Relating salt marsh pore water geochemistry patterns to vegetation zones and hydrologic influences

NASA Astrophysics Data System (ADS)

Moffett, Kevan B.; Gorelick, Steven M.

2016-03-01

Physical, chemical, and biological factors influence vegetation zonation in salt marshes and other wetlands, but connections among these factors could be better understood. If salt marsh vegetation and marsh pore water geochemistry coorganize, e.g., via continuous plant water uptake and persistently unsaturated sediments controlling vegetation zone-specific pore water geochemistry, this could complement known physical mechanisms of marsh self-organization. A high-resolution survey of pore water geochemistry was conducted among five salt marsh vegetation zones at the same intertidal elevation. Sampling transects were arrayed both parallel and perpendicular to tidal channels. Pore water geochemistry patterns were both horizontally differentiated, corresponding to vegetation zonation, and vertically differentiated, relating to root influences. The geochemical patterns across the site were less broadly related to marsh hydrology than to vegetation zonation. Mechanisms contributing to geochemical differentiation included: root-induced oxidation and nutrient (P) depletion, surface and creek-bank sediment flushing by rainfall or tides, evapotranspiration creating aerated pore space for partial sediment flushing in some areas while persistently saturated conditions hindered pore water renewal in others, and evapoconcentration of pore water solutes overall. The concentrated pore waters draining to the tidal creeks accounted for 41% of ebb tide solutes (median of 14 elements), including being a potentially toxic source of Ni but a slight sink for Zn, at least during the short, winter study period in southern San Francisco Bay. Heterogeneous vegetation effects on pore water geochemistry are not only significant locally within the marsh but may broadly influence marsh-estuary solute exchange and ecology.

POLLUTION PREVENTION OPPORTUNITY ASSESSMENT - GEOCHEMISTRY LABORATORY AT SANDIA NATIONAL LABORATORIES

EPA Science Inventory

These reports summarize pollution prevention opportunity assessments conducted jointly by EPA and DOE at the Geochemistry Laboratory and the Manufacturing and Fabrication Repair Laboratory at the Department of Energy's Sandia National Laboratories facility in Albuquerque, New Mex...

Exploration Geochemistry.

ERIC Educational Resources Information Center

Closs, L. Graham

1983-01-01

Contributions in mineral-deposit model formulation, geochemical exploration in glaciated and arid environments, analytical and sampling problems, and bibliographic research were made in symposia held and proceedings volumes published during 1982. Highlights of these symposia and proceedings and comments on trends in exploration geochemistry are…

Publications - PDF 98-39 | Alaska Division of Geological & Geophysical

Science.gov Websites

content DGGS PDF 98-39 Publication Details Title: Rock geochemistry from the Manley mining district ., Bundtzen, T.K., Newberry, R.J., Dover, J.H., and Blodgett, R.B., 1998, Rock geochemistry from the Manley

Teaching Environmental Geochemistry: An Authentic Inquiry Approach

ERIC Educational Resources Information Center

Koretsky, Carla M.; Petcovic, Heather L.; Rowbotham, Katherine L.

2012-01-01

A field-based environmental geochemistry course was developed at Western Michigan University for undergraduate geosciences and environmental studies students to (1) improve student understanding of complex environmental systems, specifically targeting lake systems; (2) facilitate student development of professional-level, field- and…

Publications - PDF 97-29G | Alaska Division of Geological & Geophysical

Science.gov Websites

content DGGS PDF 97-29G Publication Details Title: Rock geochemistry from the Rampart mining district , K.H., Bundtzen, T.K., Newberry, R.J., Dover, J.H., and Blodgett, R.B., 1997, Rock geochemistry from

Monitoring Subsurface Fluid Flow Using Perfluorocarbon Tracers: Another Tool Potentially Available for Subsurface Fluid Flow Assessments

EPA Pesticide Factsheets

Perfluorocarbon Tracers (PFTs) Complement stable Isotopes and Geochemistry for Verifying, Assessing or Modeling Fluid Flow. Geochemistry, Isotopes and PFT’s complement Geophysics to monitor and verify plume movement, leakage to shallow aquifers or surface

GEOCHEMISTRY OF SULFUR IN IRON CORROSION SCALES FOUND IN DRINKING WATER DISTRIBUTION SYSTEMS

EPA Science Inventory

Iron-sulfur geochemistry is important in many natural and engineered environments, including drinking water systems. In the anaerobic environment beneath scales of corroding iron drinking water distribution system pipes, sulfate reducing bacteria (SRB) produce sulfide from natu...

Climate and geochemistry as drivers of eucalypt diversification in Australia.

PubMed

Bui, E N; Thornhill, A H; González-Orozco, C E; Knerr, N; Miller, J T

2017-05-01

Eucalypts cover most of Australia. Here, we investigate the relative contribution of climate and geochemistry to the distribution and diversity of eucalypts. Using geostatistics, we estimate major element concentrations, pH, and electrical conductivity at sites where eucalypts have been recorded. We compare the median predicted geochemistry and reported substrate for individual species that appear associated with extreme conditions; this provides a partial evaluation of the predictions. We generate a site-by-species matrix by aggregating observations to the centroids of 100-km-wide grid cells, calculate diversity indices, and use numerical ecology methods (ordination, variation partitioning) to investigate the ecology of eucalypts and their response to climatic and geochemical gradients. We find that β-diversity coincides with variations in climatic and geochemical patterns. Climate and geochemistry together account for less than half of the variation in eucalypt species assemblages across Australia but for greater than 80% in areas of high species richness. Climate is more important than geochemistry in explaining eucalypts species distribution and change in assemblages across Australia as a whole but there are correlations between the two sets of environmental variables. Many individual eucalypt species and entire taxonomic sections (Aromatica, Longistylus of subgenus Eucalyptus, Dumaria, and Liberivalvae of subgenus Symphyomyrtus) have distributions affected strongly by geochemistry. We conclude that eucalypt diversity is driven by steep geochemical gradients that have arisen as climate patterns have fluctuated over Australia over the Cenozoic, generally aridifying since the Miocene. The diversification of eucalypts across Australia is thus an excellent example of co-evolution of landscapes and biota in space and time and challenges accepted notions of macroecology. © 2017 John Wiley & Sons Ltd.

10 CFR 960.4-2-2 - Geochemistry.

Code of Federal Regulations, 2010 CFR

2010-01-01

... REPOSITORY Postclosure Guidelines § 960.4-2-2 Geochemistry. (a) Qualifying condition. The present and... future, not affect or would favorably affect the ability of the geologic repository to isolate the waste... subjected to expected repository conditions, would remain unaltered or would alter to mineral assemblages...

Lunar carbon chemistry - Relations to and implications for terrestrial organic geochemistry.

NASA Technical Reports Server (NTRS)

Eglinton, G.; Maxwell, J. R.; Pillinger, C. T.

1972-01-01

Survey of the various ways in which studies of lunar carbon chemistry have beneficially affected terrestrial organic geochemistry. A lunar organic gas-analysis operating system is cited as the most important instrumental development in relation to terrestrial organic geochemistry. Improved methods of analysis and handling of organic samples are cited as another benefit derived from studies of lunar carbon chemistry. The problem of controlling contamination and minimizing organic vapors is considered, as well as the possibility of analyzing terrestrial samples by the techniques developed for lunar samples. A need for new methods of analyzing carbonaceous material which is insoluble in organic solvents is indicated.

U.S. National Committee for Geochemistry

ERIC Educational Resources Information Center

Geotimes, 1974

1974-01-01

Reports highlights of the April, 1973 meeting of the U.S. National Committee for Geochemistry. Some of the topics reported on were: The Geophysics Research Board, deep drilling, exchange of geochemists with China and the activities of the Subcommittee on Geochemical Environment in Relation to Health and Disease. (BR)

Geochemistry in Action: Watch a Dripstone Grow!

ERIC Educational Resources Information Center

Schmidkonz, Bertram

2017-01-01

Learning how cave formations, such as dripstone, take shape can be a valuable pedagogical tool in chemistry and geochemistry. Grasping the underlying processes requires students to synthesize knowledge of several different topical areas. The activity presented here uses an innovative experiment to connect chemistry concepts with an interesting…

MICROFRACTURE SURFACE GEOCHEMISTRY AND ADHERENT MICROBIAL POPULATION METABOLISM IN TCE-CONTAMINATED COMPETENT BEDROCK

EPA Science Inventory

A TCE-contaminated competent bedrock site in Portsmouth, NH was used to determine if a relation existed between microfracture (MF) surface geochemistry and the ecology and metabolic activity of attached microbes relative to terminal electron accepting processes (TEAPs) and TCE bi...

Distinguishing the Source of Natural Gas Accumulations with a Combined Gas and Co-produced Formation Water Geochemical Approach: a Case Study from the Appalachian Basin

EPA Pesticide Factsheets

The purpose of this study is to discuss the use of gas and co-produced formation water geochemistry for identifying the source of natural gas and present gas geochemistry for the northern Appalachian Basin.

Scientific Communication of Geochemical Data and the Use of Computer Databases.

ERIC Educational Resources Information Center

Le Bas, M. J.; Durham, J.

1989-01-01

Describes a scheme in the United Kingdom that coordinates geochemistry publications with a computerized geochemistry database. The database comprises not only data published in the journals but also the remainder of the pertinent data set. The discussion covers the database design; collection, storage and retrieval of data; and plans for future…

Fallon, Nevada FORGE Fluid Geochemistry

DOE Data Explorer

Blankenship, Doug; Ayling, Bridget

2018-03-13

Fluid geochemistry analysis for wells supporting the Fallon FORGE project. Samples were collected from geothermal wells using standard geothermal water sampling techniques, including filtration and acidification of the cation sample to pH < 2 prior to geochemical analysis. Analyses after 2005 were done in reputable commercial laboratories that follow standard protocols for aqueous chemistry analysis.

Fluid-rock geochemical interaction for modelling calibration in geothermal exploration in Indonesia

NASA Astrophysics Data System (ADS)

Deon, Fiorenza; Barnhoorn, Auke; Lievens, Caroline; Ryannugroho, Riskiray; Imaro, Tulus; Bruhn, David; van der Meer, Freek; Hutami, Rizki; Sibarani, Besteba; Sule, Rachmat; Saptadij, Nenny; Hecker, Christoph; Appelt, Oona; Wilke, Franziska

2017-04-01

Indonesia with its large, but partially unexplored geothermal potential is one of the most interesting and suitable places in the world to conduct geothermal exploration research. This study focuses on geothermal exploration based on fluid-rock geochemistry/geomechanics and aims to compile an overview on geochemical data-rock properties from important geothermal fields in Indonesia. The research carried out in the field and in the laboratory is performed in the framework of the GEOCAP cooperation (Geothermal Capacity Building program Indonesia- the Netherlands). The application of petrology and geochemistry accounts to a better understanding of areas where operating power plants exist but also helps in the initial exploration stage of green areas. Because of their relevance and geological setting geothermal fields in Java, Sulawesi and the sedimentary basin of central Sumatra have been chosen as focus areas of this study. Operators, universities and governmental agencies will benefit from this approach as it will be applied also to new green-field terrains. By comparing the characteristic of the fluids, the alteration petrology and the rock geochemistry we also aim to contribute to compile an overview of the geochemistry of the important geothermal fields in Indonesia. At the same time the rock petrology and fluid geochemistry will be used as input data to model the reservoir fluid composition along with T-P parameters with the geochemical workbench PHREEQC. The field and laboratory data are mandatory for both the implementation and validation of the model results.

Thiols in Hydrothermal Solution: Standard Partial Molal Properties and Their Role in the Organic Geochemistry of Hydrothermal Environments

NASA Technical Reports Server (NTRS)

Schulte, Mitchell D.; Rogers, Karyn L.; DeVincenzi, D. (Technical Monitor)

2001-01-01

Modern seafloor hydrothermal systems are locations where great varieties of geochemistry occur due to the enormous disequilibrium between vent fluids and seawater. The disequilibrium geochemistry has been hypothesized to include reactions to synthesize organic compounds. Despite the incomplete understanding of the carbon budget in hydrothermal systems, the organic geochemistry of these sites has received little attention. Experimental simulations of these environments, however, indicate that organic compounds may have difficulty forming in a purely aqueous environment. On the other hand, thiols, thioesters and disulfides have been implicated as reaction intermediates between CO or CO2 in experiments of carbon reduction in hydrothermal environments, as well as in a variety of biological processes and other abiotic reactions. The reduction of CO2 to thesis, for example, is observed using the FeS-H2S/FeS2 couple to provide the reducing power. We have used recent advances in theoretical geochemistry to estimate the standard partial moral thermodynamic properties and parameters for the revised Helgeson-Kirkham-Flowers equation of state for aqueous straight-chain alkyl thesis. With these data and parameters we have evaluated the role that organic sulfur compounds may play as reaction intermediates during organic compound synthesis. We conclude that organic sulfur compounds may hold the key to the organic chemistry leading to the origin of life in hydrothermal settings. These results may also explain the presence of sulfur in a number of biomolecules present in ancient thermophilic microorganisms.

Springwater geochemistry at Honey Creek State Natural Area, central Texas: Implications for surface water and groundwater interaction in a karst aquifer

NASA Astrophysics Data System (ADS)

Musgrove, M.; Stern, L. A.; Banner, J. L.

2010-06-01

SummaryA two and a half year study of two adjacent watersheds at the Honey Creek State Natural Area (HCSNA) in central Texas was undertaken to evaluate spatial and temporal variations in springwater geochemistry, geochemical evolution processes, and potential effects of brush control on karst watershed hydrology. The watersheds are geologically and geomorphologically similar, and each has springs discharging into Honey Creek, a tributary to the Guadalupe River. Springwater geochemistry is considered in a regional context of aquifer components including soil water, cave dripwater, springwater, and phreatic groundwater. Isotopic and trace element variability allows us to identify both vadose and phreatic groundwater contributions to surface water in Honey Creek. Spatial and temporal geochemical data for six springs reveal systematic differences between the two watersheds. Springwater Sr isotope values lie between values for the limestone bedrock and soils at HCSNA, reflecting a balance between these two primary sources of Sr. Sr isotope values for springs within each watershed are consistent with differences between soil compositions. At some of the springs, consistent temporal variability in springwater geochemistry (Sr isotopes, Mg/Ca, and Sr/Ca values) appears to reflect changes in climatic and hydrologic parameters (rainfall/recharge) that affect watershed processes. Springwater geochemistry was unaffected by brush removal at the scale of the HCSNA study. Results of this study build on previous regional studies to provide insight into watershed hydrology and regional hydrologic processes, including connections between surface water, vadose groundwater, and phreatic groundwater.

Isotope Geochemistry for Comparative Planetology of Exoplanets

NASA Technical Reports Server (NTRS)

Mandt, K. E.; Atreya, S.; Luspay-Kuti, A.; Mousis, O.; Simon, A.; Hofstadter, M. D.

2017-01-01

Isotope geochemistry has played a critical role in understanding processes at work in and the history of solar system bodies. Application of these techniques to exoplanets would be revolutionary and would allow comparative planetology with the formation and evolution of exoplanet systems. The roadmap for comparative planetology of the origins and workings of exoplanets involves isotopic geochemistry efforts in three areas: (1) technology development to expand observations of the isotopic composition of solar system bodies and expand observations to isotopic composition of exoplanet atmospheres; (2) theoretical modeling of how isotopes fractionate and the role they play in evolution of exoplanetary systems, atmospheres, surfaces and interiors; and (3) laboratory studies to constrain isotopic fractionation due to processes at work throughout the solar system.

Making Connections to Real Data and Peer-Review Literature: A Short Soil Exercise in a Geochemistry Class

ERIC Educational Resources Information Center

Gutiérrez, Mélida; Baker, Becky

2013-01-01

A class exercise was designed for a college-level geochemistry class to promote inquiry and student participation. In this exercise, real soil data available online was analyzed to evaluate geochemical associations among different soil orders and as a screening tool for anthropogenic metal contamination. Students were asked to read a peer-reviewed…

Geochemistry and geophysics field maps used during the USGS 2011 field season in southwest Alaska

USGS Publications Warehouse

Giles, Stuart A.

2013-01-01

The US Geological Survey (USGS) has been studying a variety of geochemical and geophyscial assessment techniques for concealed mineral deposits. The 2011 field season for this project took place in southwest Alaska, northeast of Bristol Bay between Dillingham and Iliamna Lake. Four maps were created for the geochemistry and geophysics teams to use during field activities.

Stable isotopes in mid-ocean ridge hydrothermal systems: Interactions between fluids, minerals, and organisms

NASA Astrophysics Data System (ADS)

Shanks, W. C., III; Böhlke, J. K.; Seal, R. R., II

Studies of abundance variations of light stable isotopes in nature have had a tremendous impact on all aspects of geochemistry since the development, in 1947, of a gas source isotope ratio mass spectrometer capable of measuring small variations in stable isotope ratios [Nier, 1947] Stable isotope geochemistry is now a mature field, as witnessed by the proliferation of commercially available mass spectrometers installed at virtually every major academic, government, and private-sector research geochemistry laboratory. A recent search of a literature database revealed over 3,000 articles that utilized stable isotope geochemistry over the last 20 years. Nonetheless, many exciting new technical developments are leading to exciting new discoveries and applications. In particular, micro analytical techniques involving new generations of laser- and ion-microprobes are revolutionizing the types of analyses that can be done on spot sizes as small as a few tens of micrometers [Shanks and Criss, 1989]. New generations of conventional gas source and thermal ionization mass spectrometers, with high levels of automation and increased sensitivity and precision, are allowing analyses of large numbers of samples, like those needed for stable isotope stratigraphy in marine sediments, and are enabling the development and application of new isotopic systems.

Stable isotopes in mid-ocean ridge hydrothermal systems: Interactions between fluids, minerals, and organisms

USGS Publications Warehouse

Shanks, Wayne C.; Böhlke, John Karl; Seal, Robert R.; Humphries, S.D.; Zierenberg, Robert A.; Mullineaux, Lauren S.; Thomson, Richard E.

1995-01-01

Studies of abundance variations of light stable isotopes in nature have had a tremendous impact on all aspects of geochemistry since the development, in 1947, of a gas source isotope ratio mass spectrometer capable of measuring small variations in stable isotope ratios (Nice, 1947]. Stable isotope geochemistry is now a mature field, as witnessed by the proliferation of commercially available mass spectrometers installed at virtually every major academic, government, and private-sector research geochemistry laboratory. A recent search of a literature database revealed over 3,000 articles that utilized stable isotope geochemistry over the last 20 years. Nonetheless, many exciting new technical developments are leading to exciting new discoveries and applications. In particular, micro-analytical techniques involving new generations of laser- and ion-microprobes are revolutionizing the types of analyses that can be done on spot sizes as small as a few tens of micrometers [Shanks and Criss, 1989]. New generations of conventional gas source and thermal ionization mass spectrometers, with high levels of automation and increased sensitivity and precision, are allowing analyses of large numbers of samples, like those needed for stable isotope stratigraphy in marine sediments, and are enabling the development and application of new isotopic systems.

Sedimentary basin geochemistry and fluid/rock interactions workshop

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1991-12-31

Fundamental research related to organic geochemistry, fluid-rock interactions, and the processes by which fluids migrate through basins has long been a part of the U.S. Department of Energy Geosciences program. Objectives of this program were to emphasize those principles and processes which would be applicable to a wide range of problems associated with petroleum discovery, occurrence and extraction, waste disposal of all kinds, and environmental management. To gain a better understanding of the progress being made in understanding basinal fluids, their geochemistry and movement, and related research, and to enhance communication and interaction between principal investigators and DOE and othermore » Federal program managers interested in this topic, this workshop was organized by the School of Geology and Geophysics and held in Norman, Oklahoma in November, 1991.« less

Indoor radon measurements in south west England explained by topsoil and stream sediment geochemistry, airborne gamma-ray spectroscopy and geology.

PubMed

Ferreira, Antonio; Daraktchieva, Zornitza; Beamish, David; Kirkwood, Charles; Lister, T Robert; Cave, Mark; Wragg, Joanna; Lee, Kathryn

2018-01-01

Predictive mapping of indoor radon potential often requires the use of additional datasets. A range of geological, geochemical and geophysical data may be considered, either individually or in combination. The present work is an evaluation of how much of the indoor radon variation in south west England can be explained by four different datasets: a) the geology (G), b) the airborne gamma-ray spectroscopy (AGR), c) the geochemistry of topsoil (TSG) and d) the geochemistry of stream sediments (SSG). The study area was chosen since it provides a large (197,464) indoor radon dataset in association with the above information. Geology provides information on the distribution of the materials that may contribute to radon release while the latter three items provide more direct observations on the distributions of the radionuclide elements uranium (U), thorium (Th) and potassium (K). In addition, (c) and (d) provide multi-element assessments of geochemistry which are also included in this study. The effectiveness of datasets for predicting the existing indoor radon data is assessed through the level (the higher the better) of explained variation (% of variance or ANOVA) obtained from the tested models. A multiple linear regression using a compositional data (CODA) approach is carried out to obtain the required measure of determination for each analysis. Results show that, amongst the four tested datasets, the soil geochemistry (TSG, i.e. including all the available 41 elements, 10 major - Al, Ca, Fe, K, Mg, Mn, Na, P, Si, Ti - plus 31 trace) provides the highest explained variation of indoor radon (about 40%); more than double the value provided by U alone (ca. 15%), or the sub composition U, Th, K (ca. 16%) from the same TSG data. The remaining three datasets provide values ranging from about 27% to 32.5%. The enhanced prediction of the AGR model relative to the U, Th, K in soils suggests that the AGR signal captures more than just the U, Th and K content in the soil. The best result is obtained by including the soil geochemistry with geology and AGR (TSG + G + AGR, ca. 47%). However, adding G and AGR to the TSG model only slightly improves the prediction (ca. +7%), suggesting that the geochemistry of soils already contain most of the information given by geology and airborne datasets together, at least with regard to the explanation of indoor radon. From the present analysis performed in the SW of England, it may be concluded that each one of the four datasets is likely to be useful for radon mapping purposes, whether alone or in combination with others. The present work also suggest that the complete soil geochemistry dataset (TSG) is more effective for indoor radon modelling than using just the U (+Th, K) concentration in soil. Copyright © 2016 Natural Environment Research Council. Published by Elsevier Ltd.. All rights reserved.

JPRS Report, Science & Technology, USSR: Science & Technology Policy

DTIC Science & Technology

1989-12-07

technologies. —The restoration of the biosphere and its return to an ecologically clean, healthy state; the preservation and reproduction of soils and the...and Geochemistry of Combustible Materials Institute, Casting Problems Institute, Technical Thermal Physics Institute, Gas Insti- tute, Social and...academician, honorary director of the Institute of Geochemistry imeni A.P. Vinogradov of the Siberian Department of the USSR Academy of Sciences

Merging metagenomics and geochemistry reveals environmental controls on biological diversity and evolution.

PubMed

Alsop, Eric B; Boyd, Eric S; Raymond, Jason

2014-05-28

The metabolic strategies employed by microbes inhabiting natural systems are, in large part, dictated by the physical and geochemical properties of the environment. This study sheds light onto the complex relationship between biology and environmental geochemistry using forty-three metagenomes collected from geochemically diverse and globally distributed natural systems. It is widely hypothesized that many uncommonly measured geochemical parameters affect community dynamics and this study leverages the development and application of multidimensional biogeochemical metrics to study correlations between geochemistry and microbial ecology. Analysis techniques such as a Markov cluster-based measure of the evolutionary distance between whole communities and a principal component analysis (PCA) of the geochemical gradients between environments allows for the determination of correlations between microbial community dynamics and environmental geochemistry and provides insight into which geochemical parameters most strongly influence microbial biodiversity. By progressively building from samples taken along well defined geochemical gradients to samples widely dispersed in geochemical space this study reveals strong links between the extent of taxonomic and functional diversification of resident communities and environmental geochemistry and reveals temperature and pH as the primary factors that have shaped the evolution of these communities. Moreover, the inclusion of extensive geochemical data into analyses reveals new links between geochemical parameters (e.g. oxygen and trace element availability) and the distribution and taxonomic diversification of communities at the functional level. Further, an overall geochemical gradient (from multivariate analyses) between natural systems provides one of the most complete predictions of microbial taxonomic and functional composition. Clustering based on the frequency in which orthologous proteins occur among metagenomes facilitated accurate prediction of the ordering of community functional composition along geochemical gradients, despite a lack of geochemical input. The consistency in the results obtained from the application of Markov clustering and multivariate methods to distinct natural systems underscore their utility in predicting the functional potential of microbial communities within a natural system based on system geochemistry alone, allowing geochemical measurements to be used to predict purely biological metrics such as microbial community composition and metabolism.

Precambrian organic geochemistry - Preservation of the record

NASA Technical Reports Server (NTRS)

Hayes, J. M.; Wedeking, K. W.; Kaplan, I. R.

1983-01-01

A review of earlier studies is presented, and new results in Precambrian organic geochemistry are discussed. It is pointed out that two lines of evidence can be developed. One is based on structural organic chemistry, while the other is based on isotopic analyses. In the present investigation, the results of both structural and isotopic investigations of Precambrian organic matter are discussed. Processes and products related to organic geochemistry are examined, taking into account the carbon cycle, an approximate view of the principal pathways of carbon cycling associated with organic matter in the present global ecosystem, processes affecting sedimentary organic matter, and distribution and types of organic matter. Attention is given to chemical fossils in Precambrian sediments, kerogen analyses, the determination of the structural characteristics of kerogen, and data concerning the preservation of the Precambrian organic geochemical record.

The compact AMS facility at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences

NASA Astrophysics Data System (ADS)

Zhu, Sanyuan; Ding, Ping; Wang, Ning; Shen, Chengde; Jia, Guodong; Zhang, Gan

2015-10-01

A compact 14C AMS facility manufactured by the National Electrostatics Corporation (NEC) has been installed at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences (GIGCAS). The system is based on a Model 1.5SDH-1 Pelletron accelerator with a maximum terminal volt 0.6 MV. This paper reports the performance and the operation of this machine in the first several months after installation.

Active Layer and Water Geochemistry Dynamics throughout the Yukon River Basin

NASA Astrophysics Data System (ADS)

Mutter, E. A.; Toohey, R.; Herman-Mercer, N. M.; Schuster, P. F.

2017-12-01

The hydrology of the Yukon River Basin has changed over the last several decades as evidenced by a variety of discharge, gravimetric, and geochemical analyses. The Indigenous Observation Network (ION), a community-based project, was initiated by the Yukon River Inter-Tribal Watershed Council and USGS. Capitalizing on existing USGS monitoring and research infrastructure and supplementing USGS collected data, ION investigates changes in surface water geochemistry and active layer dynamics throughout the Yukon River Basin. Over 1600 samples of surface water geochemistry (i.e., major ions, dissolved organic carbon, and 18O and 2H) have been collected at 35 sites throughout the Yukon River and its major tributaries over the past 15 years. Active layer dynamics (maximum thaw depth, soil temperature and moisture) have been collected at 20 sites throughout the Yukon River Basin for the past eight years. Important regional differences in geochemistry and active layer parameters linked to permafrost continuity and tributaries will be highlighted. Additionally, annual trends and seasonal dynamics describing the spatial and temporal heterogeneity of the watershed will be presented in the context of observed hydrological changes. These data assist the global effort to characterize arctic river fluxes and their relationship to the carbon cycle, weathering and permafrost degradation.

The Isotope Geochemistry of Abyssal Peridotites and Related Rocks

DTIC Science & Technology

1993-06-01

object of several cruises, including a combined geophysics and petrology cruise (R/V Robert Conrad 27-09: Dick, et al., 1991) and an ocean drilling ...al. (1991) Proceed- ings of the Ocean Drilling Program, Scientific Results Vol. 118. Snow, J., Hart, S.R. and Dick, H.J.B. (1991) "Os isotopic...the geology, petrology , and geochemistry of mantle rocks, as well as their physical and acoustic properties. The first indications that the oceanic

Rethinking early Earth phosphorus geochemistry

PubMed Central

Pasek, Matthew A.

2008-01-01

Phosphorus is a key biologic element, and a prebiotic pathway leading to its incorporation into biomolecules has been difficult to ascertain. Most potentially prebiotic phosphorylation reactions have relied on orthophosphate as the source of phosphorus. It is suggested here that the geochemistry of phosphorus on the early Earth was instead controlled by reduced oxidation state phosphorus compounds such as phosphite (HPO32−), which are more soluble and reactive than orthophosphates. This reduced oxidation state phosphorus originated from extraterrestrial material that fell during the heavy bombardment period or was produced during impacts, and persisted in the mildly reducing atmosphere. This alternate view of early Earth phosphorus geochemistry provides an unexplored route to the formation of pertinent prebiotic phosphorus compounds, suggests a facile reaction pathway to condensed phosphates, and is consistent with the biochemical usage of reduced oxidation state phosphorus compounds in life today. Possible studies are suggested that may detect reduced oxidation state phosphorus compounds in ancient Archean rocks. PMID:18195373

Hydrocarbon Reservoir Identification in Volcanic Zone by using Magnetotelluric and Geochemistry Information

NASA Astrophysics Data System (ADS)

Firda, S. I.; Permadi, A. N.; Supriyanto; Suwardi, B. N.

2018-03-01

The resistivity of Magnetotelluric (MT) data show the resistivity mapping in the volcanic reservoir zone and the geochemistry information for confirm the reservoir and source rock formation. In this research, we used 132 data points divided with two line at exploration area. We used several steps to make the resistivity mapping. There are time series correction, crosspower correction, then inversion of Magnetotelluric (MT) data. Line-2 and line-3 show anomaly geological condition with Gabon fault. The geology structure from the resistivity mapping show the fault and the geological formation with the geological rock data mapping distribution. The geochemistry information show the maturity of source rock formation. According to core sample analysis information, we get the visual porosity for reservoir rock formation in several geological structure. Based on that, we make the geological modelling where the potential reservoir and the source rock around our interest area.

Rethinking early Earth phosphorus geochemistry.

PubMed

Pasek, Matthew A

2008-01-22

Phosphorus is a key biologic element, and a prebiotic pathway leading to its incorporation into biomolecules has been difficult to ascertain. Most potentially prebiotic phosphorylation reactions have relied on orthophosphate as the source of phosphorus. It is suggested here that the geochemistry of phosphorus on the early Earth was instead controlled by reduced oxidation state phosphorus compounds such as phosphite (HPO(3)(2-)), which are more soluble and reactive than orthophosphates. This reduced oxidation state phosphorus originated from extraterrestrial material that fell during the heavy bombardment period or was produced during impacts, and persisted in the mildly reducing atmosphere. This alternate view of early Earth phosphorus geochemistry provides an unexplored route to the formation of pertinent prebiotic phosphorus compounds, suggests a facile reaction pathway to condensed phosphates, and is consistent with the biochemical usage of reduced oxidation state phosphorus compounds in life today. Possible studies are suggested that may detect reduced oxidation state phosphorus compounds in ancient Archean rocks.

Geochemistry, petrology, and palynology of the Pond Creek coal bed, northern Pike and southern Martin counties, Kentucky

USGS Publications Warehouse

Hower, J.C.; Ruppert, L.F.; Eble, C.F.; Clark, W.L.

2005-01-01

The geochemistry, petrology, and palynology of the Duckmantian-age Pond Creek coal bed were investigated in northern Pike and southern Martin counties, eastern Kentucky. The coal bed exhibits significant vertical variation in the investigated geochemical parameters, with many diagenetic overprints of the original geochemistry. Included in the range of geochemical signatures are the presence of elements, particularly TiO2 and Zr, suggesting the detrital influences at the time of deposition of a low-vitrinite durain; a high CaO zone with elevated B/Be, both suggesting marine influence, in a lithotype in the middle of the coal bed; and the postdepositional emplacement of pyrite in the uppermost lithotype. Individual lithotypes, each representing distinct depositional environments, all complicated to some degree by diagentic overprints, comprise the complex history of the coal bed. ?? 2004 Elsevier B.V. All rights reserved.

Factors affecting the geochemistry of a thick, subbituminous coal bed in the Powder River Basin: volcanic, detrital, and peat-forming processes

USGS Publications Warehouse

Crowley, S.S.; Ruppert, L.F.; Belkin, H.E.; Stanton, R.W.; Moore, T.A.

1993-01-01

The inorganic geochemistry and mineralogy of three cores from the Anderson-Dietz 1 coal bed, a 15.2-m-thick subbituminous coal bed in the Tongue River Member (Paleocene) of the Fort Union Formation, were examined (1) to determine if the cores could be correlated by geochemical composition alone over a total distance of 2 km and (2) to identify the major factors that influenced the geochemistry of the coal bed. Chemical data (46 elements on a coal-ash basis) for 81 coal samples and 4 carbonaceous rock samples, with most samples representing a 0.6-m-thick (2-ft) interval of core, were grouped into compositional clusters by means of cluster analysis. Seven major clusters were produced; two of these clusters can be used to correlate the coal bed throughout the study area. Data from scanning electron and optical microscope analyses indicate that several factors influenced the geochemistry of the Anderson-Dietz 1 coal bed. The majority of mineral grains in the coal bed are interpreted to be detrital (water borne); evidence includes the presence of rounded to subrounded quartz grains having two-phase, aqueous fluid inclusions characteristic of hydrothermal or low-to-moderate grade metamorphic quartz. These quartz grains are found throughout the coal bed but are most abundant in samples from the midpart of the bed, which was influenced by detrital input associated with the deposition of the clastic rocks that form the split between the Anderson and Dietz 1 coal beds 900 m to the east of the study area. In addition to the detrital minerals mentioned above, volcanic ash that was fluvially transported to the sites of peat deposition or possibly deposited as air-fall volcanic ash also affected the geochemistry of the coal bed. For example, crandallite(?), a mineral reported to form as an alteration product of volcanic ash, is found in seven samples from the coal bed. The presence of quartz grains containing silicate-melt inclusions in eight samples from the coal bed.provides further support for a volcanic ash component. Other factors that probably affected the geochemistry of the coal bed include (1) detrital input associated with the deposition of the roof rocks of the coal bed, (2) peat-forming processes and plant material, and (3) epigenetic ground-water flow. ?? 1993.

Erratum: Erratum to: "New Data on the Age and Nature of the Khan-Bogd Alkaline Granites, Mongolia"

NASA Astrophysics Data System (ADS)

Gerdes, A.; Kogarko, L. N.; Vladykin, N. V.

2018-01-01

The list of authors and their affiliations should read as follows: A. Gerdes a , Academician L. N. Kogarko b,*, and N. V. Vladykin c a Institute of Earth Sciences, Goethe University, Frankfurt, Germany b Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia c Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, 664033 Russia * e-mail: kogarko@geochi.ru

Field-scale study of the influence of differing remediation strategies on trace metal geochemistry in metal mine tailings from the Irish Midlands.

PubMed

Perkins, William T; Bird, Graham; Jacobs, Suzanne R; Devoy, Cora

2016-03-01

Mine tailings represent a globally significant source of potentially harmful elements (PHEs) to the environment. The management of large volumes of mine tailings represents a major challenge to the mining industry and environmental managers. This field-scale study evaluates the impact of two highly contrasting remediation approaches to the management and stabilisation of mine tailings. The geochemistry of the tailings, overlying amendment layers and vegetation are examined in the light of the different management approaches. Pseudo-total As, Cd and Pb concentrations and solid-state partitioning (speciation), determined via sequential extraction, were established for two Tailings Management Facilities (TMFs) in Ireland subjected to the following: (1) a 'walk-away' approach (Silvermines) and (2) application of an amendment layer (Galmoy). PHE concentrations in roots and herbage of grasses growing on the TMFs were also determined. Results identify very different PHE concentration profiles with depth through the TMFs and the impact of remediation approach on concentrations and their potential bioavailability in the rooting zone of grass species. Data also highlight the importance of choice of grass species in remediation approaches and the benefits of relatively shallow-rooting Agrostis capillaris and Festuca rubra varieties. In addition, data from the Galmoy TMF indicate the importance of regional soil geochemistry for interpreting the influence of the PHE geochemistry of capping and amendment layers applied to mine tailings.

Sulfur Geochemistry of a Lacustrine Record from Taiwan Reveals Enhanced Marine Aerosol Input during the Early Holocene

PubMed Central

Ding, Xiaodong; Li, Dawei; Zheng, Liwei; Bao, Hongyan; Chen, Huei-Fen; Kao, Shuh-Ji

2016-01-01

Lacustrine record of marine aerosol input has rarely been documented. Here, we present the sulfur geochemistry during the last deglaciation and early Holocene of a sediment core retrieved from the Dongyuan Lake in southern Taiwan. An unusually high sulfur peak accompanying pyrite presence is observed at 10.5 ka BP. Such high sulfur content in lacustrine record is unusual. The δ34S of sulfur varied from +9.5 to + 17.1‰ with two significant positive shifts at 10.5 and 9.4 ka BP. The sources of sulfur and potential processes involving the sulfur isotope variation including bacterial sulfate reduction, volcanic emissions, in-catchment sulfide oxidation and marine aerosol input are discussed. Enhanced marine aerosol input is the most likely explanation for such sulfur peaks and δ34S shifts. The positive δ34S shifts appeared concurrently with the maximum landslide events over Taiwan resulted from enhanced typhoon activities. The synchronicity among records suggests that increased typhoon activities promoted sea spray, and consequently enhanced the marine aerosol input with 34S-enriched sulfate. Our sulfur geochemistry data revealed sea spray history and marine influence onto terrestrial environment at coastal regions. Wider coverage of spatial-temporal lacustrine sulfur geochemistry record is needed to validate the applicability of sulfur proxy in paleoenvironmental research. PMID:27941864

Geothermal Geodatabase for Wagon Wheel Hot Springs, Mineral County, Colorado

DOE Data Explorer

Richard Zehner

2012-11-01

This geodatabase was built to cover several geothermal targets developed by Flint Geothermal in 2012 during a search for high-temperature systems that could be exploited for electric power development. Several of the thermal springs at Wagon Wheel Gap have geochemistry and geothermometry values indicative of high-temperature systems. Datasets include: 1. Results of reconnaissance shallow (2 meter) temperature surveys 2. Air photo lineaments 3. Groundwater geochemistry 4. Power lines 5. Georeferenced geologic map of Routt County 6. Various 1:24,000 scale topographic maps

Summary of the research work of the Trace Elements Section, Geochemistry and Petrology Branch, for the period April 1, 1948-December 31, 1950

USGS Publications Warehouse

Rabbitt, John C.

1951-01-01

Much of the material in this report has been paraphrased from reports prepared by members of the Section. My special thanks are due them; to Earl Ingerson, chief of the Geochemistry and Petrology Branch of the Survey, for his critical review; to my secretary, Marie Woolihan, for her aid in collecting material; and to Virginia Layne of the editorial staff of the Section for typing the manuscript and the multilith mats.

A Water Geochemistry Study of Indian Wells Valley, Inyo and Kern Counties, California. Supplement. Isotope Geochemistry and Appendix H.

DTIC Science & Technology

1990-09-01

accuracy by Carl F. Austin, NWC; James Moore, California Energy Co.; and Robert 0. Fournier, Unites States Geological Survey. Approved by Under authority...protons, electrons , and neutrons. The electrical charge of protons is positive, and that of electrons is negative. Neutrons have no electrical charge...The number of protons determines what element an atom is and gives it its atomic number. In a neutral or nonionized atom the number of electrons

Temperature, Geochemistry, and Gravity Data of the Tularosa Basin

DOE Data Explorer

Nash, Greg

2017-06-16

This submission contains multiple excel spreadsheets and associated written reports. The datasets area are representative of shallow temperature, geochemistry, and other well logging observations made across WSMR (white sands missile range); located to the west of the Tularosa Basin but still within the study area. Written reports accompany some of the datasets, and they provide ample description of the methodology and results obtained from these studies. Gravity data is also included, as point data in a shapefile, along with a written report describing that particular study.

Optical Measurements with Related Chemical, Biological, and Physical Parameters from the Central Equatorial Pacific Ocean: NOAA Ship Discoverer Cruise RP-9-DI-84

DTIC Science & Technology

1986-09-01

stations one and two, separate casts were made for Freon sampling and deep geochemistry sampling with either Freon syringes or 30-liter bottles. On...subsequent stations, deep geochemistry and Freon sampling were done on one cast. A separate cast for chlorophyll using 10-liter bottles on the Rosette...vertical to horizontal. The deck sensor used was a Biospherical Instruments, Inc., Solar Reference Hemispherical Irradiance Sensor which monitors the

USGS exploration geochemistry studies at the Pebble porphyry Cu-Au-Mo deposit, Alaska-pdf of presentation

USGS Publications Warehouse

Eppinger, Robert G.; Kelley, Karen D.; Fey, David L.; Giles, Stuart A.; Minsley, Burke J.; Smith, Steven M.

2010-01-01

From 2007 through 2010, scientists in the U.S. Geological Survey (USGS) have been conducting exploration-oriented geochemical and geophysical studies in the region surrounding the giant Pebble porphyry Cu-Au-Mo deposit in southwestern Alaska. The Cretaceous Pebble deposit is concealed under tundra, glacial till, and Tertiary cover rocks, and is undisturbed except for numerous exploration drill holes. These USGS studies are part of a nation-wide research project on evaluating and detecting concealed mineral resources. This report focuses on exploration geochemistry and comprises illustrations and associated notes that were presented as a case study in a workshop on this topic. The workshop, organized by L.G. Closs and R. Glanzman, is called 'Geochemistry in Mineral Exploration and Development,' presented by the Society of Economic Geologists at a technical conference entitled 'The Challenge of Finding New Mineral Resources: Global Metallogeny, Integrative Exploration and New Discoveries,' held at Keystone, Colorado, October 2-5, 2010.

From extreme pH to extreme temperature: An issue in honor of the geochemical contributions of Kirk Nordstrom, USGS hydrogeochemist

USGS Publications Warehouse

Campbell, Kate M.; Verplanck, Philip L.; McCleskey, R. Blaine; Alpers, Charles N.

2015-01-01

This special issue of Applied Geochemistry honors Dr. D. Kirk Nordstrom, and his influential career spent primarily at the U.S. Geological Survey (USGS). This issue does not herald his retirement or other significant career milestone, but serves as a recognition of the impact his work has had on the field of geochemistry in general. This special issue grew from a symposium in Kirk’s honor (affectionately dubbed “Kirkfest”) at the Geological Society of America’s annual meeting in Denver, Colorado, USA, during October 2013. At GSA, 27 talks and 35 posters showed how Kirk’s work has influenced a wide range of current hydrogeochemical research, from geothermal processes to acid mine drainage to geochemical modeling. The breadth of his knowledge and his many contributions to the published literature have left an indelible mark on the field of geochemistry, and this special issue is a tribute to his experience and contributions.

Anthropogenic influence on trace element geochemistry of healing mud (peloid) from Makirina Cove (Croatia)

NASA Astrophysics Data System (ADS)

Miko, S.; Koch, G.; Mesić, S.; Šparica-Miko, M.; Šparica, M.; Čepelak, R.; Bačani, A.; Vreča, P.; Dolenec, T.; Bergant, S.

2008-08-01

Due to their balneotherapeutic features, the organic-rich sediments in Makirina Cove are an important source of healing mud. An environmental geochemistry approach using normalization techniques was applied to evaluate the anthropogenic contribution of trace metals to sediments used as healing mud. Sediment geochemistry was found to be associated with land-use change and storm events, as well as with proximity of a road with heavy traffic in the summer months. Local valley topography preferentially channels lithogenic and pollutant transport to the cove. Concentrations and distribution of trace metals indicate lithogenic (Ni, Cr, Co) and anthropogenic (Pb, Cu, Zn and Se) contributions to the sediments. The calculation of enrichment factors indicates a moderate (EFs between 2-3.5) input of anthropogenic Cu and Pb in surficial sediments to a depth of 10 cm. Patients using the Makirina Cove sediments as healing mud could be to some extent exposed to enhanced uptake of metals from anthropogenic sources via dermal contact.

Introduction to the special issue on ‘Frontiers in gas geochemistry’

USGS Publications Warehouse

Hilton, David R.; Fischer, Tobias P.; Kulongoski, Justin T.

2013-01-01

The study of the geochemistry of gases pervades the Earth and Environmental Sciences. This is due in no small measure to the well-established thermodynamic properties of gases which allow their application to a variety of processes occurring over a wide spectrum of natural conditions. In this respect, both major and associated minor gases have been proven useful: indeed, the trace gases have been particularly important given their role as sensitive geochemical tracers. Examples where gas geochemistry places key constraints on geochemical processes include the degassing history of the solid Earth to form the atmosphere and oceans, the origin and migration characteristics of hydrocarbon deposits, the scale of climate variability, the P–T characteristics of geothermal reservoirs, and the dynamics of the earthquake cycle and volcanic activity, to name but a few. This volume continues this rich tradition with an eclectic selection of papers aimed at exploring and exploiting gas geochemistry over a myriad set of research themes.

Microbial diversity and impact on carbonate geochemistry across a changing geochemical gradient in a karst aquifer

PubMed Central

Gray, Cassie J; Engel, Annette S

2013-01-01

Although microbes are known to influence karst (carbonate) aquifer ecosystem-level processes, comparatively little information is available regarding the diversity of microbial activities that could influence water quality and geological modification. To assess microbial diversity in the context of aquifer geochemistry, we coupled 16S rRNA Sanger sequencing and 454 tag pyrosequencing to in situ microcosm experiments from wells that cross the transition from fresh to saline and sulfidic water in the Edwards Aquifer of central Texas, one of the largest karst aquifers in the United States. The distribution of microbial groups across the transition zone correlated with dissolved oxygen and sulfide concentration, and significant variations in community composition were explained by local carbonate geochemistry, specifically calcium concentration and alkalinity. The waters were supersaturated with respect to prevalent aquifer minerals, calcite and dolomite, but in situ microcosm experiments containing these minerals revealed significant mass loss from dissolution when colonized by microbes. Despite differences in cell density on the experimental surfaces, carbonate loss was greater from freshwater wells than saline, sulfidic wells. However, as cell density increased, which was correlated to and controlled by local geochemistry, dissolution rates decreased. Surface colonization by metabolically active cells promotes dissolution by creating local disequilibria between bulk aquifer fluids and mineral surfaces, but this also controls rates of karst aquifer modification. These results expand our understanding of microbial diversity in karst aquifers and emphasize the importance of evaluating active microbial processes that could affect carbonate weathering in the subsurface. PMID:23151637

Microbial diversity and impact on carbonate geochemistry across a changing geochemical gradient in a karst aquifer.

PubMed

Gray, Cassie J; Engel, Annette S

2013-02-01

Although microbes are known to influence karst (carbonate) aquifer ecosystem-level processes, comparatively little information is available regarding the diversity of microbial activities that could influence water quality and geological modification. To assess microbial diversity in the context of aquifer geochemistry, we coupled 16S rRNA Sanger sequencing and 454 tag pyrosequencing to in situ microcosm experiments from wells that cross the transition from fresh to saline and sulfidic water in the Edwards Aquifer of central Texas, one of the largest karst aquifers in the United States. The distribution of microbial groups across the transition zone correlated with dissolved oxygen and sulfide concentration, and significant variations in community composition were explained by local carbonate geochemistry, specifically calcium concentration and alkalinity. The waters were supersaturated with respect to prevalent aquifer minerals, calcite and dolomite, but in situ microcosm experiments containing these minerals revealed significant mass loss from dissolution when colonized by microbes. Despite differences in cell density on the experimental surfaces, carbonate loss was greater from freshwater wells than saline, sulfidic wells. However, as cell density increased, which was correlated to and controlled by local geochemistry, dissolution rates decreased. Surface colonization by metabolically active cells promotes dissolution by creating local disequilibria between bulk aquifer fluids and mineral surfaces, but this also controls rates of karst aquifer modification. These results expand our understanding of microbial diversity in karst aquifers and emphasize the importance of evaluating active microbial processes that could affect carbonate weathering in the subsurface.

Progress in 1988 1990 with computer applications in the ``hard-rock'' arena: Geochemistry, mineralogy, petrology, and volcanology

NASA Astrophysics Data System (ADS)

Rock, Nicholas M. S.

This review covers rock, mineral and isotope geochemistry, mineralogy, igneous and metamorphic petrology, and volcanology. Crystallography, exploration geochemistry, and mineral exploration are excluded. Fairly extended comments on software availability, and on computerization of the publication process and of specimen collection indexes, may interest a wider audience. A proliferation of both published and commercial software in the past 3 years indicates increasing interest in what traditionally has been a rather reluctant sphere of geoscience computer activity. However, much of this software duplicates the same old functions (Harker and triangular plots, mineral recalculations, etc.). It usually is more efficient nowadays to use someone else's program, or to employ the command language in one of many general-purpose spreadsheet or statistical packages available, than to program a specialist operation from scratch in, say, FORTRAN. Greatest activity has been in mineralogy, where several journals specifically encourage publication of computer-related activities, and IMA and MSA Working Groups on microcomputers have been convened. In petrology and geochemistry, large national databases of rock and mineral analyses continue to multiply, whereas the international database IGBA grows slowly; some form of integration is necessary to make these disparate systems of lasting value to the global "hard-rock" community. Total merging or separate addressing via an intelligent "front-end" are both possibilities. In volcanology, the BBC's videodisk Volcanoes and the Smithsonian Institution's Global Volcanism Project use the most up-to-date computer technology in an exciting and innovative way, to promote public education.

Foraminiferal Stable Isotope Geochemistry At The Micrometer Scale: Is It A Dream Or Reality?

NASA Astrophysics Data System (ADS)

Misra, S.; Shuttleworth, S.; Lloyd, N. S.; Sadekov, A.; Elderfield, H.

2012-12-01

Over last few decades trace metals and stable isotope compositions of foraminiferal shells became one of the major tools to study past oceans and associated climate change. Empirical calibrations of δ11B, δ18O, Mg/Ca, Cd/Ca, Ba/Ca shells compositions have linked them to various environmental parameters such as seawater pH, temperature, salinity and productivity. Despite their common use as proxies, little is known about mechanisms of trace metals incorporation into foraminiferal calcite. Trace metals partition coefficients for foraminiferal calcite is significantly different from inorganic calcite precipitates underlining strong biological control on metal transport to the calcification sites and their incorporation into the calcite. Microscale distribution of light elements isotopes (e.g. Li, B, Mg) could potentially provide unique inside into these biomineralization processes improving our understanding of foraminiferal geochemistry. In this work we explore potentials of using recent advances in analytical geochemistry by employing laser ablation and multi-collector ICP-MS to study microscale distribution of Mg isotopes across individual foraminiferal shells and δ11B, and δ7Li analyses of individual shell chambers. The analytical setup includes an Analyte.G2 193nm excimer laser ablation system with two volume ablation cell connected to a Thermo Scientific NEPTUNE Plus MC-ICP-MS with Jet Interface option. We will discuss method limitations and advantages for foraminiferal geochemistry as well as our data on Mg isotopes distribution within shells of planktonic foraminifera.

Geothermal Geodatabase for Routt Hot Springs, Routt County, Colorado

DOE Data Explorer

Richard Zehner

2012-11-01

This geodatabase was built to cover several geothermal targets developed by Flint Geothermal in 2012 during a search for high-temperature systems that could be exploited for electric power development. Several of the thermal springs and wells in the Routt Hot Spring and Steamboat Springs areahave geochemistry and geothermometry values indicative of high-temperature systems. Datasets include: 1. Results of reconnaissance shallow (2 meter) temperature surveys 2. Air photo lineaments 3. Groundwater geochemistry 5. Georeferenced geologic map of Routt County 6. Various 1:24,000 scale topographic maps

The Apollo 16 Mare Component: Petrography, Geochemistry, and Provenance

NASA Technical Reports Server (NTRS)

Zeigler, R. A.; Haskin, L. A.; Korotev, R. L.; Jolliff, B. L.; Gillis, J. J.

2003-01-01

The A16 (Apollo16) site in the lunar nearside highlands is 220 km from the nearest mare. Thus it is no surprise that mare basalt samples are uncommon at the site. Here, we present the petrography and geochemistry of 5 new mare basalt samples found at the A16 site. We also discuss possible provenances of all A16 mare basalt samples using high-resolution global data for the distribution of Fe and Ti on the lunar surface derived from Clementine UV-VIS data [1-2].

Summary of the research work of the Trace Elements Section, Geochemistry and Petrology Branch, for the period January 1-March 31, 1951

USGS Publications Warehouse

Rabbitt, John C.

1951-01-01

This report summarized the research work of the Trace Elements Section, Geochemistry and Petrology Branch for the period January 1 - March 31, 1951. Work before that is summarized in an earlier report, "Summary of the research work of the Trace Elements Section, Geochemistry and Petrology Branch, for the period April 1, 1948 - December 31, 1950," by John C. Rabbitt (U.S. Geol. Survey Trace Elements Investigations Rept. 148, January 1951). This report will be referred to as TEIR 148. In TEIR 148 the purpose of each project was described and it is not thought necessary to repeat that material. The research work of the section consists of laboratory and related field studies in the following fields: 1. Mineralogic and petrologic investigations of radioactive rocks, minerals, and ores. 2. Investigations of chemical methods of analysis for uranium, thorium, and other elements and compounds in radioactive materials, and related chemical problems. 3. Investigations of spectographic method of analysis for a wide variety of elements in radioactive materials. 4. Investigation of radiometric methods of analysis is applied to radioactive materials. It should be emphasized that the work undertaken so far is almost entirely in the nature of investigations supporting the field appraisal of known uraniferous deposits. A program of more fundamental research, particularly in the mineralogy and geochemistry of uranium, is now being drawn up and will be submitted for approval soon. This report does not deal with the routine analytical work of the Section nor the public-sample program. The analytical work will be summarized in a report to be issued after the end of fiscal year 1951, and a report on the public-sample program is in process. Special thanks are due members of the Section who are engaged in the research work and who have supplied material for this report, the Early Ingerson, Chief of the Geochemistry and Petrology Branch for his critical review, to Jane Titcomb of the editorial staff of the Section for editing the report, and to Virginia Layne of the same staff, for typing the manuscript and the multilith mats.

Interaction of Land Management Intensity and Micro-topography Controls on Geochemistry of Raindrop-Liberated/Mobilized Soil Particles

NASA Astrophysics Data System (ADS)

Hou, T.; Filley, T. R.; Berry, T.; Singh, S.; Hughes, M.; Tong, Y.; Papanicolaou, T.; Wacha, K.; Wilson, C. G.; Chaubey, I.

2017-12-01

The dynamics of raindrop-induced breakdown of soil aggregates, a critical factor in the initial process of surface erosion and lateral redistribution of soil, are strongly tied to land use intensity. What is unclear however is the relative control of rain and mechanical disturbance on the development of landscape-level heterogeneity in surface soil geochemistry. We used artificial rainfall simulated experiments including an aggregate stability test and time course rainfall-erosional test to evaluate the role of management intensity and micro-topography on the geochemistry of raindrop-liberated/mobilized particles from landscapes in southeastern Iowa. Comparing restored prairie, conservation tillage, and conventional tillage sites we found, and with a trend toward increasing tillage intensity, a decrease in aggregate stability and raindrop-liberated particles that were lower in organic carbon, nitrogen, and plant-derived biopolymers, while containing higher proportions of microbially-processed nitrogen than the raindrop stable aggregates. Time evolution of the geochemistry (e.g. elemental, stable isotope, and biopolymer composition) of transported soil particles exhibited distinct patterns based upon both position of the hillslope and oriented soil roughness. Additionally, in the restored prairie, raindrop liberated particles had identical geochemical composition to the raindrop stable aggregates. Our results demonstrate that agricultural sites under intensive tillage have not only a greater potential to liberate and mobilize soil particles during storms, but the mobilized particles will have a distinct chemical character based on tillage intensity, hillslope position and oriented roughness thus lead to a greater potential for landscape level heterogeneity in surface and buried soil chemistry upon mobilization and burial.

Compositional trends in aeolian dust along a transect across the southwestern United States

USGS Publications Warehouse

Goldstein, H.L.; Reynolds, R.L.; Reheis, M.C.; Yount, J.C.; Neff, J.C.

2008-01-01

Aeolian dust strongly influences ecology and landscape geochemistry over large areas that span several desert ecosystems of the southwestern United States. This study evaluates spatial and temporal variations and trends of the physical and chemical properties of dust in the southwestern United States by examining dust deposited in natural depressions on high isolated surfaces along a transect from the Mojave Desert to the central Colorado Plateau. Aeolian dust is recognized in these depressions on the basis of textural, chemical, isotopic, and mineralogical characteristics and comparisons of those characteristics to the underlying bedrock units. Spatial and temporal trends suggest that although local dust sources are important to the accumulated material in these depressions, Mojave Desert dust sources may also contribute. Depth trends in the depressions suggest that Mojave sources may have contributed more dust to the Colorado Plateau recently than in the past. These interpretations point to the important roles of far-traveled aeolian dust for landscape geochemistry and imply future changes to soil geochemistry under changing conditions in far-distant dust source areas. Copyright 2008 by the American Geophysical Union.

Impacts of retrogressive thaw slumps on the geochemistry of permafrost catchments, Stony Creek Watershed, NWT

NASA Astrophysics Data System (ADS)

Malone, Laura

Retrogressive thaw slumps are one of the most dramatic thermokarst landforms in periglacial regions. This thesis investigates the impacts of two of the largest hillslope thaw slumps on the geochemistry of periglacial streams on the Peel Plateau, Northwest Territories. It aims to describe the inorganic geochemistry of runoff across active mega-slumps, impacted and pristine tundra streams, as well as that of the ice-rich permafrost exposed in the slump headwalls. Slump runoff is characterized by elevated suspended sediments (911 g/L), high conductivity (2700 microS/cm), and high SO42- (up to 2078 ppm). The runoff originates as a solute-rich meltwater near the slump headwall, and leaches and re-dissolves soluble salts (e.g., gypsum) as it flows along the mudflow. Conductivity increases until the runoff mixes with pristine tundra streams, diluting the slump runoff signal. SO4 2-/Cl- is used as a tracer to isolate the slump runoff signal in impacted waters, and suggests that the contribution of slump runoff to the Peel River has been increasing since the 1960s.

A Conversation with Karl K. Turekian

NASA Astrophysics Data System (ADS)

Turekian, Karl K.; Cochran, J. Kirk

2012-01-01

Editors' Note Each year, the editorial board invites a distinguished member of the oceanographic community to contribute a prefatory chapter; this year, we were delighted when Karl Turekian, Sterling Professor of Geology and Geophysics at Yale, accepted our invitation. Over the course of a long and productive career, Dr. Turekian has pursued his interests in marine and atmospheric geochemistry by using natural radioactive and radiogenic isotopes to study Earth's evolution and the impacts of global change. He has also directed both the Center for the Study of Global Change at Yale and the Yale Institute for Biospheric Studies. In this interview, conducted by his former student Kirk Cochran, Dr. Turekian tells the story of his early career and discusses some of the major scientific challenges and opportunities faced along the way. His personal account of the rise of geochemistry is a charming story of how chance events and personalities impact scientific careers. His technical insight into the future of this field is illuminating, particularly for scientific outsiders who appreciate the central role of geochemistry in discerning and understanding patterns of global change. Craig A. Carlson and Stephen J. Giovannoni, Editors [Figure: see text

Sedimentary Geochemistry of Martian Samples from the Pathfinder Mission

NASA Technical Reports Server (NTRS)

McLennan, Scott M.

2001-01-01

The purpose of this research project was to evaluate the APXS data collected on soils and rocks at the Pathfinder site in terms of sedimentary geochemistry. Below are described the major findings of this research: (1) An influential model to explain the chemical variation among Pathfinder soils and rocks is a two component mixing model where rocks of fairly uniform composition mix with soil of uniform composition; (2) The very strong positive correlation between MgO and SO, points to a control by a MgSO4 mineral however, spectroscopic data continue to suggest that Fe-sulfates, notably schwertmannite and jarosite, may be important components; (3) In an attempt to better understand the causes of complexities in mixing relationships, the possible influence of sedimentary transport has been evaluated; (4) Another aspect of this research has been to examine the possibility of sedimentary silica being a significant phase on Mars; and (5) On Earth, the geochemistry of sedimentary rocks has been used to constrain the chemical composition of the continental crust and an important part of this research was to evaluate this approach for Mars.

Geochemistry of Israeli oil shales: a review

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shirav, M.; Ginzburg, D.

1983-01-01

The oil shales of Israel are widely distributed throughout the country and have current reserves of about 3500 million tons located in the following deposits: Zin, Oron, Ef'e, Hartuv, and Nabi-Musa. The geochemistry and chemical analysis of these shales are discussed, along with the calorific value, oil yield, and trace elements. The main components influencing the quality of the oil shales are organic matter, carbonate, clay minerals, and apatite. Compositional variations within the organic matter are responsible for changes in the relative calorific value and retorted oil yield while fluidized bed combustion is affected by the inorganic components. (JMT)

Geochemical and Morphologic Evolution of Soil-Covered Hillslopes in the Feather River Basin, California: Responses to Channel Incision

NASA Astrophysics Data System (ADS)

Weinman, B.; Yoo, K.; Mudd, S. M.; Hurst, M. D.; Mayer, K.; Maher, K.

2009-12-01

Tectonically driven changes in channel incision rates lead to changes in hillslope erosion rates that propagate upslope. In an effort to understand how these changes affect soil geochemistry, this study theoretically and empirically integrates sediment transport and chemical weathering. Here, we focus on a tributary basin of the Middle Folk Feather River (FR) in Sierra Nevada, California. This basin is adjusting to an increase in main stem channel incision that has resulted in rapidly eroding, steep hillslopes near the main stem channel and gentler, more slowly eroding slopes further upstream. To constrain how geomorphic signals (i.e., knickpoint) propagate upslope and affect soil geochemistry, soils were sampled in July 2009 along three hillslope transects within the FR basin: transect POMD (40% slope at 780m elevation), FTA (70% slope at 680m elevation), and BRC (90% slope at 630m elevation). To capture and bracket a coupled change in soil geochemistry upslope, transects were specifically chosen so that POMD is downstream of the knickpoint of the main channel, FTA in a transitional region, and BRC upstream of the knickpoint. Along each ~50 m transect, soil pits were dug <10 m apart of each other to depths of about 1m. CRN samples were collected from the upper saprolite and undisturbed B horizons to determine the soil production rates. For constraining soil mixing, sediment ages, and chemical weathering, OSL and geochemistry samples were collected every ~10 cm in the A, B, and saprolite horizons. Judging from the soil color, the abundances of pedogenic iron oxides systematically are greater in the less steep hillslopes. This is consistent with a preliminary view that the soils have briefer residence times in the steeper hillslopes, which have greater rates of channel incision at their lower boundaries. One contrast to our expectations, however, was that the soils were not consistently thicker in the gentler hillslopes, which presumably undergo reduced rates of soil erosion. Additionally, within each hillslope, soil thicknesses were largely constant, ~50-70 cm thick. Therefore, tree throw, which appears to be dominant soil production mechanism at the site, may be capable of buffering soil thickness against the variation of soil erosion rate. While we are still in the preliminary stages of the OSL and CRN work, transect profiles of major oxide elements Si, Al, Fe, Ca, Mg, Na, K, P, and Mn versus potentially immobile elements such as Zr and Ti in the soils are used to infer how channel incision affects soil geochemistry in the three hillslopes. In the future, these results will be coupled with LiDAR, OSL, CRN, and pore-water chemistry work for a more holistic view of how the morphology and geochemistry of hillslopes evolve together in their responses to tectonic forcing.

Teaching Environmental Geochemistry as a Service-Learning Course (Invited)

NASA Astrophysics Data System (ADS)

Ku, T. C.

2010-12-01

Service-learning courses seek to broaden students’ understanding of class content through activities, which are, at the same time, of service to the community. At Wesleyan University, I have taught an Environmental Geochemistry and Laboratory course three times as a service-learning course. The course meets for two 80-minute lecture periods and one 3-hour lab period each week and class sizes have been 19-27 students. The lectures cover traditional geochemistry topics such as equilibrium thermodynamics, acid-base equilibria, oxidation-reduction reactions, and isotope geochemistry, while the lab periods focus on a semester-long environmental project in collaboration with a community organization. Problem sets and class exercises are chosen to demonstrate how theoretical concepts are applied to topics relevant to the service-learning project. The three service-learning projects and associated community partners were entitled 1) “An Initial Assessment of the North End Middletown Landfill as a Renewable Energy Sources” in collaboration with The Johan Center for Earth and Art, 2) “The Water and Sediment Geochemistry of Beseck Lake, CT: Implications for Cultural Eutrophication” in collaboration with the Beseck Lake Association, and 3) “Geochemistry and Hydrology of Jobs Pond, CT” with the Jobs Pond Water Quality Commission. Initial contact with the community partner was made through Wesleyan’s Center for Community Partnerships or through the Connecticut Department of Environmental Protection. At the start of each semester, the lead member(s) of the community organization present their environmental problem to the class. This initial meeting allows the students to hear about the problem from the community’s perspective. The faculty member collaborates with the community organization to design 5-8 mini-projects and the students are assigned group projects (2-5 students) through a ranking system. Throughout the semester each group works on their project, but several lab periods involve the entire class when the activity is beneficial to multiple groups or for educational purposes. For example, during lake projects, all students learn how to collect water column samples and piston and freeze sediment cores. The course culminates with a written report for each group and student oral presentations to the public usually held at an off-campus site and covered by the local media. The public presentations can be very successful and especially rewarding for the students, the faculty member, and the community organization. This type of service-learning class requires more faculty preparation time, additional funds or supplies, and a cooperative community organization. The result though, is that approximately one-third of the student evaluations specifically mentioned that the service-learning project was one of the most enjoyable or educational experiences of the course.

Relation between organic-wastewater compounds, groundwater geochemistry, and well characteristics for selected wells in Lansing, Michigan

USGS Publications Warehouse

Haack, Sheridan K.; Luukkonen, Carol L.

2013-01-01

In 2010, groundwater from 20 Lansing Board of Water and Light (BWL) production wells was tested for 69 organic-wastewater compounds (OWCs). The OWCs detected in one-half of the sampled wells are widely used in industrial and environmental applications and commonly occur in many wastes and stormwater. To identify factors that contribute to the occurrence of these constituents in BWL wells, the U.S. Geological Survey (USGS) interpreted the results of these analyses and related detections of OWCs to local characteristics and groundwater geochemistry. Analysis of groundwater-chemistry data collected by the BWL during routine monitoring from 1969 to 2011 indicates that the geochemistry of the BWL wells has changed over time, with the major difference being an increase in sodium and chloride. The concentrations of sodium and chloride were positively correlated to frequency of OWC detections. The BWL wells studied are all completed in the Saginaw aquifer, which consists of water-bearing sandstones of Pennsylvanian age. The Saginaw aquifer is underlain by the Parma-Bayport aquifer, and overlain by the Glacial aquifer. Two possible sources of sodium and chloride were evaluated: basin brines by way of the Parma-Bayport aquifer, and surficial sources by way of the Glacial aquifer. To determine if water from the underlying aquifer had influenced well-water geochemistry over time, the total dissolved solids concentration and changes in major ion concentrations were examined with respect to well depth, age, and pumping rate. To address a possible surficial source of sodium and chloride, 25 well, aquifer, or hydrologic characteristics, and 2 groundwater geochemistry variables that might influence whether, or the rate at which, water from the land surface could reach each well were compared to OWC detections and well chemistry. The statistical tests performed during this study, using available variables, indicated that reduced time of travel of water from the land surface to the well opening was significantly correlated with detections of OWCs. No specific well or aquifer characteristic was correlated with OWC detections; however, wells with detections tended to have less modeled confining material thickness (as simulated in the regional groundwater flow model), which is an estimate of the amount of clay or shale between the Glacial and Saginaw aquifers. Additional analyses and collection of other data would be required to more conclusively identify the source and to determine the potential vulnerability of other wells because each BWL well may have a somewhat unique set of characteristics that governs its response to pumping. Therefore, it is possible that a relevant explanatory variable was not included in this analysis. The current patterns of geochemistry, and the relation between these patterns and volume of pumpage for the BWL wells, indicates other wells may be susceptible to OWCs in the future.

Spatial variability of organic matter molecular composition and elemental geochemistry in surface sediments of a small boreal Swedish lake

NASA Astrophysics Data System (ADS)

Tolu, Julie; Rydberg, Johan; Meyer-Jacob, Carsten; Gerber, Lorenz; Bindler, Richard

2017-04-01

The composition of sediment organic matter (OM) exerts a strong control on biogeochemical processes in lakes, such as those involved in the fate of carbon, nutrients and trace metals. While between-lake spatial variability of OM quality is increasingly investigated, we explored in this study how the molecular composition of sediment OM varies spatially within a single lake and related this variability to physical parameters and elemental geochemistry. Surface sediment samples (0-10 cm) from 42 locations in Härsvatten - a small boreal forest lake with a complex basin morphometry - were analyzed for OM molecular composition using pyrolysis gas chromatography mass spectrometry for the contents of 23 major and trace elements and biogenic silica. We identified 162 organic compounds belonging to different biochemical classes of OM (e.g., carbohydrates, lignin and lipids). Close relationships were found between the spatial patterns of sediment OM molecular composition and elemental geochemistry. Differences in the source types of OM (i.e., terrestrial, aquatic plant and algal) were linked to the individual basin morphometries and chemical status of the lake. The variability in OM molecular composition was further driven by the degradation status of these different source pools, which appeared to be related to sedimentary physicochemical parameters (e.g., redox conditions) and to the molecular structure of the organic compounds. Given the high spatial variation in OM molecular composition within Härsvatten and its close relationship with elemental geochemistry, the potential for large spatial variability across lakes should be considered when studying biogeochemical processes involved in the cycling of carbon, nutrients and trace elements or when assessing lake budgets.

Spatial heterogeneity of high-resolution Chalk groundwater geochemistry - Underground quarry at Saint Martin-le-Noeud, France

NASA Astrophysics Data System (ADS)

Barhoum, S.; Valdès, D.; Guérin, R.; Marlin, C.; Vitale, Q.; Benmamar, J.; Gombert, P.

2014-11-01

Chalk groundwater is an important aquifer resource in France because it accounts for a production of 12 million m3 y-1 with a large proportion reserved for drinking water. Processes occurring in the unsaturated zone (UZ) and the overlying superficial formations have a high impact on Chalk groundwater geochemistry and require better understanding. The study site is a former underground Chalk quarry located near Beauvais (France) that extends over 1200 m in length, at a depth ranging from 20 to 30 m. The water table intersects the cavity creating 15 underground ;lake; that give access to the Chalk groundwater. Lakes geochemistry has been studied: water samples were collected in July 2013 and major ion concentrations were analyzed. UZ and clay-with-flints thickness above each lake were estimated qualitatively using an electromagnetic sensor (EM31) and Underground GPS. The results unexpectedly showed that groundwater quality varied widely in spatial terms for both allochthonous and autochthonous ions (e.g., HCO3- ranged from 2.03 to 4.43 meq L-1, NO3- ranged from 0.21 to 1.33 meq L-1). Principal component analysis indicated the impact of agricultural land use on water quality, with the intake of NO3- as well as SO42-, Cl- and Ca2+. Chalk groundwater geochemistry is compared with the nature and structure of the UZ. We highlight correlations (1) between thick clay-with-flints layers and the ions Mg2+ and K+, and (2) between UZ thickness and Na+. In conclusion, this paper identifies various ion sources (agriculture, clay-with-flints and Chalk) and demonstrates different processes in the UZ: dissolution, ionic exchange and solute storage.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ames, L.L.; Rai, D.; Serne, R.J.

The annotated bibliography is divided into sections on chemistry and geochemistry, migration and accumulation, cultural distributions, natural distributions, and bibliographies and annual reviews. (LK)

Application of fuzzy set and Dempster-Shafer theory to organic geochemistry interpretation

NASA Technical Reports Server (NTRS)

Kim, C. S.; Isaksen, G. H.

1993-01-01

An application of fuzzy sets and Dempster Shafter Theory (DST) in modeling the interpretational process of organic geochemistry data for predicting the level of maturities of oil and source rock samples is presented. This was accomplished by (1) representing linguistic imprecision and imprecision associated with experience by a fuzzy set theory, (2) capturing the probabilistic nature of imperfect evidences by a DST, and (3) combining multiple evidences by utilizing John Yen's generalized Dempster-Shafter Theory (GDST), which allows DST to deal with fuzzy information. The current prototype provides collective beliefs on the predicted levels of maturity by combining multiple evidences through GDST's rule of combination.

Evidence against a chondritic Earth.

PubMed

Campbell, Ian H; O'Neill, Hugh St C

2012-03-28

The (142)Nd/(144)Nd ratio of the Earth is greater than the solar ratio as inferred from chondritic meteorites, which challenges a fundamental assumption of modern geochemistry--that the composition of the silicate Earth is 'chondritic', meaning that it has refractory element ratios identical to those found in chondrites. The popular explanation for this and other paradoxes of mantle geochemistry, a hidden layer deep in the mantle enriched in incompatible elements, is inconsistent with the heat flux carried by mantle plumes. Either the matter from which the Earth formed was not chondritic, or the Earth has lost matter by collisional erosion in the later stages of planet formation.

A critical review of inductively coupled plasma-mass spectrometry for geoanalysis, geochemistry and hydrology, Part 1. Analytical performance

USGS Publications Warehouse

Brenner, I.B.; Taylor, Howard E.

1992-01-01

Present-day inductively coupled plasma-mass spectrometry (ICP-MS) instrumentation is described briefly. Emphasis is placed on performance characteristics for geoanalysis, geochemistry, and hydrology. Applications where ICP-MS would be indispensable are indicated. Determination of geochemically diagnostic trace elements (such as the rare earth elements [REE], U and Th), of isotope ratios for fingerprinting, tracer and other geo-isotope applications, and benchmark isotope dilution determinations are considered to be typical priority applications for ICP-MS. It is concluded that ICP-MS furnishes unique geoanalytical and environmental data that are not readily provided by conventional spectroscopic (emission and absorption) techniques.

Future directions in geobiology and low-temperature geochemistry

USGS Publications Warehouse

Freeman, Katherine H.; Goldhaber, M.B.

2011-01-01

Humanity is confronted with an enormous challenge, as succinctly stated by the late Steven Schneider (2001; quoted by Jantzen 2004*): “Humans are forcing the Earth’s environmental systems to change at a rate that is more advanced than their knowledge of the consequences.” Geobiologists and low-temperature geochemists characterize material from the lithosphere, hydrosphere, atmosphere, and biosphere to understand processes operating within and between these components of the Earth system from the atomic to the planetary scale. For this reason, the interwoven disciplines of geobiology and low-temperature geochemistry are central to understanding and ultimately predicting the behavior of these life-sustaining systems. We present here comments and recommendations from the participants of a workshop entitled “Future Directions in Geobiology and Low-Temperature Geochemistry,” hosted by the Carnegie Institution of Washington, Geophysical Laboratory, Washington, DC, on 27–28 August 2010. The goal of the workshop was to suggest ways to leverage the vast intellectual and analytical capabilities of our diverse scientific community to characterize the Earth’s past, present, and future geochemical habitat as we enter the second decade of what E. O. Wilson dubbed “the century of the environment.”

Geochemistry of bed and suspended sediment in the Mississippi river system: provenance versus weathering and winnowing.

PubMed

Piper, D Z; Ludington, Steve; Duval, J S; Taylor, H E

2006-06-01

Stream-bed sediment for the size fraction less than 150 microm, examined in 14,000 samples collected mostly from minor tributaries to the major rivers throughout the Mississippi River drainage system, is composed of 5 mineral fractions identified by factor analysis-Al-silicate minerals, quartz, calcite and dolomite, heavy minerals, and an Fe-Mn fraction. The Al-silicate fraction parallels its distribution in the regolith, emphasizing the local sediment source as a primary control to its distribution. Quartz and the heavy-mineral fraction, and associated trace elements, exhibit a complementary distribution to that of the Al-silicate fraction, with a level of enrichment in the bed sediment that is achieved through winnowing and sorting. The carbonate fraction has a distribution suggesting its dissolution during transport. Trace elements partitioned onto the Fe-Mn, possibly amorphous oxyhydride, fraction are introduced to the streams, in part, through human activity. Except for the heavy-mineral fraction, these fractions are identified in suspended sediment from the Mississippi River itself. Although comparison of the tributary bed sediment with the riverine suspended sediment is problematic, the geochemistry of the suspended sediment seems to corroborate the interpretation of the geochemistry of the bed sediment.

Geochemistry of bed and suspended sediment in the Mississippi river system: Provenance versus weathering and winnowing

USGS Publications Warehouse

Piper, D.Z.; Ludington, S.; Duval, J.S.; Taylor, Howard E.

2006-01-01

Stream-bed sediment for the size fraction less than 150 ??m, examined in 14,000 samples collected mostly from minor tributaries to the major rivers throughout the Mississippi River drainage system, is composed of 5 mineral fractions identified by factor analysis-Al-silicate minerals, quartz, calcite and dolomite, heavy minerals, and an Fe-Mn fraction. The Al-silicate fraction parallels its distribution in the regolith, emphasizing the local sediment source as a primary control to its distribution. Quartz and the heavy-mineral fraction, and associated trace elements, exhibit a complementary distribution to that of the Al-silicate fraction, with a level of enrichment in the bed sediment that is achieved through winnowing and sorting. The carbonate fraction has a distribution suggesting its dissolution during transport. Trace elements partitioned onto the Fe-Mn, possibly amorphous oxyhydride, fraction are introduced to the streams, in part, through human activity. Except for the heavy-mineral fraction, these fractions are identified in suspended sediment from the Mississippi River itself. Although comparison of the tributary bed sediment with the riverine suspended sediment is problematic, the geochemistry of the suspended sediment seems to corroborate the interpretation of the geochemistry of the bed sediment.

Groundwater geochemistry in shallow aquifers above longwall mines in Illinois, USA

NASA Astrophysics Data System (ADS)

Booth, C. J.; Bertsch, L. P.

1999-12-01

Aquifers above high-extraction underground coal mines are not affected by mine drainage, but they may still exhibit changes in groundwater chemistry due to alterations in groundwater flow induced by mine subsidence. At two active longwall mine sites in Illinois, USA, glacial-drift aquifers were largely unaffected by mining, but the geochemistry of the bedrock aquifers changed during the post-mining water-level recovery. At the Jefferson site, brackish, high-sulfate water present in the upper bedrock shale briefly had lower values of total dissolved solids (TDS) after mining due to increased recharge from the overlying drift, whereas TDS and sulfate increased in the sodium-bicarbonate water present in the underlying sandstone due to downward leakage from the shale and lateral inflow of water through the sandstone. At the Saline site, sandstones contained water ranging from brackish sodium-chloride to fresh sodium-bicarbonate type. Post-mining recovery of the potentiometric levels was minimal, and the water had minor quality changes. Longwall mining affects geochemistry due to subsidence-related fracturing, which increases downward leakage from overlying units, and due to the temporary potentiometric depression and subsequent recovery, whereby water from surrounding areas of the aquifer recharges the affected zone above and adjacent to the mine.

Thermal, dynamic and compositional aspects of the core-forming Earth

NASA Technical Reports Server (NTRS)

Stevenson, D. J.

1985-01-01

Core formation is the most important and singular differentiation event in the history of a terrestrial planet. It almost certainly involved the downward migration of a partially or wholly molten iron alloy through a silicate and oxide mantle, and was contemporaneous with accretion. Several important, unresolved issues which have implications for mantle and core geochemistry, the thermal history of the Earth, and the origin of geomagnetism are addressed: whether the early Earth was molten; whether core formation involved low or high pressure geochemistry, or both; early Earth mantle homogenization; whether equilibration established between core forming material and the mantle through which it migrated; and how much iron is stranded and unable to reach the core.

Euromet Ureilite Consortium: A preliminary report on carbon and nitrogen geochemistry

NASA Technical Reports Server (NTRS)

Grady, Monica M.; Pillinger, C. T.

1993-01-01

The first Euromet expedition to the Frontier Mountain in Antarctica in December 1990 recovered two ureilites, FRO 90036 (34.6g) and FRO 90054 (17.5g). Preliminary classification indicated that the specimens had very different textures and mineral chemistries, and hence were not paired. A third ureilite, Acfer 277 (41.0 g), has also recently been returned from the Sahara. Due to the small sample sizes of the meteorites, and the unusual mineralogy of FRO 90054, a consortium was established to ensure the most effective study of these samples; this abstract reports on the carbon and nitrogen stable isotope geochemistry of two of the three ureilites issued to the consortium.

Geochemical appraisal of fluoride-laden groundwater in Suri I and II blocks, Birbhum district, West Bengal

NASA Astrophysics Data System (ADS)

Das, Shreya; Nag, S. K.

2017-09-01

The present study has been carried out covering two blocks—Suri I and II in Birbhum district, West Bengal, India. The evaluation focuses on occurrence, distribution and geochemistry in 26 water samples collected from borewells spread across the entire study area homogeneously. Quantitative chemical analysis of groundwater samples collected from the present study area has shown that samples from two locations—Gangta and Dhalla contain fluoride greater than the permissible limit prescribed by WHO during both post-monsoon and pre-monsoon sampling sessions. Significant factor controlling geochemistry of groundwater has been identified to be rock-water interaction processes during both sampling sessions based on the results of Gibb's diagrams. Geochemical modeling studies have revealed that fluorite (CaF2) is, indeed, present as a significant fluoride-bearing mineral in the groundwaters of this study area. Calcite or CaCO3 is one of the most common minerals with which fluorite remains associated, and saturation index calculations have revealed that the calcite-fluorite geochemistry is the dominant factor controlling fluoride concentration in this area during both post- and pre-monsoon. High fluoride waters have also been found to be of `bicarbonate' type showing increase of sodium in water with decrease of calcium.

EMSL Geochemistry, Biogeochemistry and Subsurface Science-Science Theme Advisory Panel Meeting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, Gordon E.; Chaka, Anne; Shuh, David K.

2011-08-01

This report covers the topics of discussion and the recommendations of the panel members. On December 8 and 9, 2010, the Geochemistry, Biogeochemistry, and Subsurface Science (GBSS) Science Theme Advisory Panel (STAP) convened for a more in-depth exploration of the five Science Theme focus areas developed at a similar meeting held in 2009. The goal for the fiscal year (FY) 2011 meeting was to identify potential topical areas for science campaigns, necessary experimental development needs, and scientific members for potential research teams. After a review of the current science in each of the five focus areas, the 2010 STAP discussionsmore » successfully led to the identification of one well focused campaign idea in pore-scale modeling and five longer-term potential research campaign ideas that would likely require additional workshops to identify specific research thrusts. These five campaign areas can be grouped into two categories: (1) the application of advanced high-resolution, high mass accuracy experimental techniques to elucidate the interplay between geochemistry and microbial communities in terrestrial ecosystems and (2) coupled computation/experimental investigations of the electron transfer reactions either between mineral surfaces and outer membranes of microbial cells or between the outer and inner membranes of microbial cells.« less

Mineralogy and geochemistry of claystones from the Guadalupian-Lopingian boundary at Penglaitan, South China: Insights into the pre-Lopingian geological events

NASA Astrophysics Data System (ADS)

Zhong, Yu-Ting; He, Bin; Xu, Yi-Gang

2013-01-01

The Guadalupian-Lopingian (G/L) boundary, at a stratigraphically well-documented outcrop in Penglaitan, Guangxi Autonomous Region, South China, has been approved as the Global Stratotype Section and Point (GSSP). Several volcanic ashes or tuffs occur at this boundary, but their mineralogy and geochemistry are not available yet and no reliable age for this boundary has been obtained. A combined study of mineralogy, geochemistry and geochronology has been carried out in this study on six layers of claystones collected below (Group 1) and above (Group 2) the G/L boundary at the Penglaitan section. Both Group 1 and Group 2 claystones are likely clastic in origin, rather than volcanic ashes as previously thought. Thus the Penglaitan claystones are not suitable for age determination of the G/L boundary. They are significantly different in terms of mineralogy and geochemistry. Specifically, Group 1 claystones are likely derived from a mafic source which is genetically related to the Emeishan large igneous province, therefore providing additional evidence for the synchroneity between the G/L boundary mass extinction and the Emeishan volcanism. Group 2 samples were derived from a felsic source, of which zircons yield an age spectrum peaked at 262 ± 3 Ma, undistinguishable within the uncertainty from the currently accepted G/L boundary age (260.4 ± 0.4 Ma). Nevertheless, Group 2 samples are not related to Emeishan volcanism, because their negative zircon ɛHf(t) values differ significantly from those of Emeishan magmas and trace element compositions of zircons are indicative of an arc source, rather than a within-plate source. In consideration of paleogeographic reconstruction, we propose that the Group 2 claystones may have been derived from continental arcs during the palaeo-Tethys evolution. This is the first sedimentary evidence for Permian continental arc in the northern margin of palaeo-Tethys.

Efficacy of Biostimulation for Uranium Sequestration: Coupled Effects Sediment/Groundwater Geochemistry and Microbiology

NASA Astrophysics Data System (ADS)

Xu, J.; Veeramani, H.; Qafoku, N. P.; Singh, G.; Pruden, A.; Kukkadapu, R. K.; Hochella, M. F., Jr.

2015-12-01

A systematic flow-through column study was conducted using sediments and groundwater from the subsurface at the U.S. Department of Energy's Integrated Field Research Challenge (IFRC) site in Rifle, Colorado, to better understand the efficacy of uranium removal from the groundwater with and without biostimulation in the form of acetate amendments. The interactive effects of acetate amendment, groundwater/sediment geochemistry, and intrinsic bacterial community composition were evaluated using four types of sediments, collected from different uranium-contaminated (D08, LQ107, CD) or non-contaminated (RABS) aquifers. Subtle variations in the sediments' geochemistry in terms of mineral compositions, particle sizes, redox conditions, and metal(loid) co-contaminants had a marked effect on the uranium removal efficiency, following a descending trend of D08 (~ 90 to 95%) >> RABS (~ 20 to 25) ≥ LQ107 (~ 15 to 20%) > CD (~ -10 to 0%). Overall, biostimulation of the sediments with acetate drove deeper anoxic conditions and observable shifts in bacterial population structures. The abundance of dissimilatory sulfate-reduction genes (i.e., drsA), markers of sulfate-reducing bacteria, were highest in the sediments that performed best in terms of uranium removal. By comparison, no obvious associations were found between the uranium removal efficiency and the abundance of typical iron-reducing microorganisms, e.g., Geobacter spp. In the sediments where bacterial biomass was relatively low and sulfate-reduction was not detected (i.e., CD), abiotic adsorption onto fine mineral surfaces such as phyllosilates likely played a dominant role in the attenuation of aqueous uranium. In these scenarios, however, acetate amendment induced significant remobilization of the sequestered uranium and other heavy metals (e.g., strontium), leading to zero or negative uranium removal efficiencies (i.e., CD). The results of this study suggest that reductive immobilization of uranium can be effectively achieved under predominantly sulfate-reducing conditions in sediment microenvironments when bioavailable iron (III) (oxyhydr)oxides are mostly depleted, and provide insight into the integrated roles of sediment geochemistry, mineralogy, and bacterial population dynamics.

Characterizing the proposed geologic repository for high-level radioactive waste at Yucca Mountain, Nevada--hydrology and geochemistry

USGS Publications Warehouse

Stuckless, John S.; Levich, Robert A.

2012-01-01

This hydrology and geochemistry volume is a companion volume to the 2007 Geological Society of America Memoir 199, The Geology and Climatology of Yucca Mountain and Vicinity, Southern Nevada and California, edited by Stuckless and Levich. The work in both volumes was originally reported in the U.S. Department of Energy regulatory document Yucca Mountain Site Description, for the site characterization study of Yucca Mountain, Nevada, as the proposed U.S. geologic repository for high-level radioactive waste. The selection of Yucca Mountain resulted from a nationwide search and numerous committee studies during a period of more than 40 yr. The waste, largely from commercial nuclear power reactors and the government's nuclear weapons programs, is characterized by intense penetrating radiation and high heat production, and, therefore, it must be isolated from the biosphere for tens of thousands of years. The extensive, unique, and often innovative geoscience investigations conducted at Yucca Mountain for more than 20 yr make it one of the most thoroughly studied geologic features on Earth. The results of these investigations contribute extensive knowledge to the hydrologic and geochemical aspects of radioactive waste disposal in the unsaturated zone. The science, analyses, and interpretations are important not only to Yucca Mountain, but also to the assessment of other sites or alternative processes that may be considered for waste disposal in the future. Groundwater conditions, processes, and geochemistry, especially in combination with the heat from radionuclide decay, are integral to the ability of a repository to isolate waste. Hydrology and geochemistry are discussed here in chapters on unsaturated zone hydrology, saturated zone hydrology, paleohydrology, hydrochemistry, radionuclide transport, and thermally driven coupled processes affecting long-term waste isolation. This introductory chapter reviews some of the reasons for choosing to study Yucca Mountain as a repository site.

Characterizing the proposed geologic repository for high-level radioactive waste at Yucca Mountain, Nevada: hydrology and geochemistry

USGS Publications Warehouse

Stuckless, John S.; Levich, Robert A.

2012-01-01

This hydrology and geochemistry volume is a companion volume to the 2007 Geological Society of America Memoir 199, The Geology and Climatology of Yucca Mountain and Vicinity, Southern Nevada and California, edited by Stuckless and Levich. The work in both volumes was originally reported in the U.S. Department of Energy regulatory document Yucca Mountain Site Description, for the site characterization study of Yucca Mountain, Nevada, as the proposed U.S. geologic repository for high-level radioactive waste. The selection of Yucca Mountain resulted from a nationwide search and numerous committee studies during a period of more than 40 yr. The waste, largely from commercial nuclear power reactors and the government's nuclear weapons programs, is characterized by intense penetrating radiation and high heat production, and, therefore, it must be isolated from the biosphere for tens of thousands of years. The extensive, unique, and often innovative geoscience investigations conducted at Yucca Mountain for more than 20 yr make it one of the most thoroughly studied geologic features on Earth. The results of these investigations contribute extensive knowledge to the hydrologic and geochemical aspects of radioactive waste disposal in the unsaturated zone. The science, analyses, and interpretations are important not only to Yucca Mountain, but also to the assessment of other sites or alternative processes that may be considered for waste disposal in the future. Groundwater conditions, processes, and geochemistry, especially in combination with the heat from radionuclide decay, are integral to the ability of a repository to isolate waste. Hydrology and geochemistry are discussed here in chapters on unsaturated zone hydrology, saturated zone hydrology, paleohydrology, hydrochemistry, radionuclide transport, and thermally driven coupled processes affecting long-term waste isolation. This introductory chapter reviews some of the reasons for choosing to study Yucca Mountain as a repository site.

Proceedings of the 38th Lunar and Planetary Science Conference

NASA Technical Reports Server (NTRS)

2007-01-01

The sessions in the conference include: Titan, Mars Volcanism, Mars Polar Layered Deposits, Early Solar System Isotopes, SPECIAL SESSION: Mars Reconnaissance Orbiter: New Ways of Studying the Red Planet, Achondrites: Exploring Oxygen Isotopes and Parent-Body Processes, Solar System Formation and Evolution, SPECIAL SESSION: SMART-1, . Impact Cratering: Observations and Experiments, SPECIAL SESSION: Volcanism and Tectonism on Saturnian Satellites, Solar Nebula Composition, Mars Fluvial Geomorphology, Asteroid Observations: Spectra, Mostly, Mars Sediments and Geochemistry: View from the Surface, Mars Tectonics and Crustal Dichotomy, Stardust: Wild-2 Revealed, Impact Cratering from Observations and Interpretations, Mars Sediments and Geochemistry: The Map View, Chondrules and Their Formation, Enceladus, Asteroids and Deep Impact: Structure, Dynamics, and Experiments, Mars Surface Process and Evolution, Martian Meteorites: Nakhlites, Experiments, and the Great Shergottite Age Debate, Stardust: Mainly Mineralogy, Astrobiology, Wind-Surface Interactions on Mars and Earth, Icy Satellite Surfaces, Venus, Lunar Remote Sensing, Space Weathering, and Impact Effects, Interplanetary Dust/Genesis, Mars Cratering: Counts and Catastrophes?, Chondrites: Secondary Processes, Mars Sediments and Geochemistry: Atmosphere, Soils, Brines, and Minerals, Lunar Interior and Differentiation, Mars Magnetics and Atmosphere: Core to Ionosphere, Metal-rich Chondrites, Organics in Chondrites, Lunar Impacts and Meteorites, Presolar/Solar Grains, Topics for Print Only papers are: Outer Planets/Satellites, Early Solar System, Interplanetary Dust, Comets and Kuiper Belt Objects, Asteroids and Meteoroids, Chondrites, Achondrites, Meteorite Related, Mars Reconnaissance Orbiter, Mars, Astrobiology, Planetary Differentiation, Impacts, Mercury, Lunar Samples and Modeling, Venus, Missions and Instruments, Global Warming, Education and Public Outreach, Poster sessions are: Asteroids/Kuiper Belt Objects, Galilean Satellites: Geology and Mapping, Titan, Volcanism and Tectonism on Saturnian Satellites, Early Solar System, Achondrite Hodgepodge, Ordinary Chondrites, Carbonaceous Chondrites, Impact Cratering from Observations and Interpretations, Impact Cratering from Experiments and Modeling, SMART-1, Planetary Differentiation, Mars Geology, Mars Volcanism, Mars Tectonics, Mars: Polar, Glacial, and Near-Surface Ice, Mars Valley Networks, Mars Gullies, Mars Outflow Channels, Mars Sediments and Geochemistry: Spirit and Opportunity, Mars Reconnaissance Orbiter: New Ways of Studying the Red Planet, Mars Reconnaissance Orbiter: Geology, Layers, and Landforms, Oh, My!, Mars Reconnaissance Orbiter: Viewing Mars Through Multicolored Glasses; Mars Science Laboratory, Phoenix, and ExoMars: Science, Instruments, and Landing Sites; Planetary Analogs: Chemical and Mineral, Planetary Analogs: Physical, Planetary Analogs: Operations, Future Mission Concepts, Planetary Data, Imaging, and Cartography, Outer Solar System, Presolar/Solar Grains, Stardust Mission; Interplanetary Dust, Genesis, Asteroids and Comets: Models, Dynamics, and Experiments, Venus, Mercury, Laboratory Instruments, Methods, and Techniques to Support Planetary Exploration; Instruments, Techniques, and Enabling Techologies for Planetary Exploration; Lunar Missions and Instruments, Living and Working on the Moon, Meteoroid Impacts on the Moon, Lunar Remote Sensing, Lunar Samples and Experiments, Lunar Atmosphere, Moon: Soils, Poles, and Volatiles, Lunar Topography and Geophysics, Lunar Meteorites, Chondrites: Secondary Processes, Chondrites, Martian Meteorites, Mars Cratering, Mars Surface Processes and Evolution, Mars Sediments and Geochemistry: Regolith, Spectroscopy, and Imaging, Mars Sediments and Geochemistry: Analogs and Mineralogy, Mars: Magnetics and Atmosphere, Mars Aeolian Geomorphology, Mars Data Processing and Analyses, Astrobiology, Engaging Student Educators and the Public in Planetary Science,

The geochemistry of carbonatites revisited: Two major types of continental carbonatites and their trace-element signatures

NASA Astrophysics Data System (ADS)

Chakhmouradian, A.

2009-04-01

There have been several attempts to systematize the geochemistry of carbonatites, most recently by Samoilov (1984), Nelson et al. (1988), Woolley and Kempe (1989), and Rass (1998). These studies revealed a number of important geochemical characteristics that can be used to track the evolutionary history of these rocks, distinguish them from modally similar metamorphic parageneses, and aid in mineral exploration for rare earths, niobium and other resources commonly associated with carbonatites. Important breakthroughs in the understanding of carbonatite petrogenesis and numerous reports of new carbonatite localities made in the past two decades lay the ground for a critical re-assessment of the geochemistry of these rocks. A new representative database of whole-rock carbonatite analyses was compiled from the post-1988 literature and various unpublished sources. The database contains 820 analyses encompassing calcio-, magnesio- and ferrocarbonatites from 174 localities (ca. one-third of the total number of carbonatites known worldwide) reduced to ca. 350 analyses following the approach of Woolley and Kempe (1989). Carbonatites emplaced in oceanic settings (e.g., Cape Verde), ophiolite belts (e.g., Oman), or those of uncertain tectonic affinity (e.g., El Picacho in Mexico) were not included. Two major types of continental carbonatites can be distinguished on the basis of their geological setting and trace-element geochemistry: (1) carbonatites emplaced in rifts and smaller-scale extensional structures developed in stable Archean cratons or paleo-orogenic belts, and (2) carbonatites emplaced in collisional settings following the orogenesis. In both settings, the most common and best-studied type of carbonatite is calcite carbonatite (predominantly intrusive with a small percentage of extrusive occurrences), which accounts for 62% of the analyses included in the database. Both types of carbonatite are typically associated with alkaline silicate lithologies (meleigites, nepheline syenites, etc.), but those associated with type-1 rocks are typically Na-rich and silica-undersaturated, whereas type-2 carbonatites are associated with K-rich silica-saturated to undersaturated syenites. Type-1 carbonatites are notably different from their type-2 counterparts in showing higher abundances of high-field-strength elements (HFSE = Ti, Zr, Hf, Nb, Ta), Rb, U and V, but lower levels of Sr, Ba, Pb, rare-earth elements, F and S. Key element ratios are also different in the two carbonatite types; in particular, Rb/K, Nb/Ta, Zr/Hf and Ga/Al values are consistently higher in type-1 samples. Notably, some element ratios (e.g., Co/Ni and Y/Ho) are very similar in both groups. Type-2 carbonatites commonly show a 13C-depleted signature relative to the "primary carbonatite" range (Deines, 1989). The observed differences in geological setting and geochemistry indicate the existence of two distinct carbonatite sources in the subcontinental lithosphere: amphibole-bearing lherzolite producing type-1 rocks (cf. Chakhmouradian, 2006), and subducted oceanic crust (rutile-bearing eclogite?) yielding type-2 melts depleted in HFSE, but enriched in light carbon, large-ion-incompatible elements, F and S. References: Chakhmouradian, A.R. (2006) High-field-strength elements in carbonatitic rocks: Geochemistry, crystal chemistry and significance for constraining the sources of carbonatites. Chem. Geol., 235, 138-160. Deines, P. (1989) Stable isotope variations in carbonatites. In: Carbonatites: Genesis and Evolution (K. Bell, Ed.). Unwin Hyman, London, 301-359. Nelson, D.R., Chivas, A.R., Chappell, B.V. and McCulloch, M.T. (1988) Geochemical and isotopic systematic in carbonatites and implications for the evolution of ocean-island sources. Geochim. Cosmochim. Acta, 52, 1-17. Rass, I.T. (1998) Geochemical features of carbonatite indicative of the composition, evolution, and differentiation of their mantle magmas. Geochem. Int., 36, 107-116. Samoilov, V.S. (1984) Geochemistry of Carbonatites. Nauka, Moscow (in Russ.). Woolley, A.R. and Kempe, D.R.C. (1989) Carbonatites: nomenclature, average chemical compositions, and element distribution. In: Carbonatites: Genesis and Evolution (K. Bell, Ed.). Unwin Hyman, London, 1-14.

Analysis of data from test-well sites along the downdip limit of freshwater in the Edwards Aquifer, San Antonio, Texas, 1985-87

USGS Publications Warehouse

Groschen, G.E.

1994-01-01

A consistent trend in the water quality was not detected in the monitor-well data for July 1986-April 1987. This was caused, in part, by the average to above-average rainfall and by the lack of large withdrawals during the period. The water quality of samples from several of the wells was similar to the water quality determined by a previous study of the area. Geochemistry of the oil- or gas-well brines from downdip in the saline-water zone had slight resemblance to the geochemistry of the water at the downdip limit of freshwater; updip flow of saline water toward the freshwater zone was not indicated.

Aubrite and Impact Melt Enstatite Chondrite Meteorites as Potential Analogs to Mercury

NASA Technical Reports Server (NTRS)

Wilbur, Z. E.; Udry, A.; Mccubbin, Francis M.; McCubbin, F. M.; Combs, L. M.; Rahib, R. R.; McCoy, C.; McCoy, T. J.

2018-01-01

The MESSENGER (MErcury Sur-face, Space ENvironment, GEochemistry and Ranging) orbiter measured the Mercurian surface abundances of key rock-forming elements to help us better understand the planet's surface and bulk geochemistry. A major discovery is that the Mercurian surface and interior are characterized by an extremely low oxygen fugacity (ƒO2; Iron-Wüstite (IW) -7.3 to IW-2.6. This is supported by low Fe and high S abundances on the surface. This low ƒO2 causes a different elemental partioning from what is observed on Earth. Using surface composition, it was shown that the Mercurian surface mainly consists of normative plagioclase, pyroxene, olivine, and exotic sulfides, such as niningerite ((Mg,Mn, Fe)S) and oldhamite (CaS).

Further foraging for pristine nonmare rocks - Correlations between geochemistry and longitude

NASA Technical Reports Server (NTRS)

Warren, P. H.; Wasson, J. T.

1980-01-01

The most recent results from a project to find and describe pristine (that is, compositionally endogenous) nonmare rocks are reported. Sixteen nonmare samples are characterized petrographically and by composition, among them numerous key trace elements (siderophiles, incompatibles). Current knowledge about nonmare lunar rocks is surveyed, with emphasis placed on correlations between geochemistry and longitude. Several systematic differences between western ANT (that is, nonKREEPy, nonmare) rocks and the much more thoroughly studied eastern ANT rocks are noted. It is noted that western ANT rocks, whether pristine or nonpristine, tend to have higher Eu/Sm than their eastern counterparts. Pristine western ANT rocks, however, tend to have lower Sc/Sm and Ti/Sm than pristine eastern ANT rocks.

TRACE ELEMENT DISTRIBUTION IN SEDIMENTS OF THE MID-ATLANTIC RIDGE.

DTIC Science & Technology

MARINE GEOLOGY, ATLANTIC OCEAN), (*OCEAN BOTTOM, MINERALS), SEDIMENTATION, IRON, COBALT, MANGANESE, STRONTIUM, CHLORITES, NEUTRON ACTIVATION, GEOCHEMISTRY, CALCITE , CARBONATES, X RAY DIFFRACTION, CLAY MINERALS, THESES

Conference on Chondrules and Their Origins

NASA Technical Reports Server (NTRS)

Hrametz, K.

1983-01-01

Chondrule parent materials, chondrule formation, and post-formational history are addressed. Contributions involving mineralogy petrology, geochemistry, geochronology, isotopic measurements, physical measurements, experimental studies, and theoretical studies are included.

Coal emissions adverse human health effects associated with ultrafine/nano-particles role and resultant engineering controls.

PubMed

Oliveira, Marcos L S; Navarro, Orlando G; Crissien, Tito J; Tutikian, Bernardo F; da Boit, Kátia; Teixeira, Elba C; Cabello, Juan J; Agudelo-Castañeda, Dayana M; Silva, Luis F O

2017-10-01

There are multiple elements which enable coal geochemistry: (1) boiler and pollution control system design parameters, (2) temperature of flue gas at collection point, (3) feed coal and also other fuels like petroleum coke, tires and biomass geochemistry and (4) fuel feed particle size distribution homogeneity distribution, maintenance of pulverisers, etc. Even though there is a large number of hazardous element pollutants in the coal-processing industry, investigations on micrometer and nanometer-sized particles including their aqueous colloids formation reactions and their behaviour entering the environment are relatively few in numbers. X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/ (Energy Dispersive Spectroscopy) EDS/ (selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM)/EDS and granulometric distribution analysis were used as an integrated characterization techniques tool box to determine both geochemistry and nanomineralogy for coal fly ashes (CFAs) from Brazil´s largest coal power plant. Ultrafine/nano-particles size distribution from coal combustion emissions was estimated during the tests. In addition the iron and silicon content was determined as 54.6% of the total 390 different particles observed by electron bean, results aimed that these two particles represent major minerals in the environment particles normally. These data may help in future investigations to asses human health actions related with nano-particles. Copyright © 2017 Elsevier Inc. All rights reserved.

Community-Based Development of Standards for Geochemical and Geochronological Data

NASA Astrophysics Data System (ADS)

Lehnert, K. A.; Walker, D.; Vinay, S.; Djapic, B.; Ash, J.; Falk, B.

2007-12-01

The Geoinformatics for Geochemistry (GfG) Program (www.geoinfogeochem.org) and the EarthChem project (www.earthchem.org) aim to maximize the application of geochemical data in Geoscience research and education by building a new advanced data infrastructure for geochemistry that facilitates the compilation, communication, serving, and visualization of geochemical data and their integration with the broad Geoscience data set. Building this new data infrastructure poses substantial challenges that are primarily cultural in nature, and require broad community involvement in the development and implementation of standards for data reporting (e.g., metadata for analytical procedures, data quality, and analyzed samples), data publication, and data citation to achieve broad acceptance and use. Working closely with the science community, with professional societies, and with editors and publishers, recommendations for standards for the reporting of geochemical and geochronological data in publications and to data repositories have been established, which are now under consideration for adoption in journal and agency policies. The recommended standards are aligned with the GfG and EarthChem data models as well as the EarthChem XML schema for geochemical data. Through partnerships with other national and international data management efforts in geochemistry and in the broader marine and terrestrial geosciences, GfG and EarthChem seek to integrate their development of geochemical metadata standards, data format, and semantics with relevant existing and emerging standards and ensure compatibility and compliance.

Using geochemistry as a tool for correlating proximal andesitic tephra: Case studies from Mt Rainier (USA) and Mt Ruapehu (New Zealand)

USGS Publications Warehouse

Donoghue, S.L.; Vallance, J.; Smith, I.E.M.; Stewart, R.B.

2007-01-01

Volcanic hazards assessments at andesite stratovolcanoes rely on the assessment of frequency and magnitude of past events. The identification and correlation of proximal and distal andesitic tephra, which record the explosive eruptive history, are integral to such assessments. These tephra are potentially valuable stratigraphic marker beds useful to the temporal correlation and age dating of Quaternary volcanic, volcaniclastic and epiclastic sedimentary deposits with which they are interbedded. At Mt Ruapehu (New Zealand) and Mt Rainier (USA), much of the detail of the recent volcanic record remains unresolved because of the difficulty in identifying proximal tephra. This study investigates the value of geochemical methods in discriminating andesitic tephra. Our dataset comprises petrological and geochemical analyses of tephra that span the late Quaternary eruptive record of each volcano. Our data illustrate that andesitic tephra are remarkably heterogeneous in composition. Tephra compositions fluctuate widely over short time intervals, and there are no simple or systematic temporal trends in geochemistry within either eruptive record. This complexity in tephra geochemistry limits the application of geochemical approaches to tephrostratigraphic studies, beyond a general characterisation useful to provenance assignation. Petrological and geochemical data suggest that the products of andesite systems are inherently variable and therefore intractable to discrimination by simple geochemical methods alone. Copyright ?? 2006 John Wiley & Sons, Ltd.

The data of geochemistry

USGS Publications Warehouse

Clarke, Frank Wigglesworth

1924-01-01

Upon the subject of geochemistry a vast literature exists, but it is widely scattered and portions of it are difficult of access. The general treatises, like the classical works of Bischof and of Koth, are not recent, and great masses of modern data are as yet uncorrelated. The American material alone is singularly rich, but most of it has been accumulated since Roth's treatise was published. The science of chemistry, moreover, has undergone great changes during the last 25 years, and many subjects now appear under new and generally unfamiliar aspects. The methods and principles of physical chemistry are being more and more applied to the solution of geochemical problems,1 as is shown by the well-known researches of Van't Hoff upon the Stassfurt salts and the magmatic studies of Vogt, Doelter, and others. The great work in progress at the geophysical laboratory of the Carnegie Institution is another illustration of the change now taking place in geochemical investigation. To bring some of the data together, to formulate a few of the problems and to present certain general conclusions in their modern form are the purposes of this memoir. It is not an exhaustive monograph upon geochemistry, but rather a critical summary of what is now known, and a guide to the more important literature of the subject. If it does no more than to make existing data available to the reader, its preparation will be justified.

Mineralogy and geochemistry of picro-dolerite dykes from the central Deccan Traps flood basaltic province, India, and their geodynamic significance

NASA Astrophysics Data System (ADS)

Dongre, Ashish; Viljoen, K. S.; Rathod, A.

2018-04-01

Constituent mineral compositions and whole rock major element geochemistry of picro-dolerite dykes from the central part of the Deccan flood basalt province are presented and discussed. The dykes are characterized by an MgO content of about 13 wt%, coupled with 13-16 modal percents of olivine. A high whole rock molar Mg# value of 71 and the presence of magnesian olivine phenocrysts ( Fo78) are consistent with a primitive (i.e. unevolved) geochemistry. The nature and composition of clinopyroxene (augite and pigeonite), plagioclase feldspar (labradorite) and Fe-Ti oxides (mostly ilmenite and magnetite) are also discussed, with implications drawn with respect to the geodynamics. High MgO magmas and rocks such as picrites are generally considered to be indicative of plume magmatism, formed by high degrees of partial melting in, e.g. the high-temperature region of a plume head. Recent age data is consistent with a model in which the Deccan LIP picritic magmatism is associated with the main phase of Deccan Trap activity at 66 Ma, as a result of a syn- to post rifting phase associated with the impact of the Rèunion mantle plume. It is speculated that the differentiation of primary olivine basaltic magma of picritic composition, may have been the mechanism for the generation of alkalic basalts which occurs in the Deccan Trap basaltic sequence.

Petrography and geochemistry of the Middle Miocene Gebel El Rusas sandstones, Eastern Desert, Egypt: Implications for provenance and tectonic setting

NASA Astrophysics Data System (ADS)

Zaid, Samir M.

2017-10-01

Petrography and bulk rock geochemistry of the Middle Miocene sandstones of the lower and upper members of Gebel El Rusas Formation along the Egyptian Red Sea Coastal plain, have been investigated to determine the provenance, tectonic setting, and weathering condition of this formation. The Lower Member is formed mainly of sandstones and conglomerates with clay interbeds. The Upper Member is more calcareous and formed mainly of sandstones and limestones with marls and clays intercalations. Petrographically, the Lower Member sandstones are mostly immature and classified as arkoses with an average framework composition of Q_{66}F_{29}R5, and the Upper Member sandstones are partly submature (more quartzose, less feldspathic) and classified as subarkoses with an average framework composition of Q_{80}F_{17}R3. The Gebel El Rusas sandstones are enriched in Sr, Ba, Zr and Rb and depleted in Co and U, as compared to UCC. The chemical index of alteration (CIA) values suggest moderate weathering conditions. The geochemistry results revealed that the Gebel El Rusas sandstones were derived from felsic-granitic source rocks and deposited in a passive margin of a synrift basin. The inferred tectonic setting for Middle Miocene Gebel El Rusas sandstones in the study area is consistent with the regional geology of the Eastern Desert of Egypt during Middle Miocene.

Essential Elements of Geologic Reports.

ERIC Educational Resources Information Center

Webb, Elmer James

1988-01-01

Described is a report outline for geologic reports. Essential elements include title; abstract; introduction; stratigraphy; petrography; geochemistry; petrology; geophysics; structural geology; geologic history; modeling; economics; conclusions; and recommendations. (Author/CW)

Favorable Geochemistry from Springs and Wells in Colorado

DOE Data Explorer

Richard E. Zehner

2012-02-01

This layer contains favorable geochemistry for high-temperature geothermal systems, as interpreted by Richard "Rick" Zehner. The data is compiled from the data obtained from the USGS. The original data set combines 15,622 samples collected in the State of Colorado from several sources including 1) the original Geotherm geochemical database, 2) USGS NWIS (National Water Information System), 3) Colorado Geological Survey geothermal sample data, and 4) original samples collected by R. Zehner at various sites during the 2011 field season. These samples are also available in a separate shapefile FlintWaterSamples.shp. Data from all samples were reportedly collected using standard water sampling protocols (filtering through 0.45 micron filter, etc.) Sample information was standardized to ppm (micrograms/liter) in spreadsheet columns. Commonly-used cation and silica geothermometer temperature estimates are included.

Environmental geochemistry at the global scale

USGS Publications Warehouse

Plant, J.; Smith, D.; Smith, B.; Williams, L.

2001-01-01

Land degradation and pollution caused by population pressure and economic development pose a threat to the sustainability of the earth's surface, especially in tropical regions where a long history of chemical weathering has made the surface environment particularly fragile. Systematic baseline geochemical data provide a means of monitoring the state of the environment and identifying problem areas. Regional surveys have already been carried out in some countries, and with increased national and international funding they can be extended to cover the rest of the land surface of the globe. Preparations have been made, under the auspices of the International Union of Geological Surveys (IUGS) and the International Association of Geochemistry and Cosmochemistry (IAGC) for the establishment of just such an integrated global database. ?? 2001 NERC. Published by Elsevier Science Ltd.

Geochemistry of Enceladus and the Galilean Moons from in situ Analysis of Ejecta

NASA Astrophysics Data System (ADS)

Postberg, F.; Schmidt, J.; Hillier, J. K.; Kempf, S.; Srama, R.

2012-09-01

The contribution of Cassini's dust detector CDA in revealing subsurface liquid water on Enceladus has demonstrated how questions in planetary science can be addressed by in situ analyses of icy dust particles. As the measurements are particularly sensitive to non-ice compounds embedded in an ice matrix, concentrations of various salts and organic compounds can be identified in different dust populations. This has successfully been demonstrated at Enceladus, giving insights in the moons subsurface geochemistry. This method can be applied to any planetary body that ejects particles to distances suitable for spacecraft sensing. The Galilean moons are of particular relevance since they are believed to steadily emit grains from their surfaces either by active volcanism (Io) or stimulated by micrometeoroid bombardment (Europa, Ganymede, Callisto).

Environmental and medical geochemistry in urban disaster response and preparedness

USGS Publications Warehouse

Plumlee, Geoffrey S.; Morman, Suzette A.; Cook, A.

2012-01-01

History abounds with accounts of cities that were destroyed or significantly damaged by natural or anthropogenic disasters, such as volcanic eruptions, earthquakes, wildland–urban wildfires, hurricanes, tsunamis, floods, urban firestorms, terrorist attacks, and armed conflicts. Burgeoning megacities place ever more people in the way of harm from future disasters. In addition to the physical damage, casualties, and injuries they cause, sudden urban disasters can also release into the environment large volumes of potentially hazardous materials. Environmental and medical geochemistry investigations help us to (1) understand the sources and environmental behavior of disaster materials, (2) assess potential threats the materials pose to the urban environment and health of urban populations, (3) develop strategies for their cleanup/disposal, and (4) anticipate and mitigate potential environmental and health effects from future urban disasters.

Boulder Creek: A stream ecosystem in an urban landscape

USGS Publications Warehouse

Verplanck, Philip L.; Murphy, Sheila F.; Birkeland, Peter W.; Pitlick,; Barber, Larry B.; Schmidt, Travis S.; Raynolds, Robert G.H.

2008-01-01

The Boulder Creek Watershed, within the Front Range region of Colorado, is typical of many western watersheds because it is composed of a high-gradient upper reach mostly fed by snowmelt, a substantial change in gradient at the range front, and an urban corridor within the lower gradient section. A stream ecosystem within an urban landscape not only can provide water for municipal, industrial, and agricultural needs, but also can be utilized for recreation, esthetic enjoyment, and wastewater disposal. The purpose of this 26 km bicycle field trip is to explore the hydrology and geochemistry of Boulder and South Boulder Creeks and to discuss topics including flood frequency and hazards, aqueous geochemistry of the watershed, and potential impacts of invasive species and emerging contaminants on stream ecology.

Sedimentary petrography of the Early Proterozoic Pretoria Group, Transvaal Sequence, South Africa: implications for tectonic setting

NASA Astrophysics Data System (ADS)

Schreiber, U. M.; Eriksson, P. G.; van der Neut, M.; Snyman, C. P.

1992-11-01

Sandstone petrography, geochemistry and petrotectonic assemblages of the predominantly clastic sedimentary rocks of the Early Proterozoic Pretoria Group, Transvaal Sequence, point to relatively stable cratonic conditions at the beginning of sedimentation, interrupted by minor rifting events. Basement uplift and a second period of rifting occurred towards the end of Pretoria Group deposition, which was followed by the intrusion of mafic sill swarms and the emplacement of the Bushveld Complex in the Kaapvaal Craton at about 2050 Ma, the latter indicating increased extensional tectonism, and incipient continental rifting. An overall intracratonic lacustrine tectonic setting for the Pretoria Group is supported by periods of subaerial volcanic activity and palaeosol formation, rapid sedimentary facies changes, significant arkosic sandstones, the presence of non-glacial varves and a highly variable mudrock geochemistry.

Exercises in Applied Geochemistry

ERIC Educational Resources Information Center

Shackleton, W. G.

1977-01-01

Reviews exercises in the analysis of samples and interpretations of results from the geochemical survey portion of a three year teacher education program in geology presented at Salisbury College of Advanced Education. (SL)

Catalog of Computer Programs Used in Undergraduate Geological Education.

ERIC Educational Resources Information Center

Burger, H. Robert

1983-01-01

Provides list of mineralogy, petrology, and geochemistry computer programs. Each entry includes a brief description, program name and language, availability of program listing, and source and/or reference. (JN)

The Role of the Ion Microprobe in Solid-Earth Geochemistry

NASA Astrophysics Data System (ADS)

Hauri, E. H.

2002-12-01

Despite the early success of the electron microprobe in taking petrology to the micron scale, and the widespread use of mass spectrometers in geochemistry and geochronology, it was not until the mid-1970s that the ion microprobe came into its own as an in situ analytical tool in the Earth sciences. Despite this inauspicious beginning, secondary ion mass spectrometry (SIMS) was widely advertised as a technology that would eventually eclipse thermal ion mass spectrometry (TIMS) in isotope geology. However this was not to happen. While various technical issues in SIMS such as interferences and matrix effects became increasingly clear, an appreciation grew for the complimentary abilities of SIMS and TIMS that, even with the advent of ICP-MS, continues to this day. Today the ion microprobe is capable of abundance measurements in the parts-per-billion range across nearly the entire periodic table, and SIMS stable isotope data quality is now routinely crossing the 1 per mil threshold, all at the micron scale. Much of this success is due to the existence of multi-user community facilities for SIMS research, and the substantial efforts of interested scientists to understand the fundamentals of sputtered ion formation and their application to geochemistry. Recent discoveries of evidence for the existence of ancient crust and oceans, the emergence of life on Earth, the large-scale cycling of surficial materials into the deep Earth, and illumination of fundamental high-pressure phenomena have all been made possible by SIMS, and these (and many more) discoveries owe a debt to the vision of creating and supporting multi-user community facilities for SIMS. The ion microprobe remains an expensive instrument to purchase and maintain, yet it is also exceedingly diverse in application. Major improvements in SIMS, indeed in all mass spectrometry, are visible on the near horizon. Yet the geochemical community cannot depend on commercial manufacturers alone to design and build the next generation of instrumentation for geochemistry. Such will be the role of instrument-minded scientists asking questions that simply cannot be answered by extant means. And it will be multi-user facilities that will make such advancements available to the wider geochemical community.

77 FR 50505 - Science Advisory Board Staff Office Request for Nominations of Experts for the SAB Hydraulic...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-21

... and internationally recognized scientists and engineers having experience and expertise related to...; geochemistry and analytical chemistry; environmental monitoring; conducting laboratory and/or field-based...

Rare Earth Geochemistry of Rock Core form WY Reservoirs

DOE Data Explorer

Quillinan, Scott; Bagdonnas, Davin; McLaughlin, J. Fred; Nye, Charles

2016-10-01

These data include major, minor, trace and rare earth element concentration of geologic formations in Wyoming oil and gas fields. *Note - Link below contains updated version of spreadsheet (6/14/2017)

Gas Geochemistry of the Dogger Geothermal Aquifer (Paris Basin, France)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Criaud, A.; Fouillac, C.; Marty, B.

1987-01-20

The low enthalpy program developed in the Paris Basin provides the opportunity for studying the gas geochemistry of the calcareous aquifer of the Dogger. Hydrocarbons and CO{sub 2} are mainly biogenic, He displays high concentrations. He, Ar and N{sub 2} have multiple origins (radioactive decay, atmospheric migration, biochemical processes). The distribution of the gases in the zones of the basin varies in relation to the general chemistry, sedimentology and hydrodynamics. The gas geothermometers do not apply to this environment but useful estimations of the redox potential of the fluid can be derived from CO{sub 2}/CH{sub 4} and N{sub 2}/NH{sub 4}{supmore » +} ratios. H{sub 2} and H{sub 2}S are involved in corrosion processes and scaling in the pipes. 12 refs., 3 figs., 2 tabs.« less

Isotopic geochemistry of Panama rivers

USGS Publications Warehouse

Harmon, Russell S.; Worner, Gerhard; Pribil, Michael; Kern, Zoltan; Forizs, Istvan; Lyons, W. Berry; Gardner, Christopher B.; Goldsmith, Steven T.

2015-01-01

River water samples collected from 78 watersheds rivers along a 500-km transect across a Late Cretaceous-Tertiary andesitic volcanic arc terrane in west-central Panama provide a synoptic overview of riverine geochemistry, chemical denudation, and CO2 consumption in the tropics. D/H and 18O/16O relationships indicate that bedrock dissolution of andesitic arc crust in Panama is driven by water-rock interaction with meteoric precipitation as it passes through the critical zone, with no evidence of a geothermal or hydrothermal input. Sr-isotope relationships suggest a geochemical evolution for Panama riverine waters that involves mixing of bedrock pore water with water having 87Sr/86Sr ratios between 0.7037-0.7043 and relatively high Sr-contents with waters of low Sr content that enriched in radiogenic Sr that are diluted by infiltrating rainfall to variable extents.

Geochemistry of Woranso-Mille Pliocene basalts from west-central Afar, Ethiopia: Implications for mantle source characteristics and rift evolution

NASA Astrophysics Data System (ADS)

Alene, Mulugeta; Hart, William K.; Saylor, Beverly Z.; Deino, Alan; Mertzman, Stanley; Haile-Selassie, Yohannes; Gibert, Luis B.

2017-06-01

The Woranso-Mille (WORMIL) area in the west-central Afar, Ethiopia, contains several Pliocene basalt flows, tuffs, and fossiliferous volcaniclastic beds. We present whole-rock major- and trace-element data including REE, and Sr-Nd-Pb isotope ratios from these basalts to characterize the geochemistry, constrain petrogenetic processes, and infer mantle sources. Six basalt groups are distinguished stratigraphically and geochemically within the interval from 3.8 to 3 Ma. The elemental and isotopic data show intra- and inter-group variations derived primarily from source heterogeneity and polybaric crystallization ± crustal inputs. The combined Sr-Nd-Pb isotope data indicate the involvement of three main reservoirs: the Afar plume, depleted mantle, and enriched continental lithosphere (mantle ± crust). Trace element patterns and ratios further indicate the basalts were generated from spinel-dominated shallow melting, consistent with significantly thinned Pliocene lithosphere in western Afar. The on-land continuation of the Aden rift into western Afar during the Pliocene is reexamined in the context of the new geochemistry and age constraints of the WORMIL basalts. The new data reinforce previous interpretations that progressive rifting and transformation of the continental lithosphere to oceanic lithosphere allows for increasing asthenospheric inputs through time as the continental lithosphere is thinned. Accepted trace element values for BHVO-2 are those recently recommended by Jochum et al. (2016) rounded to provide the same significant figures as the data. Ternary model after Schilling et al. (1992); Endmembers from Rooney et al. (2012).

Physicochemical variations in atmospheric aerosols recorded at sea onboard the Atlantic-Mediterranean 2008 Scholar Ship cruise (Part II): Natural versus anthropogenic influences revealed by PM 10 trace element geochemistry

NASA Astrophysics Data System (ADS)

Moreno, Teresa; Pérez, Noemi; Querol, Xavier; Amato, Fulvio; Alastuey, Andrés; Bhatia, Ravinder; Spiro, Baruch; Hanvey, Melanie; Gibbons, Wes

2010-07-01

The geochemistry of PM 10 filter samples collected at sea during the Scholar Ship Atlantic-Mediterranean 2008 research cruise reveals a constantly changing compositional mix of pollutants into the marine atmosphere. Source apportionment modelling using Positive Matrix Factorization identifies North African desert dust, sea spray, secondary inorganic aerosols, metalliferous carbon, and V-Ni-bearing combustion particles as the main PM 10 factors/sources. The least contaminated samples show an upper continental crust composition (UCC)-normalised geochemistry influenced by seawater chemistry, with marked depletions in Rb, Th and the lighter lanthanoid elements, whereas the arrival of desert dust intrusions imposes a more upper crustal signature enriched in "geological" elements such as Si, Al, Ti, Rb, Li and Sc. Superimposed on these natural background aerosol loadings are anthropogenic metal aerosols (e.g. Cu, Zn, Pb, V, and Mn) which allow identification of pollution sources such as fossil fuel combustion, biomass burning, metalliferous industries, and urban-industrial ports. A particularly sensitive tracer is La/Ce, which rises in response to contamination from coastal FCC oil refineries. The Scholar Ship database allows us to recognise seaborne pollution sourced from NW Africa, the Cape Verde and Canary islands, and European cities and industrial complexes, plumes which in extreme cases can produce a downwind deterioration in marine air quality comparable to that seen in many cities, and can persist hundreds of kilometres from land.

Helium and carbon gas geochemistry of pore fluids from the sediment-rich hydrothermal system in Escanaba Trough

USGS Publications Warehouse

Ishibashi, J.-I.; Sato, M.; Sano, Y.; Wakita, H.; Gamo, T.; Shanks, Wayne C.

2002-01-01

Ocean Drilling Program (ODP) Leg 169, which was conducted in 1996 provided an opportunity to study the gas geochemistry in the deeper part of the sediment-rich hydrothermal system in Escanaba Trough. Gas void samples obtained from the core liner were analyzed and their results were compared with analytical data of vent fluid samples collected by a submersible dive program in 1988. The gas geochemistry of the pore fluids consisted mostly of a hydrothermal component and was basically the same as that of the vent fluids. The He isotope ratios (R/RA = 5.6-6.6) indicated a significant mantle He contribution and the C isotopic compositions of the hydrocarbons [??13C(CH4) = -43???, ??13C(C2H6) = -20???] were characterized as a thermogenic origin caused by hydrothermal activity. On the other hand, the pore fluids in sedimentary layers away from the hydrothermal fields showed profiles which reflected lateral migration of the hydrothermal hydrocarbons and abundant biogenic CH4. Helium and C isotope systematics were shown to represent a hydrothermal component and useful as indicators for their distribution beneath the seafloor. Similarities in He and hydrocarbon signatures to that of the Escanaba Trough hydrothermal system were found in some terrestrial natural gases, which suggested that seafloor hydrothermal activity in sediment-rich environments would be one of the possible petroleum hydrocarbon generation scenarios in unconventional geological settings. ?? 2002 Elsevier Science Ltd. All rights reserved.

Mobile Geochemistry Instrument Package Facility (MGIPF) for In Situ Mineralogical and Chemical Analysis of Planetary Surface Material

NASA Astrophysics Data System (ADS)

Klingelhöfer, G.; Romstedt, J.; Henkel, H.; Michaelis, H.; Brückner, J.; D'Uston, C.

A first order requirement for any spacecraft mission to land on a solid planetary or moon surface is instrumentation for in-situ mineralogical and chemical analysis 2 Such analysis provide data needed for primary classification and characterization of surface materials present We will discuss a mobile instrument package we have developed for in-situ investigations under harsh environmental conditions like on Mercury or Mars This Geochemistry Instrument Package Facility is a compact box also called payload cab containing three small advanced geochemistry mineralogy instruments the chemical spectrometer APXS the mineralogical M o ssbauer spectrometer MIMOS II 3 and a textural imager close-up camera The payload cab is equipped with two actuating arms with two degrees of freedom permitting precision placement of all instruments at a chosen sample This payload cab is the central part of the small rover Nanokhod which has the size of a shoebox 1 The Nanokhod rover is a tethered system with a typical operational range of sim 100 m Of course the payload cab itself can be attached by means of its arms to any deployment device of any other rover or deployment device 1 Andre Schiele Jens Romstedt Chris Lee Sabine Klinkner Rudi Rieder Ralf Gellert G o star Klingelh o fer Bodo Bernhardt Harald Michaelis The new NANOKHOD Engineeering model for extreme cold environments 8th International symposium on Artificial Intelligence Robotics and Automation in Space 5 - 9 September 2005

Incorporation of basic research and service components in a field environmental geochemistry course

NASA Astrophysics Data System (ADS)

Senko, J.

2015-12-01

"Application-based service learning" (ABSL) refers to an approach to formal course instruction that integrates service and research components into the course. An ABSL approach was employed in a field-based environmental chemistry course, whose goal was to evaluate and monitor the aqueous geochemistry of coal mine-derived acid mine drainage (AMD) in the Appalachia basin. In this course, students conducted literature reviews on the geochemistry and environmental impacts of AMD, participated in a field sampling campaign of several AMD treatment systems, and conducted chemical analyses of the samples that they retrieved. The remainder of the course was dedicated to "lab meetings," during which data was analyzed, conclusions were drawn from the data, and a manuscript was drafted that described the findings of the field analyses, and made recommendations regarding the performance of the AMD treatment systems. The service component of the course focused on socioeconomic impacts of coal mining and the Appalachian region, with the final manuscript distributed to AMD treatment practitioners and state regulatory agencies. A comparison of pre- and post-course questionnaires that included Likert scale questions revealed that students' attitudes toward basic research improved over the period or the course. Based on the questionnaires attitudes toward service diminished, but "open-ended" questionnaires indicated an improved attitude toward both research and service, with an emphasis on the benefits of research that serves the community. Ultimately, we hope to develop approaches to compare the effectiveness of ABSL-based across disciplines.

Publications - GMC 163 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 163 Publication Details Title: Gas chromatograms from the following 7 North Slope wells Reference Unocal Geochemistry Group, 1990, Gas chromatograms from the following 7 North Slope wells: Aufeis

A Random Sample

ERIC Educational Resources Information Center

Cochran, Wendell

1976-01-01

Presented is a review of papers presented at the 25th International Geological Congress held August 16-25, 1976, Sydney, Australia. Topics include precambrian geology, tectonics, biostratigraphy, geochemistry, quaternary geology, engineering geology, planetology, geological education, and stress environments. (SL)

Geochemistry and origin of regional dolomites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hanson, G.N.; Meyers, W.J.

1992-01-01

This grant supports research on the origins and geochemical aspects of regional dolomites. Eight graduate students are involved in research on dolomite allowing a diverse range of studies. This report outlines their work in the field. (JL)

Rare Earth Element Geochemistry for Produced Waters, WY

DOE Data Explorer

Quillinan, Scott; Nye, Charles; McLing, Travis; Neupane, Hari

2016-06-30

These data represent major, minor, trace, isotopes, and rare earth element concentrations in geologic formations and water associated with oil and gas production. *Note - Link below contains updated version of spreadsheet (6/14/2017)

Experimental microcosm study of the effects of Deepwater Horizon MC-252 oil on the geochemistry and microbiology of Gulf Coast sediment

NASA Astrophysics Data System (ADS)

Donahoe, R. J.; Bej, A.; Raulerson, A.; Rentschler, E. K.

2011-12-01

Microcosm experiments were conducted to examine the impact of oil contamination on Gulf Coast sediment geochemistry and microbial population dynamics. Coastal sediment and seawater were collected from a salt marsh at Bayou la Batre, Alabama, which was not severely impacted by the BP Deepwater Horizon accident of April 2010. Sediment/seawater microcosms were set up in glass jars combusted for 5 hours at 450 degrees C. Non-sterile microcosms spiked with 500 ppm of MC-252 oil were sacrificed in duplicate at various time intervals over a 14 day period to establish a data time series. Sterile controls with and without oil and a non-sterile control without oil were sacrificed in duplicate at 14 days for comparison with the time-series experiments. Solid and aqueous phases were separated by centrifugation and prepared for analysis. Sediment mineralogy was determined using X-ray diffraction and acid-extractable sediment chemistry determined using EPA Method 3051A and ICP-OES analysis. The aqueous phase chemistry was analyzed by ICP-OES and ion chromatography. The mineralogy of the salt marsh sediment is predominantly quartz, but includes reactive phases such as clays (smectite, illite), feldspar, and iron oxide. Iron-bearing clays and iron oxides can serve as electron acceptors for the growth of Fe(III)-reducing bacteria. Microwave digestions of the microcosm substrate samples were performed in triplicate and show no significant variation in major element chemistry over the course of the two week experiment, suggesting that observed temporal trends in aqueous geochemistry may be due to ion exchange processes, rather than mineral dissolution reactions. Microcosm substrate trace element data which indicate possible differences with time are being analyzed for statistical significance. Analysis of aqueous solution geochemistry reveals several interesting temporal trends. Iron and manganese were released to solution after 2 days, suggesting the presence of facultative anaerobic bacteria which are utilizing iron-bearing minerals in the sediment as an electron receptor. Analysis of the bacterial communities present in the experimental substrates is ongoing. Preliminary results using PCR amplification of biodegradative genes relevant to the crude oil show that the 14 day oil-contaminated substrate exhibits positive detection of alkene hydroxylase (alkB), catechol 2,3-dioxygenase (C23DO) and biophenyl dioxygenase (bph) genes. Positive amplification of the bph gene in the uncontaminated non-sterile control confirms that hydrocarbon-degrading microorganisms naturally exist in the sediment. Bacterial tag-encoded FLX-titanium amplicon pyrosequencing is underway to evaluate microbial diversity and function, and is expected to explain observed trends in iron, manganese and trace element geochemistry. Microbial diversity analysis will also include taxonomic and biochemical characterization of bacterial isolates plated on 0.5 Marine Agar and 0.5 R2A and minimal media with MC-252 oil.

Geochemistry of groundwater in the eastern Snake River Plain aquifer, Idaho National Laboratory and vicinity, eastern Idaho

USGS Publications Warehouse

Rattray, Gordon W.

2018-05-30

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) in eastern Idaho produced radiochemical and chemical wastes that were discharged to the subsurface, resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may pose risks to the water quality of the aquifer. In order to understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted a study of groundwater geochemistry to improve the understanding of hydrologic and chemical processes in the ESRP aquifer at and near the INL and to understand how these processes affect waste constituents in the aquifer.Geochemistry data were used to identify sources of recharge, mixing of water, and directions of groundwater flow in the ESRP aquifer at the INL. The geochemistry data were analyzed from 167 sample sites at and near the INL. The sites included 150 groundwater, 13 surface-water, and 4 geothermal-water sites. The data were collected between 1952 and 2012, although most data collected at the INL were collected from 1989 to 1996. Water samples were analyzed for all or most of the following: field parameters, dissolved gases, major ions, dissolved metals, isotope ratios, and environmental tracers.Sources of recharge identified at the INL were regional groundwater, groundwater from the Little Lost River (LLR) and Birch Creek (BC) valleys, groundwater from the Lost River Range, geothermal water, and surface water from the Big Lost River (BLR), LLR, and BC. Recharge from the BLR that may have occurred during the last glacial epoch, or paleorecharge, may be present at several wells in the southwestern part of the INL. Mixing of water at the INL primarily included mixing of surface water with groundwater from the tributary valleys and mixing of geothermal water with regional groundwater. Additionally, a zone of mixing between tributary valley water and regional groundwater, trending southwesterly, extended from near the northeastern boundary of the INL to the southern boundary of the INL. Groundwater flow directions for regional groundwater were southwesterly, and flow directions for tributary groundwater were southeasterly upon entering the ESRP, but eventually began to flow southwesterly in a direction parallel with regional groundwater. Several discrepancies were identified from comparison of sources of recharge determined from geochemistry data and backward particle tracking with a groundwater-flow model. Some discrepancies observed in the particle tracking results included representation of recharge from BC near the north INL boundary, groundwater from the BC valley not extending far enough south, regional groundwater that extends too far west in the southern part of the INL, and no representation of recharge from geothermal water in model layer 1 or recharge from the BLR in the southwestern part of the INL.

Thermodynamics of Aqueous Organic Sulfur Compounds: A Key to the Organic Geochemistry of Hydrothermal Systems?

NASA Technical Reports Server (NTRS)

Schulte, Mitchell; Rogers, Karyn L.; DeVincenzi, Donald L. (Technical Monitor)

2000-01-01

Hydrothermal environments are locations of varied geochemistry due to the disequilibrium between vent fluids and seawater. The disequilibrium geochemistry has been hypothesized to include reactions to synthesize organic compounds. Observations of the organic geochemistry of hydrothermal vent sites has received little attention. Experimental simulations of these environments, however, indicate that organic compounds may have difficulty forming in a purely aqueous environment. On the other hand, thiols. thioesters and disulfides have been implicated as reaction intermediates between CO or CO2 in experiments of carbon reduction in hydrothermal environments as well as in a variety of biological processes and other abiotic reactions (Wachtershauser, 1990, OLEB 20, 173; Heinen and Lauwers, 1996, OLEB 26, 13 1, Huber and Wachtershauser, 1997, Science 276, 245; Russell et al., 1998, in Thermophiles: The keys to molecular evolution and the origin of life?). The reduction of CO2 to thiols, for example, is observed using the FeS-H2S/FeS2 couple to provide the reducing power (see Schoonen et al., 1999, OLEB 29, 5). In addition, the enzyme involved in final stage of methanogenesis, coenzyme-M, is itself a thiol. Thus, organic sulfur compounds may hold the key to the organic chemistry leading to the origin of life at high temperatures. Understanding the biochemical processes of microorganisms that can live to temperatures at least as high as 113 C (Blochl et al., 1996, Extremophiles 1, 14) requires knowledge of the properties of the chemical reactions involved. In order to assess the role of aqueous organic sulfur compounds in hydrothermal organic geochemistry, we have been attempting to determine their thermodynamic properties. We have culled the literature to obtain the properties of organic sulfur compounds. We are able to calculate a number of essential properties, such as free energies of formation, from solubility data available in the literature together with standard properties of organic sulfur gases. However, a number of the properties for aqueous organic sulfur compounds have not been experimentally determined. Furthermore, most of thermodynamic data that are available are for 25 C and 1 bar. In order to determine reaction properties to temperatures and pressures appropriate to the hydrothermal conditions in which thermophilic organisms actually live, we use equations of state developed by Helgeson and co-workers (Helgeson et al., 1981, AJS 281, 1249). A key piece of information needed to go up in temperature is the partial molal heat capacity, which is one of the properties for which experimental data are unavailable for nearly all organic sulfur compounds. We have used correlation methods to determine the partial molal heat capacities and volumes of many organic solutes. These estimates allow us to asses the role of organic sulfur compounds during the reduction of carbon in hydrothermal settings. We will present these data, along with examples of the thermodynamic properties of reactions involving aqueous organic sulfur compounds.

Publications of the exobiology program for 1983: A special bibliography

NASA Technical Reports Server (NTRS)

Pleasant, L. G. (Compiler); Devincenzi, D. L. (Compiler)

1984-01-01

A list of 1983 publications resulting from research pursued under the auspices of NASA's Exobiology Program is given. Topics in the fields of biological, chemical, and planetary evolution; geochemistry; and intelligent extraterrestrial life are listed.

Fifteenth workshop on geothermal reservoir engineering: Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-01-01

The Fifteenth Workshop on Geothermal Reservoir Engineering was held at Stanford University on January 23--25, 1990. Major topics included: DOE's geothermal research and development program, well testing, field studies, geosciences, geysers, reinjection, tracers, geochemistry, and modeling.

Earth Science in 1970

ERIC Educational Resources Information Center

Geotimes, 1971

1971-01-01

Reviews advancements in earth science during 1970 in each of these areas: economic geology (fuels), economic geology (metals), economic geology (nonmetals), environmental geology, geochemistry, manpower, hydrology, mapping, marine geology, mineralogy, paleontology, plate tectonics, politics and geology, remote sensing, and seismology. (PR)

Project Introduction for SUBSEA: Systematic Underwater Biogeochemical Science and Exploration Analog

NASA Astrophysics Data System (ADS)

Nawotniak, S. E. K.; Lim, D. S. S.; German, C. R.; Shock, E. L.; Huber, J. A.; Breier, J. A.

2018-05-01

NASA SUBSEA studies low T, low P seamounts via integrated volcanology, geochemistry, and microbiology as an analog for Enceladus. Research done in telerobotic space exploration simulation. First cruise is Loihi in August 2018.

Global Catastrophes in Earth History: An Interdisciplinary Conference on Impacts, Volcanism, and Mass Mortality

NASA Technical Reports Server (NTRS)

1988-01-01

Topics addressed include: Cretaceous-Tertiary mass extinctions; geologial indicators for meteorite collisions; carbon dioxide catastrophes; volcanism; climatic changes; geochemistry; mineralogy; fossil records; biospheric traumas; stratigraphy; mathematical models; and ocean dynamics.

Organic and inorganic geochemistry of samples returned from Mars

NASA Technical Reports Server (NTRS)

Kotra, R. K.; Johnson, R. G.

1988-01-01

Although a tremendous amount of knowledge can be obtained by in situ experiments on Mars, greater benefits will be realized with the sample return mission from the perspective of exobiology. Sampling techniques are briefly discussed.

Publications - RDF 2015-17 | Alaska Division of Geological & Geophysical

Science.gov Websites

/10.14509/29519 Publication Products Report Report Information rdf2015_017.pdf (347.0 K) Digital Geospatial Data Digital Geospatial Data Tonsina geochemistry: DGGS samples Data File Format File Size Info

In Situ Instrumentation for Sub-Surface Planetary Geochemistry

NASA Technical Reports Server (NTRS)

Bodnarik, J.; Evans, L.; Floyd, S.; Lim, L.; McClanahan, T.; Namkung, M.; Parsons, A.; Schweitzer, J.; Starr, R.; Trombka, J.

2010-01-01

Novel instrumentation is under development at NASA's Goddard Space Flight Center, building upon earth-based techniques for hostile environments, to infer geochemical processes important to formation and evolution of solid bodies in our Solar System. A prototype instrument, the Pulsed Neutron Generator Gamma Ray and Neutron Detectors (PNG-GRAND), has a 14 MeV pulsed neutron generator coupled with gamma ray and neutron detectors to measure quantitative elemental concentrations and bulk densities of a number of major, minor and trace elements at or below the surfaces with approximately a meter-sized spatial resolution down to depths of about 50 cm without the need to drill. PNG-GRAND's in situ a meter-scale measurements and adaptability to a variety of extreme space environments will complement orbital kilometer-scale and in-situ millimeter scale elemental and mineralogical measurements to provide a more complete picture of the geochemistry of planets, moons, asteroids and comets.

Understanding thermodynamic relationships and geochemical mass balances from catchment to coast: A tribute to the life and career of Owen P. Bricker III

USGS Publications Warehouse

Bricker, Suzanne B.; Mackenzie, Fred T.; Baron, Jill S.; Price, Jason

2014-01-01

This special volume of aquatic geochemistry is dedicated to the memory of Owen Peterson Bricker III (1936–2011) and serves as a tribute to his life and career. Owen had a distinguished and productive research career in both academics at Johns Hopkins University (Fig. 1) and as a public servant with the Maryland Geological Survey, the US Environmental Protection Agency, and the US Geological Survey. He was a pioneer and leader in aqueous geochemistry, who applied a study approach that quantified mineral weathering reactions and equilibrium thermodynamic relations to better understand the chemical evolution of stream water in small watersheds. He will be especially remembered for his efforts to establish rigorous field studies in small catchments around the United States as a means of quantifying the sources of acid-neutralizing capacity that affect the chemical status and biological health of natural waters.

Geothermal Geodatabase for Rico Hot Springs Area and Lemon Hot Springs, Dolores and San Miguel Counties, Colorado

DOE Data Explorer

Richard Zehner

2012-11-01

This geodatabase was built to cover several geothermal targets developed by Flint Geothermal in 2012 during a search for high-temperature systems that could be exploited for electric power development. Several of the thermal springs have geochemistry and geothermometry values indicative of high-temperature systems. In addition, the explorationists discovered a very young Climax-style molybdenum porphyry system northeast of Rico, and drilling intersected thermal waters at depth. Datasets include: 1. Structural data collected by Flint Geothermal 2. Point information 3. Mines and prospects from the USGS MRDS dataset 4. Results of reconnaissance shallow (2 meter) temperature surveys 5. Air photo lineaments 6. Areas covered by travertine 7. Groundwater geochemistry 8. Land ownership in the Rico area 9. Georeferenced geologic map of the Rico Quadrangle, by Pratt et al. 10. Various 1:24,000 scale topographic maps

Elemental geochemistry of sedimentary rocks at Yellowknife Bay, Gale crater, Mars.

PubMed

McLennan, S M; Anderson, R B; Bell, J F; Bridges, J C; Calef, F; Campbell, J L; Clark, B C; Clegg, S; Conrad, P; Cousin, A; Des Marais, D J; Dromart, G; Dyar, M D; Edgar, L A; Ehlmann, B L; Fabre, C; Forni, O; Gasnault, O; Gellert, R; Gordon, S; Grant, J A; Grotzinger, J P; Gupta, S; Herkenhoff, K E; Hurowitz, J A; King, P L; Le Mouélic, S; Leshin, L A; Léveillé, R; Lewis, K W; Mangold, N; Maurice, S; Ming, D W; Morris, R V; Nachon, M; Newsom, H E; Ollila, A M; Perrett, G M; Rice, M S; Schmidt, M E; Schwenzer, S P; Stack, K; Stolper, E M; Sumner, D Y; Treiman, A H; VanBommel, S; Vaniman, D T; Vasavada, A; Wiens, R C; Yingst, R A

2014-01-24

Sedimentary rocks examined by the Curiosity rover at Yellowknife Bay, Mars, were derived from sources that evolved from an approximately average martian crustal composition to one influenced by alkaline basalts. No evidence of chemical weathering is preserved, indicating arid, possibly cold, paleoclimates and rapid erosion and deposition. The absence of predicted geochemical variations indicates that magnetite and phyllosilicates formed by diagenesis under low-temperature, circumneutral pH, rock-dominated aqueous conditions. Analyses of diagenetic features (including concretions, raised ridges, and fractures) at high spatial resolution indicate that they are composed of iron- and halogen-rich components, magnesium-iron-chlorine-rich components, and hydrated calcium sulfates, respectively. Composition of a cross-cutting dike-like feature is consistent with sedimentary intrusion. The geochemistry of these sedimentary rocks provides further evidence for diverse depositional and diagenetic sedimentary environments during the early history of Mars.

Geochemistry of Precambrian carbonates. IV - Early Paleoproterozoic (2.25 +/- 0.25 Ga) seawater

NASA Technical Reports Server (NTRS)

Veizer, Jan; Clayton, R. N.; Hinton, R. W.

1992-01-01

The mineralogy, chemistry, and isotopic composition of the Malmani Dolomite, Duck Creek Dolomite, and Bruce 'Limestone' Member of the Espanola Formation are studied in an effort to restrict the first- and second-order variations in isotopic composition of Early Paleoproterozoic seawater. The diagenetic rank is found to increase in the order Duck Creek less than Bruce less than Malmani. The interpolation of alteration trends to 'best' value yields an estimate of 0.70550 for Sr-87/Sr-86. For delta C-13, the measured range of 0 +/- 1.5 percent PDB is similar to that observed for Phanerozoic marine carbonates, while the 'best' delta O-18 value for dolostones is -5 percent PDB, depleted in O-18 relative to Phanerozoic counterparts but comparable to estimates obtained for Archean facies. The isotope geochemistry and mineralogy of Bruce 'Limestone' Member is consistent with the proposition that the sequence was deposited in a lacustrine environment.

Chemical Oceanography and the Marine Carbon Cycle

NASA Astrophysics Data System (ADS)

Emerson, Steven; Hedges, John

The principles of chemical oceanography provide insight into the processes regulating the marine carbon cycle. The text offers a background in chemical oceanography and a description of how chemical elements in seawater and ocean sediments are used as tracers of physical, biological, chemical and geological processes in the ocean. The first seven chapters present basic topics of thermodynamics, isotope systematics and carbonate chemistry, and explain the influence of life on ocean chemistry and how it has evolved in the recent (glacial-interglacial) past. This is followed by topics essential to understanding the carbon cycle, including organic geochemistry, air-sea gas exchange, diffusion and reaction kinetics, the marine and atmosphere carbon cycle and diagenesis in marine sediments. Figures are available to download from www.cambridge.org/9780521833134. Ideal as a textbook for upper-level undergraduates and graduates in oceanography, environmental chemistry, geochemistry and earth science and a valuable reference for researchers in oceanography.

Clinopyroxene precursors to amphibole sponge in arc crust

PubMed Central

Smith, Daniel J.

2014-01-01

The formation of amphibole cumulates beneath arc volcanoes is a key control on magma geochemistry, and generates a hydrous lower crust. Despite being widely inferred from trace element geochemistry as a major lower crustal phase, amphibole is neither abundant nor common as a phenocryst phase in arc lavas and erupted pyroclasts, prompting some authors to refer to it as a ‘cryptic’ fractionating phase. This study provides evidence that amphibole develops by evolved melts overprinting earlier clinopyroxene—a near-ubiquitous mineral in arc magmas. Reaction-replacement of clinopyroxene ultimately forms granoblastic amphibole lithologies. Reaction-replacement amphiboles have more primitive trace element chemistry (for example, lower concentrations of incompatible Pb) than amphibole phenocrysts, but still have chemistries suitable for producing La/Yb and Dy/Yb ‘amphibole sponge’ signatures. Amphibole can fractionate cryptically as reactions between melt and mush in lower crustal ‘hot zones’ produce amphibole-rich assemblages, without significant nucleation and growth of amphibole phenocrysts. PMID:25002269

Maps showing water geochemistry of the Buffalo Peaks Wilderness Study Area, Lake, Park, and Chaffee Counties, Colorado

USGS Publications Warehouse

Nowlan, G.A.; Ficklin, Walter H.; Dover, Robert A.

1985-01-01

This report presents results of geochemical studies carried out in June and July of 1982 in the Buffalo Peaks Wilderness Study Area, Colo. (see index map). Samples of water were collected from 84 streams and 18 springs draining the study area. Tabulations of the analyses and a sample locality map are in Ficklin and others (1984). The geochemistry of stream sediments and panned concentrates of the study area is in Nowlan and Gerstel (1985). The geology of the study area and vicinity is in Hedlund (1985). The mineral resource potential of the study area is described in Hedlund and others (1983). This report (1) assists in the assessment of the mineral resource potential of the Buffalo Peaks Wilderness Study Area; and (2) compares analyses of water samples with analyses of stream-sediment and panned-concentrate samples (Nowlan and Gerstel, 1985).

Areas with Surface Thermal Anomalies as Detected by ASTER and LANDSAT Data around Pinkerton Hot Springs, Colorado

DOE Data Explorer

Khalid Hussein

2012-02-01

This map shows areas of anomalous surface temperature in northern Saguache Counties identified from ASTER and LANDSAT thermal data and spatial based insolation model. The temperature for the ASTER data was calculated using the Emissivity Normalization Algorithm that separate temperature from emissivity. The incoming solar radiation was calculated using spatial based insolation model developed by Fu and Rich (1999). Then the temperature due to solar radiation was calculated using emissivity derived from ASTER data. The residual temperature, i.e. temperature due to solar radiation subtracted from ASTER temperature was used to identify thermally anomalous areas. Areas having anomalous temperature in the ASTER data are shown in blue diagonal hatch, while areas having anomalous temperature in the LANDSAT data are shown in magenta on the map. Thermal springs and areas with favorable geochemistry are also shown. Springs or wells having non-favorable geochemistry are shown as blue dots.

Areas with Surface Thermal Anomalies as Detected by ASTER and LANDSAT Data in Northwest Delta, Colorado

DOE Data Explorer

Khalid Hussein

2012-02-01

This map shows areas of anomalous surface temperature in northern Saguache Counties identified from ASTER and LANDSAT thermal data and spatial based insolation model. The temperature for the ASTER data was calculated using the Emissivity Normalization Algorithm that separate temperature from emissivity. The incoming solar radiation was calculated using spatial based insolation model developed by Fu and Rich (1999). Then the temperature due to solar radiation was calculated using emissivity derived from ASTER data. The residual temperature, i.e. temperature due to solar radiation subtracted from ASTER temperature was used to identify thermally anomalous areas. Areas having anomalous temperature in the ASTER data are shown in blue diagonal hatch, while areas having anomalous temperature in the LANDSAT data are shown in magenta on the map. Thermal springs and areas with favorable geochemistry are also shown. Springs or wells having non-favorable geochemistry are shown as blue dots.

Areas with Surface Thermal Anomalies as Detected by ASTER and LANDSAT Data in Ouray, Colorado

DOE Data Explorer

Khalid Hussein

2012-02-01

This map shows areas of anomalous surface temperature in Ouray identified from ASTER and LANDSAT thermal data and spatial based insolation model. The temperature for the ASTER data was calculated using the Emissivity Normalization Algorithm that separate temperature from emissivity. The incoming solar radiation was calculated using spatial based insolation model developed by Fu and Rich (1999). Then the temperature due to solar radiation was calculated using emissivity derived from ASTER data. The residual temperature, i.e. temperature due to solar radiation subtracted from ASTER temperature was used to identify thermally anomalous areas. Areas having anomalous temperature in the ASTER data are shown in blue diagonal hatch, while areas having anomalous temperature in the LANDSAT data are shown in magenta on the map. Thermal springs and areas with favorable geochemistry are also shown. Springs or wells having non-favorable geochemistry are shown as blue dots.

Areas with Surface Thermal Anomalies as Detected by ASTER and LANDSAT Data in Southwest Steamboat Springs, Garfield County, Colorado

DOE Data Explorer

Khalid Hussein

2012-02-01

This map shows areas of anomalous surface temperature around south Steamboat Springs as identified from ASTER and LANDSAT thermal data and spatial based insolation model. The temperature for the ASTER data was calculated using the Emissivity Normalization Algorithm that separate temperature from emissivity. The incoming solar radiation was calculated using spatial based insolation model developed by Fu and Rich (1999). Then the temperature due to solar radiation was calculated using emissivity derived from ASTER data. The residual temperature, i.e. temperature due to solar radiation subtracted from ASTER temperature was used to identify thermally anomalous areas. Areas having anomalous temperature in the ASTER data are shown in blue diagonal hatch, while areas having anomalous temperature in the LANDSAT data are shown in magenta on the map. Thermal springs and areas with favorable geochemistry are also shown. Springs or wells having non-favorable geochemistry are shown as blue dots.

Areas with Surface Thermal Anomalies as Detected by ASTER and LANDSAT Data in Northern Saguache County, Colorado

DOE Data Explorer

Khalid Hussein

2012-02-01

This map shows areas of anomalous surface temperature in northern Saguache Counties identified from ASTER and LANDSAT thermal data and spatial based insolation model. The temperature for the ASTER data was calculated using the Emissivity Normalization Algorithm that separate temperature from emissivity. The incoming solar radiation was calculated using spatial based insolation model developed by Fu and Rich (1999). Then the temperature due to solar radiation was calculated using emissivity derived from ASTER data. The residual temperature, i.e. temperature due to solar radiation subtracted from ASTER temperature was used to identify thermally anomalous areas. Areas having anomalous temperature in the ASTER data are shown in blue diagonal hatch, while areas having anomalous temperature in the LANDSAT data are shown in magenta on the map. Thermal springs and areas with favorable geochemistry are also shown. Springs or wells having non-favorable geochemistry are shown as blue dots.

Geochemistry of lunar crustal rocks from breccia 67016 and the composition of the moon

NASA Technical Reports Server (NTRS)

Norman, Marc D.; Taylor, Stuart R.

1992-01-01

The geochemistry of anorthositic clasts from an Apollo 16 breccia 67016 is studied in order to investigate the role of these rock types in lunar crustal evolution. The samples have aluminous, alkali-poor compositions and varied FeO and MgO contents. Three compositional groups are recognized. One group is poor in mafic constituents with low abundances of lithophile trace elements typical of lunar anorthosites, while the other two groups are more mafic and are distinguished from each other by FeO/MgO ratios greater than one in the case of ferroan noritic and less than one in the case of magnesian troctolitic. These mafic-enriched varieties have considerably higher lithophile element concentrations, at levels similar to that of the bulk lunar crust. The ferroan noritic clasts may represent a fundamental type of igneous rock in the lunar crust which has not been widely recognized.

Geological controls on soil parent material geochemistry along a northern Manitoba-North Dakota transect

USGS Publications Warehouse

Klassen, R.A.

2009-01-01

As a pilot study for mapping the geochemistry of North American soils, samples were collected along two continental transects extending east–west from Virginia to California, and north–south from northern Manitoba to the US–Mexican border and subjected to geochemical and mineralogical analyses. For the northern Manitoba–North Dakota segment of the north–south transect, X-ray diffraction analysis and bivariate relations indicate that geochemical properties of soil parent materials may be interpreted in terms of minerals derived from Shield and clastic sedimentary bedrock, and carbonate sedimentary bedrock terranes. The elements Cu, Zn, Ni, Cr and Ti occur primarily in silicate minerals decomposed by aqua regia, likely phyllosilicates, that preferentially concentrate in clay-sized fractions; Cr and Ti also occur in minerals decomposed only by stronger acid. Physical glacial processes affecting the distribution and concentration of carbonate minerals are significant controls on the variation of trace metal background concentrations.

Geochemistry of water in the Fort Union Formation of the northern Powder River basin, southeastern Montana

USGS Publications Warehouse

Lee, Roger W.

1980-01-01

Shallow water in the coal-bearing Fort Union Formation of southeastern Montana was investigated to provide a better understanding of the geochemistry. Springs, wells less than 200 feet deep, and wells greater then 200 feet deep were observed to have different water qualities. Overall, the ground water exists as two systems: a mosaic of shallow, chemically dynamic, and localized recharge-discharge cells superimposed on a deeper, chemically static regional system. Water chemistry is highly variable in the shallow system, whereas sodium and bicarbonate waters characterize the deeper system. Within the shallow system , springs, and wells less than 200 feet deep show predominantly sodium and sulfate enrichment processes from recharge to discharge. These processes are consistent with the observed aquifer mineralogy and aqueous chemistry. However, intermittent mixing with downward moving recharge waters or upward moving deeper waters, and bacterially catalyzed sulfate reduction, may cause apparent reversals in these processes. (USGS)

Geochemistry of water in the Fort Union formation of the northern Powder River basin, southeastern Montana

USGS Publications Warehouse

Lee, Roger W.

1981-01-01

Shallow water in the coal-bearing Paleocene Fort Union Formation of southeastern Montana was investigated to provide a better understanding of its geochemistry. Springs, wells less than 200 feet deep, and wells greater than 200 feet deep were observed to have different water qualities. Overall, the ground water exists as two systems: a mosaic of shallow, chemically dynamic, and localized recharge-discharge cells superimposed on a deeper, chemically static regional system. Water chemistry is highly variable in the shallow system; whereas, waters containing sodium and bicarbonate characterize the deeper system. Within the shallow system, springs and wells less than 200 feet deep show predominantly sodium and sulfate enrichment processes from recharge to discharge. These processes are consistent with the observed aquifer mineralogy and aqueous chemistry. However, intermittent mixing with downward moving recharge waters or upward moving deeper waters, and bacterially catalyzed sulfate reduction, may cause apparent reversals in these processes.

Distribution and Geochemistry of Rare-Earth Elements in Rivers of Southern and Eastern Primorye (Far East of Russia)

NASA Astrophysics Data System (ADS)

Chudaev, O. V.; Bragin, I. V.; A, Kharitonova N.; Chelnokov, G. A.

2016-03-01

The distribution and geochemistry of rare earth elements (REE) in anthropogenic, technogenic and natural surface waters of southern and eastern Primorye, Far East of Russia, are presented in this study. The obtained results indicated that most of REE (up to 70%) were transported as suspended matter, ratio between dissolved and suspended forms varing from the source to the mouth of rivers. It is shown that all REE (except Ce) in the source of the rivers are predominantly presented in dissolved form, however, the content of light and heavy REE is different. Short-term enrichment of light rare earth elements (LREE) caused by REE-rich runoff from waste dumps and mining is neutralized by the increase in river flow rate. Rivers in urban areas are characterized by high content of LREE in dissolved form and very low in suspended one.

Bacterial Diversity and Biogeochemistry of Two Marine Shallow-Water Hydrothermal Systems off Dominica (Lesser Antilles).

PubMed

Pop Ristova, Petra; Pichler, Thomas; Friedrich, Michael W; Bühring, Solveig I

2017-01-01

Shallow-water hydrothermal systems represent extreme environments with unique biogeochemistry and high biological productivity, at which autotrophic microorganisms use both light and chemical energy for the production of biomass. Microbial communities of these ecosystems are metabolically diverse and possess the capacity to transform a large range of chemical compounds. Yet, little is known about their diversity or factors shaping their structure or how they compare to coastal sediments not impacted by hydrothermalism. To this end, we have used automated ribosomal intergenic spacer analysis (ARISA) and high-throughput Illumina sequencing combined with porewater geochemical analysis to investigate microbial communities along geochemical gradients in two shallow-water hydrothermal systems off the island of Dominica (Lesser Antilles). At both sites, venting of hydrothermal fluids substantially altered the porewater geochemistry by enriching it with silica, iron and dissolved inorganic carbon, resulting in island-like habitats with distinct biogeochemistry. The magnitude of fluid flow and difference in sediment grain size, which impedes mixing of the fluids with seawater, were correlated with the observed differences in the porewater geochemistry between the two sites. Concomitantly, individual sites harbored microbial communities with a significantly different community structure. These differences could be statistically linked to variations in the porewater geochemistry and the hydrothermal fluids. The two shallow-water hydrothermal systems of Dominica harbored bacterial communities with high taxonomical and metabolic diversity, predominated by heterotrophic microorganisms associated with the Gammaproteobacterial genera Pseudomonas and Pseudoalteromonas , indicating the importance of heterotrophic processes. Overall, this study shows that shallow-water hydrothermal systems contribute substantially to the biogeochemical heterogeneity and bacterial diversity of coastal sediments.

Statistical geochemistry reveals disruption in secular lithospheric evolution about 2.5 Gyr ago.

PubMed

Keller, C Brenhin; Schoene, Blair

2012-05-23

The Earth has cooled over the past 4.5 billion years (Gyr) as a result of surface heat loss and declining radiogenic heat production. Igneous geochemistry has been used to understand how changing heat flux influenced Archaean geodynamics, but records of systematic geochemical evolution are complicated by heterogeneity of the rock record and uncertainties regarding selection and preservation bias. Here we apply statistical sampling techniques to a geochemical database of about 70,000 samples from the continental igneous rock record to produce a comprehensive record of secular geochemical evolution throughout Earth history. Consistent with secular mantle cooling, compatible and incompatible elements in basalts record gradually decreasing mantle melt fraction through time. Superimposed on this gradual evolution is a pervasive geochemical discontinuity occurring about 2.5 Gyr ago, involving substantial decreases in mantle melt fraction in basalts, and in indicators of deep crustal melting and fractionation, such as Na/K, Eu/Eu* (europium anomaly) and La/Yb ratios in felsic rocks. Along with an increase in preserved crustal thickness across the Archaean/Proterozoic boundary, these data are consistent with a model in which high-degree Archaean mantle melting produced a thick, mafic lower crust and consequent deep crustal delamination and melting--leading to abundant tonalite-trondhjemite-granodiorite magmatism and a thin preserved Archaean crust. The coincidence of the observed changes in geochemistry and crustal thickness with stepwise atmospheric oxidation at the end of the Archaean eon provides a significant temporal link between deep Earth geochemical processes and the rise of atmospheric oxygen on the Earth.

Biogeographic congruency among bacterial communities from terrestrial sulfidic springs

PubMed Central

Headd, Brendan; Engel, Annette S.

2014-01-01

Terrestrial sulfidic springs support diverse microbial communities by serving as stable conduits for geochemically diverse and nutrient-rich subsurface waters. Microorganisms that colonize terrestrial springs likely originate from groundwater, but may also be sourced from the surface. As such, the biogeographic distribution of microbial communities inhabiting sulfidic springs should be controlled by a combination of spring geochemistry and surface and subsurface transport mechanisms, and not necessarily geographic proximity to other springs. We examined the bacterial diversity of seven springs to test the hypothesis that occurrence of taxonomically similar microbes, important to the sulfur cycle, at each spring is controlled by geochemistry. Complementary Sanger sequencing and 454 pyrosequencing of 16S rRNA genes retrieved five proteobacterial classes, and Bacteroidetes, Chlorobi, Chloroflexi, and Firmicutes phyla from all springs, which suggested the potential for a core sulfidic spring microbiome. Among the putative sulfide-oxidizing groups (Epsilonproteobacteria and Gammaproteobacteria), up to 83% of the sequences from geochemically similar springs clustered together. Abundant populations of Hydrogenimonas-like or Sulfurovum-like spp. (Epsilonproteobacteria) occurred with abundant Thiothrix and Thiofaba spp. (Gammaproteobacteria), but Arcobacter-like and Sulfurimonas spp. (Epsilonproteobacteria) occurred with less abundant gammaproteobacterial populations. These distribution patterns confirmed that geochemistry rather than biogeography regulates bacterial dominance at each spring. Potential biogeographic controls were related to paleogeologic sedimentation patterns that could control long-term microbial transport mechanisms that link surface and subsurface environments. Knowing the composition of a core sulfidic spring microbial community could provide a way to monitor diversity changes if a system is threatened by anthropogenic processes or climate change. PMID:25250021

Patterns and variability in geochemical signatures and microbial activity within and between diverse cold seep habitats along the lower continental slope, Northern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Bowles, Marshall; Hunter, Kimberley S.; Samarkin, Vladimir; Joye, Samantha

2016-07-01

We collected 69 sediment cores from distinct ecological and geological settings along the deep slope in the Northern Gulf of Mexico to evaluate whether specific geochemical- or habitat-related factors correlated with rates of microbial processes and geochemical signatures. By collecting replicate cores from distinct habitats across multiple sites, we illustrate and quantify the heterogeneity of cold seep geochemistry and microbial activity. These data also document the factors driving unique aspects of the geochemistry of deep slope gas, oil and brine seeps. Surprisingly little variation was observed between replicate (n=2-5) cores within sites for most analytes (except methane), implying that the common practice of collecting one core for geochemical analysis can capture the signature of a habitat in most cases. Depth-integrated concentrations of methane, dissolved inorganic carbon (DIC), and calcium were the predominant geochemical factors that correlated with a site's ecological or geological settings. Pore fluid methane concentration was related to the phosphate and DIC concentration, as well as to rates of sulfate reduction. While distinctions between seep habitats were identified from geochemical signatures, habitat specific geochemistry varied little across sites. The relative concentration of dissolved inorganic nitrogen versus phosphorus suggests that phosphorus availability limits biomass production at cold seeps. Correlations between calcium, chloride, and phosphate concentrations were indicative of brine-associated phosphate transport, suggesting that in addition to the co-migration of methane, dissolved organic carbon, and ammonium with brine, phosphate delivery is also associated with brine advection.

Geochemistry and origin of metamorphosed mafic rocks from the Lower Paleozoic Moretown and Cram Hill Formations of North-Central Vermont: Delamination magmatism in the western New England appalachians

USGS Publications Warehouse

Coish, Raymond; Kim, Jonathan; Twelker, Evan; Zolkos, Scott P.; Walsh, Gregory J.

2015-01-01

The Moretown Formation, exposed as a north-trending unit that extends from northern Vermont to Connecticut, is located along a critical Appalachian litho-tectonic zone between the paleomargin of Laurentia and accreted oceanic terranes. Remnants of magmatic activity, in part preserved as metamorphosed mafic rocks in the Moretown Formation and the overlying Cram Hill Formation, are a key to further understanding the tectonic history of the northern Appalachians. Field relationships suggest that the metamorphosed mafic rocks might have formed during and after Taconian deformation, which occurred at ca. 470 to 460 Ma. Geochemistry indicates that the sampled metamorphosed mafic rocks were mostly basalts or basaltic andesites. The rocks have moderate TiO2 contents (1–2.5 wt %), are slightly enriched in the light-rare earth elements relative to the heavy rare earths, and have negative Nb-Ta anomalies in MORB-normalized extended rare earth element diagrams. Their chemistry is similar to compositions of basalts from western Pacific extensional basins near volcanic arcs. The metamorphosed mafic rocks of this study are similar in chemistry to both the pre-Silurian Mount Norris Intrusive Suite of northern Vermont, and also to some of Late Silurian rocks within the Lake Memphremagog Intrusive Suite, particularly the Comerford Intrusive Complex of Vermont and New Hampshire. Both suites may be represented among the samples of this study. The geochemistry of all samples indicates that parental magmas were generated in supra-subduction extensional environments during lithospheric delamination.

Benthic foraminiferal micro-ecology and the geochemical environments they sample

NASA Astrophysics Data System (ADS)

Jacobsen, Brittani; Loubere, Paul; Yavorska, Iryna; Klitgaard-Kristensen, Dorthe; Jernas, Patrycja

2010-05-01

Benthic foraminifera inhabit, and are adapted to, microenvironments ranging from within the water column to centimeters into the sediments. These influence the geochemistry of the foraminiferal shell, and the paleoceanographic tracers we extract from that geochemistry. For a number of proxies it is important to know what geochemical environments the foraminifera are calcifying in, and whether species are consistent in the habitats they select for calcification. We examine these issues by sampling pore water chemistry and living species distributions on the microscale that the foraminifera themselves experience. We maintained cores from the Norwegian margin under in-situ conditions while measuring oxygen microprofiles and small scale sampling for foraminifera using rose Bengal and cell tracker green staining. In addition we sampled cores for porosity and pore water carbon isotopes using two extraction techniques so as to measure isotope profiles and degree of sediment irrigation via infaunal structures. The primary forcing variable we examined was changing labile organic carbon flux to the seabed. Under moderate to higher fluxes we found evidence for extensive bio-irrigation which influenced the composition of pore waters and microhabitats available to foraminifera. Macro-meiofaunal burrows and tubes produced a mosaic of pore water geochemical conditions rather than smooth gradients from the sediment-water interface. We found species adapted to particular conditions living at various subsurface depths, where their preferred conditions existed. We also found evidence that foraminiferal species responded to larger organism activities (feeding activities) and products (fecal deposits). It appears that taxa select for particular conditions rather than simply living at specific subsurface depths, recording whatever geochemistry happens to exist at that level.

Peat characteristics and groundwater geochemistry of calcareous fens in the Minnesota River Basin, U.S.A

USGS Publications Warehouse

Almendinger, J.E.; Leete, J.H.

1998-01-01

. Calcareous fens in Minnesota are spring-seepage peatlands with a distinctive flora of rare calciphilic species. Peat characteristics and groundwater geochemistry were determined for six calcareous fens in the Minnesota River Basin to better understand the physical structure and chemical processes associated with stands of rare vegetation. Onset of peat accumulation in three of the fens ranged from about 4,700 to 11,000 14C yrs BP and probably resulted from a combination of climate change and local hydrogeologic conditions. Most peat cores had a carbonate-bearing surface zone with greater than 10% carbonates (average 27%, dry wt basis), an underlying carbonate-depleted zone with 10% or less carbonates (average 4%), and a carbonate-bearing lower zone again with greater than 10% carbonates (average 42%). This carbonate zonation was hypothesized to result from the effect of water-table level on carbonate equilibria: carbonate precipitation occurs when the water table is above a critical level, and carbonate dissolution occurs when the water table is lower. Other processes that changed the major ion concentrations in upwelling groundwater include dilution by rain water, sulfate reduction or sulfide oxidation, and ion adsorption or exchange. Geochemical modeling indicated that average shallow water in the calcareous fens during the study period was groundwater mixed with about 6 to 13% rain water. Carbonate precipitation in the surface zone of calcareous fens could be decreased by a number of human activities, especially those that lower the water table. Such changes in shallow water geochemistry could alter the growing conditions that apparently sustain rare fen vegetation.

Anthropophile elements in river sediments: Overview from the Seine River, France

NASA Astrophysics Data System (ADS)

Chen, Jiu-Bin; Gaillardet, Jérôme; Bouchez, Julien; Louvat, Pascale; Wang, Yi-Na

2014-11-01

In contrast to larger river systems that drain relatively pristine basins, little is known about the sediment geochemistry of rivers impacted by intense human activities. In this paper, we present a systematic investigation of the anthropogenic overprints on element geochemistry in sediments of the human-impacted Seine River, France. Most elements are fractionated by grain size, as shown by the comparison between suspended particulate matter (SPM) and riverbank deposits (RBD). The RBD are particularly coarse and enriched in carbonates and heavy minerals and thus in elements such as Ba, Ca, Cr, Hf, Mg, Na, REEs, Sr, Ti, Th, and Zr. Although the enrichment/depletion pattern of some elements (e.g., K, REEs, and Zr) can largely be explained by a binary mixture between two sources, other elements such as Ag, Bi, Cr, Cd, Co, Cu, Fe, Mo, Ni, Pb, Sb, Sn, W, and Zn in SPM in Paris show that a third end-member having anthropogenic characteristics is needed to account for their enrichment at low water stage. These "anthropophile" elements, with high enrichment factors (EFs) relative to the upper continental crust (UCC), display a progressive enrichment downstream and different geochemical behaviors with respect to the hydrodynamic conditions (e.g., grain size) compared to elements having mainly a natural origin. Our findings emphasize the need for systematic studies of these anthropophile elements in other human-impacted rivers using geochemical normalization techniques, and stress the importance of studying the chemical variability associated with hydrodynamic conditions when characterizing riverine element geochemistry and assessing their flux to the ocean.

Major, trace and REE geochemistry of recent sediments from lower Catumbela River (Angola)

NASA Astrophysics Data System (ADS)

Vinha, Manuela; Silva, M. G.; Cabral Pinto, Marina M. S.; Carvalho, Paula Cristina S.

2016-03-01

The mineralogy, texture, major, trace and rare earth elements, from recent sediment samples collected in the lower Catumbela River, were analysed in this study to characterize and discuss the factors controlling its geochemistry and provide data that can be used as tracers of Catumbela River inputs to the Angolan continental shelf. The sediments are mainly sands and silty-sands, but sandy-silt also occurs and the mineralogy is composed of quartz, feldspar, phyllosilicates, magnetite, ilmenite and also carbonates when the river crosses limestones and marls in the downstream sector. The hydraulic sorting originates magnetite-ilmenite and REE-enriched minerals placers. The mineralogy of the sediments is controlled by the source rocks and the degree of chemical weathering is lower than erosion. The texture is mainly controlled by location. There is enrichment in all the analysed trace elements in the fine grained, clay minerals and Fe-oxy-hydroxides rich sediments, compared to the coarse grained and quartz plus feldspar rich ones. The coarse grained sediments (without the placers) are impoverished in ΣREE when compared with UCC and NASC compositions, while the fine grained sediments have ΣREE contents similar to UCC and NASC. The placers have ΣREE contents up to 959.59 mg/kg. The source composition is the dominant factor controlling the REE geochemistry of the analysed sediments as there is no difference in the (La/Yb)N, (La/Sm)N and (Gd/Yb)N ratios in coarse and fine grained sediments. The sorting of magnetite, ilmenite, zircon, throrite, thorianite, rutile and titanite explain the HREE/LREE enriched patterns of the coarse grained sediments.

Geology and geochemistry of the Atacama Desert.

PubMed

Tapia, J; González, R; Townley, B; Oliveros, V; Álvarez, F; Aguilar, G; Menzies, A; Calderón, M

2018-02-14

The Atacama Desert, the driest of its kind on Earth, hosts a number of unique geological and geochemical features that make it unlike any other environment on the planet. Considering its location on the western border of South America, between 17 and 28 °S, its climate has been characterized as arid to hyperarid for at least the past 10 million years. Notably dry climatic conditions of the Atacama Desert have been related to uplift of the Andes and are believed to have played an important role in the development of the most distinctive features of this desert, including: (i) nitrates and iodine deposits in the Central Depression, (ii) secondary enrichment in porphyry copper deposits in the Precordillera, (iii) Li enrichment in salt flats of the Altiplano, and (iv) life in extreme habitats. The geology and physiography of the Atacama Desert have been largely shaped by the convergent margin present since the Mesozoic era. The geochemistry of surface materials is related to rock geochemistry (Co, Cr, Fe, Mn, V, and Zn), salt flats, and evaporite compositions in endorheic basins (As, B, and Li), in addition to anthropogenic activities (Cu, Mo, and Pb). The composition of surface water is highly variable, nonetheless in general it presents a circumneutral pH with higher conductivity and total dissolved solids in brines. Major water constituents, with the exception of HCO 3 - , are generally related to the increase of salinity, and despite the fact that trace elements are not well-documented, surface waters of the Atacama Desert are enriched in As, B, and Li when compared to the average respective concentrations in rivers worldwide.

Geochemistry of extremely alkaline (pH>12) ground water in slag-fill aquifers.

PubMed

Roadcap, George S; Kelly, Walton R; Bethke, Craig M

2005-01-01

Extremely alkaline ground water has been found underneath many shuttered steel mills and slag dumps and has been an impediment to the cleanup and economic redevelopment of these sites because little is known about the geochemistry. A large number of these sites occur in the Lake Calumet region of Chicago, Illinois, where large-scale infilling of the wetlands with steel slag has created an aquifer with pH values as high as 12.8. To understand the geochemistry of the alkaline ground water system, we analyzed samples of ground water and the associated slag and weathering products from four sites. We also considered several potential remediation schemes to lower the pH and toxicity of the water. The principal cause of the alkaline conditions is the weathering of calcium silicates within the slag. The resulting ground water at most of the sites is dominated by Ca2+ and OH- in equilibrium with Ca(OH)2. Where the alkaline ground water discharges in springs, atmospheric CO2 dissolves into the water and thick layers of calcite form. Iron, manganese, and other metals in the metallic portion of the slag have corroded to form more stable low-temperature oxides and sulfides and have not accumulated in large concentrations in the ground water. Calcite precipitated at the springs is rich in a number of heavy metals, suggesting that metals can move through the system as particulate matter. Air sparging appears to be an effective remediation strategy for reducing the toxicity of discharging alkaline water.

The impact of fire on the geochemistry of speleothem-forming drip water in a sub-alpine cave.

PubMed

Coleborn, Katie; Baker, Andy; Treble, Pauline C; Andersen, Martin S; Baker, Andrew; Tadros, Carol V; Tozer, Mark; Fairchild, Ian J; Spate, Andy; Meehan, Sophia

2018-06-12

Fire dramatically modifies the surface environment by combusting vegetation and changing soil properties. Despite this well-documented impact on the surface environment, there has been limited research into the impact of fire events on karst, caves and speleothems. Here we report the first experiment designed to investigate the short-term impacts of a prescribed fire on speleothem-forming cave drip water geochemistry. Before and after the fire, water was collected on a bi-monthly basis from 18 drip sites in South Glory Cave, New South Wales, Australia. Two months post-fire, there was an increase in B, Si, Na, Fe and Pb concentrations at all drip sites. We conclude that this response is most likely due to the transport of soluble ash-derived elements from the surface to the cave drip water below. A significant deviation in stable water isotopic composition from the local meteoric water line was also observed at six of the sites. We hypothesise that this was due to partial evaporation of soil water resulting in isotopic enrichment of drip waters. Our results demonstrate that even low-severity prescribed fires can have an impact on speleothem-forming cave drip water geochemistry. These findings are significant because firstly, fires need to be considered when interpreting past climate from speleothem δ 18 O isotope and trace element records, particularly in fire prone regions such as Australia, North America, south west Europe, Russia and China. Secondly, it supports research that demonstrates speleothems could be potential proxy records for past fires. Copyright © 2017 Elsevier B.V. All rights reserved.

Bacterial Diversity and Biogeochemistry of Two Marine Shallow-Water Hydrothermal Systems off Dominica (Lesser Antilles)

PubMed Central

Pop Ristova, Petra; Pichler, Thomas; Friedrich, Michael W.; Bühring, Solveig I.

2017-01-01

Shallow-water hydrothermal systems represent extreme environments with unique biogeochemistry and high biological productivity, at which autotrophic microorganisms use both light and chemical energy for the production of biomass. Microbial communities of these ecosystems are metabolically diverse and possess the capacity to transform a large range of chemical compounds. Yet, little is known about their diversity or factors shaping their structure or how they compare to coastal sediments not impacted by hydrothermalism. To this end, we have used automated ribosomal intergenic spacer analysis (ARISA) and high-throughput Illumina sequencing combined with porewater geochemical analysis to investigate microbial communities along geochemical gradients in two shallow-water hydrothermal systems off the island of Dominica (Lesser Antilles). At both sites, venting of hydrothermal fluids substantially altered the porewater geochemistry by enriching it with silica, iron and dissolved inorganic carbon, resulting in island-like habitats with distinct biogeochemistry. The magnitude of fluid flow and difference in sediment grain size, which impedes mixing of the fluids with seawater, were correlated with the observed differences in the porewater geochemistry between the two sites. Concomitantly, individual sites harbored microbial communities with a significantly different community structure. These differences could be statistically linked to variations in the porewater geochemistry and the hydrothermal fluids. The two shallow-water hydrothermal systems of Dominica harbored bacterial communities with high taxonomical and metabolic diversity, predominated by heterotrophic microorganisms associated with the Gammaproteobacterial genera Pseudomonas and Pseudoalteromonas, indicating the importance of heterotrophic processes. Overall, this study shows that shallow-water hydrothermal systems contribute substantially to the biogeochemical heterogeneity and bacterial diversity of coastal sediments. PMID:29255454

METALS IN GROUND WATER: SAMPLING ARTIFACTS AND REPRODUCIBILITY

EPA Science Inventory

Field studies evaluated sampling procedures for determination of aqueous inorganic geochemistry and assessment of contaminant transport by colloidal mobility. esearch at three different metal-contaminated sites has shown that 0.45 tm filtration has not removed potentially mobile ...

Chemistry on Stamps.

ERIC Educational Resources Information Center

Schreck, James O.

1986-01-01

Suggests how postage stamps can be incorporated into chemistry teaching. Categories considered include emergence of chemistry as a science, metric system, atoms (and molecules and ions), stoichiometry, energy relationships in chemical systems, chemical bonding, nuclear chemistry, biochemistry, geochemistry, matter (gases, liquids, and solids),…

Workshop on Early Crustal Genesis: The World's Oldest Rocks

NASA Technical Reports Server (NTRS)

Ashwal, L. D. (Editor)

1986-01-01

Topics addressed include: a general review of Precambrain crustal evolution; geology and geochemistry of the Archean Craton in Greenland and Labrador; Precambrian crustal evolution in North and South America; and the field excursion to the Ameralik Fjord.

EFFECT OF BACTERIAL SULFATE REDUCTION ON IRON-CORROSION SCALES

EPA Science Inventory

Iron-sulfur geochemistry is important in many natural and engineered environments including drinking water systems. In the anaerobic environment beneath scales of corroding iron drinking water distribution system pipes, sulfate reducing bacteria (SRB) produce sulfide from natura...

Publications - RDF 2011-4 v. 2 | Alaska Division of Geological &

Science.gov Websites

://doi.org/10.14509/23002 Publication Products Report Report Information rdf2011_004.pdf (519.0 K) Digital Geospatial Data Digital Geospatial Data Moran Geochemistry Data File Format File Size Info Download moran

Special Issue on Earth Science: The View From '76

ERIC Educational Resources Information Center

Geotimes, 1976

1976-01-01

Presents the latest developments concerning the following topics: astrogeology, coal, deep sea drilling project, engineering geology; environmental geology, exploration geophysics, geochemistry, geodynamics project, hydrology, industrial minerals, international geology, mapping, mathematical geology, metals, mineralogy, oil and gas, invertebrate…

Determination of Uncertainties for +III and +IV Actinide Solubilities in the WIPP Geochemistry Model for the 2009 Compliance Recertification Application

NASA Astrophysics Data System (ADS)

Ismail, A. E.; Xiong, Y.; Nowak, E. J.; Brush, L. H.

2009-12-01

The Waste Isolation Pilot Plant (WIPP) is a U.S. Department of Energy (DOE) repository in southeast New Mexico for defense-related transuranic (TRU) waste. Every five years, the DOE is required to submit an application to the Environmental Protection Agency (EPA) demonstrating the WIPP’s continuing compliance with the applicable EPA regulations governing the repository. Part of this recertification effort involves a performance assessment—a probabilistic evaluation of the repository performance with respect to regulatory limits on the amount of releases from the repository to the accessible environment. One of the models used as part of the performance assessment process is a geochemistry model, which predicts solubilities of the radionuclides in the brines that may enter the repository in the different scenarios considered by the performance assessment. The dissolved actinide source term comprises actinide solubilities, which are input parameters for modeling the transport of radionuclides as a result of brine flow through and from the repository. During a performance assessment, the solubilities are modeled as the product of a “base” solubility determined from calculations based on the chemical conditions expected in the repository, and an uncertainty factor that describes the potential deviations of the model from expected behavior. We will focus here on a discussion of the uncertainties. To compute a cumulative distribution function (CDF) for the uncertainties, we compare published, experimentally measured solubility data to predictions made using the established WIPP geochemistry model. The differences between the solubilities observed for a given experiment and the calculated solubilities from the model are used to form the overall CDF, which is then sampled as part of the performance assessment. We will discuss the methodology used to update the CDF’s for the +III actinides, obtained from data for Nd, Am, and Cm, and the +IV actinides, obtained from data for Th, and present results for the calculations of the updated CDF’s. We compare the CDF’s to the distributions computed for the previous recertification, and discuss the potential impact of the changes on the geochemistry model. This research is funded by WIPP programs administered by the U.S. Department of Energy. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000.

Catalog of Mount St. Helens 2004-2007 Dome Samples with Major- and Trace-Element Chemistry

USGS Publications Warehouse

Thornber, Carl R.; Pallister, John S.; Rowe, Michael C.; McConnell, Siobhan; Herriott, Trystan M.; Eckberg, Alison; Stokes, Winston C.; Cornelius, Diane Johnson; Conrey, Richard M.; Hannah, Tammy; Taggart, Joseph E.; Adams, Monique; Lamothe, Paul J.; Budahn, James R.; Knaack, Charles M.

2008-01-01

Sampling and analysis of eruptive products at Mount St. Helens is an integral part of volcano monitoring efforts conducted by the U.S. Geological Survey?s Cascades Volcano Observatory (CVO). The objective of our eruption sampling program is to enable petrological assessments of pre-eruptive magmatic conditions, critical for ascertaining mechanisms for eruption triggering and forecasting potential changes in eruption behavior. This report provides a catalog of near-vent lithic debris and new dome-lava collected during 34 intra-crater sampling forays throughout the October 2004 to October 2007 (2004?7) eruptive interval at Mount St. Helens. In addition, we present comprehensive bulk-rock geochemistry for a time-series of representative (2004?7) eruption products. This data, along with that in a companion report on Mount St. Helens 2004 to 2006 tephra by Rowe and others (2008), are presented in support of the contents of the U.S. Geological Survey Professional Paper 1750 (Sherrod and others, eds., 2008). Readers are referred to appropriate chapters in USGS Professional Paper 1750 for detailed narratives of eruptive activity during this time period and for interpretations of sample characteristics and geochemical data. The suite of rock samples related to the 2004?7 eruption of Mount St. Helens and presented in this catalog are archived at the David A. Johnson Cascades Volcano Observatory, Vancouver, Wash. The Mount St. Helens 2004?7 Dome Sample Catalogue with major- and trace-element geochemistry is tabulated in 3 worksheets of the accompanying Microsoft Excel file, of2008-1130.xls. Table 1 provides location and sampling information. Table 2 presents sample descriptions. In table 3, bulk-rock major and trace-element geochemistry is listed for 44 eruption-related samples with intra-laboratory replicate analyses of 19 dacite lava samples. A brief overview of the collection methods and lithology of dome samples is given below as an aid to deciphering the dome sample catalog. This is followed by an explanation of the categories of sample information (column headers) in Tables 1 and 2. A summary of the analytical methods used to obtain the geochemical data in this report introduces the presentation of major- and trace-element geochemistry of 2004?7 Mount St. Helens dome samples in table 3. Intra-laboratory results for the USGS AGV-2 standard are presented (tables 4 and 5), which demonstrate the compatibility of chemical data from different sources.

Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bacon, Diana H.

2013-03-31

The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. Thismore » report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite sorption sites proving to be of secondary importance. The Groundwater Geochemistry ROM was developed using nonlinear regression to fit the response surface with a quadratic polynomial. The goodness of fit was excellent for the CO2 flux to the atmosphere, and very good for predicting the volumes of groundwater exceeding the pH, TDS, As, Cd and Pb threshold values.« less

Lake Qinghai sediment geochemistry linked to hydroclimate variability since the last glacial

NASA Astrophysics Data System (ADS)

Jin, Zhangdong; An, Zhisheng; Yu, Jimin; Li, Fuchun; Zhang, Fei

2015-08-01

Geochemistry of basin sediments from semi-arid regions is valuable to understand past hydroclimatic changes. Here, we investigate the links of sedimentary geochemistry (Rb, Sr, Ca/Zr, TOC, and %CaCO3), carbonate mineralogy and ostracod shell δ18O of Lake Qinghai, a basin proximal to major dust production centers at mid-latitudes of the Northern Hemisphere, to changes in depositional conditions and hydroclimate during the past 32 ka. Surface lacustrine sediments are characterized by low-Rb, high-Sr, low-Rb/Sr, high-%CaCO3 and high-Ca/Zr values, in contrast to the chemical compositions of eolian loess (high-Rb, low-Sr, high-Rb/Sr, low-%CaCO3, and low-Ca/Zr). A direct comparison of soluble Ca and Sr in two short cores with instrumental water discharge data suggests that lacustrine precipitates in Lake Qinghai are dominated by authigenic aragonite formed under Ca2+-limited water conditions, and that the accumulation rate of aragonite dominantly depends on solute fluxes into the lake during the rainy seasons (late May to September). Our high-resolution down-core records show that sediments during the last glacial (∼32-19.8 ka) had high-Rb, low-Sr, low-%CaCO3, and low-Ca/Zr, indicating eolian dust (loess) accumulation in a desiccated basin under dry glacial conditions, further supported by grain size and pollen results. This type of sedimentation was maintained during the last deglacial (∼19.8-11.5 ka), but interrupted by episodic lacustrine precipitates with high-Sr, high-%CaCO3, high-Ca/Zr, and low-Rb. At ∼11.5 ka, sedimentary Rb/Sr, Ca/Zr, %CaCO3 and TOC show dramatic and permanent changes, implying an abrupt shift in the atmospheric circulation at the onset of the Holocene in the Lake Qinghai region. Lacustrine precipitates have persisted throughout the Holocene with a maximum during the early to mid-Holocene (∼10.5-8.0 ka). Since ∼8.0 ka, the gradual and significant decreases in aragonite and Sr accumulations in tandem with increasing dust deposit and more positive ostracod δ18O may be linked to a weakening of Asian summer monsoons during the mid-to-late Holocene. Overall, our records appear to show a high sensitivity of sediment development and geochemistry in Lake Qinghai to the regional hydroclimate changes since the last glacial.

Probing the volcanic-plutonic connection and the genesis of crystal-rich rhyolite in a deeply dissected supervolcano in the Nevada Great Basin: Source of the late Eocene Caetano Tuff

USGS Publications Warehouse

Watts, Kathryn E.; John, David A.; Colgan, Joseph P.; Henry, Christopher D.; Bindeman, Ilya N.; Schmitt, Axel K.

2016-01-01

Late Cenozoic faulting and large-magnitude extension in the Great Basin of the western USA has created locally deep windows into the upper crust, permitting direct study of volcanic and plutonic rocks within individual calderas. The Caetano caldera in north–central Nevada, formed during the mid-Tertiary ignimbrite flare-up, offers one of the best exposed and most complete records of caldera magmatism. Integrating whole-rock geochemistry, mineral chemistry, isotope geochemistry and geochronology with field studies and geologic mapping, we define the petrologic evolution of the magmatic system that sourced the >1100 km3Caetano Tuff. The intra-caldera Caetano Tuff is up to ∼5 km thick, composed of crystal-rich (30–45 vol. %), high-silica rhyolite, overlain by a smaller volume of comparably crystal-rich, low-silica rhyolite. It defies classification as either a monotonous intermediate or crystal-poor zoned rhyolite, as commonly ascribed to ignimbrite eruptions. Crystallization modeling based on the observed mineralogy and major and trace element geochemistry demonstrates that the compositional zonation can be explained by liquid–cumulate evolution in the Caetano Tuff magma chamber, with the more evolved lower Caetano Tuff consisting of extracted liquids that continued to crystallize and mix in the upper part of the chamber following segregation from a cumulate-rich, and more heterogeneous, source mush. The latter is represented in the caldera stratigraphy by the less evolved upper Caetano Tuff. Whole-rock major, trace and rare earth element geochemistry, modal mineralogy and mineral chemistry, O, Sr, Nd and Pb isotope geochemistry, sanidine Ar–Ar geochronology, and zircon U–Pb geochronology and trace element geochemistry provide robust evidence that the voluminous caldera intrusions (Carico Lake pluton and Redrock Canyon porphyry) are genetically equivalent to the least evolved Caetano Tuff and formed from magma that remained in the lower chamber after ignimbrite eruption and caldera collapse. Thus, the Caetano Tuff contradicts models for the mutually exclusive origins of voluminous volcanic and plutonic magmas in the upper crust. Crystal-scale O isotope data indicate that the Caetano Tuff is one of the most 18O-enriched rhyolites in the Great Basin (δ18Omagma = 10·2 ± 0·2‰), supporting anatexis of local metasedimentary basement crust. Metapelite xenoliths in the Carico Lake pluton and ubiquitous xenocrystic zircons in the Caetano Tuff provide constraints for the anatexis process; these data point to shallow (<15 km) dehydration melting of a protolith similar to the Proterozoic McCoy Creek Group siliciclastic sediments in eastern Nevada, projected beneath Caetano in fault-stacked shelf sediments that were thickened during Mesozoic crustal shortening. Mean zircon U–Pb ages for different stratigraphic levels of the intra-caldera Caetano Tuff are 34·2–34·5 Ma, 0·2–0·5 Myr older than the caldera sanidine 40Ar/39Ar age of 34·00 ± 0·03 Ma, documenting protracted duration of assembly and homogenization of isotopically diverse upper crustal melts, followed by crystallization and zonation to generate the Caetano Tuff magma chamber. Sanidine rims in the least evolved Caetano Tuff and in the Carico Lake pluton and Redrock Canyon porphyry have sharply zoned Ba domains that point to crystal growth during magmatic recharge events. The recharge magma is inferred to have been compositionally similar to the Caetano Tuff magma, with increased Ba resulting from remelting of Ba-rich sanidine cumulates. Mush reactivation to generate the Caetano Tuff eruption was sufficiently rapid to preserve compositional gradients in the intracaldera ignimbrite, calling into question models that predict homogeneity as a prerequisite for remobilizing crystal-rich ignimbrite magmas.

Chem I Supplement: The Geochemistry of Coal: I. The Classification and Origin of Coal.

ERIC Educational Resources Information Center

Schobert, Harold H.

1989-01-01

Discusses the composition and properties of various types of coal. Follows the origin of coal and amounts available in the ground. Explores the anaerobic decay needed to produce coal. Touches upon the greenhouse effect. (MVL)

10 CFR 960.4-2-2 - Geochemistry.

Code of Federal Regulations, 2013 CFR

2013-01-01

.... Considering the likely chemical interactions among radionuclides, the host rock, and the ground water, the... the rock matrix, or sorption of radionuclides; inhibit the formation of particulates, colloids... transport of radionuclides by particulates, colloids, or complexes. (3) Mineral assemblages that, when...

10 CFR 960.4-2-2 - Geochemistry.

Code of Federal Regulations, 2014 CFR

2014-01-01

.... Considering the likely chemical interactions among radionuclides, the host rock, and the ground water, the... the rock matrix, or sorption of radionuclides; inhibit the formation of particulates, colloids... transport of radionuclides by particulates, colloids, or complexes. (3) Mineral assemblages that, when...

Publications of the exobiology program for 1984: A special bibliography

NASA Technical Reports Server (NTRS)

Wallace, J. S. (Compiler); Devincenzi, D. L. (Compiler)

1986-01-01

A bibliography of NASA exobiology programs is given. Planetary environments; chemical evolution; organic geochemistry; extraterrestrial intelligence; and the effect of planetary solar and astrophysical phenomena on the evolution of complex life in the universe are among the topics listed.

Student Enrollment in Geoscience Departments. 1982-1983.

ERIC Educational Resources Information Center

American Geological Inst., Washington, DC.

Presented in table format are student enrollment data for geoscience disciplines at colleges and universities in the United States and Canada. Subfields for both countries include: geology; geophysics; oceanography; marine science; geological engineering; geophysical engineering; geochemistry; hydrology; mineralogy; paleontology; soil science;…

Trace Metal Geochemistry and Mobility in the Marcellus Shale

EPA Pesticide Factsheets

Drilling and “fracing” of the Marcellus shale causes fluid‐rock interactions that has the potential to mobilize metals naturally enriched in the shale. While these metal concentrations are low, their mobilization from the solid, is cause for further study

Sediment Microbial Community Dynamics and Geochemistry During Oxic and Hypoxic Periods in the Gulf of Mexico

EPA Science Inventory

Seasonal hypoxia in the benthic waters of the Louisiana Coastal Shelf contributes to the Gulf of Mexico "dead zone" phenomena. Limited information is available on sedimentary biogeochemical interactions during periods of hypoxia.

COLLOIDAL-FACILITATED TRANSPORT OF INORGANIC CONTAMINANTS IN GROUND WATER: PART I. SAMPLING CONSIDERATIONS

EPA Science Inventory

Investigations at Pinal Creek, Arizona, evaluated routine sampling procedures for determination of aqueous inorganic geochemistry and assessment of contaminant transport by colloidal mobility. Sampling variables included pump type and flow rate, collection under air or nitrogen,...

STUDIES OF INTERFACIAL REACTIONS BETWEEN ARSENIC AND MINERALS AND ITS SIGNIFICANCE TO SITE CHARACTERIZATION

EPA Science Inventory

Natural attenuation remediation is based on the intrinsic attenuation capacities of the subsurface. Geochemistry of the subsurface controls the fate, transport, transformation, and bioavailability of contaminants. This paper demonstrates that interfacial reactions (e.g., adsorp...

Reports of planetary geology program, 1979 - 1980. [bibliographies

NASA Technical Reports Server (NTRS)

Wirth, P.; Greeley, R.; Dalli, R.

1980-01-01

Abstracts of 145 reports are compiled addressing the morphology, geochemistry, and stratigraphy of planetary surfaces with some specific examinations of volcanic, aeolian, fluvial, and periglacial processes and landforms. In addition, reports on cartography and remote sensing of planet surfaces are included.

The Medical Geochemistry of Dusts, Soils, and Other Earth Materials

NASA Astrophysics Data System (ADS)

Plumlee, G. S.; Ziegler, T. L.

2003-12-01

"Town clenched in suffocating grip of asbestos"USA Today, article on Libby,Montana, February, 2000"Researchers find volcanoes are bad for your health… long after they finish erupting"University of WarwickPress Release, 1999"Toxic soils plague city - arsenic, lead in 5 neighborhoods could imperil 17,000 residents"Denver Post, 2002"Ill winds - dust storms ferry toxic agents between countries and even continents"Science News, 2002A quick scan of newspapers, television, science magazines, or the internet on any given day has a fairly high likelihood of encountering a story (usually accompanied by a creative headline such as those above) regarding human health concerns linked to dusts, soils, or other earth materials. Many such concerns have been recognized and studied for decades, but new concerns arise regularly.Earth scientists have played significant roles in helping the medical community understand some important links between earth materials and human health, such as the role of asbestos mineralogy in disease (Skinner et al., 1988; Ross, 1999; Holland and Smith, 2001), and the role of dusts generated by the 1994 Northridge, California, earthquake in an outbreak of Valley Fever ( Jibson et al., 1998; Schneider et al., 1997).Earth science activities tied to health issues are growing (Skinner and Berger, 2003), and are commonly classified under the emerging discipline of medical geology (Finkelman et al., 2001; Selinus and Frank, 2000; Selinus, in press).Medical geochemistry (also referred to as environmental geochemistry and health: Smith and Huyck (1999), Appleton et al. (1996)) can be considered as a diverse subdiscipline of medical geology that deals with human and animal health in the context of the Earth's geochemical cycle ( Figure 1). Many medical geochemistry studies have focused on how chemical elements in rocks, soils, and sediments are transmitted via water or vegetation into the food chain, and how regional geochemical variations can result in disease clusters either through dietary deficiency of essential elements or dietary excess of toxic elements. (28K)Figure 1. Potential human exposure routes within the earth's geochemical cycle can come from a wide variety of both natural and anthropogenic sources. This chapter focuses on a somewhat narrower area of medical geochemistry: the study of mechanisms of uptake of earth materials by humans and animals and their reactions to these materials. In order for earth materials to affect health, they must first interact with the body across key interfaces such as the respiratory tract, gastrointestinal tract, skin, and eyes. In some way, all of these interfaces require the earth materials to interact chemically with water-based body fluids such as lung fluids, gastrointestinal fluids, saliva, or blood plasma.The primary goal of this chapter, co-authored by a geochemist and a toxicologist, is to provide both geochemists and scientists from health disciplines with an overview of the potential geochemical mechanisms by which earth materials can influence human health. It is clear that significant opportunities for advancement in this arena will require continued and increased research collaborations between geochemists and their counterparts in the health disciplines.

Hydrogen generation during serpentinisation in ophiolite complexes: A comparison of H2-rich gases from Oman, Philippines and Turkey.

NASA Astrophysics Data System (ADS)

Beaumont, Valérie; Vacquand, Christèle; Deville, Eric; Prinzhofer, Alain

2013-04-01

H2-rich gas seepages in ultrabasic to basic contexts both in marine and continental environment are by-products of serpentinisation. Hydrothermal systems at MOR expose ultrabasic rocks to thermodynamic conditions favouring oxidation of FeII bearing minerals and water reduction. In continental context such thermodynamic conditions do not exist although active serpentinisation occurs in all known ophiolitic complexes (Barnes et al., 1978; Bruni et al., 2002; Cipolli et al., 2004; Boschetti and Toscani, 2008; Marques et al., 2008). Hyperalkaline springs are reported in these contexts as evidence of this active serpentinisation (Barnes et al., 1967) and are often associated with seepages of reduced gases (Neal and Stanger, 1983; Sano et al., 1993). Dry gas seepages are also observed (Abrajano et al., 1988, 1990; Hosgörmez, 2007; Etiope et al., 2011) Such H2-rich gases from ophiolite complexes were sampled in the Sultanate of Oman, the Philippines and Turkey and were analysed for chemical composition, noble gases contents, stable isotopes of carbon, hydrogen and nitrogen. The conditions for present-day serpentinisation in ophiolites were recognised as low temperature processes in Oman with high rock/water ratios (Neal and Stanger, 1985), while the origin of gases is not as univocal for Philippines and Turkey gas seepages. Although, H2 generation is directly linked with FeII oxidation, different reactions can occur during peridotite hydration (McCollom and Bach, 2009; Marcaillou et al., 2011) and serpentine weathering. Produced H2 can react with carbonate species to produce methane via processes that could be biological or abiotic, while carbon availability depends on water recharge chemistry. In the present study, the geochemical properties of gases sampled from three different ophiolite complexes are compared and provide evidence that weathering reactions producing H2 depend on structural, geological, geomorphologic and hydrological local features. REFERENCES Abrajano, T. A., et al. (1988). Chemical Geology, 71(1-3), 211-222. Abrajano, T. A, et al. (1990). Applied Geochemistry, 5(5-6), 625-630. Barnes, I., et al. (1967). Science (New York, N.Y.), 156(3776), 830-2. Barnes, I., et al. (1978). Geochimica et Cosmochimica Acta, 42(1), 144-145. Boschetti, T., & Toscani, L. (2008). Chemical Geology, 257(1-2), 76-91. Bruni, J., et al. (2002). Applied Geochemistry, 17, 455-474. Cipolli, F., et al. (2004). Applied Geochemistry, 19(5), 787-802. Etiope, G., et al. (2011). Earth and Planetary Science Letters, 310(1-2), 96-104. Hosgörmez, H. (2007). Journal of Asian Earth Sciences, 30(1), 131-141. Marcaillou, C., et al. (2011). Earth and Planetary Science Letters, 303(3-4), 281-290. Marques, J. M., et al. (2008). Applied Geochemistry, 23(12), 3278-3289. McCollom, T. M. & Bach, W. (2009). Geochimica et Cosmochimica Acta, 73(3), 856-875. Neal, C. & Stanger, G. (1983). Earth and Planetary Science Letters, 66(66), 315-320. Neal, C. & Stanger, G. (1985). In J. I. Dever (Ed.), The Chemistry of Weathering (pp. 249-275). D. Reidel Publishing Company. Sano, Y., et al. (1993). Applied Geochemistry, 8(1), 1-8.

GEOCHEMISTRY OF PAHS IN AQUATIC ENVIRONMENTS: A SYNTHESIS OF DISTRIBUTION, SOURCE, PERSISTENCE, PARTITIONING AND BIOAVAILABILITY

EPA Science Inventory

On the basis of their distributions, sources, persistence, partitioning and bioavailability, polycyclic aromatic hydrocarbons (PAHs) are a unique class of persistent organic pollutants (POPs) contaminating the aquatic environment. They are of particular interest to geochemists an...

10 CFR 63.114 - Requirements for performance assessment.

Code of Federal Regulations, 2014 CFR

2014-01-01

... GEOLOGIC REPOSITORY AT YUCCA MOUNTAIN, NEVADA Technical Criteria Postclosure Performance Assessment § 63..., hydrology, and geochemistry (including disruptive processes and events) of the Yucca Mountain site, and the... disposal, and provide for the technical basis for parameter ranges, probability distributions, or bounding...

10 CFR 63.114 - Requirements for performance assessment.

Code of Federal Regulations, 2013 CFR

2013-01-01

... GEOLOGIC REPOSITORY AT YUCCA MOUNTAIN, NEVADA Technical Criteria Postclosure Performance Assessment § 63..., hydrology, and geochemistry (including disruptive processes and events) of the Yucca Mountain site, and the... disposal, and provide for the technical basis for parameter ranges, probability distributions, or bounding...

10 CFR 63.114 - Requirements for performance assessment.

Code of Federal Regulations, 2012 CFR

2012-01-01

... GEOLOGIC REPOSITORY AT YUCCA MOUNTAIN, NEVADA Technical Criteria Postclosure Performance Assessment § 63..., hydrology, and geochemistry (including disruptive processes and events) of the Yucca Mountain site, and the... disposal, and provide for the technical basis for parameter ranges, probability distributions, or bounding...

10 CFR 63.114 - Requirements for performance assessment.

Code of Federal Regulations, 2011 CFR

2011-01-01

... GEOLOGIC REPOSITORY AT YUCCA MOUNTAIN, NEVADA Technical Criteria Postclosure Performance Assessment § 63..., hydrology, and geochemistry (including disruptive processes and events) of the Yucca Mountain site, and the... disposal, and provide for the technical basis for parameter ranges, probability distributions, or bounding...

10 CFR 63.114 - Requirements for performance assessment.

Code of Federal Regulations, 2010 CFR

2010-01-01

... GEOLOGIC REPOSITORY AT YUCCA MOUNTAIN, NEVADA Technical Criteria Postclosure Performance Assessment § 63..., hydrology, and geochemistry (including disruptive processes and events) of the Yucca Mountain site, and the... disposal, and provide for the technical basis for parameter ranges, probability distributions, or bounding...

Geochemistry of highly basic calcium hydroxide groundwater in Jordan

USGS Publications Warehouse

Barnes, I.; Presser, T.S.; Saines, M.; Dickson, P.; Van Groos, A. F. K.

1982-01-01

Highly-alkaline (pH > 12.5) meteoric waters of a Ca2+OH--type issue from naturally calcined bituminous marl. The cold (16.5 ??? T(??C) ??? 19.1) waters are super-saturated with minerals thought to be of high-temperature origin. ?? 1982.

Postglacial eruptive history, geochemistry, and recent seismicity of Aniakchak volcano, Alaska Peninsula

USGS Publications Warehouse

Bacon, Charles R.; Neal, Christina A.; Miller, Thomas P.; McGimsey, Robert G.; Nye, Christopher J.

2014-01-01

Future volcanic activity of Aniakchak could include hydromagmatic explosions, possibly followed by effusion or strombolian eruption of basaltic andesite to Plinian eruption of dacite. Another voluminous eruption, such as Aniakchak II, is considered unlikely in the near future.

US National Report to International Union of Geodesy and Geophysics 1987-1990

DOE Office of Scientific and Technical Information (OSTI.GOV)

USAF, Geophysics Laboratory, Hanscom AFB, MA

1991-01-01

An authoritative record of contributions of geophysical research in the U.S. during 1987-1990 is reported. Major areas of research include atmospheric sciences, geodesy, hydrology, planetology, geomagnetism, paleomagnetism, volcanology, geochemistry, petrology, oceanography, seismology, tectonophysics, and solar-planetary relations.

Mercury bioaccumulation assessment for the St. Louis River Area of Concern (poster)

EPA Science Inventory

Elevated mercury concentrations have been documented in fish and invertebrates within the St. Louis River Area of Concern (AOC). Mercury bioavailability is affected by multiple factors, including mercury sources, sediment and water geochemistry, food web structure, individual fis...

Development of stable isotope mixing models in ecology - Dublin

EPA Science Inventory

More than 40 years ago, stable isotope analysis methods used in geochemistry began to be applied to ecological studies. One common application is using mathematical mixing models to sort out the proportional contributions of various sources to a mixture. Examples include contri...

Historical development of stable isotope mixing models in ecology

EPA Science Inventory

More than 40 years ago, stable isotope analysis methods used in geochemistry began to be applied to ecological studies. One common application is using mathematical mixing models to sort out the proportional contributions of various sources to a mixture. Examples include contri...

Development of stable isotope mixing models in ecology - Perth

EPA Science Inventory

More than 40 years ago, stable isotope analysis methods used in geochemistry began to be applied to ecological studies. One common application is using mathematical mixing models to sort out the proportional contributions of various sources to a mixture. Examples include contri...

Development of stable isotope mixing models in ecology - Fremantle

EPA Science Inventory

More than 40 years ago, stable isotope analysis methods used in geochemistry began to be applied to ecological studies. One common application is using mathematical mixing models to sort out the proportional contributions of various sources to a mixture. Examples include contri...

Development of stable isotope mixing models in ecology - Sydney

EPA Science Inventory

More than 40 years ago, stable isotope analysis methods used in geochemistry began to be applied to ecological studies. One common application is using mathematical mixing models to sort out the proportional contributions of various sources to a mixture. Examples include contri...

POLLUTION PREVENTION OPPORTUNITY ASSESSMENT - MANUFACTURING AND FABRICATION REPAIR LABORATORY AT SANDIA NATIONAL LABORATORIES

EPA Science Inventory

These reports summarize pollution prevention opportunity assessments conducted jointly by EPA and DOE at the Geochemistry Laboratory and the Manufacturing and Fabrication Repair Laboratory at the Department of Energy's Sandia National Laboratories facility in Albuquerque, New Mex...

Publications of the Exobiology Program for 1980: A special bibliography

NASA Technical Reports Server (NTRS)

Pleasant, L. G.; Devincenzi, D. L.

1981-01-01

a list of approximately 160 publications resulting from research pursued under the auspices of NASA'S exobiology Program is given. The publications address chemical evolution, organic geochemistry, origin and evolution of life, planetary environments, life in the universe, and planetary protection.

Baseline geochemistry of soil and bedrock Tshirege Member of the Bandelier Tuff at MDA-P

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warren, R.G.; McDonald, E.V.; Ryti, R.T.

1997-08-01

This report provides baseline geochemistry for soils (including fill), and for bedrock within three specific areas that are planned for use in the remediation of Material Disposal Area P (MDA-P) at Technical Area 16 (TA-16). The baseline chemistry includes leachable element concentrations for both soils and bedrock and total element concentrations for all soil samples and for two selected bedrock samples. MDA-P operated from the early 1950s to 1984 as a landfill for rubble and debris generated by the burning of high explosives (HE) at the TA-16 Burning Ground, HE-contaminated equipment and material, barium nitrate sand, building materials, and trash.more » The aim of this report is to establish causes for recognizable chemical differences between the background and baseline data sets. In many cases, the authors conclude that recognizable differences represent natural enrichments. In other cases, differences are best attributed to analytical problems. But most importantly, the comparison of background and baseline geochemistry demonstrates significant contamination for several elements not only at the two remedial sites near the TA-16 Burning Ground, but also within the entire region of the background study. This contamination is highly localized very near to the surface in soil and fill, and probably also in bedrock; consequently, upper tolerance limits (UTLs) calculated as upper 95% confidence limits of the 95th percentile are of little value and thus are not provided. This report instead provides basic statistical summaries and graphical comparisons for background and baseline samples to guide strategies for remediation of the three sites to be used in the restoration of MDA-P.« less

The geochemistry of deep-sea coral skeletons: a review of vital effects and applications for palaeoceanography

USGS Publications Warehouse

Robinson, Laura F.; Adkins, Jess F.; Frank, Norbert; Gagon, Alexander C.; Prouty, Nancy G.; Roark, E. Brendan; van de Flierdt, Tina

2014-01-01

Deep-sea corals were discovered over a century ago, but it is only over recent years that focused efforts have been made to explore the history of the oceans using the geochemistry of their skeletal remains. They offer a promising archive of past oceanic environments given their global distribution, layered growth patterns, longevity and preservation as well as our ability to date them using radiometric techniques. This paper provides an overview of the current state-of-the-art in terms of geochemical approaches to using deep-sea coral skeletons to explore the history of the ocean. Deep-sea coral skeletons have a wide array of morphologies (e.g. solitary cup corals, branching colonial corals) and materials (calcite, aragonite and proteins). As such their biomineralization strategies are diverse, leading to complex geochemistry within coral skeletons. Notwithstanding these complications, progress has been made on developing methods for reconstructing the oceanographic environment in the past using trace elements and isotopic methods. Promising approaches within certain coral groups include clumped isotopes and Mg/Li for temperature reconstructions, boron isotopes and radiocarbon for carbon cycling, εNd, and radiocarbon for circulation studies and δ15N, P/Ca and Ba/Ca for nutrient tracer studies. Likewise there is now a range of techniques for dating deep-sea corals skeletons (e.g. U-series, radiocarbon), and determining their growth rates (e.g. radiocarbon and 210Pb). Dating studies on historic coral populations in the Atlantic, Southern Ocean and Pacific point to climate and environmental changes being dominant controls on coral populations over millennial and orbital timescales. This paper provides a review of a range of successes and promising approaches. It also highlights areas in which further research would likely provide new insights into biomineralization, palaeoceanography and distribution of past coral populations.

Reservoir Characterization using geostatistical and numerical modeling in GIS with noble gas geochemistry

NASA Astrophysics Data System (ADS)

Vasquez, D. A.; Swift, J. N.; Tan, S.; Darrah, T. H.

2013-12-01

The integration of precise geochemical analyses with quantitative engineering modeling into an interactive GIS system allows for a sophisticated and efficient method of reservoir engineering and characterization. Geographic Information Systems (GIS) is utilized as an advanced technique for oil field reservoir analysis by combining field engineering and geological/geochemical spatial datasets with the available systematic modeling and mapping methods to integrate the information into a spatially correlated first-hand approach in defining surface and subsurface characteristics. Three key methods of analysis include: 1) Geostatistical modeling to create a static and volumetric 3-dimensional representation of the geological body, 2) Numerical modeling to develop a dynamic and interactive 2-dimensional model of fluid flow across the reservoir and 3) Noble gas geochemistry to further define the physical conditions, components and history of the geologic system. Results thus far include using engineering algorithms for interpolating electrical well log properties across the field (spontaneous potential, resistivity) yielding a highly accurate and high-resolution 3D model of rock properties. Results so far also include using numerical finite difference methods (crank-nicholson) to solve for equations describing the distribution of pressure across field yielding a 2D simulation model of fluid flow across reservoir. Ongoing noble gas geochemistry results will also include determination of the source, thermal maturity and the extent/style of fluid migration (connectivity, continuity and directionality). Future work will include developing an inverse engineering algorithm to model for permeability, porosity and water saturation.This combination of new and efficient technological and analytical capabilities is geared to provide a better understanding of the field geology and hydrocarbon dynamics system with applications to determine the presence of hydrocarbon pay zones (or other reserves) and improve oil field management (e.g. perforating, drilling, EOR and reserves estimation)

A discussion on the tectonic implications of Ediacaran late- to post-orogenic A-type granite in the northeastern Arabian Shield, Saudi Arabia

NASA Astrophysics Data System (ADS)

Robinson, F. A.; Bonin, B.; Pease, V.; Anderson, J. L.

2017-03-01

The transition from late-orogenic to post-orogenic magmatism following major orogenic episodes such as the Neoproterozoic to Cambrian East African Orogen (EAO) is an important, yet not well-understood geological event marking the cessation of subduction-controlled magmatism between buoyant lithospheric fragments. Forming the northern part of the EAO in the Arabian-Nubian Shield are three granitic suites that successively intruded the same northeastern area and post-date the 640 Ma major orogenic episode: (1) 620-600 Ma alkali feldspar (hypersolvous) granite with alkaline/ferroan/A-type geochemistry, (2) 599 Ma granite cumulates (some garnet-bearing) with calc-alkaline/magnesian affinities, and (3) 584-566 Ma alkali feldspar (hypersolvous) granite (aegirine-bearing) with a distinctive peralkaline/ferroan/A-type signature. Combining whole-rock geochemistry from the southern and northern Arabian Shield, suites 1 and 2 are suggested to be products of late-orogenic slab tear/rollback inducing asthenospheric mantle injection and lower crustal melting/fractionation toward A-type/ferroan geochemistry. Suite 3, however, is suggested to be produced by post-orogenic lithospheric delamination, which replaced the older mantle with new asthenospheric (rare earth element-enriched) mantle that ultimately becomes the thermal boundary layer of the new lithosphere. Major shear zones, such as the 620-540 Ma Najd Fault System (NFS), are some of the last tectonic events recorded across the Arabian Shield. Data presented here suggest that the NFS is directly related to the late-orogenic (620-600 Ma) slab tear/rollback in the northeastern Shield as it met with opposing subduction polarity in the southern Shield. Furthermore, this study infers that east and west Gondwana amalgamation interacted with opposing convergence reflected by the NFS.

Upper Carboniferous retroarc volcanism with submarine and subaerial facies at the western Gondwana margin of Argentina

NASA Astrophysics Data System (ADS)

Koukharsky, M.; Kleiman, L.; Etcheverría, M.; Quenardelle, S.; Bercowski, F.

2009-04-01

During Late Carboniferous times a continental magmatic arc developed at the western margin of Gondwana in South America, as several marine sedimentary basins were formed at the same time in the retroarc region. North of 33°S, at Cordón Agua del Jagüel, Precordillera of Mendoza, Argentina, a volcanic sequence crops out which was emplaced in a submarine environment with some subaerial exposures, and it is intercalated in marine sediments of Agua del Jagüel Formation, which fills of one of these retroarc basins. This paper presents, for the first time, a facies analyses together with geochemical and isotopic data of this volcanic suite, suggesting its deposition in an ensialic retroarc marine basin. The volcanic succession comprises debris flows with either sedimentary or volcanic fragments, base surge, resedimented massive and laminated dacitic-andesitic hyaloclastite, pillow lava, basic hyaloclastite and dacitic-andesitic lavas and hyaloclastite facies. Its composition is bimodal, either basaltic or dacitic-andesitic. The geochemistry data indicate a subalkaline, low K calk-alkaline and metaluminous affinity. The geochemistry of the basalts points to an origin of the magmas from a depleted mantle source with some crustal contamination. Conversely, the geochemistry of the dacites-andesites shows an important participation of both crustal components and subduction related fluids. A different magmatic source for the basalts than for the dacites-andesites is also supported by Sr and Nd isotopic initial ratios and Nd model ages. The characteristics of this magmatic suite suggest its emplacement in an extensional setting probably associated with the presence of a steepened subduction zone at this latitude during Upper Carboniferous times.

Mineralogy of Rock Flour in Glaciated Volcanic Terrains: An Analog for a Cold and Icy Early Mars

NASA Technical Reports Server (NTRS)

Rampe, E. B.; Horgan, B.; Scudder, N.; Smith, R. J.; Rutledge, A. M.

2017-01-01

Geomorphological and mineralogical data from early Martian surfaces indicate liquid water was present on ancient Mars. The relative surface temperatures, however, remain a subject of debate. Was early Mars warm and wet or cold and icy with punctuated periods of warmth and ice melt? By characterizing the mineralogy and geochemistry of modern icy mafic terrains on Earth, we can search for these characteristics in early Martian terrains to better constrain the early Martian climate. Here, we describe the mineralogy of glacial flour in a modern glaciated volcanic terrain in Oregon, USA. We are particularly interested in secondary phases that form in these environments, and we hypothesize that poorly crystalline phases may preferentially form in these terrains because of the low temperatures and the seasonality of melt water production. A description of the mineralogy of the moraines, the composition of the amorphous materials, and the geochemistry of the glacial melt waters are presented elsewhere. Glacial flour is made up of silt- and clay-sized particles that form from the physical weathering of rock underlying a wet-based glacier as the glacier slides over it. Flour is usually transported from underneath a glacier by melt water streams. The geochemistry of glacial melt water streams has been studied extensively and has been used to infer weathering reactions within glacial systems. However, the mineralogy of these environments, especially on mafic volcanic terrains, is not well studied. Rock flour is a ubiquitous physical weathering product in glaciated terrains and, therefore, affects microbial habitats, stream and lake chemistry, and chemical weathering processes. and by studying the mineralogy of glacial flour, we can better understand geochemical and microbiological processes in subglacial and proglacial terrains.

Recurrent patterns in fluid geochemistry data prior to phreatic eruptions

NASA Astrophysics Data System (ADS)

Rouwet, Dmitri; Sandri, Laura; Todesco, Micol; Tonini, Roberto; Pecoraino, Giovannella; Diliberto, Iole Serena

2016-04-01

Not all volcanic eruptions are magma-driven: the sudden evaporation and expansion of heated groundwater may cause phreatic eruptions, where the magma involvement is absent or negligible. Active crater lakes top some of the volcanoes prone to phreatic activity. This kind of eruption may occur suddenly, and without clear warning: on September 27, 2014 a phreatic eruption of Ontake, Japan, occurred without timely precursors, killing 57 tourists near the volcano summit. Phreatic eruptions can thus be as fatal as higher VEI events, due to the lack of recognised precursory signals, and because of their explosive and violent nature. In this study, we tackle the challenge of recognising precursors to phreatic eruptions, by analysing the records of two "phreatically" active volcanoes in Costa Rica, i.e. Poás and Turrialba, respectively with and without a crater lake. These volcanoes cover a wide range of time scales in eruptive behaviour, possibly culminating into magmatic activity, and have a long-term multi-parameter dataset mostly describing fluid geochemistry. Such dataset is suitable for being analysed by objective pattern recognition techniques, in search for recurrent schemes. The aim is to verify the existence and nature of potential precursory patterns, which will improve our understanding of phreatic events, and allow the assessment of the associated hazard at other volcanoes, such as Campi Flegrei or Vulcano, in Italy. Quantitative forecast of phreatic activity will be performed with BET_UNREST, a Bayesian Event Tree tool recently developed within the framework of FP7 EU VUELCO project. The study will combine the analysis of fluid geochemistry data with pattern recognition and phreatic eruption forecast on medium and short-term. The study will also provide interesting hints on the features that promote or hinder phreatic activity in volcanoes that host well-developed hydrothermal circulation.

Groundwater ecosystem resilience to organic contaminations: microbial and geochemical dynamics throughout the 5-year life cycle of a surrogate ethanol blend fuel plume.

PubMed

Ma, Jie; Nossa, Carlos W; Alvarez, Pedro J J

2015-09-01

The capacity of groundwater ecosystem to recover from contamination by organic chemicals is a vital concern for environmental scientists. A pilot-scale aquifer system was used to investigate the long-term dynamics of contaminants, groundwater geochemistry, and microbial community structure (by 16S rRNA gene pyrosequencing and quantitative real-time PCR) throughout the 5-year life cycle of a surrogate ethanol blend fuel plume (10% ethanol + 50 mg/L benzene + 50 mg/L toluene). Two-year continuous ethanol-blended release significantly changed the groundwater geochemistry (resulted in anaerobic, low pH, and organotrophic conditions) and increased bacterial and archaeal populations by 82- and 314-fold respectively. Various anaerobic heterotrophs (fermenters, acetogens, methanogens, and hydrocarbon degraders) were enriched. Two years after the release was shut off, all contaminants and their degradation byproducts disappeared and groundwater geochemistry completely restored to the pre-release states (aerobic, neutral pH, and oligotrophic). Bacterial and archaeal populations declined by 18- and 45-fold respectively (relative to the time of shut off). Microbial community structure reverted towards the pre-release states and alpha diversity indices rebounded, suggesting the resilience of microbial community to ethanol blend releases. We also found shifts from O2-sensitive methanogens (e.g., Methanobacterium) to methanogens that are not so sensitive to O2 (e.g., Methanosarcina and Methanocella), which is likely to contribute to the persistence of methanogens and methane generation following the source removal. Overall, the rapid disappearance of contaminants and their metabolites, rebound of geochemical footprints, and resilience of microbial community unequivocally document the natural capacity of groundwater ecosystem to attenuate and recover from a large volume of catastrophic spill of ethanol-based biofuel. Copyright © 2015 Elsevier Ltd. All rights reserved.

Geochemistry of Archean metasedimentary rocks of the Aravalli craton, NW India: Implications for provenance, paleoweathering and supercontinent reconstruction

NASA Astrophysics Data System (ADS)

Ahmad, Iftikhar; Mondal, M. E. A.; Satyanarayanan, M.

2016-08-01

Basement complex of the Aravalli craton (NW India) known as the Banded Gneissic Complex (BGC) is classified into two domains viz. Archean BGC-I and Proterozoic BGC-II. We present first comprehensive geochemical study of the Archean metasedimentary rocks occurring within the BGC-I. These rocks occur associated with intrusive amphibolites in a linear belt within the basement gneisses. The association is only concentrated on the western margin of the BGC-I. The samples are highly mature (MSm) to very immature (MSi), along with highly variable geochemistry. Their major (SiO2/Al2O3, Na2O/K2O and Al2O3/TiO2) and trace (Th/Sc, Cr/Th, Th/Co, La/Sc, Zr/Sc) element ratios, and rare earth element (REE) patterns are consistent with derivation of detritus from the basement gneisses and its mafic enclaves, with major contribution from the former. Variable mixing between the two end members and closed system recycling (cannibalism) resulted in the compositional heterogeneity. Chemical index of alteration (CIA) of the samples indicate low to moderate weathering of the source terrain in a sub-tropical environment. In A-CN-K ternary diagram, some samples deceptively appear to have undergone post-depositional K-metasomatism. Nevertheless, their petrography and geochemistry (low K2O and Rb) preclude the post-depositional alteration. We propose non-preferential leaching of elements during cannibalism as the cause of the deceptive K-metasomatism as well as enigmatic low CIA values of some highly mature samples. The Archean metasedimentary rocks were deposited on stable basement gneisses, making the BGC-I a plausible participant in the Archean Ur supercontinent.

Geochemistry, petrography, and zircon U-Pb geochronology of Paleozoic metaigneous rocks in the Mount Veta area of east-central Alaska: implications for the evolution of the westernmost part of the Yukon-Tanana terrane

USGS Publications Warehouse

Dusel-Bacon, Cynthia; Day, Warren C.; Aleinikoff, John N.

2013-01-01

We report the results of new mapping, whole-rock major, minor, and trace-element geochemistry, and petrography for metaigneous rocks from the Mount Veta area in the westernmost part of the allochthonous Yukon–Tanana terrane (YTT) in east-central Alaska. These rocks include tonalitic mylonite gneiss and mafic metaigneous rocks from the Chicken metamorphic complex and the Nasina and Fortymile River assemblages. Whole-rock trace-element data from the tonalitic gneiss, whose igneous protolith was dated by SHRIMP U–Pb zircon geochronology at 332.6 ± 5.6 Ma, indicate derivation from tholeiitic arc basalt. Whole-rock analyses of the mafic rocks suggest that greenschist-facies rocks from the Chicken metamorphic complex, a mafic metavolcanic rock from the Nasina assemblage, and an amphibolite from the Fortymile River assemblage formed as island-arc tholeiite in a back-arc setting; another Nasina assemblage greenschist has MORB geochemical characteristics, and another mafic metaigneous rock from the Fortymile River assemblage has geochemical characteristics of calc-alkaline basalt. Our geochemical results imply derivation in an arc and back-arc spreading region within the allochthonous YTT crustal fragment, as previously proposed for correlative units in other parts of the terrane. We also describe the petrography and geochemistry of a newly discovered tectonic lens of Alpine-type metaharzburgite. The metaharzburgite is interpreted to be a sliver of lithospheric mantle from beneath the Seventymile ocean basin or from sub-continental mantle lithosphere of the allochthonous YTT or the western margin of Laurentia that was tectonically emplaced within crustal rocks during closure of the Seventymile ocean basin and subsequently displaced and fragmented by faults.

Spatial variation of urban soil geochemistry in a roadside sports ground in Galway, Ireland.

PubMed

Dao, Ligang; Morrison, Liam; Zhang, Chaosheng

2010-02-01

Characterization of spatial variation of urban soil geochemistry especially heavy metal pollution is essential for a better understanding of pollution sources and potential risks. A total of 294 surface soil samples were collected from a roadside sports ground in Galway, Ireland, and were analysed by ICP-OES for 23 chemical elements (Al, Ca, Ce, Co, Cu, Fe, K, La, Li, Mg, Mn, Na, Ni, P, Pb, S, Sc, Sr, Th, Ti, V, Y and Zn). Strong variations in soil geochemistry were observed and most elements, with the exception of Cu, Pb, P, S and Zn, showed multi-modal features, indicating the existence of mixed populations which proved difficult to separate. To evaluate the pollution level of the study area, the pollution index (PI) values were calculated based on a comparison with the Dutch target and intervention values. None of the concentrations of metal pollutants exceeded their intervention values, indicating the absence of serious contaminated soil, and the ratios to target values were therefore employed to produce the hazard maps. The spatial distribution and hazard maps for Cu, Pb and Zn indicated relatively high levels of pollution along the southern roadside extending almost 30m into the sports ground, revealing the strong influence of pollution from local traffic. However, heavy metal pollution was alleviated along the eastern roadside of the study area by the presence of a belt of shrubs. Therefore, in order to prevent further contamination from traffic emissions, the planting of hedging or erection of low walls should be considered as shields against traffic pollution for roadside parks. The results in this study are useful for management practices in sports and parks in urban areas. Copyright 2009 Elsevier B.V. All rights reserved.

Stable, geochemically mediated biospheres in the Deep Mine Microbial Observatory, SD, USA

NASA Astrophysics Data System (ADS)

Osburn, M. R.; Casar, C. P.; Kruger, B.; Flynn, T. M.

2017-12-01

The terrestrial subsurface is a vast reservoir of life, hosting diverse microbial ecosystems with varying levels of connectivity to surface inputs. Understanding long term ecosystem dynamics within the subsurface biosphere is very challenging due to limitations in accessibility, sample availability, and slow microbial growth rates. The establishment of the Deep Mine Microbial Observatory (DeMMO) at the Sanford Underground Research Facility, SD, USA has allowed for bimonthly sampling for nearly two years at six sites spanning 250 to 1500 m below the surface. Here we present a time-resolved analysis of the geomicrobiology of the six DeMMO sites, which have been created from legacy mine boreholes modified to allow for controlled sampling. Our interdisciplinary approach includes analysis of passively draining fracture fluid for aqueous and gas geochemistry, DNA sequencing, microscopy, and isotopic measurements of organic and inorganic substrates. Fluid geochemistry varies significantly between sites, but is relatively stable over time for a given site, even through significant external perturbations such as drilling and installation of permanent sampling devices into the boreholes. The fluid-hosted microbial diversity follows these trends, with consistent populations present at each site through time, even through drilling events. For instance, the shallowest site (DeMMO 1) consistently hosts >30% uncharacterized phyla and >25% Omnitrophica whereas the deepest site (DeMMO 6) is dominated by Firmicutes and Bacterioidetes. Microbial diversity appears to respond to the availability of energy sources such as organic carbon, sulfate, sulfide, hydrogen, and iron. Carbon isotopic measurements reveal closed system behavior with significant recycling of organic carbon into the DIC pool. Together these observations suggest DeMMO hosts isolated subsurface microbial populations adapted to local geochemistry that are stable on yearlong timescales.

GEOCHEMISTRY OF SUBSURFACE REACTIVE BARRIERS FOR REMEDIATION OF CONTAMINATED GROUND WATER

EPA Science Inventory

Reactive barriers that couple subsurface fluid flow with a passive chemical treatment zone are emerging, cost effective approaches for in-situ remediation of contaminated groundwater. Factors such as the build-up of surface precipitates, bio-fouling, and changes in subsurface tr...

Publications of the planetary biology program for 1978: A special bibliography

NASA Technical Reports Server (NTRS)

Pleasant, L. G. (Compiler); Young, R. S. (Compiler)

1979-01-01

The planetary events which are responsible for, or related to, the origin, evolution, and distribution of life in the universe are investigated. Bibliographies from chemical evolution, organic geochemistry, life detection, biological adaptation, bioinstrumentation, planetary environments, and origin of life studies are presented.

Anatomy of a cluster IDP. Part 2: Noble gas abundances, trace element geochemistry, isotopic abundances, and trace organic chemistry of several fragments from L2008#5

NASA Technical Reports Server (NTRS)

Thomas, K. L.; Clemett, S. J.; Flynn, G. J.; Keller, L. P.; Mckay, David S.; Messenger, S.; Nier, A. O.; Schlutter, D. J.; Sutton, S. R.; Walker, R. M.

1994-01-01

The topics discussed include the following: noble gas content and release temperatures; trace element abundances; heating summary of cluster fragments; isotopic measurements; and trace organic chemistry.

Publications - PIR 2004-3 | Alaska Division of Geological & Geophysical

Science.gov Websites

) Keywords Alaska, State of; Alluvial Deposits; Amy Creek Assemblage; Amy Dolomite; Ar-Ar; Bison Fossils ; Cambrian; Caribou Fossils; Cascaden Ridge Unit; Cenozoic; Colluvial Deposits; Cretaceous; Devonian ; Engineering Geology; Eolian; Fox Fossils; Geochemistry; Geochronology; Geologic Hazards; Geologic Materials

SMALL-SCALE HETEROGENEITY IN THE GEOCHEMISTRY OF SEAGRASS VEGETATED AND NON-VEGETATIVE SEDIMENTS: CAUSES AND CONSEQUENCES

EPA Science Inventory

In addition to nutrient and light availability, sedimentary biogeochemical processes can play an essential role in seagrass productivity. Previous investigations of the interactions between seagrasses and their underlying sediments have failed to clearly identify the spatio-tempo...

Geochemistry

ERIC Educational Resources Information Center

Brett, Robin; Hanshaw, Bruce B.

1978-01-01

The past year has seen the development of certain fields of geochemical research including Nd-Sm isotope studies of meteorites and ancient terrestrial rocks; the use of the consortium approach of assembling a multidisciplined team to tackle a problem; and the handling and analysis of small quantities of materials. (Author/MA)

A Field Course Teaching Research Concepts in Environmental Geochemistry.

ERIC Educational Resources Information Center

Brown, Foster; De Lacerda, Luiz Drude

1986-01-01

Describes a graduate field course taught in Brazil that uses a system concept and the geochemical cycle as unifying paradigms to study various environments. Emphasizes the acquisition of techniques of integrated observation, using operational definitions, measurement scales, and a priori hypotheses. (Author/TW)

Geochemistry and origin of regional dolomites. Technical progress report, July 26, 1991--April 21, 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hanson, G.N.; Meyers, W.J.

1992-07-01

This grant supports research on the origins and geochemical aspects of regional dolomites. Eight graduate students are involved in research on dolomite allowing a diverse range of studies. This report outlines their work in the field. (JL)

Chemistry and the Modern Prospector.

ERIC Educational Resources Information Center

Neff, Thomas R.

1981-01-01

States that the object of any geochemical survey is to detect the trace element "halo" associated with a mineral deposit. Describes primary and secondary halos and the following types of surveys: stream sediment, water, soil, vegetation, bedrock, and vapor surveys. Briefly reviews future trends including airborne geochemistry. (SK)

In-Situ Lake Bio-Geochemistry Using Laser Raman Spectroscopy and Optrode Sensing

NASA Astrophysics Data System (ADS)

Sobron, P.; Sanz, A.; Thompson, C.; Cabrol, N.; Planetary Lake Lander Project Team

2014-06-01

We have used LRS for characterizing the organic content of a lake through real-time, in-situ analyses and through lab analyses of returned samples. β-carotene and fatty acids (triglycerides) were identified as major components of the organic samples.

IRON SULFIDES IN THE ENVIRONMENT: FORMATION, FATE, AND SIGNIFICANCE TO CONTAMINANT BEHAVIOR

EPA Science Inventory

This seminar will cover aspects of the geochemistry of iron sulfides, their formation in sedimentary and aquifer environments, and their roles in sequestering and releasing contaminants. A special emphasis will be placed on the interactions between iron sulfides and arsenic.

Potential Aquifer Vulnerability in Regions Down-Gradient from Uranium In Situ Recovery (ISR) Sites

EPA Science Inventory

Sandstone-hosted roll-front uranium ore deposits originate when U(VI) dissolved in groundwater is reduced and precipitated as insoluble U(IV) minerals. Groundwater redox geochemistry, aqueous complexation, and solute migration are instrumental in leaching uranium from source rock...

Isotopic Biogeochemistry

NASA Technical Reports Server (NTRS)

Hayes, J. M.

1985-01-01

An overview is provided of the biogeochemical research. The funding, productivity, personnel and facilities are reviewed. Some of the technical areas covered are: carbon isotopic records; isotopic studies of banded iron formations; isotope effects in microbial systems; studies of organic compounds in ancient sediments; and development in isotopic geochemistry and analysis.

USE OF STABLE ISOTOPES IN ENVIRONMENTAL AND FORENSIC GEOCHEMISTRY STUDIES

EPA Science Inventory

Stable carbon and hydrogen isotopes have been used for many decades in the petroleum industry, but the development of combined gas chromatography-isotope ratio mass spectrometry (GCIRMS) has led to a virtual explosion in application of this technique not only in petroleum explora...

Geochemistry of uranium and thorium and natural radioactivity levels of the western Anatolian plutons, Turkey

NASA Astrophysics Data System (ADS)

Papadopoulos, Argyrios; Altunkaynak, Şafak; Koroneos, Antonios; Ünal, Alp; Kamaci, Ömer

2017-10-01

Seventy samples from major plutons (mainly granitic) of Western Anatolia (Turkey) have been analyzed by γ-ray spectrometry to determine the specific activities of 238U, 226Ra, 232Th and 40K (Bq/kg). Τhe natural radioactivity ranged up to 264 Bq/kg for 238U, 229.62 Bq/kg for 226Ra, up to 207.32 Bq/kg for 232Th and up to 2541.95 Bq/kg for 40K. Any possible relationship between the specific activities of 226Ra, 238U, 232Th and 40K and some characteristics of the studied samples (age, rock-type, colour, grain size, occurrence, chemical and mineralogical composition) was investigated. Age, major and trace element geochemistry, color, pluton location and mineralogical composition are likely to affect the concentrations of the measured radionuclides. The range of the Th/U ratio was large (0.003-11.374). The latter, along with 226Ra/238U radioactive secular disequilibrium, is also discussed and explained by magmatic processes during differentiation.

Expected Geochemical and Mineralogical Properties of Meteorites from Mercury: Inferences from Messenger Data

NASA Technical Reports Server (NTRS)

McCubbin, F. M.; McCoy, T. J.

2016-01-01

Meteorites from the Moon, Mars, and many types of asteroid bodies have been identified among our global inventory of meteorites, however samples of Mercury and Venus have not been identified. The absence of mercurian and venusian meteorites could be attributed to an inability to recognize them in our collections due to a paucity of geochemical information for Venus and Mercury. In the case of mercurian meteorites, this possibility is further supported by dynamical calculations that suggest mercurian meteorites should be present on Earth at a factor of 2-3 less than meteorites from Mars [1]. In the present study, we focus on the putative mineralogy of mercurian meteorites using data obtained from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft, which has provided us with our first quantitative constraints on the geochemistry of planet Mercury. We have used the MESSENGER data to compile a list of mineralogical and geochemical characteristics that a meteorite from Mercury is likely to exhibit.

The Conterminous United States Mineral Assessment Program; background information to accompany folio of geologic, geochemical, geophysical, and mineral resource maps of the Ajo and Lukeville 1 degree x 2 degrees quadrangles, Arizona

USGS Publications Warehouse

Gray, Floyd; Tosdal, R.M.; Peterson, J.A.; Cox, D.P.; Miller, R.J.; Klein, D.P.; Theobald, P.K.; Haxel, G.B.; Grubensky, M.J.; Raines, G.L.; Barton, H.N.; Singer, D.A.; Eppinger, R.G.

1992-01-01

Encompassing about 21,000 km 2 in southwestern Arizona, the Ajo and Lukeville 1 ? by 2 ? quadrangles have been the subject of mineral resource investigations utilizing field and laboratory studies in the disciplines of geology, geochemistry, geophysics, and Landsat imagery. The results of these studies are published as a folio of maps, figures, and tables, with accompanying discussions. Past mineral production has been limited to copper from the Ajo Mining District. In addition to copper, the quadrangles contain potentially significant resources of gold and silver; a few other commodities, including molybdenum and evaporites, may also exist in the area as appreciable resources. This circular provides background information on the mineral deposits and on the investigations and integrates the information presented in the folio. The bibliography cites references to the geology, geochemistry, geophysics, and mineral deposits of the two quadrangles.

The effects of Hurricanes Katrina and Rita on seabed polycyclic aromatic hydrocarbon dynamics in the Gulf of Mexico.

PubMed

Mitra, Siddhartha; Lalicata, Joseph J; Allison, Mead A; Dellapenna, Timothy M

2009-06-01

To assess the extent to which Hurricanes Katrina and Rita affected polycyclic aromatic hydrocarbons (PAH) in the Gulf of Mexico (GOM), sediment cores were analyzed in late 2005 from: a shallow shelf, a deeper shelf, and a marsh station. Sediment geochronology, fabric, and geochemistry show that the 2005 storms deposited approximately 10cm of sediment to the surface of a core at 5-12A. Bulk carbon geochemistry and PAH isomers in this top layer suggest that the source of sediment to the top portion of core 5-12A was from a relatively more marine area. Particulate PAHs in the marsh core (04M) appeared unaffected by the storms while sediments in the core from Station 5-1B (deeper shelf) were affected minimally (some possible storm-derived deposition). Substantial amounts of PAH-laden particles may have been displaced from the seabed in shallow areas of the water column in the GOM by these 2005 storms.

Annotated bibliography of environmentally relevant investigations of uranium mining and milling in the Grants Mineral Belt, northwestern New Mexico

USGS Publications Warehouse

Otton, James K.

2011-01-01

Studies of the natural environment in the Grants Mineral Belt in northwestern New Mexico have been conducted since the 1930s; however, few such investigations predate uranium mining and milling operations, which began in the early 1950s. This report provides an annotated bibliography of reports that describe the hydrology and geochemistry of groundwaters and surface waters and the geochemistry of soils and sediments in the Grants Mineral Belt and contiguous areas. The reports referenced and discussed provide a large volume of information about the environmental conditions in the area after mining started. Data presented in many of these studies, if evaluated carefully, may provide much basic information about the baseline conditions that existed over large parts of the Grants Mineral Belt prior to mining. Other data may provide information that can direct new work in efforts to discriminate between baseline conditions and the effects of the mining and milling on the natural environment.

Bibliography of selected references on the hydrogeologic and chemical properties of the Galena-Platteville bedrock unit in Illinois and Wisconsin, 1877-1997

USGS Publications Warehouse

Brown, Timothy A.; Dunning, Charles P.; Batten, William G.

1997-01-01

This report presents selected references concerning the Galena-Platteville deposits in Illinois and Wisconsin published from 1877 to 1997. Sources of the bibliographic information are the Universities of Illinois and Wisconsin Library Computer Systems; Illinet Online; the Illinois and Wisconsin District Libraries of the U.S. Geological Survey; U.S. Geological Survey Selected Water Resources Abstracts; U.S. Environmental Protection Agency reports; and Federal, State, and local agencies, corporations, and consultants. The bibliography is arranged alphabetically, by county, in Illinois and Wisconsin. The references available for each county are arranged alphabetically by author. In addition, one or more selected hydrogeologic key words describing the content of the reference follow each listing. These key words are geophysical properties, hydraulic properties, inorganic geochemistry, lithology, organic geochemistry, physical properties, and water use. Included in the bibliography are 186 references obtained for 15 counties in Illinois and 21 counties in Wisconsin.

Combining stable isotope isotope geochemistry and carbonic anhydrase activity to trace vital effect in carbonate precipitation experiments

NASA Astrophysics Data System (ADS)

Thaler, C.; Ader, M.; Menez, B.; Guyot, F. J.

2013-12-01

Carbonates precipitated by skeleton-forming eukaryotic organisms are often characterized by non-equilibrium isotopic signatures. This specificity is referred to as the "vital effect" and can be used as an isotopic evidence to trace life. Combining stable isotope geochemistry and enzymology (using the enzyme carbonic anhydrase) we aim to demonstrate that prokaryotes are also able to precipitate carbonate with a non-equilibrium d18OCaCO3. Indeed, if in an biomineralization experiment carbonates are precipitated with a vital effect, the addition of carbonic anhydrase should drive the system to isotope equilibrium, And provide a comparison point to estimate the vital effect range. This protocol allowed us to identify a -20‰ vital effect for the d18O of carbonates precipitated by Sporosarcina pasteurii, a bacterial model of carbonatogen metabolisms. This approach is thus a powerfull tool for the understanding of microbe carbonatogen activity and will probably bring new insights into the understanding of bacterial activity in subsurface and during diagenesis.

Geological and geochemical aspects of uranium deposits. A selected, annotated bibliography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garland, P.A.; Thomas, J.M.; Brock, M.L.

1980-06-01

A bibliography of 479 references encompassing the fields of uranium and thorium geochemistry and mineralogy, geology of uranium deposits, uranium mining, and uranium exploration techniques has been compiled by the Ecological Sciences Information Center of Oak Ridge National Laboratory. The bibliography was produced for the National Uranium Resource Evaluation Program, which is funded by the Grand Junction Office of the Department of Energy. The references contained in the bibliography have been divided into the following eight subject categories: (1) geology of deposits, (2) geochemistry, (3) genesis O deposits, (4) exploration, (5) mineralogy, (6) uranium industry, (7) reserves and resources, andmore » (8) geology of potential uranium-bearing areas. All categories specifically refer to uranium and thorium; the last category contains basic geologic information concerning areas which the Grand Junction Office feels are particularly favorable for uranium deposition. The references are indexed by author, geographic location, quadrangle name, geoformational feature, taxonomic name, and keyword.« less

Geochemical and mineralogical evidence for Sahara and Sahel dust additions to Quaternary soils on Lanzarote, eastern Canary Islands, Spain

USGS Publications Warehouse

Muhs, D.R.; Budahn, J.; Skipp, G.; Prospero, J.M.; Patterson, D.; Bettis, E. Arthur

2010-01-01

Africa is the most important source of dust in the world today, and dust storms are frequent on the nearby Canary Islands. Previous workers have inferred that the Sahara is the most important source of dust to Canary Islands soils, with little contribution from the Sahel region. Soils overlying a late Quaternary basalt flow on Lanzarote, Canary Islands, contain, in addition to volcanic minerals, quartz and mica, exotic to the island's bedrock. Kaolinite in the soils also likely has an exotic origin. Trace-element geochemistry shows that the soils are derived from varying proportions of locally derived basalt and African dust. Major-element geochemistry, clay mineralogy and interpretation of satellite imagery suggest that dust additions to the Canary Islands come not only from the Sahara Desert, but also from the Sahel region. ?? Published 2010. This article is a US Government work and is in the public domain in the USA.

Microbial Paleontology, Mineralogy and Geochemistry of Modern and Ancient Thermal Spring Deposits and Their Recognition on the Early Earth and Mars"

NASA Technical Reports Server (NTRS)

Farmer, Jack D.

2004-01-01

The vision of this project was to improve our understanding of the processes by which microbiological information is captured and preserved in rapidly mineralizing sedimentary environments. Specifically, the research focused on the ways in which microbial mats and biofilms influence the sedimentology, geochemistry and paleontology of modem hydrothermal spring deposits in Yellowstone national Park and their ancient analogs. Toward that goal, we sought to understand how the preservation of fossil biosignatures is affected by 1) taphonomy- the natural degradation processes that affect an organism from the time of its death, until its discovery as a fossil and 2) diagenesis- longer-term, post-depositional processes, including cementation and matrix recrystallization, which collectively affect the mineral matrix that contains fossil biosignature information. Early objectives of this project included the development of observational frameworks (facies models) and methods (highly-integrated, interdisciplinary approaches) that could be used to explore for hydrothermal deposits in ancient terranes on Earth, and eventually on Mars.

Areas with Surface Thermal Anomalies as Detected by ASTER and LANDSAT Data around South Canyon Hot Springs, Garfield County, Colorado

DOE Data Explorer

Khalid Hussein

2012-02-01

This map shows areas of anomalous surface temperature around South Canyon Hot Springs as identified from ASTER and LANDSAT thermal data and spatial based insolation model. The temperature for the ASTER data was calculated using the Emissivity Normalization Algorithm that separate temperature from emissivity. The incoming solar radiation was calculated using spatial based insolation model developed by Fu and Rich (1999). Then the temperature due to solar radiation was calculated using emissivity derived from ASTER data. The residual temperature, i.e. temperature due to solar radiation subtracted from ASTER temperature was used to identify thermally anomalous areas. Areas having anomalous temperature in the ASTER data are shown in blue diagonal hatch, while areas having anomalous temperature in the LANDSAT data are shown in magenta on the map. Thermal springs and areas with favorable geochemistry are also shown. Springs or wells having non-favorable geochemistry are shown as blue dots.

Analysis of DGGE profiles to explore the relationship between prokaryotic community composition and biogeochemical processes in deep subseafloor sediments from the Peru Margin.

PubMed

Fry, John C; Webster, Gordon; Cragg, Barry A; Weightman, Andrew J; Parkes, R John

2006-10-01

The aim of this work was to relate depth profiles of prokaryotic community composition with geochemical processes in the deep subseafloor biosphere at two shallow-water sites on the Peru Margin in the Pacific Ocean (ODP Leg 201, sites 1228 and 1229). Principal component analysis of denaturing gradient gel electrophoresis banding patterns of deep-sediment Bacteria, Archaea, Euryarchaeota and the novel candidate division JS1, followed by multiple regression, showed strong relationships with prokaryotic activity and geochemistry (R(2)=55-100%). Further correlation analysis, at one site, between the principal components from the community composition profiles for Bacteria and 12 other variables quantitatively confirmed their relationship with activity and geochemistry, which had previously only been implied. Comparison with previously published cell counts enumerated by fluorescent in situ hybridization with rRNA-targeted probes confirmed that these denaturing gradient gel electrophoresis profiles described an active prokaryotic community.

Data Packages for the Hanford Immobilized Low Activity Tank Waste Performance Assessment 2001 Version [SEC 1 THRU 5

DOE Office of Scientific and Technical Information (OSTI.GOV)

MANN, F.M.

Data package supporting the 2001 Immobilized Low-Activity Waste Performance Analysis. Geology, hydrology, geochemistry, facility, waste form, and dosimetry data based on recent investigation are provided. Verification and benchmarking packages for selected software codes are provided.

10 CFR 960.4-2-2 - Geochemistry.

Code of Federal Regulations, 2012 CFR

2012-01-01

.... Considering the likely chemical interactions among radionuclides, the host rock, and the ground water, the... the rock matrix, or sorption of radionuclides; inhibit the formation of particulates, colloids... geochemical conditions and a volumetric flow rate of water in the host rock that would allow less than 0.001...

Aeromagnetic maps of the Mazatzal Wilderness and contiguous roadless areas, Gila, Maricopa, and Yavapai counties, Arizona

USGS Publications Warehouse

Moss, C.K.; Abrams, G.A.

1985-01-01

Studies of the geology, geochemistry (Marsh and others, 1983a, b, Erickson, 1984), mines and prospects (Ellis, 1982), and mineral resource potential (Wrucke and others, 1983) of the Mazatzal Wilderness and contiguous roadless areas have been published elsewhere.

Geochemistry and Organic Chemistry on the Surface of Titan

NASA Technical Reports Server (NTRS)

Lunine, J. I.; Beauchamp, P.; Beauchamp, J.; Dougherty, D.; Welch, C.; Raulin, F.; Shapiro, R.; Smith, M.

2001-01-01

Titan's atmosphere produces a wealth of organic products from methane and nitrogen. These products, deposited on the surface in liquid and solid form, may interact with surface ices and energy sources to produce compounds of exobiological interest. Additional information is contained in the original extended abstract.

Publications - PIR 2004-3A | Alaska Division of Geological & Geophysical

Science.gov Websites

; Bedrock; Bedrock Geology; Cambrian; Caribou Fossils; Cascaden Ridge Unit; Cenozoic; Colluvial Deposits ; Cretaceous; Devonian; Eolian; Fox Fossils; Generalized; Geochemistry; Geochronology; Geologic Map; Geology ; Holocene; Horse Fossils; Igneous Rocks; K-Ar; Livengood Bench; Livengood Dome Chert; Lost Creek Unit

A Course in Chemistry of Silicates for Beginning Undergraduate Students: An Interdisciplinary Study

ERIC Educational Resources Information Center

Dunstone, John

1973-01-01

The course was designed: (1) to broaden the base for chemistry majors to build their courses; (2) to illustrate how some chemistry principles are applied to real situations; and (3) to serve as an introduction to geochemistry for geology majors. (DF)

Technical support for geopressured-geothermal activities in Louisiana. Final geological report, 1 November 1981-31 October 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pilger, R.H.

1984-06-25

This report contains the component Site-Specific Studies-Geophysics, Diagenesis, Geochemistry. Work for Site-Specific Studies is finished, and the results presented in this report are final. Individual studies have been entered separately into the data base. (ACR)

MSATT Workshop on Chemical Weathering on Mars

NASA Technical Reports Server (NTRS)

Burns, Roger (Editor); Banin, Amos (Editor)

1992-01-01

The topics covered with respect to chemical weathering on Mars include the following: Mars soil, mineralogy, spectroscopic analysis, clays, silicates, oxidation, iron oxides, water, chemical reactions, geochemistry, minerals, Mars atmosphere, atmospheric chemistry, salts, planetary evolution, volcanology, Mars volcanoes, regolith, surface reactions, Mars soil analogs, carbonates, meteorites, and reactivity.

ARE ELEMENTAL FINGERPRINTS OF FISH OTOLITHS DISTINCT AMONG GREAT LAKES COASTAL NURSERY AREAS?

EPA Science Inventory

Elemental composition of an otolith reflects a fish's rearing environment,
so otolith geochemistry can record differences in ambient water conditions
specific to habitats used during a fish's life history. Although few studies
have been conducted in freshwater, trace ...

Flow and Suspended Sediment Events in the Near-Coastal Zone off Corpus Christi, Texas

DTIC Science & Technology

2003-09-30

redistribution of preexisting shelf sediments during storms and (2) transportation of suspended sediment from the adjacent bay- lagoon system. Snedden et al...and K.E. Schmedes. (1983). Submerged lands of Texas, Corpus Christi area: sediments, geochemistry, benthic macroinvertebrates and associated

Plankton Production Biology

DTIC Science & Technology

2007-09-30

schedule was also a discussion of a draft plan for the next decade by NASA’s Ocean Biology and Bio- geochemistry Program, tentatively entitled, “Earth’s...workshop was being held in Seattle. (GLOBEC was a ten-year field program under ICSU that was co-sponsored by the In- ternational Geosphere- Biosphere

Calibrating NIST SRM 683 as A New International Reference Standard for Zn Isotopes

NASA Astrophysics Data System (ADS)

Yang, Y.; Zhang, X.; Yu, H.; Huang, F.

2017-12-01

Zinc isotopes have been widely applied in the cosmochemical, geochemical, and environmental studies (Moynier et al. 2017). Obtaining precise Zn isotopic data for inter-laboratory comparison is a prerequisite to these applications. Currently, the JMC3-0749L is the primary reference standard for Zn isotopes (Albarède 2004), but it is not commercially available now. Thus, it is necessary to calibrate a new international primary reference standard for Zn isotopic analysis. Chen et al. (2016) showed that NIST SRM 683 (a pure Zn metal nugget of 140 grams) has a δ66ZnJMC of 0.12‰, which is falling within the range of natural Zn isotopic compositions, and it may a good candidate for the next generation of international reference standard (Chen et al. 2016). In order to further examine whether NIST SRM 683 has a homogeneous Zn isotopic composition, we measured more NIST SRM 683 by double-spike methods using MC-ICPMS (Conway et al. 2013). The metal nuggets of NIST SRM 683 were intensively sampled by micro-drilling. Zinc isotope analyses for two nuggets show that they have δ66Zn of 0.14 ± 0.02‰ (2SD, N = 32) and 0.13 ± 0.02‰ (2SD, N = 33), respectively. These values are similar to those of two Zn metal nuggets (0.11 ± 0.02‰ vs. 0.12 ± 0.02‰) reported previously by Chen et al. (2016). We fully dissolved one nugget, producing pure Zn solution with identical Zn isotopic composition with the drilling samples. All results strongly support that NIST SRM 683 is homogeneous in Zn isotopic compositions which could be an ideal candidate for the next reference for Zn isotopes. Tests on more metal nuggets will be performed in a few months for further confirming the Zn isotope compositions and homogeneity. Reference: Albarède et al., 2004. 'The stable isotope geochemistry of copper and zinc', Reviews in Mineralogy and Geochemistry, 55: 409-27. Chen et al., 2016. 'Zinc Isotopic Compositions of NIST SRM 683 and Whole-Rock Reference Materials', Geostandards and Geoanalytical Research, 40: 417-32. Conway et al., 2013. 'A new method for precise determination of iron, zinc and cadmium stable isotope ratios in seawater by double-spike mass spectrometry', Analytica chimica acta, 793: 44-52. Moynier et al., 2017. 'The isotope geochemistry of zinc and copper', Reviews in Mineralogy and Geochemistry, 82: 543-600.

Questa baseline and premining ground-water quality investigation. 8. Lake-sediment geochemical record from 1960 to 2002, Eagle Rock and Fawn Lakes, Taos County, New Mexico

USGS Publications Warehouse

Church, S.E.; Fey, D.L.; Marot, M.E.

2005-01-01

Geochemical studies of lake sediment from Eagle Rock Lake and upper Fawn Lake were conducted to evaluate the effect of mining at the Molycorp Questa porphyry molybdenum deposit located immediately north of the Red River. Two cores were taken, one from each lake near the outlet where the sediment was thinnest, and they were sampled at 1-cm intervals to provide geochemical data at less than 1-year resolution. Samples from the core intervals were digested and analyzed for 34 elements using ICP-AES (inductively coupled plasma-atomic emission spectrometry). The activity of 137Cs has been used to establish the beginning of sedimentation in the two lakes. Correlation of the geochemistry of heavy-mineral suites in the cores from both Fawn and Eagle Rock Lakes has been used to develop a sedimentation model to date the intervals sampled. The core from upper Fawn Lake, located upstream of the deposit, provided an annual sedimentary record of the geochemical baseline for material being transported in the Red River, whereas the core from Eagle Rock Lake, located downstream of the deposit, provided an annual record of the effect of mining at the Questa mine on the sediment in the Red River. Abrupt changes in the concentrations of many lithophile and deposit-related metals occur in the middle of the Eagle Rock Lake core, which we correlate with the major flood-of-record recorded at the Questa gage at Eagle Rock Lake in 1979. Sediment from the Red River collected at low flow in 2002 is a poor match for the geochemical data from the sediment core in Eagle Rock Lake. The change in sediment geochemistry in Eagle Rock Lake in the post-1979 interval is dramatic and requires that a new source of sediment be identified that has substantially different geochemistry from that in the pre-1979 core interval. Loss of mill tailings from pipeline breaks are most likely responsible for some of the spikes in trace-element concentrations in the Eagle Rock Lake core. Enrichment of Al2O3, Cu, and Zn occurred as a result of chemical precipitation of these metals from ground water upstream in the Red River. Comparisons of the geochemistry of the post-1979 sediment core with both mine wastes and with premining sediment from the vicinity of the Questa mine indicate that both are possible sources for this new component of sediment. Existing data have not resolved this enigma.

Global Lunar Geochemistry and Its Significant Parallel With Terrestrial One

NASA Astrophysics Data System (ADS)

Kochemasov, G.

Planetary geochemistry reflects planetary tectonic pattern. The most global tectonic feature is the ubiquitous dichotomy (Theorem 1, [1]) with one hemisphere of a di- minished radius (concave) opposed by the convex hemisphere with an increased ra- dius. The terrestrial case is well known: the pressed in Pacific hemisphere is opposed by the bulging out continental one. This tectonics finds its demonstration in global geochemistry: the concave part is filled with denser basalts, rich in Fe, Ti, and the convex part is built of more acidic less dense lithologies, on average of andesitic composition. Much smaller Moon (almost 100 times less massive) reveals the same tectonic-geochemical construction. The near concave side is occupied by Procellarum basin and large marea filled with dense basalts rich in Fe, Ti. The far convex side is built of less dense anarthosites. On both planetary bodies the convex hemispheres are complicated by large subsided sectors (Theorem 2, [1]) filled with, as required by Theorem 4 [1], denser basalts. At Earth it is the Indoceanic sector, on the Moon the South Pole-Aitken basin. Genetically they are similar and constitute regular parts of global tectono-geochemistry (here there is no place for random impact or plate tec- tonic origin of these deep global depressions, they are components of "wave1-wave2" produced structures). The Lunar Prospector global geochemical coverage [2] allows to make lunar - terrestrial parallels not only in dichotomic distribution of iron and ti- tanium but also in distribution of potassium and thorium marking a contact between two dichotomic hemispheres. At Earth the seismically active contact is famous by its andesitic volcanism. Andesites comparative to basalts are richer in K and Th. On the Moon this transitional zone between the dichotomic halves is enriched with Th and K as well [2]. The transition to highlands requires less dense than mare basalts lithologies and they appear as feldspar-rich KREEP basalts enriched with K and Th. The geochemical parallel between two planetary bodies is not occasional and is a con- sequence of the wave planetary tectonics. References: [1] Kochemasov G.G. (1999) Theorems of wave planetary tectonics //Geophys. Res. Abstr., v.1, #3, 700; [2]Chevrel 1 S.D., Pinet P.C., Daydou Y. et al (2001) Global scale multielement analysis of the lunar surface using iron, titanium and thorium abundances // 34th Vernadsky-Brown microsymposium. Topics in comparative planetology. Moscow, Vernadsky Inst., Oct. 8-9, 2001,Abstracts, (CD-ROM).

Teaching Mineralogy, Petrology and Geochemistry in the 21st Century: Instructional Resources for Geoscience Faculty

NASA Astrophysics Data System (ADS)

Mogk, D. W.; Beane, R. J.; Whitney, D. L.; Nicolaysen, K. E.; Panero, W. R.; Peck, W. H.

2011-12-01

Mineralogy, petrology and geochemistry (MPG) are pillars of the geoscience curriculum because of their relevance in interpreting Earth history and processes, application to geo-hazards, resources, and environmental issues, and contributions to emerging fields such as geology and human health. To keep faculty current in scientific advances in these fields, and in modern instructional methods, the On the Cutting Edge program convened a workshop at the University of Minnesota in August, 2011. This workshop builds on the previous 15 year's work that has been focused on identifying, aggregating, and developing high-quality collections of teaching activities and related resources, and in building a community of scholars in support of excellence in instruction in MPG courses. The goals of the workshop were to: a) develop an integrated, comprehensive and reviewed curriculum for MPG courses, and to seek ways to make connections with the larger geoscience curriculum; b) to explore emerging topics in MPG such as geobiology and climate change; c) demonstrate effective methods in teaching MPG in the context of Earth system science; d) share effective teaching activities and strategies for the classroom, laboratory and field including advances in pedagogy, assessments and research on learning; e) keep faculty current on recent advances in mineralogy, petrology and geochemistry research and to apply these findings to our teaching; f) explore and utilize current societal and global issues that intersect mineralogy, petrology and geochemistry to heighten the relevancy of course content for students; and h) meet colleagues and foster future teaching and research collaborations. A significant outcome of this workshop is a peer reviewed of collection of 300+ existing teaching activities, and a gap analysis to identify teaching activities needed to make these collections comprehensive and coherent. In addition, a series of thematic collections were developed to assist high priority areas of teaching MPG (e.g. MPG in Introductory Geoscience Courses-Beyond "Rocks in a Box"; thermobarometry programs). All demonstrations and presentations made at the workshop are accessible from the workshop webpage, including a wide variety of active learning exercises and demonstrations of modern computer applications (e.g. SHAPE, ATOMS, CrystalMaker, MELTS, Theriak-Domino, Perplex, TWQ, Google Earth and Gigapans, and PHREEQC). A post-workshop field trip to the Precambrian rocks of northern Minnesota focused on effective teaching and learning in the field. We encourage the geoscience community to use these online resources, and please consider contributing additional teaching activities and resources to these collections.

STATISTICAL ANALYSIS OF GROUNDWATER GEOCHEMISTRY DATA FROM AREA 6, DOVER AIR FORCE BASE, DOVER, DELAWARE

EPA Science Inventory

The work described in this report is part of a project undertaken by the Bioremediation of Chlorinated Solvents Action Team of the Remediation Technologies Development Forum, a joint U.S. Federal agency-industry collaboration, to study the natural attenuation of chlorinated ethen...

Using integrated noble gas and hydrocarbon geochemistry to constrain the source of hydrocarbon gases in shallow aquifers in the northern Appalachian Basin

EPA Pesticide Factsheets

Rising demands for domestic energy sources, mandates for cleaner burning fuels for electricity generation, and the approach of peak global hydrocarbon production are driving the transformation from coal to natural gas from unconventional energy resources.

MODELING OF HEAVY METAL MOVEMENT IN VEGETATED, UNSATURATED SOILS WITH EMPHASIS ON GEOCHEMISTRY. (R825549C046)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

The Twenty-Fifth Lunar and Planetary Science Conference. Part 2: H-O

NASA Technical Reports Server (NTRS)

1994-01-01

Various papers on lunar and planetary science are presented, covering such topics as: planetary geology, lunar geology, meteorites, shock loads, cometary collisions, planetary mapping, planetary atmospheres, chondrites, chondrules, planetary surfaces, impact craters, lava flow, achondrites, geochemistry, stratigraphy, micrometeorites, tectonics, mineralogy, petrology, geomorphology, and volcanology.

A Classroom Simulation of Water-Rock Interaction for Upper-Level Geochemistry Courses.

ERIC Educational Resources Information Center

Cercone, Karen Rose

1988-01-01

Describes a simple hands-on model of water-rock interaction that can be constructed in the classroom using styrofoam bowls and foil-wrapped candies. This interactive simulation allows students to vary the factors which control water-rock interaction and to obtain immediate results. (Author/CW)

Geochemical Exploration of the Moon.

ERIC Educational Resources Information Center

Adler, Isidore

1984-01-01

Provides information based on explorations of the Apollo program about the geochemistry of the moon and its importance in developing an understanding of formation/evolution of the solar system. Includes description and some results of orbital remote sensing, lunar x-ray experiments, gamma-ray experiments, alpha-particle experiments, and the Apollo…

Selenium geochemistry in reclaimed phosphate mine soils and its relationship with plant bioavailability

USDA-ARS?s Scientific Manuscript database

Background and Aims Selenium contamination and accumulation in vegetation have resulted in Se toxicity in livestock and wildlife in reclaimed phosphate mine soils in Southeastern Idaho. Methods Plant and soil samples were collected from five study sites near phosphate mines. Soil physiochemical pr...

HYDROGIOLOGIC FRAMEWORK, GROUND-WATER GEOCHEMISTRY, AND ASSESSMENT OF NITROGEN YIELD FROM BASE FLOW IN TWO AGRICULTURAL WATERSHEDS, KENT COUNTY, MARYLAND

EPA Science Inventory

Hydrostratigraphic and geochemical data collected in two adjacent watersheds on the Delmarva Peninsula, in Kent County, Maryland, indicate that shallow subsurface stratigraphy is an important factor that affects the concentrations of nitrogen in ground water discharging as stream...

Crude oil in a shallow sand and gravel aquifer—I. Hydrogeology and inorganic geochemistry

USGS Publications Warehouse

Bennett, P.C.; Siegel, D.E.; Baedecker, M.J.; Hult, M.F.

1993-01-01

The observed changes in inorganic aqueous chemistry document changes in water-mineral interactions caused by the presence of an organic contaminant. These organic-initiated interactions are likely present in many contaminated aquifers and may be analogous to interactions occurring in other organic-rich natural waters.

A REVIEW OF BIOMARKER COMPOUNDS AS SOURCE INDICATORS AND TRACERS FOR AIR POLLUTION (R823990)

EPA Science Inventory

An overview of the application of organic geochemistry to the analysis of organic matter on aerosol particles is presented here. This organic matter is analyzed as solvent extractable
bitumen/lipids by gas chromatography-mass spectrometry. The organic geochemical approach asse...

SUPPORT OF MSA AND GS SHORT COURSES AND THE COMPANION REVIEWS VOLUMES

DOE Office of Scientific and Technical Information (OSTI.GOV)

J Alex Speer

2008-01-23

Report on two short courses: [1] Fluid-fluid Equilibria in the Crust: Petrology - Geochemistry - Economic potential. August 16-17, 2007 preceding the Goldschmidt Conference in Cologne, Germany) and [2] Paleoaltimetry: Geochemical And Thermodynamic Approaches. October 26-27, 2007 (preceding the GSA Annual Meeting in Denver, Colorado)

New Isotopic Tracers for Shale Gas and Hydraulic Fracturing Fluids

EPA Pesticide Factsheets

The combined application of geochemistry, stable isotopes (δ18O, δ2H), strontium isotopes (87Sr/86Sr), boron isotopes (δ11B), and radium isotopes (228Ra/226Ra) provides a unique methodology for tracing and monitoring shale gas and fracking fluids in the environment.

Nitrogen fate and transport through palustrine depressional wetlands along an alteration gradient in an agricultural landscape, upper Choptank Watersheds, Maryland, USA

USDA-ARS?s Scientific Manuscript database

Understanding local groundwater hydrology and geochemistry is critical for evaluating the effectiveness of wetlands at mitigating agricultural impacts on surface waters. The effectiveness of forested, prior-converted cropland (historic wetlands), and restored palustrine depressional wetlands at miti...

Cascades/Aleutian Play Fairway Analysis: Data and Map Files

DOE Data Explorer

Lisa Shevenell

2015-11-15

Contains Excel data files used to quantifiably rank the geothermal potential of each of the young volcanic centers of the Cascade and Aleutian Arcs using world power production volcanic centers as benchmarks. Also contains shapefiles used in play fairway analysis with power plant, volcano, geochemistry and structural data.

The Twenty-Fifth Lunar and Planetary Science Conference. Part 3: P-Z

NASA Technical Reports Server (NTRS)

1994-01-01

Various papers on lunar and planetary science are presented, covering such topics as: impact craters, tektites, lunar geology, lava flow, geodynamics, chondrites, planetary geology, planetary surfaces, volcanology, tectonics, topography, regolith, metamorphic rock, geomorphology, lunar soil, geochemistry, petrology, cometary collisions, geochronology, weathering, and meteoritic composition.

SEAGRASS STRESS RESPONSE MODEL: THE IMPORTANCE OF LIGHT, TEMPERATURE, SEDIMENTATION AND GEOCHEMISTRY

EPA Science Inventory

Our objective is to define interactions between seagrass and water-column and sediment stressors. The model was developed and optimized for sediments in Thalassia testudinum seagrass beds of Lower Laguna Madre, Texas, USA and is composed of a plant sub-model and a sediment diagen...

STRESS RESPONSE MODEL FOR THE TROPICAL SEAGRASS THALASSIA TESTUDINUM: THE INTERACTIONS OF LIGHT, TEMPERATURE, SEDIMENTATION AND GEOCHEMISTRY

EPA Science Inventory

Our modeling objective was to better define the relationship between a tropical seagrass and water-column and sediment stressors (i.e., light, organic and particle sedimentation, sediment nutrients and sulfides). The model was developed and optimized for sediments in Thalassia t...

DIAGNOSIS OF TRACE PB IN DOMESTIC WELLS, UPPER GLOUCESTER CATCHMENT, MAINE

EPA Science Inventory

Dissolved Pb in 32 wells associated with corroding submersible pumps is examined within a rural water district after almost 20 years (1984 to 2002). Groundwater Pb ranged from 0.4 – 24.9 µg L^-1 after 24 hr pump flushing. Preliminary geochemistry and represent...

Mars Observer: Phase 0 safety review data package

NASA Technical Reports Server (NTRS)

1986-01-01

The Mars Observer Program has as its primary objectives a study of the geochemistry, atmospheric dynamics, atmosphere/surface interactions, seasonal variations, and magnetic field characteristics of Mars. The Mars Observer Spacecraft, safety critical spacecraft subsystems, ground support equipment, ground operations scenario, requirements matrix, and equipment specifications are described.

Publications of the exobiology program for 1981: A special bibliography

NASA Technical Reports Server (NTRS)

Pleasant, L. G. (Compiler); Devincenzi, D. L. (Compiler)

1982-01-01

The exobiology program investigates the planetary events which were responsible for, or, related to, the origin, evolution, and distribution of life in the universe. The areas involved include: chemical evolution, organic geochemistry, origin and evolution of life, planetary environments, life in the universe, planetary protection, and Mars data analysis.

Relation of specific conductance in ground water to intersection of flow paths by wells, and associated major ion and nitrate geochemistry, Barton Springs Segment of the Edwards Aquifer, Austin, Texas, 1978-2003

USGS Publications Warehouse

Garner, Bradley D.; Mahler, Barbara J.

2007-01-01

Understanding of karst flow systems can be complicated by the presence of solution-enlarged conduits, which can transmit large volumes of water through the aquifer rapidly. If the geochemistry at a well can be related to streamflow or spring discharge (springflow), or both, the relations can indicate the presence of recent recharge in water at the well, which in turn might indicate that the well intersects a conduit (and thus a major flow path). Increasing knowledge of the occurrence and distribution of conduits in the aquifer can contribute to better understanding of aquifer framework and function. To that end, 26 wells in the Barton Springs segment of the Edwards aquifer, Austin, Texas, were investigated for potential intersection with conduits; 26 years of arbitrarily timed specific conductance measurements in the wells were compared to streamflow in five creeks that provide recharge to the aquifer and were compared to aquifer flow conditions as indicated by Barton Springs discharge. A nonparametric statistical test (Spearman's rho) was used to divide the 26 wells into four groups on the basis of correlation of specific conductance of well water to streamflow or spring discharge, or both. Potential relations between conduit intersection by wells and ground-water geochemistry were investigated through analysis of historical major ion and nitrate geochemistry for wells in each of the four groups. Specific conductance at nine wells was negatively correlated with both streamflow and spring discharge, or streamflow only. These correlations were interpreted as evidence of an influx of surface-water recharge during periods of high streamflow and the influence at the wells of water from a large, upgradient part of the aquifer; and further interpreted as indicating that four wells intersect major aquifer flow paths and five wells intersect minor aquifer flow paths (short, tributary conduits). Specific conductance at six wells was positively correlated with spring discharge, which was interpreted as not intersecting a flow path (conduit). Of the 11 wells for which specific conductance did not correlate with either streamflow or spring discharge, no interpretations regarding flow-path intersection by wells were made. In some cases, specific conductance data might not have indicated intersection with a flow path because of small sample sets. Water in the Barton Springs segment generally is a calcium-magnesium-bicarbonate type, although some water compositions deviate from this. Multiple geochemical processes were identified that might affect geochemistry at the wells, but in general the geochemical composition of ground water, except for dilution by surface-water recharge, was not related to intersection of a well with a flow path. Some samples from wells indicate inflow of water from the saline zone to the east; this inflow is associated with low streamflow and spring discharge. Other samples indicate that the aquifer at some wells might be receiving water that has been in contact with rocks of the Trinity aquifer; this mixing is most evident when spring discharge is high. Occurrence of nitrate in ground water was unrelated to intersection of flow paths by wells and appeared to be the result of localized contamination. However, most of the wells with one or more samples contaminated by nitrate are in the more densely populated parts of the study area.

Publications - PDF 96-18 | Alaska Division of Geological & Geophysical

Science.gov Websites

content DGGS PDF 96-18 Publication Details Title: Major and trace element analyses of Cretaceous plutonic Bibliographic Reference Newberry, R.J., 1996, Major and trace element analyses of Cretaceous plutonic rocks in pdf1996_018.pdf (571.0 K) Keywords Geochemistry; Geology; Igneous Rocks; Major Oxides; Plutonic Rocks

Reports of Planetary Geology and Geophysics Program, 1984

NASA Technical Reports Server (NTRS)

Holt, H. E. (Compiler); Watters, T. R. (Compiler)

1985-01-01

Topics include outer planets and satellites; asteroids and comets; Venus; lunar origin and solar dynamics; cratering process; planetary interiors, petrology, and geochemistry; volcanic processes; aeolian processes and landforms; fluvial processes; geomorphology; periglacial and permafrost processes; remote sensing and regolith studies; structure, tectonics, and stratigraphy; geological mapping, cartography, and geodesy; and radar applications.

Catalog of Computer Programs Used in Undergraduate Geological Education, Second Edition: Installment 2.

ERIC Educational Resources Information Center

Burger, H. Robert

1983-01-01

Part 1 (SE 533 635) presented programs for use in mineralogy, petrology, and geochemistry. This part presents an annotated list of 64 additional programs, focusing on introductory geology, mapping, and statistical packages for geological analyses. A brief description, source, suggested use(s), programing language, and other information are…

INFLUENCE OF GROUNDWATER GEOCHEMISTRY ON THE LONG-TERM PERFORMANCE OF IN-SITU PERMEABLE REACTIVE BARRIERS CONTAINING ZERO-VALENT IRON

EPA Science Inventory

Reactive barriers that couple subsurface fluid flow with a passive chemical treatment zone are emerging, cost effective approaches for in-situ remediation of contaminated groundwater. Factors such as the build-up of surface precipitates, bio-fouling, and changes in subsurface tr...

Laboratory simulation of organic geochemical processes.

NASA Technical Reports Server (NTRS)

Eglinton, G.

1972-01-01

Discussion of laboratory simulations that are important to organic geochemistry in that they provide direct evidence relating to geochemical cycles involving carbon. Reviewed processes and experiments include reactions occurring in the geosphere, particularly, short-term diagenesis of biolipids and organochlorine pesticides in estuarine muds, as well as maturation of organic matter in ancient sediments.

Fourteenth workshop geothermal reservoir engineering: Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ramey, H.J. Jr.; Kruger, P.; Horne, R.N.

1989-01-01

The Fourteenth Workshop on Geothermal Reservoir Engineering was held at Stanford University on January 24--26, 1989. Major areas of discussion include: (1) well testing; (2) various field results; (3) geoscience; (4) geochemistry; (5) reinjection; (6) hot dry rock; and (7) numerical modelling. For these workshop proceedings, individual papers are processed separately for the Energy Data Base.

Organic geochemistry of core samples from an ultradeep hot well (300°C, 7 km)

USGS Publications Warehouse

Price, Leigh C.

1982-01-01

Concepts prevelant among petroleum organic geochemists concerning the thermal fate of hydrocarbons, with subsequent graphite formation, and greenschist metamorphism, are in sharp contradiction to these data. Conventional concepts of the distribution of heavy hydrocarbons with increasing temperature and depth apparently require further review and revision.

Chemical Geology: An Annotated Bibliography. CEGS Programs Publication Number 11.

ERIC Educational Resources Information Center

Billings, Gale K.

The annotated bibliography is intended to aid geologists whose primary background is not in geochemistry. The references thus range from chemistry texts to papers on complex geochemical applications. The emphasis has been on those books and papers concerned with the application of chemical concepts to geology. Citations are arranged topically to…

Three Techniques to Help Students Teach Themselves Concepts in Environmental Geochemistry.

ERIC Educational Resources Information Center

Brown, I. Foster

1984-01-01

Describes techniques in which students learn to: (1) create elemental "fairy tales" based on the geochemical behavior of elements and on imagination to integrate concepts; (2) to visually eliminate problems of bias; and (3) to utilize multiple working hypotheses as a basis for testing concepts of classification and distinguishing…

David L. Parkhurst as the recipient of the 2012 O.E. Meinzer Award of the Hydrogeology Division of the Geological Society of America

USGS Publications Warehouse

Glynn, Pierre D.

2012-01-01

Describes the impact of USGS scientist David Parkhurst's influential contributions to the fields of aqueous geochemistry and hydrogeology. Parkhurst is the recipient of the 2012 O.E. Meinzer award of the Geological Society of America's Hydrogeology Division.

Workshop on Viability of Halophilic Bacteria in Salt Deposits

NASA Technical Reports Server (NTRS)

1997-01-01

The significance of finding viable extreme halophiles in halites associated with Permian-aged sedimentary deposits is considered. Issues related to the microbiology and geochemistry of the halite environment are addressed. Recommendations that related the significance of this phenomenon to NASA's interest in planetary exploration and the early evolution of life are provided.

Fourteenth workshop geothermal reservoir engineering: Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ramey, H.J. Jr.; Kruger, P.; Horne, R.N.

The Fourteenth Workshop on Geothermal Reservoir Engineering was held at Stanford University on January 24--26, 1989. Major areas of discussion include: (1) well testing; (2) various field results; (3) geoscience; (4) geochemistry; (5) reinjection; (6) hot dry rock; and (7) numerical modelling. For these workshop proceedings, individual papers are processed separately for the Energy Data Base.

Delicacy, Imprecision, and Uncertainty of Oceanic Simulations: An Investigation with the Regional Oceanic Modeling System (ROMS)

DTIC Science & Technology

2013-09-30

Geochemistry and Ecosystems: An important community use for ROMS is biogeochemisty: chemical cycles, water quality, blooms , micro-nutrients, larval...Sci., submitted. Colas, F., J.C. McWilliams, X. Capet, and J. Kurian, 2012: Heat balance and eddies in the Peru- Chile Current System. Climate

Fallon, Nevada Geophysics and Geochemistry

DOE Data Explorer

Doug Blankenship

2016-05-23

The data is associated to the Fallon FORGE project and includes mudlogs for all wells used to characterize the subsurface, as wells as gravity, magnetotelluric, earthquake seismicity, and temperature data from the Navy GPO and Ormat. Also included are geologic maps from the USGS and Nevada Bureau of Mines and Geology for the Fallon, NV area.

Publications - GMC 405 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 405 Publication Details Title: Geochemical analyses of oil and gas cuttings from the of Alaska, and TestAmerica Laboratories, Inc., 2012, Geochemical analyses of oil and gas cuttings (265.0 K) Keywords Geochemistry; Oil and Gas Top of Page Department of Natural Resources, Division of

Workshop on Geology of the Apollo 17 Landing Site

NASA Technical Reports Server (NTRS)

Ryder, G. (Editor); Schmitt, H. H. (Editor); Spudis, P. D. (Editor)

1992-01-01

The topics covered include the following: petrology, lithology, lunar rocks, lunar soil, geochemistry, lunar geology, lunar resources, oxygen production, ilmenite, volcanism, highlands, lunar maria, massifs, impact melts, breccias, lunar crust, Taurus-Littrow, minerals, site selection, regolith, glasses, geomorphology, basalts, tectonics, planetary evolution, anorthosite, titanium oxides, chemical composition, and the Sudbury-Serenitatis analogy.

Papers presented to the Conference on Luna 24. [lunar soil studies

NASA Technical Reports Server (NTRS)

1977-01-01

Topics covered include: the regional geology, geochemistry, and geophysics of Mare Crisium and the Luna 24 landing site; the petrology, mineral chemistry, and cooling histories of lithic fragments, the chemistry, isotopic studies, and geochronology of Luna 24 samples; and regolith studies of soil samples. Subject and topical indexes are provided.

THE HYDRAULIC CHARACTERISTICS AND GEOCHEMISTRY OF HYPORHEIC AND PARAFLUVIAL ZONES IN ARCTIC TUNDRA STREAMS, NORTH SLOPE, ALASKA

EPA Science Inventory

Sodium bromide and Rhodamine WT were used as conservative tracers to examine the hydrologic characteristics of seven tundra streams in Arctic Alaska, during the summers of 1994-1996. Continuous tracer additions were conducted in seven rivers ranging from 1st to 5th order with sam...

Sedimentary Rocks and Methane - Southwest Arabia Terra

NASA Technical Reports Server (NTRS)

Allen, Carlton C.; Oehler, Dorothy Z.; Venechuk, Elizabeth M.

2006-01-01

We propose to land the Mars Science Laboratory in southwest Arabia Terra to study two key aspects of martian history the extensive record of sedimentary rocks and the continuing release of methane. The results of this exploration will directly address the MSL Scientific Objectives regarding biological potential, geology and geochemistry, and past habitability.

Geochemistry of biomolecules

NASA Technical Reports Server (NTRS)

Bonner, J.

1976-01-01

A highly sensitive fluorometric technique is developed for the determination of biological and geo-organic compounds in ancient sediments and extraterrestrial samples. This technique is used to establish chemical evidence for fossil pigments in an extraterrestrial sample. Also developed is a highly sensitive and specific fluorometric method for the determination of total primary amine nitrogen in soil samples.

Rock geochemistry related to mineralization processes in geothermal areas

NASA Astrophysics Data System (ADS)

Kausar, A. Al; Indarto, S.; Setiawan, I.

2018-02-01

Abundant geothermal systems in Indonesia suggest high heat and mass transfer associated with recent or paleovolcanic arcs. In the active geothermal system, the upflow of mixed fluid between late stage hydrothermal and meteoric water might contain mass of minerals associated with epithermal mineralisation process as exemplified at Lihir gold mine in Papua New Guinea. In Indonesia, there is a lack of study related to the precious metals occurrence within active geothermal area. Therefore, in this paper, we investigate the possibility of mineralization process in active geothermal area of Guci, Central Java by using geochemical analysis. There are a lot of conducted geochemical analysis of water, soil and gas by mapping the temperature, pH, Hg and CO2 distribution, and estimating subsurface temperature based on geothermometry approach. Then we also apply rock geochemistry to find minerals that indicate the presence of mineralization. The result from selected geothermal area shows the presence of pyrite and chalcopyrite minerals on the laharic breccias at Kali Putih, Sudikampir. Mineralization is formed within host rock and the veins are associated with gold polymetallic mineralization.

Volatile transport on Venus and implications for surface geochemistry and geology

NASA Technical Reports Server (NTRS)

Brackett, Robert A.; Fegley, Bruce; Arvidson, Raymond E.

1995-01-01

The high vapor pressure of volatile metal halides and chalcogenides (e.g., of Cu, Zn, Sn, Pb, As, Sb, Bi) at typical Venus surface temperatures, coupled with the altitude-dependent temperature gradient of approximately 8.5 K/km, is calculated to transport volatile metal vapors to the highlands of Venus, where condensation and accumulation will occur. The predicted geochemistry of volatile metals on Venus is supported by observations of CuCl in volcanic gases at Kilauea and Nyiragongo, and large enrichments of these and other volatile elements in terrestrial volcanic aerosols. A one-dimensional finite difference vapor transport model shows the diffusive migration of a thickness of 0.01 to greater than 10 microns/yr of moderately to highly volatile phases (e.g., metal halides and chalcogenides) from the hot lowlands (740 K) to the cold highlands (660 K) on Venus. The diffusive transport of volatile phases on Venus may explain the observed low emissivity of the Venusian highlands, hazes at 6-km altitude observed by two Pioneer Venus entry probes, and the Pioneer Venus entry probe anomalies at 12.5 km.

Climatic Constraints on Growth Rate and Geochemistry (Sr/Ca and U/Ca) of the Coral Siderastrea stellata in the Southwest Equatorial Atlantic (Rocas Atoll, Brazil)

NASA Astrophysics Data System (ADS)

Evangelista, H.; Sifeddine, A.; Corrège, T.; Servain, J.; Dassié, E. P.; Logato, R.; Cordeiro, R. C.; Shen, C.-C.; Le Cornec, F.; Nogueira, J.; Segal, B.; Castagna, A.; Turcq, B.

2018-03-01

Although relatively rare compared to similar latitudes in the Pacific or Indian Oceans, massive coral colonies are present in the Tropical/Equatorial Southwestern Atlantic Ocean. However, detailed geochemical compositions of these corals are still largely unknown. In this work, we present growth rates, Sr/Ca, and U/Ca ratios of the coral colony (Siderastrea stellata) sampled at Rocas Atoll, off the Brazilian coast. These variables are primarily affected by sea surface temperature (SST) at seasonal scale, and by wind stress at interannual scale, these results represent a broad new finding. A lower significance at the interannual time scale between Sr/Ca and U/Ca with respect to SST is attributed to the low SST amplitude closed to Equator. An investigation on the dependence of coral growth rates with respect to the "cloud shading effect" promoted by the Intertropical Convergence Zone (ITCZ) does not show significant influence. Additionally, rain seems to act on local geochemistry of Sr/Ca ratios and growth rate at the decadal scale.

Characterization of the geology, geochemistry, hydrology and microbiology of the in-situ air stripping demonstration site at the Savannah River Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eddy, C.A.; Looney, B.B.; Dougherty, J.M.

1991-05-01

The Savannah River Site is the location of an Integrated Demonstration Project designed to evaluate innovative remediation technologies for environmental restoration at sites contaminated with volatile organic contaminants. This demonstration utilizes directionally drilled horizontal wells to deliver gases and extract contaminants from the subsurface. Phase I of the Integrated Demonstration focused on the application and development of in-situ air stripping technologies to remediate soils and sediments above and below the water table as well as groundwater contaminated with volatile organic contaminants. The objective of this report is to provide baseline information on the geology, geochemistry, hydrology, and microbiology of themore » demonstration site prior to the test. The distribution of contaminants in soils and sediments in the saturated zone and groundwater is emphasized. These data will be combined with data collected after the demonstration in order to evaluate the effectiveness of in-situ air stripping. New technologies for environmental characterization that were evaluated include depth discrete groundwater sampling (HydroPunch) and three-dimensional modeling of contaminant data.« less

Alchemy in the underworld - recent progress and future potential of organic geochemistry applied to speleothems.

NASA Astrophysics Data System (ADS)

Blyth, Alison

2016-04-01

Speleothems are well used archives for chemical records of terrestrial environmental change, and the integration of records from a range of isotopic, inorganic, and organic geochemical techniques offers significant power in reconstructing both changes in past climates and identifying the resultant response in the overlying terrestrial ecosystems. The use of organic geochemistry in this field offers the opportunity to recover new records of vegetation change (via biomarkers and compound specific isotopes), temperature change (via analysis of glycerol dialkyl glycerol tetraethers, a compound group derived from microbes and varying in structure in response to temperature and pH), and changes in soil microbial behaviour (via combined carbon isotope analysis). However, to date the use of organic geochemical techniques has been relatively limited, due to issues relating to sample size, concerns about contamination, and unanswered questions about the origins of the preserved organic matter and rates of transport. Here I will briefly review recent progress in the field, and present a framework for the future research needed to establish organic geochemical analysis in speleothems as a robust palaeo-proxy approach.

The application of iodine and magnetic susceptibility surface geochemical surveys in the Lodgepole Play, Eastern Williston Basin, North Dakota

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tedesco, S.A.

1996-06-01

The use of surface geochemistry as a first pass exploration tool is becoming more prevalent in petroleum exploration. This is especially true due to the high cost of 2-D and 3-D surveys in defining small targets such as the Waulsortian mounds of the Lodgepole Formation. Surface geochemical surveys are very effective in pinpointing specific target areas for seismic surveying and thus reducing costs. Presented are examples of surface geochemical surveys utilizing magnetic susceptibility and iodine methods in delineating reservoirs in the Lodgepole, Mission Canyon and Red River formations. The types of surveys presented vary from reconnaissance to detail and examplesmore » of how to define a grid will be discussed. Surface geochemical surveys can be very effective when the areal extent of the target(s) and the purpose of the survey are clearly defined prior to implementation. By determining which areas have microseepage and which areas do not, surface geochemistry can be a very effective tool in focusing exploration efforts and maximizing exploration dollars.« less

Geochemistry and petrogenesis of a peralkaline granite complex from the Midian Mountains, Saudi Arabia

NASA Astrophysics Data System (ADS)

Harris, N. B. W.; Marriner, G. F.

1980-10-01

A zoned intrusion with a biotite granodiorite core and arfvedsonite granite rim represents the source magma for an albitised granite plug near its eastern margin and radioactive siliceous veins along its western margin. A study of selected REE and trace elements of samples from this complex reveals that the albitised granite plug has at least a tenfold enrichment in Zr, Hf, Nb, Ta, Y, Th, U and Sr, and a greatly enhanced heavy/light REE ratio compared with the peralkaline granite. The siliceous veins have even stronger enrichment of these trace elements, but a heavy/light REE ratio and negative eu anomaly similar to the peralkaline granite. It is suggested that the veins were formed from acidic volatile activity and the plug from a combination of highly fractionated magma and co-existing alkaline volatile phase. The granodiorite core intrudes the peralkaline granite and has similar trace element geochemistry. The peralkaline granite is probably derived from the partial melting of the lower crust in the presence of halide-rich volatiles, and the granodiorite from further partial melting under volatile-free conditions.

MESSENGER, MErcury: Surface, Space ENvironment, GEochemistry, and Ranging; A Mission to Orbit and Explore the Planet Mercury

NASA Technical Reports Server (NTRS)

1999-01-01

MESSENGER is a scientific mission to Mercury. Understanding this extraordinary planet and the forces that have shaped it is fundamental to understanding the processes that have governed the formation, evolution, and dynamics of the terrestrial planets. MESSENGER is a MErcury Surface, Space ENvironment, GEochemistry and Ranging mission to orbit Mercury for one Earth year after completing two flybys of that planet following two flybys of Venus. The necessary flybys return significant new data early in the mission, while the orbital phase, guided by the flyby data, enables a focused scientific investigation of this least-studied terrestrial planet. Answers to key questions about Mercury's high density, crustal composition and structure, volcanic history, core structure, magnetic field generation, polar deposits, exosphere, overall volatile inventory, and magnetosphere are provided by an optimized set of miniaturized space instruments. Our goal is to gain new insight into the formation and evolution of the solar system, including Earth. By traveling to the inner edge of the solar system and exploring a poorly known world, MESSENGER fulfills this quest.

Marine-influenced microbial communities inhabit terrestrial hot springs on a remote island volcano.

PubMed

Stewart, Lucy C; Stucker, Valerie K; Stott, Matthew B; de Ronde, Cornel E J

2018-07-01

Raoul Island is a subaerial island volcano approximately 1000 km northeast of New Zealand. Its caldera contains a circumneutral closed-basin volcanic lake and several associated pools, as well as intertidal coastal hot springs, all fed by a hydrothermal system sourced from both meteoric water and seawater. Here, we report on the geochemistry, prokaryotic community diversity, and cultivatable abundance of thermophilic microorganisms of four terrestrial features and one coastal feature on Raoul. Hydrothermal fluid contributions to the volcanic lake and pools make them brackish, and consequently support unusual microbial communities dominated by Planctomycetes, Chloroflexi, Alphaproteobacteria, and Thaumarchaeota, as well as up to 3% of the rare sister phylum to Cyanobacteria, Candidatus Melainabacteria. The dominant taxa are mesophilic to moderately thermophilic, phototrophic, and heterotrophic marine groups related to marine Planctomycetaceae. The coastal hot spring/shallow hydrothermal vent community is similar to other shallow systems in the Western Pacific Ocean, potentially due to proximity and similarities of geochemistry. Although rare in community sequence data, thermophilic methanogens, sulfur-reducers, and iron-reducers are present in culture-based assays.

(De)Constructing the Undergraduate Research Experience in an Environmental Geochemistry Lab (Invited)

NASA Astrophysics Data System (ADS)

Kim, C. S.

2013-12-01

Maintaining a productive research lab at the undergraduate level requires a savvy combination of internal organization, high (but realistic) expectations, and adaptation of one's research interests into semester- and summer-length projects. Several key strategies can help achieve the goal of building a lab culture that both enriches students' academic experiences and advances one's own scholarly research and visibility. Foremost among these is the need to maintain momentum and preserve institutional knowledge in an environment where undergraduate students' lifetime in an individual lab may only last a year or two. Examples from the Environmental Geochemistry Lab at Chapman University (www.chapman.edu/envgeo) developed over several years and with 40+ undergraduate students will be presented which can be transferable to other faculty research labs in the earth sciences. Approaches to writing successful external research grant proposals at a primarily undergraduate institution (PUI) and strategies for both personal and institutional time management/savings will also be discussed, with a focus on new models at Chapman offered to further incentivize faculty involvement in undergraduate research.

Subseabed Disposal Project annual report, FY85 to termination of project: Physical Oceanography and Water Column Geochemistry Studies, October 1984 through May 1986

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kupferman, S.L.

This report covers the work of the Physical Oceanography and Water Column Geochemistry (POWCG) Studies Group of the Subseabed Disposal Project (SDP) from October 1984 to termination of the project in May 1986. The overview of the work includes an introduction, general descriptions of the activities, and a summary. Detailed discussions are included as appendices. During the period of this report the POWCG Studies Group held a meeting to develop a long-term research plan for the Nares Abyssal Plain, which was recently designated as a study area for the Environmental Study Group of the SDP. The POWCG Studies Group hasmore » also planned and participated in two interdisciplinary oceanographic missions to the Nares which have resulted in the acquisition of data and samples which can be used to begin to understand the workings of the ecosystem at the site, and for developing a preliminary site assessment. The papers in the appendices have been processed for inclusion in the Energy Data Base.« less

Geochemistry of Peralkaline Melts at Kone Volcanic Complex, Main Ethiopian Rift

NASA Astrophysics Data System (ADS)

Iddon, F. E.; Edmonds, M.; Jackson, C.; Hutchison, W.; Mather, T. A.; Fontijn, K.; Pyle, D. M.

2016-12-01

The East Africa rift system (EARS) is the archetypal example of continental rifting, with the Main Ethiopian rift (MER) segment offering a unique opportunity to examine the dynamics of peralkaline magmas; the development of central volcanoes; melt distribution and transport in the crust; the volatile budgets of rift magmas and their implications for the formation of ore deposits. The alkali- and halogen-rich magmas of the MER differ from their calc-alkaline counterparts in other settings due to their lower viscosities and higher volatile contents, which have important implications for magma transport, reservoir dynamics and eruptive hazards. The high halogen contents of the magmas give rise to halogen-rich vapor which has the capacity to transport and concentrate metals and REE. The Kone Volcanic complex is one of the lesser studied Quaternary peralkaline centres, located on the axial portion of the MER. It comprises two superimposed calderas, surrounded by ignimbrite deposits and unwelded felsic pyroclastic material, small basaltic vents and rhyolitic domes. Unusually for the central volcanoes of the MER, the caldera has refilled with basaltic lava, not pyroclastic material. We use whole rock and micro-analysis to characterize a range of Kone tephras, glasses, crystal phases and melt inclusions in terms of major, trace and volatile element abundances, alongside detailed textural analysis using QEMSCAN and SEM. The whole rock geochemistry reflects the clear peralkaline nature of the suite, with a distinct compositional gap between 50 wt% and 65 wt% SiO2, controlled largely by fractional crystallization. Trace element systematics illustrate that trachytes entrain alkali feldspars, with the crystal cargo of the entire suite reflecting the structure of the magma reservoir at depth, with liquid-rich lenses and regions of syenitic mush. Melt inclusion geochemistry allows reconstruction of complex, multiphase differentiation processes and the exsolution of both a vapor phase and a brine, allowing the fluid-melt partitioning behaviour of halogens and metals to be reconstructed.

Geochemical Analyses of Rock, Sediment, and Water from the Region In and Around the Tuba City Landfill, Tuba City, Arizona

USGS Publications Warehouse

Johnson, Raymond H.; Wirt, Laurie

2009-01-01

The Tuba City Landfill (TCL) started as an unregulated waste disposal site in the 1940s and was administratively closed in 1997. Since the TCL closure, radionuclides have been detected in the shallow ground water. In 2006, the Bureau of Indian Affairs (BIA) contracted with the U.S. Geological Survey (USGS) to better understand the source of radionuclides in the ground water at the TCL compared to the surrounding region. This report summarizes those data and presents interpretations that focus on the geochemistry in the rocks and water from the Tuba City region. The TCL is sited on Navajo Sandstone above the contact with the Kayenta Formation. These formations are not rich in uranium but generally are below average crustal abundance values for uranium. Uranium ores in the area were mined nearby in the Chinle Formation and processed at the Rare Metals mill (RMM). Regional samples of rock, sediment, leachates, and water were collected in and around the TCL site and analyzed for major and minor elements, 18O, 2H, 3H, 13C, 14C,34S, 87Sr, and 234U/238U, as appropriate. Results of whole rock and sediment samples, along with leachates, suggest the Chinle Formation is a major source of uranium and other trace elements in the area. Regional water samples indicate that some of the wells within the TCL site have geochemical signatures that are different from the regional springs and surface water. The geochemistry from these TCL wells is most similar to leachates from the Chinle Formation rocks and sediments. Isotope samples do not uniquely identify TCL-derived waters, but they do provide a useful indicator for shallow compared to deep ground-water flow paths and general rock/water interaction times. Information in this report provides a comparison between the geochemistry within the TCL and in the region as a whole.

Holocene and late glacial palaeoceanography and palaeolimnology of the Black Sea: Changing sediment provenance and basin hydrography over the past 20,000 years

USGS Publications Warehouse

Piper, David Z.; Calvert, S.E.

2011-01-01

The elemental geochemistry of Late Pleistocene and Holocene sediments of the Black Sea, recovered in box cores from the basin margins and a 5-m gravity core from the central abyssal region of the basin, identifies two terrigenous sediment sources over the last 20 kyrs. One source region includes Anatolia and the southern Caucasus; the second region is the area drained by rivers entering the Black Sea from Eastern Europe. Alkali metal:Al and heavy:light rare-earth element ratios reveal that the relative contribution of the two sources shifted abruptly every few thousand years during the late glacial and early Holocene lacustrine phase of the basin. The shifts in source were coeval with changes in the lake level as determined from the distribution of quartz and the heavy mineral-hosted trace elements Ti and Zr.The geochemistry of the abyssal sediments further recorded a sequence of changes to the geochemistry of the water column following the lacustrine phase, when high salinity Mediterranean water entered the basin beginning 9.3 kyrs BP. Bottom water that had been oxic throughout the lake phase became anoxic at approximately 8.4 kyrs BP, as recorded by the accumulation from the water column of several redox-sensitive trace metals (Mo, Re, U). The accumulation of organic carbon and several trace nutrients (Cd, Cu, Ni, Zn) increased sharply ca. 0.4 kyrs later, at 8.0 kyrs BP, reflecting an increase of primary productivity. Its increase was coeval with a shift in the dinoflagellate ecology from stenohaline to euryhaline assemblages. During this profound environmental change from the lacustrine to the marine phase, the accumulation rate of the lithogenous sediment fraction decreased as much as 10-fold in response to the rise of the water level in the basin from a low stand ca. 9.3 ka to its current level.

Holocene and late glacial palaeoceanography and palaeolimnology of the Black Sea: Changing sediment provenance and basin hydrography over the past 20,000 years

USGS Publications Warehouse

Piper, D.Z.; Calvert, S.E.

2011-01-01

The elemental geochemistry of Late Pleistocene and Holocene sediments of the Black Sea, recovered in box cores from the basin margins and a 5-m gravity core from the central abyssal region of the basin, identifies two terrigenous sediment sources over the last 20. kyrs. One source region includes Anatolia and the southern Caucasus; the second region is the area drained by rivers entering the Black Sea from Eastern Europe. Alkali metal:Al and heavy:light rare-earth element ratios reveal that the relative contribution of the two sources shifted abruptly every few thousand years during the late glacial and early Holocene lacustrine phase of the basin. The shifts in source were coeval with changes in the lake level as determined from the distribution of quartz and the heavy mineral-hosted trace elements Ti and Zr. The geochemistry of the abyssal sediments further recorded a sequence of changes to the geochemistry of the water column following the lacustrine phase, when high salinity Mediterranean water entered the basin beginning 9.3. kyrs BP. Bottom water that had been oxic throughout the lake phase became anoxic at approximately 8.4. kyrs BP, as recorded by the accumulation from the water column of several redox-sensitive trace metals (Mo, Re, U). The accumulation of organic carbon and several trace nutrients (Cd, Cu, Ni, Zn) increased sharply ca. 0.4. kyrs later, at 8.0. kyrs BP, reflecting an increase of primary productivity. Its increase was coeval with a shift in the dinoflagellate ecology from stenohaline to euryhaline assemblages. During this profound environmental change from the lacustrine to the marine phase, the accumulation rate of the lithogenous sediment fraction decreased as much as 10-fold in response to the rise of the water level in the basin from a low stand ca. 9.3. ka to its current level.

Biotoxicity of Mars soils: 1. Dry deposition of analog soils on microbial colonies and survival under Martian conditions

NASA Astrophysics Data System (ADS)

Schuerger, Andrew C.; Golden, D. C.; Ming, Doug W.

2012-11-01

Six Mars analog soils were created to simulate a range of potentially biotoxic geochemistries relevant to the survival of terrestrial microorganisms on Mars, and included basalt-only (non-toxic control), salt, acidic, alkaline, aeolian, and perchlorate rich geochemistries. Experiments were designed to simulate the dry-deposition of Mars soils onto spacecraft surfaces during an active descent landing scenario with propellant engines. Six eubacteria were initially tested for tolerance to desiccation, and the spore-former Bacillus subtilis HA101 and non-spore former Enterococcus faecalis ATCC 29212 were identified to be strongly resistant (HA101) and moderately resistant (29212) to desiccation at 24 °C. Furthermore, tests with B. subtilis and E. faecalis demonstrated that at least 1 mm of Mars analog soil was required to fully attenuate the biocidal effects of a simulated Mars-normal equatorial UV flux. Biotoxicity experiments were conducted under simulated Martian conditions of 6.9 mbar, -10 °C, CO2-enriched anoxic atmosphere, and a simulated equatorial solar spectrum (200-1100 nm) with an optical depth of 0.1. For B. subtilis, the six analog soils were found, in general, to be of low biotoxicity with only the high salt and acidic soils exhibiting the capacity to inactivate a moderate number of spores (<1 log reductions) exposed 7 days to the soils under simulated Martian conditions. In contrast, the overall response of E. faecalis to the analog soils was more dramatic with between two and three orders of magnitude reductions in viable cells for most soils, and between six and seven orders of magnitude reductions observed for the high-salt soil. Results suggest that Mars soils are likely not to be overtly biotoxic to terrestrial microorganisms, and suggest that the soil geochemistries on Mars will not preclude the habitability of the Martian surface.

Spatial Autocorrelation, Source Water and the Distribution of Total and Viable Microbial Abundances within a Crystalline Formation to a Depth of 800 m

PubMed Central

Beaton, E. D.; Stuart, Marilyne; Stroes-Gascoyne, Sim; King-Sharp, Karen J.; Gurban, Ioana; Festarini, Amy; Chen, Hui Q.

2017-01-01

Proposed radioactive waste repositories require long residence times within deep geological settings for which we have little knowledge of local or regional subsurface dynamics that could affect the transport of hazardous species over the period of radioactive decay. Given the role of microbial processes on element speciation and transport, knowledge and understanding of local microbial ecology within geological formations being considered as host formations can aid predictions for long term safety. In this relatively unexplored environment, sampling opportunities are few and opportunistic. We combined the data collected for geochemistry and microbial abundances from multiple sampling opportunities from within a proposed host formation and performed multivariate mixing and mass balance (M3) modeling, spatial analysis and generalized linear modeling to address whether recharge can explain how subsurface communities assemble within fracture water obtained from multiple saturated fractures accessed by boreholes drilled into the crystalline formation underlying the Chalk River Laboratories site (Deep River, ON, Canada). We found that three possible source waters, each of meteoric origin, explained 97% of the samples, these are: modern recharge, recharge from the period of the Laurentide ice sheet retreat (ca. ∼12000 years before present) and a putative saline source assigned as Champlain Sea (also ca. 12000 years before present). The distributed microbial abundances and geochemistry provide a conceptual model of two distinct regions within the subsurface associated with bicarbonate – used as a proxy for modern recharge – and manganese; these regions occur at depths relevant to a proposed repository within the formation. At the scale of sampling, the associated spatial autocorrelation means that abundances linked with geochemistry were not unambiguously discerned, although fine scale Moran’s eigenvector map (MEM) coefficients were correlated with the abundance data and suggest the action of localized processes possibly associated with the manganese and sulfate content of the fracture water. PMID:28974945

Process recognition in multi-element soil and stream-sediment geochemical data

USGS Publications Warehouse

Grunsky, E.C.; Drew, L.J.; Sutphin, D.M.

2009-01-01

Stream-sediment and soil geochemical data from the Upper and Lower Coastal Plains of South Carolina (USA) were studied to determine relationships between soils and stream sediments. From multi-element associations, characteristic compositions were determined for both media. Primary associations of elements reflect mineralogy, including heavy minerals, carbonates and clays, and the effects of groundwater. The effects of groundwater on element concentrations are more evident in soils than stream sediments. A "winnowing index" was created using ratios of Th to Al that revealed differing erosional and depositional environments. Both soils and stream sediments from the Upper and Lower Coastal Plains show derivation from similar materials and subsequent similar multi-element relationships, but have some distinct differences. In the Lower Coastal Plain, soils have high values of elements concentrated in heavy minerals (Ce, Y, Th) that grade into high values of elements concentrated into finer-grain-size, lower-density materials, primarily comprised of carbonates and feldspar minerals (Mg, Ca, Na, K, Al). These gradational trends in mineralogy and geochemistry are inferred to reflect reworking of materials during marine transgressions and regressions. Upper Coastal Plain stream-sediment geochemistry shows a higher winnowing index relative to soil geochemistry. A comparison of the 4 media (Upper Coastal Plain soils and stream sediments and Lower Coastal Plain soils and stream sediments) shows that Upper Coastal Plain stream sediments have a higher winnowing index and a higher concentration of elements contained within heavy minerals, whereas Lower Coastal Plain stream sediments show a strong correlation between elements typically contained within clays. It is not possible to calculate a functional relationship between stream sediment-soil compositions for all elements due to the complex history of weathering, deposition, reworking and re-deposition. However, depending on the spatial separation of the stream-sediment and soil samples, some elements are more highly correlated than others. Crown Copyright ?? 2009.

The Effect of Shock on the Amorphous Component in Altered Basalt

NASA Technical Reports Server (NTRS)

Eckley, S. A.; Wright, S. P.; Rampe, E. B.; Niles, P. B.

2017-01-01

Investigation of the geochemical and mineralogical composition of the Martian surface provides insight into the geologic history of the predominantly basaltic crust. The Chemistry and Mineralogy (CheMin) instrument onboard the Curiosity rover has returned the first X-Ray diffraction data from the Martian surface. However, large proportions (27 +/- 14 with some estimates as high as 50 weight percentage) of an amorphous component have been reported. As a remedy to this problem, mass balance equations using geochemistry, volatile chemistry, and mineralogy have been employed to constrain the geochemistry of the amorphous component. However, "the nature and number of amorphous phases that constitute the amorphous component is not unequivocally known". Multiple hypotheses have been proposed to explain the origin of this amorphous component: Allophane (Al2O); Basaltic glass (Volcanic and impact); Palagonite (Altered basaltic glass); Hisingerite (Fe (sup 3 plus)-bearing phyllosilicate); S/Cl-rich component (sulfates and/or akaganeite); Nanophase ferric oxide component (npOx). Establishing a multi-phase amorphous component from a basaltic precursor that has undergone physical and chemical weathering within geochemical constraints is of paramount importance to better understand the composition of a large portion of the Martian surface (up to 50 weight percentage). Shocked basalts from Lonar Crater in India are valuable analogs for the Martian surface because it is a well-preserved impact crater in a basaltic target. Having undergone pre- and post-shock aqueous alteration, these rocks provide crucial data regarding the effect of shock on the amorphous component in altered basalt. By conducting mass balance equations similar to what has been performed for Gale crater materials, we attempt to calculate the geochemistry of the amorphous component in altered basalts ranging from unshocked to Class 5 (Table 1). This has the potential to reveal the nature and origin (i.e. primary igneous, shock metamorphic, and/or aqueous alteration occurring before or after the impact event) of the amorphous component in shocked basalt with the goal of unravelling the history of the Martian surface.

Geological Characteristics of Active Methane Expulsion In Accretionary Prism Kaoping Slope Off SW Taiwan

NASA Astrophysics Data System (ADS)

Huang, C.; Chien, C.; Yang, T. F.; Lin, S.

2005-12-01

The Kaoping Slope off SW Taiwan represents the syn-collision accretionary prism characterized by active NW-trending folding - thrusting structures and high sedimentation rate favoring the formation of gas hydrate. For an assessment of gas hydrate potential in the Kaoping Slope off SW Taiwan, sedimentology, paleontology and geochemistry in box cores and piston cores were studied. BSRs are commonly found in seismic profiles in 400-600 m below seafloor of water depth 2500-1000 m. Active expulsions of methane were found along active thrust faults where sulfate/methane interface could be as shallow as 30 cm and the methane concentration of dissolved gases in bottom water and in pore-space of drilled core samples could be three-four order higher than the normal marine environments. Occurrences of authigenic carbonate and elongated pyrite tubes are correlated with shallow SMI depth and high methane content in bottom water and pore-space of sediment cores. Authigenic carbonates were found in seafloor surface and in 20-25 meters below seafloor. The authigenic carbonate nodules are characterized by irregular shape, whitish color, no visible microfossil, containing native sulfur, pyrites, gypsum, small open spaces, and very depleted carbon isotope (-54 ~ -43 per mil PDB). Tiny native sulfur and gypsum crystals were commonly found either on surface of foraminiferal tests and elongated pyrite tubes or in the authigenic carbonate nodules. Morphological measurements of elongated pyrite tubes show that they could represent pseudomorphs after three types of Pogonophora tube worm. Foraminifers are commonly filled by rhomboidal pyrites or cemented by pyrite crystals. Normal marine benthic foraminifers predominated by calcareous tests of slope fauna are associated with authigenic carbonate nodules in the study area, suggesting no major geochemistry effect on distribution of benthic foraminifers. Integrating sedimentology, paleontology and geochemistry characters, there could be high potential to have gas hydrate in the accretionary prism off SW Taiwan.

Model for the Evolution of an Oceanic Core Complex and its Hydrothermal Vent on the Ultraslow-Spreading Mid Cayman Spreading Center

NASA Astrophysics Data System (ADS)

Harding, J.; Van Avendonk, H. J.; Hayman, N. W.; Grevemeyer, I.; Peirce, C.

2016-12-01

The Mid Cayman Spreading Center (MCSC) is an ultraslow-spreading center (15 mm yr-1 full rate) along the Caribbean-North American plate boundary. Despite the paradigm that ultraslow-spreading centers are amagmatic and cold, two hydrothermal vent fields have recently been discovered along the MCSC. The Beebe Vent Field is a black smoker in the northern axial deep, and the Von Damm Vent Field (VDVF) is a moderate-temperature, talc precipitating vent found atop an oceanic core complex (OCC). This OCC, "Mt. Dent", is a large (3 km high) massif that formed beneath a detachment fault, which exhumed lower crustal and upper mantle material. The CaySeis Experiment was conducted in April, 2015 in order to collect wide-angle refraction data of the MCSC crust and upper mantle. We modeled the across-axis crustal structure of Mt. Dent as well as the surrounding lithosphere using 2.5D P-wave tomography. Using this tomographic model, along with geochemistry, we propose a model for the formation and evolution of the OCC Mt. Dent and the VDVF. A detachment fault formed in a magma-poor environment due to a pulse of magmatism, producing a large gabbro body that was then exhumed and rotated into the OCC footwall. Once magmatism waned and the gabbroic body cooled, the OCC was faulted and fractured due to plate flexure and increased tectonic extensional stress in the naturally cold and thick lithosphere. These faults provide a permeable and deep network of hydrothermal pathways that mine deep lithospheric heat and expose gabbro and fresh mantle peridotite. This model is consistent with the basalt geochemistry, hydrothermal fluid geochemistry, and the distribution of brittle vs. ductile structures along the detachment shear zone. The VDVF is therefore a product of a pulse of magmatism in an overall melt-poor environment, conditions that may be found at other ultraslow-spreading ridges.

Sulfur geochemistry and microbial sulfate reduction during low-temperature alteration of uplifted lower oceanic crust: Insights from ODP Hole 735B

USGS Publications Warehouse

Alford, Susan E.; Alt, Jeffrey C.; Shanks, Wayne C.

2011-01-01

Sulfide petrography plus whole rock contents and isotope ratios of sulfur were measured in a 1.5 km section of oceanic gabbros in order to understand the geochemistry of sulfur cycling during low-temperature seawater alteration of the lower oceanic crust, and to test whether microbial effects may be present. Most samples have low SO4/ΣS values (≤ 0.15), have retained igneous globules of pyrrhotite ± chalcopyrite ± pentlandite, and host secondary aggregates of pyrrhotite and pyrite laths in smectite ± iron-oxyhydroxide ± magnetite ± calcite pseudomorphs of olivine and clinopyroxene. Compared to fresh gabbro containing 100–1800 ppm sulfur our data indicate an overall addition of sulfide to the lower crust. Selection of samples altered only at temperatures ≤ 110 °C constrains microbial sulfate reduction as the only viable mechanism for the observed sulfide addition, which may have been enabled by the production of H2 from oxidation of associated olivine and pyroxene. The wide range in δ34Ssulfide values (− 1.5 to + 16.3‰) and variable additions of sulfide are explained by variable εsulfate-sulfide under open system pathways, with a possible progression into closed system pathways. Some samples underwent oxidation related to seawater penetration along permeable fault horizons and have lost sulfur, have high SO4/ΣS (≥ 0.46) and variable δ34Ssulfide (0.7 to 16.9‰). Negative δ34Ssulfate–δ34Ssulfide values for the majority of samples indicate kinetic isotope fractionation during oxidation of sulfide minerals. Depth trends in sulfide–sulfur contents and sulfide mineral assemblages indicate a late-stage downward penetration of seawater into the lower 1 km of Hole 735B. Our results show that under appropriate temperature conditions, a subsurface biosphere can persist in the lower oceanic crust and alter its geochemistry.

Global Carbon Reservoir Oxidative Ratios

NASA Astrophysics Data System (ADS)

Masiello, C. A.; Gallagher, M. E.; Hockaday, W. C.

2010-12-01

Photosynthesis and respiration move carbon and oxygen between the atmosphere and the biosphere at a ratio that is characteristic of the biogeochemical processes involved. This ratio is called the oxidative ratio (OR) of photosynthesis and respiration, and is defined as the ratio of moles of O2 per moles of CO2. This O2/CO2 ratio is a characteristic of biosphere-atmosphere gas fluxes, much like the 13C signature of CO2 transferred between the biosphere and the atmosphere has a characteristic signature. OR values vary on a scale of 0 (CO2) to 2 (CH4), with most ecosystem values clustered between 0.9 and 1.2. Just as 13C can be measured for both carbon fluxes and carbon pools, OR can also be measured for fluxes and pools and can provide information about the processes involved in carbon and oxygen cycling. OR values also provide information about reservoir organic geochemistry because pool OR values are proportional to the oxidation state of carbon (Cox) in the reservoir. OR may prove to be a particularly valuable biogeochemical tracer because of its ability to couple information about ecosystem gas fluxes with ecosystem organic geochemistry. We have developed 3 methods to measure the OR of ecosystem carbon reservoirs and intercalibrated them to assure that they yield accurate, intercomparable data. Using these tools we have built a large enough database of biomass and soil OR values that it is now possible to consider the implications of global patterns in ecosystem OR values. Here we present a map of the natural range in ecosystem OR values and begin to consider its implications. One striking pattern is an apparent offset between soil and biospheric OR values: soil OR values are frequently higher than that of their source biomass. We discuss this trend in the context of soil organic geochemistry and gas fluxes.

Trace-element geochemistry of metabasaltic rocks from the Yukon-Tanana Upland and implications for the origin of tectonic assemblages in east-central Alaska

USGS Publications Warehouse

Dusel-Bacon, C.; Cooper, K.M.

1999-01-01

We present major- and trace- element geochemical data for 27 amphibolites and six greenstones from three structural packages in the Yukon-Tanana Upland of east-central Alaska: the Lake George assemblage (LG) of Devono-Mississippian augen gneiss, quartz-mica schist, quartzite, and amphibolite; the Taylor Mountain assemblage (TM) of mafic schist and gneiss, marble, quartzite, and metachert; and the Seventymile terrane of greenstone, serpentinized peridotite, and Mississippian to Late Triassic metasedimentary rocks. Most LG amphibolites have relatively high Nb, TiO2, Zr, and light rare earth element contents, indicative of an alkalic to tholeiitic, within-plate basalt origin. The within-plate affinities of the LG amphibolites suggest that their basaltic parent magmas developed in an extensional setting and support a correlation of these metamorphosed continental-margin rocks with less metamorphosed counterparts across the Tintina fault in the Selwyn Basin of the Canadian Cordillera. TM amphibolites have a tholeiitic or calc-alkalic composition, low normalized abundances of Nb and Ta relative to Th and La, and Ti/V values of <20, all indicative of a volcanic-arc origin. Limited results from Seventymile greenstones indicate a tholeiitic or calc-alkalic composition and intermediate to high Ti/V values (27-48), consistent with either a within-plate or an ocean-floor basalt origin. Y-La-Nb proportions in both TM and Seventymile metabasalts indicate the proximity of the arc and marginal basin to continental crust. The arc geochemistry of TM amphibolites is consistent with a model in which the TM assemblage includes arc rocks generated above a west-dipping subduction zone outboard of the North American continental margin in mid-Paleozoic through Triassic time. The ocean-floor or within-plate basalt geochemistry of the Seventymile greenstones supports the correlation of the Seventymile terrane with the Slide Mountain terrane in Canada and the hypothesis that these oceanic rocks originated in a basin between the continental margin and an arc to the west.

Do Skeletal Density Changes Within the Tissue Layer of Corals Affect Paleoclimate Reconstructions?

NASA Astrophysics Data System (ADS)

Griffiths, J. S.; DeLong, K. L.; Quinn, T.; Taylor, F. W.; Kilbourne, K. H.; Wagner, A. J.

2016-02-01

Sea surface temperature (SST) reconstructions from coral geochemistry provide information on past climate variability; however, not all coral studies agree on a common calibration slope. Therefore, understanding the impacts of coral skeletal growth on strontium-to-calcium ratios (Sr/Ca) and oxygen isotopic ratios (δ18O) is necessary to ensure accurate calibrations. The study of Gagan et al. (2012) suggests that for the Pacific coral genera Porites, SST calibrations for coral Sr/Ca and δ18O need to be adjusted to account for skeletal density changes in the tissue layer, which may attenuate the seasonal cycle in coral geochemistry. We attempt to duplicate those results and density patterns in several Porites lutea colonies from two locations, yet our results do not show an increase in density in the tissue layer. Another study with Montastraea faveolata reveals reduced seasonality in coral Sr/Ca compared to slower-growing Siderastrea siderea in close proximity and same water depth, suggesting the faster growing M. faveolata geochemistry may be attenuated. By measuring skeletal density changes by micromilling a standard volume throughout the tissue layer and immediately below, we find no pattern of skeletal accumulation in the tissue layer of multiple colonies of M. faveolata and S. siderea from different locations. We conclude that these species lay down all of their skeletal material at the skeleton surface, thus skeletal density changes in the tissue layer do not account for reduced seasonality. We propose that time averaging occurs in M. faveolata as a result of the coral polyp's deep calyces mixing time intervals in the adjacent thecal wall in which micromilling for geochemical analysis produces a sample area that contains several growth increments. Our results show that skeletal density growth effects cannot be applied to all coral genera and paves the way for new research on calyx depth as an alternative explanation for differences in coral calibration slopes.

Geochemistry driven trends in microbial diversity and function across a temperature transect of a shallow water hydrothermal system off Milos (Greece)

NASA Astrophysics Data System (ADS)

Bühring, Solveig I.; Amend, Jan P.; Gómez Sáez, Gonzalo V.; Häusler, Stefan; Hinrichs, Kai-Uwe; Pichler, Thomas; Pop Ristova, Petra; Price, Roy E.; Santi, Ioulia; Sollich, Miriam

2014-05-01

The shallow water hydrothermal vents off Milos Island, Greece, discharge hot, slightly acidic, reduced fluids into colder, slightly alkaline, oxygenated seawater. Gradients in temperature, pH, and geochemistry are established as the two fluids mix, leading to the formation of various microbial microniches. In contrast to deep-sea hydrothermal systems, the availability of sun light allows for a combination of photo- and chemotrophic carbon fixation. Despite the comparably easy accessibility of shallow water hydrothermal systems, little is known about their microbial diversity and functioning. We present data from a shallow hydrothermal system off Milos Island, one of the most hydrothermally active regions in the Mediterranean Sea. The physico-chemical changes from ambient seafloor to hydrothermal area were investigated and documented by in situ microsensor profiling of temperature, pH, total reduced sulfur and dissolved oxygen alongside porewater geochemistry. The spatial microbial diversity was determined using a combination of gene- and lipid-based approaches, whereas microbial functioning was assessed by stable isotope probing experiments targeting lipid biomarkers. In situ microprofiles indicated an extreme environment with steep gradients, offering a variety of microniches for metabolically diverse microbial communities. We sampled a transect along a hydrothermal patch, following an increase in sediment surface temperature from background to 90°C, including five sampling points up to 20 cm sediment depth. Investigation of the bacterial diversity using ARISA revealed differences in the community structure along the geochemical gradients, with the least similarity between the ambient and highly hydrothermally impacted sites. Furthermore, using multivariate statistical analyses it was shown that variations in the community structure could be attributed to differences in the sediment geochemistry and especially the sulfide content, and only indirectly to shifts in temperature. Results from intact polar lipid analyses were consistent with the ARISA data and clearly differentiated those samples located close to the vent from those found in less affected areas. Changes from phospho- and betaine lipids within the top layer of the unaffected area to glyco- and ornithine lipids in the hydrothermally influenced sediment layers reflected a change from photoautotrophic algae to a bacteria-dominated community as predominant lipid sources. A clear dominance of archaeal lipids indicated archaea as key players in the deeper, hotter layers of the hydrothermal sediment. We performed stable isotope probing experiments with 13C-bicarbonate in the dark to investigate if chemolithotrophy, as opposed to phototrophy, plays any significant role for carbon fixation in shallow vent systems. Different amendments revealed that not only chemolithotrophy represents an important pathway for carbon fixation in these ecosystems, but that diverse ways of dark CO2 fixation exist, with hydrogen being the most effective electron donor under high temperature conditions.

Age, geochemistry and melt flux variations for the Hawaiian Ridge

NASA Astrophysics Data System (ADS)

Garcia, M. O.; Weis, D. A.; Greene, A. R.; Wessel, P.; Harrison, L.; Tree, J.

2012-12-01

The Hawaiian Ridge portion of the Hawaiian-Emperor Chain, the classic example of a mantle plume produced linear island chain, is 6000 km in length, active for 80+ Myr, and tectonically simple. Despite its importance to our understanding of mantle plumes and Cenozoic plate motion, there are large data gaps for the age and geochemistry of lavas from volcanoes along the Hawaiian Ridge (HR) portion of the Chain. Ages: Only volcanoes near the Hawaiian-Emperor bend and in the Hawaiian Islands have modern Ar-Ar ages, leaving a gap of 2000 km where existing K-Ar ages suggest synchronous volcanism over a 1000 km section. Geochemistry: There is a 2900 km gap in high precision geochemical data for the HR. The Emperor Seamounts (>45 Ma) have better regional coverage of recent isotopic data and show a correlation of Sr isotope composition with age of the underlying oceanic lithosphere (Regelous et al. 2003). The HR has an unexplained, exponential increase in magma flux over the last 30 Myr (Vidal & Bonneville 2004). Potential explanations for the increase in magma flux include: changes in melting conditions (temperature and/or pressure), change in source fertility related to rock type (pyroxenite vs. peridotite) or previous melting history, and/or changes in plate stresses resulting from reconfigurations of plate motion. Our new multi-disciplinary project will: 1) Determine 40Ar/39Ar ages, and whole-rock major, trace element, and Pb, Sr, Nd and Hf isotopic geochemistry for lavas from 20 volcanoes spanning ~2150 km of the HR (NW of the Hawaiian Islands). 2) Use the geochemical data to determine the long-term evolution of the Hawaiian mantle plume source components and to evaluate whether there have been systematic variations in mantle potential temperature, melting pressure, and/or source lithology during the creation of the HR. If so, are they responsible for the 300% variation in melt production along the Ridge? Also, we will assess when the more fertile Loa source component appeared. 3) Reassess models for the origin of the HR using the new 40Ar/39Ar ages. 4) Recompute and compare the magma flux rate for the Hawaiian and Louisville Ridges using our new HR ages and IODP results for Louisville Ridge, and updated bathymetric data for both chains. 5) Utilize the new ages to revise Cenozoic Pacific plate motions and to compute differential motions as proxies for stress changes along the HR with time to evaluate the effects of plate motion on magma flux rate. These studies will have fundamental implications for mantle plume sources, plume dynamics, and plate kinematics. Vidal V, Bonneville A, 2004. J. Geophys. Res., 109, B03104, doi:10.1029/2003JB002559 Regelous M, Hofmann AW, Abouchami W, Galer SJG, 2003. Jour. Petrol. 44, 113-140

Continental-scale patterns in soil geochemistry and mineralogy: results from two transects across the United States and Canada

USGS Publications Warehouse

Woodruff, L.G.; Cannon, W.F.; Eberl, D.D.; Smith, D.B.; Kilburn, J.E.; Horton, J.D.; Garrett, R.G.; Klassen, R.A.

2009-01-01

In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada (GSC) initiated a pilot study that involved collection of more than 1500 soil samples from 221 sites along two continental transects across Canada and the United States. The pilot study was designed to test and refine protocols for a soil geochemical survey of North America. The two transects crossed a wide array of soil parent materials, soil ages, climatic conditions, landforms, land covers and land uses. Sample sites were selected randomly at approximately 40-km intervals from a population defined as all soils of the continent. At each site, soils representing 0 to 5 cm depth, and the O, A, and C horizons, if present, were collected and analyzed for their near-total content of over 40 major and trace elements. Soils from 0–5 cm depth were also collected for analysis of organic compounds. Results from the transects confirm that soil samples collected at a 40-km spacing reveal coherent, continental- to subcontinental-scale geochemical and mineralogical patterns that can be correlated to aspects of underlying soil parent material, soil age and climate influence. The geochemical data also demonstrate that at the continental-scale the dominance of any of these major factors that control soil geochemistry can change across the landscape. Along both transects, soil mineralogy and geochemistry change abruptly with changes in soil parent materials. However, the chemical influence of a soil’s parent material can be obscured by changing climatic conditions. For the transects, increasing precipitation from west to east and increasing temperature from north to south affect both soil mineralogy and geochemistry because of climate effects on soil weathering and leaching, and plant productivity. Regional anomalous metal concentrations can be linked to natural variations in soil parent materials, such as high Ni and Cr in soils developed on ultramafic rocks in California or high P in soils formed on weathered Ordovician limestones in central Kentucky. On local scales, anomalous metal concentrations recognized in soil profiles, such as high P in soils from animal confinement sites, are consistent with local anthropogenic disturbances. At a larger scale, the distribution of Hg across the west to east transect demonstrates that it can be difficult to distinguish between natural or anthropogenic contributions and that many factors can contribute to an element’s spatial distribution. Only three samples in a subset of seventy-three 0–5 cm depth soil samples from the north to south transect had organochlorine pesticides values above the method detection limit, apparently related to historic usage of the pesticides DDT and dieldrin.

The Mineralogy and Geochemistry of Manganese Nodules From the Southern Ocean

DTIC Science & Technology

1968-02-01

accumulations. Quartz, plagioclase, montmorillonite , and phillipsite are almost invariably present, while clinoptilolite ii and amphibole occur less... Montmorillonite Diffraction Data ........... 125 16. Phillipsite Diffraction Data .. ......... ... 126 17. Sources of X-ray Diffraction Data...concretion. (Crust from ELTANIN 5-4; nucleus probably phillipsite- montmorillonite ; glacial erratics incorporated in ferro- manganese oxide crust.) 0 cm I

A Teaching Exercise to Introduce Stable Isotope Fractionation of Metals into Geochemistry Courses

ERIC Educational Resources Information Center

Weiss, Dominik J.; Harris, Caroline; Maher, Kate; Bullen, Thomas

2013-01-01

Variations in the isotopic composition of elements have been widely used to study earth's climate, biosphere, and interior, and more recently to track the fate of contaminants. Within the broad range of elements that exhibit measureable isotopic variations, metal stable isotopes are increasingly applied across the biological, geological,…

Ninth Annual V. M. Goldschmidt Conference

NASA Technical Reports Server (NTRS)

1999-01-01

This volume contains abstracts that have been accepted for presentation at the Ninth Annual V. M. Goldschmidt Conference, August 22-27, 1999, hosted by the Department of Earth and Planetary Sciences, Harvard University, Cambridge, Massachusetts. The meeting is a forum for presenting and discussing new chemical and isotopic measurements, experimental and theoretical results, and discoveries in geochemistry and cosmochemistry.

Using geochemistry in the greater Yellowstone area

USGS Publications Warehouse

,

1995-01-01

The greater Yellowstone area lies within adjoining parts of Wyoming, Montana, and Idaho (see figure) and includes Yellowstone and Grand Teton National Parks, parts of six national forests, plus State lands, national wildlife refuges, Bureau of Land Management lands, and private lands. This area is known worldwide for its scenic beauty, wildlife, and geologic and geothermal features.

Residence times of alluvium in an east Texas stream as indicated by sediment color

Treesearch

Jonathan D. Phillips; Daniel A. Marion

2001-01-01

The relationships between sediment production, storage, and transport in fluvial systems are complex and variable. Key issues in addressing these relationships are the residence times of sediment delivered to the channel, and the proportion derived from recent upland erosion as opposed to remobilized alluvium. The systematic changes in iron geochemistry often...

Trace element geochemistry of Archean volcanic rocks

NASA Technical Reports Server (NTRS)

Jahn, B.-M.; Shih, C.-Y.; Murthy, V. R.

1974-01-01

The K, Rb, Sr, Ba and rare-earth-element contents of some Archean volcanic rocks from the Vermilion greenstone belt, northeast Minnesota, were determined by the isotopic dilution method. The characteristics of trace element abundances, supported by the field occurrences and major element chemistry, suggest that these volcanic rocks were formed in an ancient island arc system.

Characterization of preferential flow pathways in a siliciclastic aquifer system using human enteric viruses and groundwater geochemistry

USDA-ARS?s Scientific Manuscript database

Human enteric viruses have been recognized as an emerging groundwater contaminant and are found only in human waste. In urban environments the most likely source of human waste is from sanitary sewers. Determining the travel time for near-surface contaminants to reach deep public supply wells is i...

U.S. National Report to International Union of Geodesy and Geophysics 1987-1990; Proceedings of the IUGG General Assembly, 20th, Vienna, Austria, Aug. 11-24, 1991

NASA Technical Reports Server (NTRS)

Shea, Margaret A. (Editor)

1991-01-01

An authoritative record of contributions of geophysical research in the U.S. during 1987-1990 is reported. Major areas of research include atmospheric sciences, geodesy, hydrology, planetology, geomagnetism, paleomagnetism, volcanology, geochemistry, petrology, oceanography, seismology, tectonophysics, and solar-planetary relations.

The Problem of Sample Contamination in a Fluvial Geochemistry Research Experience for Undergraduates.

ERIC Educational Resources Information Center

Andersen, Charles B.

2001-01-01

Introduces the analysis of a river as an excellent way to teach geochemical techniques because of the relative ease of sample collection and speed of sample analysis. Focuses on the potential sources of sample contamination during sampling, filtering, and bottle cleaning processes, and reviews methods to reduce and detect contamination. Includes…

C-13 nuclear magnetic resonance in organic geochemistry.

NASA Technical Reports Server (NTRS)

Balogh, B.; Wilson, D. M.; Burlingame, A. L.

1972-01-01

Study of C-13 nuclear magnetic resonance (NMR) spectra of polycyclic fused systems. The fingerprint qualities of the natural abundance in C-13 NMR spectra permitting unequivocal identification of these compounds is discussed. The principle of structural additivity of C-13 NMR information is exemplified on alpha and beta androstanes, alpha and beta cholestanes, ergostanes, sitostanes, and isodecanes.

Publications - GMC 410 | Alaska Division of Geological & Geophysical

Science.gov Websites

) Keywords Geochemistry; Rare Earth Elements Top of Page Department of Natural Resources, Division of Surveys Skip to content State of Alaska myAlaska My Government Resident Business in Alaska Visiting Alaska State Employees DGGS State of Alaska search Alaska Division of Geological & Geophysical

Publications - GMC 409 | Alaska Division of Geological & Geophysical

Science.gov Websites

) Keywords Geochemistry; Rare Earth Elements Top of Page Department of Natural Resources, Division of Surveys Skip to content State of Alaska myAlaska My Government Resident Business in Alaska Visiting Alaska State Employees DGGS State of Alaska search Alaska Division of Geological & Geophysical

Publications - RDF 2016-2 | Alaska Division of Geological & Geophysical

Science.gov Websites

, Major-oxide and trace-element geochemistry of mafic rocks in the Carboniferous Lisburne Group, Ivishak Surveys Skip to content State of Alaska myAlaska My Government Resident Business in Alaska Visiting Alaska State Employees DGGS State of Alaska search Alaska Division of Geological & Geophysical

Stratigraphy and geochemistry of the Stone mountain core (64001/2)

NASA Astrophysics Data System (ADS)

Korotev, R. L.; Morris, R. V.; Lauer, H. V.

1984-11-01

Ferromagnetic resonance and magnetic data measured on both sections of the double drive tube cord 64001/2 collected on Stone mountain, station four, Apollo 16 are reported, along with instrumental neutron activation analysis data measured on the lower section. These data provide insight into the depositional and irradiational history and the geochemical provenances of the core.

Variation in chemistry of stream water and bulk deposition across the Hubbard Brook Valley, New Hampshire, USA

Treesearch

Gene E. Likens; Donald C. Buso; James W. Hornbeck

2002-01-01

Chemistry and volume of precipitation and stream water have been measured in south-facing watersheds of the Hubbard Brook Experimental Forest (HBEF), continuously for 37 years. These long-term data have provided important insights into the bio-geochemistry of these watershed ecosystems and the region (e.g. LIKENS & BORMANN 1995).

Petrology and Geochemistry of Lunar Regolith Particle 65903,16-7: Evidence for Extreme Reduction and Oxidation

NASA Technical Reports Server (NTRS)

Zeigler, R. A.; Jolliff, B. L.; Korotev, R. L.; Kremser, D. T.; Haskin, L. A.

2001-01-01

Apollo 16 particle 65903,16-7 is a magnesian, alkali-rich impact melt breccia. Low Fe/Mn and high phosphide/phosphate ratios are evidence of severe reduction during impact-melt cooling. Presence of carbonate and FeOOH is evidence for later oxidation. Additional information is contained in the original extended abstract.

Stratigraphy and geochemistry of the Stone mountain core (64001/2)

NASA Technical Reports Server (NTRS)

Korotev, R. L.; Morris, R. V.; Lauer, H. V., Jr.

1984-01-01

Ferromagnetic resonance and magnetic data measured on both sections of the double drive tube cord 64001/2 collected on Stone mountain, station four, Apollo 16 are reported, along with instrumental neutron activation analysis data measured on the lower section. These data provide insight into the depositional and irradiational history and the geochemical provenances of the core.

Comparative planetology - Basic concepts, terminology, and definitions

NASA Astrophysics Data System (ADS)

Sliuta, Evgenii N.; Ivanov, Mikhail A.; Ivanov, Andrei V.

The book presents an alphabetical list of Russian terms, and their English equivalents, used in comparative planetology, space chemistry, and meteoritics, as well as many terms used in geology, geophysics, geochemistry, and sciences related to space studies. Besides giving the definitions of these terms, this work also contains basic information on planets, their satellites, and the largest asteroids.

Corrigendum to "Geochemistry and geochronology of orthogneisses in Bode Saadu area, southwestern Nigeria and their implications for the Paleoproterozoic evolution of the area" [J. African Earth Sciences 109 (2015) 131-142

NASA Astrophysics Data System (ADS)

Okonkwo, Chukwuemeka T.; Ganev, Valentin Y.

2018-04-01

The authors regret the error in Table 1-Chemical composition of the orthogneisses where the sum of the elements for each sample was mistakenly indicated as LOI (loss on ignition). The correct table is given below.

Geochemistry and petrography of the MacAlpine Hills lunar meteorites

NASA Technical Reports Server (NTRS)

Lindstrom, Marilyn M.; Mckay, David S.; Wentworth, Susan J.; Martinez, Rene R.; Mittlefehldt, David W.; Wang, Ming-Sheng; Lipschutz, Michael E.

1991-01-01

MacAlpine Hills 88104 and 88105, anorthositic lunar meteorites recovered form the same area in Antartica, are characterized. Petrographic studies show that MAC88104/5 is a polymict breccia dominated by impact melt clasts. It is better classified as a fragmental breccia than a regolith breccia. The bulk composition is ferroan and highly aluminous (Al2O3-28 percent).

The medical geochemistry of dusts, soils, and other Earth materials: Chapter 7

USGS Publications Warehouse

Plumlee, Geoffrey S.; Ziegler, Thomas L.

2003-01-01

A quick scan of newspapers, television, science magazines, or the internet on any given day has a fairly high likelihood of encountering stories (accompanied by headlines such as those above) regarding human health concerns linked to dusts, soils, or other Earth materials. Many such concerns have been recognized and studied for decades, but new concerns arise regularly.

The effects of fire events on soil geochemistry in semi-arid grasslands

Treesearch

Thomas H. Biggs; Lisa N. Florkowski; Philip A. Pearthree; Pei-Jen L. Shaner

2005-01-01

Throughout the southwestern United States, vegetation in what historically was grassland has changed to a mixture of trees and shrubs; exotic grass species and undesirable shrubs have also invaded the grasslands at the expense of native grasses. The availability and amount of soil nutrients influence the relative success of plants, but few studies have examined fire...

Geochemical data from groundwater at the proposed Dewey Burdock uranium in-situ recovery mine, Edgemont, South Dakota

USGS Publications Warehouse

Johnson, Raymond H.

2012-01-01

This report releases groundwater geochemistry data from samples that were collected in June 2011 at the Dewey Burdock proposed uranium in-situ recovery site near Edgemont, South Dakota. The sampling and analytical methods are summarized, and all of the data, including quality assurance/quality control information are provided in data tables.

The performance and capabilities of terrestrial organisms in extreme and unusual gaseous and liquid environments. Performance of fungi in exotic and harsh environments

NASA Technical Reports Server (NTRS)

Siegel, S. M.

1975-01-01

The growth of Penicillium in saline and low temperature conditions during a 15 month incubation period was studied. Data are also given on the potential 1f fungu for modification of the surface geochemistry of the earth and the capacity of these fungi to solubilize and concentrate metals.

Experimental Study of Porosity Changes in Shale Caprocks Exposed to Carbon Dioxide-Saturated Brine II: Insights from Aqueous Geochemistry

DOE PAGES

Miller, Quin R. S.; Wang, Xiuyu; Kaszuba, John P.; ...

2016-07-18

Laboratory experiments evaluated two shale caprock formations, the Gothic Shale and Marine Tuscaloosa Formation, at conditions relevant to carbon dioxide (CO 2) sequestration. Both rocks were exposed to CO 2-saturated brines at 160°C and 15 MPa for ~45 days. Baseline experiments for both rocks were pressurized with argon to 15 MPa for ~35 days. Varying concentrations of iron, aqueous silica, sulfate, and initial pH decreases coincide with enhanced carbonate and silicate dissolution due to reaction between CO 2-saturated brine and shale. Saturation indices were calculated and activity diagrams were constructed to gain insights into sulfate, silicate, and carbonate mineral stabilities.more » We found that upon exposure to CO 2-saturated brines, the Marine Tuscaloosa Formation appeared to be more reactive than the Gothic Shale. Evolution of aqueous geochemistry in the experiments is consistent with mineral precipitation and dissolution reactions that affect porosity. Finally, this study highlights the importance of tracking fluid chemistry to clarify downhole physicochemical responses to CO 2 injection and subsequent changes in sealing capacity in CO 2 storage and utilization projects.« less

Factors influencing the biogeochemistry of sedimentary carbon and phosphorus in the Sacramento-San Joaquin Delta

USGS Publications Warehouse

Nilsen, E.B.; Delaney, M.L.

2005-01-01

This study characterizes organic carbon (Corganic) and phosphorus (P) geochemistry in surface sediments of the Sacramento-San Joaquin Delta, California. Sediment cores were collected from five sites on a sample transect from the edge of the San Francisco Bay eastward to the freshwater Consumnes River. The top 8 cm of each core were analyzed (in 1-cm intervals) for Corganic, four P fractions, and redox-sensitive trace metals (uranium and manganese). Sedimentary Corganic concentrations and Corganic:P ratios decreased, while reactive P concentrations increased moving inland in the Delta. The fraction of total P represented by organic P increased inland, while that of authigenic P was higher bayward than inland reflecting increased diagenetic alteration of organic matter toward the bayward end of the transect. The redox indicator metals are consistent with decreasing sedimentary suboxia inland. The distribution of P fractions and C:P ratios reflect the presence of relatively labile organic matter in upstream surface sediments. Sediment C and P geochemistry is influenced by site-specific particulate organic matter sources, the sorptive power of the sedimentary material present, physical forcing, and early diagenetic transformations presumably driven by Corganic oxidation. ?? 2005 Estuarine Research Federation.

Introduction to special section: China shale gas and shale oil plays

USGS Publications Warehouse

Jiang, Shu; Zeng, Hongliu; Zhang, Jinchuan; Fishman, Neil; Bai, Baojun; Xiao, Xianming; Zhang, Tongwei; Ellis, Geoffrey S.; Li, Xinjing; Richards-McClung, Bryony; Cai, Dongsheng; Ma, Yongsheng

2015-01-01

Even though China shale gas and shale oil exploration is still in an early stage, limited data are already available. We are pleased to have selected eight high-quality papers from fifteen submitted manuscripts for this timely section on the topic of China shale gas and shale oil plays. These selected papers discuss various subject areas including regional geology, resource potentials, integrated and multidisciplinary characterization of China shale reservoirs (geology, geophysics, geochemistry, and petrophysics) China shale property measurement using new techniques, case studies for marine, lacustrine, and transitional shale deposits in China, and hydraulic fracturing. One paper summarizes the regional geology and different tectonic and depositional settings of the major prospective shale oil and gas plays in China. Four papers concentrate on the geology, geochemistry, reservoir characterization, lithologic heterogeneity, and sweet spot identification in the Silurian Longmaxi marine shale in the Sichuan Basin in southwest China, which is currently the primary focus of shale gas exploration in China. One paper discusses the Ordovician Salgan Shale in the Tarim Basin in northwest China, and two papers focus on the reservoir characterization and hydraulic fracturing of Triassic lacustrine shale in the Ordos Basin in northern China. Each paper discusses a specific area.

Trace elements geochemistry of fractured basement aquifer in southern Malawi: A case of Blantyre rural

NASA Astrophysics Data System (ADS)

Mapoma, Harold Wilson Tumwitike; Xie, Xianjun; Nyirenda, Mathews Tananga; Zhang, Liping; Kaonga, Chikumbusko Chiziwa; Mbewe, Rex

2017-07-01

In this study, twenty one (21) trace elements in the basement complex groundwater of Blantyre district, Malawi were analyzed. The majority of the analyzed trace elements in the water were within the standards set by World Health Organization (WHO) and Malawi Standards Board (MSB). But, iron (Fe) (BH16 and 21), manganese (Mn) (BH01) and selenium (Se) (BH02, 13, 18, 19 and 20) were higher than the WHO and MSB standards. Factor analysis (FA) revealed up to five significant factors which accounted for 87.4% of the variance. Factor 1, 2 and 3 suggest evaporite dissolution and silicate weathering processes while the fourth factor may explain carbonate dissolution and pH influence on trace element geochemistry of the studied groundwater samples. According to PHREEQC computed saturation indices, dissolution, precipitation and rock-water-interaction control the levels of trace elements in this aquifer. Elevated concentrations of Fe, Mn and Se in certain boreholes are due to the geology of the aquifer and probable redox status of groundwater. From PHREEQC speciation results, variations in trace element species were observed. Based on this study, boreholes need constant monitoring and assessment for human consumption to avoid health related issues.

Leaf Evolution: Gases, Genes and Geochemistry

PubMed Central

BEERLING, DAVID J.

2005-01-01

• Aims This Botanical Briefing reviews how the integration of palaeontology, geochemistry and developmental biology is providing a new mechanistic framework for interpreting the 40- to 50-million-year gap between the origination of vascular land plants and the advent of large (megaphyll) leaves, a long-standing puzzle in evolutionary biology. • Scope Molecular genetics indicates that the developmental mechanisms required for leaf production in vascular plants were recruited long before the advent of large megaphylls. According to theory, this morphogenetic potential was only realized as the concentration of atmospheric CO2 declined during the late Palaeozoic. Surprisingly, plants effectively policed their own evolution since the decrease in CO2 was brought about as terrestrial floras evolved accelerating the rate of silicate rock weathering and enhancing sedimentary organic carbon burial, both of which are long-term sinks for CO2. • Conclusions The recognition that plant evolution responds to and influences CO2 over millions of years reveals the existence of an intricate web of vegetation feedbacks regulating the long-term carbon cycle. Several of these feedbacks destabilized CO2 and climate during the late Palaeozoic but appear to have quickened the pace of terrestrial plant and animal evolution at that time. PMID:15965270

Geochemistry of vanadium (V) in Chinese coals.

PubMed

Liu, Yuan; Liu, Guijian; Qu, Qinyuan; Qi, Cuicui; Sun, Ruoyu; Liu, Houqi

2017-10-01

Vanadium in coals may have potential environmental and economic impacts. However, comprehensive knowledge of the geochemistry of V in coals is lacking. In this study, abundances, distribution and modes of occurrence of V are reviewed by compiling >2900 reported Chinese coal samples. With coal reserves in individual provinces as the weighting factors, V in Chinese coals is estimated to have an average abundance of 35.81 μg/g. Large variation of V concentration is observed in Chinese coals of different regions, coal-forming periods, and maturation ranks. According to the concentration coefficient of V in coals from individual provinces, three regions are divided across Chinese coal deposits. Vanadium in Chinese coals is probably influenced by sediment source and sedimentary environment, supplemented by late-stage hydrothermal fluids. Specifically, hydrothermal fluids have relatively more significant effect on the enrichment of V in local coal seams. Vanadium in coals is commonly associated with aluminosilicate minerals and organic matter, and the modes of V occurrence in coal depend on coal-forming environment and coal rank. The Chinese V emission inventory during coal combustion is estimated to be 4906 mt in 2014, accounting for 50.55 % of global emission. Vanadium emissions by electric power plants are the largest contributor.

Rare earth element geochemistry of outcrop and core samples from the Marcellus Shale

DOE Office of Scientific and Technical Information (OSTI.GOV)

Noack, Clinton W.; Jain, Jinesh C.; Stegmeier, John

In this paper, we studied the geochemistry of the rare earth elements (REE) in eleven outcrop samples and six, depth-interval samples of a core from the Marcellus Shale. The REE are classically applied analytes for investigating depositional environments and inferring geochemical processes, making them of interest as potential, naturally occurring indicators of fluid sources as well as indicators of geochemical processes in solid waste disposal. However, little is known of the REE occurrence in the Marcellus Shale or its produced waters, and this study represents one of the first, thorough characterizations of the REE in the Marcellus Shale. In thesemore » samples, the abundance of REE and the fractionation of REE profiles were correlated with different mineral components of the shale. Namely, samples with a larger clay component were inferred to have higher absolute concentrations of REE but have less distinctive patterns. Conversely, samples with larger carbonate fractions exhibited a greater degree of fractionation, albeit with lower total abundance. Further study is necessary to determine release mechanisms, as well as REE fate-and-transport, however these results have implications for future brine and solid waste management applications.« less

Interface COMSOL-PHREEQC (iCP), an efficient numerical framework for the solution of coupled multiphysics and geochemistry

NASA Astrophysics Data System (ADS)

Nardi, Albert; Idiart, Andrés; Trinchero, Paolo; de Vries, Luis Manuel; Molinero, Jorge

2014-08-01

This paper presents the development, verification and application of an efficient interface, denoted as iCP, which couples two standalone simulation programs: the general purpose Finite Element framework COMSOL Multiphysics® and the geochemical simulator PHREEQC. The main goal of the interface is to maximize the synergies between the aforementioned codes, providing a numerical platform that can efficiently simulate a wide number of multiphysics problems coupled with geochemistry. iCP is written in Java and uses the IPhreeqc C++ dynamic library and the COMSOL Java-API. Given the large computational requirements of the aforementioned coupled models, special emphasis has been placed on numerical robustness and efficiency. To this end, the geochemical reactions are solved in parallel by balancing the computational load over multiple threads. First, a benchmark exercise is used to test the reliability of iCP regarding flow and reactive transport. Then, a large scale thermo-hydro-chemical (THC) problem is solved to show the code capabilities. The results of the verification exercise are successfully compared with those obtained using PHREEQC and the application case demonstrates the scalability of a large scale model, at least up to 32 threads.

Rare earth element geochemistry of outcrop and core samples from the Marcellus Shale

DOE PAGES

Noack, Clinton W.; Jain, Jinesh C.; Stegmeier, John; ...

2015-06-26

In this paper, we studied the geochemistry of the rare earth elements (REE) in eleven outcrop samples and six, depth-interval samples of a core from the Marcellus Shale. The REE are classically applied analytes for investigating depositional environments and inferring geochemical processes, making them of interest as potential, naturally occurring indicators of fluid sources as well as indicators of geochemical processes in solid waste disposal. However, little is known of the REE occurrence in the Marcellus Shale or its produced waters, and this study represents one of the first, thorough characterizations of the REE in the Marcellus Shale. In thesemore » samples, the abundance of REE and the fractionation of REE profiles were correlated with different mineral components of the shale. Namely, samples with a larger clay component were inferred to have higher absolute concentrations of REE but have less distinctive patterns. Conversely, samples with larger carbonate fractions exhibited a greater degree of fractionation, albeit with lower total abundance. Further study is necessary to determine release mechanisms, as well as REE fate-and-transport, however these results have implications for future brine and solid waste management applications.« less

Interplay between microorganisms and geochemistry in geological carbon storage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Altman, Susan J.; Kirk, Matthew Fletcher; Santillan, Eugenio-Felipe U.

Researchers at the Center for Frontiers of Subsurface Energy Security (CFSES) have conducted laboratory and modeling studies to better understand the interplay between microorganisms and geochemistry for geological carbon storage (GCS). We provide evidence of microorganisms adapting to high pressure CO 2 conditions and identify factors that may influence survival of cells to CO 2 stress. Factors that influenced the ability of cells to survive exposure to high-pressure CO 2 in our experiments include mineralogy, the permeability of cell walls and/or membranes, intracellular buffering capacity, and whether cells live planktonically or within biofilm. Column experiments show that, following exposure tomore » acidic water, biomass can remain intact in porous media and continue to alter hydraulic conductivity. Our research also shows that geochemical changes triggered by CO 2 injection can alter energy available to populations of subsurface anaerobes and that microbial feedbacks on this effect can influence carbon storage. Our research documents the impact of CO 2 on microorganisms and in turn, how subsurface microorganisms can influence GCS. Furthermore, we conclude that microbial presence and activities can have important implications for carbon storage and that microorganisms should not be overlooked in further GCS research.« less

The Frasnian-Famennian mass killing event(s), methods of identification and evaluation

NASA Technical Reports Server (NTRS)

Geldsetzer, H. H. J.

1988-01-01

The absence of an abnormally high number of earlier Devonian taxa from Famennian sediments was repeatedly documented and can hardly be questioned. Primary recognition of the event(s) was based on paleontological data, especially common macrofossils. Most paleontologists place the disappearance of these common forms at the gigas/triangularis contact and this boundary was recently proposed as the Frasnian-Famennian (F-F) boundary. Not unexpectedly, alternate F-F positions were suggested caused by temporary Frasnian survivors or sudden post-event radiations of new forms. Secondary supporting evidence for mass killing event(s) is supplied by trace element and stable isotope geochemistry but not with the same success as for the K/T boundary, probably due to additional 300 ma of tectonic and diagenetic overprinting. Another tool is microfacies analysis which is surprisingly rarely used even though it can explain geochemical anomalies or paleontological overlap not detectable by conventional macrofacies analysis. The combination of microfacies analysis and geochemistry was applied at two F-F sections in western Canada and showed how interdependent the two methods are. Additional F-F sections from western Canada, western United States, France, Germany and Australia were sampled or re-sampled and await geochemical/microfacies evaluation.

Statistical analysis of major ion and trace element geochemistry of water, 1986-2006, at seven wells transecting the freshwater/saline-water interface of the Edwards Aquifer, San Antonio, Texas

USGS Publications Warehouse

Mahler, Barbara J.

2008-01-01

The statistical analyses taken together indicate that the geochemistry at the freshwater-zone wells is more variable than that at the transition-zone wells. The geochemical variability at the freshwater-zone wells might result from dilution of ground water by meteoric water. This is indicated by relatively constant major ion molar ratios; a preponderance of positive correlations between SC, major ions, and trace elements; and a principal components analysis in which the major ions are strongly loaded on the first principal component. Much of the variability at three of the four transition-zone wells might result from the use of different laboratory analytical methods or reporting procedures during the period of sampling. This is reflected by a lack of correlation between SC and major ion concentrations at the transition-zone wells and by a principal components analysis in which the variability is fairly evenly distributed across several principal components. The statistical analyses further indicate that, although the transition-zone wells are less well connected to surficial hydrologic conditions than the freshwater-zone wells, there is some connection but the response time is longer. 

Interplay between microorganisms and geochemistry in geological carbon storage

DOE PAGES

Altman, Susan J.; Kirk, Matthew Fletcher; Santillan, Eugenio-Felipe U.; ...

2016-02-28

Researchers at the Center for Frontiers of Subsurface Energy Security (CFSES) have conducted laboratory and modeling studies to better understand the interplay between microorganisms and geochemistry for geological carbon storage (GCS). We provide evidence of microorganisms adapting to high pressure CO 2 conditions and identify factors that may influence survival of cells to CO 2 stress. Factors that influenced the ability of cells to survive exposure to high-pressure CO 2 in our experiments include mineralogy, the permeability of cell walls and/or membranes, intracellular buffering capacity, and whether cells live planktonically or within biofilm. Column experiments show that, following exposure tomore » acidic water, biomass can remain intact in porous media and continue to alter hydraulic conductivity. Our research also shows that geochemical changes triggered by CO 2 injection can alter energy available to populations of subsurface anaerobes and that microbial feedbacks on this effect can influence carbon storage. Our research documents the impact of CO 2 on microorganisms and in turn, how subsurface microorganisms can influence GCS. Furthermore, we conclude that microbial presence and activities can have important implications for carbon storage and that microorganisms should not be overlooked in further GCS research.« less

A routine high-precision method for Lu-Hf isotope geochemistry and chronology

USGS Publications Warehouse

Patchett, P.J.; Tatsumoto, M.

1981-01-01

A method for chemical separation of Lu and Hf from rock, meteorite and mineral samples is described, together with a much improved mass spectrometric running technique for Hf. This allows (i) geo- and cosmochronology using the176Lu???176Hf+??- decay scheme, and (ii) geochemical studies of planetary processes in the earth and moon. Chemical yields for the three-stage ion-exchange column procedure average 90% for Hf. Chemical blanks are <0.2 ng for Lu and Hf. From 1 ??g of Hf, a total ion current of 0.5??10-11 Ampere can be maintained for 3-5 h, yielding 0.01-0.03% precision on the ratio176Hf/177Hf. Normalisation to179Hf/177Hf=0.7325 is used. Extensive results for the Johnson Matthey Hf standard JMC 475 are presented, and this sample is urged as an international mass spectrometric standard; suitable aliquots, prepared from a single batch of JMC 475, are available from Denver. Lu-Hf analyses of the standard rocks BCR-1 and JB-1 are given. The potential of the Lu-Hf method in isotope geochemistry is assessed. ?? 1980 Springer-Verlag.

Paragneiss zircon geochronology and trace element geochemistry, North Qaidam HP/UHP terrane, western China

USGS Publications Warehouse

Mattinson, C.G.; Wooden, J.L.; Zhang, J.X.; Bird, D.K.

2009-01-01

In the southeastern part of the North Qaidam terrane, near Dulan, paragneiss hosts minor peridotite and UHP eclogite. Zircon geochronology and trace element geochemistry of three paragneiss samples (located within a ???3 km transect) indicates that eclogite-facies metamorphism resulted in variable degrees of zircon growth and recrystallization in the three samples. Inherited zircon core age groups at 1.8 and 2.5 Ga suggest that the protoliths of these rocks may have received sediments from the Yangtze or North China cratons. Mineral inclusions, depletion in HREE, and absence of negative Eu anomalies indicate that zircon U-Pb ages of 431 ?? 5 Ma and 426 ?? 4 Ma reflect eclogite-facies zircon growth in two of the samples. Ti-in-zircon thermometry results are tightly grouped at ???660 and ???600 ??C, respectively. Inclusions of metamorphic minerals, scarcity of inherited cores, and lack of isotopic or trace element inheritance demonstrate that significant new metamorphic zircon growth must have occurred. In contrast, zircon in the third sample is dominated by inherited grains, and rims show isotopic and trace element inheritance, suggesting solid-state recrystallization of detrital zircon with only minor new growth. ?? 2009 Elsevier Ltd.

Assessment of arsenic in Australian grown and imported rice varieties on sale in Australia and potential links with irrigation practises and soil geochemistry.

PubMed

Fransisca, Yunnita; Small, Darryl M; Morrison, Paul D; Spencer, Michelle J S; Ball, Andrew S; Jones, Oliver A H

2015-11-01

Chronic dietary exposure to arsenic, particularly the inorganic forms (defined as elemental arsenic, predominantly As(3+) and As(5+), and all its inorganic compounds except arsine), is a matter of concern for human health. Ingestion of arsenic usually occurs via contaminated water but recent studies show there is also a risk of exposure from food, particularly Asian rice (Oryza sativa). Australia is a rice growing country, contributing around 2% of the world rice trade, and a large proportion of the population consumes rice regularly. In the present study we investigated concentrations of arsenic in both Australian grown and imported rice on sale in Australia and examined the potential links with irrigation practises and soil geochemistry. The results indicated a wide spread of arsenic levels of 0.09-0.33 mg kg(-1), with Australian grown Arborio and sushi varieties of O. sativa containing the highest mean value of ∼0.22 mg kg(-1). Arsenic levels in all samples were below the 1 mg kg(-1) limit set by Food Standards Australia New Zealand. Copyright © 2014 Elsevier Ltd. All rights reserved.

Leaf evolution: gases, genes and geochemistry.

PubMed

Beerling, David J

2005-09-01

This Botanical Briefing reviews how the integration of palaeontology, geochemistry and developmental biology is providing a new mechanistic framework for interpreting the 40- to 50-million-year gap between the origination of vascular land plants and the advent of large (megaphyll) leaves, a long-standing puzzle in evolutionary biology. Molecular genetics indicates that the developmental mechanisms required for leaf production in vascular plants were recruited long before the advent of large megaphylls. According to theory, this morphogenetic potential was only realized as the concentration of atmospheric CO2 declined during the late Palaeozoic. Surprisingly, plants effectively policed their own evolution since the decrease in CO2 was brought about as terrestrial floras evolved accelerating the rate of silicate rock weathering and enhancing sedimentary organic carbon burial, both of which are long-term sinks for CO2. The recognition that plant evolution responds to and influences CO(2) over millions of years reveals the existence of an intricate web of vegetation feedbacks regulating the long-term carbon cycle. Several of these feedbacks destabilized CO2 and climate during the late Palaeozoic but appear to have quickened the pace of terrestrial plant and animal evolution at that time.

Acropora interbranch skeleton Sr/Ca ratios: Evaluation of a potential new high-resolution paleothermometer

NASA Astrophysics Data System (ADS)

Sadler, James; Nguyen, Ai D.; Leonard, Nicole D.; Webb, Gregory E.; Nothdurft, Luke D.

2016-04-01

The majority of coral geochemistry-based paleoclimate reconstructions in the Indo-Pacific are conducted on selectively cored colonies of massive Porites. This restriction to a single genus may make it difficult to amass the required paleoclimate data for studies that require deep reef coring techniques. Acropora, however, is a highly abundant coral genus in both modern and fossil reef systems and displays potential as a novel climate archive. Here we present a calibration study for Sr/Ca ratios recovered from interbranch skeleton in corymbose Acropora colonies from Heron Reef, southern Great Barrier Reef. Significant intercolony differences in absolute Sr/Ca ratios were normalized by producing anomaly plots of both coral geochemistry and instrumental water temperature records. Weighted linear regression of these anomalies from the lagoon and fore-reef slope provide a sensitivity of -0.05 mmol/mol °C-1, with a correlation coefficient (r2 = 0.65) comparable to those of genera currently used in paleoclimate reconstructions. Reconstructions of lagoon and reef slope mean seasonality in water temperature accurately identify the greater seasonal amplitude observed in the lagoon of Heron Reef. A longer calibration period is, however, required for reliable reconstructions of annual mean water temperatures.

Multivariate analysis of the geochemistry and mineralogy of soils along two continental-scale transects in North America

USGS Publications Warehouse

Drew, L.J.; Grunsky, E.C.; Sutphin, D.M.; Woodruff, L.G.

2010-01-01

Soils collected in 2004 along two North American continental-scale transects were subjected to geochemical and mineralogical analyses. In previous interpretations of these analyses, data were expressed in weight percent and parts per million, and thus were subject to the effect of the constant-sum phenomenon. In a new approach to the data, this effect was removed by using centered log-ratio transformations to 'open' the mineralogical and geochemical arrays. Multivariate analyses, including principal component and linear discriminant analyses, of the centered log-ratio data reveal the effects of soil-forming processes, including soil parent material, weathering, and soil age, at the continental-scale of the data arrays that were not readily apparent in the more conventionally presented data. Linear discriminant analysis of the data arrays indicates that the majority of the soil samples collected along the transects can be more successfully classified with Level 1 ecological regional-scale classification by the soil geochemistry than soil mineralogy. A primary objective of this study is to discover and describe, in a parsimonious way, geochemical processes that are both independent and inter-dependent and manifested through compositional data including estimates of the elements and corresponding mineralogy. ?? 2010.

Ostracod Geochemistry as a Proxy for Paleoenvironmental Change

NASA Astrophysics Data System (ADS)

Carrier, A.; Herrmann, A. D.

2016-02-01

Recent studies in the field of paleoceanography suggest that the geochemistry of ostracods, through their uptake of elements from their environment, has the potential to act as proxies for paleoenvironmental change. For example, pH-sensitive elements such as Boron and Uranium potentially record changes in the environment's pH, while temperature sensitive elements Magnesium and Strontium record temperature changes. If this is the case, a random sample of ostracods taken from the same environment should have very little variation in their elemental concentration. This hypothesis was tested using a group of ostracods of the genus Cyprideis taken from a horizon in a hypersaline lake in the southwest of Big Darby Island, Bahamas. Laser-ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) was used in order to measure the elemental concentrations from each ostracod carapace. Despite differences in size and species, the ostracods showed very little variations in Boron and Uranium concentrations. However, Magnesium and Strontium showed more elemental variation in each ostracod. This data suggests that ostracod carapaces do have the potential to act as proxies for environmental pH change; however, their potential to record temperature changes is inconclusive based on these results.

Geology and surface geochemistry of the Roosevelt Springs Known Geothermal Resource Area, Utah

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lovell, J.S.; Meyer, W.T.; Atkinson, D.J.

1980-01-01

Available data on the Roosevelt area were synthesized to determine the spatial arrangement of the rocks, and the patterns of mass and energy flow within them. The resulting model lead to a new interpretation of the geothermal system, and provided ground truth for evaluating the application of soil geochemistry to exploration for concealed geothermal fields. Preliminary geochemical studies comparing the surface microlayer to conventional soil sampling methods indicated both practical and chemical advantages for the surface microlayer technique, which was particularly evident in the case of As, Sb and Cs. Subsequent multi-element analyses of surface microlayer samples collected over anmore » area of 100 square miles were processed to produce single element contour maps for 41 chemical parameters. Computer manipulation of the multi-element data using R-mode factor analysis provided the optimum method of interpretation of the surface microlayer data. A trace element association of As, Sb and Cs in the surface microlayer provided the best indication of the leakage of geothermal solutions to the surface, while regional mercury trends may reflect the presence of a mercury vapour anomaly above a concealed heat source.« less

Regional geochemistry Bandung Quadrangle West Java: for environmental and resources studies

NASA Astrophysics Data System (ADS)

Sendjaja, Purnama; Baharuddin

2017-06-01

Geochemical mapping based on the stream sediment method has been carried out in the whole of Java Region by the Centre for Geological Survey. The Regional Geochemistry Bandung Quadrangle as part of West Java Region has been mapped in 1:100.000 scale map, base on the Geological Map of Bandung Quadrangle. About 82 stream sediment samples collected and sieved in the 80 mesh sieve fraction during the field work session at 2011. This fraction was prepared and analysed for 30 elements by X-ray fluorescence spectrometry at the Centre for Geological Survey Laboratory. There are some elements indicating significant anomaly in this region, and it is important to determine the present abundance and spatial distribution of the elements for presuming result from natural product or derived from human activities. The volcanic products (Tangkuban Perahu Volcano, Volcanic Rock Complex and Quarternary Volcanic-Alluvial Deposit) are clearly identified on the distribution of As, Ba, Cl, Cu, Zr and La elements. However Mn, Zn, V and Sr are related to precipitation in the Tertiary Sediments, while the influence of human activities are showing from a geochemical map of Cl, Cr, Cu, Pb and Zn that show scattered anomalies localized close to the cities, farming and industries.

Petrology and Geochemistry of Mercury

NASA Astrophysics Data System (ADS)

Weider, Shoshana Z.

2018-04-01

Although having knowledge of a terrestrial planet's chemistry is fundamental to understanding the origin and composition of its rocks, until recently, the geochemistry of Mercury—the Solar System's innermost planet—was largely unconstrained. Without the availability of geological specimens from Mercury, studying the planet's surface and bulk composition relies on remote sensing techniques. Moreover, Mercury's proximity to the Sun makes it difficult to study with Earth/space-based telescopes, or with planetary probes. Indeed, to date, only NASA's Mariner 10 and MESSENGER missions have been sent to Mercury. The former made three "flyby" encounters of Mercury between 1974 and 1975, but did not carry any instrument to make geochemical or mineralogical measurements of the surface. Until the MESSENGER flyby and orbital campaigns (2008–2015), therefore, knowledge of Mercury's chemical composition was severely limited and consisted of only a few facts. For example, it has long been known that Mercury has the highest uncompressed density of all the terrestrial planets (and thus a disproportionately large iron core). In addition, Earth-based spectral reflectance observations indicated a dark surface, largely devoid of iron within silicate minerals. To improve understanding of Mercury's geochemistry, the MESSENGER payload included a suite of geochemical sensing instruments: namely the X-Ray Spectrometer, Gamma-Ray Spectrometer, and Neutron Spectrometer. Indeed, the datasets obtained from these instruments (as well as from other complementary instruments) during MESSENGER's 3.5-year orbital mission allow a much more complete picture of Mercury's geochemistry to be drawn, and quantitative abundance estimates for several major rock-forming elements in Mercury's crust are now available. Overall, the MESSENGER data reveal a surface that is rich in Mg, but poor in Al and Ca, compared with typical terrestrial and lunar crustal materials. Mercury's surface also contains high concentrations of the volatile elements Na, S, K, and Cl. Furthermore, the total surface Fe abundance is now known to be <2 wt%, and the planet's low reflectance is thought to be primarily caused by the presence of C (in graphite) at a level of >1 wt%. Such data are key to constraining models for Mercury's formation and early evolution. Large-scale spatial variations in the MESSENGER geochemical datasets have also led to the designation of several geochemical "terrains" across Mercury's surface, which do not always align to otherwise mapped geological regions. Based on the MESSENGER geochemical results, several recent petrological experiments and calculations have been, and continue to be, performed to study Mercury's surface mineralogy. The results show that there are substantial differences in the precise mineral compositions and abundances among the different terrains, but Mercury's surface appears to be dominated by Mg-rich olivines and pyroxenes, as well as plagioclase and sulphide phases. Depending on the classification scheme used, Mercury's ultramafic surface rocks can thus be described as similar in nature to terrestrial boninites, andesites, norites, or gabbros.

Petrogenesis of Franciscan Complex and Coast Range Ophiolite Serpentinites in northern California

NASA Astrophysics Data System (ADS)

Eldam, R.; Barnes, J.; Lee, C.; Errico, J. C.; Loewy, S. L.; Cisneros, M.

2012-12-01

Franciscan Complex serpentinites have been interpreted as eroded pieces of the overriding Coast Range Ophiolite (CRO), off-scraped pieces of the subducting oceanic plate, and as sedimentary serpentinites (e.g., Wakabayashi, 2004); however, most of these interpretations are based on tectonic models and field relationships. Here we present bulk rock major and trace element geochemistry, pyroxene and spinel geochemistry, and stable isotope data (O, H, Cl) for serpentinite samples with the goal of determining protolith origin and subsequent serpentinizing fluid sources of several metasomatized Franciscan and CRO ultramafic rocks in order to decipher the tectonic setting of serpentinization. We focused on serpentinite bodies found in the Franciscan Complex (west of Cuesta Ridge; south of San Francisco; Tiburon Peninsula; Healdsburg) (n = 12). Three samples from Cuesta Ridge (CRO) were also analyzed for comparison. All samples are >~95% serpentinized and consist of lizardite +/- chrysotile. Relict grains are rarely preserved. Franciscan serpentinites (Tiburon Peninsula, west of Cuesta Ridge) show positive-sloped REE patterns. This depletion in LREE is typical of abyssal peridotites. Relict clinopyroxenes from Tiburon Peninsula have high HREE concentrations, also supporting an abyssal origin. 2 of the 3 samples from the Cuesta Ridge show flat REE patterns; whereas, one is U-shaped. This enrichment in LREE is similar to forearc peridotites. Spinels from Cuesta Ridge have Cr# > 0.60 also implying a forearc setting; whereas, Franciscan localities have typically have lower Cr# (0.21 to 0.51). All samples show remarkable positive Ce and Y anomalies. We speculate that these anomalies may be due to interaction with ferromanganese nodules and crusts (also high in Ce and Y) on the seafloor prior to subduction. Cuesta Ridge samples have δ18O values between +6.0 to +6.6‰. Franciscan serpentinites (except those south of San Francisco) have δ18O values of +5.4 to +7.9‰. These δ18O values are similar to typical oceanic serpentinites and likely represent low-T seawater hydration on the seafloor. δD values of all samples are extremely low (-107 to -90‰) and likely result from post-serpentinization, post-emplacement interaction with meteoric water at low temperature. Samples south of San Francisco lie on the San Andreas fault and have high δ18O values (+7.2 to +9.5‰) and low δD values (-107 to -104‰) likely due to low-T interaction with meteoric water at high fluid-rock ratios. Most of the serpentinites (12 of the 15) have δ37Cl values between +0.2 and +0.9‰, typical values for serpentinites formed by interaction with seawater. Based on bulk rock geochemistry and pyroxene and spinel compositions, serpentinites located within the Franciscan Complex have geochemical characteristics of abyssal peridotites; whereas, those from Cuesta Ridge are more chemically heterogeneous with most having affinity to forearc peridotites. All stable isotope geochemistry indicates seafloor serpentinization by seawater. Wakabayashi, J., 2004, International Geology Review, 46, 1103-1118.

Significant achievements in the planetary geology program, 1981

NASA Technical Reports Server (NTRS)

Holt, H. E. (Editor)

1981-01-01

Recent developments in planetology research as reported at the 1981 NASA Planetary Geology Principal Investigators meeting are summarized. The evolution of the solar system, comparative planetology, and geologic processes active on other planets are considered. Galilean satellites and small bodies, Venus, geochemistry and regoliths, volcanic and aeolian processes and landforms, fluvial and periglacial processes, and planetary impact cratering, remote sensing, and cartography are discussed.

Geochemistry of an abandoned landfill containing coal combustion waste: Implications for remediation

Treesearch

Christopher Barton; Linda Paddock; Christopher Romanek; John Seaman

2001-01-01

The 488-D Ash Basin (488-DAB) is an unlined, earthen landfill containing approximately one million tons of dry ash and coal reject material at the U.S. Department of Energy's Savannah River Site, SC. The pyritic nature of the coal rejects has resulted in the formation of acidic drainage (AD), which has contributed to groundwater deterioration and threatened biota...

GEOCHEMISTRY AND CHARACTERISTICS OF NITROGEN TRANSPORT AT A CONFINED ANIMAL FEEDING OPERATION IN A COASTAL PLAIN AGRICULTURAL WATERSHED, AND IMPLICATIONS FOR NUTRIENT LOADING IN THE NEUSE RIVER BASIN, NORTH CAROLINA, 1999-2002

EPA Science Inventory

Chemical, geologic, hydrologic, and age-dating information collected between 1999 and 2002 were used to examine the transport of contaminants, primarily nitrogen, in ground water and the pathways to surface water in a coastal plain setting in North Carolina. Data were collected f...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The purpose of this report is to: (a) review the extensive published and unpublished literature on the geochemistry, hydrology and geology of Lake Magadi, Kenya, and its associated hot springs; (b) based on this review of field visits, estimate the temperature in the geothermal reservoir beneath the lake; and (c) from this, develop a plan to determine the potential for the development of geothermal electric power at Lake Magadi. 6 refs., 9 figs., 2 tabs.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Palumbo, Anthony V.

Our current research represents a joint effort between Oak Ridge National Laboratory (ORNL), the University of Tennessee (UT), and Florida State University (FSU). ORNL serves as the lead institution with Dr. A.V. Palumbo responsible for project coordination, integration, and deliverables. This project is in its second year. The overall goal of our project is to provide an improved understanding of the relationships between microbial community structure, geochemistry, and metal reduction rates.

The Archean crust in the Wawa-Chapleau-Timmins region. A field guidebook prepared for the 1983 Archean Geochemistry-Early Crustal Genesis Field Conference

NASA Technical Reports Server (NTRS)

Percival, J. A.; Card, K. D.; Sage, R. P.; Jensen, L. S.; Luhta, L. E.

1983-01-01

This guidebook describes the characteristics and interrelationships of Archean greenstone-granite and high-grade gneiss terrains of the Superior Province. A 300-km long west to east transect between Wawa and Timmins, Ontario will be used to illustrate regional-scale relationships. The major geological features of the Superior Province are described.

Twenty-fourth Lunar and Planetary Science Conference. Part 1: A-F

NASA Technical Reports Server (NTRS)

1993-01-01

The topics covered include the following: petrology, petrography, meteoritic composition, planetary geology, atmospheric composition, astronomical spectroscopy, lunar geology, Mars (planet), Mars composition, Mars surface, volcanology, Mars volcanoes, Mars craters, lunar craters, mineralogy, mineral deposits, lithology, asteroids, impact melts, planetary composition, planetary atmospheres, planetary mapping, cosmic dust, photogeology, stratigraphy, lunar craters, lunar exploration, space exploration, geochronology, tectonics, atmospheric chemistry, astronomical models, and geochemistry.

Field testing of aquifer thermal energy storage

NASA Astrophysics Data System (ADS)

Kannberg, L. D.; Allen, R. D.

1984-03-01

Results of field and laboratory studies of aquifer thermal energy storage (ATES) indicate both the problems and promise of the concept. Geohydrothermal modeling and field testing demonstrated the ability to recover substantial quantities of aquifer stored energy. However, the local hydrologic conditions play an important role in determining the recovery temperature and storage efficiency. Geochemistry is also an important factor, particularly for higher temperature ATES systems.

"THE DYNAMICS OF ARSENIC IN SATURATED POROUS MEDIA: FATE AND TRANSPORT MODELING FOR DEEP-WATER SEDIMENTS, WETLAND SEDIMENTS, AND GROUNDWATER ENVIRONMENTS," WATER ROCK INTERACTIONS, ORE DEPOSITS, AND ENVIRONMENTAL GEOCHEMISTRY: A TRIBUTE TO DAVID CRERAR. (R827288)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

Data Set 1

EPA Pesticide Factsheets

The data set contains the raw data used to develop the figures and tables associated with the published manuscriptThis dataset is associated with the following publication:Eckley , C., T. Luxton , J. McKernan , J. Goetz , and J. Goulet. Influence of Reservoir Water-Level Fluctuations on Mercury Methylation Downstream of the Historic Black Butte Mercury Mine, OR. Michael Kersten APPLIED GEOCHEMISTRY. Elsevier Science Ltd, New York, NY, USA, 61: 284-293, (2015).

Geological and Geochemical Controls on Subsurface Microbial Life in the Samail Ophiolite, Oman.

PubMed

Rempfert, Kaitlin R; Miller, Hannah M; Bompard, Nicolas; Nothaft, Daniel; Matter, Juerg M; Kelemen, Peter; Fierer, Noah; Templeton, Alexis S

2017-01-01

Microbial abundance and diversity in deep subsurface environments is dependent upon the availability of energy and carbon. However, supplies of oxidants and reductants capable of sustaining life within mafic and ultramafic continental aquifers undergoing low-temperature water-rock reaction are relatively unknown. We conducted an extensive analysis of the geochemistry and microbial communities recovered from fluids sampled from boreholes hosted in peridotite and gabbro in the Tayin block of the Samail Ophiolite in the Sultanate of Oman. The geochemical compositions of subsurface fluids in the ophiolite are highly variable, reflecting differences in host rock composition and the extent of fluid-rock interaction. Principal component analysis of fluid geochemistry and geologic context indicate the presence of at least four fluid types in the Samail Ophiolite ("gabbro," "alkaline peridotite," "hyperalkaline peridotite," and "gabbro/peridotite contact") that vary strongly in pH and the concentrations of H 2 , CH 4 , Ca 2+ , Mg 2+ , [Formula: see text], [Formula: see text], trace metals, and DIC. Geochemistry of fluids is strongly correlated with microbial community composition; similar microbial assemblages group according to fluid type. Hyperalkaline fluids exhibit low diversity and are dominated by taxa related to the Deinococcus-Thermus genus Meiothermus , candidate phyla OP1, and the family Thermodesulfovibrionaceae. Gabbro- and alkaline peridotite- aquifers harbor more diverse communities and contain abundant microbial taxa affiliated with Nitrospira , Nitrosospharaceae, OP3, Parvarcheota, and OP1 order Acetothermales. Wells that sit at the contact between gabbro and peridotite host microbial communities distinct from all other fluid types, with an enrichment in betaproteobacterial taxa. Together the taxonomic information and geochemical data suggest that several metabolisms may be operative in subsurface fluids, including methanogenesis, acetogenesis, and fermentation, as well as the oxidation of methane, hydrogen and small molecular weight organic acids utilizing nitrate and sulfate as electron acceptors. Dynamic nitrogen cycling may be especially prevalent in gabbro and alkaline peridotite fluids. These data suggest water-rock reaction, as controlled by lithology and hydrogeology, constrains the distribution of life in terrestrial ophiolites.

What's in the mud?: Water-rock-microbe interactions in thermal mudpots and springs

NASA Astrophysics Data System (ADS)

Dahlquist, G. R.; Cox, A. D.

2016-12-01

Limited aspects of mudpot geochemistry, mineralogy, and microbiology have been previously investigated in a total of 58 mudpots in Yellowstone National Park (YNP), Kamchatka, Iceland, Italy, Valles Caldera, New Mexico, Nicaragua, and the Stefanos hydrothermal crater, Greece (Allen and Day, 1935; Raymahashay, 1968; Shevenell, 1987; Bradley, 2005; Prokofeva, 2006; Bortnikova, 2007; Kaasalainen, 2012; Szynkiewicz, 2012; Hynek, 2013; Pol, 2014; Kanellopoulos, 2016). The composition of 35 mudpots was analyzed for aqueous geochemistry of filtrate and solid phase characterization. Here mudpots are defined as thermal features with viscosities between 5 and 100 centipoise at the approximate temperature of the mudpot, which was measured by an Ofite hand cranked viscometer. Analogous samples of nearby hot springs provide comparisons between mudpots and non-viscous thermal features. Aqueous geochemistry from mudpots was obtained by a novel two-step filtration process consisting of gravity prefiltration by a 100 or 50 micron trace metal cleaned polyethylene bag filter followed by syringe filtration with 0.8/0.2 Supor membrane filters. This filtered sample water was preserved and analyzed for water isotopes, major anions and cations, dissolved organic carbon, and trace metals. Mudpot meter readings show dissolved oxygen values ranging from below the detection limit of 0.156 to 22.5uM, pH values ranging from 1.41 to 6.08, and temperatures ranging from 64.8 to 92.5°C. Mudpots and turbid hot springs exhibited an inverse relationship between dissolved rare earth element concentrations and dissolved calcium concentrations (where calcium concentrations > 0.4mM). Mudpots altered existing surficial geology to form clays, primarily kaolinite, montmorillionite, and alunite. This hydrothermal alteration leaches metals, allowing mudpots to concentrate metals. DNA was extracted from mudpot solids and amplified with eukaryotic, bacterial, archaeal, and universal primers, which yielded only bacterial and archaeal amplicons. Water, rock, and microbial communities interact to form diverse mudpots. The range of chemical conditions surveyed in YNP mudpots suggests varying underlying rock units, seasonal water variations, and sources of organic matter drastically affect geobiochemical characteristics.

Intriguing Connections Between Economic Geology, the Environment, Human Health, and Disasters: Observations from my Career(s) in Transdisciplinary Science

NASA Astrophysics Data System (ADS)

Plumlee, G. S.

2015-12-01

I have been fortunate to be able to follow a varied career path from economic geology, to environmental geochemistry, to geochemistry and human health, to environmental disasters. I have been privileged to collaborate with many exceptional scientists from across and well beyond the earth sciences (e.g., public heath, engineering, economics, emergency response, microbiology). Much of this transdisciplinary work has intriguing links back to economic geology/geochemistry. Geological characteristics of different ore deposit types predictably influence the environmental and health impacts of mining, and so can help anticipate and prevent adverse impacts before they occur. Geologic maps showing potential for natural occurrences of asbestos or erionite are analogous to permissive tract maps used for mineral-resource assessments, and can be correlated with epidemiological data to help understand whether living on or near such rocks poses a risk for developing asbestos-related diseases. Mineral particles that are taken up by the human body along inhalation or incidental ingestion exposure routes are "weathered" by reactions with diverse body fluids that differ greatly in composition between and along the different exposure routes. These in vivo chemical reactions (e.g., dissolution, alteration, metal complexation, oxidation/reduction, reprecipitation) are in ways analogous to processes of ore deposit formation and weathering, and some can be shown (in collaboration with toxicologists) to play a role in toxicity. Concepts of ore petrography and paragenesis can be applied to interpret (in collaboration with pathologists) the origin, physiological implications, and toxicity effects of mineral matter in human tissue samples obtained by biopsy, transplant or autopsy. Some disaster materials can originate from mining- or mineral-processing sources, and methods originally developed to study ore deposits or mining-environmental issues can also be applied to understand many disaster materials. These examples illustrate an appropriate core role for earth scientists in transdisciplinary research: applying our expertise and toolkits to help understand topics well beyond earth sciences, but doing so in collaboration with experts from disciplines that traditionally examine those topics.

Geological and geochemical controls on subsurface microbial life in the Samail Ophiolite, Oman

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rempfert, Kaitlin R.; Miller, Hannah M.; Bompard, Nicolas

Microbial abundance and diversity in deep subsurface environments is dependent upon the availability of energy and carbon. However, supplies of oxidants and reductants capable of sustaining life within mafic and ultramafic continental aquifers undergoing low-temperature water-rock reaction are relatively unknown. We conducted an extensive analysis of the geochemistry and microbial communities recovered from fluids sampled from boreholes hosted in peridotite and gabbro in the Tayin block of the Samail Ophiolite in the Sultanate of Oman. The geochemical compositions of subsurface fluids in the ophiolite are highly variable, reflecting differences in host rock composition and the extent of fluid-rock interaction. Principal component analysis of fluid geochemistry and geologic context indicate the presence of at least four fluid types in the Samail Ophiolite (“gabbro,” “alkaline peridotite,” “hyperalkaline peridotite,” and “gabbro/peridotite contact”) that vary strongly in pH and the concentrations of H 2, CH 4, Ca 2+, Mg 2+, NO 3 more » $-$, SO$$2-\\atop{4}$$, trace metals, and DIC. Geochemistry of fluids is strongly correlated with microbial community composition; similar microbial assemblages group according to fluid type. Hyperalkaline fluids exhibit low diversity and are dominated by taxa related to the Deinococcus-Thermus genus Meiothermus, candidate phyla OP1, and the family Thermodesulfovibrionaceae. Gabbro- and alkaline peridotite- aquifers harbor more diverse communities and contain abundant microbial taxa affiliated with Nitrospira, Nitrosospharaceae, OP3, Parvarcheota, and OP1 order Acetothermales. Wells that sit at the contact between gabbro and peridotite host microbial communities distinct from all other fluid types, with an enrichment in betaproteobacterial taxa. Together the taxonomic information and geochemical data suggest that several metabolisms may be operative in subsurface fluids, including methanogenesis, acetogenesis, and fermentation, as well as the oxidation of methane, hydrogen and small molecular weight organic acids utilizing nitrate and sulfate as electron acceptors. Dynamic nitrogen cycling may be especially prevalent in gabbro and alkaline peridotite fluids. As a result, these data suggest water-rock reaction, as controlled by lithology and hydrogeology, constrains the distribution of life in terrestrial ophiolites.« less

Environmental drivers of differences in microbial community structure in crude oil reservoirs across a methanogenic gradient

USGS Publications Warehouse

Shelton, Jenna L.; Akob, Denise M.; McIntosh, Jennifer C.; Fierer, Noah; Spear, John R.; Warwick, Peter D.; McCray, John E.

2016-01-01

Stimulating in situ microbial communities in oil reservoirs to produce natural gas is a potentially viable strategy for recovering additional fossil fuel resources following traditional recovery operations. Little is known about what geochemical parameters drive microbial population dynamics in biodegraded, methanogenic oil reservoirs. We investigated if microbial community structure was significantly impacted by the extent of crude oil biodegradation, extent of biogenic methane production, and formation water chemistry. Twenty-two oil production wells from north central Louisiana, USA, were sampled for analysis of microbial community structure and fluid geochemistry. Archaea were the dominant microbial community in the majority of the wells sampled. Methanogens, including hydrogenotrophic and methylotrophic organisms, were numerically dominant in every well, accounting for, on average, over 98% of the total Archaea present. The dominant Bacteria groups were Pseudomonas, Acinetobacter, Enterobacteriaceae, and Clostridiales, which have also been identified in other microbially-altered oil reservoirs. Comparing microbial community structure to fluid (gas, water, and oil) geochemistry revealed that the relative extent of biodegradation, salinity, and spatial location were the major drivers of microbial diversity. Archaeal relative abundance was independent of the extent of methanogenesis, but closely correlated to the extent of crude oil biodegradation; therefore, microbial community structure is likely not a good sole predictor of methanogenic activity, but may predict the extent of crude oil biodegradation. However, when the shallow, highly biodegraded, low salinity wells were excluded from the statistical analysis, no environmental parameters could explain the differences in microbial community structure. This suggests that the microbial community structure of the 5 shallow, up-dip wells was different than the 17 deeper, down-dip wells. Also, the 17 down-dip wells had statistically similar microbial communities despite significant changes in environmental parameters between oil fields. Together, this implies that no single microbial population is a reliable indicator of a reservoir's ability to degrade crude oil to methane, and that geochemistry may be a more important indicator for selecting a reservoir suitable for microbial enhancement of natural gas generation.

Geological and Geochemical Controls on Subsurface Microbial Life in the Samail Ophiolite, Oman

PubMed Central

Rempfert, Kaitlin R.; Miller, Hannah M.; Bompard, Nicolas; Nothaft, Daniel; Matter, Juerg M.; Kelemen, Peter; Fierer, Noah; Templeton, Alexis S.

2017-01-01

Microbial abundance and diversity in deep subsurface environments is dependent upon the availability of energy and carbon. However, supplies of oxidants and reductants capable of sustaining life within mafic and ultramafic continental aquifers undergoing low-temperature water-rock reaction are relatively unknown. We conducted an extensive analysis of the geochemistry and microbial communities recovered from fluids sampled from boreholes hosted in peridotite and gabbro in the Tayin block of the Samail Ophiolite in the Sultanate of Oman. The geochemical compositions of subsurface fluids in the ophiolite are highly variable, reflecting differences in host rock composition and the extent of fluid-rock interaction. Principal component analysis of fluid geochemistry and geologic context indicate the presence of at least four fluid types in the Samail Ophiolite (“gabbro,” “alkaline peridotite,” “hyperalkaline peridotite,” and “gabbro/peridotite contact”) that vary strongly in pH and the concentrations of H2, CH4, Ca2+, Mg2+, NO3-, SO42-, trace metals, and DIC. Geochemistry of fluids is strongly correlated with microbial community composition; similar microbial assemblages group according to fluid type. Hyperalkaline fluids exhibit low diversity and are dominated by taxa related to the Deinococcus-Thermus genus Meiothermus, candidate phyla OP1, and the family Thermodesulfovibrionaceae. Gabbro- and alkaline peridotite- aquifers harbor more diverse communities and contain abundant microbial taxa affiliated with Nitrospira, Nitrosospharaceae, OP3, Parvarcheota, and OP1 order Acetothermales. Wells that sit at the contact between gabbro and peridotite host microbial communities distinct from all other fluid types, with an enrichment in betaproteobacterial taxa. Together the taxonomic information and geochemical data suggest that several metabolisms may be operative in subsurface fluids, including methanogenesis, acetogenesis, and fermentation, as well as the oxidation of methane, hydrogen and small molecular weight organic acids utilizing nitrate and sulfate as electron acceptors. Dynamic nitrogen cycling may be especially prevalent in gabbro and alkaline peridotite fluids. These data suggest water-rock reaction, as controlled by lithology and hydrogeology, constrains the distribution of life in terrestrial ophiolites. PMID:28223966

Integrated modelling of enhanced in situ biodenitrification in a fractured aquifer: biogeochemistry and isotope geochemistry

NASA Astrophysics Data System (ADS)

Rodríguez-Escales, Paula; Folch, Albert; van Breukelen, Boris M.; Vidal-Gavilan, Georgina; Soler, Albert

2014-05-01

Enhanced in-situ biodenitrification is a feasible technology to recovery groundwater polluted by nitrates and achieves drinking water standards. Under optimum conditions, nitrate is reduced by autochthonous bacteria trough different reactions until arrive to harmless dinitrogen gas. Isotopic fractionation monitoring in field applications allows knowing the exact degree and the real scope of this technology. Using the Rayleigh equation the change in the isotope ratio of the nitrate molecule (δ15N-NO3-, δ18O-NO3-) is related to the fraction of molecules remaining as a result of biodenitrification. However, Rayleigh application at field scale is sometimes limited due to other processes involved during groundwater flow such as dispersion or adsorption and geological media heterogeneities that interferes in concentration values. Then, include isotope fractionation processes in reactive transport models is a useful tool to interpret and predict data from in-situ biodenitrification. We developed a reactive transport model of enhanced in situ application at field scale in a fractured aquifer that considers biogeochemical processes as well as isotope fractionation to enable better monitoring and management of this technology. Processes considered were: microbiological- exogenous and endogenous nitrate and sulfate respiration coupled with microbial growth and decay, geochemical reactions (precipitation of calcite) and isotopic fractionation (δ15N-NO3-; δ18O- NO3- and carbon isotope network). The 2-D simulations at field scale were developed using PHAST code. Modeling of nitrate isotope geochemistry has allowed determining the extent of biodenitrification in model domain. We have quantified which is the importance in decreasing of nitrate concentrations due to biodegradation (percentage of biodegradation, 'B%') and due to dilution process (percentage of dilution, 'D%'). On the other hand, the stable carbon isotope geochemistry has been modeled. We have considered the isotopic carbon fractionation of different carbon species involved in enhanced biodenitrification: external organic carbon, biomass, inorganic carbon (in different forms) and calcite. The inclusion of carbon isotopes in the model, which are involved in both direct (oxidation of organic carbon) and indirect (carbonate mineral interaction) processes of enhanced biodenitrification, improves the evaluation of the overall model consistency due to the central role of carbon in the reaction network.

New Insights into an Old Cycle: The Marine Phosphorus Cycle and the Formation of Critical Phosphate Rock Resources (Invited)

NASA Astrophysics Data System (ADS)

Filippelli, G. M.

2010-12-01

The cycling and geochemistry of phosphorus (P) in the marine environment is a critical component of biological productivity and of resource availability: P control the long-term carbon cycle via its role as a limiting nutrient, and the burial and concentration of P within marine sediments dictates the quality and availability of P as a fertilizer component from a resources standpoint. Given the projections of severe P fertilizer limitation over the next several centuries, understanding the controls on P geochemistry and concentration into a minable resource is critical in sustaining global populations. Several critical aspects of the marine P cycle have been uncovered over the past few decades which have clarified our understanding of P burial and concentration. First, the initial authigenic process of P mineralization within marine sediments, termed phosphogenesis, seems to occur regardless of marine setting. Phosphogenesis results from the release of P into sedimentary pore waters from organic and oxide-bound fractions, and the subsequent supersaturation with respect to carbonate fluorapatite. In sediment-starved basins with significant upwelling-driven productivity, the supply of P into sedimentary pore waters can be so high that visibly apparent layers of carbonate fluorapatite can be formed. Even in such environments, however, the mineral P content is too low to be of economic value unless it has undergone concentration via sediment reworking, a common occurrence in some dynamic continental margin environments. Thus, a combination of phosphogenesis in a high productivity setting plus sediment starvation plus condensation via reworking are necessary to produce phosphorites, sedimentary rocks with high P contents which are ideal as fertilizer-grade P resources. Given these special marine conditions, phosphorites are largely distributed along ancient marine environments (with the exception of the nearly-depleted atoll guano reserves). The largest currently-identified minable reservoirs of ore-grade P are found in the United States, in China, and in Morocco. Numerous less-economic sedimentary deposits exist, but these deposits are more dilute and represent former marine settings without the trifecta of productivity, geochemistry and sedimentology that makes phosphorites economically viable.

Coal Formation and Geochemistry

NASA Astrophysics Data System (ADS)

Orem, W. H.; Finkelman, R. B.

2003-12-01

Coal is one of the most complex and challenging natural materials to analyze and to understand. Unlike most rocks, which consist predominantly of crystalline mineral grains, coal is largely an assemblage of amorphous, degraded plant remains metamorphosed to various degrees and intermixed with a generous sprinkling of minute syngenetic, diagenetic, epigenetic, and detrital mineral grains, and containing within its structure various amounts of water, oils, and gases. Each coal is unique, having been derived from different plant sources over geologic time, having experienty -45ced different thermal histories, and having been exposed to varying geologic processes. This diversity presents a challenge to constructing a coherent picture of coal geochemistry and the processes that influence the chemical composition of coal.Despite the challenge coal presents to geochemists, a thorough understanding of the chemistry and geology of this complex natural substance is essential because of its importance to our society. Coal is, and will remain for sometime, a crucial source of energy for the US and for many other countries (Figure 1). In the USA, more than half of the electricity is generated by coal-fired power plants, and almost 90% of the coal mined in the USA is sold for electricity generation (Pierce et al., 1996). It is also an important source of coke for steel production, chemicals, pharmaceuticals, and even perfumes ( Schobert, 1987). It may also, in some cases, be an economic source of various mineral commodities. The utilization of coal through mining, transport, storage, combustion, and the disposal of the combustion by-products, also presents a challenge to geochemists because of the wide range of environmental and human health problems arising from these activities. The sound and effective use of coal as a natural resource requires a better understanding of the geochemistry of coal, i.e., the chemical and mineralogical characteristics of the coal that control its technological behavior, by-product characteristics, and environmental and human health impacts. In this chapter, we will try to make geochemical sense of this wonderfully complex and important resource. (5K)Figure 1. Photograph of a low rank coal bed (lignite of Pliocene age) from southwestern Romania.

Geochemistry of Permian rocks from the margins of the Phosphoria Basin

USGS Publications Warehouse

Perkins, Robert B.; McIntyre, Brandie; Hein, James R.; Piper, David Z.

2003-01-01

The Permian Phosphoria Formation and interbedded units of the Park City Formation and Shedhorn Sandstone in western Wyoming represent deposition along a carbonate ramp at the eastern margin of the Phosphoria Basin, with portions of the Phosphoria units reflecting periods of upwelling and widespread phosphogenesis. Thickness-weighted slab-samples of these units were collected at a maximum interval of 3 m along an 80+ m-length of unweathered core and analyzed for major-, minor-, and trace-element contents. Interpretations of geochemistry were made within the confines of a previously recognized sequence stratigraphy framework. Major shifts in element ratios characteristic of terrigenous debris that occur at sequence boundaries at the base of the Meade Peak and Retort Members of the Phosphoria Formation are attributed to changing sediment sources. Inter-element relationships in the marine fraction indicate that bottom waters of the Phosphoria Basin were predominantly denitrifying during deposition of the Ervay, Grandeur, and Phosphoria sediments, although sulfate-reducing conditions may have existed during deposition of the lower Meade Peak sediments. Oxic conditions were prevalent during deposition of a large part of the Franson Member, which represents sedimentation in a shallow, inner- to back-ramp setting. Variations in sediment facies and organic matter and trace element contents largely reflect changes in Permian sea level. Changes in sea level in basin-margin areas, such as represented by the study section, may have affected the oxidation of settling organic matter, the foci of intersection of upwelling bottom waters with the photic zone, the rate of terrigenous sedimentation, and, ultimately, the overall environment of deposition. Our study suggests that phosphogenesis can occur under lowstand, transgressive, and highstand conditions in marginal areas, assuming water depths sufficient for upwelling to occur. Formation of phosphorite layers under upwelling conditions appears to have been most dependent on a lack of dilution by terrigenous sedimentation and carbonate shoaling. Differences in the geochemistry between two similar environments represented by the upper and lower Phosphoria units are largely attributed to higher rates of diluting terrigenous sediment during deposition of the upper unit. This is consistent with prior interpretations of a more shoreward setting for the upper Phosphoria.

Trace Element Geochemistry of Silica Phases: Understanding the Evolution of the Cerro Pabellón Geothermal System

NASA Astrophysics Data System (ADS)

Alvear, B.; Morata, D.; Leisen, M.; Reich, M.; Barra, F.

2017-12-01

The study of mineral textures coupled with trace element geochemistry has proven to be a useful tool to understand the evolution of geological environments. The purpose of this study is to provide new constrains on the formation of an active geothermal system, specifically the Cerro Pabellón field. The Cerro Pabellón system is located at 4500 m above sea level and is the first geothermal power plant in operation in Chile and South America. Thirteen samples were collected from a 550 m long drill core. Samples were first studied under petrographic microscopy followed by scanning electron microscopy coupled with a cathodoluminescence detector (CL-SEM). The different textures recognized using petrography and the CL-SEM technique were later analyzed by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) in order to determine variations in the trace element concentrations as a function of silica textures. Two vein types (A and B) with different silica polymorphs were identified by CL-SEM. Vein type A has only a colloform texture, whereas vein type B, younger and crosscutting the type A, shows zonation, colloform, and jigsaw textures. LA-ICPMS results show high concentrations of Li, Al, Na, K, As, and Sb for all types of silica. A comparison between vein type A and B, show that vein type A is Al-Na-K-Li poor (2088, 36, 309, and 122 ppm average, respectively) and As-Sb rich (43 and 249 ppm average, respectively). On the other hand, vein type B has variable concentrations of Al-Na-K-Li-Sb, but usually higher than in vein type A. Overall, the Cerro Pabellón geothermal system shows high concentrations of Li and Sb, reaching up to 360 and 703 ppm, respectively. Our preliminary results show that the trace element geochemistry is strongly related to the different silica textures, which formed as a response to different thermodynamic conditions and fluid-rock ratios. This work is a contribution to the FONDAP-CONICYT 15090013 Project.

Geological, geochemical and isotope diversity of 134 Ma dykes from the Florianópolis Dyke Swarm, Paraná Magmatic Province: Geodynamic controls on petrogenesis

NASA Astrophysics Data System (ADS)

Florisbal, L. M.; Janasi, V. A.; Bitencourt, M. F.; Nardi, L. V. S.; Marteleto, N. S.

2018-04-01

The Florianópolis Dyke Swarm (FDS), one of the major dyke swarms belonging to the Early cretaceous (135-131 Ma) Paraná Magmatic Province, is largely dominated by high Sr-Ti-P basalts that are confirmed here as feeders of the unique Urubici (= Khumib) lavas of the Paraná and Edendeka lava piles on the basis of their age and geochemistry. Our study integrates field, petrographic, whole-rock geochemistry, and Sr-Nd-Pb isotope geochemistry of representative samples from three main areas of exposition (Santa Catarina Island, Garopaba and Pinheira beaches), thus encompassing the whole extension of the FDS. Compared to the Urubici lavas, the dykes have usually higher contents of LILE and LREE, more radiogenic Sr and Pb, and more unradiogenic Nd, features attributed to a more pronounced interaction with melts derived from the country rocks registered in the basic magmas that remained in the conduits. Some of these dykes show strongly interactive contacts that must be part of a wider zone of crustal melting, probably more developed at greater depths. Small volumes of intermediate to acidic rocks form the cores of some composite dykes, and correspond to products of fractional crystallization from Urubici basalts contaminated with high Rb/Sr, and U/Th crustal melts (probably derived from Neoproterozoic granites), as indicated by geochemical and Sr-Nd-Pb isotope data. The chemical and isotope signatures of the less contaminated FDS basalts and related Urubici lavas do not show clear evidence of inputs from primitive mantle, and seem heavily influenced by enriched mantle. This suggests that the mantle wedge that was affected by subduction during the Neoproterozoic may have been frozen and coupled to the base of the lithospheric plate where the Early cretaceous magmatism occurred. A control of previous tectonic limits on the sources of the Urubici basalts seems evident, since they seem to be related to the younger lithosphere from the South Domain, related to the Florianópolis Batholith, and no influence from the older "cratonic" lithosphere of the Central Domain can be identified in their feeders.

Advances in authigenic silicate geochemistry: Evidence for Precessional Control of Pleistocene Lake Salinity at Olduvai Gorge, Tanzania

NASA Astrophysics Data System (ADS)

Deocampo, D.; Simpson, A. J.; Cuadros, J.; Beverly, E.; Ashley, G. M.; Delaney, J. S.; Longstaffe, F. J.

2017-12-01

Magnesium enrichment of authigenic clays is an indicator of elevated salinity in hydrologically closed lake basins. Studies at Olduvai Gorge over the last four decades have shown that chemically-precipitated clay minerals form a substantial portion of the sedimentary succession, in some intervals even dominating the sediment. Outcrops of lacustrine mud in two localities near the depocenter were examined using a new geochronological framework based on Ar/Ar dating of volcaniclastic sanidine (Deino, 2012). Olduvai's clay mineralogy is dominated by 2:1 clays, including smectite, illite, and interstratified illite-smectite. Previous work has shown that clay alteration includes octahedral Mg-enrichment, Fe-reduction, K-fixation, and low-temperature illitization. Here we show that long term environmental conditions in Paleolake Olduvai indicated by sub-micron clay geochemistry were generally saline and alkaline between 1.78 and 1.92 Ma, but 6 episodes of freshened paleolake water are indicated by intervals of lower Mg content. Five of these freshening episodes occurred at peak climatic precession. The sub-micron clay geochemistry agrees with infrared spectroscopy and whole-rock geochemical compositions, and the same stratigraphic variation is observed at both localities, separated laterally by 330m. Preliminary analyses show that the <0.1µm clay mineral δ18Oclay suggest a δ18OH2O range of about -4 to +3‰ (SMOW) through this stratigraphic interval. No significant correlation is found with elemental composition, but lighter isotopic values are associated stratigraphically with geochemically defined freshening events. This suggests that isotopic and elemental equilibrium may not be reached at the same time, or that diagenetic events may have differentially altered the isotopic record. The environmental changes recorded in the Olduvai sediments occurred at a time when zonal Walker circulation increasingly affected global climate, new stone technologies emerged, and the genus Homo spread beyond Africa. Unraveling the details of mineralogical records such as those at Olduvai will be important in characterizing details of continental Quaternary environmental change, particularly in stratigraphic intervals where biotic proxies are unavailable.

Influence of rock composition on the geochemistry of stream and spring waters from mountainous watersheds in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado

USGS Publications Warehouse

Miller, William Roger

2002-01-01

The ranges of geochemical baselines for stream and spring waters were determined and maps were constructed showing acid-neutralizing capacity and potential release of total dissolved solids for streams and spring waters for watersheds underlain by each of ten different rock composition types in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado (GMUG). Water samples were collected in mountainous headwater watersheds that have comparatively high precipitation and low evapotranspiration rates and that generally lack extensive ground-water reservoirs. Mountainous headwaters react quickly to changes in input of water from rain and melting snow and they are vulnerable to anthropogenic impact. Processes responsible for the control and mobility of elements in the watersheds were investigated. The geochemistry of water from the sampled watersheds in the GMUG, which are underlain by rocks that are relatively unmineralized, is compared to the geochemistry of water from the mineralized Redcloud Peak area. The water with the highest potential for release of total dissolved solids is from watersheds that are underlain by Paleozoic sedimentary rocks; that high potential is caused primarily by gypsum in those rocks. Water that has the highest acid-neutralizing capacity is from watersheds that are underlain by Paleozoic sedimentary rocks. The water from watersheds underlain by the Mancos Shale has the next highest acid-neutralizing capacity. Water that has the lowest acid-neutralizing capacity is from watersheds that are underlain by Tertiary ash-flow tuff. Tertiary sedimentary rocks containing oil shale, the Mesavede Formation containing coal, and the Mancos Shale all contain pyrite with elevated metal contents. In these mountainous head-water areas, water from watersheds underlain by these rock types is only slightly impacted by oxidation of pyrite, and over-all it is of good chemical quality. These geochemical baselines demonstrate the importance of rock composition in determining the types of waters that are in the headwater areas. The comparison of these geochemical baselines to later geochemical base-lines will allow recognition of any significant changes in water quality that may occur in the future.

Tomography & Geochemistry: Precision, Repeatability, Accuracy and Joint Interpretations

NASA Astrophysics Data System (ADS)

Foulger, G. R.; Panza, G. F.; Artemieva, I. M.; Bastow, I. D.; Cammarano, F.; Doglioni, C.; Evans, J. R.; Hamilton, W. B.; Julian, B. R.; Lustrino, M.; Thybo, H.; Yanovskaya, T. B.

2015-12-01

Seismic tomography can reveal the spatial seismic structure of the mantle, but has little ability to constrain composition, phase or temperature. In contrast, petrology and geochemistry can give insights into mantle composition, but have severely limited spatial control on magma sources. For these reasons, results from these three disciplines are often interpreted jointly. Nevertheless, the limitations of each method are often underestimated, and underlying assumptions de-emphasized. Examples of the limitations of seismic tomography include its ability to image in detail the three-dimensional structure of the mantle or to determine with certainty the strengths of anomalies. Despite this, published seismic anomaly strengths are often unjustifiably translated directly into physical parameters. Tomography yields seismological parameters such as wave speed and attenuation, not geological or thermal parameters. Much of the mantle is poorly sampled by seismic waves, and resolution- and error-assessment methods do not express the true uncertainties. These and other problems have become highlighted in recent years as a result of multiple tomography experiments performed by different research groups, in areas of particular interest e.g., Yellowstone. The repeatability of the results is often poorer than the calculated resolutions. The ability of geochemistry and petrology to identify magma sources and locations is typically overestimated. These methods have little ability to determine source depths. Models that assign geochemical signatures to specific layers in the mantle, including the transition zone, the lower mantle, and the core-mantle boundary, are based on speculative models that cannot be verified and for which viable, less-astonishing alternatives are available. Our knowledge is poor of the size, distribution and location of protoliths, and of metasomatism of magma sources, the nature of the partial-melting and melt-extraction process, the mixing of disparate melts, and the re-assimilation of crust and mantle lithosphere by rising melt. Interpretations of seismic tomography, petrologic and geochemical observations, and all three together, are ambiguous, and this needs to be emphasized more in presenting interpretations so that the viability of the models can be assessed more reliably.

Geological and geochemical controls on subsurface microbial life in the Samail Ophiolite, Oman

DOE PAGES

Rempfert, Kaitlin R.; Miller, Hannah M.; Bompard, Nicolas; ...

2017-02-07

Microbial abundance and diversity in deep subsurface environments is dependent upon the availability of energy and carbon. However, supplies of oxidants and reductants capable of sustaining life within mafic and ultramafic continental aquifers undergoing low-temperature water-rock reaction are relatively unknown. We conducted an extensive analysis of the geochemistry and microbial communities recovered from fluids sampled from boreholes hosted in peridotite and gabbro in the Tayin block of the Samail Ophiolite in the Sultanate of Oman. The geochemical compositions of subsurface fluids in the ophiolite are highly variable, reflecting differences in host rock composition and the extent of fluid-rock interaction. Principal component analysis of fluid geochemistry and geologic context indicate the presence of at least four fluid types in the Samail Ophiolite (“gabbro,” “alkaline peridotite,” “hyperalkaline peridotite,” and “gabbro/peridotite contact”) that vary strongly in pH and the concentrations of H 2, CH 4, Ca 2+, Mg 2+, NO 3 more » $-$, SO$$2-\\atop{4}$$, trace metals, and DIC. Geochemistry of fluids is strongly correlated with microbial community composition; similar microbial assemblages group according to fluid type. Hyperalkaline fluids exhibit low diversity and are dominated by taxa related to the Deinococcus-Thermus genus Meiothermus, candidate phyla OP1, and the family Thermodesulfovibrionaceae. Gabbro- and alkaline peridotite- aquifers harbor more diverse communities and contain abundant microbial taxa affiliated with Nitrospira, Nitrosospharaceae, OP3, Parvarcheota, and OP1 order Acetothermales. Wells that sit at the contact between gabbro and peridotite host microbial communities distinct from all other fluid types, with an enrichment in betaproteobacterial taxa. Together the taxonomic information and geochemical data suggest that several metabolisms may be operative in subsurface fluids, including methanogenesis, acetogenesis, and fermentation, as well as the oxidation of methane, hydrogen and small molecular weight organic acids utilizing nitrate and sulfate as electron acceptors. Dynamic nitrogen cycling may be especially prevalent in gabbro and alkaline peridotite fluids. As a result, these data suggest water-rock reaction, as controlled by lithology and hydrogeology, constrains the distribution of life in terrestrial ophiolites.« less

Mars

NASA Astrophysics Data System (ADS)

McSween, H. Y., Jr.

2003-12-01

More than any other planet, Mars has captured our attention and fueled our speculations. Much of this interest relates to the possibility of martian life, as championed by Percival Lowell in the last century and subsequently in scientific papers and science fiction. Lowell's argument for life on Mars was based partly on geochemistry, in that his assessmentof the planet's hospitable climate was dependent on the identification of H2O ice rather than frozen CO2 in the polar caps. Although this reasoning was refuted by Alfred Wallace in 1907, widespread belief in extant martian life persisted within the scientific community until the mid-twentieth century (Zahnle, 2001). In 1965 the Mariner 4 spacecraft flyby suddenly chilled this climate, by demonstrating that the martian atmosphere was thin and the surface was a cratered moonscape devoid of canals. This view of Mars was overturned again in 1971, when the Mariner 9 spacecraft discovered towering volcanoes and dry riverbeds, implying a complex geologic history. The first geochemical measurements on Mars, made by two Viking landers in 1976, revealed soils enriched in salts suggesting exposure to water, but lacking organic compounds which virtually ended discussion of martian life.The suggestion that a small group of achondritic meteorites were martian samples (McSween and Stolper, 1979; Walker et al., 1979; Wasson and Wetherill, 1979) found widespread acceptance when trapped gases in them were demonstrated to be compositionally similar to the Mars atmosphere ( Bogard and Johnson, 1983; Becker and Pepin, 1984). The ability to perform laboratory measurements of elements and isotopes present in trace quantities in meteorites has invigorated the subject of martian geochemistry. Indeed, because of these samples, we now know more about the geochemistry of Mars than of any other planet beyond the Earth-Moon system. Some studies of martian meteorites have prompted a renewed search for extraterrestrial life using chemical biomarkers.Recent Mars spacecraft, including the Mars Pathfinder lander/rover in 1997 and Mars Global Surveyor and Mars Odyssey now orbiting the planet, have provided significant new geochemical findings. These missions have also generated geophysical data with which to constrain geochemical models of the martian interior.

Linking the climatic and geochemical controls on global soil carbon cycling

NASA Astrophysics Data System (ADS)

Doetterl, Sebastian; Stevens, Antoine; Six, Johan; Merckx, Roel; Van Oost, Kristof; Casanova Pinto, Manuel; Casanova-Katny, Angélica; Muñoz, Cristina; Boudin, Mathieu; Zagal Venegas, Erick; Boeckx, Pascal

2015-04-01

Climatic and geochemical parameters are regarded as the primary controls for soil organic carbon (SOC) storage and turnover. However, due to the difference in scale between climate and geochemical-related soil research, the interaction of these key factors for SOC dynamics have rarely been assessed. Across a large geochemical and climatic transect in similar biomes in Chile and the Antarctic Peninsula we show how abiotic geochemical soil features describing soil mineralogy and weathering pose a direct control on SOC stocks, concentration and turnover and are central to explaining soil C dynamics at larger scales. Precipitation and temperature had an only indirect control by regulating geochemistry. Soils with high SOC content have low specific potential CO2 respiration rates, but a large fraction of SOC that is stabilized via organo-mineral interactions. The opposite was observed for soils with low SOC content. The observed differences for topsoil SOC stocks along this transect of similar biomes but differing geo-climatic site conditions are of the same magnitude as differences observed for topsoil SOC stocks across all major global biomes. Using precipitation and a set of abiotic geochemical parameters describing soil mineralogy and weathering status led to predictions of high accuracy (R2 0.53-0.94) for different C response variables. Partial correlation analyses revealed that the strength of the correlation between climatic predictors and SOC response variables decreased by 51 - 83% when controlling for geochemical predictors. In contrast, controlling for climatic variables did not result in a strong decrease in the strength of the correlations of between most geochemical variables and SOC response variables. In summary, geochemical parameters describing soil mineralogy and weathering were found to be essential for accurate predictions of SOC stocks and potential CO2 respiration, while climatic factors were of minor importance as a direct control, but are important through governing soil weathering and geochemistry. In conclusion, we pledge for a stronger implementation of geochemical soil properties to predict SOC stocks on a global scale. Understanding the effects of climate (temperature and precipitation) change on SOC dynamics also requires good understanding of the relationship between climate and soil geochemistry.

"Normal" to adakite-like arc magmatism associated with the El Abra porphyry copper deposit, Central Andes, Northern Chile

NASA Astrophysics Data System (ADS)

Rabbia, Osvaldo M.; Correa, Karen J.; Hernández, Laura B.; Ulrich, Thomas

2017-03-01

The El Abra porphyry copper deposit belongs to the Late Eocene—Early Oligocene metallogenic belt of northern Chile, which host several world-class porphyry copper deposits. Our previous geochronological work done on this deposit provides the temporal framework for petrological data interpretation. The magmatic history of the El Abra deposit lasts for 8.6 Ma and can be divided into two stages. An early period, from about 45 to 38.7 Ma, dominated by diorites and quartz monzodiorites with "normal" (non-adakite) arc geochemistry and a late period, with rocks younger than 38.7 Ma that developed adakite-like geochemistry, where equigranular granodiorites are the volumetrically dominant rock type (e.g., Clara granodiorite 38 Ma). These granodiorites are then intruded by leucocratic porphyry dikes and aplites. Most copper mineralization is associated with multiple intrusions of these younger porphyritic rocks, described as the El Abra porphyry unit, and emplaced over a 1.4 Ma period, from 37.5 to 36.1 Ma. The adakite-like geochemistry of the younger rock units (<38.7 Ma) is attested by a significant depletion in REE contents, particularly MREE and HREE (concave MREE distribution patterns), high La/Yb and Sr/Y ratios, and Na2O and Al2O3 contents, along with the absence of the Eu anomaly in normalized REE distribution patterns. The evolution of this large, long-lived magmatic system from "normal" to adakite-like arc magmatism is discussed in a tectonic context of crust overthickening due to a major orogenic episode (Incaic compressive phase). This tectonic setting may have promoted higher pressure conditions at the lower crust "hot zone" and increased the crustal residence time of derivative melts favoring extensive differentiation leading to water-rich (and oxidized?) felsic melts, where amphibole fractionation played an important role. Strontium, Nd, and Pb isotope data suggest a common mantle source for both the non-adakite and adakite-like rocks. This implies that these two groups of rocks from the El Abra porphyry copper deposit may have largely resulted from the different crustal conditions under which they have evolved.

SPATIAL Short Courses Build Expertise and Community in Isotope Geochemistry

NASA Astrophysics Data System (ADS)

Riggs, E. M.; Bowen, G. J.

2015-12-01

The SPATIAL short course at the University of Utah is designed for graduate students and professionals in the earth and environmental sciences from around the globe. An integral part of the broader, NSF-funded Inter-university Training for Continental-scale Ecology (ITCE) project, the course is an intensive two-week field, classroom and laboratory experience with internationally-known researchers as instructors. The course focuses on stable isotope geochemistry coupled with spatial analysis techniques. Participants do not typically know each other or this research community well upon entering. One of the stated goals of the overall project is to build a community of practice around these techniques. This design is common in many professional fields, but is not often applied at the graduate level nor formally assessed in the earth sciences. Paired pre- and post-tests were administered before the start and after the close of the short courses over 3 years. The survey is a set of instruments adapted from social-cognitive psychology measuring changes in identity and community with other items to measure content knowledge outcomes. We see a subtle, consistent convergence of identities between large-scale isotope geochemistry and participants' research areas. Results also show that the course generates an increase in understanding about stable isotopes' use and application. The data show the SPATIAL course is very effective at bringing students together socially with each other and with faculty to create an environment that fosters community and scientific cooperation. Semi-structured pre-and post- interviews were conducted to understand the program elements that generated gains in learning and community. Participants were selected based on initial responses on the pre-survey to capture the range of initial conditions for the group. Qualitative analysis shows that the major factors for participants were 1) ready access to researchers in an informal setting during the course with many substantial opportunities to discuss research, 2) scaffolded, guided-inquiry group research designed to build group cohesion and skills, 3) just-in-time teaching at key junctures during lab and field exercises, and 4) access to curated sets of research literature from disparate fields relevant to SPATIAL content.

Baseline Geochemical Data for Medical Researchers in Kentucky

NASA Astrophysics Data System (ADS)

Anderson, W.

2017-12-01

According to the Centers for Disease Control, Kentucky has the highest cancer incidence and death rates in the country. New efforts by geochemists and medical researchers are examining ways to diagnose the origin and sources of carcinogenesis. In an effort to determine if naturally occurring geochemical or mineral elements contributes to the cancer causation, the Kentucky Geological Survey has established a Minerals and Geochemical Database that is available to medical researchers for examination of baseline geochemistry and determine if naturally occurring mineral or chemical elements contribute to the high rate of cancers in the state. Cancer causation is complex, so if natural sources can be accounted for, then researchers can focus on the true causation. Naturally occurring minerals, metals and elements occur in many parts of the state, and their presence is valuable for evaluating causation. For example, some data in the database contain maps showing (a) statewide elemental geochemistry, (b) areas of black shale oxidation occurrence, which releases metals in soil and surface waters, (c) some clay deposits in the state that can contain high content of rare earth elements, and (d) site-specific uranium occurrences. Knowing the locations of major ore deposits in the state can also provide information related to mineral and chemical anomalies, such as for base metals and mercury. Radionuclide data in soil and water analyses are limited, so future research may involve obtaining more analyses to determine radon potential. This database also contains information on faulting and geology in the state. Although the metals content of trees may not seem relevant, the ash and humus content of degraded trees affects soil, stream sediment and water geochemistry. Many rural homes heat with wood, releasing metals into the surrounding biosphere. Stressed vegetation techniques can be used to explore for ore deposits and look for high metal contents in soils and rocks. These naturally occurring elements could be used for baseline information related to new collaborative research that integrates medicine, geology, forestry, and botany to predict metal contents of stream sediments, soil residuum, trees, plants, and forest cover and determine their relation to carcinogenesis.

Obtaining higher-accuracy estimates of water-rich rocks and water-poor sand dunes on Mars in active neutron experiments

NASA Astrophysics Data System (ADS)

Gabriel, T. S. J.; Hardgrove, C.; Litvak, M. L.; Nowicki, S.; Mitrofanov, I. G.; Boynton, W. V.; Fedosov, F.; Golovin, D.; Jun, I.; Mischna, M.; Tate, C. G.; Moersch, J.; Harshman, K.; Kozyrev, A.; Malakhov, A. V.; Mokrousov, M.; Nikiforov, S.; Sanin, A. B.; Vostrukhin, A.; Thompson, L. M.

2017-12-01

The Dynamic Albedo of Neutrons (DAN) experiment on the Mars Science Laboratory Curiosity Rover delivers high-energy (14.1 MeV) pulses of neutrons into the surface when operating in "active" mode. Neutrons are moderated in the subsurface and return to two detectors to provide a time-of-flight profile in 64 time-bins in epithermal and thermal energy ranges. Results are compared to simulations of the experiment in the Monte Carlo N-Particle Transport Code where several aspects are modeled including the DAN detectors, neutron source, rover components, and underlying rock. Models can be improved by increasing the fidelity of the rock geochemistry as informed by instruments including the Alpha Particle X-Ray Spectrometer (APXS). Furthermore, increasing the fidelity of the rock morphology in models is enabled by the suite of imaging instruments on the rover.To rapidly interpret DAN data a set of pre-simulated generic rock density and bulk geochemistry models are compared to several DAN active observations. While, to first order, this methodology provides an indication of significant geochemical changes in the subsurface, higher-fidelity models should be used to provide accurate constraints on water content, depth of geologic layers, or abundance of neutron absorbers. For example, in high-silicon, low-iron rocks observed along the rover's traverse, generic models can differ by several wt%H2O from models that use APXS measurements of nearby drill samples. Accurate measurements of high-silicon targets are necessary in outlining the extent of aqueous alteration and hydrothermal activity in Gale Crater. Additionally, we find that for DAN active experiments over sand dunes best-fit models can differ by greater than 0.5 wt%HO when the upper layer density is reduced by 0.6 g/cm3 to account for the low-bulk density of sand. In areas where the rock geochemistry differs little from generic models the difference in results is expectedly less disparate. We report refined wt%HO values for high-silicon, aqueously-altered rock and comparatively dry sand dunes along the rover traverse. We also outline the methodology for providing accurate geochemical and morphological constraints using DAN active measurements.

Sulfur and carbon geochemistry of the Santa Elena peridotites: Comparing oceanic and continental processes during peridotite alteration

NASA Astrophysics Data System (ADS)

Schwarzenbach, Esther M.; Gill, Benjamin C.; Gazel, Esteban; Madrigal, Pilar

2016-05-01

Ultramafic rocks exposed on the continent serve as a window into oceanic and continental processes of water-peridotite interaction, so called serpentinization. In both environments there are active carbon and sulfur cycles that contain abiogenic and biogenic processes, which are eventually imprinted in the geochemical signatures of the basement rocks and the calcite and magnesite deposits associated with fluids that issue from these systems. Here, we present the carbon and sulfur geochemistry of ultramafic rocks and carbonate deposits from the Santa Elena ophiolite in Costa Rica. The aim of this study is to leverage the geochemistry of the ultramafic sequence and associated deposits to distinguish between processes that were dominant during ocean floor alteration and those dominant during low-temperature, continental water-peridotite interaction. The peridotites are variably serpentinized with total sulfur concentrations up to 877 ppm that is typically dominated by sulfide over sulfate. With the exception of one sample the ultramafic rocks are characterized by positive δ34Ssulfide (up to + 23.1‰) and δ34Ssulfate values (up to + 35.0‰). Carbon contents in the peridotites are low and are isotopically distinct from typical oceanic serpentinites. In particular, δ13C of the inorganic carbon suggests that the carbon is not derived from seawater, but rather the product of the interaction of meteoric water with the ultramafic rocks. In contrast, the sulfur isotope data from sulfide minerals in the peridotites preserve evidence for interaction with a hydrothermal fluid. Specifically, they indicate closed system abiogenic sulfate reduction suggesting that oceanic serpentinization occurred with limited input of seawater. Overall, the geochemical signatures preserve evidence for both oceanic and continental water-rock interaction with the majority of carbon (and possibly sulfate) being incorporated during continental water-rock interaction. Furthermore, there is evidence for microbial activity that was possibly stimulated by carbon sourced from water-rock interaction with adjacent sediments or fluid inclusions. This study provides detailed insight into the complex hydrothermal history of continental serpentinization systems and adds to our understanding of the carbon and sulfur cycling within peridotite-hosted hydrothermal systems.

Applied Geochemistry Special Issue on Environmental geochemistry of modern mining

USGS Publications Warehouse

Seal, Robert R.; Nordstrom, D. Kirk

2015-01-01

Environmental geochemistry is an integral part of the mine-life cycle, particularly for modern mining. The critical importance of environmental geochemistry begins with pre-mining baseline characterization and the assessment of environmental risks related to mining, continues through active mining especially in water and waste management practices, and culminates in mine closure. The enhanced significance of environmental geochemistry to modern mining has arisen from an increased knowledge of the impacts that historical and active mining can have on the environment, and from new regulations meant to guard against these impacts. New regulations are commonly motivated by advances in the scientific understanding of the environmental impacts of past mining. The impacts can be physical, chemical, and biological in nature. The physical challenges typically fall within the purview of engineers, whereas the chemical and biological challenges typically require a multidisciplinary array of expertise including geologists, geochemists, hydrologists, microbiologists, and biologists. The modern mine-permitting process throughout most of the world now requires that potential risks be assessed prior to the start of mining. The strategies for this risk assessment include a thorough characterization of pre-mining baseline conditions and the identification of risks specifically related to the manner in which the ore will be mined and processed, how water and waste products will be managed, and what the final configuration of the post-mining landscape will be.In the Fall 2010, the Society of Economic Geologists held a short course in conjunction with the annual meeting of the Geological Society of America in Denver, Colorado (USA) to examine the environmental geochemistry of modern mining. The intent was to focus on issues that are pertinent to current and future mines, as opposed to abandoned mines, which have been the focus of numerous previous short courses. The geochemical challenges of current and future mines share similarities with abandoned mines, but differences also exist. Mining and ore processing techniques have changed; the environmental footprint of waste materials has changed; environmental protection has become a more integral part of the mine planning process; and most historical mining was done with limited regard for the environment. The 17 papers in this special issue evolved from the Society of Economic Geologists’ short course.The relevant geochemical processes encompass the source, transport, and fate of contaminants related to the life cycle of a mine. Contaminants include metals and other inorganic species derived from geologic sources such as ore and solid mine waste, and substances brought to the site for ore processing, such as cyanide to leach gold. Factors, such as mine-waste mineralogy, hydrologic setting, mine-drainage chemistry, and microbial activity, that affect the hydrochemical risks from mining are reviewed by Nordstrom et al. In another paper, Nordstrom discusses baseline characterization at mine sites in a regulatory framework, and emphasizes the influence of mineral deposits in producing naturally elevated concentrations of many trace elements in surface water and groundwater. Surface water quality in mineralized watersheds is influenced by a number of processes that act on daily (diel) cycles and can produce dramatic variations in trace element concentrations as described by Gammons et al. Pre-mining baseline characterization studies should strive to capture the magnitude of these diel variations. Desbarats et al., using a case study of mine drainage from a gold mine, illustrate how elements that commonly occur as negatively charged species (anions) in solution, such as arsenic as arsenate, behave in an opposite fashion than most metals, which occur as positively charged species (cations). Significant improvement in the understanding of factors that influence the toxicity of metals to aquatic organisms in surface water has highlighted the importance of aqueous chemistry, particularly dissolved organic carbon, as described by Smith et al. Stream sediment contamination is another important pathway for affecting aquatic organisms, as reviewed by Besser et al. Understanding and predicting environmental consequences from mining begins with knowing the mineralogy and mineral reactivity of the ore, the wastes, and of secondary minerals formed later. Jamieson et al. review the importance of mineralogical studies in mine planning and remediation. A number of types of site-specific studies are needed to identify environmental risks related to individual mines. Lapakko reviews the general framework of mine waste characterization studies that are integral to the mine planning process. Hageman et al. present a comparative study of several static tests commonly used to characterize mine waste.The mining and ore processing practices employed at a specific mine site will vary on the basis of the commodities being targeted, the geology of the deposit, the geometry of the deposit, and the mining and ore processing methods used. Thus, these factors, in addition to the waste management practices used, can result in a variety of end-member mine waste features, each of which has its own set of challenges. Open pit mines and underground mines require waste rock to be removed to access ore. Waste rock presents unique problems because the rock is commonly mineralized at sub-economic grades and has not been processed to remove potentially problematic minerals, such as pyrite. Amos et al. examine the salient aspects of the geochemistry of waste rock. Mill tailings – the waste material after ore minerals have been removed – are a volumetrically important solid waste at many mine sites. Their fine grain size and the options for their management make their behavior in the environment distinct from that of waste rock. Lindsay et al. describe some of these differences through three case-study examples. Subaqueous disposal of tailings is another option described by Moncur et al. Cyanide leaching for gold extraction is a common method throughout the world. Johnson describes environmental aspects of cyanidation. Uranium mining presents unique environmental challenges, particularly since in-situ recovery has seen widespread use. Campbell et al. review the environmental geochemistry of uranium mining and current research on bioremediation. Ore concentrates from many types of metal mining undergo a pyrometallurgical technique known as smelting to extract the metal. Slag is the result of smelting, and it may be an environmental liability or a valuable byproduct, as described by Piatak et al. Finally, the open pits that result from surface mining commonly reach below the water table. At the end of mining, these pits may fill to form lakes that become part of the legacy of the mine. Castendyk et al., in two papers, review theoretical aspects of the environmental limnology of pit lakes. They also describe approaches that have been used to model pit lake water balance, wall-rock contributions to pit lake chemistry, pit lake water quality, and limnological processes, such as vertical mixing, through the use of three case studies.

Miscellaneous geochemical data from waters in the Upper Animas River Watershed, Colorado

USGS Publications Warehouse

Johnson, Raymond H.; Yager, Douglas B.

2013-01-01

This report releases geochemistry data in waters from the upper Animas River watershed that have been analyzed by inductively coupled plasma–mass spectrometry. These samples were collected at various sites and at various dates (41 sites and 86 samples from 2008 to 2010). A main data table is provided and the text discusses the sampling methods and locations in relation to other published reports.

Twenty-Fourth Lunar and Planetary Science Conference. Part 2: G-M

NASA Technical Reports Server (NTRS)

1993-01-01

The topics covered include the following: meteorites, meteoritic composition, geochemistry, planetary geology, planetary composition, planetary craters, the Moon, Mars, Venus, asteroids, planetary atmospheres, meteorite craters, space exploration, lunar geology, planetary surfaces, lunar surface, lunar rocks, lunar soil, planetary atmospheres, lunar atmosphere, lunar exploration, space missions, geomorphology, lithology, petrology, petrography, planetary evolution, Earth surface, planetary surfaces, volcanology, volcanos, lava, magma, mineralogy, minerals, ejecta, impact damage, meteoritic damage, tectonics, etc.

Latest Proterozoic stratigraphy and earth history

NASA Technical Reports Server (NTRS)

Knoll, Andrew H.; Walter, Malcolm R.

1992-01-01

Novel biostratigraphic and chemostratigraphic data furnish an improved framework for stratigraphic correlation of the Proterozoic Eon as well as tools for a chronostratigraphic division of the late Proterozoic. It is argued that, in conjunction with geochronometric data, protistan microfossils and isotope geochemistry can furnish a means for an eventual integration of the latest Proterozoic Eon. Attention is given to the emerging methodologies of fossil protists and prokaryotes and of isotopic chemostratigraphy.

Astrobiology, Sustainability and Ethical Perspectives

NASA Astrophysics Data System (ADS)

Arnould, Jacques

2009-12-01

Astrobiology, a new field of research associating the prospects and constraints of prebiotic chemistry, mineralogy, geochemistry, astrophysics, theoretical physics, microbial ecology, etc., is assessed in terms of sustainability through the scientific and social functions it fulfils, and the limits it encounters or strives to overcome. In the same way as sustainable development, astrobiology must also take into account the temporal dimension specific to its field of investigation and examine its underlying conception of Nature.

River history.

PubMed

Vita-Finzi, Claudio

2012-05-13

During the last half century, advances in geomorphology-abetted by conceptual and technical developments in geophysics, geochemistry, remote sensing, geodesy, computing and ecology-have enhanced the potential value of fluvial history for reconstructing erosional and depositional sequences on the Earth and on Mars and for evaluating climatic and tectonic changes, the impact of fluvial processes on human settlement and health, and the problems faced in managing unstable fluvial systems. This journal is © 2012 The Royal Society

Geochemistry and Ar-Ar muscovite ages of the Daraban Leucogranite, Mawat Ophiolite, northeastern Iraq: Implications for Arabia-Eurasia continental collision

NASA Astrophysics Data System (ADS)

Mohammad, Yousif O.; Cornell, David H.; Qaradaghi, Jabbar H.; Mohammad, Fahmy O.

2014-06-01

Daraban Leucogranite dykes intruded discordantly into the basal serpentinized harzburgite of the Mawat Ophiolite, Kurdistan region, NE Iraq. These coarse grained muscovite-tourmaline leucogranites are the first leucogranite dykes identified within the Mawat Ophiolite. They are mainly composed of quartz, K-feldspar, plagioclase, tourmaline, muscovite, and secondary phologopite, while zircon, xenotime, corundum, mangano-ilemnite and cassiterite occur as accessories.

Effects of Near-Term Sea-Level Rise on Coastal Infrastructure

DTIC Science & Technology

2013-03-01

methodology is more objective, and more robust, than the standard methods of counting overwash sand layers or identifying marine microfossils in the...duration thresholds on Atlantic tropical cyclone counts , J. Climate, 23, 2508-2519, doi:10.1175/2009JCLI3034.1. Lane, P., Donnelly, J.P., Woodruff...Holocene Climate in the Northern Great Plains Inferred from Sediment Stratigraphy, Stable Isotopes, Carbonate Geochemistry, Diatoms, and Pollen at Moon

New Bedford, Marine And Estuarine Geochemistry - Chapter 7: Partitioning Of Polychlorinated Biphenyls (PCBs) In Marine Sediments, 01-01-1985, SDMS no. 51931

EPA Pesticide Factsheets

2012-04-15

... 1: i:ii:ii'iii!'ini|ii;:i:a|:ih:h: I n, ;, I. 1 l.ul.'Uin cli'j llolii!, Misiiiisini: him in? I: it n II I \\\\A\\\\ Ji'o.ll yi: li:h:u: l.mi!iiil:i!"il hi phnriiy I n '!:'' i'.n ! rani? mini! I'nII. modi! ...

Semi-quantitative spectrographic analysis and rank correlation in geochemistry

USGS Publications Warehouse

Flanagan, F.J.

1957-01-01

The rank correlation coefficient, rs, which involves less computation than the product-moment correlation coefficient, r, can be used to indicate the degree of relationship between two elements. The method is applicable in situations where the assumptions underlying normal distribution correlation theory may not be satisfied. Semi-quantitative spectrographic analyses which are reported as grouped or partly ranked data can be used to calculate rank correlations between elements. ?? 1957.

Abstracts of Manuscripts Submitted in 1991 for Publication

DTIC Science & Technology

1992-05-01

and Peter M. Williams ........ ............................... C-4 Sedimentary and Geochemical Expressions of Oxic and Anoxic Conditions on the Peru ...Organic Geochemistry as a Too] to Study Upwelling Systems: Recent Results from the Peru and Namibian Shelves Daniel J. Repeta, Mark A. McCaffrey, and...intensity must also lie within a certain THE AMAZON OUTFLOW narrow range. With these limitations we couple the W. Rockwell Geyer, Robert C. Beardsley, air

Proceedings of GeoTech 85: Personal computers in geology conference

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-01-01

This book presents the papers given at a conference which considered the use of microprocessors in the exploration of petroleum and natural gas deposits. Topics covered at the conference included seismic surveys, geochemistry, expert systems, artificial intelligence, data base management systems, a portable exploration work station, open pit planning on a microcomputer, well logging, fracture analysis, production scheduling of open pit mines, resistivity logging, and coal washability.

Cometary Dust: The Diversity of Primitive Matter

NASA Technical Reports Server (NTRS)

Wooden, D. H.; Ishiiii, H. A.; Zolensky, M. E.

2017-01-01

The connections between comet dust and primitive chondrites from asteroids has strengthened considerably over the past decade. Understanding the importance of the connections between Stardust samples and chondrites requires geochemistry lingo as well as a perspective of other cometary dust samples besides Stardust. We present the principal findings of an extensive review prepared for by us for the June 2016 "Cometary Science After Rosetta" meeting at The Royal Society, London.

Methods of Determining Playa Surface Conditions Using Remote Sensing

DTIC Science & Technology

1987-10-08

NO. 11. TITLE (include Security Classification) METHODS OF DETERMINING PLAYA SURFACE CONDITIONS USING REMOTE SENSING 12. PERSONAL AUTHOR(S) J. PONDER...PLAYA SURFACE CONDITIONS USING REMOTE SENSING J. Ponder Henley U. S. Army Engineer Topographic Laboratories Fort Belvoir, Virginia 22060-5546 "ABSTRACT...geochemistry, hydrology and remote sensing but all of these are important to the understanding of these unique geomorphic features. There is a large body

Geochemistry of granitoid rocks from the western Superior Province: Evidence for 2- and 3-stage crustal evolution models

NASA Technical Reports Server (NTRS)

Beakhouse, G. P.; errane) are discussed.

1986-01-01

The Superior Province is divisible into subprovinces that can be classified as greenstone-tonalite, paragneiss, or batholitic terranes and are distinguished by differences in lithologic proportions, metamorphic grade, and structural style. The origin and significance of contrasting geochemical characteristics of plutonic rocks from the Winnipeg River subprovince (a batholithic terrane) and the Wabigoon subprovince (a greenstone-tonalite terrane) are discussed.

Aqueous organic geochemistry at high temperature/high pressure

NASA Technical Reports Server (NTRS)

Simoneit, Bernd R. T.

1992-01-01

A description of the fate and chemical alterations of organic matter under hydrothermal conditions is given, with a brief overview of the geographic localities where these processes have been investigated to date. Two major aspects are examined: (1) alteration and degradation processes and reactions, both reductive and oxidative; and (2) synthesis processes and reactions which are primarily reductive. Examples of industrial applications of the related supercritical fluid technology are discussed.

Chemical environments of submarine hydrothermal systems. [supporting abiogenetic theory

NASA Technical Reports Server (NTRS)

Shock, Everett L.

1992-01-01

The paper synthesizes diverse information about the inorganic geochemistry of submarine hydrothermal systems, provides a description of the fundamental physical and chemical properties of these systems, and examines the implications of high-temperature, fluid-driven processes for organic synthesis. Emphasis is on a few general features, i.e., pressure, temperature, oxidation states, fluid composition, and mineral alteration, because these features will control whether organic synthesis can occur in hydrothermal systems.

Modeling and Decision Support Tools Based on the Effects to Sediment Geochemistry and Microbial Populations on Contaminant Reactions in Sediments

DTIC Science & Technology

2011-09-01

Deltaproteobacteria(4) Others(5) Unclassified bacteria(7) Nitrospira(2) Actinobacteria (2) Betaproteobacteria(17) Re su lts  a nd  D is cu...3/7.18E-1) » » » phylum Actinobacteria (2/0/2.38E-1) » » » » class Actinobacteria (2/0/2.38E-1) » » » » » subclass Coriobacteridae

Catalog of Canadian Industrial Capabilities.

DTIC Science & Technology

1981-09-01

corporation. Capability: Barringer has undertaken research projects primarily in the earth sciences in the disciplines of geology, geochemistry, electro...GASPEC concept is also to be used in the ERBS ( Earth Radiation Budget Satellite) wherein it will detect HF, HCI, CH4 and NO by looking at the rising...anechoic shielded enclosure. Experience: BNR carries out some R&D for groups other than their owners. They estimate their business with the US Military

The nature and location of the suture zone in the Rokelide orogen, Sierra Leone: Geochemical evidence

NASA Astrophysics Data System (ADS)

Lytwyn, Jennifer; Burke, Kevin; Culver, Stephen

2006-12-01

The boundaries of the West African Craton mark the location of a continuous suture zone that records Neoproterozoic to Early Cambrian oceanic closure. The western part of the circum-West African suture zone extends through the line of outcrop of the Mauritanide, Bassaride and Rokelide mountain belts. Our geochemical analyses are consistent with the idea that igneous and metamorphic rocks of the Rokelide and Southern Mauritanide mountain belts of West Africa occupy a suture zone that records the closing of a Neoproterozoic to Early Cambrian ocean basin during the Pan-African orogeny and final assembly of Gondwana. The closing of that basin was marked by the collision between Archean rocks of the Leo massif of the West African Craton and reactivated Archean and Paleoproterozoic rocks that now outcrop nearer to the coast of Africa in Sierra Leone and Liberia. Within the Rokelides, the geochemistry of the Kasewe Hills volcanic rocks and Marampa amphibolite indicate that remnants of an arc system are caught up in the suture zone. The geochemistry of Guingan schists that outcrop along strike of the Rokelides is compatible with the idea that the metamorphosed equivalents of the Marampa and Kasewe Hills arc volcanic rocks extend through the Bassarides and into the Southern Mauritanides.

Large-scale subduction of continental crust implied by India-Asia mass-balance calculation

NASA Astrophysics Data System (ADS)

Ingalls, Miquela; Rowley, David B.; Currie, Brian; Colman, Albert S.

2016-11-01

Continental crust is buoyant compared with its oceanic counterpart and resists subduction into the mantle. When two continents collide, the mass balance for the continental crust is therefore assumed to be maintained. Here we use estimates of pre-collisional crustal thickness and convergence history derived from plate kinematic models to calculate the crustal mass balance in the India-Asia collisional system. Using the current best estimates for the timing of the diachronous onset of collision between India and Eurasia, we find that about 50% of the pre-collisional continental crustal mass cannot be accounted for in the crustal reservoir preserved at Earth's surface today--represented by the mass preserved in the thickened crust that makes up the Himalaya, Tibet and much of adjacent Asia, as well as southeast Asian tectonic escape and exported eroded sediments. This implies large-scale subduction of continental crust during the collision, with a mass equivalent to about 15% of the total oceanic crustal subduction flux since 56 million years ago. We suggest that similar contamination of the mantle by direct input of radiogenic continental crustal materials during past continent-continent collisions is reflected in some ocean crust and ocean island basalt geochemistry. The subduction of continental crust may therefore contribute significantly to the evolution of mantle geochemistry.

Zircon evidence for incorporation of terrigenous sediments into the magma source of continental basalts.

PubMed

Xu, Zheng; Zheng, Yong-Fei; Zhao, Zi-Fu

2018-01-09

Crustal components may be incorporated into continental basalts by either shallow contamination or deep mixing. While the former proceeds at crustal depths with common preservation of refractory minerals, the latter occurs at mantle depths with rare survival of relict minerals. Discrimination between the two mechanisms has great bearing to subcontinental mantle geochemistry. Here we report the occurrence of relict zircons in Cenozoic continental basalts from eastern China. A combined study of zircon U-Pb ages and geochemistry indicates that detrital zircons were carried by terrigenous sediments into a subcontinental subduction zone, where the zircon were transferred by fluids into the magma sources of continental basalts. The basalts were sampled from three petrotectonic units with distinct differences in their magmatic and metamorphic ages, making the crustal contamination discernible. The terrigenous sediments were carried by the subducting oceanic crust into the asthenospheric mantle, producing both soluble and insoluble materials at the slab-mantle interface. These materials were served as metasomatic agents to react with the overlying mantle wedge peridotite, generating a kind of ultramafic metasomatites that contain the relict zircons. Therefore, the occurrence of relict zircons in continental basalts indicates that this refractory mineral can survive extreme temperature-pressure conditions in the asthenospheric mantle.

Integration of 3 Consecutive Years of Aqueous Geochemistry Monitoring Serpentinization at the Coast Range Ophiolite Microbial Observatory (CROMO), Northern California, USA

NASA Astrophysics Data System (ADS)

Cardace, D.; Hoehler, T. M.; McCollom, T. M.; Schrenk, M. O.; Kubo, M. D.

2014-12-01

In August 2011, a set of 8 groundwater monitoring wells were established in actively serpentinizing ultramafic rocks of the Coast Range Ophiolite near Lower Lake, CA, as a NASA Astrobiology Institute project (Cardace et al., 2013). These wells have enabled repeated sampling and analysis of aqueous geochemistry, which we now present in an integrated model of the progress of serpentinization at this locality. The Coast Range Ophiolite Microbial Observatory (CROMO) plumbs groundwaters percolating through a tectonic mélange of Jurassic-aged oceanic crust, with blocks of metabasalt and metagabbro, variably serpentinized ultramafics, Great Valley Sequence sedimentary rocks including the Jurassic Knoxville formation and the Cretaceous Crack Canyon formation, as well as rocks resulting from silica-carbonate alteration of serpentinites (marginal listvenites). All of these rock units are accessible in the McLaughlin Natural Reserve (administered by the University of California-Davis). In this work, we report on persistent geochemical trends in CROMO waters, which are gas-rich, high pH (11+), Ca2+-OH- type waters, contrast their characteristics with other continental sites of serpentinization and deep sea serpentinizing vent systems, and place the evolution of these waters in a water-rock reaction context based on geochemical modeling.

Soil geochemistry and digestive solubilization control mercury bioaccumulation in the earthworm Pheretima guillemi.

PubMed

Dang, Fei; Zhao, Jie; Greenfield, Ben K; Zhong, Huan; Wang, Yujun; Yang, Zhousheng; Zhou, Dongmei

2015-07-15

Mercury presents a potential risk to soil organisms, yet our understanding of mercury bioaccumulation in soil dwelling organisms is limited. The influence of soil geochemistry and digestive processes on both methylmercury (MeHg) and total mercury (THg) bioavailability to earthworms (Pheretima guillemi) was evaluated in this study. Earthworms were exposed to six mercury-contaminated soils with geochemically contrasting properties for 36 days, and digestive fluid was concurrently collected to solubilize soil-associated mercury. Bioaccumulation factors were 7.5-31.0 and 0.2-0.6 for MeHg and THg, respectively, and MeHg accounted for 17-58% of THg in earthworm. THg and MeHg measured in soils and earthworms were negatively associated with soil total organic carbon (TOC). Earthworm THg and MeHg also increased with increasing soil pH. The proportion of MeHg and THg released into the digestive fluid (digestive solubilizable mercury, DSM) was 8.3-18.1% and 0.4-1.3%, respectively. The greater solubilization of MeHg by digestive fluid than CaCl2, together with a biokinetic model-based estimate of dietary MeHg uptake, indicated the importance of soil ingestion for MeHg bioaccumulation in earthworms. Copyright © 2015 Elsevier B.V. All rights reserved.

Eruption style at Kīlauea Volcano in Hawai‘i linked to primary melt composition

USGS Publications Warehouse

Sides. I.R.,; Edmonds, M.; Maclennan, J.; Swanson, Don; Houghton, Bruce F.

2014-01-01

Explosive eruptions at basaltic volcanoes have been linked to gas segregation from magmas at shallow depths in the crust. The composition of primary melts formed at greater depths was thought to have little influence on eruptive style. Ocean island basaltic volcanoes are the product of melting of a geochemically heterogeneous mantle plume and are expected to give rise to heterogeneous primary melts. This range in primary melt composition, particularly with respect to the volatile components, will profoundly influence magma buoyancy, storage and eruption style. Here we analyse the geochemistry of a suite of melt inclusions from 25 historical eruptions at the ocean island volcano of Kīlauea, Hawai‘i, over the past 600 years. We find that more explosive styles of eruption at Kīlauea Volcano are associated statistically with more geochemically enriched primary melts that have higher volatile concentrations. These enriched melts ascend faster and retain their primary nature, undergoing little interaction with the magma reservoir at the volcano’s summit. We conclude that the eruption style and magma-supply rate at Kīlauea are fundamentally linked to the geochemistry of the primary melts formed deep below the volcano. Magmas might therefore be predisposed towards explosivity right at the point of formation in their mantle source region.

Vanadium Geochemistry of Oil Sands Fluid Petroleum Coke.

PubMed

Nesbitt, Jake A; Lindsay, Matthew B J

2017-03-07

Vanadium has previously been linked to elevated toxicity of leachates derived from oil sands petroleum coke. However, geochemical controls on V mobility within coke deposits remain poorly constrained. Detailed examinations of porewater and solid-phase V geochemistry were therefore performed on oil sands fluid petroleum coke deposits in Alberta, Canada. Sample collection focused on both active and reclaimed deposits, which contained more than 3 × 10 7 m 3 of fluid petroleum coke. Dissolved V concentrations were highest (up to 3.0 mg L -1 ) immediately below the water table but decreased rapidly with increasing depth. This trend corresponded to a transition from mildly acidic (pH 6-7) and oxic conditions to mildly alkaline (pH 7-8.5) and anoxic conditions. Scanning electron microscopy (SEM), electron microprobe analysis (EMPA), and micro-X-ray fluorescence (μXRF) mapping revealed coke particles exhibited an internal structure characterized by successive concentric layers. The outer margins of these layers were characterized by elevated V, Fe, Si, and Al concentrations, indicating the presence of inorganic phases. Micro-X-ray absorption near-edge structure (μXANES) spectroscopy revealed that V speciation was dominated by V(IV) porphyrins except at outer margins of layers, where octahedrally coordinated V(III) was a major component. Minor to trace V(V) was also detected within fluid petroleum coke particles.

Combine the soil water assessment tool (SWAT) with sediment geochemistry to evaluate diffuse heavy metal loadings at watershed scale.

PubMed

Jiao, Wei; Ouyang, Wei; Hao, Fanghua; Huang, Haobo; Shan, Yushu; Geng, Xiaojun

2014-09-15

Assessing the diffuse pollutant loadings at watershed scale has become increasingly important when formulating effective watershed water management strategies, but the process was seldom achieved for heavy metals. In this study, the overall temporal-spatial variability of particulate Pb, Cu, Cr and Ni losses within an agricultural watershed was quantitatively evaluated by combining SWAT with sediment geochemistry. Results showed that the watershed particulate heavy metal loadings displayed strong variability in the simulation period 1981-2010, with an obvious increasing trend in recent years. The simulated annual average loadings were 20.21 g/ha, 21.75 g/ha, 47.35 g/ha and 21.27 g/ha for Pb, Cu, Cr and Ni, respectively. By comparison, these annual average values generally matched the estimated particulate heavy metal loadings at field scale. With spatial interpolation of field loadings, it was found that the diffuse heavy metal pollution mainly came from the sub-basins dominated with cultivated lands, accounting for over 70% of total watershed loadings. The watershed distribution of particulate heavy metal losses was very similar to that of soil loss but contrary to that of heavy metal concentrations in soil, highlighting the important role of sediment yield in controlling the diffuse heavy metal loadings. Copyright © 2014 Elsevier B.V. All rights reserved.

Earth Sciences Division

NASA Astrophysics Data System (ADS)

1991-06-01

This Annual Report presents summaries of selected representative research activities grouped according to the principal disciplines of the Earth Sciences Division: Reservoir Engineering and Hydrogeology, Geology and Geochemistry, and Geophysics and Geomechanics. Much of the Division's research deals with the physical and chemical properties and processes in the earth's crust, from the partially saturated, low-temperature near-surface environment to the high-temperature environments characteristic of regions where magmatic-hydrothermal processes are active. Strengths in laboratory and field instrumentation, numerical modeling, and in situ measurement allow study of the transport of mass and heat through geologic media -- studies that now include the appropriate chemical reactions and the hydraulic-mechanical complexities of fractured rock systems. Of particular note are three major Division efforts addressing problems in the discovery and recovery of petroleum, the application of isotope geochemistry to the study of geodynamic processes and earth history, and the development of borehole methods for high-resolution imaging of the subsurface using seismic and electromagnetic waves. In 1989, a major DOE-wide effort was launched in the areas of Environmental Restoration and Waste Management. Many of the methods previously developed for and applied to deeper regions of the earth will, in the coming years, be turned toward process definition and characterization of the very shallow subsurface, where man-induced contaminants now intrude and where remedial action is required.

Ca isotopic geochemistry of an Antarctic aquatic system

USGS Publications Warehouse

Lyons, W. Berry; Bullen, Thomas D.; Welch, Kathleen A.

2017-01-01

The McMurdo Dry Valleys, Antarctica, are a polar desert ecosystem. The hydrologic system of the dry valleys is linked to climate with ephemeral streams that flow from glacial melt during the austral summer. Past climate variations have strongly influenced the closed-basin, chemically stratified lakes on the valley floor. Results of previous work point to important roles for both in-stream processes (e.g., mineral weathering, precipitation and dissolution of salts) and in-lake processes (e.g., mixing with paleo-seawater and calcite precipitation) in determining the geochemistry of these lakes. These processes have a significant influence on calcium (Ca) biogeochemistry in this aquatic ecosystem, and thus variations in Ca stable isotope compositions of the waters can aid in validating the importance of these processes. We have analyzed the Ca stable isotope compositions of streams and lakes in the McMurdo Dry Valleys. The results validate the important roles of weathering of aluminosilicate minerals and/or CaCO3 in the hyporheic zone of the streams, and mixing of lake surface water with paleo-seawater and precipitation of Ca-salts during cryo-concentration events to form the deep lake waters. The lakes in the McMurdo Dry Valleys evolved following different geochemical pathways, evidenced by their unique, nonsystematic Ca isotope signatures.

Rare earth element geochemistry characteristics of seawater and porewater from deep sea in western Pacific.

PubMed

Deng, Yinan; Ren, Jiangbo; Guo, Qingjun; Cao, Jun; Wang, Haifeng; Liu, Chenhui

2017-11-28

Deep-sea sediments contain high concentrations of rare earth element (REE) which have been regarded as a huge potential resource. Understanding the marine REE cycle is important to reveal the mechanism of REE enrichment. In order to determine the geochemistry characteristics and migration processes of REE, seawater, porewater and sediment samples were systematically collected from the western Pacific for REE analysis. The results show a relatively flat REE pattern and the HREE (Heavy REE) enrichment in surface and deep seawater respectively. The HREE enrichment distribution patterns, low concentrations of Mn and Fe and negative Ce anomaly occur in the porewater, and high Mn/Al ratios and low U concentrations were observed in sediment, indicating oxic condition. LREE (Light REE) and MREE (Middle REE) enrichment in upper layer and depletion of MREE in deeper layer were shown in porewater profile. This study suggests that porewater flux in the western Pacific basin is a minor source of REEs to seawater, and abundant REEs are enriched in sediments, which is mainly caused by the extensive oxic condition, low sedimentation rate and strong adsorption capacity of sediments. Hence, the removal of REEs of porewater may result in widespread REE-rich sediments in the western Pacific basin.

Geochemistry of Dissolved Organic Matter in a Spatially Highly Resolved Groundwater Petroleum Hydrocarbon Plume Cross-Section.

PubMed

Dvorski, Sabine E-M; Gonsior, Michael; Hertkorn, Norbert; Uhl, Jenny; Müller, Hubert; Griebler, Christian; Schmitt-Kopplin, Philippe

2016-06-07

At numerous groundwater sites worldwide, natural dissolved organic matter (DOM) is quantitatively complemented with petroleum hydrocarbons. To date, research has been focused almost exclusively on the contaminants, but detailed insights of the interaction of contaminant biodegradation, dominant redox processes, and interactions with natural DOM are missing. This study linked on-site high resolution spatial sampling of groundwater with high resolution molecular characterization of DOM and its relation to groundwater geochemistry across a petroleum hydrocarbon plume cross-section. Electrospray- and atmospheric pressure photoionization (ESI, APPI) ultrahigh resolution mass spectrometry (FT-ICR-MS) revealed a strong interaction between DOM and reactive sulfur species linked to microbial sulfate reduction, i.e., the key redox process involved in contaminant biodegradation. Excitation emission matrix (EEM) fluorescence spectroscopy in combination with Parallel Factor Analysis (PARAFAC) modeling attributed DOM samples to specific contamination traits. Nuclear magnetic resonance (NMR) spectroscopy evaluated the aromatic compounds and their degradation products in samples influenced by the petroleum contamination and its biodegradation. Our orthogonal high resolution analytical approach enabled a comprehensive molecular level understanding of the DOM with respect to in situ petroleum hydrocarbon biodegradation and microbial sulfate reduction. The role of natural DOM as potential cosubstrate and detoxification reactant may improve future bioremediation strategies.

Spatial variability and geochemistry of rare earth elements in soils from the largest uranium-phosphate deposit of Brazil.

PubMed

Cunha, Cleyton Saialy Medeiros; da Silva, Ygor Jacques Agra Bezerra; Escobar, Maria Eugenia Ortiz; do Nascimento, Clístenes Williams Araújo

2018-02-22

The Itataia uranium-phosphate deposit is the largest uranium reserve in Brazil. Rare earth elements (REEs) are commonly associated with phosphate deposits; however, there are no studies on the concentrations of REEs in soils of the Itataia deposit region. Thus, the objective of the research was to evaluate the concentration and spatial variability of REEs in topsoils of Itataia phosphate deposit region. In addition, the influence of soil properties on the geochemistry of REEs was investigated. Results showed that relatively high mean concentrations (mg kg -1 ) of heavy REEs (Gd 6.01; Tb 1.25; Ho 1.15; Er 4.05; Tm 0.64; Yb 4.61; Lu 0.65) were found in surface soils samples. Soil properties showed weak influence on the geochemical behavior of REEs in soils, except for the clay content. On the other hand, parent material characteristics, such as P and U, had strong influence on REEs concentrations. Spatial distribution patterns of REEs in soils are clearly associated with P and U contents. Therefore, geochemical surveys aiming at the delineation of ore-bearing zones in the region can benefit from our data. The results of this work reinforce the perspective for co-mining of P, U and REEs in this important P-U reserve.

Disseminated gold-sulfide mineralization at the Zhaima deposit, eastern Kazakhstan

NASA Astrophysics Data System (ADS)

Kovalev, K. R.; Kuzmina, O. N.; Dyachkov, B. A.; Vladimirov, A. G.; Kalinin, Yu. A.; Naumov, E. A.; Kirillov, M. V.; Annikova, I. Yu.

2016-03-01

The Zhaima gold-sulfide deposit is located in the northwestern part of the West Kalba gold belt in eastern Kazakhstan. The mineralization is hosted in Lower Carboniferous volcanic and carbonate rocks formed under conditions of marginal-sea and island-arc volcanic activity. The paper considers the mineralogy and geochemistry of primary gold-sulfide ore and Au-bearing weathering crusts. Au-bearing arsenopyrite-pyrite mineralization formed during only one productive stage. Disseminated, stringer-disseminated, and massive rocks are enriched in Ti, Cr, V, Cu, and Ni, which correspond to the mafic profile of basement. The main ores minerals are represented by finely acicular arsenopyrite containing Au (up to few tens of ppm) and cubic and pentagonal dodecahedral pyrite with sporadic submicroscopic inclusions of native gold. The sulfur isotopic composition of sulfides is close to that of the meteoritic standard (δ34S =-0.2 to +0.2). The 40Ar/39Ar age of three sericite samples from ore veinlets corresponds to the Early Permian: 279 ± 3.3, 275.6 ± 2.9, and 272.2 ± 2.9 Ma. The mantle source of sulfur, ore geochemistry, and spatial compatibility of mineralization with basic dikes allow us to speak about the existence of deep fluid-magmatic systems apparently conjugate with the Tarim plume.

Geochemistry and petrology of selected coal samples from Sumatra, Kalimantan, Sulawesi, and Papua, Indonesia

USGS Publications Warehouse

Belkin, H.E.; Tewalt, S.J.; Hower, J.C.; Stucker, J.D.; O'Keefe, J.M.K.

2009-01-01

Indonesia has become the world's largest exporter of thermal coal and is a major supplier to the Asian coal market, particularly as the People's Republic of China is now (2007) and perhaps may remain a net importer of coal. Indonesia has had a long history of coal production, mainly in Sumatra and Kalimantan, but only in the last two decades have government and commercial forces resulted in a remarkable coal boom. A recent assessment of Indonesian coal-bed methane (CBM) potential has motivated active CBM exploration. Most of the coal is Paleogene and Neogene, low to moderate rank and has low ash yield and sulfur (generally < 10 and < 1??wt.%, respectively). Active tectonic and igneous activity has resulted in significant rank increase in some coal basins. Eight coal samples are described that represent the major export and/or resource potential of Sumatra, Kalimantan, Sulawesi, and Papua. Detailed geochemistry, including proximate and ultimate analysis, sulfur forms, and major, minor, and trace element determinations are presented. Organic petrology and vitrinite reflectance data reflect various precursor flora assemblages and rank variations, including sample composites from active igneous and tectonic areas. A comparison of Hazardous Air Pollutants (HAPs) elements abundance with world and US averages show that the Indonesian coals have low combustion pollution potential.

A Robust Analysis Method For Δ13c Signal Of Bulk Organic Matter In Speleothems

NASA Astrophysics Data System (ADS)

Bian, F.; Blyth, A. J.; Smith, C.; Baker, A.

2017-12-01

Speleothems preserve organic matter that is derived from both the surface soil and cave environments. This organic matter can be used to understand paleoclimate and paleoenvironments. However, a stable and quick micro-analysis method to measure the δ13C signals from speleothem organic matter separate from the total δ13C remains absent. And speleothem organic geochemistry is still relatively unexplored compared to inorganic geochemistry. In this research, for the organic matter analysis, bulk homogeneous power samples were obtained from one large stalagmite. These were dissolved by phosphoric acid to produce the aqueous solution. Then, the processed solution was degassed through a rotational vacuum concentrator. A liquid chromatograph was coupled to IRMS to control the oxidization and the measurement of analytes. This method is demonstrated to be robust for the analysis of speleothem d13C organic matter analysis under different preparation and instrumental settings, with the low standard deviation ( 0.2‰), and low sample consumption (<25 mg). Considering the complexity of cave environments, this method will be useful in further investigations the δ13C of entrapped organic matter and environmental controls in other climatic and ecological contexts, including the determination of whether vegetation or soil microbial activity is the dominant control on speleothem d13C of organic matter.

Comment on "Geochemistry of the Early Miocene volcanic succession of Northland, New Zealand, and implications for the evolution of subduction in the Southwest Pacific" by M.A. Booden, I.E.M. Smith, P.M. Black and J.L. Mauk

NASA Astrophysics Data System (ADS)

Schellart, W. P.

2012-01-01

In a recent paper Booden et al. (2011) present new geochemical and petrological data of Early Miocene volcanics from the Northland region (Northland volcanic belt) in New Zealand, and interpret these data to support a particular regional tectonic model. This tectonic model involves Early Miocene westward subduction of Cretaceous Pacific oceanic lithosphere below the Northland volcanic belt and the authors interpret the volcanic belt as a continental magmatic arc. Although the new data are not in disagreement with such a tectonic model, they provide more support for an alternative interpretation that involves a northeast-dipping subduction zone. Furthermore, geometric and plate kinematic data show that the west-dipping subduction model is unviable, geological and geophysical data contradict the model, while geodynamic arguments indicate that the model is implausible. Here it will be shown that a subduction model, involving a northeast-dipping southwestward retreating slab (made of the Late Cretaceous-Paleocene South Loyalty backarc basin lithosphere) that subsequently detaches, is in agreement with the local geology, geophysics and geochemistry, is geometrically, kinematically and geodynamically viable, and fits within the regional Southwest Pacific tectonic framework.

Long-Term Geochemical and Geodynamic Segmentation of the Paleo-Pacific Margin of Gondwana: Insight From the Antarctic and Adjacent Sectors

NASA Astrophysics Data System (ADS)

Nelson, D. A.; Cottle, J. M.

2017-12-01

Combined zircon geochemistry and geochronology of Mesozoic volcaniclastic sediments of the central Transantarctic Mountains, Antarctica, yield a comprehensive record of both the timing and geochemical evolution of the magmatic arc along the Antarctic sector of the paleo-Pacific margin of Gondwana. Zircon age populations at 266-183 Ma, 367-328 Ma, and 550-490 Ma correspond to episodic arc activity from the Ediacaran to the Jurassic. Zircon trace element geochemistry indicates a temporal shift from granitoid-dominated source(s) during Ediacaran to Early Ordovician times to mafic sources in the Devonian through Early Jurassic. Zircon initial ɛHf shifts to more radiogenic Hf isotope compositions following the Ross Orogeny and is inferred to reflect juvenile crustal growth within an extensional arc system during progressive slab rollback. These new ages and Hf isotopic record are similar to those from the Australian sector, indicating that these regions constituted an 3,000 km laterally continuous extensional arc from at least the Carboniferous to the Permian. Conversely, the South American sector records enriched zircon Hf isotopic compositions and compressional/advancing arc tectonics during the same time period. Our new data constrain the location of this profound along-arc geochemical and geodynamic "switch" to the vicinity of the Thurston Island block of West Antarctica.

Tectono-Magmatic Cycles and Geodynamic Settings of Ore-Bearing System Formation in the Southern Cis-Argun Region

NASA Astrophysics Data System (ADS)

Petrov, V. A.; Andreeva, O. V.; Poluektov, V. V.; Kovalenko, D. V.

2017-11-01

The ore-bearing geological structural units of the southern Cis-Argun region are considered in the context of varying geodynamic regimes related to the Proterozoic, Caledonian, and Hercynian tectono-magmatic cycles, as well as during the Late Mesozoic within-plate tectono-magmatic activity, which give rise to the formation of subalkaline igneous rocks of the Shakhtama Complex with Au, Cu-Mo, Pb-Zn-Ag metallogenic specialization; volcano-plutonic complexes of calderas with Mo-U, Pb-Zn, and fluorite ores; and rare-metal granite of the Kukulbei Complex with a Sn-W-Li-Ta spectrum of mineralization. The comparative geochemical characteristics inherent to Mesozoic ore-bearing felsic igneous rocks are considered, as well as geodynamic settings of ore-bearing fluido-magmatic systems, taking into consideration new data on geochemistry of bimodal trachybasalt-trachydacite series and rhyolite of the Turga Series, which fill the Strel'tsovka Caldera, whose trend of evolution is defined as a reference for geological history of the studied territory. The geodynamic conditions, phase composition, and geochemistry of rocks along with metallogenic specialization of Mesozoic volcano-plutonic complexes of southern Cis-Argun region are close to those of the Great Khingan Belt in northeastern China and eastern Mongolia.

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, NASA’s MESSENGER spacecraft is secure after transfer to the work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

NASA Image and Video Library

2004-03-10

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, NASA’s MESSENGER spacecraft is secure after transfer to the work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, NASA’s MESSENGER spacecraft is lifted off the pallet for transfer to a work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

NASA Image and Video Library

2004-03-10

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, NASA’s MESSENGER spacecraft is lifted off the pallet for transfer to a work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

KENNEDY SPACE CENTER, FLA. - In the high bay clean room at the Astrotech Space Operations processing facilities near KSC, workers remove the protective cover from NASA’s MESSENGER spacecraft. Employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

NASA Image and Video Library

2004-03-10

KENNEDY SPACE CENTER, FLA. - In the high bay clean room at the Astrotech Space Operations processing facilities near KSC, workers remove the protective cover from NASA’s MESSENGER spacecraft. Employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, workers check the placement of NASA’s MESSENGER spacecraft on a work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

NASA Image and Video Library

2004-03-10

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, workers check the placement of NASA’s MESSENGER spacecraft on a work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities near KSC, workers move NASA’s MESSENGER spacecraft into a high bay clean room. Employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

NASA Image and Video Library

2004-03-10

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities near KSC, workers move NASA’s MESSENGER spacecraft into a high bay clean room. Employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, an overhead crane moves NASA’s MESSENGER spacecraft toward a work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

NASA Image and Video Library

2004-03-10

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, an overhead crane moves NASA’s MESSENGER spacecraft toward a work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, an overhead crane lowers NASA’s MESSENGER spacecraft onto a work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

NASA Image and Video Library

2004-03-10

KENNEDY SPACE CENTER, FLA. - At the Astrotech Space Operations processing facilities, an overhead crane lowers NASA’s MESSENGER spacecraft onto a work stand. There employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

KENNEDY SPACE CENTER, FLA. - In the high bay clean room at the Astrotech Space Operations processing facilities near KSC, NASA’s MESSENGER spacecraft is revealed. Employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

NASA Image and Video Library

2004-03-10

KENNEDY SPACE CENTER, FLA. - In the high bay clean room at the Astrotech Space Operations processing facilities near KSC, NASA’s MESSENGER spacecraft is revealed. Employees of the Johns Hopkins University Applied Physics Laboratory, builders of the spacecraft, will perform an initial state-of-health check. Then processing for launch can begin, including checkout of the power systems, communications systems and control systems. The thermal blankets will also be attached for flight. MESSENGER - short for MErcury Surface, Space ENvironment, GEochemistry and Ranging - will be launched May 11 on a six-year mission aboard a Boeing Delta II rocket. Liftoff is targeted for 2:26 a.m. EDT on Tuesday, May 11.

Performance Audit of the U.S. Geological Survey, Energy Resource Program Inorganic Geochemistry Laboratory

USGS Publications Warehouse

Luppens, James A.; Janke, Louis G.; McCord, Jamey D.; Bullock, John H.; Brazeau, Lisa; Affronter, Ronald H.

2007-01-01

A performance audit of the U.S. Geological Survey (USGS), Energy Resource Program (ERP) Inorganic Geochemistry Laboratory (IGL) was conducted between August, 2003 and October, 2005. The goals were to ensure that a high level of analytical performance was maintained and identify any areas that could be enhanced. The audit was subdivided into three phases. Phase 1 was a preliminary assessment of current performance based on recent performance on CANSPEX samples. IGL performance was also compared to laboratories world-wide with similar scope. Phase 2 consisted of the implementation of the recommended changes made in Phase 1. Phase 3 of the audit consisted of a reassessment effort to evaluate the effectiveness of the recommendations made in the Phase 1 and an on-site audit of the laboratory facilities. Phases 1 and 3 required summary reports that are included in Appendices A and B of this report. The audit found that the IGL was one of the top two laboratories compared for trace element analyses. Several recommendations to enhance performance on major and minor elemental parameters were made and implemented. Demonstrated performance improvements as a result of the recommended changes were documented. Several initiatives to sustain the performance improvements gained from the audit have been implemented.

Palynofacies and organic geochemistry studies of organic matter from a wetland system of southern Brazil influenced by different hydrological regimes in the Quaternary

NASA Astrophysics Data System (ADS)

Gadens-Marcon, Gabrielli Teresa; Guerra-Sommer, Margot; Mendonça-Filho, João Graciano

2014-12-01

The main goal of this study was to quantitatively and qualitatively characterize the sedimentary organic matter (OM) and demonstrate the usefulness of geochemistry and palynofacies analysis for obtaining paleoenvironmental data for the Holocene in southernmost Brazil. The results indicate that during the time interval from 10,586 cal yr BP to the present, the study area housed a wetland characterized by different hydrologic regimes. The basal peaty deposits correspond to a phase influenced mainly by the groundwater table, whereas the upper deposits composed of silty organic mud indicate fluvial influence related to river overflow events. In a similar manner, the TOC (total organic carbon) and TS (total sulfur) contents are higher in the basal portion of the profile, decreasing toward the top. These findings could be related to granulometry alterations that are linked to hydrologic regimes or anthropogenic interference in the landscape dynamics. Anomalous TS content observed in one of the samples might be due to an external source and perhaps related to the presence of thermal springs in the region. These types of areas have potential as a modern reference that can be applied in the reconstruction of past analogous environments such as coal deposits associated with fluvial paleoenvironments.

Sustainable rehabilitation of mining waste and acid mine drainage using geochemistry, mine type, mineralogy, texture, ore extraction and climate knowledge.

PubMed

Anawar, Hossain Md

2015-08-01

The oxidative dissolution of sulfidic minerals releases the extremely acidic leachate, sulfate and potentially toxic elements e.g., As, Ag, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Th, U, Zn, etc. from different mine tailings and waste dumps. For the sustainable rehabilitation and disposal of mining waste, the sources and mechanisms of contaminant generation, fate and transport of contaminants should be clearly understood. Therefore, this study has provided a critical review on (1) recent insights in mechanisms of oxidation of sulfidic minerals, (2) environmental contamination by mining waste, and (3) remediation and rehabilitation techniques, and (4) then developed the GEMTEC conceptual model/guide [(bio)-geochemistry-mine type-mineralogy- geological texture-ore extraction process-climatic knowledge)] to provide the new scientific approach and knowledge for remediation of mining wastes and acid mine drainage. This study has suggested the pre-mining geological, geochemical, mineralogical and microtextural characterization of different mineral deposits, and post-mining studies of ore extraction processes, physical, geochemical, mineralogical and microbial reactions, natural attenuation and effect of climate change for sustainable rehabilitation of mining waste. All components of this model should be considered for effective and integrated management of mining waste and acid mine drainage. Copyright © 2015 Elsevier Ltd. All rights reserved.

The petrology, structure and geochemistry of an Archean terrane in the North Snowy Block, Beartooth Mountains, Montana

NASA Astrophysics Data System (ADS)

Mogk, D. W.

1984-12-01

Six major rock units in the North Snowy Block in an Archean mobile belt are recognized between all units representing discontinuities in metamorphic grade, structural style, geochemistry, and isotopic ages. Four of the units occur in NE trending linear belts; the Basement Gneiss; the phyllitic Davis Creek Schist; the mount cowen augen gneis; the Paragneiss unit. Overlying the linear units is the 3.2 Ga old Pine Creek Nappe Complex, an isoclinally folded, middle to upper amphibolite facies, thrust nappe consisting of the Barney Creek Amphibolite, George Lake Marble and Jewel Quartzite. The highest structural units, including a thick sequence of upper amphibolite grade supracrustal rocks and a lower section of injected 3.4 Ga old granitic to tonalitic migmatitic rocks were emplaced on the Columbine Thrust. It is shown that there was secular variation in tectonic style in the Archean of southwest Montana. Three stages are recognized: (1) melting of ancient matic crust produced trondhjemitic continental nuclei; (2) numerous ensialic basins were created and destroyed, resulting in high grade metamorphism and mignatization of supracrustal rocks; and (3) contemporary style plate tectonics resulted in generation of large volumes of andesities and calc-alkaline granitic rocks, transcurrent faulting, and thrust faulting.

Geochemistry and the understanding of ground-water systems

USGS Publications Warehouse

Glynn, Pierre D.; Plummer, Niel

2005-01-01

Geochemistry has contributed significantly to the understanding of ground-water systems over the last 50 years. Historic advances include development of the hydrochemical facies concept, application of equilibrium theory, investigation of redox processes, and radiocarbon dating. Other hydrochemical concepts, tools, and techniques have helped elucidate mechanisms of flow and transport in ground-water systems, and have helped unlock an archive of paleoenvironmental information. Hydrochemical and isotopic information can be used to interpret the origin and mode of ground-water recharge, refine estimates of time scales of recharge and ground-water flow, decipher reactive processes, provide paleohydrological information, and calibrate ground-water flow models. Progress needs to be made in obtaining representative samples. Improvements are needed in the interpretation of the information obtained, and in the construction and interpretation of numerical models utilizing hydrochemical data. The best approach will ensure an optimized iterative process between field data collection and analysis, interpretation, and the application of forward, inverse, and statistical modeling tools. Advances are anticipated from microbiological investigations, the characterization of natural organics, isotopic fingerprinting, applications of dissolved gas measurements, and the fields of reaction kinetics and coupled processes. A thermodynamic perspective is offered that could facilitate the comparison and understanding of the multiple physical, chemical, and biological processes affecting ground-water systems.

Metal Oxides in Surface Sediment Control Nickel Bioavailability to Benthic Macroinvertebrates.

PubMed

Mendonca, Raissa M; Daley, Jennifer M; Hudson, Michelle L; Schlekat, Christian E; Burton, G Allen; Costello, David M

2017-11-21

In aquatic ecosystems, the cycling and toxicity of nickel (Ni) are coupled to other elemental cycles that can limit its bioavailability. Current sediment risk assessment approaches consider acid-volatile sulfide (AVS) as the major binding phase for Ni, but have not yet incorporated ligands that are present in oxic sediments. Our study aimed to assess how metal oxides play a role in Ni bioavailability in surficial sediments exposed to effluent from two mine sites. We coupled spatially explicit sediment geochemistry (i.e., separate oxic and suboxic) to the indigenous macroinvertebrate community structure. Effluent-exposed sites contained high concentrations of sediment Ni and AVS, though roughly 80% less AVS was observed in surface sediments. Iron (Fe) oxide mineral concentrations were elevated in surface sediments and bound a substantial proportion of Ni. Redundancy analysis of the invertebrate community showed surface sediment geochemistry significantly explained shifts in community abundances. Relative abundance of the dominant mayfly (Ephemeridae) was reduced in sites with greater bioavailable Ni, but accounting for Fe oxide-bound Ni greatly decreased variation in effect thresholds between the two mine sites. Our results provide field-based evidence that solid-phase ligands in oxic sediment, most notably Fe oxides, may have a critical role in controlling nickel bioavailability.

The emplacement, geochemistry and petrogenesis of two central Morocco Hercynian granites. Geotectonic implications

NASA Astrophysics Data System (ADS)

Giuliani, G.; Cheilletz, A.; Zimmermann, J. L.

New field, petrographic and geochemical data including REE, Rb-Sr, and K-Ar, are presented concerning the emplacement and petrogenesis of two calc-alkaline Moroccan Hercynian granites: the Zaër pluton and the Djebel Aouam stocks. Zonation in the Zaër pluton does not appear to result from simple fractional crystallization nor from hydrothermal alteration but is rather the diapiric intrusion of two interlocked bodies. REE geochemistry supports the interpretation that the biotite-granodiorite magma (301 ± 8.2 M.a.) and the Djebel Aouam stocks appear to have been derived by fusion of crustal materials with possible mantle contamination ( Initial87Sr/ 86Srratio = 0.70514 ). The second two-mica granitic magma (283.4 ± 6.2 M.a.) corresponds to a peraluminous granite (1.22 < A/ CNK < 1.33) generated by fusion of continental crust including mature sedimentarr materials (Initial 87Sr/ 86Sr ratio = 0.70836). These granites are compared to the Acadian granites of north Appalachian and classified in the «post-collision, uplift environmentå type. An illustrative four step model presenting the generation and emplacement of these two granites together with the associated W-Sn-Pb-Zn-Ag mineralizations is proposed: (1) first magma generation, (2) first melt emplacement, (3) second melt emplacement, (4) late convective flow.

Sedimentology, geochemistry, pollution status and ecological risk assessment of some heavy metals in surficial sediments of an Egyptian lagoon connecting to the Mediterranean Sea.

PubMed

El-Said, Ghada F; Draz, Suzanne E O; El-Sadaawy, Manal M; Moneer, Abeer A

2014-01-01

Spatial distribution of heavy metals (Co, Cu, Ni, Cr, Mn, Zn and Fe) was studied on Lake Edku's surface sediments in relation to sedimentology and geochemistry characteristics and their contamination status on the ecological system. Lake Edku's sediments were dominated by sandy silt and silty sand textures and were enriched with carbonate content (9.83-58.46%). Iron and manganese were the most abundant heavy metals with ranges of 1.69 to 8.06 mg g(-1) and 0.88 to 3.27 mg g(-1), respectively. Cobalt and nickel showed a harmonic distribution along the studied sediments. The results were interpreted by the statistical means. The heavy metal pollution status and their ecological risk in Lake Edku was evaluated using the sediment quality guidelines and the contamination assessment methods (geoaccumulation, pollution load and potential ecological risk indices, enrichment factor, contamination degree as well as effect range median (ERM) and probable effect level (PEL) quotients). Amongst the determined heavy metals, zinc had the most ecological risk. Overall, the heavy metals in surface sediments showed ecological effect range from moderate to considerable risk, specially, in the stations in front of the seawater and in drain sources that had the highest toxic priority.

Immobilization of Radionuclides Through Anaerobic Bio-oxidation of Fe(ll)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Coates, John D.

2005-06-01

Over the last year we have focused our efforts on two independent aspects (a) further investigation of the microbiology and geochemistry of nitrate-dependent Fe(II) oxidation and (b) assembling the sequenced genome of Dechloromonas aromatica strain RCB. This work has been performed in a cooperative fashion amongst the independent labs of the three PI's with the UC Berkeley lab taking the lead under the guidance of J.D. Coates.

Analytical techniques for identification and study of organic matter in returned lunar samples

NASA Technical Reports Server (NTRS)

Burlingame, A. L.

1974-01-01

The results of geochemical research are reviewed. Emphasis is placed on the contribution of mass spectrometric data to the solution of specific structural problems. Information on the mass spectrometric behavior of compounds of geochemical interest is reviewed and currently available techniques of particular importance to geochemistry, such as gas chromatograph-mass spectrometer coupling, modern sample introduction methods, and computer application in high resolution mass spectrometry, receive particular attention.

Unravelling ancient microbial history with community proteogenomics and lipid geochemistry.

PubMed

Brocks, Jochen J; Banfield, Jillian

2009-08-01

Our window into the Earth's ancient microbial past is narrow and obscured by missing data. However, we can glean information about ancient microbial ecosystems using fossil lipids (biomarkers) that are extracted from billion-year-old sedimentary rocks. In this Opinion article, we describe how environmental genomics and related methodologies will give molecular fossil research a boost, by increasing our knowledge about how evolutionary innovations in microorganisms have changed the surface of planet Earth.

Remote sensing and geologic studies of the planetary crusts

NASA Technical Reports Server (NTRS)

Hawke, B. R.

1983-01-01

Dark haloed craters and regions of the Moon which were sites of ancient volcanism were remotely sensed as well as KREEP deposits in the Inbrium region. The relationship between geology and geochemistry in the Undarum/Spumans region was also examined. Results are summarized for observations of the Reiner Gamma formation, studies of impact cratering mechanics and processes, spectral variations of asteroidal surfaces, albedo and color variations on Ganymede, and studies of lunar impact structures.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pfiffner, Susan M.

Our current research represents a joint effort between Oak Ridge National Laboratory (ORNL), Florida State University (FSU), and the University of Tennessee. ORNL will serve as the lead institution with Dr. A.V. Palumbo responsible for project coordination, integration, and deliverables. This project was initiated in November, 2004, in the Integrative Studies Element of the NABIR program. The overall goal of our project is to provide an improved understanding of the relationships between microbial community structure, geochemistry, and metal reduction rates.

Use of Geochemistry Data Collected by the Mars Exploration Rover Spirit in Gusev Crater to Teach Geomorphic Zonation through Principal Components Analysis

ERIC Educational Resources Information Center

Rodrigue, Christine M.

2011-01-01

This paper presents a laboratory exercise used to teach principal components analysis (PCA) as a means of surface zonation. The lab was built around abundance data for 16 oxides and elements collected by the Mars Exploration Rover Spirit in Gusev Crater between Sol 14 and Sol 470. Students used PCA to reduce 15 of these into 3 components, which,…

Arsenic and radionuclide occurrence and relation to geochemistry in groundwater of the Gulf Coast Aquifer System in Houston, Texas, 2007–11

USGS Publications Warehouse

Oden, Jeannette H.; Szabo, Zoltan

2016-03-21

Associated geochemical conditions conducive for mobility of arsenic and radionuclides and their spatial and vertical extent in the Gulf Coast aquifer system in Houston are important aspects to the areal management of the municipal groundwater supplies in Houston. Ongoing research is seeking to define chemical or geological factors that are the optimal indicators for elevated concentrations of these naturally occurring constituents.

Oxygen and hydrogen isotope geochemistry of zeolites

NASA Technical Reports Server (NTRS)

Karlsson, Haraldur R.; Clayton, Robert N.

1990-01-01

Oxygen and hydrogen isotope ratios for natural samples of the zeolites analcime, chabazite, clinoptilolite, laumontite, mordenite, and natrolite have been obtained. The zeolite samples were classified into sedimentary, hydrothermal, and igneous groups. The ratios for each species of zeolite are reported. The results are used to discuss the origin of channel water, the role of zeolites in water-rock interaction, and the possibility that a calibrated zeolite could be used as a low-temperature geothermometer.

Geochemical Constraints on Core Formation in the Earth

NASA Technical Reports Server (NTRS)

Jones, John H.; Drake, Michael J.

1986-01-01

New experimental data on the partitioning of siderophile and chalcophile elements among metallic and silicate phases may be used to constrain hypotheses of core formation in the Earth. Three current hypotheses can explain gross features of mantle geochemistry, but none predicts siderophile and chalcophile element abundances to within a factor of two of observed values. Either our understanding of metal-silicate interactions and/or our understanding of the early Earth requires revision.

Investigating the Transport and Fate of Polychlorinated Biphenyls with Stable Chlorine Isotopes

DTIC Science & Technology

2001-09-30

recently accepted in the journal Organic Geochemistry. We published another manuscript in Environmental Science and Pollution Research on the...Chlorine in the Environment a book written by Ruth Stringer and Paul Johnson. This review will soon appear in the journal Environmental Science and...Heraty, L.J., Holt, B.D., Sturchio, N.C., Eglinton, T.I., Drenzek, N.J., Xu, L., Lake, J.L., Maruya, K.A., 2000. Environmental Science and

Acceptance of the Treibs Award

NASA Astrophysics Data System (ADS)

Freeman, Katherine H.

2018-03-01

My thanks to Roger Summons, for such a generous and kind introduction. My sincere thanks to the members of the selection committee, to those who did the work to support my nomination, and to the leadership of the Organic Geochemistry Division, especially Liz Sikes and Hilairy Hartnett. My thanks also to the EAOG and the IMOG organizers for sharing time in the program, and for bringing us to Florence, a beautiful city of art and science.

Chapter A6. Section 6.4. pH

USGS Publications Warehouse

Wilde, Franceska D.; Busenberg, Eurybiades; Radtke, Dean B.

2006-01-01

Measurement of pH is critical to the understanding of the viability and vulnerability of environmental waters and is considered a master variable in determining the aqueous geochemistry of an aqueous system. pH is a measure that represents the hydrogen-ion concentration (activity) of a solution. This section of the National Field Manual (NFM) describes U.S. Geological Survey (USGS) guidance and protocols for measurement of pH in ground and surface waters.

Surface Exposure Geochronology Using Cosmogenic Nuclides: Applications in Antarctic Glacial Geology

DTIC Science & Technology

1994-02-01

Department of Marine Chemistry and Geochemistry Dist Special Dean of Graduate Studies I I I SURFACE EXPOSURE GEOCHRONOLOGY USING COSMOGENIC NUCLIDES... studies of Sirius Group tills. Comparison of measured 10Be concentrations in Sirius Group deposits with those predicted with a model of the effects of...that this deposit does not, 1 as previous studies suggested, represent a single ice advance in response to lowered sea level at the last glacial

Mantle reservoirs (EM-1, OIB, E-MORB and N-MORB), long duration and polystages history for PGE-bearing paleoproterozoic layered intrusions in the N-E part of Fennoscandian Shield.

NASA Astrophysics Data System (ADS)

Bayanova, Tamara; Nerovich, Ludmila; Serov, Pavel; Kunakkuzin, Evgeniy; Elizarov, Dmitriy

2015-04-01

Paleoproterozoic layered PGE -bearing intrusions located in the N-E part of the Fennoscandian Shield and have a total are about 2000 km2. Long multidisciplinary studies using isotope Nd-Sr, U-Pb and 3He/4He systematics permit create a big bank of geochemistry data for different part of the intrusions: barren and main Cu-Ni-Cr-Ti-V and PGE phases, dykes complexes and host rocks. Based on U-Pb isotope data (on baddeleyite and zircon) and Sm-Nd mineral isochrones (on rock-forming and sulphides minerals) there is distinguished long magmatic duration from 2.53 to 2.40 Ga. Using precise U-Pb and Sm-Nd data for different part of the intrusions there are established four main impulses: 2.53, 2.50, 2.45, and 2.40 Ga of magmatic (LIP) activities for gabbronorite, anothosite et.set. rocks. The primary reservoir for all precious and multimetal massifs are considered as enriched mantle EM-1 using ɛNd- ISr system with negative ɛNd values and low ISr data for whole rocks of the intrusions. Dyke complexes are presented as three groups: high Ti-ferrodolerites, low Ti and low Fe-gabbronorites. Complex isotope (U-Pb, Sm-Nd) and geochemistry (REE, ɛNd, ISr) data investigations reflect OIB, E-MORB and N-MORB reservoirs for its origin (Nerovich et all., 2014). Isotope 3He/4He and 3He concentrations for accessory minerals ( ilmenite, magnetite et. set ) from the layered paleoproterozoic intrusions reflect significant lower mantle component and upper mantle contribution. According to the model of binary mixing (Jahn et all, 2000) there were calculated mantle and core component into plume magmatic reservoir connected with the origin of the PGE paleoproterozoic intrusions. The mantle contributions lie in the interval from 85 to 93% and core component are very less. All investigations are devoted to memory of academician RAS, professor F.Mitrofanov (Russia), he was a leader of scientific school for geology, geochemistry and metallogenesis of ore deposits. The studies are contribution by RFBR OFI-M 13-05-12055, 13-05-00493, Department of Earth Sciences RAS (programs 2 and 4) and IGCP-SIDA 599.

Gas hydrate prospecting using well cuttings and mud-gas geochemistry from 35 wells, North Slope, Alaska

USGS Publications Warehouse

Lorenson, T.D.; Collett, Timothy S.

2011-01-01

Gas hydrate deposits are common on the North Slope of Alaska around Prudhoe Bay; however, the extent of these deposits is unknown outside of this area. As part of a U.S. Geological Survey (USGS) and Bureau of Land Management gas hydrate research collaboration, well-cutting and mud-gas samples have been collected and analyzed from mainly industry-drilled wells on the North Slope for the purpose of prospecting for gas hydrate deposits. On the Alaska North Slope, gas hydrates are now recognized as an element within a petroleum systems approach or "total petroleum system." Since 1979, 35 wells have been sampled from as far west as Wainwright to Prudhoe Bay in the east. Regionally, the USGS has assessed the gas hydrate resources of the North Slope and determined that there is about 85.4 trillion cubic feet of technically recoverable hydrate-bound gas within three assessment units. The assessment units are defined mainly by three separate stratigraphic sections and constrained by the physical temperatures and pressures where gas hydrate can form. Geochemical studies of known gas hydrate occurrences on the North Slope have shown a link between gas hydrate and more deeply buried conventional oil and gas deposits. The link is established when hydrocarbon gases migrate from depth and charge the reservoir rock within the gas hydrate stability zone. It is likely gases migrated into conventional traps as free gas and were later converted to gas hydrate in response to climate cooling concurrent with permafrost formation. Results from this study indicate that some thermogenic gas is present in 31 of the wells, with limited evidence of thermogenic gas in four other wells and only one well with no thermogenic gas. Gas hydrate is known to occur in one of the sampled wells, likely present in 22 others on the basis of gas geochemistry, and inferred by equivocal gas geochemistry in 11 wells, and one well was without gas hydrate. Gas migration routes are common in the North Slope and include faults and widespread, continuous shallowly dipping permeable sand sections that are potentially in communication with deeper oil and gas sources. The application of the petroleum system model with the geochemical evidence suggests that gas hydrate deposits may be widespread across the North Slope of Alaska.

Mantle plumes and hotspot geochemistry

NASA Astrophysics Data System (ADS)

Jackson, M. G.; Becker, T. W.; Konter, J.

2017-12-01

Ever improving global seismic models, together with expanding databases of mantle derived hotspot lavas, herald advances that relate the geochemistry of hotspots with low seismic shear-wave velocity conduits (plumes) in the mantle. Early efforts linked hotspot geochemistry with deep mantle large low velocity provinces (LLVPs) [1]. More recently, Konter and Becker (2012) [2] observed that the proportion of the C mantle component (inferred from Sr-Nd-Pb isotopes) in hotspot lavas shows an inverse relationship with seismic S-wave velocity anomalies in the shallow mantle (200 km) beneath each hotspot. They proposed that these correlations should also be made based on 3He/4He. Thus, we compare 3He/4He versus seismic S-wave velocity anomalies at 200 km depth. We find that plume-fed hotspots with the highest maximum 3He/4He (i.e., which host more of the C component) have higher hotspot buoyancy fluxes and overlie regions of lower seismic S-wave velocity (interpreted to relate to hotter mantle temperatures) at 200 km depth than hotspots that have only low 3He/4He [3]. This result complements recent work that shows an inverse relationship between maximum 3He/4He and seismic S-wave velocity anomalies in the mantle beneath the western USA [4]. The relationship between 3He/4He, shallow mantle seismic S-wave velocity anomalies, and buoyancy flux is most easily explained by a model where hotter plumes are more buoyant and entrain more of a deep, dense high 3He/4He reservoir than cooler plumes that underlie low 3He/4He hotspots. If the high 3He/4He domain is denser than other mantle components, it will be entrained only by the hottest, most buoyant plumes [3]. Such a deep, dense reservoir is ideally suited to preserving early-formed Hadean domains sampled in modern plume-fed hotspots. An important question is whether, like 3He/4He, seismic S-wave velocity anomalies in the mantle are associated with distinct heavy radiogenic isotopic compositions. C signatures are related to hot mantle upwellings, but are geochemically enriched (EM) and HIMU mantle signatures observed in oceanic hotspots associated with such upwellings? We will present new constraints on this and similar problems. [1] Castillo (1988) Nature 336. [2] Konter and Becker (2012) G-cubed 13. [3] Jackson et al. (2017), Nature 542. [4] Crossey et al. (2016), EPSL 435.

Onondaga Lake: A Forsaken Superfund Site, or a Sampling Playground for Environmental Geochemistry Classes?

NASA Astrophysics Data System (ADS)

Karmosky, C. C.; Harpp, K. S.

2004-05-01

Onondaga Lake, in Syracuse, NY, is described by the EPA as one of the most polluted lakes in the US. High levels of heavy metal and semi-volatile organic contamination provide an excellent case study that serves as the cornerstone for an environmental geochemistry course at Colgate University. Our course is designed to teach students basic environmental analysis skills including experimental design, sample preparation, analytical instrumentation operation, data processing and statistical analysis, and preparation of a collaborative scientific paper. Participating students generally have some background in environmental geology, but rarely more than one semester of chemistry. The Onondaga Lake project is the focus of the course for approximately half the semester. At the outset of the project, students are presented with a driving question that is answered through a series of guided field and lab investigations, such as an assessment of the environmental consequences of a proposed marina along the lakefront. The students' first task is to delve into the lake's environmental history, including identification of contaminants, location of point and non-point pollution sources, and clean-up efforts. Students then participate in 2 field trips to the site. First, students learn the geography of the lake system, collect sediment and water samples, and observe mitigation efforts at the wastewater treatment plant. The second trip is 2-3 weeks later, after students have assessed further sampling needs. Identification and quantification of organic compounds are accomplished by GC-MS, and heavy metal contents are determined by ICP-MS. Students compile their results, perform statistical analyses, and collaboratively draw their conclusions regarding the impact of the proposed project. The final product is a single report written by the entire class, an exercise in organization, cooperation, and planning that is usually the most challenging, but ultimately the most rewarding, aspect of the project. Basic laboratory and data processing skills are introduced to the class as they become necessary, but not before they are applied to the project. We have found that students find these very real environmental questions so compelling that they are motivated to learn the necessary skills when, in a more isolated laboratory setting, they would often otherwise be intimidated by them. Instead, the Onondaga Lake case study provides students with a powerful motivating force to learn both environmental geochemistry and the underlying chemical principles.

Hydrological controls on Chemical weathering in the Jinsha River draining the southeastern Qinghai-Tibet Plateau

NASA Astrophysics Data System (ADS)

Zhong, Jun; Li, Siliang; Yue, Fujun; Ding, Hu

2016-04-01

The geochemistry of the riverine waters could provide an insight in understanding the surface processes, such as chemical weathering and carbon cycle. As the headwater of Chanjiang (Yangtze) River, Jinsha River flows on the southestern Qinhai-Tibet Plateau at high altitute (from 1000m to 4600m) above the major areas of human impact and carries important information on this erosive region. In spite of being impacted by monsoonal climate and with significant variations of discharge, the temporal variations of compositions of main ions and chemical weathering of Jinsha River are rarely documented. In this study, a systematic investigation on the seasonal and episodic water geochemistry (major ions and δ13CDIC) of the outlet of Jinsha River basin were carried out with the purpose of 1) characterizing temporal variations of aqueous geochemistry and its controlling factors, 2) quantifying rock weathering and associated CO2 consumption rates, and 3) exploring the impact of hydrological controls on chemical weathering of the Jinsha River Basin. The results show that the concentrations of Ca, Mg, HCO3 and NO3 are generally decreased during monsoon season, while that of Cl, Na, SO4, K are relative higher in monsoon season than in dry season, which may be mainly caused by hydrological condition, i.e., with increased runoff, more surficial evaporate dissolved water and salt lake water of the Basin flow into the river. Moreover, due to increased contribution of soil CO2and fast decomposition of organic matters, δ13CDIC in the high-flow period has more negative values than in low-flow period, and shows a negative relation with the concentration of DOC. An increasing of Ca concentrations was found with shift of the δ13CDIC values, positively, indicating the precipitation might be occured. Meanwhile, the dissolution of gypsum and anhydrite might enhance the calcium precipition. The forward model results show that the weathering rates of silicate and carbonate as well as that of related CO2 consumption have a positive relation with water discharge, highlighting the hydrological controls on chemical weathering and CO2 consumption rates, which should be considered in the future study in river basins impacted by monsoon climate. This work was supported by The China National Science Fund for Outstanding Young Scholars (Grant No. 41422303).

Long-Lived Mantle Plumes Sample Multiple Deep Mantle Geochemical Domains: The Example of the Hawaiian-Emperor Chain

NASA Astrophysics Data System (ADS)

Harrison, L.; Weis, D.

2017-12-01

Oceanic island basalts provide the opportunity for the geochemist to study the deep mantle source removed from continental sources of contamination and, for long-lived systems, the evolution of mantle sources with time. In the case of the Hawaiian-Emperor (HE) chain, formation by a long-lived (>81 Myr), deeply-sourced mantle plume allows for insight into plume dynamics and deep mantle geochemistry. The geochemical record of the entire chain is now complete with analysis of Pb-Hf-Nd-Sr isotopes and elemental compositions of the Northwest Hawaiian Ridge (NWHR), which consists of 51 volcanoes spanning 42 Ma between the bend in the chain and the Hawaiian Islands. This segment of the chain previously represented a significant data gap where Hawaiian plume geochemistry changed markedly, along with magmatic flux: only Kea compositions have been observed on Emperor seamounts (>50 Ma), whereas the Hawaiian Islands (<6 Ma) present both Kea and Loa compositions. A database of 700 Hawaiian Island shield basalts Pb-Hf-Nd-Sr isotopic compositions were compiled to construct a logistical regression model of Loa or Kea affinity that sorts data into a dichotomous category and provides insight into the relationship between independent variables. We use this model to predict whether newly analyzed NWHR samples are Loa or Kea composition based on their Pb-Sr-Nd-Hf isotopic compositions. The logistical regression model is significantly better at prediciting Loa or Kea affinity than the constant only model (χ2=263.3, df=4, p<0.0001), with Pb and Sr isotopes providing the most predicitive power. Daikakuji, West Nihoa, Nihoa, and Mokumanamana erupt Loa-type lavas, suggesting that the Loa source is sampled ephemerally during the NWHR and increases in presence and volume towards the younger section of the NWHR (younger than Midway 20-25 Ma). These results complete the picture of Hawaiian mantle plume geochemistry and geodynamics for 81 Myr, and show that the Hawaiian mantle plume has transitioned from a dominately Kea source during the Emperor seamounts and older NWHR to an increasingly enriched Loa source from the mid NWHR to Hawaiian Islands. We propose this is due to Hawaiian mantle plume drift through different lower mantle geohemical domains.

Recovering the primary geochemistry of Jack Hills zircons through quantitative estimates of chemical alteration

NASA Astrophysics Data System (ADS)

Bell, Elizabeth A.; Boehnke, Patrick; Harrison, T. Mark

2016-10-01

Despite the robust nature of zircon in most crustal and surface environments, chemical alteration, especially associated with radiation damaged regions, can affect its geochemistry. This consideration is especially important when drawing inferences from the detrital record where the original rock context is missing. Typically, alteration is qualitatively diagnosed through inspection of zircon REE patterns and the style of zoning shown by cathodoluminescence imaging, since fluid-mediated alteration often causes a flat, high LREE pattern. Due to the much lower abundance of LREE in zircon relative both to other crustal materials and to the other REE, disturbance to the LREE pattern is the most likely first sign of disruption to zircon trace element contents. Using a database of 378 (148 new) trace element and 801 (201 new) oxygen isotope measurements on zircons from Jack Hills, Western Australia, we propose a quantitative framework for assessing chemical contamination and exchange with fluids in this population. The Light Rare Earth Element Index is scaled on the relative abundance of light to middle REE, or LREE-I = (Dy/Nd) + (Dy/Sm). LREE-I values vary systematically with other known contaminants (e.g., Fe, P) more faithfully than other suggested proxies for zircon alteration (Sm/La, various absolute concentrations of LREEs) and can be used to distinguish primary compositions when textural evidence for alteration is ambiguous. We find that zircon oxygen isotopes do not vary systematically with placement on or off cracks or with degree of LREE-related chemical alteration, suggesting an essentially primary signature. By omitting zircons affected by LREE-related alteration or contamination by mineral inclusions, we present the best estimate for the primary igneous geochemistry of the Jack Hills zircons. This approach increases the available dataset by allowing for discrimination of on-crack analyses (and analyses with ambiguous or no information on spot placement or zircon internal structures) that do not show evidence for chemical alteration. It distinguishes between altered and unaltered samples in ambiguous cases (e.g., relatively high Ti), identifying small groups with potentially differing provenance from the main Jack Hills population. Finally, filtering of the population using the LREE-I helps to more certainly define primary correlations among trace element variables, potentially relatable to magmatic compositional evolution.

Biogeoscience from a Metallomic and Proteomic Perspective

NASA Astrophysics Data System (ADS)

Anbar, A. D.; Shock, E.

2004-12-01

In the wake of the genomics revolution, life scientists are expanding their focus from the genome to the "proteome" - the assemblage of all proteins in a cell - and the "metallome" - the distribution of inorganic species in a cell. The proteome and metallome are tightly connected because proteins and protein products are intimately involved in the transport and homeostasis of inorganic elements, and because many enzymes depend on inorganic elements for catalytic activity. Together, they are at the heart of metabolic function. Unlike the relatively static genome, the proteome and metallome are extremely dynamic, changing rapidly in response to environmental cues. They are substantially more complex than the genome; for example, in humans, some 30,000 genes code for approximately 500,000 proteins. Metaphorically, the proteome and metallome constitute the complex, dynamic "language" by which the genome and the environment communicate. Therefore biogeochemists, like life scientists, are moving beyond a strictly genomic perspective. Research guided by proteomic and metallomic perspectives and methodologies should provide new insights into the connections between life and the inorganic Earth in modern environments, and the evolution of these connections through time. For example, biogeochemical research in modern environments, such as Yellowstone hot springs, is hindered by the gap between genomic determinations of metabolic potential in ecosystems and geochemical characterizations of the energetic boundary conditions faced by these ecosystems; genomics tells us "who is there" and geochemistry tells us "what they might be doing", but neither genomics nor geochemistry easily provide quantitative information about which metabolisms are actually active or a framework for understanding why ecosystems do not fully exploit the energy available in their surroundings. Such questions are fundamentally kinetic rather than thermodynamic and therefore demand that we characterize and understand the proteins and inorganic elements used by organisms to catalyze reactions and capture energy from their surroundings. Similar challenges are faced when attempting to map the evolutionary relationships inferred from phylogenetic analyses of genomes to ecological histories determined by geochemists and paleobiologists - for example, ongoing efforts to understand the evolutionary history of eukaryotes and metazoa - because the driving forces for the evolution and ecological radiation of organisms lie at the intersection of metabolism and environment, and hence in the gap between genomes and geochemistry. Future progress in understanding the biogeochemistry of modern and ancient environments will be spurred by integrating proteomic and metallomic methods and perspectives.

Using geochemistry to identify the source of groundwater to Montezuma Well, a natural spring in Central Arizona, USA: Part 2

USGS Publications Warehouse

Johnson, Raymond H.; DeWitt, Ed; Wirt, Laurie; Manning, Andrew H.; Hunt, Andrew G.

2012-01-01

Montezuma Well is a unique natural spring located in a sinkhole surrounded by travertine. Montezuma Well is managed by the National Park Service, and groundwater development in the area is a potential threat to the water source for Montezuma Well. This research was undertaken to better understand the sources of groundwater to Montezuma Well. Strontium isotopes (87Sr/86Sr) indicate that groundwater in the recharge area has flowed through surficial basalts with subsequent contact with the underlying Permian aged sandstones and the deeper, karstic, Mississippian Redwall Limestone. The distinctive geochemistry in Montezuma Well and nearby Soda Springs (higher concentrations of alkalinity, As, B, Cl, and Li) is coincident with added carbon dioxide and mantle-sourced He. The geochemistry and isotopic data from Montezuma Well and Soda Springs allow for the separation of groundwater samples into four categories: (1) upgradient, (2) deep groundwater with carbon dioxide, (3) shallow Verde Formation, and (4) mixing zone. δ18O and δD values, along with noble gas recharge elevation data, indicate that the higher elevation areas to the north and east of Montezuma Well are the groundwater recharge zones for Montezuma Well and most of the groundwater in this portion of the Verde Valley. Adjusted groundwater age dating using likely 14C and δ13C sources indicate an age for Montezuma Well and Soda Springs groundwaters at 5,400–13,300 years, while shallow groundwater in the Verde Formation appears to be older (18,900). Based on water chemistry and isotopic evidence, groundwater flow to Montezuma Well is consistent with a hydrogeologic framework that indicates groundwater flow by (1) recharge in higher elevation basalts to the north and east of Montezuma Well, (2) movement through the upgradient Permian and Mississippian units, especially the Redwall Limestone, and (3) contact with a basalt dike/fracture system that provides a mechanism for groundwater to flow to the surface. While the exact nature of the groundwater flow connections is still uncertain, the available data indicate that flow to Montezuma Well may be more susceptible to future groundwater development in the Redwall Limestone than from any other geologic unit. Overall, the shallow groundwater in the surrounding Verde Formation appears to be largely disconnected from deeper groundwater flowing to Montezuma Well.