate the potential utility of fast SPAD detectors in time-resolved DOT. PMID:26417526

  1. Flexible Photodiodes Based on Nitride Core/Shell p–n Junction Nanowires

    PubMed Central

    2016-01-01

    A flexible nitride p-n photodiode is demonstrated. The device consists of a composite nanowire/polymer membrane transferred onto a flexible substrate. The active element for light sensing is a vertical array of core/shell p–n junction nanowires containing InGaN/GaN quantum wells grown by MOVPE. Electron/hole generation and transport in core/shell nanowires are modeled within nonequilibrium Green function formalism showing a good agreement with experimental results. Fully flexible transparent contacts based on a silver nanowire network are used for device fabrication, which allows bending the detector to a few millimeter curvature radius without damage. The detector shows a photoresponse at wavelengths shorter than 430 nm with a peak responsivity of 0.096 A/W at 370 nm under zero bias. The operation speed for a 0.3 × 0.3 cm2 detector patch was tested between 4 Hz and 2 kHz. The −3 dB cutoff was found to be ∼35 Hz, which is faster than the operation speed for typical photoconductive detectors and which is compatible with UV monitoring applications. PMID:27615556

  2. Optimization of eyesafe avalanche photodiode lidar for automobile safety and autonomous navigation systems

    NASA Astrophysics Data System (ADS)

    Williams, George M.

    2017-03-01

    Newly emerging accident-reducing, driver-assistance, and autonomous-navigation technology for automobiles is based on real-time three-dimensional mapping and object detection, tracking, and classification using lidar sensors. Yet, the lack of lidar sensors suitable for meeting application requirements appreciably limits practical widespread use of lidar in trucking, public livery, consumer cars, and fleet automobiles. To address this need, a system-engineering perspective to eyesafe lidar-system design for high-level advanced driver-assistance sensor systems and a design trade study including 1.5-μm spot-scanned, line-scanned, and flash-lidar systems are presented. A cost-effective lidar instrument design is then proposed based on high-repetition-rate diode-pumped solid-state lasers and high-gain, low-excess-noise InGaAs avalanche photodiode receivers and focal plane arrays. Using probabilistic receiver-operating-characteristic analysis, derived from measured component performance, a compact lidar system is proposed that is capable of 220 m ranging with 5-cm accuracy, which can be readily scaled to a 360-deg field of regard.

  3. Update on Linear Mode Photon Counting with the HgCdTe Linear Mode Avalanche Photodiode

    NASA Technical Reports Server (NTRS)

    Beck, Jeffrey D.; Kinch, Mike; Sun, Xiaoli

    2014-01-01

    The behavior of the gain-voltage characteristic of the mid-wavelength infrared cutoff HgCdTe linear mode avalanche photodiode (e-APD) is discussed both experimentally and theoretically as a function of the width of the multiplication region. Data are shown that demonstrate a strong dependence of the gain at a given bias voltage on the width of the n- gain region. Geometrical and fundamental theoretical models are examined to explain this behavior. The geometrical model takes into account the gain-dependent optical fill factor of the cylindrical APD. The theoretical model is based on the ballistic ionization model being developed for the HgCdTe APD. It is concluded that the fundamental theoretical explanation is the dominant effect. A model is developed that combines both the geometrical and fundamental effects. The model also takes into account the effect of the varying multiplication width in the low bias region of the gain-voltage curve. It is concluded that the lower than expected gain seen in the first 2 × 8 HgCdTe linear mode photon counting APD arrays, and higher excess noise factor, was very likely due to the larger than typical multiplication region length in the photon counting APD pixel design. The implications of these effects on device photon counting performance are discussed.

  4. Solution-processed colloidal quantum dot photodiodes for low-cost SWIR imaging

    NASA Astrophysics Data System (ADS)

    Klem, Ethan J. D.; Lewis, Jay; Gregory, Christopher; Cunningham, Garry; Temple, Dorota

    2012-06-01

    While InGaAs-based focal plane arrays (FPAs) provide excellent detectivity and low noise for SWIR imaging applications, wider scale adoption of systems capable of working in this spectral range is limited by high costs, limited spectral response, and costly integration with Si ROIC devices. RTI has demonstrated a novel photodiode technology based on IR-absorbing solution-processed PbS colloidal quantum dots (CQD) that can overcome these limitations of InGaAs FPAs. We have fabricated devices with quantum efficiencies exceeding 50%, and detectivities that are competitive with that of InGaAs. Dark currents of ~2 nA/cm2 were measured at temperatures compatible with solid state coolers. Additionally, by processing these devices entirely at room temperature we find them to be compatible with monolithic integration onto readout ICs, thereby removing any limitation on device size. We will show early efforts towards demonstrating a direct integration of this sensor technology onto a Si ROIC IC and describe a path towards fabricating sensors sensitive from the visible to 2200 nm at a cost comparable to that of CMOS based devices. This combination of high performance, dramatic cost reduction, and multispectral sensitivity is ideally suited to expand the use of SWIR imaging in current applications, as well as to address applications which require a multispectral sensitivity not met by existing technologies.

  5. Magnetic arrays

    DOEpatents

    Trumper, D.L.; Kim, W.; Williams, M.E.

    1997-05-20

    Electromagnet arrays are disclosed which can provide selected field patterns in either two or three dimensions, and in particular, which can provide single-sided field patterns in two or three dimensions. These features are achieved by providing arrays which have current densities that vary in the windings both parallel to the array and in the direction of array thickness. 12 figs.

  6. Magnetic arrays

    SciTech Connect

    Trumper, David L.; Kim, Won-jong; Williams, Mark E.

    1997-05-20

    Electromagnet arrays which can provide selected field patterns in either two or three dimensions, and in particular, which can provide single-sided field patterns in two or three dimensions. These features are achieved by providing arrays which have current densities that vary in the windings both parallel to the array and in the direction of array thickness.

  7. Studies of Avalanche Photodiodes (APDS) as Readout Devices for Scintillating Fibers for High Energy Gamma-Ray Astronomy Telescopes

    NASA Technical Reports Server (NTRS)

    Vasile, Stefan; Shera, Suzanne; Shamo, Denis

    1998-01-01

    New gamma ray and charged particle telescope designs based on scintillating fiber arrays could provide low cost, high resolution, lightweight, very large area and multi radiation length instrumentation for planned NASA space exploration. The scintillating fibers low visible light output requires readout sensors with single photon detection sensitivity and low noise. The sensitivity of silicon Avalanche Photodiodes (APDS) matches well the spectral output of the scintillating fibers. Moreover, APDs have demonstrated single photon capability. The global aim of our work is to make available to NASA a novel optical detector concept to be used as scintillating fiber readouts and meeting the requirements of the new generations of space-borne gamma ray telescopes. We proposed to evaluate the feasibility of using RMD's small area APDs ((mu)APD) as scintillating fiber readouts and to study possible alternative (mu)APD array configurations for space borne readout scintillating fiber systems, requiring several hundred thousand to one million channels. The evaluation has been conducted in accordance with the task description and technical specifications detailed in the NASA solicitation "Studies of Avalanche Photodiodes (APD as readout devices for scintillating fibers for High Energy Gamma-Ray Astronomy Telescopes" (#8-W-7-ES-13672NAIS) posted on October 23, 1997. The feasibility study we propose builds on recent developments of silicon APD arrays and light concentrators advances at RMD, Inc. and on more than 5 years of expertise in scintillating fiber detectors. In a previous program we carried out the initial research to develop a high resolution, small pixel, solid-state, silicon APD array which exhibited very high sensitivity in the UV-VIS spectrum. This (mu)APD array is operated in Geiger mode and results in high gain (greater than 10(exp 8)), extremely low noise, single photon detection capability, low quiescent power (less than 10 (mu)W/pixel for 30 micrometers sensitive

  8. Absolute light and resolution measurements for sensitive CsI(Tl)/photodiode detectors

    NASA Astrophysics Data System (ADS)

    Meier, Michael M.

    2003-01-01

    To conserve volume and power, photodiode/scintillator combinations are strong candidates for gamma-ray detection in space applications. High sensitivity to MeV gamma rays necessitates large-volume scintillators, which are most effectively read out with large-area photodiodes. However, because photodiodes have unity gain, the electronic noise limits resolution, and therefore small-area photodiodes that minimize capacitance are preferred. Thus, optimization of resolution involves maximizing light production and transport in the scintillator and light collection in the photodiode, while minimizing photodiode area. Measurements of performance are reported for 1×1×1cm3/10×10mm2, 80cm3/18×18mm2, and 85cm3/10×10mm2 CsI(Tl)/photodiode combinations. Each large scintillator was a single crystal, machined to a geometry that comprised a 40mm diameter × 50mm height cylindrical section that was extended through a 20°conical section to a square face that matched the respective photodiode sensitive surface. Absolute scales were estimated for the light output by measuring the photodiode responses to 241Am (59.54keV), 57Co (122.06 and 136.47keV), and 133Ba (80.99keV) and assuming a value of 3.67eV/electron-hole pair. The photodiode quantum efficiencies for the CsI(Tl) emission spectrum, corrected for Si reflection back into the scintillator, was taken to be 0.835. We obtained values of 58.2, 46.7, and 34.6 photons/keV for the combined light production and transport into the CsI for the 1cm3, ~80cm3, and ~85cm3 detectors, respectively. The best measured resolutions at 662keVfor the detectors were 5.9%, 7.2%, and 7.4% FWHM, respectively.

  9. Linear charge coupled device detector array for imaging light propagating in an integrated thin-film optical waveguide

    NASA Technical Reports Server (NTRS)

    Chen, C. L.; Boyd, J. T.

    1976-01-01

    Device design, fabrication, and operation of a linear charge coupled device (CCD) detector array integrated with a thin film optical waveguide and applications of this structure to integrated optical signal processing and fiber optical communications were discussed. A two phase, overlapping-gate CCD is connected in parallel by means of a series of gates to an array of photodiodes. The photodiode provides an electrode free surface region so that a highly efficient waveguide detector coupling technique can be implemented. A thermally-oxidized layer of SiO2 forms an effective substrate for the optical waveguide.

  10. Development of high performance SWIR InGaAs focal plane array

    NASA Astrophysics Data System (ADS)

    Nagi, Richie; Bregman, Jeremy; Mizuno, Genki; Oduor, Patrick; Olah, Robert; Dutta, Achyut K.; Dhar, Nibir K.

    2015-05-01

    Banpil Photonics has developed a novel InGaAs based photodetector array for Short-Wave Infrared (SWIR) imaging, for the most demanding security, defense, and machine vision applications. These applications require low noise from both the detector and the readout integrated circuit arrays. In order to achieve high sensitivity, it is crucial to minimize the dark current generated by the photodiode array. This enables the sensor to function in extremely low light situations, which enables it to successfully exploit the benefits of the SWIR band. In addition to minimal dark current generation, it is essential to develop photodiode arrays with higher operating temperatures. This is critical for reducing the power consumption of the device, as less energy is spent in cooling down the focal plane array (in order to reduce the dark current). We at Banpil Photonics are designing, simulating, fabricating and testing SWIR InGaAs arrays, and have achieved low dark current density at room temperature. This paper describes Banpil's development of the photodetector array. We also highlight the fabrication technique used to reduce the amount of dark current generated by the photodiode array, in particular the surface leakage current. This technique involves the deposition of strongly negatively doped semiconductor material in the area between the pixels. This process reduces the number of dangling bonds present on the edges of each pixel, which prevents electrons from being swept across the surface of the pixels. This in turn drastically reduces the amount of surface leakage current at each pixel, which is a major contributor towards the total dark current. We present the optical and electrical characterization data, as well as the analysis that illustrates the dark current mechanisms. Also highlighted are the challenges and potential opportunities for further reduction of dark current, while maintaining other parameters of the photodiode array, such as size, weight, temperature

  11. Development of novel technologies to enhance performance and reliability of III-Nitride avalanche photodiodes

    NASA Astrophysics Data System (ADS)

    Suvarna, Puneet Harischandra

    Solar-blind ultraviolet avalanche photodiodes are an enabling technology for applications in the fields of astronomy, communication, missile warning systems, biological agent detection and particle physics research. Avalanche photodiodes (APDs) are capable of detecting low-intensity light with high quantum efficiency and signal-to-noise ratio without the need for external amplification. The properties of III-N materials (GaN and AlGaN) are promising for UV photodetectors that are highly efficient, radiation-hard and capable of visible-blind or solar-blind operation without the need for external filters. However, the realization of reliable and high performance III-N APDs and imaging arrays has several technological challenges. The high price and lack of availability of bulk III-N substrates necessitates the growth of III-Ns on lattice mismatched substrates leading to a high density of dislocations in the material that can cause high leakage currents, noise and premature breakdown in APDs. The etched sidewalls of III-N APDs and high electric fields at contact edges are also detrimental to APD performance and reliability. In this work, novel technologies have been developed and implemented that address the issues of performance and reliability in III-Nitride based APDs. To address the issue of extended defects in the bulk of the material, a novel pulsed MOCVD process was developed for the growth of AlGaN. This process enables growth of high crystal quality AlxGa1-xN with excellent control over composition, doping and thickness. The process has also been adapted for the growth of high quality III-N materials on silicon substrate for devices such as high electron mobility transistors (HEMTs). A novel post-growth defect isolation technique is also discussed that can isolate the impact of conductive defects from devices. A new sidewall passivation technique using atomic layer deposition (ALD) of dielectric materials was developed for III-N APDs that is effective in

  12. Maximum detection range limitation of pulse laser radar with Geiger-mode avalanche photodiode array

    NASA Astrophysics Data System (ADS)

    Luo, Hanjun; Xu, Benlian; Xu, Huigang; Chen, Jingbo; Fu, Yadan

    2015-05-01

    When designing and evaluating the performance of laser radar system, maximum detection range achievable is an essential parameter. The purpose of this paper is to propose a theoretical model of maximum detection range for simulating the Geiger-mode laser radar's ranging performance. Based on the laser radar equation and the requirement of the minimum acceptable detection probability, and assuming the primary electrons triggered by the echo photons obey Poisson statistics, the maximum range theoretical model is established. By using the system design parameters, the influence of five main factors, namely emitted pulse energy, noise, echo position, atmospheric attenuation coefficient, and target reflectivity on the maximum detection range are investigated. The results show that stronger emitted pulse energy, lower noise level, more front echo position in the range gate, higher atmospheric attenuation coefficient, and higher target reflectivity can result in greater maximum detection range. It is also shown that it's important to select the minimum acceptable detection probability, which is equivalent to the system signal-to-noise ratio for producing greater maximum detection range and lower false-alarm probability.

  13. Post-processing Free Quantum Random Number Generator Based on Avalanche Photodiode Array

    NASA Astrophysics Data System (ADS)

    Yang, Li; Sheng-Kai, Liao; Fu-Tian, Liang; Qi, Shen; Hao, Liang; Cheng-Zhi, Peng

    2016-03-01

    Not Available Supported by the Chinese Academy of Sciences Center for Excellence and Synergetic Innovation Center in Quantum Information and Quantum Physics, Shanghai Branch, University of Science and Technology of China, and the National Natural Science Foundation of China under Grant No 11405172.

  14. Si/Ge photodiodes for coherent and analog communication

    NASA Astrophysics Data System (ADS)

    Piels, Molly

    High-speed photodiodes have diverse applications in wireless and fiber communications. They can be used as output stages for antenna systems as well as receivers for fiber optic networks. Silicon is an attractive substrate material for photonic components for a number of reasons. Low cost manufacturing in CMOS fabrication facilities, low material loss at telecommunications wavelengths, and relatively simple co-packaging with electronics are all driving interest in silicon photonic devices. Since silicon does not absorb light at telecommunications wavelengths, photodetector fabrication requires the integration of either III-V materials or germanium. Recent work on germanium photodetectors has focused on low-capacitance devices suitable for integration with silicon electronics. These devices have excellent bandwidth and efficiency, but have not been designed for the levels of photocurrent required by coherent and analog systems. This thesis explores the design, fabrication, and measurement of photodetectors fabricated on silicon with germanium absorbing regions for high speed and high power performance. There are numerous design trade-offs between speed, efficiency, and output power. Designing for high bandwidth favors small devices for low capacitance. Small devices require abrupt absorption profiles for good efficiency, but design for high output power favors large devices with dilute absorption. The absorption profile can be controlled by the absorber layer thickness, but this will also affect the bandwidth and power handling. This work quantifies the trade-offs between high speed, high efficiency, and high power design. Intrinsic region thickness and absorption profile are identified as the most important design variables. For PIN structures, the absorption profile and intrinsic region thickness are both functions of the Ge thickness, but in uni-traveling carrier (UTC) structures the absorption profile and intrinsic region can be designed independently. This

  15. Application of cooled IR focal plane arrays in thermographic cameras

    NASA Astrophysics Data System (ADS)

    Vollheim, B.; Gaertner, M.; Dammass, G.; Krausz, M.

    2016-05-01

    The usage of cooled IR Focal Plane Array detectors in thermographic or radiometric thermal imaging cameras, respectively, leads to special demands on these detectors, which are discussed in this paper. For a radiometric calibration of wide temperature measuring ranges from -40 up to 2,000 °C, a linear and time-stable response of the photodiode array has to be ensured for low as well as high radiation intensities. The maximum detectable photon flux is limited by the allowed shift of the photodiode's bias that should remain in the linear part of the photodiode's I(V) curve even for the highest photocurrent. This limits the measurable highest object temperature in practice earlier than the minimum possible integration time. Higher temperature measuring ranges are realized by means of neutral or spectral filters. Defense and Security applications normally provide images at the given ambient temperature with small hot spots. The usage of radiometric thermal imagers for thermography often feature larger objects with a high temperature contrast to the background. This should not generate artifacts in the image, like pixel patterns or stripes. Further issues concern the clock regime or the sub-frame capabilities of the Read-Out-Circuit and the frame rate dependency of the signal. We will briefly describe the demands on the lens design for thermal imaging cameras when using cooled IR Focal Plane Array detectors with large apertures.

  16. Avalanche photodiode based time-of-flight mass spectrometry.

    PubMed

    Ogasawara, Keiichi; Livi, Stefano A; Desai, Mihir I; Ebert, Robert W; McComas, David J; Walther, Brandon C

    2015-08-01

    This study reports on the performance of Avalanche Photodiodes (APDs) as a timing detector for ion Time-of-Flight (TOF) mass spectroscopy. We found that the fast signal carrier speed in a reach-through type APD enables an extremely short timescale response with a mass or energy independent <2 ns rise time for <200 keV ions (1-40 AMU) under proper bias voltage operations. When combined with a microchannel plate to detect start electron signals from an ultra-thin carbon foil, the APD comprises a novel TOF system that successfully operates with a <0.8 ns intrinsic timing resolution even using commercial off-the-shelf constant-fraction discriminators. By replacing conventional total-energy detectors in the TOF-Energy system, APDs offer significant power and mass savings or an anti-coincidence background rejection capability in future space instrumentation.

  17. Avalanche photodiode based time-of-flight mass spectrometry

    NASA Astrophysics Data System (ADS)

    Ogasawara, Keiichi; Livi, Stefano A.; Desai, Mihir I.; Ebert, Robert W.; McComas, David J.; Walther, Brandon C.

    2015-08-01

    This study reports on the performance of Avalanche Photodiodes (APDs) as a timing detector for ion Time-of-Flight (TOF) mass spectroscopy. We found that the fast signal carrier speed in a reach-through type APD enables an extremely short timescale response with a mass or energy independent <2 ns rise time for <200 keV ions (1-40 AMU) under proper bias voltage operations. When combined with a microchannel plate to detect start electron signals from an ultra-thin carbon foil, the APD comprises a novel TOF system that successfully operates with a <0.8 ns intrinsic timing resolution even using commercial off-the-shelf constant-fraction discriminators. By replacing conventional total-energy detectors in the TOF-Energy system, APDs offer significant power and mass savings or an anti-coincidence background rejection capability in future space instrumentation.

  18. Systematic afterpulsing-estimation algorithms for gated avalanche photodiodes.

    PubMed

    Wiechers, Carlos; Ramírez-Alarcón, Roberto; Muñiz-Sánchez, Oscar R; Yépiz, Pablo Daniel; Arredondo-Santos, Alejandro; Hirsch, Jorge G; U'Ren, Alfred B

    2016-09-10

    We present a method designed to efficiently extract optical signals from InGaAs avalanche photodiodes (APDs) operated in gated mode. In particular, our method permits an estimation of the fraction of counts that actually results from the signal being measured, as opposed to being produced by noise mechanisms, specifically by afterpulsing. Our method in principle allows the use of InGaAs APDs at high detection efficiencies, with the full operation bandwidth, either with or without resorting to the application of a dead-time. As we show below, our method can be used in configurations where afterpulsing exceeds the genuine signal by orders of magnitude, even near saturation. The algorithms that we have developed are suitable to be used either in real-time processing of raw detection probabilities or in post-processing applications, after a calibration step has been performed. The algorithms that we propose here can complement technologies designed for the reduction of afterpulsing.

  19. Correcting for accidental correlations in saturated avalanche photodiodes.

    PubMed

    Grieve, J A; Chandrasekara, R; Tang, Z; Cheng, C; Ling, A

    2016-02-22

    In this paper we present a general method for estimating rates of accidental coincidence between a pair of single photon detectors operated within their saturation regimes. By folding the effects of recovery time of both detectors and the detection circuit into an "effective duty cycle" we are able to accomodate complex recovery behaviour at high event rates. As an example, we provide a detailed high-level model for the behaviour of passively quenched avalanche photodiodes, and demonstrate effective background subtraction at rates commonly associated with detector saturation. We show that by post-processing using the updated model, we observe an improvement in polarization correlation visibility from 88.7% to 96.9% in our experimental dataset. This technique will be useful in improving the signal-to-noise ratio in applications which depend on coincidence measurements, especially in situations where rapid changes in flux may cause detector saturation.

  20. Avalanche Photodiodes as Fast X-ray Detectors.

    PubMed

    Kishimoto, S

    1998-05-01

    An avalanche photodiode (APD) detector provides a sub-nanosecond time resolution and an output rate of more than 10(8) counts s(-1) of synchrotron X-rays. Moreover, the APD has the advantage of low noise. A review of recent developments of detectors using APD devices designed for X-ray experiments is presented in this paper. One of the detectors has an excellent time response of 100 ps resolution and a narrow width on its response function, 1.4 ns at 10(-5) maximum. The other consists of a stack of four diodes and has a transmission structure. The stacked detector improved the efficiency for X-rays, e.g. 55% at 16.53 keV. The output rates reached more than 10(8) counts s(-1) per device.

  1. Cesium hafnium chloride scintillator coupled with an avalanche photodiode photodetector

    NASA Astrophysics Data System (ADS)

    Kurosawa, S.; Kodama, S.; Yokota, Y.; Horiai, T.; Yamaji, A.; Shoji, Y.; Král, R.; Pejchal, J.; Ohashi, Y.; Kamada, K.; Nikl, M.; Yoshikawa, A.

    2017-02-01

    Optical and scintillation properties of pure Cs2HfCl6 (CHC) single crystals were investigated. In particular, light output and energy resolution were measured using a Si avalanche photodiode (Si-APD), since the Si-APD has sufficient quantum efficiency of around 70 % at emission wavelength region of CHC around 420 nm. This CHC single crystal grown using the vertical Bridgeman method showed light output of 37,000± 2,000 photons/MeV . The FWHM energy resolution was determined to be 3.7± 0.5× (E/662 keV)-0.85± 0.03[%], where E [keV] is the gamma-ray energy. Moreover, the temperature dependence of the light output was stable from -5 to 30 oC, while the light output increased below -10 oC.

  2. Photon-counting techniques with silicon avalanche photodiodes

    NASA Astrophysics Data System (ADS)

    Dautet, Henri; Deschamps, P.; Dion, Bruno; MacGregor, Andrew D.; MacSween, D.; McIntyre, Robert J.; Trottier, C.; Webb, Paul P.

    1993-05-01

    Silicon avalanche photodiodes (APD) have been used for photon counting for a number of years. This paper reviews their properties and the associated electronics required for photon counting in the Geiger mode. Significant improvements are reported in overall photon detection efficiencies (approaching 75% at 633 nm), and timing jitter (under 200 ps) achieved at high over-voltages (20 - 30 V). Results obtained using an active-mode fast quench circuit capable of switching over-voltages as high as 20 V (giving photon detection efficiencies in the 50% range), are reported with a dead-time of less than 50 ns. Larger diodes (up to 1 mm diameter), usable in the Geiger mode, which have quantum efficiencies over 80% in the 500 - 800 nm range also are reported.

  3. Temperature Control of Avalanche Photodiode Using Thermoelectric Cooler

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Luck, William S., Jr.; DeYoung, Russell J.

    1999-01-01

    Avalanche photodiodes (APDS) are quantum optical detectors that are used for visible and near infrared optical detection applications. Although APDs are compact, rugged, and have an internal gain mechanism that is suitable for low light intensity; their responsivity, and therefore their output, is strongly dependent on the device temperature. Thermoelectric coolers (TEC) offers a suitable solution to this problem. A TEC is a solid state cooling device, which can be controlled by changing its current. TECs are compact and rugged, and they can precisely control the temperature to within 0.1 C with more than a 150 C temperature gradient between its surfaces. In this Memorandum, a proportional integral (PI) temperature controller for APDs using a TEC is discussed. The controller is compact and can successfully cool the APD to almost 0 C in an ambient temperature environment of up to 27 C.

  4. High resolution, low energy avalanche photodiode X-ray detectors

    NASA Technical Reports Server (NTRS)

    Farrell, R.; Vanderpuye, K.; Entine, G.; Squillante, M. R.

    1991-01-01

    Silicon avalanche photodiodes have been fabricated, and their performance as X-ray detectors has been measured. Photon sensitivity and energy resolution were measured as a function of size and operating parameters. Noise thresholds as low as 212 eV were obtained at room temperature, and backscatter X-ray fluorescence data were obtained for aluminum and other light elements. It is concluded that the results with the X-ray detector are extremely encouraging, and the performance is challenging the best available proportional counters. While not at the performance level of either cryogenic silicon or HgI2, these device operate at room temperature and can be reproduced in large numbers and with much larger areas than typically achieved with HgI2. In addition, they are rugged and appear to be indefinitely stable.

  5. High resolution, low energy avalanche photodiode X-ray detectors

    NASA Technical Reports Server (NTRS)

    Farrell, R.; Vanderpuye, K.; Entine, G.; Squillante, M. R.

    1991-01-01

    Silicon avalanche photodiodes have been fabricated, and their performance as X-ray detectors has been measured. Photon sensitivity and energy resolution were measured as a function of size and operating parameters. Noise thresholds as low as 212 eV were obtained at room temperature, and backscatter X-ray fluorescence data were obtained for aluminum and other light elements. It is concluded that the results with the X-ray detector are extremely encouraging, and the performance is challenging the best available proportional counters. While not at the performance level of either cryogenic silicon or HgI2, these device operate at room temperature and can be reproduced in large numbers and with much larger areas than typically achieved with HgI2. In addition, they are rugged and appear to be indefinitely stable.

  6. Responsivity of Diamond X-ray Photodiodes Calibrated at NSLS

    SciTech Connect

    Keister,J.W.; Smedley, J.; Muller, E. M.; Bohon, J.

    2009-09-27

    Single crystal, high purity synthetic diamond is used as photoabsorption and carrier transport medium in x-ray photodiodes. While the thermal / mechanical robustness and high x-ray transmission of diamond make such devices attractive for synchrotron instrumentation, state-of-the-art quality material and electrical interfaces further make such detectors feasible. The present work develops methodology for attaining calculable responsivity (photocurrent yield) over a wide range of photon energies (0.2 to 28 keV) to within 5% accuracy. These methods achieve linear response for up to 0.2 W absorbed x-ray power and response time as low as 1 ns. Details of contact formation / robustness and bias configuration are explored.

  7. Avalanche photodiode based time-of-flight mass spectrometry

    SciTech Connect

    Ogasawara, Keiichi Livi, Stefano A.; Desai, Mihir I.; Ebert, Robert W.; McComas, David J.; Walther, Brandon C.

    2015-08-15

    This study reports on the performance of Avalanche Photodiodes (APDs) as a timing detector for ion Time-of-Flight (TOF) mass spectroscopy. We found that the fast signal carrier speed in a reach-through type APD enables an extremely short timescale response with a mass or energy independent <2 ns rise time for <200 keV ions (1−40 AMU) under proper bias voltage operations. When combined with a microchannel plate to detect start electron signals from an ultra-thin carbon foil, the APD comprises a novel TOF system that successfully operates with a <0.8 ns intrinsic timing resolution even using commercial off-the-shelf constant-fraction discriminators. By replacing conventional total-energy detectors in the TOF-Energy system, APDs offer significant power and mass savings or an anti-coincidence background rejection capability in future space instrumentation.

  8. Innovative Detection System of Ochratoxin A by Thin Film Photodiodes

    PubMed Central

    Caputo, Domenico; de Cesare, Giampiero; Fanelli, Corrado; Nascetti, Augusto; Ricelli, Alessandra; Scipinotti, Riccardo

    2007-01-01

    In this work we present, for the first time, a rapid, compact and innovative method for detection of Ochratoxin A (OTA) based on hydrogenated amorphous silicon (a-Si:H) sensors. 2 μl of acidified toluene containing OTA at different concentrations were spotted on the silica side of a High Performance Thin Layer Cromatography plate and aligned with a a-Si:H p-i-n photodiode deposited by Plasma Enhanced Chemical Vapor Deposition on a different glass substrate. As an UV radiation excites the mycotoxin, the re-emitted light is detected by the a-Si:H sensor. Results show a very good linearity between OTA concentration and the sensor photocurrent over almost three orders of magnitude. The minimum detected OTA concentration is equal to 0.1ng, showing that the presented system has the potential for a low cost system suitable for the early detection of toxins in foods.

  9. Feedback in close-coupled axial VCSEL-photodiode pairs

    NASA Astrophysics Data System (ADS)

    Geib, Kent M.; Serkland, Darwin K.; Peake, Gregory M.; Sanchez, Victoria M.

    2011-03-01

    We have been investigating the use of coaxial multimode VCSEL/PD (vertical cavity surface emitting laser/photodiode) pairs for positional sensing with emitter to target mirror distances on the order of 1mm. We have observed large variations in signal levels due to the strong optical feedback in these close-coupled systems, employing either heterogeneously integrated commercial components or our own monolithically integrated devices. The feedback effect is larger than anticipated due to the annular geometry of the photodetector. Even though there is very little change in the measured VCSEL total output power, the optical feedback induces variations in the transverse mode distributions in these multimode VCSELs. The higher order modes have a larger divergence angle resulting in changes in the reflected light power incident upon the active detector area for a large range of emitter/mirror separations. We will review the experimental details and provide strategies for avoiding these variations in detected power.

  10. Comprehensive analysis of new near-infrared avalanche photodiode structure

    NASA Astrophysics Data System (ADS)

    Czuba, Krzysztof; Jurenczyk, Jaroslaw; Kaniewski, Janusz

    2014-01-01

    The essential steps in simulations of modern separate absorption, grading, charge, and multiplication avalanche photodiode and their results are discussed. All simulations were performed using two commercial technology computer-aided design type software packages, namely Silvaco ATLAS and Crosslight APSYS. Comparison between those two frameworks was made and differences between them were pointed out. Several examples of the influence of changes made in individual layers on overall device characteristics have been shown. Proper selection of models and their parameters as well as its significance on results has been illustrated. Additionally, default values of material parameters were revised and adequate values from the literature were entered. Simulated characteristics of optimized structure were compared with ones obtained from measurements of real devices (e.g., current-voltage curves). Finally, properties of crucial layers in the structure were discussed.

  11. Evaluation of high quantum efficiency silicon photodiodes for calibration in the 400 nm to 900 nm spectral region

    NASA Technical Reports Server (NTRS)

    Jorquera, Carlos; Bruegge, Carol; Duval, Valerie

    1992-01-01

    The reflectance and internal quantum efficiency (QE) of three single-element photodiodes are determined using two different light-trapping devices. The QED-200 light trapping device which is based on inversion layer photodiodes exhibits the best performance within the short wavelengths of the visible spectrum (VIS), while the A-O device based on p-n photodiodes, performs best in the long wave VIS up to 950 nm. The combination of the two light-traps provides nearly 100 percent external QE coverage from 400 to 950 nm. The reflectances and internal QE were determined within this spectral range for three photodiodes: UV100, an inversion layer photodiode; X-UV100, a shallow diffused n-p photodiode; and 10DPI/SB, a blue-enhanced p-n photodiode.

  12. Kokkos Array

    SciTech Connect

    Edwards Daniel Sunderland, Harold Carter

    2012-09-12

    The Kokkos Array library implements shared-memory array data structures and parallel task dispatch interfaces for data-parallel computational kernels that are performance-portable to multicore-CPU and manycore-accelerator (e.g., GPGPU) devices.

  13. Ultra-low noise single-photon detector based on Si avalanche photodiode.

    PubMed

    Kim, Yong-Su; Jeong, Youn-Chang; Sauge, Sebastien; Makarov, Vadim; Kim, Yoon-Ho

    2011-09-01

    We report operation and characterization of a lab-assembled single-photon detector based on commercial silicon avalanche photodiodes (PerkinElmer C30902SH, C30921SH). Dark count rate as low as 5 Hz was achieved by cooling the photodiodes down to -80 °C. While afterpulsing increased as the photodiode temperature was decreased, total afterpulse probability did not become significant due to detector's relatively long deadtime in a passively-quenched scheme. We measured photon detection efficiency >50% at 806 nm. © 2011 American Institute of Physics

  14. Improving an organic photodiode by incorporating a tunnel barrier between the donor and acceptor layers

    NASA Astrophysics Data System (ADS)

    Campbell, I. H.; Crone, B. K.

    2012-07-01

    We demonstrate increased photocurrent quantum efficiency in a model donor/acceptor (tetracene/C60) photodiode by incorporating an insulating tunnel barrier between the tetracene and C60 layers. Photodiode efficiency results from the interplay of a number of processes which add to or subtract from the overall device efficiency. The positive rates are those of exciton dissociation and charge separation, the negative rates include exciton and charge transfer complex recombination. We show that by introducing a thin insulating layer between the donor and acceptor layers in a photodiode, we can modify the exciton dissociation and charge transfer complex recombination rates and improve device performance.

  15. Nanocylinder arrays

    DOEpatents

    Tuominen, Mark; Schotter, Joerg; Thurn-Albrecht, Thomas; Russell, Thomas P.

    2007-03-13

    Pathways to rapid and reliable fabrication of nanocylinder arrays are provided. Simple methods are described for the production of well-ordered arrays of nanopores, nanowires, and other materials. This is accomplished by orienting copolymer films and removing a component from the film to produce nanopores, that in turn, can be filled with materials to produce the arrays. The resulting arrays can be used to produce nanoscale media, devices, and systems.

  16. Nanocylinder arrays

    DOEpatents

    Tuominen, Mark; Schotter, Joerg; Thurn-Albrecht, Thomas; Russell, Thomas P.

    2009-08-11

    Pathways to rapid and reliable fabrication of nanocylinder arrays are provided. Simple methods are described for the production of well-ordered arrays of nanopores, nanowires, and other materials. This is accomplished by orienting copolymer films and removing a component from the film to produce nanopores, that in turn, can be filled with materials to produce the arrays. The resulting arrays can be used to produce nanoscale media, devices, and systems.

  17. Application of visible linear array technology to earth observation sensors

    NASA Technical Reports Server (NTRS)

    Noll, R. E.; Tracy, R. A.

    1975-01-01

    The present paper identifies the systems engineering aspects of applying solid-state technology to earth observations applications being traditionally performed by point (or multiple-point) detector line scanned mechanisms. It is shown that the translation from a basically serial data flow point-detector mechanically-scanned sensor to a solid state highly parallel linear-array pushbroom sensor results in minimizing mechanical complexity and maximizing electronics complexity, with increased demands upon optical performance in some applications. Technical aspects relevant to highly parallel photodiode linear-array pushbroom applications are discussed. Examples of systems engineering applications are provided.

  18. Characterization of silicon avalanche photodiodes for photon correlation measurements. 2: Active quenching.

    PubMed

    Brown, R G; Jones, R; Rarity, J G; Ridley, K D

    1987-06-15

    We continue examination of the photon correlation properties of silicon avalanche photodiodes operated in photon-counting mode by extending their operation from that of passive quenching(1) to active quenching, yielding shorter dead time and higher frequency operation.

  19. Characterization of a Photodiode Coupled with a Si Nanowire-FET on a Plastic Substrate

    PubMed Central

    Kwak, Kiyeol; Cho, Kyoungah; Kim, Sangsig

    2010-01-01

    In this study, a laterally coupled device composed of a photodiode and a Si nanowires-field-effect transistor (NWs-FET) is constructed on a plastic substrate and the coupled device is characterized. The photodiode is made of p-type Si NWs and an n-type ZnO film. The Si NWs-FET is connected electrically to the photodiode in order to enhance the latter’s photocurrent efficiency by adjusting the gate voltage of the FET. When the FET is switched on by biasing a gate voltage of −9 V, the photocurrent efficiency of the photodiode is three times higher than that when the FET is switched off by biasing a gate voltage of 0 V. PMID:22163398

  20. Low-noise extended-frequency response with cooled silicon photodiodes.

    PubMed

    Neiswander, R S; Plews, G S

    1975-11-01

    With appropriate preamplifier design and cooled silicon photodiode and input field effect transistor, broad frequency bandwidth (e.g., 0.01 Hz to 100 kHz) performance comparable or better than that of photon noise limited photomultipliers can be achieved. The FET input preamplifier is operated current mode with a large feedback resistance. Consequent limited frequency response of the preamplifier is compensated by treble boosting at the postamplifier. Cooling the photodiode and input FET to 200 K eliminates photodiode dark current and FET gate reverse current shot noises as significant contributors. Remaining noise sources are FET voltage noise, minimized by small input capacitances, and feedback and FET load resistances Johnson noise. At an output SNR of 10, for example, the internal noise and the photon noise are about the same level. Thus the performance gain attributable to the photodiode's high quantum efficiency can be significant.

  1. Optical AND and NOT gates at 40 Gbps using electro-absorption modulator/photodiode pairs.

    SciTech Connect

    Tauke-Pedretti, Anna; Overberg, Mark E.; Skogen, Erik J.; Alford, Charles Fred; Sullivan, Charles Thomas; Vawter, Gregory Allen; Peake, Gregory Merwin; Torres, David L.

    2010-06-01

    We demonstrate an optical gate architecture using electro-absorption modulator/photodiode pairs to perform AND and NOT functions. Optical bandwidth for both gates reach 40 GHz. Also shown are AND gate waveforms at 40 Gbps.

  2. PiN photodiode performance comparison for dosimetry in radiology applications.

    PubMed

    Oliveira, Charles N P; Khoury, Helen J; Santos, Edval J P

    2016-12-01

    Performance comparison of selected photodiodes for usage as radiation detectors for radio-protection is presented. In this study, based on the criteria of minimum sensitive area of 5mm(2), minimum half angle 60° and low cost, four commercial photodiodes are selected for evaluation: SFH205, SFH206, BPW34, and BPX90F. Photodiodes are low cost, small volume and lightweight detectors. As an electronic transducer, photodiode detector is an attractive approach for the development of low power portable electronic dosimeter for direct-reading real-time radiation dose measurement. The devices have been studied with respect to sensitivity (efficiency) in X-rays and gamma rays detection, repeatability and linearity in air kerma.

  3. A novel PIN photodetector with double linear arrays for rainfall prediction

    NASA Astrophysics Data System (ADS)

    Yan, Yao; Xiong, Liu; Li, Yuan; Zhaohua, Zhang; Tianling, Ren

    2015-09-01

    A novel PIN (positive-intrinsic-negative) photodetector with double linear arrays that can be used to measure the diameter of precipitation particles and the space between two droplets in clouds is proposed. The sensitive unit is the PIN photodiode. The chip with a size of 10 × 8 mm2 has 128 photodiodes, and each row has 64 photodiodes. The device design, fabrication process and package are introduced in the paper. The photocurrent of the packaged chip was systematically tested with a red laser. Also the diameter of one water drop and the space between two water drops were measured. The minimum raindrop diameter which can be tested in this paper is 100 μm. This device can be useful for rainfall prediction. Project supported by the National Natural Science Foundation of China (No. 61434001) and the ‘Thousands Talents’ Program for Pioneer Researchers and Its Innovation Team, China.

  4. Characterization of novel Hamamatsu Multi Pixel Photon Counter (MPPC) arrays for the GlueX experiment

    NASA Astrophysics Data System (ADS)

    Soto, Orlando; Rojas, Rimsky; Kuleshov, Sergey; Hakobyan, Hayk; Toro, Alam; Brooks, William K.

    2013-12-01

    The novel Hamamatsu Multi Pixel Photon Counter Array S12045(X) is an array of 16 individual MPPCs (3×3 mm2) (further in the paper MPPC array channel) each with 3600 G-APD (Geiger-mode Avalanche Photodiodes) pixels (50×50 [μm2]). Each MPPC in the array works with its individual reverse bias voltage mode (around 70 V). The paper summarizes the characterization process of MPPC arrays used in GlueX experiment (Hall D, Jefferson Lab). We studied the main features of each MPPC array channel for 2800 MPPC arrays at different temperatures. Two measurement stations were built to extract gain, breakdown voltage, photo detection efficiency (PDE), optical crosstalk and dark rate for each MPPC array channel. The hardware and the data analysis are described, which includes new analytical expressions to obtain the mean number of photo-electrons and optical crosstalk. The dynamical behavior of characterization parameters is presented as well.

  5. Characterization of novel Hamamatsu Multi Pixel Photon Counter (MPPC) arrays for the GlueX experiment

    SciTech Connect

    Soto, Orlando; Rojas, Rimsky; Kuleshov, Sergey V.; Hakobyan, Hayk; Toro, Alam; Brooks, William K.

    2013-12-01

    The novel Hamamatsu Multi Pixel Photon Counter Array S12045(X) is an array of 16 individual MPPCs (3x3 mm{sup 2}) (further in the paper MPPC array channel) each with 3600 G-APD (Geiger-mode Avalanche Photodiodes) pixels (50x50 [{micro}m{sup 2}]). Each MPPC in the array works with its individual reverse bias voltage mode (around 70 V). The paper summarizes the characterization process of MPPC arrays used in GlueX experiment (Hall D, Jefferson Lab). We studied the main features of each MPPC array channel for 2800 MPPC arrays at different temperatures. Two measurement stations were built to extract gain, breakdown voltage, photo detection efficiency (PDE), optical crosstalk and dark rate for each MPPC array channel. The hardware and the data analysis are described, which includes new analytical expressions to obtain the mean number of photo-electrons and optical crosstalk. The dynamical behavior of characterization parameters is presented as well.

  6. Epitaxially-grown Ge/Si avalanche photodiodes for 1.3 microm light detection.

    PubMed

    Kang, Y; Zadka, M; Litski, S; Sarid, G; Morse, M; Paniccia, M J; Kuo, Y-H; Bowers, J; Beling, A; Liu, H D; McIntosh, D C; Campbell, J; Pauchard, A

    2008-06-23

    We designed and fabricated Ge/Si avalanche photodiodes grown on silicon substrates. The mesa-type photodiodes exhibit a responsivity at 1310 nm of 0.54 A/W, a breakdown voltage thermal coefficient of 0.05%/ degrees C, a 3 dB-bandwidth of 10 GHz. The gain-bandwidth product was measured as 153 GHz. The effective k value extracted from the excess noise factor was 0.1.

  7. High-power high-linearity flip-chip bonded modified uni-traveling carrier photodiode.

    PubMed

    Li, Zhi; Fu, Yang; Piels, Molly; Pan, Huapu; Beling, Andreas; Bowers, John E; Campbell, Joe C

    2011-12-12

    We demonstrate a flip-chip bonded modified uni-traveling carrier (MUTC) photodiode with an RF output power of 0.75 W (28.8 dBm) at 15 GHz and OIP3 as high as 59 dBm. The photodiode has a responsivity of 0.7 A/W, 3-dB bandwidth > 15 GHz, and saturation photocurrent > 180 mA at 11 V reverse bias.

  8. State-of-the-art MCT photodiodes for cutting-edge sensor applications by AIM

    NASA Astrophysics Data System (ADS)

    Figgemeier, H.; Hanna, S.; Eich, D.; Fries, P.; Mahlein, K.-M.; Wenisch, J.; Schirmacher, W.; Beetz, J.; Breiter, R.

    2017-02-01

    For about 30 years, AIM has been ranking among the leading global suppliers for high-performance MCT infrared detectors, with its portfolio spanning the photosensitivity cut-off range from the SWIR to the VLWIR and from 1st generation to 3rd generation FPA devices. To meet the market demands for SWaP-C- and IR-detectors with additional functionalities such as multicolor detection, AIM employs both LPE and MBE technology. From AIḾs line of highest-performance single color detectors fabricated by LPE, we will present our latest excellent results of 5.3 μm cut-off MWIR MCT detectors with 1024x768 pixels and a 10 μm pixel pitch. AIM's powerful low dark current LWIR and VLWIR p-on-n device technology on LPE-grown MCT has now been extended to the MWIR spectral range. A comparison of results from n-on-p and p-on-n MWIR MCT planar photodiode arrays is presented. Operating temperatures of 160 K and higher, in conjunction with low defect density and excellent thermal sensitivity (NETD) are attained. The results achieved for LPE MWIR are compared to MBE MWIR data. For both the cost-efficient production of MWIR single color MCT detectors, as well as 3rd generation multicolor MCT detectors, AIM makes use of MBE growth of MCT on large-area GaAs substrates. The now-available AIM MWIR single color MBE MCT detectors grown on GaAs are qualified, delivered, and have reached a maturity fully meeting customers' requirements. Representing AIM's multicolor detector development, latest test results on a 640x512 pixels with a 20 μm pitch design will be presented. The MWIR/MWIR diodes demonstrate high QE, very low color cross talk, and excellent NETD in conjunction with low defect densities.

  9. Modeling of InGaAs/InAlAs/InP avalanche photodiodes with undepleted absorber

    NASA Astrophysics Data System (ADS)

    Kaniewski, Janusz; Jurenczyk, Jaroslaw; Zak, Dariusz; Muszalski, Jan

    2012-01-01

    For high-bit rate and long-haul receivers in optical telecommunication systems the avalanche photodiodes are preferred since they offer an improvement of the receiver sensitivity by several decibels. Recently critical sensing and imaging applications stimulated development of modified avalanche photodiodes structures operating in 1.55 μm spectral range. For these devices speed is not further critical. Instead, very low current densities and low multiplication noises are the main requirements. The most advanced structure of avalanche photodiodes is known as Separate Absorption, Grading, Charge and Multiplication (SAGCM). In the present work the performance of uncooled InGaAs/InAlAs/InP avalanche photodiodes operating near 1.55 μm has been studied theoretically. Device modeling based on advanced drift - diffusion model with commercial Crosslight APSYS software has been performed. Conventional SAGCM avalanche photodiodes as well as devices with a relatively thick undepleted p-type InGaAs absorption region and thin InAlAs multiplication layer have been considered. This type of avalanche photodiodes enables to increase device quantum efficiency, reduce dark current and eliminate impact ionization processes within absorbing layer. Extensive calculations allowed for detailed analysis of individual regions of the device and determination of their influence on diode characteristics.

  10. Numerical analysis of the temperature field in silicon avalanche photodiode by millisecond laser irradiation

    NASA Astrophysics Data System (ADS)

    Wang, Di; Jin, Guangyong; Wei, Zhi; Zhao, Hongyu

    2016-10-01

    Recent years, millisecond laser become a research hotspot. Avalanche photodiode (APD) based on silicon structure has excellent characteristics such as low noise and high-sensitivity. It is key components in receives for long-haul high-bit-rate optical communication system. The failure mechanism of silicon APD remains quite unknown, although some silicon p-i-n photodiode failure modes have been speculated. The COMSOL Multiphysics finite element analysis software was utilized in this paper. And the 2D model, which based on heat conduction equation, was established to simulate the temperature field of the silicon avalanche photodiode irradiated by millisecond laser. The model presented in the following section is a work which considers only melting of silicon by a millisecond laser pulse. The temperature dependences of material properties are taken into account, which has a great influence on the temperature fields indicated by the numerical results. The pulsed laser-induced transient temperature fields in silicon avalanche photodiode are obtained, which will be useful in the research on the mechanism of interactions between millisecond laser and photodiode. The evolution of temperature at the central point of the top surface, the temperature distribution along the radial direction in the end of laser irradiation and the temperature distribution along the axial direction in the end of laser irradiation were considered. Meanwhile, the fluence threshold value was obtained through the model. The conclusions had a reference value for revealing the mechanism of interactions between millisecond laser and the silicon avalanche photodiode.

  11. Heterogeneously integrated waveguide-coupled photodiodes on silicon-on-diamond (SOD)

    NASA Astrophysics Data System (ADS)

    Xie, Xiaojun; Ramaswamy, Anand; Shen, Yang; Yang, Zhanyu; Jacob-Mitos, Matt; Wang, Ye; Zang, Jizhao; Norberg, Erik; Fish, Greg; Campbell, Joe C.; Beling, Andreas

    2016-09-01

    We report on InP-based high power modified uni-traveling carrier (MUTC) photodiodes heterogeneously integrated on silicon on diamond (SOD) waveguides. Typical dark currents of MUTC photodiodes on SOD waveguides are 20 nA at - 5 V bias voltage. A 50-μm long photodiode has an internal responsivity of 1.07 A/W at 1550 nm wavelength. The bandwidths of photodiodes with active areas of 14×25 μm2, 14×50 μm2, 14×100 μm2 and 14×150 μm2 are 22 GHz, 16 GHz, 10 GHz and 7 GHz, respectively. The maximum output RF powers of 14×100 μm2 photodiodes are 13 dBm, 14.4 dBm and 15.3 dBm at 10 GHz, respectively. The maximum DC dissipated power is 0.67 W. To our knowledge, this is the first demonstration of III-V photodiodes integrated on SOD waveguides.

  12. Development of printed ITO coatings on PET and PEN foil for flexible organic photodiodes

    NASA Astrophysics Data System (ADS)

    Heusing, S.; Oliveira, P. W.; Kraker, E.; Haase, A.; Palfinger, C.; Veith, M.

    2008-04-01

    ITO (tin doped indium oxide) coatings with a sheet resistance of 2 to 3 kΩ(square) were produced by gravure printing process on PET and PEN foil. The printing paste consisted of ITO nanoparticles which were dispersed in a solvent by using a surfactant. The dispersion was mixed with a binder and a photo initiator before printing. The printed films were hardened under UV-irradiation at low temperatures (< 130°C). The sheet resistance could be decreased by heat treatment at 120°C under forming gas atmosphere (N II/H II) to 1.5 kΩ(square). The transmission of the ITO coated PET and PEN foils is more than 80 % in the visible range. The ITO films were directly used as the bottom electrode in an organic photodiode (OPD). The setup of the OPD originates from the well known Tang photodiode, consisting of a stacked layer of copper phthalocyanine (p-type material) and perylene tetracarboxylic bisbenzimidazole (n-type material). The photodiodes are characterised via current-voltage (I-V) characteristics. The performance of the photodiodes with printed ITO on plastic substrates could be improved by the deposition of a PEDOT/PSS layer (Baytron (R) P) on the ITO coated foils and was then comparable to the performance of photodiodes with semi-transparent gold as anode on PET substrates. These results demonstrate the suitability of the printed ITO layers as anode for organic photodiodes.

  13. High quantum efficiency annular backside silicon photodiodes for reflectance pulse oximetry in wearable wireless body sensors

    NASA Astrophysics Data System (ADS)

    Duun, Sune; Haahr, Rasmus G.; Hansen, Ole; Birkelund, Karen; Thomsen, Erik V.

    2010-07-01

    The development of annular photodiodes for use in a reflectance pulse oximetry sensor is presented. Wearable and wireless body sensor systems for long-term monitoring require sensors that minimize power consumption. We have fabricated large area 2D ring-shaped silicon photodiodes optimized for minimizing the optical power needed in reflectance pulse oximetry. To simplify packaging, backside photodiodes are made which are compatible with assembly using surface mounting technology without pre-packaging. Quantum efficiencies up to 95% and area-specific noise equivalent powers down to 30 fW Hz-1/2 cm-1 are achieved. The photodiodes are incorporated into a wireless pulse oximetry sensor system embedded in an adhesive patch presented elsewhere as 'The Electronic Patch'. The annular photodiodes are fabricated using two masked diffusions of first boron and subsequently phosphor. The surface is passivated with a layer of silicon nitride also serving as an optical filter. As the final process, after metallization, a hole in the center of the photodiode is etched using deep reactive ion etch.

  14. Downsampling Photodetector Array with Windowing

    NASA Technical Reports Server (NTRS)

    Patawaran, Ferze D.; Farr, William H.; Nguyen, Danh H.; Quirk, Kevin J.; Sahasrabudhe, Adit

    2012-01-01

    In a photon counting detector array, each pixel in the array produces an electrical pulse when an incident photon on that pixel is detected. Detection and demodulation of an optical communication signal that modulated the intensity of the optical signal requires counting the number of photon arrivals over a given interval. As the size of photon counting photodetector arrays increases, parallel processing of all the pixels exceeds the resources available in current application-specific integrated circuit (ASIC) and gate array (GA) technology; the desire for a high fill factor in avalanche photodiode (APD) detector arrays also precludes this. Through the use of downsampling and windowing portions of the detector array, the processing is distributed between the ASIC and GA. This allows demodulation of the optical communication signal incident on a large photon counting detector array, as well as providing architecture amenable to algorithmic changes. The detector array readout ASIC functions as a parallel-to-serial converter, serializing the photodetector array output for subsequent processing. Additional downsampling functionality for each pixel is added to this ASIC. Due to the large number of pixels in the array, the readout time of the entire photodetector is greater than the time between photon arrivals; therefore, a downsampling pre-processing step is done in order to increase the time allowed for the readout to occur. Each pixel drives a small counter that is incremented at every detected photon arrival or, equivalently, the charge in a storage capacitor is incremented. At the end of a user-configurable counting period (calculated independently from the ASIC), the counters are sampled and cleared. This downsampled photon count information is then sent one counter word at a time to the GA. For a large array, processing even the downsampled pixel counts exceeds the capabilities of the GA. Windowing of the array, whereby several subsets of pixels are designated

  15. High Response in a Tellurium-Supersaturated Silicon Photodiode

    NASA Astrophysics Data System (ADS)

    Wang, Xi-Yuan; Huang, Yong-Guang; Liu, De-Wei; Zhu, Xiao-Ning; Zhu, Hong-Liang

    2013-03-01

    Single crystalline silicon supersaturated with tellurium are formed by ion implantation followed by excimer nanosecond pulsed laser melting (PLM). The lattice damaged by ion implantation is restored during the PLM process, and dopants are effectively activated. The hyperdoped layer exhibits high and broad optical absorption from 400 to 2500nm. The n+ p photodiodes fabricated from these materials show high response (6.9A/W at 1000nm) with reverse bias 12 V at room temperature. The corresponding cut-off wavelength is 1258nm. The amount of gain and extended cut-off wavelength both increase with increasing reverse bias voltage; above 100% external quantum efficiency is observed even at a reverse bias of 1 V. The cut-off wavelength with 0 V bias is shorter than the commercial silicon detector. This implies that the Burstein-Moss shift is due to hyperdoping. The amount of the extended cut-off wavelength increases with increasing reverse bias voltage, suggesting existence of the Franz—Keldysh effect.

  16. Spectral correction of silicon photodiode solar radiation detectors

    SciTech Connect

    Zhou, C.; Michalsky, J.

    1994-12-31

    The multi-filter rotating shadowband radiometer (MFRSR) is a ground- based instrument that uses a silicon photodiode sensor to measure shortwave global and diffuse horizontal irradiance from which direct normal irradiance is calculated. Besides this multiplexing advantage, silicon sensors are rugged, stable and have a fast time response. On the other hand, silicon sensors are both thermally and spectrally sensitive. They, as do all pyranometric sensors, have an imperfect cosine response, especially at high solar-zenith angles. In the MFRSR two of these problems are solved. The MFRSR`s cosine response is measured and corrected. An automatic heater maintains the MFRSR detector at a constant temperature near 40 {degree}C. This paper describes a correction scheme, based on sky conditions, to account for the remaining spectral bias. The data base for these corrections was collected in Albany, New York, during 1993. The MFRSR and WMO firstclass thermopile instruments were sampled every 15 seconds and 5- minute averages were compared. The differences in time response between silicon and thermopile instruments contributes substantially to the remaining root-mean-square error reported.

  17. Simulation of infrared avalanche photodiodes from first principles

    NASA Astrophysics Data System (ADS)

    Storebø, Asta Katrine; Goldar, Dara; Brudevoll, Trond

    2017-02-01

    The present article deals with device physics and modeling of an Hg0.28Cd0.72Te wide-area electron-initiated avalanche photodiode, with main input data extracted from first principles electronic structure codes. Due to the large dimensions of 30 μm x 30 μm x 11 μm a method which combines Monte Carlo transport simulation in the active multiplication layer with `weak conduction' modeling in the charge carrier exit paths is introduced. Consequences resulting from adding perturbative, non-self-consistent small-signal analyses upon a self-consistent, large-signal background bias simulation are briefly examined. Likewise, the issue of ambipolar versus independent electron-hole transport in the absorption layer is discussed. We investigate the effects of alloy scattering on avalanche gain and compare alloy scattering rates used in some recent studies. Alloy scattering is for this particular device and model shown to increase the gain by more than an order of magnitude at typical bias voltages.

  18. New gamma detector modules based on micropixel avalanche photodiode

    NASA Astrophysics Data System (ADS)

    Ahmadov, F.; Ahmadov, G.; Guliyev, E.; Madatov, R.; Sadigov, A.; Sadygov, Z.; Suleymanov, S.; Akberov, R.; Nuriyev, S.; Zerrouk, F.

    2017-01-01

    In this paper presented the results of the ionizing radiation detector modules, which developed on the basis of a new generation of micropixel avalanche photodiode (MAPD) of MAPD-3NK type. The samples were produced in cooperation with the Zecotek Photonics and characterized by the following parameters: sensitive area—3.7 mm × 3.7 mm, density of pixels—10000 pixels/mm2, photon detection efficiency—35-40% (at wavelength of 450-550 nm) and operation voltage—91 V. The beta particle and gamma ray detection performance of MAPD with different single scintillation crystal such as NaI, LFS and p-terphenyl was investigated. The gamma ray detector modules demonstrated a perfect linear behavior of detected signal amplitudes as a function of the gamma ray energy (from 26.3 keV up to 1.33 MeV). Energy resolution for 662 keV gamma rays was 11.2% and the minimum detectable energy was 26.3 keV.

  19. Avalanche photodiodes and quenching circuits for single-photon detection

    NASA Astrophysics Data System (ADS)

    Cova, S.; Ghioni, M.; Lacaita, A.; Samori, C.; Zappa, F.

    1996-04-01

    Avalanche photodiodes, which operate above the breakdown voltage in Geiger mode connected with avalanche-quenching circuits, can be used to detect single photons and are therefore called single-photon avalanche diodes SPAD's. Circuit configurations suitable for this operation mode are critically analyzed and their relative merits in photon counting and timing applications are assessed. Simple passive-quenching circuits (PQC's), which are useful for SPAD device testing and selection, have fairly limited application. Suitably designed active-quenching circuits (AQC's) make it possible to exploit the best performance of SPAD's. Thick silicon SPAD's that operate at high voltages (250-450 V) have photon detection efficiency higher than 50% from 540-to 850-nm wavelength and still approximately 3% at 1064 nm. Thin silicon SPAD's that operate at low voltages (10-50 V) have 45% efficiency at 500 nm, declining to 10% at 830 nm and to as little as 0.1% at 1064 nm. The time resolution achieved in photon timing is 20 ps FWHM with thin SPAD's; it ranges from 350 to 150 ps FWHM with thick SPAD's. The achieved minimum counting dead time and maximum counting rate are 40 ns and 10 Mcps with thick silicon SPAD's, 10 ns and 40 Mcps with thin SPAD's. Germanium and III-V compound semiconductor SPAD's extend the range of photon-counting techniques in the near-infrared region to at least 1600-nm wavelength.

  20. Avalanche photodiodes and quenching circuits for single-photon detection.

    PubMed

    Cova, S; Ghioni, M; Lacaita, A; Samori, C; Zappa, F

    1996-04-20

    Avalanche photodiodes, which operate above the breakdown voltage in Geiger mode connected with avalanche-quenching circuits, can be used to detect single photons and are therefore called singlephoton avalanche diodes SPAD's. Circuit configurations suitable for this operation mode are critically analyzed and their relative merits in photon counting and timing applications are assessed. Simple passive-quenching circuits (PQC's), which are useful for SPAD device testing and selection, have fairly limited application. Suitably designed active-quenching circuits (AQC's) make it possible to exploit the best performance of SPAD's. Thick silicon SPAD's that operate at high voltages (250-450 V) have photon detection efficiency higher than 50% from 540- to 850-nm wavelength and still ~3% at 1064 nm. Thin silicon SPAD's that operate at low voltages (10-50 V) have 45% efficiency at 500 nm, declining to 10% at 830 nm and to as little as 0.1% at 1064 nm. The time resolution achieved in photon timing is 20 ps FWHM with thin SPAD's; it ranges from 350 to 150 ps FWHM with thick SPAD's. The achieved minimum counting dead time and maximum counting rate are 40 ns and 10 Mcps with thick silicon SPAD's, 10 ns and 40 Mcps with thin SPAD's. Germanium and III-V compound semiconductor SPAD's extend the range of photon-counting techniques in the near-infrared region to at least 1600-nm wavelength.

  1. Avalanche photodiode photon counting receivers for space-borne lidars

    NASA Technical Reports Server (NTRS)

    Sun, Xiaoli; Davidson, Frederic M.

    1991-01-01

    Avalanche photodiodes (APD) are studied for uses as photon counting detectors in spaceborne lidars. Non-breakdown APD photon counters, in which the APD's are biased below the breakdown point, are shown to outperform: (1) conventional APD photon counters biased above the breakdown point; (2) conventional APD photon counters biased above the breakdown point; and (3) APD's in analog mode when the received optical signal is extremely weak. Non-breakdown APD photon counters were shown experimentally to achieve an effective photon counting quantum efficiency of 5.0 percent at lambda = 820 nm with a dead time of 15 ns and a dark count rate of 7000/s which agreed with the theoretically predicted values. The interarrival times of the counts followed an exponential distribution and the counting statistics appeared to follow a Poisson distribution with no after pulsing. It is predicted that the effective photon counting quantum efficiency can be improved to 18.7 percent at lambda = 820 nm and 1.46 percent at lambda = 1060 nm with a dead time of a few nanoseconds by using more advanced commercially available electronic components.

  2. Characterization of midwave infrared InSb avalanche photodiode

    SciTech Connect

    Abautret, J. Evirgen, A.; Perez, J. P.; Christol, P.; Rothman, J.; Cordat, A.

    2015-06-28

    This paper focuses on the InSb material potential for the elaboration of Avalanche Photodiodes (APD) for high performance infrared imaging applications, both in passive or active mode. The first InSb electron-APD structure was grown by molecular beam epitaxy, processed and electrically characterized. The device performances are at the state of the art for the InSb epi-diode technology, with a dark current density J(−50 mV) = 32 nA/cm{sup 2} at 77 K. Then, a pure electron injection was performed, and an avalanche gain, increasing exponentially, was observed with a gain value near 3 at −4 V at 77 K. The Okuto–Crowell model was used to determine the electron ionization coefficient α(E) in InSb, and the InSb gain behavior is compared with the one of InAs and MCT APDs.

  3. Single photon counting linear mode avalanche photodiode technologies

    NASA Astrophysics Data System (ADS)

    Williams, George M.; Huntington, Andrew S.

    2011-10-01

    The false count rate of a single-photon-sensitive photoreceiver consisting of a high-gain, low-excess-noise linear-mode InGaAs avalanche photodiode (APD) and a high-bandwidth transimpedance amplifier (TIA) is fit to a statistical model. The peak height distribution of the APD's multiplied dark current is approximated by the weighted sum of McIntyre distributions, each characterizing dark current generated at a different location within the APD's junction. The peak height distribution approximated in this way is convolved with a Gaussian distribution representing the input-referred noise of the TIA to generate the statistical distribution of the uncorrelated sum. The cumulative distribution function (CDF) representing count probability as a function of detection threshold is computed, and the CDF model fit to empirical false count data. It is found that only k=0 McIntyre distributions fit the empirically measured CDF at high detection threshold, and that false count rate drops faster than photon count rate as detection threshold is raised. Once fit to empirical false count data, the model predicts the improvement of the false count rate to be expected from reductions in TIA noise and APD dark current. Improvement by at least three orders of magnitude is thought feasible with further manufacturing development and a capacitive-feedback TIA (CTIA).

  4. Characterization of Advanced Avalanche Photodiodes for Water Vapor Lidar Receivers

    NASA Technical Reports Server (NTRS)

    Refaat, Tamer F.; Halama, Gary E.; DeYoung, Russell J.

    2000-01-01

    Development of advanced differential absorption lidar (DIAL) receivers is very important to increase the accuracy of atmospheric water vapor measurements. A major component of such receivers is the optical detector. In the near-infrared wavelength range avalanche photodiodes (APD's) are the best choice for higher signal-to-noise ratio, where there are many water vapor absorption lines. In this study, characterization experiments were performed to evaluate a group of silicon-based APD's. The APD's have different structures representative of different manufacturers. The experiments include setups to calibrate these devices, as well as characterization of the effects of voltage bias and temperature on the responsivity, surface scans, noise measurements, and frequency response measurements. For each experiment, the setup, procedure, data analysis, and results are given and discussed. This research was done to choose a suitable APD detector for the development of an advanced atmospheric water vapor differential absorption lidar detection system operating either at 720, 820, or 940 nm. The results point out the benefits of using the super low ionization ratio (SLIK) structure APD for its lower noise-equivalent power, which was found to be on the order of 2 to 4 fW/Hz(sup (1/2)), with an appropriate optical system and electronics. The water vapor detection systems signal-to-noise ratio will increase by a factor of 10.

  5. Enhanced Red and Near Infrared Detection in Flow Cytometry Using Avalanche Photodiodes

    PubMed Central

    Lawrence, William G.; Varadi, Gyula; Entine, Gerald; Podniesinski, Edward; Wallace, Paul K.

    2008-01-01

    Background Polychromatic flow cytometry enables detailed identification of cell phenotype using multiple fluorescent parameters. The photomultiplier tubes used to detect fluorescence in current instruments limit the sensitivity in the long wavelength spectral range. We demonstrate the flow cytometric applications of silicon avalanche photodiodes, which have improved red sensitivity and a working fluorescence detection range beyond 1000 nm. Methods A comparison of the wavelength dependent performance of the avalanche photodiode and photomultiplier tube was carried out using pulsed light emitting diode sources, calibrated test beads and biological samples. A breadboard flow cytometer test bench was constructed to compare the performance of photomultiplier tubes and avalanche photodiode detectors. The avalanche photodiode used an additional amplifier stage to match the internal gain of the photomultiplier tube. Results The resolution of the avalanche photodiode and photomultiplier tube was compared for flow cytometry applications using a pulsed light emitting diode source over the 500 nm to 1060 nm spectral range. These measurements showed the relative changes in the signal to noise performance of the APD and PMT over a broad spectral range. Both the avalanche photodiode and photomultiplier tubes were used to measure the signal to noise response for a set of 6 peak calibration beads over the 530 to 800 nm wavelength range. CD4 positive cells labeled with antibody conjugated phycoerythrin or 800 nm quantum dots were identified by simultaneous detection using the avalanche photodiode and the photomultiplier tube. The ratios of the intensities of the CD4− and CD4+ populations were found to be similar for both detectors in the visible wavelengths, but only the avalanche photodiode was able to separate these populations at wavelengths above 800 nm. Conclusions These measurements illustrate the differences in APD and PMT performance at different wavelengths and signal

  6. Breadboard linear array scan imager using LSI solid-state technology

    NASA Technical Reports Server (NTRS)

    Tracy, R. A.; Brennan, J. A.; Frankel, D. G.; Noll, R. E.

    1976-01-01

    The performance of large scale integration photodiode arrays in a linear array scan (pushbroom) breadboard was evaluated for application to multispectral remote sensing of the earth's resources. The technical approach, implementation, and test results of the program are described. Several self scanned linear array visible photodetector focal plane arrays were fabricated and evaluated in an optical bench configuration. A 1728-detector array operating in four bands (0.5 - 1.1 micrometer) was evaluated for noise, spectral response, dynamic range, crosstalk, MTF, noise equivalent irradiance, linearity, and image quality. Other results include image artifact data, temporal characteristics, radiometric accuracy, calibration experience, chip alignment, and array fabrication experience. Special studies and experimentation were included in long array fabrication and real-time image processing for low-cost ground stations, including the use of computer image processing. High quality images were produced and all objectives of the program were attained.

  7. Performance measurements of a depth-encoding PET detector module based on position-sensitive avalanche photodiode read-out.

    PubMed

    Dokhale, P A; Silverman, R W; Shah, K S; Grazioso, R; Farrell, R; Glodo, J; McClish, M A; Entine, G; Tran, V H; Cherry, S R

    2004-09-21

    We are developing a high-resolution, high-efficiency positron emission tomography (PET) detector module with depth of interaction (DOI) capability based on a lutetium oxyorthosilicate (LSO) scintillator array coupled at both ends to position-sensitive avalanche photodiodes (PSAPDs). In this paper we present the DOI resolution, energy resolution and timing resolution results for complete detector modules. The detector module consists of a 7 x 7 matrix of LSO scintillator crystals (1 x 1 x 20 mm3 in dimension) coupled to 8 x 8 mm2 PSAPDs at both ends. Flood histograms were acquired and used to generate crystal look-up tables. The DOI resolution was measured for individual crystals within the array by using the ratio of the signal amplitudes from the two PSAPDs on an event-by-event basis. A measure of the total scintillation light produced was obtained by summing the signal amplitudes from the two PSAPDs. This summed signal was used to measure the energy resolution. The DOI resolution was measured to be 3-4 mm FWHM irrespective of the position of the crystal within the array, or the interaction location along the length of the crystal. The total light signal and energy resolution was almost independent of the depth of interaction. The measured energy resolution averaged 14% FWHM. The coincidence timing resolution measured using a pair of identical detector modules was 4.5 ns FWHM. These results are consistent with the design goals and the performance required of a compact, high-resolution and high-efficiency PET detector module for small animal and breast imaging applications.

  8. Photodiode Preamplifier for Laser Ranging With Weak Signals

    NASA Technical Reports Server (NTRS)

    Abramovici, Alexander; Chapsky, Jacob

    2007-01-01

    An improved preamplifier circuit has been designed for processing the output of an avalanche photodiode (APD) that is used in a high-resolution laser ranging system to detect laser pulses returning from a target. The improved circuit stands in contrast to prior such circuits in which the APD output current pulses are made to pass, variously, through wide-band or narrow-band load networks before preamplification. A major disadvantage of the prior wide-band load networks is that they are highly susceptible to noise, which degrades timing resolution. A major disadvantage of the prior narrow-band load networks is that they make it difficult to sample the amplitudes of the narrow laser pulses ordinarily used in ranging. In the improved circuit, a load resistor is connected to the APD output and its value is chosen so that the time constant defined by this resistance and the APD capacitance is large, relative to the duration of a laser pulse. The APD capacitance becomes initially charged by the pulse of current generated by a return laser pulse, so that the rise time of the load-network output is comparable to the duration of the return pulse. Thus, the load-network output is characterized by a fast-rising leading edge, which is necessary for accurate pulse timing. On the other hand, the resistance-capacitance combination constitutes a lowpass filter, which helps to suppress noise. The long time constant causes the load network output pulse to have a long shallow-sloping trailing edge, which makes it easy to sample the amplitude of the return pulse. The output of the load network is fed to a low-noise, wide-band amplifier. The amplifier must be a wide-band one in order to preserve the sharp pulse rise for timing. The suppression of noise and the use of a low-noise amplifier enable the ranging system to detect relatively weak return pulses.

  9. Advanced active quenching circuits for single-photon avalanche photodiodes

    NASA Astrophysics Data System (ADS)

    Stipčević, M.; Christensen, B. G.; Kwiat, P. G.; Gauthier, D. J.

    2016-05-01

    Commercial photon-counting modules, often based on actively quenched solid-state avalanche photodiode sensors, are used in wide variety of applications. Manufacturers characterize their detectors by specifying a small set of parameters, such as detection efficiency, dead time, dark counts rate, afterpulsing probability and single photon arrival time resolution (jitter), however they usually do not specify the conditions under which these parameters are constant or present a sufficient description. In this work, we present an in-depth analysis of the active quenching process and identify intrinsic limitations and engineering challenges. Based on that, we investigate the range of validity of the typical parameters used by two commercial detectors. We identify an additional set of imperfections that must be specified in order to sufficiently characterize the behavior of single-photon counting detectors in realistic applications. The additional imperfections include rate-dependence of the dead time, jitter, detection delay shift, and "twilighting." Also, the temporal distribution of afterpulsing and various artifacts of the electronics are important. We find that these additional non-ideal behaviors can lead to unexpected effects or strong deterioration of the system's performance. Specifically, we discuss implications of these new findings in a few applications in which single-photon detectors play a major role: the security of a quantum cryptographic protocol, the quality of single-photon-based random number generators and a few other applications. Finally, we describe an example of an optimized avalanche quenching circuit for a high-rate quantum key distribution system based on time-bin entangled photons.

  10. SNP Arrays

    PubMed Central

    Louhelainen, Jari

    2016-01-01

    The papers published in this Special Issue “SNP arrays” (Single Nucleotide Polymorphism Arrays) focus on several perspectives associated with arrays of this type. The range of papers vary from a case report to reviews, thereby targeting wider audiences working in this field. The research focus of SNP arrays is often human cancers but this Issue expands that focus to include areas such as rare conditions, animal breeding and bioinformatics tools. Given the limited scope, the spectrum of papers is nothing short of remarkable and even from a technical point of view these papers will contribute to the field at a general level. Three of the papers published in this Special Issue focus on the use of various SNP array approaches in the analysis of three different cancer types. Two of the papers concentrate on two very different rare conditions, applying the SNP arrays slightly differently. Finally, two other papers evaluate the use of the SNP arrays in the context of genetic analysis of livestock. The findings reported in these papers help to close gaps in the current literature and also to give guidelines for future applications of SNP arrays. PMID:27792140

  11. Black silicon n-type photodiodes with high response over wide spectral range

    NASA Astrophysics Data System (ADS)

    Heinonen, Juha; Juntunen, Mikko A.; Laine, Hannu S.; Vähänissi, Ville; Repo, Päivikki; Dönsberg, Timo; Savin, Hele

    2017-05-01

    Commercial photodiodes suffer from reflection losses and different recombination losses that reduce the collection efficiency of photogenerated charge carriers. Recently, we realized a near-ideal silicon photodiode, which steps closer to the physical performance limits of silicon photodiodes than any other silicon photodiode realized before. Our device exhibits an external quantum efficiency above 95% over the wavelength range of 235 - 980 nm, and provides a very high response at incident angles of up to 70 degrees. The high quantum efficiency is reached by 1) virtually eliminating front surface reflectance by forming a "black silicon" nanostructured surface having dimensions in the range of wavelength of optical light and 2) using an induced junction for signal collection, formed by negatively charged alumina, instead of a conventional doped p-n junction. Here, we describe the latest efforts in further development of the photodiode technology. In particular, we report improvements both in the short wavelength response via better control of the surface quality, and superior response to photons with energies close to the silicon bandgap.

  12. Aerosol optical depth as observed by the Mars Science Laboratory REMS UV photodiodes

    NASA Astrophysics Data System (ADS)

    Smith, Michael D.; Zorzano, María-Paz; Lemmon, Mark; Martín-Torres, Javier; Mendaza de Cal, Teresa

    2016-12-01

    Systematic observations taken by the REMS UV photodiodes on a daily basis throughout the landed Mars Science Laboratory mission provide a highly useful tool for characterizing aerosols above Gale Crater. Radiative transfer modeling is used to model the approximately 1.75 Mars Years of observations taken to date taking into account multiple scattering from aerosols and the extended field of view of the REMS UV photodiodes. The retrievals show in detail the annual cycle of aerosol optical depth, which is punctuated with numerous short timescale events of increased optical depth. Dust deposition onto the photodiodes is accounted for by comparison with aerosol optical depth derived from direct imaging of the Sun by Mastcam. The effect of dust on the photodiodes is noticeable, but does not dominate the signal. Cleaning of dust from the photodiodes was observed in the season around Ls=270°, but not during other seasons. Systematic deviations in the residuals from the retrieval fit are indicative of changes in aerosol effective particle size, with larger particles present during periods of increased optical depth. This seasonal dependence of aerosol particle size is expected as dust activity injects larger particles into the air, while larger aerosols settle out of the atmosphere more quickly leading to a smaller average particle size over time.

  13. Aerosol Optical Depth as Observed by the Mars Science Laboratory REMS UV Photodiodes

    NASA Astrophysics Data System (ADS)

    Smith, M. D.; Zorzano, M. P.; Lemmon, M. T.; Martín-Torres, J.; Mendaza de Cal, T.

    2016-12-01

    Systematic observations taken by the REMS UV photodiodes on a daily basis throughout the landed Mars Science Laboratory mission provide a highly useful tool for characterizing aerosols above Gale Crater. Radiative transfer modeling is used to model the more than two Mars Years of observations taken to date taking into account multiple scattering from aerosols and the extended field of view of the REMS UV photodiodes. The retrievals show in detail the annual cycle of aerosol optical depth, which is punctuated with numerous short timescale events of increased optical depth. Dust deposition onto the photodiodes is accounted for by comparison with aerosol optical depth derived from direct imaging of the Sun by Mastcam. The effect of dust on the photodiodes is noticeable, but does not dominate the signal. Cleaning of dust from the photodiodes was observed in the season around Ls=270°, but not during other seasons. Systematic deviations in the residuals from the retrieval fit are indicative of changes in aerosol effective particle size, with larger particles present during periods of increased optical depth. This seasonal dependence of aerosol particle size is expected as dust activity injects larger particles into the air, while larger aerosols settle out of the atmosphere more quickly leading to a smaller average particle size over time.

  14. Aerosol Optical Depth as Observed by the Mars Science Laboratory REMS UV Photodiodes

    NASA Technical Reports Server (NTRS)

    Smith, M. D.; Zorzano, M.-P.; Lemmon, M.; Martin-Torres, J.; Mendaza de Cal, T.

    2017-01-01

    Systematic observations taken by the REMS UV photodiodes on a daily basis throughout the landed Mars Science Laboratory mission provide a highly useful tool for characterizing aerosols above Gale Crater. Radiative transfer modeling is used to model the approximately two Mars Years of observations taken to date taking into account multiple scattering from aerosols and the extended field of view of the REMS UV photodiodes. The retrievals show in detail the annual cycle of aerosol optical depth, which is punctuated with numerous short timescale events of increased optical depth. Dust deposition onto the photodiodes is accounted for by comparison with aerosol optical depth derived from direct imaging of the Sun by Mastcam. The effect of dust on the photodiodes is noticeable, but does not dominate the signal. Cleaning of dust from the photodiodes was observed in the season around Ls=270deg, but not during other seasons. Systematic deviations in the residuals from the retrieval fit are indicative of changes in aerosol effective particle size, with larger particles present during periods of increased optical depth. This seasonal dependence of aerosol particle size is expected as dust activity injects larger particles into the air, while larger aerosols settle out of the atmosphere more quickly leading to a smaller average particle size over time. A full description of these observations, the retrieval algorithm, and the results can be found in Smith et al. (2016).

  15. Integrated array of 2-μm antimonide-based single-photon counting devices.

    PubMed

    Diagne, M A; Greszik, M; Duerr, E K; Zayhowski, J J; Manfra, M J; Bailey, R J; Donnelly, J P; Turner, G W

    2011-02-28

    A 32x32 Sb-based Geiger-mode (GM) avalanche photodiode array, operating at 2 μm with three-dimensional imaging capability, is presented. The array is interfaced with a ROIC (readout integrated circuit) in which each pixel can detect a photon and record the arrival time. The hybridized unit for the 1000-element focal plane array, when operated at 77K with 1 V overbias range, shows an average dark count rate of 1.5 kHz. Three-dimensional range images of objects were acquired.

  16. Enthalpy arrays

    PubMed Central

    Torres, Francisco E.; Kuhn, Peter; De Bruyker, Dirk; Bell, Alan G.; Wolkin, Michal V.; Peeters, Eric; Williamson, James R.; Anderson, Gregory B.; Schmitz, Gregory P.; Recht, Michael I.; Schweizer, Sandra; Scott, Lincoln G.; Ho, Jackson H.; Elrod, Scott A.; Schultz, Peter G.; Lerner, Richard A.; Bruce, Richard H.

    2004-01-01

    We report the fabrication of enthalpy arrays and their use to detect molecular interactions, including protein–ligand binding, enzymatic turnover, and mitochondrial respiration. Enthalpy arrays provide a universal assay methodology with no need for specific assay development such as fluorescent labeling or immobilization of reagents, which can adversely affect the interaction. Microscale technology enables the fabrication of 96-detector enthalpy arrays on large substrates. The reduction in scale results in large decreases in both the sample quantity and the measurement time compared with conventional microcalorimetry. We demonstrate the utility of the enthalpy arrays by showing measurements for two protein–ligand binding interactions (RNase A + cytidine 2′-monophosphate and streptavidin + biotin), phosphorylation of glucose by hexokinase, and respiration of mitochondria in the presence of 2,4-dinitrophenol uncoupler. PMID:15210951

  17. Array tomography: imaging stained arrays.

    PubMed

    Micheva, Kristina D; O'Rourke, Nancy; Busse, Brad; Smith, Stephen J

    2010-11-01

    Array tomography is a volumetric microscopy method based on physical serial sectioning. Ultrathin sections of a plastic-embedded tissue are cut using an ultramicrotome, bonded in an ordered array to a glass coverslip, stained as desired, and imaged. The resulting two-dimensional image tiles can then be reconstructed computationally into three-dimensional volume images for visualization and quantitative analysis. The minimal thickness of individual sections permits high-quality rapid staining and imaging, whereas the array format allows reliable and convenient section handling, staining, and automated imaging. Also, the physical stability of the arrays permits images to be acquired and registered from repeated cycles of staining, imaging, and stain elution, as well as from imaging using multiple modalities (e.g., fluorescence and electron microscopy). Array tomography makes it possible to visualize and quantify previously inaccessible features of tissue structure and molecular architecture. However, careful preparation of the tissue is essential for successful array tomography; these steps can be time-consuming and require some practice to perfect. In this protocol, tissue arrays are imaged using conventional wide-field fluorescence microscopy. Images can be captured manually or, with the appropriate software and hardware, the process can be automated.

  18. Array tomography: production of arrays.

    PubMed

    Micheva, Kristina D; O'Rourke, Nancy; Busse, Brad; Smith, Stephen J

    2010-11-01

    Array tomography is a volumetric microscopy method based on physical serial sectioning. Ultrathin sections of a plastic-embedded tissue are cut using an ultramicrotome, bonded in an ordered array to a glass coverslip, stained as desired, and imaged. The resulting two-dimensional image tiles can then be reconstructed computationally into three-dimensional volume images for visualization and quantitative analysis. The minimal thickness of individual sections permits high-quality rapid staining and imaging, whereas the array format allows reliable and convenient section handling, staining, and automated imaging. Also, the physical stability of the arrays permits images to be acquired and registered from repeated cycles of staining, imaging, and stain elution, as well as from imaging using multiple modalities (e.g., fluorescence and electron microscopy). Array tomography makes it possible to visualize and quantify previously inaccessible features of tissue structure and molecular architecture. However, careful preparation of the tissue is essential for successful array tomography; these steps can be time consuming and require some practice to perfect. This protocol describes the sectioning of embedded tissues and the mounting of the serial arrays. The procedures require some familiarity with the techniques used for ultramicrotome sectioning for electron microscopy.

  19. Infrared Arrays

    NASA Astrophysics Data System (ADS)

    McLean, I.; Murdin, P.

    2000-11-01

    Infrared arrays are small electronic imaging devices subdivided into a grid or `array' of picture elements, or pixels, each of which is made of a material sensitive to photons (ELECTROMAGNETIC RADIATION) with wavelengths much longer than normal visible light. Typical dimensions of currently available devices are about 27-36 mm square, and formats now range from 2048×2048 pixels for the near-infra...

  20. High performance waveguide-coupled Ge-on-Si linear mode avalanche photodiodes.

    PubMed

    Martinez, Nicholas J D; Derose, Christopher T; Brock, Reinhard W; Starbuck, Andrew L; Pomerene, Andrew T; Lentine, Anthony L; Trotter, Douglas C; Davids, Paul S

    2016-08-22

    We present experimental results for a selective epitaxially grown Ge-on-Si separate absorption and charge multiplication (SACM) integrated waveguide coupled avalanche photodiode (APD) compatible with our silicon photonics platform. Epitaxially grown Ge-on-Si waveguide-coupled linear mode avalanche photodiodes with varying lateral multiplication regions and different charge implant dimensions are fabricated and their illuminated device characteristics and high-speed performance is measured. We report a record gain-bandwidth product of 432 GHz for our highest performing waveguide-coupled avalanche photodiode operating at 1510nm. Bit error rate measurements show operation with BER< 10-12, in the range from -18.3 dBm to -12 dBm received optical power into a 50 Ω load and open eye diagrams with 13 Gbps pseudo-random data at 1550 nm.

  1. High performance waveguide-coupled Ge-on-Si linear mode avalanche photodiodes

    DOE PAGES

    Martinez, Nicholas J. D.; Derose, Christopher T.; Brock, Reinhard W.; ...

    2016-08-09

    Here, we present experimental results for a selective epitaxially grown Ge-on-Si separate absorption and charge multiplication (SACM) integrated waveguide coupled avalanche photodiode (APD) compatible with our silicon photonics platform. Epitaxially grown Ge-on-Si waveguide-coupled linear mode avalanche photodiodes with varying lateral multiplication regions and different charge implant dimensions are fabricated and their illuminated device characteristics and high-speed performance is measured. We report a record gain-bandwidth product of 432 GHz for our highest performing waveguide-coupled avalanche photodiode operating at 1510nm. Bit error rate measurements show operation with BER< 10–12, in the range from –18.3 dBm to –12 dBm received optical power intomore » a 50 Ω load and open eye diagrams with 13 Gbps pseudo-random data at 1550 nm.« less

  2. Blue-enhanced thin-film photodiode for dual-screen x-ray imaging

    SciTech Connect

    Vygranenko, Y.; Vieira, M.; Sazonov, A.; Heiler, G.; Tredwell, T.; Nathan, A.

    2009-12-28

    This article reports on a-Si:H-based low-leakage blue-enhanced photodiodes for dual-screen x-ray imaging detectors. Doped nanocrystalline silicon was incorporated in both the n- and p-type regions to reduce absorption losses for light incoming from the top and bottom screens. The photodiode exhibits a dark current density of 900 pA/cm{sup 2} and an external quantum efficiency up to 90% at a reverse bias of 5 V. In the case of illumination through the tailored p-layer, the quantum efficiency of 60% at a 400 nm wavelength is almost double that for the conventional a-Si:H n-i-p photodiode.

  3. Effects of low-level boron doping on the photocurrent of amorphous silicon Schottky photodiodes

    NASA Astrophysics Data System (ADS)

    Kakinuma, H.; Kasuya, Y.; Sakamoto, M.; Shibata, S.

    1989-03-01

    The effects of low-level boron doping on the photocurrent-electric field (Jph-F) characteristics of amorphous silicon Schottky photodiodes were investigated by measuring the Jph-F characteristics of a lightly B-doped photodiode with a configuration of Cr/a-Si:H/tin-doped indium oxide (ITO). The Jph-F curves, which were found to be strongly dependent on the B-doping ratio, were analyzed on the basis of Crandall's (1984) theory, and the B-doping dependencies of the mobility-lifetime (mu-tau) product for electrons and holes were deduced. The effects of low-level B-doping on the mu-tau products and space charges of the photodiodes were discussed in terms of the charge state of the dangling bond state.

  4. Indium phosphide-based monolithically integrated PIN waveguide photodiode readout for resonant cantilever sensors

    SciTech Connect

    Siwak, N. P.; Fan, X. Z.; Ghodssi, R.; Kanakaraju, S.; Richardson, C. J. K.

    2014-10-06

    An integrated photodiode displacement readout scheme for a microelectromechanical cantilever waveguide resonator sensing platform is presented. III-V semiconductors are used to enable the monolithic integration of passive waveguides with active optical components. This work builds upon previously demonstrated results by measuring the displacement of cantilever waveguide resonators with on-chip waveguide PIN photodiodes. The on-chip integration of the readout provides an additional 70% improvement in mass sensitivity compared to off-chip photodetector designs due to measurement stability and minimized coupling loss. In addition to increased measurement stability, reduced packaging complexity is achieved due to the simplicity of the readout design. We have fabricated cantilever waveguides with integrated photodetectors and experimentally characterized these cantilever sensors with monolithically integrated PIN photodiodes.

  5. Photosensitivity of Te-doped silicon photodiodes fabricated using femtosecond laser irradiation.

    PubMed

    Li, Rui; Du, Lingyan; Tang, Fei; Jiang, Yadong; Wu, Zhiming

    2016-12-20

    Microstructured Te-doped silicon is prepared via a femtosecond laser irradiating Si coated with Si-Te bilayer films, and photodiodes are successfully fabricated from this material. The samples are thermally annealed at 773 K for three different time durations. The effects of annealing time on microstructures, infrared absorptance, and photosensitivity of Te-doped silicon are investigated. From the scanning electronic microscope images and the optical absorptance spectra, the results show that the infrared absorptance decreases with the increase of annealing time durations, while the infrared photoresponse follows an opposite tendency. At 1064 nm, the responsivity achieves 2.4836 A/W at -10  V reverse bias for the Te-doped silicon photodiode annealed at 775 K for 2 h, which is higher than that of usual commercial Si photodiodes. These results are important for the fabrication of Te-doped silicon and facilitate its application in infrared detectors.

  6. Analysis of the photodiode boundary layer transition indicator. LDRD final report

    SciTech Connect

    Kuntz, D.W.; Wilken, A.C.; Payne, J.L.

    1994-06-01

    The photodiode transition indicator is a device which has been successfully used to determine the onset of boundary layer transition on numerous hypersonic flight vehicles. The exact source of the electromagnetic radiation detected by the photodiode at transition was not understood. In some cases early saturation of the device occurred, and the device failed to detect transition. Analyses have been performed to determine the source of the radiation producing the photodiode signal. The results of these analyses indicate that the most likely source of the radiation is blackbody emission from the heatshield material bordering the quartz window of the device. Good agreement between flight data and calculations based on this radiation source has been obtained. Analyses also indicate that the most probable source of the radiation causing early saturation is blackbody radiation from carbon particles which break away from the nosetip during the ablation process.

  7. Fabrication and characterization of Au/n-Si photodiode with lithium as back-surface-field

    NASA Astrophysics Data System (ADS)

    Keffous, A.; Zitouni, M.; Belkacem, Y.; Menari, H.; Chergui, W.

    2002-10-01

    In this work, we present a design and characterization of Schottky barrier Au/n-Si/Li based UV-VIS photodiode for application, such as solar UV monitoring, flame sensors and UV astronomy. The Schottky photodiode was realized with a thin layer of gold (Au) at the front side of high purity n-type silicon and lithium (Li) on the back side as back-surface-field (Li-BSF). The Li-BSF used was a new method which allow us to modulate and choice the depletion width. I- V characteristic, capacitance and spectral response were performed, the results were found in agreement with those determined by simulation method. A quantum efficiency (QE) of 47% at about 550 nm wavelength was obtained using only a thin gold layer as sensitive area. The thickness of gold used on the photodiode was around 125 Å, where 58% of light transmission was carried out.

  8. Silicon photodiode soft x-ray detectors for pulsed power experiments

    SciTech Connect

    Idzorek, G.C.; Bartlett, R.J.

    1997-10-01

    Silicon photodiodes offer a number of advantages over conventional photocathode type soft x-ray detectors in pulsed power experiments. These include a nominally flat response, insensitivity to surface contamination, low voltage biasing requirements, sensitivity to low energy photons, excellent detector to detector response reproducibility, and ability to operate in poor vacuum or gas backfilled experiments. Silicon photodiodes available from International Radiation Detectors (IRD), Torrance, California have been characterized for absolute photon response from 1 eV to 10 keV photon energy, time response, and signal saturation levels. The authors calibration measurements show factor of ten deviations from the silicon photodiode theoretical flat response due to diode sensitivity outside the center `sensitive area`. Detector response reproducibility between diodes appears to be better than 5%. Time response measurements show a 10-90% rise time of about 0.1 nanoseconds and a fall time of about 0.5 nanoseconds.

  9. Low-Noise Large-Area Photoreceivers with Low Capacitance Photodiodes

    NASA Technical Reports Server (NTRS)

    Joshi, Abhay M. (Inventor); Datta, Shubhashish (Inventor)

    2013-01-01

    A quad photoreceiver includes a low capacitance quad InGaAs p-i-n photodiode structure formed on an InP (100) substrate. The photodiode includes a substrate providing a buffer layer having a metal contact on its bottom portion serving as a common cathode for receiving a bias voltage, and successive layers deposited on its top portion, the first layer being drift layer, the second being an absorption layer, the third being a cap layer divided into four quarter pie shaped sections spaced apart, with metal contacts being deposited on outermost top portions of each section to provide output terminals, the top portions being active regions for detecting light. Four transimpedance amplifiers have input terminals electrically connected to individual output terminals of each p-i-n photodiode.

  10. High performance waveguide-coupled Ge-on-Si linear mode avalanche photodiodes

    SciTech Connect

    Martinez, Nicholas J. D.; Derose, Christopher T.; Brock, Reinhard W.; Starbuck, Andrew L.; Pomerene, Andrew T.; Lentine, Anthony L.; Trotter, Douglas C.; Davids, Paul S.

    2016-08-09

    Here, we present experimental results for a selective epitaxially grown Ge-on-Si separate absorption and charge multiplication (SACM) integrated waveguide coupled avalanche photodiode (APD) compatible with our silicon photonics platform. Epitaxially grown Ge-on-Si waveguide-coupled linear mode avalanche photodiodes with varying lateral multiplication regions and different charge implant dimensions are fabricated and their illuminated device characteristics and high-speed performance is measured. We report a record gain-bandwidth product of 432 GHz for our highest performing waveguide-coupled avalanche photodiode operating at 1510nm. Bit error rate measurements show operation with BER< 10–12, in the range from –18.3 dBm to –12 dBm received optical power into a 50 Ω load and open eye diagrams with 13 Gbps pseudo-random data at 1550 nm.

  11. High performance waveguide-coupled Ge-on-Si linear mode avalanche photodiodes

    DOE PAGES

    Martinez, Nicholas J. D.; Derose, Christopher T.; Brock, Reinhard W.; ...

    2016-08-09

    Here, we present experimental results for a selective epitaxially grown Ge-on-Si separate absorption and charge multiplication (SACM) integrated waveguide coupled avalanche photodiode (APD) compatible with our silicon photonics platform. Epitaxially grown Ge-on-Si waveguide-coupled linear mode avalanche photodiodes with varying lateral multiplication regions and different charge implant dimensions are fabricated and their illuminated device characteristics and high-speed performance is measured. We report a record gain-bandwidth product of 432 GHz for our highest performing waveguide-coupled avalanche photodiode operating at 1510nm. Bit error rate measurements show operation with BER< 10–12, in the range from –18.3 dBm to –12 dBm received optical power intomore » a 50 Ω load and open eye diagrams with 13 Gbps pseudo-random data at 1550 nm.« less

  12. Design, fabrication, and characterization of mid wavelength infrared avalanche photodiode

    NASA Astrophysics Data System (ADS)

    Mallick, Shubhrangshu

    Photodetectors with high bandwidth and internal gain are required to detect highly attenuated optical signals for defense applications and long distance communication. Modern laser detection and ranging (LADAR) systems as well as weapon systems, used for long range military and astronomical applications, need to detect, recognize and track a variety of targets under a wide spectrum of atmospheric conditions. A continually varying atmospheric conditions and optical absorption by carbon dioxide, carbon monoxide and water vapor pose severe threats for the proper recognition of the target. The choice of an additional amplification stage along with the detection stage becomes obvious to enhance the signal to noise ratio at the receiver. Avalanche Photodiode (APD) plays a unique role by combing the detection and amplification stage and hence reduces the complexity. But due to the probabilistic nature associated with the incident radiation absorption and multiplication of the photo-generated carriers, the noise level (known as excess noise) of an APD increases and might result in the deterioration of the signal to noise ratio at the detector output. Participation of both electrons and holes in the avalanche mechanism increases the probability, hence the excess noise at the detector output. So, the goal of the APD design lies in the fact of the minimization of the excess noise along with a reasonable multiplication gain. In this research, two material systems, II-VI based Hg1-xCd xTe on Si, and III-V based InAs/GaSb strained layer superlattice (SLS) was studied extensively to achieve the noiseless avalanche characteristics in the mid wavelength infrared region. The electronic bandstructure of the multiplication region of these APDs were designed with the help of 14 band k.p model. The doping and thickness of individual layers were designed with the help of Atlas and Sentaurus simulation platform. The devices were fabricated using standard UV Photo-lithography and wet

  13. High-performance fused indium gallium arsenide/silicon photodiode

    NASA Astrophysics Data System (ADS)

    Kang, Yimin

    Modern long haul, high bit rate fiber-optic communication systems demand photodetectors with high sensitivity. Avalanche photodiodes (APDs) exhibit superior sensitivity performance than other types of photodetectors by virtual of its internal gain mechanism. This dissertation work further advances the APD performance by applying a novel materials integration technique. It is the first successful demonstration of wafer fused InGaAs/Si APDs with low dark current and low noise. APDs generally adopt separate absorption and multiplication (SAM) structure, which allows independent optimization of materials properties in two distinct regions. While the absorption material needs to have high absorption coefficient in the target wavelength range to achieve high quantum efficiency, it is desirable for the multiplication material to have large discrepancy between its electron and hole ionization coefficients to reduce noise. According to these criteria, InGaAs and Si are the ideal materials combination. Wafer fusion is the enabling technique that makes this theoretical ideal an experimental possibility. APDs fabricated on the fused InGaAs/Si wafer with mesa structure exhibit low dark current and low noise. Special device fabrication techniques and high quality wafer fusion reduce dark current to nano ampere level at unity gain, comparable to state-of-the-art commercial III/V APDs. The small excess noise is attributed to the large difference in ionization coefficients between electrons and holes in silicon. Detailed layer structure designs are developed specifically for fused InGaAs/Si APDs based on principles similar to those used in traditional InGaAs/InP APDs. An accurate yet straightforward technique for device structural parameters extraction is also proposed. The extracted results from the fabricated APDs agree with device design parameters. This agreement also confirms that the fusion interface has negligible effect on electric field distributions for devices fabricated

  14. Improved x-ray detection and particle identification with avalanche photodiodes.

    PubMed

    Diepold, Marc; Fernandes, Luis M P; Machado, Jorge; Amaro, Pedro; Abdou-Ahmed, Marwan; Amaro, Fernando D; Antognini, Aldo; Biraben, François; Chen, Tzu-Ling; Covita, Daniel S; Dax, Andreas J; Franke, Beatrice; Galtier, Sandrine; Gouvea, Andrea L; Götzfried, Johannes; Graf, Thomas; Hänsch, Theodor W; Hildebrandt, Malte; Indelicato, Paul; Julien, Lucile; Kirch, Klaus; Knecht, Andreas; Kottmann, Franz; Krauth, Julian J; Liu, Yi-Wei; Monteiro, Cristina M B; Mulhauser, Françoise; Naar, Boris; Nebel, Tobias; Nez, François; Santos, José Paulo; dos Santos, Joaquim M F; Schuhmann, Karsten; Szabo, Csilla I; Taqqu, David; Veloso, João F C A; Voss, Andreas; Weichelt, Birgit; Pohl, Randolf

    2015-05-01

    Avalanche photodiodes are commonly used as detectors for low energy x-rays. In this work, we report on a fitting technique used to account for different detector responses resulting from photoabsorption in the various avalanche photodiode layers. The use of this technique results in an improvement of the energy resolution at 8.2 keV by up to a factor of 2 and corrects the timing information by up to 25 ns to account for space dependent electron drift time. In addition, this waveform analysis is used for particle identification, e.g., to distinguish between x-rays and MeV electrons in our experiment.

  15. Large-area avalanche photodiodes for the detection of soft x rays.

    PubMed

    Gullikson, E M; Gramsch, E; Szawlowski, M

    1995-08-01

    The charge-collection efficiency of beveled-edge-type silicon avalanche photodiodes has been determined for soft x rays in the 50-300-eV range. An efficiency of greater than 80% is measured for energies below the Si L absorption edge. The measured efficiency is well described by a model that accounts for absorption in an oxide overlayer and recombination at the front surface of the diode. The avalanche photodiodes are shown to be significantly more sensitive compared with other detectors for pulsed sources such as a laser-produced plasma source. These results are also very encouraging for soft-xray/ extreme-UV applications involving synchrotron radiation.

  16. Ultralow-noise readout circuit with an avalanche photodiode: toward a photon-number-resolving detector.

    PubMed

    Tsujino, Kenji; Akiba, Makoto; Sasaki, Masahide

    2007-03-01

    The charge-integration readout circuit was fabricated to achieve an ultralow-noise preamplifier for photoelectrons generated in an avalanche photodiode with linear mode operation at 77 K. To reduce the various kinds of noise, the capacitive transimpedance amplifier was used and consisted of low-capacitance circuit elements that were cooled with liquid nitrogen. As a result, the readout noise is equal to 3.0 electrons averaged for a period of 40 ms. We discuss the requirements for avalanche photodiodes to achieve photon-number-resolving detectors below this noise level.

  17. Look-back-upon tree recurrence method for Geiger-mode avalanche photodiode performance prediction.

    PubMed

    Peng, Zhao; Yan, Zhang; Yuming, Hua; Weiping, Qian

    2015-08-15

    This Letter, for the first time, proposes the look-back-upon tree recurrence (LTR) method based on the Poisson statistics for discrete time to predict the performance of Geiger-mode avalanche photodiodes with a short dead time. The results of the proposed method correspond to the results of previous methods for diverse input fluxes. The LTR method possesses very low time and space complexity to allow for the real-time analysis of the Geiger-mode avalanche photodiodes' performance over the entire ranges of dead time and input diversity.

  18. A near infrared organic photodiode with gain at low bias voltage

    SciTech Connect

    Campbell, Ian H; Crone, Brian K

    2009-01-01

    We demonstrate an organic photodiode with near infrared optical response out to about 1100 run with a gain of {approx}10 at 1000 run under 5V reverse bias. The diodes employ a soluble naphthalocyanine with a peak absorption coefficient of {approx}10{sup 5} cm{sup -1} at 1000 nm. In contrast to most organic photodiodes, no exciton dissociating material is used. At zero bias, the diodes are inefficient with an external quantum efficiency of {approx} 10{sup -2}. In reverse bias, large gain occurs and is linear with bias voltage above 4V. The observed gain is consistent with a photoconductive gain mechanism.

  19. Improved x-ray detection and particle identification with avalanche photodiodes

    SciTech Connect

    Diepold, Marc Franke, Beatrice; Götzfried, Johannes; Hänsch, Theodor W.; Krauth, Julian J.; Mulhauser, Françoise; Nebel, Tobias; Pohl, Randolf; Fernandes, Luis M. P.; Amaro, Fernando D.; Gouvea, Andrea L.; Monteiro, Cristina M. B.; Santos, Joaquim M. F. dos; Machado, Jorge; Amaro, Pedro; Santos, José Paulo; and others

    2015-05-15

    Avalanche photodiodes are commonly used as detectors for low energy x-rays. In this work, we report on a fitting technique used to account for different detector responses resulting from photoabsorption in the various avalanche photodiode layers. The use of this technique results in an improvement of the energy resolution at 8.2 keV by up to a factor of 2 and corrects the timing information by up to 25 ns to account for space dependent electron drift time. In addition, this waveform analysis is used for particle identification, e.g., to distinguish between x-rays and MeV electrons in our experiment.

  20. Silicon photodiode with selective Zr/Si coating for extreme ultraviolet spectral range

    SciTech Connect

    Aruev, P N; Barysheva, Mariya M; Ber, B Ya; Zabrodskaya, N V; Zabrodskii, V V; Lopatin, A Ya; Pestov, Alexey E; Petrenko, M V; Polkovnikov, V N; Salashchenko, Nikolai N; Sukhanov, V L; Chkhalo, Nikolai I

    2012-10-31

    The procedure of manufacturing silicon photodiodes with an integrated Zr/Si filter for extreme ultraviolet (EUV) spectral range is developed. A setup for measuring the sensitivity profile of detectors with spatial resolution better than 100 {mu}m is fabricated. The optical properties of silicon photodiodes in the EUV and visible spectral ranges are investigated. Some characteristics of SPD-100UV diodes with Zr/Si coating and without it, as well as of AXUV-100 diodes, are compared. In all types of detectors a narrow region beyond the operating aperture is found to be sensitive to the visible light. (photodetectors)

  1. Probing higher order correlations of the photon field with photon number resolving avalanche photodiodes.

    PubMed

    Dynes, J F; Yuan, Z L; Sharpe, A W; Thomas, O; Shields, A J

    2011-07-04

    We demonstrate the use of two high speed avalanche photodiodes in exploring higher order photon correlations. By employing the photon number resolving capability of the photodiodes the response to higher order photon coincidences can be measured. As an example we show experimentally the sensitivity to higher order correlations for three types of photon sources with distinct photon statistics. This higher order correlation technique could be used as a low cost and compact tool for quantifying the degree of correlation of photon sources employed in quantum information science.

  2. 4H-SiC Schottky photodiodes for ultraviolet flame detection

    NASA Astrophysics Data System (ADS)

    Mazzillo, M.; Sciuto, A.

    2015-10-01

    In the last few years silicon carbide (SiC) has emerged as an appropriate material for the detection of very low ultraviolet photon fluxes even at elevated temperatures. In this paper we report on the electro-optical characteristics of large area interdigit Ni2Si/4H-SiC photodiodes in TO metal can package with a suitable molded cap quartz window with high transmission in the ultraviolet wavelength range. The detectors have been tested for the detection of the ultraviolet component of the yellow flame emitted by a small candle, showing good sensitivity for very weak photon fluxes notwithstanding the linear operation condition of the photodiodes.

  3. Injection photodiodes based on low-resistivity ZnS single crystals

    SciTech Connect

    Losev, V. V.

    2009-12-15

    Results of an experimental study of Ni-n-n{sup +}-In photodiode structures fabricated from a low-resistivity ZnS:Al crystal (n{sup +}-region) are reported. The high-resistivity compensated n-type layer is produced by thermal diffusion of silver. The photodiodes exhibit an injection amplification of the photocurrent under a forward bias of 1-10 V. The dependence of the currents through the diodes on the thickness of the n-type layer in the dark and under UV irradiation is determined. The photosensitivity is at a maximum in the fundamental absorption range in a narrow spectral band.

  4. Development of an integrated four-channel fast avalanche-photodiode detector system with nanosecond time resolution

    NASA Astrophysics Data System (ADS)

    Li, Zhenjie; Li, Qiuju; Chang, Jinfan; Ma, Yichao; Liu, Peng; Wang, Zheng; Hu, Michael Y.; Zhao, Jiyong; Alp, E. E.; Xu, Wei; Tao, Ye; Wu, Chaoqun; Zhou, Yangfan

    2017-10-01

    A four-channel nanosecond time-resolved avalanche-photodiode (APD) detector system is developed at Beijing Synchrotron Radiation. It uses a single module for signal processing and readout. This integrated system provides better reliability and flexibility for custom improvement. The detector system consists of three parts: (i) four APD sensors, (ii) four fast preamplifiers and (iii) a time-digital-converter (TDC) readout electronics. The C30703FH silicon APD chips fabricated by Excelitas are used as the sensors of the detectors. It has an effective light-sensitive area of 10 × 10 mm2 and an absorption layer thickness of 110 μm. A fast preamplifier with a gain of 59 dB and bandwidth of 2 GHz is designed to readout of the weak signal from the C30703FH APD. The TDC is realized by a Spartan-6 field-programmable-gate-array (FPGA) with multiphase method in a resolution of 1ns. The arrival time of all scattering events between two start triggers can be recorded by the TDC. The detector has been used for nuclear resonant scattering study at both Advanced Photon Source and also at Beijing Synchrotron Radiation Facility. For the X-ray energy of 14.4 keV, the time resolution, the full width of half maximum (FWHM) of the detector (APD sensor + fast amplifier) is 0.86 ns, and the whole detector system (APD sensors + fast amplifiers + TDC readout electronics) achieves a time resolution of 1.4 ns.

  5. Novel wearable-type biometric devices based on skin tissue optics with multispectral LED–photodiode matrix

    NASA Astrophysics Data System (ADS)

    Jo, Young Chang; Kim, Hae Na; Kang, Jae Hwan; Hong, Hyuck Ki; Choi, Yeon Shik; Jung, Suk Won; Kim, Sung Phil

    2017-04-01

    In this study, we examined the possibility of using a multispectral skin photomatrix (MSP) module as a novel biometric device. The MSP device measures optical patterns of the wrist skin tissue. Optical patterns consist of 2 × 8 photocurrent intensities of photodiode arrays, which are generated by optical transmission and diffuse reflection of photons from LED light sources with variable wavelengths into the wrist skin tissue. Optical patterns detected by the MSP device provide information on both the surface and subsurface characteristics of the human skin tissue. We found that in the 21 subjects we studied, they showed their unique characteristics, as determined using several wavelengths of light. The experimental results show that the best personal identification accuracy can be acquired using a combination of infrared light and yellow light. This novel biometric device, the MSP module, exhibited an excellent false acceptance rate (FAR) of 0.3% and a false rejection rate (FRR) of 0.0%, which are better than those of commercialized biometric devices such as a fingerprint biometric system. From these experimental results, we found that people exhibit unique optical patterns of their inner-wrist skin tissue and this uniqueness could be used for developing novel high-accuracy personal identification devices.

  6. Note: Effect of photodiode aluminum cathode frame on spectral sensitivity in the soft x-ray energy band

    SciTech Connect

    McGarry, M. B. Den Hartog, D. J.; Goetz, J. A.; Johnson, J.; Franz, P.

    2014-09-15

    Silicon photodiodes used for soft x-ray detection typically have a thin metal electrode partially covering the active area of the photodiode, which subtly alters the spectral sensitivity of the photodiode. As a specific example, AXUV4BST photodiodes from International Radiation Detectors have a 1.0 μm thick aluminum frame covering 19% of the active area of the photodiode, which attenuates the measured x-ray signal below ∼6 keV. This effect has a small systematic impact on the electron temperature calculated from measurements of soft x-ray bremsstrahlung emission from a high-temperature plasma. Although the systematic error introduced by the aluminum frame is only a few percent in typical experimental conditions on the Madison Symmetric Torus, it may be more significant for other instruments that use similar detectors.

  7. Double-layer electrode based on TiO2 nanotubes arrays for enhancing photovoltaic properties in dye-sensitized solar cells.

    PubMed

    He, Zuoli; Que, Wenxiu; Sun, Peng; Ren, Jiangbo

    2013-12-26

    The present work reports a rapid and facile method to fabricate a novel double-layer TiO2 photoanode, which is based on highly ordered TiO2 nanotube arrays and monodispersive scattering microspheres. This double-layer TiO2 sphere/TNTA photoanode have got many unique structural and optical properties from TiO2 scattering microspheres, such as high specific surface area, multiple interparticle scattering, and efficient light-harvesting. Results indicate that this as-fabricated double-layer TiO2 sphere/TNTA front-illumination dye-sensitized solar cell, which is fabricated from the TiO2 nanotube arrays with a 17.4 μm length after TiCl4 treatment, exhibits a pronounced power conversion efficiency of 7.24% under an AM1.5 G irradiation, which can be attributed to the increased incident photon-to-current conversion and light-harvesting efficiency.

  8. Femtosecond laser-drilling-induced HgCdTe photodiodes.

    PubMed

    Zha, F-X; Li, M S; Shao, J; Yin, W T; Zhou, S M; Lu, X; Guo, Q T; Ye, Z H; Li, T X; Ma, H L; Zhang, B; Shen, X C

    2010-04-01

    Femtosecond-laser drilling may induce holes in HgCdTe with morphology similar to that induced by ion-milling in loophole technique. So-formed hole structures are proven to be pn junction diodes by the laser beam induced current characterization as well as the conductivity measurement. Transmission and photoluminescence spectral measurements on a n-type dominated hole-array structure give rise to different results from those of an ion-milled sample.

  9. Microlens arrays

    NASA Astrophysics Data System (ADS)

    Hutley, Michael C.; Stevens, Richard F.; Daly, Daniel J.

    1992-04-01

    Microlenses have been with us for a long time as indeed the very word lens reminds us. Many early lenses,including those made by Hooke and Leeuwenhoek in the 17th century were small and resembled lentils. Many languages use the same word for both (French tilentillelt and German "Linse") and the connection is only obscure in English because we use the French word for the vegetable and the German for the optic. Many of the applications for arrays of inicrolenses are also well established. Lippmann's work on integral photography at the turn of the century required lens arrays and stimulated an interest that is very much alive today. At one stage, lens arrays played an important part in high speed photography and various schemes have been put forward to take advantage of the compact imaging properties of combinations of lens arrays. The fact that many of these ingenious schemes have not been developed to their full potential has to a large degree been due to the absence of lens arrays of a suitable quality and cost.

  10. Filter arrays

    DOEpatents

    Page, Ralph H.; Doty, Patrick F.

    2017-08-01

    The various technologies presented herein relate to a tiled filter array that can be used in connection with performance of spatial sampling of optical signals. The filter array comprises filter tiles, wherein a first plurality of filter tiles are formed from a first material, the first material being configured such that only photons having wavelengths in a first wavelength band pass therethrough. A second plurality of filter tiles is formed from a second material, the second material being configured such that only photons having wavelengths in a second wavelength band pass therethrough. The first plurality of filter tiles and the second plurality of filter tiles can be interspersed to form the filter array comprising an alternating arrangement of first filter tiles and second filter tiles.

  11. A comparison of imaging methods for use in an array biosensor.

    PubMed

    Golden, Joel P; Ligler, Frances S

    2002-09-01

    An array biosensor has been developed which uses an actively-cooled, charge-coupled device (CCD) imager. In an effort to save money and space, a complementary metal-oxide semiconductor (CMOS) camera and photodiode were tested as replacements for the cooled CCD imager. Different concentrations of CY5 fluorescent dye in glycerol were imaged using the three different detection systems with the same imaging optics. Signal discrimination above noise was compared for each of the three systems.

  12. A comparison of imaging methods for use in an array biosensor

    NASA Technical Reports Server (NTRS)

    Golden, Joel P.; Ligler, Frances S.

    2002-01-01

    An array biosensor has been developed which uses an actively-cooled, charge-coupled device (CCD) imager. In an effort to save money and space, a complementary metal-oxide semiconductor (CMOS) camera and photodiode were tested as replacements for the cooled CCD imager. Different concentrations of CY5 fluorescent dye in glycerol were imaged using the three different detection systems with the same imaging optics. Signal discrimination above noise was compared for each of the three systems.

  13. A comparison of imaging methods for use in an array biosensor

    NASA Technical Reports Server (NTRS)

    Golden, Joel P.; Ligler, Frances S.

    2002-01-01

    An array biosensor has been developed which uses an actively-cooled, charge-coupled device (CCD) imager. In an effort to save money and space, a complementary metal-oxide semiconductor (CMOS) camera and photodiode were tested as replacements for the cooled CCD imager. Different concentrations of CY5 fluorescent dye in glycerol were imaged using the three different detection systems with the same imaging optics. Signal discrimination above noise was compared for each of the three systems.

  14. Use of a vacuum-planar photodiode to drive an electro-optic Q switch directly.

    PubMed

    Stankov, K A; Milev, I Y

    1991-12-20

    A vacuum photodiode was used to drive a Pockels cell directly in an optical-feedback arrangement. This technique was used to achieve Q switching and a single-longitudinal-mode operation in a flash-lamp-pumped Nd:YAG laser. Synchronization within 2 ns with an external short-pulse laser source was demonstrated.

  15. Recent Advances in Ultra-High-Speed Waveguide Photodiodes for Optical Communication Systems

    NASA Astrophysics Data System (ADS)

    Makita, Kikuo; Shiba, Kazuhiro; Nakata, Takeshi; Mizuki, Emiko; Watanabe, Sawaki

    This paper describes the recent advances in semiconductor photodiodes for use in ultra-high-speed optical systems. We developed two types of waveguide photodiodes (WG-PD) — an evanescently coupled waveguide photodiode (EC-WG-PD) and a separated-absorption-and-multiplication waveguide avalanche photodiode (WG-APD). The EC-WG-PD is very robust under high optical input operation because of its distribution of photo current density along the light propagation. The EC-WG-PD simultaneously exhibited a high external quantum efficiency of 70% for both 1310 and 1550nm, and a wide bandwidth of more than 40GHz. The WG-APD, on the other hand, has a wide bandwidth of 36.5GHz and a gain-bandwidth product of 170GHz as a result of its small waveguide mesa structure and a thin multiplication layer. Record high receiver sensitivity of -19.6dBm at 40Gbps was achieved. Additionally, a monolithically integrated dual EC-WG-PD for differential phase shift-keying (DPSK) systems was developed. Each PD has equivalent characteristics with 3-dB-down bandwidth of more than 40GHz and external quantum efficiency of 70% at 1550nm.

  16. Experimental analysis of a novel and low-cost pin photodiode dosimetry system for diagnostic radiology

    NASA Astrophysics Data System (ADS)

    Nazififard, Mohammad; Suh, Kune Y.; Mahmoudieh, Afshin

    2016-07-01

    Silicon PIN photodiode has recently found broad and exciting applications in the ionizing radiation dosimetry. In this study a compact and novel dosimetry system using a commercially available PIN photodiode (BPW34) has been experimentally tested for diagnostic radiology. The system was evaluated with clinical beams routinely used for diagnostic radiology and calibrated using a secondary reference standard. Measured dose with PIN photodiode (Air Kerma) varied from 10 to 430 μGy for tube voltages from 40 to 100 kVp and tube current from 0.4 to 40 mAs. The minimum detectable organ dose was estimated to be 10 μGy with 20% uncertainty. Results showed a linear correlation between the PIN photodiode readout and dose measured with standard dosimeters spanning doses received. The present dosimetry system having advantages of suitable sensitivity with immediate readout of dose values, low cost, and portability could be used as an alternative to passive dosimetry system such as thermoluminescent dosimeter for dose measurements in diagnostic radiology.

  17. Temperature-Dependent Detectivity of Near-Infrared Organic Bulk Heterojunction Photodiodes.

    PubMed

    Wu, Zhenghui; Yao, Weichuan; London, Alexander E; Azoulay, Jason D; Ng, Tse Nga

    2017-01-18

    Bulk heterojunction photodiodes are fabricated using a new donor-acceptor polymer with a near-infrared absorption edge at 1.2 μm, achieving a detectivity up to 10(12) Jones at a wavelength of 1 μm and an excellent linear dynamic range of 86 dB. The photodiode detectivity is maximized by operating at zero bias to suppress dark current, while a thin 175 nm active layer is used to facilitate charge collection without reverse bias. Analysis of the temperature dependence of the dark current and spectral response demonstrates a 2.8-fold increase in detectivity as the temperature was lowered from 44 to -12 °C, a relatively small change when compared to that of inorganic-based devices. The near-infrared photodiode shows a switching speed reaching up to 120 μs without an external bias. An application using our NIR photodiode to detect arterial pulses of a fingertip is demonstrated.

  18. Influence of hot-carrier luminescence from avalanche photodiodes on time-correlated photon detection.

    PubMed

    Ulu, G; Sergienko, A V; Unlü, M S

    2000-05-15

    We present the results of our time-resolved measurements of hot-carrier luminescence from passively quenched Geiger-mode avalanche photodiodes. In time-correlated photon-counting (TCPC) experiments, hot-carrier luminescence interferes overwhelmingly with the coincidence spectrum, which results in artifacts. This potential problem should be taken into account in setting up TCPC experiments.

  19. Characterization of silicon avalanche photodiodes for photon correlation measurements. 3: Sub-Geiger operation.

    PubMed

    Brown, R G; Daniels, M

    1989-11-01

    We continue examination of the photon correlation properties of silicon avalanche photodiodes operated in the single-photon counting mode by extending their operation from that of passive [Appl. Opt. 25, 4122-4126 (1986)] and active [Appl. Opt. 26, 2383-2389 (1987)] quenching to the sub-Geiger mode, with potential for high quantum efficiency and very low afterpulsing.

  20. Photon Detection with Cooled Avalanche Photodiodes: Theory and Preliminary Experimental Results

    NASA Technical Reports Server (NTRS)

    Robinson, D. L.; Hays, D. A.

    1985-01-01

    Avalanche photodiodes (APDs) can be operated in a geiger-tube mode so that they can respond to single electron events and thus be used as photon counting detectors. Operational characteristics and theory of APDs while used in this mode are analyzed and assessed. Preliminary experimental investigation of several commercially available APDs has commenced, and initial results for dark count statistics are presented.