Sample records for ga detrital zircons

  1. Early Paleozoic tectonic reconstruction of Iran: Tales from detrital zircon geochronology

    NASA Astrophysics Data System (ADS)

    Moghadam, Hadi Shafaii; Li, Xian-Hua; Griffin, William L.; Stern, Robert J.; Thomsen, Tonny B.; Meinhold, Guido; Aharipour, Reza; O'Reilly, Suzanne Y.

    2017-01-01

    In this study we use detrital zircons to probe the Early Paleozoic history of NE Iran and evaluate the link between sediment sources and Gondwanan pre-Cadomian, Cadomian and younger events. U-Pb zircon ages and Hf isotopic compositions are reported for detrital zircons from Ordovician and Early Devonian sedimentary rocks from NE Iran. These clastic rocks are dominated by zircons with major age populations at 2.5 Ga, 0.8-0.6 Ga, 0.5 Ga and 0.5-0.4 Ga as well as a minor broad peak at 1.0 Ga. The source of 2.5 Ga detrital zircons is enigmatic; they may have been supplied from the Saharan Metacraton (or West African Craton) to the southwest or Afghanistan-Tarim to the east. The detrital zircons with age populations at 0.8-0.6 Ga probably originated from Cryogenian-Ediacaran juvenile igneous rocks of the Arabian-Nubian Shield; this inference is supported by their juvenile Hf isotopes, although some negative εHf (t) values suggest that other sources (such as the West African Craton) were also involved. The age peak at ca 0.5 Ga correlates with Cadomian magmatism reported from Iranian basement and elsewhere in north Gondwana. The variable εHf (t) values of Cadomian detrital zircons, resembling the εHf (t) values of zircons in magmatic Cadomian rocks from Iran and Taurides (Turkey), suggest an Andean-type margin and the involvement of reworked older crust in the generation of the magmatic rocks. The youngest age population at 0.5-0.4 Ga is interpreted to represent Gondwana rifting and the opening of Paleotethys, which probably started in Late Cambrian-Ordovician time. A combination of U-Pb dating and Hf-isotope data from Iran, Turkey and North Gondwana confirms that Iran and Turkey were parts of Gondwana at least until late Paleozoic time.

  2. Zircon U-Pb ages and Hf isotopic compositions indicate multiple sources for Grenvillian detrital zircon deposited in western Laurentia

    NASA Astrophysics Data System (ADS)

    Howard, Amanda L.; Farmer, G. Lang; Amato, Jeffrey M.; Fedo, Christopher M.

    2015-12-01

    Combined U-Pb ages and Hf isotopic data from 1.0 Ga to 1.3 Ga (Grenvillian) detrital zircon in Neoproterozoic and Cambrian siliciclastic sedimentary rocks in southwest North America, and from igneous zircon in potential Mesoproterozoic source rocks, are used to better assess the provenance of detrital zircon potentially transported across Laurentia in major river systems originating in the Grenville orogenic highlands. High-precision hafnium isotopic analyses of individual ∼1.1 Ga detrital zircon from Neoproterozoic siliciclastic sedimentary rocks in Sonora, northern Mexico, reveal that these zircons have low εHf (0) (-22 to -26) and were most likely derived from ∼1.1 Ga granitic rocks embedded in local Mojave Province Paleoproterozoic crust. In contrast, Grenvillian detrital zircons in Cambrian sedimentary rocks in Sonora, the Great Basin, and the Mojave Desert, have generally higher εHf (0) (-15 to -21) as demonstrated both by high precision solution-based, and by lower precision laser ablation, ICPMS data and were likely derived from more distal sources further to the east/southeast in Laurentia. Comparison to new and existing zircon U-Pb geochronology and Hf isotopic data from Grenvillian crystalline rocks from the Appalachian Mountains, central and west Texas, and from Paleoproterozoic terranes throughout southwest North America reveals that zircon in Cambrian sandstones need not entirely represent detritus transported across the continent from Grenville province rocks in the vicinity of the present-day southern Appalachian Mountains. Instead, these zircons could have been derived from more proximal, high εHf (0), ∼1.1 Ga, crystalline rocks such as those exposed today in the Llano Uplift in central Texas and in the Franklin Mountains of west Texas. Regardless of the exact source(s) of the Grenvillian detrital zircon, new and existing whole-rock Nd isotopic data from Neoproterozoic to Cambrian siliciclastic sedimentary rocks in the Mojave Desert

  3. Detrital zircon provenance of Mesoproterozoic to Cambrian arenites in the Western United States and Northwestern Mexico

    USGS Publications Warehouse

    Stewart, John H.; Gehrels, G.E.; Barth, A.P.; Link, P.K.; Christie-Blick, N.; Wrucke, C.T.

    2001-01-01

    U-Pb isotopic dating of detrital zircon from supracrustal Proterozoic and Cambrian arenites from the western United States and northern Mexico reveal three main age groups, 1.90 to 1.62 Ga, 1.45 to 1.40 Ga, and 1.2 to 1.0 Ga. Small amounts of zircons with ages of 3.1 to 2.5 Ga, 1.57 Ga, 1.32 Ga, 1.26 Ga, 0.7 Ga, and 0.5 Ga are also present. Detrital zircons ranging in age from 1.90 to 1.62 Ga and from 1.45 to 1.40 Ga are considered to have been derived from Proterozoic crystalline basement rocks of these known ages, and probably in part from reworked Proterozoic supracrustal sedimentary rocks, of the western United States. The 1.2 to 1.0 Ga detrital zircon ages from California, Arizona, and Sonora are characterized by distinct spikes (1.11 Ga, in particular) in the age-probability plots. These spikes are interpreted to indicate the influx of zircon from major silicic volcanic fields. Igneous rocks such as the Pikes Peak Granite (1.093 Ga) of Colorado, and the Aibo Granite (1.110 Ga) of Sonora, Mexico, may represent the deeply eroded roots of such volcanic fields. Samples from farther north along the Cordilleran margin that contain abundant 1.2-1.0 Ga detrital zircons do not show spikes in the age distribution, but rather ages spread out across the entire 1.2-1.0 Ga range. These age spectra resemble those for detrital zircons from the Grenville province, which is considered their source. Less common detrital zircons had a variety of sources. Zircons ranging in age from 3.36 to 2.31 Ga were apparently derived from inland parts of the North American continent from Wyoming to Canada. Zircons of about 1.577 Ga are highly unusual and may have had an exotic source; they may have come from Australia and been deposited in North America when Australia and North America were juxtaposed as part of the hypothetical Rodinian supercontinent. Detrital zircon of ??1.320 Ga apparently had the same source as that for tuff (1.320 Ga) in the Pioneer Shale of the Apache Group in Arizona

  4. Origin of northern Gondwana Cambrian sandstone revealed by detrital zircon SHRIMP dating

    USGS Publications Warehouse

    Avigad, D.; Kolodner, K.; McWilliams, M.; Persing, H.; Weissbrod, T.

    2003-01-01

    Voluminous Paleozoic sandstone sequences were deposited in northern Africa and Arabia following an extended Neoproterozoic orogenic cycle that culminated in the assembly of Gondwana. We measured sensitive high-resolution ion microprobe (SHRIMP) U-Pb ages of detrital zircons separated from several Cambrian units in the Elat area of southern Israel in order to unravel their provenance. This sandstone forms the base of the widespread siliciclastic section now exposed on the periphery of the Arabian-Nubian shield in northeastern Africa and Arabia. Most of the detrital zircons we analyzed yielded Neoproterozoic concordant ages with a marked concentration at 0.55–0.65 Ga. The most likely provenance of the Neoproterozoic detritus is the Arabian-Nubian shield; 0.55–0.65 Ga was a time of posttectonic igneous activity, rift-related volcanism, and strike-slip faulting there. Of the zircons, 30% yielded pre-Neoproterozoic ages grouped at 0.9–1.1 Ga (Kibaran), 1.65–1.85 Ga, and 2.45–2.7 Ga. The majority of the pre-Neoproterozoic zircons underwent Pb loss, possibly as a consequence of the Pan-African orogeny resetting their provenance. Rocks of the Saharan metacraton and the southern Afif terrane in Saudi Arabia (∼1000 km south of Elat) are plausible sources of these zircons. Kibaran basement rocks are currently exposed more than 3000 km south of Elat (flanking the Mozambique belt), but the shape of the detrital zircons of that age and the presence of feldspar in the host sandstone are not fully consistent with such a long-distance transport. Reworking of Neoproteorozoic glacial detritus may explain the presence of Kibaran detrital zircons in the Cambrian of Elat, but the possibility that the Arabian-Nubian shield contains Kibaran rocks (hitherto not recognized) should also be explored.

  5. The role of detrital zircons in Hadean crustal research

    NASA Astrophysics Data System (ADS)

    Nebel, Oliver; Rapp, Robert P.; Yaxley, Gregory M.

    2014-03-01

    Meso-Archean sedimentary sequences at Mt. Narryer and the Jack Hills of the Narryer Terrane in Western Australia's Yilgarn Craton contain detrital zircon grains with ages as old as 4.37 Ga, the oldest preserved terrestrial matter. These grains are rare remnants of Hadean (4.5-4.0 Ga) terrestrial crust and their survival stems from the crystallographic properties of zircon during crustal reworking: they are resistant to physical and chemical weathering. Zircons are further suitable for single grain, precise age determinations making them a unique archive of the crustal past. Only a small proportion of all detrital zircons from the Narryer Terrane show Hadean age spectra and younger overgrowth rims on all 'Hadean' grains indicate multiple recycling events. Numerous studies that applied a spectacular range of analytical tools and proxies have been undertaken to decipher the geochemical nature of these zircons' host rocks, in order to place constraints on Hadean geodynamics and the processes responsible for creating the earliest terrestrial crust. Their elemental and isotope budget and mineral inclusions have helped to develop an emerging picture of a water-rich, evolved Hadean crust. However, subsequent studies have challenged this view and it seems that each piece of new evidence indicative of an early, evolved continental crust has non-unique interpretations also permissive of mafic to ultra-mafic crust. In this review we examine these disparate interpretations and their possible implications and conclude that at least parts of the earliest terrestrial crust were hydrated. However, to date there is no conclusive evidence for preserved granitic, continental crust. The protoliths of the Hadean detrital zircons were likely acidic in nature, yet the composition of the greater terrane from which these melts were derived was probably mafic. It remains unclear if the zircons formed in a geodynamic environment that includes Hadean subduction. We suspect that the Hadean

  6. Detrital zircon geochronology of quartzose metasedimentary rocks from parautochthonous North America, east-central Alaska

    USGS Publications Warehouse

    Dusel-Bacon, Cynthia; Holm-Denoma, Christopher S.; Jones, James V.; Aleinikoff, John N.; Mortensen, James K.

    2017-01-01

    We report eight new U-Pb detrital zircon ages for quartzose metasedimentary rocks from four lithotectonic units of parautochthonous North America in east-central Alaska: the Healy schist, Keevy Peak Formation, and Sheep Creek Member of the Totatlanika Schist in the northern Alaska Range, and the Butte assemblage in the northwestern Yukon-Tanana Upland. Excepting 1 of 3 samples from the Healy schist, all have dominant detrital zircon populations of 1.9–1.8 Ga and a subordinate population of 2.7–2.6 Ga. Three zircons from Totatlanika Schist yield the youngest age of ca. 780 Ma. The anomalous Healy schist sample has abundant 1.6–0.9 Ga detrital zircon, as well as populations at 2.0–1.8 Ga and 2.7–2.5 Ga that overlap the ages from the rest of our samples; it has a minimum age population of ca. 1007 Ma.Detrital zircon age populations from all but the anomalous sample are statistically similar to those from (1) other peri-Laurentian units in east-central Alaska; (2) the Snowcap assemblage in Yukon, basement of the allochthonous Yukon-Tanana terrane; (3) Neoproterozoic to Ordovician Laurentian passive margin strata in southern British Columbia, Canada; and (4) Proterozoic Laurentian Sequence C strata of northwestern Canada. Recycling of zircon from the Paleoproterozoic Great Bear magmatic zone in the Wopmay orogen and its Archean precursors could explain both the Precambrian zircon populations and arc trace element signatures of our samples. Zircon from the anomalous Healy schist sample resembles that in Nation River Formation and Adams Argillite in eastern Alaska, suggesting recycling of detritus in those units.

  7. Detrital zircon ages from southern Norway - implications for the Proterozoic evolution of the southwestern Baltic Shield

    NASA Astrophysics Data System (ADS)

    Knudsen, T.-L.; Andersen, T.; Whitehouse, M. J.; Vestin, J.

    An ion-microprobe (SIMS) U-Pb zircon dating study on four samples of Precambrian metasediments from the high-grade Bamble Sector, southern Norway, gives the first information on the timing of discrete crust-forming events in the SW part of the Baltic Shield. Recent Nd and Pb studies have indicated that the sources of the clastic metasediments in this area have crustal histories extending back to 1.7 to 2.1Ga, although there is no record of rocks older than 1.6Ga in southern Norway. The analysed metasediments are from a sequence of intercalated, centimetre to 10-metre wide units of quartzites, semi-metapelites, metapelites and mafic granulites. The zircons can be grouped in two morphological populations: (1) long prismatic; (2) rounded, often flattened. The BSE images reveal that both populations consist of oscillatory zoned, rounded and corroded cores (detrital grains of magmatic origin), surrounded by homogeneous rims (metamorphic overgrowths). The detrital zircons have 207Pb/206Pb ages between 1367 and 1939Ma, with frequency maxima in the range 1.85 to 1.70Ga and 1.60 to 1.50Ga. There is no correlation between crystal habit and age of the zircon. One resorbed, inner zircon core in a detrital grain is strongly discordant and gives a composite inner core-magmatic outer core 207Pb/206Pb age of 2383 Ma. Two discrete, unzoned zircons have 207Pb/206Pb ages of 1122 and 1133Ma, representing zircon growth during the Sveconorwegian high-grade metamorphism. Also the μm wide overgrowths, embayments in the detrital cores and apparent ``inner cores'' which represent secondary metamorphic zircon growth in deep embayments in detrital grains, are of Sveconorwegian age. The composite-detrital-metamorphic zircon analyses give generally discordant 206Pb/238U versus 207Pb/235U ratios and maximum 207Pb/206Pb ages of 1438Ma. These data demonstrate the existence of a protocrust of 1.7 to 2.0Ga in the southwestern part of the Baltic Shield, implying a break in the overall westward

  8. Paleomagnetism of Hadean and Archean Detrital Zircons from the Jack Hills, Western Australia

    NASA Astrophysics Data System (ADS)

    Weiss, B. P.; Lima, E. A.; Alexander, E.; Bell, E. A.; Boehnke, P.; Wielicki, M. M.; Harrison, M.; Fu, R. R.; Kehayias, P.; Glenn, D. R.; Walsworth, R. L.; Araujo, J. F. D.; Einsle, J. F.; Harrison, R.; Trail, D.; Watson, E. B.

    2016-12-01

    Determining the history of Earth's dynamo prior to the oldest known well-preserved rock record is one of the ultimate challenges in the field of paleomagnetism. The dynamo's early history has major implications for the evolution of the core, the initiation of plate tectonics, the physics of magnetic field generation, and the habitability of the early Earth. The only known minerals that might retain paleomagnetic records from well before 3.5 billion years ago (Ga) are detrital zircon crystals found in sedimentary rocks in Western Australia. Ranging up to 4.38 Ga in age, they are the oldest known terrestrial minerals. Tarduno et al. (2015) argued that detrital zircons contain records of an active dynamo dating back to 4.2 Ga. However, it has not been demonstrated that the zircons have escaped remagnetization during the intervening time since their formation (Weiss et al. 2016). Therefore, the age of magnetization in the Jack Hills zircons and the existence of a dynamo prior to 3.5 Ga have yet to be established. To address this issue, we have been studying the magnetism and thermal and aqueous alteration histories of single Archean and Hadean Jack Hills zircon crystals. Peak unblocking temperatures combined with electron backscatter diffraction indicate that the zircons contain inclusions of magnetite and hematite. Electron microscopy, X-ray tomography, and quantum diamond magnetometry indicate that much of the iron oxides in the zircons are associated with cracks and are therefore likely secondary. However, our newly developed Li-in-zircon geospeedometry technique shows for the first time that a small fraction of Hadean zircons retain sharp gradients in Li concentration (see figure), indicating they likely have never heated above the magnetite Curie temperature since their formation at >4 Ga. We describe thermal demagnetization and Thellier-Thellier paleointensity studies of these zircons and implications for the existence of a Hadean dynamo.

  9. Do Jack Hills Detrital Zircons Contain Records of the Early Geodynamo?

    NASA Astrophysics Data System (ADS)

    Weiss, B. P.; Maloof, A. C.; Tailby, N. D.; Ramezani, J.; Fu, R. R.; Glenn, D. R.; Kehayias, P.; Walsworth, R. L.; Hanus, V.; Trail, D.; Watson, E. B.; Harrison, T. M.; Bowring, S. A.; Kirschvink, J. L.; Swanson-Hysell, N.; Coe, R. S.; Einsle, J. F.; Harrison, R. J.

    2015-12-01

    It is unknown when Earth's dynamo magnetic field originated. With crystallization ages ranging from 3.0-4.38 Ga, detrital zircon crystals found in the Jack Hills of Western Australia might preserve a record of the missing first billion years of Earth's magnetic field history. Recently, Tarduno et al. (2015) argued that magnetization in Jack Hills zircons provides evidence for a substantial geomagnetic field dating back to their U/Pb formation ages (3.3 and 4.2 Ga). However, the identification of such ancient field records requires establishing that the zircons have avoided remagnetization since their formation. At a minimum, it should be demonstrated that they have not been remagnetized since being deposited at ~3.0 Ga. To establish the timing and intensity of the metamorphic and alteration events experienced by the zircon, we conducted 12 paleomagnetic field tests in combination with U-Pb geochronology on their host rocks (see Weiss et al. 2015, EPSL). Our data show that the Hadean zircon-bearing rocks and surrounding region have been pervasively remagnetized, with the final major overprinting likely from emplacement of the Warakurna large igneous province at 1.1 Ga (see Figure). Even if some Jack Hills zircons do record a pre-depositional magnetization, they still could have been remagnetized sometime during the 1.4 Gy between their crystallization and their deposition. First, the temperatures capable of remagnetizing magnetite inclusions are well below those that could reset a U-Pb date or result in significant discordance. Therefore, thermal events capable of completely remagnetizing Jack Hills zircons could be undetected by the techniques reported by Tarduno at al. (2015). Second, the zircons' magnetization might be dominated by secondary ferromagnetic inclusions or contamination. To address the latter possibility, we are conducting electron microscopy, x-ray tomography, and magnetic field mapping on the zircons. Our initial quantum diamond magnetometry high

  10. Detrital Zircons Split Sibumasu in East Gondwana

    NASA Astrophysics Data System (ADS)

    Zhang, X.; Chung, S. L.

    2017-12-01

    It is widely accepted that Sibumasu developed as a united terrane and originated from NW Australian margin in East Gondwana. Here we report new detrital zircon U-Pb-Hf isotopic data from Sumatra that, in combination with literature data, challenge and refute the above long-held view. In particular, the East and West Sumatra terranes share nearly identical Precambrian to Paleozoic detrital zircon age distributions and Hf isotopes, indicating a common provenance/origin for them. The Sumatra detrital zircons exhibit a prominent population of ca. 1170-1070 Ma, indistinguishable from those of the Lhasa and West Burma terranes, with detritus most probably sourcing from western Australia. By contrast, Sibuma (Sibumasu excluding Sumatra) detrital zircons display a prevailing population of ca. 980-935 Ma, strongly resembling those of the western Qiangtang terrane, with detrital materials most likely derived from Greater India and Himalayas. Such markedly distinct detrital zircon age profiles between Sumatra and Sibuma require disparate sources/origin for them, provoking disintegration of the widely-adopted, but outdated, term Sibumasu and thus inviting a new configuration of East Gondwana in the early Paleozoic, with Sumatra and West Burma lying outboard the Lhasa terrane in the NW Australian margin and Sibuma situated in the northern Greater Indian margin. More future investigations are needed to establish the precise rifting and drifting histories of Sumatra and Sibuma, as two separated terranes, during the breakup of Gondwana.

  11. Significance of detrital zircons in upper Devonian ocean-basin strata of the Sonora allochthon and Lower Permian synorogenic strata of the Mina Mexico foredeep, central Sonora, Mexico

    USGS Publications Warehouse

    Poole, F.G.; Gehrels, G.E.; Stewart, John H.

    2008-01-01

    U-Pb isotopic dating of detrital zircons from a conglomeratic barite sandstone in the Sonora allochthon and a calciclastic sandstone in the Mina Mexico foredeep of the Minas de Barita area reveals two main age groups in the Upper Devonian part of the Los Pozos Formation, 1.73-1.65 Ga and 1.44-1.42 Ga; and three main age groups in the Lower Permian part of the Mina Mexico Formation, 1.93-1.91 Ga, 1.45-1.42 Ga, and 1.1-1.0 Ga. Small numbers of zircons with ages of 2.72-2.65 Ga, 1.30-1.24 Ga, ca. 2.46 Ga, ca. 1.83 Ga, and ca. 0.53 Ga are also present in the Los Pozos sandstone. Detrital zircons ranging in age from 1.73 to 1.65 Ga are considered to have been derived from the Yavapai, Mojave, and Mazatzal Provinces and their transition zones of the southwestern United States and northwestern Mexico. The 1.45-1.30 Ga detrital zircons were probably derived from scattered granite bodies within the Mojave and Mazatzal basement rocks in the southwestern United States and northwestern Mexico, and possibly from the Southern and Eastern Granite-Rhyolite Provinces of the southern United States. The 1.24-1.0 Ga detrital zircons are believed to have been derived from the Grenville (Llano) Province to the east and northeast or from Grenvilleage intrusions or anatectites to the north. Several detrital zircon ages ranging from 2.72 to 1.91 Ga were probably derived originally from the Archean Wyoming Province and Early Paleoproterozoic rocks of the Lake Superior region. These older detrital zircons most likely have been recycled one or more times into the Paleozoic sandstones of central Sonora. The 0.53 Ga zircon is believed to have been derived from a Lower Cambrian granitoid or meta-morphic rock northeast of central Sonora, possibly in New Mexico and Colorado, or Oklahoma. Detrital zircon geochronology suggests that most of the detritus in both samples was derived from Laurentia to the north, whereas some detritus in the Permian synorogenic foredeep sequence was derived from the

  12. Hadean Crustal Processes Revealed from Oxygen Isotopes and U-Th-Pb Depth Profiling of Pre-4.0 Ga Detrital Zircons from Western Australia

    NASA Technical Reports Server (NTRS)

    Trail, D.; Mojzsis, S. J.; Harrison, T. M.

    2005-01-01

    Because physical and chemical processes of the past are determined from analysis of a preserved geologic record, little is known about terrestrial crustal processes of the first 500 Ma during the so-called Hadean Eon. What is known from direct measurements has been derived almost exclusively from the study of greater than 4.0 Ga detrital zircons from the Jack Hills, Western Australia. The geochemistry of these zircons has direct application to understanding the origin and evolution of the rocks during the Hadean because: (i) U-Th-Pb age determinations by ion microprobe suggests the presence of crust as early as 4.37 Ga, or shortly after lunar formation; (ii) high-resolution U-Th-Pb zircon depth profiles reported here reveal several episodes of zircon growth in the Hadean previously unrecognized; (iii) core regions of pre-4.0 Ga zircons with igneous compositions are enriched in O-18 and contain metaluminous and peraluminous mineral inclusions, both features indicative of S-type grainitod protoliths. Study of these ancient zircons provides a unique window into the first half billion years that permits assessment of the potential of the Hadean Earth to host an emergent biosphere.

  13. Trace element chemistry of zircons from oceanic crust: A method for distinguishing detrital zircon provenance

    USGS Publications Warehouse

    Grimes, Craig B.; John, Barbara E.; Kelemen, P.B.; Mazdab, F.K.; Wooden, J.L.; Cheadle, Michael J.; Hanghoj, K.; Schwartz, J.J.

    2007-01-01

    We present newly acquired trace element compositions for more than 300 zircon grains in 36 gabbros formed at the slow-spreading Mid-Atlantic and Southwest Indian Ridges. Rare earth element patterns for zircon from modern oceanic crust completely overlap with those for zircon crystallized in continental granitoids. However, plots of U versus Yb and U/Yb versus Hf or Y discriminate zircons crystallized in oceanic crust from continental zircon, and provide a relatively robust method for distinguishing zircons from these environments. Approximately 80% of the modern ocean crust zircons are distinct from the field defined by more than 1700 continental zircons from Archean and Phanerozoic samples. These discrimination diagrams provide a new tool for fingerprinting ocean crust zircons derived from reservoirs like that of modern mid-ocean ridge basalt (MORB) in both modern and ancient detrital zircon populations. Hadean detrital zircons previously reported from the Acasta Gneiss, Canada, and the Narryer Gneiss terrane, Western Australia, plot in the continental granitoid field, supporting hypotheses that at least some Hadean detrital zircons crystallized in continental crust forming magmas and not from a reservoir like modern MORB. ?? 2007 The Geological Society of America.

  14. Pan-Africa/Pan-Brazilian detrital zircons in Lower Palaeozoic schists of SW Norway - enigmatic detrital zircon U-Pb ages

    NASA Astrophysics Data System (ADS)

    Zimmermann, Udo; Bjørheim, Maren; Clark, Chris

    2013-04-01

    We present Sensitive High Resolution Ion Microprobe (SHRIMP) U-Pb zircon age data from metasedimentary rocks (schists and quartzites) located in the town of Stavanger (SW Norway). The metasedimentary sequence is composed of schists, medium grained quartz-rich metawackes and quartzites. Quartzites and meta-quartz-wackes exhibit a mylonitic fabric with newly grown fine-grained muscovite defining the fabric. Accessory minerals are zircon, allanite, detrital apatite, monazite, ilmenite, rutile and zircon. The schists are dark and dominated by quartz and feldspar in a fine chloritic and silica-rich matrix and represent the dominant lithology of the region. While quartzites and metawackes show typical geochemical characteristics for strongly reworked rocks, the schists have very low Zr/Sc and Th/Sc ratios below 0.9 and point together with other trace element ratios (La/Sc, Ti/Zr) to the strong influence of less fractionated, mafic, sources in the detritus, possibly arc derived. U-Pb ages of detrital zircon from quartzites range between 740 to 1800 Ma. There is a defined population at 1135 and 1010 Ma tentatively correlated with the Sveconorwegian orogeny. A second population at ~1450 Ma that can be related to a tectono-magmatic event during the Earliest Mesoproterozoic, also recorded in Oslo, southern Sweden and Bornholm, mapped along the proposed southern margin of Baltica. Other detrital zircons record ages between 1586 - 1664 Ma that are not related to the latter event. The oldest U-Pb detrital zircon grain age was 1796 Ma and is potentially associated with the terminal phase of the Svecofennian orogeny. Detrital zircons from the associated schists do show a similar abundance of main age clusters but the oldest found zircons dates to 2013 Ma while the maximum depositional age could be determined by grains of Cambrian to even Ordovician ages with a large 1 sigma error, as such that we rather propose a Cambrian maximum depositional age. It is possible to speculate that

  15. Using detrital zircons from river sands to constrain major tectono-thermal events of the Cathaysia Block, SE China

    NASA Astrophysics Data System (ADS)

    Xu, Yonghang; Wang, Christina Yan; Zhao, Taiping

    2016-07-01

    Detrital zircons from the Minjiang and Zhujiang Rivers in SE China have been analyzed for U/Pb ages and Lu-Hf isotopic compositions to constrain their provenance and the growth history of the continental crust of the Cathaysia Block. Zircon U/Pb ages show five major populations at 90-250 Ma, 400-500 Ma, 0.7-1.2 Ga, 1.6-2.0 Ga and 2.3-2.6 Ga. Proterozoic zircons have Hf isotopic signatures consistent with the remelted ancient crust and the involvement of juvenile crust. However, Phanerozoic zircons have Hf isotopic signatures indicative of reworked or recycled ancient crust. Crustal growth rates based on the two-stage Hf model ages of the detrital zircons indicate that 30% and 90% of present crust in the northeastern Cathaysia Block was formed by 2.5 Ga and 1.6 Ga, respectively, whereas <20% continental crust was formed by 2.5 Ga, and 80% by 1.6 Ga in the southwestern Cathaysia Block. Therefore, Neoarchean and Paleoproterozoic were two major periods of crustal growth of the Cathaysia Block. Our results also reveal that the tectono-thermal events at ∼370 Ma and ∼117 Ma may have occurred to the Wuyishan terrane in the northeastern Cathaysia Block. Jurassic zircon grains have Hf isotopic compositions more variable than Cretaceous grains, which may have been derived from different source rocks. The 140-120 Ma tectono-thermal events were likely related to the change of the subduction direction of the Paleo-Pacific plate from northward to northwestward at 140 Ma. The 112-90 Ma tectono-thermal events may be correlated with the rollback of the subducted paleo-Pacific plate at ∼110 Ma.

  16. Provenance of the exotic Northern Sierra terrane (North American Cordillera) based on U-Pb detrital zircon data

    NASA Astrophysics Data System (ADS)

    Powerman, V.; Girty, G.; Hanson, R. E.; Grove, M.; Miller, E. L.; Hourigan, J. K.

    2017-12-01

    Ages of detrital zircons from the Northern Sierra terrane (NST) suggest an exotic provenance with respect to NW Laurentia. We have acquired U-Pb LA-ICPMS dz ages from 16 samples collected from the uppermost NST allochthon, the Sierra City mélange, and 1 sample from the lower Culbertson Lake allochthon. Age distributions can be divided into 3 partly intersecting groups: (a) 6 mélange samples and the 1 Culbertson Lake allochthon sample are dominated by >1 Ga grains; (b)5 samples are characterized by the additional presence of Early Paleozoic and Neoproterozoic grains (520-640;680-800;840-1000Ma); (c) 9 samples, 8 feldspathic, 1—qtz-rich, can be also characterized by the presence of 360-520Ma grains. These results strengthen the non Laurentian nature of detrital sources:(1)most of the detrital age distributions possess ages in the 1.49-1.61Ga interval, the "N.American magmatic gap";(2) Ediacaran zircons cannot be linked to any igneous event within West Laurentia. Most samples possess detrital age distributions that include the 1.0-2.0 Ga peak, characteristic of Baltica rather than Laurentia. These data, supplemented by SHRIMP-RG data (353-368Ma) from stitching igneous units suggest the following model: parts of NST were located at the NE margin of Baltica in the early Paleozoic, receiving "Baltica" (1.0-2.0 Ga) and "Timanide"(Late Vendian — Early Cambrian) zircons. This crustal block was later rifted away from Baltica and by mid-Paleozoic was juxtaposed with allochthons of presumably NW Laurentia provenance. The assembled terrane was involved in a subduction zone, resulting in the emplacement of 353-368Ma igneous rocks. The U-Pb detrital zircon age distributions presented here are similar to signatures of strata in along strike exotic terranes of the North American Cordillera (such as the Yreka terrane of the Klamath Mts., the Alexander terrane of S.Alaska and the Arctic Chukotka-Alaska terrane) by having Timanian, Baltica, and Caledonian signatures. Hence, it

  17. Tectonic Recycling in the Paleozoic Ouachita Assemblage from U-Pb Detrital Zircon Studies

    NASA Astrophysics Data System (ADS)

    Gleason, J. D.; Gehrels, G. E.; Finney, S. C.

    2001-05-01

    The Paleozoic Ouachita deep-marine clastic sedimentary assemblage records a complex provenance over the course of its 200 m.y. history, with evidence for mixed sources and multiple dispersal paths. Combined neodymium and U-Pb detrital zircon work has established that most of the assemblage in Arkansas and Oklahoma is derived from Laurentian sources, meaning that regardless of the multiple pathways by which sediment was delivered to Ouachita seafloor, the material had its ultimate origin on the North American continent. More detailed work is in progress to elucidate specific dispersal paths, in particular for the middle to late Ordovician when a major change in provenance is recorded, and during the Carboniferous when voluminous turbidites entered the basin. We sampled three formations for U-Pb detrital zircon studies: the lower Middle Ordovician Blakely Sandstone, the Upper Ordovician/Lower Silurian Blaylock Sandstone, and the Pennsylvanian Jackfork Group. Individual zircon ages from these units document a major change in provenance between deposition of the Blakely Sandstone and Blaylock Sandstone, which is also reflected in the neodymium isotopic signature. Both units have a large population of Grenvillian-age zircons (1.0-1.2 Ga), and a less abundant population of 1.3-1.4 Ga zircons likely derived from sources in the mid-continent region. The Blakely Sandstone also contains abundant Archean zircons (2.5-2.7 Ga, likely derived from the Superior Province), and one grain apparently derived from the Penokean orogen (1.9 Ga). Zircon morphology (highly rounded, spherical), combined with the pure quartz sandstone lithology of the Blakely Sandstone, indicates very mature sedimentary sources. We conclude that zircons from this source were recycled ultimately from source terranes in the North American craton. This is reinforced by neodymium isotopes (eNd = -15), paleocurrents (from the north) and olistoliths (1.3 Ga granites), the latter indicating that Blakely turbidites

  18. North Qinling Terrain as a provenance of Kuanping Group: LA-ICP-MS U-Pb Geochronology of detrital zircons

    NASA Astrophysics Data System (ADS)

    Hu, B.; Li, S.; Zhai, M.; Wu, J.; Jia, X.

    2017-12-01

    Though some Neoproterozoic S-type granites in the North Qinling Terrain (NQT), China indicate the collision between the NQT and an unknown block, there are still controversial. The LA-ICP-MS U-Pb ages of detrital zircons of meta-sandstones from the Kuanping Group in Luonan area, NQT, provide sedimentology evidence to prove that the NQT and an unknown block from Rodinia supercontinent have been collided during Meso-Neoproterozoic. The U-Pb ages of detrital zircons from the Kuanping Group show that the main age peaks are at 2.58 Ga, 2.46 Ga, 2.0 Ga, 1.78 Ga, 1.6 Ga, 1.45 Ga and 1.27 Ga. The youngest age of 880 Ma indicates that the sedimentary age of the Kuanping Group is less than 880 Ma. The provenances, which provide 1.45 - 0.88 Ga sediments may come from NQT, which magmatic and metamorphic rocks during this period outcropped. Whereas provenances providing 2.6- 1.6 Ga sediments may come from an unknown block. This indicates that the Kuangping Group received both NQT and the unknown block materials. Therefore, the NQT and the unknown block may have collided before 880 Ma. 889 - 848 Ma A-type granites distributing the NQT was considered forming under a post-collisional tectonics. According the youngest detrital zircon ages of 880 Ma, it is inferred that the Kuanping Basin may also form in the same tectonic environments. Neoproterozoic Kuanping basin and 889 - 848 Ma A-type granites may be a result which NQT broken off a block of Rodinia supercontinent. Acknowledgments: This research is supported by National Key Research and Development Plan of China (2016YFC0601002), Special Fund for Basic Scientific Research of Central Colleges, Chang'an University (310827172201, 0009-2014G1271067) and National Nature Science Foundation of China (41402042).

  19. Pervasive remagnetization of detrital zircon host rocks in the Jack Hills, Western Australia and implications for records of the early geodynamo

    NASA Astrophysics Data System (ADS)

    Weiss, Benjamin P.; Maloof, Adam C.; Tailby, Nicholas; Ramezani, Jahandar; Fu, Roger R.; Hanus, Veronica; Trail, Dustin; Bruce Watson, E.; Harrison, T. Mark; Bowring, Samuel A.; Kirschvink, Joseph L.; Swanson-Hysell, Nicholas L.; Coe, Robert S.

    2015-11-01

    It currently is unknown when Earth's dynamo magnetic field originated. Paleomagnetic studies indicate that a field with an intensity similar to that of the present day existed 3.5 billion years ago (Ga). Detrital zircon crystals found in the Jack Hills of Western Australia are some of the very few samples known to substantially predate this time. With crystallization ages ranging from 3.0-4.38 Ga, these zircons might preserve a record of the missing first billion years of Earth's magnetic field history. However, a key unknown is the age and origin of magnetization in the Jack Hills zircons. The identification of >3.9 Ga (i.e., Hadean) field records requires first establishing that the zircons have avoided remagnetization since being deposited in quartz-rich conglomerates at 2.65-3.05 Ga. To address this issue, we have conducted paleomagnetic conglomerate, baked contact, and fold tests in combination with U-Pb geochronology to establish the timing of the metamorphic and alteration events and the peak temperatures experienced by the zircon host rocks. These tests include the first conglomerate test directly on the Hadean-zircon bearing conglomerate at Erawandoo Hill. Although we observed little evidence for remagnetization by recent lightning strikes, we found that the Hadean zircon-bearing rocks and surrounding region have been pervasively remagnetized, with the final major overprinting likely due to thermal and/or aqueous effects from the emplacement of the Warakurna large igneous province at ∼1070 million years ago (Ma). Although localized regions of the Jack Hills might have escaped complete remagnetization, there currently is no robust evidence for pre-depositional (>3.0 Ga) magnetization in the Jack Hills detrital zircons.

  20. Single grain U/Pb geochronology of detrital zircons from Midcontinent rift arkoses, NE Kansas: Implications for depositional history

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Martin, M.W.; Van Schmus, W.R.; Berendsen, P.

    1993-03-01

    The Midcontinent rift system in the subsurface south of the Lake Superior region has been well imaged by magnetic, gravity and seismic surveys, however only a few wells have penetrated and recovered core from rift-basin fill in this region. Texaco's exploratory Noel Poersch well [number sign]1 in northeastern Kansas, penetrated [approximately] 2,600 m of rift-related volcanic, igneous, and arkosic sedimentary rocks from which a total of 35 m of core was taken from fourteen different horizons in the rift-related section. To determine provenance ages and to constrain better the depositional patterns of clastic sedimentary rocks within the Mid-continent rift basin,more » the authors have undertaken U/Pb geochronology of detrital zircon from arkosic horizons along the depth of recovered core from the Texaco Poersch [number sign]1 well. Preliminary analyses indicate that the stratigraphically lowest arkoses recovered in core have provenance ages that range in age from 1.7--1.8 Ga, 1.4--1.5 Ga and 1.1--1.2 Ga. These data suggest the following conclusions: (1) The arkosic sediments were primarily derived proximally from the adjacent rift margin, which is known to consist of 1.75--1.80 Ga gneissic and granitic basement intruded by 1.35--1.45 Ga granitic plutons in Nebraska and northernmost Kansas plus 1.63--1.68 Ga granitic basement intruded by 1.35--1.45 granitic plutons in most of Kansas; 1.63--1.70 detrital zircons were absent, suggesting that most of the detritus was derived from northerly directions. (2) No Archean or 1.85 to 1.90 Ga Early proterozoic detrital zircons were found, suggesting very little to no transport of detritus along the rift axis from farther north, e.g., from Penokean, Trans-Hudson, or Superior Province regions. (3) One nearly concordant zircon with a Pb-Pb age of 1.18 Ga was found, suggesting that some of the detritus was derived either from older phases of igneous rift fill or from ca. 1.2 Ga intrusions that pre-date rifting.« less

  1. Detrital zircons and Earth system evolution

    NASA Astrophysics Data System (ADS)

    McKenzie, R.

    2016-12-01

    Zircon is a mineral commonly produced in silicic magmatism. Therefore, due to its resilience and exceedingly long residence times in the continental crust, detrital zircon records can be used to track processes associated with silicic magmatism throughout Earth history. In this contribution I will address the potential role of preservational biases in zircon record, and further discuss how zircon datasets can be used to help better understand the relationship between lithospheric and Earth system evolution. I will use large compilations of zircon data to trace the composition and weatherability of the continental crust, to evaluate temporal rates of crustal recycling, and finally to track spatiotemporal variation in continental arc magmatism and volcanic CO2 outgassing throughout Earth history. These records demonstrate that secular changes in plate tectonic regimes played a prominent role in modulating conditions of the ocean+atmosphere system and long-term climate state for the last 3 billion years.

  2. Detrital Zircon Geochronology of Sedimentary Rocks of the 3.6 - 3.2 Ga Barberton Greenstone Belt: No Evidence for Older Continental Crust

    NASA Astrophysics Data System (ADS)

    Drabon, N.; Lowe, D. R.; Byerly, G. R.; Harrington, J.

    2017-12-01

    The crustal setting of early Archean greenstone belts and whether they formed on or associated with blocks of older continental crust or in more oceanic settings remains a major issue in Archean geology. We report detrital zircon U-Pb age data from sandstones of the 3.26-3.20 Ga Fig Tree and Moodies Groups and from 3.47 to 3.23 Ga meteorite impact-related deposits in the 3.55-3.20 Ga Barberton greenstone belt (BGB), South Africa. The provenance signatures of these sediments are characterized by zircon age peaks at 3.54, 3.46, 3.40, 3.30, and 3.25 Ga. These clusters are coincident either with the ages of major episodes of felsic to intermediate igneous activity within and around the belt or with the ages of thin felsic tuffs reflecting distant volcanic activity. Only 15 of the reported 3410 grains (<0.5%) pre-date the age of the oldest rocks in the BGB. The extreme rarity of zircons older than the felsic components of the BGB itself, even after widespread deformation, uplift, and deep erosion of the BGB, implies that an older continental substrate is unlikely to have existed beneath or adjacent to the BGB. Ten of the 15 pre -BGB zircons were recovered from a single meteorite impact-related layer and may have been derived from far beyond the BGB by impact-related processes. The remaining old zircons could represent felsic rocks in older, unexposed parts of the BGB sequence, but are too few to provide evidence for a continental source. This finding offers further evidence that the large, thick, high-standing, highly evolved blocks of continental crust with an andesitic bulk composition that characterize the Earth during younger geologic times were scarce in the early Archean.

  3. The Origin of the Chinese Central Tianshan Block in the Southern Central Asian Orogenic Belt: Evidence from Detrital Zircon Study

    NASA Astrophysics Data System (ADS)

    Huang, Z.; Long, X.; Yuan, C.

    2016-12-01

    The Chinese Central Tianshan Block (CTB) is one of the oldest continental fragments in the southern Central Asian Orogenic Belt (CAOB). Although it is vital for understanding the evolution of the CAOB, its origin has been poorly studied. The CTB was previously suggested to have been originated from the North China, the South China, the Tarim cratons or the East European Craton (Baltica). A total of 165 concordant U-Pb and Hf isotopic analyses of detrital zircon are obtained from three meta-sediments in the CTB, including one meta-sandstone from Xingxingxia formation and one meta-sandstone as well as one quartzite from Kawabulake formation. Detrital zircon grains from the Xingxingxia and Kawabulake formations are dominated by respective youngest age populations at 1002 Ma and 930-960 Ma, providing constraints on the maximum depositional ages for these two formations. Zircon grains from the meta-sediments have very similar age distributions, with two dominant peaks at 0.93-1.0 Ga and 1.0-1.6 Ga and a minor peak at 2.3-2.7 Ga. They have similar Hf isotopic signatures, suggesting that the meta-sediments in the CTB share similar sedimentary provenance. The early Neoproterozoic detrital zircon grains are mainly local-derived, whereas the Paleo-Mesoproterozoic grains are both autochthonous and allochthonous. The occurrence of these Mesoproterozoic and Neoproterozoic zircon grains are coincident with the Nuna breakup and the Rodinia assembly. This suggests that the CTB might experience the tectonic switching of the Nuna to the Rodinia. The distinct Meso-Neoproterozoic age patterns and Hf isotopic compositions of these detrital grains from the CTB and the surrounding blocks indicate that the CTB was not located close to the North China, the South China or the Tarim cratons in Precambrian. Our new data suggest that the CTB was most likely once a part of the East European Craton before the Neoproterozoic. This study was supported by National Basic Research Program of China

  4. The provenance of Archean clastic metasediments in the Narryer Gneiss Complex, Western Australia: Trace element geochemistry, Nd isotopes, and U-Pb ages for detrital zircons

    NASA Astrophysics Data System (ADS)

    Maas, Roland; McCulloch, Malcolm T.

    1991-07-01

    Clastic metasedimentary rocks of mid-Archean age from the Mt. Narryer and Jack Hills metasedimentary belts have REE patterns resembling those of mid- to late-Archean pelitic-quartzitic cratonic sequences elsewhere, and post-Archean continental rocks in general. Detrital zircons in the metasediments range in age from ca. 3000 to 3700 Ma. This indicates a provenance from mature cratonic sources controlled by K-rich granitic rocks. Additional minor sediment sources were identified as older, mainly chemical sedimentary sequences, ultramafic rocks, and felsic rocks characterized by low HREE contents, perhaps of tonalitic affinity. The association of the near-shore/fluviatile clastic association studied here with extensive turbiditic and chemical sedimentary sequences indicates these sources formed part of a (rifted ?) cratonic margin ca. 3 Ga ago. Differences between sedimentary REE patterns and those in the surrounding 3.73-3.0 Ga orthogneiss terrain, and between detrital zircon ages and the age distribution in the gneisses, suggest that the present association of the metasedimentary belts with the orthogneiss terrain is of tectonic origin. The occurrence of detrital zircons with U-Pb ages > 4 Ga in certain quartzites and conglomerates of the Jack Hills and Mt. Narryer metasedimentary sequences indicates a further, most likely granitic, source. ɛNd( TDep) values in Jack Hills metasediments vary widely (+5 to -12) but have a smaller range in the Mt. Narryer belt (-5 to -9). The lowest ɛNd values of both sequences are interpreted to reflect the presence of detritus derived from 4.1-4.2 Ga old LREE-enriched continental crust in proportions considerably larger (≥ 10%) than estimated previously from the abundance of pre-4 Ga detrital zircons (≈3%). This would imply the former existence of significant volumes of pre-4 Ga continental crust in the provenance of the Mt. Narryer and Jack Hills metasediments.

  5. Detrital zircon U-Pb geochronology of Cambrian to Triassic miogeoclinal and eugeoclinal strata of Sonora, Mexico

    USGS Publications Warehouse

    Gehrels, G.E.; Stewart, John H.

    1998-01-01

    One hundred and eighty two individual detrital zircon grains from Cambrian through Permian miogeoclinal strata, Ordovician eugeoclinal rocks, and Triassic post-orogenic sediments in northwestern Sonora have been analyzed. During Cambrian, Devonian, Permian, and Triassic time, most zircons accumulating along this part of the Cordilleran margin were shed from 1.40-1.45 and 1.62-1.78 Ga igneous rocks that are widespread in the southwestern United States and northwestern Mexico. Zircons with ages of approximately 1.11 Ga are common in Cambrian strata and were apparently shed from granite bodies near the sample site. The sources of 225-280 Ma zircons in our Triassic sample are more problematic, as few igneous rocks of these ages are recognized in northwestern Mexico. Such sources may be present but unrecognized, or the grains could have been derived from igneous rocks of the appropriate ages to the northwest in the Mojave Desert region, to the east in Chihuahua and Coahuila, or to the south in accreted(?) arc-type terranes. Because the zircon grains in our Cambrian and Devonian to Triassic samples could have accumulated in proximity to basement rocks near their present position or in the Death Valley region of southern California, our data do not support or refute the existence of the Mojave-Sonora megashear. Ordovician strata of both miogeoclinal and eugeoclinal affinity are dominated by >1.77 Ga detrital zircons, which are considerably older than most basement rocks in the region. Zircon grains in the miogeoclinal sample were apparently derived from the Peace River arch area of northwestern Canada and transported southward by longshore currents. The eugeoclinal grains may also have come from the Peace River arch region, with southward transport by either sedimentary or tectonic processes, or they may have been shed from off-shelf slivers of continents (perhaps Antarctica?) removed from the Cordilleran margin during Neoproterozoic rifting. It is also possible that the

  6. The provenance of Archean clastic metasediments in the Narryer Gneiss Complex, western Australia: Trace element geochemistry, Nd isotopes, and U-Pb ages for detrital zircons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Maas, R.; McCulloch, M.T.

    1991-07-01

    Clastic metasedimentary rocks of mid-Archean age from the Mt. Narryer and Jack Hills metasedimentary belts have REE patterns resembling those of mid- to late-Archean pelitic-quartzitic cratonic sequences elsewhere, and post-Archean continental rocks in general. Detrital zircons in the metasediments range in age from ca. 3,000 to 3,700 Ma. This indicates a provenance from mature cratonic sources controlled by K-rich granitic rocks. Additional minor sediment sources were identified as older, mainly chemical sedimentary sequences, ultramafic rocks, and felsic rocks characterized by low HREE contents, perhaps of tonalitic affinity. Differences between sedimentary REE patterns and those in the surrounding 3.73-3.0 Ga orthogneissmore » terrain, and between detrital zircon ages and the age distribution in the gneisses, suggest that the present association of the metasedimentary belts with the orthogneiss terrain is of tectonic origin. The occurrence of detrital zircons with U-Pb ages > 4 Ga in certain quartzites and conglomerates of the Jack Hills and Mt. Narryer metasedimentary sequences indicates a further, most likely granitic, source. {epsilon}{sub Nd}(T{sub Dep}) values in Jack Hills metasediments vary widely (+5 to {minus}12) but have a smaller range in the Mt. Narryer belt ({minus}5 to {minus}9). The lowest {epsilon}{sub Nd} values of both sequences are interpreted to reflect the presence of detritus derived from 4.1-4.2 Ga old LREE-enriched continental crust in proportions considerably larger ({ge} 10%) than estimated previously from the abundance of pre-4 Ga detrital zircons ({approx}3%). This would imply the former existence of significant volumes of pre-4 Ga continental crust in the provenance of the Mt. Narryer and Jack Hills metasediments.« less

  7. Early Mesozoic paleogeography and tectonic evolution of the western United States: Insights from detrital zircon U-Pb geochronology, Blue Mountains Province, northeastern Oregon

    USGS Publications Warehouse

    LaMaskin, Todd A.; Vervoort, J.D.; Dorsey, R.J.; Wright, J.E.

    2011-01-01

    This study assesses early Mesozoic provenance linkages and paleogeographic-tectonic models for the western United States based on new petrographic and detrital zircon data from Triassic and Jurassic sandstones of the "Izee" and Olds Ferry terranes of the Blue Mountains Province, northeastern Oregon. Triassic sediments were likely derived from the Baker terrane offshore accretionary subduction complex and are dominated by Late Archean (ca. 2.7-2.5 Ga), Late Paleoproterozoic (ca. 2.2-1.6 Ga), and Paleozoic (ca. 380-255 Ma) detrital zircon grains. These detrital ages suggest that portions of the Baker terrane have a genetic affinity with other Cordilleran accretionary subduction complexes of the western United States, including those in the Northern Sierra and Eastern Klamath terranes. The abundance of Precambrian grains in detritus derived from an offshore complex highlights the importance of sediment reworking. Jurassic sediments are dominated by Mesozoic detrital ages (ca. 230-160 Ma), contain significant amounts of Paleozoic (ca. 290, 380-350, 480-415 Ma), Neoproterozoic (ca. 675-575 Ma), and Mesoproterozoic grains (ca. 1.4-1.0 Ga), and have lesser quantities of Late Paleoproterozoic grains (ca. 2.1-1.7 Ga). Detrital zircon ages in Jurassic sediments closely resemble well-documented age distributions in transcontinental sands of Ouachita-Appalachian provenance that were transported across the southwestern United States and modified by input from cratonal, miogeoclinal, and Cordilleran-arc sources during Triassic and Jurassic time. Jurassic sediments likely were derived from the Cordilleran arc and an orogenic highland in Nevada that yielded recycled sand from uplifted Triassic backarc basin deposits. Our data suggest that numerous Jurassic Cordilleran basins formed close to the Cordilleran margin and support a model for moderate post-Jurassic translation (~400 km) of the Blue Mountains Province. ?? 2011 Geological Society of America.

  8. Age and origin of the Merrimack terrane, southeastern New England: A detrital zircon U-Pb geochronology study

    NASA Astrophysics Data System (ADS)

    Sorota, Kristin

    Metasedimentary rocks of the Merrimack terrane (MT) originated as a thick cover sequence on Ganderia consisting of sandstones, calcareous sandstones, pelitic rocks and turbidites. In order to investigate the age, provenance and stratigraphic order of these rocks and correlations with adjoining terranes, detrital zircon suites from 7 formations across the MT along a NNE-trending transect from east-central Massachusetts to SE New Hampshire were analyzed by U-Pb LA-ICP-MS methods on 90-140 grains per sample. The youngest detrital zircons in the western units, the Worcester, Oakdale and Paxton Formations, are ca. 438 Ma while those in the Kittery, Eliot and Berwick Formations in the northeast are ca. 426 Ma. The Tower Hill Formation previously interpreted to form the easternmost unit of the MT in MA, has a distinctly different zircon distribution with its youngest zircon population in the Cambrian. All samples except for the Tower Hill Formation have detrital zircon age distributions with significant peaks in the mid-to late Ordovician, similar abundances of early Paleozoic and late Neoproterozoic zircons, significant input from ˜1.0 to ˜1.8 Ga sources and limited Archean grains. The similarities in zircon provenance suggest that all units across the terrane, except for the Tower Hill Formation, belong to a single sequence of rocks, with similar sources and with the units in the NE possibly being somewhat younger than those in east-central Massachusetts. The continuous zircon age distributions observed throughout the Mesoproterozoic and late Paleoproterozoic are consistent with an Amazonian source. All samples, except the Tower Hill Formation, show sedimentary input from both Ganderian and Laurentian sources and suggest that Laurentian input increases as the maximum depositional age decreases.

  9. Lithofacies control in detrital zircon provenance studies: Insights from the Cretaceous Methow basin, southern Canadian Cordillera

    USGS Publications Warehouse

    DeGraaff-Surpless, K.; Mahoney, J.B.; Wooden, J.L.; McWilliams, M.O.

    2003-01-01

    High-frequency sampling for detrital zircon analysis can provide a detailed record of fine-scale basin evolution by revealing the temporal and spatial variability of detrital zircon ages within clastic sedimentary successions. This investigation employed detailed sampling of two sedimentary successions in the Methow/Methow-Tyaughton basin of the southern Canadian Cordillera to characterize the heterogeneity of detrital zircon signatures within single lithofacies and assess the applicability of detrital zircon analysis in distinguishing fine-scale provenance changes not apparent in lithologic analysis of the strata. The Methow/Methow-Tyaughton basin contains two distinct stratigraphic sequences of middle Albian to Santonian clastic sedimentary rocks: submarine-fan deposits of the Harts Pass Formation/Jackass Mountain Group and fluvial deposits of the Winthrop Formation. Although both stratigraphic sequences displayed consistent ranges in detrital zircon ages on a broad scale, detailed sampling within each succession revealed heterogeneity in the detrital zircon age distributions that was systematic and predictable in the turbidite succession but unpredictable in the fluvial succession. These results suggest that a high-density sampling approach permits interpretation of finescale changes within a lithologically uniform turbiditic sedimentary succession, but heterogeneity within fluvial systems may be too large and unpredictable to permit accurate fine-scale characterization of the evolution of source regions. The robust composite detrital zircon age signature developed for these two successions permits comparison of the Methow/Methow-Tyaughton basin age signature with known plutonic source-rock ages from major plutonic belts throughout the Cretaceous North American margin. The Methow/Methow-Tyaughton basin detrital zircon age signature matches best with source regions in the southern Canadian Cordillera, requiring that the basin developed in close proximity to the

  10. Investigating the Early Carbon Cycle Using Carbonaceous Inclusions and Dissolved Carbon in Detrital Zircon

    NASA Astrophysics Data System (ADS)

    Bell, E. A.; Boehnke, P.; Harrison, M.; Mao, W. L.

    2015-12-01

    Because the terrestrial rock record extends only to ~4 Ga and older materials thus far identified are limited to detrital zircons, information about volatile abundances and cycles on early Earth is limited. Carbon, for instance, plays an important role not only in the modern biosphere but also in deep recycling of materials between the crust and mantle. We are investigating the record of carbon abundance and origin in Hadean zircons from Jack Hills (W. Australia) using two main approaches. First, carbon may partition into the zircon structure at trace levels during crystallization from a magma, and better understanding of this partitioning behavior will allow for zircon's use as a monitor of magmatic carbon contents. We have measured carbon abundances in zircon from a variety of igneous rocks (gabbro; I-, A-, and S-type granitoids) via SIMS and found that although abundances are typically low (average raw 12C/30Si ~ 1x10-6), S-type granite zircons can reach a factor of 1000 over this background. Around 10% of Hadean zircons investigated show similar enrichments, consistent with other evidence for the derivation of many Jack Hills zircons from S-type granitoids and with the establishment of modern-level carbon abundances in the crust by ca. 4.2 Ga. Diamond and graphite inclusions reported in the Jack Hills zircons by previous studies proved to be contamination by polishing debris, leaving the true abundance of these materials in the population uncertain. On a second front, we have identified and investigated primary carbonaceous inclusions in these zircons. From a population of over 10,000 Jack Hills zircons, we identified one concordant 4.10±0.01 Ga zircon that contains primary graphite inclusions (so interpreted due to their enclosure in a crack-free zircon host as shown by transmission X-ray microscopy and their crystal habit). Their δ13CPDB of -24±5‰ is consistent with a biogenic origin and, in the absence of a likely inorganic mechanism to produce such a

  11. Detrital zircon geochronology of Neoproterozoic to Middle Cambrian miogeoclinal and platformal strata: Northwest Sonora, Mexico

    USGS Publications Warehouse

    Gross, E.L.; Stewart, John H.; Gehreis, G.E.

    2000-01-01

    Eighty-five detrital zircon grains from Mesoproterozoic and/or Neoproterozoic to Middle Cambrian sedimentary strata in northwest Sonora, Mexico, have been analyzed to determine source terranes and provide limiting depositional ages of the units. The zircon suites from the Mesoproterozoic and/or Neoproterozoic El Alamo Formation and El Aguila unit yield ages between 1.06 Ga and 2.67 Ga, with predominant ages of 1.1 to 1.2 Ga. Zircons from the Lower? and Middle Cambrian Bolsa Quartzite show age groups from 525 Ma to 1.63 Ga, with a dominant population of 1.1 to 1.2 Ga grains. Grains older than 1.2 Ga in the samples were most likely derived from basement terranes and ???1.4 Ga granitic bodies of the southwest U.S. and northwest Mexico. It is also possible that the sediments were transported from the south, although source rocks of the appropriate age are not presently exposed south of the study area in northern Mexico. Three possibilities for the dominant 1.1 to 1.2 Ga grains include derivation from: (I) exposures of the Grenville belt in southern North America, (2) local 1.1-1.2 Ga granite bodies, or (3) a southern source, such as the Oaxaca terrane, that was subsequently rifted away. Sampling of additional units in the western U.S. and northern Mexico may help resolve the ambiguity surrounding the source of the 1.1 to 1.2 Ga grains.

  12. Assessment of Paleozoic terrane accretion along the southern central Andes using detrital zircon geochronology

    NASA Astrophysics Data System (ADS)

    McKenzie, R.; Horton, B. K.; Fuentes, F.; Fosdick, J. C.; Capaldi, T.; Stockli, D. F.; Alvarado, P. M.

    2015-12-01

    Two distinct Paleozoic terranes known as Cuyania and Chilenia occupy the southern central Andes of Argentina and Chile. Because the proposed terrane boundaries coincide with major structural elements of the modern Andean system at 30-36°S, it is important to understand their origins and potential role in guiding later Andean deformation. The Cuyania terrane of western Argentina encompasses the Precordillera (PC) and a thick-skinned thrust block of the western Sierras Pampeanas, persisting southward to the San Rafael Basin (SRB). Although recently challenged, Cuyania has been long considered a piece of southern Laurentia that rifted away during the early Cambrian and collided with the Argentine margin during the Ordovician. Chilenia is situated west of Cuyania and includes the Frontal Cordillera (FC) and Andean magmatic arc. This less-studied terrane was potentially accreted during an enigmatic Devonian orogenic event. We present new detrital zircon U-Pb age data from siliciclastic sedimentary rocks that span the entire Paleozoic to Triassic from the FC, PC, and SRB. Cambrian rocks of the PC exhibit similar zircon age distributions with prominent ~1.4 and subordinate ~1.1 Ga populations, which are distinct from other Paleozoic strata. Plutonic rocks with these ages are common in southern Laurentia, whereas ~1.4 Ga zircons are uncommon in South American age distributions. This supports a Laurentian origin for Cuyania in isolation from Argentina during the Cambrian. Upper Paleozoic strata from the PC, FC, and SRB all yield similar age data suggesting shared provenance across the proposed Cuyania-Chilenia suture. Age distributions also notably lack Devonian-age grains. The regional paucity of Devonian plutonic rocks and detrital zircon casts doubt on a possible arc system between these terranes at this time, a key requisite for the mid-Paleozoic transfer and accretion of Chilenia to the Argentine margin. Collectively, these data question the precise boundaries of the

  13. Detrital zircon geochronology of the Cretaceous succession from the Iberian Atlantic Margin: palaeogeographic implications

    NASA Astrophysics Data System (ADS)

    Dinis, Pedro A.; Dinis, Jorge; Tassinari, Colombo; Carter, Andy; Callapez, Pedro; Morais, Manuel

    2016-04-01

    Detrital zircon U-Pb data performed on eight Cretaceous sandstone samples (819 age isotopic results) from the Lusitanian basin (west Portugal) constrain the history of uplift and palaeodrainage of western Iberia following break-up of Pangaea and opening of the North Atlantic Ocean. We examined the links between shifts in provenance and known basinwide unconformities dated to the late Berriasian, Barremian, late Aptian and Cenomanian-Turonian. The detrital zircon record of sedimentary rocks with wider supplying areas is relatively homogenous, being characterized by a clear predominance of late Palaeozoic ages (c. 375-275 Ma) together with variable proportions of ages in the range c. 800-460 Ma. These two groups of ages are diagnostic of sources within the Variscan Iberian Massif. A few samples also reveal significant amounts of middle Palaeozoic (c. 420-385 Ma) and late Mesoproterozoic to early Neoproterozoic (c. 1.2-0.9 Ga) zircon, which are almost absent in the basement to the east of the Lusitanian basin, but are common in terranes with a Laurussia affinity found in NW Iberia and the conjugate margin (Newfoundland). The Barremian unconformity marks a sudden rise in the proportion of c. 375-275 Ma zircon ages accompanied by a decrease in the abundance of the c. 420-385 Ma and c. 1.2-0.9 Ga ages. This shift in the zircon signature, which is contemporaneous with the separation of the Galicia Bank from Flemish Cap, reflects increased denudation of Variscan crystalline rocks and a reduction in source material from NW Iberia and adjoining areas. The late Aptian unconformity, which represents the largest hiatus in the sedimentary record, is reflected by a shift in late Palaeozoic peak ages from c. 330-310 Ma (widespread in Iberia) to c. 310-290 Ma (more frequent in N Iberia). It is considered that this shift in the age spectra resulted from a westward migration of catchment areas following major uplift in northern Iberia and some transport southward from the Bay of

  14. Provenance of north Gondwana Cambrian-Ordovician sandstone: U-Pb SHRIMP dating of detrital zircons from Israel and Jordan

    USGS Publications Warehouse

    Kolodner, K.; Avigad, D.; McWilliams, M.; Wooden, J.L.; Weissbrod, T.; Feinstein, S.

    2006-01-01

    A vast sequence of quartz-rich sandstone was deposited over North Africa and Arabia during Early Palaeozoic times, in the aftermath of Neoproterozoic Pan-African orogeny and the amalgamation of Gondwana. This rock sequence forms a relatively thin sheet (1-3 km thick) that was transported over a very gentle slope and deposited over a huge area. The sense of transport indicates unroofing of Gondwana terranes but the exact provenance of the siliciclastic deposit remains unclear. Detrital zircons from Cambrian arkoses that immediately overlie the Neoproterozoic Arabian-Nubian Shield in Israel and Jordan yielded Neoproterozoic U-Pb ages (900-530 Ma), suggesting derivation from a proximal source such as the Arabian-Nubian Shield. A minor fraction of earliest Neoproterozoic and older age zircons was also detected. Upward in the section, the proportion of old zircons increases and reaches a maximum (40%) in the Ordovician strata of Jordan. The major earliest Neoproterozoic and older age groups detected are 0.95-1.1, 1.8-1.9 and 2.65-2.7 Ga, among which the 0.95-1.1 Ga group is ubiquitous and makes up as much as 27% in the Ordovician of Jordan, indicating it is a prominent component of the detrital zircon age spectra of northeast Gondwana. The pattern of zircon ages obtained in the present work reflects progressive blanketing of the northern Arabian-Nubian Shield by Cambrian-Ordovician sediments and an increasing contribution from a more distal source, possibly south of the Arabian-Nubian Shield. The significant changes in the zircon age signal reflect many hundreds of kilometres of southward migration of the provenance. ?? 2006 Cambridge University Press.

  15. Detrital Zircon Geochronology of Cretaceous and Paleogene Strata Across the South-Central Alaskan Convergent Margin

    USGS Publications Warehouse

    Bradley, Dwight; Haeussler, Peter J.; O'Sullivan, Paul; Friedman, Rich; Till, Alison; Bradley, Dan; Trop, Jeff

    2009-01-01

    Ages of detrital zircons are reported from ten samples of Lower Cretaceous to Paleogene metasandstones and sandstones from the Chugach Mountains, Talkeetna Mountains, and western Alaska Range of south-central Alaska. Zircon ages are also reported from three igneous clasts from two conglomerates. The results bear on the regional geology, stratigraphy, tectonics, and mineral resource potential of the southern Alaska convergent margin. Chugach Mountains - The first detrital zircon data are reported here from the two main components of the Chugach accretionary complex - the inboard McHugh Complex and the outboard Valdez Group. Detrital zircons from sandstone and two conglomerate clasts of diorite were dated from the McHugh Complex near Anchorage. This now stands as the youngest known part of the McHugh Complex, with an inferred Turonian (Late Cretaceous) depositional age no older than 91-93 Ma. The zircon population has probability density peaks at 93 and 104 Ma and a smattering of Early Cretaceous and Jurassic grains, with nothing older than 191 Ma. The two diorite clasts yielded Jurassic U-Pb zircon ages of 179 and 181 Ma. Together, these findings suggest a Mesozoic arc as primary zircon source, the closest and most likely candidate being the Wrangellia composite terrane. The detrital zircon sample from the Valdez Group contains zircons as young as 69 and 77 Ma, consistent with the previously assigned Maastrichtian to Campanian (Late Cretaceous) depositional age. The zircon population has peaks at 78, 91, 148, and 163 Ma, minor peaks at 129, 177, 330, and 352 Ma, and no concordant zircons older than Devonian. A granite clast from a Valdez Group conglomerate yielded a Triassic U-Pb zircon age of 221 Ma. Like the McHugh Complex, the Valdez Group appears to have been derived almost entirely from Mesozoic arc sources, but a few Precambrian zircons are also present. Talkeetna Mountains - Detrital zircons ages were obtained from southernmost metasedimentary rocks of the

  16. 3. 96 Ga zircons from an Archean quartzite, Beartooth Mountains, Montana

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mueller, P.A.; Wooden, J.L.; Nutman, A.P.

    1992-04-01

    U-Pb isotopic systematics of detrital zircons incorporated in a middle Archean quartzite from the Beartooth Mountains, Montana, were investigated with the SHRIMP ion microprobe. These new data reveal an extended and previously unrecognized record of crustal evolution for the northern Wyoming province. Seventy-eight analyses of 67 grains yielded a range of {sup 207}Pb/{sup 206}Pb ages from 2.69 to 3.96 Ga. Concordant analyses from 43 separate grains defined a maximum age for the deposition of the quartzite of 3.30 Ga; other provenance ages extend to 3.96 Ga. Ages of < 3.30 Ga are generally discordant, and appear to reflect late Archeanmore » disturbance of the U-Pb system, including metamorphism at {approximately}2.8 Ga. The predominance of ages at {approximately}3.3 Ga is interpreted to represent the last major episode of crust formation prior to deposition of the quartzite. The concordant analyses of > 3.30 Ga indicate that older crustal components with ages up to 3.96 Ga, or detritus from them, were also in the provenance of this quartzite. This older age is equivalent to that of the oldest known rock from the Acasta gneisses of the Slave province and is exceeded only by the > 4.0 Ga age of detrital zircons of the Yilgarn block of Western Australia. These data support an increased probability for the survival of sialic crust created before the cessation of the late bombardment at 3.8 to 3.9 Ga.« less

  17. Detrital zircon geochronology of some neoproterozoic to triassic rocks in interior alaska

    USGS Publications Warehouse

    Bradley, D.C.; McClelland, W.C.; Wooden, J.L.; Till, A.B.; Roeske, S.M.; Miller, M.L.; Karl, Susan M.; Abbott, J.G.

    2007-01-01

    We report 777 U-Pb SHRIMP detrital zircon ages from thirteen sandstones and metasandstones in interior Alaska. About sixty grains per sample were analyzed; typically, half to three-fourths of these were concordant within ?? 10%. Farewell terrane. Two quartzites were collected from Ruby quadrangle and a third from Taylor Mountains quadrangle. All three are interpreted to represent a low stratigraphic level in the Nixon Fork platform succession; the samples from Ruby quadrangle are probably late Neoproterozoic, and the sample from Taylor Mountains quadrangle is probably Cambrian in age. The youngest detrital zircon in any of the three is 851 Ma. The two Ruby quadrangle samples area almost identical: one has a major age cluster at 1980-2087 and minor age clusters at 944-974 and 1366-1383 Ma; the other has a major age cluster at 1993-2095 Ma and minor age clusters at 912-946 and 1366-1395 Ma. The Taylor Mountains sample shows one dominant peak at 1914-2057 Ma. Notably absent are zircons in the range 1800-1900 Ma, which are typical of North American sources. The detrital zircon populations are consistent with paleontological evidence for a peri- Siberian position of the Farewell terrane during the early Paleozoic. Mystic subterrane of the Farewell terrane. Three graywackes from flysch of the Mystic subterrane, Talkeetna quadrangle, were sampled with the expectation that all three were Pennsylvanian. Asample from Pingston Creek is Triassic (as revealed by an interbedded ash dated at ca. 223 Ma) and is dominated by age clusters of 341-359 and 1804-1866 Ma, both consistent with a sediment source in the Yukon-Tanana terrane. Minor age clusters at 848-869 and 1992-2018 Ma could have been sourced in the older part of the Farewell terrane. Still other minor age clusters at 432-461, 620-657, 1509-1536, and 1627-1653 Ma are not readily linked to sources that are now nearby. Asample from Surprise Glacier is mid-Mississippian or younger. Adominant age cluster at 1855-1883 and a

  18. Late Proterozoic-Paleozoic evolution of the Arctic Alaska-Chukotka terrane based on U-Pb igneous and detrital zircon ages: Implications for Neoproterozoic paleogeographic reconstructions

    USGS Publications Warehouse

    Amato, J.M.; Toro, J.; Miller, E.L.; Gehrels, G.E.; Farmer, G.L.; Gottlieb, E.S.; Till, A.B.

    2009-01-01

    The Seward Peninsula of northwestern Alaska is part of the Arctic Alaska-Chukotka terrane, a crustal fragment exotic to western Laurentia with an uncertain origin and pre-Mesozoic evolution. U-Pb zircon geochronology on deformed igneous rocks reveals a previously unknown intermediate-felsic volcanic event at 870 Ma, coeval with rift-related magmatism associated with early breakup of eastern Rodinia. Orthogneiss bodies on Seward Peninsula yielded numerous 680 Ma U-Pb ages. The Arctic Alaska-Chukotka terrane has pre-Neoproterozoic basement based on Mesoproterozoic Nd model ages from both 870 Ma and 680 Ma igneous rocks, and detrital zircon ages between 2.0 and 1.0 Ga in overlying cover rocks. Small-volume magmatism occurred in Devonian time, based on U-Pb dating of granitic rocks. U-Pb dating of detrital zircons in 12 samples of metamorphosed Paleozoic siliciclastic cover rocks to this basement indicates that the dominant zircon age populations in the 934 zircons analyzed are found in the range 700-540 Ma, with prominent peaks at 720-660 Ma, 620-590 Ma, 560-510 Ma, 485 Ma, and 440-400 Ma. Devonian- and Pennsylvanian-age peaks are present in the samples with the youngest detrital zircons. These data show that the Seward Peninsula is exotic to western Laurentia because of the abundance of Neoproterozoic detrital zircons, which are rare or absent in Lower Paleozoic Cordilleran continental shelf rocks. Maximum depositional ages inferred from the youngest detrital age peaks include latest Proterozoic-Early Cambrian, Cambrian, Ordovician, Silurian, Devonian, and Pennsylvanian. These maximum depositional ages overlap with conodont ages reported from fossiliferous carbonate rocks on Seward Peninsula. The distinctive features of the Arctic Alaska-Chukotka terrane include Neoproterozoic felsic magmatic rocks intruding 2.0-1.1 Ga crust overlain by Paleozoic carbonate rocks and Paleozoic siliciclastic rocks with Neoproterozoic detrital zircons. The Neoproterozoic ages are

  19. Hf isotope compositions In detrital zircons as a new tool for provenance studies

    NASA Astrophysics Data System (ADS)

    Jacobsen, Y. J.; Münker, C.; Mezger, K.

    2003-04-01

    Identifying the provenance of continental sediments is a major issue in palaeo-tectonic studies, providing important information for paleogeographic reconstructions. Isotope studies, e.g. those of whole rock Sm-Nd or detrital zircon U-Pb dating, have widely been used for this purpose. Here we assess the potential of combined Lu-Hf data and U-Pb ages determined on the same single detrital zircons as a new tool for provenance studies. Due to the low Lu/Hf ratios in zircons the Hf isotope composition of a zircon changes insignificantly after its crystallization. Thus each particular grain preserves information on the Hf-siotpe composition of its source and the age of this source. Provided that both the U-Pb and Lu-Hf isotope systems have not been disturbed, this information can be used to constrain the sources of each individual zircon. In order to demonstrate the capability of Hf isotope studies on detrital zircons for provenance studies, we obtained combined U-Pb ages and Lu-Hf isotope data for zircons from the Cambrian Junction Formation in New Zealand. The Junction Formation was deposited on the (present) SE margin of Gondwana near the Australian continent and consists of turbidites, siltstones and conglomerates [1]. Typical continent derived Paleozoic sediments in SE Gondwana generally show characteristic age maxima at 500-600 Ma, 1000-1200 Ma (Grenvillian) and additional older peaks (early Proterozoic to Archean) [2]. We focused on two groups of detrital zircons with Grenvillian and Proterozoic to Late Archean ages. The initial ɛHf values for these zircons range from 0.7 to -15.5 for the Grenvillian and from -5.2 to -14.1 for the Proterozoic/Archean zircons. Corresponding two stage Hf model ages range from ca. 1500 to 2500 Ma for the Grenvillian and from ca. 3200 to 3600 Ma for the Proterozoic/Archean zircons. Furthermore it can be shown that the Grenvillian zircons must have been derived from recycled Grenvillian provinces. Comparison of these Hf model ages

  20. Detrital zircon geochronology of pre- and syncollisional strata, Acadian orogen, Maine Appalachians

    USGS Publications Warehouse

    Bradley, Dwight C.; O'Sullivan, Paul B.

    2017-01-01

    The Central Maine Basin is the largest expanse of deep-marine, Upper Ordovician to Devonian metasedimentary rocks in the New England Appalachians, and is a key to the tectonics of the Acadian Orogeny. Detrital zircon ages are reported from two groups of strata: (1) the Quimby, Rangeley, Perry Mountain and Smalls Falls Formations, which were derived from inboard, northwesterly sources and are supposedly older; and (2) the Madrid, Carrabassett and Littleton Formations, which were derived from outboard, easterly sources and are supposedly younger. Deep-water deposition prevailed throughout, with the provenance shift inferred to mark the onset of foredeep deposition and orogeny. The detrital zircon age distribution of a composite of the inboard-derived units shows maxima at 988 and 429 Ma; a composite from the outboard-derived units shows maxima at 1324, 1141, 957, 628, and 437 Ma. The inboard-derived units have a greater proportion of zircons between 450 and 400 Ma. Three samples from the inboard-derived group have youngest age maxima that are significantly younger than the nominal depositional ages. The outboard-derived group does not share this problem. These results are consistent with the hypothesised provenance shift, but they signal potential problems with the established stratigraphy, structure, and (or) regional mapping. Shallow-marine deposits of the Silurian to Devonian Ripogenus Formation, from northwest of the Central Maine Basin, yielded detrital zircons featuring a single age maximum at 441 Ma. These zircons were likely derived from a nearby magmatic arc now concealed by younger strata. Detrital zircons from the Tarratine Formation, part of the Acadian foreland-basin succession in this strike belt, shows age maxima at 1615, 980 and 429 Ma. These results are consistent with three episodes of zircon recycling beginning with the deposition of inboard-derived strata of the Central Maine Basin, which were shed from post-Taconic highlands located to the

  1. Proterozoic to Mesozoic evolution of North-West Africa and Peri-Gondwana microplates: Detrital zircon ages from Morocco and Canada

    NASA Astrophysics Data System (ADS)

    Marzoli, Andrea; Davies, Joshua H. F. L.; Youbi, Nasrrddine; Merle, Renaud; Dal Corso, Jacopo; Dunkley, Daniel J.; Fioretti, Anna Maria; Bellieni, Giuliano; Medina, Fida; Wotzlaw, Jörn-Frederik; McHone, Greg; Font, Eric; Bensalah, Mohamed Khalil

    2017-05-01

    The complex history of assemblage and disruption of continental plates surrounding the Atlantic Ocean is in part recorded by the distribution of detrital zircon ages entrained in continental sedimentary strata from Morocco (Central High Atlas and Argana basins) and Canada (Grand Manan Island, New Brunswick). Here we investigate detrital zircon from the latest Triassic (ca. 202 Ma) sedimentary strata directly underlying lava flows of the Central Atlantic magmatic province or interlayered within them. SHRIMP (Sensitive High-Resolution Ion MicroProbe) and LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry) U-Pb ages for zircon range from Paleozoic to Archean with a dominant Neoproterozoic peak, and significant amounts of ca. 2 Ga zircon. These ages suggest a prevailing West African (Gondwanan) provenance at all sampling sites. Notably, the Paleoproterozoic zircon population is particularly abundant in central Morocco, north of the High Atlas chain, suggesting the presence of Eburnean-aged rocks in this part of the country, which is consistent with recent geochronologic data from outcropping rocks. Minor amounts of late Mesoproterozoic and early Neoproterozoic zircon ages (ca. 1.1-0.9 Ga) in Moroccan samples are more difficult to interpret. A provenance from Avalonia or Amazonia, as proposed by previous studies is not supported by the age distributions observed here. An involvement of more distal source regions, possibly located in north-eastern Africa (Arabian Nubian Shield) would instead be possible. Paleozoic zircon ages are abundant in the Canadian sample, pointing to a significant contribution from Hercynian aged source rocks. Such a signal is nearly absent in the Moroccan samples, suggesting that zircon-bearing Hercynian granitic rocks of the Moroccan Meseta block were not yet outcropping at ca. 200 Ma. The only Moroccan samples that yield Paleozoic zircon ages are those interlayered within the CAMP lavas, suggesting an increased dismantling

  2. Involvement of old crustal materials during formation of the Sakhalin Island (Russian Far East) and its paleogeographic implication: Constraints from detrital zircon ages of modern river sand and Miocene sandstone

    NASA Astrophysics Data System (ADS)

    Zhao, Pan; Li, Jia-jin; Alexandrov, Igor; Ivin, Vitaly; Jahn, Bor-ming

    2017-09-01

    In order to decipher crustal nature of the Sakhalin Island in Russian Far East, we carried out detrital zircon U-Pb age analyses on Miocene sandstone and river sand from the longest river (Poronay River) of the Sakhalin Island. The detrital zircon data from two river sand samples display similar age distribution patterns with a dominant Mesozoic age group, subordinate age peaks at 1.8 Ga and 2.5 Ga, and a few Paleozoic and Neoproterozoic grains. The Miocene sandstone shows age peaks at 22, 84, 260 and 497 Ma, respectively, and a few Paleo-proterozoic grains. These age groups indicate that abundant old crustal materials have been involved in the crustal formation of the Sakhalin Island. Detrital zircon result reveals two episodes of post-accretion magmatism from the Sakhalin Island in ages of 37 Ma and 22-21 Ma. They can be correlated with coeval post-accretion magmatic events in the Hokkaido Island, supporting the geological correlation between the Sakhalin Island and the Hokkaido Island. Comparison of detrital zircon dating result from the Sakhalin Island with those from surrounding blocks and cratons in eastern Asia allows us to propose two possible sources in eastern Asia: the Bureya-Jiamusi-Khanka block with the Sikhote-Alin orogenic belt to its west and the South China Craton. The detrital zircon result indicates that the formation of the Sakhalin Island should be close to the East Asia continent, rather than as an independent intro-oceanic island arc within the Pacific Ocean. Similar to formation of the Japanese islands, the South China Craton may have played an important role during formation of the Sakhalin Island.

  3. Proterozoic tectonostratigraphy and paleogeography of central Madagascar derived from detrital zircon U-Pb age populations

    USGS Publications Warehouse

    Cox, R.; Coleman, D.S.; Chokel, C.B.; DeOreo, S.B.; Wooden, Joseph L.; Collins, A.S.; De Waele, B.; Kroner, A.

    2004-01-01

    Detrital zircon U‐Pb ages determined by SHRIMP distinguish two clastic sequences among Proterozoic metasedimentary rocks from central Madagascar. The Itremo Group is older: zircon data, stromatolite characteristics, and carbon isotope data all point to a depositional age around 1500–1700 Ma. The Molo Group is younger, deposited between ∼620 Ma (the age of the youngest zircon) and ∼560 Ma (the age of metamorphic overgrowths on detrital cores). Geochronologic provenance analysis of the Itremo Group points to sources in East Africa as well as local sources in central and southern Madagascar but provides no evidence for a detrital contribution from northern and eastern Madagascar nor from southern India. Detrital zircon and sedimentologic similarities between rocks of the Itremo Group and the Zambian Muva Supergroup suggest a lithostratigraphic correlation between the two. The Molo Group has a strong 1000–1100 Ma detrital signature that also indicates an east African provenance and suggests a Neoproterozoic geographic connection with Sri Lanka but shows no indication of input from the Dharwar craton and eastern Madagascar. Central Madagascar was probably juxtaposed with the Tanzanian craton in the Paleo‐ and Mesoproterozoic, whereas northern and eastern Madagascar were connected to India. Internal assembly of Madagascar postdates Neoproterozoic Molo Group sedimentation and is likely to have occurred at about 560 Ma.

  4. 3-D Characterization of Detrital Zircon Grains and its Implications for Fluvial Transport, Mixing, and Preservation Bias

    NASA Astrophysics Data System (ADS)

    Markwitz, V.; Kirkland, C. L.; Mehnert, A.; Gessner, K.; Shaw, J.

    2017-12-01

    Detrital zircon studies can suffer from selective loss of provenance information due to U-Pb age discordance, metamictization, metamorphic overprinting and fluviatile transport processes. The relationship between isotopic composition and zircon grain shape, and how grain shape is modified during transport, is largely unknown. We combine X-ray tomography with U-Pb geochronology to quantify how fluvial transport affects 3-D zircon shape, detrital age signature, and grain density along the Murchison River, whose catchment comprises Eoarchean to Early Paleozoic source rocks in Western Australia. We acquired tomographic volumes and isotopic data from 373 detrital zircons to document changes in size, shape and density in transport direction, and explore how grain shape, age spectra and the proportion of discordant material vary along the channel. Results show that shape characteristics are sensitive to transport distance, stream gradient, proximity to source material, and whether the source consists of primary or recycled zircons. With increasing transport distance, grain lengths decrease more than their widths. Furthermore, the loss of metamict grains occurs at a near constant rate, resulting in a linear increase of mean calculated zircon density by ca. 0.03 g/cm3 per 100 km transport distance. 3-D grain shape is therefore strongly linked to detrital age signature, and mean grain density is a function of the absolute transport distance. 3-D shape characteristics provide valuable information on detrital zircon populations, including the interaction between source materials with fluvial transport processes, which significantly affects preservation bias and, by inference, the representativeness of the sampled data.

  5. In situ detrital zircon (U-Th)/He thermochronology

    NASA Astrophysics Data System (ADS)

    Tripathy, A.; Monteleone, B. D.; van Soest, M. C.; Hodges, K.; Hourigan, J. K.

    2010-12-01

    Detrital studies of both sand and rock are relevant to many problems, ranging from the climate and tectonics feedback debate to the long-term record of orogenic evolution. When applying the conventional (U-Th)/He technique to such studies, two important issues arise. Often, only euhedral grains are permissible for analysis in order to make simple geometric corrections for α-recoil. In detrital samples, this is problematic because euhedral grains can be scarce due to mechanical abrasion during transport, and potentially introduce bias in favour of more proximally sourced grains. Second, inherent to detrital studies is the need to date many grains (>100) per sample to ensure a representative sampling of the sediment source region, thus making robust conventional detrital studies both expensive and time-consuming. UV laser microprobes can improve this by permitting careful targeting of the grain interior away from the α-ejection zone, rendering the α-recoil correction unnecessary, thus eliminating bias toward euhedral grains. In the Noble Gas, Geochemistry, and Geochronology Laboratory at ASU, apatite and zircon have been successfully dated using in situ methods. For this study, the conventional and in situ techniques are compared by dating zircons from a modern river sand that drains a small catchment in the Mesozoic-Cenozoic Ladakh Batholith in NW India. This sample has a simple provenance, which allows us to demonstrate the robustness of the in situ method. Moreover, different microbeam techniques will be explored to establish the most efficient approach to obtain accurate and precise U-Th concentrations using synrock, which is our powdered, homogenized, and reconstituted zircon-rock standard. Without this, such in situ U-Th data would be difficult to obtain. 117 zircons were dated using the conventional (U-Th)/He method, revealing dates ranging from 9.70±0.35 to 106.6±3.5 Ma (2σ) with the major mode at 26 Ma. For comparison, 44 grains were dated using the in

  6. Evidence for prolonged mid-Paleozoic plutonism and ages of crustal sources in east-central Alaska from SHRIMP U-Pb dating of syn-magmatic, inherited, and detrital zircon

    USGS Publications Warehouse

    Dusel-Bacon, C.; Williams, I.S.

    2009-01-01

    Sensitive high-resolution ion microprobe (SHRIMP) U-Pb analyses of igneous zircons from the Lake George assemblage in the eastern Yukon-Tanana Upland (Tanacross quadrangle) indicate both Late Devonian (???370 Ma) and Early Mississippian (???350 Ma) magmatic pulses. The zircons occur in four textural variants of granitic orthogneiss from a large area of muscovite-biotite augen gneiss. Granitic orthogneiss from the nearby Fiftymile batholith, which straddles the Alaska-Yukon border, yielded a similar range in zircon U-Pb ages, suggesting that both the Fiftymile batholith and the Tanacross orthogneiss body consist of multiple intrusions. We interpret the overall tectonic setting for the Late Devonian and Early Mississippian magmatism as an extending continental margin (broad back-arc region) inboard of a northeast-dipping (present coordinates) subduction zone. New SHRIMP U-Pb ages of inherited zircon cores in the Tanacross orthogneisses and of detrital zircons from quartzite from the Jarvis belt in the Alaska Range (Mount Hayes quadrangle) include major 2.0-1.7 Ga clusters and lesser 2.7-2.3 Ga clusters, with subordinate 3.2, 1.4, and 1.1 Ga clusters in some orthogneiss samples. For the most part, these inherited and core U-Pb ages match those of basement provinces of the western Canadian Shield and indicate widespread potential sources within western Laurentia for most grain populations; these ages also match the detrital zircon reference for the northern North American miogeocline and support a correlation between the two areas.

  7. U Pb and Lu Hf isotope record of detrital zircon grains from the Limpopo Belt Evidence for crustal recycling at the Hadean to early-Archean transition

    NASA Astrophysics Data System (ADS)

    Zeh, Armin; Gerdes, Axel; Klemd, Reiner; Barton, J. M., Jr.

    2008-11-01

    Detrital zircon grains from Beit Bridge Group quartzite from the Central Zone of the Limpopo Belt near Musina yield mostly ages of 3.35-3.15 Ga, minor 3.15-2.51 Ga components, and numerous older grains grouped at approximately 3.4, 3.5 and 3.6 Ga. Two grains yielded concordant Late Hadean U-Pb ages of 3881 ± 11 Ma and 3909 ± 26 Ma, which are the oldest zircon grains so far found in Africa. The combined U-Pb and Lu-Hf datasets and field relationships provide evidence that the sedimentary protolith of the Beit Bridge Group quartzite was deposited after the emplacement of the Sand River Gneisses (3.35-3.15 Ga), but prior to the Neoarchean magmatic-metamorphic events at 2.65-2.60 Ga. The finding of abundant magmatic zircon detritus with concordant U-Pb ages of 3.35-3.15 Ga, and 176Hf/ 177Hf of 0.28066 ± 0.00004 indicate that the Sand River Gneiss-type rocks were a predominant source. In contrast, detrital zircon grains older than approximately 3.35 Ga were derived from the hinterland of the Limpopo Belt; either from a so far unknown crustal source in southern Africa, possibly from the Zimbabwe Craton and/or a source, which was similar but not necessarily identical to the one that supplied the Hadean zircons to Jack Hills, Western Australia. The Beit Bridge Group zircon population at >3.35 Ga shows a general ɛHf t increase with decreasing age from ɛHf 3.9Ga = -6.3 to ɛHf 3.3-3.1Ga = -0.2, indicating that Hadean crust older than 4.0 Ga ( TDM = 4.45-4.36 Ga) was rejuvenated during magmatic events between >3.9 and 3.1 Ga, due to a successive mixing of crustal rocks with mantle derived magmas. The existence of a depleted mantle reservoir in the Limpopo's hinterland is reflected by the ˜3.6 Ga zircon population, which shows ɛHf 3.6Ga between -4.6 and +3.2. In a global context, our data suggest that a long-lived, mafic Hadean protocrust with some tonalite-trondhjemite-granodiorite constituents was destroyed and partly recycled at the Hadean/Archean transition, perhaps

  8. Petrogenesis, detrital zircon SHRIMP U-Pb geochronology, and tectonic implications of the Upper Paleoproterozoic Seosan iron formation, western Gyeonggi Massif, Korea

    NASA Astrophysics Data System (ADS)

    Kim, Chang Seong; Jang, Yirang; Samuel, Vinod O.; Kwon, Sanghoon; Park, Jung-Woo; Yi, Keewook; Choi, Seon-Gyu

    2018-05-01

    This study involves investigations on the Upper Paleoproterozoic iron formation (viz., Seosan iron formation) from the Seosan Group, Gyeonggi Massif of the southwestern Korean Peninsula. It occurs as thin banded layers within meta-arkosic sandstone, formed by alternating processes of chemical (hydrothermal) and detrital depositions under a shallow marine environment. It mainly consists of alternating layers of iron oxides, mostly hematite, and quartz. Minor amounts of magnetite surrounded by muscovite, clinopyroxene and amphibole indicate hydrothermal alteration since its formation. Meta-arkosic sandstone is composed of recrystallized or porphyroclastic quartz and microcline, with small amounts of hematite and pyrite clusters. The Seosan iron formation has high contents of total Fe2O3 and SiO2 with positive Eu anomalies similar to those of other Precambrian banded iron formations, and its formation is clearly related to hydrothermal alteration since its deposition. Detrital zircon SHRIMP U-Pb geochronology data from a meta-arkosic sandstone (SN-1) and an iron formation (SN-2) show mainly two age groups of ca. 2.5 Ga and ca. 1.9-1.75 Ga. This together with intrusion age of the granite gneiss (ca. 1.70-1.65 Ga) clearly indicate that the iron formations were deposited during the Upper Paleoproterozoic. The dominant Paleoproterozoic detrital zircon bimodal age peaks preserved in the Seosan iron formation compare well with those from the South China Craton sedimentary basins, reflecting global tectonic events related to the Columbia supercontinent in East Asia.

  9. Detrital zircon U-Pb geochronology and provenance of the Carboniferous-Permian glaciomarine pebbly slates in the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Wang, Q.; Zhu, D.; Zhao, Z.; Chung, S.; Li, C.; Sui, Q.; Fu, X.; Mo, X.

    2011-12-01

    Glaciomarine diamictites (including pebbly slate, pebbly siltstone, and pebbly sandstone) in the Tibetan Plateau are widely interpreted to have been associated with the deglaciation of the Indian continent. Guiding by zircon cathodoluminescence images, we determined U-Pb ages for detrital zircons from five typical Carboniferous-Permian pebbly slate samples from the Qiangtang, Lhasa, and Tethyan Himalaya of the Tibetan Plateau. The age distributions of detrital zircons from two samples (180 analyses) from Qiwu and Gangma Tso of the Qiangtang Terrane are similar, with two main age peaks ca. 579 and ca. 816 Ma and one minor age peak ca. 2490 Ma. Two samples (177 analyses) from Jiangrang and Damxung of the Lhasa Terrane define similar age distributions with two main age peaks ca. 539 and ca. 1175 Ma. Ages of detrital zircons from one sample (110 analyses) from Kangmar of the Tethyan Himalaya display main age peaks ca. 535, ca. 949, and ca. 2490 Ma. The ca. 816-Ma detrital zircons from the Qiangtang Terrane were most likely derived from the Lesser Himalaya, and the ca. 950-Ma detrital zircons from the Tethyan Himalaya might have been sourced from the High Himalaya, Eastern Ghats Province of the Indian plate and the Rayner Province of East Antarctica. The distinctive ca. 1175-Ma age population characteristic of zircons in the pebbly slates from the Lhasa Terrane is identical to the detrital zircons from the late Paleozoic sandstones (Zhu et al., 2011a) and the inherited zircons from the Mesozoic peraluminous granites (Zhu et al., 2011b) in this terrane, but significantly absent in the pebbly slates from both the Qiangtang and the Tethyan Himalayan terranes. The ca. 1175-Ma detrital zircons in the Lhasa Terrane were most likely sourced from the Albany-Fraser-Wilkes in southwestern Australia and East Antarctica. These new data obtained in this study reveal a distinct difference of detrital zircon provenance for the coeval Carboniferous-Permian glaciomarine pebbly slates

  10. U-Pb detrital zircon geochronology from the basement of the Central Qilian Terrane: implications for tectonic evolution of northeastern Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Liu, Changfeng; Wu, Chen; Zhou, Zhiguang; Yan, Zhu; Jiang, Tian; Song, Zhijie; Liu, Wencan; Yang, Xin; Zhang, Hongyuan

    2018-03-01

    The Tuolai Group dominates the Central Qilian Terrane, and there are different opinions on the age and tectonic attribute of the Tuolai Group. Based on large-scale geologic mapping and zircon dating, the Tuolai Group is divided into four parts: metamorphic supracrustal rocks, Neoproterozoic acid intrusive rocks, early-middle Ordovician acid intrusive rocks and middle Ordovician basic intrusive rocks. The metamorphic supracrustal rocks are the redefined Tuolai complex-group and include gneiss and schist assemblage by faulting contact. Zircon U-Pb LA-MC-ICP-MS dating was conducted on these samples of gneiss and migmatite from the gneiss assemblage, quartzite, two-mica schist and slate from the schist assemblage. The five detrital samples possess similar age spectra; have detrital zircon U-Pb main peak ages of 1.7 Ga with youngest U-Pb ages of 1150 Ma. They are intruded by Neoproterozoic acid intrusive rocks. Therefore, the Tuolai Group belonging to late Mesoproterozoic and early Neoproterozoic. With this caveat in mind, we believe that U-Pb detrital zircon dating, together with the geologic constraints obtained from this study and early work in the neighboring regions. We suggest that the formation age of the entire crystalline basement rocks of metasedimentary sequence from the Central Qilian Terrane should be constrained between the Late Mesoproterozoic and the Late Neoproterozoic, but not the previous Paleoproterozoic. The basement of the Central Qilian Terrane contains the typical Grenville ages, which indicates the Centre Qilian Terrane have been experienced the Grenville orogeny event.

  11. Central Antarctic provenance of Permian sandstones in Dronning Maud Land and the Karoo Basin: Integration of U Pb and TDM ages and host-rock affinity from detrital zircons

    NASA Astrophysics Data System (ADS)

    Veevers, J. J.; Saeed, A.

    2007-12-01

    In conjugate SE Africa and Antarctica, Early Permian sandstones of the Swartrant Formation of the Ellisras Basin, Vryheid Formation of the Karoo Basin, and Amelang Plateau Formation of Dronning Maud Land (DML) were deposited after Gondwanan glaciation on a westward paleoslope. We analysed detrital zircons for U-Pb ages by a laser ablation microprobe-inductively coupled plasma mass spectrometer (LAM-ICPMS) and attached age significance only to clusters of three or more overlapping analyses. We analysed Hf-isotope compositions by a multi-collector spectrometer (LAM-MC-ICPMS) and trace elements by electron microprobe (EMP) and ICPMS. These analyses indicate the rock type and source (whether crustal or juvenile mantle) of the host magma, and a "crustal" model age ( TDMC). The integrated analysis gives a more distinctive, and more easily interpreted, picture of crustal evolution in the provenance area than age data alone. Zircons from the Ellisras Basin are aged 2700-2540 Ma with minor populations about 2815 Ma and 2040 Ma, which correspond with the ages of the upslope parts of the proximal Kaapvaal Craton and Limpopo Belt. Mafic rock is the dominant host rock, and it reflects the Archean granite-greenstone terrane of the Kaapvaal Craton. The three Karoo Basin samples and the two DML samples have zircons with these common properties: (1) 1160-880 Ma, host magma mafic granitoid (< 65% SiO 2) derived from juvenile depleted mantle sources ( ɛHf positive) at 1.65 Ga and 1.35 Ga, with TDMC of 2.0-0.9 Ga; (2) 760 to 480 Ma, host magma granitoid and low-heavy rare earth element rock (?alkaline rock-carbonatite), derived from mixed crustal and juvenile depleted mantle sources ( ɛHf positive and negative) at 1.50 Ga and 1.35 Ga, with TDMC of 2.0-0.9 Ga. Together with similar detrital zircons in Triassic sandstone of SE Australia, these properties reflect those in upslope central Antarctica, indicating a provenance of ˜ 1000 Ma (Grenville) cratons embedded in 700-500 Ma (Pan

  12. Signatures of mountain building: Detrital zircon U/Pb ages from northeast Tibet

    USGS Publications Warehouse

    Lease, Richard O.; Burbank, Douglas W.; Gehrels, George E.; Wang, Zhicai; Yuan, Daoyang

    2007-01-01

    Although detrital zircon has proven to be a powerful tool for determining provenance, past work has focused primarily on delimiting regional source terranes. Here we explore the limits of spatial resolution and stratigraphic sensitivity of detrital zircon in ascertaining provenance, and we demonstrate its ability to detect source changes for terranes separated by only a few tens of kilometers. For such an analysis to succeed for a given mountain, discrete intrarange source terranes must have unique U/Pb zircon age signatures and sediments eroded from the range must have well-defined depositional ages. Here we use ∼1400 single-grain U/Pb zircon ages from northeastern Tibet to identify and analyze an area that satisfies these conditions. This analysis shows that the edges of intermontane basins are stratigraphically sensitive to discrete, punctuated changes in local source terranes. By tracking eroding rock units chronologically through the stratigraphic record, this sensitivity permits the detection of the differential rock uplift and progressive erosion that began ca. 8 Ma in the Laji Shan, a 10-25-km-wide range in northeastern Tibet with a unique U/Pb age signature.

  13. Detrital zircon geochronology and provenance of the Chubut Group in the northeast of Patagonia, Argentina

    NASA Astrophysics Data System (ADS)

    Navarro, Edgardo L.; Astini, Ricardo A.; Belousova, Elena; Guler, M. Verónica; Gehrels, George

    2015-11-01

    The Chubut Group constitutes the most widespread sedimentary unit in NE Patagonia, characterized by variable-energy fluvial deposits. U-Pb analysis of detrital zircons from two sections of the Chubut Group constraint the age of the oldest sedimentary rocks in the northeast of the Somuncurá - Cañadón Asfalto Basin. In the Cañadón Williams area, at San Jorge section, 20 km NW of Telsen locality, dating of 56 detrital zircons from a medium to coarse sandstone indicated a maximum depositional age of 109 ± 1 Ma (n = 4). These sandstones were interpreted to represent shallow channels, associated with a lacustrine system. In the Telsen locality, a laser ablation analysis of 115 detrital zircons from a medium to coarse-grained sandstone, from fluvial channel facies, yielded a maximum depositional age of ca. 106 ± 1 Ma (n = 8). Both ages are consistent with volcanic events of the Barremian to Albian age in the central Patagonian Andes Region. Cathodoluminescence images of zircons from the San Jorge sample suggest an igneous origin, which is further supported by Th/U values above 0.5 in most of the grains. The distribution of the statistical modes of the main age populations of detrital zircons for the two samples [182, 185 and 189 Ma for Telsen sample (T2S) and 181 ± 1 Ma for San Jorge sample (SJS)] matches the age of the volcanic Marifil Formation. The rocks of the Marifil Formation of these ages are exposed NE to SE of the study area. The abundance of zircons of similar Jurassic ages (n = 52 for SJS and n = 105 for T2S) and the external morphology of the zircons in the sample SJS, implies a close proximity of the source area. Suggestion that the Marifil Formation was the main provenance source is also supported by northeast-southeasterly paleocurrents measured at the San Jorge and Telsen sections.

  14. U-Pb Dating of Unabraded Detrital Zircon Metamorphic Rims in the Nanaimo Basin, British Columbia

    NASA Astrophysics Data System (ADS)

    Boivin, M. P.; Guest, B.; Matthews, W.

    2016-12-01

    Thin metamorphic rims on detrital zircons from the Nanaimo Basin in SW British Columbia offer a unique opportunity to further constrain the source of these zircons, helping to resolve the long standing Baja BC controversy. Here we present an analytical approach for dating thin zircon rims and use it to show that zircons from the Nanaimo Basin are most likely derived from metamorphic rocks in southern California. Conventional in-situ laser ablation sample preparation typically requires mounting and polishing zircon grains to expose their core. However, in order to date these thin metamorphic zircon rims a depth-profiling approach on unabraded grains was employed. Zircon grains from the Upper Cretaceous Geoffrey, Spray, and Gabriola formations of the Nanaimo Group exposed on Denman and Hornby Islands (British Columbia) were sorted into five groups based on morphology. The zircons were then mounted on tape along with several grains of a well-characterised zircon reference material to validate the uncertainty of the method. The zircons were then imaged using a Zygo Zescope optical profilometer in order to correct for grain-to-grain variations in elevation relative to mounting medium and ensure consistent laser focus. Backscatter electron images (BSE) were used to further characterised the grains and optimize the location of laser ablation targets. Zircons were ablated using a Resonetics 193 nm excimer laser and uranium and lead isotopic ratios were measured using an Agilent 7700 quadrupole mass spectrometer. A low frequency laser repetition rate extended the data collection period on relatively thin zircon rims. Our results show that metamorphic zircon growth occurred in two main phases at 100 Ma and 77 Ma suggesting two sources of detrital zircons with differing metamorphic histories were present in the catchment area. The timing of metamorphism of the source area for the Nanaimo basin is inconsistent with derivation from sources in the Rocky Mountains (Lemhi sub

  15. What can zircon ages from the Jack Hills detrital zircon suite really tell us about Hadean geodynamics?

    NASA Astrophysics Data System (ADS)

    Whitehouse, Martin; Nemchin, Alexander

    2015-04-01

    As the only direct sample of the Hadean Earth, detrital zircon grains from the Jack Hills, Western Australia, have been the subject of intense investigation over the almost three decades since their discovery. A wide variety of geochemical and isotopic analyses of these grains, as well as their mineral inclusions, have been used variously to support two fundamentally different models for Hadean geodynamics: (i) Some form of (not necessarily modern-style) plate recycling generating felsic (continental-type?) crust at the boundaries [1, 2], or conversely (ii) the persistence of a long-lived, stagnant basaltic lid within which magmatism occurred as a result of internal temperature perturbations and/or impacts [3, 4], a model also generally consistent with a wide range of observations from post-Hadean geochemical reservoirs. Despite the considerable time and resources expended, the majority of these studies uncritically accept the individual U-Pb zircon ages, even though their veracity is key to many of the interpretations [5, 6]. We report here the results of an in-depth evaluation of all published (and new) U-Pb ages from the Jack Hills zircon suite in order to define age populations that can be used with a high degree of confidence in geodynamic interpretations. A notable problem in the interpretation of U-Pb data from ancient zircon grains (including those as young as the Neoarchean) is that disturbance of the systematics even several 100 Ma after crystallization causes data to spread along the concordia curve without becoming discernably discordant within the relatively large error bounds associated with U/Pb ages from in situ dating methods (e.g. SIMS). While 207Pb/206Pb ages are typically more precise, individually they provide no means to detect Pb-loss-induced younging. However, if two or preferably more analyses have been made in the same zircon growth zone, a reasonable evaluation of the possibility of Pb-loss can be made. In the available Jack Hills zircon

  16. New insights into Arctic paleogeography and tectonics from U-Pb detrital zircon geochronology

    USGS Publications Warehouse

    Miller, E.L.; Toro, J.; Gehrels, G.; Amato, J.M.; Prokopiev, A.; Tuchkova, M.I.; Akinin, V.V.; Dumitru, T.A.; Moore, Thomas E.; Cecile, M.P.

    2006-01-01

    To test existing models for the formation of the Amerasian Basin, detrital zircon suites from 12 samples of Triassic sandstone from the circum-Arctic region were dated by laser ablation-inductively coupled plasma-mass spectrometry (ICP-MS). The northern Verkhoyansk (NE Russia) has Permo-Carboniferous (265-320 Ma) and Cambro-Silurian (410-505 Ma) zircon populations derived via river systems from the active Baikal Mountain region along the southern Siberian craton. Chukotka, Wrangel Island (Russia), and the Lisburne Hills (western Alaska) also have Permo-Carboniferous (280-330 Ma) and late Precambrian-Silurian (420-580 Ma) zircons in addition to Permo-Triassic (235-265 Ma), Devonian (340-390 Ma), and late Precambrian (1000-1300 Ma) zircons. These ages suggest at least partial derivation from the Taimyr, Siberian Trap, and/ or east Urals regions of Arctic Russia. The northerly derived Ivishak Formation (Sadlerochit Mountains, Alaska) and Pat Bay Formation (Sverdrup Basin, Canada) are dominated by Cambrian-latest Precambrian (500-600 Ma) and 445-490 Ma zircons. Permo-Carboniferous and Permo-Triassic zircons are absent. The Bjorne Formation (Sverdrup Basin), derived from the south, differs from other samples studied with mostly 1130-1240 Ma and older Precambrian zircons in addition to 430-470 Ma zircons. The most popular tectonic model for the origin of the Amerasian Basin involves counterclockwise rotation of the Arctic Alaska-Chukotka microplate away from the Canadian Arctic margin. The detrital zircon data suggest that the Chukotka part of the microplate originated closer to the Taimyr and Verkhoyansk, east of the Polar Urals of Russia, and not from the Canadian Arctic. Copyright 2006 by the American Geophysical Union.

  17. Detrital zircon age patterns from turbidites of the Balagne and Piedmont nappes of Alpine Corsica (France): Evidence for an European margin source

    NASA Astrophysics Data System (ADS)

    Lin, Wei; Rossi, Philippe; Faure, Michel; Li, Xian-Hua; Ji, Wenbin; Chu, Yang

    2018-01-01

    At the front of metamorphic Cenozoic Alpine nappe of Schistes Lustrés, Western Alpine Corsica (France) exposes non- to very low grade metamorphic nappes, such as the Piedmont nappes, Upper nappes, and the Balagne nappe. The provenance of the Balagne nappe remains still opened: an origin close to the Corsican continental margin; or an origin far East from the Corsican margin toward the "Apenninic" oceanic domain. This would constrain that the Balagne ophiolite be derived from the opposite OCT (Ocean - Continent transition), close to a microcontinent located to the East of the Mesozoic Corsican margin. A systematic U-Pb dating of 586 detrital zircon grains collected from the turbidites in the Balagne and Piedmont nappes has been performed to constrain the source of sediments. The zircon grains yield U-Pb age spectra ranging from Neoarchean to Late Paleozoic with age peaks at 2600 Ma, 2080 Ma, 1830 Ma, 910 Ma, 600 Ma, 560 Ma, 450 Ma, 330 Ma and 280 Ma with different continental model ages (TDM2) from 3.5 Ga to 1.0 Ga. The variety of composition of the Corsican batholith, unique in its present Mediterranean environment, and in spite of Alpine transcurrent movements, provide a key to analyze the detrital zircon age distribution patterns of sedimentary rocks. These new results i) confirm the lack of any Cretaceous zircon that validates absence of a magmatic arc of this age, at least in the surroundings of the turbiditic formations from the Balagne and the Piedmont nappes; ii) fully support an European provenance of detritus of the Balagne nappe, iii) put forward evidence that no ophiolitic zircon was contained neither in the Cretaceous nor in the Eocene turbidites samples, and iv) question both the deposition of the Piedmont Narbinco flysch within the ocean continent transition and its possible relationships with the Late Cretaceous Pyrenean basins.

  18. Ti-in-Zircon Thermometer: Preliminary Results

    NASA Astrophysics Data System (ADS)

    Fu, B.; Cavosie, A. J.; Clechenko, C. C.; Fournelle, J.; Kita, N. T.; Lackey, J.; Page, F.; Wilde, S. A.; Valley, J. W.

    2005-12-01

    The titanium in zircon thermometer has been applied to 167 zircons from diverse rock types. These rocks include metamorphosed anorthosite and gabbro (1.15 Ga, intrusion age), and unmetamorphosed granitic pegmatite (0.9 Ga) from the Adirondack Highlands; metaluminous and peraluminous granites (114-90 Ma) of the Sierra Nevada Batholith; megacrysts from kimberlite pipes in southern Africa, Brazil, and Siberia; and detrital zircons (4.4-3.9 Ga) of metaconglomerate from Jack Hills, Western Australia. Titanium concentration in zircon was analysed using a CAMECA IMS-1280 ion microprobe (see Page et al., this volume). Spot analyses were correlated to U-Pb SHRIMP pits especially for Adirondack and Jack Hills zircons. The majority of zircons have Ti-content less than 10 ppm. Variability, in excess of analytical precision, within individual zircons is observed in about one-third of crystals. In general, there is no systematic change in Ti from core to rim (identified by cathodoluminescence) of zircons, or with regard to age, U content, Th/U ratio, or U-Pb age concordance for these non-metamict grains. The average temperatures for zircon crystallization in different rock suites using the experimental/empirical calibration of Watson and Harrison (W&H, 2005, Science 308:841), assuming the presence of rutile and quartz, are estimated to be: anorthosite 735±41°C (1SD, n=24; Ti = 10±5 ppm); metagabbro 714±31°C (n=19; Ti = 8±4 ppm); Adirondack pegmatite 500±16°C (n=5; Ti = 0.3±0.1 ppm); metaluminous and peraluminous granites from Sierra Nevada 681±67°C (n=53; Ti = 6±5 ppm) and 613±75°C (n=68; Ti = 3±3 ppm); kimberlite megacrysts 740±64°C (n=169; Ti = 14±13 ppm) (Page et al., this volume); and detrital zircons from Jack Hills metaconglomerate 718±63°C (n=64; Ti = 10±9 ppm). Most of the host rocks contain ilmenite or titanite suggesting that α(TiO2)>0.5, but rutile activity is unknown for megacrysts and detrital zircons. Pegmatite contains no Ti-rich minerals

  19. Creation of a continent recorded in zircon zoning

    USGS Publications Warehouse

    Moser, D.E.; Bowman, J.R.; Wooden, J.; Valley, J.W.; Mazdab, F.; Kita, N.

    2008-01-01

    We have discovered a robust microcrystalline record of the early genesis of North American lithosphere preserved in the U-Pb age and oxygen isotope zoning of zircons from a lower crustal paragneiss in the Neoarchean Superior province. Detrital igneous zircon cores with ??18O values of 5.1???-7.1??? record creation of primitive to increasingly evolved crust from 2.85 ?? 0.02 Ga to 2.67 ?? 0.02 Ga. Sharp chemical unconformity between cores and higher ??18O (8.4???-10.4???) metamorphic overgrowths as old as 2.66 ?? 0.01 Ga dictates a rapid sequence of arc unroofing, burial of detrital zircons in hydrosphere-altered sediment, and transport to lower crust late in upper plate assembly. The period to 2.58 ?? 0.01 Ga included ???80 m.y. of high-temperature (???700-650 ??C), nearly continuous overgrowth events reflecting stages in maturation of the subjacent mantle root. Huronian continental rifting is recorded by the youngest zircon tip growth at 2512 ?? 8 Ma (??? 600 ??C) signaling magma intraplating and the onset of rigid plate behavior. This >150 m.y. microscopic isotope record in single crystals demonstrates the sluggish volume diffusion of U, Pb, and O in zircon throughout protracted regional metamorphism, and the consequent advances now possible in reconstructing planetary dynamics with zircon zoning. ?? 2008 The Geological Society of America.

  20. Detrital zircon ages in Korean mid-Paleozoic meta-sandstones (Imjingang Belt and Taean Formation): Constraints on tectonic and depositional setting, source regions and possible affinity with Chinese terranes

    NASA Astrophysics Data System (ADS)

    Han, Seokyoung; de Jong, Koen; Yi, Keewook

    2017-08-01

    Sensitive High-Resolution Ion Microprobe (SHRIMP) U-Th-Pb isotopic data of detrital zircons from mature, quartz-rich meta-sandstones are used to constrain possible tectonic affinities and source regions of the rhythmically layered and graded-bedded series in the Yeoncheon Complex (Imjingang Belt) and the correlative Taean Formation. These metamorphic marine turbidite sequences presently occur along the Paleoproterozoic (1.93-1.83 Ga) Gyeonggi Massif, central Korea's main high-grade metamorphic gneiss terrane. Yet, detrital zircons yielded highly similar multimodal age spectra with peaks that do not match the age repartition in these basement rocks, as late (1.9-1.8 Ga) and earliest (∼ 2.5 Ga) Paleoproterozoic detrital modes are subordinate but, in contrast, Paleozoic (440-425 Ma) and Neoproterozoic (980-920 Ma) spikes are prominent, yet the basement essentially lacks lithologies with such ages. The youngest concordant zircon ages in each sample are: 378, 394 and 423 Ma. The maturity of the meta-sandstones and the general roundness of zircons of magmatic signature, irrespective of their age, suggest that sediments underwent considerable transport from source to sink, and possibly important weathering and recycling, which may have filtered out irradiation-weakened metamorphic zircon grains. In combination with these isotopic data, presence of a low-angle ductile fault contact between the Yeoncheon Complex and the Taean Formation and the underlying mylonitized Precambrian basement implies that they are in tectonic contact and do not have a stratigraphic relationship, as often assumed. Consequently, in all likelihood, both meta-sedimentary formations: (1) are at least of early Late Devonian age, (2) received much of their detritus from distant (reworked) Silurian-Devonian and Early Neoproterozoic magmatic sources, not present in the Gyeonggi Massif, (3) and not from Paleoproterozoic crystalline rocks of this massif, or other Korean Precambrian basement terranes, and

  1. Ancient Laurentian detrital zircon in the closing Iapetus Ocean, Southern Uplands terrane, Scotland

    NASA Astrophysics Data System (ADS)

    Waldron, John W. F.; Floyd, James D.; Simonetti, Antonio; Heaman, Larry M.

    2008-07-01

    Early Paleozoic sandstones in the Southern Uplands terrane ofScotland were deposited during closure of the Iapetus Oceanbetween Laurentia and Avalonia. Their tectonic setting and sourcesare controversial, and different authors have supported subduction-accretion,extensional continental-margin development, or back-arc basinsettings. We report new U-Pb detrital zircon ages from fiveLate Ordovician sandstones from the Northern Belt of the SouthernUplands and test models of their tectonic setting. The U-Pbzircon age distributions are dominated by peaks characteristicof sources in Laurentia and include grains as old as 3.6 Ga,older than any previously recorded in the British CaledonidesSE of the Laurentian foreland. Discordant grains in one samplesuggest derivation via erosion of metasedimentary rocks incorporatedin the Grampian-Taconian orogen. Rare Neoproterozoic grains,previously interpreted as originating from a peri-Gondwananterrane, may be derived from igneous rocks associated with Iapetanrifting. Only rare zircons are contemporary with the depositionalages. The results are difficult to reconcile with extensionalcontinental-margin and back-arc models, but they support anactive continental-margin subduction-accretion model. Closesimilarities with distributions from the Newfoundland Appalachiansare consistent with sinistral transpression during closing ofthe Iapetus Ocean.

  2. Applications of biotite inclusion composition to zircon provenance determination

    NASA Astrophysics Data System (ADS)

    Bell, Elizabeth A.; Boehnke, Patrick; Mark Harrison, T.

    2017-09-01

    Detrital zircons are the only confirmed surviving remnants of >4.03 Ga crust while younger detrital zircons provide a parallel record of more recent crustal evolution to that preserved in crystalline rocks. Zircons often preserve inclusions that may provide clues as to the origins of out-of-context grains in the sedimentary record. Previous studies have established that inclusions of biotite in magmatic zircon are compositionally well-matched to biotite in the source rock matrix, although a direct application to ancient detrital zircons has not been made. A number of studies have documented variations in the Fe, Mg, and Al contents of magmatic biotite from different source rocks and tectonic settings, suggesting that biotite inclusions may indeed serve as provenance indicators for detrital zircons. Consistent with earlier studies, we find that the FeO*/MgO ratio of magmatic biotite from continental arcs, collisional, and within-plate settings varies with relative oxidation state as well as whole-rock FeO*/MgO, while its Al2O3/(FeO* + MgO) varies with whole-rock A/CNK (molar Al/(2 ṡ Ca + Na + K)). Biotite from oxidized metaluminous and reduced S-type granitoids can be readily distinguished from each other using FeO*/MgO and Al2O3/(FeO* + MgO), while biotite from reduced I-type and oxidized peraluminous granites may in some cases be more ambiguous. Biotite from peralkaline and reduced A-type granites are also distinguishable from all other categories by Al2O3/(FeO* + MgO) and FeO*/MgO, respectively. Biotite inclusions in Hadean zircons from Jack Hills, Western Australia indicate a mixture of metaluminous and reduced S-type host rocks, while inclusions in 3.6-3.8 Ga detrital zircons from the Nuvvuagittuq Supracrustal Belt indicate more oxidized peraluminous magmas. These results highlight the diversity of felsic materials on the early Earth and suggest that biotite inclusions are applicable to zircon provenance throughout the sedimentary record.

  3. Silicic melt evolution in the early Izu-Bonin arc recorded in detrital zircons: Zircon U-Pb geochronology and trace element geochemistry for Site U1438, Amami Sankaku Basin

    NASA Astrophysics Data System (ADS)

    Barth, A. P.; Tani, K.; Meffre, S.; Wooden, J. L.; Coble, M. A.

    2016-12-01

    Understanding the petrologic evolution of oceanic arc magmas through time is important because these arcs reveal the processes of formation and the early evolution of juvenile continental crust. The Izu-Bonin (IB) arc system has been targeted because it is one of several western Pacific intraoceanic arcs initiated at 50 Ma and because of its prominent spatial asymmetry, with widespread development of relatively enriched rear arc lavas. We examined Pb/U and trace element compositions in zircons recovered at IODP Site 351-U1438 and compared them to regional and global zircon suites. These new arc zircon data indicate that detrital zircons will yield new insights into the generation of IB silicic melts and form a set of useful geochemical proxies for interpreting ancient arc detrital zircon provenance. Project IBM drilling target IBM1 was explored by Expedition 351 at Site U1438, located in the proximal back-arc of the northern Kyushu-Palau Ridge (KPR) at 27.3°N. A 1.2 km thick section of Paleogene volcaniclastic rocks, increasingly lithified and hydrothermally altered with depth, constitutes a proximal rear arc sedimentary record of IB arc initiation and early arc evolution. The ages and compositions of U1438 zircons are compatible with provenance in one or more edifices of the northern KPR and are incompatible with drilling contamination. Melt zircon saturation temperatures and Ti-in-zircon thermometry suggest a provenance in relatively cool and silicic KPR melts. The abundances of selected trace elements with high native concentrations provide insight into the petrogenesis of U1438 detrital zircon host melts, and may be useful indicators of both short and long-term variations in melt compositions in arc settings. The U1438 zircons are slightly enriched in U and LREE and are depleted in Nb compared to zircons from mid-ocean ridges and the Parece-Vela Basin, as predicted for melts in a primitive oceanic arc setting with magmas derived from a highly depleted mantle

  4. First U-Pb geochronology on detrital zircons from Early-Middle Cambrian strata of the Torgau-Doberlug Syncline (eastern Germany) and palaeogeographic implications

    NASA Astrophysics Data System (ADS)

    Abubaker, Atnisha; Hofmann, Mandy; Gärtner, Andreas; Linnemann, Ulf; Elicki, Olaf

    2017-10-01

    LA-ICP-MS U-Pb data from detrital zircons of the Ediacaran to Cambrian siliciclastic sequence of the Torgau-Doberlug Syncline (TDS, Saxo-Thuringia, Germany) are reported for the first time. The majority of 203 analysed zircon grains is Proterozoic with minor amount of Archean and Palaeozoic grains. The U-Pb ages fall into three groups: 2.8-2.4 Ga (3%), Neoarchean to earliest Palaeoproterozoic; 2.3-1.6 Ga (46%), early to late Palaeoproterozoic; 1.0-0.5 Ga (47%), Neoproterozoic to Cambrian. This age distribution is typical for the West African Craton as the source area and for Cadomian orogenic events in northwestern Gondwana. The samples show an age gap between 1.6 and 1.0 Ga, which is characteristic for West African provenance and diagnostic in distinguishing this unit from East Avalonia and Baltica. The dataset shows clusters of Palaeoproterozoic ages at 2.2-1.7 Ga, that is typical for western Gondwana, which was affected by abundant magmatic intrusions (ca. 2.2-1.8 Ga) during the Eburnean orogeny (West African craton). Neoarchean zircon ages (3%) point to recycling of magmatic rocks formed during the Liberian and Leonian orogenies. Ediacaran to earliest Cambrian rocks of the TDS originated in an active margin regime of the Gondwanan shelf. The following early Palaeozoic overstep sequence was deposited within rift settings that reflects instability of the West-Gondwanan shelf and the separation of terranes from Ordovician onward. The results of this study demonstrate distinct northwestern African provenance of the Cambrian siliciclastics of the TDS. Due to Th-U ratios from concordant zircon analysis, igneous origin from felsic melts is concluded as the source of these grains.

  5. Triassic deposits of the Chukotka Arctic continental margin (sedimentary implications and detrital zircon data)

    NASA Astrophysics Data System (ADS)

    Tuchkova, Marianna; Sokolov, Sergey; Verzhbitsky, Vladimir

    2013-04-01

    Triassic clastic deposits of Chukotka are represented by rhythmic intercalation of sandstones, siltstones and mudstones. During the Triassic, sedimentation was represented by continental slope progradation. Detrital zircons from Triassic sedimentary rocks were collected for constrain its paleogeographic links to source terranes. Zircons populations from three Chukotka's samples are very similar, and youngest zircon ages show peaks at 236-255 Ma (Miller et al., 2006). Lower Triassic sandstones from the Chaun subterrane do not contain the young population 235-265 Ma that is characteristic of the Upper Triassic rocks from the Anyui subterrane and Wrangel Island. The young zircon population is missing also from the coeval Sadlerochit Group (Alaska) and Blind Fiord Formation of the Sverdrup basin (Miller et al., 2006; Omma et al., 2011). Our data of Triassic sandstones of Wrangel island demonstrate detrital zircons ages dominated by Middle Triassic (227-245 Ma), Carboniferous (309-332 Ma) and Paleoproterozoic (1808-2500 Ma) ages. The new data on Chukotka show that populations of detrital zircons from Chukotka, the Sverdrup basin, and Alaska, the Sadlerochit Mountains included, demonstrate greater similarity than it was previously thought. Consequently, it may be assumed that they originate from a single source situated in the north. The data on zircon age of gabbro-dolerite magmatism in eastern Chukotka (252 Ma. Ledneva et al., 2011) and K-Ar ages obtained for sills and small intrusive bodies (Geodynamics…, 2006) in Lower Triassic deposits allow the local provenance. The presence of products of synchronous magmatism and shallow-water facies in the Lower Triassic sequences confirm this assumption. At the same time, coeval zircons appear only in the Upper Triassic strata. It is conceivable that the young zircon population originates from intrusive, not volcanic rocks, which were subjected to erosion only in the Late Triassic. In our opinion, the assumption of the local

  6. Development of the Archaean Mallina Basin, Pilbara Craton, northwestern Australia; a study of detrital and inherited zircon ages

    NASA Astrophysics Data System (ADS)

    Smithies, R. H.; Nelson, D. R.; Pike, G.

    2001-06-01

    SHRIMP U-Pb zircon dates are combined with an examination of the age distribution patterns and provenance of both detrital zircons and of zircon xenocrysts in granites to investigate the development of the Archaean Mallina Basin, in the granite-greenstone terrain of the Pilbara Craton, northwestern Australia. The oldest dated components of the basin are c. 3010 Ma volcaniclastic rocks in the western part of the area. New data indicate that siliciclastic turbidites that dominate the southern and eastern part of the basin were deposited at or after c. 2970 Ma but before c. 2955 Ma. Linking both the detrital zircon populations as well as zircon xenocrysts from granites that intruded the Mallina Basin to well-dated areas of the Pilbara granite-greenstone terrane indicates that the sediment was derived from the south, north, northwest, and east. The basin probably evolved primarily in an intracontinental setting between two elevated land masses to the southeast and northwest. Most of the rocks within the basin were folded before intrusion of granites, the oldest of which has been dated at 2954±4 Ma. Evidence of a second depositional cycle is provided by a maximum depositional age of 2941±9 Ma, indicated by a detrital zircon population from a sample of wacke from the southeast part of the Mallina Basin. This second depositional phase may have been related to renewed extension, and recycling of sedimentary rocks within the basin.

  7. The earth's oldest known crust - A geochronological and geochemical study of 3900-4200 Ma old detrital zircons from Mt. Narryer and Jack Hills, Western Australia

    NASA Astrophysics Data System (ADS)

    Maas, Roland; Kinny, Peter D.; Williams, Ian S.; Froude, Derek O.; Compston, William

    1992-03-01

    Trace element characteristics were analyzed and inclusions were identified within a suite of pre-3.9 Ga detritral zircons from western Australia representing the earth's oldest-known minerals. A diversity of trace-element compositions was found, particularly in the REE compositions of the old Mt. Narryer zircons, implying a variety of source-rock compositions and hence, the presence of a differentiated crust in the earth 4.15-4.20 Ga ago. Comparisons drawn with data obtained from younger detrital zircons occurring within the same deposits indicate nothing unique about the chemical compositions of the old grains. A number of interelement covariations were observed among the analyzed grains which were independent of age and isotopic characteristics, most notably that occurring between Lu and Hf. A general positive correlation between total LREE and the U + Th contents is also apparent. The findings indicate an origin in felsic igneous rocks, which has implications for early-Archaean crustal evolution.

  8. Evidence From Detrital Zircon U-Pb Analysis for Suturing of Pre-Mississippian Terranes in Arctic Alaska

    NASA Astrophysics Data System (ADS)

    Moore, T. E.; Potter, C. J.; O'Sullivan, P. B.; Aleinikoff, J. N.

    2007-12-01

    Detrital zircon U-Pb ages of pre-Mississippian sandstones were determined using SHRIMP and LA-ICPMS techniques for four key geographic parts of the Arctic Alaska terrane, northern Alaska. In the northeastern Brooks Range, a sample of quartz-rich turbidites from the Proterozoic Neroukpuk Quartzite yielded zircon ages ranging from 980 Ma to 2.9 Ga with clusters at 980-1100 Ma, 1680-1850 Ma and 2220-2660 Ma. Quartz and chert-bearing sandstone in the Tulageak well from Ordovician-Silurian argillite in basement beneath the North Slope yielded a broad spectrum of ages between 1.0 to 2.1 Ga and 2.8 Ga, including peaks at 1.0-1.2 and 1.5-1.7 Ga. Paleozoic zircons cluster at 390 and 440 Ma in this sample, indicating it is Devonian. Lithic sandstone from the Silurian Iviagik Group at Cape Dyer on the Lisburne Peninsula yielded a variety of ages from 450 to 1600 Ma, with a large peak at 475-600 Ma and several grains between 1.9 and 2.5 Ga. In contrast to the broad distributions of the latter two samples, zircons in metamorphosed Proterozoic-Cambrian(?) lithic sandstone from the an unnamed metagraywacke unit near Mt. Snowden on the Dalton Highway in the southern Brooks Range are largely 600-650 Ma with lesser clusters at 1050-1200 Ma and 1600-1900 Ga. Samples of quartz-rich Mississippian sandstone at the base of the unconformably overlying Mississippian to Triassic Ellesmerian sequence near three of the pre-Mississippian sample locations were also analyzed. Mississippian sandstones from the West Dease well (near the Tulageak well) and at Cape Dyer on the Lisburne Peninsula display zircon distributions similar to those found in the underlying pre-Mississippian samples, indicating the Mississippian clastic strata are locally derived and that the observed zircon distributions are representative of a broad area. However, the Mississippian Kekiktuk Conglomerate, which rests on the Neroukpuk Quartzite in the northeastern Brooks Range, also contains a variety of ages between 560 and

  9. Reliability and longitudinal change of detrital-zircon age spectra in the Snake River system, Idaho and Wyoming: An example of reproducing the bumpy barcode

    NASA Astrophysics Data System (ADS)

    Link, Paul Karl; Fanning, C. Mark; Beranek, Luke P.

    2005-12-01

    Detrital-zircon age-spectra effectively define provenance in Holocene and Neogene fluvial sands from the Snake River system of the northern Rockies, U.S.A. SHRIMP U-Pb dates have been measured for forty-six samples (about 2700 zircon grains) of fluvial and aeolian sediment. The detrital-zircon age distributions are repeatable and demonstrate predictable longitudinal variation. By lumping multiple samples to attain populations of several hundred grains, we recognize distinctive, provenance-defining zircon-age distributions or "barcodes," for fluvial sedimentary systems of several scales, within the upper and middle Snake River system. Our detrital-zircon studies effectively define the geochronology of the northern Rocky Mountains. The composite detrital-zircon grain distribution of the middle Snake River consists of major populations of Neogene, Eocene, and Cretaceous magmatic grains plus intermediate and small grain populations of multiply recycled Grenville (˜950 to 1300 Ma) grains and Yavapai-Mazatzal province grains (˜1600 to 1800 Ma) recycled through the upper Belt Supergroup and Cretaceous sandstones. A wide range of older Paleoproterozoic and Archean grains are also present. The best-case scenario for using detrital-zircon populations to isolate provenance is when there is a point-source pluton with known age, that is only found in one location or drainage. We find three such zircon age-populations in fluvial sediments downstream from the point-source plutons: Ordovician in the southern Beaverhead Mountains, Jurassic in northern Nevada, and Oligocene in the Albion Mountains core complex of southern Idaho. Large detrital-zircon age-populations derived from regionally well-defined, magmatic or recycled sedimentary, sources also serve to delimit the provenance of Neogene fluvial systems. In the Snake River system, defining populations include those derived from Cretaceous Atlanta lobe of the Idaho batholith (80 to 100 Ma), Eocene Challis Volcanic Group and

  10. Geochemical signatures and magmatic stability of terrestrial impact produced zircon

    NASA Astrophysics Data System (ADS)

    Wielicki, Matthew M.; Harrison, T. Mark; Schmitt, Axel K.

    2012-03-01

    Understanding the role of impacts on early Earth has major implications to near surface conditions, but the apparent lack of preserved terrestrial craters > 2 Ga does not allow a direct sampling of such events. Ion microprobe U-Pb ages, REE abundances and Ti-in-zircon thermometry for impact produced zircon are reported here. These results from terrestrial impactites, ranging in age from ~ 35 Ma to ~ 2 Ga, are compared with the detrital Hadean zircon population from Western Australia. Such comparisons may provide the only terrestrial constraints on the role of impacts during the Hadean and early Archean, a time predicted to have a high bolide flux. Ti-in-zircon thermometry indicates an average of 773 °C for impact-produced zircon, ~ 100 °C higher than the average for Hadean zircon crystals. The agreement between whole-rock based zircon saturation temperatures for impactites and Ti-in-zircon thermometry (at aTiO2 = 1) implies that Ti-in-zircon thermometry record actual crystallization temperatures for impact melts. Zircon saturation modeling of Archean crustal rock compositions undergoing thermal excursions associated with the Late Heavy Bombardment predicts equally high zircon crystallization temperatures. The lack of such thermal signatures in the Hadean zircon record implies that impacts were not a dominant mechanism of producing the preserved Hadean detrital zircon record.

  11. Sensitive high resolution ion microprobe (SHRIMP) detrital zircon geochronology provides new evidence for a hidden neoproterozoic foreland basin to the Grenville Orogen in the eastern Midwest, U.S.A

    USGS Publications Warehouse

    Santos, J.O.S.; Hartmann, L.A.; McNaughton, N.J.; Easton, R. M.; Rea, R.G.; Potter, P.E.

    2002-01-01

    A sensitive high resolution ion microprobe (SHRIMP) was used in combination with backscattered electron (BSE) and cathodoluminescence (CL) images to determine the age of detrital zircons from sandstones in the Neoproterozoic Middle Run Formation of the eastern Midwest, United States. Eleven samples from seven drill cores of the upper part of the Middle Run Formation contain detrital zircons ranging in age from 1030 to 1982 Ma (84 analyses), with six distinctive modes at 1.96, 1.63, 1.47, 1.34, 1.15, and 1.08 Ga. This indicates that most, but not all, of the zircon at the top of the Middle Run Formation was derived from the Grenville Orogen. The youngest concordant detrital zircon yields a maximum age of 1048 ?? 22 Ma for the Middle Run Formation, indicating that the formation is younger than ca. 1026 Ma minus the added extra time needed for later uplift, denudation, thrusting, erosion, and transport to southwestern Ohio. Thus, as judged by proximity, composition, thickness, and geochronology, it is a North American equivalent to other Neoproterozoic Grenvillian-derived basins, such as the Torridon Group of Scotland and the Palmeiral Formation of South America. An alternate possibility, although much less likely in our opinion, is that it could be much younger, any time between 1048 ?? 22 Ma and the deposition of the Middle Cambrian Mount Simon Sandstone at about 510 Ma, and still virtually almost all derived from rocks of the Grenville Orogen.

  12. Provenance analysis and detrital zircon geochronology on the onshore Makran accretionary wedge, SE Iran: implication for the geodynamic setting

    NASA Astrophysics Data System (ADS)

    Mohammadi, Ali; Burg, Jean-Pierre; Winkler, Wilfried; Ruh, Jonas

    2014-05-01

    The Makran, located in Southeast Iran and South Pakistan, is one of the largest accretionary wedges on Earth. In Iran it comprises turbiditic sediments ranging in age from Late Cretaceous to Holocene. We present a provenance analysis on sandstones, which is aimed at reconstructing the assemblages of source rocks and the tectonic setting from which the clastic material was derived. Sandstone samples collected from different units span the regional stratigraphy from Late Cretaceous to Miocene. Laser ablation ICP-MS resulted in ca 2800 new U-Pb ages of individual detrital zircons from 18 samples collected in onshore Makran. 101 detrital zircons from a Late Cretaceous fine grained sandstone range from 180 to 160 Ma (Middle Jurassic). 478 detrital zircons from mid- to late Eocene sandstones allow differentiating a NE and NW sector of the Makran Basin. Zircon grains in the NE basin belong to two populations peaking at 180 to 160 Ma (late Early to Middle Jurassic) and 50 to 40 Ma (Mid-Eocene), with the noticeable absence of Cretaceous grains. In the NW basin, detrital zircons are 120 to 40 Ma (late Early Cretaceous to Lutetian, Eocene). 587 detrital zircon grains from fine to medium grained Oligocene sandstones collected over the whole area also range from 120 to 40 Ma (late Early Cretaceous to Eocene, Lutetian). 1611 detrital zircons from early Miocene sandstones show again distinctly different ages in the eastern and western parts of the basin. They range from 120 to 40 Ma (late Early Cretaceous to Eocene) in the eastern and from 80 to 40 Ma (Late Cretaceous to Eocene) in the western basin. Hf isotopes analyses were performed on 120 zircon grains from 6 samples. Negative values (-2 to -15) in Middle Jurassic and late Early Cretaceous zircons indicate minor or no influence of mantle reservoirs which implies a rifting setting during crystallization of the zircons. Low negative to positive (-5 to +10) values in Late Cretaceous and Eocene zircons indicate mixed crustal and

  13. Detrital zircon evidence for the ternary sources of the Chinese Loess Plateau

    NASA Astrophysics Data System (ADS)

    Sun, Jimin; Ding, Zhongli; Xia, Xiaoping; Sun, Min; Windley, Brian F.

    2018-04-01

    The provenance of Chinese loess is fundamental for understanding its origin, transportation and climatic significance. In this paper, eight samples were collected for detrital zircon age analysis, five from different deserts, and three from the Jingbian Section in the northern Chinese Loess Plateau, covering an age range of 2.6-0.03 Ma. The new results, integrated with knowledge of relevant topography and wind patterns, demonstrate that the age spectra of the detrital zircons in the loess are different from those of the sands from the Tarim, Junggar and Qaidam basins, implying that these basins were not the sources of the silts of the Loess Plateau. Further analysis suggests that the three sources for the loess are: (1) clastic materials eroded from the mountains of the Central Asian Orogenic Belt (especially the Gobi Altai and Hangay), (2) clastic loess-sized materials generated by erosion of the Qilian Mountains in the NE Tibetan Plateau, and (3) minor clastic debris derived from the mountains of the North China Craton. Thus, silts of the Loess Plateau have a complex origin, although inland basins, long believed to be important sources, have only a minor role at most.

  14. Evolution of the depleted mantle and growth of the continental crust: improving on the imperfect detrital zircon record

    NASA Astrophysics Data System (ADS)

    Vervoort, J. D.; Kemp, A. I. S.; Patchett, P. J.

    2012-04-01

    One of the basic tenets of terrestrial geochemistry is that the continental crust has been extracted from the mantle leaving the latter depleted in incompatible elements. Nd and Hf isotopes have long shown that this process has been an essential feature of the Earth throughout its history. There is wide agreement on the general nature of this process, but the details of the isotopic record—and their implications for the depletion of the mantle and the extraction of continental crust—remain debated. Recently, much attention has been given to detrital zircons in both modern and ancient sediments. An advantage of this approach is the integration of the crystallization history of the zircon from the U-Pb chronometer with its Hf isotopic composition, which can provide important information on whether the zircons have been derived from juvenile or reworked crust. One essential requirement in this approach, however, is to unambiguously determine the crystallization ages of the zircons. We suggest that this represents an important—but generally ignored—source of uncertainty in the Hf isotopic record from detrital zircons. The quality filter most often used to assess the integrity of zircon U-Pb systematics is concordance; if a zircon is concordant, it is assumed that the U-Pb age is accurate. A concordance filter is less effective in old zircons, however, because ancient Pb loss, viewed today, parallels concordia. Without the benefit from the geological context of the host rock to the zircons, it is impossible to unambiguously determine it true crystallization age. Ancient Pb loss in zircons produces an apparent age less than the true magmatic age. The initial Hf isotopic composition of these zircons, as a result, will be calculated at the wrong age and will be anomalously low (by ~2.2 epsilon Hf units per 0.1 Ga). Hf model ages, calculated from these parameters, will be artificially old and spurious. The combination of unradiogenic Hf and Hf model ages > U-Pb ages

  15. Detrital Zircons From the Jack Hills and Mount Narryer, Western Australia: Geochronological, Morphological, and Geochemical Evidence for Diverse >4000 Ma Source Rocks

    NASA Astrophysics Data System (ADS)

    Crowley, J. L.; Myers, J. S.; Sylvester, P. J.; Cox, R. A.

    2004-05-01

    Detrital zircons from all major clastic units in the Jack Hills and Mount Narryer metasedimentary belts, Western Australia, were analyzed for morphology, internal zoning, inclusion mineralogy, age, and trace element concentrations (latter two obtained by laser-ablation microprobe ICPMS). The results show that zircons were derived from a wide diversity of rocks, including previously described, >4000 Ma grains that are older than any known terrestrial rocks. In three metaconglomerate samples from the western Jack Hills, 4200-3800 Ma zircons ("old grains") comprise 14% of the population, 3800-3600 Ma grains form only 2%, and 3550-3250 Ma zircons ("young grains") are dominant with a significant peak at 3380 Ma. Old and young grains are interpreted as being from similar rock types because they are indistinguishable in trace element concentrations, size (several hundred microns), morphology (subequant, typically fragmented), internal zoning (typically both oscillatory and sector), and U concentration (50-200 ppm). Many of these properties suggest an intermediate plutonic source, whereas an evolved granitic source was previously interpreted from rare-earth element and oxygen isotope data. Detrital zircons in quartzites and metaconglomerates at Mount Narryer differ significantly from zircons from the western Jack Hills. Old grains comprise only 3% (most of which are 4200-4100 Ma), 3800-3600 Ma zircons form 31%, and there are peaks at 3650, 3600, and 3500 Ma. Old and young grains have similar properties that suggest granitic sources, such as elongate prismatic morphology, oscillatory zoning, high U concentrations (100-600 ppm), and xenotime and monazite inclusions. Trace element concentrations are broadly similar to those in Jack Hills zircons, with notable exceptions being generally higher U, smaller Ce and Eu anomalies, and lower Nb/Ta. It is considered unlikely that Jack Hills zircons were derived from granitic gneisses that surround the metasedimentary belts because

  16. Re-evaluation of the origin and evolution of > 4.2 Ga zircons from the Jack Hills metasedimentary rocks

    NASA Astrophysics Data System (ADS)

    Nemchin, A. A.; Pidgeon, R. T.; Whitehouse, M. J.

    2006-04-01

    New data are presented on internal structures, U-Pb systematics and oxygen isotope compositions of eight detrital zircons with ages greater than 4.2 Ga, from the Jack Hills metasedimentary belt, Australia. Cathodoluminescence imaging, ion-microprobe U-Pb and oxygen isotope results show evidence for an extensive period of complex zircon growth, secondary reaction and U-Pb isotopic disturbance from 4.36 to 3.90 Ga. In addition many of the zircons have discordant U-Pb systems and excess common Pb indicating a superimposed, relatively recent, reaction between radiation damaged zircon and low temperature fluids. The significance of oxygen isotope compositions for zircons with complex internal structures and U-Pb systems is complicated by uncertainty in the origin of the grains and the unknown effect of later reactions. However, a minority of grains with sharp oscillatory zoning, uniform and concordant U-Pb systems, igneous Th-U ratios and low common Pb contents, are interpreted as undisturbed primary magmatic zircons. The oldest identified, oscillatory zoned, magmatic grain, with an age 4363 ± 20 Ma, is one of a few reported magmatic grains with this age, which is interpreted as the oldest reliable age for Hadean magmatic zircons. Mantle δ18O values are reported for these zircons. Younger oscillatory zoned zircon, including oscillatory zoned cores in complex grains, have δ18O values lower than 6.5‰, which are within the range of ion microprobe analysed δ18O values for zircons in high temperature equilibrium with the normal mantle rocks of 5.3 ± 0.6‰ (2 standard deviations). These values are also within the range of δ18O values found in lunar zircons. The absence of heavy oxygen in the grains that can be interpreted as primary magmatic zircons and the complex history over the period from 4.36 to 3.9 Ga, seen in all other Jack Hills zircons and reflected in the internal structures and U-Pb isotopic systems, questions the model for the early Earth involving long

  17. Field, petrologic and detrital zircon study of the Kings sequence and Calaveras complex, Southern Lake Kaweah Roof Pendant, Tulare County, California

    NASA Astrophysics Data System (ADS)

    Buchen, Christopher T.

    U-Pb dating of detrital zircon grains separated from elastic sedimentary rocks is combined with field, petrographic and geochemical data to reconstruct the geologic history of Mesozoic rocks exposed at the southern end of the Lake Kaweah metamorphic pendant, western Sierra Nevada. Identification of rocks exposed at Limekiln Hill, Kern County, CA, as belonging to the Calaveras complex and Kings sequence was confirmed. Detrital zircon populations from two Calaveras complex samples provide Permo-Triassic maximum depositional ages (MDA) and reveal a Laurentian provenance indicating that continental accretion of the northwest-trending Kings-Kaweah ophiolite belt was in process prior to the Jurassic Period. Rock types including radiolarian metachert, metachert-argillite, and calc-silicate rocks with marble lenses are interpreted as formed in a hemipelagic environment of siliceous radiolarian deposition, punctuated by extended episodes of lime-mud gravity flows mixing with siliceous ooze forming cafe-silicate protoliths and limestone olistoliths forming marble lenses. Two samples of the overlying Kings sequence turbidites yield detrital zircons with an MDA of 181.4 +/-3.0 Ma and an interpreted provenance similar to other Jurassic metasediments found in the Yokohl Valley, Sequoia and Boyden Cave roof pendants. Age peaks indicative of Jurassic erg heritage are also present. In contrast, detrital zircon samples from the Sequoia and Slate Mountain roof pendants bear age-probability distributions interpreted as characteristic of the Snow Lake block, a tectonic sliver offset from the Paleozoic miogeocline.

  18. Tectonic and sedimentary linkages between the Belt-Purcell basin and southwestern Laurentia during the Mesoproterozoic ca. 1.60-1.40 Ga

    USGS Publications Warehouse

    Jones, James V.; Dainel, Christohper G; Doe, Michael F

    2015-01-01

    Mesoproterozoic sedimentary basins in western North America provide key constraints on pre-Rodinia craton positions and interactions along the western rifted margin of Laurentia. One such basin, the Belt-Purcell basin, extends from southern Idaho into southern British Columbia and contains a >18-km-thick succession of siliciclastic sediment deposited ca. 1.47–1.40 Ga. The ca. 1.47–1.45 Ga lower part of the succession contains abundant distinctive non-Laurentian 1.61–1.50 Ga detrital zircon populations derived from exotic cratonic sources. Contemporaneous metasedimentary successions in the southwestern United States–the Trampas and Yankee Joe basins in Arizona and New Mexico–also contain abundant 1.61–1.50 Ga detrital zircons. Similarities in depositional age and distinctive non-Laurentian detrital zircon populations suggest that both the Belt-Purcell and southwestern successions record sedimentary and tectonic linkages between western Laurentia and one or more cratons including North Australia, South Australia, and (or) East Antarctica. At ca. 1.45 Ga, both the Belt-Purcell and southwest successions underwent major sedimentological changes, with a pronounced shift to Laurentian provenance and the disappearance of the 1.61–1.50 Ga detrital zircon. Upper Belt-Purcell strata contain strongly unimodal ca. 1.73 Ga detrital zircon age populations that match the detrital zircon signature of Paleoproterozoic metasedimentary rocks of the Yavapai province to the south and southeast. We propose that the shift at ca. 1.45 Ga records the onset of orogenesis in southern Laurentia coeval with rifting along its northwestern margin. Bedrock uplift associated with orogenesis and widespread, coeval magmatism caused extensive exhumation and erosion of the Yavapai province ca. 1.45–1.36 Ga, providing a voluminous and areally extensive sediment source–with suitable zircon ages–during upper Belt deposition. This model provides a comprehensive and integrated view of

  19. Evaluating the utility of detrital thermochronometric studies: detrital laser ablation (U-Th)/He dating and conventional bedrock zircon (U-Th)/He analyses from the eastern Sierra Nevada, California

    NASA Astrophysics Data System (ADS)

    Horne, A.; Hodges, K. V.; Van Soest, M. C.

    2016-12-01

    Recent applications of the newly developed `laser ablation double dating' (LADD) technique, an integrated laser microprobe U/Pb and (U-Th)/He dating method, have showcased the potential utility of LADD for detrital thermochronologic studies. However, detrital thermochronologic techniques rely on confidence that detrital data adequately represent the full range of bedrock cooling ages within a catchment. To test this primary assumption, we compare (U-Th)/He zircon ages from age-elevation transects to LADD (U-Th)/He zircon ages from modern fluvial detritus collected at the range front in the eastern Sierra Nevada, California. Terminated by a normal fault escarpment, the small, steep catchments along the eastern side of the Sierra Nevada batholith are apropos locations for comparing the ability of detrital data to deduce the exhumation history of a source terrain with standard age-elevation transects. Additionally, the exhumation of the Sierra Nevada batholith is also intriguing, as past evaluations of the post-emplacement exhumation history of the range have yielded discrepant results. Thus far, analyses from the southern extent of the eastern Sierra Nevada show narrow ranges of cooling ages consistent with simple, relatively rapid exhumation. Ongoing analyses will expand the dataset such that we can fully compare bedrock and detrital age ranges as well as characterize the exhumation history of the range with a thermochronometer that has not been used to date the batholith.

  20. Proterozoic events recorded in quartzite cobbles at Jack Hills, Western Australia: New constraints on sedimentation and source of > 4 Ga zircons

    NASA Astrophysics Data System (ADS)

    Grange, Marion L.; Wilde, Simon A.; Nemchin, Alexander A.; Pidgeon, Robert T.

    2010-03-01

    Rare heavy mineral bands within quartzite cobbles were identified in two conglomerate units within the Jack Hills belt, Western Australia. Seven zircon-bearing cobbles were analysed from one location (site 152) and three from another (site 154), both approximately 1 km west of the site where zircons in excess of 4 Ga are abundant (W74 'discovery' site). Individual pebbles from the 152 site reveal three distinctive features, containing either zircons > 3.0 Ga in age, < 1.9 Ga in age or a range of ages from ˜ 1.2 to ˜ 3.6 Ga. Those from site 154 are more uniform, containing only zircons with ages between 3.1 and 3.9 Ga. Only one grain > 4 Ga was discovered from the entire suite of pebbles, in contrast to the well-studied W74 site. A single detrital zircon with an age of 1220 ± 42 Ma from location 152 is the youngest grain so far reported from sedimentary rocks at Jack Hills. It shows magmatic oscillatory zoning and thus implies at least two sedimentary cycles within the Proterozoic; requiring erosion of an igneous precursor, incorporation into a clastic sediment, induration and subsequent erosion and transport to be hosted in the conglomerate. The nearest source for rocks of this age is the Bangemall Supergroup in the Collier Basin, ˜ 100 km northeast in the Capricorn Orogen. This would imply tectonic interleaving of originally more extensive Bangemall rocks, possibly related to activity along the Cargarah Shear Zone that traverses the Jack Hills belt. The lack of > 4.1 Ga zircons in the pebbles is highly significant, suggesting the immediate source of ancient zircons was no longer present at the Earth's surface. This equates with a general lack of ancient crystals noted in rocks that contain Proterozoic zircons from previous studies and implies that such grains diminish in number as earlier sedimentary rocks were successively recycled.

  1. Detrital zircon evidence for progressive underthrusting in Franciscan metagraywackes, west-central California

    USGS Publications Warehouse

    Snow, C.A.; Wakabayashi, J.; Ernst, W.G.; Wooden, J.L.

    2010-01-01

    We present new U/Pb ages for detrital zircons separated from six quartzose metagraywackes collected from different Franciscan Complex imbricate nappes around San Francisco Bay. All six rocks contain a broad spread of Late Jurassic-Cretaceous grains originating from the Klamath-Sierra Nevada volcanic-plutonic arc. Units young structurally downward, consistent with models of progressive underplating and offscraping within a subduction complex. The youngest specimen is from the structurally lowest San Bruno Mountain sheet; at 52 Ma, it evidently was deposited during the Eocene. None of the other metagraywackes yielded zircon ages younger than 83 Ma. Zircons from both El Cerrito units are dominated by ca. 100-160 Ma grains; the upper El Cerrito also contains several grains in the 1200-1800 Ma interval. These samples are nearly identical to 97 Ma metasedimentary rock from the Hunters Point shear zone. Zircon ages from this m??lange block exhibit a broad distribution, ranging from 97 to 200 Ma, with only a single pre-Mesozoic age. The Albany Hill specimen has a distribution of pre-Mesozoic grains from 1300 to 1800 Ma, generally similar to that of the upper El Cerrito sheet; however, it contains zircons as young as 83 Ma, suggesting that it is significantly younger than the upper El Cerrito unit. The Skaggs Spring Schist is the oldest studied unit; its youngest analyzed grains were ca. 144 Ma, and it is the only investigated specimen to display a significant Paleozoic detrital component. Sedimentation and subduction-accretion of this tract of the trench complex took place along the continental margin during Early to early-Late Cretaceous time, and perhaps into Eocene time. Franciscan and Great Valley deposition attests to erosion of an Andean arc that was active over the entire span from ca. 145 to 80 Ma, with an associated accretionary prism built by progressive underthrusting. We use these new data to demonstrate that the eastern Franciscan Complex in the northern and

  2. Continental crustal history in SE Asia: Insights from zircon geochronology

    NASA Astrophysics Data System (ADS)

    Sevastjanova, I.; Hall, R.; Gunawan, I.; Ferdian, F.; Decker, J.

    2012-12-01

    It is well known that SE Asia is underlain mostly by continental crust derived from Gondwana. However, there are still many uncertainties about the ages of protoliths, origin, arrival ages and history of different blocks, because much of the basement is unexposed. We have compiled previously published and new zircon U-Pb age and Hf isotope data from SE Asia. Our data set currently contains over 8400 U-Pb ages and over 600 Hf isotope analyses from sedimentary, metamorphic and igneous rocks and work is continuing to increase its size and the area covered. Zircons range in age from 3.4 Ga to near-zero. Archean zircons (>2.5 Ga) are rare in SE Asia and significant Archean populations (particularly zircons >2.8 Ga) are found only in East Java and the Sibumasu block of the Malay Peninsula. The presence of Archean zircons strongly suggests that the East Java and Sibumasu blocks were once situated near present-day Western Australia. Detrital Paleoproterozoic (ca. 1.9-1.8 Ga) zircons are abundant in many parts of SE Asia. In Sundaland (Malay Peninsula, Sumatra, West Java, Borneo) the most likely source for these zircons is the tin belt basement, but a north Australian source is more likely for eastern Indonesian samples. An early Mesoproterozoic (ca. 1.6-1.5 Ga) zircon population, particularly common in eastern Indonesia, is interpreted to be derived from central or northern Australia. Mesoproterozoic zircons, ca. 1.4 Ga, are common only on fragments that are now attached to or were previously part of the north Australian margin, such as the Bird's Head of New Guinea, Timor, Seram, Sulawesi and SW Borneo. Hf isotope characteristics of zircons from Seram are similar to those of zircons from eastern Australia. This supports the suggestion that Seram was part of the Australian margin. Late Meso- and early Neoproterozoic zircons (ca. 1.2-1.1 Ga, 900 Ma, and 600 Ma) are present, but not abundant, in SE Asia. Dominant Phanerozoic populations are Permian-Triassic, Cretaceous, and

  3. Detrital zircon geochronology support for Baja-BC hypothesis or Why zircons in the Nanaimo Basin, British Columbia are not from the Rocky Mountains.

    NASA Astrophysics Data System (ADS)

    Guest, B.; Matthews, W.; Hubbard, S. M.; Coutts, D. S.; Bain, H.

    2016-12-01

    The development of Cordilleran orogen of western North American is disputed despite a century of study. Paleomagnetic observations require large-scale dextral displacement of crustal fragments along the western margin of North America, from low latitudes to moderate latitudes during the Cretaceous-Paleogene. A lack of corroborating geological evidence for large-scale displacements has prevented the widespread integration of paleomagnetic data into contemporary tectonic models for the margin. Here we investigate the Cretaceous paleogeographic position of the Baja-BC block, a crustal fragment consisting of the Alexander and Wrangel terranes, using detrital zircons from the Nanaimo Basin of Vancouver Island, British Columbia. We compare 4310 detrital zircon U/Pb analyses from 16 samples to potential source areas in western North America to test hypothesized northern and southern paleogeographic positions. Our detrital zircon data suggest that sediment in the Nanaimo Basin derives from the Mojave-Sonoran Region of southwestern North America, supporting a southerly late Cretaceous paleogeographic position. We present a speculative Cretaceous to Paleogene paleogeographic reconstruction for the southwestern United States and northern Mexico that accommodates the presence, and northward transport, of the Baja-BC block. We propose that the Western Coast Mountains Batholith and the Nanaimo Basin represent the missing segment of the Mesozoic magmatic arc and associated forearc regions, between the Sierra Nevada and Peninsular Ranges Batholiths. This segment was translated northward following capture by the Kula plate. As such, we reconcile the paleomagnetic data for the Baja-BC block with the geology of the southwestern United States. Our model, albeit speculative, is compatible with the large-scale tectonic and magmatic processes that affected western North America in the Late Cretaceous and Paleogene.

  4. Detrital zircons from the Nanaimo basin, Vancouver Island, British Columbia: An independent test of Late Cretaceous to Cenozoic northward translation

    NASA Astrophysics Data System (ADS)

    Matthews, W. A.; Guest, B.; Coutts, D.; Bain, H.; Hubbard, S.

    2017-05-01

    The development of the Cordilleran orogen of western North American is disputed despite a century of study. Paleomagnetic observations require large-scale dextral displacements of crustal fragments along the western margin of North America, from low latitudes to moderate latitudes during the Cretaceous-Paleogene. A lack of corroborating geological evidence for large-scale (>1500 km) displacements has prevented the widespread integration of paleomagnetic data into most contemporary tectonic models for the margin. Here we use detrital zircons from the Nanaimo basin, southwestern British Columbia, Canada as an independent test of its Late Cretaceous paleogeographic position. We compare 4310 detrital zircon U/Pb dates from 16 samples to potential source areas in western North America to test hypothesized northern and southern Late Cretaceous paleogeographic positions. Our detrital zircon data suggest that sediment in the Nanaimo basin derives from either a geographically restricted portion of the Belt-Purcell basin or the Mojave-Sonoran region of southwestern North America. A paleogeographic position for the basin adjacent to the Mojave-Sonoran region is preferred as it is consistent with the paleomagnetic results, but further geological, isotopic, or geophysical data are required to rule out a Belt-Purcell source.

  5. Ti-in-zircon thermometry: applications and limitations

    NASA Astrophysics Data System (ADS)

    Fu, Bin; Page, F. Zeb; Cavosie, Aaron J.; Fournelle, John; Kita, Noriko T.; Lackey, Jade Star; Wilde, Simon A.; Valley, John W.

    2008-08-01

    The titanium concentrations of 484 zircons with U-Pb ages of ˜1 Ma to 4.4 Ga were measured by ion microprobe. Samples come from 45 different igneous rocks (365 zircons), as well as zircon megacrysts (84) from kimberlite, Early Archean detrital zircons (32), and zircon reference materials (3). Samples were chosen to represent a large range of igneous rock compositions. Most of the zircons contain less than 20 ppm Ti. Apparent temperatures for zircon crystallization were calculated using the Ti-in-zircon thermometer (Watson et al. 2006, Contrib Mineral Petrol 151:413-433) without making corrections for reduced oxide activities (e.g., TiO2 or SiO2), or variable pressure. Average apparent Ti-in-zircon temperatures range from 500° to 850°C, and are lower than either zircon saturation temperatures (for granitic rocks) or predicted crystallization temperatures of evolved melts (˜15% melt residue for mafic rocks). Temperatures average: 653 ± 124°C (2 standard deviations, 60 zircons) for felsic to intermediate igneous rocks, 758 ± 111°C (261 zircons) for mafic rocks, and 758 ± 98°C (84 zircons) for mantle megacrysts from kimberlite. Individually, the effects of reduced a_{TiO2} or a_{SiO2}, variable pressure, deviations from Henry’s Law, and subsolidus Ti exchange are insufficient to explain the seemingly low temperatures for zircon crystallization in igneous rocks. MELTs calculations show that mafic magmas can evolve to hydrous melts with significantly lower crystallization temperature for the last 10-15% melt residue than that of the main rock. While some magmatic zircons surely form in such late hydrous melts, low apparent temperatures are found in zircons that are included within phenocrysts or glass showing that those zircons are not from evolved residue melts. Intracrystalline variability in Ti concentration, in excess of analytical precision, is observed for nearly all zircons that were analyzed more than once. However, there is no systematic change in Ti

  6. Potentially biogenic carbon preserved in a 4.1 billion-year-old zircon.

    PubMed

    Bell, Elizabeth A; Boehnke, Patrick; Harrison, T Mark; Mao, Wendy L

    2015-11-24

    Evidence of life on Earth is manifestly preserved in the rock record. However, the microfossil record only extends to ∼ 3.5 billion years (Ga), the chemofossil record arguably to ∼ 3.8 Ga, and the rock record to 4.0 Ga. Detrital zircons from Jack Hills, Western Australia range in age up to nearly 4.4 Ga. From a population of over 10,000 Jack Hills zircons, we identified one >3.8-Ga zircon that contains primary graphite inclusions. Here, we report carbon isotopic measurements on these inclusions in a concordant, 4.10 ± 0.01-Ga zircon. We interpret these inclusions as primary due to their enclosure in a crack-free host as shown by transmission X-ray microscopy and their crystal habit. Their δ(13)CPDB of -24 ± 5‰ is consistent with a biogenic origin and may be evidence that a terrestrial biosphere had emerged by 4.1 Ga, or ∼ 300 My earlier than has been previously proposed.

  7. Potentially biogenic carbon preserved in a 4.1 billion-year-old zircon

    PubMed Central

    Bell, Elizabeth A.; Harrison, T. Mark; Mao, Wendy L.

    2015-01-01

    Evidence of life on Earth is manifestly preserved in the rock record. However, the microfossil record only extends to ∼3.5 billion years (Ga), the chemofossil record arguably to ∼3.8 Ga, and the rock record to 4.0 Ga. Detrital zircons from Jack Hills, Western Australia range in age up to nearly 4.4 Ga. From a population of over 10,000 Jack Hills zircons, we identified one >3.8-Ga zircon that contains primary graphite inclusions. Here, we report carbon isotopic measurements on these inclusions in a concordant, 4.10 ± 0.01-Ga zircon. We interpret these inclusions as primary due to their enclosure in a crack-free host as shown by transmission X-ray microscopy and their crystal habit. Their δ13CPDB of −24 ± 5‰ is consistent with a biogenic origin and may be evidence that a terrestrial biosphere had emerged by 4.1 Ga, or ∼300 My earlier than has been previously proposed. PMID:26483481

  8. Detrital zircons from phanerozoic rocks of the Songliao Block, NE China: Evidence and tectonic implications

    NASA Astrophysics Data System (ADS)

    Zhou, Jian-Bo; Wilde, Simon A.; Zhang, Xing-Zhou; Liu, Fu-Lai; Liu, Jian-Hui

    2012-03-01

    Rocks that crop out in the northern part of the Songliao Block are mainly consist of high-grade metamorphic gneiss, Paleozoic strata and Mesozoic granites. They are essentially similar to rocks reported from beneath the Songliao Basin that occupies the majority of the Songliao Block. Four samples of Paleozoic metasedimentary rocks from Tieli in the north-eastern part of the Songliao Block yield detrital zircon U-Pb ages ranging from 2690 to 501 Ma, with four age populations at: 2071-2690 Ma, with a peak at 2585 Ma; 1776-1997 Ma, with a peak at 1890 Ma; 719-991 Ma, with a peak at 800 Ma; and 501-592 Ma, with a peak at 518 Ma. These are similar to age populations in other parts of the Central Asian Orogenic Belt (CAOB), although sediments from the Songliao Block contain more abundant Archean and Proterozoic detrital zircons than the neighboring Jiamusi-Khanka Block to the east and Xing'an Block to the west. This may indicate that rocks of this age comprise a minor component of the Songliao Block. The Pan-African zircon ages from the Songliao Block, taken together with ˜500 Ma magmatic and high-grade metamorphic zircons obtained from the nearby Erguna, Xing'an and Jiamusi-Khanka blocks, indicate that Pan-African events affected all blocks of the CAOB in NE China. This suggests that these blocks not only share a common basement, but that they had a common history. An extensive Late Pan-African (˜500 Ma) orogenic terrane thus occupies much of the CAOB in NE China.

  9. Provenance and metamorphic PT conditions of Cryogenian-Ediacaran metasediments from the Kid metamorphic complex, Sinai, NE Arabian-Nubian Shield: Insights from detrital zircon geochemistry and mineral chemistry

    NASA Astrophysics Data System (ADS)

    El-Bialy, Mohammed Z.; Ali, Kamal A.; Abu El-Enen, Mahrous M.; Ahmed, Ahmed H.

    2015-12-01

    The Malhaq and Um Zariq formations occupy the northern part of the Neoproterozoic Kid metamorphic complex of SE Sinai, NE Arabian-Nubian Shield. This study presents new mineral chemistry data and LA-ICP-MS analyses of the trace element concentrations on zircons separated from metapelites from these formations. The detrital zircons of Um Zariq Formation are more enriched in ΣREE, whereas Malhaq Formation zircons are markedly HREE-enriched with strongly fractionated HREE patterns. The quite differences in the overall slope and size of the Eu and Ce anomalies between REE patterns of the two zircon suites provide a robust indication of different sources. The Ti-in-zircon thermometer has revealed that the zircons separated from Malhaq Formation were crystallized within the 916-1018 °C range, while those from Um Zariq Formation exhibit higher range of crystallization temperatures (1084-1154 °C). The detrital zircons of Malhaq Formation were derived mainly from mafic source rocks (basalt and dolerite), whereas Um Zariq Formation zircons have varied and more evolved parent rocks. Most of the investigated zircons from both formations are concluded to be unaltered magmatic that were lately crystallized from a high LREE/HREE melt. All the studied detrital zircon grains show typical trace elements features of crustal-derived zircons. All of the Um Zariq Formation and most of Malhaq Formation detrital zircons are geochemically discriminated as continental zircons. Both formation metapelites record similar, overlapping peak metamorphic temperatures (537-602 °C and 550-579 °C, respectively), and pressures (3.83-4.93 kbar and 3.69-4.07 kbar, respectively). The geothermal gradient, at the peak metamorphic conditions, was quite high (37-41 °C/km) corresponding to metamorphism at burial depth of 14-16 km. The peak regional metamorphism of Um Zariq and Malhaq formations is concluded to be generated during extensional regime and thinning of the lithosphere in an island arc

  10. Detrital zircon age patterns and provenance of the metamorphic complexes of southern Chile

    NASA Astrophysics Data System (ADS)

    Hervé, F.; Fanning, C. M.; Pankhurst, R. J.

    2003-05-01

    Zircon SHRIMP U-Pb age patterns are reported for 13 metasedimentary rocks from the low grade metamorphic complexes of the Patagonian Andes. Combined with four recently published patterns, these provide the first detailed survey of the provenance of these complexes. The youngest dated zircons, corresponding to maximum sedimentation ages, are Devonian-Late Triassic in the eastern Andes metamorphic complex, Carboniferous in the main range metamorphic complex, Permian in the Duque de York complex, and Late Triassic in the Chonos metamorphic complex. In the last two cases, these ages are in agreement with their respective fossil ages. Older components in the eastern Andes metamorphic complex include a large proportion of Proterozoic (predominantly 1000-1200 Ma) zircons, which may indicate distribution, probably by rivers, of detrital material from regions currently in northern South America, Africa, or east Antarctica. The abundance of Proterozoic zircons is very much less in the Duque de York complex, possibly because of the rise of an inferred Permian magmatic arc related to the Gondwanan orogeny and consequent westward migration of the watershed. A Late Triassic magmatic episode is registered in the Chonos metamorphic complex, where reappearance of significant Proterozoic zircons indicates exhumation of the cratonic areas or of recycled sedimentary material.

  11. Detrital zircon U-Pb geochronology, Lu-Hf isotopes and REE geochemistry constrains on the provenance and tectonic setting of Indochina Block in the Paleozoic

    NASA Astrophysics Data System (ADS)

    Wang, Ce; Liang, Xinquan; Foster, David A.; Fu, Jiangang; Jiang, Ying; Dong, Chaoge; Zhou, Yun; Wen, Shunv; Van Quynh, Phan

    2016-05-01

    In situ U-Pb geochronology, Lu-Hf isotopes and REE geochemical analyses of detrital zircons from Cambrian-Devonian sandstones in the Truong Son Belt, central Vietnam, are used to provide the information of provenance and tectonic evolution of the Indochina Block. The combined detrital zircon age spectra of all of the samples ranges from 3699 Ma to 443 Ma and shows with dominant age peaks at ca. 445 Ma and 964 Ma, along with a number of age populations at 618-532 Ma, 1160-1076 Ma, 1454 Ma, 1728 Ma and 2516 Ma. The zircon age populations are similar to those from time equivalent sedimentary sequences in continental blocks disintegrated from the East Gondwana during the Phanerozoic. The younger zircon grains with age peaks at ca. 445 Ma were apparently derived from middle Ordovician-Silurian igneous and metamorphic rocks in Indochina. Zircons with ages older than about 600 Ma were derived from other Gondwana terrains or recycled from the Precambrian basement of the Indochina Block. Similarities in the detrital zircon U-Pb ages suggest that Paleozoic strata in the Indochina, Yangtze, Cathaysia and Tethyan Himalayas has similar provenance. This is consistent with other geological constrains indicating that the Indochina Block was located close to Tethyan Himalaya, northern margin of the India, and northwestern Australia in Gondwana.

  12. Using U-Pb Detrital Zircon Geochronology to Study Ice Streams in the Weddell Sea Embayment, Antarctica

    NASA Astrophysics Data System (ADS)

    Agrios, L.; Licht, K.; Hemming, S. R.; Williams, T.

    2016-12-01

    Till from major ice streams of the Weddell Sea Embayment contain detrital zircons with distinct U-Pb age populations that can be used as a provenance tool to better understand ice stream dynamics. The ice streams in this study include the Foundation Ice Stream, and Academy, Slessor, and Recovery glaciers, all of which drain ice from the continent's interior into the Weddell Sea. Characterizing the U-Pb detrital zircon ages in till and rocks will (1) provide the zircon provenance signatures of the material carried by the ice stream - when these signatures are found in LGM and older deposits downstream they can enable interpretation of past ice flow history; and (2) constrain ice-covered upstream bedrock geology that supplies the till carried by ice streams and glaciers. U-Pb ages of detrital zircons were measured in 21 samples of onshore till, erratics, and bedrock of potential source rocks. Grains were analyzed by LA-ICPMS at the University of Arizona (n=300). Relative probability U-Pb age density plots of till in moraines along the Foundation Ice Stream and Academy Glacier show prominent peaks at 500-530 and 615-650 Ma, which overlap with the timing of the Ross and Pan-African orogenies. Zircon ages of 1000-1095 Ma are also present. Local bedrock in the Patuxent Range has the most prominent peak at 510 Ma, suggesting the till is predominantly derived from local Patuxent Formation. However, local bedrock also has fewer grains at 1030 Ma which suggests that this age population is carried in the till as well. Prominent peaks in U-Pb ages from till transported by the Recovery Glacier are 530, 635, 1610 and 1770 Ma. Bedrock of this area contains similar age peaks, with the exception of the 635 Ma peak, suggesting that this ice stream is carrying a signature from an unexposed source of this age completely buried by ice. The Slessor Glacier carries zircons with prominent populations at 1710 and 2260-2420 Ma, which overlap with a high-grade metamorphic event in the

  13. Oligo-Miocene Alpine Sediment Routing from Integrated Analysis of Seismic-Reflection Data and Detrital Zircon U-Pb Geochronology

    NASA Astrophysics Data System (ADS)

    Hubbard, S. M.; Sharman, G.; Covault, J. A.

    2014-12-01

    We integrate detrital zircon geochronology and 3D seismic-reflection data to reconstruct Oligo-Miocene paleogeography and sediment routing from the Alpine hinterland to Austrian Molasse foreland basin. Three-dimensional seismic-reflection data image a network of deepwater tributaries and a long-lived (>8 Ma) foredeep-axial channel belt through which predominantly southerly and westerly turbidity currents are interpreted to have transported Alpine detritus >100 km. We analyzed 793 detrital zircon grains from ten sandstone samples collected from the seismically mapped network of channel fill. Grain age populations correspond with major Alpine orogenic cycles: the Cadomian (750-530 Ma), the Caledonian (500-400 Ma), and the Variscan orogenies (350-250 Ma). Additional age populations correspond with Eocene-Oligocene Periadriatic magmatism (40-30 Ma) and pre-Alpine, Precambrian sources >750 Ma. The abundances of these age populations vary between samples. Sediment that entered the foredeep-axial channel belt from the west (freshwater Molasse) and southwest (Inntal fault zone) is characterized by statistically indistinguishable, well-distributed detrital zircon ages. Sandstone from a shallow marine unit that was deposited proximal to the northern basin margin consists of >75% Variscan (350-300 Ma) zircon, which is believed to have originated from the Bohemian Massif to the north. Mixing calculations based on the Kolmogorov-Smirnoff statistic suggest that the Alpine fold-thrust belt was an important source of detritus to the deepwater Molasse basin. We document east-to-west provenance dilution within the axial channel belt via one or more southern tributaries. Our results have important implications for sediment dispersal patterns within continental-scale orogens, including the relative role of longitudinal versus transverse sediment delivery in peripheral foreland basins.

  14. Detrital Record of Phanerozoic Tectonics in Iran: Evidence From U-Pb Zircon Geochronology

    NASA Astrophysics Data System (ADS)

    Horton, B. K.; Gillis, R. J.; Stockli, D. F.; Hassanzadeh, J.; Axen, G. J.; Grove, M.

    2004-12-01

    Ion-microprobe U-Pb ages of 91 detrital zircon grains supplement ongoing investigations of the tectonic history of Iran, a critical region bridging the gap between the Alpine and Himalayan orogenic belts. These data improve understanding of the distribution of continental blocks during a complex history of Late Proterozoic (Pan-African) crustal growth, Paleozoic passive-margin sedimentation, early Mesozoic collision with Eurasia, and Cenozoic collision with Arabia. U-Pb analyses of detrital zircon grains from four sandstone samples (two Lower Cambrian, one uppermost Triassic-Lower Jurassic, one Neogene) collected from the Alborz mountains of northern Iran reveal a spectrum of ages ranging from 50 to 2900 Ma. Most analyses yield concordant to moderately discordant ages. The Lower Cambrian Lalun and Barut sandstones yield age distribution peaks at approximately 550-650, 1000, and 2500 Ma, consistent with a Gondwanan source area presently to the south and west in parts of Iran and the Arabian-Nubian shield (Saudi Arabia and northwestern Africa). The uppermost Triassic-Lower Jurassic Shemshak Formation exhibits a broad range of U-Pb ages, including peaks of approximately 200-260, 330, 430, 600, and 1900 Ma, requiring a Eurasian source area presently to the north and east in the Turan plate (Turkmenistan and southwestern Asia). Neogene strata display both the youngest and oldest ages (approximately 50 and 2900 Ma) of any samples, a result of substantial sedimentary recycling of older Phanerozoic cover rocks. Because the youngest zircon ages for three of the four samples are indistinguishable from their stratigraphic (depositional) ages, these data suggest rapid exhumation and help constrain the termination age of Late Proterozoic-Early Cambrian (Pan-African) orogenesis and the timing of the Iran-Eurasia collision.

  15. Testing the reliability of information extracted from ancient zircon

    NASA Astrophysics Data System (ADS)

    Kielman, Ross; Whitehouse, Martin; Nemchin, Alexander

    2015-04-01

    Studies combining zircon U-Pb chronology, trace element distribution as well as O and Hf isotope systematics are a powerful way to gain understanding of the processes shaping Earth's evolution, especially in detrital populations where constraints from the original host are missing. Such studies of the Hadean detrital zircon population abundant in sedimentary rocks in Western Australia have involved analysis of an unusually large number of individual grains, but also highlighted potential problems with the approach, only apparent when multiple analyses are obtained from individual grains. A common feature of the Hadean as well as many early Archaean zircon populations is their apparent inhomogeneity, which reduces confidence in conclusions based on studies combining chemistry and isotopic characteristics of zircon. In order to test the reliability of information extracted from early Earth zircon, we report results from one of the first in-depth multi-method study of zircon from a relatively simple early Archean magmatic rock, used as an analogue to ancient detrital zircon. The approach involves making multiple SIMS analyses in individual grains in order to be comparable to the most advanced studies of detrital zircon populations. The investigated sample is a relatively undeformed, non-migmatitic ca. 3.8 Ga tonalite collected a few kms south of the Isua Greenstone Belt, southwest Greenland. Extracted zircon grains can be combined into three different groups based on the behavior of their U-Pb systems: (i) grains that show internally consistent and concordant ages and define an average age of 3805±15 Ma, taken to be the age of the rock, (ii) grains that are distributed close to the concordia line, but with significant variability between multiple analyses, suggesting an ancient Pb loss and (iii) grains that have multiple analyses distributed along a discordia pointing towards a zero intercept, indicating geologically recent Pb-loss. This overall behavior has

  16. Cambrian Sauk transgression in the Grand Canyon region redefined by detrital zircons

    NASA Astrophysics Data System (ADS)

    Karlstrom, Karl; Hagadorn, James; Gehrels, George; Matthews, William; Schmitz, Mark; Madronich, Lauren; Mulder, Jacob; Pecha, Mark; Giesler, Dominique; Crossey, Laura

    2018-06-01

    The Sauk transgression was one of the most dramatic global marine transgressions in Earth history. It is recorded by deposition of predominantly Cambrian non-marine to shallow marine sheet sandstones unconformably above basement rocks far into the interiors of many continents. Here we use dating of detrital zircons sampled from above and below the Great Unconformity in the Grand Canyon region to bracket the timing of the Sauk transgression at this classic location. We find that the Sixtymile Formation, long considered a Precambrian unit beneath the Great Unconformity, has maximum depositional ages that get younger up-section from 527 to 509 million years old. The unit contains angular unconformities and soft-sediment deformation that record a previously unknown period of intracratonic faulting and epeirogeny spanning four Cambrian stages. The overlying Tapeats Sandstone has youngest detrital zircon ages of 505 to 501 million years old. When linked to calibrated trilobite zone ages of greater than 500 million years old, these age constraints show that the marine transgression across a greater than 300-km-wide cratonic region took place during an interval 505 to 500 million years ago—more recently and more rapidly than previously thought. We redefine this onlap as the main Sauk transgression in the region. Mechanisms for this rapid flooding of the continent include thermal subsidence following the final breakup of Rodinia, combined with abrupt global eustatic changes driven by climate and/or mantle buoyancy modifications.

  17. Constraints on the age and provenance of the Chugach accretionary complex from detrital zircons in the Sitka Graywacke near Sitka, Alaska

    USGS Publications Warehouse

    Haeussler, Peter J.; Gehrels, George E.; Karl, Susan M.

    2006-01-01

    The Sitka Graywacke is the westernmost and youngest unit of the Chugach accretionary complex in southeastern Alaska. Using laser-ablation inductively coupled plasma mass spectroscopy, we obtained 492 detrital-zircon ages on seven typical samples of Sitka Graywacke turbidites, which were collected in a transect across much of the unit near Sitka, Alaska. Individual grains range in age from 66 to 1,802 m.y. The youngest peak ages on relative-probability plots of the western four samples (74, 72, 74, and 74 m.y., from west to east) are distinctly younger than the youngest peak ages of the eastern three samples (105, 103, and 97 m.y., from west to east). These youngest peak ages set maximum depositional ages for each sample. We suggest that these peak ages are not significantly older (within ~5 m.y.) than the depositional age of the Sitka Graywacke because the deposits accumulated in a trench along a convergent margin, where magmatic sources likely continuously introduced juvenile zircons. The differences in the youngest cluster of detrital-zircon ages between the eastern and western sample localities is likely due to both a change in provenance and a fault. The similarity of the youngest peak ages in the Sitka Graywacke to fossil ages in the Valdez Group, in Prince William Sound, implies that the western part of the Sitka Graywacke is correlative with the Valdez Group, as previously inferred. However, the eastern part of the Sitka Graywacke has youngest detrital-zircon ages older than fossil ages in the Valdez Group and younger than fossil ages in the McHugh Complex, which in south-central Alaska is the oldest part of the accretionary complex. The age distribution of zircons in the older, eastern sequence suggests sources along the British Columbia margin. The detrital-zircon ages in the younger, western sequence are similar to igneous ages from south-central Alaska to southern British Columbia. Right-lateral strike slip on various fault systems inboard of the Sitka

  18. Detrital zircon study along the Tsangpo River, SE Tibet

    NASA Astrophysics Data System (ADS)

    Liang, Y.; Chung, S.; Liu, D.; O'Reilly, S. Y.; Chu, M.; Ji, J.; Song, B.; Pearson, N. J.

    2004-12-01

    The interactions among tectonic uplift, river erosion and alluvial deposition are fundamental processes that shape the landscape of the Himalayan-Tibetan orogen since its creation from early Cenozoic time. To better understand these processes around the eastern Himalayan Syntaxis, we conducted a study by systematic sampling riverbank sediments along the Tsangpo River, SE Tibet. Detrital zircons separated from the sediments were subjected to U-Pb dating by the SHRIMP II at the Beijing SHRIMP Center and then in-situ measurements of Hf isotope ratios using LA-MC-ICPMS at GEMOC. These results, together with U-Pb ages and Hf isotope data that we recently obtained for the Transhimalayan plutonic and surrounding basement rocks, allow a more quantitative examination of the provenance or protosource areas for the river sediments. Consequently, the percentage inputs from these source areas can be estimated. Our study indicates that, before the Tsangpo River flows into the Namche Barwa Syntaxis of the eastern Himalayas where the River forms a 180° Big Bend gorge and crosscuts the Himalayan sequences, the Gangdese batholith that crops out just north of the River appear to be an overwhelming source accounting for ˜50 % of the bank sediments. The Tethyan Himalayan sequences south of the River are the second important source, with an input of ˜25 %. The proportion of sediment supply changes after the River enters the Big Bend gorge and turns to south: ˜25 % of detrital zircons are derived from the Greater Himalayas so that the input from the Tethyan Himalayas decreases (< 10 %) despite those from the Gangdese batholith remains high ( ˜40 %). Comparing with the sediment budget of the Brahmaputra River in the downstream based on literature Sr, Nd and Os isotope information, which suggests dominant ( ˜90-60 %) but subordinate ( ˜10-40 %) contributions by the (Greater and Lesser) Himalayan and Tibetan (including Tethyan Himalayan) rocks, respectively, the change is interpreted

  19. Interaction of the Siberian craton and Central Asian Orogenic Belt (CAOB) recorded by detrital zircons from Transbaikalia

    NASA Astrophysics Data System (ADS)

    Powerman, V.; Shatsillo, A.; Chumakov, N.; Kapitonov, I.; Hourigan, J. K.

    2015-12-01

    The goal of this study is to pinpoint the beginning of interaction of two gigantic crustal structures: the Siberian Craton and the Central Asian Orogenic Belt (CAOB). We hypothesize that the beginning of convergence should be recorded in the Neoproterozoic passive margin strata of Siberian Craton by the first appearance of extraregional Neoproterozoic zircons. In order to test this hypothesis, we have acquired U-Pb zircon age distributions from twelve Neoproterozoic clastic rocks from the Baikal-Patom margin of Siberia and one sample from the volcaniclastic Padrinsky Group that was deposited atop accreted CAOB crust. Stratigraphically lower strata from the Siberian margin yield Archean - Paleoproterozoic detrital zircon ages, which are similar to, and probably derived from the Siberian Precambrian craton. A few extra-regional Mesoproterozoic grains are also present. The provenance shift happens in the upper portion of the section and is marked by a strong influx of extra-regional Neoproterozoic sediments. The youngest grains of 610 Ma constrain the sedimentation age and confine the timing of interaction between CAOB and Siberia in this region. Neoproterozoic zircons also dominate the overlying sedimentary unit, suggesting the continuance of the convergence. The coeval volcanoclastic unit on the CAOB side has a similar U-Pb detrital age distribution, strengthening the provenance link. Analysis of the local tectonics suggests that the beginning of accretion might have started even before the first appearance of Neoproterozoic zircon: during the development of a regional unconformity, capped by 635 Ma (?) "Snowball Earth" tillites of Dzhemkukan Fm. The absence of Neoproterozoic zircons in Dzhemkukan Fm. is probably explained by a thin-skinned tectonics that did not result in massive orogenesis . Our data are in good correlation with other Neoproterozoic sedimentary basins of southern Siberian Craton, including Cisbaikalia and Bodaibo Synclinorium.

  20. Initiation and evolution of the Arabia-Eurasia collision in the Caucasus region constrained by detrital zircon geochronology

    NASA Astrophysics Data System (ADS)

    Tye, A. R.; Niemi, N. A.

    2016-12-01

    The Greater Caucasus (GC) mountain range is composed of thrust sheets of Paleozoic (Pz) - Mesozoic (Mz) flysch. Crystalline basement is exposed in the western part of the range, but not in the eastern. Detrital zircon ages from Eocene - recent foreland strata to the south of the western GC in Georgia suggest sediment sourcing from GC basement or Pz strata since Eocene time, requiring significant exhumation prior to or coincident with the onset of Arabia-Eurasia collision 30 Ma. We sampled foreland basin sedimentary rocks and modern river sands whose catchment areas together span the potential source rocks exposed in the western Greater Caucasus (GC) in Georgia. We find that GC basement rocks and lower Pz strata contain a diagnostic 450 Ma zircon population that is absent from the upper Pz and Mz sedimentary strata that are exposed throughout most of the range. These 450 Ma zircons are from an unknown source with an age distinct from the Hercynian ( 300 Ma) and Pan-African ( 600 Ma) orogens. Despite their absence in late Pz and Mz strata, the 450 Ma zircons are prevalent in Eocene - recent foreland basin deposits, whose ages were determined biostratigraphically [1]. Paleocurrent directions also indicate a GC source for Eocene strata [2], necessitating early Cenozoic exposure of GC basement or Pz strata. Exposing GC basement or Pz strata during Eocene time requires erosional removal of >3500 m of Mesozoic and late Paleozoic strata [1]. The detrital zircon age observations suggest that erosional removal of these strata took place prior to the initiation of the Arabia-Eurasia collision at 30 Ma and well before the ongoing episode of rapid GC exhumation and erosion from 5 Ma - present. Foreland basin detrital zircon ages also reveal a lack of input from Late Cretaceous to Paleogene volcanism of the Adjara-Trialet zone. This finding is consistent with the existence of a Paleogene ocean basin between the Greater Caucasus and Lesser Caucasus wide enough to prevent

  1. Potentially biogenic carbon preserved in a 4.1 billion-year-old zircon

    DOE PAGES

    Bell, Elizabeth A.; Boehnke, Patrick; Harrison, T. Mark; ...

    2015-10-19

    Here, evidence of life on Earth is manifestly preserved in the rock record. However, the microfossil record only extends to ~3.5 billion years (Ga), the chemofossil record arguably to ~3.8 Ga, and the rock record to 4.0 Ga. Detrital zircons from Jack Hills, Western Australia range in age up to nearly 4.4 Ga. From a population of over 10,000 Jack Hills zircons, we identified one >3.8-Ga zircon that contains primary graphite inclusions. Here, we report carbon isotopic measurements on these inclusions in a concordant, 4.10 ± 0.01-Ga zircon. We interpret these inclusions as primary due to their enclosure in amore » crack-free host as shown by transmission X-ray microscopy and their crystal habit. Their δ 13C PDB of –24 ± 5‰ is consistent with a biogenic origin and may be evidence that a terrestrial biosphere had emerged by 4.1 Ga, or ~300 My earlier than has been previously proposed.« less

  2. Potentially biogenic carbon preserved in a 4.1 billion-year-old zircon

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bell, Elizabeth A.; Boehnke, Patrick; Harrison, T. Mark

    Here, evidence of life on Earth is manifestly preserved in the rock record. However, the microfossil record only extends to ~3.5 billion years (Ga), the chemofossil record arguably to ~3.8 Ga, and the rock record to 4.0 Ga. Detrital zircons from Jack Hills, Western Australia range in age up to nearly 4.4 Ga. From a population of over 10,000 Jack Hills zircons, we identified one >3.8-Ga zircon that contains primary graphite inclusions. Here, we report carbon isotopic measurements on these inclusions in a concordant, 4.10 ± 0.01-Ga zircon. We interpret these inclusions as primary due to their enclosure in amore » crack-free host as shown by transmission X-ray microscopy and their crystal habit. Their δ 13C PDB of –24 ± 5‰ is consistent with a biogenic origin and may be evidence that a terrestrial biosphere had emerged by 4.1 Ga, or ~300 My earlier than has been previously proposed.« less

  3. Generation of Silicic Melts in the Early Izu-Bonin Arc Recorded by Detrital Zircons in Proximal Arc Volcaniclastic Rocks From the Philippine Sea

    NASA Astrophysics Data System (ADS)

    Barth, A. P.; Tani, K.; Meffre, S.; Wooden, J. L.; Coble, M. A.; Arculus, R. J.; Ishizuka, O.; Shukle, J. T.

    2017-10-01

    A 1.2 km thick Paleogene volcaniclastic section at International Ocean Discovery Program Site 351-U1438 preserves the deep-marine, proximal record of Izu-Bonin oceanic arc initiation, and volcano evolution along the Kyushu-Palau Ridge (KPR). Pb/U ages and trace element compositions of zircons recovered from volcaniclastic sandstones preserve a remarkable temporal record of juvenile island arc evolution. Pb/U ages ranging from 43 to 27 Ma are compatible with provenance in one or more active arc edifices of the northern KPR. The abundances of selected trace elements with high concentrations provide insight into the genesis of U1438 detrital zircon host melts, and represent useful indicators of both short and long-term variations in melt compositions in arc settings. The Site U1438 zircons span the compositional range between zircons from mid-ocean ridge gabbros and zircons from relatively enriched continental arcs, as predicted for melts in a primitive oceanic arc setting derived from a highly depleted mantle source. Melt zircon saturation temperatures and Ti-in-zircon thermometry suggest a provenance in relatively cool and silicic melts that evolved toward more Th and U-rich compositions with time. Th, U, and light rare earth element enrichments beginning about 35 Ma are consistent with detrital zircons recording development of regional arc asymmetry and selective trace element-enriched rear arc silicic melts as the juvenile Izu-Bonin arc evolved.

  4. Evidence from detrital zircons for the existence of continental crust and oceans on the Earth 4.4 Gyr ago.

    PubMed

    Wilde, S A; Valley, J W; Peck, W H; Graham, C M

    2001-01-11

    No crustal rocks are known to have survived since the time of the intense meteor bombardment that affected Earth between its formation about 4,550 Myr ago and 4,030 Myr, the age of the oldest known components in the Acasta Gneiss of northwestern Canada. But evidence of an even older crust is provided by detrital zircons in metamorphosed sediments at Mt Narryer and Jack Hills in the Narryer Gneiss Terrane, Yilgarn Craton, Western Australia, where grains as old as approximately 4,276 Myr have been found. Here we report, based on a detailed micro-analytical study of Jack Hills zircons, the discovery of a detrital zircon with an age as old as 4,404+/-8 Myr--about 130 million years older than any previously identified on Earth. We found that the zircon is zoned with respect to rare earth elements and oxygen isotope ratios (delta18O values from 7.4 to 5.0%), indicating that it formed from an evolving magmatic source. The evolved chemistry, high delta18O value and micro-inclusions of SiO2 are consistent with growth from a granitic melt with a delta18O value from 8.5 to 9.5%. Magmatic oxygen isotope ratios in this range point toward the involvement of supracrustal material that has undergone low-temperature interaction with a liquid hydrosphere. This zircon thus represents the earliest evidence for continental crust and oceans on the Earth.

  5. The pre-orogenic detrital zircon record of the Variscan orogeny: Preliminary results

    NASA Astrophysics Data System (ADS)

    Stephan, Tobias; Kroner, Uwe

    2017-04-01

    To test plate-tectonic constellations in consideration of the long-term development of sedimentary transport paths, temporally and spatially highly resolved records of provenance analysis are mandatory. The interpretation of existing studies focus on small-scale areas within an orogen thereby neglecting the differing distribution of provenance data in the entire orogenic system. This study reviews a large data set of compiled geochronological data to document the development of pre-orogenic tectonic units on the example of the Variscan orogeny. Constrained by tectonic and geological models, the temporal distribution of U-Pb detrital zircon ages, used as a proxy for sedimentary provenance, shows that some minima and maxima of zircon abundance are nearly synchronous for thousands of kilometres along the orogeny. Age spectra of Precambrian to Lower Palaeozoic samples were constructed on the basis of 38729 U-Pb ages from 685 samples that were compiled from 102 publications. The age compilation combines thermal ionization mass spectrometry (TIMS), laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS), sensitive high-resolution ion microprobe (SHRIMP), and secondary ion mass spectrometry (SIMS) analyses. The data was re-processed using a common age calculation and concordance filter to ensure comparability. The concordance of each zircon grain was calculated from 206Pb/238U and 207Pb/235U ages to guarantee that only concordant grains, i.e., with <10% normal and <5% reverse discordance, were included in the age compilation. In order to ignore a metamorphic overprint and hence a blur of the younger age spectra, the compilation is constrained to age data older than 400 Ma only. If a precise sample age is not documented by the author, the weighted-mean age of the youngest zircon population (n > 3) is used for the maximum age of deposition. In addition to the location of >600 samples, the precise depositional ages result in a spatially and temporally high

  6. Alpine Palaeogeography: new constraints from detrital zircon geochronology

    NASA Astrophysics Data System (ADS)

    Galster, Federico; Stockli, Daniel

    2017-04-01

    Schardt's (1898) discovery of the "allochtony" of the Préalpes Médianes and its exotic character, provided Alpine geologist with a first picture of Alpine palaeogeography: a Middle Jurassic sea divided in two branches by the rise of an emerged island. Later on, Schardt's island had been recognized at the scale of the Alpine belt and took the name of Briançonnais "geoanticline". In many Alpine palaeogeographic reconstructions, the Briançonnais and its exotic character have played a crucial role (e.g. Stampfli 1993; Manatschal et al., 2006;). In particular some of them explained the exotic character of the Briançonnais facies by proposing a pre-Cretaceous position located far from the Helvetic domain. In this view, the Briançonnais terrain was related to the Iberian plate and entered the Central Alpine system only after a Lower Cretaceous eastward drift associated with anticlockwise rotation of Iberia, opening of the northern Atlantic and closure of the Vardar ocean. In the Central Alps, the remnants of the northern Jurassic margin of the Alpine Tethys (sensu Stampfli) are contained in the Helvetic (s.l.) and Lower Penninic units. The basements and original substrate of these nappes are exposed in the crystalline external massifs and in the gneissic Lepontine dome. The highest, more internal, gneissic units within this dome are the Monte Leone, the Maggia and the Adula nappe. Theses units, as well as the autochthonous basement of the European margin, are characterized by large "Variscan" granitoids with ages between 290 and 330 Ma. The "ophiolite-bearing" units thrust on top of the Adula nappe are composed of Cretaceous and younger sedimentary rocks, with thin soles of Triassic and Jurassic strata. In addition to Variscan, Cambro-Ordovician and Proterozoic ages, detrital zircons in these soles show a peak at 260-280 Ma accompanied by a cluster of ca. 230 Ma zircons, similarly to what is observed in the Schams and Préalpes Médianes nappes (Briançonnais s

  7. Detrital zircon provenance evidence for large-scale extrusion along the Altyn Tagh fault

    USGS Publications Warehouse

    Yue, Y.; Graham, S.A.; Ritts, B.D.; Wooden, J.L.

    2005-01-01

    The question of whether or not the Altyn Tagh fault is a large-scale extrusion boundary is critical for understanding the role of lateral extrusion in accommodating the Indo-Asian convergence and in building the Tibetan Plateau. Oligocene conglomerate clasts in the eastern Xorkol basin are low-grade slate, phyllite, sandstone, dacite and carbonate, and associated paleocurrent indicators evince sediment derivation from the opposing side of the Altyn Tagh fault. Matching these clasts with similar basement rocks in the North Qilian and Tuolainanshan terranes requires post-Oligocene left-lateral offset of 380 ?? 60 km on the eastern segment of the Altyn Tagh fault, suggesting large-scale extrusion along the fault in the Cenozoic (Yue, Y.J., Ritts, B.D., Graham, S.A., 2001b. Initiation and long-term slip history of the Altyn Tagh fault. International Geological Review 43, 1087-1094.). In order to further define this piercing point, the detrital zircon pattern of Oligocene sandstone from the Xorkol basin and the zircon ages of basement on the southern side of the fault were established by ion microprobe dating. Characterized by strong peaks between 850 and 950 Ma and the absence of Paleozoic and Mesozoic ages, the detrital zircon age pattern of the Oligocene sandstone matches the age distribution of zircon-bearing rocks of the Tuolainanshan terrane. This match requires 360 ?? 40 km of post-Oligocene left-lateral displacement on the eastern segment of the Altyn Tagh fault, supporting as well as refining the previously reported lithology-based cross-fault match. At least one of the following three extrusion scenarios must have existed to accommodate this large offset: (1) northeastward extrusion along the Altyn Tagh-Alxa-East Mongolia fault, (2) eastward extrusion along the Altyn Tagh-North Qilian-Haiyuan fault, and (3) northeastward extrusion of northern Tibet as a Himalaya-scale thrust sheet along the North Qilian-Haiyuan fault. We prefer the first scenario inasmuch as

  8. Correlating rates of magmatic arc unroofing and sedimentation using detrital zircon U/Pb and (U-Th)/He thermochronology

    NASA Astrophysics Data System (ADS)

    Fosdick, J. C.

    2017-12-01

    Double and triple dating of minerals using multiple geo-thermochronometers has revolutionized efforts to evaluate complex thermotectonic histories of orogens, isolate unique sedimentary sources, and quantify basin burial reheating. A persisting challenge is to distinguish volcanic sources from rapidly exhumed sources, with the simplistic premise that coincident cooling dates among high- to low-temperature thermochronometers are diagnostic of volcanic sources. Coupled zircon U/Pb and (U-Th)/He geo-thermochronometry from the Miocene Bermejo foreland basin in the southern Central Andes reveals a high temporal resolution of unroofing signatures of the Choiyoi Group, a Permian-Triassic silicic volcanic and plutonic complex, and the Pennsylvanian-Permian Colangüil batholith. Both units are important sediment sources within the High Andes for the Cenozoic east-flowing sediment routing systems. Results show fluvial sourcing of Colangüil detrital zircons with progressively greater partial loss of He (<8% to 12-23% fractional loss from 9.5 Ma to 6 Ma), as indicated by upsection younging of zircon He dates for a given U/Pb age cluster. These findings suggest erosion of increasingly deeper levels of the Colangüil arc during late Miocene development of the High Andes. This progression of higher He loss and thus younger He dates during sedimentation for a given U/Pb age cluster is analogous to the magmatic arc unroofing trend revealed by undissected to dissected arc provenance fields in sandstone petrography. Multi-method thermochronometry of detrital minerals may reveal an added level of information regarding rates of cooling, unroofing, and thermal evolution of magmatic systems as preserved in the detrital record.

  9. Coordinated U–Pb geochronology, trace element, Ti-in-zircon thermometry and microstructural analysis of Apollo zircons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Crow, Carolyn A.; McKeegan, Kevin D.; Moser, Desmond E.

    Here, we present the results of a coordinated SIMS U–Pb, trace element, Ti-in-zircon thermometry, and microstructural study of 155 lunar zircons separated from Apollo 14, 15, and 17 breccia and soil samples that help resolve discrepancies between the zircon data, the lunar whole rock history and lunar magma ocean crystallization models. The majority of lunar grains are detrital fragments, some nearly 1 mm in length, of large parent crystals suggesting that they crystallized in highly enriched KREEP magmas. The zircon age distributions for all three landing sites exhibit an abundance of ages at ~4.33 Ga, however they differ in thatmore » only Apollo 14 samples have a population of zircons with ages between 4.1 and 3.9 Ga. These younger grains comprise only 10% of all dated lunar zircons and are usually small and highly shocked making them more susceptible to Pb-loss. These observations suggest that the majority of zircons crystallized before 4.1 Ga and that KREEP magmatism had predominantly ceased by this time. We also observed that trace element analyses are easily affected by contributions from inclusions (typically injected impact melt) within SIMS analyses spots. After filtering for these effects, rare-earth element (REE) abundances of pristine zircon are consistent with one pattern characterized by a negative Eu anomaly and no positive Ce anomaly, implying that the zircons formed in a reducing environment. This inference is consistent with crystallization temperatures based on measured Ti concentrations and new estimates of oxide activities which imply temperatures ranging between 958 ± 57 and 1321 ± 100 °C, suggesting that zircon parent magmas were anhydrous. Together, the lunar zircon ages and trace elements are consistent with a ≤300 My duration of KREEP magmatism under anhydrous, reducing conditions. We also report two granular texture zircons that contain baddeleyite cores, which both yield 207Pb– 206Pb ages of 4.33 Ga. These grains are our best

  10. Coordinated U-Pb geochronology, trace element, Ti-in-zircon thermometry and microstructural analysis of Apollo zircons

    NASA Astrophysics Data System (ADS)

    Crow, Carolyn A.; McKeegan, Kevin D.; Moser, Desmond E.

    2017-04-01

    We present the results of a coordinated SIMS U-Pb, trace element, Ti-in-zircon thermometry, and microstructural study of 155 lunar zircons separated from Apollo 14, 15, and 17 breccia and soil samples that help resolve discrepancies between the zircon data, the lunar whole rock history and lunar magma ocean crystallization models. The majority of lunar grains are detrital fragments, some nearly 1 mm in length, of large parent crystals suggesting that they crystallized in highly enriched KREEP magmas. The zircon age distributions for all three landing sites exhibit an abundance of ages at ∼4.33 Ga, however they differ in that only Apollo 14 samples have a population of zircons with ages between 4.1 and 3.9 Ga. These younger grains comprise only 10% of all dated lunar zircons and are usually small and highly shocked making them more susceptible to Pb-loss. These observations suggest that the majority of zircons crystallized before 4.1 Ga and that KREEP magmatism had predominantly ceased by this time. We also observed that trace element analyses are easily affected by contributions from inclusions (typically injected impact melt) within SIMS analyses spots. After filtering for these effects, rare-earth element (REE) abundances of pristine zircon are consistent with one pattern characterized by a negative Eu anomaly and no positive Ce anomaly, implying that the zircons formed in a reducing environment. This inference is consistent with crystallization temperatures based on measured Ti concentrations and new estimates of oxide activities which imply temperatures ranging between 958 ± 57 and 1321 ± 100 °C, suggesting that zircon parent magmas were anhydrous. Together, the lunar zircon ages and trace elements are consistent with a ⩽300 My duration of KREEP magmatism under anhydrous, reducing conditions. We also report two granular texture zircons that contain baddeleyite cores, which both yield 207Pb-206Pb ages of 4.33 Ga. These grains are our best constraints on

  11. Coordinated U–Pb geochronology, trace element, Ti-in-zircon thermometry and microstructural analysis of Apollo zircons

    DOE PAGES

    Crow, Carolyn A.; McKeegan, Kevin D.; Moser, Desmond E.

    2016-12-28

    Here, we present the results of a coordinated SIMS U–Pb, trace element, Ti-in-zircon thermometry, and microstructural study of 155 lunar zircons separated from Apollo 14, 15, and 17 breccia and soil samples that help resolve discrepancies between the zircon data, the lunar whole rock history and lunar magma ocean crystallization models. The majority of lunar grains are detrital fragments, some nearly 1 mm in length, of large parent crystals suggesting that they crystallized in highly enriched KREEP magmas. The zircon age distributions for all three landing sites exhibit an abundance of ages at ~4.33 Ga, however they differ in thatmore » only Apollo 14 samples have a population of zircons with ages between 4.1 and 3.9 Ga. These younger grains comprise only 10% of all dated lunar zircons and are usually small and highly shocked making them more susceptible to Pb-loss. These observations suggest that the majority of zircons crystallized before 4.1 Ga and that KREEP magmatism had predominantly ceased by this time. We also observed that trace element analyses are easily affected by contributions from inclusions (typically injected impact melt) within SIMS analyses spots. After filtering for these effects, rare-earth element (REE) abundances of pristine zircon are consistent with one pattern characterized by a negative Eu anomaly and no positive Ce anomaly, implying that the zircons formed in a reducing environment. This inference is consistent with crystallization temperatures based on measured Ti concentrations and new estimates of oxide activities which imply temperatures ranging between 958 ± 57 and 1321 ± 100 °C, suggesting that zircon parent magmas were anhydrous. Together, the lunar zircon ages and trace elements are consistent with a ≤300 My duration of KREEP magmatism under anhydrous, reducing conditions. We also report two granular texture zircons that contain baddeleyite cores, which both yield 207Pb– 206Pb ages of 4.33 Ga. These grains are our best

  12. Controls on Cenozoic exhumation of the Tethyan Himalaya from fission-track thermochronology and detrital zircon U-Pb geochronology in the Gyirong basin area, southern Tibet

    NASA Astrophysics Data System (ADS)

    Shen, Tianyi; Wang, Guocan; Leloup, Philippe Hervé; van der Beek, Peter; Bernet, Matthias; Cao, Kai; Wang, An; Liu, Chao; Zhang, Kexin

    2016-07-01

    The Gyirong basin, southern Tibet, contains the record of Miocene-Pliocene exhumation, drainage development, and sedimentation along the northern flank of the Himalaya. The tectonic controls on basin formation and their potential link to the South Tibetan Detachment System (STDS) are not well understood. We use detrital zircon (ZFT) and apatite (AFT) fission-track analysis, together with detrital zircon U-Pb dating to decipher the provenance of Gyirong basin sediments and the exhumation history of the source areas. Results are presented for nine detrital samples of Gyirong basin sediments (AFT, ZFT, and U-Pb), two modern river-sediment samples (ZFT and AFT), and six bedrock samples (ZFT) from transect across the Gyirong fault bounding the basin to the east. The combination of detrital zircon U-Pb and fission-track data demonstrates that the Gyirong basin sediments were sourced locally from the Tethyan Sedimentary Sequence. This provenance pattern indicates that deposition was controlled by the Gyirong fault, active since 10 Ma, whose vertical throw was probably < 5000 m, rather than being controlled by normal faults associated with the STDS. The detrital thermochronology data contain two prominent age groups at 37-41 and 15-18 Ma, suggesting rapid exhumation at these times. A 15-18 Ma phase of rapid exhumation has been recorded widely in both southern Tibet and the Himalaya. A possible interpretation for such a major regional exhumation event might be detachment of the subducting Indian plate slab during the middle Miocene, inducing dynamic uplift of the Indian plate overriding its own slab.

  13. A detrital zircon provenance study of the Lower Carboniferous sequences in the East Fife section of the Midland Valley of Scotland

    NASA Astrophysics Data System (ADS)

    Murchie, Sean; Robinson, Ruth, ,, Dr; Lancaster, Penelope, ,, Dr

    2014-05-01

    Detrital zircons from the Lower Carboniferous clastic rocks of the Midland Valley of Scotland have been dated using U-Pb laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) to determine which source areas contributed sediment to the basin during its development, and to investigate whether provenance changed during deposition of these units. Specific provenance detection using U/Pb dating of zircons has never been attempted in these rocks, and there are uncertainties remaining about the regional paleogeographic setting for the Midland Valley. Four samples from the Dinantian Strathclyde Group have been analysed, and the units are locally known as the Fife Ness, Anstruther, Pittenweem, Sandy Craig, and Pathhead formations. The formations are composed of shallow marine, deltaic, fluvial and floodplain deposits and these predominantly siliciclastic sedimentary rocks are interbedded with thin fossiliferous carbonate bands. The samples are quartz arenitic, sub-arkosic and lithic arkosic medium-grained sandstones, predominantly from a fluvial origin. The British Geological Survey developed a lithostratigraphy which is the most used framework for the Strathclyde Group (Browne et al., 1997), but a different biostratigraphical framework based on palynology has been proposed by Owens et al. (2005). In addition to identifying provenance, the zircon age populations for each formation are compared to test which stratigraphic framework is correct. More broadly, the provenance data provides a way to improve the regional palaeogeographic setting for the Midland Valley. Zircon ages in the Strathclyde Group are dominated by Late Mesoproterozoic to Late Palaeoproterozoic (0.9 - 2.0 Ga) and Early Palaeozoic (350 - 450 Ma) ages which reflect Caledonide (Laurentian-Baltica margin including Scotland, Scandinavia, Greenland, Newfoundland), Grampian and internal Midland Valley source areas. Notable peaks occur at 400 Ma, 1.0 --1.1 Ga, 1.3 Ga, 1.6 - 1.7 Ga, and 2.7 Ga, and

  14. Triassic North American paleodrainage networks and sediment dispersal of the Chinle Formation: A quantitative approach utilizing detrital zircons

    NASA Astrophysics Data System (ADS)

    Blum, M. D.; Umbarger, K.

    2017-12-01

    The Triassic Chinle Formation is a fluvial succession deposited in a backarc setting across the present-day Colorado Plateau of the southwestern United States. Existing studies have proposed various mechanisms responsible for the unique stratigraphic architecture and depositional sequences of the Chinle. However, these studies lack necessary age control to correlate stratigraphic patterns with contemporaneous mechanisms. This study will collect new samples for detrital zircon analysis, as well as upgrade existing samples (to n=300) from Dickinson and Gehrels (2008), to improve the resolution of Triassic sediment provenance from source-to-sink. The improved dataset allows appraisal of the multiple provenance terranes that contributed to the Chinle depositional system to delineate and reconstruct paleodrainage patterns. The additional samples will be collected systematically from the base of the Chinle, and vertically throughout the section to capture a regional story of how the continental scale drainage reorganized through time. U-Pb ages of detrital zircons will be utilized to provide quantitative fingerprinting information to constrain interpretations for the origin and transport history of the Chinle fluvial succession in time and space.

  15. Phanerozoic polyphase orogenies recorded in the northeastern Okcheon Belt, Korea from SHRIMP U-Pb detrital zircon and K-Ar illite geochronologies

    NASA Astrophysics Data System (ADS)

    Jang, Yirang; Kwon, Sanghoon; Song, Yungoo; Kim, Sung Won; Kwon, Yi Kyun; Yi, Keewook

    2018-05-01

    We present the SHRIMP U-Pb detrital zircon and K-Ar illite 1Md/1M and 2M1 ages, suggesting new insight into the Phanerozoic polyphase orogenies preserved in the northeastern Okcheon Belt, Korea since the initial basin formation during Neoproterozoic rifting through several successive contractional orogens. The U-Pb detrital zircon ages from the Early Paleozoic strata of the Taebaeksan Zone suggest a Cambrian maximum deposition age, and are supported by trilobite and conodont biostratigraphy. Although the age spectra from two sedimentary groups, the Yeongwol and Taebaek Groups, show similar continuous distributions from the Late Paleoproterozoic to Early Paleozoic ages, a Grenville-age hiatus (1.3-0.9 Ga) in the continuous stratigraphic sequence from the Taebaek Group suggests the existence of different peripheral clastic sources along rifted continental margin(s). In addition, we present the K-Ar illite 1Md/1M ages of the fault gouges, which confirm fault formation/reactivation during the Late Cretaceous to Early Paleogene (ca. 82-62 Ma) and the Early Miocene (ca. 20-18 Ma). The 2M1 illite ages, at least those younger than the host rock ages, provide episodes of deformation, metamorphism and hydrothermal effects related to the tectonic events during the Devonian (ca.410 Ma) and Permo-Triassic (ca. 285-240 Ma). These results indicate that the northeastern Okcheon Belt experienced polyphase orogenic events, namely the Okcheon (Middle Paleozoic), Songrim (Late Paleozoic to Early Mesozoic), Daebo (Middle Mesozoic) and Bulguksa (Late Mesozoic to Early Cenozoic) Orogenies, reflecting the Phanerozoic tectonic evolution of the Korean Peninsula along the East Asian continental margin.

  16. Using Detrital Zircon Geochronology to Constrain Paleogene Provenance and Its Relationship to Rifting in the Zhu 1 Depression, Pearl River Mouth Basin, South China Sea

    NASA Astrophysics Data System (ADS)

    Wang, Wei; Ye, Jiaren; Bidgoli, Tandis; Yang, Xianghua; Shi, Hesheng; Shu, Yu

    2017-11-01

    Paleogene syn-rift successions in the South China Sea are poorly understood and systematic provenance analysis, which could provide clues to their history, is lacking. Here we report 409 new concordant U-Pb ages from detrital zircons separated from the Paleogene Wenchang, Enping, and Zhuhai formations in the Zhu 1 depression, Pearl River Mouth Basin. The new data, combined with the published age data from the region, document changes in the provenance of syn-rift successions. Detrital zircons from the Eocene Wenchang Formation are unimodal, with Jurassic-Cretaceous (180-80 Ma) ages making up >80% of grains. The ages are consistent with the geochronology of intrabasinal highs, dominated by igneous rocks emplaced during the Yanshanian orogeny, and suggest local provenance. By contrast, detrital zircons from the upper Eocene to lower Oligocene Enping Formation form three well-recognized age-clusters, with peaks at 150, 254, and 438 Ma that match documented tectonomagmatism in South China Block (SCB). Combined with increasing numbers of Precambrian zircons, the data suggest increasing influence of regional provenance of the SCB. Similar age peaks are also recognized from the limited number of zircons analyzed from the upper Oligocene Zhuhai Formation and comparability with modern shelf and river sediment indicates the unit was mainly sourced from the SCB and likely transported by a paleo-Pearl River. We infer that the change in provenance, from local uplifts within the Zhu 1 to the SCB, is related to distinct phases of PRMB rift development; however, later changes are best explained by SCB drainage evolution.

  17. Detrital Zircon U-Pb and Hf-isotope Constrains on Basement Ages, Granitic Magmatism, and Sediment Provenance in the Malay Peninsula

    NASA Astrophysics Data System (ADS)

    Sevastjanova, Inga; Clements, Benjamin; Hall, Robert; Belousova, Elena; Pearson, Norman; Griffin, William

    2010-05-01

    The Malay Peninsula forms the western part of central Sundaland in SE Asia. Sundaland comprises Indochina, the Thai-Malay Peninsula, Sumatra, Java, Borneo, and the shallow shelf between these landmasses. It is a composite region of continental crustal fragments that are separated by sutures that represent remnant ocean basins and volcanic arcs. The Malay Peninsula includes two of these fragments - East Malaya and Sibumasu - separated by the Bentong-Raub Suture Zone. The latter is a Palaeo-Tethyan ocean remnant. Granitoids of the Malay Peninsula are the major sources of detrital zircon in Sundaland. East Malaya is intruded by Permian-Triassic Eastern Province granitoids interpreted as products of Palaeozoic subduction of oceanic crust beneath the East Malaya Volcanic Arc. Sibumasu is intruded by Triassic Main Range Province granitoids interpreted as syn- to post-collisional magmatism following suturing to East Malaya. Locally, there are minor Late Cretaceous plutons. Basements of Sibumasu and East Malaya are not exposed and their ages are poorly constrained. The exact timing of the collision between these fragments is also contentious. In order to resolve these uncertainties, 752 U-Pb analyses from 9 samples were carried out on detrital zircons from modern rivers draining the Malay Peninsula and, of these, 243 grains from 6 samples were selected for Hf-isotope analyses. U-Pb zircon ages show that small numbers of Neoarchean-Proterozoic grains are consistently present in all samples, but do not form prominent populations. Permian-Triassic populations are dominant. Only one sample contains a small Jurassic population probably sourced from the area of Thailand and most likely recycled from fluvial-alluvial Mesozoic 'red-beds'. Late Cretaceous populations are locally abundant. Hf-isotope crustal model ages suggest that basement beneath the Malay Peninsula is heterogeneous. Some basement may be Neoarchean but there is no evidence for basement older than 2.8 Ga beneath

  18. Detrital zircon geochronology of the Adams Argillite and Nation River Formation, east-central Alaska, U.S.A

    USGS Publications Warehouse

    Gehrels, G.E.; Johnsson, M.J.; Howell, D.G.

    1999-01-01

    The Cambrian Adams Argillite and the Devonian Nation River Formation are two sandstone-bearing units within a remarkably complete Paleozoic stratigraphic section in east-central Alaska. These strata, now foreshortened and fault-bounded, were originally contiguous with miogeoclinal strata to the east that formed as a passive-margin sequence along the northwestern margin of the North American continent. Seventy-five detrital zircon grains from the Adams Argillite and the Nation River Formation were analyzed in an effort to provide constraints on the original sources of the grains, and to generate a detrital zircon reference for miogeoclinal strata in the northern Cordillera. Thirty-five single zircon grains from a quartzite in the Adams Argillite yield dominant age clusters of 1047-1094 (n = 6), 1801-1868 (n = 10), and 2564-2687 (n = 5) Ma. Forty zircons extracted from a sandstone in the Nation River Formation yield clusters primarily of 424-434 (n = 6), 1815-1838 (n = 6), 1874-1921 (n = 7), and 2653-2771 (n = 4) Ma. The Early Proterozoic and Archean grains in both units probably originated in basement rocks in a broad region of the Canadian Shield. In contrast, the original igneous sources for mid-Protcrozoic grains in the Adams Argillite and ??? 430 Ma grains in the Nation River Formation are more difficult to identify. Possible original sources for the mid-Proterozoic grains include: (1) the Grenville Province of eastern Laurentia, (2) the Pearya terrane along the Arctic margin, and (3) mid-Proterozoic igneous rocks that may have been widespread along or outboard of the Cordilleran margin. The ??? 430 Ma grains may have originated in: (1) arc-type sources along the Cordilleran margin, (2) the Caledonian orogen, or (3) a landmass, such as Pearya, Siberia, or crustal fragments now in northern Asia, that resided outboard of the Innuitian orogen during mid-Paleozoic time. Copyright ?? 1999, SEPM (Society for Sedimentary Geology).

  19. Detrital Zircon Signature of Proterozoic Metasedimentary Rocks of the Pearya Terrane, Northern Ellesmere Island: Implications for Terrane Stratigraphy and Circum-Arctic Terrane Correlations

    NASA Astrophysics Data System (ADS)

    Malone, S. J.; McClelland, W.

    2012-12-01

    The Pearya Terrane, currently recognized as the only exotic terrane in the Canadian Arctic margin, includes early Tonian metaigneous rocks and a sequence of sedimentary rocks ranging from Proterozoic shallow marine to Silurian arc-accretionary units. Succession II (Trettin, 1987) of the Pearya Terrane represents variably metamorphosed metasedimentary rocks of presumed Neoproterozoic to early Ordocician age. These units are structurally juxtaposed with earliest Neoproterozoic orthogneiss of Succession I and the overlaying sedimentary rocks of the Paleozoic section. Detrital zircon age spectra from seven samples of Neoproterozoic meta-sedimentary rocks define three groups on the basis of dominant age peaks and the age of the youngest peaks. Group I, representing three quartzite samples, contains young zircon age peaks at c. 1050 Ma with numerous c. 1100 Ma to 1800 Ma peaks. Detrital zircon spectra from Group I correlate closely with data from the latest Mesoproterozoic Brennevinsfjorden Group of Northeastern Svalbard, suggesting that the base of Succession II may be older than the Succession I orthogneiss, and that the contact between them is tectonic. Group II is defined by a dominant c. 970 Ma age peak that overlaps with ages determined for basement orthogneiss units and indicates that local sedimentary sources, possibly relating to Tonian igneous activity, dominated. Group III displays a similar pattern of c. 1000 Ma to 1800 Ma age peaks to Group I, but contains a small population of c. 600 Ma to 700 Ma grains that are likely sourced from elements of the Timanide orogen and/or the Arctic Alaska-Chukotka (AAC) microplate. The ubiquitous Mesoproterozoic ages suggest extensive sediment input from the Grenville-Svegonorwegian domains of Laurentia and Baltica, either directly or by sediment recycling. This is consistent with detrital zircon datasets from other North Atlantic-Arctic Caledonide terranes, reinforcing stratigraphic links between the Pearya Terrane

  20. Recycling of Amazonian detrital zircons in the Mixteco terrane, southern Mexico: Paleogeographic implications during Jurassic-Early Cretaceous and Paleogene times

    NASA Astrophysics Data System (ADS)

    Silva-Romo, Gilberto; Mendoza-Rosales, Claudia Cristina; Campos-Madrigal, Emiliano; Morales-Yáñez, Axél; de la Torre-González, Alam Israel; Nápoles-Valenzuela, Juan Ivan

    2018-04-01

    In the northeastern Mixteco terrane of southern Mexico, in the Ixcaquixtla-Atzumba region, the recycling of Amazonian detrital zircons records the paleogeography during the Mesozoic period in the context of the breakup of Pangea, a phenomenon that disarticulated the Sanozama-La Mora paleo-river. The clastic units of southern Mexico in the Ayuquila, Otlaltepec and Zapotitlán Mesozoic basins, as well as in the Atzumba Cenozoic basin, are characterized by detrital zircon contents with ages specific to the Amazonian craton, ranging between 3040 and 1278 Ma. The presence of zircons of Amazonian affinity suggests a provenance by recycling from carrier units such as the La Mora Formation or the Ayú Complex. In the area, the Ayú and Acatlán complexes form the Cosoltepec block, a paleogeographic element that during Early Cretaceous time acted as the divide between the slopes of the paleo-Gulf of Mexico and the paleo-Pacific Ocean. The sedimentological characteristics of the Jurassic-Cenozoic clastic successions in the Ixcaquixtla-Atzumba region denote relatively short transport in braided fluvial systems and alluvial fans. In this way, several basins are recognized around the Cosoltepec block. At the southeastern edge of the Cosoltepec block, the Ayuquila and Tecomazúchil formations accumulated in the Ayuquila continental basin on the paleo-Pacific Ocean slope. On the other hand, within the paleo-Gulf of Mexico slope, in the Otlaltepec continental basin, the Piedra Hueca and the Otlaltepec formations accumulated. The upper member of the Santa Lucía Formation accumulated in a transitional environment on the southwestern shoulder of the Zapotitlán basin, as well as on the paleo-Gulf of Mexico slope. In the Ayuquila basin, a marine transgression is recognized that advanced from south to north during the Late Jurassic. At the northeastern edge of the Cosoltepec block, we propose that the Santa Lucía formation attests to a transgression from the paleo-Gulf of Mexico

  1. Detrital zircon provenance of the Hartselle Sandstone Unit, Southeastern USA: Insights into sediment source, paleogeography, and setting

    NASA Astrophysics Data System (ADS)

    Harthy, M. A.; Gifford, J.

    2017-12-01

    The Hartselle sandstone is an excellent example of an Oil sand, a resource rich in bitumen. The unit is a light-colored thick-bedded to massive quartzose sandstone, that is widespread across an area from Georgia in the east to Mississippi in the west, and south from Alabama to Kentucky as a northern border. Formation thickness ranges from 0 to more than 150 feet. The unit has been stratigraphically dated to the Middle-Upper Mississippian age. One hypothesis suggests that the sandstone unit formed from the geological remains of barrier islands located in the ocean between Gondwana and Laurentia. The Hartselle is thought to have formed by the movement waves and currents along the shoreline, which carried sand and concentrated it into a set of northwest to southeast trending barrier islands. Transgression-regression events shifted the islands back and forth in relation to the position of the shoreline, leading to the large areal extent of the unit. However, the current data are not enough to explain the geographical position of the Hartselle sandstone unit as it is not running parallel to the ancient shoreline. Another mystery is the source of the sand, some believing the source was from the south (Gondwana) and others that erosion was from the north (Laurentia). Detrital zircon provenance analysis will address the uncertainty in sediment source. We will compare zircon U-Pb age spectra to possible Laurentian and Gondwanan source areas to discriminate between these possibilities. In addition, the age of the youngest detrital zircon population will provide additional constraints on the maximum age of deposition for the unit. These detrital ages will also help us to understand the tectonic setting at the time of Hartselle deposition. Lastly, we aim to explain the widespread nature of the unit and the processes involved in the formation of the Hartselle sandstone. When taken together, these interpretations will illuminate the age, depositional and tectonic setting of a

  2. New Evidence for opening of the Black Sea; U-Pb analysis of detrital zircons and paleocurrent measurements of the Early Cretaceous turbidites

    NASA Astrophysics Data System (ADS)

    Akdoğan, Remziye; Okay, Aral I.; Sunal, Gürsel; Tari, Gabor; Kylander-Clark, Andrew R. C.

    2015-04-01

    Shelf to submarine turbidite fan deposits of the Early Cretaceous crop out over a large area along the southern coast of the Black Sea. Early Cretaceous turbidites have a thickness of over 2000 meters in the Central Pontides. The shelf of this turbidite basin, represented by shallow marine clastics and carbonates, crops out along the Black Sea coast between Zonguldak and Amasra. Paleocurrent directions in the Lower Cretaceous turbidites were measured in 90 localities using mostly flute and groove casts and to a lesser extend cross-beds. At the eastern part of the basin, the paleocurrents were from north to south. It is scattered in the west of the basin, however, the main paleocurrent directions were from the north. Detrital zircons were analyzed using LA-ICP-MS in eleven samples from the turbiditic sandstones and two samples from the shelf sandstones. Four samples are from the western part (two samples from shelf sediments), four samples from the central part and five samples from the eastern part of the Lower Cretaceous basin. 1085 of 1348 zircon analyses are concordant with rates of 95-105% and the zircon ages range between 141 ± 4 Ma (Berriasian) and 3469 ± 8 Ma (Paleoarchean). 22% of the detrital zircon ages are Paleoproterozoic, 20% Archean, 16% Carboniferous, 13% Neoproterozoic, 8% Permian, 6% Triassic, 5% Mesoproterozoic and 11% other ages. In the western part of the basin the Carboniferous zircons constitute the main population with a less dominant peak at Ordovician, Cambrian and Late Neoproterozoic. The zircons from the center of the basin show scattered distribution with dominant populations in the Triassic, Permian, Carboniferous, Silurian, Paleoproterozoic, Early Neoproterozoic-Late Mesoproterozoic, and minor peak at Late Neoarchean. On the other hand, zircons from the eastern most part of the basin, show dominant peaks in the Paleoproterozoic, Mesoarchean and Permian with minor peaks in Triassic, Carboniferous and Silurian. Anatolia and the Balkans

  3. Zircon ion microprobe dating of high-grade rocks in Sri Lanka

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kroener, A.; Williams, I.S.; Compston, W.

    1987-11-01

    The high-grade gneisses of Sri Lanka display spectacular in-situ granulitization phenomena similar to those observed in southern India and of current interest for evolutionary models of the lower continental crust. The absolute ages of these rocks are poorly constrained and so, using the SHRIMP ion microprobe, the authors have analyzed small spots on zircons from upper amphibolite to granulite grade quartzitic and pelitic metasediments. Detrital grains from a metaquartzite of the Highland Group preserve premetamorphic U-Pb ages of between 3.17 and 2.4 Ga and indicate derivation of the sediment from an unidentified Archean source terrain. The Pb-loss patterns of thesemore » zircons and the other samples suggest severe disturbance at ca 1100 Ma ago, which the authors attribute to high-grade regional metamorphism. Two pelitic gneisses contain detrital zircons with ages up to 2.04 Ga and also record an approx. = 1100 Ma event that is also apparent from metamorphic rims around old cores and new zircon growth. A granite intrusive into the Highland Group granulites records an emplacement age of 1000-1100 Ma as well as metamorphic disturbance some 550 Ma ago but also contains older, crustally derived xenocrysts. Zircons from a metaquartzite xenolith within the granitoid Vijayan Complex are not older than approx. 1100 Ma; therefore the Vijayan is neither Archean in age nor acted as basement to the Highland Group, as previously proposed. The authors suggest that the Vijayan Complex formed significantly later than the Highland Group and that the two units were brought into contact through post-1.1 Ga thrusting. Although the granulitization phenomena in India and Sri Lanka are similar, the granulite event in Sri Lanka is not Archean in age but took place in the late Proterozoic.« less

  4. Evidence of early Archean crust in northwest Gondwana, from U-Pb and Hf isotope analysis of detrital zircon, in Ediacaran surpacrustal rocks of northern Spain

    NASA Astrophysics Data System (ADS)

    Naidoo, Thanusha; Zimmermann, Udo; Vervoort, Jeff; Tait, Jenny

    2018-03-01

    The Mora Formation (Narcea Group) is one of the oldest Precambrian supracrustal successions in northern Spain. Here, we use U-Pb and in situ Hf isotope analysis on detrital zircon to determine its age and provenance. The youngest U-Pb dates constrain the maximum depositional age of the Mora Formation at 565 ± 11 Ma. Results indicate: (1) a dominant Ediacaran zircon population (33%; 565-633 Ma, Cadomian) within a spectrum of Neoproterozoic ages (40%; 636-996 Ma); and (2) smaller Mesoproterozoic (5%; 1004-1240 Ma), Palaeoproterozoic (11%; 1890-2476 Ma) and Archean (11%; 2519-3550 Ma) populations. Results here do not point to one specific cratonic source area; instead, detritus may have been derived from the West African craton and Amazonia, or even the concealed Iberian basement. The lack of 1.3-1.8 Ga grains suggests exclusion of the Sahara Craton as a major source, but this is not certain. This mixed composition favours a complex source history with reworking of detritus across terrane/craton boundaries. Hafnium isotope compositions indicate a range of crustal and juvenile sources, with initial ɛHf values between -15.8 and 11.1, and Hf model ages from 0.8 to 3.7 Ga. For Neoproterozoic zircons (80%), juvenile components (ɛHf(i) +10) may be related to Rodinia fragmentation and the onset of an active margin setting leading to the Cadomian orogeny. Palaeoproterozoic to Paleoarchean grains (20%) all have negative ɛHf values and Meso- to Eoarchean Hf model ages. This indicates an early (Archean) sialic crustal component for northwestern Gondwana.

  5. Detrital zircon U-Pb Geochronology of the Boleo Formation of Santa RosalÍa Basin, Baja California Sur, México

    NASA Astrophysics Data System (ADS)

    Henry, M.; Alvarez Ortega, K. G.; Banes, A.; Holm-Denoma, C.; Busby, C.; Niemi, T.

    2017-12-01

    The Santa Rosalía Basin (SRB) is a rift basin related to the opening of the Gulf of California. The Boleo Formation is the oldest and dominant sedimentary fill of the SRB, with a poorly constrained age. We carried out a U-Pb detrital zircon (DZ) study of the Boleo Formation to constrain its maximum depositional age. The Boleo Formation has a basal limestone-gypsum section, overlain by an up to 250 m thick clastic sequence, with coarsening upward cycles of mudstone, sandstone, and conglomerate. Cu-Zn-Co-Mn stratiform ore deposits ("mantos") cap the conglomerate in each cycle, numbered 0, 1, 2, 3 and 4 (from top to bottom of section1). Sandstone samples were collected for U-Pb detrital zircon geochronology from four stratigraphic levels beneath a manto, including one each below mantos 1, 3 and 4, as well as two localities beneath manto 2. Additionally, one sample was collected above the gypsum. The sandstones are lithic feldspathic wackes derived from erosion of andesitic arc volcanic rocks, which generally lack zircon, so large DZ samples were collected. A field Wilfley table was constructed from local materials as a first step to concentrate heavy minerals, from 88 kg/sample to 16 kg/sample. The field-processed samples were further concentrated in the lab using standard zircon separation methods. Yields were excellent, 1,000 zircons per sample. We analyzed 315 zircons per sample by LA-ICPMS, using the Arizona LaserChron Center. DZ ages from the Boleo Formation range dominantly from Late Miocene through Early Cretaceous, with minor Paleozoic and Precambrian ages. However, the maximum depositional age of the formation is constrained by 40 Ar/39 Ar age of 9.42 +/- 0.29 Ma on underlying volcanic rocks2. Only 5 to 22 zircons per sample are less than 10 Ma, and of those, all stratigraphic levels are dominated mostly by 9 Ma zircons, except for the stratigraphically highest sample. Zircons from this form a coherent group of 3 with a TuffZirc age of 6.04 +/- 0.02 (75

  6. Sands of West Gondwana: An archive of secular magmatism and plate interactions — A case study from the Cambro-Ordovician section of the Tassili Ouan Ahaggar (Algerian Sahara) using U-Pb-LA-ICP-MS detrital zircon ages

    NASA Astrophysics Data System (ADS)

    Linnemann, Ulf; Ouzegane, Khadidja; Drareni, Amar; Hofmann, Mandy; Becker, Sindy; Gärtner, Andreas; Sagawe, Anja

    2011-04-01

    Enormous masses of highly mature quartz sands were deposited in Western Gondwana during the Cambrian-Ordovician time, and provide a wide range of information concerning magmatic events through time, provenance, paleoclimate, and basin history. We present a provenance study based on 630 U-Pb (LA-ICP-MS) ages of detrital zircon from the latest Cambrian to Ordovician siliciclastic rocks of the Tassili Ouan Ahaggar basin situated in the Algerian Sahara. Most authors suggest local sources only for the sandstones. Instead, we demonstrate that the detritus is derived from different cratons and terranes which contributed to the deposition of a Cambrian-Ordovician overstep sequence covering western and northern Africa. Most zircon ages (61.0%) fall in the range of ~ 540 to 740 Ma and are interpreted to have been derived from Pan-African orogenic belts such as the Trans-Saharan Belt of NW Africa and previously from the Brazila belt of South America. Other potential sources for this zircon population are terranes of Cadomian affinity situated marginal to West Africa. The second-largest zircon population (20.2%) is 2.0 to 2.2 Ga, and is attributed to sources in the West African craton, such as the Birimian basement and the Eburnean orogenic belt, with possible partial input from the Amazonian craton. A zircon population of 7.1% yields Mesoproterozoic and early Paleoproterozoic ages in the range of ~ 1.3 to ~ 1.8 Ga and was probably derived from source rocks outside of the West African basement, the Tuareg shield and other adjoining areas. The Amazonian craton is a potential source region. A population of 6.7% of all zircon ages scatter from ~ 750 Ma to ~ 980 Ma and may reflect input from latest stages of the formation of Rodinia and its subsequent dispersal. A smaller population (3.2%) of zircon ages lie between ~ 2.3 and 2.65 Ga, and may be derived from late Paleoproterozoic to early Archaean rocks from the West African craton and possibly from Amazonia. Less than 1% of all

  7. Paleoproterozoic mojaveprovince in northwestern Mexico? Isotopic and U-Pb zircon geochronologic studies of precambrian and Cambrian crystalline and sedimentary rocks, Caborca, Sonora

    USGS Publications Warehouse

    Lang, Farmer G.; Bowring, S.A.; Matzel, J.; Maldonado, G.E.; Fedo, C.; Wooden, J.

    2005-01-01

    Whole-rock Nd isotopic data and U-Pb zircon geochronology from Precambrian crystalline rocks in the Caborca area, northern Sonora, reveal that these rocks are most likely a segment of the Paleoproterozoic Mojave province. Supporting this conclusion are the observations that paragneiss from the ??? 1.75 Ga Bamori Complex has a 2.4 Ga Nd model age and contains detrital zircons ranging in age from Paleo- proterozoic (1.75 Ga) to Archean (3.2 Ga). Paragneisses with similar age and isotopic characteristics occur in the Mojave province in southern California. In addition, "A-type" granite exposed at the southern end of Cerro Rajon has ca 2.0 Ga Nd model age and a U-Pb zircon age of 1.71 Ga, which are similar to those of Paleoproterozoic granites in the Mojave province. Unlike the U.S. Mojave province, the Caborcan crust contains ca. 1.1 Ga granite (Aibo Granite), which our new Nd isotopic data suggest is largely the product of anatexis of the local Precambrian basement. Detrital zircons from Neoproterozoic to early Cambrian miogeoclinal arenites at Caborca show dominant populations ca. 1.7 Ga, ca. 1.4 Ga, and ca. 1.1 Ga, with subordinate Early Cambrian and Archean zircons. These zircons were likely derived predominately from North American crust to the east and northeast, and not from the underlying Caborcan basement. The general age and isotopic similarities between Mojave province basement and overlying miogeoclinal sedimentary rocks in Sonora and southern California is necessary, but not sufficient, proof of the hypothesis that Sonoran crust is allochthonous and was transported to its current position during the Mesozoic along the proposed Mojave-Sonora megashear. One viable alternative model is that the Caborcan Precambrian crust is an isolated, autochthonous segment of Mojave province crust that shares a similar, but not identical, Proterozoic geological history with Mojave province crust found in the southwest United States ?? 2005 Geological Society of America.

  8. U-Pbdating on detrital zircon and Nd and Hf isotopes related to the provenance of siliciclastic rocks of the Amazon Basin: Implications for the origin of Proto-Amazonas River

    NASA Astrophysics Data System (ADS)

    Dantas, Elton Luiz; Silva Souza, Valmir; Nogueira, Afonso C. R.; Ventura Santos, Roberto; Poitrasson, Franck; Vieira Cruz, Lucieth; Mendes Conceição, Anderson

    2014-05-01

    Previous provenance studies along the Amazonas river have demonstrated that the Amazon drainage basin has been reorganized since the Late Cretaceous with the uplift of the Andes and the establishment of the transcontinental Amazon fluvial system from Late Miocene to Late Pleistocene (Hoorn et al., 1995; Potter, 1997, Wesselingh et al., 2002; Figueiredo et al. 2009, Campbell et al., 2006, Nogueira et al. 2013).There is a lack of data from Eastern and Central Amazonia and only limited core data from the Continental Platform near to current Amazonas river mouth. Central Amazonia is strategic to unveil the origin of Amazonas River because it represents the region where the connection of the Solimões and Amazonas basin can be studied through time (Nogueira et al. 2013). Also, there is a shortage of information on the old Precambrian and Paleozoic sediment sources relative to Cretaceous and Miocene siliciclastic deposits of the Solimões and Amazonas basins. We collected stratigraphic data, detrital zircon U-Pb ages and Nd and Hf isotopes from Precambrian, Paleozoic, Cretaceous and Miocene siliciclastic deposits of the Northwestern border of Amazonas Basin. They are exposed in the Presidente Figueiredo region and in the scarps of Amazon River, and occur to the east of the Purus Arch. This Northwest-Southeast trending structural feature that divides the Solimões and Amazonas basin was active at various times since the Paleozoic. Detrital zircon ages for the Neoproterozoic Prosperança Formation yielded a complex signature, with different populations of Neoproterozoic (550, 630 and 800 Ma) and Paleoproterozoic to Archean sources (1.6, 2.1 and 2.6 Ga). Also Nd and Hf isotopes show two groups of TDM model ages between 1.4 to 1.53 Ga and 2.2 and 3.1 Ga. Sediments typical of Paleozoic sedimentary rocks of the Nhamundá and Manacapuru Formations revealed NdTDM model ages of 1.7, 2.2 and 2.7 Ga, but Hf isotopes and U-Pb zircon ages are more varied. They characterize a

  9. New Analyses of Diverse Hadean Zircon Inclusions from Jack Hills, Western Australia

    NASA Technical Reports Server (NTRS)

    Trail, D.; Catlos, E. J.; Harrison, T. M.; Mojzsis, S. J.

    2004-01-01

    The geological record is the only direct source of information regarding physical/chemical processes that may have ultimately been responsible for the origin of life. Known terrestrial rocks have ages that span from present day to approx. 4.0 Ga. This leaves a time gap of more than 500 Myr between lunar formation, and preservation of the oldest terrestrial crust. What were planetary conditions like wherein the prebiotic chemistry leading to life took place? The recent discovery of up to 4.37 Ga detrital zircons from Western Australia represents the only tangible record of the time period termed the Hadean Eon (4.5-4.0 Ga). Knowledge of the paragenesis of the oldest zircons potentially contributes information regarding the origin of the atmosphere, hydrosphere, continental lithosphere and the potential for life on the Hadean Earth.

  10. Petrography and U-Pb detrital zircon geochronology of metasedimentary strata dredged from the Chukchi Borderland, Amerasia Basin, Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Brumley, K.; Miller, E. L.; Mayer, L. A.; Andronikov, A.; Wooden, J. L.; Dumitru, T. A.; Elliott, B.; Gehrels, G. E.; Mukasa, S. B.

    2010-12-01

    In 2008-2009, twelve dredges were taken aboard the USCGC Healy from outcrops along the Alpha Ridge, Northern Chukchi Borderland, Northwind Ridge and the Chukchi Plateau in the Arctic Ocean as part of the U.S. Extended Continental Shelf Project. To ensure sampling of outcrop, steep bathymetric slopes (>40°) with little mud cover were identified with multibeam sonar and targeted for dredging. The first dredge from Alpha Ridge yielded volcaniclastic sedimentary rocks deposited from a phreatomagmatic eruption in shallow water (<200m). This is inconsistent with tectonic reconstructions suggesting that the Alpha Ridge was created as an oceanic plateau on deep oceanic crust of the Canada Basin. Another dredge, taken from the northern tip of Northwind Ridge, yielded metasedimentary rocks deformed under greenschist facies conditions (chlorite+white mica). These rocks are intruded and/or overlain by mid-Cretaceous alkalic basalts, also taken in this dredge, and dated by 40Ar/39Ar (plagioclase separate) to be 112±1 Ma. The metasedimentary rocks, from this single dredge, range in grain size from mud to coarse sandstone and grit which all contain grains and sub-angular clasts of volcanic, plutonic, metamorphic and fine grained sedimentary rocks as well as monocrystalline quartz, potassium feldspar, and plagioclase. All of these samples display the same bedding to foliation angle and lithology, which further indicates that they were dredged from in situ outcrop and are not random samples of ice rafted debris. Based on grain size variations and graded beds, they are interpreted as Silurian gravity flow deposits fed by proximal syn-orogenic and/or magmatic arc sources. Detrital zircons were separated from four sandstone samples of the Northwind Ridge dredge, and their U-Pb single grain ages determined by LA-MC-ICPMS and SHRIMP, (N= 393). Their detrital zircon populations are dominated by euhedral first-cycle zircon ca. 430 and 980 Ma with lesser older recycled zircons between

  11. Juvenile crust formation in the Zimbabwe Craton deduced from the O-Hf isotopic record of 3.8-3.1 Ga detrital zircons

    NASA Astrophysics Data System (ADS)

    Bolhar, Robert; Hofmann, Axel; Kemp, Anthony I. S.; Whitehouse, Martin J.; Wind, Sandra; Kamber, Balz S.

    2017-10-01

    Hafnium and oxygen isotopic compositions measured in-situ on U-Pb dated zircon from Archaean sedimentary successions belonging to the 2.9-2.8 Ga Belingwean/Bulawayan groups and previously undated Sebakwian Group are used to characterize the crustal evolution of the Zimbabwe Craton prior to 3.0 Ga. Microstructural and compositional criteria were used to minimize effects arising from Pb loss due to metamorphic overprinting and interaction with low-temperature fluids. 207Pb/206Pb age spectra (concordance >90%) reveal prominent peaks at 3.8, 3.6, 3.5, and 3.35 Ga, corresponding to documented geological events, both globally and within the Zimbabwe Craton. Zircon δ18O values from +4 to +10‰ point to both derivation from magmas in equilibrium with mantle oxygen and the incorporation of material that had previously interacted with water in near-surface environments. In εHf-time space, 3.8-3.6 Ga grains define an array consistent with reworking of a mafic reservoir (176Lu/177Hf ∼0.015) that separated from chondritic mantle at ∼3.9 Ga. Crustal domains formed after 3.6 Ga depict a more complex evolution, involving contribution from chondritic mantle sources and, to a lesser extent, reworking of pre-existing crust. Protracted remelting was not accompanied by significant mantle depletion prior to 3.35 Ga. This implies that early crust production in the Zimbabwe Craton did not cause complementary enriched and depleted reservoirs that were tapped by later magmas, possibly because the volume of crust extracted and stabilised was too small to influence (asthenospheric) mantle isotopic evolution. Growth of continental crust through pulsed emplacement of juvenile (chondritic mantle-derived) melts, into and onto the existing cratonic nucleus, however, involved formation of complementary depleted subcontinental lithospheric mantle since the early Archaean, indicative of strongly coupled evolutionary histories of both reservoirs, with limited evidence for recycling and lateral

  12. Zircon U-Pb Geochronology, Hf Isotopic Composition and Geological Implications of the Neoproterozoic Huashan Group in the Jingshan Area, Northern Yangtze Block, China

    NASA Astrophysics Data System (ADS)

    Yang, Z.; Yang, K.

    2015-12-01

    In the northern Yangtze Block, a clear angular unconformity between the Mesoproterozoic sequences (e.g. Dagushi Group) and the overlying Neoproterozoic strata (e.g. Huashan Group) marks the the Jinning orogeny. A combined study of Lu-Hf isotopes and U-Pb ages for detrital zircons from Huashan Group can provide information on the crustal evolution of sedimentary provenances and the timing of the Jinning orogeny. Detrital zircons from Huashan Group have two major U-Pb age populations of about 2.0Ga, 2.65Ga, and three subordinate age groups of about 0.82Ga, 2.5Ga, 2.9Ga with minor >3.0Ga ages. The youngest five analyses yield a weighted average age of 816±9Ma, which is consistent with that of interlayered basalt (824±9Ma, Deng et al., 2013) and roughly defines the minimum depositional age of Huashan Group. Detrital zircons of Huashan Group mostly have two stage Hf isotope model ages (TDM2) between 3.0 to 3.3Ga, indicating that the northern Yangtze Block experienced significant continental crustal growth during the Paleo- to Meso-archean. Similar U-Pb ages of detrital zircons have been obtained from Precambrian sedimentary rocks in the northern Yangtze Block from previous studies (Liu et al., 2008; Guo et al., 2014 and references therein). Recently, ca. 2.65Ga A-type granites had been reported from the Kongling and Huji area, which likely record the thermally stable lithosphere (Chen et al., 2013; Zhou et al., 2015). In combination with this study, it documents the widespread 2.6-2.7Ga magmatic rocks in the northern Yangtze Block. Zhao et al. (2013) demonstrated both the ca. 850Ma tonalite and trondhjemite of the Huangling igneous complex were formed in a continental arc setting. This suggests the Miaowan-Huashan oceanic basin proposed by Bader et al. (2013) has not been closed at ca. 850Ma. This evidence, together with the depositional age of the Huashan Group, indicates the Jinning orogeny took place at 850-820 Ma. [1] Bader et al., 2013 Tectonics [2] Deng et al

  13. Cadomian basement and Paleozoic to Triassic siliciclastics of the Taurides (Karacahisar dome, south-central Turkey): Paleogeographic constraints from U-Pb-Hf in zircons

    NASA Astrophysics Data System (ADS)

    Abbo, Avishai; Avigad, Dov; Gerdes, Axel; Güngör, Talip

    2015-06-01

    The Tauride block in Turkey is a peri-Gondwana, Cadomian-type terrane that rifted from the Afro-Arabian margin of Gondwana in the Permo-Triassic and re-accreted to Arabia in the Neogene. In the Karacahisar dome in the southern-central Taurides, Neoproterozoic basement metasediments and intrusive rocks are overlain by Cambro-Ordovician, Carboniferous and Triassic sediments. We studied U-Pb-Hf in zircons from major rock units exposed in Karacahisar in order to constrain the Cadomian crustal evolution of the Taurides, to evaluate the provenance of the Neoproterozoic and overlying sediments, to constrain the paleogeography of the Taurides, and to assess their linkage to Gondwana. The Neoproterozoic metasediments are low-grade metamorphic wacke-type turbidites that evolved in a broad back-arc basin peripheral to Afro-Arabia. Their detrital zircon U-Pb signal comprises a preponderance (40-68%) of Neoproterozoic-aged zircons (peak ages defined at 635 and 830 Ma), indicating that the sedimentary pile was built mainly from the erosion of Pan-African terranes from Afro-Arabia. The εHf values of the younger population (635 Ma) are mostly positive, indicating derivation from a juvenile arc, whereas Cryogenian-Tonian detrital zircons spread vertically (- 25 < εHf < 15), indicating a different provenance where mixing of juvenile magmas with Paleoproterozoic to Neoarchean crust was widespread. An unusually high proportion of pre-Neoproterozoic zircons is found in all Cadomian metasediments, including up to 31% Grenvillian-aged (ca. 1.0 Ga) and up to 35% of ca. 2.5 Ga zircons; about a third of the latter possess positive εHf values. Because only minor exposures of 1.0 and 2.5 Ga crustal vestiges are currently known in North Africa and Arabia, we infer that pre-Neoproterozoic terranes were dispersed within the Cadomian realm itself. The youngest detrital zircons in all Cadomian metasediments concentrate at 0.58 Ga, indicating that the proto-Cadomian back-arc basin was formed

  14. Uniformly mantle-like δ18O in zircons from oceanic plagiogranites and gabbros

    NASA Astrophysics Data System (ADS)

    Grimes, Craig B.; Ushikubo, Takayuki; John, Barbara E.; Valley, John W.

    2011-01-01

    Lower ocean crust is primarily gabbroic, although 1-2% felsic igneous rocks that are referred to collectively as plagiogranites occur locally. Recent experimental evidence suggests that plagiogranite magmas can form by hydrous partial melting of gabbro triggered by seawater-derived fluids, and thus they may indicate early, high-temperature hydrothermal fluid circulation. To explore seawater-rock interaction prior to and during the genesis of plagiogranite and other late-stage magmas, oxygen-isotope ratios preserved in igneous zircon have been measured by ion microprobe. A total of 197 zircons from 43 plagiogranite, evolved gabbro, and hydrothermally altered fault rock samples have been analyzed. Samples originate primarily from drill core acquired during Ocean Drilling Program and Integrated Ocean Drilling Program operations near the Mid-Atlantic and Southwest Indian Ridges. With the exception of rare, distinctively luminescent rims, all zircons from ocean crust record remarkably uniform δ18O with an average value of 5.2 ± 0.5‰ (2SD). The average δ18O(Zrc) would be in magmatic equilibrium with unaltered MORB [δ18O(WR) ~ 5.6-5.7‰], and is consistent with the previously determined value for equilibrium with the mantle. The narrow range of measured δ18O values is predicted for zircon crystallization from variable parent melt compositions and temperatures in a closed system, and provides no indication of any interactions between altered rocks or seawater and the evolved parent melts. If plagiogranite forms by hydrous partial melting, the uniform mantle-like δ18O(Zrc) requires melting and zircon crystallization prior to significant amounts of water-rock interactions that alter the protolith δ18O. Zircons from ocean crust have been proposed as a tectonic analog for >3.9 Ga detrital zircons from the earliest (Hadean) Earth by multiple workers. However, zircons from ocean crust are readily distinguished geochemically from zircons formed in continental crustal

  15. Detrital-zircon fission-track geochronology of the Lower Cenozoic sediments, NW Himalayan foreland basin: Clues for exhumation and denudation of the Himalaya during the India-Asia collision

    NASA Astrophysics Data System (ADS)

    Jain, A.; Lal, N.; Suelmani, B.; Awasthi, A. K.; Singh, S.; Kumar, R.

    2007-12-01

    Detrital-zircon fission-track geochronology of the synorogenically-deposited Subathu-Dagshai-Kasauli-Lower Siwalik Formations of the Sub-Himalayan Lower Cenozoic foreland basin reflects progressive effects of the Himalayan tectonometamorphic events on the Proterozoic-Paleozoic source rock as a consequence of the India-Asia collision. The oldest transgressive marine Subathu Formation (57.0-41.5 Ma) contains a very dominant 302.4 ± 21.9 Ma old detrital zircon FT suite with a few determinable 520.0 Ma grains. This old suite was derived by mild erosion of the Zircon Partially Annealed Zone (ZPAZ) of 240-180 oC, which affected the Himalayan Proterozoic basement and its Tethyan sedimentary cover as a consequence of first imprint of the collision. In addition, 50.0 Ma old detrital zircons in this formation were derived possibly from the Indus Tsangpo Suture Zone and the Trans-Himalayan Ladakh Batholith. Sudden source rock changes and unroofing are manifested in the overlying fluvial Dagshai (~30-20 Ma) and Kasauli (20-13 Ma) molassic sediments, which are characterised by dominant 30.0 and 25.0 Ma old youngest zircon FT peaks, respectively. A distinct unconformity spanning for about 10 Myr gets established between the Subathu-Dagshai formations on the basis of detrital- zircon FT ages. Molassic sedimentation since ~30 Ma coincides with the depletion of detritus from the suture zone, and the bulk derivation from the main Higher Himalayan source rock, which has undergone sequentially the UHP-HP-amphibolite facies metamorphism (53-40 Ma) in the extreme north and widespread Eo- and Neo-Himalayan tectonothermal events in the middle. Strength of the Pre-Himalayan Peaks (PHP) >50 Ma in these younger sediments gradually decreases with the intensification of the Himalayan thermal events till the end of the Kasauli sedimentation. Widespread Eo- and Neo-Himalayan metamorphic events (40.0-30.0 and 25.0-15.0 Ma) have almost remobilised the provenance and obliterated most of the

  16. Role of zircon in tracing crustal growth and recycling

    NASA Astrophysics Data System (ADS)

    Compston, W.; Williams, I. S.; Armstrong, R. A.; Claoue-Long, J. C.; Kinny, P. D.; Foster, J. J.; Kroener, A.; Pidgeon, R. T.; Myers, J. S.

    Single crystal ion probe ages of zircons is discussed, which allow much better time resolution compared to other geochronological methods, although the technique is not without problems. Rocks from two areas that contain composite zircon populations, including true magmatic zircons as well as a variety of xenocrystic types are described. It is often difficult to distinguish these; xenocrystic zircons, for example, cannot always be identified on the basis of morphology alone. Additional evidence is needed before making age interpretations. Evidence is also presented of zircon growth long after the original time of crystallization, in some cases apparently at temperatures less than 300 C. The spectacular discovery of 4.1 to 4.2 Ga detrital zircons in metaquartzites from the Mount Narryer area of Western Australia is described. Similar zircons with ages as old as 4276 Ma have been found in the nearby Jack Hills area. The source areas or parent lithologies of these zircons have not yet been determined, but the author expects that they may be unrecognized or buried antecedents of the K rich Narryer gneisses. U or Th concentrations of zircon cannot be used to discriminate between felsic and mafic source rocks.

  17. Role of zircon in tracing crustal growth and recycling

    NASA Technical Reports Server (NTRS)

    Compston, W.; Williams, I. S.; Armstrong, R. A.; Claoue-Long, J. C.; Kinny, P. D.; Foster, J. J.; Kroener, A.; Pidgeon, R. T.; Myers, J. S.

    1988-01-01

    Single crystal ion probe ages of zircons is discussed, which allow much better time resolution compared to other geochronological methods, although the technique is not without problems. Rocks from two areas that contain composite zircon populations, including true magmatic zircons as well as a variety of xenocrystic types are described. It is often difficult to distinguish these; xenocrystic zircons, for example, cannot always be identified on the basis of morphology alone. Additional evidence is needed before making age interpretations. Evidence is also presented of zircon growth long after the original time of crystallization, in some cases apparently at temperatures less than 300 C. The spectacular discovery of 4.1 to 4.2 Ga detrital zircons in metaquartzites from the Mount Narryer area of Western Australia is described. Similar zircons with ages as old as 4276 Ma have been found in the nearby Jack Hills area. The source areas or parent lithologies of these zircons have not yet been determined, but the author expects that they may be unrecognized or buried antecedents of the K rich Narryer gneisses. U or Th concentrations of zircon cannot be used to discriminate between felsic and mafic source rocks.

  18. New U-Pb zircon geochronology of the Choma-Kalomo Block (Zambia) and the Dete-Kamativi Inlier (Zimbabwe), with implications for the extent of the Zimbabwe Craton.

    NASA Astrophysics Data System (ADS)

    Glynn, Sarah; Wiedenbeck, Michael; Master, Sharad; Frei, Dirk

    2015-04-01

    The Choma-Kalomo Block is a north-east trending, Mesoproterozoic terrane located in southern Zambia. It is composed of as yet undated gneissic basement with a high-grade metamorphosed supracrustal metasedimentary sequence, which is intruded by hornblende granites and gneisses of the Choma-Kalomo Batholith, that is dated between ca. 1.37 and 1.18 Ga. Our new zircon U-Pb age data on metasedimentary rocks of the Choma-Kalomo Block identifies samples of different ages, with slightly different provenances. The oldest metasedimentary rock is a muscovite-biotite schist, which has only Palaeoproterozoic detrital zircons, the two age clusters around 2.03-2.02 Ga and 1.8-1.9 Ga, correspond to the ages of granitic intrusion, and metamorphism, in the Magondi Mobile Belt on the western side of the Archaean Zimbabwe Craton. The second sample is a garnetiferous paragneiss, which contains both Palaeoproterozoic (2.04 Ga), and Mesoproterozoic zircons, ca. 1.36 Ga, derived from the granites of the Choma-Kalomo Batholith. The third sample is a biotite-muscovite schist, in which the detrital zircon ages fall into four separate clusters: ca. 3.39 Ga, ca. 2.7-2.6 Ga, ca. 2.1-1.7 Ga (with a peak at ca. 1.18 Ga), and 1.55 - 1.28 Ga. The Archaean zircons in this sample are derived from the Zimbabwe Craton, while the Palaeoproterozoic samples come from the Magondi belt, and the youngest zircons come from both phases of the Choma-Kalomo Batholith. A possible connection between the Choma-Kalomo Block and the Dete-Kamativi Inlier - some 150 km to the south-east in western Zimbabwe - has been proposed on the basis of similarities in the nature of their Sn-Ta-muscovite pegmatite mineralisation. The Dete-Kamativi Inlier, which is part of the Magondi Mobile Belt, is a window into Palaeoproterozoic north-east trending belts of deformed and metamorphosed supracrustal rocks. By dating localities which we suspect form the basement to the surrounding younger sediments, along with selected pegmatites

  19. Detrital zircon U-Pb geochronological and sedimentological study of the Simao Basin, Yunnan: Implications for the Early Cenozoic evolution of the Red River

    NASA Astrophysics Data System (ADS)

    Chen, Yi; Yan, Maodu; Fang, Xiaomin; Song, Chunhui; Zhang, Weilin; Zan, Jinbo; Zhang, Zhiguo; Li, Bingshuai; Yang, Yongpeng; Zhang, Dawen

    2017-10-01

    The paleo-Red River is suggested to have been a continental-scale drainage system connecting the Tibetan Plateau to the South China Sea. However, the evolution of the paleo-Red River is still under debate. This study presents new results from sedimentological analyses and detrital zircon U-Pb geochronologic data from fluvial sedimentary rocks of Paleocene to Oligocene age of the Simao Basin to constrain the nature of the paleo-drainage system of the Red River. The detrital zircon U-Pb results reveal multiple age groups at 190-240 Ma, 260-280 Ma, 450-540 Ma, 1700-1900 Ma and 2400-2600 Ma for the Paleocene to late Eocene Denghei Formation (Fm.), but only one conspicuous peak at 220-240 Ma for the late Eocene-Oligocene Mengla Fm. Provenance analyses illustrate that the former likely had source areas that included the Hoh-Xil, Songpan-Ganzi, northern Qiangtang, Yidun and western Yangtze Terranes, which are consistent with the catchments of the Upper and Lower Jinshajiang Segments, whereas the latter mainly transported material from a limited number of sources, such as the Lincang granitic intrusions west of the Simao Basin. Integrated with available detrital zircon U-Pb geochronologic and paleogeographic data, our study suggests the existence of a paleo-Red River during the Paleocene to late Eocene that was truncated and lost its northern sources after approximately 35 Ma, due to left-lateral strike-slip faulting of the Ailao Shan-Red River and clockwise rotation of the Lanping-Simao Terrane.

  20. Provenance of the lower Miocene of the Gulf of Mexico from detrital zircon double dating

    NASA Astrophysics Data System (ADS)

    xu, J.

    2013-12-01

    The lower Miocene interval of the Gulf of Mexico (GOM) has recently gained increasing attention from oil and gas industry due to its hydrocarbon potential below the salt canopy. However, it has been less well studied than both the underlying Oligocene and overlying middle Miocene strata. The lower Miocene worldwide is a transitional period of tectonic, climatic, and oceanographic change. In particular, it is a period of major tectonic reorganization in the western interior of North America (Rocky Mountains), involving a shift from the Oligocene thermal phase, with abundant volcanic activity recorded in the thick Frio/Vicksburg succession of the GOM, to the Miocene Basin-Range extensional phase. Climatic conditions also changed from a relatively arid Oligocene to wetter Miocene, resulting in increased sediment yields from exhumed tectonic structures. Previous provenance studies used proportions of quartz, feldspar and lithic fragments and consideration of likely river courses through known paleogeomorphological elements. Only limited detrital zircon (DZ) U-Pb studies on Paleocene strata have been undertaken and there has been no previous U-Pb and (U-Th)/He double dating in the GOM. In this study we apply the latest analytical approaches, such as DZ U-Pb dating to gain robust source terranes ages and more fully elucidate the complex sediment provenance and dispersal history of GOM. We also employ DZ (U-Th)/He (ZHe) dating, combined with DZ U-Pb, to not only define sedimentary provenance but also the exhumation histories of detrital source regions. Samples of lower Miocene outcrop exposures in Texas and Louisiana have been collected to discriminate the varied tectonic and drainage system changes across the basin in lateral. In addition, samples from the Eocene, Oligocene and middle Miocene have been obtained to reveal vertical shift of source terranes contributions. Our initial age data show detrital zircons of lower Miocene sediments come from a wide range of source

  1. A non-zircon Hf isotope record in Archean black shales from the Pilbara craton confirms changing crustal dynamics ca. 3 Ga ago.

    PubMed

    Nebel-Jacobsen, Yona; Nebel, Oliver; Wille, Martin; Cawood, Peter A

    2018-01-17

    Plate tectonics and associated subduction are unique to the Earth. Studies of Archean rocks show significant changes in composition and structural style around 3.0 to 2.5 Ga that are related to changing tectonic regime, possibly associated with the onset of subduction. Whole rock Hf isotope systematics of black shales from the Australian Pilbara craton, selected to exclude detrital zircon components, are employed to evaluate the evolution of the Archean crust. This approach avoids limitations of Hf-in-zircon analyses, which only provide input from rocks of sufficient Zr-concentration, and therefore usually represent domains that already underwent a degree of differentiation. In this study, we demonstrate the applicability of this method through analysis of shales that range in age from 3.5 to 2.8 Ga, and serve as representatives of their crustal sources through time. Their Hf isotopic compositions show a trend from strongly positive εHf initial values for the oldest samples, to strongly negative values for the younger samples, indicating a shift from juvenile to differentiated material. These results confirm a significant change in the character of the source region of the black shales by 3 Ga, consistent with models invoking a change in global dynamics from crustal growth towards crustal reworking around this time.

  2. Detrital zircon provenance from three turbidite depocenters of the Middle-Upper Triassic Songpan-Ganzi complex, central China: Record of collisional tectonics, erosional exhumation, and sediment production

    USGS Publications Warehouse

    Weislogel, A.L.; Graham, S.A.; Chang, E.Z.; Wooden, J.L.; Gehrels, G.E.

    2010-01-01

    To test the idea that the voluminous upper Middle to Upper Triassic turbidite strata in the Songpan-Ganzi complex of central China archive a detrital record of Dabie ultrahigh-pressure (UHP) terrane unroofing, we report 2080 single detrital U-Pb zircon ages by sensitive high-resolution ion microprobe-reverse geometry (SHRIMP-RG) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis from 29 eastern Songpan-Ganzi complex sandstone samples. Low (<0.07) Th/U zircons, consistent with crystallization under UHP conditions, are rare in eastern Songpan-Ganzi complex zircon, and U-Pb ages of low Th/U zircons are incompatible with a Dabie terrane source. An unweighted pair group method with arithmetic mean nearest-neighbor analysis of Kolmogorov-Smirnov two-sample test results reveals that the eastern Songpan-Ganzi complex is not a single contiguous turbidite system but is instead composed of three subsidiary depocenters, each associated with distinct sediment sources. The northeastern depocenter contains zircon ages characterized by Paleozoic and bimodally distributed Precambrian zircon populations, which, together with south-to southeast-directed paleocurrent data, indicate derivation from the retro-side of the Qinling-Dabie (Q-D) collisional orogen wedge. In the central depocenter, the dominantly Paleozoic detrital zircon signature and south-to southwest-oriented paleocurrent indicators reflect a profusion of Paleozoic zircon grains. These data are interpreted to reflect an influx of material derived from erosion of Paleozoic supra-UHP rocks of the Dabie terrane in the eastern Qinling-Dabie orogen, which we speculate may have been enhanced by development of a monsoonal climate. This suggests that erosional unroofing played a significant role in the initial phase of UHP exhumation and likely influenced the petrotectonic and structural evolution of the Qinling-Dabie orogen, as evidenced by compressed Triassic isotherms/grads reported in the

  3. Tasmania in Nuna: Witness to a ~1.4 Ga East Antarctica-Laurentia Connection

    NASA Astrophysics Data System (ADS)

    Halpin, J. A.; Mulder, J. A.; Daczko, N. R.

    2015-12-01

    Most recent reconstructions of the supercontinent Nuna juxtapose the North Australian craton, Mawson continent (South Australia-East Antarctica), and Laurentia between 1.6 Ga and 1.3 Ga, but differ in their relative positioning. Tasmania (SE Australia) has not been considered in previous Nuna reconstructions. Prior to late Neoproterozoic rifting, this crustal fragment was likely part of the eastern margin of East Antarctica. The significance of Tasmania's position within Nuna has recently been highlighted with the discovery that the majority of a >10-km-thick marine shelfal package exposed in northwest Tasmania (Rocky Cape Group) was deposited between 1.45 and 1.30 Ga. The detrital zircon signatures of these strata are distinct from other Mesoproterozoic basins in Australia, and instead closely resemble time-equivalent upper parts of the Belt-Purcell Basin of Laurentia, suggesting correlations within Nuna. We investigate the provenance of the Rocky Cape Group quartzites by comparing new detrital zircon U-Pb-Hf isotopic data to an extensive compilation of zircon data from Australia, East Antarctica, and Laurentia. Our analysis demonstrates that the Rocky Cape Group is unlikely to have been sourced from any geological terrane exposed in present-day Australia. Instead, zircon isotopic signatures from basement terranes in Laurentia and East Antarctica show striking similarities to the Rocky Cape Group detrital signature. Paleocurrent data indicate a northwest-southeast-trending paleoshoreline
and suggest that the majority of sediment was sourced from Paleoproterozoic crust in SW Laurentia, which was to the southeast (present-day coordinates) of Tasmania. These new data support a SWEAT-like (southwest United States-East Antarctica) configuration for Nuna. We suggest that rifting propagated southward from ca. 1.4 Ga, leaving a thinned continental connection between East Antarctica and southwest Laurentia onto which the lower-middle RCG was deposited prior to 1.3 Ga.

  4. Provenance analysis on detrital zircons from the back-arc Arivechi basin: Implications for the Upper Cretaceous tectonic evolution of northern Sonora and southern Arizona

    NASA Astrophysics Data System (ADS)

    Rodríguez-Castañeda, José Luis; Ortega-Rivera, Amabel; Roldán-Quintana, Jaime; Espinoza-Maldonado, Inocente Guadalupe

    2018-07-01

    In the Arivechi region of eastern Sonora, northwestern Mexico, mountainous exposures of Upper Cretaceous rocks that contain monoliths within coarse sedimentary debris are enigmatic, in a province of largely Late Cretaceous continental-margin arc rocks. The rocks sequence in the study area are grouped in two Upper Cretaceous units: the lower Cañada de Tarachi and the younger El Potrero Grande. Detrital zircons collected from three samples of the Cañada de Tarachi and El Potrero Grande units have been analyzed for U-Pb ages to constrain their provenance. These ages constrain the age of the exposed rocks and provide new insights into the geological evolution of eastern Sonora Cretaceous rocks. The detrital zircon age populations determined for the Cañada de Tarachi and El Potrero Grande units contain distinctive Precambrian, Paleozoic, and Mesozoic zircon ages that provide probable source areas which are discussed in detail constraining the tectonic evolution of the region. Comparison of these knew ages with published data suggests that the source terranes, that supplied zircons to the Arivechi basin, correlate with Proterozoic, Paleozoic and Mesozoic domains in southern California and Baja California, northern Sonora, southern Arizona and eastern Chihuahua. The provenance variation is vital to constrain the source of the Cretaceous rocks in eastern Sonora and support a better understanding of the Permo-Triassic Cordilleran Magmatic Arc in the southwestern North America.

  5. The Pliocene Lost River found to west: Detrital zircon evidence of drainage disruption along a subsiding hotspot track

    USGS Publications Warehouse

    Hodges, M.K.V.; Link, P.K.; Fanning, C.M.

    2009-01-01

    SHRIMP analysis of U/Pb ages of detrital zircons in twelve late Miocene to Pleistocene sand samples from six drill cores on the Snake River Plain (SRP), Idaho, suggests that an ancestral Lost River system was drained westward along the northern side of the SRP. Neoproterozoic (650 to 740??Ma, Cryogenian) detrital zircon grains from the Wildhorse Creek drainage of the Pioneer Mountains core complex, with a source in 695??Ma orthogneiss, and which are characteristic of the Big Lost River system, are found in Pliocene sand from cores drilled in the central SRP (near Wendell) and western SRP (at Mountain Home). In addition to these Neoproterozoic grains, fluvial sands sourced from the northern margin of the SRP contain detrital zircons with the following ages: 42 to 52??Ma from the Challis magmatic belt, 80 to 100??Ma from the Atlanta lobe of the Idaho batholith, and mixed Paleozoic and Proterozoic ages (1400 to 2000??Ma). In contrast, sands in the Mountain Home Air Base well (MHAB) that contain 155-Ma Jurassic detrital grains with a source in northern Nevada are interpreted to represent an integrated Snake River, with provenance on the southern, eastern and northern sides of the SRP. We propose that late Pliocene and early Pleistocene construction of basaltic volcanoes and rhyolitic domes of the Axial Volcanic Zone of the eastern SRP and the northwest-trending Arco Volcanic Rift Zone (including the Craters of the Moon volcanic center), disrupted the paleo-Lost River drainage, confining it to the Big Lost Trough, a volcanically dammed basin of internal drainage on the Idaho National Laboratory (INL). After the Axial Volcanic Zone and Arco Volcanic Rift Zone were constructed to form a volcanic eruptive and intrusive highland to the southwest, sediment from the Big Lost River was trapped in the Big Lost Trough instead of being delivered by surface streams to the western SRP. Today, water from drainages north of the SRP enters the Snake River Plain regional aquifer

  6. Birth and demise of the Rheic Ocean magmatic arc(s): Combined U-Pb and Hf isotope analyses in detrital zircon from SW Iberia siliciclastic strata

    NASA Astrophysics Data System (ADS)

    Pereira, M. F.; Gutíerrez-Alonso, G.; Murphy, J. B.; Drost, K.; Gama, C.; Silva, J. B.

    2017-05-01

    Paleozoic continental reconstructions indicate that subduction of Rheic oceanic lithosphere led to collision between Laurussia and Gondwana which was a major event in the formation of the Ouachita-Appalachian-Variscan orogenic belt and the amalgamation of Pangea. However, arc systems which record Rheic Ocean subduction are poorly preserved. The preservation of Devonian detrital zircon in Late Devonian-Early Carboniferous siliciclastic rocks of SW Iberia, rather than arc-related igneous rocks indicates that direct evidence of the arc system may have been largely destroyed by erosion. Here we report in-situ detrital zircon U-Pb isotopic analyses of Late Devonian-Early Carboniferous siliciclastic rocks from the Pulo do Lobo Zone, which is a reworked Late Paleozoic suture zone located between Laurussia and Gondwana. Detrital zircon age spectra from the Pulo do Lobo Zone Frasnian formations show striking similarities, revealing a wide range of ages dominated by Neoproterozoic and Paleoproterozoic grains sourced from rocks typical of peri-Gondwanan terranes, such as Avalonia, the Meguma terrane and the Ossa-Morena Zone. Pulo do Lobo rocks also include representative populations of Mesoproterozoic and Early Silurian zircons that are typical of Avalonia and the Meguma terrane which are absent in the Ossa-Morena Zone. The Famennian-Tournaisian formations from the Pulo do Lobo Zone, however, contain more abundant Middle-Late Devonian zircon indicating the contribution from a previously unrecognized source probably related to the Rheic Ocean magmatic arc(s). The Middle-Late Devonian to Early Carboniferous zircon ages from the siliciclastic rocks of SW Iberia (South Portuguese, Pulo do Lobo and Ossa-Morena zones) have a wide range in εHfT values (- 8.2 to + 8.3) indicating the likely crystallization from magmas formed in a convergent setting. The missing Rheic Ocean arc was probably built on a Meguma/Avalonia type basement. We propose for the Pulo do Lobo Zone that the

  7. Detrital zircons from the Tananao metamorphic complex of Taiwan: Implications for sediment provenance and Mesozoic tectonics

    NASA Astrophysics Data System (ADS)

    Yui, T. F.; Maki, K.; Lan, C. Y.; Hirata, T.; Chu, H. T.; Kon, Y.; Yokoyama, T. D.; Jahn, B. M.; Ernst, W. G.

    2012-05-01

    Taiwan formed during the Plio-Pleistocene collision of Eurasia with the outboard Luzon arc. Its pre-Tertiary basement, the Tananao metamorphic complex, consists of the western Tailuko belt and the eastern Yuli belt. These circum-Pacific belts have been correlated with the high-temperature/low-pressure (HT/LP) Ryoke belt and the high-pressure/low-temperature (HP/LT) Sanbagawa belt of Japan, respectively. To test this correlation and to reveal the architecture and plate-tectonic history of the Tananao metamorphic basement, detrital zircons were separated from 7 metasedimentary rock samples for U-Pb dating by LA-ICPMS techniques. Results of the present study, coupled with previous data, show that (1) the Tailuko belt consists of a Late Jurassic to earliest Cretaceous accretionary complex sutured against a Permian-Early Jurassic marble ± metabasaltic terrane, invaded in the north by scattered Late Cretaceous granitic plutons; the latter as well as minor Upper Cretaceous cover strata probably formed in a circum-Pacific forearc; (2) the Yuli belt is a mid- to Late Cretaceous accretionary complex containing HP thrust sheets that were emplaced attending the Late Cenozoic Eurasian plate-Luzon arc collision; (3) these two Late Mesozoic belts are not coeval, and in part were overprinted by low-grade metamorphism during the Plio-Pleistocene collision; (4) accreted clastic sediments of the Tailuko belt contain mainly Phanerozoic detrital zircons, indicating that terrigenous sediments were mainly sourced from western Cathaysia, whereas in contrast, clastic rocks of the Yuli accretionary complex contain a significant amount of Paleoproterozoic and distinctive Neoproterozoic zircons, probably derived from the North China craton and the Yangtze block ± eastern Cathaysia, as a result of continent uplift/exhumation after the Permo-Triassic South China-North China collision; and (5) the Late Jurassic-Late Cretaceous formation of the Tananao basement complex precludes the possibility

  8. U-Pb Detrital Zircon Ages from Sarawak: Changes in Provenance Reflecting the Tectonic Evolution of Southeast Asia

    NASA Astrophysics Data System (ADS)

    Breitfeld, H. T.; Galin, T.; Hall, R.

    2014-12-01

    Sarawak is located on the northern edge of Sundaland in NW Borneo. Five sedimentary basins are distinguished with ages from Triassic to Cenozoic. New light mineral, heavy mineral and U-Pb detrital zircon ages show differences in provenance reflecting the tectonic evolution of the region. The oldest clastic sediments are Triassic of the Sadong-Kuching Basin and were sourced by a Carnian to Norian volcanic arc and erosion of Cathaysian rocks containing zircons of Paleoproterozoic age. Sandstones of the Upper Jurassic to Cretaceous Bau-Pedawan Basin have distinctive zircon populations indicating a major change of tectonic setting, including initiation of subduction below present-day West Sarawak in the Late Jurassic. A wide range of inherited zircon ages indicates various Cathaysian fragments as major source areas and the arrival of the SW Borneo Block following subduction beneath the Schwaner Mountains in the early Late Cretaceous. After collision of the SW Borneo Block and the microcontinental fragments with Sundaland in the early Late Cretaceous, deep marine sedimentation (Pedawan Formation) ceased, and there was uplift forming the regional Pedawan-Kayan unconformity. Two episodes of extension were responsible for basin development on land from the latest Cretaceous onwards, probably in a strike-slip setting. The first episode formed the Kayan Basin in the Latest Cretaceous (Maastrichtian) to Early Paleocene, and the second formed the Ketungau Basin and the Penrissen Sandstone in the Middle to Late Eocene. Zircons indicate nearby volcanic activity throughout the Early Cenozoic in NW Borneo. Inherited zircon ages indicate an alternation between Borneo and Tin Belt source rocks. A large deep marine basin, the Rajang Basin, formed north of the Lupar Line fault. Zircons from sediments of the Rajang Basin indicate they are of similar age and provenance as the contemporaneous terrestrial sediments to the south suggesting a narrow steep continental Sundaland margin at the

  9. Exhumation of the Ladakh batholith revealed through the combined analysis of bedrock and detrital zircon (U-Th)/He data

    NASA Astrophysics Data System (ADS)

    Tripathy-Lang, A.; Fox, M.; Bohon, W.; Van Soest, M. C.; Hodges, K. V.; Dortch, J.

    2013-12-01

    Recent studies of the Ladakh batholith, in the northwestern Indian Himalaya, have yielded various hypotheses for its exhumation history and relationship with the evolution of the southwestern margin of the Tibetan Plateau, which is today bounded by the Karakoram fault. Different hypotheses are supported by various datasets with differing spatial and temporal resolution. First, low-temperature thermochronologic and thermobarometric data provide constraints on long term exhumation (10^6 - 10^7 yr) and suggest that the Ladakh batholith experienced multiple tilting events since ~40 Ma (Kirstein, Tectonophysics, 2011). Second, cosmogenic nuclide concentrations (CNCs), which provide evidence for erosion rates averaged over millennial timescales (10^2-10^4 yr), suggest that erosion rates increase toward the Karakoram fault (Dortch et al., Geomorphology, 2011). A third dataset comprises detrital zircon (U-Th)/He data obtained from the mouth of the Basgo catchment, on the southern flank of the Ladakh batholith (Tripathy-Lang et al., JGR-ES, 2013). This exceptionally large detrital dataset provides information about both the bedrock age distribution and recent erosion rates that sample different parts of the catchment. Interpreting this dataset requires an understanding of the erosion history at multiple timescales. To these already existing datasets, we add new bedrock zircon (U-Th)/He data from an age-elevation transect collected from the base to range crest of the Basgo catchment, which we use to verify models of bedrock age distribution. Through the combined analysis of the datasets, the resolution of both the long term exhumation rate and the spatial distribution of modern erosion rates can be greatly improved, thus advancing our understanding of this part of the Tibetan margin. With this aim, we use thermo-kinematic models to predict bedrock ages that we compare to our new bedrock data. We test different modern erosion rate distributions to generate synthetic detrital

  10. A chronostratigraphic assessment of the Moenave Formation, USA using C-isotope chemostratigraphy and detrital zircon geochronology: Implications for the terrestrial end Triassic extinction

    NASA Astrophysics Data System (ADS)

    Suarez, Celina A.; Knobbe, Todd K.; Crowley, James L.; Kirkland, James I.; Milner, Andrew R. C.

    2017-10-01

    The Late Triassic is a period of abrupt climate change associated with a disruption to the global carbon cycle usually ascribed to the emplacement of the Central Atlantic Magmatic Province (CAMP). Geochronologic, paleontologic, and geochemical studies have shown that the CAMP was likely the major factor for the end-Triassic extinction (ETE), however, difficulties correlating and dating terrestrial strata has left the nature of the terrestrial extinction in question. The lacustrine Whitmore Point Member (WPM) of the Moenave Formation is ideal for investigating these details because it is reported to be Late Triassic to Early Jurassic. However, currently there are conflicting age constraints between biostratigraphy and magnetostratigraphy. In this study we attempt to elucidate the ETE by incorporating C-isotope chemostratigraphy and detrital zircon geochronology. Detrital zircon geochronology suggests the upper part of the Dinosaur Canyon Member (DCM) is younger (201.33 ± 0.07/0.12/0.25 Ma) than the ETE (201.564 Ma) suggesting the ETE is in the middle to lower DCM, in agreement with track biostratigraphy (first occurrence of Eubrontes, Anomoepus, and Batrachopus). Meanwhile a distinct negative carbon isotope (NCIE) excursion (-5.5‰) occurs at the base of the WPM at Potter Canyon, AZ with a more subtle NCIE at the base of the WPM at Black Canyon, UT (-2.0‰) that may correlate to the initial NCIE at the ETE. However, the WPM NCIE is correlated to the preservation of organic C (relative %C) suggesting it may be either related to local lake productivity and biases in organic matter preservation or may be a negative CIE in the Jurassic Hettangian stage. With the addition of the detrital zircon data, we suggest the M2r reversal at the base of the WPM is a reversal in the Hettangian (the H24r, H25r, or H26r) and the ETE is within the DCM. Additional C-isotope analysis of the DCM is necessary to determine if the initial NCIE that is the hallmark of the ETE occurs in

  11. Correlated microanalysis of zircon: Trace element, δ 18O, and U-Th-Pb isotopic constraints on the igneous origin of complex >3900 Ma detrital grains

    NASA Astrophysics Data System (ADS)

    Cavosie, Aaron J.; Valley, John W.; Wilde, Simon A.; E. I. M. F.

    2006-11-01

    The origins of >3900 Ma detrital zircons from Western Australia are controversial, in part due to their complexity and long geologic histories. Conflicting interpretations for the genesis of these zircons propose magmatic, hydrothermal, or metamorphic origins. To test the hypothesis that these zircons preserve magmatic compositions, trace elements [rare earth elements (REE), Y, P, Th, U] were analyzed by ion microprobe from a suite of >3900 Ma zircons from Jack Hills, Western Australia, and include some of the oldest detrital zircons known (4400-4300 Ma). The same ˜20 μm domains previously characterized for U/Pb age, oxygen isotope composition (δ 18O), and cathodoluminescence (CL) zoning were specifically targeted for analysis. The zircons are classified into two types based on the light-REE (LREE) composition of the domain analyzed. Zircons with Type 1 domains form the largest group (37 of 42), consisting of grains that preserve evolved REE compositions typical of igneous zircon from crustal rocks. Grains with Type 1 domains display a wide range of CL zoning patterns, yield nearly concordant U/Pb ages from 4400 to 3900 Ma, and preserve a narrow range of δ 18O values from 4.7‰ to 7.3‰ that overlap or are slightly elevated relative to mantle oxygen isotope composition. Type 1 domains are interpreted to preserve magmatic compositions. Type 2 domains occur in six zircons that contain spots with enriched light-REE (LREE) compositions, here defined as having chondrite normalized values of La N > 1 and Pr N > 10. A subset of analyses in Type 2 domains appear to result from incorporation of sub-surface mineral inclusions in the analysis volume, as evidenced by positively correlated secondary ion beam intensities for LREE, P, and Y, which are anti-correlated to Si, although not all Type 2 analyses show these features. The LREE enrichment also occurs in areas with discordant U/Pb ages and/or high Th/U ratios, and is apparently associated with past or present

  12. SHRIMP U-Pb detrital zircon dating to check subdivisions in metamorphic complexes: a case of study in the Nevado-Filábride complex (Betic Cordillera, Spain)

    NASA Astrophysics Data System (ADS)

    Santamaría-López, Ángel; Sanz de Galdeano, Carlos

    2018-04-01

    U-Pb dating on inherited detrital zircons has been applied to obtain the probable maximum age of deposition of the detrital protolith of the Nevado-Filábride complex (Betic Cordillera, Spain). Five of eight samples correspond to the lower part of the lithologic sequence of this complex, where radiometric dating of metasediments has not been presented till the present. The youngest age populations in the majority of samples are Carboniferous. The estimation of the maximum age of deposition in the lower and upper units is 349.1 ± 1.6 and 334.6 ± 2.9 Ma, respectively. In addition, samples show common age populations at ca. 490-630 and ca. 910-1010 Ma. Observations agree with the Carboniferous to early Permian U-Pb ages previously obtained in orthogneisses levels which are situated in the upper part of the complex. Combination of the minimum age of deposition deducible from the orthogneisses studies and the maximum ages of deposition obtained from the detrital zircons of this work, allow establishing the deposition of de studied lithological succession comprised between ca. 282 and 349 Ma or a shorter period.

  13. Zircon Messengers Reveal the Age and History of Great Basin Crust, Kern Mountains, Nevada

    NASA Astrophysics Data System (ADS)

    Gottlieb, E. S.; Miller, E. L.; Wooden, J. L.

    2011-12-01

    Results of SHRIMP-RG analyses of complexly zoned zircons from muscovite-bearing granitic rocks exposed in the Kerns Mountains of East-Central Nevada constrain the timing, duration, and loci of zircon growth within the interior of the U.S. Cordillera during Late Cretaceous through Eocene time. The Kern Mountains are an exhumed block of greenschist to amphibolite facies metamorphosed miogeoclinal rocks that were pervasively intruded by the Late Cretaceous Tungstonia granite pluton and the Eocene Skinner Canyon and Uvada plutons (Best et al., 1974). Euhedral zircons separated from a coarse-grained (2-3 cm) muscovite-bearing phase of the Tungstonia pluton exhibit complex cathodeluminescence (CL) zonation. Sub-angular to sub-rounded cores with highly variable CL are overgrown by oscillatory-zoned zircon which in turn is rimmed by dark CL zircon (U>5000 ppm). A weighted mean Pb/U age of 70.2±0.9 Ma (n=20, MSWD=2.5) obtained from the oscillatory-zoned zircon coincides with the end of Cretaceous peak metamorphism at shallow crustal levels. Pb/U ages from core zones (n=18) predominantly are 0.9-1.4 Ga (n=11; 7 of which <15% discordant) or 2.4-2.7 Ga (n=5; 1 of which <15% discordant), consistent with ages of detrital zircons within the Late Proterozoic McCoy Creek Group exposed in adjacent ranges. A previously undated muscovite-bearing dike in Skinner Canyon yielded a texturally complex population of subhedral zircon grains. CL imaging of these grains reveals fragmental, ghost-like cores surrounded by irregularly shaped overgrowth zones with diffuse boundaries which are rimmed by oscillatory-zoned zircon. Both oscillatory zoned and gradational rim areas (n=32) yielded Late Cretaceous to Eocene ages. Twelve spots define the age of intrusion at 41.7±0.3 Ma (MSWD=1.8), consistent with the local onset of Eocene magmatism. An older period of zircon growth from ~75-45 Ma, coincident with the proposed duration of the Laramide shallow slab, is defined by zircon with flat to

  14. Applications of primary and secondary inclusion assemblages for zircon petrogenesis and alteration

    NASA Astrophysics Data System (ADS)

    Bell, E. A.

    2017-12-01

    Igneous zircon often contains abundant mineral inclusions which represent a mixture of primary phases captured during crystallization in magma and secondary phases formed either during late-stage deuteric alteration of a solidifying pluton, during later metamorphism, or during detrital transport and diagenesis in groundwater. Microstructural examination of zircon from both magmatic and metamorphic rocks reveals varying abundances of clearly secondary phases filling cracks and potentially secondary phases in contact with cracks or in disturbed regions of the host zircon. We used EDS and WDS X-ray spectroscopy to examine crack-isolated, crack-intersecting, and crack-filling phases in zircon from Phanerozoic magmatic rocks (USA, Victoria), several Grenville (Blue Ridge, VA) orthogneisses, and detrital zircons in metasediments from Jack Hills, Mt. Narryer (Western Australia) and the Nuvvuagittuq supracrustal belt (northern Quebec). Orthogneiss and detrital zircon appear to retain primary inclusion compositions away from contact with cracks or disturbed regions of zircon (as distinguished by U-Pb). Characteristic trace element patterns associated with chemical alteration of zircon match well with the apparently dominant secondary phases in metasedimentary detrital zircons and magmatic zircon subjected to deuteric alteration. Additionally, high spatial resolution Pb isotopic analyses of secondary phosphates using the CAMECA ims1290 ion microprobe reveal preservation of multiple generations of metamorphic phosphate, in some cases juxtaposed within a single inclusion on the 5-10 micron scale. Zircon can therefore in many cases preserve the compositions of its primary inclusion cargo through later metamorphism. Zircon can also preserve information about individual hydrothermal or metamorphic events during the grain's residence in the crust.

  15. Detrital zircon and igneous protolith ages of high-grade metamorphic rocks in the Highland and Wanni Complexes, Sri Lanka: Their geochronological correlation with southern India and East Antarctica

    NASA Astrophysics Data System (ADS)

    Kitano, Ippei; Osanai, Yasuhito; Nakano, Nobuhiko; Adachi, Tatsuro; Fitzsimons, Ian C. W.

    2018-05-01

    The high-grade metamorphic rocks of Sri Lanka place valuable constraints on the assembly of central parts of the Gondwana supercontinent. They are subdivided into the Wanni Complex (WC), Highland Complex (HC) and Vijayan Complex (VC), but their correlation with neighbouring Gondwana terranes is hindered by a poor understanding of the contact between the HC and WC. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb dating of remnant zircon cores from 45 high-grade metamorphic rocks in Sri Lanka reveals two domains with different age characteristics that correlate with the HC and WC and which help constrain the location of the boundary between them. The HC is dominated by detrital zircon ages of ca. 3500-1500 Ma from garnet-biotite gneiss, garnet-cordierite-biotite gneiss, some samples of garnet-orthopyroxene-biotite gneiss and siliceous gneiss (interpreted as paragneisses) and igneous protolith ages of ca. 2000-1800 Ma from garnet-hornblende-biotite gneiss, other samples of garnet-orthopyroxene-biotite gneiss, garnet-two-pyroxene granulite, two-pyroxene granulite and charnockite (interpreted as orthogneisses). In contrast, the WC is dominated by detrital zircon ages of ca. 1100-700 Ma from paragneisses and igneous protolith ages of ca. 1100-800 Ma from orthogneisses. This clearly suggests the HC and WC have different origins, but some of our results and previous data indicate their spatial distribution does not correspond exactly to the unit boundary proposed in earlier studies using Nd model ages. Detrital zircon and igneous protolith ages in the HC suggest that sedimentary protoliths were eroded from local 2000-1800 Ma igneous rocks and an older Paleoproterozoic to Archean craton. In contrast, the WC sedimentary protoliths were mainly eroded from local late Mesoproterozoic to Neoproterozoic igneous rocks with very minor components from an older 2500-1500 Ma craton, and in the case of the WC precursor sediments there was possibly

  16. Provenance of Modern Soils and Limestone and Chert Bedrock of Middle Tennessee Assessed Using Detrital Zircon U-Pb Geochronology

    NASA Astrophysics Data System (ADS)

    Ayers, J. C.; Katsiaficas, N. J.; Wang, X.

    2014-12-01

    Relatively thick soils mantle limestone bedrock throughout much of middle TN. Detrital zircon U-Pb geochronology was used to test two hypotheses: 1) That soil formed by accumulation of insoluble residue during chemical weathering of "dirty" limestone bedrock. 2) That an exotic component, perhaps wind-blown loess, was deposited and weathered to form soil. Samples of soil and underlying bedrock were collected from flat surfaces at the tops of cliffs. At Site 1 the Mississippian cherty limestone of the Fort Payne Formation was collected along with the B1 and B2 horizons of the overlying ultisol. At Site 2 a composite sample of A and B horizons of an alfisol and a sample of the underlying Ordovician limestone of the Hermitage Formation were collected. Zircon was recovered from soil and limestone samples, imaged using cathodoluminescence, and analyzed for trace elements and U-Pb isotopes using a 193 nm laser and quadrupole ICP-MS. Discordant analyses were discarded and 206Pb/238U ages are reported. Trace element concentrations and ratios in zircon seem to not be useful as provenance indicators. However, comparison of U-Pb age spectra showed that soils at both sites predominantly formed by weathering of limestone, with a small exotic component. The Hermitage has significant age peaks at ~1330, 1043, 955 and 439 Ma, and its overlying soil has age peaks at 1410, 1235, 1036 and 442 Ma. The age spectra are significantly different (Kolmogorov-Smirnov probability P = 0.01 < 0.05 significance). The Fort Payne has age peaks at ~1253, 967 and 417 Ma, while the B1 has age peaks at 1440, 1182, 1012 and 450 Ma (K-S P = 0.051) and the B2 at 1240, 941, 362, 81 and 33 Ma (K-S P = 0.073). The young ages in B2 require an exotic component that may account for ~25% of the measured ages. The source of the exotic material has not yet been identified, but its zircon age spectrum does not match previously published age spectra for the regional Pleistocene Peoria loess. Bedrock age peaks

  17. The Comparison of Detrital Zircon Ages to Point Count Provenance Analysis for the Pottsville Sandstone in the Northern Appalachian Foreland Basin Venango County, Pennsylvania

    NASA Astrophysics Data System (ADS)

    Loveday, S.; Harris, D. B.; Schiappa, T.; Pecha, M.

    2017-12-01

    The specific sources of sediments deposited in the Appalachian basin prior to and immediately following the Alleghenian orogeny has long been a topic of debate. Recent advances in U-Pb dating of detrital zircons have greatly helped to determine some of the sources of these sediments. For this study, sandstone samples were collected from the Pottsville Formation in the northern Appalachian Foreland Basin, Venango County, Pennsylvania to provide supplementary data for previous work that sought to describe the provenance of the same sediments by point counts of thin sections of the same units. Results of this previous work established that the provenance for these units was transitional recycled orogenic, including multiple recycled sediments, and that a cratonic contribution was not able to be determined clearly. The previous results suggested that the paleoenvironment was a fluvial dominated delta prograding in the northern direction. However, no geochronologic data was found during this study to confirm this interpretation. We sought to verify these results by U-Pb analysis of detrital zircons. Samples were collected from the areas where the previous research took place. U-Pb ages were found from sample at the highest elevation and lowest elevation. In the first sample, sample 17SL01 (younger sample stratigraphically), the zircons yield U-Pb age range peaks at 442-468 ma and 1037-1081 ma. The probability density plot for this specific sample displays a complete age gap from 500 ma to 811 ma. In the second sample, sample 17SL03 (older rock stratigraphically), the zircons yield U-Pb ages range peaks of 424-616 ma and 975-1057 ma. This sample doesn't show any ages younger than 424 ma and it doesn't display the sample age gap as sample 17SL01 does. The ages of zircons are consistent with thin section point counting provenance results from previous research suggesting zircon transport from the northern direction.

  18. Detrital zircon geochronology overlying the Naga Hills ophiolite

    NASA Astrophysics Data System (ADS)

    Roeder, T.; Aitchison, J.; Stojanovic, D.; Agarwal, A.; Ao, A.; Bhowmik, S.

    2013-12-01

    The Nagaland ophiolite in NE India represents the easternmost section of the ophiolitic belt running along the India-Asia suture. Outcrops near the border between Nagaland and Myanmar include not only a full suite of ophiolitic rocks but also high P/T blueschist rocks within a serpentinite-matrix mélange. Although Upper Jurassic radiolarians have been reported from the ophiolite itself (Baxter et al., 2011), few constraints have been placed on the timing of its emplacement onto India. Terrestrial sediments of the Phokphur Formation unconformably overlie the ophiolite. Similar to other sediments from along the ophiolite belt such as the Luiqu conglomerates in Tibet (Davis et al., 2002), they contain detritus derived from both the ophiolite and the continental margin onto which the ophiolite was emplaced. The clastic sediments of the Phokphur Formation potentially record not only the timing of ophiolite generation but also the ages of source terranes and can be used to place a minimum age constraint on the timing of ophiolite emplacement. As a contribution towards extending knowledge of the ophiolite belt and the India/Asia collision, we report preliminary results of an investigation into the sedimentology and detrital zircon geochronology of the Phokphur Formation in areas near Salumi and Zephu. Baxter, A.T., Aitchison, J.C., Zyabrev, S.V., Ali, J.R., 2011. Upper Jurassic radiolarians from the Naga Ophiolite, Nagaland, northeast India. Gondwana Research 20, 638-644. Davis, A.M., Aitchison, J.C., Badengzhu, Luo, H., Zyabrev, S., 2002. Paleogene island arc collision-related conglomerates, Yarlung-Tsangpo suture zone, Tibet. Sedimentary Geology 150, 247-273.

  19. Combined Detrital U/Pb Zircon and 40Ar/39Ar Mica Geoochronology to Test Structural Models for a Devonian Orogenic Collapse Basin in the Norwegian Caledonides

    NASA Astrophysics Data System (ADS)

    Templeton, J.; Anders, M.; Fossen, H.

    2014-12-01

    The Hornelen basin is the largest of the Devonian 'Old Red' sandstone basins in Norway, comprising 25 km of alluvial-fluvial deposits which are organized into basin-wide, coarsening-upward megacycles. Hornelen sits with several smaller basins in the hanging wall a major extensional shear zone along which the ultra-high pressure metamorphic core of subducted Baltican crust was rapidly exhumed during the extensional collapse of the Caledonian orogeny. The timing of orogenic collapse corresponds closely to the timing of the basins, which are loosely constrained by sparse trace-fossil assemblages to a mid-Devonian age. Further, the basins are now in brittle fault contact with the underlying mylonitic shear zone and the metamorphic core, implying that they are the upper-crustal expression of large-scale extension and deep-crustal exhumation. Two distinct structural models have been proposed for Hornelen to account for these observations. The strike-slip model juxtaposes different source terranes across the basin-controlling fault and predicts spatially changing provenance within chronostratigraphic units. The supradetachment model links the filling of the basin directly to unroofing of the metamorphic core on a low-angle detachment fault, and predicts basin-wide changes in provenance through time with progressive exhumation of the metamorphic hinterland. We present an extensive new provenance dataset, spanning the Hornelen basin strata through space and time. Detrital zircon U/Pb ages from 18 new samples comprise three distinct populations (1.6, 1.0, and 0.43 Ga) with the Caledonian-aged zircons (ca 0.43 Ga) present mainly along the northern margin of the basin, representing an Upper Allochthon source not found on the southern or eastern margins of the basin. Juxtaposition of different source terranes across the basin supports the strike-slip model. 40Ar/39Ar detrital white mica from the same sample set documents a younging of the dominant age peak from 432 Ma in the

  20. Provenance of sediments from Sumatra, Indonesia - Insights from detrital U-Pb zircon geochronology, heavy mineral analyses and Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Liebermann, C.; Hall, R.; Gough, A.

    2017-12-01

    The island of Sumatra is situated at the southwestern margin of the Indonesian archipelago. Although it is the sixth largest island in the world, the geology of the Sumatra sedimentary basins and their underlying basement is relatively poorly understood in terms of their provenance. This work is a multi-proxy provenance study utilizing U-Pb detrital zircon dating by LA-ICP-MS combined with optical and Raman spectroscopy-based heavy mineral analysis. It will help to unravel the stratigraphy of Sumatra, contribute to paleogeographic reconstruction of western SE Asia, and aid a wider understanding of Sumatran petroleum plays. Thin section analyses, heavy mineral assemblages, and >3500 concordant U-Pb zircon ages, from samples acquired during two fieldwork seasons indicate a mixed provenance for Cenozoic sedimentary formations, including both local igneous sources and mature basement rocks. Characteristic Precambrian zircon age spectra are found in all analysed Cenozoic sedimentary strata. These can be correlated with zircon age populations found in Sumatran basement rocks; Neoproterozoic and Mesoproterozoic age groups are dominant (c. 500-600 Ma, c. 850-1000 Ma, c. 1050-1200 Ma). Paleoproterozoic to Archaean zircons occur as minor populations. The Phanerozoic age spectra of the Cenozoic formations are characterised by distinct Carboniferous, Permo-Triassic, and Jurassic-Cretaceous zircon populations. Permo-Triassic zircons are interpreted to come from granitoids in the Malay peninsula or Sumatra itself. Eocene to Lower Miocene strata are characterised by ultrastable heavy minerals such as zircon, tourmaline, and rutile, which together with garnet, suggest the principal sources were igneous and metamorphic basement rocks. Cenozoic zircons appear only from the Middle Miocene onwards. This change is interpreted to indicate a new contribution from a local volcanic arc, and is supported by the occurrence of unstable heavy minerals such as apatite and clinopyroxene, and the

  1. Provenance studies by fission-track dating of zircon-etching and counting procedures

    USGS Publications Warehouse

    Naeser, Nancy D.; Zeitler, Peter K.; Naeser, Charles W.; Cerveny, Philip F.

    1987-01-01

    In sedimentary rocks that have not been heated to high enough temperatures to anneal fission tracks in zircon (greater than approximately equals 160 degree C), fission-track ages of individual detrital zircon grains provide valuable information about the source rocks eroded to form the sediments. The success of such studies depends, however, on the degree to which the ages determined from the detrital suite accurately portray the range of grain ages that are present in the suite. This in turn depends to a large extent on using counting and, in particular, etching procedures that permit proper sampling of grains with a wide range of age and uranium concentrations. Results are reported here of an experimental study of a 'detrital' zircon suite manufactured from several zircon populations of known age. This study suggests that multiple etches are required when a complete spectrum of ages in a zircon suite is desired.

  2. Paragneiss zircon geochronology and trace element geochemistry, North Qaidam HP/UHP terrane, western China

    USGS Publications Warehouse

    Mattinson, C.G.; Wooden, J.L.; Zhang, J.X.; Bird, D.K.

    2009-01-01

    In the southeastern part of the North Qaidam terrane, near Dulan, paragneiss hosts minor peridotite and UHP eclogite. Zircon geochronology and trace element geochemistry of three paragneiss samples (located within a ???3 km transect) indicates that eclogite-facies metamorphism resulted in variable degrees of zircon growth and recrystallization in the three samples. Inherited zircon core age groups at 1.8 and 2.5 Ga suggest that the protoliths of these rocks may have received sediments from the Yangtze or North China cratons. Mineral inclusions, depletion in HREE, and absence of negative Eu anomalies indicate that zircon U-Pb ages of 431 ?? 5 Ma and 426 ?? 4 Ma reflect eclogite-facies zircon growth in two of the samples. Ti-in-zircon thermometry results are tightly grouped at ???660 and ???600 ??C, respectively. Inclusions of metamorphic minerals, scarcity of inherited cores, and lack of isotopic or trace element inheritance demonstrate that significant new metamorphic zircon growth must have occurred. In contrast, zircon in the third sample is dominated by inherited grains, and rims show isotopic and trace element inheritance, suggesting solid-state recrystallization of detrital zircon with only minor new growth. ?? 2009 Elsevier Ltd.

  3. A hidden Late Cretaceous arc and subsequent magmatic events in the Caucasus-Iran-Anatolia (CIA) orogenic belt: Detrital zircon U-Pb and Hf isotopic constraints

    NASA Astrophysics Data System (ADS)

    Tien, C. Y.; Lin, Y. C.; Chu, M. F.; Chung, S. L.; Bi˙ngöl, A. F.

    2017-12-01

    The Caucasus-Iran-Anatolia (CIA) orogenic belt formed by "Turkic-type orogeny" consists mainly of subduction-accretion complexes following the collision between Eurasia and Arabia and the closure of Neotethy. This study reports U-Pb and Hf isotopic data of detrital zircon separates from five Eocene to mid-Miocene sandstone samples from Divrigi and Duranlar in the west to the Mus basin in the east, all locating in the northern part of the Bitlis-Zagros suture zone. The U-Pb age data suggest four main magmatic episodes: (1) 100-70 Ma, (2) 60-40 Ma, (3) 30 Ma, and (4) 15 Ma. The Late Cretaceous zircons recovered mainly from the Mus basin are marked by a significant Hf isotopic variation over time, with ɛHf(T) values dropping from +15 to -10. Zircons from the second and third episodes show spatial variations in isotopic compositions, with positive ɛHf(T) values (+10 to +5) in the Mus basin and heterogeneous ɛHf(T) values (+10 to -10) in the west. The fourth and youngest episode of zircons, mainly from Duranlar area, shows uniform ɛHf(T) values around +5. We attribute the Late Cretaceous episode of zircons to the broadly coeval Elazig arc magmatism that, according to our counterpart study, occurred as a short-lived, intra-oceanic arc system by subduction initiation after the formation of Neotethyan ophiolites in the region. Moreover, we argue that this Late Cretaceous arc system may have existed more widely within the southern branch of Neothethys than that suggested by present-day outcrops. The dramatic change in Hf isotopic composition from 100 to 70 Ma, also observed in the rock record by our counterpart study, may be interpreted as a result of subduction to accretion processes. The remaining three episodes of zircons are related to younger stages of magmatism within or around the suture zone that remains poorly studied. Our results indicate that detrital zircon is a useful tool to uncover "hidden" magmatic records in the CIA and other "Turkic-type" orogenic

  4. A Change in Igneous Activity of the Jack Hills Zircon Sources ca. 3.9 Ga

    NASA Astrophysics Data System (ADS)

    Bell, E. A.; Harrison, T. M.

    2010-12-01

    New Ti-in-zircon crystallization temperature (Txlln) data for <4 Ga Jack Hills zircons reveal that the tight clustering of Hadean grains around a Txlln of 680°C, possibly indicative of felsic-to-intermediate minimum melting conditions, continues to ~3.92 Ga. Between 3.92-3.82 Ga the 680°C clustering ceases and most concordant grains cluster around an apparent Txlln of 610°C. A small group of zircons with higher Txlln (~750°C), present during the Hadean, is also observed during this period. After 3.82 Ga a Hadean-like distribution resumes for ~100 Ma. This large, concordant, low-Ti group at ~3.9 Ga is statistically distinct from the Hadean distribution and appears to be unique in the Jack Hills zircon record. The existence of coeval high- and low-Ti groups suggests that two distinct zircon-forming processes are distinguishable ~3.9 Ga, unlike during the Hadean. The significant numbers of zircons with apparent Txlln below 600°C may be suggestive of subsolidus formation, since igneous units with solidii below 600°C are relatively rare. The higher-Ti group is more consistent with an intermediate to mafic igneous origin but metamorphic overprinting or subsolidus formation at granulite grade cannot be ruled out by Txlln alone. A substantial proportion of the high-Ti group display oscillatory and disrupted oscillatory zoning in cathodoluminescence images, usually indicative of igneous origins and later metamorphism, respectively; most low-Ti grains are homogeneous. Several of each group display patchy zonation indicative of metamorphic overprinting. Although several grains with apparent Txlln >600°C display oscillatory zonation, the majority of the low-Ti group do not show textural evidence for igneous origins. We interpret these results to indicate the transition from a mechanism(s) that produced dominantly 680°C apparent zircon temperatures at ca. 3.9 Ga to include a new zircon-forming process in the sediment source(s), likely a protracted period of metamorphism

  5. Detrital zircon and apatite (U-Th)/He geochronology of intercalated baked sediments: A new approach to dating young basalt flows

    NASA Astrophysics Data System (ADS)

    Cooper, Frances J.; van Soest, Matthijs C.; Hodges, Kip V.

    2011-07-01

    Simple numerical models suggest that many basaltic lava flows should sufficiently heat the sediments beneath them to reset (U-Th)/He systematics in detrital zircon and apatite. This result suggests a useful way to date such flows when more conventional geochronological approaches are either impractical or yield specious results. We present here a test of this method on sediments interstratified with basalt flows of the Taos Plateau Volcanic Field of New Mexico. Nineteen zircons and apatites from two samples of baked sand collected from the uppermost 2 cm of a fluvial channel beneath a flow of the Upper Member of the Servilleta Basalt yielded an apparent age of 3.487 ± 0.047 Ma (2 SE confidence level), within the range of all published 40Ar/39Ar dates for other flows in the Upper Member (2.81-3.72 Ma) and statistically indistinguishable from the 40Ar/39Ar dates for basal flows of the Upper Member with which the studied flow is broadly correlative (3.61 ± 0.13 Ma). Given the high yield of 4He from U and Th decay, this technique may be especially useful for dating Pleistocene basalt flows. Detailed studies of the variation of (U-Th)/He detrital mineral dates in sedimentary substrates, combined with thermal modeling, may be a valuable tool for physical volcanologists who wish to explore the temporal and spatial evolution of individual flows and lava fields.

  6. Detrital zircon age distribution from Devonian and Carboniferous sandstone in the Southern Variscan Fold-and-Thrust belt (Montagne Noire, French Massif Central), and their bearings on the Variscan belt evolution

    NASA Astrophysics Data System (ADS)

    Lin, Wei; Faure, Michel; Li, Xian-hua; Chu, Yang; Ji, Wenbin; Xue, Zhenhua

    2016-05-01

    In the Southern French Massif Central, the Late Paleozoic sedimentary sequences of the Montagne Noire area provide clues to decipher the successive tectonic events that occurred during the evolution of the Variscan belt. Previous sedimentological studies already demonstrated that the siliciclastic deposits were supplied from the northern part of the Massif Central. In this study, detrital zircon provenance analysis has been investigated in Early Devonian (Lochkovian) conglomerate and sandstone, and in Carboniferous (Visean to Early Serpukhovian) sandstone from the recumbent folds and the foreland basin of the Variscan Southern Massif Central in Montagne Noire. The zircon grains from all of the samples yielded U-Pb age spectra ranging from Neoarchean to Late Paleozoic with several age population peaks at 2700 Ma, 2000 Ma, 980 Ma, 750 Ma, 620 Ma, 590 Ma, 560 Ma, 480 Ma, 450 Ma, and 350 Ma. The dominant age populations concentrate on the Neoproterozoic and Paleozoic. The dominant concordant detrital zircon age populations in the Lochkovian samples, the 480-445 Ma with a statistical peak around 450 Ma, are interpreted as reflecting the rifting event that separated several continental stripes, such as Armorica, Mid-German Crystalline Rise, and Avalonia from the northern part of Gondwana. However, Ediacaran and Cambrian secondary peaks are also observed. The detrital zircons with ages at 352 - 340 Ma, with a statistical peak around 350 Ma, came from the Early Carboniferous volcanic and plutonic rocks similar to those exposed in the NE part of the French Massif Central. Moreover, some Precambrian grains recorded a more complex itinerary and may have experienced a multi-recycling history: the Archean and Proterozoic grains have been firstly deposited in Cambrian or Ordovician terrigenous rocks, and secondly re-sedimented in Devonian and/or Carboniferous formations. Another possibility is that ancient grains would be inherited grains, scavenged from an underlying but not

  7. Zircon ages delimit the provenance of a sand extrudite from the Botucatu Formation in the Paraná volcanic province, Iraí, Brazil.

    PubMed

    Pinto, Viter M; Hartmann, Léo A; Santos, João O S; McNaughton, Neal J

    2015-09-01

    Ion microprobe age determinations of 102 detrital zircon crystals from a sand extrudite, Cretaceous Paraná volcanic province, set limits on the origin of the numerous sand layers present in this major flood basalt province. The zircon U-Pb ages reflect four main orogenic cycles: Mesoproterozoic (1155-962 Ma), latest Proterozoic-early Cambrian (808-500 Ma) and two Palaeozoic (Ordovician- 480 to 450 Ma, and Permian to Lower Triassic- 296 to 250 Ma). Two additional small concentrations are present in the Neoarchean (2.8 to 2.6 Ga) and Paleoproterozoic (2.0 to 1.7 Ga). Zircon age peaks closely match the several pulses of igneous activity in the Precambrian Brazilian Shield and active orogeny in Argentina. A main delimitation of the origin of the sand is the absence of zircon ages from the underlying Cretaceous basalts, thus supporting an injectite origin of the sand as an extrudite that emanated from the paleoerg that constitutes the Botucatu Formation.

  8. A search for thermal excursions from ancient extraterrestrial impacts using Hadean zircon Ti-U-Th-Pb depth profiles.

    PubMed

    Abbott, Sunshine S; Harrison, T Mark; Schmitt, Axel K; Mojzsis, Stephen J

    2012-08-21

    Few terrestrial localities preserve more than a trace lithic record prior to ca. 3.8 Ga greatly limiting our understanding of the first 700 Ma of Earth history, a period inferred to have included a spike in the bolide flux to the inner solar system at ca. 3.85-3.95 Ga (the Late Heavy Bombardment, LHB). An accessible record of this era may be found in Hadean detrital zircons from the Jack Hills, Western Australia, in the form of μm-scale epitaxial overgrowths. By comparing crystallization temperatures of pre-3.8 Ga zircon overgrowths to the archive of zircon temperature spectra, it should, in principle, be possible to identify a distinctive impact signature. We have developed Ti-U-Th-Pb ion microprobe depth profiling to obtain age and temperature information within these zircon overgrowths and undertaken a feasibility study of its possible use in identifying impact events. Of eight grains profiled in this fashion, four have overgrowths of LHB-era age. Age vs. temperature profiles reveal a period between ca. 3.85-3.95 Ga (i.e., LHB era) characterized by significantly higher temperatures (approximately 840-875 °C) than do older or younger zircons or zircon domains (approximately 630-750 °C). However, temperatures approaching 900 °C can result in Pb isotopic exchange rendering interpretation of these profiles nonunique. Coupled age-temperature depth profiling shows promise in this role, and the preliminary data we report could represent the first terrestrial evidence for impact-related heating during the LHB.

  9. Timing of deformation and rapid subsidence in the northern Altiplano, Peru: Insights from detrital zircon geochronology of the Ayaviri hinterland basin

    NASA Astrophysics Data System (ADS)

    Horton, B. K.; Perez, N. D.; Saylor, J. E.

    2011-12-01

    Although age constraints on crustal deformation and sediment accumulation prove critical to testing hypotheses of orogenic plateau construction, a common lack of marine facies, volcanic tuffs, and suitable fossils hinders many attempts at chronological reconstructions. A series of elevated retroarc basins along the axis of the Andean orogenic belt provide opportunities to define the timing of deformation and transformation from foreland to hinterland basin configurations. In this study, we present new U-Pb ages of detrital zircons in the Ayaviri intermontane basin of southern Peru (~4 km elevation) in the northern part of the central Andean (Altiplano) plateau. Nearly all sandstone samples show strong unimodal U-Pb age peaks (generally defined by > 5-50 zircons), suggesting these age peaks represent syndepositional volcanism and can be regarded as accurate estimates of true depositional (stratigraphic) age. Integration of these ages with structural and stratigraphic relationships demonstrate the utility of zircon U-Pb geochronology in defining both (1) the timing of basin partitioning and (2) the pace of sediment accumulation. (1) U-Pb ages for several sandstone samples from growth-strata packages associated with two basin-bounding faults reveal structural partitioning of the Ayaviri basin from late Oligocene to Miocene time. In the north, displacement along the southwest-directed Ayaviri thrust fault commenced in late Oligocene time (~28-24 Ma), inducing initial structural partitioning of an upper Eocene-Oligocene, > 5 km thick succession potentially representing an early Andean retroarc foreland basin. In the south, the Ayaviri basin was further disrupted by initial displacement along the northeast-directed Pasani thrust fault in early to middle Miocene time (~18-15 Ma). (2) Additional U-Pb analyses from the Ayaviri basin fill help delimit the long-term rates of sedimentation, suggesting relatively short-lived (< 5 Myr) pulses of accelerated accumulation. Rapid

  10. What Hf isotopes in zircon tell us about crust-mantle evolution

    NASA Astrophysics Data System (ADS)

    Iizuka, Tsuyoshi; Yamaguchi, Takao; Itano, Keita; Hibiya, Yuki; Suzuki, Kazue

    2017-03-01

    The 176Lu-176Hf radioactive decay system has been widely used to study planetary crust-mantle differentiation. Of considerable utility in this regard is zircon, a resistant mineral that can be precisely dated by the U-Pb chronometer and record its initial Hf isotope composition due to having low Lu/Hf. Here we review zircon U-Pb age and Hf isotopic data mainly obtained over the last two decades and discuss their contributions to our current understanding of crust-mantle evolution, with emphasis on the Lu-Hf isotope composition of the bulk silicate Earth (BSE), early differentiation of the silicate Earth, and the evolution of the continental crust over geologic history. Meteorite zircon encapsulates the most primitive Hf isotope composition of our solar system, which was used to identify chondritic meteorites best representative of the BSE (176Hf/177Hf = 0.282793 ± 0.000011; 176Lu/177Hf = 0.0338 ± 0.0001). Hadean-Eoarchean detrital zircons yield highly unradiogenic Hf isotope compositions relative to the BSE, providing evidence for the development of a geochemically enriched silicate reservoir as early as 4.5 Ga. By combining the Hf and O isotope systematics, we propose that the early enriched silicate reservoir has resided at depth within the Earth rather than near the surface and may represent a fractionated residuum of a magma ocean underlying the proto-crust, like urKREEP beneath the anorthositic crust on the Moon. Detrital zircons from world major rivers potentially provide the most robust Hf isotope record of the preserved granitoid crust on a continental scale, whereas mafic rocks with various emplacement ages offer an opportunity to trace the Hf isotope evolution of juvenile continental crust (from εHf[4.5 Ga] = 0 to εHf[present] = + 13). The river zircon data as compared to the juvenile crust composition highlight that the supercontinent cycle has controlled the evolution of the continental crust by regulating the rates of crustal generation and intra

  11. A search for thermal excursions from ancient extraterrestrial impacts using Hadean zircon Ti-U-Th-Pb depth profiles

    PubMed Central

    Abbott, Sunshine S.; Harrison, T. Mark; Schmitt, Axel K.; Mojzsis, Stephen J.

    2012-01-01

    Few terrestrial localities preserve more than a trace lithic record prior to ca. 3.8 Ga greatly limiting our understanding of the first 700 Ma of Earth history, a period inferred to have included a spike in the bolide flux to the inner solar system at ca. 3.85–3.95 Ga (the Late Heavy Bombardment, LHB). An accessible record of this era may be found in Hadean detrital zircons from the Jack Hills, Western Australia, in the form of μm-scale epitaxial overgrowths. By comparing crystallization temperatures of pre-3.8 Ga zircon overgrowths to the archive of zircon temperature spectra, it should, in principle, be possible to identify a distinctive impact signature. We have developed Ti-U-Th-Pb ion microprobe depth profiling to obtain age and temperature information within these zircon overgrowths and undertaken a feasibility study of its possible use in identifying impact events. Of eight grains profiled in this fashion, four have overgrowths of LHB-era age. Age vs. temperature profiles reveal a period between ca. 3.85–3.95 Ga (i.e., LHB era) characterized by significantly higher temperatures (approximately 840–875 °C) than do older or younger zircons or zircon domains (approximately 630–750 °C). However, temperatures approaching 900 °C can result in Pb isotopic exchange rendering interpretation of these profiles nonunique. Coupled age-temperature depth profiling shows promise in this role, and the preliminary data we report could represent the first terrestrial evidence for impact-related heating during the LHB. PMID:22869711

  12. Using the magmatic record to constrain the growth of continental crust-The Eoarchean zircon Hf record of Greenland

    NASA Astrophysics Data System (ADS)

    Fisher, Christopher M.; Vervoort, Jeffrey D.

    2018-04-01

    Southern West Greenland contains some of the best-studied and best-preserved magmatic Eoarchean rocks on Earth, and these provide an excellent vantage point from which to view long-standing questions regarding the growth of the earliest continental crust. In order to address the questions surrounding early crustal growth and complementary mantle depletion, we present Laser Ablation Split Stream (LASS) analyses of the U-Pb and Hf isotope compositions of zircon from eleven samples of the least-altered meta-igneous rocks from the Itsaq (Amîtsoq) Gneisses of the Isukasia and Nuuk regions of southern West Greenland. This analytical technique allows a less ambiguous approach to determining the age and Hf isotope composition of complicated zircon. Results corroborate previous findings that Eoarchean zircon from the Itsaq Gneiss (∼3.85 Ga to ∼3.63 Ga) were derived from a broadly chondritic source. In contrast to the Sm-Nd whole rock isotope record for southern West Greenland, the zircon Lu-Hf isotope record provides no evidence for early mantle depletion, nor does it suggest the presence of crust older than ∼3.85 Ga in Greenland. Utilizing LASS U-Pb and Hf data from the Greenland zircons studied here, we demonstrate the importance of focusing on the magmatic (rather than detrital) zircon record to more confidently understand early crustal growth and mantle depletion. We compare the Greenland Hf isotope data with other Eoarchean magmatic complexes such as the Acasta Gneiss Complex, Nuvvuagittuq greenstone belt, and the gneissic complexes of southern Africa, and all lack zircons with suprachondritic Hf isotope compositions. In total, these data suggest only a very modest volume of crust was produced during (or survived from) the Hadean and earliest Eoarchean. There remains no record of planet-scale early Earth mantle depletion in the Hf isotope record prior to 3.8 Ga.

  13. Erosional history of the Appalachians as recordeed in detrital zircon fission-track ages and lithic detritus in Atlantic Coastal Plain sediments

    USGS Publications Warehouse

    Naeser, C.W.; Naeser, N.D.; Edwards, Lucy E.; Weems, Robert E.; Southworth, C. Scott; Newell, Wayne L.

    2016-01-01

    Comparison of fission-track (FT) ages of detrital zircons recovered from Atlantic Coastal Plain sediments to FT ages of zircons from bedrock in source terranes in the Appalachians provides a key to understanding the provenance of the sediments and, in turn, the erosional and depositional history of the Atlantic passive margin.In Appalachian source terranes, the oldest zircon fission-track (ZFT) ages from bedrock in the western Appalachians (defined for this paper as the Appalachian Plateau, Valley and Ridge, and far western Blue Ridge) are notably older than the oldest ages from bedrock in the eastern Appalachians (Piedmont and main part of the Blue Ridge). The age difference is seen both in ZFT sample ages and in individual zircon grain ages and reflects differences in the thermotectonic history of the rocks. In the east, ZFT data indicate that the rocks cooled from temperatures high enough to partially or totally reset ZFT ages during the Paleozoic and (or) Mesozoic. The majority of the rocks are interpreted to have cooled through the ZFT closure temperature (∼235 °C) at various times during the late Paleozoic Alleghanian orogeny. In contrast, most of the rocks sampled in the western Appalachians have never been heated to temperatures high enough to totally reset their ZFT ages. Reflecting their contrasting thermotectonic histories, nearly 80 percent of the sampled western rocks yield one or more zircon grains with very old FT ages, in excess of 800 Ma; zircon grains yielding FT ages this old have not been found in rocks in the Piedmont and main part of the Blue Ridge. The ZFT data suggest that the asymmetry of zircon ages of exposed bedrock in the eastern and western Appalachians was in evidence by no later than the Early Cretaceous and probably by the Late Triassic.Detrital zircon suites from sands collected in the Atlantic Coastal Plain provide a record of detritus eroded from source terranes in the Appalachians during the Mesozoic and Cenozoic. In Virginia

  14. Detrital zircon microtextures and U-PB geochronology of Upper Jurassic to Paleocene strata in the distal North American Cordillera foreland basin

    NASA Astrophysics Data System (ADS)

    Finzel, E. S.

    2017-07-01

    Detrital zircon surface microtextures, geochronologic U-Pb data, and tectonic subsidence analysis from Upper Jurassic to Paleocene strata in the Black Hills of South Dakota reveal provenance variations in the distal portion of the Cordillera foreland basin in response to tectonic events along the outboard margin of western North America. During Late Jurassic to Early Cretaceous time, nonmarine strata record initially low rates of tectonic subsidence that facilitated widespread recycling of older foreland basin strata in eolian and fluvial systems that dispersed sediment to the northeast, with minimal sediment derived from the thrust belt. By middle Cretaceous time, marine inundation reflects increased subsidence rates coincident with a change to eastern sediment sources. Lowstand Albian fluvial systems in the Black Hills may have been linked to fluvial systems upstream in the midcontinent and downstream in the Bighorn Basin in Wyoming. During latest Cretaceous time, tectonic uplift in the study area reflects dynamic processes related to Laramide low-angle subduction that, relative to other basins to the west, was more influential due to the greater distance from the thrust load. Provenance data from Maastrichtian and lower Paleocene strata indicate a change back to western sources that included the Idaho-Montana batholith and exhumed Belt Supergroup. This study provides a significant contribution to the growing database that is refining the tectonics and continental-scale sediment dispersal patterns in North America during Late Jurassic-early Paleocene time. In addition, it demonstrates the merit of using detrital zircon grain shape and surface microtextures to aid in provenance interpretations.

  15. Detrital zircon analysis of Mesoproterozoic and neoproterozoic metasedimentary rocks of northcentral idaho: Implications for development of the Belt-Purcell basin

    USGS Publications Warehouse

    Lewis, R.S.; Vervoort, J.D.; Burmester, R.F.; Oswald, P.J.

    2010-01-01

    The authors analyzed detrital zircon grains from 10 metasedimentary rock samples of the Priest River complex and three other amphibolite-facies metamorphic sequences in north-central Idaho to test the previous assignment of these rocks to the Mesoproterozoic Belt-Purcell Supergroup. Zircon grains from two samples of the Prichard Formation (lower Belt) and one sample of Cambrian quartzite were also analyzed as controls with known depositional ages. U-Pb zircon analysis by laser ablation - inductively coupled plasma - mass spectrometry reveals that 6 of the 10 samples contain multiple age populations between 1900 and 1400 Ma and a scatter of older ages, similar to results reported from the Belt- Purcell Supergroup to the north and east. Results from the Priest River metamorphic complex confirm previous correlations with the Prichard Formation. Samples from the Golden and Elk City sequences have significant numbers of 1500-1380 Ma grains, which indicates that they do not predate the Belt. Rather, they are probably from a relatively young, southwestern part of the Belt Supergroup (Lemhi subbasin). Non-North American (1610-1490 Ma) grains are rare in these rocks. Three samples of quartzite from the Syringa metamorphic sequence northwest of the Idaho batholith contain zircon grains younger than the Belt Supergroup and support a Neoproterozoic age. A single Cambrian sample has abundant 1780 Ma grains and none younger than ~1750 Ma. These results indicate that the likely protoliths of many high-grade metamorphic rocks in northern Idaho were strata of the Belt-Purcell Supergroup or overlying rocks of the Neoproterozoic Windermere Supergroup and not basement rocks.

  16. Detrital zircon U-Pb reconnaissance of the Franciscan subduction complex in northwestern California

    USGS Publications Warehouse

    Dimitru, Trevor; Ernst, W. Gary; Hourigan, Jeremy K.; McLaughlin, Robert J.

    2015-01-01

    In northwestern California, the Franciscan subduction complex has been subdivided into seven major tectonostratigraphic units. We report U-Pb ages of ≈2400 detrital zircon grains from 26 sandstone samples from 5 of these units. Here, we tabulate each unit's interpreted predominant sediment source areas and depositional age range, ordered from the oldest to the youngest unit. (1) Yolla Bolly terrane: nearby Sierra Nevada batholith (SNB); ca. 118 to 98 Ma. Rare fossils had indicated that this unit was mostly 151-137 Ma, but it is mostly much younger. (2) Central Belt: SND; ca. 103 too 53 Ma (but poorly constrained), again mostly younger than previously thought. (3) Yager terrane: distant Idaho batholith (IB); ca. 52 to 50 Ma. Much of the Yager's detritus was shed during major core complex extension and erosion in Idaho that started 53 Ma. An eocene Princeton River-Princeton submarine canyon system transported this detritus to the Great Valley forearc basin and thence to the Franciscan trench. (4) Coastal terrane: mostly IB, ±SNB, ±nearby Cascade arc, ±Nevada Cenozoic ignimbrite belt; 52 to <32 Ma. (5) King Range terrane: dominated by IB and SNB zircons; parts 16-14 Ma based on microfossils. Overall, some Franciscan units are younger than previously thought, making them more compatible with models for the growth of subduction complexes by positive accretion. From ca. 118 to 70 Ma, Franciscan sediments were sourced mainly from the nearby Sierra Nevada region and were isolated from southwestern US and Mexican sources. From 53 to 49 Ma, the Franciscan was sourced from both Idaho and the Sierra Nevada. By 37-32 Ma, input from Idaho had ceased. The influx from Idaho probably reflects major tectonism in Idaho, Oregon, and Washington, plus development of a through-going Princeton River to California, rather than radical changes in the subduction system at the Franciscan trench itself.

  17. U-Pb Detrital Zircon Geochronologic Constraints on Depositional Age and Sediment Source Terrains of the Late Paleozoic Tepuel-Genoa Basin

    NASA Astrophysics Data System (ADS)

    Griffis, N. P.; Montanez, I. P.; Isbell, J.; Gulbranson, E. L.; Wimpenny, J.; Yin, Q. Z.; Cúneo, N. R.; Pagani, M. A.; Taboada, A. C.

    2014-12-01

    The late Paleozoic Ice Age (LPIA) is the longest-lived icehouse of the Phanerozoic and the only time a metazoan dominated and vegetated world transitioned from an icehouse climate into a greenhouse. Despite several decades of research, the timing, extent of glaciation and the location of ice centers remain unresolved, which prohibits reconstruction of ice volume. The Permo-Carboniferous sediments in the Tepuel-Genoa Basin, Patagonia contains a near complete record of sedimentation from the lower Carboniferous through lower Permian. Outsized clasts, thin pebble-rich diamictites and slumps represent the last of the late Paleozoic glacially influenced deep-water marine sediments in the Mojón de Hierro Fm. and the Paleozoic of Patagonia. U-Pb analysis of detrital zircons separated from slope sediments reveal groupings (20 myr bins, n≥5 zircons) with peak depositional ages of 420, 540 to 660 and 1040 Ma. Zircon age populations recovered from the Mojón de Hierro Fm. compare well with bedrock ages of the Deseado Massif of SE Patagonia, suggesting this may be a potential source of sediments. The maximum depositional age of the sediments is 306.05 ± 3.7 Ma (2σ) as determined by the median age of the two youngest concordant zircons that overlap in error. The youngest zircon from the analysis yields a 238U/206Pb age of 301.3 ± 4.5 Ma (2σ; MSWD = 2.3). Younger zircons from the analysis compare well with the age of granite bedrock exposed along the basin margin to the E-NE suggesting they may reflect a more proximal source. These data, which indicate a maximum age of late Carboniferous for the Mojón de Hierro Fm, provide the first geochemical constraints for the timing of final deposition of glaciomarine sediments in the Tepuel-Genoa Basin, and contributes to the biostratigraphic correlation of the late Paleozoic succession in Patagonia with other key LPIA basins that has thus far been hindered by faunal provincialism.

  18. Provenance studies by fission-track dating of zircon-etching and counting procedures

    USGS Publications Warehouse

    Naeser, N.D.; Zeitler, P.K.; Naeser, C.W.; Cerveny, P.F.

    1987-01-01

    In sedimentary rocks that have not been heated to high enough temperatures to anneal fission tracks in zircon (greater than ≈ 160°C), fission-track ages of individual detrital zircon grains provide valuable information about the source rocks eroded to form the sediments. The success of such studies depends, however, on the degree to which the ages determined from the detrital suite accurately portray the range of grain ages that are present in the suite. This in turn depends to a large extent on using counting and, in particular, etching procedures that permit proper sampling of grains with a wide range of age and uranium concentrations. Results are reported here of an experimental study of a ‘detrital’ zircon suite manufactured from several zircon populations of known age. This study suggests that multiple etches are required when a complete spectrum of ages in a zircon suite is desired.

  19. Prospects for Practical Laser Ablation U/Pb and (U-Th)/He Double-Dating (LADD) of Detrital Apatite

    NASA Astrophysics Data System (ADS)

    Horne, A.; Hodges, K. V.; Van Soest, M. C.

    2017-12-01

    A laser ablation micro-analytical technique for (U-Th)/He dating has been shown to be an effective approach to the thermochronologic study of detrital zircons (Tripathy-Lang et al., J. Geophys. Res., 2013), while Evans et al. (J. Anal. At. Spectrom., 2015) and Horne et al. (Geochim. Cosmochim. Acta, 2016) demonstrated how the technique could be modified to enable laser ablation U/Pb and (U-Th)/He double-dating (LADD) of detrital zircon and titanite. These successes beg the question of whether or not LADD is viable for another commonly encountered detrital mineral: apatite. Exploratory LADD studies in Arizona State University's Group 18 Laboratories - using Durango fluorapatite, apatite from the Fish Canyon tuff, and detrital apatite from modern fluvial sediments in the eastern Sierra Nevada of California - illustrate that the method is indeed viable for detrital apatite. However, the method may not be appropriate for all detrital samples. For example, many apatite grains encountered in detrital samples from young orogenic settings have low concentrations of U and Th and small crystal sizes. This can lead to imprecise laser ablation (U-Th)/He dates, especially for very young grains potentially obscuring or inhibiting relevant interpretations of the data set.

  20. Detrital zircon U-Pb geochronology and whole-rock Nd-isotope constraints on sediment provenance in the Neoproterozoic Sergipano orogen, Brazil: From early passive margins to late foreland basins

    NASA Astrophysics Data System (ADS)

    Oliveira, E. P.; McNaughton, N. J.; Windley, B. F.; Carvalho, M. J.; Nascimento, R. S.

    2015-11-01

    SHRIMP U-Pb detrital zircon geochronology and depleted-mantle Nd-model ages of clastic rocks were combined to understand the sediment provenance in the Neoproterozoic Sergipano Belt. The Sergipano is the main orogenic belt between the Borborema province and the São Francisco Craton, eastern South America; it is divisible into several lithostratigraphic domains from North to South: Canindé, Poço Redondo-Marancó, Macururé, Vaza Barris, and Estância. Nd model ages (TDM) and detrital zircon U-Pb SHRIMP geochronology indicate that the protoliths of clastic metasedimentary rocks from the Marancó and Macururé domains were mostly derived from eroded late Mesoproterozoic to early Neoproterozoic rocks (1000-900 Ma), whereas detritus of similar rocks from the Canindé domain came from a younger source (ca. 700 Ma and 1000 Ma). Samples from the Vaza Barris domain show the greatest scatter of both TDM and zircon ages amongst all domains, but with important contributions from Proterozoic sources (690-1050 Ma and ca. 2100 Ma) and less from Archaean sources. The Estância domain samples have zircon population peaks at 570 Ma, 600 Ma, and 920-980 Ma, with a few older grains; one diamictite contains only ca. 2150 Ma zircon grains. Our preliminary results support a model in which sediments of the Marancó and Macururé domains were deposited on a continental margin of the ancient Borborema plate before its collision with the São Francisco Craton; the Canindé domain is likely to be an aborted Neoproterozoic rift assemblage within the southern part of the Borborema plate (Pernambuco-Alagoas massif). The basal units of the Vaza Barris and Estância domains have clast sources from the São Francisco Craton and are best interpreted as passive margin sediments. However, the uppermost units of the Estância and Vaza Barris domains come from foreland basins formed during collision of Borborema plate with the São Francisco Craton.

  1. Depositional ages of clastic metasediments from Samos and Syros, Greece: results of a detrital zircon study

    NASA Astrophysics Data System (ADS)

    Löwen, Kersten; Bröcker, Michael; Berndt, Jasper

    2015-01-01

    Siliciclastic metasediments from the islands of Samos and Syros, Cycladic blueschist unit, Greece, were studied to determine maximum sedimentation ages. Four samples from the Ampelos unit on Samos yielded age distribution spectra that range from ~320 Ma to ~3.2 Ga with a dominance of Cambrian-Neoproterozoic zircons (500-1,100 Ma). The youngest well-constrained age groups cluster at 500-550 Ma. Our results allow to link the Samos metasediments with occurrences showing similar age distribution patterns elsewhere in the eastern Mediterranean region (Greece, Turkey, Libya, Israel and Jordan) that record the influx of `Pan-African' detritus. The lack of post-500-Ma zircons in the Samos samples is in marked contrast to the data from Syros that indicates Triassic to Cretaceous depositional ages. The samples from Syros were collected from the matrix of a meta-ophiolitic mélange that is exposed near the top of the metamorphic succession as well as from outcrops representing the basal part of the underlying marble-schist sequence. The zircon populations from Syros were mainly supplied by Mesozoic sources dominated by Triassic protolith ages. Subordinate is the importance of pre-Triassic zircons, but this may reflect bias induced by the research strategy. Sediment accumulation continued until Late Cretaceous time, but the overall contribution of Jurassic to Cretaceous detritus is more limited. Zircon populations are dominated by grains with small degree of rounding suggesting relatively short sediment transportation. Available observations are in accordance with a model suggesting deposition close to the magmatic source rocks.

  2. Constraints on mountain building in the northeastern Tibet: Detrital zircon records from synorogenic deposits in the Yumen Basin

    NASA Astrophysics Data System (ADS)

    Wang, Weitao; Zhang, Peizhen; Yu, Jingxing; Wang, Yizhou; Zheng, Dewen; Zheng, Wenjun; Zhang, Huiping; Pang, Jianzhang

    2016-06-01

    The Cenozoic basins and ranges form the high topography of the northeastern Tibet that resulted from the India-Eurasia collision. Sedimentary rocks in the basins provide direct insight into the exhumation history of the ranges and the tectonic processes that led to the northeastward growth of the Tibetan Plateau. In this study, we analyzed and compared detrital zircon U-Pb ages from sands of modern rivers draining the Bei Shan, and North Qilian Shan and sandstones from the Yumen Basin. The zircon age distributions indicate that the strata dated to 24.2-16.7 Ma in the basin were derived from the Bei Shan, and the basin provenance changed rapidly to the North Qilian Shan terrane at ~16 Ma. These results suggest that an early stage of deformation along the Bei Shan at ~24 Ma was replaced by the growth of the North Qilian Shan at ~16 Ma. We conclude that the far-field effect associated with the Indo-Asian collision may result from Oligocene deformation in the Bei Shan, but the emergence of the North Qilian Shan at ~16 Ma could reflect the most recent outward growth of the Tibetan Plateau that may have been caused by the removal of some lithospheric mantle beneath central Tibet.

  3. Elemental and Isotopic Tomography at Single-Atom-Scale in 4.0 and 2.4 Ga Zircons

    NASA Astrophysics Data System (ADS)

    Valley, J. W.; Reinhard, D. A.; Snoeyenbos, D.; Lawrence, D.; Martin, I.; Kelly, T. F.; Ushikubo, T.; Strickland, A.; Cavosie, A. J.

    2012-12-01

    Atom probe tomography can determine identity (mass/charge ratio) and 3-D position of individual atoms in minerals such as zircon. These data provide unique information for understanding the thermal history and mechanisms of mineral reaction and exchange, including radiation damage. Nine needle-shaped specimens ~100 nm in diameter (at the apex) were sampled from 2 zircons by FIB and analyzed with a local-electrode atom probe (LEAP), CAMECA LEAP 4000X HR. The LEAP uses pulsed-laser heating to field evaporate the tip of a zircon needle and accelerates the ions into a position-sensitive TOF-MS. With due care for complex isobaric interferences (molecules, multiple ionizations) and background correction, it is possible to individually identify up to 10E8 atoms/needle (36% detection efficiency) by mass/charge (MRP ~ 1000@ m/n=16Da) and position (X-Y-Z coordinates on 0.2 nm scale) (Kelly & Larson 2012). The 3-D distribution of Pb and Y differ at atom-scale in the 2 zircons. Zircon #1 (4007 Ma, Jack Hills, W. Australia, Cavosie 2005, Ushikubo et al. 2008, Bouvier et al. 2011) is homogeneous in Pb and Y. In contrast, incompatible elements, including Pb and Y, are concentrated in equant 5-10 nm dia. domains, spaced ~50 nm apart in zircon #2 (2438 Ma, Albion-Raft R-Grouse Ck core complex, Utah, Strickland et al. 2011). U is homogeneously distributed in both zircons. The analyzed domains suffered 4-8 x 10E15 α-decay events/mg due to U and Th decay and yet both zircons yield >97% concordant U-Pb ages by SIMS, suggesting annealing of radiation damage during the life of the zircons. The 207-Pb/206-Pb ratios for these nm-scale domains, as measured by LEAP, average 0.17 for the 2.4 Ga Zrc2 (3 needles) and 0.43 for the 4.0 Ga Zrc1 (5 needles). These ratios are less precise (±40% 2σ) due to ultra-small sample size, but are in excellent agreement with values measured by SIMS, 0.1684 and 0.4269, respectively. Thus Pb in both zircons is radiogenic. The Pb-Y-rich domains and lack of

  4. Palynology and detrital zircon geochronology of the Carboniferous Fenestella Shale Formation of the Tethyan realm in Kashmir Himalaya: Implications for global correlation and floristic evolution

    NASA Astrophysics Data System (ADS)

    Agnihotri, Deepa; Pandita, Sundeep K.; Tewari, Rajni; Ram-Awatar; Linnemann, Ulf; Pillai, S. Suresh K.; Joshi, Arun; Gautam, Saurabh; Kumar, Kamlesh

    2018-05-01

    First palynological data, supplemented by detrital zircon U-Pb ages, from the Fenestella Shale Formation near the Gund Village in the Banihal area of Jammu and Kashmir State, India, provide new insights into the floristic evolution of Gondwana during the Late Palaeozoic, especially in India, from where the Carboniferous-Permian macro- and microfloral records are impoverished. We also present a first approach to the palynological correlation of the Carboniferous-Permian palynoassemblages described from the various Gondwana countries. The palynomorphs from the Fenestella Shale Formation are fairly well preserved and diversified and include 11 genera and 18 species. While the trilete spores and striate bisaccate pollen grains are scarce, monosaccate pollen taxa mainly - Parasaccites, Plicatipollenites and Potonieisporites are dominant. The assemblage is most similar to the Parasaccites korbaensis palynozone of the Lower Gondwana basins of the Indian peninsula and the Stage 2 palynozone of the late Carboniferous of east Australia. Besides, it is comparable with the known Carboniferous assemblages of Pakistan, Yemen and South America; Carboniferous-early Permian assemblages of South Africa and Permian assemblages of Antarctica. The sediment source of the siliciclastic shelf and delta deposits intercalated in the Fenestella Shale Formation is a hinterland in which Precambrian rocks dominantly were exposed and the Th-U ratios of detrital zircons suggest, that most rocks exposed on the erosion level in the hinterland had a felsic composition. The youngest U-Pb zircon age of the investigated fossiliferous strata is 329 ± 16 Ma (late Visean to early Serpukhovian), providing a maximum age of deposition of the studied succession. Based on the affinities of the palynofloral assemblage and earlier palaeontological records, a warm, temperate and arid climate has been inferred for the Fenestella Shale Formation.

  5. Detrital zircon age and isotopic constraints on the provenance of turbidites from the southernmost part of the Beishan orogen, NW China

    NASA Astrophysics Data System (ADS)

    Guo, Q. Q.; Chung, S. L.; Lee, H. Y.; Xiao, W.; Hou, Q.; Li, S.

    2017-12-01

    The Altaids in Central and East Asia is one of the largest accretionary orogenic collages in the world. The Beishan orogen, linked the Tianshan and Xingmeng orogens, occupy a key position to trace the terminal processes of the Altaids. It comprises an assemblage of magmatic arcs and ophiolitic mélanges. The Permian clastic turbidites, situated between the Huaniushan arc and the Shibanshan arc, are the youngest reported deep-marine clasts in the Beishan orogen. They are separated into the Liuyuan turbidites (NT) to the north and the Heishankou turbidites (ST) to the south by the Liuyuan complex. Detrital zircon grains from the NT yielded a wide range, from 254-3111 Ma, with two age clusters at 273 Ma and 424 Ma, indicating they provenance from the Huaniushan arc to the north. Those from the ST yielded ages from 260-2209 Ma, with age clusters at 270 Ma, 295 Ma, 420 Ma and 878 Ma, indicating the provenance from the Shibanshan arc to the south. The youngest three grains from the NT yield a weighted mean age of 260 Ma and those from the ST an age of 255 Ma, indicating an End-Permian maximum depositional age. The Precambrian zircons of the NT have diverse ɛHf(t) values (-12.6 to +10.4), while those of the ST from -6 to -2.6, indicating distinguishing histories of their provenances. The NT have more positive ɛNd(t) values than the ST, suggesting more juvenile or less evolved crustal components in the source. Two contrasting provenances, together with data in the literature, define the latest suture in the Beishan region at 240-250 Ma. The younger peak of U-Pb analysis results of detrital zircons from the northern part of the final suture zone in the southern Altaids is younging eastward from 288 Ma to 247 Ma, which may characterize the closure of the Paleo-Asian Ocean from west to east in about 40 Ma. This identification of the latest suture in the southern Altaids provides new constraints on the Paleo-Asian Ocean - specifically the nature and timing of the end of the

  6. U-Pb SHRIMP-RG zircon ages and Nd signature of lower Paleozoic rifting-related magmatism in the Variscan basement of the Eastern Pyrenees

    USGS Publications Warehouse

    Martinez, F.J.; Iriondo, A.; Dietsch, C.; Aleinikoff, J.N.; Peucat, J.J.; Cires, J.; Reche, J.; Capdevila, R.

    2011-01-01

    The ages of orthogneisses exposed in massifs of the Variscan chain can determine whether they are part of a pre-Neoproterozoic basement, a Neoproterozoic, Panafrican arc, or are, in fact, lower Paleozoic, and their isotopic compositions can be used to probe the nature of their source rocks, adding to the understanding of the types, distribution, and tectonic evolution of peri-Gondwanan crystalline basement. Using SHRIMP U-Pb zircon geochronology and Nd isotopic analysis, pre-Variscan metaigneous rocks from the N??ria massif in the Eastern Pyrenean axial zone and the Guilleries massif, 70km to the south, have been dated and their Nd signatures characterized. All dated orthogneisses from the N??ria massif have the same age within error, ~457Ma, including the Ribes granophyre, interpreted as a subvolcanic unit within Caradocian sediments contemporaneous with granitic magmas intruded into Cambro-Ordovician sediments at deeper levels. Orthogneisses in the Guilleries massif record essentially continuous magmatic activity during the Ordovician, beginning at the Cambro-Ordovician boundary (488??3Ma) and reaching a peak in the volume of magma in the early Late Ordovician (~460Ma). Metavolcanic rocks in the Guilleries massif were extruded at 452??4Ma and appear to have their intrusive equivalent in thin, deformed veins of granitic gneiss (451??7Ma) within metasedimentary rocks. In orthogneisses from both massifs, the cores of some zircons yield Neoproterozoic ages between ~520 and 900Ma. The age of deposition of a pre-Late Ordovician metapelite in the Guilleries massif is bracketed by the weighted average age of the youngest detrital zircon population, 582??11Ma, and the age of cross-cutting granitic veins, 451??7Ma. Older detrital zircons populations in this metapelite include Neoproterozoic (749-610Ma; n=10), Neo- to Mesoproterozoic (1.04-0.86Ga; n=7), Paleoproterozoic (2.02-1.59Ga; n=5), and Neoarchean (2.74-2.58Ga; n=3). Nd isotopic analyses of the N??ria and Guilleries

  7. U-Pb ages of detrital zircon from Cenozoic sediments in the southwestern Tarim Basin, NW China: Implications for Eocene-Pliocene source-to-sink relations and new insights into Cretaceous-Paleogene magmatic sources

    NASA Astrophysics Data System (ADS)

    Yang, Wei; Fu, Ling; Wu, Chaodong; Song, Yan; Jiang, Zhenxue; Luo, Qun; Zhang, Ziya; Zhang, Chen; Zhu, Bei

    2018-05-01

    A detailed investigation of potential provenance is still lacking in the southwestern Tarim Basin, which restricts our complete understanding of Cenozoic source-to-sink relations between the basin interior and the Pamir salient - western Kunlun Mountain Range. Debate also exists concerning the potential sources of the Paleogene and Cretaceous igneous detritus present in the Cenozoic sedimentary sequences. Here, we present U-Pb (LA-ICP-MS) ages of detrital zircons from the continuous Eocene-Pliocene sediment series in the well-exposed Aertashi section to investigate changes in sediment provenance through time. The U-Pb detrital zircon ages range widely from 45 to 3204 Ma and can be divided into seven main groups: 45-65 Ma (sub-peak at 49 Ma), 67-103 Ma (sub-peak at 95 Ma), 196-251 Ma (sub-peak at 208 Ma), 252-416 Ma (sub-peak at 296 Ma), 417-540 Ma (sub-peak at 446 Ma), 550-1429 Ma (sub-peaks at 614 Ma, 828 Ma and 942 Ma) and 1345-3204 Ma (sub-peaks at 1773 Ma and 2480 Ma). These zircons were mainly derived from the western Kunlun Mountain Range and northern Pamir salient to the west and south. The evolution of the provenance and source-to-sink relationship patterns in the southwestern Tarim Basin can be divided into three stages: (1) The Middle Eocene to Lower Oligocene sediments display a wide variety of detrital zircon ages, suggesting that the source area was extensive. (2) A major change in provenance occurred during the Late Oligocene to Early Miocene and was characterized by an abrupt increase in the proportion of Triassic and Lower Paleozoic igneous components, implying a significant adjustment in topography induced by the initial uplift and exhumation of the western Kunlun Mountain Range and northern Pamir salient. (3) In the Late Miocene, the source-to-sink system transformed again, and contributions of Triassic to Lower Paleozoic material weakened substantially due to the sufficient indentation of the Pamir salient. Our integrated analyses of zircon

  8. Detrital zircon provenance of the Late Triassic Songpan-Ganzi complex: Sedimentary record of collision of the North and South China blocks

    USGS Publications Warehouse

    Weislogel, A.L.; Graham, S.A.; Chang, E.Z.; Wooden, J.L.; Gehrels, G.E.; Yang, H.

    2006-01-01

    Using detrital zircon geochronology, turbidite deposystems fed from distinct sediment sources can be distinguished within the Songpan-Ganzi complex, a collapsed Middle to Late Triassic turbidite basin of central China. A southern Songpan-Ganzi deposystem initially was sourced solely by erosion of the Qinling-Dabie orogen during early Late Triassic time, then by Qinling-Dabie orogen, North China block, and South China block sources during middle to late Late Triassic time. A northern Songpan-Ganzi system was sourced by erosion of the Qinling-Dabie orogen and the North China block throughout its deposition. These separate deposystems were later tectonically amalgamated to form one complex and then uplifted as the eastern Tibet Plateau. ?? 2006 Geological Society of America.

  9. Assessing the role of detrital zircon sorting on provenance interpretations in an ancient fluvial system using paleohydraulics - Permian Cutler Group, Paradox Basin, Utah and Colorado

    NASA Astrophysics Data System (ADS)

    Findlay, C. P., III; Ewing, R. C.; Perez, N. D.

    2017-12-01

    Detrital zircon age signatures used in provenance studies are assumed to be representative of entire catchments from which the sediment was derived, but the extent to which hydraulic sorting can bias provenance interpretations is poorly constrained. Sediment and mineral sorting occurs with changes in hydraulic conditions driven by both allogenic and autogenic processes. Zircon is sorted from less dense minerals due to the difference in density, and any age dependence on zircon size could potentially bias provenance interpretations. In this study, a coupled paleohydraulic and geochemical provenance approach is used to identify changes in paleohydraulic conditions and relate them to spatial variations in provenance signatures from samples collected along an approximately time-correlative source-to-sink pathway in the Permian Cutler Group of the Paradox Basin. Samples proximal to the uplift have a paleoflow direction to the southwest. In the medial basin, paleocurrent direction indicates salt movement caused fluvial pathways divert to the north and northwest on the flanks of anticlines. Channel depth, flow velocity, and discharge calculations were derived from field measurements of grain size and dune and bar cross-stratification indicate that competency of the fluvial system decreased from proximal to the medial basin by up to a factor of 12. Based upon the paleohydraulic calculations, zircon size fractionation would occur along the transect such that the larger zircons are removed from the system prior to reaching the medial basin. Analysis of the size and age distribution of zircons from the proximal and distal fluvial system of the Cutler Group tests if this hydraulic sorting affects the expected Uncompahgre Uplift age distribution.

  10. The Paleogene California River: Evidence of Mojave-Uinta paleodrainage from U-Pb ages of detrital zircons

    USGS Publications Warehouse

    Davis, S.J.; Dickinson, W.R.; Gehrels, G.E.; Spencer, J.E.; Lawton, T.F.; Carroll, A.R.

    2010-01-01

    U-Pb age spectra of detrital zircons in samples from the Paleogene Colton Formation in the Uinta Basin of northeastern Utah and the Late Cretaceous McCoy Mountains Formation of southwestern Arizona (United States) are statistically indistinguishable. This finding refutes previous inferences that arkosic detritus of the Colton was derived from cratonic basement exposed by Laramide tectonism, and instead establishes the Cordilleran magmatic arc (which also provided sediment to the McCoy Mountains Formation) as the primary source. Given the existence of a north-south-trending drainage divide in eastern Nevada and the north-northeast direction of Laramide paleoflow throughout Arizona and southern Utah, we infer that a large river system headed in the arc of the Mojave region flowed northeast ~700 km to the Uinta Basin. Named after its source area, this Paleogene California River would have been equal in scale but opposite in direction to the modern Green River-Colorado River system, and the timing and causes of the subsequent drainage reversal are important constraints on the tectonic evolution of the Cordillera and the Colorado Plateau. ?? 2010 Geological Society of America.

  11. Tracing source terranes using U-Pb-Hf isotopic analysis of detrital zircons: provenance of the Orhanlar Unit of the Palaeotethyan Karakaya subduction-accretion complex, NW Turkey

    NASA Astrophysics Data System (ADS)

    Ustaömer, Timur; Ayda Ustaömer, Petek; Robertson, Alastair; Gerdes, Axel

    2016-04-01

    Sandstones of the Late Palaeozoic-Early Mesozoic Karakaya Complex are interpreted to have accumulated along an active continental margin related to northward subduction of Palaeotethys. The age of deposition and provenance of the sandstones are currently being determined using radiometric dating of detrital zircons, coupled with dating of potential source terranes. Our previous work shows that the U-Pb-Hf isotopic characteristics of the sandstones of all but one of the main tectonostratigraphic units of the Karakaya Complex are compatible with a provenance that was dominated by Triassic and Permo-Carboniferous magmatic arc-type rocks, together with a minor contribution from Lower to Mid-Devonian igneous rocks (Ustaömer et al. 2015). However, one of the tectono-stratigraphic units, the Orhanlar Unit, which occurs in a structurally high position, differs in sedimentary facies and composition from the other units of the Karakaya Complex. Here, we report new isotopic age data for the sandstones of the Orhanlar Unit and also from an extensive, associated tectonic slice of continental metamorphic rocks (part of the regional Sakarya Terrane). Our main aim is to assess the provenance of the Orhanlar Unit sandstones in relation to the tectonic development of the Karakaya Complex as a whole. The Orhanlar Unit is composed of shales, sandstone turbidites and debris-flow deposits, which include blocks of Devonian radiolarian chert and Carboniferous and Permian neritic limestones. The sandstones are dominated by rock fragments, principally volcanic and plutonic rocks of basic-to-intermediate composition, metamorphic rocks and chert, together with common quartz, feldspar and mica. This modal composition contrasts significantly with the dominantly arkosic composition of the other Karakaya Complex sandstones. The detrital zircons were dated by the U-Pb method, coupled with determination of Lu-Hf isotopic compositions using a laser ablation microprobe attached to a multicollector

  12. U-Pb detrital zircon dates and provenance data from the Beaufort Group (Karoo Supergroup) reflect sedimentary recycling and air-fall tuff deposition in the Permo-Triassic Karoo foreland basin

    NASA Astrophysics Data System (ADS)

    Viglietti, Pia A.; Frei, Dirk; Rubidge, Bruce S.; Smith, Roger M. H.

    2018-07-01

    Detrital zircon U-Pb age dating was used for provenance determination and maximum age of deposition for the Upper Permian (upper Teekloof and Balfour formations) and Lower Triassic (Katberg Formation) lithostratigraphic subdivisions of the Beaufort Group of South Africa's Karoo Basin. Ten samples were analysed using laser ablation - single collector - magnetic sectorfield - inductively coupled plasma - mass spectrometry (LA-SF-ICP-MS). The results reveal a dominant Late Carboniferous-Late Permian population (250 ± 5 Ma - 339 ± 5 Ma), a secondary Cambrian-Neoproterozoic (489 ± 5 Ma to 878 ± 24 Ma) population, a minor Mesoproterozoic (908 ± 24 Ma to 1308 ± 23) population, and minor occurrences of Devonian, Ordovician, Proterozoic and Archean zircon grains. Multiple lines of evidence (e.g. roundness and fragmentary nature of zircons, palaeo-current directions, and previous work), suggest the older zircon populations are related to sedimentary recycling in the Gondwanide Orogeny. The youngest and dominant population contain elongate euhedral grains interpreted to be directly derived from their protolith. Since zircons form in felsic igneous rocks, and no igneous rocks of Late Permian age occur in the Karoo Basin, these findings suggest significant input of volcanic material by ash falls. These results support sedimentological and palaeontological data for a Lopingian (Late Permian) age for the upper Beaufort Group, but contradict previous workers who retrieved Early Triassic dates from zircons in ashes for the Beaufort and Ecca Groups. Pb-loss not revealed by resolvable discordance on the concordia diagram, and metamictization of natural zircons are not factored into the conclusions of earlier workers.

  13. Enhanced provenance interpretation using combined U-Pb and (U-Th)/He double dating of detrital zircon grains from lower Miocene strata, proximal Gulf of Mexico Basin, North America

    NASA Astrophysics Data System (ADS)

    Xu, Jie; Stockli, Daniel F.; Snedden, John W.

    2017-10-01

    Detrital zircon U-Pb analysis is an effective approach for investigating sediment provenance by relating crystallization age to potential crystalline source terranes. Studies of large passive margin basins, such as the Gulf of Mexico Basin, that have received sediment from multiple terranes with non-unique crystallization ages or sedimentary strata, benefit from additional constraints to better elucidate provenance interpretation. In this study, U-Pb and (U-Th)/He double dating analyses on single zircons from the lower Miocene sandstones in the northern Gulf of Mexico Basin reveal a detailed history of sediment source evolution. U-Pb age data indicate that most zircon originated from five major crystalline provinces, including the Western Cordillera Arc (<250 Ma), the Appalachian-Ouachita orogen (500-260 Ma), the Grenville (1300-950 Ma) orogen, the Mid-Continent Granite-Rhyolite (1500-1300 Ma), and the Yavapai-Mazatzal (1800-1600 Ma) terranes as well as sparse Pan-African (700-500 Ma) and Canadian Shield (>1800 Ma) terranes. Zircon (U-Th)/He ages record tectonic cooling and exhumation in the U.S. since the Mesoproterozoic related to the Grenville to Laramide Orogenies. The combined crystallization and cooling information from single zircon double dating can differentiate volcanic and plutonic zircons. Importantly, the U-Pb-He double dating approach allows for the differentiation between multiple possible crystallization-age sources on the basis of their subsequent tectonic evolution. In particular, for Grenville zircons that are present in all of lower Miocene samples, four distinct zircon U-Pb-He age combinations are recognizable that can be traced back to four different possible sources. The integrated U-Pb and (U-Th)/He data eliminate some ambiguities and improves the provenance interpretation for the lower Miocene strata in the northern Gulf of Mexico Basin and illustrate the applicability of this approach for other large-scale basins to reconstruct sediment

  14. Geological Evidence That Resolves the Baja-BC Controversy: Detrital Zircons Indicate That Vancouver Island Was Adjacent to Southern California in the Late Cretaceous

    NASA Astrophysics Data System (ADS)

    Guest, B.; Matthews, W.; Coutts, D. S.; Bain, H.; Hubbard, S. M.

    2015-12-01

    The Baja-BC hypothesis is at the center of a great earth sciences controversy. It stems from paleomagnetic observations that require large-scale displacements of continental crust from low latitudes (Baja, California) to moderate latitudes (British Columbia). Many geologists dispute the scale of the displacements due to a lack of corroborating geological evidence. We provide a robust, geological dataset that confirms the paleomagnetic observations. Detrital zircons from Cretaceous to Paleocene sandstone of the Nanaimo Group, which crops out in western Vancouver Island and the Gulf Islands of southwest British Columbia, are analyzed. The data show a clear transition from local <300 Ma western Coast Plutonic Complex sources in the Campanian, to sources that include a significant component of >300 Ma grains in the Maastrichtian-Paleogene. An identical pattern is observed in detrital zircon datasets from southern California forearc basin deposits, and schists interpreted as the subducted remnants of forearc deposits. With a high-n dataset (n=3041) we are able to rule out possible >300 Ma source regions in Canada and the northern United States, and uniquely tie Nanaimo Group rocks to the Mojave-Sonora region of SW United States. This implies that at the end of the Cretaceous, Vancouver Island and western mainland BC were adjacent to southern California and northwestern Mexico, requiring 1900 km of displacement during the latest Cretaceous and Paleocene, consistent with paleomagnetic results. An implication of this result is that the western Coast Batholith of southwest BC was positioned between the northern Peninsular Ranges and southern Sierra Nevada batholiths in the late Cretaceous, and likely represents a displaced segment of a once continuous Cordilleran arc batholith. These results have broad implications for our understanding of episodic arc magmatism in the Cordillera, the tectonic evolution of western North America, Laramide orogenesis, the development and

  15. Extinct 244Pu in ancient zircons.

    PubMed

    Turner, Grenville; Harrison, T Mark; Holland, Greg; Mojzsis, Stephen J; Gilmour, Jamie

    2004-10-01

    We have found evidence, in the form of fissiogenic xenon isotopes, for in situ decay of 244Pu in individual 4.1- to 4.2-billion-year-old zircons from the Jack Hills region of Western Australia. Because of its short half-life, 82 million years, 244Pu was extinct within 600 million years of Earth's formation. Detrital zircons are the only known relics to have survived from this period, and a study of their Pu geochemistry will allow us to date ancient metamorphic events and determine the terrestrial Pu/U ratio for comparison with the solar ratio.

  16. Extended history of a 3.5 Ga trondhjemitic gneiss, Wyoming Province, USA: Evidence from U-Pb systematics in zircon

    USGS Publications Warehouse

    Mueller, P.A.; Wooden, J.L.; Mogk, D.W.; Nutman, A.P.; Williams, I.S.

    1996-01-01

    The Beartooth-Bighorn magmatic zone (BBMZ) and the Montana metasedimentary province (MMP) are two major subprovinces of the Archean Wyoming province. In the northwestern Beartooth Mountains, these subprovinces are separated by a structurally, lithologically and metamorphically complex assemblage of lithotectonic units that include: (1) a strongly deformed complex of trondhjemitic gneiss and interlayered amphibolites; and (2) an amphibolite facies mafic unit that occurs in a nappe that structurally overlies the gneiss complex. Zircons from a trondhjemitic blastomylonite in the gneiss complex yield concordant U-Pb ages of 3.5 Ga, establishing it as the oldest rock yet documented in the Wyoming province. Two younger events are also recorded by zircons in this rock: (1) an apparently protracted period of high-grade metamorphism and/or intrusion of additional magmas at ??? 3.25 Ga; and (2) growth of hydrothermal zircon at ??? 2.55 Ga, apparently associated with ductile deformation that immediately preceded structural emplacement of the gneiss. Although this latter event appears confined to areas along the BBMZ-MMP boundary, evidence of ??? 3.25 Ga igneous activity is found in the overlying amphibolite (3.24 Ga) and throughout the MMP. These data suggest that this boundary first developed as a major intracratonic zone of displacement at or before 3.25 Ga. The limited occurrences of 2.8 Ga magmatic activity in the MMP suggest that it had a controlling influence on late Archean magmatism as well.

  17. Lower Paleozoic Through Archean Detrital Zircon Ages From Metasedimentary Rocks of the Nome Group, Seward Peninsula, Alaska

    NASA Astrophysics Data System (ADS)

    Amato, J. M.; Miller, E. L.; Gehrels, G.

    2003-12-01

    Metamorphic rocks of Seward Peninsula have been divided into two groups based on their metamorphic grade and history: The Nome Group and the Kigluaik Group. Although it is sometime been assumed that the higher structural position of the Nome Group versus the Kigluaik Group indicates the Kigluaik Group is older, this relationship and the age of the protoliths of these rocks has never been well-established. The Nome Group includes (delete the) lower grade blueschist and greenschist facies rocks which are widespread across the Seward Peninsula (delete) Rock types include pelitic schist, more mafic chlorite-white mica-albite schist, marble, quartzite, and metabasite. An early metamorphic event (pre-120 Ma) occurred at high pressure and relatively low temperature, and is everywhere overprinted by younger deformation and greenschist facies Rare eclogite facies assemblages are preserved in metabasites, and garnet-glaucophane in some of the pelitic schists. The Kigluaik Group includes upper greenschist to granulite facies rocks that are exposed in the core of a gneiss dome. They record a younger event (~91 Ma) that occurred at higher temperatures and resulted in partial thermal overprinting of the Nome Group and upper greenschist to granulite facies assemblages forming in the Kigluaik Group. The Kigluaik Group and equivalent rocks in the Bendeleben and Darby Mountains represent at least in part similar protoliths to many of the units in the Nome Group (Till and Dumoulin, 1994). The boundary between the rocks of the Nome Group and those clearly affected by the second metamorphic event is placed arbitrarily at the "Biotite-in" isograd along the flanks of the gneiss dome. In order to assess the protolith ages and source rock ages for these units, detrital zircon ages were obtained from three samples from the Nome Group, with Kigluaik Group ages forthcoming. LA-MC-ICPMS U/Pb isotope analysis was used for dating. Two samples were collected from the western Kigluaik Mountains

  18. Reassessment of Paleo- and Mesoproterozoic basin sediments of Arizona: Implications for tectonic growth of southern Laurentia and global tectonic configurations

    NASA Astrophysics Data System (ADS)

    Doe, Michael Frederick

    Proterozoic crustal provinces that underlie much of the United States record prolonged southward growth of the North American craton (Laurentia) between ca. 1.8 and 1.0 Ga. Exposures throughout central Arizona's Tonto Basin represent multiple generations of sedimentary basins formed during Proterozoic accretion. Metasedimentary rocks sampled across Tonto Basin resulted have identified remnants of a previously undated but potentially widespread Mesoproterozoic basin called the Yankee Joe Basin. Sediments of Yankee Joe Basin are particularly interesting because they have depositional age's ca. 200 m.y. younger than previously thought and because they are rich in detrital zircons with ages between 1.6-1.48 Ga, a time period not widely represented in the igneous record of Laurentia. Metasedimentary rocks with similar age and provenance are found in northern New Mexico and in the lower parts of the Belt Supergroup in northern Idaho, Montana, and Canada. Zircon ages and Hf isotopic characteristics suggest the distinctive 1.6-1.48 Ga grains might have been derived from non-Laurentian sources, most likely one or more formerly adjacent cratons such as north Australia. Circa 1.48-1.43 Ga units in the Yankee Joe Basin rest disconformably on Paleoproterozoic quartzite, and all were deformed together during northwest-directed foreland-style thrusting. This event was previously interpreted to represent the ca. 1.66-1.60 Ga Mazatzal orogeny. However, new findings challenge this view and suggest a major deformation event occurred ca. 1.47-1.45 Ga, possibly representing the Picuris orogeny as recently described in northern New Mexico. Regional thrust faulting during the Mesoproterozoic might have unroofed and removed significant portions of the Yankee Joe section, potentially shedding detritus north from the thrust front into the upper parts of the Belt-Purcell basin. Detrital zircon ages and hafnium isotope compositions provide a critical test of sediment provenance and

  19. Detrital Zircon U-Pb Analysis of the Liuqu Conglomerate Along the Yarlung-Zangbo Suture Zone, and Implications for the Mode and Timing of Collision Tectonics in Southern Tibet

    NASA Astrophysics Data System (ADS)

    Xie, Y.; Dilek, Y.

    2016-12-01

    The Liuqu Conglomerate (LQC) along the Yarlung-Zangbo suture zone (YZSZ) in Southern Tibet is a terrestrial deposit that provides significant spatial and temporal constraints for the timing and nature of collisional events in the tectonic evolution of the Tibetan-Himalayan orogenic belt. The 10-km-wide (N-S) LQC is exposed discontinuously for more than 1000 km in an E-W direction, and is tectonically overlain to the north by the Cretaceous Neotethyan oceanic lithosphere along a S-vergent thrust fault system and to the south by Triassic-Jurassic metamorphosed sedimentary-volcanic rocks of the Tethyan Himalaya along N-vergent reverse-thrust faults. The major facies of the LQC are the matrix-supported to clast-supported conglomerates. The matrix is poorly to moderate sorted red quartz sandstone, mudstone and sub-rounded pebble to cobble-sized clasts. The clast lithology present in central and southern parts includes dark red sandstone, siltstone and mudstone greyish-green shale, grey phyllite and slate with their provenance in the Triassic Tethyan Himalaya to the south. The clastic material making up its stratigraphy in the northern part of the LQC includes quartz sandstone, radiolarian chert, minor dolerite, gabbro and peridotite derived from the Cretaceous ophiolite. Here we report in-situ detrital zircon U-Pb age analysis of sandstone from the LQC near Liuqu area. 163 concordant U-Pb ages obtained from sample 22-LQ-15, 27-LQ-15 and 35-LQ-15 show the youngest age is 307±13 Ma with discordance of -17.02%, and the oldest zircon grain is 3362 ±51 Ma with discordance of 2.63%. Statistically, the age spectrum of these zircons from the three sandstone samples display a prominent peak centred in 935 Ma, a large peak around 516 Ma, and two small clusters around 2429 Ma and 2772 Ma. The zircon U-Pb results provide evidence of age clusters of the sandstone in LQC are consistent with the detrital U-Pb age signature of the sandstone in Tethyan Himalaya. Thus, the sediments in

  20. Maximum depositional ages and evolving provenance of Franciscan metagraywackes, NW California: LA-ICPMS zircon U-Pb data

    NASA Astrophysics Data System (ADS)

    Ernst, W. G.; Dumitru, T. A.; Tsujimori, T.; McLaughlin, R. J.; Makishima, A.; Nakamura, E.

    2012-12-01

    In the Cape Mendocino-Garberville-Covelo area, the Franciscan Complex comprises an imbricate stack of east-rooting allochthons. Five structurally higher to lower thrust sheets crop out from east to west: Eastern Belt outliers; Central Belt mélange; Coastal Belt Yager terrane; Coastal Belt Coastal terrane; and Coastal Belt King Range/False Cape terranes. We analyzed detrital zircons from 11 rocks: 2 Eastern Belt; 5 Central Belt; 4 King Range/False Cape terrane. Combined with earlier analyses of 3 Yager terrane and 3 Coastal terrane zircon suites (Dumitru et al., in review), 17 rocks were investigated. Maximum ages of sedimentation and inferred ultimate sources of these units as follows. Eastern Belt (Yolla Bolly): 98-120 Ma Sierran batholith, 140- 230 Ma Andean arc, minor 1300-1400 Ma Mazatzal granites, minor 1800 Ma Yavapai basement, trace >2.5 Ga Archean craton. Central Belt: minor 62-80 Ma Idaho batholith, 85-200 Ma Sierran batholith-Andean arc, 1300-1400 Ma Mazatzal granites, minor 1600-1750 Ma Mazatzal-Yavapai basement. Yager terrane: 50-75 Ma Idaho batholith, 85-120 Ma Sierran batholith, minor 160-200 Ma Andean arc. Coastal terrane: 30-50 Ma, Cascade + Challis volcanics, 55-80 Ma Idaho batholith, 100 Ma Sierran batholith, 1300-1400 Ma, Mazatzal granites. King Range/False Cape terrane: 22-50 Ma Cascade + Challis Idaho batholith, 100-180 Ma Sierran batholith-Andean arc, minor 1400 Ma Mazatzal-Yavapai granites. Depositional ages of Franciscan imbricate thrust sheets young westward from the mid Cretaceous Eastern Belt through the end-of-Cretaceous Central Belt, to the Paleogene Coastal Belt. Over time, the Franciscan received greater proportions of younger clastics derived from more northerly sources. Although mostly arc-derived, some recycled 1400 and 1700-1800 Ma ± 2.5 Ga arc zircons probably were supplied to the Franciscan Complex by erosion and westward transport of detrital grains from Lower Paleozoic miogeoclinal strata covering the cratonal edge. Except

  1. Detrital and volcanic zircon U-Pb ages from southern Mendoza (Argentina): An insight on the source regions in the northern part of the Neuquén Basin

    NASA Astrophysics Data System (ADS)

    Naipauer, Maximiliano; Tapia, Felipe; Mescua, José; Farías, Marcelo; Pimentel, Marcio M.; Ramos, Victor A.

    2015-12-01

    The infill of the Neuquén Basin recorded the Meso-Cenozoic geological and tectonic evolution of the southern Central Andes being an excellent site to investigate how the pattern of detrital zircon ages varies trough time. In this work we analyze the U-Pb (LA-MC-ICP-MS) zircon ages from sedimentary and volcanic rocks related to synrift and retroarc stages of the northern part of the Neuquén Basin. These data define the crystallization age of the synrift volcanism at 223 ± 2 Ma (Cerro Negro Andesite) and the maximum depositional age of the original synrift sediments at ca. 204 Ma (El Freno Formation). Two different pulses of rifting could be recognized according to the absolute ages, the oldest developed during the Norian and the younger during the Rhaetian-Sinemurian. The source regions of the El Freno Formation show that the Choiyoi magmatic province was the main source rock of sediment supply. An important amount of detrital zircons with Triassic ages was identified and interpreted as a source area related to the synrift magmatism. The maximum depositional age calculated for the Tordillo Formation in the Atuel-La Valenciana depocenter is at ca. 149 Ma; as well as in other places of the Neuquén Basin, the U-Pb ages calculated in the Late Jurassic Tordillo Formation do not agree with the absolute age of the Kimmeridgian-Tithonian boundary (ca. 152 Ma). The main source region of sediment in the Tordillo Formation was the Andean magmatic arc. Basement regions were also present with age peaks at the Carboniferous, Neoproterozoic, and Mesoproterozoic; these regions were probably located to the east in the San Rafael Block. The pattern of zircon ages summarized for the Late Jurassic Tordillo and Lagunillas formations were interpreted as a record of the magmatic activity during the Triassic and Jurassic in the southern Central Andes. A waning of the magmatism is inferred to have happened during the Triassic. The evident lack of ages observed around ca. 200 Ma suggests

  2. At what conditions does zircon grow/dissolve during high-T metamorphism? Relating zircon textures to PT-conditions

    NASA Astrophysics Data System (ADS)

    Kunz, Barbara E.; Regis, Daniele; Manzotti, Paola; Engi, Martin

    2015-04-01

    A key question in ziconology is when and how zircon grows during metamorphism. To shed light on zircon forming processes and the corresponding PT-conditions during high-T metamorphism a case study was undertaken. The Ivrea Zone (N-Italy) exposes a lower continental crustal section in which a continuous metamorphic field gradient from amphibolite to granulite facies is documented. This field gradient is thought to reflect protracted heating during late Paleozoic times, with a probable high-T peak in the Permian. We present first results from a primarily textural study supported by U-Pb ages, Th/U ratios and Ti-in-Zrn thermometry. Four types of zircon were identified based on their overgrowth proportions and the preservation of detrital cores. Zircon grains were thus classified as Type1 - detrital grains with no overgrowth or very narrow rims (300 Ma) and appears to reflect an early dehydration phase. Rim2b has Permian ages (median 275 Ma), is by far the most common overgrowth type, found in a wide PT-range. Its development appears related to biotite breakdown. Rim3 is texturally indicative of magmatic zircon, occurs only in diatexites. Rim4 is the latest overgrowth and is locally found at all metamorphic grades. Textural features suggest late fluid-related recrystallization of existing zircon. At lowest grade (675±35°C, 6±2 kbar) zircons show type1 only, overgrowths are too thin to clearly identify the rim type. Further upgrade (~700°C, 7 kbar) type1 and type2 dominate. Type2 zircons show rim1, rim2a and occasionally rim4. At the Mu-out isograd (750±50°C, 8.2±1.4 kbar) most zircons are of type2, now with rim2b instead of 2a, in addition to rim1 and rim4. Near and in granulite facies (to 800°C, 8±2 kbar) mostly zircon type2 and type4 are present. While rim1 gets more narrow with increasing metamorphic grade, rim2b grows significantly thicker. Occasionally rim2a and rim4 occur. Close to the Bt-out isograd (~860°C, 9.2±1.7 kbar), mostly type3 and type4 are

  3. Sediment provenance in contractional orogens: The detrital zircon record from modern rivers in the Andean fold-thrust belt and foreland basin of western Argentina

    NASA Astrophysics Data System (ADS)

    Capaldi, Tomas N.; Horton, Brian K.; McKenzie, N. Ryan; Stockli, Daniel F.; Odlum, Margaret L.

    2017-12-01

    This study analyzes detrital zircon U-Pb age populations from Andean rivers to assess whether active synorogenic sedimentation accurately records proportional contributions from varied bedrock source units across different drainage areas. Samples of modern river sand were collected from west-central Argentina (28-33°S), where the Andes are characterized by active uplift and deposition in diverse contractional provinces, including (1) hinterland, (2) wedge-top, (3) proximal foreland, and (4) distal broken foreland basin settings. Potential controls on sediment provenance were evaluated by comparing river U-Pb age distributions with predicted age spectra generated by a sediment mixing model weighted by relative catchment exposure (outcrop) areas for different source units. Several statistical measures (similarity, likeness, and cross-correlation) are employed to compare how well the area-weighted model predicts modern river age populations. (1) Hinterland basin provenance is influenced by local relief generated along thrust-bounded ranges and high zircon fertility of exposed crystalline basement. (2) Wedge-top (piggyback) basin provenance is controlled by variable lithologic durability among thrust-belt bedrock sources and recycled basin sediments. (3) Proximal foreland (foredeep) basin provenance of rivers and fluvial megafans accurately reflect regional bedrock distributions, with limited effects of zircon fertility and lithologic durability in large (>20,000 km2) second-order drainage systems. (4) In distal broken segments of the foreland basin, regional provenance signatures from thrust-belt and hinterland areas are diluted by local contributions from foreland basement-cored uplifts.

  4. Detrital K-feldspar thermochronology of the Nanaimo Group: Characterization of Basement and Extraregional Basin Contributions

    NASA Astrophysics Data System (ADS)

    Isava, V.; Grove, M.; Mahoney, J. B.; Kimbrough, D. L.

    2016-12-01

    The Late Cretaceous-Early Paleogene Nanaimo Group covers the contact between Triassic basement Wrangellia terrane and the Jurassic-Cretaceous Coast Plutonic Complex (CPC) in southern British Columbia. Prior detrital zircon U-Pb and Hf studies indicate a change in sediment source for the Nanaimo basin, from the primitive CPC in Santonian-Early Campanian time to an isotopically evolved continental extraregional source during the late Campanian/Maastrictian. Two notably different areas have been proposed as potential source regions: (1) the Idaho/Boulder batholith and Belt Supergroup, and (2) the Mojave/Salinia segment of structurally disrupted late Cretaceous southern California margin. Single crystal 40Ar/39Ar laser fusion of ca. 100-200 grains apiece from seven detrital K-feldspar samples from Santonian-Maastrichtian strata of the northern Nanaimo Group constrain the history of the sediments' source regions. The two oldest samples, from the K-feldspar poor Comox and Extension Fms., display a monotonic increasing distribution of cooling ages 80-125 Ma that reflects shallow erosion of the CPC. In contrast, Late Campanian strata of the Cedar District and De Courcy Fms. exhibit a more pronounced cluster of cooling ages 80-95 Ma as well as a greater proportion of Jurassic ages that represent progressively deeper erosion of the CPC. Evidence for an extraregional sediment source appears abruptly in the Geoffrey Fm. by 72 Ma, matching the time of local-to-extraregional shift indicated in detrital zircon U-Pb studies. Over 90% of the detrital K-feldspars from these arkosic sandstones yield cooling ages of 70-80 Ma, with sparse older ages associated with the CPC. Samples from the successively younger Spray and Gabriola Fms. also yield >90% K-feldspar ages younger than 80 Ma and exhibit age maxima of 68 Ma and 65 Ma, respectively. These results are distinct from detrital zircon U-Pb and K-feldspar 40Ar/39Ar ages of the southern Sierra Nevada, Mojave/Salina, and northern

  5. 207Pb-206Pb zircon ages of eastern and western Dharwar craton, southern India : Evidence for contemporaneous Archaean crust

    NASA Astrophysics Data System (ADS)

    Maibam, B.; Goswami, J. N.; Srinivasan, R.

    2009-04-01

    Dharwar craton is one of the major Archaean crustal blocks in the Indian subcontinent. The craton is comprised of two blocks, western and eastern. The western domain is underlain by orthogneisses and granodiorites (ca. 2.9-3.3 Ga) collectively termed as Peninsular Gneiss [e.g., 1] interspersed with older tracts of metasedimentary and metamorphosed igneous suites (Sargur Group and Dharwar Group; [2]). The eastern part of the craton is dominated by Late Archaean (2.50-2.75 Ga) granitoids and their gneissic equivalents. They are interspersed with schist belts (also of Sargur Group and Dharwar Group), which are lithologically similar to the Dharwar Supergroup in the western block, but are in different metamorphic dress. Here we report 207Pb-206Pb age of zircons separated from the metasedimentary and gneissic samples from the two blocks to constrain the evolution of the Dharwar craton during the early Archaean. Detrital zircons of the metasedimentary rocks from both the blocks show a wide range of overlapping ages between ~2.9 to >3.5 Ga. Zircon ages of the orthogneisses from the two blocks showed that most of the analysed grains of the eastern Dharwar block are found to be of the age as old as the western Dharwar gneisses. Imprints of younger events could be discerned from the presence of overgrowths in zircons from the studied samples throughout the craton. Our data suggest that crust forming cycles in the two blocks of the Dharwar craton occurred contemporaneously during the Archaean. References [1] Beckinsale, R.D., Drury, S.A., Holt, R.W. (1980) Nature 283, 469-470. [2] Swami Nath J., Ramakrishnan M., Viswanatha M.N. (1976) Rec. Geol. Surv. Ind., 107, 149-175.

  6. Li isotopes in archean zircons

    NASA Astrophysics Data System (ADS)

    Bouvier, A.; Ushikubo, T.; Kita, N.; Cavosie, A. J.; Kozdon, R.; Valley, J. W.

    2009-12-01

    Li is a fluid mobile, moderately incompatible element with a large mass difference between its two stable isotopes. Different processes can fractionate 7Li/6Li (fluid-rock interaction, metamorphic reactions, and Li diffusion), leading to variation by over 50‰ of δ7Li for common crustal material. These large variations make δ7Li a potential tracer of continental weathering and of the fluids affecting magma sources. Here, we report δ7Li and trace elements in Archean igneous zircons from TTG and sanukitoid granitoids from the Superior Province (Canada) in order to characterize Li in Archean zircons from well-described samples. These data are compared to detrital zircons from the Jack Hills (Western Australia) for which parent rock-type is uncertain. This study aims to better understand Li substitution in zircon and to evaluate the utility of δ7Li and [Li] for Archean petrogenesis. Zircons (n=71) were analyzed for δ7Li and trace elements (Li, P, Ca, Ti, V, Fe, Y, REE, U, Th) using an IMS-1280 ion microprobe. Most of the zircons display typical igneous REE patterns and zoning by CL. [Li] averages 13.1 ± 9 for TTG, 25.7 ± 19 for Sanukitoid and 31.0 ± 14 ppm for Jack Hills zircons, which are distinct from mantle-related zircons (<0.1 ppm). Values of δ7Li average 1.0 ± 4.5‰ for TTGs, 6.3 ± 4.4‰ for sanukitoids and -2.6 ± 8.8‰ for Jack Hills samples. Trace elements were analyzed from single spots in order to evaluate coupled substitutions. Atomic ratios (3Li+Y+REE)/P average 2.6, showing that Li and trivalent atoms are not charge-balanced by P, and suggesting that Li does not replace Zr, according to the xenotime substitution. However, (Y+REE)/(Li+P) atomic ratios average 1.0 ± 0.6, supporting the hypothesis that Li is interstitial and partly compensates trivalent cations. Several observations in this study suggest that [Li] is primary in the studied zircons: i) if Li is interstitial, charge-balance and slow diffusion of REE would control Li mobility

  7. 40Ar- 39Ar dating of detrital muscovite in provenance investigations: a case study from the Adelaide Rift Complex, South Australia

    NASA Astrophysics Data System (ADS)

    Haines, Peter W.; Turner, Simon P.; Kelley, Simon P.; Wartho, Jo-Anne; Sherlock, Sarah C.

    2004-11-01

    Detrital zircon ages are commonly used to investigate sediment provenance and supply routes. Here, we explore the advantages of employing multiple, complimentary techniques via a case study of the Neoproterozoic and Cambrian of the Adelaide Rift Complex, South Australia. Detrital muscovite Ar-Ar ages are presented from stratigraphic units, or equivalents, that have previously been the subject of U-Pb detrital zircon dating, and, in some cases, whole-rock Sm-Nd isotope studies. The zircon age ranges and whole-rock Sm-Nd isotope data suggest that early Neoproterozoic sediments from near the base of the Adelaide Rift Complex comprise a mixture of detritus derived from the adjacent Gawler Craton (Palaeoproterozoic to earliest Mesoproterozoic) and overlying Gairdner flood basalts. In contrast, detrital muscovites from this level have a broad scatter of Mesoproterozoic infrared (IR) laser total fusion Ar-Ar ages, while UV laser traverses indicate that the age spread reflects partial resetting by multiple heating events, rather than a mixture of sources. Younger Neoproterozoic sediments document replacement of the Gawler Craton by the more distant Musgrave and/or Albany-Fraser Orogens as the main provenance. The Cambrian Kanmantoo Group marks an abrupt change in depositional style and a new sediment source. The Kanmantoo Group have older Nd model ages than underlying strata, yet are dominated by near to deposition-aged (˜500-650 Ma) detrital zircons and muscovites, suggesting rapid cooling and exhumation of a tectonically active provenance region. Although this source remains uncertain, evidence points towards the distant Pan-African orogenic belts. Deposition in the Adelaide Rift Complex was terminated in the late Early Cambrian by the Delamerian Orogeny, and the results of previous detrital mineral dating studies from the Lachlan Fold Belt to the east are consistent with at least partial derivation of these sediments from reworked upper Adelaide Rift Complex (Kanmantoo

  8. Zircon ages in granulite facies rocks: decoupling from geochemistry above 850 °C?

    NASA Astrophysics Data System (ADS)

    Kunz, Barbara E.; Regis, Daniele; Engi, Martin

    2018-03-01

    Granulite facies rocks frequently show a large spread in their zircon ages, the interpretation of which raises questions: Has the isotopic system been disturbed? By what process(es) and conditions did the alteration occur? Can the dates be regarded as real ages, reflecting several growth episodes? Furthermore, under some circumstances of (ultra-)high-temperature metamorphism, decoupling of zircon U-Pb dates from their trace element geochemistry has been reported. Understanding these processes is crucial to help interpret such dates in the context of the P-T history. Our study presents evidence for decoupling in zircon from the highest grade metapelites (> 850 °C) taken along a continuous high-temperature metamorphic field gradient in the Ivrea Zone (NW Italy). These rocks represent a well-characterised segment of Permian lower continental crust with a protracted high-temperature history. Cathodoluminescence images reveal that zircons in the mid-amphibolite facies preserve mainly detrital cores with narrow overgrowths. In the upper amphibolite and granulite facies, preserved detrital cores decrease and metamorphic zircon increases in quantity. Across all samples we document a sequence of four rim generations based on textures. U-Pb dates, Th/U ratios and Ti-in-zircon concentrations show an essentially continuous evolution with increasing metamorphic grade, except in the samples from the granulite facies, which display significant scatter in age and chemistry. We associate the observed decoupling of zircon systematics in high-grade non-metamict zircon with disturbance processes related to differences in behaviour of non-formula elements (i.e. Pb, Th, U, Ti) at high-temperature conditions, notably differences in compatibility within the crystal structure.

  9. Paleogeographic changes across the Pennsylvanian-Permian boundary within the Mid-Continent (USA) inferred from detrital zircon geochronology of continental deposits

    NASA Astrophysics Data System (ADS)

    Soreghan, M. J.; Soreghan, G. S.

    2017-12-01

    The Permo-Pennsylvanian was characterized by intense orogenesis associated with Pangaean assembly, and profound climate shifts as earth transitioned from full icehouse conditions in the Pennsylvanian-early Permian to collapse into greenhouse conditions by latest Permian time. The modern U.S. Midcontinent was part of equatorial western Pangaea (North America) sandwiched between a continental-scale orogenic zone to the east and south (Appalachian-Ouachita-Marathon orogenic belt) and a series of basement-cored, intra-plate uplifts along western Pangaea (Ancestral Rocky Mountains). Here, we present a compilation of detrital zircon geochronology data from the Permo-Pennsylvanian of the Midcontinent as well as coeval strata of the east and west to explore sediment dispersal and potential tectonic and climatic influences on these provenance signatures. Zircon provenance data come from mostly eolian and fluvial silt- and sandstones of Early Pennsylvanian through Mid Permian age, although some data include marine sandstones. Our new data were acquired by LA-ICPMS at the University of Arizona Laserchron, and predominant age groups include >2500 Ma (Archean), 1600-1800 Ma (Yavapai-Matzatzal), 1300-900 Ma (Grenville), 790-570 Ma (Neoproterozoic), and 480-360 (E-M Paleozoic). However, the relative distributions of these populations exhibit distinctive temporal differences, especially across the Pennsylvanian-Permian boundary, but also spatially in comparison to published data from the Appalachian-Ouachita-Marathon basin, Ancestral Rocky Mountain basins, and the western Pangaean margin. Although the Central Pangaean Mountains, and in particular the Grenville-age basement rocks, were a dominant source of sediment to the Midcontinent, the data suggest an abrupt introduction of Neoproterozoic zircons in the early Permian. This signature also appears within the Ancestral Rocky Mountains region, but is rare along the western margin and the Appalachian basin in the early Permian. This

  10. Detrital thermochronology of Rhine, Elbe and Meuse river sediment (Central Europe): implications for provenance, erosion and mineral fertility

    NASA Astrophysics Data System (ADS)

    Glotzbach, C.; Busschers, F. S.; Winsemann, J.

    2018-03-01

    Here we present detrital apatite fission track (AFT), zircon fission track (ZFT) and a few apatite (U-Th)/He (AHe) data of Middle Pleistocene to modern Rhine, Meuse and Elbe river sediments in order to resolve processes that control detrital age distributions (provenance, erosion and mineral fertility). We used a modelling approach to compare observed with theoretically predicted age distributions from an interpolated in situ AFT and ZFT age map. In situ cooling ages do show large differences in the Rhine drainage basin, facilitating the differentiation between different source regions. Inconsistencies between observed and theoretical age distributions of the Meuse and Elbe samples can be explained by mixing and reworking of sediments with different provenances (Meuse Middle Pleistocene terrace sediment) and a yet unexplored source region with old AFT ages (Elbe samples). Overall, the results show that detrital thermochronology is capable of identifying the provenance of Middle Pleistocene to modern sediments. The AFT age distributions of Rhine sediments are dominated ( 70%) by AFT ages representing the Alps. A possible explanation is higher erosion rates in the Alps as compared to areas outside the Alps. A Late Pleistocene sample from the Upper Rhine Graben contains apatite grains from the Molasse and Hegau volcanics, which we explain with a shift of the headwaters of the Rhine to the north as a result of intense Middle Pleistocene Riss glaciation. Contrary to the observed dominance of Alpine-derived AFT ages in Rhine sediments, the relative contribution of zircon ages with sources in the Alps is lower and significantly decreases downstream, suggesting a major source of zircons outside the Alps. This can be explained by increased zircon fertility of sediments derived from the Rhenish massif. Therefore, we conclude that erosion and mineral fertility are the main processes controlling detrital AFT and ZFT age distributions of the sampled river sediment. In case of

  11. 2.6-2.7 Ga continental crust growth in Yangtze craton, South China

    NASA Astrophysics Data System (ADS)

    Chen, K.; Gao, S.; Wu, Y.

    2013-12-01

    A combined study of zircon U-Pb and Lu-Hf isotopes and whole rock major and trace elements and Sr-Nd isotopes has been conducted for 10 granitic and tonalitic-trondhjemitic-granodioritic (TTG) gneisses from the Kongling terrain, the only known Archean microcontinent in the Yangtze craton, South China. The results reveal a significant magmatic event at ~2.6-2.7 Ga (Fig. 1), in addition to the previously reported ~2.9 Ga and ~3.2-3.3 Ga magmatism (Zhang et al., 2006; Jiao et al., 2009; Gao et al., 2011). The ~2.6-2.7 Ga rocks show relatively high REE (530-1074 ppm), apparently negative Eu anomaly (Eu/Eu* = 0.22-0.35), low #Mg (19.51-22.63) and low LaN/YbN (10.3-24.2). Besides, they have high K-feldspar proportion and relatively evaluated (K2O+Na2O)/CaO, TFeO/MgO, Zr, Nb, Ce and Y contents. Their 10000 × Ga/Al ratios range between 3.00 and 3.54. All these features suggest that the protoliths of these gneisses are A-type granites. Most of the ~2.6-2.7 Ga zircon grains have ɛHf(t) values >0 (up to 7.93, close to the depleted mantle value). This clearly indicates a considerably higher proportion of new crustal components in the ~2.6-2.7 Ga granitoids compared to the ~3.2-3.3 Ga and ~2.9 Ga TTGs. Our results support the conclusion of worldwide studies of igneous and detrital zircons that age peaks at 2.65-2.76 Ga represent increases in the volume of juvenile continental crust. The present study also confirms the existence of the two older magmatic events in the Kongling terrain. Both whole rock ɛNd(t) values (-3.74 to 1.59) and the zircon ɛHf(t) values (-11.18 to 3.55) for the ~2.9 Ga TTG and the Hf isotopes of ~3.2-3.3 Ga igneous zircons (-7.37 to 3.12) are chondritic or subchondritic, suggesting that they were mainly generated by reworking of older rocks with a small amount of new crustal additions. References Gao, S., Yang, J., Zhou, L., Li, M., Hu, Z.C., Guo, J.L., Yuan, H.L., Gong, H.J., Xiao, G.Q., Wei, J.Q., 2011. Age and growth of the Archean Kongling terrain

  12. Dating the Indo-Asia collision in NW Himalaya: constraints from Sr-Nd isotopes and detrital zircon (U-Pb) and Hf isotopes of Paleogene-Neogene rocks in the Katawaz basin, NW Pakistan

    NASA Astrophysics Data System (ADS)

    Zhuang, Guangsheng; Najman, Yani; Millar, Ian; Chauvel, Catherine; Guillot, Stephane; Carter, Andrew

    2015-04-01

    The time of collision between the Indian and Asian plates is key for understanding the convergence history and the impact on climatic systems and marine geochemistry. Despite much active research, the fundamental questions still remain elusive regarding when and where the Indian plate collided with the Asian plate. Especially in the west Himalaya, the questions become more complex due to disputes on the amalgamation history of interoceanic Kohistan-Ladakh arcs (KLA) with Karakoram of the Asian plate and the Indian plate. Here, we present a result of multiple-isotopic geochemistry and geochronology study in the Katawaz Basin in NW Pakistan, a remnant oceanic basin on the western Indian plate which was the repository for the sediments eroded from the west Himalaya ( Qayyum et al., 1996, 1997a, 1997b, 2001; Carter et al., 2010), to evaluate the time and character of collision in this region. In this study, we analyzed 22 bulk mudstone samples for Sr-Nd isotopes and 11 medium-grained sandstones for detrital zircon (U-Pb) geochronology and Hf isotopes. We constructed the Cenozoic chronology in the Katawaz Basin based on our newly collected detrital zircon U-Pb ages and fission track ages. We present the first record of Katawaz chronology that constrained the Khojak Formation to be < 40 Ma to < 22 Ma. The result is consistent with the previous nanofossil study that constrained the upper part of underlying Nisai Formation to be the Middle to Late Eocene. Our current study revealed that the Katawaz sedimentary sequence ranges in age from Eocene to the earliest Miocene. The samples from the Nisai Formation show the 87Sr/86Sr - ɛNd values overlapping those of the end member of the Karakoram of Asian origin, revealing the arrival of Asian detritus on the Indian plate prior to 50 Ma. There are two parallel lines of evidence supporting this conclusion: (1) young zircon grains (< 120 Ma), characterizing the KLA and Karakoram, persistently exist throughout the whole sedimentary

  13. A new geological framework for south-central Madagascar, and its relevance to the "out-of-Africa" hypothesis

    USGS Publications Warehouse

    Tucker, R.D.; Roig, J.Y.; Macey, P.H.; Delor, C.; Amelin, Y.; Armstrong, R.A.; Rabarimanana, M.H.; Ralison, A.V.

    2011-01-01

    The Precambrian shield of south-central Madagascar, excluding the Vohibory region, consists of three geologic domains, from north to south: Antananarivo, Ikalamavony-Itremo, and Anosyen-Androyen. The northern Antananarivo domain represents the Neoarchean sector of the Greater Dharwar Craton amalgamated at 2.52-2.48. Ga. The Greater Dharwar Craton is overlain by several groups of Meso- to Neoproterozoic supracrustal rocks (Ambatolampy, Manampotsy, Ampasary, Sahantaha, and Maha Groups) each with a common and diagnostic signature of Paleoproterozoic detrital zircons (2.2-1.8. Ga). The central domain (Ikalamavony-Itremo) consists of two distinct parts. The Itremo Sub-domain, in the east, is a structurally intercalated sequence of Neoarchean gneiss and shallow marine metasedimentary rocks of Paleo-Mesoproterozoic age (Itremo Group), the latter with Paleoproterozoic detrital zircons ranging in age between 2.2 and 1.8. Ga. The Ikalamavony Sub-domain, to the west, contains abundant volcano-clastic metasediments and lesser quartzite (Ikalamavony Group), formed between 1.03. Ga and 0.98. Ga, and intruded by igneous rocks (Dabolava Suite) of Stenian-Tonian age. Structurally intercalated with these are sheets of Neoarchean gneiss (~2.5. Ga) and Neoproterozoic metaclastic rocks (Molo Group). Like the Itremo Group, quartzite of the Ikalamavony Group has detrital zircons of Paleoproterozoic age (2.1-1.8. Ga). The southern domain of Anosyen-Androyen consists of a newly recognized suite of Paleoproterozoic igneous rocks (2.0-1.8. Ga), and stratified supracrustal rocks also having Paleoproterozoic detrital zircons (2.3-1.8. Ga). The contact between the Anosyen-Androyen and Ikalamavony-Itremo domains, formerly known as the Ranotsara-Bongolava shear zone, is a tightly folded and highly flattened boundary that was ductilely deformed in Ediacaran time. It is roughly equivalent to the Palghat-Cauvery shear zone in south India, and it defines approximately the boundary between the Archean

  14. Pre-Alpine evolution of the Seckau Complex (Austroalpine basement/Eastern Alps): Constraints from in-situ LA-ICP-MS Usbnd Pb zircon geochronology

    NASA Astrophysics Data System (ADS)

    Mandl, Magdalena; Kurz, Walter; Hauzenberger, Christoph; Fritz, Harald; Klötzli, Urs; Schuster, Ralf

    2018-01-01

    The Variscan European Belt is a complex orogen with its southern margin partly obscured by Alpine tectonics and metamorphism. We present a study of one of the units, the Seckau Complex, that constitute the southern part of the Variscan European Belt in the Eastern Alps in order to clarify its origin, age and lithostratigraphy. The magmatic and geochronological evolution of this Complex in the northwestern part of the Seckau Nappe (as part of the Austroalpine Silvretta-Seckau Nappe System) was investigated by zircon Usbnd Pb dating of paragneisses and metagranitoids coupled with petrological and geochemical data. This reveals the distinction of three newly defined lithostratigraphic/lithodemic sub-units: (1) Glaneck Metamorphic Suite, (2) Hochreichart Plutonic Suite and (3) Hintertal Plutonic Suite. The Glaneck Metamorphic Suite is mainly composed of fine-grained paragneisses that yield Usbnd Pb zircon ages in the range between 2.7 Ga and 2.0 Ga, as well as concordia ages from 572 ± 7 Ma to 559 ± 11 Ma. All of these ages are interpreted as detrital zircon ages originating from an igneous source. The paragneisses are the host rock for the large volumes of metagranitoids of the Hochreichart Plutonic Suite and the Hintertal Plutonic Suite. The Hochreichart Plutonic Suite comprises highly fractionated melts with mainly S-type characteristics and late Cambrian to Early Ordovician Usbnd Pb zircon ages (508 ± 9 Ma to 486 ± 9 Ma), interpreted as magmatic protolith ages. The Hintertal Plutonic Suite is composed of metagranitoids with Late Devonian to early Carboniferous (365 ± 11 Ma and 331 ± 10 Ma) protolith ages, that intruded during an early phase of the Variscan tectonometamorphic event. The metagranitoids of the Hintertal Plutonic Suites define a magmatic fractionation trend, seen in variable Rb/Sr ratios. On this base they can be further subdivided into (a) the Griessstein Pluton characterized by S-type metagranitoids and (b) the Pletzen Pluton distinguished by

  15. Experimental evidence for use of aluminum in zircon as a new tracer to distinguish peraluminous and metaluminous melts

    NASA Astrophysics Data System (ADS)

    Wang, Y.; Trail, D.

    2017-12-01

    Aluminum (Al) is the third most abundant rock-forming element in Earth's crust. It also substitutes into the zircon lattice as trace impurity. For zircons that lack parent rock information, e.g. Hadean zircon (>4.0 Ga), Al in zircon could be a potentially useful tool to investigate the formation and evolution of the parental magma. Aluminum saturation index (ASI; molar ratio of Al2O3/(CaO+Na2O+K2O)) is widely used to distinguish peraluminous rocks (ASI>1) from metaluminous rocks (ASI<1). We grew zircons in piston cylinder from granitic melts, with different ASI values but same temperature, pressure and water content. Synthetic zircons with variable sizes, as large as 20 µm, were observed under SEM and analyzed using LA-ICP-MS. Our analyses reveal that the Al content of zircons that crystalized from a peraluminous melt (ASI=1.25) is, on average, one magnitude higher than crystals from peralkaline melt (ASI=0.5), e.g., 100s of ppm, vs. 10s of ppm. This indicates that aluminum solubility in zircon is related to the ASI value of parental melt. This experimental result agrees with studies of natural zircons, where Al contents of peraluminous zircons ( 10 ppm) are an order of magnitude higher than zircons from metaluminous rocks ( 1.3 ppm) (Trail et al., 2017). We suggest that melts with ASI>1 can result in an elevated alumina activity, which leads to zircons with elevated Al contents. The notably higher Al concentration in experimental zircons (10s to 100s ppm), compared with natural zircons (1 to 10 ppm), could be explained by the much higher crystallization temperature, e.g., >1100°C vs. <900°C. Both field and experimental studies support the notion that a relationship exists between the Al content in zircon and the melt ASI value. This conclusion has several meaningful applications: 1) it may be used to infer source rock characteristics of Hadean zircons, and to shed light on the formation and evolution of the earliest crust; 2) it may provide additional

  16. Zircon and monazite response to prograde metamorphism in the Reynolds Range, central Australia

    NASA Astrophysics Data System (ADS)

    Rubatto, Daniela; Williams, Ian S.; Buick, Ian S.

    2001-01-01

    We report an extensive field-based study of zircon and monazite in the metamorphic sequence of the Reynolds Range (central Australia), where greenschist- to granulite-facies metamorphism is recorded over a continuous crustal section. Detailed cathodoluminescence and back-scattered electron imaging, supported by SHRIMP U-Pb dating, has revealed the different behaviours of zircon and monazite during metamorphism. Monazite first recorded regional metamorphic ages (1576 ± 5 Ma), at amphibolite-facies grade, at ˜600 °C. Abundant monazite yielding similar ages (1557 ± 2 to 1585 ± 3 Ma) is found at granulite-facies conditions in both partial melt segregations and restites. New zircon growth occurred between 1562 ± 4 and 1587 ± 4 Ma, but, in contrast to monazite, is only recorded in granulite-facies rocks where melt was present (≥700 °C). New zircon appears to form at the expense of pre-existing detrital and inherited cores, which are partly resorbed. The amount of metamorphic growth in both accessory minerals increases with temperature and metamorphic grade. However, new zircon growth is influenced by rock composition and driven by partial melting, factors that appear to have little effect on the formation of metamorphic monazite. The growth of these accessory phases in response to metamorphism extends over the 30 Ma period of melt crystallisation (1557-1587 Ma) in a stable high geothermal regime. Rare earth element patterns of zircon overgrowths in leucosome and restite indicate that, during the protracted metamorphism, melt-restite equilibrium was reached. Even in the extreme conditions of long-lasting high temperature (750-800 °C) metamorphism, Pb inheritance is widely preserved in the detrital zircon cores. A trace of inheritance is found in monazite, indicating that the closure temperature of the U-Pb system in relatively large monazite crystals can exceed 750-800 °C.

  17. Integrated in situ U-Pb Age and Hf-O Analyses of Zircon from the Northern Yangtze Block: New Insights into the Neoproterozoic Low-δ18O Magmas in the South China Block

    NASA Astrophysics Data System (ADS)

    Yang, Y. N.; Wang, X. C.; Li, Q. L.; Li, X. H.

    2015-12-01

    The oxygen isotopic composition of Neoproterozoic magmas from the northern Yangtze Block holds a key for the origin of large-scale 18O depletion in the HP and UHP metamorphic rocks in the Dabie-Sulu orogenic belt, northern margin of the South China Block. We report here the integrated in situ U-Pb dating and O-Hf isotope analyses of zircon grains from sedimentary and volcanic rocks of the late Neoproterozoic Suixian Group (SG) from the northern Yangtze Block. Detrital zircon grains display age peaks of 0.73-0.74 Ga, 0.79 Ga, and 2.0 Ga. Zircon U-Pb ages together with Hf-O isotopic composition indicate provenance of SG dominantly from proximal Neoproterozoic igneous rock and likely hidden Paleoproterozoic basement along the northern margin of the Yangtze Block. The zircon δ18O values from SG range from 10.5‰ to 1.3‰. Zircon grains with negative δ18O value, typical result of magma-ice interaction, were not identified in this study. The major phase of low-δ18O (< 4‰) magmas initiated at ca. 780 Ma, long before the first glaciation event (< 715 Ma) in the South China Block. Thus caution should be taken when using low-δ18O zircon grains to infer cold climate. Low-δ18O zircon grains have large ranges of ɛHf(t) values, varying from -15.5 to 10.7, concentrating on negative ɛHf(t). This strongly argues against the possibility that the low-δ18O magma was produced by partial melting of high-temperature hydrothermally altered oceanic crust because this model predicted MORB-like Hf isotopes for the resultant low-δ18O magmas. This study emphasizes that high-T water-rock interaction and continental rifting tectonic setting are essential to generate abundant low-δ18O magmas. The important application of our study is to confirm that most of negative-δ18O zircons identified in HP and UHP metamorphic rocks may not have been inherited from their Neoproterozoic protoliths.

  18. LA-ICP-MS zircon U-Pb and muscovite K-Ar ages of basement rocks from the south arm of Sulawesi, Indonesia

    NASA Astrophysics Data System (ADS)

    Jaya, Asri; Nishikawa, Osamu; Hayasaka, Yasutaka

    2017-11-01

    The zircon U-Pb and muscovite K-Ar age from the Bantimala, Barru and Biru basement complexes in the South Arm of Sulawesi, Indonesia provide new information regarding the timing of magmatism, metamorphism and sedimentation in this region and have implications for the origin and evolution of the study area. The study area is at the juncture between the southeast margin of Sundaland and Bird's Head-Australia. The age of both the zircon U-Pb of detrital materials in the Bantimala Complex and the muscovite K-Ar of amphibolite in the Biru Complex fall in the Late Early Cretaceous (between 109 and 115 Ma), which is a similar age range to previous data for both the sedimentary and metamorphic rocks. The youngest detrital zircon in the schist samples from the Barru Complex fall into the Triassic in age (between 243 and 247 Ma). These age data indicate that the protolith of all three basement complexes were involved in the subduction system and metamorphosed in the late Early Cretaceous, but there are several differences in their deposition environment under and out of the influence of the late Early Cretaceous magmatism in the Bantimala and Barru Complexes, respectively. Felsic igneous activities are confirmed in the Late Cretaceous and the Eocene by the zircon U-Pb age of igneous rocks intruding or included as detrital fragments in three basement complexes. These dates are similar to those reported from the Meratus Complex of South Kalimantan. The detrital zircon age distributions of the basement rocks in the South Arm of Sulawesi display predominant Mesozoic (Cretaceous and Triassic) and Paleozoic populations with a small population of Proterozoic ages supporting the hypothesis that the West Sulawesi block originated from the region of the circum Bird's Head-Australian, namely the Inner Banda block. The absence of Jurassic zircon age population in the South Arm of Sulawesi suggests the division of the South Arm of Sulawesi from the Inner Banda block in early stage of

  19. Xenotime-(Y) formation from zircon dissolution-precipitation and HREE fractionation: an example from a metamorphosed phosphatic sandstone, Espinhaço fold belt (Brazil)

    NASA Astrophysics Data System (ADS)

    Franz, Gerhard; Morteani, Giulio; Rhede, Dieter

    2015-10-01

    We present an example where xenotime-(Y) together with metamorphic zircon replaces detrital zircon in a phosphatic sandstone from the Mesoproterozoic Espinhaço fold belt, Brazil, in a dissolution-precipitation reaction: {{zircon}}1 ( {{relict}} ) + {{P-}}{{bearing fluid}} = {{zircon}}2 ( {{metamorphic}} ) + {{xenotime}}. During the Brasiliano orogeny at 634 ± 19 Ma, the rocks experienced amphibolite facies metamorphism at ≥0.6 GPa/ 550 ± 37 °C (Southern Espinhaço) and ≥0.6 GPa/ 570 ± 35 °C (Northern Espinhaço), constrained by Zr-in-rutile and Ti-in-quartz thermometry and the presence of kyanite + muscovite + quartz. Many of the rocks show unusual rare earth element (REE) patterns with a hump at Gd-Tb-Dy and depletion in light REE. Detrital zircons (with relict ages between 1.5 and 3.3 Ga) show varying degrees of replacement as indicated by the presence of xenotime and associated porosity, from almost pristine to complete alteration. Textural evidence indicates local mobility of Zr and REE at the scale of the thin section. Xenotime-(Y) occurs together with other phosphates, mainly augelite, lazulite, and minerals of the svanbergite-crandallite-goyacite-florencite group. Xenotime-(Y) is very heterogeneous and reaches unusually high contents of up to 14 wt% Gd2O3, 13 wt% Dy2O3, and 3 wt% Tb2O3, corresponding to ≤0.36 REE atoms per formula unit due to the exchange Y = REE. The heavy REE patterns of xenotime-(Y) therefore show variable enrichment in individual elements, which explains the characteristic hump at Gd-Tb-Dy in the REE patterns of the whole rock. Although the rocks reached amphibolite facies conditions, textures indicate that formation of xenotime likely occurred during the early stages of diagenesis—metamorphism. Comparison with REE concentrations in xenotime-(Y) from the literature shows that selective REE incorporation into xenotime-(Y) is controlled by interaction with P-bearing hydrous fluids.

  20. Mesozoic-Cenozoic evolution of the Zoige depression in the Songpan-Ganzi flysch basin, eastern Tibetan Plateau: Constraints from detrital zircon U-Pb ages and fission-track ages of the Triassic sedimentary sequence

    NASA Astrophysics Data System (ADS)

    Tang, Yan; Zhang, Yunpeng; Tong, Lili

    2018-01-01

    The Zoige depression is an important depocenter within the northeast Songpan-Ganzi flysch basin, which is bounded by the South China, North China and Qiangtang Blocks and forms the northeastern margin of the Tibetan Plateau. This paper discusses the sediment provenance and Mesozoic-Cenozoic evolution of the Zoige depression in the Songpan-Ganzi flysch basin, eastern Tibetan Plateau, using the detrital zircon U-Pb ages and apatite fission-track data from the Middle to Late Triassic sedimentary rocks in the area. The U-Pb ages of the Middle to Late Triassic zircons range from 260-280 Ma, 429-480 Ma, 792-974 Ma and 1800-2500 Ma and represent distinct source region. Our new results demonstrate that the detritus deposited during the Middle Triassic (Ladinian, T2zg) primarily originated from the Eastern Kunlun and North Qinling Orogens, with lesser contributions from the North China Block. By the Late Triassic (early Carnian, T3z), the materials at the southern margin of the North China Block were generally transported westward to the basin along a river network that flowed through the Qinling region between the North China and South China Blocks: this interpretation is supported by the predominance of the bimodal distribution of 1.8 Ga and 2.5 Ga age peaks and a lack of significant Neoproterozoic zircon. Since the Late Triassic (middle Carnian, T3zh), considerable changes have occurred in the source terranes, such as the cessation of the Eastern Kunlun Orogen and North China Block sources and the rise of the northwestern margin of the Yangtze Block and South Qinling Orogen. These drastic changes are compatible with a model of a sustained westward collision between the South China and North China Blocks during the late Triassic and the clockwise rotation of the South China Block progressively closed the basin. Subsequently, orogeny-associated folds have formed in the basin since the Late Triassic (late Carnian), and the study area was generally subjected to uplifting and

  1. Archean crustal evolution of the Narryer Gneiss Terrane, Western Australia, as revealed by the U-Pb age and Hf-isotope compositions of zircon from the granitic gneisses

    NASA Astrophysics Data System (ADS)

    Sylvester, P.; Souders, K.; Crowley, J. L.; Myers, J.

    2011-12-01

    The Narryer Gneiss Terrane of the Yilgarn Craton, Western Australia, is an important area for studies of early crustal evolution because of the preservation of (1) detrital zircons of Hadean to Archean age in the Jack Hills and Mt. Narryer metasedimentary belts, and (2) several widespread units of granitic gneisses emplaced between ca. 3.7 and 2.6 Ga. We have analyzed the U-Pb geochronology and Hf-isotope geochemistry of magmatic zircons from 38 samples of the granitic gneisses using laser ablation - (multicollector) - ICPMS. The sample suite is dominated by the Meeberrie gneiss, a banded quartz-microcline-oligoclase-biotite gneiss of monzogranite to granodiorite composition, and the Dugel gneiss, a leucocratic, pegmatite-layered syenogranite gneiss, but gneisses of dioritic to tonalitic composition, as well as less deformed granite sheets, are also represented. Magmatic zircons were identified on the basis of the preservation of oscillatory zoning in BSE and CL images, igneous Th/U ratios (>0.2), and concordant U-Pb isotopic systematics with low common Pb contents. The results indicate many of the gneisses are composed of the products of multiple magmatic events, as has been reported previously for samples of the Meeberrie gneiss (Kinny & Nutman, 1996, Precambrian Res. 78, 165-178). Major ages of magmatism preserved in the gneisses occurred at ca. 3685-3665 Ma, 3620-3565 Ma, 3495-3440 Ma, 3375-3330 Ma, and 3300-3260 Ma. The late granite sheets crystallized at 2710-2645 Ma. Hf-isotope compositions of the zircons trend to less radiogenic values with decreasing age, with ɛHf values of ca. 0 to -5 for 3.7-3.4 Ga gneisses, ca. -1 to -9 for 3.4-3.2 Ga gneisses and ca. -5 to -20 for the late granite sheets. The array of the Hf isotopic compositions with time for the entire sample set are fit well by a regression indicating a source reservoir with a 176Lu/177Hf of 0.022 extracted from the depleted mantle at 3.9 Ga. This suggests that the Narryer gneisses and late granite

  2. U-Pb and Hf isotope analysis of detrital zircons from Mesozoic strata of the Gravina belt, southeast Alaska

    NASA Astrophysics Data System (ADS)

    Yokelson, Intan; Gehrels, George E.; Pecha, Mark; Giesler, Dominique; White, Chelsi; McClelland, William C.

    2015-10-01

    The Gravina belt consists of Upper Jurassic through Lower Cretaceous marine clastic strata and mafic-intermediate volcanic rocks that occur along the western flank of the Coast Mountains in southeast Alaska and coastal British Columbia. This report presents U-Pb ages and Hf isotope determinations of detrital zircons that have been recovered from samples collected from various stratigraphic levels and from along the length of the belt. The results support previous interpretations that strata in the western portion of the Gravina belt accumulated along the inboard margin of the Alexander-Wrangellia terrane and in a back-arc position with respect to the western Coast Mountains batholith. Our results are also consistent with previous suggestions that eastern strata accumulated along the western margin of the inboard Stikine, Yukon-Tanana, and Taku terranes and in a fore-arc position with respect to the eastern Coast Mountains batholith. The history of juxtaposition of western and eastern assemblages is obscured by subsequent plutonism, deformation, and metamorphism within the Coast Mountains orogen, but may have occurred along an Early Cretaceous sinistral transform system. Our results are inconsistent with models in which an east-facing subduction zone existed along the inboard margin of the Alexander-Wrangellia terrane during Late Jurassic-Early Cretaceous time.

  3. An Integrated Analytical Approach to Obtaining Reliable U-Pb and Hf Isotopic Data from Complex (>3.9 to 3.3 Ga) Zircon from the Acasta Gneiss Complex

    NASA Astrophysics Data System (ADS)

    Bauer, A.; Bowring, S. A.; Vervoort, J. D.; Fisher, C. M.

    2014-12-01

    The Acasta Gneiss Complex (AGC) of northwestern Canada preserves some of Earth's oldest granitic crust (>4.03 Ga) and thereby contains important insight into crust forming processes on the early Earth. In general, rocks of the AGC have undergone a complex history of metamorphism and deformation (Archean and Paleoproterozoic)1,2, and, as a consequence, the zircons retain a complex history including inheritance, magmatic and metamorphic overgrowths, recrystallization, and multi-stage Pb loss. Previously published Hf isotopic data on zircons show within sample variability in excess of analytical uncertainty2,3,4. In order to assess the meaning and significance of this apparent isotopic variability, we are using two different methods to obtain coupled U-Pb and Lu-Hf isotopic data in zircon from a suite of rocks ranging in age from ca. > 3.9 Ga to 3.3 Ga. To obtain these data from the same volume of zircon, our approach involves: 1) split stream LA-ICPMS for U-Pb and Lu-Hf; 2) mechanical isolation of zircon domains for chemical abrasion and ID-TIMS U-Pb analyses and solution ICPMS for Lu-Hf recovered from U-Pb ion exchange chromatography. The deconvolution of complex histories requires this integrated approach and permits us to take advantage of both high spatial resolution and highest precision measurements to ultimately decipher the age and isotopic composition of discrete domains of multi-phase zircon. We demonstrate our approach with both relatively simple and complex grain populations in an attempt to understand within and between grain heterogeneity. The samples with the simplest zircon systematics have increasingly negative ɛHf from oldest to youngest, consistent with involvement of 4.0 Ga or older crust in later generations; also, none of our samples have been derived solely from strongly depleted sources. The presence of intra-zircon variability within samples from the AGC reflects a complex history of magmatic additions requiring melting/assimilation of older

  4. Detrital zircon U-Pb geochronology and stratigraphy of the Cretaceous Sanjiang Basin in NE China: Provenance record of an abrupt tectonic switch in the mode and nature of the NE Asian continental margin evolution

    NASA Astrophysics Data System (ADS)

    Zhang, Feng-Qi; Chen, Han-Lin; Batt, Geoffrey E.; Dilek, Yildirim; A, Min-Na; Sun, Ming-Dao; Yang, Shu-Feng; Meng, Qi-An; Zhao, Xue-Qin

    2015-12-01

    The age spectra obtained from 505 spots of detrital zircon U-Pb ages of five representative sandstone samples from the Sanjiang Basin in NE China point to a significant change in its provenance during the Coniacian-Santonian. The predominant detrital source for the Sanjiang Basin during the early Cretaceous was the Zhangguangcai Range magmatic belt and Jiamusi Block along its western and southern periphery, whereas it changed in the late Cretaceous to its eastern periphery. The timing of these inferred changes in the detrital source regions and drainage patterns nearly coincide with the age of a regional unconformity in and across the basin. The time interval of non-deposition and unconformity development was coeval with a transitional period between an extensional tectonic regime in the early Cretaceous and a contractional deformation episode in the late Cretaceous. The Sanjiang Basin evolved during this time window from a backarc to a foreland basin. The migration of the coastal orogenic belt and the fold and thrust belt development farther inland during the late Cretaceous marked the onset of regional-scale shortening and surface uplift in the upper plate of a flat (or very shallow-dipping) subduction zone. The stratigraphic record, the detrital source and geochronology of the basinal strata, and the internal structure of the Sanjiang Basin present, therefore, an important record of a tectonic switch in the nature of continental margin evolution of Northeast Asia during the late Mesozoic.

  5. Detrital Thermochronology Record of the Local-to-Extraregional Provenance Shift Recorded by the Northern Peninsular Ranges Forearc

    NASA Astrophysics Data System (ADS)

    Flores, M.; Shulaker, D. Z.

    2016-12-01

    Previously measured detrital zircon U-Pb age distributions have revealed that Late Cretaceous to Eocene forearc strata in the Santa Ana mountains region experienced a dramatic shift in sedimentary provenance from a 125-90 Ma northern Peninsular Ranges batholith (PRB) source region along the continental margin to a cratonal source area intruded by Late Cretaceous (85-75 Ma) plutons within the continental interior (western Sonora). To improve our understanding of the timing and magnitude of denudation prior to, and during this local to extraregional provenance shift, we have measured new detrital K-feldspar 40Ar/39Ar total fusion and zircon U-Pb age distributions from forearc sandstones. Our combined crystallization age and thermal history results confirm two pulses of rapid denudation of the PRB. These include a syn-batholith phase (Cenomanian) and a post-batholithic (Maastrichtian to Paleocene) phase attributed to shallow subduction. The new data require that significant (5-10 km) syn-batholithic erosional denudation of the northern PRB had already occurred by ca. 95 Ma and that post-emplacement denudation of the PRB accelerated again during the Maastrichtian with the eastern PRB providing the bulk of the detritus. Our new results demonstrate that deposition of the Paleocene Silverado Fm. occurred during a transitional period. Sand reaching the forearc during the Paleocene was derived from both the heavily denuded eastern PRB with additional input supplied either from Late Cretaceous plutons of northwestern Sonoran region and/or similar plutons emplaced in thrust sheets atop PRB basement within the Santa Rosa Mountains. In contrast, the Eocene Santiago Fm. was nearly entirely derived from extraregional sources that supplied abundant late Cretaceous (75-85 Ma) and Proterozoic (1.4 & 1.7 Ga) detritus with virtually no PRB-derived sediment detected.

  6. Late Permian rivers draining the uplifted Cape Fold Belt: magnetostratigraphy and detrital thermochronology of Karoo Basin sediments

    NASA Astrophysics Data System (ADS)

    Tohver, E.; Schmieder, M.; Arosio, R.; Lanci, L.; Jourdan, F.; Wilson, A.; Ratcliffe, K.; Payenberg, T.; Flint, S.

    2017-12-01

    The Cape Fold Belt and Karoo Basin of southern Africa formed during the Permian orogeny that affected the 13,000 km southern margin of the Gondwanan continent. In this report, we synthesize new and recent magnetostratigraphic and geochronologic data to establish a chronostratigraphic framework for Karoo Basin sedimentation for comparison with the thermal/exhumation history of the Cape Fold Belt. The source-sink model is evaluated using new data from detrital muscovite and zircon from 2 km composite section of fluvial sandstone and mudstones deposited at ca.275 - 260 Ma. Coherent age populations of detrital zircon grains indicate rapid incorporation of contemporary volcanic ashbeds into the sedimentary record. In contrast, cooling age distributions of detrital muscovite are typically ca. 5 - 10 Ma older than the age of deposition; similar lag times are observed from modern sediments in active mountain belts. Trace element geochemical signatures demonstrate a clear shift towards crustal recycling via headland erosion in the Beaufort Group relative to the underlying Ecca Group. These observations pinpoint the age of uplift for the Cape Fold Belt, which began to function as the major sediment source for the foreland Karoo Basin with the deposition of the uppermost Ecca Group and basal Beaufort Group.

  7. The 3.5 Ga granulites of the Bug polymetamorphic complex, Ukraine (U-Pb SHRIMP-II zircon data)

    NASA Astrophysics Data System (ADS)

    Lobach-Zhuchenko, Svetlana; Kaulina, Tatiana; Baltybaev, Shauket; Yurchenko, Anastasija; Balagansky, Victor; Skublov, Sergei; Sukach, Vitaliji

    2014-05-01

    The Bug polymetamorphic complex composes the south-west of the Ukrainian Shield. It experienced multistage deformation and metamorphism of 3.6 to 1.95 Ga. The age of protolith of the gneiss enderbite is up to 3.7-3.6 Ga (Claesson et al., 2006: Lobach-Zhuchenko et al., 2010, 2013; Bibikova et al, 2013). The 3.5 old granulitic zircon (sample UR132) was found in a light grey massive medium grained with weak foliation granulite from the Odessa quarry located at the right riverside of the Bug (N 48° 13' 55.2''; E 29° 59' 75''). The rock is mafic in composition (SiO2 = 51.50 wt%, #mg=0.43, (La/Yb)n =7.5), and shows enrichment in Sr (333 ppm), Zr (244 ppm), and Nb (12 ppm) compared to MORB. This contains antiperthitic plagioclase (An30-35), hypersthene (En0.46 Fs0.53 Wo0.01 ), diopside (En0.33 Fs0.20Wo0.47), quartz, ilmenite, magnetite, apatite, and zircon. Three types of zircon are recognized. (1) Large (~300 μm) isometric and oval grains displaying bright colour and sector zoning in CL. Some crystals have fir-tree texture. Isometric shape together with fir-tree zoning is typical for zircons growing under conditions of granulite- facies metamorphism (Hoskin and Schaltegger, 2003). These zircons are low in U and Th, have high Th/U ratios (0.61-1.1), and display decreasing of element contents from the centre to margin (ppm): U - 68 to 44, Th - 58 to 19, total REE - 723 to 406, Y - 1049 to 553, and Li - 1.23 to 0.91 at the constant (Lu/La)n ratios (4200-4600). Zircon's crystallization temperature calculated from the Ti content is 705 °C and is consistent with those calculated on the base of the mineral composition. (2) Small sized (60-100 μm) zircons. Most of these occur within plagioclase and truncate antiperthite lamellae. They show euhedral zoned cores and bright rims in CL. (3) Zircons principally distinguished from those of groups 1 and 2. These are dark in CL, some grains are severely structurally damaged and contain numerous inclusions (Qzt, Pl, Kfsp, rare Opx

  8. Detrital shocked minerals: microstructural provenance indicators of impact craters

    NASA Astrophysics Data System (ADS)

    Cavosie, A. J.

    2014-12-01

    The study of detrital shocked minerals (DSMs) merges planetary science, sedimentology, mineralogy/crystallography, accessory mineral geochemistry, and geochronology, with the goal of identifying and determining provenance of shock metamorphosed sand grains. Diagnostic high-pressure impact-generated microstructures (planar fractures, planar deformation features) are readily identified on external grain surfaces using standard SEM imaging methods (BSE), and when found, unambiguously confirm an impact origin for a given sand grain. DSMs, including quartz, zircon, monazite, and apatite, have thus far been documented at the Vredefort Dome [1,2,3], Sudbury [4], Rock Elm [5], and Santa Fe [6,7] impact structures. DSMs have been identified in alluvium, colluvium, beach sand, and glacial deposits. Two main processes are recognized that imply the global siliciclastic record contains DSMs: they survive extreme distal transport, and they survive 'deep time' lithification. Distal transport: In South Africa, shocked minerals are preserved in alluvium from the Vaal River >750 km downstream from the Vredefort impact; SHRIMP U-Pb geochronology has confirmed the origin of detrital shocked zircon and monazite from shocked Vredefort bedrock [2]. Vredefort-derived shocked zircons have also been found at the mouth of the Orange River on the Atlantic coast, having travelled ~2000 km downriver from Vredefort [8]. Deep time preservation: Vredefort-derived shocked zircon and quartz has been documented in glacial diamictite from the 300 Myr-old Dwyka Group in South Africa. Shocked minerals were thus entrained and transported in Paleozoic ice sheets that passed over Vredefort [9]. An impact crater can thus be viewed as a unique 'point source', in some cases for billions of years [2,4]; DSMs thus have applications in studying eroded impact craters, sedimentary provenance, landscape evolution, and long-term sediment transport processes throughout the geologic record. This work was supported by

  9. Origin of zircon-bearing mantle eclogites entrained in the V. Grib kimberlite (Arkhangelsk region, NW Russia): Evidence from mineral geochemistry and the U-Pb and Lu-Hf isotope compositions of zircon

    NASA Astrophysics Data System (ADS)

    Shchukina, Elena V.; Agashev, Alexey M.; Zedgenizov, Dmitry A.

    2018-05-01

    The concentrations of major and trace elements in minerals, reconstructed whole-rock compositions of zircon-bearing equigranular eclogites from the V. Grib kimberlite pipe located within the Arkhangelsk Diamondiferous Province (North-Western Russia), and results of the U-Pb and Lu-Hf isotope analyses of zircon grains from eclogites and granulite xenoliths are reported. These data suggest that the equigranular eclogites could represent the fragments of mid-ocean-ridge basalt that were metamorphosed during Paleoproterozoic subduction at 1.7-1.9 Ga. The Hf isotope compositions of the eclogitic zircon display uniformity and indicate corresponding Hf-depleted mantle model ages of 2.2-2.3 Ga. The formation of zircon in eclogites could have resulted from interactions with metasomatic/subduction-related fluids just prior to, but associated with, Paleoproterozoic eclogite formation. A link between eclogitic zircon formation and continental lower-crustal rocks can be excluded based on differences in the Hf isotope compositions of eclogitic and granulitic zircon grains. The U-Pb upper intercept age of granulitic zircon of 2716 ± 61 Ma provides a new minimum age constraint for zircon crystallisation and granulite formation. The U-Pb ages obtained from granulitic zircon show two stages of Pb loss at 2.2-2.6 Ga and 1.7-2.0 Ga. The late Paleoproterozoic stage of Pb loss recorded in granulitic zircon is due to the intensive reworking of basement crustal rocks, which was caused by a tectonic process/subduction event associated with equigranular eclogite formation. Our data, along with evidence previously obtained from the V. Grib pipe coarse-granular eclogites, show at least two main subduction events in the lithospheric mantle of the Arkhangelsk region: the Archean (2.8 Ga) and Paleoproterozoic (1.7-1.9 Ga) subductions, which correspond to major magmatic and metamorphic events in the Baltic Shield.

  10. Primary Data on U/Pb-Isotope Ages and Lu/Hf-Isotope Geochemical Systematization of Detrital Zircons from the Lopatinskii Formation (Vendian-Cambrian Transition Levels) and the Tectonic Nature of Teya-Chapa Depression (Northeastern Yenisei Ridge)

    NASA Astrophysics Data System (ADS)

    Kuznetsov, N. B.; Priyatkina, N. S.; Rud'ko, S. V.; Shatsillo, A. V.; Collins, W. J.; Romanyuk, T. V.

    2018-03-01

    The main results are presented on U/Pb-isotope dating of 100 detrital zircons and, selectively, on the Lu/Hf-isotope system of 43 grains from sandstones of the Lopatinskii formation (the lower stratigraphic level of the Chingasan group). Ages from 896 ± 51 to 2925 ± 38 Ma were obtained with a pronounced maximum of 1890 Ma in the curve of probability density, along with ɛHf estimates from +8.4 to-15.1, which allow one to throw doubt upon the molasse nature of the Lopatinskii formation.

  11. Transformations to granular zircon revealed: Twinning, reidite, and ZrO2 in shocked zircon from Meteor Crater (Arizona, USA)

    USGS Publications Warehouse

    Cavosie, Aaron; Timms, Nicholas E.; Erickson, Timmons M.; Hagerty, Justin J.; Hörz, Friedrich

    2016-01-01

    Granular zircon in impact environments has long been recognized but remains poorly understood due to lack of experimental data to identify mechanisms involved in its genesis. Meteor Crater in Arizona (United States) contains abundant evidence of shock metamorphism, including shocked quartz, the high pressure polymorphs coesite and stishovite, diaplectic SiO2 glass, and lechatelierite (fused SiO2). Here we report the presence of granular zircon, a new shocked mineral discovery at Meteor Crater, that preserve critical orientation evidence of specific transformations that occurred during its formation at extreme impact conditions. The zircon grains occur as aggregates of sub-µm neoblasts in highly shocked Coconino Formation Sandstone (CFS) comprised of lechatelierite. Electron backscatter diffraction shows that each grain consists of multiple domains, some with boundaries disoriented by 65°, a known {112} shock-twin orientation. Other domains have crystallographic c-axes in alignment with {110} of neighboring domains, consistent with the former presence of the high pressure ZrSiO4 polymorph reidite. Additionally, nearly all zircon preserve ZrO2 + SiO2, providing evidence of partial dissociation. The genesis of CFS granular zircon started with detrital zircon that experienced shock-twinning and reidite formation from 20 to 30 GPa, ultimately yielding a phase that retained crystallographic memory; this phase subsequently recrystallized to systematically oriented zircon neoblasts, and in some areas partially dissociated to ZrO2. The lechatelierite matrix, experimentally constrained to form at >2000 °C, provided an ultra high-temperature environment for zircon dissociation (~1670 °C) and neoblast formation. The capacity of granular zircon to preserve a cumulative P-T record has not been recognized previously, and provides a new method for retrieving histories of impact-related mineral transformations in the crust at conditions far beyond which most rocks melt.

  12. The 3.66 Ga Nuvvuagittuq Tonalite-Trondhjemite-Granodiorite Suite: A Case of Hadean Anatexis

    NASA Astrophysics Data System (ADS)

    Stevenson, R. K.; Bizzarro, M.

    2011-12-01

    The ca 3.8-4.3 Ga Nuvvuagittuq supracrustal sequence in northern Quebec, Canada, ranks as one of the most exciting early Earth terrain discoveries of the past fifteen years. The supracrustal sequence consists of mafic amphibolite rocks with rare felsic schists along with ultramafic sills and oxide-rich and quartz-rich iron formation. The supracrustal sequence is semi-oval in form and is folded around a core of foliated tonalite-trondhjemite-granodiorite (TTG) suite. A similar TTG suite forms a sheath around the exterior margin of the Nuvvuagittuq supracrustal sequence. Zircons from a felsic volcanic unit within the sequence yielded a minimum age of 3.8 Ga (U-Pb) for volcanic rocks of the sequence (David et al. 2009). A study of the Nd142 isotope systematics of the sequence found evidence for a Nd142 deficit in the sequence and a Nd142-Sm147 isochron yielded an age of 4.28 Ga (O'Neil et al. 2008). Dating of zircons from the tonalite sheath (U-Pb TIMS; David et al., 2009) and from the inner core (U-Pb SHRIMP; this study) yield similar ages (3.66 Ga). Zircons from this sequence undoubtedly contributed to the Hf isotopic composition of Archean sedimentary sequences of the Canadian Shield (Stevenson and Patchett 1990).The zircons from the TTG suite are very homogeneous and only have rare thin metamorphic rims that yield an age of 2.7 Ga (U-Pb Shrimp; this study). Radiogenic isotope studies (Sm-Nd and Lu-Hf) indicate that the TTG suite is an anatectic product of the melting of the Nuvvuagittuq supracrustal suite. The geochemical compositions of the Nuvvuagittuq TTG suite are compared with the compositions of ca 3.6 TTG suites from other localities around the world. David, J. Godin, L., Stevenson, R., O'Neil, J. and Francis, D. 2009. U-Pb ages (3.8-2.7 Ga) and Nd isotope data from the newly- identified Eoarchean Nuvvuagittuq supracrustal sequence, Superior Craton, Canada. GSA Bulletin 121; 150-163. O'Neil, J., Carlson, R.W., Francis, D., and Stevenson, R.K. 2008

  13. Contrasting cratonal provenances for upper Cretaceous Valle Group quartzite clasts, Baja California

    USGS Publications Warehouse

    Kimbrough, D.L.; Abbott, G.; Smith, D.P.; Mahoney, J.B.; Moore, Thomas E.; Gehrels, G.E.; Girty, G.H.; Cooper, John D.

    2006-01-01

    Late Cretaceous Valle Group forearcbasin deposits on the Vizcaino Peninsula of Baja California Sur are dominated by firstcycle arc-derived volcanic-plutonic detritus derived from the adjacent Peninsular Ranges batholith. Craton-derived quartzite clasts are a minor but ubiquitous component in Valle Group conglomerates. The source of these clasts has implications for tectonic reconstructions and sediment-dispersal paths along the paleo-North American margin. Three strongly contrasting types of quartzite are recognized based on petrology and detrital zircon U-Pb geochronology. The first type is ultramature quartz arenite with well-rounded, highly spherical zircon grains. Detrital zircon ages from this type are nearly all >1.8 Ga with age distributions that closely match the distinctive Middle-Late Ordovician Peace River arch detrital signature of the Cordilleran margin. This type has been previously recognized from prebatholithic rocks in northeast Baja California (San Felipe quartzite). A second quartzite type is subarkosic sandstone with strong affinity to southwestern North America; important features of the age spectra are ~1.0-1.2 Ga, 1.42 and 1.66 Ga peaks representing cratonal basement, 500-300 Ma grains interpreted as recycled Appalachian-derived grains, and 284- 232 Ma zircon potentially derived from the Early Permian-Middle Triassic east Mexico arc. This quartzite type could have been carried to the continental margin during Jurassic time as outboard equivalents of Colorado Plateau eolianites. The third quartzite type is quartz pebble conglomerate with significant ~900- 1400 Ma and ~450-650 Ma zircon components, as well as mid- and late Paleozoic grains. The source of this type of quartzite is more problematic but could match either upper Paleozoic strata in the Oaxaca terrane of southern Mexico or a southwestern North America source. The similarity of detrital 98 zircon spectra in all three Valle Group quartzite types to rocks of the adjacent Cordilleran

  14. U-Pb systematics of zircon and titanite from the Gardnos impact structure, Norway: Evidence for impact at 546 Ma?

    NASA Astrophysics Data System (ADS)

    Kalleson, E.; Corfu, F.; Dypvik, H.

    2009-05-01

    Zircon and titanite were investigated in impactites of the Gardnos structure, a crater formed in Sveconorwegian (ca. 1 Ga) crust, which was then overridden in the Devonian by Caledonian nappes. Observed deformation features in zircons are granular texture, planar microstructures, and likely the incorporation of organic carbon during impact causing black staining of the zircon grains. The grains were studied by scanning electron microscopy (SEM) and cathode luminescence (CL) and dated by U-Pb isotope dilution - thermo-ionization mass spectrometry (ID-TIMS). Zircon grains without impact related features have U-Pb data showing moderate discordance (5-13%) and indicating formation ages mostly in the range of 1600-1000 Ma, except detrital zircon ages as old as >2481 Ma, reflecting the diversity of target rocks in the area. Titanite with concordant ages of 995-999 Ma dates metamorphism during final juxtaposition of the Telemarkia on the Idefjorden terrane to the east. Zircon grains with demonstrated or presumed shock features yield highly discordant (14-40%) U-Pb data, with a majority of them plotting along an array with a lower intercept of about 340 Ma reflecting the influence of the Caledonian orogeny and recent Pb-loss. One zircon grain was totally reset at 379 Ma during late Caledonian metamorphism, which also caused local growth of new titanite. A specific group of zircon grains yields data with relatively high discordance for moderate U contents, and five of these analyses, including that of a grain with proven granular or aggregate texture, fit a discordia line with an upper intercept of 546 ± 5 Ma. These features are interpreted as indicating zircon break-down to an amorphous state during impact, with subsequent recrystallization into microcrystalline aggregates causing extensive to complete Pb loss. We further suggest that their crystallinity prevented Pb loss during the Caledonian orogeny, while the small subgrain size and increasing metamictisation allowed

  15. Diachronous evolution of volcano-sedimentary basins north of the Congo craton: Insights from U Pb ion microprobe dating of zircons from the Poli, Lom and Yaoundé Groups (Cameroon)

    NASA Astrophysics Data System (ADS)

    Toteu, Sadrack Félix; Penaye, Joseph; Deloule, Etienne; Van Schmus, William Randall; Tchameni, Rigobert

    2006-04-01

    Ion microprobe U-Pb dating of zircons from Neoproterozoic volcano-sedimentary sequences in Cameroon north of the Congo craton is presented. For the Poli basin, the depositional age is constrained between 700-665 Ma; detrital sources comprise ca. 920, 830, 780 and 736 Ma magmatic zircons. In the Lom basin, the depositional age is constrained between 613 and 600 Ma, and detrital sources include Archaean to Palaeoproterozoic, late Mesoproterozoic to early Neoproterozoic (1100-950 Ma), and Neoproterozoic (735, 644 and 613 Ma) zircons. The Yaoundé Group is probably younger than 625 Ma, and detrital sources include Palaeoproterozoic and Neoproterozoic zircons. The depositional age of the Mahan metavolcano-sedimentary sequence is post-820 Ma, and detrital sources include late Mesoproterozoic (1070 Ma) and early Neoproterozoic volcanic rocks (824 Ma). The following conclusions can be made from these data. (1) The three basins evolved during the Pan-African event but are significantly different in age and tectonic setting; the Poli is a pre- to syn-collisional basin developed upon, or in the vicinity of young magmatic arcs; the Lom basin is post-collisional and intracontinental and developed on old crust; the tectono-metamorphic evolution of the Yaoundé Group resulted from rapid tectonic burial and subsequent collision between the Congo craton and the Adamawa-Yade block. (2) Late Mesoproterozoic to early Neoproterozoic inheritance reflects the presence of magmatic event(s) of this age in west-central Africa.

  16. Regional Comparison of Detrital Zircon Populations in Syn-rift, Jurassic Rocks from the Northern Gulf of Mexico to Northern South America

    NASA Astrophysics Data System (ADS)

    Kouassi, M.

    2016-12-01

    We have compiled over 3200 detrital zircon ages in rock samples collected by various groups of previous workers that range in age from Cambrian to Cenozoic and cover the area of rifting between southern North America, Mexico, the Caribbean, and northern South America. We focussed this study on age populations in Jurassic sedimentary rocks from localities in the southern USA, Mexico, and Colombia to identify similar age populations that could constrain the relative locations of the various blocks during the period of Pangea's breakup and the formation of the Gulf of Mexico and Proto-Caribbean seaway. Jurassic samples from the Mixteca and Maya blocks of southern Mexico, the Norphlet Formation of Alabama and the Giron Formation of Eastern Cordillera of Colombia revealed a good correlation with correlative age populations of 900-1200 Ma and 200- 400 Ma. These results indicate that in a closed fit reconstruction all of these areas may have been overlain by common basin that covered the present-day area of the GOM, Yucatan block, and northern South America. We point out key areas for future sampling and dating that will help expand this study.

  17. U-Pb zircon and biostratigraphic data of high-pressure/low-temperature metamorphic rocks of the Talea Ori: tracking the Paleotethys suture in central Crete, Greece

    NASA Astrophysics Data System (ADS)

    Zulauf, G.; Dörr, W.; Krahl, J.; Lahaye, Y.; Chatzaras, V.; Xypolias, P.

    2016-10-01

    Inherited deformation microfabrics of detrital quartz grains and U-Pb (Laser ablation (LA)-ICPMS and ID TIMS) ages of detrital zircons separated from the Phyllite-Quartzite Unit s.l. of the Talea Ori, central Crete, suggest strikingly different source rocks. Albite gneiss of the lower Rogdia Beds includes Cambrian and Neoproterozoic rounded zircons with main U-Pb age peaks at 628 and 988 Ma. These and minor Paleoproterozoic and Archean peaks, together with the lack of Variscan-aged and Mesoproterozoic zircons, are similar to the age spectra obtained from the Phyllite-Quartzite Unit s.str. of the Peloponnesus and eastern Crete and from the Taurides. All of these zircons should be derived from the northeastern passive margin of Gondwana (Cimmeria). Metatuffites of the uppermost Rogdia Beds and metasandstone of Bali beach, on the other hand, include euhedral detrital zircons displaying a Variscan U-Pb age spectra at ca. 300 Ma with concordia ages at 291 ± 3, 300 ± 1 Ma (Rogdia) and 286 ± 3, 300 ± 3, 313 ± 2 Ma (Bali). Both types of metasediments and their zircons are similar to those of the pre-Alpine basement and overlying Tyros Beds of eastern Crete, revealing a provenance at the southern active margin of Laurasia. Thus, in central Crete the Paleotethys suture should be situated inside the Rogdia Beds. Magmatic zircons separated from a rhyolite boulder of the lower Achlada Beds yielded a concordant U-Pb zircon age at 242 ± 2 Ma placing a maximum age for the deposition of the (meta)conglomerate from which the boulder was collected. This age is compatible with an Olenekian-early Anisian age of the underlying Vasilikon marble suggested by new findings of the foraminifera Meandrospira aff. pusilla. Both the Achlada Beds and the Vasilikon marble can be attributed to the lower Tyros Beds of eastern Crete. The Alpine deformation led to a pervasive mylonitic foliation, which is affecting most of the studied rocks. This foliation results from D2 top

  18. Provenance and detrital zircon geochronologic evolution of lower Brookian foreland basin deposits of the western Brooks Range, Alaska, and implications for early Brookian tectonism

    USGS Publications Warehouse

    Moore, Thomas; O'Sullivan, Paul B.; Potter, Christopher J.; Donelick, Raymond A.

    2015-01-01

    The Upper Jurassic and Lower Cretaceous part of the Brookian sequence of northern Alaska consists of syntectonic deposits shed from the north-directed, early Brookian orogenic belt. We employ sandstone petrography, detrital zircon U-Pb age analysis, and zircon fission-track double-dating methods to investigate these deposits in a succession of thin regional thrust sheets in the western Brooks Range and in the adjacent Colville foreland basin to determine sediment provenance, sedimentary dispersal patterns, and to reconstruct the evolution of the Brookian orogen. The oldest and structurally highest deposits are allochthonous Upper Jurassic volcanic arc–derived sandstones that rest on accreted ophiolitic and/or subduction assemblage mafic igneous rocks. These strata contain a nearly unimodal Late Jurassic zircon population and are interpreted to be a fragment of a forearc basin that was emplaced onto the Brooks Range during arc-continent collision. Synorogenic deposits found at structurally lower levels contain decreasing amounts of ophiolite and arc debris, Jurassic zircons, and increasing amounts of continentally derived sedimentary detritus accompanied by broadly distributed late Paleozoic and Triassic (359–200 Ma), early Paleozoic (542–359 Ma), and Paleoproterozoic (2000–1750 Ma) zircon populations. The zircon populations display fission-track evidence of cooling during the Brookian event and evidence of an earlier episode of cooling in the late Paleozoic and Triassic. Surprisingly, there is little evidence for erosion of the continental basement of Arctic Alaska, its Paleozoic sedimentary cover, or its hinterland metamorphic rocks in early foreland basin strata at any structural and/or stratigraphic level in the western Brooks Range. Detritus from exhumation of these sources did not arrive in the foreland basin until the middle or late Albian in the central part of the Colville Basin.These observations indicate that two primary provenance areas provided

  19. Are there impact-formed zircons in the Hadean record?

    NASA Astrophysics Data System (ADS)

    Wielicki, M. M.; Lu, X.; Bell, E. A.; Schmitt, A. K.; Harrison, T. M.

    2008-12-01

    Detrital Hadean zircons from the Jack Hills, Western Australia, show a remarkable cluster of crystallization temperatures at 680±25°C. This is particularly surprising as a simple model relating rock composition and Zr concentration predicts that a very broad spectrum of crystallization temperatures (ca. 650°C to 1000°C) with a median value of 780°C, would result from impact melting of the Earth's surface. Magmatic fractionation would tend to increase the aforementioned values. Given the predicted high rate of impacts during the Hadean, the absence of such a population in the Jack Hills zircons could signal a profound sampling problem, a hint of a history much different than previously supposed, or our lack of understanding of zircon formation due to impact related processes. We have begun to examine the latter issue by investigating the crystallization temperatures of zircons formed in melt sheets preserved in the geologic record. The Sudbury Igneous Complex, formed at 1850±3 Ma within the second largest impact crater on Earth, includes two igneous units termed the Black and Felsic Norites. Examination of zircons from each by SIMS confirms their crystallization age at 1847.3±2.2 Ma and yields Ti-in-zircon temperatures of 720°C and 750°C, respectively. This is consistent with that predicted from zircon saturation systematics. A statistical test indicates that the combined norite population is distinct from the Hadean temperature distribution. Thus the question arises: where are the Hadean zircons expected to have formed at >780°C via impact processes? Similar analysis is being pursued for zircons from the Vredefort Impact Structure, South Africa, which should provide further information on impact-formed zircon temperature spectra.

  20. Integration of PLZT and BST family oxides with GaN[Lead Lanthanum Zirconate Titanate, Barium Strontium Titanate

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Osinsky, A.V.; Fuflyigin, V.N.; Wang, F.

    2000-07-01

    Recent advances in the processing of complex-oxide materials has allowed the authors to monolithically grow ferroelectrics of lead lanthanum zirconate titanate (PLZT) and barium strontium titanate (BST) systems on a GaN/sapphire structure. High quality films of PLZT and BST were grown on GaN/c-Al{sub 2}O{sub 3} in a thickness range of 0.3--5 {micro}m by a sol-gel technique. Field-induced birefringence, as large as 0.02, was measured from a PLZT layer grown on a buffered GaN/sapphire structure. UV illumination was found to result in more symmetrical electrooptic hysteresis loop. BST films on GaN demonstrated a low frequency dielectric constant of up to 800more » with leakage current density as low as 5.5 {center_dot} 10{sup {minus}8} A/cm{sup 2}.« less

  1. New ichnological, paleobotanical and detrital zircon data from an unnamed rock unit in Yukon-Charley Rivers National Preserve (Cretaceous: Alaska): Stratigraphic implications for the region

    USGS Publications Warehouse

    Fiorillo, Anthony R.; Fanti, Federico; Hults, Chad; Hasiotis, Stephen T

    2014-01-01

    A paleontological reconnaissance survey on Cretaceous and Paleogene terrestrial units along the Yukon River drainage through much of east-central Alaska has provided new chronostratigraphic constraints, paleoclimatological data, and the first information on local biodiversity within an ancient, high-latitude ecosystem. The studied unnamed rock unit is most notable for its historic economic gold placer deposits, but our survey documents its relevance as a source rock for Mesozoic terrestrial vertebrates, invertebrates, and associated flora. Specifically, new U-Pb ages from detrital zircons combined with ichnological data are indicative of a Late Cretaceous age for at least the lower section of the studied rock unit, previously considered to be representative of nearly exclusively Paleogene deposition. Further, the results of our survey show that this sedimentary rock unit preserves the first record of dinosaurs in the vast east-central Alaska region. Lastly, paleobotanical data, when compared to correlative rock units, support previous interpretations that the Late Cretaceous continental ecosystem of Alaska was heterogeneous in nature and seasonal.

  2. Alps to Apennines zircon roller coaster along the Adria microplate margin.

    PubMed

    Jacobs, J; Paoli, G; Rocchi, S; Ksienzyk, A K; Sirevaag, H; Elburg, M A

    2018-02-09

    We have traced the particle path of high-pressure metasedimentary rocks on Elba Island, Northern Apennines, with the help of a U-Pb-Hf detrital zircon study. One quarter of the analysed zircons are surprisingly young, 41-30 Ma, with a main age peak at ca. 32 Ma, indicating an unexpected early Oligocene maximum deposition age. These Oligocene ages with negative εHf indicate a volcanic source region in the central-southern Alps. Though young by geological means, these zircons record an extraordinary geodynamic history. They originated in a volcanic arc, during the convergence/collision of the the Adria microplate with Europe from ca. 65 to 30 Ma. Thereafter, the Oligocene zircons travelled ca. 400 km southward along the Adria margin and the accretionary prism to present-day Tuscany, where they were subducted to depths of at least 40 km. Shortly thereafter, they were brought to the surface again in the wake of hinge roll back of the Apennine subduction zone and the resulting rapid extensional exhumation. Such a zircon roller coaster requires a microplate that has back-to-back subduction zones with opposing polarities on two sides.

  3. On the tectonic evolution of the Tyrrhenian basin: new data from detrital zircons sampled in the Sardinia-Corsica Block and in the Calabria-Peloritain Arc

    NASA Astrophysics Data System (ADS)

    Pavanetto, Pamela; Funedda, Antonio; Matteini, Massimo; Loi, Alfredo

    2013-04-01

    Geodynamic models and palinspastic reconstructions of pery-Thyrrenian terranes in the Western Mediterranean area are still extremely complex and speculative (Stampfly & Borel 2002, Trombetta et al., 2004; Alvarez & Shimabukuro, 2009; Carminati et al., 2012).A contribute can be done by considering the relationships between Sardinia-Corsica Block (SCB) and Calabria-Peloritain Arc (CPA). They shared a similar Variscan evolution and were the western part of the Briançonnais plate until the opening of the Algero-Provençal Basin during Burdigalian and then were separated in Late Tertiary during the spreading of South-Tyrrhenian Basin. During this period the CPA moved southeastward, with respect to the SCB, driven by a progressive roll-back of the subducted slab. However, is still ambiguous if the CPA was a single terrane during the Middle and Late Tertiary (Amodio Morelli et alii, 1976) or formed by the amalgamation of two or more continental "terranes" that collided during the Tertiary (Bonardi et al., 1980; Scandone, 1982; Alvarez & Shimabukuro, 2009). The data about the paleo-tectonic linkages, the terranes derivations, and the tectonic setting of the SCB and CPA as peri-Tyrrhenian blocks during Tertiary are still poor. Some evidence of their early evolution could be found in coeval Tertiary deposits cropping out both in the SCB and CPA. These deposits represent the early stage of the estensional event developed in the Tyrrhenian region during late Oligocene-Lower Miocene in a broader regional context dominated by the opening of Atlantic Ocean and the resulting convergence of Europe and Apulia microplate (Oggiano et al., 2009). To improve the knowledge on this topic, combined U-Pb and Lu-Hf analyses on zircons from Tertiary detrital sediments from Sardinia, Corsica, and both North and South Calabria have been performed using a Thermo-Fisher Neptune MC-ICP-MS coupled with a Nd:YAG UP213 New Wave laser ablation system, at the Laboratory of Geochronology of the

  4. Maximum sedimentation ages and provenance of metasedimentary rocks from Tinos Island, Cycladic blueschist belt, Greece

    NASA Astrophysics Data System (ADS)

    Hinsken, Tim; Bröcker, Michael; Berndt, Jasper; Gärtner, Claudia

    2016-10-01

    U-Pb zircon ages of five metasedimentary rocks from the Lower Unit on Tinos Island (Cycladic blueschist belt, Greece) document supply of detritus from various Proterozoic, Paleozoic and Mesozoic source rocks as well as post-depositional metamorphic zircon formation. Essential features of the studied zircon populations are Late Cretaceous (70-80 Ma) maximum sedimentation ages for the lithostratigraphic succession above the lowermost dolomite marble, significant contributions from Triassic to Neoproterozoic source rocks, minor influx of detritus recording Paleoproterozoic and older provenance (1.9-2.1, 2.4-2.5 and 2.7-2.8 Ga) and a lack or paucity of zircons with Mesoproterozoic ages (1.1-1.8 Ga). In combination with biostratigraphic evidence, the new dataset indicates that Late Cretaceous or younger rocks occur on top of or very close to the basal Triassic metacarbonates, suggesting a gap in the stratigraphic record near the base of the metamorphic succession. The time frame for sediment deposition is bracketed by the youngest detrital zircon ages (70-80 Ma) and metamorphic overgrowths that are related to high-pressure/low-temperature overprinting in the Eocene. This time interval possibly indicates a significant difference to the sedimentation history of the southern Cyclades, where Late Cretaceous detrital zircons have not yet been detected.

  5. Alxa Block Provenance of Ediacaran (Sinian) Sediments in the Helanshan Area: Constraints from Hf Isotopes and U-Pb Geochronology of Detrital Zircons

    NASA Astrophysics Data System (ADS)

    Xiaopeng, D.

    2016-12-01

    The tectonic relationship between the Alxa Block and the North China Craton has long been controversial. The Helanshan area lies at the western margin of the Ordos Block and east of the Alxa Block (Fig.a), and it contains rocks of the lower Zhengmuguan and upper Tuerkeng formations that belong to the Ediacaran system. The Zhengmuguan Formation is made up of abyssal facies rocks including dolomite and glacial conglomerate with dropstones, and the Tuerkeng Formation consists of silty slate of the neritic facies. A discontinuity marks the boundary between the Tuerkeng Formation and the Early Cambrian Suyukou Formation, which is composed mainly of pebbly sandstone towards the base and sandstone towards the top, representing a change in sedimentary facies from terrestrial to littoral.The Neoproterozoic U-Pb ages of zircons from the Ediacaran and Early Cambrian sediments peak at 818 ± 4 Ma (n = 88) and 905 ± 8 Ma (n = 20), consistent with the Neoproterozoic age peaks found in the Precambrian basement of the Alxa Block(Fig.b). There are few Neoproterozoic zircons in the Neoproterozoic strata of the Langshan area, and there are no reports of Neoproterozoic zircons in the Zhuozishan area, northwest of Helanshan, or in the western margin of the neighboring Ordos Basin. A number of Neoproterozoic zircons are found in the Middle Cambrian to Middle Ordovician strata of the Niushoushan area. And while Niushoushan is part of the Hexi Corridor, it did not amalgamate with the NCC before the Early-Middle Cambrian. Therefore, the Neoproterozoic and Early Cambrian sediments in Helanshan record information about Neoproterozoic magmatic events in the Alxa Block, and indicate an Alxa Block provenance(Fig.c).The Hf isotopic characteristics of the Neoproterozoic zircons from the Ediacaran Zhengmuguan Formation in the Helanshan area (eHf(t) = -7.812 to 3.274, TDMC = 2211-1578 Ma, n = 10) are similar to those Neoproterozoic igneous zircons from the Langshan area (eHf(t) = -1.105 to 5

  6. Evaluating Rifean Corridor Closure using Detrital Zircon Sediment Provenance of the Taza-Guercif Basin, Morocco

    NASA Astrophysics Data System (ADS)

    Pratt, J. R.; Barbeau, D. L.; Emran, A.

    2013-12-01

    -ICP-MS detrital zircon analysis of 10 samples from the basin-fill and 3 samples from two separate domains within the Rif. The new data reveal a lack of dramatic shifts in provenance within the basin-fill tied to corridor closure but instead reveal more subtle changes in peak zircon ages. Peak age shifts from 600 Ma to 700 Ma periodically within the strata in both open marine marls and within turbidites derived from the Middle Atlas in a pattern consistent with changes in basin bathymetry. Basin samples show an age-distribution consistent with the Rifean samples, which acquire an slight overprinting of Middle Atlas ages in the latter half of the succession. The data point to a progressive closure of the corridor through the advancement of the Rifean orogenic wedge with minor influence from uplift within the core of the Middle Atlas without a major shift in provenance during rapid basin emergence.

  7. The synrift evolution of the early Domeyko Basin (Domeyko Range, northern Chile): Coupling detrital 40Ar-39Ar white mica and U-Pb zircon analysis into a tectonostratigraphic framework

    NASA Astrophysics Data System (ADS)

    Espinoza, M. E.; Oliveros, V.; Solari, L.

    2017-12-01

    Compressional tectonics that shaped the western flank of the Andes seems to have been strongly influenced by the heritage of extensional basins developed during the break-up of Gondwana. However, major questions remain about the exact timing, architecture and driving mechanism of these basins (subduction-related rift versus continental rift). In this work, we coupled U-Pb detrital zircon (DZ) and 39Ar-40Ar in detrital muscovites (DM) into a tectonostratigraphic framework in order to unravel the synrift evolution of the Domeyko Basin (northern Chile, 24° - 26° S). U-Pb data indicate that the rifting in the Domeyko Basin occurred in two stages; a first from ca. 240-225 Ma which led to the formation of the Sierra Exploradora sub-basin (SESB) and a second from ca. 217-200 Ma, opening the Sierra de Varas sub-basin (SVSB) and reactivating the SESB. The competition between mechanical subsidence and the volcanic supply rates in these magma-rich depocenters, led to the dominance of the inter-eruption period in the SVSB and a predominance of the syn-eruptive period along the SESB. Geochronology of detrital minerals deposited during the second rift stage reveal significant differences between both sub-basins. At the SVSB, DZ ages show a main peak at ca. 285-295 Ma and much younger WDM ages, with a main peak close to ca. 200 Ma, slightly younger than the depositional age at ca. 213-210 Ma, likely due to partial resetting of the WDM ages by burial. A lack of muscovite-bearing plutonic sources of 230-200 Ma, leads us to interpret that WDM ages indicate a significant cooling of the Permian plutonic sources close to the basin aperture. On the contrary, along the SESB, WDM ages (260-265 Ma) are only slightly younger than DZ ages (280-270 Ma). The small difference between the WDM and the DZ ages, points to a rapid cooling of plutonic source rocks at ca. 260 Ma, coinciding with the age of the San Rafael orogenic phase in northern Chile. DZ data of the Domeyko Basin show a

  8. Zircon U-Pb ages and Hf-O isotopic composition of migmatites from the Zanjan-Takab complex, NW Iran: Constraints on partial melting of metasediments

    NASA Astrophysics Data System (ADS)

    Moghadam, Hadi Shafaii; Li, Xian-Hua; Stern, Robert J.; Ghorbani, Ghasem; Bakhshizad, Farzaneh

    2016-01-01

    We study migmatites and other metamorphic rocks in the Zanjan-Takab region of NW Iran and use these results to report the first evidence of Oligocene core complex formation in Iran. Four samples of migmatites associated with paragneisses, including leucosomes and associated para-amphibolite melanosomes were selected for U-Pb dating and Hf-O isotopic analysis. Zircon cores - interpreted as originally detrital zircons - have variable ages that peak at ca. 100-110 Ma, but their sedimentation age - indicated by the youngest 206Pb/238U ages - is ca. 35-40 Ma. New zircons associated with incipient melting occur as overgrowths around zircon cores and/or as newly grown grains. Morphologies and internal structures suggest that rim growth and formation of new zircons were associated with partial melting. All four samples contain zircons with rims that yield 206Pb/238U ages of 28-25 Ma, indicating that partial melting occurred in Late Oligocene time. δ18O values for zircon rims vary between 8.2 and 12.3‰, significantly higher than expected for mantle inputs (δ18O 6‰) and consistent with equilibrium with surface materials. Zircon rims yield εHf(t) between 2.2 and 12.4 and two-stage Hf model ages of 448-562 Ma, indicating that the region is underlain by Cadomian-Caledonian crust. According to the Hf-O isotopic values, the main mechanism forming zircon rims was dissolution of pre-existing detrital zircons with reprecipitation of new zircon shortly thereafter. Oligocene ages indicate that partial melting accompanied core complex formation in the Zanjan-Takab region. Extension, melting, and core complex formation in south-central Iran are Eocene in age, but younger ages of Oligocene-Miocene in NW Iran and Turkey indicate that extension was distributed throughout the region during Cenozoic time.

  9. Advances and limitations on interpreting the erosional record from isotopic analysis of single detrital mineral grains

    NASA Astrophysics Data System (ADS)

    Parrish, Randall

    2010-05-01

    The analysis of provenance of clastic sediments is useful for reconstructing the characteristics and rates of exhumation of source areas, and sometimes placing minimum age constraints on depositional age. Due largely to increased availability and ease of access to LA-ICP-MS instrumentation, the analysis of provenance using single detrital accessory minerals has grown very rapidly over recent years. With this however is a culture of casual users who may not fully appreciate subtleties of measurement and isotope interpretation. The isotopic provenance literature is dominated by zircon-centric studies that use U-Pb dating and Hf isotope measurements of single zircons, but unfortunately an increasing number of these studies appear to lack sufficient understanding of U-Pb and Hf systematics; misleading interpretations are increasingly common. The inherent information contained in detrital accessory minerals is potentially immense, scientifically, but comprehensive interpretations attempting to reconstruct the geological make-up and evolution of sources require dating of multiple types of accessory minerals (i.e. zircon, titanite, monazite, garnet inclusions, micas, allanite, rutile, apatite) by various methods (U-Pb, fission track, Ar-Ar…) at times accompanied by isotope geochemical data (Lu-Hf, Sm-Nd, Rb-Sr) of phases where Sr, Hf, or REE comprise a major element (≥0.5%). Many approaches have been demonstrated but the mix of methodologies needs to be tailored to the problem, in view of the variable effort and expense needed to acquire good datasets. To date there are few comprehensive multi-mineral, multi-isotope system applications, and too many studies that follow a prescriptive cookbook that lacks innovation and fails to address a problem. The field needs to focus effort on the approaches that can solve a problem well rather than doing either just the easy methods or too many methods only moderately well. Zircon studies require strategies that reduce or

  10. A Further Investigation of the Exceptional Zircon Aggregate in Lunar Thin Section 73235,82

    NASA Technical Reports Server (NTRS)

    Pidgeon, R. T.; Nemchin, a. A.; Meyer, C.

    2005-01-01

    Introduction: Smith et al. described an exceptional zircon assemblage in thin section 82 from lunar breccia 73235 which, in transmitted light, resembles a cluster of pomegranate seeds, situated in a clast dominated by bytownite (Fig.1). They reported that high-contrast back-scattered electron (BSE) images of the zircon assemblage clearly show an overgrowth around most of the crystals. Most significantly these authors reported that the age of the rims of ca 4.18Ga is 120 million years younger than age of the interiors, dated at ca 4.31Ga. Smith et al. concluded that ca 4.31 billion years ago a relatively large (500+micron) zircon crystallized within a clast of Ca rich plagioclase. The zircon was fractured into numerous smaller crystals and was subsequently overgrown by a second generation of zircon at approximately 4.18Ga.

  11. Triassic arc-derived detritus in the Triassic Karakaya accretionary complex was not derived from either the S Eurasian margin (Istanbul terrane) or the N Gondwana margin (Taurides)

    NASA Astrophysics Data System (ADS)

    Ustaömer, Timur; Ayda Ustaömer, Petek; Robertson, Alastair H. F.; Gerdes, Axel; Zulauf, Gernold

    2014-05-01

    We present new U-Pb zircon source age data for Upper Triassic sandstones of the Istanbul Terrane (S Eurasian margin) and also for Triassic sandstones of the Taurides (N Gondwana margin). The main aim is to detect and quantify the contribution of Triassic magmatism as detritus to either of these crustal blocks. This follows the recent discovery of a Triassic magmatic arc source for the Triassic sandstones of the Palaeotethyan Karakaya subduction-accretion complex (Ustaömer et al. 2013; this meeting). Carboniferous (Variscan) zircon grains also form a significant detrital population, plus several more minor populations. Six sandstone samples were studied, two from the İstanbul Terrane (Bakırlıkıran Formation of the Kocaeli Triassic Basin) and four from the Tauride Autochthon (latest Triassic Üzümdere Formation and Mid-Triassic Kasımlar Formations; Beyşehir region). Detrital zircon grains were dated by the laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS) U-Pb method at Goethe University, Frankfurt. Our results do not reveal Triassic detritus in the Üzümdere Formation. The U-Pb age of the analysed zircon grains ranges from 267 Ma to 3.2 Ga. A small fraction of Palaeozoic zircons are Permian (267 to 296 Ma), whereas the remainder are Early Palaeozoic. Ordovician grains (4%) form two age clusters, one at ca. 450 Ma and the other at ca. 474 Ma. Cambrian-aged grains dominate the zircon population, while the second largest population is Ediacaran (576 to 642 Ma). Smaller populations occur at 909-997 Ma, 827-839 Ma, 1.8-2.0 Ga and 2.4-2.6 Ga. The sandstones of the Kasımlar Formation have similar zircon age cluster to those of the somewhat younger Üzümdere Formation, ranging from 239 Ma to 2.9 Ga. A few grains gave Anisian ages. Cambrian zircon grains are less pronounced than in the Kasımlar Formation compared to the Üzümdere Formation. The detrital zircon record of Tauride sandstones, therefore, not indicates significant contribution

  12. The southwestern extension of the Jiao-Liao-Ji belt in the North China Craton: Geochronological and geochemical evidence from the Wuhe Group in the Bengbu area

    NASA Astrophysics Data System (ADS)

    Liu, Chaohui; Zhao, Guochun; Liu, Fulai; Cai, Jia

    2018-04-01

    The Wuhe complex is located at the southeastern margin of the North China Craton. The complex consists of metamorphosed Paleoproterozoic potassic granitoids and supracrustal rocks, of which the latter include the Fengyang and Wuhe groups. Meta-mafic rocks from the lower Wuhe Group have igneous zircon U-Pb ages of 2126 ± 37 Ma with εHf(t) values of -6.22 to +8.38, and xenocrystic zircons of 2.39-2.36 Ga, 2.55-2.54 Ga and 2.77-2.69 Ga. Geochemically, the meta-mafic rocks can be classified into two groups. Group 1 island arc tholeiites display flat to slightly right declined REE patterns and moderately negative Nb, Ta, Zr, and Ti anomalies. Group 2 mature arc calcalkaline basalts display strongly fractionated chondrite-normalized REE patterns and evidently negative Nb, Ta and Ti anomalies. These meta-mafic rocks formed by partial melting of sub-arc depleted mantle wedge which had been modified by slab-derived melts at an active continental margin. Depositional age of the group can be constrained in the period of 2.16-2.10 Ga based on ages of the youngest detrital zircons and latter intrusions. U-Pb ages of detrital zircons yield major age peaks of 2.69 Ga and 2.52 Ga, with minor peaks at 2.88 Ga, 2.78 Ga, 2.35 Ga and 2.17 Ga, most of which are derived from the late Mesoarchean to early Paleoproterozoic granitoids in the Wuhe complex and the Jiaodong Terrane. Metamorphic zircons in the marbles coexisting with garnet amphibolites or granulites occur as either single grains or overgrowth (or recrystallization) rims surrounding magmatic zircon cores and yield ages of 1882 ± 19 Ma to 1844 ± 15 Ma. The comparable ca. 2.1 Ga potassic granites with A-type granite affinity, the ca. 2.1 Ga meta-mafic rocks with arc-like geochemical features, the 2.1-1.9 Ga meta-sedimentary units and the 1.9-1.8 Ga subduction- and collision-related granulite-facies metamorphism suggest that the Wuhe complex and the Jiao-Liao-Ji Belt share the same late Paleoproterozoic tectonic evolution

  13. Detrital provenance constraints from the Austral (Magallanes) Basin on dynamic changes in orogenic paleogeography during Cenozoic growth and denudation of the Patagonian Andes

    NASA Astrophysics Data System (ADS)

    Fosdick, J. C.; Leonard, J. S.; Bostelmann, J. E.; Ugalde, R.; Schwartz, T.

    2015-12-01

    The topographic development of the Patagonian Andes is influenced by crustal shortening, magmatism, asthenospheric mantle upwelling, climate, and erosion - yet knowledge of how these processes interact is hindered by an incomplete understanding of the timing and tempo of deformation and erosion. We report new detrital zircon U/Pb geochronology and sedimentology from the Cenozoic Austral (Magallanes) foreland basin in Argentina and Chile (near 51°S) that record changes in orogenic paleogeography during uplift of the Patagonian Andes. Near Cerro Castillo, Chile, zircons from deltaic and estuarine sandstones of the Cerro Dorotea Fm. indicate sedimentation ~60-61 Ma, revising the long-held Danian age assignment based on the foraminiferal content. Lower Eocene (47-46 Ma) zircons constrain the age of the overlying unit, the deltaic lower Río Turbio Fm., which shares sedimentological, paleontological, and provenance affinity with the northern Man Aike Fm. Deposition of the upper Río Turbio Fm. in Argentina occurred during the Eocene-Oligocene transition ~33-34 Ma and continued until ~26 Ma. Deposition of the Río Guillermo Fm. resumed ~23.5 Ma with the first occurrence of fluvial sedimentation that continued until the marine Patagonian transgression ~21-19 Ma at this location. Detrital zircon ages reveal upsection reduction in Late Jurassic and Paleozoic igneous sources, variable contributions of Late Cretaceous zircons, and younging of arc-derived zircons. Combined with published bedrock thermochronology and structural data, we suggest that early Miocene faulting and exhumation of the thrust-belt resulted in drainage reorganization and eastward shift in the drainage divide to the central domain, isolating the retroarc basin from the Jurassic Tobífera thrust sheets. Revised timing of sedimentation and changes in upland source areas during Paleocene-Miocene time reveals a complex relationship between basin evolution, Cenozoic climate, and phases of Andean tectonic

  14. The first discovery of Hadean zircon in garnet granulites from the Sutam River (Aldan Shield)

    NASA Astrophysics Data System (ADS)

    Glukhovskii, M. Z.; Kuz'min, M. I.; Bayanova, T. B.; Lyalina, L. M.; Makrygina, V. A.; Shcherbakova, T. F.

    2017-09-01

    For the first time in Russia, a Hadean zircon grain with an age of 3.94 Ga (ID-TIMS) has been discovered in high-aluminous garnet granulites of the Aldan Shield among the U-Pb zircons with an age from 1.92 Ga. In this connection, the problems of its parental source, the petrogenesis of granulites that captured this zircon, and the mechanism of occurrence of these deep rocks in the upper horizons of the crust have been solved. The comparison of the geochemistry of garnet granulites and the middle crust has shown that the granulites are enriched in the entire range of rare-earth elements (except for the Eu minimum), as well as in Al2O3, U, and Th and are depleted in the most mobile elements (Na, Ca, Sr). In the upper part of the allitic weathering zone of the middle crust, which formed under conditions of arid climate, this zircon grain was originated from the weathered granites from the middle crust. In the latter case, they were empleced discretely in the upper granite-gneiss crust under high pressure conditions (the rutile age is 1.83-1.82 Ga). The zircon with an age of 3.94 Ga is comparable to the Hadean zircons from orthogneisses of the Acasta region (Canadian Shield, 4.03-3.94 Ga).

  15. Integrated Laser Ablation U/Pb and (U-Th)/He Dating of Detrital Accessory Minerals from the Naryani River, Central Nepal

    NASA Astrophysics Data System (ADS)

    Horne, A.; Hodges, K. V.; Van Soest, M. C.

    2015-12-01

    The newly developed 'laser ablation double dating' (LADD) technique, an integrated laser microprobe U/Pb and (U-Th)/He dating method, could be an exceptionally valuable tool in detrital thermochronology for identifying sedimentary provenance and evaluating the exhumation history of a source region. A recent proof-of-concept study has used LADD to successfully date both zircon and titanite crystals from the well-characterized Fish Canyon tuff, but we also believe that another accessory mineral, rutile, could be amenable to dating via the LADD technique. To continue the development of the method, we present an application of LADD to detrital zircon, titanite, and rutile from a sample collected on the lower Naryani River of central Nepal. Preliminary analyses of the sample have yielded zircon U/Pb dates ranging from 31.4 to 2405 Ma; zircon (U-Th)/He from 1.8 to 15.4 Ma; titanite U/Pb between 18 and 110 Ma; titanite (U-Th)/He between 1 and 16 Ma; rutile U/Pb from 6 to 45 Ma; and rutile (U-Th)/He from 2 to 25 Ma. In addition to the initial data, we can use Ti-in-zircon, Zr-in-titanite, and Zr-in-rutile thermometers to determine the range of possible long-term cooling rates from grains with U/Pb ages younger than collision. Thus far our results from zircon analyses imply a cooling rate of approximately 15°C/Myr; titanite analyses imply between 10 and 67°C/Myr; and rutile between 9 and 267°C/Myr. This spread in potential cooling rates, especially in the order of magnitude differences of cooling rates calculated from the rutile grains, suggests that the hinterland source regions of the Naryani river experienced dramatically different exhumation histories during Himalayan orogenisis. Ongoing analyses will expand the dataset such that we can more adequately characterize the range of possibilities represented in the sample.

  16. Precambrrian crustal evolution in the great falls tectonic zone

    NASA Astrophysics Data System (ADS)

    Gifford, Jennifer N.

    The Great Falls Tectonic Zone (GFTZ) is a zone of northeast trending geological structures in central Montana that parallel structures in the underlying basement. U-Pb zircon and Nd isotopic data from the Little Belt Mountains (LBM) suggest that the GFTZ formed at ~1.86 to 1.80 Ga due to ocean subduction followed by collision between the Archean Wyoming Province (WP) and Medicine Hat Block (MHB). This study characterizes the GFTZ basement by geochronological and geochemical analysis of crustal xenoliths collected from Montana Alkali Province volcanics and exposed basement rock in the Little Rocky Mountains (LRM). Xenoliths collected from the Grassrange and Missouri Breaks diatremes and volcanics in the Bearpaw and Highwood Mountains have igneous crystallization ages from ~1.7 Ga to 1.9 Ga and 2.4 Ga to 2.7 Ga, and metamorphic ages from ~1.65 Ga to 1.84 Ga. Zircon Lu-Hf and whole-rock Sm-Nd data indicate that the xenoliths originated from reworked older continental crust mixed with mantle-derived components in all cases. Trace element patterns show fluid mobile element enrichments and fluid immobile element depletions suggestive of a subduction origin. Igneous ages in the LRM range older, from ~2.4 Ga to 3.2 Ga. Geochemical evidence suggests that the LRM meta-igneous units also formed in a subduction setting. Detrital zircon ages span the early Paleoproterozoic to Mesoarchean, with abundant 2.8 Ga ages. Zircon U-Pb igneous crystallization age data from xenoliths and the LRM are consistent with U-Pb zircon igneous crystallization ages from the MHB, suggesting that this segment of the GFTZ shares an affinity with concealed MHB crust. Published detrital zircon ages from the northern Wyoming Province reveal more abundant >3.0 Ga ages than the MHB or GFTZ samples. These geochronologic and geochemical data from the xenoliths and LRM samples allow for a refined model for crustal evolution in the GFTZ. Subduction under the Neoarchean to Paleoproterozoic crust of the MHB

  17. New Zircon U-Pb Age Constrain of the Origin of Devil's River Uplift (SW Texas) and Insights into the Late Proterozoic and Paleozoic Evolution of the Southern Margin of Laurentia

    NASA Astrophysics Data System (ADS)

    Rodriguez, E.; Dickerson, P. W.; Stockli, D. F.

    2017-12-01

    The Devils River Uplift (DRU) in SW Texas records the evolution of the southern Laurentian margin from Grenvillian orogenesis and assembly of Rodinia, to its fragmentation by rifting, and to the amalgamation of Pangaea. It was cored by a well (Shell No. 1 Stewart), penetrating Precambrian gneisses and Cambrian metasediments and sandstones. New zircon LA-ICP-MS data from a total of 10 samples elucidate the crystallization and depositional ages, as well as the detrital provenance, of Precambrian and Cambrian rocks from the DRU. Zircons from five Precambrian crystalline basement samples (6000-9693') yield uniform U-Pb crystallization ages of 1230 Ma that are similar to ages for young gneisses of the Valley Spring Domain (Llano uplift) in central Texas, where they mark the cessation of arc magmatism within the Grenville orogenic belt. The 1230 Ma igneous basement is overlain by L.-M. Cambrian metasedimentary rocks ( 4000-6000') with maximum depositional ages of 533-545 Ma. Detrital zircons from Cambrian strata are dominated by a 1070-1080 Ma population, likely derived from basement units exposed in Texas (Llano uplift, Franklin Mts.), with minor contributions from local 1230 Ma Precambrian basement and the 1380-1500 Ma Granite Rhyolite Province. The L.-M. Cambrian interval is dominated (>80%) by Neoproterozoic detrital magmatic zircons with two major distinct age clusters at 570-700 Ma and 780-820 Ma, supporting a two-stage Rodinia rift model and providing strong evidence for major Cryogenian-Eocambrian intraplate magmatism along the southern margin of Rodinia. Moreover, detrital zircon signatures for L.-M. and U. Cambrian strata strongly correlate with those from the Cuyania terrane of W. Argentina - notably the W. Sierras Pampeanas (Sa. Pie de Palo, Sa. de Maz): 1230 Ma from metasandstones (PdP); 1081-1038 Ma from metasiliciclastics (PdP, SdM); Cryogenian-Eocambrian [774 & 570 Ma] plutons (SdM, PdP). In summary, these new zircon U-Pb data from DRU in SW Texas show

  18. Detrital Zircon Provenance response to slip transfer from the San Gabriel Fault to the San Andreas Fault in Late Miocene-Early Pliocene Ridge Basin, southern California

    NASA Astrophysics Data System (ADS)

    Zhao, V.; Cohen, H.; Cecil, R.; Heermance, R. V., III

    2016-12-01

    The San Andreas Fault (SAF) in southern California has created a dynamic plate-boundary that has controlled basin depocenters, fluvial systems, and range uplift since the early Miocene. From 11-5 Ma, dextral slip was localized along the San Gabriel Fault (SGF) north of Los Angeles. Slip was transferred onto the SAF in the Late Miocene or Early Pliocene, but the timing and landscape implications of this tectonic reorganization are not well constrained. We use detrital zircon (DZ) geochronology from the Ridge Basin, located at the nexus of the SGF and SAF, to determine the provenance of stratigraphy during this fault reorganization. We present data from two samples (n=187) from Middle to Upper Miocene Ridge Route Formation (RRF) and four samples (n=483) from Pliocene Hungry Valley Formation (HVF) of Ridge Basin Group. All Ridge Basin samples have peaks at ca. 1.7 Ga, though the relative proportion of Precambrian grains decreases upsection. RRF samples have two dominant Mesozoic peaks at ca. 150 Ma and at ca. 80 Ma. HVF has peak ages of 145-135 Ma and ca. 77 Ma. HVF samples also have Triassic peaks at 235-220 Ma, which is absent in the RRF. To evaluate the provenance of these samples, modern sands were collected from five major drainages in the San Gabriel (SGM, n=181), the San Bernardino Mountains (SBM, n=258) and a rock sample from the Middle Miocene Crowder Formation (n=99) between the ranges. DZ spectra of the RRF is dissimilar to that of modern rivers draining the SGM, although we acknowledge that a more proximal source from the western Transverse Ranges or Sierra Pelona is possible. The source for HVF is more problematic, in that the DZ spectra of the HVF is unlike that of all modern rivers and Crowder Formation. Triassic zircons combined with the presence of unique volcanic clasts suggest a source from the Granite Mountain area in the Mojave Desert. The differences in DZ spectra between RRF and HVF suggests that the transfer of slip from the SGF to the SAF in

  19. Impact of mineral fertility and bedrock erosion on single-mineral detrital studies: insights from trace-element and Nd-isotope systematics of detrital apatite from the Po River catchment

    NASA Astrophysics Data System (ADS)

    Malusa', Marco Giovanni; Wang, Jiangang; Garzanti, Eduardo; Villa, Igor M.; Wittman, Hella

    2017-04-01

    The detrital record provides an archive of mountain erosion that preserves key information for paleotectonic and paleoclimatic reconstructions. Detrital studies are often based on single-mineral analyses (e.g., geo/thermochronologic analyses on apatite and zircon). Their geologic interpretation can be challenging, because the impact of each eroding source on the detrital record is controlled by a range of factors including the rate of erosion and the fertility of chosen minerals in eroded bedrock. Here, we combine (i) a state-of-the art dataset of trace element and Nd isotope fingerprints of detrital apatite, (ii) a comprehensive dataset of apatite-fertility measurements (Malusà et al. 2016), (iii) fission-track data, and (iv) cosmogenic-derived erosion rates from the Po River catchment (Wittmann et al. 2016), to test the impact of mineral fertility and bedrock erosion on the single-mineral detrital signal preserved in the final sediment sink. Our results show that the information provided by accessory minerals, when complemented with accurate mineral fertility measurements, are fully consistent with information provided by the analysis of more abundant framework minerals. We found that trace element and Nd isotope analyses provide a reliable tool to disentangle the complex single-mineral record of orogenic erosion, and demonstrate that such a record is largely determined by high-fertility source rocks exposed within the drainage. Detrital thermochronology studies based on the lag-time approach should thus preferably include independent provenance discriminations and a full mineral fertility characterization of the potential source areas, in order to ensure a correct identification of the sediment sources and of the exogenic and endogenic processes monitored in the stratigraphic archive. Malusà M.G., Resentini A., Garzanti E., 2016. Hydraulic sorting and mineral fertility bias in detrital geochronology. Gondwana Res., 31, 1-19 Wittmann H., Malusà M.G., Resentini

  20. Zircon evidence for incorporation of terrigenous sediments into the magma source of continental basalts.

    PubMed

    Xu, Zheng; Zheng, Yong-Fei; Zhao, Zi-Fu

    2018-01-09

    Crustal components may be incorporated into continental basalts by either shallow contamination or deep mixing. While the former proceeds at crustal depths with common preservation of refractory minerals, the latter occurs at mantle depths with rare survival of relict minerals. Discrimination between the two mechanisms has great bearing to subcontinental mantle geochemistry. Here we report the occurrence of relict zircons in Cenozoic continental basalts from eastern China. A combined study of zircon U-Pb ages and geochemistry indicates that detrital zircons were carried by terrigenous sediments into a subcontinental subduction zone, where the zircon were transferred by fluids into the magma sources of continental basalts. The basalts were sampled from three petrotectonic units with distinct differences in their magmatic and metamorphic ages, making the crustal contamination discernible. The terrigenous sediments were carried by the subducting oceanic crust into the asthenospheric mantle, producing both soluble and insoluble materials at the slab-mantle interface. These materials were served as metasomatic agents to react with the overlying mantle wedge peridotite, generating a kind of ultramafic metasomatites that contain the relict zircons. Therefore, the occurrence of relict zircons in continental basalts indicates that this refractory mineral can survive extreme temperature-pressure conditions in the asthenospheric mantle.

  1. 3.3 Ga SHRIMP U-Pb zircon age of a felsic metavolcanic rock from the Mundo Novo greenstone belt in the São Francisco craton, Bahia (NE Brazil)

    NASA Astrophysics Data System (ADS)

    Peucat, J. J.; Mascarenhas, J. F.; Barbosa, J. S. F.; de Souza, S. L.; Marinho, M. M.; Fanning, C. M.; Leite, C. M. M.

    2002-07-01

    Felsic metavolcanics associated with supracrustal rocks provide U-Pb zircon and Sm-Nd TDM ages of approximately 3.3 Ga, which establish an Archean age of the Mundo Novo greenstone belt. A granodioritic gneiss from the Mairi complex, located on the eastern boundary of the Mundo Novo greenstone belt, exhibits a zircon evaporation minimum age of 3.04 Ga and a Nd model age of 3.2 Ga. These results constrain the occurrence of at least three major geological units in this area: the Archean Mundo Novo greenstone belt, the Archean Mairi gneisses, and the adjoining Paleoproterozoic (<2.1 Ga) Jacobina sedimentary basin. The Jacobina basin follows the same trend as the Archean structure, extending southward to the Contendas-Mirante belt, in which a similar Archean-Paleoproterozoic association appears. We postulate that during the Paleoproterozoic in the eastern margin of the Gavião block, these Archean greenstone belts constituted a zone of weakness along which a late-stage orogenic sedimentary basin developed.

  2. New Robust Reference Materials for In Situ Single Grain Rutile U-Pb Geochronology and Method Refinements for Detrital Rutile Analysis by LA-MC-ICP-MS

    NASA Astrophysics Data System (ADS)

    Parrish, R. R.; Bracciali, L.; Condon, D. J.; Horstwood, M. S.; Najman, Y.

    2012-12-01

    While rutile (TiO2) occurs in the heavy mineral suite of detrital sediments and originates mainly in medium- to high-grade metamorphic and some igneous rocks, there are very few applications of U-Pb dating of rutile to provenance studies; this is due to an overreliance on zircon, low U content of rutile limiting measurement quality by in situ methods, a higher proportion of common Pb relative to zircon, and a lack of widely available good quality reference materials. We have addressed these issues and characterized two ~ 1.8 Ga rutile reference materials by SEM, trace elements, U-Pb ID-TIMS, and intra-grain and inter-grain U-Pb LA-MC-ICP-MS analysis using mixed faraday and multiple ion counting detectors with high sensitivity. We have assessed U-Pb discordance and in situ variations in relative common Pb and age and their bearing on the quality of the reference materials for in situ U-Pb dating. The rutiles (Sugluk-4 and PCA-S207) come from granulite facies belts of the Canadian Shield, namely the northern Cape Smith Belt of Quebec and the Snowbird Tectonic Zone (Sasatchewan). The ID-TIMS data are slightly discordant due to variable common Pb and limited Pb loss; the variation in 6 single grains of Sugluk-4, that we use as the primary reference material, is <1% in 206Pb/238U, and <2% for 207Pb/206Pb (95 % conf.); after common Pb correction these variations are <1%. The measured variations are smaller than in existing reference materials (i.e. R10) in current use. LA-ICP-MC-MS data (n ~ 500 for each) have a reproducibility of 206Pb/238U and 207Pb/206Pb of ~2-4% (at the 2S level), which is only modestly worse than long-term data for multiple zircon standards, this being due to the real variation in measured values arising from limited Pb loss, age variation, and common Pb variability [1]. We have applied our refined method to the provenance of rutile from drainages from British Columbia, Bhutan, and the Brahmaputra River of NE India (predominant rutile ages ~ 50, 15

  3. 2.9, 2.36, and 1.96 Ga zircons in orthogneiss south of the Red River shear zone in Viet Nam: evidence from SHRIMP U-Pb dating and tectonothermal implications

    NASA Astrophysics Data System (ADS)

    Nam, Tran Ngoc; Toriumi, Mitsuhiro; Sano, Yuji; Terada, Kentaro; Thang, Ta Trong

    2003-05-01

    Orthogneissic rocks coexisting with migmatites and containing small amphibolite lenses are exposed in the center of the metamorphic belt which runs parallel to the Day Nui Con Voi-Red River shear zone in northern Viet Nam. The orthogneiss complex has given some radiogenic dates of Early Proterozoic and Late Archean, which are the oldest ages ever registered for the Southeast Asian continent. Zircon grains separated from three samples of the orthogneiss complex have been dated to establish the protolith age and the timing of high-grade tectonothermal events in the complex. Sixty-five SHRIMP U-Th-Pb analyses of these zircons define three age groups of 2.84-2.91, 2.36, and 1.96 Ga. The age groups correspond to three periods of zircon generation. The oldest ˜2.9 Ga cores indicate a minimum age for the protolith of the orthogneiss complex. Two younger generations (including ˜2.36 Ga outer-cores and ˜1.96 Ga rims) probably grew during later high-grade tectono-metamorphic events, which were previously suggested by K-Ar and 40Ar/ 39Ar cooling ages of ˜2.0 Ga for synkinematic hornblendes. An early thermal history of the orthogneiss complex has been constrained, including a primary magma-crystallization stage starting at ˜2.9 Ga, followed by two Early Proterozoic (˜2.36 and ˜1.96 Ga) high-grade tectonothermal events. The ca. 2.9 Ga protolith age of the orthogneiss complex documented in this study provides new convincing evidence for the presence of Archean rocks in Indochina, and clearly indicates that the crustal evolution of northern Viet Nam started as early as Late Archean time.

  4. Cenozoic exhumation and tectonic evolution of the Qimen Tagh Range, northern Tibetan Plateau: Insights from the heavy mineral compositions, detrital zircon U-Pb ages and seismic interpretations

    NASA Astrophysics Data System (ADS)

    Zhu, W.; Wu, C.; Wang, J.; Zhou, T.; Zhang, C.; Li, J.

    2017-12-01

    The Qaidam Basin is the largest intermountain basin within the Tibetan Plateau. The Cenozoic sedimentary flling characteristics of the basin was significantly influenced by the surrounding tectonic belt, such as the Altyn Tagh Range to the north-west and Qimen Tagh Range to the south. The tectonic evolution of the Qimen Tagh Range and the structural relationship between the Qaidam Basin and Qimen Tagh Range remain controversial. To address these issues, we analyzed thousands of heavy mineral data, 720 detrital zircon ages and seismic data of the Qaidam Basin. Based on the regional geological framework and our kinematic analyses, the Cenozoic tectonic evolution of the Qimen Tagh Range can be divided into two stages. From the Early Eocene to the Middle Miocene, the Devonian (400-360 Ma) and Permian to Triassic (300-200 Ma) zircons which were sourced from the Qimen Tagh Range and the heavy mineral assemblage of zircon-leucoxene-garnet-sphene on the north flank of the Qimen Tagh Range indicated that the Qimen Tagh Range has been exhumed before the Eocene and acted as the primary provenance of the Qaidam Basin. The Kunbei fault system (i.e. the Kunbei, Arlar and Hongliuquan faults) in the southwest of the Qaidam Basin, which can be seen as a natural study window of the Qimen Tagh Range, was characterized by left-lateral strike-slip faults and weak south-dipping thrust faults based on the seismic sections. This strike-slip motion was generated by the uplift of the Tibetan Plateau caused by the onset of the Indian-Eurasian collision. Since the Middle Miocene, the primary mineral assemblages along the northern flank of the Qimen Tagh Range changed from the zircon-leucoxene-garnet-sphene assemblage to the epidote-hornblende-garnet-leucoxene assemblage. Simultaneously, the Kunbei fault system underwent intense south-dipping thrusting, and a nearly 2.2-km uplift can be observed in the hanging wall of the Arlar fault. We attributed these variations to the rapid uplift event of

  5. Rifting, drifting, convergence and orogenesis: The sedimentary record of the Wernecke Supergroup on the Paleoproterozoic margin of northwestern Columbia

    NASA Astrophysics Data System (ADS)

    Furlanetto, F.; Thorkelson, D. J.; Rainbird, R.; Davis, B.; Gibson, D.; Marshall, D. D.

    2015-12-01

    The Wernecke Supergroup was deposited when the northwestern margin of Laurentia was undergoing major adjustments related to the assembly of the supercontinent Columbia (Nuna) in the late Paleoproterozoic. The succession was deposited between ca. 1663 and ca. 1620 Ma in two clastic to carbonate grand cycles. The detrital zircon population is bimodal, reflecting derivation from cratonic Laurentia. Basin shallowing at the end of the second grand cycle corresponds to a significant younging of detrital zircon populations. Specifically, the late Paleoproterozoic peak of zircon ages shifted from ca. 1900 Ma to ca. 1825 Ma, and the proportion of Archaean and early Paleoproterozoic zircon decreased. These shifts were caused by a change in drainage pattern in northern Laurentia during an early phase of the Forward orogeny, farther inland. The orogeny also led to inversion of the broadly correlative Hornby Bay Group. Zircon younger than 1.75 Ga is present throughout the sedimentary succession and may have originated from small igneous suites in northern Laurentia or larger magmatic arc terranes of the Yavapai and early Mazatzal orogenies in southern Laurentia. Eastern and southern Australia and the intervening Bonnetian arc may have contributed. The Wernecke Supergroup shares similar detrital zircon age and Nd isotope signatures with the Hornby Bay, Muskwa, Athabasca and Thelon successions of Canada; the Tarcoola Formation, Willyama Supergroup, and Isan Supergroup of Australia; and of the Dongchuan-Dahongshan-Hondo successions of South China. These similarities are compelling evidence for a shared depositional system in the late Paleoproterozoic. Western Columbia may have had a dynamic SWEAT-like configuration with Australia, East Antarctica and South China moving in a complex manner near the margin of western Laurentia. All of the continents except for South China underwent post-Wernecke tectonism during the Racklan, Forward, Olarian, Isan, Mazatzal and related orogenies, ca

  6. Usbnd Pb detrital zircon ages from some Neoproterozoic successions of Uruguay: Provenance, stratigraphy and tectonic evolution

    NASA Astrophysics Data System (ADS)

    Pecoits, Ernesto; Aubet, Natalie R.; Heaman, Larry M.; Philippot, Pascal; Rosière, Carlos A.; Veroslavsky, Gerardo; Konhauser, Kurt O.

    2016-11-01

    The Neoproterozoic volcano-sedimentary successions of Uruguay have been the subject of several sedimentologic, chrono-stratigraphic and tectonic interpretation studies. Recent studies have shown, however, that the stratigraphy, age and tectonic evolution of these units remain uncertain. Here we use new Usbnd Pb detrital zircon ages, combined with previously published geochronologic and stratigraphic data in order to provide more precise temporal constraints on their depositional age and to establish a more solid framework for the stratigraphic and tectonic evolution of these units. The sequence of events begins with a period of tectonic quiescence and deposition of extensive mixed siliciclastic-carbonate sedimentary successions. This is followed by the development of small fault-bounded siliciclastic and volcaniclastic basins and the emplacement of voluminous granites associated with episodic terrane accretion. According to our model, the Arroyo del Soldado Group and the Piedras de Afilar Formation were deposited sometime between ∼1000 and 650 Ma, and represent passive continental margin deposits of the Nico Pérez and Piedra Alta terranes, respectively. In contrast, the Ediacaran San Carlos (<552 ± 3 Ma) and Barriga Negra (<581 ± 6 Ma) formations, and the Maldonado Group (<580-566 Ma) were deposited in tectonically active basins developed on the Nico Pérez and Cuchilla Dionisio terranes, and the herein defined Edén Terrane. The Edén and the Nico Pérez terranes likely accreted at ∼650-620 Ma (Edén Accretionary Event), followed by their accretion to the Piedra Alta Terrane at ∼620-600 Ma (Piedra Alta Accretionary Event), and culminating with the accretion of the Cuchilla Dionisio Terrane at ∼600-560 Ma (Cuchilla Dionisio Accretionary Event). Although existing models consider all the Ediacaran granites as a result of a single orogenic event, recently published age constraints point to the existence of at least two distinct stages of granite generation

  7. Provenance of Carboniferous sedimentary rocks in the northern margin of Dabie Mountains, central China and the tectonic significance: constraints from trace elements, mineral chemistry and SHRIMP dating of zircons

    NASA Astrophysics Data System (ADS)

    Li, Renwei; Li, Shuangying; Jin, Fuquan; Wan, Yusheng; Zhang, Shukun

    2004-04-01

    A suite of slightly metamorphosed Carboniferous sedimentary strata occurs in the northern margin of the Dabie Mountains, central China. It consists, in ascending order, of the upper Huayuanqiang Formation (C 1), the Yangshan Formation (C 1), the Daorenchong Formation (C 1-2), the most widely distributed Huyoufang Formation (C 2) and the Yangxiaozhuang Formation (C 2). The provenance of the Carboniferous sedimentary rocks is constrained by the integration of trace elements, detrital mineral chemistry and sensitive high resolution ion microprobe (SHRIMP) dating of detrital zircons, which can help to understand the connection between the provenance and the Paleozoic tectonic evolution of the Qinling-Dabie Orogen. The trace element compositions indicate that the source terrain was probably a continental island arc. Detrital tourmalines were mainly derived from aluminous and Al-poor metapelites and metapsammites, and some are sourced from Li-poor granitoids, pegmatites and aplites. Detrital garnets, found only in the uppermost Huyoufang Formation, are almandine and Mn-almandine garnets, indicating probable sources mainly from garnetiferous schists, and partly from granitoid rocks. The detrital white K-micas are muscovitic in the Huayuanqiang, Daorenchong and Huyoufang Formations, and phengitic with Si contents (p.f.u.) from 3.20 up to max. 3.47-3.53 in the uppermost Huyoufang and the Yangxiaozhuang Formations, a meta-sedimentary source. Major components in the detrital zircon age structure for the Huyoufang Formation range from 506 to 363 Ma, centering on ˜400 and ˜480 Ma, which is characteristic of the Qinling and Erlangping Groups in the Qinling and Tongbai Mountains, central China. Evidently, the major source of the Carboniferous sedimentary rocks in the northern margin of Dabie Mountains was from the southern margin of the Sino-Korean Craton represented by the Qinling and Erlangping Groups. The source area was an island-arc system during the Early Paleozoic that

  8. Detrital-zircon geochronology of Paleozoic sedimentary rocks in the Hangay Hentey basin, north-central Mongolia: Implications for the tectonic evolution of the Mongol Okhotsk Ocean in central Asia

    NASA Astrophysics Data System (ADS)

    Kelty, Thomas K.; Yin, An; Dash, Batulzii; Gehrels, George E.; Ribeiro, Angela E.

    2008-04-01

    Understanding the development of the Central Asian Orogenic System (CAOS), which is the largest Phanerozoic accretionary orogen in the world, is critical to the determination of continental growth mechanisms and geological history of central Asia. A key to unraveling its geological history is to ascertain the origin and tectonic setting of the large flysch complexes that dominate the CAOS. These complexes have been variably interpreted as deep-marine deposits that were accreted onto a long-evolving arc against large continents to form a mega-accretionary complex or sediments trapped in back-arc to fore-arc basins within oceanic island-arc systems far from continents. To differentiate the above models we conducted U-Pb geochronological analyses of detrital-zircon grains from turbidites in the composite Hangay-Hentey basin of central Mongolia. This basin was divided by a Cenozoic fault system into the western and eastern sub-basins: the Hangay Basin in the west and Hentey basin in the east. This study focuses on the Hentey basin and indicates two groups of samples within this basin: (1) a southern group that were deposited after the earliest Carboniferous (˜ 339 Ma to 354 Ma) and a northern group that were deposited after the Cambrian to Neoproterozoic (˜ 504 Ma to 605 Ma). The samples from the northern part of the basin consistently contain Paleoproterozoic and Archean zircon grains that may have been derived from the Tuva-Mongol massif and/or the Siberian craton. In contrast, samples from the southern part of the basin contain only a minor component of early Paleozoic to Neoproterozoic zircon grains, which were derived from the crystalline basement bounding the Hangay-Hentey basin. Integrating all the age results from this study, we suggest that the Hangay-Hentey basin was developed between an island-arc system with a Neoproterozoic basement in the south and an Andean continental-margin arc in the north. The initiation of the southern arc occurred at or after the

  9. Magmatic oxygen fugacity estimated using zircon-melt partitioning of cerium

    NASA Astrophysics Data System (ADS)

    Smythe, Duane J.; Brenan, James M.

    2016-11-01

    Using a newly-calibrated relation for cerium redox equilibria in silicate melts (Smythe and Brenan, 2015), and an internally-consistent model for zircon-melt partitioning of Ce, we provide a method to estimate the prevailing redox conditions during crystallization of zircon-saturated magmas. With this approach, oxygen fugacities were calculated for samples from the Bishop tuff (USA), Toba tuff (Indonesia) and the Nain plutonic suite (Canada), which typically agree with independent estimates within one log unit or better. With the success of reproducing the fO2 of well-constrained igneous systems, we have applied our Ce-in-zircon oxygen barometer to estimating the redox state of Earth's earliest magmas. Using the composition of the Jack Hills Hadean zircons, combined with estimates of their parental magma composition, we determined the fO2 during zircon crystallization to be between FMQ -1.0 to +2.5 (where FMQ is the fayalite-magnetite-quartz buffer). Of the parental magmas considered, Archean tonalite-trondhjemite-granodiorite (TTG) compositions yield zircon-melt partitioning most similar to well-constrained modern suites (e.g., Sano et al., 2002). Although broadly consistent with previous redox estimates from the Jack Hills zircons, our results provide a more precise determination of fO2, narrowing the range for Hadean parental magmas by more than 8 orders of magnitude. Results suggest that relatively oxidized magmatic source regions, similar in oxidation state to that of 3.5 Ga komatiite suites, existed by ∼4.4 Ga.

  10. Recent exhumational pattern across the Lhasa Terrain: Revealed by detrital zircon fission track and U/Pb ages from modern fluvial sediments along Yarlung-Tsangpo, South Tibet

    NASA Astrophysics Data System (ADS)

    Huang, Shao-Yi; Chen, Yue-Gau; Liu, Tsung-Kwei; Cao, Zhongquan

    2010-05-01

    Detrital samples from the foreland basin and so forth depositional environments archive the evolutional phases of adjacent orogens. Modern fluvial sediments, similarly, provide the integrated information of exposed bedrocks in the studied drainages where sometimes few access is allowed to get the in situ samples. However, the nature of the dispersed detrital ages has long hampered our interpretation in thermal evolution and surface processes of the studied terrain, mainly spatial-wise. With suitable thermo-chronometers, multiple dated single-grain ages can shed a light on the provenance of studied grains and limit the uncertainties of plausible source areas. In this study, we present the detrital zircon fission track (ZFT) and U/Pb ages from the modern fluvial sediments collected along the Yarlung-Tsangpo and its two tributaries, Lhasa River and Nyang River. The sample collected from Lhasa River (LS) shows its ZFT age population peaks as: 1.5 Ma (2.1%), 6.8 Ma (44.5%), 11.3 Ma (34.1%), and 32.5 Ma (19.3%) while the sample collected from Nyang River ( BY) shows the age peaks as: 6.2 Ma (10.3%), 22.8 Ma (36.3%), and 51.6 Ma (53.4%). The ZFT ages are much younger than the bedrock strata of Lhasa terrain (Proterozoic to Mesozoic) and most of the intrusive Gangdese belt (Mesozoic to Mid-Miocene). So far, our U/Pb ages from LS has corresponded to published Gangdese intrusion ages and further confirm that the majority of analyzed grains exhibit consistent young ZFT ages, indicating a significant exhumational phase in the Lhasa Terrain from 15-6 Ma. However, the occurrence of this recent exhumation may not be contemporary and the magnitude must be diverse across the Lhasa Terrain. Evidently, we observe a dramatic decrease of younger ZFT age population (grain ages younger than 15 Ma) descending from ~78% in the Lhasa River drainage down to less than 15% in the Nyang River drainage. On the other hand, the older population (grain ages > 15 Ma) shifts from ~20% (Lhasa River

  11. Reworked Middle Jurassic sandstones as a marker for Upper Cretaceous basin inversion in Central Europe—a case study for the U-Pb detrital zircon record of the Upper Cretaceous Schmilka section and their implication for the sedimentary cover of the Lausitz Block (Saxony, Germany)

    NASA Astrophysics Data System (ADS)

    Hofmann, Mandy; Voigt, Thomas; Bittner, Lucas; Gärtner, Andreas; Zieger, Johannes; Linnemann, Ulf

    2018-04-01

    The Saxonian-Bohemian Cretaceous Basin (Elbsandsteingebirge, E Germany and Czech Republic, Elbtal Group) comprises Upper Cretaceous sedimentary rocks from Upper Cenomanian to Santonian age. These sandstones were deposited in a narrow strait of the sea linking the northern Boreal shelf to the southern Tethyan areas. They were situated between the West Sudetic Island in the north and the Mid-European Island in the south. As known by former studies (e.g. Tröger, Geologie 6/7:717-730, 1964; Tröger, Geologie von Sachsen, Schweizerbart, 311-358, 2008; Voigt and Tröger, Proceedings of the 4th International Cretaceous Symposium, 275-290, 1996; Voigt, Dissertation, TU Bergakademie Freiberg, 1-130, 1995; Voigt, Zeitschrift der geologischen Wissenschaften 37(1-2): 15-39, 2009; Wilmsen et al., Freiberger Forschungshefte C540: 27-45, 2011) the main sedimentary input came from the north (Lausitz Block, southern West-Sudetic Island). A section of Turonian to Coniacian sandstones was sampled in the Elbsandsteingebirge near Schmilka (Elbtal Group, Saxony, Germany). The samples were analysed for their U-Pb age record of detrital zircon using LA-ICP-MS techniques. The results show main age clusters typical for the Bohemian Massif (local material) and are interpreted to reflect the erosion of uniform quartz-dominated sediments and basement rocks. Surprisingly, these rocks lack an expected Upper Proterozoic to Lower Palaeozoic age peak, which would be typical for the basement of the adjacent Lausitz Block (c. 540-c. 560 Ma). Therefore, the Lausitz Block basement must have been covered by younger sediments that acted as source rocks during deposition of the Elbtal Group. The sandstones of the Elbe valley (Elbtal Group, Schmilka section) represent the re-deposited sedimentary cover of the Lausitz Block in inverse order. This cover comprised Permian, Triassic, Jurassic and Lower Cretaceous deposits, which are eroded already today and cannot be investigated. Within the samples of the

  12. Origin and tectonic evolution of upper Triassic Turbidites in the Indo-Burman ranges, West Myanmar

    NASA Astrophysics Data System (ADS)

    Yao, Wei; Ding, Lin; Cai, Fulong; Wang, Houqi; Xu, Qiang; Zaw, Than

    2017-11-01

    The Pane Chaung Formation is exposed in the Indo-Burman Ranges, and has been involved in collision between the Indian Plate and West Burma Block. However, controversies exist over the provenance and paleogeographic reconstruction of the Pane Chaung Formation. This study presents new petrographical and detrital zircon Usbnd Pb ages and Hf isotopic data from the Pane Chaung Formation in Rakhine Yoma and Chin Hills, west Myanmar. The depositional age of the Pane Chaung Formation is Late Triassic, indicated by the Carnian-Norian Halobia fossils and maximum depositional ages between 233.0 ± 2.5 Ma and 206.2 ± 1.8 Ma. Upper Triassic sandstones contain 290-200 Ma detrital zircons, εHf(t) values of - 6 to 11 and TDMC of 1.6 to 0.6 Ga, interpreted to be derived from West Papua region. The most abundant zircon age population of 750-450 Ma is derived from Pan-African orogenic belts in Australia. Zircons of 1250-900 Ma age were derived from the Grenvillian orogen in Australia. Archean zircons are interpreted to be derived from the Yilgarn and Pilbara cratons in Western Australia. Detrital zircon ages of the Pane Chaung Formation are distinct from similar aged strata in Indochina and Sibumasu, but comparable to NW Australia (Carnarvon Basin) and Greater India (Langjiexue Formation). It is suggested that the Pane Chaung Formation was deposited in a Late Triassic submarine fan along the northern margin of Australia.

  13. Deciphering igneous and metamorphic events in high-grade rocks of the Wilmington complex, Delaware: Morphology, cathodoluminescence and backscattered electron zoning, and SHRIMP U-Pb geochronology of zircon and monazite

    USGS Publications Warehouse

    Aleinikoff, J.N.; Schenck, W.S.; Plank, M.O.; Srogi, L.A.; Fanning, C.M.; Kamo, S.L.; Bosbyshell, H.

    2006-01-01

    High-grade rocks of the Wilmington Complex, northern Delaware and adjacent Maryland and Pennsylvania, contain morphologically complex zircons that formed through both igneous and metamorphic processes during the development of an island-arc complex and suturing of the arc to Laurentia. The arc complex has been divided into several members, the protoliths of which include both intrusive and extrusive rocks. Metasedimentary rocks are interlayered with the complex and are believed to be the infrastructure upon which the arc was built. In the Wilmingto n Complex rocks, both igneous and metamorphic zircons occur as elongate and equant forms. Chemical zoning, shown by cathodoluminescence (CL), includes both concentric, oscillatory patterns, indicative of igneous origin, and patchwork and sector patterns, suggestive of metamorphic growth. Metamorphic monazites are chemically homogeneous, or show oscillatory or spotted chemical zoning in backscattered electron images. U-Pb geochronology by sensitive high resolution ion microprobe (SHRIMP) was used to date complexly zoned zircon and monazite. All but one member of the Wilmington Complex crystallized in the Ordovician between ca. 475 and 485 Ma; these rocks were intruded by a suite of gabbro-to-granite plutonic rocks at 434 ?? Ma. Detrital zircons in metavolcanic and metasedimentary units were derived predominantly from 0.9 to 1.4 Ga (Grenvillian) basement, presumably of Laurentian origin. Amphibolite to granulite facies metamorphism of the Wilmington Complex, recorded by ages of metamorphic zircon (428 ?? 4 and 432 ?? 6 Ma) and monazite (429 ?? 2 and 426 ?? 3 Ma), occurred contemporaneously with emplacement of the younger plutonic rocks. On the basis of varying CL zoning patterns and external morphologies, metamorphic zircons formed by different processes (presumably controlled by rock chemistry) at slightly different times and temperatures during prograde metamorphism. In addition, at least three other thermal episodes are

  14. Characterization of inclusions in terrestrial impact formed zircon: Constraining the formation conditions of Hadean zircon from Jack Hills, Western Australia

    NASA Astrophysics Data System (ADS)

    Faltys, J. P.; Wielicki, M. M.; Sizemore, T. M.

    2017-12-01

    Due to the discovery and subsequent geochemical analysis of Hadean terrestrial material (e.g. detrital zircon from Jack Hills, Western Australia), a dramatic paradigm shift has occurred in the hypothesized near surface conditions of the first 500 million years of Earth's evolution. From a hellish setting riddled with impactors and not fit for life to a much milder environment that may have been uniquely suitable for the origin of life. Geochemical analyses of these ancient materials have been used to suggest the presence of water at or near the surface as well as the existence of continental crust during the Hadean, both of which have been suggested as necessary for the origin of life. However, the intensity of extraterrestrial bombardment during the Hadean and the effects of such events on the origin of life remains poorly understood. Clearly, as evidenced by Phanerozoic impact events, extraterrestrial impactors have the potential to dramatically effect the environment, particularly the biosphere. Early Earth likely experienced multiple large impact events, as evidenced by the lunar record, however whether those impacts were sufficient to frustrate the origin of life remains an open question. Although multiple lines of evidence, including the inclusion population, suggest the formation of Hadean zircon from Jack Hills as crystallizing in an under-thrust environment from S-type magmas, a recent study has suggested their formation in an impact melt environment analogous to a portion of the Sudbury Igneous Complex at the Sudbury impact structure. To determine between these two formation scenarios we have under-taken an inclusion study of terrestrial impact formed zircon from four of the largest terrestrial impact structures (Sudbury, Canada; Manicouagan, Canada; Vredefort, South Africa; Morokweng, South Africa), to compare to the vast inclusion dataset that exists for Jack Hills zircon. Preliminary data suggests a different inclusion population, from Hadean zircon

  15. Low heat flow inferred from >4 Gyr zircons suggests Hadean plate boundary interactions.

    PubMed

    Hopkins, Michelle; Harrison, T Mark; Manning, Craig E

    2008-11-27

    The first approximately 600 million years of Earth history (the 'Hadean' eon) remain poorly understood, largely because there is no rock record dating from that era. Detrital Hadean igneous zircons from the Jack Hills, Western Australia, however, can potentially provide insights into the conditions extant on our planet at that time. Results of geochemical investigations using these ancient grains have been interpreted to suggest the presence of a hydrosphere and continental crust before 4 Gyr. An underexploited characteristic of the >4 Gyr zircons is their diverse assemblage of mineral inclusions. Here we present an examination of over 400 Hadean zircons from Jack Hills, which shows that some inclusion assemblages are conducive to thermobarometry. Our thermobarometric analyses of 4.02-4.19-Gyr-old inclusion-bearing zircons constrain their magmatic formation conditions to about 700 degrees C and 7 kbar. This result implies a near-surface heat flow of approximately 75 mW m(-2), about three to five times lower than estimates of Hadean global heat flow. As the only site of magmatism on modern Earth that is characterized by heat flow of about one-quarter of the global average is above subduction zones, we suggest that the magmas from which the Jack Hills Hadean zircons crystallized were formed largely in an underthrust environment, perhaps similar to modern convergent margins.

  16. Isotopic-Geochemical Features of Zircon and Its Significance for Reconstructing the Geological History of Paleoarchean Granulites in the Ukrainian Shield

    NASA Astrophysics Data System (ADS)

    Lobach-Zhuchenko, S. B.; Kaulina, T. V.; Lokhov, K. I.; Egorova, Yu. S.; Skublov, S. G.; Galankina, O. L.; Antonov, A. V.

    2017-12-01

    This paper presents the results of a complex study (morphology of grains, internal texture in cathodoluminescence and backscattered electrons, microprobe analysis, Lu-Hf data) of five groups (generations) of zircon crystals differing in age and separated from the same granulite sample pertaining to the Bug River Complex of the Ukrainian Shield. The data show that the oldest zircon crystals of the first group (3.74 Ga in age) are xenogenic and initially crystallized from a granitic melt; zircon of the second group (3.66 Ga) formed from a mafic melt contaminated by felsic country rocks. The third group (3.59 Ga) is represented by zircons that formed about 100 Ma later than the second group under conditions of granulite-facies metamorphism and with the participation of fluid-saturated anatectic melt. Two Paleoproterozoic zircon groups ( 2.5 and 2.1 Ga) also formed under granulite-facies conditions; to a certain extent, their structure and composition were controlled by fluid. The geochemistry of all zircon generations provides evidence for their crystallization in the continental crust, but from the sources differing in the contribution of mantle-derived material and in oxygen fugacity.

  17. Lithium in Jack Hills zircons: Evidence for extensive weathering of Earth's earliest crust

    NASA Astrophysics Data System (ADS)

    Ushikubo, Takayuki; Kita, Noriko T.; Cavosie, Aaron J.; Wilde, Simon A.; Rudnick, Roberta L.; Valley, John W.

    2008-08-01

    In situ Li analyses of 4348 to 3362 Ma detrital zircons from the Jack Hills, Western Australia by SIMS reveal that the Li abundances (typically 10 to 60 ppm) are commonly over 10,000 times higher than in zircons crystallized from mantle-derived magmas and in mantle-derived zircon megacrysts (typically < 2 ppb). High Li concentrations in zircons (10 to 250 ppm) have also been found in igneous zircons from three continental parent rocks: granites, Li-rich pegmatites, and migmatites in pelitic metasediment. The substitution of trivalent cations (REEs and Y) in zircon correlates with Li + 1 and P + 5 , suggesting that an interstitial site for Li, as well as the xenotime substitution for P, provides charge balance for REEs. Li is thus fixed in the zircon structure by coupled substitutions, and diffusive changes in [Li] composition are rate-limited by slow diffusion of REEs. The Jack Hills zircons also have fractionated lithium isotope ratios ( δ7Li = - 19 to + 13‰) about five times more variable than those recorded in primitive ocean floor basalts (2 to 8‰), but similar to continental crust and its weathering products. Values of δ7Li below - 10‰ are found in zircons that formed as early as 4300 Ma. The high Li compositions indicate that primitive magmas were not the source of Jack Hills zircons and the fractionated values of δ7Li suggest that highly weathered regolith was sampled by these early Archean magmas. These new Li data provide evidence that the parent magmas of ancient zircons from Jack Hills incorporated materials from the surface of the Earth that interacted at low temperature with liquid water. These data support the hypothesis that continental-type crust and oceans existed by 4300 Ma, within 250 million years of the formation of Earth and the low values of δ7Li suggest that weathering was extensive in the early Archean.

  18. 500 Myr of thermal history elucidated by multi-method detrital thermochronology of North Gondwana Cambrian sandstone (Eilat area, Israel)

    NASA Astrophysics Data System (ADS)

    Vermeesch, P.; Avigad, D.

    2009-04-01

    Following the Neoproterozoic Pan-African orogeny, the Arabian-Nubian Shield (ANS) of North Africa and Arabia was eroded and then covered by Cambrian sandstones that record the onset of platform sedimentation. We applied K-feldspar 40Ar/39Ar, zircon and apatite fission track and apatite (U-Th)/He thermochronology to detritus from Cambrian sandstones of southern Israel deposited at about 500 Ma. U-Pb detrital zircon ages from these sandstones predate deposition and record the earlier Neoproterozoic crustal evolution of the Pan-African orogens. 40Ar/39Ar ages from 50 single grains of K-feldspar yield a Cambrian mean of approximately 535 Ma. The 40Ar/39Ar age spectrum of a multi-grain K-feldspar aliquot displays diffusion behaviour compatible with >560 Ma cooling later affected by a heating event. Assuming that the high temperature domains of the K-feldspars have not been affected by subsequent (hydro)thermal events, and taking previously published K-Ar and Rb-Sr ages from other parts of the East African Orogen at face value, these ages apparently record Pan-African thermal resetting below a thick volcano-sedimentary pile similar to the Saramuj conglomerate in Jordan and/or the Hammamat in Egypt. Detrital zircon fission track (ZFT) ages cluster around 380 Ma, consistent with previous ZFT results from Neoproterozoic basement and sediments of the region, revealing that the Cambrian platform sequence experienced a middle Devonian thermal event and low-grade metamorphism. Regional correlation indicates that during Devonian time the sedimentary cover atop the Cambrian in Israel was never in excess of 2.5 km, requiring an abnormally steep geothermal gradient to explain the complete ZFT annealing. A basal Carboniferous unconformity can be traced from Syria to southern Saudi Arabia, suggesting that the observed Devonian ZFT ages represent a regional tectonothermal event. Similar Devonian ZFT ages were reported from ANS basement outcrops in the Eastern Desert, 500 km south of

  19. Allogenic and Autogenic Signals in the Detrital Zircon U-Pb Record of the Deep-Sea Bengal Fan

    NASA Astrophysics Data System (ADS)

    Blum, M. D.; Rogers, K. G.; Gleason, J. D.; Najman, Y.

    2017-12-01

    The Himalayan-sourced Ganges-Brahmaputra river system and the deep-sea Bengal Fan represent Earth's largest sediment-dispersal system. This presentation summarizes a new detrital zircon U-Pb (DZ) provenance record from the Bengal Fan from cores collected during IODP Expedition 354, with coring sites located 1350 km downdip from the shelf margin. Each of our 15 samples were collected from medium- to fine-grained turbidite sand and, based on shipboard biostratigraphic analyses, our samples are late Miocene to late Pleistocene in age. Each sample was analyzed by LA-ICPMS at the Arizona Laserchron facility, with an average of n=270 concordant U-Pb ages per sample. Our goals are to use these data to evaluate the influence of allogenic controls vs. autogenic processes on signal propagation from source-to-sink. At the first order, large-scale sediment transfer to the Bengal Fan clearly records the strong tectonic and climatic forcing associated with the Himalayas and Ganges-Brahmaputra system: after up to 2500 km of river transport, and 1350 km of transport in turbidity currents, the DZ record faithfully represents Himalayan source terrains. The sand-rich turbidite part of the record is nevertheless biased towards glacial periods when rivers extended across the shelf in response to climate-forced sea-level fall, and discharged directly to slope canyons. However, only part of the Bengal Fan DZ record represents either the Ganges or the Brahmaputra, with most samples representing varying degrees of mixing of sediments from the two systems: this mixing, or the lack thereof, represents the signal of autogenic avulsions on the delta plain that result in the two river systems delivering sediment separately to the shelf margin, or together as they do today. Within the allogenic framework established by tectonic processes, the climatic system, and global climate-forced sea-level change, the DZ U-Pb record of sediment mixing or the lack thereof provides a fingerprint of autogenic

  20. Sulfur in zircons: A new window into melt chemistry

    NASA Astrophysics Data System (ADS)

    Tang, H.; Bell, E. A.; Boehnke, P.; Barboni, M.; Harrison, T. M.

    2017-12-01

    The abundance and isotopic composition of sulfur are important tools for exploring the photochemistry of the atmosphere, the thermal history of mantle and igneous rocks, and ancient metabolic processes on the early Earth. Because the oldest terrestrial samples are zircons, we developed a new in-situ procedure to analyze the sulfur content of zircons using the CAMECA ims 1290 at UCLA. We analyzed zircons from three metaluminous/I-type granites (reduced and oxidized Peninsular range and Elba), which exhibit low sulfur abundance with the average of 0.5ppm, and one peraluminous/S-type zircon (Strathbogie Range), which shows an elevated sulfur level with the average of 1.5ppm. Additionally, we found that sulfur content ranges between 0.4 and 2.3 ppm in young volcanic zircons (St. Lucia). Our analyses of zircons from the Jack Hills, Western Australia, whose ages range between 3.4 and 4.1 Ga, show a variety of sulfur contents. Three out of the ten zircons are consistent with the sulfur contents of S-type zircons; the rest have low sulfur contents, which are similar to those of I-type zircons. The high sulfur content in some of these Jack Hills zircons can be interpreted as indicating their origin in either a S-type granite or a volcanic reservoir. We favor the former interpretation since the Ti-in-zircon temperatures of our Jack Hills zircons is lower than those of volcanic zircons. Future work will be undertaken to develop a systematic understanding of the relationship between melt volatile content, melt chemistry, and zircon sulfur content.

  1. Metamorphism and magmatism in the western East European Craton: implications for 1.84 to 1.45 Ga evolution in Lithuania

    NASA Astrophysics Data System (ADS)

    Skridlaite, Grazina; Baginski, Boguslaw; Bogdanova, Svetlana; Whitehouse, Martin

    2010-05-01

    The western East European Craton (EEC) was formed by the accretion of distinct terrains at c. 1.8 Ga. Some boundaries between particular terrains and their continuation across the Baltic Sea from Lithuania to Sweden have to be justified. Recently obtained numerous U-Pb zircon ages from the Siupariai 3 (Sp3), Palukne 1 (Pl1) charnockites, Rukai 1 (Rk1), Geluva 99 (Gl99) granitoids, Bliudziai 150 (Bl150), Lauksargiai (Lk2, 5) and Pociai 3(Pc3) granulites determined using a Cameca ims1270 instrument of the Nordic high-resolution ion-microprobe facility (NORDSIM), as well as monazites of the Sp3, Pl1, Vydmantai 1 (Vd1) charnockites, Lk2, 5, Bl150 granulites dated by Cameca SX-100 electron microprobe (EPMA dating) at University of Warsaw allowed to reconstruct terrain boundaries from north to south in western Lithuania and a sequence of crust-forming events. In the north, the slightly deformed, coarse-grained Sp3, Pl1 and Vd1 (Claesson et al., 2001) charnockitoids crystallized in the time span of c. 1.84-1.81 Ga. The magmatic zircons contain a few c. 2.4-2.0 Ga inherited cores. The rocks were deformed and thermally reworked immediately after their crystallization as indicated by c. 1.79-1.74 Ga zircons and c. 1.85-1.76 Ga high-Y monazites, but the major metamorphism they underwent not earlier than c. 1.70 Ga. Thick zircon rims and rounded sector-zoned metamorphic zircons of c. 1.70 Ga likely grew together with peak garnet at 800o C, 7 kbar (Sp3) or 760o C and 6.5 kbar (Pl1). Numerous 1.62-1.56 Ga monazites recorded decompression to 2 kbar and cooling to 500o C in Sp3, mostly cooling to 450o C (at 4 kbar) in Pl1, and isothermal decompression from 650o C at 7 kbar to 500o C at 3 kbar in Vd1. In the south, the Bl150, Lk2, 5 and Pc 3 metasedimentary granulites containing a wide age range (3.0 to 1.85 Ga) of detrital zircons were deposited not earlier than 1.89 Ga. An incipient metamorphism started with the growth of relatively high-Y monazite (Y>3%) at 1.84-1.83 Ga, however

  2. Detrital Geochemical Fingerprints of Rivers Along Southern Tibet and Nepal: Implications for Erosion of the Indus-Yarlung Suture Zone and the Himalayas

    NASA Astrophysics Data System (ADS)

    Hassim, M. F. B.; Carrapa, B.; DeCelles, P. G.; Kapp, P. A.; Gehrels, G. E.

    2014-12-01

    Our detrital geochemical study of modern sand collected from tributaries of the Yarlung River in southern Tibet and the Kali Gandaki River and its tributaries in Nepal shed light on the ages and exhumation histories of source rocks within the Indus-Yarlung Suture (IYS) zone and the Himalayas. Seven sand samples from rivers along the suture zone in southern Tibet between Xigatze to the east and Mt. Kailas to the west were collected for detrital zircon U-Pb geochronologic and Apatite Fission Track (AFT) thermochronologic analyses. Zircon U-Pb ages for all rivers range between 15 and 3568 Ma. Rivers draining the northern side of the suture zone mainly yield ages between 40 and 60 Ma, similar to the age of the Gangdese magmatic arc. Samples from rivers draining the southern side of the suture zone record a Tethyan Himalayan signal characterized by age clusters at 500 Ma and 1050 Ma. Our results indicate that the ages and proportion of U-Pb zircons ages of downstream samples from tributaries of the Yarlung River directly reflect source area ages and relative area of source rock exposure in the catchment basin. Significant age components at 37 - 40 Ma, 47 - 50 Ma, 55 - 58 Ma and 94 - 97 Ma reflect episodicity in Gangdese arc magmatism. Our AFT ages show two main signals at 23-18 Ma and 12 Ma, which are in agreement with accelerated exhumation of the Gangdese batholith during these time intervals. The 23 - 18 Ma signal partly overlaps with deposition of the Kailas Formation along the suture zone and may be related to exhumation due to upper plate extension in southern Tibet in response to Indian slab rollback and/or break-off events. Detrital thermochronology of four sand samples from the Kali Gandaki River and some of its tributaries in Nepal is underway and will provide constraints on the timing of erosion of the central Nepal Himalaya.

  3. Precambrian-Cambrian provenance of Matinde Formation, Karoo Supergroup, northwestern Mozambique, constrained from detrital zircon U-Pb age and Lu-Hf isotope data

    NASA Astrophysics Data System (ADS)

    Bicca, Marcos Müller; Jelinek, Andrea Ritter; Philipp, Ruy Paulo; de Carvalho Lana, Cristiano; Alkmim, Ana Ramalho

    2018-02-01

    The Permian-Triassic time interval was a period of high sedimentation rates in the intracontinental Karoo rift basin of northwestern Mozambique, reflecting high exhumation rates in the surrounding high ground Precambrian-Cambrian basement and juxtaposed nappes. U-Pb LA-MC-ICPMS dating and Lu-Hf isotopic analysis of detrital zircons from the Late Permian-Early Triassic Matinde Formation of the Karoo Supergroup is used as a reliable proxy to map denudation patterns of source regions. Data allow discrimination of U-Pb age populations of ca. 1250-900 Ma, a secondary population between ca. 900-700 and a major contribution of ages around ca. 700-490 Ma. Zircon grains of the Mesoproterozoic age population present Mesoproterozoic (1000-1500 Ma) to Paleoproterozoic (1800-2300 Ma) Hf TDM ages, with positive (0 to +11) and negative εHf values (-3 to -15), respectively. The younger U-Pb age population also presents two different groups of zircon grains according to Lu-Hf isotopes. The first group comprise Paleoproterozoic (1800-2300 Ma) ages, with highly negative εHf values, between -10 and -22, and the second group exhibits Mesoproterozoic ages (1200-1500 Ma), with increased juvenile εHf values (ca. 0 to -5). These Hf isotopes reinforce the presence of unexposed ancient crust in this region. The oldest U-Pb age population resembles the late stages of Grenville Orogeny and the Rodinia Supercontinent geotectonic activity mostly represented by magmatic rocks, which are widely present in the basement of northern Mozambique. The juvenile Hf-isotope signature with an older age component is associated to rocks generated from subduction processes with crust assimilation by continental arcs, which we correlate to rocks of the Nampula Complex, south and east of the Moatize-Minjova Basin. The U-Pb ages between 900 and 700 Ma were correlated to the calc-alkaline magmatism registered in the Guro Suite, related to the breakup phase of Rodinia, and mark the western limit of the Moatize

  4. Permian arc evolution associated with Panthalassa subduction along the eastern margin of the South China block, based on sandstone provenance and U-Pb detrital zircon ages of the Kurosegawa belt, Southwest Japan

    NASA Astrophysics Data System (ADS)

    Hara, Hidetoshi; Hirano, Miho; Kurihara, Toshiyuki; Takahashi, Toshiro; Ueda, Hayato

    2018-01-01

    We have studied the petrography, geochemistry, and detrital zircon U-Pb ages of sandstones from shallow-marine forearc sediments, accretionary complexes (ACs), and metamorphosed accretionary complexes (Meta-ACs) within the Kurosegawa belt of Southwest Japan. Those rocks formed in a forearc region of a Permian island arc associated with subduction of the Panthalassa oceanic crust along the eastern margin of the South China block (Yangtze block). The provenance of the shallow-marine sediments was dominated by basaltic to andesitic volcanic rocks and minor granitic rocks during the late Middle to Late Permian. The ACs were derived from felsic to andesitic volcanic rocks during the Late Permian. The provenance of Meta-ACs was dominated by andesitic volcanic rocks in the Middle Permian. The provenance, source rock compositions, and zircon age distribution for the forearc sediments, ACs and Meta-ACs have allowed us to reconstruct the geological history of the Permian arc system of the Kurosegawa belt. During the Middle Permian, the ACs were accreted along the eastern margin of the South China block. The Middle Permian arc was an immature oceanic island arc consisting of andesitic volcanic rocks. During the Late Permian, the ACs formed in a mature arc, producing voluminous felsic to andesitic volcanic rocks. A forearc basin developed during the late Middle to Late Permian. Subsequently, the Middle Permian ACs and part of the Late Permian AC underwent low-grade metamorphism in the Late to Early Jurassic, presenting the Meta-ACs.

  5. New Hf isotope data from the Jack Hills zircons: constraints on the Hadean crustal evolution

    NASA Astrophysics Data System (ADS)

    Amelin, Y.; Davis, D.; Lee, D.

    2004-05-01

    Here we present a follow-up of our study of the "older" population of detrital zircons from the Jack Hills metaconglomerate W-74 [1]. We report Lu-Hf data for zircon grains, which have been previously analyzed with a number of techniques: BSE and CL imaging, detailed U-Pb SHRIMP geochronology, trace element concentrations, and oxygen isotopic compositions. After completion of non-destructive SIMS analyses and imaging, the zircons were extracted from the mounts, dissolved and analyzed for U-Pb and Lu-Hf using isotope dilution. Twenty five grains were air abraded before digestion, and eight grains were digested without abrasion. Four grains were cut, and the fragments were analyzed for U-Pb and Lu-Hf separately. The 207Pb/206Pb ages determined by isotope dilution vary between 3788-4186 Ma; the maximum SHRIMP spot 207Pb/206Pb ages of the same grains are between 3871-4276 Ma. The spot 207Pb/206Pb ages averaged over each grain are close to the whole grain isotope dilution values. The U-Pb discordance depends mainly on whether the grains were abraded: the median discordance of 27 abraded grains and fragments is 2.7 (the range is -0.4 to 20.2), whereas the median discordance of 11 unabraded grains and fragments is 66.5 (the range is 20.5 to 83.5). The epsilon176Hf values, calculated using the whole grain TIMS 207Pb/206Pb ages and the 176Lu decay constant of 1.865*10-11, are between -1.4 and -10.6. Using maximum SHRIMP spot 207Pb/206Pb ages and the same decay constant yields the range of epsilon176Hf of 0.1 to -8.6. If the decay constant of 1.983*10-11 is used instead, then the range of epsilon176Hf becomes 4.7 to -5.0 using the whole grain ages, or 6.3 to -3.0 using the maximum SHRIMP spot ages. Grain fragment analyses show internal variations of initial 176Hf/177Hf in three grains out of five. This observation is consistent with multi-episodic zircon growth rather than with ancient Pb loss. In the presentation we shall discuss the prospect of reliable interpretation of

  6. The India and South China cratons at the margin of Rodinia — Synchronous Neoproterozoic magmatism revealed by LA-ICP-MS zircon analyses

    NASA Astrophysics Data System (ADS)

    Hofmann, M.; Linnemann, U.; Rai, V.; Becker, S.; Gärtner, A.; Sagawe, A.

    2011-04-01

    The palaeogeographic position of South China in relation to India in the Neoproterozoic is controversial. Resolution of this controversy constrains the reconstruction of Rodinia during its breakup and contributes to our understanding of Snowball Earth. This work compares the Neoproterozoic histories of the Lesser Himalaya in northern India and the Yangtze block in southern China. We present U-Pb LA-ICP-MS ages of detrital zircon grains from six Indian and three Chinese siliciclastic sedimentary rocks, such as sandstones or diamictites/tillites. In total, 1148 grains were analysed from which 833 measurements gave ages with a degree of concordance between 90 and 110%. The correlation of the Indian and the Chinese sections is possible using the tillites of both areas purportedly deposited during the Snowball Earth time interval: the Blaini tillite from India and the Nantuo tillite from China. The U-Pb ages confirm the Marinoan age of the Chinese Liantuo tillite. Although the youngest zircon age for the Indian Blaini tillite is about 678 Ma, the Marinoan age is indicated by the presence of a typical Marinoan white to bright yellowish overlying cap carbonate. In addition to the tillites, representative detrital zircon ages from over- and underlying clastic rocks were determined. The Chinese samples are dominated by zircons with Neoproterozoic ages with a main peak between ca. 750 Ma and ca. 950 Ma and are characterised by the absence of Archaean ages. The Indian samples contain abundant Neoproterozoic zircon grains, but also contain Mesoproterozoic to Archaean zircons. For all samples, a local source area that provided the Neoproterozoic zircons is likely. A synchronous Neoproterozoic magmatic event in both cratons probably reflects the breakup of the supercontinent Rodinia and therefore the same tectono-magmatic event. Our results indicate a similar history for India and South China which both underwent at least one synchronous episode of crustal growth during the

  7. The Triassic reworking of the Yunkai massif (South China): EMP monazite and U-Pb zircon geochronologic evidence

    NASA Astrophysics Data System (ADS)

    Chen, Cheng-Hong; Liu, Yung-Hsin; Lee, Chi-Yu; Sano, Yuji; Zhou, Han-Wen; Xiang, Hua; Takahata, Naoto

    2017-01-01

    Geohistory of the Yunkai massif in South China Block is important in understanding the geodynamics for the build-up of this block during the Phanerozoic orogenies. To investigate this massif, we conduct EMP monazite and U-Pb zircon geochronological determinations on mineral inclusions and separate for seventeen samples in four groups, representing metamorphic rocks from core domain, the Gaozhou Complex (amphibolite facies, NE-striking) and the Yunkai Group (greenschist facies, NW-striking) of this massif and adjacent undeformed granites. Some EMP monazite ages are consistent with the NanoSIMS results. Monazite inclusions, mostly with long axis parallel to the cleavage of platy and elongated hosts, give distinguishable age results for NW- and NE-trending deformations at 244-236 Ma and 236-233 Ma, respectively. They also yield ages of 233-230 Ma for core domain gneissic granites and 232-229 Ma for undefomed granites. Combining U-Pb zircon ages of the same group, 245 Ma and 230 Ma are suggested to constrain the time of two phases of deformation. Aside from ubiquity of Triassic ages in studied rocks, ages of detrital monazite in the meta-sandstone match the major U-Pb zircon age clusters of the metamorphic rock that are largely concentrated at Neoproterozoic (1.0-0.9 Ga) and Early Paleozoic (444-431 Ma). Based on these geochronological data, Triassic is interpreted as representing the time for recrystallization of these host minerals on the Early Paleozoic protolith, and the also popular Neoproterozoic age is probably inherited. With this context, Yunkai massif is regarded as a strongly reactivated Triassic metamorphic terrain on an Early Paleozoic basement which had incorporated sediments with Neoproterozoic provenances. Triassic tectonic evolution of the Yunkai massif is suggested to have been controlled by converging geodynamics of the South China and Indochina Blocks as well as mafic magma emplacement related to the Emeishan large igneous province (E-LIP).

  8. Faulting and erosion in the Argentine Precordillera during changes in subduction regime: Reconciling bedrock cooling and detrital records

    NASA Astrophysics Data System (ADS)

    Fosdick, Julie C.; Carrapa, Barbara; Ortíz, Gustavo

    2015-12-01

    The Argentine Precordillera is an archetypal retroarc fold-and-thrust belt that records tectonics associated with changing subduction regimes. The interactions between exhumation and faulting in the Precordillera were investigated using apatite and zircon (U-Th-Sm)/He and apatite fission track thermochronometry from the Precordillera and adjacent geologic domains. Inverse modeling of thermal histories constrains eastward in-sequence rock cooling associated with deformation and erosion from 18 to 2 Ma across the Central Precordillera tracking thrusting during this time. The youngest AHe ages (5-2 Ma) and highest erosion rates are located in the eastern and western extremities of the Precordillera and indicate that recent denudation is concentrated at its structural boundaries. Moreover, synchronous rapid Pliocene cooling of the Frontal Cordillera, Eastern Precordillera, and Sierra del Valle Fértil was coeval with initiation of basement-involved faulting in the foreland. Detrital zircon U-Pb geochronology from the ca. 16-8.1 Ma Bermejo foreland basin strata suggests fluvial connectivity westward beyond the Frontal Cordillera to the Main Cordillera and Coast Range followed by an important shift in sediment provenance at ca. 10 Ma. At this time, we suggest that a substantial decrease in Permo-Triassic igneous sources in the Frontal Cordillera and concurrent increase in recycled zircons signatures of Paleozoic strata are best explained by uplift and erosion of the Precordillera during widening of the thrust-belt. Bedrock thermochronology and modeling indicate a 2-6 Myr lag time between faulting-related cooling in the hinterland and the detrital record of deformation in the foreland basin, suggesting that for tectonically active semi-arid settings, bedrock cooling may be more sensitive to onset of faulting. We suggest that high erosion rates in the Frontal Cordillera and Eastern Precordillera are associated with increased interplate coupling during shallowing of the

  9. 1.8 billion years of fluid-crust interaction: A zircon oxygen isotope record for the lower crust, western Churchill Province, Canadian Shield

    NASA Astrophysics Data System (ADS)

    Petts, Duane C.; Moser, Desmond E.; Longstaffe, Frederick J.; Davis, William J.; Stern, Richard A.

    2014-04-01

    The western Churchill Province of the Canadian Shield experienced a prolonged and complex formation history (ca. 4.04 to 1.70 Ga), with evidence for multiple episodes of orogenesis and regional magmatic activity. Here we report on the oxygen isotopic compositions of garnet and zircon recovered from lower crustal xenoliths, which have U-Pb ages between ca. 3.5 and 1.7 Ga. Overall, zircon from four metabasite xenoliths from the Rankin Inlet sample suite have δ18O values ranging from + 5.5 to + 8.6‰. Zircon from three metatonalite/anorthosite xenoliths and five metabasite xenoliths from the Repulse Bay sample suite have δ18O values of + 5.6 to + 8.3‰. High δ18O values (> + 6.0‰) for the oldest igneous zircon cores (ca. 3.5 Ga and 3.0-2.6 Ga) indicate that their metatonalite/anorthosite protolith magmas were generated from, or had assimilated, supracrustal rocks that interacted previously with surface-derived fluids. Igneous zircon cores (ca. 2.9-2.6 Ga) from one metabasite xenolith have δ18O values of + 5.6 to + 6.4‰, which suggests a formation from a mantle-derived basaltic/gabbroic magma. Metamorphic zircon cores (ca. 2.0-1.9 Ga) from one metabasite xenolith commonly have δ18O values between + 6.0 and + 6.3‰, which is indicative of a basalt/gabbro protolith and localized reworking of the lower crust caused by regional-scale plate convergence. The wide range of δ18O values (+ 5.5 to + 8.3‰) for ca. 1.75-1.70 Ga metamorphic zircon rims (identified in all xenoliths) indicates regional transient heating and reworking of mantle- and supracrustal-derived crust, induced by magmatic underplating along the crust-mantle boundary.

  10. Dating high-grade metamorphism: constraints from zircon and garnet REE compositions

    NASA Astrophysics Data System (ADS)

    Whitehouse, M. J.; Platt, J. P.

    2001-12-01

    We present high spatial resolution ion microprobe REE analyses of zircon and garnet from pelitic granulite adjacent to the Ronda peridotite, Betic Cordillera, southern Spain. The zircons exhibit polyphase growth, with thick structureless (in cathodoluminescence) overgrowths over detrital cores. These overgrowths yield a U-Pb age of 21.3 +/- 0.3 Ma [1, unpublished data] which we intepret as dating an episode of zircon growth during the Alpine orogeny. REE analyses of the dated portions of these zircons reveal profound differences between cores and rims. Cores show patterns typical of magmatic zircon (steep upward slopes from La to Lu with marked positive Ce anomaly), while the overgrowths are characterised by flat or even negatively sloping HREE profiles (Gd - Lu). Garnet, which occupies ca. 30 % by volume of the rock, is the most likely phase to host the HREEs in the rock and has been the subject of further ion-microprobe REE, textural and trace element investigations. The garnets are themselves zoned, with dominant central regions that are relatively free of inclusions overgrown by inclusion-rich, more calcic rims. Inclusions of kyanite +rutile in the central regions and sillimanite +ilmenite in the rims suggests that the garnets grew during decompression, and the Ca-enrichment in the rims suggests that their growth coincided with the initiation of partial melting. The presence of rimmed zircons only in the garnet rims and the matrix further suggests that the zircons also grew during this late decompressional history. An REE traverse of the garnet from core to rim reveals marked HREE depletion in the rims relative to the cores which we suggest is consistent with the textural evidence and probably results from early garnet core growth strongly depleting the HREEs available to subsequent growth. This mechanism can also be invoked to explain depletion in the zircon rims and more closely ties their formation to this stage of garnet growth. We therefore interpret the

  11. Tracing collisional route of the Danubian terranes (South Carpathians, Romania), using detrital U-Pb isotopic record

    NASA Astrophysics Data System (ADS)

    Balica, Constantin; Balintoni, Ioan; Campeanu, Mara

    2017-04-01

    [3]. Based on the analysis of two detrital zircon age patterns, an Avalonian-type origin and a peri-Amazonian provenance is suggested. In addition to these arguments, the absence of any Cadomian intrusion was used as strong point to constrain the location of Drǎgșan terrane outside the Cadomian arc. Beyond the terranes origin, provenance and tectonic setting, the evolution of the Danubian terranes starting with their formation at the Gondwana margin up to the final Variscan continental collision remains still undisclosed. In order to trace the collisional route of the two Danubian terranes, a comparative analysis is done on 12 detrital zircon samples from the Dragsan terrane and 15 detrital zircon samples from Lainici-Paius terrane has been carried out, in terms of the detrital zircon U-Pb age distribution. The two aggregate age distributions show similarities, sharing common maxima within 600-300 Ma. Based on these similarities, a sequence of events is proposed. Following the formation of the two Danubian terranes (i.e. minimum 800 Ma for the Dragsan terrane and 622-600 Ma for the Lainici-Paius terrane, respectively), age peaks falling within 630-580 Ma might represent the accretion and collision of the Dragsan arc to the Gondwanan margin represented by Lainici-Paius terrane. The 570 Ma peak, common for both distributions and identified also in a set of metamorphic zircons from the Lainici-Paius terrane, possibly represent the age of metamorphism for both terranes. The age minima observed within the 450-430 Ma interval, might suggest the separation of the Danubian terranes from the Gondwana mainland. Finally, the Variscan collision is clearly recorded by the 320 Ma peak Acknowledgments: this study was founded through grant PN-II ID-PCE-2011-3-0100 References [1] Balintoni, I., Balica, C., Ducea, M., Stremțan, C., 2011. Peri-Amazonian, Avalonian-type and Ganderian-type terranes in the South Carpathians, Romania: The Danubian domain basement Gondwana Research 19

  12. Micron-Scale Correlations Among Ti, P, Ce, and Y in Hadean Jack Hills Zircons

    NASA Astrophysics Data System (ADS)

    Hofmann, A. E.; Cavosie, A. J.; Valley, J. W.; Eiler, J. M.

    2007-12-01

    Detrital zircons and the inclusions found therein are our only mineralogical constraints on geologic events that occurred on the Hadean Earth. These zircons are commonly small (ca. <100 μm in the longest dimension) and preserve micron to sub-micron chemical zonations indicative of a dynamic petrological history. Trace elements within zircon are of particular interest because concentrations and ratios of these elements can provide information regarding chemical and physical conditions during zircon growth. In this study, we analyzed Hadean-age detrital zircons from Archean metasediment in the Jack Hills (Australia) using the Caltech Microanalysis Center Cameca NanoSIMS 50L. Trace elements analyzed included Ti, P, Ce, and Y. Ti- thermometry [1,2,3] can potentially constrain growth and/or re-equilibration temperatures of zircons; P, Ce, and Y are known to enter the zircon lattice by the coupled xenotime-type substitution mechanism: (Y, REE)3+ + P5+ = Zr4+ + Si4+ [5]. The 89Y/28Si ratio was observed to correlate with, and was used as a proxy for, cathodoluminescence (CL) banding. Growth features manifested in CL (e.g., sector, oscillatory zoning) were observed in all zircons analyzed. CL zones vary from <1 μm to several microns in width; therefore, the NanoSIMS---with a beam diameter resolved to ca. 250 nm on the sample surface when operating with an O- primary beam---is uniquely suited for this scale of analysis. Regions displaying CL banding were imaged as 20 x 20 μm areas. All elements were normalized to 28Si; 49Ti/28Si ratios were converted to [Ti] via calibration based on analyses of synthetic, high-Ti zircons (provided by B. Watson) that were independently analyzed on Caltech's JEOL JXA-8200 electron microprobe. We observe three types of relationships between trace element distribution and CL banding in the zircons imaged: 1) strong positive correlations between CL banding, P, Ce, and Ti; 2) subtle positive correlations between CL banding, P, Ce, and Ti; 3) no

  13. Using Zircon Geochronology to Unravel the History of the Naga Hills Ophiolite

    NASA Astrophysics Data System (ADS)

    Roeder, T.; Aitchison, J. C.; Clarke, G. L.; Ireland, T. R.; Ao, A.; Bhowmik, S. K.

    2014-12-01

    Outcrops of the Naga Hills Ophiolite (NHO), a possible eastern extension of the ophiolitic belt running along the India-Asia suture, in Northeast India include a full suite of ophiolitic rocks. The ophiolite has been dated Upper Jurassic based on radiolarian studies of the unit (Baxter et al., 2011) but details of its emplacement onto the Indian margin have not been the subject of detailed investigation. Conglomerates of the Phokphur Formation unconformably overlie an eroded surface on top of dismembered ophiolite fragments and include sediments sourced from both the ophiolite and the margin of the Indian subcontinent. Notably no Asian margin-derived detritus is recognised (similar to the Liuqu conglomerates of Tibet (Davis et al., 2002)). Thus, a detailed study of the Phokphur sediments can produce valuable details of the NHO history, including constraining the timing of ophiolite emplacement. Studies of detrital sandstone petrography confirm a recycled orogen provenance for the Phokphur Formation and thus serve as validation of the methods of Dickinson and Suczek (1979) and Garzanti et al. (2007). Detrital zircon data provides further insight as to the age of source rocks of Phokphur sediments and help to further constrain the timing of ophiolite emplacement. We present results of sedimentary and detrital zircon geochronology analyses of Phokphur sediments from outcrops near the villages of Salumi and Wazeho as a contribution to furthering research on aspects of the India-Asia collision. Baxter, A.T., et al. 2011. Upper Jurassic radiolarians from the Naga Ophiolite, Nagaland, northeast India. Gondwana Research, 20: 638-644. Davis, A.M., et al. 2002. Paleogene island arc collision-related conglomerates, Yarlung-Tsangpo suture zone, Tibet. Sedimentary Geology, 150: 247-273. Dickinson, W.R. and Suczek, C.A., 1979. Plate tectonics and sandstone compositions. Am. Assoc. Pet. Geol. Bull., 63, 2164-2182, (1979). Garzanti, E., et al., 2007. Orogenic belts and orogenic

  14. Provenance and tectonic setting of siliciclastic rocks associated with the Neoproterozoic Dahongliutan BIF: Implications for the Precambrian crustal evolution of the Western Kunlun orogenic belt, NW China

    NASA Astrophysics Data System (ADS)

    Hu, Jun; Wang, He; Wang, Min

    2017-10-01

    The Late Neoproterozoic Dahongliutan BIF is associated with siliciclastic rocks in the Tianshuihai terrane of the Western Kunlun orogenic belt (WKO), NW China. The sedimentary rocks have various weathering indices (e.g., CIA = 57-87, PIA = 61-96 and Th/U = 4.85-12.45), indicative of varying degrees of weathering in the source area. The rocks have trace element ratios, such as Th/Sc = 0.60-1.21 and Co/Th = 0.29-1.67, and light rare earth element (LREE) enriched chondrite-normalized REE patterns, suggesting that they were mainly sourced from intermediate and felsic rocks. Available U-Pb ages of detrital zircon from these rocks reveal that the detrital sources may have been igneous and metamorphic rocks from the WKO and the Tarim Block. Our study suggests that the Dahongliutan BIF and hosting siliciclastic rocks may have deposited in a setting transitional from a passive to active continental margin, probably related to the Late Neoproterozoic-Early Cambrian seafloor spreading and subduction of the Proto-Tethys Ocean. U-Pb dating of 163 detrital zircons defines five major age populations at 2561-2329 Ma, 2076-1644 Ma, 1164-899 Ma, 869-722 Ma and 696-593 Ma. These age groups broadly correspond to the major stages of supercontinent assembly and breakup events widely accepted for Columbia, Rodinia and Gondwana. Some zircons have TDM2 model ages of 3.9-1.8 Ga and negative εHf(t) values, suggesting that the Archean to Paleoproterozoic (as old as Eoarchean) crustal materials were episodically reworked and incorporated into the late magmatic process in the WKO. Some Neoproterozoic zircons have TDM2 model ages of 1.47-1.07 Ga and 1.81-1.53 Ga and positive εHf(t) values, indicating juvenile crustal growth during the Mesoproterozoic. Our new results, combined with published data, imply that both the Tianshuihai terrane in the WKO and the Tarim Block share the same Precambrian tectonic evolution history.

  15. Detrital geochronology of unroofing magmatic complexes

    NASA Astrophysics Data System (ADS)

    Malusà, Marco Giovanni; Villa, Igor Maria; Vezzoli, Giovanni; Garzanti, Eduardo

    2010-05-01

    Tectonic reconstructions performed in recent years are increasingly based on petrographic (Dickinson & Suczek, 1979; Garzanti et al., 2007) and geochronological (Brandon et al., 1998; DeCelles et al., 2004) analyses of detrital systems. Detrital age patterns are traditionally interpreted as a result of cooling induced by exhumation (Jäger, 1967; Dodson, 1973). Such an approach can lead to infer extremely high erosion rates (Giger & Hurford 1989) that conflict with compelling geological evidence (Garzanti & Malusà, 2008). This indicates that interpretations solely based on exhumational cooling may not have general validity (Villa, 2006). Here we propose a new detrital geochronology model that takes into account the effects of both crystallization and exhumational cooling on geochronometers, from U-Pb on zircon to fission tracks on apatite. This model, specifically designed for unroofing magmatic complexes, predicts both stationary and moving mineral-age peaks. Because its base is the ordinary interaction between endogenic and exogenic processes, it is applicable to any geological setting. It was tested on the extremely well-studied Bregaglia-Bergell pluton in the Alps, and on the sedimentary succession derived from its erosion. The consistency between predicted and observed age patterns validates the model. Our results demonstrate that volcanoes were active on top of the growing Oligocene Alps, and resolve a long-standing paradox in quantitative erosion-sedimentation modelling, the scarcity of sediment during apparently fast erosion. Dickinson, W. R. & Suczek, C. A. Plate tectonics and sandstone composition. Am. Assoc. Petrol. Geol. Bull. 63, 2164-2172 (1979). Garzanti, E., Doglioni, C., Vezzoli. G. & Andò, S. Orogenic belts and orogenic sediment provenance. J. Geol. 115, 315-334 (2007). Brandon, M. T., Roden-Tice, M. K. & Garver, J. I. Cenozoic exhumation of the Cascadia accretionary wedge in the Olympic Mountains, northwest Washington State. Geol. Soc. Am. Bull

  16. U-Pb ages and Hf isotope compositions of zircons in plutonic rocks from the central Famatinian arc, Argentina

    NASA Astrophysics Data System (ADS)

    Otamendi, Juan E.; Ducea, Mihai N.; Cristofolini, Eber A.; Tibaldi, Alina M.; Camilletti, Giuliano C.; Bergantz, George W.

    2017-07-01

    The Famatinian arc formed around the South Iapetus rim during the Ordovician, when oceanic lithosphere subducted beneath the West Gondwana margin. We present combined in situ U-Th-Pb and Lu-Hf isotope analyses for zircon to gain insights into the origin and evolution of Famatinian magmatism. Zircon crystals sampled from four intermediate and silicic plutonic rocks confirm previous observations showing that voluminous magmatism took place during a relatively short pulse between the Early and Middle Ordovician (472-465 Ma). The entire zircon population for the four plutonic rocks yields coherent εHf negative values and spreads over several ranges of initial εHf(t) units (-0.3 to -8.0). The range of εHf units in detrital zircons of Famatinian metasedimentary rocks reflects a prolonged history of the cratonic sources during the Proterozoic to the earliest Phanerozoic. Typical tonalites and granodiorites that contain zircons with evolved Hf isotopic compositions formed upon incorporating (meta)sedimentary materials into calc-alkaline metaluminous magmas. The evolved Hf isotope ratios of zircons in the subduction related plutonic rocks strongly reflect the Hf isotopic character of the metasedimentary contaminant, even though the linked differentiation and growth of the Famatinian arc crust was driven by ascending and evolving mantle magmas. Geochronology and Hf isotope systematics in plutonic zircons allow us understanding the petrogenesis of igneous series and the provenance of magma sources. However, these data could be inadequate for computing model ages and supporting models of crustal evolution.

  17. Filling in the juvenile magmatic gap: Evidence for uninterrupted Paleoproterozoic plate tectonics

    NASA Astrophysics Data System (ADS)

    Partin, C. A.; Bekker, A.; Sylvester, P. J.; Wodicka, N.; Stern, R. A.; Chacko, T.; Heaman, L. M.

    2014-02-01

    Despite several decades of research on growth of the continental crust, it remains unclear whether the production of juvenile continental crust has been continuous or episodic throughout the Precambrian. Models for episodic crustal growth have gained traction recently through compilations of global U-Pb zircon age frequency distributions interpreted to delineate peaks and lulls in crustal growth through geologic time. One such apparent trough in zircon age frequency distributions between ∼2.45 and 2.22 Ga is thought to represent a pause in crustal addition, resulting from a global shutdown of magmatic and tectonic processes. The ∼2.45-2.22 Ga magmatic shutdown model envisions a causal relationship between the cessation of plate tectonics and accumulation of atmospheric oxygen over the same period. Here, we present new coupled U-Pb, Hf, and O isotope data for detrital and magmatic zircon from the western Churchill Province and Trans-Hudson orogen of Canada, covering an area of approximately 1.3 million km2, that demonstrate significant juvenile crustal production during the ∼2.45-2.22 Ga time interval, and thereby argue against the magmatic shutdown hypothesis. Our data is corroborated by literature data showing an extensive 2.22-2.45 Ga record in both detrital and magmatic rocks on every continent, and suggests that the operation of plate tectonics continued throughout the early Paleoproterozoic, while atmospheric oxygen rose over the same time interval. We argue that uninterrupted plate tectonics between ∼2.45 and 2.22 Ga would have contributed to efficient burial of organic matter and sedimentary pyrite, and the consequent rise in atmospheric oxygen documented for this time interval.

  18. Mass-spectrometric mining of Hadean zircons by automated SHRIMP multi-collector and single-collector U/Pb zircon age dating: The first 100,000 grains

    NASA Astrophysics Data System (ADS)

    Holden, Peter; Lanc, Peter; Ireland, Trevor R.; Harrison, T. Mark; Foster, John J.; Bruce, Zane

    2009-09-01

    The identification and retrieval of a large population of ancient zircons (>4 Ga; Hadean) is of utmost priority if models of the early evolution of Earth are to be rigorously tested. We have developed a rapid and accurate U-Pb zircon age determination protocol utilizing a fully automated multi-collector ion microprobe, the ANU SHRIMP II, to screen and date these zircons. Unattended data acquisition relies on the calibration of a digitized sample map to the Sensitive High Resolution Ion MicroProbe (SHRIMP) sample-stage co-ordinate system. High precision positioning of individual grains can be produced through optical image processing of a specified mount location. The focal position of the mount can be optimized through a correlation between secondary-ion steering and the spot position on the target. For the Hadean zircon project, sample mounts are photographed and sample locations (normally grain centers) are determined off-line. The sample is loaded, reference points calibrated, and the target positions are then visited sequentially. In SHRIMP II multiple-collector mode, zircons are initially screened (ca. 5 s data acquisition) through their 204Pb corrected 207Pb/206Pb ratio; suitable candidates are then analyzed in a longer routine to obtain better measurement statistics, U/Pb, and concentration data. In SHRIMP I and SHRIMP RG, we have incorporated the automated analysis protocol to single-collector measurements. These routines have been used to analyze over 100,000 zircons from the Jack Hills quartzite. Of these, ca. 7%, have an age greater than 3.8 Ga, the oldest grain being 4372 +/- 6 Ma (2[sigma]), and this age is part of a group of analyses around 4350 Ma which we interpret as the age when continental crust first began to coalesce in this region. In multi-collector mode, the analytical time taken for a single mount with 400 zircons is approximately 6 h; whereas in single-collector mode, the analytical time is ca. 17 h. With this productivity, we can produce

  19. Contrasting Cu-Au and Sn-W Granite Metallogeny through the Zircon Geochemical and Isotopic Record

    NASA Astrophysics Data System (ADS)

    Gardiner, Nicholas; Hawkesworth, Chris; Robb, Laurence; Whitehouse, Martin; Roberts, Nick; Kirkland, Chris

    2017-04-01

    -hydrothermal deposit, and empirical observations suggest that this threshold may be marked by zircon Eu/Eu* values of ca. < 0.08. The isotope and trace element signatures of both magmatic and detrital zircons can be developed into a useful exploration tool.

  20. A 4.43 Ga Transition from Mega-impact to Habitability Deduced from Microstructural Geochronology of Martian Zircon and Baddeleyite

    NASA Astrophysics Data System (ADS)

    Moser, D.; Reinhard, D. A.; Larson, D. J.; McCubbin, F. M.; Darling, J.; White, L. F.; Arcuri, G.; Irving, A. J.; Tait, K.; Barker, I.

    2017-12-01

    The rates at which early planetary surfaces like those of Mars and Earth transitioned to stability within the heavy bombardment epoch are poorly constrained. Here we show through analysis of the shock history of the earliest mineral remnants of Mars crust, specifically the accessory and highly refractory phases zircon and baddeleyite in martian meteorites, that the transition for Mars was relatively rapid and early. The Moon-sized impactor widely believed to have generated the martian hemispheric dichotomy, would have caused catastrophic heating, impact metamorphism and global re-surfacing by magma.This process would either destroy any primordial accessory phases through melting and vaporization, or impart micro- or nano-structural signatures of ultra-high temperature and/or pressure metamorphism on survivor crystals. We have conducted atom probe and/or correlative electron microscopy on intensely shocked and heated zircon and baddeleyite reference samples from Earth and the Moon, as well as from 4.43 Ga grains occurring as crystals and in lithic clasts in six polished surfaces of the Rabt Sbayta suite of martian polymict regolith breccias (NWA 7475, NWA 7034, NWA 7906, Rabt Sbayta 003). The martian population (n=68) shows no micro- or nano-signatures of ultra high temperature or pressure metamorphism. Instead, it exhibits mostly low-grade shock and thermal features consistent with regolith formation at 1.5 Ga and recent low pressure ( 5GPa) launch to Earth. Taken together with the time for decay of the mega-impact heat effects, as well as the 4.50 Ga age estimate for martian mantle solidification (modelled by other workers) our results indicate an early, 70 million year long transition from initiation of the hemispheric dichotomy to establishment of at least one domain of persistently stable and potentially habitable crust. The accelerated deep mantle convection prompted by mega-impact may have also increased the transport rate of volatiles to the Martian exterior

  1. CL-imaging and ion microprobe dating of single zircons from a high-grade rock from the Central Zone, Limpopo Belt, South Africa: Evidence for a single metamorphic event at ˜2.0 Ga

    NASA Astrophysics Data System (ADS)

    Mouri, H.; Brandl, G.; Whitehouse, M.; de Waal, S.; Guiraud, M.

    2008-02-01

    The combination of ion microprobe dating and cathodoluminescence (CL) imaging of zircons from a high-grade rock from the Central Zone of the Limpopo Belt were used to constrain the age of metamorphic events in the area. Zircon grains extracted from an orthopyroxene-gedrite-bearing granulite were prepared for single crystal CL-imaging and ion microprobe dating. The grains display complex zoning when using SEM-based CL-imaging. A common feature in most grains is the presence of a distinct core with a broken oscillatory zoned structure, which clearly appears to be the remnant of an original grain of igneous origin. This core is overgrown by an unzoned thin rim measuring about 10-30 μm in diameter, which is considered as new zircon growth during a single metamorphic event. Selected domains of the zircon grains were analysed for U, Pb and Th isotopic composition using a CAMECA IMS 1270 ion microprobe (Nordsim facility). Most of the grains define a near-concordant cluster with some evidence of Pb loss. The most concordant ages of the cores yielded a weighted mean 207Pb/ 206Pb age of 2689 ± 15 (2 σ) Ma, interpreted as the age of the protolith of an igneous origin. The unzoned overgrowths of the zircon grains yielded a considerably younger weighted mean 207Pb/ 206Pb age of ˜2006.5 ± 8.0 Ma (2 σ), and these data are interpreted to reflect closely the age of the ubiquitous high-grade metamorphic event in the Central Zone. This study shows clearly, based on both the internal structure of the zircons and the data obtained by ion microprobe dating, that only a single metamorphic event is recorded by the studied 2.69 Ga old rocks, and we found no evidence of an earlier metamorphic event at ˜2.5 Ga as postulated earlier by some workers.

  2. Recovering the primary geochemistry of Jack Hills zircons through quantitative estimates of chemical alteration

    NASA Astrophysics Data System (ADS)

    Bell, Elizabeth A.; Boehnke, Patrick; Harrison, T. Mark

    2016-10-01

    Despite the robust nature of zircon in most crustal and surface environments, chemical alteration, especially associated with radiation damaged regions, can affect its geochemistry. This consideration is especially important when drawing inferences from the detrital record where the original rock context is missing. Typically, alteration is qualitatively diagnosed through inspection of zircon REE patterns and the style of zoning shown by cathodoluminescence imaging, since fluid-mediated alteration often causes a flat, high LREE pattern. Due to the much lower abundance of LREE in zircon relative both to other crustal materials and to the other REE, disturbance to the LREE pattern is the most likely first sign of disruption to zircon trace element contents. Using a database of 378 (148 new) trace element and 801 (201 new) oxygen isotope measurements on zircons from Jack Hills, Western Australia, we propose a quantitative framework for assessing chemical contamination and exchange with fluids in this population. The Light Rare Earth Element Index is scaled on the relative abundance of light to middle REE, or LREE-I = (Dy/Nd) + (Dy/Sm). LREE-I values vary systematically with other known contaminants (e.g., Fe, P) more faithfully than other suggested proxies for zircon alteration (Sm/La, various absolute concentrations of LREEs) and can be used to distinguish primary compositions when textural evidence for alteration is ambiguous. We find that zircon oxygen isotopes do not vary systematically with placement on or off cracks or with degree of LREE-related chemical alteration, suggesting an essentially primary signature. By omitting zircons affected by LREE-related alteration or contamination by mineral inclusions, we present the best estimate for the primary igneous geochemistry of the Jack Hills zircons. This approach increases the available dataset by allowing for discrimination of on-crack analyses (and analyses with ambiguous or no information on spot placement or

  3. Extinct Plutonium Geochemistry of Ancient Hadean Zircons

    NASA Astrophysics Data System (ADS)

    Turner, G.; Gilmour, J.; Crowther, S.; Busfield, A.; Mojzsis, S.; Harrison, M.

    2005-12-01

    The abundance of 244Pu in the early solar system has important implications for r-process nucleosynthesis and models of noble gas transport within the Earth's mantle. Our recent discovery(1) of xenon isotopes from the in-situ decay of 244Pu in ancient Jack Hills zircons promises to provide a new time-sensitive window on the first 500 Ma of Earth history. We have extended this initial work by the use of resonance ioniisation mass spectrometry to analyse xenon released by stepped heating from 17 individual zircons with Pb-Pb ages in the range 3.95 to 4.18 Ga. Our immediate objectives are to determine the causes of variations in the inferred Pu/U ratios and in the longer term to determine the initial Pu/U ratio of the Earth. The Pu/U ratios calculated for individual zircons may be expected to vary as a result of igneous fractionation and also from differential loss of Pu and U fission xenon in the last 4 Ga. We have studied the effects of xenon loss by irradiating the zircons with thermal neutrons to generate xenon from 235U neutron fission in order to determine U/Xe ratios and apparent ages. 131Xe/134Xe and 132Xe/134Xe ratios can be used to calculate the relative contributions from 244Pu and 238U spontaneous fission and 235U neutron fission. The measured Pu/U ratios (back calculated to 4.56 Ga on the basis of the individual Pb-Pb ages) range from zero to 0.012. The highest ratio in our initial study was 0.008 (note that the published ratio has been revised upwards on the basis of improved decay parameters for 238U spontaneous fission). Comparison of Pb-Pb and U-Xe ages indicate varying amounts of xenon loss, over 50% in some cases. While this accounts for some of the variability in the inferred Pu/U, igneous fractionation may also play a part, and we are currently attempting to investigate this by a comparison with REE abundances. Reference: (1) Turner et al. (2004) Science, 306, 89-91.

  4. The history of a continent from U-Pb ages of zircons from Orinoco River sand and Sm-Nd isotopes in Orinoco basin river sediments

    USGS Publications Warehouse

    Goldstein, S.L.; Arndt, N.T.; Stallard, R.F.

    1997-01-01

    igneous and metamorphic history of these sources, as recorded by the detrital zircons, is that of the Orinoco basin basement. This implies that, despite evidence of fast sedimentary recycling, global similarities in Nd crustal-residence ages, and the probability of cross-continent mixing through continental drift, the sedimentary material carried by individual rivers is mainly derived from the crystalline basement in the basin. The global semblance in Nd isotope ratios in major river sediments and atmospheric dusts results from the averaging effect of large-scale sampling of the continents, which are heterogeneous in age on smaller regional scales. A large portion of the continental crust in the Orinoco basin formed during the Trans-Amazonian orogeny at 2.0-2.1 Ga, and smaller portions formed both earlier, at ??? 2.8 Ga, and later, after 1.6 Ga. These observations, which are consistent with the relative sizes of crustal age provinces in the Orinoco basin, indicate that sediments from the lower Orinoco and Andean tributaries contain 25-35% of material added to the crust since Trans-Amazonian times. Nd model ages of these sediments underestimate the average crust-formation age of the basement of the Orinoco basin by only about 10%. If this relationship holds in other river basins, then Nd model ages of major rivers and wind blown particulates indicate that the mean age of the continental crust is ??? 1.9-2 Ga. ?? 1997 Elsevier Science B.V.

  5. Elucidating tectonic events and processes from variably tectonized conglomerate clast detrital geochronology: examples from the Hongliuhe Formation in the southern Central Asian Orogenic Belt, NW China

    NASA Astrophysics Data System (ADS)

    Cleven, Nathan; Lin, Shoufa; Davis, Donald; Xiao, Wenjiao; Guilmette, Carl

    2017-04-01

    This work expands upon detrital zircon geochronology with a sampling and analysis strategy dating granitoid conglomerate clasts that exhibit differing degrees of internal ductile deformation. As deformation textures within clastic material reflect the variation and history of tectonization in the source region of a deposit, we outline a dating methodology that can provide details of the provenance's tectonomagmatic history from deformation-relative age distributions. The method involves bulk samples of solely granitoid clasts, as they are representative of the magmatic framework within the provenance. The clasts are classified and sorted into three subsets: undeformed, slightly deformed, and deformed. LA-ICPMS U-Pb geochronology is performed on zircon separates of each subset. Our case study, involving the Permian Hongliuhe Formation in the southern Central Asian Orogenic Belt, analyzes each of the three clast subsets, as well as sandstone detrital samples, at three stratigraphic levels to yield a profile of the unroofed provenance. The age spectra of the clast samples exhibit different, wider distributions than sandstone samples, considered an effect of proximity to the respective provenance. Comparisons of clast data to sandstone data, as well as comparisons between stratigraphic levels, yield indications of key tectonic processes, in addition to the typical characteristics provided by detrital geochronology. The clast data indicates a minimal lag time, implying rapid exhumation rates, whereas sandstone data alone would indicate a 90 m.y. lag time. Early Paleozoic arc building episodes appear as Ordovician peaks in sandstone data, and Silurian-Devonian peaks in clast data, indicating a younging of magmatism towards the proximal provenance. A magmatic hiatus starts in the Devonian, correlating with the latest age of deformed clasts, interpreted as timing of collisional tectonics. Provenance interpretation using the correlations seen between the clast and sandstone

  6. The White Nile as a source for Nile sediments: Assessment using U-Pb geochronology of detrital rutile and monazite

    NASA Astrophysics Data System (ADS)

    Be'eri-Shlevin, Yaron; Avigad, Dov; Gerdes, Axel

    2018-04-01

    Basement terranes exposed at the headwaters of the White Nile include Archean-Paleoproterozoic rocks of the Congo Craton, whose northern sectors were severely reworked during Neoproterozoic orogeny. New U-Pb analyses of detrital rutile and monazite from early Quaternary to Recent coastal quartz sands of Israel, at the northeast extension of the Nile sedimentary system, yield mostly late Neoproterozoic ages, with a dominant peak at ca. 600 Ma. While derivation from the reworked sectors of the Craton cannot be negated, the absence of pre-Neoproterozoic rutile and monazite indicates that the detrital contribution from the Congo cratonic nuclei into the main Nile was insignificant. The near absence of White Nile basement-derived heavy minerals from the Nile sands arriving at the Eastern Mediterranean may be explained by a number of factors such as relatively minor erosion of the Cratonic basement nuclei during the Quaternary, late connection of the White Nile to the main Nile system with a possibility that northern segments connected prior to more southerly ones, and a long-term effective sediment blockage mechanism at the mouth of White Nile. Likewise, our previous study demonstrated that Nile sands display a detrital zircon U-Pb-Hf pattern consistent with significant recycling of NE African Paleozoic sediments. It is thus plausible that any detrital contribution from White Nile basement rocks was thoroughly diluted by eroded Paleozoic sediments, or their recycled products, which were likely the greatest sand reservoir in the region. This study adds to previous studies showing the advantage of a multi mineral U-Pb geochronology strategy in constraining sediment provenance patterns.

  7. Magmatic @d^1^8O in 4400-3900 Ma detrital zircons: A record of the alteration and recycling of crust in the Early Archean [rapid communication

    NASA Astrophysics Data System (ADS)

    Cavosie, A. J.; Valley, J. W.; Wilde, S. A.

    2005-07-01

    Ion microprobe analyses of δ 18O in 4400-3900 Ma igneous zircons from the Jack Hills, Western Australia, provide a record of the oxygen isotope composition of magmas in the earliest Archean. We have employed a detailed analysis protocol aimed at correlating spatially related micro-volumes of zircon concordant in U/Pb age with δ 18O and internal zoning. Simultaneous analysis of 18O and 16O with dual Faraday cup detectors, combined with frequent standardization, has yielded data with improved accuracy and precision over prior studies, and resulted in a narrower range of what is interpreted as magmatic δ 18O in > 3900 Ma zircons. Preserved magmatic δ 18O values from individual zircons (Zrc) range from 5.3‰ to 7.3‰ (VSMOW), and increasingly deviate from the mantle range of 5.3 ± 0.3‰ as zircons decrease in age from 4400 to 4200 Ma. Elevated δ 18O (Zrc) values up to 6.5‰ occur as early as 4325 Ma, which suggests that evolved rocks were incorporated into magmas within ˜230 Ma of Earth's accretion. Values of magmatic δ 18O (Zrc) as high as 7.3‰ are recorded in zircons by 4200 Ma, and are common thereafter. The protoliths of the magmas these zircons crystallized in were altered by low temperature interaction with liquid water near Earth's surface. These results provide the strongest evidence yet for the existence of liquid water oceans and supracrustal rocks by approximately 4200 Ma, and possibly as early as 4325 Ma. The range of magmatic δ 18O values in the 4400-3900 Ma zircons is indistinguishable from Archean igneous zircons, suggesting similar magmatic processes occurred over the first two billion years of recorded Earth history. Zircons with sub-solidus alteration histories, identified by the presence of disturbed internal zoning patterns, record δ 18O values both below (4.6‰) and above (10.3‰) the observed range for primary magmatic zircon, and are unreliable indicators of Early Archean magma chemistry.

  8. Laser ablation U-Th-Sm/He dating of detrital apatite

    NASA Astrophysics Data System (ADS)

    Guest, B.; Pickering, J. E.; Matthews, W.; Hamilton, B.; Sykes, C.

    2016-12-01

    Detrital apatite U-Th-Sm/He thermochronology has the potential to be a powerful tool for conducting basin thermal history analyses as well as complementing the well-established detrital zircon U-Pb approach in source to sink studies. A critical roadblock that prevents the routine application of detrital apatite U-Th-Sm/He thermochronology to solving geological problems is the costly and difficult whole grain approach that is generally used to obtain apatite U-Th-Sm/He data. We present a new analytical method for laser ablation thermochronology on apatite. Samples are ablated using a Resonetics™ 193 nm excimer laser and liberated 4He is measured using an ASI (Australian Scientific Instruments) Alphachron™ quadrupole mass spectrometer system; collectively known as the Resochron™. The ablated sites are imaged using a Zygo ZescopeTM optical profilometer and ablated pit volume measured using PitVol, a custom MatLabTM algorithm. The accuracy and precision of the method presented here was confirmed using well-characterized Durango apatite and Fish Canyon Tuff (FCT) apatite reference materials, with Durango apatite used as a primary reference and FCT apatite used as a secondary reference. The weighted average of our laser ablation Durango ages (30.5±0.35 Ma) compare well with ages obtained using conventional whole grain degassing and dissolution U-Th-Sm/He methods (32.56±0.43 Ma) (Jonckheere et.al., 1 993; Farley, 2000; McDowell et.al., 2005) for chips of the same Durango crystal. These Durango ages were used to produce a K-value to correct the secondary references and unknown samples. After correction, FCT apatite has a weighted average age of 28.37 ± 0.96 Ma, which agrees well with published ages. As a further test of this new method we have conducted a case study on a set of samples from the British Mountains of the Yukon Territory in NW Canada. Sandstone samples collected across the British Mountains were analyzed using conventional U-Th-Sm/He whole grain

  9. Detrital Zircon Provenance Record of Pre-Andean to Modern Tectonics in the Northern Andes: Examples from Peru, Ecuador, and Colombia

    NASA Astrophysics Data System (ADS)

    George, S. W. M.; Jackson, L. J.; Horton, B. K.

    2015-12-01

    Detrital zircon U-Pb age distributions from modern rivers and Mesozoic-Cenozoic basin fill in the northern Andes provide insights into pre-Andean, Andean, and active uplift and exhumation of distinctive sediment source regions. Diagnostic age signatures enable straightforward discrimination of competing sediment sources within the Andean magmatic arc (Western Cordillera-Central Cordillera), retroarc fold-thrust belt (Eastern Cordillera-Subandean Zone), and Amazonian craton (composed of several basement provinces). More complex, however, are the mid/late Cenozoic provenance records generated by recycling of basin fill originally deposited during early/mid Mesozoic extension, late Mesozoic thermal subsidence, and early Cenozoic shortening. Although subject to time-transgressive trends, regionally significant provenance patterns in Peru, Ecuador, and Colombia reveal: (1) Triassic-Jurassic growth of extensional subbasins fed by local block uplifts (with commonly unimodal 300­-150 Ma age peaks); (2) Cretaceous deposition in an extensive postrift setting fed by principally cratonic sources (with common 1800-900 Ma ages); and (3) Cenozoic growth of a broad flexural basin fed initially fed by magmatic-arc rocks (100-0 Ma), then later dominance by thrust-belt sedimentary rocks with progressively greater degrees of basin recycling (yielding diverse and variable age populations from the aforementioned source regions). U-Pb results from modern rivers and smaller subbasins prove useful in evaluating source-to-sink relationships, downstream mixing relationships, hinterland-foreland basin connectivity, paleodrainage integration, and tectonic/paleotopographic reconstructions. Most but not all of the elevated intermontane basins in the modern hinterland of the northern Andes contain provenance records consistent with genesis in a broader foreland basin developed at low elevation. Downstream variations within modern axial rivers and Cenozoic axial basins inform predictive models of

  10. Paleozoic and Paleoproterozoic Zircon in Igneous Xenoliths Assimilated at Redoubt Volcano, Alaska

    NASA Astrophysics Data System (ADS)

    Bacon, C. R.; Vazquez, J. A.; Wooden, J. L.

    2010-12-01

    Historically active Redoubt Volcano is a basalt-to-dacite cone constructed upon the Jurassic-early Tertiary Alaska-Aleutian Range batholith. New SHRIMP-RG U-Pb age and trace-element concentration results for zircons from gabbroic xenoliths and crystal-rich andesitic mush from a late Pleistocene pyroclastic deposit indicate that ~310 Ma and ~1865 Ma igneous rocks underlie Redoubt at depth. Two gabbros have sharply terminated prismatic zircons that yield ages of ~310 Ma. Zircons from a crystal mush sample are overwhelmingly ~1865 Ma and appear rounded due to incomplete dissolution. Binary plots of element concentrations or ratios show clustering of data for ~310-Ma grains and markedly coherent trends for ~1865-Ma grains; e.g., ~310-Ma grains have higher Eu/Eu* than most of the ~1865-Ma grains, the majority of which form a narrow band of decreasing Eu/Eu* with increasing Hf content which suggests that ~1865-Ma zircons come from igneous source rocks. It is very unlikely that detrital zircons from a metasedimentary rock would have this level of homogeneity in age and composition. One gabbro contains abundant ~1865 Ma igneous zircons, ~300-310 Ma fluid-precipitated zircons characterized by very low U and Th concentrations and Th/U ratios, and uncommon ~100 Ma zircons. We propose that (1) ~310 Ma gabbro xenoliths from Redoubt Volcano belong to the same family of plutons dated by Aleinikoff et al. (USGS Circular 1016, 1988) and Gardner et al. (Geology, 1988) located ≥500 km to the northeast in basement rocks of the Wrangellia and Alexander terranes and (2) ~1865 Ma zircons are inherited from igneous rock, potentially from a continental fragment that possibly correlates with the Fort Simpson terrane or Great Bear magmatic zone of the Wopmay Orogen of northwestern Laurentia. Possibly, elements of these Paleoproterozoic terranes intersected the Paleozoic North American continental margin where they may have formed a component of the basement to the Wrangellia

  11. HAFNIAN ZIRCONS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    von Knorring, O.; Hornung, G.

    1961-06-17

    Two hafnia zircons were examined in detail, one from Mtoko in Southern Rhodesia, containing 21% HfO/sub 2/, and the other from Karibib in South-West Africa, with 31% HfO/sub 2/. In both cases the zircons are associated with the later tantalum-rich phase of mineralization. The Mtoko zircon forms small, mauve- colored, independent crystals in the albitic zone of the pegmatite. The zircon from Karibib occurs in larger reddish-brown masses, partly intergrown with minute manganotantalite crystals and set in a matrix of lithium-bearing mica, albite, quartz and kaolinized feldspar. Some crystals show dominant pyramid faces, with a suppressed prism. Both zircons exhibitmore » an intense golden-yellow fluorescence in UV light. The zircon from Karibib was found to be only weakly radioactive. Data are given concerning various properties of the two zircons. (P.C.H.)« less

  12. Paleogeography, Paleo-drainage Systems, and Tectonic Reconstructions of Eocene Northern South America Constrained by U-Pb Detrital Zircon Geochronology

    NASA Astrophysics Data System (ADS)

    Xie, X.; Mann, P.; Escalona, A.

    2008-12-01

    Thick, Eocene to Miocene clastic sedimentary basins are widespread across on- and offshore northern South America and have been identified using seismic reflection data in offshore basins of the Leeward Antilles, the Lesser Antilles arc and forearc, and the Barbados accretionary prism. Several 3 to12-km-thick Paleogene depocenters occur in shelf to deep basinal settings along the offshore margins of Venezuela, Trinidad and Tobago, and Barbados. Previous studies proposed that the proto-Orinoco River has been the single fluvial source for these distal, continentally-derived sandstone units along northern Venezuela as part of the early Eocene to Miocene, proto-Maracaibo fluvial-deltaic system that emanated from the northern Andes of western Venezuela and Colombia. Those distal sandstones were displaced eastward with the movement of the Caribbean plate by several hundred kilometers and are now found in basins and islands of the southeastern Caribbean region. We collected nine Eocene age sandstone samples from well cores and outcrops along the northern South America margin, including Lake Maracaibo, Trinidad and Tobago, and Barbados Island. In total, 945 single detrital zircon grains were analyzed using LA-ICP-MS. The objective is to reconstruct the paleogeography, paleo-drainage system, and tectonic history during Eocene time. New data show that the Eocene Misoa Formation of Lake Maracaibo was characterized by a mixture of Precambrian, Paleozoic, and Mesozoic ages matching age provinces from eastern Cordillera and the Guayana Shield, which is consistent with previous proto-Orinoco River model flowing from the western Amazonian region of Colombia and Brazil through the Maracaibo basin into the area of western Falcon basin. However, coeval Eocene samples from Barbados and Trinidad show a much different age population dominated by Precambrian matching the eastern part of the Guyana shield to the south, which suggests that the western onland system and eastern offshore

  13. Relict basin closure accommodates continental convergence with minimal crustal shortening or deceleration of plate motion as inferred from detrital zircon provenance in the Caucasus

    NASA Astrophysics Data System (ADS)

    Cowgill, E.; Forte, A. M.; Niemi, N. A.; Avdeev, B.; Tye, A. R.; Trexler, C. C.; Javakhishvili, Z.; Elashvili, M.; Godoladze, T.

    2016-12-01

    Comparison of plate convergence with the timing and magnitude of upper-crustal shortening in collisional orogens indicates both shortening deficits (200-1700 km) and significant (30-40%) plate deceleration during collision, the cause(s) for which remain debated. The Greater Caucasus Mountains, which result from post-collisional Cenozoic closure of a relict Mesozoic back-arc basin on the northern margin of the Arabia-Eurasia collision zone, help reconcile these debates. Here we use U-Pb detrital zircon provenance data and the regional geology of the Caucasus to investigate the width of the now-consumed Mesozoic back-arc basin and its closure history. The provenance data record distinct southern and northern provenance domains that persisted until at least the Miocene; maximum basin width was likely 350-400 km. We propose that closure of the back-arc basin initiated at 35 Ma, coincident with initial (soft) Arabia-Eurasia collision along the Bitlis suture, eventually leading to 5 Ma (hard) collision between the Lesser Caucasus arc and the Scythian platform to form the Greater Caucasus Mountains. Final basin closure triggered deceleration of plate convergence and tectonic reorganization throughout the collision. Post-collisional subduction of such small (500-1000 km wide) relict ocean basins can account for both shortening deficits and delays in plate deceleration by accommodating convergence via subduction/underthrusting, although such shortening is easily missed if it occurs along structures hidden within flysch/slate belts. Relict-basin closure is likely typical early in continental collision at the end of a Wilson cycle due to the irregularity of colliding margins and extensive back-arc basin development during closure of long-lived ocean basins.

  14. Major zircon megacryst suites of the Indo-Pacific lithospheric margin (ZIP) and their petrogenetic and regional implications

    NASA Astrophysics Data System (ADS)

    Sutherland, Lin; Graham, Ian; Yaxley, Gregory; Armstrong, Richard; Giuliani, Gaston; Hoskin, Paul; Nechaev, Victor; Woodhead, Jon

    2016-04-01

    Zircon megacrysts (± gem corundum) appear in basalt fields of Indo-Pacific origin over a 12,000 km zone (ZIP) along West Pacific continental margins. Age-dating, trace element, oxygen and hafnium isotope studies on representative zircons (East Australia-Asia) indicate diverse magmatic sources. The U-Pb (249 to 1 Ma) and zircon fission track (ZFT) ages (65 to 1 Ma) suggest thermal annealing during later basalt transport, with < 1 to 203 Ma gaps between the U-Pb and ZFT ages. Magmatic growth zonation and Zr/Hf ratios (0.01-0.02) suggest alkaline magmatic sources, while Ti—in—zircon thermometry suggests that most zircons crystallized within ranges between 550 and 830 °C. Chondrite-normalised multi-element plots show variable enrichment patterns, mostly without marked Eu depletion, indicating little plagioclase fractionation in source melts. Key elements and ratios matched against zircons from magmatic rocks suggest a range of ultramafic to felsic source melts. Zircon O-isotope ratios (δ18O in the range 4 to 11‰) and initial Hf isotope ratios (ɛHf in the range +2 to +14) encompass ranges for both mantle and crustal melts. Calculated Depleted Mantle (TDM 0.03-0.56 Ga) and Crustal Residence (0.20-1.02 Ga) model ages suggest several mantle events, continental break-ups (Rodinia and Gondwana) and convergent margin collisions left imprints in the zircon source melts. East Australian ZIP sites reflect prolonged intraplate magmatism (~85 Ma), often during times of fast-migrating lithosphere. In contrast, East Asian-Russian ZIP sites reflect later basaltic magmatism (<40 Ma), often linked to episodes of back-arc rifting and spreading, slow-migrating lithosphere and slab subduction.

  15. Are arc lower crustal metasediments derived from above or below? A detrital zircon study in the lower crust of the Sierra Nevada, California

    NASA Astrophysics Data System (ADS)

    Klein, B. Z.; Jagoutz, O. E.; VanTongeren, J. A.

    2016-12-01

    Multiple hypotheses exist to explain the presence of metasedimentary rocks within arc lower crust. Relamination and subduction underplating require that sediments are derived from the subducted slab, while processes such as wall-rock return flow and retro-arc underthrusting imply that the sediments originated in the crust of the upper plate. Evaluating these proposed mechanisms has wide-reaching implications, including better constraining the mass-balance of active arcs, characterizing a theorized trigger mechanism for magmatic flare-up events, and more broadly for describing the tectonic construction of continental arcs. The southernmost Sierra Nevada, California, exposes a continuous continental arc cross-section that spans pressures from 3 to <10 kbar. Metasedimentary rocks are exposed at all crustal levels within this section and are intruded by 100 Ma igneous rocks. These metasediments offer a unique opportunity to evaluate the source, and emplacement of lower crustal metasediments into an active arc. The proposed mechanisms for the transport of sediments to the lower crust predict distinct sedimentary protoliths with unique detrital zircon (DZ) age spectra. Specifically, slab-derived sediments are likely to resemble the underplated Polona-Oroccopia-Rand schists to the south, with dominantly Mesozoic DZ peaks and few to no older grains. Upper plate derived sediments are predicted to have significant Paleozoic and Proterozoic DZ populations, in addition to arc-derived, Mesozoic meta-volcanic material. We have conducted a detailed DZ study of metasedimentary rocks in the Sierran lower and middle crust to assess these hypotheses. Initial results show that at least some of this material has an unambiguous slab-derived signature implying that relamination and/or subduction underplating were active processes during the construction of the Sierran arc system. We explore the implications of these processes for the magmatic and tectonic history of the Sierra Nevada, as

  16. U-Pb age constraints for the La Tuna Granite and Montevideo Formation (Paleoproterozoic, Uruguay): Unravelling the structure of the Río de la Plata Craton

    NASA Astrophysics Data System (ADS)

    Pamoukaghlián, Karina; Gaucher, Claudio; Frei, Robert; Poiré, Daniel G.; Chemale, Farid; Frei, Dirk; Will, Thomas M.

    2017-11-01

    The Río de la Plata Craton is a continental block that crops out in Uruguay, eastern Argentina, southernmost Brazil and Paraguay. It comprises in Uruguay the Piedra Alta, Tandilia and Nico Pérez terranes, separated by the Colonia and the Sarandí del Yí megashears. The La Tuna Granite, which intrudes the Araminda metasandstones in the Tandilia Terrane, was considered Cambrian in age and the intruded sandstones were assigned to the Neoproterozoic Piedras de Afilar Formation. We show that the granite is Paleoproterozoic in age and that the host metasandstones do not belong to the Piedras de Afilar Formation, but to the Paleoproterozoic Montevideo Formation. U-Pb LA ICP-MS of zircon ages for the La Tuna Granite yielded a concordant crystallization age of 2156 ± 26 Ma. Furthermore a metamorphic event at 2010 ± 9 Ma is revealed by Pb stepwise leaching dating of monazites. U-Pb detrital zircon ages of the host Araminda metasandstone yield an upper intercept discordia age of 2152 ± 29 Ma, which marks the intrusion of the La Tuna pluton, and which is in accordance with the zircon U-Pb LA ICP MS constraints. A concordant U-Pb detrital zircon age of 2465 ± 40 Ma provides a maximum depositional age constraint for the metapsammites. Comparing quartz arenites of the Ediacaran Piedras de Afilar Formation with the Araminda metaquartzites, we conclude that they are very similar regarding petrology but they differ in age and metamorphic overprint. Detrital zircons in quartz arenites of the Piedras de Afilar Formation show youngest ages of 1.0 Ga. On the other hand, detrital zircons recovered from the Araminda metasandstones and the age of the intruding granite allow interpreting a depositional age between 2465 and 2150 Ma. Nd model ages show crustal residence times in average more than 200 myr older for the Tandilia Terrane both in Uruguay and Argentina, with a significant Neoarchean component, which is lacking in the Piedra Alta Terrane. Whereas the Piedra Alta Terrane was

  17. Devonian post-orogenic extension-related volcano-sedimentary rocks in the northern margin of the Tibetan Plateau, NW China: Implications for the Paleozoic tectonic transition in the North Qaidam Orogen

    NASA Astrophysics Data System (ADS)

    Qin, Yu; Feng, Qiao; Chen, Gang; Chen, Yan; Zou, Kaizhen; Liu, Qian; Jiao, Qianqian; Zhou, Dingwu; Pan, Lihui; Gao, Jindong

    2018-05-01

    The Maoniushan Formation in the northern part of the North Qaidam Orogen (NQO), NW China, contains key information on a Paleozoic change in tectonic setting of the NQO from compression to extension. Here, new zircon U-Pb, petrological, and sedimentological data for the lower molasse sequence of the Maoniushan Formation are used to constrain the timing of this tectonic transition. Detrital zircons yield U-Pb ages of 3.3-0.4 Ga with major populations at 0.53-0.4, 1.0-0.56, 2.5-1.0, and 3.3-2.5 Ga. The maximum depositional age of the Maoniushan Formation is well constrained by a youngest detrital zircon age of ∼409 Ma. Comparing these dates with geochronological data for the region indicates that Proterozoic-Paleozoic zircons were derived mainly from the NQO as well as the Oulongbuluk and Qaidam blocks, whereas Archean zircons were probably derived from the Oulongbuluk Block and the Tarim Craton. The ∼924, ∼463, and ∼439 Ma tectonothermal events recorded in this region indicate that the NQO was involved in the early Neoproterozoic assembly of Rodinia and early Paleozoic microcontinental convergence. A regional angular unconformity between Devonian and pre-Devonian strata within the NQO suggests a period of strong mountain building between the Oulongbuluk and Qaidam blocks during the Silurian, whereas an Early Devonian post-orogenic molasse, evidence of extensional collapse, and Middle to Late Devonian bimodal volcanic rocks and Carboniferous marine carbonate rocks clearly reflect long-lived tectonic extension. Based on these results and the regional geology, we suggest that the Devonian volcano-sedimentary rocks within the NQO were formed in a post-orogenic extensional setting similar to that of the East Kunlun Orogen, indicating that a major tectonic transition from compression to extension in these two orogens probably commenced in the Early Devonian.

  18. Zircon U-Pb Ages from an Ultra-High Temperature Metapelite, Rauer Group, East Antarctica: Implications for Overprints by Grenvillian and Pan-African Events

    USGS Publications Warehouse

    Wang, Yanbin; Tong, Laixi; Liu, Dunyi

    2007-01-01

    SHRIMP U-Pb dating of zircon from an ultra-high temperature (UHT, ~1000 °C) granulite-facies metapelite from the Rauer Group, Mather Peninsula, east Antarctica, has yielded evidence for two episodes of metamorphic zircon growth, at ~1.00 Ga and ~530 Ma, and two episodes of magmatism in the source region for the protolith sediment, at ~2.53 and ~2.65 Ga, were identified from the zircon cores. Successive zircon growth at ~1.00 Ga and ~530 Ma records a sequence of distinct, widely spaced high-temperature metamorphic and/or anatectic events related to Grenvillian and Pan-African orogenesis. This study presents the first robust geochronological evidence for the timing of UHT metamorphism of the Rauer Group, supporting arguments that the peak UHT metamorphic event occurred at ~1.00 Ga and was overprinted by a separate high-grade event at ~530 Ma. The new age data indicate that the UHT granulites of the Rauer Group experienced a complex, multi-stage tectonothermal history, which cannot simply be explained via a single Pan-African (~500 Ma) high-grade tectonic event. This is critical in understanding the role of the eastern Prydz Bay region during the assembly of the east Gondwana supercontinent, and the newly recognized inherited Archaean ages (~2.53 and ~2.65 Ga) suggest a close tectonic relationship between the Rauer Group and the adjacent Archaean of the Vestfold Hills

  19. Sequence stratigraphy, geodynamics, and detrital geothermochronology of Cretaceous foreland basin deposits, western interior U.S.A

    NASA Astrophysics Data System (ADS)

    Painter, Clayton S.

    Three studies on Cordilleran foreland basin deposits in the western U.S.A. constitute this dissertation. These studies differ in scale, time and discipline. The first two studies include basin analysis, flexural modeling and detailed stratigraphic analysis of Upper Cretaceous depocenters and strata in the western U.S.A. The third study consists of detrital zircon U-Pb analysis (DZ U-Pb) and thermochronology, both zircon (U-Th)/He and apatite fission track (AFT), of Upper Jurassic to Upper Cretaceous foreland-basin conglomerates and sandstones. Five electronic supplementary files are a part of this dissertation and are available online; these include 3 raw data files (Appendix_A_raw_isopach_data.txt, Appendix_C_DZ_Data.xls, Appendix_C_U-Pb_apatite.xls), 1 oversized stratigraphic cross section (Appendix_B_figure_5.pdf), and 1 figure containing apatite U-Pb concordia plots (Appendix_C_Concordia.pdf). Appendix A is a combination of detailed isopach maps of the Upper Cretaceous Western Interior, flexural modeling and a comparison to dynamic subsidence models as applied to the region. Using these new isopach maps and modeling, I place the previously recognized but poorly constrained shift from flexural to non-flexural subsidence at 81 Ma. Appendix B is a detailed stratigraphic study of the Upper Cretaceous, (Campanian, ~76 Ma) Sego Sandstone Member of the Mesaverde Group in northwestern Colorado, an area where little research has been done on this formation. Appendix C is a geo-thermochronologic study to measure the lag time of Upper Jurassic to Upper Cretaceous conglomerates and sandstones in the Cordilleran foreland basin. The maximum depositional ages using DZ U-Pb match existing biostratigraphic age controls. AFT is an effective thermochronometer for Lower to Upper Cretaceous foreland stratigraphy and indicates that source material was exhumed from >4--5 km depth in the Cordilleran orogenic belt between 118 and 66 Ma, and zircon (U-Th)/He suggests that it was exhumed

  20. Archean Arctic continental crust fingerprints revealing by zircons from Alpha Ridge bottom rocks

    NASA Astrophysics Data System (ADS)

    Sergeev, Sergey; Petrov, Oleg; Morozov, Andrey; Shevchenko, Sergey; Presnyakov, Sergey; Antonov, Anton; Belyatsky, Boris

    2015-04-01

    Whereas thick Cenozoic sedimentary cover overlapping bedrock of the Arctic Ocean, some tectonic windows were sampled by scientific submarine manipulator, as well as by grabbing, dredging and drilling during «Arctic-2012» Russian High-Arctic expedition (21 thousands samples in total, from 400-km profile along Alpha-Mendeleev Ridges). Among others, on the western slope of Alpha Ridge one 10x10 cm fragment without any tracks of glacial transportation of fine-layered migmatitic-gneiss with prominent quartz veinlets was studied. Its mineral (47.5 vol.% plagioclase + 29.6% quartz + 16.6% biotite + 6.1% orthoclase) and chemical composition (SiO2:68.2, Al2O3:14.9, Fe2O3:4.44, TiO2:0.54, MgO:2.03, CaO:3.13, Na2O:3.23, K2O:2.16%) corresponds to trachydacite vulcanite, deformed and metamorphozed under amphibolite facies. Most zircon grains (>80%) from this sample has an concordant U-Pb age 3450 Ma with Th/U 0.8-1.4 and U content of 100-400 ppm, epsilon Hf from -4 up to 0, and ca 20% - ca 3.3 Ga with Th/U 0.7-1.4 and 90-190 ppm U, epsilon Hf -6.5 to -4.5, while only 2% of the grains show Proterozoic age of ca 1.9 Ga (Th/U: 0.02-0.07, U~500 ppm, epsilon Hf about 0). No younger zircons were revealed at all. We suppose that magmatic zircon crystallized as early as 3450 Ma ago during acid volcanism, the second phase zircon crystallization from partial melt (or by volcanics remelting) under amphibolite facies metamorphism was at 3.3 Ga ago with formation of migmatitie gneisses. Last zircon formation from crustal fluids under low-grade metamorphic conditions was 1.9 Ga ago. There are two principal possibilities for the provenance of this metavolcanic rock. The first one - this is ice-rafted debris deposited by melted glacial iceberg. However, presently there are no temporal and compositional analogues of such rocks in basement geology of peri-oceanic regions, including Archean Itsaq Gneiss Complex, Lewisian Complex and Baltic Shield but these regions are far from the places of

  1. Exploring for early bombardments on Earth from pre-3.85 Fa thermal effects recorded in Hadean zircons - a status report

    NASA Astrophysics Data System (ADS)

    Mojzsis, S. J.; Abramov, O.; Harrison, T. M.; Kring, D. A.; Levison, H. F.; Trail, D.; Watson, E. B.

    2008-12-01

    We report on our progress with high-resolution ion microprobe U-Th-Pb depth profiles and Ti+REEs spot analysis which show that subsequent to their crystallization in melts under typical crustal conditions on Earth, some Hadean (pre-3.85 Ga) zircons record common age domains with unusual chemical and isotopic characteristics consistent with a high-temperature (possibly impact) origin. We have found evidence for later overprints caused by intense thermal alteration between 3.94-3.97 Ga in six of eight studied grains but no evidence for older events. These findings alert us to two fundamental things we did not know before about the probiotic potential of the Earth in the earliest solar system: (i) that the bombardment epoch did not result in complete 'Doomsday' scale destruction of the Earth's crust since the Moon-forming event at ca. 4.5 Ga; and (ii) age constraints on both sides of the ther-mally altered 3.94-3.97 Ga zircon domains are very good and so far our data show that no detectable thermal events are recorded by the zircons before ~3.97 Ga up to about 4.3 Ga. This observation is consistent with the output of new classes of dynamical models that successfully re-create the decay of impactor populations in the early solar system as recorded on the Moon and in meteorites.

  2. Sandstone provenance and U-Pb ages of detrital zircons from Permian-Triassic forearc sediments within the Sukhothai Arc, northern Thailand: Record of volcanic-arc evolution in response to Paleo-Tethys subduction

    NASA Astrophysics Data System (ADS)

    Hara, Hidetoshi; Kunii, Miyuki; Miyake, Yoshihiro; Hisada, Ken-ichiro; Kamata, Yoshihito; Ueno, Katsumi; Kon, Yoshiaki; Kurihara, Toshiyuki; Ueda, Hayato; Assavapatchara, San; Treerotchananon, Anuwat; Charoentitirat, Thasinee; Charusiri, Punya

    2017-09-01

    Provenance analysis and U-Pb dating of detrital zircons in Permian-Triassic forearc sediments from the Sukhothai Arc in northern Thailand clarify the evolution of a missing arc system associated with Paleo-Tethys subduction. The turbidite-dominant formations within the forearc sediments include the Permian Ngao Group (Kiu Lom, Pha Huat, and Huai Thak formations), the Early to earliest Late Triassic Lampang Group (Phra That and Hong Hoi formations), and the Late Triassic Song Group (Pha Daeng and Wang Chin formations). The sandstones are quartzose in the Pha Huat, Huai Thak, and Wang Chin formations, and lithic wacke in the Kiu Lom, Phra That, Hong Hoi and Pha Daeng formations. The quartzose sandstones contain abundant quartz, felsic volcanic and plutonic fragments, whereas the lithic sandstones contain mainly basaltic to felsic volcanic fragments. The youngest single-grain (YSG) zircon U-Pb age generally approximates the depositional age in the study area, but in the case of the limestone-dominant Pha Huat Formation the YSG age is clearly older. On the other hand, the youngest cluster U-Pb age (YC1σ) represents the peak of igneous activity in the source area. Geological evidence, geochemical signatures, and the YC1σ ages of the sandstones have allowed us to reconstruct the Sukhothai arc evolution. The initial Sukhothai Arc (Late Carboniferous-Early Permian) developed as a continental island arc. Subsequently, there was general magmatic quiescence with minor I-type granitic activity during the Middle to early Late Permian. In the latest Permian to early Late Triassic, the Sukhothai Arc developed in tandem with Early to Middle Triassic I-type granitic activity, Middle to Late Triassic volcanism, evolution of an accretionary complex, and an abundant supply of sediments from the volcanic rocks to the trench through a forearc basin. Subsequently, the Sukhothai Arc became quiescent as the Paleo-Tethys closed after the Late Triassic. In addition, parts of sediments of

  3. Tracing the depositional history of Kalimantan diamonds by zircon provenance and diamond morphology studies

    NASA Astrophysics Data System (ADS)

    Kueter, Nico; Soesilo, Joko; Fedortchouk, Yana; Nestola, Fabrizio; Belluco, Lorenzo; Troch, Juliana; Wälle, Markus; Guillong, Marcel; Von Quadt, Albrecht; Driesner, Thomas

    2016-11-01

    Diamonds in alluvial deposits in Southeast Asia are not accompanied by indicator minerals suggesting primary kimberlite or lamproite sources. The Meratus Mountains in Southeast Borneo (Province Kalimantan Selatan, Indonesia) provide the largest known deposit of these so-called "headless" diamond deposits. Proposals for the origin of Kalimantan diamonds include the adjacent Meratus ophiolite complex, ultra-high pressure (UHP) metamorphic terranes, obducted subcontinental lithospheric mantle and undiscovered kimberlite-type sources. Here we report results from detailed sediment provenance analysis of diamond-bearing Quaternary river channel material and from representative outcrops of the oldest known formations within the Alino Group, including the diamond-bearing Campanian-Maastrichtian Manunggul Formation. Optical examination of surfaces of diamonds collected from artisanal miners in the Meratus area (247 stones) and in West Borneo (Sanggau Area, Province Kalimantan Barat; 85 stones) points toward a classical kimberlite-type source for the majority of these diamonds. Some of the diamonds host mineral inclusions suitable for deep single-crystal X-ray diffraction investigation. We determined the depth of formation of two olivines, one coesite and one peridotitic garnet inclusion. Pressure of formation estimates for the peridotitic garnet at independently derived temperatures of 930-1250 °C are between 4.8 and 6.0 GPa. Sediment provenance analysis includes petrography coupled to analyses of detrital garnet and glaucophane. The compositions of these key minerals do not indicate kimberlite-derived material. By analyzing almost 1400 zircons for trace element concentrations with laser ablation ICP-MS (LA-ICP-MS) we tested the mineral's potential as an alternative kimberlite indicator. The screening ultimately resulted in a small subset of ten zircons with a kimberlitic affinity. Subsequent U-Pb dating resulting in Cretaceous ages plus a detailed chemical reflection make

  4. Archaean zircons in Miocene oceanic hotspot rocks establish ancient continental crust beneath Mauritius

    PubMed Central

    Ashwal, Lewis D.; Wiedenbeck, Michael; Torsvik, Trond H.

    2017-01-01

    A fragment of continental crust has been postulated to underlie the young plume-related lavas of the Indian Ocean island of Mauritius based on the recovery of Proterozoic zircons from basaltic beach sands. Here we document the first U–Pb zircon ages recovered directly from 5.7 Ma Mauritian trachytic rocks. We identified concordant Archaean xenocrystic zircons ranging in age between 2.5 and 3.0 Ga within a trachyte plug that crosscuts Older Series plume-related basalts of Mauritius. Our results demonstrate the existence of ancient continental crust beneath Mauritius; based on the entire spectrum of U–Pb ages for old Mauritian zircons, we demonstrate that this ancient crust is of central-east Madagascar affinity, which is presently located ∼700 km west of Mauritius. This makes possible a detailed reconstruction of Mauritius and other Mauritian continental fragments, which once formed part of the ancient nucleus of Madagascar and southern India. PMID:28140395

  5. Implications for late Grenvillian (Rigolet phase) construction of Rodinia using new U-Pb data from the Mars Hill terrane, Tennessee and North Carolina, United States

    USGS Publications Warehouse

    Aleinikoff, John N.; Southworth, Scott; Merschat, Arthur J.

    2013-01-01

    New data for zircon (external morphology, cathodoluminescence zoning, and sensitive high resolution ion microprobe [SHRIMP] U-Pb ages) from the Carvers Gap granulite gneiss of the Mars Hill terrane (Tennessee and North Carolina, United States) require reevaluation of interpretations of the age and origin of this rock. The new results indicate that the zircon is detrital and that the sedimentary protolith of this gneiss (and related Cloudland gneiss) was deposited no earlier than ca. 1.02 Ga and was metamorphosed at ca. 0.98 Ga. Tectonic models that included the gneiss as a piece of 1.8 Ga Amazonian crust (perhaps as part of the hypothetical Columbia supercontinent) are now untenable. The remarkably fast cycle of exhumation, erosion, deposition, and deep burial also is characteristic of other late Grenvillian (post-Ottawan) Mesoproterozoic paragneisses that occur throughout the Appalachians. These rocks provide new evidence for the duration of the formation of the Rodinia supercontinent lasting until at least 0.98 Ma.

  6. New zircon ages on the Cambrian-Ordovician volcanism of the Southern Gemericum basement (Western Carpathians, Slovakia): SHRIMP dating, geochemistry and provenance

    NASA Astrophysics Data System (ADS)

    Vozárová, Anna; Rodionov, Nickolay; Šarinová, Katarína; Presnyakov, Sergey

    2017-09-01

    The Southern Gemericum basement in the Inner Western Carpathians, composed of low-grade volcano-sedimentary rock complexes, constitutes a record of the polyphase Cambrian-Ordovician continental volcanic arc volcanism. These metavolcanic rocks are characterized by the enrichment in K, Rb, Ba, Th and Ce and Sm relative to Ta, Nb, Hf, Zr, Y and Yb that are the characteristic features for volcanic arc magmatites. The new SHRIMP U-Pb zircon data and compilation of previously published and re-evaluated zircon ages, contribute to a new constrain of the timing of the Cambrian-Ordovician volcanism that occurred between 496 and 447 Ma. The following peaks of the volcanic activity of the Southern Gemericum basement have been recognized: (a) mid-late Furongian at 492 Ma; (b) Tremadocian at 481 Ma; (c) Darriwilian at 464 Ma prolonged to 453 Ma within the early Upper Ordovician. The metavolcanic rocks are characterized by a high zircon inheritance, composed of Ediacaran (650-550 Ma), Tonian-Stenian (1.1-0.9 Ma), and, to a lesser extent, Mesoproterozoic (1.3 Ga), Paleoproterozoic (1.9 Ga) and Archaean assemblages (2.6 Ga). Based on the acquired zircon populations, it could be deduced that Cambrian-Ordovician arc crust was generated by a partial melting of Ediacaran basement in the subduction-related setting, into which old crustal fragments were incorporated. The ascertained zircon inheritances with Meso-, Paleoproterozoic and Archaean cores indicate the similarities with the Saharan Metacraton provenance.

  7. Timing of crust formation and recycling in accretionary orogens: Insights learned from the western margin of South America

    NASA Astrophysics Data System (ADS)

    Bahlburg, Heinrich; Vervoort, Jeffrey D.; Du Frane, S. Andrew; Bock, Barbara; Augustsson, Carita; Reimann, Cornelia

    2009-12-01

    Accretionary orogens are considered major sites of formation of juvenile continental crust. In the central and southern Andes this is contradicted by two observations: siliciclastic fills of Paleozoic basins in the central Andean segment of the accretionary Terra Australis Orogen consist almost exclusively of shales and mature sandstones; and magmatic rocks connected to the Famatinian (Ordovician) and Late Paleozoic magmatic arcs are predominantly felsic and characterized by significant crustal contamination and strongly unradiogenic Nd isotope compositions. Evidence of juvenile crustal additions is scarce. We present laser ablation (LA)-ICPMS U-Pb ages and LA-MC-ICPMS Hf isotope data of detrital zircons from seven Devonian to Permian turbidite sandstones incorporated into a Late Paleozoic accretionary wedge at the western margin of Gondwana in northern Chile. The combination with Nd whole-rock isotope data permits us to trace the evolution of the South American continental crust through several Proterozoic and Paleozoic orogenic cycles. The analyzed detrital zircon spectra reflect all Proterozoic orogenic cycles representing the step-wise evolution of the accretionary SW Amazonia Orogenic System between 2.0 and 0.9 Ga, followed by the Terra Australis Orogen between 0.9 and 0.25 Ga. The zircon populations are characterized by two prominent maxima reflecting input from Sunsas (Grenville) age magmatic rocks (1.2-0.9 Ga) and from the Ordovician to Silurian Famatinian magmatic arc (0.52-0.42 Ga). Grains of Devonian age are scarce or absent from the analyzed zircon populations. The Hf isotopic compositions of selected dated zircons at the time of their crystallization ( ɛHf ( T) ; T = 3.3-0.25 Ga) vary between - 18 and + 11. All sandstones have a significant juvenile component; between 20 and 50% of the zircons from each sedimentary rock have positive ɛHf ( T) and can be considered juvenile. The majority of the juvenile grains have Hf-depleted mantle model ages (Hf

  8. Identification of Detrital Carbonate in East Cepu High

    NASA Astrophysics Data System (ADS)

    Sari, R.; Andika, I. K.; Haris, A.; Miftah, A.

    2018-03-01

    East Cepu High is a part of horst – graben series which formed by extensional tectonic processes during Paleogene in North East Java Basin. Due to excellent paleogeography position, the carbonate build-up was growth very well and as the main reservoir in East Cepu High. Sea level change have important factor to provide variation of facies in each carbonate buildup, one of emerging facies is detrital carbonate. Detrital carbonate indicated by onlap horizon featured with carbonate build up body. Based on paleogeography, fluctuation of sea level change and sediment source, detrital carbonate formed in leeward area in lowstand or highstand phases. Distinguish between detrital carbonate facies with other facies, advanced seismic processing performed by using continuous wavelet transform (CWT) and seismic inversion. CWT is one method of spectral decomposition used to find the frequency that represent a facies. The result from seismic inversion will support the interpretation for facies distribution. As the result, seismic data which have interval frequency 10 – 45 Hz and Acoustic Impedance (AI) value above 35000 (from cross plot between acoustic impedance and gamma ray) can be interpreted as detrital carbonate. Based on seismic interpretation, detrital carbonate facies distributed along leeward area with geometrical spreading. The lateral facies change from detrital carbonate to shale was identified which causing this facies become potential as hydrocarbon reservoir with stratigraphic trap. Based on the earlier studies, North East Java Basin have a strong hydrocarbon migration to fill the reservoir, therefore the detrital carbonate have high chance to be a new hydrocarbon prospect in this area.

  9. First application of the revised Ti-in-zircon geothermometer to Paleoproterozoic ultrahigh-temperature granulites of Tuguiwula, Inner Mongolia, North China Craton

    NASA Astrophysics Data System (ADS)

    Liu, S. J.; Li, J. H.; Santosh, M.

    2010-02-01

    The revised titanium-in-zircon geothermometer was applied to Paleoproterozoic ultrahigh-temperature (UHT) granulites at Tuguiwula, Inner Mongolia, North China Craton. The Tuguiwula granulites contain diagnostic UHT mineral assemblages such as sapphirine + quartz and high alumina orthopyroxene + sillimanite + quartz, suggesting formation under temperatures of ca. 1,000°C and pressures of up to 10 kbar. Here, we report detailed petrographic studies and ICP-MS data on titanium concentration in zircons associated with the UHT assemblages. The zircons associated with sapphirine-spinel-sillimanite-magnetite assemblages have the highest Ti concentration of up to 57 ppm, yielding a temperature of 941°C, and suggesting that the growth of zircons occurred under ultrahigh-temperature conditions. The maximum temperatures obtained by the revised Ti-in-zircon geothermometer is lower than the equilibrium temperature of sapphirine + quartz, indicating an interval of cooling history of the granulites from UHT condition to ca. 940°C. Many of the zircons have Ti concentrations ranging from 10 to 33 ppm, indicating their growth or recrystallization under lower temperatures of ca. 745-870°C. These zircons are interpreted to have recrystallized during the retrograde stage indicated by microstructures such as cordierite rim or corona between spinel and quartz, and orthopyroxene-cordierite symplectite around garnet. Previous geochronological study on the zircons of the Tuguiwula UHT granulites gave a mean U-Pb SHRIMP age of 1.92 Ga. However, based on the Ti-in-zircon geothermometer results reported in this work, and considering the relatively slow thermal relaxation of these rocks, we infer that the timing of peak UHT metamorphism in the Tuguiwula area could be slightly older than 1.92 Ga.

  10. The 190Pt-186Os Decay System Applied to Dating Platinum-Group Element Mineralization in Layered Intrusions, Ophiolites and Detrital Deposits

    NASA Astrophysics Data System (ADS)

    Coggon, J. A.; Nowell, G.; Pearson, G.; Oberthür, T.; Lorand, J.; Melcher, F.; Parman, S. W.

    2010-12-01

    Discrete platinum-group minerals (PGM) occur as accessory phases in mafic-ultamafic intrusions and ophiolitic chromitites, as well as numerous detrital deposits globally. The 190Pt-186Os decay system, measured by laser ablation MC-ICPMS (LA-MC-ICPMS) provides a useful geochronometric tool for direct dating of PGM. Here we present two examples that verify the accuracy of the technique in geologically well constrained situations and demonstrate the potential for using the 190Pt-186Os PGM method to accurately date layered mafic intrusions, ophiolitic chromitites and detrital PGM deposits. Fifty PGM grains from three different horizons within the Bushveld complex yield a Pt-Os isochron age of 2012 ± 47 Ma (2σ, MSWD = 1.19, 186Os/188Osi = 0.119818 ± 0.000006). This is consistent with the published U-Pb zircon age of 2054 Ma (Scoates and Friedman, 2008). The younger PGM isochron age is not likely to be a function of difference in blocking temperatures in the different systems. Pt-Os model ages are possible in high pt grains because initial 186Os/188Os can be well constrained. Using this approach we obtained Pt-Os model ages of 2113 ± 106 Ma and 2042 ± 102 Ma for a Bushveld Pt-Fe alloy and sperrylite respectively. Detrital PGM derived from the Meratus ophiolite, southeast Borneo yield a 190Pt-186Os isochron age of 202.5 Ma ± 8.3 Ma (2σ, n = 260, MSWD = 0.90, 186Os/188Osi = 0.119830 ± 0.000003), consistent with radiometric and biostratigraphic age constraints (Wakita et al., 1998). We interpret this as the age of formation of the PGM grains in during chromitite genesis in the lower oceanic lithosphere. Our combined data demonstrate the utility of the LA-MC-ICPMS method as a tool for accurate Pt-Os dating of detrital PGM as well as their igneous parent bodies. We can constrain Pt/Os fractionation at the ablation site as being < 2.5%, while within-grain heterogeneity is ultimately one of the strongest controls on isochron and single-grain ages given the partial

  11. Separation of the Guajira-Bonaire pair in the southern margin of the Caribbean: 65-50 Ma exhumation followed by 300 km right-lateral transtensional deformation

    NASA Astrophysics Data System (ADS)

    Zapata Henao, S.; Cardona, A.; Montes, C.; Valencia, V.; Vervoort, J. D.; Reiners, P. W.

    2012-12-01

    Middle to upper Eocene fluvial strata in the island of Bonaire contains detrital components that were tracked to the basement massifs of the Guajira Peninsula in northern Colombia. These detrital components confirm previous hypothesis that the Guajira-Bonaire pair constitute a tectonic piercing point along the southern Caribbean plate margin that was right-laterally displaced approximately 300 km after middle Eocene times. Other possible sources, the nearby Curacao and the far away Santa Marta massif, did not pass statistical similarity and overlap tests. U-Pb LA-ICP-MS from the metamorphic boulders of the Soebi Blanco Formation in Bonaire yield Grenvillian ages (1084 Ma, 1130 Ma and 1184 Ma), while the detrital zircons recovered from the sandy matrix of the conglomerates contains populations with peaks of 1000 Ma - 1200 Ma, 750 Ma - 950 Ma, and 200 Ma - 300 Ma. Overlap and Similarity tests run between these populations and published data from Guajira yield values of 0.750 and 0.680, which are significantly higher than the same comparison against the Santa Marta Massif (0.637 and 0.522), and the Curacao island (0.629 and 0.467). Thermochronological results from the metamorphic clasts yield Paleocene-middle Eocene ages (65 - 50 Ma) that confirm not only a regional-scale cooling event in this time period, but also help constrain the maximum depositional age (50 Ma) of the poorly dated Soebi Blanco Formation. Figure 6. U-Pb results from analyzed samples and other Caribbean provinces. (A), Detrital zircons from Soebi Blanco conglomerate matrix; (B), Zircon ages from metamorphic clasts (C), detrital zircons from late Cretaceous Etpana Formation in Guajira Peninsula (Weber et al., 2010); (D), detrital zircons from late Cretaceous Santa Marta San Lorenzo schists (Cardona et al., 2010a); (E), detrital zircons from late Cretaceous Knip Group (Wrigth and Wyld, 2010); (F), overlap and similarity values.

  12. The Hadean to Paleoarchean geodynamo: microconglomerate tests from siliciclastic metasedimentary rocks from the Southern Cross Terrane of Western Australia

    NASA Astrophysics Data System (ADS)

    Cottrell, R. D.; Tarduno, J. A.; Bono, R. K.; Thern, E. R.; Chhibber, S. K.

    2016-12-01

    Detrital zircons found within metasedimentary rocks of the Yilgarn Craton (Western Austrlia) contain information about the early history of the geodynamo. Recently reported single crystal paleointensity (SCP) values obtained from zircon grains of the Jack Hills (JH) belt (Tarduno et al., 2015) suggest the presence of a core dynamo to times as old as 4.2 Ga. Magnetizations carried by zircons within these rocks have been preserved despite multiple reheating events of the host metasedimentary unit. Two positive conglomerate tests (Tarduno and Cottrell, 2013; Tarduno et al., 2015) as well as interlaboratory studies reproducing a prior positive conglomerate test (Dare et al., 2015; 2016) attest to the primary nature of the remanence carried by these zircons. Moreover, new Li data limit heating after zircon formation to < 500 oC. Similarly, the metasedimentary rocks of the Southern Cross Terrane, more than 400 kilometers away from the Discovery Site of the Jack Hills, contain detrital Eoarchean to Hadean age zircons (Nelson, 2005; Wyche, 2007). Following Tarduno et al. (2015), a micro-conglomerate test of oriented, small ( 500-700 mm) samples centered on single zircons ( 200-350 mm) was performed using the University of Rochester's ultra-high resolution 3-component DC SQUID magnetometer that affords an order of magnitude greater sensitivity than other high-resolution SQUID rock magnetometers. The characteristic remanences from oriented zircons (N=10; R=0.81) that unblock between 565 and 580 °C, consistent with a magnetite carrier, are well defined but together cannot be distinguished from those drawn from a random distribution (Ro=5.03) at the 95% confidence level; this indicates a positive microconglomerate test. Preliminary paleointensity determinations range between 4-27 μT. Additional studies of hand samples from the Southern Cross Terrane are underway.

  13. Origin and tectonic evolution of early Paleozoic arc terranes abutting the northern margin of North China Craton

    NASA Astrophysics Data System (ADS)

    Zhou, Hao; Pei, Fu-Ping; Zhang, Ying; Zhou, Zhong-Biao; Xu, Wen-Liang; Wang, Zhi-Wei; Cao, Hua-Hua; Yang, Chuan

    2017-12-01

    The origin and tectonic evolution of the early Paleozoic arc terranes abutting the northern margin of the North China Craton (NCC) are widely debated. This paper presents detrital zircon U-Pb and Hf isotopic data of early Paleozoic strata in the Zhangjiatun arc terrane of central Jilin Province, northeast (NE) China, and compares them with the Bainaimiao and Jiangyu arc terranes abutting the northern margin of the NCC. Detrital zircons from early Paleozoic strata in three arc terranes exhibit comparable age groupings of 539-430, 1250-577, and 2800-1600 Ma. The Paleoproterozoic to Neoarchean ages and Hf isotopic composition of the detrital zircons imply the existence of the Precambrian fragments beneath the arc terranes. Given the evidences from geology, igneous rocks, and detrital zircons, we proposed that the early Paleozoic arc terranes abutting the northern margin of the NCC are a united arc terrane including the exotic Precambrian fragments, and these fragments shared a common evolutionary history from Neoproterozoic to early-middle Paleozoic.

  14. Lu-Hf systematics of magmatic zircons reveal a Proterozoic crustal boundary under the Cretaceous Pioneer batholith, Montana

    NASA Astrophysics Data System (ADS)

    Foster, David A.; Mueller, Paul A.; Heatherington, Ann; Gifford, Jennifer N.; Kalakay, Thomas J.

    2012-06-01

    Lu-Hf systematics of magmatic zircons from quartz diorite and granodiorite plutons of the Late Cretaceous Pioneer batholith, Montana, indicate involvement of distinctly different crustal sources in the petrogensis of individual components of the batholith. Plutons of the eastern Pioneer batholith contain magmatic zircons with initial ɛHf values of - 28 to - 34 that crystallized in magmas likely derived from dominantly Archean and earliest Paleoproterozoic crust. Contemporaneous granodiorite in the western Pioneer batholith contains magmatic zircons with initial ɛHf values ranging from - 9 to - 33, but dominated by values between - 18 and - 22, which suggest a mixture of Paleoproterozoic and possible Mesoproterozoic sources. These data suggest that distinct segments of crust juxtaposed and produced during formation of the Great Falls tectonic zone (1.78-1.86 Ga) and the Belt basin (~ 1.43-1.47 Ga) contributed to magmatic compositions in the batholith and that these contributions are recorded in the magmatic zircons. The contrasting ɛHf distributions between eastern and western components of the Pioneer batholith suggest that an important crustal and/or lithospheric boundary underlies the Pioneer batholith. The Hf-isotopic results also suggest that the high P-wave velocity lower crust of the northern Rocky Mountains did not form in a single event.

  15. Thermal events documented in Hadean zircons by ion microprobe depth profiles

    NASA Astrophysics Data System (ADS)

    Trail, Dustin; Mojzsis, Stephen J.; Harrison, T. Mark

    2007-08-01

    We report the first U-Th-Pb ion microprobe depth profiles of four Hadean zircons from the Jack Hills and Mount Narryer supracrustal belts of the Narryer Gneiss Complex (NGC), Western Australia. This ultra-high spatial resolution technique probes the age and origin of sub-micron features in individual crystals that can record episodes of zircon growth. Near-surface grain dates of 2700 Ma or older are coincident with post-depositional growth/modification. Some ages may coincide with documented pre-deposition metamorphic events for the NGC and igneous emplacement at ca. 3700 Ma. Separate events that do not correlate in time with known geologic episodes prior to the preserved rock record are also present on pre-4000 Ma zircons. We find evidence for a ˜3.9 Ga event, which is coterminous within age uncertainty with one or several large basin-forming impacts (e.g. Nectaris) on the Moon attributed to the late heavy bombardment of the inner solar system.

  16. Discriminating Sediment Supply versus Accommodation Controls on Late Cretaceous Foreland Basin Stratigraphic Architecture in the Book Cliffs, Utah using Detrital Zircon Double Dating

    NASA Astrophysics Data System (ADS)

    Bartschi, N.; Saylor, J. E.

    2016-12-01

    Middle to late Campanian strata of the Book Cliffs, Utah record the Late Cretaceous deposition of three clastic wedges in the North American Cordilleran foreland basin east of the Sevier thrust-belt. Variations in wedge geometries provide an opportunity to evaluate the effects of sediment supply versus accommodation on foreland basin stratal architecture. There is a significant increase in eastward progradation rate from the Lower to the Upper Castlegate Sandstone. However, the progradation rate decreases in the overlying Bluecastle and Price River formations, as well as the laterally equivalent Farrer and Tuscher formations. Rapid progradation during Upper Castlegate deposition may be caused by increased sediment supply from either rapid exhumation of the Sevier thrust-belt or introduction of a new sediment source. Alternatively, reduced accommodation within the proximal foreland basin from uplifts associated with Laramide deformation, or a transition from flexural to dynamic subsidence, could produce the observed rapid wedge progradation. Changes in sediment provenance and source-area exhumation rate can be identified using a combination of detrital zircon U-Pb geochronology and (U-Th)/He thermochronology. Quantitative comparisons between collected samples and published provenance data indicates an upsection increase in a new sediment source, revealing a significant overall shift in provenance between wedge boundaries. This change in provenance is coupled by an upsection decrease in lag time between the Lower and Upper Castlegate, consistent with an increase in exhumation rate. Conversely, there is no change in lag time between the Upper Castlegate and overlying Price River Formation, suggesting a relatively constant exhumation rate. Near-zero lag times during the Upper Castlegate is consistent with rapid exhumation associated with increased thrusting of the Sevier thrust-belt. Therefore, progradation of the Upper Castlegate can be attributed to an increase in

  17. SHRIMP-RG U-Pb ages of provenance and metamorphism from detrital zircon populations and Pb-Sr-Nd signatures of prebatholithic metasedimentary rocks at Searl Ridge, northern Peninsular Ranges batholith, southern California: Implications for their age, origin, and tectonic setting

    USGS Publications Warehouse

    Premo, Wayne R.; Morton, Douglas M.

    2014-01-01

    Twenty-four samples were collected from prebatholithic metasedimentary rocks along Searl Ridge, the north rim of the Diamond Valley Reservoir, Domenigoni Valley, centrally located in the northern Peninsular Ranges of southern California. These rocks exhibit progressive metamorphism from west to east across fundamental structural discontinuities now referred to as a “transition zone.” Documented structural and mineralogical changes occur across this metamorphic gradient. Sensitive high-resolution ion microprobe–reverse geometry (SHRIMP-RG) U-Pb ages were obtained from detrital zircons from metasedimentary rocks through the transition zone. To the west, metapelitic and minor metasandstone units yielded numerous concordant 206Pb/238U ages between 210 and 240 Ma, and concordant 207Pb/206Pb ages at 1075–1125 Ma, 1375–1430 Ma, and 1615–1735 Ma, although distinct differences in provenance were noted between units. A few older 207Pb/206Pb ages obtained were ca. 2250 Ma and ca. 2800 Ma. Rocks of the eastern part of the transition zone include high-grade paragneisses that yielded numerous concordant 206Pb/238U ages between 103 and 123 Ma and between 200 and 255 Ma, and concordant 207Pb/206Pb ages at 1060–1150 Ma, 1375–1435 Ma, and 1595–1710 Ma. Some zircon results from these high-grade gneisses are marked by distinct Pb-loss discordia with lower-intercept ages of ca. 215 Ma and Paleoproterozoic upper-intercept ages. Younger ages between 100 and 105 Ma are mainly obtained from rims of some zircon grains that are characterized by low Th/U values (<0.1) and high U contents (>1000 ppm), indicating the likelihood of metamorphic zircon growth at that time. The similarity of zircon age populations between western and eastern units through the transition zone indicates that this fundamental structure probably dissects sediments of the same basin. This supposition is further supported by initial whole-rock Pb-Sr-Nd isotopic data that show similar average

  18. Melting depths associated with Jack Hills zircons crystallization as revealed by in situ trace element measurements

    NASA Astrophysics Data System (ADS)

    Profeta, L.; Ducea, M. N.; Gehrels, G. E.

    2016-12-01

    The Jack Hills zircons hosted within the Narryer Gneiss Complex, Yilgarn craton have ages from 4.4 Ga up to Mesoarchean. These zircons crystallized from low temperature granitoid magmas (Harrison, 2009). Here, we use trace element measurements obtained simultaneously with U-Pb ages using LA-ICP-MS on 276 Jack Hills zircons in order to estimate the depth of melting. La/Yb are converted to whole rock equivalent values using newly determined REE -whole rock partition coefficients (Chapman et al., 2016). La/Yb are subsequently transformed into depth estimates using the correlation between whole rock La/Yb and crustal thickness put forward in Profeta et al. (2015) for modern arcs. Our data pertains to 4.2 to 3.2 Ga zircons, which are supplemented with previously published data on 4.4.-4.3 Ga zircons (Peck et al. 2001). Depth estimates are averaged over 100 Ma bins, revealing a remarkably constant trend throughout the investigated period with values around 50 ± 10 km. We interpret that these depths may not be the result of a thick continental crust, as is the case for modern arcs, but rather the existence of different melting conditions during the Hadean and Paleoarchean due to elevated thermal regimes within the mantle. The high La/Yb whole rock ratios (with computed values greater than 10) coupled with elevated mantle temperatures point towards granitoid generation from partial melting of hydrated basalts (e.g. Martin et al., 2014). [1] Harrison, T.M., Annu. Rev. Earth Planet. Sci. 37, 479-505 (2009). [2] Chapman, J. B. et al., Chem. Geol. 439, 59-70 (2016). doi: 10.1016/j.chemgeo.2016.06.014. [3] Profeta, L. et al., Sci. Rep. 5, 17786 (2015). doi: 10.1038/srep17786 [4] Peck, W. et al., Cosmochim. Acta 65, 4215-4229 (2001). doi: 10.1016/S0016-7037(01)00711-6 [5] Martin, H. et al. Lithos 198, 1-13 (2014). doi: 10.1016/j.lithos.2014.02.017

  19. Ages of the Xinghuadukou Group in the Erguna Block, NE China

    NASA Astrophysics Data System (ADS)

    Liu, X.; Hou, W.

    2016-12-01

    The Xinghuadukou group is outcropped in the Erguna block (EB) of NE China, which is an important component of the eastern segment of the Central Asian Orogenic Belt (CAOB). This group was previously classified as Paleoproterozoic in age. However, recent studies reported Paleozoic ages from the meta-volcanic rocks, Paleoproterozoic to Neoarchean detrital zircon ages from the meta-sedimentary rocks and Neoproterozoic ages from the granitoids. The tectonic affinity of the EB is still debated. In order to clarify the aforementioned issues, 19 samples were collected from the Xinghuadukou group from the Mohe region in NE China. All samples underwent gneiss facies metamorphism, including two-mica granitic gneiss and quartz biotite gneiss. Based on the protolith discrimination diagram of Si—(al+fm)-(c+alk) system, 7 samples originated from sedimentary rocks and the other 12 of igneous origin. The orthogneiss samples were plotted as diorite, granodiorite and granite respectively in TAS, showing felsic character (SiO2 57% - 74%). One orthogneiss and one paragneiss samples were chosen to conduct the LA-ICP-MS U-Pb zircon age analysis. Apart from one zircon with the age of 742 Ma shows evident metamorphic rim, all zircons from the orthogneiss show euhedral to subhedral prismatic shape and typical concentric or oscillatory structure indicating the igneous origin. The concordant age of 2478±26 Ma was generated, indicating the existence of the near Archean basement of the EB. The detrital zircons from the paragneiss produced age populations cluster at 0.6, 0.8, 1.9, 2.6 and 2.7 Ga, lacking of the Grenville event age. The youngest zircon age is 395 Ma, taken as the maximum depositional age of the sedimentary protolith. According to the new data obtained, it is suggested that the Xinghuadukou group comprises the early Paleoproterozoic granite-gneiss, which proves the granitic basement of the Erguna block. The sedimentary rocks formed overlying the basement during the early

  20. The significance of the Medicine Hat Block (southern Alberta, northern Montana) in the assembly of Laurentia: New interpretations from recent single grain zircon geochronological and geochemical data

    NASA Astrophysics Data System (ADS)

    LaDouceur, B. O.; Gifford, J.; Malone, S.; Davis, B.

    2017-12-01

    Keywords: Medicine Hat Block, Zircon, U/Pb ages, Hf isotopes, Laurentia The Medicine Hat Block (MHB) is one of the core cratonic elements that amalgamated in the Paleoproterozoic to form Laurentia. However, unlike many of the other cratons, the role of the MHB in the formation of Laurentia is poorly constrained. Virtually all of the MHB is concealed by Proterozoic and younger supracrustal sequences, limiting the data collected from this craton. The primary source of samples from the MHB comes from two sources: 1) xenoliths of variably metamorphoses gneisses, amphibolites, and meta-plutonic rocks collected from Eocene volcanic rock, and 2) similar lithologies recovered from boreholes that penetrate to the MHB basement. Multigrain zircon TIMS analyses yielded U/Pb ages ranging from 1.70 Ga to 3.26 Ga. Recent zircon single-grain LA-ICPMS U-Pb ages revealed a slightly older range of Archean ages, 2.63 Ga to 3.27 Ga, and two samples yielding Paleoproterozoic ages at 1.78 and 1.82 Ga. Whole-rock Sm/Nd data indicated that the samples formed from crustal sources, with model ages ranging between 1.80 Ga to 3.48 Ga. In-situ zircon Hf isotopic results revealed that Archean-aged zircon are generally suprachondritic, with eHf(t) values between 8.3 and -8.7. In contrast, the Paleoproterozoic grains yielded negative eHf(t) values ranging from -6.8 to -21.2, suggestive of a reworked Archean crustal component in their genesis. In particular, the Sweetgrass Hill xenolith suite is characterized solely by Paleoproterozoic ages, with evolved eHf(t) suggesting that any older U-Pb ages were reset by granulite facies metamorphism and zircon recrystallization. The combined U-Pb and Hf isotopic data from these samples helps illuminate the character of the MHB and its relationships to the Wyoming and Hearne cratons, as well as the Great Falls Tectonic Zone (GFTZ). The ages overlap between cratonic elements; however, the abundance of positive eHf(t) values of the 2.8 Ga ages suggests that the

  1. Armorican provenance for the mélange deposits below the Lizard ophiolite (Cornwall, UK): evidence for Devonian obduction of Cadomian and Lower Palaeozoic crust onto the southern margin of Avalonia

    NASA Astrophysics Data System (ADS)

    Strachan, Rob A.; Linnemann, Ulf; Jeffries, Teresa; Drost, Kerstin; Ulrich, Jens

    2014-07-01

    Devonian sedimentary rocks of the Meneage Formation within the footwall of the Lizard ophiolite complex in SW England are thought to have been derived from erosion of the over-riding Armorican microplate during collision with Avalonia and the closure of the Rheic Ocean. We further test this hypothesis by comparison of their detrital zircon suites with those of autochthonous Armorican strata. Five samples analysed from SW England (Avalonia) and NW France (Armorica) have a bimodal U-Pb zircon age distribution dominated by late Neoproterozoic to middle Cambrian (c. 710-518 Ma) and Palaeoproterozoic (c. 1,800-2,200 Ma) groupings. Both can be linked with lithologies exposed within the Cadomian belt as well as the West African craton, which is characterized by major tectonothermal events at 2.0-2.4 Ga. The detrital zircon signature of Avalonia is distinct from that of Armorica in that there is a much larger proportion of Mesoproterozoic detritus. The common provenance of the samples is therefore consistent with: (a) derivation of the Meneage Formation mélange deposits from the Armorican plate during Rheic Ocean closure and obduction of the Lizard Complex and (b) previous correlation of quartzite blocks within the Meneage Formation with the Ordovician Grès Armoricain Formation of NW France.

  2. He diffusion in zircon: Observations from (U-Th)/He age suites and 4He diffusion experiments and implications for radiation damage and anisotropic effects

    NASA Astrophysics Data System (ADS)

    Guenthner, W. R.; Reiners, P. W.

    2009-12-01

    Despite widespread use of zircon (U-Th)/He thermochronometry in many geologic applications, our understanding of the kinetics of He diffusion in this system is rudimentary. Previous studies have shown that both radiation damage and crystallographic anisotropy may strongly influence diffusion kinetics and ages. We present observations of zircon He ages from multiple single-grain analyses from both detrital and bedrock suites from a wide variety of locations, showing relationships consistent with effects arising from the interaction of radiation damage and anisotropy. Individual zircons in each suite have experienced the same post-depositional or exhumational t-T history but grains appear to have experienced differential He loss that is correlated with effective uranium (eU) content, a proxy for the relative extent of radiation damage within each suite. Several suites of zircons heated to partial resetting upon burial or that have experienced slow cooling show positive correlations between age and eU. Examples of partially reset detrital samples include Cretaceous Sevier foreland basin sandstones buried to ~6-8 km depth, with ages ranging from 88-309 Ma across an eU range of 215-1453 ppm, and Apennines and Olympics greywackes heated to >~120 °C, showing similar trends. Some slowly-cooled bedrock samples also show positive age-eU correlations, suggesting increasing closure temperature with higher extents of radiation damage. Conversely, zircons from cratonal bedrock samples with high levels of radiation damage—measured as accumulated alpha dosage (in this case >~10^18 α/g)—generally show negative age-eU correlations. We interpret these contrasting age-eU relationships as a manifestation of the interaction of radiation damage and anisotropic diffusion: at low damage, He diffusivity is relatively high and preferentially through c-axis-parallel channels. As suggested by Farley (2007), however, with increasing damage, channels are progressively blocked and He

  3. Relict zircon U-Pb age and O isotope evidence for reworking of Neoproterozoic crustal rocks in the origin of Triassic S-type granites in South China

    NASA Astrophysics Data System (ADS)

    Gao, Peng; Zheng, Yong-Fei; Chen, Yi-Xiang; Zhao, Zi-Fu; Xia, Xiao-Ping

    2018-02-01

    Granites derived from partial melting of sedimentary rocks are generally characterized by high δ18O values and abundant relict zircons. Such relict zircons are valuable in tracing the source rocks of granites and the history of crustal anatexis. Here we report in-situ U-Pb ages, O isotopes and trace elements in zircons from Triassic granites in the Zhuguangshan and Jiuzhou regions, which are located in the Nanling Range and the Darongshan area, respectively, in South China. Zircon U-Pb dating yields magma crystallization ages of 236 ± 2 Ma for the Zhuguangshan granites and 246 ± 2 Ma to 252 ± 3 Ma for the Jiuzhou granites. The Triassic syn-magmatic zircons are characterized by high δ18O values of 10.1-11.9‰ in Zhuguangshan and 8.5-13.5‰ in Jiuzhou. The relict zircons show a wide range of U-Pb ages from 315 to 2185 Ma in Zhuguangshan and from 304 to 3121 Ma in Jiuzhou. Nevertheless, a dominant age peak of 700-1000 Ma is prominent in both occurrences, demonstrating that their source rocks were dominated by detrital sediments weathered from Neoproterozoic magmatic rocks. Taking previous results for regional granites together, Neoproterozoic relict zircons show δ18O values in a small range from 5 to 8‰ for the Nanling granites but a large range from 5 to 11‰ for the Darongshan granites. In addition, relict zircons of Paleozoic U-Pb age occur in the two granitic plutons. They exhibit consistently high δ18O values similar to the Triassic syn-magmatic zircons in the host granites. These Paleozoic relict zircons are interpreted as the peritectic product during transient melting of the metasedimentary rocks in response to the intracontinental orogenesis in South China. Therefore, the relict zircons of Neoproterozoic age are directly inherited from the source rocks of S-type granites, and those of Paleozoic age record the transient melting of metasedimentary rocks before intensive melting for granitic magmatism in the Triassic.

  4. Early to Middle Jurassic tectonic evolution of the Bogda Mountains, Northwest China: Evidence from sedimentology and detrital zircon geochronology

    NASA Astrophysics Data System (ADS)

    Ji, Hongjie; Tao, Huifei; Wang, Qi; Qiu, Zhen; Ma, Dongxu; Qiu, Junli; Liao, Peng

    2018-03-01

    The Bogda Mountains, as an important intracontinental orogenic belt, are situated in the southern part of the Central Asian Orogenic Belt (CAOB), and are a key area for understanding the Mesozoic evolution of the CAOB. However, the tectonic evolution of the Bogda Mountains remains controversial during the Mesozoic Era, especially the Early to Middle Jurassic Periods. The successive Lower to Middle Jurassic strata are well preserved and exposed along the northern flank of the Western Bogda Mountains and record the uplift processes of the Bogda Mountains. In this study, we analysed sedimentary facies combined with detrital zircon U-Pb geochronology at five sections of Lower to Middle Jurassic strata to detect the tectonic evolution and changes of provenance in the Bogda area. During Early to Middle Jurassic times, the fluvial, deltaic and lacustrine environments dominated in the western section of the Bogda area. The existence of Early Triassic peak age indicates that the Bogda Mountains did not experience uplift during the period of early Badaowan Formation deposition. The Early Triassic to Late Permian granitoid plutons and Carboniferous volcanic rocks from the Barkol and Santanghu areas were the main provenances. The significant change in the U-Pb age spectrum implies that the Eastern Bogda Mountains initiated uplift in the period of late Badaowan Formation deposition, and the Eastern Junggar Basin and the Turpan-Hami Basin were partially partitioned. The Eastern Bogda Mountains gradually became the major provenance. From the period of early Sangonghe to early Toutunhe Formations deposition, the provenance of the sediments and basin-range frame were similar to that of late Badaowan. However, the Eastern Bogda Mountains suffered intermittent uplift three times, and successive denudation. The uplifts respectively happened in early Sangonghe, late Sangonghe to early Xishanyao, and late Xishanyao to early Toutunhe. During the deposition stage of Toutunhe Formation, a

  5. Late Cambrian - Early Ordovician turbidites of Gorny Altai (Russia): Compositions, sources, deposition settings, and tectonic implications

    NASA Astrophysics Data System (ADS)

    Kruk, Nikolai N.; Kuibida, Yana V.; Shokalsky, Sergey P.; Kiselev, Vladimir I.; Gusev, Nikolay I.

    2018-06-01

    The Cambrian-Ordovician transition was the time of several key events in the history of Central Asia. They were the accretion of Mariana-type island arc systems to the Siberian continent, the related large-scale orogeny and intrusions of basaltic and granitic magma and the formation of a huge turbidite basin commensurate with the Bengal Gulf basin in the western part of the Central Asian orogenic belt (CAOB). The structure of the basin, as well as the sources and environments of deposition remain open to discussion. This paper presents new major- and trace-element data on Late-Cambrian-Early Ordovician turbidites from different parts of the Russian Altai and a synthesis of Nd isotope composition and ages of detrital zircons. The turbidites share chemical similarity with material shed from weathered continental arcs. Broad variations of CIA (39-73) and ICV (0.63-1.66) signatures in sandstones suggest origin from diverse sources and absence of significant sorting. Trace elements vary considerably and have generally similar patterns in rocks from different terranes. On the other hand, there are at least two provinces according to Nd isotope composition and age of detrital zircons. Samples from eastern Russian Altai contain only Phanerozoic zircons and have Nd isotope ratios similar to those in Early Cambrian island arcs (εNdt + 4.4… + 5.4; TNd(DM)-2-st = 0.8-0.9 Ga). Samples from central, western, and southern parts of Russian Altai contain Precambrian zircons (some as old as Late Archean) and have a less radiogenic Nd composition (εNdt up to -3.6; TNd(DM)-2-st up to 1.5 Ga). The chemical signatures of Late Cambrian to Early Ordovician turbidites indicate a provenance chemically more mature than the island arc rocks, and the presence of zircons with 510-490 Ma ages disproves their genetic relation with island arcs. The turbidite basin formed simultaneously with peaks of granitic and alkali-basaltic magmatism in the western Central Asian orogen and resulted from

  6. Early Cretaceous to Paleocene North American Drainage Reorganization and Sediment Routing from Detrital Zircons: Significance to the Alberta Oil Sands and Gulf of Mexico Petroleum Provinces

    NASA Astrophysics Data System (ADS)

    Blum, M. D.

    2014-12-01

    Detrital zircons (DZs) represent a powerful tool for reconstructing continental paleodrainage. This paper uses new DZ data from Lower Cretaceous strata of the Alberta foreland basin, and Upper Cretaceous and Cenozoic strata of the Gulf of Mexico passive margin, to reconstruct paleodrainage and sediment routing, and illustrate significance to giant hydrocarbon systems. DZ populations from the Lower Cretaceous Mannville Group of Alberta and Saskatchewan infer a continental-scale river system that routed sediment from the eastern 2/3rds of North America to the Boreal Sea. Aptian McMurray Formation fluvial sands were derived from a drainage sourced in the Appalachians that was similar in scale to the modern Amazon. Albian fluvial sandstones of the Clearwater and Grand Rapids Formations were derived from the same Appalachian-sourced drainage area, which had expanded to include tributaries from the Cordilleran arc of the northwest US and southwest Canada. DZ populations from the Gulf of Mexico coastal plain complement this view, showing that only the southern US and Appalachian-Ouachita cordillera was integrated with the Gulf through the Late Cretaceous. However, by the Paleocene, drainage from the US Western Cordillera to the Appalachians had been routed to the Gulf of Mexico, establishing the template for sediment routing that persists today. The paleodrainage reorganization and changes in sediment routing described above played key roles in establishment of the Alberta oil sands and Gulf of Mexico as giant petroleum provinces. Early Cretaceous routing of a continental-scale fluvial system to the Alberta foreland provided large and contiguous fluvial point-bar sand bodies that became economically viable reservoirs, whereas mid- to late Cretaceous drainage reorganization routed greatly increased sediment loads to the Gulf of Mexico, which loaded the shelf, matured source rocks, and drove the gravitational and salt tectonics that helped establish the working hydrocarbon

  7. Provenance from zircon U-Pb age distributions in crustally contaminated granitoids

    NASA Astrophysics Data System (ADS)

    Bahlburg, Heinrich; Berndt, Jasper

    2016-05-01

    The basement of sedimentary basins is often entirely covered by a potentially multi-stage basin fill and therefore removed from direct observation and sampling. Melts intruding through the basin stratigraphy at a subsequent stage in the geological evolution of a region may assimilate significant volumes of country rocks. This component may be preserved in the intrusive body either as xenoliths or it may be reflected only by the age spectrum of incorporated zircons. Here we present the case of an Ordovician calc-alkaline intrusive belt in NW Argentina named the "Faja Eruptiva de la Puna Oriental" (Faja Eruptiva), which in the course of intrusion sampled the unexposed and unknown basement of the Ordovician basin in this region, and parts of the basin stratigraphy. We present new LA-ICP-MS U-Pb ages on zircons from 9 granodiorites and granites of the Faja Eruptiva. The main part of the Faja Eruptiva intruded c. 445 Ma in the Late Ordovician. The zircon ages obtained from the intrusive rocks have a large spread between 2683.5 ± 21.6 and 440.0 ± 4.9 Ma and reflect the underlying crust and may be interpreted in several ways. The inherited zircons may have been derived from the oldest known unit in the region, the thick siliciclastic turbidite successions of the upper Neoproterozoic-lower Cambrian Puncoviscana Formation, which is inferred to represent the basement of the NW Argentina. The basement to the Puncoviscana Formation is not known. Alternatively, the inherited zircons may reflect the geochronological structure of the entire unexposed Early Paleozoic crust underlying this region of which the Puncoviscana Formation was only one component. This crust likely contained rocks pertaining to and detritus derived from earlier orogenic cycles of the southwestern Amazonia craton, including sources of Early Meso- and Paleoproterozoic age. Detritus derived, in turn, from the Faja Eruptiva intrusive belt reflects the origin of the granitoids as well as the inherited

  8. Internal morphology, habit and U-Th-Pb microanalysis of amphibolite-to-granulite facies zircons: geochronology of the Ivrea Zone (Southern Alps)

    NASA Astrophysics Data System (ADS)

    Vavra, Gerhard; Schmid, Rolf; Gebauer, Dieter

    Several types of growth morphologies and alteration mechanisms of zircon crystals in the high-grade metamorphic Ivrea Zone (IZ) are distinguished and attributed to magmatic, metamorphic and fluid-related events. Anatexis of pelitic metasediments in the IZ produced prograde zircon overgrowths on detrital cores in the restites and new crystallization of magmatic zircons in the associated leucosomes. The primary morphology and Th-U chemistry of the zircon overgrowth in the restites show a systematic variation apparently corresponding to the metamorphic grade: prismatic (prism-blocked) low-Th/U types in the upper amphibolite facies, stubby (fir-tree zoned) medium-Th/U types in the transitional facies and isometric (roundly zoned) high-Th/U types in the granulite facies. The primary crystallization ages of prograde zircons in the restites and magmatic zircons in the leucosomes cannot be resolved from each other, indicating that anatexis in large parts of the IZ was a single and short lived event at 299+/-5Ma (95% c. l.). Identical U/Pb ages of magmatic zircons from a metagabbro (293+/-6Ma) and a metaperidotite (300+/-6Ma) from the Mafic Formation confirm the genetic context of magmatic underplating and granulite facies anatexis in the IZ. The U-Pb age of 299+/-5Ma from prograde zircon overgrowths in the metasediments also shows that high-grade metamorphic (anatectic) conditions in the IZ did not start earlier than 20Ma after the Variscan amphibolite facies metamorphism in the adjacent Strona-Ceneri Zone (SCZ). This makes it clear that the SCZ cannot represent the middle to upper crustal continuation of the IZ. Most parts of zircon crystals that have grown during the granulite facies metamorphism became affected by alteration and Pb-loss. Two types of alteration and Pb-loss mechanisms can be distinguished by cathodoluminescence imaging: zoning-controlled alteration (ZCA) and surface-controlled alteration (SCA). The ZCA is attributed to thermal and/or decompression pulses

  9. Significance of zircon U-Pb ages from the Pescadero felsite, west-central California coast ranges

    USGS Publications Warehouse

    McLaughlin, Robert J.; Moore, Diane E.; ,; Martens, UWE C.; Clark, J.C.

    2011-01-01

    Weathered felsite is associated with the late Campanian–Maastrichtian Pigeon Point Formation near Pescadero, California. Poorly exposed, its age and correlation are uncertain. Is it part of the Pigeon Point section west of the San Gregorio–Hosgri fault? Does it rest on Nacimiento block basement? Is it dextrally offset from the Oligocene Cambria Felsite, ∼185 km to the southeast? Why is a calc-alkaline hypabyssal igneous rock intrusive into the outboard accretionary prism? To address these questions, we analyzed 43 oscillatory-zoned zircon crystals from three incipiently recrystallized pumpellyite ± prehnite ± laumontite-bearing Pescadero felsite samples by sensitive high-resolution ion microprobe–reverse geometry (SHRIMP-RG) and laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) techniques. Thirty-three zircons gave late Mesozoic U-Pb ages, with single-grain values ranging from 81 to 167 Ma; ten have pre-Mesozoic, chiefly Proterozoic ages. A group of the four youngest Pescadero zircons yielded an apparent maximum igneous age of ca. 86–90 Ma. Reflecting broad age scatter and presence of partly digested sandstone inclusions, we interpret the rest of the zircons (perhaps all) as xenocrysts. Twenty-three zircons were separated and analyzed from two samples of the similar Cambria Felsite, yielding a unimodal 27 Ma U-Pb age. Clearly, the origin of the Upper Oligocene Cambria Felsite is different from that of the Upper Cretaceous Pescadero felsite; these rocks are not correlated, and do not constrain displacement along the San Gregorio–Hosgri fault. Peak ages differ slightly, but relative probability curves for Mesozoic and pre-Mesozoic Pescadero zircons compare well, for example, with abundant U-Pb age data for detrital zircons from Franciscan metaclastic strata ∼100 km to the east in the Diablo Range–San Francisco Bay area, San Joaquin Great Valley Group turbidites, Upper Cretaceous Nacimiento block Franciscan strata, and Upper

  10. Generation and Reworking of Archaean and Hadean Crust

    NASA Astrophysics Data System (ADS)

    Hawkesworth, C.; Kemp, T.; Storey, C.; Dhuime, B.

    2008-12-01

    Combined Hf and O isotopes in well-dated zircons are increasingly used to investigate the age of the crustal source rocks of detrital and inherited zircons. O isotopes are used to screen out samples that may have a sediment contribution in the parental magma, since sediments yield hybrid model ages that are difficult to interpret. Mafic and granitic rocks also have different Lu/Hf ratios, and so in principle the Hf isotope ratios of zircons can be used to investigate the broad composition of the average crust. The unradiogenic Hf isotope compositions of the Jack Hills zircons from Western Australia indicate the existence of enriched (crustal) reservoirs by at least 4.3 Ga (Y. Amelin et al., 1998, Nature v. 399, p. 252- 255; T. M. Harrison et al., 2005, Science, v. 310, p. 1947-1950). We report in situ Hf isotope analyses of the Jack Hills zircons in which the Pb isotope age information is measured concurrently with the Hf isotope data. The simple data arrays provide clear evidence for Earth differentiation at 4.5 Ga, with the production of both continental crust-like material and a mafic crustal reservoir with higher Lu/Hf. The continued resampling of this reservoir over at least 1.5 Ga argues for a substantial stabilised volume of mafic crust, and, in tandem with oxygen isotope data, the existence of Hadean continents. Zircons remain poor windows into the upper mantle. We therefore investigate Nd isotopes in well-dated titanites; they have closure temperatures for Pb in the range 600-750oC and they can retain cores with distinct age and REE chemistry to subsequent rim overgrowths. Nd isotopes offer a complementary approach to Hf in zircon that can be used to construct the both depleted mantle evolution and crustal growth curves.

  11. Sedimentary records on the subduction-accretion history of the Russian Altai, northwestern Central Asian Orogenic Belt

    NASA Astrophysics Data System (ADS)

    Chen, Ming; Sun, Min

    2017-04-01

    The Russian Altai, comprising the northern segment of the Altai-Mongolian terrane (AM) in the south, the Gorny Altai terrane (GA) in the north and the intervening Charysh-Terekta-Ulagan-Sayan suture zone, is a key area of the northwestern Central Asian Orogenic Belt (CAOB). A combined geochemical and detrital zircon study was conducted on the (meta-)sedimentary sequences from the Russian Altai to reveal the tectono-magmatic history of these two terranes and their amalgamation history, which in turn place constraints on the accretionary orogenesis and crustal growth in the CAOB. The Cambrian-Ordovician meta-sedimentary rocks from the northern AM are dominated by immature sediments possibly sourced from intermediate-felsic igneous rocks. Geochemical data show that the sediments were likely deposited in a continental arc-related setting. Zircons separated from these rocks are mainly 566-475 Ma and 1015-600 Ma old, comparable to the magmatic records of the Tuva-Mongolian terrane and surrounding island arcs in the western Mongolia. The similar source nature, provenance and depositional setting of these rocks to the counterparts from the Chinese Altai (i.e., the southern AM) imply that the whole AM possibly represents a coherent accretionary prism of the western Mongolia in the early Paleozoic rather than a Precambrian continental block with passive marginal deposition as previously thought. In contrast, the Cambrian to Silurian (meta-)sedimentary rocks from the GA are characterized by a unitary zircon population with ages of 640-470 Ma, which were potentially sourced from the Kuznetsk-Altai intra-oceanic island arc in the east of this terrane. The low abundance of 640-540 Ma zircons (5%) may attest that this arc was under a primitive stage in the late Neoproterozoic, when mafic igneous rocks dominated. However, the voluminous 530-470 Ma zircons (95%) suggest that this arc possibly evolved toward a mature one in the Cambrian to early Ordovician with increasing amount of

  12. LA-ICP-MS U-Pb detrital zircon study and structural observations of the Cycladic Blueschist Unit on Heraklia Island (Cyclades, Greece)

    NASA Astrophysics Data System (ADS)

    Laskari, Sofia; Soukis, Konstantinos; Lozios, Stylianos; Stockli, Daniel

    2017-04-01

    At the central and southern part of the Attic-Cycladic complex (Aegean Sea, Greece) significant exposures of the Cycladic Basement Unit orthogneisses and meta-sediments are observed. These are mainly cropping out in Paros, Naxos and Ios islands and to a much lesser extend in Sikinos Island and they comprise Variscan (granitic) orthogneisses and late Paleozoic metasediments. In this paper we present evidence of a hitherto not identified possible outcrop of the Cycladic Basement in Heraklia Island (central Cyclades). The small Heraklia Island, situated at the center of the Attic-Cycladic core complex in the Aegean, between the islands of Naxos and Ios, consists of rocks that are attributed to the Cycladic Blueschist Unit. The tectonostratigraphy of Heraklia Island includes: a) a lowermost schist sequence with interbedded lenses of felsic orthogneisses whose primary relationship is obliterated by later subduction and exhumation related shearing b) A 200m thick variegated marble sequence with sparse calk-schist intercalations, which is isoclinally folded together with 100m thick overlying quartz-mica and calc-schists schists. All rocks comprise a penetrative foliation formed by greenschist facies mineral assemblages but in the uppermost schists relics of the Eocene HP event are found in the form of glaucophane inclusions within albite porphyroblasts. A mylonitic planar fabric with a cataclastic overprint is observed at the base of the marble sequence and the roof of the underlying schists and orthogneisses. It is accompanied by a N-S stretching lineation, subparallel to isoclinal folding in all scales. Numerous kinematic indicators reveal a top-to-N sense of shear thus linking the Heraklia rocks kinematically with the crustal extensional detachment systems of both Naxos and Ios islands. LA-ICP-MS U-Pb detrital zircon study of schists and gneisses is used in order to identify provenance and to elucidate the tectonostratigrachic relationship between the lower and upper

  13. New Insights into Arctic Tectonics: Uranium-Lead, (Uranium-Thorium)/Helium, and Hafnium Isotopic Data from the Franklinian Basin, Canadian Arctic Islands

    NASA Astrophysics Data System (ADS)

    Anfinson, Owen Anthony

    More than 2300 detrital zircon uranium-lead (U-Pb) ages, 32 176Hf/177Hf (eHf) isotopic values, 37 apatite helium (AHe) ages, and 72 zircon helium (ZHe) ages represent the first in-depth geochronologic and thermochronologic study of Franklinian Basin strata in the Canadian Arctic and provide new insight on >500 M.y. of geologic history along the northern Laurentian margin (modern orientation). Detrital zircon U-Pb age data demonstrate that the Franklinian Basin succession is composed of strata with three distinctly different provenance signatures. Neoproterozoic and Lower Cambrian formations contain detrital zircon populations consistent with derivation from Archean to Paleoproterozoic gneisses and granites of the west Greenland--northeast Canadian Shield. Lower Silurian to Middle Devonian strata are primarily derived from foreland basin strata of the East Greenland Caledonides (Caledonian orogen). Middle Devonian to Upper Devonian strata also contain detrital zircon populations interpreted as being primarily northerly derived from the continental landmass responsible for the Ellesmerian Orogen (often referred to as Crockerland). U-Pb age data from basal turbidites of the Middle to Upper Devonian clastic succession suggest Crockerland contributed sediment to the northern Laurentian margin by early-Middle Devonian time and that prior to the Ellesmerian Orogeny Crockerland had a comparable geologic history to the northern Baltica Craton. Detrital zircon U-Pb ages in Upper Devonian strata suggest Crockerland became the dominant source by the end of Franklinian Basin sedimentation. Mean eHf values from Paleozoic detrital zircon derived from Crockerland suggest the zircons were primarily formed in either an island arc or continental arc built on accreted oceanic crust setting. ZHe cooling ages from Middle and Upper Devonian strata were not buried deeper than 7 km since deposition and suggest Crockerland was partially exhumed during the Caledonian Orogen. AHe cooling ages

  14. U-Pb SHRIMP II age and origin of zircon from lhertzolite of the bug Paleoarchean complex, Ukrainian Shield

    NASA Astrophysics Data System (ADS)

    Lobach-Zhuchenko, S. B.; Baltybaev, Sh. K.; Glebovitsky, V. A.; Sergeev, S. A.; Lokhov, K. O.; Egorova, Yu. S.; Balagansky, V. V.; Skublov, S. G.; Galankina, O. L.; Stepanyuk, L. M.

    2017-12-01

    Complex study of the U-Pb and Lu-Hf systems of zircon from a lhertzolite lens of Archean gneiss enderbites of the Bug complex, Ukrainian Shield, showed that ultramafic magma was contaminated by the material of the country gneiss enderbites. The age of the zircons of 2.81 ± 0.05 Ga corresponds to the period of ultramafic magmatism within the Bug complex. Previously, this peak of endogenic activity was considered the stage of manifestation of metamorphism and magmatism of mafic composition.

  15. Chemical evolution of Himalayan leucogranites based on an O, U-Pb and Hf study of zircon

    NASA Astrophysics Data System (ADS)

    Hopkinson, Thomas N.; Warren, Clare J.; Harris, Nigel B. W.; Hammond, Samantha J.; Parrish, Randall R.

    2015-04-01

    Crustal melting is a characteristic process at convergent plate margins, where crustal rocks are heated and deformed. Miocene leucogranite sheets and plutons are found intruded into the high-grade metasedimentary core (the Greater Himalayan Sequence, GHS) across the Himalayan orogen. Previously-published Himalayan whole-rock data suggest that these leucogranites formed from a purely meta-sedimentary source, isotopically similar to those into which they now intrude. Bulk rock analyses carry inherent uncertainties, however: they may hide contributions from different contributing sources, and post-crystallization processes such as fluid interaction may significantly alter the original chemistry. In contrast, zircon is more able to retain precise information of the contributing sources of the melt from which it crystallises whilst its resistant nature is impervious to post-magmatic processes. This multi-isotope study of Oligocene-Miocene leucogranite zircons from the Bhutan Himalaya, seeks to differentiate between various geochemical processes that contribute to granite formation. Hf and O isotopes are used to detect discrete changes in melt source while U-Pb isotopes provide the timing of zircon crystallisation. Our data show that zircon rims of Himalayan age yield Hf-O signatures that lie within the previously reported whole-rock GHS field, confirming the absence of a discernible mantle contribution to the leucogranite source. Importantly, we document a decrease in the minimum ɛHf values during Himalayan orogenesis through time, correlating to a change in Hf model age from 1.4 Ga to 2.4 Ga. Nd model ages for the older Lesser Himalayan metasediments (LHS) that underthrust the GHS are significantly older than those for the GHS (2.4-2.9 Ga compared with 1.4-2.2 Ga), and as such even minor contributions of LHS material incorporated into a melt would significantly increase the resulting Hf model age. Hence our leucogranite data suggest either a change of source within

  16. Provenance of a large Lower Cretaceous turbidite submarine fan complex on the active Laurasian margin: Central Pontides, northern Turkey

    NASA Astrophysics Data System (ADS)

    Akdoğan, Remziye; Okay, Aral I.; Sunal, Gürsel; Tari, Gabor; Meinhold, Guido; Kylander-Clark, Andrew R. C.

    2017-02-01

    The Pontides formed the southern active margin of Laurasia during the Mesozoic. They became separated from mainland Laurasia during the Late Cretaceous, with the opening of the Black Sea as an oceanic back-arc basin. During the Early Cretaceous, a large submarine turbidite fan complex developed in the Central Pontides. The turbidites cover an area of 400 km by 90 km with a thickness of more than 2 km. We have investigated the provenance of these turbidites-the Çağlayan Formation-using paleocurrent measurements, U-Pb detrital zircon ages, REE abundances of dated zircons and geochemistry of detrital rutile grains. 1924 paleocurrent measurements from 96 outcrop stations indicate flow direction from northwest to southeast in the eastern part of the Çağlayan Basin and from north-northeast to west-southwest in the western part. 1194 detrital zircon ages from 13 Lower Cretaceous sandstone samples show different patterns in the eastern, central and western parts of the basin. The majority of the U-Pb detrital zircon ages in the eastern part of the basin are Archean and Paleoproterozoic (61% of all zircon ages, 337 grains); rocks of these ages are absent in the Pontides and present in the Ukrainian Shield, which indicates a source north of the Black Sea. In the western part of the basin the majority of the zircons are Carboniferous and Neoproterozoic (68%, 246 grains) implying more local sources within the Pontides. The detrital zircons from the central part show an age spectrum as mixture of zircons from western and eastern parts. Significantly, Jurassic and Early Cretaceous zircons make up less than 2% of the total zircon population, which implies lack of a coeval magmatic arc in the region. This is compatible with the absence of the Lower Cretaceous granites in the Pontides. Thus, although the Çağlayan Basin occupied a fore-arc position above the subduction zone, the arc was missing, probably due to flat subduction, and the basin was largely fed from the Ukrainian

  17. The timing of tertiary metamorphism and deformation in the Albion-Raft River-Grouse Creek metamorphic core complex, Utah and Idaho

    USGS Publications Warehouse

    Strickland, A.; Miller, E.L.; Wooden, J.L.

    2011-01-01

    The Albion-Raft River-Grouse Creek metamorphic core complex of southern Idaho and northern Utah exposes 2.56-Ga orthogneisses and Neoproterozoic metasedimentary rocks that were intruded by 32-25-Ma granitic plutons. Pluton emplacement was contemporaneous with peak metamorphism, ductile thinning of the country rocks, and top-to-thewest, normal-sense shear along the Middle Mountain shear zone. Monazite and zircon from an attenuated stratigraphic section in the Middle Mountain were dated with U-Pb, using a SHRIMP-RG (reverse geometry) ion microprobe. Zircons from the deformed Archean gneiss preserve a crystallization age of 2532 ?? 33 Ma, while monazites range from 32.6 ?? 0.6 to 27.1 ?? 0.6 Ma. In the schist of the Upper Narrows, detrital zircons lack metamorphic overgrowths, and monazites produced discordant U-Pb ages that range from 52.8 ?? 0.6 to 37.5 ?? 0.3 Ma. From the structurally and stratigraphically highest unit sampled, the schist of Stevens Spring, narrow metamorphic rims on detrital zircons yield ages from 140-110 Ma, and monazite grains contained cores that yield an age of 141 ??2 Ma, whereas rims and some whole grains ranged from 35.5 ?? 0.5 to 30.0 ?? 0.4 Ma. A boudinaged pegmatite exposed in Basin Creek is deformed by the Middle Mountains shear zone and yields a monazite age of 27.6 ?? 0.2 Ma. We interpret these data to indicate two periods of monazite and metamorphic zircon growth: a poorly preserved Early Cretaceous period (???140 Ma) that is strongly overprinted by Oligocene metamorphism (???32-27 Ma) related to regional plutonism and extension. ?? 2011 by The University of Chicago.

  18. In situ U-Pb and Lu-Hf isotopic studies of zircons from the Sancheong-Hadong AMCG suite, Yeongnam Massif, Korea: Implications for the petrogenesis of ∼1.86 Ga massif-type anorthosite

    NASA Astrophysics Data System (ADS)

    Lee, Yuyoung; Cho, Moonsup; Yi, Keewook

    2017-05-01

    Isotopic and geochemical characteristics of Proterozoic anorthosite-mangerite-charnockite-granite (AMCG) suite have long been used for tracing the mantle-crustal source and magmatic evolution. We analyzed Lu-Hf isotopic compositions of zircon from the Sancheong-Hadong AMCG complex, Yeongnam Massif, Korea, in order to understand tectonomagmatic evolution of the Paleoproterozoic AMCG suite occurring at the southeastern margin of the North China Craton (NCC). The anorthositic rocks in this complex, associated with charnockitic and granitic gneisses, were recrystallized to eradicate magmatic features. In situ SHRIMP (sensitive high-resolution ion microprobe) U-Pb analyses of zircon from a leuconorite and an oxide-bearing gabbroic dyke yielded weighted mean 207Pb/206Pb ages of 1870 ± 2 Ma and 1861 ± 6 Ma, respectively. Charnockitic, granitic, and porphyroblastic gneisses yielded weighted mean 207Pb/206Pb zircon ages of 1861 ± 6 Ma, 1872 ± 6 Ma, and 1873 ± 4 Ma, respectively. These crystallization ages, together with our previous geochronological data for anorthosites (1862 ± 2 Ma), are indicative of episodic AMCG magmatism over an ∼10 Ma interval. Initial εHf(t) values of zircon analyzed from five anorthositic rocks and four felsic gneisses range from +2.1 to -6.1 and -0.3 to -5.4, respectively. Zircon Hf isotopic data in combination with available whole rock Sr-Nd isotopic data suggest that anorthositic parental magma was most likely derived from a mantle source and variably affected by crustal contamination. This crustal component is also reflected in charnockitic-granitic magmas produced primarily by the melting of lower crust. Taken together, the AMCG magmatism at 1.87-1.86 Ga in the Yeongnam Massif is most likely a late orogenic product of Paleoproterozoic NCC amalgamation tectonically linked to assembly of the Columbia supercontinent.

  19. Detrital dating of Asian orogenesis: insights and caveats

    NASA Astrophysics Data System (ADS)

    Burbank, D. W.

    2007-12-01

    Technological advances over the past two decades have facilitated increasingly routine application of single- crystal dating and cosmogenic nuclide dating to studies of orogenic erosion. Both approaches commonly utilize grab samples of detrital sediment, either modern or ancient. Whereas detrital cosmogenic data are typically used to define mean erosion rates for upstream catchments, single-crystal ages are used both to discern provenance and to define lag times: interval between isotopic closure and deposition. Recent results from dating modern fluvial sediments illuminate key concepts that underpin interpretations of results from older strata: the fidelity of the detrital signal, its evolution through an orogen, its relationship to discrete source areas, and its temporal evolution. Despite the increasing availability of dates and rates for detrial grains, relatively few studies have addressed the sources of uncertainty that modulate the precision and accuracy with which detrital results should be interpreted. Such uncertainties derive not only from sampling statistics and measurement uncertainties, but also from both geomorphic sources (seasonal variation in sediment supply and source, changes in glacial cover, the impact of stochastic geomorphic events, such as landslides), as well as tectonic ones (time-dependent deformation and thermal models, particle paths through the orogen). A better understanding of the impact of these uncertainties will underpin more reliable and less speculative interpretations of future dating results from both ancient and modern detrital fluvial sediments.

  20. Provenance of Jurassic sediments in the Hefei Basin, east-central China and the contribution of high-pressure and ultrahigh-pressure metamorphic rocks from the Dabie Shan

    NASA Astrophysics Data System (ADS)

    Li, Renwei; Wan, Yusheng; Cheng, Zhenyu; Zhou, Jianxiong; Li, Shuangying; Jin, Fuquan; Meng, Qingren; Li, Zhong; Jiang, Maosheng

    2005-03-01

    The provenance of the Jurassic sediments in the Hefei Basin is constrained by compositions of the detrital K-white micas and garnets, and SHRIMP dating of the detrital zircons, which can help to understand the evolution and to reconstruct the paleogeographic distribution of HP-UHP rocks in the Jurassic Dabie Shan. (1) For the oldest Mesozoic sediments at the bottom of the Fanghushan Formation ( J1), the predominance of the early Paleozoic and Luliang (1700-1900 Ma) zircons indicates a major source from the North China Block. However, Neoproterozoic zircons as the major component in other Jurassic sediments indicate that the source rocks were mainly derived from the exhumed Yangtze Block in the Dabie Shan. (2) The co-occurrence of high-Si phengites and Triassic zircons provides stratigraphic evidence that the first exposure of the UHP rocks at the Earth's surface in the Dabie Shan occurred in the Early Jurassic during deposition of the Fanghushan Formation. (3) From the east to the west of the Hefei Basin, there is a spatial variation in the compositions for detrital micas and garnets, and in the U-Pb ages of detrital zircons. Evidently, HP-UHP rocks were widely distributed at outcrop in the eastern Dabie Shan. In contrast, they were less important in the western Dabie Shan during the Jurassic.

  1. Petrologic and zircon U-Pb geochronological characteristics of the pelitic granulites from the Badu Complex of the Cathaysia Block, South China

    NASA Astrophysics Data System (ADS)

    Zhao, Lei; Zhou, Xiwen; Zhai, Mingguo; Liu, Bo; Cui, Xiahong

    2018-06-01

    The recognition of the Indosinian Orogeny in the South China block has been controversial and difficult because of strong weathering and thick cover. High temperature (HT) and high pressure (HP) metamorphic rocks related to this orogeny were considered to be absent from this orogenic belt until the recent discovery of eclogite and granulite facies meta-igneous rocks, occurring as lenses within the meta-sedimentary rocks of the Badu Complex. However, metamorphic state of these meta-sedimentary rocks is still not clear. Besides, there have been no geochronological data of HT pelitic granulites previously reported from the Badu Complex. This paper presents petrographic characteristics and zircon geochronological results on the newly discovered kyanite garnet gneiss, pyroxene garnet gneiss and the HT pelitic granulites (sillimanite garnet gneiss). Mineral assemblages are garnet + sillimanite + ternary feldspar + plagioclase + quartz + biotite for the HT pelitic granulite, kyanite + ternary feldspar + garnet + sillimanite + plagioclase + quartz + biotite for the kyanite garnet gneiss, and garnet + biotite + pyroxene + plagioclase + ternary feldspar + quartz for the pyroxene garnet gneiss, respectively. Decompressional coronas around garnet grains can be observed in all these pelitic rocks. Typical granulite facies mineral assemblages and reaction textures suggest that these rocks experienced HP granulite facies metamorphism and overprinted decompression along a clockwise P-T loop. Results from integrated U-Pb dating and REE analysis indicate the growth of metamorphic zircons from depleted heavy REE sources (100-50 chondrite) compared with detrital zircons derived from granitic sources (typically > 1000 chondrite). Metamorphic zircons in HP granulite exhibit no or subdued negative Eu anomalies, which perhaps indicate zircon overgrowth under eclogite facies conditions. The zircon overgrowth ages range from 250 to 235 Ma, suggesting that HP granulite (eclogite) to

  2. Magmatic origin and fluid alteration versus inheritance: Complex history of accessory minerals from I-type granites from northern Victoria Land (Antarctica)

    NASA Astrophysics Data System (ADS)

    Menneken, M.; John, T.; Läufer, A.; Berndt, J.; Henjes-Kunst, F.; Giese, J.

    2016-12-01

    When reconstructing the formation and evolution of Earths earliest crust, one is still heavily reliant on information that can be gathered from detrital zircon grains, which have been proven to be a useful tool concerning the various isotopic, chemical, and mineralogical features that can be utilized within. However, detailed investigations have shown that some of these tracers might be prone to alteration and will not necessarily reflect conditions during formation [1, 2]. In this study, zircons and their host rocks from the Granite Harbour Intrusives (GHI) of northern Victoria Land, Antarctica, have been investigated with respect to regional evolution of continental crust as well as the reliability of zircon as a recorder of crustal formation. Here we present U-Pb, δ18O, trace element and inclusion data of zircons from Cambro-Ordovician granitoids, as well as geochemical analyses of accessory apatites. Our initial results show that even in I-type granitoids with a presumably simple formation history, U-Pb-age data and related isotopic, chemical, or mineralogical features have to be evaluated carefully in order to constrain the timing of magmatic events, inheritance or fluid alteration events. They do, for example, incorporate a large portion of recycled material, which is clearly reflected by a strong component of inherited U-Pb-zircon ages, but can also be inferred by comparing main- and trace-element compositions of apatite inclusions in zircon with accessory apatites. Apatite inclusions from all investigated samples for example, are clearly higher in F concentration, than their accessory counterparts. However, not all zircon grains record the youngest event, emphasizing that not only alteration might be a key factor to consider when evaluating zircon characteristics with respect to their host rock, but also, the timing and preservation of predating features. [1] Rasmussen et al. (2011) Metamorphic replacement of mineral inclusions in detrital zircon from Jack

  3. Multiple Hadean crystallization and reworking events preserved in individual Jack Hills zircon grains

    NASA Astrophysics Data System (ADS)

    Bellucci, Jeremy; Nemchin, Alexander; Whitehouse, Martin; Snape, Joshua

    2017-04-01

    Five Hadean (>3.9 Ga) aged zircon grains from the Jack Hills metasedimentary belt have been investigated by an improved secondary ion mass spectrometry scanning ion image technique. This technique has the ability to obtain accurate and precise full U-Pb systematics on a scale <5 μm, as well as document the spatial distribution of U, Th and Pb. All five of the grains investigated here have complex cathodoluminescence patterns that correlate to different U, Th, and Pb concentration domains. The age determinations for these different chemical zones indicate multiple reworking events that are preserved in each grain and have affected the primary crystalized zircon on the scale of <10 μm, smaller than traditional ion microprobe spot analyses. These new scanning ion images and age determinations suggest that roughly half, if not all, previous analyses, including those of trace elements and various isotope systems, could have intersected several domains of unfractured zircon, thus making the interpretation of any trace element, Hf, or O isotopic data tenuous. Lastly, all of the grains analyzed here preserve at least two distinguishable 207Pb/206Pb ages. These ages are preserved in core-rim and/or complex internal textural relationships. These secondary events took place during at ca. 4.3, 4.2, 4.1, 4.0, and 3.7 Ga potentially indicating a sequence of magmatic and/or metamorphic events that recycled some volume of early crust during the Hadean and into Paleo- to Mesoarchean several times with an apparent periodicity of ca. 100 Ma.

  4. Implications of Bishop Tuff zircon U-Pb ages for rates of zircon growth and magma accumulation

    NASA Astrophysics Data System (ADS)

    Reid, M. R.; Schmitt, A. K.

    2012-12-01

    Rates of geologic processes obtained from natural studies rely on accurate geochronologic information. An important benchmark in geochronology as well as a valuable source of insights into the evolution of voluminous explosive eruptions is the >600 km3 Bishop Tuff (BT). A recently determined weighted mean 206Pb/238U date of 767.1±0.9 ka for a BT zircon population [1] is indistinguishable from the recalibrated 40Ar/39Ar sanidine date of 767.4±2.2 ka [2], potentially providing a key intercalibration point between astronomical and radio-isotopic dating approaches. Consequences of these results are linear zircon growth rates of >1×10-14 cm/sec and magma accumulation rates of >200 km3/ka. In contrast, spatially selective SIMS U-Pb dating of BT zircons yielded mean pre-eruption ages of 850 ka [3], a difference that raises questions about the validity of intercalibration between U-Pb and K-Ar dating methods and the history of magma accumulation. We obtained new SIMS analyses of the BT zircons using more spatially and analytically sensitive methods and verifying our accuracy against the TIMS dated Quaternary zircon 61.308A (2.488±0.002 Ma). Analyses were performed on zircon rims and on oriented cross-sections exposed during optical interferometry-calibrated serial sectioning removing the outermost ~31 μm. Sputtering by a 100 nA ion beam versus the normally employed 10-12 nA beam resulted in enhanced radiogenic Pb yields and analytical uncertainties for Quaternary zircon approaching the U-Pb age reproducibility of the primary zircon standard (~1-2 % for AS3). Ages obtained at ~31 μm depth (representing <5% of crystal growth in most cases) average 892±26ka (MSWD=0.29), corroborating previous evidence for residence times of several tens of ka. Rim ages average 781±22 ka (MSWD=0.61), overlapping Ar/Ar determinations of eruption age and corroborating the importance of near-eruption aged zircon growth. Our results confirm the presence of BT zircon domains that predate

  5. Proterozoic evolution of part of the Embu Complex, eastern São Paulo state, SE Brazil

    NASA Astrophysics Data System (ADS)

    Vinagre da Costa, Rodrigo; Trouw, Rudolph Allard Johannes; Mendes, Julio Cezar; Geraldes, Mauro; Távora, Arthur; Nepomuceno, Felipe; de Araújo Junior, Edson Barros

    2017-11-01

    This paper presents detrital zircon ages obtained in rocks of the Embu Complex, southeastern São Paulo State, Brazil. The Embu Complex encompasses a Paleoproterozoic basement represented by migmatitic hornblende and biotite orthogneisses covered by (kyanite)-(sillimanite)-(garnet) bearing biotite-muscovite schists and paragneisses with decametric intercalations of quartzites and calcsilicate rocks. In the studied area this metasedimentary sequence is intruded by the porphyritic Serra do Quebra Cangalhagranite. Through field and microstructural studies, four ductile deformational phases wereidentified. Metamorphic events related to the Brasiliano Orogeny that affected the studied rocks were dominantly under medium temperature and pressure conditions, from greenschist to middle amphibolite facies. Detrital zircon crystals from a ∼10 m thick quartzite layer were analyzed by LA-ICP-MS resulting in a wide range of ages between 2100 and 600 Ma that fall mainly in four groups: the first group between 2.1 and 1.6 Ga, with apex at 1.7 Ga; two less expressive Mesoproterozoic groups with values between 1.6 and 1.2 Ga; and a fourth group with values between 1.2 and 0.6 Ga. Considering the geochronological data, the sedimentation of the basin began after 852 ± 40 Ma (the youngest igneous grain) and finished before ∼786 Ma (metamorphic rim). The age of the intrusive Serra do Quebra Cangalha granite (∼680 Ma) is consistent with this minimum age. The opening of the basin could be related to the break-up of Rodinia, which resulted in several small continents, among them the Paranapanema and São Francisco paleocontinents. Comparing these data with similar provenance data from the Apiaí terrane, itseems probable that the Embu Complex was physically connected with it during most of their evolution.

  6. Zircon from charnockite gneiss, charnockite, and leucosome of migmatite in the Nimnyr Block of the Aldan Shield

    NASA Astrophysics Data System (ADS)

    Glebovitsky, V. A.; Sedova, I. S.; Berezhnaya, N. G.; Skublov, S. G.; Samorukova, L. M.

    2015-12-01

    The microgeochemistry of zircon was studied in three samples: charnockite gneiss (1594), charnockite (1594a), and migmatite leucosome Lc4 (1594c). Prismatic (Zrn I) and oval (Zrn II) zircon morphotypes are distinguished in the first two samples. Most zircon grains consist of two-phase cores and overgrowth rims variable in thickness. The average weighted concordant U-Pb age of Zrn II cores from charnockite gneiss is 2436 ± 10 Ma. The concordant ages of Zrn I and Zrn II cores from charnockite are 2402 ± 16 Ma and 2453 ± 14 Ma, respectively. Some overgrowth rims are 1.9-2.1 Ga in age. In leucosome Lc4, all measured prismatic zircon crystals yielded a discordant age of 1942 ± 11 Ma (the upper intersection of discordia with concordia). These zircons are strongly altered and anomalously enriched in U and Th. Zrn I grains are enriched relative to Zrn II in REE, Li, Ca, Sr, Ba, Hf, Th, and U. Zrn I is considered to be a product of melt crystallization or subsolidus recrystallization in the presence of melt. Zrn II is relict or crystallizing from melt and then partly fused again. Zrn I from charnockite gneiss and especially from charnockite are markedly altered and have a more discordant age than Zrn II. This is probably related to concentration of fluid in the residual melt left after zircon crystallization.

  7. Detrital zircon fission track analysis reveals the thermotectonic history of ice-covered rocks of the Chugach-St. Elias orogen, SE-Alaska

    NASA Astrophysics Data System (ADS)

    Enkelmann, E.; Garver, J. I.; Pavlis, T. L.; Bruhn, R. L.; Chapman, J. B.

    2007-12-01

    Investigating the exhumation history of the Chugach-St. Elias orogen (SE Alaska) using low-temperature thermochronometers is challenged by significant ice cover. Assuming exhumation drove cooling, cooling ages increase with elevation in an orogenic belt, and as such the youngest ages occur in valley bottoms. Cooling and exhumation rates are expected to be very high in the Chugach-St. Elias orogen due to efficient glacial erosion and the most intense erosion occurs under the major ice fields. To study the cooling history of rapidly exhuming rocks underneath this ice cover, we analyzed detrital zircon fission track (DZFT) ages of Recent sand samples from modern rivers that drain the central Bagley Ice field and smaller glaciers draining north (Chitina valley) and south (Pacific) of the mountain range. A distinct advantage of DZFT is that it allows one to sample a landscape regardless of accessibility. The youngest ZFT component populations of samples north and south of the Bagley Ice field record a Late Miocene (5-13 Ma) cooling of the orogen. The pattern of cooling ages shows symmetry across the orogen predates the earliest record of the collision of the Yakutat terrane with Alaska. This result contrasts with the asymmetric cooling pattern displayed by low- temperature thermochronological ages (AFT and AHe) of the exposed bedrock within the range. Apatite FT and U- Th/He ages of bedrock samples south of the Bagley Ice field record the syn-collisional (<5 Ma) fast exhumation whereas apatite ages to the north reveal more heterogeneous exhumation and vary widely from Miocene to Eocene. The bedrock samples from throughout the orogenic belt thus display predominantly the effects of the recent climatic situation of the mountain range with very high precipitation on the south, seaward side versus a more arid north side. Our ZFT results from the northern drainages highlight the relative sense and timing of two important fault zones, both accommodate south-side-up exhumation

  8. A relatively reduced Hadean continental crust

    NASA Astrophysics Data System (ADS)

    Yang, Xiaozhi; Gaillard, Fabrice; Scaillet, Bruno

    2014-05-01

    Among the physical and chemical parameters used to characterize the Earth, oxidation state, as reflected by its prevailing oxygen fugacity (fO2), is a particularly important one. It controls many physicochemical properties and geological processes of the Earth's different reservoirs, and affects the partitioning of elements between coexisting phases and the speciation of degassed volatiles in melts. In the past decades, numerous studies have been conducted to document the evolution of mantle and atmospheric oxidation state with time and in particular the possible transition from an early reduced state to the present oxidized conditions. So far, it has been established that the oxidation state of the uppermost mantle is within ±2 log units of the quartz-fayalite-magnetite (QFM) buffer, probably back to ~4.4 billion years ago (Ga) based on trace-elements studies of mantle-derived komatiites, kimberlites, basalts, volcanics and zircons, and that the O2 levels of atmosphere were initially low and rose markedly ~2.3 Ga known as the Great Oxidation Event (GOE), progressively reaching its present oxidation state of ~10 log units above QFM. In contrast, the secular evolution of oxidation state of the continental crust, an important boundary separating the underlying upper mantle from the surrounding atmosphere and buffering the exchanges and interactions between the Earth's interior and exterior, has rarely been addressed, although the presence of evolved crustal materials on the Earth can be traced back to ~4.4 Ga, e.g. by detrital zircons. Zircon is a common accessory mineral in nature, occurring in a wide variety of igneous, sedimentary and metamorphic rocks, and is almost ubiquitous in crustal rocks. The physical and chemical durability of zircons makes them widely used in geochemical studies in terms of trace-elements, isotopes, ages and melt/mineral inclusions; in particular, zircons are persistent under most crustal conditions and can survive many secondary

  9. Convergence of detrital stoichiometry predicts thresholds of nutrient-stimulated breakdown in streams

    Treesearch

    David W. P. Manning; Amy D. Rosemond; Vladislav Gulis; Jonathan P. Benstead; John S. Kominoski; John C. Maerz

    2016-01-01

    Nutrient enrichment of detritus-based streams increases detrital resource quality for consumers and stimulates breakdown rates of particulate organic carbon (C). The relative importance of dissolved inorganic nitrogen (N) vs. phosphorus (P) for detrital quality and their effects on microbial- vs. detritivore-mediated detrital breakdown are poorly understood....

  10. Observations and controls on the occurrence of inherited zircon in Concord-type granitoids, New Hampshire

    USGS Publications Warehouse

    Harrison, T.M.; Aleinikoff, J.N.; Compston, W.

    1987-01-01

    U-Pb analyses of zircons separated from two Concord-type plutons near Sunapee and Dixville Notch, New Hampshire, reveal differences in the pattern and magnitude of zircon inheritance which are related to differences in melt chemistry. The Sunapee pluton contains only slightly more Zr than required to saturate the melt at the peak temperature of 700 ?? 30??C. Traces of inherited zircon in this separate are inferred to be present as small, largely resorbed grains. In contrast, the Long Mountain pluton, near Dixville Notch, contains about 240% more Zr than required to saturate the melt. Thus, more than half of the Zr existed as stable, inherited zircon crystals during the partial fusion event, consistent with the observation of substantial inheritance in all grain size fractions. Ion probe intra-grain analyses of zircon from the Long Mountain pluton indicate a complex pattern of inheritance with contributions from at least two Proterozoic terrenes and caution against simple interpretations of upper and lower intercepts of chords containing an inherited component. Ion probe analyses of zircons from the Sunapee pluton reveal clear evidence of U loss which results in incorrect apparent conventional U-Pb ages. Ages of crystallization for the Long Mountain and Sunapee pluton are ~350 and 354 ?? 5 Ma, respectively. A Sm/Nd measurement for the Long Mountain pluton yields a depleted mantle model age of 1.5 Ga, consistent with the observed inheritance pattern. In contrast, a Sm/Nd model age for the Sunapee pluton is improbably old due to minor monazite fractionation. ?? 1987.

  11. SHRIMP U-Pb zircon dating from eclogite lenses in marble, Dabie-Sulu UHP terrane: restriction on the prograde, UHP and retrograde metamorphic ages

    NASA Astrophysics Data System (ADS)

    Liu, F.; Gerdes, A.; Xue, H.; Liang, F.

    2006-12-01

    Eclogite as lenses in impure marbles from Dabie-Sulu UHP terrane, represent parts of deeply subducted meta- sedimentary rocks. To constrain the age of metamorphism during subduction and exhumation, zircons from 2 eclogite samples in Dabie-Sulu impure marbles have been investigated. Beside Inherited (detrital) grains, 3 different metamorphic zircon domains have been identified based on distribution of mineral inclusion, trace elements and cathodoluminescence (CL) imaging: 1. Dark-luminescent rounded cores with quartz eclogite- facies mineral inclusions suggest formation at high-pressure (HP) metamorphic conditions. 2. White- luminescent zircon, either surrounding domain 1 or as rounded to spindly cores with index coesite eclogite- facies mineral inclusions indicates formation at UHP conditions. 3. Grey-luminescent rims around domain 2 with low-pressure mineral inclusions suggest formation during late regional amphibolite-facies retrogression. The three distinct zircon domains were dated by SHRIMP and yielded three discrete and meaningful age groups: 245±4 Ma for prograde HP metamorphism, 235±3 Ma for UHP metamorphism and 215±6 Ma for late amphibolite-facies retrogression from Dabie-Sulu eclogite. This data suggests that subduction and exhumation took place in about 10-11 Myr and 19-20 Myr, respectively. Continental materials was subducted from surface to the deep mantle depth at rates of 10 km/Myr, and subsequently exhumed from the mantle to the base of the crust at rates of 7 km/Myr. Ultrafast exhumation of the Dabie-Sulu UHP terrane from depth of 160 to 30 km was probably driven by buoyancy forces after UHP slab break-off at deep mantle depths.

  12. Zircon growth in shear zones

    NASA Astrophysics Data System (ADS)

    Kaulina, Tatiana

    2013-04-01

    The possibility of direct dating of the deformation process is critical for understanding of orogenic belts evolution. Establishing the age of deformation by isotopic methods is indispensable in the case of uneven deformation overlapping, when later deformation inherits the structural plan of the early strains, and to distinguish them on the basis of the structural data only is impossible. A good example of zircon from the shear zones is zircon formed under the eclogite facies conditions. On the one hand, the composition of zircon speaks about its formation simultaneously to eclogitic paragenesis (Rubatto, Herman, 1999; Rubatto et al., 2003). On the other hand, geological studies show that mineral reactions of eclogitization are often held only in areas of shear deformations, which provides access of fluid to the rocks (Austrheim, 1987; Jamtveit et al., 2000; Bingen et al., 2004). Zircons from mafic and ultramafic rocks of the Tanaelv and Kolvitsa belts (Kola Peninsula, the Baltic Shield) have showed that the metamorphic zircon growth is probably controlled by the metamorphic fluid regime, as evidenced by an increase of zircon quantity with the degree of shearing. The internal structure of zircon crystals can provide an evidence of zircon growth synchronous with shearing. The studied crystals have a sector zoning and often specific "patchy" zoning (Fig. 1), which speaks about rapid change of growth conditions. Such internal structure can be compared with the "snowball" garnet structure reflecting the rotation of crystals during their growth under a shift. Rapidly changing crystallization conditions can also be associated with a small amount of fluid, where supersaturation is changing even at a constant temperature. Thus, the growth of metamorphic zircon in shear zones is more likely to occur in the fluid flow synchronous with deformation. A distinctive feature of zircons in these conditions is isometric shape and sector "patchy" zoning. The work was supported by

  13. Insight into the geology of the East Antarctic hinterland: a study of sediment inclusions from ice cores of the Lake Vostok borehole

    USGS Publications Warehouse

    Leitchenkov, G.L.; Belyatsky, B.V.; Rodionov, N.V.; Sergeev, S.A.

    2007-01-01

    refrozen from the lake water. This ice layer contains random sediment inclusions, eight of which have been studied using state-of the-art analytical techniques. Six inclusions comprise soft aggregates consisting mainly of clay-mica minerals and micron-sized quartz grains while two others are solid clasts of fine-grained cemented rocks. The largest rock clast consists of poorly-rounded quartz and minor amounts of accessory minerals and is classified as quartzose siltstone. More than twenty grains of zircon and monazite have been identified in this siltstone and dated by SIMS SHRIMP-II. Two age clusters have been recognized for these detrital grains, in the ranges 0.8−1.2 Ga and 1.6−1.8 Ga. The compositions of the rock clasts suggest that the bedrock situated to the west of Lake Vostok is sedimentary. The age data on the detrital accessory minerals suggest that the provenance of these sedimentary rocks − the Gamburtsev Mountains and Vostok Subglacial Highlands, is mainly represented by Paleoproterozoic and MesoproterozoicNeoproterozoic crustal provinces

  14. U-Pb zircon age data for selected sedimentary, metasedimentary, and igneous rocks from northern and central Alaska

    USGS Publications Warehouse

    Moore, Thomas E.

    2014-01-01

    Data from two studies are included in this report. The first study, by Dumoulin and others (2013), reported the detrital zircon U-Pb age analysis of a single sample from the Upper Mississippian Ikalukrok unit of the Kuna Formation (table 1). The second study is that of Moore and others (in press), which focuses on the Upper Jurassic and Lower Cretaceous part of the Brookian sequence in the western Brooks Range (17 samples; table 2). For the latter study, samples were analyzed from the following units (1) the Upper Jurassic unit, Jw, of Curtis and others (1984), (2) the Lower Cretaceous Igrarok Hills unit of Moore and others (2002), (3) the Upper Jurassic and Lower Cretaceous Okpikruak Formation, (4) the Lower Cretaceous lower Brookian shale of Mull (1995), (5) the Lower Cretaceous Mount Kelly Graywacke Tongue of the Fortress Mountain Formation, (6) and the upper Lower Cretaceous Nanushuk Formation as redefined by Mull and others (2003). The results for each study are reported in separate Excel files, with individual samples in each study being shown as separate sheets within the files. The analyses of individual zircons are listed separately on the sheet according to the filtering schemes of the study and by the type of mass spectrometer used.

  15. Applications of detrital geochronology and thermochronology from glacial deposits to the Paleozoic and Mesozoic thermal history of the Ross Embayment, Antarctica

    NASA Astrophysics Data System (ADS)

    Welke, Bethany; Licht, Kathy; Hennessy, Andrea; Hemming, Sidney; Pierce Davis, Elizabeth; Kassab, Christine

    2016-07-01

    Till from moraines at the heads of six major outlet glaciers in the Transantarctic Mountains (TAM) and from till beneath three West Antarctic ice streams have a ubiquitous zircon U-Pb age population spanning the time of the Ross/Pan-African Orogenies (610-475 Ma). Geochronology and thermochronology of detrital minerals in these Antarctic glacial tills reveal two different thermal histories for the central and southern TAM. Double-dating of the zircons reveals a geographically widespread (U-Th)/He (ZHe) population of 180-130 Ma in most of the till samples. Sandstone outcrops at Shackleton Glacier, and three Beacon Supergroup sandstone clasts from three moraines, have ZHe ages that fall entirely within this range. The similar population and proximity of many of the till samples to Beacon outcrops lead us to suggest that this extensive ZHe population in the tills is derived from Beacon Supergroup rocks and reflects the thermal response of the Beacon Basin to the breakup of Gondwana. A second population of older (>200 Ma) ZHe ages in tills at the head of Byrd, Nimrod, and Reedy Glaciers. For the tills at the head of the Nimrod and Byrd Glaciers, integrating the double-dated zircon results with 40Ar/39Ar of hornblende, muscovite and biotite, and U-Pb and (U-Th-Sm)/He double-dates on apatite yields a typical pattern of early rapid orogenic cooling (˜4-10°C/Myr) 590-475 Ma after the emplacement of the Granite Harbour Intrusives. Low temperature thermochronometers at these sites yield variable but quite old ages (ZHe 480-70 Ma and AHe 200-70 Ma) that require a long history at low temperature.

  16. Sedimentary Provenance Constraints on the Middle Jurassic to Late Cretaceous Paleogeography of the Sichuan Basin, SW China

    NASA Astrophysics Data System (ADS)

    Li, Y.; He, D.; Li, D.; Lu, R.

    2017-12-01

    Sedimentary provenance of the Middle Jurassic to Late Cretaceous sediments in the Sichuan Basin is constrained by sandstone petrology and detrital zircon U-Pb geochronology, which provides critical insights into mid-late Mesozoic paleogeographic evolution of the Sichuan Basin. Petrographic analyses of 22 sandstone samples indicate moderate to high mature sediments and are primarily derived from cratonic or recycled sources. U-Pb age data for the Middle Jurassic to Late Cretaceous detrital zircons generally show populations at 130-200, 200-330, 400-490, 680-890, 1730-1960, and 2360-2600 Ma, with up-section variations. The Middle Jurassic sediments contain a relatively high density of 1.85 and 2.5 Ga zircons and a low density of the 800 Ma zircons, which are consistent with derivation mainly from the Songpan-Ganzi terrane and the South Qinling belt, and secondarily from the Western Jiangnan Orogen. The Late Jurassic and Early Cretaceous sedimentation with a scattered age distribution shared common multiple-source to sink systems that were predominantly draining towards the south and southeast, but increasingly drained southward, and were later disrupted by a synchronous northeastward drainage capture. Late Cretaceous sediments have a distinct reduction in <213 Ma zircons, suggesting that sedimentation involved southeastward and southwestward transport of sediments likely derived from the Songpan-Ganzi terrane, the south segment of the Longmenshan fault belt and western Yangtze Craton, and the uplifting areas of the N- and NE-Sichuan Basin. Changes in provenances during the mid-late Mesozoic period are coincident with temporal-spatial variations in depocenter migration and paleogeographic evolution of the Sichuan Basin, which are closely related to the multi-stage intracontinental subduction associated with clockwise rotation of the South China Block.

  17. U-Pb systematics in coexisting zircon, rutile and titanite from granophyres in the Archean Stillwater Complex: metamictization and the fate of radiogenic Pb

    NASA Astrophysics Data System (ADS)

    Friedman, R. M.; Wall, C. J.; Scoates, J. S.; Meurer, W. P.

    2009-12-01

    Self-irradiation of zircon causes structural damage (metamictization) that can result in the loss of radiogenic Pb during interaction with aqueous solutions. To evaluate this behavior in metamict zircon, and in other U-bearing accessory phases like titanite and rutile, we are examining the U-Pb systematics of granophyric rocks from the ca. 2.7 Ga Stillwater layered intrusion, Montana. Four samples were studied in detail, including a pegmatitic ksp-qtz core to a gabbroic pegmatoid in the Lower Banded Series (N1), an alaskite and an amphibole-rich reaction zone between the alaskite and anorthosite (AN1) in the Middle Banded Series, and an amphibole-bearing granophyre from the Upper Banded Series (GN3). Except in the pegmatite, zircon is variably metamict with amorphous zones characterized by distinctive Ca-enrichment. Single zircon grains were analyzed by ID-TIMS following annealing and chemical abrasion, and multi-grain (n=4-5) fractions of titanite and rutile were analyzed by conventional ID-TIMS; the UBC 233-235U-205Pb isotopic tracer is calibrated against mixed U-Pb gravimetric reference solutions made available through the EarthTime initiative. The U-Pb systematics are coherent only for the pegmatite yielding both a Concordia age of 2709.60 ± 0.80 Ma (2σ, including tracer calibration, decay-constant errors not included) for low-U zircon (76-237 ppm) and concordant titanite results with 207Pb/206Pb ages from 2701-2710 Ma. The results for high-U zircon (up to 1438 ppm) for the other three samples are strongly discordant (9-43%, 85-89%, 28-71%, respectively) with a wide range of 207Pb/206Pb ages (2583-2647 Ma, 2210-2357 Ma, 2345-2499 Ma). Given the extreme incompatibility of Pb2+ in zircon and the highly metamict state of zircon in these granophyres, we are investigating the extent to which radiogenic lead is selectively removed during the chemical abrasion and annealing process from step-wise leaching experiments and image analysis (CL, SEM). In contrast

  18. The effect of weathering on U-Th-Pb and oxygen isotope systems of ancient zircons from the Jack Hills, Western Australia

    NASA Astrophysics Data System (ADS)

    Pidgeon, R. T.; Nemchin, A. A.; Whitehouse, M. J.

    2017-01-01

    We report the result of a SIMS U-Th-Pb and O-OH study of 44 ancient zircons from the Jack Hills in Western Australia with ages ranging from 4.3 Ga to 3.3 Ga. We have investigated the behaviour of oxygen isotopes and water in the grains by determining δ18O and OH values at a number of locations on the polished surfaces of each grain. We have divided the zircons into five groups on the basis of their U-Th-Pb and OH-oxygen isotopic behaviour. The first group has concordant U-Th-Pb ages, minimal common Pb, δ18O values consistent with zircons derived from mantle source rocks and no detectable OH content. U-Th-Pb systems in zircons from Groups 2, 3 and 4 vary from concordant to extremely discordant where influenced by cracks. Discordia intercepts with concordia at approximately zero Ma age are interpreted as disturbance of the zircon U-Th-Pb systems by weathering solutions during the extensive, deep weathering that has affected the Archean Yilgarn Craton of Western Australia since at least the Permian. Weathering solutions entering cracks have resulted in an influx of Th and U. δ18O values of Group 2 grains fall approximately within the "mantle" range and OH is within background levels or slightly elevated. δ18O values of Group 3 grains are characterised by an initial trend of decreasing δ18O with increasing OH content. With further increase in OH this trend reverses and δ18O becomes heavier with increasing OH. Group 4 grains have a distinct trend of increasing δ18O with increasing OH. These trends are explained in terms of the reaction of percolating water with the metamict zircon structure and appear to be independent of analytical overlap with cracks. Group five zircons are characterised by U-Pb systems that appear to consist of more than one age but show only minor U-Pb discordance. Nevertheless trends in δ18O versus OH in this group of grains resemble trends seen in the other groups. The observed trends of δ18O with OH in the Jack Hills zircons are similar

  19. Detrital zircon U-Pb and (U-Th)/He double-dating of Upper Cretaceous-Cenozoic Zagros foreland basin strata in the Kurdistan Region of northern Iraq

    NASA Astrophysics Data System (ADS)

    Barber, D. E.; Stockli, D. F.; Koshnaw, R. I.; Horton, B. K.; Tamar-Agha, M. Y.; Kendall, J. J.

    2014-12-01

    The NW Zagros orogen is the result of the multistage collisional history associated with Late Cretaceous-Cenozoic convergence of the Arabian and Eurasian continents and final closure of Neotethys. Siliciclastic strata preserved within a ~400 km segment of the NW Zagros fold-thrust belt and foreland basin in the Iraqi Kurdistan Region (IKR) provide a widespread record of exhumation and sedimentation. As a means of assessing NW Zagros foreland basin evolution and chronostratigraphy, we present coupled detrital zircon (DZ) U-Pb and (U-Th)/He geo-thermochronometric data of Upper Cretaceous to Pliocene siliciclastic strata from the Duhok, Erbil, and Suleimaniyah provinces of IKR. LA-ICP-MS U-Pb age analyses reveal that the foreland basin fill in IKR in general was dominantly derived from Pan-African/Arabian-Nubian, Peri-Gondwandan, Eurasian, and Cretaceous volcanic arc terrenes. However, the provenance of these strata varies systematically along strike and through time, with an overall increase in complexity upsection. DZ age distribution of Paleocene-Eocene strata is dominated by a ~95 Ma grain age population, likely sourced from the Late Cretaceous Hassanbag-Bitlis volcanic arc complex along the northern margin of Arabia. In contrast, DZ U-Pb age distributions of Neogene strata show a major contribution derived from various Eurasian (e.g., Iranian, Tauride, Pontide; ~45, 150, 300 Ma) and Pan-African (~550, 950 Ma) sources. The introduction of Eurasian DZ ages at the Paleogene-Neogene transition likely records the onset of Arabian-Eurasian collision. Along strike to the southeast, the DZ U-Pb spectra of Neogene strata show a decreased percentage of Pan-African, Peri-Gondwandan, Tauride, and Ordovician ages, coupled with a dramatic increase in 40-50 Ma DZ ages that correspond to Urumieh-Dokhtar magmatic rocks in Iran. Combined with paleocurrent data, this suggests that Neogene sediments were transported longitudinally southeastward through an unbroken foreland basin

  20. Sediment unmixing using detrital geochronology

    USGS Publications Warehouse

    Sharman, Glenn R.; Johnstone, Samuel

    2017-01-01

    Sediment mixing within sediment routing systems can exert a strong influence on the preservation of provenance signals that yield insight into the influence of environmental forcings (e.g., tectonism, climate) on the earth’s surface. Here we discuss two approaches to unmixing detrital geochronologic data in an effort to characterize complex changes in the sedimentary record. First we summarize ‘top-down’ mixing, which has been successfully employed in the past to characterize the different fractions of prescribed source distributions (‘parents’) that characterize a derived sample or set of samples (‘daughters’). Second we propose the use of ‘bottom-up’ methods, previously used primarily for grain size distributions, to model parent distributions and the abundances of these parents within a set of daughters. We demonstrate the utility of both top-down and bottom-up approaches to unmixing detrital geochronologic data within a well-constrained sediment routing system in central California. Use of a variety of goodness-of-fit metrics in top-down modeling reveals the importance of considering the range of allowable mixtures over any single best-fit mixture calculation. Bottom-up modeling of 12 daughter samples from beaches and submarine canyons yields modeled parent distributions that are remarkably similar to those expected from the geologic context of the sediment-routing system. In general, mixture modeling has potential to supplement more widely applied approaches in comparing detrital geochronologic data by casting differences between samples as differing proportions of geologically meaningful end-member provenance categories.

  1. Sediment unmixing using detrital geochronology

    NASA Astrophysics Data System (ADS)

    Sharman, Glenn R.; Johnstone, Samuel A.

    2017-11-01

    Sediment mixing within sediment routing systems can exert a strong influence on the preservation of provenance signals that yield insight into the effect of environmental forcing (e.g., tectonism, climate) on the Earth's surface. Here, we discuss two approaches to unmixing detrital geochronologic data in an effort to characterize complex changes in the sedimentary record. First, we summarize 'top-down' mixing, which has been successfully employed in the past to characterize the different fractions of prescribed source distributions ('parents') that characterize a derived sample or set of samples ('daughters'). Second, we propose the use of 'bottom-up' methods, previously used primarily for grain size distributions, to model parent distributions and the abundances of these parents within a set of daughters. We demonstrate the utility of both top-down and bottom-up approaches to unmixing detrital geochronologic data within a well-constrained sediment routing system in central California. Use of a variety of goodness-of-fit metrics in top-down modeling reveals the importance of considering the range of allowable that is well mixed over any single best-fit mixture calculation. Bottom-up modeling of 12 daughter samples from beaches and submarine canyons yields modeled parent distributions that are remarkably similar to those expected from the geologic context of the sediment-routing system. In general, mixture modeling has the potential to supplement more widely applied approaches in comparing detrital geochronologic data by casting differences between samples as differing proportions of geologically meaningful end-member provenance categories.

  2. Ceramic with zircon coating

    NASA Technical Reports Server (NTRS)

    Wang, Hongyu (Inventor)

    2003-01-01

    An article comprises a silicon-containing substrate and a zircon coating. The article can comprise a silicon carbide/silicon (SiC/Si) substrate, a zircon (ZrSiO.sub.4) intermediate coating and an external environmental/thermal barrier coating.

  3. CONSTRAINTS ON EXHUMATION AND SEDIMENTS PROVENANCE DURING PALEOGENE IN THE NORTHERN PYRENEES (FRANCE) USING DETRITAL AFT, ZHe AND Z(U/Pb) THERMOCHRONOLOGY

    NASA Astrophysics Data System (ADS)

    Filleaudeau, P.; Mouthereau, F.; Fellin, M.; Pik, R.; Lacombe, O.

    2009-12-01

    The Pyrenees are a doubly vergent orogenic wedge built by the convergence between the subducting Iberian microplate and the European plate lasting from late Cretaceous to early Miocene. The backbone of the Pyrenean belt (Axial Zone) consists in a stack of thrusts units composed of Paleozoic series intruded by late-Variscan granitoids. Both pro- and retro-wedge sides of the Pyrenees are fold-and-thrust belts made of Meso-Cenozoic sediments thrusted onto the Ebro and Aquitaine foreland basins. The deep structure, highlighted by the ECORS profile, shows a strong asymmetry caused by the southward migration of deformation associated with the development of a Paleogene antiformal stack emplaced during wedge growth in the Iberian plate. The present study focuses on the synorogenic deposits of the retro-foreland basin in the northern part of the belt. To examine the source rocks and quantify the exhumation rates, we combine fission track thermochronometry on detrital apatites with Helium diffusion and U/Pb thermochronometry on zircons. Due to the very high closure temperature of the U/Pb system and the wide range of age distribution, the U/Pb method, that provides zircon crystallisation ages, is a powerful tool to distinguish the various eroded sources feeding the North Pyrenean basin. Thus, we can separate grains coming from Variscan intrusive basement with ages around 310 Ma from younger grains coming from Permian or Triassic to lower Jurassic volcanics. Zircon ages of 220 Ma found in the Paleocene sandstones point to the Triassic volcanic rocks (the so-called “ophites”) as the main source of detrital grains. We infer that Paleozoic units of the Axial Zone were not outcropping in the Paleocene catchments. Exhumation rates are estimated through apatite fission track grain-age distributions and (U-Th)/He dating for two Lutetian and Bartonian synorogenic sandstone samples of the North Pyenean foreland basin. The first results obtained with AFT dating show two main grain

  4. Magmatic tempo of Earth's youngest exposed plutons as revealed by detrital zircon U-Pb geochronology.

    PubMed

    Ito, Hisatoshi; Spencer, Christopher J; Danišík, Martin; Hoiland, Carl W

    2017-09-29

    Plutons are formed by protracted crystallization of magma bodies several kilometers deep within the crust. The temporal frequency (i.e. episodicity or 'tempo') of pluton formation is often poorly constrained as timescales of pluton formation are largely variable and may be difficult to resolve by traditional dating methods. The Hida Mountain Range of central Japan hosts the youngest exposed plutons on Earth and provides a unique opportunity to assess the temporal and spatial characteristics of pluton emplacement at high temporal resolution. Here we apply U-Pb geochronology to zircon from the Quaternary Kurobegawa Granite and Takidani Granodiorite in the Hida Mountain Range, and from modern river sediments whose fluvial catchments include these plutons in order to reconstruct their formation. The U-Pb data demonstrate that the Kurobegawa pluton experienced two magmatic pulses at ~2.3 Ma and ~0.9 Ma; whereas, to the south, the Takidani pluton experienced only one magmatic pulse at ~1.6 Ma. These data imply that each of these magmatic systems were both spatially and temporally distinct. The apparent ~0.7 Myr age gap between each of the three magmatic pulses potentially constrains the recharge duration of a single pluton within a larger arc plutonic complex.

  5. SHRIMP U-Pb evidence for a Late Silurian age of metasedimentary rocks in the Merrimack and Putnam-Nashoba terranes, eastern New England

    USGS Publications Warehouse

    Wintsch, R.P.; Aleinikoff, J.N.; Walsh, G.J.; Bothner, Wallace A.; Hussey, A.M.; Fanning, C.M.

    2007-01-01

    U-Pb ages of detrital, metamorphic, and magmatic zircon and metamorphic monazite and titanite provide evidence for the ages of deposition and metamorphism of metasedimentary rocks from the Merrimack and Putnam-Nashoba terranes of eastern New England. Rocks from these terranes are interpreted here as having been deposited in the middle Paleozoic above Neoproterozoic basement of the Gander terrane and juxtaposed by Late Paleozoic thrusting in thin, fault-bounded slices. The correlative Hebron and Berwick formations (Merrimack terrane) and Tatnic Hill Formation (Putnam-Nashoba terrane), contain detrital zircons with Mesoproterozoic, Ordovician, and Silurian age populations. On the basis of the age of the youngest detrital zircon population (???425 Ma), the Hebron, Berwick and Tatnic Hill formations are no older than Late Silurian (Wenlockian). The minimum deposition ages of the Hebron and Berwick are constrained by ages of cross-cutting plutons (414 ?? 3 and 418 ?? 2 Ma, respectively). The Tatnic Hill Formation must be older than the oldest metamorphic monazite and zircon (???407 Ma). Thus, all three of these units were deposited between ???425 and 418 Ma, probably in the Ludlovian. Age populations of detrital zircons suggest Laurentian and Ordovician arc provenance to the west. High grade metamorphism of the Tatnic Hill Formation soon after deposition probably requires that sedimentation and burial occurred in a fore-arc environment, whereas time-equivalent calcareous sediments of the Hebron and Berwick formations probably originated in a back-arc setting. In contrast to age data from the Berwick Formation, the Kittery Formation contains primarily Mesoproterozoic detrital zircons; only 2 younger grains were identified. The absence of a significant Ordovician population, in addition to paleocurrent directions from the east and structural data indicating thrusting, suggest that the Kittery was derived from peri-Gondwanan sources and deposited in the Fredericton Sea

  6. Tracing ancient events in the lithospheric mantle: A case study from ophiolitic chromitites of SW Turkey

    NASA Astrophysics Data System (ADS)

    Akbulut, Mehmet; González-Jiménez, José María; Griffin, William L.; Belousova, Elena; O'Reilly, Suzanne Y.; McGowan, Nicole; Pearson, Norman J.

    2016-04-01

    New major-, minor- and trace-element data on high-Cr chromites from several ophiolitic podiform chromitites from Lycian and Antalya peridotites in southwestern Turkey reveal a polygenetic origin from a range of arc-type melts within forearc and back-arc settings. These forearc and the back-arc related high-Cr chromitites are interpreted to reflect the tectonic juxtaposition of different lithospheric mantle segments during the obduction. The diversity of the γOs(t=0) values (-8.28 to +13.92) in the Antalya and Lycian chromitite PGMs and their good correlations with the sub- to supra-chondritic 187Os/188Os ratios (0.1175-0.1459) suggests a heterogeneous mantle source that incorporated up to 40% recycled crust, probably due to subduction processes of the orogenic events. The few model ages calculated define two significant peaks in TRD model ages at 1.5 and 0.25 Ga, suggesting that the chromitites are younger than 0.25 Ga and include relics of an at least Mesoproterozoic or older (>1.0 Ga) mantle protolith. Eight of the nine zircon grains separated from the chromitites, are interpreted as detrital and/or resorbed xenocrystic relics, whilst a significantly less reworked/resorbed one is considered to be of metasomatic origin. In-situ U-Pb dating of the xenocrystic zircon grains yielded a spread of ages within ca 0.6-2.1 Ga, suggesting recycling of crustal rocks younger than 0.6 Ga (Late Neoproterozoic). The notable coincidence between the lower age limit of the older zircons (ca 1.6 Ga) and the oldest Os model age peak (ca 1.5 Ga) from the PGM may suggest a Mesoproterozoic rifting stage. These findings imply a Paleoproterozoic sub-continental lithospheric mantle (SCLM) protolith for the SW Anatolian mantle which was later converted into an oceanic lithospheric mantle domain possibly following a rifting and continental break-up initiated during Mesoproterozoic (ca 1.5-1.0 Ga). The single metasomatic zircon of ca 0.09 Ga age coinciding with the initiation of the

  7. Context-specific effects of the identity of detrital mixtures on invertebrate communities

    PubMed Central

    Bishop, Melanie J; Kelaher, Brendan P

    2013-01-01

    Many aquatic ecosystems are sustained by detrital subsidies of leaf litter derived from exogenous sources. Although numerous studies have examined the effects of litter species richness and identity on decomposition processes, it remains unclear how these effects extend to associated invertebrate communities or how these effects vary spatially according to local environmental context. Using field enrichment experiments, we assessed how the species richness, assemblage composition, and supply of detrital litter resources interact to affect benthic communities of three temperate Australian estuarine mudflats. Our experiments utilized eight litter sources that are presently experiencing human-mediated changes in their supply to estuarine mudflats. Contrary to predictions, we did not detect effects of the species richness of detrital mixtures on benthic communities. Macroinvertebrate community structure and, in particular, abundance were, instead, influenced by the assemblage composition of detrital mixtures. At two of the three sites, plots receiving the most labile detrital mix, containing the ephemeral algae Chaetomorpha and Ulva, supported the fewest macroinvertebrates of all the experimental enrichments. The large effect of detrital mix identity on macroinvertebrate communities is of concern given present trends of proliferation of macroalgae at the expense of more refractory seagrasses and marsh grasses. As such environmental degradation continues, it will be important to more fully understand under what environmental contexts such compositional changes in detrital resources will have the most detrimental effects on important prey resources for commercially important fish and wading shorebirds. PMID:24198954

  8. Developing Zircon as a Probe of Planetary Impact History

    NASA Astrophysics Data System (ADS)

    Wielicki, Matthew

    2014-12-01

    the Hadean population remains difficult and this study hopes to develop criteria to recognize impact zircon and possibly provide constraints on the early impactor flux. Five large terrestrial craters, Vredefort and Morokweng, South Africa, Sudbury and Manicouagan, Canada, and Popigai, Russia, are the focus of this study as smaller craters do not have the energy to produce thick melt sheets, which persist over time-scales sufficient for crystallization of zircon, permitting geochemical and geochronological analysis. Geochemical analysis of these impact-produced zircons yields similar chemical signatures to endogenic igneous zircon from crustal melts and highlights the need for well-developed criteria for discriminating impact and endogenic grains for impact geochronology. One such criterion is modeling of impact zircon crystallization temperature spectra for simulated impact events on targets of varying composition. Provided some assumptions the zircon crystallization spectra can be estimated from well established Zr systematics in crustal melts. Results for impacts into an Archean terrestrial surface (used as a proxy for the Hadean as little to no rock record exists >4.0 Ga) yields a crystallization spectra significantly higher than that reported for the Hadean zircon population and appears to rule out impacts as a dominant source for these ancient grains. When no dateable impact melt sheet exists, either due to the lack of energy of the impact itself or from subsequent erosion at Earth's surface, loss of radiogenic lead, Pb*, has been suggested as an alternative method to date the event. Pb*-loss was investigated from target rocks from Vredefort and Morokweng and suggests that Pb* diffusion, even in zircon isolated from shocked and brecciated target rocks, is remarkably slow. This may explain the seeming lack of 'reset' zircon in terrestrial impactites. Little is known about Pb* diffusion pathways associated with shock microstructures introduced during impact

  9. Detrital carbon pools in temperate forests: magnitude and potential for landscape-scale assessment

    Treesearch

    John B. Bradford; Peter Weishampel; Marie-Louise Smith; Randall Kolka; Richard A. Birdsey; Scott V. Ollinger; Michael G. Ryan

    2009-01-01

    Reliably estimating carbon storage and cycling in detrital biomass is an obstacle to carbon accounting. We examined carbon pools and fluxes in three small temperate forest landscapes to assess the magnitude of carbon stored in detrital biomass and determine whether detrital carbon storage is related to stand structural properties (leaf area, aboveground biomass,...

  10. Geology, Petrology and O and H isotope geochemistry of remarkably 18O depleted Paleoproterozoic rocks of the Belomorian Belt, Karelia, Russia, attributed to global glaciation 2.4 Ga

    NASA Astrophysics Data System (ADS)

    Bindeman, I. N.; Serebryakov, N. S.

    2011-06-01

    This paper deals with strongly 18O-depleted (down to - 27.3‰ VSMOW) 1.9Ga Paleoproterozoic mid-grade metamorphic rocks found in the Belomorian Belt of Karelia (E. Baltic Shield). The protolith of these rocks is attributed to have been altered by glacial meltwaters during the world's first 2.4-2.3 Ga Paleoproterozoic "Slushball" glaciation, when Karelia was located near equatorial latitudes. We describe in detail three and report seven new localities with unusually depleted 18O signatures that now span 220 km across the Belomorian Belt. Hydrogen isotope ratios measured in amphibole, biotite and staurolite also display remarkably low values of - 212 to - 235‰. Isotope mapping in the three best exposed localities has allowed us to identify the world's most 18O depleted rock, located at Khitostrov with a δ 18O value - 27‰. In Khitostrov samples, zircons have normal δ 18O detrital cores and low-δ 18O metamorphic rims. Mapping demonstrates that zones of δ 18O depletion occur in a concentric pattern 100-400 m in dimension, and each locality displays significant δ 18O and δD heterogeneity on a meter to centimeter scale, characteristic of meteoric-hydrothermal systems worldwide. The zone of maximum δ 18O depletions usually has the highest concentration of metamorphic corundum, rutile, and zircon and also display doubled concentrations of insoluble trace elements (Zr, Ti, Cr, HREE). These results are explained by elemental enrichment upon mass loss during hydrothermal dissolution in pH-neutral meteoric fluid. Remarkably low-δ 18O and δD values suggest that alteration could have only happened by glacial meltwaters in a subglacial rift zone. Many localities with δ 18O depletions occur inside metamorphozed 2.4 Ga gabbro-noritic intrusions, or near their contact with Belomorian gneisses, implying that the intrusions were driving meteoric hydrothermal systems during the known 2.4 Ga episode of Belomorian rifting. Given that the isotopically-depleted localities now

  11. Characteristics of zircon suitable for REE extraction

    NASA Astrophysics Data System (ADS)

    Watanabe, Y.; Hoshino, M.

    2011-12-01

    Zircons (ZrSiO4) from Naegi and Ohro granitic pegmatites, Japan and from Saigon alkaline basalt, Vietnam, were mineralogically characterized by inductively couples plasma mass spectrometry (ICP-MS), electron-microprobe analysis (EMPA), X-ray powder diffraction, micro-Raman spectroscopy and leaching experiment. The powder XRD and Raman spectra analyses show that the degree of crystallinity decreases from Saigon, to Ohro and Naegi zircons. Quantitative analytical results by the EMPA indicate that the Naegi and Ohro zircon samples contain a large amount of REE2O3, while REE contents in Saigon zircon are below detection limit. The leaching experiments for the present zircons under the condition of a solvent 1M-HCl, at a room temperature to 250 °C and retention time of 30h resulted in about 100 %, 50 % and 1 % recoveries of REE from the Naegi, Ohro and Saigon zircons, respectively. Leaching experiments for the Naegi zircon under the condition of a solvent 1N-HCl, heating temperature of 50 °C, 100 °C, 150 °C and 200 °C, and retention time 30h, showed that a significant amount of REE was leached out at a temperature above 150 °C. However, the leaching experiments of the Naegi and Ohro zircons at room temperature (about 25 °C) show that REE were hard to be leached. These results indicates that both low crystallinity of zircon and higher leaching temperature are requisite for effective leaching of REE from zircon.

  12. Geochemistry and isotopic signatures of Paleogene plutonic and detrital rocks of the Northern Andes of Colombia: A record of post-collisional arc magmatism

    NASA Astrophysics Data System (ADS)

    Bustamante, Camilo; Cardona, Agustín; Archanjo, Carlos J.; Bayona, Germán; Lara, Mario; Valencia, Victor

    2017-04-01

    Between the Late Cretaceous and Paleogene, the Northern Andes experienced subduction and collision due to the convergence between the oceanic Caribbean Plate and the continental margin of Ecuador and Colombia. Subduction-related calc-alkaline plutonic rocks form stocks of limited areal expression or local batholiths that consist mostly of diorites and granodiorites. We investigated two stocks (Hatillo and Bosque) exposed in the Central Cordillera of Colombia that had U-Pb zircon crystallization ages between 60 and 53 Ma. Relatively low radiogenic Sr, Nd and Pb isotopes from selected samples account for a heterogeneous crustal source, whereas negative anomalies of Nb and Ti, high LREE/HREE and Sr/Y > 28 ratios indicate that the magmas were emplaced in a continental magmatic arc setting. ƐHf(i) values of the dated zircons were between - 4 and + 7 and suggest some contamination of the magmas during their ascent through the crust. The high Sr/Y ratios recorded both in the investigated plutons as well as in other Paleogene plutons in the Central Cordillera suggest that the magmas differentiate in high-pressure conditions (garnet stability field). This differentiation probably occurred at the base of a thickened crust through the Mesozoic subduction and accretion of oceanic arcs to the continental margin during the Lower Cretaceous and Paleocene. The existence of other Paleogene granitoids with evidence of shallower differentiation signatures may be also an inheritance of along strike variations in the Northern Andean continental crust due to Cretaceous to Paleogene oblique convergence. The Hf isotope results from Paleogene detrital zircons from volcanoclastic rocks of the eastern Colombian basins reinforce the possibility of a distal magmatic focus.

  13. Zircon U-Pb age of the Pescadero felsite: A late Cretaceous igneous event in the forearc, west-central California Coast Ranges

    USGS Publications Warehouse

    Ernst, W.G.; Martens, U.C.; McLaughlin, R.J.; Clark, J.C.; Moore, Diane E.

    2011-01-01

    Weathered felsite is associated with the late Campanian-Maastrichtian Pigeon Point Formation near Pescadero, California. Poorly exposed, its age and correlation are uncertain. Is it part of the Pigeon Point section west of the San Gregorio-Hosgri fault? Does it rest on Nacimiento block basement? Is it dextrally offset from the Oligocene Cambria Felsite, ~185 km to the southeast? Why is a calc-alkaline hypabyssal igneous rock intrusive into the outboard accretionary prism? To address these questions, we analyzed 43 oscillatory-zoned zircon crystals from three incipiently recrystallized pumpellyite ?? prehnite ?? laumontite-bearing Pescadero felsite samples by sensitive high-resolution ion microprobe-reverse geometry (SHRIMPRG) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) techniques. Thirty-three zircons gave late Mesozoic U-Pb ages, with single-grain values ranging from 81 to 167 Ma; ten have pre-Mesozoic, chiefl y Proterozoic ages. A group of the four youngest Pescadero zircons yielded an apparent maximum igneous age of ca. 86-90 Ma. Refl ecting broad age scatter and presence of partly digested sandstone inclusions, we interpret the rest of the zircons (perhaps all) as xenocrysts. Twenty-three zircons were separated and analyzed from two samples of the similar Cambria Felsite, yielding a unimodal 27 Ma U-Pb age. Clearly, the origin of the Upper Oligocene Cambria Felsite is different from that of the Upper Cretaceous Pescadero felsite; these rocks are not correlated, and do not constrain displacement along the San Gregorio-Hosgri fault. Peak ages differ slightly, but relative probability curves for Mesozoic and pre-Mesozoic Pescadero zircons compare well, for example, with abundant U-Pb age data for detrital zircons from Franciscan metaclastic strata ~100 km to the east in the Diablo Range- San Francisco Bay area, San Joaquin Great Valley Group turbidites, Upper Cretaceous Nacimiento block Franciscan strata, and Upper Cretaceous

  14. A Modern Analog to the Depositional Age Problem: Zircon and Apatite Fission Track and U-Pb Age Distributions by LA-ICP-MS

    NASA Astrophysics Data System (ADS)

    Donelick, H. M.; Donelick, M. B.; Donelick, R. A.

    2012-12-01

    Sand from three river systems in North Idaho (Snake River near Lewiston, Clearwater River near Lewiston and the Salmon River near White Bird) and two regional ash fall events (Mt. Mazama and Mt. St. Helens) were collected for zircon U-Pb detrital age analysis. Up to 120 grains of zircon per sample were ablated using a Resonetics M-50 193 nm ArF Excimer laser ablation (LA) system and the Pb, Th, and U isotopic signals were quantified using an Agilent 7700x quadrupole inductively coupled plasma-mass spectrometer (ICP-MS). Isotopic signals for major, minor, and trace elements, including all REEs, were also monitored. The youngest zircon U-Pb ages from the river samples were approximately 44 Ma; Cenozoic Idaho Batholith and Precambrian Belt Supergroup ages were well represented. Significant common Pb contamination of the Clearwater River sample (e.g., placer native Cu was observed in the sample) precluded detailed analysis of the zircon U-Pb ages but no interpretable ages <44 Ma were observed. Interestingly, not one of the river samples yielded zircon U-Pb ages near 0 Ma, despite all three catchment areas having received significant ash from Mt. St. Helens in 1980, and Mount Mazama 7,700 years ago, and no doubt other events during the Quaternary. Work currently in progress seeks to address bias against near 0 Ma ages in the catchment areas due to: a) small, local ash fall grain sizes and b) overwhelming number of older grains relative to the ash fall grains. Data from Mt. St. Helens ash from several localities near the mountain (Toutle River and Maple Flats, WA) and several far from the mountain (Spokane, WA; Princeton, ID; Kalispell, MT) and Mt. Mazama ash fall deposits near Lewiston, ID and Spokane, WA will be presented to address these possibilities. Additionally, fission track and U-Pb ages from apatites collected from these river and ash fall samples will also be shown to help constrain the problem.

  15. Evidence of extinct 244Pu in ancient terrestrial zircons

    NASA Astrophysics Data System (ADS)

    Harrison, T. M.; Turner, G.; Holland, G.; Gilmour, J. D.; Mojzsis, S. J.

    2003-04-01

    could result from loss of Xe after 4.0 Ga or represent U-Pu fractionation. We are currently repeating the exercise with older zircons and intend to search for correlations with REE patterns, oxygen isotopes, and the degree of U-Pb concordance, and to investigate the thermal release characteristics of the xenon. In addition to constraining the terrestrial Pu/U ratio these investigations may allow us to characterise the geochemical behaviour of Pu as a constraint on the earliest crust forming processes.

  16. Zircon U-Pb dating, Hf analysis from the Horoman perdiotite -age constraint for lithospheric process, and tectonic juxtaposition of collision root zone-

    NASA Astrophysics Data System (ADS)

    Okamoto, K.; Yi, K.; Wang, K. L.; Chung, S. L.

    2017-12-01

    Hidaka metamorphic belt, Hokkaido, Japan is known as youngest arc-arc collision in the world. It ncludes the youngest granulite and the Horoman peridotite complex in the highest grade zone. Age of these rocks have been determined by various methods (K-Ar, U-Pb, Rb-Sr). However, the age of Horoman peridotite complex has not been determined yet. Only Yoshikawa et al 1993) reported the cooling age of the complex as 23 Ma according to whole rock Rb-Sr isochron. This study has performed U-Pb dating of zircons from the Horoman peridotite, and from the paragneiss surrounding the peridotite complex in order to determine the intrusive age of the Horoman peridotite complex into the lower crustal conditions. Several zircon grains were separated from the peridotite. All zircons are homogeneous exhibiting different age group; 267-278 Ma, 33-40 Ma and 18-20 Ma. Hf isotope analysis indicates that the 267-278 Ma is juvenile age and other two are recycled. As a result of this measurement, rims of the zircons from the gneisses show that 238U-206Pb ages are 20 Ma and detrital cores are ranging from 580-510 Ma, 60-50 Ma, 46-40 Ma and 27 Ma. The rim ages are from the gneiss suffered amphibolite facies and granulite faices, and there is a consistancy with zircon rim ages (19 Ma) from the granulite (Kemp et al 2007, Usuki et al 2006 and so on). That is, granulite faices metamorphism was coeval to regional metamorphism in the lower crust at 20 Ma. The zircon ages from the peridotite was probably related to local hydration related to precipitation of phlogopite at 20 Ma, I type magma infiltration at 40 Ma and lithosphere formation at 270 Ma. It is considered that the Horoman peridotite complex was part of the lithosphere at 270 Ma, and the joined as subarc mantle prior to I type magma activity at 40 Ma, aud suffered local hydration and regional metamorphism at 20 Ma. Ref. Kemp, A.I.S., et al., 2007, Geology, 35, 807-810; Usuki, T. et al, 2006, Island Arc, 14, 503-516.

  17. Early Pan-African evolution of the basement around Elat, Israel, and the Sinai Peninsula revealed by single-zircon evaporation dating, and implications for crustal accretion rates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kroener, A.; Eyal, M.; Eyal, Y.

    1990-06-01

    The authors report {sup 207}Pb/{sup 206}Pb single-zircon evaporation ages for early Pan-African rocks from southern Israel and the northeastern Sinai Peninsula, the northernmost extension of the Arabian-Nubian shield. The oldest rocks are metamorphic schists of presumed island-arc derivation; detrital zircons date the source terrain at ca. 800-820 Ma. A major phase of tonalite-trondhjemite plutonism occurred at ca. 760-780 Ma; more evolved granitic rocks were emplaced at about 745 Ma. A metagabbro-metadiorite complex reflects the youngest igneous phase at ca. 640 Ma. We find no evidence for pre-Pan-African crust, and our data document important crust-forming events that correlate with similar episodesmore » elsewhere in the shield. The widespread presence of early Pan-African juvenile rocks (i.e., ca. 760-850 Ma) in many parts of the Arabian-Nubian shield makes this period the most important in the magmatic history of the shield and supports earlier suggestions for unusually high crust-production rates.« less

  18. SHRIMP U–Pb and REE data pertaining to the origins of xenotime in Belt Supergroup rocks: evidence for ages of deposition, hydrothermal alteration, and metamorphism

    USGS Publications Warehouse

    Aleinikoff, John N.; Lund, Karen; Fanning, C. Mark

    2015-01-01

    derivation. A previous study on the Revett Formation at the Spar Lake Ag–Cu deposit provides data for xenotime overgrowths in several ore zones formed by hydrothermal processes; herein, those results are compared with data from newly analyzed diagenetic, metamorphic, and magmatic xenotime overgrowths. The origin of a xenotime overgrowth is reflected in its rareearth element (REE) pattern. Detrital (i.e., igneous) xenotime has a large negative Eu anomaly and is heavy rare-earth element (HREE)-enriched (similar to REE in igneous zircon). Diagenetic xenotime has a small negative Eu anomaly and flat HREE (Tb to Lu). Hydrothermal xenotime is depleted in light rare-earth element (LREE), has a small negative Eu anomaly, and decreasing HREE. Metamorphic xenotime is very LREE-depleted, has a very small negative Eu anomaly, and is strongly depleted in HREE (from Gd to Lu). Because these characteristics seem to be process related, they may be useful for interpretation of xenotime of unknown origin. The occurrence of 1.16–1.05 Ga metamorphic xenotime, in the apparent absence of pervasive deformation structures, suggests that the heating may be related to poorly understood regional heating due to broad regional underplating of mafic magma. These results may be additional evidence (together with published ages from metamorphic titanite, zircon, monazite, and garnet) for an enigmatic, Grenville-age metamorphic event that is more widely recognized in the southwestern and eastern United States

  19. Zircon (U-Th)/He Thermochronometric Constraints on Himalayan Thrust Belt Exhumation, Bedrock Weathering, and Cenozoic Seawater Chemistry

    NASA Astrophysics Data System (ADS)

    Colleps, Cody L.; McKenzie, N. Ryan; Stockli, Daniel F.; Hughes, Nigel C.; Singh, Birendra P.; Webb, A. Alexander G.; Myrow, Paul M.; Planavsky, Noah J.; Horton, Brian K.

    2018-01-01

    Shifts in global seawater 187Os/188Os and 87Sr/86Sr are often utilized as proxies to track global weathering processes responsible for CO2 fluctuations in Earth history, particularly climatic cooling during the Cenozoic. It has been proposed, however, that these isotopic records instead reflect the weathering of chemically distinctive Himalayan lithologies exposed at the surface. We present new zircon (U-Th)/He thermochronometric and detrital zircon U-Pb geochronologic evidence from the Himalaya of northwest India to explore these contrasting interpretations concerning the driving mechanisms responsible for these seawater records. Our data demonstrate in-sequence southward thrust propagation with rapid exhumation of Lesser Himalayan strata enriched in labile 187Os and relatively less in radiogenic 87Sr at ˜16 Ma, which directly corresponds with coeval shifts in seawater 187Os/188Os and 87Sr/86Sr. Results presented here provide substantial evidence that the onset of exhumation of 187Os-enriched Lesser Himalayan strata could have significantly impacted the marine 187Os/188Os record at 16 Ma. These results support the hypothesis that regional weathering of isotopically unique source rocks can drive seawater records independently from shifts in global-scale weathering rates, hindering the utility of these records as reliable proxies to track global weathering processes and climate in deep geologic time.

  20. Cosmogenic 3He in detrital gold

    NASA Astrophysics Data System (ADS)

    Stuart, Finlay; Yakubovich, Olga; Caracedo, Ana; Nesterenok, Alexander

    2017-04-01

    Since the measurement of cosmogenic He in an alluvial diamond by McConville and Reynolds (1996) the application of cosmogenic noble gases to individual detrital grains to quantify surface processes has not been vigorously pursued. The likely low rate of diffusion of cosmogenic He in native metals, and their resistance to weathering and disintegration during erosion and transport, makes them a potential record of long-term Earth surface processes. In an effort to assess the extent that detrital refractory metals record the exposure history during transport and storage we have undertaken a reconnaissance study of the He isotope composition in 18 grains (2-200 mg) of native gold, copper, silver, and PtPd, Pt3Fe and OsIr alloys from alluvial placer deposits from around the world. 4He is dominantly the result of U and Th decay within the grains, or decay of 190Pt in the Pt-rich alloys. 3He is measurable in 13 grains, concentrations range up to 2.7E+6 atoms/g. 3He/4He are always in excess of the crustal radiogenic ratio, up to 306 Ra. Although nucleogenic 3He produced by (n,α) reactions on 6Li, and 3He from trapped hydrothermal fluids, are present, the majority of the 3He is cosmogenic in origin. Using newly calculated cosmogenic 3He production rates in heavy metals, and a determination of the effect of implantation based on the stopping distances of spallogenic 3He and 3H, the grains have 3Hecos concentrations that are equivalent to 0.35 to 1.5 Ma exposure at Earth's surface. In a study of detrital gold grains from several sites in Scotland we have found that 10 % have 3He concentrations that are significantly in excess of that generated since the Last Glacial Maximum. These studies demonstrate that, with refinement, cosmogenic 3He in refractory detrital minerals can be used to quantify sediment transport and storage on the 1-10 Ma timescale. P. McConville & J.H. Reynolds (1989). Geochim. Cosmochim. Acta, 53, 2365-75.

  1. Provenance of Marine Sediment in the Gulf of Alaska, IODP Expedition 341: Links Between Sediment Derivation, Glacial Systems, and Exhumation of the Coastal Mountain Belts

    NASA Astrophysics Data System (ADS)

    Allen, W. K.; Dunn, C. A.; Enkelmann, E.; Ridgway, K.; Colliver, L.

    2015-12-01

    Provenance analysis of Neogene sand and diamict beds from marine boreholes drilled by the IODP Expedition 341 provides a marine sedimentary record of the interactions between tectonics, climate and sediment deposition along a glaciated convergent margin. The 341 boreholes represent a cross-margin transect that sampled the continental shelf, slope, and deep sea Surveyor Fan of the Gulf of Alaska. Our dataset currently consists of ~ 650 detrital zircons selected for double dating method utilizing both detrital zircon fission track (FT) and U-Pb analysis from sand and diamict beds, as well as zircon U-Pb geochronology and apatite FT from igneous and gneissic clasts. Detrital zircon U-Pb geochronology of sand records dominant peak ages of 53, 62, 70, and 98 Ma with minor populations of 117, 154, and 170 Ma. Most of these ages can be correlated to primary igneous sources in the Coast Plutonic Complex, the Chugach Metamorphic Complex, the plutonic rocks of Wrangellia, and the Sanak-Baranoff plutonic belt. All samples analyzed to date, covering a 10 Myr range, share nearly identical detrital zircon populations suggesting similar primary sediment sources and reworking of sediment in thrust belts and accretionary prisms along this convergent margin. Plutonic and gneissic clasts collected from the boreholes on the shelf have already been double dated. These clasts have general U-Pb zircon crystallization ages of 52-54 Ma and apatite fission track cooling ages of 10-12 Ma. These results, along with previous published studies, indicate that these clasts were derived from the Chugach Metamorphic Complex and were eroded and transported by the Bagley Ice Field and Bering Glacier. Future results using this approach should allow us to pinpoint which parts of the exhumed onshore ranges and which glacial systems provided sediment to marine environments in the Gulf of Alaska.

  2. Mid to late Devonian back-arc rift basins in the Brooks Range, AK, and across the Arctic: a possible paleogeographic piercing point for Arctic reconstructions

    NASA Astrophysics Data System (ADS)

    Hoiland, C. W.; Miller, E. L.; Hourigan, J. K.

    2013-12-01

    The westernmost Brooks Range, Alaska, is underlain by basement of probable Baltic or Timanian affinity (e.g. Miller et al., 2011; Amato et al., 2009), while the eastern Brooks Range is underlain by Laurentian affinity basement (e.g. Strauss et al., 2013). A post-Timanian and pre-Mississippian suture or contact is thus required based on continuity of late Devonian and younger strata across the Brooks Range (e.g. Dumoulin et al., 2002). This inferred juxtaposition has been proposed as the distal and diachronous (though possibly non-collisional) continuation of the Caledonian orogen (e.g. Moore et al., 2012) but the actual location and character of this suture within basement rocks of the Brooks Range remain speculative. New laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb single grain detrital zircon (DZ) geochronology of basement rocks from the Cosmos Hills, Slate Creek, and Wiseman regions suggest that metamorphic rocks in these regions are Devonian, not pre-Devonian. New SHRIMP-RG analyses of the Kogoluktuk orthogneiss (Cosmos) (zircon: 383 Ma × 5 Ma, 2-sigma errors, consistent with Dillon et al. 1980) revealed no inherited cores from which to infer basement affinity. DZ spectra from metasedimentary and metavolcanic wall rock contain youngest detrital zircon populations with ages (390 Ma) just barely older than the cross-cutting intrusive age, providing tight bracketing of depositional age. These zircon ages are noticeably younger than Caledonian magmatic ages (430-420 Ma) suggesting deposition in a volcanically and tectonically active setting (likely extensional) as originally suggested by Hitzman et al (1986). Zircon spectra (Cosmos) contain notable amounts of "Timanian" age zircons (c. 700-550 Ma), and a spread of zircons from 1-2 Ga (including 1.5-1.6 Ga ages of the Laurentian "magmatic gap', e.g. Grove et al. 2008) more typical of derivation from Baltic rather than Laurentian sources. East in the Wiseman and Slate Creek localities

  3. Age and source of terrigenous rocks of the turan group of the bureya terrane of the eastern part of the central Asian foldbelt: Results of geochemical (Sm-Nd) and geochronological (U-Pb LA-ICP-MS) studies

    NASA Astrophysics Data System (ADS)

    Sorokin, A. A.; Smirnov, Yu. V.; Kotov, A. B.; Kovach, V. P.

    2014-06-01

    According to Sm-Nd isotopic-geochemical studies, the t Nd(DM) of the terrigenous rocks of the Turan Group of the Bureya terrane is 1.4-1.5 Ga and their sources are Precambrian rocks and (or) younger effusive rocks, the formation of which is related to the reworking of the Late Precambrian continental crust. The U-Pb LA-ICP-MS geochronological studies indicate dominant Vendian-Cambrian (588-483 Ma) and Late Riphean (865-737 Ma) detrital zircons. Our data point to their accumulation at the beginning of the Paleozoic rather than in the Precambrian as is accepted in modern stratigraphic schemes.

  4. Steady State Growth of Continental Crust?

    NASA Astrophysics Data System (ADS)

    Bowring, S. A.; Bauer, A.; Dudas, F. O.; Schoene, B.; McLean, N. M.

    2012-12-01

    More than twenty years since the publication of Armstrong's seminal paper, debate still rages about most aspects of the Earth's first billion years. Although orders of magnitude more data have been generated since then, the arguments remain the same. The debate is largely centered on the isotopic systematics of minerals and whole rocks, the major and trace element geochemistry of continental crust, and various geodynamic models for differentiation of the planet. Most agree that earth, like all the terrestrial planets, differentiated into a crust, mantle and core very early in its history. After that, models of crustal evolution diverge significantly, including the suggestions that modern style plate tectonics did not originate until ca. 2.7 Ga or younger and that plumes have played a major role in the generation of continental crust. Many believe that the preserved rock record and the detrital zircon record are consistent with episodic crustal growth, which in turn has led to geodynamic models of episodic mantle convection driving major crust forming events. High-precision and high-throughput geochronology have led to claims of episodicity even more pronounced than that presented in Gastil's 1960 paper. We believe that Earth history has been dominated by plate tectonics and that continental crust is formed largely by amalgamation of island arcs, seamounts, micro continents, and oceanic plateaus. While there are geochemical differences in the average composition of Archean igneous rocks when compared to younger rocks, the processes responsible for their formation may not have changed a great deal. In this view, the so-called crustal growth curves originated by Hurley are in fact crude approximations of crustal preservation. The most highly cited rationales for the view that little silicic crust formed during Earth's first billion years are the lack of known exposed crust older than 3.5 Ga and the paucity of detrital zircons older than 4.0 Ga in sedimentary rocks of

  5. Hydrogen diffusion in Zircon

    NASA Astrophysics Data System (ADS)

    Ingrin, Jannick; Zhang, Peipei

    2016-04-01

    Hydrogen mobility in gem quality zircon single crystals from Madagascar was investigated through H-D exchange experiments. Thin slices were annealed in a horizontal furnace flushed with a gas mixture of Ar/D2(10%) under ambient pressure between 900 ° C to 1150 ° C. FTIR analyses were performed on oriented slices before and after each annealing run. H diffusion along [100] and [010] follow the same diffusion law D = D0exp[-E /RT], with log D0 = 2.24 ± 1.57 (in m2/s) and E = 374 ± 39 kJ/mol. H diffusion along [001] follows a slightly more rapid diffusion law, with log D0 = 1.11 ± 0.22 (in m2/s) and E = 334 ± 49 kJ/mol. H diffusion in zircon has much higher activation energy and slower diffusivity than other NAMs below 1150 ° C even iron-poor garnets which are known to be among the slowest (Blanchard and Ingrin, 2004; Kurka et al. 2005). During H-D exchange zircon incorporates also deuterium. This hydration reaction involves uranium reduction as it is shown from the exchange of U5+ and U4+ characteristic bands in the near infrared region during annealing. It is the first time that a hydration reaction U5+ + OH- = U4+ + O2- + 1/2H2, is experimentally reported. The kinetics of deuterium incorporation is slightly slower than hydrogen diffusion, suggesting that the reaction is limited by hydrogen mobility. Hydrogen isotopic memory of zircon is higher than other NAMs. Zircons will be moderately retentive of H signatures at mid-crustal metamorphic temperatures. At 500 ° C, a zircon with a radius of 300 μm would retain its H isotopic signature over more than a million years. However, a zircon is unable to retain this information for geologically significant times under high-grade metamorphism unless the grain size is large enough. Refrences Blanchard, M. and Ingrin, J. (2004) Hydrogen diffusion in Dora Maira pyrope. Physics and Chemistry of Minerals, 31, 593-605. Kurka, A., Blanchard, M. and Ingrin, J. (2005) Kinetics of hydrogen extraction and deuteration in

  6. Zircon-scale insights into the history of a Supervolcano, Bishop Tuff, Long Valley, California, with implications for the Ti-in-zircon geothermometer

    USGS Publications Warehouse

    Reid, M.R.; Vazquez, J.A.; Schmitt, A.K.

    2011-01-01

    Zircon has the outstanding capacity to record chronological, thermal, and chemical information, including the storage history of zoned silicic magma reservoirs like the one responsible for the Bishop Tuff of eastern California, USA. Our novel ion microprobe approach reveals that Bishop zircon rims with diverse chemical characteristics surround intermediate domains with broadly similar compositions. The highest Y, REE, U, and Th concentrations tend to accompany the largest excesses in Y + REE3+:P beyond what can be explained by xenotime substitution in zircon. Apparent Ti-in-zircon temperatures of <720??C for zircon rims are distinctly lower than most of the range in eruption temperatures, as estimated from FeTi-oxide equilibria and zircon solubility at quench. While permissive of crystallization of zircon at near-solidus conditions, the low Ti-in-zircon temperatures are probably better explained by sources of inaccuracy in the temperature estimates. After apparently nucleating from different melts, zircons from across the Bishop Tuff compositional spectrum may have evolved to broadly similar chemical and thermal conditions and therefore it is possible that there was no significant thermal gradient in the magma reservoir at some stage in its evolution. There is also no compelling evidence for punctuated heat ?? chemical influxes during the intermediate stages of zircon growth. Judging by the zircon record, the main volume of the erupted magma evolved normally by secular cooling but the latest erupted portion is characterized by a reversal in chemistry that appears to indicate perfusion of the magma reservoir by-or zircon entrainment in-a less evolved melt from the one in which the zircons had previously resided. ?? 2010 Springer-Verlag.

  7. Etching fission tracks in zircons

    USGS Publications Warehouse

    Naeser, C.W.

    1969-01-01

    A new technique has been developed whereby fission tracks can be etched in zircon with a solution of sodium hydroxide at 220??C. Etching time varied between 15 minutes and 5 hours. Colored zircon required less etching time than the colorless varieties.

  8. Formation of Hadean granites by melting of igneous crust

    NASA Astrophysics Data System (ADS)

    Burnham, A. D.; Berry, A. J.

    2017-06-01

    The oldest known samples of Earth, with ages of up to 4.4 Gyr, are detrital zircon grains in meta-sedimentary rocks of the Jack Hills in Australia. These zircons offer insights into the magmas from which they crystallized, and, by implication, igneous activity and tectonics in the first 500 million years of Earth’s history, the Hadean eon. However, the compositions of these magmas and the relative contributions of igneous and sedimentary components to their sources have not yet been resolved. Here we compare the trace element concentrations of the Jack Hills zircons to those of zircons from the locality where igneous (I-) and sedimentary (S-) type granites were first distinguished. We show that the Hadean zircons crystallized predominantly from I-type magmas formed by melting of a reduced, garnet-bearing igneous crust. Further, we propose that both the phosphorus content of zircon and the ratio of phosphorus to rare earth elements can be used to distinguish between detrital zircon grains from I- and S-type sources. These elemental discriminants provide a new geochemical tool to assess the relative contributions of primeval magmatism and melting of recycled sediments to the continents over geological time.

  9. Using zircon (U-Th)/He damage-diffusivity patterns to quantify detachment-related basement exhumation in the Mecca Hills, CA

    NASA Astrophysics Data System (ADS)

    Moser, A. C.; Ault, A. K.; Evans, J. P.; Reiners, P. W.; Stearns, M.; Guenthner, W.

    2017-12-01

    Exposures of gneiss and Orocopia Schist (OS) in the Mecca Hills, California, adjacent to the southernmost San Andreas Fault system, preserve the exhumation history of Oligocene detachment faulting. We investigate the duration, magnitude, and mechanisms of exhumation of these units at regional and local scales using in situ U-Pb zircon dating (n = 248), (U-Th)/He (He) thermochronometry (n = 39), and He date-effective U (eU) patterns. Zircons with variable preserved visual metamictization were targeted for He analyses to purposefully build a dataset with a range in eU concentration and zircon He closure temperatures, as well as induce a He date-eU correlation. Analyzed zircon crystals range from clear and transparent to purple-brown and translucent in each sample. Zircon cathodoluminescence images reveal oscillatory and sector chemical zoning. Each sample contains a population of largely Proterozoic U-Pb dates implying some grains accumulated radiation damage since 1.9-1.1 Ga. Zircon (U-Th)/He dates from seven samples of OS and gneiss yield a mean date of 24 ± 3.5 Ma (n = 32) and uniform dates over an 90-2950 ppm eU range. One gneiss sample yields a mean date of 65 ± 5.6 Ma (n = 7) over a limited eU spread ( 500-950 ppm). Mean zircon He dates from these two units overlap, but dates are broadly younger in northeastern exposures dominated by OS. Preliminary thermal history simulations integrating zircon U-Pb data, He date-eU patterns, and independent geologic constraints require at least 200 °C of cooling through the zircon He partial retention zone 30-21 Ma and show that the pre-70 Ma thermal history does not affect the predicted date-eU correlation. This shared rapid cooling history documented in the OS and gneiss imply these units were juxtaposed prior to 30 Ma and exhumed as a coherent structural block within the footwall of the Orocopia Mountains Detachment Fault in the Mecca Hills. Spatio-temporal variation in mean zircon He dates may delineate time

  10. Zircon age-temperature-compositional spectra in plutonic rocks

    DOE PAGES

    Samperton, Kyle M.; Bell, Elizabeth A.; Barboni, Mélanie; ...

    2017-08-23

    We present that geochronology can resolve dispersed zircon dates in plutonic rocks when magma cooling time scales exceed the temporal precision of individual U-Pb analyses; such age heterogeneity may indicate protracted crystallization between the temperatures of zircon saturation (T sat) and rock solidification (T solid). Diffusive growth models predict asymmetric distributions of zircon dates and crystallization temperatures in a cooling magma, with volumetrically abundant old, hot crystallization at T sat decreasing continuously to volumetrically minor young, cold crystallization at T solid. We present integrated geochronological and geochemical data from Bergell Intrusion tonalites (Central Alps, Europe) that document zircon compositional changemore » over hundreds of thousands of years at the hand-sample scale, indicating melt compositional evolution during solidification. Ti-in-zircon thermometry, crystallization simulation using MELTS software, and U-Pb dates produce zircon mass-temperature-time distributions that are in excellent agreement with zircon growth models. In conclusion, these findings provide the first quantitative validation of longstanding expectations from zircon saturation theory by direct geochronological investigation, underscoring zircon’s capacity to quantify supersolidus cooling rates in magmas and resolve dynamic differentiation histories in the plutonic rock record.« less

  11. Zircon age-temperature-compositional spectra in plutonic rocks

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Samperton, Kyle M.; Bell, Elizabeth A.; Barboni, Mélanie

    We present that geochronology can resolve dispersed zircon dates in plutonic rocks when magma cooling time scales exceed the temporal precision of individual U-Pb analyses; such age heterogeneity may indicate protracted crystallization between the temperatures of zircon saturation (T sat) and rock solidification (T solid). Diffusive growth models predict asymmetric distributions of zircon dates and crystallization temperatures in a cooling magma, with volumetrically abundant old, hot crystallization at T sat decreasing continuously to volumetrically minor young, cold crystallization at T solid. We present integrated geochronological and geochemical data from Bergell Intrusion tonalites (Central Alps, Europe) that document zircon compositional changemore » over hundreds of thousands of years at the hand-sample scale, indicating melt compositional evolution during solidification. Ti-in-zircon thermometry, crystallization simulation using MELTS software, and U-Pb dates produce zircon mass-temperature-time distributions that are in excellent agreement with zircon growth models. In conclusion, these findings provide the first quantitative validation of longstanding expectations from zircon saturation theory by direct geochronological investigation, underscoring zircon’s capacity to quantify supersolidus cooling rates in magmas and resolve dynamic differentiation histories in the plutonic rock record.« less

  12. Petrography and zircon U-Pb isotopic study of the Bayanwulashan Complex: Constrains on the Paleoproterozoic evolution of the Alxa Block, westernmost North China Craton

    NASA Astrophysics Data System (ADS)

    Wu, Sujuan; Hu, Jianmin; Ren, Minghua; Gong, Wangbin; Liu, Yang; Yan, Jiyuan

    2014-11-01

    The Bayanwulashan Metamorphic Complex (BMC) exposes along the eastern margin of the Alxa Block, the westernmost part of the North China Craton (NCC). BMC is principally composed of metamorphic rocks with amphibole plagiogneiss, biotite plagioclase gneiss and granitic gneiss. Our research has been focused on the petrography and zircon U-Pb geochronology of the BMC to better understand the evolution of the Alxa Block and its relationship with the NCC. Evidences from field geology, petrography, and mineral chemistry indicate that two distinct metamorphic assemblages, the amphibolite and greenschist facies, had overprinted the preexisting granitic gneiss and suggest that the BMC experienced retrograde metamorphic episodes. The LA-ICP-MS zircon U-Pb ages reveal that the primary magmatic activities of BMC were at ca. 2.30-2.24 Ga and the two metamorphic events were at ca. 1.95-1.91 Ga and ca. 1.88-1.85 Ga respectively. These ages indicate that BMC initially intruded during Paleoproterozoic, not as previously suggested at Archean period. The Early Paleoproterozoic metamorphic records and the magmatic thermochronological data in BMC exhibit different evolution paths between the Alxa Block and the NCC. The Alxa Block was most likely an independent Early Paleoproterozoic terrain. Following different amalgamation processes, The Alxa Block combined with Western Block at ca. 1.95 Ga and then united with NCC at ca. 1.85 Ga.

  13. Zircon trace element and isotopic (Sr, Nd, Hf, Pb) effects of assimilation-fractional crystallization of pegmatite magma: A case study of the Guangshigou biotite pegmatites from the North Qinling Orogen, central China

    NASA Astrophysics Data System (ADS)

    Yuan, Feng; Liu, Jia-Jun; Carranza, Emmanuel John M.; Zhang, Shuai; Zhai, De-Gao; Liu, Gang; Wang, Gong-Wen; Zhang, Hong-Yuan; Sha, Ya-Zhou; Yang, Shang-Song

    2018-03-01

    Evidence for open-system magmatic processes related to wallrock assimilation accompanied by fractional crystallization (AFC) is present in the Guangshigou biotite pegmatites, North Qinling Orogen. The biotite pegmatite-gneiss contacts generally coincide with the greatest enrichment of U and Th. Zircon Usbnd Pb dating constrains the crystallization ages of the biotite pegmatite (rim zone-415 ± 2.6 Ma; internal zone-413.5 ± 2.5 Ma), in line with a pyrite Pbsbnd Pb isochron age (413 ± 22 Ma). Metamict areas in zircon show generally elevated concentrations of trace elements and expulsion of radioactive Pb. Internal zone samples, representing uncontaminated magma, have negative to positive zircon ( 413 Ma) εHf(t) (- 1.53 - + 3.24), low εNd(t) values (- 2.4), and old Hf and Nd model ages (tDM2 = 1.5-1.19 Ga, T2DM = 1.35 Ga, respectively), indicating a dominantly recycled Mesoproterozoic lower crustal material with involvement of some juvenile materials in the source region. The magmatic oxygen fugacity (fO2) and crystallization temperatures ranges from - 24.81 to - 13.34 of log fO2 and 570 °C to 793 °C, respectively. Compared to the internal zone, pegmatite rim samples display a variable and lower εNd(t) values (- 3.9 to - 2.8) and T2DM (1.47-1.37 Ga), but similar Hf isotopic compositions, favouring a three-component isotopic mixing model (recycled Mesoproterozoic lower crust materials, juvenile materials, and host gneiss). Pronounced variations of Ti, Y, U, Th, Hf, and REE concentrations in zircon from grain to grain in individual samples and from area to area within individual grains suggest a fluctuating crystallization environment in hybridized magma from which the rim-hosted zircons crystallized. Variable and high radiogenic Pb ratios of pyrites forming in the hybridized magma were inherited from the matrix. Zircons from both zones exhibit similar Hf isotope patterns, indicating the rim-hosted zircons crystallized during the early stage of hybridization of

  14. The Effect of Element Substitution on Ti-in-Zircon Geothermometry in Volcanic Zircons from Mount Pinatubo, Philippines

    NASA Astrophysics Data System (ADS)

    Lee, S. L.; Hattori, K.

    2017-12-01

    Despite the extensive application of the Ti-in-zircon geothermometer, its accuracy in natural systems remains uncertain. In order to investigate the parameters contributing to Ti in zircon, we examined zircons from dacitic eruption products of Mount Pinatubo, Philippines, from the Pliocene (>2.5-2.7 Ma), 35000BP and 1991AD. All samples are unaltered and quenched from magmas at 790-825°C (Fe-Ti-oxide thermometry). Furthermore, the magma conditions of 1991 samples are well characterized: 780°C (cummingtonite rims on hornblende, Fe-Ti-oxide thermometry), 2 kbar pressure, 5.5-6.5 wt.% H2O and fO2 of NNO+1.6. Calculated zircon saturation temperatures are 760, 744 and 738°C (oldest to youngest). Zircon Ti concentrations are low (2.0-8.8 ppm), show positive covariation with U (35.6-639 ppm), Th (18.7-696 ppm), ∑REE (237-1310 ppm) and Y (247-1770 ppm), and negative covariation with Hf (7610-12000 ppm). The Ti-in-zircon geothermometer by Ferry and Watson (2007) yields mean temperatures of 690, 666 and 663°C (oldest to youngest), using TiO2 activity=0.6, SiO2 activity=1 and -40°C pressure correction. Therefore, temperatures calculated using this method are underestimated by >100°C. We suggest that elements in the Zr site impact the substitution of Ti in the Si site of zircon. Ti shows a positive covariation with Zr/Hf (37.0-57.3, r2=0.551). The ionic radius of Hf4+ is smaller than Zr4+, whereas cations like U4+, Th4+, REE3+ and Y3+ are larger. The departure from the ideal crystal configuration is evaluated using the parameter Zr/(Hf-x), whereby x=U4+, Th4+, ∑REE and Y3+. Ti contents are more strongly correlated with the parameter than Zr/Hf (r2=0.559, 0.565, 0.608, 0.616; respectively). This suggests that large cations replacing Zr strain the lattice, reducing the amount of Ti incorporated into zircon. This further suggests that ZrSiO4 activity is less than 1 in natural rocks, resulting in the systematic underestimation of Ti-in-zircon temperatures.

  15. Assembling and disassembling california: A zircon and monazite geochronologic framework for proterozoic crustal evolution in southern California

    USGS Publications Warehouse

    Barth, A.P.; Wooden, J.L.; Coleman, D.S.; Vogel, M.B.

    2009-01-01

    The Mojave province in southern California preserves a comparatively complete record of assembly, postorogenic sedimentation, and rifting along the southwestern North American continental margin. The oldest exposed rocks are metasedimentary gneisses and amphibolite, enclosing intrusive suites that range from tonalite and quartz mon-zodiorite to granite with minor trondhjemite. Discrete magmatic episodes occurred at approximately 1790-1730 and 1690-1640 Ma. Evidence from detrital and premagmatic zircons indicates that recycling of 1900-1790 Ma Paleopro-terozoic crust formed the unique isotopic character of the Mojave province. Peak metamorphic conditions in the Mojave province reached middle amphibolite to granulite facies; metamorphism occurred locally from 1795 to 1640 Ma, with widespread evidence for metamorphism at 1711-1689 and 1670-1650 Ma. Structures record early, tight to isoclinal folding and penetrative west-vergent shear during the final metamorphic event in the west Mojave province. Proterozoic basement rocks are overlain by siliciclastic-carbonate sequences of Mesoproterozoic, Neoproterozoic, and Cambrian age, recording environmental change over the course of the transition from stable Mojave crust to the rifted Cordilleran margin. Neoproterozoic quartzites have diverse zircon populations inconsistent with a southwest North American source, which we infer were derived from the western conjugate rift pair within Rodinia, before establishment of the miogeocline. Neoproterozoic-Cambrian miogeoclinal clastic rocks record an end to rifting and establishment of the Cordilleran miogeocline in southern California by latest Neoproterozoic to Early Cambrian time. ?? 2009 by The University of Chicago.

  16. (De)coupled zircon metamictization, radiation damage, and He diffusivity

    NASA Astrophysics Data System (ADS)

    Ault, A. K.; Guenthner, W.; Reiners, P. W.; Moser, A. C.; Miller, G. H.; Refsnider, K. A.

    2017-12-01

    We develop and apply a new protocol for targeting crystals for the zircon (U-Th)/He (He) thermochronometry to maximize effective U (eU) and corresponding closure temperature variability to develop zircon He date-eU correlations observed in some datasets. Our approach exploits visual proxies for radiation damage accumulation (metamictization) during zircon selection. We show that by purposefully targeting a spectrum of zircon textures from pristine to metamict grains, it is possible to generate broad eU variation in suites of zircon from a single sample and zircon He date-eU-metamictization trends that can be exploited to resolve increasingly complex thermal histories. We present plane light photographs, eU concentration, and zircon He results from 59 individual zircons from nine crystalline rock samples. Six of the nine samples come from exposed Proterozoic granitoids on SE Baffin Island, Canada; Boulder Creek, CO; Sandia Mountains, NM; and Mecca Hills, CA. We report data from three Archean Baffin samples to compare with the Proterozoic Baffin sample date-eU-metamictization trend. In each Proterozoic sample, target zircons display a spectrum of metamictization from pristine, transparent crystals to purple-brown, translucent grains. Progressive loss of transparency and increase in discoloration consistently corresponds to an increase in eU in all samples. Individual zircon eU varies from 89-1885 ppm and, within each sample, the total eU spread is 538 ppm to 1374 ppm. For any given eU value, the Archean zircon appear comparatively more metamict than the Proterozoic Baffin grains and samples collectively define a 1681 ppm range in eU, with more restrictive intrasample eU spreads (199-1120 ppm). Proterozoic samples from Baffin, Sandia, and Front Range yield negative zircon He date-eU correlations with intrasample date ranges of 90-783 Ma. Increasing eU and younger dates correspond with increasing metamictization. In contrast, all three Proterozoic Mecca Hills samples

  17. Isotopic evidence for the diversity of late Quaternary loess in Nebraska: Glaciogenic and nonglaciogenic sources

    USGS Publications Warehouse

    Aleinikoff, John N.; Muhs, Daniel R.; Bettis, E. Arthur; Johnson, William C.; Fanning, C. Mark; Benton, Rachel

    2008-01-01

    Pb isotope compositions of detrital K-feldspars and U-Pb ages of detrital zircons are used as indicators for determining the sources of Peoria Loess deposited during the last glacial period (late Wisconsin, ca. 25–14 ka) in Nebraska and western Iowa. Our new data indicate that only loess adjacent to the Platte River has Pb isotopic characteristics suggesting derivation from this river. Most Peoria Loess in central Nebraska (up to 20 m thick) is non-glaciogenic, on the basis of Pb isotope ratios in K-feldspars and the presence of 34-Ma detrital zircons. These isotopic characteristics suggest derivation primarily from the Oligocene White River Group in southern South Dakota, western Nebraska, southeastern Wyoming, and northeastern Colorado. The occurrence of 10–25 Ma detrital zircons suggests additional minor contributions of silt from the Oligocene-Miocene Arikaree Group and Miocene Ogallala Group. Isotopic data from detrital K-feldspar and zircon grains from Peoria Loess deposits in eastern Nebraska and western Iowa suggest that the immediate source of this loess was alluvium of the Missouri River. We conclude that this silt probably is of glaciogenic origin, primarily derived from outwash from the western margin of the Laurentide Ice Sheet. Identification of the White River Group as the main provenance of Peoria Loess of central Nebraska and the Missouri River valley as the immediate source of western Iowa Peoria Loess indicates that paleowind directions during the late Wisconsin were primarily from the northwest and west, in agreement with earlier studies of particle size and loess thickness variation. In addition, the results are in agreement with recent simulations of non-glaciogenic dust sources from linked climate-vegetation modeling, suggesting dry, windy, and minimally vegetated areas in parts of the Great Plains during the last glacial period.

  18. Crustal Zircons from the Podiform Chromitites in Luobusa Ophiolite, Tibet

    NASA Astrophysics Data System (ADS)

    Yamamoto, S.; Komiya, T.; Maruyama, S.

    2004-12-01

    For the past decade, diamonds and unusual mineral asemblages were reported in podiform chromitites of the Luobusa ophiolite, southern Tibet, China (Bai 1993, Bai 2000, Yan 2001) by heavy mineral separation. These include (1) native elements, (2) alloys, (3) carbide, (4) platinium group elements (PGE) and arsenides, (5) silicates (6) oxide, (7) carbonates, (8) minerals with unusual compositons. Despite many questions as to these minerals above still remain open, these mineral inclusions would provide us the important infomation on the formation of the podiform chromitites. In this study, over 100 zircons were discovered by heavy mineral separation of podiform chromitite in Luobusa ophiolite. The discovery of accessory zircons in chromitites allowed us to date the formation of the chromitite and history of tectonic evolutions. Here we report the U-Pb age and mineral inclusions of zircons and discuss with unusually old age zircons. 20 zircon grains in chromitites from No. 1 site were analyzed. Zircons from the chromitites in Luobusa ophiolite are usually euhedral-subhedral and some are rounded. Cathodoluminescence images of these zircons indicate that some zircons have clear oscillatory zoning, whereas other zircons show apparent homogeneous overgrowth. U-Pb dating of these zircons by LA-ICP-MS yielded two different ages. One group has relatively younger age, 107-534Ma, which plots nearly on a concordia line. Another group has older age 1460-1822Ma, which plots off the concordia line. There is insignificant difference of apparent ages within a single zircon grain. For example, a zircon has 1650 Ma in the core, whereas does 1654 Ma in the rim. We identified several mineral inclusions, quartz, feldspar, mica, apatite, within both yonger and older zircons using laser-Raman spectrometry and EPMA. No high-pressure minerals or mantle minerals were identified. This means that these unusually old zircons were formed in low-pressure crustal emvironment. Where did the zircons

  19. Complex Effects of Ecosystem Engineer Loss on Benthic Ecosystem Response to Detrital Macroalgae.

    PubMed

    Rossi, Francesca; Gribsholt, Britta; Gazeau, Frederic; Di Santo, Valentina; Middelburg, Jack J

    2013-01-01

    Ecosystem engineers change abiotic conditions, community assembly and ecosystem functioning. Consequently, their loss may modify thresholds of ecosystem response to disturbance and undermine ecosystem stability. This study investigates how loss of the bioturbating lugworm Arenicola marina modifies the response to macroalgal detrital enrichment of sediment biogeochemical properties, microphytobenthos and macrofauna assemblages. A field manipulative experiment was done on an intertidal sandflat (Oosterschelde estuary, The Netherlands). Lugworms were deliberately excluded from 1× m sediment plots and different amounts of detrital Ulva (0, 200 or 600 g Wet Weight) were added twice. Sediment biogeochemistry changes were evaluated through benthic respiration, sediment organic carbon content and porewater inorganic carbon as well as detrital macroalgae remaining in the sediment one month after enrichment. Microalgal biomass and macrofauna composition were measured at the same time. Macroalgal carbon mineralization and transfer to the benthic consumers were also investigated during decomposition at low enrichment level (200 g WW). The interaction between lugworm exclusion and detrital enrichment did not modify sediment organic carbon or benthic respiration. Weak but significant changes were instead found for porewater inorganic carbon and microalgal biomass. Lugworm exclusion caused an increase of porewater carbon and a decrease of microalgal biomass, while detrital enrichment drove these values back to values typical of lugworm-dominated sediments. Lugworm exclusion also decreased the amount of macroalgae remaining into the sediment and accelerated detrital carbon mineralization and CO2 release to the water column. Eventually, the interaction between lugworm exclusion and detrital enrichment affected macrofauna abundance and diversity, which collapsed at high level of enrichment only when the lugworms were present. This study reveals that in nature the role of this

  20. Changing exhumation patterns during Cenozoic growth and glaciation of the Alaska Range: Insights from detrital thermochronology and geochronology

    USGS Publications Warehouse

    Lease, Richard O.; Haeussler, Peter J.; O'Sullivan, Paul

    2016-01-01

    Cenozoic growth of the Alaska Range created the highest topography in North America, but the space-time pattern and drivers of exhumation are poorly constrained. We analyzed U/Pb and fission-track double dates of detrital zircon and apatite grains from 12 catchments that span a 450 km length of the Alaska Range to illuminate the timing and extent of exhumation during different periods. U/Pb ages indicate a dominant Late Cretaceous to Oligocene plutonic provenance for the detrital grains, with only a small percentage of grains recycled from the Mesozoic and Paleozoic sedimentary cover. Fission-track ages record exhumation during Alaska Range growth and incision and reveal three distinctive patterns. First, initial Oligocene exhumation was focused in the central Alaska Range at ~30 Ma and expanded outward along the entire length of the range until 18 Ma. Oligocene exhumation, coeval with initial Yakutat microplate collision >600 km to the southeast, suggests a far-field response to collision that was localized by the Denali Fault within a weak Mesozoic suture zone. Second, the variable timing of middle to late Miocene exhumation suggests independently evolving histories influenced by local structures. Time-transgressive cooling ages suggest successive rock uplift and erosion of Mounts Foraker (12 Ma) through Denali (6 Ma) as crust was advected through a restraining bend in the Denali Fault and indicate a long-term slip rate ~4 mm/yr. Third, Pliocene exhumation is synchronous (3.7–2.7 Ma) along the length of the Alaska Range but only occurs in high-relief, glacier-covered catchments. Pliocene exhumation may record an acceleration in glacial incision that was coincident with the onset of Northern Hemisphere glaciation.

  1. Zircon U-Pb dating of eclogite from the Qiangtang terrane, north-central Tibet: a case of metamorphic zircon with magmatic geochemical features

    NASA Astrophysics Data System (ADS)

    Zhai, Qing-guo; Jahn, Bor-ming; Li, Xian-hua; Zhang, Ru-yuan; Li, Qiu-li; Yang, Ya-nan; Wang, Jun; Liu, Tong; Hu, Pei-yuan; Tang, Suo-han

    2017-06-01

    Zircon is probably the most important mineral used in the dating formation of high-pressure (HP) and ultrahigh-pressure (UHP) metamorphic rocks. The origin of zircon, i.e., magmatic or metamorphic, is commonly assessed by its external morphology, internal structure, mineral inclusions, Th/U ratios and trace element composition. In this study, we present an unusual case of metamorphic zircon from the Qiangtang eclogite, north-central Tibet. The zircon grains contain numerous eclogite-facies mineral inclusions, including omphacite, phengite, garnet and rutile; hence, they are clearly of metamorphic origin. However, they display features similar to common magmatic zircon, including euhedral crystal habit, high Th/U ratios and enriched heavy rare earth elements pattern. We suggest that these zircon grains formed from a different reservoir from that for garnet where no trace elements was present and trace element equilibrium between zircon and garnet was achieved. U-Pb dating of zircon gave an age of 232-237 Ma for the eclogite, and that of rutile yielded a slightly younger age of ca. 217 Ma. These ages are consistent with the reported Lu-Hf mineral isochron and phengite Ar-Ar ages. The zircon U-Pb and mineral Lu-Hf isochron ages are interpreted as the time of the peak eclogite-facies metamorphism, whereas the rutile U-Pb and phengite Ar-Ar ages represent the time of exhumation to the middle crust. Thus, the distinction between metamorphic and magmatic zircons cannot be made using only Th/U ratios and heavy REE compositions for HP-UHP metamorphic rocks of oceanic derivation.

  2. Zircon/fluid trace element partition coefficients measured by recrystallization of Mud Tank zircon at 1.5 GPa and 800-1000 °C

    NASA Astrophysics Data System (ADS)

    Ayers, John C.; Peters, Timothy J.

    2018-02-01

    Hydrothermal zircon grains have trace element characteristics such as low Th/U, high U, and high rare earth element (REE) concentrations that distinguish them from magmatic, metamorphic, and altered zircon grains, but it is unclear whether these characteristics result from distinctive fluid compositions or zircon/fluid fractionation effects. New experiments aimed at measuring zircon/fluid trace element partition coefficients Dz/f involved recrystallizing natural Mud Tank zircon with low trace element concentrations in the presence of H2O, 1 m NaOH, or 1 m HCl doped with ∼1000 ppm of rare earth elements (REE), Y, U and Th and ∼500 ppm of Li, B, P, Nb, Ba, Hf, and Ta. Experiments were run for 168 h at 1.5 GPa, 800-1000 °C, and fO2 = NNO in a piston cylinder apparatus using the double capsule method. LA-ICP-MS analysis shows that run product zircon crystals have much higher trace element concentrations than in Mud Tank zircon starting material. Dz/f values were estimated from run product zircon analyses and bulk composition using mass balance. Most elements behave incompatibly, with median Dz/f being highest for Hf = 8 and lowest for B = 0.02. Addition of NaOH or HCl had little influence on Dz/f values. Dz/f for LREE are anomalously high, likely due to contamination of run product zircon with quenched solutes enriched in incompatible elements, so DLREE were estimated using lattice strain theory. Brice curves for +3 ions yield zircon/fluid DLu/DLa of ∼800-5000. A Brice curve fit to +4 ions yielded DCe4+ values. Estimated concentrations of Ce3+ and Ce4+ show that the average Ce4+/Ce3+ in zircon of 27 is much higher than in fluid of 0.02. Th and U show little fractionation, with median DTh/DU = 0.7, indicating that the low Th/U in natural hydrothermal zircon is inherited from the fluid. Natural fluid compositions estimated from measured Dz/f and published compositions of hydrothermal zircon grains from aplite and eclogite reflect the mineralogy of the host rock, e

  3. Correlation of Brunhes detrital-layer stratigraphy into the North Atlantic from Orphan Knoll (Labrador Sea)

    NASA Astrophysics Data System (ADS)

    Channell, J. E.; Hodell, D. A.; Romero, O. E.; Hillaire-Marcel, C.; de Vernal, A.; Stoner, J. S.; Mazaud, A.; Roehl, U.

    2011-12-01

    IODP Site U1302-U1303, on the SE flank of Orphan Knoll (Labrador Sea), has a record of detrital layers that extends through most of the Brunhes Chron. The age model is built by tandem matching of relative paleointensity (RPI) and oxygen isotope data (δ18O) from Neogloboquadrina pachyderma (sin.) to reference records, indicating a mean Brunhes sedimentation rate of 14 cm/kyr. Sedimentation back to marine isotope stage (MIS) 18 is characterized by detrital layers that are detected by higher than background gamma-ray attenuation (GRA) density, peaks in X-ray fluorescence (XRF) indicators for detrital carbonate (Ca/Sr) and detrital silicate (Si/Sr), an ice-rafted debris (IRD) proxy (>106 μm), magnetic susceptibility, and magnetic grain-size peaks. The age model enables correlation of Site U1302/03 to IODP Site U1308 (re-drill of DSDP Site 609) in the heart of the central Atlantic IRD belt where an age model and a similar set of detrital-layer proxies have already been derived. Ages of Heinrich layers H1, H2, H4, H5 and H6 are within ~2 kyr at the two sites (H0, H3 and H5a are not observed at Site U1308), and agree with previous work at Orphan Knoll within ~3 kyr. At Site U1308, Brunhes detrital layers are restricted to peak glacials and glacial terminations back to MIS16, however, these same proxies at Site U1302/03 indicate detrital layers distributed throughout the record in both glacial and most interglacial stages. At Site U1302/03, we distinguish Heinrich-type layers in glacial stages, which are associated with IRD (some of which have near-synchronous analogues at Site U1308), from detrital layers within interglacial stages manifested by multiple detrital layer proxies (including Ca/Sr) but usually not associated with IRD, that may be attributed to a distinct depositional process, namely drainage and debris-flow events funneled down the nearby NAMOC (North Atlantic Mid-Ocean Channel).

  4. Distinguishing Grenvillian basement from pre-Taconian cover rocks in the Northern Appalachians

    USGS Publications Warehouse

    Karabinos, P.; Aleinikoff, J.N.; Fanning, C.M.

    1999-01-01

    Distinguishing Grenvillian basement rocks from pre-Taconian cover sequences in the Appalachians is a first-order problem essential for accurate structural interpretations. The Cavendish Formation in southeastern Vermont presents a classic example of this problem. Doll and others (1961) showed the Cavendish Formation as younger than the Middle Proterozoic Mount Holly Complex but older than the lithologically similar Cambrian Tyson and Hoosac Formations. More recently, the name Cavendish Formation has been informally abandoned, and its metasedimentary units have been mapped as the Tyson and Hoosac Formations of Late Proterozoic to Cambrian age. In a radical departure from these interpretations, Ratcliffe and others (1997) reassigned metasedimentary rocks of the Cavendish Formation to the Mount Holly Complex based on an inferred intrusive relationship between them and a 1.42 Ga tonalite. This new age assignment, if correct, requires a completely new structural interpretation of the region. SHRIMP and Pb evaporation ages of detrital zircons extracted from a quartzite layer from Cavendish Gorge near the proposed intrusive contact with the tonalite constrain the time of deposition of the Cavendish Formation. Grain shapes of the zircons vary from euhedral to nearly spherical. Virtually all the grains have pitted surfaces and show at least some rounding of edges and terminations; grains exhibit oscillatory zoning typical of zircons that crystallized from a magma. Single-grain Pb evaporation analyses of ten zircons and SHRIMP analyses of 15 zircons all yield ages less than 1.42 Ga. Seven of the grains are consistent with derivation from the Bull Hill Gneiss that postdates the Grenville orogenic cycle and predates deposition of the Cavendish Formation. Thus, the metasedimentary units of the Cavendish Formation should not be assigned to the Mount Holly Complex.

  5. Fission track dating of kimberlitic zircons

    USGS Publications Warehouse

    Haggerty, S.E.; Raber, E.; Naeser, C.W.

    1983-01-01

    The only reliable method for dating kimberlites at present is the lengthy and specialized hydrothermal procedure that extracts 206Pb and 238U from low-uranium zircons. This paper describes a second successful method by fission track dating of large single-crystal zircons, 1.0-1.5 cm in dimension. The use of large crystals overcomes the limitations imposed in conventional fission track analysis which utilizes crushed fragments. Low track densities, optical track dispersion, and the random orientation of polished surfaces in the etch and irradiation cycle are effectively overcome. Fission track ages of zircons from five African kimberlites are reported, from the Kimberley Pool (90.3 ?? 6.5 m.y.), Orapa (87.4 ?? 5.7 and 92.4 ?? 6.1 m.y.), Nzega (51.1 ?? 3.8 m.y.), Koffiefontein (90.0 ?? 8.2 m.y.), and Val do Queve (133.4 ?? 11.5 m.y.). In addition we report the first radiometric ages (707.9 ?? 59.6 and 705.5 ?? 61.0 m.y.) of crustal zircons from kimberlites in northwest Liberia. The fission track ages agree well with earlier age estimates. Most of the zircons examined in this study are zoned with respect to uranium but linear correlations are established (by regression analysis) between zones of variable uranium content, and within zones of constant uranium content (by analysis of variance). Concordance between the fission track method and the U/Pb technique is established and we concluded that track fading from thermal annealing has not taken place. Kimberlitic zircons dated in this study, therefore, record the time of eruption. ?? 1983.

  6. Radiation damage-He diffusivity models applied to deep-time thermochronology: Zircon and titanite (U-Th)/He datasets from cratonic settings

    NASA Astrophysics Data System (ADS)

    Guenthner, W.; DeLucia, M. S.; Marshak, S.; Reiners, P. W.; Drake, H.; Thomson, S.; Ault, A. K.; Tillberg, M.

    2017-12-01

    Advances in understanding the effects of radiation damage on He diffusion in uranium-bearing accessory minerals have shown the utility of damage-diffusivity models for interpreting datasets from geologic settings with long-term, low-temperature thermal histories. Craton interiors preserve a billion-year record of long-term, long-wavelength vertical motions of the lithosphere. Prior thermochronologic work in these settings has focused on radiation damage models used in conjunction with apatite (U-Th)/He dates to constrain Phanerozoic thermal histories. Owing to the more complex damage-diffusivity relationship in zircon, the zircon (U-Th)/He system yields both higher and, in some cases, lower temperature sensitivities than the apatite system, and this greater range in turn allows researchers to access deeper time (i.e., Proterozoic) segments of craton time-temperature histories. Here, we show two examples of this approach by focusing on zircon (U-Th)/He datasets from 1.8 Ga granitoids of the Fennoscandian Shield in southeastern Sweden, and 1.4 Ga granites and rhyolites of the Ozark Plateau in southeastern Missouri. In the Ozark dataset, the zircon (U-Th)/He data, combined with a damage-diffusivity model, predict negative correlations between date and effective uranium (eU) concentration (a measurement proportional to radiation damage) from thermal histories that include an episode of Proterozoic cooling (interpreted as exhumation) following reheating (interpreted as burial) to temperature of 260°C at 850-680 Ma. In the Fennoscandian Shield, a similar damage model-based approach yields time-temperature constraints with burial to 217°C between 944 Ma and 851 Ma, followed by exhumation from 850 to 500 Ma, and burial to 154°C between 366 Ma and 224 Ma. Our Fennoscandian Shield samples also include titanite (U-Th)/He dates that span a wide range (945-160 Ma) and are negatively correlated with eU concentration, analogous to our zircon He dataset. These results support

  7. Hydrogen incorporation and charge balance in natural zircon

    NASA Astrophysics Data System (ADS)

    De Hoog, J. C. M.; Lissenberg, C. J.; Brooker, R. A.; Hinton, R.; Trail, D.; Hellebrand, E.

    2014-09-01

    The water and trace element contents of natural igneous zircons were determined to constrain the mechanism of hydrogen incorporation. The low radiation-damage zircons were derived from Fe-Ti oxide gabbros from the Vema Fracture Zone (11°N, Mid-Atlantic Ridge). They contain up to 1212 ppmw H2O, 1.9 wt.% Y2O3 and 0.6 wt.% P2O5 and are generally strongly zoned. REE + Y are partially charge-balanced by P (Y, REE3+ + P5+ = Zr4+ + Si4+), but a large REE excess is present. On an atomic basis, this excess is closely approximated by the amount of H present in the zircons. We therefore conclude that H is incorporated by a charge-balance mechanism (H+ + REE3+ = Zr4+). This interpretation is consistent with FTIR data of the Vema zircons, which shows a strongly polarised main absorption band at ca. 3100 cm-1, similar to experimentally grown Lu-doped hydrous zircon. The size of this 3100 cm-1 band scales with H and REE contents. Apart from a small overlapping band at 3200 cm-1, no other absorption bands are visible, indicating that a hydrogrossular-type exchange mechanism does not appear to be operating in these zircons. Because of charge-balanced uptake of H, P and REE in zircon, the partitioning of these elements into zircon is dependent on each of their concentrations. For instance, DREEzrc/melt increases with increasing H and P contents of the melt, whereas DHzrc/melt increases with increasing REE content but decreases with increasing P content. In addition, H-P-REE systematics of sector zoning indicate kinetic effects may play an important role. Hence, using H in zircon to determine the water content of melts is problematic, and REE partitioning studies need to take into account P and H2O contents of the melt.

  8. Environmental controls on photosynthetic microbial mat distribution and morphogenesis on a 3.42 Ga clastic-starved platform.

    PubMed

    Tice, Michael M

    2009-12-01

    Three morphotypes of microbial mats are preserved in rocks deposited in shallow-water facies of the 3.42 Ga Buck Reef chert (BRC). Morphotype alpha consists of fine anastomosing and bifurcating carbonaceous laminations, which loosely drape underlying detrital grains or form silica-filled lenses. Morphotype beta consists of meshes of fine carbonaceous strands intergrown with detrital grains and dark laminations, which loosely drape coarse detrital grains. Morphotype gamma consists of fine, even carbonaceous laminations that tightly drape underlying detrital grains. Preservation of nearly uncompacted mat morphologies and detrital grains deposited during mat growth within a well-characterized sedimentary unit makes quantitative correlation between morphology and paleoenvironment possible. All mats are preserved in the shallowest-water interval of those rocks deposited below normal wave base and above storm wave base. This interval is bounded below by a transgressive lag formed during regional flooding and above by a small condensed section that marks a local relative sea-level maximum. Restriction of all mat morphotypes to the shallowest interval of the storm-active layer in the BRC ocean reinforces previous interpretations that these mats were constructed primarily by photosynthetic organisms. Morphotypes alpha and beta dominate the lower half of this interval and grew during deposition of relatively coarse detrital carbonaceous grains, while morphotype gamma dominates the upper half and grew during deposition of fine detrital carbonaceous grains. The observed mat distribution suggests that either light intensity or, more likely, small variations in ambient current energy acted as a first-order control on mat morphotype distribution. These results demonstrate significant environmental control on biological morphogenetic processes independent of influences from siliciclastic sedimentation.

  9. Tectonic Evolution of the Izmir Ankara Suture Zone in Northwest Turkey Using Zircon U-Pb Geochronology and Zircon Lu-Hf Isotopic Tracers

    NASA Astrophysics Data System (ADS)

    Campbell, C.; Taylor, M. H.; Licht, A.; Mueller, M.; Ocakglu, F.; Moeller, A.; Metais, G.; Beard, K. C.

    2017-12-01

    Detrital zircons from a Cretaceous forearc basin and Tertiary foreland basin located along the Sakarya Zone of the Western Pontides were analyzed to better understand the closure history of the Tethyan oceans. The Variscan Orogeny is characterized by abundant 350-300 Ma U-Pb ages and vertical ɛHf arrays, consistent with a mature magmatic arc that emplaced plutons through a southward growing accretionary margin. An ɛHf pull-up is observed from 300-250 Ma interpreted as rifting of the Intra-Pontide Ocean. The Cimmerian Orogeny is characterized by a 250-230 Ma ɛHf pull-down, followed by a 230-200 Ma magmatic gap consistent with underthrusting of the Karakaya Complex. From 200-120 Ma another magmatic lull is observed. The Alpine Orogeny is characterized by an ɛHf pull-down from 120-85 Ma within Cretaceous forearc sediments and a 100 Ma deviant ɛHf vertical array within Tertiary foreland basin sediments. Minor zircon U-Pb age peaks and contrasting inter-basinal ɛHf evolution are interpreted to represent onset of Andean-style subduction along the southern margin of the Sakarya Zone at 120 Ma followed by crustal thickening until 85 Ma. The deviant 100 Ma ɛHf vertical array within foreland basin detritus is interpreted as initiation of intra-oceanic subduction within the Izmir-Ankara Ocean. An 85-75 Ma ɛHf pull-up from forearc basin sediments is interpreted as slab roll-back along the southern margin of the Sakarya Zone, responsible for final rifting of the Western Black Sea. At 80 Ma, a vertical ɛHf array from Tertiary foreland basin deposits is interpreted to represent synchronous melting of the Tavsanli Zone and intra-oceanic slab break-off. A single 66 Myr pre-collisional grain defines a sharp ɛHf pull-down immediately prior to total arc shut-off, interpreted to represent incipient collision between the Sakarya and Tavsanli zones. A 52 Ma syn-collisional tuff yields minimally intermediate ɛHf values followed by a slight 48 Ma ɛHf pull-down, interpreted as a

  10. Zircon U-Pb ages, geochemistry, and Nd-Hf isotopes of the TTG gneisses from the Jiaobei terrane: Implications for Neoarchean crustal evolution in the North China Craton

    NASA Astrophysics Data System (ADS)

    Shan, Houxiang; Zhai, Mingguo; Wang, Fang; Zhou, Yanyan; Santosh, M.; Zhu, Xiyan; Zhang, Huafeng; Wang, Wei

    2015-02-01

    The Precambrian basement in the Jiaobei terrane is largely composed of Tonalite-Trondhjemite-Granodiorite (TTG) suite of rocks and offers important insights into the crustal evolution history of the North China Craton (NCC). The LA-ICP-MS zircon U-Pb age data presented in this study show that the magmatic protoliths of the TTG gneisses formed during 2508-2547 Ma and recorded the Paleoproterozoic metamorphism (∼1905 Ma). The rocks are enriched in LILE (Rb, Ba and Sr) and depleted in HFSE (Nb, Ta, Zr and Hf). They are characterized by high Sr contents (406-2906 ppm), Sr/Y ratios (31.3-355) and subchondritic Nb/Ta ratios (18.5-68.9). The TTGs show relatively high ΣREE contents (72.0-266 ppm) with strongly enriched LREE ((La/Yb)N = 11.5-121) and positive or negligible negative Eu anomalies (Eu/Eu∗ = 0.84-1.89). These geochemical features suggest that the magma source might have been rutile-bearing amphibole eclogite. Their high Mg# numbers (42-56) and high Cr (153-285 ppm) and Ni contents (22.2-74.5 ppm) indicate interaction with the mantle wedge during magma ascent. The whole rock εNd (t) values (+2.6 to +3.8) and most of the magmatic zircon εHf (t) values (+1.3 to +7.6) suggest juvenile to evolved isotopic signatures. All these lines of evidence suggest that the TTG rocks in this study formed through partial melting of subducted oceanic slab in a continental arc environment. The drill holes in the Jiaobei terrane are dominated by ∼2.5 Ga TTG gneisses, suggesting that the TTG magma at ∼2.5 Ga is more widely distributed deep underground than that of ∼2.7-2.9 Ga, at least within the approachable depth range of our research. Some zircon grains from Jiaobei TTGs give high εHf (t) values plotting above the curve of 0.75 ∗ εHf of DM, and their TCDM ages are very close to the time of the zircon crystallization. However, the majority of the εHf (t) values fall below the curve of 0.75 ∗ εHf of DM and their TCDM ages are concentrated between ∼2.7-2.9 Ga

  11. Oxygen isotopic composition and U-Pb discordance in zircon

    USGS Publications Warehouse

    Booth, A.L.; Kolodny, Y.; Chamberlain, C.P.; McWilliams, M.; Schmitt, A.K.; Wooden, J.

    2005-01-01

    We have investigated U-Pb discordance and oxygen isotopic composition of zircon using high-spatial resolution ??18O measurement by ion microprobe. ??18O in both concordant and discordant zircon grains provides an indication of the relationship between fluid interaction and discordance. Our results suggest that three characteristics of zircon are interrelated: (1) U-Pb systematics and concomitant age discordance, (2) ??18O and the water-rock interactions implied therein, and (3) zircon texture, as revealed by cathodoluminescence and BSE imaging. A key observation is that U-Pb-disturbed zircons are often also variably depleted in 18O, but the relationship between discordance and ??18O is not systematic. ??18O values of discordant zircons are generally lighter but irregular in their distribution. Textural differences between zircon grains can be correlated with both U-Pb discordance and ??18O. Discordant grains exhibit either a recrystallized, fractured, or strongly zoned CL texture, and are characteristic of 18O depletion. We interpret this to be a result of metamictization, leading to destruction of the zircon lattice and an increased susceptibility to lead loss. Conversely, grains that are concordant have less-expressed zoning and a smoother CL texture and are enriched in 18O. From this it is apparent that various stages of water-rock interaction, as evidenced by systematic variations in ??18O, leave their imprint on both the texture and U-Pb systematics of zircon. Copyright ?? 2005 Elsevier Ltd.

  12. Fission track dating of kimberlitic zircons

    NASA Astrophysics Data System (ADS)

    Haggerty, Stephen E.; Raber, Ellen; Naeser, Charles W.

    1983-04-01

    The only reliable method for dating kimberlites at present is the lengthy and specialized hydrothermal procedure that extracts 206Pb and 238U from low-uranium zircons. This paper describes a second successful method by fission track dating of large single-crystal zircons, 1.0-1.5 cm in dimension. The use of large crystals overcomes the limitations imposed in conventional fission track analysis which utilizes crushed fragments. Low track densities, optical track dispersion, and the random orientation of polished surfaces in the etch and irradiation cycle are effectively overcome. Fission track ages of zircons from five African kimberlites are reported, from the Kimberley Pool (90.3 ± 6.5 m.y.), Orapa (87.4 ± 5.7 and 92.4 ± 6.1 m.y.), Nzega (51.1 ± 3.8 m.y.), Koffiefontein (90.0 ± 8.2 m.y.), and Val do Queve (133.4 ± 11.5 m.y.). In addition we report the first radiometric ages (707.9 ± 59.6 and 705.5 ± 61.0 m.y.) of crustal zircons from kimberlites in northwest Liberia. The fission track ages agree well with earlier age estimates. Most of the zircons examined in this study are zoned with respect to uranium but linear correlations are established (by regression analysis) between zones of variable uranium content, and within zones of constant uranium content (by analysis of variance). Concordance between the fission track method and the U/Pb technique is established and we concluded that track fading from thermal annealing has not taken place. Kimberlitic zircons dated in this study, therefore, record the time of eruption.

  13. Detrital record of initial basement exhumation along the Laramide deformation front, southern Rocky Mountains

    NASA Astrophysics Data System (ADS)

    Bush, Meredith A.; Horton, Brian K.; Murphy, Michael A.; Stockli, Daniel F.

    2016-09-01

    New geochronological constraints on upper crustal exhumation in the southern Rocky Mountains help delineate the latest Cretaceous-Paleogene history of drainage reorganization and landscape evolution during Laramide flat-slab subduction beneath western North America. Detrital zircon U-Pb results for the Raton basin of southern Colorado and northern New Mexico define the inception of coarse-grained siliciclastic sedimentation and a distinctive shift in provenance, from distal to proximal sources, that recorded shortening-related uplift and unroofing along the Laramide deformation front of the northern Sangre de Cristo Mountains. This Maastrichtian-early Paleocene ( 70-65 Ma) change—from distal foreland accumulation of sediment derived from the thin-skinned Cordilleran (Sevier) fold-thrust belt to coarse-grained sedimentation proximal to a Laramide basement block uplift—reflects cratonward (eastward) deformation advance and reorganization of drainage systems that supplied a large volume of Paleocene-lower Eocene sediments to the Gulf of Mexico. The timing of unroofing along the eastern deformation front is synchronous with basement-involved shortening across the interior of the Laramide province, suggesting abrupt wholesale uplift rather than a systematic inboard advance of deformation. The growth and infilling of broken foreland basins within the interior and margins of the Laramide province had a significant impact on continental-scale drainage systems, as several ponded/axial Laramide basins trapped large volumes of sediment and induced reorganization of major source-to-sink sediment pathways.

  14. Constraints on the timing of Co-Cu ± Au mineralization in the Blackbird district, Idaho, using SHRIMP U-Pb ages of monazite and xenotime plus zircon ages of related Mesoproterozoic orthogneisses and metasedimentary rocks

    USGS Publications Warehouse

    Aleinikoff, John N.; Slack, John F.; Lund, Karen; Evans, Karl V.; Fanning, C. Mark; Mazdab, Frank K.; Wooden, Joseph L.; Pillers, Renee M.

    2012-01-01

    The Blackbird district, east-central Idaho, contains the largest known Co reserves in the United States. The origin of strata-hosted Co-Cu ± Au mineralization at Blackbird has been a matter of controversy for decades. In order to differentiate among possible genetic models for the deposits, including various combinations of volcanic, sedimentary, magmatic, and metamorphic processes, we used U-Pb geochronology of xenotime, monazite, and zircon to establish time constraints for ore formation. New age data reported here were obtained using sensitive high resolution ion microprobe (SHRIMP) microanalysis of (1) detrital zircons from a sample of Mesoproterozoic siliciclastic metasedimentary country rock in the Blackbird district, (2) igneous zircons from Mesoproterozoic intrusions, and (3) xenotime and monazite from the Merle and Sunshine prospects at Blackbird. Detrital zircon from metasandstone of the biotite phyllite-schist unit has ages mostly in the range of 1900 to 1600 Ma, plus a few Neoarchean and Paleoproterozoic grains. Age data for the six youngest grains form a coherent group at 1409 ± 10 Ma, regarded as the maximum age of deposition of metasedimentary country rocks of the central structural domain. Igneous zircons from nine samples of megacrystic granite, granite augen gneiss, and granodiorite augen gneiss that crop out north and east of the Blackbird district yield ages between 1383 ± 4 and 1359 ± 7 Ma. Emplacement of the Big Deer Creek megacrystic granite (1377 ± 4 Ma), structurally juxtaposed with host rocks in the Late Cretaceous ca. 5 km north of Blackbird, may have been involved in initial deposition of rare earth elements (REE) minerals and, possibly, sulfides. In situ SHRIMP ages of xenotime and monazite in Co-rich samples from the Merle and Sunshine prospects, plus backscattered electron imagery and SHRIMP analyses of trace elements, indicate a complex sequence of Mesoproterozoic and Cretaceous events. On the basis of textural relationships

  15. Oxygen diffusion in zircon

    NASA Astrophysics Data System (ADS)

    Watson, E. B.; Cherniak, D. J.

    1997-05-01

    Oxygen diffusion in natural, non-metamict zircon was characterized under both dry and water-present conditions at temperatures ranging from 765°C to 1500°C. Dry experiments were performed at atmospheric pressure by encapsulating polished zircon samples with a fine powder of 18O-enriched quartz and annealing the sealed capsules in air. Hydrothermal runs were conducted in cold-seal pressure vessels (7-70 MPa) or a piston cylinder apparatus (400-1000 MPa) on zircon samples encapsulated with both 18O-enriched quartz and 18O water. Diffusive-uptake profiles of 18O were measured in all samples with a particle accelerator, using the 18O(p, α) 15N reaction. For dry experimental conditions at 1100-1500°C, the resulting oxygen diffusivities (24 in all) are well described by: D dry (m 2/s) = 1.33 × 10 -4exp(-53920/T) There is no suggestion of diffusive anisotropy. Under wet conditions at 925°C, oxygen diffusion shows little or no dependence upon P H 2O in the range 7-1000 MPa, and is insensitive to total pressure as well. The results of 27 wet experiments at 767-1160°C and 7-1000 MPa can be described a single Arrhenius relationship: D wet (m 2/s) = 5.5 × 10 -12exp(-25280/T) The insensitivity of oxygen diffusion to P H 2O means that applications to geologic problems can be pursued knowing only whether the system of interest was 'wet' (i.e., P H 2O > 7MPa ) or 'dry'. Under dry conditions (presumably rare in the crust), zircons are extremely retentive of their oxygen isotopic signatures, to the extent that δ 18O would be perturbed at the center of a 200 μm zircon only during an extraordinarily hot and protracted event (e.g., 65 Ma at 900°C). Under wet conditions, δ 18O may or may not be retained in the central regions of individual crystals, cores or overgrowth rims, depending upon the specific thermal history of the system.

  16. Marked spatial gradient in the topographic evolution of the Andes spanning the Chilean flat-slab transition: evidence from stable isotope paleoaltimetry and zircon double dating

    NASA Astrophysics Data System (ADS)

    Hoke, G. D.; McPhillips, D. F.; Giambiagi, L.; Garzione, C. N.; Mahoney, J. B.; Strecker, M. R.

    2015-12-01

    The major changes in the subduction angle of the Nazca plate are often hypothesized to have important consequences for the tectonic evolution of the Andes. Temporal and spatial patterns of topographic growth and exhumation are indicators that should help elucidate any linkages to subduction angle. Here, we combine observations from stable isotope paleoaltimetry with detrital zircon double dating between 30 and 35°S to demonstrate a consistent increase in surface and rock uplift in the Andes south of 32°S. The stable isotope data are from Miocene pedogenic carbonates collected from seven different basin sequences spanning different tectonic and topographic positions in the range. Paleoelevations between 1 km and 1.9 km are calculated using modern local isotope-elevation gradients along with carbonate-formation temperatures determined from clumped isotope studies in modern soils. Present day, low elevation foreland localities were at their present elevations during the Miocene, while three of the intermontane basins experienced up to 2 km of surface uplift between the end of deposition during the late Miocene and present. Detrital zircon (U-Th-Sm)/He and U-Pb double dating in three modern drainage basins (Tunuyán, Arroyo Grande and Río de los Patos) reveals clear Miocene exhumation signals south of the flat slab with no recent exhumation apparent at 32°S. The exhumation pattern is consistent with paleoaltimetry results. Interestingly, the maximum inferred surface uplift is greatest where the crust is thinnest, and the timing of the observed changes in elevation and exhumation has not been linked to any documented episodes of large-magnitude crustal shortening in the eastern half of the range. The spatial pattern of surface uplift and exhumation seems to mimic the Pampean flat slab's geometry, however, it could be equally well explained by eastward migration of a crustal root via ductile deformation in the lower crust and is not related to flat-slab subduction.

  17. Radiation Damage Study in Natural Zircon Using Neutrons Irradiation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lwin, Maung Tin Moe; Amin, Yusoff Mohd.; Kassim, Hasan Abu

    2011-03-30

    Changes of atomic displacements in crystalline structure of natural zircon (ZrSiO{sub 4}) can be studied by using neutron irradiation on the surface of zircon and compared the data from XRD measurements before and after irradiation. The results of neutron irradiation on natural zircon using Pneumatic Transfer System (PTS) at PUSPATI TRIGA Research Reactor in the Malaysian Nuclear Agency are discussed in this work. The reactor produces maximum thermal power output of 1 MWatt and the neutron flux of up to 1x10{sup 13} ncm{sup -2}s{sup -1}. From serial decay processes of uranium and thorium radionuclides in zircon crystalline structure, the emissionmore » of alpha particles can produce damage in terms of atomic displacements in zircon. Hence, zircon has been extensively studied as a possible candidate for immobilization of fission products and actinides.« less

  18. Deformation-related microstructures in magmatic zircon and implications for diffusion

    NASA Astrophysics Data System (ADS)

    Reddy, Steven Michael; Timms, Nicholas E.; Hamilton, Patrick Joseph; Smyth, Helen R.

    2009-02-01

    An undeformed glomeroporphyritic andesite from the Sunda Arc of Java, Indonesia, contains zoned plagioclase and amphibole glomerocrysts in a fine-grained groundmass and records a complex history of adcumulate formation and subsequent magmatic disaggregation. A suite of xenocrystic zircon records Proterozoic and Archaean dates whilst a discrete population of zoned, euhedral, igneous zircon yields a SHRIMP U-Pb crystallisation age of 9.3 ± 0.2 Ma. Quantitative microstructural analysis of zircon by electron backscatter diffraction (EBSD) shows no deformation in the inherited xenocrysts, but intragrain orientation variations of up to 30° in 80% of the young zircon population. These variations are typically accommodated by both progressive crystallographic bending and discrete low angle boundaries that overprint compositional growth zoning. Dispersion of crystallographic orientations are dominantly by rotation about an axis parallel to the zircon c-axis [001], which is coincident with the dominant orientation of misorientation axes of adjacent analysis points in EBSD maps. Less common <100> misorientation axes account for minor components of crystallographic dispersion. These observations are consistent with zircon deformation by dislocation creep and the formation of tilt and twist boundaries associated with the operation of <001>{100} and <100>{010} slip systems. The restriction of deformation microstructures to large glomerocrysts and the young magmatic zircon population, and the absence of deformation within the host igneous rock and inherited zircon grains, indicate that zircon deformation took place within a low-melt fraction (<5% melt), mid-lower crustal cumulate prior to fragmentation during magmatic disaggregation and entrainment of xenocrystic zircons during magmatic decompression. Tectonic stresses within the compressional Sunda Arc at the time of magmatism are considered to be the probable driver for low-strain deformation of the cumulate in the late

  19. Accessory Mineral Records of Early Earth Crust-Mantle Systematics: an Example From West Greenland

    NASA Astrophysics Data System (ADS)

    Storey, C. D.; Hawkesworth, C. J.

    2008-12-01

    Conditions for the formation and the nature of Earth's early crust are enigmatic due to poor preservation. Before c.4 Ga the only archives are detrital minerals eroded from earlier crust, such as the Jack Hills zircons in western Australia, or extinct isotope systematics. Zircons are particularly powerful since they retain precise records of their ages of crystallisation, and the Lu-Hf radiogenic isotope and O stable isotope systematics of the reservoir from which they crystallised. In principle, this allows insight into the nature of the crust, the mantle reservoir from which the melt was extracted and any reworked material incorporated into that melt. We have used in situ methods to measure U-Pb, O and Lu-Hf within single zircon crystals from tonalitic gneisses from West Greenland in the vicinity of the Isua Supracrustal Belt. They have little disturbed ages of c.3.8 Ga, mantle-like O isotope signatures and Lu-Hf isotope signatures that lie on the CHUR evolution line at 3.8 Ga. These samples have previously been subjected to Pb isotope feldspar and 142Nd whole rock analysis and have helped constrain models in which early differentiation of a proto-crust must have occurred. The CHUR-like Lu-Hf signature, along with mantle-like O signature from these zircons suggests juvenile melt production at 3.8 Ga from undifferentiated mantle, yet the other isotope systems preclude this possibility. Alternatively, this is further strong evidence for a heterogeneous mantle in the early Earth. Whilst zircons afford insight into the nature of the early crust and mantle, it is through the Sm-Nd system that the mantle has traditionally been viewed. Titanite often contains several thousand ppm Nd, making it amenable to precise analysis, and is a common accessory phase. It has a reasonably high closure temperature for Pb and O, and it can retain cores with older ages and distinct REE chemistry. It is often the main accessory phase alongside zircon, and it is the main carrier of Nd

  20. Zircon-Based Ceramics Composite Coating for Environmental Barrier Coating

    NASA Astrophysics Data System (ADS)

    Suzuki, M.; Sodeoka, S.; Inoue, T.

    2008-09-01

    Studies on plasma spraying of zircon (ZrSiO4) have been carried out by the authors as one of the candidates for an environmental barrier coating (EBC) application, and had reported that substrate temperature is one of the most important factors to obtain crack-free and highly adhesive coating. In this study, several amounts of yttria were added to zircon powder, and the effect of the yttria addition on the structure and properties of the coatings were evaluated to improve the stability of the zircon coating structure at elevated temperature. The coatings obtained were composed of yttria-stabilized zirconia (YSZ), glassy silica, whereas the one prepared from monolithic zircon powder was composed of the metastable high temperature tetragonal phase of zirconia and glassy silica. After the heat treatment over 1200 °C, silica and zirconia formed zircon in all coatings. However, coatings with higher amounts of yttria exhibited lower amounts of zircon. This resulted in the less open porosity of the coating at elevated temperature. These yttria-added coatings also showed good adhesion even after the heat treatment, while monolithic zircon coating pealed off.

  1. Early Mesozoic rift basin architecture and sediment routing system in the Moroccan High Atlas

    NASA Astrophysics Data System (ADS)

    Perez, N.; Teixell, A.; Gomez, D.

    2016-12-01

    Late Permian to Triassic extensional systems associated with Pangea breakup governed the structural framework and rift basin architecture that was inherited by Cenozoic High Atlas Mountains in Morocco. U-Pb detrital zircon geochronologic and mapping results from Permo-Triassic deposits now incorporated into the High Atlas Mountains provide new constraints on the geometry and interconnectivity among synextensional depocenters. U-Pb detrital zircon data provide provenance constraints of Permo-Triassic deposits, highlighting temporal changes in sediment sources and revealing the spatial pattern of sediment routing along the rift. We also characterize the U-Pb detrital zircon geochronologic signature of distinctive interfingering fluvial, tidal, and aeolian facies that are preferentially preserved near the controlling normal faults. These results highlight complex local sediment mixing patterns potentially linked to the interplay between fault motion, eustatic, and erosion/transport processes. We compare our U-Pb geochronologic results with existing studies of Gondwanan and Laurentian cratonic blocks to investigate continent scale sediment routing pathways, and with analogous early Mesozoic extensional systems situated in South America (Mitu basin, Peru) and North America (Newark Basin) to assess sediment mixing patterns in rift basins.

  2. A new estimate of detrital redox-sensitive metal concentrations and variability in fluxes to marine sediments

    NASA Astrophysics Data System (ADS)

    Cole, Devon B.; Zhang, Shuang; Planavsky, Noah J.

    2017-10-01

    The enrichment and depletion of redox sensitive trace metals in marine sediments have been used extensively as paleoredox proxies. The trace metals in shale are comprised of both detrital (transported or particulate) and authigenic (precipitated, redox-driven) constituents, potentially complicating the use of this suite of proxies. Untangling the influence of these components is vital for the interpretation of enrichments, depletions, and isotopic signals of iron (Fe), chromium (Cr), uranium (U), and vanadium (V) observed in the rock record. Traditionally, a single crustal average is used as a cutoff for detrital input, and concentrations above or below this value are interpreted as redox derived authigenic enrichment or depletion, while authigenic isotopic signals are frequently corrected for an assumed detrital contribution. Building from an extensive study of soils across the continental United States - which upon transport will become marine sediments - and their elemental concentrations, we find large deviations from accepted crustal averages in redox-sensitive metals (Fe, Cr, U, V) compared to typical detrital tracers (Al, Ti, Sc, Th) and provide new estimates for detrital contributions to the ocean. The variability in these elemental ratios is present over large areas, comparable to the catchment-size of major rivers around the globe. This heterogeneity in detrital flux highlights the need for a reevaluation of how the detrital contribution is assessed in trace metal studies, and the use of confidence intervals rather than single average values, especially in local studies or in the case of small authigenic enrichments.

  3. Magnetic signatures of Heinrich-like detrital layers in the Quaternary of the North Atlantic

    NASA Astrophysics Data System (ADS)

    Channell, J. E. T.; Hodell, D. A.

    2013-05-01

    Magnetic parameters are useful for distinguishing North Atlantic Heinrich-like detrital layers from background sediments. Here we compare magnetic properties with XRF scanning data back to 700 ka and 1.3 Ma at IODP Sites U1302-U1303 and U1308, respectively. Multi-domain magnetite, with grain sizes >20 µm, is characteristic of both Ca- and Si-rich detrital layers, as defined by XRF core scanning, confirming the contribution of ice rafting. Reflectance spectra and magnetic parameters distinguish Ca- and Si-rich IRD layers due the presence of high coercivity hematite in Si-rich layers. Heinrich layer 6 (H6) at Site U1302-U1303 is unlike other detrital layers, being marked by a 45-cm thick homogeneous cream-colored clay layer underlain by a thin (5-cm) graded coarse-sand. Comparison of Site U1302/03 and Site U1308 detrital layers implies a dominant Laurentide source for both Ca- and Si-rich detrital layers. At Site U1308, low benthic δ13C values during stadials are in-step with magnetic grain-size coarsening associated with Si-rich detrital layers back to 1.3 Ma, indicating a link between deep-sea ventilation and ice rafting. The surface-sediment tan-colored oxic layer (~2 m thick at Site U1308) yields magnetic hysteresis ratios that are offset from the single-domain to multi-domain (SD-MD) magnetite mixing-line in hysteresis-ratio diagrams. This offset is attributed to maghemite grain-coatings, that form on magnetite in surface sediment, and undergo dissolution as they pass through the oxic/anoxic boundary.

  4. Isotopic Composition of Oxygen in Lunar Zircons

    NASA Technical Reports Server (NTRS)

    Nemchin, A. A.; Whitehouse, M. J.; Pidgeon, R. T.; Meyer, C.

    2005-01-01

    The recent discovery of heavy oxygen in zircons from the Jack Hills conglomerates Wilde et al. and Mojzsis et al. was interpreted as an indication of presence of liquid water on the surface of Early Earth. The distribution of ages of Jack Hills zircons and lunar zircons appears to be very similar and therefore analysis of oxygen in the lunar grains may provide a reference frame for further study of the early history of the Earth as well as give additional information regarding processes that operated on the Moon. In the present study we have analysed the oxygen isotopic composition of zircon grains from three lunar samples using the Swedish Museum of Natural History CAMECA 1270 ion microprobe. The samples were selected as likely tests for variations in lunar oxygen isotopic composition. Additional information is included in the original extended abstract.

  5. Deciphering the evolution of rapakivi magmas from mineral inclusions in alkali feldspar megacrysts and zircon

    NASA Astrophysics Data System (ADS)

    Heinonen, Aku; Mänttäri, Irmeli; Rämö, Tapani; Larjamo, Kirsi

    2017-04-01

    Rapakivi granites are ferroan (A-type) granites that are characterized by ovoid-shaped alkali feldspar megacrysts (diameter up to 15 cm) commonly mantled by plagioclase forming the namesake rapakivi texture. The 1.63 Ga Wiborg batholith in southeastern Finland is the type area of rapakivi granites. Recent studies into the chemistry and geochronology of the mineral inclusions within the Wiborg rapakivi granite ovoids have shown that the megacrysts may represent magmas that crystallized significantly earlier and either in different P/T conditions or from magmas with dissimilar compositions than the matrices of the respective granites. It is possible that the ovoids crystallized from magmas with more evolved geochemical characteristics than the matrices, including higher levels of REE and other incompatibe elements. All ovoids are perthitic and have concave and rod-shaped quartz, hypidiomorphic or slightly resorbed plagioclase (often with partial quartz rim), zircon, biotite, apatite, and ilmenite (and occasionally minor magnetite) inclusions. The ovoids of the mafic rapakivi granite types have also hornblende and sometimes olivine and clinopyroxene inclusions, whereas the more felsic types have abundant fluorite. In contrast to the ovoids, the groundmass feldspar grains have hardly any inclusions. Differences are also observed in the hornblende compositions between the ovoid inclusion (dominantly ferroedenitic) and matrix (ferropargasitic/hastingsitic) populations. As zircon is an almost ubiquitous inclusion phase, time-integrated trace element composition comparisons of not only ovoid inclusion and matrix populations but also between different morphological types have been possible. Also the zircon crystals themselves contain plenty of inclusions. Alkali feldspar (albite and potassic feldspar) and quartz constitute the bulk of the inclusions within zircon crystals but chloritized mafic minerals, and sometimes also fluorite and ilmenite are common. A detailed

  6. Elemental Analysis of Zircon by High Mass Resolution USGS-Stanford SHRIMP-RG: Measuring and Evaluating Ti-in-zircon Temperatures and Compositional Characteristics

    NASA Astrophysics Data System (ADS)

    Wooden, J. L.; Mazdab, F. K.; Claiborne, L. L.; Miller, C. F.; Barth, A. P.

    2006-12-01

    High mass resolution of SHRIMP-RG permits measurement of a large set of trace elements for zircon, including 48Ti, Sc, and Nb (requiring better than 9,000 MR) and Be, B, F, P, 49Ti, V, Y, all the REE, Hf, Th, and U (Mazdab and Wooden 2006). A 15-20 micron spot allows analysis of numerous discrete CL zones from single zircons with minimal contributions from unknown material below the exposed surface. Data from suites of zircons from more than 20 individual granitoid samples suggest several general observations: (1) Temperatures calculated by Ti-in-zircon (Watson et al 2006) are entirely compatible with petrologic constraints; uncertainty in a(TiO2) introduces uncertainty in calculated T, but for reasonable values between 0.5 and 0.8 T's consistently fall between 650 and 900 C, mostly in the lower half of the range; (2) T can vary by 150-200 C within suites of zircons from individual samples and even in single zircons, where zonation may be normal (high to low, core to rim), reverse (low to high) or fluctuating; (3) Hf concentrations increase with decreasing T because of Zr/Hf fractionation between zircon and melt (Claiborne et al in press); (4) Many elements and element ratios show a co-variation with T and Hf concentration e.g., Th/U and MREE/HREE decrease with increasing Hf and decreasing T. Hf concentrations can continue to increase after a minimum T is reached, indicating continuing zircon growth from remaining (near eutectic?) melt. Yb/Gd (steepness of the HREE pattern) is an excellent monitor of fractionation, particularly at lower T (below 750 C) where the ratio increases rapidly. This trend may result from co-fractionation of accessory minerals and/or be driven by the thermodynamics of crystal growth, and/or may involve other factors and processes as yet poorly understood. Magmatic zircons commonly have a negative Eu anomaly of about 0.5 or lower which may change little or become more pronounced with falling T; anomalies probably reflect feldspar

  7. U-Pb geochronology and Hf-Nd isotope compositions of the oldest Neoproterozoic crust within the Cadomian orogen: new evidence for a unique juvenile terrane

    NASA Astrophysics Data System (ADS)

    Samson, S. D.; D'Lemos, R. S.; Blichert-Toft, J.; Vervoort, J.

    2003-03-01

    New U-Pb dates, combined with Nd and Hf isotopic data, from rocks within the Port Morvan area of the Baie de St Brieuc region of Brittany identify a unique portion of the Neoproterozoic Cadomia terrane. Two gneisses near Port Morvan yielded U-Pb dates of 754.6±0.8 Ma and 746.0±0.9 Ma, ages that are more than 130 Myr older than the oldest units formed during the main phase of early Cadomian magmatism. Two trondhjemite boulders from the monogenetic facies of the Cesson conglomerate yielded identical ages of 665.2±0.5 Ma and 665.5±0.7 Ma, and a cobble from the polygenetic facies yields a 207Pb- 206Pb date of 637±2 Ma. Individual detrital zircons from a sandstone associated with the Cesson conglomerates yield concordant U-Pb dates ranging from 650±3 Ma to 624.1±0.6 Ma. Initial ɛNd values for the rocks in this region range from +5.0 to +6.6, indicative of a substantial input from depleted mantle. Initial ɛHf values determined on zircons from these Neoproterozoic rocks, including the detrital zircons, range from +6.7 to +14.5, consistent with the Nd isotopic results. Maximum initial ɛHf values for two 2 Ga Icartian gneisses, considered basement to Cadomia, average +8.4 and +8.7. In contrast to the results of the Port Morvan rocks, 616-608 Ma syn-tectonic intrusions from Normandy and the British Channel Islands all have negative initial ɛNd values (-10.4 to -8.3) consistent with significant contamination by ancient crust such as the 2 Ga gneisses. The oldest arc-related magmas should have interacted most extensively with Cadomian basement, buffering younger mantle-derived magmas that were generated in subsequent magmatic episodes. The rocks within the Port Morvan region are thus inconsistent as examples of the earliest Cadomian intrusions as they show no evidence of interaction with 2 Ga basement. Instead, the older ages and mantle-like isotopic composition of these rocks suggest they are part of an independent terrane that formed prior to, and independently

  8. Gold in Accessory Zircon (the Kozhim Massif, Subpolar Urals)

    NASA Astrophysics Data System (ADS)

    Denisova, Yuliya; Pystin, Aleksandr

    2017-12-01

    The crystals of zircon due to their resistance to external impact of various processes can reveal information about the environment of their formation and the inclusions observed of them. Zircon contains different mineral inclusions: biotite, plagioclase, quartz, apatite, etc. However, there is no information about gold inclusions in the zircons from granites of the Sudpolar Urals. The study results of the inclusions of gold in accessory zircon of the Kozhim granitic massif are presented in this paper. The studied mineral is a dark-brown translucent short-prismatic crystal containing the inclusion of gold and the allocations of quartz. According to studies, the inclusion of gold formed during the growth of zircon and it is the gold covered with a thin film of oxide gold. It was confirmed that the crystallization of the studied zircon occurred at a temperature of 800°C and above on the stage of formation of granites of Kozhim massif. The assumption is made about the additional temperature in the course of which was caused by decreasing of temperature up to 700° C and below during postmagmatic stage.

  9. P-T-t conditions, Nd and Pb isotopic compositions and detrital zircon geochronology of the Massabesic Gneiss Complex, New Hampshire: isotopic and metamorphic evidence for the identification of Gander basement, central New England

    USGS Publications Warehouse

    Dorais, Michael J.; Wintsch, Robert P.; Kunk, Michael J.; Aleinikoff, John; Burton, William; Underdown, Christine; Kerwin, Charles M.

    2012-01-01

    We present new evidence for the assignment of the Neoproterozoic Massabesic Gneiss Complex of New Hampshire to the Gander terrane rather than the Avalon terrane. The majority of Avalonian (sensu stricto) igneous and meta-igneous rocks as defined in Maritime Canada have positive whole-rock ɛNd compared to more negative values for Gander rocks, although there is a region of overlap in ɛNd between the two terranes. Our samples from areas in Connecticut previously thought to be Avalonian and samples from the Willimantic dome have the same isotopic signatures as Maritime Canada Avalon. In contrast, samples from the Clinton dome of southern Connecticut plots exclusively in the Gander field. The majority of the orthogneiss samples from Lyme dome (coastal Connecticut), Pelham dome (central Massachusetts) and Massabesic Gneiss Complex also plot in the Gander field, with a few samples plotting in the overlap zone between Gander and Avalon. U-Pb age distributions of detrital zircon populations from quartzites from the Massabesic Gneiss Complex more closely approximate the data from the Lyme Dome rather than Avalon. Additionally, the similarity of the P-T-t path for the rocks of the Massabesic Gneiss Complex (established by thermobarometry and 40Ar/39Ar dating of amphibole, muscovite, biotite and K-feldspar) with that established in the Ganderian Lyme dome of southern Connecticut strengthens the assignment of these rocks to a single Gander block that docked to Laurentia during the Salinic Orogeny. The identification of Ganderian isotopic signatures for these rocks all of which show evidence for Alleghanian metamorphism, supports the hypothesis that Neoproterozoic Gander lower crustal rocks underlie southern New Hampshire, Massachusetts, and Connecticut, and that all rocks of the overlying Central Maine trough that largely escaped high-grade Alleghanian metamorphism are allochthonous. We suggest that during the Alleghanian, the docking of Gondwana caused Avalon to wedge into

  10. Improved zircon iron corals for the 1990s

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Decker, C.

    1992-03-01

    CIBA-GEIGY/Drakenfeld Colors is dedicated to the research and development of consistent and cost-effective ceramic stains for the whitewares industry. After identifying the trends in color for the 1990s. CIBA-GEIGY/Drakenfeld Colors initiated an extensive R D project to improve zircon ion corals for the whitewares industry. These color trends indicated a need for stronger and cleaner zircon iron corals. This paper discusses the chemistry and crystal structure of zircon iron corals. A historical review of Drakenfeld corals will also be presented. The most recent development in Drakenfeld corals will then be compared to other commercially available zircon iron corals. Taking intomore » consideration these comparisons, conclusions will be drawn suggesting the coral of choice for the 1990s.« less

  11. Twinning in Zircon: Not a High-Pressure Phenomenon

    NASA Astrophysics Data System (ADS)

    Jones, G. A.; Moser, D.; Shieh, S. R.; Barker, I.

    2017-12-01

    Microtwins in zircon are commonly found in shocked terrestrial and extraterrestrial samples and are potentially important for shock history and crater reconstruction. Twinning is easily observed with both the optical microscope and variety of electron beam techniques. Twinning as a deformation mechanism is consistent with the high strain rates generated during impact. No constitutive relationships, or even general limits on the physical conditions required for twinning in zircon are known, however. Present speculation on the critical quantity for twin formation, i.e. 10s of GPa of shock pressure (Moser et al. 2011, Timms et al., 2012), has no basis in the underlying mechanisms of twin nucleation, which are related to the motion of dislocations. This erroneous value is due to conflation of twinning sensu stricto with a phase transformation to reidite. Reidite occurs as twin-like lamellae occupying the {112} planes which are thought to be a mirror plane for twinning. We review the crystallographic theory of twinning in zircon. We then evaulate several theories on the nucleation of twins along with their necessary stresses involved. Our aim is to show that shock microtwins in zircon can be a `low pressure' shock phenomenon. This 'low pressure' hypothesis is supported by natural samples. These zircons are from the lower crust nearly 80 km from the centre of the Vredefort impact structure—the most distal zircon shock microstructures yet found in the lithosphere. Twins are present in 10% of the zircon grains greater than 50 µm in diameter. As an extensive, 'low pressure' phenomenon, twins are an easily recognized and potentially widespread record of Earth's impact history.Moser, D.E., Cupelli, C. L., Barker, I., Flowers, R. M., Mowman, J. R., Wooden, J. and Hart, R. (2011) New zircon shock phenomena and their use for dating and […] analysis of the Vredefort dome, Canadian Journal of Earth Sciences 48(2), 117-139.Timms, N.E., Reddy, S. M., Healy, D., Nemchin, A. A

  12. Detrital U-Pb zircon dating of lower Ordovician syn-arc-continent collision conglomerates in the Irish Caledonides

    USGS Publications Warehouse

    Clift, P.D.; Carter, A.; Draut, A.E.; Long, H.V.; Chew, D.M.; Schouten, H.A.

    2009-01-01

    The Early Ordovician Grampian Orogeny in the British Isles represents a classic example of collision between an oceanic island arc and a passive continental margin, starting around 480??Ma. The South Mayo Trough in western Ireland preserves a complete and well-dated sedimentary record of arc collision. We sampled sandstones and conglomerates from the Rosroe, Maumtrasna and Derryveeny Formations in order to assess erosion rates and patterns during and after arc collision. U-Pb dating of zircons reveals a provenance dominated by erosion from the upper levels of the Dalradian Supergroup (Southern Highland and Argyll Groups), with up to 20% influx from the colliding arc into the Rosroe Formation, but only 6% in the Maumtrasna Formation (~ 465??Ma). The dominant source regions lay to the northeast (e.g. in the vicinity of the Ox Mountains, 50??km distant, along strike). The older portions of the North Mayo Dalradian and its depositional basement (the Annagh Gneiss Complex) do not appear to have been important sources, while the Connemara Dalradian only plays a part after 460??Ma, when it supplies the Derryveeny Formation. By this time all erosion from the arc had effectively ceased and exhumation rates had slowed greatly. The Irish Grampian Orogeny parallels the modern Taiwan collision in showing little role for the colliding arc in the production of sediment. Negligible volumes of arc crust are lost because of erosion during accretion to the continental margin. ?? 2008 Elsevier B.V.

  13. Modeling effects of climate change and phase shifts on detrital production of a kelp bed.

    PubMed

    Krumhansl, Kira A; Lauzon-Guay, Jean-Sébastien; Scheibling, Robert E

    2014-03-01

    The exchange of energy and nutrients between ecosystems (i.e., resource subsidies) plays a central role in ecological dynamics over a range of spatial and temporal scales. Little attention has been paid to the role of anthropogenic impacts on natural systems in altering the magnitude, timing, and quality of resource subsidies. Kelp ecosystems are highly productive on a local scale and export over 80% of kelp primary production as detritus, subsidizing consumers across broad spatial scales. Here, we generate a model of detrital production from a kelp bed in Nova Scotia to hindcast trends in detrital production based on temperature and wave height recorded in the study region from 1976 to 2009, and to project changes in detrital production that may result from future climate change. Historical and projected increases in temperature and wave height led to higher rates of detrital production through increased blade breakage and kelp dislodgment from the substratum, but this reduced kelp biomass and led to a decline in detrital production in the long-term. We also used the model to demonstrate that the phase shift from a highly productive kelp bed to a low-productivity barrens, driven by the grazing activity of sea urchins, reduces kelp detrital production by several orders of magnitude, an effect that would be exacerbated by projected increases in temperature and wave action. These results indicate that climate-mediated changes in ecological dynamics operating on local scales may alter the magnitude of resource subsidies to adjacent ecosystems, affecting ecological dynamics on regional scales.

  14. Tectonic isolation from regional sediment sourcing of the Paradox Basin

    NASA Astrophysics Data System (ADS)

    Smith, T. M.; Saylor, J.; Sundell, K. E.; Lapen, T. J.

    2017-12-01

    The Appalachian and Ouachita-Marathon mountain ranges were created by a series of tectonic collisions that occurred through the middle and late Paleozoic along North America's eastern and southern margins, respectively. Previous work employing detrital zircon U-Pb geochronology has demonstrated that fluvial and eolian systems transported Appalachian-derived sediment across the continent to North America's Paleozoic western margin. However, contemporaneous intraplate deformation of the Ancestral Rocky Mountains (ARM) compartmentalized much of the North American western interior and mid-continent. We employ lithofacies characterization, stratigraphic thickness, paleocurrent data, sandstone petrography, and detrital zircon U-Pb geochronology to evaluate source-sink relationships of the Paradox Basin, which is one of the most prominent ARM basins. Evaluation of provenance is conducted through quantitative comparison of detrital zircon U-Pb distributions from basin samples and potential sources via detrital zircon mixture modeling, and is augmented with sandstone petrography. Mixing model results provide a measure of individual source contributions to basin stratigraphy, and are combined with outcrop and subsurface data (e.g., stratigraphic thickness and facies distributions) to create tectonic isolation maps. These maps elucidate drainage networks and the degree to which local versus regional sources influence sediment character within a single basin, or multiple depocenters. Results show that despite the cross-continental ubiquity of Appalachian-derived sediment, fluvial and deltaic systems throughout much of the Paradox Basin do not record their influence. Instead, sediment sourcing from the Uncompahgre Uplift, which has been interpreted to drive tectonic subsidence and formation of the Paradox Basin, completely dominated its sedimentary record. Further, the strong degree of tectonic isolation experienced by the Paradox Basin appears to be an emerging, yet common

  15. Detrital minerals from source to sink : tracing Orange River sand from Lesotho to Angola

    NASA Astrophysics Data System (ADS)

    Garzanti, Eduardo; Vermeesch, Pieter; Andò, Sergio; Resentini, Alberto; Vezzoli, Giovanni; Lustrino, Michele; Padoan, Marta; Pereira, Alcides

    2015-04-01

    Quantitative provenance analysis based on high-resolution bulk-petrography and heavy-mineral data on beach and dune sands, integrated with detrital-zircon geochronology and chemical analyses of pyroxene, garnet and staurolite, demonstrates that sand carried by the Orange River and derived from Lesotho and South Africa is carried by powerful and persistent longshore currents as far as southern Angola (Garzanti et al., 2014a). This is the longest cell of littoral sand transport documented so far on Earth, and a great test case for investigating physical controls on sand texture and composition. We have monitored textural, mineralogical and geochemical variability of beach and eolian-dune sands along a 1750 km stretch of the Atlantic coast of southern Africa by using an integrated set of techniques, including image analysis, laser granulometry, optical microscopy, Raman spectroscopy and bulk-sediment geochemistry (Garzanti et al., 2014b). Our results contrast with previous reports that feldspars and volcanic detritus break down during transport, that sand grains are rounded rapidly in shallow-marine environments, and that quartzose sands may be produced by physical processes alone. We demonstrate that basaltic rock fragments and pyroxenes, traditionally believed to be rapidly destroyed, survive healthily the 4000 km-long multistep hazardous journey from Lesotho volcanic highlands to Angola. Feldspar abundance remains remarkably constant from the Orange mouth to southern Angola, and quartz increases only very slightly, possibly as a result of local recycling. Among sedimentary and metasedimentary rock fragments, unconsolidated or strongly foliated types are readily comminuted when they enter the high-energy marine environment, but cemented sandstone/siltstone grains can survive the travel from the Karoo Basin of South Africa to northern Namibia and beyond. No detrital mineral displays a significant increase in grain roundness after 300-350 km of longshore transport in

  16. Is Myanmar jadeitite of Jurassic age? A result from incompletely recrystallized inherited zircon

    NASA Astrophysics Data System (ADS)

    Yui, Tzen-Fu; Fukoyama, Mayuko; Iizuka, Yoshiyuki; Wu, Chao-Ming; Wu, Tsai-Way; Liou, J. G.; Grove, Marty

    2013-02-01

    Zircons from two Myanmar jadeitite samples were separated for texture, mineral inclusion, U-Pb dating and trace element composition analyses. Three types of zircons, with respect to U-Pb isotope system, were recognized. Type I zircons are inherited ones, yielding an igneous protolith age of 160 ± 1 Ma; Type II zircons are metasomatic/hydrothermal ones, giving a (minimum) jadeitite formation age of 77 ± 3 Ma; and Type III zircons are incompletely recrystallized ones, with non-coherent and geologically meaningless ages from 153 to 105 Ma. These Myanmar jadeitites would therefore have formed through whole-sale metasomatic replacement processes. Compared with Type I zircons, Type II zircons show typical metasomatic/hydrothermal geochemical signatures, with low Th/U ratio (< 0.1), small Ce anomaly (Ce/Ce* = < 5) and low ΣREE content (40-115 ppm). Type III zircons, however, commonly have the above geochemical signatures straddle in between Type I and Type II zircons. It is shown that the resetting rates of various trace element compositions and U-Pb isotope system of inherited zircons are not coupled "in phase" in response to zircon recrystallization during jadeitite formation. The observed abnormally low Th/U ratio and small Ce anomaly of some Type I zircons, as well as the lack of negative Eu anomaly of all Type I zircons, should be suspected to be of secondary origin. In extreme cases, incompletely recrystallized zircons may show typical metasomatic/hydrothermal geochemical signatures, but leave U-Pb isotope system partially reset or even largely unchanged. Such zircons easily lead to incorrect age interpretation, and hence erroneous geological implication. The Myanmar jadeitites, based on the present study, might have formed during the Late Cretaceous subduction before the beginning of India-Asia continental collision at Paleocene. Previously proposed Late Jurassic ages for Myanmar jadeitites are suggested as results rooted on data retrieved from incompletely

  17. Determination of uranium in zircon

    USGS Publications Warehouse

    Cuttitta, F.; Daniels, G.J.

    1959-01-01

    A routine fluorimetric procedure is described for the determination of trace amounts of uranium in zircon. It employs the direct extraction of uranyl nitrate with ethyl acetate using phosphate as a retainer for zirconium. Submicrogram amounts or uranium are separated in the presence of 100,000 times the amount of zirconium. The modified procedure has been worked out using synthetic mixtures of known composition and zircon. Results of analyses have an accuracy of 97-98% of the contained uranium and a standard deviation of less than 2.5%. ?? 1959.

  18. Response of zircon to melting and metamorphism in deep arc crust, Fiordland (New Zealand): implications for zircon inheritance in cordilleran granites

    NASA Astrophysics Data System (ADS)

    Bhattacharya, Shrema; Kemp, A. I. S.; Collins, W. J.

    2018-04-01

    The Cretaceous Mount Daniel Complex (MDC) in northern Fiordland, New Zealand was emplaced as a 50 m-thick dyke and sheet complex into an active shear zone at the base of a Cordilleran magmatic arc. It was emplaced below the 20-25 km-thick, 125.3 ± 1.3 Ma old Western Fiordland Orthogneiss (WFO) and is characterized by metre-scale sheets of sodic, low and high Sr/Y diorites and granites. 119.3 ± 1.2 Ma old, pre-MDC lattice dykes and 117.4 ± 3.1 Ma late-MDC lattice dykes constrain the age of the MDC itself. Most dykes were isoclinally folded as they intruded, but crystallised within this deep-crustal, magma-transfer zone as the terrain cooled and was buried from 25 to 50 km (9-14 kbar), based on published P-T estimated from the surrounding country rocks. Zircon grains formed under these magmatic/granulite facies metamorphic conditions were initially characterized by conservatively assigning zircons with oscillatory zoning as igneous and featureless rims as metamorphic, representing 54% of the analysed grains. Further petrological assignment involved additional parameters such as age, morphology, Th/U ratios, REE patterns and Ti-in-zircon temperature estimates. Using this integrative approach, assignment of analysed grains to metamorphic or igneous groupings improved to 98%. A striking feature of the MDC is that only 2% of all igneous zircon grains reflect emplacement, so that the zircon cargo was almost entirely inherited, even in dioritic magmas. Metamorphic zircons of MDC show a cooler temperature range of 740-640 °C, reflects the moderate ambient temperature of the lower crust during MDC emplacement. The MDC also provides a cautionary tale: in the absence of robust field and microstructural relations, the igneous-zoned zircon population at 122.1 ± 1.3 Ma, derived mostly from inherited zircons of the WFO, would be meaningless in terms of actual magmatic emplacement age of MDC, where the latter is further obscured by younger (ca. 114 Ma) metamorphic overgrowths

  19. Assessment of Alternative [U] and [Th] Zircon Standards for SIMS

    NASA Astrophysics Data System (ADS)

    Monteleone, B. D.; van Soest, M. C.; Hodges, K.; Moore, G. M.; Boyce, J. W.; Hervig, R. L.

    2009-12-01

    The quality of in situ (U-Th)/He zircon dates is dependent upon the accuracy and precision of spatially distributed [U] and [Th] measurements on often complexly zoned zircon crystals. Natural zircon standards for SIMS traditionally have been used to obtain precise U-Pb ages rather than precise U and Th concentration. [U] and [Th] distributions within even the most homogeneous U-Pb age standards are not sufficient to make good microbeam standards (i.e., yield good precision: 2σ < 5%) for (U-Th)/He dates. In the absence of sufficiently homogeneous natural zircon crystals, we evaluate the use of the NIST 610 glass standard and a synthetic polycrystalline solid “zircon synrock” made by powdering and pressing natural zircon crystals at 2 GPa and 1100°C within a 13 mm piston cylinder for 24 hours. SIMS energy spectra and multiple spot analyses help assess the matrix-dependence of secondary ion emission and [U] and [Th] homogeneity of these materials. Although spot analyses on NIST 610 glass yielded spatially consistent ratios of 238U/30Si and 232Th/30Si (2σ = 2%, n = 14), comparison of energy spectra collected on glass and zircon reveal significant differences in U, UO, Th, and ThO ion intensities over the range of initial kinetic energies commonly used for trace element analyses. Computing [U] and [Th] in zircon using NIST glass yields concentrations that vary by more than 10% for [U] and [Th], depending on the initial kinetic energy and ion mass (elemental, oxide, or sum of elemental and oxide) used for the analysis. The observed effect of chemistry on secondary ion energy spectra suggests that NIST glass cannot be used as a standard for trace [U] and [Th] in zircon without a correction factor (presently unknown). Energy spectra of the zircon synrock are similar to those of natural zircon, suggesting matrix compatibility and therefore potential for accurate standardization. Spot analyses on the zircon powder pellets, however, show that adequate homogeneity of [U

  20. U-Th-Pb zircon ages of some Keweenawan Supergroup rocks from the south shore of Lake Superior

    USGS Publications Warehouse

    Zartman, R.E.; Nicholson, S.W.; Cannon, W.F.; Morey, G.B.

    1997-01-01

    New single-crystal zircon U-Th-Pb ages for plutonic and rhyolitic Keweenawan Supergroup rocks from the south shore of Lake Superior provide geochronological constraints on magmatic evolution associated with the 1.1 Ga Midcontinent rift. Analyses of a granophyric phase of the Mineral Lake intrusion and the Meilen granite, both parts of the Meilen Intrusive Complex, and a laterally extensive rhyolite from the top of the Kallander Creek Volcanics have weighted average 207Pb/206Pb ages of 1102.0 ?? 2.8 Ma (N = 2), 1100.9 ?? 1.4 Ma (N = 5), and 1098.8 ?? 1.9 Ma (N = 4), respectively. Analyses of a pyroclastic rhyolite flow at the top of the Porcupine Volcanics result in variable 207Pb/206Pb ages that range from 1080 to 1137 Ma. This rhyolite exhibits a continuum between morphologically complex and simpler prismatic zircon crystals, the latter yielding concordant analyses having a weighted average 207Pb/206Pb age of 1093.6 ?? 1.8 Ma (N = 2). Four prismatic zircons from an aphyric rhyolite of the Chengwatana Volcanics in the Ashland syncline form a linear array intersecting concordia at 1094.6 ?? 2.1 Ma (MSWD = 1.3). Another presumed Chengwatana rhyolite recovered from drill core intersecting the Hudson-Afton horst in southeast Minnesota yielded only ???20 morphologically indistinguishable zircons. Six analyses give 207Pb/206Pb ages ranging from 1112 to 1136 Ma, including one analysis with a virtually concordant age of 1130 Ma. This age, however, is considerably older than that obtained for the Chengwatana Volcanics in the Ashland syncline or any other precisely dated rock from the Midcontinent rift.

  1. Detrital rutile geochemistry and thermometry from the Dabie orogen: Implications for source-sediment links in a UHPM terrane

    NASA Astrophysics Data System (ADS)

    Liu, Lei; Xiao, Yilin; Wörner, G.; Kronz, A.; Simon, K.; Hou, Zhenhui

    2014-08-01

    This study explores the potential of detrital rutile geochemistry and thermometry as a provenance tracer in rocks from the Central Dabie ultrahigh-pressure metamorphic (UHPM) zone in east-central China that formed during Triassic continental collision. Trace element data of 176 detrital rutile grains selected from local river sediments and 91 rutile grains from distinct bedrocks in the Shuanghe and Bixiling areas, obtained by both electron microprobe (EMP) and in situ LA-ICP-MS analyses, suggest that geochemical compositions and thermometry of detrital rutiles are comparable to those from their potential source rocks. After certification of the Cr-Nb discrimination method for the Central Dabie UHPM zone, we show that 29% of the detrital rutiles in the Shuanghe area were derived from metamafic sources whereas in the Bixiling area that it is up to 76%. Furthermore, the proportion of distinct types of detrital rutiles combined with modal abundances of rutile in metapelites and metamafic bedrocks can be used to estimate the proportion of different source lithologies. Based on this method the proportion of mafic source rocks was estimated to ∼10% at Shuanghe and >60% at Bixiling, respectively, which is consistent with the proportions of eclogite (the major rutile-bearing metamafic rock) distribution in the field. Therefore, the investigation of detrital rutiles is a potential way to evaluate the proportion of metamafic rocks and even to prospect for metamafic bodies in UHPM terranes. Zr-in-rutile temperatures were calculated at different pressures and compared with temperatures derived from rock-in rutiles and garnet-clinopyroxene Fe-Mg thermometers. Temperatures calculated for detrital rutiles range from 606 °C to 707 °C and 566 °C to 752 °C in Shuanghe and Bixiling, respectively, at P = 3 GPa with an average temperatures of ca. 630 °C for both areas. These temperature averages and ranges are similar to those calculated for rutiles from surrounding source rocks

  2. Provenance of Cretaceous-Pliocene Clastic Sediments in the Tachira Saddle, Western Venezuela, and Implications for Sediment Dispersal Patterns in the Northern Andes

    NASA Astrophysics Data System (ADS)

    Gomez, Ali Ricardo

    Northwestern South America is highly deformed due to the transpressive plate boundary associated with complex interactions between the Caribbean plate, the South American plate, the Nazca plate and the Panama arc. Previous studies suggest that the Cenozoic uplift of the Merida Andes and Eastern Cordillera of Colombia affected sediment dispersal patterns in the region, shifting from a Paleocene foreland basin configuration to the modern isolated basins. Well-exposed Cretaceous to Pliocene strata in the Tachira Saddle provides a unique opportunity to test proposed sediment dispersal patterns in the region. U-Pb detrital zircon geochronology and supplementary XRD heavy mineral data are used together to document the provenance of the Tachira Saddle sediments and refine the sediment dispersal patterns in the region. Results from the U-Pb detrital zircon geochronology show that there are six age groups recorded in these samples. Two groups are related to the Precambrian Guyana shield terranes and Putumayo basement in the Eastern Cordillera, and four groups are related to different magmatic episodes occurring during the Andean orogenic process. The transition between the Cretaceous passive margin and the Paleocene foreland basin and the initial uplift of the Eastern Cordillera and the uplift of the Merida Andes by the Early Miocene were also recorded in the Tachira saddle detrital zircon signature.

  3. Zircons as a Probe of Early Luanr History

    NASA Astrophysics Data System (ADS)

    Crow, C. A.; McKeegan, K. D.; Gilmour, J. D.; Crowther, S. A.; Talor, D. J.

    2013-09-01

    Zircons are ideal for investigating the early lunar bombardment because we can measure both U-Pb crystallization ages and fissiongenic Xe degassing ages for the same crystal. We report U-Pb, Pb-Pb and U-Xe ages for three lunar zircons.

  4. Whole-rock Pb and Sm-Nd isotopic constraints on the growth of southeastern Laurentia during Grenvillian orogenesis

    USGS Publications Warehouse

    Fisher, C.M.; Loewy, S.L.; Miller, C.F.; Berquist, P.; Van Schmus, W. R.; Hatcher, R.D.; Wooden, J.L.; Fullagar, P.D.

    2010-01-01

    The conventional view that the basement of the southern and central Appalachians represents juvenile Mesoproterozoic crust, the final stage of growth of Laurentia prior to Grenville collision, has recently been challenged. New whole-rock Pb and Sm-Nd isotopic data are presented from Meso protero zoic basement in the southern and central Appalachians and the Granite-Rhyolite province, as well as one new U-Pb zircon age from the Granite-Rhyolite province. These data, combined with existing data from Mesoproterozoic terranes throughout southeastern Laurentia, further substantiate recent suggestions that the southern and central Appalachian basement is exotic with respect to Laurentia. Sm-Nd isotopic compositions of most rocks from the southern and central Appalachian basement are consistent with progressive growth through reworking of the adjacent Granite-Rhyolite province. However, Pb isotopic data, including new analyses from important regions not sampled in previous studies, do not correspond with Pb isotopic compositions of any adjacent crust. The most distinct ages and isotopic compositions in the southern and central Appalachian basement come from the Roan Mountain area, eastern Tennessee-western North Carolina. The data set indicates U-Pb zircon ages up to 1.8 Ga for igneous rocks, inherited and detrital zircon ages >2.0 Ga, Sm-Nd depleted mantle model (TDM) ages >2.0 Ga, and the most elevated 207Pb/204Pb observed in southeastern Laurentia. The combined U-Pb geochronologic and Sm-Nd and Pb isotopic data preclude derivation of southern and central Appalachian basement from any nearby crustal material and demonstrate that Grenville age crust in southeastern Laurentia is exotic and probably was transferred during collision and assembly of Rodinia. These new data better define the boundary between the exotic southern and central Appalachian basement and adjacent Laurentian Granite-Rhyolite province. ?? 2010 Geological Society of America.

  5. High Pressure Behavior of Zircon at Room Temperature

    NASA Astrophysics Data System (ADS)

    Reichmann, H. J.; Rocholl, A.

    2016-12-01

    Zircon, ZrSiO4, is an ubiquitous mineral in the Earth's crust, forming under a wide range of metamorphic and igneous conditions. Its high content in certain trace elements (REE, Hf, Th, U) and due to its isotopic information, together with its chemical and physical robustness makes zircon an unique geochemical tool and geochronometer. Despite its geological importance there is a disagreement regarding the responds of zircon to elevated pressure, especially about the commencement of a pressure - induced structural phase transition. At elevated pressure zircon (I41/amd) undergoes a pressure induced phase transition to the scheelite structure (I41/a) . In the low pressure and high pressure phase, the (SiO4)4- tetrahedral units are present. However, the onset of the phase transition at room temperature is not well defined: zircon - scheelite transitions have been reported in a pressure regime ranging from 20 to 30 GPa (e.g. Ono et al., 2004). To clarify this issue, we performed Raman spectroscopy measurement up to 60 GPa on a non-metamict single crystal zircon sample (reference material 91500; Wiedenbeck et al., 1995; Wiedenbeck et al., 2004). A closer look at the external lattice modes at 201 cm-1 shows a decreasing of the wavenumbers with increasing pressure up to 21 GPa followed by a steep increase. The lattice modes at 213 and 224 cm-1 also exhibit a subtle kink in this pressure range. This pressure coincides with that one reported for the zircon - scheelite transition (van Westrenen et al., 2004). Another interesting issue is the behavior of the internal modes at higher pressures. The ν3 stretching modes at about 1000 cm-1show distinct discontinuities at 31 GPa accompanied by the emerging of new features in the Raman spectrum suggesting another, pressure triggered modification in the zircon structure. References: Ono, Funakoshi, Nakajima, Tange, and Katsura (2004) Contr. Mineral. Petrol., 147, 505-509. Van Westrenen, Frank, Hanchar, Fei, Finch, and Zha (2004

  6. Contributions of detrital subsidies to aboveground spiders during secondary succession, revealed by radiocarbon and stable isotope signatures.

    PubMed

    Haraguchi, Takashi F; Uchida, Masao; Shibata, Yasuyuki; Tayasu, Ichiro

    2013-04-01

    Prey subsidies originating from detritus add nutrients and energy to arboreal communities. Measurement of this subsidy is required in the understanding of how food web dynamics respond to changes in surrounding environments. Shrub spiders are one of the key predators involved in food web coupling. We evaluate the effects of potential changes in prey availabilities during secondary succession on the contribution of subsidy from detrital food webs to shrub spiders and how different spider feeding guilds used the subsidy of prey from detrital food webs. We measured the relative importance of the subsidy for the spider feeding guilds, using the ratios of stable isotopes of C (δ(13)C), and N (δ(15)N) and C isotope discrimination (Δ(14)C). Diet age was calculated from Δ(14)C values, because old diet ages of spiders indicate that the spiders consume prey from detrital food sources. Dominant aerial prey (Diptera) had a distinctively old diet age compared with arboreal prey, which indicates that aerial prey were subsidized from detrital food webs. Sit-and-wait spiders tended to have an older diet age than active hunting spiders, which indicates that sit-and-wait spiders depended more on subsidies. Diet age varied only slightly for spiders in stands of different ages, indicating that rates at which spiders use grazing and detrital prey are probably determined more by foraging strategies and not by stand age. A dominance of sit-and-wait predators will lead to higher detrital subsidy inputs in shrub habitats. This study highlights the effect of shrub spider community structure (feeding guild composition) on the volume of the subsidy received from the detrital food web.

  7. Unravelling the pre-Variscan evolution of the Habach terrane (Tauern Window, Austria) by U-Pb SHRIMP zircon data

    NASA Astrophysics Data System (ADS)

    Eichhorn, Roland; Loth, Georg; Kennedy, Allen

    2001-08-01

    The U-Pb SHRIMP age determinations of zircons from the Habach terrane (Tauern Window, Austria) reveal a complex evolution of this basement unit, which is exposed in the Penninic domain of the Alpine orogen. The oldest components are found in zircons of a metamorphosed granitoid clast, of a migmatitic leucosome, and of a meta-rhyolitic (Variscan) tuff which bear cores of Archean age. The U-Pb ages of discordant zircon cores of the same rocks range between 540 and 520 Ma. It is assumed that the latter zircons were originally also of Archean origin and suffered severe lead loss, whilst being incorporated into Early-Cambrian volcanic arc magmas. The provenance region of the Archean (2.64-2.06 Ga) zircons is assumed to be a terrane of Gondwana affinity: i.e., the West African craton (Hoggar Shield, Reguibat Shield). The Caledonian metamorphism left a pervasive structural imprint in amphibolite facies on rocks of the Habach terrane; it is postdated by discordant zircons of a migmatitic leucosome at <440 Ma (presumably ca. 420 Ma). Alpine and Variscan upper greenschist- to amphibolite-facies conditions caused partial lead loss in zircons of a muscovite gneiss ('white schist') only, where extensive fluid flow and brittle deformation due to its position near a nappe-sole thrust enhanced the grains' susceptibility to isotopic disturbance. The Habach terrane - an active continental margin with ensialic back-arc development - showed subduction-induced magmatic activity approx. between 550 and 507 Ma. Back-arc diorites and arc basalts were intruded by ultramafic sills and subsequently by small patches of mantle-dominated unaltered and (in the vicinity of a major tungsten deposit) altered granitoids. Fore-arc (shales) and back-arc (greywackes, cherts) basin sediments as well as arc and back-arc magmatites were not only nappe-stacked by the Caledonian compressional regime closing the presumably narrow oceanic back-arc basin and squeezing mafic to ultramafic cumulates out of high

  8. Paleoproterozoic (ca. 1.8 Ga) arc magmatism in the Lützow-Holm Complex, East Antarctica: Implications for crustal growth and terrane assembly in erstwhile Gondwana fragments

    NASA Astrophysics Data System (ADS)

    Takahashi, Kazuki; Tsunogae, Toshiaki; Santosh, M.; Takamura, Yusuke; Tsutsumi, Yukiyasu

    2018-05-01

    The Lützow-Holm Complex (LHC) of East Antarctica forms a part of the latest Neoproterozoic-Cambrian high-grade metamorphic segment of the East African-Antarctic Orogen. Here we present new petrological, geochemical, and zircon U-Pb geochronological data on meta-igneous rocks from four localities (Austhovde, Telen, Skallevikshalsen, and Skallen) in the LHC, and evaluate the regional Paleoproterozoic (ca. 1.8 Ga) arc magmatism in this terrane for the first time. The geochemical features reveal a volcanic-arc affinity for most of the meta-igneous rocks from Austhovde and Telen, suggesting that the protoliths of these rocks were derived from felsic to mafic arc magmatic rocks. The protoliths of two mafic granulites from Austhovde are inferred as non-volcanic-arc basalt such as E-MORB, suggesting the accretion of remnant oceanic lithosphere together with the volcanic-arc components during the subduction-collision events. The weighted mean 206Pb/238U ages of the dominant population of magmatic zircons in felsic orthogneisses from Austhovde and Telen show 1819 ± 19 Ma and 1830 ± 10 Ma, respectively, corresponding to Paleoproterozoic magmatic event. The magmatic zircons in orthogneisses from other two localities yield upper intercept ages of 1837 ± 54 Ma (Skallevikshalsen), and 1856 ± 37 Ma and 1854 ± 45 Ma (Skallen), which also support Paleoproterozoic magmatism. The earlier thermal events during Neoarchean to Early Paleoproterozoic are also traced by 206Pb/238U ages of xenocrystic zircons in the felsic orthogneisses from Austhovde (2517 ± 17 Ma and 2495 ± 15 Ma) and Telen (2126 ± 16 Ma), suggesting partial reworking of the basement of a 2.5 Ga microcontinent during ca. 1.8 Ga continental-arc magmatism. The timing of peak metamorphism is inferred to be in the range of 645.6 ± 10.4 to 521.4 ± 12.0 Ma based on 206Pb/238U weighted mean ages of metamorphic zircon grains. The results of this study, together with the available magmatic ages as well as geophysical and

  9. Empirical constraints on the effects of radiation damage on helium diffusion in zircon

    NASA Astrophysics Data System (ADS)

    Anderson, Alyssa J.; Hodges, Kip V.; van Soest, Matthijs C.

    2017-12-01

    In this study, we empirically evaluate the impact of radiation damage on zircon (U-Th)/He closure temperatures for a suite of zircon crystals from the slowly cooled McClure Mountain syenite of south-central Colorado, USA. We present new zircon, titanite, and apatite conventional (U-Th)/He dates, zircon laser ablation (U-Th)/He and U-Pb dates, and zircon Raman spectra for crystals from the syenite. Titanite and apatite (U-Th)/He dates range from 447 to 523 Ma and 88.0 to 138.9 Ma, respectively, and display no clear correlation between (U-Th)/He date and effective uranium concentration. Conventional zircon (U-Th)/He dates range from 230.3 to 474 Ma, while laser ablation zircon (U-Th)/He dates show even greater dispersion, ranging from 5.31 to 520 Ma. Dates from both zircon (U-Th)/He datasets decrease with increasing alpha dose, indicating that most of the dispersion can be attributed to radiation damage. Alpha dose values for the dated zircon crystals range from effectively zero to 2.15 × 1019 α /g, spanning the complete damage spectrum. We use an independently constrained thermal model to empirically assign a closure temperature to each dated zircon grain. If we assume that this thermal model is robust, the zircon radiation damage accumulation and annealing model of Guenthner et al. (2013) does not accurately predict closure temperatures for many of the analyzed zircon crystals. Raman maps of the zircons dated by laser ablation document complex radiation damage zoning, sometimes revealing crystalline zones in grains with alpha dose values suggestive of amorphous material. Such zoning likely resulted in heterogeneous intra-crystalline helium diffusion and may help explain some of the discrepancies between our empirical findings and the Guenthner et al. (2013) model predictions. Because U-Th zoning is a common feature in zircon, radiation damage zoning is likely to be a concern for most ancient, slowly cooled zircon (U-Th)/He datasets. Whenever possible, multiple

  10. Pore structure characterization of Chang-7 tight sandstone using MICP combined with N2GA techniques and its geological control factors

    NASA Astrophysics Data System (ADS)

    Cao, Zhe; Liu, Guangdi; Zhan, Hongbin; Li, Chaozheng; You, Yuan; Yang, Chengyu; Jiang, Hang

    2016-11-01

    Understanding the pore networks of unconventional tight reservoirs such as tight sandstones and shales is crucial for extracting oil/gas from such reservoirs. Mercury injection capillary pressure (MICP) and N2 gas adsorption (N2GA) are performed to evaluate pore structure of Chang-7 tight sandstone. Thin section observation, scanning electron microscope, grain size analysis, mineral composition analysis, and porosity measurement are applied to investigate geological control factors of pore structure. Grain size is positively correlated with detrital mineral content and grain size standard deviation while negatively related to clay content. Detrital mineral content and grain size are positively correlated with porosity, pore throat radius and withdrawal efficiency and negatively related to capillary pressure and pore-to-throat size ratio; while interstitial material is negatively correlated with above mentioned factors. Well sorted sediments with high debris usually possess strong compaction resistance to preserve original pores. Although many inter-crystalline pores are produced in clay minerals, this type of pores is not the most important contributor to porosity. Besides this, pore shape determined by N2GA hysteresis loop is consistent with SEM observation on clay inter-crystalline pores while BJH pore volume is positively related with clay content, suggesting N2GA is suitable for describing clay inter-crystalline pores in tight sandstones.

  11. The pre-Atlantic Hf isotope evolution of the east Laurentian continental margin: Insights from zircon in basement rocks and glacial tillites from northern New Jersey and southeastern New York

    NASA Astrophysics Data System (ADS)

    Zirakparvar, N. Alex; Setera, Jacob; Mathez, Edmond; Vantongeren, Jill; Fossum, Ryanna

    2017-02-01

    This paper presents laser ablation U-Pb age and Hf isotope data for zircons from basement rocks and glacial deposits in northern New Jersey and southeastern New York. The purpose is to understand the eastern Laurentian continental margin's Hf isotope record in relation to its geologic evolution prior to the opening of the Atlantic Ocean. The basement samples encompass a Meso- to Neoproterozoic continental margin arc, an anatectic magmatic suite, as well as a Late Ordovician alkaline igneous suite emplaced during post-orogenic melting of the lithospheric mantle. Additional samples were collected from terminal moraines of two Quaternary continental ice sheets. Across the entire dataset, zircons with ages corresponding to the timing of continental margin arc magmatism ( 1.4 Ga to 1.2 Ga) have positive εHf(initial) values that define the more radiogenic end of a crustal evolution array. This array progresses towards more unradiogenic εHf(initial) values along a series of low 176Lu/177Hf (0.022 to 0.005) trajectories during subsequent anatectic magmatism ( 1.2 Ga to 1.0 Ga) and later metamorphic and metasomatic re-working ( 1.0 Ga to 0.8 Ga) of the continental margin arc crust. In contrast, nearly chondritic εHf(initial) values from the Late Ordovician alkaline magmas indicate that the Laurentian margin was underlain by a re-fertilized mantle source. Such a source may have developed by subduction enrichment of the mantle wedge beneath the continental margin during the Mesoproterozoic. Additionally, preliminary data from a metasedimentary unit of unknown provenance hints at the possibility that some of the sediments occupying this portion of the Laurentian margin prior to the Ordovician were sourced from crust older than 1.9 Ga.

  12. Contrasting Granite Metallogeny through the Zircon Record: A Case Study from Myanmar.

    PubMed

    Gardiner, Nicholas J; Hawkesworth, Chris J; Robb, Laurence J; Whitehouse, Martin J; Roberts, Nick M W; Kirkland, Christopher L; Evans, Noreen J

    2017-04-07

    Granitoid-hosted mineral deposits are major global sources of a number of economically important metals. The fundamental controls on magma metal fertility are tectonic setting, the nature of source rocks, and magma differentiation. A clearer understanding of these petrogenetic processes has been forged through the accessory mineral zircon, which has considerable potential in metallogenic studies. We present an integrated zircon isotope (U-Pb, Lu-Hf, O) and trace element dataset from the paired Cu-Au (copper) and Sn-W (tin) magmatic belts in Myanmar. Copper arc zircons have juvenile εHf (+7.6 to +11.5) and mantle-like δ 18 O (5.2-5.5‰), whereas tin belt zircons have low εHf (-7 to -13) and heavier δ 18 O (6.2-7.7‰). Variations in zircon Hf and U/Yb reaffirm that tin belt magmas contain greater crustal contributions than copper arc rocks. Links between whole-rock Rb/Sr and zircon Eu/Eu* highlight that the latter can monitor magma fractionation in these systems. Zircon Ce/Ce* and Eu/Eu* are sensitive to redox and fractionation respectively, and here are used to evaluate zircon sensitivity to the metallogenic affinity of their host rock. Critical contents of Sn in granitic magmas, which may be required for the development of economic tin deposits, are marked by zircon Eu/Eu* values of ca. ≤0.08.

  13. Biogenic magnetite, detrital hematite, and relative paleointensity in Quaternary sediments from the Southwest Iberian Margin

    NASA Astrophysics Data System (ADS)

    Channell, J. E. T.; Hodell, D. A.; Margari, V.; Skinner, L. C.; Tzedakis, P. C.; Kesler, M. S.

    2013-08-01

    Magnetic properties of late Quaternary sediments on the SW Iberian Margin are dominated by bacterial magnetite, observed by transmission electron microscopy (TEM), with contributions from detrital titanomagnetite and hematite. Reactive hematite, together with low organic matter concentrations and the lack of sulfate reduction, lead to dissimilatory iron reduction and availability of Fe(II) for abundant magnetotactic bacteria. Magnetite grain-size proxies (κARM/κ and ARM/IRM) and S-ratios (sensitive to hematite) vary on stadial/interstadial timescales, contain orbital power, and mimic planktic δ18O. The detrital/biogenic magnetite ratio and hematite concentration are greater during stadials and glacial isotopic stages, reflecting increased detrital (magnetite) input during times of lowered sea level, coinciding with atmospheric conditions favoring hematitic dust supply. Magnetic susceptibility, on the other hand, has a very different response being sensitive to coarse detrital multidomain (MD) magnetite associated with ice-rafted debris (IRD). High susceptibility and/or magnetic grain-size coarsening, mark Heinrich stadials (HS), particularly HS2, HS3, HS4, HS5, HS6 and HS7, as well as older Heinrich-like detrital layers, indicating the sensitivity of this region to fluctuations in the position of the polar front. Relative paleointensity (RPI) records have well-constrained age models based on planktic δ18O correlation to ice-core chronologies, however, they differ from reference records (e.g. PISO) particularly in the vicinity of glacial maxima, mainly due to inefficient normalization of RPI records in intervals of enhanced hematite input.

  14. Closure of Tethys and early stages of Himalayan evolution: constraints from the detrital record, Ladakh, India

    NASA Astrophysics Data System (ADS)

    Jenks, D.; Najman, Y.; Godin, L.; Parrish, R.; Horstwood, M.; Green, O.; Bown, P.; Garzanti, E.; Willems, H.

    2009-04-01

    Closure of Tethys marks initiation of collision between India and Asia, and the start of Himalayan orogenesis. A clear understanding of when this occurred is paramount to understanding the tectonic and denudational processes that have occurred since collision. A number of methods and datasets have been used to constrain the initiation of collision, from faunal mixing at 65 Ma [1] to the timing at which Indian rocks reached UHP depths at 57 Ma [2], to a reduction in northward drift of the Indian plate at 55 Ma [3]. New interpretations have placed collision as late as 38 Ma [4]. The extent of diachroneity is also disputed, varying from slight [5] to substantial [6]. Two approaches are used here to determine collision, 1) the timing of closure of the Tethys Ocean [7], based on stratigraphic succession, 2) first evidence of Asian derived material deposited on the Indian plate [8], using U-Pb ages of detrital zircon to assess provenance. In Ladakh, Indian plate passive margin limestones of the Mid-Late Paleocene Dibling Formation [9] are overlain by the youngest marine facies of the region, the marine siltstones of the Kong Fm. and the fluvio-deltaic facies of the Chulung La Fm. [8]. The age of the Kong and Chulung La formations is disputed, ranging from P5/6 (56 Ma) [10] to P8 (50.5 Ma) [8]. The provenance is also debated, considered either to be eroded from ophiolitic material from the Indian plate [10] or containing detritus from the Trans-Himalayan arc of the Asian plate [8,11]. We applied biostratigraphy, and U-Pb dating on detrital zircon, to samples from the Kong and Chulung La Formations to define depositional age and provenance. Biostratigraphy identified Asselines A. placentula grande and A. pomeroli, from the SBZ 10 (50.5 to 52.5 Ma) and SBZ 9 (53 Ma) zones respectively, thereby defining a minimum age of collision at 50.5 Ma, based on cessation of marine facies. However, the possibility that these fossils are reworked will be discussed. U-Pb dating of

  15. Detrital illite crystals identified from crystallite thickness measurements in siliciclastic sediments

    USGS Publications Warehouse

    Aldega, L.; Eberl, D.D.

    2005-01-01

    Illite crystals in siliciclastic sediments are heterogeneous assemblages of detrital material coming from various source rocks and, at paleotemperatures >70 ??C, of superimposed diagenetic modification in the parent sediment. We distinguished the relative proportions of 2M1 detrital illite and possible diagenetic 1Md + 1M illite by a combined analysis of crystal-size distribution and illite polytype quantification. We found that the proportions of 1Md + 1M and 2M1 illite could be determined from crystallite thickness measurements (BWA method, using the MudMaster program) by unmixing measured crystallite thickness distributions using theoretical and calculated log-normal and/or asymptotic distributions. The end-member components that we used to unmix the measured distributions were three asymptotic-shaped distributions (assumed to be the diagenetic component of the mixture, the 1Md + 1M polytypes) calculated using the Galoper program (Phase A was simulated using 500 crystals per cycle of nucleation and growth, Phase B = 333/cycle, and Phase C = 250/ cycle), and one theoretical log-normal distribution (Phase D, assumed to approximate the detrital 2M1 component of the mixture). In addition, quantitative polytype analysis was carried out using the RockJock software for comparison. The two techniques gave comparable results (r2 = 0.93), which indicates that the unmixing method permits one to calculate the proportion of illite polytypes and, therefore, the proportion of 2M1 detrital illite, from crystallite thickness measurements. The overall illite crystallite thicknesses in the samples were found to be a function of the relative proportions of thick 2M1 and thin 1Md + 1M illite. The percentage of illite layers in I-S mixed layers correlates with the mean crystallite thickness of the 1Md + 1M polytypes, indicating that these polytypes, rather than the 2M1 polytype, participate in I-S mixed layering.

  16. Detrital sources and water mass circulation in the tropical North Atlantic during the Late Cretaceous to Paleogene

    NASA Astrophysics Data System (ADS)

    Martin, E. E.; Pugh, E.; Kamenov, G. D.; MacLeod, K. G.

    2014-12-01

    Seawater Nd isotopes from fossil fish teeth in Campanian to Paleogene calcareous claystone on Demerara Rise in the tropical North Atlantic record a change from epsilon Nd values of -17 to -11 during the late Maastrichtian. This shift has been identified in three different Ocean Drilling Program (ODP) sites that span from 600 to 1500 m paleodepths (ODP sites 1259, 1260 and 1261) and has been interpreted as a transition from a warm saline intermediate water mass formed on the South American margin, referred to as Demerara Bottom Water, to a source from the North Atlantic. A study of corresponding detrital Sr, Nd and Pb isotopes was undertaken to confirm the isotopic values derived from fish teeth record water mass compositions rather than diagenesis or boundary exchange. Several leaching procedures designed to remove Fe-Mn oxide coatings and the seawater signature they carry from the detrital fractions were tested. Sr isotopic data indicate a 0.02 M hydroxylamine hydrochloride (HH) leach was ineffective at removing the Fe-Mn oxides whereas a 1.0 M HH leach produced detrital Sr isotopic values that were consistent for all three sites and plotted farther from the seawater value. Detrital isotopic results can be divided into three intervals: 1) 73 - 66 Ma, when DBW is present, 2) 66 - 61 Ma, during the transition to North Atlantic sources, and 3) <61 Ma, when North Atlantic sources appear to dominate. During interval 1, detrital Nd isotopes increase gradually, while Sr and Pb isotopic ratios are relatively constant. Leading into interval 2, detrital Nd isotopes are fairly constant while there is a stepwise increase in Sr and Pb isotopes. Leading into interval 3, there is a large increase in Nd and decrease in Sr isotopes and a slight decrease in Pb isotopes. The subtle differences in the timing of changes in fish teeth and detrital Nd isotopes suggest the seawater signal is responding to changes in water mass rather than changes in sediment composition (boundary

  17. Zircons as a Probe of Early Lunar Impact History

    NASA Astrophysics Data System (ADS)

    Crow, C. A.; McKeegan, K. D.; Gilmour, J. D.; Crowther, S. A.; Taylor, D. J.

    2013-08-01

    Zircons are ideal for investigating the early lunar bombardment because we can measure both U-Pb crystallization ages and fissiongenic Xe degassing ages for the same crystal. We report U-Pb, Pb-Pb and U-Xe ages for two lunar zircons.

  18. U-Pb zircon geochronologycal investigation on the Morro dos Seis Lagos Carbonatite Complex and associated Nb deposit (Amazonas, Brazil)

    NASA Astrophysics Data System (ADS)

    Rossoni, Marco B.; Bastos Neto, Artur C.; Souza, Valmir S.; Marques, Juliana C.; Dantas, Elton; Botelho, Nilson F.; Giovannini, Arthur L.; Pereira, Vitor P.

    2017-12-01

    We present results of U-Pb dating (by MC-ICP-MS) of zircons from samples that cover all of the known lithotypes in the Seis Lagos Carbonatite Complex and associated lateritic mineralization (the Morro dos Seis Lagos Nb deposit). The host rock (gneiss) yielded an age of 1828 ± 09 Ma interpreted as the crystallization time of this unit. The altered feldspar vein in the same gneiss yielded an age of 1839 ± 29 Ma. Carbonatite samples provided 3 groups of ages. The first group comprises inherited zircons with ages compatible with the gneissic host rock: 1819 ± 10 Ma (superior intercept), 1826 ± 5 Ma (concordant age), and 1812 ± 27 Ma (superior intercept), all from the Orosirian. The second and the third group of ages are from the same carbonatite sample: the superior intercept age of 1525 ± 21 Ma (MSWD = 0.77) and the superior intercept age of 1328 ± 58 Ma (MSWD = 1.4). The mineralogical study indicates that the ∼1.3 Ga zircons have affinity with carbonatite. It is, however, a tendence rather than a well-defined result. The data allow state that the age of 1328 ± 58 Ma represents the maximum age of the carbonatite. Without the same certainty, we consider that the data suggest that this age may be the carbonatite age, whose emplacement would have been related to the evolution of the K'Mudku belt. The best age obtained in laterite samples (a superior intercept age of 1828 ± 12 Ma) is considered the age of the main source for the inherited zircons related to the gneissic host rock.

  19. Crystallization process of zircon and fergusonite during hydrothermal alteration in Nechalacho REE deposit, Thor Lake, Canada

    NASA Astrophysics Data System (ADS)

    Hoshino, M.; Watanabe, Y.; Murakami, H.; Kon, Y.; Tsunematsu, M.

    2012-04-01

    The core samples of two drill holes, which penetrate sub-horizontal mineralized horizons at Nechalacho REE deposit in the Proterozoic Thor Lake syenite, Canada, were studied in order to clarify magmatic and hydrothermal processes that enriched HFSE (e.g. Zr, Nb, Y and REE). Zircon is the most common REE minerals in Nechalacho REE deposit. The zircon is divided into five types as follows: Type-1 zircon occurs as single grain in phlogopite and the chondrite-normalized REE pattern is characterized by a steeply-rising slope from the LREE to the HREE with a positive Ce-anomaly and negative Eu-anomaly. This chemical characteristic is similar to that of igneous zircon. Type-2 zircon consists of HREE-rich magmatic porous core and LREE-Nb-F-rich hydrothermal rim. This type zircon is mostly included in phlogopite and fluorite, and occasionally in microcline. Type-3 zircon is characterized by euhedral to anhedral crystal, occurring in a complex intergrowth with REE fluorocarbonates. Type-3 zircons have high contents of REE, Nb and fluorine. Type-4 zircon consists of porous-core and -rim zones, but their chemical compositions are similar to each other. This type zircon is a subhedral crystal rimmed by fergusonite. Type-5 zircon is characterized by smaller, porous and subhedral to anhedral crystals. The interstices between small zircons are filled by fergusonite. Type-4 and -5 zircons show low REE and Nb contents. Occurrences of these five types of zircon are different according to the depth and degree of the alteration by hydrothermal solutions rich in F- and CO3 of the two drill holes, which permit a model for evolution of the zircon crystallization in Nechalacho REE deposit as follows: (1) type-1 (single magmatic zircon) is formed in miaskitic syenite. (2) LREE-Nb-F-rich hydrothermal zircon formed around HREE-rich magmatic zircon (type-2 zircon); (3) type-3 zircon crystallized thorough F and CO3-rich hydrothermal alteration of type-2 zircon which formed the complex

  20. Experimental shock deformation in zircon: a transmission electron microscopic study

    NASA Astrophysics Data System (ADS)

    Leroux, H.; Reimold, W. U.; Koeberl, C.; Hornemann, U.; Doukhan, J.-C.

    1999-06-01

    In recent years, apparently shock-induced and, thus, impact-characteristic microdeformations, in the form of planar microdeformation features and so-called strawberry (granular) texture, have been observed in zircons in rocks from confirmed impact structures and from the K/ T boundary. The nature of the planar microdeformations in this mineral is, however, still unknown, and critical information is needed regarding the shock pressure range in which these deformation effects are produced. We experimentally shock deformed two series of thin zircon (ZrSiO 4) target plates, cut perpendicular to the c-axis, at shock pressures of 20, 40, and 60 GPa. The recovered samples were characterized by optical and scanning electron microscopy. In addition, one sample series was studied by transmission electron microscopy (TEM). Microdeformation effects observed at 20 GPa include pervasive micro-cleavage and dislocation patterns. Plastic deformation is indicated by a high density of straight dislocations in glide configuration. The dominant glide systems are <100>{010}. Micro-cleavages, induced by shear stresses during the compression stage, occur mostly in the {100} planes. The large density of dislocations at crack tips shows that plastic deformation was initiated by the micro-cracking processs. At 40 GPa, the sample was partly transformed from the zircon (z) to a scheelite (CaWO 4)-type (s) structure. Planar deformation features (PDFs) containing an amorphous phase of zircon composition are present in the not yet transformed zircon relics. The phase with scheelite structure, initiated in the {100} planes of zircon, consists of thin (0.1 to several μm) bands that crosscut the zircon matrix. The phase transformation is displacive (martensitic) and can be related by {100} z // {112} s and [001] z // <110> s. The scheelite structure phase is densely twinned, with twins in the (112) plane. The 60-GPa sample consists completely of the scheelite structure phase. Crosscutting and

  1. Effects of Detrital Subsidies on Soft-Sediment Ecosystem Function Are Transient and Source-Dependent.

    PubMed

    Gladstone-Gallagher, Rebecca V; Lohrer, Andrew M; Lundquist, Carolyn J; Pilditch, Conrad A

    2016-01-01

    Detrital subsidies from marine macrophytes are prevalent in temperate estuaries, and their role in structuring benthic macrofaunal communities is well documented, but the resulting impact on ecosystem function is not understood. We conducted a field experiment to test the effects of detrital decay on soft-sediment primary production, community metabolism and nutrient regeneration (measures of ecosystem function). Twenty four (2 m2) plots were established on an intertidal sandflat, to which we added 0 or 220 g DW m-2 of detritus from either mangroves (Avicennia marina), seagrass (Zostera muelleri), or kelp (Ecklonia radiata) (n = 6 plots per treatment). Then, after 4, 17 and 46 d we measured ecosystem function, macrofaunal community structure and sediment properties. We hypothesized that (1) detrital decay would stimulate benthic primary production either by supplying nutrients to the benthic macrophytes, or by altering the macrofaunal community; and (2) ecosystem responses would depend on the stage and rate of macrophyte decay (a function of source). Avicennia detritus decayed the slowest with a half-life (t50) of 46 d, while Zostera and Ecklonia had t50 values of 28 and 2.6 d, respectively. However, ecosystem responses were not related to these differences. Instead, we found transient effects (up to 17 d) of Avicennia and Ecklonia detritus on benthic primary production, where initially (4 d) these detrital sources suppressed primary production, but after 17 d, primary production was stimulated in Avicennia plots relative to controls. Other ecosystem function response variables and the macrofaunal community composition were not altered by the addition of detritus, but did vary with time. By sampling ecosystem function temporally, we were able to capture the in situ transient effects of detrital subsidies on important benthic ecosystem functions.

  2. Residence, resorption and recycling of zircons in Devils Kitchen rhyolite, Coso Volcanic Field, California

    USGS Publications Warehouse

    Miller, J.S.; Wooden, J.L.

    2004-01-01

    Zircons from the Devils Kitchen rhyolite in the Pleistocene Coso Volcanic field, California have been analyzed by in situ Pb/U ion microprobe (SHRIMP-RG) and by detailed cathodoluminescence imaging. The zircons yield common-Pb-corrected and disequilibrium-corrected 206Pb/238U ages that predate a previously reported K-Ar sanidine age by up to 200 kyr, and the range of ages exhibited by the zircons is also approximately 200 kyr. Cathodoluminescence imaging indicates that zircons formed in contrasting environments. Most zircons are euhedral, and a majority of the zircons are weakly zoned, but many also have anhedral, embayed cores, with euhedral overgrowths and multiple internal surfaces that are truncated by later crystal zones. Concentrations of U and Th vary by two orders of magnitude within the zircon population, and by 10-20 times between zones within some zircon crystals, indicating that zircons were transferred between contrasting chemical environments. A zircon saturation temperature of ???750??C overlaps within error a previously reported phenocryst equilibration temperature of 740 ?? 25??C. Textures in zircons indicative of repeated dissolution and subsequent regrowth are probably caused by punctuated heating by mafic magma input into rhyolite. The overall span of ages and large variation in U and Th concentrations, combined with calculated zircon saturation temperatures and resorption times, are most compatible with crystallization in magma bodies that were emplaced piecemeal in the crust at Coso over 200 kyr prior to eruption, and that were periodically rejuvenated or melted by subsequent basaltic injections. ?? Oxford University Press 2004; all rights reserved.

  3. Annealing effects on cathodoluminescence of zircon

    NASA Astrophysics Data System (ADS)

    Tsuchiya, Y.; Nishido, H.; Noumi, Y.

    2011-12-01

    U-Pb zircon dating (e. g., SHRIMP) is an important tool to interpret a history of the minerals at a micrometer-scale, where cathodoluminescence (CL) imaging allows us to recognize internal zones and domains with different chemical compositions and structural disorder at high spatial resolution. The CL of zircon is attributed by various types of emission centers, which are extrinsic ones such as REE impurities and intrinsic ones such as structural defects. Metamictization resulted from radiation damage to the lattice by alpha particles from the decay of U and Th mostly causes an effect on the CL features of zircon as a defect center. However, slightly radiation-damaged zircon, which is almost nondetectable by XRD, has not been characterized using CL method. In this study, annealing effects on CL of zircon has been investigated to clarify a recovery process of the damaged lattice at low radiation dose. A single crystal of zircon from Malawi was selected for CL measurements. It contains HfO2: 2.30 w.t %, U: 241 ppm and Th: 177 ppm. Two plate samples perpendicular to c and a axes were prepared for annealing experiments during 12 hours from room temperature to 1400 degree C. Color CL images were captured using a cold-cathode microscope (Luminoscope: Nuclide ELM-3R). CL spectral measurements were conducted using an SEM (JEOL: JSM-5410) combined with a grating monochromator (Oxford: Mono CL2) to measure CL spectra ranging from 300 to 800 nm in 1 nm steps with a temperature controlled stage. The dispersed CL was collected by a photoncounting method using a photomultiplier tube (Hamamatsu: R2228) and converted to digital data. All CL spectra were corrected for the total instrumental response. Spectral analysis reveals an anisotropy of the CL emission bands related to intrinsic defect center in blue region, radiation-induced defect center from 500 to 700 nm, and trivalent Dy impurity center at 480 and 580 nm, but their relative intensities are almost constant. CL on the

  4. SHRIMP study of zircons from Early Archean rocks in the Minnesota River Valley: Implications for the tectonic history of the Superior Province

    USGS Publications Warehouse

    Bickford, M.E.; Wooden, J.L.; Bauer, R.L.

    2006-01-01

    Interest in Paleoarchean to early Mesoarchean crust in North America has been sparked by the recent identification of ca. 3800-3500 Ma rocks on the northern margin of the Superior craton in the Assean Lake region of northern Manitoba and the Porpoise Cove terrane in northern Quebec. It has long been known that similarly ancient gneisses are exposed on the southern margin of the Superior craton in the Minnesota River Valley and in northern Michigan, but the ages of these rocks have been poorly constrained, because methods applied in the 1960s through late 1970s were inadequate to unravel the complexities of their thermotectonic history. Rocks exposed in the Minnesota River Valley include a complex of migmatitic granitic gneisses, schistose to gneissic amphibolite, metagabbro, and paragneisses. The best-known units are the Morton Gneiss and the Montevideo Gneiss. The complex of ancient gneisses is intruded by a major younger, weakly deformed granite body, the Sacred Heart granite. Regional geophysical anomalies that extend across the Minnesota River Valley have been interpreted as defining boundaries between distinct blocks containing the various gneissic units. New sensitive high-resolution ion microprobe (SHRIMP) U-Pb data from complex zircons yielded the following ages: Montevideo Gneiss near Montevideo, 3485 ?? 10 Ma, granodiorite intrusion, 3385 ?? 8 Ma; Montevideo Gneiss at Granite Falls, 3497 ?? 9 Ma, metamorphic event, 3300-3350 Ma, mafic intrusion, 3141 ?? 2 Ma, metamorphic overprint (rims), 2606 ?? 4 Ma; Morton Gneiss: 3524 ?? 9 Ma, granodiorite intrusion, 3370 ?? 8 Ma, metamorphic overprints (growth of rims), 3140 ?? 2 Ma and 2595 ?? 4 Ma; biotite-garnet paragneiss, 2619 ?? 20 Ma; and Sacred Heart granite, 2604 ?? 4 Ma. Zircons from a cordierite-bearing feldspar-biotite schist overlying the Morton Gneiss yielded well-defined age peaks at 3520, 3480, 3380, and 3140 Ma, showing detrital input from most of the older rock units; 2600 Ma rims on these zircons

  5. Provenance of upper Triassic sandstone, southwest Iberia (Alentejo and Algarve basins): tracing variability in the sources

    NASA Astrophysics Data System (ADS)

    Pereira, M. F.; Ribeiro, C.; Gama, C.; Drost, K.; Chichorro, M.; Vilallonga, F.; Hofmann, M.; Linnemann, U.

    2017-01-01

    Laser ablation ICP-MS U-Pb analyses have been conducted on detrital zircon of Upper Triassic sandstone from the Alentejo and Algarve basins in southwest Iberia. The predominance of Neoproterozoic, Devonian, Paleoproterozoic and Carboniferous detrital zircon ages confirms previous studies that indicate the locus of the sediment source of the late Triassic Alentejo Basin in the pre-Mesozoic basement of the South Portuguese and Ossa-Morena zones. Suitable sources for the Upper Triassic Algarve sandstone are the Upper Devonian-Lower Carboniferous of the South Portuguese Zone (Phyllite-Quartzite and Tercenas formations) and the Meguma Terrane (present-day in Nova Scotia). Spatial variations of the sediment sources of both Upper Triassic basins suggest a more complex history of drainage than previously documented involving other source rocks located outside present-day Iberia. The two Triassic basins were isolated from each other with the detrital transport being controlled by two independent drainage systems. This study is important for the reconstruction of the late Triassic paleogeography in a place where, later, the opening of the Central Atlantic Ocean took place separating Europe from North America.

  6. Trace-element and Nd-isotope systematics in detrital apatite of the Po river catchment: Implications for provenance discrimination and the lag-time approach to detrital thermochronology

    NASA Astrophysics Data System (ADS)

    Malusà, Marco G.; Wang, Jiangang; Garzanti, Eduardo; Liu, Zhi-Chao; Villa, Igor M.; Wittmann, Hella

    2017-10-01

    Detrital thermochronology is often employed to assess the evolutionary stage of an entire orogenic belt using the lag-time approach, i.e., the difference between the cooling and depositional ages of detrital mineral grains preserved in a stratigraphic succession. The impact of different eroding sources to the final sediment sink is controlled by several factors, including the short-term erosion rate and the mineral fertility of eroded bedrock. Here, we use apatite fertility data and cosmogenic-derived erosion rates in the Po river catchment (Alps-Apennines) to calculate the expected percentage of apatite grains supplied to the modern Po delta from the major Alpine and Apenninic eroding sources. We test these predictions by using a cutting-edge dataset of trace-element and Nd-isotope signatures on 871 apatite grains from 14 modern sand samples, and we use apatite fission-track data to validate our geochemical approach to provenance discrimination. We found that apatite grains shed from different sources are geochemically distinct. Apatites from the Lepontine dome in the Central Alps show relative HREE enrichment, lower concentrations in Ce and U, and higher 147Sm/144Nd ratios compared to apatites derived from the External Massifs. Derived provenance budgets point to a dominant apatite contribution to the Po delta from the high-fertility Lepontine dome, consistent with the range independently predicted from cosmonuclide and mineral-fertility data. Our results demonstrate that the single-mineral record in the final sediment sink can be largely determined by high-fertility source rocks exposed in rapidly eroding areas within the drainage. This implies that the detrital thermochronology record may reflect processes affecting relatively small parts of the orogenic system under consideration. A reliable approach to lag-time analysis would thus benefit from an independent provenance discrimination of dated mineral grains, which may allow to proficiently reconsider many

  7. Trace element determination of zircons from adakites and granitoids: implications for petrogenetic processes

    NASA Astrophysics Data System (ADS)

    Chen, T. W.; Chu, M. F.; Chung, S. L.; Iizuka, Y.

    2017-12-01

    Zircon has long been proposed as a time capsule of crustal formation. Concerning of its high capacity of lithophile elements, the dramatic change of crustal chemical composition in late Archean, i.e. from TTG suites to granitoids, may be recorded in zircon remnants. In this study, major- and trace element contents of zircons from adakites, a modern analogue of TTG suites, in southern Tibet were determined by EPMA and LA-ICPMS, respectively, and compared with those in Gangdese granitoids and Sumatra high/low ΣREE granitoids in order to examine the hypothesis. The REE patterns of zircons in this study show little inter-sample discrepancy though there is significant difference in whole-rock HREE contents between adakites and granitoids. Since none of geochemical feature, including REE contents, of zircons correlates with SiO2 content or ASI of corresponding host rocks, fractional crystallization shows insignificant impact on the compositional variation in zircons. In addition to the influence of lattice strain and charge balance requirements, zircons in these rock samples are proposed to crystallize from the magma mush, so they record the composition with least composition difference, not that of the bulk melt. More specifically, the pre-/co-existing mineral phases, e.g. apatite, play a critical role in preferentially taking the LREE and MREE from melt, and eliminating the HREE depletion in residual melt and thus zircons of Gangdese adakites. With the aim of objectively identifying geochemical discriminants of zircons from adakites and granitoids, statistical analysis was used and then 8 parameters were selected, i.e. Ti, V, Yb, Hf, Sc/Yb, U/Yb, Eu/Eu*, ΣHREE. Despite the zircon populations of adakites- and granitoids-origins overlapping in any bivariate plot, the linear combination of discriminants provides a potential way to distinguish zircons from these two groups.

  8. Peculiar Feldspar And Quartz Inclusions Within Zircons From Anorthosites, North Eastern Desert, Egypt

    NASA Astrophysics Data System (ADS)

    Eliwa, H. A.; Dawoud, M. I.; Khalaf, I. M.; Negendank, J. F.; Itaya, T.

    2004-12-01

    Zircons from three anorthosite outcrops along Wadi Dib area, north Eastern Desert of Egypt contain abundant and conspicuous inclusions of quartz, feldspar, amphibole and apatite. These anorthosites, as (50-100m thick) layers, represent the top of mafic-ultramafic intrusions exhibiting rhythmic layering visible by reputation of melanocratic and leucocratic layers. Field and microscopic studies exhibit that these anorthosites were affected by the action of residual magmatic solutions associated with the late stage crystallization of the younger granites, which modified their mineralogical composition. They are composed totally of plagioclase with subordinate amount of clinoenstatite, augite, amphibole, biotite, K-feldspar, and quartz. Accessories are magnetite, ilmenite, apatite and zircon. The abundance and the mode of occurrence of K-feldspar, quartz, and biotite with apatite and zircon among the megacrysts suggest their formation is ascribed to the interaction with the residual solutions. The microprobe data exhibit difference between feldspar and amphiboles contained herein zircons and those as anorthosite mineral constituents. The genetic relationship between zircons and their inclusions suggests later growth of zircons than inclusions and most probably at the final stage of rock modification. Zircons are magmatic and found in the interstitial feldspar and quartz among plagioclase megacrysts in aggregates or as individual grains. The microscopic and SEM images investigation exhibit that most zircons are subhedral to euhedral equant and prismatic crystals. Most zircons have same range of crystal morphologies and internal growth structures with predominance of prism /{100/} and pyramid /{101/} and occasionally prism /{110/} and pyramid /{111/}. No evidences for poly-faceted grains, inherited cores or later overgrowths were detected. CL images distinguished zircons with visible core-rim structures and others with regular and continuous growth zones contained herein

  9. Raman study of radiation-damaged zircon under hydrostatic compression

    NASA Astrophysics Data System (ADS)

    Nasdala, Lutz; Miletich, Ronald; Ruschel, Katja; Váczi, Tamás

    2008-12-01

    Pressure-induced changes of Raman band parameters of four natural, gem-quality zircon samples with different degrees of self-irradiation damage, and synthetic ZrSiO4 without radiation damage, have been studied under hydrostatic compression in a diamond anvil cell up to ~10 GPa. Radiation-damaged zircon shows similar up-shifts of internal SiO4 stretching modes at elevated pressures as non-damaged ZrSiO4. Only minor changes of band-widths were observed in all cases. This makes it possible to estimate the degree of radiation damage from the width of the ν3(SiO4) band of zircon inclusions in situ, almost independent from potential “fossilized pressures” or compressive strain acting on the inclusions. An application is the non-destructive analysis of gemstones such as corundum or spinel: broadened Raman bands are a reliable indicator of self-irradiation damage in zircon inclusions, whose presence allows one to exclude artificial color enhancement by high-temperature treatment of the specimen.

  10. Interpreting U-Pb data from primary and secondary features in lunar zircon

    NASA Astrophysics Data System (ADS)

    Grange, M. L.; Pidgeon, R. T.; Nemchin, A. A.; Timms, N. E.; Meyer, C.

    2013-01-01

    In this paper, we describe primary and secondary microstructures and textural characteristics found in lunar zircon and discuss the relationships between these features and the zircon U-Pb isotopic systems and the significance of these features for understanding lunar processes. Lunar zircons can be classified according to: (i) textural relationships between zircon and surrounding minerals in the host breccias, (ii) the internal microstructures of the zircon grains as identified by optical microscopy, cathodoluminescence (CL) imaging and electron backscattered diffraction (EBSD) mapping and (iii) results of in situ ion microprobe analyses of the Th-U-Pb isotopic systems. Primary zircon can occur as part of a cogenetic mineral assemblage (lithic clast) or as an individual mineral clast and is unzoned, or has sector and/or oscillatory zoning. The age of primary zircon is obtained when multiple ion microprobe analyses across the polished surface of the grain give reproducible and essentially concordant data. A secondary set of microstructures, superimposed on primary zircon, include localised recrystallised domains, localised amorphous domains, crystal-plastic deformation, planar deformation features and fractures, and are associated with impact processes. The first two secondary microstructures often yield internally consistent and close to concordant U-Pb ages that we interpret as dating impact events. Others secondary microstructures such as planar deformation features, crystal-plastic deformation and micro-fractures can provide channels for Pb diffusion and result in partial resetting of the U-Pb isotopic systems.

  11. Nano-Scale Structure of Twin Boundaries in Shocked Zircon from the Vredefort Impact Structure.

    NASA Astrophysics Data System (ADS)

    Sharp, T. G.; Cavosie, A. J.

    2017-12-01

    Shock deformation of zircon produces distinct microstructures that can be used as evidence of shock in natural samples. These deformation features include {112} twins that have been observed in naturally shocked samples from Vredefort and elsewhere [1-3]. Electron backscatter diffraction (EBSD) has shown that these twins are polysynthetic, generally < 1µm wide and have a 65°/<110> crystallographic relation to the host zircon [2]. The structure and composition of these twin boundaries, and their effects on element mobility have not been explored previously. Here we use high-resolution TEM to investigate the nano-structure of a {112} twin in a shocked zircon crystal from the 2.0 Ga Vredefort impact structure [3]. Focused-ion-beam lift-out techniques were used to prepare a TEM foil with a 1 µm wide {112}-twin lamella. The foil was characterized by TEM imaging and electron diffraction using a FEI CM200-FEG transmission electron microscope. Selected area diffraction from the {112}-twin boundary, along a <111> zone, showed no apparent evidence of twining. However, the domain boundaries displayed weak diffraction contrast in this orientation. High-resolution images show a 50-nm wide zone of heterogeneous structural disorder and locally amorphous domains along the twin boundaries that is inferred to be a localized metamict zone. The detailed lattice structure of the interface was not discernable because of this structural disorder. Diffraction and imaging along <021> confirms that the {112}-twin composition plane is a mirror plane. The crystallographic relations observed along <110> and <021> are consistent with the 65°/<110> twin structure previously determined from EBSD [2]. Enhanced metamict disorder suggests a higher concentration of actinides along the twin boundaries and implies actinide mobility near twin boundaries. [1] Moser et al, 2011 Can J Earth Sci. [2] Erickson et al. 2013 Am Min. [3] Cavosie et al. 2015 Geol.

  12. Determination of zircon/melt trace element partition coefficients from SIMS analysis of melt inclusions in zircon

    NASA Astrophysics Data System (ADS)

    Thomas, J. B.; Bodnar, R. J.; Shimizu, N.; Sinha, A. K.

    2002-09-01

    Partition coefficients ( zircon/meltD M) for rare earth elements (REE) (La, Ce, Nd, Sm, Dy, Er and Yb) and other trace elements (Ba, Rb, B, Sr, Ti, Y and Nb) between zircon and melt have been calculated from secondary ion mass spectrometric (SIMS) analyses of zircon/melt inclusion pairs. The melt inclusion-mineral (MIM) technique shows that D REE increase in compatibility with increasing atomic number, similar to results of previous studies. However, D REE determined using the MIM technique are, in general, lower than previously reported values. Calculated D REE indicate that light REE with atomic numbers less than Sm are incompatible in zircon and become more incompatible with decreasing atomic number. This behavior is in contrast to most previously published results which indicate D > 1 and define a flat partitioning pattern for elements from La through Sm. The partition coefficients for the heavy REE determined using the MIM technique are lower than previously published results by factors of ≈15 to 20 but follow a similar trend. These differences are thought to reflect the effects of mineral and/or glass contaminants in samples from earlier studies which employed bulk analysis techniques. D REE determined using the MIM technique agree well with values predicted using the equations of Brice (1975), which are based on the size and elasticity of crystallographic sites. The presence of Ce 4+ in the melt results in elevated D Ce compared to neighboring REE due to the similar valence and size of Ce 4+ and Zr 4+. Predicted zircon/meltD values for Ce 4+ and Ce 3+ indicate that the Ce 4+/Ce 3+ ratios of the melt ranged from about 10 -3 to 10 -2. Partition coefficients for other trace elements determined in this study increase in compatibility in the order Ba < Rb < B < Sr < Ti < Y < Nb, with Ba, Rb, B and Sr showing incompatible behavior (D M < 1.0), and Ti, Y and Nb showing compatible behavior (D M > 1.0). The effect of partition coefficients on melt evolution during

  13. Effect of α-damage on fission-track annealing in zircon

    USGS Publications Warehouse

    Kasuya, Masao; Naeser, Charles W.

    1988-01-01

    The thermal stability of confined fission-track lengths in four zircon samples having different spontaneous track densities (i.e., different amounts of ??-damage) has been studied by one-hour isochronal annealing experiments. The thermal stability of spontaneous track lengths is independent of initial spontaneous track density. The thermal stability of induced track lengths in pre-annealed zircon, however, is significantly higher than that of spontaneous track lengths. The results indicate that the presence of ??-damage lowers the thermal stability of fission-tracks in zircon.

  14. Pore structure characterization of Chang-7 tight sandstone using MICP combined with N2GA techniques and its geological control factors

    PubMed Central

    Cao, Zhe; Liu, Guangdi; Zhan, Hongbin; Li, Chaozheng; You, Yuan; Yang, Chengyu; Jiang, Hang

    2016-01-01

    Understanding the pore networks of unconventional tight reservoirs such as tight sandstones and shales is crucial for extracting oil/gas from such reservoirs. Mercury injection capillary pressure (MICP) and N2 gas adsorption (N2GA) are performed to evaluate pore structure of Chang-7 tight sandstone. Thin section observation, scanning electron microscope, grain size analysis, mineral composition analysis, and porosity measurement are applied to investigate geological control factors of pore structure. Grain size is positively correlated with detrital mineral content and grain size standard deviation while negatively related to clay content. Detrital mineral content and grain size are positively correlated with porosity, pore throat radius and withdrawal efficiency and negatively related to capillary pressure and pore-to-throat size ratio; while interstitial material is negatively correlated with above mentioned factors. Well sorted sediments with high debris usually possess strong compaction resistance to preserve original pores. Although many inter-crystalline pores are produced in clay minerals, this type of pores is not the most important contributor to porosity. Besides this, pore shape determined by N2GA hysteresis loop is consistent with SEM observation on clay inter-crystalline pores while BJH pore volume is positively related with clay content, suggesting N2GA is suitable for describing clay inter-crystalline pores in tight sandstones. PMID:27830731

  15. Implications of Western-sourced Paleogene Flexural Foreland Basin Development in the Peruvian Altiplano on Andean Geodynamics

    NASA Astrophysics Data System (ADS)

    Sundell, K. E.; Saylor, J.; Lapen, T. J.; Styron, R. H.; Villarreal, D. P.; Usnayo Perales, W. P.; Cárdenas, J.

    2017-12-01

    Stratigraphy of the Peruvian Altiplano contains valuable information salient to debated geodynamic processes active during the Cenozoic construction of the Andean Plateau. Central to this discussion is the relative timing, location, and magnitude of basin subsidence and surface uplift; however, records of these processes are limited in the Andean Plateau of southern Peru. We measured 6200 m of non-marine clastic stratigraphy in the northernmost Altiplano, characterized through lithofacies and paleocurrent analysis, conglomerate clast counts, sandstone petrography, and detrital zircon U-Pb geochronology. We employ a host of new quantitative detrital zircon techniques including multidimensional scaling, mixture modeling, and quantification of zircon roundness. Results consistently show sediment sourcing from the Western Cordillera and/or western Altiplano, despite close proximity to the modern Eastern Cordillera. Sediment accumulation rates based on new detrital zircon U-Pb maximum depositional ages define an upward-convex, Paleogene subsidence profile with rates increasing from 36 m/Myr to >150 m/Myr. These rates are consistent with deposition and northeastward migration of a Paleogene flexural foreland basin system, which requires coeval lithospheric loading in the Western Cordillera and/or western Altiplano and relative subsidence in the location of the modern Eastern Cordillera. Transition to hinterland basin deposition is marked by a latest Oligocene to middle Miocene angular unconformity. Following this transition, sediment accumulation rates increase to >800 m/Myr during the late Miocene, consistent with strike-slip-induced subsidence, likely under Airy isostatic support. Results in the context of the greater Andean Plateau highlight along-strike variability in rates and timing of deposition in a regionally-contiguous foreland basin system extending from southern Peru to northwest Argentina, and support models of cyclical orogenic processes.

  16. Proterozoic geochronological links between the Farewell, Kilbuck, and Arctic Alaska terranes

    USGS Publications Warehouse

    Bradley, Dwight C.; McClelland, William C.; Friedman, Richard M.; O'Sullivan, Paul B.; Layer, Paul; Miller, Marti L.; Dumoulin, Julie A.; Till, Alison B.; Abbott, J. Grant; Bradley, Dan B.; Wooden, Joseph L.

    2014-01-01

    New U-Pb igneous and detrital zircon ages reveal that despite being separated by younger orogens, three of Alaska’s terranes that contain Precambrian rocks—Farewell, Kilbuck, and Arctic Alaska—are related. The Farewell and Kilbuck terranes can be linked by felsic magmatism at ca. 850 Ma and by abundant detrital zircons in the Farewell that overlap the ca. 2010–2085 Ma age range of granitoids in the Kilbuck. The Farewell and Arctic Alaska terranes have already been linked via correlative Neoproterozoic to Devonian carbonate platform deposits that share nearly identical faunas of mixed Siberian and Laurentian affinity. New igneous ages strengthen these ties. Specifically, 988, 979, and 979 Ma metafelsites in the Farewell terrane are close in age to a 971 Ma granitic orthogneiss in the Arctic Alaska terrane. Likewise, 852, 850, 845, and 837 Ma granitic orthogneisses, metafelsite, and rhyolite in the Farewell terrane are similar to the reported 874 to 848 Ma age range of metarhyolites in the Arctic Alaska terrane. The Kilbuck and Arctic Alaska terranes have been previously linked on the basis of provenance: detrital zircons from the Carboniferous Nuka Formation in the Arctic Alaska terrane range from 2013 to 2078 Ma, overlapping the age of Kilbuck granitoids. A new 849 Ma age of a Kilbuck granitoid strengthens the proposed connection. Among the other new results from Kilbuck terrane is a 2085 Ma zircon from a granitoid that now stands as the oldest tightly dated rock in Alaska. We conclude that the Kilbuck, Farewell, and Arctic Alaska terranes were not independent entities with unique geologic histories but instead are related pieces of the circum-Arctic tectonic puzzle.

  17. Settling equivalence of detrital minerals and grain-size dependence of sediment composition

    NASA Astrophysics Data System (ADS)

    Garzanti, Eduardo; Andò, Sergio; Vezzoli, Giovanni

    2008-08-01

    This study discusses the laws which govern sediment deposition, and consequently determine size-dependent compositional variability. A theoretical approach is substantiated by robust datasets on major Alpine, Himalayan, and African sedimentary systems. Integrated (bulk-petrography, heavy-mineral, X-ray powder diffraction) multiple-window analyses at 0.25ϕ to 0.50ϕ sieve interval of eighty-five fluvial, beach, and eolian-dune samples, ranging from very fine silt to coarse sand, document homologous intrasample compositional trends, revealed by systematic concentration of denser grains in finer-grained fractions (“size-density sorting”). These trends are explained by the settling-equivalence principle, stating that detrital minerals are deposited together if their settling velocity is the same. Settling of silt is chiefly resisted by fluid viscosity, and Stokes' law predicts that size differences between detrital minerals in ϕ units (“size shifts”) are half the difference between the logarithms of their submerged densities. Settling of pebbles is chiefly resisted by turbulence effects, and the Impact law predicts double size shifts than Stokes' law. Settling of sand is resisted by both viscosity and turbulence, the settling-equivalence formula is complex, and size shifts increase - with increasing settling velocity and grain size - from those predicted by Stokes' law to those predicted by the Impact law. In wind-laid sands, size shifts match those predicted by the Impact law; size-density sorting is thus greater than in water-laid fine sands. New analytical, graphical, and statistical techniques for rigorous settling-equivalence analysis of terrigenous sediments are illustrated. Deviations associated with non-spherical shape, density anomalies, inheritance from source rocks, or mixing of detrital species with contrasting provenance and different size distribution are also tentatively assessed. Such integrated theoretical and experimental approach allows us

  18. Constraints on the timing of multiple thermal events and re-equilibration recorded by high-U zircon and xenotime: Case study of pegmatite from Piława Górna (Góry Sowie Block, SW Poland)

    NASA Astrophysics Data System (ADS)

    Budzyń, Bartosz; Sláma, Jiří; Kozub-Budzyń, Gabriela A.; Konečný, Patrik; Holický, Ivan; Rzepa, Grzegorz; Jastrzębski, Mirosław

    2018-06-01

    The application of zircon and xenotime geochronometers requires knowledge of their potential and limitations related to possible disturbance of the age record. The alteration of the intergrown zircon and xenotime in pegmatite from the Góry Sowie Block (SW Poland) was studied using the electron microprobe analysis, X-ray WDS compositional mapping, micro-Raman analysis, and LA-ICP-MS U-Pb dating of zircon and xenotime, as well as the U-Th-total Pb dating of uraninite. These microanalytical techniques were applied to understand the formation mechanisms of the secondary textures related to post-magmatic processes in the zircon and xenotime intergrowth, and to constrain their timing. Textural and compositional features combined with U-Pb data indicate that the pegmatite-related crystallization of the zircon and xenotime intergrowth occurred ca. 2.09 Ga (2086 ± 35 Ma for zircon and 2093 ± 52 Ma for xenotime), followed by the re-equilibration of zircon and xenotime ca. 370 Ma (373 ± 18 Ma and 368 ± 6 Ma, respectively) during the formation of the younger pegmatite. The zircon and xenotime were most likely derived from Precambrian basement rocks and emplaced in the pegmatite as a restite. The zircon preserved textures related to diffusion-reaction processes that affected its high-U core (up to ca. 9.6 wt% UO2), which underwent further metamictization and amorphization due to self-radiation damage. The zircon rim and xenotime were affected by coupled dissolution-reprecipitation processes that resulted in patchy zoning, age disturbance and sponge-like textures. Xenotime was also partially replaced by fluorapatite or hingganite-(Y) and Y-enriched allanite-(Ce). The termination of the low-temperature alteration was constrained by the U-Th-total Pb age of the uraninite inclusions that crystallized in zircon at 281 ± 2 Ma, which is consistent with the age of 278 ± 15 Ma obtained from the youngest cluster of U-Pb ages in the re-equilibrated high-U zircon domains. This study

  19. Do Hf isotopes in magmatic zircons represent those of their host rocks?

    NASA Astrophysics Data System (ADS)

    Wang, Di; Wang, Xiao-Lei; Cai, Yue; Goldstein, Steven L.; Yang, Tao

    2018-04-01

    Lu-Hf isotopic system in zircon is a powerful and widely used geochemical tracer in studying petrogenesis of magmatic rocks and crustal evolution, assuming that zircon Hf isotopes can represent initial Hf isotopes of their parental whole rock. However, this assumption may not always be valid. Disequilibrium partial melting of continental crust would preferentially melt out non-zircon minerals with high time-integrated Lu/Hf ratios and generate partial melts with Hf isotope compositions that are more radiogenic than those of its magma source. Dissolution experiments (with hotplate, bomb and sintering procedures) of zircon-bearing samples demonstrate this disequilibrium effect where partial dissolution yielded variable and more radiogenic Hf isotope compositions than fully dissolved samples. A case study from the Neoproterozoic Jiuling batholith in southern China shows that about half of the investigated samples show decoupled Hf isotopes between zircons and the bulk rocks. This decoupling could reflect complex and prolonged magmatic processes, such as crustal assimilation, magma mixing, and disequilibrium melting, which are consistent with the wide temperature spectrum from ∼630 °C to ∼900 °C by Ti-in-zircon thermometer. We suggest that magmatic zircons may only record the Hf isotopic composition of their surrounding melt during crystallization and it is uncertain whether their Hf isotopic compositions can represent the primary Hf isotopic compositions of the bulk magmas. In this regard, using zircon Hf isotopic compositions to trace crustal evolution may be biased since most of these could be originally from disequilibrium partial melts.

  20. Ancient and modern rhyolite: Using zircon trace element compositions to examine the origin of volcanic rocks

    NASA Astrophysics Data System (ADS)

    Klemetti, E. W.; Lackey, J.; Starnes, J.; Wooden, J. L.

    2011-12-01

    along with crystal fractionation. At a given Hf concentration, the Th/U of Mineral King rhyolites are lower than Okataina rhyolites. Yb/Sm are, on average, lower for Mineral King rhyolite at a given Hf than in the Okataina rhyolites. At high Hf concentrations (>12000 ppm), Mineral King rhyolites show a wide range of Yb/Sm (<100 to 500). A xenocrystic zircon with an age of ~1.63 Ga was found in one Mineral King rhyolite suggesting crustal melting/assimilation was also important during the evolution in the younger rhyolites in the pendant. Additionally, bulk zircon oxygen isotopic analyses from Mineral King rhyolites show a change from more mantle-like values δ18O at 196 Ma (+5.3%) to higher values at 136 Ma (+6.8%), evidence of increasing input of continental crust. In all, the differences in the trace element and isotopic compositions between the Okataina and Mineral King zircon likely reflect the difference in the crustal thickness and composition of their respective crustal settings, but also reflect the particular volcanic environment.