Method for removing undesired particles from gas streams

DOEpatents

Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

1998-11-10

The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

Are cosmological gas accretion streams multiphase and turbulent?

NASA Astrophysics Data System (ADS)

Cornuault, Nicolas; Lehnert, Matthew D.; Boulanger, François; Guillard, Pierre

2018-03-01

Simulations of cosmological filamentary accretion reveal flows ("streams") of warm gas, T 104 K, which bring gas into galaxies efficiently. We present a phenomenological scenario in which gas in such flows, if it is shocked as it enters the halo as we assume and depending on the post-shock temperature, stream radius, its relative overdensity, and other factors, becomes biphasic and turbulent. We consider a collimated stream of warm gas that flows into a halo from an overdense filament of the cosmic web. The post-shock streaming gas expands because it has a higher pressure than the ambient halo gas and fragments as it cools. The fragmented stream forms a two phase medium: a warm cloudy phase embedded in hot post-shock gas. We argue that the hot phase sustains the accretion shock. During fragmentation, a fraction of the initial kinetic energy of the infalling gas is converted into turbulence among and within the warm clouds. The thermodynamic evolution of the post-shock gas is largely determined by the relative timescales of several processes. These competing timescales characterize the cooling, expansion of the post-shock gas, amount of turbulence in the clouds, and dynamical time of the halo. We expect the gas to become multiphase when the gas cooling and dynamical times are of the same order of magnitude. In this framework, we show that this mainly occurs in the mass range, Mhalo 1011 to 1013 M⊙, where the bulk of stars have formed in galaxies. Because of the expansion of the stream and turbulence, gas accreting along cosmic web filaments may eventually lose coherence and mix with the ambient halo gas. Through both the phase separation and "disruption" of the stream, the accretion efficiency onto a galaxy in a halo dynamical time is lowered. Decollimating flows make the direct interaction between galaxy feedback and accretion streams more likely, thereby further reducing the overall accretion efficiency. As we discuss in this work, moderating the gas accretion

Methanation of gas streams containing carbon monoxide and hydrogen

DOEpatents

Frost, Albert C.

1983-01-01

Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

Partial oxidation process for producing a stream of hot purified gas

DOEpatents

Leininger, Thomas F.; Robin, Allen M.; Wolfenbarger, James K.; Suggitt, Robert M.

1995-01-01

A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.

Partial oxidation process for producing a stream of hot purified gas

DOEpatents

Leininger, T.F.; Robin, A.M.; Wolfenbarger, J.K.; Suggitt, R.M.

1995-03-28

A partial oxidation process is described for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H{sub 2}, CO, CO{sub 2}, H{sub 2}O, CH{sub 4}, NH{sub 3}, HCl, HF, H{sub 2}S, COS, N{sub 2}, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N{sub 2} and H{sub 2}. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000 F. 1 figure.

Method and apparatus for decreased undesired particle emissions in gas streams

DOEpatents

Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Bustard, C.J.

1999-04-13

The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 5 figs.

Method and apparatus for decreased undesired particle emissions in gas streams

DOEpatents

Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Bustard, Cynthia Jean

1999-01-01

The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

Reclamation of potable water from mixed gas streams

DOEpatents

Judkins, Roddie R.; Bischoff, Brian L.; Debusk, Melanie Moses; Narula, Chaitanya

2016-07-19

An apparatus for separating a liquid from a mixed gas stream can include a wall, a mixed gas stream passageway, and a liquid collection assembly. The wall can include a first surface, a second surface, and a plurality of capillary condensation pores. The capillary condensation pores extend through the wall, and have a first opening on the first surface of the wall, and a second opening on the second surface of the wall. The pore size of the pores can be between about 2 nm to about 100 nm. The mixed gas stream passageway can be in fluid communication with the first opening. The liquid collection assembly can collect liquid from the plurality of pores.

Reclamation of potable water from mixed gas streams

DOEpatents

Judkins, Roddie R; Bischoff, Brian L; Debusk, Melanie Moses; Narula, Chaitanya

2013-08-20

An apparatus for separating a liquid from a mixed gas stream can include a wall, a mixed gas stream passageway, and a liquid collection assembly. The wall can include a first surface, a second surface, and a plurality of capillary condensation pores. The capillary condensation pores extend through the wall, and have a first opening on the first surface of the wall, and a second opening on the second surface of the wall. The pore size of the pores can be between about 2 nm to about 100 nm. The mixed gas stream passageway can be in fluid communication with the first opening. The liquid collection assembly can collect liquid from the plurality of pores.

Giant Intergalactic Gas Stream Longer Than Thought

NASA Astrophysics Data System (ADS)

2010-01-01

A giant stream of gas flowing from neighbor galaxies around our own Milky Way is much longer and older than previously thought, astronomers have discovered. The new revelations provide a fresh insight on what started the gaseous intergalactic streamer. The astronomers used the National Science Foundation's Robert C. Byrd Green Bank Telescope (GBT) to fill important gaps in the picture of gas streaming outward from the Magellanic Clouds. The first evidence of such a flow, named the Magellanic Stream, was discovered more than 30 years ago, and subsequent observations added tantalizing suggestions that there was more. However, the earlier picture showed gaps that left unanswered whether this other gas was part of the same system. "We now have answered that question. The stream is continuous," said David Nidever, of the University of Virginia. "We now have a much more complete map of the Magellanic Stream," he added. The astronomers presented their findings to the American Astronomical Society's meeting in Washington, DC. The Magellanic Clouds are the Milky Way's two nearest neighbor galaxies, about 150,000 to 200,000 light-years distant from the Milky Way. Visible in the Southern Hemisphere, they are much smaller than our Galaxy and may have been distorted by its gravity. Nidever and his colleagues observed the Magellanic Stream for more than 100 hours with the GBT. They then combined their GBT data with that from earlier studies with other radio telescopes, including the Arecibo telescope in Puerto Rico, the Parkes telescope in Australia, and the Westerbork telescope in the Netherlands. The result shows that the stream is more than 40 percent longer than previously known with certainty. One consequence of the added length of the gas stream is that it must be older, the astronomers say. They now estimate the age of the stream at 2.5 billion years. The revised size and age of the Magellanic Stream also provides a new potential explanation for how the flow got started

Method for the removal of elemental mercury from a gas stream

DOEpatents

Mendelsohn, Marshall H.; Huang, Hann-Sheng

1999-01-01

A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents.

Models of Tidally Induced Gas Filaments in the Magellanic Stream

NASA Astrophysics Data System (ADS)

Pardy, Stephen A.; D’Onghia, Elena; Fox, Andrew J.

2018-04-01

The Magellanic Stream and Leading Arm of H I that stretches from the Large and Small Magellanic Clouds (LMC and SMC) and over 200° of the Southern sky is thought to be formed from multiple encounters between the LMC and SMC. In this scenario, most of the gas in the Stream and Leading Arm is stripped from the SMC, yet recent observations have shown a bifurcation of the Trailing Arm that reveals LMC origins for some of the gas. Absorption measurements in the Stream also reveal an order of magnitude more gas than in current tidal models. We present hydrodynamical simulations of the multiple encounters between the LMC and SMC at their first pass around the Milky Way, assuming that the Clouds were more extended and gas-rich in the past. Our models create filamentary structures of gas in the Trailing Stream from both the LMC and SMC. While the SMC trailing filament matches the observed Stream location, the LMC filament is offset. In addition, the total observed mass of the Stream in these models is underestimated by a factor of four when the ionized component is accounted for. Our results suggest that there should also be gas stripped from both the LMC and SMC in the Leading Arm, mirroring the bifurcation in the Trailing Stream. This prediction is consistent with recent measurements of spatial variation in chemical abundances in the Leading Arm, which show that gas from multiple sources is present, although its nature is still uncertain.

Automatable Measurement of Gas Exchange Rate in Streams: Oxygen-Carbon Method

NASA Astrophysics Data System (ADS)

Pennington, R.; Haggerty, R.; Argerich, A.; Wondzell, S. M.

2015-12-01

Gas exchange rates between streams and the atmosphere are critically important to measurement of in-stream ecologic processes, as well as fate and transport of hazardous pollutants such as mercury and PCBs. Methods to estimate gas exchange rates include empirical relations to hydraulics, and direct injection of a tracer gas such as propane or SF6. Empirical relations are inconsistent and inaccurate, particularly for lower order, high-roughness streams. Gas injections are labor-intensive, and measured gas exchange rates are difficult to extrapolate in time since they change with discharge and stream geometry. We propose a novel method for calculation of gas exchange rates utilizing O2, pCO2, pH, and temperature data. Measurements, which can be automated using data loggers and probes, are made on the upstream and downstream end of the study reach. Gas exchange rates are then calculated from a solution to the transport equations for oxygen and dissolved inorganic carbon. Field tests in steep, low order, high roughness streams of the HJ Andrews Experimental Forest indicate the method to be viable along stream reaches with high downstream gas concentration gradients and high rates of gas transfer velocity. Automated and continuous collection of oxygen and carbonate chemistry data is increasingly common, thus the method may be used to estimate gas exchange rates through time, and is well suited for interactivity with databases.

Method for the removal of elemental mercury from a gas stream

DOEpatents

Mendelsohn, M.H.; Huang, H.S.

1999-05-04

A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents. 7 figs.

Method for treating a nuclear process off-gas stream

DOEpatents

Pence, Dallas T.; Chou, Chun-Chao

1984-01-01

Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

Method for removing particulate matter from a gas stream

DOEpatents

Postma, Arlin K.

1984-01-01

Particulate matter is removed from a stream of pressurized gas by directing the stream of gas upwardly through a bed of porous material, the porous bed being held in an open ended container and at least partially submerged in liquid. The passage of the gas through the porous bed sets up a circulation in the liquid which cleans the particulate matter from the bed.

Gas stream cleaning system and method

DOEpatents

Kunchal, S. Kumar; Erck, Louis J.; Harris, Harry A.

1979-04-13

An oil mist and solid particle laden gas from an oil shale retorting operation is initially treated with a temperature controlled oil spray and then by a coalescer to reduce the quantity of oil mist and remove most of the solid particle content of the gas stream and then finally treated by an electrostatic precipitator to essentially remove the oil mist remaining in the gas.

Electrolytic trapping of iodine from process gas streams

DOEpatents

Horner, Donald E.; Mailen, James C.; Posey, Franz A.

1977-01-25

A method for removing molecular, inorganic, and organic forms of iodine from process gas streams comprises the electrolytic oxidation of iodine in the presence of cobalt-III ions. The gas stream is passed through the anode compartment of a partitioned electrolytic cell having a nitric acid anolyte containing a catalytic amount of cobalt to cause the oxidation of effluent iodine species to aqueous soluble species.

Process for injecting liquid in moving natural gas streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Budke, H.T. Jr.; Rivers, J.B. Jr.

1979-01-02

A simplified, low-cost method of treating pressurized, moving natural gas streams in order to control problems created by entrained water in the gas is provided which facilitates downstream treatment of the gas and increases product yields by lessening the formation of oil and water emulsions and hydrates which can coat and clog processing equipment, while also minimizing corrosion of the latter. The method involves introduction of an agent into the moving gas stream which includes a polymer having recurring quaternized pyridinium groups therein for controlling the emulsion, hydrate, and corrosion problems. The method is especially effective when the entrained watermore » contains surfactants, detergents, soaps, and the like. In preferred forms a low moleuclar weight copolymer of styrene and 2-vinyl pyridine dispersed in water is atomized into the gas stream adjacent cooling and scrubbing stations. 8 claims.« less

Process for injecting liquid in moving natural gas streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rivers, J.B. Jr.; Budke, H.T. Jr.

1979-01-02

Western Chemical Co.'s simplified, low-cost method of treating pressurized, moving natural gas streams in order to control problems created by entrained water facilitates the downstream treatment of the gas and increases product yields by lessening the formation of oil and water emulsions and hydrates that can coat and clog the processing equipment, while also minimizing equipment corrosion. The method involves introducing into the moving gas stream an agent that includes a polymer having recurring quaternized pyridinium groups for controlling the emulsion, hydrate, and corrosion problems. The method is especially effective when the entrained water contains surfactants, detergents, soaps, etc. Inmore » preferred forms, a low-molecular-weight copolymer of styrene and 2-vinyl pyridine dispersed in water is atomized into the gas stream adjacent to cooling and scrubbing stations. The method is particularly useful in connection with natural gas products plants.« less

Use of argon to measure gas exchange in turbulent mountain streams

NASA Astrophysics Data System (ADS)

Hall, Robert O., Jr.; Madinger, Hilary L.

2018-05-01

Gas exchange is a parameter needed in stream metabolism and trace gas emissions models. One way to estimate gas exchange is via measuring the decline of added tracer gases such as sulfur hexafluoride (SF6). Estimates of oxygen (O2) gas exchange derived from SF6 additions require scaling via Schmidt number (Sc) ratio, but this scaling is uncertain under conditions of high gas exchange via bubbles because scaling depends on gas solubility as well as Sc. Because argon (Ar) and O2 have nearly identical Schmidt numbers and solubility, Ar may be a useful tracer gas for estimating stream O2 exchange. Here we compared rates of gas exchange measured via Ar and SF6 for turbulent mountain streams in Wyoming, USA. We measured Ar as the ratio of Ar : N2 using a membrane inlet mass spectrometer (MIMS). Normalizing to N2 confers higher precision than simply measuring [Ar] alone. We consistently enriched streams with Ar from 1 to 18 % of ambient Ar concentration and could estimate gas exchange rate using an exponential decline model. The mean ratio of gas exchange of Ar relative to SF6 was 1.8 (credible interval 1.1 to 2.5) compared to the theoretical estimate 1.35, showing that using SF6 would have underestimated exchange of Ar. Steep streams (slopes 11-12 %) had high rates of gas exchange velocity normalized to Sc = 600 (k600, 57-210 m d-1), and slope strongly predicted variation in k600 among all streams. We suggest that Ar is a useful tracer because it is easily measured, requires no scaling assumptions to estimate rates of O2 exchange, and is not an intense greenhouse gas as is SF6. We caution that scaling from rates of either Ar or SF6 gas exchange to CO2 is uncertain due to solubility effects in conditions of bubble-mediated gas transfer.

Method for high temperature mercury capture from gas streams

DOEpatents

Granite, Evan J [Wexford, PA; Pennline, Henry W [Bethel Park, PA

2006-04-25

A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

Superamphiphobic Silicon-Nanowire-Embedded Microsystem and In-Contact Flow Performance of Gas and Liquid Streams.

PubMed

Ko, Dong-Hyeon; Ren, Wurong; Kim, Jin-Oh; Wang, Jun; Wang, Hao; Sharma, Siddharth; Faustini, Marco; Kim, Dong-Pyo

2016-01-26

Gas and liquid streams are invariably separated either by a solid wall or by a membrane for heat or mass transfer between the gas and liquid streams. Without the separating wall, the gas phase is present as bubbles in liquid or, in a microsystem, as gas plugs between slugs of liquid. Continuous and direct contact between the two moving streams of gas and liquid is quite an efficient way of achieving heat or mass transfer between the two phases. Here, we report a silicon nanowire built-in microsystem in which a liquid stream flows in contact with an underlying gas stream. The upper liquid stream does not penetrate into the lower gas stream due to the superamphiphobic nature of the silicon nanowires built into the bottom wall, thereby preserving the integrity of continuous gas and liquid streams, although they are flowing in contact. Due to the superamphiphobic nature of silicon nanowires, the microsystem provides the best possible interfacial mass transfer known to date between flowing gas and liquid phases, which can achieve excellent chemical performance in two-phase organic syntheses.

Gas stream analysis using voltage-current time differential operation of electrochemical sensors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woo, Leta Yar-Li; Glass, Robert Scott; Fitzpatrick, Joseph Jay

A method for analysis of a gas stream. The method includes identifying an affected region of an affected waveform signal corresponding to at least one characteristic of the gas stream. The method also includes calculating a voltage-current time differential between the affected region of the affected waveform signal and a corresponding region of an original waveform signal. The affected region and the corresponding region of the waveform signals have a sensitivity specific to the at least one characteristic of the gas stream. The method also includes generating a value for the at least one characteristic of the gas stream basedmore » on the calculated voltage-current time differential.« less

Efficient gas-separation process to upgrade dilute methane stream for use as fuel

DOEpatents

Wijmans, Johannes G [Menlo Park, CA; Merkel, Timothy C [Menlo Park, CA; Lin, Haiqing [Mountain View, CA; Thompson, Scott [Brecksville, OH; Daniels, Ramin [San Jose, CA

2012-03-06

A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

Cleanup procedure for water, soil, animal and plant extracts for the use of electron-capture detector in the gas chromatographic analysis of organophosphorus insecticide residues.

PubMed

Kadoum, A M

1968-07-01

A simple, aqueous acetonitrile partition cleanup method for analyses of some common organophosphorus insecticide residues is described. The procedure described is for cleanup and quantitative recovery of parathion, methyl parathion, diazinon, malathion and thimet from different extracts. Those insecticides in the purified extracts of ground water, grain, soil, plant and animal tissues can be detected quantitatively by gas chromatography with an electron capture-detector at 0.01 ppm. Cleanup is satisfactory for paper and thin-layer chromatography for further identification of individual insecticides in the extracts.

A gas-tracer injection for evaluating the fate of methane in a coastal plain stream: Degassing versus in-stream oxidation

USGS Publications Warehouse

Heilweil, Victor M.; Solomon, D. Kip; Darrah, Thomas H.; Gilmore, Troy E.; Genereux, David P.

2016-01-01

Methane emissions from streams and rivers have recently been recognized as an important component of global greenhouse budgets. Stream methane is lost as evasion to the atmosphere or in-stream methane oxidation. Previous studies have quantified evasion and oxidation with point-scale measurements. In this study, dissolved gases (methane, krypton) were injected into a coastal plain stream in North Carolina to quantify stream CH4 losses at the watershed scale. Stream-reach modeling yielded gas transfer and oxidation rate constants of 3.2 ± 0.5 and 0.5 ± 1.5 d–1, respectively, indicating a ratio of about 6:1. The resulting evasion and oxidation rates of 2.9 mmol m–2 d–1 and 1,140 nmol L–1 d–1, respectively, lie within ranges of published values. Similarly, the gas transfer velocity (K600) of 2.1 m d–1 is consistent with other gas tracer studies. This study illustrates the utility of dissolved-gas tracers for evaluating stream methane fluxes. In contrast to point measurements, this approach provides a larger watershed-scale perspective. Further work is needed to quantify the magnitude of these fluxes under varying conditions (e.g., stream temperature, nutrient load, gradient, flow rate) at regional and global scales before reliable bottom-up estimates of methane evasion can be determined at global scales.

Process for simultaneous removal of SO.sub.2 and NO.sub.x from gas streams

DOEpatents

Rosenberg, Harvey S.

1987-01-01

A process for simultaneous removal of SO.sub.2 and NO.sub.x from a gas stream that includes flowing the gas stream to a spray dryer and absorbing a portion of the SO.sub.2 content of the gas stream and a portion of the NO.sub.x content of the gas stream with ZnO by contacting the gas stream with a spray of an aqueous ZnO slurry; controlling the gas outlet temperature of the spray dryer to within the range of about a 0.degree. to 125.degree. F. approach to the adiabatic saturation temperature; flowing the gas, unreacted ZnO and absorbed SO.sub.2 and NO.sub.x from the spray dryer to a fabric filter and collecting any solids therein and absorbing a portion of the SO.sub.2 remaining in the gas stream and a portion of the NO.sub.x remaining in the gas stream with ZnO; and controlling the ZnO content of the aqueous slurry so that sufficient unreacted ZnO is present in the solids collected in the fabric filter to react with SO.sub.2 and NO.sub.x as the gas passes through the fabric filter whereby the overall feed ratio of ZnO to SO.sub.2 plus NO.sub.x is about 1.0 to 4.0 moles of ZnO per of SO.sub.2 and about 0.5 to 2.0 moles of ZnO per mole of NO.sub.x. Particulates may be removed from the gas stream prior to treatment in the spray dryer. The process further allows regeneration of ZnO that has reacted to absorb SO.sub.2 and NO.sub.x from the gas stream and acid recovery.

Process for simultaneous removal of SO[sub 2] and NO[sub x] from gas streams

DOEpatents

Rosenberg, H.S.

1987-02-03

A process is described for simultaneous removal of SO[sub 2] and NO[sub x] from a gas stream that includes flowing the gas stream to a spray dryer and absorbing a portion of the SO[sub 2] content of the gas stream and a portion of the NO[sub x] content of the gas stream with ZnO by contacting the gas stream with a spray of an aqueous ZnO slurry; controlling the gas outlet temperature of the spray dryer to within the range of about a 0 to 125 F approach to the adiabatic saturation temperature; flowing the gas, unreacted ZnO and absorbed SO[sub 2] and NO[sub x] from the spray dryer to a fabric filter and collecting any solids therein and absorbing a portion of the SO[sub 2] remaining in the gas stream and a portion of the NO[sub x] remaining in the gas stream with ZnO; and controlling the ZnO content of the aqueous slurry so that sufficient unreacted ZnO is present in the solids collected in the fabric filter to react with SO[sub 2] and NO[sub x] as the gas passes through the fabric filter whereby the overall feed ratio of ZnO to SO[sub 2] plus NO[sub x] is about 1.0 to 4.0 moles of ZnO per of SO[sub 2] and about 0.5 to 2.0 moles of ZnO per mole of NO[sub x]. Particulates may be removed from the gas stream prior to treatment in the spray dryer. The process further allows regeneration of ZnO that has reacted to absorb SO[sub 2] and NO[sub x] from the gas stream and acid recovery. 4 figs.

Apparatus and method for removing mercury vapor from a gas stream

DOEpatents

Ganesan, Kumar [Butte, MT

2008-01-01

A metallic filter effectively removes mercury vapor from gas streams. The filter captures the mercury which then can be released and collected as product. The metallic filter is a copper mesh sponge plated with a six micrometer thickness of gold. The filter removes up to 90% of mercury vapor from a mercury contaminated gas stream.

Stream macroinvertebrate communities across a gradient of natural gas development in the Fayetteville Shale.

PubMed

Johnson, Erica; Austin, Bradley J; Inlander, Ethan; Gallipeau, Cory; Evans-White, Michelle A; Entrekin, Sally

2015-10-15

Oil and gas extraction in shale plays expanded rapidly in the U.S. and is projected to expand globally in the coming decades. Arkansas has doubled the number of gas wells in the state since 2005 mostly by extracting gas from the Fayetteville Shale with activity concentrated in mixed pasture-deciduous forests. Concentrated well pads in close proximity to streams could have adverse effects on stream water quality and biota if sedimentation associated with developing infrastructure or contamination from fracturing fluid and waste occurs. Cumulative effects of gas activity and local habitat conditions on macroinvertebrate communities were investigated across a gradient of gas well activity (0.2-3.6 wells per km(2)) in ten stream catchments in spring 2010 and 2011. In 2010, macroinvertebrate density was positively related to well pad inverse flowpath distance from streams (r=0.84, p<0.001). Relatively tolerant mayflies Baetis and Caenis (r=0.64, p=0.04), filtering hydropsychid caddisflies (r=0.73, p=0.01), and chironomid midge densities (r=0.79, p=0.008) also increased in streams where more well pads were closer to stream channels. Macroinvertebrate trophic structure reflected environmental conditions with greater sediment and primary production in streams with more gas activity close to streams. However, stream water turbidity (r=0.69, p=0.02) and chlorophyll a (r=0.89, p<0.001) were the only in-stream variables correlated with gas well activities. In 2011, a year with record spring flooding, a different pattern emerged where mayfly density (p=0.74, p=0.01) and mayfly, stonefly, and caddisfly richness (r=0.78, p=0.008) increased in streams with greater well density and less silt cover. Hydrology and well pad placement in a catchment may interact to result in different relationships between biota and catchment activity between the two sample years. Our data show evidence of different macroinvertebrate communities expressed in catchments with different levels of gas

Optical backscatter probe for sensing particulate in a combustion gas stream

DOEpatents

Parks, James E; Partridge, William P

2013-05-28

A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

Louisiana's statewide beach cleanup

USGS Publications Warehouse

Lindstedt, Dianne M.; Holmes, Joseph C.

1989-01-01

Litter along Lousiana's beaches has become a well-recognized problem. In September 1987, Louisiana's first statewide beach cleanup attracted about 3300 volunteers who filled 16,000 bags with trash collected along 15 beaches. An estimated 800,173 items were gathered. Forty percent of the items were made of plastic and 11% were of polystyrene. Of all the litter collected, 37% was beverage-related. Litter from the oil and gas, commercial fishing, and maritime shipping industries was found, as well as that left by recreational users. Although beach cleanups temporarily rid Louisiana beaches of litter, the real value of the effort is in public participation and education. Civic groups, school children, and individuals have benefited by increasing their awareness of the problems of trash disposal.

Stream primary producers relate positively to watershed natural gas measures in north-central Arkansas streams.

PubMed

Austin, Bradley J; Hardgrave, Natalia; Inlander, Ethan; Gallipeau, Cory; Entrekin, Sally; Evans-White, Michelle A

2015-10-01

Construction of unconventional natural gas (UNG) infrastructure (e.g., well pads, pipelines) is an increasingly common anthropogenic stressor that increases potential sediment erosion. Increased sediment inputs into nearby streams may decrease autotrophic processes through burial and scour, or sediment bound nutrients could have a positive effect through alleviating potential nutrient limitations. Ten streams with varying catchment UNG well densities (0-3.6 wells/km(2)) were sampled during winter and spring of 2010 and 2011 to examine relationships between landscape scale disturbances associated with UNG activity and stream periphyton [chlorophyll a (Chl a)] and gross primary production (GPP). Local scale variables including light availability and water column physicochemical variables were measured for each study site. Correlation analyses examined the relationships of autotrophic processes and local scale variables with the landscape scale variables percent pasture land use and UNG metrics (well density and well pad inverse flow path length). Both GPP and Chl a were primarily positively associated with the UNG activity metrics during most sample periods; however, neither landscape variables nor response variables correlated well with local scale factors. These positive correlations do not confirm causation, but they do suggest that it is possible that UNG development can alleviate one or more limiting factors on autotrophic production within these streams. A secondary manipulative study was used to examine the link between nutrient limitation and algal growth across a gradient of streams impacted by natural gas activity. Nitrogen limitation was common among minimally impacted stream reaches and was alleviated in streams with high UNG activity. These data provide evidence that UNG may stimulate the primary production of Fayetteville shale streams via alleviation of N-limitation. Restricting UNG activities from the riparian zone along with better enforcement of

Evaluation of Ruthenium Capture Methods for Tritium Pretreatment Off-Gas Streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spencer, Barry B.; Jubin, Robert Thomas; Bruffey, Stephanie H.

2017-07-01

In the reprocessing of used nuclear fuel, radioactive elements are released into various plant off-gas streams. While much research and development has focused on the abatement of the volatile nuclides 3H, 14C, 85Kr, and 129I, the potential release of semivolatile isotopes that could also report to the off-gas streams in a reprocessing facility has been examined. Ruthenium (as 106Ru) has been identified as one of the semivolatile nuclides requiring the greatest degree of abatement prior to discharging the plant off-gas to the environment.

Method of immobilizing carbon dioxide from gas streams

DOEpatents

Holladay, David W.; Haag, Gary L.

1979-01-01

This invention is a method for rapidly and continuously immobilizing carbon dioxide contained in various industrial off-gas streams, the carbon dioxide being immobilized as dry, stable, and substantially water-insoluble particulates. Briefly, the method comprises passing the gas stream through a fixed or fluidized bed of hydrated barium hydroxide to remove and immobilize the carbon dioxide by converting the bed to barium carbonate. The method has several important advantages: it can be conducted effectively at ambient temperature; it provides a very rapid reaction rate over a wide range of carbon dioxide concentrations; it provides high decontamination factors; and it has a high capacity for carbon dioxide. The invention is especially well suited for the removal of radioactive carbon dioxide from off-gases generated by nuclear-fuel reprocessing facilities and nuclear power plants.

Stream measurements locate thermogenic methane fluxes in groundwater discharge in an area of shale-gas development.

PubMed

Heilweil, Victor M; Grieve, Paul L; Hynek, Scott A; Brantley, Susan L; Solomon, D Kip; Risser, Dennis W

2015-04-07

The environmental impacts of shale-gas development on water resources, including methane migration to shallow groundwater, have been difficult to assess. Monitoring around gas wells is generally limited to domestic water-supply wells, which often are not situated along predominant groundwater flow paths. A new concept is tested here: combining stream hydrocarbon and noble-gas measurements with reach mass-balance modeling to estimate thermogenic methane concentrations and fluxes in groundwater discharging to streams and to constrain methane sources. In the Marcellus Formation shale-gas play of northern Pennsylvania (U.S.A.), we sampled methane in 15 streams as a reconnaissance tool to locate methane-laden groundwater discharge: concentrations up to 69 μg L(-1) were observed, with four streams ≥ 5 μg L(-1). Geochemical analyses of water from one stream with high methane (Sugar Run, Lycoming County) were consistent with Middle Devonian gases. After sampling was completed, we learned of a state regulator investigation of stray-gas migration from a nearby Marcellus Formation gas well. Modeling indicates a groundwater thermogenic methane flux of about 0.5 kg d(-1) discharging into Sugar Run, possibly from this fugitive gas source. Since flow paths often coalesce into gaining streams, stream methane monitoring provides the first watershed-scale method to assess groundwater contamination from shale-gas development.

A stream-based methane monitoring approach for evaluating groundwater impacts associated with unconventional gas development.

PubMed

Heilweil, Victor M; Stolp, Bert J; Kimball, Briant A; Susong, David D; Marston, Thomas M; Gardner, Philip M

2013-01-01

Gaining streams can provide an integrated signal of relatively large groundwater capture areas. In contrast to the point-specific nature of monitoring wells, gaining streams coalesce multiple flow paths. Impacts on groundwater quality from unconventional gas development may be evaluated at the watershed scale by the sampling of dissolved methane (CH4 ) along such streams. This paper describes a method for using stream CH4 concentrations, along with measurements of groundwater inflow and gas transfer velocity interpreted by 1-D stream transport modeling, to determine groundwater methane fluxes. While dissolved ionic tracers remain in the stream for long distances, the persistence of methane is not well documented. To test this method and evaluate CH4 persistence in a stream, a combined bromide (Br) and CH4 tracer injection was conducted on Nine-Mile Creek, a gaining stream in a gas development area in central Utah. A 35% gain in streamflow was determined from dilution of the Br tracer. The injected CH4 resulted in a fivefold increase in stream CH4 immediately below the injection site. CH4 and δ(13) CCH4 sampling showed it was not immediately lost to the atmosphere, but remained in the stream for more than 2000 m. A 1-D stream transport model simulating the decline in CH4 yielded an apparent gas transfer velocity of 4.5 m/d, describing the rate of loss to the atmosphere (possibly including some microbial consumption). The transport model was then calibrated to background stream CH4 in Nine-Mile Creek (prior to CH4 injection) in order to evaluate groundwater CH4 contributions. The total estimated CH4 load discharging to the stream along the study reach was 190 g/d, although using geochemical fingerprinting to determine its source was beyond the scope of the current study. This demonstrates the utility of stream-gas sampling as a reconnaissance tool for evaluating both natural and anthropogenic CH4 leakage from gas reservoirs into groundwater and surface water

Cold fronts and shocks formed by gas streams in galaxy clusters

NASA Astrophysics Data System (ADS)

Zinger, E.; Dekel, A.; Birnboim, Y.; Nagai, D.; Lau, E.; Kravtsov, A. V.

2018-05-01

Cold fronts (CFs) and shocks are hallmarks of the complex intra-cluster medium (ICM) in galaxy clusters. They are thought to occur due to gas motions within the ICM and are often attributed to galaxy mergers within the cluster. Using hydro-cosmological simulations of clusters of galaxies, we show that collisions of inflowing gas streams, seen to penetrate to the very centre of about half the clusters, offer an additional mechanism for the formation of shocks and CFs in cluster cores. Unlike episodic merger events, a gas stream inflow persists over a period of several Gyr and it could generate a particular pattern of multiple CFs and shocks.

Estimating the gas and dye quantities for modified tracer technique measurements of stream reaeration coefficients

USGS Publications Warehouse

Rathbun, R.E.

1979-01-01

Measuring the reaeration coefficient of a stream with a modified tracer technique has been accomplished by injecting either ethylene or ethylene and propane together and a rhodamine-WT dye solution into the stream. The movement of the tracers through the stream reach after injection is described by a one-dimensional diffusion equation. The peak concentrations of the tracers at the downstream end of the reach depend on the concentrations of the tracers in the stream at the injection site, the longitudinal dispersion coefficient, the mean water velocity, the length of the reach, and the duration of the injection period. The downstream gas concentrations also depend on the gas desorption coefficients of the reach. The concentrations of the tracer gases in the stream at the injection site depend on the flow rates of the gases through the injection diffusers, the efficiency of the gas absorption process, and the stream discharge. The concentration of dye in the stream at the injection site depends on the flow rate of the dye solution, the concentration of the dye solution, and the stream discharge. Equations for estimating the gas flow rates, the quantities of the gases, the dye concentration, and the quantity of dye together with procedures for determining the variables in these equations are presented. (Woodard-USGS)

Using high resolution measurements of gas tracers to determine metabolic rates in streams

NASA Astrophysics Data System (ADS)

Knapp, J. L.; Osenbrück, K.; Brennwald, M. S.; Cirpka, O. A.

2017-12-01

Hyporheic exchange and other hyporheic processes are strongly linked to stream respiration, as the majority of a streams' microorganisms are located within the streambed. Directly estimating these respiration rates on the reach scale is usually not possible, but they can indirectly be inferred from measurements of dissolved oxygen. This, however, requires determining stream reaeration rates with high precision. Conducting gas-tracer tests has been found to be the most reliable method to estimate stream reaeration, but the majority of field-based sampling techniques for tracer gases are either costly in time and materials, or imprecise. By contrast, on-site gas analysis using gas-equilibrium membrane-inlet mass spectrometers (miniRUEDI, Gasometrix GmbH [1]) avoid the errors caused by sampling, storage, and analysis in the standard sampling techniques. Furthermore, the high analytical frequency of the on-site mass-spectrometer provides concentration data exhibiting a low uncertainty. We present results from gas-tracer tests with a continuous injection of propane and noble gases as tracers in a number of small streams. The concentrations of the tracer gases are recorded continuously over time at the first measurement station to account for fluctuations of the input signal, whereas shorter sample sets are collected at all further measurement stations. Reaeration rate constants are calculated from gas measurements for individual stream sections. These rates are then used to estimate metabolic rates of respiration and primary production based on time series of oxygen measurements. To demonstrate the advancement of the method provided by the on-site analysis, results from measurements performed by on-site mass spectroscopy are compared to those from traditional headspace sampling with gas chromatography analysis. Additionally, differences in magnitude and uncertainty of the obtained reaeration rates of oxygen and calculated metabolic rates from both methods highlight the

Method for combined removal of mercury and nitrogen oxides from off-gas streams

DOEpatents

Mendelsohn, Marshall H [Downers Grove, IL; Livengood, C David [Lockport, IL

2006-10-10

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Stagnation pressure probe. [for measuring pressure of supersonic gas streams

NASA Technical Reports Server (NTRS)

Goodyer, M. J. (Inventor)

1974-01-01

A method and apparatus for measuring the stagnation pressure of supersonic velocity gas streams without the generation of shock waves which interfere with such measurements are given. The technique is insensitive to the type of gas and Mach number and is therefore particularly useful in the study of jet engine exhausts.

Method of purifying a gas stream using 1,2,3-triazolium ionic liquids

DOEpatents

Luebke, David; Nulwala, Hunald; Tang, Chau

2014-12-09

A method for separating a target gas from a gaseous mixture using 1,2,3-triazolium ionic liquids is presented. Industrial effluent streams may be cleaned by removing carbon dioxide from the stream by contacting the effluent stream with a 1,2,3-triazolium ionic liquid compound.

Method for removal and stabilization of mercury in mercury-containing gas streams

DOEpatents

Broderick, Thomas E.

2005-09-13

The present invention is directed to a process and apparatus for removing and stabilizing mercury from mercury-containing gas streams. A gas stream containing vapor phase elemental and/or speciated mercury is contacted with reagent, such as an oxygen-containing oxidant, in a liquid environment to form a mercury-containing precipitate. The mercury-containing precipitate is kept or placed in solution and reacts with one or more additional reagents to form a solid, stable mercury-containing compound.

The Interstellar Gas Dust Streams and Seeds of Life

NASA Astrophysics Data System (ADS)

Oleg, Khavroshkin; Vladislav, Tsyplakov

Gas dust Streams from Double Stars & Lunar Seismicity. The time series of seismic events were generated as follows: on the ordinate axis the peak amplitudes of events in standard units, on abscissa axis - seismogram durations of the same moonquakes and subsequent time intervals between them were used. Spectrum of the series disclosed time picks on hidden cosmological periodicities of lunar seismicity. A part of results (picks) presents orbital periods of double stars nearest to the Solar system. The explanation of that results is existing gas-dust streams from binary stars systems and interacting of it with lunar surface. Information content of the Nakamura`s Catalog of moonquakes is very rich: from solar-earth tides to clustering among the meteoroid streams [1, 2]. The histograms from meteoroid impacts seismic data revealed the seismic wave responses of the Moon to solar oscillations and the action on the lunar surface by dust-gas plasma of meteoroid streams [3]. The time series of seismic events were generated as follows: on an axis of ordinates - the peak amplitudes of events in standard units, on an abscissa - seismogram durations of the same moonquakes and subsequent time intervals between them were put aside [4]. Spectrum of the series of meteoroid streams seismicity disclosed time picks on orbital periods some planets and their satellites and solar oscillations [4, 5]. The research of peculiarities of histogram envelopes [3] and comparative common analysis solar bursts data and mass meteoroid distribution are confirmed [3, 4] and revealed Forbush`s effect for gas-dust plasma [6]. Hidden astrophysical periodicities of lunar seismicity were obtained early from an analysis of time series [7] which were similarity to series [4]. The path of results of [7] is presented in the Table where picks presents orbital periods of double stars nearest to the Solar system. Hypothesis for explanation of the Table results is existing gas-dust streams from binary stars near

Control of gas contaminants in air streams through biofiltration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holt, T.; Lackey, L.

1996-11-01

According to the National Institute for Occupational Safety and Health (NIOSH), the maximum styrene concentration allowed in the work place is 50 ppm for up to a 10-hour work day during a 40-hour work week. The US EPA has classified styrene as one of the 189 hazardous air pollutants listed under Title 3 of the Clean Air Act Amendments to be reduced by a factor of 90% by the year 2000. Significant quantities of styrene are emitted to the atmosphere each year by boat manufacturers. A typical fiberglass boat manufacturing facility can emit over 273 metric tons/year of styrene. Themore » concentration of styrene in the industrial exhaust gas ranges from 20 to 100 ppmv. Such dilute, high volume organically tainted air streams can make conventional abatement technologies such as thermal incineration, adsorption, or absorption technically incompetent or prohibitively expensive. An efficient, innovative, and economical means of remediating styrene vapors would be of value to industries and to the environment. Biofilter technology depends on microorganisms that are immobilized on the packing material in a solid phase reactor to remove or degrade environmentally undesirable compounds contaminating gas streams. The technology is especially successful for treating large volumes of air containing low concentrations of contaminants. The objective of this study was to investigate the feasibility of using biofiltration to treat waste gas streams containing styrene and to determine the critical design and operating parameters for such a system.« less

Investigation of post hydraulic fracturing well cleanup physics in the Cana Woodford Shale

NASA Astrophysics Data System (ADS)

Lu, Rong

Hydraulic fracturing was first carried out in the 1940s and has gained popularity in current development of unconventional resources. Flowing back the fracturing fluids is critical to a frac job, and determining well cleanup characteristics using the flowback data can help improve frac design. It has become increasingly important as a result of the unique flowback profiles observed in some shale gas plays due to the unconventional formation characteristics. Computer simulation is an efficient and effective way to tackle the problem. History matching can help reveal some mechanisms existent in the cleanup process. The Fracturing, Acidizing, Stimulation Technology (FAST) Consortium at Colorado School of Mines previously developed a numerical model for investigating the hydraulic fracturing process, cleanup, and relevant physics. It is a three-dimensional, gas-water, coupled fracture propagation-fluid flow simulator, which has the capability to handle commonly present damage mechanisms. The overall goal of this research effort is to validate the model on real data and to investigate the dominant physics in well cleanup for the Cana Field, which produces from the Woodford Shale in Oklahoma. To achieve this goal, first the early time delayed gas production was explained and modeled, and a simulation framework was established that included all three relevant damage mechanisms for a slickwater fractured well. Next, a series of sensitivity analysis of well cleanup to major reservoir, fracture, and operational variables was conducted; five of the Cana wells' initial flowback data were history matched, specifically the first thirty days' gas and water producing rates. Reservoir matrix permeability, net pressure, Young's modulus, and formation pressure gradient were found to have an impact on the gas producing curve's shape, in different ways. Some moderately good matches were achieved, with the outcome of some unknown reservoir information being proposed using the

Influence of infrastructure on water quality and greenhouse gas dynamics in urban streams

NASA Astrophysics Data System (ADS)

Smith, Rose M.; Kaushal, Sujay S.; Beaulieu, Jake J.; Pennino, Michael J.; Welty, Claire

2017-06-01

Streams and rivers are significant sources of nitrous oxide (N2O), carbon dioxide (CO2), and methane (CH4) globally, and watershed management can alter greenhouse gas (GHG) emissions from streams. We hypothesized that urban infrastructure significantly alters downstream water quality and contributes to variability in GHG saturation and emissions. We measured gas saturation and estimated emission rates in headwaters of two urban stream networks (Red Run and Dead Run) of the Baltimore Ecosystem Study Long-Term Ecological Research project. We identified four combinations of stormwater and sanitary infrastructure present in these watersheds, including: (1) stream burial, (2) inline stormwater wetlands, (3) riparian/floodplain preservation, and (4) septic systems. We selected two first-order catchments in each of these categories and measured GHG concentrations, emissions, and dissolved inorganic and organic carbon (DIC and DOC) and nutrient concentrations biweekly for 1 year. From a water quality perspective, the DOC : NO3- ratio of streamwater was significantly different across infrastructure categories. Multiple linear regressions including DOC : NO3- and other variables (dissolved oxygen, DO; total dissolved nitrogen, TDN; and temperature) explained much of the statistical variation in nitrous oxide (N2O, r2 = 0.78), carbon dioxide (CO2, r2 = 0.78), and methane (CH4, r2 = 0.50) saturation in stream water. We measured N2O saturation ratios, which were among the highest reported in the literature for streams, ranging from 1.1 to 47 across all sites and dates. N2O saturation ratios were highest in streams draining watersheds with septic systems and strongly correlated with TDN. The CO2 saturation ratio was highly correlated with the N2O saturation ratio across all sites and dates, and the CO2 saturation ratio ranged from 1.1 to 73. CH4 was always supersaturated, with saturation ratios ranging from 3.0 to 2157. Longitudinal surveys extending form headwaters to third

Potential flue gas impurities in carbon dioxide streams separated from coal-fired power plants.

PubMed

Lee, Joo-Youp; Keener, Tim C; Yang, Y Jeffery

2009-06-01

For geological sequestration of carbon dioxide (CO2) separated from pulverized coal combustion flue gas, it is necessary to adequately evaluate the potential impacts of flue gas impurities on groundwater aquifers in the case of the CO2 leakage from its storage sites. This study estimated the flue gas impurities to be included in the CO2 stream separated from a CO2 control unit for a different combination of air pollution control devices and different flue gas compositions. Specifically, the levels of acid gases and mercury vapor were estimated for the monoethanolamine (MEA)-based absorption process on the basis of published performance parameters of existing systems. Among the flue gas constituents considered, sulfur dioxide (SO2) is known to have the most adverse impact on MEA absorption. When a flue gas contains 3000 parts per million by volume (ppmv) SO2 and a wet flue gas desulfurization system achieves its 95% removal, approximately 2400 parts per million by weight (ppmw) SO2 could be included in the separated CO2 stream. In addition, the estimated concentration level was reduced to as low as 135 ppmw for the SO2 of less than 10 ppmv in the flue gas entering the MEA unit. Furthermore, heat-stable salt formation could further reduce the SO2 concentration below 40 ppmw in the separated CO2 stream. In this study, it is realized that the formation rates of heat-stable salts in MEA solution are not readily available in the literature and are critical to estimating the levels and compositions of flue gas impurities in sequestered CO2 streams. In addition to SO2, mercury, and other impurities in separated CO2 streams could vary depending on pollutant removal at the power plants and impose potential impacts on groundwater. Such a variation and related process control in the upstream management of carbon separation have implications for groundwater protection at carbon sequestration sites and warrant necessary considerations in overall sequestration planning

Dissolved Greenhouse Gas Concentration Patterns and Relationships with Stream Chemistry in Tropical Headwater Streams

NASA Astrophysics Data System (ADS)

López-Lloreda, C.; McDowell, W. H.; Potter, J.

2017-12-01

Recent studies have shown that freshwater ecosystems, mainly lakes and large rivers, can be an important source of greenhouse gas (GHG) emissions. Headwater streams have received less attention but have been identified as being a potentially important contributor to these emissions. The complex biogeochemical interactions between dissolved GHG, stream chemistry and other physicochemical parameters in streams are not well understood, particularly in small, tropical headwater streams. Surface water samples were taken at weekly intervals at 8 sites in the Luquillo Experimental Forest in Puerto Rico. Samples were analyzed for carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) as well as dissolved organic carbon (DOC), nitrate (NO3) and other major cations and anions. Additionally, physicochemical parameters and discharge (at a subset of sites) were recorded for each sample. Initial analyses of stream greenhouse gas concentrations showed very little seasonality across all sites as well as no change in concentrations during a drought in 2015. One of our hypothesized drivers, discharge, did not show any significant relationship with any of the greenhouse gases at our two gaged sites. Relationships between GHG and stream chemistry, mainly DOC and NO3, varied across sites. A significant negative relationship was found between NO3 and N2O when data were pooled across all sites, but no significant relationship was found at any individual site. CH4 was positively correlated with NO3, but only at one of our sites. N2O showed a significant positive relationship with DOC at two of our sites but interestingly, CO2 and CH4 did not show any significant relationship with DOC. Our initial results suggest that NO3 can be an important driver for N2O and CH4 concentrations, while DOC can be an important driver for N2O. Our results differ from those found in lowland tropical rivers, suggesting that river order and floodplain connections may be important drivers of GHG

Plutonium mining for cleanup.

PubMed

Bramlitt, E T

1988-08-01

Cleanup is the act of making a contaminated site relatively free of Pu so it may be used without radiological safety restrictions. Contaminated ground is the focus of major cleanups. Cleanup traditionally involves determining Pu content of soil, digging up soil in which radioactivity exceeds guidelines, and relocating excised soil to a waste-disposal site. Alternative technologies have been tested at Johnston Atoll (JA), where there is as much as 100,000 m3 of Pu-contaminated soil. A mining pilot plant operated for the first 6 mo of 1986 and made 98% of soil tested "clean", from more than 40 kBq kg-1 (1000 pCi g-1) to less than about 500 Bq kg-1 (15 pCi g-1) by concentrating Pu in 2% of the soil. The pilot plant is now installed at the U.S. Department of Energy Nevada Test Site for evaluating cleanup of other contaminated soils and refining cleanup effectiveness. A full-scale cleanup plant has been programmed for JA in 1988. In this paper, previous cleanups are reviewed, and the mining endeavor at JA is detailed. "True soil cleanup" is contrasted with the classical "soil relocation cleanup." The mining technology used for Pu cleanup has been in use for more than a century. Mining for cleanup, however, is unique. It is envisioned as being prominent for radiological and other cleanups in the future.

Process for producing methane from gas streams containing carbon monoxide and hydrogen

DOEpatents

Frost, Albert C.

1980-01-01

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

Airfoil lance apparatus for homogeneous humidification and sorbent dispersion in a gas stream

DOEpatents

Myers, Robert B.; Yagiela, Anthony S.

1990-12-25

An apparatus for spraying an atomized mixture into a gas stream comprises a stream line airfoil member having a large radius leading edge and a small radius trailing edge. A nozzle assembly pierces the trailing edge of the airfoil member and is concentrically surrounded by a nacelle which directs shielding gas from the interior of the airfoil member around the nozzle assembly. Flowable medium to be atomized and atomizing gas for atomizing the medium are supplied in concentric conduits to the nozzle. A plurality of nozzles each surrounded by a nacelle are spaced along the trailing edge of the airfoil member.

Airfoil lance apparatus for homogeneous humidification and sorbent dispersion in a gas stream

DOEpatents

Myers, R.B.; Yagiela, A.S.

1990-12-25

An apparatus for spraying an atomized mixture into a gas stream comprises a stream line airfoil member having a large radius leading edge and a small radius trailing edge. A nozzle assembly pierces the trailing edge of the airfoil member and is concentrically surrounded by a nacelle which directs shielding gas from the interior of the airfoil member around the nozzle assembly. Flowable medium to be atomized and atomizing gas for atomizing the medium are supplied in concentric conduits to the nozzle. A plurality of nozzles each surrounded by a nacelle are spaced along the trailing edge of the airfoil member. 3 figs.

Removal of VOCs from humidified gas streams using activated carbon cloth

USGS Publications Warehouse

Cal, M.P.; Rood, M.J.; Larson, S.M.

1996-01-01

This research investigates the effects of relative humidity (RH) on the adsorption of soluble (acetone) and insoluble (benzene) volatile organic compounds (VOCs) with activated carbon cloths (ACC). A gravimetric balance was used in conjunction with a gas chromatograph/mass spectrophotometer to determine the individual amounts of water and VOC adsorbed on an ACC sample. RH values from 0 to 90% and organic concentrations from 350 to 1000 ppmv were examined. The presence of water vapor in the gas-stream along with acetone (350 and 500 ppmv) had little effect on the adsorption capacity of acetone even at 90% RH. Water vapor in the gas stream had little effect on the adsorption capacity of benzene (500 ppmv) until about 65% RH, when a rapid decrease resulted in the adsorption capacity of benzene with increasing RH. This RH was also about where capillary condensation of water vapor occurs within ACC pores. Water vapor condenses within the ACC pores, making them unavailable for benzene adsorption. Increasing benzene concentration can have a significant effect on the amount of water vapor adsorbed. At 86% RH and 500 ppmv, 284 mg/g water was adsorbed, while at 86% RH and 1000 ppmv, only 165 mg/g water was adsorbed. Water vapor was more inhibitory for benzene adsorption as benzene concentration in the gas stream decreased. Copyright ?? 1996 Elsevier Science Ltd.

Method for directly recovering fluorine from gas streams

DOEpatents

Orlett, Michael J.; Saraceno, Anthony J.

1981-01-01

This invention is a process for the direct recovery of gaseous fluorine from waste-gas streams or the like. The process comprises passing the gas stream through a bed of anhydrous K.sub.3 NiF.sub.6 pellets to fluorinate the same to K.sub.3 NiF.sub.7 and subsequently desorbing the fluorine by heating the K.sub.3 NiF.sub.7 pellets to a temperature re-converting them to K.sub.3 NiF.sub.6. The efficiency of the fluorine-absorption step is maximized by operating in a selected and conveniently low temperature. The desorbed fluorine is highly pure and is at a pressure of several atmospheres. Preferably, the K.sub.3 NiF.sub.6 pellets are prepared by a method including the steps of forming agglomerates of hydrated K.sub.3 NiF.sub.5, sintering the agglomerates to form K.sub.3 NiF.sub.5 pellets of enhanced reactivity with respect to fluorine, and fluorinating the sintered pellets to K.sub.3 NiF.sub.6.

Spray process for the recovery of CO.sub.2 from a gas stream and a related apparatus

DOEpatents

Soloveichik, Grigorii Lev; Perry, Robert James; Wood, Benjamin Rue; Genovese, Sarah Elizabeth

2014-02-11

A method for recovering carbon dioxide (CO.sub.2) from a gas stream is disclosed. The method includes the step of reacting CO.sub.2 in the gas stream with fine droplets of a liquid absorbent, so as to form a solid material in which the CO.sub.2 is bound. The solid material is then transported to a desorption site, where it is heated, to release substantially pure CO.sub.2 gas. The CO.sub.2 gas can then be collected and used or transported in any desired way. A related apparatus for recovering carbon dioxide (CO.sub.2) from a gas stream is also described herein.

Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

DOEpatents

Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

2005-11-08

A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

Automated mini-column solid-phase extraction cleanup for high-throughput analysis of chemical contaminants in foods by low-pressure gas chromatography – tandem mass spectrometry

USDA-ARS?s Scientific Manuscript database

This study demonstrated the application of an automated high-throughput mini-cartridge solid-phase extraction (mini-SPE) cleanup for the rapid low-pressure gas chromatography – tandem mass spectrometry (LPGC-MS/MS) analysis of pesticides and environmental contaminants in QuEChERS extracts of foods. ...

Greener Cleanups

EPA Pesticide Factsheets

OSWER’s goal is to reduce the environmental footprint of cleanup activities at contaminated sites to the maximum extent possible. This website shares policies, tools and practices to achieve that goal across cleanup programs.

Applications for activated carbons from waste tires: Natural gas storage and air pollution control

USGS Publications Warehouse

Brady, T.A.; Rostam-Abadi, M.; Rood, M.J.

1996-01-01

Natural gas storage for natural gas vehicles and the separation and removal of gaseous contaminants from gas streams represent two emerging applications for carbon adsorbents. A possible precursor for such adsorbents is waste tires. In this study, activated carbon has been developed from waste tires and tested for its methane storage capacity and SO2 removal from a simulated flue-gas. Tire-derived carbons exhibit methane adsorption capacities (g/g) within 10% of a relatively expensive commercial activated carbon; however, their methane storage capacities (Vm/Vs) are almost 60% lower. The unactivated tire char exhibits SO2 adsorption kinetics similar to a commercial carbon used for flue-gas clean-up. Copyright ?? 1996 Elsevier Science Ltd.

Reedy Creek Cleanup: The Evolution of a University Geography Service-Learning Project

ERIC Educational Resources Information Center

Parece, Tammy E.; Aspaas, Helen Ruth

2007-01-01

Service-learning courses within a university setting help students to better understand their roles as members of civil society. This article examines the evolution of an urban stream cleanup project that has been part of a world regions geography course for six years. After connecting course goals with the current best practice literature on…

Determination of the effect of formation water on fracture-fluid cleanup

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-03-01

Understanding hydraulic-fracture cleanup is essential for improving well stimulation. Residual gel damages fracture conductivity, shortens effective fracture half-length, and limits well productivity. The drive to develop fluids, additives, and procedures that minimize this damage continues to be a dominant theme in fracture-fluid-development programs. Fracture cleanup is a complex problem, and many parameters (e.g., fluid system, job design, flowback procedure, and reservoir conditions) can influence polymer and fluid recovery efficiencies. Often, specific products and methods that work well in one reservoir have little effect in another. Systematic analysis of fluid and polymer returns after a treatment is completed is the onlymore » way to quantify fracture cleanup. This is referred to as flowback analysis. This paper discusses a flowback-analysis field study on large hydraulic-fracturing treatments in the Taylor zone of the Cotton Valley formation in east Texas. This is a low-permeability (approximately 0.01 md) tight gas formation. It is a heterogeneous zone with layers of productive sandstone interspersed with relatively impermeable layers of shale. A typical well in this field initially produces approximately 0.75 to 1.3 MMcf/D gas and 35 to 40 bbl of water/MMcf of gas. The returns from 10 wells in this field were analyzed thoroughly.« less

Gas-film coefficients for streams

USGS Publications Warehouse

Rathbun, R.E.; Tai, D.Y.

1983-01-01

Equations for predicting the gas-film coefficient for the volatilization of organic solutes from streams are developed. The film coefficient is a function of windspeed and water temperature. The dependence of the coefficient on windspeed is determined from published information on the evaporation of water from a canal. The dependence of the coefficient on temperature is determined from laboratory studies on the evaporation of water. Procedures for adjusting the coefficients for different organic solutes are based on the molecular diffusion coefficient and the molecular weight. The molecular weight procedure is easiest to use because of the availability of molecular weights. However, the theoretical basis of the procedure is questionable. The diffusion coefficient procedure is supported by considerable data. Questions, however, remain regarding the exact dependence of the film coefficint on the diffusion coefficient. It is suggested that the diffusion coefficient procedure with a 0.68-power dependence be used when precise estimate of the gas-film coefficient are needed and that the molecular weight procedure be used when only approximate estimates are needed.

Heat Transfer to Bodies in a High-speed Rarified-Gas Stream

NASA Technical Reports Server (NTRS)

Stalder, Jackson R; Goodwin, Glen; Creager, Marcus O

1952-01-01

Report presents the results of an investigation to determine the equilibrium temperature and heat-transfer coefficients for transverse cylinders in a high-speed stream of rarefied gas measured over a range of Knudsen numbers (ratio of molecular-mean-free path to cylinder diameter) from 0.025 to 11.8 and for Mach numbers from 2.0 to 3.3. The range of free-stream Reynolds numbers was from 0.28 to 203. The models tested were 0.0010-, 0.0050-, 0.030-, 0.051-, 0.080-, and 0.126-inch -diameter cylinders held normal to the stream.

Iodine Pathways and Off-Gas Stream Characteristics for Aqueous Reprocessing Plants – A Literature Survey and Assessment

DOE Office of Scientific and Technical Information (OSTI.GOV)

R. T. Jubin; D. M. Strachan; N. R. Soelberg

2013-09-01

Used nuclear fuel is currently being reprocessed in only a few countries, notably France, England, Japan, and Russia. The need to control emissions of the gaseous radionuclides to the air during nuclear fuel reprocessing has already been reported for the entire plant. But since the gaseous radionuclides can partition to various different reprocessing off-gas streams, for example, from the head end, dissolver, vessel, cell, and melter, an understanding of each of these streams is critical. These off-gas streams have different flow rates and compositions and could have different gaseous radionuclide control requirements, depending on how the gaseous radionuclides partition. Thismore » report reviews the available literature to summarize specific engineering data on the flow rates, forms of the volatile radionuclides in off-gas streams, distributions of these radionuclides in these streams, and temperatures of these streams. This document contains an extensive bibliography of the information contained in the open literature.« less

Coal derived fuel gases for molten carbonate fuel cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1979-11-01

Product streams from state-of-the-art and future coal gasification systems are characterized to guide fuel cell program planners and researchers in establishing performance goals and developing materials for molten carbonate fuel cells that will be compatible with gasifier product gases. Results are presented on: (1) the range of gasifier raw-gas compositions available from the major classes of coal gasifiers; (2) the degree of gas clean-up achievable with state-of-the-art and future gas clean-up systems; and (3) the energy penalties associated with gas clean-up. The study encompasses fixed-bed, fluid-bed, entrained-bed, and molten salt gasifiers operating with Eastern bituminous and Western subbituminous coals. Gasifiersmore » operating with air and oxygen blowing are evaluated, and the coal gasification product streams are characterized with respect to: (1) major gas stream constituents, e.g., CO, H/sub 2/, CO/sub 2/, CH/sub 4/, N/sub 2/, H/sub 2/O; (2) major gas stream contaminants, e.g., H/sub 2/S, COS, particulates, tars, etc.; and (3) trace element contaminants, e.g., Na, K, V, Cl, Hg, etc.« less

CO 2 capture from IGCC gas streams using the AC-ABC process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagar, Anoop; McLaughlin, Elisabeth; Hornbostel, Marc

The objective of this project was to develop a novel, low-cost CO 2 capture process from pre-combustion gas streams. The bench-scale work was conducted at the SRI International. A 0.15-MWe integrated pilot plant was constructed and operated for over 700 hours at the National Carbon Capture Center, Wilsonville, AL. The AC-ABC (ammonium carbonate-ammonium bicarbonate) process for capture of CO 2 and H 2S from the pre-combustion gas stream offers many advantages over Selexol-based technology. The process relies on the simple chemistry of the NH 3-CO 2-H 2O-H 2S system and on the ability of the aqueous ammoniated solution to absorbmore » CO 2 at near ambient temperatures and to release it as a high-purity, high-pressure gas at a moderately elevated regeneration temperature. It is estimated the increase in cost of electricity (COE) with the AC-ABC process will be ~ 30%, and the cost of CO 2 captured is projected to be less than $27/metric ton of CO 2 while meeting 90% CO 2 capture goal. The Bechtel Pressure Swing Claus (BPSC) is a complementary technology offered by Bechtel Hydrocarbon Technology Solutions, Inc. BPSC is a high-pressure, sub-dew-point Claus process that allows for nearly complete removal of H 2S from a gas stream. It operates at gasifier pressures and moderate temperatures and does not affect CO 2 content. When coupled with AC-ABC, the combined technologies allow a nearly pure CO 2 stream to be captured at high pressure, something which Selexol and other solvent-based technologies cannot achieve.« less

Mold: Cleanup and Remediation

MedlinePlus

... National Center for Environmental Health (NCEH) Cleanup and Remediation Recommend on Facebook Tweet Share Compartir On This ... CDC and EPA on mold cleanup, removal and remediation. Cleanup information for you and your family Homeowner’s ...

A Novel Method for Determining the Gas Transfer Velocity of Carbon Dioxide in Streams

NASA Astrophysics Data System (ADS)

McDowell, M. J.; Johnson, M. S.

2016-12-01

Characterization of the global carbon cycle relies on the accurate quantification of carbon fluxes into and out of natural and human-dominated ecosystems. Among these fluxes, carbon dioxide (CO2) evasion from surface water has received increasing attention in recent years. However, limitations of current methods, including determination of the gas transfer velocity (k), compromise our ability to evaluate the significance of CO2 fluxes between freshwater systems and the atmosphere. We developed an automated method to determine gas transfer velocities of CO2 (kCO2), and tested it under a range of flow conditions for a first-order stream of a headwater catchment in southwestern British Columbia, Canada. Our method uses continuous in situ measurements of CO2 concentrations using two non-dispersive infrared (NDIR) sensors enclosed in water impermeable, gas permeable membranes (Johnson et al., 2010) downstream from a gas diffuser. CO2 was injected into the stream at regular intervals via a compressed gas tank connected to the diffuser. CO2 injections were controlled by a datalogger at fixed time intervals and in response to storm-induced changes in streamflow. Following the injection, differences in CO2 concentrations at known distances downstream from the diffuser relative to pre-injection baseline levels allowed us to calculate kCO2. Here we present relationships between kCO2 and hydro-geomorphologic (flow velocity, streambed slope, stream width, stream depth), atmospheric (wind speed and direction), and water quality (stream temperature, pH, electrical conductivity) variables. This method has advantages of being automatable and field-deployable, and it does not require supplemental gas chromatography, as is the case for propane injections typically used to determine k. The dataset presented suggests the potential role of this method to further elucidate the role that CO2 fluxes from headwater streams play in the global carbon cycle. Johnson, M. S., Billett, M. F

Using Stream Chemistry Measurements by Scientists and Nonscientists to Assess Leakage from Oil and Gas Wells in Pennsylvania

NASA Astrophysics Data System (ADS)

Brantley, S. L.; Wendt, A.; Sowers, T. A.

2016-12-01

The recent controversies concerning the role of hydraulic fracturing in impacting water quality in the United States document that decision-making must include both scientists and nonscientists. The most common water quality problem documented in Pennsylvania with respect to shale gas well development is the occasional migration of methane into private groundwater wells. Assessing the rate of migration is difficult and has led to controversial estimates. We explore the use of nonscientists in helping to collect data from streams for comparison to groundwater data collected by government and academic scientists. Stream waters in upland landscapes generally act as collectors for upwelling groundwater, including both natural and anthropogenic methane. Collection of stream water for methane analysis is simple and robust and can be completed by nonscientists throughout the state. We have discovered several locations in the state where new or legacy gas or oil wells are leaking methane into aquifers and into streams. Methane also seeps out of landfills and from natural sources. We present stream methane data from across the oil and gas development region in Pennsylvania, including sites of release of biogenic gas, natural thermogenic gas, legacy oil/gas well leakage, shale gas well leakage, and landfill leakage, and we assess the natural background of methane in stream water in the state. In some locations we compare methane in streams to methane in groundwater. As the state with the oldest oil wells in the U.S.A., Pennsylvania is a natural laboratory to understand not only the science of methane migration but also how to incorporate citizens into strategies to understand water quality impacts related to hydrocarbon development.

Removal of nitrogen oxides from gas streams by biofiltration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barrett, K.B.; Barnes, J.M.; Apel, W.A.

1994-12-31

Nitrogen oxides (NO{sub x}) are primary air pollutants and, as such, there is considerable interest in the development of efficient, cost effective technologies to remediate NO{sub x} containing emissions. Biofiltration involves the venting of contaminated gas streams through biologically active material such as soil or compost. This technology has been used successfully to control odors as well as volatile organic compounds from a variety of industrial and public sources. The purpose of this study was to evaluate the feasibility of using biofiltration to convert NO{sub x} to nitrogen gas.

Cleanups in My Community

EPA Pesticide Factsheets

Cleanups In My Community is a web app of hazardous waste cleanups for which EPA collects information, on maps and in lists, and to access additional information about those cleanups. This page describes and links to the application.

Continuous analysis of nitrogen dioxide in gas streams of plants

NASA Technical Reports Server (NTRS)

Durkin, W. T.; Kispert, R. C.

1969-01-01

Analyzer and sampling system continuously monitors nitrogen dioxide concentrations in the feed and tail gas streams of a facility recovering nitric acid. The system, using a direct calorimetric approach, makes use of readily available equipment and is flexible and reliable in operation.

U-PLANT GEOGRAPHIC ZONE CLEANUP PROTOTYPE

DOE Office of Scientific and Technical Information (OSTI.GOV)

ROMINE, L.D.

2006-02-01

The U Plant geographic zone (UPZ) occupies 0.83 square kilometers on the Hanford Site Central Plateau (200 Area). It encompasses the U Plant canyon (221-U Facility), ancillary facilities that supported the canyon, soil waste sites, and underground pipelines. The UPZ cleanup initiative coordinates the cleanup of the major facilities, ancillary facilities, waste sites, and contaminated pipelines (collectively identified as ''cleanup items'') within the geographic zone. The UPZ was selected as a geographic cleanup zone prototype for resolving regulatory, technical, and stakeholder issues and demonstrating cleanup methods for several reasons: most of the area is inactive, sufficient characterization information is availablemore » to support decisions, cleanup of the high-risk waste sites will help protect the groundwater, and the zone contains a representative cross-section of the types of cleanup actions that will be required in other geographic zones. The UPZ cleanup demonstrates the first of 22 integrated zone cleanup actions on the Hanford Site Central Plateau to address threats to groundwater, the environment, and human health. The UPZ contains more than 100 individual cleanup items. Cleanup actions in the zone will be undertaken using multiple regulatory processes and decision documents. Cleanup actions will include building demolition, waste site and pipeline excavation, and the construction of multiple, large engineered barriers. In some cases, different cleanup actions may be taken at item locations that are immediately adjacent to each other. The cleanup planning and field activities for each cleanup item must be undertaken in a coordinated and cohesive manner to ensure effective execution of the UPZ cleanup initiative. The UPZ zone cleanup implementation plan (ZCIP) was developed to address the need for a fundamental integration tool for UPZ cleanup. As UPZ cleanup planning and implementation moves forward, the ZCIP is intended to be a living document that

Cleanup/stimulation of a horizontal wellbore using propellants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rougeot, J.E.; Lauterbach, K.A.

1993-01-01

This report documents the stimulation/cleanup of a horizontal well bore (Wilson 25) using propellants. The Wilson 25 is a Bartlesville Sand well located in the Flatrock Field, Osage County, Oklahoma. The Wilson 25 was drilled to determine if horizontal drilling could be used as a means to economically recover primary oil that had been left in place in a mostly abandoned oil field because of the adverse effects of water coning. Pump testing of the Wilson 25 horizontal well bore before cleanup or stimulation produced 6 barrels of oil and .84 barrels of water per day. The high percentage ofmore » daily oil production to total daily fluid production indicated that the horizontal well bore had accessed potentially economical oil reserves if the fluid production rate could be increased by performing a cleanup/stimulation treatment. Propellants were selected as an inexpensive means to stimulate and cleanup the near well bore area in a uniform manner. The ignition of a propellant creates a large volume of gas which penetrates the formation, creating numerous short cracks through which hydrocarbons can travel into the well bore. More conventional stimulation/cleanup techniques were either significantly more expensive, less likely to treat uniformly, or could not be confined to the near well bore area. Three different propellant torpedo designs were tested with a total of 304' of horizontal well bore being shot and producible. The initial test shot caused 400' of the horizontal well bore to become plugged off, and subsequently it could not be production tested. The second and third test shots were production tested, with the oil production being increased 458% and 349%, respectively, on a per foot basis. The Wilson 25 results indicate that a propellant shot treatment is an economically viable means to cleanup/stimulate a horizontal well bore.« less

Regenerable sorbents for CO.sub.2 capture from moderate and high temperature gas streams

DOEpatents

Siriwardane, Ranjani V [Morgantown, WV

2008-01-01

A process for making a granular sorbent to capture carbon dioxide from gas streams comprising homogeneously mixing an alkali metal oxide, alkali metal hydroxide, alkaline earth metal oxide, alkaline earth metal hydroxide, alkali titanate, alkali zirconate, alkali silicate and combinations thereof with a binder selected from the group consisting of sodium ortho silicate, calcium sulfate dihydrate (CaSO.sub.4.2H.sub.2O), alkali silicates, calcium aluminate, bentonite, inorganic clays and organic clays and combinations thereof and water; drying the mixture and placing the sorbent in a container permeable to a gas stream.

Cleanups in My Community

EPA Pesticide Factsheets

Cleanups in My Community (CIMC) is a public web application that enables integrated access through maps, lists and search filtering to site-specific information EPA has across all cleanup programs. CIMC taps into data publicly available from EPA's EnviroFacts (RCRA Corrective Action facilities, Brownfields properties and grant areas, Superfund NPL sites, other facility data) and web services (water monitoring stations, impaired waters, emergency responses, tribal boundaries, congressional districts, etc.) and connects to other applications (e.g., Superfund's CPAD) to provide easy seamless access to site-specific cleanup information with explanatory text and within the context of related data. Data can be filtered by cleanup program, geography, environmental indicators, controls, and cleanup stage. CIMC also provides some web services that integrate these data for others to use in their applications.

Warm Cleanup of Coal-Derived Syngas: Multicontaminant Removal Process Demonstration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spies, Kurt A.; Rainbolt, James E.; Li, Xiaohong S.

Warm cleanup of coal- or biomass-derived syngas requires sorbent and catalytic beds to protect downstream processes and catalysts from fouling. Sulfur is particularly harmful because even parts-per-million amounts are sufficient to poison downstream synthesis catalysts. Zinc oxide (ZnO) is a conventional sorbent for sulfur removal; however, its operational performance using real gasifier-derived syngas and in an integrated warm cleanup process is not well reported. In this paper, we report the optimal temperature for bulk desulfurization to be 450oC, while removal of sulfur to parts-per-billion levels requires a lower temperature of approximately 350oC. Under these conditions, we found that sulfur inmore » the form of both hydrogen sulfide and carbonyl sulfide could be absorbed equally well using ZnO. For long-term operation, sorbent regeneration is desirable to minimize process costs. Over the course of five sulfidation and regeneration cycles, a ZnO bed lost about a third of its initial sulfur capacity, however sorbent capacity stabilized. Here, we also demonstrate, at the bench-scale, a process and materials used for warm cleanup of coal-derived syngas using five operations: 1) Na2CO3 for HCl removal, 2) regenerable ZnO beds for bulk sulfur removal, 3) a second ZnO bed for trace sulfur removal, 4) a Ni-Cu/C sorbent for multi-contaminant inorganic removal, and 5) a Ir-Ni/MgAl2O4 catalyst employed for ammonia decomposition and tar and light hydrocarbon steam reforming. Syngas cleanup was demonstrated through successful long-term performance of a poison-sensitive, Cu-based, water-gas-shift catalyst placed downstream of the cleanup process train. The tar reformer is an important and necessary operation with this particular gasification system; its inclusion was the difference between deactivating the water-gas catalyst with carbon deposition and successful 100-hour testing using 1 LPM of coal-derived syngas.« less

Cleanups in My Community Data

EPA Pesticide Factsheets

Cleanups in My Community (CIMC) enables you to map and list hazardous waste cleanup locations and grant areas, and drill down to details about those cleanups and grants and other, related information.

Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream

DOEpatents

Kromer, Brian R.; Litwin, Michael M.; Kelly, Sean M.

2016-09-27

A method and system for generating electrical power in which a high pressure synthesis gas stream generated in a gasifier is partially oxidized in an oxygen transport membrane based reactor, expanded and thereafter, is combusted in an oxygen transport membrane based boiler. A low pressure synthesis gas slip stream is split off downstream of the expanders and used as the source of fuel in the oxygen transport membrane based partial oxidation reactors to allow the oxygen transport membrane to operate at low fuel pressures with high fuel utilization. The combustion within the boiler generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.

Effect of Fourier transform on the streaming in quantum lattice gas algorithms

NASA Astrophysics Data System (ADS)

Oganesov, Armen; Vahala, George; Vahala, Linda; Soe, Min

2018-04-01

All our previous quantum lattice gas algorithms for nonlinear physics have approximated the kinetic energy operator by streaming sequences to neighboring lattice sites. Here, the kinetic energy can be treated to all orders by Fourier transforming the kinetic energy operator with interlaced Dirac-based unitary collision operators. Benchmarking against exact solutions for the 1D nonlinear Schrodinger equation shows an extended range of parameters (soliton speeds and amplitudes) over the Dirac-based near-lattice-site streaming quantum algorithm.

Analysis of trace contaminants in hot gas streams using time-weighted average solid-phase microextraction: proof of concept.

PubMed

Woolcock, Patrick J; Koziel, Jacek A; Cai, Lingshuang; Johnston, Patrick A; Brown, Robert C

2013-03-15

Time-weighted average (TWA) passive sampling using solid-phase microextraction (SPME) and gas chromatography was investigated as a new method of collecting, identifying and quantifying contaminants in process gas streams. Unlike previous TWA-SPME techniques using the retracted fiber configuration (fiber within needle) to monitor ambient conditions or relatively stagnant gases, this method was developed for fast-moving process gas streams at temperatures approaching 300 °C. The goal was to develop a consistent and reliable method of analyzing low concentrations of contaminants in hot gas streams without performing time-consuming exhaustive extraction with a slipstream. This work in particular aims to quantify trace tar compounds found in a syngas stream generated from biomass gasification. This paper evaluates the concept of retracted SPME at high temperatures by testing the three essential requirements for TWA passive sampling: (1) zero-sink assumption, (2) consistent and reliable response by the sampling device to changing concentrations, and (3) equal concentrations in the bulk gas stream relative to the face of the fiber syringe opening. Results indicated the method can accurately predict gas stream concentrations at elevated temperatures. Evidence was also discovered to validate the existence of a second boundary layer within the fiber during the adsorption/absorption process. This limits the technique to operating within reasonable mass loadings and loading rates, established by appropriate sampling depths and times for concentrations of interest. A limit of quantification for the benzene model tar system was estimated at 0.02 g m(-3) (8 ppm) with a limit of detection of 0.5 mg m(-3) (200 ppb). Using the appropriate conditions, the technique was applied to a pilot-scale fluidized-bed gasifier to verify its feasibility. Results from this test were in good agreement with literature and prior pilot plant operation, indicating the new method can measure low

Process for CO.sub.2 capture using zeolites from high pressure and moderate temperature gas streams

DOEpatents

Siriwardane, Ranjani V [Morgantown, WV; Stevens, Robert W [Morgantown, WV

2012-03-06

A method for separating CO.sub.2 from a gas stream comprised of CO.sub.2 and other gaseous constituents using a zeolite sorbent in a swing-adsorption process, producing a high temperature CO.sub.2 stream at a higher CO.sub.2 pressure than the input gas stream. The method utilizes CO.sub.2 desorption in a CO.sub.2 atmosphere and effectively integrates heat transfers for optimizes overall efficiency. H.sub.2O adsorption does not preclude effective operation of the sorbent. The cycle may be incorporated in an IGCC for efficient pre-combustion CO.sub.2 capture. A particular application operates on shifted syngas at a temperature exceeding 200.degree. C. and produces a dry CO.sub.2 stream at low temperature and high CO.sub.2 pressure, greatly reducing any compression energy requirements which may be subsequently required.

Acoustic observations of gas bubble streams in the NW Black Sea as a method for estimation of gas flux from vent sites

NASA Astrophysics Data System (ADS)

Artemov, Yu. G.

2003-04-01

Relatively recent discovery of the natural CH_4 gas seepage from the sea bed had action upon the philosophy of CH_4 contribution to global budgets. So far as numerous gas vent sites are known, an acceptable method for released gas quantification is required. In particular, the questions should be answered as follows: 1) how much amount of gas comes into the water column due to a certain bubble stream, 2) how much amount of gas comes into the water column due to a certain seepage area of the see floor, 3) how much amount of gas diffuses into the water and how much gas phase enters the atmosphere. Echo-sounder is the habitual equipment for detecting gas plumes (flares) in the water column. To provide observations of gas seeps with bubbles tracking, single target and volume backscattering strength measurements, we use installed on board the R/V "Professor Vodyanitskiy" dual frequency (38 and 120 kHz) split-beam scientific echo-sounder SIMRAD EK-500. Dedicated software is developed to extract from the raw echo data and to handle the definite information for analyses of gas bubble streams features. This improved hydroacoustic techniques allows to determine gas bubbles size spectrum at different depths through the water column as well as rise velocity of bubbles of different sizes. For instance, bubble of 4.5 mm diameter has rising speed of 25.8 cm/sec at 105 m depth, while bubble of 1.7 mm diameter has rising speed of 16.3 cm/sec at 32 m depth. Using volume backscattering measurements in addition, it is possible to evaluate flux of the gas phase produced by methane bubble streams and to learn of its fate in the water column. Ranking of various gas plumes by flux rate value is available also. In this presentation results of acoustic observations at the shallow NW Black Sea seepage area are given.

Cleanup/stimulation of a horizontal wellbore using propellants. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rougeot, J.E.; Lauterbach, K.A.

1993-01-01

This report documents the stimulation/cleanup of a horizontal well bore (Wilson 25) using propellants. The Wilson 25 is a Bartlesville Sand well located in the Flatrock Field, Osage County, Oklahoma. The Wilson 25 was drilled to determine if horizontal drilling could be used as a means to economically recover primary oil that had been left in place in a mostly abandoned oil field because of the adverse effects of water coning. Pump testing of the Wilson 25 horizontal well bore before cleanup or stimulation produced 6 barrels of oil and .84 barrels of water per day. The high percentage ofmore » daily oil production to total daily fluid production indicated that the horizontal well bore had accessed potentially economical oil reserves if the fluid production rate could be increased by performing a cleanup/stimulation treatment. Propellants were selected as an inexpensive means to stimulate and cleanup the near well bore area in a uniform manner. The ignition of a propellant creates a large volume of gas which penetrates the formation, creating numerous short cracks through which hydrocarbons can travel into the well bore. More conventional stimulation/cleanup techniques were either significantly more expensive, less likely to treat uniformly, or could not be confined to the near well bore area. Three different propellant torpedo designs were tested with a total of 304` of horizontal well bore being shot and producible. The initial test shot caused 400` of the horizontal well bore to become plugged off, and subsequently it could not be production tested. The second and third test shots were production tested, with the oil production being increased 458% and 349%, respectively, on a per foot basis. The Wilson 25 results indicate that a propellant shot treatment is an economically viable means to cleanup/stimulate a horizontal well bore.« less

The role of penetrating gas streams in setting the dynamical state of galaxy clusters

NASA Astrophysics Data System (ADS)

Zinger, E.; Dekel, A.; Birnboim, Y.; Kravtsov, A.; Nagai, D.

2016-09-01

We utilize cosmological simulations of 16 galaxy clusters at redshifts z = 0 and z = 0.6 to study the effect of inflowing streams on the properties of the X-ray emitting intracluster medium. We find that the mass accretion occurs predominantly along streams that originate from the cosmic web and consist of heated gas. Clusters that are unrelaxed in terms of their X-ray morphology are characterized by higher mass inflow rates and deeper penetration of the streams, typically into the inner third of the virial radius. The penetrating streams generate elevated random motions, bulk flows and cold fronts. The degree of penetration of the streams may change over time such that clusters can switch from being unrelaxed to relaxed over a time-scale of several giga years.

US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dennis, R.A.

1997-05-01

The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systemsmore » has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.« less

Springs, streams, and gas vent on and near Mount Adams volcano, Washington

USGS Publications Warehouse

Nathenson, Manuel; Mariner, Robert H.

2013-01-01

Springs and some streams on Mount Adams volcano have been sampled for chemistry and light stable isotopes of water. Spring temperatures are generally cooler than air temperatures from weather stations at the same elevation. Spring chemistry generally reflects weathering of volcanic rock from dissolved carbon dioxide. Water in some springs and streams has either dissolved hydrothermal minerals or has reacted with them to add sulfate to the water. Some samples appear to have obtained their sulfate from dissolution of gypsum while some probably involve reaction with sulfide minerals such as pyrite. Light stable isotope data for water from springs follow a local meteoric water line, and the variation of isotopes with elevation indicate that some springs have very local recharge and others have water from elevations a few hundred meters higher. No evidence was found for thermal or slightly thermal springs on Mount Adams. A sample from a seeping gas vent on Mount Adams was at ambient temperature, but the gas is similar to that found on other Cascade volcanoes. Helium isotopes are 4.4 times the value in air, indicating that there is a significant component of mantle helium. The lack of fumaroles on Mount Adams and the ambient temperature of the gas indicates that the gas is from a hydrothermal system that is no longer active.

Interaction of a liquid jet with an oncoming gas stream

NASA Astrophysics Data System (ADS)

Koval', M. A.; Shvets, A. I.

1987-06-01

Wind-tunnel tests were carried out to study the interaction between water jets issuing from various types of nozzles (including cylindrical) and subsonic and supersonic air streams with Mach numbers from 0.3 to 3 and Reynolds numbers from 1 x 10 to the 6th to 3 x 10 to the 7th. The following interaction structure was observed: (1) at moderate outflow velocities, the liquid jet has an extended region, which subsequently expands abruptly as a spherical or mushroom-shaped drop; (2) this drop is atomized in the peripheral region and is carried away as a gas-liquid mixture; (3) a shock wave is formed in front of the jet in the oncoming supersonic stream; and (4) a separated flow region is present in the vicinity of the cylindrical nozzle section.

Silver-mordenite for radiologic gas capture from complex streams. Dual catalytic CH 3I decomposition and I confinement

DOE PAGES

Nenoff, Tina M.; Rodriguez, Mark A.; Soelberg, Nick R.; ...

2014-05-09

The selective capture of radiological iodine ( 129I) is a persistent concern for safe nuclear energy. In these nuclear fuel reprocessing scenarios, the gas streams to be treated are extremely complex, containing several distinct iodine-containing molecules amongst a large variety of other species. Silver-containing mordenite (MOR) is a longstanding benchmark for radioiodine capture, reacting with molecular iodine (I 2) to form AgI. However the mechanisms for organoiodine capture is not well understood. Here we investigate the capture of methyl iodide from complex mixed gas streams by combining chemical analysis of the effluent gas stream with in depth characterization of themore » recovered sorbent. Tools applied include infrared spectroscopy, thermogravimetric analysis with mass spectrometry, micro X-ray fluorescence, powder X-ray diffraction analysis, and pair distribution function analysis. Moreover, the MOR zeolite catalyzes decomposition of the methyl iodide through formation of surface methoxy species (SMS), which subsequently reacts with water in the mixed gas stream to form methanol, and with methanol to form dimethyl ether, which are both detected downstream in the effluent. The liberated iodine reacts with Ag in the MOR pore to the form subnanometer AgI clusters, smaller than the MOR pores, suggesting that the iodine is both physically and chemically confined within the zeolite.« less

Method and apparatus for transport, introduction, atomization and excitation of emission spectrum for quantitative analysis of high temperature gas sample streams containing vapor and particulates without degradation of sample stream temperature

DOEpatents

Eckels, David E.; Hass, William J.

1989-05-30

A sample transport, sample introduction, and flame excitation system for spectrometric analysis of high temperature gas streams which eliminates degradation of the sample stream by condensation losses.

Extracorporeal gas exchange with the DeltaStream rotary blood pump in experimental lung injury.

PubMed

Dembinski, Rolf; Kopp, Rüdger; Henzler, Dietrich; Hochhausen, Nadine; Oslender, Nicole; Max, Martin; Rossaint, Rolf; Kuhlen, Ralf

2003-06-01

In most severe cases of the acute respiratory distress syndrome, veno-venous extracorporeal membrane oxygenation (ECMO) can be used to facilitate gas exchange. However, the clinical use is limited due to the size and the concomitant risk of severe adverse events of conventionally-used centrifugal blood pumps with high extracorporeal blood volumes. The DeltaStream blood pump is a small-sized rotary blood pump that may reduce extracorporeal blood volume, foreign surfaces, contact activation of the coagulation system, and blood trauma. The aim of the present study was to test the safety and efficacy of the DeltaStream pump for ECMO in animals with normal lung function and experimental acute lung injury (ALI). Therefore, veno-venous ECMO was performed for 6 hours in mechanically ventilated pigs with normal lung function (n=6) and with ALI induced by repeated lung lavage (n=6) with a blood flow of 30% of the cardiac output. Gas flow with a FiO2 of 1.0 was set to equal blood flow. With a mean activated clotting time of 121 +/- 22 s, no circulatory impairment or thrombus formation was revealed during ECMO. Furthermore, free plasma Hb did not increase. In controls, hemodynamics and gas exchange remained unchanged. In animals with ALI, hemodynamics remained stable and gas transfer across the extracorporeal oxygenators was optimal, but only in 2 animals was a marked increase in PaO2 observed. CO2 removal was efficacious in all animals. We concluded that the DeltaStream blood pump may be used for veno-venous ECMO without major blood damage or hemodynamic impairment.

Source limitation of carbon gas emissions in high-elevation mountain streams and lakes

USGS Publications Warehouse

Crawford, John T.; Dornblaser, Mark M.; Stanley, Emily H.; Clow, David W.; Striegl, Robert G.

2015-01-01

Inland waters are an important component of the global carbon cycle through transport, storage, and direct emissions of CO2 and CH4 to the atmosphere. Despite predictions of high physical gas exchange rates due to turbulent flows and ubiquitous supersaturation of CO2—and perhaps also CH4—patterns of gas emissions are essentially undocumented for high mountain ecosystems. Much like other headwater networks around the globe, we found that high-elevation streams in Rocky Mountain National Park, USA, were supersaturated with CO2 during the growing season and were net sources to the atmosphere. CO2concentrations in lakes, on the other hand, tended to be less than atmospheric equilibrium during the open water season. CO2 and CH4 emissions from the aquatic conduit were relatively small compared to many parts of the globe. Irrespective of the physical template for high gas exchange (high k), we found evidence of CO2 source limitation to mountain streams during the growing season, which limits overall CO2emissions. Our results suggest a reduced importance of aquatic ecosystems for carbon cycling in high-elevation landscapes having limited soil development and high CO2 consumption via mineral weathering.

HANFORD SITE CENTRAL PLATEAU CLEANUP COMPLETION STRATEGY

DOE Office of Scientific and Technical Information (OSTI.GOV)

BERGMAN TB

2011-01-14

Cleanup of the Hanford Site is a complex and challenging undertaking. The U.S. Department of Energy (DOE) has developed a comprehensive vision for completing Hanford's cleanup mission including transition to post-cleanup activities. This vision includes 3 principle components of cleanup: the {approx}200 square miles ofland adjacent to the Columbia River, known as the River Corridor; the 75 square miles of land in the center of the Hanford Site, where the majority of the reprocessing and waste management activities have occurred, known as the Central Plateau; and the stored reprocessing wastes in the Central Plateau, the Tank Wastes. Cleanup of themore » River Corridor is well underway and is progressing towards completion of most cleanup actions by 2015. Tank waste cleanup is progressing on a longer schedule due to the complexity of the mission, with construction of the largest nuclear construction project in the United States, the Waste Treatment Plant, over 50% complete. With the progress on the River Corridor and Tank Waste, it is time to place increased emphasis on moving forward with cleanup of the Central Plateau. Cleanup of the Hanford Site has been proceeding under a framework defmed in the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). In early 2009, the DOE, the State of Washington Department of Ecology, and the U.S. Environmental Protection Agency signed an Agreement in Principle in which the parties recognized the need to develop a more comprehensive strategy for cleanup of the Central Plateau. DOE agreed to develop a Central Plateau Cleanup Completion Strategy as a starting point for discussions. This DOE Strategy was the basis for negotiations between the Parties, discussions with the State of Oregon, the Hanford Advisory Board, and other Stakeholder groups (including open public meetings), and consultation with the Tribal Nations. The change packages to incorporate the Central Plateau Cleanup Completion Strategy were

Reactor water cleanup system

DOEpatents

Gluntz, Douglas M.; Taft, William E.

1994-01-01

A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling.

Reactor water cleanup system

DOEpatents

Gluntz, D.M.; Taft, W.E.

1994-12-20

A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling. 1 figure.

Cleanups In My Community (CIMC) - Recovery Act Funded Cleanups, National Layer

EPA Pesticide Factsheets

This data layer provides access to Recovery Act Funded Cleanup sites as part of the CIMC web service. The American Recovery and Reinvestment Act was signed into law by President Obama on February 17th, 2009 and all reporting on ARRA for these 3 programs was complete as of 2013. Out of the five EPA programs that distributed recovery act funding, three of them were cleanup programs: Brownfields, Superfund and Leaking Underground Storage Tanks. CIMC provides information on site cleanups that received ARRA Recovery Act funding for Superfund and Brownfields, but not Leaking Underground Storage Tanks. Data for Brownfields came from the ACRES database. Data for Superfund came from the Comprehensive Environmental Response, Compensation, and Liability Information System (CERCLIS) database. Data in CIMC no longer need to be updated for the ARRA program. For information on all EPA Recovery Act funded work, please see: http://archive.epa.gov/recovery/web/html/ and http://epamap17.epa.gov/arra/.

Vertical gas injection into liquid cross-stream beneath horizontal surfaces

NASA Astrophysics Data System (ADS)

Lee, In-Ho; Makiharju, Simo; Lee, Inwon; Perlin, Marc; Ceccio, Steve

2013-11-01

Skin friction drag reduction on flat bottomed ships and barges can be achieved by creating an air layer immediately beneath the horizontal surface. The simplest way of introducing the gas is through circular orifices; however the dynamics of gas injection into liquid cross-streams under horizontal surfaces is not well understood. Experiments were conducted to investigate the development of the gas topology following its vertical injection through a horizontal surface. The liquid cross-flow, orifice diameter and gas flow rate were varied to investigate the effect of different ratios of momentum fluxes. The testing was performed on a 4.3 m long and 0.73 m wide barge model with air injection through a hole in the transparent bottom hull. The incoming boundary layer was measured via a pitot tube. Downstream distance based Reynolds number at the injection location was 5 × 105 through 4 × 106 . To observe the flow topology, still images and video were recorded from above the model (i.e. through the transparent hull), from beneath the bottom facing upward, and from the side at an oblique angle. The transition point of the flow topology was determined and analyzed.

Hazardous Waste: Cleanup and Prevention.

ERIC Educational Resources Information Center

Vandas, Steve; Cronin, Nancy L.

1996-01-01

Discusses hazardous waste, waste disposal, unsafe exposure, movement of hazardous waste, and the Superfund clean-up process that consists of site discovery, site assessment, clean-up method selection, site clean up, and site maintenance. Argues that proper disposal of hazardous waste is everybody's responsibility. (JRH)

Removal of I, Rn, Xe and Kr from off gas streams using PTFE membranes

DOEpatents

Siemer, Darryl D.; Lewis, Leroy C.

1990-01-01

A process for removing I, R, Xe and Kr which involves the passage of the off gas stream through a tube-in-shell assembly, whereby the tubing is a PTFE membrane which permits the selective passages of the gases for removing and isolating the gases.

Removal of I, Rn, Xe and Kr from off gas streams using PTFE membranes

DOEpatents

Siemer, Darryl D.; Lewis, Leroy C.

1990-08-07

A process for removing I, R, Xe and Kr which involves the passage of the off gas stream through a tube-in-shell assembly, whereby the tubing is a PTFE membrane which permits the selective passages of the gases for removing and isolating the gases.

SUPERFUND CLEANUPS AND INFANT HEALTH

PubMed Central

Currie, Janet; Greenstone, Michael; Moretti, Enrico

2013-01-01

We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989–2003 in five large states. Our “difference in differences” approach compares birth outcomes before and after a site clean-up for mothers who live within 2,000 meters of the site and those who live between 2,000– 5,000 meters of a site. We find that proximity to a Superfund site before cleanup is associated with a 20 to 25% increase in the risk of congenital anomalies. PMID:25152535

SUPERFUND CLEANUPS AND INFANT HEALTH.

PubMed

Currie, Janet; Greenstone, Michael; Moretti, Enrico

2011-05-01

We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989-2003 in five large states. Our "difference in differences" approach compares birth outcomes before and after a site clean-up for mothers who live within 2,000 meters of the site and those who live between 2,000- 5,000 meters of a site. We find that proximity to a Superfund site before cleanup is associated with a 20 to 25% increase in the risk of congenital anomalies.

Assessing sorbent injection mercury control effectiveness in flue gas streams

USGS Publications Warehouse

Carey, T.R.; Richardson, C.F.; Chang, R.; Meserole, F.B.; Rostam-Abadi, M.; Chen, S.

2000-01-01

One promising approach for removing mercury from coal-fired, utility flue gas involves the direct injection of mercury sorbents. Although this method has been effective at removing mercury in municipal waste incinerators, tests conducted to date on utility coal-fired boilers show that mercury removal is much more difficult in utility flue gas. EPRI is conducting research to investigate mercury removal using sorbents in this application. Bench-scale, pilot-scale, and field tests have been conducted to determine the ability of different sorbents to remove mercury in simulated and actual flue gas streams. This paper focuses on recent bench-scale and field test results evaluating the adsorption characteristics of activated carbon and fly ash and the use of these results to develop a predictive mercury removal model. Field tests with activated carbon show that adsorption characteristics measured in the lab agree reasonably well with characteristics measured in the field. However, more laboratory and field data will be needed to identify other gas phase components which may impact performance. This will allow laboratory tests to better simulate field conditions and provide improved estimates of sorbent performance for specific sites. In addition to activated carbon results, bench-scale and modeling results using fly ash are presented which suggest that certain fly ashes are capable of adsorbing mercury.

The preparation of calcium superoxide in a flowing gas stream and fluidized bed

NASA Technical Reports Server (NTRS)

Wood, P. C.; Ballou, E. V.; Spitze, L. A.; Wydeven, T.

1980-01-01

Superoxides can be used as sources of chemically stored oxygen in emergency breathing apparatus. The work reported here describes the use of a low-pressure nitrogen gas sweep through the reactant bed, for temperature control and water vapor removal. For a given set of gas temperature, bed thickness, and reaction time values, the highest purity calcium superoxide, Ca(O2)2, was obtained at the highest space velocity of the nitrogen gas sweep. The purity of the product was further increased by flow conditions that resulted in the fluidization of the reactant bed. However, scale-up of the low-pressure fluidized bed process was limited to the formation of agglomerates of reactant particles, which hindered thermal control by the flowing gas stream. A radiofrequency flow discharge inside the reaction chamber prevented agglomeration, presumably by dissipation of the static charges on the fluidized particles.

Selective catalytic reduction system and process for control of NO.sub.x emissions in a sulfur-containing gas stream

DOEpatents

Sobolevskiy, Anatoly

2015-08-11

An exhaust gas treatment process, apparatus, and system for reducing the concentration of NOx, CO and hydrocarbons in a gas stream, such as an exhaust stream (29), via selective catalytic reduction with ammonia is provided. The process, apparatus and system include a catalytic bed (32) having a reducing only catalyst portion (34) and a downstream reducing-plus-oxidizing portion (36). Each portion (34, 36) includes an amount of tungsten. The reducing-plus-oxidizing catalyst portion (36) advantageously includes a greater amount of tungsten than the reducing catalyst portion (36) to markedly limit ammonia salt formation.

Texas Coastal Cleanup Report, 1986.

ERIC Educational Resources Information Center

O'Hara, Kathryn; And Others

During the 1986 Coastweek, a national event dedicated to improvement of the marine environment, a large beach cleanup was organized on the Texas coast. The goals of the cleanup were to create public awareness of the problems caused by marine debris, and to collect data on the types and quantities of debris found on the Texas coastline. The…

Cryogenic treatment of gas

DOEpatents

Bravo, Jose Luis [Houston, TX; Harvey, III, Albert Destrehan; Vinegar, Harold J [Bellaire, TX

2012-04-03

Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

Fast-Track Cleanup at Closing DoD Installations

EPA Pesticide Factsheets

The Fast-Track Cleanup program strives to make parcels available for reuse as quickly as possible by the transfer of uncontaminated or remediated parcels, the lease of contaminated parcels where cleanup is underway, or the 'early transfer' of contaminated property undergoing cleanup.

Recovery of ammonia and production of high-grade phosphates from side-stream digester effluents using gas-permeable membranes

USDA-ARS?s Scientific Manuscript database

Phosphorus recovery was combined with ammonia recovery using gas-permeable membranes. In a first step, the ammonia and alkalinity were removed from municipal side-stream wastewater using low-rate aeration and a gas-permeable membrane manifold. In a second step, the phosphorus was removed using magne...

Tephra fall clean-up in urban environments

NASA Astrophysics Data System (ADS)

Hayes, Josh L.; Wilson, Thomas M.; Magill, Christina

2015-10-01

Tephra falls impact urban communities by disrupting transport systems, contaminating and damaging buildings and infrastructures, and are potentially hazardous to human health. Therefore, prompt and effective tephra clean-up measures are an essential component of an urban community's response to tephra fall. This paper reviews case studies of tephra clean-up operations in urban environments around the world, spanning 50 years. It identifies methods used in tephra clean-up and assesses a range of empirical relationships between level of tephra accumulation and clean-up metrics such as collected tephra volume, costs, and duration of operations. Results indicate the volume of tephra collected from urban areas is proportional to tephra accumulation. Urban areas with small tephra accumulations (1,000 m3/km2 or an average of 1 mm thickness) may collect < 1% of the total deposit, whereas urban areas which experience large accumulations (> 50,000 m3/km2 or an average of 50 mm thickness) remove up to 80%. This relationship can inform impact and risk assessments by providing an estimate of the likely response required for a given tephra fall. No strong relationship was found between tephra fall accumulation and clean-up cost or duration for urban environments which received one-off tephra falls, suggesting that these aspects of tephra fall clean-up operations are context specific. Importantly, this study highlights the advantage of effective planning for tephra clean-up and disposal in potentially exposed areas.

Method For Enhanced Gas Monitoring In High Density Flow Streams

DOEpatents

Von Drasek, William A.; Mulderink, Kenneth A.; Marin, Ovidiu

2005-09-13

A method for conducting laser absorption measurements in high temperature process streams having high levels of particulate matter is disclosed. An impinger is positioned substantially parallel to a laser beam propagation path and at upstream position relative to the laser beam. Beam shielding pipes shield the beam from the surrounding environment. Measurement is conducted only in the gap between the two shielding pipes where the beam propagates through the process gas. The impinger facilitates reduced particle presence in the measurement beam, resulting in improved SNR (signal-to-noise) and improved sensitivity and dynamic range of the measurement.

Rediscovering a Stream in Danville, Kentucky: The Clark Run Corridor and Trails Project.

ERIC Educational Resources Information Center

Bright, Debra

1998-01-01

In Danville, Kentucky, the community cooperated in converting a neglected stream into a walking trail and park network, resulting in increased community pride, environmental awareness, community revitalization, and public-private cooperation. The local middle school regularly tests the water, and the local college's annual clean-up party earned an…

Spatial and temporal variability in greenhouse gas abundance of urban streams: The role of urban infrastructure

EPA Science Inventory

Background/Question/MethodsStreams and rivers are significant sources of greenhouse gas emissions globally. Water quality and watershed management, are likely to influence GHG emissions regionally. In urban-impacted watersheds, increased nitrogen loading, organic matter, and war...

High-Temperature Desulfurization of Heavy Fuel-Derived Reformate Gas Streams for SOFC Applications

NASA Technical Reports Server (NTRS)

Flytzani-Stephanopoulos, Maria; Surgenor, Angela D.

2007-01-01

Desulfurization of the hot reformate gas produced by catalytic partial oxidation or autothermal reforming of heavy fuels, such as JP-8 and jet fuels, is required prior to using the gas in a solid oxide fuel cell (SOFC). Development of suitable sorbent materials involves the identification of sorbents with favorable sulfidation equilibria, good kinetics, and high structural stability and regenerability at the SOFC operating temperatures (650 to 800 C). Over the last two decades, a major barrier to the development of regenerable desulfurization sorbents has been the gradual loss of sorbent performance in cyclic sulfidation and regeneration at such high temperatures. Mixed oxide compositions based on ceria were examined in this work as regenerable sorbents in simulated reformate gas mixtures and temperatures greater than 650 C. Regeneration was carried out with dilute oxygen streams. We have shown that under oxidative regeneration conditions, high regeneration space velocities (greater than 80,000 h(sup -1)) can be used to suppress sulfate formation and shorten the total time required for sorbent regeneration. A major finding of this work is that the surface of ceria and lanthanan sorbents can be sulfided and regenerated completely, independent of the underlying bulk sorbent. This is due to reversible adsorption of H2S on the surface of these sorbents even at temperatures as high as 800 C. La-rich cerium oxide formulations are excellent for application to regenerative H2S removal from reformate gas streams at 650 to 800 C. These results create new opportunities for compact sorber/regenerator reactor designs to meet the requirements of solid oxide fuel cell systems at any scale.

Effect of multi-stream heat exchanger on performance of natural gas liquefaction with mixed refrigerant

NASA Astrophysics Data System (ADS)

Chang, Ho-Myung; Lim, Hye Su; Choe, Kun Hyung

2012-12-01

A thermodynamic study is carried out to investigate the effect of multi-stream heat exchanger on the performance of natural gas (NG) liquefaction with mixed refrigerant (MR). A cold stream (low-pressure MR) is in thermal contact with opposite flow of two hot streams (high-pressure MR and NG feed) at the same time. In typical process simulation with commercial software (such as Aspen HYSYS®), the liquefaction performance is estimated with a method of minimum temperature approach, simply assuming that two hot streams have the same temperature. In this study, local energy balance equations are rigorously solved with temperature-dependent properties of MR and NG feed, and are linked to the thermodynamic cycle analysis. The figure of merit (FOM) is quantitatively examined in terms of UA (the product of overall heat transfer coefficient and heat exchange area) between respective streams. In a single-stage MR process, it is concluded that the temperature profile from HYSYS is difficult to realize in practice, and the FOM value from HYSYS is an over-estimate, but can be closely achieved with a proper heat-exchanger design. It is also demonstrated that there exists a unique optimal ratio in three UA's, and no direct heat exchanger between hot streams is recommended.

Reduction of dioxin emission by a multi-layer reactor with bead-shaped activated carbon in simulated gas stream and real flue gas of a sinter plant.

PubMed

Hung, Pao Chen; Lo, Wei Chiao; Chi, Kai Hsien; Chang, Shu Hao; Chang, Moo Been

2011-01-01

A laboratory-scale multi-layer system was developed for the adsorption of PCDD/Fs from gas streams at various operating conditions, including gas flow rate, operating temperature and water vapor content. Excellent PCDD/F removal efficiency (>99.99%) was achieved with the multi-layer design with bead-shaped activated carbons (BACs). The PCDD/F removal efficiency achieved with the first layer adsorption bed decreased as the gas flow rate was increased due to the decrease of the gas retention time. The PCDD/F concentrations measured at the outlet of the third layer adsorption bed were all lower than 0.1 ng I-TEQ Nm⁻³. The PCDD/Fs desorbed from BAC were mainly lowly chlorinated congeners and the PCDD/F outlet concentrations increased as the operating temperature was increased. In addition, the results of pilot-scale experiment (real flue gases of an iron ore sintering plant) indicated that as the gas flow rate was controlled at 15 slpm, the removal efficiencies of PCDD/F congeners achieved with the multi-layer reactor with BAC were better than that in higher gas flow rate condition (20 slpm). Overall, the lab-scale and pilot-scale experiments indicated that PCDD/F removal achieved by multi-layer reactor with BAC strongly depended on the flow rate of the gas stream to be treated. Copyright © 2010 Elsevier Ltd. All rights reserved.

Automated Mini-Column Solid-Phase Extraction Cleanup for High-Throughput Analysis of Chemical Contaminants in Foods by Low-Pressure Gas Chromatography-Tandem Mass Spectrometry.

PubMed

Lehotay, Steven J; Han, Lijun; Sapozhnikova, Yelena

2016-01-01

This study demonstrated the application of an automated high-throughput mini-cartridge solid-phase extraction (mini-SPE) cleanup for the rapid low-pressure gas chromatography-tandem mass spectrometry (LPGC-MS/MS) analysis of pesticides and environmental contaminants in QuEChERS extracts of foods. Cleanup efficiencies and breakthrough volumes using different mini-SPE sorbents were compared using avocado, salmon, pork loin, and kale as representative matrices. Optimum extract load volume was 300 µL for the 45 mg mini-cartridges containing 20/12/12/1 (w/w/w/w) anh. MgSO 4 /PSA (primary secondary amine)/C 18 /CarbonX sorbents used in the final method. In method validation to demonstrate high-throughput capabilities and performance results, 230 spiked extracts of 10 different foods (apple, kiwi, carrot, kale, orange, black olive, wheat grain, dried basil, pork, and salmon) underwent automated mini-SPE cleanup and analysis over the course of 5 days. In all, 325 analyses for 54 pesticides and 43 environmental contaminants (3 analyzed together) were conducted using the 10 min LPGC-MS/MS method without changing the liner or retuning the instrument. Merely, 1 mg equivalent sample injected achieved <5 ng g -1 limits of quantification. With the use of internal standards, method validation results showed that 91 of the 94 analytes including pairs achieved satisfactory results (70-120 % recovery and RSD ≤ 25 %) in the 10 tested food matrices ( n  = 160). Matrix effects were typically less than ±20 %, mainly due to the use of analyte protectants, and minimal human review of software data processing was needed due to summation function integration of analyte peaks. This study demonstrated that the automated mini-SPE + LPGC-MS/MS method yielded accurate results in rugged, high-throughput operations with minimal labor and data review.

Demographic response of Louisiana Waterthrush, a stream obligate songbird of conservation concern, to shale gas development

USGS Publications Warehouse

Frantz, Mack W.; Wood, Petra B.; Sheehan, James; George, Gregory

2018-01-01

Shale gas development continues to outpace the implementation of best management practices for wildlife affected by development. We examined demographic responses of the Louisiana Waterthrush (Parkesia motacilla) to shale gas development during 2009–2011 and 2013–2015 in a predominantly forested landscape in West Virginia, USA. Forest cover across the study area decreased from 95% in 2008 to 91% in 2015, while the area affected by shale gas development increased from 0.4% to 3.9%. We quantified nest survival and productivity, a source–sink threshold, riparian habitat quality, territory density, and territory length by monitoring 58.1 km of forested headwater streams (n = 14 streams). Across years, we saw annual variability in nest survival, with a general declining trend over time. Of 11 a priori models tested to explain nest survival (n = 280 nests), 4 models that included temporal, habitat, and shale gas covariates were supported, and 2 of these models accounted for most of the variation in daily nest survival rate. After accounting for temporal effects (rainfall, nest age, and time within season), shale gas development had negative effects on nest survival. Population-level nest productivity declined and individual productivity was lower in areas disturbed by shale gas development than in undisturbed areas, and a source–sink threshold suggested that disturbed areas were more at risk of being sink habitat. Riparian habitat quality scores, as measured by a U.S. Environmental Protection Agency index and a waterthrush-specific habitat suitability index, differed by year and were negatively related to the amount of each territory disturbed by shale gas development. Territory density was not related to the amount of shale gas disturbance, but decreased over time as territory lengths increased. Overall, our results suggest a decline in waterthrush site quality as shale gas development increases, despite relatively small site-wide forest loss.

Stream vulnerability to widespread and emergent stressors: a focus on unconventional oil and gas

USGS Publications Warehouse

Entrekin, Sally; Maloney, Kelly O.; Katherine E. Kapo,; Walters, Annika W.; Evans-White, Michelle A.; Klemow, Kenneth M.

2015-01-01

Multiple stressors threaten stream physical and biological quality, including elevated nutrients and other contaminants, riparian and in-stream habitat degradation and altered natural flow regime. Unconventional oil and gas (UOG) development is one emerging stressor that spans the U.S. UOG development could alter stream sedimentation, riparian extent and composition, in-stream flow, and water quality. We developed indices to describe the watershed sensitivity and exposure to natural and anthropogenic disturbances and computed a vulnerability index from these two scores across stream catchments in six productive shale plays. We predicted that catchment vulnerability scores would vary across plays due to climatic, geologic and anthropogenic differences. Across-shale averages supported this prediction revealing differences in catchment sensitivity, exposure, and vulnerability scores that resulted from different natural and anthropogenic environmental conditions. For example, semi-arid Western shale play catchments (Mowry, Hilliard, and Bakken) tended to be more sensitive to stressors due to low annual average precipitation and extensive grassland. Catchments in the Barnett and Marcellus-Utica were naturally sensitive from more erosive soils and steeper catchment slopes, but these catchments also experienced areas with greater UOG densities and urbanization. Our analysis suggested Fayetteville and Barnett catchments were vulnerable due to existing anthropogenic exposure. However, all shale plays had catchments that spanned a wide vulnerability gradient. Our results identify vulnerable catchments that can help prioritize stream protection and monitoring efforts. Resource managers can also use these findings to guide local development activities to help reduce possible environmental effects.

Stream Vulnerability to Widespread and Emergent Stressors: A Focus on Unconventional Oil and Gas

PubMed Central

Entrekin, Sally A.; Maloney, Kelly O.; Kapo, Katherine E.; Walters, Annika W.; Evans-White, Michelle A.; Klemow, Kenneth M.

2015-01-01

Multiple stressors threaten stream physical and biological quality, including elevated nutrients and other contaminants, riparian and in-stream habitat degradation and altered natural flow regime. Unconventional oil and gas (UOG) development is one emerging stressor that spans the U.S. UOG development could alter stream sedimentation, riparian extent and composition, in-stream flow, and water quality. We developed indices to describe the watershed sensitivity and exposure to natural and anthropogenic disturbances and computed a vulnerability index from these two scores across stream catchments in six productive shale plays. We predicted that catchment vulnerability scores would vary across plays due to climatic, geologic and anthropogenic differences. Across-shale averages supported this prediction revealing differences in catchment sensitivity, exposure, and vulnerability scores that resulted from different natural and anthropogenic environmental conditions. For example, semi-arid Western shale play catchments (Mowry, Hilliard, and Bakken) tended to be more sensitive to stressors due to low annual average precipitation and extensive grassland. Catchments in the Barnett and Marcellus-Utica were naturally sensitive from more erosive soils and steeper catchment slopes, but these catchments also experienced areas with greater UOG densities and urbanization. Our analysis suggested Fayetteville and Barnett catchments were vulnerable due to existing anthropogenic exposure. However, all shale plays had catchments that spanned a wide vulnerability gradient. Our results identify vulnerable catchments that can help prioritize stream protection and monitoring efforts. Resource managers can also use these findings to guide local development activities to help reduce possible environmental effects. PMID:26397727

Central Plateau Cleanup at DOE's Hanford Site - 12504

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dowell, Jonathan

The discussion of Hanford's Central Plateau includes significant work in and around the center of the Hanford Site - located about 7 miles from the Columbia River. The Central Plateau is the area to which operations will be shrunk in 2015 when River Corridor cleanup is complete. This work includes retrieval and disposal of buried waste from miles of trenches; the cleanup and closure of massive processing canyons; the clean-out and demolition to 'slab on grade' of the high-hazard Plutonium Finishing Plant; installation of key groundwater treatment facilities to contain and shrink plumes of contaminated groundwater; demolition of all othermore » unneeded facilities; and the completion of decisions about remaining Central Plateau waste sites. A stated goal of EM has been to shrink the footprint of active cleanup to less than 10 square miles by 2020. By the end of FY2011, Hanford will have reduced the active footprint of cleanup by 64 percent exceeding the goal of 49 percent. By 2015, Hanford will reduce the active footprint of cleanup by more than 90 percent. The remaining footprint reduction will occur between 2015 and 2020. The Central Plateau is a 75-square-mile region near the center of the Hanford Site including the area designated in the Hanford Comprehensive Land Use Plan Environmental Impact Statement (DOE 1999) and Record of Decision (64 FR 61615) as the Industrial-Exclusive Area, a rectangular area of about 20 square miles in the center of the Central Plateau. The Industrial-Exclusive Area contains the 200 East and 200 West Areas that have been used primarily for Hanford's nuclear fuel processing and waste management and disposal activities. The Central Plateau also encompasses the 200 Area CERCLA National Priorities List site. The Central Plateau has a large physical inventory of chemical processing and support facilities, tank systems, liquid and solid waste disposal and storage facilities, utility systems, administrative facilities, and groundwater

Voluntary Guidelines for Methamphetamine Laboratory Cleanup - Document

EPA Pesticide Factsheets

provides technical guidance for state and local personnel responsible for meth lab cleanup, based on an extensive review of the best available science and practices, and addresses general cleanup activities, specific items/materials, sampling.

Commercialization of waste gob gas and methane produced in conjunction with coal mining operations. Final report, August 1992--December 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-12-01

The primary objectives of the project were to identify and evaluate existing processes for (1) using gas as a feedstock for production of marketable, value-added commodities, and (2) enriching contaminated gas to pipeline quality. The following gas conversion technologies were evaluated: (1) transformation to liquid fuels, (2) manufacture of methanol, (3) synthesis of mixed alcohols, and (4) conversion to ammonia and urea. All of these involved synthesis gas production prior to conversion to the desired end products. Most of the conversion technologies evaluated were found to be mature processes operating at a large scale. A drawback in all of themore » processes was the need to have a relatively pure feedstock, thereby requiring gas clean-up prior to conversion. Despite this requirement, the conversion technologies were preliminarily found to be marginally economic. However, the prohibitively high investment for a combined gas clean-up/conversion facility required that REI refocus the project to investigation of gas enrichment alternatives. Enrichment of a gas stream with only one contaminant is a relatively straightforward process (depending on the contaminant) using available technology. However, gob gas has a unique nature, being typically composed of from constituents. These components are: methane, nitrogen, oxygen, carbon dioxide and water vapor. Each of the four contaminants may be separated from the methane using existing technologies that have varying degrees of complexity and compatibility. However, the operating and cost effectiveness of the combined system is dependent on careful integration of the clean-up processes. REI is pursuing Phase 2 of this project for demonstration of a waste gas enrichment facility using the approach described above. This is expected to result in the validation of the commercial and technical viability of the facility, and the refinement of design parameters.« less

Fuel-cell engine stream conditioning system

DOEpatents

DuBose, Ronald Arthur

2002-01-01

A stream conditioning system for a fuel cell gas management system or fuel cell engine. The stream conditioning system manages species potential in at least one fuel cell reactant stream. A species transfer device is located in the path of at least one reactant stream of a fuel cell's inlet or outlet, which transfer device conditions that stream to improve the efficiency of the fuel cell. The species transfer device incorporates an exchange media and a sorbent. The fuel cell gas management system can include a cathode loop with the stream conditioning system transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell related to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

Study of diffuse H II regions potentially forming part of the gas streams around Sgr A*

NASA Astrophysics Data System (ADS)

Armijos-Abendaño, J.; López, E.; Martín-Pintado, J.; Báez-Rubio, A.; Aravena, M.; Requena-Torres, M. A.; Martín, S.; Llerena, M.; Aldás, F.; Logan, C.; Rodríguez-Franco, A.

2018-05-01

We present a study of diffuse extended ionized gas towards three clouds located in the Galactic Centre (GC). One line of sight (LOS) is towards the 20 km s-1 cloud (LOS-0.11) in the Sgr A region, another LOS is towards the 50 km s-1 cloud (LOS-0.02), also in Sgr A, while the third is towards the Sgr B2 cloud (LOS+0.693). The emission from the ionized gas is detected from Hnα and Hmβ radio recombination lines (RRLs). Henα and Hemβ RRL emission is detected with the same n and m as those from the hydrogen RRLs only towards LOS+0.693. RRLs probe gas with positive and negative velocities towards the two Sgr A sources. The Hmβ to Hnα ratios reveal that the ionized gas is emitted under local thermodynamic equilibrium conditions in these regions. We find a He to H mass fraction of 0.29±0.01 consistent with the typical GC value, supporting the idea that massive stars have increased the He abundance compared to its primordial value. Physical properties are derived for the studied sources. We propose that the negative velocity component of both Sgr A sources is part of gas streams considered previously to model the GC cloud kinematics. Associated massive stars with what are presumably the closest H II regions to LOS-0.11 (positive velocity gas), LOS-0.02, and LOS+0.693 could be the main sources of ultraviolet photons ionizing the gas. The negative velocity components of both Sgr A sources might be ionized by the same massive stars, but only if they are in the same gas stream.

Establishing Final Cleanup Decisions for the Hanford Site River Corridor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lerch, J.A.; Sands, J.P.

2007-07-01

A major challenge in the River Corridor Closure Contract is establishing final cleanup decisions for the source operable units in the Hanford Site river corridor. Cleanup actions in the river corridor began in 1994 and have been performed in accordance with a 'bias for action' approach adopted by the Tri-Parties - the U.S. Department of Energy, U.S. Environmental Protection Agency, and Washington State Department of Ecology. This approach enabled early application of cleanup dollars on actual remediation of contaminated waste sites. Consequently, the regulatory framework authorizing cleanup actions at source operable units in the river corridor consists largely of interimmore » action records of decision, which were supported by qualitative risk assessments. Obtaining final cleanup decisions for the source operable units is necessary to determine whether past cleanup actions in the river corridor are protective of human health and the environment and to identify any course corrections that may be needed to ensure that ongoing and future cleanup actions are protective. Because the cleanup actions are ongoing, it is desirable to establish the final cleanup decisions as early as possible to minimize the impacts of any identified course corrections to the present cleanup approach. Development of a strategy to obtain final cleanup decisions for the source operable units in a manner that is responsive to desires for an integrated approach with the groundwater and Columbia River components while maintaining the ability to evaluate each component on its own merit represents a significant challenge. There are many different options for grouping final cleanup decisions, and each involved party or stakeholder brings slightly different interests that shape the approach. Regardless of the selected approach, there are several specific challenges and issues to be addressed before making final cleanup decisions. A multi-agency and contractor working group has been established to

Recent changes to the Gulf Stream causing widespread gas hydrate destabilization.

PubMed

Phrampus, Benjamin J; Hornbach, Matthew J

2012-10-25

The Gulf Stream is an ocean current that modulates climate in the Northern Hemisphere by transporting warm waters from the Gulf of Mexico into the North Atlantic and Arctic oceans. A changing Gulf Stream has the potential to thaw and convert hundreds of gigatonnes of frozen methane hydrate trapped below the sea floor into methane gas, increasing the risk of slope failure and methane release. How the Gulf Stream changes with time and what effect these changes have on methane hydrate stability is unclear. Here, using seismic data combined with thermal models, we show that recent changes in intermediate-depth ocean temperature associated with the Gulf Stream are rapidly destabilizing methane hydrate along a broad swathe of the North American margin. The area of active hydrate destabilization covers at least 10,000 square kilometres of the United States eastern margin, and occurs in a region prone to kilometre-scale slope failures. Previous hypothetical studies postulated that an increase of five degrees Celsius in intermediate-depth ocean temperatures could release enough methane to explain extreme global warming events like the Palaeocene-Eocene thermal maximum (PETM) and trigger widespread ocean acidification. Our analysis suggests that changes in Gulf Stream flow or temperature within the past 5,000 years or so are warming the western North Atlantic margin by up to eight degrees Celsius and are now triggering the destabilization of 2.5 gigatonnes of methane hydrate (about 0.2 per cent of that required to cause the PETM). This destabilization extends along hundreds of kilometres of the margin and may continue for centuries. It is unlikely that the western North Atlantic margin is the only area experiencing changing ocean currents; our estimate of 2.5 gigatonnes of destabilizing methane hydrate may therefore represent only a fraction of the methane hydrate currently destabilizing globally. The transport from ocean to atmosphere of any methane released--and thus its

Determination of stream reaeration coefficients by use of tracers

USGS Publications Warehouse

Kilpatrick, F.A.; Rathbun, R.E.; Yotsukura, N.; Parker, G.W.; DeLong, L.L.

1987-01-01

Stream reaeration is the physical absorption of oxygen from the atmosphere by a flowing stream. This is the primary process by which a stream replenishes the oxygen consumed in the biodegradation of organic wastes.Prior to 1965, reaeration rate coefficients could be estimated only by indirect methods. In 1965, a direct method of measuring stream reaeration coefficients was developed in which a radioactive tracer gas was injected into a stream--the tracer gas being desorbed from the stream inversely to how oxygen would be absorbed. The technique has since been modified by substituting hydrocarbon gases for the radioactive tracer gas.This manual describes the slug-injection and constant-rate injection methods of performing gas-tracer desorption measurements. Emphasis is on the use of rhodamine WT dye as a relatively conservative tracer and propane as the nonconservative gas tracer, on planning field tests, methods of injection, sampling and analysis, and computational techniques to compute desorption and reaeration coefficients.

Determination of stream reaeration coefficients by use of tracers

USGS Publications Warehouse

Kilpatrick, F.A.; Rathbun, R.E.; Yotsukura, Nobuhiro; Parker, G.W.; DeLong, L.L.

1989-01-01

Stream reaeration is the physical absorption of oxygen from the atmosphere by a flowing stream. This is the primary process by which a stream replenishes the oxygen consumed in the biodegradation of organic wastes. Prior to 1965, reaeration rate coefficients could be estimated only by indirect methods. In 1965, a direct method of measuring stream reaeration coefficients was developed whereby a radioactive tracer gas was injected into a stream-the principle being that the tracer gas would be desorbed from the stream inversely to how oxygen would be absorbed. The technique has since been modified by substituting hydrocarbon gases for the radioactive tracer gas. This manual describes the slug-injection and constant-rate-injection methods of measuring gas-tracer desorption. Emphasis is on the use of rhodamine WT dye as a relatively conservative tracer and propane as the nonconservative gas tracer, on planning field tests, on methods of injection, sampling, and analysis, and on techniques for computing desorption and reaeration coefficients.

Intergenerational equity and environmental restoration cleanup levels.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hocking, E. K.; Environmental Assessment

2001-01-01

The United States Department of Energy environmental restoration program faces difficult decisions about the levels of cleanup to be achieved at its many contaminated sites and has acknowledged the need for considering intergenerational equity in its decision making. Intergenerational equity refers to the fairness of access to resources across generations. Environmental restoration cleanup levels can have unintended and unfair consequences for future generations access to resources. The potentially higher costs associated with using low, non-risk-based cleanup levels for remediation may divert funding from other activities that could have a greater beneficial impact on future generations. Low, non-risk-based cleanup levels couldmore » also result in more damage to the nation's resources than would occur if a higher cleanup level were used. The loss or impairment of these resources could have an inequitable effect on future generations. However, intergenerational inequity could arise if sites are not completely restored and if access to and use of natural and cultural resources are unfairly limited as a result of residual contamination. In addition to concerns about creating possible intergenerational inequities related to selected cleanup levels, the tremendous uncertainties associated with sites and their restoration can lead site planners to rely on stewardship by default. An ill-conceived stewardship program can contribute to intergenerational inequity by limiting access to resources while passing on risks to future generations and not preparing them for those risks. This paper presents a basic model and process for designing stewardship programs that can achieve equity among generations.« less

Removal of dichloromethane from waste gas streams using a hybrid bubble column/biofilter bioreactor

PubMed Central

2014-01-01

The performance of a hybrid bubble column/biofilter (HBCB) bioreactor for the removal of dichloromethane (DCM) from waste gas streams was studied in continuous mode for several months. The HBCB bioreactor consisted of two compartments: bubble column bioreactor removing DCM from liquid phase and biofilter removing DCM from gas phase. Effect of inlet DCM concentration on the elimination capacity was examined in the DCM concentration range of 34–359 ppm with loading rates ranged from 2.2 to 22.8 g/m3.h and constant total empty bed retention time (EBRT) of 200 s. In the equal loading rates, the elimination capacity and removal efficiency of the biofilter were higher than the corresponding values of the bubble column bioreactor. The maximum elimination capacity of the HBCB bioreactor was determined to be 15.7 g/m3.h occurred in the highest loading rate of 22.8 g/m3.h with removal efficiency of 69%. The overall mineralization portion of the HBCB bioreactor was in the range of 72-79%. The mixed liquor acidic pH especially below 5.5 inhibited microbial activity and decreased the elimination capacity. Inhibitory effect of high ionic strength was initiated in the mixed liquor electrical conductivity of 12.2 mS/cm. This study indicated that the HBCB bioreactor could benefit from advantages of both bubble column and biofilter reactors and could remove DCM from waste gas streams in a better manner. PMID:24406056

Three-axis acoustic device for levitation of droplets in an open gas stream and its application to examine sulfur dioxide absorption by water droplets.

PubMed

Stephens, Terrance L; Budwig, Ralph S

2007-01-01

Two acoustic devices to stabilize a droplet in an open gas stream (single-axis and three-axis levitators) have been designed and tested. The gas stream was provided by a jet apparatus with a 64 mm exit diameter and a uniform velocity profile. The acoustic source used was a Langevin vibrator with a concave reflector. The single-axis levitator relied primarily on the radial force from the acoustic field and was shown to be limited because of significant droplet wandering. The three-axis levitator relied on a combination of the axial and radial forces. The three-axis levitator was applied to examine droplet deformation and circulation and to investigate the uptake of SO(2) from the gas stream to the droplet. Droplets ranging in diameters from 2 to 5 mm were levitated in gas streams with velocities up to 9 ms. Droplet wandering was on the order of a half droplet diameter for a 3 mm diameter droplet. Droplet circulation ranged from the predicted Hadamard-Rybczynski pattern to a rotating droplet pattern. Droplet pH over a central volume of the droplet was measured by planar laser induced fluorescence. The results for the decay of droplet pH versus time are in general agreement with published theory and experiments.

Three-axis acoustic device for levitation of droplets in an open gas stream and its application to examine sulfur dioxide absorption by water droplets

NASA Astrophysics Data System (ADS)

Stephens, Terrance L.; Budwig, Ralph S.

2007-01-01

Two acoustic devices to stabilize a droplet in an open gas stream (single-axis and three-axis levitators) have been designed and tested. The gas stream was provided by a jet apparatus with a 64mm exit diameter and a uniform velocity profile. The acoustic source used was a Langevin vibrator with a concave reflector. The single-axis levitator relied primarily on the radial force from the acoustic field and was shown to be limited because of significant droplet wandering. The three-axis levitator relied on a combination of the axial and radial forces. The three-axis levitator was applied to examine droplet deformation and circulation and to investigate the uptake of SO2 from the gas stream to the droplet. Droplets ranging in diameters from 2to5mm were levitated in gas streams with velocities up to 9m /s. Droplet wandering was on the order of a half droplet diameter for a 3mm diameter droplet. Droplet circulation ranged from the predicted Hadamard-Rybczynski pattern to a rotating droplet pattern. Droplet pH over a central volume of the droplet was measured by planar laser induced fluorescence. The results for the decay of droplet pH versus time are in general agreement with published theory and experiments.

Software to Control and Monitor Gas Streams

NASA Technical Reports Server (NTRS)

Arkin, C.; Curley, Charles; Gore, Eric; Floyd, David; Lucas, Damion

2012-01-01

This software package interfaces with various gas stream devices such as pressure transducers, flow meters, flow controllers, valves, and analyzers such as a mass spectrometer. The software provides excellent user interfacing with various windows that provide time-domain graphs, valve state buttons, priority- colored messages, and warning icons. The user can configure the software to save as much or as little data as needed to a comma-delimited file. The software also includes an intuitive scripting language for automated processing. The configuration allows for the assignment of measured values or calibration so that raw signals can be viewed as usable pressures, flows, or concentrations in real time. The software is based on those used in two safety systems for shuttle processing and one volcanic gas analysis system. Mass analyzers typically have very unique applications and vary from job to job. As such, software available on the market is usually inadequate or targeted on a specific application (such as EPA methods). The goal was to develop powerful software that could be used with prototype systems. The key problem was to generalize the software to be easily and quickly reconfigurable. At Kennedy Space Center (KSC), the prior art consists of two primary methods. The first method was to utilize Lab- VIEW and a commercial data acquisition system. This method required rewriting code for each different application and only provided raw data. To obtain data in engineering units, manual calculations were required. The second method was to utilize one of the embedded computer systems developed for another system. This second method had the benefit of providing data in engineering units, but was limited in the number of control parameters.

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

30 CFR 75.400-2 - Cleanup program.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

Gas venting system

DOEpatents

Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

2010-06-29

A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

Clean-up of a pesticide-lanolin mixture by gel permeation chromatography.

PubMed

López-Mesas, M; Crespi, M; Brach, J; Mullender, J P

2000-12-01

In this study, the efficiency of a clean-up method by gel permeation chromatography (GPC) for the separation of pesticides from lanolin is analyzed. The pesticides analyzed belong to two different families, organophosphorous and synthetic pyrethroids. Lanolin, a standard mixture of the pesticides, and a lanolin-pesticides mixture are injected in a GPC column. The recoveries and elution times from the GPC column of lanolin (by a gravimetric method) and pesticides (by gas chromatography-electron capture detector) are determined. From this column, a good separation of the lanolin-pesticides mixture is observed.

The ecological impact of land restoration and cleanup. Technical report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1978-08-01

The report is concerned with the ecological impacts of specific cleanup treatment on the land where they were carried out. The cleanup procedures given apply equally to chemical or radioactive materials. Guidance is provided for cleanup procedures likely to be suggested by government, industry, or environmental groups. The basic types of cleanup procedures for removing or deactiving spilled contamination involve moving people and animals from the affected area, scraping and grading the contaminated soil into windrows, plowing the contamination under, or digging up the contamination and hauling it away. The report describes and evaluates the various land-type cleanup effects inmore » terms of impact of the techniques on the environment. Part I defines several natural ecosystems and some of their natural derivations. Part II presents managed ecosystems which are imposed on natural ecosystems and are no longer bound by the initial native ecosystem balances. Part III deals with avion and mammilian wild life displaced by cleanup.« less

Treatment of gas from an in situ conversion process

DOEpatents

Diaz, Zaida [Katy, TX; Del Paggio, Alan Anthony [Spring, TX; Nair, Vijay [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX

2011-12-06

A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

Problems and limitations of voluntary cleanup programs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, S.F.

1995-12-31

At least a dozen states have already implemented voluntary cleanup programs (VCPs). Provisions to promote state VCPs were prominent in the EPA`s 1994 proposed revisions to CERCLA and in current legislative initiatives. Under the VCP, property owners voluntarily enroll to investigate and remediate contaminated sites with the aegis of a state agency and thus avoid involvement with the federal Superfund program. When the state agency is satisfied with the condition of the site, it issues a certificate to the owner. The VCP is meant to mitigate unintended consequences of CERCLA such as the economic abandonment of urban industrial sites inmore » favor of unpolluted suburban sites. The VCP concept has been combined with other reforms including cleanup standards, financial incentives, and independent action. The effectiveness of voluntary cleanup programs is limited by the costs of investigation and cleanup relative to the value of the property in question. It is also limited when property has environmental problems outside the traditional focus of state Superfund agencies on soil and groundwater contamination. VCPs also have potential unintended consequences of their own. The VCP concept is consistent with a 15 year trend of increasing government attention and involvement with sites of diminishing health and environmental significance. VCP may reinforce the perception of liability and unwittingly raise the standard of due diligence in property assessments, especially if combined with generic cleanup standard.« less

Experimental transient turbine blade temperatures in a research engine for gas stream temperatures cycling between 1067 and 1567 k

NASA Technical Reports Server (NTRS)

Gauntner, D. J.; Yeh, F. C.

1975-01-01

Experimental transient turbine blade temperatures were obtained from tests conducted on air-cooled blades in a research turbojet engine, cycling between cruise and idle conditions. Transient data were recorded by a high speed data acquisition system. Temperatures at the same phase of each transient cycle were repeatable between cycles to within 3.9 K (7 F). Turbine inlet pressures were repeatable between cycles to within 0.32 N/sq cm (0.47 psia). The tests were conducted at a gas stream temperature of 1567 K (2360 F) at cruise, and 1067 K (1460 F) at idle conditions. The corresponding gas stream pressures were about 26.2 and 22.4 N/sq cm (38 and 32.5 psia) respectively. The nominal coolant inlet temperature was about 811 K (1000 F).

Coaxial twin-fluid atomization with pattern air gas streams

NASA Astrophysics Data System (ADS)

Hei Ng, Chin; Aliseda, Alberto

2010-11-01

Coaxial twin-fluid atomization has numerous industrial applications, most notably fuel injection and spray coating. In the coating process of pharmaceutical tablets, the coaxial atomizing air stream is accompanied by two diametrically opposed side jets that impinge on the liquid/gas coaxial jets at an angle to produce an elliptical shape of the spray's cross section. Our study focuses on the influence of these side jets on the break up process and on the droplet velocity and diameter distribution along the cross section. The ultimate goal is to predict the size distribution and volume flux per unit area in the spray. With this predictive model, an optimal atomizing air/pattern air ratio can be found to achieve the desired coating result. This model is also crucial in scaling up the laboratory setup to production level. We have performed experiments with different atomized liquids, such as water and glycerine-water mixtures, that allow us to establish the effect of liquid viscosity, through the Ohnesorge number, in the spray characteristics. The gas Reynolds number of our experiments ranges from 9000 to 18000 and the Weber number ranges from 400 to 1600. We will present the effect of pattern air in terms of the resulting droplets size, droplet number density and velocity at various distances downstream of the nozzle where the effect of pattern air is significant.

Prospecting for zones of contaminated ground-water discharge to streams using bottom-sediment gas bubbles

USGS Publications Warehouse

Vroblesky, Don A.; Lorah, Michelle M.

1991-01-01

Decomposition of organic-rich bottom sediment in a tidal creek in Maryland results in production of gas bubbles in the bottom sediment during summer and fall. In areas where volatile organic contaminants discharge from ground water, through the bottom sediment, and into the creek, part of the volatile contamination diffuses into the gas bubbles and is released to the atmosphere by ebullition. Collection and analysis of gas bubbles for their volatile organic contaminant content indicate that relative concentrations of the volatile organic contaminants in the gas bubbles are substantially higher in areas where the same contaminants occur in the ground water that discharges to the streams. Analyses of the bubbles located an area of previously unknown ground-water contamination. The method developed for this study consisted of disturbing the bottom sediment to release gas bubbles, and then capturing the bubbles in a polyethylene bag at the water-column surface. The captured gas was transferred either into sealable polyethylene bags for immediate analysis with a photoionization detector or by syringe to glass tubes containing wires coated with an activated-carbon adsorbent. Relative concentrations were determined by mass spectral analysis for chloroform and trichloroethylene.

Hazardous waste sites: voluntary industry cleanup proposed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1984-02-27

A proposal that calls for the chemical industry to undertake voluntary cleanup of hazardous waste sites was presented recently to the Environmental Protection Agency and on Capitol Hill. And although still in draft form, the proposal has elicited a very favorable response. In its present form, the proposal calls for setting up a nonprofit holding company, supported by donations from the chemical industry, to plan and carry out cleanup operations. It is the result of nine months of discussion among representatives of industry, environmental groups, and former government personnel, carried out under the auspices of the Conservation Foundation to assessmore » what could be done to speed the cleanup of hazardous waste sites. Although still in draft form, the proposal already is getting excellent reviews. One Congressional staff member says that the idea of a voluntary program is excellent. And EPA sees it as a real opportunity to supplement its funds - which it has been saying are nowhere near adequte to clean up all the sites that it expects eventually to be placed on the national priorities list - and get the work done. All this, of course, would occur under the agency's watchful eye. Some in the environmental community fear that the mere discussion of a private cleanup exercise might be used as an argument for not reauthorizing Superfund or for not expanding the size of the fund. However, most see the voluntary cleanup as a supplement to, not a replacement for, the Superfund program.« less

Task 3.9 -- Catalytic tar cracking. Semi-annual report, January 1--June 30, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Young, B.C.; Timpe, R.C.

1995-12-31

Tar produced in the gasification of coal is deleterious to the operation of downstream equipment including fuel cells, gas turbines, hot-gas stream cleanup filters, and pressure swing adsorption systems. Catalytic cracking of tars to smaller hydrocarbons can be an effective means to remove these tars from gas streams and, in the process, generate useful products, e.g., methane gas, which is crucial to the operation of molten carbonate fuel cells. The objectives of this project are to investigate whether gasification tars can be cracked by synthetic nickel-substituted micamontmorillonite, zeolite, or dolomite material; and whether the tars can be cracked selectively bymore » these catalysts to produce a desired liquid and/or gas stream. Results to date are presented in the cited papers.« less

Integrated vacuum absorption steam cycle gas separation

DOEpatents

Chen, Shiaguo [Champaign, IL; Lu, Yonggi [Urbana, IL; Rostam-Abadi, Massoud [Champaign, IL

2011-11-22

Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

The National LUST Cleanup Backlog: A Study of Opportunities

EPA Pesticide Factsheets

To understand the makeup of UST releases remaining and why the pace of cleanups is slowing, EPA undertook a two-phase, data-driven analysis of the cleanups remaining as of 2006 (Phase 1) and 2009 (Phase 2).

Pollution control: utility ships adapt for spill cleanups

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1986-02-01

A practical and cost effective approach to oil spill cleanup is being undertaken by Dutch companies. The approach involves constructing and equipping multi-use ships for pollution control. Usually, these ships are maintained in another type of service and come into use for spill cleanup only when needed. The use of these ships in pollution control is discussed.

Recent trends at the state and federal level in accelerating CERCLA clean-ups

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clegg, B.

Efforts at accelerating remedial action at the federal level focus on the following: the Superfund accelerated clean-up model (SCAM); Brownfields economic redevelopment initiative; guidance documents and policies; and collaboration with state voluntary cleanup programs. At the state level efforts involved in accelerating clean-ups include voluntary clean-up programs and Brownfields initiatives.

Novel fracture technology proves marginal Viking prospect economic, part II: Well clean-up, flowback and testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haidar, S.; Rylance, M.; Tybero, G.

1996-12-31

Having completed both fracture treatments as discussed in a companion paper, this paper continues on to describe the post fracture shut-in, clean-up and well testing operations that took place on the Viking Wx exploration well 49/17-12. These operations involved the removal of Resin Coated Proppant (RCP) from the wellbore, via Coiled Tubing (CT), through the use of a specially designed jetting nozzle. The RCP pack stability at a concentration of 3.0 lb/ft{sup 2} (as per planned design) had already been tested in a flowback cell. The use of a Surface Read-Out (SRO) gauge, combined with gas, water and proppant flowmore » rates as well as the viscosity of fracturing fluids returns, enabled real time calculation of the drag forces, on the proppant pack, during clean-up. The flow rate, in the field, was controlled such that the calculated drag forces remained below those observed in the laboratory. Following the clean-up a flow and build-up test was conducted, to evaluate the fracture half length and fracture conductivity, from which a Pseudo-radial skin was calculated. The Non-Darcy effects in the fracture were also evaluated, and finally the short term and long term well deliverabilities were assessed.« less

PFB Coal Fired Combined Cycle Development Program. Advanced hot gas cleanup concept evaluation (Task 4. 3). Volume A. Aerodyne cyclone evaluation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This report summarizes the results of testing of a rotary flow cyclone, manufactured by Aerodyne Development Corporation under license by Siemens Kraftwerk Union. This cyclone was selected for evaluation due to the unusually high separative efficiencies claimed by the manufacturer (based on developer data), and relative lack of open literature data. The most significant finding of this work was the observation that electrostatic forces could enhance or, in fact, dominate the separation process. Separative efficiencies, with electrostatic forces present, were found to be substantially independent of flow rate and, by inference, could be independent of unit size. Hence this findingmore » offers a major hope that large cyclones employed in the hot gas cleanup train of the CFCC system may not suffer the performance degradation compared to small cyclones, as projected from conventional inertial theory. The separative efficiencies of the Aerodyne cyclone separator were found from both the cold flow and the hot flow tests to be disappointingly poorer than expectations (in agreement with Westinghouse results), and even poorer than conventional cyclones. (LTN)« less

Process and system for removing impurities from a gas

DOEpatents

Henningsen, Gunnar; Knowlton, Teddy Merrill; Findlay, John George; Schlather, Jerry Neal; Turk, Brian S

2014-04-15

A fluidized reactor system for removing impurities from a gas and an associated process are provided. The system includes a fluidized absorber for contacting a feed gas with a sorbent stream to reduce the impurity content of the feed gas; a fluidized solids regenerator for contacting an impurity loaded sorbent stream with a regeneration gas to reduce the impurity content of the sorbent stream; a first non-mechanical gas seal forming solids transfer device adapted to receive an impurity loaded sorbent stream from the absorber and transport the impurity loaded sorbent stream to the regenerator at a controllable flow rate in response to an aeration gas; and a second non-mechanical gas seal forming solids transfer device adapted to receive a sorbent stream of reduced impurity content from the regenerator and transfer the sorbent stream of reduced impurity content to the absorber without changing the flow rate of the sorbent stream.

Operation of a sampling train for the analysis of environmental species in coal gasification gas-phase process streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pochan, M.J.; Massey, M.J.

1979-02-01

This report discusses the results of actual raw product gas sampling efforts and includes: Rationale for raw product gas sampling efforts; design and operation of the CMU gas sampling train; development and analysis of a sampling train data base; and conclusions and future application of results. The results of sampling activities at the CO/sub 2/-Acceptor and Hygas pilot plants proved that: The CMU gas sampling train is a valid instrument for characterization of environmental parameters in coal gasification gas-phase process streams; depending on the particular process configuration, the CMU gas sampling train can reduce gasifier effluent characterization activity to amore » single location in the raw product gas line; and in contrast to the slower operation of the EPA SASS Train, CMU's gas sampling train can collect representative effluent data at a rapid rate (approx. 2 points per hour) consistent with the rate of change of process variables, and thus function as a tool for process engineering-oriented analysis of environmental characteristics.« less

48 CFR 49.105-4 - Cleanup of construction site.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Cleanup of construction site. 49.105-4 Section 49.105-4 Federal Acquisition Regulations System FEDERAL ACQUISITION REGULATION CONTRACT MANAGEMENT TERMINATION OF CONTRACTS General Principles 49.105-4 Cleanup of construction site. In...

Supersonic gas streams enhance the formation of massive black holes in the early universe

NASA Astrophysics Data System (ADS)

Hirano, Shingo; Hosokawa, Takashi; Yoshida, Naoki; Kuiper, Rolf

2017-09-01

Supermassive black holes existed less than a billion years after the Big Bang. Because black holes can grow at a maximum rate that depends on their current mass, it has been difficult to understand how such massive black holes could have formed so quickly. Hirano et al. developed simulations to show that streaming motions—velocity offsets between the gas and dark matter components—could have produced black holes with tens of thousands of solar masses in the early universe. That's big enough to grow into the supermassive black holes that we observe today.

Factors affecting cleanup of exhaust gases from a pressurized, fluidized-bed coal combustor

NASA Technical Reports Server (NTRS)

Rollbuhler, R. J.; Kobak, J. A.

1980-01-01

The cleanup of effluent gases from the fluidized-bed combustion of coal is examined. Testing conditions include the type and feed rate of the coal and the sulfur sorbent, the coal-sorbent ratio, the coal-combustion air ratio, the depth of the reactor fluidizing bed, and the technique used to physically remove fly ash from the reactor effluent gases. Tests reveal that the particulate loading matter in the effluent gases is a function not only of the reactor-bed surface gas velocity, but also of the type of coal being burnt and the time the bed is operating. At least 95 percent of the fly ash particules in the effluent gas are removed by using a gas-solids separator under controlled operating conditions. Gaseous pollutants in the effluent (nitrogen and sulfur oxides) are held within the proposed Federal limits by controlling the reactor operating conditions and the type and quantity of sorbent material.

TEST RESULTS FOR FUEL-CELL OPERATION ON LANDFILL GAS

EPA Science Inventory

Test results from a demonstration of fuel-cell (FC) energy recovery and control of landfill gas emissions are presented. The project addressed two major issues: (i) the design, construction, and testing of a landfill-gas cleanup system; and (ii) a field test of a commercial phos...

SO x /NO x Removal from Flue Gas Streams by Solid Adsorbents: A Review of Current Challenges and Future Directions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rezaei, Fateme; Rownaghi, Ali A.; Monjezi, Saman

One of the main challenges in the power and chemical industries is to remove generated toxic or environmentally harmful gases before atmospheric emission. To comply with stringent environmental and pollutant emissions control regulations, coal-fired power plants must be equipped with new technologies that are efficient and less energy-intensive than status quo technologies for flue gas cleanup. While conventional sulfur oxide (SOx) and nitrogen oxide (NOx) removal technologies benefit from their large-scale implementation and maturity, they are quite energy-intensive. In view of this, the development of lower-cost, less energy-intensive technologies could offer an advantage. Significant energy and cost savings can potentiallymore » be realized by using advanced adsorbent materials. One of the major barriers to the development of such technologies remains the development of materials that are efficient and productive in removing flue gas contaminants. In this review, adsorption-based removal of SOx/NOx impurities from flue gas is discussed, with a focus on important attributes of the solid adsorbent materials as well as implementation of the materials in conventional and emerging acid gas removal technologies. The requirements for effective adsorbents are noted with respect to their performance, key limitations, and suggested future research directions. The final section includes some key areas for future research and provides a possible roadmap for the development of technologies for the removal of flue gas impurities that are more efficient and cost-effective than status quo approaches.« less

Utilizing the right mix of environmental cleanup technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whitaker, Wade; Bergren, Chris; Flora, Mary

2007-07-01

The Savannah River Site (SRS) is a 310-square-mile United States Department of Energy nuclear facility located along the Savannah River near Aiken, South Carolina. During operations, which started in 1951, hazardous substances (chemicals and radionuclides) were released to the environment. The releases occurred as a result of inadvertent spills and waste disposal in unlined pits and basins which was common practice before environmental regulations existed. The hazardous substances have migrated to the vadose zone and groundwater in many areas of the SRS, resulting in 515 waste units that are required by environmental regulations, to undergo characterization and, if needed, remediation.more » In the initial years of the SRS environmental cleanup program (early 1990's), the focus was to use common technologies (such as pump and treat, air stripping, excavation and removal) that actively and tangibly removed contamination. Exclusive use of these technologies required continued and significant funding while often failing to meet acceptable clean-up goals and objectives. Recognizing that a more cost-effective approach was needed, SRS implemented new and complementary remediation methods focused on active and passive technologies targeted to solve specific remediation problems. Today, SRS uses technologies such as chemical / pH-adjusting injection, phyto-remediation, underground cutoff walls, dynamic underground stripping, soil fracturing, microbial degradation, baro-balls, electrical resistance heating, soil vapor extraction, and micro-blowers to more effectively treat contamination at lower costs. Additionally, SRS's remediation approach cost effectively maximizes cleanup as SRS works pro-actively with multiple regulatory agencies. Using GIS, video, animation, and graphics, SRS is able to provide an accurate depiction of the evolution of SRS groundwater and vadose zone cleanup activities to convince stakeholders and regulators of the effectiveness of various cleanup

The WHAM Hα Magellanic Stream Survey: Progress and Early Results

NASA Astrophysics Data System (ADS)

Smart, Brianna; Haffner, L. Matthew; Barger, Kat; Krishnarao, Dhanesh

2017-01-01

We present early analysis of the Hα survey of the Magellanic Stream using the Wisconsin H-Alpha Mapper (WHAM). The neutral component of the Stream extends some 200° across the sky (Nidever et al. 2010). However, the full extent of the ionized gas has not been mapped in detail. Previous studies (e.g., Putman et al. 2003; Weiner & Williams 1996) suggest that ionized gas is likely to be found all along the length of the Stream, and may extend beyond the current neutral boundaries as traced by 21 cm. Barger et al. (2013) used WHAM to map ionized gas throughout the Magellanic Bridge between the Magellanic Clouds. Although ionized emission tracks the neutral emission for the most part, it often spans a few degrees away from the H I at slightly offset velocities. Additionally, Fox et al. (2014) find evidence in an absorption line study that the tidal debris in the Magellanic System contains twice as much ionized gas as neutral material and may extend 30° away from 21-cm sensitivity boundaries. We are now compiling the first comprehensive picture of the ionized component of the Magellanic Stream using WHAM's unprecedented sensitivity to trace diffuse emission (~tens of mR), its velocity resolution (12 km/s) to separate the Stream from the Milky Way, and its multiwavelength capabilities (e.g., [S II] and [N II]) to examine the physical conditions of the gas. Much of the data along the primary axis of the Stream has been collected for the first phase of this extensive study, a complete kinematic Hα survey of the Stream. We present survey progress, challenges in extracting Stream emission, and first-look kinematic maps at select positions along the Stream.

Apparatus for removal of particulate matter from gas streams

DOEpatents

Smith, Peyton L.; Morse, John C.

2000-01-01

An apparatus for the removal of particulate matter from the gaseous product stream of an entrained flow coal gasifier which apparatus includes an initial screen, an intermediate screen which is aligned with the direction of flow of the gaseous product stream and a final screen transversely disposed to the flow of gaseous product and which apparatus is capable of withstanding at least a pressure differential of about 10 psi (68.95 kPa) or greater at the temperatures of the gaseous product stream.

Determination of mercury evasion in a contaminated headwater stream.

PubMed

Maprani, Antu C; Al, Tom A; Macquarrie, Kerry T; Dalziel, John A; Shaw, Sean A; Yeats, Phillip A

2005-03-15

Evasion from first- and second-order streams in a watershed may be a significant factor in the atmospheric recycling of volatile pollutants such as mercury; however, methods developed for the determination of Hg evasion rates from larger water bodies are not expected to provide satisfactory results in highly turbulent and morphologically complex first- and second-order streams. A new method for determining the Hg evasion rates from these streams, involving laboratory gas-indexing experiments and field tracer tests, was developed in this study to estimate the evasion rate of Hg from Gossan Creek, a first-order stream in the Upsalquitch River watershed in northern New Brunswick, Canada. Gossan Creek receives Hg-contaminated groundwater discharge from a gold mine tailings pile. Laboratory gas-indexing experiments provided the ratio of gas-exchange coefficients for zero-valent Hg to propane (tracer gas) of 0.81+/-0.16, suggesting that the evasion mechanism in highly turbulent systems can be described by the surface renewal model with an additional component of enhanced gas evasion probably related to the formation of bubbles. Deliberate field tracer tests with propane and chloride tracers were found to be a reliable and practical method for the determination of gas-exchange coefficients for small streams. Estimation of Hg evasion from the first 1 km of Gossan Creek indicates that about 6.4 kg of Hg per year is entering the atmosphere, which is a significant fraction of the regional sources of Hg to the atmosphere.

Falling microbead counter-flow process for separating gas mixtures

DOEpatents

Hornbostel, Marc D.; Krishnan, Gopala N.; Sanjurjo, Angel

2015-07-07

A method and reactor for removing a component from a gas stream is provided. In one embodiment, the method includes providing the gas stream containing the component that is to be removed and adsorbing the component out of the gas stream as the gas stream rises via microbeads of a sorbent falling down an adsorber section of a reactor.

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

40 CFR 761.125 - Requirements for PCB spill cleanup.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) Additional pre- or post-cleanup sampling. (B) The estimated cost of the cleanup by man-hours, dollars, or... section are designed to be consistent with existing reporting requirements to the extent possible so as to...) by standard commercial wipe tests. (ii) All soil within the spill area (i.e., visible traces of soil...

Means and method for the destruction of particles entrained in a gas stream

DOEpatents

Botts, Thomas E.; Powell, James R.

1980-01-01

An apparatus and method for the destruction of particles entrained in a gas stream are disclosed. Destruction in the context of the subject invention means the fragmentation and/or vaporization of particles above a certain size limit. The subject invention contemplates destroying such particles by exposing them to intense bursts of laser light, such light having a frequency approximately equal to or less than the mean size of such particles. This invention is particularly adopted to the protection of turbine blades in open cycle coal-fired turbine systems. Means for introducing various chemical species and activating them by exposure to laser light are also disclosed.

Hazardous Waste: Cleanup and Prevention.

ERIC Educational Resources Information Center

Vandas, Steve; Cronin, Nancy L.

1996-01-01

Describes the Superfund, a federal cleanup program created in response to growing public concern over the health and environmental risks posed by hazardous waste sites. Discusses sources, disposal, and movement and risk of hazardous waste. (JRH)

Detecting the effects of coal mining, acid rain, and natural gas extraction in Appalachian basin streams in Pennsylvania (USA) through analysis of barium and sulfate concentrations.

PubMed

Niu, Xianzeng; Wendt, Anna; Li, Zhenhui; Agarwal, Amal; Xue, Lingzhou; Gonzales, Matthew; Brantley, Susan L

2018-04-01

To understand how extraction of different energy sources impacts water resources requires assessment of how water chemistry has changed in comparison with the background values of pristine streams. With such understanding, we can develop better water quality standards and ecological interpretations. However, determination of pristine background chemistry is difficult in areas with heavy human impact. To learn to do this, we compiled a master dataset of sulfate and barium concentrations ([SO 4 ], [Ba]) in Pennsylvania (PA, USA) streams from publically available sources. These elements were chosen because they can represent contamination related to oil/gas and coal, respectively. We applied changepoint analysis (i.e., likelihood ratio test) to identify pristine streams, which we defined as streams with a low variability in concentrations as measured over years. From these pristine streams, we estimated the baseline concentrations for major bedrock types in PA. Overall, we found that 48,471 data values are available for [SO 4 ] from 1904 to 2014 and 3243 data for [Ba] from 1963 to 2014. Statewide [SO 4 ] baseline was estimated to be 15.8 ± 9.6 mg/L, but values range from 12.4 to 26.7 mg/L for different bedrock types. The statewide [Ba] baseline is 27.7 ± 10.6 µg/L and values range from 25.8 to 38.7 µg/L. Results show that most increases in [SO 4 ] from the baseline occurred in areas with intensive coal mining activities, confirming previous studies. Sulfate inputs from acid rain were also documented. Slight increases in [Ba] since 2007 and higher [Ba] in areas with higher densities of gas wells when compared to other areas could document impacts from shale gas development, the prevalence of basin brines, or decreases in acid rain and its coupled effects on [Ba] related to barite solubility. The largest impacts on PA stream [Ba] and [SO 4 ] are related to releases from coal mining or burning rather than oil and gas development.

ENERGY CONSERVATION AND PRODUCTION AT WASTE CLEANUP SITES (ISSUE PAPER)

EPA Science Inventory

Saving energy used by hazardous waste cleanup remediation systems should interest those people working on waste cleanup sites. Presidential Executive Order 13123, "Greening the Government Through Efficient Energy Management", states that each agency shall strive to expand the us...

Review of State Soil Cleanup Levels for Dioxin (December 2009)

EPA Science Inventory

This final report summarizes a survey of state soil cleanup levels for dioxin and characterizes the science underlying these values. The objective of this project was to summarize existing state cleanup levels for dioxin in soil, together with their scientific bases where availa...

40 CFR 312.25 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2010 CFR

2010-07-01

... cleanup liens. 312.25 Section 312.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SUPERFUND, EMERGENCY PLANNING, AND COMMUNITY RIGHT-TO-KNOW PROGRAMS INNOCENT LANDOWNERS, STANDARDS FOR... cleanup liens. (a) All appropriate inquiries must include a search for the existence of environmental...

The suitability of using dissolved gases to determine groundwater discharge to high gradient streams

USGS Publications Warehouse

Gleeson, Tom; Manning, Andrew H.; Popp, Andrea; Zane, Mathew; Clark, Jordan F.

2018-01-01

Determining groundwater discharge to streams using dissolved gases is known to be useful over a wide range of streamflow rates but the suitability of dissolved gas methods to determine discharge rates in high gradient mountain streams has not been sufficiently tested, even though headwater streams are critical as ecological habitats and water resources. The aim of this study is to test the suitability of using dissolved gases to determine groundwater discharge rates to high gradient streams by field experiments in a well-characterized, high gradient mountain stream and a literature review. At a reach scale (550 m) we combined stream and groundwater radon activity measurements with an in-stream SF6 tracer test. By means of numerical modeling we determined gas exchange velocities and derived very low groundwater discharge rates (∼15% of streamflow). These groundwater discharge rates are below the uncertainty range of physical streamflow measurements and consistent with temperature, specific conductance and streamflow measured at multiple locations along the reach. At a watershed-scale (4 km), we measured CFC-12 and δ18O concentrations and determined gas exchange velocities and groundwater discharge rates with the same numerical model. The groundwater discharge rates along the 4 km stream reach were highly variable, but were consistent with the values derived in the detailed study reach. Additionally, we synthesized literature values of gas exchange velocities for different stream gradients which show an empirical relationship that will be valuable in planning future dissolved gas studies on streams with various gradients. In sum, we show that multiple dissolved gas tracers can be used to determine groundwater discharge to high gradient mountain streams from reach to watershed scales.

The suitability of using dissolved gases to determine groundwater discharge to high gradient streams

NASA Astrophysics Data System (ADS)

Gleeson, Tom; Manning, Andrew H.; Popp, Andrea; Zane, Matthew; Clark, Jordan F.

2018-02-01

Determining groundwater discharge to streams using dissolved gases is known to be useful over a wide range of streamflow rates but the suitability of dissolved gas methods to determine discharge rates in high gradient mountain streams has not been sufficiently tested, even though headwater streams are critical as ecological habitats and water resources. The aim of this study is to test the suitability of using dissolved gases to determine groundwater discharge rates to high gradient streams by field experiments in a well-characterized, high gradient mountain stream and a literature review. At a reach scale (550 m) we combined stream and groundwater radon activity measurements with an in-stream SF6 tracer test. By means of numerical modeling we determined gas exchange velocities and derived very low groundwater discharge rates (∼15% of streamflow). These groundwater discharge rates are below the uncertainty range of physical streamflow measurements and consistent with temperature, specific conductance and streamflow measured at multiple locations along the reach. At a watershed-scale (4 km), we measured CFC-12 and δ18O concentrations and determined gas exchange velocities and groundwater discharge rates with the same numerical model. The groundwater discharge rates along the 4 km stream reach were highly variable, but were consistent with the values derived in the detailed study reach. Additionally, we synthesized literature values of gas exchange velocities for different stream gradients which show an empirical relationship that will be valuable in planning future dissolved gas studies on streams with various gradients. In sum, we show that multiple dissolved gas tracers can be used to determine groundwater discharge to high gradient mountain streams from reach to watershed scales.

Bench-scale demonstration of hot-gas desulfurization technology. Quarterly report, April 1 - June 30, 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-12-31

The US Department of Energy (DOE) Morgantown Energy Technology Center (METC) is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal gas) streams of integrated gasification combined-cycle (IGCC) power systems. The programs focus on hot-gas particulate removal and desulfurization technologies that match or nearly match the temperatures and pressures of the gasifier, cleanup system, and power generator. The work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. The goal of this project is to continue further development of the zinc titanate desulfurizationmore » and direct sulfur recovery process (DSRP) technologies by (1) scaling up the zinc titanate reactor system; (2) developing an integrated skid-mounted zinc titanate desulfurization-DSRP reactor system; (3) testing the integrated system over an extended period with real coal-as from an operating gasifier to quantify the degradative effect, if any, of the trace contaminants present in cola gas; (4) developing an engineering database suitable for system scaleup; and (5) designing, fabricating and commissioning a larger DSRP reactor system capable of operating on a six-fold greater volume of gas than the DSRP reactor used in the bench-scale field test. The work performed during the April 1 through June 30, 1996 period is described.« less

Apparatus for the liquefaction of natural gas and methods relating to same

DOEpatents

Wilding, Bruce M [Idaho Falls, ID; McKellar, Michael G [Idaho Falls, ID; Turner, Terry D [Ammon, ID; Carney, Francis H [Idaho Falls, ID

2009-09-29

An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream.

Method for removing acid gases from a gaseous stream

DOEpatents

Gorin, Everett; Zielke, Clyde W.

1981-01-01

In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

Evaluation of a new carbon/zirconia-based sorbent for the cleanup of food extracts in multiclass analysis of pesticides and environmental contaminants.

PubMed

Han, Lijun; Sapozhnikova, Yelena; Matarrita, Jessie

2016-12-01

A novel carbon/zirconia-based material, Supel TM QuE Verde, was evaluated in a filter-vial dispersive solid-phase extraction cleanup of pork, salmon, kale, and avocado extracts for the residual analysis of 65 pesticides and 52 environmental contaminants (flame retardants, polychlorinated biphenyls, polybrominated diphenyl ethers, and polycyclic aromatic hydrocarbons) using low-pressure gas chromatography with tandem mass spectrometry. An amount of 180 mg sorbent per 0.6 mL extract in filter-vial dispersive solid-phase extraction cleanup was found the optimum in terms of achieving satisfactory removal of co-extractives and recoveries of analytes, especially for structurally planar compounds. For analytes partially retained by Verde, normalization to an internal standard resulted in 62-107% recoveries. Addition of Verde to primary secondary amine and C 18 in cleanup resulted in 38% more removal of gas-chromatography-amenable co-extractives in avocado, 30% in kale, 39% in salmon, and 50% in pork. The removal efficiency of co-extracted chlorophyll was 93% for kale and 64% for avocado based on ultraviolet-visible absorbance. The developed method was validated at three spiking levels (10, 25, and 100 ng/g), and 70-120% recoveries with ≤20% relative standard deviation were achieved for 96 (83%) out of 117 analytes in pork, 79 (69%) in salmon, 71 (62%) in kale, and 75 (65%) in avocado. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Buying time: Franchising hazardous and nuclear waste cleanup

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hale, D.R.

This paper describes a private franchise approach to long-term custodial care, monitoring and eventual cleanup of hazardous and nuclear waste sites. The franchise concept could be applied to Superfund sites, decommissioning commercial reactors and safeguarding their wastes and to Department of Energy sites. Privatization would reduce costs by enforcing efficient operations and capital investments during the containment period, by providing incentives for successful innovation and by sustaining containment until the cleanup`s net benefits exceed its costs. The franchise system would also permit local governments and citizens to demand and pay for more risk reduction than provided by the federal government.more » In principle, they would have the option of taking over site management. The major political drawback of the idea is that it requires society to be explicit about what it is willing to pay for now to protect current and future generations. Hazardous waste sites are enduring legacies of energy development. Abandoned mines, closed refineries, underground storage tanks and nuclear facilities have often become threats to human health and water quality. The policy of the United States government is that such sites should quickly be made nonpolluting and safe for unrestricted use. That is, the policy of the United States is prompt cleanup. Orphaned commercial hazardous waste sites are addressed by the US Environmental Protection Agency`s Superfund program. 17 refs., 2 tabs.« less

Apparatus for the liquefaction of a gas and methods relating to same

DOEpatents

Turner, Terry D [Idaho Falls, ID; Wilding, Bruce M [Idaho Falls, ID; McKellar, Michael G [Idaho Falls, ID

2009-12-29

Apparatuses and methods are provided for producing liquefied gas, such as liquefied natural gas. In one embodiment, a liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream may be sequentially pass through a compressor and an expander. The process stream may also pass through a compressor. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. A portion of the liquid gas may be used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line.

Expediting contaminated site cleanup in California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Newman, B.S.; Conlan, J.T.

California generally has been considered a leader in the advocacy of policies for the cleanup and abatement of environmental pollution. Many of the more innovative programs and policies were developed within the broad framework of California`s Brownfields Initiative. Because both the public and private sectors recognize that environmental cleanup and reuse of California`s industrial properties are major components of economic revitalization, the state has used administrative and legislative tools to provide incentives for redeveloping brownfields contaminated by leaking underground storage tanks (USTs) and other industrial operations. However, it is the broader reach of various state and local policies, programs, agreementsmore » and management communication that provide benefits to the majority of the regulated community.« less

Effects of coalbed natural gas development on fish assemblages in tributary streams of the Powder and Tongue rivers

USGS Publications Warehouse

Davis, W.N.; Bramblett, R.G.; Zale, A.V.

2010-01-01

1. Extraction of coalbed natural gas (CBNG) often results in disposal of large quantities of CBNG product water, which may affect aquatic ecosystems. We evaluated the effects of CBNG development on fish assemblages in tributary streams of the Powder and Tongue rivers. We used treatment and control, impact versus reference sites comparisons, surveys of CBNG product-water streams and in situ fish survival approaches to determine if CBNG development affected fish assemblages.2. Several of our results suggested that CBNG development did not affect fish assemblages. Species richness and index of biotic integrity (IBI) scores were similar in streams with and streams without CBNG development, and overall biotic integrity was not related to the number or density of CBNG wells. Fish occurred in one stream that was composed largely or entirely of CBNG product water. Sentinel fish survived in cages at treatment sites where no or few fish were captured, suggesting that factors such as lack of stream connectivity rather than water quality limited fish abundance at these sites. Fish species richness did not differ significantly from 1994 to 2006 in comparisons of CBNG-developed and undeveloped streams. Biotic integrity declined from 1994 to 2006; however, declines occurred at both impact and reference sites, possibly because of long-term drought.3. Some evidence suggested that CBNG development negatively affected fish assemblages, or may do so over time. Specific conductivity was on average higher in treatment streams and was negatively related to biotic integrity. Four IBI species richness metrics were negatively correlated with the number or density of CBNG wells in the catchment above sampling sites. Bicarbonate, one of the primary ions in product water, was significantly higher in developed streams and may have limited abundance of longnose dace (Rhinichthys cataractae). Total dissolved solids, alkalinity, magnesium and sulphate were significantly higher in developed streams

Landscape geomorphic characteristic impacts on greenhouse gas fluxes in exposed stream and riparian sediments.

PubMed

Vidon, Philippe; Serchan, Satish

2016-07-13

While excessive releases of greenhouse gases (GHG: N2O, CO2, CH4) to the atmosphere due to the burning of fossil fuel remains a concern, we also need to better quantify GHG emissions from natural systems. This study investigates GHG fluxes at the soil-atmosphere interface in a series of 7 stream reaches (riparian zones + exposed streambed sediment) across a range of geomorphic locations from headwaters reaches to lowland wetland reaches. When riparian fluxes (RZ) are compared to fluxes from in-stream locations (IS) under summer baseflow conditions, total CO2-equivalent (CO2eq) emissions are approximately 5 times higher at RZ locations than at IS locations, with most CO2eq driven by CH4 production at RZ locations where wet conditions dominate (headwater wetlands, lowland wetlands). On a gas-by-gas basis, no clear differences in N2O fluxes between RZ and IS locations were observed regardless of locations (headwater vs. lowland reaches), while CO2 fluxes were significantly larger at RZ locations than IS locations. Methane fluxes were significantly higher in wetland-influenced reaches than other reaches for both RZ and IS locations. However, GHG fluxes were not consistently correlated to DOC, DO, NO3(-), NH4(+), or water temperature, stressing the limitations of using water quality parameters to predict GHG emissions at the floodplain scale, at least during summer baseflow conditions. As strategies are developed to further constrain GHG emission for whole watersheds, we propose that approaches linking landscape geomorphic characteristics to GHG fluxes at the soil-atmosphere interface offer a promising avenue to successfully predict GHG emissions in floodplains at the watershed scale.

Apparatus for the liquefaction of natural gas and methods relating to same

DOEpatents

Turner, Terry D [Ammon, ID; Wilding, Bruce M [Idaho Falls, ID; McKellar, Michael G [Idaho Falls, ID

2009-09-22

An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates a vapor from the liquid natural gas. A portion of the liquid gas is used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line or recirculation within the system for further processing.

Planetesimal Formation through the Streaming Instability

NASA Astrophysics Data System (ADS)

Yang, Chao-Chin; Johansen, Anders; Schäfer, Urs

2015-12-01

The streaming instability is a promising mechanism to circumvent the barriers in direct dust growth and lead to the formation of planetesimals, as demonstrated by many previous studies. In order to resolve the thin layer of solids, however, most of these studies were focused on a local region of a protoplanetary disk with a limited simulation domain. It remains uncertain how the streaming instability is affected by the disk gas on large scales, and models that have sufficient dynamical range to capture both the thin particle layer and the large-scale disk dynamics are required.We hereby systematically push the limits of the computational domain up to more than the gas scale height, and study the particle-gas interaction on large scales in the saturated state of the streaming instability and the initial mass function of the resulting planetesimals. To overcome the numerical challenges posed by this kind of models, we have developed a new technique to simultaneously relieve the stringent time step constraints due to small-sized particles and strong local solid concentrations. Using these models, we demonstrate that the streaming instability can drive multiple radial, filamentary concentrations of solids, implying that planetesimals are born in well separated belt-like structures. We also find that the initial mass function of planetesimals via the streaming instability has a characteristic exponential form, which is robust against computational domain as well as resolution. These findings will help us further constrain the cosmochemical history of the Solar system as well as the planet formation theory in general.

Myelodysplastic syndromes in Chernobyl clean-up workers.

PubMed

Gluzman, Daniil F; Sklyarenko, Lilia M; Koval, Stella V; Rodionova, Nataliia K; Zavelevich, Michael P; Ivanivskaya, Tetiana S; Poludnenko, Liudmyla Yu; Ukrainskaya, Nataliia I

2015-10-01

The studies of the recent decades posed the question of the association between radiation exposure and myelodysplastic syndromes (MDS). This association has been proved in secondary MDS originating upon exposure to chemotherapeutics and/or radiation therapy. The long-term study in Japanese atomic (A)-bomb survivors demonstrated the significant linear dose-response for MDS confirming the link between radiation exposure and this form of hematopoietic malignancies. All these findings provide the strong basis for studying MDS in the persons exposed to radiation following the Chernobyl disaster, especially those in the cohort of Chernobyl clean-up workers of 1986-1987. The data on MDS among Chernobyl clean-up workers (1986-1987) diagnosed in 1996-2012 at the reference laboratory of RE Kavetsky Institute of Experimental Pathology, Oncology and Radiobiology are summarized. MDS cases were diagnosed in 23 persons (21 males and 2 females) having been exposed to radiation as clean-up workers of 1986-1987. Refractory anemia (RA) has been detected in 13, refractory anemia with ring sideroblasts (RARS)-in 2, and refractory anemia with excess blasts (RAEB)-in 8 patients. The median age of those MDS patients was 62.0 years. In addition, 5 cases of chronic myelomonocytic leukemia (CMML) were recorded in the group of Chernobyl clean-up workers with the median time of 14.8 years from 1986-1987 to diagnosis. The association between radiation exposure and MDS is discussed. The suggested life-long risk for myelodysplastic syndromes among A-bomb survivors in Japan highlights the importance of the continuing follow-up studies in the affected populations in the post-Chernobyl period.

Nuclear radiation cleanup and uranium prospecting

DOEpatents

Mariella, Jr., Raymond P.; Dardenne, Yves M.

2016-02-02

Apparatus, systems, and methods for nuclear radiation cleanup and uranium prospecting include the steps of identifying an area; collecting samples; sample preparation; identification, assay, and analysis; and relating the samples to the area.

Nuclear radiation cleanup and uranium prospecting

DOEpatents

Mariella, Jr., Raymond P.; Dardenne, Yves M.

2017-01-03

Apparatus, systems, and methods for nuclear radiation cleanup and uranium prospecting include the steps of identifying an area; collecting samples; sample preparation; identification, assay, and analysis; and relating the samples to the area.

Molecular Communication over Gas Stream Channels using Portable Mass Spectrometry.

PubMed

Giannoukos, Stamatios; Marshall, Alan; Taylor, Stephen; Smith, Jeremy

2017-11-01

The synthetic generation/coding and transmission of olfactory information over a gas stream or an odor network is a new and unexplored field. Application areas vary from the entertainment or advertisement industry to security and telemedicine. However, current technological limitations frustrate the accurate reproduction of decoded and transmitted olfactory data. This study describes the development, testing, and characterization of a novel odor emitter (OE) that is used to investigate the generation-encoding of gaseous standards with odorous characteristics with a regulatable way, for scent transmission purposes. The calibration and the responses of a developed OE were examined using a portable quadrupole mass spectrometer (MS). Experiments were undertaken for a range of volatile organic compounds (VOCs) at different temperatures and flow rates. Individual compounds and mixtures were tested to investigate periodic and dynamic transmission characteristics within two different size tubular containers for distances up to 3 m. Olfactory information transmission is demonstrated using MS as the main molecular sensor for odor detection and monitoring and for the first time spatial encryption of olfactory information is shown. Graphical Abstract ᅟ.

Molecular Communication over Gas Stream Channels using Portable Mass Spectrometry

NASA Astrophysics Data System (ADS)

Giannoukos, Stamatios; Marshall, Alan; Taylor, Stephen; Smith, Jeremy

2017-07-01

The synthetic generation/coding and transmission of olfactory information over a gas stream or an odor network is a new and unexplored field. Application areas vary from the entertainment or advertisement industry to security and telemedicine. However, current technological limitations frustrate the accurate reproduction of decoded and transmitted olfactory data. This study describes the development, testing, and characterization of a novel odor emitter (OE) that is used to investigate the generation-encoding of gaseous standards with odorous characteristics with a regulatable way, for scent transmission purposes. The calibration and the responses of a developed OE were examined using a portable quadrupole mass spectrometer (MS). Experiments were undertaken for a range of volatile organic compounds (VOCs) at different temperatures and flow rates. Individual compounds and mixtures were tested to investigate periodic and dynamic transmission characteristics within two different size tubular containers for distances up to 3 m. Olfactory information transmission is demonstrated using MS as the main molecular sensor for odor detection and monitoring and for the first time spatial encryption of olfactory information is shown.

LANDFILL GAS PRETREATMENT FOR FUEL CELL APPLICATIONS

EPA Science Inventory

The paper discusses the U.S. EPA's program, underway at International Fuel Cells Corporation, to demonstrate landfill methane control and the fuel cell energy recovery concept. In this program, two critical issues are being addressed: (1) a landfill gas cleanup method that would ...

Simultaneous determination of multiresidual phenyl acetanilide pesticides in different food commodities by solid-phase cleanup and gas chromatography-mass spectrometry.

PubMed

Li, Yongjun; Wang, Meiling; Yan, Hongfei; Fu, Shanliang; Dai, Hua

2013-03-01

An efficient and sensitive multiresidue method has been developed for quantification and confirmation of 25 phenyl acetanilide pesticides in a wide variety of food commodities including maize, spinach, mushroom, apple, soybean, chestnut, tea, beef, cattle liver, chicken, fish, and milk. Analytes were extracted with acetone-n-hexane (1:2, v/v) followed by cleanup using SPE. Several types of adsorbents were evaluated. Neutral aluminum and graphitized carbon black cartridge showed good cleanup efficiency. The extract was determined by GC-MS in the selected ion monitoring mode using one target and two qualitative ions for each analyte. The limits of detection were 0.01 mg/kg for all analytes. The average recoveries ranged from 66.9 to 110.6% (mean 88.8%) and RSDs were in the range 2.0-19% (mean 10.5%) across three fortification levels. The proposed method was successfully applied to real samples in routine analysis and a satisfactory result was obtained. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Online Hazardous Waste Cleanup Technical Resources

EPA Pesticide Factsheets

This issue paper is intended to give the reader examples of some online technical resources that can assist with hazardous waste cleanups in the Superfund, Resource Conservation and Recovery Act (RCRA), and Brownfields programs.

EPA waiver of ground water cleanup standards in NY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hess, A.A.

1995-11-01

EPA may invoke a technical impracticability (TI) waiver at a site when the Agency determines that it is technically impracticable from an engineering perspective to attain cleanup standards within a reasonable time period. The October 6, 1994 TI waiver of ground water cleanup standards at the G.E./Moreau Superfund Site in New York is the first post-Record of Decision (ROD) TI waiver granted by EPA since issuance of the September 1993 guidance on technical impracticability of ground water restoration. In the 1987 ROD, EPA selected natural gradient flushing and treatment as the ground water remedy and estimated that TCE-contaminated ground watermore » within the unconsolidated aquifer at the Site would be restored to drinking water quality within decades. EPA`s subsequent reevaluation showed that cleanup of the ground water would take 200 years or more, regardless of the remedial technology employed, due to the presence of site-specific physical and chemical factors that limit the effectiveness of ground water remediation technologies. Following public participation activities, EPA issued the TI waiver as an Explanation of Significant Differences (ESD) to the ROD. The ESD revised the time frame expected for ground water restoration but did not reduce or change any of the required cleanup actions.« less

A Citizen's Guide to Drycleaner Cleanup

EPA Pesticide Factsheets

The State Coalition for Remediation of Drycleaners (SCRD) has prepared an easy-to-read guide explaining the drycleaner cleanup process and describing the technologies that are most commonly used to clean up contaminated drycleaner sites.

Ebullitive methane emissions from oxygenated wetland streams

USGS Publications Warehouse

Crawford, John T.; Stanley, Emily H.; Spawn, Seth A.; Finlay, Jacques C.; Striegl, Robert G.

2014-01-01

Stream and river carbon dioxide emissions are an important component of the global carbon cycle. Methane emissions from streams could also contribute to regional or global greenhouse gas cycling, but there are relatively few data regarding stream and river methane emissions. Furthermore, the available data do not typically include the ebullitive (bubble-mediated) pathway, instead focusing on emission of dissolved methane by diffusion or convection. Here, we show the importance of ebullitive methane emissions from small streams in the regional greenhouse gas balance of a lake and wetland-dominated landscape in temperate North America and identify the origin of the methane emitted from these well-oxygenated streams. Stream methane flux densities from this landscape tended to exceed those of nearby wetland diffusive fluxes as well as average global wetland ebullitive fluxes. Total stream ebullitive methane flux at the regional scale (103 Mg C yr−1; over 6400 km2) was of the same magnitude as diffusive methane flux previously documented at the same scale. Organic-rich stream sediments had the highest rates of bubble release and higher enrichment of methane in bubbles, but glacial sand sediments also exhibited high bubble emissions relative to other studied environments. Our results from a database of groundwater chemistry support the hypothesis that methane in bubbles is produced in anoxic near-stream sediment porewaters, and not in deeper, oxygenated groundwaters. Methane interacts with other key elemental cycles such as nitrogen, oxygen, and sulfur, which has implications for ecosystem changes such as drought and increased nutrient loading. Our results support the contention that streams, particularly those draining wetland landscapes of the northern hemisphere, are an important component of the global methane cycle.

Chronic Lymphocytic Leukemia in Chornobyl Cleanup Workers.

PubMed

Bazyka, Dimitry; Gudzenko, Natalya; Dyagil, Iryna; Goroh, Eugeny; Polyschuk, Oksana; Trotsuk, Natalya; Babkina, Nataly; Romanenko, Anatoly

2016-08-01

This paper describes the chronic lymphocytic leukemia (CLL) incidence in a cohort of 110,645 (enlarged later to 152,520) male Ukrainian cleanup workers of the Chornobyl (Chernobyl) accident who were exposed to a range of radiation doses over the 1986-1990 time period. The standardized incidence rates are presented for a 27-y period after the exposure. For 2007-2012 period, the authors have identified the incident CLL cases in an enlarged cohort of 152,520 persons by linkage of the cohort file with the Ukrainian National Cancer Registry (NCRU). CLL data for the previous period (1987-2006) were identified in a frame of the Ukrainian-American leukemia study in the original cohort of 110,645 male clean-up workers. A significant CLL incidence excess was shown for the entire study period 1987-2012, with more prominent levels for the earliest years (1987-1996) when the standardized incidence rate (SIR) value was estimated to be 3.61 with 95% confidence interval from 2.32 to 4.91. In 2007-2012, the CLL incidence decreased substantially but still exceeded the national level although not significantly. In parallel, the several studies were performed at the National Research Center for Radiation Medicine (NRCRM) to explore if any clinical and cytogenetic features of CLL existed in the clean-up workers. The clinical study included 80 exposed and 70 unexposed CLL cases. Among the major clinical differences of the CLL course in the clean-up workers were a shorter period of white blood cells (WBC) doubling (10.7 vs. 18.0; p<0.001), frequent infectious episodes, lymphoadenopathy and hepatosplenomegaly (37 vs. 16), higher expression for CD38, and lower expression for ZAP-70 antigen.

A novel polymer inclusion membrane based method for continuous clean-up of thiocyanate from gold mine tailings water.

PubMed

Cho, Youngsoo; Cattrall, Robert W; Kolev, Spas D

2018-01-05

Thiocyanate is present in gold mine tailings waters in concentrations up to 1000mgL -1 and this has a serious environmental impact by not allowing water reuse in the flotation of gold ore. This significantly increases the consumption of fresh water and the amount of wastewater discharged in tailings dams. At the same time thiocyanate in tailings waters often leads to groundwater contamination. A novel continuous membrane-based method for the complete clean-up of thiocyanate in concentrations as high as 1000mgL -1 from its aqueous solutions has been developed. It employs a flat sheet polymer inclusion membrane (PIM) of composition 70wt% PVC, 20wt% Aliquat 336 and 10wt% 1-tetradecanol which separates counter-current streams of a feed thiocyanate solution and a 1M NaNO 3 receiving solution. The PIM-based system has been operated continuously for 45days with 99% separation efficiency. The volume of the receiving solution has been drastically reduced by recirculating it and continuously removing thiocyanate by precipitating it with in-situ generated Cu(I). The newly developed PIM-based thiocyanate clean-up method is environmentally friendly in terms of reagent use and inexpensive with respect to both equipment and running costs. Copyright © 2017 Elsevier B.V. All rights reserved.

Mental disorders among Chernobyl cleanup workers from Estonia: A clinical assessment.

PubMed

Laidra, Kaia; Rahu, Kaja; Kalaus, Katri-Evelin; Tekkel, Mare; Leinsalu, Mall

2017-08-01

To assess, at a clinical level, the mental health of former Chernobyl cleanup workers from Estonia by comparing them with same-age controls. The Mini International Neuropsychiatric Interview (MINI) was administered during 2011-2012 to 99 cleanup workers and 100 population-based controls previously screened for mental health symptoms. Logistic regression analysis showed that cleanup workers had higher odds of current depressive disorder (odds ratio [OR] = 3.07, 95% confidence interval [CI: 1.34, 7.01]), alcohol dependence (OR = 3.47, 95% CI [1.29, 9.34]), and suicide ideation (OR = 3.44, 95% CI [1.28, 9.21]) than did controls. Except for suicide ideation, associations with Chernobyl exposure became statistically nonsignificant when adjusted for education and ethnicity. A quarter of a century after the Chernobyl accident, Estonian cleanup workers were still at increased risk of mental disorders, which was partly attributable to sociodemographic factors. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

Successful implementation of property cleanup under the Ohio and the Texas voluntary programs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roffman, A.

1999-07-01

Cleanups of two properties, one located in Ohio and the other in Texas were successfully implemented. The facilities were printing plants that manufactured printed material and forms for commercial and industrial use. Primary products and chemicals involved in the manufacturing of the forms included ink, petroleum products and cleaning solvents. The Ohio property underwent a successful cleanup under the Ohio EPA Voluntary Action Program (VAP). It met the Ohio EPA residential land use cleanup standards for soil and shallow groundwater. A No Further Action letter has been submitted to the state and it resulted in the issuance of a Covenantmore » Not to Sue. The Texas facility underwent a successful cleanup under the Texas Natural Resource Conservation Commission (TNRCC) Voluntary Cleanup Program (VCP). It resulted in the issuance of a Certificate of Completion (COC) for residential land use for soil, and a conditional COC for industrial land use for the shallow groundwater.« less

The Great Oil Spill Cleanup Contest.

ERIC Educational Resources Information Center

Hampton, Elaine

1993-01-01

Presents an exciting way to acquaint students with current methods to clean up oil spills. Students also have the freedom to create new clean-up methods as they think through the problem and experiment to find effective solutions. (PR)

High temperature desulfurization of synthesis gas

DOEpatents

Najjar, Mitri S.; Robin, Allen M.

1989-01-01

The hot process gas stream from the partial oxidation of sulfur-containing heavy liquid hydrocarbonaceous fuel and/or sulfur-containing solid carbonaceous fuel comprising gaseous mixtures of H.sub.2 +CO, sulfur-containing gases, entrained particulate carbon, and molten slag is passed through the unobstructed central passage of a radiant cooler where the temperature is reduced to a temperature in the range of about 1800.degree. F. to 1200.degree. F. From about 0 to 95 wt. % of the molten slag and/or entrained material may be removed from the hot process gas stream prior to the radiant cooler with substantially no reduction in temperature of the process gas stream. In the radiant cooler, after substantially all of the molten slag has solidified, the sulfur-containing gases are contacted with a calcium-containing material to produce calcium sulfide. A partially cooled stream of synthesis gas, reducing gas, or fuel gas containing entrained calcium sulfide particulate matter, particulate carbon, and solidified slag leaves the radiant cooler containing a greatly reduced amount of sulfur-containing gases.

Great cleanup skims the surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dillingham, S.

1990-09-03

Appalled by the pollution of the Great Lakes, the United States embarked on a multibillion-dollar cleanup. Twenty years later the nation's largest freshwater source is teeming with life, but problems caused by man and nature remain. Amid the finger-pointing, states in the region and Congress are continuing to clean up the mess.

Streamlining Site Cleanup in New York City

EPA Pesticide Factsheets

This joint effort, supported by the New York State Department of Environmental Conservation (NYS DEC), advances the environmental cleanup goals of PlaNYC 2030, the city's comprehensive sustainability plan.

HANDBOOK ON THE BENEFITS, COSTS, AND IMPACTS OF LAND CLEANUP AND REUSE

EPA Science Inventory

Summarizes the theoretical and empirical literature addressing benefit-cost and impact assessment of the land cleanup and reuse scenario. When possible, recommendations are provided for conducting economic analysis of land cleanup and reuse sites and programs. The knowledge base ...

HST Spatially Resolved Spectra of the Accretion Disc and Gas Stream of the Nova-Like Variable UX Ursae Majoris

NASA Technical Reports Server (NTRS)

Baptista, Raymundo; Horne, Keith; Wade, Richard A.; Hubeny, Ivan; Long, Knox S.; Rutten, Rene G. M.

1998-01-01

Time-resolved eclipse spectroscopy of the nova-like variable UX UMa obtained with the Hubble Space Telescope/Faint Object Spectrograph (HST/FOS) on 1994 August and November is analysed with eclipse mapping techniques to produce spatially resolved spectra of its accretion disk and gas stream as a function of distance from the disk centre. The inner accretion disk is characterized by a blue continuum filled with absorption bands and lines, which cross over to emission with increasing disk radius, similar to that reported at optical wavelengths. The comparison of spatially resolved spectra at different azimuths reveals a significant asymmetry in the disk emission at ultraviolet (UV) wavelengths, with the disk side closest to the secondary star showing pronounced absorption by an 'iron curtain' and a Balmer jump in absorption. These results suggest the existence of an absorbing ring of cold gas whose density and/or vertical scale increase with disk radius. The spectrum of the infalling gas stream is noticeably different from the disc spectrum at the same radius suggesting that gas overflows through the impact point at the disk rim and continues along the stream trajectory, producing distinct emission down to 0.1 R(sub LI). The spectrum of the uneclipsed light shows prominent emission lines of Lyalpha, N v lambda1241, SiIV Lambda 1400, C IV Lambda 1550, HeII Lambda 1640, and MgII Lambda 2800, and a UV continuum rising towards longer wavelengths. The Balmer jump appears clearly in emission indicating that the uneclipsed light has an important contribution from optically thin gas. The lines and optically thin continuum emission are most probably emitted in a vertically extended disk chromosphere + wind. The radial temperature profiles of the continuum maps are well described by a steady-state disc model in the inner and intermediate disk regions (R greater than or equal to 0.3R(sub LI) ). There is evidence of an increase in the mass accretion rate from August to November

Ultrasonication extraction and gel permeation chromatography clean-up for the determination of polycyclic aromatic hydrocarbons in edible oil by an isotope dilution gas chromatography–mass spectrometry.

PubMed

Wang, Jian-Hua; Guo, Cui

2010-07-09

An analytical method for the determination of US EPA priority pollutant 16 polycyclic aromatic hydrocarbons (PAHs) in edible oil was developed by an isotope dilution gas chromatography-mass spectrometry (GC-MS). Extraction was performed with ultrasonication mode using acetonitrile as solvent, and subsequent clean-up was applied using narrow gel permeation chromatographic column. Three deuterated PAHs surrogate standards were used as internal standards for quantification and analytical quality control. The limits of quantification (LOQs) were globally below 0.5 ng/g, the recoveries were in the range of 81-96%, and the relative standard deviations (RSDs) were lower than 20%. Further trueness assessment of the method was also verified through participation in international cocoa butter proficiency test (T0638) organised by the FAPAS with excellent results in 2008. The results obtained with the described method were satisfying (z ≤ 2). The method has been applied to determine PAH in real edible oil samples.

Mental health and alcohol problems among Estonian cleanup workers 24 years after the Chernobyl accident.

PubMed

Laidra, Kaia; Rahu, Kaja; Tekkel, Mare; Aluoja, Anu; Leinsalu, Mall

2015-11-01

To study the long-term mental health consequences of the 1986 Chernobyl nuclear accident among cleanup workers from Estonia. In 2010, 614 Estonian Chernobyl cleanup workers and 706 geographically and age-matched population-based controls completed a mail survey that included self-rated health, the Posttraumatic Stress Disorder Checklist (PCL), alcohol symptoms (AUDIT), and scales measuring depressive, anxiety, agoraphobia, fatigue, insomnia, and somatization symptoms. Respondents were dichotomized into high (top quartile) and low symptom groups on each measure. Logistic regression analysis detected significant differences between cleanup workers and controls on all measures even after adjustment for ethnicity, education, marital status, and employment status. The strongest difference was found for somatization, with cleanup workers being three times more likely than controls to score in the top quartile (OR = 3.28, 95% CI 2.39-4.52), whereas for alcohol problems the difference was half as large (OR = 1.52, 95% CI 1.16-1.99). Among cleanup workers, arrival at Chernobyl in 1986 (vs. later) was associated with sleep problems, somatization, and symptoms of agoraphobia. The toll of cleanup work was evident 24 years after the Chernobyl accident among Estonian cleanup workers indicating the need for focused mental health interventions.

Evaluation of beach cleanup effects using linear system analysis.

PubMed

Kataoka, Tomoya; Hinata, Hirofumi

2015-02-15

We established a method for evaluating beach cleanup effects (BCEs) based on a linear system analysis, and investigated factors determining BCEs. Here we focus on two BCEs: decreasing the total mass of toxic metals that could leach into a beach from marine plastics and preventing the fragmentation of marine plastics on the beach. Both BCEs depend strongly on the average residence time of marine plastics on the beach (τ(r)) and the period of temporal variability of the input flux of marine plastics (T). Cleanups on the beach where τ(r) is longer than T are more effective than those where τ(r) is shorter than T. In addition, both BCEs are the highest near the time when the remnants of plastics reach the local maximum (peak time). Therefore, it is crucial to understand the following three factors for effective cleanups: the average residence time, the plastic input period and the peak time. Copyright © 2014 Elsevier Ltd. All rights reserved.

40 CFR 761.366 - Cleanup equipment.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Cleanup equipment. 761.366 Section 761.366 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT POLYCHLORINATED BIPHENYLS (PCBs) MANUFACTURING, PROCESSING, DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS Double...

Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

DOEpatents

Clawson, Lawrence G.; Mitchell, William L.; Bentley, Jeffrey M.; Thijssen, Johannes H. J.

2000-01-01

A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

Increased leukemia risk in Chernobyl cleanup workers

Cancer.gov

A new study found a significantly elevated risk for chronic lymphocytic leukemia among workers who were engaged in recovery and clean-up activities following the Chernobyl power plant accident in 1986.

Radiation Dose to Post-Chernobyl Cleanup Workers

Cancer.gov

Radiation dose calculation for post-Chernobyl Cleanup Workers in Ukraine - both external radiation exposure due to fallout and internal doses due to inhalation (I131 intake) or ingestion of contaminated foodstuffs.

NANOMATERIAL SOLUTIONS FOR HOT COAL GAS CLEANUP - PHASE I

EPA Science Inventory

Integrated gasification combined cycle (IGCC) is a new coal gasification technique that efficiently uses the hot (900-1500°C) generated syngas to power both steam and gas turbines. Due to regulations, this syngas must be free of sulfur and purification is normally carried ...

Clean-up and disposal process of polluted sediments from urban rivers.

PubMed

He, P J; Shao, L M; Gu, G W; Bian, C L; Xu, C

2001-10-01

In this paper, the discussion is concentrated on the properties of the polluted sediments and the combination of clean-up and disposal process for the upper layer heavily polluted sediments with good flowability. Based on the systematic analyses of various clean-up processes, a suitable engineering process has been evaluated and recommended. The process has been applied to the river reclamation in Yangpu District of Shanghai City, China. An improved centrifuge is used for dewatering the dredged sludge, which plays an important role in the combination of clean-up and disposal process. The assessment of the engineering process shows its environmental and technical economy feasibility, which is much better than that of traditional dredging-disposal processes.

Cleanup Verification Package for the 118-F-5 PNL Sawdust Pit

DOE Office of Scientific and Technical Information (OSTI.GOV)

L. D. Habel

2008-05-20

This cleanup verification package documents completion of remedial action, sampling activities, and compliance with cleanup criteria for the 118-F-5 Burial Ground, the PNL (Pacific Northwest Laboratory) Sawdust Pit. The 118-F-5 Burial Ground was an unlined trench that received radioactive sawdust from the floors of animal pens in the 100-F Experimental Animal Farm.

Integrated low emissions cleanup system for direct coal-fueled turbines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lippert, T.E.; Newby, R.A.; Alvin, M.A.

1992-01-01

The Westinghouse Electric Corporation, Science Technology Center (W-STC) is developing an Integrated Low Emissions Cleanup (ILEC) concept for high-temperature gas cleaning to meet environmental standards, as well as to economical gas turbine life. The ILEC concept simultaneously controls sulfur, particulate, and alkali contaminants in high-pressure fuel gases or combustion gases at temperatures up to 1850[degrees]F for advanced power generation systems (PFBC, APFBC, IGCC, DCF7). The objective of this program is to demonstrate, at a bench scale, the conceptual, technical feasibility of the REC concept. The ELEC development program has a 3 phase structure: Phase 1 - laboratory-scale testing; phase 2more » - bench-scale equipment; design and fabrication; and phase 3 - bench-scale testing. Phase 1 laboratory testing has been completed. In Phase 1, entrained sulfur and alkali sorbent kinetics were measured and evaluated, and commercial-scale performance was projected. Related cold flow model testing has shown that gas-particle contacting within the ceramic barrier filter vessel will provide a good reactor environment. The Phase 1 test results and the commercial evaluation conducted in the Phase 1 program support the bench-scale facility testing to be performed in Phase 3. Phase 2 is nearing completion with the design and assembly of a modified, bench-scale test facility to demonstrate the technical feasibility of the ILEC features. This feasibility testing will be conducted in Phase 3.« less

Integrated low emissions cleanup system for direct coal-fueled turbines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lippert, T.E.; Newby, R.A.; Alvin, M.A.

1992-12-31

The Westinghouse Electric Corporation, Science & Technology Center (W-STC) is developing an Integrated Low Emissions Cleanup (ILEC) concept for high-temperature gas cleaning to meet environmental standards, as well as to economical gas turbine life. The ILEC concept simultaneously controls sulfur, particulate, and alkali contaminants in high-pressure fuel gases or combustion gases at temperatures up to 1850{degrees}F for advanced power generation systems (PFBC, APFBC, IGCC, DCF7). The objective of this program is to demonstrate, at a bench scale, the conceptual, technical feasibility of the REC concept. The ELEC development program has a 3 phase structure: Phase 1 - laboratory-scale testing; phasemore » 2 - bench-scale equipment; design and fabrication; and phase 3 - bench-scale testing. Phase 1 laboratory testing has been completed. In Phase 1, entrained sulfur and alkali sorbent kinetics were measured and evaluated, and commercial-scale performance was projected. Related cold flow model testing has shown that gas-particle contacting within the ceramic barrier filter vessel will provide a good reactor environment. The Phase 1 test results and the commercial evaluation conducted in the Phase 1 program support the bench-scale facility testing to be performed in Phase 3. Phase 2 is nearing completion with the design and assembly of a modified, bench-scale test facility to demonstrate the technical feasibility of the ILEC features. This feasibility testing will be conducted in Phase 3.« less

Investigation of the trajectories and length of combustible gas jet flames in a sweeping air stream

NASA Astrophysics Data System (ADS)

Polezhaev, Yu. V.; Mostinskii, I. L.; Lamden, D. I.; Stonik, O. G.

2011-05-01

The trajectories of round gas jets and jet flames introduced into a sweeping air stream are studied. The influence of various initial conditions and of the physical properties of gases on the trajectory is considered. Experimental verification of the available approximation relations for the trajectories of flames in a wide range of the values of the blowing ratio has been carried out. It is shown that the newly obtained experimental approximation of the trajectory shape differs from the existing ones by about 20%. At small values of the blowing ratio (smaller than ~4.5) the flame trajectories cease to depend on it.

Methods of hydrotreating a liquid stream to remove clogging compounds

DOEpatents

Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

2009-09-22

A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

Patterns of hematological malignancies in Chernobyl clean-up workers (1996-2005).

PubMed

Gluzman, D; Imamura, N; Sklyarenko, L; Nadgornaya, V; Zavelevich, M; Machilo, V

2006-03-01

The question as to whether the incidence of leukemias and malignant lymphomas among the Chernobyl clean-up workers increased in 20 years after the catastrophe is still a point of much controversy. Precise diagnosis of the main forms of hematopoietic malignancies according to FAB classification and new WHO classification and comparison of these data with that in the general population will be helpful in estimating the relative contribution of the radiation factor to the overall incidence of such pathologies. The data on 218 consecutive cases of malignant diseases of hematopoietic and lymphoid tissues in Chernobyl clean-up workers diagnosed in 1996-2005 are given in comparison with the data of 2697 consecutive patients of general population of the same age group. The morphology and cytochemistry of bone marrow and peripheral blood cells were studied. Immunocytochemical techniques (APAAP, LSAB-AP) and the broad panel of monoclonal antibodies to lineage specific and differentiation antigens of leukocytes were employed for immunophenotyping leukemic cells. Various types of oncohematological diseases developing 10-20 years after Chernobyl accident were registered in a group of clean-up workers under study including myelodysplastic syndromes (MDS), acute leukemias (ALL and AML), chronic myelogenous leukemia (CML) and other chronic myeloproliferative diseases, chronic lymphocytic leukemia (B-CLL) and other chronic lymphoproliferative diseases of B and T cell origin. MDS percentage among patients of clean-up workers group tended to exceed MDS percentage in the group of patients representing the general population examined at the same period (4.58 vs. 3.70%). Among 34 AML cases, leukemia was preceded by MDS in seven patients. The relative contribution of CML to the total number of clean-up workers with leukemia was higher than the corresponding percentage value in general population examined at the same period (9.17 vs. 6.59%). B-CLL was a predominant form of hematopoietic

Stability analysis applied to the early stages of viscous drop breakup by a high-speed gas stream

NASA Astrophysics Data System (ADS)

Padrino, Juan C.; Longmire, Ellen K.

2013-11-01

The instability of a liquid drop suddenly exposed to a high-speed gas stream behind a shock wave is studied by considering the gas-liquid motion at the drop interface. The discontinuous velocity profile given by the uniform, parallel flow of an inviscid, compressible gas over a viscous liquid is considered, and drop acceleration is included. Our analysis considers compressibility effects not only in the base flow, but also in the equations of motion for the perturbations. Recently published high-resolution images of the process of drop breakup by a passing shock have provided experimental evidence supporting the idea that a critical gas dynamic pressure can be found above which drop piercing by the growth of acceleration-driven instabilities gives way to drop breakup by liquid entrainment resulting from the gas shearing action. For a set of experimental runs from the literature, results show that, for shock Mach numbers >= 2, a band of rapidly growing waves forms in the region well upstream of the drop's equator at the location where the base flow passes from subsonic to supersonic, in agreement with experimental images. Also, the maximum growth rate can be used to predict the transition of the breakup mode from Rayleigh-Taylor piercing to shear-induced entrainment. The authors acknowledge support of the NSF (DMS-0908561).

Tribal Lands Cleanup and Spill Prevention Programs

EPA Pesticide Factsheets

EPA takes strides to prevent and cleanup contamination and contaminated sites located on or near Tribal lands. Our programs work hand-in-hand with tribes to ensure we protect their health and the environment.

Feed gas contaminant removal in ion transport membrane systems

DOEpatents

Carolan, Michael Francis [Allentown, PA; Miller, Christopher Francis [Macungie, PA

2008-09-16

Method for gas purification comprising (a) obtaining a feed gas stream containing one or more contaminants selected from the group consisting of volatile metal oxy-hydroxides, volatile metal oxides, and volatile silicon hydroxide; (b) contacting the feed gas stream with a reactive solid material in a guard bed and reacting at least a portion of the contaminants with the reactive solid material to form a solid reaction product in the guard bed; and (c) withdrawing from the guard bed a purified gas stream.

Method for removing metal vapor from gas streams

DOEpatents

Ahluwalia, R.K.; Im, K.H.

1996-04-02

A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

Method for removing metal vapor from gas streams

DOEpatents

Ahluwalia, R. K.; Im, K. H.

1996-01-01

A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

Louisiana waterthrush and benthic macroinvertebrate response to shale gas development

USGS Publications Warehouse

Wood, Petra; Frantz, Mack W.; Becker, Douglas A.

2016-01-01

Because shale gas development is occurring over large landscapes and consequently is affecting many headwater streams, an understanding of its effects on headwater-stream faunal communities is needed. We examined effects of shale gas development (well pads and associated infrastructure) on Louisiana waterthrush Parkesia motacilla and benthic macroinvertebrate communities in 12 West Virginia headwater streams in 2011. Streams were classed as impacted (n = 6) or unimpacted (n = 6) by shale gas development. We quantified waterthrush demography (nest success, clutch size, number of fledglings, territory density), a waterthrush Habitat Suitability Index, a Rapid Bioassessment Protocol habitat index, and benthic macroinvertebrate metrics including a genus-level stream-quality index for each stream. We compared each benthic metric between impacted and unimpacted streams with a Student's t-test that incorporated adjustments for normalizing data. Impacted streams had lower genus-level stream-quality index scores; lower overall and Ephemeroptera, Plecoptera, and Trichoptera richness; fewer intolerant taxa, more tolerant taxa, and greater density of 0–3-mm individuals (P ≤ 0.10). We then used Pearson correlation to relate waterthrush metrics to benthic metrics across the 12 streams. Territory density (no. of territories/km of stream) was greater on streams with higher genus-level stream-quality index scores; greater density of all taxa and Ephemeroptera, Plecoptera, and Trichoptera taxa; and greater biomass. Clutch size was greater on streams with higher genus-level stream-quality index scores. Nest survival analyses (n = 43 nests) completed with Program MARK suggested minimal influence of benthic metrics compared with nest stage and Habitat Suitability Index score. Although our study spanned only one season, our results suggest that shale gas development affected waterthrush and benthic communities in the headwater streams we studied. Thus, these ecological effects of

An improved dispersive solid-phase extraction clean-up method for the gas chromatography-negative chemical ionisation tandem mass spectrometric determination of multiclass pesticide residues in edible oils.

PubMed

Deme, Pragney; Azmeera, Tirupathi; Prabhavathi Devi, B L A; Jonnalagadda, Padmaja R; Prasad, R B N; Vijaya Sarathi, U V R

2014-01-01

An improved sample preparation using dispersive solid-phase extraction clean-up was proposed for the trace level determination of 35 multiclass pesticide residues (organochlorine, organophosphorus and synthetic pyrethroids) in edible oils. Quantification of the analytes was carried out by gas chromatography-mass spectrometry in negative chemical ionisation mode (GC-NCI-MS/MS). The limit of detection and limit of quantification of residues were in the range of 0.01-1ng/g and 0.05-2ng/g, respectively. The analytes showed recoveries between 62% and 110%, and the matrix effect was observed to be less than 25% for most of the pesticides. Crude edible oil samples showed endosulfan isomers, p,p'-DDD, α-cypermethrin, chlorpyrifos, and diazinon residues in the range of 0.56-2.14ng/g. However, no pesticide residues in the detection range of the method were observed in refined oils. Copyright © 2013 Elsevier Ltd. All rights reserved.

Amounts and activity concentrations of radioactive wastes from the cleanup of large areas contaminated in nuclear accidents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lehto, J.; Ikaeheimonen, T.K.; Salbu, B.

The fallout from a major nuclear accident at a nuclear plant may result in a wide-scale contamination of the environment. Cleanup of contaminated areas is of special importance if these areas are populated or cultivated. All cleanup measures generate high amounts of radioactive waste, which have to be treated and disposed of in a safe manner. Scenarios assessing the amounts and activity concentrations of radioactive wastes for various cleanup measures after severe nuclear accidents have been worked out for urban, forest and agricultural areas. These scenarios are based on contamination levels and ares of contaminated lands from a model accident,more » which simulates a worst case accident at a nuclear power plant. Amounts and activity concentrations of cleanup wastes are not only dependent on the contamination levels and areas of affected lands, but also on the type of deposition, wet or dry, on the time between the deposition and the cleanup work, on the season, at which the deposition took place, and finally on the level of cleanup work. In this study practically all types of cleanup wastes were considered, whether or not the corresponding cleanup measures are cost-effective or justified. All cleanup measures are shown to create large amounts of radioactive wastes, but the amounts, as well as the activity concentrations vary widely from case to case.« less

Epidemiology of Late Health Effects in Ukrainian Chornobyl Cleanup Workers.

PubMed

Bazyka, Dimitry; Prysyazhnyuk, Anatoly; Gudzenko, Natalya; Dyagil, Iryna; Belyi, David; Chumak, Vadim; Buzunov, Volodymyr

2018-07-01

This article summarizes the results of 30 y of follow-up of cancer and noncancer effects in Ukrainian cleanup workers after the Chornobyl accident. The number of power plant employees and first responders with acute radiation syndrome under follow-up by the National Research Center for Radiation Medicine decreased from 179 in 1986-1991 to 105 in 2011-2015. Cancers and leukemia (19) and cardiovascular diseases (21) were the main causes of deaths among acute radiation syndrome survivors (54) during the postaccident period. Increased radiation risks of leukemia in the Ukrainian cohort of 110,645 cleanup workers exposed to low doses are comparable to those among survivors of the atomic bomb explosions in Japan in 1945. Additionally, an excess of chronic lymphocytic leukemia was demonstrated in the cleanup workers cohort for 26 y after the exposure. A significant excess of multiple myeloma incidence [standardized incidence rate (SIR) 1.61 %, 95% confidence interval (CI) 1.01-2.21], thyroid cancer (SIR 4.18, 95% CI 3.76-4.59), female breast cancer (SIR 1.57 CI 1.40-1.73), and all cancers combined (SIR 1.07; 95% CI 1.05-1.09) was registered. High prevalence was demonstrated for cardio- and cerebrovascular diseases and mental health changes. However, the reasons for the increases require further investigation. To monitor other possible late effects of radiation exposure in Chornobyl cleanup workers, analytical cohort and case-control studies need to include cardiovascular pathology, specifically types of potentially radiogenic cancers using a molecular epidemiology approach. Possible effects for further study include increased rates of thyroid, breast, and lung cancers and multiple myeloma; reduction of radiation risks of leukemia to population levels; and increased morbidity and mortality of cleanup workers from cardio- and cerebrovascular pathology.

Data on Oil, Gas and Other Wells in New York State - NYS Dept. of

Science.gov Websites

Site Cleanup Water Air Pesticides Oil & Gas Wells and Mining Regulatory Regulations Permits and ): Search DEC D E C banner Home » Energy and Climate » Oil and Gas » Data on Oil, Gas and Other Wells in New York State Skip to main navigation Data on Oil, Gas and Other Wells in New York State The

A modified extraction and clean-up procedure for the detection and determination of parathion-methyl and chlorpyrifos residues in tea.

PubMed

Shanker, A; Sood, C; Kumar, V; Ravindranath, S D

2001-05-01

Recent advances in methodology and instrumentation have made possible the detection and determination of pesticides at microgram kg-1 (ppb) levels. The sensitivity of a method of analysis depends greatly on the efficient extraction of the pesticide and the subsequent clean-up of the extract. The extract from green tea leaves is a mixture of aroma components, polyphenols and caffeine. The preparation of made tea from green tea leaves adds to this complexity by concentrating these coextractives. Conventional clean-up techniques provide poor recoveries for parathion-methyl and chlorpyrifos from both green tea leaves and made tea. This arises from interference by caffeine during gas chromatography, as it has a similar retention time to the two pesticides and peaks overlap. A modification to the protocol based on a solvent partitioning process using dichloromethane and subsequent washing of the extracts with warm water removed the caffeine, and pigments were removed by column chromatography. Recoveries ranging from 80 to 90% were then obtained for both pesticides.

Influence of infrastructure on water quality and greenhouse gasdynamics in urban streams

EPA Science Inventory

Streams and rivers are significant sources of nitrous oxide (N2O), carbon dioxide (CO2), and methane (CH4), and watershed management can alter greenhouse gas emissions from streams. GHG emissions from streams in agricultural watersheds have been investigated in numerous studies,...

CO2 and CH4 emissions from streams in a lake-rich landscape: Patterns, controls, and regional significance

USGS Publications Warehouse

Crawford, John T.; Lottig, Noah R.; Stanley, Emily H.; Walker, John F.; Hanson, Paul C.; Finlay, Jacques C.; Striegl, Robert G.

2014-01-01

Aquatic ecosystems are important components of landscape carbon budgets. In lake-rich landscapes, both lakes and streams may be important sources of carbon gases (CO2 and CH4) to the atmosphere, but the processes that control gas concentrations and emissions in these interconnected landscapes have not been adequately addressed. We use multiple data sets that vary in their spatial and temporal extent during 2001–2012 to investigate the carbon gas source strength of streams in a lake-rich landscape and to determine the contribution of lakes, metabolism, and groundwater to stream CO2 and CH4. We show that streams emit roughly the same mass of CO2 (23.4 Gg C yr−1; 0.49 mol CO2 m−2 d−1) as lakes at a regional scale (27 Gg C yr−1) and that stream CH4 emissions (189 Mg C yr−1; 8.46 mmol CH4 m−2 d−1) are an important component of the regional greenhouse gas balance. Gas transfer velocity variability (range = 0.34 to 13.5 m d−1) contributed to the variability of gas flux in this landscape. Groundwater inputs and in-stream metabolism control stream gas supersaturation at the landscape scale, while carbon cycling in lakes and deep groundwaters does not control downstream gas emissions. Our results indicate the need to consider connectivity of all aquatic ecosystems (lakes, streams, wetlands, and groundwater) in lake-rich landscapes and their connections with the terrestrial environment in order to understand the full nature of the carbon cycle.

Jovian Jet Stream

NASA Image and Video Library

2018-05-31

See a jet stream speeding through Jupiter's atmosphere in this new view taken by NASA's Juno spacecraft. The jet stream, called Jet N2, was captured along the dynamic northern temperate belts of the gas giant planet. It is the white stream visible from top left to bottom right in the image. The color-enhanced image was taken at 10:34 p.m. PST on May 23 (1:34 a.m. EST on May 24), as Juno performed its 13th close flyby of Jupiter. At the time the image was taken, the spacecraft was about 3,516 miles (5,659 kilometers) from the tops of the clouds of the planet at a northern latitude of 32.9 degrees. Citizen scientists Gerald Eichstädt and Seán Doran created this image using data from the spacecraft's JunoCam imager. The view is a composite of several separate JunoCam images that were re-projected, blended, and healed. https://photojournal.jpl.nasa.gov/catalog/PIA22422

PFB coal fired combined cycle development program. Advanced hot gas cleanup concept evaluation (Task 4. 3). Volume A. Aerodyne cyclone evaluation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This report summarizes the results of testing of a rotary flow cyclone, manufactured by Aerodyne Development Corporation under license by Siemens Kraftwerk Union. This cyclone was selected for evaluation due to the unusually high separative efficiencies claimed by the manufacturer (based on developer data), and relative lack of open literature data. The most significant finding of this work was the observation that electrostatic forces could enhance or, in fact, dominate the separation process. Separative efficiencies, with electrostatic forces present, were found to be substantially independent of flow rate and, by inference, could be independent of unit size. This finding suggestsmore » that large cyclones with natural or augmented electrostatic forces employed in the hot gas cleanup train of the CFCC system may not suffer the performance degradation compared to small cyclones, as projected from conventional inertial theory. This is of special importance since the use of many small cyclones in parallel, or multicyclones, commonly suffers from fouling and this approach is not recommended in the CFCC application. The original objective of this investigation was to assess the relative merits of the Aerodyne cyclone separator. It was found from both the cold flow and the hot flow tests that its separative efficiencies are disappointingly poorer than expectations (in agreement with Westinghouse results), and even poorer than conventional cyclones.« less

Doses of Ukrainian female clean-up workers with diagnosed breast cancer.

PubMed

Chumak, Vadim V; Klymenko, Sergiy V; Zitzelsberger, Horst; Wilke, Christina; Rybchenko, Lyudmila A; Bakhanova, Elena V

2018-05-01

The Chernobyl reactor accident in 1986 has caused significant exposure to ionizing radiation of the Ukrainian population, in particular clean-up workers and evacuees from the exclusion zones. A study aiming at the discovery of radiation markers of the breast cancer was conducted from 2008 to 2015 within a collaborative project by HZM, LMU, and NRCRM. In this study, post-Chernobyl breast cancer cases both in radiation-exposed female patients diagnosed at age less than 60 from 1992 to 2014 and in non-exposed controls matched for residency, tumor type, age at diagnosis, TNM classification as well as tumor grading were investigated for molecular changes with special emphasis to copy number alterations and miRNA profiles. Cancer registry and clinical archive data were used to identify 435 breast cancer patients among female clean-up workers and 14 among evacuees from highly contaminated territories as candidates for the study. Of these, 129 breast cancer patients fit study inclusion criteria and were traced for individual reconstruction of the target organ (breast) doses. The doses were estimated for 71 exposed cases (clean-up workers and evacuees from which biomaterial was available for molecular studies and who agreed to participate in a dosimetric interview) by the use of the well-established RADRUE method, which was adjusted specifically for the assessment of breast doses. The results of 58 female clean-up workers showed a large inter-individual variability of doses in a range of about five orders of magnitude: from 0.03 to 929 mGy, with median of 5.8 mGy. The study provides the first quantitative estimate of exposures received by female clean-up workers, which represent a limited but very important group of population affected by the Chernobyl accident. The doses of 13 women evacuated after the accident who did not take part in the clean-up activities (from 4 to 45 mGy with median of 19 mGy) are in line with the previous estimates for the evacuees from Pripyat

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

At Launch Complex 34, Greg Beyke, with Current Environmental Solutions, talks to representatives from environmental and federal agencies about the environmental research project that involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA in a groundwater cleanup effort. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program, which used the complex, in the 60s. The group formed the Interagency NDAPL Consortium (IDC) to study three contamination cleanup technologies: Six Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. KSC hosted a two-day conference that presented information and demonstrations of the three technologies being tested at the site.

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

At Launch Complex 34, the Six-Phase Soil Heating site that is involved in a groundwater cleanup project can be seen. The project involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program, which used the complex, in the 60s. The group formed the Interagency NDAPL Consortium (IDC) to study three contamination cleanup technologies: Six-Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. In the background is the block house for the complex. KSC hosted a two-day conference that presented information and demonstrations of the three technologies being tested at the site.

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

At Launch Complex 34, representatives from environmental and Federal agencies head for the block house during presentations about the environmental research project that involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA in a groundwater cleanup effort. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program, which used the complex, in the 60s. The group formed the Interagency NDAPL Consortium (IDC) to study three contamination cleanup technologies: Six Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. KSC hosted a two-day conference that presented information and demonstrations of the three technologies being tested at the site.

Specificities of Acoustic Streaming in Cylindrical Cavity with Increasing Nonlinearity of the Process

NASA Astrophysics Data System (ADS)

Gubaidullin, A. A.; Pyatkova, A. V.

2018-01-01

This paper presents a numerical study of a gas acoustic streaming in a cylindrical cavity under a vibratory action. The walls of the cavity are considered impermeable and maintained at a constant temperature. The test gas is air. Variations in acoustic streaming and period-average temperature of the gas in the cavity with increasing nonlinearity of the process are shown. The increase in the nonlinearity is caused by an increase in the vibration amplitude.

Dating base flow in streams using dissolved gases and diurnal temperature changes

USGS Publications Warehouse

Sanford, Ward E.; Casile, Gerolamo C.; Haase, Karl B.

2015-01-01

A method is presented for using dissolved CFCs or SF6 to estimate the apparent age of stream base flow by indirectly estimating the mean concentration of the tracer in the inflowing groundwater. The mean value is estimated simultaneously with the mean residence times of the gas and water in the stream by sampling the stream for one or both age tracers, along with dissolved nitrogen and argon at a single location over a period of approximately 12–14 h. The data are fitted to an equation representing the temporal in-stream gas exchange as it responds to the diurnal temperature fluctuation. The efficacy of the method is demonstrated by collecting and analyzing samples at six different stream locations across parts of northern Virginia, USA. The studied streams drain watersheds with areas of between 2 and 122 km2 during periods when the diurnal stream temperature ranged between 2 and 5°C. The method has the advantage of estimating the mean groundwater residence time of discharge from the watershed to the stream without the need for the collection of groundwater infiltrating to streambeds or local groundwater sampled from shallow observation wells near the stream.

Method for improved gas-solids separation

DOEpatents

Kusik, C.L.; He, B.X.

1990-11-13

Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from where it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel. 4 figs.

Method for improved gas-solids separation

DOEpatents

Kusik, Charles L.; He, Bo X.

1990-01-01

Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from when it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel.

Flood Cleanup to Protect Indoor Air Quality

EPA Pesticide Factsheets

During a flood cleanup, the indoor air quality in your home or office may appear to be the least of your problems. However, failure to remove contaminated materials and to reduce moisture and humidity can present serious long-term health risks.

On the feeding zone of planetesimal formation by the streaming instability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Chao-Chin; Johansen, Anders, E-mail: ccyang@astro.lu.se, E-mail: anders@astro.lu.se

2014-09-10

The streaming instability is a promising mechanism to overcome the barriers in direct dust growth and lead to the formation of planetesimals. Most previous studies of the streaming instability, however, were focused on a local region of a protoplanetary disk with a limited simulation domain such that only one filamentary concentration of solids has been observed. The characteristic separation between filaments is therefore not known. To address this, we conduct the largest-scale simulations of the streaming instability to date, with computational domains up to 1.6 gas scale heights both horizontally and vertically. The large dynamical range allows the effect ofmore » vertical gas stratification to become prominent. We observe more frequent merging and splitting of filaments in simulation boxes of high vertical extent. We find multiple filamentary concentrations of solids with an average separation of about 0.2 local gas scale heights, much higher than the most unstable wavelength from linear stability analysis. This measures the characteristic separation of planetesimal forming events driven by the streaming instability and thus the initial feeding zone of planetesimals.« less

Environmental Liabilities: DoD Training Range Cleanup Cost Estimates Are Likely Understated

DTIC Science & Technology

2001-04-01

1Federal accounting standards define environmental cleanup costs as...report will not be complete or accurate. Federal financial accounting standards have required that DOD report a liability for the estimated cost of...within the range is better than any other amount. SFFAS No. 6, Accounting for Property, Plant, and Equipment, further defines cleanup costs as costs for

Improved gas tagging and cover gas combination for nuclear reactor

DOEpatents

Gross, K.C.; Laug, M.T.

1983-09-26

The invention discloses the use of stable isotopes of neon and argon, sealed as tags in different cladding nuclear fuel elements to be used in a liquid metal fast breeder reactor. Cladding failure allows fission gases and these tag isotopes to escape and to combine with the cover gas. The isotopes are Ne/sup 20/, Ne/sup 21/ and Ne/sup 22/ and Ar/sup 36/, Ar/sup 38/ and Ar/sup 40/, and the cover gas is He. Serially connected cryogenically operated charcoal beds are used to clean the cover gas and to separate out the tags. The first or cover gas cleanup bed is held between 0 and -25/sup 0/C to remove the fission gases from the cover gas and tags, and the second or tag recovery system bed between -170 and -185/sup 0/C to isolate the tags from the cover gas. Spectrometric analysis is used to identify the specific tags that are recovered, and thus the specific leaking fuel element. By cataloging the fuel element tags to the location of the fuel elements in the reactor, the location of the leaking fuel element can then be determined.

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

At Launch Complex 34, Cape Canaveral Air Station, several studies are under way for groundwater cleanup of trichloroethylene at the site. Shown here is monitoring equipment for one of the methods, potassium permanganate oxidation. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program in the 60s. The environmental research project involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA, who formed the Interagency NDAPL Consortium (IDC), to study three contamination cleanup technologies: Six Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. KSC hosted a two-day conference that presented information and demonstrations of the three technologies for representatives from environmental and federal agencies.

The Breakup Mechanism and the Spray Pulsation Behavior of a Three-Stream Atomizer

NASA Astrophysics Data System (ADS)

Ng, Chin; Dord, Anne; Aliseda, Alberto

2011-11-01

In many processes of industrial importance, such as gasification, the liquid to gas mass ratio injected at the atomizer exceeds the limit of conventional two-fluid coaxial atomizers. To maximize the shear rate between the atomization gas and the liquid while maintaining a large contact area, a secondary gas stream is added at the centerline of the spray, interior to the liquid flow, which is annular in this configuration. This cylindrical gas jet has low momentum and does not contribute to the breakup process, which is still dominated by the high shear between the concentric annular liquid flow and the high momentum gas stream. The presence of two independently controlled gas streams leads to the appearance of a hydrodynamic instability that manifests itself in pulsating liquid flow rates and droplet sizes. We study the dependency of the atomization process on the relative flow rates of the three streams. We measure the size distribution, droplet number density and total liquid volumetric flow rate as a function of time, for realistic Weber and Ohnesorge numbers. Analysis of the temporal evolution of these physical variables reveals the dominant frequency of the instability and its effect on the breakup and dispersion of droplets in the spray. We present flow visualization and Phase Doppler Particle Analyzer results that provide insight into the behavior of this complex coaxial shear flow.

33 CFR 165.1329 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA. 165.1329... Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA... (EPA) and others in the Thea Foss and Wheeler-Osgood Waterways EPA superfund cleanup site. Vessels may...

33 CFR 165.1329 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA. 165.1329... Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA... (EPA) and others in the Thea Foss and Wheeler-Osgood Waterways EPA superfund cleanup site. Vessels may...

33 CFR 165.1329 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Code of Federal Regulations, 2013 CFR

2013-07-01

... Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA. 165.1329... Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA... (EPA) and others in the Thea Foss and Wheeler-Osgood Waterways EPA superfund cleanup site. Vessels may...

33 CFR 165.1329 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Code of Federal Regulations, 2012 CFR

2012-07-01

... Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA. 165.1329... Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site, Commencement Bay, Tacoma, WA... (EPA) and others in the Thea Foss and Wheeler-Osgood Waterways EPA superfund cleanup site. Vessels may...

Health investigations of depleted-uranium clean-up workers.

PubMed

Milacic, Snezana

2008-01-01

The soil contaminated by depleted uranium (238U) ammunition during the NATO bombing of Serbia and Montenegro was cleaned-up for four months in 2002. A team of 11 clean-up workers (expert members) were medically examined three times: before decontamination as a preliminary medical check-up, immediately after decontamination, and four years after cleaning up contaminated ground. This short report presents investigations and health risk assessments of clean-up workers in radioactive decontamination operations and an assessment of the environmental health perspectives for citizens living in surrounding areas. The method of initial health disorders was used, analyzing the most sensitive biological materials, such as blood cells or chromosome damage, DNA strand breaks, radio-toxicological examination of urine. The total number of blood cells did not change, but variations of the relative number (percentage) of cells in the leukocyte formula were observed. The total number of DNA alterations was higher immediately after decontamination than before decontamination. Four years after decontamination the number of DNA alterations had decreased. However, the number of damaged cells (lymphocytes containing chromosome lesions) was higher in both medical examinations, immediately after and four years after decontamination. Disease or tumours due to 238U did not develop in the group of depleted uranium clean-up workers during the investigation period of four years. Further monitoring of haematological and chromosomal effects and the health condition of workers is necessary.

Spectrometer for measuring the concentration of components in a fluid stream and method for using same

DOEpatents

Durham, Michael D.; Stedman, Donald H.; Ebner, Timothy G.; Burkhardt, Mark R.

1991-01-01

A device and method for measuring the concentrations of components of a fluid stream. Preferably, the fluid stream is an in situ gas stream, such as a fossil fuel fired flue gas in a smoke stack. The measurements are determined from the intensity of radiation over a selected range of radiation wavelengths using peak-to-trough calculations. The need for a reference intensity is eliminated.

A detailed risk assessment of shale gas development on headwater streams in the Pennsylvania portion of the Upper Susquehanna River Basin, U.S.A.

USGS Publications Warehouse

Maloney, Kelly O.; Young, John A.; Faulkner, Stephen; Hailegiorgis, Atesmachew; Slonecker, E. Terrence; Milheim, Lesley

2018-01-01

The development of unconventional oil and gas (UOG) involves infrastructure development (well pads, roads and pipelines), well drilling and stimulation (hydraulic fracturing), and production; all of which have the potential to affect stream ecosystems. Here, we developed a fine-scaled (1:24,000) catchment-level disturbance intensity index (DII) that included 17 measures of UOG capturing all steps in the development process (infrastructure, water withdrawals, probabilistic spills) that could affect headwater streams (< 200 km2 in upstream catchment) in the Upper Susquehanna River Basin in Pennsylvania, U.S.A. The DII ranged from 0 (no UOG disturbance) to 100 (the catchment with the highest UOG disturbance in the study area) and it was most sensitive to removal of pipeline cover, road cover and well pad cover metrics. We related this DII to three measures of high quality streams: Pennsylvania State Exceptional Value (EV) streams, Class A brook trout streams and Eastern Brook Trout Joint Venture brook trout patches. Overall only 3.8% of all catchments and 2.7% of EV stream length, 1.9% of Class A streams and 1.2% of patches were classified as having medium to high level DII scores (> 50). Well density, often used as a proxy for development, only correlated strongly with well pad coverage and produced materials, and therefore may miss potential effects associated with roads and pipelines, water withdrawals and spills. When analyzed with a future development scenario, 91.1% of EV stream length, 68.7% of Class A streams and 80.0% of patches were in catchments with a moderate to high probability of development. Our method incorporated the cumulative effects of UOG on streams and can be used to identify catchments and reaches at risk to existing stressors or future development.

From Cleanup to Stewardship. A companion report to Accelerating Cleanup: Paths to Closure and background information to support the scoping process required for the 1998 PEIS Settlement Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

None, None

1999-10-01

Long-term stewardship is expected to be needed at more than 100 DOE sites after DOE's Environmental Management program completes disposal, stabilization, and restoration operations to address waste and contamination resulting from nuclear research and nuclear weapons production conducted over the past 50 years. From Cleanup to stewardship provides background information on the Department of Energy (DOE) long-term stewardship obligations and activities. This document begins to examine the transition from cleanup to long-term stewardship, and it fulfills the Secretary's commitment to the President in the 1999 Performance Agreement to provide a companion report to the Department's Accelerating Cleanup: Paths to Closuremore » report. It also provides background information to support the scoping process required for a study on long-term stewardship required by a 1998 Settlement Agreement.« less

Thermal chemical recuperation method and system for use with gas turbine systems

DOEpatents

Yang, W.C.; Newby, R.A.; Bannister, R.L.

1999-04-27

A system and method are disclosed for efficiently generating power using a gas turbine, a steam generating system and a reformer. The gas turbine receives a reformed fuel stream and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer. The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine. 2 figs.

Thermal chemical recuperation method and system for use with gas turbine systems

DOEpatents

Yang, Wen-Ching; Newby, Richard A.; Bannister, Ronald L.

1999-01-01

A system and method for efficiently generating power using a gas turbine, a steam generating system (20, 22, 78) and a reformer. The gas turbine receives a reformed fuel stream (74) and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer (18). The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine.

Test results for fuel cell operation on anaerobic digester gas

NASA Astrophysics Data System (ADS)

Spiegel, R. J.; Preston, J. L.

EPA, in conjunction with ONSI, embarked on a project to define, design, test, and assess a fuel cell energy recovery system for application at anaerobic digester waste water (sewage) treatment plants. Anaerobic digester gas (ADG) is produced at these plants during the process of treating sewage anaerobically to reduce solids. ADG is primarily comprised of methane (57-66%), carbon dioxide (33-39%), nitrogen (1-10%), and a small amount of oxygen (<0.5%). Additionally, ADG contains trace amounts of fuel cell catalyst contaminants consisting of sulfur-bearing compounds (principally hydrogen sulfide) and halogen compounds (chlorides). The project has addressed two major issues: development of a cleanup system to remove fuel cell contaminants from the gas and testing/assessing of a modified ONSI PC25 C fuel cell power plant operating on the cleaned, but dilute, ADG. Results to date demonstrate that the ADG fuel cell power plant can, depending on the energy content of the gas, produce electrical output levels close to full power (200 kW) with measured air emissions comparable to those obtained by a natural gas fuel cell. The cleanup system results show that the hydrogen sulfide levels are reduced to below 10 ppbv and halides to approximately 30 ppbv.

Clean-up of aqueous acetone vegetable extracts by solid-matrix partition for pyrethroid residue determination by gas chromatography-electron-capture detection.

PubMed

Di Muccio, A; Barbini, D A; Generali, T; Pelosi, P; Ausili, A; Vergori, F; Camoni, I

1997-03-21

Disposable, ready-to-use cartridges filled with macroporous diatomaceous material are used to carry out a partition clean-up that, in a single step, is capable of transferring pesticide residues from aqueous acetone extracts into light petroleum-dichloromethane (75:25, v/v). This procedure takes the place of some functions (such as separatory-funnel partition, drying over anhydrous sodium sulphate and partial adsorption clean-up) usually performed by separate steps in classical schemes. Fourteen pyrethroid pesticides, including tefluthrin, tetramethrin, cyphenothrin, cyfluthrin, flucythrinate, tau-fluvalinate, deltamethrin, bioallethrin, fenpropathrin, lambda-cyhalothrin, permethrin, alpha-cypermethrin, esfenvalerate and tralomethrin were determined using the described procedure with satisfactory recoveries for most of them, at spiking levels ranging from 0.08 to 0.82 mg/kg for the different compounds. Crops subjected to the described procedure included strawberry, apple, and orange gave extracts containing a mass of co-extractives that was between 5 and 30 mg. Compared with classical schemes, the described procedure is simple, less labour intensive, allows parallel handling of several extracts and does not require the preparation and maintenance of equipment. Troublesome emulsions such as those frequently observed in separation funnel partitioning do not occur.

The formation and early evolution of meteoroid streams

NASA Astrophysics Data System (ADS)

Moorhead, Althea

2018-04-01

Meteor showers occur when the Earth encounters a stream of particles liberated from the surface of a comet or, more rarely, an asteroid. Initially, meteoroids follow a trajectory that is similar to that of their parent comet but modified by both the outward flow of gas from the nucleus and radiation pressure. Sublimating gases impart an “ejection velocity” to solid particles in the coma; this ejection velocity is larger for smaller particles but cannot exceed the speed of the gas itself. Radiation pressure provides a repulsive force that, like gravity, follows an inverse square law, and thus effectively reduces the central potential experienced by small particles. Depending on the optical properties of the particle, the speed of the particle may exceed its effective escape velocity; such particles will be unbound and hence excluded from meteoroid streams and meteor showers. These processes also modify the heliocentric distance at which meteoroid orbits cross the ecliptic plane, and can thus move portions of the stream out of range of the Earth. This talk presents recent work on these components of the early evolution of meteoroid streams and their implications for the meteoroid environment seen at Earth.

Spectrometer for measuring the concentration of components in a fluid stream and method for using same

DOEpatents

Durham, M.D.; Stedman, D.H.; Ebner, T.G.; Burkhardt, M.R.

1991-12-03

A device and method are described for measuring the concentrations of components of a fluid stream. Preferably, the fluid stream is an in-situ gas stream, such as a fossil fuel fired flue gas in a smoke stack. The measurements are determined from the intensity of radiation over a selected range of radiation wavelengths using peak-to-trough calculations. The need for a reference intensity is eliminated. 15 figures.

Hantavirus Prevention: Cleanup of Rodent Contamination

DTIC Science & Technology

2008-09-01

Hantaviruses in the Americas may cause human disease involving the lungs, hence the name " hantavirus pulmonary syndrome" (HPS). Since May 1993, a...humans are also found in other rodents, but the number of cases stemming from these hantaviruses is small when compared to SNV. Hantavirus is shed in... HANTAVIRUS PREVENTION: CLEANUP OF RODENT CONTAMINATION Technical Information Paper 18-001-0306

Methods and apparatus for carbon dioxide removal from a fluid stream

DOEpatents

Wei, Wei; Ruud, James Anthony; Ku, Anthony Yu-Chung; Ramaswamy, Vidya; Liu, Ke

2010-01-19

An apparatus for producing hydrogen gas wherein the apparatus includes a reactor. In one embodiment, the reactor includes at least two conversion-removal portions. Each conversion-removal portion comprises a catalyst section configured to convert CO in the stream to CO.sub.2 and a membrane section located downstream of and in flow communication with the catalyst section. The membrane section is configured to selectively remove the CO.sub.2 from the stream and to be in flow communication with a sweep gas.

Emissions of carbon dioxide and methane from a headwater stream network of interior Alaska

USGS Publications Warehouse

Crawford, John T.; Striegl, Robert G.; Wickland, Kimberly P.; Dornblaser, Mark M.; Stanley, Emily H.

2013-01-01

Boreal ecosystems store significant quantities of organic carbon (C) that may be vulnerable to degradation as a result of a warming climate. Despite their limited coverage on the landscape, streams play a significant role in the processing, gaseous emission, and downstream export of C, and small streams are thought to be particularly important because of their close connection with the surrounding landscape. However, ecosystem carbon studies do not commonly incorporate the role of the aquatic conduit. We measured carbon dioxide (CO2) and methane (CH4) concentrations and emissions in a headwater stream network of interior Alaska underlain by permafrost to assess the potential role of stream gas emissions in the regional carbon balance. First-order streams exhibited the greatest variability in fluxes of CO2 and CH4,and the greatest mean pCO2. High-resolution time series of stream pCO2 and discharge at two locations on one first-order stream showed opposing pCO2 responses to storm events, indicating the importance of hydrologic flowpaths connecting CO2-rich soils with surface waters. Repeated longitudinal surveys on the stream showed consistent areas of elevated pCO2 and pCH4, indicative of discrete hydrologic flowpaths delivering soil water and groundwater having varying chemistry. Up-scaled basin estimates of stream gas emissions suggest that streams may contribute significantly to catchment-wide CH4 emissions. Overall, our results indicate that while stream-specific gas emission rates are disproportionately high relative to the terrestrial landscape, both stream surface area and catchment normalized emission rates were lower than those documented for the Yukon River Basin as a whole. This may be due to limitations of C sources and/or C transport to surface waters.

Pulse combusted acoustic agglomeration apparatus and process

DOEpatents

Mansour, Momtaz N.

1993-01-01

An improved apparatus and process for removal of particulates entrained in a gas stream are provided. The removal process employs a pulse combustor to provide an acoustic pressure wave to acoustically enhance bimodal agglomeration of particulates which may be collected and removed using a conventional separation apparatus. A particulate having a size different from the size of the particulate in the gas stream to be cleaned is introduced into the system to effectuate the bimodal process. The apparatus may be employed as a direct fired system for improved operation of gas-operated equipment such as a gas turbine, or may, alternatively, be employed as an add-on subsystem for combustion exhaust clean-up. Additionally, the added particulate may be a sorbent for effecting sorption of other contaminants such as sulfur. Various other particulates for contaminant removal may also be introduced into the system as exemplified by alkali-gettering agents.

Glufosinate ammonium clean-up procedure from water samples using SPE

NASA Astrophysics Data System (ADS)

Tayeb M., A.; Ismail B., S.; Mardiana-Jansar, K.; Ta, Goh Choo; Agustar, Hani Kartini

2015-09-01

For the determination of glufosinate ammonium residue in soil and water samples, different solid phase extraction (SPE) sorbent efficiency was studied. Four different SPE sorbents i.e.: CROMABOND PS-H+, CROMABOND PS-OH-, ISOLUTE ENV+, Water Sep-Pak and OASIS HLB were used. Sample clean-up performance was evaluated using high performance liquid chromatography (Agilent 1220 infinity LC) with fluorescence detector. Detection of FMO-derivatives was done at λ ex = 260 nm and λ em= 310 nm. OASIS HLB column was the most suitable for the clean-up in view of the overall feasibility of the analysis.

Detectability of cold streams into high-redshift galaxies by absorption lines

NASA Astrophysics Data System (ADS)

Goerdt, Tobias; Dekel, Avishai; Sternberg, Amiel; Gnat, Orly; Ceverino, Daniel

2012-08-01

Cold gas streaming along the dark matter filaments of the cosmic web is predicted to be the major source of fuel for disc buildup, violent disc instability and star formation in massive galaxies at high redshift. We investigate to what extent such cold gas is detectable in the extended circumgalactic environment of galaxies via Lyα absorption and selected low-ionization metal absorption lines. We model the expected absorption signatures using high-resolution zoom-in adaptive mesh refinement cosmological simulations. In the post-processing, we distinguish between self-shielded gas and unshielded gas. In the self-shielded gas, which is optically thick to Lyman continuum radiation, we assume pure collisional ionization for species with an ionization potential greater than 13.6 eV. In the optically-thin, unshielded gas, these species are also photoionized by the metagalactic radiation. In addition to absorption of radiation from background quasars, we compute the absorption line profiles of radiation emitted by the galaxy at the centre of the same halo. We predict the strength of the absorption signal for individual galaxies without stacking. We find that the Lyα absorption profiles produced by the streams are consistent with observations of absorption and emission Lyα profiles in high-redshift galaxies. Due to the low metallicities in the streams, and their low covering factors, the metal absorption features are weak and difficult to detect.

Patterns in stream greenhouse gas dynamics from mountains to plains in northcentral Wyoming

NASA Astrophysics Data System (ADS)

Kuhn, C.; Bettigole, C.; Glick, H. B.; Seegmiller, L.; Oliver, C. D.; Raymond, P.

2017-09-01

Quantification of small stream contributions to global carbon cycling is key to understanding how freshwater systems transmit and transform carbon between terrestrial and atmospheric pools. To date, greenhouse gas emissions of carbon dioxide and methane from freshwaters, particularly in mountainous regions, remain poorly characterized due to a lack of direct field observations. Using a unique longitudinal approach, we conducted field surveys across two ecoregions (Middle Rockies and Great Plains) in the Clear Creek watershed, a subwatershed of Wyoming's Powder River Basin. We took direct measurements of stream gases using headspace sampling at 30 sites (8 June to 23 October). We observed the lowest and most variable concentrations in headwaters, which flow through a federally designated alpine wilderness area. By contrast, the Great Plains exhibited 1.45 and 4 times higher pCO2 and pCH4 concentrations and the relative contributions of methane increased downstream. Fluxes during snowmelt were 45% and 58% higher for CO2 and CH4 than during base flow but overall were lower than estimates for other systems. Variability for pCO2 was highest during late summer and in the uppermost sections of the headwaters. The high heterogeneity and common undersaturation observed through space and time, especially in the mountains, suggest that downscaled regional estimates may fail to capture variability in fluxes observed at these smaller scales. Based on these results, we strongly recommend higher resolution time series studies and increased scrutiny of systems at near equilibrium, inclusive of winter storage and ice-off events, to improve our understanding of the effects of seasonal dynamics on these processes.

GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard S. Meyer

A new project was initiated this quarter to develop gas/liquid membranes for natural gas upgrading. Efforts have concentrated on legal agreements, including alternative field sites. Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbingmore » liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project.« less

78 FR 50447 - Agency Information Collection Activities; Submission for OMB Review; Comment Request; Cleanup...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-19

... for OMB Review; Comment Request; Cleanup Program for Accumulations of Coal and Float Coal Dusts, Loose Coal, and Other Combustibles ACTION: Notice. SUMMARY: The Department of Labor (DOL) is submitting the... (ICR) proposal; titled, ``Cleanup Program for Accumulations of Coal and Float Coal Dusts, Loose Coal...

Development of Metal-impregnated Single Walled Carbon Nanotubes for Toxic Gas Contaminant Control in Advanced Life Support Systems

NASA Technical Reports Server (NTRS)

Pisharody, Suresh A.; Fisher, John W.; Wignarajah, K.

2002-01-01

The success of physico-chemical waste processing and resource recovery technologies for life support application depends partly on the ability of gas clean-up systems to efficiently remove trace contaminants generated during the process with minimal use of expendables. Carbon nanotubes promise superior performance over conventional approaches to gas clean-up due to their ability to direct the selective uptake of gaseous species based on their controlled pore size, high surface area, ordered chemical structure that allows functionalization and their effectiveness also as catalyst support materials for toxic gas conversion. We present results and findings from a preliminary study on the effectiveness of metal impregnated single walled nanotubes as catalyst/catalyst support materials for toxic gas contaminate control. The study included the purification of single walled nanotubes, the catalyst impregnation of the purified nanotubes, the experimental characterization of the surface properties of purified single walled nanotubes and the characterization of physisorption and chemisorption of uptake molecules.

The SAMI Galaxy Survey: gas streaming and dynamical M/L in rotationally supported systems

NASA Astrophysics Data System (ADS)

Cecil, G.; Fogarty, L. M. R.; Richards, S.; Bland-Hawthorn, J.; Lange, R.; Moffett, A.; Catinella, B.; Cortese, L.; Ho, I.-T.; Taylor, E. N.; Bryant, J. J.; Allen, J. T.; Sweet, S. M.; Croom, S. M.; Driver, S. P.; Goodwin, M.; Kelvin, L.; Green, A. W.; Konstantopoulos, I. S.; Owers, M. S.; Lawrence, J. S.; Lorente, N. P. F.

2016-02-01

Line-of-sight velocities of gas and stars can constrain dark matter (DM) within rotationally supported galaxies if they trace circular orbits extensively. Photometric asymmetries may signify non-circular motions, requiring spectra with dense spatial coverage. Our integral-field spectroscopy of 178 galaxies spanned the mass range of the Sydney-AAO Multi-object integral field spectrograph (SAMI) Galaxy Survey. We derived circular speed curves (CSCs) of gas and stars from non-parametric fits out to r ˜ 2re. For 12/14 with measured H I profiles, ionized gas and H I maximum velocities agreed. We fitted mass-follows-light models to 163 galaxies by approximating the radial light profile as nested, very flattened mass homeoids viewed as a Sérsic form. Fitting broad-band spectral energy distributions to Sloan Digital Sky Survey images gave median stellar mass/light 1.7 assuming a Kroupa initial mass function (IMF) versus 2.6 dynamically. Two-thirds of the dynamical mass/light measures were consistent with star+remnant IMFs. One-fifth required upscaled starlight to fit, hence comparable mass of unobserved baryons and/or DM distributed like starlight across the SAMI aperture that came to dominate motions as the starlight CSCs declined rapidly. The rest had mass distributed differently from light. Subtracting fits of Sérsic radial profiles to 13 VIKING Z-band images revealed residual weak bars. Near the bar major axis, we assessed m = 2 streaming velocities, and found deviations usually <30 km s-1 from the CSC; three showed no deviation. Thus, asymmetries rarely influenced the CSC despite colocated shock-indicating, emission-line flux ratios in more than 2/3 of our sample.

Combined extraction-cleanup column chromatographic procedure for determination of dicofol in avian eggs

USGS Publications Warehouse

Krynitsky, A.J.; Stafford, C.J.; Wiemeyer, Stanley N.

1988-01-01

Dicofol in avian eggs was completely oxidized to dichlorobenzophenone (DCBP) when a hexane Soxhlet extraction procedure was used. This degradation did not occur with other avian tissues (muscle and liver). For this reason, a combined extraction-cleanup column chromatographic procedure, without added heat, was developed for the determination of dicofol in avian eggs. Homogenized subsamples of eggs were mixed with sodium sulfate, and the mixture was added as the top layer on a column prepacked with Florisil. The dicofol and other compounds of interest were then eluted with ethyl ether-hexane. The extracts, relatively free from lipids, were quantitated on a gas chromatograph equipped with a 63Ni electron-capture detector and a methyl silicone capillary column. Recoveries from chicken eggs, fortified with dicofol and other DDT-related compounds, averaged 96%. Analysis of eggs of eastern screech-owls, fed a meat diet containing 10 ppm technical Kelthane, showed that both dicofol and DCBP were present. Results were confirmed by gas chromatography/mass spectrometry. This method is rapid and reliable, involves a minimum of sample handling, and is well suited for high volume determination of dicofol in eggs and other avian tissues.

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

DOEpatents

Ayala, Raul E.

1993-01-01

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

GLOBAL SIMULATIONS OF GALACTIC WINDS INCLUDING COSMIC-RAY STREAMING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ruszkowski, Mateusz; Yang, H.-Y. Karen; Zweibel, Ellen, E-mail: mateuszr@umich.edu, E-mail: hsyang@astro.umd.edu, E-mail: zweibel@astro.wisc.edu

2017-01-10

Galactic outflows play an important role in galactic evolution. Despite their importance, a detailed understanding of the physical mechanisms responsible for the driving of these winds is lacking. In an effort to gain more insight into the nature of these flows, we perform global three-dimensional magnetohydrodynamical simulations of an isolated Milky Way-size starburst galaxy. We focus on the dynamical role of cosmic rays (CRs) injected by supernovae, and specifically on the impact of the streaming and anisotropic diffusion of CRs along the magnetic fields. We find that these microphysical effects can have a significant effect on the wind launching andmore » mass loading factors, depending on the details of the plasma physics. Due to the CR streaming instability, CRs propagating in the interstellar medium scatter on self-excited Alfvén waves and couple to the gas. When the wave growth due to the streaming instability is inhibited by some damping process, such as turbulent damping, the coupling of CRs to the gas is weaker and their effective propagation speed faster than the Alfvén speed. Alternatively, CRs could scatter from “extrinsic turbulence” that is driven by another mechanism. We demonstrate that the presence of moderately super-Alfvénic CR streaming enhances the efficiency of galactic wind driving. Cosmic rays stream away from denser regions near the galactic disk along partially ordered magnetic fields and in the process accelerate more tenuous gas away from the galaxy. For CR acceleration efficiencies broadly consistent with the observational constraints, CRs reduce the galactic star formation rates and significantly aid in launching galactic winds.« less

Nanocomposite thin films for optical gas sensing

DOEpatents

Ohodnicki, Paul R; Brown, Thomas D

2014-06-03

The disclosure relates to a plasmon resonance-based method for gas sensing in a gas stream utilizing a gas sensing material. In an embodiment the gas stream has a temperature greater than about 500.degree. C. The gas sensing material is comprised of gold nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10.sup.-7 S/cm at a temperature of 700.degree. C. Exemplary inert matrix materials include SiO.sub.2, Al.sub.2O.sub.3, and Si.sub.3N.sub.4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. Changes in the chemical composition of the gas stream are detected by changes in the plasmon resonance peak. The method disclosed offers significant advantage over active and reducible matrix materials typically utilized, such as yttria-stabilized zirconia (YSZ) or TiO.sub.2.

Metal oxide membranes for gas separation

DOEpatents

Anderson, Marc A.; Webster, Elizabeth T.; Xu, Qunyin

1994-01-01

A method for permformation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation.

Brownfields to School Sites: How Can the State Facilitate Cleanup To Build Essential Schools?

ERIC Educational Resources Information Center

California State Legislature, Sacramento. Select Committee on Environmental Justice.

This document presents background information and testimony concerning the cleanup of potentially contaminated vacant or underutilized property for use as future school sites in low-income and minority communities. Various proposals are offered that would allow the state, where necessary, to facilitate the cleanup of these "brownfields"…

Removal of fluoride impurities from UF.sub.6 gas

DOEpatents

Beitz, James V.

1985-01-01

A method of purifying a UF.sub.6 gas stream containing one or more metal fluoride impurities composed of a transuranic metal, transition metal or mixtures thereof, is carried out by contacting the gas stream with a bed of UF.sub.5 in a reaction vessel under conditions where at least one impurity reacts with the UF.sub.5 to form a nongaseous product and a treated gas stream, and removing the treated gas stream from contact with the bed. The nongaseous products are subsequently removed in a reaction with an active fluorine affording agent to form a gaseous impurity which is removed from the reaction vessel. The bed of UF.sub.5 is formed by the reduction of UF.sub.6 in the presence of UV light. One embodiment of the reaction vessel includes a plurality of UV light sources as tubes on which UF.sub.5 is formed.

Cleanup Verification Package for the 300-18 Waste Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. M. Capron

This cleanup verification package documents completion of remedial action for the 300-18 waste site. This site was identified as containing radiologically contaminated soil, metal shavings, nuts, bolts, and concrete.

Natural gas treating with molecular sieves. Pt. 2. Regeneration, economics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harris, T.B.

1972-08-01

Regeneration considerations are often the key to successful and economical application of molecular sieves for natural gas sweetening. In effect, molecular sieves remove the sulfur compounds from the feed stream and concentrate them into a smaller regeneration gas stream. Because a molecular sieve natural gas sweetener concentrates the hydrogen sulfide from the feed stream in a smaller regeneration gas stream, the sulfur-rich gas must be subsequently treated or disposed of. Molecular sieve sweeteners afford a high degree of flexibility in operating rates. They have a very high turndown ratio limited only by the use of product gas for regeneration, whichmore » can be utilized to full advantage with a control system that provides variable cycle times. Tabular data provide a range of designed conditions for existing molecular sieve natural gas sweeteners. Actual operating experience has shown that, in most cases, the following economical advantages can be realized: (1) investment cost is competitive to alternate forms of gas treating; (2) operating cost of molecular sieve units are generally lower (3) the value of carbon dioxide left in natural gas can lead to a considerable operating credit; and (4) the incremental costs of expansion to an existing plant are normally much less. (24 refs.)« less

Burbank performs the scheduled extensive cleanup of ventilation systems

NASA Image and Video Library

2012-02-22

ISS030-E-093414 (22 Feb. 2012) --- NASA astronaut Dan Burbank, Expedition 30 commander, performs the scheduled extensive cleanup of ventilation systems in the Columbus laboratory of the International Space Station.

Process and system for removing sulfur from sulfur-containing gaseous streams

DOEpatents

Basu, Arunabha; Meyer, Howard S.; Lynn, Scott; Leppin, Dennis; Wangerow, James R.

2012-08-14

A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

Nonlinear acoustic streaming in straight and tapered tubes

NASA Astrophysics Data System (ADS)

Tuttle, Brian C.

In thermoacoustic and Stirling devices such as the pulse-tube refrigerator, efficiency is diminished by the formation of a second-order mean velocity known as Rayleigh streaming. This flow emerges from the interaction of the working gas with the wall of the tube in a thin boundary layer. Recent studies have suggested that streaming velocity can be decreased in a tube by tapering it slightly. This research investigates that claim through the development of a numerical model of Rayleigh streaming in variously tapered tubes. It is found that the numerical simulation of streaming in a straight tube compares well with theory, and the application of different thermal boundary conditions at the tube wall shows that for pressurized helium, inner streaming vortices which appear near an adiabatic tube wall do not develop near an isothermal wall. An order analysis indicates that the temperature dependence of viscosity and thermal conductivity contributes appreciably to an accurate numerical model of streaming. Comparison of Rayleigh streaming in tapered tubes shows the effects of taper angle on the circulation and velocity of the mean flow.

Innovative PCDD/F-containing gas stream generating system applied in catalytic decomposition of gaseous dioxins over V2O5-WO3/TiO2-based catalysts.

PubMed

Yang, Chia Cheng; Chang, Shu Hao; Hong, Bao Zhen; Chi, Kai Hsien; Chang, Moo Been

2008-10-01

Development of effective PCDD/F (polychlorinated dibenzo-p-dioxin and dibenzofuran) control technologies is essential for environmental engineers and researchers. In this study, a PCDD/F-containing gas stream generating system was developed to investigate the efficiency and effectiveness of innovative PCDD/F control technologies. The system designed and constructed can stably generate the gas stream with the PCDD/F concentration ranging from 1.0 to 100ng TEQ Nm(-3) while reproducibility test indicates that the PCDD/F recovery efficiencies are between 93% and 112%. This new PCDD/F-containing gas stream generating device is first applied in the investigation of the catalytic PCDD/F control technology. The catalytic decomposition of PCDD/Fs was evaluated with two types of commercial V(2)O(5)-WO(3)/TiO(2)-based catalysts (catalyst A and catalyst B) at controlled temperature, water vapor content, and space velocity. 84% and 91% PCDD/F destruction efficiencies are achieved with catalysts A and B, respectively, at 280 degrees C with the space velocity of 5000h(-1). The results also indicate that the presence of water vapor inhibits PCDD/F decomposition due to its competition with PCDD/F molecules for adsorption on the active vanadia sites for both catalysts. In addition, this study combined integral reaction and Mars-Van Krevelen model to calculate the activation energies of OCDD and OCDF decomposition. The activation energies of OCDD and OCDF decomposition via catalysis are calculated as 24.8kJmol(-1) and 25.2kJmol(-1), respectively.

Groundwater cleanup demonstrations at Complex 34, CCAS

NASA Technical Reports Server (NTRS)

2000-01-01

On top of the block house at Launch Complex 34, representatives from environmental and Federal agencies hear from Laymon Gray, with Florida State University, about the environmental research project that involves the Department of Defense, Environmental Protection Agency, Department of Energy and NASA in a groundwater cleanup effort. Concentrations of trichloroethylene solvent have been identified in the soil at the complex as a result of cleaning methods for rocket parts during the Apollo Program, which used the complex, in the 60s. The group formed the Interagency NDAPL Consortium (IDC) to study three contamination cleanup technologies: Six Phase Soil Heating, Steam Injection and In Situ Oxidation with Potassium Permanganate. All three methods may offer a way to remove the contaminants in months instead of decades. In the background (left) can be seen the cement platform and walkway from the block house to the pad. Beyond it is the Atlantic Ocean. KSC hosted a two-day conference that presented information and demonstrations of the three technologies being tested at the site.

GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard S. Meyer

Efforts this quarter have concentrated on legal agreements, including alternative field sites. Preliminary design of the bench-scale equipment has been initiated. Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranesmore » provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50--70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project.« less

GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard S. Meyer

Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting inmore » equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. KPS and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on legal agreements, including alternative field sites. Preliminary design of the bench-scale equipment continues.« less

GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard S. Meyer

Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting inmore » equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on legal agreements, including alternative field sites. Preliminary design of the bench-scale equipment continues.« less

GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard S. Meyer

Efforts this quarter have concentrated on legal agreements, including alternative field sites. Preliminary design of the bench-scale equipment continues. Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide muchmore » greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting in equipment 50--70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project.« less

Automated gas chromatography

DOEpatents

Mowry, Curtis D.; Blair, Dianna S.; Rodacy, Philip J.; Reber, Stephen D.

1999-01-01

An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute.

Removal of fluoride impurities from UF/sub 6/ gas

DOEpatents

Beitz, J.V.

1984-01-06

A method of purifying a UF/sub 6/ gas stream containing one or more metal fluoride impurities composed of a transuranic metal, transition metal or mixtures thereof, is carried out by contacting the gas stream with a bed of UF/sub 5/ in a reaction vessel under conditions where at least one impurity reacts with the UF/sub 5/ to form a nongaseous product and a treated gas stream, and removing the treated gas stream from contact with the bed. The nongaseous products are subsequently removed in a reaction with an active fluorine affording agent to form a gaseous impurity which is removed from the reaction vessel. The bed of UF/sub 5/ is formed by the reduction of UF/sub 6/ in the presence of uv light. One embodiment of the reaction vessel includes a plurality of uv light sources as tubes on which UF/sub 5/ is formed. 2 figures.

Fuel cell gas management system

DOEpatents

DuBose, Ronald Arthur

2000-01-11

A fuel cell gas management system including a cathode humidification system for transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell equal to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

Resting-state FMRI confounds and cleanup

PubMed Central

Murphy, Kevin; Birn, Rasmus M.; Bandettini, Peter A.

2013-01-01

The goal of resting-state functional magnetic resonance imaging (FMRI) is to investigate the brain’s functional connections by using the temporal similarity between blood oxygenation level dependent (BOLD) signals in different regions of the brain “at rest” as an indicator of synchronous neural activity. Since this measure relies on the temporal correlation of FMRI signal changes between different parts of the brain, any non-neural activity-related process that affects the signals will influence the measure of functional connectivity, yielding spurious results. To understand the sources of these resting-state FMRI confounds, this article describes the origins of the BOLD signal in terms of MR physics and cerebral physiology. Potential confounds arising from motion, cardiac and respiratory cycles, arterial CO2 concentration, blood pressure/cerebral autoregulation, and vasomotion are discussed. Two classes of techniques to remove confounds from resting-state BOLD time series are reviewed: 1) those utilising external recordings of physiology and 2) data-based cleanup methods that only use the resting-state FMRI data itself. Further methods that remove noise from functional connectivity measures at a group level are also discussed. For successful interpretation of resting-state FMRI comparisons and results, noise cleanup is an often over-looked but essential step in the analysis pipeline. PMID:23571418

Metal oxide membranes for gas separation

DOEpatents

Anderson, M.A.; Webster, E.T.; Xu, Q.

1994-08-30

A method for formation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation. 4 figs.

Dyscirculatory encephalopathy in Chernobyl disaster clean-up workers (a 20-year study).

PubMed

Podsonnaya, I V; Shumakher, G I; Golovin, V A

2010-05-01

Results obtained over 20-years of following 536 Chernobyl clean-up workers and 436 control subjects are presented. Dyscirculatory encephalopathy developed more frequently in persons exposed to radiation at age 30 years. As compared with the control group, workers were characterized by early onset of disease, faster progression, stable symptomatology for 5-6 years, and further progression of disease in the form of autonomic dysfunction, psycho-organic syndrome, and epilepsy. Major strokes were also more common in clean-up workers.

Green Remediation Best Management Practices: Overview of EPA's Methodology to Address the Environmental Footprint of Site Cleanup

EPA Pesticide Factsheets

Contaminated site cleanups involving complex activities may benefit from a detailed environmental footprint analysis to inform decision-making about application of suitable best management practices for greener cleanups.

Oxidation and thermal fatigue of coated and uncoated NX-188 nickel-base alloy in a high velocity gas stream

NASA Technical Reports Server (NTRS)

Johnson, J. R.; Young, S. G.

1972-01-01

A cast nickel-base superalloy, NX-188, coated and uncoated, was tested in a high-velocity gas stream for resistance to oxidation and thermal fatigue by cycling between room temperature and 980, 1040, and 1090 C. Contrary to the behavior of more conventional nickel-base alloys, uncoated NX-188 exhibited the greatest weight loss at the lowest test temperature. In general, on the basis of weight change and metallographic observations a coating consisting of vapor-deposited Fe-Cr-Al-Y over a chromized substrate exhibited the best overall performance in resistance to oxidation and thermal fatigue.

Development of Metal-impregnated Single Walled Carbon Nanotubes for Toxic Gas Contaminant Control in Advanced Life Support Systems

NASA Technical Reports Server (NTRS)

Cinke, Martin; Li, Jing; Chen, Bin; Wignarajah, Kanapathipillai; Pisharody, Suresh A.; Fisher, John W.; Delzeit, Lance; Meyyappan, Meyya; Partridge, Harry; Clark, Kimberlee

2003-01-01

The success of physico-chemical waste processing and resource recovery technologies for life support application depends partly on the ability of gas clean-up systems to efficiently remove trace contaminants generated during the process with minimal use of expendables. Highly purified metal-impregnated carbon nanotubes promise superior performance over conventional approaches to gas clean-up due to their ability to direct the selective uptake gaseous species based both on the nanotube s controlled pore size, high surface area, and ordered chemical structure that allows functionalization and on the nanotube s effectiveness as a catalyst support material for toxic contaminants removal. We present results on the purification of single walled carbon nanotubes (SWCNT) and efforts at metal impregnation of the SWCNT's.

Military Base Realignments and Closures: DOD Has Improved Environmental Cleanup Reporting but Should Obtain and Share More Information

DTIC Science & Technology

2017-01-01

the property, put final cleanup remedies in place before the property is transferred. However, under some circumstances the services may conduct an...early transfer before cleanup has been completed. When remedies are in place for addressing the contamination of a former installation or the...cleanup at BRAC installations will significantly increase due to the high cost of remediating emerging contaminants, primarily perfluorooctane

Wastewater disposal from unconventional oil and gas development degrades stream quality at a West Virginia injection facility

USGS Publications Warehouse

Akob, Denise M.; Mumford, Adam; Orem, William H.; Engle, Mark A.; Klinges, Julia (Grace); Kent, Douglas B.; Cozzarelli, Isabelle M.

2016-01-01

The development of unconventional oil and gas (UOG) resources has rapidly increased in recent years; however, the environmental impacts and risks are poorly understood. A single well can generate millions of liters of wastewater, representing a mixture of formation brine and injected hydraulic fracturing fluids. One of the most common methods for wastewater disposal is underground injection; we are assessing potential risks of this method through an intensive, interdisciplinary study at an injection disposal facility in West Virginia. In June 2014, waters collected downstream from the site had elevated specific conductance (416 μS/cm) and Na, Cl, Ba, Br, Sr, and Li concentrations, compared to upstream, background waters (conductivity, 74 μS/cm). Elevated TDS, a marker of UOG wastewater, provided an early indication of impacts in the stream. Wastewater inputs are also evident by changes in 87Sr/86Sr in streamwater adjacent to the disposal facility. Sediments downstream from the facility were enriched in Ra and had high bioavailable Fe(III) concentrations relative to upstream sediments. Microbial communities in downstream sediments had lower diversity and shifts in composition. Although the hydrologic pathways were not able to be assessed, these data provide evidence demonstrating that activities at the disposal facility are impacting a nearby stream and altering the biogeochemistry of nearby ecosystems.

System Regulates the Water Contents of Fuel-Cell Streams

NASA Technical Reports Server (NTRS)

Vasquez, Arturo; Lazaroff, Scott

2005-01-01

An assembly of devices provides for both humidification of the reactant gas streams of a fuel cell and removal of the product water (the water generated by operation of the fuel cell). The assembly includes externally-sensing forward-pressure regulators that supply reactant gases (fuel and oxygen) at variable pressures to ejector reactant pumps. The ejector supply pressures depend on the consumption flows. The ejectors develop differential pressures approximately proportional to the consumption flow rates at constant system pressure and with constant flow restriction between the mixer-outlet and suction ports of the ejectors. For removal of product water from the circulating oxygen stream, the assembly includes a water/gas separator that contains hydrophobic and hydrophilic membranes. The water separator imposes an approximately constant flow restriction, regardless of the quality of the two-phase flow that enters it from the fuel cell. The gas leaving the water separator is nearly 100 percent humid. This gas is returned to the inlet of the fuel cell along with a quantity of dry incoming oxygen, via the oxygen ejector, thereby providing some humidification.

Considering Traditional Ecological Knowledge (TEK) During the Cleanup Process

EPA Pesticide Factsheets

This memorandum provides direction to improve the decision-making process as it relates to site assessment, characterization, and cleanup activities, to ensure EPA's Office of Land and Emergency Management is considering TEK when tribes provide it to EPA.

Automated gas chromatography

DOEpatents

Mowry, C.D.; Blair, D.S.; Rodacy, P.J.; Reber, S.D.

1999-07-13

An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute. 7 figs.

Acoustic instability driven by cosmic-ray streaming

NASA Technical Reports Server (NTRS)

Begelman, Mitchell C.; Zweibel, Ellen G.

1994-01-01

We study the linear stability of compressional waves in a medium through which cosmic rays stream at the Alfven speed due to strong coupling with Alfven waves. Acoustic waves can be driven unstable by the cosmic-ray drift, provided that the streaming speed is sufficiently large compared to the thermal sound speed. Two effects can cause instability: (1) the heating of the thermal gas due to the damping of Alfven waves driven unstable by cosmic-ray streaming; and (2) phase shifts in the cosmic-ray pressure perturbation caused by the combination of cosmic-ray streaming and diffusion. The instability does not depend on the magnitude of the background cosmic-ray pressure gradient, and occurs whether or not cosmic-ray diffusion is important relative to streaming. When the cosmic-ray pressure is small compared to the gas pressure, or cosmic-ray diffusion is strong, the instability manifests itself as a weak overstability of slow magnetosonic waves. Larger cosmic-ray pressure gives rise to new hybrid modes, which can be strongly unstable in the limits of both weak and strong cosmic-ray diffusion and in the presence of thermal conduction. Parts of our analysis parallel earlier work by McKenzie & Webb (which were brought to our attention after this paper was accepted for publication), but our treatment of diffusive effects, thermal conduction, and nonlinearities represent significant extensions. Although the linear growth rate of instability is independent of the background cosmic-ray pressure gradient, the onset of nonlinear eff ects does depend on absolute value of DEL (vector differential operator) P(sub c). At the onset of nonlinearity the fractional amplitude of cosmic-ray pressure perturbations is delta P(sub C)/P(sub C) approximately (kL) (exp -1) much less than 1, where k is the wavenumber and L is the pressure scale height of the unperturbed cosmic rays. We speculate that the instability may lead to a mode of cosmic-ray transport in which plateaus of uniform cosmic

Removing sulphur oxides from a fluid stream

DOEpatents

Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

2014-04-08

A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

Dual-mode nonlinear instability analysis of a confined planar liquid sheet sandwiched between two gas streams of unequal velocities and prediction of droplet size and velocity distribution using maximum entropy formulation

NASA Astrophysics Data System (ADS)

Dasgupta, Debayan; Nath, Sujit; Bhanja, Dipankar

2018-04-01

Twin fluid atomizers utilize the kinetic energy of high speed gases to disintegrate a liquid sheet into fine uniform droplets. Quite often, the gas streams are injected at unequal velocities to enhance the aerodynamic interaction between the liquid sheet and surrounding atmosphere. In order to improve the mixing characteristics, practical atomizers confine the gas flows within ducts. Though the liquid sheet coming out of an injector is usually annular in shape, it can be considered to be planar as the mean radius of curvature is much larger than the sheet thickness. There are numerous studies on breakup of the planar liquid sheet, but none of them considered the simultaneous effects of confinement and unequal gas velocities on the spray characteristics. The present study performs a nonlinear temporal analysis of instabilities in the planar liquid sheet, produced by two co-flowing gas streams moving with unequal velocities within two solid walls. The results show that the para-sinuous mode dominates the breakup process at all flow conditions over the para-varicose mode of breakup. The sheet pattern is strongly influenced by gas velocities, particularly for the para-varicose mode. Spray characteristics are influenced by both gas velocity and proximity to the confining wall, but the former has a much more pronounced effect on droplet size. An increase in the difference between gas velocities at two interfaces drastically shifts the droplet size distribution toward finer droplets. Moreover, asymmetry in gas phase velocities affects the droplet velocity distribution more, only at low liquid Weber numbers for the input conditions chosen in the present study.

Acute Health Effects Among Military Personnel Participating in the Cleanup of the Hebei Spirit Oil Spill, 2007, in Taean County, Korea

PubMed Central

Gwack, Jin; Lee, Ju Hyung; Kang, Young Ah; Chang, Kyu-jin; Lee, Moo Sik; Hong, Jee Young

2012-01-01

Objectives This study was conducted to investigate acute health effects and its related factors among military personnel participating in the cleanup of the 2007 Hebei Spirit oil spill accident in Taean county, Korea. Methods We collected data on acute symptoms during the cleanup and their predictors using a self-administered questionnaire to 2624 military personnel. Selfreported symptoms included six neurologic symptoms, five respiratory symptoms, two dermatologic symptoms, three ophthalmic symptoms, and three general symptoms. Independent variables were demographic factors (gender, age, education level, and rank), health behavioral factors (smoking history and usage of the personal protective equipment such as masks and gloves), and occupational history such as where and for how long individuals participated in cleanup. Results The duration of work days was significantly associated with 17 acute symptoms except for itchiness and red skin.Working in Taean county also increased the risk of most acute symptoms except headache and back pain. In regard to personal protective equipment, wearing masks was mainly related to the development of respiratory symptoms such as sore throat and wearing other protective equipment was related to the development of sore throat, back pain, headache, and cough. Military personnel younger than 25 years reported 4.66 times more hot flushing and 5.39 times more itchiness than those older than 25 years. Conclusion It should be emphasized that for early-stage cleanup the number of workers should be minimized, sufficient personal protective equipment with approved quality for blocking noxious gas should be supplied, and systematic health care for the workers should be provided. Health effects could be diminished by providing adequate education regarding the appropriate use of protective equipment, especially to nonprofessionals such as residents and volunteers. To make disaster response expeditious, a national and regional preparedness

HANFORD SITE RIVER CORRIDOR CLEANUP

DOE Office of Scientific and Technical Information (OSTI.GOV)

BAZZELL, K.D.

2006-02-01

In 2005, the US Department of Energy (DOE) launched the third generation of closure contracts, including the River Corridor Closure (RCC) Contract at Hanford. Over the past decade, significant progress has been made on cleaning up the river shore that bordes Hanford. However, the most important cleanup challenges lie ahead. In March 2005, DOE awarded the Hanford River Corridor Closure Contract to Washington Closure Hanford (WCH), a limited liability company owned by Washington Group International, Bechtel National and CH2M HILL. It is a single-purpose company whose goal is to safely and efficiently accelerate cleanup in the 544 km{sup 2} Hanfordmore » river corridor and reduce or eliminate future obligations to DOE for maintaining long-term stewardship over the site. The RCC Contract is a cost-plus-incentive-fee closure contract, which incentivizes the contractor to reduce cost and accelerate the schedule. At $1.9 billion and seven years, WCH has accelerated cleaning up Hanford's river corridor significantly compared to the $3.2 billion and 10 years originally estimated by the US Army Corps of Engineers. Predictable funding is one of the key features of the new contract, with funding set by contract at $183 million in fiscal year (FY) 2006 and peaking at $387 million in FY2012. Another feature of the contract allows for Washington Closure to perform up to 40% of the value of the contract and subcontract the balance. One of the major challenges in the next few years will be to identify and qualify sufficient subcontractors to meet the goal.« less

GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard S. Meyer

Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting inmore » equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. KPS and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on field site selection. ChevronTexaco has nominated their Headlee Gas Plant in Odessa, TX for a commercial-scale dehydration test. Potting and module materials testing were initiated. Preliminary

GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard S. Meyer

Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting inmore » equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on field site selection. ChevronTexaco has nominated their Headlee Gas Plant in Odessa, TX for a commercial-scale dehydration test. Design and cost estimation for this new site are underway

Inexpensive, effective novel activated carbon fibers for sample cleanup: application to multipesticide residue analysis in food commodities using a QuEChERS method.

PubMed

Singh, Shiv; Srivastava, Anshuman; Singh, Sheelendra Pratap

2018-03-01

Phenolic resin based activated carbon fibers (ACFs) were applied for the first time as a reversed-dispersive solid-phase extraction (r-DSPE) sorbent. A modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) method was applied to determine 26 pesticides (organophosphates, organochlorines, synthetic pyrethroids, and herbicides) in different complex matrices, including cauliflower, cucumber, banana, apple, wheat, and black gram. Different physicochemical characterization techniques were used to investigate the engineering and structural properties of the r-DSPE sorbent. All the chromatographic analyses were performed with a gas chromatograph equipped with an electron capture detector. The recoveries of all 26 pesticides were acceptable (70-120%), with relative standard deviations of less than 15%. The limit of detection and the limit of quantification were 1.13-5.48 ng/g and 3.42-16.60 ng/g, respectively. In the original QuEChERS method, primary secondary amine is extensively used as the r-DSPE sorbent in the cleanup process, but it is eightfold more expensive than the ACFs used in this study. Therefore, the modified QuEChERS method using ACFs during the cleanup process is more efficient, cheaper, and more robust to determine pesticides from different types of matrices, including vegetables, grains, and fruits, and ACFs could be used as a cost-effective alternative to primary secondary amine. Graphical Abstract Sample clean-up using PSA and ACF as r-DSPE sorbent in QuEChERS method.

Streaming motions and kinematic distances to molecular clouds

NASA Astrophysics Data System (ADS)

Ramón-Fox, F. G.; Bonnell, Ian A.

2018-02-01

We present high-resolution smoothed particle hydrodynamics simulations of a region of gas flowing in a spiral arm and identify dense gas clouds to investigate their kinematics with respect to a Milky Way model. We find that, on average, the gas in the arms can have a net radial streaming motion of vR ≈ -9 km s-1 and rotate ≈ 6 km s-1 slower than the circular velocity. This translates to average peculiar motions towards the Galaxy centre and opposite to Galactic rotation. These results may be sensitive to the assumed spiral arm perturbation, which is ≈ 3 per cent of the disc potential in our model. We compare the actual distance and the kinematic estimate and we find that streaming motions introduce systematic offsets of ≈1 kpc. We find that the distance error can be as large as ±2 kpc, and the recovered cloud positions have distributions that can extend significantly into the inter-arm regions. We conclude that this poses a difficulty in tracing spiral arm structure in molecular cloud surveys.

System and method for producing substitute natural gas from coal

DOEpatents

Hobbs, Raymond [Avondale, AZ

2012-08-07

The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor

DOEpatents

Vimalchand, Pannalal; Liu, Guohai; Peng, WanWang

2010-08-10

The system of the present invention includes a centripetal cyclone for separating particulate material from a particulate laden gas solids stream. The cyclone includes a housing defining a conduit extending between an upstream inlet and a downstream outlet. In operation, when a particulate laden gas-solids stream passes through the upstream housing inlet, the particulate laden gas-solids stream is directed through the conduit and at least a portion of the solids in the particulate laden gas-solids stream are subjected to a centripetal force within the conduit.

Marine Debris Clean-Ups as Meaningful Science Learning

ERIC Educational Resources Information Center

Stepath, Carl M.; Bacon, Joseph Scott

2010-01-01

This seven to eight week hands-on Marine Debris Clean-up Project used a service project to provide an introduction of marine science ecology, watershed interrelationships, the scientific method, and environmental stewardship to 8th grade middle school students. It utilized inquiry based learning to introduce marine debris sources and impacts to…

Method for removing impurities from an impurity-containing fluid stream

DOEpatents

Ginosar, Daniel M.; Fox, Robert V.

2010-04-06

A method of removing at least one polar component from a fluid stream. The method comprises providing a fluid stream comprising at least one nonpolar component and at least one polar component. The fluid stream is contacted with a supercritical solvent to remove the at least one polar component. The at least one nonpolar component may be a fat or oil and the at least one polar component may be water, dirt, detergents, or mixtures thereof. The supercritical solvent may decrease solubility of the at least one polar component in the fluid stream. The supercritical solvent may function as a solvent or as a gas antisolvent. The supercritical solvent may dissolve the nonpolar components of the fluid stream, such as fats or oils, while the polar components may be substantially insoluble. Alternatively, the supercritical solvent may be used to increase the nonpolarity of the fluid stream.

75 FR 76280 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-08

.../ Tideflats superfund cleanup remediation efforts. This RNA will prohibit activities that would disturb the.../Tideflats superfund cleanup remediation process in those waters. These caps consist of approximately three... remediation efforts of the U.S. Environmental Protection Agency (EPA) and others in the Thea Foss and Wheeler...

Apparatus for dispensing compressed natural gas and liquified natural gas to natural gas powered vehicles

DOEpatents

Bingham, Dennis A.; Clark, Michael L.; Wilding, Bruce M.; Palmer, Gary L.

2007-05-29

A fueling facility and method for dispensing liquid natural gas (LNG), compressed natural gas (CNG) or both on-demand. The fueling facility may include a source of LNG, such as cryogenic storage vessel. A low volume high pressure pump is coupled to the source of LNG to produce a stream of pressurized LNG. The stream of pressurized LNG may be selectively directed through an LNG flow path or to a CNG flow path which includes a vaporizer configured to produce CNG from the pressurized LNG. A portion of the CNG may be drawn from the CNG flow path and introduced into the CNG flow path to control the temperature of LNG flowing therethrough. Similarly, a portion of the LNG may be drawn from the LNG flow path and introduced into the CNG flow path to control the temperature of CNG flowing therethrough.

On the radial oxygen distribution in the Galactic disc - II. Effects of local streams

NASA Astrophysics Data System (ADS)

Mishurov, Yu N.; Tkachenko, R. V.

2018-06-01

We analyse the idea that the local dips (˜1 kpc along the Galactic radius) observed in oxygen abundance are associated with the infall of intergalactic low-abundant gas (˜0.2 Z⊙) on to the Galactic disc during the last ˜100 Myr. We term such infall events local streams. The derived masses of the falling gas (of the order of several times 108 M⊙) are close to the observed ones (e.g. in the Magellanic Stream). Such local streams do not change the mean mass of oxygen ejected per core-collapse supernova (CC SN) event, so that our previous inference on probable upper initial masses for progenitors of CC SNe remains valid.

Simulation and Preliminary Design of a Cold Stream Experiment on Omega EP

NASA Astrophysics Data System (ADS)

Coffing, Shane; Angulo, Adrianna; Trantham, Matt; Malamud, Guy; Kuranz, Carolyn; Drake, R. P.

2017-10-01

Galaxies form within dark matter halos, accreting gas that may clump and eventually form stars. Infalling matter gradually increases the density of the halo, and, if cooling is insufficient, rising pressure forms a shock that slows the infalling gas, reducing star formation. However, galaxies with sufficient cooling become prolific star formers. A recent theory suggests that so called ``stream fed galaxies'' are able to acquire steady streams of cold gas via galactic ``filaments'' that penetrate the halo. The cold, dense filament flowing into a hot, less dense environment is potentially Kelvin-Helmholtz unstable. This instability may hinder the ability of the stream to deliver gas deeply enough into the halo. To study this process, we have begun preliminary design of a well-scaled laser experiment on Omega EP. We present here early simulation results and the physics involved. This work is funded by the U.S. Department of Energy, through the NNSA-DS and SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas, Grant Number DE-NA0002956, and the National Laser User Facility Program, Grant Number DE-NA0002719, and through the Laboratory for Laser Energetics, University of Rochester by the NNSA/OICF under Cooperative Agreement No. DE-NA0001944.

Method and apparatus for producing thermal vapor stream

DOEpatents

Cradeur, Robert R.; Sperry, John S.; Krajicek, Richard W.

1979-01-01

Method and apparatus for producing a thermal vapor stream for injecting into a subterranean formation for the recovery of liquefiable minerals therefrom, including a pressure vessel containing a high pressure combustion chamber for producing a heating gas for introduction into a heating gas injector. The heating gas injector is partly immersed in a steam generating section of the pressure vessel such that the heating gas is passed through the steam generating section to produce steam and combustion products which are directed between the pressure vessel and the combustion chamber for simultaneously cooling of the combustion chamber by further heating of the steam and combustion gases.

Minimization of steam requirements and enhancement of water-gas shift reaction with warm gas temperature CO2 removal

DOEpatents

Siriwardane, Ranjani V; Fisher, II, James C

2013-12-31

The disclosure utilizes a hydroxide sorbent for humidification and CO.sub.2 removal from a gaseous stream comprised of CO and CO.sub.2 prior to entry into a water-gas-shift reactor, in order to decrease CO.sub.2 concentration and increase H.sub.2O concentration and shift the water-gas shift reaction toward the forward reaction products CO.sub.2 and H.sub.2. The hydroxide sorbent may be utilized for absorbtion of CO.sub.2 exiting the water-gas shift reactor, producing an enriched H.sub.2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H.sub.2O product liberated as a result of the CO.sub.2 absorption.

75 FR 30753 - Regulated Navigation Area; Thea Foss and Wheeler-Osgood Waterways EPA Superfund Cleanup Site...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-02

... superfund cleanup remediation efforts. To more effectively protect those efforts, the Coast Guard is... cleanup remediation process in those waters. These caps consist of approximately three feet of sand and... remediation efforts that underlie the whole concept of the proposed RNA, and we would consult with the City of...

Impact of Unconventional Shale Gas Waste Water Disposal on Surficial Streams

NASA Astrophysics Data System (ADS)

Cozzarelli, I.; Akob, D.; Mumford, A. C.

2014-12-01

The development of unconventional natural gas resources has been rapidly increasing in recent years, however, the environmental impacts and risks are not yet well understood. A single well can generate up to 5 million L of produced water (PW) consisting of a blend of the injected fluid and brine from a shale formation. With thousands of wells completed in the past decade, the scope of the challenge posed in the management of this wastewater becomes apparent. The USGS Toxic Substances Hydrology Program is studying both intentional and unintentional releases of PW and waste solids. One method for the disposal of PW is underground injection; we are assessing the potential risks of this method through an intensive, interdisciplinary study at an injection disposal facility in the Wolf Creek watershed in WV. Disposal of PW via injection begun in 2002, with over 5.5 mil. L of PW injected to date. The facility consists of the injection well, a tank farm, and two former holding ponds (remediated in early 2014) and is bordered by two small tributaries of Wolf Creek. Water and sediments were acquired from these streams in June 2014, including sites upstream, within, and downstream from the facility. We are analyzing aqueous and solid phase geochemistry, mineralogy, hydrocarbon content, microbial community composition, and potential toxicity. Field measurements indicated that conductivity downstream (416 μS/cm) was elevated in comparison to upstream (74 μS/cm) waters. Preliminary data indicated elevated Cl- (115 mg/L) and Br- (0.88 mg/L) concentrations downstream, compared to 0.88 mg/L Cl- and <0.03 mg/L Br- upstream of the facility. Because elevated TDS is a marker of PW, these data provide a first indication that PW from the facility is impacting nearby streams. In addition, total Fe concentrations downstream were 8.1 mg/L, far in excess of the 0.13 mg/L found upstream from the facility, suggesting the potential for microbial Fe cycling. We are conducting a broad suite of

Engineering Forum Issue Paper: Online Hazardous Waste Cleanup Technical Resources

EPA Pesticide Factsheets

This issue paper is intended to give the reader examples of some online technical resources that can assist with hazardous waste cleanups in the Superfund, Resource Conservation and Recovery Act (RCRA), and Brownfields programs.

Method of controlling injection of oxygen into hydrogen-rich fuel cell feed stream

DOEpatents

Meltser, Mark Alexander; Gutowski, Stanley; Weisbrod, Kirk

2001-01-01

A method of operating a H.sub.2 --O.sub.2 fuel cell fueled by hydrogen-rich fuel stream containing CO. The CO content is reduced to acceptable levels by injecting oxygen into the fuel gas stream. The amount of oxygen injected is controlled in relation to the CO content of the fuel gas, by a control strategy that involves (a) determining the CO content of the fuel stream at a first injection rate, (b) increasing the O.sub.2 injection rate, (c) determining the CO content of the stream at the higher injection rate, (d) further increasing the O.sub.2 injection rate if the second measured CO content is lower than the first measured CO content or reducing the O.sub.2 injection rate if the second measured CO content is greater than the first measured CO content, and (e) repeating steps a-d as needed to optimize CO consumption and minimize H.sub.2 consumption.

Method for sequestering CO.sub.2 and SO.sub.2 utilizing a plurality of waste streams

DOEpatents

Soong, Yee [Monroeville, PA; Allen, Douglas E [Salem, MA; Zhu, Chen [Monroe County, IN

2011-04-12

A neutralization/sequestration process is provided for concomitantly addressing capture and sequestration of both CO.sub.2 and SO.sub.2 from industrial gas byproduct streams. The invented process concomitantly treats and minimizes bauxite residues from aluminum production processes and brine wastewater from oil/gas production processes. The benefits of this integrated approach to coincidental treatment of multiple industrial waste byproduct streams include neutralization of caustic byproduct such as bauxite residue, thereby decreasing the risk associated with the long-term storage and potential environmental of storing caustic materials, decreasing or obviating the need for costly treatment of byproduct brines, thereby eliminating the need to purchase CaO or similar scrubber reagents typically required for SO.sub.2 treatment of such gasses, and directly using CO.sub.2 from flue gas to neutralize bauxite residue/brine mixtures, without the need for costly separation of CO.sub.2 from the industrial byproduct gas stream by processes such as liquid amine-based scrubbers.

Report: EPA Needs to Track Compliance with Superfund Cleanup Requirements

EPA Pesticide Factsheets

Report #08-P-0141, April 28, 2008. According to EPA’s Superfund information system, there were 3,397 active Superfund enforcement instruments to ensure cleanups at National Priorities List sites as of September 30, 2007.

Introduction to Energy Conservation and Production at Waste Cleanup Sites

EPA Pesticide Factsheets

This issue paper, prepared by EPA's Engineering Forum under the Technical Support Project, provides an overview on the considerations for energy conservation and production during the design and (O&M) phases of waste cleanup projects.

Two-stream Convolutional Neural Network for Methane Emissions Quantification

NASA Astrophysics Data System (ADS)

Wang, J.; Ravikumar, A. P.; McGuire, M.; Bell, C.; Tchapmi, L. P.; Brandt, A. R.

2017-12-01

Methane, a key component of natural gas, has a 25x higher global warming potential than carbon dioxide on a 100-year basis. Accurately monitoring and mitigating methane emissions require cost-effective detection and quantification technologies. Optical gas imaging, one of the most commonly used leak detection technology, adopted by Environmental Protection Agency, cannot estimate leak-sizes. In this work, we harness advances in computer science to allow for rapid and automatic leak quantification. Particularly, we utilize two-stream deep Convolutional Networks (ConvNets) to estimate leak-size by capturing complementary spatial information from still plume frames, and temporal information from plume motion between frames. We build large leak datasets for training and evaluating purposes by collecting about 20 videos (i.e. 397,400 frames) of leaks. The videos were recorded at six distances from the source, covering 10 -60 ft. Leak sources included natural gas well-heads, separators, and tanks. All frames were labeled with a true leak size, which has eight levels ranging from 0 to 140 MCFH. Preliminary analysis shows that two-stream ConvNets provides significant accuracy advantage over single steam ConvNets. Spatial stream ConvNet can achieve an accuracy of 65.2%, by extracting important features, including texture, plume area, and pattern. Temporal stream, fed by the results of optical flow analysis, results in an accuracy of 58.3%. The integration of the two-stream ConvNets gives a combined accuracy of 77.6%. For future work, we will split the training and testing datasets in distinct ways in order to test the generalization of the algorithm for different leak sources. Several analytic metrics, including confusion matrix and visualization of key features, will be used to understand accuracy rates and occurrences of false positives. The quantification algorithm can help to find and fix super-emitters, and improve the cost-effectiveness of leak detection and repair

Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust

DOEpatents

Wijmans, Johannes G [Menlo Park, CA; Merkel, Timothy C [Menlo Park, CA; Baker, Richard W [Palo Alto, CA

2012-05-15

A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

Multi-component removal in flue gas by aqua ammonia

DOEpatents

Yeh, James T [Bethel Park, PA; Pennline, Henry W [Bethel Park, PA

2007-08-14

A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

Improving Sampling, Analysis, and Data Management for Site Investigation and Cleanup

EPA Pesticide Factsheets

The United States Environmental Protection Agency (EPA) supports the adoption of streamlined approaches to sampling, analysis, and data management activities conducted during site assessment, characterization, and cleanup.

The effect of wind and currents on gas exchange in an estuarine system

NASA Technical Reports Server (NTRS)

Broecker, W. S.; Ledwell, J. R.; Bopp, R.

1987-01-01

The objectives were to develop a non-volatile tracer to use in gas exchange experiments in laterally unconfined systems and to study applications of deliberate tracers in limnology and oceanography. Progress was made on both fronts but work on the development of the non-volatile tracer proved to be more difficult and labor intensive that anticipated so no field experiments using non-volatile tracers was performed as yet. In the search for a suitable non-volatile tracer for an ocean scale gas exchange experiment a tracer was discovered which does not have the required sensitivity for a large scale experiment, but is very easy to analyze and will be well suited for smaller experiments such as gas exchange determinations on rivers and streams. Sulfur hexafluoride, SF6, was used successfully as a volatile tracer along with tritium as a non-volatile tracer to study gas exchange rates from a primary stream. This is the first gas exchange experiment in which gas exchange rates were determined on a head water stream where significant groundwater input occurs along the reach. In conjunction with SF6, Radon-222 measurements were performed on the groundwater and in the stream. The feasibility of using a combination of SF6 and radon is being studied to determine groundwater inputs and gas exchange of rates in streams with significant groundwater input without using a non-volatile tracer.

Integration of stripping of fines slurry in a coking and gasification process

DOEpatents

DeGeorge, Charles W.

1980-01-01

In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

Catalysts, systems and methods to reduce NOX in an exhaust gas stream

DOEpatents

Castellano, Christopher R.; Moini, Ahmad; Koermer, Gerald S.; Furbeck, Howard

2010-07-20

Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having an SCR catalyst comprising silver tungstate on an alumina support. The emissions treatment system may be used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines. An emissions treatment system may further comprise an injection device operative to dispense a hydrocarbon reducing agent upstream of the catalyst.

Land Disturbance Associated with Oil and Gas Development and Effects of Development-Related Land Disturbance on Dissolved-Solids Loads in Streams in the Upper Colorado River Basin, 1991, 2007, and 2025

USGS Publications Warehouse

Buto, Susan G.; Kenney, Terry A.; Gerner, Steven J.

2010-01-01

Oil and gas resource development in the Upper Colorado River Basin (UCRB) has increased substantially since the year 2000. The UCRB encompasses several significant oil and gas producing areas that have the potential for continued oil and gas resource development. Land disturbance associated with oil and gas resource development is caused by activities related to constructing drill pads to contain drilling and well maintenance equipment and roads to access the drill pad. Land disturbed by oil and gas development has the potential to cause increased erosion, stream degradation, habitat fragmentation and alteration, and increase public use of areas that may be environmentally sensitive. Land disturbance resulting from oil and gas resource development has not been monitored and mapped on a regional scale in the UCRB. However, information on the location and age of oil and gas wells in the UCRB is available. These data combined with geographic data analysis and modeling techniques were used to estimate the total area of disturbed land associated with oil and gas resource development in 1991 and in 2007 in the UCRB. Additional information about anticipated oil and gas development in the UCRB was used to project land disturbance to the year 2025. Results of the analysis indicate that approximately 117,500 acres (183 mi2) of total land disturbance was associated with drill pads and related roads in the UCRB in 1991. The estimated area of disturbed land associated with oil and gas development increased 53 percent to 179,400 acres (280 mi2) in 2007. Projecting oil and gas development through 2025 results in a potential near doubling of the land surface disturbance to approximately 319,300 acres (500 mi2). Estimated land disturbance for 1991 and 2007 were input to a contaminant transport model developed for the UCRB to assess the statistical significance of energy-related land disturbance to contributing dissolved solids to basin streams. The statistical assessment was an

A Cs(x)WO3/ZnO nanocomposite as a smart coating for photocatalytic environmental cleanup and heat insulation.

PubMed

Wu, Xiaoyong; Yin, Shu; Xue, Dongfeng; Komarneni, Sridhar; Sato, Tsugio

2015-10-28

A novel CsxWO3/ZnO smart coating was proposed to achieve multiple functions, such as heat insulation, photodecomposition of toxic NO gas, blocking of harmful UV light, etc. In this composite coating, CsxWO3 nanorods were used as a NIR and UV light shielding material while ZnO nanoparticles were utilized as a photocatalyst and a material to enhance visible light transmittance and block UV light. When the mass ratio of CsxWO3/ZnO was 1, the composite coating possessed a very good visible light transmittance of over 80% and an excellent UV-shielding ability. This novel coating showed heat insulation that is superior to the ITO coating and photocatalytic decontamination of NO gas that is superior to the standard TiO2 (P25). The proposed CsxWO3/ZnO smart coating is a promising material not only for energy saving but also for environmental cleanup.

Planar solid phase extraction clean-up for pesticide residue analysis in tea by liquid chromatography-mass spectrometry.

PubMed

Oellig, Claudia; Schwack, Wolfgang

2012-10-19

Efficient clean-up is indispensable for preventing matrix effects in multi-residue analysis of pesticides in food by liquid and gas chromatography (LC and GC) coupled to mass spectrometry (MS). High-throughput planar solid phase extraction (HTpSPE) was recently introduced as a new clean-up concept in residue analysis of pesticides in fruit and vegetables (C. Oellig, W. Schwack, 2011 [45]). Thin-layer chromatography (TLC) was used to completely separate pesticides from matrix compounds and to focus them into a sharp zone, followed by extraction of the target zone by the TLC-MS interface. As rather challenging matrices, tea samples were chosen in this study. Besides chlorophylls and polyphenols, high amount of caffeine is co-extracted resulting in strong matrix effects both in LC-MS and GC-MS. The former HTpSPE procedure was adapted to initial extracts of green and black tea resulting in colorless extracts nearly free of matrix effects and interferences, as shown for seven chemically representative pesticides (acetamiprid, penconazole, azoxystrobin, chlorpyrifos, pirimicarb, fenarimol, and mepanipyrim). LC-MS/MS calibration curves obtained in the range of 0.002-0.5 mg/kg from matrix-matched standards and solvent standards were nearly identical and demonstrated the effectiveness of clean-up by HTpSPE. Mean recoveries determined by LC-MS/MS against solvent standards at spiking levels of 0.01 and 0.1 mg/kg ranged between 72 and 114% with relative standard deviations (RSDs) of 0.7-4.7% (n=4), while LC-MS measurements of tea samples spiked at 1 mg/kg provided recoveries of 81-104% with RSDs of 1.2-4.9% (n=6). Using LC-MS/MS, the method showed high sensitivity with signal-to-noise ratios>10 for concentrations below 0.002 mg/kg. HTpSPE of one sample was done in a few minutes, while numerous samples were cleaned in parallel at minimal costs with very low sample and solvent consumption. Copyright © 2012 Elsevier B.V. All rights reserved.

Cleanup Verification Package for the 300 VTS Waste Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

S. W. Clark and T. H. Mitchell

2006-03-13

This cleanup verification package documents completion of remedial action for the 300 Area Vitrification Test Site, also known as the 300 VTS site. The site was used by Pacific Northwest National Laboratory as a field demonstration site for in situ vitrification of soils containing simulated waste.

Finite Element Modeling and Analysis of Powder Stream in Low Pressure Cold Spray Process

NASA Astrophysics Data System (ADS)

Goyal, Tarun; Walia, Ravinderjit Singh; Sharma, Prince; Sidhu, Tejinder Singh

2016-07-01

Low pressure cold gas dynamic spray (LPCGDS) is a coating process that utilize low pressure gas (5-10 bars instead of 25-30 bars) and the radial injection of powder instead of axial injection with the particle range (1-50 μm). In the LPCGDS process, pressurized compressed gas is accelerated to the critical velocity, which depends on length of the divergent section of nozzle, the propellant gas and particle characteristics, and the diameters ratio of the inlet and outer diameters. This paper presents finite element modeling (FEM) of powder stream in supersonic nozzle wherein adiabatic gas flow and expansion of gas occurs in uniform manner and the same is used to evaluate the resultant temperature and velocity contours during coating process. FEM analyses were performed using commercial finite volume package, ANSYS CFD FLUENT. The results are helpful to predict the characteristics of powder stream at the exit of the supersonic nozzle.

Improving risk assessments for manufactured gas plant soils by measuring PAH availability.

PubMed

Stroo, Hans F; Nakles, David V; Kreitinger, Joseph P; Loehr, Raymond C; Hawthorne, Steven B; Luthy, Richard G; Holman, Hoi-Ying; LaPierre, Adrienne

2005-07-01

Remediation of soils at oil-gas manufactured gas plant (MGP) sites is driven primarily by the human health risks posed by the carcinogenic polycyclic aromatic hydrocarbons (PAHs), particularly benzo[a]pyrene (BaP), that are associated with lampblack residues. Although PAHs on lampblack are tightly sorbed, risk assessments do not account for this reduced availability. A multi-investigator study of 7 oil-gas MGP site soil samples demonstrated that the dermal and ingestion absorption factors are far lower than current default assumptions used in risk assessments. Using these sample-specific absorption factors in standard risk assessment equations increased risk-based cleanup levels by a factor of 72 on average (with a range from 23 to 142 times the default level). The rapidly released fraction of the BaP in each sample, as measured by supercritical fluid extraction, was closely correlated (r2 = 0.96) to these calculated cleanup levels. The weight of evidence developed during this research indicates that the risks posed by PAHs on lampblack are far less than assumed when using default absorption factors and that a tiered evaluation protocol employing chemical analyses, chemical release data, and in vitro bioassays can be used to establish more realistic site-specific criteria.

Clamp and Gas Nozzle for TIG Welding

NASA Technical Reports Server (NTRS)

Gue, G. B.; Goller, H. L.

1982-01-01

Tool that combines clamp with gas nozzle is aid to tungsten/inert-gas (TIG) welding in hard-to-reach spots. Tool holds work to be welded while directing a stream of argon gas at weld joint, providing an oxygen-free environment for tungsten-arc welding.

Stream Width Dynamics in a Small Headwater Catchment

NASA Astrophysics Data System (ADS)

Barefoot, E. A.; Pavelsky, T.; Allen, G. H.; Zimmer, M. A.; McGlynn, B. L.

2016-12-01

Changing streamflow conditions cause small, ephemeral and intermittent stream networks to expand and contract, while simultaneously driving widening and narrowing of streams. The resulting dynamic surface area of ephemeral streams impacts critical hydrological and biogeochemical processes, including air-water gas exchange, solute transport, and sediment transport. Despite the importance of these dynamics, to our knowledge there exists no complete study of how stream widths vary throughout an entire catchment in response to changing streamflow conditions. Here we present the first characterization of how variable hydrologic conditions impact the distribution of stream widths in a 48 ha headwater catchment in the Stony Creek Research Watershed, NC, USA. We surveyed stream widths longitudinally every 5 m on 12 occasions over a range of stream discharge from 7 L/s to 128 L/s at the catchment outlet. We hypothesize that the shape and location of the stream width distribution are driven by the action of two interrelated mechanisms, network extension and at-a-station widening, both of which increase with discharge. We observe that during very low flow conditions, network extension more significantly influences distribution location, and during high flow conditions stream widening is the dominant driver. During moderate flows, we observe an approximately 1 cm rightward shift in the distribution peak with every additional 10 L/s of increased discharge, which we attribute to a greater impact of at-a-station widening on distribution location. Aside from this small shift, the qualitative location and shape of the stream width distribution are largely invariant with changing streamflow. We suggest that the basic characteristics of stream width distributions constitute an equilibrium between the two described mechanisms across variable hydrologic conditions.

Activation of catalysts for synthesizing methanol from synthesis gas

DOEpatents

Blum, David B.; Gelbein, Abraham P.

1985-01-01

A method for activating a methanol synthesis catalyst is disclosed. In this method, the catalyst is slurried in an inert liquid and is activated by a reducing gas stream. The activation step occurs in-situ. That is, it is conducted in the same reactor as is the subsequent step of synthesizing methanol from a methanol gas stream catalyzed by the activated catalyst still dispersed in a slurry.

Using geostatistics to evaluate cleanup goals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marcon, M.F.; Hopkins, L.P.

1995-12-01

Geostatistical analysis is a powerful predictive tool typically used to define spatial variability in environmental data. The information from a geostatistical analysis using kriging, a geostatistical. tool, can be taken a step further to optimize sampling location and frequency and help quantify sampling uncertainty in both the remedial investigation and remedial design at a hazardous waste site. Geostatistics were used to quantify sampling uncertainty in attainment of a risk-based cleanup goal and determine the optimal sampling frequency necessary to delineate the horizontal extent of impacted soils at a Gulf Coast waste site.

Oil spill cleanup method and apparatus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mayes, F.M.

1980-06-24

A method for removing oil from the surface of water where an oil spill has occurred, particularly in obstructed or shallow areas, which comprises partially surrounding a hovercraft with a floating oil-collecting barrier, there being no barrier at the front of the hovercraft, moving the oil-barrier-surrounded-hovercraft into oil contaminated water, and collecting oil gathered within the barrier behind the hovercraft through a suction line which carries the oil to a storage tank aboard the hovercraft. The invention also embodies the hovercraft adapted to effect an oil spill cleanup.

Thief process for the removal of mercury from flue gas

DOEpatents

Pennline, Henry W.; Granite, Evan J.; Freeman, Mark C.; Hargis, Richard A.; O'Dowd, William J.

2003-02-18

A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

Controls on Nitrous Oxide Emissions from the Hyporheic Zones of Streams.

PubMed

Quick, Annika M; Reeder, W Jeffery; Farrell, Tiffany B; Tonina, Daniele; Feris, Kevin P; Benner, Shawn G

2016-11-01

The magnitude and mechanisms of nitrous oxide (N 2 O) release from rivers and streams are actively debated. The complex interactions of hydrodynamic and biogeochemical controls on emissions of this important greenhouse gas preclude prediction of when and where N 2 O emissions will be significant. We present observations from column and large-scale flume experiments supporting an integrative model of N 2 O emissions from stream sediments. Our results show a distinct, replicable, pattern of nitrous oxide generation and consumption dictated by subsurface (hyporheic) residence times and biological nitrogen reduction rates. Within this model, N 2 O emission from stream sediments requires subsurface residence times (and microbially mediated reduction rates) be sufficiently long (and fast reacting) to produce N 2 O by nitrate reduction but also sufficiently short (or slow reacting) to limit N 2 O conversion to dinitrogen gas. Most subsurface exchange will not result in N 2 O emissions; only specific, intermediate, residence times (reaction rates) will both produce and release N 2 O to the stream. We also confirm previous observations that elevated nitrate and declining organic carbon reactivity increase N 2 O production, highlighting the importance of associated reaction rates in controlling N 2 O accumulation. Combined, these observations help constrain when N 2 O release will occur, providing a predictive link between stream geomorphology, hydrodynamics, and N 2 O emissions.

Environmental liability protection and other advantages of voluntary cleanup programs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bost, R.C.; Linton, K.E.

Historically, regulatory agencies have required that contaminated sites be returned to pristine conditions, often at very high costs. Fear of these enormous environmental liabilities has resulted in abandonment of many industrial and commercial properties, referred to as brownfields. The development of Risk-Based Corrective Action programs has provided a means for regulatory agencies to evaluate contaminated sites based on risk to human health and the environment, resulting in more reasonable remedial measures and costs. Governmental bodies have created a more flexible means of addressing contaminated sites using Risk-Based Corrective Action and other incentives to encourage the redevelopment of sites through Voluntarymore » Cleanup Programs. This study describes the development of Voluntary Cleanup Programs, and the successful implementation of Risk-Based Corrective Action with a focus on the states of Texas, Louisiana, and Oklahoma.« less

GAS/LIQUID MEMBRANES FOR NATURAL GAS UPGRADING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard S. Meyer

Gas Technology Institute (GTI) is conducting this research program whose objective is to develop gas/liquid membranes for natural gas upgrading to assist DOE in achieving their goal of developing novel methods of upgrading low quality natural gas to meet pipeline specifications. Kvaerner Process Systems (KPS) and W. L. Gore & Associates (GORE) gas/liquid membrane contactors are based on expanded polytetrafluoroethylene (ePTFE) membranes acting as the contacting barrier between the contaminated gas stream and the absorbing liquid. These resilient membranes provide much greater surface area for transfer than other tower internals, with packing densities five to ten times greater, resulting inmore » equipment 50-70% smaller and lower weight for the same treating service. The scope of the research program is to (1) build and install a laboratory- and a field-scale gas/liquid membrane absorber; (2) operate the units with a low quality natural gas feed stream for sufficient time to verify the simulation model of the contactors and to project membrane life in this severe service; and (3) conducted an economic evaluation, based on the data, to quantify the impact of the technology. Chevron, one of the major producers of natural gas, has offered to host the test at a gas treating plant. KPS will use their position as a recognized leader in the construction of commercial amine plants for building the unit along with GORE providing the membranes. GTI will provide operator and data collection support during lab- and field-testing to assure proper analytical procedures are used. Kvaerner and GTI will perform the final economic evaluation. GTI will provide project management and be responsible for reporting and interactions with DOE on this project. Efforts this quarter have concentrated on field site selection. ChevronTexaco has nominated their Headlee Gas Plant in Odessa, TX for a commercial-scale dehydration test. Design and cost estimation for this new site are underway. A

Department of Defense Environmental Cleanup Cost Allowability Policy.

DTIC Science & Technology

1994-12-01

The environment is directly affected by the industrial requirements and manufacturing processes necessary to provide those goods and services. As...and the industrial base. To begin the process , DCMC initiated the Environmental Initiatives Task Force Pilot Cost Allowance Program at five locations...policy covering environmental cleanup costs. Information will be provided to assist in the decision making process regarding the factors affecting the

Method and apparatus for dispensing compressed natural gas and liquified natural gas to natural gas powered vehicles

DOEpatents

Bingham, Dennis A.; Clark, Michael L.; Wilding, Bruce M.; Palmer, Gary L.

2005-05-31

A fueling facility and method for dispensing liquid natural gas (LNG), compressed natural gas (CNG) or both on-demand. The fueling facility may include a source of LNG, such as cryogenic storage vessel. A low volume high pressure pump is coupled to the source of LNG to produce a stream of pressurized LNG. The stream of pressurized LNG may be selectively directed through an LNG flow path or to a CNG flow path which includes a vaporizer configured to produce CNG from the pressurized LNG. A portion of the CNG may be drawn from the CNG flow path and introduced into the CNG flow path to control the temperature of LNG flowing therethrough. Similarly, a portion of the LNG may be drawn from the LNG flow path and introduced into the CNG flow path to control the temperature of CNG flowing therethrough.

Evaluation of New Cleanup Agents for Analysis of Pesticide Residues in Tea.

PubMed

Ueda, Yuko; Honda, Katsuhisa

2017-01-01

We evaluated the effectiveness of new cleanup agents (S-NH 2 and S-Si) compared with other previously reported cleanup agents (octadecylsilane, graphitized carbon, aminopropyl and silica gel) for removal of interfering substances such as catechin and caffeine prior to analysis of pesticide residues in tea. S-NH 2 and S-Si were highly efficient in removal of catechin and caffeine, respectively. Recoveries of 80 pesticides using S-NH 2 and S-Si were tested, and more than 70% of pesticides showed recovery greater than 70%. These results indicate that S-NH 2 and S-Si agents will be useful for analysis of pesticide residues in tea.

Technical support for the EPA cleanup rule on radioactively contaminated sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hull, H.B.; Newman, A.; Wolbarst, A.B.

1995-12-31

The U.S. Environmental Protection Agency (EPA) is developing a radiation site cleanup regulation for the protection of the public from radionuclide contamination at sites that are to be cleaned up and released for public use. The regulation will apply to sites under the control of Federal agencies, and to sites licensed by the Nuclear Regulatory Commission (NRC) or NRC Agreement States. The agency is therefore conducting a comprehensive technical analysis aimed at developing information that will be used to support the rule. This presentation describes the regulation and the approach developed to determine how radiological health impacts and volumes ofmore » soil requiring remediation vary as functions of the possible cleanup dose or risk level.« less

Techniques for Minimizing and Monitoring the Impact of Pipeline Construction on Coastal Streams

Treesearch

Thomas W. Mulroy; John R. Storrer; Vincent J. Semonsen; Michael L. Dungan

1989-01-01

This paper describes specific measures recently employed for protection of riparian resources during construction of an oil and gas pipeline that crossed coastal reaches of 23 perennial and intermittent streams between Point Conception and Gaviota in Santa Barbara County, California. Flumes were constructed to maintain stream flow; anchored straw bales and silt fences...

Synthesis gas method and apparatus

DOEpatents

Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie; Kosowski, Lawrence W; Robinson, Charles

2015-11-06

A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

Synthesis gas method and apparatus

DOEpatents

Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie R.; Kosowski, Lawrence W.; Robinson, Charles

2013-01-08

A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

Green Remediation Best Management Practices: Integrating Renewable Energy into Site Cleanup

EPA Pesticide Factsheets

The U.S. Environmental Protection Agency (EPA) Principles for Greener Cleanups outline the Agency's policy for evaluating and minimizing the environmental 'footprint' of activities undertaken when cleaning up a contaminated site.

Apparatus for preventing particle deposition from process streams on optical access windows

DOEpatents

Logan, Ronald G.; Grimm, Ulrich

1993-01-01

An electrostatic precipitator is disposed inside and around the periphery of the window of a viewing port communicating with a housing through which a particle-laden gas stream is being passed. The precipitator includes a pair of electrodes around the periphery of the window, spaced apart and connected to a unidirectional voltage source. Application of high voltage from the source to the electrodes causes air molecules in the gas stream to become ionized, attaching to solid particles and causing them to be deposited on a collector electrode. This prevents the particles from being deposited on the window and keeps the window clean for viewing and making optical measurements.

A simple technique for continuous measurement of time-variable gas transfer in surface waters

USGS Publications Warehouse

Tobias, Craig R.; Bohlke, John Karl; Harvey, Judson W.; Busenberg, Eurybiades

2009-01-01

Mass balance models of dissolved gases in streams, lakes, and rivers serve as the basis for estimating wholeecosystem rates for various biogeochemical processes. Rates of gas exchange between water and the atmosphere are important and error-prone components of these models. Here we present a simple and efficient modification of the SF6 gas tracer approach that can be used concurrently while collecting other dissolved gas samples for dissolved gas mass balance studies in streams. It consists of continuously metering SF6-saturated water directly into the stream at a low rate of flow. This approach has advantages over pulse injection of aqueous solutions or bubbling large amounts of SF6 into the stream. By adding the SF6 as a saturated solution, we minimize the possibility that other dissolved gas measurements are affected by sparging and/or bubble injecta. Because the SF6 is added continuously we have a record of changing gas transfer velocity (GTV) that is contemporaneous with the sampling of other nonconservative ambient dissolved gases. Over a single diel period, a 30% variation in GTV was observed in a second-order stream (Sugar Creek, Indiana, USA). The changing GTV could be attributed in part to changes in temperature and windspeed that occurred on hourly to diel timescales.

Resonant Drag Instabilities in protoplanetary disks: the streaming instability and new, faster-growing instabilities

NASA Astrophysics Data System (ADS)

Squire, Jonathan; Hopkins, Philip F.

2018-04-01

We identify and study a number of new, rapidly growing instabilities of dust grains in protoplanetary disks, which may be important for planetesimal formation. The study is based on the recognition that dust-gas mixtures are generically unstable to a Resonant Drag Instability (RDI), whenever the gas, absent dust, supports undamped linear modes. We show that the "streaming instability" is an RDI associated with epicyclic oscillations; this provides simple interpretations for its mechanisms and accurate analytic expressions for its growth rates and fastest-growing wavelengths. We extend this analysis to more general dust streaming motions and other waves, including buoyancy and magnetohydrodynamic oscillations, finding various new instabilities. Most importantly, we identify the disk "settling instability," which occurs as dust settles vertically into the midplane of a rotating disk. For small grains, this instability grows many orders of magnitude faster than the standard streaming instability, with a growth rate that is independent of grain size. Growth timescales for realistic dust-to-gas ratios are comparable to the disk orbital period, and the characteristic wavelengths are more than an order of magnitude larger than the streaming instability (allowing the instability to concentrate larger masses). This suggests that in the process of settling, dust will band into rings then filaments or clumps, potentially seeding dust traps, high-metallicity regions that in turn seed the streaming instability, or even overdensities that coagulate or directly collapse to planetesimals.

Boiler Stack Gas Heat Recovery

DTIC Science & Technology

1987-09-01

flue gas environ- ment. Conventional finned metal (aluminum, copper, stainless steel) tubes should not be used unless controls maintain the outer metal...xý Table 5. Summary of Actual Applications of Fiberglass Reinforced Plastic (FRP) in Corrosive Flue Gas Desulfurization Service Equipment Corrosive...process-steam/water heating. The procedure for estimating the energy potential of a given flue - gas stream is explained in detail with sample plots

Pulse combusted acoustic agglomeration apparatus and process

DOEpatents

Mansour, Momtaz N.; Chandran, Ravi

1994-01-01

An improved apparatus and process for removal of particulates entrained in a gas stream are provided. The removal process employs a pulse combustor to provide an acoustic pressure wave to acoustically enhance agglomeration of particulates which may be collected and removed using a conventional separation apparatus. The apparatus may be employed as a direct fired system for improved operation of gas-operated equipment such as a gas turbine, or may, alternatively, be employed as an add-on subsystem for combustion exhaust clean-up. Additionally, added particulates may include a sorbent for effecting sorption of other contaminants such as sulfur. Various other particulates for contaminant removal may also be introduced into the system as exemplified by alkali-gettering agents.

Using the Triad Approach to Streamline Brownfields Site Assessment and Cleanup

EPA Pesticide Factsheets

EPA's Brownfields Technology Support Center (BTSC) has prepared this document to provide an educational tool for site owners, project managers, and regulators to help streamline assessment and cleanup activities at brownfields sites.

Determination of mycotoxins produced by Fusarium isolates from banana fruits by capillary gas chromatography and high-performance liquid chromatography.

PubMed

Jiménez, M; Mateo, R

1997-08-22

A method of analysis for trichothecenes (nivalenol, deoxynivalenol, 3- and 15-acetyldeoxynivalenol, diacetoxyscirpenol, neosolaniol, T-2 tetraol, T-2 and HT-2 toxins), zearalenone and zearalenols, and another method for determination of fumonisin B1 are described and applied to cultures of Fusarium isolated from bananas. Both methods were adapted from different techniques of extraction, clean-up and determination of these mycotoxins. The first method involves extraction with methanol-1% aqueous sodium chloride, clean-up of extracts by partition with hexane and dichloromethane, additional solid reversed-phase clean-up and analysis of two eluates by both high-performance liquid chromatography with ultraviolet detection and capillary gas chromatography. The method for fumonisin B1 implies extraction with aqueous methanol, concentration, clean-up with water and methanol on Amberlite XAD-2 column, formation of a fluorescent 4-fluoro-7-nitrobenzofurazan derivative and analysis by high-performance liquid chromatography with fluorescence detection. Both procedures give good limits of detection and recoveries, and are considered suitable for the detection and quantification of the studied toxins in corn and rice cultures of Fusarium spp. isolated from banana fruits.

Revealing the Ionization Properties of the Magellanic Stream Using Optical Emission

NASA Astrophysics Data System (ADS)

Barger, K. A.; Madsen, G. J.; Fox, A. J.; Wakker, B. P.; Bland-Hawthorn, J.; Nidever, D.; Haffner, L. M.; Antwi-Danso, Jacqueline; Hernandez, Michael; Lehner, N.; Hill, A. S.; Curzons, A.; Tepper-García, T.

2017-12-01

The Magellanic Stream, a gaseous tail that trails behind the Magellanic Clouds, could replenish the Milky Way (MW) with a tremendous amount of gas if it reaches the Galactic disk before it evaporates into the halo. To determine how the Magellanic Stream’s properties change along its length, we have conducted an observational study of the Hα emission, along with other optical warm ionized gas tracers, toward 39 sight lines. Using the Wisconsin Hα Mapper telescope, we detect Hα emission brighter than 30–50 mR in 26 of our 39 sight lines. This Hα emission extends over 2^\\circ away from the H I emission. By comparing {I}{{H}α } and {I}[{{O}{{I}}]}, we find that regions with {log}{N}{{H}{{I}}}/{{cm}}-2≈ 19.5{--}20.0 are 16%–67% ionized. Most of the {I}{{H}α } along the Magellanic Stream are much higher than expected if the primary ionization source is photoionization from Magellanic Clouds, the MW, and the extragalactic background. We find that the additional contribution from self ionization through a “shock cascade” that results as the Stream plows through the halo might be sufficient to reproduce the underlying level of Hα emission along the Stream. In the sparsely sampled region below the South Galactic Pole, there exists a subset of sight lines with uncharacteristically bright emission, which suggest that gas is being ionized further by an additional source that could be a linked to energetic processes associated with the Galactic center.

Cleanups In My Community (CIMC) - Federal Facility RCRA Sites, National Layer

EPA Pesticide Factsheets

Federal facilities are properties owned by the federal government. This data layer provides access to Federal facilities that are Resource Conservation and Recovery Act (RCRA) sites as part of the CIMC web service. The Resource Conservation and Recovery Act, among other things, helps ensure that wastes are managed in an environmentally sound manner so as to protect human health and the environment from the potential hazards of waste disposal.In particular, RCRA tightly regulates all hazardous waste from cradle to grave. In general, all generators, transporters, treaters, storers, and disposers of hazardous waste are required to provide information about their activities to state environmental agencies. These agencies, in turn pass on the information to regional and national EPA offices. Accidents or other activities at facilities that treat, store or dispose of hazardous wastes have sometimes led to the release of hazardous waste or hazardous constituents into soil, ground water, surface water, or air. When that happens, the RCRA Corrective Action program is one program that may be used to accomplish the necessary cleanup.In Cleanups in My Community, you can map or list RCRA Corrective Action sites that are currently undergoing corrective action, sites for which a remedy has been selected, sites for which construction has been completed, and sites where the corrective action cleanup is complete. This data layer shows those RCRA sites that are located at Federa

Process for off-gas particulate removal and apparatus therefor

DOEpatents

Carl, D.E.

1997-10-21

In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

Hebei Spirit Oil Spill Exposure and Subjective Symptoms in Residents Participating in Clean-Up Activities

PubMed Central

Cheong, Hae-Kwan; Lee, Jong Seong; Kwon, Hojang; Ha, Eun-Hee; Hong, Yun-Chul; Choi, Yeyong; Jeong, Woo-Chul; Hur, Jongil; Lee, Seung-Min; Kim, Eun-Jung; Im, Hosub

2011-01-01

Objectives This study was conducted to examine the relationship between crude oil exposure and physical symptoms among residents participating in clean-up work associated with the Hebei Spirit oil spill, 2007 in Korea. Methods A total of 288 residents responded to a questionnaire regarding subjective physical symptoms, sociodemographic characteristics and clean-up activities that occurred between two and eight weeks after the accident. Additionally, the urine of 154 of the respondents was analyzed for metabolites of volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs) and heavy metals. To compare the urinary levels of exposure biomarkers, the urine of 39 inland residents who were not directly exposed to the oil spill were analyzed. Results Residents exposed to oil remnants through clean-up work showed associations between physical symptoms and the exposure levels defined in various ways, including days of work, degree of skin contamination, and levels of some urinary exposure biomarkers of VOCs, metabolites and metals, although no major abnormalities in urinary exposure biomarkers were observed. Conclusions This study provides evidence of a relationship between crude oil exposure and acute human health effects and suggests the need for follow-up to evaluate the exposure status and long-term health effects of clean-up participants. PMID:22125768

Thief carbon catalyst for oxidation of mercury in effluent stream

DOEpatents

Granite, Evan J [Wexford, PA; Pennline, Henry W [Bethel Park, PA

2011-12-06

A catalyst for the oxidation of heavy metal contaminants, especially mercury (Hg), in an effluent stream is presented. The catalyst facilitates removal of mercury through the oxidation of elemental Hg into mercury (II) moieties. The active component of the catalyst is partially combusted coal, or "Thief" carbon, which can be pre-treated with a halogen. An untreated Thief carbon catalyst can be self-promoting in the presence of an effluent gas streams entrained with a halogen.

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

33 CFR 137.55 - Searches for recorded environmental cleanup liens.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Searches for recorded environmental cleanup liens. 137.55 Section 137.55 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE POLLUTION FINANCIAL RESPONSIBILITY AND COMPENSATION OIL SPILL...

Gas-separation process

DOEpatents

Toy, Lora G.; Pinnau, Ingo; Baker, Richard W.

1994-01-01

A process for separating condensable organic components from gas streams. The process makes use of a membrane made from a polymer material that is glassy and that has an unusually high free volume within the polymer material.

Nitrate loading and CH4 and N2O Flux from headwater streams

NASA Astrophysics Data System (ADS)

Sousa, C. H. R. D.; Hilker, T.; Hall, F. G.; Moura, Y. M.; McAdam, E.

2014-12-01

Freshwater ecosystems transport and process significant amounts of terrestrial carbon and can be considerable sources of CO2, CH4, and N2O. A great deal of uncertainty, however, remains in both global estimates and our understanding of drivers of freshwater greenhouse gas emissions. Furthermore, small headwater streams have received insufficient attention to date and may contribute disproportionately to global GHG flux. Our objective was to quantify GHG flux and assess the impact of changes in DOC and NO3 concentrations in surface and subsurface water on flux rates in three streams in the Lamprey River watershed in New Hampshire, USA, that contrast in surface water DOC:NO3. We measured DOC, NO3 and dissolved gas concentrations in surface waters of each stream monthly from May 2011 to April 2012. Empirical measurements of reaeration coefficients were used to convert dissolved gas concentrations to fluxes. We found higher GHG concentrations and fluxes in the two streams with high DOC concentrations, particularly gases produced by anaerobic metabolism (CH4, N2O from methanogenesis and denitrification, respectively). The stream with high DOC and high NO3 showed high N2O and low CH4 flux, while the high DOC, low NO3 stream showed high CH4 and low N2O flux. Our results are consistent with a model in which C inputs drive total GHG production, while NO3 input regulates the relative importance of CH4 and N2O by suppressing methanogenesis and stimulating denitrification. The magnitude of GHG fluxes suggests that streams in this region are likely to be small sources of CO2, but potentially important sources of CH4 and N2O. Since CH4 and N2O are many times more powerful than CO2 at trapping heat in the atmosphere, freshwater emissions of these gases have the potential to offset a significant proportion of the climate benefits of the terrestrial carbon sink, a possibility that has not been sufficiently incorporated into climate models.

Nitrate loading and CH4 and N2O Flux from headwater streams

NASA Astrophysics Data System (ADS)

Schade, J. D.; Bailio, J.; McDowell, W. H.

2015-12-01

Freshwater ecosystems transport and process significant amounts of terrestrial carbon and can be considerable sources of CO2, CH4, and N2O. A great deal of uncertainty, however, remains in both global estimates and our understanding of drivers of freshwater greenhouse gas emissions. Furthermore, small headwater streams have received insufficient attention to date and may contribute disproportionately to global GHG flux. Our objective was to quantify GHG flux and assess the impact of changes in DOC and NO3 concentrations in surface and subsurface water on flux rates in three streams in the Lamprey River watershed in New Hampshire, USA, that contrast in surface water DOC:NO3. We measured DOC, NO3 and dissolved gas concentrations in surface waters of each stream monthly from May 2011 to April 2012. Empirical measurements of reaeration coefficients were used to convert dissolved gas concentrations to fluxes. We found higher GHG concentrations and fluxes in the two streams with high DOC concentrations, particularly gases produced by anaerobic metabolism (CH4, N2O from methanogenesis and denitrification, respectively). The stream with high DOC and high NO3 showed high N2O and low CH4 flux, while the high DOC, low NO3 stream showed high CH4 and low N2O flux. Our results are consistent with a model in which C inputs drive total GHG production, while NO3 input regulates the relative importance of CH4 and N2O by suppressing methanogenesis and stimulating denitrification. The magnitude of GHG fluxes suggests that streams in this region are likely to be small sources of CO2, but potentially important sources of CH4 and N2O. Since CH4 and N2O are many times more powerful than CO2 at trapping heat in the atmosphere, freshwater emissions of these gases have the potential to offset a significant proportion of the climate benefits of the terrestrial carbon sink, a possibility that has not been sufficiently incorporated into climate models.

Verification of capillary pressure functions and relative permeability equations for gas production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jang, Jaewon

The understanding of multiphase fluid flow in porous media is of great importance in many fields such as enhanced oil recovery, hydrology, CO 2 sequestration, contaminants cleanup and natural gas production from hydrate bearing sediments. However, there are many unanswered questions about the key parameters that characterize gas and water flows in porous media. The characteristics of multiphase fluid flow in porous media such as water retention curve, relative permeability, preferential fluid flow patterns and fluid-particle interaction should be taken into consideration for a fundamental understanding of the behavior of pore scale systems.

Carbon dioxide degassing at the groundwater-stream-atmosphere interface: isotopic equilibration and hydrological mass balance in a sandy watershed

NASA Astrophysics Data System (ADS)

Deirmendjian, Loris; Abril, Gwenaël

2018-03-01

Streams and rivers emit significant amounts of CO2 and constitute a preferential pathway of carbon transport from terrestrial ecosystems to the atmosphere. However, the estimation of CO2 degassing based on the water-air CO2 gradient, gas transfer velocity and stream surface area is subject to large uncertainties. Furthermore, the stable isotope signature of dissolved inorganic carbon (δ13C-DIC) in streams is strongly impacted by gas exchange, which makes it a useful tracer of CO2 degassing under specific conditions. For this study, we characterized the annual transfers of dissolved inorganic carbon (DIC) along the groundwater-stream-river continuum based on DIC concentrations, stable isotope composition and measurements of stream discharges. We selected a homogeneous, forested and sandy lowland watershed as a study site, where the hydrology occurs almost exclusively through drainage of shallow groundwater (no surface runoff). We observed the first general spatial pattern of decreases in pCO2 and DIC and an increase in δ13C-DIC from groundwater to stream orders 1 and 2, which was due to the experimentally verified faster degassing of groundwater 12C-DIC compared to 13C-DIC. This downstream enrichment in 13C-DIC could be modelled by simply considering the isotopic equilibration of groundwater-derived DIC with the atmosphere during CO2 degassing. A second spatial pattern occurred between stream orders 2 and 4, consisting of an increase in the proportion of carbonate alkalinity to the DIC accompanied by the enrichment of 13C in the stream DIC, which was due to the occurrence of carbonate rock weathering downstream. We could separate the contribution of these two processes (gas exchange and carbonate weathering) in the stable isotope budget of the river network. Thereafter, we built a hydrological mass balance based on drainages and the relative contribution of groundwater in streams of increasing order. After combining with the dissolved CO2 concentrations, we

Predicting properties of gas and solid streams by intrinsic kinetics of fast pyrolysis of wood

DOE PAGES

Klinger, Jordan; Bar-Ziv, Ezra; Shonnard, David; ...

2015-12-12

Pyrolysis has the potential to create a biocrude oil from biomass sources that can be used as fuel or as feedstock for subsequent upgrading to hydrocarbon fuels or other chemicals. The product distribution/composition, however, is linked to the biomass source. This work investigates the products formed from pyrolysis of woody biomass with a previously developed chemical kinetics model. Different woody feedstocks reported in prior literature are placed on a common basis (moisture, ash, fixed carbon free) and normalized by initial elemental composition through ultimate analysis. Observed product distributions over the full devolatilization range are explored, reconstructed by the model, andmore » verified with independent experimental data collected with a microwave-assisted pyrolysis system. These trends include production of permanent gas (CO, CO 2), char, and condensable (oil, water) species. Elementary compositions of these streams are also investigated. As a result, close agreement between literature data, model predictions, and independent experimental data indicate that the proposed model/method is able to predict the ideal distribution from fast pyrolysis given reaction temperature, residence time, and feedstock composition.« less

The formation of direct collapse black holes under the influence of streaming velocities

NASA Astrophysics Data System (ADS)

Schauer, Anna T. P.; Regan, John; Glover, Simon C. O.; Klessen, Ralf S.

2017-11-01

We study the influence of a high baryonic streaming velocity on the formation of direct collapse black holes (DCBHs) with the help of cosmological simulations carried out using the moving mesh code arepo. We show that a streaming velocity that is as large as three times the root-mean-squared value is effective at suppressing the formation of H2-cooled minihaloes, while still allowing larger atomic cooling haloes (ACHs) to form. We find that enough H2 forms in the centre of these ACHs to effectively cool the gas, demonstrating that a high streaming velocity by itself cannot produce the conditions required for DCBH formation. However, we argue that high streaming velocity regions do provide an ideal environment for the formation of DCBHs in close pairs of ACHs (the `synchronized halo' model). Due to the absence of star formation in minihaloes, the gas remains chemically pristine until the ACHs form. If two such haloes form with only a small separation in time and space, then the one forming stars earlier can provide enough ultraviolet radiation to suppress H2 cooling in the other, allowing it to collapse to form a DCBH. Baryonic streaming may therefore play a crucial role in the formation of the seeds of the highest redshift quasars.

Risk-Based Decision Making Case Study: Application at a Superfund Cleanup.

ERIC Educational Resources Information Center

Blacker, Stanley; Goodman, Daniel

1994-01-01

Describes a case study comparing an integrated approach to Superfund cleanup with traditional approaches at a particular Superfund site. Emphasizes ways to save time and money while still achieving the desired risk reduction level. (LZ)

Microstructures of superhydrophobic plant leaves - inspiration for efficient oil spill cleanup materials.

PubMed

Zeiger, Claudia; Rodrigues da Silva, Isabelle C; Mail, Matthias; Kavalenka, Maryna N; Barthlott, Wilhelm; Hölscher, Hendrik

2016-08-16

The cleanup of accidental oil spills in water is an enormous challenge; conventional oil sorbents absorb large amounts of water in addition to oil and other cleanup methods can cause secondary pollution. In contrast, fresh leaves of the aquatic ferns Salvinia are superhydrophobic and superoleophilic, and can selectively absorb oil while repelling water. These selective wetting properties are optimal for natural oil absorbent applications and bioinspired oil sorbent materials. In this paper we quantify the oil absorption capacity of four Salvinia species with different surface structures, water lettuce (Pistia stratiotes) and Lotus leaves (Nelumbo nucifera), and compare their absorption capacity to artificial oil sorbents. Interestingly, the oil absorption capacities of Salvinia molesta and Pistia stratiotes leaves are comparable to artificial oil sorbents. Therefore, these pantropical invasive plants, often considered pests, qualify as environmentally friendly materials for oil spill cleanup. Furthermore, we investigated the influence of oil density and viscosity on the oil absorption, and examine how the presence and morphology of trichomes affect the amount of oil absorbed by their surfaces. Specifically, the influence of hair length and shape is analyzed by comparing different hair types ranging from single trichomes of Salvinia cucullata to complex eggbeater-shaped trichomes of Salvinia molesta to establish a basis for improving artificial bioinspired oil absorbents.

Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

DOEpatents

Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

2012-08-21

A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

Mercury sorbent delivery system for flue gas

DOEpatents

Klunder,; Edgar, B [Bethel Park, PA

2009-02-24

The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

Cleanup Verification Package for the 600-47 Waste Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. J. Cutlip

This cleanup verification package documents completion of interim remedial action for the 600-47 waste site. This site consisted of several areas of surface debris and contamination near the banks of the Columbia River across from Johnson Island. Contaminated material identified in field surveys included four areas of soil, wood, nuts, bolts, and other metal debris.

Cleanup Verification Package for the 618-2 Burial Ground

DOE Office of Scientific and Technical Information (OSTI.GOV)

W. S. Thompson

2006-12-28

This cleanup verification package documents completion of remedial action for the 618-2 Burial Ground, also referred to as Solid Waste Burial Ground No. 2; Burial Ground No. 2; 318-2; and Dry Waste Burial Site No. 2. This waste site was used primarily for the disposal of contaminated equipment, materials and laboratory waste from the 300 Area Facilities.

Gas-separation process

DOEpatents

Toy, L.G.; Pinnau, I.; Baker, R.W.

1994-01-25

A process is described for separating condensable organic components from gas streams. The process makes use of a membrane made from a polymer material that is glassy and that has an unusually high free volume within the polymer material. 6 figures.

In-stream hydrokinetic power: Review and appraisal

DOE PAGES

Van Zwieten, J.; McAnally, William; Ahmad, Jameel; ...

2015-09-01

The objective of this paper is to provide a review of in-stream hydrokinetic power, which is defined as electric power generated by devices capturing the energy of naturally flowing water-stream, tidal, or open ocean flows-without impounding the water. North America has significant in-stream energy resources, and hydrokinetic electric power technologies to harness those resources have the potential to make a significant contribution to U.S. electricity needs by adding as much as 120 TWh/year from rivers alone to the present hydroelectric power generation capacity. Additionally, tidal and ocean current resources in the U.S. respectively contain 438 TWh/year and 163 TWh/year ofmore » extractable power. Among their attractive features, in-stream hydrokinetic operations do not contribute to greenhouse gas emissions or other air pollution and have less visual impact than wind turbines. Since these systems do no utilize dams the way traditional hydropower systems typically do, their impact on the environment will differ, and a small but growing number of studies support conclusions regarding those impacts. Furthermore, potential environmental impacts include altered water quality, altered sediment deposition, altered habitats, direct impact on biota, and navigability of waterways.« less

Application of computational methods to analyse and investigate physical and chemical processes of high-temperature mineralizing of condensed substances in gas stream

NASA Astrophysics Data System (ADS)

Markelov, A. Y.; Shiryaevskii, V. L.; Kudrinskiy, A. A.; Anpilov, S. V.; Bobrakov, A. N.

2017-11-01

A computational method of analysis of physical and chemical processes of high-temperature mineralizing of low-level radioactive waste in gas stream in the process of plasma treatment of radioactive waste in shaft furnaces was introduced. It was shown that the thermodynamic simulation method allows fairly adequately describing the changes in the composition of the pyrogas withdrawn from the shaft furnace at different waste treatment regimes. This offers a possibility of developing environmentally and economically viable technologies and small-sized low-cost facilities for plasma treatment of radioactive waste to be applied at currently operating nuclear power plants.

NUCLEAR CLEANUP: Progress Made at Rocky Flats, but Closure by 2006 Is Unlikely, and Costs May Increase

DTIC Science & Technology

2001-02-01

liquids or residues from process pipes and tanks. The contractor also dismantled plutonium - processing furnaces, stripped out contaminated process...Soil Cleanup Levels on the Scope and Cost of the 903 Pad Cleanup 30 Figures Figure 1: Workers in Protective Clothing Handling Plutonium - Contaminated ...activities—shipping nuclear materials such as plutonium - contaminated metals and powders—is expected to be completed in 2002. Another activity

Acetonitrile extraction and dual-layer solid phase extraction clean-up for pesticide residue analysis in propolis.

PubMed

Oellig, Claudia

2016-05-06

Propolis is a very complex mixture of substances that is produced by honey bees and is known to be a rather challenging matrix for residue analysis. Besides resins, flavonoids and phenols, high amount of wax is co-extracted resulting in immense matrix effects. Therefore a suitable clean-up is crucial and indispensable. In this study, a reliable solid phase extraction (SPE) clean-up was developed for pesticide residue analysis in propolis. The clean-up success was quickly and easily monitored by high-performance thin-layer chromatography with different detection possibilities. The final method consists of the extraction of propolis with acetonitrile according to the QuEChERS method followed by an effective extract purification on dual-layer SPE cartridges with spherical hydrophobic polystyrene-divinylbenzene resin/primary secondary amine as sorbent and a mixture of toluene/acetone (95:5, v/v) for elution. Besides fat-soluble components like waxes, flavonoids, and terpenoids, more polar compounds like organic acids, fatty acids, sugars and anthocyanins were also removed to large extent. Method performance was assessed by recovery experiments at spiking levels of 0.5 and 1mg/kg (n=5) for fourteen pesticides that are relevant for propolis. Mean recoveries determined by HPLC-MS against solvent standards were between 40 and 101%, while calculation against matrix-matched standards provided recoveries of 79-104%. Precision of recovery, assessed by relative standard deviations, were below 9%. Thus, the developed dual-layer SPE clean-up enables the reliable pesticide residue analysis in propolis and provides a suitable alternative to time-consuming clean-up procedures proposed in literature. Copyright © 2016 Elsevier B.V. All rights reserved.

Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

DOEpatents

DeGeorge, Charles W.

1981-01-01

In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

Hollow fiber gas-liquid membrane contactors for acid gas capture: a review.

PubMed

Mansourizadeh, A; Ismail, A F

2009-11-15

Membrane contactors using microporous membranes for acid gas removal have been extensively reviewed and discussed. The microporous membrane acts as a fixed interface between the gas and the liquid phase without dispersing one phase into another that offers a flexible modular and energy efficient device. The gas absorption process can offer a high selectivity and a high driving force for transport even at low concentrations. Using hollow fiber gas-liquid membrane contactors is a promising alternative to conventional gas absorption systems for acid gas capture from gas streams. Important aspects of membrane contactor as an efficient energy devise for acid gas removal including liquid absorbents, membrane characteristics, combination of membrane and absorbent, mass transfer, membrane modules, model development, advantages and disadvantages were critically discussed. In addition, current status and future potential in research and development of gas-liquid membrane contactors for acid gas removal were also briefly discussed.