The wide-range ejector flowmeter: calibrated gas evacuation comprising both high and low gas flows.

PubMed

Waaben, J; Brinkløv, M M; Jørgensen, S

1984-11-01

The wide-range ejector flowmeter is an active scavenging system applying calibrated gas removal directly to the anaesthetic circuit. The evacuation rate can be adjusted on the flowmeter under visual control using the calibration scale ranging from 200 ml X min-1 to 151 X min-1. The accuracy of the calibration was tested on three ejector flowmeters at 12 different presettings. The percentage deviation from presetting varied from + 18 to - 19.4 per cent. The ejector flowmeter enables the provision of consistent and accurately calibrated extraction of waste gases and is applicable within a wide range of fresh gas flows.

Self-Calibrating Respiratory-Flowmeter Combination

NASA Technical Reports Server (NTRS)

Westenskow, Dwayne R.; Orr, Joseph A.

1990-01-01

Dual flowmeters ensure accuracy over full range of human respiratory flow rates. System for measurement of respiratory flow employs two flowmeters; one compensates for deficiencies of other. Combination yields easily calibrated system accurate over wide range of gas flow.

[Evaluation of vaporizers by anesthetic gas monitors corrected with a new method for preparation of calibration gases].

PubMed

Kurashiki, T

1996-11-01

For resolving the discrepancy of concentrations found among anesthetic gas monitors, the author proposed a new method using a vaporizer as a standard anesthetic gas generator for calibration. In this method, the carrier gas volume is measured by a mass flow meter (SEF-510 + FI-101) installed before the inlet of the vaporizer. The vaporized weight of volatile anesthetic agent is simultaneously measured by an electronic force balance (E12000S), on which the vaporizer is placed directly. The molar percent of the anesthetic is calculated using these data and is transformed into the volume percent. These gases discharging from the vaporizer are utilized for calibrating anesthetic gas monitors. These monitors are normalized by the linear equation describing the relationship between concentrations of calibration gases and readings of the anesthetic gas monitors. By using normalized monitors, flow rate-concentration performance curves of several anesthetic vaporizers were obtained. The author concludes that this method can serve as a standard in evaluating anesthetic vaporizers.

Anemometer calibrator

NASA Technical Reports Server (NTRS)

Bate, T.; Calkins, D. E.; Price, P.; Veikins, O.

1971-01-01

Calibrator generates accurate flow velocities over wide range of gas pressure, temperature, and composition. Both pressure and flow velocity can be maintained within 0.25 percent. Instrument is essentially closed loop hydraulic system containing positive displacement drive.

Note: Ultrasonic gas flowmeter based on optimized time-of-flight algorithms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, X. F.; Tang, Z. A.

2011-04-15

A new digital signal processor based single path ultrasonic gas flowmeter is designed, constructed, and experimentally tested. To achieve high accuracy measurements, an optimized ultrasound driven method of incorporation of the amplitude modulation and the phase modulation of the transmit-receive technique is used to stimulate the transmitter. Based on the regularities among the received envelope zero-crossings, different received signal's signal-to-noise ratio situations are discriminated and optional time-of-flight algorithms are applied to take flow rate calculations. Experimental results from the dry calibration indicate that the designed flowmeter prototype can meet the zero-flow verification test requirements of the American Gas Association Reportmore » No. 9. Furthermore, the results derived from the flow calibration prove that the proposed flowmeter prototype can measure flow rate accurately in the practical experiments, and the nominal accuracies after FWME adjustment are lower than 0.8% throughout the calibration range.« less

Gauge calibration by diffusion

NASA Technical Reports Server (NTRS)

Brock, F. J.; Feakes, F. (Inventor)

1968-01-01

Vacuum gage calibration by diffusing a known quantity of gas through a heated barrier into a gauge is examined. The gas flow raises the pressure in the gauge to known level and is then compared with the gauge's pressure reading.

Evaluation of a novel wind tunnel for the measurement of the kinetics of odour emissions from piggery effluent.

PubMed

Sohn, J H; Smith, R; Yoong, E; Hudson, N; Kim, T I

2004-01-01

A novel laboratory wind tunnel, with the capability to control factors such as air flow-rate, was developed to measure the kinetics of odour emissions from liquid effluent. The tunnel allows the emission of odours and other volatiles under an atmospheric transport system similar to ambient conditions. Sensors for wind speed, temperature and humidity were installed and calibrated. To calibrate the wind tunnel, trials were performed to determine the gas recovery efficiency under different air flow-rates (ranging from 0.001 to 0.028m3/s) and gas supply rates (ranging from 2.5 to 10.0 L/min) using a standard CO gas mixture. The results have shown gas recovery efficiencies ranging from 61.7 to 106.8%, while the average result from the trials was 81.14%. From statistical analysis, it was observed that the highest, most reliable gas recovery efficiency of the tunnel was 88.9%. The values of air flow-rate and gas supply rate corresponding to the highest gas recovery efficiency were 0.028 m3/s and 10.0 L/min respectively. This study suggested that the wind tunnel would provide precise estimates of odour emission rate. However, the wind tunnel needs to be calibrated to compensate for errors caused by different air flow-rates.

Device-scale CFD modeling of gas-liquid multiphase flow and amine absorption for CO 2 capture: Original Research Article: Device-scale CFD modeling of gas-liquid multiphase flow and amine absorption for CO 2 capture

DOE PAGES

Pan, Wenxiao; Galvin, Janine; Huang, Wei Ling; ...

2018-03-25

In this paper we aim to develop a validated device-scale CFD model that can predict quantitatively both hydrodynamics and CO 2 capture efficiency for an amine-based solvent absorber column with random Pall ring packing. A Eulerian porous-media approach and a two-fluid model were employed, in which the momentum and mass transfer equations were closed by literature-based empirical closure models. We proposed a hierarchical approach for calibrating the parameters in the closure models to make them accurate for the packed column. Specifically, a parameter for momentum transfer in the closure was first calibrated based on data from a single experiment. Withmore » this calibrated parameter, a parameter in the closure for mass transfer was next calibrated under a single operating condition. Last, the closure of the wetting area was calibrated for each gas velocity at three different liquid flow rates. For each calibration, cross validations were pursued using the experimental data under operating conditions different from those used for calibrations. This hierarchical approach can be generally applied to develop validated device-scale CFD models for different absorption columns.« less

Device-scale CFD modeling of gas-liquid multiphase flow and amine absorption for CO 2 capture: Original Research Article: Device-scale CFD modeling of gas-liquid multiphase flow and amine absorption for CO 2 capture

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pan, Wenxiao; Galvin, Janine; Huang, Wei Ling

In this paper we aim to develop a validated device-scale CFD model that can predict quantitatively both hydrodynamics and CO 2 capture efficiency for an amine-based solvent absorber column with random Pall ring packing. A Eulerian porous-media approach and a two-fluid model were employed, in which the momentum and mass transfer equations were closed by literature-based empirical closure models. We proposed a hierarchical approach for calibrating the parameters in the closure models to make them accurate for the packed column. Specifically, a parameter for momentum transfer in the closure was first calibrated based on data from a single experiment. Withmore » this calibrated parameter, a parameter in the closure for mass transfer was next calibrated under a single operating condition. Last, the closure of the wetting area was calibrated for each gas velocity at three different liquid flow rates. For each calibration, cross validations were pursued using the experimental data under operating conditions different from those used for calibrations. This hierarchical approach can be generally applied to develop validated device-scale CFD models for different absorption columns.« less

An Improved Calibration Method for Hydrazine Monitors for the United States Air Force

DOE Office of Scientific and Technical Information (OSTI.GOV)

Korsah, K

2003-07-07

This report documents the results of Phase 1 of the ''Air Force Hydrazine Detector Characterization and Calibration Project''. A method for calibrating model MDA 7100 hydrazine detectors in the United States Air Force (AF) inventory has been developed. The calibration system consists of a Kintek 491 reference gas generation system, a humidifier/mixer system which combines the dry reference hydrazine gas with humidified diluent or carrier gas to generate the required humidified reference for calibrations, and a gas sampling interface. The Kintek reference gas generation system itself is periodically calibrated using an ORNL-constructed coulometric titration system to verify the hydrazine concentrationmore » of the sample atmosphere in the interface module. The Kintek reference gas is then used to calibrate the hydrazine monitors. Thus, coulometric titration is only used to periodically assess the performance of the Kintek reference gas generation system, and is not required for hydrazine monitor calibrations. One advantage of using coulometric titration for verifying the concentration of the reference gas is that it is a primary standard (if used for simple solutions), thereby guaranteeing, in principle, that measurements will be traceable to SI units (i.e., to the mole). The effect of humidity of the reference gas was characterized by using the results of concentrations determined by coulometric titration to develop a humidity correction graph for the Kintek 491 reference gas generation system. Using this calibration method, calibration uncertainty has been reduced by 50% compared to the current method used to calibrate hydrazine monitors in the Air Force inventory and calibration time has also been reduced by more than 20%. Significant findings from studies documented in this report are the following: (1) The Kintek 491 reference gas generation system (generator, humidifier and interface module) can be used to calibrate hydrazine detectors. (2) The Kintek system output concentration is less than the calculated output of the generator alone but can be calibrated as a system by using coulometric titration of gas samples collected with impingers. (3) The calibrated Kintek system output concentration is reproducible even after having been disassembled and moved and reassembled. (4) The uncertainty of the reference gas concentration generated by the Kintek system is less than half the uncertainty of the Zellweger Analytics' (ZA) reference gas concentration and can be easily lowered to one third or less of the ZA method by using lower-uncertainty flow rate or total flow measuring instruments. (5) The largest sources of uncertainty in the current ORNL calibration system are the permeation rate of the permeation tubes and the flow rate of the impinger sampling pump used to collect gas samples for calibrating the Kintek system. Upgrading the measurement equipment, as stated in (4), can reduce both of these. (6) The coulometric titration technique can be used to periodically assess the performance of the Kintek system and determine a suitable recalibration interval. (7) The Kintek system has been used to calibrate two MDA 7100s and an Interscan 4187 in less than one workday. The system can be upgraded (e.g., by automating it) to provide more calibrations per day. (8) The humidity of both the reference gas and the environment of the Chemcassette affect the MDA 7100 hydrazine detector's readings. However, ORNL believes that the environmental effect is less significant than the effect of the reference gas humidity. (9) The ORNL calibration method based on the Kintek 491 M-B gas standard can correct for the effect of the humidity of the reference gas to produce the same calibration as that of ZA's. Zellweger Analytics calibrations are typically performed at 45%-55% relative humidity. (10) Tests using the Interscan 4187 showed that the instrument was not accurate in its lower (0-100 ppb) range. Subsequent discussions with Kennedy Space Center (KSC) personnel also indicated that the Interscan units were not reproducible when new sensors were used. KSC had discovered that the Interscan units read incorrectly on the low range because of the presence of carbon dioxide. ORNL did not test the carbon dioxide effect, but it was found that the units did not read zero when a test gas containing no hydrazine was sampled. According to the KSC personnel that ORNL had these discussions with, NASA is phasing out the use of these Interscan detectors.« less

40 CFR 1065.248 - Gas divider.

Code of Federal Regulations, 2012 CFR

2012-07-01

... use a gas divider to blend calibration gases. (b) Component requirements. Use a gas divider that... testing. You may use critical-flow gas dividers, capillary-tube gas dividers, or thermal-mass-meter gas... and CO2 Measurements ...

40 CFR 1065.248 - Gas divider.

Code of Federal Regulations, 2011 CFR

2011-07-01

... use a gas divider to blend calibration gases. (b) Component requirements. Use a gas divider that... testing. You may use critical-flow gas dividers, capillary-tube gas dividers, or thermal-mass-meter gas... and CO2 Measurements ...

40 CFR 1065.248 - Gas divider.

Code of Federal Regulations, 2014 CFR

2014-07-01

... use a gas divider to blend calibration gases. (b) Component requirements. Use a gas divider that... testing. You may use critical-flow gas dividers, capillary-tube gas dividers, or thermal-mass-meter gas... and CO2 Measurements ...

40 CFR 1065.248 - Gas divider.

Code of Federal Regulations, 2013 CFR

2013-07-01

... use a gas divider to blend calibration gases. (b) Component requirements. Use a gas divider that... testing. You may use critical-flow gas dividers, capillary-tube gas dividers, or thermal-mass-meter gas... and CO2 Measurements ...

Primary flow meter for calibrating a sniffer test leak artefact by a pressure rise method

NASA Astrophysics Data System (ADS)

Arai, Kenta; Yoshida, Hajime

2014-10-01

Sniffer tests are used to locate leaks in equipment during operation. The sensitivity of a sniffer leak detector must be calibrated against a known gas flow to atmospheric pressure generated by a sniffer test leak artefact. We have developed a primary flow meter for calibrating gas flows to atmospheric pressure through the leak artefact. The flow meter is based on a pressure rise method and two chambers are used to measure the pressure rise with small uncertainty even at atmospheric pressure. The calibration range of the flow rate is 5 × 10-7 Pa m3 s-1 to 7 × 10-4 Pa m3 s-1 to atmospheric pressure at 23.0 °C with a minimum uncertainty of 1.4% (k = 2), as well as 4 × 10-8 Pa m3 s-1 to 5 × 10-4 Pa m3 s-1 to a vacuum at 23.0 °C. The long term stability of the flow meter was determined as 0.41% by repeated measurements of the conductance of the leak artefact. In case of the flow rate into a vacuum, the flow meter was successfully linked to the international reference value of CCM.P-K12 by a lab-internal comparison.

Using noble gas tracers to constrain a groundwater flow model with recharge elevations: A novel approach for mountainous terrain

USGS Publications Warehouse

Doyle, Jessica M.; Gleeson, Tom; Manning, Andrew H.; Mayer, K. Ulrich

2015-01-01

Environmental tracers provide information on groundwater age, recharge conditions, and flow processes which can be helpful for evaluating groundwater sustainability and vulnerability. Dissolved noble gas data have proven particularly useful in mountainous terrain because they can be used to determine recharge elevation. However, tracer-derived recharge elevations have not been utilized as calibration targets for numerical groundwater flow models. Herein, we constrain and calibrate a regional groundwater flow model with noble-gas-derived recharge elevations for the first time. Tritium and noble gas tracer results improved the site conceptual model by identifying a previously uncertain contribution of mountain block recharge from the Coast Mountains to an alluvial coastal aquifer in humid southwestern British Columbia. The revised conceptual model was integrated into a three-dimensional numerical groundwater flow model and calibrated to hydraulic head data in addition to recharge elevations estimated from noble gas recharge temperatures. Recharge elevations proved to be imperative for constraining hydraulic conductivity, recharge location, and bedrock geometry, and thus minimizing model nonuniqueness. Results indicate that 45% of recharge to the aquifer is mountain block recharge. A similar match between measured and modeled heads was achieved in a second numerical model that excludes the mountain block (no mountain block recharge), demonstrating that hydraulic head data alone are incapable of quantifying mountain block recharge. This result has significant implications for understanding and managing source water protection in recharge areas, potential effects of climate change, the overall water budget, and ultimately ensuring groundwater sustainability.

Atmospheric Carbon Dioxide Record from Mauna Loa (1958-2008)

DOE Data Explorer

Keeling, R. F. [Scripps Institution of Oceanography, University of California, La Jolla, California; Piper, S. C. [Scripps Institution of Oceanography, University of California, La Jolla, California; Bollenbacher, A. F. [Scripps Institution of Oceanography, University of California, La Jolla, California; Walker, J. S. [Scripps Institution of Oceanography, University of California, La Jolla, California

2009-02-01

Air samples at Mauna Loa are collected continuously from air intakes at the top of four 7-m towers and one 27-m tower. Four air samples are collected each hour for the purpose of determining the CO2 concentration. Determinations of CO2 are made by using a Siemens Ultramat 3 nondispersive infrared gas analyzer with a water vapor freeze trap. This analyzer registers the concentration of CO2 in a stream of air flowing at ~0.5 L/min. Every 30 minutes, the flow is replaced by a stream of calibrating gas or "working reference gas". In December 1983, CO2-in-N2 calibration gases were replaced with the currently used CO2-in-air calibration gases. These calibration gases and other reference gases are compared periodically to determine the instrument sensitivity and to check for possible contamination in the air-handling system. These reference gases are themselves calibrated against specific standard gases whose CO2 concentrations are determined manometrically. Greater details about the sampling methods at Mauna Loa are given in Keeling et al. (1982) and Keeling et al. (2002).

Analysis of a Pneumatic Probe for Measuring Exhaust-Gas Temperatures with Some Preliminary Experimental Results

NASA Technical Reports Server (NTRS)

Scadron, Marvin D.

1952-01-01

A pneumatic probe based on continuity of mass flow through two restrictions separated by a cooling chamber was constructed to measure gas temperature at and beyond the limit of thermocouples. This probe consisted of a subsonic flat-plate orifice for the first restriction and a sonic-flow converging-diverging nozzle for the second restriction. The effect of variation in gas constants on the calibration is examined for common engine-exhaust gases. A high-temperature wind tunnel that allowed calibration of the probe at temperatures up to 2000 deg R and. Mach numbers up to 0.8 is described. Agreement to better than 30 deg R between pneumatic probe indication and the indication of a rake of radiation shielded thermocouples indicates that extrapolation of the calibration to higher temperatures is possible with fair accuracy

Research yields precise uncertainty equations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, E.H.; Ferguson, K.R.

1987-08-03

Results of a study of orifice-meter accuracy by Chevron Oil Field Research Co. at its Venice, La., calibration facility have important implications for natural gas custody-transfer measurement. The calibration facility, data collection, and equipment calibration were described elsewhere. This article explains the derivation of uncertainty factors and details the study's findings. The results were based on calibration of two 16-in. orifice-meter runs. The experimental data cover a beta-ratio range of from 0.27 to 0.71 and a Reynolds number range of from 4,000,000 to 35,000,000. Discharge coefficients were determined by comparing the orifice flow to the flow from critical-flow nozzles.

Field calibration of orifice meters for natural gas flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ting, V.C.; Shen, J.J.S.

1989-03-01

This paper presents the orifice calibration results for nominal 15.24, 10.16, and 5.08-cm (6,4,2-in.) orifice meters conducted at the Chevron's Sand Hills natural gas flow measurement facility in Crane, Texas. Over 200 test runs were collected in a field environment to study the accuracy of the orifice meters. Data were obtained at beta ratios ranging from 0.12 to 0.74 at the nominal conditions of 4576 kPa and 27{sup 0}C (650 psig and 80{sup 0}F) with a 0.57 specific gravity processed, pipeline quality natural gas. A bank of critical flow nozzles was used as the flow rate proving device to calibratemore » the orifice meters. Orifice discharge coefficients were computed with ANSI/API 2530-1985 (AGA3) and ISO 5167/ASME MFC-3M-1984 equations for every set of data points. With the orifice bore Reynolds numbers ranging from 1 to 9 million, the Sand Hills calibration data bridge the gap between the Ohio State water data at low Reynolds numbers and Chevron's high Reynolds number test data taken at a large test facility in Venice, Louisiana. The test results also successfully demonstrate that orifice meters can be accurately proved with critical flow nozzles under realistic field conditions.« less

Gas Dynamics, Characterization, and Calibration of Fast Flow Flight Cascade Impactor Quartz Crystal Microbalances (QCM) for Aerosol Measurements

NASA Technical Reports Server (NTRS)

Grant, J.R.; Thorpe, A. N.; James, C.; Michael, A.; Ware, M.; Senftle, F.; Smith, S.

1997-01-01

During recent high altitude flights, we have tested the aerosol section of the fast flow flight cascade impactor quartz crystal microbalance (QCM) on loan to Howard University from NASA. The aerosol mass collected during these flights was disappointingly small. Increasing the flow through the QCM did not correct the problem. It was clear that the instrument was not being operated under proper conditions for aerosol collect ion primarily because the gas dynamics is not well understood. A laboratory study was therefore undertaken using two different fast flow QCM's in an attempt to establish the gas flow characteristics of the aerosol sections and its effect on particle collection, Some tests were made at low temperatures but most of the work reported here was carried out at room temperature. The QCM is a cascade type impactor originally designed by May (1945) and later modified by Anderson (1966) and Mercer et al (1970) for chemical gas analysis. The QCM has been used extensively for collecting and sizing stratospheric aerosol particles. In this paper all flow rates are given or corrected and referred to in terms of air at STP. All of the flow meters were kept at STP. Although there have been several calibration and evaluation studies of moderate flow cascade impactors of less than or equal to 1 L/rein., there is little experimental information on the gas flow characteristics for fast flow rates greater than 1 L/rein.

Particle dispersing system and method for testing semiconductor manufacturing equipment

DOEpatents

Chandrachood, Madhavi; Ghanayem, Steve G.; Cantwell, Nancy; Rader, Daniel J.; Geller, Anthony S.

1998-01-01

The system and method prepare a gas stream comprising particles at a known concentration using a particle disperser for moving particles from a reservoir of particles into a stream of flowing carrier gas. The electrostatic charges on the particles entrained in the carrier gas are then neutralized or otherwise altered, and the resulting particle-laden gas stream is then diluted to provide an acceptable particle concentration. The diluted gas stream is then split into a calibration stream and the desired output stream. The particles in the calibration stream are detected to provide an indication of the actual size distribution and concentration of particles in the output stream that is supplied to a process chamber being analyzed. Particles flowing out of the process chamber within a vacuum pumping system are detected, and the output particle size distribution and concentration are compared with the particle size distribution and concentration of the calibration stream in order to determine the particle transport characteristics of a process chamber, or to determine the number of particles lodged in the process chamber as a function of manufacturing process parameters such as pressure, flowrate, temperature, process chamber geometry, particle size, particle charge, and gas composition.

40 CFR 86.331-79 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2010 CFR

2010-07-01

... plot of the difference between the span and zero response versus fuel flow will be similar to the one... least one-half hour after the oven has reached temperature for the system to equilibrate. (c) Initial... difference between the span-gas response and the zero-gas response. Incrementally adjust the fuel flow above...

Pockels-effect cell for gas-flow simulation

NASA Astrophysics Data System (ADS)

Weimer, D.

1982-05-01

A Pockels effect cell using a 75 cu cm DK*P crystal was developed and used as a gas flow simulator. Index of refraction gradients were produced in the cell by the fringing fields of parallel plate electrodes. Calibration curves for the device were obtained for index of refraction gradients in excess of .00025 m.

Effect of variation in argon content of calibration gases on determination of atmospheric carbon dioxide.

PubMed

Min, Deullae; Kang, Namgoo; Moon, Dong Min; Lee, Jin Bok; Lee, Dong Soo; Kim, Jin Seog

2009-12-15

Carbon dioxide (CO(2)) is a greenhouse gas that makes by far the largest contribution to the global warming of the Earth's atmosphere. For the measurements of atmospheric CO(2) a non-dispersive infrared analyzer (NDIR) and gas chromatography are conventionally being used. We explored whether and to what degree argon content can influence the determination of atmospheric CO(2) using the comparison of CO(2) concentrations between the sample gas mixtures with varying Ar amounts at 0 and 18.6 mmol mol(-1) and the calibration gas mixtures with Ar at 8.4, 9.1, and 9.3 mmol mol(-1). We newly discovered that variation of Ar content in calibration gas mixtures could undermine accuracy for precise and accurate determination of atmospheric CO(2) in background air. The differences in CO(2) concentration due to the variation of Ar content in the calibration gas mixtures were negligible (<+/-0.03 micromol mol(-1)) for NDIR systems whereas they noticeably increased (<+/-1.09 micromol mol(-1)) especially for the modified GC systems to enhance instrumental sensitivity. We found that the thermal mass flow controller is the main source of the differences although such differences appeared only in the presence of a flow restrictor in GC systems. For reliable monitoring of real atmospheric CO(2) samples, one should use calibration gas mixtures that contain Ar content close to the level (9.332 mmol mol(-1)) in the ambient air as possible. Practical guidelines were highlighted relating to selection of appropriate analytical approaches for the accurate and precise measurements of atmospheric CO(2). In addition, theoretical implications from the findings were addressed.

40 CFR 91.315 - Analyzer initial calibration.

Code of Federal Regulations, 2013 CFR

2013-07-01

... in § 91.316(b). (c) Zero setting and calibration. Using purified synthetic air (or nitrogen), set the CO, CO2, NOX and HC analyzers at zero. Connect the appropriate calibrating gases to the analyzers and record the values. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

40 CFR 91.315 - Analyzer initial calibration.

Code of Federal Regulations, 2014 CFR

2014-07-01

... in § 91.316(b). (c) Zero setting and calibration. Using purified synthetic air (or nitrogen), set the CO, CO2, NOX and HC analyzers at zero. Connect the appropriate calibrating gases to the analyzers and record the values. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

40 CFR 91.315 - Analyzer initial calibration.

Code of Federal Regulations, 2012 CFR

2012-07-01

... in § 91.316(b). (c) Zero setting and calibration. Using purified synthetic air (or nitrogen), set the CO, CO2, NOX and HC analyzers at zero. Connect the appropriate calibrating gases to the analyzers and record the values. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

40 CFR 91.315 - Analyzer initial calibration.

Code of Federal Regulations, 2010 CFR

2010-07-01

... in § 91.316(b). (c) Zero setting and calibration. Using purified synthetic air (or nitrogen), set the CO, CO2, NOX and HC analyzers at zero. Connect the appropriate calibrating gases to the analyzers and record the values. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

40 CFR 91.315 - Analyzer initial calibration.

Code of Federal Regulations, 2011 CFR

2011-07-01

... in § 91.316(b). (c) Zero setting and calibration. Using purified synthetic air (or nitrogen), set the CO, CO2, NOX and HC analyzers at zero. Connect the appropriate calibrating gases to the analyzers and record the values. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

Performance Testing of Tracer Gas and Tracer Aerosol Detectors for use in Radionuclide NESHAP Compliance Testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fuehne, David Patrick; Lattin, Rebecca Renee

The Rad-NESHAP program, part of the Air Quality Compliance team of LANL’s Compliance Programs group (EPC-CP), and the Radiation Instrumentation & Calibration team, part of the Radiation Protection Services group (RP-SVS), frequently partner on issues relating to characterizing air flow streams. This memo documents the most recent example of this partnership, involving performance testing of sulfur hexafluoride detectors for use in stack gas mixing tests. Additionally, members of the Rad-NESHAP program performed a functional trending test on a pair of optical particle counters, comparing results from a non-calibrated instrument to a calibrated instrument. Prior to commissioning a new stack samplingmore » system, the ANSI Standard for stack sampling requires that the stack sample location must meet several criteria, including uniformity of tracer gas and aerosol mixing in the air stream. For these mix tests, tracer media (sulfur hexafluoride gas or liquid oil aerosol particles) are injected into the stack air stream and the resulting air concentrations are measured across the plane of the stack at the proposed sampling location. The coefficient of variation of these media concentrations must be under 20% when evaluated over the central 2/3 area of the stack or duct. The instruments which measure these air concentrations must be tested prior to the stack tests in order to ensure their linear response to varying air concentrations of either tracer gas or tracer aerosol. The instruments used in tracer gas and aerosol mix testing cannot be calibrated by the LANL Standards and Calibration Laboratory, so they would normally be sent off-site for factory calibration by the vendor. Operational requirements can prevent formal factory calibration of some instruments after they have been used in hazardous settings, e.g., within a radiological facility with potential airborne contamination. The performance tests described in this document are intended to demonstrate the reliable performance of the test instruments for the specific tests used in stack flow characterization.« less

Measurement of trace impurities in ultra pure hydrogen and deuterium at the parts-per-billion level using gas chromatography

NASA Astrophysics Data System (ADS)

Ganzha, V.; Ivshin, K.; Kammel, P.; Kravchenko, P.; Kravtsov, P.; Petitjean, C.; Trofimov, V.; Vasilyev, A.; Vorobyov, A.; Vznuzdaev, M.; Wauters, F.

2018-02-01

A series of muon experiments at the Paul Scherrer Institute in Switzerland deploy ultra-pure hydrogen active targets. A new gas impurity analysis technique was developed, based on conventional gas chromatography, with the capability to measure part-per-billion (ppb) traces of nitrogen and oxygen in hydrogen and deuterium. Key ingredients are a cryogenic admixture accumulation, a directly connected sampling system and a dedicated calibration setup. The dependence of the measured concentration on the sample volume was investigated, confirming that all impurities from the sample gas are collected in the accumulation column and measured with the gas chromatograph. The system was calibrated utilizing dynamic dilution of admixtures into the gas flow down to sub-ppb level concentrations. The total amount of impurities accumulated in the purification system during a three month long experimental run was measured and agreed well with the calculated amount based on the measured concentrations in the flow.

Modeling Improvements and Users Manual for Axial-flow Turbine Off-design Computer Code AXOD

NASA Technical Reports Server (NTRS)

Glassman, Arthur J.

1994-01-01

An axial-flow turbine off-design performance computer code used for preliminary studies of gas turbine systems was modified and calibrated based on the experimental performance of large aircraft-type turbines. The flow- and loss-model modifications and calibrations are presented in this report. Comparisons are made between computed performances and experimental data for seven turbines over wide ranges of speed and pressure ratio. This report also serves as the users manual for the revised code, which is named AXOD.

High vacuum measurements and calibrations, molecular flow fluid transient effects

DOE PAGES

Leishear, Robert A.; Gavalas, Nickolas A.

2015-04-29

High vacuum pressure measurements and calibrations below 1 × 10 -8 Torr are problematic. Specifically, measurement accuracies change drastically for vacuum gauges when pressures are suddenly lowered in vacuum systems. How can gauges perform like this? A brief system description is first required to answer this question. Calibrations were performed using a vacuum calibration chamber with attached vacuum gauges. To control chamber pressures, vacuum pumps decreased the chamber pressure while nitrogen tanks increased the chamber pressure. By balancing these opposing pressures, equilibrium in the chamber was maintained at selected set point pressures to perform calibrations. When pressures were suddenly decreasedmore » during set point adjustments, a sudden rush of gas from the chamber also caused a surge of gas from the gauges to decrease the pressures in those gauges. Gauge pressures did not return to equilibrium as fast as chamber pressures due to the sparse distribution of gas molecules in the system. This disparity in the rate of pressure changes caused the pressures in different gauges to be different than expected. This discovery was experimentally proven to show that different gauge designs return to equilibrium at different rates, and that gauge accuracies vary for different gauge designs due to fluid transients in molecular flow.« less

40 CFR 1065.307 - Linearity verification.

Code of Federal Regulations, 2011 CFR

2011-07-01

... different flow rates. Use a gravimetric reference measurement (such as a scale, balance, or mass comparator... the gas-division system to divide the span gas with purified air or nitrogen. Select gas divisions... verification for gravimetric PM balances, use external calibration weights that that meet the requirements in...

A primary standard for the calibration of sniffer test leak devices

NASA Astrophysics Data System (ADS)

Jousten, Karl; Becker, Ute

2009-10-01

Test leaks with a gas flow to atmospheric pressure are often called sniffer test leaks. They are used to calibrate leak detectors for sniffing applications. Sniffer test leaks need calibration against a standard. A primary standard for the calibration of sniffer test leaks with relatively low measurement uncertainties is described. It is assured that the measurement result is traceable to the relevant SI units and that there is a well-known and complete measurement uncertainty budget. The measurement range of the system is from 4 × 10-11 mol s-1 (corresponding to 10-4 Pa l s-1 at 23 °C) to 4 × 10-9 mol s-1 (10-2 Pa l s-1 at 23 °C), which is the most often needed range in industry of around 1 g loss per year of the cooling agent R134a. The temperature where the calibration can be carried out may vary from 18 °C to 30 °C. The flow rate of any test gas not condensing in this temperature range can be measured.

Calibration of Axisymmetric and Quasi-1D Solvers for High Enthalpy Nozzles

NASA Technical Reports Server (NTRS)

Papadopoulos, P. E.; Gochberg, L. A.; Tokarcik-Polsky, S.; Venkatapathy, E.; Deiwert, G. S.; Edwards, Thomas A. (Technical Monitor)

1994-01-01

The proposed paper will present a numerical investigation of the flow characteristics and boundary layer development in the nozzles of high enthalpy shock tunnel facilities used for hypersonic propulsion testing. The computed flow will be validated against existing experimental data. Pitot pressure data obtained at the entrance of the test cabin will be used to validate the numerical simulations. It is necessary to accurately model the facility nozzles in order to characterize the test article flow conditions. Initially the axisymmetric nozzle flow will be computed using a Navier Stokes solver for a range of reservoir conditions. The calculated solutions will be compared and calibrated against available experimental data from the DLR HEG piston-driven shock tunnel and the 16-inch shock tunnel at NASA Ames Research Center. The Reynolds number is assumed to be high enough at the throat that the boundary layer flow is assumed turbulent at this point downstream. The real gas affects will be examined. In high Mach number facilities the boundary layer is thick. Attempts will be made to correlate the boundary layer displacement thickness. The displacement thickness correlation will be used to calibrate the quasi-1D codes NENZF and LSENS in order to provide fast and efficient tools of characterizing the facility nozzles. The calibrated quasi-1D codes will be implemented to study the effects of chemistry and the flow condition variations at the test section due to small variations in the driver gas conditions.

ANN-based calibration model of FTIR used in transformer online monitoring

NASA Astrophysics Data System (ADS)

Li, Honglei; Liu, Xian-yong; Zhou, Fangjie; Tan, Kexiong

2005-02-01

Recently, chromatography column and gas sensor have been used in online monitoring device of dissolved gases in transformer oil. But some disadvantages still exist in these devices: consumption of carrier gas, requirement of calibration, etc. Since FTIR has high accuracy, consume no carrier gas and require no calibration, the researcher studied the application of FTIR in such monitoring device. Experiments of "Flow gas method" were designed, and spectrum of mixture composed of different gases was collected with A BOMEM MB104 FTIR Spectrometer. A key question in the application of FTIR is that: the absorbance spectrum of 3 fault key gases, including C2H4, CH4 and C2H6, are overlapped seriously at 2700~3400cm-1. Because Absorbance Law is no longer appropriate, a nonlinear calibration model based on BP ANN was setup to in the quantitative analysis. The height absorbance of C2H4, CH4 and C2H6 were adopted as quantitative feature, and all the data were normalized before training the ANN. Computing results show that the calibration model can effectively eliminate the cross disturbance to measurement.

40 CFR 57.404 - Measurements, records, and reports.

Code of Federal Regulations, 2010 CFR

2010-07-01

... and record at least one measurement of sulfur dioxide concentration and stack gas flow rate from the... manufacturer's recommended zero adjustment and calibration procedures at least once per 24-hour operating... which clearly show instrument readings before and after zero adjustment and calibration. (5) The results...

Validation of a new mixing chamber system for breath-by-breath indirect calorimetry.

PubMed

Kim, Do-Yeon; Robergs, Robert Andrew

2012-02-01

Limited validation research exists for applications of breath-by-breath systems of expired gas analysis indirect calorimetry (EGAIC) during exercise. We developed improved hardware and software for breath-by-breath indirect calorimetry (NEW) and validated this system as well as a commercial system (COM) against 2 methods: (i) mechanical ventilation with known calibration gas, and (ii) human subjects testing for 5 min each at rest and cycle ergometer exercise at 100 and 175 W. Mechanical calibration consisted of medical grade and certified calibration gas ((4.95% CO(2), 12.01% O(2), balance N(2)), room air (20.95% O(2), 0.03% CO(2), balance N(2)), and 100% nitrogen), and an air flow turbine calibrated with a 3-L calibration syringe. Ventilation was mimicked manually using complete 3-L calibration syringe manouvers at a rate of 10·min(-1) from a Douglas bag reservoir of calibration gas. The testing of human subjects was completed in a counterbalanced sequence based on 5 repeated tests of all conditions for a single subject. Rest periods of 5 and 10 min followed the 100 and 175 W conditions, respectively. COM and NEW had similar accuracy when tested with known ventilation and gas fractions. However, during human subjects testing COM significantly under-measured carbon dioxide gas fractions, over-measured oxygen gas fractions and minute ventilation, and resulted in errors to each of oxygen uptake, carbon dioxide output, and respiratory exchange ratio. These discrepant findings reveal that controlled ventilation and gas fractions are insufficient to validate breath-by-breath, and perhaps even time-averaged, systems of EGAIC. The errors of the COM system reveal the need for concern over the validity of commercial systems of EGAIC.

Uncertainty and Traceability for the CEESI Iowa Natural Gas Facility.

PubMed

Johnson, Aaron; Kegel, Tom

2004-01-01

This paper analyzes the uncertainty of a secondary flow measurement facility that calibrates a significant fraction of United States and foreign flow meters used for custody transfer of natural gas. The facility, owned by the Colorado Experimental Engineering Station Incorporated (CEESI), is located in Iowa. This facility measures flow with nine turbine meter standards, each of which is traceable to the NIST primary flow standard. The flow capacity of this facility ranges from 0.7 actual m(3)/s to 10.7 actual m(3)/s at nominal pressures of 7174 kPa and at ambient temperatures. Over this flow range the relative expanded flow uncertainty varies from 0.28 % to 0.30 % (depending on flow).

40 CFR 1065.307 - Linearity verification.

Code of Federal Regulations, 2012 CFR

2012-07-01

... meter at different flow rates. Use a gravimetric reference measurement (such as a scale, balance, or... nitrogen. Select gas divisions that you typically use. Use a selected gas division as the measured value.... For linearity verification for gravimetric PM balances, use external calibration weights that that...

40 CFR 1065.307 - Linearity verification.

Code of Federal Regulations, 2013 CFR

2013-07-01

... meter at different flow rates. Use a gravimetric reference measurement (such as a scale, balance, or... nitrogen. Select gas divisions that you typically use. Use a selected gas division as the measured value.... For linearity verification for gravimetric PM balances, use external calibration weights that that...

Thermal Analysis of a Carbon Fiber Rope Barrier for Use in the Reusable Solid Rocket Motor Nozzle Joint-2

NASA Technical Reports Server (NTRS)

Clayton, J. Louie

2002-01-01

This study provides development and verification of analysis methods used to assess performance of a carbon fiber rope (CFR) thermal barrier system that is currently being qualified for use in Reusable Solid Rocket Motor (RSRM) nozzle joint-2. Modeled geometry for flow calculations considers the joint to be vented with the porous CFR barriers placed in the 'open' assembly gap. Model development is based on a 1-D volume filling approach where flow resistances (assembly gap and CFRs) are defined by serially connected internal flow and the porous media 'Darcy' relationships. Combustion gas flow rates are computed using the volume filling code by assuming a lumped distribution total joint fill volume on a per linear circumferential inch basis. Gas compressibility, friction and heat transfer are included in the modeling. Gas-to-wall heat transfer is simulated by concurrent solution of the compressible flow equations and a large thermal 2-D finite element (FE) conduction grid. The derived numerical technique loosely couples the FE conduction matrix with the compressible gas flow equations. Free constants that appear in the governing equations are calibrated by parametric model comparison to hot fire subscale test results. The calibrated model is then used to make full-scale motor predictions using RSRM aft dome environments. Model results indicate that CFR thermal barrier systems will provide a thermally benign and controlled pressurization environment for the RSRM nozzle joint-2 primary seal activation.

Thermal Analysis of a Carbon Fiber Rope Barrier for Use in the Reusable Solid Rocket Motor Nozzle Joint-2

NASA Technical Reports Server (NTRS)

Clayton, J. Louie; Phelps, Lisa (Technical Monitor)

2001-01-01

This study provides for development and verification of analysis methods used to assess performance of a carbon fiber rope (CFR) thermal barrier system that is currently being qualified for use in Reusable Solid Rocket Motor (RSRM) nozzle joint-2. Modeled geometry for flow calculations considers the joint to be vented with the porous CFR barriers placed in the "open' assembly gap. Model development is based on a 1-D volume filling approach where flow resistances (assembly gap and CFRs) are defined by serially connected internal flow and the porous media "Darcy" relationships. Combustion gas flow rates are computed using the volume filling code by assuming a lumped distribution total joint fill volume on a per linear circumferential inch basis. Gas compressibility, friction and heat transfer are included in the modeling. Gas-to-wall heat transfer is simulated by concurrent solution of the compressible flow equations and a large thermal 2-D finite element (FE) conduction grid. The derived numerical technique loosely couples the FE conduction matrix with the compressible gas flow equations, Free constants that appear in the governing equations are calibrated by parametric model comparison to hot fire subscale test results. The calibrated model is then used to make full-scale motor predictions using RSRM aft dome environments. Model results indicate that CFR thermal barrier systems will provide a thermally benign and controlled pressurization environment for the RSRM nozzle joint-2 primary seal activation.

40 CFR 89.313 - Initial calibration of analyzers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... the HFID analyzer shall be optimized in order to meet the specifications in § 89.319(b)(2). (c) Zero... analyzers shall be set at zero. (2) Introduce the appropriate calibration gases to the analyzers and the values recorded. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

40 CFR 89.313 - Initial calibration of analyzers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... the HFID analyzer shall be optimized in order to meet the specifications in § 89.319(b)(2). (c) Zero... analyzers shall be set at zero. (2) Introduce the appropriate calibration gases to the analyzers and the values recorded. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

40 CFR 89.313 - Initial calibration of analyzers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... the HFID analyzer shall be optimized in order to meet the specifications in § 89.319(b)(2). (c) Zero... analyzers shall be set at zero. (2) Introduce the appropriate calibration gases to the analyzers and the values recorded. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

40 CFR 89.313 - Initial calibration of analyzers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... the HFID analyzer shall be optimized in order to meet the specifications in § 89.319(b)(2). (c) Zero... analyzers shall be set at zero. (2) Introduce the appropriate calibration gases to the analyzers and the values recorded. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

40 CFR 89.313 - Initial calibration of analyzers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the HFID analyzer shall be optimized in order to meet the specifications in § 89.319(b)(2). (c) Zero... analyzers shall be set at zero. (2) Introduce the appropriate calibration gases to the analyzers and the values recorded. The same gas flow rates shall be used as when sampling exhaust. (d) Rechecking of zero...

Nitric Oxide Measurement Study. Volume I. Optical Calibration

DTIC Science & Technology

1979-10-18

Comparison ......... ........................ ... 111-52 III-L Static Cell Calibration Data (NO in N2) ... .......... ... 111-62 III-M Flowing Gas Heater (FGH...appears necessary in order to continually replace the heated NO, a static heated cell would clearly be impractical. Several other calibration devices can...and Frech’s conclusions are accepted, then a static quartz cell could be used up to 1100 K only, of course, if extreme care is taken so as to avoid

An Investigation of Slurry Fuel Combustion.

DTIC Science & Technology

1981-01-01

tit Lil’ sitas wtae f).4 mm ap.art. w w =Q L-1~ rAn Li w > 0 0- - q The propane gas flow rate was metered withi a Matlieson Model 604 rotameter and...controlled by a Harris Model 2515 pressure regulator with an output capacity of 0-0.69 MPa. The flow rate of the iydrog’en gas was metered with a...propane 3nd hydrogen flows were calibrated with a Precision Scientific Companv wet-test meter (2.83 ml/rev). The fuel drops were mounted with a

Low pressure gas flow analysis through an effusive inlet using mass spectrometry

NASA Technical Reports Server (NTRS)

Brown, David R.; Brown, Kenneth G.

1988-01-01

A mass spectrometric method for analyzing flow past and through an effusive inlet designed for use on the tethered satellite and other entering vehicles is discussed. Source stream concentrations of species in a gaseous mixture are determined using a calibration of measured mass spectral intensities versus source stream pressure for standard gas mixtures and pure gases. Concentrations are shown to be accurate within experimental error. Theoretical explanations for observed mass discrimination effects as they relate to the various flow situations in the effusive inlet and the experimental apparatus are discussed.

Experimental constraints on the outgassing dynamics of basaltic magmas

NASA Astrophysics Data System (ADS)

Pioli, L.; Bonadonna, C.; Azzopardi, B. J.; Phillips, J. C.; Ripepe, M.

2012-03-01

The dynamics of separated two-phase flow of basaltic magmas in cylindrical conduits has been explored combining large-scale experiments and theoretical studies. Experiments consisted of the continuous injection of air into water or glucose syrup in a 0.24 m diameter, 6.5 m long bubble column. The model calculates vesicularity and pressure gradient for a range of gas superficial velocities (volume flow rates/pipe area, 10-2-102 m/s), conduit diameters (100-2 m), and magma viscosities (3-300 Pa s). The model is calibrated with the experimental results to extrapolate key flow parameters such as Co (distribution parameter) and Froude number, which control the maximum vesicularity of the magma in the column, and the gas rise speed of gas slugs. It predicts that magma vesicularity increases with increasing gas volume flow rate and decreases with increasing conduit diameter, until a threshold value (45 vol.%), which characterizes churn and annular flow regimes. Transition to annular flow regimes is expected to occur at minimum gas volume flow rates of 103-104 m3/s. The vertical pressure gradient decreases with increasing gas flow rates and is controlled by magma vesicularity (in bubbly flows) or the length and spacing of gas slugs. This study also shows that until conditions for separated flow are met, increases in magma viscosity favor stability of slug flow over bubbly flow but suggests coexistence between gas slugs and small bubbles, which contribute to a small fraction of the total gas outflux. Gas flow promotes effective convection of the liquid, favoring magma homogeneity and stable conditions.

40 CFR 86.331-79 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for New Gasoline-Fueled and Diesel-Fueled Heavy-Duty Engines; Gaseous Exhaust Test Procedures § 86... difference between the span-gas response and the zero-gas response. Incrementally adjust the fuel flow above...

40 CFR 86.331-79 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for New Gasoline-Fueled and Diesel-Fueled Heavy-Duty Engines; Gaseous Exhaust Test Procedures § 86... difference between the span-gas response and the zero-gas response. Incrementally adjust the fuel flow above...

40 CFR 98.444 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

...), the American Gas Association (AGA), the American Society of Mechanical Engineers (ASME), the American... any flow meter calibrations performed are National Institute of Standards and Technology (NIST...

Cryogenic flow rate measurement with a laser Doppler velocimetry standard

NASA Astrophysics Data System (ADS)

Maury, R.; Strzelecki, A.; Auclercq, C.; Lehot, Y.; Loubat, S.; Chevalier, J.; Ben Rayana, F.

2018-03-01

A very promising alternative to the state-of-the-art static volume measurements for liquefied natural gas (LNG) custody transfer processes is the dynamic principle of flow metering. As the Designated Institute (DI) of the LNE (‘Laboratoire National de métrologie et d’Essais’, being the French National Metrology Institute) for high-pressure gas flow metering, Cesame-Exadebit is involved in various research and development programs. Within the framework of the first (2010-2013) and second (2014-2017) EURAMET Joint Research Project (JRP), named ‘Metrological support for LNG custody transfer and transport fuel applications’, Cesame-Exadebit explored a novel cryogenic flow metering technology using laser Doppler velocimetry (LDV) as an alternative to ultrasonic and Coriolis flow metering. Cesame-Exadebit is trying to develop this technique as a primary standard for cryogenic flow meters. Currently, cryogenic flow meters are calibrated at ambient temperatures with water. Results are then extrapolated to be in the Reynolds number range of real applications. The LDV standard offers a unique capability to perform online calibration of cryogenic flow meters in real conditions (temperature, pressure, piping and real flow disturbances). The primary reference has been tested on an industrial process in a LNG terminal during truck refuelling. The reference can calibrate Coriolis flow meters being used daily with all the real environmental constraints, and its utilisation is transparent for LNG terminal operators. The standard is traceable to Standard International units and the combined extended uncertainties have been determined and estimated to be lower than 0.6% (an ongoing improvement to reducing the correlation function uncertainty, which has a major impact in the uncertainty estimation).

The Development of a Gas-Liquid Two-Phase Flow Sensor Applicable to CBM Wellbore Annulus.

PubMed

Wu, Chuan; Wen, Guojun; Han, Lei; Wu, Xiaoming

2016-11-18

The measurement of wellbore annulus gas-liquid two-phase flow in CBM (coalbed methane) wells is of great significance for reasonably developing gas drainage and extraction processes, estimating CBM output, judging the operating conditions of CBM wells and analyzing stratum conditions. Hence, a specially designed sensor is urgently needed for real-time measurement of gas-liquid two-phase flow in CBM wellbore annulus. Existing flow sensors fail to meet the requirements of the operating conditions of CBM wellbore annulus due to such factors as an inapplicable measurement principle, larger size, poor sealability, high installation accuracy, and higher requirements for fluid media. Therefore, based on the principle of a target flowmeter, this paper designs a new two-phase flow sensor that can identify and automatically calibrate different flow patterns of two-phase flows. Upon the successful development of the new flow sensor, lab and field tests were carried out, and the results show that the newly designed sensor, with a measurement accuracy of ±2.5%, can adapt to the operating conditions of CBM wells and is reliable for long-term work.

Two-Phase Flow Instrumentation Review Group Meeting. Proceedings of Meeting Held in Silver Spring, Maryland on January 13-14, 1977

DTIC Science & Technology

1978-03-01

ADWRESS OInclud Zip Code) 10. PROJECTfTASK/WORK UNI1 VO. Same as 9. above. I1. CONTRACT NO. 13. TYPE OF REPORT PERIOD COVERED (inclusive dews ) Meeting...Discussion of basic principles. c. Lists of y-emitling tracers for gas ; for liquid; commercially available radioisotope milking systems; elements easily...factors) - single phase loops, full flow, (2) prototype calibration (a) gas -water loop, (b) geometry effect. (c) scaling. (3) proof testing - simulation of

FInd Gas Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Travis, Bryan; Sauer, Jeremy; Dubey, Manvendra

2017-02-24

FIGS is a neural network software that ingests real time synchronized field data on environmental flow fields and turbulence and gas concentration variations at high frequency and uses an error minimization algorithm to locate the gas source and quantify its strength. The software can be interfaced with atmospheric, oceanic and subsurface instruments in a variety of platforms stationary or mobile (e.g. cars, UAVs, submersible vehicles or boreholes) and used to find gas sources by smart use of data and phenomenology. FIGS can be trained by phenomenological model of the flow fields in the environment of interest and/or be calibrated bymore » controlled release. After initial deployment the FIGS learning will grow with time as it accumulates data on source quantification. FIGS can be installed on any computer from small beagle-bones for field deployment/end-use to PC/MACs/main-frame for training/analysis. FIGS has been trained (using LANL's high resolution atmospheric simulations) and calibrated, tested and evaluated in the field and shown to perform well in finding and quantifying methane leaks at 10-100m scales at well pads by ingesting atmospheric measurements. The code is applicable to gas and particle source location at large scales.« less

SI-traceable and dynamic reference gas mixtures for water vapour at polar and high troposphere atmospheric levels

NASA Astrophysics Data System (ADS)

Guillevic, Myriam; Pascale, Céline; Mutter, Daniel; Wettstein, Sascha; Niederhauser, Bernhard

2017-04-01

In the framework of METAS' AtmoChem-ECV project, new facilities are currently being developed to generate reference gas mixtures for water vapour at concentrations measured in the high troposphere and polar regions, in the range 1-20 µmol/mol (ppm). The generation method is dynamic (the mixture is produced continuously over time) and SI-traceable (i.e. the amount of substance fraction in mole per mole is traceable to the definition of SI-units). The generation process is composed of three successive steps. The first step is to purify the matrix gas, nitrogen or synthetic air. Second, this matrix gas is spiked with the pure substance using a permeation technique: a permeation device contains a few grams of pure water in liquid form and loses it linearly over time by permeation through a membrane. In a third step, to reach the desired concentration, the first, high concentration mixture exiting the permeation chamber is then diluted with a chosen flow of matrix gas with one or two subsequent dilution steps. All flows are piloted by mass flow controllers. All parts in contact with the gas mixture are passivated using coated surfaces, to reduce adsorption/desorption processes as much as possible. The mixture can eventually be directly used to calibrate an analyser. The standard mixture produced by METAS' dynamic setup was injected into a chilled mirror from MBW Calibration AG, the designated institute for absolute humidity calibration in Switzerland. The used chilled mirror, model 373LX, is able to measure frost point and sample pressure and therefore calculate the water vapour concentration. This intercomparison of the two systems was performed in the range 4-18 ppm water vapour in synthetic air, at two different pressure levels, 1013.25 hPa and 2000 hPa. We present here METAS' dynamic setup, its uncertainty budget and the first results of the intercomparison with MBW's chilled mirror.

Thermal Fault Tolerance Analysis of Carbon Fiber Rope Barrier Systems for Use in the Reusable Solid Rocket Motor ( RSRM) Nozzle Joints

NASA Technical Reports Server (NTRS)

Clayton, J. Louie; Phelps, Lisa (Technical Monitor)

2001-01-01

Carbon Fiber Rope (CFR) thermal barrier systems are being considered for use in several RSRM (Reusable Solid Rocket Motor) nozzle joints as a replacement for the current assembly gap close-out process/design. This study provides for development and test verification of analysis methods used for flow-thermal modeling of a CFR thermal barrier subject to fault conditions such as rope combustion gas blow-by and CFR splice failure. Global model development is based on a 1-D (one dimensional) transient volume filling approach where the flow conditions are calculated as a function of internal 'pipe' and porous media 'Darcy' flow correlations. Combustion gas flow rates are calculated for the CFR on a per-linear inch basis and solved simultaneously with a detailed thermal-gas dynamic model of a local region of gas blow by (or splice fault). Effects of gas compressibility, friction and heat transfer are accounted for the model. Computational Fluid Dynamic (CFD) solutions of the fault regions are used to characterize the local flow field, quantify the amount of free jet spreading and assist in the determination of impingement film coefficients on the nozzle housings. Gas to wall heat transfer is simulated by a large thermal finite element grid of the local structure. The employed numerical technique loosely couples the FE (Finite Element) solution with the gas dynamics solution of the faulted region. All free constants that appear in the governing equations are calibrated by hot fire sub-scale test. The calibrated model is used to make flight predictions using motor aft end environments and timelines. Model results indicate that CFR barrier systems provide a near 'vented joint' style of pressurization. Hypothetical fault conditions considered in this study (blow by, splice defect) are relatively benign in terms of overall heating to nozzle metal housing structures.

A novel perspective to calibrate temporal delays in cerebrovascular reactivity using hypercapnic and hyperoxic respiratory challenges.

PubMed

Champagne, Allen A; Bhogal, Alex A; Coverdale, Nicole S; Mark, Clarisse I; Cook, Douglas J

2017-12-05

Redistribution of blood flow across different brain regions, arising from the vasoactive nature of hypercapnia, can introduce errors when examining cerebrovascular reactivity (CVR) response delays. In this study, we propose a novel analysis method to characterize hemodynamic delays in the blood oxygen level dependent (BOLD) response to hypercapnia, and hyperoxia, as a way to provide insight into transient differences in vascular reactivity between cortical regions, and across tissue depths. A pseudo-continuous arterial spin labeling sequence was used to acquire BOLD and cerebral blood flow simultaneously in 19 healthy adults (12 F; 20 ± 2 years) during boxcar CO 2 and O 2 gas inhalation paradigms. Despite showing distinct differences in hypercapnia-induced response delay times (P < 0.05; Bonferroni corrected), grey matter regions showed homogenous hemodynamic latencies (P > 0.05) once calibrated for bolus arrival time derived using non-vasoactive hyperoxic gas challenges. Longer hypercapnic temporal delays were observed as the depth of the white matter tissue increased, although no significant differences in response lag were found during hyperoxia across tissue depth, or between grey and white matter. Furthermore, calibration of hypercapnic delays using hyperoxia revealed that deeper white matter layers may be more prone to dynamic redistribution of blood flow, which introduces response lag times ranging between 1 and 3 s in healthy subjects. These findings suggest that the combination of hypercapnic and hyperoxic gas-inhalation MRI can be used to distinguish between differences in CVR that arise as a result of delayed stimulus arrival time (due to the local architecture of the cerebrovasculature), or preferential blood flow distribution. Calibrated response delays to hypercapnia provide important insights into cerebrovascular physiology, and may be used to correct response delays associated with vascular impairment. Copyright © 2017. Published by Elsevier Inc.

Surface-acoustic-wave (SAW) flow sensor

NASA Astrophysics Data System (ADS)

Joshi, Shrinivas G.

1991-03-01

The use of a surface-acoustic-wave (SAW) device to measure the rate of gas flow is described. A SAW oscillator heated to a suitable temperature above ambient is placed in the path of a flowing gas. Convective cooling caused by the gas flow results in a change in the oscillator frequency. A 73-MHz oscillator fabricated on 128 deg rotated Y-cut lithium niobate substrate and heated to 55 C above ambient shows a frequency variation greater than 142 kHz for flow-rate variation from 0 to 1000 cu cm/min. The output of the sensor can be calibrated to provide a measurement of volume flow rate, pressure differential across channel ports, or mass flow rate. High sensitivity, wide dynamic range, and direct digital output are among the attractive features of this sensor. Theoretical expressions for the sensitivity and response time of the sensor are derived. It is shown that by using ultrasonic Lamb waves propagating in thin membranes, a flow sensor with faster response than a SAW sensor can be realized.

Surface-acoustic-wave (SAW) flow sensor.

PubMed

Joshi, S G

1991-01-01

The use of a surface-acoustic-wave (SAW) device to measure the rate of gas flow is described. A SAW oscillator heated to a suitable temperature above ambient is placed in the path of a flowing gas. Convective cooling caused by the gas flow results in a change in the oscillator frequency. A 73-MHz oscillator fabricated on 128 degrees rotated Y-cut lithium niobate substrate and heated to 55 degrees C above ambient shows a frequency variation greater than 142 kHz for flow-rate variation from 0 to 1000 cm(3)/min. The output of the sensor can be calibrated to provide a measurement of volume flow rate, pressure differential across channel ports, or mass flow rate. High sensitivity, wide dynamic range, and direct digital output are among the attractive features of this sensor. Theoretical expressions for the sensitivity and response time of the sensor are derived. It is shown that by using ultrasonic Lamb waves, propagating in thin membranes, a flow sensor with faster response than a SAW sensor can be realized.

High-pressure plastic scintillation detector for measuring radiogenic gases in flow systems

NASA Astrophysics Data System (ADS)

Schell, W. R.; Vives-Batlle, J.; Yoon, S. R.; Tobin, M. J.

1999-02-01

Radioactive gases are emitted into the atmosphere from nuclear electric power and nuclear fuel reprocessing plants, from hospitals discarding xenon used in diagnostic medicine, as well as from nuclear weapons tests. A high-pressure plastic scintillation detector was constructed to measure atmospheric levels of such radioactive gases by detecting the beta and internal conversion (IC) electron decays. Operational tests and calibrations were made that permit integration of the flow detectors into a portable Gas Analysis, Separation and Purification system (GASP). The equipment developed can be used for measuring fission gases released from nuclear reactor sources and/or as part of monitoring equipment for enforcing the Comprehensive Test Ban Treaty. The detector is being used routinely for in-line gas separation efficiency measurements, at the elevated operational pressures used for the high-pressure swing analysis system (2070 kPa) and at flow rates of 5-15 l/min [1, 2]. This paper presents the design features, operational methods, calibration, and detector applications.

Performance of different PEEP valves and helmet outlets at increasing gas flow rates: a bench top study.

PubMed

Isgrò, S; Zanella, A; Giani, M; Abd El Aziz El Sayed Deab, S; Pesenti, A; Patroniti, N

2012-10-01

Aim of the paper was to assess the performance of different expiratory valves and the resistance of helmet outlet ports at increasing gas flow rates. A gas flow-meter was connected to 10 different expiratory peep valves: 1 water-seal valve, 4 precalibrated fixed PEEP valves and 5 adjustable PEEP valves. Three new valves of each brand, set at different pressure levels (5-7.5-10-12.5-15 cmH(2)O, if available), were tested at increasing gas flow rates (from 30 to 150 L/min). We measured the pressure generated just before the valves. Three different helmets sealed on a mock head were connected at the inlet port with a gas flow-meter while the outlet was left clear. We measured the pressure generated inside the helmet (due to the flow-resistance of the outlet port) at increasing gas flow rates. Adjustable valves showed a variable degree flow-dependency (increasing difference between the measured and the expected pressure at increasing flow rates), while pre-calibrated valves revealed a flow-independent behavior. Water seal valve showed low degree flow-dependency. The pressures generated by the outlet port of the tested helmets ranged from 0.02 to 2.29 cmH(2)O at the highest gas flow rate. Adjustable PEEP valves are not suggested for continuous-flow CPAP systems as their flow-dependency can lead to pressures higher than expected. Precalibrated and water seal valves exhibit the best performance. Different helmet outlet ports do not significantly affect the pressure generated during helmet CPAP. In order to avoid iatrogenic complications gas flow and pressure delivered during helmet CPAP must always be monitored.

Direct Methanol Fuel Cell (DMFC) Battery Replacement Program

DTIC Science & Technology

2013-01-29

selection of the Reynold’s number enables use of water for simulation of gas or liquid flow. Introduction of dye to the flow stream, with video...calibrated using a soap -film flow meter (Bubble-o-meter, Dublin, OH). Eleven Array system temperature regions were set as follows prior to start of...expected. The ar- ray flow proceeds down the columns: column effects would be more likely than row effects from a design of experiments perspective

40 CFR 85.2233 - Steady state test equipment calibrations, adjustments, and quality control-EPA 91.

Code of Federal Regulations, 2013 CFR

2013-07-01

... tolerance range. The pressure in the sample cell must be the same with the calibration gas flowing during... this chapter. The check is done at 30 mph (48 kph), and a power absorption load setting to generate a... in § 85.2225(c)(1) are not met. (2) Leak checks. Each time the sample line integrity is broken, a...

40 CFR 85.2233 - Steady state test equipment calibrations, adjustments, and quality control-EPA 91.

Code of Federal Regulations, 2011 CFR

2011-07-01

... tolerance range. The pressure in the sample cell must be the same with the calibration gas flowing during... this chapter. The check is done at 30 mph (48 kph), and a power absorption load setting to generate a... in § 85.2225(c)(1) are not met. (2) Leak checks. Each time the sample line integrity is broken, a...

40 CFR 85.2233 - Steady state test equipment calibrations, adjustments, and quality control-EPA 91.

Code of Federal Regulations, 2012 CFR

2012-07-01

... tolerance range. The pressure in the sample cell must be the same with the calibration gas flowing during... this chapter. The check is done at 30 mph (48 kph), and a power absorption load setting to generate a... in § 85.2225(c)(1) are not met. (2) Leak checks. Each time the sample line integrity is broken, a...

Use of a turbine in a breath-by-breath computer-based respiratory measurement system.

PubMed

Venkateswaran, R S; Gallagher, R R

1997-01-01

The Computer-Based Respiratory Measurement System (CBRMS) is capable of analyzing individual breaths to monitor the kinetics of oxygen uptake, carbon dioxide production, tidal volumes, pulmonary ventilation, and other respiratory parameters during rest, exercise, and recovery. Respiratory gas volumes are measured by a calibrated turbine transducer while the respiratory gas concentrations are measured by a calibrated, fast-responding medical gas analyzer. To improve accuracy of the results, the inspiratory volumes and gas concentrations are measured and not assumed to be equal to expiratory volumes or ambient concentrations respectively. The respiratory gas volumes and concentration signals are digitized and stored in arrays. The gas volumes are converted to flow signals by software differentiation. These digitized data arrays are stored as files in a personal computer. Time alignment of the flow and gas concentration signals is performed at each breath for maximum accuracy in analysis. For system verification, data were obtained under resting conditions and under constant load exercises at 50 W, 100 W, and 150 W. These workloads were performed by a healthy, male subject on a bicycle ergometer. A strong correlation existed between the CBRMS steady-state results and the standard end-expirate bag collection technique. Thus, there is reason to believe that the CBRMS is capable of calculating respiratory transient responses accurately, a significant contribution to an understanding of total respiratory system function.

Development of a new dynamic gas flow-control system in the pressure range of 1 Pa-133 Pa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hong, S. S.; Chung, J. W.; Khan, Wakil

2011-12-15

A new flow-control system (FCS-705) has been developed at Korea Research Institute of Standards and Science. The system is intended for calibration of vacuum gauges in the pressure range of 1 Pa-133 Pa by comparison method. This paper describes some basic characteristics of the system including; (1) the design and construction of the system, (2) the generation of stable pressures in the chamber, (3) achieving high upstream pressure limit by installing a short duct in the by-pass pumping line, and (4) investigation of the gas flow regimes within the short duct.

Method and apparatus for measuring the gas permeability of a solid sample

DOEpatents

Carstens, D.H.W.

1984-01-27

The disclosure is directed to an apparatus and method for measuring the permeability of a gas in a sample. The gas is allowed to reach a steady flow rate through the sample. A measurable amount of the gas is collected during a given time period and then delivered to a sensitive quadrupole. The quadrupole signal, adjusted for background, is proportional to the amount of gas collected during the time period. The quadrupole can be calibrated with a standard helium leak. The gas can be deuterium and the sample can be polyvinyl alcohol.

Pressure-Drop Considerations in the Characterization of Dew-Point Transfer Standards at High Temperatures

NASA Astrophysics Data System (ADS)

Mitter, H.; Böse, N.; Benyon, R.; Vicente, T.

2012-09-01

During calibration of precision optical dew-point hygrometers (DPHs), it is usually necessary to take into account the pressure drop induced by the gas flow between the "point of reference" and the "point of use" (mirror or measuring head of the DPH) either as a correction of the reference dew-point temperature or as part of the uncertainty estimation. At dew-point temperatures in the range of ambient temperature and below, it is sufficient to determine the pressure drop for the required gas flow, and to keep the volumetric flow constant during the measurements. In this case, it is feasible to keep the dry-gas flow into the dew-point generator constant or to measure the flow downstream the DPH at ambient temperature. In normal operation, at least one DPH in addition to the monitoring DPH are used, and this operation has to be applied to each instrument. The situation is different at high dew-point temperatures up to 95 °C, the currently achievable upper limit reported in this paper. With increasing dew-point temperatures, the reference gas contains increasing amounts of water vapour and a constant dry-gas flow will lead to a significant enhanced volume flow at the conditions at the point of use, and therefore, to a significantly varying pressure drop depending on the applied dew-point temperature. At dew-point temperatures above ambient temperature, it is also necessary to heat the reference gas and the mirror head of the DPH sufficiently to avoid condensation which will additionally increase the volume flow and the pressure drop. In this paper, a method is provided to calculate the dry-gas flow rate needed to maintain a known wet-gas flow rate through a chilled mirror for a range of temperature and pressures.

Self-Calibrating, Variable-Flow Pumping System

NASA Technical Reports Server (NTRS)

Walls, Joe T.

1994-01-01

Pumping system provides accurate, controlled flows of two chemical liquids mixed in spray head and react to form rigid or flexible polyurethane or polyisocyanurate foam. Compatible with currently used polyurethane-based coating materials and gas-bubble-forming agents (called "blowing agents" in industry) and expected to be compatible with materials that used in near future. Handles environmentally acceptable substitutes for chlorofluorocarbon foaming agents.

Hydrogen recombiner catalyst test supporting data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Britton, M.D.

1995-01-19

This is a data package supporting the Hydrogen Recombiner Catalyst Performance and Carbon Monoxide Sorption Capacity Test Report, WHC-SD-WM-TRP-211, Rev 0. This report contains 10 appendices which consist of the following: Mass spectrometer analysis reports: HRC samples 93-001 through 93-157; Gas spectrometry analysis reports: HRC samples 93-141 through 93-658; Mass spectrometer procedure PNL-MA-299 ALO-284; Alternate analytical method for ammonia and water vapor; Sample log sheets; Job Safety analysis; Certificate of mixture analysis for feed gases; Flow controller calibration check; Westinghouse Standards Laboratory report on Bois flow calibrator; and Sorption capacity test data, tables, and graphs.

40 CFR 63.7732 - What test methods and other procedures must I use to demonstrate initial compliance with the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... hexane); n = Number of exhaust streams sampled; and Qi = Volumetric flow rate of effluent gas from... organic compounds (TOC), using hexane as the calibration gas. (2) Determine the average VOHAP, TGNMO, or... the concentration of TGNMO or TOC in ppmv as hexane as measured by Method 25 or 25A in 40 CFR part 60...

40 CFR 63.7732 - What test methods and other procedures must I use to demonstrate initial compliance with the...

Code of Federal Regulations, 2014 CFR

2014-07-01

... hexane); n = Number of exhaust streams sampled; and Qi = Volumetric flow rate of effluent gas from... organic compounds (TOC), using hexane as the calibration gas. (2) Determine the average VOHAP, TGNMO, or... the concentration of TGNMO or TOC in ppmv as hexane as measured by Method 25 or 25A in 40 CFR part 60...

40 CFR 63.7732 - What test methods and other procedures must I use to demonstrate initial compliance with the...

Code of Federal Regulations, 2013 CFR

2013-07-01

... hexane); n = Number of exhaust streams sampled; and Qi = Volumetric flow rate of effluent gas from... organic compounds (TOC), using hexane as the calibration gas. (2) Determine the average VOHAP, TGNMO, or... the concentration of TGNMO or TOC in ppmv as hexane as measured by Method 25 or 25A in 40 CFR part 60...

40 CFR 63.7732 - What test methods and other procedures must I use to demonstrate initial compliance with the...

Code of Federal Regulations, 2012 CFR

2012-07-01

... hexane); n = Number of exhaust streams sampled; and Qi = Volumetric flow rate of effluent gas from... organic compounds (TOC), using hexane as the calibration gas. (2) Determine the average VOHAP, TGNMO, or... the concentration of TGNMO or TOC in ppmv as hexane as measured by Method 25 or 25A in 40 CFR part 60...

[Calibration of a room air gas monitor with certified reference gases].

PubMed

Krueger, W A; Trick, M; Schroeder, T H; Unertl, K E

2003-12-01

Photo-acoustic infrared spectrometry is considered to be the gold standard for on-line measurement of anesthetic waste gas in room air. For maintenance of the precision of the measurements, the manufacturer recommends calibration of the gas monitor monitor every 3-12 months. We investigated whether the use of reference gases with analysis certificate could serve as a feasible alternative to commercial recalibration. We connected a multi-gas monitor type1302 (Bruel & Kjaer, Naerum, Denmark) to compressed air bottles containing reference gases with analysis certificate. Using a T-piece with a flow-meter, we avoided the entry of room air during the calibration phase. Highly purified nitrogen was used for zero calibration. The reference concentrations for desflurane, enflurane, halothane, isoflurane, and sevoflurane ranged from 41.6-51.1 ml/m(3) (ppm) in synthetic air. Since there is an overlap of the infrared absorption spectra of volatile anesthetics with alcohol used in operating rooms, we performed a cross-compensation with iso-propanol (107.0 ppm). A two-point calibration was performed for N(2)O (96.2 and 979.0 ppm), followed by cross-compensation with CO(2). Nafion tubes were used in order to avoid erroneous measurements due to molecular relaxation phenomena. The deviation of the measurement values ranged initially from 0-2.0% and increased to up to 4.9% after 18 months. For N(2)O, the corresponding values were 4.2% and 2.7%, respectively. Thus, our calibration procedure using certified reference gases yielded precise measurements with low deterioration over 18 months. It seems to be advantageous that the precision can be determined whenever deemed necessary. This allows for an individual decision, when the gas monitor needs to be calibrated again. The costs for reference gases and working time as well as logistic aspects such as storage and expiration dates must be individually balanced against the costs for commercial recalibration.

Field campaigns of the autonomous, closed-path, airborne TDLAS Hygrometer SEALDH-II and traceability to the German Primary Humidity Standards.

NASA Astrophysics Data System (ADS)

Buchholz, Bernhard; Ebert, Volker

2014-05-01

Airborne hygrometry is often demanded in scientific flight campaigns to provide datasets for environmental modeling or to correct for water vapor dilution or cross sensitivity effects in other gas analytical techniques. Water vapor measurements, however, are quite challenging due to the large dynamic range in the atmosphere (between 2 and 40000 ppmv) and the high spatio-temporal variability. Airborne hygrometers therefore need to combine a large measurement range with high temporal resolution to resolve - at typical airspeeds of 500 to 900 km/h - atmospheric gradients of several 1000 ppmv/s. Especially during the ascent into the upper troposphere, hygrometers need to work at high gas exchange rates to minimize water vapor adsorption effects. On the other hand, water vapor sensors are difficult to calibrate due to the strong water adsorption and the lack of bottled reference gas standards, which requires pre- or/and post-flight field calibrations. Recently in-flight calibration using an airborne H2O generator was demonstrated, which minimizes calibration drift but still imposes a lot of additional work and hardware to the experiments, since these kind of calibrations just transfer the accuracy level issues to the in-flight calibration-source. To make things worse, the low gas flow (1-5 std l/min, compared with up to 100 std l/min in flight for fast response instruments) adheres critical questions of wall absorption/desorption of the source and instrument even during the calibration process. The national metrological institutes (NMIs) maintain a global metrological water vapor scale which is defined via national primary humidity generators. These provide for calibration purposes well-defined, accurate water vapor samples of excellent comparability and stability traced back to the SI-units. The humidity calibration chain is maintained via high accuracy (but rather slow) Dew-Point-Mirror-Hygrometers as transfer standards. These provide a traceable performance and calibration link to any industrial or research laboratory hygrometer. To establish metrological traceability in field and particular in airborne hygrometers is however challenging and requires fast, field-compatible, metrologically qualified transfer hygrometry standards to link the metrological and the environmental sciences water scales. The SEALDH (Selective Extractive Airborne Laser Diode Hygrometer) development started 3 years ago and aims at filling this gap by using Tunable Diode Laser Absorption Spectroscopy (TDLAS) with a special, calibration-free data evaluation [1]. Previously developed, laboratory-based TDLAS instruments, such as [2] [3], were starting points to develop an autonomously operating, extractive water vapor sensor in a compact 19' 4 HU form factor. This new airborne package and far-reaching developments [4] in hard- and software allow an autonomous, low maintenance, airborne operation. SEALDH-II can be used in a calibration-free field sensor mode (with an absolute, metrologically defined uncertainty of 4.3% +- 3ppmv). The response time is mainly limited by the gas flow and significantly below 1 sec with a precision down to 0.08 ppmv (1σ, 1sec) measured at 600 ppmv and 1000 hPa. The excellent long-term stability of SEALDH-II (

A Precise Calibration Technique for Measuring High Gas Temperatures

NASA Technical Reports Server (NTRS)

Gokoglu, Suleyman A.; Schultz, Donald F.

2000-01-01

A technique was developed for direct measurement of gas temperatures in the range of 2050 K 2700 K with improved accuracy and reproducibility. The technique utilized the low-emittance of certain fibrous materials, and the uncertainty of the technique was United by the uncertainty in the melting points of the materials, i.e., +/-15 K. The materials were pure, thin, metal-oxide fibers whose diameters varied from 60 microns to 400 microns in the experiments. The sharp increase in the emittance of the fibers upon melting was utilized as indication of reaching a known gas temperature. The accuracy of the technique was confirmed by both calculated low emittance values of transparent fibers, of order 0.01, up to a few degrees below their melting point and by the fiber-diameter independence of the results. This melting-point temperature was approached by increments not larger than 4 K, which was accomplished by controlled increases of reactant flow rates in hydrogen-air and/or hydrogen-oxygen flames. As examples of the applications of the technique, the gas-temperature measurements were used: (a) for assessing the uncertainty in inferring gas temperatures from thermocouple measurements, and (b) for calibrating an IR camera to measure gas temperatures. The technique offers an excellent calibration reference for other gas-temperature measurement methods to improve their accuracy and reliably extending their temperature range of applicability.

A Precise Calibration Technique for Measuring High Gas Temperatures

NASA Technical Reports Server (NTRS)

Gokoglu, Suleyman A.; Schultz, Donald F.

1999-01-01

A technique was developed for direct measurement of gas temperatures in the range of 2050 K - 2700 K with improved accuracy and reproducibility. The technique utilized the low-emittance of certain fibrous Materials, and the uncertainty of the technique was limited by the uncertainty in the melting points of the materials, i.e., +/- 15 K. The materials were pure, thin, metal-oxide fibers whose diameters varied from 60 mm to 400 mm in the experiments. The sharp increase in the emittance of the fibers upon melting was utilized as indication of reaching a known gas temperature. The accuracy of the technique was confirmed by both calculated low emittance values of transparent fibers, of order 0.01, up to a few degrees below their melting point and by the fiber-diameter independence of the results. This melting-point temperature was approached by increments not larger than 4 K, which was accomplished by controlled increases of reactant flow rates in hydrogen-air and/or hydrogen- oxygen flames. As examples of the applications of the technique, the gas-temperature measurements were used (a) for assessing the uncertainty in infering gas temperatures from thermocouple measurements, and (b) for calibrating an IR camera to measure gas temperatures. The technique offers an excellent calibration reference for other gas-temperature measurement methods to improve their accuracy and reliably extending their temperature range of applicability.

Thermo-Mechanical Characterization of Silicon Carbide-Silicon Carbide Composites at Elevated Temperatures Using a Unique Combustion Facility

DTIC Science & Technology

2009-09-10

Calibration Tool(s) Surface Temperature ~1250oC Furnace, R-type TC & IR Gas Temperature < 1800oC R-type TC Gas Velocity ~ Mach 0.5 XS -4 High Speed...Camera Equivalence Ratio ~ 0.9 HVOFTM Flow Controller Gas Composition H 2 O, O 2 ,CO 2 , CO, NOx Testo XL 350 Gas Analyzer Mechanical Loading Fatigue...unavailability, however, gas velocity was measured using the X-StreamTM XS -4 High Speed Camera. The range of our interest was the velocity in the upstream of a

Modelling and optimization of a wellhead gas flowmeter using concentric pipes

NASA Astrophysics Data System (ADS)

Nec, Yana; Huculak, Greg

2017-09-01

A novel configuration of a landfill wellhead was analysed to measure the flow rate of gas extracted from sanitary landfills. The device provides access points for pressure measurement integral to flow rate computation similarly to orifice and Venturi meters, and has the advantage of eliminating the problem of water condensation often impairing the accuracy thereof. It is proved that the proposed configuration entails comparable computational complexity and negligible sensitivity to geometric parameters. Calibration for the new device was attained using a custom optimization procedure, operating on a quadri-dimensional parameter surface evincing discontinuity and non-smoothness.

Feasibility Assessment of CO2 Sequestration and Enhanced Recovery in Gas Shale Reservoirs

NASA Astrophysics Data System (ADS)

Vermylen, J. P.; Hagin, P. N.; Zoback, M. D.

2008-12-01

CO2 sequestration and enhanced methane recovery may be feasible in unconventional, organic-rich, gas shale reservoirs in which the methane is stored as an adsorbed phase. Previous studies have shown that organic-rich, Appalachian Devonian shales adsorb approximately five times more carbon dioxide than methane at reservoir conditions. However, the enhanced recovery and sequestration concept has not yet been tested for gas shale reservoirs under realistic flow and production conditions. Using the lessons learned from previous studies on enhanced coalbed methane (ECBM) as a starting point, we are conducting laboratory experiments, reservoir modeling, and fluid flow simulations to test the feasibility of sequestration and enhanced recovery in gas shales. Our laboratory work investigates both adsorption and mechanical properties of shale samples to use as inputs for fluid flow simulation. Static and dynamic mechanical properties of shale samples are measured using a triaxial press under realistic reservoir conditions with varying gas saturations and compositions. Adsorption is simultaneously measured using standard, static, volumetric techniques. Permeability is measured using pulse decay methods calibrated to standard Darcy flow measurements. Fluid flow simulations are conducted using the reservoir simulator GEM that has successfully modeled enhanced recovery in coal. The results of the flow simulation are combined with the laboratory results to determine if enhanced recovery and CO2 sequestration is feasible in gas shale reservoirs.

Optical characterization of clouds of fine liquid-nitrogen particles

NASA Technical Reports Server (NTRS)

Ingebo, Robert D.

1990-01-01

Characteristic drop size, D sub 32, of clouds of fine liquid nitrogen particles was measured with a scattered light scanning instrument developed at NASA-Lewis. Calibration of the instrument was accomplished with suspensions of monosized polystyrene spheres and the scattered light scanner was then used to investigate the mechanism of liquid nitrogen jet disintegration in high velocity gas flow. The Sauter mean diameter, D sub 32, was found to vary inversely with nitrogen gas mass-flux raised to the 1.33 power. Values of D sub 32 varied from 5 to 25 microns and the mass-flux exponent 1.33 agrees well with theory for liquid jet breakup in high velocity gas flow. Loss of fine particles due to the high vaporization rate of liquid nitrogen was avoided by sampling the spray 1.3 cm downstream of the nozzle orifice. The presence of high velocity and thermal gradients in the gas phase also made sampling of the particles quite difficult. As a result, it was necessary to correct the measurements for background noise produced by both highly turbulent gas flow and thermally induced density gradients in the gas phase.

An integrated exhaust gas analysis system with self-contained data processing and automatic calibration

NASA Technical Reports Server (NTRS)

Anderson, R. C.; Summers, R. L.

1981-01-01

An integrated gas analysis system designed to operate in automatic, semiautomatic, and manual modes from a remote control panel is described. The system measures the carbon monoxide, oxygen, water vapor, total hydrocarbons, carbon dioxide, and oxides of nitrogen. A pull through design provides increased reliability and eliminates the need for manual flow rate adjustment and pressure correction. The system contains two microprocessors to range the analyzers, calibrate the system, process the raw data to units of concentration, and provides information to the facility research computer and to the operator through terminal and the control panels. After initial setup, the system operates for several hours without significant operator attention.

Turbulence modeling in simulation of gas-turbine flow and heat transfer.

PubMed

Brereton, G; Shih, T I

2001-05-01

The popular k-epsilon type two-equation turbulence models, which are calibrated by experimental data from simple shear flows, are analyzed for their ability to predict flows involving shear and an extra strain--flow with shear and rotation and flow with shear and streamline curvature. The analysis is based on comparisons between model predictions and those from measurements and large-eddy simulations of homogenous flows involving shear and an extra strain, either from rotation or from streamline curvature. Parameters are identified, which show the conditions under which performance of k-epsilon type models can be expected to be poor.

Piston manometer as an absolute standard for vacuum-gage calibration in the range 2 to 500 millitorr

NASA Technical Reports Server (NTRS)

Warshawsky, I.

1972-01-01

A thin disk is suspended, with very small annular clearance, in a cylindrical opening in the base plate of a calibration chamber. A continuous flow of calibration gas passes through the chamber and annular opening to a downstream high vacuum pump. The ratio of pressures on the two faces of the disk is very large, so that the upstream pressure is substantially equal to net force on the disk divided by disk area. This force is measured with a dynamometer that is calibrated in place with dead weights. A probable error of + or - (0.2 millitorr plus 0.2 percent) is attainable when downstream pressure is known to 10 percent.

A Rotary Flow Channel for Shear Stress Sensor Calibration

NASA Technical Reports Server (NTRS)

Zuckerwar, Allan J.; Scott, Michael A.

2004-01-01

A proposed shear sensor calibrator consists of a rotating wheel with the sensor mounted tangential to the rim and positioned in close proximity to the rim. The shear stress generated by the flow at the sensor position is simply tau(sub omega) = (mu)r(omega)/h, where mu is the viscosity of the ambient gas, r the wheel radius, omega the angular velocity of the wheel, and h the width of the gap between the wheel rim and the sensor. With numerical values of mu = 31 (mu)Pa s (neon at room temperature), r = 0.5 m, omega = 754 /s (7200 rpm), and h = 50.8 m, a shear stress of tau(sub omega) = 231 Pa can be generated. An analysis based on one-dimensional flow, with the flow velocity having only an angular component as a function of the axial and radial coordinates, yields corrections to the above simple formula for the curvature of the wheel, flatness of the sensor, and finite width of the wheel. It is assumed that the sensor mount contains a trough (sidewalls) to render a velocity release boundary condition at the edges of the rim. The Taylor number under maximum flow conditions is found to be 62.3, sufficiently low to obviate flow instability. The fact that the parameters entering into the evaluation of the shear stress can be measured to high accuracy with well-defined uncertainties makes the proposed calibrator suitable for a physical standard for shear stress calibration.

CFD Based Prediction of Discharge Coefficient of Sonic Nozzle with Surface Roughness

NASA Astrophysics Data System (ADS)

Bagaskara, Agastya; Agoes Moelyadi, Mochammad

2018-04-01

Due to its simplicity and accuracy, sonic nozzle is widely used in gas flow measurement, gas flow meter calibration standard, and flow control. The nozzle obtains mass flow rate by measuring temperature and pressure in the inlet during choked flow condition and calculate the flow rate using the one-dimensional isentropic flow equation multiplied by a discharge coefficient, which takes into account multiple non-isentropic effects, which causes the reduction in mass flow. Proper determination of discharge coefficient is crucial to ensure the accuracy of mass flow measurement by the nozzle. Available analytical solution for the prediction of discharge coefficient assumes that the nozzle wall is hydraulically smooth which causes disagreement with experimental results. In this paper, the discharge coefficient of sonic nozzle is determined using computational fluid dynamics method by taking into account the roughness of the wall. It is found that the result shows better agreement with the experiment data compared to the analytical result.

Investigation on Dynamic Calibration for an Optical-Fiber Solids Concentration Probe in Gas-Solid Two-Phase Flows

PubMed Central

Xu, Guiling; Liang, Cai; Chen, Xiaoping; Liu, Daoyin; Xu, Pan; Shen, Liu; Zhao, Changsui

2013-01-01

This paper presents a review and analysis of the research that has been carried out on dynamic calibration for optical-fiber solids concentration probes. An introduction to the optical-fiber solids concentration probe was given. Different calibration methods of optical-fiber solids concentration probes reported in the literature were reviewed. In addition, a reflection-type optical-fiber solids concentration probe was uniquely calibrated at nearly full range of the solids concentration from 0 to packed bed concentration. The effects of particle properties (particle size, sphericity and color) on the calibration results were comprehensively investigated. The results show that the output voltage has a tendency to increase with the decreasing particle size, and the effect of particle color on calibration result is more predominant than that of sphericity. PMID:23867745

Development and analysis of closed cycle circulator elements. Final report 31 Jul 978-31 May 1980

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shih, C.C.; Karr, G.R.; Perkins, J.F.

1980-05-01

A series of experiments with various flow rates of laser gas and coolants under several levels of energy inputs has been conducted on the Army Closed Cycle Circulator for pulsed EDL to collect sufficient data for flow calibration and coefficient determination. Verification of the theoretical models depicting the functions of the heat exchangers in maintaining the thermal balance in the flow through the steady and transient states are made through comparison with results of the experimental analysis.

Effect of gas mass flux on cryogenic liquid jet breakup

NASA Technical Reports Server (NTRS)

Ingebo, R. D.

1992-01-01

A scattered-light scanning instrument developed at NASA Lewis Research Center was used to measure the characteristic drop size of clouds of liquid nitrogen droplets. The instrument was calibrated with suspensions of monosized polystyrene spheres. In this investigation of the mechanism of liquid nitrogen jet disintegration in a high-velocity gas flow, the Sauter mean diameter, D32, was found to vary inversely with the nitrogen gas mass flux raised to the power 1.33. Values of D32 varied from 5 to 25 microns and the mass flux exponent of 1.33 agrees well with theory for liquid jet breakup in high-velocity gas flows. The loss of very small droplets due to the high vaporization rate of liquid nitrogen was avoided by sampling the spray very close to the atomizer, i.e., 1.3 cm downstream of the nozzle orifice. The presence of high velocity and thermal gradients in the gas phase also made sampling of the particles difficult. As a result, it was necessary to correct the measurements for background noise produced by both highly turbulent gas flows and thermally induced density gradients in the gas phase.

The ejector flowmeter: an evaluation of its accuracy.

PubMed

Waaben, J; Thomsen, A

1978-01-01

The accuracy of five ejector flowmeters was assessed using three different gases and four flow-rates. A soap-bubble flowmeter was used for the calibaration. Significant variations were found between individual flowmeters and between different gas mixtures. No variation was found between the four different flowrates, indicating that the calibration is linear. The mean calibration factor was 84.8% +/- 4.1 (100% O2:87.4 +/- 3.4, 50% N2O/O2: 84.2 +/- 2.8, and 100% N2O: 83.0 +/- 4.6).

Gasification in pulverized coal flames. Second annual progress report, July 1976--August 1977. [Pulverized coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

George, P. E.; Lenzer, R. C.; Thomas, J. F.

1977-08-01

This project concerns the production of power and synthesis gases from pulverized coal via suspension gasification. Swirling flow in both concentric jet and cyclone gasifiers will separate oxidation and reduction zones. Gasifier performance will be correlated with internally measured temperature and concentration profiles. The test cell flow system and electrical system, which includes a safety interlock design, has been installed. Calibration of the UTI-30C mass spectrometer and construction of the gas sampling system are complete. Both the coal feeder, which has been calibrated, and the boiler are ready for integration into the test cell flow system. Construction and testing ofmore » the cyclone reactor, including methane combustion experiments, is complete. The confined jet reactor has been designed and construction is underway. Investigation of combustion and gasification modeling techniques has begun.« less

Piston manometer as an absolute standard for vacuum gage calibration in the range 10 to 700 microtorr

NASA Technical Reports Server (NTRS)

Warshawsky, I.

1972-01-01

Total pressure in a calibration chamber is determined by measuring the force on a disk suspended in an orifice in the baseplate of the chamber. The disk forms a narrow annular gap with the orifice. A continuous flow of calibration gas passes through the chamber and annulus to a downstream pumping system. The ratio of pressures on the two faces of the disk exceeds 100:1, so that chamber pressure is substantially equal to the product of disk area and net force on the disk. This force is measured with an electrodynamometer that can be calibrated in situ with dead weights. Probable error in pressure measurement is plus or minus (0.5 microtorr + 0.6 percent).

Single Particle Studies of Heterogeneous Atmospheric Chemistry on Aluminum Oxide Particles in a Quadrupole Trap

DTIC Science & Technology

2000-03-01

For Figures 17 and 18, the H20 content of the N2 gas flow is ណ ppm ( dew point < 220 K); for Figure 19, the HC1 content of the gas stream is 30 ppm...the same temperature to prevent supersaturation. We have calibrated the water delivery system in H2S04 trapping experiments, 35 by a dew point ...We have investigated the activities of different types of aluminum oxide particles for uptake of gas -phase H20 and HCI. The particle types

Experimental investigation of nozzle/plume aerodynamics at hypersonic speeds

NASA Technical Reports Server (NTRS)

Bogdanoff, David W.; Cambier, Jean-Luc; Papadopoulos, Perikles

1994-01-01

Much of the work involved the Ames 16-Inch Shock Tunnel facility. The facility was reactivated and upgraded, a data acquisition system was configured and upgraded several times, several facility calibrations were performed and test entries with a wedge model with hydrogen injection and a full scramjet combustor model, with hydrogen injection, were performed. Extensive CFD modeling of the flow in the facility was done. This includes modeling of the unsteady flow in the driver and driven tubes and steady flow modeling of the nozzle flow. Other modeling efforts include simulations of non-equilibrium flows and turbulence, plasmas, light gas guns and the use of non-ideal gas equations of state. New experimental techniques to improve the performance of gas guns, shock tubes and tunnels and scramjet combustors were conceived and studied computationally. Ways to improve scramjet engine performance using steady and pulsed detonation waves were also studied computationally. A number of studies were performed on the operation of the ram accelerator, including investigations of in-tube gasdynamic heating and the use of high explosives to raise the velocity capability of the device.

Single-shot gas-phase thermometry by time-to-frequency mapping of coherence dephasing.

PubMed

Yue, Orin; Bremer, Marshall T; Pestov, Dmitry; Gord, James R; Roy, Sukesh; Dantus, Marcos

2012-08-09

We demonstrate a single-beam coherent anti-Stokes Raman scattering (CARS) technique for gas-phase thermometry that assesses the species-specific local gas temperature by single-shot time-to-frequency mapping of Raman-coherence dephasing. The proof-of-principle experiments are performed with air in a temperature-controlled gas cell. Impulsive excitation of molecular vibrations by an ultrashort pump/Stokes pulse is followed by multipulse probing of the 2330 cm(-1) Raman transition of N(2). This sequence of colored probe pulses, delayed in time with respect to each other and corresponding to three isolated spectral bands, imprints the coherence dephasing onto the measured CARS spectrum. For calibration purposes, the dephasing rates are recorded at various gas temperatures, and the relationship is fitted to a linear regression. The calibration data are then used to determine the gas temperature and are shown to provide better than 15 K accuracy. The described approach is insensitive to pulse energy fluctuations and can, in principle, gauge the temperature of multiple chemical species in a single laser shot, which is deemed particularly valuable for temperature profiling of reacting flows in gas-turbine combustors.

Relative Humidity in Limited Streamer Tubes for Stanford Linear Accelerator Center's BaBar Detector

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lang, M.I.; /MIT; Convery, M.

2005-12-15

The BABAR Detector at the Stanford Linear Accelerator Center studies the decay of B mesons created in e{sup +}e{sup -} collisions. The outermost layer of the detector, used to detect muons and neutral hadrons created during this process, is being upgraded from Resistive Plate Chambers (RPCs) to Limited Streamer Tubes (LSTs). The standard-size LST tube consists of eight cells, where a silver-plated wire runs down the center of each. A large potential difference is placed between the wires and ground. Gas flows through a series of modules connected with tubing, typically four. LSTs must be carefully tested before installation, asmore » it will be extremely difficult to repair any damage once installed in the detector. In the testing process, the count rate in most modules showed was stable and consistent with cosmic ray rate over an approximately 500 V operating range between 5400 to 5900 V. The count in some modules, however, was shown to unexpectedly spike near the operation point. In general, the modules through which the gas first flows did not show this problem, but those further along the gas chain were much more likely to do so. The suggestion was that this spike was due to higher humidity in the modules furthest from the fresh, dry inflowing gas, and that the water molecules in more humid modules were adversely affecting the modules' performance. This project studied the effect of humidity in the modules, using a small capacitive humidity sensor (Honeywell). The sensor provided a humidity-dependent output voltage, as well as a temperature measurement from a thermistor. A full-size hygrometer (Panametrics) was used for testing and calibrating the Honeywell sensors. First the relative humidity of the air was measured. For the full calibration, a special gas-mixing setup was used, where relative humidity of the LST gas mixture could be varied from almost dry to almost fully saturated. With the sensor calibrated, a set of sensors was used to measure humidity vs. time in the LSTs. The sensors were placed in two sets of LST modules, one gas line flowing through each set. These modules were tested for count rate v. voltage while simultaneously measuring relative humidity in each module. One set produced expected readings, while the other showed the spike in count rate. The relative humidity in the two sets of modules looked very similar, but it rose significantly for modules further along the gas chain.« less

40 CFR 86.121-90 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2010 CFR

2010-07-01

... sample bag with a known volume of zero grade air measured by a gas flow meter meeting the performance....121-90 Section 86.121-90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... operating adjustment using the appropriate FID fuel and zero-grade air. (2) Optimize on the most common...

40 CFR 86.121-90 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2011 CFR

2011-07-01

... sample bag with a known volume of zero grade air measured by a gas flow meter meeting the performance....121-90 Section 86.121-90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... operating adjustment using the appropriate FID fuel and zero-grade air. (2) Optimize on the most common...

Simultaneous imaging of fuel vapor mass fraction and gas-phase temperature inside gasoline sprays using two-line excitation tracer planar laser-induced fluorescence.

PubMed

Zigan, Lars; Trost, Johannes; Leipertz, Alfred

2016-02-20

This paper reports for the first time, to the best of our knowledge, on the simultaneous imaging of the gas-phase temperature and fuel vapor mass fraction distribution in a direct-injection spark-ignition (DISI) spray under engine-relevant conditions using tracer planar laser-induced fluorescence (TPLIF). For measurements in the spray, the fluorescence tracer 3-pentanone is added to the nonfluorescent surrogate fuel iso-octane, which is excited quasi-simultaneously by two different excimer lasers for two-line excitation LIF. The gas-phase temperature of the mixture of fuel vapor and surrounding gas and the fuel vapor mass fraction can be calculated from the two LIF signals. The measurements are conducted in a high-temperature, high-pressure injection chamber. The fluorescence calibration of the tracer was executed in a flow cell and extended significantly compared to the existing database. A detailed error analysis for both calibration and measurement is provided. Simultaneous single-shot gas-phase temperature and fuel vapor mass fraction fields are processed for the assessment of cyclic spray fluctuations.

Characterization and calibration of gas sensor systems at ppb level—a versatile test gas generation system

NASA Astrophysics Data System (ADS)

Leidinger, Martin; Schultealbert, Caroline; Neu, Julian; Schütze, Andreas; Sauerwald, Tilman

2018-01-01

This article presents a test gas generation system designed to generate ppb level gas concentrations from gas cylinders. The focus is on permanent gases and volatile organic compounds (VOCs) for applications like indoor and outdoor air quality monitoring or breath analysis. In the design and the setup of the system, several issues regarding handling of trace gas concentrations have been considered, addressed and tested. This concerns not only the active fluidic components (flow controllers, valves), which have been chosen specifically for the task, but also the design of the fluidic tubing regarding dead volumes and delay times, which have been simulated for the chosen setup. Different tubing materials have been tested for their adsorption/desorption characteristics regarding naphthalene, a highly relevant gas for indoor air quality monitoring, which has generated high gas exchange times in a previous gas mixing system due to long time adsorption/desorption effects. Residual gas contaminations of the system and the selected carrier air supply have been detected and quantified using both an analytical method (GC-MS analysis according to ISO 16000-6) and a metal oxide semiconductor gas sensor, which detected a maximum contamination equivalent to 28 ppb of carbon monoxide. A measurement strategy for suppressing even this contamination has been devised, which allows the system to be used for gas sensor and gas sensor system characterization and calibration in the low ppb concentration range.

Chemical Discrimination in Turbulent Gas Mixtures with MOX Sensors Validated by Gas Chromatography-Mass Spectrometry

PubMed Central

Fonollosa, Jordi; Rodríguez-Luján, Irene; Trincavelli, Marco; Vergara, Alexander; Huerta, Ramón

2014-01-01

Chemical detection systems based on chemo-resistive sensors usually include a gas chamber to control the sample air flow and to minimize turbulence. However, such a kind of experimental setup does not reproduce the gas concentration fluctuations observed in natural environments and destroys the spatio-temporal information contained in gas plumes. Aiming at reproducing more realistic environments, we utilize a wind tunnel with two independent gas sources that get naturally mixed along a turbulent flow. For the first time, chemo-resistive gas sensors are exposed to dynamic gas mixtures generated with several concentration levels at the sources. Moreover, the ground truth of gas concentrations at the sensor location was estimated by means of gas chromatography-mass spectrometry. We used a support vector machine as a tool to show that chemo-resistive transduction can be utilized to reliably identify chemical components in dynamic turbulent mixtures, as long as sufficient gas concentration coverage is used. We show that in open sampling systems, training the classifiers only on high concentrations of gases produces less effective classification and that it is important to calibrate the classification method with data at low gas concentrations to achieve optimal performance. PMID:25325339

Chemical discrimination in turbulent gas mixtures with MOX sensors validated by gas chromatography-mass spectrometry.

PubMed

Fonollosa, Jordi; Rodríguez-Luján, Irene; Trincavelli, Marco; Vergara, Alexander; Huerta, Ramón

2014-10-16

Chemical detection systems based on chemo-resistive sensors usually include a gas chamber to control the sample air flow and to minimize turbulence. However, such a kind of experimental setup does not reproduce the gas concentration fluctuations observed in natural environments and destroys the spatio-temporal information contained in gas plumes. Aiming at reproducing more realistic environments, we utilize a wind tunnel with two independent gas sources that get naturally mixed along a turbulent flow. For the first time, chemo-resistive gas sensors are exposed to dynamic gas mixtures generated with several concentration levels at the sources. Moreover, the ground truth of gas concentrations at the sensor location was estimated by means of gas chromatography-mass spectrometry. We used a support vector machine as a tool to show that chemo-resistive transduction can be utilized to reliably identify chemical components in dynamic turbulent mixtures, as long as sufficient gas concentration coverage is used. We show that in open sampling systems, training the classifiers only on high concentrations of gases produces less effective classification and that it is important to calibrate the classification method with data at low gas concentrations to achieve optimal performance.

Design of artificial neural networks using a genetic algorithm to predict collection efficiency in venturi scrubbers.

PubMed

Taheri, Mahboobeh; Mohebbi, Ali

2008-08-30

In this study, a new approach for the auto-design of neural networks, based on a genetic algorithm (GA), has been used to predict collection efficiency in venturi scrubbers. The experimental input data, including particle diameter, throat gas velocity, liquid to gas flow rate ratio, throat hydraulic diameter, pressure drop across the venturi scrubber and collection efficiency as an output, have been used to create a GA-artificial neural network (ANN) model. The testing results from the model are in good agreement with the experimental data. Comparison of the results of the GA optimized ANN model with the results from the trial-and-error calibrated ANN model indicates that the GA-ANN model is more efficient. Finally, the effects of operating parameters such as liquid to gas flow rate ratio, throat gas velocity, and particle diameter on collection efficiency were determined.

Design and test of porous-tungsten mercury vaporizers

NASA Technical Reports Server (NTRS)

Kerslake, W. R.

1972-01-01

Future use of large size Kaufman thrusters and thruster arrays will impose new design requirements for porous plug type vaporizers. Larger flow rate coupled with smaller pores to prevent liquid intrusion will be desired. The results of testing samples of porous tungsten for flow rate, liquid intrusion pressure level, and mechanical strength are presented. Nitrogen gas was used in addition to mercury flow for approximate calibration. Liquid intrusion pressure levels will require that flight thruster systems with long feed lines have some way (a valve) to restrict dynamic line pressures during launch.

Computational Analysis of the Transonic Dynamics Tunnel Using FUN3D

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chwalowski, Pawel; Quon, Eliot; Brynildsen, Scott E.

This paper presents results from an explanatory two-year effort of applying Computational Fluid Dynamics (CFD) to analyze the empty-tunnel flow in the NASA Langley Research Center Transonic Dynamics Tunnel (TDT). The TDT is a continuous-flow, closed circuit, 16- x 16-foot slotted-test-section wind tunnel, with capabilities to use air or heavy gas as a working fluid. In this study, experimental data acquired in the empty tunnel using the R-134a test medium was used to calibrate the computational data. The experimental calibration data includes wall pressures, boundary-layer profiles, and the tunnel centerline Mach number profiles. Subsonic and supersonic flow regimes were considered,more » focusing on Mach 0.5, 0.7 and Mach 1.1 in the TDT test section. This study discusses the computational domain, boundary conditions, and initial conditions selected in the resulting steady-state analyses using NASA's FUN3D CFD software.« less

Computational Analysis of the Transonic Dynamics Tunnel Using FUN3D

NASA Technical Reports Server (NTRS)

Chwalowski, Pawel; Quon, Eliot; Brynildsen, Scott E.

2016-01-01

This paper presents results from an exploratory two-year effort of applying Computational Fluid Dynamics (CFD) to analyze the empty-tunnel flow in the NASA Langley Research Center Transonic Dynamics Tunnel (TDT). The TDT is a continuous-flow, closed circuit, 16- x 16-foot slotted-test-section wind tunnel, with capabilities to use air or heavy gas as a working fluid. In this study, experimental data acquired in the empty tunnel using the R-134a test medium was used to calibrate the computational data. The experimental calibration data includes wall pressures, boundary-layer profiles, and the tunnel centerline Mach number profiles. Subsonic and supersonic flow regimes were considered, focusing on Mach 0.5, 0.7 and Mach 1.1 in the TDT test section. This study discusses the computational domain, boundary conditions, and initial conditions selected and the resulting steady-state analyses using NASA's FUN3D CFD software.

Shock shapes on blunt bodies in hypersonic-hypervelocity helium, air, and CO2 flows, and calibration results in Langley 6-inch expansion tube

NASA Technical Reports Server (NTRS)

Miller, C. G., III

1975-01-01

Shock shape results for flat-faced cylinders, spheres, and spherically blunted cones in various test gases, along with preliminary results from a calibration study performed in the Langley 6-inch expansion tube are presented. Free-stream velocities from 5 to 7 km/sec are generated at hypersonic conditions with helium, air, and CO2, resulting in normal shock density ratios from 4 to 19. Ideal-gas shock shape predictions, in which an effective ratio of specific heats is used as input, are compared with the measured results. The effect of model diameter is examined to provide insight to the thermochemical state of the flow in the shock layer. The regime for which equilibrium exists in the shock layer for the present air and CO2 test conditions is defined. Test core flow quality, test repeatability, and comparison of measured and predicted expansion-tube flow quantities are discussed.

Development of a New Fundamental Measuring Technique for the Accurate Measurement of Gas Flowrates by Means of Laser Doppler Anemometry

NASA Astrophysics Data System (ADS)

Dopheide, D.; Taux, G.; Krey, E.-A.

1990-01-01

In the Physikalisch-Technische Bundesanstalt (PTB), a research test facility for the accurate measurement of gas (volume and mass) flowrates has been set up in the last few years on the basis of a laser Doppler anemometer (LDA) with a view to directly measuring gas flowrates with a relative uncertainty of only 0,1%. To achieve this, it was necessary to develop laser Doppler anemometry into a precision measuring technique and to carry out detailed investigations on stationary low-turbulence nozzle flow. The process-computer controlled test facility covers the flowrate range from 100 to 4000 m3/h (~0,03 - 1,0 m3/s), any flowrate being measured directly, immediately and without staggered arrangement of several flow meters. After the development was completed, several turbine-type gas meters were calibrated and international comparisons carried out. The article surveys the most significant aspects of the work and provides an outlook on future developments with regard to the miniaturization of optical flow and flowrate sensors for industrial applications.

Thin film temperature sensor

NASA Technical Reports Server (NTRS)

Grant, H. P.; Przybyszewski, J. S.

1980-01-01

Thin film surface temperature sensors were developed. The sensors were made of platinum-platinum/10 percent rhodium thermocouples with associated thin film-to-lead wire connections and sputtered on aluminum oxide coated simulated turbine blades for testing. Tests included exposure to vibration, low velocity hydrocarbon hot gas flow to 1250 K, and furnace calibrations. Thermal electromotive force was typically two percent below standard type S thermocouples. Mean time to failure was 42 hours at a hot gas flow temperature of 1250 K and an average of 15 cycles to room temperature. Failures were mainly due to separation of the platinum thin film from the aluminum oxide surface. Several techniques to improve the adhesion of the platinum are discussed.

Controlling the emission profile of an H2 discharge lamp to simulate interstellar radiation fields

NASA Astrophysics Data System (ADS)

Ligterink, N. F. W.; Paardekooper, D. M.; Chuang, K.-J.; Both, M. L.; Cruz-Diaz, G. A.; van Helden, J. H.; Linnartz, H.

2015-12-01

Context. Microwave discharge hydrogen-flow lamps have been used for more than half a century to simulate interstellar ultraviolet radiation fields in the laboratory. Recent discrepancies between identical measurements in different laboratories, as well as clear wavelength dependent results obtained in monochromatic (synchrotron) experiments, hint at a more elaborate dependence on the exact discharge settings than assumed so far. Aims: We have investigated systematically two lamp geometries in full dependence of a large number of different running conditions and the spectral emission patterns are characterized for the first time with fully calibrated absolute flux numbers. Methods: A sophisticated plasma lamp calibration set-up has been used to record the vacuum-ultraviolet emission spectra with a spectral resolution of 0.5 nm and bandwidth of 1.6 nm in the 116-220 nm region. Spectra are compared with the output of a calibrated D2-lamp which allows a derivation of absolute radiance values. Results: The general findings of over 200 individual measurements are presented, illustrating how the lamp emission pattern depends on i) microwave power; ii) gas and gas mixing ratios; iii) discharge lamp geometry; iv) cavity positioning; and v) gas pressure.

A high sensitivity fiber optic macro-bend based gas flow rate transducer for low flow rates: Theory, working principle, and static calibration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schena, Emiliano; Saccomandi, Paola; Silvestri, Sergio

2013-02-15

A novel fiber optic macro-bend based gas flowmeter for low flow rates is presented. Theoretical analysis of the sensor working principle, design, and static calibration were performed. The measuring system consists of: an optical fiber, a light emitting diode (LED), a Quadrant position sensitive Detector (QD), and an analog electronic circuit for signal processing. The fiber tip undergoes a deflection in the flow, acting like a cantilever. The consequent displacement of light spot center is monitored by the QD generating four unbalanced photocurrents which are function of fiber tip position. The analog electronic circuit processes the photocurrents providing voltage signalmore » proportional to light spot position. A circular target was placed on the fiber in order to increase the sensing surface. Sensor, tested in the measurement range up to 10 l min{sup -1}, shows a discrimination threshold of 2 l min{sup -1}, extremely low fluid dynamic resistance (0.17 Pa min l{sup -1}), and high sensitivity, also at low flow rates (i.e., 33 mV min l{sup -1} up to 4 l min{sup -1} and 98 mV min l{sup -1} from 4 l min{sup -1} up to 10 l min{sup -1}). Experimental results agree with the theoretical predictions. The high sensitivity, along with the reduced dimension and negligible pressure drop, makes the proposed transducer suitable for medical applications in neonatal ventilation.« less

40 CFR 1066.625 - Flow meter calibration calculations.

Code of Federal Regulations, 2014 CFR

2014-07-01

... to calculate viscosities of gas mixtures. b The model results are valid only for ambient conditions..., including a polynomial or a power series. The following equation is an example of a commonly used... each combination of venturis as one venturi by determining K v for the system. (1) To determine K v for...

40 CFR 60.5225 - What are the monitoring and calibration requirements for compliance with my operating limits?

Code of Federal Regulations, 2012 CFR

2012-07-01

... SOURCES Emission Guidelines and Compliance Times for Existing Sewage Sludge Incineration Units Model Rule... monitoring system according to your monitoring plan required under § 60.4880. Additionally: (i) For carrier gas flow rate monitors (for activated carbon injection), during the performance test conducted...

A flow calorimeter for determining combustion efficiency from residual enthalpy of exhaust gases

NASA Technical Reports Server (NTRS)

Evans, Albert; Hibbard, Robert R

1954-01-01

A flow calorimeter for determining the combustion efficiency of turbojet and ram-jet combustors from measurement of the residual enthalpy of combustion of the exhaust gas is described. Briefly, the calorimeter catalytically oxidizes the combustible constituents of exhaust-gas samples, and the resultant temperature rise is measured. This temperature rise is related to the residual enthalpy of combustion of the sample by previous calibration of the calorimeter. Combustion efficiency can be calculated from a knowledge of the residual enthalpy of the exhaust gas and the combustor input enthalpy. An accuracy of +-0.2 Btu per cubic foot was obtained with prepared fuel-air mixtures, and the combustion efficiencies of single turbojet combustors measured by both the flow-calorimeter and heat-balance methods compared within 3 percentage units. Flow calorimetry appears to be a suitable method for determining combustion efficiencies at high combustor temperatures where ordinary thermocouples cannot be used. The method is fundamentally more accurate than heat-balance methods at high combustion efficiencies and can be used to verify near-100-percent efficiency data.

Calibrated FMRI.

PubMed

Hoge, Richard D

2012-08-15

Functional magnetic resonance imaging with blood oxygenation level-dependent (BOLD) contrast has had a tremendous influence on human neuroscience in the last twenty years, providing a non-invasive means of mapping human brain function with often exquisite sensitivity and detail. However the BOLD method remains a largely qualitative approach. While the same can be said of anatomic MRI techniques, whose clinical and research impact has not been diminished in the slightest by the lack of a quantitative interpretation of their image intensity, the quantitative expression of BOLD responses as a percent of the baseline T2*- weighted signal has been viewed as necessary since the earliest days of fMRI. Calibrated MRI attempts to dissociate changes in oxygen metabolism from changes in blood flow and volume, the latter three quantities contributing jointly to determine the physiologically ambiguous percent BOLD change. This dissociation is typically performed using a "calibration" procedure in which subjects inhale a gas mixture containing small amounts of carbon dioxide or enriched oxygen to produce changes in blood flow and BOLD signal which can be measured under well-defined hemodynamic conditions. The outcome is a calibration parameter M which can then be substituted into an expression providing the fractional change in oxygen metabolism given changes in blood flow and BOLD signal during a task. The latest generation of calibrated MRI methods goes beyond fractional changes to provide absolute quantification of resting-state oxygen consumption in micromolar units, in addition to absolute measures of evoked metabolic response. This review discusses the history, challenges, and advances in calibrated MRI, from the personal perspective of the author. Copyright © 2012 Elsevier Inc. All rights reserved.

Are high flow nasal cannulae noisier than bubble CPAP for preterm infants?

PubMed

Roberts, C T; Dawson, J A; Alquoka, E; Carew, P J; Donath, S M; Davis, P G; Manley, B J

2014-07-01

Noise exposure in the neonatal intensive care unit is believed to be a risk factor for hearing loss in preterm neonates. Continuous positive airway pressure (CPAP) devices exceed recommended noise levels. High flow nasal cannulae (HFNC) are an increasingly popular alternative to CPAP for treating preterm infants, but there are no in vivo studies assessing noise production by HFNC. To study whether HFNC are noisier than bubble CPAP (BCPAP) for preterm infants. An observational study of preterm infants receiving HFNC or BCPAP. Noise levels within the external auditory meatus (EAM) were measured using a microphone probe tube connected to a calibrated digital dosimeter. Noise was measured across a range of frequencies and reported as decibels A-weighted (dBA). A total of 21 HFNC and 13 BCPAP noise measurements were performed in 21 infants. HFNC gas flows were 2-5 L/min, and BCPAP gas flows were 6-10 L/min with set pressures of 5-7 cm of water. There was no evidence of a difference in average noise levels measured at the EAM: mean difference (95% CI) of -1.6 (-4.0 to 0.9) dBA for HFNC compared to BCPAP. At low frequency (500 Hz), HFNC was mean (95% CI) 3.0 (0.3 to 5.7) dBA quieter than BCPAP. Noise increased with increasing BCPAP gas flow (p=0.007), but not with increasing set pressure. There was a trend to noise increasing with increasing HFNC gas flows. At the gas flows studied, HFNC are not noisier than BCPAP for preterm infants.

Computed tomography measurement of gaseous fuel concentration by infrared laser light absorption

NASA Astrophysics Data System (ADS)

Kawazoe, Hiromitsu; Inagaki, Kazuhisa; Emi, Y.; Yoshino, Fumio

1997-11-01

A system to measure gaseous hydrocarbon distributions was devised, which is based on IR light absorption by C-H stretch mode of vibration and computed tomography method. It is called IR-CT method in the paper. Affection of laser light power fluctuation was diminished by monitoring source light intensity by the second IR light detector. Calibration test for methane fuel was carried out to convert spatial data of line absorption coefficient into quantitative methane concentration. This system was applied to three flow fields. The first is methane flow with lifted flame which is generated by a gourd-shaped fuel nozzle. Feasibility of the IR-CT method was confirmed through the measurement. The second application is combustion field with diffusion flame. Calibration to determine absorptivity was undertaken, and measured line absorption coefficient was converted spatial fuel concentration using corresponding temperature data. The last case is modeled in cylinder gas flow of internal combustion engine, where gaseous methane was led to the intake valve in steady flow state. The fuel gas flow simulates behavior of gaseous gasoline which is evaporated at intake valve tulip. Computed tomography measurement of inner flow is essentially difficult because of existence of surrounding wall. In this experiment, IR laser beam was led to planed portion by IR light fiber. It is found that fuel convection by airflow takes great part in air-fuel mixture formation and the developed IR-CT system to measure fuel concentration is useful to analyze air-fuel mixture formation process and to develop new combustors.

Flow-based ammonia gas analyzer with an open channel scrubber for indoor environments.

PubMed

Ohira, Shin-Ichi; Heima, Minako; Yamasaki, Takayuki; Tanaka, Toshinori; Koga, Tomoko; Toda, Kei

2013-11-15

A robust and fully automated indoor ammonia gas monitoring system with an open channel scrubber (OCS) was developed. The sample gas channel dimensions, hydrophilic surface treatment to produce a thin absorbing solution layer, and solution flow rate of the OCS were optimized to connect the OCS as in-line gas collector and avoid sample humidity effects. The OCS effluent containing absorbed ammonia in sample gas was injected into a derivatization solution flow. Derivatization was achieved with o-phthalaldehyde and sulfite in pH 11 buffer solution. The product, 1-sulfonateisoindole, is detected with a home-made fluorescence detector. The limit of detection of the analyzer based on three times the standard deviation of baseline noise was 0.9 ppbv. Sample gas could be analyzed 40 times per hour. Furthermore, relative humidity of up to 90% did not interfere considerably with the analyzer. Interference from amines was not observed. The developed gas analysis system was calibrated using a solution-based method. The system was used to analyze ammonia in an indoor environment along with an off-site method, traditional impinger gas collection followed by ion chromatographic analysis, for comparison. The results obtained using both methods agreed well. Therefore, the developed system can perform on-site monitoring of ammonia in indoor environments with improved time resolution compared with that of other methods. Crown Copyright © 2013 Published by Elsevier B.V. All rights reserved.

Comparison of an infrared anaesthetic agent analyser (Datex-Ohmeda) with refractometry for measurement of isoflurane, sevoflurane and desflurane concentrations.

PubMed

Rudolff, Andrea S; Moens, Yves P S; Driessen, Bernd; Ambrisko, Tamas D

2014-07-01

To assess agreement between infrared (IR) analysers and a refractometer for measurements of isoflurane, sevoflurane and desflurane concentrations and to demonstrate the effect of customized calibration of IR analysers. In vitro experiment. Six IR anaesthetic monitors (Datex-Ohmeda) and a single portable refractometer (Riken). Both devices were calibrated following the manufacturer's recommendations. Gas samples were collected at common gas outlets of anaesthesia machines. A range of agent concentrations was produced by stepwise changes in dial settings: isoflurane (0-5% in 0.5% increments), sevoflurane (0-8% in 1% increments), or desflurane (0-18% in 2% increments). Oxygen flow was 2 L minute(-1) . The orders of testing IR analysers, agents and dial settings were randomized. Duplicate measurements were performed at each setting. The entire procedure was repeated 24 hours later. Bland-Altman analysis was performed. Measurements on day-1 were used to yield calibration equations (IR measurements as dependent and refractometry measurements as independent variables), which were used to modify the IR measurements on day-2. Bias ± limits of agreement for isoflurane, sevoflurane and desflurane were 0.2 ± 0.3, 0.1 ± 0.4 and 0.7 ± 0.9 volume%, respectively. There were significant linear relationships between differences and means for all agents. The IR analysers became less accurate at higher gas concentrations. After customized calibration, the bias became almost zero and the limits of agreement became narrower. If similar IR analysers are used in research studies, they need to be calibrated against a reference method using the agent in question at multiple calibration points overlapping the range of interest. © 2013 Association of Veterinary Anaesthetists and the American College of Veterinary Anesthesia and Analgesia.

Evaluation of Aerosol Optical Thickness algorithm for Geostationary Environmental Monitoring Spectrometer (GEMS) Using the OMI Instrument over East Asia

NASA Astrophysics Data System (ADS)

Go, S.; Kim, J.; KIM, M.; Choi, M.; Lim, H.; Torres, O.; Chang, L.; Hong, J.

2016-12-01

Nitrous oxide (N2O) is a powerful greenhouse gas and ozone depleting substance. With high atmospheric backgrounds and small relative signals, N2O emissions have been challenging to observe and understand on regional scales with traditional instrumentation. Fast-response airborne measurements with high precision and accuracy can potentially bridge this observational gap. Here we present flight assessments of a new flight system based on an Aerodyne mini-spectrometer as well as a Los Gatos N2O/CO analyzer during the Fertilizer Emissions Airborne Study (FEAST). With the Scientific Aviation Mooney aircraft, we conducted test flights for both analyzers where a known calibration gas was sampled throughout the flight (`null' tests). Clear altitude/cabin-pressure dependencies were observed for both analyzers if operated in an "off-the-shelf' manner. For the remainder of test flights and the FEAST campaign we used a new flight system based on an Aerodyne mini-spectrometer with the addition of a custom pressure control/calibration system. Instead of using traditional approaches with spectral-zeros and infrequent in-flight calibrations, we employ a high-flow system with stable flow control to enable high frequency (2 minutes), short duration (15 seconds) sampling of a known calibration gas. This approach, supported by the null test, enables correction for spectral drift caused by a variety of factors while maintaining a 90% duty cycle for 1Hz sampling from an aircraft. Preliminary in-flight precisions are estimated at 0.05 ppb, 0.1 ppm, 1 ppb, and 10 ppm for N2O, CO2, CO, and H2O respectively. We also present a further 40 hours of inter-comparison in flight with a Picarro 2301-f ring-down spectrometer demonstrating consistency between CO2 and H2O measurements and no altitude dependent error.

Airborne testing and demonstration of a new flight system based on an Aerodyne N2O-CO2-CO-H2O mini-spectrometer

NASA Astrophysics Data System (ADS)

Gvakharia, A.; Kort, E. A.; Smith, M. L.; Conley, S.

2017-12-01

Nitrous oxide (N2O) is a powerful greenhouse gas and ozone depleting substance. With high atmospheric backgrounds and small relative signals, N2O emissions have been challenging to observe and understand on regional scales with traditional instrumentation. Fast-response airborne measurements with high precision and accuracy can potentially bridge this observational gap. Here we present flight assessments of a new flight system based on an Aerodyne mini-spectrometer as well as a Los Gatos N2O/CO analyzer during the Fertilizer Emissions Airborne Study (FEAST). With the Scientific Aviation Mooney aircraft, we conducted test flights for both analyzers where a known calibration gas was sampled throughout the flight (`null' tests). Clear altitude/cabin-pressure dependencies were observed for both analyzers if operated in an "off-the-shelf' manner. For the remainder of test flights and the FEAST campaign we used a new flight system based on an Aerodyne mini-spectrometer with the addition of a custom pressure control/calibration system. Instead of using traditional approaches with spectral-zeros and infrequent in-flight calibrations, we employ a high-flow system with stable flow control to enable high frequency (2 minutes), short duration (15 seconds) sampling of a known calibration gas. This approach, supported by the null test, enables correction for spectral drift caused by a variety of factors while maintaining a 90% duty cycle for 1Hz sampling from an aircraft. Preliminary in-flight precisions are estimated at 0.05 ppb, 0.1 ppm, 1 ppb, and 10 ppm for N2O, CO2, CO, and H2O respectively. We also present a further 40 hours of inter-comparison in flight with a Picarro 2301-f ring-down spectrometer demonstrating consistency between CO2 and H2O measurements and no altitude dependent error.

Wet-Atmosphere Generator

NASA Technical Reports Server (NTRS)

Hamner, Richard M.; Mcguire, Janice K.

1988-01-01

Water content in gas controlled. Portable flow-control system generates nitrogen/water atmosphere having range of dew points and pressures. One use of system provides wet nitrogen for canister of wide-field camera requiring this special atmosphere. Also used to inject trace gases other than water vapor for leak testing of large vessels. Potential applications in photography, hospitals, and calibration laboratories.

International Space Station Major Constituent Analyzer On-Orbit Performance

NASA Technical Reports Server (NTRS)

Gardner, Ben D.; Erwin, Philip M.; Thoresen, Souzan; Granahan, John; Matty, Chris

2010-01-01

The Major Constituent Analyzer is a mass spectrometer based system that measures the major atmospheric constituents on the International Space Station. A number of limited-life components require periodic changeout, including the analyzer (ORU 02) and the verification gas assembly (ORU 08). The longest lasting ORU 02 was recently replaced after a record service length of 1033 days. The comparatively high performance duration may be attributable to a reduced inlet flow rate into the analyzer, resulting in increased ion pump lifetime; however, there may be other factors as well. A recent schedule slip for delivery of replacement verification gas led to a demonstration that the calibration interval could be extended on a short-term basis. An analysis of ORU 08 performance characteristics indicates that it is possible to temporarily extend the calibration interval from 6 weeks to 12 weeks if necessary.

State of the art stationary and mobile infrastructure for the dynamic generation and dilution of traceable reference gas mixtures of Ammonia at ambient air amount fractions

NASA Astrophysics Data System (ADS)

Leuenberger, Daiana; Pascale, Céline; Guillevic, Myriam; Ackermann, Andreas; Niederhauser, Bernhard

2017-04-01

Ammonia (NH3) in the atmosphere is the major precursor for neutralising atmospheric acids and is thus affecting not only the long-range transport of sulphur dioxide and nitrogen oxides but also stabilises secondary particulate matter. These aerosols have negative impacts on air quality and human health. Moreover, they negatively affect terrestrial ecosystems after deposition. NH3 has been included in the air quality monitoring networks and emission reduction directives of European nations. Atmospheric concentrations are in the order of 0.5-500 nmol/mol. However, the lowest substance amount fraction of available certified reference material (CRM) is 10 μmol/mol. This due to the fact that adsorption on the walls of aluminium cylinders and desorption as pressure in the cylinder decreases cause substantial instabilities in the amount fractions of the gas mixtures. Moreover, analytical techniques to be calibrated are very diverse and cause challenges for the production and application of CRM. The Federal Institute of Metrology METAS has developed, partially in the framework of EMRP JRP ENV55 MetNH3, an infrastructure to meet with the different requirements in order to generate SI-traceable NH3 reference gas mixtures dynamically in the amount fraction range 0.5-500 nmol/mol and with uncertainties UNH3 <3%. The infrastructure consists of a stationary as well as a mobile device for full flexibility in the application: In the stationary system, a magnetic suspension balance monitors the specific temperature and pressure dependent mass loss over time of the pure substance in a permeation tube (here NH3) by permeation through a membrane into a constant flow of carrier gas. Subsequently, this mixture is diluted with a system of thermal mass flow controllers in one or two consecutive steps to desired amount fractions. The permeation tube with calibrated permeation rate (mass loss over time previously determined in the magnetic suspension balance) can be transferred into the temperature-regulated permeation chamber of a newly developed mobile reference gas generator (ReGaS1). In addition to the permeation chamber it consists of the same dilution system as afore mentioned, stationary system. All components are fully traceable to SI standards. Considerable effort has been made to minimise adsorption on the gas-wetted stainless steel surfaces and thus to reduce stabilisation times by applying the SilcoNert2000® coating substance. Analysers can be connected directly to both, stationary and mobile systems for calibration. Moreover, the resulting gas mixture can also be pressurised into coated cylinders by cryo-filling. The mobile system as well as these cylinders can be applied for calibrations in other laboratories and in the field. In addition, an SI traceable system based on a cascade of critical orifices has been established to dilute NH3 mixtures in the order of μmol/mol stored in cylinders for the participation in the international key-comparison CCQM K117. It is planned to establish this system to calibrate and re-sample gas cylinders due to its very economical gas use. Here we present insights into the development of said infrastructure and results of the first performance tests. Moreover, we include results of the study on adsorption/desorption effects in dry as well as humidified matrix gas into the discussion on the generation of reference gas mixtures. Acknowledgement: This work was supported by the European Metrology Research Programme (EMRP). The EMRP is jointly funded by the EMRP participating countries within EURAMET and the European Union.

Shock wave calibration of under-expanded natural gas fuel jets

NASA Astrophysics Data System (ADS)

White, T. R.; Milton, B. E.

2008-10-01

Natural gas, a fuel abundant in nature, cannot be used by itself in conventional diesel engines because of its low cetane number. However, it can be used as the primary fuel with ignition by a pilot diesel spray. This is called dual-fuelling. The gas may be introduced either into the inlet manifold or, preferably, directly into the cylinder where it is injected as a short duration, intermittent, sonic jet. For accurate delivery in the latter case, a constant flow-rate from the injector is required into the constantly varying pressure in the cylinder. Thus, a sonic (choked) jet is required which is generally highly under-expanded. Immediately at the nozzle exit, a shock structure develops which can provide essential information about the downstream flow. This shock structure, generally referred to as a “barrel” shock, provides a key to understanding the full injection process. It is examined both experimentally and numerically in this paper.

Heavy Gas Conversion of the NASA Langley Transonic Dynamics Tunnel

NASA Technical Reports Server (NTRS)

Corliss, James M.; Cole, Stanley, R.

1998-01-01

The heavy gas test medium has recently been changed in the Transonic Dynamics Tunnel (TDT) at the NASA Langley Research Center. A NASA Construction of Facilities project has converted the TDT heavy gas from dichlorodifluoromethane (R12) to 1,1,1,2 tetrafluoroethane (R134a). The facility s heavy gas processing system was extensively modified to implement the conversion to R134a. Additional system modifications have improved operator interfaces, hardware reliability, and quality of the research data. The facility modifications included improvements to the heavy gas compressor and piping, the cryogenic heavy gas reclamation system, and the heavy gas control room. A series of wind tunnel characterization and calibration tests are underway. Results of the flow characterization tests show the TDT operating envelope in R134a to be very similar to the previous operating envelope in R12.

CO 2 Leakage Into Shallow Aquifers: Modeling CO 2 Gas Evolution and Accumulation at Interfaces of Heterogeneity

DOE PAGES

Porter, Mark L.; Plampin, Michael; Pawar, Rajesh; ...

2014-12-31

The physicochemical processes associated with CO 2 leakage into shallow aquifer systems are complex and span multiple spatial and time scales. Continuum-scale numerical models that faithfully represent the underlying pore-scale physics are required to predict the long-term behavior and aid in risk analysis regarding regulatory and management decisions. This study focuses on benchmarking the numerical simulator, FEHM, with intermediate-scale column experiments of CO 2 gas evolution in homogeneous and heterogeneous sand configurations. Inverse modeling was conducted to calibrate model parameters and determine model sensitivity to the observed steady-state saturation profiles. It is shown that FEHM is a powerful tool thatmore » is capable of capturing the experimentally observed out ow rates and saturation profiles. Moreover, FEHM captures the transition from single- to multi-phase flow and CO 2 gas accumulation at interfaces separating sands. We also derive a simple expression, based on Darcy's law, for the pressure at which CO 2 free phase gas is observed and show that it reliably predicts the location at which single-phase flow transitions to multi-phase flow.« less

Design and performance of the Ames electric-arc shock tunnel

NASA Technical Reports Server (NTRS)

Reller, J. O., Jr.

1973-01-01

A high enthalpy shock tunnel using arc-heated helium as the driver gas was designed for gas dynamic research at total stream energies from 7,000 to 35,000 j/g. The arc driver was found to be a relatively efficient energy converter. Tailored shock Mach numbers from 11.5 to 14.6 in air were demonstrated. A nozzle calibration with a total stream enthalpy of 18,600 j/g of air gave test times of 1.5 to 2.0 m sec at flow Mach numbers from 16 to 24.

Electronic field permeameter

DOEpatents

Chandler, Mark A.; Goggin, David J.; Horne, Patrick J.; Kocurek, Gary G.; Lake, Larry W.

1989-01-01

For making rapid, non-destructive permeability measurements in the field, a portable minipermeameter of the kind having a manually-operated gas injection tip is provided with a microcomputer system which operates a flow controller to precisely regulate gas flow rate to a test sample, and reads a pressure sensor which senses the pressure across the test sample. The microcomputer system automatically turns on the gas supply at the start of each measurement, senses when a steady-state is reached, collects and records pressure and flow rate data, and shuts off the gas supply immediately after the measurement is completed. Preferably temperature is also sensed to correct for changes in gas viscosity. The microcomputer system may also provide automatic zero-point adjustment, sensor calibration, over-range sensing, and may select controllers, sensors, and set-points for obtaining the most precise measurements. Electronic sensors may provide increased accuracy and precision. Preferably one microcomputer is used for sensing instrument control and data collection, and a second microcomputer is used which is dedicated to recording and processing the data, selecting the sensors and set-points for obtaining the most precise measurements, and instructing the user how to set-up and operate the minipermeameter. To provide mass data collection and user-friendly operation, the second microcomputer is preferably a lap-type portable microcomputer having a non-volatile or battery-backed CMOS memory.

Small Gas Turbine Combustor Primary Zone Study

NASA Technical Reports Server (NTRS)

Sullivan, R. E.; Young, E. R.; Miles, G. A.; Williams, J. R.

1983-01-01

A development process is described which consists of design, fabrication, and preliminary test evaluations of three approaches to internal aerodynamic primary zone flow patterns: (1) conventional double vortex swirl stabilization; (2) reverse flow swirl stabilization; and (3) large single vortex flow system. Each concept incorporates special design features aimed at extending the performance capability of the small engine combustor. Since inherent geometry of these combustors result in small combustion zone height and high surface area to volume ratio, design features focus on internal aerodynamics, fuel placement, and advanced cooling. The combustors are evaluated on a full scale annular combustor rig. A correlation of the primary zone performance with the overall performance is accomplished using three intrusion type gas sampling probes located at the exit of the primary zone section. Empirical and numerical methods are used for designing and predicting the performance of the three combustor concepts and their subsequent modifications. The calibration of analytical procedures with actual test results permits an updating of the analytical design techniques applicable to small reverse flow annular combustors.

Quantitative blood flow measurements in the small animal cardiopulmonary system using digital subtraction angiography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin Mingde; Marshall, Craig T.; Qi, Yi

Purpose: The use of preclinical rodent models of disease continues to grow because these models help elucidate pathogenic mechanisms and provide robust test beds for drug development. Among the major anatomic and physiologic indicators of disease progression and genetic or drug modification of responses are measurements of blood vessel caliber and flow. Moreover, cardiopulmonary blood flow is a critical indicator of gas exchange. Current methods of measuring cardiopulmonary blood flow suffer from some or all of the following limitations--they produce relative values, are limited to global measurements, do not provide vasculature visualization, are not able to measure acute changes, aremore » invasive, or require euthanasia. Methods: In this study, high-spatial and high-temporal resolution x-ray digital subtraction angiography (DSA) was used to obtain vasculature visualization, quantitative blood flow in absolute metrics (ml/min instead of arbitrary units or velocity), and relative blood volume dynamics from discrete regions of interest on a pixel-by-pixel basis (100x100 {mu}m{sup 2}). Results: A series of calibrations linked the DSA flow measurements to standard physiological measurement using thermodilution and Fick's method for cardiac output (CO), which in eight anesthetized Fischer-344 rats was found to be 37.0{+-}5.1 ml/min. Phantom experiments were conducted to calibrate the radiographic density to vessel thickness, allowing a link of DSA cardiac output measurements to cardiopulmonary blood flow measurements in discrete regions of interest. The scaling factor linking relative DSA cardiac output measurements to the Fick's absolute measurements was found to be 18.90xCO{sub DSA}=CO{sub Fick}. Conclusions: This calibrated DSA approach allows repeated simultaneous visualization of vasculature and measurement of blood flow dynamics on a regional level in the living rat.« less

Evaluation of liquid aerosol transport through porous media

NASA Astrophysics Data System (ADS)

Hall, R.; Murdoch, L.; Falta, R.; Looney, B.; Riha, B.

2016-07-01

Application of remediation methods in contaminated vadose zones has been hindered by an inability to effectively distribute liquid- or solid-phase amendments. Injection as aerosols in a carrier gas could be a viable method for achieving useful distributions of amendments in unsaturated materials. The objectives of this work were to characterize radial transport of aerosols in unsaturated porous media, and to develop capabilities for predicting results of aerosol injection scenarios at the field-scale. Transport processes were investigated by conducting lab-scale injection experiments with radial flow geometry, and predictive capabilities were obtained by developing and validating a numerical model for simulating coupled aerosol transport, deposition, and multi-phase flow in porous media. Soybean oil was transported more than 2 m through sand by injecting it as micron-scale aerosol droplets. Oil saturation in the sand increased with time to a maximum of 0.25, and decreased with radial distance in the experiments. The numerical analysis predicted the distribution of oil saturation with only minor calibration. The results indicated that evolution of oil saturation was controlled by aerosol deposition and subsequent flow of the liquid oil, and simulation requires including these two coupled processes. The calibrated model was used to evaluate field applications. The results suggest that amendments can be delivered to the vadose zone as aerosols, and that gas injection rate and aerosol particle size will be important controls on the process.

Development of an in situ calibration technique for combustible gas detectors

NASA Technical Reports Server (NTRS)

Shumar, J. W.; Wynveen, R. A.; Lance, N., Jr.; Lantz, J. B.

1977-01-01

This paper describes the development of an in situ calibration procedure for combustible gas detectors (CGD). The CGD will be a necessary device for future space vehicles as many subsystems in the Environmental Control/Life Support System utilize or produce hydrogen (H2) gas. Existing calibration techniques are time-consuming and require support equipment such as an environmental chamber and calibration gas supply. The in situ calibration procedure involves utilization of a water vapor electrolysis cell for the automatic in situ generation of a H2/air calibration mixture within the flame arrestor of the CGD. The development effort concluded with the successful demonstration of in situ span calibrations of a CGD.

Small-volume, ultrahigh-vacuum-compatible high-pressure reaction cell for combined kinetic and in situ IR spectroscopic measurements on planar model catalysts

NASA Astrophysics Data System (ADS)

Zhao, Z.; Diemant, T.; Häring, T.; Rauscher, H.; Behm, R. J.

2005-12-01

We describe the design and performance of a high-pressure reaction cell for simultaneous kinetic and in situ infrared reflection (IR) spectroscopic measurements on model catalysts at elevated pressures, between 10-3 and 103mbars, which can be operated both as batch reactor and as flow reactor with defined gas flow. The cell is attached to an ultrahigh-vacuum (UHV) system, which is used for sample preparation and also contains facilities for sample characterization. Specific for this design is the combination of a small cell volume, which allows kinetic measurements with high sensitivity under batch or continuous flow conditions, the complete isolation of the cell from the UHV part during UHV measurements, continuous temperature control during both UHV and high-pressure operation, and rapid transfer between UHV and high-pressure stage. Gas dosing is performed by a designed gas-handling system, which allows operation as flow reactor with calibrated gas flows at adjustable pressures. To study the kinetics of reactions on the model catalysts, a quadrupole mass spectrometer is connected to the high-pressure cell. IR measurements are possible in situ by polarization-modulation infrared reflection-absorption spectroscopy, which also allows measurements at elevated pressures. The performance of the setup is demonstrated by test measurements on the kinetics for CO oxidation and the CO adsorption on a Au /TiO2/Ru(0001) model catalyst film at 1-50 mbar total pressure.

Evaluation of the response of tritium-in-air instrumentation to HT in dry and humid conditions and to HTO vapor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phillips, H.; Dean, J.; Privas, E.

2015-03-15

Nuclear plant operators (power generation, decommissioning and reprocessing operations) are required to monitor releases of tritium species for regulatory compliance and radiation protection purposes. Tritium monitoring is performed using tritium-in-air gas monitoring instrumentation based either on flow-through ion chambers or proportional counting systems. Tritium-in-air monitors are typically calibrated in dry conditions but in service may operate at elevated levels of relative humidity. The NPL (National Physical Laboratory) radioactive gas-in-air calibration system has been used to study the effect of humidity on the response to tritium of two tritium-in-air ion chamber based monitors and one proportional counting system which uses amore » P10/air gas mixture. The response of these instruments to HTO vapour has also been evaluated. In each case, instrument responses were obtained for HT in dry conditions (relative humidity (RH) about 2%), HT in 45% RH, and finally HTO at 45% RH. Instrumentation response to HT in humid conditions has been found to slightly exceed that in dry conditions. (authors)« less

The development of an electrochemical technique for in situ calibrating of combustible gas detectors

NASA Technical Reports Server (NTRS)

Shumar, J. W.; Lantz, J. B.; Schubert, F. H.

1976-01-01

A program to determine the feasibility of performing in situ calibration of combustible gas detectors was successfully completed. Several possible techniques for performing the in situ calibration were proposed. The approach that showed the most promise involved the use of a miniature water vapor electrolysis cell for the generation of hydrogen within the flame arrestor of a combustible gas detector to be used for the purpose of calibrating the combustible gas detectors. A preliminary breadboard of the in situ calibration hardware was designed, fabricated and assembled. The breadboard equipment consisted of a commercially available combustible gas detector, modified to incorporate a water vapor electrolysis cell, and the instrumentation required for controlling the water vapor electrolysis and controlling and calibrating the combustible gas detector. The results showed that operation of the water vapor electrolysis at a given current density for a specific time period resulted in the attainment of a hydrogen concentration plateau within the flame arrestor of the combustible gas detector.

Predicting the performance uncertainty of a 1-MW pilot-scale carbon capture system after hierarchical laboratory-scale calibration and validation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Zhijie; Lai, Canhai; Marcy, Peter William

2017-05-01

A challenging problem in designing pilot-scale carbon capture systems is to predict, with uncertainty, the adsorber performance and capture efficiency under various operating conditions where no direct experimental data exist. Motivated by this challenge, we previously proposed a hierarchical framework in which relevant parameters of physical models were sequentially calibrated from different laboratory-scale carbon capture unit (C2U) experiments. Specifically, three models of increasing complexity were identified based on the fundamental physical and chemical processes of the sorbent-based carbon capture technology. Results from the corresponding laboratory experiments were used to statistically calibrate the physical model parameters while quantifying some of theirmore » inherent uncertainty. The parameter distributions obtained from laboratory-scale C2U calibration runs are used in this study to facilitate prediction at a larger scale where no corresponding experimental results are available. In this paper, we first describe the multiphase reactive flow model for a sorbent-based 1-MW carbon capture system then analyze results from an ensemble of simulations with the upscaled model. The simulation results are used to quantify uncertainty regarding the design’s predicted efficiency in carbon capture. In particular, we determine the minimum gas flow rate necessary to achieve 90% capture efficiency with 95% confidence.« less

40 CFR 1065.325 - Intake-flow calibration.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Section 1065.325 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calibrations and Verifications Flow-Related Measurements § 1065.325 Intake-flow calibration. (a) Calibrate intake-air flow meters upon initial installation. Follow the...

Application of laser Doppler velocimeter to chemical vapor laser system

NASA Technical Reports Server (NTRS)

Gartrell, Luther R.; Hunter, William W., Jr.; Lee, Ja H.; Fletcher, Mark T.; Tabibi, Bagher M.

1993-01-01

A laser Doppler velocimeter (LDV) system was used to measure iodide vapor flow fields inside two different-sized tubes. Typical velocity profiles across the laser tubes were obtained with an estimated +/-1 percent bias and +/-0.3 to 0.5 percent random uncertainty in the mean values and +/-2.5 percent random uncertainty in the turbulence-intensity values. Centerline velocities and turbulence intensities for various longitudinal locations ranged from 13 to 17.5 m/sec and 6 to 20 percent, respectively. In view of these findings, the effects of turbulence should be considered for flow field modeling. The LDV system provided calibration data for pressure and mass flow systems used routinely to monitor the research laser gas flow velocity.

40 CFR 1065.640 - Flow meter calibration calculations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Flow meter calibration calculations... POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.640 Flow meter calibration calculations. This section describes the calculations for calibrating various flow meters. After...

Radioisotope measurement of selected parameters of liquid-gas flow using single detector system

NASA Astrophysics Data System (ADS)

Zych, Marcin; Hanus, Robert; Jaszczur, Marek; Mosorov, Volodymyr; Świsulski, Dariusz

2018-06-01

To determine the parameters of two-phase flows using radioisotopes, usually two detectors are used. Knowing the distance between them, the velocity of the dispersed phase is calculated based on time delay estimation. Such a measurement system requires the use of two gamma-ray sealed sources. But in some situations it is also possible to determine velocity of dispersed phase using only one scintillation probe and one gamma-ray source. However, this requires proper signal analysis and prior calibration. This may also cause larger measurement errors. On the other hand, it allows measurements in hard to reach areas where there is often no place for the second detector. Additionally, by performing a previous calibration, it is possible to determine the void fraction or concentration of the selected phase. In this work an autocorrelation function was used to analyze the signal from the scintillation detector, which allowed for the determination of air velocities in slug and plug flows with an accuracy of 8.5%. Based on the analysis of the same signal, a void fraction with error of 15% was determined.

Flow injection gas chromatography with sulfur chemiluminescence detection for the analysis of total sulfur in complex hydrocarbon matrixes.

PubMed

Hua, Yujuan; Hawryluk, Myron; Gras, Ronda; Shearer, Randall; Luong, Jim

2018-01-01

A fast and reliable analytical technique for the determination of total sulfur levels in complex hydrocarbon matrices is introduced. The method employed flow injection technique using a gas chromatograph as a sample introduction device and a gas phase dual-plasma sulfur chemiluminescence detector for sulfur quantification. Using the technique described, total sulfur measurement in challenging hydrocarbon matrices can be achieved in less than 10 s with sample-to-sample time <2 min. The high degree of selectivity and sensitivity toward sulfur compounds of the detector offers the ability to measure low sulfur levels with a detection limit in the range of 20 ppb w/w S. The equimolar response characteristic of the detector allows the quantitation of unknown sulfur compounds and simplifies the calibration process. Response is linear over a concentration range of five orders of magnitude, with a high degree of repeatability. The detector's lack of response to hydrocarbons enables direct analysis without the need for time-consuming sample preparation and chromatographic separation processes. This flow injection-based sulfur chemiluminescence detection technique is ideal for fast analysis or trace sulfur analysis. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Experimental investigation of 20 K two-stage layered active magnetic regenerative refrigerator

NASA Astrophysics Data System (ADS)

Park, Inmyong; Jeong, Sangkwon

2015-12-01

The performance of a two-stage layered AMRR is experimentally investigated. The test apparatus includes two-stage layered AMRs, low temperature superconducting (LTS) magnet which generates maximum magnetic field of 4 T, and the helium gas flow system. The helium compressor with the tandem rotary valve is employed to generate the oscillating flow of the helium gas minimizing the pressure swing effect. The mass flow rate of working fluid is controlled separately at the first and second stages of the AMR by solenoid valves. The mass flow rate of the AMRs is measured by the mass flow meter and the cryogenic hot-film sensor which is calibrated at cryogenic temperature range from 20 K to 77 K. In order to reduce the heat leak by shuttle heat transfer of the working fluid, void volumes have been implemented and connected to the cold ends of the AMR1 and AMR2. The temperature span of the AMR is recorded as 52 K and the performance of the AMR with the variation of the mass flow rate is analysed. The results show that the mass flow rate and the heat leak due to the shuttle heat transfer by oscillating working fluid are crucial factors in the AMR performance.

Turbine blade and vane heat flux sensor development, phase 1

NASA Technical Reports Server (NTRS)

Atkinson, W. H.; Cyr, M. A.; Strange, R. R.

1984-01-01

Heat flux sensors available for installation in the hot section airfoils of advanced aircraft gas turbine engines were developed. Two heat flux sensors were designed, fabricated, calibrated, and tested. Measurement techniques are compared in an atmospheric pressure combustor rig test. Sensors, embedded thermocouple and the Gordon gauge, were fabricated that met the geometric and fabricability requirements and could withstand the hot section environmental conditions. Calibration data indicate that these sensors yielded repeatable results and have the potential to meet the accuracy goal of measuring local heat flux to within 5%. Thermal cycle tests and thermal soak tests indicated that the sensors are capable of surviving extended periods of exposure to the environment conditions in the turbine. Problems in calibration of the sensors caused by severe non-one dimensional heat flow were encountered. Modifications to the calibration techniques are needed to minimize this problem and proof testing of the sensors in an engine is needed to verify the designs.

Turbine blade and vane heat flux sensor development, phase 1

NASA Astrophysics Data System (ADS)

Atkinson, W. H.; Cyr, M. A.; Strange, R. R.

1984-08-01

Heat flux sensors available for installation in the hot section airfoils of advanced aircraft gas turbine engines were developed. Two heat flux sensors were designed, fabricated, calibrated, and tested. Measurement techniques are compared in an atmospheric pressure combustor rig test. Sensors, embedded thermocouple and the Gordon gauge, were fabricated that met the geometric and fabricability requirements and could withstand the hot section environmental conditions. Calibration data indicate that these sensors yielded repeatable results and have the potential to meet the accuracy goal of measuring local heat flux to within 5%. Thermal cycle tests and thermal soak tests indicated that the sensors are capable of surviving extended periods of exposure to the environment conditions in the turbine. Problems in calibration of the sensors caused by severe non-one dimensional heat flow were encountered. Modifications to the calibration techniques are needed to minimize this problem and proof testing of the sensors in an engine is needed to verify the designs.

Simultaneous flow of gas and water in a damage-susceptible argillaceous rock

NASA Astrophysics Data System (ADS)

Nguyen, T. S.

2011-12-01

A research project has been initiated by the Canadian Nuclear Safety Commission (CNSC) to study the influence of gas generation and migration on the long term safety of deep geological repositories for radioactive wastes. Such facilities rely on multiple barriers to isolate and contain the wastes. Depending on the level of radioactivity of the wastes, those barriers include some or all of the following: corrosion and structurally resistant containers, low permeability seals around the emplacements rooms, galleries and shaft, and finally the host rock formations. Large quantities of gas may be generated from the degradation of the waste forms or the corrosion of the containers. The generated gas pressures, if sufficiently large, can induce cracks and microcracks in the engineered and natural barriers and affect their containment functions. The author has developed a mathematical model to simulate the above effects. The model must be calibrated and validated with laboratory and field experiments in order to provide confidence in its future use for assessing the effects of gas on the long term safety of nuclear wastes repositories. The present communication describes the model and its use in the simulation of laboratory and large scale in-situ gas injection experiments in an argillaceous rock, known as Opalinus clay, from Mont Terri, Switzerland. Both the laboratory and in-situ experiments show that the gas flow rate substantially increases when the injection pressure is higher than the confining stress. The above observation seems to indicate that at high gas injection pressures, damage could possibly be induced in the rock formation resulting in an important increase in its permeability. In order to simulate the experiments, we developed a poro-elastoplastic model, with the consideration of two compressible pore fluids (water and gas). The bulk movement of the pore fluids is assumed to obey the generalized Darcy's law, and their respective degree of saturation is represented by the Van Genuchten's functions. The solid skeleton is assumed to be elastoplastic, with degradation of the strength and elastic modulus accompanied by an increase in permeability when damage is accumulated. The model can predict the three distinct flow regimes found in the experiments: a low flow regime where gas movement is restricted to the injection zone, a moderate flow regime when damage is limited, and a high flow regime when damage induces a substantial increase in the permeability.

40 CFR 63.2163 - If I monitor fermenter exhaust, what are my monitoring installation, operation, and maintenance...

Code of Federal Regulations, 2010 CFR

2010-07-01

...-accuracy test PS 8 requires. (3) If you continuously monitor VOC emissions using gas chromatography, you... percent of the span value (or more than 10 percent of the calibration gas value if your CEMS is a gas... calibration drift exceeds 5 percent of the span value (or more than 20 percent of the calibration gas value...

40 CFR 63.2163 - If I monitor fermenter exhaust, what are my monitoring installation, operation, and maintenance...

Code of Federal Regulations, 2011 CFR

2011-07-01

...-accuracy test PS 8 requires. (3) If you continuously monitor VOC emissions using gas chromatography, you... percent of the span value (or more than 10 percent of the calibration gas value if your CEMS is a gas... calibration drift exceeds 5 percent of the span value (or more than 20 percent of the calibration gas value...

Transient, hypervelocity flow in an axisymmetric nozzle

NASA Technical Reports Server (NTRS)

Jacobs, P. A.

1991-01-01

The performance of an axisymmetric nozzle was examined which was designed to produce uniform, parallel flow with a nominal Mach number of 8. A free-piston driven shock tube was used to supply the nozzle with high-temperature, high-pressure test gas. Performance was assessed by measuring Pitot pressures across the exit plane of the nozzle and, over the range of operating conditions examined, the nozzle produced satisfactory test flows. However, there were flow disturbances that persisted for significant times after flow initiation. The detailed starting process of the nozzle was also investigated by performing numerical simulations at several nominal test conditions. The classical description of the starting process, based on a quasi-one-dimensional model, provided a reasonable approximation and was used to demonstrate that the starting process could consume a significant fraction of the otherwise usable test gas. This was especially important at high operating enthalpies where nozzle supply conditions were maintained for shorter times. Multidimensional simulations illustrated a mechanism by which the starting process in the actual nozzle could take longer than that predicted by the quasi-one-dimensional analysis. However, the cause of the persistent disturbances observed in the experimental calibration was not identified.

Flow visualization studies of VTOL aircraft models during Hover in ground effect

NASA Technical Reports Server (NTRS)

Mourtos, Nikos J.; Couillaud, Stephane; Carter, Dale; Hange, Craig; Wardwell, Doug; Margason, Richard J.

1995-01-01

A flow visualization study of several configurations of a jet-powered vertical takeoff and landing (VTOL) aircraft model during hover in ground effect was conducted. A surface oil flow technique was used to observe the flow patterns on the lower surfaces of the model. There were significant configuration effects. Wing height with respect to fuselage, the presence of an engine inlet duct beside the fuselage, and nozzle pressure ratio are seen to have strong effects on the surface flow angles on the lower surface of the wing. This test was part of a program to improve the methods for predicting the hot gas ingestion (HGI) for jet-powered vertical/short takeoff and landing (V/STOL) aircraft. The tests were performed at the Jet Calibration and Hover Test (JCAHT) Facility at Ames Research Center.

Viewing inside Pyroclastic Flows - Large-scale Experiments on hot pyroclast-gas mixture flows

NASA Astrophysics Data System (ADS)

Breard, E. C.; Lube, G.; Cronin, S. J.; Jones, J.

2014-12-01

Pyroclastic density currents are the largest threat from volcanoes. Direct observations of natural flows are persistently prevented because of their violence and remain limited to broad estimates of bulk flow behaviour. The Pyroclastic Flow Generator - a large-scale experimental facility to synthesize hot gas-particle mixture flows scaled to pyroclastic flows and surges - allows investigating the physical processes behind PDC behaviour in safety. The ability to simulate natural eruption conditions and to view and measure inside the hot flows allows deriving validation and calibration data sets for existing numerical models, and to improve the constitutive relationships necessary for their effective use as powerful tools in hazard assessment. We here report on a systematic series of large-scale experiments on up to 30 ms-1 fast, 2-4.5 m thick, 20-35 m long flows of natural pyroclastic material and gas. We will show high-speed movies and non-invasive sensor data that detail the internal structure of the analogue pyroclastic flows. The experimental PDCs are synthesized by the controlled 'eruption column collapse' of variably diluted suspensions into an instrumented channel. Experiments show four flow phases: mixture acceleration and dilution during free fall; impact and lateral blasting; PDC runout; and co-ignimbrite cloud formation. The fully turbulent flows reach Reynolds number up to 107 and depositional facies similar to natural deposits. In the PDC runout phase, the shear flows develop a four-partite structure from top to base: a fully turbulent, strongly density-stratified ash cloud with average particle concentrations <<1vol%; a transient, turbulent dense suspension region with particle concentrations between 1 and 10 vol%; a non-turbulent, aerated and highly mobile dense underflows with particle concentrations between 40 and 50 vol%; and a vertically aggrading bed of static material. We characterise these regions and the exchanges of energy and momentum through their interfaces via vertical time-series profiles of velocity, particle concentration, gas and particle transport directionality and turbulent eddy characteristics. We highlight the importance of each region for the PDC runout dynamics and introduce a new transport and sedimentation model for downslope evolving pyroclastic flows.

Minimizing thermal degradation in gas chromatographic quantitation of pentaerythritol tetranitrate.

PubMed

Lubrano, Adam L; Field, Christopher R; Newsome, G Asher; Rogers, Duane A; Giordano, Braden C; Johnson, Kevin J

2015-05-15

An analytical method for establishing calibration curves for the quantitation of pentaerythriol tetranitrate (PETN) from sorbent-filled thermal desorption tubes by gas chromatography with electron capture detection (TDS-GC-ECD) was developed. As PETN has been demonstrated to thermally degrade under typical GC instrument conditions, peaks corresponding to both PETN degradants and molecular PETN are observed. The retention time corresponding to intact PETN was verified by high-resolution mass spectrometry with a flowing atmospheric pressure afterglow (FAPA) ionization source, which enabled soft ionization of intact PETN eluting the GC and subsequent accurate-mass identification. The GC separation parameters were transferred to a conventional GC-ECD instrument where analytical method-induced PETN degradation was further characterized and minimized. A method calibration curve was established by direct liquid deposition of PETN standard solutions onto the glass frit at the head of sorbent-filled thermal desorption tubes. Two local, linear relationships between detector response and PETN concentration were observed, with a total dynamic range of 0.25-25ng. Published by Elsevier B.V.

SI-traceable standards for atmospheric monitoring of halogenated gases

NASA Astrophysics Data System (ADS)

Guillevic, Myriam; Wyss, Simon A.; Pascale, Céline; Vollmer, Martin K.; Niederhauser, Bernhard; Reimann, Stefan

2017-04-01

To support atmospheric monitoring of greenhouse gases and in particular halogenated gases, we have developed a method to produce reference gas mixtures at nmol/mol (ppb) to pmol/mol levels (ppt). This method is dynamic and SI-traceable. This work is conducted in the framework of the EMRP projects HIGHGAS and KEY-VOCs as well as METAS' AtmoChemECV project. The method has been already applied to HFC-125 (pentafluoroethane, widely used in air conditioners), HFC-1234yf (2,3,3,3-tetrafluoropropene, a car air conditioner fluid of growing importance) and SF6 (insulant in electric switch-gears). It is currently being extended to HCFC-132b and CFC-13. It is particularly suitable for gas species and/or concentration ranges that are not stable in cylinders and it can be applied to a large variety of molecules related to air pollution and climate change (e.g., NO2, volatile organic compounds such as BTEX, NH3, water vapour at ppm level, CFCs, HCFCs, HFCs). The expanded uncertainty is less than 3 % (95 % confidence interval or k=2). The generation process is composed of four successive steps. In the first step the matrix gas, nitrogen or synthetic air is purified. Then this matrix gas is spiked with the pure substance, using a permeation device which contains a few grams of the pure substance (e.g., HFC-125) in the liquid form and loses it linearly over time by permeation through a membrane. This mass loss is precisely calibrated in our lab in Bern, using a magnetic suspension balance. In a third step the desired concentration is reached by dilution of the high concentration mixture exiting the permeation chamber with a chosen flow of the matrix gas in one or two subsequent dilution steps. All flows are piloted by mass flow controllers. All parts in contact with the gas mixture - including the balance - are passivated using coated surfaces, to reduce adsorption/desorption processes as much as possible. In the last step the mixture can be i) directly used to calibrate an analyser, ii) sampled on sorbent tubes or iii) pressurized into Silconert2000-coated stainless steel cylinders by cryo-filling. We focus here on standards made for the gases HFC-125 and HFC-1234yf. We present here the method, the uncertainty budget as well as first results of intercomparisons to other references.

Response characteristics of stable mixed-potential NH 3 sensors in diesel engine exhaust

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brosha, Eric L.; Prikhodko, Vitaly Y.; Kreller, Cortney R.

Here, a mixed-potential, electrochemical sensor platform is extended to NH 3 sensing by the introduction of a new gold alloy working electrode. A planar, pre-commercial NH 3 sensor utilized LANL’s controlled interface approach, and a Pd-Au alloy working electrode was tested in exhaust of a GM 1.9 L diesel engine downstream of a diesel oxidation catalyst through a slipstream arrangement. A fraction of the exhaust was pulled across the sensor with a pump at 20 L/min. In order to simulate NH 3 slip inside of a full SCR emissions control system, NH 3 was injected immediately upstream of the sensormore » using a calibrated mass flow controller. The sensor response quantitatively tracked the NH 3 as measured via Fourier transform infrared (FTIR) analyzer. A calibration curve was obtained in the exhaust from an ammonia staircase response with the engine running at steady-state engine conditions resulting in low background concentrations of NO x and HC (<20 ppm) during calibration. Exhaust gas recirculation (EGR) switching and sweeps were used to evaluate the NH 3 sensor response under different amounts of total background NO x. The calibration curve was used to directly compare the [NH 3] calculated from sensor response to the gas phase composition measured via FTIR. In general, there was excellent quantitative agreement between the sensor response and the actual NH 3 in the exhaust gas, and fast response time such that transients (<5 ppm) could be easily discerned from baseline. A LANL pre-commercial NO x sensor was tested simultaneously with the NH 3 sensor and the extent of cross-sensitivity between the two sensors will be discussed.« less

Response characteristics of stable mixed-potential NH 3 sensors in diesel engine exhaust

DOE PAGES

Brosha, Eric L.; Prikhodko, Vitaly Y.; Kreller, Cortney R.; ...

2016-10-20

Here, a mixed-potential, electrochemical sensor platform is extended to NH 3 sensing by the introduction of a new gold alloy working electrode. A planar, pre-commercial NH 3 sensor utilized LANL’s controlled interface approach, and a Pd-Au alloy working electrode was tested in exhaust of a GM 1.9 L diesel engine downstream of a diesel oxidation catalyst through a slipstream arrangement. A fraction of the exhaust was pulled across the sensor with a pump at 20 L/min. In order to simulate NH 3 slip inside of a full SCR emissions control system, NH 3 was injected immediately upstream of the sensormore » using a calibrated mass flow controller. The sensor response quantitatively tracked the NH 3 as measured via Fourier transform infrared (FTIR) analyzer. A calibration curve was obtained in the exhaust from an ammonia staircase response with the engine running at steady-state engine conditions resulting in low background concentrations of NO x and HC (<20 ppm) during calibration. Exhaust gas recirculation (EGR) switching and sweeps were used to evaluate the NH 3 sensor response under different amounts of total background NO x. The calibration curve was used to directly compare the [NH 3] calculated from sensor response to the gas phase composition measured via FTIR. In general, there was excellent quantitative agreement between the sensor response and the actual NH 3 in the exhaust gas, and fast response time such that transients (<5 ppm) could be easily discerned from baseline. A LANL pre-commercial NO x sensor was tested simultaneously with the NH 3 sensor and the extent of cross-sensitivity between the two sensors will be discussed.« less

Ecologically-focused Calibration of Hydrological Models for Environmental Flow Applications

NASA Astrophysics Data System (ADS)

Adams, S. K.; Bledsoe, B. P.

2015-12-01

Hydrologic alteration resulting from watershed urbanization is a common cause of aquatic ecosystem degradation. Developing environmental flow criteria for urbanizing watersheds requires quantitative flow-ecology relationships that describe biological responses to streamflow alteration. Ideally, gaged flow data are used to develop flow-ecology relationships; however, biological monitoring sites are frequently ungaged. For these ungaged locations, hydrologic models must be used to predict streamflow characteristics through calibration and testing at gaged sites, followed by extrapolation to ungaged sites. Physically-based modeling of rainfall-runoff response has frequently utilized "best overall fit" calibration criteria, such as the Nash-Sutcliffe Efficiency (NSE), that do not necessarily focus on specific aspects of the flow regime relevant to biota of interest. This study investigates the utility of employing flow characteristics known a priori to influence regional biological endpoints as "ecologically-focused" calibration criteria compared to traditional, "best overall fit" criteria. For this study, 19 continuous HEC-HMS 4.0 models were created in coastal southern California and calibrated to hourly USGS streamflow gages with nearby biological monitoring sites using one "best overall fit" and three "ecologically-focused" criteria: NSE, Richards-Baker Flashiness Index (RBI), percent of time when the flow is < 1 cfs (%<1), and a Combined Calibration (RBI and %<1). Calibrated models were compared using calibration accuracy, environmental flow metric reproducibility, and the strength of flow-ecology relationships. Results indicate that "ecologically-focused" criteria can be calibrated with high accuracy and may provide stronger flow-ecology relationships than "best overall fit" criteria, especially when multiple "ecologically-focused" criteria are used in concert, despite inabilities to accurately reproduce additional types of ecological flow metrics to which the models are not explicitly calibrated.

High Accuracy Acoustic Relative Humidity Measurement in Duct Flow with Air

PubMed Central

van Schaik, Wilhelm; Grooten, Mart; Wernaart, Twan; van der Geld, Cees

2010-01-01

An acoustic relative humidity sensor for air-steam mixtures in duct flow is designed and tested. Theory, construction, calibration, considerations on dynamic response and results are presented. The measurement device is capable of measuring line averaged values of gas velocity, temperature and relative humidity (RH) instantaneously, by applying two ultrasonic transducers and an array of four temperature sensors. Measurement ranges are: gas velocity of 0–12 m/s with an error of ±0.13 m/s, temperature 0–100 °C with an error of ±0.07 °C and relative humidity 0–100% with accuracy better than 2 % RH above 50 °C. Main advantage over conventional humidity sensors is the high sensitivity at high RH at temperatures exceeding 50 °C, with accuracy increasing with increasing temperature. The sensors are non-intrusive and resist highly humid environments. PMID:22163610

High accuracy acoustic relative humidity measurement in duct flow with air.

PubMed

van Schaik, Wilhelm; Grooten, Mart; Wernaart, Twan; van der Geld, Cees

2010-01-01

An acoustic relative humidity sensor for air-steam mixtures in duct flow is designed and tested. Theory, construction, calibration, considerations on dynamic response and results are presented. The measurement device is capable of measuring line averaged values of gas velocity, temperature and relative humidity (RH) instantaneously, by applying two ultrasonic transducers and an array of four temperature sensors. Measurement ranges are: gas velocity of 0-12 m/s with an error of ± 0.13 m/s, temperature 0-100 °C with an error of ± 0.07 °C and relative humidity 0-100% with accuracy better than 2 % RH above 50 °C. Main advantage over conventional humidity sensors is the high sensitivity at high RH at temperatures exceeding 50 °C, with accuracy increasing with increasing temperature. The sensors are non-intrusive and resist highly humid environments.

Cascadia Gas Vent Distribution and Challenges to Quantify Margin-Wide Methane Fluxes

NASA Astrophysics Data System (ADS)

Scherwath, M.; Riedel, M.; Roemer, M.; Veloso, M.; Heesemann, M.; Spence, G.

2017-12-01

Gas venting along the Cascadia Margin has been mapped over decades with ship sonar and in recent years with permanent seafloor installations utilizing the seafloor observatories NEPTUNE of Ocean Networks Canada and the Cabled Array of the Ocean Observatories Initiative. We show the distribution of over 1000 vents, most on the shallow shelf. For a third of the vents we have estimated methane flow rates, ranging from 0.05 to 69 L/min, and extrapolate these results to a margin-wide methane flow estaimate of around 4 Mt/yr (at surface pressure and temperature) and a flux estimate of 0.05 kg yr-1 m-2. However, these estimates are based on several assumptions, e.g. bubble sizes or data coverage, providing large uncertainties. With continued research expeditions and potential seafloor calibration experiments, these data can be refined and improved in future years.

Advanced technologies and devices for inhalational anesthetic drug dosing.

PubMed

Meyer, J-U; Kullik, G; Wruck, N; Kück, K; Manigel, J

2008-01-01

Technological advances in micromechanics, optical sensing, and computing have led to innovative and reliable concepts of precise dosing and sensing of modern volatile anesthetics. Mixing of saturated desflurane flow with fresh gas flow (FGF) requires differential pressure sensing between the two circuits for precise delivery. The medical gas xenon is administered most economically in a closed circuit breathing system. Sensing of xenon in the breathing system is achieved with miniaturized and unique gas detector systems. Innovative sensing principles such as thermal conductivity and sound velocity are applied. The combination of direct injection of volatile anesthetics and low-flow in a closed circuit system requires simultaneous sensing of the inhaled and exhaled gas concentrations. When anesthetic conserving devices are used for sedation with volatile anesthetics, regular gas concentration monitoring is advised. High minimal alveolar concentration (MAC) of some anesthetics and low-flow conditions bear the risk of hypoxic gas delivery. Oxygen sensing based on paramagnetic thermal transduction has become the choice when long lifetime and one-time calibration are required. Compact design of beam splitters, infrared filters, and detectors have led to multiple spectra detector systems that fit in thimble-sized housings. Response times of less than 500 ms allow systems to distinguish inhaled from exhaled gas concentrations. The compact gas detector systems are a prerequisite to provide "quantitative anesthesia" in closed circuit feedback-controlled breathing systems. Advanced anesthesia devices in closed circuit mode employ multiple feedback systems. Multiple feedbacks include controls of volume, concentrations of anesthetics, and concentration of oxygen with a corresponding safety system. In the ideal case, the feedback system delivers precisely what the patient is consuming. In this chapter, we introduce advanced technologies and device concepts for delivering inhalational anesthetic drugs. First, modern vaporizers are described with special attention to the particularities of delivering desflurane. Delivery of xenon is presented, followed by a discussion of direct injection of volatile anesthetics and of a device designed to conserve anesthetic drugs. Next, innovative sensing technologies are presented for reliable control and precise metering of the delivered volatile anesthetics. Finally, we discuss the technical challenges of automatic control in low-flow and closed circuit breathing systems in anesthesia.

Molecular Imaging of Kerogen and Minerals in Shale Rocks across Micro- and Nano- Scales

NASA Astrophysics Data System (ADS)

Hao, Z.; Bechtel, H.; Sannibale, F.; Kneafsey, T. J.; Gilbert, B.; Nico, P. S.

2016-12-01

Fourier transform infrared (FTIR) spectroscopy is a reliable and non-destructive quantitative method to evaluate mineralogy and kerogen content / maturity of shale rocks, although it is traditionally difficult to assess the organic and mineralogical heterogeneity at micrometer and nanometer scales due to the diffraction limit of the infrared light. However, it is truly at these scales that the kerogen and mineral content and their formation in share rocks determines the quality of shale gas reserve, the gas flow mechanisms and the gas production. Therefore, it's necessary to develop new approaches which can image across both micro- and nano- scales. In this presentation, we will describe two new molecular imaging approaches to obtain kerogen and mineral information in shale rocks at the unprecedented high spatial resolution, and a cross-scale quantitative multivariate analysis method to provide rapid geochemical characterization of large size samples. The two imaging approaches are enhanced at nearfield respectively by a Ge-hemisphere (GE) and by a metallic scanning probe (SINS). The GE method is a modified microscopic attenuated total reflectance (ATR) method which rapidly captures a chemical image of the shale rock surface at 1 to 5 micrometer resolution with a large field of view of 600 X 600 micrometer, while the SINS probes the surface at 20 nm resolution which provides a chemically "deconvoluted" map at the nano-pore level. The detailed geochemical distribution at nanoscale is then used to build a machine learning model to generate self-calibrated chemical distribution map at micrometer scale with the input of the GE images. A number of geochemical contents across these two important scales are observed and analyzed, including the minerals (oxides, carbonates, sulphides), the organics (carbohydrates, aromatics), and the absorbed gases. These approaches are self-calibrated, optics friendly and non-destructive, so they hold the potential to monitor shale gas flow at real time inside the micro- or nano- pore network, which is of great interest for optimizing the shale gas extraction.

Development of a primary diffusion source of organic vapors for gas analyzer calibration

NASA Astrophysics Data System (ADS)

Lecuna, M.; Demichelis, A.; Sassi, G.; Sassi, M. P.

2018-03-01

The generation of reference mixtures of volatile organic compounds (VOCs) at trace levels (10 ppt-10 ppb) is a challenge for both environmental and clinical measurements. The calibration of gas analyzers for trace VOC measurements requires a stable and accurate source of the compound of interest. The dynamic preparation of gas mixtures by diffusion is a suitable method for fulfilling these requirements. The estimation of the uncertainty of the molar fraction of the VOC in the mixture is a key step in the metrological characterization of a dynamic generator. The performance of a dynamic generator was monitored over a wide range of operating conditions. The generation system was simulated by a model developed with computational fluid dynamics and validated against experimental data. The vapor pressure of the VOC was found to be one of the main contributors to the uncertainty of the diffusion rate and its influence at 10-70 kPa was analyzed and discussed. The air buoyancy effect and perturbations due to the weighing duration were studied. The gas carrier flow rate and the amount of liquid in the vial were found to play a role in limiting the diffusion rate. The results of sensitivity analyses were reported through an uncertainty budget for the diffusion rate. The roles of each influence quantity were discussed. A set of criteria to minimize the uncertainty contribution to the primary diffusion source (25 µg min-1) were estimated: carrier gas flow rate higher than 37.7 sml min-1, a maximum VOC liquid mass decrease in the vial of 4.8 g, a minimum residual mass of 1 g and vial weighing times of 1-3 min. With this procedure a limit uncertainty of 0.5% in the diffusion rate can be obtained for VOC mixtures at trace levels (10 ppt-10 ppb), making the developed diffusion vials a primary diffusion source with potential to become a new reference material for trace VOC analysis.

40 CFR 1065.330 - Exhaust-flow calibration.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Section 1065.330 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calibrations and Verifications Flow-Related Measurements § 1065.330... ultrasonic flow meter for raw exhaust flow measurement, we recommend that you calibrate it as described in...

Calibrating the Helium Pressurization System for the Space Shuttle Liquid-Hydrogen Tank

NASA Technical Reports Server (NTRS)

2008-01-01

Analysis of the results from the STS-114 tanking tests and subsequent launch called into question existing thermal and mass models of helium pressurization of the liquid hydrogen tank. This hydrogen tank, which makes up the bottom two-thirds of the External Tank, is pressurized prior to launch to avoid cavitation in the Shuttle Main Engine pumps. At about 2 minutes prior to launch, the main vent valve is closed, and pressurized helium flows into the tank ullage space to achieve set point pressure. As the helium gas cools, its pressure drops, calling for additional helium. Subsequent helium flows are provided in short, timed pulses. The number of pulses is taken as a rough leak indicator. An analysis of thermal models by Marshall Space Flight Center showed considerable uncertainty in the pressure-versus-time behavior of the helium ullage space and the ability to predict the number of pulses normally expected. Kennedy Space Center proposed to calibrate the dime-sized orifice, which together with valves, controls the helium flow quantity (Figure 1). Pressure and temperature sensors were installed to provide upstream and downstream measurements necessary to compute flow rate based on the orifice discharge coefficient. An assessment of flow testing with helium indicated an extremely costly use of this critical resource. In order to reduce costs, we proposed removing the orifices from each Mobile Launcher Platform (MLP) and asking Colorado Engineering Experiment Station Inc. (CEESI) to calibrate the flow. CEESI has a high-pressure air flow system with traceable flow meters capable of handling the large flow rates. However, literature research indicated that square-edged orifices of small diameters often exhibit significant hysteresis and nonrepeatability in the vicinity of choked or sonic flow. Fortunately, the MLP orifices behaved relatively well in testing (Figure 2). Using curve fitting of the air-flow data, in conjunction with ASME orifice modeling equations, a method of relating the helium mass flow to measured air flow data was obtained. This analysis showed that the highest uncertainty in flow occurred in the vicinity of the choking pressure ratio, as would be expected. In addition, analysis of typical flow pulses showed that most of the helium flow occurred either well below or well above this uncertain area. The final result is the ability to provide postlaunch estimates of helium mass flows that are within 1.5 percent of the actual value.

Turbine blade and vane heat flux sensor development, phase 2

NASA Technical Reports Server (NTRS)

Atkinson, W. H.; Cyr, M. A.; Strange, R. R.

1985-01-01

The development of heat flux sensors for gas turbine blades and vanes and the demonstration of heat transfer measurement methods are reported. The performance of the heat flux sensors was evaluated in a cylinder in cross flow experiment and compared with two other heat flux measurement methods, the slug calorimeter and a dynamic method based on fluctuating gas and surface temperature. Two cylinders, each instrumented with an embedded thermocouple sensor, a Gardon gauge, and a slug calorimeter, were fabricated. Each sensor type was calibrated using a quartz lamp bank facility. The instrumented cylinders were then tested in an atmospheric pressure combustor rig at conditions up to gas stream temperatures of 1700K and velocities to Mach 0.74. The test data are compared to other measurements and analytical prediction.

High-temperature optical fiber instrumentation for gas flow monitoring in gas turbine engines

NASA Astrophysics Data System (ADS)

Roberts, Adrian; May, Russell G.; Pickrell, Gary R.; Wang, Anbo

2002-02-01

In the design and testing of gas turbine engines, real-time data about such physical variables as temperature, pressure and acoustics are of critical importance. The high temperature environment experienced in the engines makes conventional electronic sensors devices difficult to apply. Therefore, there is a need for innovative sensors that can reliably operate under the high temperature conditions and with the desirable resolution and frequency response. A fiber optic high temperature sensor system for dynamic pressure measurement is presented in this paper. This sensor is based on a new sensor technology - the self-calibrated interferometric/intensity-based (SCIIB) sensor, recently developed at Virginia Tech. State-of-the-art digital signal processing (DSP) methods are applied to process the signal from the sensor to acquire high-speed frequency response.

Temperature and Structure of Active Eruptions from a Handheld Camcorder

NASA Astrophysics Data System (ADS)

Radebaugh, Jani; Carling, Greg T.; Saito, Takeshi; Dangerfield, Anne; Tingey, David G.; Lorenz, Ralph D.; Lopes, Rosaly M.; Howell, Robert R.; Diniega, Serina; Turtle, Elizabeth P.

2014-11-01

A commercial handheld digital camcorder can operate as a high-resolution, short-wavelength, low-cost thermal imaging system for monitoring active volcanoes, when calibrated against a laboratory heated rock of similar composition to the given eruptive material. We utilize this system to find full pixel brightness temperatures on centimeter scales at close but safe proximity to active lava flows. With it, observed temperatures of a Kilauea tube flow exposed in a skylight reached 1200 C, compared with pyrometer measurements of the same flow of 1165 C, both similar to reported eruption temperatures at that volcano. The lava lake at Erta Ale, Ethiopia had crack and fountain temperatures of 1175 C compared with previous pyrometer measurements of 1165 C. Temperature calibration of the vigorously active Marum lava lake in Vanuatu is underway, challenges being excessive levels of gas and distance from the eruption (300 m). Other aspects of the fine-scale structure of the eruptions are visible in the high-resolution temperature maps, such as flow banding within tubes, the thermal gradient away from cracks in lake surfaces, heat pathways through pahoehoe crust and temperature zoning in spatter and fountains. High-resolution measurements such as these reveal details of temperature, structure, and change over time at the rapidly evolving settings of active lava flows. These measurement capabilities are desirable for future instruments exploring bodies with active eruptions like Io, Enceladus and possibly Venus.

The structure of evaporating and combusting sprays: Measurements and predictions

NASA Technical Reports Server (NTRS)

Shuen, J. S.; Solomon, A. S. P.; Faeth, G. M.

1984-01-01

An apparatus developed, to allow observations of monodisperse sprays, consists of a methane-fueled turbulent jet diffusion flame with monodisperse methanol drops injected at the burner exit. Mean and fluctuating-phase velocities, drop sizes, drop-mass fluxes and mean-gas temperatures were measured. Initial drop diameters of 100 and 180 microns are being considered in order to vary drop penetration in the flow and effects of turbulent dispersion. Baseline tests of the burner flame with no drops present were also conducted. Calibration tests, needed to establish methods for predicting drop transport, involve drops supported in the post-flame region of a flat-flame burner operated at various mixture ratios. Spray models which are being evaluated include: (1) locally homogeneous flow (LFH) analysis, (2) deterministic separated flow (DSF) analysis and (3) stochastic separated flow (SSF) analysis.

Linearization of calibration curves by aerosol carrier effect of CCl 4 vapor in electrothermal vaporization inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Kántor, Tibor; de Loos-Vollebregt, Margaretha T. C.

2005-03-01

Carbon tetrachloride vapor as gaseous phase modifier in a graphite furnace electrothermal vaporizer (GFETV) converts heavy volatile analyte forms to volatile and medium volatile chlorides and produces aerosol carrier effect, the latter being a less generally recognized benefit. However, the possible increase of polyatomic interferences in inductively coupled plasma mass spectrometry (GFETV-ICP-MS) by chlorine and carbon containing species due to CCl 4 vapor introduction has been discouraging with the use of low resolution, quadrupole type MS equipment. Being aware of this possible handicap, it was aimed at to investigate the feasibility of the use of this halogenating agent in ICP-MS with regard of possible hazards to the instrument, and also to explore the advantages under these specific conditions. With sample gas flow (inner gas flow) rate not higher than 900 ml min -1 Ar in the torch and 3 ml min -1 CCl 4 vapor flow rate in the furnace, the long-term stability of the instrument was ensured and the following benefits by the halocarbon were observed. The non-linearity error (defined in the text) of the calibration curves (signal versus mass functions) with matrix-free solution standards was 30-70% without, and 1-5% with CCl 4 vapor introduction, respectively, at 1 ng mass of Cu, Fe, Mn and Pb analytes. The sensitivity for these elements increased by 2-4-fold with chlorination, while the relative standard deviation (RSD) was essentially the same (2-5%) for the two cases in comparison. A vaporization temperature of 2650 °C was required for Cr in Ar atmosphere, while 2200 °C was sufficient in Ar + CCl 4 atmosphere to attain complete vaporization. Improvements in linear response and sensitivity were the highest for this least volatile element. The pyrolytic graphite layer inside the graphite tube was protected by the halocarbon, and tube life time was further increased by using traces of hydrocarbon vapor in the external sheath gas of the graphite furnace. Details of the modification of the gas supply for HGA-600MS furnace and the design of the volatilization device are described.

Methods to produce calibration mixtures for anesthetic gas monitors and how to perform volumetric calculations on anesthetic gases.

PubMed

Christensen, P L; Nielsen, J; Kann, T

1992-10-01

A simple procedure for making calibration mixtures of oxygen and the anesthetic gases isoflurane, enflurane, and halothane is described. One to ten grams of the anesthetic substance is evaporated in a closed, 11,361-cc glass bottle filled with oxygen gas at atmospheric pressure. The carefully mixed gas is used to calibrate anesthetic gas monitors. By comparison of calculated and measured volumetric results it is shown that at atmospheric conditions the volumetric behavior of anesthetic gas mixtures can be described with reasonable accuracy using the ideal gas law. A procedure is described for calculating the deviation from ideal gas behavior in cases in which this is needed.

FlowCal: A user-friendly, open source software tool for automatically converting flow cytometry data from arbitrary to calibrated units

PubMed Central

Castillo-Hair, Sebastian M.; Sexton, John T.; Landry, Brian P.; Olson, Evan J.; Igoshin, Oleg A.; Tabor, Jeffrey J.

2017-01-01

Flow cytometry is widely used to measure gene expression and other molecular biological processes with single cell resolution via fluorescent probes. Flow cytometers output data in arbitrary units (a.u.) that vary with the probe, instrument, and settings. Arbitrary units can be converted to the calibrated unit molecules of equivalent fluorophore (MEF) using commercially available calibration particles. However, there is no convenient, non-proprietary tool available to perform this calibration. Consequently, most researchers report data in a.u., limiting interpretation. Here, we report a software tool named FlowCal to overcome current limitations. FlowCal can be run using an intuitive Microsoft Excel interface, or customizable Python scripts. The software accepts Flow Cytometry Standard (FCS) files as inputs and is compatible with different calibration particles, fluorescent probes, and cell types. Additionally, FlowCal automatically gates data, calculates common statistics, and produces publication quality plots. We validate FlowCal by calibrating a.u. measurements of E. coli expressing superfolder GFP (sfGFP) collected at 10 different detector sensitivity (gain) settings to a single MEF value. Additionally, we reduce day-to-day variability in replicate E. coli sfGFP expression measurements due to instrument drift by 33%, and calibrate S. cerevisiae mVenus expression data to MEF units. Finally, we demonstrate a simple method for using FlowCal to calibrate fluorescence units across different cytometers. FlowCal should ease the quantitative analysis of flow cytometry data within and across laboratories and facilitate the adoption of standard fluorescence units in synthetic biology and beyond. PMID:27110723

Design and Calibration of a Flush Air Data System (FADS) for Prediction of the Atmospheric Properties During Re-Entry

DTIC Science & Technology

2013-01-01

was obtained by solving Vibrational-Translational Energy Transfer and energy conservation equations for the Longshot nozzle geometry. Compared to the...temperature 1-D solver A gas in the process of being slowed down is heated due to the kinetic energy of flow. The amount of the heating depends on...release; distribution is unlimited. 8 ( ) ( ) Where the total energy E equals the internal energy plus a kinetic

Microwave plasma monitoring system for the elemental composition analysis of high temperature process streams

DOEpatents

Woskov, Paul P.; Cohn, Daniel R.; Titus, Charles H.; Surma, Jeffrey E.

1997-01-01

Microwave-induced plasma for continuous, real time trace element monitoring under harsh and variable conditions. The sensor includes a source of high power microwave energy and a shorted waveguide made of a microwave conductive, high temperature capability refractory material communicating with the source of the microwave energy to generate a plasma. The high power waveguide is constructed to be robust in a hot, hostile environment. It includes an aperture for the passage of gases to be analyzed and a spectrometer is connected to receive light from the plasma. Provision is made for real time in situ calibration. The spectrometer disperses the light, which is then analyzed by a computer. The sensor is capable of making continuous, real time quantitative measurements of desired elements, such as the heavy metals lead and mercury. The invention may be incorporated into a high temperature process device and implemented in situ for example, such as with a DC graphite electrode plasma arc furnace. The invention further provides a system for the elemental analysis of process streams by removing particulate and/or droplet samples therefrom and entraining such samples in the gas flow which passes through the plasma flame. Introduction of and entraining samples in the gas flow may be facilitated by a suction pump, regulating gas flow, gravity or combinations thereof.

VETA-1 x ray detection system

NASA Technical Reports Server (NTRS)

Podgorski, W. A.; Flanagan, Kathy A.; Freeman, Mark D.; Goddard, R. G.; Kellogg, Edwin M.; Norton, T. J.; Ouellette, J. P.; Roy, A. G.; Schwartz, Daniel A.

1992-01-01

The alignment and X-ray imaging performance of the Advanced X-ray Astrophysics Facility (AXAF) Verification Engineering Test Article-I (VETA-I) was measured by the VETA-I X-Ray Detection System (VXDS). The VXDS was based on the X-ray detection system utilized in the AXAF Technology Mirror Assembly (TMA) program, upgraded to meet the more stringent requirements of the VETA-I test program. The VXDS includes two types of X-ray detectors: (1) a High Resolution Imager (HRI) which provides X-ray imaging capabilities, and (2) sealed and flow proportional counters which, in conjunction with apertures of various types and precision translation stages, provide the most accurate measurement of VETA-I performance. Herein we give an overview of the VXDS hardware including X-ray detectors, translation stages, apertures, proportional counters and flow counter gas supply system and associated electronics. We also describe the installation of the VXDS into the Marshall Space Flight Center (MSFC) X-Ray Calibration Facility (XRCF). We discuss in detail the design and performance of those elements of the VXDS which have not been discussed elsewhere; translation systems, flow counter gas supply system, apertures and thermal monitoring system.

Oxygen-Mass-Flow Calibration Cell

NASA Technical Reports Server (NTRS)

Martin, Robert E.

1996-01-01

Proposed calibration standard for mass flow rate of oxygen based on conduction of oxygen ions through solid electrolyte membrane made of zirconia and heated to temperature of 1,000 degrees C. Flow of oxygen ions proportional to applied electric current. Unaffected by variations in temperature and pressure, and requires no measurement of volume. Calibration cell based on concept used to calibrate variety of medical and scientific instruments required to operate with precise rates of flow of oxygen.

Broadband spectroscopic sensor for real-time monitoring of industrial SO(2) emissions.

PubMed

Xu, Feng; Zhang, Yungang; Somesfalean, Gabriel; Wang, Huashan; Wu, Shaohua; Zhang, Zhiguo

2007-05-01

A spectroscopic system for continuous real-time monitoring of SO(2) concentrations in industrial emissions was developed. The sensor is well suited for field applications due to simple and compact instrumental design, and robust data evaluation based on ultraviolet broadband absorption without the use of any calibration cell. The sensor has a detection limit of 1 ppm, and was employed both for gas-flow simulations with and without suspended particles, and for in situ measurement of SO(2) concentrations in the flue gas emitted from an industrial coal-fired boiler. The price/performance ratio of the instrument is expected to be superior to other comparable real-time monitoring systems.

Dry calibration of electromagnetic flowmeters based on numerical models combining multiple physical phenomena (multiphysics)

NASA Astrophysics Data System (ADS)

Fu, X.; Hu, L.; Lee, K. M.; Zou, J.; Ruan, X. D.; Yang, H. Y.

2010-10-01

This paper presents a method for dry calibration of an electromagnetic flowmeter (EMF). This method, which determines the voltage induced in the EMF as conductive liquid flows through a magnetic field, numerically solves a coupled set of multiphysical equations with measured boundary conditions for the magnetic, electric, and flow fields in the measuring pipe of the flowmeter. Specifically, this paper details the formulation of dry calibration and an efficient algorithm (that adaptively minimizes the number of measurements and requires only the normal component of the magnetic flux density as boundary conditions on the pipe surface to reconstruct the magnetic field involved) for computing the sensitivity of EMF. Along with an in-depth discussion on factors that could significantly affect the final precision of a dry calibrated EMF, the effects of flow disturbance on measuring errors have been experimentally studied by installing a baffle at the inflow port of the EMF. Results of the dry calibration on an actual EMF were compared against flow-rig calibration; excellent agreements (within 0.3%) between dry calibration and flow-rig tests verify the multiphysical computation of the fields and the robustness of the method. As requiring no actual flow, the dry calibration is particularly useful for calibrating large-diameter EMFs where conventional flow-rig methods are often costly and difficult to implement.

Calibration of CORSIM models under saturated traffic flow conditions.

DOT National Transportation Integrated Search

2013-09-01

This study proposes a methodology to calibrate microscopic traffic flow simulation models. : The proposed methodology has the capability to calibrate simultaneously all the calibration : parameters as well as demand patterns for any network topology....

Using chromatography – desorption method of manufacturing gas mixtures for analytical instruments calibration

NASA Astrophysics Data System (ADS)

Platonov, I. A.; Kolesnichenko, I. N.; Lange, P. K.

2018-05-01

In this paper, the chromatography desorption method of obtaining gas mixtures of known compositions stable for a time sufficient to calibrate analytical instruments is considered. The comparative analysis results of the preparation accuracy of gas mixtures with volatile organic compounds using diffusion, polyabarbotage and chromatography desorption methods are presented. It is shown that the application of chromatography desorption devices allows one to obtain gas mixtures that are stable for 10...60 hours in a dynamic condition. These gas mixtures contain volatile aliphatic and aromatic hydrocarbons with a concentration error of no more than 7%. It is shown that it is expedient to use such gas mixtures for analytical instruments calibration (chromatographs, spectrophotometers, etc.)

Vapor phase tri-methyl-indium seeding system suitable for high temperature spectroscopy and thermometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whiddon, R.; Zhou, B.; Borggren, J.

2015-09-15

Tri-methyl-indium (TMI) is used as an indium transport molecule to introduce indium atoms to reactive hot gas flows/combustion environments for spectroscopic diagnostics. A seeding system was constructed to allow the addition of an inert TMI laden carrier gas into an air/fuel mixture burning consequently on a burner. The amount of the seeded TMI in the carrier gas can be readily varied by controlling the vapor pressure through the temperature of the container. The seeding process was calibrated using the fluorescent emission intensity from the indium 6{sup 2}S{sub 1/2} → 5{sup 2}P{sub 1/2} and 6{sup 2}S{sub 1/2} → 5{sup 2}P{sub 3/2}more » transitions as a function of the calculated TMI seeding concentration over a range of 2–45 ppm. The response was found to be linear over the range 3–22.5 ppm; at concentrations above 25 ppm there is a loss of linearity attributable to self-absorption or loss of saturation of TMI vapor pressure in the carrier gas flow. When TMI was introduced into a post-combustion environment via an inert carrier gas, molecular transition from InH and InOH radicals were observed in the flame emission spectrum. Combined laser-induced fluorescence and absorption spectroscopy were applied to detect indium atoms in the TMI seeded flame and the measured atomic indium concentration was found to be at the ppm level. This method of seeding organometallic vapor like TMI to a reactive gas flow demonstrates the feasibility for quantitative spectroscopic investigations that may be applicable in various fields, e.g., chemical vapor deposition applications or temperature measurement in flames with two-line atomic fluorescence.« less

Multi-metric calibration of hydrological model to capture overall flow regimes

NASA Astrophysics Data System (ADS)

Zhang, Yongyong; Shao, Quanxi; Zhang, Shifeng; Zhai, Xiaoyan; She, Dunxian

2016-08-01

Flow regimes (e.g., magnitude, frequency, variation, duration, timing and rating of change) play a critical role in water supply and flood control, environmental processes, as well as biodiversity and life history patterns in the aquatic ecosystem. The traditional flow magnitude-oriented calibration of hydrological model was usually inadequate to well capture all the characteristics of observed flow regimes. In this study, we simulated multiple flow regime metrics simultaneously by coupling a distributed hydrological model with an equally weighted multi-objective optimization algorithm. Two headwater watersheds in the arid Hexi Corridor were selected for the case study. Sixteen metrics were selected as optimization objectives, which could represent the major characteristics of flow regimes. Model performance was compared with that of the single objective calibration. Results showed that most metrics were better simulated by the multi-objective approach than those of the single objective calibration, especially the low and high flow magnitudes, frequency and variation, duration, maximum flow timing and rating. However, the model performance of middle flow magnitude was not significantly improved because this metric was usually well captured by single objective calibration. The timing of minimum flow was poorly predicted by both the multi-metric and single calibrations due to the uncertainties in model structure and input data. The sensitive parameter values of the hydrological model changed remarkably and the simulated hydrological processes by the multi-metric calibration became more reliable, because more flow characteristics were considered. The study is expected to provide more detailed flow information by hydrological simulation for the integrated water resources management, and to improve the simulation performances of overall flow regimes.

EPA Protocol Gas Verification Program - Presented at NIST Gas Panel Meeting

EPA Science Inventory

Accurate compressed gas calibration standards are needed to calibrate continuous emission monitors (CEMs) and ambient air quality monitors that are being used for regulatory purposes. US Environmental Protection Agency (EPA) established its traceability protocol to ensure that c...

40 CFR Appendix A to Part 75 - Specifications and Test Procedures

Code of Federal Regulations, 2010 CFR

2010-07-01

... from the National Technical Information Service, 5285 Port Royal Road, Springfield, VA, 703-605-6585 or... specified in section 5.2 of this appendix. Introduce the calibration gas at the gas injection port, as... 5.1 of this appendix. Introduce the calibration gas at the gas injection port, as specified in...

In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy

DOEpatents

Braymen, Steven D.

1996-06-11

A method and apparatus for in situ addition calibration of an inductively coupled plasma atomic emission spectrometer or mass spectrometer using a precision gas metering valve to introduce a volatile calibration gas of an element of interest directly into an aerosol particle stream. The present situ calibration technique is suitable for various remote, on-site sampling systems such as laser ablation or nebulization.

Chevron facility focused on commercial orifice-meter research

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, E.H.; Ferguson, K.R.

1987-07-27

Research to determine the accuracy of commercial orifice meters for custody-transfer measurement has indicated that high-volume gas meters can be flow-proven while in such service. The research further yielded more accurate orifice-meter discharge coefficient equations (at Reynolds numbers greater than 4,000,000) than current equations of the International Standards Organization (ISO) and the American Petroleum Institute (API). These are partial findings of a major study conducted by Chevron Oil Field Research Co. at its Venice, La., calibration facility.

Real-time monitoring of volatile organic compounds using chemical ionization mass spectrometry

DOEpatents

Mowry, Curtis Dale; Thornberg, Steven Michael

1999-01-01

A system for on-line quantitative monitoring of volatile organic compounds (VOCs) includes pressure reduction means for carrying a gaseous sample from a first location to a measuring input location maintained at a low pressure, the system utilizing active feedback to keep both the vapor flow and pressure to a chemical ionization mode mass spectrometer constant. A multiple input manifold for VOC and gas distribution permits a combination of calibration gases or samples to be applied to the spectrometer.

Calibration of the Flow in the Test Section of the Research Wind Tunnel at DST Group

DTIC Science & Technology

2015-10-01

calibration of the flow in the test section of the Research Wind Tunnel at DST Group. The calibration was performed to establish the flow quality and to...of the Flow in the Test Section of the Research Wind Tunnel at DST Group Executive Summary The Defence Science and Technology Group (DST

The NASA Langley Research Center 0.3-meter transonic cryogenic tunnel T-P/Re-M controller manual

NASA Technical Reports Server (NTRS)

Balakrishna, S.; Kilgore, W. Allen

1989-01-01

A new microcomputer based controller for the 0.3-m Transonic Cryogenic Tunnel (TCT) has been commissioned in 1988 and has reliably operated for more than a year. The tunnel stagnation pressure, gas stagnation temperature, tunnel wall structural temperature and flow Mach number are precisely controlled by the new controller in a stable manner. The tunnel control hardware, software, and the flow chart to assist in calibration of the sensors, actuators, and the controller real time functions are described. The software installation details are also presented. The report serves as the maintenance and trouble shooting manual for the 0.3-m TCT controller.

Gas Flow Detection System

NASA Technical Reports Server (NTRS)

Moss, Thomas; Ihlefeld, Curtis; Slack, Barry

2010-01-01

This system provides a portable means to detect gas flow through a thin-walled tube without breaking into the tubing system. The flow detection system was specifically designed to detect flow through two parallel branches of a manifold with only one inlet and outlet, and is a means for verifying a space shuttle program requirement that saves time and reduces the risk of flight hardware damage compared to the current means of requirement verification. The prototype Purge Vent and Drain Window Cavity Conditioning System (PVD WCCS) Flow Detection System consists of a heater and a temperature-sensing thermistor attached to a piece of Velcro to be attached to each branch of a WCCS manifold for the duration of the requirement verification test. The heaters and thermistors are connected to a shielded cable and then to an electronics enclosure, which contains the power supplies, relays, and circuit board to provide power, signal conditioning, and control. The electronics enclosure is then connected to a commercial data acquisition box to provide analog to digital conversion as well as digital control. This data acquisition box is then connected to a commercial laptop running a custom application created using National Instruments LabVIEW. The operation of the PVD WCCS Flow Detection System consists of first attaching a heater/thermistor assembly to each of the two branches of one manifold while there is no flow through the manifold. Next, the software application running on the laptop is used to turn on the heaters and to monitor the manifold branch temperatures. When the system has reached thermal equilibrium, the software application s graphical user interface (GUI) will indicate that the branch temperatures are stable. The operator can then physically open the flow control valve to initiate the test flow of gaseous nitrogen (GN2) through the manifold. Next, the software user interface will be monitored for stable temperature indications when the system is again at thermal equilibrium with the test flow of GN2. The temperature drop of each branch from its "no flow" stable temperature peak to its stable "with flow" temperature will allow the operator to determine whether a minimum level of flow exists. An alternative operation has the operator turning on the software only long enough to record the ambient temperature of the tubing before turning on the heaters and initiating GN2 flow. The stable temperature of the heated tubing with GN2 flow is then compared with the ambient tubing temperature to determine if flow is present in each branch. To help quantify the level of flow in the manifolds, each branch will be bench calibrated to establish its thermal properties using the flow detection system and different flow rates. These calibration values can then be incorporated into the software application to provide more detailed flow rate information.

Nicotine, acetanilide and urea multi-level2H-,13C- and15N-abundance reference materials for continuous-flow isotope ratio mass spectrometry

USGS Publications Warehouse

Schimmelmann, A.; Albertino, A.; Sauer, P.E.; Qi, H.; Molinie, R.; Mesnard, F.

2009-01-01

Accurate determinations of stable isotope ratios require a calibration using at least two reference materials with different isotopic compositions to anchor the isotopic scale and compensate for differences in machine slope. Ideally, the S values of these reference materials should bracket the isotopic range of samples with unknown S values. While the practice of analyzing two isotopically distinct reference materials is common for water (VSMOW-SLAP) and carbonates (NBS 19 and L-SVEC), the lack of widely available organic reference materials with distinct isotopic composition has hindered the practice when analyzing organic materials by elemental analysis/isotope ratio mass spectrometry (EA-IRMS). At present only L-glutamic acids USGS40 and USGS41 satisfy these requirements for ??13C and ??13N, with the limitation that L-glutamic acid is not suitable for analysis by gas chromatography (GC). We describe the development and quality testing of (i) four nicotine laboratory reference materials for on-line (i.e. continuous flow) hydrogen reductive gas chromatography-isotope ratio mass-spectrometry (GC-IRMS), (ii) five nicotines for oxidative C, N gas chromatography-combustion-isotope ratio mass-spectrometry (GC-C-IRMS, or GC-IRMS), and (iii) also three acetanilide and three urea reference materials for on-line oxidative EA-IRMS for C and N. Isotopic off-line calibration against international stable isotope measurement standards at Indiana University adhered to the 'principle of identical treatment'. The new reference materials cover the following isotopic ranges: ??2Hnicotine -162 to -45%o, ??13Cnicotine -30.05 to +7.72%, ?? 15Nnicotine -6.03 to +33.62%; ??15N acetanilide +1-18 to +40.57%; ??13Curea -34.13 to +11.71%, ??15Nurea +0.26 to +40.61% (recommended ?? values refer to calibration with NBS 19, L-SVEC, IAEA-N-1, and IAEA-N-2). Nicotines fill a gap as the first organic nitrogen stable isotope reference materials for GC-IRMS that are available with different ??13N values. Comparative ??13C and ??15N on-line EA-IRMS data from 14 volunteering laboratories document the usefulness and reliability of acetanilides and ureas as EA-IRMS reference materials.

Beat frequency quartz-enhanced photoacoustic spectroscopy for fast and calibration-free continuous trace-gas monitoring

PubMed Central

Wu, Hongpeng; Dong, Lei; Zheng, Huadan; Yu, Yajun; Ma, Weiguang; Zhang, Lei; Yin, Wangbao; Xiao, Liantuan; Jia, Suotang; Tittel, Frank K.

2017-01-01

Quartz-enhanced photoacoustic spectroscopy (QEPAS) is a sensitive gas detection technique which requires frequent calibration and has a long response time. Here we report beat frequency (BF) QEPAS that can be used for ultra-sensitive calibration-free trace-gas detection and fast spectral scan applications. The resonance frequency and Q-factor of the quartz tuning fork (QTF) as well as the trace-gas concentration can be obtained simultaneously by detecting the beat frequency signal generated when the transient response signal of the QTF is demodulated at its non-resonance frequency. Hence, BF-QEPAS avoids a calibration process and permits continuous monitoring of a targeted trace gas. Three semiconductor lasers were selected as the excitation source to verify the performance of the BF-QEPAS technique. The BF-QEPAS method is capable of measuring lower trace-gas concentration levels with shorter averaging times as compared to conventional PAS and QEPAS techniques and determines the electrical QTF parameters precisely. PMID:28561065

Preserving Flow Variability in Watershed Model Calibrations

EPA Science Inventory

Background/Question/Methods Although watershed modeling flow calibration techniques often emphasize a specific flow mode, ecological conditions that depend on flow-ecology relationships often emphasize a range of flow conditions. We used informal likelihood methods to investig...

Variable leak gas source

DOEpatents

Henderson, Timothy M.; Wuttke, Gilbert H.

1977-01-01

A variable leak gas source and a method for obtaining the same which includes filling a quantity of hollow glass micro-spheres with a gas, storing said quantity in a confined chamber having a controllable outlet, heating said chamber above room temperature, and controlling the temperature of said chamber to control the quantity of gas passing out of said controllable outlet. Individual gas filled spheres may be utilized for calibration purposes by breaking a sphere having a known quantity of a known gas to calibrate a gas detection apparatus.

A novel explicit equation for the friction factor prediction in the annular flow with drag-reducing polymer

NASA Astrophysics Data System (ADS)

Lakzian, Esmail; Masoudifar, Amir; Saghi, Hassan

2017-03-01

In this paper, a novel explicit equation is presented for the friction factor prediction in the annular flow with drag reducing polymer (DRP). By using dimensional analyses and curve fitting on the published experimental data, the suggested equation is derived based on the logarithmic velocity profiles and power law in boundary layers. In the next step, a least squares method is used to calibrate the presented equation. Then, the equation is used to friction factor prediction of the gas-liquid mixture with DRP and the results are compared with the experimental data and the Al-Sarkhi ones. Finally, drag reduction (DR) is applied as the ratio of the friction factor reduction using DRP to the friction factor without DRP. The DR results show that the suggested equation has a better agreement with the experimental data in comparison with the pervious equations. The results also show that DR prediction decreases with the increase of the gas superficial velocity.

Measurements of Flow Turbulence in the NASA Langley Transonic Dynamics Tunnel

NASA Technical Reports Server (NTRS)

Wiesman, Carol D.; Sleeper, Robert K.

2005-01-01

An assessment of the flow turbulence in the NASA Langley Transonic Dynamics Tunnel (TDT) was conducted during calibration activities following the facility conversion from a Freon-12 heavy-gas test medium to an R134a heavy-gas test medium. Total pressure, static pressure, and acoustic pressure levels were measured at several locations on a stingmounted rake. The test measured wall static pressures at several locations although this paper presents only those from one location. The test used two data acquisition systems, one sampling at 1000 Hz and the second sampling at 125 000 Hz, for acquiring time-domain data. This paper presents standard deviations and power spectral densities of the turbulence points throughout the wind tunnel envelope in air and R134a. The objective of this paper is to present the turbulence characteristics for the test section. No attempt is made to assess the causes of the turbulence. The present paper looks at turbulence in terms of pressure fluctuations. Reference 1 looked at tunnel turbulence in terms of velocity fluctuations.

The Development of a Gas–Liquid Two-Phase Flow Sensor Applicable to CBM Wellbore Annulus

PubMed Central

Wu, Chuan; Wen, Guojun; Han, Lei; Wu, Xiaoming

2016-01-01

The measurement of wellbore annulus gas–liquid two-phase flow in CBM (coalbed methane) wells is of great significance for reasonably developing gas drainage and extraction processes, estimating CBM output, judging the operating conditions of CBM wells and analyzing stratum conditions. Hence, a specially designed sensor is urgently needed for real-time measurement of gas–liquid two-phase flow in CBM wellbore annulus. Existing flow sensors fail to meet the requirements of the operating conditions of CBM wellbore annulus due to such factors as an inapplicable measurement principle, larger size, poor sealability, high installation accuracy, and higher requirements for fluid media. Therefore, based on the principle of a target flowmeter, this paper designs a new two-phase flow sensor that can identify and automatically calibrate different flow patterns of two-phase flows. Upon the successful development of the new flow sensor, lab and field tests were carried out, and the results show that the newly designed sensor, with a measurement accuracy of ±2.5%, can adapt to the operating conditions of CBM wells and is reliable for long-term work. PMID:27869708

Eddy Covariance measurements of stable isotopes (δD and δ18O) in water vapor

NASA Astrophysics Data System (ADS)

Braden-Behrens, J.; Knohl, A.

2016-12-01

Stable isotopes are a promising tool to enhance our understanding of ecosystem gas exchanges. Studying 18O and 2H (D) in water vapour (H2Ov) can e.g. help partitioning evapotranspiration into its components. With recent developments in laser spectroscopy direct Eddy Covariance (EC) measurements to investigate fluxes of stable isotopologues became feasible. But so far only very few case studies applying the EC method to stable isotopes in water vapor have been carried out worldwide At our micrometeorological EC tower in a managed beech forest in Thuringia, Germany, we continuously measure fluxes of water vapor isotopologues using EC since autumn 2015. The set-up is based on an off-axis cavity output water vapor isotope analyzer (WVIA, Los Gatos Research. Inc, USA) that measures the water vapour concentration and its isotopic composition (δD and δ18O). The instrument is optimized for high flow rates (app. 4slpm) to generate high frequent (2Hz) measurements. The HF-optimized WVIA showed sufficient precision with a minimal Allan Deviation of 0.023 ‰ for δD and 0.02 ‰ for δ18O for averaging periods of app. 700 s and 400 s resp. The instrument is calibrated hourly using a high-flow optimized version of the water vapor isotope standard source (WVISS, Los Gatos Research. Inc, USA) that provides water vapor with known isotopic composition for a large range of different concentrations. Our calibration scheme includes a near continuous concentration range calibration instead of a simple 2 or 3-point calibration to face the analyzers large concentration dependency within a range of app. 6 000 to 16 000 ppm in winter and app. 8 000 to 23 000 ppm in summer. We evaluate the calibration approach, present specific aspects of the set-up such as the HF optimization and compare the measured and averaged spectra and cospectra of the isotopologue analyzer with those of the longterm EC installation (using a LI-6262 as well as a LI-7200 infrared gas analyzer at 10 Hz). Furthermore, we show results for the isotopologue fluxes before and after leaf unfolding in spring/summer 2016. This novel instrument for EC measurements of water vapor isotopologues provides a new exciting opportunity for studying the hydrological cycle in long-term observation networks like Ameriflux and ICOS.

Flow through electrode with automated calibration

DOEpatents

Szecsody, James E [Richland, WA; Williams, Mark D [Richland, WA; Vermeul, Vince R [Richland, WA

2002-08-20

The present invention is an improved automated flow through electrode liquid monitoring system. The automated system has a sample inlet to a sample pump, a sample outlet from the sample pump to at least one flow through electrode with a waste port. At least one computer controls the sample pump and records data from the at least one flow through electrode for a liquid sample. The improvement relies upon (a) at least one source of a calibration sample connected to (b) an injection valve connected to said sample outlet and connected to said source, said injection valve further connected to said at least one flow through electrode, wherein said injection valve is controlled by said computer to select between said liquid sample or said calibration sample. Advantages include improved accuracy because of more frequent calibrations, no additional labor for calibration, no need to remove the flow through electrode(s), and minimal interruption of sampling.

In vitro validation of a Pitot-based flow meter for the measurement of respiratory volume and flow in large animal anaesthesia.

PubMed

Moens, Yves P S; Gootjes, Peter; Ionita, Jean-Claude; Heinonen, Erkki; Schatzmann, Urs

2009-05-01

To remodel and validate commercially available monitors and their Pitot tube-based flow sensors for use in large animals, using in vitro techniques. Prospective, in vitro experiment. Both the original and the remodelled sensor were studied with a reference flow generator. Measurements were taken of the static flow-pressure relationship and linearity of the flow signal. Sensor airway resistance was calculated. Following recalibration of the host monitor, volumes ranging from 1 to 7 L were generated by a calibration syringe, and bias and precision of spirometric volume was determined. Where manual recalibration was not available, a conversion factor for volume measurement was determined. The influence of gas composition mixture and peak flow on the conversion factor was studied. Both the original and the remodelled sensor showed similar static flow-pressure relationships and linearity of the flow signal. Mean bias (%) of displayed values compared with the reference volume of 3, 5 and 7 L varied between -0.4% and +2.4%, and this was significantly smaller than that for 1 L (4.8% to +5.0%). Conversion factors for 3, 5 and 7 L were very similar (mean 6.00 +/- 0.2, range 5.91-6.06) and were not significantly influenced by the gas mixture used. Increasing peak flow caused a small decrease in the conversion factor. Volume measurement error and conversion factors for inspiration and expiration were close to identity. The combination of the host monitor with the remodelled flow sensor allowed accurate in vitro measurement of flows and volumes in a range expected during large animal anaesthesia. This combination has potential as a reliable spirometric monitor for use during large animal anaesthesia.

Lurking systematics in dust-based estimates of galaxy ISM masses

NASA Astrophysics Data System (ADS)

Janowiecki, Steven; Cortese, Luca; Catinella, Barbara; Goodwin, Adelle

2018-01-01

We use galaxies from the Herschel Reference Survey to evaluate commonly used indirect predictors of cold gas masses. With observations of cold neutral atomic and molecular gas, we calibrate predictive relationships using infrared dust emission and gas depletion time methods. We derive a set of self-consistent predictions of cold gas masses with ~20% scatter, and the greatest accuracy for total cold gas mass. However, significant systematic residuals are found in all calibrations which depend strongly on the molecular-to-atomic hydrogen mass ratio, and they can over/under-predict gas masses by >0.5 dex. Extending these types of indirect predictions to high-z galaxies (e.g., using ALMA observations of dust continuum to determine gas masses) requires implicit assumptions about the conditions in their interstellar medium. Any scaling relations derived using predicted gas masses may be more closely related to the calibrations used than to the actual galaxies observed.

In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy

DOEpatents

Braymen, S.D.

1996-06-11

A method and apparatus are disclosed for in situ addition calibration of an inductively coupled plasma atomic emission spectrometer or mass spectrometer using a precision gas metering valve to introduce a volatile calibration gas of an element of interest directly into an aerosol particle stream. The present in situ calibration technique is suitable for various remote, on-site sampling systems such as laser ablation or nebulization. 5 figs.

40 CFR 86.1221-90 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2012 CFR

2012-07-01

... methane. When the FID analyzer to be used for the analysis of natural gas-fueled vehicle hydrocarbon... and liquefied petroleum gas-fuel shall be optimized using propane. Analyzers used with natural gas... air (or methane in air as appropriate) calibration gases having nominal concentrations of 15, 30, 45...

40 CFR 86.1221-90 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2013 CFR

2013-07-01

... methane. When the FID analyzer to be used for the analysis of natural gas-fueled vehicle hydrocarbon... and liquefied petroleum gas-fuel shall be optimized using propane. Analyzers used with natural gas... air (or methane in air as appropriate) calibration gases having nominal concentrations of 15, 30, 45...

Glass-on-Glass Fabrication of Bottle-Shaped Tunable Microlasers and their Applications

PubMed Central

Ward, Jonathan M.; Yang, Yong; Nic Chormaic, Síle

2016-01-01

We describe a novel method for making microbottle-shaped lasers by using a CO2 laser to melt Er:Yb glass onto silica microcapillaries or fibres. This is realised by the fact that the two glasses have different melting points. The CO2 laser power is controlled to flow the doped glass around the silica cylinder. In the case of a capillary, the resulting geometry is a hollow, microbottle-shaped resonator. This is a simple method for fabricating a number of glass whispering gallery mode (WGM) lasers with a wide range of sizes on a single, micron-scale structure. The Er:Yb doped glass outer layer is pumped at 980 nm via a tapered optical fibre and WGM lasing is recorded around 1535 nm. This structure facilitates a new way to thermo-optically tune the microlaser modes by passing gas through the capillary. The cooling effect of the gas flow shifts the WGMs towards shorter wavelengths and thermal tuning of the lasing modes over 70 GHz is achieved. Results are fitted using the theory of hot wire anemometry, allowing the flow rate to be calibrated with a flow sensitivity as high as 72 GHz/sccm. Strain tuning of the microlaser modes by up to 60 GHz is also demonstrated. PMID:27121151

Nitric acid oxide mixing ratio measurements using a rocket launched chemiluminescent instrument

NASA Technical Reports Server (NTRS)

Horvath, Jack J.

1989-01-01

A total of 18 rocket launched parachute borne nitric oxide instruments were launched from 1977 to 1985. A very precise instrument for the measurement of the nitric oxide mixing ratio was fabricated. No changes were made in the main body of the instruments, i.e., things associated with the reaction volume. Except for the last 4 launches, however, it did not yield the required absolute values that was hoped for. Two major problems were encountered. First, the wrong choice of the background calibration gas, nitrogen, caused the first 10 data sets to be too low in the absolute mixing ratio by nearly the order of 2 to 5 ppbv. The error was realized, and air was substituted for the bias gas measurement. Second, in the desire to extend the measurement to higher altitudes, the problem of contaminating the inlet flow tube with ozone from the reagent gas was encountered. The ozone valve was opened too early in the flight and this caused the pressure in the reaction volume to exceed the pressure at the flow tube entrance, permitting the ozone to migrate backwards. This problem was restricted to an altitude above 45 km.

Effect of hydrogen pressure on free radicals in direct coal liquefaction/coprocessing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seehra, M.S.; Ibrahim, M.M.

1995-12-31

The objective of this study was to investigate the coprocessing of coal with waste tires and commingled plastics and to characterize the relevant catalysts, using high pressure/high temperature in-situ ESR (Electron Spin Resonance) spectroscopy. The recent results from high pressure ESR spectroscopy are emphasized. During this period, considerable progress was made in developing the high pressure capabilities in in-situ ESR spectroscopy and new results carried out in 1000 psi of H{sub 2}gas are presented. In these experiments, sapphire tubes were used to contain the high pressures at temperatures up to 500{degrees}C. Results of the experiments carried out under 1000 psimore » of H{sub 2} are compared with those under 1000 psi of non-interacting argon and with the earlier experiments in flowing H{sub 2} gas where the volatiles are removed by the flowing gas. In these experiments, the free radical density N of the Blind Canyon coal was measured at each temperature and pressure by double integration of the ESR signal and calibrating it against a standard. The details of the experimental apparatus and procedures have been described in earlier publications.« less

Realization of a multipath ultrasonic gas flowmeter based on transit-time technique.

PubMed

Chen, Qiang; Li, Weihua; Wu, Jiangtao

2014-01-01

A microcomputer-based ultrasonic gas flowmeter with transit-time method is presented. Modules of the flowmeter are designed systematically, including the acoustic path arrangement, ultrasound emission and reception module, transit-time measurement module, the software and so on. Four 200 kHz transducers forming two acoustic paths are used to send and receive ultrasound simultaneously. The synchronization of the transducers can eliminate the influence caused by the inherent switch time in simple chord flowmeter. The distribution of the acoustic paths on the mechanical apparatus follows the Tailored integration, which could reduce the inherent error by 2-3% compared with the Gaussian integration commonly used in the ultrasonic flowmeter now. This work also develops timing modules to determine the flight time of the acoustic signal. The timing mechanism is different from the traditional method. The timing circuit here adopts high capability chip TDC-GP2, with the typical resolution of 50 ps. The software of Labview is used to receive data from the circuit and calculate the gas flow value. Finally, the two paths flowmeter has been calibrated and validated on the test facilities for air flow in Shaanxi Institute of Measurement & Testing. Copyright © 2013 Elsevier B.V. All rights reserved.

Multi-gauge Calibration for modeling the Semi-Arid Santa Cruz Watershed in Arizona-Mexico Border Area Using SWAT

USGS Publications Warehouse

Niraula, Rewati; Norman, Laura A.; Meixner, Thomas; Callegary, James B.

2012-01-01

In most watershed-modeling studies, flow is calibrated at one monitoring site, usually at the watershed outlet. Like many arid and semi-arid watersheds, the main reach of the Santa Cruz watershed, located on the Arizona-Mexico border, is discontinuous for most of the year except during large flood events, and therefore the flow characteristics at the outlet do not represent the entire watershed. Calibration is required at multiple locations along the Santa Cruz River to improve model reliability. The objective of this study was to best portray surface water flow in this semiarid watershed and evaluate the effect of multi-gage calibration on flow predictions. In this study, the Soil and Water Assessment Tool (SWAT) was calibrated at seven monitoring stations, which improved model performance and increased the reliability of flow, in the Santa Cruz watershed. The most sensitive parameters to affect flow were found to be curve number (CN2), soil evaporation and compensation coefficient (ESCO), threshold water depth in shallow aquifer for return flow to occur (GWQMN), base flow alpha factor (Alpha_Bf), and effective hydraulic conductivity of the soil layer (Ch_K2). In comparison, when the model was established with a single calibration at the watershed outlet, flow predictions at other monitoring gages were inaccurate. This study emphasizes the importance of multi-gage calibration to develop a reliable watershed model in arid and semiarid environments. The developed model, with further calibration of water quality parameters will be an integral part of the Santa Cruz Watershed Ecosystem Portfolio Model (SCWEPM), an online decision support tool, to assess the impacts of climate change and urban growth in the Santa Cruz watershed.

Sensor transition failure in the high flow sampler: Implications for methane emission inventories of natural gas infrastructure.

PubMed

Howard, Touché; Ferrara, Thomas W; Townsend-Small, Amy

2015-07-01

Quantification of leaks from natural gas (NG) infrastructure is a key step in reducing emissions of the greenhouse gas methane (CH4), particularly as NG becomes a larger component of domestic energy supply. The U.S. Environmental Protection Agency (EPA) requires measurement and reporting of emissions of CH4 from NG transmission, storage, and processing facilities, and the high-flow sampler (or high-volume sampler) is one of the tools approved for this by the EPA. The Bacharach Hi-Flow Sampler (BHFS) is the only commercially available high-flow instrument, and it is also used throughout the NG supply chain for directed inspection and maintenance, emission factor development, and greenhouse gas reduction programs. Here we document failure of the BHFS to transition from a catalytic oxidation sensor used to measure low NG (~5% or less) concentrations to a thermal conductivity sensor for higher concentrations (from ~5% to 100%), resulting in underestimation of NG emission rates. Our analysis includes both our own field testing and analysis of data from two other studies (Modrak et al., 2012; City of Fort Worth, 2011). Although this failure is not completely understood, and although we do not know if all BHFS models are similarly affected, sensor transition failure has been observed under one or more of these conditions: (1) Calibration is more than ~2 weeks old; (2) firmware is out of date; or (3) the composition of the NG source is less than ~91% CH4. The extent to which this issue has affected recent emission studies is uncertain, but the analysis presented here suggests that the problem could be widespread. Furthermore, it is critical that this problem be resolved before the onset of regulations on CH4 emissions from the oil and gas industry, as the BHFS is a popular instrument for these measurements. An instrument commonly used to measure leaks in natural gas infrastructure has a critical sensor transition failure issue that results in underestimation of leaks, with implications for greenhouse gas emissions estimates as well as safety.

A comparison of calibration techniques for hot-wires operated in subsonic compressible slip flows

NASA Technical Reports Server (NTRS)

Jones, Gregory S.; Stainback, P. C.; Nagabushana, K. A.

1992-01-01

This paper focuses on the correlation of constant temperature anemometer voltages to velocity, density, and total temperature in the transonic slip flow regime. Three different calibration schemes were evaluated. The ultimate use of these hot-wire calibrations is to obtain fluctuations in the flow variables. Without the appropriate mean flow sensitivities of the heated wire, the measurements of these fluctuations cannot be accurately determined.

Multi-phase-fluid discrimination with local fibre-optical probes: I. Liquid/liquid flows

NASA Astrophysics Data System (ADS)

Fordham, E. J.; Holmes, A.; Ramos, R. T.; Simonian, S.; Huang, S.-M.; Lenn, C. P.

1999-12-01

We demonstrate the use of a novel design of fibre-optical sensor (or `local probe') for immiscible-fluid discrimination in multi-phase flows. These probes are made from standard silica fibres with plane oblique facets polished at the fibre tip, with various surface treatments, including a crucial one for wettability control. Total internal reflection is used to distinguish drops, bubbles or other regions of fluid in multi-phase flows, on the basis of refractive-index contrast. Such probes have quasi-binary outputs; we demonstrate in this paper their use in distinguishing water from oil (kerosene) in oil/water two-phase flows and compare the results with those obtained from a simple cleaved fibre relying on the (small) difference in Fresnel reflectivity for discrimination. Quantitative accuracy is demonstrated by comparison of profiles, across a pipe diameter, of local, time-averaged volume fractions (`hold-ups'), with pipe-averaged hold-ups determined from a carefully calibrated gradio-manometer in a fully developed region of the flow. Companion papers deal with the sensors used and results achieved in gas/liquid flows and three-phase flows.

Modeling Total Dissolved Gas for Optimal Operation of Multireservoir Systems

DOE PAGES

Politano, Marcela; Castro, Alejandro; Hadjerioua, Boualem

2017-02-09

One important environmental issue of hydropower in the Columbia and Snake River Basins (Pacific Northwest region of United States) is elevated total dissolved gas (TDG) downstream of a dam, which has the potential to cause gas bubble disease in affected fish. Gas supersaturation in the Columbia River Basin primarily occurs due to dissolution of bubbles entrained during spill events. This paper presents a physically based TDG model that can be used to optimize spill operations in multireservoir hydropower systems. Independent variables of the model are forebay TDG, tailwater elevation, spillway and powerhouse discharges, project head, and environmental parameters such asmore » temperature and atmospheric pressure. The model contains seven physically meaningful experimental parameters, which were calibrated and validated against TDG data collected downstream of Rock Island Dam (Washington) from 2008 to 2012. In conclusion, a sensitivity analysis was performed to increase the understanding of the relationships between TDG downstream of the dam and processes such as air entrainment, lateral powerhouse flow, and dissolution.« less

A Priori Subgrid Scale Modeling for a Droplet Laden Temporal Mixing Layer

NASA Technical Reports Server (NTRS)

Okongo, Nora; Bellan, Josette

2000-01-01

Subgrid analysis of a transitional temporal mixing layer with evaporating droplets has been performed using a direct numerical simulation (DNS) database. The DNS is for a Reynolds number (based on initial vorticity thickness) of 600, with droplet mass loading of 0.2. The gas phase is computed using a Eulerian formulation, with Lagrangian droplet tracking. Since Large Eddy Simulation (LES) of this flow requires the computation of unfiltered gas-phase variables at droplet locations from filtered gas-phase variables at the grid points, it is proposed to model these by assuming the gas-phase variables to be given by the filtered variables plus a correction based on the filtered standard deviation, which can be computed from the sub-grid scale (SGS) standard deviation. This model predicts unfiltered variables at droplet locations better than simply interpolating the filtered variables. Three methods are investigated for modeling the SGS standard deviation: Smagorinsky, gradient and scale-similarity. When properly calibrated, the gradient and scale-similarity methods give results in excellent agreement with the DNS.

1998 Calibration of the Mach 4.7 and Mach 6 Arc-Heated Scramjet Test Facility Nozzles

NASA Technical Reports Server (NTRS)

Witte, David W.; Irby, Richard G.; Auslender, Aaron H.; Rock, Kenneth E.

2004-01-01

A calibration of the Arc-Heated Scramjet Test Facility (AHSTF) Mach 4.7 and Mach 6 nozzles was performed in 1998. For each nozzle, three different typical facility operating test points were selected for calibration. Each survey consisted of measurements, at 340 separate locations across the 11 inch square nozzle exit plane, of pitot pressure, static pressure, and total temperature. Measurement density was higher (4/inch) in the boundary layer near the nozzle wall than in the core nozzle flow (1/inch). The results generated for each of these calibration surveys were contour plots at the nozzle exit plane of the measured and calculated flow properties which completely defined the thermodynamic state of the nozzle exit flow. An area integration of the mass flux at the nozzle exit for each survey was compared to the AHSTF mass flow meter results to provide an indication of the overall quality of the calibration performed. The percent difference between the integrated nozzle exit mass flow and the flow meter ranged from 0.0 to 1.3 percent for the six surveys. Finally, a comparison of this 1998 calibration was made with the 1986 calibration. Differences of less than 10 percent were found within the nozzle core flow while in the boundary layer differences on the order of 20 percent were quite common.

40 CFR 61.68 - Emission monitoring.

Code of Federal Regulations, 2010 CFR

2010-07-01

... basis and analyzes the samples with gas chromatography or, if the owner or operator assumes that all... calibration gas mixture prepared from the gases specified in Sections 7.2.1 and 7.2.2 of Method 106 and in accordance with Section 10.1 of Method 106, or (2) A calibration gas cylinder standard containing the...

40 CFR 61.68 - Emission monitoring.

Code of Federal Regulations, 2011 CFR

2011-07-01

... basis and analyzes the samples with gas chromatography or, if the owner or operator assumes that all... calibration gas mixture prepared from the gases specified in Sections 7.2.1 and 7.2.2 of Method 106 and in accordance with Section 10.1 of Method 106, or (2) A calibration gas cylinder standard containing the...

40 CFR 86.1321-94 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2012 CFR

2012-07-01

... to be used for the analysis of natural gas-fueled vehicle hydrocarbon samples, the methane response... following initial and periodic calibration. The HFID used with petroleum-fueled, natural gas-fueled and liquefied petroleum gas-fueled diesel engines shall be operated to a set point ±10 °F (±5.5 °C) between 365...

40 CFR 86.1321-94 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2013 CFR

2013-07-01

... to be used for the analysis of natural gas-fueled vehicle hydrocarbon samples, the methane response... following initial and periodic calibration. The HFID used with petroleum-fueled, natural gas-fueled and liquefied petroleum gas-fueled diesel engines shall be operated to a set point ±10 °F (±5.5 °C) between 365...

Design and development of a micro-thermocouple sensor for determining temperature and relative humidity patterns within an airstream.

PubMed

Eisner, A D; Martonen, T B

1989-11-01

This paper describes the production and calibration of a miniature psychrometer treated with a specially developed porous coating. The investigation was conducted to determine localized patterns of rapidly changing temperature and relative humidity in dynamic flowing gas environments (e.g., with particular attention to future applications to the human respiratory system). The technique involved the use of dry miniature thermocouples and wetted miniature thermocouples coated with boron nitride to act as a wicking material. A precision humidity generator was developed for calibrating the psychrometer. It was found that, in most cases, the measured and expected (i.e., theoretically predicted) relative humidity agreed to within 0.5 to 1.0 percent relative humidity. Procedures that would decrease this discrepancy even further were pinpointed, and advantages of using the miniature psychrometer were assessed.

[Effect of physical properties of respiratory gas on pneumotachographic measurement of ventilation in newborn infants].

PubMed

Foitzik, B; Schmalisch, G; Wauer, R R

1994-04-01

The measurement of ventilation in neonates has a number of specific characteristics; in contrast to lung function testing in adults, the inspiratory gas for neonates is often conditioned. In pneumotachographs (PNT) based on Hagen-Poiseuille's law, changes in physical characteristics of respiratory gas (temperature, humidity, pressure and oxygen fraction [FiO2]) produce a volume change as calculated with the ideal gas equation p*V/T = const; in addition, the viscosity of the gas is also changed, thus leading to measuring errors. In clinical practice, the effect of viscosity on volume measurement is often ignored. The accuracy of these empirical laws was investigated in a size 0 Fleisch-PNT using a flow-through technique and variously processed respiratory gas. Spontaneous breathing was simulated with the aid of a calibration syringe (20 ml) and a rate of 30 min-1. The largest change in viscosity (11.6% at 22 degrees C and dry gas) is found with an increase in FiO2 (21...100%). A rise in temperature from 24 to 35 degrees C (dry air) produced an increase in viscosity of 5.2%. An increase of humidity (0...90%, 35 degrees C) decreased the viscosity by 3%. A partial compensation of these viscosity errors is thus possible. Pressure change (0...50 mbar, under ambient conditions) caused no measurable viscosity error. With the exception of temperature, the measurements have shown good agreement between the measured volume measuring errors and those calculated from viscosity changes. If the respiratory gas differs from ambient air (e.g. elevated FiO2) or if the PNT is calibrated under BTPS conditions, changes in viscosity must not be neglected when performing accurate ventilation measurements. On the basis of the well-known physical laws of Dalton, Thiesen and Sutherland, a numerical correction of adequate accuracy is possible.

40 CFR 1065.330 - Exhaust-flow calibration.

Code of Federal Regulations, 2011 CFR

2011-07-01

... CONTROLS ENGINE-TESTING PROCEDURES Calibrations and Verifications Flow-Related Measurements § 1065.330... use other reference meters such as laminar flow elements, which are not commonly designed to withstand...

Semiconductor Sensors for Studying the Heterogeneous Destruction of Ozone at Low Concentrations

NASA Astrophysics Data System (ADS)

Obvintseva, L. A.; Sharova, T. B.; Avetisov, A. K.; Sukhareva, I. P.

2018-06-01

Prospects for the use of semiconductor resistive sensors in studies of the heterogeneous destruction of ozone at low concentrations (5-400 μg/m3) were shown. The influence of various factors (sensor temperature, gas flow rate, ozone concentration) on the results of ozone concentration measurements with sensors of various types was studied. Methods for forming a sensitive layer of In2O3(3% Fe2O3) sensors with specified parameters of calibration curves were proposed. The optimum conditions for the operation of sensors in a flow mode were formulated. The results of the study of heterogeneous destruction of ozone on microfiber polymer and natural disperse (sand, coals) materials obtained by the developed method were presented.

Constraining Controls on the Emplacement of Long Lava Flows on Earth and Mars Through Modeling in ArcGIS

NASA Astrophysics Data System (ADS)

Golder, K.; Burr, D. M.; Tran, L.

2017-12-01

Regional volcanic processes shaped many planetary surfaces in the Solar System, often through the emplacement of long, voluminous lava flows. Terrestrial examples of this type of lava flow have been used as analogues for extensive martian flows, including those within the circum-Cerberus outflow channels. This analogy is based on similarities in morphology, extent, and inferred eruptive style between terrestrial and martian flows, which raises the question of how these lava flows appear comparable in size and morphology on different planets. The parameters that influence the areal extent of silicate lavas during emplacement may be categorized as either inherent or external to the lava. The inherent parameters include the lava yield strength, density, composition, water content, crystallinity, exsolved gas content, pressure, and temperature. Each inherent parameter affects the overall viscosity of the lava, and for this work can be considered a subset of the viscosity parameter. External parameters include the effusion rate, total erupted volume, regional slope, and gravity. To investigate which parameter(s) may control(s) the development of long lava flows on Mars, we are applying a computational numerical-modelling to reproduce the observed lava flow morphologies. Using a matrix of boundary conditions in the model enables us to investigate the possible range of emplacement conditions that can yield the observed morphologies. We have constructed the basic model framework in Model Builder within ArcMap, including all governing equations and parameters that we seek to test, and initial implementation and calibration has been performed. The base model is currently capable of generating a lava flow that propagates along a pathway governed by the local topography. At AGU, the results of model calibration using the Eldgá and Laki lava flows in Iceland will be presented, along with the application of the model to lava flows within the Cerberus plains on Mars. We then plan to convert the model into Python, for easy modification and portability within the community.

EPA Protocol Gas Verification Program

EPA Science Inventory

Accurate compressed gas calibration standards are needed to calibrate continuous emission monitors (CEMs) and ambient air quality monitors that are being used for regulatory purposes. US Environmental Protection Agency (EPA) established its traceability protocol to ensure that co...

Lurking systematics in predicting galaxy cold gas masses using dust luminosities and star formation rates

NASA Astrophysics Data System (ADS)

Janowiecki, Steven; Cortese, Luca; Catinella, Barbara; Goodwin, Adelle J.

2018-05-01

We use galaxies from the Herschel Reference Survey to evaluate commonly used indirect predictors of cold gas masses. We calibrate predictions for cold neutral atomic and molecular gas using infrared dust emission and gas depletion time methods that are self-consistent and have ˜20 per cent accuracy (with the highest accuracy in the prediction of total cold gas mass). However, modest systematic residual dependences are found in all calibrations that depend on the partition between molecular and atomic gas, and can over/underpredict gas masses by up to 0.3 dex. As expected, dust-based estimates are best at predicting the total gas mass while depletion time-based estimates are only able to predict the (star-forming) molecular gas mass. Additionally, we advise caution when applying these predictions to high-z galaxies, as significant (0.5 dex or more) errors can arise when incorrect assumptions are made about the dominant gas phase. Any scaling relations derived using predicted gas masses may be more closely related to the calibrations used than to the actual galaxies observed.

Calibration of the 7—Equation Transition Model for High Reynolds Flows at Low Mach

NASA Astrophysics Data System (ADS)

Colonia, S.; Leble, V.; Steijl, R.; Barakos, G.

2016-09-01

The numerical simulation of flows over large-scale wind turbine blades without considering the transition from laminar to fully turbulent flow may result in incorrect estimates of the blade loads and performance. Thanks to its relative simplicity and promising results, the Local-Correlation based Transition Modelling concept represents a valid way to include transitional effects into practical CFD simulations. However, the model involves coefficients that need tuning. In this paper, the γ—equation transition model is assessed and calibrated, for a wide range of Reynolds numbers at low Mach, as needed for wind turbine applications. An aerofoil is used to evaluate the original model and calibrate it; while a large scale wind turbine blade is employed to show that the calibrated model can lead to reliable solutions for complex three-dimensional flows. The calibrated model shows promising results for both two-dimensional and three-dimensional flows, even if cross-flow instabilities are neglected.

[Feasibility Study on Digital Signal Processor and Gear Pump of Uroflowmeter Calibration Device].

PubMed

Yuan, Qing; Ji, Jun; Gao, Jiashuo; Wang, Lixin; Xiao, Hong

2016-08-01

It will cause hidden trouble on clinical application if the uroflowmeter is out of control.This paper introduces a scheme of uroflowmeter calibration device based on digital signal processor(DSP)and gear pump and shows studies of its feasibility.According to the research plan,we analyzed its stability,repeatability and linearity by building a testing system and carried out experiments on it.The flow test system is composed of DSP,gear pump and other components.The test results showed that the system could produce a stable water flow with high precision of repeated measurement and different flow rate.The test system can calibrate the urine flow rate well within the range of 9~50mL/s which has clinical significance,and the flow error is less than 1%,which meets the technical requirements of the calibration apparatus.The research scheme of uroflowmeter calibration device on DSP and gear pump is feasible.

Evaluation of four fast-response flow measurement devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gero, A.J.; Suppers, K.L.; Tomb, T.F.

1988-01-01

The Federal Mine Safety and Health Act of 1977 requires that sampling of dust in coal mine environments be conducted with an approved sampler operating at a flow rate of 2.0 liters of air per minute or at such other flow rate as prescribed by the Secretaries of Labor and of Health and Human Services. Standard procedures for calibration of these samplers within the Mine Safety and Health Administration utilize either a 3.0 liter capacity wet test meter or a 1.0 liter soap film calibrator. Several new flow calibrating devices have become commercially available. This paper describes an evaluation conductedmore » on four such devices: the Mast Model 823-2 bubble flowmeter, the Buck Calibrator, the Kurz Model 541S mass flowmeter and the Kurz Pocket Calibrator. The precision of a series of measurements made with each instrument was compared to the precision of a series of measurements made with the wet test meter. The comparison showed that the variability of calibration measurements obtained with the fast response flow calibrators was between 1.5 and 4.5 times larger than that obtained with the WTM; however, with all of the calibration devices evaluated, three repetitive measurements were sufficient to obtain a precision of {plus minus}0.1 liters per minute. 4 refs., 2 figs., 1 tab.« less

Laminated turbine vane design and fabrication. [utilizing film cooling as a cooling system

NASA Technical Reports Server (NTRS)

Hess, W. G.

1979-01-01

A turbine vane and associated endwalls designed for advanced gas turbine engine conditions are described. The vane design combines the methods of convection cooling and selective areas of full coverage film cooling. The film cooling technique is utilized on the leading edge, pressure side, and endwall regions. The turbine vane involves the fabrication of airfoils from a stack of laminates with cooling passages photoetched on the surface. Cold flow calibration tests, a thermal analysis, and a stress analysis were performed on the turbine vanes.

Apparatus for experimental investigation of aerodynamic radiation with absorption by ablation products

NASA Technical Reports Server (NTRS)

Wells, W. L.; Snow, W. L.

1977-01-01

A description is given and calibration procedures are presented for an apparatus that is used to simulate aerodynamic radiant heating during planetary entry. The primary function of the apparatus is to simulate the spectral distribution of shock layer radiation and to determine absorption effects of simulated ablation products which are injected into the stagnation region flow field. An electric arc heater is used to heat gas mixtures that represent the planetary atmospheres of interest. Spectral measurements are made with a vacuum ultraviolet scanning monochromator.

A simple fast pulse gas valve using a dynamic pressure differential as the primary closing mechanism

NASA Astrophysics Data System (ADS)

Thomas, J. C.; Hwang, D. Q.; Horton, R. D.; Rogers, J. H.; Raman, R.

1993-06-01

In this article we describe a simple fast pulse gas valve developed for use in a plasma discharge experiment. The valve delivers 1017-1019 molecules per pulse varied by changing the voltage on the electromagnetic driver power supply. Valve pulse widths are observed to be less than 300 μs full width at half maximum with a rise time of less than 100 μs resulting in a maximum gas flow rate of ˜1022 molecules per second. An optical transmission technique was used to determine the mechanical opening and closing characteristics of the valve piston. A fast ionization gauge (FIG) was used for diagnosis of the temporal character of the gas pulse while the total gas throughput was determined by measuring the change in pressure per pulse in a small test chamber with a convectron tube gauge. Calibration of the FIG was accomplished by comparing the net change in pressure in a large chamber as measured by the FIG to the net change in pressure in a small test chamber as measured by the convectron tube gauge.

Gas density field imaging in shock dominated flows using planar laser scattering

NASA Astrophysics Data System (ADS)

Pickles, Joshua D.; Mettu, Balachandra R.; Subbareddy, Pramod K.; Narayanaswamy, Venkateswaran

2018-07-01

Planar laser scattering (PLS) imaging of ice particulates present in a supersonic stream is demonstrated to measure 2D gas density fields of shock dominated flows in low enthalpy test facilities. The technique involves mapping the PLS signal to gas density using a calibration curve that accounts for the seed particulate size distribution change across the shock wave. The PLS technique is demonstrated in a shock boundary layer interaction generated by a sharp fin placed on a cylindrical surface in Mach 2.5 flow. The shock structure generated in this configuration has complicating effects from the finite height of the fin as well as the 3D relief offered by the cylindrical surface, which result in steep spatial gradients as well as a wide range of density jumps across different locations of the shock structure. Instantaneous and mean PLS fields delineated the inviscid, separation, and reattachment shock structures at various downstream locations. The inviscid shock assumed increasingly larger curvature with downstream distance; concomitantly, the separation shock wrapped around the cylinder and the separation shock foot missed the cylinder surface entirely. The density fields obtained from the PLS technique were evaluated using RANS simulations of the same flowfield. Comparisons between the computed and measured density fields showed excellent agreement over the entire measurable region that encompassed the flow processed by inviscid, separation, and reattachment shocks away from viscous regions. The PLS approach demonstrated in this work is also shown to be largely independent of the seed particulates, which lends the extension of this approach to a wide range of test facilities.

Five-Hole Flow Angle Probe Calibration for the NASA Glenn Icing Research Tunnel

NASA Technical Reports Server (NTRS)

Gonsalez, Jose C.; Arrington, E. Allen

1999-01-01

A spring 1997 test section calibration program is scheduled for the NASA Glenn Research Center Icing Research Tunnel following the installation of new water injecting spray bars. A set of new five-hole flow angle pressure probes was fabricated to properly calibrate the test section for total pressure, static pressure, and flow angle. The probes have nine pressure ports: five total pressure ports on a hemispherical head and four static pressure ports located 14.7 diameters downstream of the head. The probes were calibrated in the NASA Glenn 3.5-in.-diameter free-jet calibration facility. After completing calibration data acquisition for two probes, two data prediction models were evaluated. Prediction errors from a linear discrete model proved to be no worse than those from a full third-order multiple regression model. The linear discrete model only required calibration data acquisition according to an abridged test matrix, thus saving considerable time and financial resources over the multiple regression model that required calibration data acquisition according to a more extensive test matrix. Uncertainties in calibration coefficients and predicted values of flow angle, total pressure, static pressure. Mach number. and velocity were examined. These uncertainties consider the instrumentation that will be available in the Icing Research Tunnel for future test section calibration testing.

Biochemical gas sensor (bio-sniffer) for ultrahigh-sensitive gaseous formaldehyde monitoring.

PubMed

Kudo, Hiroyuki; Suzuki, Yuki; Gessei, Tomoko; Takahashi, Daishi; Arakawa, Takahiro; Mitsubayashi, Kohji

2010-10-15

An ultrahigh-sensitive fiber-optic biochemical gas sensor (bio-sniffer) for continuous monitoring of indoor formaldehyde was constructed and tested. The bio-sniffer measures gaseous formaldehyde as fluorescence of nicotinamide adenine dinucleotide (NADH), which is the product of formaldehyde dehydrogenase (FALDH) reaction. The bio-sniffer device was constructed by attaching a flow cell with a FALDH immobilized membrane onto a fiber-optic NADH measurement system. The NADH measurement system utilizes an ultraviolet-light emitting diode (UV-LED) with peak emission of 335 nm as an excitation light source. The excitation light was introduced to an optical fiber probe, and fluorescence emission of neighboring NADH, which was produced by applying formaldehyde vapor to the FALDH membrane, was concentrically measured with a photomultiplier tube. Assessment of the bio-sniffer was carried out using a standard gas generator. Response, calibration range and selectivity to other chemical substances were investigated. Circulating phosphate buffer, which contained NAD+, available for continuous monitoring of formaldehyde vapor. The calibration range of the bio-sniffer was 2.5 ppb to 10 ppm, which covers the guideline value of the World Health Organization (80 ppb). High selectivity to other gaseous substances due to specific activity of FALDH was also confirmed. Considering its high sensitivity, a possible application of the bio-sniffer is continuous indoor formaldehyde monitoring to provide healthy residential atmosphere. Copyright © 2010 Elsevier B.V. All rights reserved.

Blood-gas analyzer calibration and quality control using a precision gas-mixing instrument.

PubMed

Wallace, W D; Clark, J S; Cutler, C A

1981-08-01

We describe a new instrument that performs on-site mixing of oxygen (O2), carbon dioxide (CO2), and nitrogen (N2) to create compositions that can replace gases from standard premixed cylinders. This instrument yields accurate and predictable gas mixtures that can be used for two-point gas calibration of blood gas/pH analyzers or for liquid tonometry of either an aqueous buffer or blood used as quality-control material on blood-gas electrodes. The desired mixture of O2, CO2, and N2 is produced by microprocessor control of the sequential open-times on three solenoid valves that meter these pure gases through a common small-bore orifice. Any combination of O2 and CO2 can be chosen by dialing the front panel thumbwheels and pressing a button. Gas chromatographic evaluation of this gas-mixing instrument demonstrates its accuracy and precision to be better than +/- 0.1% absolute full scale for O2, CO2, and N2, making this instrument calibration and tonometry.

Geometric calibration of Colour and Stereo Surface Imaging System of ESA's Trace Gas Orbiter

NASA Astrophysics Data System (ADS)

Tulyakov, Stepan; Ivanov, Anton; Thomas, Nicolas; Roloff, Victoria; Pommerol, Antoine; Cremonese, Gabriele; Weigel, Thomas; Fleuret, Francois

2018-01-01

There are many geometric calibration methods for "standard" cameras. These methods, however, cannot be used for the calibration of telescopes with large focal lengths and complex off-axis optics. Moreover, specialized calibration methods for the telescopes are scarce in literature. We describe the calibration method that we developed for the Colour and Stereo Surface Imaging System (CaSSIS) telescope, on board of the ExoMars Trace Gas Orbiter (TGO). Although our method is described in the context of CaSSIS, with camera-specific experiments, it is general and can be applied to other telescopes. We further encourage re-use of the proposed method by making our calibration code and data available on-line.

Calibration of the NASA GRC 16 In. Mass-Flow Plug

NASA Technical Reports Server (NTRS)

Davis, David O.; Friedlander, David J.; Saunders, J. David; Frate, Franco C.; Foster, Lancert E.

2012-01-01

The results of an experimental calibration of the NASA Glenn Research Center 16 in. Mass-Flow Plug (MFP) are presented and compared to a previously obtained calibration of a 15 in. Mass-Flow Plug. An ASME low-beta, long-radius nozzle was used as the calibration reference. The discharge coefficient for the ASME nozzle was obtained by numerically simulating the flow through the nozzle from the WIND-US code. The results showed agreement between the 15 in. and 16 in. MFPs for area ratios (MFP to pipe area ratio) greater than 0.6 but deviate at area ratios below this value for reasons that are not fully understood. A general uncertainty analysis was also performed and indicates that large uncertainties in the calibration are present for low MFP area ratios.

Calibration of the NASA Glenn Research Center 16 in. Mass-Flow Plug

NASA Technical Reports Server (NTRS)

Davis, David O.; Friedlander, David J.; Saunders, J. David; Frate, Franco C.; Foster, Lancert E.

2014-01-01

The results of an experimental calibration of the NASA Glenn Research Center 16 in. Mass-Flow Plug (MFP) are presented and compared to a previously obtained calibration of a 15 in. Mass-Flow Plug. An ASME low-beta, long-radius nozzle was used as the calibration reference. The discharge coefficient for the ASME nozzle was obtained by numerically simulating the flow through the nozzle from the WIND-US code. The results showed agreement between the 15 and 16 in. MFPs for area ratios (MFP to pipe area ratio) greater than 0.6 but deviate at area ratios below this value for reasons that are not fully understood. A general uncertainty analysis was also performed and indicates that large uncertainties in the calibration are present for low MFP area ratios.

A new portable generator to dynamically produce SI-traceable reference gas mixtures for VOCs and water vapour at atmospheric concentration

NASA Astrophysics Data System (ADS)

Guillevic, Myriam; Pascale, Céline; Ackermann, Andreas; Leuenberger, Daiana; Niederhauser, Bernhard

2016-04-01

In the framework of the KEY-VOCs and AtmoChem-ECV projects, we are currently developing new facilities to dynamically generate reference gas mixtures for a variety of reactive compounds, at concentrations measured in the atmosphere and in a SI-traceable way (i.e. the amount of substance fraction in mole per mole is traceable to SI-units). Here we present the realisation of such standards for water vapour in the range 1-10 μmol/mol and for volatile organic compounds (VOCs) such as limonene, alpha-pinene, MVK, MEK, in the nmol/mol range. The matrix gas can be nitrogen or synthetic air. Further development in gas purification techniques could make possible to use purified atmospheric air as carrier gas. The method is based on permeation and dynamic dilution: one permeator containing a pure substance (either water, limonene, MVK, MEK or α-pinene) is kept into a permeation chamber with a constant gas flow. The mass loss is precisely calibrated using a magnetic suspension balance. The carrier gas is purified beforehand from the compounds of interest to the required level, using commercially available purification cartridges. This primary mixture is then diluted to reach the required amount of substance fraction. All flows are piloted by mass flow controllers which makes the production process flexible and easily adaptable to generate the required concentration. All parts in contact with the gas mixture are passivated using coated surfaces, to reduce adsorption/desorption processes as much as possible. Two setups are currently developed: one already built and fixed in our laboratory in Bern as well as a portable generator that is still under construction and that could be used anywhere in the field. The permeation chamber of the portable generator has multiple individual cells allowing the generation of mixtures up to 5 different components if needed. Moreover the presented technique can be adapted and applied to a large variety of molecules (e.g., NO2, BTEX, CFCs, HCFCs, HFCs and other refrigerants) and is particularly suitable for gas species and/or concentration ranges that are not stable in cylinders.

Concentration of atomic hydrogen in a dielectric barrier discharge measured by two-photon absorption fluorescence

NASA Astrophysics Data System (ADS)

Dvořák, P.; Talába, M.; Obrusník, A.; Kratzer, J.; Dědina, J.

2017-08-01

Two-photon absorption laser-induced fluorescence (TALIF) was utilized for measuring the concentration of atomic hydrogen in a volume dielectric barrier discharge (DBD) ignited in mixtures of Ar, H2 and O2 at atmospheric pressure. The method was calibrated by TALIF of krypton diluted in argon at atmospheric pressure, proving that three-body collisions had a negligible effect on quenching of excited krypton atoms. The diagnostic study was complemented with a 3D numerical model of the gas flow and a zero-dimensional model of the chemistry in order to better understand the reaction kinetics and identify the key pathways leading to the production and destruction of atomic hydrogen. It was determined that the density of atomic hydrogen in Ar-H2 mixtures was in the order of 1021 m-3 and decreased when oxygen was added into the gas mixture. Spatially resolved measurements and simulations revealed a sharply bordered region with low atomic hydrogen concentration when oxygen was added to the gas mixture. At substoichiometric oxygen/hydrogen ratios, this H-poor region is confined to an area close to the gas inlet and it is shown that the size of this region is not only influenced by the chemistry but also by the gas flow patterns. Experimentally, it was observed that a decrease in H2 concentration in the feeding Ar-H2 mixture led to an increase in H production in the DBD.

Flow rate calibration to determine cell-derived microparticles and homogeneity of blood components.

PubMed

Noulsri, Egarit; Lerdwana, Surada; Kittisares, Kulvara; Palasuwan, Attakorn; Palasuwan, Duangdao

2017-08-01

Cell-derived microparticles (MPs) are currently of great interest to screening transfusion donors and blood components. However, the current approach to counting MPs is not affordable for routine laboratory use due to its high cost. The current study aimed to investigate the potential use of flow-rate calibration for counting MPs in whole blood, packed red blood cells (PRBCs), and platelet concentrates (PCs). The accuracy of flow-rate calibration was investigated by comparing the platelet counts of an automated counter and a flow-rate calibrator. The concentration of MPs and their origins in whole blood (n=100), PRBCs (n=100), and PCs (n=92) were determined using a FACSCalibur. The MPs' fold-changes were calculated to assess the homogeneity of the blood components. Comparing the platelet counts conducted by automated counting and flow-rate calibration showed an r 2 of 0.6 (y=0.69x+97,620). The CVs of the within-run and between-run variations of flow-rate calibration were 8.2% and 12.1%, respectively. The Bland-Altman plot showed a mean bias of -31,142platelets/μl. MP enumeration revealed both the difference in MP levels and their origins in whole blood, PRBCs, and PCs. Screening the blood components demonstrated high heterogeneity of the MP levels in PCs when compared to whole blood and PRBCs. The results of the present study suggest the accuracy and precision of flow-rate calibration for enumerating MPs. This flow-rate approach is affordable for assessing the homogeneity of MPs in blood components in routine laboratory practice. Copyright © 2017 Elsevier Ltd. All rights reserved.

Calibration of polydimethylsiloxane and XAD-Pocket passive air samplers (PAS) for measuring gas- and particle-phase SVOCs

NASA Astrophysics Data System (ADS)

Okeme, Joseph O.; Saini, Amandeep; Yang, Congqiao; Zhu, Jiping; Smedes, Foppe; Klánová, Jana; Diamond, Miriam L.

2016-10-01

Polydimethylsiloxane (PDMS) has seen wide use as the stationary phase of gas chromatographic columns, a passive sampler in water, and recently as a personal exposure sampler, while styrene divinyl-benzene copolymer (XAD) has been used extensively as a passive air sampler outdoors and indoors. We have introduced PDMS and XAD-Pocket as new indoor passive air samplers (PASs). The XAD-Pocket was designed to maximize the surface area-to-volume ratio of XAD and to minimize obstruction of air flow by the sampler housing. Methods were developed to expedite the use of these PASs for measuring phthalates, novel brominated flame-retardants (NFRs) and polybrominated diphenyl ethers (PBDEs) indoors. Sampling rates, Rs, (m3 day-1), were measured during a 7-week calibration study. Variability within and between analyte groups was not statistically significant. As a result, generic values of 0.8 ± 0.4 and 0.5 ± 0.3 m3 day-1 dm-2 are recommended for PDMS and XAD-Pocket for a 50-day deployment time, respectively. PDMS has a higher uptake rate and is easier to use than XAD-Pocket.

Calibration of two passive air samplers for monitoring phthalates and brominated flame-retardants in indoor air.

PubMed

Saini, Amandeep; Okeme, Joseph O; Goosey, Emma; Diamond, Miriam L

2015-10-01

Two passive air samplers (PAS), polyurethane foam (PUF) disks and Sorbent Impregnated PUF (SIP) disks, were characterized for uptake of phthalates and brominated flame-retardants (BFRs) indoors using fully and partially sheltered housings. Based on calibration against an active low-volume air sampler for gas- and particle-phase compounds, we recommend generic sampling rates of 3.5±0.9 and 1.0±0.4 m(3)/day for partially and fully sheltered housing, respectively, which applies to gas-phase phthalates and BFRs as well as particle-phase DEHP (the later for the partially sheltered PAS). For phthalates, partially sheltered SIPs are recommended. Further, we recommend the use of partially sheltered PAS indoors and a deployment period of one month. The sampling rate for the partially sheltered PUF and SIP of 3.5±0.9 m(3)/day is indistinguishable from that reported for fully sheltered PAS deployed outdoors, indicating the role of the housing outdoors to minimize the effect of variable wind velocities on chemical uptake, versus the partially sheltered PAS deployed indoors to maximize chemical uptake where air flow rates are low. Copyright © 2015. Published by Elsevier Ltd.

Development and validation of a portable gas phase standard generation and calibration system for volatile organic compounds

Treesearch

P. Veres; J. B. Gilman; J. M. Roberts; W. C. Kuster; C. Warneke; I. R. Burling; J. de Gouw

2010-01-01

We report on the development of an accurate, portable, dynamic calibration system for volatile organic compounds (VOCs). The Mobile Organic Carbon Calibration System (MOCCS) combines the production of gas-phase VOC standards using permeation or diffusion sources with quantitative total organic carbon (TOC) conversion on a palladium surface to CO2 in the presence of...

Calibration of neural networks using genetic algorithms, with application to optimal path planning

NASA Technical Reports Server (NTRS)

Smith, Terence R.; Pitney, Gilbert A.; Greenwood, Daniel

1987-01-01

Genetic algorithms (GA) are used to search the synaptic weight space of artificial neural systems (ANS) for weight vectors that optimize some network performance function. GAs do not suffer from some of the architectural constraints involved with other techniques and it is straightforward to incorporate terms into the performance function concerning the metastructure of the ANS. Hence GAs offer a remarkably general approach to calibrating ANS. GAs are applied to the problem of calibrating an ANS that finds optimal paths over a given surface. This problem involves training an ANS on a relatively small set of paths and then examining whether the calibrated ANS is able to find good paths between arbitrary start and end points on the surface.

Calibrated sulfur isotope abundance ratios of three IAEA sulfur isotope reference materials and V-CDT with a reassessment of the atomic weight of sulfur

NASA Astrophysics Data System (ADS)

Ding, T.; Valkiers, S.; Kipphardt, H.; De Bièvre, P.; Taylor, P. D. P.; Gonfiantini, R.; Krouse, R.

2001-08-01

Calibrated values have been obtained for sulfur isotope abundance ratios of sulfur isotope reference materials distributed by the IAEA (Vienna). For the calibration of the measurements, a set of synthetic isotope mixtures were prepared gravimetrically from high purity Ag2S materials enriched in32S, 33S, and 34S. All materials were converted into SF6 gas and subsequently, their sulfur isotope ratios were measured on the SF5+ species using a special gas source mass spectrometer equipped with a molecular flow inlet system (IRMM's Avogadro II amount comparator). Values for the 32S/34S abundance ratios are 22.650 4(20), 22.142 4(20), and 23.393 3(17) for IAEA-S-1, IAEA-S-2, and IAEA-S-3, respectively. The calculated 32S/34S abundance ratio for V-CDT is 22.643 6(20), which is very close to the calibrated ratio obtained by Ding et al. (1999). In this way, the zero point of the VCDT scale is anchored firmly to the international system of units SI. The 32S/33S abundance ratios are 126.942(47), 125.473(55), 129.072(32), and 126.948(47) for IAEA-S-1, IAEA-S-2, IAEA-S-3, and V-CDT, respectively. In this way, the linearity of the V-CDT scale is improved over this range. The values of the sulfur molar mass for IAEA-S-1 and V-CDT were calculated to be 32.063 877(56) and 32.063 911(56), respectively, the values with the smallest combined uncertainty ever reported for the sulfur molar masses (atomic weights).

User's manual for three dimensional boundary layer (BL3-D) code

NASA Technical Reports Server (NTRS)

Anderson, O. L.; Caplin, B.

1985-01-01

An assessment has been made of the applicability of a 3-D boundary layer analysis to the calculation of heat transfer, total pressure losses, and streamline flow patterns on the surface of both stationary and rotating turbine passages. In support of this effort, an analysis has been developed to calculate a general nonorthogonal surface coordinate system for arbitrary 3-D surfaces and also to calculate the boundary layer edge conditions for compressible flow using the surface Euler equations and experimental data to calibrate the method, calculations are presented for the pressure endwall, and suction surfaces of a stationary cascade and for the pressure surface of a rotating turbine blade. The results strongly indicate that the 3-D boundary layer analysis can give good predictions of the flow field, loss, and heat transfer on the pressure, suction, and endwall surface of a gas turbine passage.

ITOUGH2(UNIX). Inverse Modeling for TOUGH2 Family of Multiphase Flow Simulators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finsterle, S.

1999-03-01

ITOUGH2 provides inverse modeling capabilities for the TOUGH2 family of numerical simulators for non-isothermal multiphase flows in fractured-porous media. The ITOUGH2 can be used for estimating parameters by automatic modeling calibration, for sensitivity analyses, and for uncertainity propagation analyses (linear and Monte Carlo simulations). Any input parameter to the TOUGH2 simulator can be estimated based on any type of observation for which a corresponding TOUGH2 output is calculated. ITOUGH2 solves a non-linear least-squares problem using direct or gradient-based minimization algorithms. A detailed residual and error analysis is performed, which includes the evaluation of model identification criteria. ITOUGH2 can also bemore » run in forward mode, solving subsurface flow problems related to nuclear waste isolation, oil, gas, and geothermal resevoir engineering, and vadose zone hydrology.« less

Automated Heat-Flux-Calibration Facility

NASA Technical Reports Server (NTRS)

Liebert, Curt H.; Weikle, Donald H.

1989-01-01

Computer control speeds operation of equipment and processing of measurements. New heat-flux-calibration facility developed at Lewis Research Center. Used for fast-transient heat-transfer testing, durability testing, and calibration of heat-flux gauges. Calibrations performed at constant or transient heat fluxes ranging from 1 to 6 MW/m2 and at temperatures ranging from 80 K to melting temperatures of most materials. Facility developed because there is need to build and calibrate very-small heat-flux gauges for Space Shuttle main engine (SSME).Includes lamp head attached to side of service module, an argon-gas-recirculation module, reflector, heat exchanger, and high-speed positioning system. This type of automated heat-flux calibration facility installed in industrial plants for onsite calibration of heat-flux gauges measuring fluxes of heat in advanced gas-turbine and rocket engines.

Calibration of a Noble Gas Mass Spectrometer with an Atmospheric Argon Standard (Invited)

NASA Astrophysics Data System (ADS)

Prasad, V.; Grove, M.

2009-12-01

Like other mass spectrometers, gas source instruments are very good at precisely measuring isotopic ratios but need to be calibrated with a standard to be accurate. The need for calibration arises due to the complicated ionization process which inefficiently and differentially creates ions from the various isotopes that make up the elemental gas. Calibration of the ionization process requires materials with well understood isotopic compositions as standards. Our project goal was to calibrate a noble gas (Noblesse) mass spectrometer with a purified air sample. Our sample obtained from Ocean Beach in San Francisco was under known temperature, pressure, volume, humidity. We corrected the pressure for humidity and used the ideal gas law to calculate the number of moles of argon gas. We then removed all active gasses using specialized equipment designed for this purpose at the United States Geological Survey. At the same time, we measured the volume ratios of various parts of the gas extraction line system associated with the Noblesse mass spectrometer. Using this data, we calculated how much Ar was transferred to the reservoir from the vacuum-sealed vial that contained the purified gas standard. Using similar measurements, we also calculated how much Ar was introduced into the extraction line from a pipette system and how much of this Ar was ultimately expanded into the Noblesse mass spectrometer. Based upon this information, it was possible to calibrate the argon sensitivity of the mass spectrometer. From a knowledge of the isotopic composition of air, it was also possible to characterize how ionized argon isotopes were fractionated during analysis. By repeatedly analyzing our standard we measured a 40Ar Sensitivity of 2.05 amps/bar and a 40Ar/36Ar ratio of 309.2 on the Faraday detector. In contrast, measurements carried out by ion counting using electron multipliers yield a value (296.8) which is much closer to the actual atmospheric 40Ar/36Ar value of 295.5.

CURRENT STATUS OF THE EPA PROTOCOL GAS PROGRAM

EPA Science Inventory

Accurate compressed gas calibration standards are needed to calibrate continuous emission monitors (CEMs) and ambient air quality monitors that are being used for regulatory purposes. EPA has published a protocol to establish the traceability of these standards to national refer...

Intercomparison of hydrological model structures and calibration approaches in climate scenario impact projections

NASA Astrophysics Data System (ADS)

Vansteenkiste, Thomas; Tavakoli, Mohsen; Ntegeka, Victor; De Smedt, Florimond; Batelaan, Okke; Pereira, Fernando; Willems, Patrick

2014-11-01

The objective of this paper is to investigate the effects of hydrological model structure and calibration on climate change impact results in hydrology. The uncertainty in the hydrological impact results is assessed by the relative change in runoff volumes and peak and low flow extremes from historical and future climate conditions. The effect of the hydrological model structure is examined through the use of five hydrological models with different spatial resolutions and process descriptions. These were applied to a medium sized catchment in Belgium. The models vary from the lumped conceptual NAM, PDM and VHM models over the intermediate detailed and distributed WetSpa model to the fully distributed MIKE SHE model. The latter model accounts for the 3D groundwater processes and interacts bi-directionally with a full hydrodynamic MIKE 11 river model. After careful and manual calibration of these models, accounting for the accuracy of the peak and low flow extremes and runoff subflows, and the changes in these extremes for changing rainfall conditions, the five models respond in a similar way to the climate scenarios over Belgium. Future projections on peak flows are highly uncertain with expected increases as well as decreases depending on the climate scenario. The projections on future low flows are more uniform; low flows decrease (up to 60%) for all models and for all climate scenarios. However, the uncertainties in the impact projections are high, mainly in the dry season. With respect to the model structural uncertainty, the PDM model simulates significantly higher runoff peak flows under future wet scenarios, which is explained by its specific model structure. For the low flow extremes, the MIKE SHE model projects significantly lower low flows in dry scenario conditions in comparison to the other models, probably due to its large difference in process descriptions for the groundwater component, the groundwater-river interactions. The effect of the model calibration was tested by comparing the manual calibration approach with automatic calibrations of the VHM model based on different objective functions. The calibration approach did not significantly alter the model results for peak flow, but the low flow projections were again highly influenced. Model choice as well as calibration strategy hence have a critical impact on low flows, more than on peak flows. These results highlight the high uncertainty in low flow modelling, especially in a climate change context.

A fast, calibrated model for pyroclastic density currents kinematics and hazard

NASA Astrophysics Data System (ADS)

Esposti Ongaro, Tomaso; Orsucci, Simone; Cornolti, Fulvio

2016-11-01

Multiphase flow models represent valuable tools for the study of the complex, non-equilibrium dynamics of pyroclastic density currents. Particle sedimentation, flow stratification and rheological changes, depending on the flow regime, interaction with topographic obstacles, turbulent air entrainment, buoyancy reversal, and other complex features of pyroclastic currents can be simulated in two and three dimensions, by exploiting efficient numerical solvers and the improved computational capability of modern supercomputers. However, numerical simulations of polydisperse gas-particle mixtures are quite computationally expensive, so that their use in hazard assessment studies (where there is the need of evaluating the probability of hazardous actions over hundreds of possible scenarios) is still challenging. To this aim, a simplified integral (box) model can be used, under the appropriate hypotheses, to describe the kinematics of pyroclastic density currents over a flat topography, their scaling properties and their depositional features. In this work, multiphase flow simulations are used to evaluate integral model approximations, to calibrate its free parameters and to assess the influence of the input data on the results. Two-dimensional numerical simulations describe the generation and decoupling of a dense, basal layer (formed by progressive particle sedimentation) from the dilute transport system. In the Boussinesq regime (i.e., for solid mass fractions below about 0.1), the current Froude number (i.e., the ratio between the current inertia and buoyancy) does not strongly depend on initial conditions and it is consistent to that measured in laboratory experiments (i.e., between 1.05 and 1.2). For higher density ratios (solid mass fraction in the range 0.1-0.9) but still in a relatively dilute regime (particle volume fraction lower than 0.01), numerical simulations demonstrate that the box model is still applicable, but the Froude number depends on the reduced gravity. When the box model is opportunely calibrated with the numerical simulation results, the prediction of the flow runout is fairly accurate and the model predicts a rapid, non-linear decay of the flow kinetic energy (or dynamic pressure) with the distance from the source. The capability of PDC to overcome topographic obstacles can thus be analysed in the framework of the energy-conoid approach, in which the predicted kinetic energy of the flow front is compared with the potential energy jump associated with the elevated topography to derive a condition for blocking. Model results show that, although preferable to the energy-cone, the energy-conoid approach still has some serious limitations, mostly associated with the behaviour of the flow head. Implications of these outcomes are discussed in the context of probabilistic hazard assessment studies, in which a calibrated box model can be used as a fast pyroclastic density current emulator for Monte Carlo simulations.

Palaeozoic gas charging in the Ahnet-Timimoun basin, Algeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cawley, S.J.; Wilson, N.P.; Primmer, T.

1995-08-01

The Ahnet-Timimoun Basin, Southern Algeria, contains significant gas reserves expelled from originally oil prone Silurian and Frasnian shales. The gas is reservoired in Devonian and Carboniferous clastics in inversion anticlines formed, primarily, during the Hercynian orogeny. Integration of organic and inorganic geochemical techniques, such as AFTA, ZFTA, fluid inclusion analysis, vitrinite and chitinizoan reflectance, is entirely consistent with gas generation 300 +/- 30MY, immediately prior to or synchronous with the Hercynian orogeny. Data from gas fields has shown the remobilisation of gas during post Hercynian tectonics. A {open_quotes}two-event{close_quotes} heating/cooling history is proposed: (1) Maximum burial and palaeotemperature at ca. 300more » +/- 30MY prior to or synchronous with Hercynian uplift and cooling. (2) Cooling from a secondary peak (lower than maximum) palaeotemperature at ca. 30-60My following Creataceous burial. Calibrated thermal modelling indicates that Palaeozoic source rocks were heated above 200{degrees}C in the Late Carboniferous. Such high temperatures are consistent with the widespread occurrence of pyrophyllite in Silurian shales. Two end-member thermal models can account for the observed maturities. The first is a constant high Pre-Hercynian heat flow which rapidly decreases during Hercynian uplift to remain at Present day values of 50-75mW/m{sup 2}. Gas expulsion in this case commences much earlier than trap formation. The second is {open_quotes}normal{close_quotes} heat flow of ca. 50mW/m{sup 2} until ca. 310My with a rapid increase at ca. 290My followed by an equally rapid drop to constant present day values - in this model, petroleum generation and expulsion is late in relation to structuring.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nabeel A. Riza

The goals of the first six months of this project were to begin laying the foundations for both the SiC front-end optical chip fabrication techniques for high pressure gas species sensing as well as the design, assembly, and test of a portable high pressure high temperature calibration test cell chamber for introducing gas species. This calibration cell will be used in the remaining months for proposed first stage high pressure high temperature gas species sensor experimentation and data processing. All these goals have been achieved and are described in detail in the report. Both design process and diagrams for themore » mechanical elements as well as the optical systems are provided. Photographs of the fabricated calibration test chamber cell, the optical sensor setup with the calibration cell, the SiC sample chip holder, and relevant signal processing mathematics are provided. Initial experimental data from both the optical sensor and fabricated test gas species SiC chips is provided. The design and experimentation results are summarized to give positive conclusions on the proposed novel high temperature high pressure gas species detection optical sensor technology.« less

Calibration of Relative Humidity Devices in Low-pressure, Low-temperature CO2 Environment

NASA Astrophysics Data System (ADS)

Genzer, Maria; Polkko, Jouni; Nikkanen, Timo; Hieta, Maria; Harri, Ari-Matti

2017-04-01

Calibration of relative humidity devices requires in minimum two humidity points - dry (0%RH) and (near)saturation (95-100%RH) - over the expected operational temperature and pressure range of the device. In terrestrial applications these are relatively easy to achieve using for example N2 gas as dry medium, and water vapor saturation chambers for producing saturation and intermediate humidity points. But for example in applications intended for meteorological measurements on Mars there is a need to achieve at least dry and saturation points in low-temperature, low-pressure CO2 environment. We have developed a custom-made, small, relatively low-cost calibration chamber able to produce both dry points and saturation points in Martian range pressure CO2, in temperatures down to -70°C. The system utilizes a commercially available temperature chamber for temperature control, vacuum vessels and pumps. The main pressure vessel with the devices under test inside is placed inside the temperature chamber, and the pressure inside is controlled by pumps and manual valves and monitored with a commercial pressure reference with calibration traceable to national standards. Air, CO2, or if needed another gas like N2, is used for filling the vessel until the desired pressure is achieved. Another pressure vessel with a dedicated pressure pump is used as the saturation chamber. This vessel is placed in the room outside the temperature chamber, partly filled with water and used for achieving saturated water vapor in room-temperature low-pressure environment. The saturation chamber is connected to the main pressure vessel via valves. In this system dry point, low-pressure CO2 environment is achieved by filling the main pressure vessel with dry CO2 gas until the desired pressure is achieved. A constant flow of gas is maintained with the pump and valves and monitored with the pressure reference. The saturation point is then achieved by adding some water vapor from the saturation chamber to the main pressure vessel. The amount of water vapor added is also monitored with the pressure reference. For example in -70°C, very small absolute amount of water vapor corresponding to 1 Pa [1][2] pressure rise in the main chamber results in humidity saturation. As the flow of both CO2 and water vapor is kept constant, the main chamber is served with water vapor all the time, keeping the uniform saturation conditions inside the vessel even if some of the water freezes on the vessel and pipe walls. [1] Goff, J. A., and S. Gratch (1946) Low-pressure properties of water from -160 to 212 °F, Transactions of the American Society of Heating and Ventilating Engineers [2] Goff, J. A. (1957) Saturation pressure of water on the new Kelvin temperature scale, Transactions of the American Society of Heating and Ventilating Engineers

Aero-Thermal Calibration of the NASA Glenn Icing Research Tunnel (2012 Test)

NASA Technical Reports Server (NTRS)

Pastor-Barsi, Christine M.; Arrington, E. Allen; VanZante, Judith Foss

2012-01-01

A major modification of the refrigeration plant and heat exchanger at the NASA Glenn Icing Research Tunnel (IRT) occurred in autumn of 2011. It is standard practice at NASA Glenn to perform a full aero-thermal calibration of the test section of a wind tunnel facility upon completion of major modifications. This paper will discuss the tools and techniques used to complete an aero-thermal calibration of the IRT and the results that were acquired. The goal of this test entry was to complete a flow quality survey and aero-thermal calibration measurements in the test section of the IRT. Test hardware that was used includes the 2D Resistive Temperature Detector (RTD) array, 9-ft pressure survey rake, hot wire survey rake, and the quick check survey rake. This test hardware provides a map of the velocity, Mach number, total and static pressure, total temperature, flow angle and turbulence intensity. The data acquired were then reduced to examine pressure, temperature, velocity, flow angle, and turbulence intensity. Reduced data has been evaluated to assess how the facility meets flow quality goals. No icing conditions were tested as part of the aero-thermal calibration. However, the effects of the spray bar air injections on the flow quality and aero-thermal calibration measurements were examined as part of this calibration.

Portable Dew Point Mass Spectrometry System for Real-Time Gas and Moisture Analysis

NASA Technical Reports Server (NTRS)

Arkin, C.; Gillespie, Stacey; Ratzel, Christopher

2010-01-01

A portable instrument incorporates both mass spectrometry and dew point measurement to provide real-time, quantitative gas measurements of helium, nitrogen, oxygen, argon, and carbon dioxide, along with real-time, quantitative moisture analysis. The Portable Dew Point Mass Spectrometry (PDP-MS) system comprises a single quadrupole mass spectrometer and a high vacuum system consisting of a turbopump and a diaphragm-backing pump. A capacitive membrane dew point sensor was placed upstream of the MS, but still within the pressure-flow control pneumatic region. Pressure-flow control was achieved with an upstream precision metering valve, a capacitance diaphragm gauge, and a downstream mass flow controller. User configurable LabVIEW software was developed to provide real-time concentration data for the MS, dew point monitor, and sample delivery system pressure control, pressure and flow monitoring, and recording. The system has been designed to include in situ, NIST-traceable calibration. Certain sample tubing retains sufficient water that even if the sample is dry, the sample tube will desorb water to an amount resulting in moisture concentration errors up to 500 ppm for as long as 10 minutes. It was determined that Bev-A-Line IV was the best sample line to use. As a result of this issue, it is prudent to add a high-level humidity sensor to PDP-MS so such events can be prevented in the future.

Down scaled Kjeldahl digestion and flow injection conductometric system for determination of protein content in some traditional northern Thai foods.

PubMed

Yanu, Pattama; Jakmunee, Jaroon

2017-09-01

A flow injection conductometric (FIC) system for determination of total Kjeldahl nitrogen (TKN) was developed for estimating total protein content in food. A small scale Kjeldahl digestion was performed with a short digestion time of only 20min. The digested solution was injected into the FIC system, and TKN was converted to ammonia gas in an alkaline donor stream of the system. The gas diffused through a membrane and dissolved into an acceptor stream causing an increase in conductivity as detected by a detector and recorded as a peak. Under the optimum condition, a linear calibration graph in the range of 4.00-100.00mgL -1 was obtained with LOD of 0.05mgL -1 . A good precision (0.04% RSD, n=11, 30.00mgNL -1 ) and high sample throughput of 72h -1 was achieved. The method was applied for determination of protein in some traditional northern Thai foods, revealing that they are good sources of proteins. Copyright © 2017 Elsevier Ltd. All rights reserved.

Nicotine, acetanilide and urea multi-level 2H-, 13C- and 15N-abundance reference materials for continuous-flow isotope ratio mass spectrometry.

PubMed

Schimmelmann, Arndt; Albertino, Andrea; Sauer, Peter E; Qi, Haiping; Molinie, Roland; Mesnard, François

2009-11-01

Accurate determinations of stable isotope ratios require a calibration using at least two reference materials with different isotopic compositions to anchor the isotopic scale and compensate for differences in machine slope. Ideally, the delta values of these reference materials should bracket the isotopic range of samples with unknown delta values. While the practice of analyzing two isotopically distinct reference materials is common for water (VSMOW-SLAP) and carbonates (NBS 19 and L-SVEC), the lack of widely available organic reference materials with distinct isotopic composition has hindered the practice when analyzing organic materials by elemental analysis/isotope ratio mass spectrometry (EA-IRMS). At present only L-glutamic acids USGS40 and USGS41 satisfy these requirements for delta13C and delta15N, with the limitation that L-glutamic acid is not suitable for analysis by gas chromatography (GC). We describe the development and quality testing of (i) four nicotine laboratory reference materials for on-line (i.e. continuous flow) hydrogen reductive gas chromatography-isotope ratio mass-spectrometry (GC-IRMS), (ii) five nicotines for oxidative C, N gas chromatography-combustion-isotope ratio mass-spectrometry (GC-C-IRMS, or GC-IRMS), and (iii) also three acetanilide and three urea reference materials for on-line oxidative EA-IRMS for C and N. Isotopic off-line calibration against international stable isotope measurement standards at Indiana University adhered to the 'principle of identical treatment'. The new reference materials cover the following isotopic ranges: delta2H(nicotine) -162 to -45 per thousand, delta13C(nicotine) -30.05 to +7.72 per thousand, delta15N(nicotine) -6.03 to +33.62 per thousand; delta15N(acetanilide) +1.18 to +40.57 per thousand; delta13C(urea) -34.13 to +11.71 per thousand, delta15N(urea) +0.26 to +40.61 per thousand (recommended delta values refer to calibration with NBS 19, L-SVEC, IAEA-N-1, and IAEA-N-2). Nicotines fill a gap as the first organic nitrogen stable isotope reference materials for GC-IRMS that are available with different delta15N values. Comparative delta13C and delta15N on-line EA-IRMS data from 14 volunteering laboratories document the usefulness and reliability of acetanilides and ureas as EA-IRMS reference materials. Copyright 2009 John Wiley & Sons, Ltd.

Streamflow characteristics from modelled runoff time series: Importance of calibration criteria selection

USGS Publications Warehouse

Poole, Sandra; Vis, Marc; Knight, Rodney; Seibert, Jan

2017-01-01

Ecologically relevant streamflow characteristics (SFCs) of ungauged catchments are often estimated from simulated runoff of hydrologic models that were originally calibrated on gauged catchments. However, SFC estimates of the gauged donor catchments and subsequently the ungauged catchments can be substantially uncertain when models are calibrated using traditional approaches based on optimization of statistical performance metrics (e.g., Nash–Sutcliffe model efficiency). An improved calibration strategy for gauged catchments is therefore crucial to help reduce the uncertainties of estimated SFCs for ungauged catchments. The aim of this study was to improve SFC estimates from modeled runoff time series in gauged catchments by explicitly including one or several SFCs in the calibration process. Different types of objective functions were defined consisting of the Nash–Sutcliffe model efficiency, single SFCs, or combinations thereof. We calibrated a bucket-type runoff model (HBV – Hydrologiska Byråns Vattenavdelning – model) for 25 catchments in the Tennessee River basin and evaluated the proposed calibration approach on 13 ecologically relevant SFCs representing major flow regime components and different flow conditions. While the model generally tended to underestimate the tested SFCs related to mean and high-flow conditions, SFCs related to low flow were generally overestimated. The highest estimation accuracies were achieved by a SFC-specific model calibration. Estimates of SFCs not included in the calibration process were of similar quality when comparing a multi-SFC calibration approach to a traditional model efficiency calibration. For practical applications, this implies that SFCs should preferably be estimated from targeted runoff model calibration, and modeled estimates need to be carefully interpreted.

Quantification of methane fluxes from hydrocarbon seeps to the ocean and atmosphere: Development of an in situ and online gas flux measuring system

NASA Astrophysics Data System (ADS)

Di, Pengfei; Chen, Qinghua; Chen, Duofu

2017-06-01

Natural hydrocarbon seeps in the marine environment are important contributors to greenhouse gases in the atmosphere. Such gases include methane, which plays a significant role in global carbon cycling and climate change. To accurately quantify the methane flux from hydrocarbon seeps on the seafloor, a specialized in situ and online gas flux measuring (GFM) device was designed to obtain high-resolution time course gas fluxes using the process of equal volume exchange. The device consists of a 1.0-m diameter, 0.9-m tall, inverted conical tent and a GFM instrument that contains a solenoid valve, level transducer, and gas collection chamber. Rising gas bubbles from seeps were measured by laboratory-calibrated GFM instruments attached to the top of the tent. According to the experimental data, the optimal anti-shake time interval was 5 s. The measurement range of the device was 0-15 L min-1, and the relative error was ± 1.0%. The device was initially deployed at an active seep site in the Lingtou Promontory seep field in South China Sea. The amount of gas released from a single gas vent was 30.5 m3 during the measurement period, and the gas flow rate ranged from 22 to 72 L h-1, depending on tidal period, and was strongly negatively correlated with water depth. The measurement results strongly suggest that oceanic tides and swells had a significant forcing effect on gas flux. Low flow rates were associated with high tides and vice versa. The changes in gas volume escaping from the seafloor seeps could be attributed to the hydrostatic pressure induced by water depth. Our findings suggest that in the marine environment, especially in the shallow shelf area, sea level variation may play an important role in controlling methane release into the ocean. Such releases probably also affect atmospheric methane levels.

77 FR 64588 - Highway Safety Programs; Conforming Products List of Calibrating Units for Breath Alcohol Testers

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-22

... accuracy and precision for wet bath and dry gas calibrating units using infra-red spectroscopy. On June 25... infra-red spectroscopy (72 FR 34742). That notice also adds references to the dry gas standards by fixed...

Quartz Crystal Microbalance: Aerosol Viscoelastic Measurement Calibration and Subsiquent H2O Uptake

NASA Astrophysics Data System (ADS)

Farland, D. R., Jr.; Gilles, M. K.; Harder, T.; Weis, J.; Mueller, S.

2015-12-01

Aerosol particles exposed to various atmospheric relative humidity (RH) levels exhibit hygroscopic properties which are not fully understood. Water adsorption or diffusion depends on particle viscosity in semi-solid to liquid states. This relationship between particle viscosity as a function of RH and the corresponding hygroscopic behavioral response is the purpose of this study. However, reliable techniques for viscosity quantification have been limited. A Quartz Crystal Microbalance with Dissipation (QCM-D) was used for viscosity measurements and to determine phase changes. Prior to studies on field samples, microscope immersion/viscosity standard oils, salt crystals, sugars and alpha-pinene secondary organic aerosol (SOA) surrogates are used for viscosity, RH calibrations, water uptake and phase change measurements. RH was controlled by flowing N2 gas saturated with H2O for RH's between 0-75% RH. For higher RH values, (75-100% RH range) saturated salt solutions were flowed over a gore membrane to protect the QCM sensor from direct contact with the solutions. The viscosity calibration constructed via QTools fitting software illustrates the limitations as well as the ranges of reliability of the QCM viscosity measurements. Deliquescing salt crystals of differing deliquescence relative humidity's (DRH), sugars and alpha-pinene SOA's provided insight into the detection of various phase change behaviors. Water uptake experiments performed on alpha-pinene SOA and sucrose sugar yielded significantly different frequency and dissipation responses than the deliquescing salts. Future work will apply these experimental methods and analysis on aerosol particles collected during the GoAmazon field campaign.

Engineering Test Report Paint Waste Reduction Fluidized Bed Process Demonstration at Letterkenny Army Depot Chambersburg, Pennsylvania

DTIC Science & Technology

1991-07-01

predicted by equation using actual chart response obtained from each calibration gas response. (Concentration of cal. gas,l Calibration error, % span • ppm...Analyzer predicted by cali- Col. gas Chart divisions equation* bration Cylinder conc., error,** Drift,***INo. ppm or % Pretest Posttest Pretest Posttest...2m ~J * Correlation coef. * qgq’jq **Analyzer ca.error, % spn (Cal. gas conc. conc. predicted ) x 1003 cal spanSpan value Acceptable limit x ɚ% of

Quantitative Spectral Radiance Measurements in the HYMETS Arc Jet

NASA Technical Reports Server (NTRS)

Danehy, Paul M.; Hires, Drew V.; Johansen, Craig T.; Bathel, Brett F.; Jones, Stephen B.; Gragg, Jeffrey G.; Splinter, Scott C.

2012-01-01

Calibrated spectral radiance measurements of gaseous emission spectra have been obtained from the HYMETS (Hypersonic Materials Environmental Test System) 400 kW arc-heated wind tunnel at NASA Langley Research Center. A fiber-optic coupled spectrometer collected natural luminosity from the flow. Spectral radiance measurements are reported between 340 and 1000 nm. Both Silicon Carbide (SiC) and Phenolic Impregnated Carbon Ablator (PICA) samples were placed in the flow. Test gases studied included a mostly-N2 atmosphere (95% nitrogen, 5% argon), a simulated Earth Air atmosphere (75% nitrogen, 20% oxygen, 5% argon) and a simulated Martian atmosphere (71% carbon dioxide, 24% nitrogen, 5% argon). The bulk enthalpy of the flow was varied as was the location of the measurement. For the intermediate flow enthalpy tested (20 MJ/kg), emission from the Mars simulant gas was about 10 times higher than the Air flow and 15 times higher than the mostly-N2 atmosphere. Shock standoff distances were estimated from the spectral radiance measurements. Within-run, run-to-run and day-to-day repeatability of the emission were studied, with significant variations (15-100%) noted.

Improved method for calibration of exchange flows for a physical transport box model of Tampa Bay, FL USA

EPA Science Inventory

Results for both sequential and simultaneous calibration of exchange flows between segments of a 10-box, one-dimensional, well-mixed, bifurcated tidal mixing model for Tampa Bay are reported. Calibrations were conducted for three model options with different mathematical expressi...

Introduction of the 2007-2008 JOGMEC/NRCan/Aurora Mallik Gas Hydrate Production Research Program, NWT, Canada

NASA Astrophysics Data System (ADS)

Yamamoto, K.; Dallimore, S. R.; Numasawa, M.; Yasuda, M.; Fujii, T.; Fujii, K.; Wright, J.; Nixon, F.

2007-12-01

Japan Oil, Gas and Metals National Corporation (JOGMEC) and Natural Resource Canada (NRCan) have embarked on a new research program to study the production potential of gas hydrates. The program is being carried out at the Mallik gas hydrate field in the Mackenzie Delta, a location where two previous scientific investigations have been carried in 1998 and 2002. In the 2002 program that was undertaken by seven partners from five countries, 468m3 of gas flow was measured during 124 hours of thermal stimulation using hot warm fluid. Small-scale pressure drawdown tests were also carried out using Schlumberger's Modular Dynamics Tester (MDT) wireline tool, gas flow was observed and the inferred formation permeabilities suggested the possible effectiveness of the simple depressurization method. While the testing undertaken in 2002 can be cited as the first well constrained gas production from a gas hydrate deposit, the results fell short of that required to fully calibrate reservoir simulation models or indeed establish the technical viability of long term production from gas hydrates. The objectives of the current JOGMEC/NRCan/Aurora Mallik production research program are to undertake longer term production testing to further constrain the scientific unknowns and to demonstrate the technical feasibility of sustained gas hydrate production using the depressurization method. A key priority is to accurately measure water and gas production using state-of-art production technologies. The primary production test well was established during the 2007 field season with the re-entry and deepening of JAPEX/JNOC/GSC Mallik 2L-38 well, originally drilled in 1998. Production testing was carried out in April of 2007 under a relatively low drawdown pressure condition. Flow of methane gas was measured from a 12m perforated interval of gas-hydrate-saturated sands from 1093 to 1105m. The results establish the potential of the depressurization method and provide a basis for future prolonged testing planned in the near future. The authors acknowledge the Research Consortium for Methane Hydrate Resources in Japan (MH21), the Ministry of Economy, Trade and Industry (METI) and NRCan for the support and funding. The Mallik 2002 program was undertaken jointly by JNOC, NRCan, GeoForschungsZentrum Potsdam (GFZ), the United State Geological Survey (USGS), the United States Department of Energy (USDOE), the India Ministry of Petroleum and Natural Gas (MOPNG)-Gas Authority of India (GAIL), and the BP-Chevron Texaco Mackenzie Delta Joint Venture.

International Space Station (ISS)

NASA Image and Video Library

2003-01-16

In this International Space Station (ISS) onboard photo, Expedition Six Science Officer Donald R. Pettit works to set up the Pulmonary Function in Flight (PuFF) experiment hardware in the Destiny Laboratory. Expedition Six is the fourth and final crew to perform the PuFF experiment. The PuFF experiment was developed to better understand what effects long term exposure to microgravity may have on the lungs. The focus is on measuring changes in the everness of gas exchange in the lungs, and on detecting changes in respiratory muscle strength. It allows astronauts to measure blood flow through the lungs, the ability of the lung to take up oxygen, and lung volumes. Each PuFF session includes five lung function tests, which involve breathing only cabin air. For each planned extravehicular (EVA) activity, a crew member performs a PuFF test within one week prior to the EVA. Following the EVA, those crew members perform another test to document the effect of exposure of the lungs to the low-pressure environment of the space suits. This experiment utilizes the Gas Analyzer System for Metabolic Analysis Physiology, or GASMAP, located in the Human Research Facility (HRF), along with a variety of other Puff equipment including a manual breathing valve, flow meter, pressure-flow module, pressure and volume calibration syringes, and disposable mouth pieces.

Pulmonary Function in Flight (PuFF) Experiment

NASA Technical Reports Server (NTRS)

2003-01-01

In this International Space Station (ISS) onboard photo, Expedition Six Science Officer Donald R. Pettit works to set up the Pulmonary Function in Flight (PuFF) experiment hardware in the Destiny Laboratory. Expedition Six is the fourth and final crew to perform the PuFF experiment. The PuFF experiment was developed to better understand what effects long term exposure to microgravity may have on the lungs. The focus is on measuring changes in the everness of gas exchange in the lungs, and on detecting changes in respiratory muscle strength. It allows astronauts to measure blood flow through the lungs, the ability of the lung to take up oxygen, and lung volumes. Each PuFF session includes five lung function tests, which involve breathing only cabin air. For each planned extravehicular (EVA) activity, a crew member performs a PuFF test within one week prior to the EVA. Following the EVA, those crew members perform another test to document the effect of exposure of the lungs to the low-pressure environment of the space suits. This experiment utilizes the Gas Analyzer System for Metabolic Analysis Physiology, or GASMAP, located in the Human Research Facility (HRF), along with a variety of other Puff equipment including a manual breathing valve, flow meter, pressure-flow module, pressure and volume calibration syringes, and disposable mouth pieces.

Hydrogen Field Test Standard: Laboratory and Field Performance

PubMed Central

Pope, Jodie G.; Wright, John D.

2015-01-01

The National Institute of Standards and Technology (NIST) developed a prototype field test standard (FTS) that incorporates three test methods that could be used by state weights and measures inspectors to periodically verify the accuracy of retail hydrogen dispensers, much as gasoline dispensers are tested today. The three field test methods are: 1) gravimetric, 2) Pressure, Volume, Temperature (PVT), and 3) master meter. The FTS was tested in NIST's Transient Flow Facility with helium gas and in the field at a hydrogen dispenser location. All three methods agree within 0.57 % and 1.53 % for all test drafts of helium gas in the laboratory setting and of hydrogen gas in the field, respectively. The time required to perform six test drafts is similar for all three methods, ranging from 6 h for the gravimetric and master meter methods to 8 h for the PVT method. The laboratory tests show that 1) it is critical to wait for thermal equilibrium to achieve density measurements in the FTS that meet the desired uncertainty requirements for the PVT and master meter methods; in general, we found a wait time of 20 minutes introduces errors < 0.1 % and < 0.04 % in the PVT and master meter methods, respectively and 2) buoyancy corrections are important for the lowest uncertainty gravimetric measurements. The field tests show that sensor drift can become a largest component of uncertainty that is not present in the laboratory setting. The scale was calibrated after it was set up at the field location. Checks of the calibration throughout testing showed drift of 0.031 %. Calibration of the master meter and the pressure sensors prior to travel to the field location and upon return showed significant drifts in their calibrations; 0.14 % and up to 1.7 %, respectively. This highlights the need for better sensor selection and/or more robust sensor testing prior to putting into field service. All three test methods are capable of being successfully performed in the field and give equivalent answers if proper sensors without drift are used. PMID:26722192

A Technique for Murine Irradiation in a Controlled Gas Environment

PubMed Central

Walb, M. C.; Moore, J. E.; Attia, A.; Wheeler, K. T.; Miller, M. S.; Munley, M. T.

2013-01-01

NASA’s extra-vehicular activities (EVAs) involve exposure to high energy photons while breathing 100% oxygen. Using previously verified mouse models, our laboratory is studying whether low dose irradiation under these hyperoxic conditions could lead to an increase in carcinogenic potential. To simulate the environment astronauts encounter during an EVA, enclosed chambers were constructed that allowed for mouse movement, controlled gas conditions, and uniform radiation dose delivery. Custom-built gas chambers with input/output gas valves and dividers that allowed for uniform gas flow were used to keep 6 unanesthetized mice separated while they were irradiated. The chambers were supplied with 100% oxygen or air using ball valves linked together with T-splitters. A calibrated ion chamber was used to verify the radiation dose distribution across an entire chamber. Mice were placed in the gas environments for 0.5 h, irradiated with a 10 or 18 MV photon beam from a medical linear accelerator, and left in their gas environment for 2 h post-irradiation. We irradiated 200 mice (5 different doses between 0–1000 mGy) under normoxic or 100% oxygen conditions. For the next step of this research, these mice will be euthanized 9 months post-irradiation, and lung tumors will be counted and sized to determine if hyperoxia increases the carcinogenic effect for this model. PMID:22846321

Optical bio-sniffer for ethanol vapor using an oxygen-sensitive optical fiber.

PubMed

Mitsubayashi, Kohji; Kon, Takuo; Hashimoto, Yuki

2003-11-30

An optical bio-sniffer for ethanol was constructed by immobilizing alcohol oxidase (AOD) onto a tip of a fiber optic oxygen sensor with a tube-ring, using an oxygen sensitive ruthenium organic complex (excitation, 470 nm; fluorescent, 600 nm). A reaction unit for circulating buffer solution was applied to the tip of the device. After the experiment in the liquid phase, the sniffer-device was applied for gas analysis using a gas flow measurement system with a gas generator. The optical device was applied to detect the oxygen consumption induced by AOD enzymatic reaction with alcohol application. The sensor in the liquid phase was used to measure ethanol solution from 0.50 to 9.09 mmol/l. Then, the bio-sniffer was calibrated against ethanol vapor from 0.71 to 51.49 ppm with good gas-selectivity based on the AOD substrate specificity. The bio-sniffer with the reaction unit was also used to monitor the concentration change of gaseous ethanol by rinsing and cleaning the fiber tip and the enzyme membrane with buffer solution.

Simulation of natural flows in major river basins in Alabama

USGS Publications Warehouse

Hunt, Alexandria M.; García, Ana María

2014-01-01

The Office of Water Resources (OWR) in the Alabama Department of Economic and Community Affairs (ADECA) is charged with the assessment of the State’s water resources. This study developed a watershed model for the major river basins that are within Alabama or that cross Alabama’s borders, which serves as a planning tool for water-resource decisionmakers. The watershed model chosen to assess the natural amount of available water was the Precipitation-Runoff Modeling System (PRMS). Models were configured and calibrated for the following four river basins: Mobile, Gulf of Mexico, Middle Tennessee, and Chattahoochee. These models required calibrating unregulated U.S. Geological Survey (USGS) streamflow gaging stations to estimate natural flows, with emphases on low-flow calibration. The target calibration criteria required the errors be within the range of: (1) ±10 percent for total-streamflow volume, (2) ±10 percent for low-flow volume, (3) ±15 percent for high-flow volume, (4) ±30 percent for summer volume, and (5) above 0.5 for the correlation coefficient (R2). Seventy-one of the 90 calibration stations in the watershed models for the four major river basins within Alabama met the target calibration criteria. Variability in the model performance can be attributed to limitations in correctly representing certain hydrologic conditions that are characterized by some of the ecoregions in Alabama. Ecoregions consisting of predominantly clayey soils and (or) low topographic relief yield less successful calibration results, whereas ecoregions consisting of loamy and sandy soils and (or) high topographic relief yield more successful calibration results. Results indicate that the model does well in hilly regions with sandy soils because of rapid surface runoff and more direct interaction with subsurface flow.

Evaluation of hydrocarbon flow standard facility equipped with double-wing diverter using four types of working liquids

NASA Astrophysics Data System (ADS)

Doihara, R.; Shimada, T.; Cheong, K. H.; Terao, Y.

2017-06-01

A flow calibration facility based on the gravimetric method using a double-wing diverter for hydrocarbon flows from 0.1 m3 h-1 to 15 m3 h-1 was constructed as a national measurement standard in Japan. The original working liquids were kerosene and light oil. The calibration facility was modified to calibrate flowmeters with two additional working liquids, industrial gasoline (flash point  >  40 °C) and spindle oil, to achieve calibration over a wide viscosity range at the same calibration test rig. The kinematic viscosity range is 1.2 mm2 s-1 to 24 mm2 s-1. The contributions to the measurement uncertainty due to different types of working liquids were evaluated experimentally in this study. The evaporation error was reduced by using a seal system at the weighing tank inlet. The uncertainty due to droplets from the diverter wings was reduced by a modified diverter operation. The diverter timing errors for all types of working liquids were estimated. The expanded uncertainties for the calibration facility were estimated to be 0.020% for mass flow and 0.030% for volumetric flow for all considered types of liquids. Internal comparisons with other calibration facilities were also conducted, and the agreement was confirmed to be within the claimed expanded uncertainties.

Calibration of diffuse correlation spectroscopy blood flow index with venous-occlusion diffuse optical spectroscopy in skeletal muscle

PubMed Central

Li, Zhe; Baker, Wesley B.; Parthasarathy, Ashwin B.; Ko, Tiffany S.; Wang, Detian; Schenkel, Steven; Durduran, Turgut; Li, Gang; Yodh, Arjun G.

2015-01-01

Abstract. We investigate and assess the utility of a simple scheme for continuous absolute blood flow monitoring based on diffuse correlation spectroscopy (DCS). The scheme calibrates DCS using venous-occlusion diffuse optical spectroscopy (VO-DOS) measurements of arm muscle tissue at a single time-point. A calibration coefficient (γ) for the arm is determined, permitting conversion of DCS blood flow indices to absolute blood flow units, and a study of healthy adults (N=10) is carried out to ascertain the variability of γ. The average DCS calibration coefficient for the right (i.e., dominant) arm was γ=(1.24±0.15)×108 (mL·100  mL−1·min−1)/(cm2/s). However, variability can be significant and is apparent in our site-to-site and day-to-day repeated measurements. The peak hyperemic blood flow overshoot relative to baseline resting flow was also studied following arm-cuff ischemia; excellent agreement between VO-DOS and DCS was found (R2=0.95, slope=0.94±0.07, mean difference=−0.10±0.45). Finally, we show that incorporation of subject-specific absolute optical properties significantly improves blood flow calibration accuracy. PMID:26720870

Calibration and use of filter test facility orifice plates

NASA Astrophysics Data System (ADS)

Fain, D. E.; Selby, T. W.

1984-07-01

There are three official DOE filter test facilities. These test facilities are used by the DOE, and others, to test nuclear grade HEPA filters to provide Quality Assurance that the filters meet the required specifications. The filters are tested for both filter efficiency and pressure drop. In the test equipment, standard orifice plates are used to set the specified flow rates for the tests. There has existed a need to calibrate the orifice plates from the three facilities with a common calibration source to assure that the facilities have comparable tests. A project has been undertaken to calibrate these orifice plates. In addition to reporting the results of the calibrations of the orifice plates, the means for using the calibration results will be discussed. A comparison of the orifice discharge coefficients for the orifice plates used at the seven facilities will be given. The pros and cons for the use of mass flow or volume flow rates for testing will be discussed. It is recommended that volume flow rates be used as a more practical and comparable means of testing filters. The rationale for this recommendation will be discussed.

40 CFR 86.121-90 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2013 CFR

2013-07-01

... used operating range with propane in air calibration gases (either methanol or methane in air as... response factor to methane. When the FID analyzer is to be used for the analysis of gasoline, diesel, methanol, ethanol, liquefied petroleum gas, and natural gas-fueled vehicle hydrocarbon samples, the methane...

40 CFR 86.121-90 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2014 CFR

2014-07-01

... used operating range with propane in air calibration gases (either methanol or methane in air as... response factor to methane. When the FID analyzer is to be used for the analysis of gasoline, diesel, methanol, ethanol, liquefied petroleum gas, and natural gas-fueled vehicle hydrocarbon samples, the methane...

40 CFR 86.121-90 - Hydrocarbon analyzer calibration.

Code of Federal Regulations, 2012 CFR

2012-07-01

... used operating range with propane in air calibration gases (either methanol or methane in air as... response factor to methane. When the FID analyzer is to be used for the analysis of gasoline, diesel, methanol, ethanol, liquefied petroleum gas, and natural gas-fueled vehicle hydrocarbon samples, the methane...

A Combined Micro-CT Imaging/Microfluidic Approach for Understating Methane Recovery in Coal Seam Gas Reservoirs

NASA Astrophysics Data System (ADS)

Mostaghimi, P.; Armstrong, R. T.; Gerami, A.; Lamei Ramandi, H.; Ebrahimi Warkiani, M.

2015-12-01

Coal seam methane is a form of natural gas stored in coal beds and is one of the most important unconventional resources of energy. The flow and transport in coal beds occur in a well-developed system of natural fractures that are also known as cleats. We use micro-Computed Tomography (CT) imaging at both dry and wet conditions to resolve the cleats below the resolution of the image. Scanning Electron Microscopy (SEM) is used for calibration of micro-CT data. Using soft lithography technique, the cleat system is duplicated on a silicon mould. We fabricate a microfluidic chip using Polydimethylsiloxane (PDMS) to study both imbibition and drainage in generated coal structures for understating gas and water transport in coal seam reservoirs. First, we use simple patterns observed on coal images to analyse the effects of wettability, cleat size and distribution on flow behaviour. Then, we study transport in a coal by injecting both distilled water and decane with a rate of 1 microliter/ min into the fabricated cleat structure (Figure 1), initially saturated with air. We repeat the experiment for different contact angles by plasma treating the microfluidic chip, and results show significant effects of wettability on the displacement efficiency. The breakthrough time in the imbibition setup is significantly longer than in the drainage. Using rapid video capturing, and high resolution microscopy, we measure the saturation of displacing fluid with respect to time. By measuring gas and liquid recovery in the outlet at different saturation, we predict relative permeability of coal. This work has important applications for optimising gas recovery and our results can serve as a benchmark in the verification of multiphase numerical models used in coal seam gas industry.

Flow Control and Measurement in Electric Propulsion Systems: Towards an AIAA Reference Standard

NASA Technical Reports Server (NTRS)

Snyder, John Steven; Baldwin, Jeff; Frieman, Jason D.; Walker, Mitchell L. R.; Hicks, Nathan S.; Polzin, Kurt A.; Singleton, James T.

2013-01-01

Accurate control and measurement of propellant flow to a thruster is one of the most basic and fundamental requirements for operation of electric propulsion systems, whether they be in the laboratory or on flight spacecraft. Hence, it is important for the electric propulsion community to have a common understanding of typical methods for flow control and measurement. This paper addresses the topic of propellant flow primarily for the gaseous propellant systems which have dominated laboratory research and flight application over the last few decades, although other types of systems are also briefly discussed. While most flight systems have employed a type of pressure-fed flow restrictor for flow control, both thermal-based and pressure-based mass flow controllers are routinely used in laboratories. Fundamentals and theory of operation of these types of controllers are presented, along with sources of uncertainty associated with their use. Methods of calibration and recommendations for calibration processes are presented. Finally, details of uncertainty calculations are presented for some common calibration methods and for the linear fits to calibration data that are commonly used.

Flight calibration tests of a nose-boom-mounted fixed hemispherical flow-direction sensor

NASA Technical Reports Server (NTRS)

Armistead, K. H.; Webb, L. D.

1973-01-01

Flight calibrations of a fixed hemispherical flow angle-of-attack and angle-of-sideslip sensor were made from Mach numbers of 0.5 to 1.8. Maneuvers were performed by an F-104 airplane at selected altitudes to compare the measurement of flow angle of attack from the fixed hemispherical sensor with that from a standard angle-of-attack vane. The hemispherical flow-direction sensor measured differential pressure at two angle-of-attack ports and two angle-of-sideslip ports in diametrically opposed positions. Stagnation pressure was measured at a center port. The results of these tests showed that the calibration curves for the hemispherical flow-direction sensor were linear for angles of attack up to 13 deg. The overall uncertainty in determining angle of attack from these curves was plus or minus 0.35 deg or less. A Mach number position error calibration curve was also obtained for the hemispherical flow-direction sensor. The hemispherical flow-direction sensor exhibited a much larger position error than a standard uncompensated pitot-static probe.

Scientific assessment of the quality of OSIRIS images

NASA Astrophysics Data System (ADS)

Tubiana, C.; Güttler, C.; Kovacs, G.; Bertini, I.; Bodewits, D.; Fornasier, S.; Lara, L.; La Forgia, F.; Magrin, S.; Pajola, M.; Sierks, H.; Barbieri, C.; Lamy, P. L.; Rodrigo, R.; Koschny, D.; Rickman, H.; Keller, H. U.; Agarwal, J.; A'Hearn, M. F.; Barucci, M. A.; Bertaux, J.-L.; Besse, S.; Boudreault, S.; Cremonese, G.; Da Deppo, V.; Davidsson, B.; Debei, S.; De Cecco, M.; El-Maarry, M. R.; Fulle, M.; Groussin, O.; Gutiérrez-Marques, P.; Gutiérrez, P. J.; Hoekzema, N.; Hofmann, M.; Hviid, S. F.; Ip, W.-H.; Jorda, L.; Knollenberg, J.; Kramm, J.-R.; Kührt, E.; Küppers, M.; Lazzarin, M.; Lopez Moreno, J. J.; Marzari, F.; Massironi, M.; Michalik, H.; Moissl, R.; Naletto, G.; Oklay, N.; Scholten, F.; Shi, X.; Thomas, N.; Vincent, J.-B.

2015-11-01

Context. OSIRIS, the scientific imaging system onboard the ESA Rosetta spacecraft, has been imaging the nucleus of comet 67P/Churyumov-Gerasimenko and its dust and gas environment since March 2014. The images serve different scientific goals, from morphology and composition studies of the nucleus surface, to the motion and trajectories of dust grains, the general structure of the dust coma, the morphology and intensity of jets, gas distribution, mass loss, and dust and gas production rates. Aims: We present the calibration of the raw images taken by OSIRIS and address the accuracy that we can expect in our scientific results based on the accuracy of the calibration steps that we have performed. Methods: We describe the pipeline that has been developed to automatically calibrate the OSIRIS images. Through a series of steps, radiometrically calibrated and distortion corrected images are produced and can be used for scientific studies. Calibration campaigns were run on the ground before launch and throughout the years in flight to determine the parameters that are used to calibrate the images and to verify their evolution with time. We describe how these parameters were determined and we address their accuracy. Results: We provide a guideline to the level of trust that can be put into the various studies performed with OSIRIS images, based on the accuracy of the image calibration.

Coupling Hydraulic Fracturing Propagation and Gas Well Performance for Simulation of Production in Unconventional Shale Gas Reservoirs

NASA Astrophysics Data System (ADS)

Wang, C.; Winterfeld, P. H.; Wu, Y. S.; Wang, Y.; Chen, D.; Yin, C.; Pan, Z.

2014-12-01

Hydraulic fracturing combined with horizontal drilling has made it possible to economically produce natural gas from unconventional shale gas reservoirs. An efficient methodology for evaluating hydraulic fracturing operation parameters, such as fluid and proppant properties, injection rates, and wellhead pressure, is essential for the evaluation and efficient design of these processes. Traditional numerical evaluation and optimization approaches are usually based on simulated fracture properties such as the fracture area. In our opinion, a methodology based on simulated production data is better, because production is the goal of hydraulic fracturing and we can calibrate this approach with production data that is already known. This numerical methodology requires a fully-coupled hydraulic fracture propagation and multi-phase flow model. In this paper, we present a general fully-coupled numerical framework to simulate hydraulic fracturing and post-fracture gas well performance. This three-dimensional, multi-phase simulator focuses on: (1) fracture width increase and fracture propagation that occurs as slurry is injected into the fracture, (2) erosion caused by fracture fluids and leakoff, (3) proppant subsidence and flowback, and (4) multi-phase fluid flow through various-scaled anisotropic natural and man-made fractures. Mathematical and numerical details on how to fully couple the fracture propagation and fluid flow parts are discussed. Hydraulic fracturing and production operation parameters, and properties of the reservoir, fluids, and proppants, are taken into account. The well may be horizontal, vertical, or deviated, as well as open-hole or cemented. The simulator is verified based on benchmarks from the literature and we show its application by simulating fracture network (hydraulic and natural fractures) propagation and production data history matching of a field in China. We also conduct a series of real-data modeling studies with different combinations of hydraulic fracturing parameters and present the methodology to design these operations with feedback of simulated production data. The unified model aids in the optimization of hydraulic fracturing design, operations, and production.

Calibration of sonic valves for the laminar flow control, leading-edge flight test

NASA Technical Reports Server (NTRS)

Petley, D. H.; Alexander, W., Jr.; Wright, A. S., Jr.; Vallas, M.

1985-01-01

Sonic needle valves were calibrated to measure and control airflow in the suction system for the leading-edge flight test. The procedure and results for the calibration flow test of 4:41 flight valves are given. Mass-flow rates, which ranged from 0.001 to 0.012 lbm/sec, and maximum back pressure were measured for total temperatures from -30 F to 75 F and total pressures from 120 to 540 psf. Correlating equations are obtained for mass-flow rate as a function of total pressure, total temperature, and valve opening length. The most important aspect of flow measurement and control is found to be the measurement of valve opening length.

Probabilistic and Other Neural Nets in Multi-Hole Probe Calibration and Flow Angularity Pattern Recognition

NASA Technical Reports Server (NTRS)

Baskaran, Subbiah; Ramachandran, Narayanan; Noever, David

1998-01-01

The use of probabilistic (PNN) and multilayer feed forward (MLFNN) neural networks are investigated for calibration of multi-hole pressure probes and the prediction of associated flow angularity patterns in test flow fields. Both types of networks are studied in detail for their calibration and prediction characteristics. The current formalism can be applied to any multi-hole probe, however the test results for the most commonly used five-hole Cone and Prism probe types alone are reported in this article.

Natural streamflow simulation for two largest river basins in Poland: a baseline for identification of flow alterations

NASA Astrophysics Data System (ADS)

Piniewski, Mikołaj

2016-05-01

The objective of this study was to apply a previously developed large-scale and high-resolution SWAT model of the Vistula and the Odra basins, calibrated with the focus of natural flow simulation, in order to assess the impact of three different dam reservoirs on streamflow using the Indicators of Hydrologic Alteration (IHA). A tailored spatial calibration approach was designed, in which calibration was focused on a large set of relatively small non-nested sub-catchments with semi-natural flow regime. These were classified into calibration clusters based on the flow statistics similarity. After performing calibration and validation that gave overall positive results, the calibrated parameter values were transferred to the remaining part of the basins using an approach based on hydrological similarity of donor and target catchments. The calibrated model was applied in three case studies with the purpose of assessing the effect of dam reservoirs (Włocławek, Siemianówka and Czorsztyn Reservoirs) on streamflow alteration. Both the assessment based on gauged streamflow (Before-After design) and the one based on simulated natural streamflow showed large alterations in selected flow statistics related to magnitude, duration, high and low flow pulses and rate of change. Some benefits of using a large-scale and high-resolution hydrological model for the assessment of streamflow alteration include: (1) providing an alternative or complementary approach to the classical Before-After designs, (2) isolating the climate variability effect from the dam (or any other source of alteration) effect, (3) providing a practical tool that can be applied at a range of spatial scales over large area such as a country, in a uniform way. Thus, presented approach can be applied for designing more natural flow regimes, which is crucial for river and floodplain ecosystem restoration in the context of the European Union's policy on environmental flows.

Predicting equilibrium states with Reynolds stress closures in channel flow and homogeneous shear flow

NASA Technical Reports Server (NTRS)

Abid, R.; Speziale, C. G.

1993-01-01

Turbulent channel flow and homogeneous shear flow have served as basic building block flows for the testing and calibration of Reynolds stress models. A direct theoretical connection is made between homogeneous shear flow in equilibrium and the log-layer of fully-developed turbulent channel flow. It is shown that if a second-order closure model is calibrated to yield good equilibrium values for homogeneous shear flow it will also yield good results for the log-layer of channel flow provided that the Rotta coefficient is not too far removed from one. Most of the commonly used second-order closure models introduce an ad hoc wall reflection term in order to mask deficient predictions for the log-layer of channel flow that arise either from an inaccurate calibration of homogeneous shear flow or from the use of a Rotta coefficient that is too large. Illustrative model calculations are presented to demonstrate this point which has important implications for turbulence modeling.

Predicting equilibrium states with Reynolds stress closures in channel flow and homogeneous shear flow

NASA Technical Reports Server (NTRS)

Abid, R.; Speziale, C. G.

1992-01-01

Turbulent channel flow and homogeneous shear flow have served as basic building block flows for the testing and calibration of Reynolds stress models. A direct theoretical connection is made between homogeneous shear flow in equilibrium and the log-layer of fully-developed turbulent channel flow. It is shown that if a second-order closure model is calibrated to yield good equilibrium values for homogeneous shear flow it will also yield good results for the log-layer of channel flow provided that the Rotta coefficient is not too far removed from one. Most of the commonly used second-order closure models introduce an ad hoc wall reflection term in order to mask deficient predictions for the log-layer of channel flow that arise either from an inaccurate calibration of homogeneous shear flow or from the use of a Rotta coefficient that is too large. Illustrative model calculations are presented to demonstrate this point which has important implications for turbulence modeling.

Applicability of Monte-Carlo Simulation to Equipment Design of Radioactive Noble Gas Monitor

NASA Astrophysics Data System (ADS)

Sakai, Hirotaka; Hattori, Kanako; Umemura, Norihiro

In the nuclear facilities, radioactive noble gas is continuously monitored by using the radioactive noble gas monitor with beta-sensitive plastic scintillation radiation detector. The detection efficiency of the monitor is generally calibrated by using a calibration loop and standard radioactive noble gases such as 85Kr. In this study, the applicability of PHITS to the equipment design of the radioactive noble gas monitor was evaluated by comparing the calculated results to the test results obtained by actual calibration loop tests to simplify the radiation monitor design evaluation. It was confirmed that the calculated results were well matched to the test results of the monitor after the modeling. In addition, the key parameters for equipment design, such as thickness of detector window or depth of the sampler, were also specified and evaluated.

Unraveling fabrication and calibration of wearable gas monitor for use under free-living conditions.

PubMed

Yue Deng; Cheng Chen; Tsow, Francis; Xiaojun Xian; Forzani, Erica

2016-08-01

Volatile organic compounds (VOC) are organic chemicals that have high vapor pressure at regular conditions. Some VOC could be dangerous to human health, therefore it is important to determine real-time indoor and outdoor personal exposures to VOC. To achieve this goal, our group has developed a wearable gas monitor with a complete sensor fabrication and calibration protocol for free-living conditions. Correction factors for calibrating the sensors, including sensitivity, aging effect, and temperature effect are implemented into a Quick Response Code (QR code), so that the pre-calibrated quartz tuning fork (QTF) sensor can be used with the wearable monitor under free-living conditions.

Nanosecond pulsed humid Ar plasma jet in air: shielding, discharge characteristics and atomic hydrogen production

NASA Astrophysics Data System (ADS)

Yatom, Shurik; Luo, Yuchen; Xiong, Qing; Bruggeman, Peter J.

2017-10-01

Gas phase non-equilibrium plasmas jets containing water vapor are of growing interest for many applications. In this manuscript, we report a detailed study of an atmospheric pressure nanosecond pulsed Ar  +  0.26% H2O plasma jet. The plasma jet operates in an atmospheric pressure air surrounding but is shielded with a coaxial argon flow to limit the air diffusion into the jet effluent core. The jet impinges on a metal plate electrode and produces a stable plasma filament (transient spark) between the needle electrode in the jet and the metal plate. The stable plasma filament is characterized by spatially and time resolved electrical and optical diagnostics. This includes Rayleigh scattering, Stark broadening of the hydrogen Balmer lines and two-photon absorption laser induced fluorescence (TaLIF) to obtain the gas temperature, the electron density and the atomic hydrogen density respectively. Electron densities and atomic hydrogen densities up to 5 × 1022 m-3 and 2 × 1022 m-3 have been measured. This shows that atomic hydrogen is one of the main species in high density Ar-H2O plasmas. The gas temperature does not exceed 550 K in the core of the plasma. To enable in situ calibration of the H TaLIF at atmospheric pressure a previously published O density calibration scheme is extended to include a correction for the line profiles by including overlap integrals as required by H TaLIF. The line width of H TaLIF, due to collision broadening has the same trend as the neutral density obtained by Rayleigh scattering. This suggests the possibility to use this technique to in situ probe neutral gas densities.

Improvement in QEPAS system utilizing a second harmonic based wavelength calibration technique

NASA Astrophysics Data System (ADS)

Zhang, Qinduan; Chang, Jun; Wang, Fupeng; Wang, Zongliang; Xie, Yulei; Gong, Weihua

2018-05-01

A simple laser wavelength calibration technique, based on second harmonic signal, is demonstrated in this paper to improve the performance of quartz enhanced photoacoustic spectroscopy (QEPAS) gas sensing system, e.g. improving the signal to noise ratio (SNR), detection limit and long-term stability. Constant current, corresponding to the gas absorption line, combining f/2 frequency sinusoidal signal are used to drive the laser (constant driving mode), a software based real-time wavelength calibration technique is developed to eliminate the wavelength drift due to ambient fluctuations. Compared to conventional wavelength modulation spectroscopy (WMS), this method allows lower filtering bandwidth and averaging algorithm applied to QEPAS system, improving SNR and detection limit. In addition, the real-time wavelength calibration technique guarantees the laser output is modulated steadily at gas absorption line. Water vapor is chosen as an objective gas to evaluate its performance compared to constant driving mode and conventional WMS system. The water vapor sensor was designed insensitive to the incoherent external acoustic noise by the numerical averaging technique. As a result, the SNR increases 12.87 times in wavelength calibration technique based system compared to conventional WMS system. The new system achieved a better linear response (R2 = 0 . 9995) in concentration range from 300 to 2000 ppmv, and achieved a minimum detection limit (MDL) of 630 ppbv.

40 CFR Appendix I to Part 92 - Emission Related Locomotive and Engine Parameters and Specifications

Code of Federal Regulations, 2010 CFR

2010-07-01

.... b. Idle mixture. c. Transient enrichment system calibration. d. Starting enrichment system... shutoff system calibration. d. Starting enrichment system calibration. e. Transient enrichment system... parameters and calibrations. b. Transient enrichment system calibration. c. Air-fuel flow calibration. d...

The use of permeation tube device and the development of empirical formula for accurate permeation rate

USDA-ARS?s Scientific Manuscript database

A series of laboratory experiments were conducted to assess the accuracy of permeation tube (PT) devices using a calibration gas generator system to measure permeation rate (PR) of volatile organic compounds (VOCs). Calibration gas standards of benzene, toluene, and m-xylene (BTX) were produced from...

Chemical Contaminant and Decontaminant Test Methodology Source Document. Second Edition

DTIC Science & Technology

2012-07-01

performance as described in “A Statistical Overview on Univariate Calibration, Inverse Regression, and Detection Limits: Application to Gas Chromatography...Overview on Univariate Calibration, Inverse Regression, and Detection Limits: Application to Gas Chromatography/Mass Spectrometry Technique. Mass... APPLICATIONS INTERNATIONAL CORPORATION Gunpowder, MD 21010-0068 July 2012 Approved for public release; distribution is unlimited

Application of the Shiono and Knight Method in asymmetric compound channels with different side slopes of the internal wall

NASA Astrophysics Data System (ADS)

Alawadi, Wisam; Al-Rekabi, Wisam S.; Al-Aboodi, Ali H.

2018-03-01

The Shiono and Knight Method (SKM) is widely used to predict the lateral distribution of depth-averaged velocity and boundary shear stress for flows in compound channels. Three calibrating coefficients need to be estimated for applying the SKM, namely eddy viscosity coefficient ( λ), friction factor ( f) and secondary flow coefficient ( k). There are several tested methods which can satisfactorily be used to estimate λ, f. However, the calibration of secondary flow coefficients k to account for secondary flow effects correctly is still problematic. In this paper, the calibration of secondary flow coefficients is established by employing two approaches to estimate correct values of k for simulating asymmetric compound channel with different side slopes of the internal wall. The first approach is based on Abril and Knight (2004) who suggest fixed values for main channel and floodplain regions. In the second approach, the equations developed by Devi and Khatua (2017) that relate the variation of the secondary flow coefficients with the relative depth ( β) and width ratio ( α) are used. The results indicate that the calibration method developed by Devi and Khatua (2017) is a better choice for calibrating the secondary flow coefficients than using the first approach which assumes a fixed value of k for different flow depths. The results also indicate that the boundary condition based on the shear force continuity can successfully be used for simulating rectangular compound channels, while the continuity of depth-averaged velocity and its gradient is accepted boundary condition in simulations of trapezoidal compound channels. However, the SKM performance for predicting the boundary shear stress over the shear layer region may not be improved by only imposing the suitable calibrated values of secondary flow coefficients. This is because difficulties of modelling the complex interaction that develops between the flows in the main channel and on the floodplain in this region.

Eddy Covariance measurements of stable isotopes (δD and δ18O) in water vapor

NASA Astrophysics Data System (ADS)

Braden-Behrens, Jelka; Knohl, Alexander

2017-04-01

Stable isotopes are a promising tool to enhance our understanding of ecosystem gas exchanges. Studying 18O and 2H in water vapour (H2Ov) can e.g. help partitioning evapotranspiration into its components. With recent developments in laser spectroscopy direct Eddy Covariance (EC) measurements for investigating fluxes of stable isotopologues became feasible. So far very few case studies have applied the EC method to measure stable isotopes in water vapor. We continuously measure fluxes of water vapor isotopologues with the EC method in a managed beech forest in Thuringia, Germany, since autumn 2015 using the following setup: An off-axis integrated cavity output water vapor isotope analyzer (WVIA, Los Gatos Research. Inc, USA) measures the water vapour concentration and its isotopic composition (δD and δ18O). The instrument, that was optimized for high flow rates (app. 4slpm) to generate high frequency (2Hz) measurements, showed sufficient precision with Allan Deviations of app. 0.12 ‰ for δD and 0.06 ‰ for δ18O for averaging periods of 100s. The instrument was calibrated hourly using a high-flow optimized version of the water vapor isotope standard source (WVISS, Los Gatos Research. Inc, USA) that provides water vapor with known isotopic composition for a large range of different concentrations. Our calibration scheme includes a near continuous concentration range calibration instead of a simple 2 or 3-point calibration to face the analyzers strong concentration dependency within a range of app. 6 000 to 16 000 ppm in winter and app. 8 000 to 23 000 ppm in summer. In the used setup, the high-flow and high-frequency optimized water vapor isotope analyzer (WVIA) showed suitable characteristics (Allan deviation and spectral energy distribution) to perform Eddy covariance measurements of stable isotopes in H2Ov. Thus, this novel instrument for EC measurements of water vapor isotopologues provides a new opportunity for studying the hydrological cycle in long-term observation networks like Fluxnet and ICOS.

Kiloampere, Variable-Temperature, Critical-Current Measurements of High-Field Superconductors

PubMed Central

Goodrich, LF; Cheggour, N; Stauffer, TC; Filla, BJ; Lu, XF

2013-01-01

We review variable-temperature, transport critical-current (Ic) measurements made on commercial superconductors over a range of critical currents from less than 0.1 A to about 1 kA. We have developed and used a number of systems to make these measurements over the last 15 years. Two exemplary variable-temperature systems with coil sample geometries will be described: a probe that is only variable-temperature and a probe that is variable-temperature and variable-strain. The most significant challenge for these measurements is temperature stability, since large amounts of heat can be generated by the flow of high current through the resistive sample fixture. Therefore, a significant portion of this review is focused on the reduction of temperature errors to less than ±0.05 K in such measurements. A key feature of our system is a pre-regulator that converts a flow of liquid helium to gas and heats the gas to a temperature close to the target sample temperature. The pre-regulator is not in close proximity to the sample and it is controlled independently of the sample temperature. This allows us to independently control the total cooling power, and thereby fine tune the sample cooling power at any sample temperature. The same general temperature-control philosophy is used in all of our variable-temperature systems, but the addition of another variable, such as strain, forces compromises in design and results in some differences in operation and protocol. These aspects are analyzed to assess the extent to which the protocols for our systems might be generalized to other systems at other laboratories. Our approach to variable-temperature measurements is also placed in the general context of measurement-system design, and the perceived advantages and disadvantages of design choices are presented. To verify the accuracy of the variable-temperature measurements, we compared critical-current values obtained on a specimen immersed in liquid helium (“liquid” or Ic liq) at 5 K to those measured on the same specimen in flowing helium gas (“gas” or Ic gas) at the same temperature. These comparisons indicate the temperature control is effective over the superconducting wire length between the voltage taps, and this condition is valid for all types of sample investigated, including Nb-Ti, Nb3Sn, and MgB2 wires. The liquid/gas comparisons are used to study the variable-temperature measurement protocol that was necessary to obtain the “correct” critical current, which was assumed to be the Ic liq. We also calibrated the magnetoresistance effect of resistive thermometers for temperatures from 4 K to 35 K and magnetic fields from 0 T to 16 T. This calibration reduces systematic errors in the variable-temperature data, but it does not affect the liquid/gas comparison since the same thermometers are used in both cases. PMID:26401435

Total dissolved gas, barometric pressure, and water temperature data, lower Columbia River, Oregon and Washington, 1996

USGS Publications Warehouse

Tanner, Dwight Q.; Harrison, Howard E.; McKenzie, Stuart W.

1996-01-01

Increased levels of total dissolved gas pressure can cause gas-bubble trauma in fish downstream from dams on the Columbia River. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey collected data on total dissolved gas pressure, barometric pressure, water temperature, and dissolved oxygen pressure at 11 stations on the lower Columbia River from the John Day forebay (river mile 215.6) to Wauna Mill (river mile 41.9) from March to September 1996. Methods of data collection, review, and processing are described in this report. Summaries of daily minimum, maximum, and mean hourly values are presented for total dissolved gas pressure, barometric pressure, and water temperature. Hourly values for these parameters are presented graphically. Dissolved oxygen data are not presented in this report because the quality-control data show that the data have poor precision and high bias. Suggested changes to monitoring procedures for future studies include (1) improved calibration procedures for total dissolved gas and dissolved oxygen to better define accuracy at elevated levels of supersaturation and (2) equipping dissolved oxygen sensors with stirrers because river velocities at the shoreline monitoring stations probably cannot maintain an adequate flow of water across the membrane surface of the dissolved oxygen sensor.

NASA Tech Briefs, September 2010

NASA Technical Reports Server (NTRS)

2010-01-01

Topics covered include: Instrument for Measuring Thermal Conductivity of Materials at Low Temperatures; Multi-Axis Accelerometer Calibration System; Pupil Alignment Measuring Technique and Alignment Reference for Instruments or Optical Systems; Autonomous System for Monitoring the Integrity of Composite Fan Housings; A Safe, Self-Calibrating, Wireless System for Measuring Volume of Any Fuel at Non-Horizontal Orientation; Adaptation of the Camera Link Interface for Flight-Instrument Applications; High-Performance CCSDS Encapsulation Service Implementation in FPGA; High-Performance CCSDS AOS Protocol Implementation in FPGA; Advanced Flip Chips in Extreme Temperature Environments; Diffuse-Illumination Systems for Growing Plants; Microwave Plasma Hydrogen Recovery System; Producing Hydrogen by Plasma Pyrolysis of Methane; Self-Deployable Membrane Structures; Reactivation of a Tin-Oxide-Containing Catalys; Functionalization of Single-Wall Carbon Nanotubes by Photo-Oxidation; Miniature Piezoelectric Macro-Mass Balance; Acoustic Liner for Turbomachinery Applications; Metering Gas Strut for Separating Rocket Stages; Large-Flow-Area Flow-Selective Liquid/Gas Separator; Counterflowing Jet Subsystem Design; Water Tank with Capillary Air/Liquid Separation; True Shear Parallel Plate Viscometer; Focusing Diffraction Grating Element with Aberration Control; Universal Millimeter-Wave Radar Front End; Mode Selection for a Single-Frequency Fiber Laser; Qualification and Selection of Flight Diode Lasers for Space Applications; Plenoptic Imager for Automated Surface Navigation; Maglev Facility for Simulating Variable Gravity; Hybrid AlGaN-SiC Avalanche Photodiode for Deep-UV Photon Detection; High-Speed Operation of Interband Cascade Lasers; 3D GeoWall Analysis System for Shuttle External Tank Foreign Object Debris Events; Charge-Spot Model for Electrostatic Forces in Simulation of Fine Particulates; Hidden Statistics Approach to Quantum Simulations; Reconstituted Three-Dimensional Interactive Imaging; Determining Atmospheric-Density Profile of Titan; Digital Microfluidics Sample Analyzer; Radiation Protection Using Carbon Nanotube Derivatives; Process to Selectively Distinguish Viable from Non-Viable Bacterial Cells; and TEAMS Model Analyzer.

Transport of Carbon Tetrachloride in a Fractured Vadose Zone due to Atmospheric Pressure Fluctuations, Diffusion, and Vapor Density

NASA Astrophysics Data System (ADS)

McCray, J. E.; Downs, W.; Falta, R. W.; Housley, T.

2005-12-01

DNAPL sources of carbon tetrachloride (CT) vapors are of interest at the Radioactive Waste Management Complex (RWMC) at the Idaho National Engineering and Environmental Laboratory (INEEL). The site is underlain by thick fractured basalt that includes sedimentary interbeds, each are a few meters thick. Daily atmospheric pressure fluctuations serve as driving forces for CT vapor transport in the subsurface. Other important transport processes for vapor movement include gas-phase diffusion and density-driven transport. The objective of this research is to investigate the influence and relative importance of these processes on gaseous transport of CT. Gas pressure and vapor concentration measurements were conducted at various depths in two wells. A numerical multiphase flow model (TOUGH2), calibrated to field pressure data, is used to conduct sensitivity analyses to elucidate the importance of the different transport mechanisms. Results show that the basalt is highly permeable to vertical air flow. The pressure dampening occurs mainly in the sedimentary interbeds. Model-calibrated permeability values for the interbeds are similar to those obtained in a study by the U.S. Geological Survey for shallow sediments, and an order of magnitude higher than column-scale values obtained by previous studies conducted by INEEL scientists. The transport simulations indicate that considering the effect of barometric pressure changes is critical to simulating transport of pollutants in the vadose zone above the DNAPL source. Predicted concentrations can be orders of magnitude smaller than actual concentrations if the effect is not considered. Below the DNAPL vapor source, accounting for density and diffusion alone would yield acceptable results provided that a 20% error in concentrations are acceptable, and that simulating concentrations trends (and not actual concentrations) is the primary goal.

Exploring the Chemical Link Between Local Ellipticals and Their High-Redshift Progenitors

NASA Technical Reports Server (NTRS)

Leja, Joel; Van Dokkum, Pieter G.; Momcheva, Ivelina; Brammer, Gabriel; Skelton, Rosalind E.; Whitaker, Katherine E.; Andrews, Brett H.; Franx, Marijn; Kriek, Mariska; Van Der Wel, Arjen;

40 CFR 86.1216-90 - Calibrations; frequency and overview.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Petroleum Gas-Fueled and Methanol-Fueled Heavy-Duty Vehicles § 86.1216-90 Calibrations; frequency and...). (d) At least twice annually or after any maintenance perform a methanol retention check and calibration on the evaporative emission enclosure (see § 86.1217). (e) Calibrate the methanol analyzer as...

40 CFR 86.1216-90 - Calibrations; frequency and overview.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Petroleum Gas-Fueled and Methanol-Fueled Heavy-Duty Vehicles § 86.1216-90 Calibrations; frequency and...). (d) At least twice annually or after any maintenance perform a methanol retention check and calibration on the evaporative emission enclosure (see § 86.1217). (e) Calibrate the methanol analyzer as...

Thermally determining flow and/or heat load distribution in parallel paths

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chainer, Timothy J.; Iyengar, Madhusudan K.; Parida, Pritish R.

A method including obtaining calibration data for at least one sub-component in a heat transfer assembly, wherein the calibration data comprises at least one indication of coolant flow rate through the sub-component for a given surface temperature delta of the sub-component and a given heat load into said sub-component, determining a measured heat load into the sub-component, determining a measured surface temperature delta of the sub-component, and determining a coolant flow distribution in a first flow path comprising the sub-component from the calibration data according to the measured heat load and the measured surface temperature delta of the sub-component.

Thermally determining flow and/or heat load distribution in parallel paths

DOEpatents

Chainer, Timothy J.; Iyengar, Madhusudan K.; Parida, Pritish R.

2016-12-13

A method including obtaining calibration data for at least one sub-component in a heat transfer assembly, wherein the calibration data comprises at least one indication of coolant flow rate through the sub-component for a given surface temperature delta of the sub-component and a given heat load into said sub-component, determining a measured heat load into the sub-component, determining a measured surface temperature delta of the sub-component, and determining a coolant flow distribution in a first flow path comprising the sub-component from the calibration data according to the measured heat load and the measured surface temperature delta of the sub-component.

Impact of the calibration period on the conceptual rainfall-runoff model parameter estimates

NASA Astrophysics Data System (ADS)

Todorovic, Andrijana; Plavsic, Jasna

2015-04-01

A conceptual rainfall-runoff model is defined by its structure and parameters, which are commonly inferred through model calibration. Parameter estimates depend on objective function(s), optimisation method, and calibration period. Model calibration over different periods may result in dissimilar parameter estimates, while model efficiency decreases outside calibration period. Problem of model (parameter) transferability, which conditions reliability of hydrologic simulations, has been investigated for decades. In this paper, dependence of the parameter estimates and model performance on calibration period is analysed. The main question that is addressed is: are there any changes in optimised parameters and model efficiency that can be linked to the changes in hydrologic or meteorological variables (flow, precipitation and temperature)? Conceptual, semi-distributed HBV-light model is calibrated over five-year periods shifted by a year (sliding time windows). Length of the calibration periods is selected to enable identification of all parameters. One water year of model warm-up precedes every simulation, which starts with the beginning of a water year. The model is calibrated using the built-in GAP optimisation algorithm. The objective function used for calibration is composed of Nash-Sutcliffe coefficient for flows and logarithms of flows, and volumetric error, all of which participate in the composite objective function with approximately equal weights. Same prior parameter ranges are used in all simulations. The model is calibrated against flows observed at the Slovac stream gauge on the Kolubara River in Serbia (records from 1954 to 2013). There are no trends in precipitation nor in flows, however, there is a statistically significant increasing trend in temperatures at this catchment. Parameter variability across the calibration periods is quantified in terms of standard deviations of normalised parameters, enabling detection of the most variable parameters. Correlation coefficients among optimised model parameters and total precipitation P, mean temperature T and mean flow Q are calculated to give an insight into parameter dependence on the hydrometeorological drivers. The results reveal high sensitivity of almost all model parameters towards calibration period. The highest variability is displayed by the refreezing coefficient, water holding capacity, and temperature gradient. The only statistically significant (decreasing) trend is detected in the evapotranspiration reduction threshold. Statistically significant correlation is detected between the precipitation gradient and precipitation depth, and between the time-area histogram base and flows. All other correlations are not statistically significant, implying that changes in optimised parameters cannot generally be linked to the changes in P, T or Q. As for the model performance, the model reproduces the observed runoff satisfactorily, though the runoff is slightly overestimated in wet periods. The Nash-Sutcliffe efficiency coefficient (NSE) ranges from 0.44 to 0.79. Higher NSE values are obtained over wetter periods, what is supported by statistically significant correlation between NSE and flows. Overall, no systematic variations in parameters or in model performance are detected. Parameter variability may therefore rather be attributed to errors in data or inadequacies in the model structure. Further research is required to examine the impact of the calibration strategy or model structure on the variability in optimised parameters in time.

Estimation of the limit of detection in semiconductor gas sensors through linearized calibration models.

PubMed

Burgués, Javier; Jiménez-Soto, Juan Manuel; Marco, Santiago

2018-07-12

The limit of detection (LOD) is a key figure of merit in chemical sensing. However, the estimation of this figure of merit is hindered by the non-linear calibration curve characteristic of semiconductor gas sensor technologies such as, metal oxide (MOX), gasFETs or thermoelectric sensors. Additionally, chemical sensors suffer from cross-sensitivities and temporal stability problems. The application of the International Union of Pure and Applied Chemistry (IUPAC) recommendations for univariate LOD estimation in non-linear semiconductor gas sensors is not straightforward due to the strong statistical requirements of the IUPAC methodology (linearity, homoscedasticity, normality). Here, we propose a methodological approach to LOD estimation through linearized calibration models. As an example, the methodology is applied to the detection of low concentrations of carbon monoxide using MOX gas sensors in a scenario where the main source of error is the presence of uncontrolled levels of humidity. Copyright © 2018 Elsevier B.V. All rights reserved.

Calibrating Laser Gas Measurements by Use of Natural CO2

NASA Technical Reports Server (NTRS)

Webster, Chris

2003-01-01

An improved method of calibration has been devised for instruments that utilize tunable lasers to measure the absorption spectra of atmospheric gases in order to determine the relative abundances of the gases. In this method, CO2 in the atmosphere is used as a natural calibration standard. Unlike in one prior calibration method, it is not necessary to perform calibration measurements in advance of use of the instrument and to risk deterioration of accuracy with time during use. Unlike in another prior calibration method, it is not necessary to include a calibration gas standard (and the attendant additional hardware) in the instrument and to interrupt the acquisition of atmospheric data to perform calibration measurements. In the operation of an instrument of this type, the beam from a tunable diode laser or a tunable quantum-cascade laser is directed along a path through the atmosphere, the laser is made to scan in wavelength over an infrared spectral region that contains one or two absorption spectral lines of a gas of interest, and the transmission (and, thereby, the absorption) of the beam is measured. The concentration of the gas of interest can then be calculated from the observed depth of the absorption line(s), given the temperature, pressure, and path length. CO2 is nearly ideal as a natural calibration gas for the following reasons: CO2 has numerous rotation/vibration infrared spectral lines, many of which are near absorption lines of other gases. The concentration of CO2 relative to the concentrations of the major constituents of the atmosphere is well known and varies slowly and by a small enough amount to be considered constant for calibration in the present context. Hence, absorption-spectral measurements of the concentrations of gases of interest can be normalized to the concentrations of CO2. Because at least one CO2 calibration line is present in every spectral scan of the laser during absorption measurements, the atmospheric CO2 serves continuously as a calibration standard for every measurement point. Figure 1 depicts simulated spectral transmission measurements in a wavenumber range that contains two absorption lines of N2O and one of CO2. The simulations were performed for two different upper-atmospheric pressures for an airborne instrument that has a path length of 80 m. The relative abundance of CO2 in air was assumed to be 360 parts per million by volume (approximately its natural level in terrestrial air). In applying the present method to measurements like these, one could average the signals from the two N2O absorption lines and normalize their magnitudes to that of the CO2 absorption line. Other gases with which this calibration method can be used include H2O, CH4, CO, NO, NO2, HOCl, C2H2, NH3, O3, and HCN. One can also take advantage of this method to eliminate an atmospheric-pressure gauge and thereby reduce the mass of the instrument: The atmospheric pressure can be calculated from the temperature, the known relative abundance of CO2, and the concentration of CO2 as measured by spectral absorption. Natural CO2 levels on Mars provide an ideal calibration standard. Figure 2 shows a second example of the application of this method to Mars atmospheric gas measurements. For sticky gases like H2O, the method is particularly powerful, since water is notoriously difficult to handle at low concentrations in pre-flight calibration procedures.

A fast sampling device for the mass spectrometric analysis of liquid rocket engine exhaust

NASA Technical Reports Server (NTRS)

Ryason, P. R.

1975-01-01

The design of a device to obtain compositional data on rocket exhaust by direct sampling of reactive flow exhausts into a mass spectrometer is presented. Sampling at three stages differing in pressure and orifice angle and diameter is possible. Results of calibration with pure gases and gas mixtures are erratic and of unknown accuracy for H2, limiting the usefulness of the apparatus for determining oxidizer/fuel ratios from combustion product analysis. Deposition effects are discussed, and data obtained from rocket exhaust spectra are analyzed to give O/F ratios and mixture ratio distribution. The O/F ratio determined spectrometrically is insufficiently accurate for quantitative comparison with cold flow data. However, a criterion for operating conditions with improved mixing of fuel and oxidizer which is consistent with cold flow results may be obtained by inspection of contour plots. A chemical inefficiency in the combustion process when oxidizer is in excess is observed from reactive flow measurements. Present results were obtained with N2O4/N2H4 propellants.

Apparatus for measuring resistance change only in a cell analyzer and method for calibrating it

DOEpatents

Hoffman, Robert A.

1980-01-01

The disclosure relates to resistance only monitoring and calibration in an electrical cell analyzer. Sample and sheath fluid flows of different salinities are utilized, the sample flow being diameter modulated to produce a selected pattern which is compared to the resistance measured across the flows.

On the concept of virtual current as a means to enhance verification of electromagnetic flowmeters

NASA Astrophysics Data System (ADS)

Baker, Roger C.

2011-10-01

Electromagnetic flowmeters are becoming increasingly widely used in the water industry and other industries which handle electrically conducting liquids. When installed they are often difficult to remove for calibration without disturbing the liquid flow. Interest has therefore increased in the possibility of in situ calibration. The result has been the development of verification which attempts to approach calibration. However, while it checks on magnetic field and amplification circuits, it does not check adequately on the internals of the flowmeter pipe. This paper considers the use of the virtual voltage, a key element of the weight function theory of the flowmeter, to identify changes which have occurred in the flow tube and its liner. These could include a deformed insulating liner to the flow tube, or a deposit in the tube resulting from solids in the flow. The equation for virtual voltage is solved using a finite difference approach and the results are checked using a tank to simulate the flow tube, and tests on a flow rig. The concept is shown to be promising as a means of approaching verification of calibration.

Statistical analysis on experimental calibration data for flowmeters in pressure pipes

NASA Astrophysics Data System (ADS)

Lazzarin, Alessandro; Orsi, Enrico; Sanfilippo, Umberto

2017-08-01

This paper shows a statistical analysis on experimental calibration data for flowmeters (i.e.: electromagnetic, ultrasonic, turbine flowmeters) in pressure pipes. The experimental calibration data set consists of the whole archive of the calibration tests carried out on 246 flowmeters from January 2001 to October 2015 at Settore Portate of Laboratorio di Idraulica “G. Fantoli” of Politecnico di Milano, that is accredited as LAT 104 for a flow range between 3 l/s and 80 l/s, with a certified Calibration and Measurement Capability (CMC) - formerly known as Best Measurement Capability (BMC) - equal to 0.2%. The data set is split into three subsets, respectively consisting in: 94 electromagnetic, 83 ultrasonic and 69 turbine flowmeters; each subset is analysed separately from the others, but then a final comparison is carried out. In particular, the main focus of the statistical analysis is the correction C, that is the difference between the flow rate Q measured by the calibration facility (through the accredited procedures and the certified reference specimen) minus the flow rate QM contemporarily recorded by the flowmeter under calibration, expressed as a percentage of the same QM .

The Need for a Shear Stress Calibration Standard

NASA Technical Reports Server (NTRS)

Scott, Michael A.

2004-01-01

By surveying current research of various micro-electro mechanical systems (MEMS) shear stress sensor development efforts we illustrate the wide variety of methods used to test and characterize these sensors. The different methods of testing these sensors make comparison of results difficult in some cases, and also this comparison is further complicated by the different formats used in reporting the results of these tests. The fact that making these comparisons can be so difficult at times clearly illustrates a need for standardized testing and reporting methodologies. This need indicates that the development of a national or international standard for the calibration of MEMS shear stress sensors should be undertaken. As a first step towards the development of this standard, two types of devices are compared and contrasted. The first type device is a laminar flow channel with two different versions considered: the first built with standard manufacturing techniques and the second with advanced precision manufacturing techniques. The second type of device is a new concept for creating a known shear stress consisting of a rotating wheel with the sensor mounted tangentially to the rim and positioned in close proximity to the rim. The shear stress generated by the flow at the sensor position is simply tau = (mu)r(omega)/h, where mu is the viscosity of the ambient gas, r the wheel radius, omega the angular velocity of the wheel, and h the width of the gap between the wheel rim and the sensor. Additionally, issues related to the development of a standard for shear stress calibration are identified and discussed.

Experimental Validation of ARFI Surveillance of Subcutaneous Hemorrhage (ASSH) Using Calibrated Infusions in a Tissue-Mimicking Model and Dogs.

PubMed

Geist, Rebecca E; DuBois, Chase H; Nichols, Timothy C; Caughey, Melissa C; Merricks, Elizabeth P; Raymer, Robin; Gallippi, Caterina M

2016-09-01

Acoustic radiation force impulse (ARFI) Surveillance of Subcutaneous Hemorrhage (ASSH) has been previously demonstrated to differentiate bleeding phenotype and responses to therapy in dogs and humans, but to date, the method has lacked experimental validation. This work explores experimental validation of ASSH in a poroelastic tissue-mimic and in vivo in dogs. The experimental design exploits calibrated flow rates and infusion durations of evaporated milk in tofu or heparinized autologous blood in dogs. The validation approach enables controlled comparisons of ASSH-derived bleeding rate (BR) and time to hemostasis (TTH) metrics. In tissue-mimicking experiments, halving the calibrated flow rate yielded ASSH-derived BRs that decreased by 44% to 48%. Furthermore, for calibrated flow durations of 5.0 minutes and 7.0 minutes, average ASSH-derived TTH was 5.2 minutes and 7.0 minutes, respectively, with ASSH predicting the correct TTH in 78% of trials. In dogs undergoing calibrated autologous blood infusion, ASSH measured a 3-minute increase in TTH, corresponding to the same increase in the calibrated flow duration. For a measured 5% decrease in autologous infusion flow rate, ASSH detected a 7% decrease in BR. These tissue-mimicking and in vivo preclinical experimental validation studies suggest the ASSH BR and TTH measures reflect bleeding dynamics. © The Author(s) 2015.

End-to-end system test for solid-state microdosemeters.

PubMed

Pisacane, V L; Dolecek, Q E; Malak, H; Dicello, J F

2010-08-01

The gold standard in microdosemeters has been the tissue equivalent proportional counter (TEPC) that utilises a gas cavity. An alternative is the solid-state microdosemeter that replaces the gas with a condensed phase (silicon) detector with microscopic sensitive volumes. Calibrations of gas and solid-state microdosemeters are generally carried out using radiation sources built into the detector that impose restrictions on their handling, transportation and licensing in accordance with the regulations from international, national and local nuclear regulatory bodies. Here a novel method is presented for carrying out a calibration and end-to-end system test of a microdosemeter using low-energy photons as the initiating energy source, thus obviating the need for a regulated ionising radiation source. This technique may be utilised to calibrate both a solid-state microdosemeter and, with modification, a TEPC with the higher average ionisation energy of a gas.

Methods for gas detection using stationary hyperspectral imaging sensors

DOEpatents

Conger, James L [San Ramon, CA; Henderson, John R [Castro Valley, CA

2012-04-24

According to one embodiment, a method comprises producing a first hyperspectral imaging (HSI) data cube of a location at a first time using data from a HSI sensor; producing a second HSI data cube of the same location at a second time using data from the HSI sensor; subtracting on a pixel-by-pixel basis the second HSI data cube from the first HSI data cube to produce a raw difference cube; calibrating the raw difference cube to produce a calibrated raw difference cube; selecting at least one desired spectral band based on a gas of interest; producing a detection image based on the at least one selected spectral band and the calibrated raw difference cube; examining the detection image to determine presence of the gas of interest; and outputting a result of the examination. Other methods, systems, and computer program products for detecting the presence of a gas are also described.

Calibration and application of an automated seepage meter for monitoring water flow across the sediment-water interface.

PubMed

Zhu, Tengyi; Fu, Dafang; Jenkinson, Byron; Jafvert, Chad T

2015-04-01

The advective flow of sediment pore water is an important parameter for understanding natural geochemical processes within lake, river, wetland, and marine sediments and also for properly designing permeable remedial sediment caps placed over contaminated sediments. Automated heat pulse seepage meters can be used to measure the vertical component of sediment pore water flow (i.e., vertical Darcy velocity); however, little information on meter calibration as a function of ambient water temperature exists in the literature. As a result, a method with associated equations for calibrating a heat pulse seepage meter as a function of ambient water temperature is fully described in this paper. Results of meter calibration over the temperature range 7.5 to 21.2 °C indicate that errors in accuracy are significant if proper temperature-dependence calibration is not performed. The proposed calibration method allows for temperature corrections to be made automatically in the field at any ambient water temperature. The significance of these corrections is discussed.

Vessel calibre and flow splitting relationships at the internal carotid artery terminal bifurcation.

PubMed

Chnafa, C; Bouillot, P; Brina, O; Delattre, B M A; Vargas, M I; Lovblad, K O; Pereira, V M; Steinman, D A

2017-11-01

Vessel lumen calibres and flow rates are thought to be related by mathematical power laws, reflecting the optimization of cardiac versus metabolic work. While these laws have been confirmed indirectly via measurement of branch calibres, there is little data confirming power law relationships of flow distribution to branch calibres at individual bifurcations. Flow rates and diameters of parent and daughter vessels of the internal carotid artery terminal bifurcation were determined, via robust and automated methods, from 4D phase-contrast magnetic resonance imaging and 3D rotational angiography of 31 patients. Junction exponents were 2.06  ±  0.44 for relating parent to daughter branch diameters (geometrical exponent), and 2.45  ±  0.75 for relating daughter branch diameters to their flow division (flow split exponent). These exponents were not significantly different, but showed large inter- and intra-individual variations, and with confidence intervals excluding the theoretical optimum of 3. Power law fits of flow split versus diameter ratio and pooled flow rates versus diameters showed exponents of 2.17 and 1.96, respectively. A significant negative correlation was found between age and the geometrical exponent (r  =  -0.55, p  =  0.003) but not the flow split exponent. We also found a dependence of our results on how lumen diameter is measured, possibly explaining some of the variability in the literature. Our study confirms that, on average, division of flow to the middle and anterior cerebral arteries is related to these vessels' relative calibres via a power law, but it is closer to a square law than a cube law as commonly assumed.

Evaluation of commercially available techniques and development of simplified methods for measuring grille airflows in HVAC systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walker, Iain S.; Wray, Craig P.; Guillot, Cyril

2003-08-01

In this report, we discuss the accuracy of flow hoods for residential applications, based on laboratory tests and field studies. The results indicate that commercially available hoods are often inadequate to measure flows in residential systems, and that there can be a wide range of performance between different flow hoods. The errors are due to poor calibrations, sensitivity of existing hoods to grille flow non-uniformities, and flow changes from added flow resistance. We also evaluated several simple techniques for measuring register airflows that could be adopted by the HVAC industry and homeowners as simple diagnostics that are often as accuratemore » as commercially available devices. Our test results also show that current calibration procedures for flow hoods do not account for field application problems. As a result, organizations such as ASHRAE or ASTM need to develop a new standard for flow hood calibration, along with a new measurement standard to address field use of flow hoods.« less

ForGATE - A Forest Sector Greenhouse Gas Assessment Tool for Maine: Calibration and Overview

Treesearch

Chris Hennigar; Luke Amos-Binks; Ryan Cameron; John Gunn; David A. MacLean; Mark Twery

2013-01-01

This report describes the background calibration, inputs, and outputs of ForGATE, a forest sector greenhouse gas (GHG) accounting tool designed primarily to communicate information relevant to the evaluation of projected net GHG exchange in the context of Maine's forests, the Northeast forest sector, and alternative national or regional carbon (C) accounting...

Apparatus for the Calibration/Certification of Direct Reading Tritium in Air Monitors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Otlet, R.L.; Mather, I.D.; Pottinger, M

2005-07-15

Direct reading tritium-in-air-monitors are widely used for immediate observation of discharges or working area levels where significant sources of tritium are held. These monitors require initial and periodic calibration certification at the levels likely to be encountered. We describe a purpose built gas handling apparatus which enables various activity levels of tritiated gas ({sup 3}H + N{sub 2}) to be precisely metered and circulated in a closed loop through the monitor under calibration at a wide range of activity levels.

43 CFR 3275.16 - What standards apply to installing and maintaining meters?

Code of Federal Regulations, 2012 CFR

2012-10-01

...; (2) You must calibrate meters measuring steam or hot water flow with a turbine, vortex, ultrasonics... frequent; and (3) You must calibrate meters measuring steam or hot water flow with an orifice plate...

43 CFR 3275.16 - What standards apply to installing and maintaining meters?

Code of Federal Regulations, 2011 CFR

2011-10-01

...; (2) You must calibrate meters measuring steam or hot water flow with a turbine, vortex, ultrasonics... frequent; and (3) You must calibrate meters measuring steam or hot water flow with an orifice plate...

43 CFR 3275.16 - What standards apply to installing and maintaining meters?

Code of Federal Regulations, 2014 CFR

2014-10-01

...; (2) You must calibrate meters measuring steam or hot water flow with a turbine, vortex, ultrasonics... frequent; and (3) You must calibrate meters measuring steam or hot water flow with an orifice plate...

43 CFR 3275.16 - What standards apply to installing and maintaining meters?

Code of Federal Regulations, 2013 CFR

2013-10-01

...; (2) You must calibrate meters measuring steam or hot water flow with a turbine, vortex, ultrasonics... frequent; and (3) You must calibrate meters measuring steam or hot water flow with an orifice plate...

Results from the EPL monkey-pod experiment conducted as part of the 1974 NASA/Ames shuttle CVT-2

NASA Technical Reports Server (NTRS)

Rahlmann, D. F.; Kodama, A. M.; Mains, R. C.; Pace, N.

1974-01-01

The participation of the Environmental Physiology Laboratory (EPL) in the general purpose laboratory concept verification test 3 is documented. The EPL Monkey-Pod Experiment was designed to incorporate a 10-12 kg, pig tailed monkey, Macaca nemestrina, into the pod and measure the physiological responses of the animal continuously. Four major elements comprise the EPL Monkey-Pod Experiment System: (1) a fiberglass pod containing the instrumented monkey plus feeder and watering devices, (2) an inner console containing the SKYLAB mass spectrometer with its associated valving and electronic controls, sensing, control and monitoring units for lower body negative pressure, feeder activity, waterer activity, temperatures, and gas metabolism calibration, (3) an umbilical complex comprising gas flow lines and electrical cabling between the inner and outer console and (4) an outer console in principle representing the experiment support to be provided from general spacecraft sources.

Results from the EPL monkey-pod flight experiments conducted aboard the NASA/Ames CV-990, May 1976

NASA Technical Reports Server (NTRS)

Rahlmann, D. F.; Kodama, A. M.; Mains, R. C.; Pace, N.

1976-01-01

The participation of the Environmental Physiology Laboratory (EPL) in the general purpose laboratory concept verification test 3 is documented. The EPL Monkey-Pod Experiment was designed to incorporate a 10-12 kg, pig tailed monkey, Macaca nemestrina, into the pod and measure the physiological responses of the animal continously. Four major elements comprise the EPL Monkey-Pod Experiment System: (1) a fiberglass pod containing the instrumented monkey plus feeder and watering devices, (2) an inner console containing the SKYLAB mass spectrometer with its associated valving and electronic controls, sensing, control and monitoring units for lower body negative pressure, feeder activity, waterer activity, temperatures, and gas metabolism calibration, (3) an umbilical complex comprising gas flow lines and electrical cabling between the inner and outer console and (4) an outer console in principle representing the experiment support to be provided from general space craft sources.

Umbilical cannulation optimizes circuit flows in premature lambs supported by the EXTra-uterine Environment for Neonatal Development (EXTEND).

PubMed

Hornick, Matthew A; Davey, Marcus G; Partridge, Emily A; Mejaddam, Ali Y; McGovern, Patrick E; Olive, Aliza M; Hwang, Grace; Kim, Jenny; Castillo, Orlando; Young, Kathleen; Han, Jiancheng; Zhao, Sheng; Connelly, James T; Dysart, Kevin C; Rychik, Jack; Peranteau, William H; Flake, Alan W

2018-05-01

Bronchopulmonary dysplasia is a disease of extreme prematurity that occurs when the immature lung is exposed to gas ventilation. We designed a novel 'artificial womb' system for supporting extreme premature lambs (called EXTEND) that obviates gas ventilation by providing oxygen via a pumpless arteriovenous circuit with the lamb submerged in sterile artificial amniotic fluid. In the present study, we compare different arteriovenous cannulation strategies on EXTEND, including carotid artery/jugular vein (CA/JV), carotid artery/umbilical vein (CA/UV) and umbilical artery/umbilical vein (UA/UV). Compared to CA/JV and CA/UV cannulation, UA/UV cannulation provided significantly higher, physiological blood flows to the oxygenator, minimized flow interruptions and supported significantly longer circuit runs (up to 4 weeks). Physiological circuit blood flow in UA/UV lambs made possible normal levels of oxygen delivery, which is a critical step toward the clinical application of artificial womb technology. EXTEND (EXTra-uterine Environment for Neonatal Development) is a novel system that promotes physiological development by maintaining the premature lamb in a sterile fluid environment and providing gas exchange via a pumpless arteriovenous oxygenator circuit. During the development of EXTEND, different cannulation strategies evolved with the aim of improving circuit flow. The present study examines how different cannulation strategies affect EXTEND circuit haemodynamics in extreme premature lambs. Seventeen premature lambs were cannulated at gestational ages 105-117 days (term 145-150 days) and supported on EXTEND for up to 4 weeks. Experimental groups were distinguished by cannulation strategy: carotid artery outflow and jugular vein inflow (CA/JV; n = 4), carotid artery outflow and umbilical vein inflow (CA/UV; n = 5) and double umbilical artery outflow and umbilical vein inflow (UA/UV; n = 8). Circuit flows and pressures were measured continuously. As we transitioned from CA/JV to CA/UV to UA/UV cannulation, mean duration of circuit run and weight-adjusted circuit flows increased (P < 0.001) and the frequency of flow interruptions declined (P < 0.05). Umbilical vessels generally accommodated larger-bore cannulas, and cannula calibre was directly correlated with circuit pressures and indirectly correlated with flow:pressure ratio (a measure of post-membrane resistance). We conclude that UA/UV cannulation in fetal lambs on EXTEND optimizes circuit flow dynamics and flow stability and also supports circuit flows that closely approximate normal placental flow. © 2018 The Authors. The Journal of Physiology © 2018 The Physiological Society.

Derivation and calibration of semi-empirical gas geothermometers for Mahanagdong Geothermal Project, Philippines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sanchez, D.R.

1996-12-31

The dissolved CO{sub 2}, H{sub 2}S, and H{sub 2} gases in Mahanagdong aquifer fluids are controlled by specific gas-mineral equilibria. At temperature range of 250 to 310 {degrees}C, CO{sub 2} is buffered by clinozoisite + K-feldspar + calcite + muscovite (illite) + quartz mineral assemblage. For H{sub 2}S and H{sub 2} dissolved gases, they are more likely buffered by pyrrhotite + pyrite + magnetite mineral assemblage at similar temperature range. Calibration of five Mahanagdong (MG) gas geothermometers is presented, three of which used CO{sub 2}, H{sub 2}S, and H{sub 2} concentration in steam. The remaining two use CO{sub 2}/H{sub 2}more » and H{sub 2}S/H{sub 2} ratios. The calibration is based on the relation between gas content of drillhole discharges and measured aquifer temperatures. After establishing the gas content in the aquifer, gas concentrations were computed in steam after adiabatic boiling to atmospheric condition (100 {degrees}C), to obtain gas geothermometry functions. These functions could also be used in evaluating fraction of steam condensation and temperature of phase separation. A demonstration given the Mahanagdong fumarole data, indicates that there is generally a fair relation between computed temperatures using Mahanagdong gas geothermometers and the actual field trend`s temperatures.« less

Guidelines for model calibration and application to flow simulation in the Death Valley regional groundwater system

USGS Publications Warehouse

Hill, M.C.; D'Agnese, F. A.; Faunt, C.C.

2000-01-01

Fourteen guidelines are described which are intended to produce calibrated groundwater models likely to represent the associated real systems more accurately than typically used methods. The 14 guidelines are discussed in the context of the calibration of a regional groundwater flow model of the Death Valley region in the southwestern United States. This groundwater flow system contains two sites of national significance from which the subsurface transport of contaminants could be or is of concern: Yucca Mountain, which is the potential site of the United States high-level nuclear-waste disposal; and the Nevada Test Site, which contains a number of underground nuclear-testing locations. This application of the guidelines demonstrates how they may be used for model calibration and evaluation, and also to direct further model development and data collection.Fourteen guidelines are described which are intended to produce calibrated groundwater models likely to represent the associated real systems more accurately than typically used methods. The 14 guidelines are discussed in the context of the calibration of a regional groundwater flow model of the Death Valley region in the southwestern United States. This groundwater flow system contains two sites of national significance from which the subsurface transport of contaminants could be or is of concern: Yucca Mountain, which is the potential site of the United States high-level nuclear-waste disposal; and the Nevada Test Site, which contains a number of underground nuclear-testing locations. This application of the guidelines demonstrates how they may be used for model calibration and evaluation, and also to direct further model development and data collection.

MT3DMS: Model use, calibration, and validation

USGS Publications Warehouse

Zheng, C.; Hill, Mary C.; Cao, G.; Ma, R.

2012-01-01

MT3DMS is a three-dimensional multi-species solute transport model for solving advection, dispersion, and chemical reactions of contaminants in saturated groundwater flow systems. MT3DMS interfaces directly with the U.S. Geological Survey finite-difference groundwater flow model MODFLOW for the flow solution and supports the hydrologic and discretization features of MODFLOW. MT3DMS contains multiple transport solution techniques in one code, which can often be important, including in model calibration. Since its first release in 1990 as MT3D for single-species mass transport modeling, MT3DMS has been widely used in research projects and practical field applications. This article provides a brief introduction to MT3DMS and presents recommendations about calibration and validation procedures for field applications of MT3DMS. The examples presented suggest the need to consider alternative processes as models are calibrated and suggest opportunities and difficulties associated with using groundwater age in transport model calibration.

Formaldehyde preparation methods for pressure and temperature dependent laser-induced fluorescence measurements

NASA Astrophysics Data System (ADS)

Burkert, A.; Müller, D.; Rieger, S.; Schmidl, G.; Triebel, W.; Paa, W.

2015-12-01

Formaldehyde is an excellent tracer for the early phase of ignition of hydrocarbon fuels and can be used, e.g., for characterization of single droplet ignition. However, due to its fast thermal decomposition at elevated temperatures and pressures, the determination of concentration fields from laser-induced fluorescence (LIF) measurements is difficult. In this paper, we address LIF measurements of this important combustion intermediate using a calibration cell. Here, formaldehyde is created from evaporation of paraformaldehyde. We discuss three setups for preparation of formaldehyde/air mixtures with respect to their usability for well-defined heating of formaldehyde/air mixtures. The "basic setup" uses a resist heater around the measurement cell for investigation of formaldehyde near vacuum conditions or formaldehyde/air samples after sequential admixing of air. The second setup, described for the first time in detail here, takes advantage of a constant flow formaldehyde/air regime which uses preheated air to reduce the necessary time for gas heating. We used the constant flow system to measure new pressure dependent LIF excitation spectra in the 343 nm spectral region (414 absorption band of formaldehyde). The third setup, based on a novel concept for fast gas heating via excitation of SF6 (chemically inert gas) using a TEA (transverse excitation at atmospheric pressure) CO2 laser, allows to further minimize both gas heating time and thermal decomposition. Here, an admixture of CO2 is served for real time temperature measurement based on Raman scattering. The applicability of the fast laser heating system has been demonstrated with gas mixtures of SF6 + air, SF6 + N2, as well as SF6 + N2 + CO2 at 1 bar total pressure.

Constraining the Dynamics of Periodic Behavior at Mt. Semeru, Indonesia, Combining Numerical Modeling and Field Measurements of Gas emission

NASA Astrophysics Data System (ADS)

Smekens, J.; Clarke, A. B.; De'Michieli Vitturi, M.; Moore, G. M.

2012-12-01

Mt. Semeru is one of the most active explosive volcanoes on the island of Java in Indonesia. The current eruption style consists of small but frequent explosions and/or gas releases (several times a day) accompanied by continuous lava effusion that sporadically produces block-and-ash flows down the SE flank of the volcano. Semeru presents a unique opportunity to investigate the magma ascent conditions that produce this kind of persistent periodic behavior and the coexistence of explosive and effusive eruptions. In this work we use DOMEFLOW, a 1.5D transient isothermal numerical model, to investigate the dynamics of lava extrusion at Semeru. Petrologic observations from tephra and ballistic samples collected at the summit help us constrain the initial conditions of the system. Preliminary model runs produced periodic lava extrusion and pulses of gas release at the vent, with a cycle period on the order of hours, even though a steady magma supply rate was prescribed at the bottom of the conduit. Enhanced shallow permeability implemented in the model appears to create a dense plug in the shallow subsurface, which in turn plays a critical role in creating and controlling the observed periodic behavior. We measured SO2 fluxes just above the vent, using a custom UV imaging system. The device consists of two high-sensitivity CCD cameras with narrow UV filters centered at 310 and 330 nm, and a USB2000+ spectrometer for calibration and distance correction. The method produces high-frequency flux series with an accurate determination of the wind speed and plume geometry. The model results, when combined with gas measurements, and measurements of sulfur in both the groundmass and melt inclusions in eruptive products, could be used to create a volatile budget of the system. Furthermore, a well-calibrated model of the system will ultimately allow the characteristic periodicity and corresponding gas flux to be used as a proxy for magma supply rate.

Online elemental analysis of process gases with ICP-OES: A case study on waste wood combustion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wellinger, Marco, E-mail: marco.wellinger@gmail.com; Ecole Polytechnique Federale de Lausanne; Wochele, Joerg

2012-10-15

Highlights: Black-Right-Pointing-Pointer Simultaneous measurements of 23 elements in process gases of a waste wood combustor. Black-Right-Pointing-Pointer Mobile ICP spectrometer allows measurements of high quality at industrial plants. Black-Right-Pointing-Pointer Continuous online measurements with high temporal resolution. Black-Right-Pointing-Pointer Linear correlations among element concentrations in the raw flue gas were detected. Black-Right-Pointing-Pointer Novel sampling and calibration methods for ICP-OES analysis of process gases. - Abstract: A mobile sampling and measurement system for the analysis of gaseous and liquid samples in the field was developed. An inductively coupled plasma optical emission spectrometer (ICP-OES), which is built into a van, was used as detector. Themore » analytical system was calibrated with liquid and/or gaseous standards. It was shown that identical mass flows of either gaseous or liquid standards resulted in identical ICP-OES signal intensities. In a field measurement campaign trace and minor elements in the raw flue gas of a waste wood combustor were monitored. Sampling was performed with a highly transport efficient liquid quench system, which allowed to observe temporal variations in the elemental process gas composition. After a change in feedstock an immediate change of the element concentrations in the flue gas was detected. A comparison of the average element concentrations during the combustion of the two feedstocks showed a high reproducibility for matrix elements that are expected to be present in similar concentrations. On the other hand elements that showed strong differences in their concentration in the feedstock were also represented by a higher concentration in the flue gas. Following the temporal variations of different elements revealed strong correlations between a number of elements, such as chlorine with sodium, potassium and zinc, as well as arsenic with lead, and calcium with strontium.« less

Weld Development for Aluminum Fission Chamber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cross, Carl Edward; Martinez, Jesse Norris

2017-05-16

The Sigma welding team was approached to help fabricate a small fission chamber (roughly ½ inch dia. x ½ inch tall cylinder). These chambers are used as radiation sensors that contain small traces of radionuclides (Cf 252, U 235, and U 238) that serve to ionize gas atoms in addition to external radiation. When a voltage is applied within the chamber, the resulting ion flow can be calibrated and monitored. Aluminum has the advantage of not forming radioactive compounds when exposed to high external radiation (except from minor Na alloy content). Since aluminum has not been used before in thismore » application, this presented an unexplored challenge.« less

Relative importance of time, land use and lithology on determining aquifer-scale denitrification

NASA Astrophysics Data System (ADS)

Kolbe, Tamara; de Dreuzy, Jean-Raynald; Abbott, Benjamin W.; Marçais, Jean; Babey, Tristan; Thomas, Zahra; Peiffer, Stefan; Aquilina, Luc; Labasque, Thierry; Laverman, Anniet; Fleckenstein, Jan; Boulvais, Philippe; Pinay, Gilles

2017-04-01

Unconfined shallow aquifers are commonly contaminated by nitrate in agricultural regions, because of excess fertilizer application over the last decades. Watershed studies have indicated that 1) changes in agricultural practices have caused changes in nitrate input over time, 2) denitrification occurs in localized hotspots within the aquifer, and 3) heterogeneous groundwater flow circulation has led to strong nitrate gradients in aquifers that are not yet well understood. In this study we investigated the respective influence of land use, groundwater transit time distribution, and hotspot distribution on groundwater denitrification with a particular interest on how a detailed understanding of transit time distributions could be used to upscale the point denitrification measurements to the aquifer-scale. We measured CFC-based groundwater age, oxygen, nitrate, and dinitrogen gas excess in 16 agricultural wells of an unconfined crystalline aquifer in Brittany, France. Groundwater age data was used to calibrate a mechanistic groundwater flow model of the study site. Historical nitrate inputs were reconstructed by using measured nitrate concentrations, dinitrogen gas excess and transit time distributions of the wells. Field data showed large differences in denitrification activity among wells, strongly associated with differences in transit time distribution. This suggests that knowing groundwater flow dynamics and consequent transit time distributions at the catchment-scale could be used to estimate the overall denitrification capacity of agricultural aquifers.

Non-Ideal Compressible-Fluid Dynamics of Fast-Response Pressure Probes for Unsteady Flow Measurements in Turbomachinery

NASA Astrophysics Data System (ADS)

Gori, G.; Molesini, P.; Persico, G.; Guardone, A.

2017-03-01

The dynamic response of pressure probes for unsteady flow measurements in turbomachinery is investigated numerically for fluids operating in non-ideal thermodynamic conditions, which are relevant for e.g. Organic Rankine Cycles (ORC) and super-critical CO2 applications. The step response of a fast-response pressure probe is investigated numerically in order to assess the expected time response when operating in the non-ideal fluid regime. Numerical simulations are carried out exploiting the Non-Ideal Compressible Fluid-Dynamics (NICFD) solver embedded in the open-source fluid dynamics code SU2. The computational framework is assessed against available experimental data for air in dilute conditions. Then, polytropic ideal gas (PIG), i.e. constant specific heats, and Peng-Robinson Stryjek-Vera (PRSV) models are applied to simulate the flow field within the probe operating with siloxane fluid octamethyltrisiloxane (MDM). The step responses are found to depend mainly on the speed of sound of the working fluid, indicating that molecular complexity plays a major role in determining the promptness of the measurement devices. According to the PRSV model, non-ideal effects can increase the step response time with respect to the acoustic theory predictions. The fundamental derivative of gas-dynamic is confirmed to be the driving parameter for evaluating non-ideal thermodynamic effects related to the dynamic calibration of fast-response aerodynamic pressure probes.

40 CFR 1066.130 - Measurement instrument calibrations and verifications.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 33 2014-07-01 2014-07-01 false Measurement instrument calibrations... (CONTINUED) AIR POLLUTION CONTROLS VEHICLE-TESTING PROCEDURES Equipment, Measurement Instruments, Fuel, and Analytical Gas Specifications § 1066.130 Measurement instrument calibrations and verifications. The...

DETERMINATION OF ELEMENTAL COMPOSITIONS BY HIGH RESOLUTION MASS SPECTROMETRY WITHOUT MASS CALIBRANTS

EPA Science Inventory

Widely applicable mass calibrants, including perfluorokerosene, are available for gas-phase introduction of analytes ionized by electron impact (EI) prior to analysis using high resolution mass spectrometry. Unfortunately, no all-purpose calibrants are available for recently dev...

An intercomparison of NEL and DHL water flow facilities using a twin orifice plate flowmeter assembly

NASA Technical Reports Server (NTRS)

Dejong, J.; Spencer, E. A.

1983-01-01

A 205 mm transfer standard orifice plate meter assembly, consisting of two orifice plates in series separated by a length of pipe containing a flow straightener, was calibrated in two water flow facilities. Results show that the agreement in the characteristics of such a differential pressure transfer standard package is within 0.17% over a 10:1 range from flow rates of approximately 8 to 80 l/sec. When the range over which the comparison was made was limited to that for which the calibration graphs gave straight lines, the agreement is 0.1% in 3 of the 4 calibrations (0.17% in the fourth).

Tradeoffs among watershed model calibration targets for parameter estimation

EPA Science Inventory

Hydrologic models are commonly calibrated by optimizing a single objective function target to compare simulated and observed flows, although individual targets are influenced by specific flow modes. Nash-Sutcliffe efficiency (NSE) emphasizes flood peaks in evaluating simulation f...

Preparation and Thermoelectric Characteristics of ITO/PtRh:PtRh Thin Film Thermocouple

NASA Astrophysics Data System (ADS)

Zhao, Xiaohui; Wang, Hongmin; Zhao, Zixiang; Zhang, Wanli; Jiang, Hongchuan

2017-12-01

Thin film thermocouples (TFTCs) can provide more precise in situ temperature measurement for aerospace propulsion systems without disturbance of gas flow and surface temperature distribution of the hot components. ITO /PtRh:PtRh TFTC with multilayer structure was deposited on alumina ceramic substrate by magnetron sputtering. After annealing, the TFTC was statically calibrated for multiple cycles with temperature up to 1000 °C. The TFTC with excellent stability and repeatability was realized for the negligible variation of EMF in different calibration cycles. It is believed that owing to oxygen diffusion barriers by the oxidation of top PtRh layer and Schottky barriers formed at the grain boundaries of ITO, the variation of the carrier concentration of ITO film is minimized. Meanwhile, the life time of TFTC is more than 30 h in harsh environment. This makes ITO/PtRh:PtRh TFTC a promising candidate for precise surface temperature measurement of hot components of aeroengines.

Preparation and Thermoelectric Characteristics of ITO/PtRh:PtRh Thin Film Thermocouple.

PubMed

Zhao, Xiaohui; Wang, Hongmin; Zhao, Zixiang; Zhang, Wanli; Jiang, Hongchuan

2017-12-15

Thin film thermocouples (TFTCs) can provide more precise in situ temperature measurement for aerospace propulsion systems without disturbance of gas flow and surface temperature distribution of the hot components. ITO/PtRh:PtRh TFTC with multilayer structure was deposited on alumina ceramic substrate by magnetron sputtering. After annealing, the TFTC was statically calibrated for multiple cycles with temperature up to 1000 °C. The TFTC with excellent stability and repeatability was realized for the negligible variation of EMF in different calibration cycles. It is believed that owing to oxygen diffusion barriers by the oxidation of top PtRh layer and Schottky barriers formed at the grain boundaries of ITO, the variation of the carrier concentration of ITO film is minimized. Meanwhile, the life time of TFTC is more than 30 h in harsh environment. This makes ITO/PtRh:PtRh TFTC a promising candidate for precise surface temperature measurement of hot components of aeroengines.

Measuring Pressure Has a New Standard

NASA Technical Reports Server (NTRS)

2002-01-01

The Force-Balanced Piston Gauge (FPG) tests and calibrates instrumentation operating in the low pressure range. The system provides a traceable, primary calibration standard for measuring pressures in the range of near 0 to 15 kPa (2.2 psi) in both gauge and absolute measurement modes. The hardware combines a large area piston-cylinder with a load cell measuring the force resulting from pressures across the piston. The mass of the piston can be tared out, allowing measurement to start from zero. A pressure higher than the measured pressure, which keeps the piston centered, lubricates an innovative conical gap located between the piston and the cylinder, eliminating the need for piston rotation. A pressure controller based on the control of low gas flow automates the pressure control. DHI markets the FPG as an automated primary standard for very low-gauge and absolute pressures. DHI is selling the FPG to high-end metrology laboratories on a case by case basis, with a full commercial release to follow.

Effects of Distortion on Mass Flow Plug Calibration

NASA Technical Reports Server (NTRS)

Sasson, Jonathan; Davis, David O.; Barnhart, Paul J.

2015-01-01

A numerical, and experimental investigation to study the effects of flow distortion on a Mass Flow Plug (MFP) used to control and measure mass-flow during an inlet test has been conducted. The MFP was first calibrated using the WIND-US flow solver for uniform (undistorted) inflow conditions. These results are shown to compare favorably with an experimental calibration under similar conditions. The effects of distortion were investigated by imposing distorted flow conditions taken from an actual inlet test to the inflow plane of the numerical simulation. The computational fluid dynamic (CFD) based distortion study only showed the general trend in mass flow rate. The study used only total pressure as the upstream boundary condition, which was not enough to define the flow. A better simulation requires knowledge of the turbulence structure and a specific distortion pattern over a range of plug positions. It is recommended that future distortion studies utilize a rake with at least the same amount of pitot tubes as the AIP rake.

Measurement of Lipid Accumulation in Chlorella vulgaris via Flow Cytometry and Liquid-State ¹H NMR Spectroscopy for Development of an NMR-Traceable Flow Cytometry Protocol

PubMed Central

Bono Jr., Michael S.; Garcia, Ravi D.; Sri-Jayantha, Dylan V.; Ahner, Beth A.; Kirby, Brian J.

2015-01-01

In this study, we cultured Chlorella vulgaris cells with a range of lipid contents, induced via nitrogen starvation, and characterized them via flow cytometry, with BODIPY 505/515 as a fluorescent lipid label, and liquid-state 1H NMR spectroscopy. In doing so, we demonstrate the utility of calibrating flow cytometric measurements of algal lipid content using triacylglyceride (TAG, also known as triacylglycerol or triglyceride) content per cell as measured via quantitative 1H NMR. Ensemble-averaged fluorescence of BODIPY-labeled cells was highly correlated with average TAG content per cell measured by bulk NMR, with a linear regression yielding a linear fit with r 2 = 0.9974. This correlation compares favorably to previous calibrations of flow cytometry protocols to lipid content measured via extraction, and calibration by NMR avoids the time and complexity that is generally required for lipid quantitation via extraction. Flow cytometry calibrated to a direct measurement of TAG content can be used to investigate the distribution of lipid contents for cells within a culture. Our flow cytometry measurements showed that Chlorella vulgaris cells subjected to nitrogen limitation exhibited higher mean lipid content but a wider distribution of lipid content that overlapped the relatively narrow distribution of lipid content for replete cells, suggesting that nitrogen limitation induces lipid accumulation in only a subset of cells. Calibration of flow cytometry protocols using direct in situ measurement of TAG content via NMR will facilitate rapid development of more precise flow cytometry protocols, enabling investigation of algal lipid accumulation for development of more productive algal biofuel feedstocks and cultivation protocols. PMID:26267664

Measurement of lipid accumulation in Chlorella vulgaris via flow cytometry and liquid-state ¹H NMR spectroscopy for development of an NMR-traceable flow cytometry protocol.

PubMed

Bono, Michael S; Garcia, Ravi D; Sri-Jayantha, Dylan V; Ahner, Beth A; Kirby, Brian J

2015-01-01

In this study, we cultured Chlorella vulgaris cells with a range of lipid contents, induced via nitrogen starvation, and characterized them via flow cytometry, with BODIPY 505/515 as a fluorescent lipid label, and liquid-state 1H NMR spectroscopy. In doing so, we demonstrate the utility of calibrating flow cytometric measurements of algal lipid content using triacylglyceride (TAG, also known as triacylglycerol or triglyceride) content per cell as measured via quantitative 1H NMR. Ensemble-averaged fluorescence of BODIPY-labeled cells was highly correlated with average TAG content per cell measured by bulk NMR, with a linear regression yielding a linear fit with r2 = 0.9974. This correlation compares favorably to previous calibrations of flow cytometry protocols to lipid content measured via extraction, and calibration by NMR avoids the time and complexity that is generally required for lipid quantitation via extraction. Flow cytometry calibrated to a direct measurement of TAG content can be used to investigate the distribution of lipid contents for cells within a culture. Our flow cytometry measurements showed that Chlorella vulgaris cells subjected to nitrogen limitation exhibited higher mean lipid content but a wider distribution of lipid content that overlapped the relatively narrow distribution of lipid content for replete cells, suggesting that nitrogen limitation induces lipid accumulation in only a subset of cells. Calibration of flow cytometry protocols using direct in situ measurement of TAG content via NMR will facilitate rapid development of more precise flow cytometry protocols, enabling investigation of algal lipid accumulation for development of more productive algal biofuel feedstocks and cultivation protocols.

Development of a multiperspective optical measuring system for investigating decaying switching arcs at the nozzle exit of circuit breakers.

PubMed

Stoffels, M; Simon, S; Nikolic, P G; Stoller, P; Carstensen, J

2017-03-01

High-voltage gas circuit breakers, which play an important role in the operation and protection of the power grid, function by drawing an arc between two contacts and then extinguishing it by cooling it using a transonic gas flow. Improving the design of circuit breakers requires an understanding of the physical processes in the interruption of the arc, particularly during the zero crossing of the alternating current (the point in time when the arc can be interrupted). Most diagnostic techniques currently available focus on measurement of current, voltage, and gas pressure at defined locations. However, these integral properties do not give sufficient insight into the arc physics. To understand the current interruption process, spatially resolved information about the density, temperature, and conductivity of the arc and surrounding gas flow is needed. Owing to the three-dimensional, unstable nature of the arc in a circuit breaker, especially near current zero, a spatially resolved, tomographic diagnostic technique is required that is capable of freezing the rapid, transient behavior and that is insensitive to the vibrations and electromagnetic interference inherent in the interruption of short-circuit current arcs. Here a new measurement system, based on background-oriented schlieren (BOS) imaging, is presented and assessed. BOS imaging using four beams consisting of white light sources, a background pattern, imaging optics, and a camera permits measurement of the line-of-sight integrated refractive index. Tomographic reconstruction is used to determine the three-dimensional, spatially resolved index of refraction distribution that in turn is used to calculate the density. The quantitative accuracy of a single beam of the BOS setup is verified by using a calibration lens with a known focal length. The ability of the tomographic reconstruction to detect asymmetric features of the arc and surrounding gas flow is assessed semiquantitatively using a nozzle that generates two gas jets, as described in [Exp. Fluids43, 241 (2007)EXFLDU0723-486410.1007/s00348-007-0331-1]. Experiments using a simple model of a circuit breaker, which provides optical access to an ∼1  kA arc that burns between two contacts and is blown through a nozzle system by synthetic air from a high pressure reservoir, are also described. The density in the decaying arc and surrounding gas flow is reconstructed, and the limitations of the technique, which are related to the temporal and spatial resolution, are addressed.

New method for determining heats of combustion of gaseous hydrocarbons

NASA Technical Reports Server (NTRS)

Singh, J. J.; Sprinkle, D. R.; Puster, R. L.

1985-01-01

As a spin off of a system developed for monitoring and controlling the oxygen concentration in the Langley 8-foot High Temperature Tunnel, a highly accurate on-line technique was developed for determining heats of combustion of natural gas samples. It is based on measuring the ratio m/n, where m is the (volumetric) flowrate of oxygen required to enrich the carrier air in which the test gas flowing at the rate n is burned, such that the mole fraction of oxygen in the combustion product gases equals that in the carrier air. The m/n ratio is directly related to the heats of combustion of the saturated hydrocarbons present in the natural gas. A measurement of the m/n ratio for the test gas can provide a direct means of determination of its heat of combustion by using the calibration graph relating the m/n values for pure saturated hydrocarbons with their heats of combustion. The accuracy of the technique is determine solely by the accuracy with which the flowrates m and n can be measured and is of the order of 2 percent in the present study. The theoretical principles and experimental results are discussed.

Thermal/Pyrolysis Gas Flow Analysis of Carbon Phenolic Material

NASA Technical Reports Server (NTRS)

Clayton, J. Louie

2001-01-01

Provided in this study are predicted in-depth temperature and pyrolysis gas pressure distributions for carbon phenolic materials that are externally heated with a laser source. Governing equations, numerical techniques and comparisons to measured temperature data are also presented. Surface thermochemical conditions were determined using the Aerotherm Chemical Equilibrium (ACE) program. Surface heating simulation used facility calibrated radiative and convective flux levels. Temperatures and pyrolysis gas pressures are predicted using an upgraded form of the SINDA/CMA program that was developed by NASA during the Solid Propulsion Integrity Program (SPIP). Multispecie mass balance, tracking of condensable vapors, high heat rate kinetics, real gas compressibility and reduced mixture viscosity's have been added to the algorithm. In general, surface and in-depth temperature comparisons are very good. Specie partial pressures calculations show that a saturated water-vapor mixture is the main contributor to peak in-depth total pressure. Further, for most of the cases studied, the water-vapor mixture is driven near the critical point and is believed to significantly increase the local heat capacity of the composite material. This phenomenon if not accounted for in analysis models may lead to an over prediction in temperature response in charring regions of the material.

Design and numerical simulation on an auto-cumulative flowmeter in horizontal oil-water two-phase flow

NASA Astrophysics Data System (ADS)

Xie, Beibei; Kong, Lingfu; Kong, Deming; Kong, Weihang; Li, Lei; Liu, Xingbin; Chen, Jiliang

2017-11-01

In order to accurately measure the flow rate under the low yield horizontal well conditions, an auto-cumulative flowmeter (ACF) was proposed. Using the proposed flowmeter, the oil flow rate in horizontal oil-water two-phase segregated flow can be finely extracted. The computational fluid dynamics software Fluent was used to simulate the fluid of the ACF in oil-water two-phase flow. In order to calibrate the simulation measurement of the ACF, a novel oil flow rate measurement method was further proposed. The models of the ACF were simulated to obtain and calibrate the oil flow rate under different total flow rates and oil cuts. Using the finite-element method, the structure of the seven conductance probes in the ACF was simulated. The response values for the probes of the ACF under the conditions of oil-water segregated flow were obtained. The experiments for oil-water segregated flow under different heights of the oil accumulation in horizontal oil-water two-phase flow were carried out to calibrate the ACF. The validity of the oil flow rate measurement in horizontal oil-water two-phase flow was verified by simulation and experimental results.

Design and numerical simulation on an auto-cumulative flowmeter in horizontal oil-water two-phase flow.

PubMed

Xie, Beibei; Kong, Lingfu; Kong, Deming; Kong, Weihang; Li, Lei; Liu, Xingbin; Chen, Jiliang

2017-11-01

In order to accurately measure the flow rate under the low yield horizontal well conditions, an auto-cumulative flowmeter (ACF) was proposed. Using the proposed flowmeter, the oil flow rate in horizontal oil-water two-phase segregated flow can be finely extracted. The computational fluid dynamics software Fluent was used to simulate the fluid of the ACF in oil-water two-phase flow. In order to calibrate the simulation measurement of the ACF, a novel oil flow rate measurement method was further proposed. The models of the ACF were simulated to obtain and calibrate the oil flow rate under different total flow rates and oil cuts. Using the finite-element method, the structure of the seven conductance probes in the ACF was simulated. The response values for the probes of the ACF under the conditions of oil-water segregated flow were obtained. The experiments for oil-water segregated flow under different heights of the oil accumulation in horizontal oil-water two-phase flow were carried out to calibrate the ACF. The validity of the oil flow rate measurement in horizontal oil-water two-phase flow was verified by simulation and experimental results.

The use of computer models to predict temperature and smoke movement in high bay spaces

NASA Technical Reports Server (NTRS)

Notarianni, Kathy A.; Davis, William D.

1993-01-01

The Building and Fire Research Laboratory (BFRL) was given the opportunity to make measurements during fire calibration tests of the heat detection system in an aircraft hangar with a nominal 30.4 (100 ft) ceiling height near Dallas, TX. Fire gas temperatures resulting from an approximately 8250 kW isopropyl alcohol pool fire were measured above the fire and along the ceiling. The results of the experiments were then compared to predictions from the computer fire models DETACT-QS, FPETOOL, and LAVENT. In section A of the analysis conducted, DETACT-QS AND FPETOOL significantly underpredicted the gas temperature. LAVENT at the position below the ceiling corresponding to maximum temperature and velocity provided better agreement with the data. For large spaces, hot gas transport time and an improved fire plume dynamics model should be incorporated into the computer fire model activation routines. A computational fluid dynamics (CFD) model, HARWELL FLOW3D, was then used to model the hot gas movement in the space. Reasonable agreement was found between the temperatures predicted from the CFD calculations and the temperatures measured in the aircraft hangar. In section B, an existing NASA high bay space was modeled using the CFD model. The NASA space was a clean room, 27.4 m (90 ft) high with forced horizontal laminar flow. The purpose of this analysis is to determine how the existing fire detection devices would respond to various size fires in the space. The analysis was conducted for 32 MW, 400 kW, and 40 kW fires.

Estimation of the quantification uncertainty from flow injection and liquid chromatography transient signals in inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Laborda, Francisco; Medrano, Jesús; Castillo, Juan R.

2004-06-01

The quality of the quantitative results obtained from transient signals in high-performance liquid chromatography-inductively coupled plasma mass spectrometry (HPLC-ICPMS) and flow injection-inductively coupled plasma mass spectrometry (FI-ICPMS) was investigated under multielement conditions. Quantification methods were based on multiple-point calibration by simple and weighted linear regression, and double-point calibration (measurement of the baseline and one standard). An uncertainty model, which includes the main sources of uncertainty from FI-ICPMS and HPLC-ICPMS (signal measurement, sample flow rate and injection volume), was developed to estimate peak area uncertainties and statistical weights used in weighted linear regression. The behaviour of the ICPMS instrument was characterized in order to be considered in the model, concluding that the instrument works as a concentration detector when it is used to monitorize transient signals from flow injection or chromatographic separations. Proper quantification by the three calibration methods was achieved when compared to reference materials, although the double-point calibration allowed to obtain results of the same quality as the multiple-point calibration, shortening the calibration time. Relative expanded uncertainties ranged from 10-20% for concentrations around the LOQ to 5% for concentrations higher than 100 times the LOQ.

An implantable blood pressure and flow transmitter.

NASA Technical Reports Server (NTRS)

Rader, R. D.; Meehan, J. P.; Henriksen, J. K. C.

1973-01-01

A miniature totally implantable FM/FM telemetry system has been developed to simultaneously measure blood pressure and blood flow, thus providing an appreciation of the hemodynamics of the circulation to the entire body or to a particular organ. Developed for work with animal subjects, the telemetry system's transmission time is controlled by an RF signal that permits an operating life of several months. Pressure is detected by a miniature intravascular transducer and flow is detected by an extravascular interferometric ultrasonic technique. Both pressure and flow are calibrated prior to implanting. The pressure calibration can be checked after the implanting by cannulation; flow calibration can be verified only at the end of the experiment by determining the voltage output from the implanted sensing system as a function of several measured flow rates. The utility of this device has been established by its use in investigating canine renal circulation during exercise, emotional encounters, administration of drugs, and application of accelerative forces.

Two-stage preconcentrator for vapor/particle detection

DOEpatents

Linker, Kevin L.; Brusseau, Charles A.

2002-01-01

A device for concentrating particles from a high volume gas stream and delivering the particles for detection in a low volume gas stream includes first and second preconcentrators. The first preconcentrator has a first structure for retaining particles in a first gas flow path through which a first gas flows at a relatively high volume, valves for selectively stopping the first gas flow; and a second gas flow path through which gas flows at an intermediate flow volume for moving particles from the first structure. The second preconcentrator includes a second structure for retaining particles in the second gas flow path; a valve for selectively stopping the second gas flow; and a third gas flow path through which gas flows at a low volume for moving particles from the second structure to a detector. Each of the particle retaining structures is preferably a metal screen that may be resistively heated by application of an electric potential to release the particles.

Hot-wire calibration in subsonic/transonic flow regimes

NASA Technical Reports Server (NTRS)

Nagabushana, K. A.; Ash, Robert L.

1995-01-01

A different approach for calibrating hot-wires, which simplifies the calibration procedure and reduces the tunnel run-time by an order of magnitude was sought. In general, it is accepted that the directly measurable quantities in any flow are velocity, density, and total temperature. Very few facilities have the capability of varying the total temperature over an adequate range. However, if the overheat temperature parameter, a(sub w), is used to calibrate the hot-wire then the directly measurable quantity, voltage, will be a function of the flow variables and the overheat parameter i.e., E = f(u,p,a(sub w), T(sub w)) where a(sub w) will contain the needed total temperature information. In this report, various methods of evaluating sensitivities with different dependent and independent variables to calibrate a 3-Wire hot-wire probe using a constant temperature anemometer (CTA) in subsonic/transonic flow regimes is presented. The advantage of using a(sub w) as the independent variable instead of total temperature, t(sub o), or overheat temperature parameter, tau, is that while running a calibration test it is not necessary to know the recovery factor, the coefficients in a wire resistance to temperature relationship for a given probe. It was deduced that the method employing the relationship E = f (u,p,a(sub w)) should result in the most accurate calibration of hot wire probes. Any other method would require additional measurements. Also this method will allow calibration and determination of accurate temperature fluctuation information even in atmospheric wind tunnels where there is no ability to obtain any temperature sensitivity information at present. This technique greatly simplifies the calibration process for hot-wires, provides the required calibration information needed in obtaining temperature fluctuations, and reduces both the tunnel run-time and the test matrix required to calibrate hotwires. Some of the results using the above techniques are presented in an appendix.

Traffic evacuation time under nonhomogeneous conditions.

PubMed

Fazio, Joseph; Shetkar, Rohan; Mathew, Tom V

2017-06-01

During many manmade and natural crises such as terrorist threats, floods, hazardous chemical and gas leaks, emergency personnel need to estimate the time in which people can evacuate from the affected urban area. Knowing an estimated evacuation time for a given crisis, emergency personnel can plan and prepare accordingly with the understanding that the actual evacuation time will take longer. Given the urban area to be evacuated, street widths exiting the area's perimeter, the area's population density, average vehicle occupancy, transport mode share and crawl speed, an estimation of traffic evacuation time can be derived. Peak-hour traffic data collected at three, midblock, Mumbai sites of varying geometric features and traffic composition were used in calibrating a model that estimates peak-hour traffic flow rates. Model validation revealed a correlation coefficient of +0.98 between observed and predicted peak-hour flow rates. A methodology is developed that estimates traffic evacuation time using the model.

Description and preliminary calibration results for the Langley hypersonic CF4 tunnel

NASA Technical Reports Server (NTRS)

Midden, R. E.; Miller, C. G.

1978-01-01

A detailed description of the hypersonic CF4 tunnel is presented along with discussion of the basic components, instrumentation, and operating procedure. Operational experience with the CF4 reclaimer and lead-bath heater is discussed. Comparison of measured and predicted shock detachment distance on a sphere and pressure distributions measured on a sharp leading-edge flat plate revealed the absence of significant flow nonuniformity and lent creditability to predicted free stream flow conditions. The economic operation of this facility centers about the CF4 reclaimer, which was designed to operate at an efficiency of 90 to 95 percent. A number of modifications were made to the reclaimer system to improve its performance, and presently, the system reclaims approximately 75 percent of the test gas. Even with current budgetary constraints, this efficiency permits the CF4 tunnel to be operated as a viable research wind tunnel.

Calibration of the NASA Glenn 8- by 6-Foot Supersonic Wind Tunnel (1996 and 1997 Tests)

NASA Technical Reports Server (NTRS)

Arrington, E. Allen

2012-01-01

There were several physical and operational changes made to the NASA Glenn Research Center 8- by 6-Foot Supersonic Wind Tunnel during the period of 1992 through 1996. Following each of these changes, a facility calibration was conducted to provide the required information to support the research test programs. Due to several factors (facility research test schedule, facility downtime and continued facility upgrades), a full test section calibration was not conducted until 1996. This calibration test incorporated all test section configurations and covered the existing operating range of the facility. However, near the end of that test entry, two of the vortex generators mounted on the compressor exit tailcone failed causing minor damage to the honeycomb flow straightener. The vortex generators were removed from the facility and calibration testing was terminated. A follow-up test entry was conducted in 1997 in order to fully calibrate the facility without the effects of the vortex generators and to provide a complete calibration of the newly expanded low speed operating range. During the 1997 tunnel entry, all planned test points required for a complete test section calibration were obtained. This data set included detailed in-plane and axial flow field distributions for use in quantifying the test section flow quality.

Estimation of future flow regime for a spatially varied Himalayan watershed using improved multi-site calibration method of SWAT model.

NASA Astrophysics Data System (ADS)

Pradhanang, S. M.; Hasan, M. A.; Booth, P.; Fallatah, O.

2016-12-01

The monsoon and snow driven regime in the Himalayan region has received increasing attention in the recent decade regarding the effects of climate change on hydrologic regimes. Modeling streamflow in such spatially varied catchment requires proper calibration and validation in hydrologic modeling. While calibration and validation are time consuming and computationally intensive, an effective regionalized approach with multi-site information is crucial for flow estimation, especially in daily scale. In this study, we adopted a multi-site approach to calibration and validation of the Soil Water Assessment Tool (SWAT) model for the Karnali river catchment, which is characterized as being the most vulnerable catchment to climate change in the Himalayan region. APHRODITE's (Asian Precipitation - Highly-Resolved Observational Data Integration Towards Evaluation) daily gridded precipitation data, one of the accurate and reliable weather date over this region were utilized in this study. The model evaluation of the entire catchment divided into four sub-catchments, utilizing discharge records from 1963 to 2010. In previous studies, multi-site calibration used only a single set of calibration parameters for all sub-catchment of a large watershed. In this study, we introduced a technique that can incorporate different sets of calibration parameters for each sub-basin, which eventually ameliorate the flow of the whole watershed. Results show that the calibrated model with new method can capture almost identical pattern of flow over the region. The predicted daily streamflow matched the observed values, with a Nash-Sutcliffe coefficient of 0.73 during calibration and 0.71 during validation period. The method perfumed better than existing multi-site calibration methods. To assess the influence of continued climate change on hydrologic processes, we modified the weather inputs for the model using precipitation and temperature changes for two Representative Concentration Pathways (RCPs) scenarios, RCP 4.5 and 8.5. Climate simulation for RCP scenarios were conducted from 1981-2100, where 1981-2005 was considered as baseline and 2006-2100 was considered as the future projection. The result shows that probability of flooding will eventually increase in future years due to increased flow in both scenarios.

Gas flow through rough microchannels in the transition flow regime.

PubMed

Deng, Zilong; Chen, Yongping; Shao, Chenxi

2016-01-01

A multiple-relaxation-time lattice Boltzmann model of Couette flow is developed to investigate the rarified gas flow through microchannels with roughness characterized by fractal geometry, especially to elucidate the coupled effects of roughness and rarefaction on microscale gas flow in the transition flow regime. The results indicate that the surface roughness effect on gas flow behavior becomes more significant in rarefied gas flow with the increase of Knudsen number. We find the gas flow behavior in the transition flow regime is more sensitive to roughness height than that in the slip flow regime. In particular, the influence of fractal dimension on rarefied gas flow behavior is less significant than roughness height.

Cone-Probe Rake Design and Calibration for Supersonic Wind Tunnel Models

NASA Technical Reports Server (NTRS)

Won, Mark J.

1999-01-01

A series of experimental investigations were conducted at the NASA Langley Unitary Plan Wind Tunnel (UPWT) to calibrate cone-probe rakes designed to measure the flow field on 1-2% scale, high-speed wind tunnel models from Mach 2.15 to 2.4. The rakes were developed from a previous design that exhibited unfavorable measurement characteristics caused by a high probe spatial density and flow blockage from the rake body. Calibration parameters included Mach number, total pressure recovery, and flow angularity. Reference conditions were determined from a localized UPWT test section flow survey using a 10deg supersonic wedge probe. Test section Mach number and total pressure were determined using a novel iterative technique that accounted for boundary layer effects on the wedge surface. Cone-probe measurements were correlated to the surveyed flow conditions using analytical functions and recursive algorithms that resolved Mach number, pressure recovery, and flow angle to within +/-0.01, +/-1% and +/-0.1deg , respectively, for angles of attack and sideslip between +/-8deg. Uncertainty estimates indicated the overall cone-probe calibration accuracy was strongly influenced by the propagation of measurement error into the calculated results.

High-Pressure Gaseous Burner (HPGB) Facility Completed for Quantitative Laser Diagnostics Calibration

NASA Technical Reports Server (NTRS)

Nguyen, Quang-Viet

2002-01-01

A gas-fueled high-pressure combustion facility with optical access, which was developed over the last 2 years, has just been completed. The High Pressure Gaseous Burner (HPGB) rig at the NASA Glenn Research Center can operate at sustained pressures up to 60 atm with a variety of gaseous fuels and liquid jet fuel. The facility is unique as it is the only continuous-flow, hydrogen-capable, 60-atm rig in the world with optical access. It will provide researchers with new insights into flame conditions that simulate the environment inside the ultra-high-pressure-ratio combustion chambers of tomorrow's advanced aircraft engines. The facility provides optical access to the flame zone, enabling the calibration of nonintrusive optical diagnostics to measure chemical species and temperature. The data from the HPGB rig enables the validation of numerical codes that simulate gas turbine combustors, such as the National Combustor Code (NCC). The validation of such numerical codes is often best achieved with nonintrusive optical diagnostic techniques that meet these goals: information-rich (multispecies) and quantitative while providing good spatial and time resolution. Achieving these goals is a challenge for most nonintrusive optical diagnostic techniques. Raman scattering is a technique that meets these challenges. Raman scattering occurs when intense laser light interacts with molecules to radiate light at a shifted wavelength (known as the Raman shift). This shift in wavelength is unique to each chemical species and provides a "fingerprint" of the different species present. The facility will first be used to gather a comprehensive data base of laser Raman spectra at high pressures. These calibration data will then be used to quantify future laser Raman measurements of chemical species concentration and temperature in this facility and other facilities that use Raman scattering.

[New method of mixed gas infrared spectrum analysis based on SVM].

PubMed

Bai, Peng; Xie, Wen-Jun; Liu, Jun-Hua

2007-07-01

A new method of infrared spectrum analysis based on support vector machine (SVM) for mixture gas was proposed. The kernel function in SVM was used to map the seriously overlapping absorption spectrum into high-dimensional space, and after transformation, the high-dimensional data could be processed in the original space, so the regression calibration model was established, then the regression calibration model with was applied to analyze the concentration of component gas. Meanwhile it was proved that the regression calibration model with SVM also could be used for component recognition of mixture gas. The method was applied to the analysis of different data samples. Some factors such as scan interval, range of the wavelength, kernel function and penalty coefficient C that affect the model were discussed. Experimental results show that the component concentration maximal Mean AE is 0.132%, and the component recognition accuracy is higher than 94%. The problems of overlapping absorption spectrum, using the same method for qualitative and quantitative analysis, and limit number of training sample, were solved. The method could be used in other mixture gas infrared spectrum analyses, promising theoretic and application values.

Quality assured measurements of animal building emissions: gas concentrations.

PubMed

Heber, Albert J; Ni, Ji-Qin; Lim, Teng T; Tao, Pei-Chun; Schmidt, Amy M; Koziel, Jacek A; Beasley, David B; Hoff, Steven J; Nicolai, Richard E; Jacobson, Larry D; Zhang, Yuanhui

2006-10-01

Comprehensive field studies were initiated in 2002 to measure emissions of ammonia (NH3), hydrogen sulfide (H2S), carbon dioxide (CO2), methane (CH4), nonmethane hydrocarbons (NMHC), particulate matter <10 microm in diameter, and total suspended particulate from swine and poultry production buildings in the United States. This paper focuses on the quasicontinuous gas concentration measurement at multiple locations among paired barns in seven states. Documented principles, used in air pollution monitoring at industrial sources, were applied in developing quality assurance (QA) project plans for these studies. Air was sampled from multiple locations with each gas analyzed with one high quality commercial gas analyzer that was located in an environmentally controlled on-farm instrument shelter. A nominal 4 L/min gas sampling system was designed and constructed with Teflon wetted surfaces, bypass pumping, and sample line flow and pressure sensors. Three-way solenoids were used to automatically switch between multiple gas sampling lines with > or =10 min sampling intervals. Inside and outside gas sampling probes were between 10 and 115 m away from the analyzers. Analyzers used chemiluminescence, fluorescence, photoacoustic infrared, and photoionization detectors for NH3, H2S, CO2, CH4, and NMHC, respectively. Data were collected using personal computer-based data acquisition hardware and software. This paper discusses the methodology of gas concentration measurements and the unique challenges that livestock barns pose for achieving desired accuracy and precision, data representativeness, comparability and completeness, and instrument calibration and maintenance.

Calibration of the computer model describing flows in the water supply system; example of the application of a genetic algorithm

NASA Astrophysics Data System (ADS)

Orłowska-Szostak, Maria; Orłowski, Ryszard

2017-11-01

The paper discusses some relevant aspects of the calibration of a computer model describing flows in the water supply system. The authors described an exemplary water supply system and used it as a practical illustration of calibration. A range of measures was discussed and applied, which improve the convergence and effective use of calculations in the calibration process and also the effect of such calibration which is the validity of the results obtained. Drawing up results of performed measurements, i.e. estimating pipe roughnesses, the authors performed using the genetic algorithm implementation of which is a software developed by Resan Labs company from Brazil.

Continuous high-frequency dissolved O2/Ar measurements by equilibrator inlet mass spectrometry.

PubMed

Cassar, Nicolas; Barnett, Bruce A; Bender, Michael L; Kaiser, Jan; Hamme, Roberta C; Tilbrook, Bronte

2009-03-01

The oxygen (O(2)) concentration in the surface ocean is influenced by biological and physical processes. With concurrent measurements of argon (Ar), which has similar solubility properties as oxygen, we can remove the physical contribution to O(2) supersaturation and determine the biological oxygen supersaturation. Biological O(2) supersaturation in the surface ocean reflects the net metabolic balance between photosynthesis and respiration, i.e., the net community productivity (NCP). We present a new method for continuous shipboard measurements of O(2)/Ar by equilibrator inlet mass spectrometry (EIMS). From these measurements and an appropriate gas exchange parametrization, NCP can be estimated at high spatial and temporal resolution. In the EIMS configuration, seawater from the ship's continuous intake flows through a cartridge enclosing a gas-permeable microporous membrane contactor. Gases in the headspace of the cartridge equilibrate with dissolved gases in the flowing seawater. A fused-silica capillary continuously samples headspace gases, and the O(2)/Ar ratio is measured by mass spectrometry. The ion current measurements on the mass spectrometer reflect the partial pressures of dissolved gases in the water flowing through the equilibrator. Calibration of the O(2)/Ar ion current ratio (32/40) is performed automatically every 2 h by sampling ambient air through a second capillary. A conceptual model demonstrates that the ratio of gases reaching the mass spectrometer is dependent on several parameters, such as the differences in molecular diffusivities and solubilities of the gases. Laboratory experiments and field observations performed by EIMS are discussed. We also present preliminary evidence that other gas measurements, such as N(2)/Ar and pCO(2) measurements, may potentially be performed with EIMS. Finally, we compare the characteristics of the EIMS with the previously described membrane inlet mass spectrometry (MIMS) approach.

Software to Control and Monitor Gas Streams

NASA Technical Reports Server (NTRS)

Arkin, C.; Curley, Charles; Gore, Eric; Floyd, David; Lucas, Damion

2012-01-01

This software package interfaces with various gas stream devices such as pressure transducers, flow meters, flow controllers, valves, and analyzers such as a mass spectrometer. The software provides excellent user interfacing with various windows that provide time-domain graphs, valve state buttons, priority- colored messages, and warning icons. The user can configure the software to save as much or as little data as needed to a comma-delimited file. The software also includes an intuitive scripting language for automated processing. The configuration allows for the assignment of measured values or calibration so that raw signals can be viewed as usable pressures, flows, or concentrations in real time. The software is based on those used in two safety systems for shuttle processing and one volcanic gas analysis system. Mass analyzers typically have very unique applications and vary from job to job. As such, software available on the market is usually inadequate or targeted on a specific application (such as EPA methods). The goal was to develop powerful software that could be used with prototype systems. The key problem was to generalize the software to be easily and quickly reconfigurable. At Kennedy Space Center (KSC), the prior art consists of two primary methods. The first method was to utilize Lab- VIEW and a commercial data acquisition system. This method required rewriting code for each different application and only provided raw data. To obtain data in engineering units, manual calculations were required. The second method was to utilize one of the embedded computer systems developed for another system. This second method had the benefit of providing data in engineering units, but was limited in the number of control parameters.

Quantitative basis for component factors of gas flow proportional counting efficiencies

NASA Astrophysics Data System (ADS)

Nichols, Michael C.

This dissertation investigates the counting efficiency calibration of a gas flow proportional counter with beta-particle emitters in order to (1) determine by measurements and simulation the values of the component factors of beta-particle counting efficiency for a proportional counter, (2) compare the simulation results and measured counting efficiencies, and (3) determine the uncertainty of the simulation and measurements. Monte Carlo simulation results by the MCNP5 code were compared with measured counting efficiencies as a function of sample thickness for 14C, 89Sr, 90Sr, and 90Y. The Monte Carlo model simulated strontium carbonate with areal thicknesses from 0.1 to 35 mg cm-2. The samples were precipitated as strontium carbonate with areal thicknesses from 3 to 33 mg cm-2 , mounted on membrane filters, and counted on a low background gas flow proportional counter. The estimated fractional standard deviation was 2--4% (except 6% for 14C) for efficiency measurements of the radionuclides. The Monte Carlo simulations have uncertainties estimated to be 5 to 6 percent for carbon-14 and 2.4 percent for strontium-89, strontium-90, and yttrium-90. The curves of simulated counting efficiency vs. sample areal thickness agreed within 3% of the curves of best fit drawn through the 25--49 measured points for each of the four radionuclides. Contributions from this research include development of uncertainty budgets for the analytical processes; evaluation of alternative methods for determining chemical yield critical to the measurement process; correcting a bias found in the MCNP normalization of beta spectra histogram; clarifying the interpretation of the commonly used ICRU beta-particle spectra for use by MCNP; and evaluation of instrument parameters as applied to the simulation model to obtain estimates of the counting efficiency from simulated pulse height tallies.

Flow in Coal Seams: An Unconventional Challenge

NASA Astrophysics Data System (ADS)

Armstrong, R. T.; Mostaghimi, P.; Jing, Y.; Gerami, A.

2016-12-01

A significant unconventional resource for energy is the methane gas stored in shallow coal beds, known as coal seam gas. An integrated imaging and modelling framework is developed for analysing petrophysical behaviour of coals. X-ray micro-computed tomography (micro-CT) is applied using a novel contrast agent method for visualising micrometer-sized fractures in coal. The technique allows for the visualisation of coal features not visible with conventional imaging methods. A Late Permian medium volatile bituminous coal from Moura Coal Mine (Queensland, Australia) is imaged and the resulting three-dimensional coal fracture system is extracted for fluid flow simulations. The results demonstrate a direct relationship between coal lithotype and permeability. Scanning electron microscope and energy dispersive spectrometry (SEM-EDS) together with X-ray diffraction (XRD) methods are used for identifying mineral matters at high resolution. SEM high-resolution images are also used to calibrate the micro-CT images and measure the exact aperture size of fractures. This leads to a more accurate estimation of permeability using micro-CT images. To study the significance of geometry and topology of the fracture system, a fracture reconstruction method based on statistical properties of coal is also developed. The network properties including the frequency, aperture size distribution, length, and spacing of the imaged coal fracture system. This allows for a sensitivity analysis on the effects that coal fracture topology and geometry has on coal petrophysical properties. Furthermore, we generate microfluidic chips based on coal fracture observations. The chip is used for flow experiments to visualise multi-fluid processes and measure recovery of gas. A combined numerical and experimental approach is applied to obtain relative permeability curves for different regions of interest. A number of challenges associated with coal samples are discussed and insights are provided for better understanding of these complex porous media systems.

40 CFR 91.425 - CVS calibration frequency.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.425 CVS calibration frequency. Calibrate the CVS positive displacement pump or critical flow venturi...

40 CFR 91.425 - CVS calibration frequency.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.425 CVS calibration frequency. Calibrate the CVS positive displacement pump or critical flow venturi...

40 CFR 91.425 - CVS calibration frequency.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.425 CVS calibration frequency. Calibrate the CVS positive displacement pump or critical flow venturi...

40 CFR 91.425 - CVS calibration frequency.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.425 CVS calibration frequency. Calibrate the CVS positive displacement pump or critical flow venturi...

40 CFR 91.425 - CVS calibration frequency.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.425 CVS calibration frequency. Calibrate the CVS positive displacement pump or critical flow venturi...

Guide to Flow Measurement for Electric Propulsion Systems

NASA Technical Reports Server (NTRS)

Frieman, Jason D.; Walker, Mitchell L. R.; Snyder, Steve

2013-01-01

In electric propulsion (EP) systems, accurate measurement of the propellant mass flow rate of gas or liquid to the thruster and external cathode is a key input in the calculation of thruster efficiency and specific impulse. Although such measurements are often achieved with commercial mass flow controllers and meters integrated into propellant feed systems, the variability in potential propellant options and flow requirements amongst the spectrum of EP power regimes and devices complicates meter selection, integration, and operation. At the direction of the Committee on Standards for Electric Propulsion Testing, a guide was jointly developed by members of the electric propulsion community to establish a unified document that contains the working principles, methods of implementation and analysis, and calibration techniques and recommendations on the use of mass flow meters in laboratory and spacecraft electric propulsion systems. The guide is applicable to EP devices of all types and power levels ranging from microthrusters to high-power ion engines and Hall effect thrusters. The establishment of a community standard on mass flow metering will help ensure the selection of the proper meter for each application. It will also improve the quality of system performance estimates by providing comprehensive information on the physical phenomena and systematic errors that must be accounted for during the analysis of flow measurement data. This paper will outline the standard methods and recommended practices described in the guide titled "Flow Measurement for Electric Propulsion Systems."

Iodine Hall Thruster Propellant Feed System for a CubeSat

NASA Technical Reports Server (NTRS)

Polzin, Kurt A.

2014-01-01

There has been significant work recently in the development of iodine-fed Hall thrusters for in-space propulsion applications.1 The use of iodine as a propellant provides many advantages over present xenon-gas-fed Hall thruster systems. Iodine is a solid at ambient temperature (no pressurization required) and has no special handling requirements, making it safe for secondary flight opportunities. It has exceptionally high ?I sp (density times specific impulse), making it an enabling technology for small satellite near-term applications and providing system level advantages over mid-term high power electric propulsion options. Iodine provides thrust and efficiency that are comparable to xenonfed Hall thrusters while operating in the same discharge current and voltage regime, making it possible to leverage the development of flight-qualified xenon Hall thruster power processing units for the iodine application. Work at MSFC is presently aimed at designing, integrating, and demonstrating a flight-like iodine feed system suitable for the Hall thruster application. This effort represents a significant advancement in state-of-the-art. Though Iodine thrusters have demonstrated high performance with mission enabling potential, a flight-like feed system has never been demonstrated and iodine compatible components do not yet exist. Presented in this paper is the end-to-end integrated feed system demonstration. The system includes a propellant tank with active feedback-control heating, fill and drain interfaces, latching and proportional flow control valves (PFCV), flow resistors, and flight-like CubeSat power and control electronics. Hardware is integrated into a CubeSat-sized structure, calibrated and tested under vacuum conditions, and operated under under hot-fire conditions using a Busek BHT-200 thruster designed for iodine. Performance of the system is evaluated thorugh accurate measurement of thrust and a calibrated of mass flow rate measurement, which is a function of reservoir temperature/pressure, the flow resistors, and the setting of the PFCV. The calibration is performed using independent flow control monitoring techniques, providing an in situ measure of the flowrate as a function of controllable parameters. The reservoir temperature controls the iodine sublimation rate, providing propellant to ths thruster by pressurizing the propellant feed system to approx.1-2 psi. Control of the temperature and the PFCV are used to maintain reservoir pressure and keep the thruster discharge current constant.

40 CFR 63.1325 - Batch process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2011 CFR

2011-07-01

... production or activity level. (1) If the expected mix of products serves as the basis for the batch mass... from the high-level calibration gas is at least 20 times the standard deviation of the response from... 25A, 40 CFR part 60, appendix A, is acceptable if the response from the high-level calibration gas is...

40 CFR 63.490 - Batch front-end process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2011 CFR

2011-07-01

... limitation is not dependent upon any past production or activity level. (1) If the expected mix of products... acceptable if the response from the high-level calibration gas is at least 20 times the standard deviation of..., appendix A is acceptable if the response from the high-level calibration gas is at least 20 times the...

Sap Flux Scaled Transpiration in Ring-porous Tree Species: Assumptions, Pitfalls and Calibration

NASA Astrophysics Data System (ADS)

Bush, S. E.; Hultine, K. R.; Ehleringer, J. R.

2008-12-01

Thermal dissipation probes for measuring sap flow (Granier-type) at the whole tree and stand level are routinely used in forest ecology and site water balance studies. While the original empirical relationship used to calculate sap flow was reported as independent of wood anatomy (ring-porous, diffuse-porous, tracheid), it has been suggested that potentially large errors in sap flow calculations may occur when using the original calibration for ring-porous species, due to large radial trends in sap velocity and/or shallow sapwood depth. Despite these concerns, sap flux measurements have rarely been calibrated in ring-porous taxa. We used a simple technique to calibrate thermal dissipation sap flux measurements on ring-porous trees in the lab. Calibration measurements were conducted on five ring-porous species in the Salt Lake City, USA metropolitan area including Quercus gambelii (Gambel oak), Gleditsia triacanthos (Honey locust), Elaeagnus angustifolia (Russian olive), Sophora japonica (Japanese pagoda), and Celtis occidentalis (Common hackberry). Six stems per species of approximately 1 m in length were instrumented with heat dissipation probes to measure sap flux concurrently with gravimetric measurements of water flow through each stem. Safranin dye was pulled through the stems following flow rate measurements to determine sapwood area. As expected, nearly all the conducting sapwood area was limited to regions within the current year growth rings. Consequently, we found that the original Granier equation underestimated sap flux density for all species considered. Our results indicate that the use of thermal dissipation probes for measuring sap flow in ring-porous species should be independently calibrated, particularly when species- specific calibration data are not available. Ring-porous taxa are widely distributed and represent an important component of the regional water budgets of many temperate regions. Our results are important for evaluating plant water use of ring-porous tree species with thermal dissipation probes at multiple spatial scales.

Numerical modelling of methane oxidation efficiency and coupled water-gas-heat reactive transfer in a sloping landfill cover.

PubMed

Feng, S; Ng, C W W; Leung, A K; Liu, H W

2017-10-01

Microbial aerobic methane oxidation in unsaturated landfill cover involves coupled water, gas and heat reactive transfer. The coupled process is complex and its influence on methane oxidation efficiency is not clear, especially in steep covers where spatial variations of water, gas and heat are significant. In this study, two-dimensional finite element numerical simulations were carried out to evaluate the performance of unsaturated sloping cover. The numerical model was calibrated using a set of flume model test data, and was then subsequently used for parametric study. A new method that considers transient changes of methane concentration during the estimation of the methane oxidation efficiency was proposed and compared against existing methods. It was found that a steeper cover had a lower oxidation efficiency due to enhanced downslope water flow, during which desaturation of soil promoted gas transport and hence landfill gas emission. This effect was magnified as the cover angle and landfill gas generation rate at the bottom of the cover increased. Assuming the steady-state methane concentration in a cover would result in a non-conservative overestimation of oxidation efficiency, especially when a steep cover was subjected to rainfall infiltration. By considering the transient methane concentration, the newly-modified method can give a more accurate oxidation efficiency. Copyright © 2017. Published by Elsevier Ltd.

Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil

NASA Astrophysics Data System (ADS)

Sut, Magdalena; Fischer, Thomas; Repmann, Frank; Raab, Thomas

2013-04-01

In Germany, at more than 1000 sites, soil is polluted with an anthropogenic contaminant in form of iron-cyanide complexes. These contaminations are caused by former Manufactured Gas Plants (MGPs), where electricity for lighting was produced in the process of coal gasification. The production of manufactured gas was restrained in 1950, which caused cessation of MGPs. Our study describes the application of Polychromix Handheld Field Portable Near-Infrared (NIR) Analyzer to predict the cyanide concentrations in soil. In recent times, when the soil remediation is of major importance, there is a need to develop rapid and non-destructive methods for contaminant determination in the field. In situ analysis enables determination of 'hot spots', is cheap and time saving in comparison to laboratory methods. This paper presents a novel usage of NIR spectroscopy, where a calibration model was developed, using multivariate calibration algorithms, in order to determine NIR spectral response to the cyanide concentration in soil samples. As a control, the contaminant concentration was determined using conventional Flow Injection Analysis (FIA). The experiments revealed that portable near-infrared spectrometers could be a reliable device for identification of contamination 'hot spots', where cyanide concentration are higher than 2400 mg kg-1 in the field and >1750 mg kg-1 after sample preparation in the laboratory, but cannot replace traditional laboratory analyses due to high limits of detection.

A Novel True Triaxial Apparatus to Study the Geomechanical and Fluid Flow Aspects of Energy Exploitations in Geological Formations

NASA Astrophysics Data System (ADS)

Li, Minghui; Yin, Guangzhi; Xu, Jiang; Li, Wenpu; Song, Zhenlong; Jiang, Changbao

2016-12-01

Fluid-solid coupling investigations of the geological storage of CO2, efficient unconventional oil and natural gas exploitations are mostly conducted under conventional triaxial stress conditions ( σ 2 = σ 3), ignoring the effects of σ 2 on the geomechanical properties and permeability of rocks (shale, coal and sandstone). A novel multi-functional true triaxial geophysical (TTG) apparatus was designed, fabricated, calibrated and tested to simulate true triaxial stress ( σ 1 > σ 2 > σ 3) conditions and to reveal geomechanical properties and permeability evolutions of rocks. The apparatus was developed with the capacity to carry out geomechanical and fluid flow experiments at high three-dimensional loading forces and injection pressures under true triaxial stress conditions. The control and measurement of the fluid flow with effective sealing of rock specimen corners were achieved using a specially designed internally sealed fluid flow system. To validate that the apparatus works properly and to recognize the effects of each principal stress on rock deformation and permeability, stress-strain and permeability experiments and a hydraulic fracturing simulation experiment on shale specimens were conducted under true triaxial stress conditions using the TTG apparatus. Results show that the apparatus has advantages in recognizing the effects of σ 2 on the geomechanical properties and permeability of rocks. Results also demonstrate the effectiveness and reliability of the novel TTG apparatus. The apparatus provides a new method of studying the geomechanical properties and permeability evolutions of rocks under true triaxial stress conditions, promoting further investigations of the geological storage of CO2, efficient unconventional oil and gas exploitations.

Quantitative comparison between crowd models for evacuation planning and evaluation

NASA Astrophysics Data System (ADS)

Viswanathan, Vaisagh; Lee, Chong Eu; Lees, Michael Harold; Cheong, Siew Ann; Sloot, Peter M. A.

2014-02-01

Crowd simulation is rapidly becoming a standard tool for evacuation planning and evaluation. However, the many crowd models in the literature are structurally different, and few have been rigorously calibrated against real-world egress data, especially in emergency situations. In this paper we describe a procedure to quantitatively compare different crowd models or between models and real-world data. We simulated three models: (1) the lattice gas model, (2) the social force model, and (3) the RVO2 model, and obtained the distributions of six observables: (1) evacuation time, (2) zoned evacuation time, (3) passage density, (4) total distance traveled, (5) inconvenience, and (6) flow rate. We then used the DISTATIS procedure to compute the compromise matrix of statistical distances between the three models. Projecting the three models onto the first two principal components of the compromise matrix, we find the lattice gas and RVO2 models are similar in terms of the evacuation time, passage density, and flow rates, whereas the social force and RVO2 models are similar in terms of the total distance traveled. Most importantly, we find that the zoned evacuation times of the three models to be very different from each other. Thus we propose to use this variable, if it can be measured, as the key test between different models, and also between models and the real world. Finally, we compared the model flow rates against the flow rate of an emergency evacuation during the May 2008 Sichuan earthquake, and found the social force model agrees best with this real data.

Spatial calibration and temporal validation of flow for regional scale hydrologic modeling

USDA-ARS?s Scientific Manuscript database

Physically based regional scale hydrologic modeling is gaining importance for planning and management of water resources. Calibration and validation of such regional scale model is necessary before applying it for scenario assessment. However, in most regional scale hydrologic modeling, flow validat...

Calibration of nozzle for air mass flow measurement

NASA Astrophysics Data System (ADS)

Uher, Jan; Kanta, Lukáš

2017-09-01

The effort to make calibration measurement of mass flow through a nozzle was not satisfying. Traversing across the pipe radius with Pitot probe was done. The presence of overshoot behind the bend in the pipe was found. The overshoot led to an asymmetric velocity profile.

Calibrant-Free Analyte Quantitation via a Variable Velocity Flow Cell.

PubMed

Beck, Jason G; Skuratovsky, Aleksander; Granger, Michael C; Porter, Marc D

2017-01-17

In this paper, we describe a novel method for analyte quantitation that does not rely on calibrants, internal standards, or calibration curves but, rather, leverages the relationship between disparate and predictable surface-directed analyte flux to an array of sensing addresses and a measured resultant signal. To reduce this concept to practice, we fabricated two flow cells such that the mean linear fluid velocity, U, was varied systematically over an array of electrodes positioned along the flow axis. This resulted in a predictable variation of the address-directed flux of a redox analyte, ferrocenedimethanol (FDM). The resultant limiting currents measured at a series of these electrodes, and accurately described by a convective-diffusive transport model, provided a means to calculate an "unknown" concentration without the use of calibrants, internal standards, or a calibration curve. Furthermore, the experiment and concentration calculation only takes minutes to perform. Deviation in calculated FDM concentrations from true values was minimized to less than 0.5% when empirically derived values of U were employed.

High-efficiency headspace sampling of volatile organic compounds in explosives using capillary microextraction of volatiles (CMV) coupled to gas chromatography-mass spectrometry (GC-MS).

PubMed

Fan, Wen; Almirall, José

2014-03-01

A novel geometry configuration based on sorbent-coated glass microfibers packed within a glass capillary is used to sample volatile organic compounds, dynamically, in the headspace of an open system or in a partially open system to achieve quantitative extraction of the available volatiles of explosives with negligible breakthrough. Air is sampled through the newly developed sorbent-packed 2 cm long, 2 mm diameter capillary microextraction of volatiles (CMV) and subsequently introduced into a commercially available thermal desorption probe fitted directly into a GC injection port. A sorbent coating surface area of ∼5 × 10(-2) m(2) or 5,000 times greater than that of a single solid-phase microextraction (SPME) fiber allows for fast (30 s), flow-through sampling of relatively large volumes using sampling flow rates of ∼1.5 L/min. A direct comparison of the new CMV extraction to a static (equilibrium) SPME extraction of the same headspace sample yields a 30 times improvement in sensitivity for the CMV when sampling nitroglycerine (NG), 2,4-dinitrotoluene (2,4-DNT), and diphenylamine (DPA) in a mixture containing a total mass of 500 ng of each analyte, when spiked into a liter-volume container. Calibration curves were established for all compounds studied, and the recovery was determined to be ∼1 % or better after only 1 min of sampling time. Quantitative analysis is also possible using this extraction technique when the sampling temperature, flow rate, and time are kept constant between calibration curves and the sample.

System using electric furnace exhaust gas to preheat scrap for steelmaking

DOE Office of Scientific and Technical Information (OSTI.GOV)

Takai, K.; Iwasaki, K.

1987-09-08

A method is described for clean preheating of scrap contaminated with oil and organic matter, for steelmaking, using heat from exhaust gas flow from an electric furnace. It consists of: burning any combustibles present in the exhaust gas flow and simultanously separating out dust particles from the exhaust gas flow; heating a predetermined amount of the scrap by heat exchange with a predetermined portion of the exhaust gas flow; removing and collecting dust from the exhaust gas flow after preheating of scrap thereby; sensing the temperature of the exhaust flow; scrubbing the exhaust gas flow with an aqueous solution ofmore » a deodorant solvent flowing at a rate regulated to be in a predetermined relationship related to the exhaust gas temperature sensed prior to scrubbing, thereby generating saturated vapor and reducing the temperature of the exhaust gas flow by a predetermined amount; and electrostatically precipitating out oil mist attached to saturated water vapor and liquid droplets in the exhaust gas flow.« less

40 CFR 86.1326-90 - Calibration of other equipment.

Code of Federal Regulations, 2012 CFR

2012-07-01

... equipment requiring calibration is the gas chromatograph and flame ionization detector used in measuring methanol and the high pressure liquid chromatograph (HPLC) and ultraviolet detector for measuring...

40 CFR 86.1326-90 - Calibration of other equipment.

Code of Federal Regulations, 2011 CFR

2011-07-01

... equipment requiring calibration is the gas chromatograph and flame ionization detector used in measuring methanol and the high pressure liquid chromatograph (HPLC) and ultraviolet detector for measuring...

40 CFR 86.1326-90 - Calibration of other equipment.

Code of Federal Regulations, 2013 CFR

2013-07-01

... equipment requiring calibration is the gas chromatograph and flame ionization detector used in measuring methanol and the high pressure liquid chromatograph (HPLC) and ultraviolet detector for measuring...

40 CFR 86.1326-90 - Calibration of other equipment.

Code of Federal Regulations, 2010 CFR

2010-07-01

... equipment requiring calibration is the gas chromatograph and flame ionization detector used in measuring methanol and the high pressure liquid chromatograph (HPLC) and ultraviolet detector for measuring...

Method and system for measuring multiphase flow using multiple pressure differentials

DOEpatents

Fincke, James R.

2001-01-01

An improved method and system for measuring a multiphase flow in a pressure flow meter. An extended throat venturi is used and pressure of the multiphase flow is measured at three or more positions in the venturi, which define two or more pressure differentials in the flow conduit. The differential pressures are then used to calculate the mass flow of the gas phase, the total mass flow, and the liquid phase. The method for determining the mass flow of the high void fraction fluid flow and the gas flow includes certain steps. The first step is calculating a gas density for the gas flow. The next two steps are finding a normalized gas mass flow rate through the venturi and computing a gas mass flow rate. The following step is estimating the gas velocity in the venturi tube throat. The next step is calculating the pressure drop experienced by the gas-phase due to work performed by the gas phase in accelerating the liquid phase between the upstream pressure measuring point and the pressure measuring point in the venturi throat. Another step is estimating the liquid velocity in the venturi throat using the calculated pressure drop experienced by the gas-phase due to work performed by the gas phase. Then the friction is computed between the liquid phase and a wall in the venturi tube. Finally, the total mass flow rate based on measured pressure in the venturi throat is calculated, and the mass flow rate of the liquid phase is calculated from the difference of the total mass flow rate and the gas mass flow rate.

High accuracy fuel flowmeter. Phase 2C and 3: The mass flowrate calibration of high accuracy fuel flowmeters

NASA Technical Reports Server (NTRS)

Craft, D. William

1992-01-01

A facility for the precise calibration of mass fuel flowmeters and turbine flowmeters located at AMETEK Aerospace Products Inc., Wilmington, Massachusetts is described. This facility is referred to as the Test and Calibration System (TACS). It is believed to be the most accurate test facility available for the calibration of jet engine fuel density measurement. The product of the volumetric flow rate measurement and the density measurement, results in a true mass flow rate determination. A dual-turbine flowmeter was designed during this program. The dual-turbine flowmeter was calibrated on the TACS to show the characteristics of this type of flowmeter. An angular momentum flowmeter was also calibrated on the TACS to demonstrate the accuracy of a true mass flowmeter having a 'state-of-the-art' design accuracy.

Internal Water Vapor Photoacoustic Calibration

NASA Technical Reports Server (NTRS)

Pilgrim, Jeffrey S.

2009-01-01

Water vapor absorption is ubiquitous in the infrared wavelength range where photoacoustic trace gas detectors operate. This technique allows for discontinuous wavelength tuning by temperature-jumping a laser diode from one range to another within a time span suitable for photoacoustic calibration. The use of an internal calibration eliminates the need for external calibrated reference gases. Commercial applications include an improvement of photoacoustic spectrometers in all fields of use.

Optical bio-sniffer for methyl mercaptan in halitosis.

PubMed

Mitsubayashi, Kohji; Minamide, Takeshi; Otsuka, Kimio; Kudo, Hiroyuki; Saito, Hirokazu

2006-07-28

An optical bio-sniffer for methyl mercaptan (MM) one of major odorous chemicals in halitosis (bad breath) was constructed by immobilizing monoamine oxidase type A (MAO-A) onto a tip of a fiber optic oxygen sensor (od: 1.59 mm) with an oxygen sensitive ruthenium organic complex (excitation: 470 nm, fluorescent: 600 nm). A flow cell for circulating buffer solution was applied to rinse and clean the tip of the device like nasal mucosa. In order to amplify the bio-sniffer output, a substrate regeneration cycle caused by coupling MAO-A with l-ascorbic acid (AsA) as reducing reaction with reagent system was applied to the sensor system. After evaluating the sensor characteristics using a gas flow measurement system with a gas generator, the optical bio-sniffer was applied to expired gases from healthy male volunteers for halitosis analysis as a physiological application. The optical bio-sniffer was applied to detect the oxygen consumption induced by MAO-A enzymatic reaction (and AsA chemical reduction) with gaseous MM application. The bio-sniffer was calibrated against MM vapor from 8.7 to 11500 ppb with correlation coefficient of 0.977, including a MM threshold (200 ppb) of pathologic halitosis and the human sense of smell level 3.5 (10.0 ppb), with good gas-selectivity based on the MAO-A substrate specificity. As the result of the physiological application, the optical bio-sniffer could successfully monitor the MM level change in breath samples during daytime, which is consistent with the previously reported results.

Experimental calibration and validation of sewer/surface flow exchange equations in steady and unsteady flow conditions

NASA Astrophysics Data System (ADS)

Rubinato, Matteo; Martins, Ricardo; Kesserwani, Georges; Leandro, Jorge; Djordjević, Slobodan; Shucksmith, James

2017-09-01

The linkage between sewer pipe flow and floodplain flow is recognised to induce an important source of uncertainty within two-dimensional (2D) urban flood models. This uncertainty is often attributed to the use of empirical hydraulic formulae (the one-dimensional (1D) weir and orifice steady flow equations) to achieve data-connectivity at the linking interface, which require the determination of discharge coefficients. Because of the paucity of high resolution localised data for this type of flows, the current understanding and quantification of a suitable range for those discharge coefficients is somewhat lacking. To fulfil this gap, this work presents the results acquired from an instrumented physical model designed to study the interaction between a pipe network flow and a floodplain flow. The full range of sewer-to-surface and surface-to-sewer flow conditions at the exchange zone are experimentally analysed in both steady and unsteady flow regimes. Steady state measured discharges are first analysed considering the relationship between the energy heads from the sewer flow and the floodplain flow; these results show that existing weir and orifice formulae are valid for describing the flow exchange for the present physical model, and yield new calibrated discharge coefficients for each of the flow conditions. The measured exchange discharges are also integrated (as a source term) within a 2D numerical flood model (a finite volume solver to the 2D Shallow Water Equations (SWE)), which is shown to reproduce the observed coefficients. This calibrated numerical model is then used to simulate a series of unsteady flow tests reproduced within the experimental facility. Results show that the numerical model overestimated the values of mean surcharge flow rate. This suggests the occurrence of additional head losses in unsteady conditions which are not currently accounted for within flood models calibrated in steady flow conditions.

Groundwater flow and transport modeling

USGS Publications Warehouse

Konikow, Leonard F.; Mercer, J.W.

1988-01-01

Deterministic, distributed-parameter, numerical simulation models for analyzing groundwater flow and transport problems have come to be used almost routinely during the past decade. A review of the theoretical basis and practical use of groundwater flow and solute transport models is used to illustrate the state-of-the-art. Because of errors and uncertainty in defining model parameters, models must be calibrated to obtain a best estimate of the parameters. For flow modeling, data generally are sufficient to allow calibration. For solute-transport modeling, lack of data not only limits calibration, but also causes uncertainty in process description. Where data are available, model reliability should be assessed on the basis of sensitivity tests and measures of goodness-of-fit. Some of these concepts are demonstrated by using two case histories. ?? 1988.

Small Scale Mass Flow Plug Calibration

NASA Technical Reports Server (NTRS)

Sasson, Jonathan

2015-01-01

A simple control volume model has been developed to calculate the discharge coefficient through a mass flow plug (MFP) and validated with a calibration experiment. The maximum error of the model in the operating region of the MFP is 0.54%. The model uses the MFP geometry and operating pressure and temperature to couple continuity, momentum, energy, an equation of state, and wall shear. Effects of boundary layer growth and the reduction in cross-sectional flow area are calculated using an in- integral method. A CFD calibration is shown to be of lower accuracy with a maximum error of 1.35%, and slower by a factor of 100. Effects of total pressure distortion are taken into account in the experiment. Distortion creates a loss in flow rate and can be characterized by two different distortion descriptors.

A process-oriented hydro-biogeochemical model enabling simulation of gaseous carbon and nitrogen emissions and hydrologic nitrogen losses from a subtropical catchment.

PubMed

Zhang, Wei; Li, Yong; Zhu, Bo; Zheng, Xunhua; Liu, Chunyan; Tang, Jialiang; Su, Fang; Zhang, Chong; Ju, Xiaotang; Deng, Jia

2018-03-01

Quantification of nitrogen losses and net greenhouse gas (GHG) emissions from catchments is essential for evaluating the sustainability of ecosystems. However, the hydrologic processes without lateral flows hinder the application of biogeochemical models to this challenging task. To solve this issue, we developed a coupled hydrological and biogeochemical model, Catchment Nutrients Management Model - DeNitrification-DeComposition Model (CNMM-DNDC), to include both vertical and lateral mass flows. By incorporating the core biogeochemical processes (including decomposition, nitrification, denitrification and fermentation) of the DNDC into the spatially distributed hydrologic framework of the CNMM, the simulation of lateral water flows and their influences on nitrogen transportation can be realized. The CNMM-DNDC was then calibrated and validated in a small subtropical catchment belonged to Yanting station with comprehensive field observations. Except for the calibration of water flows (surface runoff and leaching water) in 2005, stream discharges of water and nitrate in 2007, the model validations of soil temperature, soil moisture, crop yield, water flows in 2006 and associated nitrate loss, fluxes of methane, ammonia, nitric oxide and nitrous oxide, and stream discharges of water and nitrate in 2008 were statistically in good agreement with the observations. Meanwhile, our initial simulation of the catchment showed scientific predictions. For instance, it revealed the following: (i) dominant ammonia volatilization among the losses of nitrogenous gases (accounting for 11-21% of the applied annual fertilizer nitrogen in croplands); (ii) hotspots of nitrate leaching near the main stream; and (iii) a net GHG sink function of the catchment. These results implicate the model's promising capability of predicting ecosystem productivity, hydrologic nitrogen loads, losses of gaseous nitrogen and emissions of GHGs, which could be used to provide strategies for establishing sustainable catchments. In addition, the model's capability would be further proved by applying in other catchments with different backgrounds. Copyright © 2017. Published by Elsevier B.V.

Testing a thermo-chemo-hydro-geomechanical model for gas hydrate-bearing sediments using triaxial compression laboratory experiments

NASA Astrophysics Data System (ADS)

Gupta, S.; Deusner, C.; Haeckel, M.; Helmig, R.; Wohlmuth, B.

2017-09-01

Natural gas hydrates are considered a potential resource for gas production on industrial scales. Gas hydrates contribute to the strength and stiffness of the hydrate-bearing sediments. During gas production, the geomechanical stability of the sediment is compromised. Due to the potential geotechnical risks and process management issues, the mechanical behavior of the gas hydrate-bearing sediments needs to be carefully considered. In this study, we describe a coupling concept that simplifies the mathematical description of the complex interactions occurring during gas production by isolating the effects of sediment deformation and hydrate phase changes. Central to this coupling concept is the assumption that the soil grains form the load-bearing solid skeleton, while the gas hydrate enhances the mechanical properties of this skeleton. We focus on testing this coupling concept in capturing the overall impact of geomechanics on gas production behavior though numerical simulation of a high-pressure isotropic compression experiment combined with methane hydrate formation and dissociation. We consider a linear-elastic stress-strain relationship because it is uniquely defined and easy to calibrate. Since, in reality, the geomechanical response of the hydrate-bearing sediment is typically inelastic and is characterized by a significant shear-volumetric coupling, we control the experiment very carefully in order to keep the sample deformations small and well within the assumptions of poroelasticity. The closely coordinated experimental and numerical procedures enable us to validate the proposed simplified geomechanics-to-flow coupling, and set an important precursor toward enhancing our coupled hydro-geomechanical hydrate reservoir simulator with more suitable elastoplastic constitutive models.

40 CFR 86.126-90 - Calibration of other equipment.

Code of Federal Regulations, 2010 CFR

2010-07-01

... according to good practice. Specific equipment requiring calibration are the gas chromatograph and flame ionization detector used in measuring methanol and the high pressure liquid chromatograph (HPLC) and...

40 CFR 86.526-90 - Calibration of other equipment.

Code of Federal Regulations, 2010 CFR

2010-07-01

... necessary according to good practice. Specific equipment requiring calibration is the gas chromatograph and flame ionization detector used in measuring methanol and the high pressure liquid chromatograph (HPLC...

40 CFR 86.126-90 - Calibration of other equipment.

Code of Federal Regulations, 2011 CFR

2011-07-01

... according to good practice. Specific equipment requiring calibration are the gas chromatograph and flame ionization detector used in measuring methanol and the high pressure liquid chromatograph (HPLC) and...

40 CFR 86.526-90 - Calibration of other equipment.

Code of Federal Regulations, 2011 CFR

2011-07-01

... necessary according to good practice. Specific equipment requiring calibration is the gas chromatograph and flame ionization detector used in measuring methanol and the high pressure liquid chromatograph (HPLC...

Comparison of continuous in-situ CO2 observations at Jungfraujoch using two different measurement techniques

NASA Astrophysics Data System (ADS)

Schibig, M. F.; Steinbacher, M.; Buchmann, B.; van der Laan-Luijkx, I. T.; van der Laan, S.; Ranjan, S.; Leuenberger, M. C.

2014-07-01

Since 2004, atmospheric carbon dioxide (CO2) is measured at the High Altitude Research Station Jungfraujoch by the division of Climate and Environmental Physics at the University of Bern (KUP) using a nondispersive infrared gas analyzer (NDIR) in combination with a paramagnetic O2 analyzer. In January 2010, CO2 measurements based on cavity ring down spectroscopy (CRDS) as part of the Swiss National Air Pollution Monitoring Network have been added by the Swiss Federal Laboratories for Materials Science and Technology (Empa). To ensure a smooth transition - a prerequisite when merging two datasets e.g. for trend determinations - the two measurement systems run in parallel for several years. Such a long-term intercomparison also allows identifying potential offsets between the two datasets and getting information about the compatibility of the two systems on different time scales. A good agreement of the seasonality as well as for the short-term variations was observed and to a lesser extent for trend calculations mainly due to the short common period. However, the comparison revealed some issues related to the stability of the calibration gases of the KUP system and their assigned CO2 mole fraction. It was possible to adapt an improved calibration strategy based on standard gas determinations, which lead to better agreement between the two data sets. By excluding periods with technical problems and bad calibration gas cylinders, the average hourly difference (CRDS - NDIR) of the two systems is -0.03 ppm ± 0.25 ppm. Although the difference of the two datasets is in line with the compatibility goal of ±0.1 ppm of the World Meteorological Organization (WMO), the standard deviation is still too high. A significant part of this uncertainty originates from the necessity to switch the KUP system frequently (every 12 min) for 6 min from ambient air to a working gas in order to correct short-term variations of the O2 measurement system. Allowing additionally for signal stabilization after switching the sample, an effective data coverage of only 1/6 for the KUP system is achieved while the Empa system has a nearly complete data coverage. Additionally, different internal volumes and flow rates between the two systems may affect observed differences.

Comparison of continuous in situ CO2 observations at Jungfraujoch using two different measurement techniques

NASA Astrophysics Data System (ADS)

Schibig, M. F.; Steinbacher, M.; Buchmann, B.; van der Laan-Luijkx, I. T.; van der Laan, S.; Ranjan, S.; Leuenberger, M. C.

2015-01-01

Since 2004, atmospheric carbon dioxide (CO2) is being measured at the High Altitude Research Station Jungfraujoch by the division of Climate and Environmental Physics at the University of Bern (KUP) using a nondispersive infrared gas analyzer (NDIR) in combination with a paramagnetic O2 analyzer. In January 2010, CO2 measurements based on cavity ring-down spectroscopy (CRDS) as part of the Swiss National Air Pollution Monitoring Network were added by the Swiss Federal Laboratories for Materials Science and Technology (Empa). To ensure a smooth transition - a prerequisite when merging two data sets, e.g., for trend determinations - the two measurement systems run in parallel for several years. Such a long-term intercomparison also allows the identification of potential offsets between the two data sets and the collection of information about the compatibility of the two systems on different time scales. A good agreement of the seasonality, short-term variations and, to a lesser extent mainly due to the short common period, trend calculations is observed. However, the comparison reveals some issues related to the stability of the calibration gases of the KUP system and their assigned CO2 mole fraction. It is possible to adapt an improved calibration strategy based on standard gas determinations, which leads to better agreement between the two data sets. By excluding periods with technical problems and bad calibration gas cylinders, the average hourly difference (CRDS - NDIR) of the two systems is -0.03 ppm ± 0.25 ppm. Although the difference of the two data sets is in line with the compatibility goal of ±0.1 ppm of the World Meteorological Organization (WMO), the standard deviation is still too high. A significant part of this uncertainty originates from the necessity to switch the KUP system frequently (every 12 min) for 6 min from ambient air to a working gas in order to correct short-term variations of the O2 measurement system. Allowing additional time for signal stabilization after switching the sample, an effective data coverage of only one-sixth for the KUP system is achieved while the Empa system has a nearly complete data coverage. Additionally, different internal volumes and flow rates may affect observed differences.

40 CFR Appendix I to Part 94 - Emission-Related Engine Parameters and Specifications

Code of Federal Regulations, 2012 CFR

2012-07-01

.... Temperature control system calibration. 4. Maximum allowable inlet air restriction. III. Fuel System. 1. General. a. Engine idle speed. 2. Fuel injection—compression ignition engines. a. Control parameters and calibrations. b. Transient enrichment system calibration. c. Air-fuel flow calibration. d. Altitude...

40 CFR Appendix I to Part 94 - Emission-Related Engine Parameters and Specifications

Code of Federal Regulations, 2011 CFR

2011-07-01

.... Temperature control system calibration. 4. Maximum allowable inlet air restriction. III. Fuel System. 1. General. a. Engine idle speed. 2. Fuel injection—compression ignition engines. a. Control parameters and calibrations. b. Transient enrichment system calibration. c. Air-fuel flow calibration. d. Altitude...

40 CFR Appendix I to Part 94 - Emission-Related Engine Parameters and Specifications

Code of Federal Regulations, 2014 CFR

2014-07-01

.... Temperature control system calibration. 4. Maximum allowable inlet air restriction. III. Fuel System. 1. General. a. Engine idle speed. 2. Fuel injection—compression ignition engines. a. Control parameters and calibrations. b. Transient enrichment system calibration. c. Air-fuel flow calibration. d. Altitude...

40 CFR Appendix I to Part 94 - Emission-Related Engine Parameters and Specifications

Code of Federal Regulations, 2013 CFR

2013-07-01

.... Temperature control system calibration. 4. Maximum allowable inlet air restriction. III. Fuel System. 1. General. a. Engine idle speed. 2. Fuel injection—compression ignition engines. a. Control parameters and calibrations. b. Transient enrichment system calibration. c. Air-fuel flow calibration. d. Altitude...

Gas flow meter and method for measuring gas flow rate

DOEpatents

Robertson, Eric P.

2006-08-01

A gas flow rate meter includes an upstream line and two chambers having substantially equal, fixed volumes. An adjustable valve may direct the gas flow through the upstream line to either of the two chambers. A pressure monitoring device may be configured to prompt valve adjustments, directing the gas flow to an alternate chamber each time a pre-set pressure in the upstream line is reached. A method of measuring the gas flow rate measures the time required for the pressure in the upstream line to reach the pre-set pressure. The volume of the chamber and upstream line are known and fixed, thus the time required for the increase in pressure may be used to determine the flow rate of the gas. Another method of measuring the gas flow rate uses two pressure measurements of a fixed volume, taken at different times, to determine the flow rate of the gas.

Using passive capillary lysimeter water flux measurements to improve flow predictions in variably saturated soils.

USDA-ARS?s Scientific Manuscript database

Passive capillary lysimeters (PCLs) are uniquely suited for measuring water fluxes in variably-saturated soils. The objective of this work was to compare PCL flux measurements with simulated fluxes obtained with a calibrated unsaturated flow model. The Richards equation-based model was calibrated us...

Calibration, Data Acquisition, and Post Analysis of Turbulent Fluid Flow in a Calibration Jet Using Hot-wire Anemometry

NASA Technical Reports Server (NTRS)

Moreno, Michelle

2004-01-01

The Turbine Branch concentrates on the following areas: Computational Fluid Dynamics (CFD), and implementing experimental procedures to obtain physical modeling data. Hot-wire Anemometry is a valuable tool for obtaining physical modeling data. Hot-wire Anemometry is likely to remain the principal research tool for most turbulent air/gas flow studies. The Hot-wire anemometer consists of a fine wire heated by electric current. When placed in a fluid stream, the hot-wire loses heat to the fluid by forced convection. In forced convection, energy transfer is due to molecular motion imposed by an extraneous force moving fluid parcels. When the hot-wire is in "equilibrium", the rate of heat input to the wire is equal to the rate of heat loss at the wire ends. The equality between heat input and heat loss is the basis for King s equation, which relates the electrical parameters of the hot-wire to the flow parameters of the fluid. Hot-wire anemometry is based on convective heat transfer from a heated wire element placed in a fluid flow. Any change in the fluid flow condition that affects the heat transfer from the heated element will be detected virtually instantaneously by a constant-temperature Hot-wire anemometry system. The system implemented for this research is the IFA 300. The system is a fully-integrated, thermal anemometer-based system that measures mean and fluctuating velocity components in air, water, and other fluids. It also measures turbulence and makes localized temperature measurements. A constant-temperature anemometer is a bridge and amplifier circuit that controls a tiny wire at constant temperature. As a fluid flow passes over the heated sensor, the amplifier senses the bridge off-balance and adjusts the voltage to the top of the bridge, keeping the bridge in balance. The voltage on top of the bridge can then be related to the velocity of the flow. The bridge voltage is sensitive to temperature as well as velocity and so the built-in thermocouple circuit can be attached to a thermocouple that can measure the fluid temperature. Additional information is included in the original extended abstract.

New technique for calibrating hydrocarbon gas flowmeters

NASA Technical Reports Server (NTRS)

Singh, J. J.; Puster, R. L.

1984-01-01

A technique for measuring calibration correction factors for hydrocarbon mass flowmeters is described. It is based on the Nernst theorem for matching the partial pressure of oxygen in the combustion products of the test hydrocarbon, burned in oxygen-enriched air, with that in normal air. It is applied to a widely used type of commercial thermal mass flowmeter for a number of hydrocarbons. The calibration correction factors measured using this technique are in good agreement with the values obtained by other independent procedures. The technique is successfully applied to the measurement of differences as low as one percent of the effective hydrocarbon content of the natural gas test samples.

Hydrogen peroxide vapor cross sections: A flow cell study using laser absorption in the near infrared

NASA Astrophysics Data System (ADS)

Rhodes, B. L.; Ronney, P. D.; DeSain, J. D.

2018-01-01

The absorption spectra of vapors of concentrated hydrogen peroxide/water mixtures (without a carrier gas) were characterized at wavelengths from 1390 to 1470 nm utilizing a near-infrared diode laser. Low pressures were employed to examine these spectral features near the Doppler-broadened limit. An advantageous portion of the spectra near 1420 nm containing several distinct H2O2 peaks and one well-known H2O peak (for calibration) was identified and the cross-sections of these peaks determined. These cross section values can be employed to measure vapor-phase concentrations of H2O2 in propulsion, atmospheric chemistry, and sterilization applications.

Approach for Self-Calibrating CO2 Measurements with Linear Membrane-Based Gas Sensors

PubMed Central

Lazik, Detlef; Sood, Pramit

2016-01-01

Linear membrane-based gas sensors that can be advantageously applied for the measurement of a single gas component in large heterogeneous systems, e.g., for representative determination of CO2 in the subsurface, can be designed depending on the properties of the observation object. A resulting disadvantage is that the permeation-based sensor response depends on operating conditions, the individual site-adapted sensor geometry, the membrane material, and the target gas component. Therefore, calibration is needed, especially of the slope, which could change over several orders of magnitude. A calibration-free approach based on an internal gas standard is developed to overcome the multi-criterial slope dependency. This results in a normalization of sensor response and enables the sensor to assess the significance of measurement. The approach was proofed on the example of CO2 analysis in dry air with tubular PDMS membranes for various CO2 concentrations of an internal standard. Negligible temperature dependency was found within an 18 K range. The transformation behavior of the measurement signal and the influence of concentration variations of the internal standard on the measurement signal were shown. Offsets that were adjusted based on the stated theory for the given measurement conditions and material data from the literature were in agreement with the experimentally determined offsets. A measurement comparison with an NDIR reference sensor shows an unexpectedly low bias (<1%) of the non-calibrated sensor response, and comparable statistical uncertainty. PMID:27869656

40 CFR 600.110-08 - Equipment calibration.

Code of Federal Regulations, 2013 CFR

2013-07-01

... FUEL ECONOMY AND GREENHOUSE GAS EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy and Carbon-Related Exhaust Emission Test Procedures § 600.110-08 Equipment calibration. The equipment used for fuel economy...

40 CFR 600.110-08 - Equipment calibration.

Code of Federal Regulations, 2012 CFR

2012-07-01

... FUEL ECONOMY AND GREENHOUSE GAS EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy and Carbon-Related Exhaust Emission Test Procedures § 600.110-08 Equipment calibration. The equipment used for fuel economy...

Method and system for gas flow mitigation of molecular contamination of optics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delgado, Gildardo; Johnson, Terry; Arienti, Marco

A computer-implemented method for determining an optimized purge gas flow in a semi-conductor inspection metrology or lithography apparatus, comprising receiving a permissible contaminant mole fraction, a contaminant outgassing flow rate associated with a contaminant, a contaminant mass diffusivity, an outgassing surface length, a pressure, a temperature, a channel height, and a molecular weight of a purge gas, calculating a flow factor based on the permissible contaminant mole fraction, the contaminant outgassing flow rate, the channel height, and the outgassing surface length, comparing the flow factor to a predefined maximum flow factor value, calculating a minimum purge gas velocity and amore » purge gas mass flow rate from the flow factor, the contaminant mass diffusivity, the pressure, the temperature, and the molecular weight of the purge gas, and introducing the purge gas into the semi-conductor inspection metrology or lithography apparatus with the minimum purge gas velocity and the purge gas flow rate.« less

40 CFR 86.1519 - CVS calibration.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Light-Duty Trucks; Idle Test Procedures...

Calibrating/testing meters in hot water test bench VM7

NASA Astrophysics Data System (ADS)

Kling, E.; Stolt, K.; Lau, P.; Mattiasson, K.

A Hot Water Test Bench, VM7, has been developed and constructed for the calibration and testing of volume and flowmeters, in a project at the National Volume Measurement Laboratory at the Swedish National Testing and Research Institute. The intended area of use includes use as a reference at audit measurements, e.g. for accredited laboratories, calibration of meters for the industry and for the testing of hot water meters. The objective of the project, which was initiated in 1989, was to design equipment with stable flow and with a minimal temperature drop even at very low flow rates. The principle of the design is a closed system with two pressure tanks at different pressures. The water is led from the high pressure tank through the test object and the volume standard, in the form of master meters or a piston prover alternatively, to the low pressure tank. Calibrations/tests are made comparing the indication of the test object to that of master meters covering the current flow rate. These are, in the same test cycle, calibrated to the piston prover. Alternatively, the test object can be calibrated directly to the piston prover.

Comparison of infusion pumps calibration methods

NASA Astrophysics Data System (ADS)

Batista, Elsa; Godinho, Isabel; do Céu Ferreira, Maria; Furtado, Andreia; Lucas, Peter; Silva, Claudia

2017-12-01

Nowadays, several types of infusion pump are commonly used for drug delivery, such as syringe pumps and peristaltic pumps. These instruments present different measuring features and capacities according to their use and therapeutic application. In order to ensure the metrological traceability of these flow and volume measuring equipment, it is necessary to use suitable calibration methods and standards. Two different calibration methods can be used to determine the flow error of infusion pumps. One is the gravimetric method, considered as a primary method, commonly used by National Metrology Institutes. The other calibration method, a secondary method, relies on an infusion device analyser (IDA) and is typically used by hospital maintenance offices. The suitability of the IDA calibration method was assessed by testing several infusion instruments at different flow rates using the gravimetric method. In addition, a measurement comparison between Portuguese Accredited Laboratories and hospital maintenance offices was performed under the coordination of the Portuguese Institute for Quality, the National Metrology Institute. The obtained results were directly related to the used calibration method and are presented in this paper. This work has been developed in the framework of the EURAMET projects EMRP MeDD and EMPIR 15SIP03.

Model simulations of flood and debris flow timing in steep catchments after wildfire

NASA Astrophysics Data System (ADS)

Rengers, F. K.; McGuire, L. A.; Kean, J. W.; Staley, D. M.; Hobley, D. E. J.

2016-08-01

Debris flows are a typical hazard on steep slopes after wildfire, but unlike debris flows that mobilize from landslides, most postwildfire debris flows are generated from water runoff. The majority of existing debris flow modeling has focused on landslide-triggered debris flows. In this study we explore the potential for using process-based rainfall-runoff models to simulate the timing of water flow and runoff-generated debris flows in recently burned areas. Two different spatially distributed hydrologic models with differing levels of complexity were used: the full shallow water equations and the kinematic wave approximation. Model parameter values were calibrated in two different watersheds, spanning two orders of magnitude in drainage area. These watersheds were affected by the 2009 Station Fire in the San Gabriel Mountains, CA, USA. Input data for the numerical models were constrained by time series of soil moisture, flow stage, and rainfall collected at field sites, as well as high-resolution lidar-derived digital elevation models. The calibrated parameters were used to model a third watershed in the burn area, and the results show a good match with observed timing of flow peaks. The calibrated roughness parameter (Manning's n) was generally higher when using the kinematic wave approximation relative to the shallow water equations, and decreased with increasing spatial scale. The calibrated effective watershed hydraulic conductivity was low for both models, even for storms occurring several months after the fire, suggesting that wildfire-induced changes to soil-water infiltration were retained throughout that time. Overall, the two model simulations were quite similar suggesting that a kinematic wave model, which is simpler and more computationally efficient, is a suitable approach for predicting flood and debris flow timing in steep, burned watersheds.

Model simulations of flood and debris flow timing in steep catchments after wildfire

USGS Publications Warehouse

Rengers, Francis K.; McGuire, Luke; Kean, Jason W.; Staley, Dennis M.; Hobley, D.E.J

2016-01-01

Debris flows are a typical hazard on steep slopes after wildfire, but unlike debris flows that mobilize from landslides, most post-wildfire debris flows are generated from water runoff. The majority of existing debris-flow modeling has focused on landslide-triggered debris flows. In this study we explore the potential for using process-based rainfall-runoff models to simulate the timing of water flow and runoff-generated debris flows in recently burned areas. Two different spatially distributed hydrologic models with differing levels of complexity were used: the full shallow water equations and the kinematic wave approximation. Model parameter values were calibrated in two different watersheds, spanning two orders of magnitude in drainage area. These watersheds were affected by the 2009 Station Fire in the San Gabriel Mountains, CA, USA. Input data for the numerical models were constrained by time series of soil moisture, flow stage, and rainfall collected at field sites, as well as high-resolution lidar-derived digital elevation models. The calibrated parameters were used to model a third watershed in the burn area, and the results show a good match with observed timing of flow peaks. The calibrated roughness parameter (Manning's $n$) was generally higher when using the kinematic wave approximation relative to the shallow water equations, and decreased with increasing spatial scale. The calibrated effective watershed hydraulic conductivity was low for both models, even for storms occurring several months after the fire, suggesting that wildfire-induced changes to soil-water infiltration were retained throughout that time. Overall the two model simulations were quite similar suggesting that a kinematic wave model, which is simpler and more computationally efficient, is a suitable approach for predicting flood and debris flow timing in steep, burned watersheds.

Simple laser vision sensor calibration for surface profiling applications

NASA Astrophysics Data System (ADS)

Abu-Nabah, Bassam A.; ElSoussi, Adnane O.; Al Alami, Abed ElRahman K.

2016-09-01

Due to the relatively large structures in the Oil and Gas industry, original equipment manufacturers (OEMs) have been implementing custom-designed laser vision sensor (LVS) surface profiling systems as part of quality control in their manufacturing processes. The rough manufacturing environment and the continuous movement and misalignment of these custom-designed tools adversely affect the accuracy of laser-based vision surface profiling applications. Accordingly, Oil and Gas businesses have been raising the demand from the OEMs to implement practical and robust LVS calibration techniques prior to running any visual inspections. This effort introduces an LVS calibration technique representing a simplified version of two known calibration techniques, which are commonly implemented to obtain a calibrated LVS system for surface profiling applications. Both calibration techniques are implemented virtually and experimentally to scan simulated and three-dimensional (3D) printed features of known profiles, respectively. Scanned data is transformed from the camera frame to points in the world coordinate system and compared with the input profiles to validate the introduced calibration technique capability against the more complex approach and preliminarily assess the measurement technique for weld profiling applications. Moreover, the sensitivity to stand-off distances is analyzed to illustrate the practicality of the presented technique.

Technical basis for the reduction of the maximum temperature TGA-MS analysis of oxide samples from the 3013 destructive examination program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scogin, J. H.

2016-03-24

Thermogravimetric analysis with mass spectroscopy of the evolved gas (TGA-MS) is used to quantify the moisture content of materials in the 3013 destructive examination (3013 DE) surveillance program. Salts frequently present in the 3013 DE materials volatilize in the TGA and condense in the gas lines just outside the TGA furnace. The buildup of condensate can restrict the flow of purge gas and affect both the TGA operations and the mass spectrometer calibration. Removal of the condensed salts requires frequent maintenance and subsequent calibration runs to keep the moisture measurements by mass spectroscopy within acceptable limits, creating delays in processingmore » samples. In this report, the feasibility of determining the total moisture from TGA-MS measurements at a lower temperature is investigated. A temperature of the TGA-MS analysis which reduces the complications caused by the condensation of volatile materials is determined. Analysis shows that an excellent prediction of the presently measured total moisture value can be made using only the data generated up to 700 °C and there is a sound physical basis for this estimate. It is recommended that the maximum temperature of the TGA-MS determination of total moisture for the 3013 DE program be reduced from 1000 °C to 700 °C. It is also suggested that cumulative moisture measurements at 550 °C and 700°C be substituted for the measured value of total moisture in the 3013 DE database. Using these raw values, any of predictions of the total moisture discussed in this report can be made.« less

Support of gas flowmeter upgrade

NASA Technical Reports Server (NTRS)

Waugaman, Dennis

1996-01-01

A project history review, literature review, and vendor search were conducted to identify a flowmeter that would improve the accuracy of gaseous flow measurements in the White Sands Test Facility (WSTF) Calibration Laboratory and the Hydrogen High Flow Facility. Both facilities currently use sonic flow nozzles to measure flowrates. The flow nozzle pressure drops combined with corresponding pressure and temperature measurements have been estimated to produce uncertainties in flowrate measurements of 2 to 5 percent. This study investigated the state of flowmeter technology to make recommendations that would reduce those uncertainties. Most flowmeters measure velocity and volume, therefore mass flow measurement must be calculated based on additional pressures and temperature measurement which contribute to the error. The two exceptions are thermal dispersion meters and Coriolis mass flowmeters. The thermal dispersion meters are accurate to 1 to 5 percent. The Coriolis meters are significantly more accurate, at least for liquids. For gases, there is evidence they may be accurate to within 0.5 percent or better of the flowrate, but there may be limitations due to inappropriate velocity, pressure, Mach number and vibration disturbances. In this report, a comparison of flowmeters is presented. Candidate Coriolis meters and a methodology to qualify the meter with tests both at WSTF and Southwest Research Institute are recommended and outlined.

Development of a mobile and high-precision atmospheric CO2 monitoring station

NASA Astrophysics Data System (ADS)

Molnár, M.; Haszpra, L.; Major, I.; Svingor, É.; Veres, M.

2009-04-01

Nowadays one of the most burning questions for the science is the rate and the reasons of the recent climate change. Greenhouse gases (GHG), mainly CO2 and CH4 in the atmosphere could affect the climate of our planet. However, the relation between the amount of atmospheric GHG and the climate is complex, full with interactions and feedbacks partly poorly known even by now. The only way to understand the processes, to trace the changes, to develop and validate mathematical models for forecasts is the extensive, high precision, continuous monitoring of the atmosphere. Fossil fuel CO2 emissions are a major component of the European carbon budget. Separation of the fossil fuel signal from the natural biogenic one in the atmosphere is, therefore, a crucial task for quantifying exchange flux of the continental biosphere through atmospheric observations and inverse modelling. An independent method to estimate trace gas emissions is the top-down approach, using atmospheric CO2 concentration measurements combined with simultaneous radiocarbon (14C) observations. As adding fossil fuel CO2 to the atmosphere, therefore, leads not only to an increase in the CO2 content of the atmosphere but also to a decrease in the 14C/12C ratio in atmospheric CO2. The ATOMKI has more than two decade long experience in atmospheric 14CO2 monitoring. As a part of an ongoing research project being carried out in Hungary to investigate the amount and temporal and spatial variations of fossil fuel CO2 in the near surface atmosphere we developed a mobile and high-precision atmospheric CO2 monitoring station. We describe the layout and the operation of the measuring system which is designed for the continuous, unattended monitoring of CO2 mixing ratio in the near surface atmosphere based on an Ultramat 6F (Siemens) infrared gas analyser. In the station one atmospheric 14CO2 sampling unit is also installed which is developed and widely used since more than one decade by ATOMKI. Mixing ratio of CO2 is measured at 2 m above the ground by the monitoring station. Air is pumped through a 9.5-mm-diameter plastic tube (PFA, Swagelok) to a CO2 analyser located in a container box. Container box (Containex) is 1.5 m wide, 1.2 m deep and 2.2 m high, designed as a mobile measuring room which is field deployable, only electric power is required. A 15 micron pore size stainless steel Tee-Type (Swagelok) particle filter is located at the inlet of the sampler tube. Diaphragm pump (KNF) is used to draw air continuously through the sampling tube from monitoring level at flow rate of ~ 2 L/min. After leaving the pump, the air at 5 psig overpressure enters a glass trap for liquid water that is cooled in a regular household refrigerator, to dry the air to a dew point of 3°-4°C. Liquid water is forced out through an orifice at the bottom of the trap. The air sample inlet tube and the standard gases (Linde Hungary) are connected to miniature solenoid valves (S Series, ASCO Numatics) in a manifold which are normally closed and controlled by the CO2 analyser, which selects which gas is sampled. The air leaving the manifold through its common outlet is further dried to a dew point of about -25°C by passage through a 360-cm-long Nafion drier (Permapure), so that the water vapour interference and dilution effect are <0.1 ppm equivalent CO2. The Nafion drier is purged in a counter flow (300 cm3/min) arrangement using waste sample air that has been further dried by passage through anhydrous CaSO4 (Drierite). Analysis is carried out using an infrared gas analyser Ultramat 6F which is a specialised model for field applications by Siemens. A constant sample flow rate of 300 cm3/min is maintained by a mass flow controller (Aalborg). The reference cell of the CO2 analyzer is continuously flushed with a compressed reference gas of 350 ppm CO2 in synthetic air (Messer Hungarogáz). The basic calibration cycle is 2 hours, consisting of a zero-point calibration and a span calibration. Each calibration is consisting of 2 min flushing and 20 sec signal integration. The usual change of the response function is below 0.2 ppm after 2 hours following a previous calibration. The analyser measures the CO2 mixing ratio in the sample gas in every 3 seconds. Output data are registered by a data logger developed for this application (Special Control Devices). The overall uncertainty of our atmospheric CO2 mixing ratio measurements is < 0.5 ppm (< 0,2 %). This level of error is acceptable for fossil fuel CO2 calculations as the uncertainty of the other required parameter radiocarbon content of atmospheric CO2 is usually 0.3-0.5%. Using the developed mobile and high-precision atmospheric CO2 monitoring station we plan to determine the fossil fuel CO2 amount in the air of different cities and other average industrial regions in Hungary. This research project was supported by Hungarian NSF (Ref No. F69029).

40 CFR 85.2232 - Calibrations, adjustments-EPA 81.

Code of Federal Regulations, 2012 CFR

2012-07-01

... readings using the span gas through the probe and through the calibration port shall be made and compared... through the probe. This paragraph does not prevent those who wish to always adjust the analyzer to the... without a calibration port, perform a simple leak check (e.g., cap the probe). Repair any leaks before...

40 CFR 85.2232 - Calibrations, adjustments-EPA 81.

Code of Federal Regulations, 2011 CFR

2011-07-01

... readings using the span gas through the probe and through the calibration port shall be made and compared... through the probe. This paragraph does not prevent those who wish to always adjust the analyzer to the... without a calibration port, perform a simple leak check (e.g., cap the probe). Repair any leaks before...

40 CFR 85.2232 - Calibrations, adjustments-EPA 81.

Code of Federal Regulations, 2013 CFR

2013-07-01

... readings using the span gas through the probe and through the calibration port shall be made and compared... through the probe. This paragraph does not prevent those who wish to always adjust the analyzer to the... without a calibration port, perform a simple leak check (e.g., cap the probe). Repair any leaks before...

33 CFR 154.2181 - Alternative testing program-Test requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... CE test must check the calibrated range of each analyzer using a lower (zero) and upper (span... instrument, R = reference value of zero or high-level calibration gas introduced into the monitoring system... Difference Zero Span 1-Zero 1-Span 2-Zero 2-Span 3-Zero 3-Span Mean Difference = Calibration Error = % % (3...

Multi-Scale Human Respiratory System Simulations to Study Health Effects of Aging, Disease, and Inhaled Substances

NASA Astrophysics Data System (ADS)

Kunz, Robert; Haworth, Daniel; Dogan, Gulkiz; Kriete, Andres

2006-11-01

Three-dimensional, unsteady simulations of multiphase flow, gas exchange, and particle/aerosol deposition in the human lung are reported. Surface data for human tracheo-bronchial trees are derived from CT scans, and are used to generate three- dimensional CFD meshes for the first several generations of branching. One-dimensional meshes for the remaining generations down to the respiratory units are generated using branching algorithms based on those that have been proposed in the literature, and a zero-dimensional respiratory unit (pulmonary acinus) model is attached at the end of each terminal bronchiole. The process is automated to facilitate rapid model generation. The model is exercised through multiple breathing cycles to compute the spatial and temporal variations in flow, gas exchange, and particle/aerosol deposition. The depth of the 3D/1D transition (at branching generation n) is a key parameter, and can be varied. High-fidelity models (large n) are run on massively parallel distributed-memory clusters, and are used to generate physical insight and to calibrate/validate the 1D and 0D models. Suitably validated lower-order models (small n) can be run on single-processor PC’s with run times that allow model-based clinical intervention for individual patients.

Self-similar dynamic converging shocks - I. An isothermal gas sphere with self-gravity

NASA Astrophysics Data System (ADS)

Lou, Yu-Qing; Shi, Chun-Hui

2014-07-01

We explore novel self-similar dynamic evolution of converging spherical shocks in a self-gravitating isothermal gas under conceivable astrophysical situations. The construction of such converging shocks involves a time-reversal operation on feasible flow profiles in self-similar expansion with a proper care for the increasing direction of the specific entropy. Pioneered by Guderley since 1942 but without self-gravity so far, self-similar converging shocks are important for implosion processes in aerodynamics, combustion, and inertial fusion. Self-gravity necessarily plays a key role for grossly spherical structures in very broad contexts of astrophysics and cosmology, such as planets, stars, molecular clouds (cores), compact objects, planetary nebulae, supernovae, gamma-ray bursts, supernova remnants, globular clusters, galactic bulges, elliptical galaxies, clusters of galaxies as well as relatively hollow cavity or bubble structures on diverse spatial and temporal scales. Large-scale dynamic flows associated with such quasi-spherical systems (including collapses, accretions, fall-backs, winds and outflows, explosions, etc.) in their initiation, formation, and evolution are likely encounter converging spherical shocks at times. Our formalism lays an important theoretical basis for pertinent astrophysical and cosmological applications of various converging shock solutions and for developing and calibrating numerical codes. As examples, we describe converging shock triggered star formation, supernova explosions, and void collapses.

Development and analytical characterization of a Grimm-type glow discharge ion source operated with high gas flow rates and coupled to a mass spectrometer with high mass resolution1

NASA Astrophysics Data System (ADS)

Beyer, Claus; Feldmann, Ingo; Gilmour, Dave; Hoffmann, Volker; Jakubowski, Norbert

2002-10-01

A Grimm-type glow discharge ion source has been developed and was coupled to a commercial inductively coupled plasma mass spectrometer (ICP-MS) with high mass resolution (Axiom, ThermoElemental, Winsford, UK) by exchanging the front plate of the ICP-MS interface system only. In addition to high discharge powers of up to 70 W, which are typical for a Grimm-type design, this source could be operated with relative high gas flow rates of up to 240 ml min -1. In combination with a high discharge voltage the signal intensities are reaching a constant level within the first 20 s after the discharge has started. An analytical characterization of this source is given utilizing a calibration using the steel standard reference material NIST 1261A-1265A. The sensitivity for the investigated elements measured with a resolution of 4000 is in the range of 500-6000 cps μg -1 g -1, and a relative standard deviation (R.S.D.) of the measured isotope relative to Fe of less than 8% for the major and minor components of the sample has been achieved. Limits of detection at ng g -1 levels could be obtained.

Reducing equifinality of hydrological models by integrating Functional Streamflow Disaggregation

NASA Astrophysics Data System (ADS)

Lüdtke, Stefan; Apel, Heiko; Nied, Manuela; Carl, Peter; Merz, Bruno

2014-05-01

A universal problem of the calibration of hydrological models is the equifinality of different parameter sets derived from the calibration of models against total runoff values. This is an intrinsic problem stemming from the quality of the calibration data and the simplified process representation by the model. However, discharge data contains additional information which can be extracted by signal processing methods. An analysis specifically developed for the disaggregation of runoff time series into flow components is the Functional Streamflow Disaggregation (FSD; Carl & Behrendt, 2008). This method is used in the calibration of an implementation of the hydrological model SWIM in a medium sized watershed in Thailand. FSD is applied to disaggregate the discharge time series into three flow components which are interpreted as base flow, inter-flow and surface runoff. In addition to total runoff, the model is calibrated against these three components in a modified GLUE analysis, with the aim to identify structural model deficiencies, assess the internal process representation and to tackle equifinality. We developed a model dependent (MDA) approach calibrating the model runoff components against the FSD components, and a model independent (MIA) approach comparing the FSD of the model results and the FSD of calibration data. The results indicate, that the decomposition provides valuable information for the calibration. Particularly MDA highlights and discards a number of standard GLUE behavioural models underestimating the contribution of soil water to river discharge. Both, MDA and MIA yield to a reduction of the parameter ranges by a factor up to 3 in comparison to standard GLUE. Based on these results, we conclude that the developed calibration approach is able to reduce the equifinality of hydrological model parameterizations. The effect on the uncertainty of the model predictions is strongest by applying MDA and shows only minor reductions for MIA. Besides further validation of FSD, the next steps include an extension of the study to different catchments and other hydrological models with a similar structure.

Reference NO2 calibration system for ground-based intercomparisons during NASA's GTE/CITE 2 mission

NASA Technical Reports Server (NTRS)

Fried, Alan; Nunnermacker, Linda; Cadoff, Barry; Sams, Robert; Yates, Nathan

1990-01-01

An NO2 calibration system, based on a permeation device and a two-stage dynamic dilution system, was designed, constructed, and characterized at the National Bureau of Standards. In this system, calibrant flow entering the second stage was controlled without contacting a metal flow controller, and permeation oven temperature and flow were continuously maintained, even during transport. The system performance and the permeation emission rate were characterized by extensive laboratory tests. This system was capable of accurately delivering known NO2 concentrations in the ppbv and sub-ppbv concentration range with a total uncertainty of approximately 10 percent. The calibration system was placed on board NASA research aircraft at both the Wallops Island and Ames research facilities. There it was employed as the reference standard in NASA's Global Tropospheric Experiment/Chemical Instrumental Test and Evaluation 2 mission in August 1986.

Hydrogen calibration of GD-spectrometer using Zr-1Nb alloy

NASA Astrophysics Data System (ADS)

Mikhaylov, Andrey A.; Priamushko, Tatiana S.; Babikhina, Maria N.; Kudiiarov, Victor N.; Heller, Rene; Laptev, Roman S.; Lider, Andrey M.

2018-02-01

To study the hydrogen distribution in Zr-1Nb alloy (Э110 alloy) GD-OES was applied in this work. Qualitative analysis needs the standard samples with hydrogen. However, the standard samples with high concentrations of hydrogen in the zirconium alloy which would meet the requirements of the shape, size are absent. In this work method of Zr + H calibration samples production was performed at the first time. Automated Complex Gas Reaction Controller was used for samples hydrogenation. To calculate the parameters of post-hydrogenation incubation of the samples in an inert gas atmosphere the diffusion equations were used. Absolute hydrogen concentrations in the samples were determined by melting in the inert gas atmosphere using RHEN602 analyzer (LECO Company). Hydrogen distribution was studied using nuclear reaction analysis (HZDR, Dresden, Germany). RF GD-OES was used for calibration. The depth of the craters was measured with the help of a Hommel-Etamic profilometer by Jenoptik, Germany.

Lineal energy calibration of mini tissue-equivalent gas-proportional counters (TEPC)

NASA Astrophysics Data System (ADS)

Conte, V.; Moro, D.; Grosswendt, B.; Colautti, P.

2013-07-01

Mini TEPCs are cylindrical gas proportional counters of 1 mm or less of sensitive volume diameter. The lineal energy calibration of these tiny counters can be performed with an external gamma-ray source. However, to do that, first a method to get a simple and precise spectral mark has to be found and then the keV/μm value of this mark. A precise method (less than 1% of uncertainty) to identify this markis described here, and the lineal energy value of this mark has been measured for different simulated site sizes by using a 137Cs gamma source and a cylindrical TEPC equipped with a precision internal 244Cm alpha-particle source, and filled with propane-based tissue-equivalent gas mixture. Mini TEPCs can be calibrated in terms of lineal energy, by exposing them to 137Cesium sources, with an overall uncertainty of about 5%.

Propellant-Flow-Actuated Rocket Engine Igniter

NASA Technical Reports Server (NTRS)

Wollen, Mark

2013-01-01

A rocket engine igniter has been created that uses a pneumatically driven hammer that, by specialized geometry, is induced into an oscillatory state that can be used to either repeatedly impact a piezoelectric crystal with sufficient force to generate a spark capable of initiating combustion, or can be used with any other system capable of generating a spark from direct oscillatory motion. This innovation uses the energy of flowing gaseous propellant, which by means of pressure differentials and kinetic motion, causes a hammer object to oscillate. The concept works by mass flows being induced through orifices on both sides of a cylindrical tube with one or more vent paths. As the mass flow enters the chamber, the pressure differential is caused because the hammer object is supplied with flow on one side and the other side is opened with access to the vent path. The object then crosses the vent opening and begins to slow because the pressure differential across the ball reverses due to the geometry in the tube. Eventually, the object stops because of the increasing pressure differential on the object until all of the kinetic energy has been transferred to the gas via compression. This is the point where the object reverses direction because of the pressure differential. This behavior excites a piezoelectric crystal via direct impact from the hammer object. The hammer strikes a piezoelectric crystal, then reverses direction, and the resultant high voltage created from the crystal is transferred via an electrode to a spark gap in the ignition zone, thereby providing a spark to ignite the engine. Magnets, or other retention methods, might be employed to favorably position the hammer object prior to start, but are not necessary to maintain the oscillatory behavior. Various manifestations of the igniter have been developed and tested to improve device efficiency, and some improved designs are capable of operation at gas flow rates of a fraction of a gram per second (0.001 lb/s) and pressure drops on the order of 30 to 50 kilopascal (a few psi). An analytical model has been created and tested in conjunction with a precisely calibrated reference model. The analytical model accurately captures the overall behavior of this innovation. The model is a simple "volume-orifice" concept, with each chamber considered a single temperature and pressure "node" connected to adjacent nodes, or to vent paths through flow control orifices. Mass and energy balances are applied to each node, with gas flow predicted using simple compressible flow equations.

77 FR 68144 - Information Collection Activities: Oil and Gas Production Measurement, Surface Commingling, and...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-15

... records & calibration runs. practices to Record mechanical- verify accuracy displacement prover, of... needed. 1202(f)(2) Copy & submit 16.5 minutes mechanical- displacement prover & tank prover calibration...

Schlieren optical visualization for transient EHD induced flow in a stratified dielectric liquid under gas-phase ac corona discharges

NASA Astrophysics Data System (ADS)

Ohyama, R.; Inoue, K.; Chang, J. S.

2007-01-01

A flow pattern characterization of electrohydrodynamically (EHD) induced flow phenomena of a stratified dielectric fluid situated in an ac corona discharge field is conducted by a Schlieren optical system. A high voltage application to a needle-plate electrode arrangement in gas-phase normally initiates a conductive type EHD gas flow. Although the EHD gas flow motion initiated from the corona discharge electrode has been well known as corona wind, no comprehensive study has been conducted for an EHD fluid flow motion of the stratified dielectric liquid that is exposed to the gas-phase ac corona discharge. The experimentally observed result clearly presents the liquid-phase EHD flow phenomenon induced from the gas-phase EHD flow via an interfacial momentum transfer. The flow phenomenon is also discussed in terms of the gas-phase EHD number under the reduced gas pressure (reduced interfacial momentum transfer) conditions.

A new algorithm for five-hole probe calibration, data reduction, and uncertainty analysis

NASA Technical Reports Server (NTRS)

Reichert, Bruce A.; Wendt, Bruce J.

1994-01-01

A new algorithm for five-hole probe calibration and data reduction using a non-nulling method is developed. The significant features of the algorithm are: (1) two components of the unit vector in the flow direction replace pitch and yaw angles as flow direction variables; and (2) symmetry rules are developed that greatly simplify Taylor's series representations of the calibration data. In data reduction, four pressure coefficients allow total pressure, static pressure, and flow direction to be calculated directly. The new algorithm's simplicity permits an analytical treatment of the propagation of uncertainty in five-hole probe measurement. The objectives of the uncertainty analysis are to quantify uncertainty of five-hole results (e.g., total pressure, static pressure, and flow direction) and determine the dependence of the result uncertainty on the uncertainty of all underlying experimental and calibration measurands. This study outlines a general procedure that other researchers may use to determine five-hole probe result uncertainty and provides guidance to improve measurement technique. The new algorithm is applied to calibrate and reduce data from a rake of five-hole probes. Here, ten individual probes are mounted on a single probe shaft and used simultaneously. Use of this probe is made practical by the simplicity afforded by this algorithm.

40 CFR 63.365 - Test methods and procedures.

Code of Federal Regulations, 2011 CFR

2011-07-01

... for Volatile Alcohols in Water By Direct Aqueous-Injection Gas Chromatography, (incorporated by... be determined by either: (A) Weighing the ethylene oxide gas cylinder(s) used to charge the... mass of gas charged by the weight percent ethylene oxide present in the gas. (B) Installing calibrated...

Gas-Dynamic Methods to Reduce Gas Flow Nonuniformity from the Annular Frames of Gas Turbine Engines

NASA Astrophysics Data System (ADS)

Kolmakova, D.; Popov, G.

2018-01-01

Gas flow nonuniformity is one of the main sources of rotor blade vibrations in the gas turbine engines. Usually, the flow circumferential nonuniformity occurs near the annular frames, located in the flow channel of the engine. This leads to the increased dynamic stresses in blades and consequently to the blade damage. The goal of the research was to find an acceptable method of reducing the level of gas flow nonuniformity. Two different methods were investigated during this research. Thus, this study gives the ideas about methods of improving the flow structure in gas turbine engine. Based on existing conditions (under development or existing engine) it allows the selection of the most suitable method for reducing gas flow nonuniformity.

Simulation of streamflow, evapotranspiration, and groundwater recharge in the Lower Frio River watershed, south Texas, 1961-2008

USGS Publications Warehouse

Lizarraga, Joy S.; Ockerman, Darwin J.

2011-01-01

The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, Fort Worth District; the City of Corpus Christi; the Guadalupe-Blanco River Authority; the San Antonio River Authority; and the San Antonio Water System, configured, calibrated, and tested a watershed model for a study area consisting of about 5,490 mi2 of the Frio River watershed in south Texas. The purpose of the model is to contribute to the understanding of watershed processes and hydrologic conditions in the lower Frio River watershed. The model simulates streamflow, evapotranspiration (ET), and groundwater recharge by using a numerical representation of physical characteristics of the landscape, and meteorological and streamflow data. Additional time-series inputs to the model include wastewater-treatment-plant discharges, surface-water withdrawals, and estimated groundwater inflow from Leona Springs. Model simulations of streamflow, ET, and groundwater recharge were done for various periods of record depending upon available measured data for input and comparison, starting as early as 1961. Because of the large size of the study area, the lower Frio River watershed was divided into 12 subwatersheds; separate Hydrological Simulation Program-FORTRAN models were developed for each subwatershed. Simulation of the overall study area involved running simulations in downstream order. Output from the model was summarized by subwatershed, point locations, reservoir reaches, and the Carrizo-Wilcox aquifer outcrop. Four long-term U.S. Geological Survey streamflow-gaging stations and two short-term streamflow-gaging stations were used for streamflow model calibration and testing with data from 1991-2008. Calibration was based on data from 2000-08, and testing was based on data from 1991-99. Choke Canyon Reservoir stage data from 1992-2008 and monthly evaporation estimates from 1999-2008 also were used for model calibration. Additionally, 2006-08 ET data from a U.S. Geological Survey meteorological station in Medina County were used for calibration. Streamflow and ET calibration were considered good or very good. For the 2000-08 calibration period, total simulated flow volume and the flow volume of the highest 10 percent of simulated daily flows were calibrated to within about 10 percent of measured volumes at six U.S. Geological Survey streamflow-gaging stations. The flow volume of the lowest 50 percent of daily flows was not simulated as accurately but represented a small percent of the total flow volume. The model-fit efficiency for the weekly mean streamflow during the calibration periods ranged from 0.60 to 0.91, and the root mean square error ranged from 16 to 271 percent of the mean flow rate. The simulated total flow volumes during the testing periods at the long-term gaging stations exceeded the measured total flow volumes by approximately 22 to 50 percent at three stations and were within 7 percent of the measured total flow volumes at one station. For the longer 1961-2008 simulation period at the long-term stations, simulated total flow volumes were within about 3 to 18 percent of measured total flow volumes. The calibrations made by using Choke Canyon reservoir volume for 1992-2008, reservoir evaporation for 1999-2008, and ET in Medina County for 2006-08, are considered very good. Model limitations include possible errors related to model conceptualization and parameter variability, lack of data to better quantify certain model inputs, and measurement errors. Uncertainty regarding the degree to which available rainfall data represent actual rainfall is potentially the most serious source of measurement error. A sensitivity analysis was performed for the Upper San Miguel subwatershed model to show the effect of changes to model parameters on the estimated mean recharge, ET, and surface runoff from that part of the Carrizo-Wilcox aquifer outcrop. Simulated recharge was most sensitive to the changes in the lower-zone ET (LZ

Nonintrusive performance measurement of a gas turbine engine in real time

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeSilva, Upul P.; Claussen, Heiko

Performance of a gas turbine engine is monitored by computing a mass flow rate through the engine. Acoustic time-of-flight measurements are taken between acoustic transmitters and receivers in the flow path of the engine. The measurements are processed to determine average speeds of sound and gas flow velocities along those lines-of-sound. A volumetric flow rate in the flow path is computed using the gas flow velocities together with a representation of the flow path geometry. A gas density in the flow path is computed using the speeds of sound and a measured static pressure. The mass flow rate is calculatedmore » from the gas density and the volumetric flow rate.« less

Modeling microelectrode biosensors: free-flow calibration can substantially underestimate tissue concentrations

PubMed Central

Wall, Mark J.

2016-01-01

Microelectrode amperometric biosensors are widely used to measure concentrations of analytes in solution and tissue including acetylcholine, adenosine, glucose, and glutamate. A great deal of experimental and modeling effort has been directed at quantifying the response of the biosensors themselves; however, the influence that the macroscopic tissue environment has on biosensor response has not been subjected to the same level of scrutiny. Here we identify an important issue in the way microelectrode biosensors are calibrated that is likely to have led to underestimations of analyte tissue concentrations. Concentration in tissue is typically determined by comparing the biosensor signal to that measured in free-flow calibration conditions. In a free-flow environment the concentration of the analyte at the outer surface of the biosensor can be considered constant. However, in tissue the analyte reaches the biosensor surface by diffusion through the extracellular space. Because the enzymes in the biosensor break down the analyte, a density gradient is set up resulting in a significantly lower concentration of analyte near the biosensor surface. This effect is compounded by the diminished volume fraction (porosity) and reduction in the diffusion coefficient due to obstructions (tortuosity) in tissue. We demonstrate this effect through modeling and experimentally verify our predictions in diffusive environments. NEW & NOTEWORTHY Microelectrode biosensors are typically calibrated in a free-flow environment where the concentrations at the biosensor surface are constant. However, when in tissue, the analyte reaches the biosensor via diffusion and so analyte breakdown by the biosensor results in a concentration gradient and consequently a lower concentration around the biosensor. This effect means that naive free-flow calibration will underestimate tissue concentration. We develop mathematical models to better quantify the discrepancy between the calibration and tissue environment and experimentally verify our key predictions. PMID:27927788

Modeling microelectrode biosensors: free-flow calibration can substantially underestimate tissue concentrations.

PubMed

Newton, Adam J H; Wall, Mark J; Richardson, Magnus J E

2017-03-01

Microelectrode amperometric biosensors are widely used to measure concentrations of analytes in solution and tissue including acetylcholine, adenosine, glucose, and glutamate. A great deal of experimental and modeling effort has been directed at quantifying the response of the biosensors themselves; however, the influence that the macroscopic tissue environment has on biosensor response has not been subjected to the same level of scrutiny. Here we identify an important issue in the way microelectrode biosensors are calibrated that is likely to have led to underestimations of analyte tissue concentrations. Concentration in tissue is typically determined by comparing the biosensor signal to that measured in free-flow calibration conditions. In a free-flow environment the concentration of the analyte at the outer surface of the biosensor can be considered constant. However, in tissue the analyte reaches the biosensor surface by diffusion through the extracellular space. Because the enzymes in the biosensor break down the analyte, a density gradient is set up resulting in a significantly lower concentration of analyte near the biosensor surface. This effect is compounded by the diminished volume fraction (porosity) and reduction in the diffusion coefficient due to obstructions (tortuosity) in tissue. We demonstrate this effect through modeling and experimentally verify our predictions in diffusive environments. NEW & NOTEWORTHY Microelectrode biosensors are typically calibrated in a free-flow environment where the concentrations at the biosensor surface are constant. However, when in tissue, the analyte reaches the biosensor via diffusion and so analyte breakdown by the biosensor results in a concentration gradient and consequently a lower concentration around the biosensor. This effect means that naive free-flow calibration will underestimate tissue concentration. We develop mathematical models to better quantify the discrepancy between the calibration and tissue environment and experimentally verify our key predictions. Copyright © 2017 the American Physiological Society.

Uncertainly Analysis of Two Types of Humidity Sensors by a Humidity Generator with a Divided-Flow System.

PubMed

Chen, Ling-Hsi; Chen, Chiachung

2018-02-21

Humidity measurement is an important technique for the agricultural, foods, pharmaceuticals, and chemical industries. For the sake of convenience, electrical relative humidity (RH) sensors have been widely used. These sensors need to be calibrated to ensure their accuracy and the uncertainty measurement of these sensors has become a major concern. In this study, a self-made divided-flow generator was established to calibrate two types of electrical humidity sensors. The standard reference humidity was calculated from dew-point temperature and air dry-bulb temperature measured by a chilled mirror monitor. This divided-flow generator could produce consistent result of RH measurement results. The uncertainty of the reference standard increased with the increase of RH values. The combined uncertainty with the adequate calibration equations were ranged from 0.82% to 1.45% RH for resistive humidity sensors and 0.63% to 1.4% for capacitive humidity sensors, respectively. This self-made, divided-flow generator, and calibration method are cheap, time-saving, and easy to be used. Thus, the proposed approach can easily be applied in research laboratories.

Uncertainly Analysis of Two Types of Humidity Sensors by a Humidity Generator with a Divided-Flow System

PubMed Central

Chen, Ling-Hsi

2018-01-01

Humidity measurement is an important technique for the agricultural, foods, pharmaceuticals, and chemical industries. For the sake of convenience, electrical relative humidity (RH) sensors have been widely used. These sensors need to be calibrated to ensure their accuracy and the uncertainty measurement of these sensors has become a major concern. In this study, a self-made divided-flow generator was established to calibrate two types of electrical humidity sensors. The standard reference humidity was calculated from dew-point temperature and air dry-bulb temperature measured by a chilled mirror monitor. This divided-flow generator could produce consistent result of RH measurement results. The uncertainty of the reference standard increased with the increase of RH values. The combined uncertainty with the adequate calibration equations were ranged from 0.82% to 1.45% RH for resistive humidity sensors and 0.63% to 1.4% for capacitive humidity sensors, respectively. This self-made, divided-flow generator, and calibration method are cheap, time-saving, and easy to be used. Thus, the proposed approach can easily be applied in research laboratories. PMID:29466313

Experimental validation of a self-calibrating cryogenic mass flowmeter

NASA Astrophysics Data System (ADS)

Janzen, A.; Boersch, M.; Burger, B.; Drache, J.; Ebersoldt, A.; Erni, P.; Feldbusch, F.; Oertig, D.; Grohmann, S.

2017-12-01

The Karlsruhe Institute of Technology (KIT) and the WEKA AG jointly develop a commercial flowmeter for application in helium cryostats. The flowmeter functions according to a new thermal measurement principle that eliminates all systematic uncertainties and enables self-calibration during real operation. Ideally, the resulting uncertainty of the measured flow rate is only dependent on signal noises, which are typically very small with regard to the measured value. Under real operating conditions, cryoplant-dependent flow rate fluctuations induce an additional uncertainty, which follows from the sensitivity of the method. This paper presents experimental results with helium at temperatures between 30 and 70 K and flow rates in the range of 4 to 12 g/s. The experiments were carried out in a control cryostat of the 2 kW helium refrigerator of the TOSKA test facility at KIT. Inside the cryostat, the new flowmeter was installed in series with a Venturi tube that was used for reference measurements. The measurement results demonstrate the self-calibration capability during real cryoplant operation. The influences of temperature and flow rate fluctuations on the self-calibration uncertainty are discussed.

Calibration of hydrological models using flow-duration curves

NASA Astrophysics Data System (ADS)

Westerberg, I. K.; Guerrero, J.-L.; Younger, P. M.; Beven, K. J.; Seibert, J.; Halldin, S.; Freer, J. E.; Xu, C.-Y.

2011-07-01

The degree of belief we have in predictions from hydrologic models will normally depend on how well they can reproduce observations. Calibrations with traditional performance measures, such as the Nash-Sutcliffe model efficiency, are challenged by problems including: (1) uncertain discharge data, (2) variable sensitivity of different performance measures to different flow magnitudes, (3) influence of unknown input/output errors and (4) inability to evaluate model performance when observation time periods for discharge and model input data do not overlap. This paper explores a calibration method using flow-duration curves (FDCs) to address these problems. The method focuses on reproducing the observed discharge frequency distribution rather than the exact hydrograph. It consists of applying limits of acceptability for selected evaluation points (EPs) on the observed uncertain FDC in the extended GLUE approach. Two ways of selecting the EPs were tested - based on equal intervals of discharge and of volume of water. The method was tested and compared to a calibration using the traditional model efficiency for the daily four-parameter WASMOD model in the Paso La Ceiba catchment in Honduras and for Dynamic TOPMODEL evaluated at an hourly time scale for the Brue catchment in Great Britain. The volume method of selecting EPs gave the best results in both catchments with better calibrated slow flow, recession and evaporation than the other criteria. Observed and simulated time series of uncertain discharges agreed better for this method both in calibration and prediction in both catchments. An advantage with the method is that the rejection criterion is based on an estimation of the uncertainty in discharge data and that the EPs of the FDC can be chosen to reflect the aims of the modelling application, e.g. using more/less EPs at high/low flows. While the method appears less sensitive to epistemic input/output errors than previous use of limits of acceptability applied directly to the time series of discharge, it still requires a reasonable representation of the distribution of inputs. Additional constraints might therefore be required in catchments subject to snow and where peak-flow timing at sub-daily time scales is of high importance. The results suggest that the calibration method can be useful when observation time periods for discharge and model input data do not overlap. The method could also be suitable for calibration to regional FDCs while taking uncertainties in the hydrological model and data into account.

A High Precision $3.50 Open Source 3D Printed Rain Gauge Calibrator

NASA Astrophysics Data System (ADS)

Lopez Alcala, J. M.; Udell, C.; Selker, J. S.

2017-12-01

Currently available rain gauge calibrators tend to be designed for specific rain gauges, are expensive, employ low-precision water reservoirs, and do not offer the flexibility needed to test the ever more popular small-aperture rain gauges. The objective of this project was to develop and validate a freely downloadable, open-source, 3D printed rain gauge calibrator that can be adjusted for a wide range of gauges. The proposed calibrator provides for applying low, medium, and high intensity flow, and allows the user to modify the design to conform to unique system specifications based on parametric design, which may be modified and printed using CAD software. To overcome the fact that different 3D printers yield different print qualities, we devised a simple post-printing step that controlled critical dimensions to assure robust performance. Specifically, the three orifices of the calibrator are drilled to reach the three target flow rates. Laboratory tests showed that flow rates were consistent between prints, and between trials of each part, while the total applied water was precisely controlled by the use of a volumetric flask as the reservoir.

Recent modifications and calibration of the Langley low-turbulence pressure tunnel

NASA Technical Reports Server (NTRS)

Mcghee, R. J.; Beasley, W. D.; Foster, J. M.

1984-01-01

Modifications to the Langley Low-Turbulence Pressure Tunnel are presented and a calibration of the mean flow parameters in the test section is provided. Also included are the operational capability of the tunnel and typical test results for both single-element and multi-element airfoils. Modifications to the facility consisted of the following: replacement of the original cooling coils and antiturbulence screens and addition of a tunnel-shell heating system, a two dimensional model-support and force-balance system, a sidewall boundary layer control system, a remote-controlled survey apparatus, and a new data acquisition system. A calibration of the mean flow parameters in the test section was conducted over the complete operational range of the tunnel. The calibration included dynamic-pressure measurements, Mach number distributions, flow-angularity measurements, boundary-layer characteristics, and total-pressure profiles. In addition, test-section turbulence measurements made after the tunnel modifications have been included with these calibration data to show a comparison of existing turbulence levels with data obtained for the facility in 1941 with the original screen installation.

Role of rough surface topography on gas slip flow in microchannels.

PubMed

Zhang, Chengbin; Chen, Yongping; Deng, Zilong; Shi, Mingheng

2012-07-01

We conduct a lattice Boltzmann simulation of gas slip flow in microchannels incorporating rough surface effects as characterized by fractal geometry with a focus on gas-solid interaction. The gas slip flow in rough microchannels, which is characterized by Poiseuille number and mass flow rate, is evaluated and compared with smooth microchannels. The effects of roughness height, surface fractal dimension, and Knudsen number on slip behavior of gas flow in microchannels are all investigated and discussed. The results indicate that the presence of surface roughness reduces boundary slip for gas flow in microchannels with respect to a smooth surface. The gas flows at the valleys of rough walls are no-slip while velocity slips are observed over the top of rough walls. We find that the gas flow behavior in rough microchannels is insensitive to the surface topography irregularity (unlike the liquid flow in rough microchannels) but is influenced by the statistical height of rough surface and rarefaction effects. In particular, decrease in roughness height or increase in Knudsen number can lead to large wall slip for gas flow in microchannels.

Base flow calibration in a global hydrological model

NASA Astrophysics Data System (ADS)

van Beek, L. P.; Bierkens, M. F.

2006-12-01

Base flow constitutes an important water resource in many parts of the world. Its provenance and yield over time are governed by the storage capacity of local aquifers and the internal drainage paths, which are difficult to capture at the global scale. To represent the spatial and temporal variability in base flow adequately in a distributed global model at 0.5 degree resolution, we resorted to the conceptual model of aquifer storage of Kraaijenhoff- van de Leur (1958) that yields the reservoir coefficient for a linear groundwater store. This model was parameterised using global information on drainage density, climatology and lithology. Initial estimates of aquifer thickness, permeability and specific porosity from literature were linked to the latter two categories and calibrated to low flow data by means of simulated annealing so as to conserve the ordinal information contained by them. The observations used stem from the RivDis dataset of monthly discharge. From this dataset 324 stations were selected with at least 10 years of observations in the period 1958-1991 and an areal coverage of at least 10 cells of 0.5 degree. The dataset was split between basins into a calibration and validation set whilst preserving a representative distribution of lithology types and climate zones. Optimisation involved minimising the absolute differences between the simulated base flow and the lowest 10% of the observed monthly discharge. Subsequently, the reliability of the calibrated parameters was tested by reversing the calibration and validation sets.

Flight Test Results of an Angle of Attack and Angle of Sideslip Calibration Method Using Output-Error Optimization

NASA Technical Reports Server (NTRS)

Siu, Marie-Michele; Martos, Borja; Foster, John V.

2013-01-01

As part of a joint partnership between the NASA Aviation Safety Program (AvSP) and the University of Tennessee Space Institute (UTSI), research on advanced air data calibration methods has been in progress. This research was initiated to expand a novel pitot-static calibration method that was developed to allow rapid in-flight calibration for the NASA Airborne Subscale Transport Aircraft Research (AirSTAR) facility. This approach uses Global Positioning System (GPS) technology coupled with modern system identification methods that rapidly computes optimal pressure error models over a range of airspeed with defined confidence bounds. Subscale flight tests demonstrated small 2-s error bounds with significant reduction in test time compared to other methods. Recent UTSI full scale flight tests have shown airspeed calibrations with the same accuracy or better as the Federal Aviation Administration (FAA) accepted GPS 'four-leg' method in a smaller test area and in less time. The current research was motivated by the desire to extend this method for inflight calibration of angle of attack (AOA) and angle of sideslip (AOS) flow vanes. An instrumented Piper Saratoga research aircraft from the UTSI was used to collect the flight test data and evaluate flight test maneuvers. Results showed that the output-error approach produces good results for flow vane calibration. In addition, maneuvers for pitot-static and flow vane calibration can be integrated to enable simultaneous and efficient testing of each system.

Invited article: Time accurate mass flow measurements of solid-fueled systems.

PubMed

Olliges, Jordan D; Lilly, Taylor C; Joslyn, Thomas B; Ketsdever, Andrew D

2008-10-01

A novel diagnostic method is described that utilizes a thrust stand mass balance (TSMB) to directly measure time-accurate mass flow from a solid-fuel thruster. The accuracy of the TSMB mass flow measurement technique was demonstrated in three ways including the use of an idealized numerical simulation, verifying a fluid mass calibration with high-speed digital photography, and by measuring mass loss in more than 30 hybrid rocket motor firings. Dynamic response of the mass balance was assessed through weight calibration and used to derive spring, damping, and mass moment of inertia coefficients for the TSMB. These dynamic coefficients were used to determine the mass flow rate and total mass loss within an acrylic and gaseous oxygen hybrid rocket motor firing. Intentional variations in the oxygen flow rate resulted in corresponding variations in the total propellant mass flow as expected. The TSMB was optimized to determine mass losses of up to 2.5 g and measured total mass loss to within 2.5% of that calculated by a NIST-calibrated digital scale. Using this method, a mass flow resolution of 0.0011 g/s or 2% of the average mass flow in this study has been achieved.

Invited Article: Time accurate mass flow measurements of solid-fueled systems

NASA Astrophysics Data System (ADS)

Olliges, Jordan D.; Lilly, Taylor C.; Joslyn, Thomas B.; Ketsdever, Andrew D.

2008-10-01

A novel diagnostic method is described that utilizes a thrust stand mass balance (TSMB) to directly measure time-accurate mass flow from a solid-fuel thruster. The accuracy of the TSMB mass flow measurement technique was demonstrated in three ways including the use of an idealized numerical simulation, verifying a fluid mass calibration with high-speed digital photography, and by measuring mass loss in more than 30 hybrid rocket motor firings. Dynamic response of the mass balance was assessed through weight calibration and used to derive spring, damping, and mass moment of inertia coefficients for the TSMB. These dynamic coefficients were used to determine the mass flow rate and total mass loss within an acrylic and gaseous oxygen hybrid rocket motor firing. Intentional variations in the oxygen flow rate resulted in corresponding variations in the total propellant mass flow as expected. The TSMB was optimized to determine mass losses of up to 2.5 g and measured total mass loss to within 2.5% of that calculated by a NIST-calibrated digital scale. Using this method, a mass flow resolution of 0.0011 g/s or 2% of the average mass flow in this study has been achieved.

One-calibrant kinetic calibration for on-site water sampling with solid-phase microextraction.

PubMed

Ouyang, Gangfeng; Cui, Shufen; Qin, Zhipei; Pawliszyn, Janusz

2009-07-15

The existing solid-phase microextraction (SPME) kinetic calibration technique, using the desorption of the preloaded standards to calibrate the extraction of the analytes, requires that the physicochemical properties of the standard should be similar to those of the analyte, which limited the application of the technique. In this study, a new method, termed the one-calibrant kinetic calibration technique, which can use the desorption of a single standard to calibrate all extracted analytes, was proposed. The theoretical considerations were validated by passive water sampling in laboratory and rapid water sampling in the field. To mimic the variety of the environment, such as temperature, turbulence, and the concentration of the analytes, the flow-through system for the generation of standard aqueous polycyclic aromatic hydrocarbons (PAHs) solution was modified. The experimental results of the passive samplings in the flow-through system illustrated that the effect of the environmental variables was successfully compensated with the kinetic calibration technique, and all extracted analytes can be calibrated through the desorption of a single calibrant. On-site water sampling with rotated SPME fibers also illustrated the feasibility of the new technique for rapid on-site sampling of hydrophobic organic pollutants in water. This technique will accelerate the application of the kinetic calibration method and also will be useful for other microextraction techniques.

Posttest analysis of the FFTF inherent safety tests

DOE Office of Scientific and Technical Information (OSTI.GOV)

Padilla, A. Jr.; Claybrook, S.W.

Inherent safety tests were performed during 1986 in the 400-MW (thermal) Fast Flux Test Facility (FFTF) reactor to demonstrate the effectiveness of an inherent shutdown device called the gas expansion module (GEM). The GEM device provided a strong negative reactivity feedback during loss-of-flow conditions by increasing the neutron leakage as a result of an expanding gas bubble. The best-estimate pretest calculations for these tests were performed using the IANUS plant analysis code (Westinghouse Electric Corporation proprietary code) and the MELT/SIEX3 core analysis code. These two codes were also used to perform the required operational safety analyses for the FFTF reactormore » and plant. Although it was intended to also use the SASSYS systems (core and plant) analysis code, the calibration of the SASSYS code for FFTF core and plant analysis was not completed in time to perform pretest analyses. The purpose of this paper is to present the results of the posttest analysis of the 1986 FFTF inherent safety tests using the SASSYS code.« less

40 CFR 1065.715 - Natural gas.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Natural gas. 1065.715 Section 1065.715... PROCEDURES Engine Fluids, Test Fuels, Analytical Gases and Other Calibration Standards § 1065.715 Natural gas. (a) Except as specified in paragraph (b) of this section, natural gas for testing must meet the...

40 CFR 86.1516 - Calibration; frequency and overview.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Light-Duty Trucks; Idle Test...

40 CFR 86.1516 - Calibration; frequency and overview.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Emission Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Light-Duty Trucks; Idle...