40 CFR 63.1544 - Standards for fugitive dust sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... according to, a standard operating procedures manual that describes in detail the measures that will be put... (c) of this section, the standard operating procedures manual shall be submitted to the Administrator... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Standards for fugitive dust sources. 63...

40 CFR 63.1544 - Standards for fugitive dust sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... according to, a standard operating procedures manual that describes in detail the measures that will be put... (c) of this section, the standard operating procedures manual shall be submitted to the Administrator... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Standards for fugitive dust sources. 63...

Measurement of Fugitive Dust Emissions and Visible Emissions.

ERIC Educational Resources Information Center

McKee, Herbert C.

The method of measuring fugitive dust emission utilized by the Texas Air Control Board is described in this presentation for the 12th Conference on Methods in Air Pollution and Industrial Hygiene Studies, University of Southern California, April, 1971. The measuring procedure, precautions, expected results, and legal acceptance of the method are…

75 FR 67784 - STP Nuclear Operating Company South Texas Project Electric Generating Station, Units 3 and 4...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-03

.... Mitigation measures, such as operational controls and practices, worker training, use of personal protective... equipment emissions, and fugitive dust caused by earth-moving activities. As stated in the ER for the COL... fugitive dust and vehicle and equipment emissions, including water suppression, covering truck loads and...

Preliminary assessment of an economical fugitive road dust sampler for the collection of bulk samples for geochemical analysis.

PubMed

Witt, Emitt C; Wronkiewicz, David J; Shi, Honglan

2013-01-01

Fugitive road dust collection for chemical analysis and interpretation has been limited by the quantity and representativeness of samples. Traditional methods of fugitive dust collection generally focus on point-collections that limit data interpretation to a small area or require the investigator to make gross assumptions about the origin of the sample collected. These collection methods often produce a limited quantity of sample that may hinder efforts to characterize the samples by multiple geochemical techniques, preserve a reference archive, and provide a spatially integrated characterization of the road dust health hazard. To achieve a "better sampling" for fugitive road dust studies, a cyclonic fugitive dust (CFD) sampler was constructed and tested. Through repeated and identical sample collection routes at two collection heights (50.8 and 88.9 cm above the road surface), the products of the CFD sampler were characterized using particle size and chemical analysis. The average particle size collected by the cyclone was 17.9 μm, whereas particles collected by a secondary filter were 0.625 μm. No significant difference was observed between the two sample heights tested and duplicates collected at the same height; however, greater sample quantity was achieved at 50.8 cm above the road surface than at 88.9 cm. The cyclone effectively removed 94% of the particles >1 μm, which substantially reduced the loading on the secondary filter used to collect the finer particles; therefore, suction is maintained for longer periods of time, allowing for an average sample collection rate of about 2 g mi. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Source apportionment of size-fractionated particles during the 2013 Asian Youth Games and the 2014 Youth Olympic Games in Nanjing, China.

PubMed

Chen, Pulong; Wang, Tijian; Lu, Xiaobo; Yu, Yiyong; Kasoar, Matthew; Xie, Min; Zhuang, Bingliang

2017-02-01

In this study, samples of size-fractionated particulate matter were collected continuously using a 9-size interval cascade impactor at an urban site in Nanjing, before, during and after the Asian Youth Games (AYG), from July to September of 2013, and the Youth Olympic Games (YOG), from July to September of 2014. First, elemental concentrations, water-soluble ions including Cl - , NO 3 - , SO 4 2- , NH 4 + , K + , Na + and Ca 2+ , organic carbon (OC) and elemental carbon (EC) were analysed. Then, the source apportionment of the fine and coarse particulate matter was carried out using the chemical mass balance (CMB) model. The average PM 10 concentrations were 90.4±20.0μg/m 3 during the 2013 AYG and 70.6±25.3μg/m 3 during the 2014 YOG. For PM 2.1, the average concentrations were 50.0±12.8μg/m 3 in 2013 and 34.6±17.0μg/m 3 in 2014. Investigations showed that the average concentrations of particles declined significantly from 2013 to 2014, and concentrations were at the lowest levels during the events. Results indicated that OC, EC, sulfate and crustal elements have significant monthly and size-based variations. The major components, including crustal elements, water-soluble ions and carbonaceous aerosol accounted for 75.3-91.9% of the total particulate mass concentrations during the sampling periods. Fugitive dust, coal combustion dust, iron dust, construction dust, soil dust, vehicle exhaust, secondary aerosols and sea salt have been classified as the main emissions in Nanjing. The source apportionment results indicate that the emissions from fugitive dust, which was the most abundance emission source during the 2013 AYG, contributed to 23.0% of the total particle mass. However, fugitive dust decreased to 6.2% of the total particle mass during the 2014 YOG. Construction dust (14.7% versus 7.8% for the AYG and the YOG, respectively) and secondary sulfate aerosol (9.3% versus 8.0% for the AYG and the YOG, respectively) showed the same trend as fugitive dust, suggesting that the mitigation measures of controlling particles from the paved roads, construction and industry worked more efficiently during the YOG. Copyright © 2016 Elsevier B.V. All rights reserved.

40 CFR 63.1541 - Applicability.

Code of Federal Regulations, 2013 CFR

2013-07-01

..., preliminary treatment, refining and casting operations, process fugitive sources, and fugitive dust sources... the blast furnace, electric smelting furnace with a converter or reverberatory furnace, and slag fuming furnace process units. The preliminary treatment process includes the drossing kettles and dross...

40 CFR 63.1541 - Applicability.

Code of Federal Regulations, 2012 CFR

2012-07-01

..., preliminary treatment, refining and casting operations, process fugitive sources, and fugitive dust sources... the blast furnace, electric smelting furnace with a converter or reverberatory furnace, and slag fuming furnace process units. The preliminary treatment process includes the drossing kettles and dross...

40 CFR 63.1541 - Applicability.

Code of Federal Regulations, 2014 CFR

2014-07-01

..., preliminary treatment, refining and casting operations, process fugitive sources, and fugitive dust sources... the blast furnace, electric smelting furnace with a converter or reverberatory furnace, and slag fuming furnace process units. The preliminary treatment process includes the drossing kettles and dross...

Fugitive Dust Emission Factors for Puff and Mobile Military Sources Measured by Micro-pulse Lidar - A Summary of Results

NASA Astrophysics Data System (ADS)

Yuen, W.; Du, K.; Rood, M. J.; Kemme, M. R.; Kim, B.; Hashmonay, R. A.

2010-12-01

A summary of the development of a novel optical remote sensing (ORS) method that determined fugitive dust emission factors for unique military activities is described for puff and mobile sources. Four field campaigns characterized artillery back blasts as puff sources (M549A1 and M107), and movement of military vehicles (M1A1, M113, Bradley Fighting Vehicle (BFV), M88, M270, M577, and HEMTT) and an airborne helicopter (Bell 210) as mobile sources. The ORS method includes a Micro-Pulse Lidar (MPL) and a reflective target that determines one-dimensional (1-D) light extinction coefficient profiles. The MPL was mounted on a positioner that allows the MPL to automatically scan vertically, which allowed 1-D extinction coefficient profiles to be measured at select angles from horizontal. Two-dimensional (2-D) light extinction coefficient profiles were then determined by interpolating the 1-D extinction profiles measured at select angles. Dust property, in the form of the mass extinction efficiency (MEE), was measured using Open Path- Fourier Transform Infrared Spectrometry (OP-FTIR) and Open Path- Laser Transmissometry (OP-LT) in the first three field campaigns and an OP-LT and DustTrak™ in the fourth field campaign. MEE was used to convert the 2-D light extinction coefficient profiles to 2-D dust mass concentration profiles. Emission factors were determined by integrating the 2-D mass concentration profiles with measured wind vectors. Results from these field campaigns show that: 1) artillery with stronger recoiling forces generates more fugitive dust; 2) the dust emission factors for tracked vehicles are correlated with vehicle momentum; 3) emission factor decreases with increasing speed for airborne helicopters; and 4) wheeled vehicles (HEMTT) generate more fugitive dust than tracked vehicles (M88, M270, M577).

Isotopically constrained lead sources in fugitive dust from unsurfaced roads in the southeast Missouri mining district.

PubMed

Witt, Emitt C; Pribil, Michael J; Hogan, John P; Wronkiewicz, David J

2016-09-01

The isotopic composition of lead (Pb) in fugitive dust suspended by a vehicle from 13 unsurfaced roads in Missouri was measured to identify the source of Pb within an established long-term mining area. A three end-member model using (207)Pb/(206)Pb and concentration as tracers resulted in fugitive dust samples plotting in the mixing field of well characterized heterogeneous end members. End members selected for this investigation include the (207)Pb/(206)Pb for 1) a Pb-mixture representing mine tailings, 2) aerosol Pb-impacted soils within close proximity to the Buick secondary recycling smelter, and 3) an average of soils, rock cores and drill cuttings representing the background conditions. Aqua regia total concentrations and (207)Pb/(206)Pb of mining area dust suggest that 35.4-84.3% of the source Pb in dust is associated with the mine tailings mixture, 9.1-52.7% is associated with the smelter mixture, and 0-21.6% is associated with background materials. Isotope ratios varied minimally within the operational phases of sequential extraction suggesting that mixing of all three Pb mixtures occurs throughout. Labile forms of Pb were attributed to all three end members. The extractable carbonate phase had as much as 96.6% of the total concentration associated with mine tailings, 51.8% associated with smelter deposition, and 34.2% with background. The next most labile geochemical phase (Fe + Mn Oxides) showed similar results with as much as 85.3% associated with mine tailings, 56.8% associated with smelter deposition, and 4.2% associated with the background soil. Published by Elsevier Ltd.

Isotopically constrained lead sources in fugitive dust from unsurfaced roads in the southeast Missouri mining district

USGS Publications Warehouse

Witt, Emitt C.; Pribil, Michael; Hogan, John P; Wronkiewicz, David

2016-01-01

The isotopic composition of lead (Pb) in fugitive dust suspended by a vehicle from 13 unsurfaced roads in Missouri was measured to identify the source of Pb within an established long-term mining area. A three end-member model using 207Pb/206Pb and concentration as tracers resulted in fugitive dust samples plotting in the mixing field of well characterized heterogeneous end members. End members selected for this investigation include the 207Pb/206Pb for 1) a Pb-mixture representing mine tailings, 2) aerosol Pb-impacted soils within close proximity to the Buick secondary recycling smelter, and 3) an average of soils, rock cores and drill cuttings representing the background conditions. Aqua regia total concentrations and 207Pb/206Pb of mining area dust suggest that 35.4–84.3% of the source Pb in dust is associated with the mine tailings mixture, 9.1–52.7% is associated with the smelter mixture, and 0–21.6% is associated with background materials. Isotope ratios varied minimally within the operational phases of sequential extraction suggesting that mixing of all three Pb mixtures occurs throughout. Labile forms of Pb were attributed to all three end members. The extractable carbonate phase had as much as 96.6% of the total concentration associated with mine tailings, 51.8% associated with smelter deposition, and 34.2% with background. The next most labile geochemical phase (Fe + Mn Oxides) showed similar results with as much as 85.3% associated with mine tailings, 56.8% associated with smelter deposition, and 4.2% associated with the background soil.

Managing dust on unpaved roads and airports.

DOT National Transportation Integrated Search

2014-10-01

Fugitive dust emanating from vehicle traffic on unpaved roads and runways can have significant impacts on safety, health, quality of life, and the cost : of maintenance. Managing dust provides a means of reducing these impacts. Shearing forces create...

Guidelines for the Use of Synthetic Fluid Dust Control Palliatives on Unpaved Roads

DOT National Transportation Integrated Search

2017-07-01

The amount of small soil particles, dust, lost from typical unpaved roads to fugitive dust is staggering. A 1 km stretch of unpaved road can contribute over 2400 kg of dust to the atmosphere (4.2 ton/mile) in a typical 3-month summer season. Road man...

Proceedings from the Workshop on Research Needs for Assessment and Management of Non-Point Air Emissions from Department of Defense Activities held in Research Triangle Park, North Carolina on 19-21 February 2008

DTIC Science & Technology

2008-10-01

Chow, J.C. (2006). Feasibility of soil dust source apportionment by the pyrolysis-gas chromatography/mass spectrometry method. J. Air Waste Manage...receptor-oriented source apportionment models. • Develop monitoring methods to determine source and fence line amounts of fugitive dust emissions for...offsite impact, including evaluation with receptor- oriented source apportionment models 76 8.8.1 Background 76 8.8.2 Significance 77 8.8.3

Investigation of fugitive dust emissions from nepheline syenite mine tailings near Nephton, Ontario

NASA Astrophysics Data System (ADS)

Ogungbemide, Damilare Immanuel

A set of experiments was designed to investigate the factors--atmospheric and surficial--controlling fugitive dust emissions from the tailings ponds of UNIMIN Canada, a mining company that extracts and produces nepheline syenite (feldspar) at two adjacent sites (Nephton and Blue Mountain) located north of Havelock, Ontario. Using wind tunnel measurements, the combined influence of relative humidity and temperature (represented by the absolute matric potential, |psi|) on dust emission was quantified and modeled. About 300 experimental runs were conducted under various conditions of wind speed (4.5-6.25 ms -1), temperature (0-30°C) and relative humidity (10-70%). Generally, dust flux decreased as a logarithmic function of matric potential, with dust emission strongly suppressed for RH > 60% or |psi|<70 MPa. Field measurements also confirmed the role of relative humidity in suppressing dust emission. Irrigation, which is widely used by mines to control dust emissions, reduced ambient dust concentration at the study site only about 60% of the time, with the highest mitigation efficiencies (average of 90%) occurring when the total depth of water applied intermittently over a few hours was greater than 10 mm. In the absence of emergent vegetation, the terrestrial laser scanning (TLS) technique proved to be a promising method for detecting and estimating both spatial and temporal moisture content changes in the field environment, particularly for the very thin surface layer, which is the most important layer for dust emission. It is hoped that the results from this study will help mines to optimize their dust management programs for the range of climate and topographic conditions found at their sites, and also serve as a source of useful information and input data for atmospheric dispersion models, such as AERMOD and CALPUFF, whose accuracy depends on the quality of the input data such as the emission rate.

KEEPING DUST UNDER THE CARPET

EPA Science Inventory

The paper gives results of a study of civil engineering fabrics applied to fugitive dust problems. The fabrics, commonly used for ground stabilization, subsurface drainage, railroad construction and maintenance, sediment control, and erosion control, are available from Celanese, ...

EFFECT OF VEHICLE CHARACTERISTICS ON UNPAVED ROAD DUST EMISSIONS

EPA Science Inventory

This paper presents PM₁₀ fugitive dust emission factors for a range of vehicles types and examines the influence of vehicle and wake characteristics on the strength of emissions from an unpaved road.

Numerical Validation of a Near-Field Fugitive Dust Model for Vehicles Moving on Unpaved Surfaces

DTIC Science & Technology

2013-02-05

vehicles such as the numerical models developed at George mason University[2, 3]. Their model focused on represent- ing vehicles in a virtual...vehicles trav- eling on unpaved roads. In Proceedings of the conference on metroplitan physical environment (1977), G . Heisler and L. Herrington, Eds., pp...295–302. [5] Etyemezian, V., Gillies, J., Huhns, H., Nikolic, D., Watson, J., Ve- ranth, J., Laben, R., Seshadri, G ., and Gillette, D. Field testing

Measurement and Modeling of Fugitive Dust from Off Road DoD Activities

DTIC Science & Technology

2017-12-08

each soil and vehicle type (see Table 2). Note, no tracked vehicles were run at YTC. CT is the curve track sampling location, CR is the curve ridge...Soil is SL = sandy loam. ...................... 116 Figure 35. Single-event Wind Erosion Evaluation Program (SWEEP) Run example results. ... 121...Figure 36. Single-event Wind Erosion Evaluation Program (SWEEP) Threshold Run example results screen

40 CFR 63.1651 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... continuously monitor relative particulate matter loadings. Capture system means the equipment (including hoods... due to wind or mechanical inducement such as vehicle traffic. Fugitive dust sources include plant...

40 CFR 63.1651 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... continuously monitor relative particulate matter loadings. Capture system means the equipment (including hoods... due to wind or mechanical inducement such as vehicle traffic. Fugitive dust sources include plant...

40 CFR 63.1651 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... continuously monitor relative particulate matter loadings. Capture system means the equipment (including hoods... due to wind or mechanical inducement such as vehicle traffic. Fugitive dust sources include plant...

A computational study of particulate emissions from an open pit quarry under neutral atmospheric conditions

NASA Astrophysics Data System (ADS)

Silvester, S. A.; Lowndes, I. S.; Hargreaves, D. M.

2009-12-01

The extraction of minerals from surface mines and quarries can produce significant fugitive dust emissions as a result of site activities such as blasting, road haulage, loading, crushing and stockpiling. If uncontrolled, these emissions can present serious environmental, health, safety and operational issues impacting both site personnel and the wider community. The dispersion of pollutant emissions within the atmosphere is principally determined by the background wind systems characterized by the atmospheric boundary layer (ABL). This paper presents an overview of the construction and solution of a computational fluid dynamics (CFD) model to replicate the development of the internal ventilation regime within a surface quarry excavation due to the presence of a neutral ABL above this excavation. This model was then used to study the dispersion and deposition of fugitive mineral dust particles generated during rock blasting operations. The paths of the mineral particles were modelled using Lagrangian particle tracking. Particles of four size fractions were released from five blast locations for eight different wind directions. The study concluded that dependent on the location of the bench blast within the quarry and the direction of the wind, a mass fraction of between 0.3 and 0.6 of the emitted mineral particles was retained within the quarry. The retention was largest when the distance from the blast location to the downwind pit boundary was greatest.

Fugitive dust mitigation for PM{sub 10} attainment in the western Mojave Desert: Recommendations on revegetation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grantz, D.A.; Vaughn, D.L.; Roberts, E.

1997-12-31

Methods to suppress fugitive dust and associated violations of federal PM{sub 10} standards in the western Mojave Desert, following removal of native vegetation by tillage or overgrazing, have been under investigation by a multi-agency task force for several years. Interim recommendations are now possible for this area of high winds, low rainfall, and mostly arable soil with patchy blowing sand. There can be no guarantee of success in any revegetation program in the desert, but the greatest probability of success in this area can be attained by using the native shrub Atriplex canescens, whether direct seeded or transplanted. No additionalmore » nitrogen should be added, and excess nitrogen should be removed if possible, perhaps by a preliminary cropping of barley. This will itself stabilize the soil surface in the short term. Young plants should be protected from herbivory and the harsh elements by using plastic cones. Irrigation is helpful if available. In areas located near native populations of rabbitbrush annual plant cover should be burned but no tillage or other soil disturbance should be imposed, as this facilitates invasion of annual species, including russian thistle, and prevents establishment of rabbitbrush. In sandy areas, seeding with Indian ricegrass may be more effective than with A. canescens. For immediate, short-term, mitigation of blowing dust, furrowing alone and installation of windfences may be effective. Rainfall exhibits high annual variability in arid regions. Absence of fugitive dust emissions in rainy periods, associated with ground cover by annual vegetation, is unlikely to survive several years of low, but normal, rainfall. It is precisely during those periods when rainfall is adequate that long-term revegetation with shrubs has the best chance of success.« less

Health Effects of Petroleum Coke

EPA Pesticide Factsheets

Significant quantities of fugitive dust from pet coke storage and handling operations present a health risk. EPA’s research suggests that petcoke does not pose a different health risk than similar-sized particulate matter (PM10).

Dust control products at Hagerman National Wildlife Refuge, Texas: environmental safety and performance

USGS Publications Warehouse

Kunz, Bethany K.; Little, Edward E.

2015-01-01

Controlling fugitive dust while protecting natural resources is a challenge faced by all managers of unpaved roads. Unfortunately, road managers choosing between dust control products often have little objective environmental information to aid their decisions. To address this information gap, the U.S. Geological Survey and the U.S. Fish and Wildlife Service collaborated on a field test of three dust control products with the objectives of (a) evaluating product performance under real-world conditions, (b) verifying the environmental safety of products identified as practically nontoxic in laboratory tests, and (c) testing the feasibility of several environmental monitoring techniques for use in dust control tests. In cooperation with refuge staff and product vendors, three products (one magnesium chloride plus binder, one cellulose, and one synthetic fluid plus binder) were applied in July 2012 to replicated road sections at the Hagerman National Wildlife Refuge in Texas. These sections were monitored periodically for 12 months after application. Product performance was assessed by mobile-mounted particulate-matter meters measuring production of fugitive dust and by observations of road conditions. Environmental safety was evaluated through on-site biological observations and leaching tests with samples of treated aggregate. All products reduced dust and improved surface condition during those 12 months. Planned environmental measurements were not always compatible with day-to-day refuge management actions; this incompatibility highlighted the need for flexible biological monitoring plans. As one of the first field tests of dust suppressants that explicitly incorporated biological endpoints, this effort provides valuable information for improving field tests and for developing laboratory or semifield alternatives.

Fugitive Dust Emissions: Development of a Real-time Monitor

DTIC Science & Technology

2011-10-01

the mechanical disturbance of soils which injects particles into the air. Common sources of FD include vehicles driving on unpaved roads...agricultural tilling, and heavy construction operations. For these sources the dust-generation process is caused by two basic physical phenomena...visibility, source apportionment , etc. The PM10 standard set by the U.S. Environmental Protection Agency in 1987 is an example of size-selective

Optical remote sensing to quantify fugitive particulate mass emissions from stationary short-term and mobile continuous sources: part II. Field applications.

PubMed

Du, Ke; Yuen, Wangki; Wang, Wei; Rood, Mark J; Varma, Ravi M; Hashmonay, Ram A; Kim, Byung J; Kemme, Michael R

2011-01-15

Quantification of emissions of fugitive particulate matter (PM) into the atmosphere from military training operations is of interest by the United States Department of Defense. A new range-resolved optical remote sensing (ORS) method was developed to quantify fugitive PM emissions from puff sources (i.e., artillery back blasts), ground-level mobile sources (i.e., movement of tracked vehicles), and elevated mobile sources (i.e., airborne helicopters) in desert areas that are prone to generating fugitive dust plumes. Real-time, in situ mass concentration profiles for PM mass with particle diameters <10 μm (PM(10)) and <2.5 μm (PM(2.5)) were obtained across the dust plumes that were generated by these activities with this new method. Back blasts caused during artillery firing were characterized as a stationary short-term puff source whose plumes typically dispersed to <10 m above the ground with durations of 10-30 s. Fugitive PM emissions caused by artillery back blasts were related to the zone charge and ranged from 51 to 463 g PM/firing for PM(10) and 9 to 176 g PM/firing for PM(2.5). Movement of tracked vehicles and flying helicopters was characterized as mobile continuous sources whose plumes typically dispersed 30-50 m above the ground with durations of 100-200 s. Fugitive PM emissions caused by moving tracked vehicles ranged from 8.3 to 72.5 kg PM/km for PM(10) and 1.1 to 17.2 kg PM/km for PM(2.5), and there was no obvious correlation between PM emission and vehicle speed. The emission factor for the helicopter flying at 3 m above the ground ranged from 14.5 to 114.1 kg PM/km for PM(10) and 5.0 to 39.5 kg PM/km for PM(2.5), depending on the velocity of the helicopter and type of soil it flies over. Fugitive PM emissions by an airborne helicopter were correlated with helicopter speed for a particular soil type. The results from this range-resolved ORS method were also compared with the data obtained with another path-integrated ORS method and a Flux Tower method.

40 CFR 52.470 - Identification of plan.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 44431 Section 604 Open Burning 3/15/85 8/28/95, 60 FR 44431 Section 605 Control of Fugitive Dust 3/15/85... 26Civil Fines for Moving and Non-Moving Violations Section 2600.1 Infraction: Inspection, Registration...

40 CFR 52.470 - Identification of plan.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 44431 Section 604 Open Burning 3/15/85 8/28/95, 60 FR 44431 Section 605 Control of Fugitive Dust 3/15/85... 26Civil Fines for Moving and Non-Moving Violations Section 2600.1 Infraction: Inspection, Registration...

EPA Requires Beemsterboer and KCBX to Take Action

EPA Pesticide Factsheets

In response to complaints of fugitive pet coke dust, EPA issued Clean Air Act Section 114 information request letters to KCBX Terminals and Beemsterboer Slag petroleum coke facilities, and ordered onsite air quality monitoring and petcoke sample analysis.

40 CFR 52.620 - Identification of plan.

Code of Federal Regulations, 2013 CFR

2013-07-01

... on applications 11/29/1982 08/18/1983, 48 FR 37403 11-60-26 Fugitive dust 11/29/1982 08/18/1983, 48..., and 1997 and 2006 Fine Particulate Matter (PM2.5) National Ambient Air Quality Standards Statewide 12...

40 CFR 52.620 - Identification of plan.

Code of Federal Regulations, 2014 CFR

2014-07-01

... on applications 11/29/1982 08/18/1983, 48 FR 37403 11-60-26 Fugitive dust 11/29/1982 08/18/1983, 48... 2006 PM2.5 national ambient air quality standards. 342B-50 Disposition of collected fines and penalties...

40 CFR 63.1651 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... due to wind or mechanical inducement such as vehicle traffic. Fugitive dust sources include plant roadways, yard areas, and outdoor material storage and transfer operations. Furnace power input means the resistive electrical power consumption of a submerged arc furnace, expressed as megawatts (MW). Malfunction...

40 CFR 63.1651 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... due to wind or mechanical inducement such as vehicle traffic. Fugitive dust sources include plant roadways, yard areas, and outdoor material storage and transfer operations. Furnace power input means the resistive electrical power consumption of a submerged arc furnace, expressed as megawatts (MW). Malfunction...

Atmospheric Fate and Transport of Agricultural Dust and Ammonia

NASA Astrophysics Data System (ADS)

Hiranuma, N.; Brooks, S. D.; Thornton, D. C.; Auvermann, B. W.; Fitz, D. R.

2008-12-01

Agricultural fugitive dust and odor are significant sources of localized air pollution in the semi-arid southern Great Plains. Daily episodes of ground-level fugitive dust emissions from the cattle feedlots associated with increased cattle activity in the early evenings are routinely observed, while consistently high ammonia is observed throughout the day. Here we present measurements of aerosol size distributions and concentrations of gas and particulate phase ammonia species collected at a feedlot in Texas during summers of 2006, 2007 and 2008. A GRIMM sequential mobility particle sizer and GRIMM 1.108 aerosol spectrometer were used to determine aerosol size distributions in the range of 10 nm to 20 µm aerodynamic diameter at the downwind and upwind edges of the facility. Using aqueous scrubbers, simultaneous measurements of both gas phase and total ammonia species present in the gas and particle phases were also collected. In addition to the continuous measurements at the edges of the facility, coincident aerosol and ammonia measurements were obtain at an additional site further downwind (~3.5 km). Taken together our measurements will be used to quantify aerosol and ammonia dispersion and transport. Relationships between the fate and transport of the aerosols and ammonia will be discussed.

78 FR 922 - Revisions to the California State Implementation Plan, Imperial County Air Pollution Control...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-01-07

... ) emissions from sources of fugitive dust such as unpaved roads and disturbed soils in open and agricultural... trespass and stabilize disturbed soil on open areas larger than 0.5 acres in urban areas, and larger than...

40 CFR 49.123 - General provisions.

Code of Federal Regulations, 2013 CFR

2013-07-01

..., road construction and road maintenance, fertilization, logging operations, and forest management... oil. Fugitive dust means a particulate matter emission made airborne by forces of wind, mechanical... § 49.123(a). (vii) ASTM D2880-03, Standard Specification for Gas Turbine Fuel Oils, IBR approved for...

40 CFR 49.123 - General provisions.

Code of Federal Regulations, 2011 CFR

2011-07-01

..., road construction and road maintenance, fertilization, logging operations, and forest management... oil. Fugitive dust means a particulate matter emission made airborne by forces of wind, mechanical... § 49.123(a). (vii) ASTM D2880-03, Standard Specification for Gas Turbine Fuel Oils, IBR approved for...

40 CFR 49.123 - General provisions.

Code of Federal Regulations, 2014 CFR

2014-07-01

..., road construction and road maintenance, fertilization, logging operations, and forest management... oil. Fugitive dust means a particulate matter emission made airborne by forces of wind, mechanical... § 49.123(a). (vii) ASTM D2880-03, Standard Specification for Gas Turbine Fuel Oils, IBR approved for...

40 CFR 49.123 - General provisions.

Code of Federal Regulations, 2012 CFR

2012-07-01

..., road construction and road maintenance, fertilization, logging operations, and forest management... oil. Fugitive dust means a particulate matter emission made airborne by forces of wind, mechanical... § 49.123(a). (vii) ASTM D2880-03, Standard Specification for Gas Turbine Fuel Oils, IBR approved for...

40 CFR 63.1544 - Standards for fugitive dust sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing emissions. Determination of whether such operation.... 63.1544 Section 63.1544 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...

40 CFR 63.1544 - Standards for fugitive dust sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing emissions. Determination of whether such operation.... 63.1544 Section 63.1544 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...

40 CFR 63.1544 - Standards for fugitive dust sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing emissions. Determination of whether such operation....1544 Section 63.1544 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS...

40 CFR 63.549 - Notification requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... shall submit the fugitive dust control standard operating procedures manual required under § 63.545(a) and the standard operating procedures manual for baghouses required under § 63.548(a) to the... (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission...

40 CFR 63.549 - Notification requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... shall submit the fugitive dust control standard operating procedures manual required under § 63.545(a) and the standard operating procedures manual for baghouses required under § 63.548(a) to the... (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission...

Characterization of the fugitive particulate emissions from construction mud/dirt carryout.

PubMed

Kinsey, John S; Linna, Kara J; Squier, William C; Muleski, Gregory E; Cowherd, Chatten

2004-11-01

Although the fugitive dust associated with construction mud/dirt carryout can represent a substantial portion of the particulate matter (PM) emissions inventory in nonattainment areas, it has not been well characterized by direct sampling methods. In this paper, a research program is described that directly determined both PM10 and PM2.5 (particles < or =10 and 2.5 microm in classical aerodynamic diameter, respectively) emission factors for mud/dirt carryout from a major construction project located in metropolitan Kansas City, MO. The program also assessed the contribution of automotive emissions to the total PM2.5 burden and determined the baseline emissions from the test road. As part of the study, both time-integrated and continuous exposure-profiling methods were used to assess the PM emissions, including particle size and elemental composition. This research resulted in overall PM10 and PM2.5 emission factors of 6 and 0.2 g/vehicle, respectively. Although PM10 is within the range of prior U.S. Environmental Protection Agency (EPA) guidance, the PM2.5 emission factor is far lower than previous estimates published by EPA. In addition, based on both the particle size and chemical data obtained in the study, a major portion of the PM2.5 emissions appears to be attributable to automotive exhaust from light-duty, gasoline-powered vehicles and not to the fugitive dust associated with reentrained mud/dirt carryout.

40 CFR 63.1548 - Notification requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... submit the fugitive dust control standard operating procedures manual required under § 63.1544(a) and the standard operating procedures manual for baghouses required under § 63.1547(a) to the Administrator or... (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission...

40 CFR 63.1548 - Notification requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... submit the fugitive dust control standard operating procedures manual required under § 63.1544(a) and the standard operating procedures manual for baghouses required under § 63.1547(a) to the Administrator or... (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission...

40 CFR 63.1654 - Operational and work practice standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... according to a written fugitive dust control plan must be incorporated in the operating permit for the... standards. 63.1654 Section 63.1654 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES...

40 CFR 63.1654 - Operational and work practice standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... according to a written fugitive dust control plan must be incorporated in the operating permit for the... standards. 63.1654 Section 63.1654 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES...

78 FR 52485 - Revisions to the Arizona State Implementation Plan, Maricopa County Area

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-23

...] Revisions to the Arizona State Implementation Plan, Maricopa County Area AGENCY: Environmental Protection... County Area portion of the Arizona State Implementation Plan (SIP). These revisions concern particulate matter (PM) emissions from fugitive dust sources. We are approving local statutes that regulate these...

40 CFR 63.1654 - Operational and work practice standards.

Code of Federal Regulations, 2013 CFR

2013-07-01

... according to a written fugitive dust control plan must be incorporated in the operating permit for the... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Operational and work practice standards... PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES...

CHARACTERIZATION OF MUD/DIRT CARRYOUT ONTO PAVED ROADS FROM CONSTRUCTION AND DEMOLITION ACTIVITIES

EPA Science Inventory

The report characterizes fugitive dust generated by vehicular traffic on paved streets and highways resulting from mud/dirt carryout from unpaved areas as a primary source of PM-10 (particles = or < 10 micrometers in aerodynamic diameter), and evaluates three technologies for eff...

Fugitive dust emission source profiles and assessment of selected control strategies for particulate matter at gravel processing sites in Taiwan.

PubMed

Chang, Chang-Tang; Chang, Yu-Min; Lin, Wen-Yinn; Wu, Ming-Ching

2010-10-01

Particles emitted from gravel processing sites are one contributor to worsening air quality in Taiwan. Major pollution sources at gravel processing sites include gravel and sand piles, unpaved roads, material crushers, and bare ground. This study analyzed fugitive dust emission characteristics at each pollution source using several types of particle samplers, including total suspended particulates (TSP), suspended particulate (PM10), fine suspended particulate (PM2.5), particulate sizer, and dust-fall collectors. Furthermore, silt content and moisture in the gravel were measured to develop particulate emission factors. The results showed that TSP (< 100 microm) concentrations at the boundary of gravel sites ranged from 280 to 1290 microg/m3, which clearly exceeds the Taiwan hourly air quality standard of 500 microg/m3. Moreover, PM10 concentrations, ranging from 135 to 550 microg/m3, were also above the daily air quality standard of 125 microg/m3 and approximately 1.2 and 1.5 times the PM2.5 concentrations, ranging from 105 to 470 microg/m3. The size distribution analysis reveals that mass mean diameter and geometric standard deviation ranged from 3.2 to 5.7 microm and from 2.82 to 5.51, respectively. In this study, spraying surfactant was the most effective control strategy to abate windblown dust from unpaved roads, having a control efficiency of approximately 93%, which is significantly higher than using paved road strategies with a control efficiency of approximately 45%. For paved roads, wet suppression provided the best dust control efficiencies ranging from 50 to 83%. Re-vegetation of disturbed ground had dust control efficiencies ranging from 48 to 64%.

40 CFR 49.126 - Rule for limiting fugitive particulate matter emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., and other surfaces that can create airborne dust. (iii) Full or partial enclosure of materials... particulate matter from becoming airborne. (iv) Implementation of good housekeeping practices to avoid or minimize the accumulation of dusty materials that have the potential to become airborne, and the prompt...

Use of Anthropogenic Radioisotopes to Estimate Rates of Soil Redistribution by Wind

USDA-ARS?s Scientific Manuscript database

Wind erosion results in soil degradation and fugitive dust emissions. The temporal and spatial variability of aeolian processes makes local estimates of long-term average erosion costly and time consuming. Atmospheric testing of nuclear weapons during the 1950s and 1960s resulted in previously non...

40 CFR 63.545 - Standards for fugitive dust sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... according to a standard operating procedures manual that describes in detail the measures that will be put... standard operating procedures manual shall be submitted to the Administrator or delegated authority for review and approval. (c) The controls specified in the standard operating procedures manual shall at a...

40 CFR 63.545 - Standards for fugitive dust sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

... according to a standard operating procedures manual that describes in detail the measures that will be put... standard operating procedures manual shall be submitted to the Administrator or delegated authority for review and approval. (c) The controls specified in the standard operating procedures manual shall at a...

Fugitive dust emissions from off-road vehicle maneuvers on military training lands

USDA-ARS?s Scientific Manuscript database

Off-road vehicle training can contribute to air quality degradation because of increased wind erosion as a result of soil disruption during high wind events. However, limited information exists regarding the impacts of off-road vehicle maneuvering on wind erosion potential of soils. This study was c...

40 CFR 49.124 - Rule for limiting visible emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

...% opacity limit. (3) The visible emissions from an oil-fired boiler or solid fuel-fired boiler that..., fuel, fuel oil, fugitive dust, gaseous fuel, grate cleaning, marine vessel, mobile sources, motor..., PM10, PM2.5, reference method, refuse, Regional Administrator, residual fuel oil, smudge pot, solid...

40 CFR 49.124 - Rule for limiting visible emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

...% opacity limit. (3) The visible emissions from an oil-fired boiler or solid fuel-fired boiler that..., fuel, fuel oil, fugitive dust, gaseous fuel, grate cleaning, marine vessel, mobile sources, motor..., PM10, PM2.5, reference method, refuse, Regional Administrator, residual fuel oil, smudge pot, solid...

Chemical characterization and receptor modeling of PM10 in the surroundings of the opencast lignite mines of Western Macedonia, Greece.

PubMed

Samara, Constantini; Argyropoulos, George; Grigoratos, Theodoros; Kouras, Αthanasios; Manoli, Εvangelia; Andreadou, Symela; Pavloudakis, Fragkiskos; Sahanidis, Chariton

2018-05-01

The Western Macedonian Lignite Center (WMLC) in northwestern Greece is the major lignite center in the Balkans feeding four major power plants of total power exceeding 4 GW. Concentrations of PM 10 (i.e., particulate matters with diameters ≤10 μm) are the main concern in the region, and the high levels observed are often attributed to the activities related to power generation. In this study, the contribution of fugitive dust emissions from the opencast lignite mines to the ambient levels of PM 10 in the surroundings was estimated by performing chemical mass balance (CMB) receptor modeling. For this purpose, PM 10 samples were concurrently collected at four receptor sites located in the periphery of the mine area during the cold and the warm periods of the year (November-December 2011 and August-September 2012), and analyzed for a total of 26 macro- and trace elements and ionic species (sulfate, nitrate, chloride). The robotic chemical mass balance (RCMB) model was employed for source identification/apportionment of PM 10 at each receptor site using as inputs the ambient concentrations and the chemical profiles of various sources including the major mine operations, the fly ash escaping the electrostatic filters of the power plants, and other primary and secondary sources. Mean measured PM 10 concentrations at the different sites ranged from 38 to 72 μg m -3 . The estimated total contribution of mines ranged between 9 and 22% in the cold period increasing to 36-42% in the dry warm period. Other significant sources were vehicular traffic, biomass burning, and secondary sulfate and nitrate aerosol. These results imply that more efficient measures to prevent and suppress fugitive dust emissions from the mines are needed.

Field testing of fugitive dust control techniques at a uranium mill tailings pile - 1982 Field Test, Gas Hills, Wyoming.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elmore, M.R.; Hartley, J.N.

A field test was conducted on a uranium tailings pile to evaluate the effectiveness of 15 chemical stabilizers for control of fugitive dust from uranium mill tailings. A tailings pile at the Federal American Partners (FAP) Uranium Mill, Gas Hills, Wyoming, was used for the field test. Preliminary laboratory tests using a wing tunnel were conducted to select the more promising stabilizers for field testing. Fourteen of the chemical stabilizers were applied with a field spray system pulled behind a tractor; one--Hydro Mulch--was applied with a hydroseeder. A portable weather station and data logger were installed to record the weathermore » conditions at the test site. After 1 year of monitoring (including three site visits), all of the stabilizers have degraded to some degree; but those applied at the manufacturers' recommended rate are still somewhat effective in reducing fugitive emissions. The following synthetic polymer emulsions appear to be the more effective stabilizers: Wallpol 40-133 from Reichold Chemicals, SP-400 from Johnson and March Corporation, and CPB-12 from Wen Don Corporation. Installed costs for the test plots ranged from $8400 to $11,300/ha; this range results from differences in stabilizer costs. Large-scale stabilization costs of the test materials are expected to range from $680 to $3600/ha based on FAP experience. Evaluation of the chemical stabilizers will continue for approximately 1 year. 2 references, 33 figures, 22 tables.« less

Evaluation of Uncertainties in Measuring Particulate Matter Emission Factors from Atmospheric Fugitive Sources Using Optical Remote Sensing

NASA Astrophysics Data System (ADS)

Yuen, W.; Ma, Q.; Du, K.; Koloutsou-Vakakis, S.; Rood, M. J.

2015-12-01

Measurements of particulate matter (PM) emissions generated from fugitive sources are of interest in air pollution studies, since such emissions vary widely both spatially and temporally. This research focuses on determining the uncertainties in quantifying fugitive PM emission factors (EFs) generated from mobile vehicles using a vertical scanning micro-pulse lidar (MPL). The goal of this research is to identify the greatest sources of uncertainty of the applied lidar technique in determining fugitive PM EFs, and to recommend methods to reduce the uncertainties in this measurement. The MPL detects the PM plume generated by mobile fugitive sources that are carried downwind to the MPL's vertical scanning plane. Range-resolved MPL signals are measured, corrected, and converted to light extinction coefficients, through inversion of the lidar equation and calculation of the lidar ratio. In this research, both the near-end and far-end lidar equation inversion methods are considered. Range-resolved PM mass concentrations are then determined from the extinction coefficient measurements using the measured mass extinction efficiency (MEE) value, which is an intensive PM property. MEE is determined by collocated PM mass concentration and light extinction measurements, provided respectively by a DustTrak and an open-path laser transmissometer. These PM mass concentrations are then integrated with wind information, duration of plume event, and vehicle distance travelled to obtain fugitive PM EFs. To obtain the uncertainty of PM EFs, uncertainties in MPL signals, lidar ratio, MEE, and wind variation are considered. Error propagation method is applied to each of the above intermediate steps to aggregate uncertainty sources. Results include determination of uncertainties in each intermediate step, and comparison of uncertainties between the use of near-end and far-end lidar equation inversion methods.

40 CFR 49.124 - Rule for limiting visible emissions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... emissions. (a) What is the purpose of this section? This section limits the visible emissions of air... residential buildings with four or fewer dwelling units, fugitive dust from public roads owned or maintained... sources. (d) What are the opacity limits for air pollution sources? (1) The visible emissions from an air...

40 CFR 52.1770 - Identification of plan.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 61213 Sect .0515 Particulates from Miscellaneous Industrial Processes 04/01/03 09/17/03, 68 FR 54362... Utility Boilers 08/01/91 02/14/96, 61 FR 5689 Sect .0540 Particulates from Fugitive Non-process Dust... Sect .0955 Thread Bonding Manufacturing 04/01/95 02/01/96, 62 FR 3589 Sect .0956 Glass Christmas...

Exposure-Reducing Behaviors among Residents Living near a Coal Ash Storage Site

ERIC Educational Resources Information Center

Zierold, Kristina M.; Sears, Clara G.; Brock, Guy N.

2016-01-01

Coal ash, a waste product generated from burning coal for energy, is composed of highly respirable particles containing heavy metals, radioactive elements, and polycylic aromatic hydrocarbons. Coal ash is stored in landfills and surface impoundments frequently located near neighborhoods. Fugitive dust from the storage sites exposes neighborhoods,…

Record of Decision for the First Air National Guard F-35A Operational Base

DTIC Science & Technology

2013-12-02

Air Quality • Employ fugitive dust control and soil retention practices including: - Water trucks or sprinkler systems to keep all areas of vehicle...with local fire departments on F-35A crash response procedures. Soils and Water • Sequence construction activities to limit the soil exposure for

40 CFR 63.545 - What are my standards for fugitive dust sources?

Code of Federal Regulations, 2013 CFR

2013-07-01

.... (4) Battery storage area. (5) Equipment maintenance. (6) Material storage areas. (7) Material... achieve 99.97 percent capture efficiency for 0.3 micron particles in a manner that does not generate... 40 CFR 302.4). (4) Battery storage areas. You must inspect any batteries that are not stored in a...

40 CFR 63.545 - What are my standards for fugitive dust sources?

Code of Federal Regulations, 2012 CFR

2012-07-01

.... (4) Battery storage area. (5) Equipment maintenance. (6) Material storage areas. (7) Material... achieve 99.97 percent capture efficiency for 0.3 micron particles in a manner that does not generate... 40 CFR 302.4). (4) Battery storage areas. You must inspect any batteries that are not stored in a...

40 CFR 63.545 - What are my standards for fugitive dust sources?

Code of Federal Regulations, 2014 CFR

2014-07-01

.... (4) Battery storage area. (5) Equipment maintenance. (6) Material storage areas. (7) Material... achieve 99.97 percent capture efficiency for 0.3 micron particles in a manner that does not generate... 40 CFR 302.4). (4) Battery storage areas. You must inspect any batteries that are not stored in a...

40 CFR 49.126 - Rule for limiting fugitive particulate matter emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... limited to the following: (i) Use, where possible, of water or chemicals for control of dust in the...) Application of asphalt, oil (but not used oil), water, or other suitable chemicals on unpaved roads, materials... stockpiles in cases where application of oil, water, or chemicals is not sufficient or appropriate to prevent...

40 CFR 49.126 - Rule for limiting fugitive particulate matter emissions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... limited to the following: (i) Use, where possible, of water or chemicals for control of dust in the...) Application of asphalt, oil (but not used oil), water, or other suitable chemicals on unpaved roads, materials... stockpiles in cases where application of oil, water, or chemicals is not sufficient or appropriate to prevent...

40 CFR 49.126 - Rule for limiting fugitive particulate matter emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... limited to the following: (i) Use, where possible, of water or chemicals for control of dust in the...) Application of asphalt, oil (but not used oil), water, or other suitable chemicals on unpaved roads, materials... stockpiles in cases where application of oil, water, or chemicals is not sufficient or appropriate to prevent...

Emission factors for fugitive dust from bulldozers working on a coal pile.

PubMed

Mueller, Stephen F; Mallard, Jonathan W; Mao, Qi; Shaw, Stephanie L

2015-01-01

A study of a Powder River Basin (PRB) coal pile found that fugitive emissions from natural and human activity each produced similar levels of downwind fine + coarse (i.e., smaller than 10 µm, or PM10) particle mass concentrations. Natural impacts were statistically removed from downwind measurements to estimate emission factor Ev for bulldozers working on the pile. The Ev determined here was similar in magnitude to emission factors (EFs) computed using a U.S. Environmental Protection Agency (EPA) formulation for unpaved surfaces at industrial sites, even though the latter was not based on data for coal piles. EF formulations from this study and those in the EPA guidance yield values of similar magnitude but differ in the variables used to compute Ev variations. EPA studies included effects of surface silt fraction and vehicle weight, while the present study captured the influence of coal moisture. Our data indicate that the relationship between PRB coal fugitive dust Ev (expressed as mass of PM10 emitted per minute of bulldozer operation) and coal moisture content Mc (in percent) at the study site is best expressed as Ev =10(f(Mc())) where f(Mc) is a function of moisture. This function was determined by statistical regression between log10(Ev) and Mc where both Ev and Mc are expressed as daily averages of observations based on 289 hours sampled during 44 days from late June through mid-November of 2012. A methodology is described that estimates Mc based on available meteorological data (precipitation amount and solar radiation flux). An example is given of computed variations in daily Ev for an entire year. This illustrates the sensitivity of the daily average particulate EF to meteorological variability at one location. Finally, a method is suggested for combining the moisture-sensitive formulation for Ev with the EPA formulation to accommodate a larger number of independent variables that influence fugitive emissions.

Petrogenic organic carbon and PAHs in snow deposited on Athabasca oil sands region lakes

NASA Astrophysics Data System (ADS)

Ahad, J. M.; Pakdel, H.; Gammon, P. R.; Savard, M. M.

2017-12-01

Fugitive dust associated with surface mining activities is one of the principal vectors for transport of airborne contaminants in Canada's Athabasca oil sands (AOS) region. The two main sources for mining-related dust - unprocessed oil sand and petroleum coke (petcoke) - contain high levels of bitumen-derived organic contaminants such as polycyclic aromatic hydrocarbons (PAHs). Here, we report the radiocarbon (14C) contents of solvent-extractable organics in snow particulates deposited during the winter of 2016-17 on fourteen lakes across the AOS region to quantify the contribution of anthropogenic dust transported directly to these ecosystems. Concentrations of parent and alkylated PAHs were determined in both dissolved and particulate fractions of snow. Radiocarbon isotope ratios (Δ14C) ranged from -805 to -177‰, indicating a significant contribution of petrogenic or fossil (i.e., Δ14C = -1000‰) carbon in snowpack dust at some sites. More negative Δ14C values were generally found in samples containing higher levels of particulate matter and at lakes closer to the geographic center of AOS mining operations. Concentrations of PAHs > 2 rings were significantly higher in the particulate phase and in samples with the largest petrogenic carbon components. Relatively high levels of PAHs at some distal sites associated with less negative Δ14C values pointed to an important modern carbon contribution, potentially ash originating from the 1.5 million acre 2016 Fort McMurray wildfire. As demonstrated here, fugitive dust in snow covering AOS region lakes can contain significant petrogenic organic carbon and high levels of PAHs, particularly in areas close (i.e., < 25 km) to the center of AOS mining operations. The spring snowmelt thus provides a direct pathway for mining-related contaminants to lake sediments.

Temporal and Spatial Variations in Fine and Coarse Particles in Seoul, Korea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghim, Young Sung

2015-01-01

Concentrations of fine (PM2.5) and coarse particles (PM10 -2.5), whose diameters are less 2.5 µm, and between 2.5 and 10 µm, respectively, at ambient air monitoring stations in Seoul between 2002 and 2008 were analyzed. Effects of Asian dust are mainly manifested as concentration spikes of PM10 - 2.5 but were considerable on PM2.5 levels in 2002 when Asian dust storms were the strongest. Excluding the effects of Asian dust, annual average PM2.5 showed a downward trend. Despite a similarity in year - to - year variations, PM10- 2.5, mostly affected by fugitive dust emissions, and CO and NO2, primarilymore » affected by motor vehicle emissions, did not show a decrease. PM2.5 along with CO and NO2 had the highest values during the morning rush hour. PM10 - 2.5 peak lagged about one hour behind that of PM2.5 because of fugitive dust emissions despite an increasing mixing height. On high PM2.5 days, PM2. 5 peaks occurred two hours later than usual as the effects of secondary formation became more important. A test for the spatial variabilities shows that PM10 - 2.5, which is known to be greatly influenced by local effects, is lower in its correlation coeffic ient and higher in its coefficient of divergence (COD, which serves as an indicator for spatial variability) than PM2.5, albeit that the difference between the two is small. The average COD of PM2.5 among monitoring stations was about 0.2 but was lowered t o 0.13 when considering high PM2.5 days only, which signifies that spatial uniformity increases significantly.« less

Inter-annual variability of wintertime PM2.5 chemical composition in Xi'an, China: Evidences of changing source emissions.

PubMed

Xu, Hongmei; Cao, Junji; Chow, Judith C; Huang, R-J; Shen, Zhenxing; Chen, L W Antony; Ho, Kin Fai; Watson, John G

2016-03-01

Chemical characteristics of PM2.5 in Xi'an in wintertime of 2006, 2008, and 2010 were investigated. Markers of OC2, EC1, and NO3(-)/SO4(2-) ratio were calculated to investigate the changes in PM2.5 emission sources over the 5-year period. Positive matrix factorization (PMF) model was used to identify and quantify the main sources of PM2.5 and their contributions. The results showed that coal combustion, motor vehicular emissions, fugitive dust, and secondary inorganic aerosol accounted for more than 80% of PM2.5 mass. The importance of these major sources to the PM2.5 mass varied yearly: coal combustion was the largest contributor (31.2% ± 5.2%), followed by secondary inorganic aerosol (20.9% ± 5.2%) and motor vehicular emissions (19.3% ± 4.8%) in 2006; the order was still coal combustion emissions (27.6% ± 3.4%), secondary inorganic aerosol (23.2% ± 6.9%), and motor vehicular emissions (20.9% ± 4.6%) in 2008; while coal combustion emission further decreased (24.1% ± 3.1%) with fugitive dust (19.4% ± 5.5%) increasing in 2010. The changes in PM2.5 chemical compositions and source contributions can be attributed to the social and economic developments in Xi'an, China, including energy structure adjustment, energy consumption, the expansion of civil vehicles, and the increase of urban construction activities. Copyright © 2015 Elsevier B.V. All rights reserved.

Advanced receptor modelling for the apportionment of road dust resuspension to atmospheric PM

NASA Astrophysics Data System (ADS)

Amato, F.; Pandolfi, M.; Escrig, A.; Querol, X.; Alastuey, A.; Pey, J.; Perez, N.; Hopke, P. K.

2009-04-01

Fugitive emissions from traffic resuspension can often represent an important source of atmospheric particulate matter in urban environments, especially when the scarce precipitations favour the accumulation of road dust. Resuspension of road dust can lead to high exposures to heavy metals, metalloids and mineral matter. Knowing the amount of its contribution to atmospheric PM is a key task for establishing eventual mitigation or preventive measures. Factor analysis techniques are widely used tools for atmospheric aerosol source apportionment, based on the mass conservation principle. Paatero and Tapper (1993) suggested the use of a Weighted Least Squares scheme with the aim of obtaining a minimum variance solution. Additionally they proposed to incorporate the basic physical constraint of non negativity, calling their approach Positive Matrix Factorization (PMF), which can be performed by the program PMF2 released by Paatero (1997). Nevertheless, Positive Matrix Factorization can be either solved with the Multilinear Engine (ME-2), a more flexible program, also developed by Paatero (1999), which can solve any model consisting in sum of products of unknowns. The main difference with PMF2 is that ME-2 does not solve only well-defined tasks, but its actions are defined in a "script file" written in a special-purpose programming language, allowing incorporating additional tasks such as data processing etc. Thus in ME-2 a priori information, e.g. chemical fingerprints can be included as auxiliary terms of the object function to be minimized. This feature of ME-2 make it especially suitable for source apportionment studies where some knowledge (chemical ratios, profiles, mass conservation etc) of involved sources is available. The aim of this study was to quantify the contribution of road dust resuspension in PM10, PM2.5 and PM1 data set from Barcelona (Spain). Given that recently the emission profile of local road dust was characterized (Amato et al., in press), authors show how to apply in ME-2 this knowledge to obtain a quantitative assessment of this source. The achievement of this objective permitted to show how is possible to improve a basic solution of PMF2 basing on an extended model. Results show that road dust resuspension accounted for 6.7 µg/m3 (16%) in PM10, 2.2 µg/m3 (8%) of PM2.5 and 0.3 µg/m3 (1%) of PM1, revealing that fugitive emissions were responsible of the 36%, 18% and 2% of total traffic emissions respectively in PM10, PM2.5 and PM1. Acknowledments: This work was funded by the Spanish Ministry of Science and Innovation (GRACCIE-SCD2007-00067)

Dust emissions from unpaved roads on the Colorado Plateau

NASA Astrophysics Data System (ADS)

Duniway, M.; Flagg, C.; Belnap, J.

2013-12-01

On the Colorado Plateau, elevated levels of aeolian dust have become a major land management and policy concern due to its influence on climate, weather, terrestrial ecosystem dynamics, landscape development and fertility, melting of snow and ice, air quality, and human health. Most desert soil surfaces are stabilized by plants, rocks, and/or physical or biological soil crusts, but once disturbed, sediment production from these surfaces can increase dramatically. Road development and use is a common surface disturbing activity in the region. The extent and density of roads and road networks is rapidly increasing due to continued energy exploration, infrastructure development, and off-highway recreation activities. Though it is well known that unpaved roads produce dust, the relative contribution of dust from existing roads or the implications of future road development to regional dust loading is unknown. To address this need, we have initiated a multifaceted research effort to evaluating dust emissions from unpaved roads regionally. At 34 sites arranged across various road surfaces and soil textures in southeastern Utah, we are: 1) monitoring dust emissions, local wind conditions, and vehicle traffic and 2) evaluating fugitive dust potential using a portable wind tunnel and measuring road characteristics that affect dust production. We will then 3) develop a GIS-based model that integrates results from 1 & 2 to estimate potential dust contributions from current and future scenarios of regional road development. Passive, horizontal sediment traps were installed at three distances downwind from the road edge. One control trap was placed upwind of the samplers to account for local, non-road dust emissions. An electronic vehicle counter and anemometer were also installed at monitoring sites. Dust samples were collected every three months at fixed heights, 15 cm up to 100 cm above the soil surface, from March 2010 to the present. Threshold friction velocities (TFV), the minimum wind velocity required to initiate erosion, and sediment production were also quantified using a portable wind tunnel at monitoring sites. Additionally, numerous characteristics including gravel cover, particle-size distribution, soil compaction, and loose-erodible material were measured on road surfaces at monitoring sites. Preliminary results suggest that roads are an important regional dust source, as emissions from roads are comparable to non-road, rural sources that are being monitored concurrently. While gravel roads produce more dust per day on average, per vehicle emissions are larger on dirt roads. Dust flux decreases with distance from the road edge on all road types, however this decline is less pronounced on dirt roads. Portable wind tunnel results indicate that TFV is consistently lower on dirt versus gravel roads across all soil types. Fugitive dust flux is generally larger and more variable on dirt roads compared to gravel roads. Initial analyses suggest that several easily measurable road surface characteristics can potentially be used to predict both TFV and sediment production, including: total gravel cover, gravel particle-size classes, clay content, and road compaction. The relation between TFV and total gravel cover in particular appears to be non-linear, with TFV increasing rapidly above ~40% gravel cover.

78 FR 27071 - Approval and Promulgation of Air Quality Implementation Plans; Alaska: Mendenhall Valley...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-09

... lungs and cause serious adverse health effects. People with heart or lung diseases, children and older...) submitted with the Mendenhall Valley NAA PM 10 LMP, for base year 2004 and projected year 2018, identifies... projected to remain close to that level through 2018. Fugitive dust emissions from travel on unpaved roads...

Lidar characterization of crystalline silica generation and transport from a sand and gravel plant.

PubMed

Trzepla-Nabaglo, Krystyna; Shiraki, Ryoji; Holmén, Britt A

2006-04-30

Light detection and ranging (Lidar) remote sensing two-dimensional vertical and horizontal scans collected downwind of a sand and gravel plant were used to evaluate the generation and transport of geologic fugitive dust emitted by quarry operations. The lidar data give unsurpassed spatial resolution of the emitted dust, but lack quantitative particulate matter (PM) mass concentration data. Estimates of the airborne PM10 and crystalline silica concentrations were determined using linear relationships between point monitor PM10 and quartz content data with the lidar backscatter signal collected from the point monitor location. Lidar vertical profiles at different distances downwind from the plant were used to quantify the PM10 and quartz horizontal fluxes at 2-m vertical resolution as well as off-site emission factors. Emission factors on the order of 65-110 kg of PM10 (10-30 kg quartz) per daily truck activity or 2-4 kg/t product shipped (0.5-1 kg quartz/t) were quantified for this facility. The lidar results identify numerous elevated plumes at heights >30 m and maximum plume heights of 100 m that cannot be practically sampled by conventional point sampler arrays. The PM10 and quartz mass flux was greatest at 10-25 m height and decreased with distance from the main operation. Measures of facility activity were useful for explaining differences in mass flux and emission rates between days. The study results highlight the capabilities of lidar remote sensing for determining the spatial distribution of fugitive dust emitted by area sources with intermittent and spatially diverse dust generation rates.

Global dust sources detection using MODIS Deep Blue Collection 6 aerosol products

NASA Astrophysics Data System (ADS)

Pérez García-Pando, C.; Ginoux, P. A.

2015-12-01

Our understanding of the global dust cycle is limited by a dearth of information about dust sources, especially small-scale features which could account for a large fraction of global emissions. Remote sensing sensors are the most useful tool to locate dust sources. These sensors include microwaves, visible channels, and lidar. On the global scale, major dust source regions have been identified using polar orbiting satellite instruments. The MODIS Deep Blue algorithm has been particularly useful to detect small-scale sources such as floodplains, alluvial fans, rivers, and wadis , as well as to identify anthropogenic sources from agriculture. The recent release of Collection 6 MODIS aerosol products allows to extend dust source detection to the entire land surfaces, which is quite useful to identify mid to high latitude dust sources and detect not only dust from agriculture but fugitive dust from transport and industrial activities. This presentation will overview the advantages and drawbacks of using MODIS Deep Blue for dust detection, compare to other instruments (polar orbiting and geostationary). The results of Collection 6 with a new dust screening will be compared against AERONET. Applications to long range transport of anthropogenic dust will be presented.

Road dust and its effect on human health: a literature review

PubMed Central

2018-01-01

The purpose of this study was to determine the effects of road dust on human health. A PubMed search was used to extract references that included the words “road dust” and “health” or “fugitive dust” and “health” in the title or abstract. A total of 46 references were extracted and selected for review after the primary screening of 949 articles. The respiratory system was found to be the most affected system in the human body. Lead, platinum-group elements (platinum, rhodium, and bohrium), aluminum, zinc, vanadium, and polycyclic aromatic hydrocarbons were the components of road dust that were most frequently referenced in the articles reviewed. Road dust was found to have harmful effects on the human body, especially on the respiratory system. To determine the complex mechanism of action of various components of road dust on the human body and the results thereof, the authors recommend a further meta-analysis and extensive risk-assessment research into the health impacts of dust exposure. PMID:29642653

75 FR 17307 - Revisions to the Arizona State Implementation Plan; Pinal County

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-06

... Standards--Hayden 01/07/09 06/12/09 PM10 Non-attainment Area. 4-2-020 Fugitive Dust--General 12/04/02 06/12... Standards--Hayden PM-10 Non- attainment Area,'' adopted on January 7, 2009. (i) Pinal County Board of... District Rules, adopted January 7, 2009; to Wit: Rule 2-8-302 (Performance Standards--Hayden PM10...

Health hazard prospecting by modeling wind transfer of metal-bearing dust from mining waste dumps: application to Jebel Ressas Pb-Zn-Cd abandoned mining site (Tunisia).

PubMed

Ghorbel, Manel; Munoz, Marguerite; Solmon, Fabien

2014-10-01

This work presents a modeling approach to simulate spatial distribution of metal contamination in aerosols with evaluation of health hazard. This approach offers the advantage to be non-intrusive, less expensive than sampling and laboratory analyses. It was applied to assess the impact of metal-bearing dust from mining wastes on air quality for a nearby community and agricultural lands in Jebel Ressas (Tunisia) locality. Dust emission rates were calculated using existing parameterization adapted to the contamination source composed of mining wastes. Metal concentrations were predicted using a Gaussian model (fugitive dust model) with, as input: emission rates, dump physical parameters and meteorological data measured in situ for 30 days in summertime. Metal concentration maps were built from calculated PM10 particle concentrations. They evidence the areas where Pb and Cd concentrations exceeded WHO guidelines (0.5 and 0.005 µg/m(3), respectively). Maximum concentrations of Pb and Cd in PM10 are, respectively, of 5.74 and 0.0768 µg/m(3) for measured wind speed values up to 22 m/s. Preferential areas of contamination were determined in agricultural lands to the NW from the source dump where Pb and Cd exceeded guidelines up to a distance of 1,200 m. The secondary spreading directions were SW and E, toward the village. Health hazard prospecting shown that a major part of the village was exposed to contaminated dust and that daily hazard quotient (HQ) values reached locally 118 and 158, respectively, for Pb and Cd during the study period. However, HQ variations in the village are high, both temporally and geographically.

A wood-strand material for wind erosion control: effects on total sediment loss, PM10 vertical flux, and PM10 loss

Treesearch

N. S. Copeland; B. S. Sharratt; J. Q. Wu; R. B. Foltz; J. H. Dooley

2009-01-01

Fugitive dust from eroding land poses risks to environmental quality and human health, and thus, is regulated nationally based on ambient air quality standards for particulate matter with mean aerodynamic diameter ≤ 10 μm (PM10) established in the Clean Air Act. Agricultural straw has been widely used for rainfall-induced...

Emissions from vehicles, tailpipe and vehicle re-entrained road dust

NASA Astrophysics Data System (ADS)

Zhu, Dongzi

Emissions from transportation are some of the largest sources of urban air pollution. Transportation emissions originate from both the engine-through combustion processes and non-tailpipe re-suspended road dust emissions induced by vehicle travel on unpaved and paved roads. Gaseous and particulate emissions from transportation sources have negative impacts on human health, visibility and may influence the global radiation balance. Fugitive dust emissions originating from vehicle travel on paved and unpaved roads constitute a significant fraction of the PM10 in many areas of the western US impacting their attainment status of National Ambient Air Quality Standards. The research used three novel instrument platforms developed at the Desert Research Institute. The In-Plume Emissions Test Stand (IPETS) was designed to provide characterization of exhaust emissions from in-use individual vehicles or engines by analyzing air as close as 1 m from the exhaust port. Real-world emission factors can be quantified by in-plume measurements and provide more realistic measures for emission inventories, source modeling, and receptor modeling than certification measurements. The Testing Re-entrained Aerosol Kinetic Emissions from Roads (TRAKER) provides an effective alternate approach to the EPA AP-42 road dust emissions estimation techniques by sampling 1000s of km of roads versus isolated 3 m sections. The Portable Deposition Monitoring Platform (PDMP incorporates PM and meteorological instruments to characterize the downwind change in particle concentrations to define depositional losses in different environments. The research outcome provides important knowledge for understanding diesel engine emissions, road dust emissions and aerosol deposition process near road sources.

Dust Generation Resulting from Desiccation of Playa Systems: Studies on Mono and Owens Lakes, California

NASA Astrophysics Data System (ADS)

Gill, Thomas Edward

1995-01-01

Playas, evaporites, and aeolian sediments frequently are linked components within the Earth system. Anthropogenic water diversions from terminal lakes form playas that release fugitive dust. These actions, documented worldwide, simulate aeolian processes activated during palaeoclimatic pluvial/interpluvial transitions, and have significant environmental impacts. Pluvial lakes Russell and Owens in North America's Great Basin preceded historic Mono and Owens Lakes, now desiccated by water diversions into dust-generating, evaporite -encrusted playas. Geochemical and hydrologic cycles acting on the Owens (Dry) Lake playa form three distinct crust types each year. Although initial dust production results from deflation of surface efflorescences after the playa dries, most aerosols are created by saltation abrasion of salt/silt/clay crusts at crust/ sand sheet contacts. The warm-season, clastic "cemented" crust is slowest to degrade into dust. If the playa surface is stabilized by an unbroken, non-efflorescent crust, dust formation is discouraged. When Mono Lake's surFace elevation does not exceed 1951 meters (6400 feet), similar processes will also generate dust from its saline lower playa. Six factors--related to wind, topography, groundwater, and sediments--control dust formation at both playas. These factors were combined into a statistical model relating suspended dust concentrations to playa/lake morphometry. The model shows the extent and severity of Mono Lake dust storms expands significantly below the surface level 6376 feet (1943.5 meters). X-ray diffraction analysis of Mono Basin soils, playa sediments, and aerosols demonstrates geochemical cycling of materials through land, air and water during Mono Lake's 1982 low stand. Soils and clastic playa sediments contain silicate minerals and tephra. Saline groundwater deposited calcite, halite, thenardite, gaylussite, burkeite and glauberite onto the lower playa. Aerosols contained silicate minerals (especially micas) and salts (including calcite, thenardite, gaylussite and halite). Playa-specific compounds were detected in the aerosol, even at a site not visually impacted by dust plumes. Anthropogenic mitigation may help alleviate playa dust storms. Reducing water diversions, legally mandated for Mono Lake, is not feasible everywhere. Most successful land rehabilitation schemes for playas have combined engineering (sand fences, flooding) and ecological (revegetation) techniques to mimic and accelerate natural processes; this is recommended for Owens (Dry) Lake.

Comparison of conventional and bio-treated methods as dust suppressants.

PubMed

Naeimi, Maryam; Chu, Jian

2017-10-01

Dust is an environmental, geotechnical, health, and economical hazard. Fugitive dust emanating along transportation systems such as roads, railways, and airports especially can have significant impacts on health, safety, material loss, cost of maintenance, and interfere with the facilities. Quantitative studies on the effectiveness of the proper dust palliatives and their environmental impact have been studied with a number of biological and chemical methods. The objective of this study was to establish a method for using the microbial Induced calcium carbonate precipitation (MICP) approach to reduce the percent of mass loss against erosive force of wind regarding to the concentration and characteristics of aggregate used, climate, and traffic amounts. The results of this study showed that the required precipitation for dust control of sand by 70% is less than 15 g CaCO 3 /m 2 between sand grains in bio-treated sand. The wind tunnel test results of this study also indicate that the effectiveness of the bio-treatment method for dust control depends on many variables, such as the percent of precipitated calcium carbonate and tensile strength.

The Atlantic Richfield Company Black Thunder mine haul road dust study. [Wyoming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maxwell, D.R.; Hormel, T.R.; Ives, J.A.

An examination of the effectiveness of various haul road dust control measures was performed at ARCO's Black Thunder Mine near Wright, Wyoming by evaluating both visible observations and quantitative measurements of particle concentrations. In order to evaluate dust control effectiveness both a 300 foot (91.5 meter) and 175 foot (53.4 meter) section of the main coal haul road was selected for testing. The test sections were separated by a 200 foot (61 meter) buffer zone. Each test section was relatively straight and away from interferences from other mine sources. The five haul road treatment test sequences evaluated for control measuremore » effectiveness were: an untreated road segment; water treatment two times per hour; water treatment four times per hour; previously chemically treated segment of haul road (ARCO 2400 dust suppressant); and testing after application of Coherex (10% dilution). By comparing uncontrolled situations with various controlled situations, an estimate of the control efficiency of the dust control measures was determined. Based upon the results of the study a fugitive dust control scheme was selected considering control effectiveness, economics and operational efficiency.« less

Environmental Assessment: Maintenance of the Bear Lake Storm Water Retention Pond Whiteman Air Force Base, Missouri

DTIC Science & Technology

2010-10-01

Services, Directorate for Information Operations and Reports, 1215 Jefferson Davis Highway, Suite 1204, Arlington VA 22202-4302. Respondents should be...and fugitive dust The noise environment due to construction vehicle operations Biological resources and wetlands due to land and water disturbance...construction vehicle operations ; Biological resources and wetlands due to land and water disturbance; Water quality due to land and water disturbance

Air quality as a constraint to the use of coal in California

NASA Technical Reports Server (NTRS)

Austin, T. C.

1978-01-01

Low-NOx burners, wet scrubbing systems, baghouses and ammonia injection systems are feasible for use on large combustion sources such as utility boilers. These devices, used in combination with coal handling techniques which minimize fugitive dust and coal transportation related emissions, should enable new power plants and large industrial boilers to burn coal without the adverse air quality impacts for which coal became notorious.

Impairment of soil health due to fly ash-fugitive dust deposition from coal-fired thermal power plants.

PubMed

Raja, R; Nayak, A K; Shukla, A K; Rao, K S; Gautam, Priyanka; Lal, B; Tripathi, R; Shahid, M; Panda, B B; Kumar, A; Bhattacharyya, P; Bardhan, G; Gupta, S; Patra, D K

2015-11-01

Thermal power stations apart from being source of energy supply are causing soil pollution leading to its degradation in fertility and contamination. Fine particle and trace element emissions from energy production in coal-fired thermal power plants are associated with significant adverse effects on human, animal, and soil health. Contamination of soil with cadmium, nickel, copper, lead, arsenic, chromium, and zinc can be a primary route of human exposure to these potentially toxic elements. The environmental evaluation of surrounding soil of thermal power plants in Odisha may serve a model study to get the insight into hazards they are causing. The study investigates the impact of fly ash-fugitive dust (FAFD) deposition from coal-fired thermal power plant emissions on soil properties including trace element concentration, pH, and soil enzymatic activities. Higher FAFD deposition was found in the close proximity of power plants, which led to high pH and greater accumulation of heavy metals. Among the three power plants, in the vicinity of NALCO, higher concentrations of soil organic carbon and nitrogen was observed whereas, higher phosphorus content was recorded in the proximity of NTPC. Multivariate statistical analysis of different variables and their association indicated that FAFD deposition and soil properties were influenced by the source of emissions and distance from source of emission. Pollution in soil profiles and high risk areas were detected and visualized using surface maps based on Kriging interpolation. The concentrations of chromium and arsenic were higher in the soil where FAFD deposition was more. Observance of relatively high concentration of heavy metals like cadmium, lead, nickel, and arsenic and a low concentration of enzymatic activity in proximity to the emission source indicated a possible link with anthropogenic emissions.

Fugitive Dust Emissions from Construction Haul Roads

DTIC Science & Technology

1977-02-01

38 APPENDIX A: Probe Analysis APPENDIX B: Soil Water Potential and Soil Psychrometers APPENDIX C: Complete Listing of Reduced Data...traveling through the 10-in. (25-cm) duct. Four soil psychrometers (see Appendix B) used to measure soil water poten- tial were buried in the wheel paths of...average slow speed test lasted approximately 8 hours. For com- par1qnn, an attempt was made to run all tests over the same range of soil psychrometer

Elucidating the urban levels, sources and health risks of polycyclic aromatic hydrocarbons (PAHs) in Pakistan: Implications for changing energy demand.

PubMed

Hamid, Naima; Syed, Jabir Hussain; Junaid, Muhammad; Mahmood, Adeel; Li, Jun; Zhang, Gan; Malik, Riffat Naseem

2018-04-01

Due to the severe fuel crisis in terms of natural gas, a paradigm shift in fuel combustion (diesel, gasoline, and biomass) may increase the atmospheric emissions and associated health risks in Pakistan. Present study was aimed to investigate the concentration of fugitive PAHs in the environment (outdoor and indoor settings), associated probabilistic health risk assessment in the exposed population, and possible linkage between fuel consumption patterns and PAHs emissions in twin cities (Rawalpindi and Islamabad) of Pakistan. Results showed that the mean PAHs concentrations (air: 2390pgm -3 ; dust: 167ngg -1 ) in the indoor environment were higher than that of the outdoor environment (air: 2132pgm -3 ; dust: 90.0ngg -1 ). Further, the source apportionment PCA-MLR receptor model identified diesel and gasoline combustion as the primary PAHs sources in the urban and sub-urban settings. Estimated life cancer risk (LCR) potential via inhalation to indoor PAHs was higher with a probability of 2.0 cases per 10,000 inhabitants as compared to outdoor exposure. Incremental lifetime cancer risk (ILCR) model from exposure to dust bound PAHs showed risk in the order of ingestion>dermal>inhalation for various exposure pathways. Likewise, estimated daily intake (EDI) model reflects that PAHs in surface dust enter into the human body mainly through the respiratory system because EDI for breathing was reported higher than that of oral intake. Therefore, adoption of sustainable fuels is recommended to meet the energy requirements and to reduce PAHs emissions and related health risks in the twin cities of Pakistan. Copyright © 2017 Elsevier B.V. All rights reserved.

Global emissions of PM10 and PM2.5 from agricultural tillage and harvesting operations

NASA Astrophysics Data System (ADS)

Chen, W.; Tong, D.; Lee, P.

2014-12-01

Soil particles emitted during agricultural activities is a major recurring source contributing to atmospheric aerosol loading. Emission inventories of agricultural dust emissions have been compiled in several regions. These inventories, compiled based on historic survey and activity data, may reflect the current emission strengths that introduce large uncertainties when they are used to drive chemical transport models. In addition, there is no global emission inventory of agricultural dust emissions required to support global air quality and climate modeling. In this study, we present our recent efforts to develop a global emission inventory of PM10 and PM2.5 released from field tillage and harvesting operations using an emission factors-based approach. Both major crops (e.g., wheat and corn) and forage production were considered. For each crop or forage, information of crop area, crop calendar, farming activities and emission factors of specified operations were assembled. The key issue of inventory compilation is the choice of suitable emission factors for specified operations over different parts of the world. Through careful review of published emission factors, we modified the traditional emission factor-based model by multiplying correction coefficient factors to reflect the relationship between emission factors, soil texture, and climate conditions. Then, the temporal (i.e., monthly) and spatial (i.e., 0.5º resolution) distribution of agricultural PM10 and PM2.5 emissions from each and all operations were estimated for each crop or forage. Finally, the emissions from individual crops were aggregated to assemble a global inventory from agricultural operations. The inventory was verified by comparing the new data with the existing agricultural fugitive dust inventory in North America and Europe, as well as satellite observations of anthropogenic agricultural dust emissions.

Design Analysis, Basin F Liquid Waste Disposal Facility, Rocky Mountain Arsenal, Commerce City, Colorado, FY81.

DTIC Science & Technology

1981-08-01

City were contacted concern- ing Building and Construction permits. No regulations apply since they do not have jurisdiction over RMA property. It may...Division. Mr. Dale advised that their agency’s regulations applied only to permanent pollution emitting sources. Mr. Plog thought that their "fugitive dust...processing, treat- ment, recovery, and disposal of hazardous waste. "Person" means an individual trust, firm, joint stock company , Federal Agency

Study on reinforcement of soil for suppressing fugitive dust by bio-cementitious material

NASA Astrophysics Data System (ADS)

Zhan, Qiwei; Qian, Chunxiang

2017-06-01

Microbial-induced reinforcement of soil, as a new green and environmental-friendly method, is being paid extensive attention to in that it has low cost, simple operation and rapid effects. In this research, reinforcement of soil for suppressing fugitive dust by bio-cementitious material was investigated. Soil cemented by bio-cementitious material had superior mechanical properties, such as hardness, compressive strength, microstructure, wind-erosion resistance, rainfall-erosion resistance and freeze-thaw resistance. The average hardness of sandy soil, floury soil and clay soil is 18.9 º, 25.2 º and 26.1 º, while average compressive strength of samples is 0.43 MPa, 0.54 MPa and 0.69 MPa, respectively; meanwhile, the average calcite content of samples is 6.85 %, 6.09 %, and 5.96 %, respectively. Compared with the original sandy soil, floury soil and clay soil, the porosity decreases by 38.5 %, 33.7 % and 29.2 %. When wind speed is 12 m/s, the mass loss of sandy soil, floury soil and clay soil cemented by bio-cementitious material are all less than 30 g/(m2·h). After three cycles of rainfall erosion of 2.5 mm/h, the mass loss are less than 25 g/(m2·h) and the compressive strength residual ratio are more than 98.0 %. Under 25 cycles of freeze-thaw, the mass loss ratio are less than 3.0 %.

A Methodology to Monitor Airborne PM10 Dust Particles Using a Small Unmanned Aerial Vehicle

PubMed Central

Alvarado, Miguel; Gonzalez, Felipe; Erskine, Peter; Cliff, David; Heuff, Darlene

2017-01-01

Throughout the process of coal extraction from surface mines, gases and particles are emitted in the form of fugitive emissions by activities such as hauling, blasting and transportation. As these emissions are diffuse in nature, estimations based upon emission factors and dispersion/advection equations need to be measured directly from the atmosphere. This paper expands upon previous research undertaken to develop a relative methodology to monitor PM10 dust particles produced by mining activities making use of small unmanned aerial vehicles (UAVs). A module sensor using a laser particle counter (OPC-N2 from Alphasense, Great Notley, Essex, UK) was tested. An aerodynamic flow experiment was undertaken to determine the position and length of a sampling probe of the sensing module. Flight tests were conducted in order to demonstrate that the sensor provided data which could be used to calculate the emission rate of a source. Emission rates are a critical variable for further predictive dispersion estimates. First, data collected by the airborne module was verified using a 5.0 m tower in which a TSI DRX 8533 (reference dust monitoring device, TSI, Shoreview, MN, USA) and a duplicate of the module sensor were installed. Second, concentration values collected by the monitoring module attached to the UAV (airborne module) obtaining a percentage error of 1.1%. Finally, emission rates from the source were calculated, with airborne data, obtaining errors as low as 1.2%. These errors are low and indicate that the readings collected with the airborne module are comparable to the TSI DRX and could be used to obtain specific emission factors from fugitive emissions for industrial activities. PMID:28216557

Large-Scale Land Development, Fugitive Dust, and Increased Coccidioidomycosis Incidence in the Antelope Valley of California, 1999-2014.

PubMed

Colson, Aaron J; Vredenburgh, Larry; Guevara, Ramon E; Rangel, Natalia P; Kloock, Carl T; Lauer, Antje

2017-06-01

Ongoing large-scale land development for renewable energy projects in the Antelope Valley, located in the Western Mojave Desert, has been blamed for increased fugitive dust emissions and coccidioidomycosis incidence among the general public in recent years. Soil samples were collected at six sites that were destined for solar farm construction and were analyzed for the presence of the soil-borne fungal pathogen Coccidioides immitis which is endemic to many areas of central and southern California. We used a modified culture-independent nested PCR approach to identify the pathogen in all soil samples and also compared the sampling sites in regard to soil physical and chemical parameters, degree of disturbance, and vegetation. Our results indicated the presence of C. immitis at four of the six sites, predominantly in non-disturbed soils of the Pond-Oban complex, which are characterized by an elevated pH and salt bush communities, but also in grassland characterized by different soil parameters and covered with native and non-native annuals. Overall, we were able to detect the pathogen in 40% of the soil samples (n = 42). Incidence of coccidioidomycosis in the Antelope Valley was positively correlated with land use and particulate matter in the air (PM10) (Pearson correlation coefficient >0.5). With the predicted population growth and ongoing large-scale disturbance of soil in the Antelope Valley in coming years, incidence of coccidioidomycosis will likely further increase if policy makers and land developers continue to ignore the risk of grading land without implementing long-term dust mitigation plans in Environmental Impact Reports.

A wood-strand material for wind erosion control: effects on total sediment loss, PM10 vertical flux, and PM10 loss.

PubMed

Copeland, N S; Sharratt, B S; Wu, J Q; Foltz, R B; Dooley, J H

2009-01-01

Fugitive dust from eroding land poses risks to environmental quality and human health, and thus, is regulated nationally based on ambient air quality standards for particulate matter with mean aerodynamic diameter < or = 10 microm (PM10) established in the Clean Air Act. Agricultural straw has been widely used for rainfall-induced erosion control; however, its performance for wind erosion mitigation has been less studied, in part because straw is mobile at moderate wind velocities. A wood-based long-strand material has been developed for rainfall-induced erosion control and has shown operational promise for control of wind-induced erosion and dust emissions from disturbed sites. The purpose of this study was to evaluate the efficacy of both agricultural straw and wood-strand materials in controlling wind erosion and fugitive dust emissions under laboratory conditions. Wind tunnel tests were conducted to compare wood strands of several geometries to agricultural wheat straw and bare soil in terms of total sediment loss, PM10 vertical flux, and PM10 loss. Results indicate that the types of wood strands tested are stable at wind speeds of up to 18 m s(-1), while wheat straw is only stable at speeds of up to 6.5 m s(-1). Wood strands reduced total sediment loss and PM10 emissions by 90% as compared to bare soil across the range of wind speeds tested. Wheat straw did not reduce total sediment loss for the range of speeds tested, but did reduce PM10 emissions by 75% compared to a bare soil at wind speeds of up to 11 m s(-1).

Saccharide Composition in Fine and Coarse Particulate Matter and Soils in Central Arizona and Use of Saccharides as Molecular Markers for Source Apportionment

NASA Astrophysics Data System (ADS)

Jia, Y.; Clements, A.; Fraser, M.

2009-04-01

The desert southwestern United States routinely exceeds health-based standards for coarse particulate matter [1]. PM10 concentrations are high in both urban and rural areas and are believed to originate from fugitive dust emissions from agricultural fields and roads and soil erosion from the surrounding desert locations. Soil together with its associated biota contains a complex mixture of biogenic detritus, including plant detritus, airborne microbes comprised of bacteria, viruses, spores of lichens and fungi, small algae, and protozoan cysts [4][5], which can mostly become airborne when winds are strong enough and soil dry enough to be re-entrained into the atmosphere [3]. Other potential sources to PM10 may include primary biological aerosol particles (PBAPs), given a multitude of flower, grass, and fungal species that thrive in the Sonoran desert and actively release pollens and spores throughout the year [2]. However, because soil and fugitive dust is also believed to contain a large number of these biological particles and is considered as a secondary host of PBAPs [3] [4], the role and contribution of PBAPs as a direct ambient PM source in the desert southwest have not been clearly stated or investigated. In an effort to identify and assess the relative contribution of these and other major PM sources in the southwestern US region, and particularly to assess the contribution from soil and fugitive dust, a series of ambient PM samples and soil samples were collected in Higley, AZ, USA, a suburb of the Phoenix metropolitan area which has seen rapid urban sprawl onto agricultural lands. Because of their suggested ability to track biologically important organic materials from natural environment [4][6][7][8][9][10], saccharides were chosen as the key compounds to trace the release of soil dusts into the atmosphere, and to elucidate other major sources that contribute to the PM levels in this location in the arid southwestern US. To this end, saccharide compounds were analyzed in size segregated soil and ambient PM samples at Higley; intra- and inter- comparisons were made between the ambient PM and three types of soil dust samples (agricultural soil, native soil, road dust) based on the particle size (fine vs. coarse), seasonality, and relative composition of 12 saccharide compounds. Based on the ambient concentrations of major saccharides and a number of other specific compounds (including elemental and organic carbon, ions, metals, alkanes, organic acids, and polycyclic aromatic hydrocarbons) that are simultaneously resolved in Higley PM samples, a Positive Matrix Factorization (PMF) model was performed to determine the key contributors to PM10 and PM2.5 levels. Six distinct factors were isolated, with two factors dominated by the enrichment of saccharide compounds. There was not consistency between the source profiles of these two saccharide rich source factors with the saccharide composition of the local size-segregated soil samples, which implies that there may be other major sources contributing to ambient PM saccharides. One possible alternative is that PBAPs that are injected directly into the atmosphere instead of residing in the surface soil and being re-entrained through soil erosion or agricultural processing. To our knowledge, this study is the first of its kind to compare the saccharide composition between the fine and coarse fraction of different soils types in two seasons, and to relate the contribution from soil dust to ambient PM using saccharide species. REFERENCE [1] AirData: Access to Air Pollution data. [cited 2009 Jan 11, 2009]; Available from: http://www.epa.gov/air/data/index.html [2] Allergy and Asthma in the Southwestern United States. [cited 2009 Jan 11, 2009]; Available from: http://allergy.peds.arizona.edu/southwest/swpollen.html [3] Cox, C.S., Wathes, C.M., 1995. Bioaerosols Handbook, Lewis Publishers, NY [4] Simoneit, B.R.T., Elias, V.O., et al., 2004. "Sugars - Dominant water-soluble organic compounds in soils and characterization as tracers in atmospheric particulate matter", Environmental Science and Technology (38): 5939-5949. [5] Simoneit, B.R.T., Mazurek, M.A., 1981. "Air Pollution - the Organic-Components", Crc Critical Reviews in Environmental Control (11): 219-276. [6] Medeiros, P.M., Simoneit, B.R.T, 2007. "Analysis of sugars in environmental samples by gas chromatography-mass spectrometry", Jouranl of Chromatography A (1141): 271-278. [7] Rogge, W.F., Medeiros, P.M, et al., 2007. ‘Organic marker compounds in surface soils of crop fields from the San Joaquin Valley fugitive dust characterization study", Atmospheric Environment (41): 8183-8204. [8] Bauer, H., Claeys, M., et al., 2008. "Arabitol and mannitol as tracers for the quantification of airborne fungal spores", Atmospheric Environment (42): 588-593. [9] Elbert, W., Taylor, P.E., et al., 2007. "Contribution of fungi to primary biogenic aerosols in the atmosphere: wet and dry discharged spores, carbohydrates, and inorganic ions", Atmospheric Chemistry and Physics (7): 4569-4588. [10] Graham, B., Guyon, P., et al., 2003. "Organic compounds present in the natural Amazonian aerosol: Characterization by gas chromatography-mass spectrometry", Journal of Geophysical Research (108): 4766, doi:10.1029/2003JD003990.

A new approach to developing a fugitive road dust emission inventory and emission trend from 2006 to 2010 in the beijing metropolitan area, china.

PubMed

Fan, Shoubin; Tian, Gang; Cheng, Shuiyuan; Qin, Jianping

2013-07-01

The USEPA emission factor (AP-42) of fugitive road dust (FRD) is widely used in establishing emission inventories. However, road silt loading sampling for AP-42 is expensive, time consuming, and dangerous. Therefore, a new method for establishing emission inventories based on road dust-fall (DF) monitors is described. Between January 2006 and December 2010, DF was monitored at 40 sites (80 samples), and background dust fall (DF) was monitored at 14 sites in the Beijing metropolitan area. Also during this period, 58 samples of road silt loadings were taken and used in the AP-42 emission factor equation to calculate FRD with particulate matter ≤10 μm in diameter [FRD(PM)] emission from the roads. Simultaneous measurement of FRD(PM) emissions calculated by AP-42 and ΔDF (i.e., the difference between the DF and DF) measured using gauges showed that the FRD(PM) emission for road dust was proportional to the ΔDF ( = 0.92). The FRD(PM) emission (kg km × 30 d) was calculated using the monitored ΔDF (t km × 30 d) by the formulation FRD(PM) = 278.3 × ΔDF - 1151.2. The ΔDF showed a general decline from 2006 to 2010. In particular, there was a sharp decline in August, September, and October 2008 due to strict dust controls enforced during the 2008 Olympic Games. Although there was a small increase in ΔDF after the Games, by the end of 2010 values were still lower than those before the Games. Using the 2006 ΔDF value as a benchmark, ΔDF values declined by 24.7, 33.0, 38.3, and 31.4% in 2007, 2008, 2009, and 2010, respectively. Based on using AP-42 calculations from silt loading and traffic information in 2007, the FRD(PM) emission distribution in the Beijing metropolitan area was mapped, and there were 2.05 × 10 tons of FRD(PM) emitted in 2007. The FRD(PM) from 2006 to 2010 was calculated by the ΔDF values. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Fugitive dust emissions from paved road travel in the Lake Tahoe basin.

PubMed

Zhu, Dongzi; Kuhns, Hampden D; Brown, Scott; Gillies, John A; Etyemezian, Vicken; Gertler, Alan W

2009-10-01

The clarity of water in Lake Tahoe has declined substantially over the past 40 yr. Causes of the degradation include nitrogen and phosphorous fertilization of the lake waters and increasing amounts of inorganic fine sediment that can scatter light. Atmospheric deposition is a major source of fine sediment. A year-round monitoring study of road dust emissions around the lake was completed in 2007 using the Testing Re-entrained Aerosol Kinetic Emissions from Roads (TRAKER) system developed at the Desert Research Institute (DRI). Results of this study found that, compared with the summer season, road dust emissions increased by a factor of 5 in winter, on average, and about a factor of 10 when traction control material was applied to the roads after snow events. For winter and summer, road dust emission factors (grams coarse particulate matter [PM10] per vehicle kilometer traveled [g/vkt]) showed a decreasing trend with the travel speed of the road. The highest emission factors were observed on very low traffic volume roads on the west side of the lake. These roads were composed of either a 3/8-in. gravel material or had degraded asphalt. The principle factors influencing road dust emissions in the basin are season, vehicle speed (or road type), road condition, road grade, and proximity to other high-emitting roads. Combined with a traffic volume model, an analysis of the total emissions from the road sections surveyed indicated that urban areas (in particular South Lake Tahoe) had the highest emitting roads in the basin.

Characterizing and Quantifying Emissions and Transport of Fugitive Dust Emissions Due to Department of Defense Activities

DTIC Science & Technology

2015-09-19

response to shear stress (τ, N m-2) induced by the PI-SWERL®, the viscosity of the fluid exerts a torque (N m-1) that eventually balances with τ. The...Engelbrecht et al. (2012) from CCSEM measurements, report that these silicate mineral particles are largely coated by a veneer of clay minerals and fine...content does not, by itself, contribute to the high emissions observed at YTC. The presence of high clay content can constrain the emissions by

Environmental Assessment for Tower Construction at the Brandywine Communication Receiver Site, Prince George’s County, Maryland

DTIC Science & Technology

2005-05-01

mobilization . • Place1nent of tower guy wires will be adjusted to avoid construction and disturbance to any wetlands or small tributaries through on...include combustion emissions (VOC, NOx, CO, SO2) and fugitive dust (PM10) from mobile heavy-duty diesel- and gasoline-powered equipment and soil...Pollutant Factors, Mobile Sources (AP 42). 4th Edition, U.S. Environmental Protection Agency, Ann Arbor, Michigan. Total estimated emissions for VOC and

Potential health benefits of controlling dust emissions in Beijing.

PubMed

Meng, Jing; Liu, Junfeng; Fan, Songmiao; Kang, Chuyun; Yi, Kan; Cheng, Yanli; Shen, Xing; Tao, Shu

2016-06-01

Although the adverse impact of fine particulate matter (i.e., PM2.5) on human health has been well acknowledged, little is known of the health effects of its specific constituents. Over the past decade, the annual average dust concentrations in Beijing were approximately ∼14 μg m(-3), a value that poses a great threat to the city's 20 million residents. In this study, we quantify the potential long-term health damages in Beijing resulting from the dust exposure that occurred from 2000 to 2011. Each year in Beijing, nearly 4000 (95% CI: 1000-7000) premature deaths may be associated with long-term dust exposure, and ∼20% of these deaths are attributed to lung cancer. A decomposition analysis of the inter-annual variability of premature deaths in Beijing indicates that dust concentrations determine the year-to-year tendency, whereas population growth and lung cancer mortality rates drive the increasing tendency of premature death. We suggest that if Beijing takes effective measures towards reducing dust concentrations (e.g., controlling the resuspension of road dust and the fugitive dust from construction sites) to a level comparable to that of New York City's, the associated premature deaths will be significantly reduced. This recommendation offers "low-hanging fruit" suggestions for pollution control that would greatly benefit the public health in Beijing. Copyright © 2016 Elsevier Ltd. All rights reserved.

Tracing Sources and Contamination Assessments of Heavy Metals in Road and Foliar Dusts in a Typical Mining City, China

PubMed Central

Yang, Jie; Teng, Yanguo; Song, Liuting; Zuo, Rui

2016-01-01

Road and foliar dust samples from four land-use districts of Panzhihua City, a famous V-Ti magnetite production area of China, were collected to investigate the sources and distribution characteristics of 9 heavy metals (V, Pb, Cd, Cu, Zn, Ni, Cr, Fe, and Mn). The results suggest that foliar samples had smaller particle size and higher heavy metal contents than road dusts. The contamination assessments of heavy metals were as follows: Pb and V (significant enrichment) > Zn, Ni, Cr, Fe, and Mn (moderate enrichment) > Cd and Ni (minimal enrichment). Statistical analyses showed Pb, as the primary pollution element, originated from waste incineration and lead-fuel combustion. The sources of Zn, Ni, Cr, Fe, V, and Mn were fugitive dust and traffic activities. Potential origins of Cu were corrosion of alloys used in vehicle components, vehicle covers, or other metallic surfaces and materials. The sources of Cd were different from any other heavy metals. Traffic and industrial activities were the main anthropogenic origins of heavy metals in dusts of Panzhihua, and more attention should be paid to heavy metal pollution in agricultural area. PMID:27992518

Tracing Sources and Contamination Assessments of Heavy Metals in Road and Foliar Dusts in a Typical Mining City, China.

PubMed

Yang, Jie; Teng, Yanguo; Song, Liuting; Zuo, Rui

2016-01-01

Road and foliar dust samples from four land-use districts of Panzhihua City, a famous V-Ti magnetite production area of China, were collected to investigate the sources and distribution characteristics of 9 heavy metals (V, Pb, Cd, Cu, Zn, Ni, Cr, Fe, and Mn). The results suggest that foliar samples had smaller particle size and higher heavy metal contents than road dusts. The contamination assessments of heavy metals were as follows: Pb and V (significant enrichment) > Zn, Ni, Cr, Fe, and Mn (moderate enrichment) > Cd and Ni (minimal enrichment). Statistical analyses showed Pb, as the primary pollution element, originated from waste incineration and lead-fuel combustion. The sources of Zn, Ni, Cr, Fe, V, and Mn were fugitive dust and traffic activities. Potential origins of Cu were corrosion of alloys used in vehicle components, vehicle covers, or other metallic surfaces and materials. The sources of Cd were different from any other heavy metals. Traffic and industrial activities were the main anthropogenic origins of heavy metals in dusts of Panzhihua, and more attention should be paid to heavy metal pollution in agricultural area.

Flux estimation of fugitive particulate matter emissions from loose Calcisols at construction sites

NASA Astrophysics Data System (ADS)

Hassan, Hala A.; Kumar, Prashant; Kakosimos, Konstantinos E.

2016-09-01

A major source of airborne pollution in arid and semi-arid environments (i.e. North Africa, Middle East, Central Asia, and Australia) is the fugitive particulate matter (fPM), which is a frequent product of wind erosion. However, accurate determination of fPM is an ongoing scientific challenge. The objective of this study is to examine fPM emissions from the loose Calcisols (i.e. soils with a substantial accumulation of secondary carbonates), owing to construction activities that can be frequently seen nowadays in arid urbanizing regions such as the Middle East. A two months field campaign was conducted at a construction site, at rest, within the city of Doha (Qatar) to measure number concentrations of PM over a size range of 0.25-32 μm using light scattering based monitoring stations. The fPM emission fluxes were calculated using the Fugitive Dust Model (FDM) in an iterative manner and were fitted to a power function, which expresses the wind velocity dependence. The power factors were estimated as 1.87, 1.65, 2.70 and 2.06 for the four different size classes of particles ≤2.5, 2.5-6, 6-10 and ≤10 μm, respectively. Fitted power function was considered acceptable given that adjusted R2 values varied from 0.13 for the smaller particles and up to 0.69 for the larger ones. These power factors are in the same range of those reported in the literature for similar sources. The outcome of this study is expected to contribute to the improvement of PM emission inventories by focusing on an overlooked but significant pollution source, especially in dry and arid regions, and often located very close to residential areas and sensitive population groups. Further campaigns are recommended to reduce the uncertainty and include more fPM sources (e.g. earthworks) and other types of soil.

Using Si depletion in aerosol to identify the sources of crustal dust in two Chinese megacities

NASA Astrophysics Data System (ADS)

Zhao, Qing; He, Kebin; Rahn, Kenneth A.; Ma, Yongliang; Yang, Fumo; Duan, Fengkui

2010-07-01

Depletion of Si in transported dust has been recognized for many years. It can be used to distinguish between transported and local dust in cities, although it rarely has been. Here we use the variations of the Si/Al ratio in 15 months of continuous PM 2.5 samples at Beijing (northern China) and Chongqing (southwestern China) to reveal the seasonal patterns of their dust sources. For both cities, peaks of concentration for Si and Al in PM 2.5 corresponded with minima of Si/Al, and could often be linked to pulsed air flow from deserts to the northwest. With significant depletion (up to 80%) and homogeneous distribution at urban and rural sites, Si/Al showed a clear seasonal evolution, which decreased from spring to summer, increased from fall to winter, and collapsed during Chinese Spring Festival, indicating the dominance of transported dust, local fugitive dust and firework influence, respectively. The low ratios implied that desert dust is a common source during spring at Chongqing, whereas its presence during cold season at Beijing was also more frequent than expected. Failing to recognize the depletion of Si may lead to an overestimate of desert dust by 15%-65% when using the average abundance of Al in crust (6%-8%), as in previous studies. The difference in Si/Al ratio between local and transported dust implies that >60% of the dust at Beijing came from outside the city during the springs of 2004-2006. This result can help resolve the contradictory findings on this topic that have been presented earlier.

Source apportionment of fine particles and its chemical components over the Yangtze River Delta, China during a heavy haze pollution episode

NASA Astrophysics Data System (ADS)

Li, L.; An, J. Y.; Zhou, M.; Yan, R. S.; Huang, C.; Lu, Q.; Lin, L.; Wang, Y. J.; Tao, S. K.; Qiao, L. P.; Zhu, S. H.; Chen, C. H.

2015-12-01

An extremely high PM2.5 pollution episode occurred over the eastern China in January 2013. In this paper, the particulate matter source apportionment technology (PSAT) method coupled within the Comprehensive air quality model with extensions (CAMx) is applied to study the source contributions to PM2.5 and its major components at six receptors (Urban Shanghai, Chongming, Dianshan Lake, Urban Suzhou, Hangzhou and Zhoushan) in the Yangtze River Delta (YRD) region. Contributions from 4 source areas (including Shanghai, South Jiangsu, North Zhejiang and Super-region) and 9 emission sectors (including power plants, industrial boilers and kilns, industrial processing, mobile source, residential, volatile emissions, dust, agriculture and biogenic emissions) to PM2.5 and its major components (sulfate, nitrate, ammonia, organic carbon and elemental carbon) at the six receptors in the YRD region are quantified. Results show that accumulation of local pollution was the largest contributor during this air pollution episode in urban Shanghai (55%) and Suzhou (46%), followed by long-range transport (37% contribution to Shanghai and 44% to Suzhou). Super-regional emissions play an important role in PM2.5 formation at Hangzhou (48%) and Zhoushan site (68%). Among the emission sectors contributing to the high pollution episode, the major source categories include industrial processing (with contributions ranging between 12.7 and 38.7% at different receptors), combustion source (21.7-37.3%), mobile source (7.5-17.7%) and fugitive dust (8.4-27.3%). Agricultural contribution is also very significant at Zhoushan site (24.5%). In terms of the PM2.5 major components, it is found that industrial boilers and kilns are the major source contributor to sulfate and nitrate. Volatile emission source and agriculture are the major contributors to ammonia; transport is the largest contributor to elemental carbon. Industrial processing, volatile emissions and mobile source are the most significant contributors to organic carbon. Results show that the Yangtze River Delta region should focus on the joint pollution control of industrial processing, combustion emissions, mobile source emissions, and fugitive dust. Regional transport of air pollution among the cities are prominent, and the implementation of regional joint prevention and control of air pollution will help to alleviate fine particulate matter concentrations under heavy pollution case significantly.

Trends in spatial patterns of heavy metal deposition on national park service lands along the Red Dog Mine haul road, Alaska, 2001-2006.

PubMed

Neitlich, Peter N; Ver Hoef, Jay M; Berryman, Shanti D; Mines, Anaka; Geiser, Linda H; Hasselbach, Linda M; Shiel, Alyssa E

2017-01-01

Spatial patterns of Zn, Pb and Cd deposition in Cape Krusenstern National Monument (CAKR), Alaska, adjacent to the Red Dog Mine haul road, were characterized in 2001 and 2006 using Hylocomium moss tissue as a biomonitor. Elevated concentrations of Cd, Pb, and Zn in moss tissue decreased logarithmically away from the haul road and the marine port. The metals concentrations in the two years were compared using Bayesian posterior predictions on a new sampling grid to which both data sets were fit. Posterior predictions were simulated 200 times both on a coarse grid of 2,357 points and by distance-based strata including subsets of these points. Compared to 2001, Zn and Pb concentrations in 2006 were 31 to 54% lower in the 3 sampling strata closest to the haul road (0-100, 100-2000 and 2000-4000 m). Pb decreased by 40% in the stratum 4,000-5,000 m from the haul road. Cd decreased significantly by 38% immediately adjacent to the road (0-100m), had an 89% probability of a small decrease 100-2000 m from the road, and showed moderate probabilities (56-71%) for increase at greater distances. There was no significant change over time (with probabilities all ≤ 85%) for any of the 3 elements in more distant reference areas (40-60 km). As in 2001, elemental concentrations in 2006 were higher on the north side of the road. Reductions in deposition have followed a large investment in infrastructure to control fugitive dust escapement at the mine and port sites, operational controls, and road dust mitigation. Fugitive dust escapement, while much reduced, is still resulting in elevated concentrations of Zn, Pb and Cd out to 5,000 m from the haul road. Zn and Pb levels were slightly above arctic baseline values in southern CAKR reference areas.

Trends in spatial patterns of heavy metal deposition on national park service lands along the Red Dog Mine haul road, Alaska, 2001–2006

PubMed Central

Ver Hoef, Jay M.; Berryman, Shanti D.; Mines, Anaka; Geiser, Linda H.; Hasselbach, Linda M.; Shiel, Alyssa E.

2017-01-01

Spatial patterns of Zn, Pb and Cd deposition in Cape Krusenstern National Monument (CAKR), Alaska, adjacent to the Red Dog Mine haul road, were characterized in 2001 and 2006 using Hylocomium moss tissue as a biomonitor. Elevated concentrations of Cd, Pb, and Zn in moss tissue decreased logarithmically away from the haul road and the marine port. The metals concentrations in the two years were compared using Bayesian posterior predictions on a new sampling grid to which both data sets were fit. Posterior predictions were simulated 200 times both on a coarse grid of 2,357 points and by distance-based strata including subsets of these points. Compared to 2001, Zn and Pb concentrations in 2006 were 31 to 54% lower in the 3 sampling strata closest to the haul road (0–100, 100–2000 and 2000–4000 m). Pb decreased by 40% in the stratum 4,000–5,000 m from the haul road. Cd decreased significantly by 38% immediately adjacent to the road (0–100m), had an 89% probability of a small decrease 100–2000 m from the road, and showed moderate probabilities (56–71%) for increase at greater distances. There was no significant change over time (with probabilities all ≤ 85%) for any of the 3 elements in more distant reference areas (40–60 km). As in 2001, elemental concentrations in 2006 were higher on the north side of the road. Reductions in deposition have followed a large investment in infrastructure to control fugitive dust escapement at the mine and port sites, operational controls, and road dust mitigation. Fugitive dust escapement, while much reduced, is still resulting in elevated concentrations of Zn, Pb and Cd out to 5,000 m from the haul road. Zn and Pb levels were slightly above arctic baseline values in southern CAKR reference areas. PMID:28542369

Superfund Record of Decision (EPA Region 8): Anaconda Smelter Site, Mill Creek, Montana (first remedial action), October 1988

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1988-10-02

The 160-acre community of Mill Creek is located in Deerlodge County, Montana, immediately adjacent to the Anaconda Smelter NPL site. The community of Mill Creek has been contaminated for over 100 years with smelter emissions, fugitive emissions of flu dust at the smelter, and continued fugitive emissions emanating from adjacent highly contaminated soils. Settled flue emissions in the community of Mill Creek, from the now-defunct copper-smelting operation, contain arsenic, cadmium, and lead. Environmental siting of the community and biological testing of pre-school children, led EPA to conclude that contamination in the Mill Creek area poses an imminent and substantial endangermentmore » to the health of individuals residing there. The primary contaminant of concern at this site is arsenic. Cadmium and lead are secondary contaminants of concern. The selected remedial action for the site includes: permanent relocation of all residents (8 homes) with temporary erosional stabilization of disturbed areas by establishing and maintaining a vegetative cover; demolition, consolidation, and storage.« less

Particulate matter over a seven year period in urban and rural areas within, proximal and far from mining and power station operations in Greece.

PubMed

Triantafyllou, A G; Zoras, S; Evagelopoulos, V

2006-11-01

Lignite mining operations and lignite-fired power stations result in major particulate pollution (fly ash and fugitive dust) problems in the areas surrounding these activities. The problem is more complicated, especially, for urban areas located not far from these activities, due to additional contribution from the urban pollution sources. Knowledge of the distribution of airborne particulate matter into size fraction has become an increasing area of focus when examining the effects of particulate pollution. On the other hand, airborne particle concentration measurements are useful in order to assess the air pollution levels based on national and international air quality standards. These measurements are also necessary for developing air pollutants control strategies or for evaluating the effectiveness of these strategies, especially, for long periods. In this study an attempt is made in order to investigate the particle size distribution of fly ash and fugitive dust in a heavy industrialized (mining and power stations operations) area with complex terrain in the northwestern part of Greece. Parallel total suspended particulates (TSP) and particulate matter with an aerodynamic diameter less than 10 microm (PM10) concentrations are analyzed. These measurements gathered from thirteen monitoring stations located in the greater area of interest. Spatial, temporal variation and trend are analyzed over the last seven years. Furthermore, the geographical variation of PM10 - TSP correlation and PM10/TSP ratio are investigated and compared to those in the literature. The analysis has indicated that a complex system of sources and meteorological conditions modulate the particulate pollution of the examined area.

[Influence of traffic restriction on road and construction fugitive dust].

PubMed

Tian, Gang; Li, Gang; Qin, Jian-Ping; Fan, Shou-Bin; Huang, Yu-Hu; Nie, Lei

2009-05-15

By monitoring the road and construction dust fall continuously during the "Good Luck Beijing" sport events, the reduction of road and construction dust fall caused by traffic restriction was studied. The contribution rate of road and construction dust to particulate matter of Beijing atmosphere environment, and the emission ratio of it to total local PM10 emission were analyzed. The results show that the traffic restriction reduces road and construction dust fall significantly. The dust fall average value of ring roads was 0.27 g x (m2 x d)(-1) in the "traffic restriction" period, and the values were 0.81 and 0.59 g x (m2 x d)(-1) 1 month and 7 days before. The dust fall average value of major arterial and minor arterial was 0.21 g x (m2 x d)(-1) in the "traffic restriction" period, and the values were 0.54 and 0.58 g x (m2 x d)(-1) 1 month and 7 days before. The roads emission reduced 60%-70% compared with before traffic restriction. The dust fall average values of civil architecture and utility architecture were 0.61 and 1.06 g x (m2 x d)(-1) in the "traffic restriction" period, and the values were 1.15 and 1.55 g x (m2 x d)(-1) 20 days before. The construction dust reduced 30%-47% compared with 20 days before traffic restriction. Road and construction dust emission are the main source of atmosphere particulate matter in Beijing, and its contribution to ambient PM10 concentration is 21%-36%. PM10 emitted from roads and constructions account for 42%-72% and 30%-51% of local emission while the local PM10 account for 50% and 70% of the total emission.

Determination of water-soluble elements in PM2.5, PM10, and PM2.5-10 collected in the surroundings of power plants

NASA Astrophysics Data System (ADS)

Zajusz-Zubek, Elwira; Mainka, Anna; Kaczmarek, Konrad

2018-01-01

The analysis reported in this study was performed to characterize the concentrations and water-soluble content of trace elements (As, Cd, Co, Cr, Hg, Mn, Ni, Pb, Sb and Se) in PM2.5, PM10 and PM2.5-10 samples collected in the surroundings of power plants in southern Poland. The solubility of trace elements bound to PM2.5 and PM10 was higher than for PM2.5-10, and in most cases, significant differences were revealed in the relative percentage concentrations of the water-soluble fractions. The occurrence of Cd, Cr, Mn, Ni, Pb and Se in first PCA (Principal Component Analysis) factor (PC1) - indicate coal combustion processes as the potential source of these elements. Other factors indicate two further anthropogenic sources: the resuspension of road dust due to vehicular activities and waste burning in domestic sources - factor (PC2), and, soil dust sources affected by fugitive dust from the mining processes and unpaved roads, as well as transportation and deposition of coal -factor (PC3).

Fort Carson Fugitive Dust Generation and Transport Study: Lessons Learned.

DTIC Science & Technology

1981-11-01

15 99.9 024.9 1309 9/16 99.9 058.6 1307 9/17 99.9 029.2 1361 9/18 99.9 058.8 1353 9/19 99.9 030.2 1352 9/20 99.9 019.4 1347 9/21 99.9 036.6 1348 9/22...0413 4/25 99.9 059.7 0412 4/26 99.9 039.3 0417 4/27 99.9 042.0 0423 4/28 99.9 023.4 0428 4/29 99.9 007.8 0425 4/30 007.8 0425 Geometric Mean - 25.561

CELiS (Compact Eyesafe Lidar System), a portable 1.5 μm elastic lidar system for rapid aerosol concentration measurement: Part 1, Instrument Design and Operation

NASA Astrophysics Data System (ADS)

Bird, A. W.; Wojcik, M.; Moore, K. D.; Lemon, R.

2014-12-01

CELiS (Compact Eyesafe Lidar System) is an elastic lidar system conceived for the purpose of monitoring air quality environmental compliance regarding particulate matter (PM) generated from off-road use of wheeled and tracked vehicles. CELiS is a prototype instrument development by the Space Dynamics Laboratory to demonstrate a small, low power, eye-safe lidar system capable of monitoring PM fence-line concentration of fugitive dust from off-road vehicle activity as part of the SERDP (Strategic Environmental Research and Development Program) Measurement and Modeling of Fugitive Dust Emission from Off-Road Department of Defense Activities program. CELiS is small, lightweight and easily transportable for quick setup and measurement of PM concentration and emissions. The instrument is mounted on Moog Quickset pan and tilt positioner. Ground support equipment includes portable racks with laser power and cooler, power supplies, readout electronics and computer. The complete CELiS instrument weighs less than 300 lbs., is less than 1 cubic meters in volume and uses 700 W of 120V AC power. CELiS has a working range of better than 6km and a range resolution of 1.5m-6m. CELiS operates in a biaxial configuration at the 1.5μm eyesafe wavelength. The receiver is an off-axis parabolic (OAP) telescope, aft-optics and alignment assembly and InGaAs APD detector readout. The transmitter is a 20Hz PRF - 25mJ Quantel 1.574 μm laser with a 20x beam expander. Both the receiver and transmitter are mounted on a carbon fiber optical breadboard with a custom mounting solution to minimize misalignment due to thermal operating range (0-40 C) and pointing vectors. Any lidar system used to monitor fence-line PM emissions related to off-road training activities will be subject to a strict eye-safety requirement to protect both troops and wildlife. CELiS is eyesafe at the output aperture. CELiS has participated in two Dugway Proving Ground Lidar exercises performing within expectations. Retrieval of particulate matter concentration is presented in companion poster by K. Moore.

Simulation of large particle transport near the surface under stable conditions: comparison with the Hanford tracer experiments

NASA Astrophysics Data System (ADS)

Kim, Eugene; Larson, Timothy

A plume model is presented describing the downwind transport of large particles (1-100 μm) under stable conditions. The model includes both vertical variations in wind speed and turbulence intensity as well as an algorithm for particle deposition at the surface. Model predictions compare favorably with the Hanford single and dual tracer experiments of crosswind integrated concentration (for particles: relative bias=-0.02 and 0.16, normalized mean square error=0.61 and 0.14, for the single and dual tracer experiments, respectively), whereas the US EPA's fugitive dust model consistently overestimates the observed concentrations at downwind distances beyond several hundred meters (for particles: relative bias=0.31 and 2.26, mean square error=0.42 and 1.71, respectively). For either plume model, the measured ratio of particle to gas concentration is consistently overestimated when using the deposition velocity algorithm of Sehmel and Hodgson (1978. DOE Report PNL-SA-6721, Pacific Northwest Laboratories, Richland, WA). In contrast, these same ratios are predicted with relatively little bias when using the algorithm of Kim et al. (2000. Atmospheric Environment 34 (15), 2387-2397).

Advancing Knowledge on Fugitive Natural Gas from Energy Resource Development at a Controlled Release Field Observatory

NASA Astrophysics Data System (ADS)

Cahill, A. G.; Chao, J.; Forde, O.; Prystupa, E.; Mayer, K. U.; Black, T. A.; Tannant, D. D.; Crowe, S.; Hallam, S.; Mayer, B.; Lauer, R. M.; van Geloven, C.; Welch, L. A.; Salas, C.; Levson, V.; Risk, D. A.; Beckie, R. D.

2017-12-01

Fugitive gas, comprised primarily of methane, can be unintentionally released from upstream oil and gas development either at surface from leaky infrastructure or in the subsurface through failure of energy well bore integrity. For the latter, defective cement seals around energy well casings may permit buoyant flow of natural gas from the deeper subsurface towards shallow aquifers, the ground surface and potentially into the atmosphere. Concerns associated with fugitive gas release at surface and in the subsurface include contributions to greenhouse gas emissions, subsurface migration leading to accumulation in nearby infrastructure and impacts to groundwater quality. Current knowledge of the extent of fugitive gas leakage including how to best detect and monitor over time, and particularly its migration and fate in the subsurface, is incomplete. We have established an experimental field observatory for evaluating fugitive gas leakage in an area of historic and ongoing hydrocarbon resource development within the Montney Resource Play of the Western Canadian Sedimentary Basin, British Columbia, Canada. Natural gas will be intentionally released at surface and up to 25 m below surface at various rates and durations. Resulting migration patterns and impacts will be evaluated through examination of the geology, hydrogeology, hydro-geochemistry, isotope geochemistry, hydro-geophysics, vadose zone and soil gas processes, microbiology, and atmospheric conditions. The use of unmanned aerial vehicles and remote sensors for monitoring and detection of methane will also be assessed for suitability as environmental monitoring tools. Here we outline the experimental design and describe initial research conducted to develop a detailed site conceptual model of the field observatory. Subsequently, results attained from pilot surface and sub-surface controlled natural gas releases conducted in late summer 2017 will be presented as well as results of numerical modelling conducted to plan methane release experiments in 2018 and onwards. This research will create knowledge which informs strategies to detect and monitor fugitive gas fluxes at the surface and in groundwater; as well as guide associated regulatory and technical policies.

Salt Efflorescence Effects on Soil Surface Erodibility and Dust Emissions

NASA Astrophysics Data System (ADS)

Van Pelt, R. S.; Zhang, G.

2017-12-01

Soluble salts resulting from weathering of geological materials often form surface crusts or efflorescences in areas with shallow saline groundwater. In many cases, the affected areas are susceptible to wind erosion due to their lack of protective vegetation and their flat topography. Fugitive dusts containing soluble salts affect the biogeochemistry of deposition regions and may result in respiratory irritation during transport. We created efflorescent crusts on soil trays by surface evaporation of single salt solutions and bombarded the resultant efflorescences with quartz abrader sand in a laboratory wind tunnel. Four replicate trays containing a Torrifluvent soil affected by one of nine salts commonly found in arid and semiarid streams were tested and the emissions were captured by an aspirated multi-stage deposition and filtering system. We found that in most cases the efflorescent crust reduced the soil surface erodibility but also resulted in the emission of salt rich dust. Two of the salts, sodium thiosulfate and calcium chloride, resulted in increased soil volume and erodibility. However, one of the calcium chloride replicates was tested after an outbreak of humid air caused hygroscopic wetting of the soil and it became indurated upon drying greatly decreasing the erodibility. Although saline affected soils are not used for agricultural production and degradation is not a great concern, the release of salt rich dust is an area of environmental concern and steps to control the dust emissions from affected soils should be developed. Future testing will utilize suites of salts found in streams of arid and semiarid regions.

40 CFR 49.126 - Rule for limiting fugitive particulate matter emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Rule for limiting fugitive particulate matter emissions. (a) What is the purpose of this section? This section limits the amount of fugitive particulate matter that may be emitted from certain air pollution... source of fugitive particulate matter emissions. (c) What is exempted from this section? This section...

Size-Resolved Dust and Aerosol Contaminants Associated with Copper and Lead Smelting Emissions: Implications for Emissions Management and Human Health

PubMed Central

Csavina, Janae; Taylor, Mark P.; Félix, Omar; Rine, Kyle P.; Sáez, A. Eduardo; Betterton, Eric A.

2014-01-01

Mining operations, including crushing, grinding, smelting, refining, and tailings management, are a significant source of airborne metal and metalloid contaminants such as As, Pb and other potentially toxic elements. In this work, we show that size-resolved concentrations of As and Pb generally follow a bimodal distribution with the majority of contaminants in the fine size fraction (< 1 μm) around mining activities that include smelting operations at various sites in Australia and Arizona. This evidence suggests that contaminated fine particles (< 1 μm) are the result of vapor condensation and coagulation from smelting operations while coarse particles are most likely the result of windblown dust from contaminated mine tailings and fugitive emissions from crushing and grinding activities. These results on the size distribution of contaminants around mining operations are reported to demonstrate the ubiquitous nature of this phenomenon so that more effective emissions management and practices that minimize health risks associated with metal extraction and processing can be developed. PMID:24995641

Lead contamination around secondary smelters: estimation of dispersal and accumulation by humans.

PubMed

Roberts, T M; Hutchinson, T C; Paciga, J; Chattopadhyay, A; Jervis, R E; VanLoon, J; Parkinson, D K

1974-12-20

A high rate of lead fallout around two secondary lead smelters originated mainly from episodal large-particulate emissions from low-level fugitive sources rather than from stack fumes. The lead content of dustfall, and consequently of soil, vegetation, and outdoor dust, decreased exponentially with distance from the two smelters. Between 13 and 30 percent of the children living in the contaminated areas had absorbed excessive amounts of lead (more than 40 micrograms per 100 milliliters of blood and more than 100 micrograms per gram of hair) as compared with less than 1 percent in a control group. A relationship between blood and hair was established which indicated that the absorption was fairly constant for most children examined. It seemned that the ingestion of contaminated dirt and dusts rather than "paint pica" was the major route of lead intake. Metabolic changes were found in most of 21 children selected from those with excessive lead absorption; 10 to 15 percent of this group showed subtle neurological dysfunctions and minor psychomotor abnormalities.

Wildlife conservation and solar energy development in the Desert Southwest, United States

USGS Publications Warehouse

Lovich, Jeffrey E.; Ennen, Josua R.

2011-01-01

Large areas of public land are currently being permitted or evaluated for utility-scale solar energy development (USSED) in the southwestern United States, including areas with high biodiversity and protected species. However, peer-reviewed studies of the effects of USSED on wildlife are lacking. The potential effects of the construction and the eventual decommissioning of solar energy facilities include the direct mortality of wildlife; environmental impacts of fugitive dust and dust suppressants; destruction and modification of habitat, including the impacts of roads; and off-site impacts related to construction material acquisition, processing, and transportation. The potential effects of the operation and maintenance of the facilities include habitat fragmentation and barriers to gene flow, increased noise, electromagnetic field generation, microclimate alteration, pollution, water consumption, and fire. Facility design effects, the efficacy of site-selection criteria, and the cumulative effects of USSED on regional wildlife populations are unknown. Currently available peer-reviewed data are insufficient to allow a rigorous assessment of the impact of USSED on wildlife.

Chemical characterization of sanding dust and methylene chloride usage in automotive refinishing: implications for occupational and environmental health.

PubMed

Enander, Richard T; Gute, David M; Cohen, Howard J; Brown, Linfield C; Desmaris, Anne Marie C; Missaghian, Richard

2002-01-01

Surface preparation activities conducted during automotive refinishing present several potential human health and environmental risks. This study examines the chemical composition of vehicle sanding dust and the prevalence of methylene chloride use as a basis for evaluating potential chemical exposures in the work environment, fugitive environmental releases, and take-home toxics. This article reports on the findings of (1) a statewide technology and work practices survey of 353 licensed auto body shops and (2) laboratory analyses of sanding dust representing more than 200 vehicles, 10 commercial body filler compounds, and work shirts worn during vehicle sanding while using nonventilated equipment. Survey data revealed that the majority of shops (78%) do not use ventilated sanding equipment, that most workers (55%) take their work clothes and shoes home at the end of the workday, and that 17% of the respondents used a methylene chloride-based paint stripper as an adjunct to mechanical sanding. Laboratory results showed that Pb, As, Cr, Mn, and Ni were present in the sanding dust at every facility tested. Lead concentrations in sanding dust were found to be highest at facilities that performed complete vehicle refinishing (range 770 to 7300 ppm) and at a collision repair shop that used a high-lead content body filler compound (1800 ppm). Hexavalent chromium also was found in two vocational high school paint dust samples at concentrations of 54 and 710 ppm. When total lead and chromium concentrations reached 7300 and 2300 ppm, respectively, facility sanding dust samples failed the U.S. Environmental Protection Agency's Toxicity Characteristic Leaching Procedure for hazardous waste. Metals found in the sanding dust also were present on the work shirts of technicians-ranging from 0.06 (Cd) to 81 (Mg) microg/inch2 of cloth-who sanded on paint without ventilated equipment. Results suggest that sanding dust and methylene chloride paint strippers used in vehicle resurfacing operations pose a potential hazard to human health and the environment.

Plutonium release from the 903 pad at Rocky Flats.

PubMed

Mongan, T R; Ripple, S R; Winges, K D

1996-10-01

The Colorado Department of Public Health and Environment (CDH) sponsored a study to reconstruct contaminant doses to the public from operations at the Rocky Flats nuclear weapons plant. This analysis of the accidental release of plutonium from the area known as the 903 Pad is part of the CDH study. In the 1950's and 1960's, 55-gallon drums of waste oil contaminated with plutonium, and uranium were stored outdoors at the 903 Pad. The drums corroded, leaking contaminated oil onto soil subsequently carried off-site by the wind. The plutonium release is estimated using environmental data from the 1960's and 1970's and an atmospheric transport model for fugitive dust. The best estimate of total plutonium release to areas beyond plant-owned property is about 0.26 TBq (7 Ci). Off-site airborne concentrations and deposition of plutonium are estimated for dose calculation purposes. The best estimate of the highest predicted off-site effective dose is approximately 72 microSv (7.2 mrem).

75 FR 48880 - Approval and Promulgation of Gila River Indian Community's Tribal Implementation Plan

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-12

...The Environmental Protection Agency (EPA) proposes to approve the Gila River Indian Community's (GRIC or the Tribe) Tribal Implementation Plan (TIP) under the Clean Air Act (CAA) to regulate air pollution within the exterior boundaries of the Tribe's reservation. The proposed TIP is one of four CAA regulatory programs that comprise the Tribe's Air Quality Management Plan (AQMP). EPA approved the Tribe for treatment in the same manner as a State (Treatment as State or TAS) for purposes of administering the AQMP and other CAA authorities on October 21, 2009. In this action we propose to act only on those portions of the AQMP that constitute a TIP containing severable elements of an implementation plan under CAA section 110(a). The proposed TIP includes general and emergency authorities, ambient air quality standards, permitting requirements for minor sources of air pollution, enforcement authorities, procedures for administrative appeals and judicial review in Tribal court, requirements for area sources of fugitive dust and fugitive particulate matter, general prohibitory rules, and source category-specific emission limitations. The purpose of the proposed TIP is to implement, maintain, and enforce the National Ambient Air Quality Standards (NAAQS) in the GRIC reservation. The intended effect of today's proposed action is to make the GRIC TIP federally enforceable.

Concentrations and bioaccessibility of metals in vegetation and dust near a mining haul road, Cape Krusenstern National Monument, Alaska

USGS Publications Warehouse

Brumbaugh, William G.; Morman, Suzette A.; May, Thomas W.

2011-01-01

Vegetation, sub-surface peat, and road dust were sampled near the Delong Mountain Transportation System (DMTS) haul road in northwest Alaska in 2005-2006 to document aluminum, barium, cadmium, lead, and zinc concentrations, and to evaluate bioaccessibility of these metals. The DMTS haul road is the transport corridor between Red Dog Mine (a large-scale, lead-zinc mine and mill) and the coastal shipping port, and it traverses National Park Service lands. Compared to reference locations, total metal concentrations in four types of vegetation (birch, cranberry, and willow leaves, and cotton grass blades/stalks) collected 25 m from the haul road were enriched on average by factors of 3.5 for zinc, 8.0 for barium, 20 for cadmium, and 150 for lead. Triple rinsing of vegetation with a water/methanol mixture reduced metals concentrations by at most 50%, and cadmium and zinc concentrations were least affected by rinsing. Cadmium and zinc bioaccessibility was greater in vegetation (50% to 100%) than in dust (15% to 20%); whereas the opposite pattern was observed for lead bioaccessibility (<30% in vegetation; 50% in dust). Barium exhibited low-to-intermediate bioaccessibility in dust and vegetation (20% to 40%), whereas aluminum bioaccessibility was relatively low (<6%) in all sample types. Our reconnaissance-level study indicates that clean-up and improvements in lead/zinc concentrate transfer activities have been effective; however, as of 2006, metal dispersion from past and/or present releases of fugitive dusts along the DMTS road still may have been contributing to elevated metals in surface vegetation. Vegetation was most enriched in lead, but because bioaccessibility of cadmium was greater, any potential risks to animals that forage near the haul road might be equally important for both of these metals.

Dust Plume Modeling at Fort Bliss: Full Training Scenario

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chapman, Elaine G.; Rishel, Jeremy P.; Rutz, Frederick C.

2006-09-26

The potential for air quality impacts from heavy mechanized vehicles operating in the training ranges and on the unpaved main supply routes at Fort Bliss is being investigated. The investigation uses the atmospheric modeling system DUSTRAN to simulate fugitive dust emission and dispersion from typical activities occurring on the installation. This report conveys the results of DUSTRAN simulations conducted using a “Full Training” scenario developed by Fort Bliss personnel. he Full Training scenario includes simultaneous off-road activities of two full Heavy Brigade Combat Teams (HCBTs) and one HCBT battalion on three training ranges. Simulations were conducted for the six-day period,more » April 25-30, 2005, using previously archived meteorological records. Simulation results are presented in the form of 24-hour average PM10 plots and peak 1-hour PM10 concentration plots, where the concentrations represent contributions resulting from the specified military vehicular activities, not total ambient PM10 concentrations. Results indicate that the highest PM10 contribution concentrations occurred on April 30 when winds were light and variable. Under such conditions, lofted particulates generated by vehicular movement stay in the area of generation and are not readily dispersed. The effect of training duration was investigated by comparing simulations with vehicular activity extending over a ten hour period (0700 to 1700 MST) with simulations where vehicular activity was compressed into a one hour period (0700 to 0800 MST). Compressing all vehicular activity into one hour led to higher peak one-hour and 24-hour average concentration contributions, often substantially higher.« less

Size-resolved dust and aerosol contaminants associated with copper and lead smelting emissions: implications for emission management and human health.

PubMed

Csavina, Janae; Taylor, Mark P; Félix, Omar; Rine, Kyle P; Eduardo Sáez, A; Betterton, Eric A

2014-09-15

Mining operations, including crushing, grinding, smelting, refining, and tailings management, are a significant source of airborne metal and metalloid contaminants such as As, Pb and other potentially toxic elements. In this work, we show that size-resolved concentrations of As and Pb generally follow a bimodal distribution with the majority of contaminants in the fine size fraction (<1 μm) around mining activities that include smelting operations at various sites in Australia and Arizona. This evidence suggests that contaminated fine particles (<1 μm) are the result of vapor condensation and coagulation from smelting operations while coarse particles are most likely the result of windblown dust from contaminated mine tailings and fugitive emissions from crushing and grinding activities. These results on the size distribution of contaminants around mining operations are reported to demonstrate the ubiquitous nature of this phenomenon so that more effective emission management and practices that minimize health risks associated with metal extraction and processing can be developed. Copyright © 2014 Elsevier B.V. All rights reserved.

Superfund record of decision amendment (EPA Region 5): Carter Industrials Site, Detroit, MI, February 28, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

This decision document changes a decision made on September 18, 1991 in which the United States Environmental Protection Agency (U.S. EPA) chose low-temperature thermal desorption as the remedy for PCB contamination at the Carter Industrials Site in Detroit, Michigan. U.S. EPA is hereby amending the 1991 Record of Decision (PB92-964126) to select off-site disposal as the remedy. This response action addresses remediation of PCB-contaminated soil, debris, and buildings at the Carter Industrials Site. The principal threats posed by conditions at the Site include inhalation of volatilized PCBs and fugitive dust, and dermal contact with contaminated materials. The amended remedy willmore » eliminate these threats.« less

Environmental Assessment for the Radar Tomography Range and Equipment Storage Facility, Wright-Patterson Air Force Base, Ohio

DTIC Science & Technology

2012-10-01

relocated to Wright-Patterson AFB, and therefore, the antenna to~ e ! ring and services must relocate to Wright-Patterson AFB to continue the AFRLIRY...Support, 88 ABW/CEANQ, Wright‐Patterson Air Force Base.  E ‐ mail to Tamar Krantz, Labat Environmental regarding Title V and fugitive dust permits April...Greene, and Montgomery  Counties, Ohio. Division of Air Pollution Control. May 2011. Accessed on August 28, 2011 at  http://www.epa.ohio.gov/ portals /27

Simplified and low cost optical remote sensing technology for fenceline monitoring of fugitive releases

EPA Science Inventory

Reducing fugitive emissions of hazardous air pollutants from industrial facilities is an ongoing priority for the U.S. Environmental Protection Agency (EPA). Unlike stack emissions, fugitive releases are difficult to detect due to their spatial extent and inherent temporal variab...

75 FR 6823 - Prevention of Significant Deterioration (PSD) and Nonattainment New Source Review (NSR...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-11

...-AP73 Prevention of Significant Deterioration (PSD) and Nonattainment New Source Review (NSR... Review (NSR): Reconsideration of Fugitive Emissions'' (``Fugitive Emissions Rule''). The Fugitive... whether a physical or operation change results in a major modification only for sources in industries that...

Sphagnum Moss as an Indicator of Contemporary Rates of Atmospheric Dust Deposition in the Athabasca Bituminous Sands Region.

PubMed

Mullan-Boudreau, Gillian; Belland, Rene; Devito, Kevin; Noernberg, Tommy; Pelletier, Rick; Shotyk, William

2017-07-05

Sphagnum moss was collected from ombrotrophic (rain-fed) peat bogs to quantify dust emissions from the open-pit mining and upgrading of Athabasca bituminous sands (ABS). A total of 30 bogs were sampled in the ABS region, and 5 were sampled in central Alberta. Ash was separated into the acid-insoluble ash (AIA) and acid-soluble ash (ASA) fractions using HCl. The AIA concentrations increase toward industry from 0.4 ± 0.5% to 4.7 ± 2.0% over a distance of 30 km; the control site at the Utikuma Region Study Area (URSA) yielded 0.29 ± 0.07% (n = 30). Mass accumulations rates showed similar spatial variation. The morphology and mineralogy of the AIA particles were studied using scanning electron microscopy and energy-dispersive X-ray analysis and the particle size distributions using optical methods. Particle size was more variable in moss closer to industry. Major ions in the ASA fraction showed elevated accumulation rates of Ca, K, Fe, Mg, P, and S, with P being up to 5 times greater in samples nearest industry compared to those in distal locations. Given that P has been regarded as the growth-limiting nutrient in bogs, fertilization of nutrient-poor ecosystems, such as these from fugitive emissions of dusts from open-pit mining, may have long-term ecological ramifications.

Fine particulate matter emissions inventories: comparisons of emissions estimates with observations from recent field programs.

PubMed

Simon, Heather; Allen, David T; Wittig, Ann E

2008-02-01

Emissions inventories of fine particulate matter (PM2.5) were compared with estimates of emissions based on data emerging from U.S. Environment Protection Agency Particulate Matter Supersites and other field programs. Six source categories for PM2.5 emissions were reviewed: on-road mobile sources, nonroad mobile sources, cooking, biomass combustion, fugitive dust, and stationary sources. Ammonia emissions from all of the source categories were also examined. Regional emissions inventories of PM in the exhaust from on-road and nonroad sources were generally consistent with ambient observations, though uncertainties in some emission factors were twice as large as the emission factors. In contrast, emissions inventories of road dust were up to an order of magnitude larger than ambient observations, and estimated brake wear and tire dust emissions were half as large as ambient observations in urban areas. Although comprehensive nationwide emissions inventories of PM2.5 from cooking sources and biomass burning are not yet available, observational data in urban areas suggest that cooking sources account for approximately 5-20% of total primary emissions (excluding dust), and biomass burning sources are highly dependent on region. Finally, relatively few observational data were available to assess the accuracy of emission estimates for stationary sources. Overall, the uncertainties in primary emissions for PM2.s are substantial. Similar uncertainties exist for ammonia emissions. Because of these uncertainties, the design of PM2.5 control strategies should be based on inventories that have been refined by a combination of bottom-up and top-down methods.

Concentrations and bioaccessibility of metals in vegetation and dust near a mining haul road, Cape Krusenstern National Monument, Alaska

USGS Publications Warehouse

Brumbaugh, W.G.; Morman, S.A.; May, T.W.

2011-01-01

Vegetation, sub-surface peat, and road dust were sampled near the Delong Mountain Transportation System (DMTS) haul road in northwest Alaska in 2005-2006 to document aluminum, barium, cadmium, lead, and zinc concentrations, and to evaluate bioaccessibility of these metals. The DMTS haul road is the transport corridor between Red Dog Mine (a large-scale, lead-zinc mine and mill) and the coastal shipping port, and it traverses National Park Service lands. Compared to reference locations, total metal concentrations in four types of vegetation (birch, cranberry, and willow leaves, and cotton grass blades/stalks) collected 25 m from the haul road were enriched on average by factors of 3.5 for zinc, 8.0 for barium, 20 for cadmium, and 150 for lead. Triple rinsing of vegetation with a water/methanol mixture reduced metals concentrations by at most 50%, and cadmium and zinc concentrations were least affected by rinsing. Cadmium and zinc bioaccessibility was greater in vegetation (50% to 100%) than in dust (15% to 20%); whereas the opposite pattern was observed for lead bioaccessibility (<30% in vegetation; 50% in dust). Barium exhibited low-to-intermediate bioaccessibility in dust and vegetation (20% to 40%), whereas aluminum bioaccessibility was relatively low (<6%) in all sample types. Our reconnaissance-level study indicates that clean-up and improvements in lead/zinc concentrate transfer activities have been effective; however, as of 2006, metal dispersion from past and/or present releases of fugitive dusts along the DMTS road still may have been contributing to elevated metals in surface vegetation. Vegetation was most enriched in lead, but because bioaccessibility of cadmium was greater, any potential risks to animals that forage near the haul road might be equally important for both of these metals. ?? 2011 Springer Science+Business Media B.V. (outside the USA).

40 CFR Table 3 to Subpart Ooo of... - Fugitive Emission Limits

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Fugitive Emission Limits 3 Table 3 to... Mineral Processing Plants Pt. 60, Subpt. OOO, Table 3 Table 3 to Subpart OOO of Part 60—Fugitive Emission...; andPeriodic inspections of water sprays according to § 60.674(b) and § 60.676(b); and A repeat...

40 CFR Table 3 to Subpart Ooo of... - Fugitive Emission Limits

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Fugitive Emission Limits 3 Table 3 to... Mineral Processing Plants Subpt. OOO, Table 3 Table 3 to Subpart OOO of Part 60—Fugitive Emission Limits... performance test according to § 60.11 of this part and § 60.675 of this subpart; andPeriodic inspections of...

40 CFR Table 3 to Subpart Ooo of... - Fugitive Emission Limits

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Fugitive Emission Limits 3 Table 3 to... Mineral Processing Plants Pt. 60, Subpt. OOO, Table 3 Table 3 to Subpart OOO of Part 60—Fugitive Emission...; andPeriodic inspections of water sprays according to § 60.674(b) and § 60.676(b); and A repeat...

40 CFR Table 3 to Subpart Ooo - Fugitive Emission Limits

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Fugitive Emission Limits 3 Table 3 to... Processing Plants Subpt. OOO, Table 3 Table 3 to Subpart OOO—Fugitive Emission Limits Table 3 to Subpart OOO...; andPeriodic inspections of water sprays according to § 60.674(b) and § 60.676(b); and A repeat...

40 CFR Table 3 to Subpart Ooo - Fugitive Emission Limits

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Fugitive Emission Limits 3 Table 3 to... Processing Plants Subpt. OOO, Table 3 Table 3 to Subpart OOO—Fugitive Emission Limits Table 3 to Subpart OOO...; andPeriodic inspections of water sprays according to § 60.674(b) and § 60.676(b); and A repeat...

40 CFR 63.7292 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2010 CFR

2010-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? (a...

40 CFR 63.7291 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2010 CFR

2010-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? (a...

40 CFR 63.7291 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2012 CFR

2012-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? (a...

40 CFR 63.7292 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2012 CFR

2012-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? (a...

40 CFR 63.7291 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2013 CFR

2013-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? (a...

40 CFR 63.7292 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2011 CFR

2011-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? (a...

40 CFR 63.7292 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2013 CFR

2013-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? (a...

40 CFR 63.7291 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2011 CFR

2011-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? (a...

40 CFR 63.7292 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2014 CFR

2014-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with horizontal flues? (a...

40 CFR 63.7291 - What work practice standards must I meet for fugitive pushing emissions if I have a by-product...

Code of Federal Regulations, 2014 CFR

2014-07-01

... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? 63...) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery... meet for fugitive pushing emissions if I have a by-product coke oven battery with vertical flues? (a...

Development of a life-cycle fugitive methane emissions model utilizing device level emissions and activity factors

NASA Astrophysics Data System (ADS)

Englander, J.; Brandt, A. R.

2017-12-01

There has been numerous studies in quantifying the scale of fugitive emissions from across the natural gas value chain. These studies have typically focused on either specific types of equipment (such as valves) or on a single part of the life-cycle of natural gas production (such as gathering stations).1,2 However it has been demonstrated that average emissions factors are not sufficient for representing leaks in the natural gas system.3 In this work, we develop a robust estimate of fugitive emissions rates by incorporating all publicly available studies done at the component up to the process level. From these known studies, we create a database of leaks with normalized nomenclature from which leak estimates can be drawn from actual leak observations. From this database, and parameterized by meta-data such as location, scale of study, or placement in the life-cycle, we construct stochastic emissions factors specific for each process unit. This will be an integrated tool as part of the Oil production greenhouse gas estimator (OPGEE) as well as the Fugitive Emissions Abatement Simulation Toolkit (FEAST) models to enhances their treatment of venting and fugitive emissions, and will be flexible to include user provided data and input parameters.4,51. Thoma, ED et al. Assessment of Uinta Basin Oil and Natural Gas Well Pad Pneumatic Controller Emissions. J. Environ. Prot. 2017. 2. Marchese, AJ et al. Methane Emissions from United States Natural Gas Gathering and Processing. ES&T 2015. doi:10.1021/acs.est.5b02275 3. Brandt, AR et al. Methane Leaks from Natural Gas Systems Follow Extreme Distributions. ES&T 2016. doi:10.1021/acs.est.6b04303 4. El-Houjeiri, HM et al. An open-source LCA tool estimating greenhouse gas emissions from crude oil production using field characteristics. ES&T 2013. doi: 10.1021/es304570m 5. Kemp, CE et al. Comparing Natural Gas Leakage Detection Technologies Using an Open-Source `Virtual Gas Field' Simulator. ES&T 2016. doi:10.1021/acs.est.5b06068

Organic Components and Elemental Carbon in Soils and Ambient Particles near Phoenix, AZ

NASA Astrophysics Data System (ADS)

Fraser, M. P.; Jia, Y.; Clements, A.

2008-12-01

In the desert southwest, fugitive dust emissions contribute significantly to ambient aerosol concentrations. Wind erosion from the arid land is a primary contributor to ambient particulate matter (PM) concentrations but, in regions including Central Arizona, desert lands have been converted for agriculture use and thus agriculture processes constitute another contributor. As the metropolitan Phoenix region expands into these agricultural lands, urban sources and construction also contributes to the ambient PM load. In an effort to identify and access relative contribution of these and other major PM sources in the region, a series of ambient PM samples and soil samples were collected near Higley, AZ, a suburb of Phoenix which has seen rapid urbanization onto agricultural lands between January and May 2008. The soil samples collected were resuspended and samples of resuspended dust were collected to represent particles smaller than 2.5 microns and 10 microns in aerodynamic diameter (PM2.5 and PM10 respectively). The size segregated soil and ambient PM samples were analyzed for bulk mass, elemental and organic carbon content, and a number of specific compounds including ions, metals, alkanes, organic acids, polycyclic aromatic hydrocarbons, and saccharides. The saccharide contribution to soil organic carbon has been studied to elucidate key factors in the soil carbon balance and markers have been developed for tracing fungal metabolites, plant growth and budding and organic matter decay. Using organic markers, the contribution of various sources to PM10 and PM2.5 levels have been determined by positive matrix factorization (PMF) of the ambient aerosol marker concentrations quantified from PM samples. Subsequently, samples of local soil from native and agricultural fields and local roadways wers size- segregated and analyzed in an effort to create a source profile for the dust in the area. A chemical mass balance model has been used to compare with the PMF results where sampled and resuspended agricultural soil, native soil and road dusts are used to characterize direct emissions of these sources to ambient fine and coarse particulate matter.

Chemical composition and source apportionment of PM10 at an urban background site in a high-altitude Latin American megacity (Bogota, Colombia).

PubMed

Ramírez, Omar; Sánchez de la Campa, A M; Amato, Fulvio; Catacolí, Ruth A; Rojas, Néstor Y; de la Rosa, Jesús

2018-02-01

Bogota registers frequent episodes of poor air quality from high PM 10 concentrations. It is one of the main Latin American megacities, located at 2600 m in the tropical Andes, but there is insufficient data on PM 10 source contribution. A characterization of the chemical composition and the source apportionment of PM 10 at an urban background site in Bogota was carried out in this study. Daily samples were collected from June 2015 to May 2016 (a total of 311 samples). Organic carbon (OC), elemental carbon (EC), water soluble compounds (SO 4 2- , Cl - , NO 3 - , NH 4 + ), major elements (Al, Fe, Mg, Ca, Na, K, P) and trace metals (V, Cd, Pb, Sr, Ba, among others) were analyzed. The results were interpreted in terms of their variability during the rainy season (RS) and the dry season (DS). The data obtained revealed that the carbonaceous fraction (∼51%) and mineral dust (23%) were the main PM 10 components, followed by others (15%), Secondary Inorganic Compounds (SIC) (11%) and sea salt (0.4%). The average concentrations of soil, SIC and OC were higher during RS than DS. However, peak values were observed during the DS due to photochemical activity and forest fires. Although trace metals represented <1% of PM 10 , high concentrations of toxic elements such as Pb and Sb on RS, and Cu on DS, were obtained. By using a PMF model, six factors were identified (∼96% PM 10 ) including fugitive dust, road dust, metal processing, secondary PM, vehicles exhaust and industrial emissions. Traffic (exhaust emissions + road dust) was the major PM 10 source, accounting for ∼50% of the PM 10 . The results provided novel data about PM 10 chemical composition, its sources and its seasonal variability during the year, which can help the local government to define control strategies for the main emission sources during the most critical periods. Copyright © 2017 Elsevier Ltd. All rights reserved.

Contamination characteristics and possible sources of PM10 and PM2.5 in different functional areas of Shanghai, China

NASA Astrophysics Data System (ADS)

Wang, Jun; Hu, Zimei; Chen, Yuanyuan; Chen, Zhenlou; Xu, Shiyuan

2013-04-01

From July 2009 through September 2010, PM10 and PM2.5 were collected at two different functional areas in Shanghai (Baoshan district, an industrial area, and Putuo district, a mixed-use area of residential, commercial, and educational compounds). In our analysis, 15 elements were determined using a 710-ES Inductively Coupled Plasma-Emission Spectrometer (ICP-AES). The contents of PM2.5, PM10, and metal elements at the two different sites were comparatively analyzed. The results show that the mean annual concentrations of PM10 and PM2.5 (149.22 μg m-3 and 103.07 μg m-3, respectively) in Baoshan district were significantly higher than those in Putuo district (97.44 μg m-3 and 62.25 μg m-3 respectively). The concentrations of PM10 and PM2.5 were both greatest in winter and lowest in summer, with the two different sites exhibiting the same seasonal variation. It was found that the proportions of 15 metal elements in PM10 and PM2.5 in Baoshan district were 20.49% and 20.56%, respectively, while the proportions in Putuo district were higher (25.98% and 25.93%, respectively). In addition, the proportions of eight heavy metals in PM10 and PM2.5 were 5.50% and 3.07%, respectively, for Baoshan district, while these proportions in Putuo district were 3.18% and 2.77%, respectively, indicating that heavy metal pollution is more pronounced in Baoshan district. Compared with cities in developed countries, the total levels of PM10, PM2.5 and heavy metals in Shanghai were slightly higher. Scanning electron microscopy (SEM) and principal component analysis (PCA) suggested that the possible sources of PM10 in Baoshan district were ground level fugitive dust, traffic sources, and industrial activities, whereas PM2.5 mainly originated from industrial activities, coal combustion, and traffic sources. The sources are same for PM10 and PM2.5 in Putuo region, which originate from traffic sources and ground level fugitive dust.

Estimating sources of Valley Fever pathogen propagation in southern Arizona: A remote sensing approach

NASA Astrophysics Data System (ADS)

Pianalto, Frederick S.

Coccidioidomycosis (Valley Fever) is an environmentally-mediated respiratory disease caused by the inhalation of airborne spores from the fungi Coccidioides spp. The fungi reside in arid and semi-arid soils of the Americas. The disease has increased epidemically in Arizona and other areas within the last two decades. Despite this increase, the ecology of the fungi remains obscure, and environmental antecedents of the disease are largely unstudied. Two sources of soil disturbance, hypothesized to affect soil ecology and initiate spore dissemination, are investigated. Nocturnal desert rodents interact substantially with the soil substrate. Rodents are hypothesized to act as a reservoir of coccidioidomycosis, a mediator of soil properties, and a disseminator of fungal spores. Rodent distributions are poorly mapped for the study area. We build automated multi-linear regression models and decision tree models for ten rodent species using rodent trapping data from the Organ Pipe Cactus National Monument (ORPI) in southwest Arizona with a combination of surface temperature, a vegetation index and its texture, and a suite of topographic rasters. Surface temperature, derived from Landsat TM thermal images, is the most widely selected predictive variable in both automated methods. Construction-related soil disturbance (e.g. road construction, trenching, land stripping, and earthmoving) is a significant source of fugitive dust, which decreases air quality and may carry soil pathogens. Annual differencing of Landsat Thematic Mapper (TM) mid-infrared images is used to create change images, and thresholded change areas are associated with coordinates of local dust inspections. The output metric identifies source areas of soil disturbance, and it estimates the annual amount of dust-producing surface area for eastern Pima County spanning 1994 through 2009. Spatially explicit construction-related soil disturbance and rodent abundance data are compared with coccidioidomycosis incidence data using rank order correlation and regression methods. Construction-related soil disturbance correlates strongly with annual county-wide incidence. It also correlates with Tucson periphery incidence aggregated to zip codes. Abundance values for the desert pocket mouse (Chaetodipus penicillatus), derived from a soil-adjusted vegetation index, aspect (northing) and thermal radiance, correlate with total study period incidence aggregated to zip code.

Summary, synthesis, and significance: Chapter 6

USGS Publications Warehouse

Esque, Todd C.; Nussear, Kenneth E.; Inman, Richard D.; Matocq, Marjorie D.; Weisberg, Peter J.; Dilts, Thomas E.; Leitner, Phillip

2013-01-01

The initial habitat suitability model estimates pre‐European suitable habitat of the Mohave ground squirrel (MGS, Xerospermophilus mohavensis) covering 19,023 km2. Impact scenarios predicted that between 10 percent and 16 percent of suitable habitat has been lost to historical human disturbances, and up to an additional 10 percent may be affected by renewable energy development in the near future. These figures are the result of analyses conducted solely on public lands. State and private lands in the region also have pending proposals for renewable energy on 260 km2, and an additional 3,500 km2 may be available for renewable energy. The sum of potential habitat disturbance on public, State, and private lands could equal up to a quarter of historic suitable habitat from pre‐European settlement levels.   While the analyses conducted here consider direct impacts from the footprint of renewable energy and associated transmission corridors, there are many indirect sources of environmental disturbance related to renewable energy development (Lovich and Ennen 2011). Some of those potentially important to the MGS include: increased fugitive dust and the release of chemicals such as dust suppressants, insulating fluids, and herbicides throughout the operational life of facilities, auditory interference from the sound and vibrations of turbines, increases in predators and invasive species that further alter system processes, and changes in surface flow of water that also influence vegetation that is important in these habitats. However, there is little research in the broader context of these topics for the Mojave Desert ecosystem, and less, if any, about the MGS.  

Natural gas fugitive emissions rates constrained by global atmospheric methane and ethane.

PubMed

Schwietzke, Stefan; Griffin, W Michael; Matthews, H Scott; Bruhwiler, Lori M P

2014-07-15

The amount of methane emissions released by the natural gas (NG) industry is a critical and uncertain value for various industry and policy decisions, such as for determining the climate implications of using NG over coal. Previous studies have estimated fugitive emissions rates (FER)--the fraction of produced NG (mainly methane and ethane) escaped to the atmosphere--between 1 and 9%. Most of these studies rely on few and outdated measurements, and some may represent only temporal/regional NG industry snapshots. This study estimates NG industry representative FER using global atmospheric methane and ethane measurements over three decades, and literature ranges of (i) tracer gas atmospheric lifetimes, (ii) non-NG source estimates, and (iii) fossil fuel fugitive gas hydrocarbon compositions. The modeling suggests an upper bound global average FER of 5% during 2006-2011, and a most likely FER of 2-4% since 2000, trending downward. These results do not account for highly uncertain natural hydrocarbon seepage, which could lower the FER. Further emissions reductions by the NG industry may be needed to ensure climate benefits over coal during the next few decades.

Constraining Methane Emissions from Natural Gas Production in Northeastern Pennsylvania Using Aircraft Observations and Mesoscale Modeling

NASA Astrophysics Data System (ADS)

Barkley, Z.; Davis, K.; Lauvaux, T.; Miles, N.; Richardson, S.; Martins, D. K.; Deng, A.; Cao, Y.; Sweeney, C.; Karion, A.; Smith, M. L.; Kort, E. A.; Schwietzke, S.

2015-12-01

Leaks in natural gas infrastructure release methane (CH4), a potent greenhouse gas, into the atmosphere. The estimated fugitive emission rate associated with the production phase varies greatly between studies, hindering our understanding of the natural gas energy efficiency. This study presents a new application of inverse methodology for estimating regional fugitive emission rates from natural gas production. Methane observations across the Marcellus region in northeastern Pennsylvania were obtained during a three week flight campaign in May 2015 performed by a team from the National Oceanic and Atmospheric Administration (NOAA) Global Monitoring Division and the University of Michigan. In addition to these data, CH4 observations were obtained from automobile campaigns during various periods from 2013-2015. An inventory of CH4 emissions was then created for various sources in Pennsylvania, including coalmines, enteric fermentation, industry, waste management, and unconventional and conventional wells. As a first-guess emission rate for natural gas activity, a leakage rate equal to 2% of the natural gas production was emitted at the locations of unconventional wells across PA. These emission rates were coupled to the Weather Research and Forecasting model with the chemistry module (WRF-Chem) and atmospheric CH4 concentration fields at 1km resolution were generated. Projected atmospheric enhancements from WRF-Chem were compared to observations, and the emission rate from unconventional wells was adjusted to minimize errors between observations and simulation. We show that the modeled CH4 plume structures match observed plumes downwind of unconventional wells, providing confidence in the methodology. In all cases, the fugitive emission rate was found to be lower than our first guess. In this initial emission configuration, each well has been assigned the same fugitive emission rate, which can potentially impair our ability to match the observed spatial variability. The current model also does not distinguish between natural gas emissions during the different stages of transportation. We finally discuss the use of additional tracers such as the 13CH4 isotopic ratio and ethane concentrations to separate the various contributors to the regional atmospheric CH4 enhancement.

Methamphetamine

MedlinePlus

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Narcotics

MedlinePlus

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Hydrocodone

MedlinePlus

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Fugitive emission rates assessment of PM2.5 and PM10 from open storage piles in China

NASA Astrophysics Data System (ADS)

Cao, Yiqi; Liu, Tao; He, Jiao

2018-03-01

An assessment of the fugitive emission rates of PM2.5 and PM10 from an open static coal and mine storage piles. The experiment was conducted at a large union steel enterprises in the East China region to effectively control the fugitive particulate emissions pollution on daily work and extreme weather conditions. Wind tunnel experiments conducted on the surface of static storage piles, and it generated specific fugitive emission rates (SERs) at ground level of between ca.10-1 and ca.102 (mg/m2·s) for PM2.5 and between ca.101 and ca.103 (mg/m2·s) for PM10 under the u*(wind velocity) between ca.3.0 (m/s) and 10.0 (m/s). Research results show that SERs of different materials differ a lot. Material particulate that has lower surface moisture content generate higher SER and coal material generate higher SER than mine material. For material storage piles with good water infiltrating properties, aspersion is a very effective measure for control fugitive particulate emission.

Heroin Photos

MedlinePlus

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Fugitive Methane Gas Emission Monitoring in oil and gas industry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Klein, Levente

Identifying fugitive methane leaks allow optimization of the extraction process, can extend gas extraction equipment lifetime, and eliminate hazardous work conditions. We demonstrate a wireless sensor network based on cost effective and robust chemi-resistive methane sensors combined with real time analytics to identify leaks from 2 scfh to 10000 scfh. The chemi-resistive sensors were validated for sensitivity better than 1 ppm of methane plume detection. The real time chemical sensor and wind data is integrated into an inversion models to identify the location and the magnitude of the methane leak. This integrated solution can be deployed in outdoor environment formore » long term monitoring of chemical plumes.« less

Monitoring fugitive methane and natural gas emissions, validation of measurement techniques.

NASA Astrophysics Data System (ADS)

Robinson, Rod; Innocenti, Fabrizio; Gardiner, Tom; Helmore, Jon; Finlayson, Andrew; Connor, Andy

2017-04-01

The detection and quantification of fugitive and diffuse methane emissions has become an increasing priority in recent years. As the requirements for routine measurement to support industry initiatives increase there is a growing requirement to assess and validate the performance of fugitive emission measurement technologies. For reported emissions traceability and comparability of measurements is important. This talk will present recent work addressing these needs. Differential Absorption Lidar (DIAL) is a laser based remote sensing technology, able to map the concentration of gases in the atmosphere and determine emission fluxes for fugitive emissions. A description of the technique and its application for determining fugitive emissions of methane from oil and gas operations and waste management sites will be given. As DIAL has gained acceptance as a powerful tool for the measurement and quantification of fugitive emissions, and given the rich data it produces, it is being increasingly used to assess and validate other measurement approaches. In addition, to support the validation of technologies, we have developed a portable controlled release facility able to simulate the emissions from area sources. This has been used to assess and validate techniques which are used to monitor emissions. The development and capabilities of the controlled release facility will be described. This talk will report on recent studies using DIAL and the controlled release facility to validate fugitive emission measurement techniques. This includes side by side comparisons of two DIAL systems, the application of both the DIAL technique and the controlled release facility in a major study carried out in 2015 by South Coast Air Quality Management District (SCAQMD) in which a number of optical techniques were assessed and the development of a prototype method validation approach for techniques used to measure methane emissions from shale gas sites. In conclusion the talk will provide an update on the current status in the development of a European Standard for the measurement of fugitive emissions of VOCs and the use of validation data in the standardisation process and discuss the application of this to methane measurement.

Methamphetamine Lab Incidents, 2004-2014

MedlinePlus

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The winter gap effect in methane leak detection and repair with optical gas imaging cameras

NASA Astrophysics Data System (ADS)

Fox, T. A.; Barchyn, T.; Hugenholtz, C.

2017-12-01

Implementing effective leak detection and repair (LDAR) programs is essential for mitigating fugitive methane emissions from oil and gas operations. In Canada, newly proposed regulations will require that high-risk facilities be surveyed 3 times/yr for fugitive leaks. Like the United States, Canada promotes the use of Optical Gas Imaging cameras (OGIs) for detecting natural gas leaks during LDAR surveys. However, recent research suggests OGIs may perform poorly under adverse environmental conditions, especially in low temperatures. For regions like Canada that experience cold winters, OGIs may not be reliably used for months at a time, meaning that leaks may accumulate and emit for longer periods before being repaired. While considerable oil and gas activity occurs in high-latitude regions with cold winters, no research has explored how extended cold periods impact OGI-focused LDAR programs. To improve this understanding, we present a simple model exploring relationships among winter gap length, fugitive methane emissions, and investment input for LDAR programs employing OGI instruments in gas producing regions of different latitudes. Preliminary results suggest that longer gaps between LDAR surveys caused by cold temperatures result in either 1) higher total emissions for the year, or 2) greater time and equipment investment in LDAR programs to achieve emissions mitigation equivalent to LDAR programs operating under ideal conditions. When weather constraints are removed and LDAR surveys are evenly spaced throughout the year, emissions mitigation is optimized. However, as the winter gap duration and the size of the implicated area increases, fugitive leaks last longer. Furthermore, a spillover effect is observed as LDAR crews become overwhelmed with the high volume of work required as temperatures increase in the spring. Our model adds weight to the argument that LDAR programs should be tailored to regional needs, and that regulators should be more cognisant of sensor-specific limitations as they develop LDAR protocols.

Effects of Adding Corn Dried Distiller Grains with Solubles (DDGS) to the Dairy Cow Diet and Effects of Bedding in Dairy Cow Slurry on Fugitive Methane Emissions.

PubMed

Massé, Daniel I; Jarret, Guillaume; Benchaar, Chaouki; Hassanat, Fadi

2014-12-09

The specific objectives of this experiment were to investigate the effects of adding 10% or 30% corn dried distillers grains with solubles (DDGS) to the dairy cow diet and the effects of bedding type (wood shavings, straw or peat moss) in dairy slurry on fugitive CH₄ emissions. The addition of DDGS10 to the dairy cow diet significantly increased (29%) the daily amount of fat excreted in slurry compared to the control diet. The inclusion of DDGS30 in the diet increased the daily amounts of excreted DM, volatile solids (VS), fat, neutral detergent fiber (NDF), acid detergent fiber (ADF) and hemicellulose by 18%, 18%, 70%, 30%, 15% and 53%, respectively, compared to the control diet. During the storage experiment, daily fugitive CH₄ emissions showed a significant increase of 15% (p < 0.05) for the slurry resulting from the corn DDGS30 diet. The addition of wood shavings and straw did not have a significant effect on daily fugitive CH₄ emissions relative to the control diet, whereas the addition of peat moss caused a significant increase of 27% (p < 0.05) in fugitive CH₄ emissions.

Health assessment for Shaw Avenue Dump, Charles City, Iowa, Region 7. CERCLIS No. IAD980630560. Preliminary report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1988-12-07

The Shaw Avenue Dump Site is listed on the National Priorities List. The 8-acre city dump site, consisting of three waste-disposal areas, is located in southeast Charles City approximately 500 feet east of the Cedar River. Sludge from the Charles City waste water treatment plant, which received liquid waste discharge from Salisbury, was placed from 1949 to 1969 in the northern waste cells and in the undefined area on the southern portion of the site. Arsenic is the contaminant of concern at the Shaw Avenue Dump Site. The site is considered to be of public health concern because of themore » potential risk to human health caused by possible exposure to hazardous substances via ingestion of ground water, soil, and surface water; inhalation of fugitive dust; and dermal contact with soil, surface water, and ground water.« less

Characteristics of coal mine ventilation air flows.

PubMed

Su, Shi; Chen, Hongwei; Teakle, Philip; Xue, Sheng

2008-01-01

Coal mine methane (CMM) is not only a greenhouse gas but also a wasted energy resource if not utilised. Underground coal mining is by far the most important source of fugitive methane emissions, and approximately 70% of all coal mining related methane is emitted to the atmosphere through mine ventilation air. Therefore, research and development on mine methane mitigation and utilisation now focuses on methane emitted from underground coal mines, in particular ventilation air methane (VAM) capture and utilisation. To date, most work has focused on the oxidation of very low concentration methane. These processes may be classified based on their combustion kinetic mechanisms into thermal oxidation and catalytic oxidation. VAM mitigation/utilisation technologies are generally divided into two basic categories: ancillary uses and principal uses. However, it is possible that the characteristics of ventilation air flows, for example the variations in methane concentration and the presence of certain compounds, which have not been reported so far, could make some potential VAM mitigation and utilisation technologies unfeasible if they cannot cope with the characteristics of mine site ventilation air flows. Therefore, it is important to understand the characteristics of mine ventilation air flows. Moreover, dust, hydrogen sulphide, sulphur dioxide, and other possible compounds emitted through mine ventilation air into the atmosphere are also pollutants. Therefore, this paper presents mine-site experimental results on the characteristics of mine ventilation air flows, including methane concentration and its variations, dust loadings, particle size, mineral matter of the dust, and other compounds in the ventilation air flows. The paper also discusses possible correlations between ventilation air characteristics and underground mining activities.

Source influence on emission pathways and ambient PM2.5 pollution over India (2015-2050)

NASA Astrophysics Data System (ADS)

Venkataraman, Chandra; Brauer, Michael; Tibrewal, Kushal; Sadavarte, Pankaj; Ma, Qiao; Cohen, Aaron; Chaliyakunnel, Sreelekha; Frostad, Joseph; Klimont, Zbigniew; Martin, Randall V.; Millet, Dylan B.; Philip, Sajeev; Walker, Katherine; Wang, Shuxiao

2018-06-01

India is currently experiencing degraded air quality, and future economic development will lead to challenges for air quality management. Scenarios of sectoral emissions of fine particulate matter and its precursors were developed and evaluated for 2015-2050, under specific pathways of diffusion of cleaner and more energy-efficient technologies. The impacts of individual source sectors on PM2.5 concentrations were assessed through systematic simulations of spatially and temporally resolved particulate matter concentrations, using the GEOS-Chem model, followed by population-weighted aggregation to national and state levels. We find that PM2.5 pollution is a pan-India problem, with a regional character, and is not limited to urban areas or megacities. Under present-day emissions, levels in most states exceeded the national PM2.5 annual standard (40 µg m-3). Sources related to human activities were responsible for the largest proportion of the present-day population exposure to PM2.5 in India. About 60 % of India's mean population-weighted PM2.5 concentrations come from anthropogenic source sectors, while the remainder are from other sources, windblown dust and extra-regional sources. Leading contributors are residential biomass combustion, power plant and industrial coal combustion and anthropogenic dust (including coal fly ash, fugitive road dust and waste burning). Transportation, brick production and distributed diesel were other contributors to PM2.5. Future evolution of emissions under regulations set at current levels and promulgated levels caused further deterioration of air quality in 2030 and 2050. Under an ambitious prospective policy scenario, promoting very large shifts away from traditional biomass technologies and coal-based electricity generation, significant reductions in PM2.5 levels are achievable in 2030 and 2050. Effective mitigation of future air pollution in India requires adoption of aggressive prospective regulation, currently not formulated, for a three-pronged switch away from (i) biomass-fuelled traditional technologies, (ii) industrial coal-burning and (iii) open burning of agricultural residue. Future air pollution is dominated by industrial process emissions, reflecting larger expansion in industrial, rather than residential energy demand. However, even under the most active reductions envisioned, the 2050 mean exposure, excluding any impact from windblown mineral dust, is estimated to be nearly 3 times higher than the WHO Air Quality Guideline.

75 FR 29338 - Energy Efficiency of Natural Gas Infrastructure and Operations Conference; Final Notice of Public...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-25

... recovery projects and issues associated with fugitive methane. Bruce Hedman, ICF International, on behalf... associated with fugitive methane. Richard D. Murphy, S.V.P. Energy Solutions Services, National Grid, on...

Center for Corporate Climate Leadership: Direct Fugitive Emissions from Refrigeration, Air Conditioning, Fire Suppression, and Industrial Gases

EPA Pesticide Factsheets

This guidance document focuses on several fugitive emissions sources that are common for organizations in many sectors: refrigeration and air conditioningsystems, fire suppression systems, and the purchase and release of industrial gases.

Investigation of fugitive emissions from petrochemical transport barges using optical remote sensing

EPA Science Inventory

Recent airborne remote sensing survey data acquired with passive gas imaging equipment (PGIE), in this case infrared cameras, have shown potentially significant fugitive volatile organic carbon (VOC) emissions from petrochemical transport barges. The experiment found remote sens...

SPECTRAL MONITORING OF FUGITIVE CONTAMINANTS IN THE ENVIRONMENT

EPA Science Inventory

The accidental or intentional release of hazardous chemical substances into the environment is an inevitable consequence of anthropogenic activity. The detection, monitoring and remediation of fugitive contaminants is a major risk factor for human and ecological health and i...

Assessing Potential Air Pollutant Emissions from Agricultural Feedstock Production using MOVES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eberle, Annika; Warner, Ethan; Zhang, Yi Min

Biomass feedstock production is expected to grow as demand for biofuels and bioenergy increases. The change in air pollutant emissions that may result from large-scale biomass supply has implications for local air quality and human health. We developed spatially explicit emissions inventories for corn grain and six cellulosic feedstocks through the extension of the National Renewable Energy Laboratory's Feedstock Production Emissions to Air Model (FPEAM). These inventories include emissions of seven pollutants (nitrogen oxides, ammonia, volatile organic compounds, particulate matter, sulfur oxides, and carbon monoxide) generated from biomass establishment, maintenance, harvest, transportation, and biofuel preprocessing activities. By integrating the EPA'smore » MOtor Vehicle Emissions Simulator (MOVES) into FPEAM, we created a scalable framework to execute county-level runs of the MOVES-Onroad model for representative counties (i.e., those counties with the largest amount of cellulosic feedstock production in each state) on a national scale. We used these results to estimate emissions from the on-road transportation of biomass and combined them with county-level runs of the MOVES-Nonroad model to estimate emissions from agricultural equipment. We also incorporated documented emission factors to estimate emissions from chemical application and the operation of drying equipment for feedstock processing, and used methods developed by the EPA and the California Air Resources Board to estimate fugitive dust emissions. The model developed here could be applied to custom equipment budgets and is extensible to accommodate additional feedstocks and pollutants. Future work will also extend this model to analyze spatial boundaries beyond the county-scale (e.g., regional or sub-county levels).« less

USER'S GUIDE: EMISSION CONTROL TECHNOLOGIES AND EMISSION FACTORS FOR UNPAVED ROAD FUGITIVE EMISSIONS

EPA Science Inventory

This document assists control agency personnel in evaluating unpaved road fugitive emissions control plans and helps industry personnel develop effective control strategies for unpaved roads. he brochure describes control techniques for reducing unpaved road emissions and methods...

Fugitive methane assessment with mobile and fence line sensors

EPA Science Inventory

There is no published abstract for this short panel talk. The panel presentation titled “Fugitive methane assessment with mobile and fence line sensors” provides a basic introduction to the topic of next generation sensor technologies for identifying and fixing emiss...

EVALUATION OF FUGITIVE EMISSIONS USING GROUND-BASED OPTICAL REMOTE SENSING TECHNOLOGY

EPA Science Inventory

EPA has developed and evaluated a method for characterizing fugitive emissions from large area sources. The method, known as radial plume mapping (RPM) uses multiple-beam, scanning, optical remote sensing (ORS) instrumentation such as open-path Fourier transform infrared spectro...

MEASUREMENT OF FUGITIVE EMISSIONS AT A BIOREACTOR LANDFILL

EPA Science Inventory

This report focuses on three field campaigns performed in 2002 and 2003 to measure fugitive emissions at a bioreactor landfill in Louisville, KY, using an open-path Fourier transform infrared spectrometer. The study uses optical remote sensing-radial plume mapping. The horizontal...

Effects of Adding Corn Dried Distiller Grains with Solubles (DDGS) to the Dairy Cow Diet and Effects of Bedding in Dairy Cow Slurry on Fugitive Methane Emissions

PubMed Central

Massé, Daniel I.; Jarret, Guillaume; Benchaar, Chaouki; Hassanat, Fadi

2014-01-01

Simple Summary The objectives of this experiment were to investigate the effects of adding corn DDGS to the dairy cow diet as well as the bedding types (wood shavings, straw or peat moss) on manure fugitive CH4 emissions. The incorporation of DDGS in the diet has increased manure methane emission by 15% and the use of peat moss as bedding has increased manure methane emission by 27%. Abstract The specific objectives of this experiment were to investigate the effects of adding 10% or 30% corn dried distillers grains with solubles (DDGS) to the dairy cow diet and the effects of bedding type (wood shavings, straw or peat moss) in dairy slurry on fugitive CH4 emissions. The addition of DDGS10 to the dairy cow diet significantly increased (29%) the daily amount of fat excreted in slurry compared to the control diet. The inclusion of DDGS30 in the diet increased the daily amounts of excreted DM, volatile solids (VS), fat, neutral detergent fiber (NDF), acid detergent fiber (ADF) and hemicellulose by 18%, 18%, 70%, 30%, 15% and 53%, respectively, compared to the control diet. During the storage experiment, daily fugitive CH4 emissions showed a significant increase of 15% (p < 0.05) for the slurry resulting from the corn DDGS30 diet. The addition of wood shavings and straw did not have a significant effect on daily fugitive CH4 emissions relative to the control diet, whereas the addition of peat moss caused a significant increase of 27% (p < 0.05) in fugitive CH4 emissions. PMID:26479012

MEASUREMENT OF FUGITIVE EMISSIONS AT A LANDFILL PRACTICING LEACHATE RECIRCULATION AND AIR INJECTION

EPA Science Inventory

Recently research has begun on operating bioreactor landfills. The bioreactor process involves the injection of liquid into the waste mass to accelerate waste degradation. Arcadis and EPA conducted a fugitive emissions characterization study at the Three Rivers Solid Waste Techno...

FUGITIVE EMISSION SOURCES AND BATCH OPERATIONS IN SYNTHETIC ORGANIC CHEMICAL PRODUCTION

EPA Science Inventory

This survey report was developed for the EPA for use in assessing the potential magnitude of fugitive volatile organic compound (VOC) emissions from agitator seals, cooling towers and batch operations in the production of 378 designated chemicals. The information presented in thi...

Next Generation Emission Measurements for Fugitive, Area Source, and Fence Line Applications?

EPA Science Inventory

Next generation emissions measurements (NGEM) is an EPA term for the rapidly advancing field of air pollutant sensor technologies, data integration concepts, and associated geospatial modeling strategies for source emissions measurements. Ranging from low coat sensors to satelli...

Next Generation Air Measurements for Fugitive, Area Source, and Fence Line Applications

EPA Science Inventory

Next generation air measurements (NGAM) is an EPA term for the advancing field of air pollutant sensor technologies, data integration concepts, and geospatial modeling strategies. Ranging from personal sensors to satellite remote sensing, NGAM systems may provide revolutionary n...

Dust emissions created by low-level rotary-winged aircraft flight over desert surfaces

NASA Astrophysics Data System (ADS)

Gillies, J. A.; Etyemezian, V.; Kuhns, H.; McAlpine, J. D.; King, J.; Uppapalli, S.; Nikolich, G.; Engelbrecht, J.

2010-03-01

There is a dearth of information on dust emissions from sources that are unique to U.S. Department of Defense testing and training activities. Dust emissions of PM 10 and PM 2.5 from low-level rotary-winged aircraft travelling (rotor-blade ≈7 m above ground level) over two types of desert surfaces (i.e., relatively undisturbed desert pavement and disturbed desert soil surface) were characterized at the Yuma Proving Ground (Yuma, AZ) in May 2007. Fugitive emissions are created by the shear stress of the outflow of high speed air created by the rotor-blade. The strength of the emissions was observed to scale primarily as a function of forward travel speed of the aircraft. Speed affects dust emissions in two ways: 1) as speed increases, peak shear stress at the soil surface was observed to decline proportionally, and 2) as the helicopter's forward speed increases its residence time over any location on the surface diminishes, so the time the downward rotor-generated flow is acting upon that surface must also decrease. The state of the surface over which the travel occurs also affects the scale of the emissions. The disturbed desert test surface produced approximately an order of magnitude greater emission than the undisturbed surface. Based on the measured emission rates for the test aircraft and the established scaling relationships, a rotary-winged aircraft similar to the test aircraft traveling 30 km h -1 over the disturbed surface would need to travel 4 km to produce emissions equivalent to one kilometer of travel by a light wheeled military vehicle also traveling at 30 km h -1 on an unpaved road. As rotary-winged aircraft activity is substantially less than that of off-road vehicle military testing and training activities it is likely that this source is small compared to emissions created by ground-based vehicle movements.

Mobile monitoring of fugitive methane emissions from natural gas consumer industries

EPA Science Inventory

Natural gas is used as a feedstock for major industrial processes, such as ammonia and fertilizer production. However, fugitive methane emissions from many major end-use sectors of the natural gas supply chain have not yet been well quantified. This presentation introduces new m...

The Mobile Monitoring of fugitive methane emissions from natural gas consumer industries

EPA Science Inventory

Natural gas is used as a feedstock for major industrial processes, such as ammonia and fertilizer production. However, fugitive methane emissions from many major end-use sectors of the natural gas supply chain have not been quantified yet. This presentation introduces new tools ...

OPEN PATH TUNABLE DIODE LASER ABSORPTION SPECTROSCOPY FOR ACQUISITION OF FUGITIVE EMISSION FLUX DATA

EPA Science Inventory

Air pollutant emission from unconfined sources is an increasingly important environmental issue. The U.S. EPA has developed a gorund-based optical remote sensing method that enables direct measurement of fugitive emission flux from large area sources. Open-path Fourier transfor...

40 CFR 60.441 - Definitions and symbols.

Code of Federal Regulations, 2011 CFR

2011-07-01

.... Fugitive volatile organic compounds means any volatile organic compounds which are emitted from the coating... capture fugitive volatile organic compounds. Oven means a chamber which uses heat or irradiation to bake... or label product. Solvent applied in the coating means all organic solvent contained in the adhesive...

40 CFR 60.441 - Definitions and symbols.

Code of Federal Regulations, 2013 CFR

2013-07-01

.... Fugitive volatile organic compounds means any volatile organic compounds which are emitted from the coating... capture fugitive volatile organic compounds. Oven means a chamber which uses heat or irradiation to bake... or label product. Solvent applied in the coating means all organic solvent contained in the adhesive...

40 CFR 60.441 - Definitions and symbols.

Code of Federal Regulations, 2012 CFR

2012-07-01

.... Fugitive volatile organic compounds means any volatile organic compounds which are emitted from the coating... capture fugitive volatile organic compounds. Oven means a chamber which uses heat or irradiation to bake... or label product. Solvent applied in the coating means all organic solvent contained in the adhesive...

40 CFR 60.441 - Definitions and symbols.

Code of Federal Regulations, 2014 CFR

2014-07-01

... = the weight fraction of organics applied of each coating (i) applied during a calendar month as.... Fugitive volatile organic compounds means any volatile organic compounds which are emitted from the coating... capture fugitive volatile organic compounds. Oven means a chamber which uses heat or irradiation to bake...

40 CFR 63.544 - Standards for process fugitive sources.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) Smelting furnace and dryer charging hoppers, chutes, and skip hoists; (2) Smelting furnace lead taps, and molds during tapping; (3) Smelting furnace slag taps, and molds during tapping; (4) Refining kettles; (5) Dryer transition pieces; and (6) Agglomerating furnace product taps. (b) Process fugitive emission...

HIGHLIGHTS FROM TECHNICAL MANUAL ON HOOD SYSTEM CAPTURE OF PROCESS FUGITIVE PARTICULATE EMISSIONS

EPA Science Inventory

The paper discusses a technical manual whose emphasis is on the design and evaluation of actual hood systems used to control various fugitive particulate emission sources. Engineering analyses of the most important hood types are presented to provide a conceptual understanding of...

Ozone and its potential control strategy for Chon Buri city, Thailand.

PubMed

Prabamroong, Thayukorn; Manomaiphiboon, Kasemsan; Limpaseni, Wongpun; Sukhapan, Jariya; Bonnet, Sebastien

2012-12-01

This work studies O3 pollution for Chon Buri city in the eastern region of Thailand, where O3 has become an increased and serious concern in the last decade. It includes emission estimation and photochemical box modeling in support of investigating the underlying nature of O3 formation over the city and the roles of precursors emitted from sources. The year 2006 was considered and two single-day episodes (January 29 and February 14) were chosen for simulations. It was found that, in the city, the industrial sector is the largest emissions contributor for every O3 precursor (i.e., NO(x), non-methane volatile organic compounds or NMVOC, and CO), followed by on-road mobile group. Fugitive NMVOC is relatively large, emitted mainly from oil refineries and tank farms. Simulated results acceptably agree with observations for daily maximum O3 level in both episodes and evidently indicate the VOC-sensitive regime for O3 formation. This regime is also substantiated by morning NMVOC/NO(x) ratios observed in the city. The corresponding O3 isopleth diagrams suggest NMVOC control alone to lower elevated O3. In seeking a potential O3 control strategy for the city, a combination of brute-force sensitivity tests, an experimental design, statistical modeling, and cost optimization was employed. A number of emission subgroups were found to significantly contribute to O3 formation, based on the February 14 episode, for example, oil refinery (fugitive), tank farm (fugitive), passenger car (gasoline), and motorcycle (gasoline). But the cost-effective strategy suggests control only on the first two subgroups to meet the standard. The cost of implementing the strategy was estimated and found to be small (only 0.2%) compared to the gross provincial product generated by the entire province where the city is located within. These findings could be useful as a needed guideline to support O3 management for the city. Elevated O3 in the urban and industrial city of Chon Buri needs better understanding of the problem and technical guidelines for its management. With a city-specific emission inventory and air quality modeling, O3 formation was found to be VOC sensitive, and a cost-effective control strategy developed highlights fugitive emissions from the industrial sector to be controlled.

Quantifying the Movement and Dissolution of Fugitive Methane in Shallow Aquifers: Visualization Experiments

NASA Astrophysics Data System (ADS)

Van De Ven, C. J. C.; Mumford, K. G.

2016-12-01

The environmental impact and potential human health implications, specifically from the contamination of groundwater sources, has sparked controversy around shale gas extraction in North America. It is clear that understanding the effects of hydraulic fracturing on shallow fresh water aquifers is of great importance, including the threat of stray gas (also referred to as fugitive methane) on groundwater quality. Faulty wells provide a preferential pathway for free gas phase (mostly methane) to migrate from deeper gas-bearing formations of natural gas to shallow aquifers, followed by its dissolution into the surrounding groundwater. An increased understanding of the fate of fugitive methane in shallow aquifers is required to assess the potential risks associated with current and future operations, as well as to better link gas migration, dissolution and the deterioration of groundwater quality. In this study, a series of laboratory experiments were performed using carbon dioxide (CO2) gas as a surrogate for methane to improve our understanding of gas dissolution in groundwater systems. Using CO2, a novel laboratory technique was developed that allows the measurement of dissolved CO2 concentrations using image analysis alongside visualization of free gas mobilization. The technique is based on the acidification of water during CO2 dissolution, which causes a colour change in an indicator dye. The colour change is recorded using a visual light transmission technique, in which digital images are used to track dissolved concentrations at high spatial (1 mm) and temporal (5 s) resolutions in a two-dimensional (25 × 25 × 1 cm3) flow cell. The experiments were completed in both homogeneous sand packs and sand packs containing layered heterogeneities to investigate the dissolution of both gas fingers and gas pools. The results demonstrate the potential of this novel technique for investigating gas dissolution, and showed significant tailing of dissolved CO2 and persistence of other gas phase components. This technique will aid in the development of conceptual models to link fugitive methane to groundwater contamination and provide detailed data required for the validation of numerical models that account for gas-water mass transfer; both of which are required for the development of sound monitoring techniques.

40 CFR 63.544 - Standards for process fugitive sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... National Emission Standards for Hazardous Air Pollutants from Secondary Lead Smelting § 63.544 Standards for process fugitive sources. (a) Each owner or operator of a secondary lead smelter shall control the...) Smelting furnace and dryer charging hoppers, chutes, and skip hoists; (2) Smelting furnace lead taps, and...

Queer Histories: Exploring Fugitive Forms of Social Knowledge.

ERIC Educational Resources Information Center

Hill, Bob, Ed.

This document contains eight papers from a conference on fugitive forms of social knowledge that was sponsored by the Adult Education Research Conference (AERC) Lesbian, Gay, Bisexual, Transgender, Queer, and Allies Caucus. The welcome address, "Working Memory at AERC: A Queer Welcome...and a Retrospective" (Bob Hill), explores the…

A Walk on the Underground Railroad.

ERIC Educational Resources Information Center

Cohen, Anthony

2001-01-01

Describes one historian's search for information on the Underground Railroad, retracing on foot one of the routes formerly traveled by fugitives, seeking historical societies and libraries in each town, and interviewing descendants of slaves. He also had himself boxed up and smuggled onto a train to simulate the situation of one fugitive. A…

Performance Evaluations and Quality Validation System for Optical Gas Imaging Cameras That Visualize Fugitive Hydrocarbon Gas Emissions

EPA Science Inventory

Optical gas imaging (OGI) cameras have the unique ability to exploit the electromagnetic properties of fugitive chemical vapors to make invisible gases visible. This ability is extremely useful for industrial facilities trying to mitigate product losses from escaping gas and fac...

76 FR 23489 - Prevention of Significant Deterioration (PSD) and Nonattainment New Source Review (NSR...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-27

...): Reconsideration of Inclusion of Fugitive Emissions; Interim Rule; Stay and Revisions AGENCY: Environmental... (PSD) and Nonattainment New Source Review (NSR): Reconsideration of Inclusion of Fugitive Emissions... inclusion in the public docket. Information so marked will not be disclosed except in accordance with...

The Yucca Mountain Project prototype air-coring test, U12g tunnel, Nevada test site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ray, J.M.; Newsom, J.C.

1994-12-01

The Prototype Air-Coring Test was conducted at the Nevada Test Site (NTS) G-Tunnel facility to evaluate standard coring techniques, modified slightly for air circulation, for use in testing at a prospective nuclear waste repository at Yucca Mountain, Nevada. Air-coring technology allows sampling of subsurface lithology with minimal perturbation to ambient characteristic such as that required for exploratory holes near aquifers, environmental applications, and site characterization work. Two horizontal holes were cored, one 50 ft long and the other 150 ft long, in densely welded fractured tuff to simulate the difficult drilling conditions anticipated at Yucca Mountain. Drilling data from sevenmore » holes on three other prototype tests in nonwelded tuff were also collected for comparison. The test was used to establish preliminary standards of performance for drilling and dust collection equipment and to assess procedural efficiencies. The Longyear-38 drill achieved 97% recovery for HQ-size core (-2.5 in.), and the Atlas Copco dust collector (DCT-90) captured 1500 lb of fugitive dust in a mine environment with only minor modifications. Average hole production rates were 6-8 ft per 6-h shift in welded tuff and almost 20 ft per shift on deeper holes in nonwelded tuff. Lexan liners were successfully used to encapsulate core samples during the coring process and protect core properties effectively. The Prototype Air-Coring Test demonstrated that horizontal air coring in fractured welded tuff (to at least 150 ft) can be safely accomplished by proper selection, integration, and minor modification of standard drilling equipment, using appropriate procedures and engineering controls. The test also indicated that rig logistics, equipment, and methods need improvement before attempting a large-scale dry drilling program at Yucca Mountain.« less

Philadelphia gas works medium-Btu coal gasification project: environmental assessment. [GKT supplied by Krupp-Koppers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-12-01

The coal gasification plant will occupy a 43-acre site, known as the Riverside Site, located along the Delaware River next to Port Richmond between the Betsy Ross and Benjamin Franklin Bridges. The cleared site was previously used for industrial purposes and has a G-2 industrial zoning. Adverse impacts during the construction phase of the project are not expected to be significantly different than those occurring during any major industrial construction project. During operation of the coal gasification facility, specific mitigative measures have been designed into the facility to avoid adverse environmental impacts wherever possible. In addition to these extensive engineeringmore » safeguards, elaborate monitoring and control instrumentation shall be used. The GKT entrained bed, oxygen-blown gasification process provided by Krupp/Koppers was selected because it is a commercially proven system and because of its positive environmental characteristics such as its ability to gasify many coal types and the fact that it does not produce tars, phenols, or ammonia. During gasification of the coal, pollutants such as heavy metals in the coal are concentrated into the slag and ash. None of these pollutants are found in the product gas. The facility will produce 250 tpd of non-hazardous slag and fly ash. The combined slag and fly ash will occupy 347 cubic yards per day of landfill volume. Available haulers and landfills have been identified.A sophisticated health and safety program will include appropriate monitoring instruments for CO, H/sub 2/, H/sub 2/S, polynuclear aromatic hydrocarbons, organic compounds, and coal dust. Air emissions from operation of the coal gasification plant are not considered significant. Dust control systems have been designed into the facility to minimize fugitive dust emissions.« less

40 CFR 63.7351 - Who implements and enforces this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and...-product coke oven battery with vertical flues, fugitive pushing emissions in § 63.7292(a) for a by-product coke oven battery with horizontal flues, fugitive pushing emissions in § 63.7293 for a non-recovery...

40 CFR 63.7351 - Who implements and enforces this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and...-product coke oven battery with vertical flues, fugitive pushing emissions in § 63.7292(a) for a by-product coke oven battery with horizontal flues, fugitive pushing emissions in § 63.7293 for a non-recovery...

40 CFR 63.7351 - Who implements and enforces this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and...-product coke oven battery with vertical flues, fugitive pushing emissions in § 63.7292(a) for a by-product coke oven battery with horizontal flues, fugitive pushing emissions in § 63.7293 for a non-recovery...

40 CFR 63.7351 - Who implements and enforces this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and...-product coke oven battery with vertical flues, fugitive pushing emissions in § 63.7292(a) for a by-product coke oven battery with horizontal flues, fugitive pushing emissions in § 63.7293 for a non-recovery...

Bayesian Estimation of Fugitive Methane Point Source Emission Rates from a SingleDownwind High-Frequency Gas Sensor

EPA Science Inventory

Bayesian Estimation of Fugitive Methane Point Source Emission Rates from a Single Downwind High-Frequency Gas Sensor With the tremendous advances in onshore oil and gas exploration and production (E&P) capability comes the realization that new tools are needed to support env...

CHARACTERIZATION OF THE FUGITIVE MERCURY EMISSIONS AT A CHLOR-ALKALI PLANT. OVERALL STUDY DESIGN

EPA Science Inventory

The paper discusses a detailed emissions measurement campaign that was conducted over a 9-day period within a mercury (Hg) cell chlor-alkali plant in the southeastern United States (U.S.). The principal focus of this study was to measure fugitive (non-ducted) airborne Hg emission...

FUGITIVE EMISSION REDUCTIONS DUE TO THE USE OF ENCLOSED DOCTOR BLADE SYSTEMS IN THE FLEXOGRAPHIC AND ROTOGRAVURE PRINTING INDUSTRIES

EPA Science Inventory

The report gives results of a quantification of the level of fugitive emission reductions resulting from the use of enclosed doctor blade (EDB) systems in place of traditional ink feed systems at flexographic and rotogravure printing operations. An EDB system is an innovative ink...

The Fugitive Literature of Acid Rain: Making Use of Nonconventional Information Sources in a Vertical File.

ERIC Educational Resources Information Center

Lovenburg, Susan L.; Stoss, Frederick W.

1988-01-01

Discusses the advantages of vertical file collections for nonconventional literature, and describes the classification scheme used for fugitive literature by the Acid Rain Information Clearinghouse at the Center for Environmental Information. An annotated list of organizations and examples of titles they offer is provided. (8 notes with…

40 CFR 60.55b - Standards for municipal waste combustor fugitive ash emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Performance for Large Municipal Waste Combustors for Which Construction is Commenced After September 20, 1994... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standards for municipal waste combustor... municipal waste combustor fugitive ash emissions. (a) On and after the date on which the initial performance...

40 CFR 60.55b - Standards for municipal waste combustor fugitive ash emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Performance for Large Municipal Waste Combustors for Which Construction is Commenced After September 20, 1994... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for municipal waste combustor... municipal waste combustor fugitive ash emissions. (a) On and after the date on which the initial performance...

77 FR 19153 - Nonpayment of Benefits to Fugitive Felons and Probation or Parole Violators

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-30

... SOCIAL SECURITY ADMINISTRATION 20 CFR Parts 404 and 416 [Docket No. SSA 2006-0173] RIN 0960-AG12 Nonpayment of Benefits to Fugitive Felons and Probation or Parole Violators AGENCY: Social Security Administration. ACTION: Proposed rules; withdrawal. SUMMARY: We are withdrawing the proposed rules we published...

Fugitive Emissions from Conventional and Hydraulically Fractured Natural Gas Developments in Western Canada

NASA Astrophysics Data System (ADS)

Atherton, E. E.; Risk, D. A.; Lavoie, M.; Marshall, A. D.; Baillie, J.; Williams, J. P.

2015-12-01

Presently, fugitive emissions released into the atmosphere during the completion and production of oil and gas wells are poorly regulated within Canada. Some possible upstream sources of these emissions include flowback during well completions, liquid unloading, chemical injection pumps, and equipment leaks. The environmental benefits of combusting natural gas compared to oil or coal are negated if methane leakages surpass 3.2% of total production, so it is important to have a thorough understanding of these fugitive emissions. This study compares atmospheric leakage pathways of methane and other fugitive gases in both conventional and unconventional oil and gas developments in Western Canada to help fill this knowledge gap. Over 5000 kilometers of mobile survey campaigns were completed in carefully selected developments in the Montney shale play in British Columbia, and in conventional oil fields in Alberta. These sites are developed by more than 25 different operators. High precision laser and UV fluorescence gas analyzers were used to gather geolocated trace gas concentrations at a frequency of 1 Hz while driving. These data were processed with an adaptive technique to compensate for fluctuations in background concentrations for each gas. The residual excess concentrations were compositionally fingerprinted on the basis of the expected gas ratios for potential emission sites in order to definitively attribute anomalies to infrastructural leak sources. Preliminary results from the mobile surveys of both conventional and unconventional oil and gas sites are presented here. Pathways of methane and other fugitive gases are mapped to their respective sources, identifying common causes of emissions leaks across the oil and gas industry. This is the first bottom-up study of fugitive emissions from Canadian energy developments to produce publicly available data. These findings are significant to operators interested in lowering emissions for economic benefit, as well as public and governmental groups looking to become more informed on the impacts of oil and gas developments in Canada.

Concentrations and source apportionment of PM10 and associated elemental and ionic species in a lignite-burning power generation area of southern Greece.

PubMed

Argyropoulos, G; Grigoratos, Th; Voutsinas, M; Samara, C

2013-10-01

Ambient concentrations of PM10 and associated elemental and ionic species were measured over the cold and the warm months of 2010 at an urban and two rural sites located in the lignite-fired power generation area of Megalopolis in Peloponnese, southern Greece. The PM10 concentrations at the urban site (44.2 ± 33.6 μg m(-3)) were significantly higher than those at the rural sites (23.7 ± 20.4 and 22.7 ± 26.9 μg m(-3)). Source apportionment of PM10 and associated components was accomplished by an advanced computational procedure, the robotic chemical mass balance model (RCMB), using chemical profiles for a variety of local fugitive dust sources (power plant fly ash, flue gas desulfurization wet ash, feeding lignite, infertile material from the opencast mines, paved and unpaved road dusts, soil), which were resuspended and sampled through a PM10 inlet onto filters and then chemically analyzed, as well as of other common sources such as vehicular traffic, residential oil combustion, biomass burning, uncontrolled waste burning, marine aerosol, and secondary aerosol formation. Geological dusts (road/soil dust) were found to be major PM10 contributors in both the cold and warm periods of the year, with average annual contribution of 32.6 % at the urban site vs. 22.0 and 29.0 % at the rural sites. Secondary aerosol also appeared to be a significant source, contributing 22.1 % at the urban site in comparison to 30.6 and 28.7 % at the rural sites. At all sites, the contribution of biomass burning was most significant in winter (28.2 % at the urban site vs. 14.6 and 24.6 % at the rural sites), whereas vehicular exhaust contribution appeared to be important mostly in the summer (21.9 % at the urban site vs. 11.5 and 10.5 % at the rural sites). The highest contribution of fly ash (33.2 %) was found at the rural site located to the north of the power plants during wintertime, when winds are favorable. In the warm period, the highest contribution of fly ash was found at the rural site located to the south of the power plants, although it was less important (7.2 %). Moderate contributions of fly ash were found at the urban site (5.4 and 2.7 % in the cold and the warm period, respectively). Finally, the mine field was identified as a minor PM10 source, occasionally contributing with lignite dust and/or deposited wet ash dust under dry summer conditions, with the summertime contributions ranging between 3.1 and 11.0 % among the three sites. The non-parametric bootstrapped potential source contribution function analysis was further applied to localize the regions of sources apportioned by the RCMB. For the majority of sources, source regions appeared as being located within short distances from the sampling sites (within the Peloponnesse Peninsula). More distant Greek areas of the NNE sector also appeared to be source regions for traffic emissions and secondary calcium sulfate dust.

EVALUATION OF FUGITIVE EMISSIONS AT A FORMER LANDFILL SITE IN COLORADO SPRINGS, COLORADO, USING GROUND-BASED OPTICAL REMOTE SENSING TECHNOLOGY

EPA Science Inventory

This report details a measurement campaign conducted using the Radial Plume Mapping (RPM) method and optical remote sensing technologies to characterize fugitive emissions. This work was funded by EPAs Monitoring and Measurement for the 21st Century Initiative, or 21M2. The si...

Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado, Utah, and Texas using mobile isotopic methane analysis based on Cavity Ringdown Spectroscopy

NASA Astrophysics Data System (ADS)

Rella, Chris; Winkler, Renato; Sweeney, Colm; Karion, Anna; Petron, Gabrielle; Crosson, Eric

2014-05-01

Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of carbon dioxide emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation, provided that the fugitive emissions of methane are kept under control. A key step in assessing these emissions in a given region is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis, using the isotopic carbon signature to distinguish between natural gas and landfills or ruminants. We present measurements of methane using a mobile spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in three intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, the Uintah basin in Utah, and the Barnett Shale in Texas. Performance of the CRDS isotope analyzer is presented, including precision, calibration, stability, and the potential for measurement bias due to other atmospheric constituents. Mobile isotope measurements of individual sources and in the nocturnal boundary layer have been combined to establish the fraction of the observed methane emissions that can be attributed to natural gas activities. The fraction of total methane emissions in the Denver-Julesburg basin attributed to natural gas emissions is 78 +/- 13%. In the Uinta basin, which has no other significant sources of methane, the fraction is 96% +/- 15%. In addition, results from the Barnett shale are presented, which includes a major urban center (Dallas / Ft. Worth). Methane emissions in this region are spatially highly heterogeneous. Spatially-resolved isotope and concentration measurements are interpreted using a simple emissions model to arrive at an overall isotope ratio for the region.

Race towards Freedom: W.E.B. Du Bois and the Tradition of Fugitive Black Study

ERIC Educational Resources Information Center

Tinson, Christopher M.

2017-01-01

This essay centers the defense of black educational possibility in the work of historian, pioneering sociologist, and scholar, W.E.B. Du Bois (1868-1963) as a conduit igniting what critical social theorists Stefano Harney and Fred Moten (2013) call Fugitive Black Study. The critical appreciation of Du Bois forces us to consider the weight of…

Identifying sources of fugitive emissions in industrial facilities using trajectory statistical methods

NASA Astrophysics Data System (ADS)

Brereton, Carol A.; Johnson, Matthew R.

2012-05-01

Fugitive pollutant sources from the oil and gas industry are typically quite difficult to find within industrial plants and refineries, yet they are a significant contributor of global greenhouse gas emissions. A novel approach for locating fugitive emission sources using computationally efficient trajectory statistical methods (TSM) has been investigated in detailed proof-of-concept simulations. Four TSMs were examined in a variety of source emissions scenarios developed using transient CFD simulations on the simplified geometry of an actual gas plant: potential source contribution function (PSCF), concentration weighted trajectory (CWT), residence time weighted concentration (RTWC), and quantitative transport bias analysis (QTBA). Quantitative comparisons were made using a correlation measure based on search area from the source(s). PSCF, CWT and RTWC could all distinguish areas near major sources from the surroundings. QTBA successfully located sources in only some cases, even when provided with a large data set. RTWC, given sufficient domain trajectory coverage, distinguished source areas best, but otherwise could produce false source predictions. Using RTWC in conjunction with CWT could overcome this issue as well as reduce sensitivity to noise in the data. The results demonstrate that TSMs are a promising approach for identifying fugitive emissions sources within complex facility geometries.

Determining a Criminal Defendant's Competency to Proceed With an Extradition Hearing.

PubMed

Piel, Jennifer; Finkle, Michael J; Giske, Megan; Leong, Gregory B

2015-06-01

When a criminal defendant flees from one state (often referred to as the requesting state) to another (often referred to as the asylum state), the requesting state can demand that the asylum state return the defendant through a process called extradition. Only a handful of states have considered a fugitive's right to be competent to proceed with an extradition hearing. Those states fall into three categories. Some states apply the same standard as in criminal trial competency cases. Others apply a more limited competency standard. Two have found that a fugitive has no right to be competent to proceed in an extradition hearing. The particular legal test adopted affects the nature and scope of the competency evaluation conducted by the psychiatrist or psychologist in the extradition hearing. In addition, we are not aware of any state that has considered what happens to the fugitive if he is ultimately found not competent to proceed. Legislation, either state by state or through amendments to the Uniform Criminal Extradition Act, can provide the legal and psychiatric communities with guidance in assessing competency initially and in taking appropriate steps if the fugitive is ultimately found not competent. © 2015 American Academy of Psychiatry and the Law.

Impact of fugitive sources and meteorological parameters on vertical distribution of particulate matter over the industrial agglomeration.

PubMed

Štrbová, Kristína; Raclavská, Helena; Bílek, Jiří

2017-12-01

The aim of the study was to characterize vertical distribution of particulate matter, in an area well known by highest air pollution levels in Europe. A balloon filled with helium with measuring instrumentation was used for vertical observation of air pollution over the fugitive sources in Moravian-Silesian metropolitan area during spring and summer. Synchronously, selected meteorological parameters were recorded together with particulate matter for exploration its relationship with particulate matter. Concentrations of particulate matter in the vertical profile were significantly higher in the spring than in the summer. Significant effect of fugitive sources was observed up to the altitude ∼255 m (∼45 m above ground) in both seasons. The presence of inversion layer was observed at the altitude ∼350 m (120-135 m above ground) at locations with major source traffic load. Both particulate matter concentrations and number of particles for the selected particle sizes decreased with increasing height. Strong correlation of particulate matter with meteorological parameters was not observed. The study represents the first attempt to assess the vertical profile over the fugitive emission sources - old environmental burdens in industrial region. Copyright © 2017 Elsevier Ltd. All rights reserved.

Chemical characterization of atmospheric particles and source apportionment in the vicinity of a steelmaking industry.

PubMed

Almeida, S M; Lage, J; Fernández, B; Garcia, S; Reis, M A; Chaves, P C

2015-07-15

The objective of this work was to provide a chemical characterization of atmospheric particles collected in the vicinity of a steelmaking industry and to identify the sources that affect PM10 levels. A total of 94 PM samples were collected in two sampling campaigns that occurred in February and June/July of 2011. PM2.5 and PM2.5-10 were analyzed for a total of 22 elements by Instrumental Neutron Activation Analysis and Particle Induced X-ray Emission. The concentrations of water soluble ions in PM10 were measured by Ion Chromatography and Indophenol-Blue Spectrophotometry. Positive Matrix Factorization receptor model was used to identify sources of particulate matter and to determine their mass contribution to PM10. Seven main groups of sources were identified: marine aerosol identified by Na and Cl (22%), steelmaking and sinter plant represented by As, Cr, Cu, Fe, Ni, Mn, Pb, Sb and Zn (11%), sinter plant stack identified by NH4(+), K and Pb (12%), an unidentified Br source (1.8%), secondary aerosol from coke making and blast furnace (19%), fugitive emissions from the handling of raw material, sinter plant and vehicles dust resuspension identified by Al, Ca, La, Si, Ti and V (14%) and sinter plant and blast furnace associated essentially with Fe and Mn (21%). Copyright © 2015 Elsevier B.V. All rights reserved.

Impacts of air pollutants from fire and non-fire emissions on the regional air quality in Southeast Asia

NASA Astrophysics Data System (ADS)

Lee, Hsiang-He; Iraqui, Oussama; Gu, Yefu; Hung-Lam Yim, Steve; Chulakadabba, Apisada; Yiu-Ming Tonks, Adam; Yang, Zhengyu; Wang, Chien

2018-05-01

Severe haze events in Southeast Asia caused by particulate pollution have become more intense and frequent in recent years. Widespread biomass burning occurrences and particulate pollutants from human activities other than biomass burning play important roles in degrading air quality in Southeast Asia. In this study, numerical simulations have been conducted using the Weather Research and Forecasting (WRF) model coupled with a chemistry component (WRF-Chem) to quantitatively examine the contributions of aerosols emitted from fire (i.e., biomass burning) versus non-fire (including fossil fuel combustion, and road dust, etc.) sources to the degradation of air quality and visibility over Southeast Asia. These simulations cover a time period from 2002 to 2008 and are driven by emissions from (a) fossil fuel burning only, (b) biomass burning only, and (c) both fossil fuel and biomass burning. The model results reveal that 39 % of observed low-visibility days (LVDs) can be explained by either fossil fuel burning or biomass burning emissions alone, a further 20 % by fossil fuel burning alone, a further 8 % by biomass burning alone, and a further 5 % by a combination of fossil fuel burning and biomass burning. Analysis of an 24 h PM2.5 air quality index (AQI) indicates that the case with coexisting fire and non-fire PM2.5 can substantially increase the chance of AQI being in the moderate or unhealthy pollution level from 23 to 34 %. The premature mortality in major Southeast Asian cities due to degradation of air quality by particulate pollutants is estimated to increase from ˜ 4110 per year in 2002 to ˜ 6540 per year in 2008. In addition, we demonstrate the importance of certain missing non-fire anthropogenic aerosol sources including anthropogenic fugitive and industrial dusts in causing urban air quality degradation. An experiment of using machine learning algorithms to forecast the occurrence of haze events in Singapore is also explored in this study. All of these results suggest that besides minimizing biomass burning activities, an effective air pollution mitigation policy for Southeast Asia needs to consider controlling emissions from non-fire anthropogenic sources.

Fugitive from Labor Cases: Henry Garnett (1850) and Moses Honner (1860). The Constitution Community: Civil War and Reconstruction (1850-1870).

ERIC Educational Resources Information Center

Lawlor, John M., Jr.

The cases of Henry Garnett and Moses Honner bookend the 1850s, a decade of intensifying political crisis that was deeply connected to the institution of slavery. In both court actions, which were tried in the Third Circuit Court, Eastern District, Philadelphia, Pennsylvania, the defendants were charged with being "fugitives from labor."…

40 CFR 63.7293 - What work practice standards must I meet for fugitive pushing emissions if I have a non-recovery...

Code of Federal Regulations, 2010 CFR

2010-07-01

... meet for fugitive pushing emissions if I have a non-recovery coke oven battery? 63.7293 Section 63.7293... Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery Stacks Emission... pushing emissions if I have a non-recovery coke oven battery? (a) You must meet the requirements in...

40 CFR 63.7293 - What work practice standards must I meet for fugitive pushing emissions if I have a non-recovery...

Code of Federal Regulations, 2013 CFR

2013-07-01

... meet for fugitive pushing emissions if I have a non-recovery coke oven battery? 63.7293 Section 63.7293... Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery Stacks Emission... pushing emissions if I have a non-recovery coke oven battery? (a) You must meet the requirements in...

40 CFR 63.7293 - What work practice standards must I meet for fugitive pushing emissions if I have a non-recovery...

Code of Federal Regulations, 2012 CFR

2012-07-01

... meet for fugitive pushing emissions if I have a non-recovery coke oven battery? 63.7293 Section 63.7293... Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery Stacks Emission... pushing emissions if I have a non-recovery coke oven battery? (a) You must meet the requirements in...

40 CFR 63.7293 - What work practice standards must I meet for fugitive pushing emissions if I have a non-recovery...

Code of Federal Regulations, 2014 CFR

2014-07-01

... meet for fugitive pushing emissions if I have a non-recovery coke oven battery? 63.7293 Section 63.7293... Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery Stacks Emission... pushing emissions if I have a non-recovery coke oven battery? (a) You must meet the requirements in...

40 CFR 63.7293 - What work practice standards must I meet for fugitive pushing emissions if I have a non-recovery...

Code of Federal Regulations, 2011 CFR

2011-07-01

... meet for fugitive pushing emissions if I have a non-recovery coke oven battery? 63.7293 Section 63.7293... Standards for Hazardous Air Pollutants for Coke Ovens: Pushing, Quenching, and Battery Stacks Emission... pushing emissions if I have a non-recovery coke oven battery? (a) You must meet the requirements in...

Characteristics of polycyclic aromatic hydrocarbons and their gas/particle partitioning from fugitive emissions in coke plants

NASA Astrophysics Data System (ADS)

Mu, Ling; Peng, Lin; Liu, Xiaofeng; Song, Chongfang; Bai, Huiling; Zhang, Jianqiang; Hu, Dongmei; He, Qiusheng; Li, Fan

2014-02-01

Coking is one of the most important emission sources of polycyclic aromatic hydrocarbons (PAHs) in China. However, there is little information available on the emission characteristics of PAHs from fugitive emission during coking, especially on the specific processes dominating the gas-particle partitioning of PAHs. In this study, emission characteristics and gas-particle partitioning of PAHs from fugitive emission in four typical coke plants (CPs) with different scales and techniques were investigated. The average concentrations of total PAHs from fugitive emission at CP2, CP3 and CP4 (stamp charging) were 146.98, 31.82, and 35.20 μg m-3, which were 13.38-, 2.90- and 3.20-fold higher, respectively, than those at CP1 (top charging, 10.98 μg m-3). Low molecular weight PAHs with 2-3 rings made up 75.3% of the total PAHs on average, and the contributions of particulate PAH to the total BaP equivalent concentrations (BaPeq) in each plant were significantly higher than the corresponding contributions to the total PAH mass concentrations. The calculated total BaPeq concentrations varied from 0.19 to 10.86 μg m-3 with an average of 3.14 μg m-3, and more efficient measures to control fugitive emission in coke plants should be employed to prevent or reduce the health risk to workers. Absorption into organic matter dominated the gas-particle partitioning for most of the PAHs including PhA, FluA, Chr, BbF, BkF and BaP, while adsorption on elemental carbon appeared to play a dominant role for AcPy, AcP and Flu.

Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado, Utah, and Texas using mobile δ13CH4 analysis

NASA Astrophysics Data System (ADS)

Rella, C.; Crosson, E.; Petron, G.; Sweeney, C.; Karion, A.

2013-12-01

Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of CO2 emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation, provided that the fugitive emissions of methane are kept under control. A key step in assessing these emissions in a given region is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis, using the δ13CH4 signature to distinguish between natural gas and landfills or ruminants. We present measurements of mobile field δ13CH4 using a spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in three intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, the Uintah basin in Utah, and the Barnett Shale in Texas. Mobile isotope measurements of individual sources and in the nocturnal boundary layer have been combined to establish the fraction of the observed methane emissions that can be attributed to natural gas activities. The fraction of total methane emissions in the Denver-Julesburg basin attributed to natural gas emissions is 78 +/- 13%. In the Uinta basin, which has no other significant sources of methane, the fraction is 96% +/- 15%. In addition, results from the Barnett shale are presented, which includes a major urban center (Dallas / Ft. Worth). Methane emissions in this region are spatially highly heterogeneous. Spatially-resolved isotope and concentration measurements are interpreted using a simple emissions model to arrive at an overall isotope ratio for the region. (left panel) Distribution of oil and gas well pads (yellow) and landfills (blue) in the Dallas / Ft. Worth area. Mobile nocturnal measurements of methane are shown in red, indicating a strong degree of source heterogeneity. (right panel) Histogram of individual isotopic source signatures, showing distinct signatures for landfills (red) and oil and gas sources (green).

No short-term cytogenetic consequences of Hungarian red mud catastrophe.

PubMed

Gundy, Sarolta; Farkas, Gyöngyi; Székely, Gábor; Kásler, Miklós

2013-01-01

Red mud is an industrial waste produced in the process of alumina extraction from bauxite with concentrated NaOH. When the red mud-containing reservoir collapsed in Ajka Alumina Plant Hungary in October 2010, the most serious immediate effects were caused by the high alkalinity (pH ≥ 13) of the flood. Many persons suffered burn-like damage to tissues and contact with caustic desiccated ultra-fine dust with traces of toxic metals also caused irritation of upper respiratory tract and eyes. This catastrophe was unique from the point of view of genotoxic effects as well. Therefore cytogenetic examinations were carried out on inhabitants, either with burns (17 persons) or on those inhaling desiccated caustic dust (42 persons). Chromosomal aberration (CA) analysis and bleomycin (BLM)-sensitivity assays, as possible markers of effects, were studied in peripheral blood lymphocytes of persons within 4-6 weeks following the catastrophe. Controls were matched for age, sex and smoking habits, and also places of residence with different constituents of air pollution either from rural (59 persons), or from urban environments (59 persons). Neither spontaneous rate of CAs (1.47% vs. 1.69%) nor BLM-induced in vitro chromosomal breakage (0.79 vs. 0.83 break/cell) showed elevated rates when cytogenetic biomarkers of genotoxicity were compared between controls and exposed persons. Time spent in cleaning did not affect cytogenetic changes either (R(2) = 0.04). BLM-induced mutagen sensitivity was similar in exposed and control persons (27.1% vs. 30.5%). It seems that the red mud exposure does not appear to pose an immediate genotoxic hazard on residents when measured with cytogenetic methods. We recommend, however, that those involved in clean-up activities should be followed closely not only for overall health, but also for further genotoxic risk assessment, because the long-term hazards of ultra-fine fugitive dust particles with alkalinity of residual NaOH in red mud are still unknown.

Public-health assessment for Mottolo Pig Farm, Raymond, Rockingham County, New Hampshire, Region 1. CERCLIS NO. NHD980503361. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-07-20

The Mottolo Pig Farm National Priorities List (NPL) Site is located east of Blueberry Hill Road, in Rockingham County, approximately three miles west of the center of Raymond, New Hampshire. Contamination at the Mottolo Pig Farm Site includes contaminated groundwater, soil, surface water, and sediments. Site contaminants consist primarily of various volatile organic compounds (VOCs). Acid and base/neutral extractable compounds (ABNs) and metals have also been identified at the site. The site was initially discovered in April of 1979 and the U.S. Environmental Protection Agency (EPA) began an emergency action to remove buried drums and pails at the site inmore » September of 1980. There are no known documented completed exposure pathways for contaminated media present at the Mottolo Pig Farm Site. Exposure pathways of potential concern include direct contact with contaminated on-site soils and surface waters; inhalation of contaminated on-site soils as fugitive dust; and incidental ingestion of contaminated on-site soils and surface waters.« less

Health assessment for Shaw Avenue Dump Site, Charles City, Iowa, Region 7 (amended). CERCLIS No. IAD980630560. Preliminary report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1988-12-07

The Shaw Avenue Dump Site is listed by the U.S. Environmental Protection Agency (USEPA) on the National Priorities List (NPL). The 8-acre city dump site, consisting of three waste disposal areas, is located in the southeast edge of Charles City approximately 500 feet east of the Cedar River. The three disposal areas are no longer in use and have been covered with soil and are vegetated. Arsenic is the contaminant of concern at the Shaw Avenue Dump Site. On-site soil samples collected in 1981 contained concentrations of arsenic that ranged from 4-820 mg/kg. On-site groundwater, surface water, and air analysesmore » were not conducted in previous investigations. From the available information, this site is considered to be of public health concern because of the potential risk to human health caused by possible exposure to hazardous substances via ingestion of groundwater, soil, and surface water; inhalation of fugitive dust; and dermal contact with soil, surface water, and groundwater.« less

Quantitation of Japanese cedar pollen and radiocesium adhered to nonwoven fabric masks worn by the general population.

PubMed

Higaki, Shogo; Shirai, Hideharu; Hirota, Masahiro; Takeda, Eisuke; Yano, Yukiko; Shibata, Akira; Mishima, Yoshitaka; Yamamoto, Hiromi; Miyazawa, Kiyoshi

2014-08-01

In the spring of 2012, a year after the Fukushima Daiichi nuclear disaster, radiocesium-contaminated Japanese cedar pollen may have caused internal exposure to the general population by inhalation. To determine if pollen had been contaminated through uptake of radiocesium by Japanese cedars and was therefore contributing to inhalation doses, the authors measured radiocesium and Japanese cedar pollen adhered to masks worn by 68 human subjects residing in eastern Japan, including Fukushima prefecture, for 8 wk in the spring of 2012. The maximum cumulative Cs and Cs radioactivities on masks worn by an individual were 21 ± 0.36 Bq and 15 ± 0.22 Bq, respectively, and the estimated effective dose during the 8 wk was 0.494 μSv. The average estimated effective dose during the 8 wk was 0.149 μSv in Fukushima prefecture and 0.015 μSv in other prefectures, including Tokyo metropolitan. The correlation between radiocesium activity and the Japanese cedar pollen count was moderate. However, imaging-plate and light microscopy observations showed that the main source of radiocesium adhered to masks was fugitive dust.

Assessing fugitive emissions of CH4 from high-pressure gas pipelines in the UK

NASA Astrophysics Data System (ADS)

Clancy, S.; Worrall, F.; Davies, R. J.; Almond, S.; Boothroyd, I.

2016-12-01

Concern over the greenhouse gas impact of the exploitation of unconventional natural gas from shale deposits has caused a spotlight to be shone on to the entire hydrocarbon industry. Numerous studies have developed life-cycle emissions inventories to assess the impact that hydraulic fracturing has upon greenhouse gas emissions. Incorporated within life-cycle assessments are transmission and distribution losses, including infrastructure such as pipelines and compressor stations that pressurise natural gas for transport along pipelines. Estimates of fugitive emissions from transmission, storage and distribution have been criticized for reliance on old data from inappropriate sources (1970s Russian gas pipelines). In this study, we investigate fugitive emissions of CH4 from the UK high pressure national transmission system. The study took two approaches. Firstly, CH4 concentration is detected by driving along roads bisecting high pressure gas pipelines and also along an equivalent distance along a route where no high pressure gas pipeline was nearby. Five pipelines and five equivalent control routes were driven and the test was that CH4 measurements, when adjusted for distance and wind speed, should be greater on any route with a pipe than any route without a pipe. Secondly, 5 km of a high pressure gas pipeline and 5 km of equivalent farmland, were walked and soil gas (above the pipeline where present) was analysed every 7 m using a tunable diode laser. When wind adjusted 92 km of high pressure pipeline and 72 km of control route were drive over a 10 day period. When wind and distance adjusted CH4 fluxes were significantly greater on routes with a pipeline than those without. The smallest leak detectable was 3% above ambient (1.03 relative concentration) with any leaks below 3% above ambient assumed ambient. The number of leaks detected along the pipelines correlate to the estimated length of pipe joints, inferring that there are constant fugitive CH4 emissions from these joints. When scaled up to the UK's National Transmission System pipeline length of 7600 km gives a fugitive CH4 flux of 62.6 kt CH4/yr with a CO2 equivalent of 1570 kt CO2eq/yr - this fugitive emission from high pressure pipelines is 0.14% of the annual gas supply.

RHIC AND THE PURSUIT OF THE QUARK-GLUON PLASMA.

DOE Office of Scientific and Technical Information (OSTI.GOV)

MITCHELL,J.T.

2001-07-25

There is a fugitive on the loose. Its name is Quark-Gluon Plasma, alias the QGP. The QGP is a known informant with knowledge about the fundamental building blocks of nature that we wish to extract. This briefing will outline the status of the pursuit of the elusive QGP. We will cover what makes the QGP tick, its modus operandi, details on how we plan to hunt the fugitive down, and our level of success thus far.

Assessing fugitive emissions of CH4 from high-pressure gas pipelines

NASA Astrophysics Data System (ADS)

Worrall, Fred; Boothroyd, Ian; Davies, Richard

2017-04-01

The impact of unconventional natural gas production using hydraulic fracturing methods from shale gas basins has been assessed using life-cycle emissions inventories, covering areas such as pre-production, production and transmission processes. The transmission of natural gas from well pad to processing plants and its transport to domestic sites is an important source of fugitive CH4, yet emissions factors and fluxes from transmission processes are often based upon ver out of date measurements. It is important to determine accurate measurements of natural gas losses when compressed and transported between production and processing facilities so as to accurately determine life-cycle CH4 emissions. This study considers CH4 emissions from the UK National Transmission System (NTS) of high pressure natural gas pipelines. Mobile surveys of CH4 emissions using a Picarro Surveyor cavity-ring-down spectrometer were conducted across four areas in the UK, with routes bisecting high pressure pipelines and separate control routes away from the pipelines. A manual survey of soil gas measurements was also conducted along one of the high pressure pipelines using a tunable diode laser. When wind adjusted 92 km of high pressure pipeline and 72 km of control route were drive over a 10 day period. When wind and distance adjusted CH4 fluxes were significantly greater on routes with a pipeline than those without. The smallest leak detectable was 3% above ambient (1.03 relative concentration) with any leaks below 3% above ambient assumed ambient. The number of leaks detected along the pipelines correlate to the estimated length of pipe joints, inferring that there are constant fugitive CH4 emissions from these joints. When scaled up to the UK's National Transmission System pipeline length of 7600 km gives a fugitive CH4 flux of 4700 ± 2864 kt CH4/yr - this fugitive emission from high pressure pipelines is 0.016% of the annual gas supply.

Airborne concentrations of methylene diphenyl diisocyanate (MDI) in North American wood mills during the manufacturing of oriented strand board (OSB).

PubMed

Karoly, William J; Flatley, John J; Stevenson, Ralph D; Bowers, John D

2004-12-01

Air monitoring data were collected from industrial hygiene surveys over an 8-year period in oriented strand board (OSB) mills. Personal samples were taken to evaluate potential employee exposures to MDI. Area samples were taken to determine the effectiveness of control measures used in the mills to prevent fugitive emissions of wood dust, MDI, and MDI-coated wood dust from the OSB manufacturing process. Personal sampling results (578 samples covering 11 different job categories) ranged from 0.0002-0.524 mg/m3, with a GM = 0.001 and GSD = 3.71. Area sampling results (1657 samples covering 14 stationary locations in the mills) ranged from 0.0002-2.5 mg/m3, with a GM = 0.004 and GSD = 5.52. The statistical range of the data suggests high variability. While exposures to MDI above the established limits (0.051 mg/m3, 8-hour time-weighted average, 0.2 mg/m3, ceiling) can and do occur when engineering controls are not maintained and/or proper work practices and personal protective equipment are not followed/used for certain high exposure potential tasks, the data indicate that over 97% of the personal and 92% of the area sampling results are less than 0.051 mg/m3. Wipe testing was performed to determine the presence of removable, unreacted diisocyanates (NCO functional groups)from various surfaces. Positive results were found in about 13% of the wipe tests on surfaces confined to the blender, forming line, and hopper deck process areas.

Modelling soil dust aerosol in the Bodélé depression during the BoDEx campaign

NASA Astrophysics Data System (ADS)

Tegen, I.; Heinold, B.; Todd, M.; Helmert, J.; Washington, R.; Dubovik, O.

2006-05-01

We present regional model simulations of the dust emission events during the Bodélé Dust Experiment (BoDEx) that was carried out in February and March 2005 in Chad. A box model version of the dust emission model is used to test different input parameters for the emission model, and to compare the dust emissions computed with observed wind speeds to those calculated with wind speeds from the regional model simulation. While field observations indicate that dust production occurs via self-abrasion of saltating diatomite flakes in the Bodélé, the emission model based on the assumption of dust production by saltation and using observed surface wind speeds as input parameters reproduces observed dust optical thicknesses well. Although the peak wind speeds in the regional model underestimate the highest wind speeds occurring on 10-12 March 2005, the spatio-temporal evolution of the dust cloud can be reasonably well reproduced by this model. Dust aerosol interacts with solar and thermal radiation in the regional model; it is responsible for a decrease in maximum daytime temperatures by about 5 K at the beginning the dust storm on 10 March 2005. This direct radiative effect of dust aerosol accounts for about half of the measured temperature decrease compared to conditions on 8 March. Results from a global dust model suggest that the dust from the Bodélé is an important contributor to dust crossing the African Savannah region towards the Gulf of Guinea and the equatorial Atlantic, where it can contribute up to 40% to the dust optical thickness.

Modelling soil dust aerosol in the Bodélé depression during the BoDEx campaign

NASA Astrophysics Data System (ADS)

Tegen, I.; Heinold, B.; Todd, M.; Helmert, J.; Washington, R.; Dubovik, O.

2006-09-01

We present regional model simulations of the dust emission events during the Bodélé Dust Experiment (BoDEx) that was carried out in February and March 2005 in Chad. A box model version of the dust emission model is used to test different input parameters for the emission model, and to compare the dust emissions computed with observed wind speeds to those calculated with wind speeds from the regional model simulation. While field observations indicate that dust production occurs via self-abrasion of saltating diatomite flakes in the Bodélé, the emission model based on the assumption of dust production by saltation and using observed surface wind speeds as input parameters reproduces observed dust optical thicknesses well. Although the peak wind speeds in the regional model underestimate the highest wind speeds occurring on 10-12 March 2005, the spatio-temporal evolution of the dust cloud can be reasonably well reproduced by this model. Dust aerosol interacts with solar and thermal radiation in the regional model; it is responsible for a decrease in maximum daytime temperatures by about 5 K at the beginning the dust storm on 10 March 2005. This direct radiative effect of dust aerosol accounts for about half of the measured temperature decrease compared to conditions on 8 March. Results from a global dust model suggest that the dust from the Bodélé is an important contributor to dust crossing the African Savannah region towards the Gulf of Guinea and the equatorial Atlantic, where it can contribute up to 40% to the dust optical thickness.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heath, Garvin; Warner, Ethan; Steinberg, Daniel

A growing number of studies have raised questions regarding uncertainties in our understanding of methane (CH 4) emissions from fugitives and venting along the natural gas (NG) supply chain. In particular, a number of measurement studies have suggested that actual levels of CH 4 emissions may be higher than estimated by EPA" tm s U.S. GHG Emission Inventory. We reviewed the literature to identify the growing number of studies that have raised questions regarding uncertainties in our understanding of methane (CH 4) emissions from fugitives and venting along the natural gas (NG) supply chain.

The Martian dust cycle: A proposed model

NASA Technical Reports Server (NTRS)

Greeley, Ronald

1987-01-01

Despite more than a decade of study of martian dust storms, many of their characteristics and associated processes remain enigmatic, including the mechanisms for dust raising, modes of settling, and the nature of dust deposits. However, observations of Mars dust, considerations of terrestrial analogs, theoretical models, and laboratory simulations permit the formulation of a Martian Dust Cycle Model, which consists of three main processes: (1) suspension threshold, (2) transportation, and (3) deposition; two associated processes are also included: (4) dust removal and (5) the addition of new dust to the cycle. Although definitions vary, dust includes particles less than 4 to approx. 60 microns in diameter, which by terrestrial usage includes silt, loess, clay, and aerosolic dust particles. The dust cycle model is explained.

Vertical distribution of Saharan dust over Rome (Italy): Comparison between 3-year model predictions and lidar soundings

NASA Astrophysics Data System (ADS)

Kishcha, P.; Barnaba, F.; Gobbi, G. P.; Alpert, P.; Shtivelman, A.; Krichak, S. O.; Joseph, J. H.

2005-03-01

Mineral dust particles loaded into the atmosphere from the Sahara desert represent one major factor affecting the Earth's radiative budget. Regular model-based forecasts of 3-D dust fields can be used in order to determine the dust radiative effect in climate models, in spite of the large gaps in observations of dust vertical profiles. In this study, dust forecasts by the Tel Aviv University (TAU) dust prediction system were compared to lidar observations to better evaluate the model's capabilities. The TAU dust model was initially developed at the University of Athens and later modified at Tel Aviv University. Dust forecasts are initialized with the aid of the Total Ozone Mapping Spectrometer aerosol index (TOMS AI) measurements. The lidar soundings employed were collected at the outskirts of Rome, Italy (41.84°N, 12.64°E) during the high-dust activity season from March to June of the years 2001, 2002, and 2003. The lidar vertical profiles collected in the presence of dust were used for obtaining statistically significant reference parameters of dust layers over Rome and for model versus lidar comparison. The Barnaba and Gobbi (2001) approach was used in the current study to derive height-resolved dust volumes from lidar measurements of backscatter. Close inspection of the juxtaposed vertical profiles, obtained from lidar and model data near Rome, indicates that the majority (67%) of the cases under investigation can be classified as good or acceptable forecasts of the dust vertical distribution. A more quantitative comparison shows that the model predictions are mainly accurate in the middle part of dust layers. This is supported by high correlation (0.85) between lidar and model data for forecast dust volumes greater than the threshold of 1 × 10-12 cm3/cm3. In general, however, the model tends to underestimate the lidar-derived dust volume profiles. The effect of clouds in the TOMS detection of AI is supposed to be the main factor responsible for this effect. Moreover, some model assumptions on dust sources and particle size and the accuracy of model-simulated meteorological parameters are also likely to affect the dust forecast quality.

Profiling of Saharan dust from the Caribbean to western Africa - Part 2: Shipborne lidar measurements versus forecasts

NASA Astrophysics Data System (ADS)

Ansmann, Albert; Rittmeister, Franziska; Engelmann, Ronny; Basart, Sara; Jorba, Oriol; Spyrou, Christos; Remy, Samuel; Skupin, Annett; Baars, Holger; Seifert, Patric; Senf, Fabian; Kanitz, Thomas

2017-12-01

A unique 4-week ship cruise from Guadeloupe to Cabo Verde in April-May 2013 see part 1, Rittmeister et al. (2017) is used for an in-depth comparison of dust profiles observed with a polarization/Raman lidar aboard the German research vessel Meteor over the remote tropical Atlantic and respective dust forecasts of a regional (SKIRON) and two global atmospheric (dust) transport models (NMMB/BSC-Dust, MACC/CAMS). New options of model-observation comparisons are presented. We analyze how well the modeled fine dust (submicrometer particles) and coarse dust contributions to light extinction and mass concentration match respective lidar observations, and to what extent models, adjusted to aerosol optical thickness observations, are able to reproduce the observed layering and mixing of dust and non-dust (mostly marine) aerosol components over the remote tropical Atlantic. Based on the coherent set of dust profiles at well-defined distances from Africa (without any disturbance by anthropogenic aerosol sources over the ocean), we investigate how accurately the models handle dust removal at distances of 1500 km to more than 5000 km west of the Saharan dust source regions. It was found that (a) dust predictions are of acceptable quality for the first several days after dust emission up to 2000 km west of the African continent, (b) the removal of dust from the atmosphere is too strong for large transport paths in the global models, and (c) the simulated fine-to-coarse dust ratio (in terms of mass concentration and light extinction) is too high in the models compared to the observations. This deviation occurs initially close to the dust sources and then increases with distance from Africa and thus points to an overestimation of fine dust emission in the models.

The Martian Dust Cycle: Observations and Modeling

NASA Technical Reports Server (NTRS)

Kahre, Melinda A.

2013-01-01

The dust cycle is critically important for Mars' current climate system. Suspended atmospheric dust affects the radiative balance of the atmosphere, and thus greatly influences the thermal and dynamical state of the atmosphere. Evidence for the presence of dust in the Martian atmosphere can be traced back to yellow clouds telescopically observed as early as the early 19th century. The Mariner 9 orbiter arrived at Mars in November of 1971 to find a planet completely enshrouded in airborne dust. Since that time, the exchange of dust between the planet's surface and atmosphere and the role of airborne dust on Mars' weather and climate has been studied using observations and numerical models. The goal of this talk is to give an overview of the observations and to discuss the successes and challenges associated with modeling the dust cycle. Dust raising events on Mars range in size from meters to hundreds of kilometers. During some years, regional storms merge to produce hemispheric or planet encircling dust clouds that obscure the surface and raise atmospheric temperatures by tens of kelvin. The interannual variability of planet encircling dust storms is poorly understood. Although the occurrence and season of large regional and global dust storms are highly variable from one year to the next, there are many features of the dust cycle that occur year after year. A low-level dust haze is maintained during northern spring and summer, while elevated levels of atmospheric dust occur during northern autumn and winter. During years without global-scale dust storms, two peaks in total dust loading are generally observed: one peak occurs before northern winter solstice and one peak occurs after northern winter solstice. Numerical modeling studies attempting to interactively simulate the Martian dust cycle with general circulation models (GCMs) include the lifting, transport, and sedimentation of radiatively active dust. Two dust lifting processes are commonly represented in these models: wind-stress lifting (i.e., saltation) and dust devil lifting. Although the predicted patterns of dust lifting and atmospheric dust loading from these simulations capture some aspects of the observed dust cycle, there are many notable differences between the simulated and observed dust cycles. For example, it is common for models to predict one peak in global dust loading near northern winter solstice due to excessive dust lifting in the Hellas basin at this season. Additionally, it is difficult for models to realistically capture the observed interannual variability in global dust storms. New avenues of dust cycle modeling research include exploring the effects of finite surface dust reservoirs and the effects of coupling the dust and water cycles on the predicted dust cycle.

Measurements of Methane Emissions and Volatile Organic Compounds from Shale Gas Operations in the Marcellus Shale

NASA Astrophysics Data System (ADS)

Omara, M.; Subramanian, R.; Sullivan, M.; Robinson, A. L.; Presto, A. A.

2014-12-01

The Marcellus Shale is the most expansive shale gas reserve in play in the United States, representing an estimated 17 to 29 % of the total domestic shale gas reserves. The rapid and extensive development of this shale gas reserve in the past decade has stimulated significant interest and debate over the climate and environmental impacts associated with fugitive releases of methane and other pollutants, including volatile organic compounds. However, the nature and magnitude of these pollutant emissions remain poorly characterized. This study utilizes the tracer release technique to characterize total fugitive methane release rates from natural gas facilities in southwestern Pennsylvania and West Virginia that are at different stages of development, including well completion flowbacks and active production. Real-time downwind concentrations of methane and two tracer gases (acetylene and nitrous oxide) released onsite at known flow rates were measured using a quantum cascade tunable infrared laser differential absorption spectrometer (QC-TILDAS, Aerodyne, Billerica, MA) and a cavity ring down spectrometer (Model G2203, Picarro, Santa Clara, CA). Evacuated Silonite canisters were used to sample ambient air during downwind transects of methane and tracer plumes to assess volatile organic compounds (VOCs). A gas chromatograph with a flame ionization detector was used to quantify VOCs following the EPA Method TO-14A. A preliminary assessment of fugitive emissions from actively producing sites indicated that methane leak rates ranged from approximately 1.8 to 6.2 SCFM, possibly reflecting differences in facility age and installed emissions control technology. A detailed comparison of methane leak rates and VOCs emissions with recent published literature for other US shale gas plays will also be discussed.

Trace elements in particulate matter from metropolitan regions of Northern China: Sources, concentrations and size distributions.

PubMed

Pan, Yuepeng; Tian, Shili; Li, Xingru; Sun, Ying; Li, Yi; Wentworth, Gregory R; Wang, Yuesi

2015-12-15

Public concerns over airborne trace elements (TEs) in metropolitan areas are increasing, but long-term and multi-site observations of size-resolved aerosol TEs in China are still lacking. Here, we identify highly elevated levels of atmospheric TEs in megacities and industrial sites in a Beijing-Tianjin-Hebei urban agglomeration relative to background areas, with the annual mean values of As, Pb, Ni, Cd and Mn exceeding the acceptable limits of the World Health Organization. Despite the spatial variability in concentrations, the size distribution pattern of each trace element was quite similar across the region. Crustal elements of Al and Fe were mainly found in coarse particles (2.1-9 μm), whereas the main fraction of toxic metals, such as Cu, Zn, As, Se, Cd and Pb, was found in submicron particles (<1.1 μm). These toxic metals were enriched by over 100-fold relative to the Earth's crust. The size distributions of Na, Mg, K, Ca, V, Cr, Mn, Ni, Mo and Ba were bimodal, with two peaks at 0.43-0.65 μm and 4.7-5.8 μm. The combination of the size distribution information, principal component analysis and air mass back trajectory model offered a robust technique for distinguishing the main sources for airborne TEs, e.g., soil dust, fossil fuel combustion and industrial emissions, at different sites. In addition, higher elemental concentrations coincided with westerly flow, indicating that polluted soil and fugitive dust were major sources of TEs on the regional scale. However, the contribution of coal burning, iron industry/oil combustion and non-ferrous smelters to atmospheric metal pollution in Northern China should be given more attention. Considering that the concentrations of heavy metals associated with fine particles in the target region were significantly higher than those in other Asian sites, the implementations of strict environmental standards in China are required to reduce the amounts of these hazardous pollutants released into the atmosphere. Copyright © 2015 Elsevier B.V. All rights reserved.

Overview of Dust Model Inter-comparison (DMIP) in East Asia

NASA Astrophysics Data System (ADS)

Uno, I.

2004-12-01

Dust transport modeling plays an important role in understanding the recent increase of Asian Dust episodes and its impact to the regional climate system. Several dust models have been developed in several research institutes and government agencies independently since 1990s. Their numerical results either look very similar or different. Those disagreements are caused by difference in dust modules (concepts and basic mechanisms) and atmospheric models (meteorological and transport models). Therefore common understanding of performance and uncertainty of dust erosion and transport models in the Asian region becomes very important. To have a better understanding of dust model application, we proposed the dust model intercomparison under the international cooperation networks as a part of activity of ADEC (Aeolian Dust Experiment on Climate Impact) project research. Current participants are Kyusyu Univ. (Japan), Meteorological Research Institute (Japan), Hong-Kong City Univ. (China), Korean Meteorological Agency METRI (Korea), US Naval Research Laboratory (USA), Chinese Meteorological Agency (China), Institute of Atmospheric Physics (China), Insular Coastal Dynamics (Malta) and Meteorological Service of Canada (Canada). As a case study episode, we set two huge dust storms occurred in March and April 2002. Results from the dust transport model from all the participants are compiled on the same methods and examined the model characteristics against the ground and airborne measurement data. We will also examine the dust model results from the horizontal distribution at specified levels, vertical profiles, concentration at special check point and emission flux at source region, and show the important parameters for dust modeling. In this paper, we will introduce the general overview of this DMIP activity and several important conclusions from this activity.

An observationally constrained estimate of global dust aerosol optical depth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ridley, David A.; Heald, Colette L.; Kok, Jasper F.

Here, the role of mineral dust in climate and ecosystems has been largely quantified using global climate and chemistry model simulations of dust emission, transport, and deposition. However, differences between these model simulations are substantial, with estimates of global dust aerosol optical depth (AOD) that vary by over a factor of 5. Here we develop an observationally based estimate of the global dust AOD, using multiple satellite platforms, in situ AOD observations and four state-of-the-science global models over 2004–2008. We estimate that the global dust AOD at 550 nm is 0.030 ± 0.005 (1σ), higher than the AeroCom model medianmore » (0.023) and substantially narrowing the uncertainty. The methodology used provides regional, seasonal dust AOD and the associated statistical uncertainty for key dust regions around the globe with which model dust schemes can be evaluated. Exploring the regional and seasonal differences in dust AOD between our observationally based estimate and the four models in this study, we find that emissions in Africa are often overrepresented at the expense of Asian and Middle Eastern emissions and that dust removal appears to be too rapid in most models.« less

An observationally constrained estimate of global dust aerosol optical depth

DOE PAGES

Ridley, David A.; Heald, Colette L.; Kok, Jasper F.; ...

2016-12-06

Here, the role of mineral dust in climate and ecosystems has been largely quantified using global climate and chemistry model simulations of dust emission, transport, and deposition. However, differences between these model simulations are substantial, with estimates of global dust aerosol optical depth (AOD) that vary by over a factor of 5. Here we develop an observationally based estimate of the global dust AOD, using multiple satellite platforms, in situ AOD observations and four state-of-the-science global models over 2004–2008. We estimate that the global dust AOD at 550 nm is 0.030 ± 0.005 (1σ), higher than the AeroCom model medianmore » (0.023) and substantially narrowing the uncertainty. The methodology used provides regional, seasonal dust AOD and the associated statistical uncertainty for key dust regions around the globe with which model dust schemes can be evaluated. Exploring the regional and seasonal differences in dust AOD between our observationally based estimate and the four models in this study, we find that emissions in Africa are often overrepresented at the expense of Asian and Middle Eastern emissions and that dust removal appears to be too rapid in most models.« less

Methane fugitive emissions quantification using the novel 'plume camera' (spatial correlation) method

NASA Astrophysics Data System (ADS)

Crosson, E.; Rella, C.

2012-12-01

Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Given that the global warming potential of methane is many times greater than that of carbon dioxide, the importance of quantifying methane emissions becomes clear. The rapidly increasing reliance on shale gas (or other unconventional sources) is only intensifying the interest in fugitive methane releases. Natural gas (which is predominantly methane) is an attractive energy source, as it emits 40% less carbon dioxide per Joule of energy generated than coal. However, if just a small percentage of the natural gas consumed is lost due to fugitive emissions during production, processing, or transport, this global warming benefit is lost (Howarth et al. 2012). It is therefore imperative, as production of natural gas increases, that the fugitive emissions of methane are quantified accurately. Traditional direct measurement techniques often involve physical access of the leak itself to quantify the emissions rate, and are generally require painstaking effort to first find the leak and then quantify the emissions rate. With over half a million natural gas producing wells in the U.S. (U.S. Energy Information Administration), not including the associated processing, storage, and transport facilities, and with each facility having hundreds or even thousands of fittings that can potentially leak, the need is clear to develop methodologies that can provide a rapid and accurate assessment of the total emissions rate on a per-well head basis. In this paper we present a novel method for emissions quantification which uses a 'plume camera' with three 'pixels' to quantify emissions using direct measurements of methane concentration in the downwind plume. By analyzing the spatial correlation between the pixels, the spatial extent of the instantaneous plume can be inferred. This information, when combined with the wind speed through the measurement plane, provides a direct measurement of the emission rate. One example of this method is shown in Fig. 1. This method is simple to deploy, does not require an accurate model of atmospheric transport or knowledge of the distance to the emission source or its spatial distribution. Accurate measurements of the emissions can be made with just a few minutes of data collection. Results of controlled release methane experiments are presented, and the strengths and limitations of the methodology are discussed. REFERENCES R. Howarth, R. Santoro, and A. Ingraffea (2011): "Methane and the greenhouse-gas footprint of natural gas from shale formations," Climatic Change 106, 679 - 690. Fig 1: Spatial correlation analysis for two measurement points (or pixels) distributed vertically (A and B) or horizontally (A and C), for measurements at a distance of 21 meters from a methane point source of 650 sccm. The emission rate recovered from this analysis was 496 ± 160 sccm of CH4. The total measurement time was 30 minutes.

High sensitivity of Indian summer monsoon to Middle East dust absorptive properties.

PubMed

Jin, Qinjian; Yang, Zong-Liang; Wei, Jiangfeng

2016-07-28

The absorptive properties of dust aerosols largely determine the magnitude of their radiative impacts on the climate system. Currently, climate models use globally constant values of dust imaginary refractive index (IRI), a parameter describing the dust absorption efficiency of solar radiation, although it is highly variable. Here we show with model experiments that the dust-induced Indian summer monsoon (ISM) rainfall differences (with dust minus without dust) change from -9% to 23% of long-term climatology as the dust IRI is changed from zero to the highest values used in the current literature. A comparison of the model results with surface observations, satellite retrievals, and reanalysis data sets indicates that the dust IRI values used in most current climate models are too low, tending to significantly underestimate dust radiative impacts on the ISM system. This study highlights the necessity for developing a parameterization of dust IRI for climate studies.

High resolution spatial and temporal evolution of dissolved gases in groundwater during a controlled natural gas release experiment.

PubMed

Cahill, Aaron G; Parker, Beth L; Mayer, Bernhard; Mayer, K Ulrich; Cherry, John A

2018-05-01

Fugitive gas comprised primarily of methane (CH 4 ) with traces of ethane and propane (collectively termed C 1-3 ) may negatively impact shallow groundwater when unintentionally released from oil and natural gas wells. Currently, knowledge of fugitive gas migration, subsurface source identification and oxidation potential in groundwater is limited. To advance understanding, a controlled release experiment was performed at the Borden Research Aquifer, Canada, whereby 51m 3 of natural gas was injected into an unconfined sand aquifer over 72days with dissolved gases monitored over 323days. During active gas injection, a dispersed plume of dissolved C 1-3 evolved in a depth discrete and spatially complex manner. Evolution of the dissolved gas plume was driven by free-phase gas migration controlled by small-scale sediment layering and anisotropy. Upon cessation of gas injection, C 1-3 concentrations increased to the greatest levels observed, particularly at 2 and 6m depths, reaching up to 31.5, 1.5 and 0.1mg/L respectively before stabilizing and persisting. At no time did groundwater become fully saturated with natural gas at the scale of sampling undertaken. Throughout the experiment the isotopic composition of injected methane (δ 13 C of -42.2‰) and the wetness parameter (i.e. the ratio of C 1 to C 2+ ) constituted excellent tracers for the presence of fugitive gas at concentrations >2mg/L. At discrete times C 1-3 concentrations varied by up to 4 orders of magnitude over 8m of aquifer thickness (e.g. from <0.01 to 30mg/L for CH 4 ), while some groundwater samples lacked evidence of fugitive gas, despite being within 10m of the injection zone. Meanwhile, carbon isotope ratios of dissolved CH 4 showed no evidence of oxidation. Our results show that while impacts to aquifers from a fugitive gas event are readily detectable at discrete depths, they are spatially and temporally variable and dissolved methane has propensity to persist. Copyright © 2017 Elsevier B.V. All rights reserved.

Dust Emission Modeling Incorporating Land Cover Parameterizations in the Chihuahuan Desert and Dissemination of Data Suites

NASA Astrophysics Data System (ADS)

Olgin, J. G.; Pennington, D. D.; Webb, N.

2017-12-01

A variety of models have been developed to better understand dust emissions - from initial erosive event to entrainment to transport through the atmosphere. Many of these models have been used to analyze dust emissions by representing atmospheric and surface variables, such as wind and soil moisture respectively, in a numerical model to determine the resulting dust emissions. Pertinent to modeling these variables, there are three important factors influencing emissions: 1) Friction velocity threshold based on wind interactions with dust, 2) horizontal flux (saltation) of dust and 3) vertical dust flux. While all of the existing models incorporate these processes, additional improvements are needed to yield results reflective of recorded data of dust events. Our investigation focuses on explicitly identifying specific land cover (LC) elements unique to the Chihuahan desert that contribute to aerodynamic roughness length (Zo); a main component to dust emission and key to provide results more representative of known dust events in semi-arid regions. These elements will be formulated into computer model inputs by conducting analysis (e.g. geostatistics) on field and satellite data to ascertain core LC characteristics responsible for affecting wind velocities (e.g. wind shadowing effects), which are conducive to dust emissions. This inputs will be used in a modified program using the Weather and Research Forecast model (WRF) to replicate previously recorded dust events. Results from this study will be presented here.

Urban dust in the Guanzhong basin of China, part II: A case study of urban dust pollution using the WRF-Dust model.

PubMed

Li, Nan; Long, Xin; Tie, Xuexi; Cao, Junji; Huang, Rujin; Zhang, Rong; Feng, Tian; Liu, Suixin; Li, Guohui

2016-01-15

We developed a regional dust dynamical model (WRF-Dust) to simulate surface dust concentrations in the Guanzhong (GZ) basin of China during two typical dust cases (19th Aug. and 26th Nov., 2013), and compared model results with the surface measurements at 17 urban and rural sites. The important improvement of the model is to employ multiple high-resolution (0.5-500 m) remote sensing data to construct dust sources. The new data include the geographic information of constructions, croplands, and barrens over the GZ basin in summer and winter of 2013. For the first time, detailed construction dust emissions have been introduced in a regional dust model in large cities of China. Our results show that by including the detailed dust sources, model performance at simulating dust pollutions in the GZ basin is significantly improved. For example, the simulated dust concentration average for the 17 sites increases from 28 μg m(-3) to 59 μg m(-3), closing to the measured concentration of 66 μg m(-3). In addition, the correlation coefficient (r) between the calculated and measured dust concentrations is also improved from 0.17 to 0.57, suggesting that our model better presents the spatial variation. Further analysis shows that urban construction activities are the crucial source in controlling urban dust pollutions. It should be considered by policy makers for mitigating particulate air pollution in many Chinese cities. Copyright © 2015 Elsevier B.V. All rights reserved.

Forecasting Dust Storms Using the CARMA-Dust Model and MM5 Weather Data

NASA Astrophysics Data System (ADS)

Barnum, B. H.; Winstead, N. S.; Wesely, J.; Hakola, A.; Colarco, P.; Toon, O. B.; Ginoux, P.; Brooks, G.; Hasselbarth, L. M.; Toth, B.; Sterner, R.

2002-12-01

An operational model for the forecast of dust storms in Northern Africa, the Middle East and Southwest Asia has been developed for the United States Air Force Weather Agency (AFWA). The dust forecast model uses the 5th generation Penn State Mesoscale Meteorology Model (MM5), and a modified version of the Colorado Aerosol and Radiation Model for Atmospheres (CARMA). AFWA conducted a 60 day evaluation of the dust model to look at the model's ability to forecast dust storms for short, medium and long range (72 hour) forecast periods. The study used satellite and ground observations of dust storms to verify the model's effectiveness. Each of the main mesoscale forecast theaters was broken down into smaller sub-regions for detailed analysis. The study found the forecast model was able to forecast dust storms in Saharan Africa and the Sahel region with an average Probability of Detection (POD)exceeding 68%, with a 16% False Alarm Rate (FAR). The Southwest Asian theater had average POD's of 61% with FAR's averaging 10%.

Modeling dust emission in the Magellanic Clouds with Spitzer and Herschel

NASA Astrophysics Data System (ADS)

Chastenet, Jérémy; Bot, Caroline; Gordon, Karl D.; Bocchio, Marco; Roman-Duval, Julia; Jones, Anthony P.; Ysard, Nathalie

2017-05-01

Context. Dust modeling is crucial to infer dust properties and budget for galaxy studies. However, there are systematic disparities between dust grain models that result in corresponding systematic differences in the inferred dust properties of galaxies. Quantifying these systematics requires a consistent fitting analysis. Aims: We compare the output dust parameters and assess the differences between two dust grain models, the DustEM model and THEMIS. In this study, we use a single fitting method applied to all the models to extract a coherent and unique statistical analysis. Methods: We fit the models to the dust emission seen by Spitzer and Herschel in the Small and Large Magellanic Clouds (SMC and LMC). The observations cover the infrared (IR) spectrum from a few microns to the sub-millimeter range. For each fitted pixel, we calculate the full n-D likelihood based on a previously described method. The free parameters are both environmental (U, the interstellar radiation field strength; αISRF, power-law coefficient for a multi-U environment; Ω∗, the starlight strength) and intrinsic to the model (YI: abundances of the grain species I; αsCM20, coefficient in the small carbon grain size distribution). Results: Fractional residuals of five different sets of parameters show that fitting THEMIS brings a more accurate reproduction of the observations than the DustEM model. However, independent variations of the dust species show strong model-dependencies. We find that the abundance of silicates can only be constrained to an upper-limit and that the silicate/carbon ratio is different than that seen in our Galaxy. In the LMC, our fits result in dust masses slightly lower than those found in the literature, by a factor lower than 2. In the SMC, we find dust masses in agreement with previous studies.

Directional passive ambient air monitoring of ammonia for fugitive source attribution; a field trial with wind tunnel characteristics

NASA Astrophysics Data System (ADS)

Solera García, M. A.; Timmis, R. J.; Van Dijk, N.; Whyatt, J. D.; Leith, I. D.; Leeson, S. R.; Braban, C. F.; Sheppard, L. J.; Sutton, M. A.; Tang, Y. S.

2017-10-01

Atmospheric ammonia is a precursor for secondary particulate matter formation, which harms human health and contributes to acidification and eutrophication. Under the 2012 Gothenburg Protocol, 2005 emissions must be cut by 6% by 2020. In the UK, 83% of total emissions originate from agricultural practices such as fertilizer use and rearing of livestock, with emissions that are spatially extensive and variable in nature. Such fugitive emissions make resolving and tracking of individual site performance challenging. The Directional Passive Air quality Sampler (DPAS) was trialled at Whim Bog, an experimental site with a wind-controlled artificial release of ammonia, in combination with CEH-developed ammonia samplers. Whilst saturation issues were identified, two DPAS-MANDE (Mini Annular Denuder) systems, when deployed in parallel, displayed an average relative deviation of 15% (2-54%) across all 12 directions, with the directions exposed to the ammonia source showing ∼5% difference. The DPAS-MANDE has shown great potential for directional discrimination and can contribute to the understanding and management of fugitive ammonia sources from intensive agriculture sites.

Chemical signatures of urban, open burning and dust transportation in an urban environment- megacity in South Asia

NASA Astrophysics Data System (ADS)

Priyadharshini, B.; Verma, S.

2016-12-01

A sub-micron aerosol sampler (SAS) consisting of two parallel stacked filter units (SFU) was deployed at an urban location (Kolkata) to study the sub-micron aerosols (water soluble inorganic ions (WSII) and carbonaceous aerosols (elemental carbon (EC) and organic carbon (OC)) collected over a year (September 2010 to August 2011). Quantification of 10 WSII species using Ion Chromatograph (IC) indicated alkaline nature of aerosols with calcium (Ca2+) being the major neutralizing factor of acidity at the study site. In terms of WSII percentage contribution, the most abundant were crustal species (Ca2+, magnesium (Mg2+) and marine species (chloride (Cl-)), followed by the secondary species sulphate (SO42-), nitrate (NO3-) and ammonium (NH4+) . Ca2+ (fugitive and transported dust) was dominant throughout the study period with K+ concentrations exhibiting seasonality with agricultural residue burning. Further, results of carbonaceous aerosols analyzed using the OC-EC aerosol analyzer following Interagency Monitoring of Protected Visual Environment (IMPROVE) protocol exhibited pronounced seasonality in OC than EC with the overall mean concentration of OC being three folds than EC. Primary organic carbon (POC) and secondary organic carbon concentrations (SOC) estimated using EC tracer method showed 57% (43%) of POC (SOC) from various emission sources. Investigation of OC/EC ratio along with non-sea salt potassium (nss-K+) values revealed influence of season specific anthropogenic activities on both OC and EC concentrations (viz. Open burning (OB)) besides fossil fuel (FF) and biofuel (BF) usage for cooking and heating prevalent over the region. Source apportionment was discerned using positive matrix factorization (PMF) with four major factors (crustal, agricultural, anthropogenic sources and mixed source (crustal + agriculture + anthropogenic) as the primary contributors to the sub-micron aerosols at the study site.

Optical properties of size-resolved particles at a Hong Kong urban site during winter

NASA Astrophysics Data System (ADS)

Gao, Yuan; Lai, Senchao; Lee, Shun-Cheng; Yau, Pui Shan; Huang, Yu; Cheng, Yan; Wang, Tao; Xu, Zheng; Yuan, Chao; Zhang, Yingyi

2015-03-01

Visibility degradation in Hong Kong is related to the city's serious air pollution problems. To investigate the aerosols' optical properties and their relationship with the chemical composition and size distribution of the particles, a monitoring campaign was conducted at an urban site in the early winter period (from October to December, 2010). The particle light scattering coefficient (Bsp) and absorption coefficient (Bap) were measured. Two collocated Micro-Orifice Uniform Deposit Impactor samplers (MOUDI110, MSP, USA) with nominal 50% cut-off aerodynamic diameters of 18, 10, 5.6, 3.2, 1.8, 1, 0.56, 0.32, 0.18, 0.1, and 0.056 μm were used to collect size-resolved particle samples. The average Bsp and Bap were 201.96 ± 105.82 Mm- 1 and 39.91 ± 19.16 Mm- 1, with an average single scattering albedo (ωo) of 0.82 ± 0.07. The theoretical method of light extinction calculation was used to determine the extinction of the size-resolved particulate matters (PM). The reconstructed light scattering coefficient correlated well with the measured scattering value in the Hong Kong urban area. Droplet mode (0.56-1.8 μm) particles contributed most to the particle light extinction (~ 69%). Organic matter, ammonium sulphate and elemental carbon were the key components causing visibility degradation in the droplet (0.56-1.8 μm) and condensation (0.1-0.56 μm) size ranges. Five sources contributing to particle light extinction have been identified using positive matrix factorisation (PMF). Traffic/engine exhausts and secondary aerosols accounted for ~ 36% and ~ 32% of particle light extinction, respectively, followed by sea salt (15%). The remaining sources, soil/fugitive dust and tire dust, contributed by ~ 10% and 7%, respectively, to particle light extinction.

Improving Air Pollution Modeling Over The Po Valley Using Saharan Dust Transport Forecasts

NASA Astrophysics Data System (ADS)

Kishcha, P.; Carnevale, C.; Finzi, G.; Pisoni, E.; Volta, M.; Nickovic, S.; Alpert, P.

2012-04-01

Our study shows that Saharan dust can contribute significantly to PM10 concentrations in the Po Valley. This dust contribution should be taken into account when estimating the exceedance of pollution limits. The DREAM dust model has been used for several years for producing operational dust forecasts at Tel-Aviv University, Israel. DREAM has been producing daily forecasts of 3-D distribution of dust concentrations over the Mediterranean region, Middle East, Europe, and over the Atlantic Ocean (http://wind.tau.ac.il/dust8/dust.html). In the current study, DREAM dust forecasts were used to give better model estimates of the contribution of Saharan dust to PM10 concentration over the Po Valley, in Northern Italy. This was carried out by the integration of daily Saharan dust forecasts into a mesoscale Transport Chemical Aerosol Model (TCAM). The Po Valley in Northern Italy is frequently affected by high PM10 concentrations, where both natural and anthropogenic sources play a significant role. Our study of TCAM and DREAM integration was carried out for the period May 15 - June 30, 2007, when four significant dust events were observed. The integrated TCAM-DREAM model performance was evaluated by comparing PM10 measurements with modeled PM10 concentrations. First, Saharan dust impact on TCAM performance was analyzed at eleven remote PM10 sites which had the lowest level of air pollution (PM10 ≤ 14 μg/m3) over the period under consideration. For those remote sites, the observed high PM10 concentrations during dust events stood prominently on the background of low PM10 concentrations. At the remote sites, such a strong deviation from the background level can not be attributed to anthropogenic aerosol emissions because of their distance from anthropogenic sources. The observed maxima in PM10 concentration during dust events is evidence of dust aerosol near the surface in Northern Italy. During all dust events under consideration, the integrated TCAM-DREAM model produced more accurate PM10 concentrations than the base TCAM model. Then, a comparison between modeled concentrations and PM10 measurements was carried out at 230 PM10 monitoring sites, distributed within the model domain. This model-vs.-measurement comparison showed that the integrated TCAM -DREAM model more accurately reproduced PM10 concentrations than the base TCAM model, both in term of correlation and mean error. Our results are of importance to countries which have to pay a penalty for exceeding the pollution limit. By extracting dust contribution from PM10 measurements, these countries could show lower rates of man-made pollution.

Petroleum coke in the urban environment: a review of potential health effects.

PubMed

Caruso, Joseph A; Zhang, Kezhong; Schroeck, Nicholas J; McCoy, Benjamin; McElmurry, Shawn P

2015-05-29

Petroleum coke, or petcoke, is a granular coal-like industrial by-product that is separated during the refinement of heavy crude oil. Recently, the processing of material from Canadian oil sands in U.S. refineries has led to the appearance of large petcoke piles adjacent to urban communities in Detroit and Chicago. The purpose of this literature review is to assess what is known about the effects of petcoke exposure on human health. Toxicological studies in animals indicate that dermal or inhalation petcoke exposure does not lead to a significant risk for cancer development or reproductive and developmental effects. However, pulmonary inflammation was observed in long-term inhalation exposure studies. Epidemiological studies in coke oven workers have shown increased risk for cancer and chronic obstructive pulmonary diseases, but these studies are confounded by multiple industrial exposures, most notably to polycyclic aromatic hydrocarbons that are generated during petcoke production. The main threat to urban populations in the vicinity of petcoke piles is most likely fugitive dust emissions in the form of fine particulate matter. More research is required to determine whether petcoke fine particulate matter causes or exacerbates disease, either alone or in conjunction with other environmental contaminants.

Petroleum Coke in the Urban Environment: A Review of Potential Health Effects

PubMed Central

Caruso, Joseph A.; Zhang, Kezhong; Schroeck, Nicholas J.; McCoy, Benjamin; McElmurry, Shawn P.

2015-01-01

Petroleum coke, or petcoke, is a granular coal-like industrial by-product that is separated during the refinement of heavy crude oil. Recently, the processing of material from Canadian oil sands in U.S. refineries has led to the appearance of large petcoke piles adjacent to urban communities in Detroit and Chicago. The purpose of this literature review is to assess what is known about the effects of petcoke exposure on human health. Toxicological studies in animals indicate that dermal or inhalation petcoke exposure does not lead to a significant risk for cancer development or reproductive and developmental effects. However, pulmonary inflammation was observed in long-term inhalation exposure studies. Epidemiological studies in coke oven workers have shown increased risk for cancer and chronic obstructive pulmonary diseases, but these studies are confounded by multiple industrial exposures, most notably to polycyclic aromatic hydrocarbons that are generated during petcoke production. The main threat to urban populations in the vicinity of petcoke piles is most likely fugitive dust emissions in the form of fine particulate matter. More research is required to determine whether petcoke fine particulate matter causes or exacerbates disease, either alone or in conjunction with other environmental contaminants. PMID:26035666

Concentration variations in primary and secondary particulate matter near a major road in Korea

DOE PAGES

Ghim, Young Sung; Won, Soo Ran; Choi, Yongjoo; ...

2016-03-31

Here, particle-phase concentrations were measured at 10, 80, and 200 m from the roadside of a national highway near Seoul in January and May 2008. The highway has two lanes each way, with an average hourly traffic volume of 1,070 vehicles. In January 2008, PM 10 concentrations decreased from 10 to 80 m but increased at 200 m. Black carbon (BC) decreased only slightly with distance due to the influence of biomass burning and open burning from the surrounding areas. In May 2008, the effect of secondary formation on both PM 10 and PM 2.5 was significant due to highmore » temperatures compared with January. Because on-road emissions had little effect on secondary formation for a short time, variations in PM 10 concentrations became smaller, and PM 2.5 concentrations increased with distance. The effects of fugitive dust on PM concentrations were greater in May than in January when the mean temperature was below freezing. In the composition variations, the amounts of primary ions, organic carbon (OC), and BC were larger in January, while those of secondary ions and others were larger in PM 10, as well as PM 2.5 in May.« less

Novorossiysk agglomeration landscapes and cement production: geochemical impact assessment

NASA Astrophysics Data System (ADS)

Alekseenko, A. V.; Pashkevich, M. A.

2016-09-01

The article deals with assessing the environmental impact of marl mining and cement production in Novorossiysk city (Krasnodar krai, Russia). The existing methods of studying the environmental effects caused by the cement industry have been reviewed. Soil and aquatic vegetation sampling has been carried out and the gross concentration of metals in the samples has been defined. The research has been conducted in the certified and accredited laboratory using emission spectral analysis. The external control has been carried out via X-ray fluorescence analysis. Based on the collected data, main chemical pollutants in soil cover and water area near the cement plant have been identified. The contaminants released by urban enterprises and motor vehicle emissions, as well as fugitive dust from dumps and the cement factory, lead to multi-element lithogeochemical anomaly at geochemical barriers in soils. Accumulation of pollutants in soil depends on the type of land use and the area relief. The most contaminated aquatic landscapes have been identified in the inner bay. According to this information, the technical proposals can be prepared for environmental safety management in strongly polluted city areas, as well as for the reclamation design in the areas currently experiencing the negative impact of cement production.

Concentration variations in primary and secondary particulate matter near a major road in Korea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghim, Young Sung; Won, Soo Ran; Choi, Yongjoo

Here, particle-phase concentrations were measured at 10, 80, and 200 m from the roadside of a national highway near Seoul in January and May 2008. The highway has two lanes each way, with an average hourly traffic volume of 1,070 vehicles. In January 2008, PM 10 concentrations decreased from 10 to 80 m but increased at 200 m. Black carbon (BC) decreased only slightly with distance due to the influence of biomass burning and open burning from the surrounding areas. In May 2008, the effect of secondary formation on both PM 10 and PM 2.5 was significant due to highmore » temperatures compared with January. Because on-road emissions had little effect on secondary formation for a short time, variations in PM 10 concentrations became smaller, and PM 2.5 concentrations increased with distance. The effects of fugitive dust on PM concentrations were greater in May than in January when the mean temperature was below freezing. In the composition variations, the amounts of primary ions, organic carbon (OC), and BC were larger in January, while those of secondary ions and others were larger in PM 10, as well as PM 2.5 in May.« less

High-resolution dust modelling over complex terrains in West Asia

NASA Astrophysics Data System (ADS)

Basart, S.; Vendrell, L.; Baldasano, J. M.

2016-12-01

The present work demonstrates the impact of model resolution in dust propagation in a complex terrain region such as West Asia. For this purpose, two simulations using the NMMB/BSC-Dust model are performed and analysed, one with a high horizontal resolution (at 0.03° × 0.03°) and one with a lower horizontal resolution (at 0.33° × 0.33°). Both model experiments cover two intense dust storms that occurred on 17-20 March 2012 as a consequence of strong northwesterly Shamal winds that spanned over thousands of kilometres in West Asia. The comparison with ground-based (surface weather stations and sunphotometers) and satellite aerosol observations (Aqua/MODIS and MSG/SEVIRI) shows that despite differences in the magnitude of the simulated dust concentrations, the model is able to reproduce these two dust outbreaks. Differences between both simulations on the dust spread rise on regional dust transport areas in south-western Saudi Arabia, Yemen and Oman. The complex orography in south-western Saudi Arabia, Yemen and Oman (with peaks higher than 3000 m) has an impact on the transported dust concentration fields over mountain regions. Differences between both model configurations are mainly associated to the channelization of the dust flow through valleys and the differences in the modelled altitude of the mountains that alters the meteorology and blocks the dust fronts limiting the dust transport. These results demonstrate how the dust prediction in the vicinity of complex terrains improves using high-horizontal resolution simulations.

Numerical study of Asian dust transport during the springtime of 2001 simulated with the Chemical Weather Forecasting System (CFORS) model

NASA Astrophysics Data System (ADS)

Uno, Itsushi; Satake, Shinsuke; Carmichael, Gregory R.; Tang, Youhua; Wang, Zifa; Takemura, Toshihiko; Sugimoto, Nobuo; Shimizu, Atsushi; Murayama, Toshiyuki; Cahill, Thomas A.; Cliff, Steven; Uematsu, Mitsuo; Ohta, Sachio; Quinn, Patricia K.; Bates, Timothy S.

2004-10-01

The regional-scale aerosol transport model Chemical Weather Forecasting System (CFORS) is used for analysis of large-scale dust phenomena during the Asian Pacific Regional Characterization Experiment (ACE-Asia) intensive observation. Dust modeling results are examined with the surface weather reports, satellite-derived dust index (Total Ozone Mapping Spectrometer (TOMS) Aerosol Index (AI)), Mie-scattering lidar observation, and surface aerosol observations. The CFORS dust results are shown to accurately reproduce many of the important observed features. Model analysis shows that the simulated dust vertical loading correlates well with TOMS AI and that the dust loading is transported with the meandering of the synoptic-scale temperature field at the 500-hPa level. Quantitative examination of aerosol optical depth shows that model predictions are within 20% difference of the lidar observations for the major dust episodes. The structure of the ACE-Asia Perfect Dust Storm, which occurred in early April, is clarified with the help of the CFORS model analysis. This storm consisted of two boundary layer components and one elevated dust (>6-km height) feature (resulting from the movement of two large low-pressure systems). Time variation of the CFORS dust fields shows the correct onset timing of the elevated dust for each observation site, but the model results tend to overpredict dust concentrations at lower latitude sites. The horizontal transport flux at 130°E longitude is examined, and the overall dust transport flux at 130°E during March-April is evaluated to be 55 Tg.

Spatial distribution of mineral dust single scattering albedo based on DREAM model

NASA Astrophysics Data System (ADS)

Kuzmanoski, Maja; Ničković, Slobodan; Ilić, Luka

2016-04-01

Mineral dust comprises a significant part of global aerosol burden. There is a large uncertainty in estimating role of dust in Earth's climate system, partly due to poor characterization of its optical properties. Single scattering albedo is one of key optical properties determining radiative effects of dust particles. While it depends on dust particle sizes, it is also strongly influenced by dust mineral composition, particularly the content of light-absorbing iron oxides and the mixing state (external or internal). However, an assumption of uniform dust composition is typically used in models. To better represent single scattering albedo in dust atmospheric models, required to increase accuracy of dust radiative effect estimates, it is necessary to include information on particle mineral content. In this study, we present the spatial distribution of dust single scattering albedo based on the Dust Regional Atmospheric Model (DREAM) with incorporated particle mineral composition. The domain of the model covers Northern Africa, Middle East and the European continent, with horizontal resolution set to 1/5°. It uses eight particle size bins within the 0.1-10 μm radius range. Focusing on dust episode of June 2010, we analyze dust single scattering albedo spatial distribution over the model domain, based on particle sizes and mineral composition from model output; we discuss changes in this optical property after long-range transport. Furthermore, we examine how the AERONET-derived aerosol properties respond to dust mineralogy. Finally we use AERONET data to evaluate model-based single scattering albedo. Acknowledgement We would like to thank the AERONET network and the principal investigators, as well as their staff, for establishing and maintaining the AERONET sites used in this work.

Forecast errors in dust vertical distributions over Rome (Italy): Multiple particle size representation and cloud contributions

NASA Astrophysics Data System (ADS)

Kishcha, P.; Alpert, P.; Shtivelman, A.; Krichak, S. O.; Joseph, J. H.; Kallos, G.; Katsafados, P.; Spyrou, C.; Gobbi, G. P.; Barnaba, F.; Nickovic, S.; PéRez, C.; Baldasano, J. M.

2007-08-01

In this study, forecast errors in dust vertical distributions were analyzed. This was carried out by using quantitative comparisons between dust vertical profiles retrieved from lidar measurements over Rome, Italy, performed from 2001 to 2003, and those predicted by models. Three models were used: the four-particle-size Dust Regional Atmospheric Model (DREAM), the older one-particle-size version of the SKIRON model from the University of Athens (UOA), and the pre-2006 one-particle-size Tel Aviv University (TAU) model. SKIRON and DREAM are initialized on a daily basis using the dust concentration from the previous forecast cycle, while the TAU model initialization is based on the Total Ozone Mapping Spectrometer aerosol index (TOMS AI). The quantitative comparison shows that (1) the use of four-particle-size bins in the dust modeling instead of only one-particle-size bins improves dust forecasts; (2) cloud presence could contribute to noticeable dust forecast errors in SKIRON and DREAM; and (3) as far as the TAU model is concerned, its forecast errors were mainly caused by technical problems with TOMS measurements from the Earth Probe satellite. As a result, dust forecast errors in the TAU model could be significant even under cloudless conditions. The DREAM versus lidar quantitative comparisons at different altitudes show that the model predictions are more accurate in the middle part of dust layers than in the top and bottom parts of dust layers.

Integrative Analysis of Desert Dust Size and Abundance Suggests Less Dust Climate Cooling

NASA Technical Reports Server (NTRS)

Kok, Jasper F.; Ridley, David A.; Zhou, Qing; Miller, Ron L.; Zhao, Chun; Heald, Colette L.; Ward, Daniel S.; Albani, Samuel; Haustein, Karsten

2017-01-01

Desert dust aerosols affect Earths global energy balance through interactions with radiation, clouds, and ecosystems. But the magnitudes of these effects are so uncertain that it remains unclear whether atmospheric dust has a net warming or cooling effect on global climate. Consequently, it is still uncertain whether large changes in atmospheric dust loading over the past century have slowed or accelerated anthropogenic climate change, and the climate impact of possible future alterations in dust loading is similarly disputed. Here we use an integrative analysis of dust aerosol sizes and abundance to constrain the climatic impact of dust through direct interactions with radiation. Using a combination of observational, experimental, and model data, we find that atmospheric dust is substantially coarser than represented in current climate models. Since coarse dust warms global climate, the dust direct radiative effect (DRE) is likely less cooling than the 0.4 W m superscript 2 estimated by models in a current ensemble. We constrain the dust DRE to -0.20 (-0.48 to +0.20) W m superscript 2, which suggests that the dust DRE produces only about half the cooling that current models estimate, and raises the possibility that dust DRE is actually net warming the planet.

Integrated spatiotemporal characterization of dust sources and outbreaks in Central and East Asia

NASA Astrophysics Data System (ADS)

Darmenova, Kremena T.

The potential of atmospheric dust aerosols to modify the Earth's environment and climate has been recognized for some time. However, predicting the diverse impact of dust has several significant challenges. One is to quantify the complex spatial and temporal variability of dust burden in the atmosphere. Another is to quantify the fraction of dust originating from human-made sources. This thesis focuses on the spatiotemporal characterization of sources and dust outbreaks in Central and East Asia by integrating ground-based data, satellite multisensor observations, and modeling. A new regional dust modeling system capable of operating over a span of scales was developed. The modeling system consists of a dust module DuMo, which incorporates several dust emission schemes of different complexity, and the PSU/NCAR mesoscale model MM5, which offers a variety of physical parameterizations and flexible nesting capability. The modeling system was used to perform for the first time a comprehensive study of the timing, duration, and intensity of individual dust events in Central and East Asia. Determining the uncertainties caused by the choice of model physics, especially the boundary layer parameterization, and the dust production scheme was the focus of our study. Implications to assessments of the anthropogenic dust fraction in these regions were also addressed. Focusing on Spring 2001, an analysis of routine surface meteorological observations and satellite multi-sensor data was carried out in conjunction with modeling to determine the extent to which integrated data set can be used to characterize the spatiotemporal distribution of dust plumes at a range of temporal scales, addressing the active dust sources in China and Mongolia, mid-range transport and trans-Pacific, long-range transport of dust outbreaks on a case-by-case basis. This work demonstrates that adequate and consistent characterization of individual dust events is central to establishing a reliable climatology, ultimately leading to improved assessments of dust impacts on the environment and climate. This will also help to identify the appropriate temporal and spatial scales for adequate intercomparison between model results and observational data as well as for developing an integrated analysis methodology for dust studies.

Dust environment of an airless object: A phase space study with kinetic models

NASA Astrophysics Data System (ADS)

Kallio, E.; Dyadechkin, S.; Fatemi, S.; Holmström, M.; Futaana, Y.; Wurz, P.; Fernandes, V. A.; Álvarez, F.; Heilimo, J.; Jarvinen, R.; Schmidt, W.; Harri, A.-M.; Barabash, S.; Mäkelä, J.; Porjo, N.; Alho, M.

2016-01-01

The study of dust above the lunar surface is important for both science and technology. Dust particles are electrically charged due to impact of the solar radiation and the solar wind plasma and, therefore, they affect the plasma above the lunar surface. Dust is also a health hazard for crewed missions because micron and sub-micron sized dust particles can be toxic and harmful to the human body. Dust also causes malfunctions in mechanical devices and is therefore a risk for spacecraft and instruments on the lunar surface. Properties of dust particles above the lunar surface are not fully known. However, it can be stated that their large surface area to volume ratio due to their irregular shape, broken chemical bonds on the surface of each dust particle, together with the reduced lunar environment cause the dust particles to be chemically very reactive. One critical unknown factor is the electric field and the electric potential near the lunar surface. We have developed a modelling suite, Dusty Plasma Environments: near-surface characterisation and Modelling (DPEM), to study globally and locally dust environments of the Moon and other airless bodies. The DPEM model combines three independent kinetic models: (1) a 3D hybrid model, where ions are modelled as particles and electrons are modelled as a charged neutralising fluid, (2) a 2D electrostatic Particle-in-Cell (PIC) model where both ions and electrons are treated as particles, and (3) a 3D Monte Carlo (MC) model where dust particles are modelled as test particles. The three models are linked to each other unidirectionally; the hybrid model provides upstream plasma parameters to be used as boundary conditions for the PIC model which generates the surface potential for the MC model. We have used the DPEM model to study properties of dust particles injected from the surface of airless objects such as the Moon, the Martian moon Phobos and the asteroid RQ36. We have performed a (v0, m/q)-phase space study where the property of dust particles at different initial velocity (v0) and initial mass per charge (m/q) ratio were analysed. The study especially identifies regions in the phase space where the electric field within a non-quasineutral plasma region above the surface of the object, the Debye layer, becomes important compared with the gravitational force. Properties of the dust particles in the phase space region where the electric field plays an important role are studied by a 3D Monte Carlo model. The current DPEM modelling suite does not include models of how dust particles are initially injected from the surface. Therefore, the presented phase space study cannot give absolute 3D dust density distributions around the analysed airless objects. For that, an additional emission model is necessary, which determines how many dust particles are emitted at various places on the analysed (v0, m/q)-phase space. However, this study identifies phase space regions where the electric field within the Debye layer plays an important role for dust particles. Overall, the initial results indicate that when a realistic dust emission model is available, the unified lunar based DPEM modelling suite is a powerful tool to study globally and locally the dust environments of airless bodies such as planetary moons, Mercury, asteroids and non-active comets far from the Sun.

Improving the Non-Hydrostatic Numerical Dust Model by Integrating Soil Moisture and Greenness Vegetation Fraction Data with Different Spatiotemporal Resolutions.

PubMed

Yu, Manzhu; Yang, Chaowei

2016-01-01

Dust storms are devastating natural disasters that cost billions of dollars and many human lives every year. Using the Non-Hydrostatic Mesoscale Dust Model (NMM-dust), this research studies how different spatiotemporal resolutions of two input parameters (soil moisture and greenness vegetation fraction) impact the sensitivity and accuracy of a dust model. Experiments are conducted by simulating dust concentration during July 1-7, 2014, for the target area covering part of Arizona and California (31, 37, -118, -112), with a resolution of ~ 3 km. Using ground-based and satellite observations, this research validates the temporal evolution and spatial distribution of dust storm output from the NMM-dust, and quantifies model error using measurements of four evaluation metrics (mean bias error, root mean square error, correlation coefficient and fractional gross error). Results showed that the default configuration of NMM-dust (with a low spatiotemporal resolution of both input parameters) generates an overestimation of Aerosol Optical Depth (AOD). Although it is able to qualitatively reproduce the temporal trend of the dust event, the default configuration of NMM-dust cannot fully capture its actual spatial distribution. Adjusting the spatiotemporal resolution of soil moisture and vegetation cover datasets showed that the model is sensitive to both parameters. Increasing the spatiotemporal resolution of soil moisture effectively reduces model's overestimation of AOD, while increasing the spatiotemporal resolution of vegetation cover changes the spatial distribution of reproduced dust storm. The adjustment of both parameters enables NMM-dust to capture the spatial distribution of dust storms, as well as reproducing more accurate dust concentration.

Wind-Stress Dust Lifting in a Mars Global Circulation Model: Representation across Resolutions

NASA Astrophysics Data System (ADS)

Chapman, R.; Lewis, S.; Balme, M. R.; Steele, L.

2017-12-01

The formation of Martian dust storms is believed to be driven by dust lifting by near-surface wind stress (NSWS). Accurately representing this dust lifting within Mars Global Circulation Models (MGCMs) is important in order to gain a full understanding of the Martian dust storm cycle. Parameterisations of dust lifting by NSWS exist within several MGCMs; implementations differ but they all follow a similar design, so progress within one model is relevant to the entire field. Few studies have explored in detail how the results of these parameterisations can be affected by changing the horizontal resolution of the model. An accurate parameterisation of dust lifting by NSWS will lift a representative dust mass, reproducing characteristic dust optical depths in the atmosphere. The geographical distribution of the dust lifting by NSWS will also change throughout the year, affecting patterns of dust storm formation and development. Currently, suitable values for dust lifting parameters must be identified at every new model resolution. Resolutions of 5° latitude x 5° longitude are often used to model the Martian climate, as thermal tides and long-term weather patterns can be well represented at this resolution. However, smaller scale phenomena (such as near-surface winds driven by local topography) cannot be accurately depicted at this resolution. We use the LMD-UK MGCM to complete multi-year simulations across multiple model resolutions. Our experiments range from `low' resolution 5° lat x 5° lon to `high' resolution 1° lat x 1° lon. In experiments with fixed, constant lifting parameters, we find that higher resolution simulations lift more dust, but that this trend is asymptotic. At low resolutions, dust lifting increases proportionately with the increase in number of horizontal gridboxes. However, at high resolutions, doubling the number of gridboxes results only in a 30% increase in the total dust mass lifted. Geographical and temporal distributions of dust lifting are investigated, as well as the total dust lifted, in order to assess the optimum parameters for each resolution, and to develop a calibration scheme for this dust lifting across model resolutions. The scheme is verified through comparison with spacecraft observations of dust optical depths and dust storm locations.

Emergence, Agency, and Interaction-Notes from the Field.

PubMed

Penny, Simon

2015-01-01

This article describes the development of several interactive installations and robotic artworks developed through the 1990s and the technological, theoretical, and discursive context in which those works arose. The main works discussed are Petit Mal (1989-1995), Sympathetic Sentience (1996-1997), Fugitive I (1996-1997), Traces (1998-1999), and Fugitive II (2001-2004)-full documentation at ( www.simonpenny.net/works ). These works were motivated by a critical analysis of cognitivist computer science, which contrasted with notions of embodied experience arising from the arts. The works address questions of agency and interaction, informed by cybernetics and artificial life.

Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado and Utah using mobile stable isotope (13CH4) analysis

NASA Astrophysics Data System (ADS)

Rella, Chris; Jacobson, Gloria; Crosson, Eric; Karion, Anna; Petron, Gabrielle; Sweeney, Colm

2013-04-01

Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of CO2 emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation. However, given that the global warming potential of methane is many times greater than that of carbon dioxide (Solomon et al. 2007), the importance of quantifying the fugitive emissions of methane throughout the natural gas production and distribution process becomes clear (Howarth et al. 2011). A key step in the process of assessing the emissions arising from natural gas production activities is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis. In particular, the 13CH4 signature of natural gas (-35 to -40 permil) is significantly different that the signature of other significant sources of methane, such as landfills or ruminants (-45 to -70 permil). In this paper we present measurements of mobile field 13CH4 using a spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in two intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, and the Uintah basin in Utah. Mobile isotope measurements in the nocturnal boundary layer have been made, over a total path of 100s of km throughout the regions, allowing spatially resolved measurements of the regional isotope signature. Secondly, this analyzer was used to quantify the isotopic signature of those individual sources (natural gas fugitive emissions, concentrated animal feeding operations, and landfills) that constitute the majority of methane emissions in these regions, by making measurements of the isotope ratio directly in the downwind plume from each source. These data are combined to establish the fraction of the observed methane emissions that can be attributed to natural gas activities in the regions. The fraction of total methane emissions in the Denver-Julesburg basin that can be attributed to natural gas fugitive emissions has been determined to be 71 +/- 9%. References: 1. S. Solomon, D. Qin, M. Manning, Z. Chen, M. Marquis, K.B. Averyt, M.Tignor and H.L. Miller (eds.). IPCC, 2007: Climate Change 2007: The Physical Science Basis of the Fourth Assessment Report. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA. 2. R.W. Howarth, R. Santoro, and A. Ingraffea. "Methane and the greenhouse-gas footprint of natural gas from shale formations." Climate Change, 106, 679 (2011).

Using dust, gas and stellar mass-selected samples to probe dust sources and sinks in low-metallicity galaxies

NASA Astrophysics Data System (ADS)

De Vis, P.; Gomez, H. L.; Schofield, S. P.; Maddox, S.; Dunne, L.; Baes, M.; Cigan, P.; Clark, C. J. R.; Gomez, E. L.; Lara-López, M.; Owers, M.

2017-10-01

We combine samples of nearby galaxies with Herschel photometry selected on their dust, metal, H I and stellar mass content, and compare these to chemical evolution models in order to discriminate between different dust sources. In a companion paper, we used an H I-selected sample of nearby galaxies to reveal a subsample of very gas-rich (gas fraction >80 per cent) sources with dust masses significantly below predictions from simple chemical evolution models, and well below Md/M* and Md/Mgas scaling relations seen in dust and stellar-selected samples of local galaxies. We use a chemical evolution model to explain these dust-poor, but gas-rich, sources as well as the observed star formation rates (SFRs) and dust-to-gas ratios. We find that (I) a delayed star formation history is required to model the observed SFRs; (II) inflows and outflows are required to model the observed metallicities at low gas fractions; (III) a reduced contribution of dust from supernovae (SNe) is needed to explain the dust-poor sources with high gas fractions. These dust-poor, low stellar mass galaxies require a typical core-collapse SN to produce 0.01-0.16 M⊙ of dust. To match the observed dust masses at lower gas fractions, significant grain growth is required to counteract the reduced contribution from dust in SNe and dust destruction from SN shocks. These findings are statistically robust, though due to intrinsic scatter it is not always possible to find one single model that successfully describes all the data. We also show that the dust-to-metal ratio decreases towards lower metallicity.

Surface Winds and Dust Biases in Climate Models

NASA Astrophysics Data System (ADS)

Evan, A. T.

2018-01-01

An analysis of North African dust from models participating in the Fifth Climate Models Intercomparison Project (CMIP5) suggested that, when forced by observed sea surface temperatures, these models were unable to reproduce any aspects of the observed year-to-year variability in dust from North Africa. Consequently, there would be little reason to have confidence in the models' projections of changes in dust over the 21st century. However, no subsequent study has elucidated the root causes of the disagreement between CMIP5 and observed dust. Here I develop an idealized model of dust emission and then use this model to show that, over North Africa, such biases in CMIP5 models are due to errors in the surface wind fields and not due to the representation of dust emission processes. These results also suggest that because the surface wind field over North Africa is highly spatially autocorrelated, intermodel differences in the spatial structure of dust emission have little effect on the relative change in year-to-year dust emission over the continent. I use these results to show that similar biases in North African dust from the NASA Modern Era Retrospective analysis for Research and Applications (MERRA) version 2 surface wind field biases but that these wind biases were not present in the first version of MERRA.

Improving dust emission characterization in dust models using dynamic high-resolution geomorphic erodibility map

NASA Astrophysics Data System (ADS)

Parajuli, S. P.; Yang, Z.; Kocurek, G.

2013-12-01

Dust is known to affect the earth radiation budget, biogeochemical cycle, precipitation, human health and visibility. Despite the increased research effort, dust emission modeling remains challenging because dust emission is affected by complex geomorphological processes. Existing dust models overestimate dust emission and rely on tuning and a static erodibility factor in order to make simulated results comparable to remote sensing and ground-based observations. In most of current models, dust emission is expressed in terms of threshold friction speed, which ultimately depends mainly upon the percentage clay content and soil moisture. Unfortunately, due to the unavailability of accurate and high resolution input data of the clay content and soil moisture, estimated threshold friction speed commonly does not represent the variability in field condition. In this work, we attempt to improve dust emission characterization by developing a high resolution geomorphic map of the Middle East and North Africa (MENA), which is responsible for more than 50% of global dust emission. We develop this geomorphic map by visually examining high resolution satellite images obtained from Google Earth Pro and ESRI base map. Albeit subjective, our technique is more reliable compared to automatic image classification technique because we incorporate knowledge of geological/geographical setting in identifying dust sources. We hypothesize that the erodibility is unique for different geomorphic landforms and that it can be quantified by the correlation between observed wind speed and satellite retrieved aerosol optical depth (AOD). We classify the study area into several key geomorphological categories with respect to their dust emission potential. Then we quantify their dust emission potential using the correlation between observed wind speed and satellite retrieved AOD. The dynamic, high-resolution geomorphic erodibility map thus prepared will help to reduce the uncertainty in current dust models associated with poor characterization of dust sources. The baseline dust scheme used in this study is the Dust Entrainment and Deposition (DEAD) model, which is also a component of the community land model (CLM). Proposed improvements in the dust emission representation will help to better understand the accurate effect of dust on climate processes.

A new hybrid particle/fluid model for cometary dust

NASA Astrophysics Data System (ADS)

Shou, Y.; Combi, M. R.; Tenishev, V.; Toth, G.; Hansen, K. C.; Huang, Z.; Gombosi, T. I.; Fougere, N.; Rubin, M.

2017-12-01

Cometary dust grains, which originate from comets, are believed to contain clues to the formation and the evolution of comets. They also play an important role in shaping the cometary environment, as they are able to decelerate and heat the gas through collisions, carry charges and interact with the plasma environment, and possibly sublimate gases. Therefore, the loss rate and behavior of dust grains are of interest to scientists. Currently, mainly two types of numerical dust models exist: particle models and fluid models have been developed. Particle models, which keep track of the positions and velocities of all gas and dust particles, allow crossing dust trajectories and a more accurate description of returning dust grains than the fluid model. However, in order to compute the gas drag force, the particle model needs to follow more gas particles than dust particles. A fluid model is usually more computationally efficient and is often used to provide simulations on larger spatial and temporal scales. In this work, a new hybrid model is developed to combine the advantages of both particle and fluid models. In the new approach a fluid model based on the University of Michigan BATSRUS code computes the gas properties, and feeds the gas drag force to the particle model, which is based on the Adaptive Mesh Particle Simulator (AMPS) code, to calculate the motion of dust grains. The coupling is done via the Space Weather Modeling Framework (SWMF). In addition to the capability of simulating the long-term dust phenomena, the model can also designate small active regions on the nucleus for comparison with the temporary fine dust features in observations. With the assistance of the newly developed model, the effect of viewing angles on observed dust jet shapes and the transportation of heavy dust grains from the southern to the northern hemisphere of comet 67P/Churyumov-Gerasimenko will be studied and compared with Rosetta mission images. Preliminary results will be presented. Support from contracts JPL #1266314 and #1266313 from the US Rosetta Project and grant NNX14AG84G from the NASA Planetary Atmospheres Program are gratefully acknowledged.

Atmospheric Dust Modeling from Meso to Global Scales with the Online NMMB/BSC-Dust Model Part 2: Experimental Campaigns in Northern Africa

NASA Technical Reports Server (NTRS)

Haustein, K.; Perez, C.; Baldasano, J. M.; Jorba, O.; Basart, S.; Miller, R. L.; Janjic, Z.; Black, T.; Nickovic, S.; Todd, M. C.;

Dust devil characteristics and associated dust entrainment based on large-eddy simulations

NASA Astrophysics Data System (ADS)

Klose, Martina; Kwidzinski, Nick; Shao, Yaping

2015-04-01

The characteristics of dust devils, such as occurrence frequency, lifetime, size, and intensity, are usually inferred from in situ field measurements and remote sensing. Numerical models, e.g. large-eddy simulation (LES) models, have also been established as a tool to investigate dust devils and their structures. However, most LES models do not contain a dust module. Here, we present results from simulations using the WRF-LES model coupled to the convective turbulent dust emission (CTDE) scheme of Klose et al. (2014). The scheme describes the stochastic process of aerodynamic dust entrainment in the absence of saltation. It therefore allows for dust emission even below the threshold friction velocity for saltation. Numerical experiments have been conducted for different atmospheric stability and background wind conditions at 10 m horizontal resolution. A dust devil tracking algorithm is used to identify dust devils in the simulation results. The detected dust devils are statistically analyzed with regard to e.g. radius, pressure drop, lifetime, and turbulent wind speeds. An additional simulation with higher horizontal resolution (2 m) is conducted for conditions, which are especially favorable for dust devil development, i.e. unstable atmospheric stratification and weak mean winds. The higher resolution enables the identification of smaller dust devils and a more detailed structure analysis. Dust emission fluxes, dust concentrations, and dust mass budgets are calculated from the simulations. The results are compared to field observations reported in literature.

Agglomeration of dust in convective clouds initialized by nuclear bursts

NASA Astrophysics Data System (ADS)

Bacon, D. P.; Sarma, R. A.

Convective clouds initialized by nuclear bursts are modeled using a two-dimensional axisymmetric cloud model. Dust transport through the atmosphere is studied using five different sizes ranging from 1 to 10,000 μm in diameter. Dust is transported in the model domain by advection and sedimentation. Water is allowed to condense onto dust particles in regions of supersaturation in the cloud. The agglomeration of dust particles resulting from the collision of different size dust particles is modeled. The evolution of the dust mass spectrum due to agglomeration is modeled using a numerical scheme which is mass conserving and has low implicit diffusion. Agglomeration moves mass from the small particles with very small fall velocity to the larger sizes which fall to the ground more readily. Results indicate that the dust fallout can be increased significantly due to this process. In preliminary runs using stable and unstable environmental soundings, at 30 min after detonation the total dust in the domain was 11 and 30%, respectively, less than a control case without agglomeration.

Mineral dust transport in the Arctic modelled with FLEXPART

NASA Astrophysics Data System (ADS)

Groot Zwaaftink, Christine; Grythe, Henrik; Stohl, Andreas

2016-04-01

Aeolian transport of mineral dust is suggested to play an important role in many processes. For instance, mineral aerosols affect the radiation balance of the atmosphere, and mineral deposits influence ice sheet mass balances and terrestrial and ocean ecosystems. While many efforts have been done to model global dust transport, relatively little attention has been given to mineral dust in the Arctic. Even though this region is more remote from the world's major dust sources and dust concentrations may be lower than elsewhere, effects of mineral dust on for instance the radiation balance can be highly relevant. Furthermore, there are substantial local sources of dust in or close to the Arctic (e.g., in Iceland), whose impact on Arctic dust concentrations has not been studied in detail. We therefore aim to estimate contributions of different source regions to mineral dust in the Arctic. We have developed a dust mobilization routine in combination with the Lagrangian dispersion model FLEXPART to make such estimates. The lack of details on soil properties in many areas requires a simple routine for global simulations. However, we have paid special attention to the dust sources on Iceland. The mobilization routine does account for topography, snow cover and soil moisture effects, in addition to meteorological parameters. FLEXPART, driven with operational meteorological data from European Centre for Medium-Range Weather Forecasts, was used to do a three-year global dust simulation for the years 2010 to 2012. We assess the model performance in terms of surface concentration and deposition at several locations spread over the globe. We will discuss how deposition and dust load patterns in the Arctic change throughout seasons based on the source of the dust. Important source regions for mineral dust found in the Arctic are not only the major desert areas, such as the Sahara, but also local bare-soil regions. From our model results, it appears that total dust load in the Arctic atmosphere is dominated by dust from Africa and Asia. However, in the lower atmosphere, local sources also contribute strongly to dust concentrations. Especially from Iceland, significant amounts of dust are mobilized. These local sources with relatively shallow transport of dust also affect the spatial distribution of dust deposition. For instance, model estimates show that in autumn and winter most of the deposited dust in Greenland originates from sources north of 60 degrees latitude.

The Mars Dust Cycle: Investigating the Effects of Radiatively Active Water Ice Clouds on Surface Stresses and Dust Lifting Potential with the NASA Ames Mars General Circulation Model

NASA Technical Reports Server (NTRS)

Kahre, Melinda A.; Hollingsworth, Jeffery

2012-01-01

The dust cycle is a critically important component of Mars' current climate system. Dust is present in the atmosphere of Mars year-round but the dust loading varies with season in a generally repeatable manner. Dust has a significant influence on the thermal structure of the atmosphere and thus greatly affects atmospheric circulation. The dust cycle is the most difficult of the three climate cycles (CO2, water, and dust) to model realistically with general circulation models. Until recently, numerical modeling investigations of the dust cycle have typically not included the effects of couplings to the water cycle through cloud formation. In the Martian atmosphere, dust particles likely provide the seed nuclei for heterogeneous nucleation of water ice clouds. As ice coats atmospheric dust grains, the newly formed cloud particles exhibit different physical and radiative characteristics. Thus, the coupling between the dust and water cycles likely affects the distributions of dust, water vapor and water ice, and thus atmospheric heating and cooling and the resulting circulations. We use the NASA Ames Mars GCM to investigate the effects of radiatively active water ice clouds on surface stress and the potential for dust lifting. The model includes a state-of-the-art water ice cloud microphysics package and a radiative transfer scheme that accounts for the radiative effects of CO2 gas, dust, and water ice clouds. We focus on simulations that are radiatively forced by a prescribed dust map, and we compare simulations that do and do not include radiatively active clouds. Preliminary results suggest that the magnitude and spatial patterns of surface stress (and thus dust lifting potential) are substantial influenced by the radiative effects of water ice clouds.

Assessment of State-of-the-Art Dust Emission Scheme in GEOS

NASA Technical Reports Server (NTRS)

Darmenov, Anton; Liu, Xiaohong; Prigent, Catherine

2017-01-01

The GEOS modeling system has been extended with state of the art parameterization of dust emissions based on the vertical flux formulation described in Kok et al 2014. The new dust scheme was coupled with the GOCART and MAM aerosol models. In the present study we compare dust emissions, aerosol optical depth (AOD) and radiative fluxes from GEOS experiments with the standard and new dust emissions. AOD from the model experiments are also compared with AERONET and satellite based data. Based on this comparative analysis we concluded that the new parameterization improves the GEOS capability to model dust aerosols originating from African sources, however it lead to overestimation of dust emissions from Asian and Arabian sources. Further regional tuning of key parameters controlling the threshold friction velocity may be required in order to achieve more definitive and uniform improvement in the dust modeling skill.

Non-monotonic spatial distribution of the interstellar dust in astrospheres: finite gyroradius effect

NASA Astrophysics Data System (ADS)

Katushkina, O. A.; Alexashov, D. B.; Izmodenov, V. V.; Gvaramadze, V. V.

2017-02-01

High-resolution mid-infrared observations of astrospheres show that many of them have filamentary (cirrus-like) structure. Using numerical models of dust dynamics in astrospheres, we suggest that their filamentary structure might be related to specific spatial distribution of the interstellar dust around the stars, caused by a gyrorotation of charged dust grains in the interstellar magnetic field. Our numerical model describes the dust dynamics in astrospheres under an influence of the Lorentz force and assumption of a constant dust charge. Calculations are performed for the dust grains with different sizes separately. It is shown that non-monotonic spatial dust distribution (viewed as filaments) appears for dust grains with the period of gyromotion comparable with the characteristic time-scale of the dust motion in the astrosphere. Numerical modelling demonstrates that the number of filaments depends on charge-to-mass ratio of dust.

Trans-Pacific yellow sand transport observed in April 1998: A numerical simulation

NASA Astrophysics Data System (ADS)

Uno, Itsushi; Amano, Hiroyasu; Emori, Seita; Kinoshita, Kisei; Matsui, Ichiro; Sugimoto, Nobuo

2001-08-01

A yellow sand transport episode from the Asian continent to Japan and North America which occurred in April 1998 is simulated. A new on-line dust tracer model coupled with a regional-scale meteorological model is developed and applied to this dust storm episode. The results for two large dust events that started during April 14-15 and 19-20, 1998, have been analyzed and discussed. The first dust storm was trapped in a cutoff vortex developed over the China plain. A modeled 3-D structure of dust associated with this cutoff vortex agreed with an observed time-height cross section of dust concentration. Results show that the strong subsidence at the backside of the vortex restricted the dust layer below 3 km level. Model analysis revealed that the second dust event that started during April 19-20 over inland China was the origin of a dust episode reported over North America. The trans-Pacific dust transport simulation successfully showed the dust onset near the West Coast of North America. Elevation of the dust layer during the long-range transport was below 3 km. The model is extended to include the transport of an Asian origin anthropogenic tracer over the North Pacific Rim. Both the natural-origin mineral dust and the Asian-origin anthropogenic tracer are simultaneously transported even if their emission regions are different.

All-Sky Observational Evidence for An Inverse Correlation Between Dust Temperature and Emissivity Spectral Index

NASA Technical Reports Server (NTRS)

Liang, Z.; Fixsen, D. J.; Gold, B.

2012-01-01

We show that a one-component variable-emissivity-spectral-index model (the free- model) provides more physically motivated estimates of dust temperature at the Galactic polar caps than one- or two-component fixed-emissivity-spectral-index models (fixed- models) for interstellar dust thermal emission at far-infrared and millimeter wavelengths. For the comparison we have fit all-sky one-component dust models with fixed or variable emissivity spectral index to a new and improved version of the 210-channel dust spectra from the COBE-FIRAS, the 100-240 micrometer maps from the COBE-DIRBE and the 94 GHz dust map from the WMAP. The best model, the free-alpha model, is well constrained by data at 60-3000 GHz over 86 per cent of the total sky area. It predicts dust temperature (T(sub dust)) to be 13.7-22.7 (plus or minus 1.3) K, the emissivity spectral index (alpha) to be 1.2-3.1 (plus or minus 0.3) and the optical depth (tau) to range 0.6-46 x 10(exp -5) with a 23 per cent uncertainty. Using these estimates, we present all-sky evidence for an inverse correlation between the emissivity spectral index and dust temperature, which fits the relation alpha = 1/(delta + omega (raised dot) T(sub dust) with delta = -.0.510 plus or minus 0.011 and omega = 0.059 plus or minus 0.001. This best model will be useful to cosmic microwave background experiments for removing foreground dust contamination and it can serve as an all-sky extended-frequency reference for future higher resolution dust models.

Operational Dust Prediction

NASA Technical Reports Server (NTRS)

Benedetti, Angela; Baldasano, Jose M.; Basart, Sara; Benincasa, Francesco; Boucher, Olivier; Brooks, Malcolm E.; Chen, Jen-Ping; Colarco, Peter R.; Gong, Sunlin; Huneeus, Nicolas;

Noble gases identify the mechanisms of fugitive gas contamination in drinking-water wells overlying the Marcellus and Barnett Shales

PubMed Central

Darrah, Thomas H.; Vengosh, Avner; Jackson, Robert B.; Warner, Nathaniel R.; Poreda, Robert J.

2014-01-01

Horizontal drilling and hydraulic fracturing have enhanced energy production but raised concerns about drinking-water contamination and other environmental impacts. Identifying the sources and mechanisms of contamination can help improve the environmental and economic sustainability of shale-gas extraction. We analyzed 113 and 20 samples from drinking-water wells overlying the Marcellus and Barnett Shales, respectively, examining hydrocarbon abundance and isotopic compositions (e.g., C2H6/CH4, δ13C-CH4) and providing, to our knowledge, the first comprehensive analyses of noble gases and their isotopes (e.g., 4He, 20Ne, 36Ar) in groundwater near shale-gas wells. We addressed two questions. (i) Are elevated levels of hydrocarbon gases in drinking-water aquifers near gas wells natural or anthropogenic? (ii) If fugitive gas contamination exists, what mechanisms cause it? Against a backdrop of naturally occurring salt- and gas-rich groundwater, we identified eight discrete clusters of fugitive gas contamination, seven in Pennsylvania and one in Texas that showed increased contamination through time. Where fugitive gas contamination occurred, the relative proportions of thermogenic hydrocarbon gas (e.g., CH4, 4He) were significantly higher (P < 0.01) and the proportions of atmospheric gases (air-saturated water; e.g., N2, 36Ar) were significantly lower (P < 0.01) relative to background groundwater. Noble gas isotope and hydrocarbon data link four contamination clusters to gas leakage from intermediate-depth strata through failures of annulus cement, three to target production gases that seem to implicate faulty production casings, and one to an underground gas well failure. Noble gas data appear to rule out gas contamination by upward migration from depth through overlying geological strata triggered by horizontal drilling or hydraulic fracturing. PMID:25225410

Noble gases identify the mechanisms of fugitive gas contamination in drinking-water wells overlying the Marcellus and Barnett Shales.

PubMed

Darrah, Thomas H; Vengosh, Avner; Jackson, Robert B; Warner, Nathaniel R; Poreda, Robert J

2014-09-30

Horizontal drilling and hydraulic fracturing have enhanced energy production but raised concerns about drinking-water contamination and other environmental impacts. Identifying the sources and mechanisms of contamination can help improve the environmental and economic sustainability of shale-gas extraction. We analyzed 113 and 20 samples from drinking-water wells overlying the Marcellus and Barnett Shales, respectively, examining hydrocarbon abundance and isotopic compositions (e.g., C2H6/CH4, δ(13)C-CH4) and providing, to our knowledge, the first comprehensive analyses of noble gases and their isotopes (e.g., (4)He, (20)Ne, (36)Ar) in groundwater near shale-gas wells. We addressed two questions. (i) Are elevated levels of hydrocarbon gases in drinking-water aquifers near gas wells natural or anthropogenic? (ii) If fugitive gas contamination exists, what mechanisms cause it? Against a backdrop of naturally occurring salt- and gas-rich groundwater, we identified eight discrete clusters of fugitive gas contamination, seven in Pennsylvania and one in Texas that showed increased contamination through time. Where fugitive gas contamination occurred, the relative proportions of thermogenic hydrocarbon gas (e.g., CH4, (4)He) were significantly higher (P < 0.01) and the proportions of atmospheric gases (air-saturated water; e.g., N2, (36)Ar) were significantly lower (P < 0.01) relative to background groundwater. Noble gas isotope and hydrocarbon data link four contamination clusters to gas leakage from intermediate-depth strata through failures of annulus cement, three to target production gases that seem to implicate faulty production casings, and one to an underground gas well failure. Noble gas data appear to rule out gas contamination by upward migration from depth through overlying geological strata triggered by horizontal drilling or hydraulic fracturing.

Source contributions to United States ozone and particulate matter over five decades from 1970 to 2020

NASA Astrophysics Data System (ADS)

Nopmongcol, Uarporn; Alvarez, Yesica; Jung, Jaegun; Grant, John; Kumar, Naresh; Yarwood, Greg

2017-10-01

Evaluating long-term air quality trends can demonstrate effectiveness of control strategies and guide future air quality management planning. Observations have shown that ozone (O3) and fine particulate matter (PM2.5) in the US have declined since as early as 1980 in some areas. But observation trends alone cannot separate effects of changes in local and global emissions to US air quality which are important to air quality planners. This study uses a regional model (CAMx) nested within a global model (GEOS-Chem) to characterize regional changes in O3 and PM2.5 due to the intercontinental transport and local/regional emissions representing six modeling years within five decades (1970-2020). We use the CAMx Source Apportionment Technology (OSAT/PSAT) to estimate contributions from 6 source sectors in 7 source regions plus 6 other groups for a total of 48 tagged contributions. On-road mobile sources consistently make the largest U.S. anthropogenic emissions contribution to O3 in all cities examined even though they decline substantially from 1970 to 2005 and also from 2005 to 2020. Off-road mobile source contributions increase from 1970 to 2005 and then decrease after 2005 in all of the cities. The boundary conditions, mostly from intercontinental transport, contribute more than 20 ppb to high maximum daily 8-h average (MDA8) O3 for all six years. We found that lowering NOx emissions raises O3 formation efficiency (OFE) across all emission categories which will limit potential O3 benefits of local NOx strategies in the near future. PM2.5 benefited from adoption of control devices between 1970 and 1980 and has continued to decline through 2005 and expected to decline further by 2020. Area sources such as residential, commercial and fugitive dust emissions stand out as making large contributions to PM2.5 that are not declining. Inter-regional transport is less important in 2020 than 1990 for both pollutants.

The impact of Saharan Dust on the genesis and evolution of Hurricane Earl (2010)

NASA Astrophysics Data System (ADS)

Pan, B.; Wang, Y.; Hsieh, J. S.; Lin, Y.; Hu, J.; Zhang, R.

2017-12-01

Dust, one of the most abundant natural aerosols, can exert substantial radiative and microphysical effects on the regional climate and has potential impacts on the genesis and intensification of tropical cyclones (TCs). A Weather Research and Forecasting Model and the Regional Oceanic Modeling System coupled model (WRF-ROMS) is used to simulate the evolution of Hurricane Earl (2010), of which Earl was interfered by Saharan dust at the TC genesis stage. A new dust module has been implemented to the TAMU two-moment microphysics scheme in the WRF model. It accounts for both dust as Cloud Condensation Nuclei (CCN) and Ice Nuclei (IN). The hurricane track, intensity and precipitation have been compared to the best track data and TRMM precipitation, respectively. The influences of Saharan dust on Hurricane Earl are investigated with dust-CCN, dust-IN, and dust-free scenarios. The analysis shows that Saharan dust changes the latent heat and moisture distribution, invigorates the convections in the hurricane's eyewall, and suppresses the development of Earl. This finding addresses the importance of accounting dust microphysics effect on hurricane predictions.

A study of long-term trends in mineral dust aerosol distributions in Asia using a general circulation model

NASA Astrophysics Data System (ADS)

Mukai, Makiko; Nakajima, Teruyuki; Takemura, Toshihiko

2004-10-01

Dust events have been observed in Japan with high frequency since 2000. On the other hand, the frequency of dust storms is said to have decreased in the desert regions of China since about the middle of the 1970s. This study simulates dust storms and transportation of mineral dust aerosols in the east Asia region from 1981 to 2001 using an aerosol transport model, Spectral Radiation-Transport Model for Aerosol Species (SPRINTARS), implemented in the Center for Climate System Research/National Institute for Environmental Studies atmospheric global circulation model, in order to investigate the main factors that control a dust event and its long-term variation. The model was forced to simulate a real atmospheric condition by a nudging technique using European Centre for Medium-Range Weather Forecasts reanalysis data on wind velocities, temperature, specific humidity, soil wetness, and snow depth. From a comparison between the long-term change in the dust emission and model parameters, it is found that the wind speed near the surface level had a significant influence on the dust emission, and snow is also an important factor in the early spring dust emission. The simulated results suggested that dust emissions from northeast China have a great impact on dust mass concentration in downwind regions, such as the cities of northeastern China, Korea, and Japan. When the frequency of dust events was high in Japan, a low-pressure system tended to develop over the northeast China region that caused strong winds. From 2000 to 2001 the simulated dust emission flux decreased in the Taklimakan desert and the northwestern part of China, while it increased in the Gobi desert and the northeastern part of China. Consequently, dust particles seem to be transported more from the latter region by prevailing westerlies in the springtime to downwind areas as actually observed. In spite of the similarity, however, there is still a large disagreement between observed and simulated dust frequencies and concentrations. A more realistic land surface and uplift mechanism of dust particles should be modeled to improve the model simulation. Desertification of the northeastern China region may be another reason for this disagreement.

Numerical simulation of "an American haboob"

NASA Astrophysics Data System (ADS)

Vukovic, A.; Vujadinovic, M.; Pejanovic, G.; Andric, J.; Kumjian, M. R.; Djurdjevic, V.; Dacic, M.; Prasad, A. K.; El-Askary, H. M.; Paris, B. C.; Petkovic, S.; Nickovic, S.; Sprigg, W. A.

2014-04-01

A dust storm of fearful proportions hit Phoenix in the early evening hours of 5 July 2011. This storm, an American haboob, was predicted hours in advance because numerical, land-atmosphere modeling, computing power and remote sensing of dust events have improved greatly over the past decade. High-resolution numerical models are required for accurate simulation of the small scales of the haboob process, with high velocity surface winds produced by strong convection and severe downbursts. Dust productive areas in this region consist mainly of agricultural fields, with soil surfaces disturbed by plowing and tracks of land in the high Sonoran Desert laid barren by ongoing draught. Model simulation of the 5 July 2011 dust storm uses the coupled atmospheric-dust model NMME-DREAM (Non-hydrostatic Mesoscale Model on E grid, Janjic et al., 2001; Dust REgional Atmospheric Model, Nickovic et al., 2001; Pérez et al., 2006) with 4 km horizontal resolution. A mask of the potentially dust productive regions is obtained from the land cover and the normalized difference vegetation index (NDVI) data from the Moderate Resolution Imaging Spectroradiometer (MODIS). The scope of this paper is validation of the dust model performance, and not use of the model as a tool to investigate mechanisms related to the storm. Results demonstrate the potential technical capacity and availability of the relevant data to build an operational system for dust storm forecasting as a part of a warning system. Model results are compared with radar and other satellite-based images and surface meteorological and PM10 observations. The atmospheric model successfully hindcasted the position of the front in space and time, with about 1 h late arrival in Phoenix. The dust model predicted the rapid uptake of dust and high values of dust concentration in the ensuing storm. South of Phoenix, over the closest source regions (~25 km), the model PM10 surface dust concentration reached ~2500 μg m-3, but underestimated the values measured by the PM10 stations within the city. Model results are also validated by the MODIS aerosol optical depth (AOD), employing deep blue (DB) algorithms for aerosol loadings. Model validation included Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO), equipped with the lidar instrument, to disclose the vertical structure of dust aerosols as well as aerosol subtypes. Promising results encourage further research and application of high-resolution modeling and satellite-based remote sensing to warn of approaching severe dust events and reduce risks for safety and health.

Radiative transfer modeling of dust-coated Pancam calibration target materials: Laboratory visible/near-infrared spectrogoniometry

USGS Publications Warehouse

Johnson, J. R.; Sohl-Dickstein, J.; Grundy, W.M.; Arvidson, R. E.; Bell, J.F.; Christensen, P.R.; Graff, T.; Guinness, E.A.; Kinch, K.; Morris, Robert; Shepard, M.K.

2006-01-01

Laboratory visible/near-infrared multispectral observations of Mars Exploration Rover Pancam calibration target materials coated with different thicknesses of Mars spectral analog dust were acquired under variable illumination geometries using the Bloomsburg University Goniometer. The data were fit with a two-layer radiative transfer model that combines a Hapke formulation for the dust with measured values of the substrate interpolated using a He-Torrance approach. We first determined the single-scattering albedo, phase function, opposition effect width, and amplitude for the dust using the entire data set (six coating thicknesses, three substrates, four wavelengths, and phase angles 3??-117??). The dust exhibited single-scattering albedo values similar to other Mars analog soils and to Mars Pathfinder dust and a dominantly forward scattering behavior whose scattering lobe became narrower at longer wavelengths. Opacity values for each dust thickness corresponded well to those predicted from the particles sizes of the Mars analog dust. We then restricted the number of substrates, dust thicknesses, and incidence angles input to the model. The results suggest that the dust properties are best characterized when using substrates whose reflectances are brighter and darker than those of the deposited dust and data that span a wide range of dust thicknesses. The model also determined the dust photometric properties relatively well despite limitations placed on the range of incidence angles. The model presented here will help determine the photometric properties of dust deposited on the MER rovers and to track the multiple episodes of dust deposition and erosion that have occurred at both landing sites. Copyright 2006 by the American Geophysical Union.

Modeling of intercontinental Saharan dust transport: What consequences on atmospheric concentrations and deposition fluxes in the Caribbean?

NASA Astrophysics Data System (ADS)

Laurent, Benoit; Formenti, Paola; Desboeufs, Karine; Vincent, Julie; Denjean, Cyrielle; Siour, Guillaume; Mayol-Bracero, Olga L.

2015-04-01

The Dust Aging and Transport from Africa to the Caribbean (Dust-AttaCk) project aims todocument the physical and optical properties of long-range transported African dust to the Caribbean. A comprehensive field campaign was conducted in Cape San Juan, Puerto Rico (18.38°N 65.62°W) during June-July 2012, offering the opportunity to constrain the way Saharan dust are transported from North Africa to the Caribbean by 3D models. Our main objectives are: (i) to discuss the ability of the CHIMERE Eulerian off-line chemistry-transport model to simulate atmospheric Saharan dust loads observed in the Caribbean during the Dust-AttaCk campaign, as well as the altitude of the dust plumes transport over the North Atlantic Ocean up to the Caribbean, (ii) to study the main Saharan dust emission source areas contributing to the dust loads in the Caribbean, (iii) to estimate the Saharan dust deposition in the Caribbean for deposition events observed during the Dust-AttaCk campaign. The dust model outputs are hourly dust concentration fields in µg m-3 for 12 aerosol size bins up to 30 µm and for each of the 15 sigma pressure vertical levels, column integrated dustaerosol optical depth (AOD), and dry and wet deposition fluxes.The simulations performed for the Dust-AttaCk campaign period as well as satellite observations (MODIS AOD, SEVIRI AOD) are used to identify the Saharan emission source regions activated and to study the evolution of the dust plumes tothe Cape San Juan station. In complement, the vertical transport of dust plumes transported from Saharan dust sources and over the North Atlantic Ocean is investigated combining model simulations and CALIOP observations. Aerosol surface concentrations and AOD simulated with CHIMERE are compared with sin-situ observations at Cape San Juan and AERONET stations. Wet deposition measurements performed allow us to constrain dust deposition flux simulated in the Caribbean after long-range transport.

Impact of Radiatively Interactive Dust Aerosols on Dust Transport and Mobilization in the NASA Goddard Earth Observing System (GEOS-5) Earth Model

NASA Astrophysics Data System (ADS)

Colarco, P. R.; Rocha Lima, A.; Darmenov, A.; Bloecker, C.

2017-12-01

Mineral dust aerosols scatter and absorb solar and infrared radiation, impacting the energy budget of the Earth system which in turns feeds back on the dynamical processes responsible for mobilization of dust in the first place. In previous work with radiatively interactive aerosols in the NASA Goddard Earth Observing System global model (GEOS-5) we found a positive feedback between dust absorption and emissions. Emissions were the largest for the highest shortwave absorption considered, which additionally produced simulated dust transport in the best agreement with observations. The positive feedback found was in contrast to other modeling studies which instead found a negative feedback, where the impact of dust absorption was to stabilize the surface levels of the atmosphere and so reduce wind speeds. A key difference between our model and other models was that in GEOS-5 we simulated generally larger dust particles, with correspondingly larger infrared absorption that led to a pronounced difference in the diurnal cycle of dust emissions versus simulations where these long wave effects were not considered. In this paper we seek to resolve discrepancies between our previous simulations and those of other modeling groups. We revisit the question of dust radiative feedback on emissions with a recent version of the GEOS-5 system running at a higher spatial resolution and including updates to the parameterizations for dust mobilization, initial dust particle size distribution, loss processes, and radiative transfer, and identify key uncertainties that remain based on dust optical property assumptions.

An online mineral dust model within the global/regional NMMB: current progress and plans

NASA Astrophysics Data System (ADS)

Perez, C.; Haustein, K.; Janjic, Z.; Jorba, O.; Baldasano, J. M.; Black, T.; Nickovic, S.

2008-12-01

While mineral dust distribution and effects are important on global scales, they strongly depend on dust emissions that are occurring on small spatial and temporal scales. Indeed, the accuracy of surface wind speed used in dust models is crucial. Due to the high-order power dependency on wind friction velocity and the threshold behaviour of dust emissions, small errors in surface wind speed lead to large dust emission errors. Most global dust models use prescribed wind fields provided by major meteorological centres (e.g., NCEP and ECMWF) and their spatial resolution is currently about 1 degree x 1 degree . Such wind speeds tend to be strongly underestimated over arid and semi-arid areas and do not account for mesoscale systems responsible for a significant fraction of dust emissions regionally and globally. Other significant uncertainties in dust emissions resulting from such approaches are related to the misrepresentation of high subgrid-scale spatial heterogeneity in soil and vegetation boundary conditions, mainly in semi-arid areas. In order to significantly reduce these uncertainties, the Barcelona Supercomputing Center is currently implementing a mineral dust model coupled on-line with the new global/regional NMMB atmospheric model using the ESMF framework under development in NOAA/NCEP/EMC. The NMMB is an evolution of the operational WRF-NMME extending from meso to global scales, and including non-hydrostatic option and improved tracer advection. This model is planned to become the next-generation NCEP mesoscale model for operational weather forecasting in North America. Current implementation is based on the well established regional dust model and forecast system Eta/DREAM (http://www.bsc.es/projects/earthscience/DREAM/). First successful global simulations show the potentials of such an approach and compare well with DREAM regionally. Ongoing developments include improvements in dust size distribution representation, sedimentation, dry deposition, wet scavenging and dust-radiation feedback, as well as the efficient implementation of the model on High Performance Supercomputers for global simulations and forecasts at high resolution.

Numerical simulation of "An American Haboob"

NASA Astrophysics Data System (ADS)

Vukovic, A.; Vujadinovic, M.; Pejanovic, G.; Andric, J.; Kumjian, M. R.; Djurdjevic, V.; Dacic, M.; Prasad, A. K.; El-Askary, H. M.; Paris, B. C.; Petkovic, S.; Nickovic, S.; Sprigg, W. A.

2013-10-01

A dust storm of fearful proportions hit Phoenix in the early evening hours of 5 July 2011. This storm, an American haboob, was predicted hours in advance because numerical, land-atmosphere modeling, computing power and remote sensing of dust events have improved greatly over the past decade. High resolution numerical models are required for accurate simulation of the small-scales of the haboob process, with high velocity surface winds produced by strong convection and severe downbursts. Dust productive areas in this region consist mainly of agricultural fields, with soil surfaces disturbed by plowing and tracks of land in the high Sonoran desert laid barren by ongoing draught. Model simulation of the 5 July 2011 dust storm uses the coupled atmospheric-dust model NMME-DREAM with 3.5 km horizontal resolution. A mask of the potentially dust productive regions is obtained from the land cover and the Normalized Difference Vegetation Index (NDVI) data from the Moderate Resolution Imaging Spectroradiometer (MODIS). Model results are compared with radar and other satellite-based images and surface meteorological and PM10 observations. The atmospheric model successfully hindcasted the position of the front in space and time, with about 1 h late arrival in Phoenix. The dust model predicted the rapid uptake of dust and high values of dust concentration in the ensuing storm. South of Phoenix, over the closest source regions (~ 25 km), the model PM10 surface dust concentration reached ~ 2500 μg m-3, but underestimated the values measured by the PM10stations within the city. Model results are also validated by the MODIS aerosol optical depth (AOD), employing deep blue (DB) algorithms for aerosol loadings. Model validation included Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO), equipped with the lidar instrument, to disclose the vertical structure of dust aerosols as well as aerosol subtypes. Promising results encourage further research and application of high-resolution modeling and satellite-based remote sensing to warn of approaching severe dust events and reduce risks for safety and health.

Sensitivity of WRF-Chem model to land surface schemes: Assessment in a severe dust outbreak episode in the Central Mediterranean (Apulia Region)

NASA Astrophysics Data System (ADS)

Rizza, Umberto; Miglietta, Mario Marcello; Mangia, Cristina; Ielpo, Pierina; Morichetti, Mauro; Iachini, Chiara; Virgili, Simone; Passerini, Giorgio

2018-03-01

The Weather Research and Forecasting model with online coupled chemistry (WRF-Chem) is applied to simulate a severe Saharan dust outbreak event that took place over Southern Italy in March 2016. Numerical experiments have been performed applying a physics-based dust emission model, with soil properties generated from three different Land Surface Models, namely Noah, RUC and Noah-MP. The model performance in reproducing the severe desert dust outbreak is analysed using an observational dataset of aerosol and desert dust features that includes optical properties from satellite and ground-based sun-photometers, and in-situ particulate matter mass concentration (PM) data. The results reveal that the combination of the dust emission model with the RUC Land Surface Model significantly over-predicts the emitted mineral dust; on the other side, the combination with Noah or Noah-MP Land Surface Model (LSM) gives better results, especially for the daily averaged PM10.

Simulating Mars' Dust Cycle with a Mars General Circulation Model: Effects of Water Ice Cloud Formation on Dust Lifting Strength and Seasonality

NASA Technical Reports Server (NTRS)

Kahre, Melinda A.; Haberle, Robert; Hollingsworth, Jeffery L.

2012-01-01

The dust cycle is critically important for the current climate of Mars. The radiative effects of dust impact the thermal and dynamical state of the atmosphere [1,2,3]. Although dust is present in the Martian atmosphere throughout the year, the level of dustiness varies with season. The atmosphere is generally the dustiest during northern fall and winter and the least dusty during northern spring and summer [4]. Dust particles are lifted into the atmosphere by dust storms that range in size from meters to thousands of kilometers across [5]. Regional storm activity is enhanced before northern winter solstice (Ls200 degrees - 240 degrees), and after northern solstice (Ls305 degrees - 340 degrees ), which produces elevated atmospheric dust loadings during these periods [5,6,7]. These pre- and post- solstice increases in dust loading are thought to be associated with transient eddy activity in the northern hemisphere with cross-equatorial transport of dust leading to enhanced dust lifting in the southern hemisphere [6]. Interactive dust cycle studies with Mars General Circulation Models (MGCMs) have included the lifting, transport, and sedimentation of radiatively active dust. Although the predicted global dust loadings from these simulations capture some aspects of the observed dust cycle, there are marked differences between the simulated and observed dust cycles [8,9,10]. Most notably, the maximum dust loading is robustly predicted by models to occur near northern winter solstice and is due to dust lifting associated with down slope flows on the flanks of the Hellas basin. Thus far, models have had difficulty simulating the observed pre- and post- solstice peaks in dust loading.

Practical Design Guidelines for Fugitive Gas Detection from Unmanned Aerial Vehicles

NASA Astrophysics Data System (ADS)

Tandy, William D., Jr.

Simulation, design, and analysis are combined in this effort to realize a UAV-scale instrument for fugitive gas detection. The contributing material to the industry begins by extending and correlating an integrated Gaussian plume model useful for instrument predictions and trade studies, regardless of the instrument type or molecule of interest. A variety of generally applicable plots are produced from this foundation, including receiver operator curves for leak rate detectability vs. wind speed, beam diameter vs. leak rate detectability, and plots for required scan densities. The atmospheric and instrument parameter trade studies are followed by hardware-specific analyses applicable to differential absorption lidar (DIAL) instruments. A synopsis of the lessons learned from hands-on experiences in the lab further define the design space for DIAL sensors. The dissertation culminates in the detailed design and analysis of two DIAL instrument concepts. The conclusion is that a DIAL instrument capable of reliably detecting a 50 SCFH plume in winds speeds up to 7 mph is on the threshold of being achievable on a quadcopter platform. Of special note is that the effort was funded by a Pipeline and Hazardous Materials Safety Administration grant and performed in collaboration with Ball Aerospace & Technologies.

Trans-Pacific transport of Asian dust: the CESM model analysis and comparison with satellite observations

NASA Astrophysics Data System (ADS)

Wu, M.; Liu, X.; Luo, T.; Wang, Z.; Yang, K.; Wu, C.; Wang, H.; Zhang, K.

2017-12-01

Mineral dust plays an important role in the Earth's climate system due to its effects on radiation budgets, clouds, chemistry and biosphere. However, modeled dust aerosol is not well constrained and large uncertainties exist in modeled dust lifecycles. We evaluate dust spatial distributions in the Community Earth System Model (CESM) with new dust extinction retrievals (Luo et al., 2015a, b) based on the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite (CALIPSO) and CloudSat measurement, with special focus on the Asian dust transport across the Pacific. It is shown that the default CESM underestimates the dust extinction over the Pacific by 1-2 order of magnitude. Especially, the model fails to capture the observed high values of dust extinction occurring from 850 to 500 hPa across the North Pacific (20°N-50°N). Modeled dust optical depth (DOD) decreases faster across the Pacific compared to the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Multi-angle Imaging SpectroRadiometer (MISR) observations. Sensitivity experiments with altered emission, vertical transport and deposition schemes have been conducted to identify the key process impacting dust transport. For that purpose, two new dust emission schemes by Kok et al. (2014a, b) and Ginoux et al. (2001), a new dry deposition scheme by Petroff and Zhang (2010) are implemented to the CESM. In addition, a new unified scheme for convective transport and wet removal of aerosols (Wang et al., 2013) is implemented to the same version of CESM to examine the influence of convective transport and wet deposition on dust transport. It is found that changes in wet scavenging and convective transport can strongly impact dust transport over the Pacific compared to changes in other processes. One of the new emission schemes further decreases the dust extinction across the Pacific. Dust extinction across the Pacific slightly increases when dry deposition velocity for fine particles is reduced.

Quantification of Fugitive Methane Emissions with Spatially Correlated Measurements Collected with Novel Plume Camera

NASA Astrophysics Data System (ADS)

Tsai, Tracy; Rella, Chris; Crosson, Eric

2013-04-01

Quantification of fugitive methane emissions from unconventional natural gas (i.e. shale gas, tight sand gas, etc.) production, processing, and transport is essential for scientists, policy-makers, and the energy industry, because methane has a global warming potential of at least 21 times that of carbon dioxide over a span of 100 years [1]. Therefore, fugitive emissions reduce any environmental benefits to using natural gas instead of traditional fossil fuels [2]. Current measurement techniques involve first locating all the possible leaks and then measuring the emission of each leak. This technique is a painstaking and slow process that cannot be scaled up to the large size of the natural gas industry in which there are at least half a million natural gas wells in the United States alone [3]. An alternative method is to calculate the emission of a plume through dispersion modeling. This method is a scalable approach since all the individual leaks within a natural gas facility can be aggregated into a single plume measurement. However, plume dispersion modeling requires additional knowledge of the distance to the source, atmospheric turbulence, and local topography, and it is a mathematically intensive process. Therefore, there is a need for an instrument capable of simple, rapid, and accurate measurements of fugitive methane emissions on a per well head scale. We will present the "plume camera" instrument, which simultaneously measures methane at different spatial points or pixels. The spatial correlation between methane measurements provides spatial information of the plume, and in addition to the wind measurement collected with a sonic anemometer, the flux can be determined. Unlike the plume dispersion model, this approach does not require knowledge of the distance to the source and atmospheric conditions. Moreover, the instrument can fit inside a standard car such that emission measurements can be performed on a per well head basis. In a controlled experiment with known releases from a methane tank, a 2-pixel plume camera measured 496 ± 160 sccm from a release of 650 sccm located 21 m away, and 4,180 ± 962 sccm from a release of 3,400 sccm located 49 m away. These results in addition to results with a higher-pixel camera will be discussed. Field campaign data collected with the plume camera pixels mounted onto a vehicle and driven through the natural gas fields in the Uintah Basin (Utah, United States) will also be presented along with the limitations and advantages of the instrument. References: 1. S. Solomon, D. Qin, M. Manning, Z. Chen, M. Marquis, K.B. Averyt, M.Tignor and H.L. Miller (eds.). IPCC, 2007: Climate Change 2007: The Physical Science Basis of the Fourth Assessment Report. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA. 2. R.W. Howarth, R. Santoro, and A. Ingraffea. "Methane and the greenhouse-gas footprint of natural gas from shale formations." Climate Change, 106, 679 (2011). 3. U.S. Energy Information Administration. "Number of Producing Wells." . Accessed 6 January 2013.

Identification of Dust Source Regions at High-Resolution and Dynamics of Dust Source Mask over Southwest United States Using Remote Sensing Data

NASA Astrophysics Data System (ADS)

Sprigg, W. A.; Sahoo, S.; Prasad, A. K.; Venkatesh, A. S.; Vukovic, A.; Nickovic, S.

2015-12-01

Identification and evaluation of sources of aeolian mineral dust is a critical task in the simulation of dust. Recently, time series of space based multi-sensor satellite images have been used to identify and monitor changes in the land surface characteristics. Modeling of windblown dust requires precise delineation of mineral dust source and its strength that varies over a region as well as seasonal and inter-annual variability due to changes in land use and land cover. Southwest USA is one of the major dust emission prone zone in North American continent where dust is generated from low lying dried-up areas with bare ground surface and they may be scattered or appear as point sources on high resolution satellite images. In the current research, various satellite derived variables have been integrated to produce a high-resolution dust source mask, at grid size of 250 m, using data such as digital elevation model, surface reflectance, vegetation cover, land cover class, and surface wetness. Previous dust source models have been adopted to produce a multi-parameter dust source mask using data from satellites such as Terra (Moderate Resolution Imaging Spectroradiometer - MODIS), and Landsat. The dust source mask model captures the topographically low regions with bare soil surface, dried-up river plains, and lakes which form important source of dust in southwest USA. The study region is also one of the hottest regions of USA where surface dryness, land use (agricultural use), and vegetation cover changes significantly leading to major changes in the areal coverage of potential dust source regions. A dynamic high resolution dust source mask have been produced to address intra-annual change in the aerial extent of bare dry surfaces. Time series of satellite derived data have been used to create dynamic dust source masks. A new dust source mask at 16 day interval allows enhanced detection of potential dust source regions that can be employed in the dust emission and transport pathways models for better estimation of emission of dust during dust storms, particulate air pollution, public health risk assessment tools and decision support systems.

Probing Dust Formation Around Evolved Stars with Near-Infrared Interferometry

NASA Astrophysics Data System (ADS)

Sargent, B.; Srinivasan, S.; Riebel, D.; Meixner, M.

2014-09-01

Near-infrared interferometry holds great promise for advancing our understanding of the formation of dust around evolved stars. For example, the Magdalena Ridge Observatory Interferometer (MROI), which will be an optical/near-infrared interferometer with down to submilliarcsecond resolution, includes studying stellar mass loss as being of interest to its Key Science Mission. With facilities like MROI, many questions relating to the formation of dust around evolved stars may be probed. How close to an evolved star such as an asymptotic giant branch (AGB) or red supergiant (RSG) star does a dust grain form? Over what temperature ranges will such dust form? How does dust formation temperature and distance from star change as a function of the dust composition (carbonaceous versus oxygen-rich)? What are the ranges of evolved star dust shell geometries, and does dust shell geometry for AGB and RSG stars correlate with dust composition, similar to the correlation seen for planetary nebula outflows? At what point does the AGB star become a post-AGB star, when dust formation ends and the dust shell detaches? Currently we are conducting studies of evolved star mass loss in the Large Magellanic Cloud using photometry from the Surveying the Agents of a Galaxy's Evolution (SAGE; PI: M. Meixner) Spitzer Space Telescope Legacy program. We model this mass loss using the radiative transfer program 2Dust to create our Grid of Red supergiant and Asymptotic giant branch ModelS (GRAMS). For simplicity, we assume spherical symmetry, but 2Dust does have the capability to model axisymmetric, non-spherically-symmetric dust shell geometries. 2Dust can also generate images of models at specified wavelengths. We discuss possible connections of our GRAMS modeling using 2Dust of SAGE data of evolved stars in the LMC and also other data on evolved stars in the Milky Way's Galactic Bulge to near-infrared interferometric studies of such stars. By understanding the origins of dust around evolved stars, we may learn more about the later parts of the life of stardust; e.g., its residence in the interstellar medium, its time spent in molecular clouds, and its inclusion into solid bodies in future planetary systems.

Model of Image Artifacts from Dust Particles

NASA Technical Reports Server (NTRS)

Willson, Reg

2008-01-01

A mathematical model of image artifacts produced by dust particles on lenses has been derived. Machine-vision systems often have to work with camera lenses that become dusty during use. Dust particles on the front surface of a lens produce image artifacts that can potentially affect the performance of a machine-vision algorithm. The present model satisfies a need for a means of synthesizing dust image artifacts for testing machine-vision algorithms for robustness (or the lack thereof) in the presence of dust on lenses. A dust particle can absorb light or scatter light out of some pixels, thereby giving rise to a dark dust artifact. It can also scatter light into other pixels, thereby giving rise to a bright dust artifact. For the sake of simplicity, this model deals only with dark dust artifacts. The model effectively represents dark dust artifacts as an attenuation image consisting of an array of diffuse darkened spots centered at image locations corresponding to the locations of dust particles. The dust artifacts are computationally incorporated into a given test image by simply multiplying the brightness value of each pixel by a transmission factor that incorporates the factor of attenuation, by dust particles, of the light incident on that pixel. With respect to computation of the attenuation and transmission factors, the model is based on a first-order geometric (ray)-optics treatment of the shadows cast by dust particles on the image detector. In this model, the light collected by a pixel is deemed to be confined to a pair of cones defined by the location of the pixel s image in object space, the entrance pupil of the lens, and the location of the pixel in the image plane (see Figure 1). For simplicity, it is assumed that the size of a dust particle is somewhat less than the diameter, at the front surface of the lens, of any collection cone containing all or part of that dust particle. Under this assumption, the shape of any individual dust particle artifact is the shape (typically, circular) of the aperture, and the contribution of the particle to the attenuation factor for a given pixel is the fraction of the cross-sectional area of the collection cone occupied by the particle. Assuming that dust particles do not overlap, the net transmission factor for a given pixel is calculated as one minus the sum of attenuation factors contributed by all dust particles affecting that pixel. In a test, the model was used to synthesize attenuation images for random distributions of dust particles on the front surface of a lens at various relative aperture (F-number) settings. As shown in Figure 2, the attenuation images resembled dust artifacts in real test images recorded while the lens was aimed at a white target.

Implementation of the fugitive emissions system program: The OxyChem experience

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deshmukh, A.

An overview is provided for the Fugitive Emissions System (FES) that has been implemented at Occidental Chemical in conjunction with the computer-based maintenance system called PassPort{reg_sign} developed by Indus Corporation. The goal of PassPort{reg_sign} FES program has been to interface with facilities data, equipment information, work standards and work orders. Along the way, several implementation hurdles had to be overcome before a monitoring and regulatory system could be standardized for the appropriate maintenance, process and environmental groups. This presentation includes step-by-step account of several case studies that developed during the implementation of the FES system.

A Mobile Sensing Approach for Regional Surveillance of Fugitive Methane Emissions in Oil and Gas Production.

PubMed

Albertson, John D; Harvey, Tierney; Foderaro, Greg; Zhu, Pingping; Zhou, Xiaochi; Ferrari, Silvia; Amin, M Shahrooz; Modrak, Mark; Brantley, Halley; Thoma, Eben D

2016-03-01

This paper addresses the need for surveillance of fugitive methane emissions over broad geographical regions. Most existing techniques suffer from being either extensive (but qualitative) or quantitative (but intensive with poor scalability). A total of two novel advancements are made here. First, a recursive Bayesian method is presented for probabilistically characterizing fugitive point-sources from mobile sensor data. This approach is made possible by a new cross-plume integrated dispersion formulation that overcomes much of the need for time-averaging concentration data. The method is tested here against a limited data set of controlled methane release and shown to perform well. We then present an information-theoretic approach to plan the paths of the sensor-equipped vehicle, where the path is chosen so as to maximize expected reduction in integrated target source rate uncertainty in the region, subject to given starting and ending positions and prevailing meteorological conditions. The information-driven sensor path planning algorithm is tested and shown to provide robust results across a wide range of conditions. An overall system concept is presented for optionally piggybacking of these techniques onto normal industry maintenance operations using sensor-equipped work trucks.

Localization and Quantification of Trace-gas Fugitive Emissions Using a Portable Optical Spectrometer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Eric; Teng, Chu; van Kessel, Theodore

We present a portable optical spectrometer for fugitive emissions monitoring of methane (CH4). The sensor operation is based on tunable diode laser absorption spectroscopy (TDLAS), using a 5 cm open path design, and targets the 2ν3 R(4) CH4 transition at 6057.1 cm-1 (1651 nm) to avoid cross-talk with common interfering atmospheric constituents. Sensitivity analysis indicates a normalized precision of 2.0 ppmv∙Hz-1/2, corresponding to a noise-equivalent absorption (NEA) of 4.4×10-6 Hz-1/2 and minimum detectible absorption (MDA) coefficient of αmin = 8.8×10-7 cm-1∙Hz-1/2. Our TDLAS sensor is deployed at the Methane Emissions Technology Evaluation Center (METEC) at Colorado State University (CSU) formore » initial demonstration of single-sensor based source localization and quantification of CH4 fugitive emissions. The TDLAS sensor is concurrently deployed with a customized chemi-resistive metal-oxide (MOX) sensor for accuracy benchmarking, demonstrating good visual correlation of the concentration time-series. Initial angle-of-arrival (AOA) results will be shown, and development towards source magnitude estimation will be described.« less

Vendors unveil one-step fugitive emissions monitoring, management

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walter, M.

1995-04-01

An alliance of manufacturers has developed a ``single-source solution`` for fugitive emissions monitoring. The LeakTracker{trademark} system combines barcode scans, and vapor detection and data collection capabilities to help companies comply with leak detection and repair requirements as mandated by the Environmental Protection Agency`s Method 21 guidelines. LeakTracker doubles productivity and helps eliminate human-error factors associated with fugitive emissions monitoring. Two-person teams, clipboard-and-pencil data entry, and manual data transcription are eliminated. By automating the process and integrating all components, a technician can monitor 500 points daily following Method 21 guidelines, compared to about 250 readings per day using other systems. LeakTrackermore » includes a handheld workstation, sampling probe and laser-scan barcode reader that fit in a vest worn by a field technician. The technician points the workstation toward a barcode tag and pulls the trigger, which initiates a barcode read and automatically records the time, date and location. While the detachable probe ``sniffs`` for emissions, an analyzer interface module converts the gas detection signal from analog to digital format, allowing data to be recorded by the workstation. LeakTracker has an accuracy rate of 1 part per million.« less

Signs of Recent Volcanism and Hydrothermal Activity Along the Eastern Segment of the Galapagos Spreading Center

NASA Astrophysics Data System (ADS)

Raineault, N.; Smart, C.; Mayer, L. A.; Ballard, R. D.; Fisher, C. R.; Marsh, L.; Shank, T. M.

2016-12-01

Since the initial discovery of the Galápagos Spreading Center (GSC) vents in 1977, large-scale disturbances resulting from eruptive and tectonic activity have both destroyed and created vent habitats along the GSC. In 2015, the E/V Nautilus returned to the GSC with remotely operated vehicles (ROVs) to explore 17 kilometers of the rift valley from the Rosebud site in the west, to a previously unexplored temperature anomaly east of the Tempus Fugit vent site. In the years to over a decade since scientists last visited the Rosebud, Rose Garden, and Tempus Fugit sites, there were many changes. Most notably, the Rosebud site, where scientists found a nascent vent community and left site markers in 2002, was apparently covered with glassy basaltic sheet flows. In addition to visual exploration, oceanographic sensor measurements and direct sampling, we used the ROV Hercules imaging suite, comprised of stereo cameras and a structured light laser sensor to map an area of diffuse flow in the Tempus Fugit field (100 m x 150 m). The centimeter-level photographic and bathymetric maps created with this system, along with ROV HD video, samples, and environmental sensors, documented hydrothermal activity and changes in biological community structure (e.g., Riftia tubeworms observed in nascent stages of community development in 2011 were now, in 2015, in greater abundance (with tubes almost 4 m in length). The detection of active venting and associated faunal assemblages will provide insight into the temporal and spatial variability of venting activity at the Tempus Fugit site. On a visual survey of the Rift east of the Tempus Fugit site, extinct sulfide chimney structures were discovered and sampled. There were several chimneys and sulfide deposits in a span of over 8 km that ranged in height from over a half meter to 1.5 m tall. Diffuse flow hosting white and blue bacterial mats was observed near the chimneys complexes. The base of a large chimney structure, venting white fluids, as well as adjacent chemically-stained sediments supported vent-endemic fauna including the Pompeii worm (Alvinella pompejana) and other polychaete worms, along with pycnogonids, rat-tail fish, and galatheid crabs. This discovery provided the first evidence that the eastern segment of the GSC may have contained high-temperature, black smoker vents.

Initial results of detected methane emissions from landfills in the Los Angeles Basin during the COMEX campaign by the Methane Airborne MAPper (MAMAP) instrument and a greenhouse gas in-situ analyser

NASA Astrophysics Data System (ADS)

Krautwurst, Sven; Gerilowski, Konstantin; Kolyer, Richard; Jonsson, Haflidi; Krings, Thomas; Horstjann, Markus; Leifer, Ira; Vigil, Sam; Buchwitz, Michael; Schüttemeyer, Dirk; Fladeland, Matthew M.; Burrows, John P.; Bovensmann, Heinrich

2015-04-01

Methane (CH4) is the second most important anthropogenic greenhouse gas beside carbon dioxide (CO2). Significant contributors to the global methane budget are fugitive emissions from landfills. Due to the growing world population, it is expected that the amount of waste and, therefore, waste disposal sites will increase in number and size in parts of the world, often adjacent growing megacities. Besides bottom-up modelling, a variety of ground based methods (e.g., flux chambers, trace gases, radial plume mapping, etc.) have been used to estimate (top-down) these fugitive emissions. Because landfills usually are large, sometimes with significant topographic relief, vary temporally, and leak/emit heterogeneously across their surface area, assessing total emission strength by ground-based techniques is often difficult. In this work, we show how airborne based remote sensing measurements of the column-averaged dry air mole fraction of CH4 can be utilized to estimate fugitive emissions from landfills in an urban environment by a mass balance approach. Subsequently, these emission rates are compared to airborne in-situ horizontal cross section measurements of CH4 taken within the planetary boundary layer (PBL) upwind and downwind of the landfill at different altitudes immediately after the remote sensing measurements were finished. Additional necessary parameters (e.g., wind direction, wind speed, aerosols, dew point temperature, etc.) for the data inversion are provided by a standard instrumentation suite for atmospheric measurements aboard the aircraft, and nearby ground-based weather stations. These measurements were part of the CO2 and Methane EXperiment (COMEX), which was executed during the summer 2014 in California and was co-funded by the European Space Agency (ESA) and the National Aeronautics and Space Administration (NASA). The remote sensing measurements were taken by the Methane Airborne MAPper (MAMAP) developed and operated by the University of Bremen and the German Research Center for Geoscience (GFZ) in Potsdam. The in-situ measurements were obtained by a greenhouse gas (GHG) in-situ analyser operated by NASA's Ames Research Center (ARC). Both instruments were installed aboard a DHC-6 Twin Otter aircraft operated by the Center for Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS). Initial results - including estimated fugitive emission rates - will be presented for the landfill Olinda Alpha in Brea, Orange County, Los Angeles Basin, California, which was overflown on four different days during the COMEX field campaign in late summer 2014.

Sources, Sinks, and Transatlantic Transport of North African Dust Aerosol: A Multimodel Analysis and Comparison With Remote Sensing Data

NASA Technical Reports Server (NTRS)

Kim, Dongchul; Chin, Mian; Yu, Hongbin; Diehl, Thomas; Tan, Qian; Kahn, Ralph A.; Tsigaridis, Kostas; Bauer, Susanne E.; Takemura, Toshihiko; Pozzoli, Luca;

Simulation of a dust episode over Eastern Mediterranean using a high-resolution atmospheric chemistry general circulation model

NASA Astrophysics Data System (ADS)

Abdel Kader, Mohamed; Zittis, Georgios; Astitha, Marina; Lelieveld, Jos; Tymvios, Fillipos

2013-04-01

An extended episode of low visibility took place over the Eastern Mediterranean in late September 2011, caused by a strong increase in dust concentrations, analyzed from observations of PM10 (Particulate Matter with <10μm in diameter). A high-resolution version of the atmospheric chemistry general circulation model EMAC (ECHAM5/Messy2.41 Atmospheric Chemistry) was used to simulate the emissions, transport and deposition of airborne desert dust. The model configuration involves the spectral resolution of T255 (0.5°, ~50Km) and 31 vertical levels in the troposphere and lower stratosphere. The model was nudged towards ERA40 reanalysis data to represent the actual meteorological conditions. The dust emissions were calculated online at each model time step and the aerosol microphysics using the GMXe submodel (Global Modal-aerosol eXtension). The model includes a sulphur chemistry mechanism to simulate the transformation of the dust particles from the insoluble (at emission) to soluble modes, which promotes dust removal by precipitation. The model successfully reproduces the dust distribution according to observations by the MODIS satellite instruments and ground-based AERONET stations. The PM10 concentration is also compared with in-situ measurements over Cyprus, resulting in good agreement. The model results show two subsequent dust events originating from the Negev and Sahara deserts. The first dust event resulted from the transport of dust from the Sahara on the 21st of September and lasted only briefly (hours) as the dust particles were efficiently removed by precipitation simulated by the model and observed by the TRMM (Tropical Rainfall Measuring Mission) satellites. The second event resulted from dust transport from the Negev desert to the Eastern Mediterranean during the period 26th - 30th September with a peak concentration at 2500m elevation. This event lasted for four days and diminished due to dry deposition. The observed reduced visibility over Cyprus resulted from the sedimentation of dust originating from the Negev, followed by dry deposition at the surface. The dust particles were both pristine and polluted (sulphate coated), and we evaluate the role of mixing in the duration and extent of the episodes.

A Model Connecting Galaxy Masses, Star Formation Rates, and Dust Temperatures across Cosmic Time

NASA Astrophysics Data System (ADS)

Imara, Nia; Loeb, Abraham; Johnson, Benjamin D.; Conroy, Charlie; Behroozi, Peter

2018-02-01

We investigate the evolution of dust content in galaxies from redshifts z = 0 to z = 9.5. Using empirically motivated prescriptions, we model galactic-scale properties—including halo mass, stellar mass, star formation rate, gas mass, and metallicity—to make predictions for the galactic evolution of dust mass and dust temperature in main-sequence galaxies. Our simple analytic model, which predicts that galaxies in the early universe had greater quantities of dust than their low-redshift counterparts, does a good job of reproducing observed trends between galaxy dust and stellar mass out to z ≈ 6. We find that for fixed galaxy stellar mass, the dust temperature increases from z = 0 to z = 6. Our model forecasts a population of low-mass, high-redshift galaxies with interstellar dust as hot as, or hotter than, their more massive counterparts; but this prediction needs to be constrained by observations. Finally, we make predictions for observing 1.1 mm flux density arising from interstellar dust emission with the Atacama Large Millimeter Array.

Development of a high resolution interstellar dust engineering model - overview of the project

NASA Astrophysics Data System (ADS)

Sterken, V. J.; Strub, P.; Soja, R. H.; Srama, R.; Krüger, H.; Grün, E.

2013-09-01

Beyond 3 AU heliocentric distance, the flow of interstellar dust through the solar system is a dominant component of the total dust population. The modulation of this flux with the solar cycle and the position in the solar system has been predicted by theoretical studies since the seventies. The modulation was proven to exist by matching dust trajectory simulations with real spacecraft data from Ulysses in 1998. The modulations were further analyzed and studies in detail in 2012. The current ESA interplanetary meteoroid model IMEM includes an interstellar dust component, but this component was modelled only with straight line trajectories through the solar system. For the new ESA IMEX model, a high-resolution interstellar dust component is implemented separately from a dust streams module. The dust streams module focuses on dust in streams that was released from comets (cf. Abstract R. Soja). Parallel processing techniques are used to improve computation time (cf. Abstract P. Strub). The goal is to make predictions for the interstellar dust flux as close to the Sun as 1 AU or closer, for future space mission design.

Eulerian-Lagrangian CFD modelling of pesticide dust emissions from maize planters

NASA Astrophysics Data System (ADS)

Devarrewaere, Wouter; Foqué, Dieter; Nicolai, Bart; Nuyttens, David; Verboven, Pieter

2018-07-01

An Eulerian-Lagrangian 3D computational fluid dynamics (CFD) model of pesticide dust drift from precision vacuum planters in field conditions was developed. Tractor and planter models were positioned in an atmospheric computational domain, representing the field and its edges. Physicochemical properties of dust abraded from maize seeds (particle size, shape, porosity, density, a.i. content), dust emission rates and exhaust air velocity values at the planter fan outlets were measured experimentally and implemented in the model. The wind profile, the airflow pattern around the machines and the dust dispersion were computed. Various maize sowing scenarios with different wind conditions, dust properties, planter designs and vacuum pressures were simulated. Dust particle trajectories were calculated by means of Lagrangian particle tracking, considering nonspherical particle drag, gravity and turbulent dispersion. The dust dispersion model was previously validated with wind tunnel data. In this study, simulated pesticide concentrations in the air and on the soil in the different sowing scenarios were compared and discussed. The model predictions were similar to experimental literature data in terms of concentrations and drift distance. Pesticide exposure levels to bees during flight and foraging were estimated from the simulated concentrations. The proposed CFD model can be used in risk assessment studies and in the evaluation of dust drift mitigation measures.

Constraining the Dust Opacity Law in Three Small and Isolated Molecular Clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Webb, K. A.; Thanjavur, K.; Di Francesco, J.

Density profiles of isolated cores derived from thermal dust continuum emission rely on models of dust properties, such as mass opacity, that are poorly constrained. With complementary measures from near-infrared extinction maps, we can assess the reliability of commonly used dust models. In this work, we compare Herschel -derived maps of the optical depth with equivalent maps derived from CFHT WIRCAM near-infrared observations for three isolated cores: CB 68, L 429, and L 1552. We assess the dust opacities provided from four models: OH1a, OH5a, Orm1, and Orm4. Although the consistency of the models differs between the three sources, themore » results suggest that the optical properties of dust in the envelopes of the cores are best described by either silicate and bare graphite grains (e.g., Orm1) or carbonaceous grains with some coagulation and either thin or no ice mantles (e.g., OH5a). None of the models, however, individually produced the most consistent optical depth maps for every source. The results suggest that either the dust in the cores is not well-described by any one dust property model, the application of the dust models cannot be extended beyond the very center of the cores, or more complex SED fitting functions are necessary.« less

Dust storm events over Delhi: verification of dust AOD forecasts with satellite and surface observations

NASA Astrophysics Data System (ADS)

Singh, Aditi; Iyengar, Gopal R.; George, John P.

2016-05-01

Thar desert located in northwest part of India is considered as one of the major dust source. Dust storms originate in Thar desert during pre-monsoon season, affects large part of Indo-Gangetic plains. High dust loading causes the deterioration of the ambient air quality and degradation in visibility. Present study focuses on the identification of dust events and verification of the forecast of dust events over Delhi and western part of IG Plains, during the pre-monsoon season of 2015. Three dust events have been identified over Delhi during the study period. For all the selected days, Terra-MODIS AOD at 550 nm are found close to 1.0, while AURA-OMI AI shows high values. Dust AOD forecasts from NCMRWF Unified Model (NCUM) for the three selected dust events are verified against satellite (MODIS) and ground based observations (AERONET). Comparison of observed AODs at 550 nm from MODIS with NCUM predicted AODs reveals that NCUM is able to predict the spatial and temporal distribution of dust AOD, in these cases. Good correlation (~0.67) is obtained between the NCUM predicted dust AODs and location specific observations available from AERONET. Model under-predicted the AODs as compared to the AERONET observations. This may be mainly because the model account for only dust and no anthropogenic activities are considered. The results of the present study emphasize the requirement of more realistic representation of local dust emission in the model both of natural and anthropogenic origin, to improve the forecast of dust from NCUM during the dust events.

A new model for Mars atmospheric dust based upon analysis of ultraviolet through infrared observations from Mariner 9, Viking, and Phobos

NASA Technical Reports Server (NTRS)

Clancy, R. T.; Lee, S. W.; Gladstone, G. R.; McMillan, W. W.; Rousch, T.

1995-01-01

We propose key modifications to the Toon et al. (1977) model of the particle size distribution and composition of Mars atmospheric dust, based on a variety of spacecraft and wavelength observations of the dust. A much broader (r(sub eff)variance-0.8 micron), smaller particle size (r(sub mode)-0.02 microns) distribution coupled with a "palagonite-like" composition is argued to fit the complete ultraviolet-to-30-micron absorption properties of the dust better than the montmorillonite-basalt r(sub eff)variance= 0.4 micron, r(sub mode)= 0.40 micron dust model of Toon et al. Mariner 9 (infrared interferometer spectrometer) IRIS spectra of high atmospheric dust opacities during the 1971 - 1972 Mars global dust storm are analyzed in terms of the Toon et al. dust model, and a Hawaiian palagonite sample with two different size distribution models incorporating smaller dust particle sizes. Viking Infrared Thermal Mapper (IRTM) emission-phase-function (EPF) observations at 9 microns are analyzed to retrieve 9-micron dust opacities coincident with solar band dust opacities obtained from the same EPF sequences. These EPF dust opacities provide an independent measurement of the visible/9-microns extinction opacity ratio (> or equal to 2) for Mars atmospheric dust, which is consistent with a previous measurement by Martin (1986). Model values for the visible/9-microns opacity ratio and the ultraviolet and visible single-scattering albedos are calculated for the palagonite model with the smaller particle size distributions and compared to the same properties for the Toon et al. model of dust. The montmorillonite model of the dust is found to fit the detailed shape of the dust 9-micron absorption well. However, it predicts structured, deep absorptions at 20 microns which are not observed and requires a separate ultraviolet-visible absorbing component to match the observed behavior of the dust in this wavelength region. The modeled palagonite does not match the 8- to 9-micron absorption presented by the dust in the IRIS spectra, probably due to its low SiO2 content (31%). However, it does provide consistent levels of ultraviolet/visible absorption, 9- to 12-micron absorption, and a lack of structured absorption at 20 microns. The ratios of dust extinction opacities at visible, 9 microns, and 30 microns are strongly affected by the dust particle size distribution. The Toon et al. dust size distribution (r(sub mode)= 0.40, r(sub eff)variance= 0.4 microns, r(sub cw mu)= 2.7 microns) predicts the correct ratio of the 9- to 30-micron opacity, but underpredicts the visible/9-micron opacity ratio considerably (1 versus > or equal to 2). A similar particle distribution width with smaller particle sizes (r(sub mode)= 0.17, r(sub eff)variance= 0.4 microns, r(sub cw mu)=1.2 microns) will fit the observed visible/9-micron opacity ratio, but overpredicts the observed 9-micron/30-micron opacity ratio. A smaller and much broader particle size distribution (r(sub mode)= 0.02, r(sub eff)variance= 0.8 microns, r(sub cw mu)= 1.8 microns) can fit both dust opacity ratios. Overall, the nanocrystalline structure of palagonite coupled with a smaller, broader distribution of dust particle sizes provides a more consistent fit than the Toon et al. model of the dust to the IRIS spectra, the observed visible/9-micron dust opacity ratio, the Phobos occultation measurements of dust particle sizes, and the weakness of surface near IR absorptions expected for clay minerals.

A new model for Mars atmospheric dust based upon analysis of ultraviolet through infrared observations from Mariner 9, Viking, and Phobos

NASA Technical Reports Server (NTRS)

Clancy, R. T.; Lee, S. W.; Gladstone, G. R.; Mcmillan, W. W.; Rousch, T.

1995-01-01

We propose key modifications to the Toon et al. (1977) model of the particle size distribution and composition of Mars atmospheric dust, based on a variety of spacecraft and wavelength observations of the dust. A much broader (r(sub eff) variance approximately 0.8 micrometers), smaller particle size (r(sub mode) approximately 0.02 micrometers) distribution coupled with a 'palagonite-like' composition is argued to fit the complete ultraviolet-to-30-micrometer absorption properties of the dust better than the montmorillonite-basalt, r(sub eff) variance = 0.4 micrometers, r(sub mode) = 0.40 dust model of Toon et al. Mariner 9 (infrared interferometer spectrometer) IRIS spectra of high atmospheric dust opacities during the 1971-1972 Mars global dust storm are analyzed in terms of the Toon et al. dust model, and a Hawaiian palagonite sample (Rousch et al., 1991) with two different size distribution models incorporating smaller dust particle sizes. Viking Infrared Thermal Mapper (IRTM) emmission-phase-function (EPF) observations at 9 micrometers are analyzed to retrieve 9-micrometer dust opacities coincident with solar band dust opacities obtained from the same EPF sequences (Clancy and Lee, 1991). These EPF dust opacities provide an independent measurement of the visible/9-micrometer extinction opacity ratio (greater than or = 2) for Mars atmospheric dust, which is consistent with a previous measurement by Martin (1986). Model values for the visible/9-micrometer opacity ratio and the ultraviolet and visible single-scattering albedos are calculated for the palagonite model with the smaller particle size distributions compared to the same properties for the Toon et al. model of dust. The montmorillonite model of the dust is found to fit the detailed shape of the dust 9-micrometer absorption well. However, it predicts structured, deep aborptions at 20 micrometers which are not observed and requires a separate ultraviolet-visible absorbing component to match the observed behavior of the dust in this wavelength region. The modeled palagonite does not match the 8-to 9-micrometer absorption presented by the dust in the IRIS spectra, probably due to its low SiO2 content (31%). However, it does provide consistent levels of ultraviolet/visible absorption, 9-to 12-micrometer absorption, and a lack of structured absorption at 20 micrometers. The ratios of dust extinction opacities at visible, 9 micrometers, and 30 micrometers are strongly affected by the dust particle size distribution. The Toon et al. dust size distribution (r(sub mode) = 0.40,r(sub eff) variance = 0.4 micrometers, r(sub cwmu) = 2.7 micrometers) predicts the correct ratio of the 9- to 30-micrometer opacity, but underpredicts the visible/9-micrometer opacity ratio considerably (1 versus greater than or = 2). A similar particle distribution width with smaller particle sizes (r(sub mode) = 0.17, r(sub eff) variance = 0.4 micrometers, r(sub cwmu) = 1.2 micrometers) will fit the observed visible/9-micrometer opacity ratio, but overpredicts the observed 9-micrometer/30-micrometer opacity ratio. A smaller and much broader particle size distribution (r(sub mode) = 0.002, r(sub eff) variance = 0.8 micrometers, r(sub cwmu) = 1.8 micrometers) can fit both dust opacity ratios. Overall, the nanocrystalline structure of palagonite coupled with a smaller, broader distribution of dust particle sizes provides a more consistent fit than the Toon et al. model of the dust to the IRIS spectra, the observed visible/9-micrometer dust opacity ratio, the Phobos occulation measurements of the dust particle sizes (Chassefiere et al., 1992), and the weakness of surface near IR absorptions expected for clay minerals (Clark, 1992; Bell and Crisp, 1993).

Evaluation of a Mineral Dust Simulation in the Atmospheric-Chemistry General Circulation Model-EMAC

NASA Astrophysics Data System (ADS)

Abdel Kader, M.; Astitha, M.; Lelieveld, J.

2012-04-01

This study presents an evaluation of the atmospheric mineral dust cycle in the Atmospheric Chemistry General Circulation Model (AC-GCM) using new developed dust emissions scheme. The dust cycle, as an integral part of the Earth System, plays an important role in the Earth's energy balance by both direct and indirect ways. As an aerosol, it significantly impacts the absorption and scattering of radiation in the atmosphere and can modify the optical properties of clouds and snow/ice surfaces. In addition, dust contributes to a range of physical, chemical and bio-geological processes that interact with the cycles of carbon and water. While our knowledge of the dust cycle, its impacts and interactions with the other global-scale bio-geochemical cycles has greatly advanced in the last decades, large uncertainties and knowledge gaps still exist. Improving the dust simulation in global models is essential to minimize the uncertainties in the model results related to dust. In this study, the results are based on the ECHAM5 Modular Earth Submodel System (MESSy) AC-GCM simulations using T106L31 spectral resolution (about 120km ) with 31 vertical levels. The GMXe aerosol submodel is used to simulate the phase changes of the dust particles between soluble and insoluble modes. Dust emission, transport and deposition (wet and dry) are calculated on-line along with the meteorological parameters in every model time step. The preliminary evaluation of the dust concentration and deposition are presented based on ground observations from various campaigns as well as the evaluation of the optical properties of dust using AERONET and satellite (MODIS and MISR) observations. Preliminarily results show good agreement with observations for dust deposition and optical properties. In addition, the global dust emissions, load, deposition and lifetime is in good agreement with the published results. Also, the uncertainties in the dust cycle that contribute to the overall model performance will be briefly discussed as it is a subject of future work.

The Importance of Physical Models for Deriving Dust Masses and Grain Size Distributions in Supernova Ejecta. I. Radiatively Heated Dust in the Crab Nebula

NASA Technical Reports Server (NTRS)

Temim, Tea; Dwek, Eli

2013-01-01

Recent far-infrared (IR) observations of supernova remnants (SNRs) have revealed significantly large amounts of newly condensed dust in their ejecta, comparable to the total mass of available refractory elements. The dust masses derived from these observations assume that all the grains of a given species radiate at the same temperature, regardless of the dust heating mechanism or grain radius. In this paper, we derive the dust mass in the ejecta of the Crab Nebula, using a physical model for the heating and radiation from the dust. We adopt a power-law distribution of grain sizes and two different dust compositions (silicates and amorphous carbon), and calculate the heating rate of each dust grain by the radiation from the pulsar wind nebula. We find that the grains attain a continuous range of temperatures, depending on their size and composition. The total mass derived from the best-fit models to the observed IR spectrum is 0.019-0.13 Solar Mass, depending on the assumed grain composition. We find that the power-law size distribution of dust grains is characterized by a power-law index of 3.5-4.0 and a maximum grain size larger than 0.1 micron. The grain sizes and composition are consistent with what is expected for dust grains formed in a Type IIP supernova (SN). Our derived dust mass is at least a factor of two less than the mass reported in previous studies of the Crab Nebula that assumed more simplified two-temperature models. These models also require a larger mass of refractory elements to be locked up in dust than was likely available in the ejecta. The results of this study show that a physical model resulting in a realistic distribution of dust temperatures can constrain the dust properties and affect the derived dust masses. Our study may also have important implications for deriving grain properties and mass estimates in other SNRs and for the ultimate question of whether SNe are major sources of dust in the Galactic interstellar medium and in external galaxies.

Testing the sensitivity of past climates to the indirect effects of dust

NASA Astrophysics Data System (ADS)

Sagoo, Navjit; Storelvmo, Trude

2017-06-01

Mineral dust particles are important ice nuclei (IN) and as such indirectly impact Earth's radiative balance via the properties of cold clouds. Using the Community Earth System Model version 1.0.6, and Community Atmosphere Model version 5.1, and a new empirical parameterization for ice nucleation on dust particles, we investigate the radiative forcing induced by dust IN for different dust loadings. Dust emissions are representative of global conditions for the Last Glacial Maximum and the mid-Pliocene Warm Period. Increased dust leads to smaller and more numerous ice crystals in mixed phase clouds, impacting cloud opacity, lifetime, and precipitation. This increases the shortwave cloud radiative forcing, resulting in significant surface temperature cooling and polar amplification—which is underestimated in existing studies relative to paleoclimate archives. Large hydrological changes occur and are linked to an enhanced dynamical response. We conclude that dust indirect effects could potentially have a significant impact on the model-data mismatch that exists for paleoclimates.