Science.gov

Sample records for global potential energy

  1. Representing Global Reactive Potential Energy Surfaces Using Gaussian Processes.

    PubMed

    Kolb, Brian; Marshall, Paul; Zhao, Bin; Jiang, Bin; Guo, Hua

    2017-04-06

    Representation of multidimensional global potential energy surfaces suitable for spectral and dynamical calculations from high-level ab initio calculations remains a challenge. Here, we present a detailed study on constructing potential energy surfaces using a machine learning method, namely, Gaussian process regression. Tests for the (3)A″ state of SH2, which facilitates the SH + H ↔ S((3)P) + H2 abstraction reaction and the SH + H' ↔ SH' + H exchange reaction, suggest that the Gaussian process is capable of providing a reasonable potential energy surface with a small number (∼1 × 10(2)) of ab initio points, but it needs substantially more points (∼1 × 10(3)) to converge reaction probabilities. The implications of these observations for construction of potential energy surfaces are discussed.

  2. Global Onshore Wind Energy Potential and Its Uncertainties

    NASA Astrophysics Data System (ADS)

    Zhou, Y.; Clarke, L.; Luckow, P.; Smith, S.

    2011-12-01

    Wind power, a clean and renewable energy resource, can play an important role in providing energy and reducing greenhouse gas emissions. Yet there are substantial and important uncertainties about the potential costs and supplies of wind that influence our ability to understand today the strategic role of wind power in the future. A detailed global assessment of onshore wind energy potential and its uncertainties will help decision-makers develop policies and strategies to meet energy and environmental goals. In this study, we assess the technical and economic potential of onshore wind energy and its spatial distribution using reanalysis wind speed data from the National Centers for Environmental Modeling (Figure 1). The study focuses in particular in exploring a range of uncertainties that impact the economic potential of wind power by constructing quantitative scenarios for eight key physical and economic parameters. We present quantification of the impact of uncertainties in these parameters, focusing on areas relevant to geoscience research (Figure 2). The amount of economic potential of wind energy depends strongly on several uncertain parameters such as wind speed, turbine cost, and land-suitability. The distribution of wind speed at fine temporal and spatial scales is a key parameter, but is not well quantified in many regions of the world. Reanalysis datasets with more accurate wind fields are a first step, along with computationally tractable downscaling methodologies. Another key assumption is land-suitability, which is the fraction of a particular land-cover type assumed to be available for wind farm development. There is currently little scientific basis for land-suitability assumptions. While some of the data needed for progress in these areas is readily available, such as high-resolution land-cover and terrain data, further advances are likely to require new methodologies and inter-disciplinary collaboration. We outline a number of areas where further

  3. Global Potential of Energy Efficiency Standards and Labeling Programs

    SciTech Connect

    McNeil, Michael A; McNeil, Michael A.; Letschert, Virginie; de la Rue du Can, Stephane

    2008-06-15

    This report estimates the global potential reductions in greenhouse gas emissions by 2030 for energy efficiency improvements associated with equipment (appliances, lighting, and HVAC) in buildings by means of energy efficiency standards and labels (EES&L). A consensus has emerged among the world's scientists and many corporate and political leaders regarding the need to address the threat of climate change through emissions mitigation and adaptation. A further consensus has emerged that a central component of these strategies must be focused around energy, which is the primary generator of greenhouse gas emissions. Two important questions result from this consensus: 'what kinds of policies encourage the appropriate transformation to energy efficiency' and 'how much impact can these policies have'? This report aims to contribute to the dialogue surrounding these issues by considering the potential impacts of a single policy type, applied on a global scale. The policy addressed in this report is Energy Efficient Standards and Labeling (EES&L) for energy-consuming equipment, which has now been implemented in over 60 countries. Mandatory energy performance standards are important because they contribute positively to a nation's economy and provide relative certainty about the outcome (both timing and magnitudes). Labels also contribute positively to a nation's economy and importantly increase the awareness of the energy-consuming public. Other policies not analyzed here (utility incentives, tax credits) are complimentary to standards and labels and also contribute in significant ways to reducing greenhouse gas emissions. We believe the analysis reported here to be the first systematic attempt to evaluate the potential of savings from EES&L for all countries and for such a large set of products. The goal of the analysis is to provide an assessment that is sufficiently well-quantified and accurate to allow comparison and integration with other strategies under

  4. Global interior eddy available potential energy diagnosed from Argo floats

    NASA Astrophysics Data System (ADS)

    Roullet, Guillaume; Capet, Xavier; Maze, Guillaume

    2014-03-01

    By combining all Argo profiles for the period 2002 to present, a cumulative density function is constructed on a 3-D grid of the global ocean. This function quantifies the statistics of isopycnals: time-averaged density, root-mean square of isopycnal displacement, and eddy available potential energy (EAPE). EAPE is the analogue of the eddy kinetic energy, but for the potential energy reservoir. Because it is essentially tied to the spatial structure and magnitude of mesoscale activity, EAPE is an important quantity that should be useful to evaluate eddy resolving/permitting model turbulence and circulation. Among other striking features are the turbulent behavior of Pacific and southern Atlantic Tsuchiya jets and subsurface EAPE maxima in some parts of the ocean, particularly in the Southern Ocean.

  5. Assessment of Global Wind Energy Resource Utilization Potential

    NASA Astrophysics Data System (ADS)

    Ma, M.; He, B.; Guan, Y.; Zhang, H.; Song, S.

    2017-09-01

    Development of wind energy resource (WER) is a key to deal with climate change and energy structure adjustment. A crucial issue is to obtain the distribution and variability of WER, and mine the suitable location to exploit it. In this paper, a multicriteria evaluation (MCE) model is constructed by integrating resource richness and stability, utilization value and trend of resource, natural environment with weights. The global resource richness is assessed through wind power density (WPD) and multi-level wind speed. The utilizable value of resource is assessed by the frequency of effective wind. The resource stability is assessed by the coefficient of variation of WPD and the frequency of prevailing wind direction. Regression slope of long time series WPD is used to assess the trend of WER. All of the resource evaluation indicators are derived from the atmospheric reanalysis data ERA-Interim with spatial resolution 0.125°. The natural environment factors mainly refer to slope and land-use suitability, which are derived from multi-resolution terrain elevation data 2010 (GMTED 2010) and GlobalCover2009. Besides, the global WER utilization potential map is produced, which shows most high potential regions are located in north of Africa. Additionally, by verifying that 22.22 % and 48.8 9% operational wind farms fall on medium-high and high potential regions respectively, the result can provide a basis for the macroscopic siting of wind farm.

  6. Evaluation of global onshore wind energy potential and generation costs.

    PubMed

    Zhou, Yuyu; Luckow, Patrick; Smith, Steven J; Clarke, Leon

    2012-07-17

    In this study, we develop an updated global estimate of onshore wind energy potential using reanalysis wind speed data, along with updated wind turbine technology performance, land suitability factors, cost assumptions, and explicit consideration of transmission distance in the calculation of transmission costs. We find that wind has the potential to supply a significant portion of the world energy needs, although this potential varies substantially by region and with assumptions such as on what types of land can be used to site wind farms. Total global economic wind potential under central assumptions, that is, intermediate between optimistic and pessimistic, is estimated to be approximately 119.5 petawatt hours per year (13.6 TW) at less than 9 cents/kWh. A sensitivity analysis of eight key parameters is presented. Wind potential is sensitive to a number of input parameters, particularly wind speed (varying by -70% to +450% at less than 9 cents/kWh), land suitability (by -55% to +25%), turbine density (by -60% to +80%), and cost and financing options (by -20% to +200%), many of which have important policy implications. As a result of sensitivities studied here we suggest that further research intended to inform wind supply curve development focus not purely on physical science, such as better resolved wind maps, but also on these less well-defined factors, such as land-suitability, that will also have an impact on the long-term role of wind power.

  7. Potential Global Benefits of Improved Ceiling Fan Energy Efficiency

    SciTech Connect

    Sathaye, Nakul; Phadke, Amol; Shah, Nihar; Letschert, Virginie

    2012-10-31

    Ceiling fans contribute significantly to residential electricity consumption, both in an absolute sense and as a proportion of household consumption in many locations, especially in developing countries in warm climates. However, there has been little detailed assessment of the costs and benefits of efficiency improvement options for ceiling fans and the potential resulting electricity consumption and greenhouse gas (GHG) emissions reductions. We analyze the costs and benefits of several options to improve the efficiency of ceiling fans and assess the global potential for electricity savings and GHG emission reductions with more detailed assessments for India, China, and the U.S. We find that ceiling fan efficiency can be cost-effectively improved by at least 50% using commercially available technology. If these efficiency improvements are implemented in all ceiling fans sold by 2020, 70 terrawatt hours per year (TWh/year) could be saved and 25 million metric tons of carbon dioxide (CO2) emissions per year could be avoided, globally. We assess how policies and programs such as standards, labels, and financial incentives can be used to accelerate the adoption of efficient ceiling fans in order to realize this savings potential.

  8. A global potential energy surface for ArH2

    NASA Technical Reports Server (NTRS)

    Schwenke, David W.; Walch, Stephen P.; Taylor, Peter R.

    1993-01-01

    We describe a simple analytic representation of the ArH2 potential energy surface which well reproduces the results of extensive ab initio electronic structure calculations. The analytic representation smoothly interpolates between the dissociated H2 and strong bonding limits. In the fitting process, emphasis is made on accurately reproducing regions of the potential expected to be important for high temperature (ca. 3000 K) collision processes. Overall, the anisotropy and H2 bond length dependence of the analytic representation well reproduce the input data.

  9. A global potential energy surface for ArH2

    NASA Technical Reports Server (NTRS)

    Schwenke, David W.; Walch, Stephen P.; Taylor, Peter R.

    1992-01-01

    We describe a simple analytic representation of the ArH2 potential energy surface which well reproduces the results of extensive ab initio electronic structure calculations. The analytic representation smoothly interpolates between the dissociated H2 and strong bonding limits. In the fitting process, emphasis is made on accurately reproducing regions of the potential expected to be important for high temperature (ca. 3000 K) collision processes. Overall, the anisotropy and H2 bond length dependence of the analytic representation well reproduce the input data.

  10. A global potential energy surface for ArH2

    NASA Technical Reports Server (NTRS)

    Schwenke, David W.; Walch, Stephen P.; Taylor, Peter R.

    1993-01-01

    We describe a simple analytic representation of the ArH2 potential energy surface which well reproduces the results of extensive ab initio electronic structure calculations. The analytic representation smoothly interpolates between the dissociated H2 and strong bonding limits. In the fitting process, emphasis is made on accurately reproducing regions of the potential expected to be important for high temperature (ca. 3000 K) collision processes. Overall, the anisotropy and H2 bond length dependence of the analytic representation well reproduce the input data.

  11. Global Expression for Representing Diatomic Potential-Energy Curves

    NASA Technical Reports Server (NTRS)

    Ferrante, John; Schlosser, Herbert; Smith, John R.

    1991-01-01

    A three-parameter expression that gives an accurate fit to diatomic potential curves over the entire range of separation for charge transfers between 0 and 1. It is based on a generalization of the universal binding-energy relation of Smith et al. (1989) with a modification that describes the crossover from a partially ionic state to the neutral state at large separations. The expression is tested by comparison with first-principles calculations of the potential curves ranging from covalently bonded to ionically bonded. The expression is also used to calculate spectroscopic constants form a curve fit to the first-principles curves. A comparison is made with experimental values of the spectroscopic constants.

  12. Global Expression for Representing Diatomic Potential-Energy Curves

    NASA Technical Reports Server (NTRS)

    Ferrante, John; Schlosser, Herbert; Smith, John R.

    1991-01-01

    A three-parameter expression that gives an accurate fit to diatomic potential curves over the entire range of separation for charge transfers between 0 and 1. It is based on a generalization of the universal binding-energy relation of Smith et al. (1989) with a modification that describes the crossover from a partially ionic state to the neutral state at large separations. The expression is tested by comparison with first-principles calculations of the potential curves ranging from covalently bonded to ionically bonded. The expression is also used to calculate spectroscopic constants form a curve fit to the first-principles curves. A comparison is made with experimental values of the spectroscopic constants.

  13. Global potential energy hypersurface for dynamical studies of energy transfer in HF--HF collisions

    SciTech Connect

    Redmon, M.J.; Binkley, J.S.

    1987-07-15

    The interaction energy of two HF molecules at 1332 individual points has been calculated with Moeller--Plesset (many--body) perturbation theory at the MP4-SDTQ level using a 6-311G** basis set. 293 of the points correspond to stretching of one HF molecule from its equilibrium geometry. No attempt was made to use a sufficiently fine grid to accurately describe the well region corresponding to hydrogen bonding. However, the location and minimum energy are consistent with experiment and other accurate theoretical results. An extensive global fit (rms error of 1 kcal/mol) is reported of 1319 points (below 10 eV of potential energy) using a modified London potential with corrections obtained using polynomials through four-body interactions. A model electrostatic potential represents the long-range interaction. In addition, the use of an expansion in products of three Legendre functions is discussed. It is shown that the latter approach, although accurately fitting the ab initio data, has difficulties interpolating in regions of the surface exhibiting diverse magnitudes of potential energy, and therefore must be used with caution. This surface should be useful for studies of T--V--R processes in this system.

  14. The global technical potential of bio-energy in 2050 considering sustainability constraints.

    PubMed

    Haberl, Helmut; Beringer, Tim; Bhattacharya, Sribas C; Erb, Karl-Heinz; Hoogwijk, Monique

    2010-12-01

    Bio-energy, that is, energy produced from organic non-fossil material of biological origin, is promoted as a substitute for non-renewable (e.g., fossil) energy to reduce greenhouse gas (GHG) emissions and dependency on energy imports. At present, global bio-energy use amounts to approximately 50 EJ/yr, about 10% of humanity's primary energy supply. We here review recent literature on the amount of bio-energy that could be supplied globally in 2050, given current expectations on technology, food demand and environmental targets ('technical potential'). Recent studies span a large range of global bio-energy potentials from ≈30 to over 1000 EJ/yr. In our opinion, the high end of the range is implausible because of (1) overestimation of the area available for bio-energy crops due to insufficient consideration of constraints (e.g., area for food, feed or nature conservation) and (2) too high yield expectations resulting from extrapolation of plot-based studies to large, less productive areas. According to this review, the global technical primary bio-energy potential in 2050 is in the range of 160-270 EJ/yr if sustainability criteria are considered. The potential of bio-energy crops is at the lower end of previously published ranges, while residues from food production and forestry could provide significant amounts of energy based on an integrated optimization ('cascade utilization') of biomass flows.

  15. The global technical potential of bio-energy in 2050 considering sustainability constraints

    PubMed Central

    Haberl, Helmut; Beringer, Tim; Bhattacharya, Sribas C; Erb, Karl-Heinz; Hoogwijk, Monique

    2010-01-01

    Bio-energy, that is, energy produced from organic non-fossil material of biological origin, is promoted as a substitute for non-renewable (e.g., fossil) energy to reduce greenhouse gas (GHG) emissions and dependency on energy imports. At present, global bio-energy use amounts to approximately 50 EJ/yr, about 10% of humanity's primary energy supply. We here review recent literature on the amount of bio-energy that could be supplied globally in 2050, given current expectations on technology, food demand and environmental targets (‘technical potential’). Recent studies span a large range of global bio-energy potentials from ≈30 to over 1000 EJ/yr. In our opinion, the high end of the range is implausible because of (1) overestimation of the area available for bio-energy crops due to insufficient consideration of constraints (e.g., area for food, feed or nature conservation) and (2) too high yield expectations resulting from extrapolation of plot-based studies to large, less productive areas. According to this review, the global technical primary bio-energy potential in 2050 is in the range of 160–270 EJ/yr if sustainability criteria are considered. The potential of bio-energy crops is at the lower end of previously published ranges, while residues from food production and forestry could provide significant amounts of energy based on an integrated optimization (‘cascade utilization’) of biomass flows. PMID:24069093

  16. Quantum Dynamics of Vinylidene Photodetachment on an Accurate Global Acetylene-Vinylidene Potential Energy Surface.

    PubMed

    Guo, Lifen; Han, Huixian; Ma, Jianyi; Guo, Hua

    2015-08-06

    Vinylidene is a high-energy isomer of acetylene, and the rearrangement of bonds in the two species serves as a prototype for isomerization reactions. Here, a full-dimensional quantum mechanical study of the vinylidene vibration is carried out on a recently developed global acetylene-vinylidene potential energy surface by simulating the photodetachment dynamics of the vinylidene anion. Several low-lying vibrational levels of the anion were first determined on a new ab initio based potential energy surface, and their photoelectron spectra were obtained within the Condon approximation. The vibrational features of the vinylidene isomer are found to agree well with the experiment in both positions and intensities, validating the global acetylene-vinylidene potential energy surface.

  17. The PyPES library of high quality semi-global potential energy surfaces.

    PubMed

    Sibaev, Marat; Crittenden, Deborah L

    2015-11-05

    In this article, we present a Python-based library of high quality semi-global potential energy surfaces for 50 polyatomic molecules with up to six atoms. We anticipate that these surfaces will find widespread application in the testing of new potential energy surface construction algorithms and nuclear ro-vibrational structure theories. To this end, we provide the ability to generate the energy derivatives required for Taylor series expansions to sixth order about any point on the potential energy surface in a range of common coordinate systems, including curvilinear internal, Cartesian, and normal mode coordinates. The PyPES package, along with FORTRAN, C, MATLAB and Mathematica wrappers, is available at http://sourceforge.net/projects/pypes-lib.

  18. Prediction of Protein Structure by Ab Initio Global Optimization of Potential Energy

    NASA Astrophysics Data System (ADS)

    Scheraga, Harold; Liwo, Adam; Pillardy, Jarek; Czaplewski, Czarek; Lee, Jooyoung; Ripoll, Daniel; Kazmierkiewicz, Rajmund; Oldziej, Stanislaw; Arnautova, Yelena; Wedemeyer, William; Saunders, Jeff

    2002-03-01

    A hierarchical ab initio method is used to predict the three-dimensional structures of globular proteins. The protein is described initially as a virtual-bond chain, with its side chains represented as ellipsoids. After searching the conformational space with this united-residue (UNRES) model, with many-body interactions, the UNRES model is converted to an all-atom model, and the global optimization of the potential energy is continued with the ECEPP/3 force field and the SRFOPT hydration free-energy. Results of the application of this methodology in the CASP3 and CASP4 exercises, and more-recent methodological improvements, will be presented.

  19. Generation of available potential energy and the energy cycle during the global weather experiment

    NASA Technical Reports Server (NTRS)

    Salstein, D. A.; Rosen, R. D.

    1985-01-01

    Two parallel sets of analyses, which in one case included and in the other omitted data observed by satellite based and other FGGE special observing systems are examined. The results of our previous work is extended in two separate, but not unrelated, ways. First, from these two parallel analyses, which are labeled FGGE (full FGGE system) and NOSAT (satellite omitted), it was discovered that the two sets of fields were quite close over much of the globe. Locally the influence of satellite based systems led to some differences, particularly over the Southern Hemisphere Oceans. The diabatic heating fields generated by the GLA FGGE analysis was also examined. From these fields, one can ascertain the role of total diabatic heating and of the various diabatic heating components in the atmospheric energy cycle, in particular in the generation of available potential energy.

  20. Accelerating the search for global minima on potential energy surfaces using machine learning

    NASA Astrophysics Data System (ADS)

    Carr, S. F.; Garnett, R.; Lo, C. S.

    2016-10-01

    Controlling molecule-surface interactions is key for chemical applications ranging from catalysis to gas sensing. We present a framework for accelerating the search for the global minimum on potential surfaces, corresponding to stable adsorbate-surface structures. We present a technique using Bayesian inference that enables us to predict converged density functional theory potential energies with fewer self-consistent field iterations. We then discuss how this technique fits in with the Bayesian Active Site Calculator, which applies Bayesian optimization to the problem. We demonstrate the performance of our framework using a hematite (Fe2O3) surface and present the adsorption sites found by our global optimization method for various simple hydrocarbons on the rutile TiO2 (110) surface.

  1. Generation of available potential energy and the energy cycle during the global weather experiment

    NASA Technical Reports Server (NTRS)

    Salstein, D. A.; Rosen, R. D.

    1986-01-01

    Two major themes were pursued during this research period. The first of these involved examining the impacts of satellite-based data and the forecast model used by the Goddard Laboratory for Atmospheres (GLA) on general circulation statistics. For the other major topic, the diabatic heating fields produced by GLA were examined for one month during the FGGE First Special Observing Period. As part of that effort, the three-dimensional distribution of the four component heating fields were studied, namely those due to shortwave radiation, Q sub SW, longwave radiation, Q sub LW, sensible heating, Q sub S, and latent heating, Q sub L. These components were calculated as part of the GLA analysis/forecast system and archived every quarter day; from these archives cross products with temperature were computed to enable the direct calculation of certain terms of the large-scale atmospheric energy cycle, namely those involving the generation of available potential energy (APE). The decision to archive the diabatic heating components separately has enabled researchers to study the role of the various processes that drive the energy cycle of the atmosphere.

  2. Global typology of urban energy use and potentials for an urbanization mitigation wedge

    PubMed Central

    Creutzig, Felix; Baiocchi, Giovanni; Bierkandt, Robert; Pichler, Peter-Paul; Seto, Karen C.

    2015-01-01

    The aggregate potential for urban mitigation of global climate change is insufficiently understood. Our analysis, using a dataset of 274 cities representing all city sizes and regions worldwide, demonstrates that economic activity, transport costs, geographic factors, and urban form explain 37% of urban direct energy use and 88% of urban transport energy use. If current trends in urban expansion continue, urban energy use will increase more than threefold, from 240 EJ in 2005 to 730 EJ in 2050. Our model shows that urban planning and transport policies can limit the future increase in urban energy use to 540 EJ in 2050 and contribute to mitigating climate change. However, effective policies for reducing urban greenhouse gas emissions differ with city type. The results show that, for affluent and mature cities, higher gasoline prices combined with compact urban form can result in savings in both residential and transport energy use. In contrast, for developing-country cities with emerging or nascent infrastructures, compact urban form, and transport planning can encourage higher population densities and subsequently avoid lock-in of high carbon emission patterns for travel. The results underscore a significant potential urbanization wedge for reducing energy use in rapidly urbanizing Asia, Africa, and the Middle East. PMID:25583508

  3. Global typology of urban energy use and potentials for an urbanization mitigation wedge.

    PubMed

    Creutzig, Felix; Baiocchi, Giovanni; Bierkandt, Robert; Pichler, Peter-Paul; Seto, Karen C

    2015-05-19

    The aggregate potential for urban mitigation of global climate change is insufficiently understood. Our analysis, using a dataset of 274 cities representing all city sizes and regions worldwide, demonstrates that economic activity, transport costs, geographic factors, and urban form explain 37% of urban direct energy use and 88% of urban transport energy use. If current trends in urban expansion continue, urban energy use will increase more than threefold, from 240 EJ in 2005 to 730 EJ in 2050. Our model shows that urban planning and transport policies can limit the future increase in urban energy use to 540 EJ in 2050 and contribute to mitigating climate change. However, effective policies for reducing urban greenhouse gas emissions differ with city type. The results show that, for affluent and mature cities, higher gasoline prices combined with compact urban form can result in savings in both residential and transport energy use. In contrast, for developing-country cities with emerging or nascent infrastructures, compact urban form, and transport planning can encourage higher population densities and subsequently avoid lock-in of high carbon emission patterns for travel. The results underscore a significant potential urbanization wedge for reducing energy use in rapidly urbanizing Asia, Africa, and the Middle East.

  4. Life-cycle energy demand and global warming potential of computational logic.

    PubMed

    Boyd, Sarah B; Horvath, Arpad; Dornfeld, David

    2009-10-01

    Computational logic, in the form of semiconductor chips of the complementary metal oxide semiconductor (CMOS) transistor structure, is used in personal computers, wireless devices, IT network infrastructure, and nearly all modem electronics. This study provides a life-cycle energy analysis for CMOS chips over 7 technology generations with the purpose of comparing energy demand and global warming potential (GWP) impacts of the life-cycle stages, examining trends in these impacts over time and evaluating their sensitivity to data uncertainty and changes in production metrics such as yield. A hybrid life-cycle assessment (LCA) model is used. While life-cycle energy and GWP of emissions have increased on the basis of a wafer or die, these impacts have been reducing per unit of computational power. Sensitivity analysis of the model shows that impacts have the highest relative sensitivity to wafer yield, line yield, and die size and largest absolute sensitivity to the use-phase power demand of the chip.

  5. A Global Analytical Representation of the Potential Energy Surface of the FHF(-) Anion.

    PubMed

    Cornaton, Yann; Marquardt, Roberto

    2016-08-04

    A global analytical representation of the potential energy hypersurface of the lowest adiabatic electronic state of the FHF(-) anion is derived from ab initio calculations at the coupled cluster level of theory with full single and double and perturbative triple excitations using explicitly correlated atomic basis functions. The new compact function of interatomic distances combines covalent short-range and long-range electrostatic interaction forms and assesses accurately both the lowest reaction channels between the F(-) and HF fragments, with reaction enthalpies to within 1 kJ mol(-1), as well as vibrational terms to within 1.5 cm(-1) deviation from experimental values.

  6. Comparing the Life Cycle Energy Consumption, Global Warming and Eutrophication Potentials of Several Water and Waste Service Options

    EPA Science Inventory

    Managing the water-energy-nutrient nexus for the built environment requires, in part, a full system analysis of energy consumption, global warming and eutrophication potentials of municipal water services. As an example, we evaluated the life cycle energy use, greenhouse gas (GHG...

  7. Comparing the Life Cycle Energy Consumption, GlobalWarming and Eutrophication Potentials of Several Water andWaste Service Options

    EPA Science Inventory

    Managing the water-energy-nutrient nexus for the built environment requires, in part, a full system analysis of energy consumption, global warming and eutrophication potentials of municipal water services. As an example, we evaluated the life cycle energy use, greenhouse gas (GHG...

  8. Comparing the Life Cycle Energy Consumption, Global Warming and Eutrophication Potentials of Several Water and Waste Service Options

    EPA Science Inventory

    Managing the water-energy-nutrient nexus for the built environment requires, in part, a full system analysis of energy consumption, global warming and eutrophication potentials of municipal water services. As an example, we evaluated the life cycle energy use, greenhouse gas (GHG...

  9. Refrigeration Playbook: Natural Refrigerants; Selecting and Designing Energy-Efficient Commercial Refrigeration Systems That Use Low Global Warming Potential Refrigerants

    SciTech Connect

    Nelson, Caleb; Reis, Chuck; Nelson, Eric; Armer, James; Arthur, Rob; Heath, Richard; Rono, James; Hirsch, Adam; Doebber, Ian

    2015-03-01

    This report provides guidance for selecting and designing energy efficient commercial refrigeration systems using low global warming potential refrigerants. Refrigeration systems are generally the largest energy end use in a supermarket type building, often accounting for more than half of a building's energy consumption.

  10. Toward spectroscopically accurate global ab initio potential energy surface for the acetylene-vinylidene isomerization

    SciTech Connect

    Han, Huixian; Li, Anyang; Guo, Hua

    2014-12-28

    A new full-dimensional global potential energy surface (PES) for the acetylene-vinylidene isomerization on the ground (S{sub 0}) electronic state has been constructed by fitting ∼37 000 high-level ab initio points using the permutation invariant polynomial-neural network method with a root mean square error of 9.54 cm{sup −1}. The geometries and harmonic vibrational frequencies of acetylene, vinylidene, and all other stationary points (two distinct transition states and one secondary minimum in between) have been determined on this PES. Furthermore, acetylene vibrational energy levels have been calculated using the Lanczos algorithm with an exact (J = 0) Hamiltonian. The vibrational energies up to 12 700 cm{sup −1} above the zero-point energy are in excellent agreement with the experimentally derived effective Hamiltonians, suggesting that the PES is approaching spectroscopic accuracy. In addition, analyses of the wavefunctions confirm the experimentally observed emergence of the local bending and counter-rotational modes in the highly excited bending vibrational states. The reproduction of the experimentally derived effective Hamiltonians for highly excited bending states signals the coming of age for the ab initio based PES, which can now be trusted for studying the isomerization reaction.

  11. Protein structure prediction and potential energy landscape analysis using continuous global minimization

    SciTech Connect

    Dill, K.A.; Phillips, A.T.; Rosen, J.B.

    1997-12-01

    Proteins require specific three-dimensional conformations to function properly. These {open_quotes}native{close_quotes} conformations result primarily from intramolecular interactions between the atoms in the macromolecule, and also intermolecular interactions between the macromolecule and the surrounding solvent. Although the folding process can be quite complex, the instructions guiding this process are specified by the one-dimensional primary sequence of the protein or nucleic acid: external factors, such as helper (chaperone) proteins, present at the time of folding have no effect on the final state of the protein. Many denatured proteins spontaneously refold into functional conformations once denaturing conditions are removed. Indeed, the existence of a unique native conformation, in which residues distant in sequence but close in proximity exhibit a densely packed hydrophobic core, suggests that this three-dimensional structure is largely encoded within the sequential arrangement of these specific amino acids. In any case, the native structure is often the conformation at the global minimum energy. In addition to the unique native (minimum energy) structure, other less stable structures exist as well, each with a corresponding potential energy. These structures, in conjunction with the native structure, make up an energy landscape that can be used to characterize various aspects of the protein structure. 22 refs., 10 figs., 2 tabs.

  12. Potential Applications for Nuclear Energy besides Electricity Generation: AREVA Global Perspective of HTR Potential Market

    SciTech Connect

    Soutworth, Finis; Gauthier, Jean-Claude; Lecomte, Michel; Carre, Franck

    2007-07-01

    Energy supply is increasingly showing up as a major issue for electricity supply, transportation, settlement, and process heat industrial supply including hydrogen production. Nuclear power is part of the solution. For electricity supply, as exemplified in Finland and France, the EPR brings an immediate answer; HTR could bring another solution in some specific cases. For other supply, mostly heat, the HTR brings a solution inaccessible to conventional nuclear power plants for very high or even high temperature. As fossil fuels costs increase and efforts to avoid generation of Greenhouse gases are implemented, a market for nuclear generated process heat will develop. Following active developments in the 80's, HTR have been put on the back burner up to 5 years ago. Light water reactors are widely dominating the nuclear production field today. However, interest in the HTR technology was renewed in the past few years. Several commercial projects are actively promoted, most of them aiming at electricity production. ANTARES is today AREVA's response to the cogeneration market. It distinguishes itself from other concepts with its indirect cycle design powering a combined cycle power plant. Several reasons support this design choice, one of the most important of which is the design flexibility to adapt readily to combined heat and power applications. From the start, AREVA made the choice of such flexibility with the belief that the HTR market is not so much in competition with LWR in the sole electricity market but in the specific added value market of cogeneration and process heat. In view of the volatility of the costs of fossil fuels, AREVA's choice brings to the large industrial heat applications the fuel cost predictability of nuclear fuel with the efficiency of a high temperature heat source free of greenhouse gases emissions. The ANTARES module produces 600 MWth which can be split into the required process heat, the remaining power drives an adapted prorated

  13. Development of global medium-energy nucleon-nucleus optical model potentials

    SciTech Connect

    Madland, D.G.; Sierk, A.J.

    1997-08-01

    The authors report on the development of new global optical model potentials for nucleon-nucleus scattering at medium energies. Using both Schroedinger and Dirac scattering formalisms, the goal is to construct a physically realistic optical potential describing nucleon-nucleus elastic scattering observables for a projectile energy range of (perhaps) 20 meV to (perhaps) 2 GeV and a target mass range of 16 to 209, excluding regions of strong nuclear deformation. They use a phenomenological approach guided by conclusions from recent microscopic studies. The experimental database consists largely of proton-nucleus elastic differential cross sections, analyzing powers, spin-rotation functions, and total reaction cross sections, and neutron-nucleus total cross sections. They will use this database in a nonlinear least-squares adjustment of optical model parameters in both relativistic equivalent Schroedinger (including relativistic kinematics) and Dirac (second-order reduction) formalisms. Isospin will be introduced through the standard Lane model and a relativistic generalization of that model.

  14. Communication: An accurate global potential energy surface for the ground electronic state of ozone

    SciTech Connect

    Dawes, Richard E-mail: hguo@unm.edu; Lolur, Phalgun; Li, Anyang; Jiang, Bin; Guo, Hua E-mail: hguo@unm.edu

    2013-11-28

    We report a new full-dimensional and global potential energy surface (PES) for the O + O{sub 2} → O{sub 3} ozone forming reaction based on explicitly correlated multireference configuration interaction (MRCI-F12) data. It extends our previous [R. Dawes, P. Lolur, J. Ma, and H. Guo, J. Chem. Phys. 135, 081102 (2011)] dynamically weighted multistate MRCI calculations of the asymptotic region which showed the widely found submerged reef along the minimum energy path to be the spurious result of an avoided crossing with an excited state. A spin-orbit correction was added and the PES tends asymptotically to the recently developed long-range electrostatic model of Lepers et al. [J. Chem. Phys. 137, 234305 (2012)]. This PES features: (1) excellent equilibrium structural parameters, (2) good agreement with experimental vibrational levels, (3) accurate dissociation energy, and (4) most-notably, a transition region without a spurious reef. The new PES is expected to allow insight into the still unresolved issues surrounding the kinetics, dynamics, and isotope signature of ozone.

  15. The H(3) (+) rovibrational spectrum revisited with a global electronic potential energy surface.

    PubMed

    Velilla, Luis; Lepetit, Bruno; Aguado, Alfredo; Beswick, J Alberto; Paniagua, Miguel

    2008-08-28

    In this paper, we have computed the rovibrational spectrum of the H(3) (+) molecule using a new global potential energy surface, invariant under all permutations of the nuclei, that includes the long range electrostatic interactions analytically. The energy levels are obtained by a variational calculation using hyperspherical coordinates. From the comparison with available experimental results for low lying levels, we conclude that our accuracy is of the order of 0.1 cm(-1) for states localized in the vicinity of equilateral triangular configurations of the nuclei, and changes to the order of 1 cm(-1) when the system is distorted away from equilateral configurations. Full rovibrational spectra up to the H(+)+H(2) dissociation energy limit have been computed. The statistical properties of this spectrum (nearest neighbor distribution and spectral rigidity) show the quantum signature of classical chaos and are consistent with random matrix theory. On the other hand, the correlation function, even when convoluted with a smoothing function, exhibits oscillations which are not described by random matrix theory. We discuss a possible similarity between these oscillations and the ones observed experimentally.

  16. Forward and pressure retarded osmosis: potential solutions for global challenges in energy and water supply.

    PubMed

    Klaysom, Chalida; Cath, Tazhi Y; Depuydt, Tom; Vankelecom, Ivo F J

    2013-08-21

    Osmotically driven membrane processes (ODMP) have gained renewed interest in recent years and they might become a potential solution for the world's most challenging problems of water and energy scarcity. Though the concept of utilizing osmotic pressure difference between high and low salinity streams across semipermeable membranes has been explored for several decades, lack of optimal membranes and draw solutions hindered competition between forward osmosis (FO) and pressure retarded osmosis (PRO) with existing water purification and power generation technologies, respectively. Driven by growing global water scarcity and by energy cost and negative environmental impacts, novel membranes and draw solutions are being developed for ODMPs, mass and heat transfer in osmotic process are becoming better understood, and new applications of ODMPs are emerging. Therefore, OMDPs might become promising green technologies to provide clean water and clean energy from abundantly available renewable resources. This review focuses primarily on new insights into osmotic membrane transport mechanisms and on novel membranes and draw solutions that are currently being developed. Furthermore, the effects of operating conditions on the overall performance of osmotic membranes will be highlighted and future perspectives will be presented.

  17. An accurate global potential energy surface, dipole moment surface, and rovibrational frequencies for NH(3).

    PubMed

    Huang, Xinchuan; Schwenke, David W; Lee, Timothy J

    2008-12-07

    A global potential energy surface (PES) that includes short and long range terms has been determined for the NH(3) molecule. The singles and doubles coupled-cluster method that includes a perturbational estimate of connected triple excitations and the internally contracted averaged coupled-pair functional electronic structure methods have been used in conjunction with very large correlation-consistent basis sets, including diffuse functions. Extrapolation to the one-particle basis set limit was performed and core correlation and scalar relativistic contributions were included directly, while the diagonal Born-Oppenheimer correction was added. Our best purely ab initio PES, denoted "mixed," is constructed from two PESs which differ in whether the ic-ACPF higher-order correlation correction was added or not. Rovibrational transition energies computed from the mixed PES agree well with experiment and the best previous theoretical studies, but most importantly the quality does not deteriorate even up to 10 300 cm(-1) above the zero-point energy (ZPE). The mixed PES was improved further by empirical refinement using the most reliable J=0-2 rovibrational transitions in the HITRAN 2004 database. Agreement between high-resolution experiment and rovibrational transition energies computed from our refined PES for J=0-6 is excellent. Indeed, the root mean square (rms) error for 13 HITRAN 2004 bands for J=0-2 is 0.023 cm(-1) and that for each band is always energies computed with our refined PES should be useful in the assignment of new high-resolution NH(3) spectra and in correcting mistakes in previous assignments. Ideas for further improvements to our refined PES and for extension to other isotopolog are discussed.

  18. A global potential energy surface for the H2 + OH ↔ H2O + H reaction using neural networks.

    PubMed

    Chen, Jun; Xu, Xin; Xu, Xin; Zhang, Dong H

    2013-04-21

    A global potential energy surface for the H2 + OH ↔ H2O + H reaction has been constructed using the neural networks method based on ~17,000 ab initio energies calculated at UCCSD(T)-F12a/AVTZ level of theory. Time-dependent wave packet calculations showed that the new potential energy surface is very well converged with respect to the number of ab initio data points, as well as to the fitting process. Various tests revealed that the new surface is considerably more smooth and accurate than the existing YZCL2 and XXZ surfaces, representing the best available potential energy surface for the benchmark four-atom system. Equally importantly, the number of ab initio energies required to obtain the well converged potential energy surface is rather limited, indicating the neural network fitting is a powerful method to construct accurate potential energy surfaces for polyatomic reactions.

  19. Assessing the global potential and regional implications of promoting bio-energy

    EPA Science Inventory

    There is no simple answer to the question “are materials from bio-based feedstocks environmentally, and socially, preferable?” Bioenergy as an alternative energy source might be effective in reducing fossil fuel use, slowing global warming effects, and providing increased revenue...

  20. Assessing the global potential and regional implications of promoting bio-energy

    EPA Science Inventory

    There is no simple answer to the question “are materials from bio-based feedstocks environmentally, and socially, preferable?” Bioenergy as an alternative energy source might be effective in reducing fossil fuel use, slowing global warming effects, and providing increased revenue...

  1. Accurate high level ab initio-based global potential energy surface and dynamics calculations for ground state of CH2(+).

    PubMed

    Li, Y Q; Zhang, P Y; Han, K L

    2015-03-28

    A global many-body expansion potential energy surface is reported for the electronic ground state of CH2 (+) by fitting high level ab initio energies calculated at the multireference configuration interaction level with the aug-cc-pV6Z basis set. The topographical features of the new global potential energy surface are examined in detail and found to be in good agreement with those calculated directly from the raw ab initio energies, as well as previous calculations available in the literature. In turn, in order to validate the potential energy surface, a test theoretical study of the reaction CH(+)(X(1)Σ(+))+H((2)S)→C(+)((2)P)+H2(X(1)Σg (+)) has been carried out with the method of time dependent wavepacket on the title potential energy surface. The total integral cross sections and the rate coefficients have been calculated; the results determined that the new potential energy surface can both be recommended for dynamics studies of any type and as building blocks for constructing the potential energy surfaces of larger C(+)/H containing systems.

  2. Conceptional Considerations to Energy Balance and Global Warming Potential of Soil Bioengineering Structures

    NASA Astrophysics Data System (ADS)

    von der Thannen, Magdalena; Paratscha, Roman; Smutny, Roman; Lampalzer, Thomas; Strauss, Alfred; Rauch, Hans Peter

    2016-04-01

    Nowadays there is a high demand on engineering solutions considering not only technical aspects but also ecological and aesthetic values. In this context soil bioengineering techniques are often used as standalone solutions or in combination with conventional engineering structures. It is a construction technique that uses biological components for hydraulic and civil engineering solutions. In general it pursues the same objectives as conventional civil engineering structures. Currently the used assessment methods for soil bioengineering structures are referencing technically, ecologically and socio-economically. In a modern engineering approach additionally, environmental impacts and potential added values should be considered. The research project E-Protect aims at developing Environmental Life Cycle Assessment (LCA) models for this special field of alpine protective constructions. Both, the Cumulative Energy Demand (CED) and the Global Warming Potential (GWP) should be considered in an Environmental LCA over the whole life cycle of an engineering structure. The life cycle itself can be divided into three phases: the construction phase, the use phase and the end of life phase. The paper represents a concept to apply an Environmental LCA model for soil bioengineering structures. Beside the construction phase of these structures particular attention will be given to the use phase. It is not only important in terms of engineering effects but also plays an important role for positive carbon footprint due to the growing plants of soil bioengineering structures in contrast to conventional structures. Innovative Environmental LCA models will be applied to soil bioengineering structures which provide a new transparency for the responsible planners and stakeholders, by pointing out the total consumption of resources in all construction phases and components.

  3. Global Energy Futures Model

    SciTech Connect

    Malczynski, Leonard; Baker, Arnold; Beyeler, Walt; Conrad, Stephen; Harris, David; Harris, Paul; Rexroth, Paul; Bixler, and Nathan

    2004-01-01

    The Global Energy Futures Model (GEFM) is a demand-based, gross domestic product (GDP)-driven, dynamic simulation tool that provides an integrated framework to model key aspects of energy, nuclear-materials storage and disposition, environmental effluents from fossil and non fossil energy and global nuclear-materials management. Based entirely on public source data, it links oil, natural gas, coal, nuclear and renewable energy dynamically to greenhouse-gas emissions and 13 other measures of environmental impact. It includes historical data from 1990 to 2000, is benchmarked to the DOE/EIA/IEO 2002 [5] Reference Case for 2000 to 2020, and extrapolates energy demand through the year 2050. The GEFM is globally integrated, and breaks out five regions of the world: United States of America (USA), the Peoples Republic of China (China), the former Soviet Union (FSU), the Organization for Economic Cooperation and Development (OECD) nations excluding the USA (other industrialized countries), and the rest of the world (ROW) (essentially the developing world). The GEFM allows the user to examine a very wide range of what ir scenarios through 2050 and to view the potential effects across widely dispersed, but interrelated areas. The authors believe that this high-level learning tool will help to stimulate public policy debate on energy, environment, economic and national security issues.

  4. Global and Regional Future Potential for Energy from Municipal Solid Waste

    NASA Astrophysics Data System (ADS)

    Gregg, J. S.; Smith, S. J.

    2008-12-01

    Municipal Solid Waste (MSW) is a low-cost form of alternative energy with a large potential for future expansion. MSW is already collected and aggregated at population centers where energy demands are high. In addition, it is non-seasonal, and using MSW as an energy source reduces land demand for waste disposal sites in urban areas where land pressures are high. Across the world, the MSW generation rate and its composition vary greatly, but detailed historical data on MSW are not well archived for most of the world. In this study, material flows into the MSW stream are estimated by analyzing production and trade statistics of food, wood, and paper. A life cycle analysis for consumption is used to estimate the amount and composition of MSW for all countries of the world. The primary energy available is estimated based on the energy content of the various waste components. The relationship between GDP, population, per capita GDP, and MSW generation is determined via a regression model. The ObjECTS MiniCAM (integrated assessment model) is used to project the demand for waste-to-energy for the next century for different regions of the world under various international climate policy scenarios. MSW is potentially a low net carbon energy source that can displace fossil energy, and as such, demand for waste-to-energy increases under a climate policy that places a price on carbon emissions.

  5. Contribution of gravitational potential energy differences to the global stress field

    NASA Astrophysics Data System (ADS)

    Ghosh, Attreyee; Holt, William E.; Flesch, Lucy M.

    2009-11-01

    Modelling the lithospheric stress field has proved to be an efficient means of determining the role of lithospheric versus sublithospheric buoyancies and also of constraining the driving forces behind plate tectonics. Both these sources of buoyancies are important in generating the lithospheric stress field. However, these sources and the contribution that they make are dependent on a number of variables, such as the role of lateral strength variation in the lithosphere, the reference level for computing the gravitational potential energy per unit area (GPE) of the lithosphere, and even the definition of deviatoric stress. For the mantle contribution, much depends on the mantle convection model, including the role of lateral and radial viscosity variations, the spatial distribution of density buoyancies, and the resolution of the convection model. GPE differences are influenced by both lithosphere density buoyancies and by radial basal tractions that produce dynamic topography. The global lithospheric stress field can thus be divided into (1) stresses associated with GPE differences (including the contribution from radial basal tractions) and (2) stresses associated with the contribution of horizontal basal tractions. In this paper, we investigate only the contribution of GPE differences, both with and without the inferred contribution of radial basal tractions. We use the Crust 2.0 model to compute GPE values and show that these GPE differences are not sufficient alone to match all the directions and relative magnitudes of principal strain rate axes, as inferred from the comparison of our depth integrated deviatoric stress tensor field with the velocity gradient tensor field within the Earth's plate boundary zones. We argue that GPE differences calibrate the absolute magnitudes of depth integrated deviatoric stresses within the lithosphere; shortcomings of this contribution in matching the stress indicators within the plate boundary zones can be corrected by

  6. Global Dynamics Above the First Excited Energy for the Nonlinear Schrödinger Equation with a Potential

    NASA Astrophysics Data System (ADS)

    Nakanishi, Kenji

    2017-08-01

    Consider the focusing nonlinear Schrödinger equation with a potential with a single negative eigenvalue. It has solitons with negative small energy, which are asymptotically stable, and solitons with positive large energy, which are unstable. We classify the global dynamics into nine sets of solutions in the phase space including both solitons, restricted by small mass, radial symmetry, and an energy bound slightly above the second lowest one of solitons. The classification includes a stable set of solutions which start near the first excited solitons, approach the ground states locally in space for large time with large radiation to the spatial infinity, and blow up in negative finite time.

  7. (Global energy development)

    SciTech Connect

    Trivelpiece, A.W.; Fulkerson, W.

    1989-11-21

    This is the report of foreign travel by Alvin W. Trivelpiece and William Fulkerson who were part of a US delegation of ten individuals who visited the Soviet Union for two weeks as part of a joint activity between the US National Academy of Sciences (NAS) and the Academy of Sciences (AS) of the USSR. Trivelpiece headed the US delegation. The trip was sponsored by the NAS under a grant from the MacArthur Foundation. It consisted of three parts: (1) a tour of energy facilities and laboratories in Siberia, including the cities of Novosibirsk, Krasnoyarsk, Nazarovo, Achinsk, Bratsk, and Irkutsk; (2) a joint seminar in Moscow called Global Energy Development and Associated Ecological (Environmental) Impacts''; and (3) a workshop to discuss areas of potential future collaboration and cooperation. A Memorandum of Record was signed on the final day. It recommended that the Presidents of the two Academies establish a joint committee for ...coordinating, recommending, and encouraging activities in accordance with this memorandum.'' Projects for possible collaboration were identified in the areas of energy data and models, global warming, technologies for more efficient use of energy, clean coal, gas turbines, tools for assessing environmental impacts, and analysis of approaches to energy decision making.

  8. A global ab initio potential for HCN/HNC, exact vibrational energies, and comparison to experiment

    NASA Technical Reports Server (NTRS)

    Bentley, Joseph A.; Bowman, Joel M.; Gazdy, Bela; Lee, Timothy J.; Dateo, Christopher E.

    1992-01-01

    An ab initio (i.e., from first principles) calculation of vibrational energies of HCN and HNC is reported. The vibrational calculations were done with a new potential derived from a fit to 1124 ab initio electronic energies which were calculated using the highly accurate CCSD(T) coupled-cluster method in conjunction with a large atomic natural orbital basis set. The properties of this potential are presented, and the vibrational calculations are compared to experiment for 54 vibrational transitions, 39 of which are for zero total angular momentum, J = 0, and 15 of which are for J = 1. The level of agreement with experiment is unprecedented for a triatomic with two nonhydrogen atoms, and demonstrates the capability of the latest computational methods to give reliable predictions on a strongly bound triatomic molecule at very high levels of vibrational excitation.

  9. The global energy system.

    PubMed

    Häfele, W; Sassin, W

    1979-05-01

    A global energy system is conceptualized and analyzed, the energy distributor sub-system of the worldwide supranational system. Its many interconnections are examined and traced back to their source to determine the major elements of this global energy system. Long-term trends are emphasized. The analysis begins with a discussion of the local systems that resulted from the deployment of technology in the mid-nineteenth century, continues with a description of the global system based on oil that has existed for the past two decades, and ends with a scenario implying that an energy transition will occur in the future in which use of coal, nuclear, and solar energy will predominate. A major problem for the future will be the management of this energy transition. The optimal use of global resources and the efficient management of this transition will require a stable and persistent global order.

  10. Available potential energy gain from mixing due to the nonlinearity of the equation of state in a global ocean model

    NASA Astrophysics Data System (ADS)

    Urakawa, L. S.; Saenz, J. A.; Hogg, A. M.

    2013-05-01

    Densification in the ocean interior upon mixing at high latitudes, due to the nonlinear equation of state (EoS) of seawater, enhances the meridional overturning circulation (MOC). However, recent calculations using numerical simulations of global ocean circulation have shown that the nonlinearity of the EoS leads to a sink of gravitational potential energy (PE), from which one might infer that there is less energy available to be released to the MOC. Here the available PE (APE) budget of the global ocean is investigated using a numerical model with a nonlinear EoS under a realistic configuration. The results show that, while the nonlinearity of the EoS leads to a loss of gravitational PE, it is a source of APE. For the model used in this study, nonlinearity of the EoS is as significant as surface buoyancy forcing in generating APE.

  11. A global potential energy surface and dipole moment surface for silane.

    PubMed

    Owens, Alec; Yurchenko, Sergei N; Yachmenev, Andrey; Thiel, Walter

    2015-12-28

    A new nine-dimensional potential energy surface (PES) and dipole moment surface (DMS) for silane have been generated using high-level ab initio theory. The PES, CBS-F12(HL), reproduces all four fundamental term values for (28)SiH4 with sub-wavenumber accuracy, resulting in an overall root-mean-square error of 0.63 cm(-1). The PES is based on explicitly correlated coupled cluster calculations with extrapolation to the complete basis set limit, and incorporates a range of higher-level additive energy corrections to account for core-valence electron correlation, higher-order coupled cluster terms, and scalar relativistic effects. Systematic errors in computed intra-band rotational energy levels are reduced by empirically refining the equilibrium geometry. The resultant Si-H bond length is in excellent agreement with previous experimental and theoretical values. Vibrational transition moments, absolute line intensities of the ν3 band, and the infrared spectrum for (28)SiH4 including states up to J = 20 and vibrational band origins up to 5000 cm(-1) are calculated and compared with available experimental results. The DMS tends to marginally overestimate the strength of line intensities. Despite this, band shape and structure across the spectrum are well reproduced and show good agreement with experiment. We thus recommend the PES and DMS for future use.

  12. A global potential energy surface and dipole moment surface for silane

    SciTech Connect

    Owens, Alec; Yurchenko, Sergei N.; Yachmenev, Andrey; Thiel, Walter

    2015-12-28

    A new nine-dimensional potential energy surface (PES) and dipole moment surface (DMS) for silane have been generated using high-level ab initio theory. The PES, CBS-F12{sup HL}, reproduces all four fundamental term values for {sup 28}SiH{sub 4} with sub-wavenumber accuracy, resulting in an overall root-mean-square error of 0.63 cm{sup −1}. The PES is based on explicitly correlated coupled cluster calculations with extrapolation to the complete basis set limit, and incorporates a range of higher-level additive energy corrections to account for core-valence electron correlation, higher-order coupled cluster terms, and scalar relativistic effects. Systematic errors in computed intra-band rotational energy levels are reduced by empirically refining the equilibrium geometry. The resultant Si–H bond length is in excellent agreement with previous experimental and theoretical values. Vibrational transition moments, absolute line intensities of the ν{sub 3} band, and the infrared spectrum for {sup 28}SiH{sub 4} including states up to J = 20 and vibrational band origins up to 5000 cm{sup −1} are calculated and compared with available experimental results. The DMS tends to marginally overestimate the strength of line intensities. Despite this, band shape and structure across the spectrum are well reproduced and show good agreement with experiment. We thus recommend the PES and DMS for future use.

  13. Nonsolar energy use and one-hundred-year global warming potential of Iowa swine feedstuffs and feeding strategies.

    PubMed

    Lammers, P J; Kenealy, M D; Kliebenstein, J B; Harmon, J D; Helmers, M J; Honeyman, M S

    2010-03-01

    Demand for nonsolar energy and concern about the implications of fossil fuel combustion have encouraged examination of energy use associated with agriculture. The United States is a global leader in pig production, and the United States swine industry is centered in Iowa. Feed is the largest individual input in pig production, but the energy consumption of the Iowa swine feed production chain has yet to be critically examined. This analysis examines nonsolar energy use and resulting 100-yr global warming potential (GWP) associated with the swine feed production chain, beginning with cultivation of crops and concluding with diet formulation. The nonsolar energy use and accompanying 100-yr GWP associated with production of 13 common swine feed ingredients are estimated. Two diet formulation strategies are considered for 4 crop sequence x ingredient choice combinations to generate 8 crop sequence x diet formulation scenarios. The first formulation strategy (simple) does not include synthetic AA or phytase. The second strategy (complex) reduces CP content of the diet by using L-lysine to meet standardized ileal digestibility lysine requirements of pigs and includes the exogenous enzyme phytase. Regardless of crop sequence x diet formulation scenario, including the enzyme phytase is energetically favorable and reduces the potential excretion of P by reducing or removing inorganic P from the complete diet. Including L-lysine reduces the CP content of the diet and requires less nonsolar energy to deliver adequate standardized ileal digestible lysine than simply feeding soybean meal. Replacing soybean meal with full-fat soybeans is not energetically beneficial under Iowa conditions. Swine diets including dried distillers grains with solubles and crude glycerol require approximately 50% more nonsolar energy inputs than corn-soybean meal diets or corn-soybean meal diets including oats. This study provides essential information on cultivation, processing, and manufacture of

  14. Potential global climate change

    SciTech Connect

    1994-09-01

    Global economic integration and growth contribute much to the construction of energy plants, vehicles and other industrial products that produces carbon emission and in effect cause the destruction of the environment. A coordinated policy and response worldwide to curb emissions and to effect global climate change must be introduced. Improvement in scientific understanding is required to monitor how much emission reduction is necessary. In the near term, especially in the next seven years, sustained research and development for low carbon or carbon-free energy is necessary. Other measures must also be introduced, such as limiting the use of vehicles, closing down inefficient power plants, etc. In the long term, the use of the electric car, use solar energy, etc. is required. Reforestation must also be considered to absorb large amounts of carbon in the atmosphere.

  15. The Global Energy Budget.

    ERIC Educational Resources Information Center

    Jax, Daniel W.

    1992-01-01

    Presents a lesson plan about greenhouse effect and global warming. Includes diagrams and graphs from which students are asked to make inferences. Provides background information about how energy enters and leaves the earth system, the energy budget, consequences of obstructing the energy balance, and the greenhouse effect. (three references) (MCO)

  16. The Global Energy Budget.

    ERIC Educational Resources Information Center

    Jax, Daniel W.

    1992-01-01

    Presents a lesson plan about greenhouse effect and global warming. Includes diagrams and graphs from which students are asked to make inferences. Provides background information about how energy enters and leaves the earth system, the energy budget, consequences of obstructing the energy balance, and the greenhouse effect. (three references) (MCO)

  17. The READY program: Building a global potential energy surface and reactive dynamic simulations for the hydrogen combustion.

    PubMed

    Mogo, César; Brandão, João

    2014-06-30

    READY (REActive DYnamics) is a program for studying reactive dynamic systems using a global potential energy surface (PES) built from previously existing PESs corresponding to each of the most important elementary reactions present in the system. We present an application to the combustion dynamics of a mixture of hydrogen and oxygen using accurate PESs for all the systems involving up to four oxygen and hydrogen atoms. Results at the temperature of 4000 K and pressure of 2 atm are presented and compared with model based on rate constants. Drawbacks and advantages of this approach are discussed and future directions of research are pointed out.

  18. Life Cycle Assessment of the Energy Independence and Security Act of 2007: Ethanol - Global Warming Potential and Environmental Emissions

    SciTech Connect

    Heath, G. A.; Hsu, D. D.; Inman, D.; Aden, A.; Mann, M. K.

    2009-07-01

    The objective of this study is to use life cycle assessment (LCA) to evaluate the global warming potential (GWP), water use, and net energy value (NEV) associated with the EISA-mandated 16 bgy cellulosic biofuels target, which is assumed in this study to be met by cellulosic-based ethanol, and the EISA-mandated 15 bgy conventional corn ethanol target. Specifically, this study compares, on a per-kilometer-driven basis, the GWP, water use, and NEV for the year 2022 for several biomass feedstocks.

  19. Global exploration of isomers and isomerization channels on the quantum chemical potential energy surface of H3 CNO3.

    PubMed

    Ohno, Koichi; Kishimoto, Naoki; Iwamoto, Takeaki; Satoh, Hiroko

    2017-04-15

    Global exploration of isomers and isomerization channels on the quantum chemical potential energy surface (PES) is performed for H3 CNO3 using the Scaled Hypersphere Search-Anharmonic Downward Distortion Following (SHS-ADDF) method. The molecular formula of H3 CNO3 includes functional groups of CH3 , OH, NH2 , COOH, NO, NO2 , and NO3 , which are very important in connection with amino acids and NOx. Geometrical structures and interconversion pathways are disclosed after 18719781 force calculations and 534726 Hessian calculations at the level of B3LYP/6-31G(d). The explored results are confirmed to be valid, especially for the important lower energy regions, by re-optimization at the higher level of B3LYP/6-311++G(d,p). A global reaction route-mapping using SHS-ADDF demonstrates the entire view and undeveloped landscapes on PES of H3 CNO3 . Typical compounds of H3 CNO3 , aminoxy formic acid, hydroxycarbamic acid, aminoperformic acid, hydroxymethyl nitrite, nitromethanol, methyl nitrate, methyl peroxynitrite, and dioxaziridine, are well separated from others by very high energy-barriers. The stable-most conformer of H3 CNO3 is difficult to be determined, because of seven structures existing with nearly the same energies within 5.7 kJ/mol at the level of CCSD(T)/aug-cc-pVTZ. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  20. The Global Energy Challenge

    ScienceCinema

    Crabtree, George

    2016-07-12

    The expected doubling of global energy demand by 2050 challenges our traditional patterns of energy production, distribution and use.   The continued use of fossil fuels raises concerns about supply, security, environment and climate.  New routes are needed for the efficient conversion of energy from chemical fuel, sunlight, and heat to electricity or hydrogen as an energy carrier and finally to end uses like transportation, lighting, and heating. Opportunities for efficient new energy conversion routes based on nanoscale materials will be presented, with emphasis on the sustainable energy technologies they enable.

  1. The distribution of eddy kinetic and potential energies in the global ocean

    NASA Astrophysics Data System (ADS)

    Ferrari, Raffaele; Wunsch, Carl

    2010-03-01

    Understanding of the major sources, sinks, and reservoirs of energy in the ocean is briefly updated in a diagram. The nature of the dominant kinetic energy reservoir, that of the balanced variablity, is then found to be indistinguishable in the observations from a sum of barotropic and first baroclinic ordinary quasi-geostrophic modes. Little supporting evidence is available to partition the spectra among forced motions and turbulent cascades, along with significant energy more consistent with weakly non-linear wave dynamics. Linear-response wind-forced motions appear to dominate the high frequency (but subinertial) mooring frequency spectra. Turbulent cascades appear to fill the high wavenumber spectra in altimetric data and numerical simulations. Progress on these issues is hindered by the difficulty in connecting the comparatively easily available frequency spectra with the variety of theoretically predicted wavenumber spectra.

  2. Coseismic changes of gravitational potential energy induced by global earthquakes based on spherical-Earth elastic dislocation theory

    NASA Astrophysics Data System (ADS)

    Xu, Changyi; Chao, B. Fong

    2017-05-01

    We compute the coseismic gravitational potential energy Eg change using the spherical-Earth elastic dislocation theory and either the fault model treated as a point source or the finite fault model. The rate of the accumulative Eg loss produced by historical earthquakes from 1976 to 2016 (about 42,000 events) using the Global Centroid Moment Tensor Solution catalogue is estimated to be on the order of -2.1 × 1020 J/a, or -6.7 TW (1 TW = 1012 W), amounting to 15% in the total terrestrial heat flow. The energy loss is dominated by the thrust faulting, especially the megathrust earthquakes such as the 2004 Sumatra earthquake (Mw 9.0) and the 2011 Tohoku-Oki earthquake (Mw 9.1). It is notable that the very deep focus events, the 1994 Bolivia earthquake (Mw 8.2) and the 2013 Okhotsk earthquake (Mw 8.3), produced significant overall coseismic Eg gain according to our calculation. The accumulative coseismic Eg is mainly lost in the mantle of the Earth and also lost in the core of the Earth but with a relatively smaller magnitude. By contrast, the crust of the Earth gains gravitational potential energy cumulatively because of the coseismic deformations. We further investigate the tectonic signature in the coseismic crustal Eg changes in some complex tectonic zone, such as Taiwan region and the northeastern margin of the Tibetan Plateau. We found that the coseismic Eg change is consistent with the regional tectonic character.

  3. A compact and accurate semi-global potential energy surface for malonaldehyde from constrained least squares regression

    SciTech Connect

    Mizukami, Wataru Tew, David P.; Habershon, Scott

    2014-10-14

    We present a new approach to semi-global potential energy surface fitting that uses the least absolute shrinkage and selection operator (LASSO) constrained least squares procedure to exploit an extremely flexible form for the potential function, while at the same time controlling the risk of overfitting and avoiding the introduction of unphysical features such as divergences or high-frequency oscillations. Drawing from a massively redundant set of overlapping distributed multi-dimensional Gaussian functions of inter-atomic separations we build a compact full-dimensional surface for malonaldehyde, fit to explicitly correlated coupled cluster CCSD(T)(F12*) energies with a root mean square deviations accuracy of 0.3%–0.5% up to 25 000 cm{sup −1} above equilibrium. Importance-sampled diffusion Monte Carlo calculations predict zero point energies for malonaldehyde and its deuterated isotopologue of 14 715.4(2) and 13 997.9(2) cm{sup −1} and hydrogen transfer tunnelling splittings of 21.0(4) and 3.2(4) cm{sup −1}, respectively, which are in excellent agreement with the experimental values of 21.583 and 2.915(4) cm{sup −1}.

  4. Ab Initio Vibrational Spectroscopy of cis- and trans-Formic Acid from a Global Potential Energy Surface.

    PubMed

    Tew, David P; Mizukami, Wataru

    2016-12-15

    A global analytic potential energy surface for the ro-vibrational dynamics of cis- and trans-formic acid is presented, constructed using LASSO-based regression to reproduce CCSD(T)(F12*)/cc-pVTZ-F12 energies. The fit is accurate to 0.25% has an RMS deviation from the ab initio data of 9 cm(-1) for the energy range 0-15000 cm(-1). Converged J = 0 vibrational eigenstates are reported, computed using vibrational configuration interaction with an internal coordinate path Hamiltonian for the torsional motion connecting the cis and trans rotamers. Methodological choices concerning the appropriate definitions of the curvilinear and diabatic bath coordinates are discussed. The zero point of the cis rotamer is 1412 cm(-1) above that of the trans, which lies at 7354 cm(-1). The computed fundamentals match the bands recorded from gas-phase IR spectroscopy with an RMSD of only 3 cm(-1). A fresh assignment of the overtone spectra of both the cis and trans rotamers is presented for the energy range 0-4720 cm(-1), where 14 out of the 51 bands are reassigned on the basis of the VCI calculations.

  5. Energy and Global Ethics.

    ERIC Educational Resources Information Center

    Reader, Mark

    1979-01-01

    Author believes that the nuclear fuel cycle is damaging to our health, physical system, ecosystem, and social system. He recommends reversing the trend toward nuclear power and solving the energy crisis by creating a global society able to live in balance with its physical environment. Journal available from 7 Harwood Drive, Amherst, New York…

  6. Integrated evaluation of energy use, greenhouse gas emissions and global warming potential for sugar beet (Beta vulgaris) agroecosystems in Iran

    NASA Astrophysics Data System (ADS)

    Yousefi, Mohammad; Khoramivafa, Mahmud; Mondani, Farzad

    2014-08-01

    The main aim of this study was to determine and discuss the aggregate of energy use and greenhouse gas emission (CO2, N2O, and CH4) for sugar beet agroecosystems in western of Iran. For this propose data was collected by using questionnaires and face to face interview with 50 farmers. Results showed that total inputs and output energy were 49517.2 and 1095360.0 MJ ha-1, respectively. Energy use efficiency was 22.12. Total CO2, N2O and CH4 emissions due to chemical inputs were 2668.35, 22.92 and 3.49 kg, respectively. In sugar beet farms total global warming potential (GWPs) was 9847.77 kg CO2eq ha-1. In terms of CO2 equivalents, 27% of the GWPs come from CO2, 72% from N2O, and 1% from CH4. In this research input and output carbon were 29340.0 and 2678.6 kg C ha-1, respectively. Hence, carbon efficiency ratio was 10.95.

  7. Comparison greenhouse gas (GHG) emissions and global warming potential (GWP) effect of energy use in different wheat agroecosystems in Iran.

    PubMed

    Yousefi, Mohammad; Mahdavi Damghani, Abdolmajid; Khoramivafa, Mahmud

    2016-04-01

    The aims of this study were to determine energy requirement and global warming potential (GWP) in low and high input wheat production systems in western of Iran. For this purpose, data were collected from 120 wheat farms applying questionnaires via face-to-face interviews. Results showed that total energy input and output were 60,000 and 180,000 MJ ha(-1) in high input systems and 14,000 and 56,000 MJ ha(-1) in low input wheat production systems, respectively. The highest share of total input energy in high input systems recorded for electricity power, N fertilizer, and diesel fuel with 36, 18, and 13 %, respectively, while the highest share of input energy in low input systems observed for N fertilizer, diesel fuel, and seed with 32, 31, and 27 %. Energy use efficiency in high input systems (3.03) was lower than of low input systems (3.94). Total CO2, N2O, and CH4 emissions in high input systems were 1981.25, 31.18, and 1.87 kg ha(-1), respectively. These amounts were 699.88, 0.02, and 0.96 kg ha(-1) in low input systems. In high input wheat production systems, total GWP was 11686.63 kg CO2eq ha(-1) wheat. This amount was 725.89 kg CO2eq ha(-1) in low input systems. The results show that 1 ha of high input system will produce greenhouse effect 17 times of low input systems. So, high input production systems need to have an efficient and sustainable management for reducing environmental crises such as change climate.

  8. Theoretical characterization of the potential energy surface for H + N2 yields HN2. II - Computed points to define a global potential

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.

    1990-01-01

    A previous calculation for H + N2 (Walch et al., 1989) focused on the minimum energy path (MEP) region of the potential energy surface and on estimates of the lifetime of the HN2 species. In this paper, energies computed at geometries selected to permit a global representation of the potential energy surface (PES) are reported. As in the previous work, the calculations were performed using the complete active space self-consistent field/externally contracted configuration interaction method. The surface was characterized using the same basis set as in the previous paper except that an improved contraction of the H s-basis is used. Calculations with a larger basis set were carried out along an approximate MEP obtained with the smaller basis set. The new PES exhibits a sharp curvature, which was not present in the previous calculations, and has a slightly narrower and smaller barrier to dissociation. Saddle points for H atom exchange via collinear and T shaped HN2 complexes are also reported.

  9. Theoretical characterization of the potential energy surface for H + N2 yields HN2. II - Computed points to define a global potential

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.

    1990-01-01

    A previous calculation for H + N2 (Walch et al., 1989) focused on the minimum energy path (MEP) region of the potential energy surface and on estimates of the lifetime of the HN2 species. In this paper, energies computed at geometries selected to permit a global representation of the potential energy surface (PES) are reported. As in the previous work, the calculations were performed using the complete active space self-consistent field/externally contracted configuration interaction method. The surface was characterized using the same basis set as in the previous paper except that an improved contraction of the H s-basis is used. Calculations with a larger basis set were carried out along an approximate MEP obtained with the smaller basis set. The new PES exhibits a sharp curvature, which was not present in the previous calculations, and has a slightly narrower and smaller barrier to dissociation. Saddle points for H atom exchange via collinear and T shaped HN2 complexes are also reported.

  10. Energy and globalization

    NASA Astrophysics Data System (ADS)

    Birjandi, Hossein Saremi

    Before the Industrial Revolution, nations required no energy fuel. People relied on human, animal, and wind and waterpower for energy need. Energy (oil) has resettled populations, elected officials in the free world, or changed the governments of the energy rich countries by force. Energy fueled wars, played the major factor in the might of those who have it or more importantly the abilities to acquire it by force. This dissertation researches the primacy of oil as an energy source from the time of oil's discovery to the present times. Between 1945 and 1960, the use of oil and gas doubled as power was generated for industries as steel, cement, metalworking and more important of all filling station hoses into automobiles gas tanks, thus energy swept people and societies quite literally off their feet. One in every six jobs in the industrial world hired by the giant automotive industries. The big five American oil companies spurred on by special tax benefit, these companies grew to gigantic sizes by taking out the best part of the nation's oil. Then, for greater growth, they leaped overseas and built up an immensely profitable system, in alliance with Anglo-Dutch Shell and British Petroleum, known as seven sisters. On the other side of the world, the energy producing nations form an alliance mainly to protect themselves from downward price fluctuations of oil. The struggle for survival in the global energy market forced those countries to get together and form OPEC, which is referred as an "oil cartel".

  11. Theoretical characterization of the potential energy surface for the reversible reaction H + O2 yields HO2(asterisk) yields OH + O. III - Computed points to define a global potential energy surface

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.; Duchovic, Ronald J.

    1991-01-01

    Computed energies and geometries are reported which, combined with previously published calculations, permit a global representation of the potential energy surface for the reaction H + O2 yields HO2(asterisk) yields OH + O. These new calculations characterize the potential energy surface (PES) for all H atom angles of approach to O2 and for the region of the inner repulsive wall. The region of the T-shaped H-O2 exchange saddle point is connected with the constrained energy minimum (CEM) path, and a new collinear H-O2 exchange saddle point is characterized which lies only 9 kcal/mol above the H + O2 asymptote. A vibrational analysis which utilizes local cubic and quartic polynomial representations of the PES along the CEM path has been carried out. Optimal geometries, energies, and harmonic frequencies are reported along with anharmonic analyses for the O2 and OH asymptotes and for the HO2 minimum region of the PES.

  12. Theoretical characterization of the potential energy surface for the reversible reaction H + O2 yields HO2(asterisk) yields OH + O. III - Computed points to define a global potential energy surface

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.; Duchovic, Ronald J.

    1991-01-01

    Computed energies and geometries are reported which, combined with previously published calculations, permit a global representation of the potential energy surface for the reaction H + O2 yields HO2(asterisk) yields OH + O. These new calculations characterize the potential energy surface (PES) for all H atom angles of approach to O2 and for the region of the inner repulsive wall. The region of the T-shaped H-O2 exchange saddle point is connected with the constrained energy minimum (CEM) path, and a new collinear H-O2 exchange saddle point is characterized which lies only 9 kcal/mol above the H + O2 asymptote. A vibrational analysis which utilizes local cubic and quartic polynomial representations of the PES along the CEM path has been carried out. Optimal geometries, energies, and harmonic frequencies are reported along with anharmonic analyses for the O2 and OH asymptotes and for the HO2 minimum region of the PES.

  13. Accurate high level ab initio-based global potential energy surface and dynamics calculations for ground state of CH{sub 2}{sup +}

    SciTech Connect

    Li, Y. Q.; Zhang, P. Y.; Han, K. L.

    2015-03-28

    A global many-body expansion potential energy surface is reported for the electronic ground state of CH{sub 2}{sup +} by fitting high level ab initio energies calculated at the multireference configuration interaction level with the aug-cc-pV6Z basis set. The topographical features of the new global potential energy surface are examined in detail and found to be in good agreement with those calculated directly from the raw ab initio energies, as well as previous calculations available in the literature. In turn, in order to validate the potential energy surface, a test theoretical study of the reaction CH{sup +}(X{sup 1}Σ{sup +})+H({sup 2}S)→C{sup +}({sup 2}P)+H{sub 2}(X{sup 1}Σ{sub g}{sup +}) has been carried out with the method of time dependent wavepacket on the title potential energy surface. The total integral cross sections and the rate coefficients have been calculated; the results determined that the new potential energy surface can both be recommended for dynamics studies of any type and as building blocks for constructing the potential energy surfaces of larger C{sup +}/H containing systems.

  14. Global energy interactions

    SciTech Connect

    Pachauri, R.K.

    1987-01-01

    This book contains 68 selections. Some of the titles are: Petroleum taxes and resource management; The effect of PURPA on the electric utility industry; The prospects of rural energy in People's Republic of China; World oil prices and the emerging world gas market; The potential of coal in the development of oil rich LDC's: the case of Indonesia; and Demand elasticities for petroleum products in Sri Lanka.

  15. Methanol clusters (CH3OH)n: putative global minimum-energy structures from model potentials and dispersion-corrected density functional theory.

    PubMed

    Kazachenko, Sergey; Bulusu, Satya; Thakkar, Ajit J

    2013-06-14

    Putative global minima are reported for methanol clusters (CH3OH)n with n ≤ 15. The predictions are based on global optimization of three intermolecular potential energy models followed by local optimization and single-point energy calculations using two variants of dispersion-corrected density functional theory. Recurring structural motifs include folded and/or twisted rings, folded rings with a short branch, and stacked rings. Many of the larger structures are stabilized by weak C-H···O bonds.

  16. Globally accurate potential energy surface for the ground-state HCS(X2A′) and its use in reaction dynamics

    PubMed Central

    Song, Yu-Zhi; Zhang, Lu-Lu; Gao, Shou-Bao; Meng, Qing-Tian

    2016-01-01

    A globally accurate many-body expansion potential energy surface is reported for HCS(X2A′) by fitting a wealth of accurate ab initio energies calculated at the multireference configuration interaction level using aug-cc-pVQZ and aug-cc-pV5Z basis sets via extrapolation to the complete basis set limit. The topographical features of the present potential energy surface are examined in detail and is in good agreement with the raw ab initio results, as well as other theoretical results available in literatures. By utilizing the potential energy surface of HCS(X2A′), the dynamic studies of the C(3P) + SH(X2Π) → H(2S) + CS(X1∑+) reaction has been carried out using quasi-classical trajectory method. PMID:27898106

  17. Innovation in Photovoltaic Science, Engineering, and Policy: A Potential Trillion-Dollar Global Industry for Sustainable Energy

    NASA Astrophysics Data System (ADS)

    Zheng, Cheng

    The solar photovoltaic (PV) technology was an expensive niche energy source only for satellite applications, hallmarked by the Bell Lab's launch of the Telstar satellite with PV cells in 1962. Over the past decades, the accumulation of vast amount of effort across various disciplines in science, engineering, and policy has enabled the phenomenal growth of the solar PV industry into a global enterprise with about 140 gigawatt (GW) of cumulative installations by the end of 2013. Further cost reduction through innovation holds the promise in deploying terawatt (TW)-scale solar PV systems globally in both developed and developing countries, meeting growing energy demand and mitigating climate change. Chapter 1 presents a big picture view of the unsustainable path, heavily relying on fossil fuels, in the current global energy landscape. The main body of the dissertation examines the solar PV technology from a holistic and interdisciplinary perspective: from the basic research, to innovations in manufacturing and installing PV modules, to the driving energy policies. Chapter 2 offers a fundamental understanding of the PV technology and a review on recent scientific advances in improving PV efficiency (W/m 2). Chapter 3 reviews the state-of-the-art process flow in manufacturing commercial PV modules. In the context of pursuing further reduction in manufacturing cost (/m2), the thin Si film concept and its recent research effort are reviewed. Aiming to explore novel ways to produce high-quality seed crystals for thin Si film deposition, the key findings of the laser crystallization experiment is presented in Chapter 4. The fundamental thermophysics of nucleation and crystal growth is first reviewed, which highlights the importance of temperature evolution and heat transport in modelling the ultrafast laser crystallization process. Laser crystallization of a range of Si nanostructures are then carried out to study the nucleation and crystal growth behavior under some novel

  18. Locating gravitational potential energy

    NASA Astrophysics Data System (ADS)

    Keeports, David

    2017-01-01

    Where does gravitational potential energy reside when a ball is in the air? The perfectly correct answer is that it is located in the ball-Earth system. Still, mechanical energy conservation problems are routinely solved by assigning a potential energy to the ball alone. Provided here is a proof that such an assignment introduces only an entirely undetectable error.

  19. Probing the global potential energy minimum of (CH2O)2: THz absorption spectrum of (CH2O)2 in solid neon and para-hydrogen.

    PubMed

    Andersen, J; Voute, A; Mihrin, D; Heimdal, J; Berg, R W; Torsson, M; Wugt Larsen, R

    2017-06-28

    The true global potential energy minimum configuration of the formaldehyde dimer (CH2O)2, including the presence of a single or a double weak intermolecular CH⋯O hydrogen bond motif, has been a long-standing subject among both experimentalists and theoreticians as two different energy minima conformations of Cs and C2h symmetry have almost identical energies. The present work demonstrates how the class of large-amplitude hydrogen bond vibrational motion probed in the THz region provides excellent direct spectroscopic observables for these weak intermolecular CH⋯O hydrogen bond motifs. The combination of concentration dependency measurements, observed isotopic spectral shifts associated with H/D substitutions and dedicated annealing procedures, enables the unambiguous assignment of three large-amplitude infrared active hydrogen bond vibrational modes for the non-planar Cs configuration of (CH2O)2 embedded in cryogenic neon and enriched para-hydrogen matrices. A (semi)-empirical value for the change of vibrational zero-point energy of 5.5 ± 0.3 kJ mol(-1) is proposed for the dimerization process. These THz spectroscopic observations are complemented by CCSD(T)-F12/aug-cc-pV5Z (electronic energies) and MP2/aug-cc-pVQZ (force fields) electronic structure calculations yielding a (semi)-empirical value of 13.7 ± 0.3 kJ mol(-1) for the dissociation energy D0 of this global potential energy minimum.

  20. Probing the global potential energy minimum of (CH2O)2: THz absorption spectrum of (CH2O)2 in solid neon and para-hydrogen

    NASA Astrophysics Data System (ADS)

    Andersen, J.; Voute, A.; Mihrin, D.; Heimdal, J.; Berg, R. W.; Torsson, M.; Wugt Larsen, R.

    2017-06-01

    The true global potential energy minimum configuration of the formaldehyde dimer (CH2O)2, including the presence of a single or a double weak intermolecular CH⋯O hydrogen bond motif, has been a long-standing subject among both experimentalists and theoreticians as two different energy minima conformations of Cs and C2h symmetry have almost identical energies. The present work demonstrates how the class of large-amplitude hydrogen bond vibrational motion probed in the THz region provides excellent direct spectroscopic observables for these weak intermolecular CH⋯O hydrogen bond motifs. The combination of concentration dependency measurements, observed isotopic spectral shifts associated with H/D substitutions and dedicated annealing procedures, enables the unambiguous assignment of three large-amplitude infrared active hydrogen bond vibrational modes for the non-planar Cs configuration of (CH2O)2 embedded in cryogenic neon and enriched para-hydrogen matrices. A (semi)-empirical value for the change of vibrational zero-point energy of 5.5 ± 0.3 kJ mol-1 is proposed for the dimerization process. These THz spectroscopic observations are complemented by CCSD(T)-F12/aug-cc-pV5Z (electronic energies) and MP2/aug-cc-pVQZ (force fields) electronic structure calculations yielding a (semi)-empirical value of 13.7 ± 0.3 kJ mol-1 for the dissociation energy D0 of this global potential energy minimum.

  1. Global Energy Issues and Alternate Fueling

    NASA Technical Reports Server (NTRS)

    Hendricks, Robert C.

    2007-01-01

    This viewgraph presentation describes world energy issues and alternate fueling effects on aircraft design. The contents include: 1) US Uses about 100 Quad/year (1 Q = 10(exp 15) Btu) World Energy Use: about 433 Q/yr; 2) US Renewable Energy about 6%; 3) Nuclear Could Grow: Has Legacy Problems; 4) Energy Sources Primarily NonRenewable Hydrocarbon; 5) Notes; 6) Alternate Fuels Effect Aircraft Design; 7) Conventional-Biomass Issue - Food or Fuel; 8) Alternate fuels must be environmentally benign; 9) World Carbon (CO2) Emissions Problem; 10) Jim Hansen s Global Warming Warnings; 11) Gas Hydrates (Clathrates), Solar & Biomass Locations; 12) Global Energy Sector Response; 13) Alternative Renewables; 14) Stratospheric Sulfur Injection Global Cooling Switch; 15) Potential Global Energy Sector Response; and 16) New Sealing and Fluid Flow Challenges.

  2. Global and local aspects of the surface potential landscape for energy level alignment at organic-ZnO interfaces

    NASA Astrophysics Data System (ADS)

    Stähler, Julia; Rinke, Patrick

    2017-03-01

    Hybrid systems of organic and inorganic semiconductors are a promising route for the development of novel opto-electronic and light-harvesting devices. A key ingredient for achieving a superior functionality by means of a hybrid system is the right relative position of energy levels at the interfaces of the two material classes. In this Perspective, we address the sensitivity of the potential energy landscape at various ZnO surfaces, a key ingredient for interfacial energy level alignment, by combining one- and two-photon photoelectron spectroscopy with density-functional theory calculations (DFT). We show that even very large work function changes (>2.5 eV) do not necessarily have to be accompanied by surface band bending in ZnO. Band bending - if it does occur - may be localized to few Å or extend over hundreds of nanometers with very different results for the surface work function and energy level alignment. Managing the delicate balance of different interface manipulation mechanisms in organic-inorganic hybrid systems will be a major challenge towards future applications.

  3. Global warming potentials of Hydrofluoroethers.

    PubMed

    Blowers, Paul; Moline, Dena Marie; Tetrault, Kyle Franklin; Wheeler, R'nld Ruth; Tuchawena, Shane Lee

    2008-02-15

    Global warming potentials are estimated for hydrofluoroethers, which are an emerging class of compounds for industrial use. Comparisons are made to the limited data previously available before observations about molecular design are discussed. We quantify how molecular structure can be manipulated to reduce environmental impacts due to global warming. We further highlight the need for additional research on this class of compounds so environmental performance can be assessed for green design.

  4. Global Heat and Precession Energy

    NASA Astrophysics Data System (ADS)

    Vanyo, J. P.

    2006-05-01

    Precession Energy: By 1975, precession energy rates were assumed to be inadequate for a geodynamo. Most agreed in favor for a heat core model, but formal critiques on the matter were never published. A 'rigid- sphere' model and two accretion models had examined a precession geodynamo on similar energy features. The core's relative motion has two limits, the core uncoupled to its mantle and then fixed rigidly to its mantle. Both limits produce no energy. Energy rate (power) is produced only when core-mantle torque and core- mantle motion interact. Earlier researchers had estimated that a geodynamo needed approximately 10E11 W to 10E12 W, but could only find 10E8 W. The rigid-sphere model analysis starts with a theoretical solution for precession energy, subject to known Earth parameters 6x10E16 W. A derived dimensionless coefficient C/(1+ Csq) can only have a maximum value 1/2 and C = 1 with Pmax = 3x10E16 W. Precession energy rates in the rigid-sphere model is related inversely to magnetic intensity by the variable C as coupling. More magnetic coupling reduces energy rate, and less magnetic coupling increases energy rate. The theories and estimates for precession energy rates (10E8 W) did not consider the total energy rate (Pmax = 3x10E16 W). This is a zero sum game, and 10E8 W represents a great gap from 3x10E16 W. Precession research has continued, and research now supports much more energetic precession geodynamo models. Experiments have now achieved successes for geodynamo energy rates, core-mantle relative motions which suggest geomagnetic CMB patterns, viscous-electromagnetic coupling analyses, and geodynamo simulations with laminar and turbulent precession models. Global Heat: The Earth's interior has the core's liquid heat reservoir, and the Earth's surface has its water and its ice's heat reservoir. Both core and ice have potential for accretion and ablation, and both have experienced these events during Earth's creation. A geodynamo heat (accretion) model

  5. Assessing energy efficiencies, economy, and global warming potential (GWP) effects of major crop production systems in Iran: a case study in East Azerbaijan province.

    PubMed

    Mohammadzadeh, Arash; Mahdavi Damghani, Abdolmajid; Vafabakhsh, Javad; Deihimfard, Reza

    2017-07-01

    Efficient use of energy in farming systems is one of the most important implications for decreasing greenhouse gas (GHG) emissions and mitigating global warming (GW). This paper describes the energy use patterns, analyze the economics, and report global warming potential effects of major crop production systems in East Azerbaijan province, Iran. For this purpose, 110 farmers whose main activity was major crop production in the region, including wheat, barley, carrot, tomato, onion, potato, alfalfa, corn silage, canola, and saffron, were surveyed. Some other data was obtained from the Ministry of Agriculture Jihad of Iran. Results showed that, in terms of total energy input, onion (87,556 Mj ha(-1)) and potato (80,869 Mj ha(-1)) production systems were more energy-intensive than other crops. Among the studied crops, the highest values of net return (6563.8 $ ha(-1)) and benefit/cost ratio (1.95) were related to carrot and corn silage production systems, respectively. Studies have also shown that onion and saffron production systems emit the highest (5332.6 kg CO2eq ha(-1)) and lowest (646.24 kg CO2eq ha(-1)) CO2 eq. emission, respectively. When it was averaged across crops, diesel fuel accounted for the greatest GHG contribution with 43% of the total, followed by electric power (28%) and nitrogen fertilizer (21%). In the present study, eco-efficiency was calculated as a ratio of the gross production value and global warming potential effect for the studied crops. Out of all the studied crops, the highest values of eco-efficiency were calculated to be 8.65 $ kg CO2eq(-1) for the saffron production system followed by the carrot (3.65 $ kg CO2eq(-1)) production. Generally, from the aspect of energy balance and use efficiency, the alfalfa production system was the best; however, from an economical point of view, the carrot production system was better than the other crops.

  6. Global triplet potential energy surfaces for the N2(X(1)Σ) + O((3)P) → NO(X(2)Π) + N((4)S) reaction.

    PubMed

    Lin, Wei; Varga, Zoltan; Song, Guoliang; Paukku, Yuliya; Truhlar, Donald G

    2016-01-14

    This work presents two global triplet potential energy surfaces (PESs) for the high-energy reaction N2(X(1)Σ) + O((3)P) → NO(X(2)Π) + N((4)S)-in particular, for the lowest energy (3)A' and (3)A″ PESs. In order to obtain the energies needed for fitting analytic surfaces, we carried out multireference configuration interaction (MRCI) calculations based on wave functions obtained from state-averaged complete active space self-consistent field calculations for 2280 geometries for the three lowest (3)A″ states and for 2298 geometries for the three lowest (3)A' states. The lowest-energy (3)A' and (3)A″ states at each of these geometries were then improved by applying the dynamically scaled external correlation (DSEC) method to all MRCI points, and the resulting DSEC energies were used for construction of the ground-state PES for each symmetry. The many-body component of the DSEC energies for the three-dimensional (3)A' and (3)A″ PESs was then least-squares fitted in terms of permutationally invariant polynomials in mixed exponential-Gaussian bond order variables. The global and local minima as well as the transition structures of both the (3)A' and the (3)A″ analytic PES were explored. In agreement with previous work, we find that the reverse reaction is barrierless on the (3)A″ surface along the minimum energy pathway. However, we have explored several new local minima and transition structures on the (3)A' PES. Furthermore, based on the newly found minima and transition structures, two independent reaction mechanisms have been illustrated for the reaction path on the (3)A' PES. The analytic surfaces may be used for dynamics calculations of electronically adiabatic reactive scattering and energy transfer.

  7. Implementation of global energy sustainability

    SciTech Connect

    Grob, G.R.

    1998-02-01

    The term energy sustainability emerged from the UN Conference on Environment and Development in Rio 1992, when Agenda 21 was formulated and the Global Energy Charter proclaimed. Emission reductions, total energy costing, improved energy efficiency, and sustainable energy systems are the four fundamental principles of the charter. These principles can be implemented in the proposed financial, legal, technical, and education framework. Much has been done in many countries toward the implementation of the Global Energy Charter, but progress has not been fast enough to ease the disastrous effects of the too many ill-conceived energy systems on the environment, climate, and health. Global warming is accelerating, and pollution is worsening, especially in developing countries with their hunger for energy to meet the needs of economic development. Asian cities are now beating all pollution records, and greenhouse gases are visibly changing the climate with rising sea levels, retracting glaciers, and record weather disasters. This article presents why and how energy investments and research money have to be rechanneled into sustainable energy, rather than into the business-as-usual of depleting, unsustainable energy concepts exceeding one trillion dollars per year. This largest of all investment sectors needs much more attention.

  8. Symmetry energy, its density slope, and neutron-proton effective mass splitting at normal density extracted from global nucleon optical potentials

    SciTech Connect

    Xu Chang; Li Baoan; Chen Liewen

    2010-11-15

    Based on the Hugenholtz-Van Hove theorem, it is shown that both the symmetry energy E{sub sym}({rho}) and its density slope L({rho}) at normal density {rho}{sub 0} are completely determined by the nucleon global optical potentials. The latter can be extracted directly from nucleon-nucleus scatterings, (p,n) charge-exchange reactions, and single-particle energy levels of bound states. Averaging all phenomenological isovector nucleon potentials constrained by world data available in the literature since 1969, the best estimates of E{sub sym}({rho}{sub 0})=31.3 MeV and L({rho}{sub 0})=52.7 MeV are simultaneously obtained. Moreover, the corresponding neutron-proton effective mass splitting in neutron-rich matter of isospin asymmetry {delta} is estimated to be (m{sub n}{sup *}-m{sub p}{sup *})/m=0.32{delta}.

  9. Potential effects of global climate change

    SciTech Connect

    Gucinski, H.; Vance, E.; Reiners, W.A.

    1995-07-01

    The difficulties of detecting climatic changes do not diminish the need to examine the consequences of a changing global radiative energy balance. In part, detecting global changes is difficult (even though many, though by no means all, theoretical climatic processes are well understood) because the potential effects of changes on the unmanaged ecosystems of the globe, especially forests, which may have great human significance, involve tightly woven ecosystems, inextricably linked to global habitat. Coniferous forests are of particular interest because they dominate high-latitude forest systems, and potential effects of global climate change are likely to be greatest at high latitudes. The degree of projected climate change is a function of many likely scenarios of fossil fuel consumption, and the ratios of manmade effects to natural sources and sinks of CO{sub 2}. Because CO{sub 2}, like water vapor, CH{sub 4}, CFCs, and other gases, absorbs infrared energy, it will alter the radiation balance of the global atmosphere. The consequences of this alteration to the radiation balance cannot simply be translated into changing climate because (1) the existence of large energy reservoirs (the oceans) can introduce a lag in responses, (2) feedback loops between atmosphere, oceans, and biosphere can change the net rate of buildup of greenhouse gases in the atmosphere, (3) complex interactions in the atmospheric water balance can change the rate of cloud formation with their persistence, in turn, changing the global albedo and the energy balance, and (4) there is intrusion of other global effects, such as periodic volcanic gas injections to the stratosphere.

  10. A global ab initio potential energy surface for the X 2A' ground state of the Si + OH → SiO + H reaction

    NASA Astrophysics Data System (ADS)

    Dayou, Fabrice; Duflot, Denis; Rivero-Santamaría, Alejandro; Monnerville, Maurice

    2013-11-01

    We report the first global potential energy surface (PES) for the X 2A' ground electronic state of the Si(3P) + OH(X2Π) → SiO(X^1Σ _g^+) + H(2S) reaction. The PES is based on a large number of ab initio energies obtained from multireference configuration interaction calculations plus Davidson correction (MRCI+Q) using basis sets of quadruple zeta quality. Corrections were applied to the ab initio energies in the reactant channel allowing a proper description of long-range interactions between Si(3P) and OH(X2Π). An analytical representation of the global PES has been developed by means of the reproducing kernel Hilbert space method. The reaction is found barrierless. Two minima, corresponding to the SiOH and HSiO isomers, and six saddle points, among which the isomerization transition state, have been characterized on the PES. The vibrational spectra of the SiOH/HSiO radicals have been computed from second-order perturbation theory and quantum dynamics methods. The structural, energetic, and spectroscopic properties of the two isomers are in good agreement with experimental data and previous high quality calculations.

  11. Decarbonizing the global energy system

    SciTech Connect

    Gruebler, A.; Nakicenovic, N.

    1996-09-01

    The study analyzes the long-term decarbonization of the global energy system, i.e., the decrease of the carbon emissions per unit of primary energy. Decarbonization appears as a continuous and persistent trend throughout the world, albeit occurring at very slow rates of approximately 0.3% per year. The study also discusses driving forces of the associated structural changes in energy systems such as technological change. Decarbonization also occurs at the level of energy end use and trends for final energy are shown. The quest for higher flexibility, convenience, and cleanliness of energy services demanded by consumers leads to decarbonization trends in final energy that are more pronounced than that of the upstream energy sector. The study concludes with a discussion of the implications for long-term scenarios of energy-environment interactions suggesting that decarbonization and its driving forces may still be insufficiently captured by most models and scenarios of the long-term evolution of the energy system. 32 refs., 5 figs., 4 tabs.

  12. A global 12-dimensional ab initio potential energy surface and dynamical studies for the SiH4+H →SiH3+H2 reaction

    NASA Astrophysics Data System (ADS)

    Wang, Manhui; Sun, Xiaomin; Bian, Wensheng; Cai, Zhengting

    2006-06-01

    A global 12-dimensional ab initio interpolated potential energy surface (PES) for the SiH4+H →SiH3+H2 reaction is presented. The ab initio calculations are based on the unrestricted quadratic configuration interaction treatment with all single and double excitations together with the cc-pVTZ basis set, and the modified Shepard interpolation method of Collins and co-workers [K. C. Thompson et al., J. Chem. Phys. 108, 8302 (1998); M. A. Collins, Theor. Chem. Acc. 108, 313 (2002); R. P. A. Bettens and M. A. Collins, J. Chem. Phys. 111, 816 (1999)] is applied. Using this PES, classical trajectory and variational transition state theory calculations have been carried out, and the computed rate constants are in good agreement with the available experimental data.

  13. Full-dimensional global potential energy surfaces describing abstraction and exchange for the H + H2S reaction

    NASA Astrophysics Data System (ADS)

    Lu, Dandan; Li, Jun

    2016-07-01

    For the H + H2S system, ˜34 000 data points are sampled over a large configuration space including both abstraction and exchange channels, and calculated at the level of explicitly correlated unrestricted coupled cluster method with singles, doubles, and perturbative triples excitations with the augmented correlation-consistent polarized triple zeta basis set (UCCSD(T)-F12a/aug-cc-pVTZ). The data set was fit using the newly proposed permutation invariant polynomial-neural network (PIP-NN) method with three different vectors as the input: two redundant sets of PIPs, one with the maximum order four (PES-I) and one with the maximum order three (PES-II), and nine non-redundant PIPs (PES-III). All these PESs show small fitting errors and essentially the same performance in representing the title system. Various kinetics and dynamical properties are calculated using the tunneling corrected transition state theory and quasi-classical trajectory, and compared with available experimental results. At a collision energy of 10 kcal/mol, both the H2 and SH products are found to be internally cold, with ˜20% of H2 at its first vibrational excited state, while SH is essentially a spectator. The angular distributions of the products are mainly in backward with considerable contributions from sideway direction. In addition, analytical partial derivatives of any PIP-NN PES with respect to the coordinates of atoms are derived by making use of the monomial symmetrization algorithm [Z. Xie and J. M. Bowman, J. Chem. Theory Comput. 6, 26-34 (2010)]. It can not only accelerate the evaluation of the derivatives, but also improve the energy convergence significantly.

  14. A New Global Potential Energy Surface for the Hydroperoxyl Radical, HO2: Reaction Coefficients for H + O2 and Vibrational Splittings for H Atom Transfer

    NASA Technical Reports Server (NTRS)

    Dateo, Christopher E.; Arnold, James O. (Technical Monitor)

    1994-01-01

    A new analytic global potential energy surface describing the hydroperoxyl radical system H((sup 2)S) + O2(X (sup 3)Sigma((sup -)(sub g))) (reversible reaction) HO2 ((X-tilde) (sup 2)A'') (reversible reaction) O((sup 3)P) + O H (X (sup 2)Pi) has been fitted using the ab initio complete active space SCF (self-consistent-field)/externally contracted configuration interaction (CASSCF/CCI) energy calculations of Walch and Duchovic. Results of quasiclassical trajectory studies to determine the rate coefficients of the forward and reverse reactions at combustion temperatures will be presented. In addition, vibrational energy levels were calculated using the quantum DVR-DGB (discrete variable representation-distributed Gaussian basis) method and the splitting due to H atom migration is investigated. The material of the proposed presentation was reviewed and the technical content will not reveal any information not already in the public domain and will not give any foreign industry or government a competitive advantage.

  15. Mode-specific multi-channel dynamics of the F- + CHD2Cl reaction on a global ab initio potential energy surface

    NASA Astrophysics Data System (ADS)

    Szabó, István; Czakó, Gábor

    2016-10-01

    We report a detailed quasiclassical trajectory study for the dynamics of the ground-state and CH/CD stretching-excited F- + CHD2Cl(vCH/CD = 0, 1) → Cl- + CHD2F, HF + CD2Cl-, and DF + CHDCl- SN2, proton-, and deuteron-abstraction reactions using a full-dimensional global ab initio analytical potential energy surface. The simulations show that (a) CHD2Cl(vCH/CD = 1), especially for vCH = 1, maintains its mode-specific excited character prior to interaction, (b) the SN2 reaction is vibrationally mode-specific, (c) double inversion can occur and is enhanced upon CH/CD stretching excitations, (d) in the abstraction reactions the HF channel is preferred and the vCH/CD = 1 excitations significantly promote the HF/DF channels, (e) back-side rebound, back-side stripping, and front-side stripping are the dominant direct abstraction mechanisms based on correlated scattering- and attack-angle distributions, (f) the exact classical vibrational energy-based Gaussian binning (1GB) provides realistic mode-specific polyatomic product state distributions, (g) in the abstraction reactions CH and CD stretchings are not pure spectator modes and mainly ground-state products are produced, thus most of the initial energy transfers into product translation, and (h) the HF and DF product molecules are rotationally cold without any significant dependence on the reactant's and HF/DF vibrational states.

  16. A New Global Potential Energy Surface for the Hydroperoxyl Radical, HO2: Reaction Coefficients for H + O2 and Vibrational Splittings for H Atom Transfer

    NASA Technical Reports Server (NTRS)

    Dateo, Christopher E.; Arnold, James O. (Technical Monitor)

    1994-01-01

    A new analytic global potential energy surface describing the hydroperoxyl radical system H((sup 2)S) + O2(X (sup 3)Sigma((sup -)(sub g))) (reversible reaction) HO2 ((X-tilde) (sup 2)A'') (reversible reaction) O((sup 3)P) + O H (X (sup 2)Pi) has been fitted using the ab initio complete active space SCF (self-consistent-field)/externally contracted configuration interaction (CASSCF/CCI) energy calculations of Walch and Duchovic. Results of quasiclassical trajectory studies to determine the rate coefficients of the forward and reverse reactions at combustion temperatures will be presented. In addition, vibrational energy levels were calculated using the quantum DVR-DGB (discrete variable representation-distributed Gaussian basis) method and the splitting due to H atom migration is investigated. The material of the proposed presentation was reviewed and the technical content will not reveal any information not already in the public domain and will not give any foreign industry or government a competitive advantage.

  17. Space and energy: Global viewpoint

    NASA Astrophysics Data System (ADS)

    Koelle, D. E.

    1981-11-01

    The potential contributions from space technology to solving the future world energy problem are addressed. The basic problem is created by the depletion of the fossile fuels in the next century. The replacement of oil, gas and coal is only feasible by nuclear power and solar energy. In the first case space technology can contribute to making the terrestrial storage of radioactive waste much less dangerous and more acceptable by expediting the highly radioactive components (only 3%) into space. In the case of solar energy space technology can contribute large solar power stations in space, providing energy via microwaves to special rectenna sites.

  18. Global warming potential impact of bioenergy systems

    NASA Astrophysics Data System (ADS)

    Tonini, D.; Hamelin, L.; Wenzel, H.; Astrup, T.

    2012-10-01

    Reducing dependence on fossil fuels and mitigation of GHG emissions is a main focus in the energy strategy of many Countries. In the case of Demark, for instance, the long-term target of the energy policy is to reach 100% renewable energy system. This can be achieved by drastic reduction of the energy demand, optimization of production/distribution and substitution of fossil fuels with biomasses. However, a large increase in biomass consumption will finally induce conversion of arable and currently cultivated land into fields dedicated to energy crops production determining significant environmental consequences related to land use changes. In this study the global warming potential impact associated with six alternative bioenergy systems based on willow and Miscanthus was assessed by means of life-cycle assessment. The results showed that bioenergy production may generate higher global warming impacts than the reference fossil fuel system, when the impacts from indirect land use changes are accounted for. In a life-cycle perspective, only highly-efficient co-firing with fossil fuel achieved a (modest) GHG emission reduction.

  19. Countdown to Drawdown: an initial overview of exponential scaling of potential societal tipping points for deep decarbonization of global energy infrastructure by 2050

    NASA Astrophysics Data System (ADS)

    McCaffrey, Mark; Bhowmik, Avit

    2017-04-01

    The 194 signatories to the Paris Agreement range in size from small island nations (Tuvalu, less than 10,000 people) to massive states (India and China, which between them have 2.6 billion people). Their cultural backgrounds, political, economic and social systems vary widely. What they all share is an agreement for climate stabilisation at 1.5-2˚ C. A roadmap outlining potential exponential transitions towards a carbon-free economy may benefit from a logarithmic "powers of ten" framework that sets aside backgrounds and systems to examine the relative population concentration scales-from the individual (100) to local/neighborhood (103) to the national/transnational scales (108) and ultimately the global population of around 10 billion anticipated in 2050 (1010). What are the related targets and indicators for successful engagement at each level for rapid and radical reductions of carbon emissions and concentrations? What are the possible interventions and barriers that may be applied at different levels of population concentration? What "drawdown" strategies are most appropriate for different scales? Could focusing demonstrations of clean energy and sustainable practices on the local/neighborhood to urban scale (103-104) provide a leverage that has not been achieved at more complex national and transnational scales? Ultimately, backgrounds and systems are important factors in the equation, but the "powers of 10" scaling framework may provide a compass to assist in identifying the challenges, opportunities and related thresholds and tipping points for achieving deep decarbonization and transformation of the global energy infrastructure at every level of society over the next thirty-three years.

  20. Benchmarks of Global Clean Energy Manufacturing

    SciTech Connect

    Sandor, Debra; Chung, Donald; Keyser, David; Mann, Margaret; Engel-Cox, Jill

    2017-01-01

    The Clean Energy Manufacturing Analysis Center (CEMAC), sponsored by the U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE), provides objective analysis and up-to-date data on global supply chains and manufacturing of clean energy technologies. Benchmarks of Global Clean Energy Manufacturing sheds light on several fundamental questions about the global clean technology manufacturing enterprise: How does clean energy technology manufacturing impact national economies? What are the economic opportunities across the manufacturing supply chain? What are the global dynamics of clean energy technology manufacturing?

  1. Global potential for wind-generated electricity

    PubMed Central

    Lu, Xi; McElroy, Michael B.; Kiviluoma, Juha

    2009-01-01

    The potential of wind power as a global source of electricity is assessed by using winds derived through assimilation of data from a variety of meteorological sources. The analysis indicates that a network of land-based 2.5-megawatt (MW) turbines restricted to nonforested, ice-free, nonurban areas operating at as little as 20% of their rated capacity could supply >40 times current worldwide consumption of electricity, >5 times total global use of energy in all forms. Resources in the contiguous United States, specifically in the central plain states, could accommodate as much as 16 times total current demand for electricity in the United States. Estimates are given also for quantities of electricity that could be obtained by using a network of 3.6-MW turbines deployed in ocean waters with depths <200 m within 50 nautical miles (92.6 km) of closest coastlines. PMID:19549865

  2. Global potential for wind-generated electricity.

    PubMed

    Lu, Xi; McElroy, Michael B; Kiviluoma, Juha

    2009-07-07

    The potential of wind power as a global source of electricity is assessed by using winds derived through assimilation of data from a variety of meteorological sources. The analysis indicates that a network of land-based 2.5-megawatt (MW) turbines restricted to nonforested, ice-free, nonurban areas operating at as little as 20% of their rated capacity could supply >40 times current worldwide consumption of electricity, >5 times total global use of energy in all forms. Resources in the contiguous United States, specifically in the central plain states, could accommodate as much as 16 times total current demand for electricity in the United States. Estimates are given also for quantities of electricity that could be obtained by using a network of 3.6-MW turbines deployed in ocean waters with depths <200 m within 50 nautical miles (92.6 km) of closest coastlines.

  3. Energy and global climate change: Why ORNL?

    SciTech Connect

    Farrell, M.P.

    1995-12-31

    Subtle signs of global warming have been detected in studies of the climate record of the past century after figuring in the cooling effects of sulfur emissions from volcanoes and human sources. According to the December 1995 report of the Intergovernment Panel on Climate Change (IPCC), the earth`s surface temperature has increased by about 0.2{degrees}C per decade since 1975. the panel projects about a 2{degrees} increase in global temperature by 2100. The IPCC report states that pollutants-greenhouse gases such as carbon dioxide and fluorocarbons that warm the globe and sulfur emission that cool it-are responsible for recent patterns of climate change. {open_quotes}The balance of evidence,{close_quotes} states the report, {open_quotes}suggests that there is a discrenible human influence on global climate.{close_quotes} This human influence stems largely from fossil fuel combustion, cement production, and the burning of forests, and could intensify as populations grow and developing countries increase energy production and industrial development. The two facts have caught the attention of the news media and public. First, 1995 was declared the hottest year in the 140-year-long record of reliable global measurements. Second, recent years have been marked by an unusually high number of extreme weather events, such as hurricanes, blizzards, and floods. In the 1990`s the world has become more aware of the prospect and possible impacts of global climate change. In the late 1950`s, global climate change was an unknown threat to the world`s environment and social systems. Except for a few ORNL researchers who had just completed their first briefing to the U.S. Atomic Energy Commission on the need to understand the global carbon cycle, the connection between rising carbon dioxide concentrations and potential changes in global climate was not common knowledge, nor were the consequences of climate change understood.

  4. Alaska's renewable energy potential.

    SciTech Connect

    Not Available

    2009-02-01

    This paper delivers a brief survey of renewable energy technologies applicable to Alaska's climate, latitude, geography, and geology. We first identify Alaska's natural renewable energy resources and which renewable energy technologies would be most productive. e survey the current state of renewable energy technologies and research efforts within the U.S. and, where appropriate, internationally. We also present information on the current state of Alaska's renewable energy assets, incentives, and commercial enterprises. Finally, we escribe places where research efforts at Sandia National Laboratories could assist the state of Alaska with its renewable energy technology investment efforts.

  5. Genetic algorithm approach to global optimization of the full-dimensional potential energy surface for hydrogen atom at fcc-metal surfaces

    NASA Astrophysics Data System (ADS)

    Kammler, Marvin; Janke, Svenja M.; Kandratsenka, Alexander; Wodtke, Alec M.

    2017-09-01

    We have developed a genetic algorithm approach for the parametrization of a multi-dimensional potential energy surface based on the analytical expression for energy derived from Effective Medium Theory by fitting it to DFT data. This approach yields consistent results for the H-atom interaction energy with a number of fcc-metal surfaces (Al, Ag, Au, Cu, Ni, Pd, Pt and Rh) and provides reasonable energy values for virtually any system geometry including various facets.

  6. Global investigation of potential energy surfaces for the pyrolysis of C(1)-C(3) hydrocarbons: toward the development of detailed kinetic models from first principles.

    PubMed

    Ryazantsev, Mikhail N; Jamal, Adeel; Maeda, Satoshi; Morokuma, Keiji

    2015-11-07

    Detailed kinetic models (DKMs) are the most fundamental "bottom-up" approaches to computational investigation of the pyrolysis and oxidation of fuels. The weakest points of existing DKMs are incomplete information about the reaction types that can be involved in the potential energy surfaces (PESs) in pyrolysis and oxidation processes. Also, the computational thermodynamic parameters available in the literature vary widely with the level of theory employed. More sophisticated models require improvement both in our knowledge of the type of the reactions involved and the consistency of thermodynamic and kinetic parameters. In this paper, we aim to address these issues by developing ab initio models that can be used to describe early stages of pyrolysis of C1-C3 hydrocarbons. We applied a recently developed global reaction route mapping (GRRM) strategy to systematically investigate the PES of the pyrolysis of C1-C3 hydrocarbons at a consistent level of theory. The reactions are classified into 14 reaction types. The critical points on the PES for all reactions in the network are calculated at the highly accurate UCCSD(T)-F12b/cc-pVTZ//UM06-2X/cc-pVTZ level of theory. The data reported in this paper can be used for first principle calculations of kinetic constants and for a subsequent study on modeling the evolution of the species from the reaction network of the pyrolysis and oxidation of C1-C3 hydrocarbons.

  7. Comparing the Life Cycle Energy Consumption, Global ...

    EPA Pesticide Factsheets

    Managing the water-energy-nutrient nexus for the built environment requires, in part, a full system analysis of energy consumption, global warming and eutrophication potentials of municipal water services. As an example, we evaluated the life cycle energy use, greenhouse gas (GHG) emissions and aqueous nutrient releases of the whole anthropogenic municipal water cycle starting from raw water extraction to wastewater treatment and reuse/discharge for five municipal water and wastewater systems. The assessed options included conventional centralized services and four alternative options following the principles of source-separation and water fit-for-purpose. The comparative life cycle assessment identified that centralized drinking water supply coupled with blackwater energy recovery and on-site greywater treatment and reuse was the most energyand carbon-efficient water service system evaluated, while the conventional (drinking water and sewerage) centralized system ranked as the most energy- and carbon-intensive system. The electricity generated from blackwater and food residuals co-digestion was estimated to offset at least 40% of life cycle energy consumption for water/waste services. The dry composting toilet option demonstrated the lowest life cycle eutrophication potential. The nutrients in wastewater effluent are the dominating contributors for the eutrophication potential for the assessed system configurations. Among the parameters for which variability

  8. Comparing the Life Cycle Energy Consumption, Global ...

    EPA Pesticide Factsheets

    Managing the water-energy-nutrient nexus for the built environment requires, in part, a full system analysis of energy consumption, global warming and eutrophication potentials of municipal water services. As an example, we evaluated the life cycle energy use, greenhouse gas (GHG) emissions and aqueous nutrient releases of the whole anthropogenic municipal water cycle starting from raw water extraction to wastewater treatment and reuse/discharge for five municipal water and wastewater systems. The assessed options included conventional centralized services and four alternative options following the principles of source-separation and water fit-for-purpose. The comparative life cycle assessment identified that centralized drinking water supply coupled with blackwater energy recovery and on-site greywater treatment and reuse was the most energyand carbon-efficient water service system evaluated, while the conventional (drinking water and sewerage) centralized system ranked as the most energy- and carbon-intensive system. The electricity generated from blackwater and food residuals co-digestion was estimated to offset at least 40% of life cycle energy consumption for water/waste services. The dry composting toilet option demonstrated the lowest life cycle eutrophication potential. The nutrients in wastewater effluent are the dominating contributors for the eutrophication potential for the assessed system configurations. Among the parameters for which variability

  9. Global Effects of Increased Use of Energy

    ERIC Educational Resources Information Center

    Weinberg, Alvin M.; Hammond, R. Philip

    1972-01-01

    This paper, which speculates on the effects of man's energy releases on world climate, concludes that global upsets are very unlikely if we are able to distribute the energy widely or into the sea. (AL)

  10. Global Energy: Supply, Demand, Consequences, Opportunities

    ScienceCinema

    Majumdar, Arun

    2016-07-12

    July 29, 2008 Berkeley Lab lecture: Arun Majumdar, Director of the Environmental Energy Technologies Division, discusses current and future projections of economic growth, population, and global energy demand and supply, and explores the implications of these trends for the environment.

  11. Global Energy: Supply, Demand, Consequences, Opportunities

    SciTech Connect

    Majumdar, Arun

    2008-08-14

    July 29, 2008 Berkeley Lab lecture: Arun Majumdar, Director of the Environmental Energy Technologies Division, discusses current and future projections of economic growth, population, and global energy demand and supply, and explores the implications of these trends for the environment.

  12. Method Forecasts Global Energy Substitution

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1975

    1975-01-01

    Describes a model developed to forecast energy demands and determine trends in demand for primary fuels. The energy model essentially considers primary energy sources as competing commodities in a market. (MLH)

  13. DOE Global Energy Storage Database

    DOE Data Explorer

    The DOE International Energy Storage Database has more than 400 documented energy storage projects from 34 countries around the world. The database provides free, up-to-date information on grid-connected energy storage projects and relevant state and federal policies. More than 50 energy storage technologies are represented worldwide, including multiple battery technologies, compressed air energy storage, flywheels, gravel energy storage, hydrogen energy storage, pumped hydroelectric, superconducting magnetic energy storage, and thermal energy storage. The policy section of the database shows 18 federal and state policies addressing grid-connected energy storage, from rules and regulations to tariffs and other financial incentives. It is funded through DOE’s Sandia National Laboratories, and has been operating since January 2012.

  14. Ab initio calculation of a global potential, vibrational energies, and wave functions for HCN/HNC, and a simulation of the (A-tilde)-(X-tilde) emission spectrum

    NASA Technical Reports Server (NTRS)

    Bowman, Joel M.; Gazdy, Bela; Bentley, Joseph A.; Lee, Timothy J.; Dateo, Christopher E.

    1993-01-01

    A potential energy surface for the HCN/HNC system which is a fit to extensive, high-quality ab initio, coupled-cluster calculations is presented. All HCN and HNC states with energies below the energy of the first delocalized state are reported and characterized. Vibrational transition energies are compared with all available experimental data on HCN and HNC, including high CH-overtone states up to 23,063/cm. A simulation of the (A-tilde)-(X-tilde) stimulated emission pumping (SEP) spectrum is also reported, and the results are compared to experiment. Franck-Condon factors are reported for odd bending states of HCN, with one quantum of vibrational angular momentum, in order to compare with the recent assignment by Jonas et al. (1992), on the basis of axis-switching arguments of a number of previously unassigned states in the SEP spectrum.

  15. Ab initio calculation of a global potential, vibrational energies, and wave functions for HCN/HNC, and a simulation of the (A-tilde)-(X-tilde) emission spectrum

    NASA Technical Reports Server (NTRS)

    Bowman, Joel M.; Gazdy, Bela; Bentley, Joseph A.; Lee, Timothy J.; Dateo, Christopher E.

    1993-01-01

    A potential energy surface for the HCN/HNC system which is a fit to extensive, high-quality ab initio, coupled-cluster calculations is presented. All HCN and HNC states with energies below the energy of the first delocalized state are reported and characterized. Vibrational transition energies are compared with all available experimental data on HCN and HNC, including high CH-overtone states up to 23,063/cm. A simulation of the (A-tilde)-(X-tilde) stimulated emission pumping (SEP) spectrum is also reported, and the results are compared to experiment. Franck-Condon factors are reported for odd bending states of HCN, with one quantum of vibrational angular momentum, in order to compare with the recent assignment by Jonas et al. (1992), on the basis of axis-switching arguments of a number of previously unassigned states in the SEP spectrum.

  16. Situational Influences upon Children's Beliefs about Global Warming and Energy

    ERIC Educational Resources Information Center

    Devine-Wright, Patrick; Devine-Wright, Hannah; Fleming, Paul

    2004-01-01

    This paper explores children's beliefs about global warming and energy sources from a psychological perspective, focusing upon situational influences upon subjective beliefs, including perceived self-efficacy. The context of the research is one of growing concern at the potential impacts of global warming, yet demonstrably low levels of…

  17. Situational Influences upon Children's Beliefs about Global Warming and Energy

    ERIC Educational Resources Information Center

    Devine-Wright, Patrick; Devine-Wright, Hannah; Fleming, Paul

    2004-01-01

    This paper explores children's beliefs about global warming and energy sources from a psychological perspective, focusing upon situational influences upon subjective beliefs, including perceived self-efficacy. The context of the research is one of growing concern at the potential impacts of global warming, yet demonstrably low levels of…

  18. Global diabatic potential energy surfaces and quantum dynamical studies for the Li(2p) + H2(X(1)Σ(+)g) → LiH(X(1)Σ(+)) + H reaction.

    PubMed

    He, Di; Yuan, Jiuchuang; Li, Huixing; Chen, Maodu

    2016-04-29

    The global diabatic potential energy surfaces which are correlated with the ground state 1A' and the excited state 2A' of the Li(2p) + H2 reaction are presented in this study. The multi-reference configuration interaction method and large basis sets (aug-cc-pVQZ for H atom and cc-pwCVQZ for Li atom) were employed in the ab initio single-point energy calculations. The diabatic potential energies were generated by the diabatization scheme based on transition dipole moment operators. The neural network method was utilized to fit the matrix elements of the diabatic energy surfaces, and the root mean square errors were extremely small (3.69 meV for , 5.34 meV for and 5.06 meV for ). The topographical features of the diabatic potential energy surfaces were characterized and the surfaces were found to be sufficiently smooth for the dynamical calculation. The crossing seam of the conical intersections between the and surfaces were pinpointed. Based on this new analytical diabatic potential energy surfaces, time-dependent wave packet calculation were conducted to investigate the mechanism of the title reaction. At low collision energies, the product LiH molecule tends to forward scattering, while at high collision energies, the forward and backward scatterings exist simultaneously.

  19. Global diabatic potential energy surfaces and quantum dynamical studies for the Li(2p) + H2(X1Σ+g) → LiH(X1Σ+) + H reaction

    PubMed Central

    He, Di; Yuan, Jiuchuang; Li, Huixing; Chen, Maodu

    2016-01-01

    The global diabatic potential energy surfaces which are correlated with the ground state 1A′ and the excited state 2A′ of the Li(2p) + H2 reaction are presented in this study. The multi-reference configuration interaction method and large basis sets (aug-cc-pVQZ for H atom and cc-pwCVQZ for Li atom) were employed in the ab initio single-point energy calculations. The diabatic potential energies were generated by the diabatization scheme based on transition dipole moment operators. The neural network method was utilized to fit the matrix elements of the diabatic energy surfaces, and the root mean square errors were extremely small (3.69 meV for , 5.34 meV for and 5.06 meV for ). The topographical features of the diabatic potential energy surfaces were characterized and the surfaces were found to be sufficiently smooth for the dynamical calculation. The crossing seam of the conical intersections between the and surfaces were pinpointed. Based on this new analytical diabatic potential energy surfaces, time-dependent wave packet calculation were conducted to investigate the mechanism of the title reaction. At low collision energies, the product LiH molecule tends to forward scattering, while at high collision energies, the forward and backward scatterings exist simultaneously. PMID:27125781

  20. Global optical model potential for A=3 projectiles

    NASA Astrophysics Data System (ADS)

    Pang, D. Y.; Roussel-Chomaz, P.; Savajols, H.; Varner, R. L.; Wolski, R.

    2009-02-01

    A global optical model potential (GDP08) for He3 projectiles has been obtained by simultaneously fitting the elastic scattering data of He3 from targets of 40⩽AT⩽209 at incident energies of 30⩽Einc⩽217 MeV. Uncertainties and correlation coefficients between the global potential parameters were obtained by using the bootstrap statistical method. GDP08 was found to satisfactorily account for the elastic scattering of H3 as well, which makes it a global optical potential for the A=3 nuclei. Optical model calculations using the GDP08 global potential are compared with the experimental angular distributions of differential cross sections for He3-nucleus and H3-nucleus scattering from different targets of 6⩽AT⩽232 at incident energies of 4⩽Einc⩽450 MeV. The optical potential for the doubly-magic nucleus Ca40, the low-energy correction to the real potential for nuclei with 58≲AT≲120 at Einc<30 MeV, the comparison with double-folding model calculations and the CH89 potential, and the spin-orbit potential parameters are discussed.

  1. The Global Energy Balance of Titan

    NASA Technical Reports Server (NTRS)

    Li, Liming; Nixon, Conor A.; Achterberg, Richard K.; Smith, Mark A.; Gorius, Nicolas J. P.; Jiang, Xun; Conrath, Barney J.; Gierasch, Peter J.; Simon-Miller, Amy A.; Flasar, F. Michael; hide

    2011-01-01

    We report the first measurement of the global emitted power of Titan. Longterm (2004-2010) observations conducted by the Composite Infrared Spectrometer (CIRS) onboard Cassini reveal that the total emitted power by Titan is (2.84 plus or minus 0.01) x 10(exp 8) watts. Together with previous measurements of the global absorbed solar power of Titan, the CIRS measurements indicate that the global energy budget of Titan is in equilibrium within measurement error. The uncertainty in the absorbed solar energy places an upper limit on the energy imbalance of 5.3%.

  2. Penetration of hydrogen-based energy system and its potential for causing global environmental change: Scoping risk analysis based on life cycle thinking

    SciTech Connect

    Kikuchi, Ryunosuke . E-mail: kikuchi@mail.esac.pt

    2006-03-15

    A hydrogen-based economy seems superficially to be environmentally friendly, and many people have worked toward its realization. Today hydrogen is mainly produced by decarbonizing fossil fuels (e.g. natural gas), and in the future decarbonization of both fossil fuels and biomass will play a leading role in the production of hydrogen. The main purpose of this paper is to suggest the identification of potential environmental risks in terms of 'life cycle thinking' (which considers all aspects from production to utilization) with regard to the hydrogen-based economy to come. Hydrogen production by decarbonization results in CO{sub 2} emissions. The final destination of the recovered CO{sub 2} is uncertain. Furthermore, there is a possibility that hydrogen molecules will escape to the atmosphere, posing risks that could occasion global environmental changes such as depletion of stratospheric ozone, temperature change in the stratosphere and change of the hydrides cycle through global vaporization. Based on the results of simulation, requirements regarding the following items are proposed to minimize potential risks: hydrogen source, production and storage loss.

  3. LHC Physics Potential versus Energy

    SciTech Connect

    Quigg, Chris; /Fermilab

    2009-08-01

    Parton luminosities are convenient for estimating how the physics potential of Large Hadron Collider experiments depends on the energy of the proton beams. I present parton luminosities, ratios of parton luminosities, and contours of fixed parton luminosity for gg, u{bar d}, and qq interactions over the energy range relevant to the Large Hadron Collider, along with example analyses for specific processes.

  4. Energy potential of geothermal energy in Germany

    SciTech Connect

    Kayser, M.; Kaltschmitt, M.

    2000-06-01

    The use of terrestrial heat could fulfill certain energy demands. For the evaluation of the possibilities in the energy system of Germany, the available potentials are one of the most important criteria. Within this context, in the past only the available resources and the reserves have been discussed. But these data have hardly practical relevance for the energy-political and energy-economic discussions, since they do not consider the conditions in the corresponding energy system. In this article, therefore, explanations additional to the overall existing amount of heat in underground portions are shown, which could be used also from a technical point of view. In addition, the demand-side restrictions are considered and the share of the available heat is pointed out which can be used within the energy system of Germany. The explanations show that consideration of the demand side is necessary to make relevant statements. The investigations also make clear that terrestrial heat will never be able to cover more than just a part of the energy demand for warmth in Germany.

  5. Global Λ polarization in high energy collisions

    NASA Astrophysics Data System (ADS)

    Xie, Yilong; Wang, Dujuan; Csernai, László P.

    2017-03-01

    With a Yang-Mills flux-tube initial state and a high-resolution (3+1)D particle-in-cell relativistic (PICR) hydrodynamics simulation, we calculate the Λ polarization for different energies. The origination of polarization in high energy collisions is discussed, and we find linear impact parameter dependence of the global Λ polarization. Furthermore, the global Λ polarization in our model decreases very quickly in the low energy domain, and the decline curve fits well the recent results of Beam Energy Scan (BES) program launched by the STAR Collaboration at the Relativistic Heavy Ion Collider (RHIC). The time evolution of polarization is also discussed.

  6. Systematic high-resolution assessment of global hydropower potential

    PubMed Central

    van de Giesen, Nick C.

    2017-01-01

    Population growth, increasing energy demand and the depletion of fossil fuel reserves necessitate a search for sustainable alternatives for electricity generation. Hydropower could replace a large part of the contribution of gas and oil to the present energy mix. However, previous high-resolution estimates of hydropower potential have been local, and have yet to be applied on a global scale. This study is the first to formally present a detailed evaluation of the hydropower potential of each location, based on slope and discharge of each river in the world. The gross theoretical hydropower potential is approximately 52 PWh/year divided over 11.8 million locations. This 52 PWh/year is equal to 33% of the annually required energy, while the present energy production by hydropower plants is just 3% of the annually required energy. The results of this study: all potentially interesting locations for hydroelectric power plants, are available online. PMID:28178329

  7. Systematic high-resolution assessment of global hydropower potential.

    PubMed

    Hoes, Olivier A C; Meijer, Lourens J J; van der Ent, Ruud J; van de Giesen, Nick C

    2017-01-01

    Population growth, increasing energy demand and the depletion of fossil fuel reserves necessitate a search for sustainable alternatives for electricity generation. Hydropower could replace a large part of the contribution of gas and oil to the present energy mix. However, previous high-resolution estimates of hydropower potential have been local, and have yet to be applied on a global scale. This study is the first to formally present a detailed evaluation of the hydropower potential of each location, based on slope and discharge of each river in the world. The gross theoretical hydropower potential is approximately 52 PWh/year divided over 11.8 million locations. This 52 PWh/year is equal to 33% of the annually required energy, while the present energy production by hydropower plants is just 3% of the annually required energy. The results of this study: all potentially interesting locations for hydroelectric power plants, are available online.

  8. Global sensitivity analysis in wind energy assessment

    NASA Astrophysics Data System (ADS)

    Tsvetkova, O.; Ouarda, T. B.

    2012-12-01

    Wind energy is one of the most promising renewable energy sources. Nevertheless, it is not yet a common source of energy, although there is enough wind potential to supply world's energy demand. One of the most prominent obstacles on the way of employing wind energy is the uncertainty associated with wind energy assessment. Global sensitivity analysis (SA) studies how the variation of input parameters in an abstract model effects the variation of the variable of interest or the output variable. It also provides ways to calculate explicit measures of importance of input variables (first order and total effect sensitivity indices) in regard to influence on the variation of the output variable. Two methods of determining the above mentioned indices were applied and compared: the brute force method and the best practice estimation procedure In this study a methodology for conducting global SA of wind energy assessment at a planning stage is proposed. Three sampling strategies which are a part of SA procedure were compared: sampling based on Sobol' sequences (SBSS), Latin hypercube sampling (LHS) and pseudo-random sampling (PRS). A case study of Masdar City, a showcase of sustainable living in the UAE, is used to exemplify application of the proposed methodology. Sources of uncertainty in wind energy assessment are very diverse. In the case study the following were identified as uncertain input parameters: the Weibull shape parameter, the Weibull scale parameter, availability of a wind turbine, lifetime of a turbine, air density, electrical losses, blade losses, ineffective time losses. Ineffective time losses are defined as losses during the time when the actual wind speed is lower than the cut-in speed or higher than the cut-out speed. The output variable in the case study is the lifetime energy production. Most influential factors for lifetime energy production are identified with the ranking of the total effect sensitivity indices. The results of the present

  9. Relativity, potential energy, and mass

    NASA Astrophysics Data System (ADS)

    Hecht, Eugene

    2016-11-01

    This paper is an exploration of the concept of energy, illuminated by the transformative insights of the special theory of relativity. Focusing on potential energy (PE), it will be shown that PE as presently defined is in conflict with the tenets of special relativity. Even though PE remains an indispensable theoretical device its actual physicality is questionable. Moreover its ontological status is quite different from that of both kinetic energy and mass, a significant point that is not widely appreciated. We will establish that PE is a theoretical concept as opposed to an empirical one; it is a descriptor of mass-energy without a detectable physical presence of its own. PE is a measure of energy stored, it is not the energy stored.

  10. Global Energy and Aviation Concerns

    NASA Technical Reports Server (NTRS)

    Hendricks, Robert C.; Daggett, Dave; Anast, Peter; Lowery, Nathan

    2006-01-01

    Renewable energy sources are usually diffuse and require large facilities. Biofuels work better, are more economical to produce for ground transportation, but sharply increase competition for food croplands. Noble laureate Richard Smalley (deceased-2005) conceptual 20 TWe power generation covers hundreds x hundreds of miles. Combined with Fuller s superconducting power grid system would enable renewable planetary energy. A solar-wind project in Australia will have a 7km diameter collector interfacing with a 1 km tower to extract 200 MW from wind turbines mounted at the base. GE Energy s 3.5MW Wind Turbine is large and placing this in perspective, it is as if one were rotating a Boeing 747-200; the blade diameter is that large. Wind turbines are rapidly gaining popularity in Europe and photovoltaic (PV) is expected to also expand rapidly. It becomes clear that we need (and still have time) to develop new sources of energy. Hf 178 bombarded by X-rays produces Gamma-rays for heating. The reaction stops when the X-rays stop; the half life is about 30 years and seems manageable vs 30 000 years. Water splitting needs to be perused as do ultra fast ultra intense laser applications in terms of fusion and new materials developments including new ways to strip and re-bind hydrogen into fuels. New methods and tools for development are being found in quantum mechanical applications to macro-systems and need to be developed into a set of new tool boxes for development of these new energy sources.

  11. An ab initio global potential-energy surface for NH2(A(2)A') and vibrational spectrum of the Renner-Teller A(2)A'-X(2)A" system.

    PubMed

    Zhou, Shulan; Li, Zheng; Xie, Daiqian; Lin, Shi Ying; Guo, Hua

    2009-05-14

    A global potential-energy surface for the first excited electronic state of NH(2)(A(2)A(')) has been constructed by three-dimensional cubic spline interpolation of more than 20,000 ab initio points, which were calculated at the multireference configuration-interaction level with the Davidson correction using the augmented correlation-consistent polarized valence quadruple-zeta basis set. The (J=0) vibrational energy levels for the ground (X(2)A(")) and excited (A(2)A(')) electronic states of NH(2) were calculated on our potential-energy surfaces with the diagonal Renner-Teller terms. The results show a good agreement with the experimental vibrational frequencies of NH(2) and its isotopomers.

  12. Assessment of Triton Potential Energy

    NASA Astrophysics Data System (ADS)

    Friar, J. L.; Payne, G. L.

    1995-12-01

    An assessment is made of the dominant features contributing to the triton potential energy, with the objective of understanding qualitatively their origins and sensitivities. Relativistic effects, short-range repulsion, and OPEP dominance are discussed. A determination of the importance of various regions of nucleon-nucleon separation is made numerically.

  13. Energies of Screened Coulomb Potentials.

    ERIC Educational Resources Information Center

    Lai, C. S.

    1979-01-01

    This article shows that, by applying the Hellman-Feynman theorem alone to screened Coulomb potentials, the first four coefficients in the energy series in powers of the perturbation parameter can be obtained from the unperturbed Coulomb system. (Author/HM)

  14. Analysis of Potential Energy Surfaces.

    ERIC Educational Resources Information Center

    Fernandez, G. M.; And Others

    1988-01-01

    Introduces different methodological strategies in analyzing potential energy surfaces (PES) used in chemical reactivity studies. Discusses the theory of PES and gives examples to be used for student work. Provides procedures for calculating normal coordinates and vibrational properties of an activated complex. (ML)

  15. Analysis of Potential Energy Surfaces.

    ERIC Educational Resources Information Center

    Fernandez, G. M.; And Others

    1988-01-01

    Introduces different methodological strategies in analyzing potential energy surfaces (PES) used in chemical reactivity studies. Discusses the theory of PES and gives examples to be used for student work. Provides procedures for calculating normal coordinates and vibrational properties of an activated complex. (ML)

  16. Global triplet potential energy surfaces for the N{sub 2}(X{sup 1}Σ) + O({sup 3}P) → NO(X{sup 2}Π) + N({sup 4}S) reaction

    SciTech Connect

    Lin, Wei; Varga, Zoltan; Song, Guoliang; Paukku, Yuliya; Truhlar, Donald G.

    2016-01-14

    This work presents two global triplet potential energy surfaces (PESs) for the high-energy reaction N{sub 2}(X{sup 1}Σ) + O({sup 3}P) → NO(X{sup 2}Π) + N({sup 4}S)—in particular, for the lowest energy {sup 3}A′ and {sup 3}A″ PESs. In order to obtain the energies needed for fitting analytic surfaces, we carried out multireference configuration interaction (MRCI) calculations based on wave functions obtained from state-averaged complete active space self-consistent field calculations for 2280 geometries for the three lowest {sup 3}A″ states and for 2298 geometries for the three lowest {sup 3}A′ states. The lowest-energy {sup 3}A′ and {sup 3}A″ states at each of these geometries were then improved by applying the dynamically scaled external correlation (DSEC) method to all MRCI points, and the resulting DSEC energies were used for construction of the ground-state PES for each symmetry. The many-body component of the DSEC energies for the three-dimensional {sup 3}A′ and {sup 3}A″ PESs was then least-squares fitted in terms of permutationally invariant polynomials in mixed exponential–Gaussian bond order variables. The global and local minima as well as the transition structures of both the {sup 3}A′ and the {sup 3}A″ analytic PES were explored. In agreement with previous work, we find that the reverse reaction is barrierless on the {sup 3}A″ surface along the minimum energy pathway. However, we have explored several new local minima and transition structures on the {sup 3}A′ PES. Furthermore, based on the newly found minima and transition structures, two independent reaction mechanisms have been illustrated for the reaction path on the {sup 3}A′ PES. The analytic surfaces may be used for dynamics calculations of electronically adiabatic reactive scattering and energy transfer.

  17. Hydrogen based global renewable energy network

    SciTech Connect

    Akai, Makoto

    1993-12-31

    In the last quarter of this century, global environmental problem has emerged as a major scientific, political and social issue. Specific Problems include: depletion of ozone layer by chlorofluorocarbons (CFCs), acid rain, destruction of tropical forests and desertification, pollution of the sea and global wanning due to the greenhouse effect by carbon dioxide and others. Among these problems, particular attention of the world has been focused on the global warming because it has direct linkage to energy consumption which our economic development depends on so far. On the other hand, the future program of The Sunshine Project for alternative energy technology R&D, The Moonlight Project for energy conservation technology R&D, and The Global Environmental Technology Program for environmental problem mitigating technology R&D which are Japan`s national projects being promoted by their Agency of Industrial Science and Technology (AIST) in the Ministry of International Trade and Industry have been reexamined in view of recent changes in the situations surrounding new energy technology. In this regard, The New Sunshine Program will be established by integrating these three activities to accelerate R&D in the field of energy and environmental technologies. In the reexamination, additional stress has been laid on the contribution to solving global environmental problem through development of clean renewable energies which constitute a major part of the {open_quotes}New Earth 21{close_quotes}, a comprehensive, long-term and international cooperative program proposed by MITI. The present paper discusses the results of feasibility study on hydrogen energy system leading to the concept of WE-NET following a brief summary on R&D status on solar and wind energy in Japan.

  18. Potential effects on health of global warming

    SciTech Connect

    Haines, A. . Whittington Hospital); Parry, M. . Environmental Change Unit)

    1993-12-01

    Prediction of the impacts of global climate change on health is complicated by a number of factors. These include: the difficulty in predicting regional changes in climate, the capacity for adaptation to climate change, the interactions between the effects of global climate change and a number of other key determinants of health, including population growth and poverty, and the availability of adequate preventive and curative facilities for diseases that may be effected by climate change. Nevertheless, it is of importance to consider the potential health impacts of global climate change for a number of reasons. It is also important to monitor diseases which could be effected by climate change in order to detect changes in incidence as early as possible and study possible interactions with other factors. It seems likely that the possible impacts on health of climate change will be a major determinant of the degree to which policies aimed at reducing global warming are followed, as perceptions of the effect of climate change to human health and well-being are particularly likely to influence public opinion. The potential health impacts of climate change can be divided into direct (primary) and indirect (secondary and tertiary) effects. Primary effects are those related to the effect of temperature on human well-being and disease. Secondary effects include the impacts on health of changes in food production, availability of water and of sea level rise. A tertiary level of impacts can also be hypothesized.

  19. Computed potential energy surfaces for chemical reactions

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.; Levin, Eugene

    1993-01-01

    A new global potential energy surface (PES) is being generated for O(P-3) + H2 yields OH + H. This surface is being fit using the rotated Morse oscillator method, which was used to fit the previous POL-CI surface. The new surface is expected to be more accurate and also includes a much more complete sampling of bent geometries. A new study has been undertaken of the reaction N + O2 yields NO + O. The new studies have focused on the region of the surface near a possible minimum corresponding to the peroxy form of NOO. A large portion of the PES for this second reaction has been mapped out. Since state to state cross sections for the reaction are important in the chemistry of high temperature air, these studies will probably be extended to permit generation of a new global potential for reaction.

  20. California Industrial Energy Efficiency Potential

    SciTech Connect

    Coito, Fred; Worrell, Ernst; Price, Lynn; Masanet, Eric; RafaelFriedmann; Rufo, Mike

    2005-06-01

    This paper presents an overview of the modeling approach andhighlights key findings of a California industrial energy efficiencypotential study. In addition to providing estimates of technical andeconomic potential, the study examines achievable program potential undervarious program-funding scenarios. The focus is on electricity andnatural gas savings for manufacturing in the service territories ofCalifornia's investor-owned utilities (IOUs). The assessment is conductedby industry type and by end use. Both crosscutting technologies andindustry-specific process measures are examined. Measure penetration intothe marketplace is modeled as a function of customer awareness, measurecost effectiveness, and perceived market barriers. Data for the studycomes from a variety of sources, including: utility billing records, theEnergy Information Association (EIA) Manufacturing Energy ConsumptionSurvey (MECS), state-sponsored avoided cost studies, energy efficiencyprogram filings, and technology savings and cost data developed throughLawrence Berkeley National Laboratory (LBNL). The study identifies 1,706GWh and 47 Mth (million therms) per year of achievable potential over thenext twelve years under recent levels of program expenditures, accountingfor 5.2 percent of industrial electricity consumption and 1.3 percent ofindustrial natural gas consumption. These estimates grow to 2,748 GWh and192 Mth per year if all cost-effective and achievable opportunities arepursued. Key industrial electricity end uses, in terms of energy savingspotential, include compressed air and pumping systems that combine toaccount for about half of the total achievable potential estimates. Fornatural gas, savings are concentrated in the boiler and process heatingend uses, accounting for over 99 percent to total achievablepotential.

  1. Examining the Potential of Renewable Energy

    SciTech Connect

    Not Available

    2006-09-01

    This outreach document goes to potential partners for NREL's Renewable Energy Potential Initiative, which will explore the long-term potential of Renewable Energy to meet a substantial share of U.S. energy needs.

  2. Halocarbon ozone depletion and global warming potentials

    NASA Technical Reports Server (NTRS)

    Cox, Richard A.; Wuebbles, D.; Atkinson, R.; Connell, Peter S.; Dorn, H. P.; Derudder, A.; Derwent, Richard G.; Fehsenfeld, F. C.; Fisher, D.; Isaksen, Ivar S. A.

    1990-01-01

    Concern over the global environmental consequences of fully halogenated chlorofluorocarbons (CFCs) has created a need to determine the potential impacts of other halogenated organic compounds on stratospheric ozone and climate. The CFCs, which do not contain an H atom, are not oxidized or photolyzed in the troposphere. These compounds are transported into the stratosphere where they decompose and can lead to chlorine catalyzed ozone depletion. The hydrochlorofluorocarbons (HCFCs or HFCs), in particular those proposed as substitutes for CFCs, contain at least one hydrogen atom in the molecule, which confers on these compounds a much greater sensitivity toward oxidation by hydroxyl radicals in the troposphere, resulting in much shorter atmospheric lifetimes than CFCs, and consequently lower potential for depleting ozone. The available information is reviewed which relates to the lifetime of these compounds (HCFCs and HFCs) in the troposphere, and up-to-date assessments are reported of the potential relative effects of CFCs, HCFCs, HFCs, and halons on stratospheric ozone and global climate (through 'greenhouse' global warming).

  3. The potential of renewable energy

    SciTech Connect

    Not Available

    1990-03-01

    On June 27 and 28, 1989, the US Department of Energy (DOE) national laboratories were convened to discuss plans for the development of a National Energy Strategy (NES) and, in particular, the analytic needs in support of NES that could be addressed by the laboratories. As a result of that meeting, interlaboratory teams were formed to produce analytic white papers on key topics, and a lead laboratory was designated for each core laboratory team. The broad-ranging renewables assignment is summarized by the following issue statement from the Office of Policy, Planning and Analysis: to what extent can renewable energy technologies contribute to diversifying sources of energy supply What are the major barriers to greater renewable energy use and what is the potential timing of widespread commercialization for various categories of applications This report presents the results of the intensive activity initiated by the June 1989 meeting to produce a white paper on renewable energy. Scores of scientists, analysts, and engineers in the five core laboratories gave generously of their time over the past eight months to produce this document. Their generous, constructive efforts are hereby gratefully acknowledged. 126 refs., 44 figs., 32 tabs.

  4. Global energy consumption for direct water use

    NASA Astrophysics Data System (ADS)

    Liu, Y.; Hejazi, M. I.; Kim, S. H.; Kyle, P.; Davies, E. G.; Miralles, D. G.; Teuling, R.; He, Y.; Niyogi, D.

    2015-12-01

    Despite significant efforts to quantify the mutual inter-dependence of the water and energy sectors, global energy for water (EFW) remains poorly understood, resulting in biases in energy accounting that directly affect water and energy management and policy. We firstly evaluate the global energy consumption for direct water use from 1973 to 2012 with sectoral, regional and process-level details. Over the 40-year period, we detected multiple shifts in EFW by county and region. For example, we find that India, the Middle East and China have surpassed the United States as the three largest consumers of EFW since 2003, mostly because of rapid growth in groundwater-based irrigation, desalination, and industrial and municipal water use, respectively. Globally, EFW accounts for 1-3% of total primary energy consumption in 2010, of which 52% is surface water, 36% is groundwater, and 12% is non-fresh water. The sectoral allocation of EFW includes municipal (45%), industrial (29%), and agricultural use (26%), and process-level contributions are from source/conveyance (41%), water purification (19%), water distribution (13%) and wastewater treatment (22%). Our evaluation suggests that the EFW may increase in importance in the future due to growth in population and income, and depletion of surface and shallow aquifer water resources in water-scarce regions. We are incorporating this element into an integrated assessment model (IAM) and linking it back to energy balance within that IAM. By doing this, we will then explore the impacts of EFW on the global energy market (e.g., changes in the share of groundwater use and desalination), and the uncertainty of future EFW under different shared social pathway (SSP) and representative concentration pathway (RCP) scenarios, and consequences on the emission of greenhouse gases as well. We expect these EFW induced impacts will be considerable, and will then have significant implications for adaptive management and policy making.

  5. Accurate ab initio-based adiabatic global potential energy surface for the 2{sup 2}A″ state of NH{sub 2} by extrapolation to the complete basis set limit

    SciTech Connect

    Li, Y. Q.; Ma, F. C.; Sun, M. T.

    2013-10-21

    A full three-dimensional global potential energy surface is reported first time for the title system, which is important for the photodissociation processes. It is obtained using double many-body expansion theory and an extensive set of accurate ab initio energies extrapolated to the complete basis set limit. Such a work can be recommended for dynamics studies of the N({sup 2}D) + H{sub 2} reaction, a reliable theoretical treatment of the photodissociation dynamics and as building blocks for constructing the double many-body expansion potential energy surface of larger nitrogen/hydrogen containing systems. In turn, a preliminary theoretical study of the reaction N({sup 2}D)+H{sub 2}(X{sup 1}Σ{sub g}{sup +})(ν=0,j=0)→NH(a{sup 1}Δ)+H({sup 2}S) has been carried out with the method of quasi-classical trajectory on the new potential energy surface. Integral cross sections and thermal rate constants have been calculated, providing perhaps the most reliable estimate of the integral cross sections and the rate constants known thus far for such a reaction.

  6. Privatization and the globalization of energy markets

    SciTech Connect

    1996-10-01

    This report reviews recent global efforts to privatize energy resources and outlines the opportunities and challenges privatization has presented to U.S. and foreign multinational energy companies. The group of energy companies studied in this report includes the major U.S. petroleum companies and many foreign companies. The foreign companies reviewed include state-run energy enterprises, recently privatized energy enterprises, and foreign multinationals that have been privately held. The privatization of non-petroleum energy industries, such as electricity generation and transmission, natural gas transmission, and coal mining, are also discussed. Overseas investments made by electric companies, natural gas companies, and coal companies are included. The report is organized into six chapters: (1) economics of privatization; (2) petroleum privatization efforts among non-U.S. Organization for Economic Cooperation and Development nations; (3) petroleum privatization efforts in Latin America; (4) privatization in socialist and former socialist regimes; (5) privatization efforts in global electric power generation, transmission, and distribution industries; and (6) privatization and globalization of world coal.

  7. Biological soil crusts: Diminutive communities of potential global importance

    USGS Publications Warehouse

    Ferrenberg, Scott; Tucker, Colin; Reed, Sasha C.

    2017-01-01

    Biological soil crusts (biocrusts) are widespread, diverse communities of cyanobacteria, fungi, lichens, and mosses living on soil surfaces, primarily in drylands. Biocrusts can locally govern primary production, soil fertility, hydrology, and surface energy balance, with considerable variation in these functions across alternate community states. Further, these communities have been implicated in Earth system functioning via potential influences on global biogeochemistry and climate. Biocrusts are easily destroyed by disturbances and appear to be exceptionally vulnerable to warming temperatures and altered precipitation inputs, signaling possible losses of dryland functions with global change. Despite these concerns, we lack sufficient spatiotemporal data on biocrust function, cover, and community structure to confidently assess their ecological roles across the extensive dryland biome. Here, we present the case for cross-scale research and restoration efforts coupled with remote-sensing and modeling approaches that improve our collective understanding of biocrust responses to global change and the ecological roles of these diminutive communities at global scales.

  8. Global Energy and Water Budgets in MERRA

    NASA Technical Reports Server (NTRS)

    Bosilovich, Michael G.; Robertson, Franklin R.; Chen, Junye

    2010-01-01

    Reanalyses, retrospectively analyzing observations over climatological time scales, represent a merger between satellite observations and models to provide globally continuous data and have improved over several generations. Balancing the Earth s global water and energy budgets has been a focus of research for more than two decades. Models tend to their own climate while remotely sensed observations have had varying degrees of uncertainty. This study evaluates the latest NASA reanalysis, called the Modern Era Retrospective-analysis for Research and Applications (MERRA), from a global water and energy cycles perspective. MERRA was configured to provide complete budgets in its output diagnostics, including the Incremental Analysis Update (IAU), the term that represents the observations influence on the analyzed states, alongside the physical flux terms. Precipitation in reanalyses is typically sensitive to the observational analysis. For MERRA, the global mean precipitation bias and spatial variability are more comparable to merged satellite observations (GPCP and CMAP) than previous generations of reanalyses. Ocean evaporation also has a much lower value which is comparable to observed data sets. The global energy budget shows that MERRA cloud effects may be generally weak, leading to excess shortwave radiation reaching the ocean surface. Evaluating the MERRA time series of budget terms, a significant change occurs, which does not appear to be represented in observations. In 1999, the global analysis increments of water vapor changes sign from negative to positive, and primarily lead to more oceanic precipitation. This change is coincident with the beginning of AMSU radiance assimilation. Previous and current reanalyses all exhibit some sensitivity to perturbations in the observation record, and this remains a significant research topic for reanalysis development. The effect of the changing observing system is evaluated for MERRA water and energy budget terms.

  9. Global evaluation of biofuel potential from microalgae.

    PubMed

    Moody, Jeffrey W; McGinty, Christopher M; Quinn, Jason C

    2014-06-10

    In the current literature, the life cycle, technoeconomic, and resource assessments of microalgae-based biofuel production systems have relied on growth models extrapolated from laboratory-scale data, leading to a large uncertainty in results. This type of simplistic growth modeling overestimates productivity potential and fails to incorporate biological effects, geographical location, or cultivation architecture. This study uses a large-scale, validated, outdoor photobioreactor microalgae growth model based on 21 reactor- and species-specific inputs to model the growth of Nannochloropsis. This model accurately accounts for biological effects such as nutrient uptake, respiration, and temperature and uses hourly historical meteorological data to determine the current global productivity potential. Global maps of the current near-term microalgae lipid and biomass productivity were generated based on the results of annual simulations at 4,388 global locations. Maximum annual average lipid yields between 24 and 27 m(3)·ha(-1)·y(-1), corresponding to biomass yields of 13 to 15 g·m(-2)·d(-1), are possible in Australia, Brazil, Colombia, Egypt, Ethiopia, India, Kenya, and Saudi Arabia. The microalgae lipid productivity results of this study were integrated with geography-specific fuel consumption and land availability data to perform a scalability assessment. Results highlight the promising potential of microalgae-based biofuels compared with traditional terrestrial feedstocks. When water, nutrients, and CO2 are not limiting, many regions can potentially meet significant fractions of their transportation fuel requirements through microalgae production, without land resource restriction. Discussion focuses on sensitivity of monthly variability in lipid production compared with annual average yields, effects of temperature on productivity, and a comparison of results with previous published modeling assumptions.

  10. Global evaluation of biofuel potential from microalgae

    PubMed Central

    Moody, Jeffrey W.; McGinty, Christopher M.; Quinn, Jason C.

    2014-01-01

    In the current literature, the life cycle, technoeconomic, and resource assessments of microalgae-based biofuel production systems have relied on growth models extrapolated from laboratory-scale data, leading to a large uncertainty in results. This type of simplistic growth modeling overestimates productivity potential and fails to incorporate biological effects, geographical location, or cultivation architecture. This study uses a large-scale, validated, outdoor photobioreactor microalgae growth model based on 21 reactor- and species-specific inputs to model the growth of Nannochloropsis. This model accurately accounts for biological effects such as nutrient uptake, respiration, and temperature and uses hourly historical meteorological data to determine the current global productivity potential. Global maps of the current near-term microalgae lipid and biomass productivity were generated based on the results of annual simulations at 4,388 global locations. Maximum annual average lipid yields between 24 and 27 m3·ha−1·y−1, corresponding to biomass yields of 13 to 15 g·m−2·d−1, are possible in Australia, Brazil, Colombia, Egypt, Ethiopia, India, Kenya, and Saudi Arabia. The microalgae lipid productivity results of this study were integrated with geography-specific fuel consumption and land availability data to perform a scalability assessment. Results highlight the promising potential of microalgae-based biofuels compared with traditional terrestrial feedstocks. When water, nutrients, and CO2 are not limiting, many regions can potentially meet significant fractions of their transportation fuel requirements through microalgae production, without land resource restriction. Discussion focuses on sensitivity of monthly variability in lipid production compared with annual average yields, effects of temperature on productivity, and a comparison of results with previous published modeling assumptions. PMID:24912176

  11. Modeling global and regional energy futures

    NASA Astrophysics Data System (ADS)

    Rethinaraj, T. S. Gopi

    A rigorous econometric calibration of a model of energy consumption is presented using a comprehensive time series database on energy consumption and other socioeconomic indicators. The future of nuclear power in the evolving distribution of various energy sources is also examined. An important consideration for the long-term future of nuclear power concerns the rate of decline of the fraction of energy that comes from coal, which has historically declined on a global basis about linearly as a function of the cumulative use of coal. The use of fluid fossil fuels is also expected to eventually decline as the more readily extractable deposits are depleted. The investigation here is restricted to examining a comparatively simple model of the dynamics of competition between nuclear and other competing energy sources. Using a defined tropical/temperate disaggregation of the world, region-specific modeling results are presented for population growth, GDP growth, energy use, and carbon use compatible with a gradual transition to energy sustainability. Results for the fractions of energy use from various sources by grouping nine commercial primary energy sources into pairs of competing fuel categories are presented in combination with the idea of experiential learning and resource depletion. Analysis based on this division provides estimates for future evolution of the fractional shares, annual use rates, cumulative use of individual energy sources, and the economic attractiveness of spent nuclear fuel reprocessing. This unified approach helps to conceptualize and understand the dynamics of evolution of importance of various energy resources over time.

  12. Diuretic potential of energy drinks.

    PubMed

    Riesenhuber, A; Boehm, M; Posch, M; Aufricht, C

    2006-07-01

    Recent literature suggests that both caffeine and taurine can induce diuresis and natriuresis in rat and man. Although they act via different cellular mechanisms, their diuretic actions might be additive. This is of considerable interest, as several commercially available energy drinks contain both substances. In this study we examined the possible diuretic effects of caffeine and taurine in a cross-over-design in which 12 healthy male volunteers received each of 4 different test drinks (750 ml of energy drink containing 240 mg caffeine and 3 g taurine, the three other test drinks either lacked caffeine, taurine or both) after restraining from fluids for 12 h. Mixed model analyses demonstrated that urinary output and natriuresis were significantly increased by caffeine (mean differences 243 ml and 27 mmol; both p < 0.001) and that there were no such effects of taurine (mean differences 59 ml and -4 mmol). Additionally, urinary osmolarity at baseline was significantly related to the urinary output (p < 0.001). Urine osmolarity values at baseline and in the 6 h urine collection did not differ significantly between treatments. Taken together, our study demonstrates that diuretic and natriuretic effects of the tested energy drink were largely mediated by caffeine. Taurine played no significant role in the fluid balance in moderately dehydrated healthy young consumers. Consequently, the diuretic potential of energy drinks will not differ significantly from other caffeine containing beverages.

  13. A global ab initio potential energy surface for the X{sup  2}A{sup ′} ground state of the Si + OH → SiO + H reaction

    SciTech Connect

    Dayou, Fabrice; Duflot, Denis; Rivero-Santamaría, Alejandro; Monnerville, Maurice

    2013-11-28

    We report the first global potential energy surface (PES) for the X{sup  2}A{sup ′} ground electronic state of the Si({sup 3}P) + OH(X{sup 2}Π) → SiO(X{sup 1}Σ{sub g}{sup +}) + H({sup 2}S) reaction. The PES is based on a large number of ab initio energies obtained from multireference configuration interaction calculations plus Davidson correction (MRCI+Q) using basis sets of quadruple zeta quality. Corrections were applied to the ab initio energies in the reactant channel allowing a proper description of long-range interactions between Si({sup 3}P) and OH(X{sup 2}Π). An analytical representation of the global PES has been developed by means of the reproducing kernel Hilbert space method. The reaction is found barrierless. Two minima, corresponding to the SiOH and HSiO isomers, and six saddle points, among which the isomerization transition state, have been characterized on the PES. The vibrational spectra of the SiOH/HSiO radicals have been computed from second-order perturbation theory and quantum dynamics methods. The structural, energetic, and spectroscopic properties of the two isomers are in good agreement with experimental data and previous high quality calculations.

  14. Vibrational Fingerprints of Low-Lying Pt(n)P(2n) (n = 1-5) Cluster Structures from Global Optimization Based on Density Functional Theory Potential Energy Surfaces.

    PubMed

    Jedidi, Abdesslem; Li, Rui; Fornasiero, Paolo; Cavallo, Luigi; Carbonniere, Philippe

    2015-12-03

    Vibrational fingerprints of small Pt(n)P(2n) (n = 1-5) clusters were computed from their low-lying structures located from a global exploration of their DFT potential energy surfaces with the GSAM code. Five DFT methods were assessed from the CCSD(T) wavenumbers of PtP2 species and CCSD relative energies of Pt2P4 structures. The eight first Pt(n)P(2n) isomers found are reported. The vibrational computations reveal (i) the absence of clear signatures made by overtone or combination bands due to very weak mechanical and electrical anharmonicities and (ii) some significant and recurrent vibrational fingerprints in correlation with the different PP bonding situations in the Pt(n)P(2n) structures.

  15. Estimates of the global tidal range energy resource

    NASA Astrophysics Data System (ADS)

    Robins, Peter; Walkington, Ian

    2017-04-01

    Renewable energy generation through tidal lagoons and barrages is an attractive energy source due to tidal predictability and the potential for energy storage. Yet so far, the annual tidal range resource has only been estimated at relatively coarse spatial resolutions and without detailed investigation of the temporal variation from individual or aggregated sites. In this study, we estimate the theoretical tidal range resource of the northwest European shelf seas, using the 3D Regional Ocean Modelling System (ROMS) at roughly 1 km spatial resolution. Through tidal analysis of model output, we calculate the potential energy in both the rising and falling tides and, hence, show temporal variations in PE throughout the year. Based on a range of energy yield thresholds (rather than thresholds based on M2 range and water depth), we calculate the total annual theoretical resource from dual (flood and ebb) strategies. Using the FES global tidal model, which resolves tidal elevations at 1/16° resolution, the global resource was also estimated with the regions with the highest energy yield isolated. We discuss our estimates in relation to the yield that can actually be obtained mechanically, and in relation to the total energy flux of a region and the potential impacts of different lagoon scenarios on the local and far-field energy fluxes.

  16. Estimates of global dew collection potential

    NASA Astrophysics Data System (ADS)

    Vuollekoski, H.; Vogt, M.; Sinclair, V. A.; Duplissy, J.; Järvinen, H.; Kyrö, E.-M.; Makkonen, R.; Petäjä, T.; Prisle, N. L.; Räisänen, P.; Sipilä, M.; Ylhäisi, J.; Kulmala, M.

    2014-08-01

    The global potential for collecting usable water from dew on an artificial collector sheet was investigated by utilising 34 years of meteorological reanalysis data as input to a dew formation model. Dew formation was found to be frequent and common, but daily yields were mostly below 0.1 mm. Nevertheless, some water-stressed areas such as the coastal regions of northern Africa and the Arabian Peninsula show potential for large-scale dew harvesting, as the yearly yield can reach up to 100 L m-2 for a commonly used polyethylene foil. Statistically significant trends were found in the data, indicating overall changes in dew yields between ±15% over the investigated time period.

  17. Convective Available Potential Energy of World Ocean

    NASA Astrophysics Data System (ADS)

    Su, Z.; Ingersoll, A. P.; Thompson, A. F.

    2012-12-01

    Here, for the first time, we propose the concept of Ocean Convective Available Potential Energy (OCAPE), which is the maximum kinetic energy (KE) per unit seawater mass achievable by ocean convection. OCAPE occurs through a different mechanism from atmospheric CAPE, and involves the interplay of temperature and salinity on the equation of state of seawater. The thermobaric effect, which arises because the thermal coefficient of expansion increases with depth, is an important ingredient of OCAPE. We develop an accurate algorithm to calculate the OCAPE for a given temperature and salinity profile. We then validate our calculation of OCAPE by comparing it with the conversion of OCAPE to KE in a 2-D numerical model. We propose that OCAPE is an important energy source of ocean deep convection and contributes to deep water formation. OCAPE, like Atmospheric CAPE, can help predict deep convection and may also provide a useful constraint for modelling deep convection in ocean GCMs. We plot the global distribution of OCAPE using data from the World Ocean Atlas 2009 (WOA09) and see many important features. These include large values of OCAPE in the Labrador, Greenland, Weddell and Mediterranean Seas, which are consistent with our present observations and understanding, but also identify some new features like the OCAPE pattern in the Antarctic Circumpolar Current (ACC). We propose that the diagnosis of OCAPE can improve our understanding of global patterns of ocean convection and deep water formation as well as ocean stratification, the meridional overturning circulation and mixed layer processes. The background of this work is briefly introduced as below. Open-ocean deep convection can significantly modify water properties both at the ocean surface and throughout the water column (Gordon 1982). Open-ocean convection is also an important mechanism for Ocean Deep Water formation and the transport of heat, freshwater and nutrient (Marshall and Schott 1999). Open

  18. Potential energy surface of cyclooctatetraene

    NASA Astrophysics Data System (ADS)

    Andrés, José L.; Castaño, Obis; Morreale, Antonio; Palmeiro, Raul; Gomperts, Roberto

    1998-01-01

    We present a theoretical study of the cyclooctatetraene (COT) molecule. Seven COT structures are located on the singlet ground state potential energy surface. Four of them, which present D2d (tub), Cs (bicyclo[4.2.0]octa-2,4,7-triene or BOT), C2h (chair) and D4 (crown) symmetries are stable species, and the other three are transition state structures showing Cs, D4h, and D8h symmetry. We discuss the symmetry of wave functions for these stationary points. Geometries, energies, and harmonic vibrational frequencies of these structures, and energy gaps between singlet-triplet states and low-lying singlets are presented. For the planar D4h and D8h structures, Jahn-Teller and tunneling effects have also been discussed. Ring inversion, bond shifting and valence isomerization reactive channels from the tub COT conformer are discussed from the point of view of the corresponding transition state structures. Where possible, in order to lend support to this theoretical information comparisons with recent transition state spectroscopy data are made.

  19. Assessment of Global Annual Atmospheric Energy Balance from Satellite Observations

    NASA Technical Reports Server (NTRS)

    Lin, Bing; Stackhouse, Paul; Minnis, Patrick; Wielicki, Bruce A.; Hu, Yongxiang; Sun, Wenbo; Fan, Tai-Fang (Alice); Hinkelman, Laura

    2008-01-01

    Global atmospheric energy balance is one of the fundamental processes for the earth's climate system. This study uses currently available satellite data sets of radiative energy at the top of atmosphere (TOA) and surface and latent and sensible heat over oceans for the year 2000 to assess the global annual energy budget. Over land, surface radiation data are used to constrain assimilated results and to force the radiation, turbulent heat, and heat storage into balance due to a lack of observation-based turbulent heat flux estimations. Global annual means of the TOA net radiation obtained from both direct measurements and calculations are close to zero. The net radiative energy fluxes into the surface and the surface latent heat transported into the atmosphere are about 113 and 86 Watts per square meter, respectively. The estimated atmospheric and surface heat imbalances are about -8 9 Watts per square meter, values that are within the uncertainties of surface radiation and sea surface turbulent flux estimates and likely systematic biases in the analyzed observations. The potential significant additional absorption of solar radiation within the atmosphere suggested by previous studies does not appear to be required to balance the energy budget the spurious heat imbalances in the current data are much smaller (about half) than those obtained previously and debated at about a decade ago. Progress in surface radiation and oceanic turbulent heat flux estimations from satellite measurements significantly reduces the bias errors in the observed global energy budgets of the climate system.

  20. Comment on ``Long-Term Global Heating From Energy Use''

    NASA Astrophysics Data System (ADS)

    Fleming, James R.

    2008-12-01

    In a prominent article published in Tellus in 1969, Mikhail I. Budyko, with the Main Geophysical Observatory, Leningrad, Soviet Union, wrote that ``all the energy used by man is transformed into heat, the main portion of this energy being an additional source of heat as compared to the present radiation gain'' [Budyko, 1969, p. 618]. He pointed out that this heating was over and above any climate forcing from anthropogenic greenhouse gases and-since energy use was growing geometrically-it was likely to result in the retreat of the cryosphere, accompanied by excessive and potentially damaging global warming, perhaps in 200 years or less. Eric J. Chaisson, in Eos (``Long-Term Global Heating From Energy Use,'' 89(28), 253-254, 2008), does not acknowledge Budyko's research. Chaisson cites cosmic history and the history of the human species, but he provides no references to the conceptual history of the idea that human energy use could result in global heating. Budyko first published on the Earth's heat budget in 1948 and in 1998 received the Blue Planet Prize, sponsored by the Asahi Glass Foundation, for his lifetime accomplishments in quantitative climatology. His work on the energy budget of the Earth and anthropogenic influences really should have been cited (see a selection of key articles in the online National Science Digital Library, at http://wiki.nsdl.org/index.php/PALE:ClassicArticles/GlobalWarming).

  1. Potential of new machine learning methods for understanding long-term interannual variability of carbon and energy fluxes and states from site to global scale

    NASA Astrophysics Data System (ADS)

    Reichstein, M.; Jung, M.; Bodesheim, P.; Mahecha, M. D.; Gans, F.; Rodner, E.; Camps-Valls, G.; Papale, D.; Tramontana, G.; Denzler, J.; Baldocchi, D. D.

    2016-12-01

    Machine learning tools have been very successful in describing and predicting instantaneous climatic influences on the spatial and seasonal variability of biosphere-atmosphere exchange, while interannual variability is harder to model (e.g. Jung et al. 2011, JGR Biogeosciences). Here we hypothesize that innterannual variability is harder to describe for two reasons. 1) The signal-to-noise ratio in both, predictors (e.g. remote sensing) and target variables (e.g. net ecosystem exchange) is relatively weak, 2) The employed machine learning methods do not sufficiently account for dynamic lag and carry-over effects. In this presentation we can largely confirm both hypotheses: 1) We show that based on FLUXNET data and an ensemble of machine learning methods we can arrive at estimates of global NEE that correlate well with the residual land sink overall and CO2 flux inversions over latitudinal bands. Furthermore these results highlight the importance of variations in water availability for variations in carbon fluxes locally, while globally, as a scale-emergent property, tropical temperatures correlate well with the atmospheric CO2 growth rate, because of spatial anticorrelation and compensation of water availability. 2) We evidence with synthetic and real data that machine learning methods with embed dynamic memory effects of the system such as recurrent neural networks (RNNs) are able to better capture lag and carry-over effect which are caused by dynamic carbon pools in vegetation and soils. For these methods, long-term replicate observations are an essential asset.

  2. Global bioenergy potential from high-lignin agricultural residue.

    PubMed

    Mendu, Venugopal; Shearin, Tom; Campbell, J Elliott; Stork, Jozsef; Jae, Jungho; Crocker, Mark; Huber, George; DeBolt, Seth

    2012-03-06

    Almost one-quarter of the world's population has basic energy needs that are not being met. Efforts to increase renewable energy resources in developing countries where per capita energy availability is low are needed. Herein, we examine integrated dual use farming for sustained food security and agro-bioenergy development. Many nonedible crop residues are used for animal feed or reincorporated into the soil to maintain fertility. By contrast, drupe endocarp biomass represents a high-lignin feedstock that is a waste stream from food crops, such as coconut (Cocos nucifera) shell, which is nonedible, not of use for livestock feed, and not reintegrated into soil in an agricultural setting. Because of high-lignin content, endocarp biomass has optimal energy-to-weight returns, applicable to small-scale gasification for bioelectricity. Using spatial datasets for 12 principal drupe commodity groups that have notable endocarp byproduct, we examine both their potential energy contribution by decentralized gasification and relationship to regions of energy poverty. Globally, between 24 million and 31 million tons of drupe endocarp biomass is available per year, primarily driven by coconut production. Endocarp biomass used in small-scale decentralized gasification systems (15-40% efficiency) could contribute to the total energy requirement of several countries, the highest being Sri Lanka (8-30%) followed by Philippines (7-25%), Indonesia (4-13%), and India (1-3%). While representing a modest gain in global energy resources, mitigating energy poverty via decentralized renewable energy sources is proposed for rural communities in developing countries, where the greatest disparity between societal allowances exist.

  3. Global bioenergy potential from high-lignin agricultural residue

    PubMed Central

    Mendu, Venugopal; Shearin, Tom; Campbell, J. Elliott; Stork, Jozsef; Jae, Jungho; Crocker, Mark; Huber, George; DeBolt, Seth

    2012-01-01

    Almost one-quarter of the world's population has basic energy needs that are not being met. Efforts to increase renewable energy resources in developing countries where per capita energy availability is low are needed. Herein, we examine integrated dual use farming for sustained food security and agro-bioenergy development. Many nonedible crop residues are used for animal feed or reincorporated into the soil to maintain fertility. By contrast, drupe endocarp biomass represents a high-lignin feedstock that is a waste stream from food crops, such as coconut (Cocos nucifera) shell, which is nonedible, not of use for livestock feed, and not reintegrated into soil in an agricultural setting. Because of high-lignin content, endocarp biomass has optimal energy-to-weight returns, applicable to small-scale gasification for bioelectricity. Using spatial datasets for 12 principal drupe commodity groups that have notable endocarp byproduct, we examine both their potential energy contribution by decentralized gasification and relationship to regions of energy poverty. Globally, between 24 million and 31 million tons of drupe endocarp biomass is available per year, primarily driven by coconut production. Endocarp biomass used in small-scale decentralized gasification systems (15–40% efficiency) could contribute to the total energy requirement of several countries, the highest being Sri Lanka (8–30%) followed by Philippines (7–25%), Indonesia (4–13%), and India (1–3%). While representing a modest gain in global energy resources, mitigating energy poverty via decentralized renewable energy sources is proposed for rural communities in developing countries, where the greatest disparity between societal allowances exist. PMID:22355123

  4. 76 FR 30325 - Application to Export Electric Energy; E-T Global Energy, LLC

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-25

    ...] Application to Export Electric Energy; E-T Global Energy, LLC AGENCY: Office of Electricity Delivery and Energy Reliability, DOE. ACTION: Notice of application. SUMMARY: E-T Global Energy, LLC (E-T Global) has... an application from E-T Global for authority to transmit electric energy from the United States...

  5. Energy Security: Reducing Vulnerabilities to Global Energy Networks

    DTIC Science & Technology

    2009-03-01

    plug-in hybrid vehicles, promote renewable energy sources, invest in low- emission coal plants , advance technologies in bio-fuels, and begin the...Zhongyuan Petroleum Prospecting, a subsidiary of the China Petrochemical Corporation, is the primary oil firm operating in Gambella. Nigeria is the...of the global warming issues and the burning of oil, in particular, is blamed for about 42 percent of the CO2 emissions . 31 Left unchecked, the

  6. Development of an Integrated Global Energy Model

    SciTech Connect

    Krakowski, R.A.

    1999-07-08

    The primary objective of this research was to develop a forefront analysis tool for application to enhance understanding of long-term, global, nuclear-energy and nuclear-material futures. To this end, an existing economics-energy-environmental (E{sup 3}) model was adopted, modified, and elaborated to examine this problem in a multi-regional (13), long-term ({approximately}2,100) context. The E{sup 3} model so developed was applied to create a Los Alamos presence in this E{sup 3} area through ''niche analyses'' that provide input to the formulation of policies dealing with and shaping of nuclear-energy and nuclear-materials futures. Results from analyses using the E{sup 3} model have been presented at a variety of national and international conferences and workshops. Through use of the E{sup 3} model Los Alamos was afforded the opportunity to participate in a multi-national E{sup 3} study team that is examining a range of global, long-term nuclear issues under the auspices of the IAEA during the 1998-99 period . Finally, the E{sup 3} model developed under this LDRD project is being used as an important component in more recent Nuclear Material Management Systems (NMMS) project.

  7. Geothermal Energy: Tapping the Potential

    ERIC Educational Resources Information Center

    Johnson, Bill

    2008-01-01

    Ground source geothermal energy enables one to tap into the earth's stored renewable energy for heating and cooling facilities. Proper application of ground-source geothermal technology can have a dramatic impact on the efficiency and financial performance of building energy utilization (30%+). At the same time, using this alternative energy…

  8. Global warming, energy use, and economic growth

    NASA Astrophysics Data System (ADS)

    Khanna, Neha

    The dissertation comprises four papers that explore the interactions between global warming, energy use, and economic growth. While the papers are separate entities, they share the underlying theme of highlighting national differences in the growth experience and their implications for long-term energy use and climate change. The first paper provides an overview of some key economic issues in the climate change literature. In doing so, the paper critically appraises the 1995 draft report of Working Group III of the Intergovernmental Panel on Climate Change. The focus is the choice of a pure rate of time preference in the economic modeling of climate change, abatement costs differentials between developed and developing countries, and contrasting implications of standard discount rates and value of life estimates for these two country groups. The second paper develops a global model that takes account of the depletion of oil resources in the context of a geo-economic model for climate change. It is found that in the presence of non-decreasing carbon and energy intensities and declining petroleum availability, the carbon emissions trajectory is much higher than that typically projected by other models of this genre. Furthermore, by introducing price and income sensitive demand functions for fossil fuels, the model provides a framework to assess the effectiveness of fuel specific carbon taxes in reducing the COsb2 emissions trajectory. Cross-price substitution effects necessitate unrealistically high tax rates in order to lower the projected emissions trajectory to the optimal level. The economic structure of five integrated assessment models for climate change is reviewed in the third paper, with a special focus on the macroeconomic and damage assessment modules. The final paper undertakes an econometric estimation of the changing shares of capital, labour, energy, and technical change in explaining the growth patterns of 38 countries. Production elasticities vary by

  9. Energy restriction and potential energy restriction mimetics.

    PubMed

    Nikolai, Sibylle; Pallauf, Kathrin; Huebbe, Patricia; Rimbach, Gerald

    2015-12-01

    Energy restriction (ER; also known as caloric restriction) is the only nutritional intervention that has repeatedly been shown to increase lifespan in model organisms and may delay ageing in humans. In the present review we discuss current scientific literature on ER and its molecular, metabolic and hormonal effects. Moreover, criteria for the classification of substances that might induce positive ER-like changes without having to reduce energy intake are summarised. Additionally, the putative ER mimetics (ERM) 2-deoxy-d-glucose, metformin, rapamycin, resveratrol, spermidine and lipoic acid and their suggested molecular targets are discussed. While there are reports on these ERM candidates that describe lifespan extension in model organisms, data on longevity-inducing effects in higher organisms such as mice remain controversial or are missing. Furthermore, some of these candidates produce detrimental side effects such as immunosuppression or lactic acidosis, or have not been tested for safety in long-term studies. Up to now, there are no known ERM that could be recommended without limitations for use in humans.

  10. Rock climbing: A local-global algorithm to compute minimum energy and minimum free energy pathways

    NASA Astrophysics Data System (ADS)

    Templeton, Clark; Chen, Szu-Hua; Fathizadeh, Arman; Elber, Ron

    2017-10-01

    The calculation of minimum energy or minimum free energy paths is an important step in the quantitative and qualitative studies of chemical and physical processes. The computations of these coordinates present a significant challenge and have attracted considerable theoretical and computational interest. Here we present a new local-global approach to study reaction coordinates, based on a gradual optimization of an action. Like other global algorithms, it provides a path between known reactants and products, but it uses a local algorithm to extend the current path in small steps. The local-global approach does not require an initial guess to the path, a major challenge for global pathway finders. Finally, it provides an exact answer (the steepest descent path) at the end of the calculations. Numerical examples are provided for the Mueller potential and for a conformational transition in a solvated ring system.

  11. The Global Climate and Energy Project at Stanford University: Fundamental Research Towards Future Energy Technologies

    NASA Astrophysics Data System (ADS)

    Milne, Jennifer L.; Sassoon, Richard E.; Hung, Emilie; Bosshard, Paolo; Benson, Sally M.

    The Global Climate and Energy Project (GCEP), at Stanford University, invests in research with the potential to lead to energy technologies with lower greenhouse gas emissions than current energy technologies. GCEP is sponsored by four international companies, ExxonMobil, GE, Schlumberger, and Toyota and supports research programs in academic institutions worldwide. Research falls into the broad areas of carbon based energy systems, renewables, electrochemistry, and the electric grid. Within these areas research efforts are underway that are aimed at achieving break-throughs and innovations that greatly improve efficiency, performance, functionality and cost of many potential energy technologies of the future including solar, batteries, fuel cells, biofuels, hydrogen storage and carbon capture and storage. This paper presents a summary of some of GCEP's activities over the past 7 years with current research areas of interest and potential research directions in the near future.

  12. Global energy shifts: Future possibilities in historical perspective

    NASA Astrophysics Data System (ADS)

    Podobnik, Bruce Michael

    2000-11-01

    This study adopts a macro-comparative, world-systems perspective in order to shed light on the dynamics that led to a global shift away from primary reliance on coal and towards over-reliance on petroleum. It is argued that the interaction of three global dynamics, those of geopolitical rivalry, commercial competition, and social unrest, undermined the nineteenth-century international coal system and paved the way for the consolidation of an international petroleum system in the twentieth century. Specifically, the historical analysis presented in this dissertation shows that: (1) intervention by state agents was absolutely crucial in the early development and later expansion of the international petroleum system; (2) private coal companies attempted to prevent the consolidation of an oil-based energy system, but these older companies were out-competed by newer, multinational petroleum corporations; and (3) waves of labor unrest in established coal industries played a key role in prompting a relatively rapid shift away from coal and towards petroleum. Indeed, a key conclusion of this study is that pressures exerted by such social movements as labor unions, nationalist movements, and environmental coalitions have played as important a role in influencing energy trajectories as the more commonly-recognized actions of governmental and corporate actors. By examining contemporary patterns of state and private investments in a cluster of new energy technologies, as well as the growing influence of environmental regulations it is argued that global dynamics are beginning to favor a shift towards new, more environmentally sustainable energy technologies. The fuel cell is highlighted as one new energy technology that is poised to enter into widespread diffusion in the coming decades, though potentials for expansions in wind, solar, small-scale hydro-electric, and modern biomass systems are also examined. Although significant hurdles must be overcome, this study concludes by

  13. Potential of renewable and alternative energy sources

    NASA Astrophysics Data System (ADS)

    Konovalov, V.; Pogharnitskaya, O.; Rostovshchikova, A.; Matveenko, I.

    2015-11-01

    The article deals with application potential of clean alternative renewable energy sources. By means of system analysis the forecast for consumption of electrical energy in Tomsk Oblast as well as main energy sources of existing energy system have been studied up to 2018. Engineering potential of renewable and alternative energy sources is evaluated. Besides, ranking in the order of their efficiency descending is performed. It is concluded that Tomsk Oblast has high potential of alternative and renewable energy sources, among which the most promising development perspective is implementation of gasification stations to save fuel consumed by diesel power stations as well as building wind-power plants.

  14. Renewable: A key component of our global energy future

    SciTech Connect

    Hartley, D.

    1995-12-31

    Inclusion of renewable energy sources in national and international energy strategies is a key component of a viable global energy future. The global energy balance is going to shift radically in the near future brought about by significant increases in population in China and India, and increases in the energy intensity of developing countries. To better understand the consequences of such global shifts in energy requirements and to develop appropriate energy strategies to respond to these shifts, we need to look at the factors driving choices among supply options by geopolitical consumers and the impact these factors can have on the future energy mix.

  15. The global potential for carbon capture and storage from forestry.

    PubMed

    Ni, Yuanming; Eskeland, Gunnar S; Giske, Jarl; Hansen, Jan-Petter

    2016-12-01

    Discussions about limiting anthropogenic emissions of CO[Formula: see text] often focus on transition to renewable energy sources and on carbon capture and storage (CCS) of CO[Formula: see text]. The potential contributions from forests, forest products and other low-tech strategies are less frequently discussed. Here we develop a new simulation model to assess the global carbon content in forests and apply the model to study active annual carbon harvest 100 years into the future. The numerical experiments show that under a hypothetical scenario of globally sustainable forestry the world's forests could provide a large carbon sink, about one gigatonne per year, due to enhancement of carbon stock in tree biomass. In addition, a large amount of wood, 11.5 GT of carbon per year, could be extracted for reducing CO[Formula: see text] emissions by substitution of wood for fossil fuels. The results of this study indicate that carbon harvest from forests and carbon storage in living forests have a significant potential for CCS on a global scale.

  16. Global Nuclear Energy Partnership Waste Treatment Baseline

    SciTech Connect

    Dirk Gombert; William Ebert; James Marra; Robert Jubin; John Vienna

    2008-05-01

    The Global Nuclear Energy Partnership program (GNEP) is designed to demonstrate a proliferation-resistant and sustainable integrated nuclear fuel cycle that can be commercialized and used internationally. Alternative stabilization concepts for byproducts and waste streams generated by fuel recycling processes were evaluated and a baseline of waste forms was recommended for the safe disposition of waste streams. Waste forms are recommended based on the demonstrated or expected commercial practicability and technical maturity of the processes needed to make the waste forms, and performance of the waste form materials when disposed. Significant issues remain in developing technologies to process some of the wastes into the recommended waste forms, and a detailed analysis of technology readiness and availability may lead to the choice of a different waste form than what is recommended herein. Evolving regulations could also affect the selection of waste forms.

  17. Platts top 250 global energy company rankings

    SciTech Connect

    2006-11-15

    The third annual survey of global energy companies measures companies' financial performance using four metrics: asset worth, revenues, profits and return on invested capital. The following industry segments were analysed: coal and consumable fuel companies; diversified utilities; exploration and production; electric utilities; gas utilities; integrated oil and gas companies; refining and marketing; independent power producers and storage and transfer companies. Integrated oil and gas companies (IOGs) captured nine out of the top ten spots while IPPS struggled in 2005 as the sector on a whole lost money. The exploration and production segment showed financial stability while gas utilities saw their financials climb. The Exxon Mobile Corp. continued its reign of the number one spot.

  18. Beyond offshoring: assess your company's global potential.

    PubMed

    Farrell, Diana

    2004-12-01

    In the past few years, companies have become aware that they can slash costs by offshoring: moving jobs to lower-wage locations. But this practice is just the tip of the iceberg in terms of how globalization can transform industries, according to research by the McKinsey Global Institute (MGI). The institute's yearlong study suggests that by streamlining their production processes and supply chains globally, rather than just nationally or regionally, companies can lower their costs-as we've seen in the consumer-electronics and PC industries. Companies can save as much as 70% of their total costs through globalization--50% from offshoring, 5% from training and business-task redesign, and 15% from process improvements. But they don't have to stop there. The cost reductions make it possible to lower prices and expand into new markets, attracting whole new classes of customers. To date, however, few businesses have recognized the full scope of performance improvements that globalization makes possible, much less developed sound strategies for capturing those opportunities. In this article, Diana Farrell, director of MGI, offers a step-by-step approach to doing both things. Among her suggestions: Assess where your industry falls along the globalization spectrum, because not all sectors of the economy face the same challenges and opportunities at the same time. Also, pay attention to production, regulatory, and organizational barriers to globalization. If any of these can be changed, size up the cost-saving (and revenue-generating) opportunities that will emerge for your company as a result of those changes. Farrell also defines the five stages of globalization-market entry, product specialization, value chain disaggregation, value chain reengineering, and the creation of new markets-and notes the different levers for cutting costs and creating value that companies can use in each phase.

  19. Guide for Conducting Energy Efficiency Potential Studies

    EPA Pesticide Factsheets

    The Guide for Conducting Energy Efficiency Potential Studies is provided to assist state officials, regulators, legislators, and others in implementing the recommendations of the National Action Plan for Energy Efficiency.

  20. Biomass energy: the scale of the potential resource.

    PubMed

    Field, Christopher B; Campbell, J Elliott; Lobell, David B

    2008-02-01

    Increased production of biomass for energy has the potential to offset substantial use of fossil fuels, but it also has the potential to threaten conservation areas, pollute water resources and decrease food security. The net effect of biomass energy agriculture on climate could be either cooling or warming, depending on the crop, the technology for converting biomass into useable energy, and the difference in carbon stocks and reflectance of solar radiation between the biomass crop and the pre-existing vegetation. The area with the greatest potential for yielding biomass energy that reduces net warming and avoids competition with food production is land that was previously used for agriculture or pasture but that has been abandoned and not converted to forest or urban areas. At the global scale, potential above-ground plant growth on these abandoned lands has an energy content representing approximately 5% of world primary energy consumption in 2006. The global potential for biomass energy production is large in absolute terms, but it is not enough to replace more than a few percent of current fossil fuel usage. Increasing biomass energy production beyond this level would probably reduce food security and exacerbate forcing of climate change.

  1. Energy, atmospheric chemistry, and global climate

    NASA Technical Reports Server (NTRS)

    Levine, Joel S.

    1991-01-01

    Global atmospheric changes due to ozone destruction and the greenhouse effect are discussed. The work of the Intergovernmental Panel on Climate Change is reviewed, including its judgements regarding global warming and its recommendations for improving predictive capability. The chemistry of ozone destruction and the global atmospheric budget of nitrous oxide are reviewed, and the global sources of nitrous oxide are described.

  2. A Comprehensive Plan for Global Energy Revolution

    NASA Astrophysics Data System (ADS)

    Blees, T.

    2009-05-01

    There is no dearth of information regarding the grave crises faced by humanity in the 21st century. There is also growing consensus that the wholesale burning of fossil fuels must come to an end, either because of climate change or other still-salient reasons such as air pollution or major conflicts over dwindling reserves of cheaply recoverable oil and gas resources. At the same time, global demographics predict with disquieting certainty a world with up to 9 or 10 billion souls by mid-century. The vast expansion of energy consumption that this population represents, along with further increases in already-unacceptable levels of atmospheric carbon dioxide from fossil fuel burning, demands that we quickly develop almost limitless sources of clean, economical power. What is sorely lacking in the public debate are realistic solutions. Expanding wind and solar generating capacity is an important near-term goal, but neither of these technologies represents a viable solution for generating base load power at the vast scales that will be required. Energy efficiency measures are likewise well-directed, but the combination of rising population along with increasingly energy-intensive economic activity by the large fraction of Earth's current population residing in developing nations suggests that absolute energy demand will continue to rise even with radically improved energy efficiency. Fortunately we have the technologies available to provide virtually unlimited clean energy, and to utilize and recycle our resources so that everyone can improve their standard of living. The Integral Fast Reactor (IFR), developed at the Argonne National Laboratory in the 80's and 90's and currently championed by General Electric, is a technology that fills the bill on every count, and then some. IFRs are safe, environmentally clean, economical, and free of conflict over fuel supply. IFRs can safely consume as fuel the nuclear waste from the current installed base of light-water reactors

  3. A global and long-range picture of energy developments.

    PubMed

    Häfele, W

    1980-07-04

    Most studies of energy supply and demand ignore either global inter-dependence or the long time spans necessary to adjust to new energy sources. The International Institute for Applied Systems Analysis has therefore studied on a global scale, for seven major world regions, the balance between energy supply and demand for the next 50 years. Reported here are the results for two benchmark scenarios. In the "low" scenario world energy consumption increases from today's 8.2 terawatt-year per year to 22 terawatt-year per year in 2030; in the "high" scenario, consumption increases to 35 terawatt-year per year. The study showed that time will be the limiting constraint in adapting the energy supply infrastructure to changing resource availability; resources will be available until the second half of the next century, but a strong shift will be required to low-grade fossil fuels such as shale oil and tar sands. Each scenario studied indicated increased environmental problems associated with increased use of fossil fuels, and potential geopolitical problems associated with the world distribution of resources.

  4. Global mental health and neuroscience: potential synergies.

    PubMed

    Stein, Dan J; He, Yanling; Phillips, Anthony; Sahakian, Barbara J; Williams, John; Patel, Vikram

    2015-02-01

    Global mental health has emerged as an important specialty. It has drawn attention to the burden of mental illness and to the relative gap in mental health research and services around the world. Global mental health has raised the question of whether this gap is a developmental issue, a health issue, a human rights issue, or a combination of these issues-and it has raised awareness of the need to develop new approaches for building capacity, mobilising resources, and closing the research and treatment gap. Translational neuroscience has also advanced. It comprises an important conceptual approach to understanding the neurocircuitry and molecular basis of mental disorders, to rethinking how best to undertake research on the aetiology, assessment, and treatment of these disorders, with the ultimate aim to develop entirely new approaches to prevention and intervention. Some apparent contrasts exist between these fields; global mental health emphasises knowledge translation, moving away from the bedside to a focus on health systems, whereas translational neuroscience emphasises molecular neuroscience, focusing on transitions between the bench and bedside. Meanwhile, important opportunities exist for synergy between the two paradigms, to ensure that present opportunities in mental health research and services are maximised. Here, we review the approaches of global mental health and clinical neuroscience to diagnosis, pathogenesis, and intervention, and make recommendations for facilitating an integration of these two perspectives.

  5. A nine-dimensional ab initio global potential energy surface for the H{sub 2}O{sup +} + H{sub 2} → H{sub 3}O{sup +} + H reaction

    SciTech Connect

    Li, Anyang; Guo, Hua

    2014-06-14

    An accurate full-dimensional global potential energy surface (PES) is developed for the title reaction. While the long-range interactions in the reactant asymptote are represented by an analytical expression, the interaction region of the PES is fit to more than 81 000 of ab initio points at the UCCSD(T)-F12b/AVTZ level using the permutation invariant polynomial neural network approach. Fully symmetric with respect to permutation of all four hydrogen atoms, the PES provides a faithful representation of the ab initio points, with a root mean square error of 1.8 meV or 15 cm{sup −1}. The reaction path for this exoergic reaction features an attractive and barrierless entrance channel, a submerged saddle point, a shallow H{sub 4}O{sup +} well, and a barrierless exit channel. The rate coefficients for the title reaction and kinetic isotope effect have been determined on this PES using quasi-classical trajectories, and they are in good agreement with available experimental data. It is further shown that the H{sub 2}O{sup +} rotational enhancement of reactivity observed experimentally can be traced to the submerged saddle point. Using our recently proposed Sudden Vector Projection model, we demonstrate that a rotational degree of freedom of the H{sub 2}O{sup +} reactant is strongly coupled with the reaction coordinate at this saddle point, thus unraveling the origin of the pronounced mode specificity in this reaction.

  6. Energy potential of modern landfills

    SciTech Connect

    Bogner, J.E.

    1990-01-01

    Methane produced by refuse decomposition in a sanitary landfill can be recovered for commercial use. Landfill methane is currently under-utilized, with commercial recovery at only a small percentage of US landfills. New federal regulations mandating control of landfill gas migration and atmospheric emissions are providing impetus to methane recovery schemes as a means of recovering costs for increased environmental control. The benefits of landfill methane recovery include utilization of an inexpensive renewable energy resource, removal of explosive gas mixtures from the subsurface, and mitigation of observed historic increases in atmospheric methane. Increased commercial interest in landfill methane recovery is dependent on the final form of Clean Air Act amendments pertaining to gaseous emissions from landfills; market shifts in natural gas prices; financial incentives for development of renewable energy resources; and support for applied research and development to develop techniques for increased control of the gas generation process in situ. This paper will discuss the controls on methane generation in landfills. In addition, it will address how landfill regulations affect landfill design and site management practices which, in turn, influence decomposition rates. Finally, future trends in landfilling, and their relationship to gas production, will be examined. 19 refs., 2 figs., 3 tabs.

  7. Global and Regional Potential for Biofuels From Residue and Waste

    NASA Astrophysics Data System (ADS)

    Gregg, J. S.; Smith, S. J.

    2007-12-01

    As co-products, agricultural and forestry residues as well as municipal solid waste (MSW) represent potential low cost lignocellulosic biomass feedstocks for the production of second generation biofuels. For agriculture, the maximum supply is a function of crop-specific attributes (harvest index and energy content of residue) and total crop production (yield and total harvested area). For forestry, two potential residue streams are considered: residue left from timber harvesting (tree tops and branches), and residue from mills (wood scraps and sawdust). The harvest index, milling efficiencies, and energy content of wood are used to estimate the total potential supply of forestry residues. MSW is predicted as a function of GDP and the proportional waste composition indicative of various regions. Limiting factors for supply of biomass feedstock from these sources include agricultural and forest productivity, residue required to prevent soil erosion and maintain soil nutrients, and cost of aggregation and transport. Using the ObjECTS MiniCAM Integrated Assessment Model, the global role of residue biomass as a feedstock for biofuels is modeled for the next century under different climate policy scenarios.

  8. Potential Water and Energy Savings from Showerheads

    SciTech Connect

    Biermayer, Peter J.

    2005-09-28

    This paper estimates the benefits and costs of six water reduction scenarios. Benefits and costs of showerhead scenarios are ranked in this paper by an estimated water reduction percentage. To prioritize potential water and energy saving scenarios regarding showerheads, six scenarios were analyzed for their potential water and energy savings and the associated dollar savings to the consumer.

  9. Geothermal Energy Potential in Western United States

    ERIC Educational Resources Information Center

    Pryde, Philip R.

    1977-01-01

    Reviews types of geothermal energy sources in the western states, including hot brine systems and dry steam systems. Conversion to electrical energy is a major potential use of geothermal energy, although it creates environmental disruptions such as noise, corrosion, and scaling of equipment. (AV)

  10. Geothermal Energy Potential in Western United States

    ERIC Educational Resources Information Center

    Pryde, Philip R.

    1977-01-01

    Reviews types of geothermal energy sources in the western states, including hot brine systems and dry steam systems. Conversion to electrical energy is a major potential use of geothermal energy, although it creates environmental disruptions such as noise, corrosion, and scaling of equipment. (AV)

  11. Ab initio potential energy and dipole moment surfaces for CS2: determination of molecular vibrational energies.

    PubMed

    Pradhan, Ekadashi; Carreón-Macedo, José-Luis; Cuervo, Javier E; Schröder, Markus; Brown, Alex

    2013-08-15

    The ground state potential energy and dipole moment surfaces for CS2 have been determined at the CASPT2/C:cc-pVTZ,S:aug-cc-pV(T+d)Z level of theory. The potential energy surface has been fit to a sum-of-products form using the neural network method with exponential neurons. A generic interface between neural network potential energy surface fitting and the Heidelberg MCTDH software package is demonstrated. The potential energy surface has also been fit using the potfit procedure in MCTDH. For fits to the low-energy regions of the potential, the neural network method requires fewer parameters than potfit to achieve high accuracy; global fits are comparable between the two methods. Using these potential energy surfaces, the vibrational energies have been computed for the four most abundant CS2 isotopomers. These results are compared to experimental and previous theoretical data. The current potential energy surfaces are shown to accurately reproduce the low-lying vibrational energies within a few wavenumbers. Hence, the potential energy and dipole moments surfaces will be useful for future study on the control of quantum dynamics in CS2.

  12. Global Energy: Supply, Demand, Consequences, Opportunities (LBNL Summer Lecture Series)

    SciTech Connect

    Majumdar, Arun

    2008-07-29

    Summer Lecture Series 2009: Arun Majumdar, Director of the Environmental Energy Technologies Division, discusses current and future projections of economic growth, population, and global energy demand and supply, and explores the implications of these trends for the environment.

  13. Global Energy: Supply, Demand, Consequences, Opportunities (LBNL Summer Lecture Series)

    ScienceCinema

    Majumdar, Arun

    2016-07-12

    Summer Lecture Series 2009: Arun Majumdar, Director of the Environmental Energy Technologies Division, discusses current and future projections of economic growth, population, and global energy demand and supply, and explores the implications of these trends for the environment.

  14. Determinants of the Pace of Global Innovation in Energy Technologies

    DTIC Science & Technology

    2013-10-14

    SECURITY CLASSIFICATION OF: Understanding the factors driving innovation in energy technologies is of critical importance to mitigating climate change and...addressing other energy-related global challenges. Low levels of innovation , measured in terms of energy patent filings, were noted in the 1980s and...release; distribution is unlimited. Determinants of the Pace of Global Innovation in Energy Technologies The views, opinions and/or findings contained in

  15. Global assessment of livestock intensification potential

    NASA Astrophysics Data System (ADS)

    Gerber, J. S.

    2016-12-01

    Stocking densities of livestock on pasture are below attainable rates in many parts of the world. Quantifying this "yield gap" in livestock would allow for targeting of interventions to reduce land use change while meeting demand for milk and meat products. Calculating such yield gaps with semi-empirical methods is more difficult for livestock than for crops for several reasons, including the existence of overstocked areas in global datasets. Here, we use measures of NDVI to exclude regions where overstocking may be associated with pasture degradation. We then use quantile regression methods to empirically determine maps of attainable livestock stocking densities. The resulting maps are compared with maps of actual stocking densities to estimate stocking density yield gaps.

  16. Potential global jamming transition in aviation networks

    NASA Astrophysics Data System (ADS)

    Ezaki, Takahiro; Nishinari, Katsuhiro

    2014-08-01

    In this paper, we propose a nonlinear transport model for an aviation network. The takeoff rate from an airport is characterized by the degree of ground congestion. Due to the effect of surface congestion, the performance of an airport deteriorates because of inefficient configurations of waiting aircraft on the ground. Using a simple transport model, we performed simulations on a United States airport network and found a global jamming transition induced by local surface congestion. From a physical perspective, the mechanism of the transition is studied analytically and the resulting aircraft distribution is discussed considering system dynamics. This study shows that the knowledge of the relationship between a takeoff rate and a congestion level on the ground is vital for efficient air traffic operations.

  17. Potential global jamming transition in aviation networks.

    PubMed

    Ezaki, Takahiro; Nishinari, Katsuhiro

    2014-08-01

    In this paper, we propose a nonlinear transport model for an aviation network. The takeoff rate from an airport is characterized by the degree of ground congestion. Due to the effect of surface congestion, the performance of an airport deteriorates because of inefficient configurations of waiting aircraft on the ground. Using a simple transport model, we performed simulations on a United States airport network and found a global jamming transition induced by local surface congestion. From a physical perspective, the mechanism of the transition is studied analytically and the resulting aircraft distribution is discussed considering system dynamics. This study shows that the knowledge of the relationship between a takeoff rate and a congestion level on the ground is vital for efficient air traffic operations.

  18. Wave Energy Potential in the Latvian EEZ

    NASA Astrophysics Data System (ADS)

    Beriņš, J.; Beriņš, J.; Kalnačs, J.; Kalnačs, A.

    2016-06-01

    The present article deals with one of the alternative forms of energy - sea wave energy potential in the Latvian Exclusice Economic Zone (EEZ). Results have been achieved using a new method - VEVPP. Calculations have been performed using the data on wave parameters over the past five years (2010-2014). We have also considered wave energy potential in the Gulf of Riga. The conclusions have been drawn on the recommended methodology for the sea wave potential and power calculations for wave-power plant pre-design stage.

  19. KEYNOTE: Simulation, computation, and the Global Nuclear Energy Partnership

    NASA Astrophysics Data System (ADS)

    Reis, Victor, Dr.

    2006-01-01

    Dr. Victor Reis delivered the keynote talk at the closing session of the conference. The talk was forward looking and focused on the importance of advanced computing for large-scale nuclear energy goals such as Global Nuclear Energy Partnership (GNEP). Dr. Reis discussed the important connections of GNEP to the Scientific Discovery through Advanced Computing (SciDAC) program and the SciDAC research portfolio. In the context of GNEP, Dr. Reis talked about possible fuel leasing configurations, strategies for their implementation, and typical fuel cycle flow sheets. A major portion of the talk addressed lessons learnt from ‘Science Based Stockpile Stewardship’ and the Accelerated Strategic Computing Initiative (ASCI) initiative and how they can provide guidance for advancing GNEP and SciDAC goals. Dr. Reis’s colorful and informative presentation included international proverbs, quotes and comments, in tune with the international flavor that is part of the GNEP philosophy and plan. He concluded with a positive and motivating outlook for peaceful nuclear energy and its potential to solve global problems. An interview with Dr. Reis, addressing some of the above issues, is the cover story of Issue 2 of the SciDAC Review and available at http://www.scidacreview.org This summary of Dr. Reis’s PowerPoint presentation was prepared by Institute of Physics Publishing, the complete PowerPoint version of Dr. Reis’s talk at SciDAC 2006 is given as a multimedia attachment to this summary.

  20. Microfinance: untapped potential for global health.

    PubMed

    Patel, Ronak B

    2014-11-01

    Microfinance has recently come under criticism for not meeting its potential for poverty reduction and its exploitation by for-profit entities. Access to finance still remains limited for many of the world’s poor. This re-examination of microfinance should not impede its proliferation and development into a tool to improve health for the underserved. There are significant returns on microfinance investments in health at the household level. Microfinance that allows the consumption of goods and services that can improve health can also lead to increased savings and productivity making it a financially viable and powerful tool for both health improvement and development.

  1. Global energetics of solar flares. I. Magnetic energies

    SciTech Connect

    Aschwanden, Markus J.; Xu, Yan; Jing, Ju E-mail: yan.xu@njit.edu

    2014-12-10

    We present the first part of a project on the global energetics of solar flares and coronal mass ejections that includes about 400 M- and X-class flares observed with Atmospheric Imaging Assembly (AIA) and Helioseismic and Magnetic Imager (HMI) on board the Solar Dynamics Observatory (SDO). We calculate the potential (E{sub p} ), the nonpotential (E {sub np}) or free energies (E {sub free} = E {sub np} – E{sub p} ), and the flare-dissipated magnetic energies (E {sub diss}). We calculate these magnetic parameters using two different NLFFF codes: the COR-NLFFF code uses the line-of-sight magnetic field component B{sub z} from HMI to define the potential field, and the two-dimensional (2D) coordinates of automatically detected coronal loops in six coronal wavelengths from AIA to measure the helical twist of coronal loops caused by vertical currents, while the PHOT-NLFFF code extrapolates the photospheric three-dimensional (3D) vector fields. We find agreement between the two codes in the measurement of free energies and dissipated energies within a factor of ≲ 3. The size distributions of magnetic parameters exhibit powerlaw slopes that are approximately consistent with the fractal-diffusive self-organized criticality model. The magnetic parameters exhibit scaling laws for the nonpotential energy, E{sub np}∝E{sub p}{sup 1.02}, for the free energy, E{sub free}∝E{sub p}{sup 1.7} and E{sub free}∝B{sub φ}{sup 1.0}L{sup 1.5}, for the dissipated energy, E{sub diss}∝E{sub p}{sup 1.6} and E{sub diss}∝E{sub free}{sup 0.9}, and the energy dissipation volume, V∝E{sub diss}{sup 1.2}. The potential energies vary in the range of E{sub p} = 1 × 10{sup 31}-4 × 10{sup 33} erg, while the free energy has a ratio of E {sub free}/E{sub p} ≈ 1%-25%. The Poynting flux amounts to F {sub flare} ≈ 5 × 10{sup 8}-10{sup 10} erg cm{sup –2} s{sup –1} during flares, which averages to F {sub AR} ≈ 6 × 10{sup 6} erg cm{sup –2} s{sup –1} during the entire observation

  2. Wind energy in China: Estimating the potential

    NASA Astrophysics Data System (ADS)

    Yuan, Jiahai

    2016-07-01

    Persistent and significant curtailment has cast concern over the prospects of wind power in China. A comprehensive assessment of the production of energy from wind has identified grid-integrated wind generation potential at 11.9-14% of China's projected energy demand by 2030.

  3. Center Views Energy Problems on Global Basis

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1972

    1972-01-01

    The National Center for Energy Management and Power at the University of Pennsylvania is committed to advancing the technology of energy conversion and training people to manage effectively whatever form the energy industry assumes in the future, including measurement of the impact of developments on both producer and consumer. (DF)

  4. Economic Energy Savings Potential in Federal Buildings

    SciTech Connect

    Brown, Daryl R.; Dirks, James A.; Hunt, Diane M.

    2000-09-04

    The primary objective of this study was to estimate the current life-cycle cost-effective (i.e., economic) energy savings potential in Federal buildings and the corresponding capital investment required to achieve these savings, with Federal financing. Estimates were developed for major categories of energy efficiency measures such as building envelope, heating system, cooling system, and lighting. The analysis was based on conditions (building stock and characteristics, retrofit technologies, interest rates, energy prices, etc.) existing in the late 1990s. The potential impact of changes to any of these factors in the future was not considered.

  5. Bacterial energy taxis: a global strategy?

    PubMed

    Schweinitzer, Tobias; Josenhans, Christine

    2010-07-01

    A functional energy metabolism is one of the most important requirements for survival of all kinds of organisms including bacteria. Therefore, many bacteria actively seek conditions of optimal metabolic activity, a behaviour which can be termed "energy taxis". Motility, combined with the sensory perception of the internal energetic conditions, is prerequisite for tactic responses to different energy levels and metabolic yields. Diverse mechanisms of energy sensing and tactic response have evolved among various bacteria. Many of the known energy taxis sensors group among the methyl-accepting chemotaxis protein (MCP)-like sensors. This review summarizes recent advances in the field of energy taxis and explores the current concept that energy taxis is an important part of the bacterial behavioural repertoire in order to navigate towards more favourable metabolic niches and to survive in a specific habitat.

  6. Bacterial energy taxis: a global strategy?

    PubMed Central

    Schweinitzer, Tobias

    2010-01-01

    A functional energy metabolism is one of the most important requirements for survival of all kinds of organisms including bacteria. Therefore, many bacteria actively seek conditions of optimal metabolic activity, a behaviour which can be termed “energy taxis”. Motility, combined with the sensory perception of the internal energetic conditions, is prerequisite for tactic responses to different energy levels and metabolic yields. Diverse mechanisms of energy sensing and tactic response have evolved among various bacteria. Many of the known energy taxis sensors group among the methyl-accepting chemotaxis protein (MCP)-like sensors. This review summarizes recent advances in the field of energy taxis and explores the current concept that energy taxis is an important part of the bacterial behavioural repertoire in order to navigate towards more favourable metabolic niches and to survive in a specific habitat. PMID:20411245

  7. Potential of China in Global Nurse Migration

    PubMed Central

    Fang, Zhiwu Zack

    2007-01-01

    Objective The purpose of this paper is to examine what is known about the nurse workforce and nursing education in China in order to assess the likely potential for nurse migration from China in the future. Principle Findings There is a severe shortage of nurses in China (only one nurse per thousand in population), but at the same time there is a very high level of unemployment and underemployment of nurses. China's nursing education system is huge in size (about 500,000 nursing students in 2005), but weak in quality and career development. Conclusions As a result of lack of limited job opportunities, low salary, and low job satisfaction, many talented Chinese nurses intend to switch occupation or work outside China. Commercial recruiters have expressed a strong interest in recruitment of nurses in China, but to date there are few examples of successful ventures. Even if the Chinese government were to implement health care financing reforms that led to an increase in nursing jobs and improved work conditions, some level of surplus will remain. As such, it is likely that China will become an important source of nurses for developed nations in the coming years. PMID:17489923

  8. Potential of China in global nurse migration.

    PubMed

    Fang, Zhiwu Zack

    2007-06-01

    The purpose of this paper is to examine what is known about the nurse workforce and nursing education in China in order to assess the likely potential for nurse migration from China in the future. There is a severe shortage of nurses in China (only one nurse per thousand in population), but at the same time there is a very high level of unemployment and underemployment of nurses. China's nursing education system is huge in size (about 500,000 nursing students in 2005), but weak in quality and career development. As a result of lack of limited job opportunities, low salary, and low job satisfaction, many talented Chinese nurses intend to switch occupation or work outside China. Commercial recruiters have expressed a strong interest in recruitment of nurses in China, but to date there are few examples of successful ventures. Even if the Chinese government were to implement health care financing reforms that led to an increase in nursing jobs and improved work conditions, some level of surplus will remain. As such, it is likely that China will become an important source of nurses for developed nations in the coming years.

  9. Theoretical studies of potential energy surfaces

    SciTech Connect

    Harding, L.B.

    1995-07-01

    MRCI (configuration interaction) calculations were used to examine possible pathways for the O{sub 2} + CCH reaction. The H{sub 2} + CN potential surface was examined. An initial survey was made of the HCl + CN potential energy surface at a low level of theory.

  10. Supply and demand in energy and agriculture: Emitters of CO{sub 2} and possibilities for global biomass energy strategies

    SciTech Connect

    Ahamer, G.; Hubergasse, J.

    1996-12-31

    As seen from the perspective of global E3-modelling (= environment-economy-energy), the sectors of energy and of agriculture are double players situated in a field of tension: both exhibit growing emissions--but both also exhibit reduction potentials for CO{sub 2}, if areas are used for growth of biomass energy carriers. On the one hand, meeting food demand requires increasing agricultural land use in some regions, on the other hand in other regions, an important input of fossil fuels buys higher efficiency levels. In the First World, newly set-aside land can be used for biomass energy production. Before envisaging global strategies for CO{sub 2} emission reductions and more specifically for an enhanced use of biomass for energy, the present boundary conditions of the global energy and agricultural systems have to be analyzed. In a second step, a likely future development has to be contrasted with the desirable increase of bioenergy.

  11. A new diagram of the global energy balance

    NASA Astrophysics Data System (ADS)

    Wild, Martin

    2014-05-01

    This study provides a new assessment of the global mean energy flows from a surface perspective as well as an associated diagram of the global mean energy balance. The radiative energy exchanges between Sun, Earth and space are now accurately quantified from new satellite missions. Much less has been known about the magnitude of the energy flows within the climate system and at the Earth surface, which cannot be directly measured by satellites. In addition to satellite observations, the growing number of surface observations is used to constrain the global energy balance not only from space, but also from the surface. These observations are combined with the latest modeling efforts performed for the 5th IPCC assessment report to infer best estimates for the global mean surface radiative components. Our analyses favor global mean downward surface solar and thermal radiation values near 185 and 342 Wm-2, respectively, which are most compatible with surface observations. Combined with an estimated global mean surface absorbed solar radiation and thermal emission of 161 Wm-2 and 398 Wm-2, respectively, this leaves 105 Wm-2 of global mean surface net radiation available for distribution amongst the non-radiative surface energy balance components. Considering an imbalance of 0.6 Wm-2, the global mean sensible and latent heat fluxes are estimated at 20 and 84 Wm-2, respectively, to close the surface energy balance. The global mean surface radiative fluxes derived here in combination with a latent heat flux of 84 Wm-2 may be able to reconcile currently disputed inconsistencies between energy and water cycle estimates. The findings of this study are compiled into a new global energy balance diagram. Related references: Wild, M., Folini, D., Schär, C., Loeb, N., Dutton E.G., and König-Langlo, G., 2013: A new diagram of the global energy balance, AIP Conf. Proc., 1531, 628-631, doi: 10.1063/1.4804848. Wild, M., Folini, D., Schär, C., Loeb, N., Dutton, E.G., and K

  12. Potential energy savings from aquifer thermal energy storage

    SciTech Connect

    Anderson, M.R.; Weijo, R.O.

    1988-07-01

    Pacific Northwest Laboratory researchers developed an aggregate-level model to estimate the short- and long-term potential energy savings from using aquifer thermal storage (ATES) in the United States. The objectives of this effort were to (1) develop a basis from which to recommend whether heat or chill ATES should receive future research focus and (2) determine which market sector (residential, commercial, or industrial) offers the largest potential energy savings from ATES. Information was collected on the proportion of US land area suitable for ATES applications. The economic feasibility of ATES applications was then evaluated. The potential energy savings from ATES applications was calculated. Characteristic energy use in the residential, commercial, and industrial sectors was examined, as was the relationship between waste heat production and consumption by industrial end-users. These analyses provided the basis for two main conclusions: heat ATES applications offer higher potential for energy savings than do chill ATES applications; and the industrial sector can achieve the highest potential energy savings for the large consumption markets. Based on these findings, it is recommended that future ATES research and development efforts be directed toward heat ATES applications in the industrial sector. 11 refs., 6 figs., 9 tabs.

  13. Applying supersymmetry to energy dependent potentials

    SciTech Connect

    Yekken, R.; Lassaut, M.; Lombard, R.J.

    2013-11-15

    We investigate the supersymmetry properties of energy dependent potentials in the D=1 dimensional space. We show the main aspects of supersymmetry to be preserved, namely the factorization of the Hamiltonian, the connections between eigenvalues and wave functions of the partner Hamiltonians. Two methods are proposed. The first one requires the extension of the usual rules via the concept of local equivalent potential. In this case, the superpotential becomes depending on the state. The second method, applicable when the potential depends linearly on the energy, is similar to what has been already achieved by means of the Darboux transform. -- Highlights: •Supersymmetry extended to energy dependent potentials. •Generalization of the concept of superpotential. •An alternative method used for linear E-dependence leads to the same results as Darboux transform.

  14. Benchmarks of Global Clean Energy Manufacturing: Summary of Findings

    SciTech Connect

    2017-01-01

    The Benchmarks of Global Clean Energy Manufacturing will help policymakers and industry gain deeper understanding of global manufacturing of clean energy technologies. Increased knowledge of the product supply chains can inform decisions related to manufacturing facilities for extracting and processing raw materials, making the array of required subcomponents, and assembling and shipping the final product. This brochure summarized key findings from the analysis and includes important figures from the report. The report was prepared by the Clean Energy Manufacturing Analysis Center (CEMAC) analysts at the U.S. Department of Energy's National Renewable Energy Laboratory.

  15. Energy in New England | Energy and Global Climate Change ...

    EPA Pesticide Factsheets

    2017-04-10

    EPA Region 1's Energy and Climate Unit provides information, technical assistance, and training on energy efficiency, renewable energy, energy use and transmission in New England. In addition, the unit works with the New England States to regulate and inventory greenhouse gas emissions.

  16. Saturation wind power potential and its implications for wind energy

    PubMed Central

    Jacobson, Mark Z.; Archer, Cristina L.

    2012-01-01

    Wind turbines convert kinetic to electrical energy, which returns to the atmosphere as heat to regenerate some potential and kinetic energy. As the number of wind turbines increases over large geographic regions, power extraction first increases linearly, but then converges to a saturation potential not identified previously from physical principles or turbine properties. These saturation potentials are >250 terawatts (TW) at 100 m globally, approximately 80 TW at 100 m over land plus coastal ocean outside Antarctica, and approximately 380 TW at 10 km in the jet streams. Thus, there is no fundamental barrier to obtaining half (approximately 5.75 TW) or several times the world’s all-purpose power from wind in a 2030 clean-energy economy. PMID:23019353

  17. Saturation wind power potential and its implications for wind energy.

    PubMed

    Jacobson, Mark Z; Archer, Cristina L

    2012-09-25

    Wind turbines convert kinetic to electrical energy, which returns to the atmosphere as heat to regenerate some potential and kinetic energy. As the number of wind turbines increases over large geographic regions, power extraction first increases linearly, but then converges to a saturation potential not identified previously from physical principles or turbine properties. These saturation potentials are >250 terawatts (TW) at 100 m globally, approximately 80 TW at 100 m over land plus coastal ocean outside Antarctica, and approximately 380 TW at 10 km in the jet streams. Thus, there is no fundamental barrier to obtaining half (approximately 5.75 TW) or several times the world's all-purpose power from wind in a 2030 clean-energy economy.

  18. Global warming mitigation potential of biogas plants in India.

    PubMed

    Pathak, H; Jain, N; Bhatia, A; Mohanty, S; Gupta, Navindu

    2009-10-01

    Biogas technology, besides supplying energy and manure, provides an excellent opportunity for mitigation of greenhouse gas (GHG) emission and reducing global warming through substituting firewood for cooking, kerosene for lighting and cooking and chemical fertilizers. A study was undertaken to calculate (1) global warming mitigation potential (GMP) and thereby earning carbon credit of a family size biogas plant in India, (2) GMP of the existing and target biogas plants in the country and (3) atmospheric pollution reduction by a family size biogas plant. The GMP of a family size biogas plant was 9.7 t CO(2) equiv. year( - 1) and with the current price of US $10 t( - 1) CO(2) equiv., carbon credit of US $97 year( - 1) could be earned from such reduction in greenhouse gas emission under the clean development mechanism (CDM). A family size biogas plant substitutes 316 L of kerosene, 5,535 kg firewood and 4,400 kg cattle dung cake as fuels which will reduce emissions of NOx, SO(2), CO and volatile organic compounds to the atmosphere by 16.4, 11.3, 987.0 and 69.7 kg year( - 1), respectively. Presently 3.83 million biogas plants are operating in the country, which can mitigate global warming by 37 Mt CO(2) equiv. year( - 1). Government of India has a target of installing 12.34 million biogas plants by 2010. This target has a GMP of 120 Mt CO(2) equiv. year( - 1) and US $1,197 million as carbon credit under the CDM. However, if all the collectible cattle dung (225 Mt) produced in the country is used, 51.2 million family size biogas plants can be supported which will have a GMP of 496 Mt of CO(2) equiv. year( - 1) and can earn US $4,968 million as carbon credit. The reduction in global warming should encourage policy makers to promote biogas technology to combat climate change and integration of carbon revenues will help the farmers to develop biogas as a profitable activity.

  19. Energy Conservation--The Global Imperative.

    ERIC Educational Resources Information Center

    Murthy, K. K.

    1978-01-01

    Presents energy as a pivotal prerequisite of highly developed economic and social structure. Discusses: (1) fossil-fuel resources and demand in various countries; (2) energy conservation; (3) measures for conservation; (4) technology transfer; and (5) considerations to be regarded internationally. (HM)

  20. A Comprehensive View of Global Potential for Hydro-generated Electricity

    SciTech Connect

    Zhou, Yuyu; Hejazi, Mohamad I.; Smith, Steven J.; Edmonds, James A.; Li, Hongyi; Clarke, Leon E.; Calvin, Katherine V.; Thomson, Allison M.

    2015-09-01

    In this study, we assess global hydropower potential using runoff and stream flow data, along with turbine technology performance, cost assumptions, and environmental considerations. The results provide the first comprehensive quantification of global hydropower potential including gross, technical, economic, and exploitable estimates. Total global potential of gross, technical, economic, and exploitable hydropower are estimated to be approximately 128, 39, 32, and 27 petawatt hours per year, respectively. The economic and exploitable potential of hydropower are calculated at less than 9 cents/kWh. We find that hydropower has the potential to supply a significant portion of the world energy needs, although this potential varies substantially by region. Globally, hydropower can potentially supply about 1.5 times the total electricity demand in 2005. Estimated hydropower resources in a number of countries are sufficient to accommodate their demand for electricity in 2005, e.g., Brazil (5.6 times), Russia (4.6 times), and Canada (3.5 times). A sensitivity analysis indicates that hydropower estimates are not highly sensitive to five key parameters: design flow (varying by -2% to +1% at less than 9 cents/kWh), cost and financing options (by -7% to +6%), turbine efficiency (by -10% to +10%), stream flow (by -10% to +10%), and fixed charge rate (by -6% to 5%). This sensitivity analysis emphasizes the reliable role of hydropower for future energy systems, when compared to other renewable energy resources with larger uncertainty in their future potentials.

  1. A new diagram of the global energy balance

    NASA Astrophysics Data System (ADS)

    Wild, Martin; Folini, Doris; Schär, Christoph; Loeb, Norman; Dutton, Ellsworth G.; König-Langlo, Gert

    2013-05-01

    Here we provide a new assessment of the global mean energy fluxes from a surface perspective and present an associated diagram of the global mean energy balance, adapted from the study by Wild et al. (2013) [1] with two slight modifications as outlined in this paper. The radiative energy exchanges between Sun, Earth and space are now accurately quantified from new satellite missions. Much less has been known about the magnitude of the energy flows within the climate system and at the Earth surface, which cannot be directly measured by satellites. In addition to satellite observations, we make extensive use of the growing number of surface observations to constrain the global energy balance not only from space, but also from the surface. We combine these observations with the latest modeling efforts performed for the 5th IPCC assessment report to infer best estimates for the global mean surface radiative components. Our analyses favor global mean downward surface solar and thermal radiation values near 185 and 342 Wm-2, respectively, which are most compatible with surface observations. Combined with an estimated surface absorbed solar radiation and thermal emission of 161 Wm-2 and 398 Wm-2, respectively, this leaves 105 Wm-2 of surface net radiation available for distribution amongst the non-radiative surface energy balance components. Considering an imbalance of 0.6 Wm-2, the global mean sensible and latent heat fluxes are estimated at 20 and 84 Wm-2, respectively, to close the surface energy balance. The global mean surface radiative fluxes derived here in combination with a latent heat flux of 84 Wm-2 may be able to reconcile currently disputed inconsistencies between energy and water cycle estimates. The findings of this study are compiled into a new global energy balance diagram.

  2. Separable representation of energy-dependent optical potentials

    NASA Astrophysics Data System (ADS)

    Hlophe, L.; Elster, Ch.

    2016-03-01

    Background: One important ingredient for many applications of nuclear physics to astrophysics, nuclear energy, and stockpile stewardship are cross sections for reactions of neutrons with rare isotopes. Since direct measurements are often not feasible, indirect methods, e.g., (d ,p ) reactions, should be used. Those (d ,p ) reactions may be viewed as three-body reactions and described with Faddeev techniques. Purpose: Faddeev equations in momentum space have a long tradition of utilizing separable interactions in order to arrive at sets of coupled integral equations in one variable. Optical potentials representing the effective interactions in the neutron (proton) nucleus subsystem are usually non-Hermitian as well as energy dependent. Potential matrix elements as well as transition matrix elements calculated with them must fulfill the reciprocity theorem. The purpose of this paper is to introduce a separable, energy-dependent representation of complex, energy-dependent optical potentials that fulfill reciprocity exactly. Methods: Momentum space Lippmann-Schwinger integral equations are solved with standard techniques to obtain the form factors for the separable representation. Results: Starting from a separable, energy-independent representation of global optical potentials based on a generalization of the Ernst-Shakin-Thaler (EST) scheme, a further generalization is needed to take into account the energy dependence. Applications to n +48Ca ,n +208Pb , and p +208Pb are investigated for energies from 0 to 50 MeV with special emphasis on fulfilling reciprocity. Conclusions: We find that the energy-dependent separable representation of complex, energy-dependent phenomenological optical potentials fulfills reciprocity exactly. In addition, taking into account the explicit energy dependence slightly improves the description of the S matrix elements.

  3. Trends in global wildfire potential in a changing climate

    Treesearch

    Y. Liu; J.A. Stanturf; S.L. Goodrick

    2009-01-01

    The trend in global wildfire potential under the climate change due to the greenhouse effect is investigated. Fire potential is measured by the Keetch-Byram Drought Index (KBDI), which is calculated using the observed maximum temperature and precipitation and projected changes at the end of this century (2070–2100) by general circulation models (GCMs) for present and...

  4. Biomass resource potential using energy crops

    SciTech Connect

    Wright, L.L.; Cushman, J.H.; Martin, S.A.

    1993-09-01

    Biomass energy crops can provide a significant and environmentally beneficial source of renewable energy feedstocks for the future. They can revitalize the agricultural sector of the US economy by providing profitable uses for marginal cropland. Energy crops include fast-growing trees, perennial grasses, and annual grasses, all capable of collecting solar energy and storing it as cellulosic compounds for several months to several years. Once solar energy is thus captured, it can be converted by means of currently available technologies to a wide variety of energy products such as electricity, heat, liquid transportation fuels, and gases. Experimental results from field trials have generated optimism that selected and improved energy crops, established on cropland with moderate limitations for crop production, have the potential for producing high yields. Both trees and grasses, under very good growing conditions, have produced average annual yields of 20 to 40 dry Mg ha{sup {minus}1} year{sup {minus}1}. Sorghum has shown especially high yields in the Midwest. Hybrids between sugar cane and its wild relatives, called energy cane, have yielded as much as 50 dry Mg ha{sup {minus}1} year{sup {minus}1} in Florida. These experimental results demonstrate that some species have the genetic potential for very rapid growth rates. New wood energy crop systems developed by the Department of Energy`s Biofuels Feedstock Development Program offer, at a minimum, a 100% increase in biomass production rates over the 2 to 4 Mg ha{sup {minus}1} year{sup {minus}1} of dry leafless woody biomass produced by most natural forest systems. Experimental data indicate that short rotation wood crops established on cropland with moderate limitations are capable of producing biomass yields of 8--20 dry Mg ha{sup {minus}1} year{sup {minus}1} with a present average about 11 dry Mg ha{sup {minus}1} year{sup {minus}1} on typical cropland sites.

  5. Mapping the global geographic potential of Zika virus spread

    PubMed Central

    Samy, Abdallah M.; Thomas, Stephanie M; Wahed, Ahmed Abd El; Cohoon, Kevin P; Peterson, A. Townsend

    2016-01-01

    The Americas are presently experiencing the most serious known outbreak of Zika virus (ZIKV). Here, we present a novel set of analyses using environmental characteristics, vector mosquito distributions, and socioeconomic risk factors to develop the first map to detail global ZIKV transmission risk in multiple dimensions based on ecological niche models. Our model predictions were tested against independent evaluation data sets, and all models had predictive ability significantly better than random expectations. The study addresses urgent knowledge gaps regarding (1) the potential geographic scope of the current ZIKV epidemic, (2) the global potential for spread of ZIKV, and (3) drivers of ZIKV transmission. Our analysis of potential drivers of ZIKV distributions globally identified areas vulnerable in terms of some drivers, but not for others. The results of these analyses can guide regional education and preparedness efforts, such that medical personnel will be better prepared for diagnosis of potential ZIKV cases as they appear. PMID:27653360

  6. Mapping the global geographic potential of Zika virus spread.

    PubMed

    Samy, Abdallah M; Thomas, Stephanie M; Wahed, Ahmed Abd El; Cohoon, Kevin P; Peterson, A Townsend

    2016-09-01

    The Americas are presently experiencing the most serious known outbreak of Zika virus (ZIKV). Here, we present a novel set of analyses using environmental characteristics, vector mosquito distributions, and socioeconomic risk factors to develop the first map to detail global ZIKV transmission risk in multiple dimensions based on ecological niche models. Our model predictions were tested against independent evaluation data sets, and all models had predictive ability significantly better than random expectations. The study addresses urgent knowledge gaps regarding (1) the potential geographic scope of the current ZIKV epidemic, (2) the global potential for spread of ZIKV, and (3) drivers of ZIKV transmission. Our analysis of potential drivers of ZIKV distributions globally identified areas vulnerable in terms of some drivers, but not for others. The results of these analyses can guide regional education and preparedness efforts, such that medical personnel will be better prepared for diagnosis of potential ZIKV cases as they appear.

  7. Privatization and the Globalization of Energy Markets

    EIA Publications

    1996-01-01

    Discusses recent efforts at privatization in petroleum, electricity, and coal, as well as the impetus that privatization has provided in fostering the evolution of the multinational and multidimensional energy company.

  8. Privatization and the Globalization of Energy Markets

    EIA Publications

    1996-01-01

    Discusses recent efforts at privatization in petroleum, electricity, and coal, as well as the impetus that privatization has provided in fostering the evolution of the multinational and multidimensional energy company.

  9. GEWEX: The Global Energy and Water Cycle Experiment

    NASA Technical Reports Server (NTRS)

    Chahine, M.; Vane, D.

    1994-01-01

    GEWEX is one of the world's largest global change research programs. Its purpose is to observe and understand the hydrological cycle and energy fluxes in the atmosphere, at land surfaces and in the upper oceans.

  10. Potential energy function for the hydroperoxyl radical

    SciTech Connect

    Lemon, W.J.; Hase, W.L.

    1987-03-12

    A switching function formalism is used to derive an analytic potential energy surface for the O + OH in equilibrium HO/sub 2/ in equilibrium H + O/sub 2/ reactive system. Both experimental and ab initio data are used to derive parameters for the potential energy surface. Trajectory calculations for highly excited HO/sub 2/ are performed on this surface. From these trajectories quasi-periodic eigentrajectories are found for vibrational levels near the HO/sub 2/ dissociation threshold with small amounts of quanta in the OH stretch mode and large amounts of quanta in the OO stretch mode.

  11. Potential energy surfaces for cluster emitting nuclei

    SciTech Connect

    Poenaru, Dorin N.; Gherghescu, Radu A.; Greiner, Walter

    2006-01-15

    Potential energy surfaces are calculated by use of the most advanced asymmetric two-center shell model that allows us to obtain shell-and-pairing corrections that are added to the Yukawa-plus-exponential model deformation energy. Shell effects are of crucial importance for the experimental observation of spontaneous disintegration by heavy-ion emission. Results for {sup 222}Ra, {sup 232}U, {sup 236}Pu, and {sup 242}Cm illustrate the main ideas and show for the first time, for a cluster emitter, a potential barrier obtained by use of the macroscopic-microscopic method.

  12. Potential reduction of DSN uplink energy cost

    NASA Technical Reports Server (NTRS)

    Dolinsky, S.; Degroot, N. F.

    1982-01-01

    DSN Earth stations typically transmit more power than that required to meet minimum specifications for uplink performance. Energy and cost savings that could result from matching the uplink power to the amount required for specified performance are studied. The Galileo mission was selected as a case study. Although substantial reduction in transmitted energy is possible, potential savings in source energy (oil or electricity) savings are much less. This is because of the rising inefficiency in power conversion and radio frequency power generation that accompanies reduced power output.

  13. Potential reduction of DSN uplink energy cost

    NASA Technical Reports Server (NTRS)

    Dolinsky, S.; Degroot, N. F.

    1982-01-01

    DSN Earth stations typically transmit more power than that required to meet minimum specifications for uplink performance. Energy and cost savings that could result from matching the uplink power to the amount required for specified performance are studied. The Galileo mission was selected as a case study. Although substantial reduction in transmitted energy is possible, potential savings in source energy (oil or electricity) savings are much less. This is because of the rising inefficiency in power conversion and radio frequency power generation that accompanies reduced power output.

  14. Global and Regional Evaluation of Energy for Water

    SciTech Connect

    Liu, Yaling; Hejazi, Mohamad; Kyle, Page; Kim, Son H.; Davies, Evan; Miralles, Diego G.; Teuling, Adriaan J.; He, Yujie; Niyogi, Dev

    2016-09-06

    Despite significant effort to quantify the inter-dependence of the water and energy sectors, global requirements of energy for water (E4W) are still poorly understood, which may result in biases in projections and consequently in water and energy management and policy. This study estimates water-related energy consumption by water source, sector, and process, for 14 global regions from 1973 to 2012. Globally, E4W amounted to 10.2 ± 5 EJ of primary energy consumption in 2010, accounting for 1.2–3% of total global primary energy consumption, of which 58% pertains to surface water, 30% to groundwater, and 12% to non-fresh water, assuming median energy intensity levels. The sectoral E4W allocation includes municipal (45%), industrial (30%), and agricultural (25%), and main process-level contributions are from source/conveyance (39%), water purification (27%), water distribution (12%) and wastewater treatment (18%). While the USA was the largest E4W consumer from the 1970’s until the 2000’s, the largest consumers at present are the Middle East, India, and China, driven by rapid growth in desalination, groundwater-based irrigation, and industrial and municipal water use, respectively. The improved understanding of global E4W will enable enhanced consistency of both water and energy representations in integrated assessment models.

  15. Global and Regional Evaluation of Energy for Water.

    PubMed

    Liu, Yaling; Hejazi, Mohamad; Kyle, Page; Kim, Son H; Davies, Evan; Miralles, Diego G; Teuling, Adriaan J; He, Yujie; Niyogi, Dev

    2016-09-06

    Despite significant effort to quantify the interdependence of the water and energy sectors, global requirements of energy for water (E4W) are still poorly understood, which may result in biases in projections and consequently in water and energy management and policy. This study estimates water-related energy consumption by water source, sector, and process for 14 global regions from 1973 to 2012. Globally, E4W amounted to 10.2 EJ of primary energy consumption in 2010, accounting for 1.7%-2.7% of total global primary energy consumption, of which 58% pertains to fresh surface water, 30% to fresh groundwater, and 12% to nonfresh water, assuming median energy intensity levels. The sectoral E4W allocation includes municipal (45%), industrial (30%), and agricultural (25%), and main process-level contributions are from source/conveyance (39%), water purification (27%), water distribution (12%), and wastewater treatment (18%). While the United States was the largest E4W consumer from the 1970s until the 2000s, the largest consumers at present are the Middle East, India, and China, driven by rapid growth in desalination, groundwater-based irrigation, and industrial and municipal water use, respectively. The improved understanding of global E4W will enable enhanced consistency of both water and energy representations in integrated assessment models.

  16. Potential energy sputtering of EUVL materials

    SciTech Connect

    Pomeroy, J M; Ratliff, L P; Gillaspy, J D; Bajt, S

    2004-07-02

    Of the many candidates employed for understanding the erosion of critical Extreme Ultraviolet Lithography (EUVL) components, potential energy damage remains relatively uninvestigated. Unlike the familiar kinetic energy sputtering, which is a consequence of the momentum transferred by an ion to atoms in the target, potential energy sputtering occurs when an ion rapidly collects charge from the target as it neutralizes. Since the neutralization energy of a singly charged ion is typically on the order of 10 eV, potential energy effects are generally neglected for low charge state ions, and hence the bulk of the sputtering literature. As an ion's charge state is increased, the potential energy (PE) increases rapidly, e.g. PE(Xe{sup 1+})= 11 eV, PE(Xe{sup 10+}) = 810 eV, PE(Xe{sup 20+}) = 4.6 keV, etc. By comparison, the binding energy of a single atom on a surface is typically about 5 eV, so even relatively inefficient energy transfer mechanisms can lead to large quantities of material being removed, e.g. 25% efficiency for Xe{sup 10+} corresponds to {approx} 40 atoms/ion. By comparison, singly charged xenon ions with {approx} 20 keV of kinetic energy sputter only about 5 atoms/ion at normal incidence, and less than 1 atom/ion at typical EUV source energies. EUV light sources are optimized for producing approximately 10{sup 16} xenon ions per shot with an average charge state of q=10 in the core plasma. At operational rates of {approx}10 kHz, the number of ions produced per second becomes a whopping 10{sup 20}. Even if only one in a billion ions reaches the collector, erosion rates could reach {approx}10{sup 12} atoms per second, severely reducing the collector lifetime (for an average yield of 10 atoms/ion). In addition, efforts to reduce contamination effects may contribute to reduced neutralization and even larger potential energy damages rates (discussed further below). In order to provide accurate estimates for collector lifetimes and to develop mitigation schemes

  17. Warm body temperature facilitates energy efficient cortical action potentials.

    PubMed

    Yu, Yuguo; Hill, Adam P; McCormick, David A

    2012-01-01

    The energy efficiency of neural signal transmission is important not only as a limiting factor in brain architecture, but it also influences the interpretation of functional brain imaging signals. Action potential generation in mammalian, versus invertebrate, axons is remarkably energy efficient. Here we demonstrate that this increase in energy efficiency is due largely to a warmer body temperature. Increases in temperature result in an exponential increase in energy efficiency for single action potentials by increasing the rate of Na(+) channel inactivation, resulting in a marked reduction in overlap of the inward Na(+), and outward K(+), currents and a shortening of action potential duration. This increase in single spike efficiency is, however, counterbalanced by a temperature-dependent decrease in the amplitude and duration of the spike afterhyperpolarization, resulting in a nonlinear increase in the spike firing rate, particularly at temperatures above approximately 35°C. Interestingly, the total energy cost, as measured by the multiplication of total Na(+) entry per spike and average firing rate in response to a constant input, reaches a global minimum between 37-42°C. Our results indicate that increases in temperature result in an unexpected increase in energy efficiency, especially near normal body temperature, thus allowing the brain to utilize an energy efficient neural code.

  18. Warm Body Temperature Facilitates Energy Efficient Cortical Action Potentials

    PubMed Central

    Yu, Yuguo; Hill, Adam P.; McCormick, David A.

    2012-01-01

    The energy efficiency of neural signal transmission is important not only as a limiting factor in brain architecture, but it also influences the interpretation of functional brain imaging signals. Action potential generation in mammalian, versus invertebrate, axons is remarkably energy efficient. Here we demonstrate that this increase in energy efficiency is due largely to a warmer body temperature. Increases in temperature result in an exponential increase in energy efficiency for single action potentials by increasing the rate of Na+ channel inactivation, resulting in a marked reduction in overlap of the inward Na+, and outward K+, currents and a shortening of action potential duration. This increase in single spike efficiency is, however, counterbalanced by a temperature-dependent decrease in the amplitude and duration of the spike afterhyperpolarization, resulting in a nonlinear increase in the spike firing rate, particularly at temperatures above approximately 35°C. Interestingly, the total energy cost, as measured by the multiplication of total Na+ entry per spike and average firing rate in response to a constant input, reaches a global minimum between 37–42°C. Our results indicate that increases in temperature result in an unexpected increase in energy efficiency, especially near normal body temperature, thus allowing the brain to utilize an energy efficient neural code. PMID:22511855

  19. Global Auroral Energy Deposition Compared with Magnetic Indices

    NASA Technical Reports Server (NTRS)

    Brittnacher, M. J.; Fillingim, M. O.; Elsen, R.; Parks, G. K.; Germany, G. A.; Spann, J. F., Jr.

    1997-01-01

    Measurement of the global rate of energy deposition in the ionosphere via auroral particle precipitation is one of the primary goals of the Polar UVI program and is an important component of the ISTP program. The instantaneous rate of energy deposition for the entire month of January 1997 has been calculated by applying models to the UVI images and is presented by Fillingim et al. in this session. Magnetic indices, such as Kp, AE, and Dst, which are sensitive to variations in magnetospheric current systems have been constructed from ground magnetometer measurements and employed as measures of activity. The systematic study of global energy deposition raises the possibility of constructing a global magnetospheric activity index explicitly based on particle precipitation to supplement magnetic indices derived from ground magnetometer measurements. The relationship between global magnetic activity as measured by these indices and the rate of total global energy loss due to precipitation is not known at present. We study the correlation of the traditional magnetic index of Kp for the month of January 1997 with the energy deposition derived from the UVI images. We address the question of whether the energy deposition through particle precipitation generally matches the Kp and AE indices, or the more exciting, but distinct, possibility that this particle-derived index may provide an somewhat independent measure of global magnetospheric activity that could supplement traditional magnetically-based activity indices.

  20. Global Auroral Energy Deposition Compared with Magnetic Indices

    NASA Technical Reports Server (NTRS)

    Brittnacher, M. J.; Fillingim, M. O.; Elsen, R.; Parks, G. K.; Germany, G. A.; Spann, J. F., Jr.

    1997-01-01

    Measurement of the global rate of energy deposition in the ionosphere via auroral particle precipitation is one of the primary goals of the Polar UVI program and is an important component of the ISTP program. The instantaneous rate of energy deposition for the entire month of January 1997 has been calculated by applying models to the UVI images and is presented by Fillingim et al. in this session. Magnetic indices, such as Kp, AE, and Dst, which are sensitive to variations in magnetospheric current systems have been constructed from ground magnetometer measurements and employed as measures of activity. The systematic study of global energy deposition raises the possibility of constructing a global magnetospheric activity index explicitly based on particle precipitation to supplement magnetic indices derived from ground magnetometer measurements. The relationship between global magnetic activity as measured by these indices and the rate of total global energy loss due to precipitation is not known at present. We study the correlation of the traditional magnetic index of Kp for the month of January 1997 with the energy deposition derived from the UVI images. We address the question of whether the energy deposition through particle precipitation generally matches the Kp and AE indices, or the more exciting, but distinct, possibility that this particle-derived index may provide an somewhat independent measure of global magnetospheric activity that could supplement traditional magnetically-based activity indices.

  1. A global perspective on energy: health effects and injustices.

    PubMed

    Wilkinson, Paul; Smith, Kirk R; Joffe, Michael; Haines, Andrew

    2007-09-15

    The exploitation of fossil fuels is integral to modern living and has been a key element of the rapid technological, social, and cultural changes of the past 250 years. Although such changes have brought undeniable benefits, this exploitation has contributed to a burden of illness through pollution of local and regional environments, and is the dominant cause of climate change. This pattern of development is therefore unsustainable at a global level. At the same time, about 2.4 billion of the world's population, disadvantaged by lack of access to clean energy, are exposed to high levels of indoor air pollutants from the inefficient burning of biomass fuels. Even in high-income countries, many people live in fuel poverty, and throughout the world, increasingly sedentary lifestyles (to which fossil-fuel-dependent transport systems contribute) are leading to chronic disease and injuries. Energy security is also an issue of growing concern to many governments in both the developed and developing world, and a potential source of international tension and conflict. In this Series, we examine the opportunities to improve health, reduce climate effects, and promote development through realistic adjustments in the way energy and food are produced and consumed.

  2. Assessing the Global Potential and Regional Implications of Promoting Bioenergy

    EPA Science Inventory

    There is no simple answer to the question “are materials from bio-based feedstocks environmentally, and socially, preferable?” Bioenergy as an alternative energy source might be effective in reducing fossil fuel use, slowing global warming effects, and providing increased revenue...

  3. Assessing the Global Potential and Regional Implications of Promoting Bioenergy

    EPA Science Inventory

    There is no simple answer to the question “are materials from bio-based feedstocks environmentally, and socially, preferable?” Bioenergy as an alternative energy source might be effective in reducing fossil fuel use, slowing global warming effects, and providing increased revenue...

  4. The potential impact of hydrogen energy use on the atmosphere

    NASA Astrophysics Data System (ADS)

    van Ruijven, B. J.; Lamarque, J. F.; van Vuuren, D. P.; Kram, T.; Eerens, H.

    2009-04-01

    Energy models show very different trajectories for future energy systems (partly as function of future climate policy). One possible option is a transition towards a hydrogen-based energy system. The potential impact of such hydrogen economy on atmospheric emissions is highly uncertain. On the one hand, application of hydrogen in clean fuel cells reduces emissions of local air pollutants, like SOx and NOx. On the other hand, emissions of hydrogen from system leakages are expected to change the atmospheric concentrations and behaviour (see also Price et al., 2007; Sanderson et al., 2003; Schultz et al., 2003; Tromp et al., 2003). The uncertainty arises from several sources: the expected use of hydrogen, the intensity of leakages and emissions, and the atmospheric chemical behaviour of hydrogen. Existing studies to the potential impacts of a hydrogen economy on the atmosphere mostly use hydrogen emission scenarios that are based on simple assumptions. This research combines two different modelling efforts to explore the range of impacts of hydrogen on atmospheric chemistry. First, the potential role of hydrogen in the global energy system and the related emissions of hydrogen and other air pollutants are derived from the global energy system simulation model TIMER (van Vuuren, 2007). A set of dedicated scenarios on hydrogen technology development explores the most pessimistic and optimistic cases for hydrogen deployment (van Ruijven et al., 2008; van Ruijven et al., 2007). These scenarios are combined with different assumptions on hydrogen emission factors. Second, the emissions from the TIMER model are linked to the NCAR atmospheric model (Lamarque et al., 2005; Lamarque et al., 2008), in order to determine the impacts on atmospheric chemistry. By combining an energy system model and an atmospheric model, we are able to consistently explore the boundaries of both hydrogen use, emissions and impacts on atmospheric chemistry. References: Lamarque, J.-F., Kiehl, J. T

  5. Potential Energy Cost Savings from Increased Commercial Energy Code Compliance

    SciTech Connect

    Rosenberg, Michael I.; Hart, Philip R.; Athalye, Rahul A.; Zhang, Jian; Cohan, David F.

    2016-08-22

    An important question for commercial energy code compliance is: “How much energy cost savings can better compliance achieve?” This question is in sharp contrast to prior efforts that used a checklist of code requirements, each of which was graded pass or fail. Percent compliance for any given building was simply the percent of individual requirements that passed. A field investigation method is being developed that goes beyond the binary approach to determine how much energy cost savings is not realized. Prototype building simulations were used to estimate the energy cost impact of varying levels of non-compliance for newly constructed office buildings in climate zone 4C. Field data collected from actual buildings on specific conditions relative to code requirements was then applied to the simulation results to find the potential lost energy savings for a single building or for a sample of buildings. This new methodology was tested on nine office buildings in climate zone 4C. The amount of additional energy cost savings they could have achieved had they complied fully with the 2012 International Energy Conservation Code is determined. This paper will present the results of the test, lessons learned, describe follow-on research that is needed to verify that the methodology is both accurate and practical, and discuss the benefits that might accrue if the method were widely adopted.

  6. Global wetlands: Potential distribution, wetland loss, and status.

    PubMed

    Hu, Shengjie; Niu, Zhenguo; Chen, Yanfen; Li, Lifeng; Zhang, Haiying

    2017-05-15

    Even though researchers have paid a great deal of attention to wetland loss and status, the actual extent of wetland loss on a global scale, especially the loss caused directly by human activities, and the actual extent of currently surviving wetlands remains uncertain. This paper simulated the potential distribution of global wetlands by employing a new Precipitation Topographic Wetness Index (PTWI) and global remote sensing training samples. The results show earth would have approximately 29.83millionkm(2) of wetlands, if humans did not interfere with wetland ecosystems. By combining datasets related to global wetlands, we found that at least 33% of global wetlands had been lost as of 2009, including 4.58millionkm(2) of non-water wetlands and 2.64millionkm(2) of open water. The areal extent of wetland loss has been greatest in Asia, but Europe has experienced the most serious losses. Wetland-related datasets suffer from major inconsistencies, and estimates of the areal extent of the remaining global wetlands ranged from 1.53 to 14.86millionkm(2). Therefore, although it is challenging, thematic mapping of global wetlands is necessary and urgently needed.

  7. Divacancy binding energy, formation energy and surface energy of BCC transition metals using MEAM potentials

    NASA Astrophysics Data System (ADS)

    Uniyal, Shweta; Chand, Manesh; Joshi, Subodh; Semalty, P. D.

    2016-05-01

    The modified embedded atom method (MEAM) potential parameters have been employed to calculate the unrelaxed divacancy formation energy, binding energy and surface energies for low index planes in bcc transition metals. The calculated results of divacancy binding energy and vacancy formation energy compare well with experimental and other available calculated results.

  8. Divacancy binding energy, formation energy and surface energy of BCC transition metals using MEAM potentials

    SciTech Connect

    Uniyal, Shweta Chand, Manesh Joshi, Subodh Semalty, P. D.

    2016-05-06

    The modified embedded atom method (MEAM) potential parameters have been employed to calculate the unrelaxed divacancy formation energy, binding energy and surface energies for low index planes in bcc transition metals. The calculated results of divacancy binding energy and vacancy formation energy compare well with experimental and other available calculated results.

  9. Status of global energy confinement studies

    SciTech Connect

    Kaye, S.M.; Bell, M.G. . Plasma Physics Lab.); Barnes, C.W. ); DeBoo, J.C.; Waltz, R. ); Greenwald, M.; Sigmar, D. . Plasma Fusion Center); Riedel, K. . Courant Inst. of Mathematical Sciences); Uckan, N. (Oak Ridge National L

    1990-02-01

    Empirical scaling expressions, reflecting the parametric dependence of the L-mode energy confinement time, have been used not only as benchmarks for tokamak operation and theories of energy transport, but for predicting the performance of proposed tokamak devices. Several scaling expressions based on data from small-and medium-sized devices have done well in predicting performance in larger devices, although great uncertainty exists in extrapolating yet farther, into the ignition regime. Several approaches exist for developing higher confidence scaling expressions. These include reducing the statistical uncertainty by identifying and filling in gaps in the present database, making use of more sophisticated statistical techniques, and developing scalings for confinement regimes within which future devices will operate. Confidence in the scaling expressions will be increased still if the expressions can be more directly tied to transport physics theory. This can be done through the use of dimensionless parameters, better describing the edge and core confinement regimes separately, and by incorporating transport models directly into the scaling expressions. 50 refs., 5 figs., 3 tabs.

  10. Potential energy hypersurface and molecular flexibility

    NASA Astrophysics Data System (ADS)

    Koča, Jaroslav

    1993-02-01

    The molecular flexibility phenomenon is discussed from the conformational potential energy(hyper) surface (PES) point of view. Flexibility is considered as a product of three terms: thermodynamic, kinetic and geometrical. Several expressions characterizing absolute and relative molecular flexibility are introduced, depending on a subspace studied of the entire conformational space, energy level E of PES as well as absolute temperature. Results obtained by programs DAISY, CICADA and PANIC in conjunction with molecular mechanics program MMX for flexibility analysis of isopentane, 2,2-dimethylpentane and isohexane molecules are introduced.

  11. Role of Fusion Energy in a Sustainable Global Energy Strategy

    SciTech Connect

    Meier, W; Najmabadi, F; Schmidt, J; Sheffield, J

    2001-03-07

    Fusion energy is one of only a few truly long-term energy options. Since its inception in the 1950s, the vision of the fusion energy research program has been to develop a viable means of harnessing the virtually unlimited energy stored in the nuclei of light atoms--the primary fuel deuterium is present as one part in 6,500 of all hydrogen. This vision grew out of the recognition that the immense power radiated by the sun is fueled by nuclear fusion in its hot core. Such high temperatures are a prerequisite for driving significant fusion reactions. The fascinating fourth state of matter at high temperatures is known as plasma. It is only in this fourth state of matter that the nuclei of two light atoms can fuse, releasing the excess energy that was needed to separately bind each of the original two nuclei. Because the nuclei of atoms carry a net positive electric charge, they repel each other. Hydrogenic nuclei, such as deuterium and tritium, must be heated to approximately 100 million degrees Celsius to overcome this electric repulsion and fuse. There have been dramatic recent advances in both the scientific understanding of fusion plasmas and in the generation of fusion power in the laboratory. Today, there is little doubt that fusion energy production is feasible. For this reason, the general thrust of fusion research has focused on configuration improvements leading to an economically competitive product. The risk of conflicts arising from energy shortages and supply cutoffs, as well as the risk of severe environmental impacts from existing methods of energy production, are among the reasons to pursue these opportunities [1]. In this paper we review the tremendous scientific progress in fusion during the last 10 years. We utilize the detailed engineering design activities of burning plasma experiments as well as conceptual fusion power plant studies to describe our visions of attractive fusion power plants. We use these studies to compare technical requirements

  12. Global terrestrial water storage capacity and flood potential using GRACE

    NASA Astrophysics Data System (ADS)

    Reager, J. T.; Famiglietti, J. S.

    2009-12-01

    Terrestrial water storage anomaly from the Gravity Recovery and Climate Experiment (GRACE) and precipitation observations from the Global Precipitation Climatology Project (GPCP) are applied at the regional scale to show the usefulness of a remotely sensed, storage-based flood potential method. Over the GRACE record length, instances of repeated maxima in water storage anomaly that fall short of variable maxima in cumulative precipitation suggest an effective storage capacity for a given region, beyond which additional precipitation must be met by marked increases in runoff or evaporation. These saturation periods indicate the possible transition to a flood-prone situation. To investigate spatially and temporally variable storage overflow, a monthly storage deficit variable is created and a global map of effective storage capacity is presented for possible use in land surface models. To highlight a flood-potential application, we design a monthly global flood index and compare with Dartmouth Flood Observatory flood maps.

  13. Potential energy surfaces of quintet and singlet O4.

    PubMed

    Paukku, Yuliya; Yang, Ke R; Varga, Zoltan; Song, Guoliang; Bender, Jason D; Truhlar, Donald G

    2017-07-21

    We present global ground-state potential energy surfaces for the quintet and singlet spin states of the O4 system that are suitable for treating high-energy vibrational-rotational energy transfer and collision-induced dissociation in electronically adiabatic, spin-conserving O2-O2 collisions. The surfaces are based on MS-CASPT2/maug-cc-pVTZ electronic structure calculations with scaled external correlation. The active space has 16 electrons in 12 orbitals. The calculations cover nine kinds of geometrical arrangements corresponding to dissociative diatom-diatom collisions of O2, geometries corresponding to O3-O, geometries identified by running trajectories, and geometries along linear synchronous transit paths. The global ground-state potential energy surfaces were obtained by a many-body approach with an accurate O-O pairwise interaction and a fit of the many-body interaction to 12 684 electronic structure data points for the singlet and 10 543 electronic structure data points for the quintet. The many-body fit is based on permutationally invariant polynomials in terms of bond-order functions of the six interatomic distances; the bond-order functions are mixed exponential-Gaussian functions.

  14. Potential energy surfaces of quintet and singlet O4

    NASA Astrophysics Data System (ADS)

    Paukku, Yuliya; Yang, Ke R.; Varga, Zoltan; Song, Guoliang; Bender, Jason D.; Truhlar, Donald G.

    2017-07-01

    We present global ground-state potential energy surfaces for the quintet and singlet spin states of the O4 system that are suitable for treating high-energy vibrational-rotational energy transfer and collision-induced dissociation in electronically adiabatic, spin-conserving O2-O2 collisions. The surfaces are based on MS-CASPT2/maug-cc-pVTZ electronic structure calculations with scaled external correlation. The active space has 16 electrons in 12 orbitals. The calculations cover nine kinds of geometrical arrangements corresponding to dissociative diatom-diatom collisions of O2, geometries corresponding to O3-O, geometries identified by running trajectories, and geometries along linear synchronous transit paths. The global ground-state potential energy surfaces were obtained by a many-body approach with an accurate O-O pairwise interaction and a fit of the many-body interaction to 12 684 electronic structure data points for the singlet and 10 543 electronic structure data points for the quintet. The many-body fit is based on permutationally invariant polynomials in terms of bond-order functions of the six interatomic distances; the bond-order functions are mixed exponential-Gaussian functions.

  15. Net global warming potential and greenhouse gas intensity

    USDA-ARS?s Scientific Manuscript database

    Various methods exist to calculate global warming potential (GWP) and greenhouse gas intensity (GHG) as measures of net greenhouse gas (GHG) emissions from agroecosystems. Little is, however, known about net GWP and GHGI that account for all sources and sinks of GHG emissions. Sources of GHG include...

  16. Mitigation potential and costs for global agricultural greenhouse gas emissions

    USDA-ARS?s Scientific Manuscript database

    Agricultural activities are a substantial contributor to global greenhouse gas (GHG) emissions, accounting for about 58% of the world’s anthropogenic non-carbon dioxide GHG emissions and 14% of all anthropogenic GHG emissions, and agriculture is often viewed as a potential source of relatively low-c...

  17. Shifting Global Invasive Potential of European Plants with Climate Change

    PubMed Central

    Peterson, A. Townsend; Stewart, Aimee; Mohamed, Kamal I.; Araújo, Miguel B.

    2008-01-01

    Global climate change and invasions by nonnative species rank among the top concerns for agents of biological loss in coming decades. Although each of these themes has seen considerable attention in the modeling and forecasting communities, their joint effects remain little explored and poorly understood. We developed ecological niche models for 1804 species from the European flora, which we projected globally to identify areas of potential distribution, both at present and across 4 scenarios of future (2055) climates. As expected from previous studies, projections based on the CGCM1 climate model were more extreme than those based on the HadCM3 model, and projections based on the a2 emissions scenario were more extreme than those based on the b2 emissions scenario. However, less expected were the highly nonlinear and contrasting projected changes in distributional areas among continents: increases in distributional potential in Europe often corresponded with decreases on other continents, and species seeing expanding potential on one continent often saw contracting potential on others. In conclusion, global climate change will have complex effects on invasive potential of plant species. The shifts and changes identified in this study suggest strongly that biological communities will see dramatic reorganizations in coming decades owing to shifting invasive potential by nonnative species. PMID:18560572

  18. Shifting global invasive potential of European plants with climate change.

    PubMed

    Peterson, A Townsend; Stewart, Aimee; Mohamed, Kamal I; Araújo, Miguel B

    2008-06-18

    Global climate change and invasions by nonnative species rank among the top concerns for agents of biological loss in coming decades. Although each of these themes has seen considerable attention in the modeling and forecasting communities, their joint effects remain little explored and poorly understood. We developed ecological niche models for 1804 species from the European flora, which we projected globally to identify areas of potential distribution, both at present and across 4 scenarios of future (2055) climates. As expected from previous studies, projections based on the CGCM1 climate model were more extreme than those based on the HadCM3 model, and projections based on the a2 emissions scenario were more extreme than those based on the b2 emissions scenario. However, less expected were the highly nonlinear and contrasting projected changes in distributional areas among continents: increases in distributional potential in Europe often corresponded with decreases on other continents, and species seeing expanding potential on one continent often saw contracting potential on others. In conclusion, global climate change will have complex effects on invasive potential of plant species. The shifts and changes identified in this study suggest strongly that biological communities will see dramatic reorganizations in coming decades owing to shifting invasive potential by nonnative species.

  19. Computed potential energy surfaces for chemical reactions

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.

    1990-01-01

    The objective was to obtain accurate potential energy surfaces (PES's) for a number of reactions which are important in the H/N/O combustion process. The interest in this is centered around the design of the SCRAM jet engine for the National Aerospace Plane (NASP), which was envisioned as an air-breathing hydrogen-burning vehicle capable of reaching velocities as large as Mach 25. Preliminary studies indicated that the supersonic flow in the combustor region of the scram jet engine required accurate reaction rate data for reactions in the H/N/O system, some of which was not readily available from experiment. The most important class of combustion reactions from the standpoint of the NASP project are radical recombinaton reactions, since these reactions result in most of the heat release in the combustion process. Theoretical characterizations of the potential energy surfaces for these reactions are presented and discussed.

  20. Computed potential energy surfaces for chemical reactions

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.

    1994-01-01

    Quantum mechanical methods have been used to compute potential energy surfaces for chemical reactions. The reactions studied were among those believed to be important to the NASP and HSR programs and included the recombination of two H atoms with several different third bodies; the reactions in the thermal Zeldovich mechanism; the reactions of H atom with O2, N2, and NO; reactions involved in the thermal De-NO(x) process; and the reaction of CH(squared Pi) with N2 (leading to 'prompt NO'). These potential energy surfaces have been used to compute reaction rate constants and rates of unimolecular decomposition. An additional application was the calculation of transport properties of gases using a semiclassical approximation (and in the case of interactions involving hydrogen inclusion of quantum mechanical effects).

  1. Potential energy surfaces of Polonium isotopes

    NASA Astrophysics Data System (ADS)

    Nerlo-Pomorska, B.; Pomorski, K.; Schmitt, C.; Bartel, J.

    2015-11-01

    The evolution of the potential energy landscape is analysed in detail for ten even-even polonium isotopes in the mass range 188\\lt A\\lt 220 as obtained within the macroscopic-microscopic approach, relying on the Lublin-Strasbourg drop model and the Yukawa-folded single-particle energies for calculating the microscopic shell and pairing corrections. A variant of the modified Funny-Hills nuclear shape parametrization is used to efficiently map possible fission paths. The approach explains the main features of the fragment partition as measured in low-energy fission along the polonium chain. The latter lies in a transitional region of the nuclear chart, and will be essential to consistently understand the evolution of fission properties from neutron-deficient mercury to heavy actinides. The ability of our method to predict fission observables over such an extended region looks promising.

  2. Global warming potentials; Part 7 of 7 supporting documents. Sector-specific issues and reporting methodologies supporting the general guidelines for voluntary reporting of greenhouse gases under Section 1605(b) of the Energy Policy Act of 1992; Public review draft

    SciTech Connect

    Not Available

    1994-05-31

    This document provides methods to account for the different effects of different gases on the atmosphere. It discusses the rationale and uses for simplified measures to represent human-related effects on climate and provides a brief introduction to a major index, the global warming potential (GWP) index. Appendix 7.A analyzes the science underlying the development of indices for concerns about climate, which is still evolving, evaluates the usefulness of currently available indices, and presents the state of the art for numerical indices and their uncertainties. For concerns about climate, the Intergovernmental Panel on Climate Change (IPCC) has been instrumental in examining relative indices for comparing the radiative influences of greenhouse gases. The IPCC developed the concept of GWPs to provide a simple representation of the relative effects on climate resulting from a unit mass emission of a greenhouse gas. Alternative measures and variations on the definition of GWPs have also been considered and reported.

  3. The Wind Energy Potential of Iceland

    NASA Astrophysics Data System (ADS)

    Nawri, Nikolai; Nína Petersen, Guðrún; Bjornsson, Halldór; Hahmann, Andrea N.; Jónasson, Kristján; Bay Hasager, Charlotte; Clausen, Niels-Erik

    2014-05-01

    While Iceland has an abundant wind energy resource, its use for electrical power production has so far been limited. Electricity in Iceland is generated primarily from hydro- and geothermal sources, and adding wind energy has so far not been considered practical or even necessary. However, wind energy is becoming a more viable option, as opportunities for new hydro- or geothermal power installations become limited. In order to obtain an estimate of the wind energy potential of Iceland, a wind atlas has been developed as part of the joint Nordic project 'Improved Forecast of Wind, Waves and Icing' (IceWind). Downscaling simulations performed with the Weather Research and Forecasting (WRF) model were used to determine the large-scale wind energy potential of Iceland. Local wind speed distributions are represented by Weibull statistics. The shape parameter across Iceland varies between 1.2 and 3.6, with the lowest values indicative of near-exponential distributions at sheltered locations, and the highest values indicative of normal distributions at exposed locations in winter. Compared with summer, average power density in winter is increased throughout Iceland by a factor of 2.0 - 5.5. In any season, there are also considerable spatial differences in average wind power density. Relative to the average value within 10 km of the coast, power density across Iceland varies between 50 - 250%, excluding glaciers, or between 300 - 1500 W m-2 at 50 m above ground level in winter. At intermediate elevations of 500 - 1000 m above mean sea level, power density is independent of the distance to the coast. In addition to seasonal and spatial variability, differences in average wind speed and power density also exist for different wind directions. Along the coast in winter, power density of onshore winds is higher by 100 - 700 W m-2 than that of offshore winds. The regions with the highest average wind speeds are impractical for wind farms, due to the distances from road

  4. Potential Energy Curves of Hydrogen Fluoride

    NASA Technical Reports Server (NTRS)

    Fallon, Robert J.; Vanderslice, Joseph T.; Mason, Edward A.

    1960-01-01

    Potential energy curves for the X(sup 1)sigma+ and V(sup 1)sigma+ states of HF and DF have been calculated by the Rydberg-Klein-Rees method. The results calculated from the different sets of data for HF and DF are found to be in very good agreement. The theoretical results of Karo are compared to the experimental results obtained here.

  5. Energy Savings Potential of Radiative Cooling Technologies

    SciTech Connect

    Fernandez, Nicholas; Wang, Weimin; Alvine, Kyle J.; Katipamula, Srinivas

    2015-11-30

    Pacific Northwest National Laboratory (PNNL), with funding from the U.S. Department of Energy’s (DOE’s) Building Technologies Program (BTP), conducted a study to estimate, through simulation, the potential cooling energy savings that could be achieved through novel approaches to capturing free radiative cooling in buildings, particularly photonic ‘selective emittance’ materials. This report documents the results of that study.

  6. Potential energy landscapes of tetragonal pyramid molecules

    NASA Astrophysics Data System (ADS)

    Yoshida, Yuichiro; Sato, Hirofumi; Morgan, John W. R.; Wales, David J.

    2016-11-01

    Hiraoka et al. have developed a self-assembling system referred to as a nanocube (Hiraoka et al., 2008). In the present contribution a coarse-grained model for this system is analysed, focusing on how the potential energy landscape for self-assembly is related to the geometry of the building blocks. We find that six molecules assemble to form various clusters, with cubic and sheet structures the most stable. The relative stability is determined by the geometry of the building blocks.

  7. Potential Energy Surfaces and Dynamics of High Energy Species

    DTIC Science & Technology

    2009-04-13

    such calculations with dynamics and condensed phase models, and (b) apply these methods to design and evaluate potentially new high energy species. The...IBM SP2 at the Maui High Performance Computation Center, the heat of formation for 1 is predicted to be 456.8 kcallmol. This translates to an l sp...which numerical derivatives become trivially parallel in a coarse-grained sense by having each function evaluation performed on a different node. If

  8. Review of Potential Characterization Techniques in Approaching Energy and Sustainability

    SciTech Connect

    LePoire, David

    2014-03-20

    Societal prosperity is linked to sustainable energy and a healthy environment. But, tough global challenges include increased demand for fossil fuels, while approaching peak oil production and uncertainty in the environmental impacts of energy generation. Recently, energy use was identified as a major component of economic productivity, along with capital and labor. Furthermore, other environmental resources and impacts may be nearing environmental thresholds as indicated by nine planetary environmental boundaries, many of which are linked to energy production and use. Foresight techniques could be applied to guide future actions which include emphasis on (1) energy efficiency to bridge the transition to a renewable energy economy, (2) continued research, development, and assessment of new technologies, (3) improved understanding of environment impacts including natural capital use and degradation, (4) exploration of GDP alternative measures that include both economic production and environmental impacts, and (5) international cooperation and awareness of longer-term opportunities and their associated potential scenarios. Examples from the U.S. and the international community illustrate challenges and potential.

  9. Review of Potential Characterization Techniques in Approaching Energy and Sustainability

    DOE PAGES

    LePoire, David

    2014-03-20

    Societal prosperity is linked to sustainable energy and a healthy environment. But, tough global challenges include increased demand for fossil fuels, while approaching peak oil production and uncertainty in the environmental impacts of energy generation. Recently, energy use was identified as a major component of economic productivity, along with capital and labor. Furthermore, other environmental resources and impacts may be nearing environmental thresholds as indicated by nine planetary environmental boundaries, many of which are linked to energy production and use. Foresight techniques could be applied to guide future actions which include emphasis on (1) energy efficiency to bridge the transitionmore » to a renewable energy economy, (2) continued research, development, and assessment of new technologies, (3) improved understanding of environment impacts including natural capital use and degradation, (4) exploration of GDP alternative measures that include both economic production and environmental impacts, and (5) international cooperation and awareness of longer-term opportunities and their associated potential scenarios. Examples from the U.S. and the international community illustrate challenges and potential.« less

  10. Eduction and outreach for the global energy challenge

    NASA Astrophysics Data System (ADS)

    Snieder, R.

    2008-12-01

    Energy is the life-blood of the modern world. According to the Energy Information Administration, global energy consumption is expected to grow by about 70% in the coming 25 years. Much of this growth is driven by developing countries, whose inhabitants seek a standard of living that more closely resembles that of the western world. Petroleum provides about 40% of the world-wide energy demand, and, although estimates vary, oil production is expected to peak in the relatively near-future. The combination of increased energy demand and declining petroleum supply can be a threat to political stability and is likely to lead to a shift towards coal and non-conventional oil. This will further increase CO2 emissions and thus accelerate global warming and life-altering regional climate changes. Many actions can be taken now to begin to reduce energy demand, diversify our energy portfolio, and reduce costs of energy supplies, with lower greenhouse gas emissions. This will not happen, however, without a plan and the willingness to implement such a plan. Public engagement and education in dealing with the pressing challenges and opportunities are the key to getting started now. In order to foster such engagement I have prepared the presentation "The Global Energy Challenge." This Powerpoint presentation is freely available and aims to be appealing and understandable for a broad audience. The comment-boxes in the Powerpoint presentation give ideas for a narrative. The presentation sketches the tension between increased energy demand, peak oil, the associated challenge in curbing climate change, and actions that we can take towards a sustainable energy system. The presentation gives ideas for positive action that teachers, students, businessmen, consumers, and citizens can take, and it conveys that the challenges related to our energy supply come with career opportunities, a point that is especially appealing to a young audience. I invite to help making a difference by

  11. Global potential of biospheric carbon management for climate mitigation.

    PubMed

    Canadell, Josep G; Schulze, E Detlef

    2014-11-19

    Elevated concentrations of atmospheric greenhouse gases (GHGs), particularly carbon dioxide (CO2), have affected the global climate. Land-based biological carbon mitigation strategies are considered an important and viable pathway towards climate stabilization. However, to satisfy the growing demands for food, wood products, energy, climate mitigation and biodiversity conservation-all of which compete for increasingly limited quantities of biomass and land-the deployment of mitigation strategies must be driven by sustainable and integrated land management. If executed accordingly, through avoided emissions and carbon sequestration, biological carbon and bioenergy mitigation could save up to 38 billion tonnes of carbon and 3-8% of estimated energy consumption, respectively, by 2050.

  12. Global potential of biospheric carbon management for climate mitigation

    NASA Astrophysics Data System (ADS)

    Canadell, Josep G.; Schulze, E. Detlef

    2014-11-01

    Elevated concentrations of atmospheric greenhouse gases (GHGs), particularly carbon dioxide (CO2), have affected the global climate. Land-based biological carbon mitigation strategies are considered an important and viable pathway towards climate stabilization. However, to satisfy the growing demands for food, wood products, energy, climate mitigation and biodiversity conservation—all of which compete for increasingly limited quantities of biomass and land—the deployment of mitigation strategies must be driven by sustainable and integrated land management. If executed accordingly, through avoided emissions and carbon sequestration, biological carbon and bioenergy mitigation could save up to 38 billion tonnes of carbon and 3-8% of estimated energy consumption, respectively, by 2050.

  13. Global Auroral Energy Deposition Derived from Polar UVI Images

    NASA Technical Reports Server (NTRS)

    Fillingim, M. O.; Brittnacher, M. J.; Elsen, R.; Parks, G. K.; Spann, J. F., Jr.; Germany, G. A.

    1997-01-01

    Quantitative measurement of the transfer of energy and momentum to the ionosphere from the solar wind is one of the main objectives of the ISTP program. Global measurement of auroral energy deposition derived from observations of the longer wavelength LBH band emissions made by the Ultraviolet Imager on the Polar spacecraft is one of the key elements in this satellite and ground-based instrument campaign. These "measurements" are inferred by combining information from consecutive images using different filters and have a time resolution on the average of three minutes and are made continuously over a 5 to 8 hour period during each 18 hour orbit of the Polar spacecraft. The energy deposition in the ionosphere from auroral electron precipitation augments are due to Joule heating associated with field aligned currents. Assuming conjugacy of energy deposition between the two hemispheres the total energy input to the ionosphere through electron precipitation can be determined at high time resolution. Previously, precipitating particle measurements along the tracks of low altitude satellites provided only local measurements and the global energy precipitation could be inferred through models but not directly measured. We use the UVI images for the entire month of January 1997 to estimate the global energy deposition at high time resolution. We also sort the energy deposition into sectors to find possible trends, for example, on the dayside and nightside, or the dawn and dusk sides.

  14. Long-term global nuclear energy and fuel cycle strategies

    SciTech Connect

    Krakowski, R.A.

    1997-09-24

    The Global Nuclear Vision Project is examining, using scenario building techniques, a range of long-term nuclear energy futures. The exploration and assessment of optimal nuclear fuel-cycle and material strategies is an essential element of the study. To this end, an established global E{sup 3} (energy/economics/environmental) model has been adopted and modified with a simplified, but comprehensive and multi-regional, nuclear energy module. Consistent nuclear energy scenarios are constructed using this multi-regional E{sup 3} model, wherein future demands for nuclear power are projected in price competition with other energy sources under a wide range of long-term demographic (population, workforce size and productivity), economic (price-, population-, and income-determined demand for energy services, price- and population-modified GNP, resource depletion, world-market fossil energy prices), policy (taxes, tariffs, sanctions), and top-level technological (energy intensity and end-use efficiency improvements) drivers. Using the framework provided by the global E{sup 3} model, the impacts of both external and internal drivers are investigated. The ability to connect external and internal drivers through this modeling framework allows the study of impacts and tradeoffs between fossil- versus nuclear-fuel burning, that includes interactions between cost, environmental, proliferation, resource, and policy issues.

  15. The Potential for Space Intervention in Global Catastrophes

    NASA Astrophysics Data System (ADS)

    Hempsell, M.

    There is a growing understanding of the risks facing mankind of global catastrophe, which is defined as an event that kills a quarter the world population and risks destruction of organised society. Such catastrophes can be triggered by either naturally occurring, or arthropogenic, initiating events. And history shows that catastrophes with a natural origin do occur, with a mean separation time of around 1000 years. Anthropogenic initiated events are a recent possibility resulting from an expansion of technology capabilities, economic activity and population and, while they clearly significantly increase the total risk level above the natural background, it is more difficult to determine quantitatively by how much. Some initiating events and be directly tackled by an appropriate space capability. For example intercepting Near Earth Object before collision, or using Solar Power Satellites to eliminating carbon dioxide production in the power generation process to which many attribute global warming. Obviously prevention is the preferred option and so, not surprisingly, these particular uses of space as a means of preventing global catastrophe have received considerable attention. However space capability has a much wider potential for intervention in global catastrophes, even in those where the initiating event itself cannot be prevented. Previous work highlighting the risks through consideration of historic catastrophes has identified that global catastrophes have a complex structure with the initiating event triggering chains of vectors, which in turn trigger death causing agents. The work also highlighted that the vectors and agents during a catastrophe are similar regardless of the initiating event. This opens the possibility that space systems capable of addressing generic vectors and agents on a global scale can help deal with any global catastrophe regardless of its cause. The paper lists known (and credible) components to global catastrophes and highlight

  16. Sensitivity of Global Warming Potentials to the assumed background atmosphere

    SciTech Connect

    Wuebbles, D.J.; Patten, K.O.

    1992-03-05

    This is the first in a series of papers in which we will examine various aspects of the Global Warming Potential (GWP) concept and the sensitivity and uncertainties associated with the GWP values derived for the 1992 updated scientific assessment report of the Intergovernmental Panel on Climate Change (IPCC). One of the authors of this report (DJW) helped formulate the GWP concept for the first IPCC report in 1990. The Global Warming Potential concept was developed for that report as an attempt to fulfill the request from policymakers for a way of relating the potential effects on climate from various greenhouse gases, in much the same way as the Ozone Depletion Potential (ODP) concept (Wuebbles, 1981) is used in policy analyses related to concerns about the relative effects of CFCs and other compounds on stratospheric ozone destruction. We are also coauthors of the section on radiative forcing and Global Warming Potentials for the 1992 IPCC update; however, there was too little time to prepare much in the way of new research material for that report. Nonetheless, we have recognized for some time that there are a number of uncertainties and limitations associated with the definition of GWPs used in both the original and new IPCC reports. In this paper, we examine one of those uncertainties, namely, the effect of the assumed background atmospheric concentrations on the derived GWPs. Later papers will examine the sensitivity of GWPs to other uncertainties and limitations in the current concept.

  17. Diabatic heating fields and the generation of available potential energy during FGGE

    NASA Technical Reports Server (NTRS)

    Salstein, David A.; Rosen, Richard D.; Baker, Wayman E.; Kalnay, Eugenia

    1986-01-01

    Global diabatic heating is estimated using fields of directly computed heating components, in particular those due to shortwave radiation, longwave radiation, sensible heating, and latent heating produced every 6 hours. The role of average fields of diabatic heating in the generation of available potential energy is examined. It is observed that latent heating is most significant in generating available potential energy.

  18. Diabatic heating fields and the generation of available potential energy during FGGE

    NASA Technical Reports Server (NTRS)

    Salstein, David A.; Rosen, Richard D.; Baker, Wayman E.; Kalnay, Eugenia

    1986-01-01

    Global diabatic heating is estimated using fields of directly computed heating components, in particular those due to shortwave radiation, longwave radiation, sensible heating, and latent heating produced every 6 hours. The role of average fields of diabatic heating in the generation of available potential energy is examined. It is observed that latent heating is most significant in generating available potential energy.

  19. Topography, energy and the global distribution of bird species richness

    PubMed Central

    Davies, Richard G; Orme, C. David L; Storch, David; Olson, Valerie A; Thomas, Gavin H; Ross, Simon G; Ding, Tzung-Su; Rasmussen, Pamela C; Bennett, Peter M; Owens, Ian P.F; Blackburn, Tim M; Gaston, Kevin J

    2007-01-01

    A major goal of ecology is to determine the causes of the latitudinal gradient in global distribution of species richness. Current evidence points to either energy availability or habitat heterogeneity as the most likely environmental drivers in terrestrial systems, but their relative importance is controversial in the absence of analyses of global (rather than continental or regional) extent. Here we use data on the global distribution of extant continental and continental island bird species to test the explanatory power of energy availability and habitat heterogeneity while simultaneously addressing issues of spatial resolution, spatial autocorrelation, geometric constraints upon species' range dynamics, and the impact of human populations and historical glacial ice-cover. At the finest resolution (1°), topographical variability and temperature are identified as the most important global predictors of avian species richness in multi-predictor models. Topographical variability is most important in single-predictor models, followed by productive energy. Adjusting for null expectations based on geometric constraints on species richness improves overall model fit but has negligible impact on tests of environmental predictors. Conclusions concerning the relative importance of environmental predictors of species richness cannot be extrapolated from one biogeographic realm to others or the globe. Rather a global perspective confirms the primary importance of mountain ranges in high-energy areas. PMID:17311781

  20. Topography, energy and the global distribution of bird species richness.

    PubMed

    Davies, Richard G; Orme, C David L; Storch, David; Olson, Valerie A; Thomas, Gavin H; Ross, Simon G; Ding, Tzung-Su; Rasmussen, Pamela C; Bennett, Peter M; Owens, Ian P F; Blackburn, Tim M; Gaston, Kevin J

    2007-05-07

    A major goal of ecology is to determine the causes of the latitudinal gradient in global distribution of species richness. Current evidence points to either energy availability or habitat heterogeneity as the most likely environmental drivers in terrestrial systems, but their relative importance is controversial in the absence of analyses of global (rather than continental or regional) extent. Here we use data on the global distribution of extant continental and continental island bird species to test the explanatory power of energy availability and habitat heterogeneity while simultaneously addressing issues of spatial resolution, spatial autocorrelation, geometric constraints upon species' range dynamics, and the impact of human populations and historical glacial ice-cover. At the finest resolution (1 degree), topographical variability and temperature are identified as the most important global predictors of avian species richness in multi-predictor models. Topographical variability is most important in single-predictor models, followed by productive energy. Adjusting for null expectations based on geometric constraints on species richness improves overall model fit but has negligible impact on tests of environmental predictors. Conclusions concerning the relative importance of environmental predictors of species richness cannot be extrapolated from one biogeographic realm to others or the globe. Rather a global perspective confirms the primary importance of mountain ranges in high-energy areas.

  1. A nine-dimensional global potential energy surface for NH4(X(2)A(1)) and kinetics studies on the H + NH3↔ H2 + NH2 reaction.

    PubMed

    Li, Jun; Guo, Hua

    2014-04-14

    Extensive ab initio calculations of the stationary points in the NH4(X(2)A1) system are reported using both coupled cluster and multi-reference configuration interaction methods. In addition, more than 100 000 points are generated over a large configuration space and energy range (6 eV) using the explicitly correlated unrestricted coupled cluster method with single, double, and perturbative triple excitations with the augmented correlation-consistent polarized triple zeta basis set (UCCSD(T)-F12a/aug-cc-pVTZ). Using the recently proposed permutation-invariant polynomial neural network (PIP-NN) method, these points are accurately fit to an analytical form with a total root mean squared error (RMSE) of 3.4 meV (0.08 kcal mol(-1)). Both the abstraction and exchange channels as well as the metastable ammonium radical (NH4) are included in this potential energy surface. Transition-state theory and quasi-classical trajectory calculations have been performed to obtain the rate constants for the abstraction reaction and its reverse. Comparison with available experimental results is satisfactory, providing supporting evidence for the accuracy of the potential.

  2. From Extraction to Renewal: A Global Campaign for Healthy Energy.

    PubMed

    Wang, Jennifer S; Euripidou, Rico; Armstrong, Fiona; Jensen, Génon K; Karliner, Josh; Guinto, Renzo R; Zhao, Ang; Narayanan, Divya; Orris, Peter

    2016-02-01

    A global movement is emerging in the health sector to engage in discourse and advocacy on the health impacts and health costs of energy choices--specifically the health harms of extractive, climate-disrupting energy sources such as coal and gas. Individuals and organizations in the health sector have begun to address climate and energy issues at multiple levels of engagement, including with others in the health sector, with pollution-affected communities, with policy makers, and with the media. We present recent examples of health sector advocacy and leadership on the health impacts of energy choices and opportunities for broadening and deepening the movement.

  3. The Computation of Potential Harmonic Coefficients Using Global Crustal Information

    NASA Astrophysics Data System (ADS)

    Tsoulis, D.

    Topographic/isostatic potential harmonic coefficients can be computed from a global elevation model, when one accounts for the compensation of the upper crust according to a certain model of isostasy. The theory is based on a series expansion of the inverse distance function, which enables an efficient computation of the dimensionless poten- tial coefficients on the sphere. The availability of global crustal models permits the application of the same theory, with the exception that here the theoretically defined boundary between upper crust and mantle is replaced with crustal thickness informa- tion derived mainly from processing repeated seismic observations. The present paper deals with the spherical harmonic analysis of such a model, namely the CRUST 2.0 global crustal model, and compares the derived spectrum with the respective coeffi- cient sets delivered by the application of idealized isostatic models such as those of Airy/Heiskanen or Pratt/Hayford.

  4. Global Warming and Energy Transition: A Public Policy Imperative

    NASA Astrophysics Data System (ADS)

    Stone, G. T.

    2006-12-01

    The historic transition from fossil fuels to alternative energy resources has begun. This development is commonly attributed to increasing energy costs and the need for energy security. Looming ever larger, however, is the issue that will soon drive the third energy revolution: global warming. A preponderance of evidence documents accelerating warming, enlarging impacts, and human causes -- principally combustion of fossil fuels. The carbon dioxide (C02) content of Earth's atmosphere has increased more than 35 percent since the beginning of the industrial revolution and is the highest in 650,000 years. This dramatic rise of C02 and attendant positive feedbacks are already forcing significant impacts worldwide. These include atmospheric warming with shifting climatic and habitat zones, spreading tropical disease, and more extreme weather events; rapid ice loss at high latitude and high altitude; ocean warming and acidification with coral reef bleaching and intensifying tropical storms; rising sea level; and accelerating extinction rates. The 2007 draft report of the Intergovernmental Panel on Climate Change (IPCC) predicts greater warming than in previous models. A tipping point to abrupt climate change may be imminent. It is incumbent upon geoscientists and geoscience educators to assume leadership in addressing this challenge through public outreach and general education. The following topics should be integrated into all appropriate courses: the evidence of global warming and its causes; observed present and predicted future impacts of global warming; mitigation and adaptation strategies; and implications for energy policies and economic opportunities. New entry-level science and general education courses -- such as Climate Change Fundamentals and Energy in Nature, Technology, and Society -- are proving to be effective should be widely developed In addition, by workshops and presentations to civic and business organizations and by demonstrated examples of

  5. California's biomass and its energy potential

    SciTech Connect

    Lucarelli, F.B. Jr.

    1980-04-01

    The potentials for using California's biomass for energy have been assessed. The study relies on the recent work of Amory Lovins and Lawrence Berkeley Laboratory's (LBL) Distributed Energy System's Project to specify an energy future for Californians. These works identify transportation fuels as the most valuable energy conversion for biomass. Within this context, the extent of five categories of terrestial biomass is estimated, in addition to the environmental impacts and monetary cost of collecting and transporting each biomass category. Estimates of the costs of transforming biomass into different fuels as well as a survey of government's role in a biomass energy program are presented. The major findings are summarized below. (1) California's existing biomass resources are sufficient to provide only 20 percent of its future liquid fuel requirements. (2) Meeting the full transportation demand with biomass derived fuels will require the development of exotic biomass sources such as kelp farms and significant reductions in automobile travel in the State. (3) Under assumptions of moderate increases in gasoline prices and without major new government incentives, the cost of transforming biomass into transport fuels will be competitive with the price of gasoline on a Btu basis by the year 1990. (4) The environmental impacts of collecting most forms of biomass are beneficial and should reduce air pollution from agricultural burning and water pollution from feedlot and dairy farm runoff. Moreover, the collection of logging residues should improve timber stand productivity and the harvest of chaparral should reduce the risk of wildfire in the State. (5) The institutional context for implementing biomass energy projects is complex and fragmented.

  6. Pseudospectral Gaussian quantum dynamics: Efficient sampling of potential energy surfaces.

    PubMed

    Heaps, Charles W; Mazziotti, David A

    2016-04-28

    Trajectory-based Gaussian basis sets have been tremendously successful in describing high-dimensional quantum molecular dynamics. In this paper, we introduce a pseudospectral Gaussian-based method that achieves accurate quantum dynamics using efficient, real-space sampling of the time-dependent basis set. As in other Gaussian basis methods, we begin with a basis set expansion using time-dependent Gaussian basis functions guided by classical mechanics. Unlike other Gaussian methods but characteristic of the pseudospectral and collocation methods, the basis set is tested with N Dirac delta functions, where N is the number of basis functions, rather than using the basis function as test functions. As a result, the integration for matrix elements is reduced to function evaluation. Pseudospectral Gaussian dynamics only requires O(N) potential energy calculations, in contrast to O(N(2)) evaluations in a variational calculation. The classical trajectories allow small basis sets to sample high-dimensional potentials. Applications are made to diatomic oscillations in a Morse potential and a generalized version of the Henon-Heiles potential in two, four, and six dimensions. Comparisons are drawn to full analytical evaluation of potential energy integrals (variational) and the bra-ket averaged Taylor (BAT) expansion, an O(N) approximation used in Gaussian-based dynamics. In all cases, the pseudospectral Gaussian method is competitive with full variational calculations that require a global, analytical, and integrable potential energy surface. Additionally, the BAT breaks down when quantum mechanical coherence is particularly strong (i.e., barrier reflection in the Morse oscillator). The ability to obtain variational accuracy using only the potential energy at discrete points makes the pseudospectral Gaussian method a promising avenue for on-the-fly dynamics, where electronic structure calculations become computationally significant.

  7. Determining the global maximum biofuel production potential without conflicting with food and feed consumption

    NASA Astrophysics Data System (ADS)

    Pumkaew, Watcharapol

    This study tries to resolve the competition between food and biofuel by balancing the allocation between food and feed areas and biofuel areas for the entire world. The maximum energy production is calculated by determining the theoretical amount of energy that can be grown, once food and feed consumption is taken into account, based on the assumption that unprotected grass and woody lands and forest lands can be converted into cultivated lands. The total optimum land area for biofuel energy, 4,926.49 Mha, consists of corn, rapeseed, sugar beet, sugar cane, and grasses. When considering energy conversion efficiency, the maximum energy production is 520.5 EJ. Of this amount, 5.9 EJ can be identified with food and feed energy and 514.6 EJ can be identified with biofuel energy. This result is a theoretical value to illustrate the potential global land area for biofuel. The biofuel energy production per area of land in this study is calculated to be 0.12 EJ/Mha. With regards to the limitation in the degree of invasion by grass and woody land and forest land areas, if it is not more than 10 percent, the biofuel energy production can serve about 76 percent of energy demand for transportation in 2009. The total optimum land area is about 45 percent of global cultivated land area. Sensitivity analysis shows that the land area of corn, sweet sorghum, sugarcane, grass, and woody crops is sensitive to energy content. The land area of sweet sorghum and soybeans is sensitive to the land area for food and feed consumption. Also, the land area of corn, sugar beet, and sugarcane is sensitive to the potential crop land area. This study, done at the global level, can also apply in a local area by using local constraints.

  8. The Global Burden of Potential Productivity Loss from Uncorrected Presbyopia.

    PubMed

    Frick, Kevin D; Joy, Susan M; Wilson, David A; Naidoo, Kovin S; Holden, Brien A

    2015-08-01

    The onset of presbyopia in middle adulthood results in potential losses in productivity among otherwise healthy adults if uncorrected or undercorrected. The economic burden could be significant in lower-income countries, where up to 94% of cases may be uncorrected or undercorrected. This study estimates the global burden of potential productivity lost because of uncorrected functional presbyopia. Population data from the US Census Bureau were combined with the estimated presbyopia prevalence, age of onset, employment rate, gross domestic product (GDP) per capita in current US dollars, and near vision impairment disability weights from the Global Burden of Disease 2010 study to estimate the global loss of productivity from uncorrected and undercorrected presbyopia in each country in 2011. To allow comparison with earlier work, we also calculated the loss with the conservative assumption that the contribution to productivity extends only up to 50 years of age. The economic modeling did not require the use of subjects. We estimated the number of cases of uncorrected or undercorrected presbyopia in each country among the working-age population. The number of working-age cases was multiplied by the labor force participation rate, the employment rate, a disability weight, and the GDP per capita to estimate the potential loss of GDP due to presbyopia. The outcome being measured is the lost productivity in 2011 US dollars resulting from uncorrected or undercorrected presbyopia. There were an estimated 1.272 billion cases of presbyopia worldwide in 2011. A total of 244 million cases, uncorrected or undercorrected among people aged <50 years, were associated with a potential productivity loss of US $11.023 billion (0.016% of global GDP). If all those people aged <65 years are assumed to be productive, the potential productivity loss would be US $25.367 billion or 0.037% of global GDP. Correcting presbyopia to the level achieved in Europe would reduce the burden to US $1

  9. Generalized Potential Energy Finite Elements for Modeling Molecular Nanostructures.

    PubMed

    Chatzieleftheriou, Stavros; Adendorff, Matthew R; Lagaros, Nikos D

    2016-10-24

    The potential energy of molecules and nanostructures is commonly calculated in the molecular mechanics formalism by superimposing bonded and nonbonded atomic energy terms, i.e. bonds between two atoms, bond angles involving three atoms, dihedral angles involving four atoms, nonbonded terms expressing the Coulomb and Lennard-Jones interactions, etc. In this work a new, generalized numerical simulation is presented for studying the mechanical behavior of three-dimensional nanostructures at the atomic scale. The energy gradient and Hessian matrix of such assemblies are usually computed numerically; a potential energy finite element model is proposed herein where these two components are expressed analytically. In particular, generalized finite elements are developed that express the interactions among atoms in a manner equivalent to that invoked in simulations performed based on the molecular dynamics method. Thus, the global tangent stiffness matrix for any nanostructure is formed as an assembly of the generalized finite elements and is directly equivalent to the Hessian matrix of the potential energy. The advantages of the proposed model are identified in terms of both accuracy and computational efficiency. In the case of popular force fields (e.g., CHARMM), the computation of the Hessian matrix by implementing the proposed method is of the same order as that of the gradient. This analysis can be used to minimize the potential energy of molecular systems under nodal loads in order to derive constitutive laws for molecular systems where the entropy and solvent effects are neglected and can be approximated as solids, such as double stranded DNA nanostructures. In this context, the sequence dependent stretch modulus for some typical base pairs step is calculated.

  10. Computed Potential Energy Surfaces and Minimum Energy Pathways for Chemical Reactions

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.; Langhoff, S. R. (Technical Monitor)

    1994-01-01

    Computed potential energy surfaces are often required for computation of such parameters as rate constants as a function of temperature, product branching ratios, and other detailed properties. For some dynamics methods, global potential energy surfaces are required. In this case, it is necessary to obtain the energy at a complete sampling of all the possible arrangements of the nuclei, which are energetically accessible, and then a fitting function must be obtained to interpolate between the computed points. In other cases, characterization of the stationary points and the reaction pathway connecting them is sufficient. These properties may be readily obtained using analytical derivative methods. We have found that computation of the stationary points/reaction pathways using CASSCF/derivative methods, followed by use of the internally contracted CI method to obtain accurate energetics, gives usefull results for a number of chemically important systems. The talk will focus on a number of applications including global potential energy surfaces, H + O2, H + N2, O(3p) + H2, and reaction pathways for complex reactions, including reactions leading to NO and soot formation in hydrocarbon combustion.

  11. Computed Potential Energy Surfaces and Minimum Energy Pathways for Chemical Reactions

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.; Langhoff, S. R. (Technical Monitor)

    1994-01-01

    Computed potential energy surfaces are often required for computation of such parameters as rate constants as a function of temperature, product branching ratios, and other detailed properties. For some dynamics methods, global potential energy surfaces are required. In this case, it is necessary to obtain the energy at a complete sampling of all the possible arrangements of the nuclei, which are energetically accessible, and then a fitting function must be obtained to interpolate between the computed points. In other cases, characterization of the stationary points and the reaction pathway connecting them is sufficient. These properties may be readily obtained using analytical derivative methods. We have found that computation of the stationary points/reaction pathways using CASSCF/derivative methods, followed by use of the internally contracted CI method to obtain accurate energetics, gives usefull results for a number of chemically important systems. The talk will focus on a number of applications including global potential energy surfaces, H + O2, H + N2, O(3p) + H2, and reaction pathways for complex reactions, including reactions leading to NO and soot formation in hydrocarbon combustion.

  12. Global Energetics of Solar Flares. III. Nonthermal Energies

    NASA Astrophysics Data System (ADS)

    Aschwanden, Markus J.; Holman, Gordon; O'Flannagain, Aidan; Caspi, Amir; McTiernan, James M.; Kontar, Eduard P.

    2016-11-01

    This study entails the third part of a global flare energetics project, in which Ramaty High-Energy Solar Spectroscopic Imager (RHESSI) data of 191 M and X-class flare events from the first 3.5 years of the Solar Dynamics Observatory mission are analyzed. We fit a thermal and a nonthermal component to RHESSI spectra, yielding the temperature of the differential emission measure (DEM) tail, the nonthermal power-law slope and flux, and the thermal/nonthermal cross-over energy e co. From these parameters, we calculate the total nonthermal energy E nt in electrons with two different methods: (1) using the observed cross-over energy e co as low-energy cutoff, and (2) using the low-energy cutoff e wt predicted by the warm thick-target bremsstrahlung model of Kontar et al. Based on a mean temperature of T e = 8.6 MK in active regions, we find low-energy cutoff energies of {e}{wt}=6.2+/- 1.6 {keV} for the warm-target model, which is significantly lower than the cross-over energies {e}{co}=21+/- 6 {keV}. Comparing with the statistics of magnetically dissipated energies E mag and thermal energies E th from the two previous studies, we find the following mean (logarithmic) energy ratios with the warm-target model: {E}{nt}=0.41 {E}{mag}, {E}{th}=0.08 {E}{mag}, and {E}{th}=0.15 {E}{nt}. The total dissipated magnetic energy exceeds the thermal energy in 95% and the nonthermal energy in 71% of the flare events, which confirms that magnetic reconnection processes are sufficient to explain flare energies. The nonthermal energy exceeds the thermal energy in 85% of the events, which largely confirms the warm thick-target model.

  13. Theoretical studies of potential energy surfaces

    SciTech Connect

    Harding, L.B.

    1993-12-01

    The goal of this program is to calculate accurate potential energy surfaces (PES) for both reactive and nonreactive systems. To do this the electronic Schrodinger equation must be solved. Our approach to this problem starts with multiconfiguration self-consistent field (MCSCF) reference wavefunctions. These reference wavefunctions are designed to be sufficiently flexible to accurately describe changes in electronic structure over a broad range of geometries. Electron correlation effects are included via multireference, singles and doubles configuration interaction (MRSDCI) calculations. With this approach, the authors are able to provide useful predictions of the energetics for a broad range of systems.

  14. Surface energy budget constraints on future global precipitation revisited

    NASA Astrophysics Data System (ADS)

    Bintanja, Richard; Selten, Frank M.

    2017-04-01

    Observations and climate model simulations both show that global mean precipitation (which equals surface evaporation) will increase with climate warming, but at a much lower rate than the atmospheric water content. This muted response has been attributed primarily to the nonlinear dependency of downwelling infrared radiation (which provides the energy for evaporation) on atmospheric water vapour. However, we demonstrate here that this is not a sufficient constraint. Instead, on the basis of fundamental physics we find that the redistribution of energy at the surface crucially limits changes in global evaporation (and hence precipitation). More specifically, the warming surface must re-emit about 70% of the extra energy through infrared radiation, leaving just maximum 30% for evaporation thereby explaining the muted global precipitation response. This fraction will further diminish as climate warms, meaning that precipitation increases will be even more subdued. This finding provides fundamental insights on the mechanisms behind the changing global hydrological cycle, with global and regional implications for issues such as water availability.

  15. Global Potential for Hydro-generated Electricity and Climate Change Impact

    NASA Astrophysics Data System (ADS)

    Zhou, Y.; Hejazi, M. I.; Leon, C.; Calvin, K. V.; Thomson, A. M.; Li, H. Y.

    2014-12-01

    Hydropower is a dominant renewable energy source at the global level, accounting for more than 15% of the world's total power supply. It is also very vulnerable to climate change. Improved understanding of climate change impact on hydropower can help develop adaptation measures to increase the resilience of energy system. In this study, we developed a comprehensive estimate of global hydropower potential using runoff and stream flow data derived from a global hydrologic model with a river routing sub-model, along with turbine technology performance, cost assumptions, and environmental consideration (Figure 1). We find that hydropower has the potential to supply a significant portion of the world energy needs, although this potential varies substantially by regions. Resources in a number of countries exceed by multiple folds the total current demand for electricity, e.g., Russia and Indonesia. A sensitivity analysis indicates that hydropower potential can be highly sensitive to a number of parameters including designed flow for capacity, cost and financing, turbine efficiency, and stream flow. The climate change impact on hydropower potential was evaluated by using runoff outputs from 4 climate models (HadCM3, PCM, CGCM2, and CSIRO2). It was found that the climate change on hydropower shows large variation not only by regions, but also climate models, and this demonstrates the importance of incorporating climate change into infrastructure-planning at the regional level though the existing uncertainties.

  16. Assessment of wind energy potential in Poland

    NASA Astrophysics Data System (ADS)

    Starosta, Katarzyna; Linkowska, Joanna; Mazur, Andrzej

    2014-05-01

    The aim of the presentation is to show the suitability of using numerical model wind speed forecasts for the wind power industry applications in Poland. In accordance with the guidelines of the European Union, the consumption of wind energy in Poland is rapidly increasing. According to the report of Energy Regulatory Office from 30 March 2013, the installed capacity of wind power in Poland was 2807MW from 765 wind power stations. Wind energy is strongly dependent on the meteorological conditions. Based on the climatological wind speed data, potential energy zones within the area of Poland have been developed (H. Lorenc). They are the first criterion for assessing the location of the wind farm. However, for exact monitoring of a given wind farm location the prognostic data from numerical model forecasts are necessary. For the practical interpretation and further post-processing, the verification of the model data is very important. Polish Institute Meteorology and Water Management - National Research Institute (IMWM-NRI) runs an operational model COSMO (Consortium for Small-scale Modelling, version 4.8) using two nested domains at horizontal resolutions of 7 km and 2.8 km. The model produces 36 hour and 78 hour forecasts from 00 UTC, for 2.8 km and 7 km domain resolutions respectively. Numerical forecasts were compared with the observation of 60 SYNOP and 3 TEMP stations in Poland, using VERSUS2 (Unified System Verification Survey 2) and R package. For every zone the set of statistical indices (ME, MAE, RMSE) was calculated. Forecast errors for aerological profiles are shown for Polish TEMP stations at Wrocław, Legionowo and Łeba. The current studies are connected with a topic of the COST ES1002 WIRE-Weather Intelligence for Renewable Energies.

  17. Geochemical energy potentially available to organisms in martian hydrothermal systems.

    NASA Astrophysics Data System (ADS)

    Varnes, E. S.; Jakosky, B. M.; McCollom, T. M.

    2001-11-01

    Although a global average of energy available to potentially support life from chemosynthesis on Mars has been estimated, issues of how the energy is distributed and which environments have the greatest potential to support life remain unresolved. We have begun to address these questions by developing numerical geochemical models of martian hydrothermal systems using the software package EQ3/6. In order to model hydrothermal systems, the elemental composition of the initial fluid (the groundwater) and the initial host rock with which it interacts must be defined. The host rock was defined using the composition of LEW 88516, which is similar to the martian mantle. This host rock was reacted at high temperature (350 deg C) with a series of groundwaters. Groundwaters are either pure water in equilibrium with present martian atmosphere or in equilibrium with Pathfinder-composition soils and the atmosphere. The hot fluid resulting from the rock/groundwater reaction was then reacted with increments of fresh groundwater, simulating the mixing that occurs in hydrothermal systems. During mixing, oxidation and reduction reactions are kinetically inhibited; organisms may exploit this inhibition to derive metabolic energy. The maximum amount of energy an organism can obtain from a given reaction is determined from the Gibbs free energy of that reaction. For each model run, we have calculated the Gibbs free energy of reactions that are important for terrestrial chemosynthetic organisms and likely representative for putative martians. Our results indicate that substantial amounts of energy may be derived from these reactions, but they depend sensitively on the oxidation state of the groundwater and whether saturated species precipitate to equilibrium. Thus, it is unknown whether sufficient energy is available to support martian life, although it is likely that suitable environments exist.

  18. Antiprotonic potentials from global fits to the PS209 data

    NASA Astrophysics Data System (ADS)

    Friedman, E.; Gal, A.

    2004-01-01

    The experimental results for strong interaction effects in antiprotonic atoms by the PS209 collaboration consist of high quality data for several sequences of isotopes along the periodic table. Global analysis of these data in terms of a p¯-nucleus optical potential achieves good description of the data using a s-wave finite-range p¯N interaction. Equally good fits are also obtained with a poorly-defined zero-range potential containing a p-wave term.

  19. Triton Binding Energy of Kharkov Potential

    NASA Astrophysics Data System (ADS)

    Kamada, H.; Shebeko, O.; Arslanaliev, A.

    2017-03-01

    The Kharkov potential is a recent field theoretical model of nucleon-nucleon (NN) interaction that has been built up in the framework of the instant form of relativistic dynamics starting with the total Hamiltonian of interacting meson and nucleon fields and using the method of unitary clothing transformations. The latter connect the representation of "bare" particles and the representation of "clothed" particles, i.e., the particles with physical properties. Unlike many available NN potentials each of which is the kernel of the corresponding nonrelativistic Lippmann-Schwinger (LS) equation this potential being dependent in momentum space on the Feynman-like propagators and covariant cutoff factors at the meson-nucleon vertices is the kernel of relativistic integral equations for the NN bound and scattering states. Therefore we do not need to invent any transform of a given nonrelativistic potential to its relativistic counterpart. As a feasible study, we have started with the so-called 5ch Faddeev calculation for three-nucleon bound state (triton) and obtained a reasonable value of its binding energy (-7.42 MeV).

  20. World Energy Projection System Plus (WEPS ): Global Activity Module

    EIA Publications

    2016-01-01

    The World Energy Projection System Plus (WEPS ) is a comprehensive, mid?term energy forecasting and policy analysis tool used by EIA. WEPS projects energy supply, demand, and prices by country or region, given assumptions about the state of various economies, international energy markets, and energy policies. The Global Activity Module (GLAM) provides projections of economic driver variables for use by the supply, demand, and conversion modules of WEPS . GLAM’s baseline economic projection contains the economic assumptions used in WEPS to help determine energy demand and supply. GLAM can also provide WEPS with alternative economic assumptions representing a range of uncertainty about economic growth. The resulting economic impacts of such assumptions are inputs to the remaining supply and demand modules of WEPS .

  1. World Energy Projection System Plus (WEPS ): Global Activity Module

    EIA Publications

    2016-01-01

    The World Energy Projection System Plus (WEPS ) is a comprehensive, mid?term energy forecasting and policy analysis tool used by EIA. WEPS projects energy supply, demand, and prices by country or region, given assumptions about the state of various economies, international energy markets, and energy policies. The Global Activity Module (GLAM) provides projections of economic driver variables for use by the supply, demand, and conversion modules of WEPS . GLAM’s baseline economic projection contains the economic assumptions used in WEPS to help determine energy demand and supply. GLAM can also provide WEPS with alternative economic assumptions representing a range of uncertainty about economic growth. The resulting economic impacts of such assumptions are inputs to the remaining supply and demand modules of WEPS .

  2. Potential energy surfaces of superheavy nuclei

    SciTech Connect

    Bender, M.; Rutz, K.; Maruhn, J.A.; Greiner, W.; Reinhard, P.-G. Rutz, K.; Maruhn, J.A.; Greiner, W.

    1998-10-01

    We investigate the structure of the potential energy surfaces of the superheavy nuclei {sub 158}{sup 258}Fm{sub 100}, {sub 156}{sup 264}Hs{sub 108}, {sub 166}{sup 278}112, {sub 184}{sup 298}114, and {sub 172}{sup 292}120 within the framework of self-consistent nuclear models, i.e., the Skyrme-Hartree-Fock approach and the relativistic mean-field model. We compare results obtained with one representative parametrization of each model which is successful in describing superheavy nuclei. We find systematic changes as compared to the potential energy surfaces of heavy nuclei in the uranium region: there is no sufficiently stable fission isomer any more, the importance of triaxial configurations to lower the first barrier fades away, and asymmetric fission paths compete down to rather small deformation. Comparing the two models, it turns out that the relativistic mean-field model gives generally smaller fission barriers. {copyright} {ital 1998} {ital The American Physical Society}

  3. Nonintuitive Diabatic Potential Energy Surfaces for Thioanisole.

    PubMed

    Li, Shaohong L; Xu, Xuefei; Hoyer, Chad E; Truhlar, Donald G

    2015-09-03

    Diabatization of potential energy surfaces is a technique that enables convenient molecular dynamics simulations of electronically nonadiabatic processes, but diabatization itself is nonunique and can be inconvenient; the best methods to achieve diabatization are still under study. Here, we present the diabatization of two electronic states of thioanisole in the S-CH3 bond stretching and C-C-S-C torsion two-dimensional nuclear coordinate space containing a conical intersection. We use two systematic methods: the (orbital-dependent) 4-fold way and the (orbital-free) Boys localization diabatization method. These very different methods yield strikingly similar diabatic potential energy surfaces that cross at geometries where the adiabatic surfaces are well separated and do not exhibit avoided crossings, and the contours of the diabatic gap and diabatic coupling are similar for the two methods. The validity of the diabatization is supported by comparing the nonadiabatic couplings calculated from the diabatic matrix elements to those calculated by direct differentiation of the adiabatic states.

  4. Flood risk assessment of potential casualties in a global scale

    NASA Astrophysics Data System (ADS)

    Diaz Loaiza, Andres; Englhardt, Johanna; Boekhorst, Ellen; Ward, Philip; Aerts, Jeroen

    2017-04-01

    Flood risk assessment of potential casualties in a global scale. M. Andres Diaz-Loaiza (1), Johanna Englhardt (1), Ellen de Boekhorst (1), Philip J. Ward (1) and Jeroen Aerts (1) (1) Institute for Environmental Studies, Vrije Universiteit Amsterdam, 1081 HV Amsterdam, The Netherlands. andres.diazloaiza@vu.nl Floods are one of the most dangerous natural disasters for humanity, affecting many people every year. Quantitative risk models on a global scale are nowadays available tools for institutions and actors in charge of risk management in order to plan possible mitigation measures in case of flood risk events. Many of these models have been focus on potential economic damage, population and GDP exposure, but the potential casualties assessment has been left aside. This is partially due to the complexity of the problem itself, in which several variables like the age of a pedestrian (drag/exposed to a flood event), or his weight and swimming experience can be decisive for the complete understanding of the problem. In the present work is presented the advances for the development of a methodology in order to include in the GLOFRIS model a new indicator in case of flood risk events. Preliminary analysis relating the GDP with the potential casualties shows that undeveloped countries have more susceptibility to loss of life in case of flood events. This because the GDP indicator evidences as well the protection measures available in a country.

  5. [Spatial Distribution and Global Potential Suitability Regions of Artemisia annua].

    PubMed

    Wang, Huan; Li, Hui; Zeng, Fan-lin; Xie, Cai-xiang

    2015-03-01

    To study the spatial distribution and potential climatic suitability regions of Artemisia annua around the world. The spatial distribution and climatic characteristics were researched by factor analysis based on Global Biodiversity Information Facility Database and World Climate Database. The global potential suitability regions of Artemisia annua were analyzed by ArcGIS. Artemisia annua distributed in three longitude zones, including 90. 55 °W - 77. 14 °W, 2. 03 °E - 11. 75 °E and 98. 27 °E - 111. 05 °E,which were respectively in North America, Europe and Asia. The latitude range was mainly 29. 15 °N - 51. 36 ° N. 80% of Artemisia annua were in the regions which elevation range was 22. 00 - 491. 00 m, annual precipitation was 492. 30 ~ 1 366. 70 mm, annual average temperature was from 8. 10 to 17. 27 °C. The potential suitability regions of Artemisia annua with 95% ~ 100% climate similarity were mainly in 30 °S and 30 °N regions, centered around the equator axis. Conclusion: Latitude is closely related to the distribution of Artemisia annua, the key affecting climatic factors are annual precipitation, the wettest season precipitation, the warmest season precipitation and the highest temperature in the warmest month, the average temperature of the warmest season, as well as the average temperature of the wettest season. The potential suitability regions of Artemnisia annua are in eastern North America, western Europe and eastern Asia.

  6. The polypill: a potential global solution to cardiovascular disease.

    PubMed

    Nguyen, Caroline; Cheng-Lai, Angela

    2013-01-01

    Despite groundbreaking advances in health care, cardiovascular disease (CVD) remains the leading cause of death and disability worldwide, making it one of the most pressing global health issues to face the modern world. In 2002, Wald and Law proposed the concept of the polypill as a potential solution to this global health epidemic. The polypill represents a powerhouse pill that would consist of a combination of several key medications commonly prescribed for CVD prevention, such as a statin, diuretic, beta blocker, or angiotensin converting enzyme inhibitor, in one pill. It was suggested that it could be a novel, tactical measure in the approach to CVD prevention in that it greatly simplifies the healthcare delivery system. Not only does it increase medication compliance for those currently receiving health care, but it also has the potential to access those in underserved healthcare sectors of the world, primarily low- and middle-income countries, which have been identified as areas of highest CVD risk. A major drawback of the polypill is that there are limited data demonstrating its safety and efficacy in the prevention of cardiovascular morbidity and mortality. Thus far, research shows that the polypill has promise but needs to be approached with a few considerations, such as desired target patient population and formulation. This article will examine the published and ongoing studies associated with the polypill, outline the advantages and disadvantages of using the polypill as a global CVD prevention strategy, and discuss the design and availability of the polypill in the United States.

  7. Stabilized quasi-Newton optimization of noisy potential energy surfaces

    NASA Astrophysics Data System (ADS)

    Schaefer, Bastian; Ghasemi, S. Alireza; Roy, Shantanu; Goedecker, Stefan; Goedecker Group Team

    Optimizations of atomic positions belong to the most frequently performed tasks in electronic structure calculations. Many simulations like global minimum searches or the identification of chemical reaction pathways can require the computation of hundreds or thousands of minimizations or saddle points. To automatize these tasks, optimization algorithms must not only be efficient but also very reliable. Unfortunately, computational noise in forces and energies is inherent to electronic structure codes. This computational noise poses a severe problem to the stability of efficient optimization methods like the limited-memory Broyden-Fletcher-Goldfarb-Shanno algorithm. In this talk a recently published technique that allows to obtain significant curvature information of noisy potential energy surfaces is presented. This technique was used to construct both, a stabilized quasi-Newton minimization method and a stabilized quasi-Newton saddle finding approach. With the help of benchmarks both the minimizer and the saddle finding approach were demonstrated to be superior to comparable existing methods.

  8. Stabilized quasi-Newton optimization of noisy potential energy surfaces

    NASA Astrophysics Data System (ADS)

    Schaefer, Bastian; Alireza Ghasemi, S.; Roy, Shantanu; Goedecker, Stefan

    2015-01-01

    Optimizations of atomic positions belong to the most commonly performed tasks in electronic structure calculations. Many simulations like global minimum searches or characterizations of chemical reactions require performing hundreds or thousands of minimizations or saddle computations. To automatize these tasks, optimization algorithms must not only be efficient but also very reliable. Unfortunately, computational noise in forces and energies is inherent to electronic structure codes. This computational noise poses a severe problem to the stability of efficient optimization methods like the limited-memory Broyden-Fletcher-Goldfarb-Shanno algorithm. We here present a technique that allows obtaining significant curvature information of noisy potential energy surfaces. We use this technique to construct both, a stabilized quasi-Newton minimization method and a stabilized quasi-Newton saddle finding approach. We demonstrate with the help of benchmarks that both the minimizer and the saddle finding approach are superior to comparable existing methods.

  9. Stabilized quasi-Newton optimization of noisy potential energy surfaces

    SciTech Connect

    Schaefer, Bastian; Goedecker, Stefan; Alireza Ghasemi, S.; Roy, Shantanu

    2015-01-21

    Optimizations of atomic positions belong to the most commonly performed tasks in electronic structure calculations. Many simulations like global minimum searches or characterizations of chemical reactions require performing hundreds or thousands of minimizations or saddle computations. To automatize these tasks, optimization algorithms must not only be efficient but also very reliable. Unfortunately, computational noise in forces and energies is inherent to electronic structure codes. This computational noise poses a severe problem to the stability of efficient optimization methods like the limited-memory Broyden–Fletcher–Goldfarb–Shanno algorithm. We here present a technique that allows obtaining significant curvature information of noisy potential energy surfaces. We use this technique to construct both, a stabilized quasi-Newton minimization method and a stabilized quasi-Newton saddle finding approach. We demonstrate with the help of benchmarks that both the minimizer and the saddle finding approach are superior to comparable existing methods.

  10. Nuclear energy position in industrial and economics global

    NASA Astrophysics Data System (ADS)

    Aji, Indarta Kuncoro; Permana, Sidik

    2012-06-01

    3E (Energy, Economics and Education) are three concepts of community development, and 3E concepts are interlinked between each other. 3E concept is divided into three levels of regions, remote area or villages, small towns and metropolitan cities, and there are different problems of each region. This paper analyzes the relations between energy, economics and education in the metropolitan and industrial city. Especially the influence of nuclear energy concerning at cost production of the industrial and the contribution of education and research for nuclear energy innovation. This relation can be explained using "S-curve". The results of this study is the comparison between the product involves the use of nuclear energy or not in the production process are explained using "S-curve" and its effect on the global economics.

  11. Current status and future potential of energy derived from Chinese agricultural land: a review.

    PubMed

    Zhai, Ningning; Mao, Chunlan; Feng, Yongzhong; Zhang, Tong; Xing, Zhenjie; Wang, Yanhong; Zou, Shuzhen; Yin, Dongxue; Han, Xinhui; Ren, Guangxin; Yang, Gaihe

    2015-01-01

    Energy crisis is receiving attention with regard to the global economy and environmental sustainable development. Developing new energy resources to optimize the energy supply structure has become an important measure to prevent energy shortage as well as achieving energy conservation and emission reduction in China. This study proposed the concept of energy agriculture and constructed an energy agricultural technical support system based on the analysis of energy supply and demand and China's foreign dependence on energy resources, combined with the function of agriculture in the energy field. Manufacturing technology equipment and agricultural and forestry energy, including crop or forestry plants and animal feces, were used in the system. The current status and future potential of China's marginal land resources, energy crop germplasm resources, and agricultural and forestry waste energy-oriented resources were analyzed. Developing the function of traditional agriculture in food production may promote China's social, economic, and environmental sustainable development and achieve energy saving and emission reduction.

  12. Current Status and Future Potential of Energy Derived from Chinese Agricultural Land: A Review

    PubMed Central

    Mao, Chunlan; Feng, Yongzhong; Zhang, Tong; Xing, Zhenjie; Wang, Yanhong; Zou, Shuzhen; Yin, Dongxue; Han, Xinhui; Ren, Guangxin; Yang, Gaihe

    2015-01-01

    Energy crisis is receiving attention with regard to the global economy and environmental sustainable development. Developing new energy resources to optimize the energy supply structure has become an important measure to prevent energy shortage as well as achieving energy conservation and emission reduction in China. This study proposed the concept of energy agriculture and constructed an energy agricultural technical support system based on the analysis of energy supply and demand and China's foreign dependence on energy resources, combined with the function of agriculture in the energy field. Manufacturing technology equipment and agricultural and forestry energy, including crop or forestry plants and animal feces, were used in the system. The current status and future potential of China's marginal land resources, energy crop germplasm resources, and agricultural and forestry waste energy-oriented resources were analyzed. Developing the function of traditional agriculture in food production may promote China's social, economic, and environmental sustainable development and achieve energy saving and emission reduction. PMID:25874229

  13. Global Tobacco Surveillance System (GTSS): purpose, production, and potential.

    PubMed

    2005-01-01

    The World Health Organization (WHO), Centers for Disease Control and Prevention (CDC), and Canadian Public Health Association (CPHA) developed the Global Tobacco Surveillance System (GTSS) to assist all 192 WHO Member States in collecting data on youth and adult tobacco use. The flexible GTSS system includes common data items but allows countries to include important unique information at their discretion. It uses a common survey methodology, similar field procedures for data collection, and similar data management and processing techniques. The GTSS includes collection of data through three surveys: the Global Youth Tobacco Survey (GYTS) for youth, and the Global School Personnel Survey (GSPS) and the Global Health Professional Survey (GHPS) for adults. GTSS data potentially can be applied in four ways. First, countries and research partners can disseminate data through publications, presentations, and an active GTSS web site. Second, countries can use GTSS data to inform politicians about the tobacco problem in their country, leading to new policy decisions to prevent and control tobacco use. Third, GTSS can provide countries with valuable feedback to evaluate and improve Country National Action Plans or develop new plans. Fourth, in response to the WHO FCTC call for countries to use consistent methods and procedures in their surveillance efforts, GTSS offers such consistency in sampling procedures, core questionnaire items, training infield procedures, and analysis of data across all survey sites. The GTSS represents the most comprehensive tobacco surveillance system ever developed and implemented. As an example, this paper describes development of the GYTS and discusses potential uses of the data. Sample data were drawn from 38 sites in 24 countries in the African Region, 82 sites in 35 countries in the Americas Region, 20 sites in 17 countries and the Gaza Strip/West Bank region in the Eastern Mediterranean Region, 25 sites in 22 countries in the European

  14. Global exploration of the energy landscape of solids on the ab initio level.

    PubMed

    Doll, K; Schön, J C; Jansen, M

    2007-12-14

    Predicting which crystalline modifications can be present in a chemical system requires the global exploration of its energy landscape. Due to the large computational effort involved, in the past this search for sufficiently stable minima has been performed employing a variety of empirical potentials and cost functions followed by a local optimization on the ab initio level. However, this entails the risk of overlooking important modifications that are not modeled accurately using empirical potentials. In order to overcome this critical limitation, we develop an approach to employ ab initio energy functions during the global optimization phase of the structure prediction. As an example, we perform a global exploration of the landscape of LiF on the ab initio level and show that the relevant crystalline modifications are found during the search.

  15. Bohm's quantum potential as an internal energy

    NASA Astrophysics Data System (ADS)

    Dennis, Glen; de Gosson, Maurice A.; Hiley, Basil J.

    2015-06-01

    We pursue our discussion of Fermi's surface initiated by Dennis, de Gosson and Hiley and show that Bohm's quantum potential can be viewed as an internal energy of a quantum system, giving further insight into its role in stationary states. This implies that the 'particle' referred to in Bohm's theory is not a classical point-like object but rather has an extended structure in phase space which can be linked to the notion of a symplectic capacity, a topological feature of the underlying symplectic geometry. This structure provides us with a new, physically motivated derivation of Schrödinger's equation provided we interpret Gleason's theorem as a derivation of the Born rule from fundamental assumptions about quantum probabilities.

  16. Potential energy surfaces and reaction dynamics of polyatomic molecules

    SciTech Connect

    Chang, Yan-Tyng

    1991-11-01

    A simple empirical valence bond (EVB) model approach is suggested for constructing global potential energy surfaces for reactions of polyatomic molecular systems. This approach produces smooth and continuous potential surfaces which can be directly utilized in a dynamical study. Two types of reactions are of special interest, the unimolecular dissociation and the unimolecular isomerization. For the first type, the molecular dissociation dynamics of formaldehyde on the ground electronic surface is investigated through classical trajectory calculations on EVB surfaces. The product state distributions and vector correlations obtained from this study suggest very similar behaviors seen in the experiments. The intramolecular hydrogen atom transfer in the formic acid dimer is an example of the isomerization reaction. High level ab initio quantum chemistry calculations are performed to obtain optimized equilibrium and transition state dimer geometries and also the harmonic frequencies.

  17. Energy Input Flux in the Global Quiet-Sun Corona

    NASA Astrophysics Data System (ADS)

    Mac Cormack, Cecilia; Vásquez, Alberto M.; López Fuentes, Marcelo; Nuevo, Federico A.; Landi, Enrico; Frazin, Richard A.

    2017-07-01

    We present first results of a novel technique that provides, for the first time, constraints on the energy input flux at the coronal base (r ˜ 1.025 R ⊙) of the quiet Sun at a global scale. By combining differential emission measure tomography of EUV images, with global models of the coronal magnetic field, we estimate the energy input flux at the coronal base that is required to maintain thermodynamically stable structures. The technique is described in detail and first applied to data provided by the Extreme Ultraviolet Imager instrument, on board the Solar TErrestrial RElations Observatory mission, and the Atmospheric Imaging Assembly instrument, on board the Solar Dynamics Observatory mission, for two solar rotations with different levels of activity. Our analysis indicates that the typical energy input flux at the coronal base of magnetic loops in the quiet Sun is in the range ˜0.5-2.0 × 105 (erg s-1 cm-2), depending on the structure size and level of activity. A large fraction of this energy input, or even its totality, could be accounted for by Alfvén waves, as shown by recent independent observational estimates derived from determinations of the non-thermal broadening of spectral lines in the coronal base of quiet-Sun regions. This new tomography product will be useful for the validation of coronal heating models in magnetohydrodinamic simulations of the global corona.

  18. The global potential of local peri-urban food production

    NASA Astrophysics Data System (ADS)

    Kriewald, Steffen; Garcia Cantu Ros, Anselmo; Sterzel, Till; Kropp, Jürgen P.

    2013-04-01

    One big challenge for the rest of the 21st century will be the massive urbanisation. It is expected that more than 7 out of 10 persons will live in a city by the year 2050. Crucial developments towards a sustainable future will therefore take place in cities. One important approach for a sustainable city development is to re-localize food production and to close urban nutrient cycles through better waste management. The re-location of food production avoids CO2 emissions from transportation of food to cities and can also generate income for inhabitants. Cities are by definition locations where fertility accumulates. As cities are often built along rivers, their soils are often fertile. Furthermore, labour force and the possibility of producing fertilizer from human fecal matter within the city promises sustainable nutrients cycles. Although urban and peri-urban agriculture can be found in many cities worldwide and already have a substantial contribution to food supply, it has not jet been comprehensibly structured by research. We combine several worldwide data sets to determine the supply of cities with regional food production, where regional is defined as a production that occurs very close to the consumption within the peri-urban area. Therefore, urban areas are not defined by administrative boundaries but by connected built-up urban areas, and peri-urban area by the surrounding area with the same size multiplied with a scaling parameter. Both together accumulate to an urban-bio-region (UBR). With regard to national food consumption, a linear program achieves the best possible yield on agricultural areas and allows the computation of the fraction of population, which can be nourished. Additionally, several climate scenarios and different dietary patterns were considered. To close the gap between single case studies and to provide a quantitative overview of the global potential of peri-urban food production we used high resolution land-use data Global Land Cover

  19. The Wind Energy Potential of Kurdistan, Iran.

    PubMed

    Arefi, Farzad; Moshtagh, Jamal; Moradi, Mohammad

    2014-01-01

    In the current work by using statistical methods and available software, the wind energy assessment of prone regions for installation of wind turbines in, Qorveh, has been investigated. Information was obtained from weather stations of Baneh, Bijar, Zarina, Saqez, Sanandaj, Qorveh, and Marivan. The monthly average and maximum of wind speed were investigated between the years 2000-2010 and the related curves were drawn. The Golobad curve (direction and percentage of dominant wind and calm wind as monthly rate) between the years 1997-2000 was analyzed and drawn with plot software. The ten-minute speed (at 10, 30, and 60 m height) and direction (at 37.5 and 10 m height) wind data were collected from weather stations of Iranian new energy organization. The wind speed distribution during one year was evaluated by using Weibull probability density function (two-parametrical), and the Weibull curve histograms were drawn by MATLAB software. According to the average wind speed of stations and technical specifications of the types of turbines, the suitable wind turbine for the station was selected. Finally, the Divandareh and Qorveh sites with favorable potential were considered for installation of wind turbines and construction of wind farms.

  20. Thermophotovoltaic energy conversion: Technology and market potential

    SciTech Connect

    Ostrowski, L.J.; Pernisz, U.C.; Fraas, L.M.

    1996-02-01

    This report contains material displayed on poster panels during the Conference. The purpose of the contribution was to present a summary of the business overview of thermophotovoltaic generation of electricity and its market potential. The market analysis has shown that the TPV market, while currently still in an early nucleation phase, is evolving into a range of small niche markets out of which larger-size opportunities can emerge. Early commercial applications on yachts and recreational vehicles which require a quiet and emission-free compact electrical generator fit the current TPV technology and economics. Follow-on residential applications are attractive since they can combine generation of electricity with space and hot water heating in a co-generation system. Development of future markets in transportation, both private and communal or industrial, will be driven by legislation requiring emission-free vehicles, and by a reduction in TPV systems cost. As a result of {open_quote}{open_quote}moving down the learning curve,{close_quote}{close_quote} growing power and consumer markets are predicted to come into reach of TPV systems, a development favored by high overall energy conversion efficiency due to high radiation energy density and to high electric conversion efficiency available with photovoltaic cells. {copyright} {ital 1996 American Institute of Physics.}

  1. Computed potential energy surfaces for chemical reactions

    NASA Technical Reports Server (NTRS)

    Walch, Stephen P.

    1988-01-01

    The minimum energy path for the addition of a hydrogen atom to N2 is characterized in CASSCF/CCI calculations using the (4s3p2d1f/3s2p1d) basis set, with additional single point calculations at the stationary points of the potential energy surface using the (5s4p3d2f/4s3p2d) basis set. These calculations represent the most extensive set of ab initio calculations completed to date, yielding a zero point corrected barrier for HN2 dissociation of approx. 8.5 kcal mol/1. The lifetime of the HN2 species is estimated from the calculated geometries and energetics using both conventional Transition State Theory and a method which utilizes an Eckart barrier to compute one dimensional quantum mechanical tunneling effects. It is concluded that the lifetime of the HN2 species is very short, greatly limiting its role in both termolecular recombination reactions and combustion processes.

  2. Thermophotovoltaic energy conversion: Technology and market potential

    NASA Astrophysics Data System (ADS)

    Ostrowski, Leon J.; Pernisz, Udo C.; Fraas, Lewis M.

    1996-02-01

    This report contains material displayed on poster panels during the Conference. The purpose of the contribution was to present a summary of the business overview of thermophotovoltaic generation of electricity and its market potential. The market analysis has shown that the TPV market, while currently still in an early nucleation phase, is evolving into a range of small niche markets out of which larger-size opportunities can emerge. Early commercial applications on yachts and recreational vehicles which require a quiet and emission-free compact electrical generator fit the current TPV technology and economics. Follow-on residential applications are attractive since they can combine generation of electricity with space and hot water heating in a co-generation system. Development of future markets in transportation, both private and communal or industrial, will be driven by legislation requiring emission-free vehicles, and by a reduction in TPV systems cost. As a result of ``moving down the learning curve,'' growing power and consumer markets are predicted to come into reach of TPV systems, a development favored by high overall energy conversion efficiency due to high radiation energy density and to high electric conversion efficiency available with photovoltaic cells.

  3. The Wind Energy Potential of Kurdistan, Iran

    PubMed Central

    Arefi, Farzad; Moshtagh, Jamal; Moradi, Mohammad

    2014-01-01

    In the current work by using statistical methods and available software, the wind energy assessment of prone regions for installation of wind turbines in, Qorveh, has been investigated. Information was obtained from weather stations of Baneh, Bijar, Zarina, Saqez, Sanandaj, Qorveh, and Marivan. The monthly average and maximum of wind speed were investigated between the years 2000–2010 and the related curves were drawn. The Golobad curve (direction and percentage of dominant wind and calm wind as monthly rate) between the years 1997–2000 was analyzed and drawn with plot software. The ten-minute speed (at 10, 30, and 60 m height) and direction (at 37.5 and 10 m height) wind data were collected from weather stations of Iranian new energy organization. The wind speed distribution during one year was evaluated by using Weibull probability density function (two-parametrical), and the Weibull curve histograms were drawn by MATLAB software. According to the average wind speed of stations and technical specifications of the types of turbines, the suitable wind turbine for the station was selected. Finally, the Divandareh and Qorveh sites with favorable potential were considered for installation of wind turbines and construction of wind farms. PMID:27355042

  4. Energy resource potential of natural gas hydrates

    USGS Publications Warehouse

    Collett, T.S.

    2002-01-01

    The discovery of large gas hydrate accumulations in terrestrial permafrost regions of the Arctic and beneath the sea along the outer continental margins of the world's oceans has heightened interest in gas hydrates as a possible energy resource. However, significant to potentially insurmountable technical issues must be resolved before gas hydrates can be considered a viable option for affordable supplies of natural gas. The combined information from Arctic gas hydrate studies shows that, in permafrost regions, gas hydrates may exist at subsurface depths ranging from about 130 to 2000 m. The presence of gas hydrates in offshore continental margins has been inferred mainly from anomalous seismic reflectors, known as bottom-simulating reflectors, that have been mapped at depths below the sea floor ranging from about 100 to 1100 m. Current estimates of the amount of gas in the world's marine and permafrost gas hydrate accumulations are in rough accord at about 20,000 trillion m3. Disagreements over fundamental issues such as the volume of gas stored within delineated gas hydrate accumulations and the concentration of gas hydrates within hydrate-bearing strata have demonstrated that we know little about gas hydrates. Recently, however, several countries, including Japan, India, and the United States, have launched ambitious national projects to further examine the resource potential of gas hydrates. These projects may help answer key questions dealing with the properties of gas hydrate reservoirs, the design of production systems, and, most important, the costs and economics of gas hydrate production.

  5. The potential impact of global environmental change on population health.

    PubMed

    Tong, S

    2000-10-01

    Due to rapid industrial changes and increased pressure of people on fragile ecosystems, large-scale environmental perturbations have been occurring on Earth. Major current environmental problems that can be expected to have a substantial effect on human health include human-induced climate change and stratosphere ozone depletion, because they threaten the ecological support systems on which human life depends. The most serious potential consequence of global environmental change is the erosion of Earth's life-support systems. The public health assessments of the present and future anthropogenic damage to the biosphere have important implications for human health and wellbeing. Medical practitioners have an important role to play in this field.

  6. Studies of global energy confinement in TFTR supershots

    SciTech Connect

    Strachan, J.D.

    1993-08-01

    The global energy confinement time, {tau}{sub E}, from TFTR supershot plasmas has been correlated with the hydrogen recycling and the pressure anisotropy. An expression for the global confinement was obtained that describes its value at the time of peak neutron emission for all TFTR supershots obtained in the 1990 campaign, and simultaneously describes the time evolution of {tau}{sub E} for an extensive subset of the 1990 data. The obtained expression is probably not unique and it can be written with different variables. An analysis of the energy balance for many of these supershots indicates that the primary effect of larger {tau}{sub E} is that the central particle diffusivity is lower.

  7. Energy conversion of biomass in coping with global warming

    SciTech Connect

    Yokoyama, Shin-ya; Ogi, Tomoko; Minowa, Tomoaki

    1993-12-31

    The main purpose of the present paper is to propose energy conversion technologies of biomass in coping with global warming. Among thermochemical conversion, liquid fuel production by high pressure process is mainly introduced. Biomass is a term used to describe materials of biological origin, either purpose-grown or arising as by-products, residues or wastes from forestry, agriculture and food processing. Such biomass is a renewable energy sources dependent on solar energy. Through photosynthesis, plants converts carbon dioxide into organic materials used in their growth. Energy can be recovered from the plant materials by several processes, the simplest way is burning in air. As far as biomass is used in this way, there is no atmospheric accumulation of carbon dioxide making no effect on the Greenhouse Effect, provided that the cycle of regrowth and burning is sustained.

  8. Foraging on the potential energy surface: A swarm intelligence-based optimizer for molecular geometry

    NASA Astrophysics Data System (ADS)

    Wehmeyer, Christoph; Falk von Rudorff, Guido; Wolf, Sebastian; Kabbe, Gabriel; Schärf, Daniel; Kühne, Thomas D.; Sebastiani, Daniel

    2012-11-01

    We present a stochastic, swarm intelligence-based optimization algorithm for the prediction of global minima on potential energy surfaces of molecular cluster structures. Our optimization approach is a modification of the artificial bee colony (ABC) algorithm which is inspired by the foraging behavior of honey bees. We apply our modified ABC algorithm to the problem of global geometry optimization of molecular cluster structures and show its performance for clusters with 2-57 particles and different interatomic interaction potentials.

  9. Transportation Energy Use and Conservation Potential

    ERIC Educational Resources Information Center

    Hirst, Eric

    1973-01-01

    Analyzes transportation energy consumption and energy intensiveness for inter-city freight and passenger traffic and urban passenger traffic with the definition of energy intensiveness as Btu per ton-mile or per passenger-mile. Indicates that public education is one of three ways to achieve the goals of energy conservation. (CC)

  10. Transportation Energy Use and Conservation Potential

    ERIC Educational Resources Information Center

    Hirst, Eric

    1973-01-01

    Analyzes transportation energy consumption and energy intensiveness for inter-city freight and passenger traffic and urban passenger traffic with the definition of energy intensiveness as Btu per ton-mile or per passenger-mile. Indicates that public education is one of three ways to achieve the goals of energy conservation. (CC)

  11. Global warming and least-cost energy planning

    SciTech Connect

    Cavanagh, R.C. )

    1989-01-01

    Energy consumption is implicated in the growing emissions of all the major greenhouse gases'': carbon dioxide, methane, chlorofluorocarbons, nitrous oxide, and tropospheric ozone. All trap heat emitted from the earth's surface, a phenomenon that could accelerate to destroy the same planetary ecosystems that it has nurtured in the past. Strategies for reducing carbon dioxide emissions are this article's principal concern; increases in such emissions account for about half the projected atmospheric warming, with the increases themselves principally attributable to fossil fuel combustion. The United States is the world's largest emissions source, and while it cannot succeed alone, neither can it abdicate leadership responsibilities without all but ensuring failure. This article contends that US energy policy has been working to increase, rather than forestall, the danger of global warming. In particular, recent trends toward deregulation of the energy sector are grossly insufficient as solutions to the problem, although not necessarily inconsistent with them. The article outlines a way to organize urgent US and international energy policy reforms, drawing on the experience of certain state utility regulators with an approach called least-cost energy planning.'' Least-cost planning recognizes improvements in the efficiency of energy use as a major source of additional energy supplies, and seeks fair competition for energy investment dollars between conservation measures and production facilities.

  12. Global Energetics of Solar Flares. Part III; Nonthermal Energies

    NASA Technical Reports Server (NTRS)

    Aschwanden, Markus J.; Holman, Gordon; O'Flannagain, Aidan; Caspi, Amir; McTiernan, James M.; Kontar, Eduard P.

    2016-01-01

    This study entails the third part of a global flare energetics project, in which Ramaty High-Energy Solar Spectroscopic Imager (RHESSI) data of 191 M and X-class flare events from the first 3.5 years of the Solar Dynamics Observatory mission are analyzed. We fit a thermal and a nonthermal component to RHESSI spectra, yielding the temperature of the differential emission measure (DEM) tail, the nonthermal power-law slope and flux, and the thermal nonthermal cross-over energy eco. From these parameters, we calculate the total nonthermal energy E(sub nt) in electrons with two different methods: (1) using the observed cross-over energy e(sub co) as low-energy cutoff, and (2) using the low-energy cut off e(sub wt) predicted by the warm thick-target bremsstrahlung model of Kontar et al. Based on a mean temperature of T(sub e) = 8.6 MK in active regions, we find low-energy cutoff energies of e(sub wt) = 6.2 +/-1.6 keV for the warm-target model, which is significantly lower than the cross-over energies e(sub co) = 21 +/- 6 keV. Comparing with the statistics of magnetically dissipated energies E(sub mag) and thermal energies E(sub th) from the two previous studies, we find the following mean (logarithmic) energy ratios with the warm-target model: E(sub nt) = 0.41E(sub mag), E(sub th) = 0.08 E(sub mag), and E(sub th) = 0.15 E(sub nt). The total dissipated magnetic energy exceeds the thermal energy in 95% and the nonthermal energy in 71% of the flare events, which confirms that magnetic reconnection processes are sufficient to explain flare energies. The nonthermal energy exceeds the thermal energy in 85% of the events, which largely confirms the warm thick-target model.

  13. Global Energetics of Solar Flares. Part III; Nonthermal Energies

    NASA Technical Reports Server (NTRS)

    Aschwanden, Markus J.; Holman, Gordon; O'Flannagain, Aidan; Caspi, Amir; McTiernan, James M.; Kontar, Eduard P.

    2016-01-01

    This study entails the third part of a global flare energetics project, in which Ramaty High-Energy Solar Spectroscopic Imager (RHESSI) data of 191 M and X-class flare events from the first 3.5 years of the Solar Dynamics Observatory mission are analyzed. We fit a thermal and a nonthermal component to RHESSI spectra, yielding the temperature of the differential emission measure (DEM) tail, the nonthermal power-law slope and flux, and the thermal nonthermal cross-over energy eco. From these parameters, we calculate the total nonthermal energy E(sub nt) in electrons with two different methods: (1) using the observed cross-over energy e(sub co) as low-energy cutoff, and (2) using the low-energy cut off e(sub wt) predicted by the warm thick-target bremsstrahlung model of Kontar et al. Based on a mean temperature of T(sub e) = 8.6 MK in active regions, we find low-energy cutoff energies of e(sub wt) = 6.2 +/-1.6 keV for the warm-target model, which is significantly lower than the cross-over energies e(sub co) = 21 +/- 6 keV. Comparing with the statistics of magnetically dissipated energies E(sub mag) and thermal energies E(sub th) from the two previous studies, we find the following mean (logarithmic) energy ratios with the warm-target model: E(sub nt) = 0.41E(sub mag), E(sub th) = 0.08 E(sub mag), and E(sub th) = 0.15 E(sub nt). The total dissipated magnetic energy exceeds the thermal energy in 95% and the nonthermal energy in 71% of the flare events, which confirms that magnetic reconnection processes are sufficient to explain flare energies. The nonthermal energy exceeds the thermal energy in 85% of the events, which largely confirms the warm thick-target model.

  14. Estimates of global dew collection potential on artificial surfaces

    NASA Astrophysics Data System (ADS)

    Vuollekoski, H.; Vogt, M.; Sinclair, V. A.; Duplissy, J.; Järvinen, H.; Kyrö, E.-M.; Makkonen, R.; Petäjä, T.; Prisle, N. L.; Räisänen, P.; Sipilä, M.; Ylhäisi, J.; Kulmala, M.

    2015-01-01

    The global potential for collecting usable water from dew on an artificial collector sheet was investigated by utilizing 34 years of meteorological reanalysis data as input to a dew formation model. Continental dew formation was found to be frequent and common, but daily yields were mostly below 0.1 mm. Nevertheless, some water-stressed areas such as parts of the coastal regions of northern Africa and the Arabian Peninsula show potential for large-scale dew harvesting, as the yearly yield may reach up to 100 L m-2 for a commonly used polyethylene foil. Statistically significant trends were found in the data, indicating overall changes in dew yields of between ±10% over the investigated time period.

  15. Global potential of phosphorus recovery from human urine and feces.

    PubMed

    Mihelcic, James R; Fry, Lauren M; Shaw, Ryan

    2011-08-01

    This study geospatially quantifies the mass of an essential fertilizer element, phosphorus, available from human urine and feces, globally, regionally, and by specific country. The analysis is performed over two population scenarios (2009 and 2050). This important material flow is related to the presence of improved sanitation facilities and also considers the global trend of urbanization. Results show that in 2009 the phosphorus available from urine is approximately 1.68 million metric tons (with similar mass available from feces). If collected, the phosphorus available from urine and feces could account for 22% of the total global phosphorus demand. In 2050 the available phosphorus from urine that is associated with population increases only will increase to 2.16 million metric tons (with similar mass available from feces). The available phosphorus from urine and feces produced in urban settings is currently approximately 0.88 million metric tons and will increase with population growth to over 1.5 million metric tons by 2050. Results point to the large potential source of human-derived phosphorus in developing regions like Africa and Asia that have a large population currently unserved by improved sanitation facilities. These regions have great potential to implement urine diversion and reuse and composting or recovery of biosolids, because innovative technologies can be integrated with improvements in sanitation coverage. In contrast, other regions with extensive sanitation coverage like Europe and North America need to determine how to retrofit existing sanitation technology combined that is combined with human behavioral changes to recover phosphorus and other valuable nutrients. Copyright © 2011 Elsevier Ltd. All rights reserved.

  16. Potential impact of global climate change on malaria risk

    SciTech Connect

    Martens, W.J.M.; Rotmans, J. |; Niessen, L.W.; Jetten, T.H.; McMichael, A.J.

    1995-05-01

    The biological activity and geographic distribution of the malarial parasite and its vector are sensitive to climatic influences, especially temperature and precipitation. We have incorporated General Circulation Model-based scenarios of anthropogenic global climate change in an integrated linked-system model for predicting changes in malaria epidemic potential in the next century. The concept of the disability-adjusted life years is included to arrive at a single measure of the effect of anthropogenic climate change on the health impact of malaria. Assessment of the potential impact of global climate change on the incidence of malaria suggests a widespread increase of risk due to expansion of the areas suitable for malaria transmission. This predicted increase is most pronounced at the borders of endemic malaria areas and at higher altitudes within malarial areas. The incidence of infection is sensitive to climate changes in areas of Southeast Asia, South America, and parts of Africa where the disease is less endemic; in these regions the numbers of years of healthy life lost may increase significantly. However, the simulated changes in malaria risk must be interpreted on the basis of local environmental conditions, the effects of socioeconomic developments, and malaria control programs or capabilities. 33 refs., 5 figs., 1 tab.

  17. CO dimer: new potential energy surface and rovibrational calculations.

    PubMed

    Dawes, Richard; Wang, Xiao-Gang; Carrington, Tucker

    2013-08-15

    The spectrum of CO dimer was investigated by solving the rovibrational Schrödinger equation on a new potential energy surface constructed from coupled-cluster ab initio points. The Schrödinger equation was solved with a Lanczos algorithm. Several 4D (rigid monomer) global ab initio potential energy surfaces (PESs) were made using a previously reported interpolating moving least-squares (IMLS) fitting procedure specialized to describe the interaction of two linear fragments. The potential has two nonpolar minima giving rise to a complicated set of energy level stacks, which are very sensitive to the shapes and relative depths of the two wells. Although the CO dimer has defied previous attempts at an accurate purely ab initio description our best surface yields results in good agreement with experiment. Root-mean-square (rms) fitting errors of less than 0.1 cm(-1) were obtained for each of the fits using 2226 ab initio data at different levels. This allowed direct assessment of the quality of various levels of ab initio theory for prediction of spectra. Our tests indicate that standard CCSD(T) is slow to converge the interaction energy even when sextuple zeta bases as large as ACV6Z are used. The explicitly correlated CCSD(T)-F12b method was found to recover significantly more correlation energy (from singles and doubles) at the CBS limit. Correlation of the core-electrons was found to be important for this system. The best PES was obtained by extrapolation of calculations at the CCSD(T)(AE)-F12b/CVnZ-F12 (n = 3,4) levels. The calculated energy levels were compared to 105 J ≤ 10 levels from experiment. The rms error for 68 levels with J ≤ 6 is only 0.29 cm(-1). The calculated energy levels were assigned stack labels using several tools. New stacks were found. One of them, stack y1, has an energy lower than many previously known stacks and may be observable.

  18. Theoretical studies of potential energy surfaces and computational methods

    SciTech Connect

    Shepard, R.

    1993-12-01

    This project involves the development, implementation, and application of theoretical methods for the calculation and characterization of potential energy surfaces involving molecular species that occur in hydrocarbon combustion. These potential energy surfaces require an accurate and balanced treatment of reactants, intermediates, and products. This difficult challenge is met with general multiconfiguration self-consistent-field (MCSCF) and multireference single- and double-excitation configuration interaction (MRSDCI) methods. In contrast to the more common single-reference electronic structure methods, this approach is capable of describing accurately molecular systems that are highly distorted away from their equilibrium geometries, including reactant, fragment, and transition-state geometries, and of describing regions of the potential surface that are associated with electronic wave functions of widely varying nature. The MCSCF reference wave functions are designed to be sufficiently flexible to describe qualitatively the changes in the electronic structure over the broad range of geometries of interest. The necessary mixing of ionic, covalent, and Rydberg contributions, along with the appropriate treatment of the different electron-spin components (e.g. closed shell, high-spin open-shell, low-spin open shell, radical, diradical, etc.) of the wave functions, are treated correctly at this level. Further treatment of electron correlation effects is included using large scale multireference CI wave functions, particularly including the single and double excitations relative to the MCSCF reference space. This leads to the most flexible and accurate large-scale MRSDCI wave functions that have been used to date in global PES studies.

  19. An ab initio method for locating potential energy minima

    SciTech Connect

    Bock, Nicolas; Peery, Travis; Venneri, Giulia; Chisolm, Eric; Wallace, Duane; Lizarraga, Raquel; Holmstrom, Erik

    2009-01-01

    We study the potential energy landscape underlying the motion of monatomic liquids by quenching from random initial configurations (stochastic configurations) to the nearest local minimum of the potential energy. We show that this procedure reveals the underlying potential energy surface directly. This is in contrast to the common technique of quenching from a molecular dynamics trajectory which does not allow a direct view of the underlying potential energy surface, but needs to be corrected for thermodynamic weighting factors.

  20. Global Nuclear Energy Partnership Programmatic Environmental Impact Statement

    SciTech Connect

    R.A. Wigeland

    2008-10-01

    Abstract: The proposed Global Nuclear Energy Partnership (GNEP) Program, which is part of the President’s Advanced Energy Initiative, is intended to support a safe, secure, and sustainable expansion of nuclear energy, both domestically and internationally. Domestically, the GNEP Program would promote technologies that support economic, sustained production of nuclear-generated electricity, while reducing the impacts associated with spent nuclear fuel disposal and reducing proliferation risks. The Department of Energy (DOE) proposed action envisions changing the United States nuclear energy fuel cycle from an open (or once-through) fuel cycle—in which nuclear fuel is used in a power plant one time and the resulting spent nuclear fuel is stored for eventual disposal in a geologic repository—to a closed fuel cycle in which spent nuclear fuel would be recycled to recover energy-bearing components for use in new nuclear fuel. At this time, DOE has no specific proposed actions for the international component of the GNEP Program. Rather, the United States, through the GNEP Program, is considering various initiatives to work cooperatively with other nations. Such initiatives include the development of grid-appropriate reactors and the development of reliable fuel services (to provide an assured supply of fresh nuclear fuel and assist with the management of the used fuel) for nations who agree to employ nuclear energy only for peaceful purposes, such as electricity generation.

  1. Global hydropower potential during recent droughts and under changing climate

    NASA Astrophysics Data System (ADS)

    Van Vliet, Michelle T. H.; Sheffield, Justin; Wiberg, David; Wood, Eric F.

    2015-04-01

    There is a strong dependency of world's electricity sector on available water resources for hydropower generation. Recent droughts showed the vulnerability of the electricity sector to surface water constraints with reduced potentials for hydropower generation in different regions worldwide. Using a global modelling framework consisting of the VIC hydrological model and a hydropower model, we assess the impacts of recent droughts and future climate change on hydropower generation potentials worldwide. Our hydrological-electricity modelling framework was optimized and evaluated for 1981-2010, showing a realistic representation of observed streamflow and hydropower generation. We assessed the impacts of recent droughts and future climate change for more than 25,000 hydropower plants worldwide. Our results show that hydropower production potentials were significantly reduced during severe recent streamflow droughts (including e.g. summer of 2003 in Europe and 2007 in the United States). Model simulations with bias-corrected CMIP5 general circulation model output indicate that in several regions considerable reductions in hydropower production potentials are projected due to declines in streamflow during parts of the year. Considering these impacts and the long design life of power plant infrastructure, adaptation options should be included in today's planning and strategies to meet the growing electricity demand in the 21st century.

  2. Interannual variability of the global net radiation balance and its consequence on global energy transport

    NASA Technical Reports Server (NTRS)

    Smith, Eric A.; Sohn, B. J.

    1990-01-01

    Global cloudiness and radiation budget data from Nimbus 6 and 7 are used to investigate the role of cloud and surface radiative forcing and elements of the earth's general circulation. Although globally integrated cloud forcing is nearly zero, there are large regional imbalances and well regulated processes in the shortwave and longwave spectrum that control the meridional gradient structure of the net radiation balance and the factors modulating the east-west oriented North Africa-western Pacific energy transport dipole. The analysis demonstrates that clouds play a dual role in both the shortwave and longwave spectra in terms of tropical and midlatitude east-west gradients. The key result is that cloud forcing, although not always the principle regulator of interannual variability of the global climate, serves to reinforce the basic three-cell meridional circulation.

  3. Interannual variability of the global net radiation balance and its consequence on global energy transport

    NASA Technical Reports Server (NTRS)

    Smith, Eric A.; Sohn, B. J.

    1990-01-01

    Global cloudiness and radiation budget data from Nimbus 6 and 7 are used to investigate the role of cloud and surface radiative forcing and elements of the earth's general circulation. Although globally integrated cloud forcing is nearly zero, there are large regional imbalances and well regulated processes in the shortwave and longwave spectrum that control the meridional gradient structure of the net radiation balance and the factors modulating the east-west oriented North Africa-western Pacific energy transport dipole. The analysis demonstrates that clouds play a dual role in both the shortwave and longwave spectra in terms of tropical and midlatitude east-west gradients. The key result is that cloud forcing, although not always the principle regulator of interannual variability of the global climate, serves to reinforce the basic three-cell meridional circulation.

  4. Water savings potentials of irrigation systems: dynamic global simulation

    NASA Astrophysics Data System (ADS)

    Jägermeyr, J.; Gerten, D.; Heinke, J.; Schaphoff, S.; Kummu, M.; Lucht, W.

    2015-04-01

    Global agricultural production is heavily sustained by irrigation, but irrigation system efficiencies are often surprisingly low. However, our knowledge of irrigation efficiencies is mostly confined to rough indicative estimates for countries or regions that do not account for spatio-temporal heterogeneity due to climate and other biophysical dependencies. To allow for refined estimates of global agricultural water use, and of water saving and water productivity potentials constrained by biophysical processes and also non-trivial downstream effects, we incorporated a dynamic representation of the three major irrigation systems (surface, sprinkler, and drip) into a process-based bio- and agrosphere model, LPJmL. Based on this enhanced model we provide a gridded worldmap of dynamically retrieved irrigation efficiencies reflecting differences in system types, crop types, climatic and hydrologic conditions, and overall crop management. We find pronounced regional patterns in beneficial irrigation efficiency (a refined irrigation efficiency indicator accounting for crop-productive water consumption only), due to differences in these features, with lowest values (< 30%) in South Asia and Sub-Saharan Africa and highest values (> 60%) in Europe and North America. We arrive at an estimate of global irrigation water withdrawal of 2396 km3 (2004-2009 average); irrigation water consumption is calculated to be 1212 km3, of which 511 km3 are non-beneficially consumed, i.e. lost through evaporation, interception, and conveyance. Replacing surface systems by sprinkler or drip systems could, on average across the world's river basins, reduce the non-beneficial consumption at river basin level by 54 and 76%, respectively, while maintaining the current level of crop yields. Accordingly, crop water productivity would increase by 9 and 15%, respectively, and by much more in specific regions such as in the Indus basin. This study significantly advances the global quantification of

  5. Renewable Energy Potential for New Mexico

    EPA Pesticide Factsheets

    RE-Powering America's Land: Renewable Energy on Contaminated Land and Mining Sites was presented by Penelope McDaniel, during the 2008 Brown to Green: Make the Connection to Renewable Energy workshop.

  6. Global energy and water balances in the latest reanalyses

    NASA Astrophysics Data System (ADS)

    Kang, Suchul; Ahn, Joong-Bae

    2015-11-01

    The recently released Japanese 55-year Reanalysis (JRA- 55) data are evaluated and compared with three other global reanalyses, namely Interim version of the next European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERA-Interim), Modern Era Retrospective-Analysis for Research and Applications (MERRA) and Climate Forecast System Reanalysis (CFSR), in terms of global energy and water balances. All four reanalyses show an energy imbalance at TOA and surface. Especially, clouds in JRA-55 are optically weaker than those in the three other reanalyses, leading to excessive outgoing longwave radiation, which in turn causes negative net energy flux at TOA. Moreover, JRA-55 has a negative imbalance at surface and at TOA, which is attributed to systematic positive biases in latent heat flux over the ocean. As for the global water balance, all reanalyses present a similar spatial pattern of the difference between evaporation and precipitation (E-P). However, JRA-55 has a relatively strong negative (positive) E-P in the Intertropical Convergence Zone and South Pacific Convergence Zone (extratropical regions) due to overestimated precipitation (evaporation), in spite of the global net being close to zero. In time series analysis, especially in E-P, significant stepwise changes occur in MERRA, CFSR and ERA-Interim due to the changes in the satellite observing system used in the data assimilation. Both MERRA and CFSR show a strong downward E-P shift in 1998, simultaneously with the start of the assimilation of AMSU-A sounding radiances. ERA-Interim exhibits an upward E-P shift in 1992 due to changes in observations from the SSM/I of new DMSP satellites. On the contrary, JRA-55 exhibits less trends and remains stable over time, which may be caused by newly available, homogenized observations and advances in data assimilation technique.

  7. Determinants of the pace of global innovation in energy technologies.

    PubMed

    Bettencourt, Luís M A; Trancik, Jessika E; Kaur, Jasleen

    2013-01-01

    Understanding the factors driving innovation in energy technologies is of critical importance to mitigating climate change and addressing other energy-related global challenges. Low levels of innovation, measured in terms of energy patent filings, were noted in the 1980s and 90s as an issue of concern and were attributed to limited investment in public and private research and development (R&D). Here we build a comprehensive global database of energy patents covering the period 1970-2009, which is unique in its temporal and geographical scope. Analysis of the data reveals a recent, marked departure from historical trends. A sharp increase in rates of patenting has occurred over the last decade, particularly in renewable technologies, despite continued low levels of R&D funding. To solve the puzzle of fast innovation despite modest R&D increases, we develop a model that explains the nonlinear response observed in the empirical data of technological innovation to various types of investment. The model reveals a regular relationship between patents, R&D funding, and growing markets across technologies, and accurately predicts patenting rates at different stages of technological maturity and market development. We show quantitatively how growing markets have formed a vital complement to public R&D in driving innovative activity. These two forms of investment have each leveraged the effect of the other in driving patenting trends over long periods of time.

  8. Determinants of the Pace of Global Innovation in Energy Technologies

    PubMed Central

    Kaur, Jasleen

    2013-01-01

    Understanding the factors driving innovation in energy technologies is of critical importance to mitigating climate change and addressing other energy-related global challenges. Low levels of innovation, measured in terms of energy patent filings, were noted in the 1980s and 90s as an issue of concern and were attributed to limited investment in public and private research and development (R&D). Here we build a comprehensive global database of energy patents covering the period 1970–2009, which is unique in its temporal and geographical scope. Analysis of the data reveals a recent, marked departure from historical trends. A sharp increase in rates of patenting has occurred over the last decade, particularly in renewable technologies, despite continued low levels of R&D funding. To solve the puzzle of fast innovation despite modest R&D increases, we develop a model that explains the nonlinear response observed in the empirical data of technological innovation to various types of investment. The model reveals a regular relationship between patents, R&D funding, and growing markets across technologies, and accurately predicts patenting rates at different stages of technological maturity and market development. We show quantitatively how growing markets have formed a vital complement to public R&D in driving innovative activity. These two forms of investment have each leveraged the effect of the other in driving patenting trends over long periods of time. PMID:24155867

  9. A global conversation about energy from biomass: the continental conventions of the global sustainable bioenergy project.

    PubMed

    Lynd, Lee Rybeck; Aziz, Ramlan Abdul; de Brito Cruz, Carlos Henrique; Chimphango, Annie Fabian Abel; Cortez, Luis Augusto Barbosa; Faaij, Andre; Greene, Nathanael; Keller, Martin; Osseweijer, Patricia; Richard, Tom L; Sheehan, John; Chugh, Archana; van der Wielen, Luuk; Woods, Jeremy; van Zyl, Willem Heber

    2011-04-06

    The global sustainable bioenergy (GSB) project was formed in 2009 with the goal of providing guidance with respect to the feasibility and desirability of sustainable, bioenergy-intensive futures. Stage 1 of this project held conventions with a largely common format on each of the world's continents, was completed in 2010, and is described in this paper. Attended by over 400 persons, the five continental conventions featured presentations, breakout sessions, and drafting of resolutions that were unanimously passed by attendees. The resolutions highlight the potential of bioenergy to make a large energy supply contribution while honouring other priorities, acknowledge the breadth and complexity of bioenergy applications as well as the need to take a systemic approach, and attest to substantial intra- and inter-continental diversity with respect to needs, opportunities, constraints and current practice relevant to bioenergy. The following interim recommendations based on stage 1 GSB activities are offered: - Realize that it may be more productive, and also more correct, to view the seemingly divergent assessments of bioenergy as answers to two different questions rather than the same question. Viewed in this light, there is considerably more scope for reconciliation than might first be apparent, and it is possible to be informed rather than paralysed by divergent assessments.- Develop established and advanced bioenergy technologies such that each contributes to the other's success. That is, support and deploy in the near-term meritorious, established technologies in ways that enhance rather than impede deployment of advanced technologies, and support and deploy advanced technologies in ways that expand rather than contract opportunities for early adopters and investors.- Be clear in formulating policies what mix of objectives are being targeted, measure the results of these policies against these objectives and beware of unintended consequences

  10. A global conversation about energy from biomass: the continental conventions of the global sustainable bioenergy project

    PubMed Central

    Lynd, Lee Rybeck; Aziz, Ramlan Abdul; de Brito Cruz, Carlos Henrique; Chimphango, Annie Fabian Abel; Cortez, Luis Augusto Barbosa; Faaij, Andre; Greene, Nathanael; Keller, Martin; Osseweijer, Patricia; Richard, Tom L.; Sheehan, John; Chugh, Archana; van der Wielen, Luuk; Woods, Jeremy; van Zyl, Willem Heber

    2011-01-01

    The global sustainable bioenergy (GSB) project was formed in 2009 with the goal of providing guidance with respect to the feasibility and desirability of sustainable, bioenergy-intensive futures. Stage 1 of this project held conventions with a largely common format on each of the world's continents, was completed in 2010, and is described in this paper. Attended by over 400 persons, the five continental conventions featured presentations, breakout sessions, and drafting of resolutions that were unanimously passed by attendees. The resolutions highlight the potential of bioenergy to make a large energy supply contribution while honouring other priorities, acknowledge the breadth and complexity of bioenergy applications as well as the need to take a systemic approach, and attest to substantial intra- and inter-continental diversity with respect to needs, opportunities, constraints and current practice relevant to bioenergy. The following interim recommendations based on stage 1 GSB activities are offered: — Realize that it may be more productive, and also more correct, to view the seemingly divergent assessments of bioenergy as answers to two different questions rather than the same question. Viewed in this light, there is considerably more scope for reconciliation than might first be apparent, and it is possible to be informed rather than paralysed by divergent assessments.— Develop established and advanced bioenergy technologies such that each contributes to the other's success. That is, support and deploy in the near-term meritorious, established technologies in ways that enhance rather than impede deployment of advanced technologies, and support and deploy advanced technologies in ways that expand rather than contract opportunities for early adopters and investors.— Be clear in formulating policies what mix of objectives are being targeted, measure the results of these policies against these objectives and beware of unintended consequences

  11. Energy savings potential from energy-conserving irrigation systems

    SciTech Connect

    Wilfert, G.L.; Patton, W.P.; Harrer, B.J.; Clark, M.A.

    1982-11-01

    This report systematically compares, within a consistent framework, the technical and economic characteristics of energy-conserving irrigation systems with those of conventional irrigation systems and to determine total energy savings. Levelized annual costs of owning and operating both energy-conserving and conventional irrigation systems have been developed and compared for all 17 states to account for the differences in energy costs and irrigation conditions in each state. Market penetration of energy-conserving systems is assessed for those systems having lower levelized annual costs than conventional systems performing the same function. Annual energy savings were computed by matching the energy savings per system with an assumed maximum market penetration of 100 percent in those markets where the levelized annual costs of energy-conserving systems are lower than the levelized annual costs of conventional systems.

  12. GIS Assessment of Wind Energy Potential in California and Florida

    NASA Astrophysics Data System (ADS)

    Snow, R. K.; Snow, M. M.

    2008-05-01

    Energy efficiency coupled with renewable energy technologies can provide most of the U.S. carbon emissions reductions needed to contain atmospheric carbon concentrations at 450-500 parts per million, considered by many to be a tipping point in mitigating climate change. Among the leaders in the alternative energy sector is wind power, which is now one of the largest sources of new power generation in the U.S. creating jobs and revenue for rural communities while powering our economy with an emissions-free source of energy. In 2006, wind turbines capable of generating more than 2,400 megawatts of electricity were installed in the U.S. and by 2007 this number had risen to 3,000 megawatts. The U.S. generated 31 billion kilowatt-hours of wind power in 2007, which is enough electricity to power the equivalent of nearly 3 million average homes. It is estimated that generating the same amount of electricity would require burning 16 million tons of coal or 50 million barrels of oil. This study examines the wind power potential of sites near populated areas in Florida and California to determine the practicability of installing wind turbines at these locations. A GIS was developed in order to conduct a spatial analysis of these sites based on mean annual wind speed measured in meters per second and wind power density ratings measured in watts per square meter. The analysis indicates that coastal areas of Cocoa Beach, Key West, Hollywood, and West Palm Beach, respectively, possess the greatest potential for wind energy in Florida with mean annual wind speeds of 4.9 m/s and average wind power density ratings of 171 w/m2 peaking at Cocoa Beach followed by wind speeds of 4.64 m/s and wind power ratings of 115 w/m2 at Key West. California wind energy potential is even greater than that of Florida with Fairfield exhibiting mean annual wind speeds of 5.9 m/s and average wind power density ratings of 327 w/m2 followed by the Mojave and Palmdale areas with mean annual wind speeds of

  13. Indirect Global Warming Potentials of Halons Using Atmospheric Models

    NASA Astrophysics Data System (ADS)

    Youn, D.; Patten, K. O.; Wuebbles, D. J.

    2007-05-01

    Emission of bromochlorofluorocarbons, or Halons, results in stratospheric ozone depletion. This leads to cooling of the climate system in the opposite direction to direct warming contribution of the Halons as greenhouse gases. This cooling is a key indirect effect of Halons on radiative forcing or climate. The Global Warming Potential (GWP) is a relative index used to compare the climate impact of an emitted greenhouse gas, relative to an equal amount of carbon dioxide. Until now, indirect GWPs have been calculated based on the concept of Equivalent Effective Stratospheric Chlorine (EESC), which oversimplifies the complex processes in the atmosphere. As a step towards obtaining indirect GWPs through a more robust approach, 2-D and 3-D global chemical transport models (CTM) were used as the computational tool to derive more realistic ozone changes caused by pulse perturbation of Halons at the surface. Indirect GWPs of Halon-1211 and -1301 for a 100-year time horizon were explicitly calculated based on the University of Illinois at Urbana-Champaign (UIUC) 2-D global CTM and radiative transport model (RTM) and the 3-D CTM, MOZART-3.1. The 2-D and 3-D model simulations show acceptable temporal variations in the atmosphere as well as derived lifetimes and direct GWP values of the Halons. The 2-D model-based indirect GWPs for a 100-year horizon are -16,294 for Halon-1211 and -33,648 for Halon-1301. 3-D indirect GWP for Halon-1211 is -18,216. The indirect GWPs for Halon-1211 presented here are much smaller than previous published results using the previous simplified appraoch.

  14. Global Energy and Water Balances in the Latest Reanalyses

    NASA Astrophysics Data System (ADS)

    Ahn, Joong-Bae; Kang, Suchul; Park, Hye-Jin

    2016-04-01

    The recently released Japanese 55-year Reanalysis (JRA-55) data are evaluated and compared with three other global reanalyses, namely Interim version of the next European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERRA-Interim), Modern Era Retrospective-Analysis for Research and Applications (MERRA) and Climate Forecast System Reanalysis (CFSR), in terms of global energy and water balances. All four reanalyses show an energy imbalance at TOA and surface. Especially, clouds in JRA-55 are optically weaker than those in the three other reanalyses, leading to excessive outgoing longwave radiation, which in turn causes negative net energy flux at TOA. Moreover, JRA-55 has a negative imbalance at surface and at TOA, which is attributed to systematic positive biases in latent heat flux over the ocean. As for the global water balance, all reanalyses present a similar spatial pattern of the difference between evaporation and precipitation (E-P). However, JRA-55 has a relatively strong negative (positive) E-P in the Intertropical Convergence Zone and South Pacific Convergence Zone (extratropical regions) due to overestimated precipitation (evaporation), in spite of the global net being close to zero. In time series analysis, especially in E-P, significant stepwise changes occur in MERRA, CFSR and ERA-Interim due to the changes occur in MERRA, CFRS and ERA-Interim due to the changes in the satellite observing system used in the data assimilation. Both MERRA and CFSR show a strong downward E-P shift in 1998, simultaneously with the start of the assimilation of AMSU-A sounding radiances. ERA-Interim exhibits an upward E-P shift in 1992 due to changes in observations from the SSM/I of new DMSP satellites. On the contrary, JRA-55 exhibits less trends and remains stable over time, which may be caused by newly available, homogenized observations and advances in data assimilation technique. Acknowledgements This work was funded by the Korea Meteorological

  15. Global warming: Energy efficiency is key to reduce dangerous threat

    SciTech Connect

    Not Available

    1989-09-01

    A consensus is growing among scientists, policymakers and citizens that human activity is altering the Earth's climate. Humans are loading carbon dioxide, methane and other pollutants into the atmosphere through deforestation and the burning of fossil fuels. The result, scientists say: pollutants are accelerating the greenhouse effect which is raising the average global temperature. A few degree temperature increase is projected to make major changes in agriculture and many other things. A growing number of scientists believe if these pollutants are not reduced, global warming could destroy the Earth's climatic balance on which our civilization rests, causing disruptions such as heat waves, droughts, coastal flooding and a rise in sea level. Clearly, all the facts about global warming, its exact causes and repercussions on the earth's climate, are not yet in. However, one thing is certain: We are not helpless and we can act now to reduce greenhouse gases through energy efficiency and halting deforestation. While energy efficiency, itself, is not a panacea, it is both an economic opportunity and environmental necessity for out nation, and for our earth.

  16. Tropospheric energy cascades in a global circulation model

    NASA Astrophysics Data System (ADS)

    Brune, Sebastian; Becker, Erich

    2010-05-01

    The global horizontal kinetic energy (KE) spectrum and its budget are analyzed using results from a mechanistic GCM. The model has a standard spectral dynamical core with very high vertikal resolution up to the middle stratosphere (T330/L100). As a turbulence model we combine the Smagorinsky scheme with an energy conserving hyperdiffusion that is applied for the very smallest resolved scales. The simulation confirms a slope of the KE spectrum close to -3 in the synoptic regime where the KE is dominated by vortical modes. Towards the mesoscales the spectrum flattens and assumes a slope close to -5/3. Here divergent modes become increasingly important and even dominate the KE. Our complete analysis of the sinks and sources in the spectral KE budget reveals the overall energy fluxes through the spectrum. For the upper troposphere, the change of KE due to horizontal advection is negative for large synoptic scales. It is positive for the planetary scale, as expected, and for the mesoscales as well. This implies that the mesoscales, which include the dynamical sources of tropospheric gravity waves, are in fact sustained by the energy injection at the baroclinic scale (forward energy cascade). We find an enstrophy cascade in accordance with 2D turbulence, but zero downscaling of energy due to the vortical modes alone. In other words, the forward energy cascade in the synoptic and mesoscale regime is solely due to the divergent modes and their nonlinear interaction with the vortical modes. This picture, derived form a mechanistic model, not only lends further evidence for a generally forward energy cascade in the upper tropospheric away from the baroclinic scale. It also extends the picture proposed earlier by Tung and Orlando: The transition from a -3 to a -5/3 slope in the tropospheric macroturbulence spectrum reflects the fact, that the energy cascade due to the horizontally divergent (3D) modes is hidden behind the (2D) enstrophy cascade in the synoptic regime but

  17. Static strings in global AdS space and quark-antiquark potential

    SciTech Connect

    Bayona, C. A. Ballon; Ferreira, Cristine N.

    2008-07-15

    We investigate the finite temperature quark antiquark problem in a compact space S{sup n-1}xS{sup 1} by considering static strings in global AdS{sub n+1} space with n{>=}3. For high temperatures we work in the black hole metric where two possible solutions show up : the big black hole and the small black hole. Using the AdS/CFT correspondence, we calculate the quark antiquark potential (free energy) as a function of the distance. We show that this potential can be intrepeted as confining for the anti-de Sitter (AdS) space and deconfining for the big black hole. We find for the small black hole a confining limit for the potential but this solution is instable following the Hawking-Page criteria. Our results for the free energy reinforce the Witten interpretation of the confinement/deconfinement transition as the dual of the well-known Hawking-Page transition.

  18. Restoring low-input high-diversity grasslands as a potential global resource for biofuels.

    PubMed

    Machovina, Brian; Feeley, Kenneth J

    2017-12-31

    Reducing meat consumption by humans and shifting to more efficient plant and animal protein sources could potentially free up large areas of pasture and feedcrop agricultural land for restoration or conversion to low-input high-diversity (LIHD) grasslands. LIHD grasslands improve biodiversity, carbon sequestration, erosion control, water storage, while also providing opportunities to produce biofuels. We examined the potential of converting pastures globally, and animal feedstock agricultural lands in the USA and Brazil, to LIHD biomass sources and the capacity of these systems to meet national energy demands via (1) cellulosic ethanol and (2) integrated gasification and combined cycle technology with Fischer-Tropsch hydrocarbon synthesis (IGCC-FT) processing. Our analyses, which we argue are conservative, indicate that large amounts of energy, far in excess of many country's current demands, can potentially be produced from IGCC-FT processing of grassland biomass grown on converted pastures, especially in tropical developing countries. Over 40 countries could meet ≥100% of their domestic demands for electricity, gasoline, and diesel. If energy products were shared between countries, the 95 countries with positive energy production yields could meet 46%, 28%, and 39% of their combined electricity, gasoline, and diesel demands, respectively. While it is clearly unrealistic to propose a 100% conversion of pasture lands to biofuel production, these analyses highlight the potential gains in ecosystem services and energy production that could theoretically be achieved on already-managed lands. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Limited options for low-global-warming-potential refrigerants

    PubMed Central

    McLinden, Mark O.; Brown, J. Steven; Brignoli, Riccardo; Kazakov, Andrei F.; Domanski, Piotr A.

    2017-01-01

    Hydrofluorocarbons, currently used as refrigerants in air-conditioning systems, are potent greenhouse gases, and their contribution to climate change is projected to increase. Future use of the hydrofluorocarbons will be phased down and, thus replacement fluids must be found. Here we show that only a few pure fluids possess the combination of chemical, environmental, thermodynamic, and safety properties necessary for a refrigerant and that these fluids are at least slightly flammable. We search for replacements by applying screening criteria to a comprehensive chemical database. For the fluids passing the thermodynamic and environmental screens (critical temperature and global warming potential), we simulate performance in small air-conditioning systems, including optimization of the heat exchangers. We show that the efficiency-versus-capacity trade-off that exists in an ideal analysis disappears when a more realistic system is considered. The maximum efficiency occurs at a relatively high volumetric refrigeration capacity, but there are few fluids in this range. PMID:28211518

  20. Limited options for low-global-warming-potential refrigerants

    NASA Astrophysics Data System (ADS)

    McLinden, Mark O.; Brown, J. Steven; Brignoli, Riccardo; Kazakov, Andrei F.; Domanski, Piotr A.

    2017-02-01

    Hydrofluorocarbons, currently used as refrigerants in air-conditioning systems, are potent greenhouse gases, and their contribution to climate change is projected to increase. Future use of the hydrofluorocarbons will be phased down and, thus replacement fluids must be found. Here we show that only a few pure fluids possess the combination of chemical, environmental, thermodynamic, and safety properties necessary for a refrigerant and that these fluids are at least slightly flammable. We search for replacements by applying screening criteria to a comprehensive chemical database. For the fluids passing the thermodynamic and environmental screens (critical temperature and global warming potential), we simulate performance in small air-conditioning systems, including optimization of the heat exchangers. We show that the efficiency-versus-capacity trade-off that exists in an ideal analysis disappears when a more realistic system is considered. The maximum efficiency occurs at a relatively high volumetric refrigeration capacity, but there are few fluids in this range.

  1. Recent decrease in typhoon destructive potential and global warming implications

    PubMed Central

    Lin, I-I; Chan, Johnny C.L.

    2015-01-01

    Typhoons (tropical cyclones) severely impact the half-billion population of the Asian Pacific. Intriguingly, during the recent decade, typhoon destructive potential (Power Dissipation Index, PDI) has decreased considerably (by ∼35%). This decrease, paradoxically, has occurred despite the increase in typhoon intensity and ocean warming. Using the method proposed by Emanuel (in 2007), we show that the stronger negative contributions from typhoon frequency and duration, decrease to cancel the positive contribution from the increasing intensity, controlling the PDI. Examining the typhoons' environmental conditions, we find that although the ocean condition became more favourable (warming) in the recent decade, the atmospheric condition ‘worsened' at the same time. The ‘worsened' atmospheric condition appears to effectively overpower the ‘better' ocean conditions to suppress PDI. This stronger negative contribution from reduced typhoon frequency over the increased intensity is also present under the global warming scenario, based on analysis of the simulated typhoon data from high-resolution modelling. PMID:25990561

  2. Limited options for low-global-warming-potential refrigerants.

    PubMed

    McLinden, Mark O; Brown, J Steven; Brignoli, Riccardo; Kazakov, Andrei F; Domanski, Piotr A

    2017-02-17

    Hydrofluorocarbons, currently used as refrigerants in air-conditioning systems, are potent greenhouse gases, and their contribution to climate change is projected to increase. Future use of the hydrofluorocarbons will be phased down and, thus replacement fluids must be found. Here we show that only a few pure fluids possess the combination of chemical, environmental, thermodynamic, and safety properties necessary for a refrigerant and that these fluids are at least slightly flammable. We search for replacements by applying screening criteria to a comprehensive chemical database. For the fluids passing the thermodynamic and environmental screens (critical temperature and global warming potential), we simulate performance in small air-conditioning systems, including optimization of the heat exchangers. We show that the efficiency-versus-capacity trade-off that exists in an ideal analysis disappears when a more realistic system is considered. The maximum efficiency occurs at a relatively high volumetric refrigeration capacity, but there are few fluids in this range.

  3. POTLIB 2001: A potential energy surface library for chemical systems

    NASA Astrophysics Data System (ADS)

    Duchovic, Ronald J.; Volobuev, Yuri L.; Lynch, Gillian C.; Truhlar, Donald G.; Allison, Thomas C.; Wagner, Albert F.; Garrett, Bruce C.; Corchado, Jose C.

    2002-04-01

    POTLIB 2001 is a computer program library of global chemical potential energy surface (PES) functions (91 functions in version 1.0) along with test data, a suite of utility programs, and a convenient user interface. The PES programs are written in ANSI standard FORTRAN77 and can be used to determine the Born-Oppenheimer potential energy of chemical systems as a function of the internal coordinates. The accompanying test data allow users to verify local implementations of this library. Finally, the utility programs permit use of this library in conjunction with a variety of chemical dynamics and chemical kinetics computer codes. Interface routines are provided for the POLYRATE and ABCRATE program packages of Truhlar and co-workers, the VENUS96 program package of Hase and co-workers, and the VARIFLEX program package of Klippenstein and co-workers; the routines in this library can also be used in conjunction with the DYNASOL program package of Zhang and co-workers. This article describes the library and the utility programs and outlines the systematic conventions used for interfaces in the computer programs contained in the library. Adherence to these conventions will allow future PESs to be compatible with this library.

  4. 40 CFR Table A-1 to Subpart A of... - Global Warming Potentials

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Global Warming Potentials A Table A-1... A-1 to Subpart A of Part 98—Global Warming Potentials Global Warming Potentials Name CAS No. Chemical formula Global warming potential(100 yr.) Carbon dioxide 124-38-9 CO2 1 Methane 74-82-8 CH4 a 25...

  5. Global Change Simulations Affect Potential Methane Oxidation in Upland Soils

    NASA Astrophysics Data System (ADS)

    Blankinship, J. C.; Hungate, B. A.

    2004-12-01

    Atmospheric concentrations of methane (CH4) are higher now than they have ever been during the past 420,000 years. However, concentrations have remained stable since 1999. Emissions associated with livestock husbandry are unlikely to have changed, so some combination of reduced production in wetlands, more efficient capture by landfills, or increased consumption by biological CH4 oxidation in upland soils may be responsible. Methane oxidizing bacteria are ubiquitous in upland soils and little is known about how these bacteria respond to anthropogenic global change, and how they will influence - or already are influencing - the radiative balance of the atmosphere. Might ongoing and future global changes increase biological CH4 oxidation? Soils were sampled from two field experiments to assess changes in rates of CH4 oxidation in response to global change simulations. Potential activities of CH4 oxidizing bacterial communities were measured through laboratory incubations under optimal temperature, soil moisture, and atmospheric CH4 concentrations (~18 ppm, or 10x ambient). The ongoing 6-year multifactorial Jasper Ridge Global Change Experiment (JRGCE) simulates warming, elevated precipitation, elevated atmospheric CO2, elevated atmospheric N deposition, and increased wildfire frequency in an annual grassland in a Mediterranean-type climate in central California. The ongoing 1-year multifactorial Merriam Climate Change Experiment (MCCE) simulates warming, elevated precipitation, and reduced precipitation in four different types of ecosystems along an elevational gradient in a semi-arid climate in northern Arizona. The high desert grassland, pinyon-juniper woodland, ponderosa pine forest, and mixed conifer forest ecosystems range in annual precipitation from 100 to 1000 mm yr-1, and from productivity being strongly water limited to strongly temperature limited. Among JRGCE soils, elevated atmospheric CO2 increased potential CH4 oxidation rates (p=0.052) and wildfire

  6. Energy conservation potential of surface modification technologies

    SciTech Connect

    Le, H.K.; Horne, D.M.; Silberglitt, R.S.

    1985-09-01

    This report assesses the energy conservation impact of surface modification technologies on the metalworking industries. The energy conservation impact of surface modification technologies on the metalworking industries is assessed by estimating their friction and wear tribological sinks and the subsequent reduction in these sinks when surface modified tools are used. Ion implantation, coatings, and laser and electron beam surface modifications are considered.

  7. The Potential Energy of an Autoencoder.

    PubMed

    Kamyshanska, Hanna; Memisevic, Roland

    2015-06-01

    Autoencoders are popular feature learning models, that are conceptually simple, easy to train and allow for efficient inference. Recent work has shown how certain autoencoders can be associated with an energy landscape, akin to negative log-probability in a probabilistic model, which measures how well the autoencoder can represent regions in the input space. The energy landscape has been commonly inferred heuristically, by using a training criterion that relates the autoencoder to a probabilistic model such as a Restricted Boltzmann Machine (RBM). In this paper we show how most common autoencoders are naturally associated with an energy function, independent of the training procedure, and that the energy landscape can be inferred analytically by integrating the reconstruction function of the autoencoder. For autoencoders with sigmoid hidden units, the energy function is identical to the free energy of an RBM, which helps shed light onto the relationship between these two types of model. We also show that the autoencoder energy function allows us to explain common regularization procedures, such as contractive training, from the perspective of dynamical systems. As a practical application of the energy function, a generative classifier based on class-specific autoencoders is presented.

  8. Energy in America: Progress and Potential.

    ERIC Educational Resources Information Center

    American Petroleum Inst., Washington, DC.

    An overview of America's energy situation is presented with emphasis on recent progress, the risk of depending upon foreign oil, and policy choices. Section one reviews the energy problems of the 1970s, issues of the 1980s, concerns for the future, and choices that if made today could alleviate future problems. Section two examines past problems,…

  9. HIGH ENERGY PHYSICS POTENTIAL AT MUON COLLIDERS

    SciTech Connect

    PARSA,Z.

    2000-04-07

    In this paper, high energy physics possibilities and future colliders are discussed. The {mu}{sup +} {mu}{sup {minus}} collider and experiments with high intensity muon beams as the stepping phase towards building Higher Energy Muon Colliders (HEMC) are briefly reviewed and encouraged.

  10. Energy in America: Progress and Potential.

    ERIC Educational Resources Information Center

    American Petroleum Inst., Washington, DC.

    An overview of America's energy situation is presented with emphasis on recent progress, the risk of depending upon foreign oil, and policy choices. Section one reviews the energy problems of the 1970s, issues of the 1980s, concerns for the future, and choices that if made today could alleviate future problems. Section two examines past problems,…

  11. Long-Term Global Heating From Energy Usage

    NASA Astrophysics Data System (ADS)

    Chaisson, Eric J.

    2008-07-01

    Even if civilization on Earth stops polluting the biosphere with greenhouse gases, humanity could eventually be awash in too much heat, namely, the dissipated heat by-product generated by any nonrenewable energy source. Apart from the Sun's natural aging-which causes an approximately 1% luminosity rise for each 108 years and thus about 1°C increase in Earth's surface temperature-well within 1000 years our technological society could find itself up against a fundamental limit to growth: an unavoidable global heating of roughly 3°C dictated solely by the second law of thermodynamics, a biogeophysical effect often ignored when estimating future planetary warming scenarios.

  12. Global and regional potential for bioenergy from agricultural and forestry residue biomass

    SciTech Connect

    Gregg, Jay S.; Smith, Steven J.

    2010-02-11

    As co-products, agricultural and forestry residues represent a potential low cost, low carbon, source for bioenergy. A method is developed method for estimating the maximum sustainable amount of energy potentially available from agricultural and forestry residues by converting crop production statistics into associated residue, while allocating some of this resource to remain on the field to mitigate erosion and maintain soil nutrients. Currently, we estimate that the world produces residue biomass that could be sustainably harvested and converted into over 50 EJ yr-1 of energy. The top three countries where this resource is estimated to be most abundant are currently net energy importers: China, the United States (US), and India. The global potential from residue biomass is estimated to increase to approximately 80-95 EJ yr-1 by mid- to late- century, depending on physical assumptions such as of future crop yields and the amount of residue sustainably harvestable. The future market for biomass residues was simulated using the Object-Oriented Energy, Climate, and Technology Systems Mini Climate Assessment Model (ObjECTS MiniCAM). Utilization of residue biomass as an energy source is projected for the next century under different climate policy scenarios. Total global use of residue biomass is estimated to increase to 70-100 EJ yr-1 by mid- to late- century in a central case, depending on the presence of a climate policy and the economics of harvesting, aggregating, and transporting residue. Much of this potential is in developing regions of the world, including China, Latin America, Southeast Asia, and India.

  13. Climate-change impact potentials as an alternative to global warming potentials

    NASA Astrophysics Data System (ADS)

    Kirschbaum, Miko U. F.

    2014-03-01

    For policy applications, such as for the Kyoto Protocol, the climate-change contributions of different greenhouse gases are usually quantified through their global warming potentials. They are calculated based on the cumulative radiative forcing resulting from a pulse emission of a gas over a specified time period. However, these calculations are not explicitly linked to an assessment of ultimate climate-change impacts. A new metric, the climate-change impact potential (CCIP), is presented here that is based on explicitly defining the climate-change perturbations that lead to three different kinds of climate-change impacts. These kinds of impacts are: (1) those related directly to temperature increases; (2) those related to the rate of warming; and (3) those related to cumulative warming. From those definitions, a quantitative assessment of the importance of pulse emissions of each gas is developed, with each kind of impact assigned equal weight for an overall impact assessment. Total impacts are calculated under the RCP6 concentration pathway as a base case. The relevant climate-change impact potentials are then calculated as the marginal increase of those impacts over 100 years through the emission of an additional unit of each gas in 2010. These calculations are demonstrated for CO2, methane and nitrous oxide. Compared with global warming potentials, climate-change impact potentials would increase the importance of pulse emissions of long-lived nitrous oxide and reduce the importance of short-lived methane.

  14. Discontinuous transitions in globally coupled potential systems with additive noise

    NASA Astrophysics Data System (ADS)

    Kürsten, Rüdiger; Behn, Ulrich

    2016-12-01

    An infinite array of globally coupled overdamped constituents moving in a double-well potential with n th order saturation term under the influence of additive Gaussian white noise is investigated. The system exhibits a continuous phase transition from a symmetric phase to a symmetry-broken phase. The qualitative behavior is independent on n . The critical point is calculated for strong and for weak noise; these limits are also bounds for the critical point. Introducing an additional nonlinearity, such that the potential can have up to three minima, leads to richer behavior. There the parameter space divides into three regions: a region with a symmetric phase, a region with a phase of broken symmetry and a region where both phases coexist. The region of coexistence collapses into one of the others via a discontinuous phase transition, whereas the transition between the symmetric phase and the phase of broken symmetry is continuous. The tricritical point where the three regions intersect can be calculated for strong and for weak noise. These limiting values form tight bounds on the tricritical point. In the region of coexistence simulations of finite systems are performed. One finds that the stationary distribution of finite but large systems differs qualitatively from the one of the infinite system. Hence the limits of stationarity and large system size do not commute.

  15. Advanced technology paths to global climate stability: energy for a greenhouse planet.

    PubMed

    Hoffert, Martin I; Caldeira, Ken; Benford, Gregory; Criswell, David R; Green, Christopher; Herzog, Howard; Jain, Atul K; Kheshgi, Haroon S; Lackner, Klaus S; Lewis, John S; Lightfoot, H Douglas; Manheimer, Wallace; Mankins, John C; Mauel, Michael E; Perkins, L John; Schlesinger, Michael E; Volk, Tyler; Wigley, Tom M L

    2002-11-01

    Stabilizing the carbon dioxide-induced component of climate change is an energy problem. Establishment of a course toward such stabilization will require the development within the coming decades of primary energy sources that do not emit carbon dioxide to the atmosphere, in addition to efforts to reduce end-use energy demand. Mid-century primary power requirements that are free of carbon dioxide emissions could be several times what we now derive from fossil fuels (approximately 10(13) watts), even with improvements in energy efficiency. Here we survey possible future energy sources, evaluated for their capability to supply massive amounts of carbon emission-free energy and for their potential for large-scale commercialization. Possible candidates for primary energy sources include terrestrial solar and wind energy, solar power satellites, biomass, nuclear fission, nuclear fusion, fission-fusion hybrids, and fossil fuels from which carbon has been sequestered. Non-primary power technologies that could contribute to climate stabilization include efficiency improvements, hydrogen production, storage and transport, superconducting global electric grids, and geoengineering. All of these approaches currently have severe deficiencies that limit their ability to stabilize global climate. We conclude that a broad range of intensive research and development is urgently needed to produce technological options that can allow both climate stabilization and economic development.

  16. Biofuels in the long-run global energy supply mix for transportation.

    PubMed

    Timilsina, Govinda R

    2014-01-13

    Various policy instruments along with increasing oil prices have contributed to a sixfold increase in global biofuels production over the last decade (2000-2010). This rapid growth has proved controversial, however, and has raised concerns over potential conflicts with global food security and climate change mitigation. To address these concerns, policy support is now focused on advanced or second-generation biofuels instead of crop-based first-generation biofuels. This policy shift, together with the global financial crisis, has slowed the growth of biofuels production, which has remained stagnant since 2010. Based upon a review of the literature, this paper examines the potential long-run contribution of biofuels to the global energy mix, particularly for transportation. We find that the contribution of biofuels to global transportation fuel demand is likely to be limited to around 5% over the next 10-15 years. However, a number of studies suggest that biofuels could contribute up to a quarter of global transportation fuel demand by 2050, provided technological breakthroughs reduce the costs of sustainably produced advanced biofuels to a level where they can compete with petroleum fuels.

  17. Global stabilization of high-energy resonance for a nonlinear wideband electromagnetic vibration energy harvester

    NASA Astrophysics Data System (ADS)

    Masuda, Arata; Sato, Takeru

    2016-04-01

    This paper presents an experimental verification of a wideband nonlinear vibration energy harvester which has a globally stabilized high-energy resonating response. For the conventional linear vibration energy harvester, the maximum performance of the power generation and its bandwidth are in a relation of trade-off. The resonance frequency band can be expanded by introducing a Duffing-type nonlinear resonator in order to enable the harvester to generate larger electric power in a wider frequency range. However, since such nonlinear resonators often have multiple stable steady-state solutions in the resonance band, it is difficult for the nonlinear harvester to maintain the high performance of the power generation constantly. The principle of self-excitation and entrainment has been utilized to provide the global stability to the highest-energy solution by destabilizing other unexpected lower-energy solutions by introducing a switching circuit of the load resistance between positive and the negative values depending on the response amplitude of the oscillator. In this study, an experimental verification of this concept are carried out. An experimental prototype harvester is designed and fabricated and the performance of the proposed harvester is experimentally verified. It has been shown that the numerical and experimental results agreed very well, and the highest-energy solutions above the threshold value were successfully stabilized globally.

  18. Potential Advantages of Reusing Potentially Contaminated Land for Renewable Energy Fact Sheet

    EPA Pesticide Factsheets

    EPA promotes the reuse of potentially contaminated lands and landfills for renewable energy. This strategy creates new markets for potentially contaminated lands, while providing a sustainable land development strategy for renewable energy.

  19. Separating the nature and nurture of the allocation of energy in response to global change.

    PubMed

    Applebaum, Scott L; Pan, T-C Francis; Hedgecock, Dennis; Manahan, Donal T

    2014-07-01

    Understanding and predicting biological stability and change in the face of rapid anthropogenic modifications of ecosystems and geosystems are grand challenges facing environmental and life scientists. Physiologically, organisms withstand environmental stress through changes in biochemical regulation that maintain homeostasis, which necessarily demands tradeoffs in the use of metabolic energy. Evolutionarily, in response to environmentally forced energetic tradeoffs, populations adapt based on standing genetic variation in the ability of individual organisms to reallocate metabolic energy. Combined study of physiology and genetics, separating "Nature and Nurture," is, thus, the key to understanding the potential for evolutionary adaptation to future global change. To understand biological responses to global change, we need experimentally tractable model species that have the well-developed physiological, genetic, and genomic resources necessary for partitioning variance in the allocation of metabolic energy into its causal components. Model species allow for discovery and for experimental manipulation of relevant phenotypic contrasts and enable a systems-biology approach that integrates multiple levels of analyses to map genotypic-to-phenotypic variation. Here, we illustrate how combined physiological and genetic studies that focus on energy metabolism in developmental stages of a model marine organism contribute to an understanding of the potential to adapt to environmental change. This integrative research program provides insights that can be readily incorporated into individual-based ecological models of population persistence under global change.

  20. Potential prediction needs in support of energy systems

    NASA Technical Reports Server (NTRS)

    Blake, R. L.

    1979-01-01

    The relationship between emerging energy systems and the natural environment is discussed, including selected examples to show that energy systems are tied to global solar terrestrial processess. The interdependence of resources, technology, and environmental impact is considered in terms of needed geophysical, atmospheric, and solar terrestrial data inputs. The need for long term basic research on the solar terrestrial system is emphasized.

  1. Atmospheric degradation and global warming potentials of three perfluoroalkenes

    NASA Astrophysics Data System (ADS)

    Acerboni, G.; Beukes, J. A.; Jensen, N. R.; Hjorth, J.; Myhre, G.; Nielsen, C. J.; Sundet, J. K.

    The vapour phase reactions of perfluoropropene, CF 3CFCF 2, and perfluorobuta-1,3-diene, CF 2CFCFCF 2, with OH, NO 3 and O 3 were studied at 298±4 K and 740±5 Torr using long-path FT-IR detection. The reactions with ozone are very slow, kCF 3CFCF 2+O 3=(6.2±1.5)×10 -22 and kCF 2CFCFCF 2+O 3=(6.5±0.2)×10 -21 cm 3 molecules -1 s -1, and upper limits of 3×10 -15 cm 3 molecules -1 s -1 are reported for the NO 3 reaction rate coefficients. The OH reaction rate coefficients were determined as kCF 3CFCF 2+OH =(2.6±0.7)×10 -12 and kCF 2CFCFCF 2+OH =(1.1±0.3)×10 -11 cm 3 molecules -1 s -1; perfluoropropene gave a nearly quantitative yield of CF 3CFO and CF 2O as organic products, while perfluorobuta-1,3-diene gave from 130% to 170% of CF 2O. A chemistry transport model was applied to calculate the atmospheric distributions and lifetimes of the perfluoroalkenes; the global and yearly averaged lifetimes were calculated as 1.9 day for C 2F 4 and C 4F 6 and 6 days for C 3F 6. Quantitative infrared cross-sections of perfluoroethene, perfluoropropene, and perfluorobuta-1,3-diene have been obtained at 298 K in the region 100-2600 cm -1. Radiative forcing calculations have been performed for these gases assuming either constant vertical profiles or the distribution derived from the chemistry transport model. The results show that the Global Warming Potentials are totally negligible for these compounds.

  2. High-resolution global forward modelling: a degree-5480 global ellipsoidal topographic potential model

    NASA Astrophysics Data System (ADS)

    Rexer, Moritz; Hirt, Christian; Pail, Roland

    2017-04-01

    The development of parallel computing and arithmetically extended integration algorithms make forward modelling of the gravitational potential of Earth possible on a global scale with very high resolution. We make use of an efficient spectral integration method and a composite global source-mass model developed at Technische Universität München over the past two years. The integration method allows the rigorous definition of an arbitrary number of volumetric mass layers of laterally varying mass-density that are referenced to an oblate ellipsoid of revolution. Often used simplifications such as spherical approximations and the rock-equivalent-topography concept are avoided in our modelling technique. Starting from band-limited degree-5400 layer-boundaries we demonstrate the creation of a (non-compensated) degree-5480 ellipsoidal topographic potential model that resolves the gravity field of Earth down to scales of ˜ 4 km. This involves multiple spherical harmonic analysis of the height-density functions and their first 25 integer powers to degree 5400. Stark oversampling is required in order to ban aliasing that otherwise would distort the short-scale gravitational signal. This results in large grids, dimensioned 64801 x 129601 (67 GB), initiating a parallelization of the analysis procedure. The ellipsoidal topographic potential model shows significant signal amplitudes in the spectral window ranging from degree 2161 to 5480 and we successfully demonstrate their importance in combined high-resolution gravity field modelling over various regions on Earth. As an aside the model reveals interesting insights into spherical harmonics at short scales: the signal degree variances actually are rising towards short scales since they refer to the spherical harmonic reference sphere, where short-scale signals are dramatically amplified due to the attenuation factors found in the spherical harmonic series expansion. The signal strengths at Earth's surface, in contrast, are

  3. The Global Energy Balance Archive (GEBA): A database for the worldwide measured surface energy fluxes

    NASA Astrophysics Data System (ADS)

    Wild, Martin; Ohmura, Atsumu; Schär, Christoph; Müller, Guido; Hakuba, Maria Z.; Mystakidis, Stefanos; Arsenovic, Pavle; Sanchez-Lorenzo, Arturo

    2017-02-01

    The Global Energy Balance Archive (GEBA) is a database for the worldwide measured energy fluxes at the Earth's surface. GEBA is maintained at ETH Zurich (Switzerland) and has been founded in the 1980s by Prof. Atsumu Ohmura. It has continuously been updated and currently contains around 2500 stations with 500`000 monthly mean entries of various surface energy balance components. Many of the records extend over several decades. The most widely measured quantity available in GEBA is the solar radiation incident at the Earth's surface ("global radiation"). The data sources include, in addition to the World Radiation Data Centre (WRDC) in St. Petersburg, data reports from National Weather Services, data from different research networks (BSRN, ARM, SURFRAD), data published in peer-reviewed publications and data obtained through personal communications. Different quality checks are applied to check for gross errors in the dataset. GEBA is used in various research applications, such as for the quantification of the global energy balance and its spatiotemporal variation, or for the estimation of long-term trends in the surface fluxes, which enabled the detection of multi-decadal variations in surface solar radiation, known as "global dimming" and "brightening". GEBA is further extensively used for the evaluation of climate models and satellite-derived surface flux products. On a more applied level, GEBA provides the basis for engineering applications in the context of solar power generation, water management, agricultural production and tourism. GEBA is publicly accessible over the internet via www.geba.ethz.ch.

  4. An effective way to address global environmental and energy problems

    NASA Astrophysics Data System (ADS)

    Andrienko, O.; Garelina, S.; Gysev, A.; Zakharyan, R.; Kazaryan, M.; Sachkov, V.

    2015-12-01

    This work scales the present globalism of ecological and energetic problems. The ecological problem is connected with environment pollution by polymeric waste. The energetic problem - with traditional approaches of modern energetic, in particular, use of fossil fuel for energy production and concentration of capacities for ensuring overall performance of global power supply systems that doesn't guarantee a sustainable development of power for long prospect, doesn't provide power safety of the country. The second part of work is devoted to a choice of the most effective solutions of the present global problems. The authors have proposed the plasma-chemical method of the polymer waste processing and developed a schematic diagram of the reactor. The paper contains the results of the theoretical calculation of the polymer waste processing products. The reagents, allowing to obtain hydrogen and other liquid products from polymer waste are selected. It is proposed to use rare elements for increasing the efficiency of hydrogen production from polymer waste. The results of the calculation of the efficiency of hydrogen production from polymer waste using molybdenum are revealed in the paper.

  5. A historical perspective of Global Warming Potential from Municipal Solid Waste Management

    SciTech Connect

    Habib, Komal; Schmidt, Jannick H.; Christensen, Per

    2013-09-15

    Highlights: • Five scenarios are compared based on different waste management systems from 1970 to 2010. • Technology development for incineration and vehicular exhaust system throughout the time period is considered. • Compared scenarios show continuous improvement regarding environmental performance of waste management system. • Energy and material recovery from waste account for significant savings of Global Warming Potential (GWP) today. • Technology development for incineration has played key role in lowering the GWP during past five decades. - Abstract: The Municipal Solid Waste Management (MSWM) sector has developed considerably during the past century, paving the way for maximum resource (materials and energy) recovery and minimising environmental impacts such as global warming associated with it. The current study is assessing the historical development of MSWM in the municipality of Aalborg, Denmark throughout the period of 1970 to 2010, and its implications regarding Global Warming Potential (GWP{sub 100}), using the Life Cycle Assessment (LCA) approach. Historical data regarding MSW composition, and different treatment technologies such as incineration, recycling and composting has been used in order to perform the analysis. The LCA results show a continuous improvement in environmental performance of MSWM from 1970 to 2010 mainly due to the changes in treatment options, improved efficiency of various treatment technologies and increasing focus on recycling, resulting in a shift from net emission of 618 kg CO{sub 2}-eq. tonne{sup −1} to net saving of 670 kg CO{sub 2}-eq. tonne{sup −1} of MSWM.

  6. Modelling of the Global Geopotential Energy & Stress Field

    NASA Astrophysics Data System (ADS)

    Schiffer, C.; Nielsen, S. B.

    2012-04-01

    Lateral density and topography variations yield in and important contribution to the lithospheric stress field. The leading quantity is the Geopotential Energy, the integrated lithostatic pressure in a rock column. The horizontal gradient of this quantity is related to horizontal stresses through the Equations of equilibrium of stresses. The Geopotential Energy furthermore can be linearly related to the Geoid under assumption of local isostasy. Satellite Geoid measurements contain, however, also non-isostatic deeper mantle responses of long wavelength. Unfortunately, high-pass filtering of the Geoid does not suppress only the deeper sources. The age-dependent signal of the oceanic lithosphere, for instance, is of long wave length and a prominent representative of in-plane stress, derived from the horizontal gradient of isostatic Geoid anomalies and responsible for the ridge push effect. Therefore a global lithospheric density model is required in order to isolate the shallow Geoid signal and calculate the stress pattern from isostatically compensated lithospheric sources. We use a linearized inverse method to fit a lithospheric reference model to observations such as topography and surface heat flow in the presence of local isostasy and a steady state geotherm. Subsequently we use a FEM code to solve the Equations of equilibrium of stresses for a three dimensional elastic shell. The modelled results are shown and compared with the global stress field and other publications.

  7. Review of global energy and carbon dioxide projections

    SciTech Connect

    Keepin, B.

    1986-01-01

    The concentration of carbon dioxide (CO/sub 2/) in the Earth's atmosphere has risen steadily over the last century, giving rise to the widely publicized ''greenhouse effect,'' believed to be responsible for a gradual warming trend in the Earth's climate. In addition to CO/sub 2/, recent studies have revealed increasing atmospheric concentrations of other ''greenhouse'' gases (e.g. methane, nitrous oxide, and chlorofluorocarbons) that may well exacerbate this warming trend considerably. While the sources of these latest gases have not yet been clearly identified, emissions of CO/sub 2/ into the atmosphere are known to come from anthropogenic sources, primarily the combustion of fossil fuels. Thus an important component in the investigation of future global warming is an understanding of future carbon emissions, which in turn requires a study of future energy developments, particularly fossil fuel consumption. Various attempts have recently been made to project the global energy future and corresponding CO/sub 2/ emissions several decades ahead. This paper provides a critical review of some of these efforts.

  8. Modeling the Oil Transition: A Summary of the Proceedings of the DOE/EPA Workshop on the Economic and Environmental Implications of Global Energy Transitions

    SciTech Connect

    Greene, David L

    2007-02-01

    The global energy system faces sweeping changes in the next few decades, with potentially critical implications for the global economy and the global environment. It is important that global institutions have the tools necessary to predict, analyze and plan for such massive change. This report summarizes the proceedings of an international workshop concerning methods of forecasting, analyzing, and planning for global energy transitions and their economic and environmental consequences. A specific case, it focused on the transition from conventional to unconventional oil and other energy sources likely to result from a peak in non-OPEC and/or global production of conventional oil. Leading energy models from around the world in government, academia and the private sector met, reviewed the state-of-the-art of global energy modeling and evaluated its ability to analyze and predict large-scale energy transitions.

  9. The Challenges and Potential of Nuclear Energy for Addressing Climate Change

    SciTech Connect

    Kim, Son H.; Edmonds, James A.

    2007-10-24

    The response to climate change and the stabilization of atmospheric greenhouse gas concentrations has major implications for the global energy system. Stabilization of atmospheric carbon dioxide (CO2) concentrations requires a peak and an indefinite decline of global CO2 emissions. Nuclear energy, along with other technologies, has the potential to contribute to the growing demand for energy without emitting CO2. Nuclear energy is of particular interest because of its global prevalence and its current significant contribution, nearly 20%, to the world’s electricity supply. We have investigated the value of nuclear energy in addressing climate change, and have explored the potential challenges for the rapid and large-scale expansion of nuclear energy as a response to climate change. The scope of this study is long-term and the modeling time frame extends out a century because the nature of nuclear energy and climate change dictate that perspective. Our results indicate that the value of the nuclear technology option for addressing climate change is denominated in trillions of dollars. Several-fold increases to the value of the nuclear option can be expected if there is limited availability of competing carbon-free technologies, particularly fossil-fuel based technologies that can capture and sequester carbon. Challenges for the expanded global use of nuclear energy include the global capacity for nuclear construction, proliferation, uranium availability, and waste disposal. While the economic costs of nuclear fuel and power are important, non-economic issues transcend the issues of costs. In this regard, advanced nuclear technologies and new vision for the global use of nuclear energy are important considerations for the future of nuclear power and climate change.

  10. Potential for energy recovery from humid air streams.

    Treesearch

    Howard H. Rosen

    1979-01-01

    The potential for energy recovery from the vent stream of dryers is examined by assuming the vent stream transfers its energy in a regenerative heat exchanger. Tables present energy recovery over a range of conditions. Example problems demonstrate the use of the energy recovery tables.

  11. Potential Seasonal Predictability of the Global Water Cycle

    NASA Astrophysics Data System (ADS)

    Feng, X.; DelSole, T. M.; Houser, P. R.

    2011-12-01

    The potential predictability of seasonal means of water cycle components, specifically precipitation and evaporation, are estimated using recently developed methods based on Analysis of Covariance (ANOCOVA) and the bootstrap, and the previous methods proposed by Katz (KZ), Shukla-Gutzler (SG) and Madden (MN). The ANOCOVA method has the advantage of not only taking into account autocorrelation structure in the daily time series but also accounting for the uncertainty of the estimated parameters in the significance test. This method tests whether interannual variability of seasonal means exceeds that due to weather noise under the null hypothesis that seasonal means are identical every year. The second method is based on the bootstrap technique that makes few assumptions about physical process, model structure and underlying distribution. The essence of the bootstrap is to randomly resample the daily time series to build up an empirical distribution of the variance of seasonal means under the null hypothesis that seasonal mean is independent of year. The predictability of the observed precipitation estimated by ANOCOVA, the bootstrap and KZ reveals similar spatial distribution patterns: large fraction of predictable variance (FPV) in tropics and low FPV over extatropics where interannual variability is not significantly distinguished from the weather noise. There are more regions identified potentially predictable in December-January-February (DJF) and March-April-May (MAM) than in June-July-August (JJA) and September-October-November (SON). The ANOCOVA method exhibits the highest predictability of the three methods and is close to the bootstrap, while KZ shows the smallest FPV due to the dominance of noise. Seasonal evaporation over global land from ANOCOVA, bootstrap, SG and MN indicates that high predictability occurs predominately over tropical and southern mid-latitude land areas, and modest predictability occurs over North America and Europe. The potential

  12. Sensitivity of direct global warming potentials to key uncertainties

    SciTech Connect

    Wuebbles, D.J.; Patten, K.O.; Grant, K.E. ); Jain, A.K. )

    1992-07-01

    A series of sensitivity studies examines the effect of several uncertainties in Global Wanning Potentials (GWPs). For example, the original evaluation of GWPs for the Intergovernmental Panel on Climate Change (EPCC, 1990) did not attempt to account for the possible sinks of carbon dioxide (CO{sub 2}) that could balance the carbon cycle and produce atmospheric concentrations of C0{sub 2} that match observations. In this study, a balanced carbon cycle model is applied in calculation of the radiative forcing from C0{sub 2}. Use of the balanced model produces up to 20 percent enhancement of the GWPs for most trace gases compared with the EPCC (1990) values for time horizons up to 100 years, but a decreasing enhancement with longer time horizons. Uncertainty limits of the fertilization feedback parameter contribute a 10 percent range in GWP values. Another systematic uncertainty in GWPs is the assumption of an equilibrium atmosphere (one in which the concentration of trace gases remains constant) versus a disequilibrium atmosphere. The latter gives GWPs that are 15 to 30 percent greater than the former, dependening upon the carbon dioxide emission scenario chosen. Seven scenarios are employed: constant emission past 1990 and the six EPCC (1992) emission scenarios. For the analysis of uncertainties in atmospheric lifetime ({tau}), the GWP changes in direct proportion to {tau} for short-lived gases, but to a lesser extent for gases with {tau} greater than the time horizon for the GWP calculation.

  13. Global scale comparison of simultaneous ionospheric potential measurements

    NASA Astrophysics Data System (ADS)

    Markson, R.; Ruhnke, L. H.; Williams, E. R.

    A unique series of simultaneous ionospheric potential ( VI) balloon soundings were obtained every 3 h over 2 full days at Weston, MA and Darwin, Australia, on the other side of the earth. These comparisons were to test the assumption that the ionosphere at sub-auroral latitudes is an equipotential and that a single measurement can provide a globally representative number. Another objective was to evaluate meteorological conditions affecting the measurements in a clean dry continental atmosphere (Darwin) compared with a more variable moist less clean atmosphere (Weston). The results indicate that for the Darwin data the VI measurements were within 10% of the classic Carnegie curve diurnal variation while the Weston data were more variable and often too large. The major source of error appears to be due to hydrated aerosol at Weston causing high electric fields in the exchange layer that were not fully compensated by electric fields above the inversion. The prototype instrumentation also contributed some error. The major finding of this experiment is that a layer of low conductivity air near the ground can have an unexpectedly large effect on electric field sounding data leading to error in the estimates of VI magnitude. This finding would not have been possible if simultaneous measurements in different airmasses had not been made since the individual electric field profiles appeared normal.

  14. Limited options for low-global-warming-potential refrigerants

    DOE PAGES

    McLinden, Mark O.; Brown, J. Steven; Brignoli, Riccardo; ...

    2017-02-17

    Hydrofluorocarbons, currently used as refrigerants in air-conditioning systems, are potent greenhouse gases, and their contribution to climate change is projected to increase. Future use of the hydrofluorocarbons will be phased down and, thus replacement fluids must be found. Here we show that only a few pure fluids possess the combination of chemical, environmental, thermodynamic, and safety properties necessary for a refrigerant and that these fluids are at least slightly flammable.We search for replacements by applying screening criteria to a comprehensive chemical database. For the fluids passing the thermodynamic and environmental screens (critical temperature and global warming potential), we simulate performancemore » in small air-conditioning systems, including optimization of the heat exchangers. We show that the efficiency-versus-capacity trade-off that exists in an ideal analysis disappears when a more realistic system is considered. Furthermore, the maximum efficiency occurs at a relatively high volumetric refrigeration capacity, but there are few fluids in this range.« less

  15. Solar Energy: Potential Powerhouse for Jobs

    ERIC Educational Resources Information Center

    McCallion, Tom

    1976-01-01

    Components of solar energy systems are described, the development of the solar industry discussed, and implications are drawn for employment opportunities in industries (which may expand into new, solar-related areas) and in the professions, from law to sales, upon the advent of solar heating. (AJ)

  16. Energy Consumption and Renewable Energy Development Potential on Indian Lands

    EIA Publications

    2000-01-01

    Includes information on the electricity use and needs of Indian households and tribes, the comparative electricity rates that Indian households are paying, and the potential for renewable resources development of Indian lands.

  17. Global Energetics of Solar Flares: II. Thermal Energies

    NASA Astrophysics Data System (ADS)

    Aschwanden, Markus J.; Boerner, Paul; Ryan, Daniel; Caspi, Amir; McTiernan, James M.; Warren, Harry P.

    2015-03-01

    We present the second part of a project on the global energetics of solar flares and coronal mass ejections that includes about 400 M- and X-class flares observed with the Atmospheric Imaging Assembly (AIA) onboard the Solar Dynamics Observatory (SDO) during the first 3.5 yr of its mission. In this Paper II we compute the differential emission measure (DEM) distribution functions and associated multithermal energies, using a spatially-synthesized Gaussian DEM forward-fitting method. The multithermal DEM function yields a significantly higher (by an average factor of ≈14), but more comprehensive (multi-)thermal energy than an isothermal energy estimate from the same AIA data. We find a statistical energy ratio of {{E}th}/{{E}diss} ≈ 2-40% between the multithermal energy Eth and the magnetically dissipated energy Ediss, which is an order of magnitude higher than the estimates of Emslie et al. 2012. For the analyzed set of M- and X-class flares we find the following physical parameter ranges: L={{10}8.2}{{-10}9.7} cm for the length scale of the flare areas, {{T}p}={{10}5.7}{{-10}7.4} K for the DEM peak temperature, {{T}w}={{10}6.8}{{-10}7.6} K for the emission measure-weighted temperature, {{n}p}={{10}10.3}-{{10}11.8} cm-3 for the average electron density, E{{M}p}={{10}47.3}-{{10}50.3} cm-3 for the DEM peak emission measure, and {{E}th}={{10}26.8}-{{10}32.0} erg for the multithermal energies. The deduced multithermal energies are consistent with the RTV scaling law {{E}th,RTV}=7.3× {{10}-10} Tp3Lp2, which predicts extremal values of {{E}th,max }≈ 1.5× {{10}33} erg for the largest flare and {{E}th,min }≈ 1× {{10}24} erg for the smallest coronal nanoflare. The size distributions of the spatial parameters exhibit powerlaw tails that are consistent with the predictions of the fractal-diffusive self-organized criticality model combined with the RTV scaling law.

  18. Global scenarios of urban density and its impacts on building energy use through 2050.

    PubMed

    Güneralp, Burak; Zhou, Yuyu; Ürge-Vorsatz, Diana; Gupta, Mukesh; Yu, Sha; Patel, Pralit L; Fragkias, Michail; Li, Xiaoma; Seto, Karen C

    2017-01-09

    Although the scale of impending urbanization is well-acknowledged, we have a limited understanding of how urban forms will change and what their impact will be on building energy use. Using both top-down and bottom-up approaches and scenarios, we examine building energy use for heating and cooling. Globally, the energy use for heating and cooling by the middle of the century will be between 45 and 59 exajoules per year (corresponding to an increase of 7-40% since 2010). Most of this variability is due to the uncertainty in future urban densities of rapidly growing cities in Asia and particularly China. Dense urban development leads to less urban energy use overall. Waiting to retrofit the existing built environment until markets are ready in about 5 years to widely deploy the most advanced renovation technologies leads to more savings in building energy use. Potential for savings in energy use is greatest in China when coupled with efficiency gains. Advanced efficiency makes the least difference compared with the business-as-usual scenario in South Asia and Sub-Saharan Africa but significantly contributes to energy savings in North America and Europe. Systemic efforts that focus on both urban form, of which urban density is an indicator, and energy-efficient technologies, but that also account for potential co-benefits and trade-offs with human well-being can contribute to both local and global sustainability. Particularly in growing cities in the developing world, such efforts can improve the well-being of billions of urban residents and contribute to mitigating climate change by reducing energy use in urban areas.

  19. Global scenarios of urban density and its impacts on building energy use through 2050

    PubMed Central

    Güneralp, Burak; Zhou, Yuyu; Ürge-Vorsatz, Diana; Gupta, Mukesh; Yu, Sha; Patel, Pralit L.; Fragkias, Michail; Li, Xiaoma; Seto, Karen C.

    2017-01-01

    Although the scale of impending urbanization is well-acknowledged, we have a limited understanding of how urban forms will change and what their impact will be on building energy use. Using both top-down and bottom-up approaches and scenarios, we examine building energy use for heating and cooling. Globally, the energy use for heating and cooling by the middle of the century will be between 45 and 59 exajoules per year (corresponding to an increase of 7–40% since 2010). Most of this variability is due to the uncertainty in future urban densities of rapidly growing cities in Asia and particularly China. Dense urban development leads to less urban energy use overall. Waiting to retrofit the existing built environment until markets are ready in about 5 years to widely deploy the most advanced renovation technologies leads to more savings in building energy use. Potential for savings in energy use is greatest in China when coupled with efficiency gains. Advanced efficiency makes the least difference compared with the business-as-usual scenario in South Asia and Sub-Saharan Africa but significantly contributes to energy savings in North America and Europe. Systemic efforts that focus on both urban form, of which urban density is an indicator, and energy-efficient technologies, but that also account for potential co-benefits and trade-offs with human well-being can contribute to both local and global sustainability. Particularly in growing cities in the developing world, such efforts can improve the well-being of billions of urban residents and contribute to mitigating climate change by reducing energy use in urban areas. PMID:28069957

  20. Acting Globally: Potential Carbon Emissions Mitigation Impacts from an International Standards and Labelling Program

    SciTech Connect

    McNeil, Michael A; Letschert, Virginie E.; de la Rue du Can, Stephane; Egan, Christine

    2009-05-29

    This paper presents an analysis of the potential impacts of an international initiative designed to support and promote the development and implementation of appliances standards and labelling programs throughout the world. As part of previous research efforts, LBNL developed the Bottom Up Energy Analysis System (BUENAS), an analysis framework that estimates impact potentials of energy efficiency policies on a global scale. In this paper, we apply this framework to an initiative that would result in the successful implementation of programs focused on high priority regions and product types, thus evaluating the potential impacts of such an initiative in terms of electricity savings and carbon mitigation in 2030. In order to model the likely parameters of such a program, we limit impacts to a five year period starting in 2009, but assume that the first 5 years of a program will result in implementation of 'best practice' minimum efficiency performance standards by 2014. The 'high priority' regions considered are: Brazil, China, the European Union,India, Mexico and the United States. The products considered are: refrigerators, air conditioners, lighting (both fluorescent and incandescent), standby power (for consumer electronics) and televisions in the residential sector, and air conditioning and lighting in commercial buildings. In 2020, these regions and enduses account for about 37percent of global residential electricity and 29percent of electricity in commercial buildings. We find that 850Mt of CO2 could be saved in buildings by 2030 compared to the baseline forecast.

  1. Bandwidth Study on Energy Use and Potential Energy Saving Opportunities in U.S. Chemical Manufacturing

    SciTech Connect

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. chemical manufacturing. The study relies on multiple sources to estimate the energy used in the production of 74 individual chemicals, representing 57% of sector-wide energy consumption. Energy savings opportunities for individual chemicals and for 15 subsectors of chemicals manufacturing are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  2. Bandwidth Study on Energy Use and Potential Energy Savings Opportunities in U.S. Petroleum Refining

    SciTech Connect

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy used in nine individual process areas, representing 68% of sector-wide energy consumption. Energy savings opportunities for individual processes are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  3. Energy Savings Potential and Research & Development Opportunities for Commercial Refrigeration

    SciTech Connect

    none,

    2009-09-01

    This study documents the energy consumption of commercial refrigeration equipment (CRE) in the U.S. and evaluated the energy savings potential of various technologies and energy efficiency measures that could be applied to such equipment. The study provided an overview of CRE applications, assessed the energy-savings potential of CRE in the U.S., outline key barriers to adoption of energy-savings technologies, and recommended opportunities for advanced energy saving technology research. The study was modeled after an earlier 1996 report by Arthur D. Little, Inc., and updated key information, examined more equipment types, and outlined long-term research and development opportunities.

  4. Bone and the regulation of global energy balance.

    PubMed

    Zhang, Q; Riddle, R C; Clemens, T L

    2015-06-01

    The skeleton, populated by large numbers of osteoblasts and long-lived osteocytes, requires a constant supply of energy-rich molecules to fuel the synthesis, deposition and mineralization of bone matrix during bone modelling and remodelling. When these energetic demands are not met, bone acquisition is suppressed. Recent findings suggest that key developmental signals emanating from Wnt low-density lipoprotein-related receptor 5 and hypoxia-inducible factor pathways impact osteoblast bioenergetics to accommodate the energy requirements for bone cells to fulfil their function. In vivo studies in several mutant mouse strains have confirmed a link between bone cells and global metabolism, ultimately leading to the identification of hormonal interactions between the skeleton and other tissues. The hormones insulin and leptin affect postnatal bone acquisition, whilst osteocalcin produced by the osteoblast in turn stimulates insulin secretion by the pancreas. These observations have prompted additional questions regarding the nature of the mechanisms of fuel sensing and processing in the osteoblast and their contribution to overall energy utilization and homeostasis. Answers to such questions should advance our understanding of metabolic diseases and may ultimately improve management of affected patients. In this review, we highlight recent studies in this field and offer a perspective on the evolutionary implications of bone as a metabolic endocrine organ. © 2015 The Association for the Publication of the Journal of Internal Medicine.

  5. ISTP Global Geospace Science. Energy transfer in geospace

    NASA Technical Reports Server (NTRS)

    1990-01-01

    Solar-terrestrial physics concerns the study of the generation, flow, and dissipation of mass, momentum, and energy between the Sun and the Earth. Mass, momentum, and energy are carried by charged particles that compose the solar wind. When the solar wind reaches the Earth, some solar-wind particles enter the magnetosphere; this coupling between the solar wind and the Earth means that the solar wind can influence the Earth's upper atmosphere. As the first step in addressing the behavior of this solar-terrestrial system, the Global Geospace Science (GGS) Initiative will use the Wind and Polar satellites, provided by NASA, and the Geotail satellite provided by the Japanese Institute of Space and Astronautical Science (ISAS), to perform simultaneous and closely coordinated measurements of the key geospace regions and will add data from equatorial missions. Magnetic field and particle changes that occur when particles are energized during auroral events will be monitored. The intention behind the GGS Initiative is to understand the physical mechanisms and various regions controlling the transport of mass, momentum, and energy in geospace. A summary of the GGS Initiative is presented.

  6. Thinking Globally, Siting Locally: Renewable Energy and Biodiversity in a 4C World

    NASA Astrophysics Data System (ADS)

    Allison, T.; Frumhoff, P. C.; Root, T.

    2012-12-01

    The continued rise of greenhouse gas emissions and limited progress toward a low-carbon global-energy economy puts increases of global average temperatures on a course to reach 3C - 4C within this century. Such temperature increases are projected to have devastating impacts on biodiversity and ecosystems in the United States, and globally. At an increase of 4C, for example, the Intergovernmental Panel on Climate Change (IPCC) estimates that ~ 50% of recognized species could be committed to extinction. Limiting the magnitude of warming well below these levels will require massive shifts in energy production, including the rapid and large-scale deployment of renewable energy. The National Renewable Energy Laboratory (NREL) estimates that generating 80% of US electricity from renewable energy by 2050 would reduce cumulative US emissions (2011-2050) from the power sector by more than 40 Gt C02e, or 41%, and reduce annual emissions from the US power sector by nearly 81% by 2050. But the expansion of renewable energy at this scale will have impacts on biodiversity and ecosystem function, affecting ~3 % of US land area for siting, transmission and storage. Concerns over impacts to vulnerable species and their habitats are a source of delay in and opposition to renewable energy siting, particularly for wind and concentrated solar. Efforts to expedite renewable energy expansion while protecting biodiversity need to factor in both the direct biodiversity risks of siting and transmission and the benefits of avoided emissions on reducing the global biodiversity risks of high magnitude warming. Toward this end, we describe a combination of research, outreach, and dialogue designed to help policymakers and stakeholders (1) promote efforts to strategically locate renewable energy projects where impacts to species potentially vulnerable to deployment and operation of renewable energy could be avoided or minimized; (2) recognize the inherent uncertainty in characterizing siting

  7. Optofluidic opportunities in global health, food, water and energy

    NASA Astrophysics Data System (ADS)

    Chen, Yih-Fan; JiangLj, Mm, Aj,; Vo Contributed Equally To This Paper., Li; Mancuso, Matthew; Jain, Aadhar; Oncescu, Vlad; Erickson, David

    2012-07-01

    Optofluidics is a rapidly advancing field that utilizes the integration of optics and microfluidics to provide a number of novel functionalities in microsystems. In this review, we discuss how this approach can potentially be applied to address some of the greatest challenges facing both the developing and developed world, including healthcare, food shortages, malnutrition, water purification, and energy. While medical diagnostics has received most of the attention to date, here we show that some other areas can also potentially benefit from optofluidic technology. Whenever possible we briefly describe how microsystems are currently used to address these problems and then explain why and how optofluidics can provide better solutions. The focus of the article is on the applications of optofluidic techniques in low-resource settings, but we also emphasize that some of these techniques, such as those related to food production, food safety assessment, nutrition monitoring, and energy production, could be very useful in well-developed areas as well.

  8. Wood Energy Potential in Northwestern South Carolina

    Treesearch

    James W. McMinn

    1986-01-01

    The quantity of unused wood in an Ill-county area in northwestern South Carolina was projected to be more than 16 million tons annually. Wood that is unsuitable for products other than fuel amounts to nearly 9 million tons annually.The most likely energy demand by industrial plants that are good candidates for wood fuel systems is 1.5 million tons annually.Maximum...

  9. Classification of global phase portraits and bifurcation diagrams of Hamiltonian systems with rational potential

    NASA Astrophysics Data System (ADS)

    Martínez, Y. P.; Vidal, C.

    2016-12-01

    In this paper we study the global dynamics of the Hamiltonian systems x ˙ =Hy (x , y), y ˙ = -Hx (x , y), where the Hamiltonian function H has the particular form H (x , y) =y2 / 2 + P (x) / Q (x), P (x) , Q (x) ∈ R [ x ] are polynomials, in particular H is the sum of the kinetic and a rational potential energies. Firstly, we provide the normal forms by a suitable μ-symplectic change of variables. Then, the global topological classification of the phase portraits of these systems having canonical forms in the Poincaré disk in the cases where degree (P) = 0 , 1 , 2 and degree (Q) = 0 , 1 , 2 are studied as a function of the parameters that define each polynomial. We use a blow-up technique for finite equilibrium points and the Poincaré compactification for the infinite equilibrium points. Finally, we show some applications.

  10. Potential flux landscapes determine the global stability of a Lorenz chaotic attractor under intrinsic fluctuations

    NASA Astrophysics Data System (ADS)

    Li, Chunhe; Wang, Erkang; Wang, Jin

    2012-05-01

    We developed a potential flux landscape theory to investigate the dynamics and the global stability of a chemical Lorenz chaotic strange attractor under intrinsic fluctuations. Landscape was uncovered to have a butterfly shape. For chaotic systems, both landscape and probabilistic flux are crucial to the dynamics of chaotic oscillations. Landscape attracts the system down to the chaotic attractor, while flux drives the coherent motions along the chaotic attractors. Barrier heights from the landscape topography provide a quantitative measure for the robustness of chaotic attractor. We also found that the entropy production rate and phase coherence increase as the molecular numbers increase. Power spectrum analysis of autocorrelation function provides another way to quantify the global stability of chaotic attractor. We further found that limit cycle requires more flux and energy to sustain than the chaotic strange attractor. Finally, by detailed analysis we found that the curl probabilistic flux may provide the origin of the chaotic attractor.

  11. Framework for State-Level Renewable Energy Market Potential Studies

    EPA Pesticide Factsheets

    This document provides a framework and next steps for state officials who require estimates of renewable energy market potential. The report gives insight into how to conduct a market potential study.

  12. Potential production of energy cane for fuel in the Caribbean

    SciTech Connect

    Samuels, G.

    1984-12-01

    Sugarcane presents a tremendous potential as a renewable energy source for the non-oil producing countries of the Caribbean. The energy cane concept is sugarcane managed for maximum dry matter (total fermentable solids for alcohol fuel and combustible solids for electricity) rather than sucrose. The use of sugarcane as a renewable energy source can provide a solution, either partial or total, to the Caribbean energy problem. Sugar cane production and the use of this crop as a renewable energy source are described.

  13. Potential impact of contrails on solar energy gain

    NASA Astrophysics Data System (ADS)

    Weihs, P.; Rennhofer, M.; Baumgartner, D.; Gadermaier, J.; Wagner, J.; Laube, W.

    2014-08-01

    We investigated the effect of contrails on global shortwave radiation and on solar energy gain. The study was done for days with a high contrail persistence and looking at situations where the contrails were obstructing the sun. Measurements of cloudiness using a fish eye camera, diffuse and direct shortwave measurements and measurements of the short circuit current of three different types of photovoltaic (PV) modules were performed at the solar observatory Kanzelhöhe (1540 m a.s.l.) during a period of one year with a time resolution of one minute. Our results show that contrails moving between sun and observer/sensor may reduce the global radiation by up to 72%. A statistic of contrail persistence and influence of contrails on global irradiance and solar energy gain is presented. The losses in solar energy gain that were recorded may even be critical under some circumstances for PV system performance.

  14. Potential impact of contrails on solar energy gain

    NASA Astrophysics Data System (ADS)

    Weihs, P.; Rennhofer, M.; Baumgartner, D. J.; Gadermaier, J.; Wagner, J. E.; Gehring, J. E.; Laube, W.

    2015-03-01

    The effect of contrails on global short-wave radiation (sum of direct and downward diffuse solar radiation) and on solar energy gain was investigated. The study was performed during days with high contrail persistence and focused on situations where the contrails were obstructing the sun. Measurements of cloudiness using a fish-eye camera, diffuse and direct short-wave measurements and measurements of the short circuit current of three different types of photovoltaic (PV) modules were performed at the Kanzelhöhe Observatory (1540 m a.s.l.) with a time resolution of 1 min over a period of 1 year. The results show that contrails moving between sun and observer/sensor may reduce the global radiation by up to 72%. An analysis of contrail persistence and the influence of contrails on global irradiance and solar energy gain is presented. The losses in solar energy gain that were recorded may be critical under specific circumstances.

  15. The global mean energy balance under cloud-free conditions

    NASA Astrophysics Data System (ADS)

    Wild, Martin; Hakuba, Maria; Folini, Dois; Ott, Patricia; Long, Charles

    2017-04-01

    är, C., Loeb, N., Dutton, E.G., and König-Langlo, G., 2013: The global energy balance from a surface perspective. Climate Dynamics, 40, 3107-3134. Wild, M., Folini, D., Hakuba, M., Schär, C., Seneviratne, S.I., Kato, S., Rutan, D., Ammann, C., Wood, E.F., and König-Langlo, G., 2015: The energy balance over land and oceans: An assessment based on direct observations and CMIP5 climate models, Climate Dynamics, 3393-3429, 44, DOI 10.1007/s00382-014-2430-z.

  16. Global Responses to Potential Climate Change: A Simulation.

    ERIC Educational Resources Information Center

    Williams, Mary Louise; Mowry, George

    This interdisciplinary five-day unit provides students with an understanding of the issues in the debate on global climate change. Introductory lessons enhance understanding of the "greenhouse gases" and their sources with possible global effects of climate change. Students then roleplay negotiators from 10 nations in a simulation of the…

  17. Global Responses to Potential Climate Change: A Simulation.

    ERIC Educational Resources Information Center

    Williams, Mary Louise; Mowry, George

    This interdisciplinary five-day unit provides students with an understanding of the issues in the debate on global climate change. Introductory lessons enhance understanding of the "greenhouse gases" and their sources with possible global effects of climate change. Students then roleplay negotiators from 10 nations in a simulation of the…

  18. Potential Energy Sources Pose Mining Problem

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1974

    1974-01-01

    Summarizes the discussions of a Division of Industrial and Engineering Chemistry symposium on solids handling for synthetic fuels production. Included is a description of technical difficulties with the use of coal seams and deposits of oil shale and oil sand as potential sources of fuel. (CC)

  19. Potential Energy Sources Pose Mining Problem

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1974

    1974-01-01

    Summarizes the discussions of a Division of Industrial and Engineering Chemistry symposium on solids handling for synthetic fuels production. Included is a description of technical difficulties with the use of coal seams and deposits of oil shale and oil sand as potential sources of fuel. (CC)

  20. Dependency of global primary bioenergy crop potentials in 2050 on food systems, yields, biodiversity conservation and political stability.

    PubMed

    Erb, Karl-Heinz; Haberl, Helmut; Plutzar, Christoph

    2012-08-01

    The future bioenergy crop potential depends on (1) changes in the food system (food demand, agricultural technology), (2) political stability and investment security, (3) biodiversity conservation, (4) avoidance of long carbon payback times from deforestation, and (5) energy crop yields. Using a biophysical biomass-balance model, we analyze how these factors affect global primary bioenergy potentials in 2050. The model calculates biomass supply and demand balances for eleven world regions, eleven food categories, seven food crop types and two livestock categories, integrating agricultural forecasts and scenarios with a consistent global land use and NPP database. The TREND scenario results in a global primary bioenergy potential of 77 EJ/yr, alternative assumptions on food-system changes result in a range of 26-141 EJ/yr. Exclusion of areas for biodiversity conservation and inaccessible land in failed states reduces the bioenergy potential by up to 45%. Optimistic assumptions on future energy crop yields increase the potential by up to 48%, while pessimistic assumptions lower the potential by 26%. We conclude that the design of sustainable bioenergy crop production policies needs to resolve difficult trade-offs such as food vs. energy supply, renewable energy vs. biodiversity conservation or yield growth vs. reduction of environmental problems of intensive agriculture.

  1. Dependency of global primary bioenergy crop potentials in 2050 on food systems, yields, biodiversity conservation and political stability

    PubMed Central

    Erb, Karl-Heinz; Haberl, Helmut; Plutzar, Christoph

    2012-01-01

    The future bioenergy crop potential depends on (1) changes in the food system (food demand, agricultural technology), (2) political stability and investment security, (3) biodiversity conservation, (4) avoidance of long carbon payback times from deforestation, and (5) energy crop yields. Using a biophysical biomass-balance model, we analyze how these factors affect global primary bioenergy potentials in 2050. The model calculates biomass supply and demand balances for eleven world regions, eleven food categories, seven food crop types and two livestock categories, integrating agricultural forecasts and scenarios with a consistent global land use and NPP database. The TREND scenario results in a global primary bioenergy potential of 77 EJ/yr, alternative assumptions on food-system changes result in a range of 26–141 EJ/yr. Exclusion of areas for biodiversity conservation and inaccessible land in failed states reduces the bioenergy potential by up to 45%. Optimistic assumptions on future energy crop yields increase the potential by up to 48%, while pessimistic assumptions lower the potential by 26%. We conclude that the design of sustainable bioenergy crop production policies needs to resolve difficult trade-offs such as food vs. energy supply, renewable energy vs. biodiversity conservation or yield growth vs. reduction of environmental problems of intensive agriculture. PMID:23576836

  2. Classical trajectory studies of gas phase reaction dynamics and kinetics using ab initio potential energy surfaces

    NASA Technical Reports Server (NTRS)

    Jaffe, Richard L.; Pattengill, Merle D.; Schwenke, David W.

    1989-01-01

    Strategies for constructing global potential energy surfaces from a limited number of accurate ab initio electronic energy calculations are discussed. Generally, these data are concentrated in small regions of configuration space (e.g., in the vicinity of saddle points and energy minima) and difficulties arise in generating a potential function that is globally well-behaved. Efficient computer codes for carrying out classical trajectory calculations on vector and parallel processors are also described. Illustrations are given from recent work on the following chemical systems: Ca + HF yields CaF + H, H + H + H2 yields H2 + H2, N + O2 yields NO + O and O + N2 yields NO + N. The dynamics and kinetics of metathesis, dissociation, recombination, energy transfer and complex formation processes will be discussed.

  3. Classical trajectory studies of gas phase reaction dynamics and kinetics using ab initio potential energy surfaces

    NASA Technical Reports Server (NTRS)

    Jaffe, Richard L.; Pattengill, Merle D.; Schwenke, David W.

    1989-01-01

    Strategies for constructing global potential energy surfaces from a limited number of accurate ab initio electronic energy calculations are discussed. Generally, these data are concentrated in small regions of configuration space (e.g., in the vicinity of saddle points and energy minima) and difficulties arise in generating a potential function that is globally well-behaved. Efficient computer codes for carrying out classical trajectory calculations on vector and parallel processors are also described. Illustrations are given from recent work on the following chemical systems: Ca + HF yields CaF + H, H + H + H2 yields H2 + H2, N + O2 yields NO + O and O + N2 yields NO + N. The dynamics and kinetics of metathesis, dissociation, recombination, energy transfer and complex formation processes will be discussed.

  4. Global Surface Temperature Response Explained by Multibox Energy Balance Models

    NASA Astrophysics Data System (ADS)

    Fredriksen, H. B.; Rypdal, M.

    2016-12-01

    We formulate a multibox energy balance model, from which global temperature evolution can be described by convolving a linear response function and a forcing record. We estimate parameters in the response function from instrumental data and historic forcing, such that our model can produce a response to both deterministic forcing and stochastic weather forcing consistent with observations. Furthermore, if we make separate boxes for upper ocean layer and atmosphere over land, we can also make separate response functions for global land and sea surface temperature. By describing internal variability as a linear response to white noise, we demonstrate that the power-law form of the observed temperature spectra can be described by linear dynamics, contrary to a common belief that these power-law spectra must arise from nonlinear processes. In our multibox model, the power-law form can arise due to the multiple response times. While one of our main points is that the climate system responds over a wide range of time scales, we cannot find one set of time scales that can be preferred compared to other choices. Hence we think the temperature response can best be characterized as something that is scale-free, but still possible to approximate by a set of well separated time scales.

  5. The global nephrology workforce: emerging threats and potential solutions!

    PubMed

    Sharif, Muhammad U; Elsayed, Mohamed E; Stack, Austin G

    2016-02-01

    Amidst the rising tide of chronic kidney disease (CKD) burden, the global nephrology workforce has failed to expand in order to meet the growing healthcare needs of this vulnerable patient population. In truth, this shortage of nephrologists is seen in many parts of the world, including North America, Europe, Australia, New Zealand, Asia and the African continent. Moreover, expert groups on workforce planning as well as national and international professional organizations predict further reductions in the nephrology workforce over the next decade, with potentially serious implications. Although the full impact of this has not been clearly articulated, what is clear is that the delivery of care to patients with CKD may be threatened in many parts of the world unless effective country-specific workforce strategies are put in place and implemented. Multiple factors are responsible for this apparent shortage in the nephrology workforce and the underpinning reasons may vary across health systems and countries. Potential contributors include the increasing burden of CKD, aging workforce, declining interest in nephrology among trainees, lack of exposure to nephrology among students and residents, rising cost of medical education and specialist training, increasing cultural and ethnic disparities between patients and care providers, increasing reliance on foreign medical graduates, inflexible work schedules, erosion of nephrology practice scope by other specialists, inadequate training, reduced focus on scholarship and research funds, increased demand to meet quality of care standards and the development of new care delivery models. It is apparent from this list that the solution is not simple and that a comprehensive evaluation is required. Consequently, there is an urgent need for all countries to develop a policy framework for the provision of kidney disease services within their health systems, a framework that is based on accurate projections of disease burden, a

  6. The global nephrology workforce: emerging threats and potential solutions!

    PubMed Central

    Sharif, Muhammad U.; Elsayed, Mohamed E.; Stack, Austin G.

    2016-01-01

    Amidst the rising tide of chronic kidney disease (CKD) burden, the global nephrology workforce has failed to expand in order to meet the growing healthcare needs of this vulnerable patient population. In truth, this shortage of nephrologists is seen in many parts of the world, including North America, Europe, Australia, New Zealand, Asia and the African continent. Moreover, expert groups on workforce planning as well as national and international professional organizations predict further reductions in the nephrology workforce over the next decade, with potentially serious implications. Although the full impact of this has not been clearly articulated, what is clear is that the delivery of care to patients with CKD may be threatened in many parts of the world unless effective country-specific workforce strategies are put in place and implemented. Multiple factors are responsible for this apparent shortage in the nephrology workforce and the underpinning reasons may vary across health systems and countries. Potential contributors include the increasing burden of CKD, aging workforce, declining interest in nephrology among trainees, lack of exposure to nephrology among students and residents, rising cost of medical education and specialist training, increasing cultural and ethnic disparities between patients and care providers, increasing reliance on foreign medical graduates, inflexible work schedules, erosion of nephrology practice scope by other specialists, inadequate training, reduced focus on scholarship and research funds, increased demand to meet quality of care standards and the development of new care delivery models. It is apparent from this list that the solution is not simple and that a comprehensive evaluation is required. Consequently, there is an urgent need for all countries to develop a policy framework for the provision of kidney disease services within their health systems, a framework that is based on accurate projections of disease burden, a

  7. Global scale energy budget contrast between warm and cold years

    NASA Astrophysics Data System (ADS)

    Lembo, Valerio; Lionello, Piero

    2014-05-01

    This contribution analyses changes to the energy budget of the troposphere associated to global warm anomalies of the Earth surface temperature. This is important for understanding the dynamics of climate change. A phenomenological approach is adopted, comparing coldest and warmest years over the last century. Data are provided by the results of 10 simulations carried out within the ERA-20CM experiment and covering the period 1900-2010. This ensemble is forced by 10 perturbed realizations of SST fields and greenhouse gases concentration time series. Analysis considers the annual mean meridional distribution of zonal mean tropospheric and surface temperature, net downward solar radiation at top of atmosphere and Earth surface, surface heat flux (SHF), consisting of net longwave upward radiation, latent heat and sensible heat vertical fluxes, and outgoing longwave radiation at top of atmosphere (OLR). Differences of these variables between the warmest and coldest years are computed, in order to analyze how the energy budget of the atmosphere is associated to the warming the Earth surface. During warm years, it is observed that tropospheric warming occurs at all latitudes, decreasing at its top, being rather uniform but larger/smaller around the North/South Pole than at the tropics. This is consistent with the overall increase of OLR at all latitudes. Shortwave absorption in the troposphere increases, with a peak around 30 degrees north, as a result of increased net downward solar radiation at the top. The warming of the surface is associated with reduced SHF almost everywhere, particularly at higher latitudes. This combined effect might be interpreted as a reduction of solar reflection by cloud cover and an increased moisture in the lower troposphere, inhibiting evaporation and heat fluxes from the surface, and increasing downward flow of longwave radiation to the surface. Finally, the meridional distribution of residual net energy budget in the troposphere suggests

  8. Modeling global macroclimatic constraints on ectotherm energy budgets

    SciTech Connect

    Grant, B.W.; Porter, W.P.

    1992-12-31

    The authors describe a mechanistic individual-based model of how global macroclimatic constraints affect the energy budgets of ectothermic animals. The model uses macroclimatic and biophysical characters of the habitat and organism and tenets of heat transfer theory to calculate hourly temperature availabilities over a year. Data on the temperature dependence of activity rate, metabolism, food consumption and food processing capacity are used to estimate the net rate of resource assimilation which is then integrated over time. They present a new test of this model in which they show that the predicted energy budget sizes for 11 populations of the lizard Sceloporus undulates are in close agreement with observed results from previous field studies. This demonstrates that model tests rae feasible and the results are reasonable. Further, since the model represents an upper bound to the size of the energy budget, observed residual deviations form explicit predictions about the effects of environmental constraints on the bioenergetics of the study lizards within each site that may be tested by future field and laboratory studies. Three major new improvements to the modeling are discussed. They present a means to estimate microclimate thermal heterogeneity more realistically and include its effects on field rates of individual activity and food consumption. Second, they describe an improved model of digestive function involving batch processing of consumed food. Third, they show how optimality methods (specifically the methods of stochastic dynamic programming) may be included to model the fitness consequences of energy allocation decisions subject to food consumption and processing constraints which are predicted from the microclimate and physiological modeling.

  9. Energy and global warming impacts of HFC refrigerants and emerging technologies: TEWI-III

    SciTech Connect

    Sand, J.R.; Fischer, S.K.; Baxter, V.D.

    1997-06-01

    The use of hydrofluorocarbons (BFCs) which were developed as alternative refrigerants and insulating foam blowing agents to replace chlorofluorocarbons (CFCs) is now being affected by scientific investigations of greenhouse warming and questions about the effects of refrigerants and blowing agents on global warming. A Total Equivalent Warming Impact (TEWI) assessment analyzes the environmental affects of these halogenated working fluids in energy consuming applications by combining a direct effect resulting from the inadvertent release of HFCs to the atmosphere with an indirect effect resulting from the combustion of fossil fuels needed to provide the energy to operate equipment using these compounds as working fluids. TEWI is a more balanced measure of environmental impact because it is not based solely on the global warming potential (GWP) of the working fluid. It also shows the environmental benefit of efficient technologies that result in less CO{sub 2} generation and eventual emission to the earth`s atmosphere. The goal of TEWI is to assess total global warming impact of all the gases released to the atmosphere, including CO{sub 2} emissions from energy conversion. Alternative chemicals and technologies have been proposed as substitutes for HFCs in the vapor-compression cycle for refrigeration and air conditioning and for polymer foams in appliance and building insulations which claim substantial environmental benefits. Among these alternatives are: (1) Hydrocarbon (HC) refrigerants and blowing agents which have zero ozone depleting potential and a negligible global warming potential, (2) CO{sub 2} as a refrigerant and blowing agent, (3) Ammonia (NH{sub 3}) vapor compression systems, (4) Absorption chiller and heat pumping cycles using ammonia/water or lithium bromide/water, and (5) Evacuated panel insulations. This paper summarizes major results and conclusions of the detailed final report on the TEWI-111 study.

  10. A GLOBAL ASSESSMENT OF SOLAR ENERGY RESOURCES: NASA's Prediction of Worldwide Energy Resources (POWER) Project

    NASA Astrophysics Data System (ADS)

    Zhang, T.; Stackhouse, P. W., Jr.; Chandler, W.; Hoell, J. M.; Westberg, D.; Whitlock, C. H.

    2010-12-01

    NASA's POWER project, or the Prediction of the Worldwide Energy Resources project, synthesizes and analyzes data on a global scale. The products of the project find valuable applications in the solar and wind energy sectors of the renewable energy industries. The primary source data for the POWER project are NASA's World Climate Research Project (WCRP)/Global Energy and Water cycle Experiment (GEWEX) Surface Radiation Budget (SRB) project (Release 3.0) and the Global Modeling and Assimilation Office (GMAO) Goddard Earth Observing System (GEOS) assimilation model (V 4.0.3). Users of the POWER products access the data through NASA's Surface meteorology and Solar Energy (SSE, Version 6.0) website (http://power.larc.nasa.gov). Over 200 parameters are available to the users. The spatial resolution is 1 degree by 1 degree now and will be finer later. The data covers from July 1983 to December 2007, a time-span of 24.5 years, and are provided as 3-hourly, daily and monthly means. As of now, there have been over 18 million web hits and over 4 million data file downloads. The POWER products have been systematically validated against ground-based measurements, and in particular, data from the Baseline Surface Radiation Network (BSRN) archive, and also against the National Solar Radiation Data Base (NSRDB). Parameters such as minimum, maximum, daily mean temperature and dew points, relative humidity and surface pressure are validated against the National Climate Data Center (NCDC) data. SSE feeds data directly into Decision Support Systems including RETScreen International clean energy project analysis software that is written in 36 languages and has greater than 260,000 users worldwide.

  11. Ab initio potential energy surface for the highly nonlinear dynamics of the KCN molecule

    SciTech Connect

    Párraga, H.; Arranz, F. J. Benito, R. M.; Borondo, F.

    2013-11-21

    An accurate ab initio quantum chemistry study at level of quadratic configuration interaction method of the electronic ground state of the KCN molecule is presented. A fitting of the results to an analytical series expansion was performed to obtain a global potential energy surface suitable for the study of the associated vibrational dynamics. Additionally, classical Poincaré surfaces of section for different energies and quantum eigenstates were calculated, showing the highly nonlinear behavior of this system.

  12. Structuring energy supply and demand networks in a general equilibrium model to simulate global warming control strategies

    SciTech Connect

    Hamilton, S.; Veselka, T.D.; Cirillo, R.R.

    1991-01-01

    Global warming control strategies which mandate stringent caps on emissions of greenhouse forcing gases can substantially alter a country's demand, production, and imports of energy products. Although there is a large degree of uncertainty when attempting to estimate the potential impact of these strategies, insights into the problem can be acquired through computer model simulations. This paper presents one method of structuring a general equilibrium model, the ENergy and Power Evaluation Program/Global Climate Change (ENPEP/GCC), to simulate changes in a country's energy supply and demand balance in response to global warming control strategies. The equilibrium model presented in this study is based on the principle of decomposition, whereby a large complex problem is divided into a number of smaller submodules. Submodules simulate energy activities and conversion processes such as electricity production. These submodules are linked together to form an energy supply and demand network. Linkages identify energy and fuel flows among various activities. Since global warming control strategies can have wide reaching effects, a complex network was constructed. The network represents all energy production, conversion, transportation, distribution, and utilization activities. The structure of the network depicts interdependencies within and across economic sectors and was constructed such that energy prices and demand responses can be simulated. Global warming control alternatives represented in the network include: (1) conservation measures through increased efficiency; and (2) substitution of fuels that have high greenhouse gas emission rates with fuels that have lower emission rates. 6 refs., 4 figs., 4 tabs.

  13. The Energy Efficiency Potential of Cloud-Based Software: A U.S. Case Study

    SciTech Connect

    Masanet, Eric; Shehabi, Arman; Liang, Jiaqi; Ramakrishnan, Lavanya; Ma, XiaoHui; Hendrix, Valerie; Walker, Benjamin; Mantha, Pradeep

    2013-06-03

    The energy use of data centers is a topic that has received much attention, given that data centers currently account for 1-2% of global electricity use. However, cloud computing holds great potential to reduce data center energy demand moving forward, due to both large reductions in total servers through consolidation and large increases in facility efficiencies compared to traditional local data centers. However, analyzing the net energy implications of shifts to the cloud can be very difficult, because data center services can affect many different components of society’s economic and energy systems.

  14. Comparison of global phenomenological and microscopic optical potentials for nuclear data predictions

    SciTech Connect

    Cai, C. ); Shen, Q.; Zhuo, Y. )

    1991-10-01

    In this paper the chi-square ({chi}{sup 2}) values, which represent the degree of agreement between the calculated total, nonelastic, and differential elastic cross sections and their experimental values, are calculated for seven kinds of optical potentials: the phenomenological optimal optical potential (OOP) for a specific element, the global phenomenological optical potentials given by Becchetti and Greenlees (BGP) and by Varner et al. (CH86) for a large number of target nuclei, and the microscopic optical potentials based on conventional Skyrme force (SII and SIII), generalized Skyrme force (GS2), and modified Skyrme force (SKa). Fourteen natural elements (each containing one to four isotopes) are calculated with 12 to 20 neutron incident energies, which are in the 0.1- to 24-MeV energy region for each element. The calculated average total chi-square values are {bar {chi}}{sub OOP}{sup 2} - 0.309, {bar {chi}}{sub BGP}{sup 2} = 0.807, {bar {chi}}{sub CH86}{sup 2} = 0.684, {bar {chi}}{sub GS2}{sup 2} = 0.600, {bar {chi}}{sub SKa}{sup 2} = 0.646, {bar {chi}}{sub SII}{sup 2} = 2.587, and {bar {chi}}{sub SIII}{sup 2} = 1.368. The conclusion is that the microscopic optical potential based on generalized and modified Skyrme force (GS2 and SKa), which has an analytical formalism without any free parameters, is useful in nuclear data calculation and evaluation.

  15. Global capacity, potentials and trends of solid waste research and management.

    PubMed

    Nwachukwu, Michael A; Ronald, Mersky; Feng, Huan

    2017-09-01

    In this study, United States, China, India, United Kingdom, Nigeria, Egypt, Brazil, Italy, Germany, Taiwan, Australia, Canada and Mexico were selected to represent the global community. This enabled an overview of solid waste management worldwide and between developed and developing countries. These are countries that feature most in the International Conference on Solid Waste Technology and Management (ICSW) over the past 20 years. A total of 1452 articles directly on solid waste management and technology were reviewed and credited to their original country of research. Results show significant solid waste research potentials globally, with the United States leading by 373 articles, followed by India with 230 articles. The rest of the countries are ranked in the order of: UK > Taiwan > Brazil > Nigeria > Italy > Japan > China > Canada > Germany >Mexico > Egypt > Australia. Global capacity in solid waste management options is in the order of: Waste characterisation-management > waste biotech/composting > waste to landfill > waste recovery/reduction > waste in construction > waste recycling > waste treatment-reuse-storage > waste to energy > waste dumping > waste education/public participation/policy. It is observed that the solid waste research potential is not a measure of solid waste management capacity. The results show more significant research impacts on solid waste management in developed countries than in developing countries where economy, technology and society factors are not strong. This article is targeted to motivate similar study in each country, using solid waste research articles from other streamed databases to measure research impacts on solid waste management.

  16. Achieving wood energy potentials: evidence in northeastern Minnesota.

    Treesearch

    Dennis P. Bradley; David C. Lothner

    1987-01-01

    A study of wood energy potential in northeastern Minnesota concludes that (1) the forests of the region could support a much larger wood energy harvest without significant cost increases for other forest products; (2) existing stands are predominantly overmature and cutting more now will enhance future wood supplies for all users; (3) converting to wood energy could...

  17. Digital Global Map of Potential Ocean Paleoshorelines on Mars

    NASA Astrophysics Data System (ADS)

    Parker, T. J.; Calef, F. J.

    2012-05-01

    Our objective is to compile a global shoreline map, in the form of GIS shapefiles. This map will be used to investigate deviations from horizontal that might indicate neotectonic changes such as mass accumulations and crustal deformations over time.

  18. Potential energy changes and the Boussinesq approximation in stratified fluids

    NASA Astrophysics Data System (ADS)

    Seshadri, K.; Rottman, J. W.; Nomura, K. K.; Stretch, D. D.

    2002-11-01

    The evolution of the potential energy of an ideal binary fluid mixture that is initially stably stratified is re-examined. The initial stable stratification evolves to a state of uniform density under the influence of molecular diffusion. We derive the appropriate governing equations using either a mass-averaged or a volume-averaged definition of velocity, and develop an energy budget describing the changes between kinetic, potential and internal energies without invoking the Boussinesq approximation. We compare the energy evolution equations with those based on the commonly used Boussinesq approximation and clarify some subtleties associated with the exchanges between the different forms of energy in this problem. In particular, we show that the mass-averaged velocity is nonzero and that all of the increase in potential energy comes from the initial kinetic energy.

  19. ENERGY INVESTMENTS UNDER CLIMATE POLICY: A COMPARISON OF GLOBAL MODELS

    SciTech Connect

    McCollum, David; Nagai, Yu; Riahi, Keywan; Marangoni, Giacomo; Calvin, Katherine V.; Pietzcker, Robert; Van Vliet, Jasper; van der Zwaan, Bob

    2013-11-01

    The levels of investment needed to mobilize an energy system transformation and mitigate climate change are not known with certainty. This paper aims to inform the ongoing dialogue and in so doing to guide public policy and strategic corporate decision making. Within the framework of the LIMITS integrated assessment model comparison exercise, we analyze a multi-IAM ensemble of long-term energy and greenhouse gas emissions scenarios. Our study provides insight into several critical but uncertain areas related to the future investment environment, for example in terms of where capital expenditures may need to flow regionally, into which sectors they might be concentrated, and what policies could be helpful in spurring these financial resources. We find that stringent climate policies consistent with a 2°C climate change target would require a considerable upscaling of investments into low-carbon energy and energy efficiency, reaching approximately $45 trillion (range: $30–$75 trillion) cumulative between 2010 and 2050, or about $1.1 trillion annually. This represents an increase of some $30 trillion ($10–$55 trillion), or $0.8 trillion per year, beyond what investments might otherwise be in a reference scenario that assumes the continuation of present and planned emissions-reducing policies throughout the world. In other words, a substantial "clean-energy investment gap" of some $800 billion/yr exists — notably on the same order of magnitude as present-day subsidies for fossil energy and electricity worldwide ($523 billion). Unless the gap is filled rather quickly, the 2°C target could potentially become out of reach.

  20. Assessing the potential global extent of SWOT river discharge observations

    NASA Astrophysics Data System (ADS)

    Pavelsky, Tamlin M.; Durand, Michael T.; Andreadis, Konstantinos M.; Beighley, R. Edward; Paiva, Rodrigo C. D.; Allen, George H.; Miller, Zachary F.

    2014-11-01

    Despite its importance as a major element of the global hydrologic cycle, runoff remains poorly constrained except at the largest spatial scales due to limitations of the global stream gauge network and inadequate data sharing. Efforts using remote sensing to infer runoff from discharge estimates are limited by characteristics of present-day sensors. The proposed Surface Water and Ocean Topography (SWOT) mission, a joint project between the United States and France, aims to substantially improve space-based estimates of river discharge. However, the extent of rivers observable by SWOT, likely limited to those wider than 50-100 m, remains unknown. Here, we estimate the extent of SWOT river observability globally using a downstream hydraulic geometry (DHG) approach combining basin areas from the Hydro1k and Hydrosheds elevation products, discharge from the Global Runoff Data Centre (GRDC), and width estimates from a global width-discharge relationship. We do not explicitly consider SWOT-specific errors associated with layover and other phenomena in this analysis, although they have been considered in formulation of the 50-100 m width thresholds. We compare the extent of SWOT-observable rivers with GRDC and USGS gauge datasets, the most complete datasets freely available to the global scientific community. In the continental US, SWOT would match USGS river basin coverage only at large scales (>25,000 km2). Globally, SWOT would substantially improve on GRDC observation extent: SWOT observation of 100 m (50 m) rivers will allow discharge estimation in >60% of 50,000 km2 (10,000 km2) river basins. In contrast, the GRDC observes fewer than 30% (15%) of these basins. SWOT could improve characterization of global runoff processes, especially with a 50 m observability threshold, but in situ gauge data remains essential and must be shared more freely with the international scientific community.

  1. The Potential for Space Intervention in Global Catastrophes

    NASA Astrophysics Data System (ADS)

    Hempsell, C. M.

    There is growing understanding of the risks that mankind faces on a global scale. These range from extinction level events down to disasters, which kill a few percent of the global population. Studies of prehistory and history show naturally induced events have occurred in the past and to this must be added risks created by mankind's activities. After considering the possible events, it is shown that space policy needs to focus on the intermediate level events which are classified as “global catastrophes” and which are defined as events that kill at least a quarter the global population. A safety policy approach is then used to address the degree to which space capability can provide an effective response to the threat of global catastrophe. It is found that there are several possible space systems that could either prevent, or control or provide escape safe havens, but all require a significant improvement of the space infrastructure in terms of size and improved economics to make them viable. It is concluded addressing the threat of global catastrophe should be the prime focus of space infrastructure policy.

  2. Impact of management strategies on the global warming potential at the cropping system level.

    PubMed

    Goglio, Pietro; Grant, Brian B; Smith, Ward N; Desjardins, Raymond L; Worth, Devon E; Zentner, Robert; Malhi, Sukhdev S

    2014-08-15

    Estimating the greenhouse gas (GHG) emissions from agricultural systems is important in order to assess the impact of agriculture on climate change. In this study experimental data supplemented with results from a biophysical model (DNDC) were combined with life cycle assessment (LCA) to investigate the impact of management strategies on global warming potential of long-term cropping systems at two locations (Breton and Ellerslie) in Alberta, Canada. The aim was to estimate the difference in global warming potential (GWP) of cropping systems due to N fertilizer reduction and residue removal. Reducing the nitrogen fertilizer rate from 75 to 50 kg N ha(-1) decreased on average the emissions of N2O by 39%, NO by 59% and ammonia volatilisation by 57%. No clear trend for soil CO2 emissions was determined among cropping systems. When evaluated on a per hectare basis, cropping systems with residue removal required 6% more energy and had a little change in GWP. Conversely, when evaluated on the basis of gigajoules of harvestable biomass, residue removal resulted in 28% less energy requirement and 33% lower GWP. Reducing nitrogen fertilizer rate resulted in 18% less GWP on average for both functional units at Breton and 39% less GWP at Ellerslie. Nitrous oxide emissions contributed on average 67% to the overall GWP per ha. This study demonstrated that small changes in N fertilizer have a minimal impact on the productivity of the cropping systems but can still have a substantial environmental impact.

  3. Morphing ab initio potential energy curve of beryllium monohydride

    NASA Astrophysics Data System (ADS)

    Špirko, Vladimír

    2016-12-01

    Effective (mass-dependent) potential energy curves of the ground electronic states of 9BeH, 9BeD, and 9BeT are constructed by morphing a very accurate MR-ACPF ab initio potential of Koput (2011) within the framework of the reduced potential energy curve approach of Jenč (1983). The morphing is performed by fitting the RPC parameters to available experimental ro-vibrational data. The resulting potential energy curves provide a fairly quantitative reproduction of the fitted data. This allows for a reliable prediction of the so-far unobserved molecular states in terms of only a small number of fitting parameters.

  4. Total-energy global optimizations using nonorthogonal localized orbitals

    NASA Astrophysics Data System (ADS)

    Kim, Jeongnim; Mauri, Francesco; Galli, Giulia

    1995-07-01

    An energy functional for orbital-based O(N) calculations is proposed, which depends on a number of nonorthogonal, localized orbitals larger than the number of occupied states in the system, and on a parameter, the electronic chemical potential, determining the number of electrons. We show that the minimization of the functional with respect to overlapping localized orbitals can be performed so as to attain directly the ground-state energy, without being trapped at local minima. The present approach overcomes the multiple-minima problem present within the original formulation of orbital-based O(N) methods; it therefore makes it possible to perform O(N) calculations for an arbitrary system, without including any information about the system bonding properties in the construction of the input wave functions. Furthermore, while retaining the same computational cost as the original approach, our formulation allows one to improve the variational estimate of the ground-state energy, and the energy conservation during a molecular dynamics run. Several numerical examples for surfaces, bulk systems, and clusters are presented and discussed.

  5. Benefits of Leapfrogging to Superefficiency and Low Global Warming Potential Refrigerants in Room Air Conditioning

    SciTech Connect

    Shah, Nihar K.; Wei, Max; Letschert, Virginie; Phadke, Amol A.

    2015-10-01

    Hydrofluorocarbons (HFCs) emitted from uses such as refrigerants and thermal insulating foam, are now the fastest growing greenhouse gases (GHGs), with global warming potentials (GWP) thousands of times higher than carbon dioxide (CO2). Because of the short lifetime of these molecules in the atmosphere,1 mitigating the amount of these short-lived climate pollutants (SLCPs) provides a faster path to climate change mitigation than control of CO2 alone. This has led to proposals from Africa, Europe, India, Island States, and North America to amend the Montreal Protocol on Substances that Deplete the Ozone Layer (Montreal Protocol) to phase-down high-GWP HFCs. Simultaneously, energy efficiency market transformation programs such as standards, labeling and incentive programs are endeavoring to improve the energy efficiency for refrigeration and air conditioning equipment to provide life cycle cost, energy, GHG, and peak load savings. In this paper we provide an estimate of the magnitude of such GHG and peak electric load savings potential, for room air conditioning, if the refrigerant transition and energy efficiency improvement policies are implemented either separately or in parallel.

  6. Potential for energy recovery from solid wastes

    SciTech Connect

    Velzy, C.O.

    1983-01-01

    This paper discusses the technologies, opportunities, and problems of energy-from-refuse systems. Topics considered include the direct combustion of as-received refuse, the mass-burn systems, the combustion of refuse-derived fuel, and the production of methane gas from the organic and cellulosic fraction of solid waste. A DOE-sponsored methane plant operated by Waste Management is now being evaluated at Pompano Beach, Florida. The Europeans have moved ahead so rapidly in the beneficial use of heat from the combustion of their solid waste because of the availability of a ready market for the heat in municipal facilities and/or town district heating systems. It is suggested that the use of the heat from the combustion of solid waste should be broadened to include district heating and cooling, complementary municipal functions (e.g. the disposal of sludges from wastewater treatment), integration in power generation facilities in uses other than direct production of power (e.g. boiler feedwater heating), and in industrial processing.

  7. Potential environmental problems of photovoltaic energy technology

    SciTech Connect

    Hendrey, G.R.; Moskowitz, P.D.; Patten, D.; Berry, W.; Conway, H.L.

    1980-01-01

    Separate abstracts were prepared for the ten papers of this proceedings of a workshop held at Brookhaven National Laboratory in 1980. The purposes of this proceedings are to provide a preliminary identificaton and assessment of environmental hazards which might be realistically associated with growth of the photovoltaic industry, and to provide a reference for environmental considerations by obtaining a 1980 state-of-the-art assessment of growth anticipated for the industry. Currently the industry is considered to be in the early stages of development and several possible technological options are available for large-scale manufacturing as the industry grows. Estimates of the industrial emissions of materials considered to be potentially harmful in the environment were obtained by several different analytical methods. (KRM)

  8. Global minima for water clusters (H 2O) n, n ⩽ 21, described by a five-site empirical potential

    NASA Astrophysics Data System (ADS)

    James, Tim; Wales, David J.; Hernández-Rojas, Javier

    2005-11-01

    Candidate global minimum structures are reported for (H 2O) n clusters for n ⩽ 21 described by the rigid-body TIP5P potential. These structures are compared with previously published results for the related TIP4P potential, and with ab initio calculations at the MP2 level. The variation of the energy gap from the putative global minimum to the next-lowest structure as a function of system size is analysed. Comparisons with previously reported structural trends in water clusters are made.

  9. Projecting Wind Energy Potential Under Climate Change with Ensemble of Climate Model Simulations

    NASA Astrophysics Data System (ADS)

    Jain, A.; Shashikanth, K.; Ghosh, S.; Mukherjee, P. P.

    2013-12-01

    Recent years have witnessed an increasing global concern over energy sustainability and security, triggered by a number of issues, such as (though not limited to): fossil fuel depletion, energy resource geopolitics, economic efficiency versus population growth debate, environmental concerns and climate change. Wind energy is a renewable and sustainable form of energy in which wind turbines convert the kinetic energy of wind into electrical energy. Global warming and differential surface heating may significantly impact the wind velocity and hence the wind energy potential. Sustainable design of wind mills requires understanding the impacts of climate change on wind energy potential, which we evaluate here with multiple General Circulation Models (GCMs). GCMs simulate the climate variables globally considering the greenhouse emission scenarios provided as Representation Concentration path ways (RCPs). Here we use new generation climate model outputs obtained from Coupled model Intercomparison Project 5(CMIP5). We first compute the wind energy potential with reanalysis data (NCEP/ NCAR), at a spatial resolution of 2.50, where the gridded data is fitted to Weibull distribution and with the Weibull parameters, the wind energy densities are computed at different grids. The same methodology is then used, to CMIP5 outputs (resultant of U-wind and V-wind) of MRI, CMCC, BCC, CanESM, and INMCM4 for historical runs. This is performed separately for four seasons globally, MAM, JJA, SON and DJF. We observe the muti-model average of wind energy density for historic period has significant bias with respect to that of reanalysis product. Here we develop a quantile based superensemble approach where GCM quantiles corresponding to selected CDF values are regressed to reanalysis data. It is observed that this regression approach takes care of both, bias in GCMs and combination of GCMs. With superensemble, we observe that the historical wind energy density resembles quite well with

  10. Review of economic and energy sector implications of adopting global climate change policies

    SciTech Connect

    Novak, M.H.

    1997-12-31

    This paper summarizes a number of studies examining potential economic impacts of global climate change policies. Implications for the United States as a whole, the U.S. energy sector, the U.S. economy, businesses and consumers, and world economies are considered. Impact assessments are performed of U.S. carbon emissions, carbon taxes, and carbon restrictions by comparing estimates from various organizations. The following conclusions were made from the economic studies: (1) the economic cost of carbon abatement is expensive; (2) the cost of unilateral action is very expensive with little quantifiable evidence that global emissions are reduced; (3) multilateral actions of developed countries are also very expensive, but there is quantifiable evidence of global emissions reductions; and (4) global actions have only been theoretically addressed. Paralleling these findings, the energy analyses show that the U.S. is technologically unprepared to give up fossil fuels. As a result: (1) carbon is not stabilized without a high tax, (2) stabilization of carbon is elusive, (3) technology is the only long-term answer, and (4) targeted programs may be appropriate to force technology development. 8 tabs.

  11. Role of nuclear energy to a future society of shortage of energy resources and global warming

    NASA Astrophysics Data System (ADS)

    Saito, Shinzo

    2010-03-01

    Human society entered into the society of large energy consumption since the industrial revolution and consumes more than 10 billion tons of oil equivalent energy a year in the world in the present time, in which over 80% is provided by fossil fuels such as coal, oil and natural gas. Total energy consumption is foreseen to increase year by year from now on due to significant economical and population growth in the developing countries such as China and India. However, fossil fuel resources are limited with conventional crude oil estimated to last about 40 years, and it is said that the peak oil production time has come now. On the other hand, global warming due to green house gases (GHG) emissions, especially carbon dioxide, has become a serious issue. Nuclear energy plays an important role as means to resolve energy security and global warming issues. Four hundred twenty-nine nuclear power plants are operating world widely producing 16% of the total electric power with total plant capacity of 386 GWe without emission of CO 2 as of 2006. It is estimated that another 250 GWe nuclear power is needed to keep the same level contribution of electricity generation in 2030. On the other hand, the Japan Atomic Energy Research Institute (JAERI) developed the very high temperature gas-cooled reactor (HTGR) named high temperature gas-cooled engineering test reactor (HTTR) and carbon free hydrogen production process (IS process). Nuclear energy utilization will surely widen in, not only electricity generation, but also various industries such as steel making, chemical industries, together with hydrogen production for transportation by introduction of HTGRs. The details of development of the HTTR and IS process are also described.

  12. The Global Energy Balance Archive (GEBA) version 2017: a database for worldwide measured surface energy fluxes

    NASA Astrophysics Data System (ADS)

    Wild, Martin; Ohmura, Atsumu; Schär, Christoph; Müller, Guido; Folini, Doris; Schwarz, Matthias; Zyta Hakuba, Maria; Sanchez-Lorenzo, Arturo

    2017-08-01

    The Global Energy Balance Archive (GEBA) is a database for the central storage of the worldwide measured energy fluxes at the Earth's surface, maintained at ETH Zurich (Switzerland). This paper documents the status of the GEBA version 2017 dataset, presents the new web interface and user access, and reviews the scientific impact that GEBA data had in various applications. GEBA has continuously been expanded and updated and contains in its 2017 version around 500 000 monthly mean entries of various surface energy balance components measured at 2500 locations. The database contains observations from 15 surface energy flux components, with the most widely measured quantity available in GEBA being the shortwave radiation incident at the Earth's surface (global radiation). Many of the historic records extend over several decades. GEBA contains monthly data from a variety of sources, namely from the World Radiation Data Centre (WRDC) in St. Petersburg, from national weather services, from different research networks (BSRN, ARM, SURFRAD), from peer-reviewed publications, project and data reports, and from personal communications. Quality checks are applied to test for gross errors in the dataset. GEBA has played a key role in various research applications, such as in the quantification of the global energy balance, in the discussion of the anomalous atmospheric shortwave absorption, and in the detection of multi-decadal variations in global radiation, known as global dimming and brightening. GEBA is further extensively used for the evaluation of climate models and satellite-derived surface flux products. On a more applied level, GEBA provides the basis for engineering applications in the context of solar power generation, water management, agricultural production and tourism. GEBA is publicly accessible through the internet via http://www.geba.ethz.ch. Supplementary data are available at

  13. French Brittany macroalgae screening: composition and methane potential for potential alternative sources of energy and products.

    PubMed

    Jard, G; Marfaing, H; Carrère, H; Delgenes, J P; Steyer, J P; Dumas, C

    2013-09-01

    Macroalgae are biomass resources that represent a valuable feedstock to be used entirely for human consumption or for food additives after some extractions (mainly colloids) and/or for energy production. In order to better develop the algal sector, it is important to determine the capacity of macroalgae to produce these added-values molecules for food and/or for energy industries on the basis of their biochemical characteristics. In this study, ten macroalgae obtained from French Brittany coasts (France) were selected. The global biochemical composition (proteins, lipids, carbohydrates, fibers), the presence and characteristics of added-values molecules (alginates, polyphenols) and the biochemical methane potential of these algae were determined. Regarding its biochemical composition, Palmaria palmata is interesting for food (rich in nutrients) and for anaerobic digestion (0.279 LCH4/gVS). Saccharina latissima could be used for alginate extraction (242 g/kgTS, ratio between mannuronic and guluronic acid M/G=1.4) and Sargassum muticum for polyphenol extraction (19.8 g/kgTS). Copyright © 2013 Elsevier Ltd. All rights reserved.

  14. Preliminary evaluation of wind energy potential: Cook Inlet area, Alaska

    SciTech Connect

    Hiester, T.R.

    1980-06-01

    This report summarizes work on a project performed under contract to the Alaska Power Administration (APA). The objective of this research was to make a preliminary assessment of the wind energy potential for interconnection with the Cook Inlet area electric power transmission and distribution systems, to identify the most likely candidate regions (25 to 100 square miles each) for energy potential, and to recommend a monitoring program sufficient to quantify the potential.

  15. Kinetic and dynamic studies of the Cl(2Pu) + H2O(X̃1A1) → HCl(X̃1Σ+) + OH(X̃2Π) reaction on an ab initio based full-dimensional global potential energy surface of the ground electronic state of ClH2O.

    PubMed

    Li, Jun; Dawes, Richard; Guo, Hua

    2013-08-21

    Extensive high-level ab initio calculations were performed on the ground electronic state of ClH2O. The barrier region for the title reaction was found to have significant multi-reference character, thus favoring the multi-reference configuration interaction (MRCI) method over single-reference methods such as coupled-cluster. A full-dimensional global potential energy surface was developed by fitting about 25 000 MRCI points using the permutation invariant polynomial method. The reaction path features a "late" barrier flanked by deep pre- and post-barrier wells. Calculated rate constants for the forward reaction are in reasonable agreement with experiment, suggesting a good representation of the forward barrier. The dynamics of the forward reaction was also investigated using a quasi-classical trajectory method at energies just above the barrier. While the OH bond is found to be a spectator, the HCl product has significant rotational excitation. The reaction proceeds via both direct rebound and stripping mechanisms, leading to backward and sideways scattering.

  16. Covariant energy density functionals: The assessment of global performance across the nuclear landscape

    SciTech Connect

    Afanasjev, A. V.

    2015-10-15

    The assessment of the global performance of the state-of-the-art covariant energy density functionals and related theoretical uncertainties in the description of ground state observables has recently been performed. Based on these results, the correlations between global description of binding energies and nuclear matter properties of covariant energy density functionals have been studied in this contribution.

  17. Tropical Cyclone Signatures in Atmospheric Convective Available Potential Energy

    NASA Astrophysics Data System (ADS)

    Studholme, Joshua; Gulev, Sergey

    2016-04-01

    Tropical cyclones play an important role in the climate system providing transports of energy and water vapor, forcing the ocean, and also affecting mid-latitude circulation phenomena. Tropical cyclone tracks experience strong interannual variability and in addition, longer term trend-like changes in all ocean basins. Analysis of recent historical data reveal a poleward shift in the locations of tropical cyclone tracks in both the Northern and Southern Hemispheres (Kossin et al. 2014, Nature, 509, 349-352). The physical consequences of these alterations are largely unconstrained. For example, the increasing encroachment of tropical cyclone activity into the extra-tropical environment presents a novel and still poorly understood paradigm for tropical-extratropical interactions. In this respect, the role that the atmospheric convective available potential energy (CAPE) plays in the dynamics of tropical cyclones is highly interesting. The two characteristic global-scale spatial patterns in CAPE are identified using EOF analysis. The first pattern shows an abundance of CAPE in the centre of the Pacific and corresponds to the El Nino Southern Oscillation. The second one is capturing positive CAPE anomalies in the oceanic tropics and negative anomalies over equatorial Africa. Associated with these buoyancy patterns, alterations in tropical cyclone activity occur in all basins forming both zonal and meridional patterns. Atmospheric buoyancy is the trigger for deep convection, and subsequently cyclone genesis. This is the mechanism of impact upon location at the start of cyclone tracks. It is found to have less impact upon where cyclones subsequently move, whether or not they undergo extratropical transition and when and where they experience lysis. It is shown that CAPE plays a critical role in the general circulation in the tropics which in turn is the larger steering context for embedded systems within the Walker and Hadley cells. So this lack of `latter life' impact

  18. Assessing the Potential for Renewable Energy on Public Lands

    SciTech Connect

    Not Available

    2003-02-01

    This report represents an initial activity of the Bureau of Land Managements (BLM) proposed National Energy Policy Implementation Plan: identify and evaluate renewable energy resources on federal lands and any limitations on accessing them. Ultimately, BLM will prioritize land-use planning activities to increase industrys development of renewable energy resources. These resources include solar, biomass, geothermal, water, and wind energy. To accomplish this, BLM and the Department of Energys National Renewable Energy Laboratory (NREL) established a partnership to conduct an assessment of renewable energy resources on BLM lands in the western United States. The objective of this collaboration was to identify BLM planning units in the western states with the highest potential for private-sector development of renewable resources. The assessment resulted in the following findings: (1) 63 BLM planning units in nine western states have high potential for one or more renewable energy technologies; and (2) 20 BLM planning units in seven western states have high potential for power production from three or more renewable energy sources. This assessment report provides BLM with information needed to prioritize land-use planning activities on the basis of potential for the development of energy from renewable resources.

  19. Global Deployment of Geothermal Energy Using a New Characterization in GCAM 1.0

    SciTech Connect

    Hannam, Phil; Kyle, G. Page; Smith, Steven J.

    2009-09-01

    This report documents modeling of geothermal energy in GCAM 1.0 (formerly MiniCAM) from FY2008 to FY2009, from the inputs to the U.S. Climate Change Technology Program report (Clarke et al., 2008a) to the present representation, which will be used in future work. To demonstrate the newest representation, we describe the procedure and outcome of six model runs that illustrate the potential role of geothermal energy in the U.S. and global regions through different futures climate policy, development and deployment of engineered, or enhanced, geothermal systems (EGS), and availability of other low-cost, low-carbon electricity generation technologies such as nuclear energy and carbon capture and storage (CCS).

  20. Global stabilization of high-energy response of a nonlinear wideband electromagnetic energy harvester

    NASA Astrophysics Data System (ADS)

    Sato, T.; Kato, S.; Masuda, A.

    2016-09-01

    This paper presents a resonance-type vibration energy harvester with a Duffing-type nonlinear oscillator which is designed to perform effectively in a wide frequency band. For the conventional linear vibration energy harvester, the maximum performance of the power generation and its bandwidth are in a relation of trade-off. Introducing a Duffing-type nonlinearity can expand the resonance frequency band and enable the harvester to generate larger electric power in a wider frequency range. However, since such nonlinear oscillator may have coexisting multiple steady-state solutions in the resonance band, it is difficult for the nonlinear harvester to maintain the high performance of the power generation constantly. The principle of self-excitation and entrainment has been utilized to give global stability to the high-energy orbit by destabilizing other unexpected low-energy orbits by introducing a switching circuit of the load resistance between positive and the negative values depending on the response amplitude of the oscillator. In this paper, an improved control law that switches the load resistance according to a frequency-dependent threshold is proposed to ensure the oscillator to respond in the high-energy orbit without ineffective power consumption. Numerical study shows that the steady-state responses of the harvester with the proposed control low are successfully kept on the high-energy orbit without repeating activation of the excitationmode.

  1. Anesthetic gases and global warming: Potentials, prevention and future of anesthesia.

    PubMed

    Gadani, Hina; Vyas, Arun

    2011-01-01

    Global warming refers to an average increase in the earth's temperature, which in turn causes changes in climate. A warmer earth may lead to changes in rainfall patterns, a rise in sea level, and a wide range of impacts on plants, wildlife, and humans. Greenhouse gases make the earth warmer by trapping energy inside the atmosphere. Greenhouse gases are any gas that absorbs infrared radiation in the atmosphere and include: water vapor, carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), halogenated fluorocarbons (HCFCs), ozone (O3), perfluorinated carbons (PFCs), and hydrofluorocarbons (HFCs). Hazardous chemicals enter the air we breathe as a result of dozens of activities carried out during a typical day at a healthcare facility like processing lab samples, burning fossil fuels etc. We sometimes forget that anesthetic agents are also greenhouse gases (GHGs). Anesthetic agents used today are volatile halogenated ethers and the common carrier gas nitrous oxide known to be aggressive GHGs. With less than 5% of the total delivered halogenated anesthetic being metabolized by the patient, the vast majority of the anesthetic is routinely vented to the atmosphere through the operating room scavenging system. The global warming potential (GWP) of a halogenated anesthetic is up to 2,000 times greater than CO2. Global warming potentials are used to compare the strength of different GHGs to trap heat in the atmosphere relative to that of CO2. Here we discuss about the GWP of anesthetic gases, preventive measures to decrease the global warming effects of anesthetic gases and Xenon, a newer anesthetic gas for the future of anesthesia.

  2. Anesthetic gases and global warming: Potentials, prevention and future of anesthesia

    PubMed Central

    Gadani, Hina; Vyas, Arun

    2011-01-01

    Global warming refers to an average increase in the earth′s temperature, which in turn causes changes in climate. A warmer earth may lead to changes in rainfall patterns, a rise in sea level, and a wide range of impacts on plants, wildlife, and humans. Greenhouse gases make the earth warmer by trapping energy inside the atmosphere. Greenhouse gases are any gas that absorbs infrared radiation in the atmosphere and include: water vapor, carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), halogenated fluorocarbons (HCFCs), ozone (O3), perfluorinated carbons (PFCs), and hydrofluorocarbons (HFCs). Hazardous chemicals enter the air we breathe as a result of dozens of activities carried out during a typical day at a healthcare facility like processing lab samples, burning fossil fuels etc. We sometimes forget that anesthetic agents are also greenhouse gases (GHGs). Anesthetic agents used today are volatile halogenated ethers and the common carrier gas nitrous oxide known to be aggressive GHGs. With less than 5% of the total delivered halogenated anesthetic being metabolized by the patient, the vast majority of the anesthetic is routinely vented to the atmosphere through the operating room scavenging system. The global warming potential (GWP) of a halogenated anesthetic is up to 2,000 times greater than CO2. Global warming potentials are used to compare the strength of different GHGs to trap heat in the atmosphere relative to that of CO2. Here we discuss about the GWP of anesthetic gases, preventive measures to decrease the global warming effects of anesthetic gases and Xenon, a newer anesthetic gas for the future of anesthesia. PMID:25885293

  3. Nitrogen fixation potential in global chickpea mini-core collection

    USDA-ARS?s Scientific Manuscript database

    Biological nitrogen fixation (BNF) is a sustainable alternative for nitrogen supply to agriculture worldwide. One approach to increasing BNF in agriculture is to breed and use legumes with greater BNF capacity. To assess the capacity for BNF in chickpea (Cicer arietinum) global germplasm, a genetica...

  4. Globalization, Democracy, and Social Movements: The Educational Potential of Activism

    ERIC Educational Resources Information Center

    Hytten, Kathy

    2016-01-01

    In this essay, I explore the contemporary value of John Dewey's conception of democracy to addressing the challenges of neoliberal globalization. I begin by describing his vision of democracy as a way of life that requires habits of experimentalism, pluralism, and hope. I then suggest that contemporary forms of mobilization, resistance, and…

  5. Globalization, Democracy, and Social Movements: The Educational Potential of Activism

    ERIC Educational Resources Information Center

    Hytten, Kathy

    2016-01-01

    In this essay, I explore the contemporary value of John Dewey's conception of democracy to addressing the challenges of neoliberal globalization. I begin by describing his vision of democracy as a way of life that requires habits of experimentalism, pluralism, and hope. I then suggest that contemporary forms of mobilization, resistance, and…

  6. Ecogenomics and potential biogeochemical impacts of globally abundant ocean viruses.

    PubMed

    Roux, Simon; Brum, Jennifer R; Dutilh, Bas E; Sunagawa, Shinichi; Duhaime, Melissa B; Loy, Alexander; Poulos, Bonnie T; Solonenko, Natalie; Lara, Elena; Poulain, Julie; Pesant, Stéphane; Kandels-Lewis, Stefanie; Dimier, Céline; Picheral, Marc; Searson, Sarah; Cruaud, Corinne; Alberti, Adriana; Duarte, Carlos M; Gasol, Josep M; Vaqué, Dolors; Bork, Peer; Acinas, Silvia G; Wincker, Patrick; Sullivan, Matthew B

    2016-09-29

    Ocean microbes drive biogeochemical cycling on a global scale. However, this cycling is constrained by viruses that affect community composition, metabolic activity, and evolutionary trajectories. Owing to challenges with the sampling and cultivation of viruses, genome-level viral diversity remains poorly described and grossly understudied, with less than 1% of observed surface-ocean viruses known. Here we assemble complete genomes and large genomic fragments from both surface- and deep-ocean viruses sampled during the Tara Oceans and Malaspina research expeditions, and analyse the resulting 'global ocean virome' dataset to present a global map of abundant, double-stranded DNA viruses complete with genomic and ecological contexts. A total of 15,222 epipelagic and mesopelagic viral populations were identified, comprising 867 viral clusters (defined as approximately genus-level groups). This roughly triples the number of known ocean viral populations and doubles the number of candidate bacterial and archaeal virus genera, providing a near-complete sampling of epipelagic communities at both the population and viral-cluster level. We found that 38 of the 867 viral clusters were locally or globally abundant, together accounting for nearly half of the viral populations in any global ocean virome sample. While two-thirds of these clusters represent newly described viruses lacking any cultivated representative, most could be computationally linked to dominant, ecologically relevant microbial hosts. Moreover, we identified 243 viral-encoded auxiliary metabolic genes, of which only 95 were previously known. Deeper analyses of four of these auxiliary metabolic genes (dsrC, soxYZ, P-II (also known as glnB) and amoC) revealed that abundant viruses may directly manipulate sulfur and nitrogen cycling throughout the epipelagic ocean. This viral catalog and functional analyses provide a necessary foundation for the meaningful integration of viruses into ecosystem models where they

  7. Ecogenomics and potential biogeochemical impacts of globally abundant ocean viruses

    NASA Astrophysics Data System (ADS)

    2016-09-01

    Ocean microbes drive biogeochemical cycling on a global scale. However, this cycling is constrained by viruses that affect community composition, metabolic activity, and evolutionary trajectories. Owing to challenges with the sampling and cultivation of viruses, genome-level viral diversity remains poorly described and grossly understudied, with less than 1% of observed surface-ocean viruses known. Here we assemble complete genomes and large genomic fragments from both surface- and deep-ocean viruses sampled during the Tara Oceans and Malaspina research expeditions, and analyse the resulting ‘global ocean virome’ dataset to present a global map of abundant, double-stranded DNA viruses complete with genomic and ecological contexts. A total of 15,222 epipelagic and mesopelagic viral populations were identified, comprising 867 viral clusters (defined as approximately genus-level groups). This roughly triples the number of known ocean viral populations and doubles the number of candidate bacterial and archaeal virus genera, providing a near-complete sampling of epipelagic communities at both the population and viral-cluster level. We found that 38 of the 867 viral clusters were locally or globally abundant, together accounting for nearly half of the viral populations in any global ocean virome sample. While two-thirds of these clusters represent newly described viruses lacking any cultivated representative, most could be computationally linked to dominant, ecologically relevant microbial hosts. Moreover, we identified 243 viral-encoded auxiliary metabolic genes, of which only 95 were previously known. Deeper analyses of four of these auxiliary metabolic genes (dsrC, soxYZ, P-II (also known as glnB) and amoC) revealed that abundant viruses may directly manipulate sulfur and nitrogen cycling throughout the epipelagic ocean. This viral catalog and functional analyses provide a necessary foundation for the meaningful integration of viruses into ecosystem models where

  8. Global positioning system watches for estimating energy expenditure.

    PubMed

    Hongu, Nobuko; Orr, Barron J; Roe, Denise J; Reed, Rebecca G; Going, Scott B

    2013-11-01

    Global positioning system (GPS) watches have been introduced commercially, converting frequent measurements of time, location, speed (pace), and elevation into energy expenditure (EE) estimates. The purpose of this study was to compare EE estimates of 4 different GPS watches (Forerunner, Suunto, Polar, Adeo), at various walking speeds, with EE estimate from a triaxial accelerometer (RT3), which was used as a reference measure in this study. Sixteen healthy young adults completed the study. Participants wore 4 different GPS watches and an RT3 accelerometer and walked at 6-minute intervals on an outdoor track at 3 speeds (3, 5, and 7 km/hr). The statistical significance of differences in EE between the 3 watches was assessed using linear contrasts of the coefficients from the overall model. Reliability across trials for a given device was assessed using intraclass correlation coefficients as estimated in the mixed model. The GPS watches demonstrated lower reliability (intraclass correlation coefficient) across trials when compared with the RT3, particularly at the higher speed, 7 km/hr. Three GPS watches (Forerunner, Polar, and Suunto) significantly and consistently underestimated EE compared with the reference EE given by the RT3 accelerometer (average mean difference: Garmin, -50.5%; Polar, -41.7%; and Suunto, -41.7%; all p < 0.001). Results suggested that caution should be exercised when using commercial GPS watches to estimate EE in athletes during field-based testing and training.

  9. Atomic bond fluctuations and crossover to potential-energy-landscape-influenced regime in supercooled liquid.

    PubMed

    Levashov, V A; Egami, T; Aga, R S; Morris, J R

    2008-10-01

    The ideas related to potential-energy landscape and cooperativity of atomic rearrangements are widely discussed in the research field of glass transition. The crossover transition from high-temperature regime to potential-energy-landscape-influenced regime was extensively studied using the concept of inherent structure. However, the interpretation of this crossover behavior in terms of microscopic changes in real structures is still lacking. In this paper we present several observations on the crossover behavior on real structures. We compare fluctuations in the global properties (total number of bonds, total potential energy, pressure) versus fluctuations in the local properties (coordination number, atomic potential energy, local atomic pressure) by means of molecular dynamics simulations. We then show that the total and local fluctuations in the number of atomic bonds in the system depend on temperature differently above and below the temperature of crossover to the landscape-influenced regime. Similarly, the ratio between the global and local fluctuations in the potential energy and pressure changes in the vicinity of the crossover temperature, whereas the change is less distinct than in the case of the bond fluctuations. Our results indicate that local fluctuations become more correlated below the crossover temperature, most likely via the interaction through the dynamic shear elastic field.

  10. Intermolecular potential energy surface for CS2 dimer.

    PubMed

    Farrokhpour, Hossein; Mombeini, Zainab; Namazian, Mansoor; Coote, Michelle L

    2011-04-15

    A new four-dimensional intermolecular potential energy surface for CS(2) dimer is obtained by ab initio calculation of the interaction energies for a range of configurations and center-of-mass separation distances for the first time. The calculations were performed using the supermolecular approach at the Møller-Plesset second-order perturbation (MP2) level of theory with the augmented correlation consistent basis sets (aug-cc-pVxZ, x = D, T) and corrected for the basis-set superposition error using the full counterpoise correction method. A two-point extrapolation method was used to extrapolate the calculated energy points to the complete basis set limit. The effect of using the higher levels of theory, quadratic configuration interaction containing single, double, and perturbative triple excitations QCISD(T) and coupled cluster singles, doubles and perturbative triples excitations CCSD(T), on the shape of potential energy surface was investigated. It is shown that the MP2 level of theory apparently performs extremely poorly for describing the intermolecular potential energy surface, overestimating the total energy by a factor of nearly 1.73 in comparison with the QCISD(T) and CCSD(T) values. The value of isotropic dipole-dipole dispersion coefficient (C(6) ) of CS(2) fluid was obtained from the extrapolated MP2 potential energy surface. The MP2 extrapolated energy points were fitted to well-known analytical potential functions using two different methods to represent the potential energy surface analytically. The most stable configuration of the dimer was determined at R = 6.23 au, α = 90°, β = 90°, and γ = 90°, with a well depth of 3.980 kcal mol(-1) at the MP2 level of theory. Finally, the calculated second virial coefficients were compared with experimental values to test the quality of the presented potential energy surface. Copyright © 2010 Wiley Periodicals, Inc.

  11. Energy and agriculture: their interacting futures. Policy implications of global models

    SciTech Connect

    Levy, M.; Robinson, J.L.

    1984-01-01

    Papers presented at a 1982 Paris symposium discuss the global aspects of energy-agriculture interaction, but often use details of local situations for clarification and illustration. The papers are grouped under the general topics of the food-energy problem, modeling and systems approach, and resource management. Four emerging problems (the energy-intensity of the green revolution, the fuelwood crisis, the shift from food to energy production, and the effect of high energy prices on the trade balances of developing countries) lend themselves to global modeling techniques. Separate abstracts were prepared on 18 papers for the Energy Data Base (EDB) and Energy Abstract for Energy Analysis (EAPA).

  12. Achieving Land, Energy, and Environmental Compatibility: Utility-Scale Solar Energy Potential and Land-Use in California

    NASA Astrophysics Data System (ADS)

    Hoffacker, M. K.; Hernandez, R. R.; Field, C. B.

    2013-12-01

    Solar energy is an archetype renewable energy technology with great potential to reduce greenhouse gas emissions when substituted for carbon-intensive energy. Utility-scale solar energy (USSE; i.e., > 1 MW) necessitates large quantities of space making the efficient use of land for USSE development critical to realizing its full potential. However, studies elucidating the interaction between land-use and utility-scale solar energy (USSE) are limited. In this study, we assessed 1) the theoretical and technical potential of terrestrial-based USSE systems, and 2) land-use and land-cover change impacts from actual USSE installations (> 20 MW; planned, under construction, operating), using California as a case study due to its early adoption of renewable energy systems, unique constraints on land availability, immense energy demand, and vast natural resources. We used topo-climatic (e.g., slope, irradiance), infrastructural (e.g., proximity to transmission lines), and ecological constraints (e.g., threatened and endangered species) to determine highly favorable, favorable, and unfavorable locations for USSE and to assess its technical potential. We found that the theoretical potential of photovoltaic (PV) and concentrating solar power (CSP) in California is 26,097 and 29,422 kWh/m2/day, respectively. We identified over 150 planned, under construction, and operating USSE installations in California, ranging in size from 20 to 1,000 MW. Currently, 29% are located on shrub- and scrublands, 23% on cultivated crop land, 13% on pasture/hay areas, 11% on grassland/herbaceous and developed open space, and 7% in the built environment. Understanding current land-use decisions of USSE systems and assessing its future potential can be instructive for achieving land, energy, and environmental compatibility, especially for other global regions that share similar resource demands and limitations.

  13. Potential production of energy cane for fuel in the Caribbean

    SciTech Connect

    Samuels, G.

    1984-08-01

    Sugarcane grown as energy cane presents a new potential to the Caribbean countries to provide their own energy needs and to reduce or eliminate fuel oil imports. The use of proper agronomic techniques can convert conventional sugarcane growing to a crop capable of giving energy feedstocks in the form of fiber for boiler fuel for electricity and fermentable solids for alcohol for motor fuel. Sugarcane can still be obtained from the energy cane for domestic consumption and export if desired. The aerable land now devoted to sugarcane can utilized for energy-cane production without causing any serious imbalance in food crop production.

  14. Saint Paul Energy Park: the potential for district heating

    SciTech Connect

    Lee, C.; Kron, R.; Davis, H.

    1980-03-01

    The results of ANL's study of the energy and economic aspects of using district heating in the St. Paul Energy Park are summarized. The Energy Park is a 6 million ft/sup 2/ residential, commercial office, and light industrial complex to be built in the midway area of St. Paul, Minnesota. Space heating and cooling design loads for the park were calculated assuming that the ASHRAE's 90-75 energy-conserving construction standards would be used in constructing the park's buildings. Based in part on this assumption, ANL estimated the costs and energy use characteristics of six possible energy system options for supplying Energy Park's space heating, space cooling, and domestic hot water heating needs. The results indicate that in today's economy, a central heating and cooling plant with natural gas boilers and electrically driven centrifugal chillers with thermal storage has good potential for energy and economic savings and clearly merits further consideration.

  15. Global warming and prairie wetlands: potential consequences for waterfowl habitat

    USGS Publications Warehouse

    Poiani, Karen A.; Johnson, W. Carter

    1991-01-01

    precipitation and runoff from melting snow on frozen or saturated soils (Figure 2). Annual water levels fluctuate widely due to climate variability in the Great Plains (Borchert 1950, Kantrud et al. 1989b). Climate affects the quality of habitat for breeding waterfowl by controlling regional water conditions--water depth, areal extent, and length of wet/dry cycles (Cowardin et al. 1988)--and vegetation patterns such as the cover ration (the ratio of emergent plant cover to open water). With increased levels of atmospheric carbon dioxide, climate models project warmer and, in some cases, drier conditions for the northern Great Plains (Karl et al. 1991, Manabe and Wetherald 1986, Mitchell 1983, Rind and Lebedeff 1984). In general, a warmer, drier climate could lower waterfowl production directly by increasing the frequency of dry basins and indirectly by producing less favorable cover rations (i.e., heavy emergent cover with few or no open-water areas). The possibility of diminished waterfowl production in a greenhouse climate comes at a time when waterfowl numbers have sharply declined for other reasons (Johnson and Shaffer 1987). Breeding habitat continues to be lost or altered by agriculture, grazing, burning, mowing, sedimentation, and drainage (Kantrud et al. 1989b). For example, it has been estimated that 60% of the wetland area in North Dakota has been drained (Tiner 1984). Pesticides entering wetlands from adjacent agricultural fields have been destructive to aquatic invertebrate populations and have significantly lowered duckling survival (Grue et al. 1988). In this article, we discuss current understanding and projections of global warming; review wetland vegetation dynamics to establish the strong relationship among climate, wetland hydrology, vegetation patterns, and waterflow habitat; discuss the potential effects of a greenhouse warming on these relationships; and illustrate the potential effects of climate change on wetland habitat by using a simulation model. The

  16. Ab initio Potential Energy Surface for H-H2

    NASA Technical Reports Server (NTRS)

    Partridge, Harry; Bauschlicher, Charles W., Jr.; Stallcop, James R.; Levin, Eugene

    1993-01-01

    Ab initio calculations employing large basis sets are performed to determine an accurate potential energy surface for H-H2 interactions for a broad range of separation distances. At large distances, the spherically averaged potential determined from the calculated energies agrees well with the corresponding results determined from dispersion coefficients; the van der Waals well depth is predicted to be 75 +/- (mu)E(sub h). Large basis sets have also been applied to reexamine the accuracy of theoretical repulsive potential energy surfaces. Multipolar expansions of the computed H-H2 potential energy surface are reported for four internuclear separation distances (1.2, 1.401, 1.449, and 1.7a(sub 0) of the hydrogen molecule. The differential elastic scattering cross section calculated from the present results is compared with the measurements from a crossed beam experiment.

  17. Semiclassical energy levels and the corresponding potentials in nonhydrogenic ions

    NASA Astrophysics Data System (ADS)

    Pankratov, P.; Meyer-Ter-Vehn, J.

    1992-11-01

    A semiclassical expression is derived for the potential seen by an nl-shell electron in a nonhydrogenic ion. Corresponding energies Enl are compared with experimental values and with results of self-consistent-field calculations.

  18. Potential energy stored by planets and grand minima events

    NASA Astrophysics Data System (ADS)

    Cionco, Rodolfo G.

    2012-07-01

    Recently, Wolff & Patrone (2010), have developed a simple but very interesting model by which the movement of the Sun around the barycentre of the Solar system could create potential energy that could be released by flows pre-existing inside the Sun. The authors claim that it is the first mechanism showing how planetary movements can modify internal structure in the Sun that can be related to solar cycle. In this work we point out limitations of mentioned mechanism (which is based on interchange arguments), which could be inapplicable to a real star. Then, we calculate the temporal evolution of potential energy stored in zones of Sun's interior in which the potential energy could be most efficiently stored taking into account detailed barycentric Sun dynamics. We show strong variations of potential energy related to Maunder Minimum, Dalton Minimum and the maximum of Cycle 22, around 1990. We discuss briefly possible implications of this putative mechanism to solar cycle specially Grand Minima events.

  19. Ab initio Potential Energy Surface for H-H2

    NASA Technical Reports Server (NTRS)

    Partridge, Harry; Bauschlicher, Charles W., Jr.; Stallcop, James R.; Levin, Eugene

    1993-01-01

    Ab initio calculations employing large basis sets are performed to determine an accurate potential energy surface for H-H2 interactions for a broad range of separation distances. At large distances, the spherically averaged potential determined from the calculated energies agrees well with the corresponding results determined from dispersion coefficients; the van der Waals well depth is predicted to be 75 +/- (mu)E(sub h). Large basis sets have also been applied to reexamine the accuracy of theoretical repulsive potential energy surfaces. Multipolar expansions of the computed H-H2 potential energy surface are reported for four internuclear separation distances (1.2, 1.401, 1.449, and 1.7a(sub 0) of the hydrogen molecule. The differential elastic scattering cross section calculated from the present results is compared with the measurements from a crossed beam experiment.

  20. Sectoral trends in global energy use and greenhouse gasemissions

    SciTech Connect

    Price, Lynn; de la Rue du Can, Stephane; Sinton, Jonathan; Worrell, Ernst; Zhou, Nan; Sathaye, Jayant; Levine, Mark

    2006-07-24

    In 2000, the Intergovernmental Panel on Climate Change (IPCC) published a new set of baseline greenhouse gas (GHG) emissions scenarios in the Special Report on Emissions Scenarios (SRES) (Nakicenovic et al., 2000). The SRES team defined four narrative storylines (A1, A2, B1 and B2) describing the relationships between the forces driving GHG and aerosol emissions and their evolution during the 21st century. The SRES reports emissions for each of these storylines by type of GHG and by fuel type to 2100 globally and for four world regions (OECD countries as of 1990, countries undergoing economic reform, developing countries in Asia, rest of world). Specific assumptions about the quantification of scenario drivers, such as population and economic growth, technological change, resource availability, land-use changes, and local and regional environmental policies, are also provided. End-use sector-level results for buildings, industry, or transportation or information regarding adoption of particular technologies and policies are not provided in the SRES. The goal of this report is to provide more detailed information on the SRES scenarios at the end use level including historical time series data and a decomposition of energy consumption to understand the forecast implications in terms of end use efficiency to 2030. This report focuses on the A1 (A1B) and B2 marker scenarios since they represent distinctly contrasting futures. The A1 storyline describes a future of very rapid economic growth, low population growth, and the rapid introduction of new and more efficient technologies. Major underlying themes are convergence among regions, capacity building, and increased cultural and social interactions, with a substantial reduction in regional differences in per capita income. The B2 storyline describes a world with an emphasis on economic, social, and environmental sustainability, especially at the local and regional levels. It is a world with moderate population growth

  1. The global land and ocean mean energy balance

    NASA Astrophysics Data System (ADS)

    Wild, Martin; Folini, Doris

    2016-04-01

    land, and 16 and 100 Wm-2 over oceans, for sensible and latent heat fluxes, respectively. Estimated uncertainties are on the order of 10 and 5 Wm-2 for most surface and TOA fluxes, respectively. Combining these surface budgets with satellite-determined TOA budgets (CERES-EBAF) results in an atmospheric solar absorption of 77 and 82 Wm-2 and a net atmospheric thermal emission of -165 and -190 Wm-2 over land and oceans, respectively. We further revisit the global mean energy balance by combining the area weighed land and ocean mean budgets. This study is published in: Wild, M., Folini, D., Hakuba, M., Schär, C., Seneviratne, S.I., Kato, S., Rutan, D., Ammann, C., Wood, E.F., and König-Langlo, G., 2015: The energy balance over land and oceans: An assessment based on direct observations and CMIP5 climate models. Clim. Dyn., Dyn., 44, 3393-3429, doi: 10.1007/s00382-014-2430-z.

  2. Potential increasing dominance of heterotrophy in the global ocean

    NASA Astrophysics Data System (ADS)

    Kvale, K. F.; Meissner, K. J.; Keller, D. P.

    2015-07-01

    Autotrophy is largely resource-limited in the modern ocean. Paleo evidence indicates this was not necessarily the case in warmer climates, and modern observations as well as standard metabolic theory suggest continued ocean warming could shift global ecology towards heterotrophy, thereby reducing autotrophic nutrient limitation. Such a shift would entail strong nutrient recycling in the upper ocean and high rates of net primary production (NPP), yet low carbon export to the deep ocean and sediments. We demonstrate transition towards such a state in the early 22nd century as a response to business-as-usual representative concentration pathway forcing (RCP8.5) in an intermediate complexity Earth system model in three configurations; with and without an explicit calcifier phytoplankton class and calcite ballast model. In all models nutrient regeneration in the near-surface becomes an increasingly important driver of primary production. The near-linear relationship between changes in NPP and global sea surface temperature (SST) found over the 21st century becomes exponential above a 2-4{ }\\circ {{C}} global mean SST change. This transition to a more heterotrophic ocean agrees roughly with metabolic theory.

  3. Automated parameterization of intermolecular pair potentials using global optimization techniques

    NASA Astrophysics Data System (ADS)

    Krämer, Andreas; Hülsmann, Marco; Köddermann, Thorsten; Reith, Dirk

    2014-12-01

    In this work, different global optimization techniques are assessed for the automated development of molecular force fields, as used in molecular dynamics and Monte Carlo simulations. The quest of finding suitable force field parameters is treated as a mathematical minimization problem. Intricate problem characteristics such as extremely costly and even abortive simulations, noisy simulation results, and especially multiple local minima naturally lead to the use of sophisticated global optimization algorithms. Five diverse algorithms (pure random search, recursive random search, CMA-ES, differential evolution, and taboo search) are compared to our own tailor-made solution named CoSMoS. CoSMoS is an automated workflow. It models the parameters' influence on the simulation observables to detect a globally optimal set of parameters. It is shown how and why this approach is superior to other algorithms. Applied to suitable test functions and simulations for phosgene, CoSMoS effectively reduces the number of required simulations and real time for the optimization task.

  4. Possible explanation of the atmospheric kinetic and potential energy spectra.

    PubMed

    Vallgren, Andreas; Deusebio, Enrico; Lindborg, Erik

    2011-12-23

    We hypothesize that the observed wave number spectra of kinetic and potential energy in the atmosphere can be explained by assuming that there are two related cascade processes emanating from the same large-scale energy source, a downscale cascade of potential enstrophy, giving rise to the k(-3) spectrum at synoptic scales and a downscale energy cascade giving rise to the k(-5/3) spectrum at mesoscales. The amount of energy which is going into the downscale energy cascade is determined by the rate of system rotation, with negligible energy going downscale in the limit of very fast rotation. We present a set of simulations of a system with strong rotation and stratification, supporting these hypotheses and showing good agreement with observations.

  5. Assessing the global warming potential of wooden products from the furniture sector to improve their ecodesign.

    PubMed

    González-García, Sara; Gasol, Carles M; Lozano, Raúl García; Moreira, María Teresa; Gabarrell, Xavier; Rieradevall i Pons, Joan; Feijoo, Gumersindo

    2011-12-01

    The main objective of this study was to determine the global warming potential of several wood products as an environmental criterion for their ecodesign. Two methodologies were combined: the quantification of greenhouse gas emissions (equivalent CO(2)) of several representative wood based products from the furniture sector and the integration of environmental aspects into product design. The products under assessment were classified in two groups: indoor products and outdoor products, depending on their location. "Indoor products" included a convertible cot/bed, a kitchen cabinet, an office table, a living room furniture, a headboard, youth room accessories and a wine crate, while the "Outdoor products" analysed were a ventilated wooden wall and a wooden playground. Spanish wood processing companies located in Galicia (NW Spain) and Catalonia (NE Spain) were analysed in detail. The life cycle of each product was carried out from a cradle-to-gate perspective according to Life Cycle Assessment (LCA) methodology, using global warming potential as the selected impact category. According to the results, metals, boards and energy use appeared to be the most contributing elements to the environmental impact of the different products under assessment, with total contributions ranging from 40% to 90%. Furthermore, eco-design strategies were proposed by means of the methodology known as Design for the Environment (DfE). Improvement strategies viable for implementation in the short term were considered and analysed in detail, accounting for remarkable reductions in the equivalent CO(2) emissions (up to 60%). These strategies would be focused on the use of renewable energies such as photovoltaic cells, the promotion of national fibres or changes in the materials used. Other alternatives to be implemented in the long term can be of potential interest for future developments. Copyright © 2011 Elsevier B.V. All rights reserved.

  6. Potential energy landscapes of elemental and heterogeneous chalcogen clusters

    SciTech Connect

    Mauro, John C.; Loucks, Roger J.; Balakrishnan, Jitendra; Varshneya, Arun K.

    2006-02-15

    We describe the potential energy landscapes of elemental S{sub 8}, Se{sub 8}, and Te{sub 8} clusters using disconnectivity graphs. Inherent structures include both ring and chain configurations, with rings especially dominant in Se{sub 8}. We also map the potential energy landscapes of heterogeneous Se{sub n}(S,Te){sub 8-n} clusters, which offer insights into the structure of heterogeneous chalcogen glasses.

  7. Energy potential of municipal solid waste is limited

    SciTech Connect

    1994-09-01

    Energy recovery from municipal solid waste has the potential for making only a limited contribution to the nation`s overall energy production. Although the current contribution of waste-derived energy production is less than one-half of 1 percent of the nation`s total energy Supply, DOE has set a goal for energy from waste at 2 percent of the total supply by 2010. The industry`s estimates show a smaller role for waste as an energy source in the future. The energy potential from waste is limited not only by the volume and energy content of the waste itself, but also by the factors affecting the use of waste disposal options, including public opposition and the availability of financing. Energy production from waste combustors and from landfill gases generates pollutants, although these are reduced through current regulations that require the use of emissions control technology and define operational criteria for the facilities. Although DOE estimates that one-third of the energy available from waste is available in the form of energy savings through the recycling of materials, the Department`s research in this area is ongoing.

  8. Geospatial Analysis of Renewable Energy Technical Potential on Tribal Lands

    SciTech Connect

    Doris, E.; Lopez, A.; Beckley, D.

    2013-02-01

    This technical report uses an established geospatial methodology to estimate the technical potential for renewable energy on tribal lands for the purpose of allowing Tribes to prioritize the development of renewable energy resources either for community scale on-tribal land use or for revenue generating electricity sales.

  9. Waste to Energy Potential - A High Concentration Anaerobic Bioreactor

    DTIC Science & Technology

    2012-05-23

    output • Uses the organic portion of solid waste (such as food waste , paper products, and agricultural waste ) to fuel an anaerobic digestion ...Sustainability Symposium & Exhibition Anaerobic Digestion • What does it do? • Offers sustainability by addressing renewable energy, waste ... Waste to Energy Potential – A High Concentration Anaerobic Bioreactor Presenter: Scott Murphy & Rebecca Robbennolt ARCADIS/Malcolm Pirnie Date

  10. Gravitational potential as a source of earthquake energy

    USGS Publications Warehouse

    Barrows, L.; Langer, C.J.

    1981-01-01

    Some degree of tectonic stress within the earth originates from gravity acting upon density structures. The work performed by this "gravitational tectonics stress" must have formerly existed as gravitational potential energy contained in the stress-causing density structure. According to the elastic rebound theory (Reid, 1910), the energy of earthquakes comes from an elastic strain field built up by fairly continuous elastic deformation in the period between events. For earthquakes resulting from gravitational tectonic stress, the elastic rebound theory requires the transfer of energy from the gravitational potential of the density structures into an elastic strain field prior to the event. An alternate theory involves partial gravitational collapse of the stress-causing density structures. The earthquake energy comes directly from a net decrease in gravitational potential energy. The gravitational potential energy released at the time of the earthquake is split between the energy released by the earthquake, including work done in the fault zone and an increase in stored elastic strain energy. The stress associated with this elastic strain field should oppose further fault slip. ?? 1981.

  11. A Global Perspective: NASA's Prediction of Worldwide Energy Resources (POWER) Project

    NASA Technical Reports Server (NTRS)

    Zhang, Taiping; Stackhouse, Paul W., Jr.; Chandler, William S.; Hoell, James M.; Westberg, David; Whitlock, Charles H.

    2007-01-01

    The Prediction of the Worldwide Energy Resources (POWER) Project, initiated under the NASA Science Mission Directorate Applied Science Energy Management Program, synthesizes and analyzes data on a global scale that are invaluable to the renewable energy industries, especially to the solar and wind energy sectors. The POWER project derives its data primarily from NASA's World Climate Research Programme (WCRP)/Global Energy and Water cycle Experiment (GEWEX) Surface Radiation Budget (SRB) project (Version 2.9) and the Global Modeling and Assimilation Office (GMAO) Goddard Earth Observing System (GEOS) assimilation model (Version 4). The latest development of the NASA POWER Project and its plans for the future are presented in this paper.

  12. Global energy transports and the influence of clouds on transport requirements - a satellite analysis

    SciTech Connect

    Sohn, ByungJu; Smith, E.A. )

    1992-07-01

    The impact of differential net radiative heating on two-dimensional energy transports within the atmospheric-ocean system and the role of clouds on this process is examined. Nimbus-7 earth radiation budget data show basic energy surpluses over the tropical oceans and relative or absolute energy deficits over low-latitude continental regions. The two-dimensional mean energy transports exhibit an east-west coupled dipole structure in which the west Pacific acts as a major energy source and North Africa as the major energy sink. The dipole is embedded in the secondary energy transports arising mainly from the differential heating between land and oceans in the tropics in which the tropical east-west (zonal) transports are up to 30% of the tropical north-south (meridonal) transports. Any perturbations to this dipole on an interannual basis give rise to low-latitude energy transport variations. In turn, the tropical variations lead to extratropical responses through alternations of requirements on both zonal and meridional transports at all positions on the globe. Cloud-induced transports indicate that year-to-year cloud amount changes are contributing to fluctuations of the global climate system through these mechanisms. Increased cloudiness increases zonal available potential energy, thus increasing the intensity of the north-south transports while slightly weakening the dipole intensity. The basic role of cloudiness appears to be to diminish the role of differential heating between continents and oceans and force the globe toward a more meridionally distributed energy imbalance. This implies the radiative feedback effects of clouds, regardless of factors determining cloud amount variability, reduce the radiative decoupling of land and ocean.

  13. Electron acceptor redox potential globally regulates transcriptomic profiling in Shewanella decolorationis S12

    NASA Astrophysics Data System (ADS)

    Lian, Yingli; Yang, Yonggang; Guo, Jun; Wang, Yan; Li, Xiaojing; Fang, Yun; Gan, Lixia; Xu, Meiying

    2016-08-01

    Electron acceptor redox potential (EARP) was presumed to be a determining factor for microbial metabolism in many natural and engineered processes. However, little is known about the potentially global effects of EARP on bacteria. In this study, we compared the physiological and transcriptomic properties of Shewanella decolorationis S12 respiring with different EARPs in microbial electrochemical systems to avoid the effects caused by the other physicochemical properties of real electron acceptor. Results showed that the metabolic activities of strain S12 were nonlinear responses to EARP. The tricarboxylic acid cycle for central carbon metabolism was down-regulated while glyoxylate shunt was up-regulated at 0.8 V compared to 0.2 and ‑0.2 V, which suggested that EARP is an important but not the only determinant for metabolic pathways of strain S12. Moreover, few cytochrome c genes were differentially expressed at different EARPs. The energy intensive flagella assembly and assimilatory sulfur metabolism pathways were significantly enriched at 0.8 V, which suggested strain S12 had stronger electrokinesis behavior and oxidative stress-response at high EARP. This study provides the first global information of EARP regulations on microbial metabolism, which will be helpful for understanding microorganism respiration.

  14. Electron acceptor redox potential globally regulates transcriptomic profiling in Shewanella decolorationis S12

    PubMed Central

    Lian, Yingli; Yang, Yonggang; Guo, Jun; Wang, Yan; Li, Xiaojing; Fang, Yun; Gan, Lixia; Xu, Meiying

    2016-01-01

    Electron acceptor redox potential (EARP) was presumed to be a determining factor for microbial metabolism in many natural and engineered processes. However, little is known about the potentially global effects of EARP on bacteria. In this study, we compared the physiological and transcriptomic properties of Shewanella decolorationis S12 respiring with different EARPs in microbial electrochemical systems to avoid the effects caused by the other physicochemical properties of real electron acceptor. Results showed that the metabolic activities of strain S12 were nonlinear responses to EARP. The tricarboxylic acid cycle for central carbon metabolism was down-regulated while glyoxylate shunt was up-regulated at 0.8 V compared to 0.2 and −0.2 V, which suggested that EARP is an important but not the only determinant for metabolic pathways of strain S12. Moreover, few cytochrome c genes were differentially expressed at different EARPs. The energy intensive flagella assembly and assimilatory sulfur metabolism pathways were significantly enriched at 0.8 V, which suggested strain S12 had stronger electrokinesis behavior and oxidative stress-response at high EARP. This study provides the first global information of EARP regulations on microbial metabolism, which will be helpful for understanding microorganism respiration. PMID:27503002

  15. Free energy calculations: an efficient adaptive biasing potential method.

    PubMed

    Dickson, Bradley M; Legoll, Frédéric; Lelièvre, Tony; Stoltz, Gabriel; Fleurat-Lessard, Paul

    2010-05-06

    We develop an efficient sampling and free energy calculation technique within the adaptive biasing potential (ABP) framework. By mollifying the density of states we obtain an approximate free energy and an adaptive bias potential that is computed directly from the population along the coordinates of the free energy. Because of the mollifier, the bias potential is "nonlocal", and its gradient admits a simple analytic expression. A single observation of the reaction coordinate can thus be used to update the approximate free energy at every point within a neighborhood of the observation. This greatly reduces the equilibration time of the adaptive bias potential. This approximation introduces two parameters: strength of mollification and the zero of energy of the bias potential. While we observe that the approximate free energy is a very good estimate of the actual free energy for a large range of mollification strength, we demonstrate that the errors associated with the mollification may be removed via deconvolution. The zero of energy of the bias potential, which is easy to choose, influences the speed of convergence but not the limiting accuracy. This method is simple to apply to free energy or mean force computation in multiple dimensions and does not involve second derivatives of the reaction coordinates, matrix manipulations nor on-the-fly adaptation of parameters. For the alanine dipeptide test case, the new method is found to gain as much as a factor of 10 in efficiency as compared to two basic implementations of the adaptive biasing force methods, and it is shown to be as efficient as well-tempered metadynamics with the postprocess deconvolution giving a clear advantage to the mollified density of states method.

  16. A global assessment of the local impacts of land cover changes on the surface energy budget

    NASA Astrophysics Data System (ADS)

    Cescatti, A.; Duveiller, G.; Hooker, J.

    2016-12-01

    Biophysical effects of land use and land cover change (LULCC) on climate have received less attention than biogeochemical effects. Yet, their impact is potentially more perceptible because the effect is almost immediate at local scales. Biophysical effects depend on the specific LULCC transition, and can change in sign and magnitude across space and time. Spatially explicit assessments are therefore required to describe these phenomena. Whilst accurately characterising these local biophysical effects using Land Surface Models (LSMs) can be problematic given the strong modelling assumptions that must be made, satellite remote sensing instruments operationally measure several of the key energy fluxes at high temporal and spatial resolution across the entire planet. We leverage this synoptic property of remote sensing to develop a methodology capable of isolating the biophysical signal of potential vegetation transitions at local scale. Because mapping LULCC accurately at global scale is notoriously challenging, and because many potential transitions may not yet have occurred in various places, the approach relies on trading space for time over a moving window as a surrogate for monitoring real change. The result is a global dataset with a spatial resolution of 1° indicating the potential change in all terms of the surface energy balance (excepting the soil heat flux) for all transitions amongst 7 different plant functional types that are widely used by the land surface modelling community. This dataset will serve three main purposes: (1) to derive a data-driven diagnostic of the local biophysical effects of LULCC on the surface energy budget and local climate; (2) to provide a benchmark to assess model performances; and (3) to develop guidelines for the monitoring, reporting and verification of climate mitigation and adaptation plans that account for land biophysical impacts on climate.

  17. Potential Increasing Dominance of Heterotrophy in the Global Ocean

    NASA Astrophysics Data System (ADS)

    Kvale, K.; Meissner, K. J.; Keller, D. P.

    2016-02-01

    Autotrophs are largely limited by resources in the modern ocean. However, standard metabolic theory suggests continued ocean warming could globally benefit heterotrophs, thereby reducing autotrophic nutrient limitation. The paleo record as well as modern observations offer evidence this has happened in the past and could happen again. Increasing dominance of heterotrophs would result in strong nutrient recycling in the upper ocean and high rates of net primary production (NPP), yet low carbon export to the deep ocean and sediments. We describe the transition towards such a state in the early 22nd century as a response to business-as-usual Representative Concentration Pathway forcing (RCP8.5) in an intermediate complexity Earth system model in three configurations: with and without an explicit calcifier phytoplankton class and calcite ballast model. In all models nutrient regeneration in the near surface becomes an increasingly important driver of primary production. The near-linear relationship between changes in NPP and global sea surface temperature (SST) found over the 21st century becomes exponential above a 2-4 °C global mean SST change. This transition to a more heterotrophic ocean agrees roughly with metabolic theory. Inclusion of small phytoplankton and calcifiers increase the model NPP:SST sensitivity because of their relatively higher nutrient affinity than general phytoplankton. Accounting for organic carbon "protected" from remineralization by carbonate ballast mitigates the exponential increase in NPP and provides an increasingly important pathway for deep carbon export with higher SST changes, despite simultaneous increasing carbonate dissolution rates due to ocean acidification.

  18. Scenarios of energy demand and efficiency potential for Bulgaria

    SciTech Connect

    Tzvetanov, P.; Ruicheva, M.; Denisiev, M.

    1996-12-31

    The paper presents aggregated results on macroeconomic and final energy demand scenarios developed within the Bulgarian Country Study on Greenhouse Gas Emissions Mitigation, supported by US Country Studies Program. The studies in this area cover 5 main stages: (1) {open_quotes}Baseline{close_quotes} and {open_quotes}Energy Efficiency{close_quotes} socioeconomic and energy policy philosophy; (2) Modeling of macroeconomic and sectoral development till 2020; (3) Expert assessments on the technological options for energy efficiency increase and GHG mitigation in the Production, Transport and Households and Services Sectors; (4) Bottom-up modeling of final energy demand; and (5) Sectoral and overall energy efficiency potential and policy. Within the Bulgarian Country Study, the presented results have served as a basis for the final integration stage {open_quotes}Assessment of the Mitigation Policy and Measures in the Energy System of Bulgaria{close_quotes}.

  19. Solar energy in California industry - Applications, characteristics and potential

    NASA Technical Reports Server (NTRS)

    Barbieri, R. H.; Pivirotto, D. S.

    1978-01-01

    Results of a survey to determine the potential applicability of solar thermal energy to industrial processes in California are presented. It is found that if the heat for all industrial processes at temperatures below 212 F were supplied by solar energy, total state energy consumption could be reduced by 100 trillion Btus (2%), while the use of solar energy in processes between 212 and 350 F could displace 500 trillion Btus. The issues and problems with which solar energy must contend are illustrated by a description of fluid milk processing operations. Solar energy application is found to be technically feasible for processes with thermal energy requirements below 212 F, with design, and degree of technical, economic and management feasibility being site specific. It is recommended that the state provide support for federal and industrial research, development and demonstration programs in order to stimulate acceptance of solar process heat application by industry.

  20. Solar energy in California industry - Applications, characteristics and potential

    NASA Technical Reports Server (NTRS)

    Barbieri, R. H.; Pivirotto, D. S.

    1978-01-01

    Results of a survey to determine the potential applicability of solar thermal energy to industrial processes in California are presented. It is found that if the heat for all industrial processes at temperatures below 212 F were supplied by solar energy, total state energy consumption could be reduced by 100 trillion Btus (2%), while the use of solar energy in processes between 212 and 350 F could displace 500 trillion Btus. The issues and problems with which solar energy must contend are illustrated by a description of fluid milk processing operations. Solar energy application is found to be technically feasible for processes with thermal energy requirements below 212 F, with design, and degree of technical, economic and management feasibility being site specific. It is recommended that the state provide support for federal and industrial research, development and demonstration programs in order to stimulate acceptance of solar process heat application by industry.